2020.01.21_CCO.p8_Fluromonomers Manufacturing Process Division Stack Emissions Test Report

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020

FLUOROMONOMERS
MANUFACTURING PROCESS
DIVISION STACK EMISSIONS TEST REPORT
TEST DATES: 22 NOVEMBER AND
4 DECEMBER 2019

THE CHEMOURS COMPANY
FAYETTEVILLE, NORTH CAROLINA
Prepared for:

THE CHEMOURS COMPANY
22828 NC Hwy 87 W
Fayetteville, North Carolina 28306

Prepared by:

WESTON SOLUTIONS, INC.
1400 Weston Way
P.O. Box 2653
West Chester, Pennsylvania 19380

January 2020

W.O. No. 15418.002.018

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
THE CHEMOURS COMPANY
FLOROMONOMERS MANUFACTURING PROCESS
DIVISION STACK EMISSIONS TEST REPORT
TEST DATES: 22 November and 4 December 2019
Weston Solutions, Inc. (WESTON®) is a commercial laboratory operating within full
accreditation of the Louisiana Environmental Laboratory Accreditation Program under
Certificate Number 03024. The qualifications to provide defensible quality data as a certified
commercial environmental testing firm as Agency Interest No. 30815 was granted by the
Louisiana Department of Environmental Quality under the Louisiana Administrative Code of
LAC 33.1 Chapter 45 et al.
I certify that I have personally examined and am familiar with the information contained herein.
Based on my information and belief formed after reasonable inquiry, the statements and
information in the document are true, accurate, and complete.
Paul M. Meeter
Weston Solutions, Inc.

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020 i
TABLE OF CONTENTS
Section Page
1. INTRODUCTION..............................................................................................................1 
1.1 FACILITY AND BACKGROUND INFORMATION ...........................................1 
1.2 TEST OBJECTIVES ...............................................................................................1 
1.3 TEST PROGRAM OVERVIEW .............................................................................1 
2. SUMMARY OF TEST RESULTS ...................................................................................4 
3. PROCESS DESCRIPTIONS ............................................................................................6 
3.1 FLUOROMONOMERS ..........................................................................................6 
3.2 PROCESS OPERATIONS AND PARAMETERS .................................................6 
4. DESCRIPTION OF TEST LOCATIONS .......................................................................7 
4.1 DIVISION STACK ..................................................................................................7 
5. SAMPLING AND ANALYTICAL METHODS .............................................................9 
5.1 STACK GAS SAMPLING PROCEDURES ...........................................................9 
5.1.1 Pre-Test Determinations ...........................................................................9 
5.2 STACK PARAMETERS .........................................................................................9 
5.2.1 EPA Method 0010.....................................................................................9 
5.2.2 EPA Method 0010 Sample Recovery .....................................................11 
5.2.3 EPA Method 0010 Sample Analysis.......................................................13 
5.3 MM18 ....................................................................................................................15 
5.4 GAS COMPOSITION ...........................................................................................17 
6. DETAILED TEST RESULTS AND DISCUSSION .....................................................19 

APPENDIX A PROCESS OPERATIONS DATA
APPENDIX B RAW AND REDUCED TEST DATA
APPENDIX C LABORATORY ANALYTICAL REPORT
APPENDIX D SAMPLE CALCULATIONS
APPENDIX E EQUIPMENT CALIBRATION RECORDS
APPENDIX F LIST OF PROJECT PARTICIPANTS

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LIST OF FIGURES
Title Page
Figure 4-1 Division Stack Test Port and Traverse Point Location ................................................ 8 
Figure 5-1 EPA Method 0010 Sampling Train ............................................................................. 10 
Figure 5-2 HFPO Dimer Acid Sample Recovery Procedures for Method 0010 ......................... 14 
Figure 5-3 Modified EPA Method 18 Sampling Train ................................................................ 16 
Figure 5-4 WESTON Sampling System ...................................................................................... 18 

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LIST OF TABLES
Title Page
Table 1-1 Sampling Plan for Division Stack .................................................................................. 3 
Table 2-1 Summary of HFPO Dimer Acid Division Stack Test Results ........................................ 4 
Table 2-2 Summary of Target Compound Division Stack Test Results ......................................... 4 
Table 6-1 Summary of HFPO Dimer Acid Test Data and Test Results Division Stack – M0010
Runs 1 and 2.......................................................................................................................... 20 
Table 6-2 Summary of Target Compound Test Data and Test Results Division Stack – MM18
Runs 1, 2 and 3...................................................................................................................... 22 

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1. INTRODUCTION
1.1 FACILITY AND BACKGROUND INFORMATION
The Chemours Fayetteville Works (Chemours) is located in Bladen County, North Carolina,
approximately 10 miles south of the city of Fayetteville. Chemours operating areas on the site
include the Fluoromonomers, IXM and Polymers Processing Aid (PPA) manufacturing areas,
Wastewater Treatment, and Powerhouse.
Chemours contracted Weston Solutions, Inc. (Weston) to perform HFPO Dimer Acid Fluoride,
captured as HFPO Dimer Acid, and other target compound, emission testing on the Division
stack at the facility. Testing was performed on 22 November and 4 December 2019 and generally
followed the “Emission Test Protocol” reviewed and approved by the North Carolina
Department of Environmental Quality (NCDEQ). This report provides the results from the
emission test program.
1.2 TEST OBJECTIVES
The specific objectives for this test program were as follows:
 Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid
Fluoride and other target compounds from the Division stack which is located in the
Fluoromonomers process area.
 Monitor and record process and emissions control data in conjunction with the test
program.
 Provide representative emissions data.
1.3 TEST PROGRAM OVERVIEW
During the emissions test program, the concentrations and mass emissions rates of HFPO Dimer
Acid and other target compounds were measured at the Division stack.
Table 1-1 provides a summary of the test location and the parameters that were measured along
with the sampling/analytical procedures that were followed.

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Section 2 provides a summary of test results. A description of the processes is provided in
Section 3. Section 4 provides a description of the test locations. The sampling and analytical
procedures are provided in Section 5. Detailed test results and discussion are provided in
Section 6.
Appendix C includes the summary reports for the laboratory analytical results. The full
laboratory data packages are provided in electronic format.

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Table 1-1
Sampling Plan for Division Stack
Sampling Point &
Location Division Stack
Number of Tests: 5 (3 MM18 and 2 M0010)
Parameters To Be Tested: HFPO
Dimer Acid
(HFPO-DA)
HFPO
Dimer
Methyl
Ester;
HFPO
Monomer;
Fluoroether
E-1;
Carbonyl
Difluoride
Total
Fluorine;
Hydrogen
Fluoride
Volumetric
Flow Rate
and
Gas Velocity
Carbon
Dioxide
Oxygen Water
Content
Sampling or Monitoring
Method
EPA M-
0010
Modified
EPA M-18
Modified
EPA M-18
EPA M1 and
M2 in
conjunction
with M-0010
tests
EPA M3/3A EPA M4 in
conjunction
with M-0010
tests
Sample Extraction/
Analysis Method(s):
LC/MS/MS GC/MS
and
LC/MS/MS
9056 NA NA NA
Sample Size ≥ 1.5m3 ≥ 1.5m3 ≥ 1.5m3 NA NA NA NA
Total Number of Samples
Collected1 2 3 3 3 3 3 3
Reagent Blanks (Solvents,
Resins)1 1 set 1 set 1 set 0 0 0 0
Field Blank Trains1 1 per source 1 per
source
0 per
source
0 0 0 0
Proof Blanks1 1 per train 1 per train 0 per train 0 0 0 0
Trip Blanks1,2 0 sets 0 sets 0 sets 0 0 0 0
Lab Blanks 1 per
fraction3
1 per
fraction3
0 per
fraction3
0 0 0 0
Laboratory or Batch
Control Spike Samples
(LCS)
1 per
fraction3
1 per
fraction3
1 per
fraction3
0 0 0 0
Laboratory or Batch
Control Spike Sample
Duplicate (LCSD)
1 per
fraction3
1 per
fraction3
1 per
fraction3
0 0 0 0
Media Blanks 1 set4 1 set4 1 set4 0 0 0 0
Isotope Dilution Internal
Standard Spikes Each sample Each
sample
Each
sample
0 0 0 0
Total No. of Samples 55 65 45 3 3 3 3
Key:
1 Sample collected in field.
2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment.
3 Lab blank and LCS/LCSD includes one set per analytical fraction (front half, back half and condensate).
4 One set of media blank archived at laboratory at media preparation.
5 Actual number of samples collected in field.

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2. SUMMARY OF TEST RESULTS
A total of three MM18 and two M0010 test runs were performed on the Division stack. Table 2-1
provides a summary of the HFPO Dimer Acid emissions test results associated with M0010.
Table 2-2 provides a summary of the target compound emissions test results associated with
MM18. Detailed test results summaries are provided in Section 6.
It is important to note that emphasis is being placed on the characterization of the emissions
based on the M0010 stack test results. Research conducted in developing the protocol for stack
testing HFPO Dimer Acid Fluoride, HFPO Dimer Acid Ammonium Salt and HFPO Dimer Acid
realized that the resulting testing, including collection of the air samples and extraction of the
various fraction of the sampling train, would result in all three compounds being expressed as
simply the HFPO Dimer Acid. However, it should be understood that the total M0010 HFPO
Dimer Acid results provided in Table 2-1 and in this report include a percentage of each of the
three compounds.
Table 2-1
Summary of M0010 HFPO Dimer Acid Division Stack Test Results
Division Stack – M0010
g/sec lb/hr
R1 1.94E-04 1.54E-03
R2 3.39E-04 2.69E-03
Average 2.66E-04 2.12E-03

Samples taken using MM18 were analyzed for the following volatile organic compounds (“target
compounds”): HFPO Dimer, Methyl Ester as HFPO (HFPO Dimer Methyl Ester); 2-MTP as
HFPO (HFPO Monomer); Heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether (Fluoroether E-1);
Carbonyl Difluoride; Total Fluorine and Hydrogen Fluoride. Results of MM18 target compound
analysis are provided in Table 2-2.

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Table 2-2
Summary of MM18 Target Compound Division Stack Test Results
Target Compound Division Stack MM18 Run 1 Division Stack MM18 Run 2 Division Stack MM18 Run 3
g/sec lb/hr g/sec lb/hr g/sec lb/hr
HFPO Dimer Methyl Ester <4.38E-03 <3.48E-02 <2.60E-03 <2.07E-02 <2.63E-03 <2.09E-02
HFPO Monomer 3.74E-01 2.97E+00 3.15E-01 2.50E+00 1.92E+00 1.53E+01
Fluoroether E-1 2.91E-02 2.31E-01 6.67E-02 5.30E-01 2.41E-02 1.92E-01
Carbonyl Difluoride <1.34E-02 <1.06E-01 <7.96E-03 <6.33E-02 <8.03E-03 <6.38E-02
Total Fluorine 7.27E+00 5.78E+01 5.94E+00 4.72E+01 1.40E+01 1.11E+02
Hydrogen Fluoride <1.82E-01 <1.45E+00 <1.09-01 <8.63E-01 <1.10E-01 <8.70E-01

Note: All < values were below the laboratory analysis detection limits. Emission rates were calculated using the method detection
limit (MDL) for the first analytical fraction of the target compound.

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020 6
3. PROCESS DESCRIPTIONS
The Fluoromonomers area is included in the scope of this test program.
3.1 FLUOROMONOMERS
These facilities produce a family of fluorocarbon compounds used to produce Chemours
products such as Nafion®, Krytox®, and Viton®, as well as sales to outside customers.
At the time of testing, process emissions were vented to the Division waste gas scrubber system
(which included the secondary scrubber) and vented to the Carbon Bed and then into the
Division stack. The VE North building air systems were vented to the Carbon Bed and then into
the Division stack.
3.2 PROCESS OPERATIONS AND PARAMETERS
The following table is a summary of the operation and products from the specific areas tested.
Source Operation/Product Batch or Continuous
VE
North
PPVE Condensation is continuous. Agitated Bed Reactor
and Refining are batch.
During the test program, the following parameters were monitored by Chemours and are
included in Appendix A.
 Fluoromonomers Process
o VEN Precurser Rate
o VEN Condensation Rate
o VEN ABR Rate

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4. DESCRIPTION OF TEST LOCATIONS
4.1 DIVISION STACK
Two 6-inch ID test ports were installed on the 36-inch ID fiberglass stack as shown below. The
four vents that enter the top of the stack and the one vent ~11 feet below are catch pots which,
under normal process operations, do not discharge to the stack. They are used to vent process gas
to the stack in the event of a process upset and are not considered a flow contributor or a
disturbance.
Per EPA Method 1, a total of 12 traverse points (six per axis) were used for M-0010 isokinetic
sampling. Figure 4-1 provides a schematic of the test ports and traverse point locations.
Location Distance from Flow Disturbance Downstream (B) Upstream (A) Division Stack 30 feet > 10 duct diameters 9 feet > 3 diameters

The EPA Method 18 sample was collected at a constant rate at a single point at the approximate
center of the stack.

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IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 9
5. SAMPLING AND ANALYTICAL METHODS
5.1 STACK GAS SAMPLING PROCEDURES
The purpose of this section is to describe the stack gas emissions sampling trains and to provide
details of the stack sampling and analytical procedures utilized during the emissions test
program.
5.1.1 Pre-Test Determinations
Preliminary test data were obtained at the test location. Stack geometry measurements were
measured and recorded, and traverse point distances verified. A preliminary velocity traverse
was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine
velocity profiles. Flue gas temperatures were observed with a calibrated direct readout panel
meter equipped with a chromel-alumel thermocouple. Preliminary water vapor content was
estimated by wet bulb/dry bulb temperature measurements.
A check for the presence or absence of cyclonic flow was previously conducted at the test
location. The cyclonic flow check was negative (< 20°) verifying that the test location was
acceptable for testing.
Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic
sampling procedures.
Calibration of probe nozzles, pitot tubes, metering systems, and temperature measurement
devices was performed as specified in Section 5 of EPA Method 5 test procedures.
5.2 STACK PARAMETERS
5.2.1 EPA Method 0010
The sampling train utilized to perform the HFPO Dimer Acid sampling at the location was an
EPA Method 0010 train (see Figure 5-1). The Method 0010 consisted of a borosilicate nozzle
that attached directly to a heated borosilicate probe. In order to minimize possible thermal
degradation of the HFPO Dimer Acid, the probe and particulate filter were heated above stack
temperature to minimize water vapor condensation before the filter. The probe was connected
directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter.
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IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020 11
A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a
Grahm (spiral) type ice water-cooled condenser, an ice water-jacketed sorbent module containing
approximately 40 grams of XAD-2 resin. The XAD-2 resin tube was equipped with an inlet
temperature sensor. The XAD-2 resin trap was followed by a condensate knockout impinger and
a series of two impingers that contained 100 mL of high-purity distilled water. The train also
included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling
train breakthrough. Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap.
The final impinger contained 300 grams of dry pre-weighed silica gel. All impingers and the
condensate traps were maintained in an ice bath. Ice water was continuously circulated in the
condenser and the XAD-2 module to maintain method-required temperature. A control console
with a leakless vacuum pump, a calibrated orifice, and dual inclined manometers was connected
to the final impinger via an umbilical cord to complete the sample train.
HFPO Dimer Acid Fluoride (CAS No. 2062-98-8) that is present in the stack gas is expected to
be captured in the sampling train along with HFPO Dimer Acid (CAS No. 13252-13-6). HFPO
Dimer Acid Fluoride underwent hydrolysis instantaneously in water in the sampling train and
during the sample recovery step, and was converted to HFPO Dimer Acid such that the amount
of HFPO Dimer Acid emissions represented a combination of both HFPO Dimer Acid Fluoride
and HFPO Dimer Acid.
During sampling, gas stream velocities were measured by attaching a calibrated S-type pitot tube
into the gas stream adjacent to the sampling nozzle. The velocity pressure differential was
observed immediately after positioning the nozzle at each traverse point, and the sampling rate
adjusted to maintain isokineticity at 100% ± 10. Flue gas temperature was monitored at each
point with a calibrated panel meter and thermocouple. Isokinetic test data was recorded at each
traverse point during all test periods, as appropriate. Leak checks were performed on the
sampling apparatus according to reference method instructions, prior to and following each run,
component change (if required) or during midpoint port changes.
5.2.2 EPA Method 0010 Sample Recovery
At the conclusion of each test, the sampling train was dismantled, the openings sealed, and the
components transported to the field laboratory trailer for recovery.
A consistent procedure was employed for sample recovery:
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1.The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were
sealed and labeled.
2.The glass fiber filter(s) were removed from the holder with tweezers and placed in a
polyethylene container along with any loose particulate and filter fragments.
3.The particulate adhering to the internal surfaces of the nozzle, probe and front half of the
filter holder were rinsed with a solution of methanol and ammonium hydroxide into a
polyethylene container while brushing a minimum of three times until no visible
particulate remained. Particulate adhering to the brush was rinsed with methanol/
ammonium hydroxide into the same container. The container was sealed.
4.The volume of liquid collected in the first condensate trap was measured, the value
recorded, and the contents poured into a polyethylene container.
5.All train components between the filter exit and the first condensate trap were rinsed with
methanol/ammonium hydroxide. The solvent rinse was placed in a separate polyethylene
container and sealed.
6.The volume of liquid in impingers one and two, and the second condensate trap, were
measured, the values recorded, and the sample was placed in the same container as Step 4
above, then sealed.
7.The two impingers, condensate trap, and connectors were rinsed with methanol/
ammonium hydroxide. The solvent sample was placed in a separate polyethylene
container and sealed.
8.The silica gel in the final impinger was weighed and the weight gain value recorded.
9.Site (reagent) blank samples of the methanol/ammonium hydroxide, XAD resin, filter
and distilled water were retained for analysis.
Each container was labeled to clearly identify its contents. All samples were maintained cool.
Following sample recovery, all samples were transported to Eurofins TestAmerica
(TestAmerica) for sample extraction and analysis.
See Figure 5-2 for a schematic of the Method 0010 sample recovery process.
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5.2.3 EPA Method 0010 Sample Analysis
Method 0010 sampling trains resulted in four separate analytical fractions for HFPO Dimer Acid
analysis according to SW-846 Method 3542:
Front-half Composite—comprised of the particulate filter, and the probe, nozzle, and
front-half of the filter holder solvent rinses;
Back-half Composite—comprised of the first XAD-2 resin material and the back-half of
the filter holder with connecting glassware solvent rinses;
Condensate Composite—comprised of the aqueous condensates and the contents of
impingers one and two with solvent rinses;
Breakthrough XAD-2 Resin Tube—comprised of the resin tube behind the series of
impingers.
The second XAD-2 resin material was analyzed separately to evaluate any possible sampling
train HFPO-DA breakthrough.
The front-half and back-half composites and the second XAD-2 resin material were placed in
polypropylene wide-mouth bottles and tumbled with methanol containing 5% NH4OH for 18
hours. Portions of the extracts were processed analytically for the HFPO dimer acid by liquid
chromatography and duel mass spectroscopy (HPLC/MS/MS). The condensate composite was
concentrated onto a solid phase extraction (SPE) cartridge followed by desorption from the
cartridge using methanol. Portions of those extracts were also processed analytically by
HPLC/MS/MS.
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Samples were spiked with isotope dilution internal standard (IDA) at the commencement of their
preparation to provide accurate assessments of the analytical recoveries. Final data was corrected
for IDA standard recoveries.
TestAmerica developed detailed procedures for the sample extraction and analysis for HFPO
Dimer Acid. These procedures were incorporated into the test protocol.
5.3 MM18
The sampling train utilized to perform the target compound sampling at the Division stack was a
modified EPA Method 18 train using full size Teflon® impingers. Impingers 1 through 6 each
contained 100 mL of methanol. See Figure 5-3 for the modified EPA Method 18 sampling train.
The impingers were maintained in a dry ice/methanol bath. Each test run was approximately 90
minutes in duration collecting at a rate of approximately ≥1.5 liters per minute.
Each impinger was recovered and included a methanol rinse of each impinger and connector.
The impinger contents and rinses were collected separately.
Each sample was analyzed by EPA SW-846 Method 8260B and 8231A procedures by Gas
Chromatography (GC) Mass Spectrometry (MS).
During the Division stack test campaign, a blank train was set up near the test location, leak-
checked and recovered along with the respective sample train. Following sample recovery, all
samples were transported to TestAmerica for sample extraction and analysis.
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5.4 GAS COMPOSITION
The Weston mobile laboratory equipped with instrumental analyzers was used to measure carbon
dioxide (CO2) and oxygen (O2) concentrations. A diagram of the Weston sampling system is
presented in Figure 5-4.
For the Division stack test campaign, the sample was collected at the exhaust of the Method
0010 sampling system. At the end of the line, a tee permitted the introduction of calibration gas.
The sample was drawn through a heated Teflon® sample line to the sample conditioner. The
output from the sampling system was recorded electronically, and one minute averages were
recorded and displayed on a data logger.
Each analyzer was set up and calibrated internally by introduction of calibration gas standards
directly to the analyzer from a calibration manifold. The calibration manifold is designed with an
atmospheric vent to release excess calibration gas and maintained the calibration at ambient
pressure. The direct calibration sequence consisted of alternate injections of zero and mid-range
gases with appropriate adjustments until the desired responses were obtained. The high-range
standards were then introduced in sequence without further adjustment.
The sample line integrity was verified by performing a bias test before and after each test period.
The sampling system bias test consisted of introducing the zero gas and one up-range calibration
standard in excess to the valve at the probe end when the system was sampling normally. The
excess calibration gas flowed out through the probe to maintain ambient sampling system
pressure. Calibration gas supply was regulated to maintain constant sampling rate and pressure.
Instrument bias check response was compared to internal calibration responses to insure sample
line integrity and to calculate a bias correction factor after each run using the ratio of the
measured concentration of the bias gas certified by the calibration gas supplier.
The oxygen and carbon dioxide content of each stack gas was measured according to EPA
Method 3A procedures which incorporate the latest updates of EPA Method 7E. A Servomex
Model 4900 analyzer (or equivalent) was used to measure oxygen content. A Servomex Model
4900 analyzer (or equivalent) was used to measure carbon dioxide content of the stack gas. Both
analyzers were calibrated with EPA Protocol gases prior to the start of the test program and
performance was verified by sample bias checks before and after each test run.
+($7('6$03/(352%(67$&.:$//+($7('),/7(5+2/'(5250(7+2'6$03/(75$,1+($7('6$03/(/,1(6$03/(&21',7,21,1*6<67(002,6785(5(029$/9(17&22*$6$1$/<=(56$&48,6I7,21,17(5)$&($1$/2*6,*1$//,1(&20387(5)25'$7$$&48,6,7,21$1'5('8&7,216$03/(3803&$/,%5$7,21*$6(6 212))9$/9(&$/,%5$7,21%,$6/,1(),*85(4 :(67216$03/,1*6<67(0,$6'$7$?&+(02856?18?),*85(4:(67216$03/,1*6<67(018
IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020 19
6.DETAILED TEST RESULTS AND DISCUSSION
M0010 test run number two was stopped prior to the full run time due to a process upset in the
area. The run was considered complete and the sample was recovered and submitted for analysis.
A total of two M0010 test runs were performed at the location. A total of three MM18 test runs
were performed at the location.
Table 6-1 provides detailed M0010 test data and test results for Division stack. Table 6-2
provides detailed MM18 test data and test results for the Division stack.
The Method 3A sampling indicated that the O2 and CO2 concentrations were at ambient air
levels (20.9% O2, 0% CO2), therefore, 20.9% O2 and 0% CO2 values were used in all
calculations.
It should be noted that methylene chloride was identified in the MM18 analytical results. This
detection was due to a special procedure done in the process area in which methylene chloride
was used to unplug equipment that experienced plugging during testing. Methylene chloride
would not typically be detected in this process area.
1/2/2020 11:03 AM
20
112219 Div Stack M0010
Test Data
Run number 1 2
Location Divison Stack Divison Stack
Date 11/22/19 11/22/19
Time period 0826-1022 1139-1324
SAMPLING DATA:
Sampling duration, min.96.0 84.0
Nozzle diameter, in.0.160 0.160
Cross sectional nozzle area, sq.ft.0.000140 0.000140
Barometric pressure, in. Hg 30.02 30.02
Avg. orifice press. diff., in H2O 1.40 1.00
Avg. dry gas meter temp., deg F 57.0 65.2
Avg. abs. dry gas meter temp., deg. R 517 525
Total liquid collected by train, ml 34.4 21.5
Std. vol. of H2O vapor coll., cu.ft.1.6 1.0
Dry gas meter calibration factor 0.9972 0.9972
Sample vol. at meter cond., dcf 63.136 47.088
Sample vol. at std. cond., dscf (1)64.704 47.462
Percent of isokinetic sampling 101.0 100.5
GAS STREAM COMPOSITION DATA:
CO2, % by volume, dry basis 0.0 0.0
O2, % by volume, dry basis 20.9 20.9
N2, % by volume, dry basis 79.1 79.1
Molecular wt. of dry gas, lb/lb mole 28.84 28.84
H20 vapor in gas stream, prop. by vol.0.024 0.021
Mole fraction of dry gas 0.976 0.979
Molecular wt. of wet gas, lb/lb mole 28.57 28.61
GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATA:
Static pressure, in. H2O -0.35 -0.35
Absolute pressure, in. Hg 29.99 29.99
Avg. temperature, deg. F 72 79
Avg. absolute temperature, deg.R 532 539
Pitot tube coefficient 0.84 0.84
Total number of traverse points 12 12
Avg. gas stream velocity, ft./sec.82.0 69.9
Stack/duct cross sectional area, sq.ft.7.07 7.07
Avg. gas stream volumetric flow, wacf/min.34799 29659
Avg. gas stream volumetric flow, dscf/min.33787 28485
(1)Standard conditions = 68 deg. F. (20 deg. C.) and 29.92 in Hg (760 mm Hg)
TABLE 6-1
CHEMOURS - FAYETTEVILLE, NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTS
DIVISION STACK
1/2/2020 11:03 AM
21
112219 Div Stack M0010
TEST DATA
Run number 1 2
Location Divison Stack Divison Stack
Date 11/22/19 11/22/19
Time period 0826-1022 1139-1324
LABORATORY REPORT DATA, ug.
HFPO Dimer Acid 22.31 33.88
EMISSION RESULTS, ug/dscm.
HFPO Dimer Acid 12.17 25.20
EMISSION RESULTS, lb/dscf.
HFPO Dimer Acid 7.60E-10 1.57E-09
EMISSION RESULTS, lb/hr.
HFPO Dimer Acid 1.54E-03 2.69E-03
EMISSION RESULTS, g/sec.
HFPO Dimer Acid 1.94E-04 3.39E-04
TABLE 6-1 (cont.)
CHEMOURS - FAYETTEVILLE, NC
SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTS
DIVISION STACK
1/21/202010:39 AM 22 112219 Div Stack MM18
TEST DATA
Test run number 1 2 3
Location Division Stack Division Stack Division Stack
Test date 11/22/19 11/22/19 12/4/19
Test time period 0826-1022 1139-1318 0955-1125
Operator WF WF KS
SAMPLING DATA
Duration, minutes 84 78 90
Average dry gas meter press. in. H2O 3.41 3.56 5.00 Average dry gas meter temp. deg. F 54.9 66.00 54.50
Average absolute meter temp. deg. R 514.9 526.0 514.5
Sample vol. at meter cond., dcl 143.580 147.394 159.313
Meter box calibration, Y 0.9996 0.9996 1.0140
Barometric pressure, in. Hg 30.02 30.02 30.12
Sample volume, dscl (1)148.843 149.624 168.860
Sample volume, dscf (1)5.256 5.283 5.963
VOLUMETRIC FLOW RATE
Avg. gas stream volumetric flow, dscf/min.33,787 28,485 31,136
(1) Standard conditions = 68 deg. F. (20 deg. C.) and 29.92 inches Hg (760mm Hg).
TABLE 6-2
CHEMOURS-FAYETTEVILLE, NC
INPUTS FOR EPA MM18 TARGET COMPOUND CALCULATIONS
DIVISION STACK
1/21/202010:39 AM 23 112219 Div Stack MM18
TEST DATA
Run number 1 2 3
Location Division Stack Division Stack Division Stack
Date 11/22/19 11/22/19 12/4/19
Time period 0826-1022 1139-1318 0955-1125
LABORATORY REPORT DATA, ug.
<40.9 <29 <30.2
HFPO Monomer 3497.4 3507 22080
Fluoroether E-1 272 743 277.7
<125 <88.7 <92.3
Total Fluorine 67940 66200 160830
Hydrogen Fluoride <1700 <1210 <1260
EMISSION RESULTS, ug/dscm.
<2.75E+02 <1.94E+02 <1.79E+02
HFPO Monomer 2.35E+04 2.34E+04 1.31E+05
Fluoroether E-1 1.83E+03 4.97E+03 1.64E+03
<8.40E+02 <5.93E+02 <5.47E+02
Total Fluorine 4.56E+05 4.42E+05 9.52E+05
Hydrogen Fluoride <1.14E+04 <8.09E+03 <7.46E+03
EMISSION RESULTS, lb/dscf.
<1.72E-08 <1.21E-08 <1.12E-08
HFPO Monomer 1.47E-06 1.46E-06 8.16E-06
Fluoroether E-1 1.14E-07 3.10E-07 1.03E-07
<5.24E-08 <3.70E-08 <3.41E-08
Total Fluorine 2.85E-05 2.76E-05 5.95E-05
Hydrogen Fluoride <7.13E-07 <5.05E-07 <4.66E-07
EMISSION RESULTS, lb/hr.
<3.48E-02 <2.07E-02 <2.09E-02
HFPO Monomer 2.97E+00 2.50E+00 1.53E+01
Fluoroether E-1 2.31E-01 5.30E-01 1.92E-01
<1.06E-01 <6.33E-02 <6.38E-02
Total Fluorine 5.78E+01 4.72E+01 1.11E+02
Hydrogen Fluoride <1.45E+00 <8.63E-01 <8.70E-01
EMISSION RESULTS, g/sec.
<4.38E-03 <2.60E-03 <2.63E-03
HFPO Monomer 3.74E-01 3.15E-01 1.92E+00
Fluoroether E-1 2.91E-02 6.67E-02 2.41E-02
<1.34E-02 <7.96E-03 <8.03E-03
Total Fluorine 7.27E+00 5.94E+00 1.40E+01
Hydrogen Fluoride <1.82E-01 <1.09E-01 <1.10E-01
Note: All < values were below the laboratory analysis detection limits. The value shown is the method detection limit (MDL) for the first analytical
fraction of the target compound in order to develop emission rates.
TABLE 6-2 (cont.)
CHEMOURS - FAYETTEVILLE, NC
SUMMARY OF EPA MM18 TARGET COMPOUND TEST DATA AND TEST RESULTS
Carbonyl Difluoride
Carbonyl Difluoride
Carbonyl Difluoride
Carbonyl Difluoride
Carbonyl Difluoride
HFPO Dimer Methyl Ester
HFPO Dimer Methyl Ester
HFPO Dimer Methyl Ester
HFPO Dimer Methyl Ester
HFPO Dimer Methyl Ester
IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX A
PROCESS OPERATIONS DATA
24
Division
Date: 11/22/2019
Time
Stack Testing
HFPO
VEN Product
VEN Precursor
VEN Condensation (HFPO)
VEN ABR
VEN Refining
Stripper Column Vent
Division WGS Recirculation Flow
Division WGS Inlet Flow
Date: 12/4/2019
Time
Stack Testing
HFPO
VEN Product
VEN Precursor
VEN Condensation (HFPO)
VEN ABR
VEN Refining
Stripper Column Vent
Division WGS Recirculation Flow
Division WGS Inlet Flow
800 900 1000 1100 1300 1400 1500 1600
RUN 1: 0826-1022 RUN 2 - 1139-1320
1200
PPVE
Burnout
15,000 kg/h
142 kg/h 145 kg/h 148 kg/h 150 kg/h 135 kg/h 128 kg/h 74 kg/h103 kg/h
RUN 3 0955-1125
PPVE
800 900 1000 1100
15,000 kg/h
65 kg/h 73 kg/h 110 kg/h
25
IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX B
RAW AND REDUCED TEST DATA
26
Sample and Velocity Traverse Point Data Sheet -Method 1
Client CJ::tl 1\1 eAA.I\,� Operator � Loact1on/Plant Vlt':f t, {;fcu, I le, /v. �Date / 2J-. !l
Source (}, v: ,,�.;,,..) _5 �-rj(.L. W O Number J,T(t� . ..!:O .�
Duct Type "' Circular D Rectangular Duct Indicate eppropMate type
Traverse Type II( Particulate Traverse D Velocity Traverse D CEM Traverse
Distance from far wall to outside of oort lln. l = C <:°<""'"" /) Flow Disturbances -Port Deoth (in.) = D 12"1'.� u:r Upstream - A (ft) (1� � (t I
Deoth or Duct, diameter (in.I= C-D �I"' '(I Area of Duct (ff) ,,,, -11 � 7 01 -, , -� . --Total Traverse Points 1 \ I t\,\J,fa.
Total Traverse Points oer Port ,, . �
Port Diameter fln.l-/Flanae-Threaded-Holel l/ I/
Monorail Lenoth t).
Rectangular Ducts Onty
Width of Duct, rectanaular duct only (In. I / Total Ports (rectanoular duct only) / Eauivalent Diameter= 12·L 'Wl/(L+W) / ,.
Traverse Point Locations
Distance from Traverse Inside Duct Distance1from Outside of Point % of Duct Wall{inl /Port/in) 1, 1 'i I 1.-\ I, b2 jtµ/,;, '1,£>
2 , ...., (,,.'>.'-/0 h A il1, 'l y :>f-uir. 7 ,vr
3 2.'1 " I0,9S-ti�·\ 1T 1/e 1�. t.J ?l,,,D""I ,,� 1 'I.'> 4 '7"/, V
5
6
7
8
10
11
12
1
2
3
9S: 'i 31 �9 l{-� t
Cf5.lv 35.)7 $"� f� '-.. L
�,4.Mre} (�
CEM 3 Polnl(Long Measurm•nt Un•) StraUflcaton PO,nt Locations
0.167
0.50
0.833 Note: If stack dla < 12 inch use EPA Method 1A (Sample port upstream of pilot port) Note: � stack dia >24" then adjust traverse point to 1 inch from wall If stack dia <.24" then adjust traverse point to 0.5 inch from wall
l 2 T I 146 r 2 85.4 . ) 'L 4 • 0 r C 5
• a 6 o I 7
8 p 0 o n 9
I 10 n II
12
Traverso Point Location Ptrcant of Stack .Circular
J 4 6.7
25
75 ,:i.;
NwnberofT IPoints 5 6 8 4.4 3.2 14.6 tQ.5
29.6 19.4
70.4 :12.3 85.4 67.7
95.6 8D.6
89.5 96.B'
9 10
26 82
14.6 22.6
)42
65.8 77.4 115.4
91.8 97.4
ll
tf<r
·'ltt
12 2.1 6.7 118
11.1 25
l5.6
64.4
15
82.3 w
9).3
97.9
Downstream - B (ft) -91 ;}Qt
Upstream - A (duct diameters\ ,."t.
Downstream - B /duct diameters) "'61Diagram of Stack
11 ::::;;,_ ..---" /
<'.l� ' I>-ry ·i 5D ...-
j .--
Duct 0·1ameters Upstream from Flow Disturbance (Distance A}
05 1 0 1 5 2.0 25 50 I I I I I I I
Stack Diameter> 24 Inches °""""""' t
40 -A
±. ---� -�·Minimum Number cf • l ...
JO -Particulate Traverse Points l .,....._. 24 (ch::ular) 25 (mctangulw dl.Jd.<l.)
�
20 -
Traverse Polllls for Velocity 16
12 I �
10 ,_ {Disturbance =Band, Expansion, Contraction, etc } B(tmJiir)lilj�
S1ad,.Dlaar�Dti."12.24Rnefl
4
Duct Dlemehn Downstraam from Ac,.v Dl!1furbance (Olslenca B)
Travers, Point Location Pan:ent of Stack �ootanaular NIJ!lber ofTnr.,ne Polnls I 2 l 4 5 6 7 8 9 10 II ll
T I 250 167 125 100 8.J 7.1 6.J 5.6 5.0 4.5 41 ' 2 7S.O 51l0 31J 30.0 25.!J ZIA 18.J 16.7 IS.II ll.li 11.l . J 8) 3 62.5 500 417 )5.7 JU 27.8 250 22.7 208 ,l 4 '7.5 70.!I ID 511.0 43.1 :IU 310 31.8 29.Z ,o '' 5 90.0 75.0 60 563 500 4S.O 40.9 Jl.l ' a 6 91.1 'JU 61.1 !U ru :!tea 45.8 'I 7 C/2.9 813 72.2 65.0 ;9.1 l4.l i tu w 75.0 42 /ill p 0 o n i 94.4 85.0 m 708
I 10 i5JI 116.4 19.1 " II 955 875 12 !J!;JI
'
27
CHEMOURS - FAYETTEVILLE, NC
INPUTS FOR HFPO DIMER ACID CALCULATIONS
DIVISION STACK
Test Data
Run number 1 2
Location Divison Stack Divison Stack
Date 11/22/19 11/22/19
Time period 0826-1022 1139-1324
Operator BB BB
Inputs For Calcs.Sq. rt. delta P 1.45039 1.22804Delta H 1.4025 1.0010Stack temp. (deg.F)71.6 79.4Meter temp. (deg.F)57.0 65.2Sample volume (act.)63.136 47.088Barometric press. (in.Hg)30.02 30.02
Volume H2O imp. (ml)10.0 7.0
Weight change sil. gel (g)24.4 14.5
% CO2 0.0 0.0
% O2 20.9 20.9
% N2 79.1 79.1
Area of stack (sq.ft.) 7.070 7.070
Sample time (min.)96.0 84.0
Static pressure (in.H2O)-0.35 -0.35
Nozzle dia. (in.)0.160 0.160
Meter box cal.0.9972 0.9972
Cp of pitot tube 0.84 0.84
Traverse points 12 12
1/2/2020 11:02 AM 112219 Div Stack M001028
ISOKINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Dimer Acid Page J~ orb
client chemours Stack Conditions Meter Box ID K Factor Q w.o.# 15418.002.018 Assumed Actual MeterBox Y ,rjq'7 a
Project ID Chemours %Moisture ^~ 3 Meter Box Del H ~ , $'j ~~ Illltlal Mid-Point Final
Mode/Source ID Division Impinger Vol (ml) Probe ID /Length L~~ ~ ` Sample Train (ft3) o , o D 5 GAO U, (~(~
Samp. Loc. ID STK Silica gel (g) Probe Material ~Boro Leak Check @ (in Hg) `~ ~ S ~~ ~"
Run No.ID 1 CO2, °/ by Vol Q Pitot /Thermocouple ID Pitot leak check good yes no / no / no
Test Method ID M0010 02, % by Vol ~ ~ Pitot Coe~cient 84~r Pitot Inspection good / no ye / no ! no
Date ID NOV2019 Temperature (°F) ~ Noale ID ~~ Method 3 System good yes ! no yes / no yes / no
Source/Location Div(sion Stack Meter Temp (F) l.~ Noale Measurements , ~ 6 p . ~ LO Temp Check re-Test Set POSt-Test Set
Sample Date ~ Static Press (in H2O) — ~ 3 ~j ~J Avg Noale Dia (in) ~ ~ 6 • ~/ Meter Box Temp
Baro. Press (in Hg) Area of Stack (ftz) , Q~ Reference Temp
Operator Ambient Temp (°F) ~ ~ Sample Time `~ (~ ,/ PasslFail (+/- 2°~ Pass /Fail Pass /Fail
Total Traverse Pts ~ a Temp Change Response ~ yes / no yes / no
~~r~~~-
~~—~~ ~ ~ ~ ~ ~ i ~~~~—
~~-~~~Iti•1~~~ • ~~~~~~~_'~~
~~-~ I ~~~~~~~~~- ~~~
a,vg uena r ( ,vvg uerca ry a. ~ ~,''Ib J
Ava Sart Delta P Avo Sart Dei t
i oral vowme~ (b ,vvg i s
~~~
nments: J ~lr ~
~~~~13~
✓J
,vvg i m J rvun~nnax rvunlnnax nnax rwax vac nnin~rv~ax ~~. d <<u~~~~ te6~~~~( sq g H~ly~
EPA Method 0010 from EPA SW- 46
(~ Q'~ ~~~
29
ISOHINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Dimer Acid Page ~ or '1
Client Chemours Stack Conditions Meter Box ID qq~ ~ K Factor ~ 6 W.O.# 15418.002.018 Assumed Actual Meter Box Y
Project ID Chemours %Moisture ~ Meter Box Del H (, g"j ► ~ Init181 Mid-Point FIn81
Mode/Source ID Division Impinger Vol (ml) Probe ID /Length H q 4 ~ 6~ Sample Train (ft3) ~ Oo ~ jj ~
Samp. Loc. ID STK Silica gel (g)
—~
Probe Material Boro Leak Check @ (in Hg) ~
Run No.ID 2 CO2, % by Vol Pitot /Thermocouple ID Pitot leak check good ~/ no e / no yes / np
Test Method ID M0010 02, °/ by Vol ~ q Pitot Coefficient 0.84 Pitot Inspection good ! no e ! no yes / no
Date ID
S /L
NOV2019 Temperature (°F)
MeterT m "F
~~ Noale ID Method 3 S stem ood Y 9 Yes / no yes / no yes / no ource ovation Diviswn Stack e P ( ) Noale Measurements ,I b~ . ~ 60 . ~ (,~ Temp Check Pre-Test et Post-Test Set
Sample Date ~ ~ 'a — ( Static Press (in Hz0) ,. —~ '3 ,/Avg Noale Dia (in) . ( ~/ Meter Box Temp
Baro. Press (in Hg) Q. Area of Stack (ft2) Reference Temp
Operator Ambient Temp (°F) SQ Sample Time _.q.~--`~j Pass/Fail (+/- 2°) Pass /Fail Pass /Fail
Total Traverse Pts ~ ;~ Temp Change Response ; yes / no ves ! no
•
—~~~~ ~ •
~~~~--- ~~~
~~—~~ ~ r ~ ~~~~~-
1,.~,__.2~ :000~5~
Avg Sgrt Delta P Avg Sgrt Del
t-#~`.~~5' ~~~~~~~
................. ,,•y •~ r.. ~.~~~~~~~a~ miuimnn man max vac mnuPnax
~~. flg~ ~1q,~1 l..o ,~.-- QOIl2(.o g3(tl5 (a~ (v ~I`b~(o0
Comments: EPA Method 0010 from EPA SW-846
,_ t~~~~_~-30
SAMPLE RECOVERY FIELD DATA
EPA Method 0010 - HFPO Diener Acid
Client
Location/Plant
Chemours
Fayetteville, NC
W.O. #
Source &Location
15418.002.018
Division Stack
Run No. 1 Sample Date /` , ~ f ~ Recovery Date ~l
Sample I.D. Chemours -Division - STK - 1 - M0010 - Analyst ~_ Filter Number
Impin er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents Empty HPLC H2O HPLC H2O Silica Gel
Final ~ ~ ~ ~ ~ , ~~ + ; a
Initial (7 goo goo soo
Gain ~ ~ v ~ ,,
Impinger Color ~~ ~j ~„~ j~ Labeled? .,
Silica Gel Condition Sealed?
Run No. 2 Sample Dafe ~~ /~Z ~~ Recovery Date ~~ y~
Sample I.D. Chemours -Division - STK - 2 - M0010 - Analyst ~ Filter Number
Impin er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents Empty HPLC H2O HPLC H2O Silica Gel
Final
~
~ /
- Q a /r,
~~
7
Initial ~ goo goo soo
Gain ~ ~ ~ f ~,% p~ .
Impinger Color ~' G~ ~ ~ Labeled? ~~ '~
' ~ l Silica Gel Condition Vt.• ~ Sealed? 3
Run No. 3 Sample Date Recovery Date
Sample I.D. Chemours -Division - STK - 3 - M0010 - Analyst Filter Number
Impin er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents Empty HPLC H2O HPLC H2O Silica Gel
Final
Initial goo goo soo
Gain
Impinger Color Labeled?
Silica Gel Condition Sealed?
Check COC for Sample IDs of Media Blanks
`~~~J~ ~~~~~ ~~
31
1/21/202010:28 AM 112219 Div Stack MM18
TEST DATA
Test run number 1 2 3
Location Division Stack Division Stack Division Stack Test date 11/22/19 11/22/19 12/4/19
Test time period 0826-1022 1139-1318 0955-1125
Operator WF WF KS
SAMPLING DATA
Duration, minutes 84 78 90
Average dry gas meter press. in. H2O 3.41 3.56 5.00
Average dry gas meter temp. deg. F 54.9 66.00 54.50
Average absolute meter temp. deg. R 514.9 526.0 514.5
Sample vol. at meter cond., dcl 143.580 147.394 159.313
Meter box calibration, Y 0.9996 0.9996 1.0140
Barometric pressure, in. Hg 30.02 30.02 30.12
Sample volume, dscl (1)148.843 149.624 168.860
Sample volume, dscf (1)5.256 5.283 5.963
VOLUMETRIC FLOW RATE
Avg. gas stream volumetric flow, dscf/min.33,787 28,485 31,136
(1) Standard conditions = 68 deg. F. (20 deg. C.) and 29.92 inches Hg (760mm Hg).
CHEMOURS-FAYETTEVILLE, NC
INPUTS FOR EPA MM18 TARGET COMPOUND CALCULATIONS
DIVISION STACK
32
FIELD DATA SHEET
Client Chemours Run No.
W.O.# 15418.002.018 Test Method
Project ID CHEM-F Date
Mode/Source ID Division Baro. Press (in Hg)
Samp. Loc. Stack Ambient Temp (°F)
Source Division Stk Operator
Sample Time
Comments: Initial Probe Leak check:
Final Probe Leak check:
MM 1 S - HFPO Diener Acid Page ~ of ~
1 Meter Box ID
Modified M18 Meter Box Y Q ' G
Nov. 2019 Probe ID/Length Leak Check @ (in Hg) (~,~~ ~„~~~ I I (~,Q (1~,,.~ ~
,3Q, (~Z Probe Material Pitot leak check good yec.Lpry yes / no ..y~uc_L.aw
• ~
~~- ~~ ~~
' ~ ~~ ~ --~
------ --
Avg Delta H Total Volume / Avg Tm Max Temp Max Vac Max Temp
33
FIELD DATA SHEET
Client
W .O.#
Project ID
Mode/Source ID
Samp. Loc.
Source
Comments:
Chemours Run No.
15418.002.018 Test Method
CHEM-F Date
Division Baro. Press (in Hg)
Stack Ambient Temp (°F)
Division Stk Operator
Sample Time
Initial Probe Leak check:
Final Probe Leak check:
MM 18 - HFPO Dimer Acid
2 Meter Box ID ~0
Modified M18 Meter Box Y G~ , ,~+
Nov. 2019 Probe ID/Length Leak Check @ (in Hg)
~(~ , p ~ Probe Material Pitot Teak check good
da
W
~~ ~«
Page ~ of
p.JCH ~~~
yes / no yes ! no
~~~~ r ~~~rl~~~f~r~~~~ ~ ~ ~m~ - ~'c~1 ~~~P~~~~i~ ' ' ~ ~m~ ~~~c~~~~!~l~~~:~ ~
m. ~ ~"_-1'
~~:•s~s7xix~~ra.x a ..
Hvg ueita n ~ i otai volume
3.5~ ~ I~1,~~
Hvg i m Hoax I emp Max Vac Max Temp
l~ ~
34
~~v S~~-
~'"Ll~,
SAMPLE RECOVERY FIELD DATA
Client "r~i?'4 ~`~, W.O. #
Location/Plant ~ ~,}~ „— r Source &Location J I~
Run No. Sample Date ~~~''~ /~ ` Recovery Date > ~
Sample I.D. ~ ~'~(~ Analyst ~ ~ Filter Number
Im in er
1 2 3 4 5 6 7 Im .Total 8 Total
Contents Silica Gel
Final ~~ ~~j~zj. ~. ~~%7i ~ ~. ~ `?~'. 1
Initial ~ G~ ; ~~ ~ ~ :~~ ! ~ ~ ~ utJ,~ ~d
ca~~ 'I3 ~-; -_~ ,, i
ImpingerColor ~A~j~=~~ Labeled?
—~ Silica Gel Condition Sealed?
Run No. ~ Sample Date ~ ~~ Recovery Date /~"~~
Sample I.D. Analyst Filter Number ~~
Im in er
1 2 3 4 5 6 7 Imp.Totai 8 Total
Contents Silica Gel
Final ~~r ~ ' 1o~i'(~ ~'0~ '~ ~Os
Initial ~ rs b~~~~ ~~~' ~~ Q ~~ f
Gain ~s d d /,.
Impinger Color ~j (./ ~ Labeled?
Silica Gel Condition Sealed?
Run No. lf,~ Sample Dated ~ , ~ ! Recovery Date ~~ 't—/
Sample I.D. ~ Analyst Filter Number
Im in er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents Silica Gel
Final ~ t ~~r ~ b s ~ ~ 0 ~1 ~~/~ b~
initial ~ ~ = ~ v b ~~> ~ ~ ~~, - ~j
Gain ~ 4 ~G(~j.~ ~
Impinger Color -~ .~. La~ed?
Silica Gel Condition Sealed?
Check COC for Sample IDs of Media Blanks ~
~~
/~
~~
35
FIELD DATA SHEET MM 18
Client Chemours Run No. 1 Meter Box ID
W.O.# 15418.002.018 Test Method Modified M18 Meter Box Y D I~{
Project ID CHEM-F Date ~'I Dec. 2019 Probe ID/Length Leak Check @ (in Hg)
Mode/Source ID VE NoRh Baro. Press (in Hg) 3~~ Probe Mate~ai Pitot leak check good
Samp. Loc. Stack Ambient Temp (°F) O
Source Division Operator f
Sample Time ~~ M;~?
Comments: Initial Probe Leak check: ~~! a. ~~p►i~
Final Probe Leak check: ~,~i y?, ~r~~~'p
Page ~ of
yes / no yes / no yes / no
a~ ~a~~~ o~r~~~.~
~~~ ~~~~a~ ~~~ ~
~~~~ I ~~ ~~ " ~ ~
~~~~~~►'~~~ ~~~~em~~
--- -- ~~-
--~ -- ~~-..,~.. Avg Delta HJ Total Volume Avg Tm Max'Temp Max Vac Max Temp
36
SAMPLE RECOVERY FIELD DATA
Client ~ "~ ►'lam C~1'` s W.O. # l~ 4 l~ >~ti~-=~~. ~vi
LocatioNPlant r-c~, t~ Source &Location ~ C JV~3c- — ~ y~~ ~,~ 5
Run No. 3 Sample Date Iz-~ ~-1 '— j ~ Recovery Date ~~9
Sample I.D. Analyst Filter Number i? l~
Im in er
1 2 3 4 5 6 7 Im .Total 8 Total
Contents Silica Gel
Final 4 ~ ~ G~. U ~,O ~ ~ C1 ~~ 3. ~ _
Initial ~ ~?, ~ C1~ • ~- L ~c3~-~j ~, , 13,~
Gain C~ ~ d + t ~ ~ ~L O ~ ~ ~ v' r ! C7 r
Impinger Color ______~~ Labeled? r
Silica Gel Condition +'~U Sealed?
Run No. Sample Date Recovery Date
Sample I.D. Analyst Filter Number
Im in er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents ~ Silica Gel
Final
Initial ~~.~, ~~.0 607,`? ~C~, ~~ ~~ , ~ f.3 ~3
Gain
Impinger Color Labeled?
Silica Gel Condition Sealed?
Run No. Sample Date Recovery Date
Sample I.D. Analyst Filter Number
Im in er
1 2 3 4 5 6 7 Imp.Total 8 Total
Contents Silica Gel
Final
Initial
Gain
Impinger Color Labeled?
Silica Gel Condition Sealed?
Check COC for Sample IDs of Media Blanks ~`
.k3aT~AF c .
37
IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX C
LABORATORY ANALYTICAL REPORT
38
ANALYTICAL REPORT
Job Number: 140-17458-1
Job Description: VEN Stack - M0010
Contract Number: LBIO-67048
For:
Chemours Company FC, LLC The
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, DE 19713
Attention: Michael Aucoin
_____________________________________________
Approved for release.
Courtney M Adkins
Project Manager II
12/10/2019 3:07 PM
Courtney M Adkins, Project Manager II
5815 Middlebrook Pike, Knoxville, TN, 37921
[phone]
[e-mail]
12/10/2019
This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at
the e-mail address or telephone number listed on this page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any
exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be
directed to the Eurofins TestAmerica Project Manager.
This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a
traditionally handwritten signature.
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike, Knoxville, TN 37921
Tel [phone] Fax [phone] www.testamericainc.com
12/10/2019Page 1 of 21339
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .4
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .11
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .15
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .18
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .22
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .24
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
LCMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
8321A_HFPO_Du . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .25
8321A_HFPO_Du QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .26
8321A_HFPO_Du Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .32
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .40
8321A_HFPO_Du ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .40
8321A_HFPO_Du CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .63
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .75
8321A_HFPO_Du Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .75
8321A_HFPO_Du Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .80
8321A_HFPO_Du LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .92
12/10/2019Page 2 of 21340
Table of Contents
8321A_HFPO_Du Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .105
8321A_HFPO_Du Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .107
Method DV-LC-0012 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .114
Method DV-LC-0012 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .115
Method DV-LC-0012 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .123
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .147
Method DV-LC-0012 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .147
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .165
Method DV-LC-0012 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .165
Method DV-LC-0012 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .170
Method DV-LC-0012 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .182
Method DV-LC-0012 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .198
Method DV-LC-0012 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .200
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 206
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .207
12/10/2019Page 3 of 21341
Definitions/Glossary
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
Qualifiers
LCMS
Qualifier Description
*LCS or LCSD is outside acceptance limits.
Qualifier
B Compound was found in the blank and sample.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Knoxville
12/10/2019Page 4 of 21342
Method Summary
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
Method Method Description LaboratoryProtocol
SW8468321AHFPO-DA TAL DEN
SW8468321APFOA and PFOS TAL DEN
TAL SOPNoneLeaching Procedure TAL DEN
TAL SOPNoneLeaching Procedure for Condensate TAL DEN
TAL SOPNoneLeaching Procedure for XAD TAL DEN
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL DEN = Eurofins TestAmerica, Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
Eurofins TestAmerica, Knoxville
12/10/2019Page 5 of 21343
Sample Summary
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-17458-1 G-2577,2578 DIV VEN STACK R1 M0010 FH Air 11/22/19 00:00 11/25/19 08:00
140-17458-2 G-2579,2580,2582 DIV VEN STACK R1 M0010
BH
Air 11/22/19 00:00 11/25/19 08:00
140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS
1,2&3 COND
Air 11/22/19 00:00 11/25/19 08:00
140-17458-4 G-2583 DIV VEN STACK R1 M0010
BREAKTHROUGH XAD-2 RESIN TUBE
Air 11/22/19 00:00 11/25/19 08:00
140-17458-5 G-2584,2585 DIV VEN STACK R2 M0010 FH Air 11/22/19 00:00 11/25/19 08:00
140-17458-6 G-2586,2587,2589 DIV VEN STACK R2 M0010
BH
Air 11/22/19 00:00 11/25/19 08:00
140-17458-7 G-2588 DIV VEN STACK R2 M0010 IMPINGERS
1,2&3 COND
Air 11/22/19 00:00 11/25/19 08:00
140-17458-8 G-2590 DIV VEN STACK R2 M0010
BREAKTHROUGH XAD-2 RESIN TUBE
Air 11/22/19 00:00 11/25/19 08:00
Eurofins TestAmerica, Knoxville
12/10/2019Page 6 of 21344
Job Narrative
140-17458-1
Sample Receipt
The samples were received on November 25, 2019 at 8:00 AM in good condition and properly preserved. The temperature of the cooler
at receipt was 1.6º C.
Quality Control and Data Interpretation
Unless otherwise noted, all holding times, and QC criteria were met and the test results shown in this report meet all applicable NELAC
requirements.
Method 0010/Method 3542 Sampling Train Preparation
Train fractions were extracted and prepared for analysis in TestAmerica’s Knoxville laboratory. Extracts and condensate samples were
forwarded to the Denver laboratory for HFPO-DA analysis. All results are reported in “Total ug” per sample.
LCMS
Method 8321A: The following samples were inadvertently spiked with a native solution of HFPO-DA rather than the isotope dilution
internal standard prior to extraction in the Knoxville Laboratory.
· DIV VEN Stack R1 FH
· DIV VEN Stack R1 BH
· DIV VEN R1 Breakthrough
· DIV VEN Stack R2 FH
· DIV VEN Stack R2 BH
· DIV VEN R2 Breakthrough
As a result, these samples received a relatively small fortification of the native HFPO-DA, and no labeled IDA as typically applied. Upon
discovery of the processing issue, the IDAs were post spiked onto the extracted samples which were then re-analyzed to acquire the
Total HFPO-DA content in the samples. The spiked amount of native HFPO-DA was subsequently subtracted from the Total HFPO-DA,
and the corrected concentration is reported in with the data set below.
Please note that under these conditions, the affected samples are not corrected for extraction losses through isotope dilution internal
standard data reduction. However, the HFPO-DA concentrations are accurate and useful for their intended purpose.
Method 8321A: The laboratory control sample (LCS) and / or laboratory control sample duplicate (LCSD) for preparation batch
280-478940 and analytical batch 280-479928 recovered outside control limits for the following analytes: HFPO. These analytes were
biased high in the LCS and were not detected in the associated samples; therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
12/10/2019Page 7 of 21345
Chemours VES Carbon Bed Outlet Test Analytical Report
TestAmerica Job No. 140-17458-1
December 10, 2019
O:\Users Folders\AdkinsC\Project Documents\Special Reporting\Chemours Corrected Values\Fayetteville\Chemours Corrected Results
HFPO-DA_DIV VEN Stack_12102019.docx Created on 01/30/2018 Last edited on 12/10/2019 3:02 PM
The following samples were inadvertently spiked with a native solution of HFPO-DA prior to extraction
in the Knoxville laboratory:
DIV VEN Stack R1 FH
DIV VEN Stack R1 BH
DIV VEN R1 Breakthrough
DIV VEN Stack R2 FH
DIV VEN Stack R2 BH
DIV VEN R2 Breakthrough
The HFPO-DA results presented below have been corrected to remove the laboratory contribution from
the final result.
TALS ID Client ID HFPO-DA Result
(ug/sample)
HFPO-DA Added
in the lab
(ug/sample)
HFPO-DA
Corrected Result
(ug/sample)
140-17458-1 DIV VEN Stack
R1 FH
9.86 2 7.86
140-17458-2 DIV VEN Stack
R1 BH
21.3 7 14.3
140-17458-4 DIV VEN R1
Breakthrough
2.30 4 ND
140-17458-5 DIV VEN Stack
R2 FH
6.58 2.5 4.08
140-17458-6 DIV VEN Stack
R2 BH
36.3 6.5 29.8
140-17458-8 DIV VEN R2
Breakthrough
2.19 4 ND
12/10/2019Page 8 of 21346
QC Association Summary
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
LCMS
Analysis Batch: 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-464589/13 Lab Control Sample Total/NA
Prep Batch: 478940
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-17458-1 G-2577,2578 DIV VEN STACK R1 M0010 FH Total/NA
Air None140-17458-5 G-2584,2585 DIV VEN STACK R2 M0010 FH Total/NA
Air NoneMB 280-478940/14-A Method Blank Total/NA
Air NoneMB 280-478940/1-A Method Blank Total/NA
Air NoneLCS 280-478940/2-A Lab Control Sample Total/NA
Air NoneLCSD 280-478940/3-A Lab Control Sample Dup Total/NA
Prep Batch: 478993
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS 1,2&3 CONDTotal/NA
Air None140-17458-7 G-2588 DIV VEN STACK R2 M0010 IMPINGERS 1,2&3 CONDTotal/NA
Air NoneMB 280-478993/14-A Method Blank Total/NA
Air NoneMB 280-478993/1-A Method Blank Total/NA
Air NoneLCS 280-478993/2-A Lab Control Sample Total/NA
Air NoneLCSD 280-478993/3-A Lab Control Sample Dup Total/NA
Prep Batch: 479245
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-17458-2 G-2579,2580,2582 DIV VEN STACK R1 M0010 BHTotal/NA
Air None140-17458-4 G-2583 DIV VEN STACK R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air None140-17458-6 G-2586,2587,2589 DIV VEN STACK R2 M0010 BHTotal/NA
Air None140-17458-8 G-2590 DIV VEN STACK R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air NoneMB 280-479245/1-A Method Blank Total/NA
Air NoneLCS 280-479245/2-A Lab Control Sample Total/NA
Air NoneLCSD 280-479245/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 479814
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 478993140-17458-3 G-2581 DIV VEN STACK R1 M0010 IMPINGERS 1,2&3 CONDTotal/NA
Air 8321A 478993140-17458-7 G-2588 DIV VEN STACK R2 M0010 IMPINGERS 1,2&3 CONDTotal/NA
Air 8321A 478993MB 280-478993/14-A Method Blank Total/NA
Air 8321A 478993MB 280-478993/1-A Method Blank Total/NA
Air 8321A 478993LCS 280-478993/2-A Lab Control Sample Total/NA
Air 8321A 478993LCSD 280-478993/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 479928
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 478940140-17458-1 G-2577,2578 DIV VEN STACK R1 M0010 FH Total/NA
Air 8321A 478940140-17458-5 G-2584,2585 DIV VEN STACK R2 M0010 FH Total/NA
Air 8321A 478940MB 280-478940/14-A Method Blank Total/NA
Air 8321A 478940MB 280-478940/1-A Method Blank Total/NA
Air 8321A 478940LCS 280-478940/2-A Lab Control Sample Total/NA
Air 8321A 478940LCSD 280-478940/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 479929
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 479245140-17458-2 G-2579,2580,2582 DIV VEN STACK R1 M0010 BHTotal/NA
Eurofins TestAmerica, Knoxville
12/10/2019Page 9 of 21347
QC Association Summary
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
LCMS (Continued)
Analysis Batch: 479929 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 479245140-17458-4 G-2583 DIV VEN STACK R1 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 8321A 479245140-17458-6 G-2586,2587,2589 DIV VEN STACK R2 M0010 BHTotal/NA
Air 8321A 479245140-17458-8 G-2590 DIV VEN STACK R2 M0010 BREAKTHROUGH XAD-2 RESIN TUBETotal/NA
Air 8321A 479245MB 280-479245/1-A Method Blank Total/NA
Air 8321A 479245LCS 280-479245/2-A Lab Control Sample Total/NA
Air 8321A 479245LCSD 280-479245/3-A Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
12/10/2019Page 10 of 21348
Client Sample Results
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
Lab Sample ID: 140-17458-1Client Sample ID: G-2577,2578 DIV VEN STACK R1 M0010 FH
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 9.86 B *0.100 0.0108 ug/Sample 11/27/19 08:04 12/08/19 09:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 133 50 -200 11/27/19 08:04 12/08/19 09:15 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-2Client Sample ID: G-2579,2580,2582 DIV VEN STACK R1
M0010 BH
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 21.3 B 0.350 0.0700 ug/Sample 12/02/19 11:25 12/08/19 09:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 116 50 -200 12/02/19 11:25 12/08/19 09:55 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-3Client Sample ID: G-2581 DIV VEN STACK R1 M0010
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - HFPO-DA
RL MDL
HFPO-DA 0.145 J 0.212 0.0108 ug/Sample 11/27/19 12:36 12/06/19 12:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 116 50 -200 11/27/19 12:36 12/06/19 12:41 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-4Client Sample ID: G-2583 DIV VEN STACK R1 M0010
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 2.30 B 0.200 0.0400 ug/Sample 12/02/19 11:25 12/08/19 09:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 126 50 -200 12/02/19 11:25 12/08/19 09:58 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
12/10/2019Page 11 of 21349
Client Sample Results
Job ID: 140-17458-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - M0010
Lab Sample ID: 140-17458-5Client Sample ID: G-2584,2585 DIV VEN STACK R2 M0010 FH
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 6.58 B *0.125 0.0135 ug/Sample 11/27/19 08:04 12/08/19 09:19 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 136 50 -200 11/27/19 08:04 12/08/19 09:19 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-6Client Sample ID: G-2586,2587,2589 DIV VEN STACK R2
M0010 BH
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 36.3 B 0.325 0.0650 ug/Sample 12/02/19 11:25 12/08/19 10:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 100 50 -200 12/02/19 11:25 12/08/19 10:01 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-7Client Sample ID: G-2588 DIV VEN STACK R2 M0010
IMPINGERS 1,2&3 COND
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - HFPO-DA
RL MDL
HFPO-DA ND 0.196 0.00999 ug/Sample 11/27/19 12:36 12/06/19 12:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 121 50 -200 11/27/19 12:36 12/06/19 12:44 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Lab Sample ID: 140-17458-8Client Sample ID: G-2590 DIV VEN STACK R2 M0010
BREAKTHROUGH XAD-2 RESIN TUBE
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Air Train
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 2.19 B 0.200 0.0400 ug/Sample 12/02/19 11:25 12/08/19 10:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 109 50 -200 12/02/19 11:25 12/08/19 10:04 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
12/10/2019Page 12 of 21350
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17458-1
Project/Site: VEN Stack - M0010
Method: 8321A - HFPO-DA
Prep: None
0.00250HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.00128
Method: 8321A - PFOA and PFOS
Prep: None
0.0250HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.00270
0.100HFPO-DA ug/Sample0.0200
Eurofins TestAmerica, Knoxville
12/10/2019Page 13 of 21351
ANALYTICAL REPORT
Job Number: 140-17461-1
Job Description: VEN Stack - MM-18
Contract Number: LBIO-67048
For:
Chemours Company FC, LLC The
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, DE 19713
Attention: Michael Aucoin
_____________________________________________
Approved for release.
Courtney M Adkins
Project Manager II
12/23/2019 3:00 PM
Courtney M Adkins, Project Manager II
5815 Middlebrook Pike, Knoxville, TN, 37921
[phone]
[e-mail]
12/23/2019
This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at
the e-mail address or telephone number listed on this page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any
exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be
directed to the Eurofins TestAmerica Project Manager.
This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a
traditionally handwritten signature.
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike, Knoxville, TN 37921
Tel [phone] Fax [phone] www.testamericainc.com
12/23/2019Page 1 of 89452
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .14
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .43
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .45
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .46
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .54
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .63
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .64
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .77
Method 8260B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .77
Method 8260B QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .78
Method 8260B Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .93
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .287
Method 8260B ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .287
Method 8260B CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .389
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .437
Method 8260B Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .437
Method 8260B Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .453
Method 8260B LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .461
12/23/2019Page 2 of 89453
Table of Contents
Method 8260B MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .474
Method 8260B Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .482
Method 8260B Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .495
HPLC/IC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .498
Method 9056 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .498
Method 9056 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .499
Method 9056 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .502
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .538
Method 9056 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .538
Method 9056 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .565
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .612
Method 9056 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .612
Method 9056 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .638
Method 9056 MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .644
Method 9056 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .650
Method 9056 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .664
Method 9056A Total Halogens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .667
Method 9056A Total Halogens QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .668
Method 9056A Total Halogens Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .676
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .715
Method 9056A Total Halogens ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .715
Method 9056A Total Halogens CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .740
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .781
Method 9056A Total Halogens Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .781
Method 9056A Total Halogens LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .817
Method 9056A Total Halogens MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .831
12/23/2019Page 3 of 89454
Table of Contents
Method 9056A Total Halogens Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .839
Method 9056A Total Halogens Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .855
Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 864
General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .864
Gen Chem Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .865
Gen Chem Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .866
Gen Chem QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .878
Gen Chem ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .878
Gen Chem Duplicates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .879
Gen Chem MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .880
Gen Chem Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .881
Gen Chem Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .882
Gen Chem Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .884
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 886
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .887
12/23/2019Page 4 of 89455
Definitions/Glossary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Qualifiers
GC/MS VOA
Qualifier Description
*LCS or LCSD is outside acceptance limits.
Qualifier
H Sample was prepped or analyzed beyond the specified holding time
GC/MS VOA TICs
Qualifier Description
H Sample was prepped or analyzed beyond the specified holding time
Qualifier
J Indicates an Estimated Value for TICs
N Presumptive evidence of material.
T Result is a tentatively identified compound (TIC) and an estimated value.
HPLC/IC
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
General Chemistry
Qualifier Description
HF Field parameter with a holding time of 15 minutes. Test performed by laboratory at client's request.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Knoxville
12/23/2019Page 5 of 89456
Method Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL KNX
SW8469056Anions, Ion Chromatography TAL KNX
SW8469041ApH TAL KNX
SW8465050Bomb Preparation Method for Solid Waste TAL KNX
NoneMeOH Prep Methanol Impinger Preparation TAL KNX
Protocol References:
None = None
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
12/23/2019Page 6 of 89457
Sample Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Air 11/22/19 00:00 11/25/19 08:00
140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Air 11/22/19 00:00 11/25/19 08:00
140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Air 11/22/19 00:00 11/25/19 08:00
140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Air 11/22/19 00:00 11/25/19 08:00
140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Air 11/22/19 00:00 11/25/19 08:00
140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Air 11/22/19 00:00 11/25/19 08:00
140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Air 11/22/19 00:00 11/25/19 08:00
140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Air 11/22/19 00:00 11/25/19 08:00
140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Air 11/22/19 00:00 11/25/19 08:00
140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Air 11/22/19 00:00 11/25/19 08:00
140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Air 11/22/19 00:00 11/25/19 08:00
140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Air 11/22/19 00:00 11/25/19 08:00
Eurofins TestAmerica, Knoxville
12/23/2019Page 7 of 89458
Job Narrative
140-17461-1
Sample Receipt
The samples were received on November 25, 2019 at 8:00 AM in good condition and properly preserved. The temperature of the cooler
at receipt was 1.6º C.
GC/MS VOA
Impinger Sample Preparation and Analysis: Impinger samples were analyzed for the volatile organic target analytes by purge and trap
GCMS using Eurofins TestAmerica Knoxville standard operating procedure KNOX-MS-0015, based on the following method:
· SW-846 8260B, “Volatile Organic Compounds by Gas Chromatography/ Mass Spectrometry (GC/MS)”
Each sample is prepared by adding a known amount of sample to the purge water in a purge and trap vessel and spiking with internal
standards, surrogates, and matrix spike analytes (as needed). Volatile compounds are introduced into the gas chromatograph by the
purge and trap method. The components are separated using the chromatograph and detected using a mass spectrometer, which
provides both qualitative and quantitative information.
Impinger sample results were calculated using the following equation:
Concentration, μg/sample = (C × DF × W × Vt) / (Va)
Where:
C = On-column concentration, μg/L
DF = Dilution factor
W = Volume of water purged, L
Vt = Methanol extract final volume, μL
Va = Volume of extract analyzed, µL
Method 8260B: The LCS (LCS 140-35706/1-A) for analytical batch 140-35903 recovered below marginal exceedance limits for
Trichlorofluoromethane. This is an ongoing instrument issue with LCS recoveries for this analyte. The project manager approved moving
forward with analysis for the current job.
Method 8260B: The following samples were analyzed outside of analytical holding time due to ongoing instrumentation problems: Y-2972
R2 VEN DIV STACK MM18 IMPINGER #3 (140-17461-9), Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 (140-17461-10), Y-2974 R2
VEN DIV STACK MM18 IMPINGER #5 (140-17461-11) and Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 (140-17461-12).
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Total Halogens: The samples were prepared for total fluorine, chlorine, bromine and/or iodine using SOP number KNOX-WC-0016
(based on ASTM Method E442 and SW-846 Method 5050). The sample is oxidized by combustion in an oxygen flask at atmospheric
pressure or a bomb containing oxygen under pressure. The liberated halogen compounds are absorbed primarily as halides in a sodium
carbonate/sodium bicarbonate buffer solution. The combustion products are collected by repeated rinsing of the combustion apparatus,
and analyzed by ion chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 9056). The results are
calculated using the following equation:
C = [(Ccom × Vcom) / W] × 1000 g/Kg
Where:
C = Concentration of analyte in the sample, mg/Kg
Ccom = Concentration of analyte in the combustate, mg/L
Vcom = Total volume of combustate, L
W = Weight of sample combusted, g
Anions in Impinger Solutions: Anions are is determined in accordance to SOP KNOX-WC-0005 (based on methods 300.0A and 9056).
The samples were diluted a minimum of 1/20 in ion chromatography solvent buffer solution to reduce the methanol concentration before
injection. Buffer concentrate was added until the pH was 10. Samples are diluted with ion chromatography eluate solution to bring the
concentrations within the calibration range when necessary. Higher dilutions are applied as necessary.
An aliquot of prepared sample is introduced into the ion chromatograph. Anions are identified based on their retention times as compared
to those of known standards. Quantification is accomplished by measuring the peak response and comparing it to a calibration curve
generated from known standards.
12/23/2019Page 8 of 89459
The pH of all samples were tested with pH paper. QC consisted of initial CCV and LCS which also serve as initial calibration, duplicate
analysis for every 10 samples, and closing CCV. A certified thermometer was used to check the ambient temperature.
12/23/2019Page 9 of 89460
QC Association Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
GC/MS VOA
Prep Batch: 35706
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH Prep140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH PrepMB 140-35706/2-A Method Blank Total/NA
Air MeOH PrepLCS 140-35706/1-A Lab Control Sample Total/NA
Air MeOH Prep140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 35903
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8260B 35706140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 8260B 35706140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35706140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 8260B 35706140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 8260B 35706140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 8260B 35706140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 8260B 35706140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 8260B 35706140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35706140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 8260B 35706140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 8260B 35706140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 8260B 35706140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 8260B 35706MB 140-35706/2-A Method Blank Total/NA
Air 8260B 35706LCS 140-35706/1-A Lab Control Sample Total/NA
Air 8260B 35706LCS 140-35706/1-A Lab Control Sample Total/NA
Air 8260B 35706140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35706140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
HPLC/IC
Prep Batch: 35705
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH PrepMB 140-35705/14-B Method Blank Total/NA
Air MeOH PrepLCS 140-35705/15-B Lab Control Sample Total/NA
Air MeOH PrepLCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Prep Batch: 35706
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 10 of 89461
QC Association Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
HPLC/IC (Continued)
Prep Batch: 35706 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH Prep140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH PrepMB 140-35706/17-A Method Blank Total/NA
Air MeOH PrepLCS 140-35706/18-A Lab Control Sample Total/NA
Air MeOH PrepLCSD 140-35706/19-A Lab Control Sample Dup Total/NA
Air MeOH Prep140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Prep Batch: 35707
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH PrepMB 140-35707/17-B Method Blank Total/NA
Air MeOH PrepLCS 140-35707/18-B Lab Control Sample Total/NA
Air MeOH PrepLCSD 140-35707/19-B Lab Control Sample Dup Total/NA
Prep Batch: 35761
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 5050 35706140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 5050 35706140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 5050 35706140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 5050 35706140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 5050 35706140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 5050 35706140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 5050 35706140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 5050 35707MB 140-35707/17-B Method Blank Total/NA
Air 5050 35707LCS 140-35707/18-B Lab Control Sample Total/NA
Air 5050 35707LCSD 140-35707/19-B Lab Control Sample Dup Total/NA
Prep Batch: 35762
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 5050 35706140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 5050 35706140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 5050 35706140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 5050 35706140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 5050 35706140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 5050 35705MB 140-35705/14-B Method Blank Total/NA
Air 5050 35705LCS 140-35705/15-B Lab Control Sample Total/NA
Air 5050 35705LCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Air 5050 35706140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 5050 35706140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 36005
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35761140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35761140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35761140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 11 of 89462
QC Association Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
HPLC/IC (Continued)
Analysis Batch: 36005 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35761140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35761140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35761140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35761140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35761MB 140-35707/17-B Method Blank Total/NA
Air 9056 35761LCS 140-35707/18-B Lab Control Sample Total/NA
Air 9056 35761LCSD 140-35707/19-B Lab Control Sample Dup Total/NA
Analysis Batch: 36121
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35762140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35762140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9056 35762140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35762140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35762140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35762MB 140-35705/14-B Method Blank Total/NA
Air 9056 35762LCS 140-35705/15-B Lab Control Sample Total/NA
Air 9056 35762LCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Air 9056 35762140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35762140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 36210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35706140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35706140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35706140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9056 35706140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35706140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35706140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35706140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35706140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35706140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9056 35706140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35706140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35706140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35706MB 140-35706/17-A Method Blank Total/NA
Air 9056 35706LCS 140-35706/18-A Lab Control Sample Total/NA
Air 9056 35706LCSD 140-35706/19-A Lab Control Sample Dup Total/NA
Air 9056 35706140-17461-8 MS Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35706140-17461-8 MSD Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
General Chemistry
Analysis Batch: 36086
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9041A140-17461-1 Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9041A140-17461-2 Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9041A140-17461-3 Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9041A140-17461-4 Y-2967 R1 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9041A140-17461-5 Y-2968 R1 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9041A140-17461-6 Y-2969 R1 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 12 of 89463
QC Association Summary
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
General Chemistry (Continued)
Analysis Batch: 36086 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9041A140-17461-7 Y-2970 R2 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9041A140-17461-8 Y-2971 R2 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9041A140-17461-9 Y-2972 R2 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9041A140-17461-10 Y-2973 R2 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9041A140-17461-11 Y-2974 R2 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9041A140-17461-12 Y-2975 R2 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9041ALCS 140-36086/2 Lab Control Sample Total/NA
Air 9041A140-17461-1 DU Y-2964 R1 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9041A140-17461-2 DU Y-2965 R1 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9041A140-17461-3 DU Y-2966 R1 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 13 of 89464
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-1Client Sample ID: Y-2964 R1 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 42.6 5.62 ug/Sample 11/29/19 10:48 12/06/19 20:54 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,1,3,3-Pentafluorobutane ND
42.6 6.13 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,1-Trichloroethane ND
85.2 16.9 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,1-Trifluoro-2,2-dichloroethane ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,1-Trifluoroethane ND
42.6 8.18 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,2,2-Tetrachloroethane ND
85.2 4.77 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,2-Trichloro-1,2,2-trifluoroethane ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,2-trichloro-1-fluoroethane ND
42.6 4.43 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1,2-Trichloroethane ND
85.2 42.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-Dichloro-1-fluoroethane ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-dichloro-2,2-difluoroethane ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-dichloro-2,2-difluoroethene ND
42.6 5.11 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-Dichloroethane ND
42.6 6.30 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-Dichloroethene ND
42.6 4.60 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-Dichloropropene ND
852 852 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,1-Difluoroethene ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2,2-trichloro-1,1-difluoroethane ND
42.6 13.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2,3-Trichlorobenzene ND
42.6 10.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2,3-Trichloropropane ND
42.6 14.3 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2,4-Trichlorobenzene ND
42.6 8.86 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2,4-Trimethylbenzene ND
85.2 15.0 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-Dibromo-3-Chloropropane ND
42.6 5.62 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-Dibromoethane (EDB)ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-dichloro-1,1-difluoroethane ND
42.6 7.49 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-Dichlorobenzene ND
42.6 7.15 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-Dichloroethane ND
42.6 4.26 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,2-Dichloropropane ND
42.6 8.86 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,3,5-Trimethylbenzene ND
42.6 7.32 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,3-Dichlorobenzene ND
42.6 4.77 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,3-Dichloropropane ND
42.6 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 11,4-Dichlorobenzene ND
85.2 8.69 ug/Sample 11/29/19 10:48 12/06/19 20:54 11-Chloro-1,1-difluoroethane ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
42.6 12.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 12,2-Dichloropropane ND
170 27.3 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-Butanone (MEK)ND
85.2 12.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
85.2 8.52 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-Chloro-1,1,1-Trifluoroethane ND
42.6 8.01 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-Chlorotoluene ND
170 39.2 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-Hexanone ND
37.2 37.2 ug/Sample 11/29/19 10:48 12/06/19 20:54 12-MTP as HFPO 820
42.6 8.86 ug/Sample 11/29/19 10:48 12/06/19 20:54 14-Chlorotoluene ND
42.6 11.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 14-Isopropyltoluene ND
170 27.3 ug/Sample 11/29/19 10:48 12/06/19 20:54 14-Methyl-2-pentanone (MIBK)ND
170 101 ug/Sample 11/29/19 10:48 12/06/19 20:54 1AcetoneND
42.6 8.18 ug/Sample 11/29/19 10:48 12/06/19 20:54 1BenzeneND
42.6 5.96 ug/Sample 11/29/19 10:48 12/06/19 20:54 1BromobenzeneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 14 of 89465
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-1Client Sample ID: Y-2964 R1 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromochloromethane ND 42.6 9.54 ug/Sample 11/29/19 10:48 12/06/19 20:54 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
42.6 7.32 ug/Sample 11/29/19 10:48 12/06/19 20:54 1BromodichloromethaneND
42.6 12.9 ug/Sample 11/29/19 10:48 12/06/19 20:54 1BromoformND
85.2 49.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 1BromomethaneND
42.6 10.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Carbon disulfide ND
42.6 5.62 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Carbon tetrachloride ND
125 125 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Carbonyl Difluoride ND
42.6 6.13 ug/Sample 11/29/19 10:48 12/06/19 20:54 1ChlorobenzeneND
42.6 9.20 ug/Sample 11/29/19 10:48 12/06/19 20:54 1ChlorodibromomethaneND
85.2 18.7 ug/Sample 11/29/19 10:48 12/06/19 20:54 1ChloroethaneND
42.6 4.94 ug/Sample 11/29/19 10:48 12/06/19 20:54 1ChloroformND
85.2 35.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 1ChloromethaneND
42.6 3.41 ug/Sample 11/29/19 10:48 12/06/19 20:54 1cis-1,2-Dichloroethene ND
42.6 7.32 ug/Sample 11/29/19 10:48 12/06/19 20:54 1cis-1,3-Dichloropropene ND
42.6 4.09 ug/Sample 11/29/19 10:48 12/06/19 20:54 1DibromomethaneND
85.2 15.0 ug/Sample 11/29/19 10:48 12/06/19 20:54 1DichlorodifluoromethaneND
42.6 6.98 ug/Sample 11/29/19 10:48 12/06/19 20:54 1EthylbenzeneND
42.6 42.6 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
111
42.6 11.2 ug/Sample 11/29/19 10:48 12/06/19 20:54 1HexachlorobutadieneND
40.9 40.9 ug/Sample 11/29/19 10:48 12/06/19 20:54 1HFPO dimer, methyl ester as
HFPO-DA
ND
42.6 5.96 ug/Sample 11/29/19 10:48 12/06/19 20:54 1IsopropylbenzeneND
85.2 6.98 ug/Sample 11/29/19 10:48 12/06/19 20:54 1m,p-Xylene ND
42.6 27.3 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Methylene Chloride 68.7
42.6 20.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 1NaphthaleneND
42.6 10.9 ug/Sample 11/29/19 10:48 12/06/19 20:54 1n-Butylbenzene ND
42.6 9.20 ug/Sample 11/29/19 10:48 12/06/19 20:54 1n-Propylbenzene ND
42.6 4.43 ug/Sample 11/29/19 10:48 12/06/19 20:54 1o-Xylene ND
42.6 8.35 ug/Sample 11/29/19 10:48 12/06/19 20:54 1sec-Butylbenzene ND
42.6 9.20 ug/Sample 11/29/19 10:48 12/06/19 20:54 1StyreneND
42.6 7.49 ug/Sample 11/29/19 10:48 12/06/19 20:54 1tert-Butylbenzene ND
42.6 5.62 ug/Sample 11/29/19 10:48 12/06/19 20:54 1TetrachloroetheneND
42.6 7.84 ug/Sample 11/29/19 10:48 12/06/19 20:54 1TolueneND
42.6 4.43 ug/Sample 11/29/19 10:48 12/06/19 20:54 1trans-1,2-Dichloroethene ND
42.6 15.0 ug/Sample 11/29/19 10:48 12/06/19 20:54 1trans-1,3-Dichloropropene ND
42.6 3.07 ug/Sample 11/29/19 10:48 12/06/19 20:54 1TrichloroetheneND
85.2 8.18 ug/Sample 11/29/19 10:48 12/06/19 20:54 1TrichlorofluoromethaneND *
85.2 20.4 ug/Sample 11/29/19 10:48 12/06/19 20:54 1Vinyl chloride ND
Butanoic acid, heptafluoro-, sodium
salt
437 T J N ug/Sample 1.13 2218-54-4 11/29/19 10:48 12/06/19 20:54 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 20:5411/29/19 10:48T JUnknown489 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:48 12/06/19 20:54 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 11/29/19 10:48 12/06/19 20:54 157-152
Eurofins TestAmerica, Knoxville
12/23/2019Page 15 of 89466
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-1Client Sample ID: Y-2964 R1 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Dibromofluoromethane (Surr)104 62 -134 11/29/19 10:48 12/06/19 20:54 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Toluene-d8 (Surr)97 11/29/19 10:48 12/06/19 20:54 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine ND 9080 4540 ug/Sample 11/29/19 10:48 12/11/19 21:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
3750 1700 ug/Sample 11/29/19 10:48 12/17/19 19:02 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-2Client Sample ID: Y-2965 R1 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 46.1 6.08 ug/Sample 11/29/19 10:48 12/06/19 21:19 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,1,3,3-Pentafluorobutane ND
46.1 6.64 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,1-Trichloroethane ND
92.2 18.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,1-Trifluoro-2,2-dichloroethane ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,1-Trifluoroethane ND
46.1 8.85 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,2,2-Tetrachloroethane ND
92.2 5.16 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,2-Trichloro-1,2,2-trifluoroethane ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,2-trichloro-1-fluoroethane ND
46.1 4.79 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1,2-Trichloroethane ND
92.2 46.1 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-Dichloro-1-fluoroethane ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-dichloro-2,2-difluoroethane ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-dichloro-2,2-difluoroethene ND
46.1 5.53 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-Dichloroethane ND
46.1 6.82 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-Dichloroethene ND
46.1 4.98 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-Dichloropropene ND
922 922 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,1-Difluoroethene ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2,2-trichloro-1,1-difluoroethane ND
46.1 14.7 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2,3-Trichlorobenzene ND
46.1 11.4 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2,3-Trichloropropane ND
46.1 15.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2,4-Trichlorobenzene ND
46.1 9.59 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2,4-Trimethylbenzene ND
92.2 16.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-Dibromo-3-Chloropropane ND
46.1 6.08 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-Dibromoethane (EDB)ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-dichloro-1,1-difluoroethane ND
46.1 8.11 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-Dichlorobenzene ND
46.1 7.74 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-Dichloroethane ND
46.1 4.61 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,2-Dichloropropane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 16 of 89467
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-2Client Sample ID: Y-2965 R1 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,3,5-Trimethylbenzene ND 46.1 9.59 ug/Sample 11/29/19 10:48 12/06/19 21:19 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
46.1 7.93 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,3-Dichlorobenzene ND
46.1 5.16 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,3-Dichloropropane ND
46.1 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 11,4-Dichlorobenzene ND
92.2 9.40 ug/Sample 11/29/19 10:48 12/06/19 21:19 11-Chloro-1,1-difluoroethane ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
46.1 13.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 12,2-Dichloropropane ND
184 29.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-Butanone (MEK)ND
92.2 13.6 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
92.2 9.22 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-Chloro-1,1,1-Trifluoroethane ND
46.1 8.66 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-Chlorotoluene ND
184 42.4 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-Hexanone ND
40.3 40.3 ug/Sample 11/29/19 10:48 12/06/19 21:19 12-MTP as HFPO 819
46.1 9.59 ug/Sample 11/29/19 10:48 12/06/19 21:19 14-Chlorotoluene ND
46.1 12.4 ug/Sample 11/29/19 10:48 12/06/19 21:19 14-Isopropyltoluene ND
184 29.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 14-Methyl-2-pentanone (MIBK)ND
184 109 ug/Sample 11/29/19 10:48 12/06/19 21:19 1AcetoneND
46.1 8.85 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BenzeneND
46.1 6.45 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BromobenzeneND
46.1 10.3 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BromochloromethaneND
46.1 7.93 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BromodichloromethaneND
46.1 14.0 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BromoformND
92.2 53.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 1BromomethaneND
46.1 11.4 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Carbon disulfide ND
46.1 6.08 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Carbon tetrachloride ND
135 135 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Carbonyl Difluoride ND
46.1 6.64 ug/Sample 11/29/19 10:48 12/06/19 21:19 1ChlorobenzeneND
46.1 9.95 ug/Sample 11/29/19 10:48 12/06/19 21:19 1ChlorodibromomethaneND
92.2 20.3 ug/Sample 11/29/19 10:48 12/06/19 21:19 1ChloroethaneND
46.1 5.35 ug/Sample 11/29/19 10:48 12/06/19 21:19 1ChloroformND
92.2 38.3 ug/Sample 11/29/19 10:48 12/06/19 21:19 1ChloromethaneND
46.1 3.69 ug/Sample 11/29/19 10:48 12/06/19 21:19 1cis-1,2-Dichloroethene ND
46.1 7.93 ug/Sample 11/29/19 10:48 12/06/19 21:19 1cis-1,3-Dichloropropene ND
46.1 4.42 ug/Sample 11/29/19 10:48 12/06/19 21:19 1DibromomethaneND
92.2 16.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 1DichlorodifluoromethaneND
46.1 7.56 ug/Sample 11/29/19 10:48 12/06/19 21:19 1EthylbenzeneND
46.1 46.1 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
161
46.1 12.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 1HexachlorobutadieneND
44.2 44.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 1HFPO dimer, methyl ester as
HFPO-DA
ND
46.1 6.45 ug/Sample 11/29/19 10:48 12/06/19 21:19 1IsopropylbenzeneND
92.2 7.56 ug/Sample 11/29/19 10:48 12/06/19 21:19 1m,p-Xylene ND
46.1 29.5 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Methylene Chloride 56.8
46.1 22.1 ug/Sample 11/29/19 10:48 12/06/19 21:19 1NaphthaleneND
46.1 11.8 ug/Sample 11/29/19 10:48 12/06/19 21:19 1n-Butylbenzene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 17 of 89468
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-2Client Sample ID: Y-2965 R1 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Propylbenzene ND 46.1 9.95 ug/Sample 11/29/19 10:48 12/06/19 21:19 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
46.1 4.79 ug/Sample 11/29/19 10:48 12/06/19 21:19 1o-Xylene ND
46.1 9.03 ug/Sample 11/29/19 10:48 12/06/19 21:19 1sec-Butylbenzene ND
46.1 9.95 ug/Sample 11/29/19 10:48 12/06/19 21:19 1StyreneND
46.1 8.11 ug/Sample 11/29/19 10:48 12/06/19 21:19 1tert-Butylbenzene ND
46.1 6.08 ug/Sample 11/29/19 10:48 12/06/19 21:19 1TetrachloroetheneND
46.1 8.48 ug/Sample 11/29/19 10:48 12/06/19 21:19 1TolueneND
46.1 4.79 ug/Sample 11/29/19 10:48 12/06/19 21:19 1trans-1,2-Dichloroethene ND
46.1 16.2 ug/Sample 11/29/19 10:48 12/06/19 21:19 1trans-1,3-Dichloropropene ND
46.1 3.32 ug/Sample 11/29/19 10:48 12/06/19 21:19 1TrichloroetheneND
92.2 8.85 ug/Sample 11/29/19 10:48 12/06/19 21:19 1TrichlorofluoromethaneND *
92.2 22.1 ug/Sample 11/29/19 10:48 12/06/19 21:19 1Vinyl chloride ND
Unknown 561 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 21:19 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 21:1911/29/19 10:48T JUnknown1150 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:48 12/06/19 21:19 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:48 12/06/19 21:19 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:48 12/06/19 21:19 162-134
Toluene-d8 (Surr)96 11/29/19 10:48 12/06/19 21:19 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 27900 9830 4920 ug/Sample 11/29/19 10:48 12/11/19 21:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
4060 1840 ug/Sample 11/29/19 10:48 12/17/19 20:06 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-3Client Sample ID: Y-2966 R1 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 8.58 1.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,1,3,3-Pentafluorobutane ND
8.58 1.24 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,1-Trichloroethane ND
17.2 3.40 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,1-Trifluoro-2,2-dichloroethane ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,1-Trifluoroethane ND
8.58 1.65 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,2,2-Tetrachloroethane ND
17.2 0.961 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,2-Trichloro-1,2,2-trifluoroethane ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1,2-trichloro-1-fluoroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 18 of 89469
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-3Client Sample ID: Y-2966 R1 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,2-Trichloroethane ND 8.58 0.892 ug/Sample 11/29/19 10:48 12/06/19 21:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
17.2 8.58 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-Dichloro-1-fluoroethane ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-dichloro-2,2-difluoroethane ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-dichloro-2,2-difluoroethene ND
8.58 1.03 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-Dichloroethane ND
8.58 1.27 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-Dichloroethene ND
8.58 0.926 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-Dichloropropene ND
172 172 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,1-Difluoroethene ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2,2-trichloro-1,1-difluoroethane ND
8.58 2.74 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2,3-Trichlorobenzene ND
8.58 2.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2,3-Trichloropropane ND
8.58 2.88 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2,4-Trichlorobenzene ND
8.58 1.78 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2,4-Trimethylbenzene ND
17.2 3.02 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-Dibromo-3-Chloropropane ND
8.58 1.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-Dibromoethane (EDB)ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-dichloro-1,1-difluoroethane ND
8.58 1.51 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-Dichlorobenzene ND
8.58 1.44 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-Dichloroethane ND
8.58 0.858 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,2-Dichloropropane ND
8.58 1.78 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,3,5-Trimethylbenzene ND
8.58 1.48 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,3-Dichlorobenzene ND
8.58 0.961 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,3-Dichloropropane ND
8.58 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 11,4-Dichlorobenzene ND
17.2 1.75 ug/Sample 11/29/19 10:48 12/06/19 21:43 11-Chloro-1,1-difluoroethane ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
8.58 2.50 ug/Sample 11/29/19 10:48 12/06/19 21:43 12,2-Dichloropropane ND
34.3 5.49 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-Butanone (MEK)ND
17.2 2.54 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
17.2 1.72 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-Chloro-1,1,1-Trifluoroethane ND
8.58 1.61 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-Chlorotoluene ND
34.3 7.89 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-Hexanone ND
7.49 7.49 ug/Sample 11/29/19 10:48 12/06/19 21:43 12-MTP as HFPO 60.4
8.58 1.78 ug/Sample 11/29/19 10:48 12/06/19 21:43 14-Chlorotoluene ND
8.58 2.30 ug/Sample 11/29/19 10:48 12/06/19 21:43 14-Isopropyltoluene ND
34.3 5.49 ug/Sample 11/29/19 10:48 12/06/19 21:43 14-Methyl-2-pentanone (MIBK)ND
34.3 20.2 ug/Sample 11/29/19 10:48 12/06/19 21:43 1AcetoneND
8.58 1.65 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BenzeneND
8.58 1.20 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BromobenzeneND
8.58 1.92 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BromochloromethaneND
8.58 1.48 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BromodichloromethaneND
8.58 2.61 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BromoformND
17.2 9.95 ug/Sample 11/29/19 10:48 12/06/19 21:43 1BromomethaneND
8.58 2.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Carbon disulfide ND
8.58 1.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Carbon tetrachloride ND
25.1 25.1 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Carbonyl Difluoride ND
8.58 1.24 ug/Sample 11/29/19 10:48 12/06/19 21:43 1ChlorobenzeneND
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-3Client Sample ID: Y-2966 R1 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Chlorodibromomethane ND 8.58 1.85 ug/Sample 11/29/19 10:48 12/06/19 21:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
17.2 3.77 ug/Sample 11/29/19 10:48 12/06/19 21:43 1ChloroethaneND
8.58 0.995 ug/Sample 11/29/19 10:48 12/06/19 21:43 1ChloroformND
17.2 7.14 ug/Sample 11/29/19 10:48 12/06/19 21:43 1ChloromethaneND
8.58 0.686 ug/Sample 11/29/19 10:48 12/06/19 21:43 1cis-1,2-Dichloroethene ND
8.58 1.48 ug/Sample 11/29/19 10:48 12/06/19 21:43 1cis-1,3-Dichloropropene ND
8.58 0.823 ug/Sample 11/29/19 10:48 12/06/19 21:43 1DibromomethaneND
17.2 3.02 ug/Sample 11/29/19 10:48 12/06/19 21:43 1DichlorodifluoromethaneND
8.58 1.41 ug/Sample 11/29/19 10:48 12/06/19 21:43 1EthylbenzeneND
8.58 8.58 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
8.58 2.26 ug/Sample 11/29/19 10:48 12/06/19 21:43 1HexachlorobutadieneND
8.23 8.23 ug/Sample 11/29/19 10:48 12/06/19 21:43 1HFPO dimer, methyl ester as
HFPO-DA
ND
8.58 1.20 ug/Sample 11/29/19 10:48 12/06/19 21:43 1IsopropylbenzeneND
17.2 1.41 ug/Sample 11/29/19 10:48 12/06/19 21:43 1m,p-Xylene ND
8.58 5.49 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Methylene Chloride ND
8.58 4.12 ug/Sample 11/29/19 10:48 12/06/19 21:43 1NaphthaleneND
8.58 2.20 ug/Sample 11/29/19 10:48 12/06/19 21:43 1n-Butylbenzene ND
8.58 1.85 ug/Sample 11/29/19 10:48 12/06/19 21:43 1n-Propylbenzene ND
8.58 0.892 ug/Sample 11/29/19 10:48 12/06/19 21:43 1o-Xylene ND
8.58 1.68 ug/Sample 11/29/19 10:48 12/06/19 21:43 1sec-Butylbenzene ND
8.58 1.85 ug/Sample 11/29/19 10:48 12/06/19 21:43 1StyreneND
8.58 1.51 ug/Sample 11/29/19 10:48 12/06/19 21:43 1tert-Butylbenzene ND
8.58 1.13 ug/Sample 11/29/19 10:48 12/06/19 21:43 1TetrachloroetheneND
8.58 1.58 ug/Sample 11/29/19 10:48 12/06/19 21:43 1TolueneND
8.58 0.892 ug/Sample 11/29/19 10:48 12/06/19 21:43 1trans-1,2-Dichloroethene ND
8.58 3.02 ug/Sample 11/29/19 10:48 12/06/19 21:43 1trans-1,3-Dichloropropene ND
8.58 0.618 ug/Sample 11/29/19 10:48 12/06/19 21:43 1TrichloroetheneND
17.2 1.65 ug/Sample 11/29/19 10:48 12/06/19 21:43 1TrichlorofluoromethaneND *
17.2 4.12 ug/Sample 11/29/19 10:48 12/06/19 21:43 1Vinyl chloride ND
Unknown 20.1 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 21:43 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 21:4311/29/19 10:48T JUnknown9.96 ug/Sample 1.18
112/06/19 21:4311/29/19 10:48T J NCyclohexane 110-82-724.8 ug/Sample 4.42
112/06/19 21:4311/29/19 10:48T J N1-Dodecene 112-41-410.5 ug/Sample 12.07
112/06/19 21:4311/29/19 10:48T J NCyclohexane, hexyl-4292-75-512.9 ug/Sample 12.69
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:48 12/06/19 21:43 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:48 12/06/19 21:43 157-152
Dibromofluoromethane (Surr)102 11/29/19 10:48 12/06/19 21:43 162-134
Toluene-d8 (Surr)97 11/29/19 10:48 12/06/19 21:43 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 9710 1830 915 ug/Sample 11/29/19 10:48 12/11/19 22:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-3Client Sample ID: Y-2966 R1 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 9056 - Anions, Ion Chromatography (Continued)
RL MDL
Hydrogen Fluoride ND 755 343 ug/Sample 11/29/19 10:48 12/17/19 20:29 20
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-4Client Sample ID: Y-2967 R1 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 26.4 3.49 ug/Sample 11/29/19 10:48 12/06/19 22:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,1,3,3-Pentafluorobutane ND
26.4 3.81 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,1-Trichloroethane ND
52.9 10.5 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,1-Trifluoro-2,2-dichloroethane ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,1-Trifluoroethane ND
26.4 5.08 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,2,2-Tetrachloroethane ND
52.9 2.96 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,2-Trichloro-1,2,2-trifluoroethane ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,2-trichloro-1-fluoroethane ND
26.4 2.75 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1,2-Trichloroethane ND
52.9 26.4 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-Dichloro-1-fluoroethane ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-dichloro-2,2-difluoroethane ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-dichloro-2,2-difluoroethene ND
26.4 3.17 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-Dichloroethane ND
26.4 3.91 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-Dichloroethene ND
26.4 2.86 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-Dichloropropene ND
529 529 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,1-Difluoroethene ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2,2-trichloro-1,1-difluoroethane ND
26.4 8.46 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2,3-Trichlorobenzene ND
26.4 6.56 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2,3-Trichloropropane ND
26.4 8.89 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2,4-Trichlorobenzene ND
26.4 5.50 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2,4-Trimethylbenzene ND
52.9 9.31 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-Dibromo-3-Chloropropane ND
26.4 3.49 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-Dibromoethane (EDB)ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-dichloro-1,1-difluoroethane ND
26.4 4.65 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-Dichlorobenzene ND
26.4 4.44 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-Dichloroethane ND
26.4 2.64 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,2-Dichloropropane ND
26.4 5.50 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,3,5-Trimethylbenzene ND
26.4 4.55 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,3-Dichlorobenzene ND
26.4 2.96 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,3-Dichloropropane ND
26.4 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 11,4-Dichlorobenzene ND
52.9 5.39 ug/Sample 11/29/19 10:48 12/06/19 22:08 11-Chloro-1,1-difluoroethane ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 21 of 89472
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-4Client Sample ID: Y-2967 R1 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
2,2-Dichloropropane ND 26.4 7.72 ug/Sample 11/29/19 10:48 12/06/19 22:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
106 16.9 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-Butanone (MEK)ND
52.9 7.83 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
52.9 5.29 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-Chloro-1,1,1-Trifluoroethane ND
26.4 4.97 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-Chlorotoluene ND
106 24.3 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-Hexanone ND
23.1 23.1 ug/Sample 11/29/19 10:48 12/06/19 22:08 12-MTP as HFPO 636
26.4 5.50 ug/Sample 11/29/19 10:48 12/06/19 22:08 14-Chlorotoluene ND
26.4 7.09 ug/Sample 11/29/19 10:48 12/06/19 22:08 14-Isopropyltoluene ND
106 16.9 ug/Sample 11/29/19 10:48 12/06/19 22:08 14-Methyl-2-pentanone (MIBK)ND
106 62.4 ug/Sample 11/29/19 10:48 12/06/19 22:08 1AcetoneND
26.4 5.08 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BenzeneND
26.4 3.70 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BromobenzeneND
26.4 5.92 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BromochloromethaneND
26.4 4.55 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BromodichloromethaneND
26.4 8.04 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BromoformND
52.9 30.7 ug/Sample 11/29/19 10:48 12/06/19 22:08 1BromomethaneND
26.4 6.56 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Carbon disulfide ND
26.4 3.49 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Carbon tetrachloride ND
77.7 77.7 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Carbonyl Difluoride ND
26.4 3.81 ug/Sample 11/29/19 10:48 12/06/19 22:08 1ChlorobenzeneND
26.4 5.71 ug/Sample 11/29/19 10:48 12/06/19 22:08 1ChlorodibromomethaneND
52.9 11.6 ug/Sample 11/29/19 10:48 12/06/19 22:08 1ChloroethaneND
26.4 3.07 ug/Sample 11/29/19 10:48 12/06/19 22:08 1ChloroformND
52.9 22.0 ug/Sample 11/29/19 10:48 12/06/19 22:08 1ChloromethaneND
26.4 2.12 ug/Sample 11/29/19 10:48 12/06/19 22:08 1cis-1,2-Dichloroethene ND
26.4 4.55 ug/Sample 11/29/19 10:48 12/06/19 22:08 1cis-1,3-Dichloropropene ND
26.4 2.54 ug/Sample 11/29/19 10:48 12/06/19 22:08 1DibromomethaneND
52.9 9.31 ug/Sample 11/29/19 10:48 12/06/19 22:08 1DichlorodifluoromethaneND
26.4 4.34 ug/Sample 11/29/19 10:48 12/06/19 22:08 1EthylbenzeneND
26.4 26.4 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
26.4 6.98 ug/Sample 11/29/19 10:48 12/06/19 22:08 1HexachlorobutadieneND
25.3 25.3 ug/Sample 11/29/19 10:48 12/06/19 22:08 1HFPO dimer, methyl ester as
HFPO-DA
ND
26.4 3.70 ug/Sample 11/29/19 10:48 12/06/19 22:08 1IsopropylbenzeneND
52.9 4.34 ug/Sample 11/29/19 10:48 12/06/19 22:08 1m,p-Xylene ND
26.4 16.9 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Methylene Chloride ND
26.4 12.7 ug/Sample 11/29/19 10:48 12/06/19 22:08 1NaphthaleneND
26.4 6.77 ug/Sample 11/29/19 10:48 12/06/19 22:08 1n-Butylbenzene ND
26.4 5.71 ug/Sample 11/29/19 10:48 12/06/19 22:08 1n-Propylbenzene ND
26.4 2.75 ug/Sample 11/29/19 10:48 12/06/19 22:08 1o-Xylene ND
26.4 5.18 ug/Sample 11/29/19 10:48 12/06/19 22:08 1sec-Butylbenzene ND
26.4 5.71 ug/Sample 11/29/19 10:48 12/06/19 22:08 1StyreneND
26.4 4.65 ug/Sample 11/29/19 10:48 12/06/19 22:08 1tert-Butylbenzene ND
26.4 3.49 ug/Sample 11/29/19 10:48 12/06/19 22:08 1TetrachloroetheneND
26.4 4.87 ug/Sample 11/29/19 10:48 12/06/19 22:08 1TolueneND
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-4Client Sample ID: Y-2967 R1 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
trans-1,2-Dichloroethene ND 26.4 2.75 ug/Sample 11/29/19 10:48 12/06/19 22:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
26.4 9.31 ug/Sample 11/29/19 10:48 12/06/19 22:08 1trans-1,3-Dichloropropene ND
26.4 1.90 ug/Sample 11/29/19 10:48 12/06/19 22:08 1TrichloroetheneND
52.9 5.08 ug/Sample 11/29/19 10:48 12/06/19 22:08 1TrichlorofluoromethaneND *
52.9 12.7 ug/Sample 11/29/19 10:48 12/06/19 22:08 1Vinyl chloride ND
Unknown 365 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 22:08 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 22:0811/29/19 10:48T JUnknown452 ug/Sample 1.18
112/06/19 22:0811/29/19 10:48T J NCyclohexane 110-82-741.9 ug/Sample 4.42
1,2-Dichloroethane-d4 (Surr)120 70 -160 11/29/19 10:48 12/06/19 22:08 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 11/29/19 10:48 12/06/19 22:08 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:48 12/06/19 22:08 162-134
Toluene-d8 (Surr)96 11/29/19 10:48 12/06/19 22:08 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 22000 5640 2820 ug/Sample 11/29/19 10:48 12/12/19 15:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2330 1060 ug/Sample 11/29/19 10:48 12/17/19 20:51 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-5Client Sample ID: Y-2968 R1 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 24.1 3.18 ug/Sample 11/29/19 10:48 12/06/19 22:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,1,3,3-Pentafluorobutane ND
24.1 3.47 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,1-Trichloroethane ND
48.2 9.54 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,1-Trifluoro-2,2-dichloroethane ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,1-Trifluoroethane ND
24.1 4.62 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,2,2-Tetrachloroethane ND
48.2 2.70 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,2-Trichloro-1,2,2-trifluoroethane ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,2-trichloro-1-fluoroethane ND
24.1 2.50 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1,2-Trichloroethane ND
48.2 24.1 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-Dichloro-1-fluoroethane ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-dichloro-2,2-difluoroethane ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-dichloro-2,2-difluoroethene ND
24.1 2.89 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-Dichloroethane ND
24.1 3.56 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-Dichloroethene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 23 of 89474
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-5Client Sample ID: Y-2968 R1 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1-Dichloropropene ND 24.1 2.60 ug/Sample 11/29/19 10:48 12/06/19 22:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
482 482 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,1-Difluoroethene ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2,2-trichloro-1,1-difluoroethane ND
24.1 7.71 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2,3-Trichlorobenzene ND
24.1 5.97 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2,3-Trichloropropane ND
24.1 8.09 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2,4-Trichlorobenzene ND
24.1 5.01 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2,4-Trimethylbenzene ND
48.2 8.48 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-Dibromo-3-Chloropropane ND
24.1 3.18 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-Dibromoethane (EDB)ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-dichloro-1,1-difluoroethane ND
24.1 4.24 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-Dichlorobenzene ND
24.1 4.05 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-Dichloroethane ND
24.1 2.41 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,2-Dichloropropane ND
24.1 5.01 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,3,5-Trimethylbenzene ND
24.1 4.14 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,3-Dichlorobenzene ND
24.1 2.70 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,3-Dichloropropane ND
24.1 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 11,4-Dichlorobenzene ND
48.2 4.91 ug/Sample 11/29/19 10:48 12/06/19 22:32 11-Chloro-1,1-difluoroethane ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
24.1 7.03 ug/Sample 11/29/19 10:48 12/06/19 22:32 12,2-Dichloropropane ND
96.3 15.4 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-Butanone (MEK)ND
48.2 7.13 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
48.2 4.82 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-Chloro-1,1,1-Trifluoroethane ND
24.1 4.53 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-Chlorotoluene ND
96.3 22.2 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-Hexanone ND
21.0 21.0 ug/Sample 11/29/19 10:48 12/06/19 22:32 12-MTP as HFPO 490
24.1 5.01 ug/Sample 11/29/19 10:48 12/06/19 22:32 14-Chlorotoluene ND
24.1 6.45 ug/Sample 11/29/19 10:48 12/06/19 22:32 14-Isopropyltoluene ND
96.3 15.4 ug/Sample 11/29/19 10:48 12/06/19 22:32 14-Methyl-2-pentanone (MIBK)ND
96.3 56.8 ug/Sample 11/29/19 10:48 12/06/19 22:32 1AcetoneND
24.1 4.62 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BenzeneND
24.1 3.37 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BromobenzeneND
24.1 5.40 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BromochloromethaneND
24.1 4.14 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BromodichloromethaneND
24.1 7.32 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BromoformND
48.2 27.9 ug/Sample 11/29/19 10:48 12/06/19 22:32 1BromomethaneND
24.1 5.97 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Carbon disulfide ND
24.1 3.18 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Carbon tetrachloride ND
70.6 70.6 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Carbonyl Difluoride ND
24.1 3.47 ug/Sample 11/29/19 10:48 12/06/19 22:32 1ChlorobenzeneND
24.1 5.20 ug/Sample 11/29/19 10:48 12/06/19 22:32 1ChlorodibromomethaneND
48.2 10.6 ug/Sample 11/29/19 10:48 12/06/19 22:32 1ChloroethaneND
24.1 2.79 ug/Sample 11/29/19 10:48 12/06/19 22:32 1ChloroformND
48.2 20.0 ug/Sample 11/29/19 10:48 12/06/19 22:32 1ChloromethaneND
24.1 1.93 ug/Sample 11/29/19 10:48 12/06/19 22:32 1cis-1,2-Dichloroethene ND
24.1 4.14 ug/Sample 11/29/19 10:48 12/06/19 22:32 1cis-1,3-Dichloropropene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 24 of 89475
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-5Client Sample ID: Y-2968 R1 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Dibromomethane ND 24.1 2.31 ug/Sample 11/29/19 10:48 12/06/19 22:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
48.2 8.48 ug/Sample 11/29/19 10:48 12/06/19 22:32 1DichlorodifluoromethaneND
24.1 3.95 ug/Sample 11/29/19 10:48 12/06/19 22:32 1EthylbenzeneND
24.1 24.1 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
24.1 6.36 ug/Sample 11/29/19 10:48 12/06/19 22:32 1HexachlorobutadieneND
23.1 23.1 ug/Sample 11/29/19 10:48 12/06/19 22:32 1HFPO dimer, methyl ester as
HFPO-DA
ND
24.1 3.37 ug/Sample 11/29/19 10:48 12/06/19 22:32 1IsopropylbenzeneND
48.2 3.95 ug/Sample 11/29/19 10:48 12/06/19 22:32 1m,p-Xylene ND
24.1 15.4 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Methylene Chloride ND
24.1 11.6 ug/Sample 11/29/19 10:48 12/06/19 22:32 1NaphthaleneND
24.1 6.17 ug/Sample 11/29/19 10:48 12/06/19 22:32 1n-Butylbenzene ND
24.1 5.20 ug/Sample 11/29/19 10:48 12/06/19 22:32 1n-Propylbenzene ND
24.1 2.50 ug/Sample 11/29/19 10:48 12/06/19 22:32 1o-Xylene ND
24.1 4.72 ug/Sample 11/29/19 10:48 12/06/19 22:32 1sec-Butylbenzene ND
24.1 5.20 ug/Sample 11/29/19 10:48 12/06/19 22:32 1StyreneND
24.1 4.24 ug/Sample 11/29/19 10:48 12/06/19 22:32 1tert-Butylbenzene ND
24.1 3.18 ug/Sample 11/29/19 10:48 12/06/19 22:32 1TetrachloroetheneND
24.1 4.43 ug/Sample 11/29/19 10:48 12/06/19 22:32 1TolueneND
24.1 2.50 ug/Sample 11/29/19 10:48 12/06/19 22:32 1trans-1,2-Dichloroethene ND
24.1 8.48 ug/Sample 11/29/19 10:48 12/06/19 22:32 1trans-1,3-Dichloropropene ND
24.1 1.73 ug/Sample 11/29/19 10:48 12/06/19 22:32 1TrichloroetheneND
48.2 4.62 ug/Sample 11/29/19 10:48 12/06/19 22:32 1TrichlorofluoromethaneND *
48.2 11.6 ug/Sample 11/29/19 10:48 12/06/19 22:32 1Vinyl chloride ND
Unknown 223 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 22:32 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 22:3211/29/19 10:48T J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-8104ug/Sample 1.18
112/06/19 22:3211/29/19 10:48T J NCyclohexane 110-82-741.0 ug/Sample 4.42
112/06/19 22:3211/29/19 10:48T JUnknown30.9 ug/Sample 13.17
1,2-Dichloroethane-d4 (Surr)121 70 -160 11/29/19 10:48 12/06/19 22:32 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:48 12/06/19 22:32 157-152
Dibromofluoromethane (Surr)106 11/29/19 10:48 12/06/19 22:32 162-134
Toluene-d8 (Surr)95 11/29/19 10:48 12/06/19 22:32 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 4360 J 5140 2570 ug/Sample 11/29/19 10:48 12/11/19 23:30 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2120 963 ug/Sample 11/29/19 10:48 12/17/19 21:14 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
12/23/2019Page 25 of 89476
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-6Client Sample ID: Y-2969 R1 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 31.3 4.13 ug/Sample 11/29/19 10:48 12/06/19 22:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,1,3,3-Pentafluorobutane ND
31.3 4.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,1-Trichloroethane ND
62.7 12.4 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,1-Trifluoro-2,2-dichloroethane ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,1-Trifluoroethane ND
31.3 6.01 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,2,2-Tetrachloroethane ND
62.7 3.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,2-Trichloro-1,2,2-trifluoroethane ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,2-trichloro-1-fluoroethane ND
31.3 3.26 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1,2-Trichloroethane ND
62.7 31.3 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-Dichloro-1-fluoroethane ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-dichloro-2,2-difluoroethane ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-dichloro-2,2-difluoroethene ND
31.3 3.76 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-Dichloroethane ND
31.3 4.64 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-Dichloroethene ND
31.3 3.38 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-Dichloropropene ND
627 627 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,1-Difluoroethene ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2,2-trichloro-1,1-difluoroethane ND
31.3 10.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2,3-Trichlorobenzene ND
31.3 7.77 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2,3-Trichloropropane ND
31.3 10.5 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2,4-Trichlorobenzene ND
31.3 6.52 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2,4-Trimethylbenzene ND
62.7 11.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-Dibromo-3-Chloropropane ND
31.3 4.13 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-Dibromoethane (EDB)ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-dichloro-1,1-difluoroethane ND
31.3 5.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-Dichlorobenzene ND
31.3 5.26 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-Dichloroethane ND
31.3 3.13 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,2-Dichloropropane ND
31.3 6.52 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,3,5-Trimethylbenzene ND
31.3 5.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,3-Dichlorobenzene ND
31.3 3.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,3-Dichloropropane ND
31.3 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 11,4-Dichlorobenzene ND
62.7 6.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 11-Chloro-1,1-difluoroethane ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
31.3 9.15 ug/Sample 11/29/19 10:48 12/06/19 22:57 12,2-Dichloropropane ND
125 20.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-Butanone (MEK)ND
62.7 9.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
62.7 6.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-Chloro-1,1,1-Trifluoroethane ND
31.3 5.89 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-Chlorotoluene ND
125 28.8 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-Hexanone ND
27.3 27.3 ug/Sample 11/29/19 10:48 12/06/19 22:57 12-MTP as HFPO 672
31.3 6.52 ug/Sample 11/29/19 10:48 12/06/19 22:57 14-Chlorotoluene ND
31.3 8.40 ug/Sample 11/29/19 10:48 12/06/19 22:57 14-Isopropyltoluene ND
125 20.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 14-Methyl-2-pentanone (MIBK)ND
125 73.9 ug/Sample 11/29/19 10:48 12/06/19 22:57 1AcetoneND
31.3 6.01 ug/Sample 11/29/19 10:48 12/06/19 22:57 1BenzeneND
31.3 4.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 1BromobenzeneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 26 of 89477
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-6Client Sample ID: Y-2969 R1 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromochloromethane ND 31.3 7.02 ug/Sample 11/29/19 10:48 12/06/19 22:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
31.3 5.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 1BromodichloromethaneND
31.3 9.52 ug/Sample 11/29/19 10:48 12/06/19 22:57 1BromoformND
62.7 36.3 ug/Sample 11/29/19 10:48 12/06/19 22:57 1BromomethaneND
31.3 7.77 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Carbon disulfide ND
31.3 4.13 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Carbon tetrachloride ND
91.6 91.6 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Carbonyl Difluoride ND
31.3 4.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 1ChlorobenzeneND
31.3 6.77 ug/Sample 11/29/19 10:48 12/06/19 22:57 1ChlorodibromomethaneND
62.7 13.8 ug/Sample 11/29/19 10:48 12/06/19 22:57 1ChloroethaneND
31.3 3.63 ug/Sample 11/29/19 10:48 12/06/19 22:57 1ChloroformND
62.7 26.1 ug/Sample 11/29/19 10:48 12/06/19 22:57 1ChloromethaneND
31.3 2.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 1cis-1,2-Dichloroethene ND
31.3 5.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 1cis-1,3-Dichloropropene ND
31.3 3.01 ug/Sample 11/29/19 10:48 12/06/19 22:57 1DibromomethaneND
62.7 11.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1DichlorodifluoromethaneND
31.3 5.14 ug/Sample 11/29/19 10:48 12/06/19 22:57 1EthylbenzeneND
31.3 31.3 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
31.3 8.27 ug/Sample 11/29/19 10:48 12/06/19 22:57 1HexachlorobutadieneND
30.0 30.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1HFPO dimer, methyl ester as
HFPO-DA
ND
31.3 4.39 ug/Sample 11/29/19 10:48 12/06/19 22:57 1IsopropylbenzeneND
62.7 5.14 ug/Sample 11/29/19 10:48 12/06/19 22:57 1m,p-Xylene ND
31.3 20.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Methylene Chloride ND
31.3 15.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1NaphthaleneND
31.3 8.02 ug/Sample 11/29/19 10:48 12/06/19 22:57 1n-Butylbenzene ND
31.3 6.77 ug/Sample 11/29/19 10:48 12/06/19 22:57 1n-Propylbenzene ND
31.3 3.26 ug/Sample 11/29/19 10:48 12/06/19 22:57 1o-Xylene ND
31.3 6.14 ug/Sample 11/29/19 10:48 12/06/19 22:57 1sec-Butylbenzene ND
31.3 6.77 ug/Sample 11/29/19 10:48 12/06/19 22:57 1StyreneND
31.3 5.51 ug/Sample 11/29/19 10:48 12/06/19 22:57 1tert-Butylbenzene ND
31.3 4.13 ug/Sample 11/29/19 10:48 12/06/19 22:57 1TetrachloroetheneND
31.3 5.76 ug/Sample 11/29/19 10:48 12/06/19 22:57 1TolueneND
31.3 3.26 ug/Sample 11/29/19 10:48 12/06/19 22:57 1trans-1,2-Dichloroethene ND
31.3 11.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1trans-1,3-Dichloropropene ND
31.3 2.26 ug/Sample 11/29/19 10:48 12/06/19 22:57 1TrichloroetheneND
62.7 6.01 ug/Sample 11/29/19 10:48 12/06/19 22:57 1TrichlorofluoromethaneND *
62.7 15.0 ug/Sample 11/29/19 10:48 12/06/19 22:57 1Vinyl chloride ND
Unknown 273 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 22:57 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 22:5711/29/19 10:48T J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-8160ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)118 70 -160 11/29/19 10:48 12/06/19 22:57 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)108 11/29/19 10:48 12/06/19 22:57 157-152
Eurofins TestAmerica, Knoxville
12/23/2019Page 27 of 89478
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-6Client Sample ID: Y-2969 R1 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Dibromofluoromethane (Surr)105 62 -134 11/29/19 10:48 12/06/19 22:57 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Toluene-d8 (Surr)97 11/29/19 10:48 12/06/19 22:57 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 3970 J 6680 3340 ug/Sample 11/29/19 10:48 12/11/19 23:50 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2760 1250 ug/Sample 11/29/19 10:48 12/17/19 21:37 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-7Client Sample ID: Y-2970 R2 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 30.2 3.99 ug/Sample 11/29/19 10:48 12/06/19 23:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,1,3,3-Pentafluorobutane ND
30.2 4.35 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,1-Trichloroethane ND
60.4 12.0 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,1-Trifluoro-2,2-dichloroethane ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,1-Trifluoroethane ND
30.2 5.80 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,2,2-Tetrachloroethane ND
60.4 3.38 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,2-Trichloro-1,2,2-trifluoroethane ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,2-trichloro-1-fluoroethane ND
30.2 3.14 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1,2-Trichloroethane ND
60.4 30.2 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-Dichloro-1-fluoroethane ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-dichloro-2,2-difluoroethane ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-dichloro-2,2-difluoroethene ND
30.2 3.62 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-Dichloroethane ND
30.2 4.47 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-Dichloroethene ND
30.2 3.26 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-Dichloropropene ND
604 604 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,1-Difluoroethene ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2,2-trichloro-1,1-difluoroethane ND
30.2 9.67 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2,3-Trichlorobenzene ND
30.2 7.49 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2,3-Trichloropropane ND
30.2 10.1 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2,4-Trichlorobenzene ND
30.2 6.28 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2,4-Trimethylbenzene ND
60.4 10.6 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-Dibromo-3-Chloropropane ND
30.2 3.99 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-Dibromoethane (EDB)ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-dichloro-1,1-difluoroethane ND
30.2 5.32 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-Dichlorobenzene ND
30.2 5.07 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-Dichloroethane ND
30.2 3.02 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,2-Dichloropropane ND
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-7Client Sample ID: Y-2970 R2 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,3,5-Trimethylbenzene ND 30.2 6.28 ug/Sample 11/29/19 10:48 12/06/19 23:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.2 5.20 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,3-Dichlorobenzene ND
30.2 3.38 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,3-Dichloropropane ND
30.2 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 11,4-Dichlorobenzene ND
60.4 6.16 ug/Sample 11/29/19 10:48 12/06/19 23:21 11-Chloro-1,1-difluoroethane ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
30.2 8.82 ug/Sample 11/29/19 10:48 12/06/19 23:21 12,2-Dichloropropane ND
121 19.3 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-Butanone (MEK)ND
60.4 8.94 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
60.4 6.04 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-Chloro-1,1,1-Trifluoroethane ND
30.2 5.68 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-Chlorotoluene ND
121 27.8 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-Hexanone ND
26.4 26.4 ug/Sample 11/29/19 10:48 12/06/19 23:21 12-MTP as HFPO 467
30.2 6.28 ug/Sample 11/29/19 10:48 12/06/19 23:21 14-Chlorotoluene ND
30.2 8.09 ug/Sample 11/29/19 10:48 12/06/19 23:21 14-Isopropyltoluene ND
121 19.3 ug/Sample 11/29/19 10:48 12/06/19 23:21 14-Methyl-2-pentanone (MIBK)ND
121 71.3 ug/Sample 11/29/19 10:48 12/06/19 23:21 1AcetoneND
30.2 5.80 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BenzeneND
30.2 4.23 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BromobenzeneND
30.2 6.77 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BromochloromethaneND
30.2 5.20 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BromodichloromethaneND
30.2 9.18 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BromoformND
60.4 35.0 ug/Sample 11/29/19 10:48 12/06/19 23:21 1BromomethaneND
30.2 7.49 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Carbon disulfide ND
30.2 3.99 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Carbon tetrachloride ND
88.7 88.7 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Carbonyl Difluoride ND
30.2 4.35 ug/Sample 11/29/19 10:48 12/06/19 23:21 1ChlorobenzeneND
30.2 6.52 ug/Sample 11/29/19 10:48 12/06/19 23:21 1ChlorodibromomethaneND
60.4 13.3 ug/Sample 11/29/19 10:48 12/06/19 23:21 1ChloroethaneND
30.2 3.50 ug/Sample 11/29/19 10:48 12/06/19 23:21 1ChloroformND
60.4 25.1 ug/Sample 11/29/19 10:48 12/06/19 23:21 1ChloromethaneND
30.2 2.42 ug/Sample 11/29/19 10:48 12/06/19 23:21 1cis-1,2-Dichloroethene ND
30.2 5.20 ug/Sample 11/29/19 10:48 12/06/19 23:21 1cis-1,3-Dichloropropene ND
30.2 2.90 ug/Sample 11/29/19 10:48 12/06/19 23:21 1DibromomethaneND
60.4 10.6 ug/Sample 11/29/19 10:48 12/06/19 23:21 1DichlorodifluoromethaneND
30.2 4.95 ug/Sample 11/29/19 10:48 12/06/19 23:21 1EthylbenzeneND
30.2 30.2 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
550
30.2 7.97 ug/Sample 11/29/19 10:48 12/06/19 23:21 1HexachlorobutadieneND
29.0 29.0 ug/Sample 11/29/19 10:48 12/06/19 23:21 1HFPO dimer, methyl ester as
HFPO-DA
ND
30.2 4.23 ug/Sample 11/29/19 10:48 12/06/19 23:21 1IsopropylbenzeneND
60.4 4.95 ug/Sample 11/29/19 10:48 12/06/19 23:21 1m,p-Xylene ND
30.2 19.3 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Methylene Chloride 116
30.2 14.5 ug/Sample 11/29/19 10:48 12/06/19 23:21 1NaphthaleneND
30.2 7.73 ug/Sample 11/29/19 10:48 12/06/19 23:21 1n-Butylbenzene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 29 of 89480
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-7Client Sample ID: Y-2970 R2 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Propylbenzene ND 30.2 6.52 ug/Sample 11/29/19 10:48 12/06/19 23:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.2 3.14 ug/Sample 11/29/19 10:48 12/06/19 23:21 1o-Xylene ND
30.2 5.92 ug/Sample 11/29/19 10:48 12/06/19 23:21 1sec-Butylbenzene ND
30.2 6.52 ug/Sample 11/29/19 10:48 12/06/19 23:21 1StyreneND
30.2 5.32 ug/Sample 11/29/19 10:48 12/06/19 23:21 1tert-Butylbenzene ND
30.2 3.99 ug/Sample 11/29/19 10:48 12/06/19 23:21 1TetrachloroetheneND
30.2 5.56 ug/Sample 11/29/19 10:48 12/06/19 23:21 1TolueneND
30.2 3.14 ug/Sample 11/29/19 10:48 12/06/19 23:21 1trans-1,2-Dichloroethene ND
30.2 10.6 ug/Sample 11/29/19 10:48 12/06/19 23:21 1trans-1,3-Dichloropropene ND
30.2 2.17 ug/Sample 11/29/19 10:48 12/06/19 23:21 1TrichloroetheneND
60.4 5.80 ug/Sample 11/29/19 10:48 12/06/19 23:21 1TrichlorofluoromethaneND *
60.4 14.5 ug/Sample 11/29/19 10:48 12/06/19 23:21 1Vinyl chloride ND
Unknown 275 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 23:21 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 23:2111/29/19 10:48T JUnknown2960 ug/Sample 1.18
112/06/19 23:2111/29/19 10:48T JUnknown57.2 ug/Sample 1.22
112/06/19 23:2111/29/19 10:48T JUnknown229 ug/Sample 2.12
112/06/19 23:2111/29/19 10:48T JUnknown104 ug/Sample 2.50
112/06/19 23:2111/29/19 10:48T J NCyclohexane 110-82-736.3 ug/Sample 4.42
1,2-Dichloroethane-d4 (Surr)118 70 -160 11/29/19 10:48 12/06/19 23:21 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:48 12/06/19 23:21 157-152
Dibromofluoromethane (Surr)105 11/29/19 10:48 12/06/19 23:21 162-134
Toluene-d8 (Surr)96 11/29/19 10:48 12/06/19 23:21 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 6490 6440 3220 ug/Sample 11/29/19 10:48 12/12/19 00:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2660 1210 ug/Sample 11/29/19 10:48 12/18/19 09:46 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-8Client Sample ID: Y-2971 R2 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 29.6 3.90 ug/Sample 11/29/19 10:48 12/06/19 23:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,1,3,3-Pentafluorobutane ND
29.6 4.26 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,1-Trichloroethane ND
59.1 11.7 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,1-Trifluoro-2,2-dichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 30 of 89481
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-8Client Sample ID: Y-2971 R2 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,1-Trifluoroethane ND 59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.6 5.67 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,2,2-Tetrachloroethane ND
59.1 3.31 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,2-Trichloro-1,2,2-trifluoroethane ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,2-trichloro-1-fluoroethane ND
29.6 3.07 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1,2-Trichloroethane ND
59.1 29.6 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-Dichloro-1-fluoroethane ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-dichloro-2,2-difluoroethane ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-dichloro-2,2-difluoroethene ND
29.6 3.55 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-Dichloroethane ND
29.6 4.37 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-Dichloroethene ND
29.6 3.19 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-Dichloropropene ND
591 591 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,1-Difluoroethene ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2,2-trichloro-1,1-difluoroethane ND
29.6 9.46 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2,3-Trichlorobenzene ND
29.6 7.33 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2,3-Trichloropropane ND
29.6 9.93 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2,4-Trichlorobenzene ND
29.6 6.15 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2,4-Trimethylbenzene ND
59.1 10.4 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-Dibromo-3-Chloropropane ND
29.6 3.90 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-Dibromoethane (EDB)ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-dichloro-1,1-difluoroethane ND
29.6 5.20 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-Dichlorobenzene ND
29.6 4.96 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-Dichloroethane ND
29.6 2.96 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,2-Dichloropropane ND
29.6 6.15 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,3,5-Trimethylbenzene ND
29.6 5.08 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,3-Dichlorobenzene ND
29.6 3.31 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,3-Dichloropropane ND
29.6 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 11,4-Dichlorobenzene ND
59.1 6.03 ug/Sample 11/29/19 10:48 12/06/19 23:46 11-Chloro-1,1-difluoroethane ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
29.6 8.63 ug/Sample 11/29/19 10:48 12/06/19 23:46 12,2-Dichloropropane ND
118 18.9 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-Butanone (MEK)ND
59.1 8.75 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
59.1 5.91 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-Chloro-1,1,1-Trifluoroethane ND
29.6 5.56 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-Chlorotoluene ND
118 27.2 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-Hexanone ND
25.9 25.9 ug/Sample 11/29/19 10:48 12/06/19 23:46 12-MTP as HFPO 610
29.6 6.15 ug/Sample 11/29/19 10:48 12/06/19 23:46 14-Chlorotoluene ND
29.6 7.92 ug/Sample 11/29/19 10:48 12/06/19 23:46 14-Isopropyltoluene ND
118 18.9 ug/Sample 11/29/19 10:48 12/06/19 23:46 14-Methyl-2-pentanone (MIBK)ND
118 69.7 ug/Sample 11/29/19 10:48 12/06/19 23:46 1AcetoneND
29.6 5.67 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BenzeneND
29.6 4.14 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BromobenzeneND
29.6 6.62 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BromochloromethaneND
29.6 5.08 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BromodichloromethaneND
29.6 8.98 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BromoformND
59.1 34.3 ug/Sample 11/29/19 10:48 12/06/19 23:46 1BromomethaneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 31 of 89482
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-8Client Sample ID: Y-2971 R2 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Carbon disulfide ND 29.6 7.33 ug/Sample 11/29/19 10:48 12/06/19 23:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.6 3.90 ug/Sample 11/29/19 10:48 12/06/19 23:46 1Carbon tetrachloride ND
86.5 86.5 ug/Sample 11/29/19 10:48 12/06/19 23:46 1Carbonyl Difluoride ND
29.6 4.26 ug/Sample 11/29/19 10:48 12/06/19 23:46 1ChlorobenzeneND
29.6 6.38 ug/Sample 11/29/19 10:48 12/06/19 23:46 1ChlorodibromomethaneND
59.1 13.0 ug/Sample 11/29/19 10:48 12/06/19 23:46 1ChloroethaneND
29.6 3.43 ug/Sample 11/29/19 10:48 12/06/19 23:46 1ChloroformND
59.1 24.6 ug/Sample 11/29/19 10:48 12/06/19 23:46 1ChloromethaneND
29.6 2.36 ug/Sample 11/29/19 10:48 12/06/19 23:46 1cis-1,2-Dichloroethene ND
29.6 5.08 ug/Sample 11/29/19 10:48 12/06/19 23:46 1cis-1,3-Dichloropropene ND
29.6 2.84 ug/Sample 11/29/19 10:48 12/06/19 23:46 1DibromomethaneND
59.1 10.4 ug/Sample 11/29/19 10:48 12/06/19 23:46 1DichlorodifluoromethaneND
29.6 4.85 ug/Sample 11/29/19 10:48 12/06/19 23:46 1EthylbenzeneND
29.6 29.6 ug/Sample 11/29/19 10:48 12/06/19 23:46 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
193
29.6 7.80 ug/Sample 11/29/19 10:48 12/06/19 23:46 1HexachlorobutadieneND
28.4 28.4 ug/Sample 11/29/19 10:48 12/06/19 23:46 1HFPO dimer, methyl ester as
HFPO-DA
ND
29.6 4.14 ug/Sample 11/29/19 10:48 12/06/19 23:46 1IsopropylbenzeneND
59.1 4.85 ug/Sample 11/29/19 10:48 12/06/19 23:46 1m,p-Xylene ND
29.6 18.9 ug/Sample 11/29/19 10:48 12/06/19 23:46 1Methylene Chloride ND
29.6 14.2 ug/Sample 11/29/19 10:48 12/06/19 23:46 1NaphthaleneND
29.6 7.57 ug/Sample 11/29/19 10:48 12/06/19 23:46 1n-Butylbenzene ND
29.6 6.38 ug/Sample 11/29/19 10:48 12/06/19 23:46 1n-Propylbenzene ND
29.6 3.07 ug/Sample 11/29/19 10:48 12/06/19 23:46 1o-Xylene ND
29.6 5.79 ug/Sample 11/29/19 10:48 12/06/19 23:46 1sec-Butylbenzene ND
29.6 6.38 ug/Sample 11/29/19 10:48 12/06/19 23:46 1StyreneND
29.6 5.20 ug/Sample 11/29/19 10:48 12/06/19 23:46 1tert-Butylbenzene ND
29.6 3.90 ug/Sample 11/29/19 10:48 12/06/19 23:46 1TetrachloroetheneND
29.6 5.44 ug/Sample 11/29/19 10:48 12/06/19 23:46 1TolueneND
29.6 3.07 ug/Sample 11/29/19 10:48 12/06/19 23:46 1trans-1,2-Dichloroethene ND
29.6 10.4 ug/Sample 11/29/19 10:48 12/06/19 23:46 1trans-1,3-Dichloropropene ND
29.6 2.13 ug/Sample 11/29/19 10:48 12/06/19 23:46 1TrichloroetheneND
59.1 5.67 ug/Sample 11/29/19 10:48 12/06/19 23:46 1TrichlorofluoromethaneND *
59.1 14.2 ug/Sample 11/29/19 10:48 12/06/19 23:46 1Vinyl chloride ND
Unknown 341 T J ug/Sample 1.13 11/29/19 10:48 12/06/19 23:46 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/06/19 23:4611/29/19 10:48T JUnknown2160 ug/Sample 1.19
112/06/19 23:4611/29/19 10:48T J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-849.7 ug/Sample 1.22
112/06/19 23:4611/29/19 10:48T J NCyclohexane 110-82-739.7 ug/Sample 4.42
112/06/19 23:4611/29/19 10:48T J NCyclotetrasiloxane, octamethyl-556-67-231.6 ug/Sample 8.78
112/06/19 23:4611/29/19 10:48T J NSalicylic acid, 2TMS derivative 3789-85-330.7 ug/Sample 11.36
112/06/19 23:4611/29/19 10:48T JUnknown56.3 ug/Sample 13.17
1,2-Dichloroethane-d4 (Surr)115 70 -160 11/29/19 10:48 12/06/19 23:46 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-8Client Sample ID: Y-2971 R2 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
4-Bromofluorobenzene (Surr)110 57 -152 11/29/19 10:48 12/06/19 23:46 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Dibromofluoromethane (Surr)104 11/29/19 10:48 12/06/19 23:46 162-134
Toluene-d8 (Surr)97 11/29/19 10:48 12/06/19 23:46 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 24300 6380 3190 ug/Sample 11/29/19 10:48 12/13/19 18:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2600 1180 ug/Sample 11/29/19 10:48 12/18/19 10:09 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-9Client Sample ID: Y-2972 R2 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND H 30.8 4.06 ug/Sample 11/29/19 10:48 12/07/19 00:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,1,3,3-Pentafluorobutane ND H
30.8 4.43 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,1-Trichloroethane ND H
61.5 12.2 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,1-Trifluoro-2,2-dichloroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,1-Trifluoroethane ND H
30.8 5.91 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,2,2-Tetrachloroethane ND H
61.5 3.45 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,2-Trichloro-1,2,2-trifluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,2-trichloro-1-fluoroethane ND H
30.8 3.20 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1,2-Trichloroethane ND H
61.5 30.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-Dichloro-1-fluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-dichloro-2,2-difluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-dichloro-2,2-difluoroethene ND H
30.8 3.69 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-Dichloroethane ND H
30.8 4.55 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-Dichloroethene ND H
30.8 3.32 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-Dichloropropene ND H
615 615 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,1-Difluoroethene ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2,2-trichloro-1,1-difluoroethane ND H
30.8 9.85 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2,3-Trichlorobenzene ND H
30.8 7.63 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2,3-Trichloropropane ND H
30.8 10.3 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2,4-Trichlorobenzene ND H
30.8 6.40 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2,4-Trimethylbenzene ND H
61.5 10.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2-Dibromo-3-Chloropropane ND H
30.8 4.06 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2-Dibromoethane (EDB)ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2-dichloro-1,1-difluoroethane ND H
30.8 5.42 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2-Dichlorobenzene ND H
30.8 5.17 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,2-Dichloroethane ND H
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-9Client Sample ID: Y-2972 R2 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2-Dichloropropane ND H 30.8 3.08 ug/Sample 11/29/19 10:48 12/07/19 00:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.8 6.40 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,3,5-Trimethylbenzene ND H
30.8 5.29 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,3-Dichlorobenzene ND H
30.8 3.45 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,3-Dichloropropane ND H
30.8 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 11,4-Dichlorobenzene ND H
61.5 6.28 ug/Sample 11/29/19 10:48 12/07/19 00:10 11-Chloro-1,1-difluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND H
30.8 8.98 ug/Sample 11/29/19 10:48 12/07/19 00:10 12,2-Dichloropropane ND H
123 19.7 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-Butanone (MEK)ND H
61.5 9.11 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-Chloro-1,1,1-Trifluoroethane ND H
30.8 5.78 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-Chlorotoluene ND H
123 28.3 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-Hexanone ND H
26.9 26.9 ug/Sample 11/29/19 10:48 12/07/19 00:10 12-MTP as HFPO 609 H
30.8 6.40 ug/Sample 11/29/19 10:48 12/07/19 00:10 14-Chlorotoluene ND H
30.8 8.25 ug/Sample 11/29/19 10:48 12/07/19 00:10 14-Isopropyltoluene ND H
123 19.7 ug/Sample 11/29/19 10:48 12/07/19 00:10 14-Methyl-2-pentanone (MIBK)ND H
123 72.6 ug/Sample 11/29/19 10:48 12/07/19 00:10 1AcetoneND H
30.8 5.91 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BenzeneND H
30.8 4.31 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BromobenzeneND H
30.8 6.89 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BromochloromethaneND H
30.8 5.29 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BromodichloromethaneND H
30.8 9.35 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BromoformND H
61.5 35.7 ug/Sample 11/29/19 10:48 12/07/19 00:10 1BromomethaneND H
30.8 7.63 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Carbon disulfide ND H
30.8 4.06 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Carbon tetrachloride ND H
90.1 90.1 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Carbonyl Difluoride ND H
30.8 4.43 ug/Sample 11/29/19 10:48 12/07/19 00:10 1ChlorobenzeneND H
30.8 6.65 ug/Sample 11/29/19 10:48 12/07/19 00:10 1ChlorodibromomethaneND H
61.5 13.5 ug/Sample 11/29/19 10:48 12/07/19 00:10 1ChloroethaneND H
30.8 3.57 ug/Sample 11/29/19 10:48 12/07/19 00:10 1ChloroformND H
61.5 25.6 ug/Sample 11/29/19 10:48 12/07/19 00:10 1ChloromethaneND H
30.8 2.46 ug/Sample 11/29/19 10:48 12/07/19 00:10 1cis-1,2-Dichloroethene ND H
30.8 5.29 ug/Sample 11/29/19 10:48 12/07/19 00:10 1cis-1,3-Dichloropropene ND H
30.8 2.95 ug/Sample 11/29/19 10:48 12/07/19 00:10 1DibromomethaneND H
61.5 10.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 1DichlorodifluoromethaneND H
30.8 5.05 ug/Sample 11/29/19 10:48 12/07/19 00:10 1EthylbenzeneND H
30.8 30.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND H
30.8 8.12 ug/Sample 11/29/19 10:48 12/07/19 00:10 1HexachlorobutadieneND H
29.5 29.5 ug/Sample 11/29/19 10:48 12/07/19 00:10 1HFPO dimer, methyl ester as
HFPO-DA
ND H
30.8 4.31 ug/Sample 11/29/19 10:48 12/07/19 00:10 1IsopropylbenzeneND H
61.5 5.05 ug/Sample 11/29/19 10:48 12/07/19 00:10 1m,p-Xylene ND H
30.8 19.7 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Methylene Chloride ND H
30.8 14.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 1NaphthaleneND H
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-9Client Sample ID: Y-2972 R2 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Butylbenzene ND H 30.8 7.88 ug/Sample 11/29/19 10:48 12/07/19 00:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.8 6.65 ug/Sample 11/29/19 10:48 12/07/19 00:10 1n-Propylbenzene ND H
30.8 3.20 ug/Sample 11/29/19 10:48 12/07/19 00:10 1o-Xylene ND H
30.8 6.03 ug/Sample 11/29/19 10:48 12/07/19 00:10 1sec-Butylbenzene ND H
30.8 6.65 ug/Sample 11/29/19 10:48 12/07/19 00:10 1StyreneND H
30.8 5.42 ug/Sample 11/29/19 10:48 12/07/19 00:10 1tert-Butylbenzene ND H
30.8 4.06 ug/Sample 11/29/19 10:48 12/07/19 00:10 1TetrachloroetheneND H
30.8 5.66 ug/Sample 11/29/19 10:48 12/07/19 00:10 1TolueneND H
30.8 3.20 ug/Sample 11/29/19 10:48 12/07/19 00:10 1trans-1,2-Dichloroethene ND H
30.8 10.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 1trans-1,3-Dichloropropene ND H
30.8 2.22 ug/Sample 11/29/19 10:48 12/07/19 00:10 1TrichloroetheneND H
61.5 5.91 ug/Sample 11/29/19 10:48 12/07/19 00:10 1TrichlorofluoromethaneND H *
61.5 14.8 ug/Sample 11/29/19 10:48 12/07/19 00:10 1Vinyl chloride ND H
Unknown 490 T H J ug/Sample 1.13 11/29/19 10:48 12/07/19 00:10 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/07/19 00:1011/29/19 10:48T H J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-82290ug/Sample 1.18
112/07/19 00:1011/29/19 10:48T H J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-841.0 ug/Sample 1.22
112/07/19 00:1011/29/19 10:48T H J NCyclohexane 110-82-742.6 ug/Sample 4.42
1,2-Dichloroethane-d4 (Surr)118 70 -160 11/29/19 10:48 12/07/19 00:10 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:48 12/07/19 00:10 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:48 12/07/19 00:10 162-134
Toluene-d8 (Surr)97 11/29/19 10:48 12/07/19 00:10 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 3770 J 6560 3280 ug/Sample 11/29/19 10:48 12/13/19 19:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2710 1230 ug/Sample 11/29/19 10:48 12/18/19 11:11 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-10Client Sample ID: Y-2973 R2 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND H 30.4 4.01 ug/Sample 11/29/19 10:48 12/07/19 00:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,1,3,3-Pentafluorobutane ND H
30.4 4.38 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,1-Trichloroethane ND H
60.8 12.0 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,1-Trifluoro-2,2-dichloroethane ND H
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-10Client Sample ID: Y-2973 R2 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,1-Trifluoroethane ND H 60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.4 5.84 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,2,2-Tetrachloroethane ND H
60.8 3.41 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,2-Trichloro-1,2,2-trifluoroethane ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,2-trichloro-1-fluoroethane ND H
30.4 3.16 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1,2-Trichloroethane ND H
60.8 30.4 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-Dichloro-1-fluoroethane ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-dichloro-2,2-difluoroethane ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-dichloro-2,2-difluoroethene ND H
30.4 3.65 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-Dichloroethane ND H
30.4 4.50 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-Dichloroethene ND H
30.4 3.28 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-Dichloropropene ND H
608 608 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,1-Difluoroethene ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2,2-trichloro-1,1-difluoroethane ND H
30.4 9.73 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2,3-Trichlorobenzene ND H
30.4 7.54 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2,3-Trichloropropane ND H
30.4 10.2 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2,4-Trichlorobenzene ND H
30.4 6.32 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2,4-Trimethylbenzene ND H
60.8 10.7 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-Dibromo-3-Chloropropane ND H
30.4 4.01 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-Dibromoethane (EDB)ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-dichloro-1,1-difluoroethane ND H
30.4 5.35 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-Dichlorobenzene ND H
30.4 5.11 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-Dichloroethane ND H
30.4 3.04 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,2-Dichloropropane ND H
30.4 6.32 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,3,5-Trimethylbenzene ND H
30.4 5.23 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,3-Dichlorobenzene ND H
30.4 3.41 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,3-Dichloropropane ND H
30.4 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 11,4-Dichlorobenzene ND H
60.8 6.20 ug/Sample 11/29/19 10:48 12/07/19 00:35 11-Chloro-1,1-difluoroethane ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND H
30.4 8.88 ug/Sample 11/29/19 10:48 12/07/19 00:35 12,2-Dichloropropane ND H
122 19.5 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-Butanone (MEK)ND H
60.8 9.00 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND H
60.8 6.08 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-Chloro-1,1,1-Trifluoroethane ND H
30.4 5.72 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-Chlorotoluene ND H
122 28.0 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-Hexanone ND H
26.6 26.6 ug/Sample 11/29/19 10:48 12/07/19 00:35 12-MTP as HFPO 629 H
30.4 6.32 ug/Sample 11/29/19 10:48 12/07/19 00:35 14-Chlorotoluene ND H
30.4 8.15 ug/Sample 11/29/19 10:48 12/07/19 00:35 14-Isopropyltoluene ND H
122 19.5 ug/Sample 11/29/19 10:48 12/07/19 00:35 14-Methyl-2-pentanone (MIBK)ND H
122 71.8 ug/Sample 11/29/19 10:48 12/07/19 00:35 1AcetoneND H
30.4 5.84 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BenzeneND H
30.4 4.26 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BromobenzeneND H
30.4 6.81 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BromochloromethaneND H
30.4 5.23 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BromodichloromethaneND H
30.4 9.24 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BromoformND H
60.8 35.3 ug/Sample 11/29/19 10:48 12/07/19 00:35 1BromomethaneND H
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-10Client Sample ID: Y-2973 R2 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Carbon disulfide ND H 30.4 7.54 ug/Sample 11/29/19 10:48 12/07/19 00:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.4 4.01 ug/Sample 11/29/19 10:48 12/07/19 00:35 1Carbon tetrachloride ND H
89.4 89.4 ug/Sample 11/29/19 10:48 12/07/19 00:35 1Carbonyl Difluoride ND H
30.4 4.38 ug/Sample 11/29/19 10:48 12/07/19 00:35 1ChlorobenzeneND H
30.4 6.57 ug/Sample 11/29/19 10:48 12/07/19 00:35 1ChlorodibromomethaneND H
60.8 13.4 ug/Sample 11/29/19 10:48 12/07/19 00:35 1ChloroethaneND H
30.4 3.53 ug/Sample 11/29/19 10:48 12/07/19 00:35 1ChloroformND H
60.8 25.3 ug/Sample 11/29/19 10:48 12/07/19 00:35 1ChloromethaneND H
30.4 2.43 ug/Sample 11/29/19 10:48 12/07/19 00:35 1cis-1,2-Dichloroethene ND H
30.4 5.23 ug/Sample 11/29/19 10:48 12/07/19 00:35 1cis-1,3-Dichloropropene ND H
30.4 2.92 ug/Sample 11/29/19 10:48 12/07/19 00:35 1DibromomethaneND H
60.8 10.7 ug/Sample 11/29/19 10:48 12/07/19 00:35 1DichlorodifluoromethaneND H
30.4 4.99 ug/Sample 11/29/19 10:48 12/07/19 00:35 1EthylbenzeneND H
30.4 30.4 ug/Sample 11/29/19 10:48 12/07/19 00:35 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND H
30.4 8.03 ug/Sample 11/29/19 10:48 12/07/19 00:35 1HexachlorobutadieneND H
29.2 29.2 ug/Sample 11/29/19 10:48 12/07/19 00:35 1HFPO dimer, methyl ester as
HFPO-DA
ND H
30.4 4.26 ug/Sample 11/29/19 10:48 12/07/19 00:35 1IsopropylbenzeneND H
60.8 4.99 ug/Sample 11/29/19 10:48 12/07/19 00:35 1m,p-Xylene ND H
30.4 19.5 ug/Sample 11/29/19 10:48 12/07/19 00:35 1Methylene Chloride ND H
30.4 14.6 ug/Sample 11/29/19 10:48 12/07/19 00:35 1NaphthaleneND H
30.4 7.78 ug/Sample 11/29/19 10:48 12/07/19 00:35 1n-Butylbenzene ND H
30.4 6.57 ug/Sample 11/29/19 10:48 12/07/19 00:35 1n-Propylbenzene ND H
30.4 3.16 ug/Sample 11/29/19 10:48 12/07/19 00:35 1o-Xylene ND H
30.4 5.96 ug/Sample 11/29/19 10:48 12/07/19 00:35 1sec-Butylbenzene ND H
30.4 6.57 ug/Sample 11/29/19 10:48 12/07/19 00:35 1StyreneND H
30.4 5.35 ug/Sample 11/29/19 10:48 12/07/19 00:35 1tert-Butylbenzene ND H
30.4 4.01 ug/Sample 11/29/19 10:48 12/07/19 00:35 1TetrachloroetheneND H
30.4 5.59 ug/Sample 11/29/19 10:48 12/07/19 00:35 1TolueneND H
30.4 3.16 ug/Sample 11/29/19 10:48 12/07/19 00:35 1trans-1,2-Dichloroethene ND H
30.4 10.7 ug/Sample 11/29/19 10:48 12/07/19 00:35 1trans-1,3-Dichloropropene ND H
30.4 2.19 ug/Sample 11/29/19 10:48 12/07/19 00:35 1TrichloroetheneND H
60.8 5.84 ug/Sample 11/29/19 10:48 12/07/19 00:35 1TrichlorofluoromethaneND H *
60.8 14.6 ug/Sample 11/29/19 10:48 12/07/19 00:35 1Vinyl chloride ND H
Butanoic acid, heptafluoro-, sodium
salt
484 T H J N ug/Sample 1.13 2218-54-4 11/29/19 10:48 12/07/19 00:35 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/07/19 00:3511/29/19 10:48T H JUnknown1700 ug/Sample 1.18
112/07/19 00:3511/29/19 10:48T H J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-831.6 ug/Sample 1.22
112/07/19 00:3511/29/19 10:48T H J NCyclohexane 110-82-743.2 ug/Sample 4.42
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:48 12/07/19 00:35 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 11/29/19 10:48 12/07/19 00:35 157-152
Dibromofluoromethane (Surr)103 11/29/19 10:48 12/07/19 00:35 162-134
Toluene-d8 (Surr)97 11/29/19 10:48 12/07/19 00:35 171-139
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-10Client Sample ID: Y-2973 R2 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 3540 J 6490 3240 ug/Sample 11/29/19 10:48 12/13/19 20:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2680 1220 ug/Sample 11/29/19 10:48 12/18/19 12:15 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-11Client Sample ID: Y-2974 R2 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND H 31.4 4.14 ug/Sample 11/29/19 10:48 12/07/19 00:59 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,1,3,3-Pentafluorobutane ND H
31.4 4.52 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,1-Trichloroethane ND H
62.7 12.4 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,1-Trifluoro-2,2-dichloroethane ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,1-Trifluoroethane ND H
31.4 6.02 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,2,2-Tetrachloroethane ND H
62.7 3.51 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,2-Trichloro-1,2,2-trifluoroethane ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,2-trichloro-1-fluoroethane ND H
31.4 3.26 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1,2-Trichloroethane ND H
62.7 31.4 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-Dichloro-1-fluoroethane ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-dichloro-2,2-difluoroethane ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-dichloro-2,2-difluoroethene ND H
31.4 3.76 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-Dichloroethane ND H
31.4 4.64 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-Dichloroethene ND H
31.4 3.39 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-Dichloropropene ND H
627 627 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,1-Difluoroethene ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2,2-trichloro-1,1-difluoroethane ND H
31.4 10.0 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2,3-Trichlorobenzene ND H
31.4 7.78 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2,3-Trichloropropane ND H
31.4 10.5 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2,4-Trichlorobenzene ND H
31.4 6.53 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2,4-Trimethylbenzene ND H
62.7 11.0 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-Dibromo-3-Chloropropane ND H
31.4 4.14 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-Dibromoethane (EDB)ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-dichloro-1,1-difluoroethane ND H
31.4 5.52 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-Dichlorobenzene ND H
31.4 5.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-Dichloroethane ND H
31.4 3.14 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,2-Dichloropropane ND H
31.4 6.53 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,3,5-Trimethylbenzene ND H
31.4 5.40 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,3-Dichlorobenzene ND H
31.4 3.51 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,3-Dichloropropane ND H
31.4 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 11,4-Dichlorobenzene ND H
62.7 6.40 ug/Sample 11/29/19 10:48 12/07/19 00:59 11-Chloro-1,1-difluoroethane ND H
Eurofins TestAmerica, Knoxville
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Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-11Client Sample ID: Y-2974 R2 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
2,2-dichloro-1,1-difluoroethylmethyl
ether
ND H 62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
31.4 9.16 ug/Sample 11/29/19 10:48 12/07/19 00:59 12,2-Dichloropropane ND H
125 20.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-Butanone (MEK)ND H
62.7 9.29 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND H
62.7 6.27 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-Chloro-1,1,1-Trifluoroethane ND H
31.4 5.90 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-Chlorotoluene ND H
125 28.9 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-Hexanone ND H
27.4 27.4 ug/Sample 11/29/19 10:48 12/07/19 00:59 12-MTP as HFPO 609 H
31.4 6.53 ug/Sample 11/29/19 10:48 12/07/19 00:59 14-Chlorotoluene ND H
31.4 8.41 ug/Sample 11/29/19 10:48 12/07/19 00:59 14-Isopropyltoluene ND H
125 20.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 14-Methyl-2-pentanone (MIBK)ND H
125 74.0 ug/Sample 11/29/19 10:48 12/07/19 00:59 1AcetoneND H
31.4 6.02 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BenzeneND H
31.4 4.39 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BromobenzeneND H
31.4 7.03 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BromochloromethaneND H
31.4 5.40 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BromodichloromethaneND H
31.4 9.54 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BromoformND H
62.7 36.4 ug/Sample 11/29/19 10:48 12/07/19 00:59 1BromomethaneND H
31.4 7.78 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Carbon disulfide ND H
31.4 4.14 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Carbon tetrachloride ND H
91.6 91.6 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Carbonyl Difluoride ND H
31.4 4.52 ug/Sample 11/29/19 10:48 12/07/19 00:59 1ChlorobenzeneND H
31.4 6.78 ug/Sample 11/29/19 10:48 12/07/19 00:59 1ChlorodibromomethaneND H
62.7 13.8 ug/Sample 11/29/19 10:48 12/07/19 00:59 1ChloroethaneND H
31.4 3.64 ug/Sample 11/29/19 10:48 12/07/19 00:59 1ChloroformND H
62.7 26.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 1ChloromethaneND H
31.4 2.51 ug/Sample 11/29/19 10:48 12/07/19 00:59 1cis-1,2-Dichloroethene ND H
31.4 5.40 ug/Sample 11/29/19 10:48 12/07/19 00:59 1cis-1,3-Dichloropropene ND H
31.4 3.01 ug/Sample 11/29/19 10:48 12/07/19 00:59 1DibromomethaneND H
62.7 11.0 ug/Sample 11/29/19 10:48 12/07/19 00:59 1DichlorodifluoromethaneND H
31.4 5.15 ug/Sample 11/29/19 10:48 12/07/19 00:59 1EthylbenzeneND H
31.4 31.4 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND H
31.4 8.28 ug/Sample 11/29/19 10:48 12/07/19 00:59 1HexachlorobutadieneND H
30.1 30.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 1HFPO dimer, methyl ester as
HFPO-DA
ND H
31.4 4.39 ug/Sample 11/29/19 10:48 12/07/19 00:59 1IsopropylbenzeneND H
62.7 5.15 ug/Sample 11/29/19 10:48 12/07/19 00:59 1m,p-Xylene ND H
31.4 20.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Methylene Chloride ND H
31.4 15.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 1NaphthaleneND H
31.4 8.03 ug/Sample 11/29/19 10:48 12/07/19 00:59 1n-Butylbenzene ND H
31.4 6.78 ug/Sample 11/29/19 10:48 12/07/19 00:59 1n-Propylbenzene ND H
31.4 3.26 ug/Sample 11/29/19 10:48 12/07/19 00:59 1o-Xylene ND H
31.4 6.15 ug/Sample 11/29/19 10:48 12/07/19 00:59 1sec-Butylbenzene ND H
31.4 6.78 ug/Sample 11/29/19 10:48 12/07/19 00:59 1StyreneND H
31.4 5.52 ug/Sample 11/29/19 10:48 12/07/19 00:59 1tert-Butylbenzene ND H
Eurofins TestAmerica, Knoxville
12/23/2019Page 39 of 89490
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-11Client Sample ID: Y-2974 R2 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Tetrachloroethene ND H 31.4 4.14 ug/Sample 11/29/19 10:48 12/07/19 00:59 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
31.4 5.77 ug/Sample 11/29/19 10:48 12/07/19 00:59 1TolueneND H
31.4 3.26 ug/Sample 11/29/19 10:48 12/07/19 00:59 1trans-1,2-Dichloroethene ND H
31.4 11.0 ug/Sample 11/29/19 10:48 12/07/19 00:59 1trans-1,3-Dichloropropene ND H
31.4 2.26 ug/Sample 11/29/19 10:48 12/07/19 00:59 1TrichloroetheneND H
62.7 6.02 ug/Sample 11/29/19 10:48 12/07/19 00:59 1TrichlorofluoromethaneND H *
62.7 15.1 ug/Sample 11/29/19 10:48 12/07/19 00:59 1Vinyl chloride ND H
Propene, hexafluoro-421 T H J N ug/Sample 1.13 116-15-4 11/29/19 10:48 12/07/19 00:59 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/07/19 00:5911/29/19 10:48T H JUnknown882 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)116 70 -160 11/29/19 10:48 12/07/19 00:59 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:48 12/07/19 00:59 157-152
Dibromofluoromethane (Surr)105 11/29/19 10:48 12/07/19 00:59 162-134
Toluene-d8 (Surr)96 11/29/19 10:48 12/07/19 00:59 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine ND 6690 3350 ug/Sample 11/29/19 10:48 12/13/19 20:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2760 1250 ug/Sample 11/29/19 10:48 12/18/19 12:38 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17461-12Client Sample ID: Y-2975 R2 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND H 30.7 4.06 ug/Sample 11/29/19 10:48 12/07/19 01:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,1,3,3-Pentafluorobutane ND H
30.7 4.43 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,1-Trichloroethane ND H
61.5 12.2 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,1-Trifluoro-2,2-dichloroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,1-Trifluoroethane ND H
30.7 5.90 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,2,2-Tetrachloroethane ND H
61.5 3.44 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,2-Trichloro-1,2,2-trifluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,2-trichloro-1-fluoroethane ND H
30.7 3.20 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1,2-Trichloroethane ND H
61.5 30.7 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-Dichloro-1-fluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-dichloro-2,2-difluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-dichloro-2,2-difluoroethene ND H
30.7 3.69 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-Dichloroethane ND H
Eurofins TestAmerica, Knoxville
12/23/2019Page 40 of 89491
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-12Client Sample ID: Y-2975 R2 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1-Dichloroethene ND H 30.7 4.55 ug/Sample 11/29/19 10:48 12/07/19 01:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.7 3.32 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-Dichloropropene ND H
615 615 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,1-Difluoroethene ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2,2-trichloro-1,1-difluoroethane ND H
30.7 9.83 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2,3-Trichlorobenzene ND H
30.7 7.62 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2,3-Trichloropropane ND H
30.7 10.3 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2,4-Trichlorobenzene ND H
30.7 6.39 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2,4-Trimethylbenzene ND H
61.5 10.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-Dibromo-3-Chloropropane ND H
30.7 4.06 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-Dibromoethane (EDB)ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-dichloro-1,1-difluoroethane ND H
30.7 5.41 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-Dichlorobenzene ND H
30.7 5.16 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-Dichloroethane ND H
30.7 3.07 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,2-Dichloropropane ND H
30.7 6.39 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,3,5-Trimethylbenzene ND H
30.7 5.29 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,3-Dichlorobenzene ND H
30.7 3.44 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,3-Dichloropropane ND H
30.7 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 11,4-Dichlorobenzene ND H
61.5 6.27 ug/Sample 11/29/19 10:48 12/07/19 01:24 11-Chloro-1,1-difluoroethane ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND H
30.7 8.97 ug/Sample 11/29/19 10:48 12/07/19 01:24 12,2-Dichloropropane ND H
123 19.7 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-Butanone (MEK)ND H
61.5 9.10 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND H
61.5 6.15 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-Chloro-1,1,1-Trifluoroethane ND H
30.7 5.78 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-Chlorotoluene ND H
123 28.3 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-Hexanone ND H
26.8 26.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 12-MTP as HFPO 583 H
30.7 6.39 ug/Sample 11/29/19 10:48 12/07/19 01:24 14-Chlorotoluene ND H
30.7 8.24 ug/Sample 11/29/19 10:48 12/07/19 01:24 14-Isopropyltoluene ND H
123 19.7 ug/Sample 11/29/19 10:48 12/07/19 01:24 14-Methyl-2-pentanone (MIBK)ND H
123 72.5 ug/Sample 11/29/19 10:48 12/07/19 01:24 1AcetoneND H
30.7 5.90 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BenzeneND H
30.7 4.30 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BromobenzeneND H
30.7 6.88 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BromochloromethaneND H
30.7 5.29 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BromodichloromethaneND H
30.7 9.34 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BromoformND H
61.5 35.6 ug/Sample 11/29/19 10:48 12/07/19 01:24 1BromomethaneND H
30.7 7.62 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Carbon disulfide ND H
30.7 4.06 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Carbon tetrachloride ND H
90.1 90.1 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Carbonyl Difluoride ND H
30.7 4.43 ug/Sample 11/29/19 10:48 12/07/19 01:24 1ChlorobenzeneND H
30.7 6.64 ug/Sample 11/29/19 10:48 12/07/19 01:24 1ChlorodibromomethaneND H
61.5 13.5 ug/Sample 11/29/19 10:48 12/07/19 01:24 1ChloroethaneND H
30.7 3.56 ug/Sample 11/29/19 10:48 12/07/19 01:24 1ChloroformND H
61.5 25.6 ug/Sample 11/29/19 10:48 12/07/19 01:24 1ChloromethaneND H
30.7 2.46 ug/Sample 11/29/19 10:48 12/07/19 01:24 1cis-1,2-Dichloroethene ND H
Eurofins TestAmerica, Knoxville
12/23/2019Page 41 of 89492
Client Sample Results
Job ID: 140-17461-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17461-12Client Sample ID: Y-2975 R2 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
cis-1,3-Dichloropropene ND H 30.7 5.29 ug/Sample 11/29/19 10:48 12/07/19 01:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.7 2.95 ug/Sample 11/29/19 10:48 12/07/19 01:24 1DibromomethaneND H
61.5 10.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 1DichlorodifluoromethaneND H
30.7 5.04 ug/Sample 11/29/19 10:48 12/07/19 01:24 1EthylbenzeneND H
30.7 30.7 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND H
30.7 8.11 ug/Sample 11/29/19 10:48 12/07/19 01:24 1HexachlorobutadieneND H
29.4 29.4 ug/Sample 11/29/19 10:48 12/07/19 01:24 1HFPO dimer, methyl ester as
HFPO-DA
ND H
30.7 4.30 ug/Sample 11/29/19 10:48 12/07/19 01:24 1IsopropylbenzeneND H
61.5 5.04 ug/Sample 11/29/19 10:48 12/07/19 01:24 1m,p-Xylene ND H
30.7 19.7 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Methylene Chloride ND H
30.7 14.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 1NaphthaleneND H
30.7 7.87 ug/Sample 11/29/19 10:48 12/07/19 01:24 1n-Butylbenzene ND H
30.7 6.64 ug/Sample 11/29/19 10:48 12/07/19 01:24 1n-Propylbenzene ND H
30.7 3.20 ug/Sample 11/29/19 10:48 12/07/19 01:24 1o-Xylene ND H
30.7 6.02 ug/Sample 11/29/19 10:48 12/07/19 01:24 1sec-Butylbenzene ND H
30.7 6.64 ug/Sample 11/29/19 10:48 12/07/19 01:24 1StyreneND H
30.7 5.41 ug/Sample 11/29/19 10:48 12/07/19 01:24 1tert-Butylbenzene ND H
30.7 4.06 ug/Sample 11/29/19 10:48 12/07/19 01:24 1TetrachloroetheneND H
30.7 5.65 ug/Sample 11/29/19 10:48 12/07/19 01:24 1TolueneND H
30.7 3.20 ug/Sample 11/29/19 10:48 12/07/19 01:24 1trans-1,2-Dichloroethene ND H
30.7 10.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 1trans-1,3-Dichloropropene ND H
30.7 2.21 ug/Sample 11/29/19 10:48 12/07/19 01:24 1TrichloroetheneND H
61.5 5.90 ug/Sample 11/29/19 10:48 12/07/19 01:24 1TrichlorofluoromethaneND H *
61.5 14.8 ug/Sample 11/29/19 10:48 12/07/19 01:24 1Vinyl chloride ND H
Propene, hexafluoro-333 T H J N ug/Sample 1.13 116-15-4 11/29/19 10:48 12/07/19 01:24 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/07/19 01:2411/29/19 10:48T H JUnknown498 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:48 12/07/19 01:24 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:48 12/07/19 01:24 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:48 12/07/19 01:24 162-134
Toluene-d8 (Surr)96 11/29/19 10:48 12/07/19 01:24 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 28100 6560 3280 ug/Sample 11/29/19 10:48 12/13/19 20:47 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2700 1230 ug/Sample 11/29/19 10:48 12/18/19 12:59 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
12/23/2019Page 42 of 89493
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17461-1
Project/Site: VEN Stack - MM-18
Method: 8260B - Volatile Organic Compounds (GC/MS)
Prep: MeOH Prep
2.501,1,1,2-Tetrachloroethane ug/Sample
Analyte UnitsMDLRL
0.330
5.001,1,1,3,3-Pentafluorobutane ug/Sample0.500
2.501,1,1-Trichloroethane ug/Sample0.360
5.001,1,1-Trifluoro-2,2-dichloroethane ug/Sample0.990
5.001,1,1-Trifluoroethane ug/Sample0.500
2.501,1,2,2-Tetrachloroethane ug/Sample0.480
5.001,1,2-Trichloro-1,2,2-trifluoroethane ug/Sample0.280
5.001,1,2-trichloro-1-fluoroethane ug/Sample0.500
2.501,1,2-Trichloroethane ug/Sample0.260
5.001,1-Dichloro-1-fluoroethane ug/Sample2.50
5.001,1-dichloro-2,2-difluoroethane ug/Sample0.500
5.001,1-dichloro-2,2-difluoroethene ug/Sample0.500
2.501,1-Dichloroethane ug/Sample0.300
2.501,1-Dichloroethene ug/Sample0.370
2.501,1-Dichloropropene ug/Sample0.270
50.01,1-Difluoroethene ug/Sample50.0
5.001,2,2-trichloro-1,1-difluoroethane ug/Sample0.500
2.501,2,3-Trichlorobenzene ug/Sample0.800
2.501,2,3-Trichloropropane ug/Sample0.620
2.501,2,4-Trichlorobenzene ug/Sample0.840
2.501,2,4-Trimethylbenzene ug/Sample0.520
5.001,2-Dibromo-3-Chloropropane ug/Sample0.880
2.501,2-Dibromoethane (EDB)ug/Sample0.330
5.001,2-dichloro-1,1-difluoroethane ug/Sample0.500
2.501,2-Dichlorobenzene ug/Sample0.440
2.501,2-Dichloroethane ug/Sample0.420
2.501,2-Dichloropropane ug/Sample0.250
2.501,3,5-Trimethylbenzene ug/Sample0.520
2.501,3-Dichlorobenzene ug/Sample0.430
2.501,3-Dichloropropane ug/Sample0.280
2.501,4-Dichlorobenzene ug/Sample0.500
5.001-Chloro-1,1-difluoroethane ug/Sample0.510
5.002,2-dichloro-1,1-difluoroethylmethyl ether ug/Sample0.500
2.502,2-Dichloropropane ug/Sample0.730
10.02-Butanone (MEK)ug/Sample1.60
5.002-chloro-1,1,1,4,4,4-hexafluoro-2-butene ug/Sample0.740
5.002-Chloro-1,1,1-Trifluoroethane ug/Sample0.500
2.502-Chlorotoluene ug/Sample0.470
10.02-Hexanone ug/Sample2.30
2.502-MTP as HFPO ug/Sample2.50
2.504-Chlorotoluene ug/Sample0.520
2.504-Isopropyltoluene ug/Sample0.670
10.04-Methyl-2-pentanone (MIBK)ug/Sample1.60
10.0Acetone ug/Sample5.90
2.50Benzene ug/Sample0.480
2.50Bromobenzene ug/Sample0.350
2.50Bromochloromethane ug/Sample0.560
2.50Bromodichloromethane ug/Sample0.430
2.50Bromoform ug/Sample0.760
5.00Bromomethane ug/Sample2.90
2.50Carbon disulfide ug/Sample0.620
2.50Carbon tetrachloride ug/Sample0.330
Eurofins TestAmerica, Knoxville
12/23/2019Page 43 of 89494
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17461-1
Project/Site: VEN Stack - MM-18
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Prep: MeOH Prep
10.0Carbonyl Difluoride ug/Sample
Analyte UnitsMDLRL
10.0
2.50Chlorobenzene ug/Sample0.360
2.50Chlorodibromomethane ug/Sample0.540
5.00Chloroethane ug/Sample1.10
2.50Chloroform ug/Sample0.290
5.00Chloromethane ug/Sample2.08
2.50cis-1,2-Dichloroethene ug/Sample0.200
2.50cis-1,3-Dichloropropene ug/Sample0.430
2.50Dibromomethane ug/Sample0.240
5.00Dichlorodifluoromethane ug/Sample0.880
2.50Ethylbenzene ug/Sample0.410
2.50Heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether ug/Sample2.50
2.50Hexachlorobutadiene ug/Sample0.660
2.50HFPO dimer, methyl ester as HFPO-DA ug/Sample2.50
2.50Isopropylbenzene ug/Sample0.350
5.00m,p-Xylene ug/Sample0.410
2.50Methylene Chloride ug/Sample1.60
2.50Naphthalene ug/Sample1.20
2.50n-Butylbenzene ug/Sample0.640
2.50n-Propylbenzene ug/Sample0.540
2.50o-Xylene ug/Sample0.260
2.50sec-Butylbenzene ug/Sample0.490
2.50Styrene ug/Sample0.540
2.50tert-Butylbenzene ug/Sample0.440
2.50Tetrachloroethene ug/Sample0.330
2.50Toluene ug/Sample0.460
2.50trans-1,2-Dichloroethene ug/Sample0.260
2.50trans-1,3-Dichloropropene ug/Sample0.880
2.50Trichloroethene ug/Sample0.180
5.00Trichlorofluoromethane ug/Sample0.480
5.00Vinyl chloride ug/Sample1.20
Method: 9056 - Anions, Ion Chromatography
Prep: MeOH Prep
11.0Hydrogen Fluoride ug/Sample
Analyte UnitsMDLRL
5.00
1000Total Fluorine ug/Sample500
Eurofins TestAmerica, Knoxville
12/23/2019Page 44 of 89495
ANALYTICAL REPORT
Job Number: 140-17557-1
Job Description: VEN Stack - MM-18
Contract Number: LBIO-67048
For:
Chemours Company FC, LLC The
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, DE 19713
Attention: Michael Aucoin
_____________________________________________
Approved for release.
Courtney M Adkins
Project Manager II
12/30/2019 6:39 AM
Courtney M Adkins, Project Manager II
5815 Middlebrook Pike, Knoxville, TN, 37921
[phone]
[e-mail]
12/30/2019
This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at
the e-mail address or telephone number listed on this page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any
exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be
directed to the Eurofins TestAmerica Project Manager.
This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a
traditionally handwritten signature.
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike, Knoxville, TN 37921
Tel [phone] Fax [phone] www.testamericainc.com
12/30/2019Page 1 of 70696
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .28
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .30
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .31
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .38
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .44
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .45
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .55
Method 8260B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .55
Method 8260B QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .56
Method 8260B Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .71
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .188
Method 8260B ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .188
Method 8260B CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .290
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .362
Method 8260B Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .362
Method 8260B Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .382
Method 8260B LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .391
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Table of Contents
Method 8260B MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .403
Method 8260B Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .411
Method 8260B Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .428
HPLC/IC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .431
Method 9056 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .431
Method 9056 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .432
Method 9056 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .437
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .455
Method 9056 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .455
Method 9056 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .482
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .511
Method 9056 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .511
Method 9056 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .532
Method 9056 MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .538
Method 9056 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .544
Method 9056 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .549
Method 9056A Total Halogens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .552
Method 9056A Total Halogens QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .553
Method 9056A Total Halogens Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .558
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .576
Method 9056A Total Halogens ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .576
Method 9056A Total Halogens CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .601
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .629
Method 9056A Total Halogens Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .629
Method 9056A Total Halogens LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .654
Method 9056A Total Halogens MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .660
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Table of Contents
Method 9056A Total Halogens Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .666
Method 9056A Total Halogens Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .680
Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 685
General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .685
Gen Chem Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .686
Gen Chem Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .687
Gen Chem QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .693
Gen Chem ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .693
Gen Chem Duplicates . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .694
Gen Chem MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .695
Gen Chem Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .696
Gen Chem Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .697
Gen Chem Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .698
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 699
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .700
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Definitions/Glossary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Qualifiers
GC/MS VOA
Qualifier Description
*LCS or LCSD is outside acceptance limits.
Qualifier
4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not
applicable.
E Result exceeded calibration range.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
GC/MS VOA TICs
Qualifier Description
J Indicates an Estimated Value for TICs
Qualifier
N Presumptive evidence of material.
T Result is a tentatively identified compound (TIC) and an estimated value.
HPLC/IC
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
General Chemistry
Qualifier Description
HF Field parameter with a holding time of 15 minutes. Test performed by laboratory at client's request.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Knoxville
12/30/2019Page 5 of 706100
Method Summary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL KNX
SW8469056Anions, Ion Chromatography TAL KNX
SW8469041ApH TAL KNX
SW8465050Bomb Preparation Method for Solid Waste TAL KNX
NoneMeOH Prep Methanol Impinger Preparation TAL KNX
Protocol References:
None = None
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
12/30/2019Page 6 of 706101
Sample Summary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Air 12/04/19 00:00 12/07/19 08:00
140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Air 12/04/19 00:00 12/07/19 08:00
140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Air 12/04/19 00:00 12/07/19 08:00
140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Air 12/04/19 00:00 12/07/19 08:00
140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Air 12/04/19 00:00 12/07/19 08:00
140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Air 12/04/19 00:00 12/07/19 08:00
Eurofins TestAmerica, Knoxville
12/30/2019Page 7 of 706102
Job Narrative
140-17557-1
Receipt

The samples were received on December 7, 2019 at 8:00 AM; the samples arrived in good condition, properly preserved and, where
required, on ice. The temperatures of the 2 coolers at receipt time were 0.9º C and 1.4º C.
GC/MS VOA
Impinger Sample Preparation and Analysis: Impinger samples were analyzed for the volatile organic target analytes by purge and trap
GCMS using Eurofins TestAmerica Knoxville standard operating procedure KNOX-MS-0015, based on the following method:
· SW-846 8260B, “Volatile Organic Compounds by Gas Chromatography/ Mass Spectrometry (GC/MS)”
Each sample is prepared by adding a known amount of sample to the purge water in a purge and trap vessel and spiking with internal
standards, surrogates, and matrix spike analytes (as needed). Volatile compounds are introduced into the gas chromatograph by the
purge and trap method. The components are separated using the chromatograph and detected using a mass spectrometer, which
provides both qualitative and quantitative information.
Impinger sample results were calculated using the following equation:
Concentration, μg/sample = (C × DF × W × Vt) / (Va)
Where:
C = On-column concentration, μg/L
DF = Dilution factor
W = Volume of water purged, L
Vt = Methanol extract final volume, μL
Va = Volume of extract analyzed, µL
Method 8260B: (LCS 140-35956/1-A) for analytical batch 140-35964 recovered below marginal exceedance limits for
Trichlorofluoromethane. This is an ongoing instrument issue with LCS recoveries for this analyte. The project manager approved moving
forward with analysis for the current job.
Method 8260B: The following samples were diluted to bring the concentration of target analytes within the calibration range: Y-2976 R3
VEN DIV STACK MM18 IMPINGER #1 (140-17557-1), Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 (140-17557-2), Y-2978 R3 VEN
DIV STACK MM18 IMPINGER #3 (140-17557-3), Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 (140-17557-4), Y-2980 R3 VEN DIV
STACK MM18 IMPINGER #5 (140-17557-5) and Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 (140-17557-6). Elevated reporting
limits (RLs) are provided.
Method 8260B: The continuing calibration verification (CCV) associated with batch 140-35990 recovered above the upper control limit for
Chloroethane. The samples associated with this CCV were non-detects for the affected analytes; therefore, the data have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
General Chemistry
Total Halogens: The samples were prepared for total fluorine, chlorine, bromine and/or iodine using SOP number KNOX-WC-0016
(based on ASTM Method E442 and SW-846 Method 5050). The sample is oxidized by combustion in an oxygen flask at atmospheric
pressure or a bomb containing oxygen under pressure. The liberated halogen compounds are absorbed primarily as halides in a sodium
carbonate/sodium bicarbonate buffer solution. The combustion products are collected by repeated rinsing of the combustion apparatus,
and analyzed by ion chromatography in accordance with SOP KNOX-WC-0005 (based on SW-846 Method 9056). The results are
calculated using the following equation:
C = [(Ccom × Vcom) / W] × 1000 g/Kg
Where:
C = Concentration of analyte in the sample, mg/Kg
Ccom = Concentration of analyte in the combustate, mg/L
Vcom = Total volume of combustate, L
W = Weight of sample combusted, g
Anions in Impinger Solutions: Anions are is determined in accordance to SOP KNOX-WC-0005 (based on methods 300.0A and 9056).
The samples were diluted a minimum of 1/20 in ion chromatography solvent buffer solution to reduce the methanol concentration before
injection. Buffer concentrate was added until the pH was 10. Samples are diluted with ion chromatography eluate solution to bring the
12/30/2019Page 8 of 706103
concentrations within the calibration range when necessary. Higher dilutions are applied as necessary.
An aliquot of prepared sample is introduced into the ion chromatograph. Anions are identified based on their retention times as compared
to those of known standards. Quantification is accomplished by measuring the peak response and comparing it to a calibration curve
generated from known standards.
The pH of all samples were tested with pH paper. QC consisted of initial CCV and LCS which also serve as initial calibration, duplicate
analysis for every 10 samples, and closing CCV. A certified thermometer was used to check the ambient temperature.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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QC Association Summary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
GC/MS VOA
Prep Batch: 35956
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17557-2 - DL Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17557-3 - DL Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17557-4 - DL Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17557-6 - DL Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH Prep140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH PrepMB 140-35956/2-A Method Blank Total/NA
Air MeOH PrepLCS 140-35956/1-A Lab Control Sample Total/NA
Air MeOH Prep140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 35964
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8260B 35956140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 8260B 35956140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35956140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 8260B 35956140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 8260B 35956140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 8260B 35956140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 8260B 35956MB 140-35956/2-A Method Blank Total/NA
Air 8260B 35956LCS 140-35956/1-A Lab Control Sample Total/NA
Air 8260B 35956LCS 140-35956/1-A Lab Control Sample Total/NA
Analysis Batch: 35990
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8260B 35956140-17557-2 - DL Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35956140-17557-3 - DL Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 8260B 35956140-17557-4 - DL Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 8260B 35956140-17557-6 - DL Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 8260B 35956140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 8260B 35956140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
HPLC/IC
Prep Batch: 35956
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air MeOH Prep140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air MeOH Prep140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air MeOH Prep140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air MeOH Prep140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air MeOH PrepMB 140-35956/19-A Method Blank Total/NA
Air MeOH PrepMB 140-35956/19-B Method Blank Total/NA
Air MeOH PrepLCS 140-35956/20-A Lab Control Sample Total/NA
Air MeOH PrepLCS 140-35956/20-B Lab Control Sample Total/NA
Air MeOH PrepLCSD 140-35956/21-A Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
12/30/2019Page 10 of 706105
QC Association Summary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
HPLC/IC (Continued)
Prep Batch: 35956 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH PrepLCSD 140-35956/21-B Lab Control Sample Dup Total/NA
Air MeOH Prep140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air MeOH Prep140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Prep Batch: 35976
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 5050 35956140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 5050 35956140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 5050 35956140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 5050 35956140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 5050 35956140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 5050 35956140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 5050 35956MB 140-35956/19-B Method Blank Total/NA
Air 5050 35956LCS 140-35956/20-B Lab Control Sample Total/NA
Air 5050 35956LCSD 140-35956/21-B Lab Control Sample Dup Total/NA
Air 5050 35956140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 5050 35956140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 36294
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35976140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35976140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35976140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9056 35976140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35976140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35976140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35976MB 140-35956/19-B Method Blank Total/NA
Air 9056 35976LCS 140-35956/20-B Lab Control Sample Total/NA
Air 9056 35976LCSD 140-35956/21-B Lab Control Sample Dup Total/NA
Air 9056 35976140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35976140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Analysis Batch: 36325
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35956140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Air 9056 35956140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35956140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9056 35956140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9056 35956140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9056 35956140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9056 35956MB 140-35956/19-A Method Blank Total/NA
Air 9056 35956LCS 140-35956/20-A Lab Control Sample Total/NA
Air 9056 35956LCSD 140-35956/21-A Lab Control Sample Dup Total/NA
Air 9056 35956140-17557-2 MS Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9056 35956140-17557-2 MSD Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
General Chemistry
Analysis Batch: 36156
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9041A140-17557-1 Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Eurofins TestAmerica, Knoxville
12/30/2019Page 11 of 706106
QC Association Summary
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
General Chemistry (Continued)
Analysis Batch: 36156 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9041A140-17557-2 Y-2977 R3 VEN DIV STACK MM18 IMPINGER #2 Total/NA
Air 9041A140-17557-3 Y-2978 R3 VEN DIV STACK MM18 IMPINGER #3 Total/NA
Air 9041A140-17557-4 Y-2979 R3 VEN DIV STACK MM18 IMPINGER #4 Total/NA
Air 9041A140-17557-5 Y-2980 R3 VEN DIV STACK MM18 IMPINGER #5 Total/NA
Air 9041A140-17557-6 Y-2981 R3 VEN DIV STACK MM18 IMPINGER #6 Total/NA
Air 9041ALCS 140-36156/2 Lab Control Sample Total/NA
Air 9041A140-17557-1 DU Y-2976 R3 VEN DIV STACK MM18 IMPINGER #1 Total/NA
Eurofins TestAmerica, Knoxville
12/30/2019Page 12 of 706107
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-1Client Sample ID: Y-2976 R3 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 31.5 4.15 ug/Sample 12/10/19 09:47 12/10/19 22:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,1,3,3-Pentafluorobutane ND
31.5 4.53 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,1-Trichloroethane ND
62.9 12.5 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,1-Trifluoro-2,2-dichloroethane ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,1-Trifluoroethane ND
31.5 6.04 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,2,2-Tetrachloroethane ND
62.9 3.52 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,2-Trichloro-1,2,2-trifluoroethane ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,2-trichloro-1-fluoroethane ND
31.5 3.27 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1,2-Trichloroethane ND
62.9 31.5 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-Dichloro-1-fluoroethane ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-dichloro-2,2-difluoroethane ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-dichloro-2,2-difluoroethene ND
31.5 3.78 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-Dichloroethane ND
31.5 4.66 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-Dichloroethene ND
31.5 3.40 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-Dichloropropene ND
629 629 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,1-Difluoroethene ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2,2-trichloro-1,1-difluoroethane ND
31.5 10.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2,3-Trichlorobenzene ND
31.5 7.80 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2,3-Trichloropropane ND
31.5 10.6 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2,4-Trichlorobenzene ND
31.5 6.54 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2,4-Trimethylbenzene ND
62.9 11.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-Dibromo-3-Chloropropane ND
31.5 4.15 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-Dibromoethane (EDB)ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-dichloro-1,1-difluoroethane ND
31.5 5.54 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-Dichlorobenzene ND
31.5 5.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-Dichloroethane ND
31.5 3.15 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,2-Dichloropropane ND
31.5 6.54 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,3,5-Trimethylbenzene ND
31.5 5.41 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,3-Dichlorobenzene ND
31.5 3.52 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,3-Dichloropropane ND
31.5 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 11,4-Dichlorobenzene ND
62.9 6.42 ug/Sample 12/10/19 09:47 12/10/19 22:58 11-Chloro-1,1-difluoroethane ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
31.5 9.19 ug/Sample 12/10/19 09:47 12/10/19 22:58 12,2-Dichloropropane ND
126 20.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-Butanone (MEK)ND
62.9 9.31 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
62.9 6.29 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-Chloro-1,1,1-Trifluoroethane ND
31.5 5.92 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-Chlorotoluene ND
126 28.9 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-Hexanone ND
27.5 27.5 ug/Sample 12/10/19 09:47 12/10/19 22:58 12-MTP as HFPO 1460
31.5 6.54 ug/Sample 12/10/19 09:47 12/10/19 22:58 14-Chlorotoluene ND
31.5 8.43 ug/Sample 12/10/19 09:47 12/10/19 22:58 14-Isopropyltoluene ND
126 20.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 14-Methyl-2-pentanone (MIBK)ND
126 74.3 ug/Sample 12/10/19 09:47 12/10/19 22:58 1AcetoneND
31.5 6.04 ug/Sample 12/10/19 09:47 12/10/19 22:58 1BenzeneND
31.5 4.41 ug/Sample 12/10/19 09:47 12/10/19 22:58 1BromobenzeneND
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12/30/2019Page 13 of 706108
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-1Client Sample ID: Y-2976 R3 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromochloromethane ND 31.5 7.05 ug/Sample 12/10/19 09:47 12/10/19 22:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
31.5 5.41 ug/Sample 12/10/19 09:47 12/10/19 22:58 1BromodichloromethaneND
31.5 9.57 ug/Sample 12/10/19 09:47 12/10/19 22:58 1BromoformND
62.9 36.5 ug/Sample 12/10/19 09:47 12/10/19 22:58 1BromomethaneND
31.5 7.80 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Carbon disulfide ND
31.5 4.15 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Carbon tetrachloride ND
92.3 92.3 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Carbonyl Difluoride ND
31.5 4.53 ug/Sample 12/10/19 09:47 12/10/19 22:58 1ChlorobenzeneND
31.5 6.80 ug/Sample 12/10/19 09:47 12/10/19 22:58 1ChlorodibromomethaneND
62.9 13.8 ug/Sample 12/10/19 09:47 12/10/19 22:58 1ChloroethaneND
31.5 3.65 ug/Sample 12/10/19 09:47 12/10/19 22:58 1ChloroformND
62.9 26.2 ug/Sample 12/10/19 09:47 12/10/19 22:58 1ChloromethaneND
31.5 2.52 ug/Sample 12/10/19 09:47 12/10/19 22:58 1cis-1,2-Dichloroethene ND
31.5 5.41 ug/Sample 12/10/19 09:47 12/10/19 22:58 1cis-1,3-Dichloropropene ND
31.5 3.02 ug/Sample 12/10/19 09:47 12/10/19 22:58 1DibromomethaneND
62.9 11.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 1DichlorodifluoromethaneND
31.5 5.16 ug/Sample 12/10/19 09:47 12/10/19 22:58 1EthylbenzeneND
31.5 31.5 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
149
31.5 8.31 ug/Sample 12/10/19 09:47 12/10/19 22:58 1HexachlorobutadieneND
30.2 30.2 ug/Sample 12/10/19 09:47 12/10/19 22:58 1HFPO dimer, methyl ester as
HFPO-DA
ND
31.5 4.41 ug/Sample 12/10/19 09:47 12/10/19 22:58 1IsopropylbenzeneND
62.9 5.16 ug/Sample 12/10/19 09:47 12/10/19 22:58 1m,p-Xylene ND
31.5 20.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Methylene Chloride 37.3
31.5 15.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 1NaphthaleneND
31.5 8.06 ug/Sample 12/10/19 09:47 12/10/19 22:58 1n-Butylbenzene ND
31.5 6.80 ug/Sample 12/10/19 09:47 12/10/19 22:58 1n-Propylbenzene ND
31.5 3.27 ug/Sample 12/10/19 09:47 12/10/19 22:58 1o-Xylene ND
31.5 6.17 ug/Sample 12/10/19 09:47 12/10/19 22:58 1sec-Butylbenzene ND
31.5 6.80 ug/Sample 12/10/19 09:47 12/10/19 22:58 1StyreneND
31.5 5.54 ug/Sample 12/10/19 09:47 12/10/19 22:58 1tert-Butylbenzene ND
31.5 4.15 ug/Sample 12/10/19 09:47 12/10/19 22:58 1TetrachloroetheneND
31.5 5.79 ug/Sample 12/10/19 09:47 12/10/19 22:58 1TolueneND
31.5 3.27 ug/Sample 12/10/19 09:47 12/10/19 22:58 1trans-1,2-Dichloroethene ND
31.5 11.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 1trans-1,3-Dichloropropene ND
31.5 2.27 ug/Sample 12/10/19 09:47 12/10/19 22:58 1TrichloroetheneND
62.9 6.04 ug/Sample 12/10/19 09:47 12/10/19 22:58 1TrichlorofluoromethaneND *
62.9 15.1 ug/Sample 12/10/19 09:47 12/10/19 22:58 1Vinyl chloride ND
Unknown 318 T J ug/Sample 1.13 12/10/19 09:47 12/10/19 22:58 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 22:5812/10/19 09:47T JUnknown626 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)121 70 -160 12/10/19 09:47 12/10/19 22:58 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)106 12/10/19 09:47 12/10/19 22:58 157-152
Dibromofluoromethane (Surr)109 12/10/19 09:47 12/10/19 22:58 162-134
Eurofins TestAmerica, Knoxville
12/30/2019Page 14 of 706109
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-1Client Sample ID: Y-2976 R3 VEN DIV STACK MM18 IMPINGER
#1
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Toluene-d8 (Surr)89 71 -139 12/10/19 09:47 12/10/19 22:58 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 98200 13400 6710 ug/Sample 12/10/19 09:47 12/23/19 12:01 2
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2770 1260 ug/Sample 12/10/19 09:47 12/24/19 01:17 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.0 HF SU 12/17/19 13:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17557-2Client Sample ID: Y-2977 R3 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 30.5 4.02 ug/Sample 12/10/19 09:47 12/10/19 22:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,1,3,3-Pentafluorobutane ND
30.5 4.39 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,1-Trichloroethane ND
61.0 12.1 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,1-Trifluoro-2,2-dichloroethane ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,1-Trifluoroethane ND
30.5 5.85 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,2,2-Tetrachloroethane ND
61.0 3.41 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,2-Trichloro-1,2,2-trifluoroethane ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,2-trichloro-1-fluoroethane ND
30.5 3.17 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1,2-Trichloroethane ND
61.0 30.5 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-Dichloro-1-fluoroethane ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-dichloro-2,2-difluoroethane ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-dichloro-2,2-difluoroethene ND
30.5 3.66 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-Dichloroethane ND
30.5 4.51 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-Dichloroethene ND
30.5 3.29 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-Dichloropropene ND
610 610 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,1-Difluoroethene ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2,2-trichloro-1,1-difluoroethane ND
30.5 9.76 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2,3-Trichlorobenzene ND
30.5 7.56 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2,3-Trichloropropane ND
30.5 10.2 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2,4-Trichlorobenzene ND
30.5 6.34 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2,4-Trimethylbenzene ND
61.0 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-Dibromo-3-Chloropropane ND
30.5 4.02 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-Dibromoethane (EDB)ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-dichloro-1,1-difluoroethane ND
30.5 5.37 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-Dichlorobenzene ND
30.5 5.12 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-Dichloroethane ND
30.5 3.05 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,2-Dichloropropane ND
30.5 6.34 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,3,5-Trimethylbenzene ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 15 of 706110
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-2Client Sample ID: Y-2977 R3 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,3-Dichlorobenzene ND 30.5 5.24 ug/Sample 12/10/19 09:47 12/10/19 22:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.5 3.41 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,3-Dichloropropane ND
30.5 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 11,4-Dichlorobenzene ND
61.0 6.22 ug/Sample 12/10/19 09:47 12/10/19 22:34 11-Chloro-1,1-difluoroethane ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
30.5 8.90 ug/Sample 12/10/19 09:47 12/10/19 22:34 12,2-Dichloropropane ND
122 19.5 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-Butanone (MEK)ND
61.0 9.03 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
61.0 6.10 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-Chloro-1,1,1-Trifluoroethane ND
30.5 5.73 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-Chlorotoluene ND
122 28.1 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-Hexanone ND
26.6 26.6 ug/Sample 12/10/19 09:47 12/10/19 22:34 12-MTP as HFPO 2430 E
30.5 6.34 ug/Sample 12/10/19 09:47 12/10/19 22:34 14-Chlorotoluene ND
30.5 8.17 ug/Sample 12/10/19 09:47 12/10/19 22:34 14-Isopropyltoluene ND
122 19.5 ug/Sample 12/10/19 09:47 12/10/19 22:34 14-Methyl-2-pentanone (MIBK)ND
122 72.0 ug/Sample 12/10/19 09:47 12/10/19 22:34 1AcetoneND
30.5 5.85 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BenzeneND
30.5 4.27 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BromobenzeneND
30.5 6.83 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BromochloromethaneND
30.5 5.24 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BromodichloromethaneND
30.5 9.27 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BromoformND
61.0 35.4 ug/Sample 12/10/19 09:47 12/10/19 22:34 1BromomethaneND
30.5 7.56 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Carbon disulfide ND
30.5 4.02 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Carbon tetrachloride ND
89.4 89.4 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Carbonyl Difluoride ND
30.5 4.39 ug/Sample 12/10/19 09:47 12/10/19 22:34 1ChlorobenzeneND
30.5 6.59 ug/Sample 12/10/19 09:47 12/10/19 22:34 1ChlorodibromomethaneND
61.0 13.4 ug/Sample 12/10/19 09:47 12/10/19 22:34 1ChloroethaneND
30.5 3.54 ug/Sample 12/10/19 09:47 12/10/19 22:34 1ChloroformND
61.0 25.4 ug/Sample 12/10/19 09:47 12/10/19 22:34 1ChloromethaneND
30.5 2.44 ug/Sample 12/10/19 09:47 12/10/19 22:34 1cis-1,2-Dichloroethene ND
30.5 5.24 ug/Sample 12/10/19 09:47 12/10/19 22:34 1cis-1,3-Dichloropropene ND
30.5 2.93 ug/Sample 12/10/19 09:47 12/10/19 22:34 1DibromomethaneND
61.0 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:34 1DichlorodifluoromethaneND
30.5 5.00 ug/Sample 12/10/19 09:47 12/10/19 22:34 1EthylbenzeneND
30.5 30.5 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
95.3
30.5 8.05 ug/Sample 12/10/19 09:47 12/10/19 22:34 1HexachlorobutadieneND
29.3 29.3 ug/Sample 12/10/19 09:47 12/10/19 22:34 1HFPO dimer, methyl ester as
HFPO-DA
ND
30.5 4.27 ug/Sample 12/10/19 09:47 12/10/19 22:34 1IsopropylbenzeneND
61.0 5.00 ug/Sample 12/10/19 09:47 12/10/19 22:34 1m,p-Xylene ND
30.5 19.5 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Methylene Chloride 21.1 J
30.5 14.6 ug/Sample 12/10/19 09:47 12/10/19 22:34 1NaphthaleneND
30.5 7.81 ug/Sample 12/10/19 09:47 12/10/19 22:34 1n-Butylbenzene ND
30.5 6.59 ug/Sample 12/10/19 09:47 12/10/19 22:34 1n-Propylbenzene ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 16 of 706111
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-2Client Sample ID: Y-2977 R3 VEN DIV STACK MM18 IMPINGER
#2
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
o-Xylene ND 30.5 3.17 ug/Sample 12/10/19 09:47 12/10/19 22:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.5 5.98 ug/Sample 12/10/19 09:47 12/10/19 22:34 1sec-Butylbenzene ND
30.5 6.59 ug/Sample 12/10/19 09:47 12/10/19 22:34 1StyreneND
30.5 5.37 ug/Sample 12/10/19 09:47 12/10/19 22:34 1tert-Butylbenzene ND
30.5 4.02 ug/Sample 12/10/19 09:47 12/10/19 22:34 1TetrachloroetheneND
30.5 5.61 ug/Sample 12/10/19 09:47 12/10/19 22:34 1TolueneND
30.5 3.17 ug/Sample 12/10/19 09:47 12/10/19 22:34 1trans-1,2-Dichloroethene ND
30.5 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:34 1trans-1,3-Dichloropropene ND
30.5 2.20 ug/Sample 12/10/19 09:47 12/10/19 22:34 1TrichloroetheneND
61.0 5.85 ug/Sample 12/10/19 09:47 12/10/19 22:34 1TrichlorofluoromethaneND *
61.0 14.6 ug/Sample 12/10/19 09:47 12/10/19 22:34 1Vinyl chloride ND
Unknown 596 T J ug/Sample 1.13 12/10/19 09:47 12/10/19 22:34 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 22:3412/10/19 09:47T JUnknown1110 ug/Sample 1.18
112/10/19 22:3412/10/19 09:47T JUnknown35.1 ug/Sample 1.22
1,2-Dichloroethane-d4 (Surr)121 70 -160 12/10/19 09:47 12/10/19 22:34 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)107 12/10/19 09:47 12/10/19 22:34 157-152
Dibromofluoromethane (Surr)106 12/10/19 09:47 12/10/19 22:34 162-134
Toluene-d8 (Surr)89 12/10/19 09:47 12/10/19 22:34 171-139
Method: 8260B - Volatile Organic Compounds (GC/MS) - DL
RL MDL
2-MTP as HFPO 2230 53.3 53.3 ug/Sample 12/10/19 09:47 12/11/19 16:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1,2-Dichloroethane-d4 (Surr)112 70 -160 12/10/19 09:47 12/11/19 16:29 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)108 12/10/19 09:47 12/11/19 16:29 157-152
Dibromofluoromethane (Surr)97 12/10/19 09:47 12/11/19 16:29 162-134
Toluene-d8 (Surr)96 12/10/19 09:47 12/11/19 16:29 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 32600 6500 3250 ug/Sample 12/10/19 09:47 12/19/19 23:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2680 1220 ug/Sample 12/10/19 09:47 12/24/19 01:40 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 4.0 HF SU 12/17/19 13:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
12/30/2019Page 17 of 706112
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-3Client Sample ID: Y-2978 R3 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 30.4 4.01 ug/Sample 12/10/19 09:47 12/10/19 22:09 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,1,3,3-Pentafluorobutane ND
30.4 4.38 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,1-Trichloroethane ND
60.8 12.0 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,1-Trifluoro-2,2-dichloroethane ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,1-Trifluoroethane ND
30.4 5.83 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,2,2-Tetrachloroethane ND
60.8 3.40 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,2-Trichloro-1,2,2-trifluoroethane ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,2-trichloro-1-fluoroethane ND
30.4 3.16 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1,2-Trichloroethane ND
60.8 30.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-Dichloro-1-fluoroethane ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-dichloro-2,2-difluoroethane ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-dichloro-2,2-difluoroethene ND
30.4 3.65 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-Dichloroethane ND
30.4 4.50 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-Dichloroethene ND
30.4 3.28 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-Dichloropropene ND
608 608 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,1-Difluoroethene ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2,2-trichloro-1,1-difluoroethane ND
30.4 9.72 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2,3-Trichlorobenzene ND
30.4 7.53 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2,3-Trichloropropane ND
30.4 10.2 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2,4-Trichlorobenzene ND
30.4 6.32 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2,4-Trimethylbenzene ND
60.8 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-Dibromo-3-Chloropropane ND
30.4 4.01 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-Dibromoethane (EDB)ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-dichloro-1,1-difluoroethane ND
30.4 5.35 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-Dichlorobenzene ND
30.4 5.10 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-Dichloroethane ND
30.4 3.04 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,2-Dichloropropane ND
30.4 6.32 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,3,5-Trimethylbenzene ND
30.4 5.23 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,3-Dichlorobenzene ND
30.4 3.40 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,3-Dichloropropane ND
30.4 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 11,4-Dichlorobenzene ND
60.8 6.20 ug/Sample 12/10/19 09:47 12/10/19 22:09 11-Chloro-1,1-difluoroethane ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
30.4 8.87 ug/Sample 12/10/19 09:47 12/10/19 22:09 12,2-Dichloropropane ND
122 19.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-Butanone (MEK)ND
60.8 8.99 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
60.8 6.08 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-Chloro-1,1,1-Trifluoroethane ND
30.4 5.71 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-Chlorotoluene ND
122 28.0 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-Hexanone ND
26.6 26.6 ug/Sample 12/10/19 09:47 12/10/19 22:09 12-MTP as HFPO 2130 E
30.4 6.32 ug/Sample 12/10/19 09:47 12/10/19 22:09 14-Chlorotoluene ND
30.4 8.14 ug/Sample 12/10/19 09:47 12/10/19 22:09 14-Isopropyltoluene ND
122 19.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 14-Methyl-2-pentanone (MIBK)ND
122 71.7 ug/Sample 12/10/19 09:47 12/10/19 22:09 1AcetoneND
30.4 5.83 ug/Sample 12/10/19 09:47 12/10/19 22:09 1BenzeneND
30.4 4.25 ug/Sample 12/10/19 09:47 12/10/19 22:09 1BromobenzeneND
Eurofins TestAmerica, Knoxville
12/30/2019Page 18 of 706113
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-3Client Sample ID: Y-2978 R3 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromochloromethane ND 30.4 6.81 ug/Sample 12/10/19 09:47 12/10/19 22:09 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.4 5.23 ug/Sample 12/10/19 09:47 12/10/19 22:09 1BromodichloromethaneND
30.4 9.24 ug/Sample 12/10/19 09:47 12/10/19 22:09 1BromoformND
60.8 35.2 ug/Sample 12/10/19 09:47 12/10/19 22:09 1BromomethaneND
30.4 7.53 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Carbon disulfide ND
30.4 4.01 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Carbon tetrachloride ND
89.4 89.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Carbonyl Difluoride ND
30.4 4.38 ug/Sample 12/10/19 09:47 12/10/19 22:09 1ChlorobenzeneND
30.4 6.56 ug/Sample 12/10/19 09:47 12/10/19 22:09 1ChlorodibromomethaneND
60.8 13.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 1ChloroethaneND
30.4 3.52 ug/Sample 12/10/19 09:47 12/10/19 22:09 1ChloroformND
60.8 25.3 ug/Sample 12/10/19 09:47 12/10/19 22:09 1ChloromethaneND
30.4 2.43 ug/Sample 12/10/19 09:47 12/10/19 22:09 1cis-1,2-Dichloroethene ND
30.4 5.23 ug/Sample 12/10/19 09:47 12/10/19 22:09 1cis-1,3-Dichloropropene ND
30.4 2.92 ug/Sample 12/10/19 09:47 12/10/19 22:09 1DibromomethaneND
60.8 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:09 1DichlorodifluoromethaneND
30.4 4.98 ug/Sample 12/10/19 09:47 12/10/19 22:09 1EthylbenzeneND
30.4 30.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
33.4
30.4 8.02 ug/Sample 12/10/19 09:47 12/10/19 22:09 1HexachlorobutadieneND
29.2 29.2 ug/Sample 12/10/19 09:47 12/10/19 22:09 1HFPO dimer, methyl ester as
HFPO-DA
ND
30.4 4.25 ug/Sample 12/10/19 09:47 12/10/19 22:09 1IsopropylbenzeneND
60.8 4.98 ug/Sample 12/10/19 09:47 12/10/19 22:09 1m,p-Xylene ND
30.4 19.4 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Methylene Chloride 20.2 J
30.4 14.6 ug/Sample 12/10/19 09:47 12/10/19 22:09 1NaphthaleneND
30.4 7.78 ug/Sample 12/10/19 09:47 12/10/19 22:09 1n-Butylbenzene ND
30.4 6.56 ug/Sample 12/10/19 09:47 12/10/19 22:09 1n-Propylbenzene ND
30.4 3.16 ug/Sample 12/10/19 09:47 12/10/19 22:09 1o-Xylene ND
30.4 5.95 ug/Sample 12/10/19 09:47 12/10/19 22:09 1sec-Butylbenzene ND
30.4 6.56 ug/Sample 12/10/19 09:47 12/10/19 22:09 1StyreneND
30.4 5.35 ug/Sample 12/10/19 09:47 12/10/19 22:09 1tert-Butylbenzene ND
30.4 4.01 ug/Sample 12/10/19 09:47 12/10/19 22:09 1TetrachloroetheneND
30.4 5.59 ug/Sample 12/10/19 09:47 12/10/19 22:09 1TolueneND
30.4 3.16 ug/Sample 12/10/19 09:47 12/10/19 22:09 1trans-1,2-Dichloroethene ND
30.4 10.7 ug/Sample 12/10/19 09:47 12/10/19 22:09 1trans-1,3-Dichloropropene ND
30.4 2.19 ug/Sample 12/10/19 09:47 12/10/19 22:09 1TrichloroetheneND
60.8 5.83 ug/Sample 12/10/19 09:47 12/10/19 22:09 1TrichlorofluoromethaneND *
60.8 14.6 ug/Sample 12/10/19 09:47 12/10/19 22:09 1Vinyl chloride ND
Unknown 411 T J ug/Sample 1.13 12/10/19 09:47 12/10/19 22:09 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 22:0912/10/19 09:47T JUnknown747 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)114 70 -160 12/10/19 09:47 12/10/19 22:09 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)107 12/10/19 09:47 12/10/19 22:09 157-152
Dibromofluoromethane (Surr)103 12/10/19 09:47 12/10/19 22:09 162-134
Eurofins TestAmerica, Knoxville
12/30/2019Page 19 of 706114
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-3Client Sample ID: Y-2978 R3 VEN DIV STACK MM18 IMPINGER
#3
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Toluene-d8 (Surr)92 71 -139 12/10/19 09:47 12/10/19 22:09 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
Method: 8260B - Volatile Organic Compounds (GC/MS) - DL
RL MDL
2-MTP as HFPO 1970 53.1 53.1 ug/Sample 12/10/19 09:47 12/11/19 16:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1,2-Dichloroethane-d4 (Surr)110 70 -160 12/10/19 09:47 12/11/19 16:53 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)108 12/10/19 09:47 12/11/19 16:53 157-152
Dibromofluoromethane (Surr)98 12/10/19 09:47 12/11/19 16:53 162-134
Toluene-d8 (Surr)95 12/10/19 09:47 12/11/19 16:53 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 13600 6480 3240 ug/Sample 12/10/19 09:47 12/20/19 00:30 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2670 1220 ug/Sample 12/10/19 09:47 12/24/19 02:48 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 5.0 HF SU 12/17/19 13:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17557-4Client Sample ID: Y-2979 R3 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 29.7 3.93 ug/Sample 12/10/19 09:47 12/10/19 21:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,1,3,3-Pentafluorobutane ND
29.7 4.28 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,1-Trichloroethane ND
59.5 11.8 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,1-Trifluoro-2,2-dichloroethane ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,1-Trifluoroethane ND
29.7 5.71 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,2,2-Tetrachloroethane ND
59.5 3.33 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,2-Trichloro-1,2,2-trifluoroethane ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,2-trichloro-1-fluoroethane ND
29.7 3.09 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1,2-Trichloroethane ND
59.5 29.7 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-Dichloro-1-fluoroethane ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-dichloro-2,2-difluoroethane ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-dichloro-2,2-difluoroethene ND
29.7 3.57 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-Dichloroethane ND
29.7 4.40 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-Dichloroethene ND
29.7 3.21 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-Dichloropropene ND
595 595 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,1-Difluoroethene ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2,2-trichloro-1,1-difluoroethane ND
29.7 9.52 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2,3-Trichlorobenzene ND
29.7 7.38 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2,3-Trichloropropane ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 20 of 706115
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-4Client Sample ID: Y-2979 R3 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2,4-Trichlorobenzene ND 29.7 10.0 ug/Sample 12/10/19 09:47 12/10/19 21:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.7 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2,4-Trimethylbenzene ND
59.5 10.5 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-Dibromo-3-Chloropropane ND
29.7 3.93 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-Dibromoethane (EDB)ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-dichloro-1,1-difluoroethane ND
29.7 5.24 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-Dichlorobenzene ND
29.7 5.00 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-Dichloroethane ND
29.7 2.97 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,2-Dichloropropane ND
29.7 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,3,5-Trimethylbenzene ND
29.7 5.12 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,3-Dichlorobenzene ND
29.7 3.33 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,3-Dichloropropane ND
29.7 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 11,4-Dichlorobenzene ND
59.5 6.07 ug/Sample 12/10/19 09:47 12/10/19 21:45 11-Chloro-1,1-difluoroethane ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
29.7 8.69 ug/Sample 12/10/19 09:47 12/10/19 21:45 12,2-Dichloropropane ND
119 19.0 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-Butanone (MEK)ND
59.5 8.81 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
59.5 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-Chloro-1,1,1-Trifluoroethane ND
29.7 5.59 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-Chlorotoluene ND
119 27.4 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-Hexanone ND
25.9 25.9 ug/Sample 12/10/19 09:47 12/10/19 21:45 12-MTP as HFPO 2560 E
29.7 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:45 14-Chlorotoluene ND
29.7 7.97 ug/Sample 12/10/19 09:47 12/10/19 21:45 14-Isopropyltoluene ND
119 19.0 ug/Sample 12/10/19 09:47 12/10/19 21:45 14-Methyl-2-pentanone (MIBK)ND
119 70.2 ug/Sample 12/10/19 09:47 12/10/19 21:45 1AcetoneND
29.7 5.71 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BenzeneND
29.7 4.16 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BromobenzeneND
29.7 6.66 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BromochloromethaneND
29.7 5.12 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BromodichloromethaneND
29.7 9.04 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BromoformND
59.5 34.5 ug/Sample 12/10/19 09:47 12/10/19 21:45 1BromomethaneND
29.7 7.38 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Carbon disulfide ND
29.7 3.93 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Carbon tetrachloride ND
87.2 87.2 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Carbonyl Difluoride ND
29.7 4.28 ug/Sample 12/10/19 09:47 12/10/19 21:45 1ChlorobenzeneND
29.7 6.43 ug/Sample 12/10/19 09:47 12/10/19 21:45 1ChlorodibromomethaneND
59.5 13.1 ug/Sample 12/10/19 09:47 12/10/19 21:45 1ChloroethaneND
29.7 3.45 ug/Sample 12/10/19 09:47 12/10/19 21:45 1ChloroformND
59.5 24.7 ug/Sample 12/10/19 09:47 12/10/19 21:45 1ChloromethaneND
29.7 2.38 ug/Sample 12/10/19 09:47 12/10/19 21:45 1cis-1,2-Dichloroethene ND
29.7 5.12 ug/Sample 12/10/19 09:47 12/10/19 21:45 1cis-1,3-Dichloropropene ND
29.7 2.86 ug/Sample 12/10/19 09:47 12/10/19 21:45 1DibromomethaneND
59.5 10.5 ug/Sample 12/10/19 09:47 12/10/19 21:45 1DichlorodifluoromethaneND
29.7 4.88 ug/Sample 12/10/19 09:47 12/10/19 21:45 1EthylbenzeneND
29.7 29.7 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 21 of 706116
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-4Client Sample ID: Y-2979 R3 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Hexachlorobutadiene ND 29.7 7.85 ug/Sample 12/10/19 09:47 12/10/19 21:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
28.5 28.5 ug/Sample 12/10/19 09:47 12/10/19 21:45 1HFPO dimer, methyl ester as
HFPO-DA
ND
29.7 4.16 ug/Sample 12/10/19 09:47 12/10/19 21:45 1IsopropylbenzeneND
59.5 4.88 ug/Sample 12/10/19 09:47 12/10/19 21:45 1m,p-Xylene ND
29.7 19.0 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Methylene Chloride 20.0 J
29.7 14.3 ug/Sample 12/10/19 09:47 12/10/19 21:45 1NaphthaleneND
29.7 7.62 ug/Sample 12/10/19 09:47 12/10/19 21:45 1n-Butylbenzene ND
29.7 6.43 ug/Sample 12/10/19 09:47 12/10/19 21:45 1n-Propylbenzene ND
29.7 3.09 ug/Sample 12/10/19 09:47 12/10/19 21:45 1o-Xylene ND
29.7 5.83 ug/Sample 12/10/19 09:47 12/10/19 21:45 1sec-Butylbenzene ND
29.7 6.43 ug/Sample 12/10/19 09:47 12/10/19 21:45 1StyreneND
29.7 5.24 ug/Sample 12/10/19 09:47 12/10/19 21:45 1tert-Butylbenzene ND
29.7 3.93 ug/Sample 12/10/19 09:47 12/10/19 21:45 1TetrachloroetheneND
29.7 5.47 ug/Sample 12/10/19 09:47 12/10/19 21:45 1TolueneND
29.7 3.09 ug/Sample 12/10/19 09:47 12/10/19 21:45 1trans-1,2-Dichloroethene ND
29.7 10.5 ug/Sample 12/10/19 09:47 12/10/19 21:45 1trans-1,3-Dichloropropene ND
29.7 2.14 ug/Sample 12/10/19 09:47 12/10/19 21:45 1TrichloroetheneND
59.5 5.71 ug/Sample 12/10/19 09:47 12/10/19 21:45 1TrichlorofluoromethaneND *
59.5 14.3 ug/Sample 12/10/19 09:47 12/10/19 21:45 1Vinyl chloride ND
Butanoic acid, heptafluoro-, sodium
salt
545 T J N ug/Sample 1.13 2218-54-4 12/10/19 09:47 12/10/19 21:45 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 21:4512/10/19 09:47T J NPropane, 1,1,1,2,2,3,3-heptafluoro-3-
[(trifluoroethenyl)oxy]
1623-05-8761ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)118 70 -160 12/10/19 09:47 12/10/19 21:45 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 12/10/19 09:47 12/10/19 21:45 157-152
Dibromofluoromethane (Surr)107 12/10/19 09:47 12/10/19 21:45 162-134
Toluene-d8 (Surr)91 12/10/19 09:47 12/10/19 21:45 171-139
Method: 8260B - Volatile Organic Compounds (GC/MS) - DL
RL MDL
2-MTP as HFPO 2330 65.0 65.0 ug/Sample 12/10/19 09:47 12/11/19 17:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1,2-Dichloroethane-d4 (Surr)112 70 -160 12/10/19 09:47 12/11/19 17:18 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)107 12/10/19 09:47 12/11/19 17:18 157-152
Dibromofluoromethane (Surr)98 12/10/19 09:47 12/11/19 17:18 162-134
Toluene-d8 (Surr)95 12/10/19 09:47 12/11/19 17:18 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 5730 J 6350 3170 ug/Sample 12/10/19 09:47 12/20/19 00:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2620 1190 ug/Sample 12/10/19 09:47 12/24/19 03:56 20Hydrogen Fluoride ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 22 of 706117
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-4Client Sample ID: Y-2979 R3 VEN DIV STACK MM18 IMPINGER
#4
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
General Chemistry
RL MDL
pH 5.0 HF SU 12/17/19 13:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17557-5Client Sample ID: Y-2980 R3 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 31.0 4.09 ug/Sample 12/10/19 09:47 12/10/19 21:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,1,3,3-Pentafluorobutane ND
31.0 4.46 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,1-Trichloroethane ND
61.9 12.3 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,1-Trifluoro-2,2-dichloroethane ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,1-Trifluoroethane ND
31.0 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,2,2-Tetrachloroethane ND
61.9 3.47 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,2-Trichloro-1,2,2-trifluoroethane ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,2-trichloro-1-fluoroethane ND
31.0 3.22 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1,2-Trichloroethane ND
61.9 31.0 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-Dichloro-1-fluoroethane ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-dichloro-2,2-difluoroethane ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-dichloro-2,2-difluoroethene ND
31.0 3.72 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-Dichloroethane ND
31.0 4.58 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-Dichloroethene ND
31.0 3.34 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-Dichloropropene ND
619 619 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,1-Difluoroethene ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2,2-trichloro-1,1-difluoroethane ND
31.0 9.91 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2,3-Trichlorobenzene ND
31.0 7.68 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2,3-Trichloropropane ND
31.0 10.4 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2,4-Trichlorobenzene ND
31.0 6.44 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2,4-Trimethylbenzene ND
61.9 10.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-Dibromo-3-Chloropropane ND
31.0 4.09 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-Dibromoethane (EDB)ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-dichloro-1,1-difluoroethane ND
31.0 5.45 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-Dichlorobenzene ND
31.0 5.20 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-Dichloroethane ND
31.0 3.10 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,2-Dichloropropane ND
31.0 6.44 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,3,5-Trimethylbenzene ND
31.0 5.33 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,3-Dichlorobenzene ND
31.0 3.47 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,3-Dichloropropane ND
31.0 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 11,4-Dichlorobenzene ND
61.9 6.32 ug/Sample 12/10/19 09:47 12/10/19 21:20 11-Chloro-1,1-difluoroethane ND
61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
31.0 9.04 ug/Sample 12/10/19 09:47 12/10/19 21:20 12,2-Dichloropropane ND
124 19.8 ug/Sample 12/10/19 09:47 12/10/19 21:20 12-Butanone (MEK)ND
61.9 9.17 ug/Sample 12/10/19 09:47 12/10/19 21:20 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 23 of 706118
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-5Client Sample ID: Y-2980 R3 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
2-Chloro-1,1,1-Trifluoroethane ND 61.9 6.19 ug/Sample 12/10/19 09:47 12/10/19 21:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
31.0 5.82 ug/Sample 12/10/19 09:47 12/10/19 21:20 12-Chlorotoluene ND
124 28.5 ug/Sample 12/10/19 09:47 12/10/19 21:20 12-Hexanone ND
27.1 27.1 ug/Sample 12/10/19 09:47 12/10/19 21:20 12-MTP as HFPO 2070
31.0 6.44 ug/Sample 12/10/19 09:47 12/10/19 21:20 14-Chlorotoluene ND
31.0 8.30 ug/Sample 12/10/19 09:47 12/10/19 21:20 14-Isopropyltoluene ND
124 19.8 ug/Sample 12/10/19 09:47 12/10/19 21:20 14-Methyl-2-pentanone (MIBK)ND
124 73.1 ug/Sample 12/10/19 09:47 12/10/19 21:20 1AcetoneND
31.0 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BenzeneND
31.0 4.34 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BromobenzeneND
31.0 6.94 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BromochloromethaneND
31.0 5.33 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BromodichloromethaneND
31.0 9.41 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BromoformND
61.9 35.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1BromomethaneND
31.0 7.68 ug/Sample 12/10/19 09:47 12/10/19 21:20 1Carbon disulfide ND
31.0 4.09 ug/Sample 12/10/19 09:47 12/10/19 21:20 1Carbon tetrachloride ND
90.9 90.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1Carbonyl Difluoride ND
31.0 4.46 ug/Sample 12/10/19 09:47 12/10/19 21:20 1ChlorobenzeneND
31.0 6.69 ug/Sample 12/10/19 09:47 12/10/19 21:20 1ChlorodibromomethaneND
61.9 13.6 ug/Sample 12/10/19 09:47 12/10/19 21:20 1ChloroethaneND
31.0 3.59 ug/Sample 12/10/19 09:47 12/10/19 21:20 1ChloroformND
61.9 25.8 ug/Sample 12/10/19 09:47 12/10/19 21:20 1ChloromethaneND
31.0 2.48 ug/Sample 12/10/19 09:47 12/10/19 21:20 1cis-1,2-Dichloroethene ND
31.0 5.33 ug/Sample 12/10/19 09:47 12/10/19 21:20 1cis-1,3-Dichloropropene ND
31.0 2.97 ug/Sample 12/10/19 09:47 12/10/19 21:20 1DibromomethaneND
61.9 10.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1DichlorodifluoromethaneND
31.0 5.08 ug/Sample 12/10/19 09:47 12/10/19 21:20 1EthylbenzeneND
31.0 31.0 ug/Sample 12/10/19 09:47 12/10/19 21:20 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
31.0 8.18 ug/Sample 12/10/19 09:47 12/10/19 21:20 1HexachlorobutadieneND
29.7 29.7 ug/Sample 12/10/19 09:47 12/10/19 21:20 1HFPO dimer, methyl ester as
HFPO-DA
ND
31.0 4.34 ug/Sample 12/10/19 09:47 12/10/19 21:20 1IsopropylbenzeneND
61.9 5.08 ug/Sample 12/10/19 09:47 12/10/19 21:20 1m,p-Xylene ND
31.0 19.8 ug/Sample 12/10/19 09:47 12/10/19 21:20 1Methylene Chloride ND
31.0 14.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1NaphthaleneND
31.0 7.93 ug/Sample 12/10/19 09:47 12/10/19 21:20 1n-Butylbenzene ND
31.0 6.69 ug/Sample 12/10/19 09:47 12/10/19 21:20 1n-Propylbenzene ND
31.0 3.22 ug/Sample 12/10/19 09:47 12/10/19 21:20 1o-Xylene ND
31.0 6.07 ug/Sample 12/10/19 09:47 12/10/19 21:20 1sec-Butylbenzene ND
31.0 6.69 ug/Sample 12/10/19 09:47 12/10/19 21:20 1StyreneND
31.0 5.45 ug/Sample 12/10/19 09:47 12/10/19 21:20 1tert-Butylbenzene ND
31.0 4.09 ug/Sample 12/10/19 09:47 12/10/19 21:20 1TetrachloroetheneND
31.0 5.70 ug/Sample 12/10/19 09:47 12/10/19 21:20 1TolueneND
31.0 3.22 ug/Sample 12/10/19 09:47 12/10/19 21:20 1trans-1,2-Dichloroethene ND
31.0 10.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1trans-1,3-Dichloropropene ND
31.0 2.23 ug/Sample 12/10/19 09:47 12/10/19 21:20 1TrichloroetheneND
61.9 5.95 ug/Sample 12/10/19 09:47 12/10/19 21:20 1TrichlorofluoromethaneND *
Eurofins TestAmerica, Knoxville
12/30/2019Page 24 of 706119
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-5Client Sample ID: Y-2980 R3 VEN DIV STACK MM18 IMPINGER
#5
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Vinyl chloride ND 61.9 14.9 ug/Sample 12/10/19 09:47 12/10/19 21:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Propene, hexafluoro-445 T J N ug/Sample 1.13 116-15-4 12/10/19 09:47 12/10/19 21:20 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 21:2012/10/19 09:47T JUnknown454 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)117 70 -160 12/10/19 09:47 12/10/19 21:20 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)108 12/10/19 09:47 12/10/19 21:20 157-152
Dibromofluoromethane (Surr)105 12/10/19 09:47 12/10/19 21:20 162-134
Toluene-d8 (Surr)91 12/10/19 09:47 12/10/19 21:20 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 5710 J 6610 3300 ug/Sample 12/10/19 09:47 12/20/19 01:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2730 1240 ug/Sample 12/10/19 09:47 12/24/19 04:19 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 5.0 HF SU 12/17/19 13:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17557-6Client Sample ID: Y-2981 R3 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 30.1 3.97 ug/Sample 12/10/19 09:47 12/10/19 20:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,1,3,3-Pentafluorobutane ND
30.1 4.33 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,1-Trichloroethane ND
60.1 11.9 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,1-Trifluoro-2,2-dichloroethane ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,1-Trifluoroethane ND
30.1 5.77 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,2,2-Tetrachloroethane ND
60.1 3.37 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,2-Trichloro-1,2,2-trifluoroethane ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,2-trichloro-1-fluoroethane ND
30.1 3.13 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1,2-Trichloroethane ND
60.1 30.1 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-Dichloro-1-fluoroethane ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-dichloro-2,2-difluoroethane ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-dichloro-2,2-difluoroethene ND
30.1 3.61 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-Dichloroethane ND
30.1 4.45 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-Dichloroethene ND
30.1 3.25 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-Dichloropropene ND
601 601 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,1-Difluoroethene ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2,2-trichloro-1,1-difluoroethane ND
30.1 9.62 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2,3-Trichlorobenzene ND
30.1 7.45 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2,3-Trichloropropane ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 25 of 706120
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-6Client Sample ID: Y-2981 R3 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2,4-Trichlorobenzene ND 30.1 10.1 ug/Sample 12/10/19 09:47 12/10/19 20:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.1 6.25 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2,4-Trimethylbenzene ND
60.1 10.6 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-Dibromo-3-Chloropropane ND
30.1 3.97 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-Dibromoethane (EDB)ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-dichloro-1,1-difluoroethane ND
30.1 5.29 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-Dichlorobenzene ND
30.1 5.05 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-Dichloroethane ND
30.1 3.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,2-Dichloropropane ND
30.1 6.25 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,3,5-Trimethylbenzene ND
30.1 5.17 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,3-Dichlorobenzene ND
30.1 3.37 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,3-Dichloropropane ND
30.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 11,4-Dichlorobenzene ND
60.1 6.13 ug/Sample 12/10/19 09:47 12/10/19 20:56 11-Chloro-1,1-difluoroethane ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
30.1 8.78 ug/Sample 12/10/19 09:47 12/10/19 20:56 12,2-Dichloropropane ND
120 19.2 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-Butanone (MEK)ND
60.1 8.90 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
60.1 6.01 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-Chloro-1,1,1-Trifluoroethane ND
30.1 5.65 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-Chlorotoluene ND
120 27.7 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-Hexanone ND
26.3 26.3 ug/Sample 12/10/19 09:47 12/10/19 20:56 12-MTP as HFPO 2550 E
30.1 6.25 ug/Sample 12/10/19 09:47 12/10/19 20:56 14-Chlorotoluene ND
30.1 8.06 ug/Sample 12/10/19 09:47 12/10/19 20:56 14-Isopropyltoluene ND
120 19.2 ug/Sample 12/10/19 09:47 12/10/19 20:56 14-Methyl-2-pentanone (MIBK)ND
120 70.9 ug/Sample 12/10/19 09:47 12/10/19 20:56 1AcetoneND
30.1 5.77 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BenzeneND
30.1 4.21 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BromobenzeneND
30.1 6.73 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BromochloromethaneND
30.1 5.17 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BromodichloromethaneND
30.1 9.14 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BromoformND
60.1 34.9 ug/Sample 12/10/19 09:47 12/10/19 20:56 1BromomethaneND
30.1 7.45 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Carbon disulfide ND
30.1 3.97 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Carbon tetrachloride ND
87.9 87.9 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Carbonyl Difluoride ND
30.1 4.33 ug/Sample 12/10/19 09:47 12/10/19 20:56 1ChlorobenzeneND
30.1 6.49 ug/Sample 12/10/19 09:47 12/10/19 20:56 1ChlorodibromomethaneND
60.1 13.2 ug/Sample 12/10/19 09:47 12/10/19 20:56 1ChloroethaneND
30.1 3.49 ug/Sample 12/10/19 09:47 12/10/19 20:56 1ChloroformND
60.1 25.0 ug/Sample 12/10/19 09:47 12/10/19 20:56 1ChloromethaneND
30.1 2.40 ug/Sample 12/10/19 09:47 12/10/19 20:56 1cis-1,2-Dichloroethene ND
30.1 5.17 ug/Sample 12/10/19 09:47 12/10/19 20:56 1cis-1,3-Dichloropropene ND
30.1 2.89 ug/Sample 12/10/19 09:47 12/10/19 20:56 1DibromomethaneND
60.1 10.6 ug/Sample 12/10/19 09:47 12/10/19 20:56 1DichlorodifluoromethaneND
30.1 4.93 ug/Sample 12/10/19 09:47 12/10/19 20:56 1EthylbenzeneND
30.1 30.1 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
Eurofins TestAmerica, Knoxville
12/30/2019Page 26 of 706121
Client Sample Results
Job ID: 140-17557-1Client: Chemours Company FC, LLC The
Project/Site: VEN Stack - MM-18
Lab Sample ID: 140-17557-6Client Sample ID: Y-2981 R3 VEN DIV STACK MM18 IMPINGER
#6
Matrix: AirDate Collected: 12/04/19 00:00
Date Received: 12/07/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Hexachlorobutadiene ND 30.1 7.94 ug/Sample 12/10/19 09:47 12/10/19 20:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
28.9 28.9 ug/Sample 12/10/19 09:47 12/10/19 20:56 1HFPO dimer, methyl ester as
HFPO-DA
ND
30.1 4.21 ug/Sample 12/10/19 09:47 12/10/19 20:56 1IsopropylbenzeneND
60.1 4.93 ug/Sample 12/10/19 09:47 12/10/19 20:56 1m,p-Xylene ND
30.1 19.2 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Methylene Chloride ND
30.1 14.4 ug/Sample 12/10/19 09:47 12/10/19 20:56 1NaphthaleneND
30.1 7.70 ug/Sample 12/10/19 09:47 12/10/19 20:56 1n-Butylbenzene ND
30.1 6.49 ug/Sample 12/10/19 09:47 12/10/19 20:56 1n-Propylbenzene ND
30.1 3.13 ug/Sample 12/10/19 09:47 12/10/19 20:56 1o-Xylene ND
30.1 5.89 ug/Sample 12/10/19 09:47 12/10/19 20:56 1sec-Butylbenzene ND
30.1 6.49 ug/Sample 12/10/19 09:47 12/10/19 20:56 1StyreneND
30.1 5.29 ug/Sample 12/10/19 09:47 12/10/19 20:56 1tert-Butylbenzene ND
30.1 3.97 ug/Sample 12/10/19 09:47 12/10/19 20:56 1TetrachloroetheneND
30.1 5.53 ug/Sample 12/10/19 09:47 12/10/19 20:56 1TolueneND
30.1 3.13 ug/Sample 12/10/19 09:47 12/10/19 20:56 1trans-1,2-Dichloroethene ND
30.1 10.6 ug/Sample 12/10/19 09:47 12/10/19 20:56 1trans-1,3-Dichloropropene ND
30.1 2.16 ug/Sample 12/10/19 09:47 12/10/19 20:56 1TrichloroetheneND
60.1 5.77 ug/Sample 12/10/19 09:47 12/10/19 20:56 1TrichlorofluoromethaneND *
60.1 14.4 ug/Sample 12/10/19 09:47 12/10/19 20:56 1Vinyl chloride ND
Propene, hexafluoro-408 T J N ug/Sample 1.13 116-15-4 12/10/19 09:47 12/10/19 20:56 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
112/10/19 20:5612/10/19 09:47T JUnknown418 ug/Sample 1.18
1,2-Dichloroethane-d4 (Surr)116 70 -160 12/10/19 09:47 12/10/19 20:56 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 12/10/19 09:47 12/10/19 20:56 157-152
Dibromofluoromethane (Surr)104 12/10/19 09:47 12/10/19 20:56 162-134
Toluene-d8 (Surr)92 12/10/19 09:47 12/10/19 20:56 171-139
Method: 8260B - Volatile Organic Compounds (GC/MS) - DL
RL MDL
2-MTP as HFPO 2350 65.7 65.7 ug/Sample 12/10/19 09:47 12/11/19 17:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1,2-Dichloroethane-d4 (Surr)112 70 -160 12/10/19 09:47 12/11/19 17:42 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)107 12/10/19 09:47 12/11/19 17:42 157-152
Dibromofluoromethane (Surr)98 12/10/19 09:47 12/11/19 17:42 162-134
Toluene-d8 (Surr)96 12/10/19 09:47 12/11/19 17:42 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 4990 J 6410 3210 ug/Sample 12/10/19 09:47 12/20/19 01:38 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2650 1200 ug/Sample 12/10/19 09:47 12/24/19 04:42 20Hydrogen Fluoride ND
General Chemistry
RL MDL
pH 5.0 HF SU 12/17/19 13:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
12/30/2019Page 27 of 706122
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17557-1
Project/Site: VEN Stack - MM-18
Method: 8260B - Volatile Organic Compounds (GC/MS)
Prep: MeOH Prep
2.501,1,1,2-Tetrachloroethane ug/Sample
Analyte UnitsMDLRL
0.330
5.001,1,1,3,3-Pentafluorobutane ug/Sample0.500
2.501,1,1-Trichloroethane ug/Sample0.360
5.001,1,1-Trifluoro-2,2-dichloroethane ug/Sample0.990
5.001,1,1-Trifluoroethane ug/Sample0.500
2.501,1,2,2-Tetrachloroethane ug/Sample0.480
5.001,1,2-Trichloro-1,2,2-trifluoroethane ug/Sample0.280
5.001,1,2-trichloro-1-fluoroethane ug/Sample0.500
2.501,1,2-Trichloroethane ug/Sample0.260
5.001,1-Dichloro-1-fluoroethane ug/Sample2.50
5.001,1-dichloro-2,2-difluoroethane ug/Sample0.500
5.001,1-dichloro-2,2-difluoroethene ug/Sample0.500
2.501,1-Dichloroethane ug/Sample0.300
2.501,1-Dichloroethene ug/Sample0.370
2.501,1-Dichloropropene ug/Sample0.270
50.01,1-Difluoroethene ug/Sample50.0
5.001,2,2-trichloro-1,1-difluoroethane ug/Sample0.500
2.501,2,3-Trichlorobenzene ug/Sample0.800
2.501,2,3-Trichloropropane ug/Sample0.620
2.501,2,4-Trichlorobenzene ug/Sample0.840
2.501,2,4-Trimethylbenzene ug/Sample0.520
5.001,2-Dibromo-3-Chloropropane ug/Sample0.880
2.501,2-Dibromoethane (EDB)ug/Sample0.330
5.001,2-dichloro-1,1-difluoroethane ug/Sample0.500
2.501,2-Dichlorobenzene ug/Sample0.440
2.501,2-Dichloroethane ug/Sample0.420
2.501,2-Dichloropropane ug/Sample0.250
2.501,3,5-Trimethylbenzene ug/Sample0.520
2.501,3-Dichlorobenzene ug/Sample0.430
2.501,3-Dichloropropane ug/Sample0.280
2.501,4-Dichlorobenzene ug/Sample0.500
5.001-Chloro-1,1-difluoroethane ug/Sample0.510
5.002,2-dichloro-1,1-difluoroethylmethyl ether ug/Sample0.500
2.502,2-Dichloropropane ug/Sample0.730
10.02-Butanone (MEK)ug/Sample1.60
5.002-chloro-1,1,1,4,4,4-hexafluoro-2-butene ug/Sample0.740
5.002-Chloro-1,1,1-Trifluoroethane ug/Sample0.500
2.502-Chlorotoluene ug/Sample0.470
10.02-Hexanone ug/Sample2.30
2.502-MTP as HFPO ug/Sample2.50
2.504-Chlorotoluene ug/Sample0.520
2.504-Isopropyltoluene ug/Sample0.670
10.04-Methyl-2-pentanone (MIBK)ug/Sample1.60
10.0Acetone ug/Sample5.90
2.50Benzene ug/Sample0.480
2.50Bromobenzene ug/Sample0.350
2.50Bromochloromethane ug/Sample0.560
2.50Bromodichloromethane ug/Sample0.430
2.50Bromoform ug/Sample0.760
5.00Bromomethane ug/Sample2.90
2.50Carbon disulfide ug/Sample0.620
2.50Carbon tetrachloride ug/Sample0.330
Eurofins TestAmerica, Knoxville
12/30/2019Page 28 of 706123
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17557-1
Project/Site: VEN Stack - MM-18
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Prep: MeOH Prep
10.0Carbonyl Difluoride ug/Sample
Analyte UnitsMDLRL
10.0
2.50Chlorobenzene ug/Sample0.360
2.50Chlorodibromomethane ug/Sample0.540
5.00Chloroethane ug/Sample1.10
2.50Chloroform ug/Sample0.290
5.00Chloromethane ug/Sample2.08
2.50cis-1,2-Dichloroethene ug/Sample0.200
2.50cis-1,3-Dichloropropene ug/Sample0.430
2.50Dibromomethane ug/Sample0.240
5.00Dichlorodifluoromethane ug/Sample0.880
2.50Ethylbenzene ug/Sample0.410
2.50Heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether ug/Sample2.50
2.50Hexachlorobutadiene ug/Sample0.660
2.50HFPO dimer, methyl ester as HFPO-DA ug/Sample2.50
2.50Isopropylbenzene ug/Sample0.350
5.00m,p-Xylene ug/Sample0.410
2.50Methylene Chloride ug/Sample1.60
2.50Naphthalene ug/Sample1.20
2.50n-Butylbenzene ug/Sample0.640
2.50n-Propylbenzene ug/Sample0.540
2.50o-Xylene ug/Sample0.260
2.50sec-Butylbenzene ug/Sample0.490
2.50Styrene ug/Sample0.540
2.50tert-Butylbenzene ug/Sample0.440
2.50Tetrachloroethene ug/Sample0.330
2.50Toluene ug/Sample0.460
2.50trans-1,2-Dichloroethene ug/Sample0.260
2.50trans-1,3-Dichloropropene ug/Sample0.880
2.50Trichloroethene ug/Sample0.180
5.00Trichlorofluoromethane ug/Sample0.480
5.00Vinyl chloride ug/Sample1.20
Method: 9056 - Anions, Ion Chromatography
Prep: MeOH Prep
11.0Hydrogen Fluoride ug/Sample
Analyte UnitsMDLRL
5.00
1000Total Fluorine ug/Sample500
Eurofins TestAmerica, Knoxville
12/30/2019Page 29 of 706124
ANALYTICAL REPORT
Job Number: 140-17462-1
Job Description: VEN MM-18 Field QC
Contract Number: LBIO-67048
For:
Chemours Company FC, LLC The
c/o AECOM
Sabre Building, Suite 300
4051 Ogletown Road
Newark, DE 19713
Attention: Michael Aucoin
_____________________________________________
Approved for release.
Courtney M Adkins
Project Manager II
12/23/2019 3:02 PM
Courtney M Adkins, Project Manager II
5815 Middlebrook Pike, Knoxville, TN, 37921
[phone]
[e-mail]
12/23/2019
This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at
the e-mail address or telephone number listed on this page.
The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology, with any
exceptions noted. This report shall not be reproduced except in full, without the express written approval of the laboratory. All questions should be
directed to the Eurofins TestAmerica Project Manager.
This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a
traditionally handwritten signature.
Eurofins TestAmerica, Knoxville
5815 Middlebrook Pike, Knoxville, TN 37921
Tel [phone] Fax [phone] www.testamericainc.com
12/23/2019Page 1 of 820125
Table of Contents
Cover Title Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Data Summaries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .5
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .7
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .8
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .10
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .13
Default Detection Limits . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .35
Surrogate Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .37
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .39
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .46
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .54
Manual Integration Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .56
Organic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
GC/MS VOA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .69
Method 8260B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .69
Method 8260B QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .70
Method 8260B Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .83
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .179
Method 8260B ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .179
Method 8260B CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .281
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .329
Method 8260B Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .329
Method 8260B Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .345
Method 8260B LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .355
12/23/2019Page 2 of 820126
Table of Contents
Method 8260B MS/MSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .368
Method 8260B Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .376
Method 8260B Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .389
HPLC/IC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .392
Method 9056 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .392
Method 9056 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .393
Method 9056 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .396
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .423
Method 9056 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .423
Method 9056 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .450
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .493
Method 9056 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .493
Method 9056 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .519
Method 9056 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .525
Method 9056 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .539
Method 9056A Total Halogens . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .541
Method 9056A Total Halogens QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .542
Method 9056A Total Halogens Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .545
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .580
Method 9056A Total Halogens ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .580
Method 9056A Total Halogens CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .605
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .624
Method 9056A Total Halogens Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .624
Method 9056A Total Halogens LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .641
Method 9056A Total Halogens Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .649
Method 9056A Total Halogens Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .658
12/23/2019Page 3 of 820127
Table of Contents
LCMS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .662
Method DV-LC-0012 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .662
Method DV-LC-0012 QC Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .663
Method DV-LC-0012 Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .668
Standards Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .704
Method DV-LC-0012 ICAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .704
Method DV-LC-0012 CCAL Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .751
Raw QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .763
Method DV-LC-0012 Tune Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .763
Method DV-LC-0012 Blank Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .768
Method DV-LC-0012 LCS/LCSD Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .772
Method DV-LC-0012 Run Logs . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .785
Method DV-LC-0012 Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .788
Inorganic Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 796
General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .796
Gen Chem Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .797
Gen Chem Sample Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .798
Gen Chem QC Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .807
Gen Chem ICV/CCV . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .807
Gen Chem MDL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .808
Gen Chem Analysis Run Log . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .809
Gen Chem Prep Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .810
Gen Chem Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .811
Shipping and Receiving Documents . . . . . . . . . . . . . . . . . . . . . . . . . . . 813
Client Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .814
12/23/2019Page 4 of 820128
Definitions/Glossary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Qualifiers
GC/MS VOA
Qualifier Description
*LCS or LCSD is outside acceptance limits.
Qualifier
B Compound was found in the blank and sample.
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
GC/MS VOA TICs
Qualifier Description
J Indicates an Estimated Value for TICs
Qualifier
N Presumptive evidence of material.
T Result is a tentatively identified compound (TIC) and an estimated value.
HPLC/IC
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
LCMS
Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Qualifier
General Chemistry
Qualifier Description
HF Field parameter with a holding time of 15 minutes. Test performed by laboratory at client's request.
Qualifier
Glossary
These commonly used abbreviations may or may not be present in this report.
¤Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Knoxville
12/23/2019Page 5 of 820129
Method Summary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Method Method Description LaboratoryProtocol
SW8468260BVolatile Organic Compounds (GC/MS)TAL KNX
SW8469056Anions, Ion Chromatography TAL KNX
SW8468321APFOA and PFOS TAL DEN
SW8469041ApH TAL KNX
SW8465050Bomb Preparation Method for Solid Waste TAL KNX
NoneMeOH Prep Methanol Impinger Preparation TAL KNX
TAL SOPNoneLeaching Procedure TAL DEN
Protocol References:
None = None
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TAL SOP = TestAmerica Laboratories, Standard Operating Procedure
Laboratory References:
TAL DEN = Eurofins TestAmerica, Denver, 4955 Yarrow Street, Arvada, CO 80002, TEL [phone]
TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL [phone]
Eurofins TestAmerica, Knoxville
12/23/2019Page 6 of 820130
Sample Summary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6
BT
Air 11/22/19 00:00 11/25/19 08:00
140-17462-7 A-5786 QC MEOH RB Air 11/22/19 00:00 11/25/19 08:00
140-17462-8 A-5787 QC MEOH TB Air 11/22/19 00:00 11/25/19 08:00
140-17462-9 A-5788 QC MEOH PB Air 11/22/19 00:00 11/25/19 08:00
Eurofins TestAmerica, Knoxville
12/23/2019Page 7 of 820131
Job Narrative
140-17462-1
Sample Receipt
The samples were received on November 25, 2019 at 8:00 AM in good condition and properly preserved. The temperature of the cooler
at receipt was 3.3º C.
GC/MS VOA
Impinger Sample Preparation and Analysis: Impinger samples were analyzed for the volatile organic target analytes by purge and trap
GCMS using Eurofins TestAmerica Knoxville standard operating procedure KNOX-MS-0015, based on the following method:
· SW-846 8260B, “Volatile Organic Compounds by Gas Chromatography/ Mass Spectrometry (GC/MS)”
Each sample is prepared by adding a known amount of sample to the purge water in a purge and trap vessel and spiking with internal
standards, surrogates, and matrix spike analytes (as needed). Volatile compounds are introduced into the gas chromatograph by the
purge and trap method. The components are separated using the chromatograph and detected using a mass spectrometer, which
provides both qualitative and quantitative information.
Impinger sample results were calculated using the following equation:
Concentration, μg/sample = (C × DF × W × Vt) / (Va)
Where:
C = On-column concentration, μg/L
DF = Dilution factor
W = Volume of water purged, L
Vt = Methanol extract final volume, μL
Va = Volume of extract analyzed, µL
Method 8260B: The following analyte(s) recovered outside control limits, but within marginal exceedance limits, for the LCS associated
with batch 140-35880: Trichlorofluoromethane. This is not indicative of a systematic control problem because these were random
marginal exceedances. Qualified results have been reported.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
LCMS
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
General Chemistry
Total Chlorine: The samples were prepared for total chlorine using SOP number KNOX-WC-0016 (based on ASTM Method E442 and
SW-846 Method 5050). The sample is oxidized by combustion in an oxygen flask at atmospheric pressure or a bomb containing oxygen
under pressure. The liberated halogen compounds are absorbed primarily as halides in a sodium carbonate/sodium bicarbonate buffer
solution. The combustion products are collected by repeated rinsing of the combustion apparatus, and analyzed by ion chromatography in
accordance with SOP KNOX- WC-0005 (based on SW-846 Method 9056). The results are calculated using the following equation:
C = [(Ccom × Vcom) / W] × 1000 g/Kg
Where:
C = Concentration of analyte in the sample, mg/Kg
Ccom = Concentration of analyte in the combustate, mg/L
Vcom = Total volume of combustate, L
W = Weight of sample combusted, g
Anions in Impinger Solutions: Anions are is determined in accordance to SOP KNOX-WC-0005 (based on methods 300.0A and 9056).
The samples were diluted a minimum of 1/20 in ion chromatography solvent buffer solution to reduce the methanol concentration before
injection. Buffer concentrate was added until the pH was 10. Samples are diluted with ion chromatography eluate solution to bring the
concentrations within the calibration range when necessary. Higher dilutions are applied as necessary.
An aliquot of prepared sample is introduced into the ion chromatograph. Anions are identified based on their retention times as compared
to those of known standards. Quantification is accomplished by measuring the peak response and comparing it to a calibration curve
generated from known standards.
12/23/2019Page 8 of 820132
The pH of all samples were tested with pH paper. QC consisted of initial CCV and LCS which also serve as initial calibration, duplicate
analysis for every 10 samples, and closing CCV. A certified thermometer was used to check the ambient temperature.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Organic Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
12/23/2019Page 9 of 820133
QC Association Summary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
GC/MS VOA
Prep Batch: 35705
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air MeOH Prep140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air MeOH Prep140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air MeOH Prep140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air MeOH Prep140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air MeOH Prep140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air MeOH Prep140-17462-7 A-5786 QC MEOH RB Total/NA
Air MeOH Prep140-17462-8 A-5787 QC MEOH TB Total/NA
Air MeOH Prep140-17462-9 A-5788 QC MEOH PB Total/NA
Air MeOH PrepMB 140-35705/2-A Method Blank Total/NA
Air MeOH PrepLCS 140-35705/1-A Lab Control Sample Total/NA
Air MeOH Prep140-17462-2 MS A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air MeOH Prep140-17462-2 MSD A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Analysis Batch: 35880
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8260B 35705140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 8260B 35705140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 8260B 35705140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 8260B 35705140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 8260B 35705140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 8260B 35705140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 8260B 35705140-17462-7 A-5786 QC MEOH RB Total/NA
Air 8260B 35705140-17462-8 A-5787 QC MEOH TB Total/NA
Air 8260B 35705140-17462-9 A-5788 QC MEOH PB Total/NA
Air 8260B 35705MB 140-35705/2-A Method Blank Total/NA
Air 8260B 35705LCS 140-35705/1-A Lab Control Sample Total/NA
Air 8260B 35705LCS 140-35705/1-A Lab Control Sample Total/NA
Air 8260B 35705140-17462-2 MS A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 8260B 35705140-17462-2 MSD A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
HPLC/IC
Prep Batch: 35705
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air MeOH Prep140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air MeOH Prep140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air MeOH Prep140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air MeOH Prep140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air MeOH Prep140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air MeOH Prep140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air MeOH Prep140-17462-7 A-5786 QC MEOH RB Total/NA
Air MeOH Prep140-17462-8 A-5787 QC MEOH TB Total/NA
Air MeOH Prep140-17462-9 A-5788 QC MEOH PB Total/NA
Air MeOH PrepMB 140-35705/14-A Method Blank Total/NA
Air MeOH PrepMB 140-35705/14-B Method Blank Total/NA
Air MeOH PrepLCS 140-35705/15-A Lab Control Sample Total/NA
Air MeOH PrepLCS 140-35705/15-B Lab Control Sample Total/NA
Air MeOH PrepLCSD 140-35705/16-A Lab Control Sample Dup Total/NA
Air MeOH PrepLCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 10 of 820134
QC Association Summary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
HPLC/IC
Prep Batch: 35762
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 5050 35705140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 5050 35705140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 5050 35705140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 5050 35705140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 5050 35705140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 5050 35705140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 5050 35705140-17462-7 A-5786 QC MEOH RB Total/NA
Air 5050 35705140-17462-8 A-5787 QC MEOH TB Total/NA
Air 5050 35705140-17462-9 A-5788 QC MEOH PB Total/NA
Air 5050 35705MB 140-35705/14-B Method Blank Total/NA
Air 5050 35705LCS 140-35705/15-B Lab Control Sample Total/NA
Air 5050 35705LCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Analysis Batch: 36121
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35762140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 9056 35762140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 9056 35762140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 9056 35762140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 9056 35762140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 9056 35762140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 9056 35762140-17462-7 A-5786 QC MEOH RB Total/NA
Air 9056 35762140-17462-8 A-5787 QC MEOH TB Total/NA
Air 9056 35762140-17462-9 A-5788 QC MEOH PB Total/NA
Air 9056 35762MB 140-35705/14-B Method Blank Total/NA
Air 9056 35762LCS 140-35705/15-B Lab Control Sample Total/NA
Air 9056 35762LCSD 140-35705/16-B Lab Control Sample Dup Total/NA
Analysis Batch: 36210
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9056 35705140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 9056 35705140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 9056 35705140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 9056 35705140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 9056 35705140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 9056 35705140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 9056 35705140-17462-7 A-5786 QC MEOH RB Total/NA
Air 9056 35705140-17462-8 A-5787 QC MEOH TB Total/NA
Air 9056 35705140-17462-9 A-5788 QC MEOH PB Total/NA
Air 9056 35705MB 140-35705/14-A Method Blank Total/NA
Air 9056 35705LCS 140-35705/15-A Lab Control Sample Total/NA
Air 9056 35705LCSD 140-35705/16-A Lab Control Sample Dup Total/NA
LCMS
Analysis Batch: 464589
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321ADLCK 280-464589/13 Lab Control Sample Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 11 of 820135
QC Association Summary
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
LCMS
Prep Batch: 479505
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air None140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air None140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air None140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air None140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air None140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air None140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air None140-17462-7 A-5786 QC MEOH RB Total/NA
Air None140-17462-8 A-5787 QC MEOH TB Total/NA
Air None140-17462-9 A-5788 QC MEOH PB Total/NA
Air NoneMB 280-479505/1-A Method Blank Total/NA
Air NoneLCS 280-479505/2-A Lab Control Sample Total/NA
Air NoneLCSD 280-479505/3-A Lab Control Sample Dup Total/NA
Analysis Batch: 479931
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 8321A 479505140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 8321A 479505140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 8321A 479505140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 8321A 479505140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 8321A 479505140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 8321A 479505140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 8321A 479505140-17462-7 A-5786 QC MEOH RB Total/NA
Air 8321A 479505140-17462-8 A-5787 QC MEOH TB Total/NA
Air 8321A 479505140-17462-9 A-5788 QC MEOH PB Total/NA
Air 8321A 479505MB 280-479505/1-A Method Blank Total/NA
Air 8321A 479505LCS 280-479505/2-A Lab Control Sample Total/NA
Air 8321A 479505LCSD 280-479505/3-A Lab Control Sample Dup Total/NA
General Chemistry
Analysis Batch: 36086
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Air 9041A140-17462-1 A-5780 QC VEN DIV STACK MM18 IMPINGER #1 BTTotal/NA
Air 9041A140-17462-2 A-5781 QC VEN DIV STACK MM18 IMPINGER #2 BTTotal/NA
Air 9041A140-17462-3 A-5782 QC VEN DIV STACK MM18 IMPINGER #3 BTTotal/NA
Air 9041A140-17462-4 A-5783 QC VEN DIV STACK MM18 IMPINGER #4 BTTotal/NA
Air 9041A140-17462-5 A-5784 QC VEN DIV STACK MM18 IMPINGER #5 BTTotal/NA
Air 9041A140-17462-6 A-5785 QC VEN DIV STACK MM18 IMPINGER #6 BTTotal/NA
Air 9041A140-17462-7 A-5786 QC MEOH RB Total/NA
Air 9041A140-17462-8 A-5787 QC MEOH TB Total/NA
Air 9041A140-17462-9 A-5788 QC MEOH PB Total/NA
Air 9041ALCS 140-36086/2 Lab Control Sample Total/NA
Eurofins TestAmerica, Knoxville
12/23/2019Page 12 of 820136
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-1Client Sample ID: A-5780 QC VEN DIV STACK MM18
IMPINGER #1 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 28.7 3.79 ug/Sample 11/29/19 10:45 12/06/19 15:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,1,3,3-Pentafluorobutane ND
28.7 4.13 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,1-Trichloroethane ND
57.4 11.4 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,1-Trifluoro-2,2-dichloroethane ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,1-Trifluoroethane ND
28.7 5.51 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,2,2-Tetrachloroethane ND
57.4 3.21 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,2-Trichloro-1,2,2-trifluoroethane ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,2-trichloro-1-fluoroethane ND
28.7 2.98 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1,2-Trichloroethane ND
57.4 28.7 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-Dichloro-1-fluoroethane ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-dichloro-2,2-difluoroethane ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-dichloro-2,2-difluoroethene ND
28.7 3.44 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-Dichloroethane ND
28.7 4.25 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-Dichloroethene ND
28.7 3.10 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-Dichloropropene ND
574 574 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,1-Difluoroethene ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2,2-trichloro-1,1-difluoroethane ND
28.7 9.18 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2,3-Trichlorobenzene ND
28.7 7.12 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2,3-Trichloropropane ND
28.7 9.64 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2,4-Trichlorobenzene ND
28.7 5.97 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2,4-Trimethylbenzene ND
57.4 10.1 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-Dibromo-3-Chloropropane ND
28.7 3.79 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-Dibromoethane (EDB)ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-dichloro-1,1-difluoroethane ND
28.7 5.05 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-Dichlorobenzene ND
28.7 4.82 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-Dichloroethane ND
28.7 2.87 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,2-Dichloropropane ND
28.7 5.97 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,3,5-Trimethylbenzene ND
28.7 4.94 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,3-Dichlorobenzene ND
28.7 3.21 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,3-Dichloropropane ND
28.7 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 11,4-Dichlorobenzene ND
57.4 5.85 ug/Sample 11/29/19 10:45 12/06/19 15:17 11-Chloro-1,1-difluoroethane ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
28.7 8.38 ug/Sample 11/29/19 10:45 12/06/19 15:17 12,2-Dichloropropane ND
115 18.4 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-Butanone (MEK)ND
57.4 8.49 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
57.4 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-Chloro-1,1,1-Trifluoroethane ND
28.7 5.40 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-Chlorotoluene ND
115 26.4 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-Hexanone ND
25.1 25.1 ug/Sample 11/29/19 10:45 12/06/19 15:17 12-MTP as HFPO ND
28.7 5.97 ug/Sample 11/29/19 10:45 12/06/19 15:17 14-Chlorotoluene ND
28.7 7.69 ug/Sample 11/29/19 10:45 12/06/19 15:17 14-Isopropyltoluene ND
115 18.4 ug/Sample 11/29/19 10:45 12/06/19 15:17 14-Methyl-2-pentanone (MIBK)ND
115 67.7 ug/Sample 11/29/19 10:45 12/06/19 15:17 1AcetoneND
28.7 5.51 ug/Sample 11/29/19 10:45 12/06/19 15:17 1BenzeneND
28.7 4.02 ug/Sample 11/29/19 10:45 12/06/19 15:17 1BromobenzeneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 13 of 820137
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-1Client Sample ID: A-5780 QC VEN DIV STACK MM18
IMPINGER #1 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromochloromethane ND 28.7 6.43 ug/Sample 11/29/19 10:45 12/06/19 15:17 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
28.7 4.94 ug/Sample 11/29/19 10:45 12/06/19 15:17 1BromodichloromethaneND
28.7 8.72 ug/Sample 11/29/19 10:45 12/06/19 15:17 1BromoformND
57.4 33.3 ug/Sample 11/29/19 10:45 12/06/19 15:17 1BromomethaneND
28.7 7.12 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Carbon disulfide ND
28.7 3.79 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Carbon tetrachloride ND
84.3 84.3 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Carbonyl Difluoride ND
28.7 4.13 ug/Sample 11/29/19 10:45 12/06/19 15:17 1ChlorobenzeneND
28.7 6.20 ug/Sample 11/29/19 10:45 12/06/19 15:17 1ChlorodibromomethaneND
57.4 12.6 ug/Sample 11/29/19 10:45 12/06/19 15:17 1ChloroethaneND
28.7 3.33 ug/Sample 11/29/19 10:45 12/06/19 15:17 1ChloroformND
57.4 23.9 ug/Sample 11/29/19 10:45 12/06/19 15:17 1ChloromethaneND
28.7 2.30 ug/Sample 11/29/19 10:45 12/06/19 15:17 1cis-1,2-Dichloroethene ND
28.7 4.94 ug/Sample 11/29/19 10:45 12/06/19 15:17 1cis-1,3-Dichloropropene ND
28.7 2.75 ug/Sample 11/29/19 10:45 12/06/19 15:17 1DibromomethaneND
57.4 10.1 ug/Sample 11/29/19 10:45 12/06/19 15:17 1DichlorodifluoromethaneND
28.7 4.71 ug/Sample 11/29/19 10:45 12/06/19 15:17 1EthylbenzeneND
28.7 28.7 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
28.7 7.58 ug/Sample 11/29/19 10:45 12/06/19 15:17 1HexachlorobutadieneND
27.5 27.5 ug/Sample 11/29/19 10:45 12/06/19 15:17 1HFPO dimer, methyl ester as
HFPO-DA
ND
28.7 4.02 ug/Sample 11/29/19 10:45 12/06/19 15:17 1IsopropylbenzeneND
57.4 4.71 ug/Sample 11/29/19 10:45 12/06/19 15:17 1m,p-Xylene ND
28.7 18.4 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Methylene Chloride ND
28.7 13.8 ug/Sample 11/29/19 10:45 12/06/19 15:17 1NaphthaleneND
28.7 7.35 ug/Sample 11/29/19 10:45 12/06/19 15:17 1n-Butylbenzene ND
28.7 6.20 ug/Sample 11/29/19 10:45 12/06/19 15:17 1n-Propylbenzene ND
28.7 2.98 ug/Sample 11/29/19 10:45 12/06/19 15:17 1o-Xylene ND
28.7 5.62 ug/Sample 11/29/19 10:45 12/06/19 15:17 1sec-Butylbenzene ND
28.7 6.20 ug/Sample 11/29/19 10:45 12/06/19 15:17 1StyreneND
28.7 5.05 ug/Sample 11/29/19 10:45 12/06/19 15:17 1tert-Butylbenzene ND
28.7 3.79 ug/Sample 11/29/19 10:45 12/06/19 15:17 1TetrachloroetheneND
28.7 5.28 ug/Sample 11/29/19 10:45 12/06/19 15:17 1TolueneND
28.7 2.98 ug/Sample 11/29/19 10:45 12/06/19 15:17 1trans-1,2-Dichloroethene ND
28.7 10.1 ug/Sample 11/29/19 10:45 12/06/19 15:17 1trans-1,3-Dichloropropene ND
28.7 2.07 ug/Sample 11/29/19 10:45 12/06/19 15:17 1TrichloroetheneND
57.4 5.51 ug/Sample 11/29/19 10:45 12/06/19 15:17 1TrichlorofluoromethaneND *
57.4 13.8 ug/Sample 11/29/19 10:45 12/06/19 15:17 1Vinyl chloride ND
Tentatively Identified Compound None ug/Sample 11/29/19 10:45 12/06/19 15:17 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:45 12/06/19 15:17 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:45 12/06/19 15:17 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 15:17 162-134
Toluene-d8 (Surr)97 11/29/19 10:45 12/06/19 15:17 171-139
Eurofins TestAmerica, Knoxville
12/23/2019Page 14 of 820138
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-1Client Sample ID: A-5780 QC VEN DIV STACK MM18
IMPINGER #1 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 11800 6120 3060 ug/Sample 11/29/19 10:45 12/13/19 21:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2530 1150 ug/Sample 11/29/19 10:45 12/18/19 13:19 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 130 50 -200 12/04/19 10:05 12/08/19 10:37 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-2Client Sample ID: A-5781 QC VEN DIV STACK MM18
IMPINGER #2 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 29.9 3.94 ug/Sample 11/29/19 10:45 12/06/19 15:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,1,3,3-Pentafluorobutane ND
29.9 4.30 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,1-Trichloroethane ND
59.8 11.8 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,1-Trifluoro-2,2-dichloroethane ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,1-Trifluoroethane ND
29.9 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,2,2-Tetrachloroethane ND
59.8 3.35 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,2-Trichloro-1,2,2-trifluoroethane ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,2-trichloro-1-fluoroethane ND
29.9 3.11 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1,2-Trichloroethane ND
59.8 29.9 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-Dichloro-1-fluoroethane ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-dichloro-2,2-difluoroethane ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-dichloro-2,2-difluoroethene ND
29.9 3.59 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-Dichloroethane ND
29.9 4.42 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-Dichloroethene ND
29.9 3.23 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-Dichloropropene ND
598 598 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,1-Difluoroethene ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2,2-trichloro-1,1-difluoroethane ND
29.9 9.56 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2,3-Trichlorobenzene ND
29.9 7.41 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2,3-Trichloropropane ND
29.9 10.0 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2,4-Trichlorobenzene ND
29.9 6.21 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2,4-Trimethylbenzene ND
59.8 10.5 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2-Dibromo-3-Chloropropane ND
29.9 3.94 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2-Dibromoethane (EDB)ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2-dichloro-1,1-difluoroethane ND
29.9 5.26 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2-Dichlorobenzene ND
29.9 5.02 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,2-Dichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 15 of 820139
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-2Client Sample ID: A-5781 QC VEN DIV STACK MM18
IMPINGER #2 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2-Dichloropropane ND 29.9 2.99 ug/Sample 11/29/19 10:45 12/06/19 15:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.9 6.21 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,3,5-Trimethylbenzene ND
29.9 5.14 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,3-Dichlorobenzene ND
29.9 3.35 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,3-Dichloropropane ND
29.9 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 11,4-Dichlorobenzene ND
59.8 6.10 ug/Sample 11/29/19 10:45 12/06/19 15:42 11-Chloro-1,1-difluoroethane ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
29.9 8.72 ug/Sample 11/29/19 10:45 12/06/19 15:42 12,2-Dichloropropane ND
120 19.1 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-Butanone (MEK)ND
59.8 8.84 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
59.8 5.98 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-Chloro-1,1,1-Trifluoroethane ND
29.9 5.62 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-Chlorotoluene ND
120 27.5 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-Hexanone ND
26.1 26.1 ug/Sample 11/29/19 10:45 12/06/19 15:42 12-MTP as HFPO ND
29.9 6.21 ug/Sample 11/29/19 10:45 12/06/19 15:42 14-Chlorotoluene ND
29.9 8.01 ug/Sample 11/29/19 10:45 12/06/19 15:42 14-Isopropyltoluene ND
120 19.1 ug/Sample 11/29/19 10:45 12/06/19 15:42 14-Methyl-2-pentanone (MIBK)ND
120 70.5 ug/Sample 11/29/19 10:45 12/06/19 15:42 1AcetoneND
29.9 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BenzeneND
29.9 4.18 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BromobenzeneND
29.9 6.69 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BromochloromethaneND
29.9 5.14 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BromodichloromethaneND
29.9 9.08 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BromoformND
59.8 34.7 ug/Sample 11/29/19 10:45 12/06/19 15:42 1BromomethaneND
29.9 7.41 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Carbon disulfide ND
29.9 3.94 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Carbon tetrachloride ND
87.9 87.9 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Carbonyl Difluoride ND
29.9 4.30 ug/Sample 11/29/19 10:45 12/06/19 15:42 1ChlorobenzeneND
29.9 6.45 ug/Sample 11/29/19 10:45 12/06/19 15:42 1ChlorodibromomethaneND
59.8 13.1 ug/Sample 11/29/19 10:45 12/06/19 15:42 1ChloroethaneND
29.9 3.47 ug/Sample 11/29/19 10:45 12/06/19 15:42 1ChloroformND
59.8 24.9 ug/Sample 11/29/19 10:45 12/06/19 15:42 1ChloromethaneND
29.9 2.39 ug/Sample 11/29/19 10:45 12/06/19 15:42 1cis-1,2-Dichloroethene ND
29.9 5.14 ug/Sample 11/29/19 10:45 12/06/19 15:42 1cis-1,3-Dichloropropene ND
29.9 2.87 ug/Sample 11/29/19 10:45 12/06/19 15:42 1DibromomethaneND
59.8 10.5 ug/Sample 11/29/19 10:45 12/06/19 15:42 1DichlorodifluoromethaneND
29.9 4.90 ug/Sample 11/29/19 10:45 12/06/19 15:42 1EthylbenzeneND
29.9 29.9 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
29.9 7.89 ug/Sample 11/29/19 10:45 12/06/19 15:42 1HexachlorobutadieneND
28.7 28.7 ug/Sample 11/29/19 10:45 12/06/19 15:42 1HFPO dimer, methyl ester as
HFPO-DA
ND
29.9 4.18 ug/Sample 11/29/19 10:45 12/06/19 15:42 1IsopropylbenzeneND
59.8 4.90 ug/Sample 11/29/19 10:45 12/06/19 15:42 1m,p-Xylene ND
29.9 19.1 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Methylene Chloride ND
29.9 14.3 ug/Sample 11/29/19 10:45 12/06/19 15:42 1NaphthaleneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 16 of 820140
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-2Client Sample ID: A-5781 QC VEN DIV STACK MM18
IMPINGER #2 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Butylbenzene ND 29.9 7.65 ug/Sample 11/29/19 10:45 12/06/19 15:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.9 6.45 ug/Sample 11/29/19 10:45 12/06/19 15:42 1n-Propylbenzene ND
29.9 3.11 ug/Sample 11/29/19 10:45 12/06/19 15:42 1o-Xylene ND
29.9 5.86 ug/Sample 11/29/19 10:45 12/06/19 15:42 1sec-Butylbenzene ND
29.9 6.45 ug/Sample 11/29/19 10:45 12/06/19 15:42 1StyreneND
29.9 5.26 ug/Sample 11/29/19 10:45 12/06/19 15:42 1tert-Butylbenzene ND
29.9 3.94 ug/Sample 11/29/19 10:45 12/06/19 15:42 1TetrachloroetheneND
29.9 5.50 ug/Sample 11/29/19 10:45 12/06/19 15:42 1TolueneND
29.9 3.11 ug/Sample 11/29/19 10:45 12/06/19 15:42 1trans-1,2-Dichloroethene ND
29.9 10.5 ug/Sample 11/29/19 10:45 12/06/19 15:42 1trans-1,3-Dichloropropene ND
29.9 2.15 ug/Sample 11/29/19 10:45 12/06/19 15:42 1TrichloroetheneND
59.8 5.74 ug/Sample 11/29/19 10:45 12/06/19 15:42 1TrichlorofluoromethaneND *
59.8 14.3 ug/Sample 11/29/19 10:45 12/06/19 15:42 1Vinyl chloride ND
Cyclohexane 43.3 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 15:42 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:45 12/06/19 15:42 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:45 12/06/19 15:42 157-152
Dibromofluoromethane (Surr)105 11/29/19 10:45 12/06/19 15:42 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 15:42 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 14800 6370 3190 ug/Sample 11/29/19 10:45 12/13/19 22:14 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2630 1200 ug/Sample 11/29/19 10:45 12/18/19 13:40 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:40 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 131 50 -200 12/04/19 10:05 12/08/19 10:40 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-3Client Sample ID: A-5782 QC VEN DIV STACK MM18
IMPINGER #3 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 16:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,1,3,3-Pentafluorobutane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 17 of 820141
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-3Client Sample ID: A-5782 QC VEN DIV STACK MM18
IMPINGER #3 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,1-Trichloroethane ND 29.1 4.19 ug/Sample 11/29/19 10:45 12/06/19 16:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
58.2 11.5 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,1-Trifluoro-2,2-dichloroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,1-Trifluoroethane ND
29.1 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,2,2-Tetrachloroethane ND
58.2 3.26 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,2-Trichloro-1,2,2-trifluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,2-trichloro-1-fluoroethane ND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1,2-Trichloroethane ND
58.2 29.1 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-Dichloro-1-fluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-dichloro-2,2-difluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-dichloro-2,2-difluoroethene ND
29.1 3.49 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-Dichloroethane ND
29.1 4.31 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-Dichloroethene ND
29.1 3.14 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-Dichloropropene ND
582 582 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,1-Difluoroethene ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2,2-trichloro-1,1-difluoroethane ND
29.1 9.32 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2,3-Trichlorobenzene ND
29.1 7.22 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2,3-Trichloropropane ND
29.1 9.78 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2,4-Trichlorobenzene ND
29.1 6.06 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2,4-Trimethylbenzene ND
58.2 10.2 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-Dibromo-3-Chloropropane ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-Dibromoethane (EDB)ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-dichloro-1,1-difluoroethane ND
29.1 5.12 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-Dichlorobenzene ND
29.1 4.89 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-Dichloroethane ND
29.1 2.91 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,2-Dichloropropane ND
29.1 6.06 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,3,5-Trimethylbenzene ND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,3-Dichlorobenzene ND
29.1 3.26 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,3-Dichloropropane ND
29.1 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 11,4-Dichlorobenzene ND
58.2 5.94 ug/Sample 11/29/19 10:45 12/06/19 16:06 11-Chloro-1,1-difluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
29.1 8.50 ug/Sample 11/29/19 10:45 12/06/19 16:06 12,2-Dichloropropane ND
116 18.6 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-Butanone (MEK)ND
58.2 8.62 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-Chloro-1,1,1-Trifluoroethane ND
29.1 5.47 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-Chlorotoluene ND
116 26.8 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-Hexanone ND
25.4 25.4 ug/Sample 11/29/19 10:45 12/06/19 16:06 12-MTP as HFPO ND
29.1 6.06 ug/Sample 11/29/19 10:45 12/06/19 16:06 14-Chlorotoluene ND
29.1 7.80 ug/Sample 11/29/19 10:45 12/06/19 16:06 14-Isopropyltoluene ND
116 18.6 ug/Sample 11/29/19 10:45 12/06/19 16:06 14-Methyl-2-pentanone (MIBK)ND
116 68.7 ug/Sample 11/29/19 10:45 12/06/19 16:06 1AcetoneND
29.1 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:06 1BenzeneND
29.1 4.08 ug/Sample 11/29/19 10:45 12/06/19 16:06 1BromobenzeneND
29.1 6.52 ug/Sample 11/29/19 10:45 12/06/19 16:06 1BromochloromethaneND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 16:06 1BromodichloromethaneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 18 of 820142
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-3Client Sample ID: A-5782 QC VEN DIV STACK MM18
IMPINGER #3 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromoform ND 29.1 8.85 ug/Sample 11/29/19 10:45 12/06/19 16:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
58.2 33.8 ug/Sample 11/29/19 10:45 12/06/19 16:06 1BromomethaneND
29.1 7.22 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Carbon disulfide ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Carbon tetrachloride ND
85.0 85.0 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Carbonyl Difluoride ND
29.1 4.19 ug/Sample 11/29/19 10:45 12/06/19 16:06 1ChlorobenzeneND
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 16:06 1ChlorodibromomethaneND
58.2 12.8 ug/Sample 11/29/19 10:45 12/06/19 16:06 1ChloroethaneND
29.1 3.38 ug/Sample 11/29/19 10:45 12/06/19 16:06 1ChloroformND
58.2 24.2 ug/Sample 11/29/19 10:45 12/06/19 16:06 1ChloromethaneND
29.1 2.33 ug/Sample 11/29/19 10:45 12/06/19 16:06 1cis-1,2-Dichloroethene ND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 16:06 1cis-1,3-Dichloropropene ND
29.1 2.80 ug/Sample 11/29/19 10:45 12/06/19 16:06 1DibromomethaneND
58.2 10.2 ug/Sample 11/29/19 10:45 12/06/19 16:06 1DichlorodifluoromethaneND
29.1 4.77 ug/Sample 11/29/19 10:45 12/06/19 16:06 1EthylbenzeneND
29.1 29.1 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
29.1 7.69 ug/Sample 11/29/19 10:45 12/06/19 16:06 1HexachlorobutadieneND
27.9 27.9 ug/Sample 11/29/19 10:45 12/06/19 16:06 1HFPO dimer, methyl ester as
HFPO-DA
ND
29.1 4.08 ug/Sample 11/29/19 10:45 12/06/19 16:06 1IsopropylbenzeneND
58.2 4.77 ug/Sample 11/29/19 10:45 12/06/19 16:06 1m,p-Xylene ND
29.1 18.6 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Methylene Chloride ND
29.1 14.0 ug/Sample 11/29/19 10:45 12/06/19 16:06 1NaphthaleneND
29.1 7.45 ug/Sample 11/29/19 10:45 12/06/19 16:06 1n-Butylbenzene ND
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 16:06 1n-Propylbenzene ND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 16:06 1o-Xylene ND
29.1 5.71 ug/Sample 11/29/19 10:45 12/06/19 16:06 1sec-Butylbenzene ND
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 16:06 1StyreneND
29.1 5.12 ug/Sample 11/29/19 10:45 12/06/19 16:06 1tert-Butylbenzene ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 16:06 1TetrachloroetheneND
29.1 5.36 ug/Sample 11/29/19 10:45 12/06/19 16:06 1TolueneND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 16:06 1trans-1,2-Dichloroethene ND
29.1 10.2 ug/Sample 11/29/19 10:45 12/06/19 16:06 1trans-1,3-Dichloropropene ND
29.1 2.10 ug/Sample 11/29/19 10:45 12/06/19 16:06 1TrichloroetheneND
58.2 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:06 1TrichlorofluoromethaneND *
58.2 14.0 ug/Sample 11/29/19 10:45 12/06/19 16:06 1Vinyl chloride ND
Cyclohexane 42.4 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 16:06 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:45 12/06/19 16:06 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:45 12/06/19 16:06 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 16:06 162-134
Toluene-d8 (Surr)98 11/29/19 10:45 12/06/19 16:06 171-139
Eurofins TestAmerica, Knoxville
12/23/2019Page 19 of 820143
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-3Client Sample ID: A-5782 QC VEN DIV STACK MM18
IMPINGER #3 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 6110 J 6210 3110 ug/Sample 11/29/19 10:45 12/13/19 22:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2560 1160 ug/Sample 11/29/19 10:45 12/18/19 14:01 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:44 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 129 50 -200 12/04/19 10:05 12/08/19 10:44 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-4Client Sample ID: A-5783 QC VEN DIV STACK MM18
IMPINGER #4 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 30.4 4.02 ug/Sample 11/29/19 10:45 12/06/19 16:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,1,3,3-Pentafluorobutane ND
30.4 4.38 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,1-Trichloroethane ND
60.8 12.0 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,1-Trifluoro-2,2-dichloroethane ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,1-Trifluoroethane ND
30.4 5.84 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,2,2-Tetrachloroethane ND
60.8 3.41 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,2-Trichloro-1,2,2-trifluoroethane ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,2-trichloro-1-fluoroethane ND
30.4 3.16 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1,2-Trichloroethane ND
60.8 30.4 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-Dichloro-1-fluoroethane ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-dichloro-2,2-difluoroethane ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-dichloro-2,2-difluoroethene ND
30.4 3.65 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-Dichloroethane ND
30.4 4.50 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-Dichloroethene ND
30.4 3.29 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-Dichloropropene ND
608 608 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,1-Difluoroethene ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2,2-trichloro-1,1-difluoroethane ND
30.4 9.74 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2,3-Trichlorobenzene ND
30.4 7.54 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2,3-Trichloropropane ND
30.4 10.2 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2,4-Trichlorobenzene ND
30.4 6.33 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2,4-Trimethylbenzene ND
60.8 10.7 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2-Dibromo-3-Chloropropane ND
30.4 4.02 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2-Dibromoethane (EDB)ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2-dichloro-1,1-difluoroethane ND
30.4 5.35 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2-Dichlorobenzene ND
30.4 5.11 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,2-Dichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 20 of 820144
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-4Client Sample ID: A-5783 QC VEN DIV STACK MM18
IMPINGER #4 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2-Dichloropropane ND 30.4 3.04 ug/Sample 11/29/19 10:45 12/06/19 16:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.4 6.33 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,3,5-Trimethylbenzene ND
30.4 5.23 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,3-Dichlorobenzene ND
30.4 3.41 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,3-Dichloropropane ND
30.4 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 11,4-Dichlorobenzene ND
60.8 6.21 ug/Sample 11/29/19 10:45 12/06/19 16:31 11-Chloro-1,1-difluoroethane ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
30.4 8.88 ug/Sample 11/29/19 10:45 12/06/19 16:31 12,2-Dichloropropane ND
122 19.5 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-Butanone (MEK)ND
60.8 9.01 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
60.8 6.08 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-Chloro-1,1,1-Trifluoroethane ND
30.4 5.72 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-Chlorotoluene ND
122 28.0 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-Hexanone ND
26.6 26.6 ug/Sample 11/29/19 10:45 12/06/19 16:31 12-MTP as HFPO ND
30.4 6.33 ug/Sample 11/29/19 10:45 12/06/19 16:31 14-Chlorotoluene ND
30.4 8.15 ug/Sample 11/29/19 10:45 12/06/19 16:31 14-Isopropyltoluene ND
122 19.5 ug/Sample 11/29/19 10:45 12/06/19 16:31 14-Methyl-2-pentanone (MIBK)ND
122 71.8 ug/Sample 11/29/19 10:45 12/06/19 16:31 1AcetoneND
30.4 5.84 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BenzeneND
30.4 4.26 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BromobenzeneND
30.4 6.81 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BromochloromethaneND
30.4 5.23 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BromodichloromethaneND
30.4 9.25 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BromoformND
60.8 35.3 ug/Sample 11/29/19 10:45 12/06/19 16:31 1BromomethaneND
30.4 7.54 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Carbon disulfide ND
30.4 4.02 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Carbon tetrachloride ND
89.4 89.4 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Carbonyl Difluoride ND
30.4 4.38 ug/Sample 11/29/19 10:45 12/06/19 16:31 1ChlorobenzeneND
30.4 6.57 ug/Sample 11/29/19 10:45 12/06/19 16:31 1ChlorodibromomethaneND
60.8 13.4 ug/Sample 11/29/19 10:45 12/06/19 16:31 1ChloroethaneND
30.4 3.53 ug/Sample 11/29/19 10:45 12/06/19 16:31 1ChloroformND
60.8 25.3 ug/Sample 11/29/19 10:45 12/06/19 16:31 1ChloromethaneND
30.4 2.43 ug/Sample 11/29/19 10:45 12/06/19 16:31 1cis-1,2-Dichloroethene ND
30.4 5.23 ug/Sample 11/29/19 10:45 12/06/19 16:31 1cis-1,3-Dichloropropene ND
30.4 2.92 ug/Sample 11/29/19 10:45 12/06/19 16:31 1DibromomethaneND
60.8 10.7 ug/Sample 11/29/19 10:45 12/06/19 16:31 1DichlorodifluoromethaneND
30.4 4.99 ug/Sample 11/29/19 10:45 12/06/19 16:31 1EthylbenzeneND
30.4 30.4 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
30.4 8.03 ug/Sample 11/29/19 10:45 12/06/19 16:31 1HexachlorobutadieneND
29.2 29.2 ug/Sample 11/29/19 10:45 12/06/19 16:31 1HFPO dimer, methyl ester as
HFPO-DA
ND
30.4 4.26 ug/Sample 11/29/19 10:45 12/06/19 16:31 1IsopropylbenzeneND
60.8 4.99 ug/Sample 11/29/19 10:45 12/06/19 16:31 1m,p-Xylene ND
30.4 19.5 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Methylene Chloride ND
30.4 14.6 ug/Sample 11/29/19 10:45 12/06/19 16:31 1NaphthaleneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 21 of 820145
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-4Client Sample ID: A-5783 QC VEN DIV STACK MM18
IMPINGER #4 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Butylbenzene ND 30.4 7.79 ug/Sample 11/29/19 10:45 12/06/19 16:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.4 6.57 ug/Sample 11/29/19 10:45 12/06/19 16:31 1n-Propylbenzene ND
30.4 3.16 ug/Sample 11/29/19 10:45 12/06/19 16:31 1o-Xylene ND
30.4 5.96 ug/Sample 11/29/19 10:45 12/06/19 16:31 1sec-Butylbenzene ND
30.4 6.57 ug/Sample 11/29/19 10:45 12/06/19 16:31 1StyreneND
30.4 5.35 ug/Sample 11/29/19 10:45 12/06/19 16:31 1tert-Butylbenzene ND
30.4 4.02 ug/Sample 11/29/19 10:45 12/06/19 16:31 1TetrachloroetheneND
30.4 5.60 ug/Sample 11/29/19 10:45 12/06/19 16:31 1TolueneND
30.4 3.16 ug/Sample 11/29/19 10:45 12/06/19 16:31 1trans-1,2-Dichloroethene ND
30.4 10.7 ug/Sample 11/29/19 10:45 12/06/19 16:31 1trans-1,3-Dichloropropene ND
30.4 2.19 ug/Sample 11/29/19 10:45 12/06/19 16:31 1TrichloroetheneND
60.8 5.84 ug/Sample 11/29/19 10:45 12/06/19 16:31 1TrichlorofluoromethaneND *
60.8 14.6 ug/Sample 11/29/19 10:45 12/06/19 16:31 1Vinyl chloride ND
Cyclohexane 45.4 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 16:31 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)118 70 -160 11/29/19 10:45 12/06/19 16:31 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 11/29/19 10:45 12/06/19 16:31 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 16:31 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 16:31 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 4170 J 6490 3250 ug/Sample 11/29/19 10:45 12/13/19 22:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2680 1220 ug/Sample 11/29/19 10:45 12/18/19 14:21 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:47 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 126 50 -200 12/04/19 10:05 12/08/19 10:47 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-5Client Sample ID: A-5784 QC VEN DIV STACK MM18
IMPINGER #5 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 26.9 3.55 ug/Sample 11/29/19 10:45 12/06/19 16:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,1,3,3-Pentafluorobutane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 22 of 820146
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-5Client Sample ID: A-5784 QC VEN DIV STACK MM18
IMPINGER #5 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,1-Trichloroethane ND 26.9 3.87 ug/Sample 11/29/19 10:45 12/06/19 16:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
53.8 10.6 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,1-Trifluoro-2,2-dichloroethane ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,1-Trifluoroethane ND
26.9 5.16 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,2,2-Tetrachloroethane ND
53.8 3.01 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,2-Trichloro-1,2,2-trifluoroethane ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,2-trichloro-1-fluoroethane ND
26.9 2.80 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1,2-Trichloroethane ND
53.8 26.9 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-Dichloro-1-fluoroethane ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-dichloro-2,2-difluoroethane ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-dichloro-2,2-difluoroethene ND
26.9 3.23 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-Dichloroethane ND
26.9 3.98 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-Dichloroethene ND
26.9 2.90 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-Dichloropropene ND
538 538 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,1-Difluoroethene ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2,2-trichloro-1,1-difluoroethane ND
26.9 8.60 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2,3-Trichlorobenzene ND
26.9 6.67 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2,3-Trichloropropane ND
26.9 9.03 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2,4-Trichlorobenzene ND
26.9 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2,4-Trimethylbenzene ND
53.8 9.46 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-Dibromo-3-Chloropropane ND
26.9 3.55 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-Dibromoethane (EDB)ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-dichloro-1,1-difluoroethane ND
26.9 4.73 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-Dichlorobenzene ND
26.9 4.52 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-Dichloroethane ND
26.9 2.69 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,2-Dichloropropane ND
26.9 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,3,5-Trimethylbenzene ND
26.9 4.62 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,3-Dichlorobenzene ND
26.9 3.01 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,3-Dichloropropane ND
26.9 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 11,4-Dichlorobenzene ND
53.8 5.48 ug/Sample 11/29/19 10:45 12/06/19 16:55 11-Chloro-1,1-difluoroethane ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
26.9 7.85 ug/Sample 11/29/19 10:45 12/06/19 16:55 12,2-Dichloropropane ND
108 17.2 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-Butanone (MEK)ND
53.8 7.96 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
53.8 5.38 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-Chloro-1,1,1-Trifluoroethane ND
26.9 5.05 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-Chlorotoluene ND
108 24.7 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-Hexanone ND
23.5 23.5 ug/Sample 11/29/19 10:45 12/06/19 16:55 12-MTP as HFPO ND
26.9 5.59 ug/Sample 11/29/19 10:45 12/06/19 16:55 14-Chlorotoluene ND
26.9 7.20 ug/Sample 11/29/19 10:45 12/06/19 16:55 14-Isopropyltoluene ND
108 17.2 ug/Sample 11/29/19 10:45 12/06/19 16:55 14-Methyl-2-pentanone (MIBK)ND
108 63.4 ug/Sample 11/29/19 10:45 12/06/19 16:55 1AcetoneND
26.9 5.16 ug/Sample 11/29/19 10:45 12/06/19 16:55 1BenzeneND
26.9 3.76 ug/Sample 11/29/19 10:45 12/06/19 16:55 1BromobenzeneND
26.9 6.02 ug/Sample 11/29/19 10:45 12/06/19 16:55 1BromochloromethaneND
26.9 4.62 ug/Sample 11/29/19 10:45 12/06/19 16:55 1BromodichloromethaneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 23 of 820147
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-5Client Sample ID: A-5784 QC VEN DIV STACK MM18
IMPINGER #5 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Bromoform ND 26.9 8.17 ug/Sample 11/29/19 10:45 12/06/19 16:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
53.8 31.2 ug/Sample 11/29/19 10:45 12/06/19 16:55 1BromomethaneND
26.9 6.67 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Carbon disulfide ND
26.9 3.55 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Carbon tetrachloride ND
79.1 79.1 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Carbonyl Difluoride ND
26.9 3.87 ug/Sample 11/29/19 10:45 12/06/19 16:55 1ChlorobenzeneND
26.9 5.81 ug/Sample 11/29/19 10:45 12/06/19 16:55 1ChlorodibromomethaneND
53.8 11.8 ug/Sample 11/29/19 10:45 12/06/19 16:55 1ChloroethaneND
26.9 3.12 ug/Sample 11/29/19 10:45 12/06/19 16:55 1ChloroformND
53.8 22.4 ug/Sample 11/29/19 10:45 12/06/19 16:55 1ChloromethaneND
26.9 2.15 ug/Sample 11/29/19 10:45 12/06/19 16:55 1cis-1,2-Dichloroethene ND
26.9 4.62 ug/Sample 11/29/19 10:45 12/06/19 16:55 1cis-1,3-Dichloropropene ND
26.9 2.58 ug/Sample 11/29/19 10:45 12/06/19 16:55 1DibromomethaneND
53.8 9.46 ug/Sample 11/29/19 10:45 12/06/19 16:55 1DichlorodifluoromethaneND
26.9 4.41 ug/Sample 11/29/19 10:45 12/06/19 16:55 1EthylbenzeneND
26.9 26.9 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
26.9 7.10 ug/Sample 11/29/19 10:45 12/06/19 16:55 1HexachlorobutadieneND
25.8 25.8 ug/Sample 11/29/19 10:45 12/06/19 16:55 1HFPO dimer, methyl ester as
HFPO-DA
ND
26.9 3.76 ug/Sample 11/29/19 10:45 12/06/19 16:55 1IsopropylbenzeneND
53.8 4.41 ug/Sample 11/29/19 10:45 12/06/19 16:55 1m,p-Xylene ND
26.9 17.2 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Methylene Chloride ND
26.9 12.9 ug/Sample 11/29/19 10:45 12/06/19 16:55 1NaphthaleneND
26.9 6.88 ug/Sample 11/29/19 10:45 12/06/19 16:55 1n-Butylbenzene ND
26.9 5.81 ug/Sample 11/29/19 10:45 12/06/19 16:55 1n-Propylbenzene ND
26.9 2.80 ug/Sample 11/29/19 10:45 12/06/19 16:55 1o-Xylene ND
26.9 5.27 ug/Sample 11/29/19 10:45 12/06/19 16:55 1sec-Butylbenzene ND
26.9 5.81 ug/Sample 11/29/19 10:45 12/06/19 16:55 1StyreneND
26.9 4.73 ug/Sample 11/29/19 10:45 12/06/19 16:55 1tert-Butylbenzene ND
26.9 3.55 ug/Sample 11/29/19 10:45 12/06/19 16:55 1TetrachloroetheneND
26.9 4.95 ug/Sample 11/29/19 10:45 12/06/19 16:55 1TolueneND
26.9 2.80 ug/Sample 11/29/19 10:45 12/06/19 16:55 1trans-1,2-Dichloroethene ND
26.9 9.46 ug/Sample 11/29/19 10:45 12/06/19 16:55 1trans-1,3-Dichloropropene ND
26.9 1.94 ug/Sample 11/29/19 10:45 12/06/19 16:55 1TrichloroetheneND
53.8 5.16 ug/Sample 11/29/19 10:45 12/06/19 16:55 1TrichlorofluoromethaneND *
53.8 12.9 ug/Sample 11/29/19 10:45 12/06/19 16:55 1Vinyl chloride ND
Cyclohexane 43.6 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 16:55 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)118 70 -160 11/29/19 10:45 12/06/19 16:55 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:45 12/06/19 16:55 157-152
Dibromofluoromethane (Surr)103 11/29/19 10:45 12/06/19 16:55 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 16:55 171-139
Eurofins TestAmerica, Knoxville
12/23/2019Page 24 of 820148
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-5Client Sample ID: A-5784 QC VEN DIV STACK MM18
IMPINGER #5 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine ND 5730 2870 ug/Sample 11/29/19 10:45 12/13/19 23:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2370 1080 ug/Sample 11/29/19 10:45 12/18/19 14:42 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 125 50 -200 12/04/19 10:05 12/08/19 10:53 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-6Client Sample ID: A-5785 QC VEN DIV STACK MM18
IMPINGER #6 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 17:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,1,3,3-Pentafluorobutane ND
29.1 4.19 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,1-Trichloroethane ND
58.2 11.5 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,1-Trifluoro-2,2-dichloroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,1-Trifluoroethane ND
29.1 5.59 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,2,2-Tetrachloroethane ND
58.2 3.26 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,2-Trichloro-1,2,2-trifluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,2-trichloro-1-fluoroethane ND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1,2-Trichloroethane ND
58.2 29.1 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-Dichloro-1-fluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-dichloro-2,2-difluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-dichloro-2,2-difluoroethene ND
29.1 3.49 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-Dichloroethane ND
29.1 4.31 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-Dichloroethene ND
29.1 3.14 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-Dichloropropene ND
582 582 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,1-Difluoroethene ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2,2-trichloro-1,1-difluoroethane ND
29.1 9.31 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2,3-Trichlorobenzene ND
29.1 7.22 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2,3-Trichloropropane ND
29.1 9.78 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2,4-Trichlorobenzene ND
29.1 6.05 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2,4-Trimethylbenzene ND
58.2 10.2 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2-Dibromo-3-Chloropropane ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2-Dibromoethane (EDB)ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2-dichloro-1,1-difluoroethane ND
29.1 5.12 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2-Dichlorobenzene ND
29.1 4.89 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,2-Dichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 25 of 820149
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-6Client Sample ID: A-5785 QC VEN DIV STACK MM18
IMPINGER #6 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,2-Dichloropropane ND 29.1 2.91 ug/Sample 11/29/19 10:45 12/06/19 17:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.1 6.05 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,3,5-Trimethylbenzene ND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,3-Dichlorobenzene ND
29.1 3.26 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,3-Dichloropropane ND
29.1 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 11,4-Dichlorobenzene ND
58.2 5.94 ug/Sample 11/29/19 10:45 12/06/19 17:20 11-Chloro-1,1-difluoroethane ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
29.1 8.50 ug/Sample 11/29/19 10:45 12/06/19 17:20 12,2-Dichloropropane ND
116 18.6 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-Butanone (MEK)ND
58.2 8.61 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
58.2 5.82 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-Chloro-1,1,1-Trifluoroethane ND
29.1 5.47 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-Chlorotoluene ND
116 26.8 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-Hexanone ND
25.4 25.4 ug/Sample 11/29/19 10:45 12/06/19 17:20 12-MTP as HFPO ND
29.1 6.05 ug/Sample 11/29/19 10:45 12/06/19 17:20 14-Chlorotoluene ND
29.1 7.80 ug/Sample 11/29/19 10:45 12/06/19 17:20 14-Isopropyltoluene ND
116 18.6 ug/Sample 11/29/19 10:45 12/06/19 17:20 14-Methyl-2-pentanone (MIBK)ND
116 68.7 ug/Sample 11/29/19 10:45 12/06/19 17:20 1AcetoneND
29.1 5.59 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BenzeneND
29.1 4.07 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BromobenzeneND
29.1 6.52 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BromochloromethaneND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BromodichloromethaneND
29.1 8.85 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BromoformND
58.2 33.8 ug/Sample 11/29/19 10:45 12/06/19 17:20 1BromomethaneND
29.1 7.22 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Carbon disulfide ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Carbon tetrachloride ND
85.0 85.0 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Carbonyl Difluoride ND
29.1 4.19 ug/Sample 11/29/19 10:45 12/06/19 17:20 1ChlorobenzeneND
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 17:20 1ChlorodibromomethaneND
58.2 12.8 ug/Sample 11/29/19 10:45 12/06/19 17:20 1ChloroethaneND
29.1 3.38 ug/Sample 11/29/19 10:45 12/06/19 17:20 1ChloroformND
58.2 24.2 ug/Sample 11/29/19 10:45 12/06/19 17:20 1ChloromethaneND
29.1 2.33 ug/Sample 11/29/19 10:45 12/06/19 17:20 1cis-1,2-Dichloroethene ND
29.1 5.01 ug/Sample 11/29/19 10:45 12/06/19 17:20 1cis-1,3-Dichloropropene ND
29.1 2.79 ug/Sample 11/29/19 10:45 12/06/19 17:20 1DibromomethaneND
58.2 10.2 ug/Sample 11/29/19 10:45 12/06/19 17:20 1DichlorodifluoromethaneND
29.1 4.77 ug/Sample 11/29/19 10:45 12/06/19 17:20 1EthylbenzeneND
29.1 29.1 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
29.1 7.68 ug/Sample 11/29/19 10:45 12/06/19 17:20 1HexachlorobutadieneND
27.9 27.9 ug/Sample 11/29/19 10:45 12/06/19 17:20 1HFPO dimer, methyl ester as
HFPO-DA
ND
29.1 4.07 ug/Sample 11/29/19 10:45 12/06/19 17:20 1IsopropylbenzeneND
58.2 4.77 ug/Sample 11/29/19 10:45 12/06/19 17:20 1m,p-Xylene ND
29.1 18.6 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Methylene Chloride ND
29.1 14.0 ug/Sample 11/29/19 10:45 12/06/19 17:20 1NaphthaleneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 26 of 820150
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-6Client Sample ID: A-5785 QC VEN DIV STACK MM18
IMPINGER #6 BT
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
n-Butylbenzene ND 29.1 7.45 ug/Sample 11/29/19 10:45 12/06/19 17:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 17:20 1n-Propylbenzene ND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 17:20 1o-Xylene ND
29.1 5.70 ug/Sample 11/29/19 10:45 12/06/19 17:20 1sec-Butylbenzene ND
29.1 6.29 ug/Sample 11/29/19 10:45 12/06/19 17:20 1StyreneND
29.1 5.12 ug/Sample 11/29/19 10:45 12/06/19 17:20 1tert-Butylbenzene ND
29.1 3.84 ug/Sample 11/29/19 10:45 12/06/19 17:20 1TetrachloroetheneND
29.1 5.35 ug/Sample 11/29/19 10:45 12/06/19 17:20 1TolueneND
29.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 17:20 1trans-1,2-Dichloroethene ND
29.1 10.2 ug/Sample 11/29/19 10:45 12/06/19 17:20 1trans-1,3-Dichloropropene ND
29.1 2.10 ug/Sample 11/29/19 10:45 12/06/19 17:20 1TrichloroetheneND
58.2 5.59 ug/Sample 11/29/19 10:45 12/06/19 17:20 1TrichlorofluoromethaneND *
58.2 14.0 ug/Sample 11/29/19 10:45 12/06/19 17:20 1Vinyl chloride ND
Tentatively Identified Compound None ug/Sample 11/29/19 10:45 12/06/19 17:20 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)119 70 -160 11/29/19 10:45 12/06/19 17:20 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)109 11/29/19 10:45 12/06/19 17:20 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 17:20 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 17:20 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine ND 6480 3240 ug/Sample 11/29/19 10:45 12/13/19 23:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
2560 1160 ug/Sample 11/29/19 10:45 12/18/19 15:03 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 10:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 127 50 -200 12/04/19 10:05 12/08/19 10:57 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-7Client Sample ID: A-5786 QC MEOH RB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 20.3 2.68 ug/Sample 11/29/19 10:45 12/06/19 14:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,1,3,3-Pentafluorobutane ND
20.3 2.93 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,1-Trichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 27 of 820151
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-7Client Sample ID: A-5786 QC MEOH RB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1,1-Trifluoro-2,2-dichloroethane ND 40.6 8.04 ug/Sample 11/29/19 10:45 12/06/19 14:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,1-Trifluoroethane ND
20.3 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,2,2-Tetrachloroethane ND
40.6 2.28 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,2-Trichloro-1,2,2-trifluoroethane ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,2-trichloro-1-fluoroethane ND
20.3 2.11 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1,2-Trichloroethane ND
40.6 20.3 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-Dichloro-1-fluoroethane ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-dichloro-2,2-difluoroethane ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-dichloro-2,2-difluoroethene ND
20.3 2.44 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-Dichloroethane ND
20.3 3.01 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-Dichloroethene ND
20.3 2.19 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-Dichloropropene ND
406 406 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,1-Difluoroethene ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2,2-trichloro-1,1-difluoroethane ND
20.3 6.50 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2,3-Trichlorobenzene ND
20.3 5.04 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2,3-Trichloropropane ND
20.3 6.83 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2,4-Trichlorobenzene ND
20.3 4.23 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2,4-Trimethylbenzene ND
40.6 7.15 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-Dibromo-3-Chloropropane ND
20.3 2.68 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-Dibromoethane (EDB)ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-dichloro-1,1-difluoroethane ND
20.3 3.58 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-Dichlorobenzene ND
20.3 3.41 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-Dichloroethane ND
20.3 2.03 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,2-Dichloropropane ND
20.3 4.23 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,3,5-Trimethylbenzene ND
20.3 3.49 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,3-Dichlorobenzene ND
20.3 2.28 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,3-Dichloropropane ND
20.3 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 11,4-Dichlorobenzene ND
40.6 4.14 ug/Sample 11/29/19 10:45 12/06/19 14:04 11-Chloro-1,1-difluoroethane ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
20.3 5.93 ug/Sample 11/29/19 10:45 12/06/19 14:04 12,2-Dichloropropane ND
81.3 13.0 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-Butanone (MEK)ND
40.6 6.01 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
40.6 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-Chloro-1,1,1-Trifluoroethane ND
20.3 3.82 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-Chlorotoluene ND
81.3 18.7 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-Hexanone ND
17.7 17.7 ug/Sample 11/29/19 10:45 12/06/19 14:04 12-MTP as HFPO ND
20.3 4.23 ug/Sample 11/29/19 10:45 12/06/19 14:04 14-Chlorotoluene ND
20.3 5.44 ug/Sample 11/29/19 10:45 12/06/19 14:04 14-Isopropyltoluene ND
81.3 13.0 ug/Sample 11/29/19 10:45 12/06/19 14:04 14-Methyl-2-pentanone (MIBK)ND
81.3 47.9 ug/Sample 11/29/19 10:45 12/06/19 14:04 1AcetoneND
20.3 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BenzeneND
20.3 2.84 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BromobenzeneND
20.3 4.55 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BromochloromethaneND
20.3 3.49 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BromodichloromethaneND
20.3 6.18 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BromoformND
40.6 23.6 ug/Sample 11/29/19 10:45 12/06/19 14:04 1BromomethaneND
Eurofins TestAmerica, Knoxville
12/23/2019Page 28 of 820152
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-7Client Sample ID: A-5786 QC MEOH RB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Carbon disulfide ND 20.3 5.04 ug/Sample 11/29/19 10:45 12/06/19 14:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
20.3 2.68 ug/Sample 11/29/19 10:45 12/06/19 14:04 1Carbon tetrachloride ND
59.6 59.6 ug/Sample 11/29/19 10:45 12/06/19 14:04 1Carbonyl Difluoride ND
20.3 2.93 ug/Sample 11/29/19 10:45 12/06/19 14:04 1ChlorobenzeneND
20.3 4.39 ug/Sample 11/29/19 10:45 12/06/19 14:04 1ChlorodibromomethaneND
40.6 8.94 ug/Sample 11/29/19 10:45 12/06/19 14:04 1ChloroethaneND
20.3 2.36 ug/Sample 11/29/19 10:45 12/06/19 14:04 1ChloroformND
40.6 16.9 ug/Sample 11/29/19 10:45 12/06/19 14:04 1ChloromethaneND
20.3 1.63 ug/Sample 11/29/19 10:45 12/06/19 14:04 1cis-1,2-Dichloroethene ND
20.3 3.49 ug/Sample 11/29/19 10:45 12/06/19 14:04 1cis-1,3-Dichloropropene ND
20.3 1.95 ug/Sample 11/29/19 10:45 12/06/19 14:04 1DibromomethaneND
40.6 7.15 ug/Sample 11/29/19 10:45 12/06/19 14:04 1DichlorodifluoromethaneND
20.3 3.33 ug/Sample 11/29/19 10:45 12/06/19 14:04 1EthylbenzeneND
20.3 20.3 ug/Sample 11/29/19 10:45 12/06/19 14:04 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
20.3 5.36 ug/Sample 11/29/19 10:45 12/06/19 14:04 1HexachlorobutadieneND
19.5 19.5 ug/Sample 11/29/19 10:45 12/06/19 14:04 1HFPO dimer, methyl ester as
HFPO-DA
ND
20.3 2.84 ug/Sample 11/29/19 10:45 12/06/19 14:04 1IsopropylbenzeneND
40.6 3.33 ug/Sample 11/29/19 10:45 12/06/19 14:04 1m,p-Xylene ND
20.3 13.0 ug/Sample 11/29/19 10:45 12/06/19 14:04 1Methylene Chloride 13.1 J B
20.3 9.75 ug/Sample 11/29/19 10:45 12/06/19 14:04 1NaphthaleneND
20.3 5.20 ug/Sample 11/29/19 10:45 12/06/19 14:04 1n-Butylbenzene ND
20.3 4.39 ug/Sample 11/29/19 10:45 12/06/19 14:04 1n-Propylbenzene ND
20.3 2.11 ug/Sample 11/29/19 10:45 12/06/19 14:04 1o-Xylene ND
20.3 3.98 ug/Sample 11/29/19 10:45 12/06/19 14:04 1sec-Butylbenzene ND
20.3 4.39 ug/Sample 11/29/19 10:45 12/06/19 14:04 1StyreneND
20.3 3.58 ug/Sample 11/29/19 10:45 12/06/19 14:04 1tert-Butylbenzene ND
20.3 2.68 ug/Sample 11/29/19 10:45 12/06/19 14:04 1TetrachloroetheneND
20.3 3.74 ug/Sample 11/29/19 10:45 12/06/19 14:04 1TolueneND
20.3 2.11 ug/Sample 11/29/19 10:45 12/06/19 14:04 1trans-1,2-Dichloroethene ND
20.3 7.15 ug/Sample 11/29/19 10:45 12/06/19 14:04 1trans-1,3-Dichloropropene ND
20.3 1.46 ug/Sample 11/29/19 10:45 12/06/19 14:04 1TrichloroetheneND
40.6 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:04 1TrichlorofluoromethaneND *
40.6 9.75 ug/Sample 11/29/19 10:45 12/06/19 14:04 1Vinyl chloride ND
Cyclohexane 34.9 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 14:04 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)116 70 -160 11/29/19 10:45 12/06/19 14:04 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)110 11/29/19 10:45 12/06/19 14:04 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 14:04 162-134
Toluene-d8 (Surr)97 11/29/19 10:45 12/06/19 14:04 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine ND 4330 2170 ug/Sample 11/29/19 10:45 12/13/19 23:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1790 813 ug/Sample 11/29/19 10:45 12/18/19 15:24 20Hydrogen Fluoride ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 29 of 820153
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-7Client Sample ID: A-5786 QC MEOH RB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA 0.0106 J 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 11:00 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 125 50 -200 12/04/19 10:05 12/08/19 11:00 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-8Client Sample ID: A-5787 QC MEOH TB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 15.4 2.03 ug/Sample 11/29/19 10:45 12/06/19 14:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,1,3,3-Pentafluorobutane ND
15.4 2.22 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,1-Trichloroethane ND
30.8 6.09 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,1-Trifluoro-2,2-dichloroethane ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,1-Trifluoroethane ND
15.4 2.95 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,2,2-Tetrachloroethane ND
30.8 1.72 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,2-Trichloro-1,2,2-trifluoroethane ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,2-trichloro-1-fluoroethane ND
15.4 1.60 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1,2-Trichloroethane ND
30.8 15.4 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-Dichloro-1-fluoroethane ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-dichloro-2,2-difluoroethane ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-dichloro-2,2-difluoroethene ND
15.4 1.85 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-Dichloroethane ND
15.4 2.28 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-Dichloroethene ND
15.4 1.66 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-Dichloropropene ND
308 308 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,1-Difluoroethene ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2,2-trichloro-1,1-difluoroethane ND
15.4 4.92 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2,3-Trichlorobenzene ND
15.4 3.82 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2,3-Trichloropropane ND
15.4 5.17 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2,4-Trichlorobenzene ND
15.4 3.20 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2,4-Trimethylbenzene ND
30.8 5.42 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-Dibromo-3-Chloropropane ND
15.4 2.03 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-Dibromoethane (EDB)ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-dichloro-1,1-difluoroethane ND
15.4 2.71 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-Dichlorobenzene ND
15.4 2.59 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-Dichloroethane ND
15.4 1.54 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,2-Dichloropropane ND
15.4 3.20 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,3,5-Trimethylbenzene ND
15.4 2.65 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,3-Dichlorobenzene ND
15.4 1.72 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,3-Dichloropropane ND
15.4 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 11,4-Dichlorobenzene ND
30.8 3.14 ug/Sample 11/29/19 10:45 12/06/19 14:28 11-Chloro-1,1-difluoroethane ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 30 of 820154
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-8Client Sample ID: A-5787 QC MEOH TB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
2,2-Dichloropropane ND 15.4 4.49 ug/Sample 11/29/19 10:45 12/06/19 14:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
61.6 9.85 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-Butanone (MEK)ND
30.8 4.55 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
30.8 3.08 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-Chloro-1,1,1-Trifluoroethane ND
15.4 2.89 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-Chlorotoluene ND
61.6 14.2 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-Hexanone ND
13.5 13.5 ug/Sample 11/29/19 10:45 12/06/19 14:28 12-MTP as HFPO ND
15.4 3.20 ug/Sample 11/29/19 10:45 12/06/19 14:28 14-Chlorotoluene ND
15.4 4.12 ug/Sample 11/29/19 10:45 12/06/19 14:28 14-Isopropyltoluene ND
61.6 9.85 ug/Sample 11/29/19 10:45 12/06/19 14:28 14-Methyl-2-pentanone (MIBK)ND
61.6 36.3 ug/Sample 11/29/19 10:45 12/06/19 14:28 1AcetoneND
15.4 2.95 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BenzeneND
15.4 2.15 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BromobenzeneND
15.4 3.45 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BromochloromethaneND
15.4 2.65 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BromodichloromethaneND
15.4 4.68 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BromoformND
30.8 17.8 ug/Sample 11/29/19 10:45 12/06/19 14:28 1BromomethaneND
15.4 3.82 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Carbon disulfide ND
15.4 2.03 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Carbon tetrachloride ND
45.1 45.1 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Carbonyl Difluoride ND
15.4 2.22 ug/Sample 11/29/19 10:45 12/06/19 14:28 1ChlorobenzeneND
15.4 3.32 ug/Sample 11/29/19 10:45 12/06/19 14:28 1ChlorodibromomethaneND
30.8 6.77 ug/Sample 11/29/19 10:45 12/06/19 14:28 1ChloroethaneND
15.4 1.78 ug/Sample 11/29/19 10:45 12/06/19 14:28 1ChloroformND
30.8 12.8 ug/Sample 11/29/19 10:45 12/06/19 14:28 1ChloromethaneND
15.4 1.23 ug/Sample 11/29/19 10:45 12/06/19 14:28 1cis-1,2-Dichloroethene ND
15.4 2.65 ug/Sample 11/29/19 10:45 12/06/19 14:28 1cis-1,3-Dichloropropene ND
15.4 1.48 ug/Sample 11/29/19 10:45 12/06/19 14:28 1DibromomethaneND
30.8 5.42 ug/Sample 11/29/19 10:45 12/06/19 14:28 1DichlorodifluoromethaneND
15.4 2.52 ug/Sample 11/29/19 10:45 12/06/19 14:28 1EthylbenzeneND
15.4 15.4 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
15.4 4.06 ug/Sample 11/29/19 10:45 12/06/19 14:28 1HexachlorobutadieneND
14.8 14.8 ug/Sample 11/29/19 10:45 12/06/19 14:28 1HFPO dimer, methyl ester as
HFPO-DA
ND
15.4 2.15 ug/Sample 11/29/19 10:45 12/06/19 14:28 1IsopropylbenzeneND
30.8 2.52 ug/Sample 11/29/19 10:45 12/06/19 14:28 1m,p-Xylene ND
15.4 9.85 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Methylene Chloride 10.1 J B
15.4 7.39 ug/Sample 11/29/19 10:45 12/06/19 14:28 1NaphthaleneND
15.4 3.94 ug/Sample 11/29/19 10:45 12/06/19 14:28 1n-Butylbenzene ND
15.4 3.32 ug/Sample 11/29/19 10:45 12/06/19 14:28 1n-Propylbenzene ND
15.4 1.60 ug/Sample 11/29/19 10:45 12/06/19 14:28 1o-Xylene ND
15.4 3.02 ug/Sample 11/29/19 10:45 12/06/19 14:28 1sec-Butylbenzene ND
15.4 3.32 ug/Sample 11/29/19 10:45 12/06/19 14:28 1StyreneND
15.4 2.71 ug/Sample 11/29/19 10:45 12/06/19 14:28 1tert-Butylbenzene ND
15.4 2.03 ug/Sample 11/29/19 10:45 12/06/19 14:28 1TetrachloroetheneND
15.4 2.83 ug/Sample 11/29/19 10:45 12/06/19 14:28 1TolueneND
15.4 1.60 ug/Sample 11/29/19 10:45 12/06/19 14:28 1trans-1,2-Dichloroethene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 31 of 820155
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-8Client Sample ID: A-5787 QC MEOH TB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
trans-1,3-Dichloropropene ND 15.4 5.42 ug/Sample 11/29/19 10:45 12/06/19 14:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
15.4 1.11 ug/Sample 11/29/19 10:45 12/06/19 14:28 1TrichloroetheneND
30.8 2.95 ug/Sample 11/29/19 10:45 12/06/19 14:28 1TrichlorofluoromethaneND *
30.8 7.39 ug/Sample 11/29/19 10:45 12/06/19 14:28 1Vinyl chloride ND
Cyclohexane 41.7 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 14:28 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)119 70 -160 11/29/19 10:45 12/06/19 14:28 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)111 11/29/19 10:45 12/06/19 14:28 157-152
Dibromofluoromethane (Surr)105 11/29/19 10:45 12/06/19 14:28 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 14:28 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 9720 3280 1640 ug/Sample 11/29/19 10:45 12/14/19 00:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1350 616 ug/Sample 11/29/19 10:45 12/19/19 09:19 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 11:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 125 50 -200 12/04/19 10:05 12/08/19 11:03 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Lab Sample ID: 140-17462-9Client Sample ID: A-5788 QC MEOH PB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS)
RL MDL
1,1,1,2-Tetrachloroethane ND 18.1 2.38 ug/Sample 11/29/19 10:45 12/06/19 14:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,1,3,3-Pentafluorobutane ND
18.1 2.60 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,1-Trichloroethane ND
36.1 7.15 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,1-Trifluoro-2,2-dichloroethane ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,1-Trifluoroethane ND
18.1 3.47 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,2,2-Tetrachloroethane ND
36.1 2.02 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,2-Trichloro-1,2,2-trifluoroethane ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,2-trichloro-1-fluoroethane ND
18.1 1.88 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1,2-Trichloroethane ND
36.1 18.1 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-Dichloro-1-fluoroethane ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-dichloro-2,2-difluoroethane ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-dichloro-2,2-difluoroethene ND
18.1 2.17 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-Dichloroethane ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 32 of 820156
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-9Client Sample ID: A-5788 QC MEOH PB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
1,1-Dichloroethene ND 18.1 2.67 ug/Sample 11/29/19 10:45 12/06/19 14:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
18.1 1.95 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-Dichloropropene ND
361 361 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,1-Difluoroethene ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2,2-trichloro-1,1-difluoroethane ND
18.1 5.78 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2,3-Trichlorobenzene ND
18.1 4.48 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2,3-Trichloropropane ND
18.1 6.07 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2,4-Trichlorobenzene ND
18.1 3.75 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2,4-Trimethylbenzene ND
36.1 6.35 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-Dibromo-3-Chloropropane ND
18.1 2.38 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-Dibromoethane (EDB)ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-dichloro-1,1-difluoroethane ND
18.1 3.18 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-Dichlorobenzene ND
18.1 3.03 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-Dichloroethane ND
18.1 1.81 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,2-Dichloropropane ND
18.1 3.75 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,3,5-Trimethylbenzene ND
18.1 3.11 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,3-Dichlorobenzene ND
18.1 2.02 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,3-Dichloropropane ND
18.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 11,4-Dichlorobenzene ND
36.1 3.68 ug/Sample 11/29/19 10:45 12/06/19 14:53 11-Chloro-1,1-difluoroethane ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 12,2-dichloro-1,1-difluoroethylmethyl
ether
ND
18.1 5.27 ug/Sample 11/29/19 10:45 12/06/19 14:53 12,2-Dichloropropane ND
72.2 11.6 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-Butanone (MEK)ND
36.1 5.34 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-chloro-1,1,1,4,4,4-hexafluoro-2-but
ene
ND
36.1 3.61 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-Chloro-1,1,1-Trifluoroethane ND
18.1 3.39 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-Chlorotoluene ND
72.2 16.6 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-Hexanone ND
15.8 15.8 ug/Sample 11/29/19 10:45 12/06/19 14:53 12-MTP as HFPO ND
18.1 3.75 ug/Sample 11/29/19 10:45 12/06/19 14:53 14-Chlorotoluene ND
18.1 4.84 ug/Sample 11/29/19 10:45 12/06/19 14:53 14-Isopropyltoluene ND
72.2 11.6 ug/Sample 11/29/19 10:45 12/06/19 14:53 14-Methyl-2-pentanone (MIBK)ND
72.2 42.6 ug/Sample 11/29/19 10:45 12/06/19 14:53 1AcetoneND
18.1 3.47 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BenzeneND
18.1 2.53 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BromobenzeneND
18.1 4.04 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BromochloromethaneND
18.1 3.11 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BromodichloromethaneND
18.1 5.49 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BromoformND
36.1 20.9 ug/Sample 11/29/19 10:45 12/06/19 14:53 1BromomethaneND
18.1 4.48 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Carbon disulfide ND
18.1 2.38 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Carbon tetrachloride ND
52.9 52.9 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Carbonyl Difluoride ND
18.1 2.60 ug/Sample 11/29/19 10:45 12/06/19 14:53 1ChlorobenzeneND
18.1 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:53 1ChlorodibromomethaneND
36.1 7.94 ug/Sample 11/29/19 10:45 12/06/19 14:53 1ChloroethaneND
18.1 2.09 ug/Sample 11/29/19 10:45 12/06/19 14:53 1ChloroformND
36.1 15.0 ug/Sample 11/29/19 10:45 12/06/19 14:53 1ChloromethaneND
18.1 1.44 ug/Sample 11/29/19 10:45 12/06/19 14:53 1cis-1,2-Dichloroethene ND
18.1 3.11 ug/Sample 11/29/19 10:45 12/06/19 14:53 1cis-1,3-Dichloropropene ND
Eurofins TestAmerica, Knoxville
12/23/2019Page 33 of 820157
Client Sample Results
Job ID: 140-17462-1Client: Chemours Company FC, LLC The
Project/Site: VEN MM-18 Field QC
Lab Sample ID: 140-17462-9Client Sample ID: A-5788 QC MEOH PB
Matrix: AirDate Collected: 11/22/19 00:00
Date Received: 11/25/19 08:00
Sample Container: Plastic 250ml - unpreserved
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
RL MDL
Dibromomethane ND 18.1 1.73 ug/Sample 11/29/19 10:45 12/06/19 14:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
36.1 6.35 ug/Sample 11/29/19 10:45 12/06/19 14:53 1DichlorodifluoromethaneND
18.1 2.96 ug/Sample 11/29/19 10:45 12/06/19 14:53 1EthylbenzeneND
18.1 18.1 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Heptafluoropropyl
1,2,2,2-tetrafluoroethyl ether
ND
18.1 4.77 ug/Sample 11/29/19 10:45 12/06/19 14:53 1HexachlorobutadieneND
17.4 17.4 ug/Sample 11/29/19 10:45 12/06/19 14:53 1HFPO dimer, methyl ester as
HFPO-DA
ND
18.1 2.53 ug/Sample 11/29/19 10:45 12/06/19 14:53 1IsopropylbenzeneND
36.1 2.96 ug/Sample 11/29/19 10:45 12/06/19 14:53 1m,p-Xylene ND
18.1 11.6 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Methylene Chloride 13.6 J B
18.1 8.67 ug/Sample 11/29/19 10:45 12/06/19 14:53 1NaphthaleneND
18.1 4.62 ug/Sample 11/29/19 10:45 12/06/19 14:53 1n-Butylbenzene ND
18.1 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:53 1n-Propylbenzene ND
18.1 1.88 ug/Sample 11/29/19 10:45 12/06/19 14:53 1o-Xylene ND
18.1 3.54 ug/Sample 11/29/19 10:45 12/06/19 14:53 1sec-Butylbenzene ND
18.1 3.90 ug/Sample 11/29/19 10:45 12/06/19 14:53 1StyreneND
18.1 3.18 ug/Sample 11/29/19 10:45 12/06/19 14:53 1tert-Butylbenzene ND
18.1 2.38 ug/Sample 11/29/19 10:45 12/06/19 14:53 1TetrachloroetheneND
18.1 3.32 ug/Sample 11/29/19 10:45 12/06/19 14:53 1TolueneND
18.1 1.88 ug/Sample 11/29/19 10:45 12/06/19 14:53 1trans-1,2-Dichloroethene ND
18.1 6.35 ug/Sample 11/29/19 10:45 12/06/19 14:53 1trans-1,3-Dichloropropene ND
18.1 1.30 ug/Sample 11/29/19 10:45 12/06/19 14:53 1TrichloroetheneND
36.1 3.47 ug/Sample 11/29/19 10:45 12/06/19 14:53 1TrichlorofluoromethaneND *
36.1 8.67 ug/Sample 11/29/19 10:45 12/06/19 14:53 1Vinyl chloride ND
Cyclohexane 28.0 T J N ug/Sample 4.42 110-82-7 11/29/19 10:45 12/06/19 14:53 1
Tentatively Identified Compound Dil FacAnalyzedPreparedUnit DQualifierEst. Result CAS No.RT
1,2-Dichloroethane-d4 (Surr)117 70 -160 11/29/19 10:45 12/06/19 14:53 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
4-Bromofluorobenzene (Surr)108 11/29/19 10:45 12/06/19 14:53 157-152
Dibromofluoromethane (Surr)104 11/29/19 10:45 12/06/19 14:53 162-134
Toluene-d8 (Surr)96 11/29/19 10:45 12/06/19 14:53 171-139
Method: 9056 - Anions, Ion Chromatography
RL MDL
Total Fluorine 2450 J 3850 1930 ug/Sample 11/29/19 10:45 12/14/19 00:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
1590 722 ug/Sample 11/29/19 10:45 12/19/19 09:40 20Hydrogen Fluoride ND
Method: 8321A - PFOA and PFOS
RL MDL
HFPO-DA ND 0.0250 0.00500 ug/Sample 12/04/19 10:05 12/08/19 11:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
13C3 HFPO-DA 131 50 -200 12/04/19 10:05 12/08/19 11:06 1
Surrogate Dil FacAnalyzedPreparedQualifier Limits%Recovery
General Chemistry
RL MDL
pH 4.00 HF SU 12/13/19 15:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Knoxville
12/23/2019Page 34 of 820158
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17462-1
Project/Site: VEN MM-18 Field QC
Method: 8260B - Volatile Organic Compounds (GC/MS)
Prep: MeOH Prep
2.501,1,1,2-Tetrachloroethane ug/Sample
Analyte UnitsMDLRL
0.330
5.001,1,1,3,3-Pentafluorobutane ug/Sample0.500
2.501,1,1-Trichloroethane ug/Sample0.360
5.001,1,1-Trifluoro-2,2-dichloroethane ug/Sample0.990
5.001,1,1-Trifluoroethane ug/Sample0.500
2.501,1,2,2-Tetrachloroethane ug/Sample0.480
5.001,1,2-Trichloro-1,2,2-trifluoroethane ug/Sample0.280
5.001,1,2-trichloro-1-fluoroethane ug/Sample0.500
2.501,1,2-Trichloroethane ug/Sample0.260
5.001,1-Dichloro-1-fluoroethane ug/Sample2.50
5.001,1-dichloro-2,2-difluoroethane ug/Sample0.500
5.001,1-dichloro-2,2-difluoroethene ug/Sample0.500
2.501,1-Dichloroethane ug/Sample0.300
2.501,1-Dichloroethene ug/Sample0.370
2.501,1-Dichloropropene ug/Sample0.270
50.01,1-Difluoroethene ug/Sample50.0
5.001,2,2-trichloro-1,1-difluoroethane ug/Sample0.500
2.501,2,3-Trichlorobenzene ug/Sample0.800
2.501,2,3-Trichloropropane ug/Sample0.620
2.501,2,4-Trichlorobenzene ug/Sample0.840
2.501,2,4-Trimethylbenzene ug/Sample0.520
5.001,2-Dibromo-3-Chloropropane ug/Sample0.880
2.501,2-Dibromoethane (EDB)ug/Sample0.330
5.001,2-dichloro-1,1-difluoroethane ug/Sample0.500
2.501,2-Dichlorobenzene ug/Sample0.440
2.501,2-Dichloroethane ug/Sample0.420
2.501,2-Dichloropropane ug/Sample0.250
2.501,3,5-Trimethylbenzene ug/Sample0.520
2.501,3-Dichlorobenzene ug/Sample0.430
2.501,3-Dichloropropane ug/Sample0.280
2.501,4-Dichlorobenzene ug/Sample0.500
5.001-Chloro-1,1-difluoroethane ug/Sample0.510
5.002,2-dichloro-1,1-difluoroethylmethyl ether ug/Sample0.500
2.502,2-Dichloropropane ug/Sample0.730
10.02-Butanone (MEK)ug/Sample1.60
5.002-chloro-1,1,1,4,4,4-hexafluoro-2-butene ug/Sample0.740
5.002-Chloro-1,1,1-Trifluoroethane ug/Sample0.500
2.502-Chlorotoluene ug/Sample0.470
10.02-Hexanone ug/Sample2.30
2.502-MTP as HFPO ug/Sample2.50
2.504-Chlorotoluene ug/Sample0.520
2.504-Isopropyltoluene ug/Sample0.670
10.04-Methyl-2-pentanone (MIBK)ug/Sample1.60
10.0Acetone ug/Sample5.90
2.50Benzene ug/Sample0.480
2.50Bromobenzene ug/Sample0.350
2.50Bromochloromethane ug/Sample0.560
2.50Bromodichloromethane ug/Sample0.430
2.50Bromoform ug/Sample0.760
5.00Bromomethane ug/Sample2.90
2.50Carbon disulfide ug/Sample0.620
2.50Carbon tetrachloride ug/Sample0.330
Eurofins TestAmerica, Knoxville
12/23/2019Page 35 of 820159
Default Detection Limits
Client: Chemours Company FC, LLC The Job ID: 140-17462-1
Project/Site: VEN MM-18 Field QC
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Prep: MeOH Prep
10.0Carbonyl Difluoride ug/Sample
Analyte UnitsMDLRL
10.0
2.50Chlorobenzene ug/Sample0.360
2.50Chlorodibromomethane ug/Sample0.540
5.00Chloroethane ug/Sample1.10
2.50Chloroform ug/Sample0.290
5.00Chloromethane ug/Sample2.08
2.50cis-1,2-Dichloroethene ug/Sample0.200
2.50cis-1,3-Dichloropropene ug/Sample0.430
2.50Dibromomethane ug/Sample0.240
5.00Dichlorodifluoromethane ug/Sample0.880
2.50Ethylbenzene ug/Sample0.410
2.50Heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether ug/Sample2.50
2.50Hexachlorobutadiene ug/Sample0.660
2.50HFPO dimer, methyl ester as HFPO-DA ug/Sample2.50
2.50Isopropylbenzene ug/Sample0.350
5.00m,p-Xylene ug/Sample0.410
2.50Methylene Chloride ug/Sample1.60
2.50Naphthalene ug/Sample1.20
2.50n-Butylbenzene ug/Sample0.640
2.50n-Propylbenzene ug/Sample0.540
2.50o-Xylene ug/Sample0.260
2.50sec-Butylbenzene ug/Sample0.490
2.50Styrene ug/Sample0.540
2.50tert-Butylbenzene ug/Sample0.440
2.50Tetrachloroethene ug/Sample0.330
2.50Toluene ug/Sample0.460
2.50trans-1,2-Dichloroethene ug/Sample0.260
2.50trans-1,3-Dichloropropene ug/Sample0.880
2.50Trichloroethene ug/Sample0.180
5.00Trichlorofluoromethane ug/Sample0.480
5.00Vinyl chloride ug/Sample1.20
Method: 9056 - Anions, Ion Chromatography
Prep: MeOH Prep
11.0Hydrogen Fluoride ug/Sample
Analyte UnitsMDLRL
5.00
1000Total Fluorine ug/Sample500
Method: 8321A - PFOA and PFOS
Prep: None
0.100HFPO-DA ug/Sample
Analyte UnitsMDLRL
0.0200
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12/23/2019Page 36 of 820160

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX D
SAMPLE CALCULATIONS

161
12/31/201911:01 AM 112219 Div Stack M0010
EXAMPLE CALCULATIONS FOR
VOLUMETRIC FLOW AND MOISTURE AND ISOKINETICS
Client: Chemours Facility: Fayetteville, NC
Test Number: Run 1 Test Date: 11/22/19
Test Location: Division Stack Test Period: 0826-1022
1. Volume of dry gas sampled at standard conditions (68 deg F, 29.92 in. Hg), dscf.
delta H
17.64 x Y x Vm x ( Pb + ------------ )
13.6
Vm(std)=--------------------------------------------
(Tm + 460)
1.403
17.64 x 0.9972 x 63.136 x ( 30.02 + --------------------- )
13.6
Vm(std)=------------------------------------------------------------ = 64.704
57.04 + 460
Where:
Vm(std)=Volume of gas sample measured by the dry gas meter,
corrected to standard conditions, dscf.
Vm =Volume of gas sample measured by the dry gas meter
at meter conditions, dcf.
Pb =Barometric Pressure, in Hg.
delt H =Average pressure drop across the orifice meter, in H2O
Tm =Average dry gas meter temperature , deg F.
Y =Dry gas meter calibration factor.
17.64 =Factor that includes ratio of standard temperature (528 deg R)
to standard pressure (29.92 in. Hg), deg R/in. Hg.
13.6 =Specific gravity of mercury.
2. Volume of water vapor in the gas sample corrected to standard conditions, scf.
Vw(std)=(0.04707 x Vwc) + (0.04715 x Wwsg)
Vw(std)=( 0.04707 x 10.0 ) + ( 0.04715 x 24.4 ) = 1.62
Where:
Vw(std)=Volume of water vapor in the gas sample corrected to
standard conditions, scf.
Vwc =Volume of liquid condensed in impingers, ml.
Wwsg =Weight of water vapor collected in silica gel, g.
0.04707 =Factor which includes the density of water
(0.002201 lb/ml), the molecular weight of water
(18.0 lb/lb-mole), the ideal gas constant
21.85 (in. Hg) (ft3)/lb-mole)(deg R); absolute
temperature at standard conditions (528 deg R), absolute
pressure at standard conditions (29.92 in. Hg), ft3/ml.
0.04715 =Factor which includes the molecular weight of water
(18.0 lb/lb-mole), the ideal gas constant
21.85 (in. Hg) (ft3)/lb-mole)(deg R); absolute
temperature at standard conditions (528 deg R), absolute
pressure at standard conditions (29.92 in. Hg), and
453.6 g/lb, ft3/g.
162
12/31/201911:01 AM 112219 Div Stack M0010
3. Moisture content
Vw(std)
bws =-------------------------
Vw(std) + Vm(std)
1.62
bws =------------------------- = 0.024
1.62 + 64.704
Where:
bws =Proportion of water vapor, by volume, in the gas
stream, dimensionless.
4. Mole fraction of dry gas.
Md =1 - bws
Md =1 - 0.024 = 0.976
Where:
Md =Mole fraction of dry gas, dimensionless.
5. Dry molecular weight of gas stream, lb/lb-mole.
MWd =( 0.440 x % CO2 ) + ( 0.320 x % O2 ) + ( 0.280 x (% N2 + % CO) )
MWd =( 0.440 x 0.0 ) + ( 0.320 x 20.9 ) + (0.280 x ( 79.1 + 0.00 ))
MWd =28.84
Where:
MWd =Dry molecular weight , lb/lb-mole.
% CO2 =Percent carbon dioxide by volume, dry basis.
% O2 =Percent oxygen by volume, dry basis.
% N2 =Percent nitrogen by volume, dry basis.
% CO =Percent carbon monoxide by volume, dry basis.
0.440 =Molecular weight of carbon dioxide, divided by 100.
0.320 =Molecular weight of oxygen, divided by 100.
0.280 =Molecular weight of nitrogen or carbon monoxide,
divided by 100.
6. Actual molecular weight of gas stream (wet basis), lb/lb-mole.
MWs =( MWd x Md ) + ( 18 x ( 1 - Md ))
MWs =( 28.84 x 0.976 ) +( 18 ( 1 - 0.976 )) = 28.57
Where:
MWs =Molecular weight of wet gas, lb/lb-mole.
18 =Molecular weight of water, lb/lb-mole.
163
12/31/201911:01 AM 112219 Div Stack M0010
7. Average velocity of gas stream at actual conditions, ft/sec.
Ts (avg)
Vs =85.49 x Cp x ((delt p)1/2)avg x ( ---------------- )1/2
Ps x MWs
532
Vs =85.49 x 0.84 x 1.45039 x ( -------------------- )^1/2 = 82.0
29.99 x 28.57
Where:
Vs =Average gas stream velocity, ft/sec.
(lb/lb-mole)(in. Hg)1/2
85.49 =Pitot tube constant, ft/sec x ------------------------------------
(deg R)(in H2O)
Cp =Pitot tube coefficient, dimensionless.
Ts =Absolute gas stream temperature, deg R = Ts, deg F + 460.
P(static)
Ps =Absolute gas stack pressure, in. Hg. = Pb + --------------
13.6
delt p =Velocity head of stack, in. H2O.
8. Average gas stream volumetric flow rate at actual conditions, wacf/min.
Qs(act)=60 x Vs x As
Qs(act)=60 x 82.0 x 7.07 = 34799
Where:
Qs(act)=Volumetric flow rate of wet stack gas at actual
conditions, wacf/min.
As =Cross-sectional area of stack, ft2.
60 =Conversion factor from seconds to minutes.
9. Average gas stream dry volumetric flow rate at standard conditions, dscf/min.
Ps
Qs(std)= 17.64 x Md x ----- x Qs(act)
Ts
29.99
Qs(std)=17.64 x 0.976 x -------------------- x 34799
531.6
Qs(std)=33787
Where:
Qs(std)=Volumetric flow rate of dry stack gas at standard
conditions, dscf/min.
164
12/31/201911:01 AM 112219 Div Stack M0010
10. Isokinetic variation calculated from intermediate values, percent.
17.327 x Ts x Vm(std)
I =-----------------------------------
Vs x O x Ps x Md x (Dn)2
17.327 x 532 x 64.704
I =-------------------------------------------------- = 101.0
82.0 x 96 x 29.99 x 0.976 x (0.160)^2
Where:
I =Percent of isokinetic sampling.
O =Total sampling time, minutes.
Dn =Diameter of nozzle, inches.
17.327 =Factor which includes standard temperature (528 deg R),
standard pressure (29.92 in. Hg), the formula for
calculating area of circle D2/4, conversion of square
feet to square inches (144), conversion of seconds
to minutes (60), and conversion to percent (100),
(in. Hg)(in2)(min)
(deg R)(ft2)(sec)
165
1/3/202012:18 PM 112219 Div Stack M0010
SAMPLE CALCULATIONS FOR
HFPO DIMER ACID (METHOD 0010)
Client: Chemours Plant: Fayetteville, NC
Test Number: Run 1 Test Date: 11/22/19
Test Location: Divison Stack Test Period: 0826-1022
1. HFPO Dimer Acid concentration, lbs/dscf.
W x 2.2046 x 10-9
Conc1 =------------------------------
Vm(std)
22.3 x 2.2046 x 10-9
Conc1 =------------------------------
64.704
Conc1 =7.60E-10
Where:
W =Weight of HFPO Dimer Acid collected in sample in ug.
Conc1 =Division Stack HFPO Dimer Acid concentration, lbs/dscf.
2.2046x10-9 =Conversion factor from ug to lbs.
2. HFPO Dimer Acid concentration, ug/dscm.
Conc2 =W / ( Vm(std) x 0.02832)
Conc2 =22.3 / ( 64.704 x 0.02832 )
Conc2 =1.22E+01
Where:
Conc2 =Division Stack HFPO Dimer Acid concentration, ug/dscm.
0.02832 =Conversion factor from cubic feet to cubic meters.
166
1/3/202012:18 PM 112219 Div Stack M0010
3. HFPO Dimer Acid mass emission rate, lbs/hr.
MR1(Outlet)=Conc1 x Qs(std) x 60 min/hr
MR1(Outlet)=7.60E-10 x 33787 x 60
MR1(Outlet)=1.54E-03
Where:
MR1(Outlet)=Division Stack HFPO Dimer Acid mass emission rate, lbs/hr.
4. HFPO Dimer Acid mass emission rate, g/sec.
MR2(Outlet)=PMR1 x 453.59 / 3600
MR2(Outlet)=1.54E-03 x 453.59 /3600
MR2(Outlet)=1.94E-04
Where:
MR2(Outlet)=Division Stack HFPO Dimer Acid mass emission rate, g/sec.
453.6 =Conversion factor from pounds to grams.
3600 =Conversion factor from hours to seconds.
167

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX E
EQUIPMENT CALIBRATION RECORDS

168
P-694 all in one.MOD
Pitot Tube Identification Number:
Inspection Date 2/19/19 Individual Conducting Inspection
Distance to A Plane (PA) - inches 0.46 PASS
Distance to B Plane (PB) - inches 0.46 PASS
Pitot OD (Dt) - inches 0.375
1.05 Dt < P < 1.5 Dt PA must Equal PB
Q1 and Q2 must be < 10o
B1 or B2 must be < 5o
Z must be < 0.125 inches
W must be < 0.03125 inches
X must be > 0.75 inches
Thermocouple meets
the Distance Criteria
in the adjacent figure
Impact Pressure
Opening Plane is
above the Nozzle
Entry Plane
NO
NA
NO
NA
PASS
PASS
PASS
Distance between Sample
Nozzle and Pitot (X) - inches
Thermocouple meets
the Distance Criteria
in the adjacent figure
YES
YES
PASS
NO YES
NA
0
0
Angle of B1 from
vertical A Tube-
degrees (absolute)0
0
0.8
Horizontal offset between A and
B Tubes (Z) - inches
Vertical offset between A and B
Tubes (W) - inches
0.004
0.015
PASS/FAIL
Angle of B1 from
vertical B Tube-
degrees (absolute)
PASS
PASS
PASS
P-694
ks
Angle of Q1 from vertical A Tube-
degrees (absolute)
Angle of Q2 from vertical B Tube-
degrees (absolute)
Type S Pitot Tube Inspection Data Form
Are Open Faces Aligned
Perpendicular to the Tube Axis YES NO PASS
If all Criteria PASS
Cp is equal to 0.84
Sample Probe
Type S Pitot Tube
Temperature Sensor
Dt
2 inch
Sample Probe
Temperature Sensor
Dt Type S Pitot Tube
3 inch
3/4 inch
A B
Face Opening Planes
A
B A B
Q1 Q1 Q2
B B
B
A A
A
FlowFlow
B1(+)B1(-)
B2(+ or -)
B1(+ or -)
B-Side Plane
AB
PA
PB
A-Side PlaneDt
X
Sampling D
Impact Pressure Opening Plane
Nozzle Entry Plane
W
B
A
B
A
Z
169
Long Cal Box_30 2-21-19
Calibrator MDW Meter Box Number 30 Ambient Temp 72
Date 21-Feb-19 Wet Test Meter Number P-2952 Temp Reference Source
Dry Gas Meter Number 17485131
Setting
in H20
(∆H)
ft3
(Vw)
ft3
(Vd)
oF
(Tw)
Outlet, oF
(Tdo)
Inlet, oF
(Tdi)
Average, oF
(Td)
Time, min
(O)Y ∆H
905.750 70.00 70.00
910.724 70.00 70.00
4.974 70.00 70.00
911.701 71.00 71.00
916.685 71.00 71.00
4.984 71.00 71.00
917.680 72.00 72.00
927.695 74.00 74.00
10.015 73.00 73.00
928.690 74.00 74.00938.780 75.00 75.00
10.090 74.50 74.50
939.800 76.00 76.00
949.930 77.00 77.00
10.130 76.50 76.50
Average 0.9972 1.8715
Vw - Gas Volume passing through the wet test meter 0 - Time of calibration run
Vd - Gas Volume passing through the dry gas meter Pb - Barometric Pressure
Tw - Temp of gas in the wet test meter
Tdi - Temp of the inlet gas of the dry gas meter
Tdo - Temp of the outlet gas of the dry gas meter
Td - Average temp of the gas in the dry gas meter

1 2 3 4 5 6
32 32 32 32 32 32.0 0.0%
212 213 213 212 212 212.4 -0.1%
932 933 933 932 932 932.4 0.0%
1832 1832 1832 1832 1832 1832.0 0.0%
1 - Channel Temps must agree with +/- 5oF or 3oC
2 - Acceptable Temperature Difference less than 1.5 %
2.0 10.0
1.850112.8 1.0002
Dry Gas Meter
70.0
0.5 70.0
1.0
Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console
Orifice
Manometer
Wet Test
Meter Dry gas Meter
Gas Volume
1.82245.0 70.0 70.0 9.0
Y - Ratio of accuracy of wet test
meter to dry gas meter
∆H - Pressure differential across
orifice
3.0 10.0 70.0
Temperatures
Wet Test
Meter
68.0
1.5 10.0
1.0007
5.0
70.0
10.7 0.9910
72.5
74.5
1.8894
1.885113.0 0.9946
15.0 0.9995
932
1832
Reference
Temperature
Select Temperature
oC oF
212
32
Average
Temperature
Reading
Thermocouple Simulator
(Accuracy +/- 1oF)
Temp
Difference 2
(%)
Temperature Reading from Individual Thermocouple Input 1
Channel Number
1.9103
Calibration Results
Baro Press, in
Hg ( Pb)29.87
76.0
( )( )
( )
( )
2
Vw
O460tw
460tdPb
H0317.0H
460tw6.13
HPbVd
)460td(PbVwY


∗+∗


+∗
∆∗=∆
+∗

∆+∗
+∗∗=
( )()( )()( )



+
+−+=460FTempferenceRe
460FTempTest460FTempferenceReDiffTempo
oo
170
Y Factor Calibration Check Calculation
MODIFIED METHOD 0010 TEST TRAIN
DIVISION STACK
METER BOX NO. 30
11/22/2019
Run 1 Run 2MWd = Dry molecular weight source gas, lb/lb-mole.
0.32 = Molecular weight of oxygen, divided by 100.
0.44 = Molecular weight of carbon dioxide, divided by 100.
0.28 = Molecular weight of nitrogen or carbon monoxide, divided by 100.
% CO2 = Percent carbon dioxide by volume, dry basis.0.0 0.0
% O2 = Percent oxygen by volume, dry basis.20.9 20.9
MWd = ( 0.32 * O2 ) + ( 0.44 * CO2 ) + ( 0.28 * ( 100 - ( CO2 + O2 )))
MWd = ( 0.32 * 20.9 ) + ( 0.44 * 0 ) + ( 0.28 * ( 100 - ( 0 + 20.9 )))
MWd = ( 6.69 ) + ( 0.00 ) + ( 22.15 )
MWd = 28.84 28.84
Tma =Source Temperature, absolute(oR)
Tm = Average dry gas meter temperature , deg F.57.0 65.2
Tma = Ts + 460
Tma = 57.04 + 460
Tma = 517.04 525.19
Ps = Absolute meter pressure, inches Hg.
13.60 = Specific gravity of mercury.
delta H = Avg pressure drop across the orifice meter during sampling, in H2O 1.40 1.00
Pb = Barometric Pressure, in Hg.30.02 30.02
Pm = Pb + (delta H / 13.6)
Pm = 30.02 + ( 1.4025 / 13.6)
Pm = 30.12 30.09
Yqa = dry gas meter calibration check value, dimensionless.
0.03 = (29.92/528)(0.75)2 (in. Hg/°/R) cfm2.
29.00 = dry molecular weight of air, lb/lb-mole.
Vm = Volume of gas sample measured by the dry gas meter at meter conditions, dcf.63.136 47.088
Y = Dry gas meter calibration factor (based on full calibration)0.9972 0.9972
Delta H@ = Dry Gas meter orifice calibration coefficient, in. H2O.1.8715 1.8715
avg SQRT Delta H =Avg SQRT press. drop across the orifice meter during sampling , in. H2O 1.1783 0.9984
O = Total sampling time, minutes.96 84
Yqa = (O / Vm ) * SQRT ( 0.0319 * Tma * 29 ) / ( Delta H@ * Pm * MWd ) * avg SQRT Delta H
Yqa = ( 96.00 / 63.14 ) * SQRT ( 0.0319 * 517.04 * 29 ) / ( 1.87 * 30.12 * 28.84 ) * 1.18
Yqa = 1.521 * SQRT 478.315 / 1,625.473 * 1.18
Yqa = 0.9719 0.9742
Diff = Absolute difference between Yqa and Y 2.54 2.31
Diff = (( Y - Yqa ) / Y ) * 100
Diff = (( 0.9972 - 0.972 ) / 0.9972 ) * 100
Average Diff = 2.43
Allowable = 5.0
1/2/202011:19 AM 112219 Div Stack M0010171
Long Cal Vost Box #5 11-29-18
Calibrator PM VOST Box Number VOST 5 Ambient Temp 72
Date 29-Nov-18 Wet Test Meter Number 10BB-1 Temp Reference Source
Dry Gas Meter Number 3605443
Results
in H20
(∆H)
liters
(Vw)
liters
(Vd)
oF
(Tw)
Outlet, oC
(Tdo)
Inlet, oC
(Tdi)
Average, oF
(Td)
Time, min
(O)Y
0.000 20.00 20.00
4.890 20.50 20.50
4.890 20.25 21.60
0.000 20.50 20.50
9.772 21.00 21.00
9.772 20.75 22.80
0.000 22.20 22.20
14.768 22.20 22.20
14.768 22.20 22.20
0.000 22.80 22.80
20.034 22.80 22.80
20.034 22.80 22.80
Average 1.0088
Vw - Gas Volume passing through the wet test meter 0 - Time of calibration run
Vd - Gas Volume passing through the dry gas meter Pb - Barometric Pressure
Tw - Temp of gas in the wet test meter
Tdi - Temp of the inlet gas of the dry gas meter
Tdo - Temp of the outlet gas of the dry gas meter
Td - Average temp of the gas in the dry gas meter

oC oF
1 2 3 4 5 6
0 0 0 0 0.0 0.0%
100 100 100 100 100.0 0.0%
500 500 500 500 500.0 0.0%
1000 1000 1000 1000 1000.0 0.0%
1 - Channel Temps must agree with +/- 5oF or 3oC
2 - Acceptable Temperature Difference less than 1.5 %
Wet Test
Meter Dry gas Meter Wet Test
Meter
Gas Volume
5.00.45 72.5
1.0154
68.5 10.2 1.0137
69.50.85 10.0
29.75
73.0 20.0 0.9943
11.0 1.0118
10.0
72.0
Dry Gas Meter
Temperatures
2.0 20.0
72.5
72.5
15.0 72.51.5 1.7
Setting
Roto-
meter
Liters per
minute
1.2
Orifice
Manometer
1.20
Long Cal and Temperature Cal Datasheet for VOST Dry Gas Meter Console
∆H - Pressure differential across
orifice
Y - Ratio of accuracy of wet test
meter to dry gas meter
Thermocouple Simulator
(Accuracy +/- 1oF)
Baro Press, in
Hg ( Pb)
2.0 2.3
0.50 0.70
1.00
Temp
Difference 2 (%)
Average
Temperature
Reading
0
500
100
1000
Channel Number
Temperature Reading from Individual Thermocouple Input 1
Select Temperature
Reference
Temperature
( )( )
( )
( )
2
Vw
O460tw
460tdPb
H0317.0H
460tw6.13
HPbVd
)460td(PbVwY


∗+∗


+∗
∆∗=∆
+∗

∆+∗
+∗∗=
( )()( )()( )



+
+−+=460FTempferenceRe
460FTempTest460FTempferenceReDiffTempo
oo
172
Long Cal Vost Box #8 9_21_2019
Calibrator MDW VOST Box Number VOST 8 Ambient Temp 73
Date 21-Sep-19 Wet Test Meter Number 10BB-1 Temp Reference Source
Dry Gas Meter Number 3602380
Results
in H20
(∆H)
liters
(Vw)
liters
(Vd)
oF
(Tw)
Outlet, oC
(Tdo)
Inlet, oC
(Tdi)
Average, oF
(Td)
Time, min
(O)Y
0.000 24.00 24.00
2.999 24.00 24.00
2.999 24.00 24.00
0.000 24.00 24.00
8.960 24.00 24.00
8.960 24.00 24.00
0.000 24.00 24.00
9.934 24.00 24.00
9.934 24.00 24.00
0.000 24.00 24.00
18.700 24.00 24.00
18.700 24.00 24.00
Average 1.0088
Vw - Gas Volume passing through the wet test meter 0 - Time of calibration run
Vd - Gas Volume passing through the dry gas meter Pb - Barometric Pressure
Tw - Temp of gas in the wet test meter
Tdi - Temp of the inlet gas of the dry gas meter
Tdo - Temp of the outlet gas of the dry gas meter
Td - Average temp of the gas in the dry gas meter

oC oF
1 2 3 4 5 6
32 32 32 32 32.0 0.0%
212 212 212 212 212.0 0.0%
932 932 932 932 932.0 0.0%
1829 1829 1829 1829 1829.0 0.1%
1 - Channel Temps must agree with +/- 5oF or 3oC
2 - Acceptable Temperature Difference less than 1.5 %
Wet Test
Meter Dry gas Meter Wet Test
Meter
Gas Volume
3.00.00 72.0
1.0093
75.0 11.8 1.0060
75.00.35 9.0
30.08
71.0 9.9 1.0099
10.0 1.0099
17.8
75.0
Dry Gas Meter
Temperatures
1.70 19.0
72.0
72.0
10.0 72.0
0.50
1.0 1.0
Setting
Roto-
meter
Liters per
minute
1.00
Orifice
Manometer
0.50
1832
Long Cal and Temperature Cal Datasheet for VOST Dry Gas Meter Console
∆H - Pressure differential across
orifice
Y - Ratio of accuracy of wet test
meter to dry gas meter
Thermocouple Simulator
(Accuracy +/- 1oF)
Baro Press, in
Hg ( Pb)
2.0 2.0
0.25 0.25
Channel Number
Temperature Reading from Individual Thermocouple Input 1 Temp
Difference 2 (%)
Average
Temperature
Reading
32
932
212
Select Temperature
Reference
Temperature
( )( )
( )
( )
2
Vw
O460tw
460tdPb
H0317.0H
460tw6.13
HPbVd
)460td(PbVwY


∗+∗


+∗
∆∗=∆
+∗

∆+∗
+∗∗=
( )()( )()( )



+
+−+=460FTempferenceRe
460FTempTest460FTempferenceReDiffTempo
oo
173

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
APPENDIX F
LIST OF PROJECT PARTICIPANTS

174

IASDATA\CHEMOURS\15418.002.018\DIVISION REPORT 11 2019-AMD 1/21/2020
The following WESTON employees participated in this project.
Paul Meeter Senior Project Manager
Jeff O’Neill Senior Project Manager
Wes Fritz Senior Project Manager
Matt Winkeler Team Member
Kyle Schweitzer Team Member
Brandon Berger Team Member

175