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HomeMy WebLinkAbout5001_Jackson_WCU_MSWLF_Feb2022GW_FID1659004_20220331wood. FEBRUARY 2022 SEMI-ANNUAL WATER QUALITY AND LANDFILL GAS MONITORING REPORT Western Carolina University Closed Municipal Solid Waste Landfill Monteith Gap Road Cullowhee, Jackson County, North Carolina 28723 NCDEQ Permit: 50-01 Prepared For: Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Prepared by: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 March 24, 2022 Wood Project 6252-15-0221 March 24, 2022 wood. Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, NC 28806 USA T: 828-252-8130 www.woodpic.com Mr. Lee Smith Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Subject: February 2022 Water Quality and Landfill Gas Monitoring Report WCU Closed Municipal Solid Waste Landfill Cullowhee, Jackson County, North Carolina NCDEQ Permit: 50-01 Wood Project 6252-15-0221 Dear Mr. Smith: Wood Environment & Infrastructure Solutions, Inc. (Wood) is pleased to submit this February 2022 Water Quality and Landfill Gas Monitoring Report for Western Carolina University's (WCU's) closed municipal solid waste landfill located in Cullowhee, North Carolina. The scope of work for this monitoring event was described in Wood's Proposal for Environmental Services, dated June 3, 2021 Wood appreciates the opportunity to provide our environmental services to WCU. If you have any questions regarding this report, please contact us at (828) 252-8130. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Gregory L. Hutchins Technical Professional III GLH/MEW:gIh Matthew E. Wallace, P.E. Principal Engineer cc: Ms. Jaclynne Drummond — NCDEQ Solid Waste Section, Asheville Regional Office Mr. Lee Hill — NCDEQ Solid Waste Section, Asheville Regional Office North Carolina Corporate Engineering License No. F-1253; Geology No. C-247 February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 TABLE OF CONTENTS Page 1. Introduction..................................................................................................................................1 1.1. Site -Specific Information............................................................................................................................1 1.2. Background Information............................................................................................................................1 2. Field Activities..............................................................................................................................2 2.1. Landfill Gas Monitoring..............................................................................................................................2 2.2. Water Quality Monitoring..........................................................................................................................2 3. Results and Discussion................................................................................................................3 3.1. Landfill Gas.......................................................................................................................................................3 3.2. Groundwater and Surface Water............................................................................................................3 3.2.1. Appendix I VOCs.......................................................................................................................................4 3.2.2. 1,4-Dioxane.................................................................................................................................................4 3.2.3. Appendix I Metals....................................................................................................................................4 LIST OF TABLES 1 Landfill Gas Well Construction Details 2 Well Construction and Water Level Data — February 2022 3 Groundwater Quality Data — February 2022 4 Groundwater Analytical Results — February 2022 5 Surface Water Analytical Results — February 2022 6 Historical Groundwater Analytical Results 7 Historical Surface Water Analytical Results LIST OF FIGURES 1 Topographic Site Map 2 Landfill Gas, Monitoring Well, and Surface Water Sampling Locations APPENDICES A Landfill Gas Monitoring Data Form B Groundwater Sampling Logs C NCDEQ Environmental Monitoring Reporting Form D Laboratory Analytical Report February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 1. INTRODUCTION This report documents field activities and results from the February 2022 water quality and landfill gas monitoring event at Western Carolina University's (WCU's) closed Municipal Solid Waste Landfill (MSWLF) located in Cullowhee, North Carolina (Site) as shown on Figure 1. 1.1. Site -Specific Information Site Name: WCU Closed MSWLF Facility Permit Number: Facility Latitude/Longitude Site Location Map: Facility Address: Facility Owner: 50-01 N 350 19' 30" / W 830 10' 55" Figure 1 Monteith Gap Road Cullowhee, North Carolina Jackson County Western Carolina University Attn. Mr. Roger Turk 3476 Old Cullowhee Road Cullowhee, North Carolina, 28723 (828) 227-3571 Primary Consultant: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 (828) 252-8130 1.2. Background Information WCU operated the MSWLF from approximately the 1960s until 1993. Jackson County also disposed of municipal solid waste at the landfill from approximately the early 1970s through the early 1980s. The landfill property is approximately 31.5 acres, approximately four acres of which contain the former landfill. The landfill was closed in accordance with the then applicable North Carolina Department of Environmental Quality (NCDEQ) closure standards (15A NCAC 13B 0.0510), and a closure letter was issued to WCU by NCDEQ on September 5, 1995. NCDEQ personnel conducted a facility audit on March 16, 2011 and determined that semi-annual water quality and landfill gas monitoring at the landfill must be performed in order for the landfill to be in compliance with the post -closure conditions identified in the 1995 closure letter. In response to the audit, a Landfill Gas Investigation Work Plan, which described the preliminary landfill gas investigation, as well as the 'full' landfill gas investigation, was submitted to NCDEQ on October 19, 2011, and approved by NCDEQ in a letter dated November 29, 2011. Wood February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 Environment & Infrastructure Solutions, Inc. (Wood) conducted the preliminary landfill gas investigation in January 2012 using the existing groundwater monitoring wells. NCDEQ indicated that when funding became available to WCU from the State of North Carolina, the 'full' landfill gas investigation was to be implemented. Wood has conducted semi-annual water quality monitoring since August 2011 and conducted semi-annual landfill gas monitoring utilizing the existing groundwater monitoring wells from August 2012 to November 2015 to comply with the post - closure conditions. The 'full' landfill gas investigation, including the installation of eight permanent landfill gas monitoring wells, was performed in February 2016. Quarterly landfill gas monitoring is now conducted. 2. FIELD ACTIVITIES Wood personnel visited the Site on February 10, 2022 to conduct landfill gas monitoring and on February 11, 2022 to conduct water quality monitoring. 2.1. Landfill Gas Monitoring Wood personnel measured landfill gas at the eight landfill gas monitoring wells (LG-1, LG-2, LG-3S, LG-3D, LG-4, LG-5, LG-6 and LG-7) at the Site (Figure 2). The landfill gas monitoring wells are screened in the unsaturated zone and located between the landfill and the Site's property boundary (Table 1). The landfill gas monitoring wells are fitted with a slip cap and ball valve to allow for measurement of potential landfill gas. A calibrated gas monitoring instrument, a Landtec GEM 5000, was used to measure atmospheric barometric pressure, as well as the following landfill gas parameters: Methane (percent by volume) Oxygen (percent by volume) Carbon dioxide (percent by volume) The initial and stabilized readings for the above parameters were measured and recorded. The Solid Waste Section's Landfill Gas Monitoring Data Form was used to record measurements and other relevant information and is provided in Appendix A. 2.2. Water Quality Monitoring Wood personnel gauged static groundwater levels in the four Site monitoring wells (MW-1, MW-2, MW-3 and MW-4). Water levels were referenced to the top -of -casing at the wells. Depth to water measurements and water table elevations for the monitoring wells are presented in Table 2. The monitoring wells were purged and sampled using low -flow purging techniques with a variable - speed submersible or a peristaltic pump with new polyethylene tubing. The tubing intake was lowered to within five feet of the bottom of the monitoring wells. The pumping rate was minimized to prevent excessive drawdown in the well and simulate the groundwater recharge rate, which was monitored using an electronic water level indicator. Water quality parameters (temperature, pH, specific conductance, dissolved oxygen, oxidation-reduction potential, and turbidity) were measured using a water quality meter equipped with a flow -through cell (Table 3). Groundwater samples were collected from the monitoring wells after the water quality parameters stabilized. 2 February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 The purge water was discharged to the ground surface in proximity to each well in a manner that precluded erosion or surface runoff. Copies of the groundwater sampling logs are provided in Appendix B. The submersible pump was decontaminated by washing the pump and electrical cable in an industrial detergent and distilled water solution. The pump was then rinsed with distilled water. An equipment blank sample, EB-1, was collected from the pump discharge by operating the pump in deionized water and pumping the water into sample containers. A surface water sample (SW-2) was collected at the approximate location depicted in Figure 2. The approximate location of surface water sample SW-1, as depicted in Figure 2, was observed to be dry. The water samples were placed in laboratory -supplied containers, labeled with sampling information, packed in an ice -chilled cooler, and shipped with appropriate chain -of -custody records via overnight delivery to Waypoint Analytical (a North Carolina -accredited analytical laboratory). The samples were submitted for analysis of Appendix I volatile organic compounds (VOCs) according to Environmental Protection Agency (EPA) Method 8260, 1,4-dioxane via EPA Method 8260 SIM (selective ion monitoring), and Appendix I metals according to EPA Method 6020 (3030C preparation method). 3. RESULTS AND DISCUSSION The results of the water quality and landfill gas monitoring event are reported in the NCDEQ Environmental Monitoring Report Form that is provided in Appendix C and summarized in the following sections. 3.1. Landfill Gas The Site landfill gas monitoring wells were tested for methane, carbon dioxide and oxygen. Refer to the attached Landfill Gas Monitoring Data Form for the testing results. Concentrations of methane were not detected in the landfill gas monitoring wells. The regulatory limit for methane at a MSWLF property boundary is equal to the lower explosive limit of methane (15A NCAC 1313.1627 (d)). The recorded results from the eight landfill gas wells (non -detect) do not exceed this limit indicating that regulatory limits are not being exceeded at the Site's property boundary. 3.2. Groundwater and Surface Water The groundwater elevations obtained from the monitoring wells on February 11, 2022 indicate that surficial groundwater flow is in a northwesterly direction towards the Tuckasegee River, which is consistent with the flow direction observed during previous monitoring events. Monitoring well MW-1 is the u pg rad ient/backg round monitoring well. The groundwater analytical results were compared to the North Carolina Groundwater Classification and Standards (15A NCAC 2L .0202, amended effective April 1, 2013), which includes applicable interim standards updated February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 April 6, 2018, herein referred to as the "2L Groundwater Standards", and the EPA Maximum Contaminant Levels (MCLs) established in the National Primary Drinking Water Regulations, dated May 2009. The surface water analytical results were compared to the North Carolina Surface Water Quality Standards, Criteria and In -Stream Target Values (15A NCAC 2B, summary tables, dated July 26, 2021), which include EPA's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health, herein referred to collectively as the "Surface Water Standards." Analytical results from the February 2022 water quality monitoring event are presented in Tables 4 and 5, and historical analytical results are presented in Tables 6 and 7. The laboratory analytical report is included in Appendix D. 3.2.1. Appendix I VOCs Five Appendix I VOCs were detected or estimated at concentrations above the MDLs in the groundwater sample collected from monitoring well MW-3, and one Appendix I VOC (acetone) was estimated at a concentration above the MDL in the groundwater samples collected from monitoring wells MW-1 and MW-2. Six Appendix I VOCs were detected or estimated at concentrations above the MDLs in the field duplicate groundwater sample, FD-1, which was collected from monitoring well MW-3. The detected or estimated VOC concentrations were below their respective 2L Groundwater Standards and EPA MCLs (if established). Appendix I VOCs were not detected above the method detection limit (MDL) in the groundwater sample collected from monitoring well MW-4. Four Appendix I VOCs were detected or estimated at concentrations above the MDLs in the surface water sample collected from SW-2. The VOC concentrations were below their respective Surface Water Standards, if established. 3.2.2. 1,4-Dioxane 1,4-Dioxane was not detected above the MDL in the groundwater samples collected from the monitoring wells; however, a concentration of 1,4-dioxane was estimated above the MDL in the field duplicate sample collected from MW-3. The concentration of 1,4-dioxane estimated in the field duplicate sample was below the 2L Groundwater Standard of 3.0 micrograms per liter (pg/L). An EPA MCL is not currently established for 1,4-dioxane in groundwater. 1,4-Dioxane was estimated at a concentration above the MDL in the surface water sample collected at SW-2. The concentration of 1,4-dioxane estimated in SW-2, 1.64 pg/L, did not exceed the applicable Surface Water Standard/In-Stream Target Value (Human Health) of 80 pg/L. 3.2.3. Appendix I Metals Six Appendix I metals were detected above the MDLs in the groundwater samples, including the field duplicate sample FD-1, which was collected from MW-3, and the equipment blank EB-1. Two of the six Appendix I metals (cobalt and vanadium) were estimated or detected at concentrations above their respective 2L Groundwater Standards. The six Appendix I metals were detected at concentrations and/or estimated concentrations below their respective EPA MCLs, if established. Information on each of the metals is presented below. 4 February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 Barium was detected at concentrations above the MDL, but below the 2L Groundwater Standard and EPA MCL in each of the groundwater samples collected, including the field duplicate and equipment blank samples. Chromium was detected or estimated at concentrations above the MDL, but below the 2L Groundwater Standard and EPA MCL in groundwater samples collected from MW-1 and MW-2. Chromium was not detected above the MDL in the remaining groundwater samples. Cobalt was detected or estimated at concentrations above the MDL in the groundwater samples collected from MW-1, MW-2, and MW-3 (including duplicate FD-1). The concentrations of cobalt detected from MW-3 and FD-1 exceeded the 2L Groundwater Standard of 1.0 pg/L. An EPA MCL is not currently established for cobalt. Cobalt was not detected above the MDL in the other groundwater samples or the equipment blank. Lead was estimated at a concentration above the MDL, but below its 2L Groundwater Standard and EPA MCL in the groundwater sample collected from the site's background/upgradient monitoring well MW-1. Lead was not detected above the MDL in the other groundwater samples or the equipment blank. Nickel was detected or estimated at concentrations above the MDL, but below its respective 2L Groundwater Standard, in the groundwater samples collected from MW-1, MW-2, and MW-3 (including duplicate FD-1). Nickel was also detected above the MDL in the equipment blank. An EPA MCL is not currently established for nickel. Vanadium was estimated at concentrations above the 2L Groundwater Standard in the groundwater samples collected from MW-1 and MW-2. Vanadium was not detected above the MDL in the other groundwater samples or the equipment blank; however, the MDL was elevated above the 2L Groundwater Standard of 0.3 pg/L. An EPA MCL is not currently established for vanadium. Concentrations of six Appendix I metals were detected or estimated above the MDL collected from the site's background/upgradient monitoring well MW-1. Concentrations of Appendix I metals in groundwater samples have generally been lower than historical concentrations with less exceedances above applicable Standards since low -flow purging/sampling has been implemented. Low -flow purging/sampling techniques will continue to be used for the next semi-annual water quality monitoring event. Four Appendix I metals were detected or estimated at concentrations above the MDLs in the surface water sample collected from SW-2. Cobalt was detected at a concentration of 4.36 pg/L in SW-2, which exceeds the North Carolina In -Stream Target Value (Human Health) of 4 pg/L. Concentrations of the other three Appendix I metals were below their respective Surface Water Standards. February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 TABLES TABLE 1 Landfill Gas Well Construction Details Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Landfill Gas Well Installation Date Drilling Method Well Material Well Depth (bgs) Screened Interval (bgs) Ground Surface Elevation Top of Casing Elevation Latitude Longitude LG-1 LG-2 2/17/2016 2/17/2016 HSA PVC PVC 18.0 5.0 - 17.8 5.0 - 19.7 2,243.52 2,246.35 2,209.97 35.3241 35.3249 -83.1822 -83.1825 HSA 20.0 2,207.23 LG-3S 2/16/2016 HSA PVC 30.0 4.8 - 29.8 2,180.25 2,183.19 35.3261 -83.1831 LG-3D 2/16/2016 HSA PVC 66.2 36.0 - 66.0 2,180.25 2,183.14 35.3261 -83.1831 LG-4 2/18/2016 HSA PVC 7.9 4.9 - 7.7 2,125.80 2,128.58 35.3266 -83.1823 LG-5 2/18/2016 HSA PVC 30.4 5.3 - 30.1 2,166.48 2,169.12 35.3266 -83.1813 LG-6 2/18/2016 HSA PVC 10.7 5.6 - 10.4 2,208.23 2,210.92 35.3253 -83.1810 LG-7 2/17/2016 HSA PVC 35.3 5.2 - 35.0 2,266.43 2,269.08 35.3244 -83.1811 Notes: 1. Depths are in feet relative to ground surface (bgs). 2. Elevations are in feet relative to mean sea level. 3. HSA - hollow -stem auger; PVC - Schedule 40 polyvinyl chloride. Prepared By: RMC 8/30/21 Checked By: GLH 9/16/21 TABLE 2 Well Construction Details and Water Level Data - February 2022 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Well Installation Date* Latitude Longitude Ground Surface Top of Casing Elevation Elevation Well Depth (feet MSL) (feet MSL) (feet BTOQ Depth to Water (feet BTOQ Groundwater Elevation (feet MSL) MW-1 1990 35.3240 -83.1811 2,302.50 2,306.01 93.28 70.59 2,235.42 MW-2 1990 35.3249 -83.1825 2,206.88 2,209.37 50.78 28.05 2,181.32 MW-3* 1990 35.3259 -83.1826 2,182.88 2,185.65 **62.92 55.15 2,130.50 MW-4 1990 35.3264 -83.1818 2,129.14 2,131.66 21.35 6.90 2,124.76 Notes: 1. Water levels were obtained on February 11, 2022 2. * Actual date of well installation is not known, but monitoring wells were first sampled in March 1990 during closure activities (Law Engineering report dated January 16, 1991); screened interval depths are not known. 3. MSL - mean sea level; BTOC - below top of casing. 4. ** Well depth indicated in 2004 monitoring report (RETAW Corporation) indicates well depth is 71.7 feet. Prepared By: GLH 2123122 Checked By: MAS 3/4/22 TABLE 3 Water Quality Data - February 2022 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Oxidation Reduction Dissolved Temperature Conductivity Potential Oxygen Turbidity Monitoring Well (°C) pH (mS/cm) (mv) (mg/L) (NTU) MW-1 13.06 4.78 0.026 300 8.36 62.9 MW-2 12.86 4.74 0.125 273 1.30 8.8 MW-3 14.24 5.60 0.437 48 0.00 2.3 MWA 13.13 5.80 0.143 181 1.29 3.1 SW-2 13.21 5.81 0.338 -31 5.01 14.5 Notes: 1. Water quality data reported above collected prior to sample collection. 2. Water quality parameters were measured on February 11, 2022 3. °C - degrees Celcius; mS/cm - milliSiemens per centimeter; my - millivolts; NTU - nephelometric turbidity units; mg/L - milligrams per liter. Prepared By: GLH 2/22/22 Checked By: MAS 3/4/22 TABLE 4 Groundwater Analytical Results - February 2022 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 2L Groundwater Standard EPA MCL MW-1 MW-2 FD-1 MW-3 (MW-3) MW-4 Appendix I VOCs Acetone 6,000 NE 2.25 J 2.35 J <1.80 12.3 <1.80 Benzene 1 5 <0.180 <0.180 0.636 0.630 <0.180 Chlorobenzene 50 100 <0.190 <0.190 15.4 15.1 <0.190 1,2-Dichlorobenzene 20 600 <0.220 <0.220 0.323 J 0.267 J <0.220 1,4-Dichlorobenzene 6 75 <0.210 <0.210 3.16 3.20 <0.210 cis-1,2-Dichloroethylene 70 70 <0.200 <0.200 1.73 1.71 <0.200 1,4-Dioxane 1,4-Dioxane 3 NE <0.139 <0.139 <0.139 1.29 J <0.139 Appendix I Metals Barium 700 2,000 36.6 83.6 111 113 37.9 Chromium 10 100 4.16 1.60 J <0.817 <0.825 <0.817 Cobalt 1 NE 0.776 J 0.949 J 14.0 14.2 <0.538 Lead 15 15 0.345 J <0.270 <0.270 <0.270 <0.270 Nickel 100 NE 2.74 J 1.43 J 3.28 3.19 <0.529 Vanadium 0.3 NE 1.45 J 1.96 J <1.35 <1.35 <1.35 Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation method. 3. Concentrations are in micrograms per liter (pg/L). 4. 2L Groundwater Standard - from 15A NCAC 2L, effective April 1, 2013, including Interim Maximum Allowable Concentrations. 5. EPA MCL - Environmental Protection Agency Maximum Contaminant Level. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated MDL. 9. J - concentration is estimated. 10. Bold concentrations indicate detected concentration or MDL exceeds the 2L Groundwater Standard. Prepared by: GLH 2/23/22 Checked by: MAS 3/7/22 TABLE 5 Surface Water Analytical Results - February 2022 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 NC Surface Water Standard (Freshwater Aquatic Life) NC Surface Water Standard (Human Health) EPA NRWQC (Human Health) In -Stream Target Values (Freshwater Aquatic Life) In -Stream Target Values (Human Health) SW-2 Appendix I VOCs Acetone Benzene Chlorobenzene NE NE NE 2,000 1,100,000 3.22 J 0.234 J 2.61 NE 51 NE NE NE NE NE 800 140 100 NE 1,4-Dichlorobenzene NE NE 900 NE 0.671 1,4-Dioxane 1,4-Dioxane NE NE NE NE 80 1.64 J Appendix I Metals Barium Cobalt NE NE NE 21,000 200,000 (t) 128 NE NE NE 16 (acute) 4 4.36 Nickel 145 (acute)* NE 4,600 NE NE 0.877 J Selenium 5 (t) NE 170 NE NE 1.20 J Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I Metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation. 3. Concentrations are in micrograms per liter (Ng/L). 4. NC Surface Water Standard - From 15A NCAC 2B (tables dated July 26, 2021). 5. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated method detection limit. 9. J - concentration is estimated 10. Bold concentration indicates exceedance of NC In -Stream Target Value. 11. t - Based upon measurement of total recoverable metal. 12. * A hardness of 25 milligrams per liter was assumed to calculate the standard. Prepared By: GLH 2/23/22 Checked By: MAS 3/7/22 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals Monitoring Location Sample Date W C 0 V Q N y N CO GI N S O O S d C G7 O C S u do Gi Q O .2 S V N ri do N S O .2V S u G 14 d c w C ++ O` O C N rj N 0 d a s O O S V ti �n m d M `p L V T O > a X O G ri T O O a Q V •� Q E 7 R CO E ? .T N CO l: •= E ra M O v E O S u = R O v N C O v .� y Y V Z 'C y y in E 3 - S I.- E 7 m m > = N MW-1 8/3/11 0.35 JB 390 63 B 28 180 7.8 38 0.88 J 0.98 J 160 212112 0.421B 62 1.7 3.5 J 0.79 JB 17 8/28/12 0.651B 0.321 270 0.351 0.591 8.2 JB 16 26 7.0 6.3 0.271 2.9 14 37 B 2/8/13 0.73 J 0.58 JB 530 0.841 0.591 17 B 42 64 19 17 0.34 J 0.481 0.64J 20 63 9/4/13 350 0.321 1.7 18 22 61 9.8 13 2.4 JB 0.151 26 80 2/19/14 0.20 J 39 0.054 J 0.161 0.261 1.11 0.201 0.47 J 0.074 J 6.01 9/9/14 3.7 0.381 45 0.096 J 0.161 1.4 2.8 J 0.531 0.67 JB 0.28 J 8.6 JA 6.1 JB 2/25/15 7.3 B /*0.27 J 0.641 110 0.141 1.1 2.1 J 0.631 0.911 0.831 26 6.8 J 11/6/15 0.082 J 0.781 40 0.141 0.111 4.3 B 0.531 2.01 0.521 1.01 0.042 J 0.17 J 3.91 3/2/16 0.21 J 2.6 B 37 0.591 6.3 B 0.161 1.9 J 0.391 3.0 0.045 J 0.121 13 B/*4.8 J 9/21/16 0.14 J 36 0.062 J 0.052 J 1.6 0.421 4.7 1 0.241 3.8 0.027 J 0.073 J 7.41 2/7/17 0.74 J 37 0.141 0.181 0.971 0.431 4.51 0.501 0.961 0.141 0.26 J 1.3 J 5.2 J 8/23/17 41 0.571 0.47 BL, 1 1.81 0.171 0.391 0.861 0.151 24 3/15/18 1.0 B /*ND 48 B/*63 0.811 0.581 3.41 0.371 0.561 0.076 J 0.054 J 20 B /*21 8/21/18 110 0.121 0.076 J 14 5.9 13 2.6 37 0.034 J 3.1 17 3/25/19 2.9 B /*<0.19 54 0.881 0.681 1.7 J 0.621 2.1 0.022 J 16 8/20/19 4.2 J 32 1.6 J 13 J 2/25/20 2.3 BJ 36 1.1 J 4.7 J 1.5 J 9/10/20 50 14 1.4 J 7.2 J 0.401 7.8 4.2 J 8.0 J 2/9/21 0.170 J 35.1 1.12 J 8/24/21 75.6 4.16 2.8 4.891 1.0 6.8 2.15 J 7.011 2/11/22 2.25 J 36.6 4.16 0.776 J 0.345 J 2.741 1.45 J M W-2 8/3/11 0.48 J 0.22 J 130 0.201 2.0 1.8 1.2 J 0.59 J 2.5 0.541 0.076 J 0.76 J 3.8 J 9.5 J 2/2/12 0.931B 120 0.331 0.721 0.17 JB 2.3 0.064 J 0.26 J 9.3 J 8/28/12 0.461B 110 0.311 0.471 4.8 JB 0.621 1.5 J 0.501 2.5 0.040 J 3.0 2.5 J 11 B 2/8/13 100 0.161 2.2 B 0.311 1.4 J 0.151 1.9 J 0.211 0.141 0.161 16 9/4/13 100 0.381 0.661 2.9 J 1.8 J 21 2/19/14 0.22 J 0.361 100 0.151 0.171 0.211 0.131 1.5 J 0.181 0.093 J 0.050 J 7.51 9/9/14 4.2 92 0.181 0.261 0.621 1.2 J 0.181 1.5 JB 0.046 J 0.35 J 6.6 JA 9.0 JB 2/25/15 5.1 B /*0.22 J 62 1.6 2.7 7.0 1.2 1.7 J 12 33 11/6/15 0.075 J 100 0.111 0.131 3.6 B 3.0 2.8 J 0.691 1.7 J 0.039 J 0.151 5.31 3/2/16 0.12 J 3.4 B 100 0.601 5.5 B 0.161 1.8 J 0.271 1.6 J 1.3 0.051 J 0.099 J 0.37 J 12 B/*4.3 J 9/21/16 2.4 J 0.12 J 110 0.095 J 1.1 0.281 8.6 0.191 2.6 0.018 J 0.059 J 8.61 2/7/17 0.59 J 89 0.241 0.281 0.571 0.331 1.21 0.431 1.6 J 0.601 0.141 0.37 J 1.1 J 5.3 J 8/23/17 0.38 J 100 0.081 J 0.071 J 0.531 0.80 BL, J 2.31 0.21 J 1.3 J 0.50 J 0.17 J 28 3/15/18 0.95 BJ/*0.701 110 B /*110 0.069 J 0.751 0.661 2.5 J 0.131 1.8 J 0.075 J 0.035 J 16 B /*16 8/21/18 100 0.085 J 0.082 J 0.531 0.083 J 4.2 J 0.321 1.5 J 13 3/25/19 3.9 B /*0.22 J 110 0.085 J 0.481 0.491 3.41 0.39 J 1.7 J 0.085 J 16 8/20/19 89 1.7 J 19 J 2/25/20 2.1 BJ 87 1.3 J 1.5 J 9/10/20 79 1.0 J 2/9/21 0.177 J 86 1.18 J 8/24/21 78.7 1.261 1.72 J 2/11/22 2.35 J 83.6 1.601 0.949 J 1.43 J 1.96 J 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 3 1 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 NE 1 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Page 1 of 2 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals Monitoring Location Sample Date W C 0 V Q N y N CO GI N S O O S d C G7 O C S u do Gi Q O .2 S V N rP do N S O .2V S u G 14 d c w C ++ O` O C N rj N 0 d a s O O S V ti �n d M `p L V T O > a X O G ri T O O C Q V •� Q E 7 R CO E ? .T N CO l: •= E ra M O v E O S u = R O v N C O v .� y Y V Z 'C y y in E 3 - S I.- E 7 m m > = N MW-3 8/3/11 78 1.0 15 0.66 4.9 9.5 0.49 J 1.0 150 0.89 J 1.3 8.5 1.7 J 0.591 5.1 1.5 0.151 1.1 3.0 J 46 2/2/12 6.6 0.79 7.1 3.4 4.8 0.34 J 0.721B 5.0 340 0.341 31 36 75 30 8.2 B 79 1.3 0.072 J 1.3 36 3,700 8/28/12 3.3 J 0.97 14 4.5 8.8 0.181B 0.971 130 0.481 4.7 JB 6.3 1.8 J 0.301 4.1 1.6 0.091 J 0.68 J 40 B 2/8/13 3.2 9.1 3.7 5.5 150 0.561 1.6 B 15 2.6 J 0.181 4.0 1.1 0.071 J 26 9/4/13 0.51 11 3.2 5.2 390 0.201 0.701 26 17 16 4.3 J 19 2.3 JB 50 95 2/19/14 0.71 12 3.7 6.4 0.13 J 0.371 150 0.073 J 0.371 7.3 2.1 J 0.331 2.5 0.771 0.068 J 0.054 J 1.8 J 18 9/9/14 0.61 12 4.1 4.5 3.4 130 0.076 J 0.241 9.0 1.6 J 0.191 3.0 B 0.161 9.5 JA 20 B 2/25/15 79 1.1 12 3.9 5.2 6.1 B /*0.41 J 1.2 340 0.281 2.1 14 13 20 4.8 16 0.831 0.074 J 0.38 J 38 120 11/6/15 250 1.1 17 0.53 4.9 5.6 1.2 390 0.231 1.1 25 B 16 25 6.3 19 1.1 0.058 J 0.33 J 54 120 3/2/16 5.4 0.59 10 2.3 4.0 0.095 J 3.1 B 120 0.048 J 0.431 5.2 B 6.2 1.4 J 0.341 1.5 J 4.5 0.048 J 0.035 J 12 B/*5.0 J 9/21/16 28 0.79 14 3.5 3.5 0.30 J 150 0.251 0.731 11 3.3 J 0.681 6.6 0.821 0.020 J 0.131 3.4 J 18 2/7/17 260 0.97 10 3.6 2.9 1.6 1.2 250 0.231 3.2 9.0 8.9 17 7.5 14 1.6 0.072 J 0.50 J 17 180 3/15/18 0.85 15 3.8 5.0 0.85BJ/*0.54 J 150 B /*150 0.461 13 4.1 280 13 0.511 67 1.2 J 0.074 J 0.38 J 0.90 J 300 B /*280 8/21/18 7.7 0.61 9.9 2.4 2.5 110 0.111 0.078 J 0.561 15 2.4 J 0.073 J 4.2 0.57 J 9.7 3/25/19 6.8 0.63 11 0.261 2.7 2.7 3.1 3.8 B /*<0.19 120 0.341 17 1.5 J 0.161 5.3 0.038 J 12 8/20/19 0.53 11 2.4 2.2 2.5 120 9.2 3.2 15 J 2/25/20 0.40 J 9.2 2.3 1.7 1.6 J 2.1 BJ 120 10 3.5 9/10/20 0.46 J 8.4 2.0 1.6 1.1 J 110 7.8 3.3 2/9/21 0.458 J 10 2.36 1.66 0.310 J 117 8.88 2.75 J 8/24/21 2.751 0.633 11.9 0.243 J 2.38 1.54 108 9.25 10.70 7.91 2/11/22 0.636 15.4 0.323 J 3.16 1.73 ill 14.0 3.28 MW-4 8/3/11 0.67 15 0.53 5.4 4.8 0.27 J 0.311 210 0.361 4.4 1.9 3.5 J 1.4 2.3 0.911 0.060 J 0.35 J 7.4 11 2/2/12 1.5 0.73 0.52 0.441B 89 0.381 1.01 0.46 JB 0.191 14 8/28/12 3.5 1.6 1.1 120 0.371 5.9 JB 0.821 2.81 0.651 1.51 0.591 0.41 J 4.1 J 28 B 2/8/13 1.7 0.83 0.65 85 0.131 3.0 B 0.471 1.91 0.331 0.671 0.331 0.041 J 18 9/4/13 10.0 3.9 2.8 190 0.261 8.01 3.1 J 7.8 1.6 J 3.0 J 101 46 2/19/14 4.3 1.8 1.4 0.099 J 0.351 120 0.067 J 0.231 0.461 1.11 0.351 0.961 0.571 0.054 J 0.053 J 1.9 J 7.8 J 9/9/14 8.3 2.9 1.6 4.0 120 0.089 J 0.241 1.2 1.8 J 0.601 0.90 JB 0.111 12 A 5.9 JB 2/25/15 6.4 2.3 1.6 6.1 B /*0.21 J 90 0.191 0.471 1.1 J 0.301 1.51 8.31 11/6/15 4.6 1.5 0.89 100 0.074 J 0.191 9.2 B 0.161 0.951 0.281 2.1 0.971 0.041 J 0.101 3.21 3/2/16 6.6 2.6 1.5 0.084 J 3.7 B 120 0.601 4.3 B 0.099 J 1.31 0.201 0.461 0.851 0.045 J 0.032 J 9.5 B, J/*4.3 J 9/21/16 8.8 2.7 1.8 0.79 0.13 J 150 0.281 0.651 0.241 7.7 0.211 1.31 0.621 0.023 J 0.050 J 8.21 2/7/17 5.0 1.4 0.90 0.471 99 0.151 0.571 0.221 0.801 0.321 0.901 0.791 0.111 1.11 4.0 J 8/23/17 9.6 3.0 1.7 140 0.201 0.771 0.31 B,1 1.31 0.099 J 1.21 0.601 0.101 17 3/15/18 1.8 0.83 0.70 BJ /*0.20 J 90 B /*80 0.054 J 0.481 0.082 J 1.1 0.060 J 59 13 B /*13 8/21/18 2.6 0.98 110 0.131 0.094 J 1.2 0.851 3.01 1.0 1.11 2.6 21 3/25/19 4.3 1.9 0.70 3.6 3.6 B /*<0.19 110 0.141 0.621 0.471 1.11 0.221 0.841 0.020 J 14 8/20/19 0.42 J 11 2.9 1.8 3.7 130 1.7 J 1.8 J 16 J 2/25/20 8.4 0.68 2.3 1.1 2.8 2.0 BJ 110 0.891 9/10/20 1.2 37 2/9/21 0.477 J 0.183 J 30.5 8/24/21 1.831 34.9 1.261 2/11/22 1 37.9 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Notes: Prepared By: GLH 2/25/22 1. VOCs - volatile organic compounds according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Metals according to EPA Method 6020, using EPA Method 3030C preparation Checked By: MAS 3/7/22 2. Concentrations are in micrograms per liter (Ng/L). 3. 2L GW Standard - 2L Groundwater Standard from 15A NCAC 2L, effective April 1, 2013 (including interim maximum allowable concentrations). EPA MCL - Envirommnetal Protection Agency's Maximum Contaminant Level, 4. NE - associated standard has not been established, 5. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents 6. Blank cells indicate constituent not detected in sample above the MDL. 7. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample 8. Bold concentrations indicate exceedance of 2L GW Standard or EPA MCL. 9. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit 10. '-' constituent not analyzed. Page 2 of 2 TABLE 7 Historical Surface Water Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals d e d d o >, s 0 `0 c e a >a v o s s O ' £ E C C O N T O £ E - 3 N CL = ? Monitoring Sample v e '� _ a R Yi+ 0/ a _ Location Date v Q d m r u a ri .. d > 14 c Q Q a m v CO m tr s u o u O u w � Z d v, W1 F > iV SW-1 2/2/12 0.75 6.2 1.8 0.68 - 0.59 JB 250 6.5 1.2 J 0.20 JB 1.2 J 1.0 0.23 J 33 3/2/16 1.1 0.19 J 3.8 B 260 0.41 J 4.3 B 2.2 5.0 J 3.3 3.3 0.78 J 0.039 J 0.11 J 1.2 J 19 B/*21 8/21/18 6.4 - 0.44 J 240 0.16 J 0.13 J 0.49 J 4.8 7.2 3.4 5.8 0.076 J 2.4 14 2/25/19 2.2 0.66 4.1 B /*<0.20 J 190 0.16 J 2.5 4.1 J 1.5 3.2 0.084 J 29 2/25/20 1.9 CCVU 2.8 0.77 2.1 2.0 BJ 260 3.9 5.11 2.0 4.3 20 2/9/21 1.2 0.542 3.43 J 3.93 0.443 J 309 0.207 J 6.8 7.46 J 3.66 5.57 19.1 J SW-2 8/3/11 2.0 0.96 1.1 - 0.23 J 250 1.0 12 1.2 J 0.080 J 1.7 J 1.0 0.064 J 0.30 J 0.67 J 12 2/2/12 1.4 0.57 0.46 JB 0.22 J 170 5.5 0.25 JB 0.95 J 0.69 J 0.19 J 13 8/28/12 2.2 0.78 0.48 J 220 5A JB 9.4 0.56 J 1.7 J 1.0 0.37 J 1.1 J 14 B 2/8/13 1.6 0.55 0.97 JB 170 1.7 B 4.4 0.77 J 1.2 J 0.79 J 0.025 J 20 9/4/13 2.5 0.84 180 8.5 0.51 J 26 2/19/14 1.8 0.62 0.43 J 160 0.12 J 5.6 0.16 J 1.1 J 0.78 J 0.056 J 13 9/9/14 2.7 1.1 4.4 200 0.070 J 10 0.95 J 0.12 J 1.2 JB 0.089 J 9.6 JA 9.1 JB 2/25/15 2.1 0.90 6.3 B /*0.22 J 170 8.0 0.92 J 0.30 J 1.1 J 0.70 J 0.082 J 4.2 J 5.7 J 11/6/15 3.3 1.2 0.31 J 200 0.041 J 3.0 B 8.8 0.59 J 0.25 J 1.5 J 0.97 J 0.038 J 6.9 J 3/2/16 1.4 0.092 J 3.0 B 140 0.36 J 4.0 B 3.1 0.72 J 0.14 J 0.49 J 0.63 J 0.028 J 0.026 J 15 B/*8.9 J 9/21/16 3.3 1.0 0.33 J 220 0.054 J 0.043 J 10 0.077 J 0.95 J 0.91 J 0.019 J 0.060 J 1.7 J 2/7/17 1.4 0.59 0.45 J 180 7.8 0.12 J 1.0 J 1.5 0.047 J 3.2 J 8/23/17 2.0 0.74 390 0.90 J 16 B 0.69 J 0.17 J 2.2 0.48 J 0.069 J 17 3/15/18 1.1 0.90 BJ /*0.29 J 180 B /*170 4.1 4.0 J 0.24 J 1.1 J 18 B /*14 8/21/18 8.1 2.0 0.57 460 0.16 J 0.10 J 0.97 17.0 2.7 J 1.4 3.0 1.1 19 2/25/19 0.80 4.1 B /*<0.19 110 2.0 1.0 J 0.14 J 1.2 J 0.022 J 19 8/20/19 3A J 3.1 0.84 5.0 190 10 1.6 J 17 J 2/25/20 1.5 0.51 1.8 J 2.0 BJ 130 3.3 1.2 J 14 J 9/10/20 0.37 J 3.6 0.94 3.0 0.18 J 170 8.6 1.3 J 2/9/21 0.202 J 2.48 0.621 2.3 0.251 J 140 5.4 0.9151 8/24/21 3.64 0.965 1.91 J 162 6.9 1.10 J 2/11/22 3.22 J 0.234 J 2.61 0.671 1.641 128 4.36 0.877 J NCSW Standard - 340 65 0.82 3.6 14 140 0.30 36 NE NE NE NE NE NE NE NE NE NE NE NE 5(t) NE NE Freshwater Aquatic Life (acute) (acute) (acute)** (acute)** (actute)** (acute)** (acute)** (acute)** NCSW Standard - NE 51 NE NE NE NE 2A NE NE 10 (t) NE NE NE NE NE NE NE NE NE NE NE NE NE Human Health EPA NRWQ - NE NE 800 900 NE NE NE NE 640 NE NE NE NE NE NE NE NE 4,600 4,200 NE NE NE NE Human Health NCISTV - Freshwater 16 2,000 NE 140 100 NE 110,000 NE NE NE NE 21,000 NE NE NE NE NE NE NE NE NE NE NE Aquatic Life (acute) NCISTV - Human Health 1,100,000 1 NE I NE I NE 1 720 1 110,000 1 NE 80 5,300 NE 1 200,000 (t) I NE I NE I NE 4 NE I NE I NE NE NE 2 NE NE Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-diozane analyzed via EPA Method 8260E SIM. Metals anlyzed according to EPA Method 6020, using EPA Method 3030C preparation 2. Concentrations are in micrograms per liter (pg/L). 3. NCSW Standard - North Carolina Surface Water Standards from 15A NCAC 2B (table dated July 26, 2021); a = acute Prepared By: GLH 2/25/22 4. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. Checked By: MAS 3/7/22 5. NCISTV - North Carolina In -Stream Target Values from table dated July 26, 2021 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. Blank cells indicate constituent not detected in sample above the MDL. 9. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample; CCVL- continuing calibration verification result is below control limits, but within method parameters, and a standard at or below the reporting limit was analyzed and found acceptable 10. Bold concentrations indicate exceedance of a Surface Water Standard. 11. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit 12. - indicates not analyzed. 13. ** A hardness of 25 milligrams per liter was assumed to calculate the standard. 14. t - based upon measurement of total recoverable metal. February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 FIGURES � f a� SI- 4F O , tiOt r91• "••.. � ?a: , � � Q 'r� r 1A S Grand 0a5m Ln . �6t yhl�Qm $ 5 %N#1,jKCM7,kK1j, Rd ddw 00 • ? tw e9 ee Qp er P C iA 6 vi I .e �F4e-, 5�I to lg Rd Y RacRy fact x mo LghtEFL a rr A`eps d • 1.ffi sd o G f y Vn - Ash Branch loc Davis Rd -_ n S7C13rCR4 Ra The map shown here has been created r. of with all due and reasonable care and is - p a strictly for use with Wood project 6252-15-0221. Wood assumes no liability, %1 S ` direct or indirect, whatsoever or any rya& such third party or unintended use. 3 IiA �h N G �' �7 At /, Wa /�E y r tiro xd tV 7ipi71f i . 0 500 1,000 LL •.:�� te�fr Feet Q V 79W nJ^Gilnr Him 14M1nson j- . C YnardriNQ� � 1 RIQy' 9takle r � g" 1 s - nail - CV�/pNhfa uy 2 Qf 4ep yC l Ir7ts �G a to7i �L _ i't�SV ce Chil_ dl A K/. � r�iilr ' SL',i rfr ri l.�,r r� R Wail hinL, Rq O a •] r. Tuckase e ©OpenStreetMap (and) ���` 9 contributors, CC -BY -SA, Sources: Esri, HERE, Garmin, Intermap, increment P Corp., GEBCO, USGS, FAO, NPS, NRCAN, GeoBase, IGN, Kadaster NL, Ordnance f Sources: Esri, HERE, Garmin, Survey, Esri Japan; METI, Esri China (Hong Kong), swisstopo, © OpenStreetMap contributors, and, lhe,GIS User Community TITLE: TOPOGRAPHIC SITE MAP PREPARED BY: G. HUTCHINS DATE: 3/9/2022 PROJECT NUMBER: 6252-15-0221 Figure No. Although every effort has been made to ensure the accuracy of information, errors and conditions originating from the physical CHECKED BY: M. WALLACE MAP PROJECTION: NC State Plane (NAD83, feet) W C U CLOSED LANDFILL sources used to develop the database may be reflected in the data supplied. The requestor must be aware of data conditions and DATE: 3/9/2022 wooultimately bear responsibility for the appropriate use of the information with respect to Possible errors, original map scale. collection M O N T E I T H GAP ROAD methodology, currency of data, and other conditions specific to certain data. Document Path: P:\Western Carolina University\GIS\Topo 2021.mxd CULLOWHEE, NORTH CAROLINA February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 4 0,191 KI_1 LANDFILL GAS MONITORING DATA FORM NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Facility Name: Western Carolina University - MSWLF Number: 50-01 Sampling Date: 2_/f[-) I ZZ NC Landfill Rule (.0500 or.1600):.0500 Sample Collector Name & Position: CfC , � ` Gas Meter Type & Serial Number66M5Q 5 a� 5017 > 5- Gas Meter Calibration Date: G —o Z z— Field Calibration Date & Time: Field Calibration Gas Type (15/15 or 35/50): 15/15 Field Calibration Gas Canister Expiration Date: Z f a Gas Meter Pump Rate: �• �!-rl Ambient Air Temperature: Barometric Pressure ( or mm Hg) Z Weather Conditions: Instructions: Under "Location or LFG Well", list monitoring well # or describe monitoring location (e.g., inside field office). Attach a test location map or drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % CH4 (by volume) to %LEL as follows: % methane (by volume)120 = % LEL. *Hydrogen Sulfide (H2S) gas monitoring may be required for Construction & Demolition Landfills (CDLFs). See individual permit conditions and/or Facility LFG monitoring plan. Location or LFG Well I❑ S ample Tube Purge Time of Day Time pumped (sec) Initial % LEL Stabilized LEL % % CH4 (volume) volume ado 02 (volume) % CO2 (volume) % H2s* (volume) NOTES Background �p U 1,05 6C2 0 Q (9 U (]-0 C2 LG-1 p I L', K4 %v 0 Q 1 06 S �_ a 0 LG-2 60 u-. 3 0 (`� o (90 (�f " 1-0 0 LG-3S co (9'o 11-0 o� LG-3D � ) L qO 60 C2 d Q -� ``-'� �-t. � LG-4 r (_7 1�.I C�JC 0 [toS (+- 0 LG-5 0 LG-6 r(� �� 6 C) 0 00 LG-7 &0 1b,2 J 60 C) C-) 0: 0 fq.G Z. 0 NOTE: Ifneeded, attach additional data forms to inchide additional LFG monitoring data locations for the facility. ACTION LEVELS: Methane: >1.25% by volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen 5ulflde: >1%by volume (inside structures) AND >4%by volume (at facility boundary) Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibili o a fine and imprisonment. a �e 55 TITLE Revised— March 6, 2017 301 Brushton Ave Suite A FIELD ENVIRONMENTAL Pittsburgh, PA 15221 A INSTRVM✓ NTES7Ir /NCs LToll ocal Free (8 0) 009 26 0 www.fieldenvironmetital.com Fax (412) 436-2616 Landtee Landfill Meter Calibration Certificate Fresh Air Oxygen Cal Standard Methane Carbon Dioxide 15% V I Cal Standard Carbon Monoxide 50 ppm Hydrogen Sulfide 25ppm .. Model S/N Bareode Order # 'GEM-5000+ W G_501735 U74437X 477443 Reading % Acceptable Range 20.9 (20.65% - 21.15%) Lot # Expiration 20-7457 9/28/2024 Reading % Acceptable Rangc 15.0 (14.7%- 15.3%) V Reading % Acceptable Range 15.0 (14.5% 155%) Lot # Expiration 20-7481 9/28/2022 Reading % Acceptable Range 50.0 (51 - 49) Reading % Acceptable Range 25.0 (24 26)... Calibrated By '..... Matthew Fennimore W Date of Calibration 1 02/08/22 All calibrations performed by Field Environmental Instruments conform to manufacturer's specifications. All calibration gas used is traceable to NIST. Additional documentation is available upon request. February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 /_1»401191E41:3 GROUNDWATER SAMPLING LOGS FIELD INSTRUMENT CALIBRATION RECORD Project Name: Western Carolina University -Closed MSWLF Date: Project Number: 6252-15-0221.07 Name: C y)� j c 1, Water Quality Meter Calibration Standard Value Meter Value Acceptance Criteria Manufacturer: H o 7 i t3 A pH: L4,0 SU (low) pH: 4, 0 C) SU +/- 10% of standard Model No.: U—'5a pH: SU (mad) pH: SU +/- 10% of standard `` Unit ID: fb 41./t/� pH: SU (high) pH: SU +/- 10% of standard Conductivity: 4, c4 61 mS/cm Conductivity: C- -' mS/cm +/- 10% of standard Thermometer Temperature: C. Temperature: Co 2.0 C° Turbidity Meter Calibration Standard Value Meter Value Acceptance Criteria Manufacturer: [ �(9 Il l�� U ` NTU (low) D NTU +/-10% of standard Model No.: �/' NTU (mad) NTU +/-10% of standard P // Unit ID: V CI V OG-) ` (C V NTU (high) NTU +/- 10% of standard - NTU (high) NTU +/- 10% of standard Photoionization Detector Acceptance Criteria Manufacturer: Background: ppmv Meter: ppmv within 5 ppmv of Zero Model No.: Span Gas: ppmv Meter: ppmv +/-10% of standard Unit ID: Calibration Sources 4, Ct l Source Value Lot Number Expiration Date pH (low) O SU �10 pH (mad) SU pH (high) SU Conductivity I,[a� . 1.�f`1 mS/cm /< <r r/,� Turbidity (low) fin (? (hcti, (9- 0 NTU r/ r Turbidity (mod): NTU Turbidity (high): NTU Turbidity (high): NTU PID gas: ppmv Other: NOTES: If a meter reading is not within acceptance criteria, clean or replace probe and re -calibrate, or use a different meter if available. If project requirements necessitate use of the Instrument, clearly document on all data sheets and log book entries that the parameter was not calibrated to the acceptance criteria. 301 Brushton Ave Suite A FIELD �E�NVIRt��►rNMENTAL Pittsburgh, PA 5221 INS/RVMEWTi7, INCr Loll Fee (8 0) 93-4 09 00 www.fieldenvironmental.com Fax (412) 436-2616 Lot # Expiration Horiba Auto -Cal Solution 8009590 10/9/2022 Cal Standard Reading Acceptable Range PH 4 a, 25` 4.00 (3.96 - 4.04) Cal Standard Reading ins/cm Acceptable Range Conductivity 4.26 1 (4.31 - 4.58) Cal Standard Readin NTU Acceptable Range Turbidity 0 NTU 0. 1 (-2 - +2) 100 NTU 100.0 (95 - 105) 71 Dissolved Oxygen Reading mg/L 100% Saturation 10.75 0% Saturation 0.00 Cal Standard Lot # Expiration Reading Acceptable Range PII 7 @ 25` 8009698 10/14/2022 1 7.00 1 (6.93 - 7.07) Cal Standard Lot # Expiration Reading Acceptable Range PI -I 10 @ 25` 8009500 10/7/2022 10.00 (9.9 - 10.1) Check Standard Temp ` Relative Reading Acceptable Range ORP 20.4 220.0 (+/- 15mV) *Solutions provided by LabChem (412-826-5230) ❑✓ ORP pin in place Model S/N Sonde Barcode Order # U-52-2 T P64RNYOG 90958 U90335X 477445 Calibrated By Glenn Turner Date of Calibration 1 2/9/2022 All calibrations performed by FEI conform to manufacturer's specifications. Please report any issues within 24 hours of receiving equipment. All calibration solutions used are traceable to NIST. Additional documentation is available upon request. FIELD DATA RECORD - GROUNDWATER SAMPLING PROJECT Western Carolina Universily MSWLF JOB NUMBER 6228.22.0027 WELL/ NUMBER QC SAMPLES COLLECTED ASSOCIATED TRIP BLANK DATE TIME ��•��/ WATER LEVEL / PUMP DATA PUMP TYPE INITIAL ) r^'� FINAL 0 Peristaltic DTW^i'„ J ft (tocJ DTW 3. ft (toc)llZI SCREENEn // t r� q ""Variable -speed submersible INTERVAL ° a "1 J.Z(vJ ft (bgs) NTA EOF '�"•C7 ( k (toc) Q Bladder AMOUNT PURGED PURGE DATA TIME DTW (fa) PURGE RATE (L/min) TEMP (C°) SPECIFIC CONDUCTIVITY (mS/cm) pH DO (mg/L) TURBIDITY (NTU) ORP (MV) COMMENTS 41142k —46 2.zu k1. 45 .v2. III. e .2 i% -z:7- 7f �° i7.G�1 v. 6Ge1 W -1 a zei 1"50 ILK 12,5-7 +J071 6.Z6 e;3I Zip- -L61 o. 014- o.v z C 5.1 a, z t t Zq 8 10) n 7z,(k 1 ,© 1 0 &C40 1 z-1t 10,E9 0'2 4 v.-3 �Z.`1 1(90 ANALYSES: NOTES: Appendix I VOCs via 8260, 1-4-Dioxane via 8260 SIM, Appendix I Metals via 6020 SIGNATURE: FIELD DATA RECORD - GROUNDWATER SAMPLING PROJECT I Western Carolina UniversitylVISWILF - JOB NUMBER 6228.22.0027 WELL/ NUMBER I ml%.1/_ D' I QC SAMPLES COLLECTED I AM ASSOCIATED TRIP BLANK 1 r) --- r DATE L L TIME WATER LEVEL / PUMP DATA PUMP TYPE INITIAL �S5 FINAL Q Peristaltic DTW a+ O5 ft(toc) DTW 3t. �i ft (toc) � �Variable-speed submersible SCREENED �!r DEPTH O99 F INTERVAL INTAKE �'�(7. k(toc) 0 Bladder AMOUNT PURGED PURGE DATA TIME DTW 011 PURGE RATE (L/min) TEMP (C°) SPECIFIC CONDUCTIVITY (mS/cm) PH DO (mg/L) TURBIDITY (NTU) ORP (mV) COMMENTS (D 4.q 3.� ��.3 1"13 I , 3 32,2 .7 6'7- q t - 9 0 I,Ctq 5q a 2 0 11 '43 (,qo 1 Z: a 3 .8 L0 ZG. Cr:�l-. L.G 12.E -3� ` ,71 1,73 i `� 2fb t; 1 3f,61 IZ a ®,[� j3 [.61 16. ( - -58 rr:5' 31,�o I2 �0 ®, 17-1 ' I 1�, 6 r ,5 31,53 2,S® o.� �- q85 1Zp3 3t 5l I� �, [z q-16 t. to I tz;tl It,y i IL& 0.1T5 61>7(1 1,3� a,q Zi IZ;rS .6 12 6 0-12- (a f. �� �'. b 273 ANALYSES: NOTES: Appendix I VOCs via 826Q 1-4-Dioxane via 8260 SIM, Appendix I Metals via 6020 SIGNATURE- FIELD DATA RECORD - GROUNDWATER SAMPLING PROJECT Western Carolina Universitv MSWLF JOB NUMBER 6228.22.0027 DATE WELL/ NUMBER l/ �' TIME QC SAMPLES COLLECTED (j I I �rJ' ASSOCIATED TRIP BLANK WATER LEVEL / PUMP DATA PUMP TYPE AMOUNT PURGED INITIAL �• FINAL 0 Peristaltic DTW Y r5 ftitoc) DTW F=J�adable-speed submersible SCREENED / 7 DEPTH OF ^� }7�" . INTERVAL 63,2� ft(bgs) INTAKE ' _ / ft(toc) 0 Bladder PURGE DATA TIME DTW 00 PURGE RATE (L/min) TEMP (C°) SPECIFIC CONDUCTIVITY (mS/cm) PH DO (mg/L) TURBIDITY (NTU) ORP (mv) COMMENTS l ,,I2S5,1 i. 1.0 iLio 5,-2 2zz- 7®,5 -z8 lq Q oo oo. I3 C 0,443 5-21 o.00 6 13 : 24- > l v 1 k 50 19 c. (® 71 213 O oO 6 q r ,ate)sz4. 1 1415 o,q31 .z(o aoo �, & I 14:2 3 D 43 8 5-3q- o- oo 73_ `3 5 3;36 155Z5 1 K ®q37 5=111 0-00 3. 1 C-T.11 I K �Z4 p .ctl 5-55 D.o c�- 044 5-3, z� irE 2 O 43 m o o 2. 4-,7 ANALYSES: Appendix I VOCs via 8260, 1-4-Dioxane via 8260 SIM, Appendix[ Metals via 6020 NOTES: SIGNATURE!'; ' _- -- FIELD DATA RECORD - GROUNDWATER SAMPLING PROJECT Western Carolina University MSWLF I JOB NUMBER 6228.22.0027 WELL / SAMPLE NUMBER (" ��^�" �4 QC SAMPLES COLLECTED ASSOCIATED TRIP BLANK-F�--� DATE 2 2 TIME WATER LEVEL / PUMP DATA PUMP TYPE INITIAL / FINAL I N Peristaltic DTW �,ft (toc) DTW ,} ft (toc) •i' Variable -speed submersible SCREENED DEPTH OF ((�� INTERVAL Z (.� ft (bgs) INTAKE n�' K7 ft (toc) 0 Bladder AMOUNT PURGED �` gal. PURGE DATA TIME DTW tfo> PURGE RATE (L/min) TEMP (C°) SPECIFIC CONDUCTIVITY (mS/cm) PH DO (m /L) TURBIDITY (NTU) ORP (mV) COMMENTS t,ab .(rod 1 16,800,141 6.zv 5 14 C4 0 2 too 143 1 0, V�4. 627 2,� 1- 6 lob 1�1•fit 25 F�. ii.(00 0114& 6.11 6 4 5 lG.�i� �'Zt3 1�.40 (�• 14�I. 6.v� 1, 1 �- , � 143 0.103 t'5,12- p. 14 j s`i v (.sty 3. 2 � v C2. (2, ANALYSES: NOTES: Appendix I VOCs via 8260, 1-4-Dioxane via 8260 SIM, Appendix I Metals via 6020 SIGNATURFC FIELD DATA RECORD - GROUNDWATER SAMPLING PROJECT Western Carolina UniversitV MSWLF JOB NUMBER 6228.22.0027 WELL/ NUMBER QC SAMPLES COLLECTED A11114 ASSOCIATED TRIP BLANK DATE l u TIME WATER LEVEL / PUMP D k —•_, INITIAL FIf DTW ft(toc) DTW SCREENED DEPTH OF -_F INTERVAL _. _ix(h s}-_ _INTAKE �—�"�^ PUMP TYPE O Peristaltic -ft{tec Q:»ad e�s earl submersible ft(toc) ��"� Bladder AMOUNT PURGED PURGE DATA TIME DTW (ft) PURGE RATE (L/min) TEMP (C°) SPECIFIC CONDUCTIVITY (mS/cm) PH DO (m L) TURBIDITY (NTU) ORP (mV) COMMENTS ANALYSES: Appendix 1 VOCs via 8260, 1-4-Dioxane via 8260 SIM, Appendix I Metals via 6020 NOTES: SIGNATURE:C February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 APPENDIX C NCDEQ ENVIRONMENTAL MONITORING REPORTING FORM I -ENR USE ONLY []Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #: rTNC DENR "II III Environmental Monitoring Division of Waste Management - Solid Waste Reoortina Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit, • Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646_ Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Matthew Wallace Phone: 828-252-8130 E-mail: Matthew.Wailace@woodple.com Facility name: Facility Address: Western Carolina University Monteith Gap Road (State Road 1336) , MSW Landfill Cullowhee, Jackson County, NC 28723 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data Surface water monitorin NC Landfill Rule: Actual sampling dates (e.g„ Permit # (.0500 or .1600) October 20-24, 2006) February 10-11, 2022 Assessment Monitoring F1 Corrective Action ® Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? ® No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Q Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my nowledge, t e in ormation reported an —statements made on this data submittal and a chmen s are true and correct. Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Matthew Wallace, PE Principal Engineer F4iMty Representative Name (print) _ _ Title ID3)?-mot )V2'L Date 1308 Patton Avenue, Asheville, NC 28806 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 62000 (828)252-8130 Geologist Seal V ViV. J, : 24933 � �3�2y 17,�,tiG a p�rrUt 1ICI111114>> February 2022 Water Quality and Landfill Gas Monitoring Report March 24, 2022 WCU Closed MSWLF Wood Project 6252-15-0227 /_1»4►1971:41191 LABORATORY ANALYTICAL REPORT Waypointo ANALYTICAL 2/23/2022 Wood Environ. & Infrastructure Inc (Asheville) Gregory Hutchins 1308 Patton Avenue (Suite C) Asheville, NC, 28806 Ref: Analytical Testing Lab Report Number: 22-045-0001 Client Project Description: WCU MSWLF Dear Gregory Hutchins: 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Waypoint Analytical, LLC (Charlotte) received sample(s) on 2/12/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, a'-1 Angela D Overcash Senior Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 49 Waypoint.0 ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom Certification Summary Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC State Program Lab ID Expiration Date North Carolina State Program 37735 07/31/2022 North Carolina State Program 402 12/31/2022 South Carolina State Program 99012 07/31/2022 South Carolina State Program 99012 12/31/2021 Page 1 of 1 00016/22-045-0001 Page 2 of 49 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Sample Summary Table Report Number: 22-045-0001 Client Project Description: WCU MSWLF Lab No Client Sample ID Matrix Date Collected Date Received 94073 TB-1 Aqueous 02/11/2022 02/12/2022 12:25 94075 FD-1 Aqueous 02/11/2022 02/12/2022 12:25 94076 MW-1 Aqueous 02/11/2022 10:20 02/12/2022 12:25 94077 MW-2 Aqueous 02/11/2022 12:15 02/12/2022 12:25 94078 EB-1 Aqueous 02/11/2022 12:30 02/12/2022 12:25 94079 MW-3 Aqueous 02/11/2022 13:50 02/12/2022 12:25 94080 MW-4 Aqueous 02/11/2022 14:55 02/12/2022 12:25 94081 SW-2 Aqueous 02/11/2022 15:00 02/12/2022 12:25 Page 3 of 49 Waypoint (D 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytica l.com Summary of Detected Analytes Project: WCU MSWLF Report Number: 22-045-0001 Client Sample ID Method Lab Sample ID Parameters Result Units Report Limit Analyzed Qualifiers FD-1 V 94075 6020B Barium 113 pg/L 0.842 02/14/202215:07 6020E Cobalt 14.2 Ng/L 0.543 02/14/202215:07 6020E Nickel 3.19 pg/L 0.532 02/17/2022 21:17 8260D Acetone 12.3 Ng/L 1.80 02/16/202217:35 8260D Benzene 0.630 pg/L 0.180 02/16/202217:35 8260D Chlorobenzene 15.1 Ng/L 0.190 02/16/202217:35 8260D 1,2-Dichlorobenzene 0.267 pg/L 0.220 02/16/202217:35 J 8260D 1,4-Dichlorobenzene 3.20 Ng/L 0.210 02/16/202217:35 8260D cis- 1,2-Dichloroethene 1.71 pg/L 0.200 02/16/202217:35 8260D SIM 1,4-Dioxane 1.29 Ng/L 0.139 02/14/2022 12:56 J MW-1 V 94076 6020E Barium 36.6 pg/L 0.834 02/14/202215:14 6020E Chromium 4.16 Ng/L 0.813 02/14/202215:14 6020E Cobalt 0.776 pg/L 0.535 02/14/202215:14 J 6020E Lead 0.345 Ng/L 0.268 02/17/2022 21:23 J 6020E Nickel 2.74 pg/L 0.525 02/17/2022 21:23 J 6020E Vanadium 1.45 Ng/L 1.34 02/17/2022 21:23 J 8260D Acetone 2.25 pg/L 1.80 02/16/202215:07 J MW-2 V 94077 6020E Barium 83.6 Ng/L 0.842 02/14/202215:20 6020E Chromium 1.60 pg/L 0.817 02/14/202215:20 J 6020E Cobalt 0.949 Ng/L 0.538 02/14/202215:20 J 6020E Nickel 1.43 pg/L 0.529 02/17/2022 21:30 J 6020E Vanadium 1.96 Ng/L 1.35 02/17/2022 21:30 J 8260D Acetone 2.35 pg/L 1.80 02/16/202215:32 J EB-1 V 94078 6020B Barium 4.18 Ng/L 0.842 02/14/202215:27 J 6020B Copper 9.26 pg/L 3.95 02/14/202215:27 J 6020B Nickel 0.652 Ng/L 0.529 02/17/2022 21:36 J 6020B Zinc 8.82 pg/L 7.14 02/17/2022 21:36 J MW-3 V 94079 6020B Barium 111 Ng/L 0.842 02/14/202215:01 6020B Cobalt 14.0 pg/L 0.538 02/14/202215:01 6020B Nickel 3.28 Ng/L 0.529 02/17/2022 20:44 Page 4 of 49 Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointana lyti ca I som Summary of Detected Analytes Project: WCU MSWLF Report Number: 22-045-0001 Client Sample ID Lab Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers MW-3 V 94079 8260D Benzene 0.636 pq/L 0.180 02/16/202216:21 8260D Chlorobenzene 15.4 Ng/L 0.190 02/16/202216:21 8260D 1,2-Dichlorobenzene 0.323 uq/L 0.220 02/16/202216:21 J 8260D 1,4-Dichlorobenzene 3.16 Ng/L 0.210 02/16/202216:21 8260D cis-1,2-Dichloroethene 1.73 pq/L 0.200 02/16/202216:21 MW-4 V 94080 6020B Barium 37.9 Ng/L 0.842 02/14/202215:34 SW-2 V 94081 6020B Barium 128 pq/L 0.842 02/14/202215:40 6020B Cobalt 4.36 Ng/L 0.538 02/14/202215:40 6020B Nickel 0.877 uq/L 0.529 02/17/2022 22:03 J 8260D Acetone 3.22 Ng/L 1.80 02/16/202217:10 J 8260D Benzene 0.234 uq/L 0.180 02/16/202217:10 J 8260D Chlorobenzene 2.61 Ng/L 0.190 02/16/202217:10 8260D 1,4-Dichlorobenzene 0.671 uq/L 0.210 02/16/202217:10 8260D SIM 1,4-Dioxane 1.64 Ng/L 0.139 02/14/2022 15:27 J Page 5 of 49 Waypointo ANALYTICAL Client: Wood Environ. & Infrastructure Inc (Asheville) Project: WCU MSWLF Lab Report Number: 22-045-0001 Date: 2/23/2022 449 5pringbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Metals Analyses Method 6020B Analyte: Selenium QC Batch No: V15106/V14895 LLICV failed high. Sample concentration BRL or 10X concentration. Sample 94075 (FD-1) Analyte: Selenium QC Batch No: V15213/V14895 CCB failed high. Sample concentration BRL. Results not affected. Sample 94079 (MW-3) Analyte: Selenium QC Batch No: V15213/V14895 CCB failed high. Sample concentration BRL. Results not affected. CASE NARRATIVE Analyte: Thallium QC Batch No: V14952/V14895 This target analyte was flagged for recoveries outside QC limits in the associated LCS/LCSD. Data for this analyte is flagged "M" to indicate that results should be considered minimum concentration due to the potential for a low bias. Page 6 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94073 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/11/2022 0:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 12:31 TBL 8260D SIM Surrogate:4-Bromofluorobenzene 106 Limits:70-130% 1 02/14/2212:31 TBL V14908 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 7 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94073 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 02/16/22 13:28 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 13:28 JLB V15071 Benzene <0.180 Ng/L 0.180 0.500 1 02/16/22 13:28 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 13:28 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 13:28 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 13:28 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 13:28 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 13:28 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 13:28 JLB V15071 Chlorobenzene <0.190 ug/L 0.190 0.500 1 02/16/22 13:28 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 13:28 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 13:28 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 13:28 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 13:28 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 13:28 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 13:28 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 13:28 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 02/16/22 13:28 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 13:28 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 8 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94073 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 13:28 JLB V15071 1,2-Dichloroethane <0.150 pg/L 0.150 0.500 1 02/16/22 13:28 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 13:28 JLB V15071 cis- 1,2-Dich loroethene <0.200 pg/L 0.200 0.500 1 02/16/22 13:28 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 13:28 JLB V15071 1,2-Dichloropropane <0.190 pg/L 0.190 0.500 1 02/16/22 13:28 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 13:28 JLB V15071 trans-1,3-Dichloropropene <0.150 pg/L 0.150 0.500 1 02/16/22 13:28 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 13:28 JLB V15071 2-Hexanone <0.380 pg/L 0.380 5.00 1 02/16/22 13:28 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 13:28 JLB V15071 4-Methyl-2-Pentanone <1.00 pg/L 1.00 5.00 1 02/16/22 13:28 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 13:28 JLB V15071 Styrene <0.220 pg/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 13:28 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 pg/L 0.160 0.500 1 02/16/22 13:28 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 Tetrahydrofuran <1.50 pg/L 1.50 10.0 1 02/16/22 13:28 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 13:28 JLB V15071 1,1,1-Trichloroethane <0.160 pg/L 0.160 0.500 1 02/16/22 13:28 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 13:28 JLB V15071 Trichloroethene <0.180 pg/L 0.180 0.500 1 02/16/22 13:28 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 9 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94073 Matrix: Aqueous Sample ID: TB-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 u9/L 0.270 1.00 N9/L 1.00 2.00 u9/L 0.170 0.500 N9/L 0.210 0.500 u9/L 0.420 1.00 N9/L 0.210 0.500 104 Limits: 80-124% 101 Limits: 75-129% 98.0 Limits: 63-136% 99.6 Limits: 77-123% 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 1 02/16/22 13:28 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 10 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94075 Sample ID: FD-1 Matrix: Aqueous Sampled: 2/11/2022 0:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 1.293 Ng/L 0.139 2.00 1 02/14/22 12:56 TBL 8260D SIM Antimony <0.512 ug/L 0.512 2.09 1 02/17/22 21:17 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 21:17 EDV 6020B Barium 113 u9/L 0.842 10.4 1 02/14/2215:07 EDV 6020B Beryllium <0.198 N9/L 0.198 1.04 1 02/14/2215:07 EDV 6020B Cadmium <0.166 u9/L 0.166 1.04 1 02/14/2215:07 EDV 6020B Chromium <0.825 N9/L 0.825 2.09 1 02/14/2215:07 EDV 6020B Cobalt 14.2 u9/L 0.543 2.09 1 02/14/2215:07 EDV 6020B Copper <3.95 N9/L 3.95 10.4 1 02/14/2215:07 EDV 6020B Lead <0.270 u9/L 0.270 1.04 1 02/17/22 21:17 EDV 6020B Nickel 3.19 N9/L 0.532 3.13 1 02/17/22 21:17 EDV 6020B Selenium <2.40 u9/L 2.40 5.21 1 02/21/22 20:37 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/2215:07 EDV 6020B Thallium <0.596 u9/L 0.596 2.09 1 02/14/2215:07 EDV 6020B Vanadium <1.35 N9/L 1.35 5.21 1 02/17/22 21:17 EDV 6020B Zinc <7.21 ug/L 7.21 20.9 1 02/17/22 21:17 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 11 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94075 Matrix: Aqueous Sample ID: FD-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 12.3 Ng/L 1.80 5.00 1 02/16/22 17:35 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 17:35 JLB V15071 Benzene 0.630 Ng/L 0.180 0.500 1 02/16/22 17:35 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 17:35 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 17:35 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 17:35 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 17:35 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 17:35 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 17:35 JLB V15071 Chlorobenzene 15.1 ug/L 0.190 0.500 1 02/16/22 17:35 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 17:35 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 17:35 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 17:35 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 17:35 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 17:35 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 17:35 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 17:35 JLB V15071 1,2-Dichlorobenzene 0.2673 ug/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 1,4-Dichlorobenzene 3.20 Ng/L 0.210 0.500 1 02/16/22 17:35 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 17:35 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 12 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94075 Matrix: Aqueous Sample ID: FD-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 17:35 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 17:35 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 17:35 JLB V15071 cis- 1,2-Dich loroethene 1.71 ug/L 0.200 0.500 1 02/16/22 17:35 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 17:35 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 17:35 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 17:35 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 17:35 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 17:35 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 17:35 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 17:35 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 17:35 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 17:35 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 17:35 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 17:35 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 17:35 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 17:35 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 17:35 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 17:35 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 17:35 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 13 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94075 Matrix: Aqueous Sample ID: FD-1 Sampled: 2/11/2022 0:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 u9/L 0.270 1.00 N9/L 1.00 2.00 u9/L 0.170 0.500 N9/L 0.210 0.500 u9/L 0.420 1.00 N9/L 0.210 0.500 101 Limits: 80-124% 103 Limits: 75-129% 98.6 Limits: 63-136% 99.8 Limits: 77-123% 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 1 02/16/22 17:35 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 14 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94076 Sample ID: MW-1 Matrix: Aqueous Sampled: 2/11/2022 10:20 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 13:21 TBL 8260D SIM Antimony <0.505 u9/L 0.505 2.06 1 02/17/22 21:23 EDV 6020B Arsenic <0.175 Ng/L 0.175 1.03 1 02/17/22 21:23 EDV 6020E Barium 36.6 u9/L 0.834 10.3 1 02/14/2215:14 EDV 6020B Beryllium <0.196 Ng/L 0.196 1.03 1 02/14/2215:14 EDV 6020E Cadmium <0.165 u9/L 0.165 1.03 1 02/14/2215:14 EDV 6020B Chromium 4.16 Ng/L 0.813 2.06 1 02/14/2215:14 EDV 6020E Cobalt 0.7763 u9/L 0.535 2.06 1 02/14/22 15:14 EDV 6020B Copper <3.91 N9/L 3.91 10.3 1 02/14/2215:14 EDV 6020B Lead 0.345 J u9/L 0.268 1.03 1 02/17/22 21:23 EDV 6020B Nickel 2.743 N9/L 0.525 3.09 1 02/17/22 21:23 EDV 6020B Selenium <2.37 pg/L 2.37 5.15 1 02/22/2218:57 EDV 6020B Silver <0.113 N9/L 0.113 1.03 1 02/14/2215:14 EDV 6020B Thallium <0.587 pg/L 0.587 2.06 1 02/14/2215:14 EDV 6020B Vanadium 1.453 N9/L 1.34 5.15 1 02/17/22 21:23 EDV 6020B Zinc <7.11 ug/L 7.11 20.6 1 02/17/22 21:23 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 15 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94076 Matrix: Aqueous Sample ID: MW-1 Sampled: 2/11/2022 10:20 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.253 Ng/L 1.80 5.00 1 02/16/22 15:07 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 15:07 JLB V15071 Benzene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:07 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 15:07 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:07 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 15:07 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 15:07 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 15:07 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 15:07 JLB V15071 Chlorobenzene <0.190 ug/L 0.190 0.500 1 02/16/22 15:07 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 15:07 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 15:07 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 15:07 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 15:07 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 15:07 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 15:07 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 15:07 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:07 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 15:07 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 16 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94076 Matrix: Aqueous Sample ID: MW-1 Sampled: 2/11/2022 10:20 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 15:07 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 15:07 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 15:07 JLB V15071 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 02/16/22 15:07 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:07 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 15:07 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:07 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 15:07 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 15:07 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 15:07 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 15:07 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 15:07 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 15:07 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:07 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:07 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 15:07 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:07 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:07 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 15:07 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 15:07 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 17 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94076 Matrix: Aqueous Sample ID: MW-1 Sampled: 2/11/2022 10:20 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 103 Limits: 75-129% 100 Limits: 63-136% 100 Limits: 77-123% 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 1 02/16/22 15:07 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 18 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94077 Sample ID: MW-2 Matrix: Aqueous Sampled: 2/11/2022 12:15 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 13:46 TBL 8260D SIM Antimony <0.507 u9/L 0.507 2.07 1 02/17/22 21:30 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 21:30 EDV 6020E Barium 83.6 u9/L 0.842 10.4 1 02/14/22 15:20 EDV 6020B Beryllium <0.198 Ng/L 0.198 1.04 1 02/14/22 15:20 EDV 6020E Cadmium <0.166 u9/L 0.166 1.04 1 02/14/22 15:20 EDV 6020B Chromium 1.603 Ng/L 0.817 2.07 1 02/14/22 15:20 EDV 6020E Cobalt 0.9493 u9/L 0.538 2.07 1 02/14/22 15:20 EDV 6020B Copper <3.95 N9/L 3.95 10.4 1 02/14/22 15:20 EDV 6020B Lead <0.270 u9/L 0.270 1.04 1 02/17/22 21:30 EDV 6020B Nickel 1.433 N9/L 0.529 3.11 1 02/17/22 21:30 EDV 6020B Selenium <2.39 u9/L 2.39 5.19 1 02/22/2219:04 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/22 15:20 EDV 6020B Thallium <0.590 u9/L 0.590 2.07 1 02/14/22 15:20 EDV 6020B Vanadium 1.963 N9/L 1.35 5.19 1 02/17/22 21:30 EDV 6020B Zinc <7.14 ug/L 7.14 20.7 1 02/17/22 21:30 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 19 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94077 Matrix: Aqueous Sample ID: MW-2 Sampled: 2/11/2022 12:15 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 2.353 Ng/L 1.80 5.00 1 02/16/22 15:32 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 15:32 JLB V15071 Benzene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:32 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 15:32 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:32 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 15:32 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 15:32 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 15:32 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 15:32 JLB V15071 Chlorobenzene <0.190 ug/L 0.190 0.500 1 02/16/22 15:32 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 15:32 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 15:32 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 15:32 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 15:32 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 15:32 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 15:32 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 15:32 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:32 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 15:32 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 20 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94077 Matrix: Aqueous Sample ID: MW-2 Sampled: 2/11/2022 12:15 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 15:32 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 15:32 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 15:32 JLB V15071 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 02/16/22 15:32 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:32 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 15:32 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:32 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 15:32 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 15:32 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 15:32 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 15:32 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 15:32 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 15:32 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:32 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:32 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 15:32 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:32 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:32 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 15:32 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 15:32 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 21 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94077 Matrix: Aqueous Sample ID: MW-2 Sampled: 2/11/2022 12:15 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 u9/L 0.270 1.00 Ng/L 1.00 2.00 u9/L 0.170 0.500 Ng/L 0.210 0.500 u9/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 99.4 Limits: 75-129% 99.4 Limits: 63-136% 101 Limits: 77-123% 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 1 02/16/22 15:32 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 22 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94078 Sample ID : EB-1 Matrix: Aqueous Sampled: 2/11/2022 12:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 14:12 TBL 8260D SIM Antimony <0.507 u9/L 0.507 2.07 1 02/17/22 21:36 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 21:36 EDV 6020E Barium 4.183 u9/L 0.842 10.4 1 02/14/22 15:27 EDV 6020B Beryllium <0.198 Ng/L 0.198 1.04 1 02/14/22 15:27 EDV 6020E Cadmium <0.166 u9/L 0.166 1.04 1 02/14/22 15:27 EDV 6020B Chromium <0.817 Ng/L 0.817 2.07 1 02/14/22 15:27 EDV 6020E Cobalt <0.538 ug/L 0.538 2.07 1 02/14/22 15:27 EDV 6020B Copper 9.263 N9/L 3.95 10.4 1 02/14/22 15:27 EDV 6020E Lead <0.270 u9/L 0.270 1.04 1 02/17/22 21:36 EDV 6020B Nickel 0.6523 N9/L 0.529 3.11 1 02/17/22 21:36 EDV 6020B Selenium <2.38 u9/L 2.38 5.18 1 02/22/2219:23 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/22 15:27 EDV 6020B Thallium <0.590 u9/L 0.590 2.07 1 02/14/22 15:27 EDV 6020B Vanadium <1.35 N9/L 1.35 5.18 1 02/17/22 21:36 EDV 6020B Zinc 8.82 J ug/L 7.14 20.7 1 02/17/22 21:36 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 23 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94078 Matrix: Aqueous Sample ID : EB-1 Sampled: 2/11/2022 12:30 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 02/16/22 15:56 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 15:56 JLB V15071 Benzene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:56 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 15:56 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:56 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 15:56 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 15:56 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 15:56 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 15:56 JLB V15071 Chlorobenzene <0.190 ug/L 0.190 0.500 1 02/16/22 15:56 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 15:56 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 15:56 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 15:56 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 15:56 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 15:56 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 15:56 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 15:56 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:56 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 15:56 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 24 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94078 Matrix: Aqueous Sample ID : EB-1 Sampled: 2/11/2022 12:30 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 15:56 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 15:56 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 15:56 JLB V15071 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 02/16/22 15:56 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 15:56 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 15:56 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 15:56 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 15:56 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 15:56 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 15:56 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 15:56 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 15:56 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 15:56 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 15:56 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:56 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 15:56 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 15:56 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 15:56 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 15:56 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 15:56 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 25 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94078 Matrix: Aqueous Sample ID : EB-1 Sampled: 2/11/2022 12:30 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 u9/L 0.270 1.00 N9/L 1.00 2.00 u9/L 0.170 0.500 N9/L 0.210 0.500 u9/L 0.420 1.00 N9/L 0.210 0.500 106 Limits: 80-124% 102 Limits: 75-129% 99.6 Limits: 63-136% 100 Limits: 77-123% 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 1 02/16/22 15:56 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 26 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94079 Sample ID: MW-3 Matrix: Aqueous Sampled: 2/11/2022 13:50 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 14:37 TBL 8260D SIM Antimony <0.507 ug/L 0.507 2.07 1 02/17/22 20:44 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 20:44 EDV 6020E Barium ill ug/L 0.842 10.4 1 02/14/2215:01 EDV 6020B Beryllium <0.198 Ng/L 0.198 1.04 1 02/14/2215:01 EDV 6020E Cadmium <0.166 u9/L 0.166 1.04 1 02/14/2215:01 EDV 6020B Chromium <0.817 N9/L 0.817 2.07 1 02/14/2215:01 EDV 6020E Cobalt 14.0 u9/L 0.538 2.07 1 02/14/2215:01 EDV 6020B Copper <3.95 N9/L 3.95 10.4 1 02/14/2215:01 EDV 6020E Lead <0.270 u9/L 0.270 1.04 1 02/17/22 20:44 EDV 6020B Nickel 3.28 N9/L 0.529 3.11 1 02/17/22 20:44 EDV 6020E Selenium <2.39 u9/L 2.39 5.19 1 02/21/22 20:31 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/2215:01 EDV 6020E Thallium <0.590 u9/L 0.590 2.07 1 02/14/2215:01 EDV 6020B Vanadium <1.35 N9/L 1.35 5.19 1 02/17/22 20:44 EDV 6020B Zinc <7.14 ug/L 7.14 20.7 1 02/17/22 20:44 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 27 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94079 Matrix: Aqueous Sample ID: MW-3 Sampled: 2/11/2022 13:50 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 02/16/22 16:21 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 16:21 JLB V15071 Benzene 0.636 Ng/L 0.180 0.500 1 02/16/22 16:21 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 16:21 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 16:21 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 16:21 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 16:21 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 16:21 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 16:21 JLB V15071 Chlorobenzene 15.4 ug/L 0.190 0.500 1 02/16/22 16:21 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 16:21 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 16:21 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 16:21 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 16:21 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 16:21 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 16:21 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 16:21 JLB V15071 1,2-Dichlorobenzene 0.3233 ug/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 1,4-Dichlorobenzene 3.16 Ng/L 0.210 0.500 1 02/16/22 16:21 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 16:21 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 28 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94079 Matrix: Aqueous Sample ID: MW-3 Sampled: 2/11/2022 13:50 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 16:21 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 16:21 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 16:21 JLB V15071 cis- 1,2-Dich loroethene 1.73 ug/L 0.200 0.500 1 02/16/22 16:21 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 16:21 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 16:21 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 16:21 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 16:21 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 16:21 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 16:21 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 16:21 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 16:21 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 16:21 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 16:21 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 16:21 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 16:21 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 16:21 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 16:21 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 16:21 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 16:21 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 29 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94079 Matrix: Aqueous Sample ID: MW-3 Sampled: 2/11/2022 13:50 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 u9/L 0.270 1.00 N9/L 1.00 2.00 u9/L 0.170 0.500 N9/L 0.210 0.500 u9/L 0.420 1.00 N9/L 0.210 0.500 102 Limits: 80-124% 101 Limits: 75-129% 101 Limits: 63-136% 99.4 Limits: 77-123% 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 1 02/16/22 16:21 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 30 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94080 Sample ID: MW-4 Matrix: Aqueous Sampled: 2/11/2022 14:55 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane <0.139 Ng/L 0.139 2.00 1 02/14/22 15:02 TBL 8260D SIM Antimony <0.507 ug/L 0.507 2.07 1 02/17/22 21:56 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 21:56 EDV 6020E Barium 37.9 u9/L 0.842 10.4 1 02/14/2215:34 EDV 6020B Beryllium <0.198 Ng/L 0.198 1.04 1 02/14/2215:34 EDV 6020E Cadmium <0.166 u9/L 0.166 1.04 1 02/14/2215:34 EDV 6020B Chromium <0.817 Ng/L 0.817 2.07 1 02/14/2215:34 EDV 6020E Cobalt <0.538 ug/L 0.538 2.07 1 02/14/2215:34 EDV 6020B Copper <3.95 N9/L 3.95 10.4 1 02/14/2215:34 EDV 6020E Lead <0.270 u9/L 0.270 1.04 1 02/17/22 21:56 EDV 6020B Nickel <0.529 N9/L 0.529 3.11 1 02/17/22 21:56 EDV 6020E Selenium <2.38 u9/L 2.38 5.18 1 02/22/2219:36 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/2215:34 EDV 6020E Thallium <0.590 u9/L 0.590 2.07 1 02/14/2215:34 EDV 6020B Vanadium <1.35 N9/L 1.35 5.18 1 02/17/22 21:56 EDV 6020B Zinc <7.14 ug/L 7.14 20.7 1 02/17/22 21:56 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 31 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94080 Matrix: Aqueous Sample ID: MW-4 Sampled: 2/11/2022 14:55 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone <1.80 Ng/L 1.80 5.00 1 02/16/22 16:46 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 16:46 JLB V15071 Benzene <0.180 Ng/L 0.180 0.500 1 02/16/22 16:46 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 16:46 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 16:46 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 16:46 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 16:46 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 16:46 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 16:46 JLB V15071 Chlorobenzene <0.190 ug/L 0.190 0.500 1 02/16/22 16:46 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 16:46 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 16:46 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 16:46 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 16:46 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 16:46 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 16:46 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 16:46 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 1,4-Dichlorobenzene <0.210 Ng/L 0.210 0.500 1 02/16/22 16:46 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 16:46 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 32 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94080 Matrix: Aqueous Sample ID: MW-4 Sampled: 2/11/2022 14:55 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 16:46 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 16:46 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 16:46 JLB V15071 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 02/16/22 16:46 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 16:46 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 16:46 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 16:46 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 16:46 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 16:46 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 16:46 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 16:46 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 16:46 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 16:46 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 16:46 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 16:46 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 16:46 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 16:46 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 16:46 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 16:46 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 16:46 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 33 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94080 Matrix: Aqueous Sample ID: MW-4 Sampled: 2/11/2022 14:55 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 102 Limits: 80-124% 101 Limits: 75-129% 100 Limits: 63-136% 101 Limits: 77-123% 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 1 02/16/22 16:46 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 34 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Number : 22-045-0001 REPOR T OF A NA L YSIS Report Date : 02/23/2022 Received : 02/12/2022 Lab No : 94081 Sample ID: SW-2 Matrix: Aqueous Sampled: 2/11/2022 15:00 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method 1,4-Dioxane 1.643 Ng/L 0.139 2.00 1 02/14/22 15:27 TBL 8260D SIM Antimony <0.507 ug/L 0.507 2.07 1 02/17/22 22:03 EDV 6020B Arsenic <0.177 Ng/L 0.177 1.04 1 02/17/22 22:03 EDV 6020B Barium 128 u9/L 0.842 10.4 1 02/14/2215:40 EDV 6020B Beryllium <0.198 N9/L 0.198 1.04 1 02/14/2215:40 EDV 6020B Cadmium <0.166 u9/L 0.166 1.04 1 02/14/2215:40 EDV 6020B Chromium <0.817 N9/L 0.817 2.07 1 02/14/2215:40 EDV 6020B Cobalt 4.36 u9/L 0.538 2.07 1 02/14/2215:40 EDV 6020B Copper <3.95 N9/L 3.95 10.4 1 02/14/2215:40 EDV 6020B Lead <0.270 u9/L 0.270 1.04 1 02/17/22 22:03 EDV 6020B Nickel 0.8773 N9/L 0.529 3.11 1 02/17/22 22:03 EDV 6020B Selenium <2.38 u9/L 2.38 5.18 1 02/22/2219:43 EDV 6020B Silver <0.114 N9/L 0.114 1.04 1 02/14/2215:40 EDV 6020B Thallium <0.590 u9/L 0.590 2.07 1 02/14/2215:40 EDV 6020B Vanadium <1.35 N9/L 1.35 5.18 1 02/17/22 22:03 EDV 6020B Zinc <7.14 ug/L 7.14 20.7 1 02/17/22 22:03 EDV 6020B Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 35 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPORT OF ANAL YSIS Lab No : 94081 Matrix: Aqueous Sample ID: SW-2 Sampled: 2/11/2022 15:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch Acetone 3.223 Ng/L 1.80 5.00 1 02/16/22 17:10 JLB V15071 Acrylonitrile <0.230 ug/L 0.230 5.00 1 02/16/22 17:10 JLB V15071 Benzene 0.2343 Ng/L 0.180 0.500 1 02/16/22 17:10 JLB V15071 Bromochloromethane <0.420 ug/L 0.420 1.00 1 02/16/22 17:10 JLB V15071 Bromodichloromethane <0.160 Ng/L 0.160 0.500 1 02/16/22 17:10 JLB V15071 Bromoform <1.50 ug/L 1.50 5.00 1 02/16/22 17:10 JLB V15071 Bromomethane <0.280 Ng/L 0.280 1.00 1 02/16/22 17:10 JLB V15071 Carbon Disulfide <0.150 ug/L 0.150 5.00 1 02/16/22 17:10 JLB V15071 Carbon Tetrachloride <0.180 Ng/L 0.180 0.500 1 02/16/22 17:10 JLB V15071 Chlorobenzene 2.61 ug/L 0.190 0.500 1 02/16/22 17:10 JLB V15071 Chlorodibromomethane <0.190 Ng/L 0.190 0.500 1 02/16/22 17:10 JLB V15071 Chloroethane <0.430 ug/L 0.430 1.00 1 02/16/22 17:10 JLB V15071 Chloroform <0.220 Ng/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 Chloromethane <0.220 ug/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 Di -Isopropyl Ether (DIPE) <0.960 Ng/L 0.960 5.00 1 02/16/22 17:10 JLB V15071 1,2-Dibromo-3-Chloropropane <1.10 ug/L 1.10 2.00 1 02/16/22 17:10 JLB V15071 1,2-Dibromoethane <0.200 Ng/L 0.200 0.500 1 02/16/22 17:10 JLB V15071 Dibromomethane <0.230 ug/L 0.230 0.500 1 02/16/22 17:10 JLB V15071 trans-1,4-Dichloro-2-butene <1.30 Ng/L 1.30 10.0 1 02/16/22 17:10 JLB V15071 1,2-Dichlorobenzene <0.220 ug/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 1,4-Dichlorobenzene 0.671 Ng/L 0.210 0.500 1 02/16/22 17:10 JLB V15071 Dichlorodifluoromethane <1.20 ug/L 1.20 5.00 1 02/16/22 17:10 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 36 of 49 Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 ANALYTICAL www.waypointanalytical.com 01222 Wood Environ. & Infrastructure Inc (Asheville) Project WCU MSWLF Gregory Hutchins Report Date : 02/23/2022 1308 Patton Avenue (Suite C) Information : Received : 02/12/2022 Asheville , NC 28806 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94081 Matrix: Aqueous Sample ID: SW-2 Sampled: 2/11/2022 15:00 Analytical Method: 8260D Prep Batch(es): V15070 02/16/22 09:00 Prep Method: 5030E Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Batch 1,1-Dichloroethane <0.240 Ng/L 0.240 0.500 1 02/16/22 17:10 JLB V15071 1,2-Dichloroethane <0.150 ug/L 0.150 0.500 1 02/16/22 17:10 JLB V15071 1,1-Dichloroethene <0.150 Ng/L 0.150 0.500 1 02/16/22 17:10 JLB V15071 cis- 1,2-Dich loroethene <0.200 ug/L 0.200 0.500 1 02/16/22 17:10 JLB V15071 trans-1,2-Dichloroethene <0.180 Ng/L 0.180 0.500 1 02/16/22 17:10 JLB V15071 1,2-Dichloropropane <0.190 ug/L 0.190 0.500 1 02/16/22 17:10 JLB V15071 cis- 1,3-Dich loropropene <0.210 Ng/L 0.210 0.500 1 02/16/22 17:10 JLB V15071 trans-1,3-Dichloropropene <0.150 ug/L 0.150 0.500 1 02/16/22 17:10 JLB V15071 Ethylbenzene <0.170 Ng/L 0.170 0.500 1 02/16/22 17:10 JLB V15071 2-Hexanone <0.380 ug/L 0.380 5.00 1 02/16/22 17:10 JLB V15071 Methyl Ethyl Ketone (MEK) <0.710 Ng/L 0.710 5.00 1 02/16/22 17:10 JLB V15071 4-Methyl-2-Pentanone <1.00 ug/L 1.00 5.00 1 02/16/22 17:10 JLB V15071 Methylene Chloride <0.330 Ng/L 0.330 1.00 1 02/16/22 17:10 JLB V15071 Styrene <0.220 ug/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 1,1,1,2-Tetrachloroethane <0.160 Ng/L 0.160 0.500 1 02/16/22 17:10 JLB V15071 1,1,2,2-Tetrachloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 17:10 JLB V15071 Tetrachloroethene <0.220 Ng/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 Tetrahydrofuran <1.50 ug/L 1.50 10.0 1 02/16/22 17:10 JLB V15071 Toluene <0.220 Ng/L 0.220 0.500 1 02/16/22 17:10 JLB V15071 1,1,1-Trichloroethane <0.160 ug/L 0.160 0.500 1 02/16/22 17:10 JLB V15071 1,1,2-Trichloroethane <0.096 Ng/L 0.096 0.500 1 02/16/22 17:10 JLB V15071 Trichloroethene <0.180 ug/L 0.180 0.500 1 02/16/22 17:10 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 37 of 49 Waypoint.0 ANALYTICAL 01222 Wood Environ. & Infrastructure Inc (Asheville) Project Gregory Hutchins 1308 Patton Avenue (Suite C) Information Asheville , NC 28806 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointana lyti ca Isom WCU MSWLF Report Date : 02/23/2022 Received : 02/12/2022 Report Number : 22-045-0001 REPOR T OF A NA L YSIS Lab No : 94081 Matrix: Aqueous Sample ID: SW-2 Sampled: 2/11/2022 15:00 Analytical Method: 8260D Prep Method: 5030E Test Results Trichlorofluoromethane <0.180 1,2,3-Trichloropropane <0.270 Vinyl Acetate <1.00 Vinyl Chloride <0.170 o-Xylene <0.210 m,p-Xylene <0.420 Xylene (Total) <0.21 Surrogate: 4-Bromofl uorobenzene Surrogate: Dibromofluoromethane Surrogate: 1,2-Dichloroethane - d4 Surrogate: Toluene-d8 Prep Batch(es): V15070 02/16/22 09:00 Units MDL MQL DF Date / Time By Analytical Analyzed Batch Ng/L 0.180 0.500 Pg/L 0.270 1.00 Ng/L 1.00 2.00 Pg/L 0.170 0.500 Ng/L 0.210 0.500 Pg/L 0.420 1.00 Ng/L 0.210 0.500 103 Limits: 80-124% 104 Limits: 75-129% 102 Limits: 63-136% 100 Limits: 77-123% 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 1 02/16/22 17:10 JLB V15071 Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 38 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V14895 QC Analytical Batch(es): V14952,V15106,V15213 QC Prep Batch Method: SM-3030C (PREP) Analysis Method: 6020B Analysis Description: Metals Analyses Lab Reagent Blank Associated Lab Samples: Parameter LRB-V14895 94075, 94076, 94077, 94078, 94079, 94080, 94081 Blank MDL MQL Units Result Matrix: AQU Analyzed Antimony pg/L <0.505 0.505 2.06 02/17/22 20:18 Arsenic pg/L <0.175 0.175 1.03 02/17/22 20:18 Barium pg/L <0.834 0.834 10.3 02/14/22 14:48 Beryllium pg/L <0.196 0.196 1.03 02/14/22 14:48 Cadmium pg/L <0.165 0.165 1.03 02/14/22 14:48 Chromium pg/L <0.813 0.813 2.06 02/14/22 14:48 Cobalt pg/L <0.535 0.535 2.06 02/14/22 14:48 Copper pg/L <3.91 3.91 10.3 02/14/22 14:48 Lead pg/L <0.268 0.268 1.03 02/17/22 20:18 Nickel pg/L <0.525 0.525 3.09 02/17/22 20:18 Selenium pg/L <2.37 2.37 5.16 02/21/22 20:18 Silver pg/L <0.113 0.113 1.03 02/14/22 14:48 Thallium pg/L <0.587 0.587 2.06 02/14/22 14:48 Vanadium pg/L <1.34 1.34 5.16 02/17/22 20:18 Zinc pg/L <7.11 7.11 20.6 02/17/22 20:18 Laboratory Control Sample LCS-V14895 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits Antimony pg/L 100 104 104 80-120 Arsenic pg/L 100 99.4 99.0 80-120 Barium pg/L 100 95.6 96.0 80-120 Beryllium pg/L 100 97.3 97.0 80-120 Cadmium pg/L 100 99.0 99.0 80-120 Chromium pg/L 100 102 102 80-120 Cobalt pg/L 100 106 106 80-120 Copper pg/L 100 107 107 80-120 Date: 02/23/2022 12:50 PM Page 1 of 9 Page 39 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V14895 QC Prep Batch Method: SM-3030C(PREP) Laboratory Control Sample LCS-V14895 QC Analytical Batch(es): V14952,V15106,V15213 Analysis Method: 6020B Analysis Description: Metals Analyses Parameter Units Spike Conc. LCS Result LCS %Rec % Rec Limits Lead pg/L 100 104 104 80-120 Nickel pg/L 100 99.6 100 80-120 Selenium pg/L 100 105 105 80-120 Silver pg/L 100 95.6 96.0 80-120 Thallium pg/L 100 76.6 77.0* 80-120 Vanadium pg/L 100 101 101 80-120 Zinc pg/L 100 105 105 80-120 Matrix Spike & Matrix Spike Duplicate Parameter Units V 94079-MS-V14895 MS Spike Result Conc. V 94079-MSD-V14895 MSD MS Result Spike Conc. MSD Result MS %Rec MSD %Rec %Rec Limits RPD Max RPD Antimony pg/L < 0.517 100 100 109 108 109 108 75-125 0.9 20.0 Arsenic pg/L < 0.179 100 100 100 99.2 100 99.0 75-125 0.8 20.0 Barium pg/L 111 100 100 202 199 91.0 88.0 75-125 1.4 20.0 Beryllium pg/L < 0.200 100 100 98.5 98.3 99.0 98.0 75-125 0.2 20.0 Cadmium pg/L < 0.168 100 100 99.5 100 100 100 75-125 0.5 20.0 Chromium pg/L < 0.833 100 100 98.0 98.5 98.0 99.0 75-125 0.5 20.0 Cobalt pg/L 14.0 100 100 114 115 100 101 75-125 0.8 20.0 Copper pg/L < 3.99 100 100 101 102 101 102 75-125 0.9 20.0 Lead pg/L < 0.273 100 100 106 103 106 103 75-125 2.8 20.0 Nickel pg/L 3.28 100 100 97.7 98.0 94.0 95.0 75-125 0.3 20.0 Selenium pg/L 1.49 100 100 106 106 106 106 75-125 0.0 20.0 Silver pg/L < 0.116 100 100 96.8 96.4 97.0 96.0 75-125 0.4 20.0 Thallium pg/L < 0.601 100 100 78.5 78.7 79.0 79.0 75-125 0.2 20.0 Vanadium pg/L < 1.37 100 100 102 102 102 102 75-125 0.0 20.0 Zinc pg/L < 7.28 100 100 106 105 106 105 75-125 0.9 20.0 * QC Fail Date: 02/23/2022 12:50 PM Page 2 of 9 Page 40 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V14895 QC Analytical Batch(es): V14952,V15106,V15213 QC Prep Batch Method: SM-3030C (PREP) Analysis Method: 6020B Analysis Description: Metals Analyses Post Digestion Spike V 94079-PDS-V14895 Parameter Units PDS Result % Recovery Analyzed Antimony pg/L 57.1 114 02/17/22 21:04 Arsenic pg/L 52.8 106 02/17/22 21:04 Barium pg/L 107 103 02/14/22 16:13 Beryllium Ng/L 50.5 101 02/14/22 16:13 Cadmium pg/L 52.4 105 02/14/22 16:13 Chromium pg/L 51.3 103 02/14/22 16:13 Cobalt pg/L 59.2 104 02/14/22 16:13 Copper pg/L 52.1 104 02/14/22 16:13 Lead pg/L 52.2 104 02/17/22 21:04 Nickel Ng/L 50.9 99.0 02/17/22 21:04 Selenium pg/L 54.0 108 02/17/22 21:04 Silver pg/L 52.2 104 02/14/22 16:13 Thallium Ng/L 50.5 101 02/14/22 16:13 Vanadium Ng/L 53.5 107 02/17/22 21:04 Zinc pg/L 54.9 110 02/17/22 21:04 Date: 02/23/2022 12:50 PM Page 3 of 9 Page 41 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V14907 QC Analytical Batch(es): V14908 QC Prep Batch Method: 5030B Analysis Method: 8260D SIM Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V14907 Matrix: AQU Associated Lab Samples: 94073, 94075, 94076, 94077, 94078, 94079, 94080, 94081 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,4-Dioxane pg/L <0.139 0.139 2.00 02/14/2210:17 4-Bromofluorobenzene (S) 02/14/22 10:17 92.6 70-130 Laboratory Control Sample LCS-V14907 Spike LCS LCS %Rec % Rec Parameter Units Conc. Result Limits 1,4-Dioxane pg/L 50.0 56.2 112 70-130 4-Bromofluorobenzene (S) 110 70-130 Matrix Spike & Matrix Spike Duplicate V 93949-MS-V14907 V 93949-MSD-V14907 MS Spike MSD MS Result MSD MS MSD %Rec Max Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD Conc. 1,4-Dioxane pg/L < 0.139 50.0 50.0 60.7 59.6 121 119 70-130 4-Bromofluorobenzene (S) 119 109 70-130 Date: 02/23/2022 12:50 PM Page 4 of 9 Page 42 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V15070 QC Prep Batch Method: 5030B QC Analytical Batch(es): V15071 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V15070 Matrix: AQU Associated Lab Samples: 94073, 94075, 94076, 94077, 94078, 94079, 94080, 94081 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Acetone pg/L <1.80 1.80 5.00 02/16/22 13:04 Acrylonitrile pg/L <0.230 0.230 5.00 02/16/22 13:04 Benzene pg/L <0.180 0.180 0.500 02/16/22 13:04 Bromochloromethane pg/L <0.420 0.420 1.00 02/16/22 13:04 Bromodichloromethane pg/L <0.160 0.160 0.500 02/16/22 13:04 Bromoform pg/L <1.50 1.50 5.00 02/16/22 13:04 Bromomethane pg/L <0.280 0.280 1.00 02/16/22 13:04 Carbon Disulfide pg/L <0.150 0.150 5.00 02/16/22 13:04 Carbon Tetrachloride pg/L <0.180 0.180 0.500 02/16/22 13:04 Chlorobenzene pg/L <0.190 0.190 0.500 02/16/22 13:04 Chlorodibromomethane pg/L <0.190 0.190 0.500 02/16/22 13:04 Chloroethane pg/L <0.430 0.430 1.00 02/16/22 13:04 Chloroform pg/L <0.220 0.220 0.500 02/16/22 13:04 Chloromethane pg/L <0.220 0.220 0.500 02/16/22 13:04 Di -Isopropyl Ether (DIPE) pg/L <0.960 0.960 5.00 02/16/22 13:04 1,2-Dibromo-3-Chloropropane pg/L < 1.10 1.10 2.00 02/16/22 13:04 1,2-Dibromoethane pg/L <0.200 0.200 0.500 02/16/22 13:04 Dibromomethane pg/L <0.230 0.230 0.500 02/16/22 13:04 trans-1,4-Dichloro-2-butene pg/L < 1.30 1.30 10.0 02/16/22 13:04 1,2-Dichlorobenzene pg/L <0.220 0.220 0.500 02/16/22 13:04 1,4-Dichlorobenzene pg/L <0.210 0.210 0.500 02/16/22 13:04 Dichlorodifluoromethane pg/L <1.20 1.20 5.00 02/16/22 13:04 1,1-Dichloroethane pg/L <0.240 0.240 0.500 02/16/22 13:04 1,2-Dichloroethane pg/L <0.150 0.150 0.500 02/16/22 13:04 1,1-Dichloroethene pg/L <0.150 0.150 0.500 02/16/22 13:04 cis-1,2-Dichloroethene pg/L <0.200 0.200 0.500 02/16/22 13:04 trans-1,2-Dichloroethene pg/L <0.180 0.180 0.500 02/16/22 13:04 Date: 02/23/2022 12:50 PM Page 5 of 9 Page 43 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V15070 QC Prep Batch Method: 5030B QC Analytical Batch(es): V15071 Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V15070 Matrix: AQU Associated Lab Samples: 94073, 94075, 94076, 94077, 94078, 94079, 94080, 94081 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits 1,2-Dichloropropane pg/L <0.190 0.190 0.500 02/16/22 13:04 cis-1,3-Dichloropropene pg/L <0.210 0.210 0.500 02/16/22 13:04 trans-1,3-Dichloropropene pg/L <0.150 0.150 0.500 02/16/22 13:04 Ethylbenzene pg/L <0.170 0.170 0.500 02/16/22 13:04 2-Hexanone pg/L <0.380 0.380 5.00 02/16/22 13:04 Methyl Ethyl Ketone (MEK) pg/L <0.710 0.710 5.00 02/16/22 13:04 4-Methyl-2-Pentanone pg/L <1.00 1.00 5.00 02/16/22 13:04 Methylene Chloride pg/L <0.330 0.330 1.00 02/16/22 13:04 Styrene pg/L <0.220 0.220 0.500 02/16/22 13:04 1,1,1,2-Tetrachloroethane pg/L <0.160 0.160 0.500 02/16/22 13:04 1,1,2,2-Tetrachloroethane pg/L <0.160 0.160 0.500 02/16/22 13:04 Tetrachloroethene pg/L <0.220 0.220 0.500 02/16/22 13:04 Tetrahydrofuran pg/L <1.50 1.50 10.0 02/16/22 13:04 Toluene pg/L <0.220 0.220 0.500 02/16/22 13:04 1,1,1-Trichloroethane pg/L <0.160 0.160 0.500 02/16/22 13:04 1,1,2-Trichloroethane pg/L <0.096 0.096 0.500 02/16/22 13:04 Trichloroethene pg/L <0.180 0.180 0.500 02/16/22 13:04 Trichlorofluoromethane pg/L <0.180 0.180 0.500 02/16/22 13:04 1,2,3-Trichloropropane pg/L <0.270 0.270 1.00 02/16/22 13:04 Vinyl Acetate pg/L <1.00 1.00 2.00 02/16/22 13:04 Vinyl Chloride pg/L <0.170 0.170 0.500 02/16/22 13:04 o-Xylene pg/L <0.210 0.210 0.500 02/16/22 13:04 m,p-Xylene pg/L <0.420 0.420 1.00 02/16/22 13:04 4-Bromofluorobenzene (S) 02/16/22 13:04 104 80-124 Dibromofluoromethane (S) 02/16/22 13:04 101 75-129 1,2-Dichloroethane - d4 (S) 02/16/22 13:04 98.4 63-136 Date: 02/23/2022 12:50 PM Page 6 of 9 Page 44 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V15070 QC Analytical Batch(es): V15071 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Lab Reagent Blank LRB-V15070 Matrix: AQU Associated Lab Samples: 94073, 94075, 94076, 94077, 94078, 94079, 94080, 94081 Blank MDL MQL Analyzed % % Rec Parameter Units Result Recovery Limits Toluene-d8 (S) 02/16/22 13:04 98.8 77-123 Laboratory Control Sample & LCSD LCS-V15070 LCSD-V15070 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec a/o Rec Limits RPD Max RPD Acetone pg/L 40.0 34.9 32.2 87.2 80.5 40-166 8.0 20.0 Acrylonitrile pg/L 40.0 41.8 41.4 105 104 81-127 0.9 20.0 Benzene pg/L 20.0 19.9 19.5 99.5 97.5 77-128 2.0 20.0 Bromochloromethane pg/L 20.0 20.4 20.4 102 102 78-135 0.0 20.0 Bromodichloromethane pg/L 20.0 20.2 20.2 101 101 76-138 0.0 20.0 Bromoform pg/L 20.0 21.7 21.2 109 106 71-135 2.3 20.0 Bromomethane pg/L 20.0 21.8 22.2 109 111 41-168 1.8 20.0 Carbon Disulfide pg/L 20.0 18.6 18.4 93.0 92.0 59-135 1.0 20.0 Carbon Tetrachloride pg/L 20.0 20.3 20.2 102 101 72-142 0.4 20.0 Chlorobenzene pg/L 20.0 20.8 20.3 104 102 78-119 2.4 20.0 Chlorodibromomethane pg/L 20.0 20.4 20.7 102 104 75-134 1.4 20.0 Chloroethane pg/L 20.0 21.8 21.1 109 106 57-142 3.2 20.0 Chloroform pg/L 20.0 20.0 19.7 100 98.5 77-130 1.5 20.0 Chloromethane pg/L 20.0 20.0 19.8 100 99.0 47-145 1.0 20.0 Di -Isopropyl Ether (DIPE) pg/L 20.0 20.3 19.5 102 97.5 60-154 4.0 20.0 1,2-Dibromo-3-Chloropropane pg/L 20.0 21.0 20.6 105 103 63-134 1.9 20.0 1,2-Dibromoethane pg/L 20.0 20.5 20.3 103 102 77-135 0.9 20.0 Dibromomethane pg/L 20.0 20.4 19.6 102 98.0 76-138 4.0 20.0 trans-1,4-Dichloro-2-butene pg/L 20.0 20.4 19.4 102 97.0 70-130 5.0 20.0 1,2-Dichlorobenzene pg/L 20.0 20.3 20.0 102 100 78-128 1.4 20.0 1,4-Dichlorobenzene pg/L 20.0 20.4 19.9 102 99.5 75-126 2.4 20.0 Date: 02/23/2022 12:50 PM Page 7 of 9 Page 45 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V15070 QC Analytical Batch(es): V15071 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V15070 LCSD-V15070 Parameter Units Spike Conc. LCS Result LCSD Result LCS %Rec LCSD % Rec % Rec Limits RPD Max RPD Dichlorodifluoromethane pg/L 20.0 18.6 17.5 93.0 87.5 28-163 6.0 20.0 1,1-Dichloroethane pg/L 20.0 19.9 19.7 99.5 98.5 70-130 1.0 20.0 1,2-Dichloroethane pg/L 20.0 19.8 19.9 99.0 99.5 68-131 0.5 20.0 1,1-Dichloroethene pg/L 20.0 20.1 19.2 101 96.0 70-154 4.5 20.0 cis-1,2-Dichloroethene pg/L 20.0 20.2 19.5 101 97.5 76-141 3.5 20.0 trans-1,2-Dichloroethene pg/L 20.0 20.2 19.7 101 98.5 76-135 2.5 20.0 1,2-Dichloropropane pg/L 20.0 20.6 20.6 103 103 77-130 0.0 20.0 cis-1,3-Dichloropropene pg/L 20.0 20.8 20.3 104 102 65-140 2.4 20.0 trans-1,3-Dichloropropene pg/L 20.0 20.5 20.3 103 102 67-140 0.9 20.0 Ethylbenzene pg/L 20.0 20.2 20.1 101 101 80-127 0.4 20.0 2-Hexanone pg/L 20.0 20.8 20.7 104 104 64-137 0.4 20.0 Methyl Ethyl Ketone (MEK) pg/L 20.0 18.3 18.0 91.5 90.0 71-134 1.6 20.0 4-Methyl-2-Pentanone pg/L 20.0 21.2 20.8 106 104 69-134 1.9 20.0 Methylene Chloride pg/L 20.0 20.5 20.5 103 103 73-131 0.0 20.0 Styrene pg/L 20.0 21.0 20.8 105 104 78-129 0.9 20.0 1,1,1,2-Tetrachloroethane pg/L 20.0 20.6 20.3 103 102 79-134 1.4 20.0 1,1,2,2-Tetrachloroethane pg/L 20.0 21.2 20.5 106 103 62-127 3.3 20.0 Tetrachloroethene pg/L 20.0 20.2 20.1 101 101 80-129 0.4 20.0 Tetrahydrofuran pg/L 20.0 19.8 18.4 99.0 92.0 70-130 7.3 20.0 Toluene pg/L 20.0 20.7 20.0 104 100 76-131 3.4 20.0 1,1,1-Trichloroethane pg/L 20.0 20.5 19.4 103 97.0 75-135 5.5 20.0 1,1,2-Trichloroethane pg/L 20.0 20.4 20.8 102 104 70-140 1.9 20.0 Trichloroethene pg/L 20.0 20.5 19.8 103 99.0 77-133 3.4 20.0 Trichlorofluoromethane pg/L 20.0 20.4 19.8 102 99.0 62-148 2.9 20.0 1,2,3-Trichloropropane pg/L 20.0 22.1 20.7 111 104 71-127 6.5 20.0 Vinyl Acetate pg/L 20.0 21.2 20.9 106 105 34-167 1.4 20.0 Date: 02/23/2022 12:50 PM Page 8 of 9 Page 46 of 49 Waypointo ANALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Quality Control Data Client ID: Wood Environ. & Infrastructure Inc (Asheville) Project Description: WCU MSWLF Report No: 22-045-0001 QC Prep: V15070 QC Analytical Batch(es): V15071 QC Prep Batch Method: 5030B Analysis Method: 8260D Analysis Description: Volatile Organic Compounds - GC/MS Laboratory Control Sample & LCSD LCS-V15070 LCSD-V15070 Spike LCS LCSD LCS LCSD % Rec Parameter Units Conc. Result Result %Rec % Rec Limits RPD Max RPD Vinyl Chloride pg/L 20.0 19.2 18.9 96.0 94.5 57-141 1.5 20.0 o-Xylene pg/L 20.0 21.0 20.3 105 102 78-128 3.3 20.0 m,p-Xylene pg/L 40.0 42.1 41.7 105 104 77-133 0.9 20.0 4-Bromofluorobenzene (S) 99.8 102 80-124 Dibromofluoromethane (S) 98.8 97.6 75-129 1,2-Dichloroethane - d4 (S) 100 99.8 63-136 Toluene-d8(S) 99.0 102 77-123 Date: 02/23/2022 12:50 PM Page 9 of 9 Page 47 of 49 WayPAoint. NALYTICAL 449 Springbrook Rd, Charlotte, NC 28217 Main 704.529.6364 www.waypointanalytical.com Shipment Receipt Form Customer Number: 01222 Customer Name: Wood Environ. & Infrastructure Inc (Asheville) Report Number: 22-045-0001 Shipping Method Fed Ex 0 US Postal 0 Lab 0 Other: 0 UPS 0 Client 0 Courier Thermometer ID: IRT-15 1.3C Shipping container/cooler uncompromised? 0 Yes 0 No Number of coolers/boxes received F Custody seals intact on shipping container/cooler? (*� Yes 0 No 0 Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample Iabel(s)? (0) Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? U Yes 0 No Sample containers intact? 0 Yes 0 No Sufficient sample volume for indicated test(s)? U Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? 0 Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. U Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) Special precautions or instructions included? Comments: 0 Yes 0 No U N/A F Low concentration EnCore samplers (48 hr) Low conc pre -weighed vials (Sod Bis -14 d) 0Yes ONo Signature: Sarah J. Locklear Date & Time: 02/14/2022 09:49:24 Page 48 of 49 70 m 0 A Q Q 0 4•i a a a Q m n 0 3 3 CD a a c 1 a man m m 7 71 1 } AZ, sFIE �� [,�. N [� N N � N • � � F in CL lb 0 �.0 V 30 N w m 0 � � 3 � d z° m ■ �o zap? mil' ■■■■■■■ NO ■■■■■■■ Q m n x _�� r o VN c�m� ` S N m r � Gaya h o m 1n� 3 a a �yp'a TJ m O N �3 6 N M.I a Ci o ..- ° aL O m ram Q ' m �0H� z x y F�a� rn t = S R �Y(y m N f C' an m L o� ru A ra m 2 L m a CM�c� m a w o C7 n 3. rs a nx N w ID O a _ m rmn n a o CJ CA 0 c P '� O1 ImN N W m 0 �0 O C 09 O y 7 z z V O Q- t. C�7 � � m • � ra m �"•m � n T a m 0 �n°'� Z x p r� 0 ro m P 2 # S.M RI m N \ yo !w • m Z C n M [D 0 0 M- 0 C A � r 2 rn rn m < r � = m ^ V Page 49 of 49