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HomeMy WebLinkAbout5002_JacksonCounty_MSWLF_CAER_FID1636625_20220113January 2022 Jackson County Closed Municipal Solid Waste Landfill ti9 kzANCHOR QEA Five -Year Corrective Action Evaluation Report Prepared for Jackson County Solid Waste Department January 2022 Jackson County Closed Municipal Solid Waste Landfill Five -Year Corrective Action Evaluation Report Prepared for Jackson County Solid Waste Department 401 Grindstaff Cove Road Sylva, North Carolina 28779 41,011-0-00f Stephen Colqu un Staff Engineer Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Senior Managing Geologist Project Number: C11480-01.01 \\athena\asheville\Projects\Jackson County\, -Reports - Groundwater\2021 Corrective Action Evaluation Report\2021-0106 Jackson County Five -Year Corrective Action Evaluation Report.docx TABLE OF CONTENTS 1 Historical Summary...................................................................................................................1 2 Constituents of Concern..........................................................................................................4 2.1 Discussion of Historical Data..........................................................................................................................4 2.1.1 Background Monitoring Well.........................................................................................................4 2.1.2 Upgradient Monitoring Wells.........................................................................................................4 2.1.3 Mid -Gradient Monitoring Wells....................................................................................................5 2.1.4 Downgradient Monitoring Wells...................................................................................................6 3 Overview of Remedial Approach...........................................................................................8 3.1 Leachate Extraction System.............................................................................................................................8 3.2 Assessment of Natural Attenuation..........................................................................................................10 3.2.1 Stability of COC Plume................................................................................................................... 10 3.2.2 Analysis of MNA................................................................................................................................ 11 3.3 Hydrogeology....................................................................................................................................................13 4 Conclusions and Recommendations...................................................................................15 5 References.................................................................................................................................17 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Well Construction Details and Corresponding Elevations Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) Table 4 Mass Removal Calculations for Volatile Organic Compounds Detected in the Leachate Sample Table 5 Summary of Natural Attenuation Parameters FIGURES Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Generalized Groundwater Flow Direction and Concentration Trend Relative to Groundwater Standards Figure 4 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-01 Figure 5 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-02 Five -Year Corrective Action Evaluation Report i January 2022 Figure 6 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-03 Figure 7 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-04 Figure 8 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-05R Figure 9 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-06 Figure 10 Hydrograph and Constituents of Concern vs. Time —Monitoring Well MW-07 Figure 11 Leachate Extraction System Trends APPENDICES Appendix A Extraction Well Boring Logs Five -Year Corrective Action Evaluation Report ii January 2022 ABBREVIATIONS pg/L micrograms per liter 1,1-DCA 1,1-dichloroethane 1,2-DCE cis- 1,2-dichloroethene 1,4-DCB 1,4-dichlorobenzene 2L standards Title 15A of the North Carolina Administrative Code, Subchapter 2L, .0202 ACM Assessment of Corrective Measures Altamont Altamont Environmental, Inc. CAP Corrective Action Plan COC constituent of concern DENR North Carolina Department of Environment and Natural Resources DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management EPA U.S. Environmental Protection Agency Fe2 ferrous iron Fe3 ferric iron ft/day feet per day ft/yr feet per year HELP Hydrologic Evaluation of Landfill Performance LFG landfill gas mg/L milligrams per liter MNA monitored natural attenuation NCAC North Carolina Administrative Code nM nanomole ORP oxidation reduction potential PCB Polychlorinated biphenyls PCE tetrachloroethene PWR partially weathered rock Site closed municipal solid waste landfill located approximately 0.75 miles west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74) SWS Solid Waste Section TCE trichloroethene TWSA Tuckaseigee Water & Sewer Authority VOC volatile organic compound Five -Year Corrective Action Evaluation Report iii January 2022 Historical Summary The Jackson County Solid Waste Department maintains a closed municipal solid waste landfill (Site) located approximately 0.75 miles west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74, Figure 1). Water quality monitoring at the landfill is performed in accordance with the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM), Solid Waste Section (SWS), under Permit No. 50-02, issued to Jackson County on April 11, 2006. The landfill permit requires semiannual monitoring of groundwater quality by sampling seven monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07). A Site Layout Map is included in Figure 2. Over time, groundwater quality monitoring indicated persistent low-level concentrations of constituents in groundwater samples that exceeded a regulatory standard. To achieve compliance with regulatory standards the following activities were completed: • September 7, 2010—An Assessment of Corrective Measures (ACM) report was submitted to the North Carolina Department of Environment and Natural Resources (DENR) DWM SWS. The ACM stated that volatile organic compounds (VOCs) and metals have been historically detected in excess of the groundwater standards listed in Title 15A of the North Carolina Administrative Code (NCAC), Subchapter 2L, .0202 (2L standards). Individual metals are not persistently detected over time and, historically, elevated turbidity levels in the samples may have affected the results. Therefore, the ACM suggested that the objective of the remedy focus on VOCs. The ACM evaluated several potential remedies. • November 12, 2010—Based on the ACM report, the SWS issued a letter to Jackson County entitled Response: Assessment of Corrective Measures, requesting a remedy to restore groundwater quality and effectively reduce contamination. • May 13, 2011—Following advertisement and solicitation for public comment on the ACM, Altamont Environmental, Inc' (Altamont). submitted a letter containing the Corrective Action Permit Modification Application —Jackson County Landfill, dated May 13, 2011. The Corrective Action Permit Modification application indicated that the selected remedy was leachate removal and monitoring of natural attenuation parameters. • June 2, 2011—The SWS approved the selected remedy with a letter entitled Response: Groundwater Corrective Action Selected Remedy Approval —Closed Jackson County Landfill, Permit No. 50-02, dated June 2, 2011. The SWS requested the preparation of a Corrective Action Plan. • June 30, 2011—Altamont submitted the Corrective Action Plan —Jackson County Municipal Solid Waste Landfill on June 30, 2011. Based upon the property currently owned by Jackson County, relative to monitoring locations, the Corrective Action Plan (CAP) established a Altamont Environmental, Inc. became Anchor QEA of North Carolina, PLLC in 2016. Five -Year Corrective Action Evaluation Report 1 January 2022 compliance and review boundary for the closed landfill in accordance with the criteria set forth in Title 15A, of the NCAC, Subchapter 2L, .0107. The CAP offered a remedy to restore groundwater quality and effectively reduce contamination for VOC constituents in excess of groundwater quality standards outside the compliance boundary. The CAP outlined a schedule for the implementation of the remedy that included a three -phased approach over a 5-year time span. Implementation of the remedy included: purchase of dedicated leachate extraction pumps (Phase 1); installation of dedicated pumps into each of the existing landfill gas extraction wells and collection of leachate into a leachate extraction sump (Phase 2); disposal of leachate through connection of leachate extraction sump to the Tuckaseigee Water & Sewer Authority (TWSA) collection system (Phase 3); and continued monitoring of groundwater for natural attenuation parameters, VOCs, and metals. • September 1, 2011—The CAP was approved by the SWS in a letter from the DENR, entitled Approval of the County's Corrective Action Plan, dated September 1, 2011. The approval letter required that after 5 years, the corrective actions discussed in the CAP shall be evaluated and reviewed. If VOC concentrations are not reduced, contingency plans may be required. • June 30, 2012—The first phase of CAP implementation was completed. The leachate extraction pumps were acquired. • September 1, 2012—The second phase of CAP implementation was completed. The leachate extraction pumps were installed in 10 landfill gas (LFG) extraction wells (Figure 2) and leachate extraction was initiated. • September 6, 2013—The third and final phase of CAP implementation was completed. Discharge from the temporary collection tank (from which the leachate was pumped and hauled for disposal) was permanently connected to the TWSA. • October 2016—the first Five -Year Corrective Action Evaluation Report was completed. This 5-year review identified that leachate extraction system did not align with the performance as modeled by the CAP. The leachate recovery system was based on an infiltration volume of 3.1 million gallons per year and leachate removal rate of 1.2 million gallons per year. Over the 3 years of continuous pumping, 0.35 million gallons had been removed by the system. Figure 2 shows the locations of the seven groundwater monitoring wells and the 10 landfill gas extraction wells. The CAP established a compliance and review boundary for the closed landfill, which are shown in Figure 2. Historically, several VOCs have been detected in samples collected from monitoring wells located outside the compliance boundary (MW-02, MW-04, MW-06, and MW-07). The DEQ-approved leachate extraction (e.g., source reduction) with monitored natural attenuation (MNA) remedy was chosen for restoring groundwater quality by reducing VOC concentrations to levels less than the groundwater quality standards outside the compliance boundary. This second Five -Year Corrective Action Evaluation Report 2 January 2022 5-year review will evaluate the performance of the leachate extraction system with MNA in regard to contaminant reduction at the compliance boundary. A summary of laboratory analyses, including the MNA parameters, is provided in Table 1. Table 2 provides a summary of well -construction information for the seven Site monitoring wells. Table 3 summarizes historical concentrations of the Site constituents of concern (COCs), which will be discussed in detail in Section 2.0. Five -Year Corrective Action Evaluation Report 3 January 2022 2 Constituents of Concern The main COCs, as outlined in the ACM, are 1,1-dichloroethane (1,1-DCA), 1,4-dichlorobenzene (1,4-DCB), benzene, cis- 1,2-dichloroethene (1,2-DCE), tetrachloroethene (PCE), trichloroethene (TCE), and vinyl chloride. Historically these compounds have been detected in Site monitoring wells located both inside and outside of the compliance boundary at concentrations greater than the 2L standards. See Table 3 for a summary of the historical concentrations of the COCs. Since the CAP's sampling activities began in 2010 and with the initiation of 1,4-dioxane analysis in 2018, using SW846 Method 8260 SIM, four VOCs, benzene, 1,4-dichlorobenzene, vinyl chloride, and 1,4-dioxane have been detected in excess of the 2L standard outside of the compliance boundary. These contaminants will be the focus for evaluating the effectiveness of corrective action at the Site. The overall Site layout, including the edge -of -waste and compliance boundaries, is shown in Figure 2. Figure 3 provides a generalized groundwater flow map and a summary of COC concentration trends. The graphs shown in Figures 4 through 10 provide a visual summary of the concentration of VOCs that consistently exceed their respective 2L standards, how they relate to groundwater elevation, and how their trend changes throughout the period that follows the implementation of leachate extraction with MNA remedy. Figure 11 provides a summary of the leachate extraction system performance. 2.1 Discussion of Historical Data Table 2 provides well -construction information for the current seven Site monitoring wells. Table 3 shows historical concentrations dating back as far as 1999 for the oldest monitoring wells on Site. 2.7. 7 Background Monitoring Well One monitoring well, MW-02 (Figures 2, and 5), serves as the Site's background monitoring well. It is located downgradient of the landfill, but is in a position that is not along a groundwater flow path from the landfill wastes. MW-02 is screened in bedrock and has only exceeded the 2L standard for 1,4-dioxane. Monitoring for 1,4-dioxane began in 2018; no other COC has exceeded the 2L standards since October 2002. Prior to that time, 1,1-dichloroethane was detected slightly above its 2L standard on two occasions. 2. 7.2 Upgradient Monitoring Wells Two monitoring wells are located in the upgradient portion of the Site: MW-01 and MW-06 (Figure 2). MW-01 is located inside the compliance boundary and was installed in 1992. MW-06 is located outside of the compliance boundary in the northwest corner of the property and was installed in 2004. Both of these monitoring wells are screened in bedrock. Five -Year Corrective Action Evaluation Report 4 January 2022 The following constituents have exceeded 2L standards in upgradient monitoring wells (Table 3): • Monitoring well MW-01 (Figure 4) - M-DCA—Concentrations have been trending downward since 1999, dropping below the 2L standard of 6 pg/L in 2012, and have remained below this standard since then. - Benzene —Concentrations have consistently exceeded the 2L standard of 1 pg/L since 1999. Concentrations have been trending downward and are now slightly above the 2L standard. - 1,4-DCB—Concentrations have exceeded the 2L standard of 6 pg/L since 2001 and have been trending downward since 2015. - PCE—Concentrations have remained slightly above or slightly below the 2L standard of 0.70 pg/L since 2007. Most detections since 2008 have been reported with a "J" flag by the laboratory, indicating the result is an estimated concentration (e.g., it is greater than the laboratory's method detection limit (MDL) and less than its reporting limit). Trends have been declining since 2017 and are now below the 2L standard. - 1,4-Dioxane-1,4-Dioxane has not been detected in this well since monitoring began in 2018. • Monitoring well MW-06 (Figure 9) - M-DCA—Concentrations regularly exceeded the 2L standard between 2004 and 2009. Concentrations have been trending downward since 2009, and in 2016, concentrations dropped below the 2L standard and have remained below it. - 1,4-DCB—Concentrations have exceeded the 2L standard since 2004 and are trending downward. The last detected concentration exceeding the 2L standard was in April 2016. - Benzene —Concentrations have generally exceeded the 2L standard since 2004; however, in 2014, concentrations began trending downward and have remained below 2L standard since 2016. - PCE—Concentrations have not exceeded 2L standards in MW-06 since the April 2009 sampling event, with the exception of the March 2018 sample, which had detection of 0.72 J (an estimated concentration). - 1,4-Dioxane-1,4-Dioxane has not been detected in this well since monitoring began in 2018. 2.1.3 Mid -Gradient Monitoring Wells Monitoring wells MW-03 and MW-05R are topographically located midway along the groundwater flow path for the Site (Figure 2). MW-03 is screened in the partially weathered rock (PWR) portion of the aquifer and was installed in 1992. MW-05R is screened in the saprolite portion of the aquifer, which is located stratigraphically above the PWR. MW-05R was installed in 2012 to replace MW-05. Five -Year Corrective Action Evaluation Report 5 January 2022 Anchor QEA's analytical records of MW-05 date back to 1999. Both monitoring wells are located inside the compliance boundary. The following constituents have exceeded 2L standards in mid -gradient monitoring wells (Table 3): • Monitoring well MW-03 (Figure 6) - 1,1-DCA—Concentrations have exceeded the 2L standard regularly between 1999 and 2005, but have not exceeded the 2L standard since 2005. Concentrations have been trending strongly downward. - 1,4-DCB—Concentrations regularly exceed its 2L standard during the fall sampling events when groundwater elevations are lower between 1999 and 2015. Seasonal variation (fall versus spring) at this well has been occurring regularly since 2006. The 2L standard has not been exceeded since March 2017. - Benzene —Concentrations follow the same seasonal pattern as 1,4-DCB, historic exceedances regularly occurred in the fall. Concentrations are trending downward and have only exceeded the 2L standard once since fall 2014. - PCE—Concentrations have never exceeded the 2L standard in MW-03 and have not been detected since April 2007. - 1,4-Dioxane—Concentrations have exceeded the 2L standard of 3 pg/L three times since semiannual monitoring began in 2018. • Monitoring well MW-05/MW-05R (Figure 8) - 1,4-DCB—Although concentrations exceeded the 2L standard regularly between 1999 and 2011, since 2011, 1,4-DCB has generally been in decline and recent detections are typically fluctuate above and below its 2L standard. - Benzene —Concentrations have exceeded the 2L standard consistently since 2007 and remain generally stable to slightly increasing in trend. - PCE—PCE has not been detected in MW-05/MW-05R. - Vinyl Chloride —Although concentrations have consistently exceeded the 2L standard since 2007, they are generally in a slight declining trend. As stated in Section 1.0, vinyl chloride is a degradation product of chlorinated solvents. Concentrations of vinyl chloride in this well indicate that conditions between the source area and MW-05R may support degradation of chlorinated solvents. - 1,4-Dioxane—Concentrations have regularly exceeded the 2L standard since monitoring began in 2018, but are in a declining trend. 2. 7.4 Downgradient Monitoring Wells Monitoring wells MW-04 and MW-07 are topographically located in the downgradient portion of the Site (Figure 2). MW-04 is screened in saprolite, and MW-07 is screened in bedrock. Five -Year Corrective Action Evaluation Report 6 January 2022 The following constituents have exceeded 2L standards in downgradient monitoring wells (Table 3): • Monitoring well MW-04 (Figure 7) - 1,4-DCB—Concentrations consistently exceeded the 2L standard between 1999 and 2009 and have since been trending downward to concentrations less than the 2L standard. Concentrations have not exceeded the 2L standard since the fall 2011 sampling event. - Benzene —Concentrations consistently exceeded the 2L standard between 2007 and 2010, and are trending downward. Benzene has not exceeded the 2L standard since the leachate extraction began in September 2012. The only detection was in 2015 at the 2L standards; all other detections have been below the 2L standard with "J" flagged concentrations. - PCE—One detection of PCE was reported in 2007 at a "J" flagged concentration well below the 2L standard. - Vinyl Chloride —Concentrations have exceeded the 2L standard consistently since 2007 with mostly "J" flagged concentrations. Vinyl chloride has not been detected since 2015. - 1,4-Dioxane—Since 1,4-dioxane monitoring began in 2018, concentrations are trending downward and have consistently exceeded the 2L standard except for the Spring 2021 event. • Monitoring well MW-07 (Figure 10) - 1,4-DCB—Concentrations have slightly exceeded the 2L standard six times since installation of this monitoring well in 2010. - Benzene —Concentrations are relatively stable and remain slightly above the 2L standard since 2011. - Vinyl Chloride —Concentrations have exceeded the 2L standard in six of the 12 events in which this well has been sampled. All detected concentrations of vinyl chloride were reported with a "J" flag by the laboratory, and the last time it was detected above the MDL was in October 2015. - 1,4-Dioxane—Since 1,4-dioxane monitoring began in 2018, concentrations are trending downward and have consistently exceeded the 2L standard. 1,4-dioxane concentrations at this monitoring well are the highest of all the Site monitoring wells. Five -Year Corrective Action Evaluation Report 7 January 2022 3 Overview of Remedial Approach As stated above, the CAP was implemented between 2012 and 2013, with leachate extraction beginning in September 2012; however, from September 2012 to September 2013, leachate was intermittently pumped, because flow was limited as a result of collecting and hauling the leachate for disposal off Site. In September 2013, the leachate extraction system was connected to the TWSA sanitary sewer system, and continuous pumping of the leachate started. The leachate extraction system was installed to remove mass from the source area, which over time will allow for downgradient concentrations to attenuate at an accelerated rate. MNA is the other component of the remedial approach at the Site. Analytical data has been collected from the Site monitoring wells since at least 1999. A review of the data indicates that, overall, COC concentrations have been declining, and that natural attenuation parameters show support for natural attenuation processes. The following sections provide greater detail of the remedial approach and analysis of the semiannual monitoring data. 3.1 Leachate Extraction System There are 10 landfill gas (LFG) extraction wells installed at the Site, referred to as extraction well 1 (EW-1) through EW-10. EW-1, EW-2, and EW-3 were installed in March 2004 to be used for a pilot study to determine potential landfill -gas -to -energy use at the Site. EW-4 through EW-9 were installed in January 2005. EW-1, EW-2, and EW-3 were replaced with new extraction wells in December 2011 (EW-1 R, EW-2R, and EW-3R, respectively). The wells range in depth from 40 feet below ground surface (bgs) to 90 feet bgs and have a screened interval that ranges from 18 feet in the shallower wells to 48 feet in the deeper wells. They are constructed of either 4- or 6-inch high -density polyethylene (HDPE) pipe, which is perforated along the screened interval to allow the flow of landfill gas into the well casing. The screened interval of the well is surrounded by a gravel pack. The gravel is 1 to 3 inches in diameter. Review of the extraction well boring logs (Appendix A) indicate the soil cap thickness is generally between 5 and 10 feet bgs throughout the landfill. The boring logs also indicate that trash and debris mixed with soil was noted from below the clay cap to each well's terminal depth. Bottom inlet pneumatic leachate extraction pumps were installed in the bottom of each landfill gas extraction well in September 2012. The leachate extraction system was connected to the TWSA in September 2013. Anchor QEA began collecting leachate samples during semiannual water quality monitoring events in October 2012. The leachate samples were analyzed for Appendix I VOCs and metals. Results from these samples were used in a mass removal calculation to determine the quantity of VOCs removed in pounds. A totalizer, installed at the TWSA sewer connection on Five -Year Corrective Action Evaluation Report 8 January 2022 September 6, 2013, is observed during each semiannual sampling event to keep track of the number of gallons of leachate removed. The following shows comparison of the anticipated performance to actual system data: Period Modeled Actual Total Volume of Leachate Removed (gallons) Total Mass of VOC Removed (pounds) Total Volume of Leachate Removed (gallons) Total Mass of VOC Removed (pounds) 2011 to 2016 6,000,000 0.55 352,375 0.159 2016 to 2021 6,000,000 0.55 349,619 0.447 Totals 12,000,000 1.1 701,994 0.607 As of October 2021, a total of 701,994 gallons of leachate have been removed from the landfill. The analytical data provided by the leachate samples indicates that approximately 0.607 pounds of VOCs have been removed since leachate extraction began in September 2012. The majority of the VOCs removed has occurred between 2016 and 2021. At the end of 2016, the system had only removed 0.159 pounds of VOCs. A summary of mass removal calculations is provided in Table 4. The leachate extraction system was designed to remove approximately 0.55 pounds of VOC mass in a 5-year period, based on the following assumptions: • The source of the extracted water is primarily water infiltrating through the landfill cap into waste. • Most, if not all, of the estimated volume of water infiltrating through the landfilled waste becomes leachate. • The quality of leachate generated by the landfill is relatively uniform. • The samples collected from EW-04 and EW-09 on February 21, 2011, are representative of the quality of the water to be extracted at the time the system started. There are many reasons that could explain why the leachate extraction system is not removing the volume of leachate that is expected by the design. The primary reason for the difference appears to be related to the volume of leachate collected by the system. The modeling and recharge calculations, as presented in the CAP, estimated the volume of water that may infiltrate through the landfill cap at approximately 3.1 million gallons per year and the estimated volume of water to be extracted was estimated at 1.2 million gallons per year at full implementation. To date, a total volume of 0.7 million gallons has been recovered since full-scale implementation. This volume is less than anticipated by the design. The model that was used to estimate the 3.1 million gallons per year was the Hydrologic Evaluation of Landfill Performance (HELP) Model (see Section 3.0 of the CAP). The 1.2 million gallons per year was calculated using a simple hydraulic model based upon the known Five -Year Corrective Action Evaluation Report 9 January 2022 characteristics/performance of the extraction pumps and incompressible fluid (leachate) flow in pressure conduits (the leachate extraction and collection pipe). The parameters upon which the model in the CAP were based were the best assumptions available at that time. Parameters could be calibrated to align observed performance with modeled performance. However, because the leachate extraction system is only part of the remedy, recalibration of the model and enhancement of the leachate extraction system based upon model recalibration should only be considered in the context of the remedy as a whole. VOC mass removal from the leachate during the 2016 to 2021 reporting period was much improved due to an increase in the volume of leachate removed and generally higher concentrations of VOC in the leachate. These increases began in 2020 and may be due to the general increase in groundwater elevations observed in most groundwater monitoring wells since the system started up. Rising groundwater elevations suggests greater infiltration of water into the landfill system, thus increasing the potential leaching of VOC and generation of greater volumes of leachate. 3.2 Assessment of Natural Attenuation Natural attenuation is a naturally occurring process in the environment that acts to reduce mass, toxicity, mobility, volume, or concentration of contaminants. Multiple in situ processes can contribute to natural attenuation. These include biodegradation, dispersion, dilution, adsorption, volatilization, and chemical stabilization or destruction of contaminants (Interstate Technology Regulatory Council 1999). Natural attenuation is monitored by collecting samples from Site monitoring wells and having the samples analyzed by a laboratory for VOCs and MNA parameters. MNA parameters are a suite of compounds that provide insight on an aquifer's ability to naturally attenuate contaminants. MNA parameters are collected every 6 months, during fall and spring of each year. The first MNA parameter suite was collected during the fall 2011 sampling event following the CAP approval. 3.2.7 Stability of COC Plume The source area for the Site is generally the landfilled waste and the area beneath it. Conditions best representing the source area are observed in the collected leachate, which has been sampled semiannually since implementation of the remedy. A generalized flow path downgradient from monitoring wells MW-01 and MW-06 consists of the extraction wells (source), monitoring wells MW-03 and MW-05R (mid -gradient), and monitoring wells MW-07 and MW-04 (downgradient). A review of historical data (including 2016 data) shows decreasing trends in total VOCs in most wells, suggesting a stable to declining COC plume. A review of COC concentrations along the flow path shown in Figure 3 suggests plume stability as well: • Source Area —In 2011 analytical results for leachate samples from EW-4 and EW-9 exceeded the 2L standards for 1,4-DCB and benzene. COC constituents detected in leachate samples collected from the leachate extraction system are now generally less than the 2L standard for Five -Year Corrective Action Evaluation Report 10 January 2022 1,4-DCB and greater than 2L standard for benzene. The 2L standard for 1,4-dioxane has been exceeded in collected leachate samples since monitoring began in 2018. • Mid -gradient Monitoring Wells —Wells MW-03 and MW-05R are located inside the compliance boundary and represent mid -gradient wells along the flow path from the source a rea. - MW-03—Groundwater samples collected from this well indicate declining VOC trends to levels that are below the 2L standards. - MW-05R—Groundwater samples collected from this well exceed 2L standards for 1,4-DCB, benzene, vinyl chloride, and 1,4-dioxane. • Downgradient Monitoring Wells —Wells MW-04 and MW-07 are located outside of the compliance boundary and represent the downgradient wells along the flow path from the source area. - MW-04—Groundwater samples collected from this well indicate declining VOC trends to levels that are below the 2L standards. - MW-07—Although groundwater samples collected from this well slightly exceed the 2L standards for benzene and 1,4-DCB, the concentrations are generally stable or in decline. Concentrations of 1,4-dioxane exceed the 2L standard, but have been in decline since monitoring began in 2018. Based on the current and historical results along the flow path from the source area to the downgradient monitoring wells MW-04 and MW-07, the observed concentrations are generally decreasing or staying the same along the flow path, providing evidence for a stable to declining COC plume. 3.2.2 Analysis of MNA Site contaminants can be categorized into two groups: aerobically degraded contaminants (such as benzene and 1,4-dichlorobenzene) and anaerobically degraded contaminants (such as PCE, TCE, and cis-1,2-DCE). A review of MNA and field parameter data can be found in Table 5. Certain parameters included in Table 1 are not included in Table 5, as these parameters were not applicable to the specific conditions at the Site. To evaluate the MNA parameters collected for the Site, Anchor QEA generally followed the procedures outlined in the Technical Protocol of Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater (U.S. Environmental Protection Agency [EPA] 1998) and the Technical Guidelines for Evaluating Monitored Natural Attenuation of Petroleum Hydrocarbons and Chlorinated Solvents in Groundwater at Naval and Marine Corps Facilities (Department of the Navy 1998). Both documents outline a screening protocol for evaluating natural attenuation processes under anaerobic conditions. The Department of Navy provides guidance for evaluating natural attenuation of petroleum constituents under aerobic conditions. While there are some anaerobically degraded Five -Year Corrective Action Evaluation Report 11 January 2022 contaminants in groundwater samples collected from Site monitoring wells, the main COCs on which this report focuses are benzene, 1,4-DCB, and vinyl chloride. These three constituents degrade aerobically; therefore, the Department of Navy guidance was used as the primary reference for evaluating natural attenuation parameters collected at the Site. Conditions at the Site are supportive of aerobic degradation, as discussed in the following section. 3.2.2.1 Summary of MNA Parameters Certain parameters are found at high concentrations in different areas of the Site. The parameters discussed in the following sections are either byproducts of contaminant degradation, or indicators of chemical reactions that promote contaminant degradation. The following MNA parameters, summarized in Table 5, are evaluated below for their support or non-support of MNA. • Dissolved Oxygen (DO) —DO concentrations that are greater than 0.5 milligrams per liter (mg/L) are generally not supportive of MNA through reductive de -chlorination. DO concentrations across the Site are generally greater than 0.5 mg/L, ranging from 0.11 to 10.45 mg/L with an average of 2.64 mg/L. This suggests aerobic conditions on Site, which are favorable for degradation of 1,4-DCB, benzene, and vinyl chloride. • Oxidation Reduction Potential (ORP)—ORP values that are less than 50 millivolts (mV) indicate that a reductive pathway for COC degradation is possible, and values that are less than -100 mV suggest that reductive degradation is likely. ORP concentrations across the Site are generally greater than 50 mV, ranging from -164 to 638, with an average of 141.54 mV. This suggests that the aquifer conditions beneath the landfill are more aerobic than anaerobic, which are favorable for degradation of 1,4-DCB, benzene, and vinyl chloride. • Nitrate —Nitrate can be used as an electron donor through aerobic biodegradation and will result in decreases in nitrate concentrations over time. Detected concentrations of nitrate from across the Site range from 0.017 to 14.6 mg/L with an average of 2.22 mg/L. Monitoring wells MW-02, MW-03, and MW-04 have a history of detectable concentrations for nitrate. While MW-02 nitrate concentrations have been relatively stable, those for MW-03 and MW-04 have increased over time. This suggests aerobic degradation through de -nitrification is not occurring at the Site. This degradation pathway will likely remain suppressed until the dissolved oxygen has been consumed and falls below a concentration of 0.5 mg/L. • Ferrous (Fe2) Iron —Once denitrification has occurred and the available nitrate has been consumed, ferric iron (Fe3)-reducing bacteria will begin to co -metabolize petroleum hydrocarbons in the presence of ferric iron, producing ferrous iron through reduction. A ferrous iron concentration above 1 mg/L is supportive of a reductive de -chlorination pathway. Across the Site, detected ferrous iron concentrations range from 0.017 mg/L to 65 mg/L, with an average of 8.90 mg/L, indicating that a reductive pathway is possible. MW-01 and MW-05R show a generally increasing trend in ferrous iron over time, suggesting that iron reduction is an active process in this area of the Site. Five -Year Corrective Action Evaluation Report 12 January 2022 • Chloride —Under aerobic conditions, increases in chloride concentrations suggest direct oxidation of chlorinated compounds may be occurring. Chloride concentrations are generally increasing in monitoring well MW-07, suggesting that direct oxidation of 1,4-DCB and vinyl chloride is occurring in the downgradient portion of the Site. At other locations across the Site, chloride concentrations are not increasing, which suggests that other natural attenuation process are more active in these areas. • Hydrogen —Hydrogen concentrations greater than 1 nanomole (nM) indicate evidence of reductive de -chlorination occurring in the aquifer. Monitoring wells must be sampled via low -flow methods in order to collect hydrogen samples. Some Site wells do not produce enough water to be sampled in this method, and hydrogen samples cannot be collected. Across the Site, hydrogen concentrations since 2011 have ranged from 0.34 to 230 nM, with an average of 33.3 nM. MW-03 shows a generally increasing trend in hydrogen concentrations, with higher concentrations of hydrogen being detected during the spring events. These concentrations suggest that reductive de -chlorination is occurring in some areas of the Site. • Carbon Dioxide —Carbon dioxide is the result of oxidation and final daughter product of degradation processes. The average concentration of carbon dioxide in monitoring well MW-02 (85 mg/L) is lower by an order of magnitude than the other wells across the Site. The Site -wide carbon dioxide concentrations (not including MW-02) have ranged between 48 and 993 mg/L from October 2011 through March 2021, with an average concentration of 240 mg/L. Monitoring well MW-02 is not located along a groundwater flow path from the landfill to a point of discharge; therefore, it is representative of a background concentration. Considering that carbon dioxide concentrations are elevated relative to background, it suggests that degradation of chlorinated compounds is occurring. Overall, MNA parameters are supportive of contaminant oxidation in the mid -gradient and downgradient portion of the Site. Parameters also provide evidence of reductive de -chlorination occurring in the upgradient portion of the Site. The upgradient portion contains both aerobically degraded and anaerobically degraded contaminants. Site -wide conditions appear to be sufficient for natural attenuation of both contaminant groups (anaerobic degradation in the upgradient and source areas and aerobic in the mid -gradient and downgradient areas). 3.3 Hydrogeology Figure 3 shows the generalized groundwater flow direction . Groundwater at the Site flows in a south-southwest direction, from the extraction wells towards MW-04 and MW-07, with MW-03 and MW-05R representing mid -gradient wells along this flow path. Anchor QEA's 2011 CAP stated that hydraulic conductivity at the Site is estimated to be 0.0001 centimeters per second (cm/s), which equates to approximately 103 feet per year (ft/yr). The hydraulic gradient was calculated to be 0.08 feet per foot, based on the elevation difference between MW-05R and MW-04. Based on these Five -Year Corrective Action Evaluation Report 13 January 2022 values, groundwater flow velocity can be calculated with an assumed effective porosity of 0.25 (established in the CAP). The following equation was used to calculate groundwater flow velocity: Equation 1 —k V= —*i n where: v = groundwater flow velocity k = hydraulic conductivity, 103 ft/year or 0.282 ft/day i = hydraulic gradient, 0.10357 feet/foot n = effective porosity, 0.25 0.282 ft ft V 0.25 Y * 0.10357 ft V = 0.117 fa ft or 42.67 ft y year The calculation of groundwater flow velocity shows that it takes approximately 12 years for groundwater to travel from the source area to MW-05R and 19 years for groundwater to travel from the source area to the downgradient wells MW-04 and MW-07. As stated in Section 3.1, leachate extraction began in 2012. Based on the calculated groundwater flow velocity, it will take another 3 years for improvements in groundwater quality due to the leachate extraction system to show any observable difference in the groundwater quality in MW-05R, and another 10 years for those changes to be observed in the downgradient portion of the Site. Five -Year Corrective Action Evaluation Report 14 January 2022 4 Conclusions and Recommendations While it is still premature to see reductions in COC concentrations as a result of the leachate extraction system, this second 5-year review has identified that the observed performance of the leachate extraction system has improved, but still does not align with the performance as modeled in the CAP. This is most likely due to an overestimation of the volume of precipitation infiltrating into the landfill. The leachate recovery system was based on an infiltration volume of 3.1 million gallons per year and a leachate removal rate of 1.2 million gallons per year. Over the 9 years of continual pumping from the leachate extraction system, a total of 0.7 million gallons of leachate have been removed resulting in approximately 0.607 pounds of VOC. Anchor QEA recommends that Jackson County evaluate the leachate extraction system to determine if performance can be improved. To evaluate the system, the following actions could be taken: 1. Gauge depths to leachate in each extraction well and compare to 2010 levels. 2. Resample the leachate in EW4 and EW9 and compare to the 2010 concentrations. 3. Sample leachate in the other extraction wells. 4. Determine if leachate extraction pumps are operating at capacity. 5. Re-evaluate the inputs used to model an estimated infiltration volume of 3.1 million gallons per year and removal rate of 1.2 million gallons per year. Because the leachate extraction system is only part of the remedy, the recommendation of evaluating the leachate extraction system is something that should be considered to enhance performance. Evidence of improved groundwater quality, potentially due to the leachate extraction system, is observed in mid -gradient well, MW-05R, which has shown continued improvement since system start-up, despite the disparity between observed performance and the performance modeled in the CAP. Analysis of long-term MNA parameters and COC results indicates slow degradation of the Site COCs. While the COCs are still detected above 2L standards outside of the compliance boundary, they appear to be stable or declining in concentration and have not been detected in either surface water samples or groundwater samples collected from domestic water supply wells. There is sufficient evidence for biodegradation of anaerobically degraded contaminants (mainly PCE) that are still present at low concentrations in the upgradient portion of the Site. Site conditions also allow for aerobic degradation of 1,4-DCB, benzene, and vinyl chloride in the mid -gradient and downgradient portions of the Site. Based on the available data, Anchor QEA believes that conditions for natural attenuation are sufficient at the Site. The hydrogeologic conditions at the Site show that it will be 20 to 30 years following system start-up (2032 to 2042) before concentration reductions, attributable to the leachate extraction system, begin to affect the concentrations in the downgradient portion of the Five -Year Corrective Action Evaluation Report 15 January 2022 Site. Site receptors (surface water and domestic water supply wells) have not been impacted by the COCs; therefore, Anchor QEA recommends continued but reduced monitoring of MNA parameters from annual to once every 2 years (biennial) and a pared -down version of the Appendix I and Appendix II parameters. Based on the lack of historical detections of the following parameters, Anchor QEA recommends removing these parameters from the monitoring schedule: • Appendix II polychlorinated biphenyls (PCBs) • Cyanide Moving forward, Anchor QEA requests on behalf of Jackson County, that the semiannual monitoring schedule includes the following constituents and frequency: Parameter Frequency Next Sample Event Appendix I VOCs Annual Spring 2022 Appendix I Metals Annual Spring 2022 Sulfide Semiannual Spring 2022 Appendix 11 VOCs Annual Fall 2022 Appendix II Metals Annual Fall 2022 Appendix 11 SVOCs Annual Fall 2022 Appendix II Herbicides2 Annual Fall 2022 Appendix 11 Pesticides' Annual Fall 2022 MNA Parameters Biennial Fall 2023 Anchor QEA will continue a semiannual monitoring schedule at the Site, which will include collecting samples from all Site monitoring wells, surface waters upstream and downstream of the landfill, and sampling domestic water supply wells annually. Anchor QEA will reassess effectiveness of the remedy following the spring 2026 monitoring event. z The DEQ approved monitoring of Appendix II Herbicides, Appendix II Pesticides, and Appendix II PCBs every two years in response to the 2016 Five -Year Corrective Action Evaluation Report. The next monitoring event including these would be the Fall 2024 event. Five -Year Corrective Action Evaluation Report 16 January 2022 5 References Altamont (Altamont Environmental, Inc.), 2011. Corrective Action Plan. June 2011. Department of the Navy, 1998. Technical Guidelines for Evaluating Monitored Natural Attenuation of Petroleum Hydrocarbons and Chlorinated Solvents in Groundwater at Naval and Marine Corps Facilities. September 1998. Interstate Technology Regulatory Council, 1999. Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices. September 1999. DEQ DWM Hazardous Waste Section (North Carolina Department of Environmental Quality Division of Waste Management Hazardous Waste Section), 2000. Guidance on Developing a Monitored Natural Attenuation Remedial Proposal for Chlorinated Organics in Ground Water. October 2000. EPA (U.S. Environmental Protection Agency), 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Ground Water. September 1998. Five -Year Corrective Action Evaluation Report 17 January 2022 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Analysis Metals' VOCs' 1,4-Dioxane Mercury Appendix II SVOCS, Appendix II Herbicides3 Appendix II Pesticide53 Appdendix II PCBs' Sample Name EPA 6020B EPA 8260D EPA 8260D SIM EPA 7470A EPA 8270D EPA 8151A EPA 8081 B and 8141 B EOAA 8082A MW-01 X X X X X X X X MW-02 X X X X X X X X MW-03 X X X X X X X X MW-04 X X X X X X X X MW-05R X X X X X X X X MW-06 X X X X X X X X MW-07 X X X X X X X X Groundwater Samples Surface Water and Leachate Samples Analysis Metals' VOCs' 1,4-Dioxane Mercury Calcium, Magnesium, Hardness Sample Name EPA 6020B EPA 8260D EPA 8260D SIM EPA 7470A EPA 200.7 SW-01 X X X X X SW-02 X X X X X LT-01 X X X Natural Attenuation Parameters Analysis Total Alkalinity to pH 4.5 BOD COD Cyanide Volatile Fatty Acids Ferrous Iron Nitrate as N Chloride Sulfate TOC Sulfide Ethane, Ethene, Methane Hydrogen Carbon Dioxide Sample Name SM 2320B SM 5210B SM 5220D SM 4500-CN-E AM23G SM 3500-Fe D EPA 9056A SM 9060A SM 4500-5 F AM20GAX AM20GAX MW-01 X X X X X X X X X X X X X MW-02 X X X X X X X X X X X X X MW-03 X X X X X X X X X X X X X X MW-04 X X X X X X X X X X X X X X MW-05R X X X X X X X X X X X X X MW-06 X X X X X X X X X X X X X X MW-07 X X X X X X X X X X X X X X Notes: 1. During Fall semiannual monitoring events, samples are analyzed for Appendix II constituents. Spring semiannual monitoring event samples are analyzed for Appendix I constituents. 2. Appendix II SVOCs are only analyzed for samples collected during the fall semiannual groundwater sampling events. 3. The NCDEQ SWS approved a modified monitoring schedule for Appendix II constituents in December 2016. The approved schedule called for the analysis of Appendix II Herbicides, Appendix II Pesticides, and Appendix II PCBs once every two years. The last monitoring event that included these Appendix II constituents was Fall 2020, with the next event including these constituents scheduled for Fall 2022. 4. Samples from MW-01, MW-02, and MW-05R could not be analyzed for hydrogen. The hydrogen analysis requires the monitoring well to be sampled via the low -flow method, whereas these wells are samples via a disposable bailer. Appendix I and Appendix II constituents were analyzed per Title 40 Code of Federal Regulations (CFR) Part 258. Blank cell: Analysis was not performed on that sample. EPA: Environmental Protection Agency BOD: biochemical oxygen demand COD: chemical oxygen demand TOC: total organic carbon VOCs: volatile organic compounds Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landfill Page 1 of 1 January 2022 Table 2 Well Construction Details and Corresponding Elevations Depth to Elevation of Ground Approx. Approx. Top Depth to Top Bottom of Top Elevation Bottom of Surface TOC Total Well Depth To Groundwater Depth to of Bedrock of Screened Screened of Screened Screened Date Drilled Elevation Elevation Stick Up Depth Water Elevation Bedrock Elevation Interval Interval Interval Interval Geology of Source of Well (feet above (feet below Screened Construction Facility Permit Well ID (mm/dd/yyyy) (feet) (feet) gs) (feet bgs) TOC) (feet) (feet bgs) (feet) (feet bgs) (feet bgs) (feet) (feet) Interval Information 50-02 MW-01 4/23/1992 2,169.40 2,171.42 2.0 110.5 95.62 2,075.80 83.0 2,086.40 95.0 110.0 2,074.40 2,059.40 bedrock S&ME, Inc. 50-02 MW-02 4/22/1992 2,013.15 2,015.38 2.3 60.7 40.16 1,975.22 13.0 2,000.15 45.0 60.0 1,968.15 1,953.15 bedrock S&ME, Inc. partially 50-02 MW-03 4/21/1992 2,044.16 2,045.53 1.3 65.5 48.00 1,997.53 57.0 1,987.16 48.5 63.5 1,995.66 1,980.66 weathered S&ME, Inc. bedrock 50-02 MW-04 4/21/1992 1,978.68 1,980.77 2.0 43.0 25.80 1,954.97 NA NA 25.0 40.0 1,953.68 1,938.68 saprolite S&ME, Inc. Altamont 50-02 MW-05R 1/26/2012 2,027.98 2,030.95 2.8 54.0 46.14 1,984.81 NA NA 44.0 54.0 1,983.98 1,973.98 saprolite Environmental, Inc. 50-02 MW-06 3/23/2004 2,136.58 2,139.57 3.0 94.0 79.95 2,059.62 47.6 2,088.98 84.6 94.6 2,051.98 2,041.98 bedrock Altamont Environmental, Inc. 50-02 MW-07 7/30/2010 1,978.71 1,981.29 2.6 95.0 31.37 1,949.92 44.0 1,935.00 70.0 95.0 1,908.71 1,883.71 bedrock Notes: Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level (msl) and are based on surveying completed by Davenport & Associates, Inc. Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum (NAD) 83 and are based on surveying completed by Wes Cole Land Surveying, P.A. MW-01 through MW-04 Depth to Bedrock and Screened Interval taken from S&ME boring logs completed April 21, 22, and 23, 1992. MW-06 Depth to Bedrock and Screened Interval taken from Altamont Environmental, Inc., boring log completed March 23, 2004. MW-07 Depth to Bedrock and Screened Interval taken from Altamont boring log completed July 30, 2010. MW-05R Screened Interval taken from Altamont boring log completed January 26, 2012. Monitoring well MW-05 was abandoned on January 26, 2012 by NYEG Drilling, LLC. Monitoring well MW-05R was installed on January 26, 2012 as a replacement to the well MW-05 by NYEG Drilling, LLC. The well MW-5R was surveyed by Wes Cole Land Surveying, P.A. on September 28, 2012. Depth to Water was measured on October 19 and 20, 2021. bgs: below ground surface gs: ground surface NA: Not Applicable TOC: top of casing Five -Year Corrective Action Evaluation Report - 2021 Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) MW-01 (Inside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 2L Standard w c R L W O O s v v v N C O O s e O C y N mV w c t W O N O 7 s = v a 41 L N O i O d F V d W t d O O .s F U v G S V 1 c i C R O_ pg/L pg/L I pg/L pg/L pg/L pg/L pg/L pg/L 6 6 1.0 70 0.70 3 0.03 3 4/22/1999 31 3.5 7.9 7.5 3.7 4.3 2.1 NA 10/21/1999 32 ND 8.9 13 ND ND ND NA 4/17/2000 25 ND 6 9.8 ND ND ND NA 10/9/2000 28 ND 9.8 17 NDI ND ND NA 4/17/2001 20 6.61 8.9 12 ND NDI ND NA 10/9/2001 21 9.7 9.9 18 ND ND ND NA 4/10/2002 22 11 12 25 ND ND ND NA 10/9/2002 20 18 14 31 ND 5.5 ND NA 4/17/2003 12 ND 8.3 21 ND ND ND NA 10/20-21/2003 13 8.6 9.6 24 ND ND ND NA 4/27/2004 10 101 7.3 ND 1.8 J N DIND NA 10/18-19/2004 9.1 11 7.5 16 ND ND NA 4/19/2005 10 15 8.1 17 ND ND NA 10/27/2005 9.5 13 7.6 18 ND ND NA 4/13/2006 6.1 14 8 17 ND ND NA 10/10-11/2006 5.4 13 6.7 13 ND ND ND NA 4/3/2007 7.8 151 6.2 11 1.6 1.61 0.58 U NA 10/9/2007 9.8 17.8 6.8 14.4 1.6 1.7 0.62 U NA 4/16/2008 9.0 0.33 U 5.9 10.7 0.46 U 0.95 J 0.67 J NA 10/9/2008 7.9 7.6 5.5 8.7 0.70 J 1.2 0.62 U NA 4/8/2009 6.5 5.6 5.8 10 0.49 J 1.2 0.62 U NA 10/6/2009 7.4 5.3 5.0 9.1 0.48 J 1.0 0.62 U NA 4/13/2010 6.6 11.01 5.2 10.8 0.69 J 1.3 0.62 U NA 10/26/2010 5.0 8.5 IS 9.2 0.46 U 1.1 0.62 U NA 4/13/2011 5.0 0.33 U 2.7 7.7 0.46 U 0.97 J 0.62 U NA 10/26/2011 7.7 9.8 2.1 10.2 0.78 J 1.0 J 0.62 U NA 4/11/2012 6.1 10.9 2.8 8.6 0.78 J 1.1 0.62 U NA 10/23/2012 5.0 10 1.7 8.0 0.68 J 0.94 J 0.62 U NA 4/11/2013 4.8 J 8.0 1.71 6.9 0.77 J 0.75 J 0.78 J NA 10/8/2013 4.5 J 9.5 3.4 10.9 0.60 J 0.91 J 0.62 U NA 4/8/2014 3.5 J 10.0 3.0 8.7 0.67 J 0.76 J 0.62 U NA 10/23/2014 4.0 J 12.8 2.4 7.9 0.6 J 0.71 J 7.7 NA 4/21/2015 4.4 J 11 1.5 7.0 0.44 J 0.90 J 0.35 1 NA 10/13/2015 5.6 141 1.5 9.0 0.85 J 0.96 J 0.097 U NA 4/5/2016 4.7 J 13 2.4 7.2 0.79 J 0.078 U 0.097 U NA 10/11/2016 2.5 J 6.9 1.3 4.5 J 1.2 0.078 U 0.097 U NA 03/21/2017 5.1 12 1.8 8.8 0.99 J 0.078 U 0.097 U NA 10/11/2017 0.083 U 7.5 1b 0.048 U 6.5 0.098 U 0.078 U 0.097 U NA 03/21/2018 3.7 J 13 1.8 5.0 1.0 0.62 J 0.097 U NA 10/17/2018 5 15 2.51 6.5 0.72 0.89 0.097 U 0.52 U 03/21/2019 4.3 13 2.3 6.9 0.66 0.81 0.097 U 0.14 U 10/24/2019 2.3 8 1.6 4.7 0.37 J 0.47 J 0.47 U 0.14 U 03/18/2020 2.7 10 1.4 ND 0.48 J 0.61 0.47 U 0.14 U 10/14/2020 2.8 9.8 1.5 4.5 0.48 J 0.57 0.37 J 0.14 U 03/10/2021 2.62 9.33 1.07 ND 0.098 U 0.545 0.097 U 0.139 U 10/20/2021 2.34 7.76 1.11 3.24 0.220 U 0.52 0.770 U 0.139 U Five -Year Corrective Action Evaluation Report - 2021 Page 1 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) M W-02 (Inside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 21. Standard v S W O O S c a � N d O O L c = y N m v S W O N O 7 L _V V c N L N O O N F V L d O O .� F V d O t _V T C > XOR C O Ng/L pg/L Ng/L pg/L Ng/L pg/L Ng/L Ng/L 6 6 1.0 70 0.70 3 0.03 3 4/22/1999 3.7 ND ND ND ND 1.1 ND NA 10/21/1999 ND ND ND ND ND ND ND NA 4/17/2000 ND ND ND ND ND ND ND NA 10/9/2000 6.S ND ND ND ND ND ND NA 4/17/2001 NDI NDI ND 5.51 ND NDI ND NA 10/9/2001 5.8 ND ND ND ND ND ND NA 4/10/2002 ND ND ND ND ND ND ND NA 10/9/2002 6.7 ND ND ND ND ND ND NA 4/17/2003 ND ND ND ND ND ND ND NA 10/20-21/2003 ND ND ND ND ND ND ND NA 4/27/2004 2.6 NDI ND NDI ND NDI ND NA 10/18-19/2004 ND ND ND ND ND ND ND NA 4/19/2005 ND ND ND ND ND ND ND NA 10/27/2005 ND ND ND ND ND ND ND NA 4/13/2006 ND ND ND ND ND ND ND NA 10/10-11/2006 ND ND ND ND ND ND ND NA 4/3/2007 1.1 0.68 J 0.31 U 1.21 0.16 U 0.26 U 0.58 U NA 10/9/2007 3.3 J 1.8 0.42 J 5.8 0.46 U 0.47 U 0.62 U NA 4/15/2008 1.1 J 0.33 U 0.25 U 1.2 J 0.46 U 0.47 U 0.62 U NA 10/7/2008 1.3 J 0.58 J 0.25 U 1.4 J 0.46 U 0.47 U 0.62 U NA 4/8/2009 0.67 J 0.33 U 0.25 U 0.56 J 0.46 U 0.47 U 0.62 U NA 10/22/2009 0.57 J 0.33 U 0.25 U 0.82 J 0.46 U 0.47 U 0.62 U NA 4/13/2010 0.43 J 0.33 U 0.25 U 0.87 J 0.46 U 0.62 J 0.62 U NA 10/27/2010 0.64 J 0.33 U 0.25 U 1.2 J 0.46 U 0.47 U 0.62 U NA 4/13/2011 0.32 U 0.33 U 0.25 U 0.50 J 0.46 U 0.47 U 0.62 U NA 10/27/2011 1.2 J 0.33 U 0.25 U 1.4 J 0.46 U 0.47 U 0.62 U NA 4/12/2012 0.45 J 0.33 U 0.25 U 0.44 J 0.46 U 0.47 U 0.62 U NA 10/24/2012 0.49 J 0.33 U 0.25 U 0.45 J 0.46 U 0.47 U 0.62 U NA 4/10/2013 0.13 U 0.19 U 0.15 U1 0.55 J 0.17 U 0.15 U 0.32 U NA 10/10/2013 0.45 J 0.33 U 0.25 U 1.2 J 0.46 U 0.47 U 0.62 U NA 4/9/2014 0.49 J 0.33 U 0.25 U 0.55 J 0.46 U 0.47 U 0.62 U NA 10/23/2014 0.39 J 0.33 U 0.25 U 0.71 J 0.46 U 0.47 U 0.62 U NA 4/21/2015 0.39 J 0.12 U 0.09 U 0.40 J 0.20 U 0.15 U 0.72 U NA 10/14/2015 0.79 J 0.050 U 0.048 U 1.0 J 0.098 U 0.078 U 0.097 U NA 4/6/2016 0.083 U 0.050 U 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 10/12/2016 0.083 U 0.05 U 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/22/2017 0.80 J 0.05 U 0.048 U 1.4 J 0.098 U 0.078 U 0.097 U NA 10/11/2017 0.083 U 1.8 Ua 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/21/2018 0.81 J 0.05 U 0.048 U 0.75 J 0.098 U 0.078 U 0.097 U NA 10/18/2018 0.43 J 0.05 U 0.048 U 0.57 0.098 U 0.078 U 0.097 U 3.8 03/21 /2019 0.35 J 0.05 0.048 U 0.55 0.098 U 0.078 U 0.097 U 2.81 10/23/2019 0.29 U 0.42 U 0.34 U 0.44 J 0.31 U 0.046 U 0.41 U 4.0 03/18/2020 0.30 J 0.42 U 0.34 U 0.40 U 0.31 U 0.046 U 0.47 U 3.6 10/13/2020 0.29 J 0.05 U 0.048 U 0.38 J 0.098 U 0.078 U 0.097 U 2.8 03/10/2021 0.083 U 0.05 U 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U 0.139 U 10/20/2021 0.150 U1 0.210 U1 0.180 U 0.200 U 0.220 U 0.180 U 1 0.770 U 1.70 J Five -Year Corrective Action Evaluation Report - 2021 Page 2 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) MW-03 (Inside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 2L Standard w W O O S C v � N 0 O L C C y N cc w W O N O S L y O O L Oy O O = V T N O pg/L pg/L I pg/L pg/L I pg/L pg/L pg/L pg/L 6 6 1.0 70 0.70 3 0.03 3 4/22/1999 7.0 4.8 4.8 5.5 1.0 1.3 1.2 NA 10/21/1999 ND ND ND 5.8 ND ND ND NA 4/17/2000 ND 5.1 ND ND ND ND ND NA 10/9/2000 8.2 10.0 6.1 9.4 ND ND ND NA 4/17/2001 5.4 7.21 ND 7.61 ND NDI ND NA 10/9/2001 6.5 11.0 ND 7.3 ND ND ND NA 4/10/2002 6.0 8.7 ND 7.8 ND ND ND NA 10/9/2002 10.0 ND ND 10.0 ND ND ND NA 4/17/2003 ND 8.3 ND ND ND ND ND NA 10/20-21/2003 5.8 17.0 ND 8.9 ND ND ND NA 4/27/2004 5.4 14.01 3.6 J 6.71 N D N D NDI NA 10/18-19/2004 6.5 18.0 ND 6.3 ND ND ND NA 4/19/2005 ND 14.0 ND 5.2 ND ND ND NA 10/27/2005 6.3 19.0 ND 7.3 ND ND ND NA 4/13/2006 ND 12.0 ND 5.4 ND ND ND NA 10/10-11/2006 ND ND ND 6.7 ND ND ND NA 4/3/2007 2.6 11 2.01 4.41 0.23 J 0.27 J 0.58 U NA 10/9/2007 5.9 18.4 1.7 10.6 0.46 U 0.47 U 0.62 U NA 4/16/2008 1.1 J 0.33 U 1.1 2.8 J 0.46 U 0.47 U 0.62 U NA 10/8/2008 2.7 J 12.6 1.3 5.1 0.46 U 0.47 U 0.62 U NA 4/7/2009 1.01 4.9 0.79 J 2.2 J 0.46 U 0.47 U 0.62 U NA 10/6/2009 1.7 J 8.3 1.7 3.6 J 0.46 U 0.47 U 0.62 U NA 4/13/2010 0.47 J 3.5 1.3 1.0 J 0.46 U 0.52 J 0.62 U NA 10/26/2010 2.7 J 9.5 1.3 4.3 J 0.46 U 0.47 U 0.62 U NA 4/13/2011 0.32 U 0.33 U 0.43 J 0.70 J 0.46 U 0.47 U 0.62 U NA 10/26/2011 2.9 J 11.2 1.2 5.4 0.46 U 0.47 U 0.62 U NA 4/11/2012 0.44 J 2.5 0.58 J 0.81 J 0.46 U 0.47 U 0.62 U NA 10/23/2012 1.8 8.6 1.3 3.5 0.46 U 0.47 U 0.62 U NA 4/10/2013 0.13U 1.8 0.15U 0.15U 0.17U 0.15U 0.32U NA 10/9/2013 0.771 6.41 1.3 1.6 J 0.46 U 0.47 U 0.62 U NA 4/8/2014 0.551 4.2 0.77 J 1.2 0.46 U 0.47 U 0.62 U NA 10/22/2014 1.4 J 10.2 1.2 3.3 0.46 U 0.47 U 0.62 U NA 4/21/2015 0.11 U 2.0 0.09 U 0.63 J 0.2 U 0.15 U 0.72 U NA 10/13/2015 1.3 J 9.2 0.79 J 2.8 0.098 U 0.078 U 0.097 U NA 4/5/2016 0.083 U 2.2 0.53 J 0.056 U 0.098 U 0.078 U 0.097 U NA 10/11/2016 0.60 J 4.71 0.64 J 1.4 J 0.098 U 0.078 U 0.097 U NA 03/21/2017 2.2 J 12 0.57 J 3.8 J 0.098 U 0.078 U 0.097 U NA 10/11/2017 0.083 U 3.7 Jb 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/21/2018 0.083 U 0.53 J 0.048 U 0.056 U 0.098 U 0.078 U a097 U NA 10/16/2018 0.39 J 3.3 0.67 1.1 0.098 U 0.078 U a097 U 7.1 03/20/2019 0.083 U 0.05 U 0.048 U 0.056 U 0.098 U 0.078 U a097 U 1.8 J 10/23/2019 0.30 J 2.91 0.66 0.96 0.31 U 0.046 U a47 U 5.6 03/17/2020 0.29 U 0.42 U 0.34 U 0.40 U 0.31 U 0.046 U a47 U 0.14 U 10/13/2020 0.083 U 0.746 0.048 U 0.056 U 0.098 U 0.078 U a097 U 0.14 U 03/09/2021 0.083 U 0.05 U 0.048 U 0.056 U 0.098 U 0.078 U a097 U 0.139 U 10/20/2021 0.781 5.19 1.19 2.18 0.220 U 0.180 U a770 U 5.96 Five -Year Corrective Action Evaluation Report - 2021 Page 3 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) M W -04 (Outside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 2L Standard w R t W O O S V C v v N O O L a _V C = y N m a d S 0 N O 7 S V 'V O N C L O i O d F v N C L O O .� F u W = C t _V T C > C N O a pg/L pg/L I pg/L pg/L pg/L pg/L pg/L ug/L 6 6 1.0 70 0.70 3 0.03 3 4/22/1999 4 7.9 2.8 24 3.9 3.5 2 NA 10/21/1999 ND 6.7 ND 20 ND ND ND NA 4/17/2000 ND 6.2 ND 15 ND ND ND NA 10/9/2000 ND 5.7 ND 19 ND ND ND NA 4/17/2001 ND 6.21 ND 9.6 ND NDI ND NA 10/9/2001 ND 7.8 ND 171 ND ND ND NA 4/10/2002 ND 7.2 ND 16 ND ND ND NA 10/9/2002 ND ND ND 19 ND ND ND NA 4/17/2003 ND ND ND ND ND ND ND NA 10/20-21/2003 ND 6.3 ND 18 ND ND NDI NA 4/27/2004 NDI 7.51 ND 13 ND ND ND NA 10/18-19/2004 ND 6.6 ND 9.71 ND ND ND NA 4/19/2005 ND ND ND 8.3 ND ND ND NA 10/27/2005 ND 8.9 ND 14 ND ND ND NA 4/13/2006 ND 7.8 ND 11 ND ND ND NA 10/10-11/2006 ND ND ND 13 NDI ND ND NA 4/3/2007 0.501 8.41 1.3 11 0.38 J 0.38 J 0.58 U NA 10/9/2007 3.1 J 11.3 1.8 18.7 0.46 U 0.47 U 0.97 J NA 4/15/2008 0.57 J 0.33 U 1.2 11.0 0.46 U 0.47 U 0.76 J NA 10/7/2008 0.52 J 9.3 1.5 10.7 0.46 U 0.47 U 0.97 J NA 4/8/2009 0.44 J 7.1 1.2 9.61 0.46 U 0.47 U 0.78 J NA 10/7/2009 0.37 J 5.6 1.1 8.8 0.46 U 0.47 U 0.90 J NA 4/13/2010 0.32 U 2.91 0.55 J 4.3 J 0.46 U 0.47 J 0.62 U NA 10/27/2010 0.32 U 4.8 1.1 5.6 0.46 U 0.47 U 0.62 U NA 4/13/2011 0.32 U 0.33 U 0.59 J 3.9 J 0.46 U 0.47 U 0.62 U NA 10/27/2011 0.32 U 6.8 0.89 J 8.6 0.46 U 0.47 U 0.89 J NA 4/12/2012 0.32 U 4.0 0.64 J 5.0 0.46 U 0.47 U 0.69 J NA 10/24/2012 0.32 U 5.8 0.93 J 6.3 0.46 U 0.47 U 1.1 NA 4/10/2013 0.13 U 2.41 0.43 J 2.5 J 0.17 U 0.15 U 0.52 J NA 10/9/2013 0.32 U 3.2 0.49 J 2.9 J 0.46 U 0.47 U 0.62 U NA 4/9/2014 0.32 U 2.6 0.44 J 2.3 0.46 U 0.47 U 0.62 U NA 10/22/2014 0.32 U 4.3 0.67 J 3.31 0.46 U 0.47 U 0.62 U NA 4/22/2015 0.11 U 4.0 0.60 J 3.8 J 0.20 U 0.15 U 0.50 J NA 10/14/2015 0.083 U 5.4 1.0 5.4 0.098 U 0.078 U 0.74 J NA 4/6/2016 0.083 U 2.7 0.048 U 1.8 J 0.098 U 0.078 U 0.097 U NA 10/12/2016 0.083 U 3.3 0.50 J 2.0 J 0.098 U 0.078 U 0.097 U NA 03/22/2017 0.083 U 5.7 0.90 J 6.2 0.098 U 0.078 U 0.097 U NA 10/10/2017 0.083 U 3.0 Jb 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/20/2018 0.083 U 4 0.048 U 3.1 J 0.098 U 0.078 U 0.097 U NA 10/16/2018 0.083 U 2.5 0.35 J 1.3 0.098 U 0.078 U 0.097 U 8.1 03/19/2019 0.083 U 1 0.048 U 0.44 J 0.098 U 0.078 U 0.097 U 3.5 10/22/2019 0.29 U 2 0.34 U 0.74 0.31 U 0.046 U 0.47 U 5.4 03/17/2020 0.29 U 1.3 0.34 U 0.40 U 0.31 U 10.046 U 0.47 U 3.0 10/12/2020 0.083 U 0.85 0.048 U 1 0.46 J 0.098 U 0.078 U 0.097 U 3.4 03/09/2021 0.083 U 1.53 0.236 J 1 0.494 J 0.098 U 0.078 U 0.097 U 2.16 10/19/2021 0.240 U 1 3.02 0.568 1.17 0.220 U 0.180 U 0.770 U 5.56 Five -Year Corrective Action Evaluation Report - 2021 Page 4 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) MW-05 (Inside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 2L Standard v L W O O L V w w N N O O L a V = y N W v L W O N O s _V d L N O N N L O G .� d 9 O t U T C C N O C a pg/L pg/L pg/L pg/L I pg/L pg/L pg/L ug/L 6 6 1.0 70 0.70 3 0.03 3 4/22/1999 3 14 3.4 36 ND NO 2.2 NA 10/21/1999 ND 14 ND 44 ND NO NO NA 4/17/2000 ND 13 ND 44 ND NO NO NA 10/9/2000 ND 12 ND 44 ND ND NO NA 4/17/2001 ND 1s ND 431 ND NDI ND NA 10/9/2001 ND 13 ND 30 ND ND ND NA 4/10/2002 ND ND ND 41 ND ND ND NA 10/9/2002 ND ND ND 38 ND ND ND NA 4/17/2003 NDI 131 ND 32 ND ND ND NA 10/20-21/2003 ND 11 ND 32 ND ND ND NA 4/27/2004 ND 16 2.3J 351 NDI NDI 2.4J NA 10/18-19/2004 ND 1SI NDI 271 NDI ND ND NA 4/19/2005 NOT SAMPLED 10/27/2005 NOT SAMPLED 4/13/2006 NOT SAMPLED 10/10-11/2006 NOT SAMPLED 4/3/2007 0.49 J 17 1.9 32 0.16 U 0.26 U 0.58 U NA 10/9/2007 0.32 U 18.8 1.6 38.1 0.46 U 0.47 U 1.4 NA 4/16/2008 0.35 J 0.33 U 0.56 J 27.4 0.46 U 0.47 U 0.93 J NA 10/10/2008 0.32 U 16.2 1.2 21.6 0.46 U 0.47 U 0.78 J NA 4/7/2009 0.32 J 15.9 1.0 21.6 0.46 U 0.47 U 0.99 J NA 10/7/2009 0.32 U 13.1 1.21 18.41 0.46 U 0.47 U 1 0.93 J NA 4/13/2010 0.32 U 12.1 2.0 17.8 0.46 U 0.55 J 1.51 NA 10/26/2010 0.32 U 13.9 1.8 17.3 0.46 U 0.47 U 1.6 NA 4/13/2011 0.32 U 0.33 U 1.5 17.8 0.46 U 0.47 U 1.1 NA 4/12/2012 0.32 U 2.5 1.3 14.3 0.46 U 0.47 U 0.82 J NA 10/24/2012 0.32 U 3.5 1.3 11.2 0.46 U 0.47 U 0.62 J NA 4/11/2013 0.13 U 3.7 1.5 3.1 J 0.17 U 0.15 U 0.32 U NA 10/9/2013 0.32 U 7.3 2.0 7.0 0.46 U 0.47 U 1 1.0 NA 4/9/2014 0.32 U 6.9 2.2 5.3 0.46 U 0.47 U 2.5 NA 10/23/2014 0.32 U 3.0 1.5 1.8 J 0.46 U 0.47 U 2.9 NA 4/22/2015 0.11 U 5.6 1.4 1.7 J 0.20 U 0.15 U 1.8 NA 10/14/2015 0.083 U 6.5 1.91 2.7 0.098 U 0.078 U 1.8 NA 4/6/2016 0.083 U 6.5 1.9 2.4 0.098 U 0.078 U 2.0 NA 10/12/2016 0.083 U 4.4 0.82 J 2.3 J 0.098 U 0.078 U 0.62 J NA 03/22/2017 0.083 U 10 1.8 10.0 0.098 U 0.078 U 1.3 NA 10/11/2017 0.083 U 6.9 Jb 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 3/21/2018 0.083 U 2.9 1 4.8 J 0.098 U 0.078 U 0.67 J NA 10/17/2018 0.083 U 4.6 1.3 4.0 0.098 U 0.078 U 0.54 5 3/20/2019 0.083 U 5.4 1.4 4.2 0.098 U 0.078 U 2.7 4.3 10/23/2019 0.29 U 7.9 2.1 4.7 0.31 U 0.046 U 1.8 5.8 3/18/2020 0.29 U 6.6 2.1 1.8 0.31 U 0.046 U 2.5 4.9 10/12/2020 0.083 U 3.41 0.048 U 0.41 J 0.098 U 0.078 U 0.097 U 3.5 03/09/2021 0.083 U 6.05 2.271 1.06 0.098 U 0.078 U 2.33 2.87 10/19/2021 0.240 U 6.13 2.38 2.1 0.220 U 0.180 U 1.52 4.34 Five -Year Corrective Action Evaluation Report - 2021 Page 5 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) MW-06 (Outside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 21. Standard v s W O O s _V C d IN, N =y O O s a V C C y N W cc W N O s V L N Q p d L N O `O .s N O C V �, c c _Om G a pg/L pg/L pg/L pg/L pg/L pg/L pg/L ug/L 6 6 1.0 70 0.70 3 0.03 3 4/27/2004 13 14 6.3 18 1.8 ND ND NA 10/18-19/2004 12 9.5 5.7 13 ND ND ND NA 4/19/2005 10 11 6.4 22 ND ND ND NA 10/27/2005 7.9 11 ND 16 ND ND ND NA 4/13/2006 7.3 14 6.3 17 ND ND ND NA 10/10-11/2006 7.9 ND 5.5 15 ND ND ND NA 4/3/2007 9.7 13 4.7 12 1.3 1.5 a58 U NA 10/9/2007 11.3 11.2 3.3 13.2 1.5 1.5 a62 U NA 4/15/2008 11.8 0.33 U 1.9 7.7 0.46 U 0.47 U 0.62 U NA 10/9/2008 12.4 2.1 1.8 7.2 0.46 U 0.861 a62 U NA 4/7/2009 13.0 3.21 1.4 7.11 0.81 J 1.4 a62 U NA 10/6/2009 2.71 1.3 0.56 J 4.2 J 0.46 U 0.47 U a62 U NA 4/13/2010 1.1 J 3.9 1.7 5.9 0.46 U 0.47 U a62 U NA 10/26/2010 5.4 7.9 4.3 12.0 0.46 U 1.2 a62 U NA 4/13/2011 0.85 J 4.6 1.8 5.4 0.46 U 0.47 U 0.62 U NA 10/26/2011 3.8 J 6.0 2.3 8.4 0.46 U 0.47 U 0.91 J NA 4/11/2012 6.7 4.31 2.5 8.6 0.46 U 0.47 U 1 0.62 U NA 10/23/2012 5.3 7.0 2.8 8.8 0.46 U 0.76 J 0.62 U NA 4/11/2013 6.1 5.8 1.9 5.1 0.17 U 0.78 J 0.32 U NA 10/8/2013 5.4 11.1 2.9 10.4 0.67 J 0.80 J 0.62 U NA 4/8/2014 5.0 8.2 3.0 10.9 0.49 J 0.85 J 0.62 U NA 10/22/2014 4.4 9.8 2.7 8.91 0.50 J 0.81 J 0.62 U NA 4/21/2015 6.2 9.31 2.4 7.2 0.32 J 0.85 J 1 0.72 U NA 10/13/2015 6.4 8.1 1.5 7.7 0.098 U 0.73 J 0.097 U NA 4/5/2016 4.0 J 6.9 0.048 U 3.6 0.098 U 0.078 U 0.097 U NA 10/11/2016 1.9 J 3.1 0.048 U 1.9 J 0.098 U 0.078 U 0.097 U NA 03/21/2017 4.4 J 4.9 0.69 J 4.5 J 0.098 U 0.078 U 0.097 U NA 10/11/2017 0.083 U 2.5 U 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/21/2018 4.2 J 3.6 0.048 U 3.4 J 0.72 J 0.078 U a097 U NA 10/18/2018 3.1 0.31 Jb 0.048 U 1.5 0.098 U 0.32 J a097 U 0.52 U 03/21/2019 2.2 0.05 U 0.048 U 1.6 0.098 U 0.26 J a097 U 0.14 U 10/23/2019 1.6 2.1 0.34 U 1.2 0.31 U 0.46 U a47 U 0.14 U 03/18/2020 1.2 0.42 U 0.34 U 1 0.31 U 0.46 U a47 U 0.14 U 10/13/2020 1.4 2.6 0.26 J 1.4 0.25 J 0.078 U a097 U 0.14 U 03/10/2021 0.907 1.04 0.048 U 0.781 0.098 U 0.078 U a097 U 0.139 U 10/20/2021 0.833 1.431 0.180 U 0.676 0.220 U 0.180 U a770 U 0.139 U Five -Year Corrective Action Evaluation Report - 2021 Page 6 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) M W -07 (Outside Compliance Boundary) Sample Collection Date Volatile Organic Compound with 2L Standard a A L G O O L V IL _ C w N N O O V L a C = y N ca a d L G O N O s _V 'V is N C ) N O O F V d C L O O .� F V � O O t _V T C > W N O C a pg/L pg/L I pg/L pg/L pg/L pg/L pg/L ug/L 6 6 1.0 70 0.70 3 0.03 3 8/11/2010 0.87 J 0.51 J 0.76 J 4.9 0.46 U 1.0 0.62 U NA 4/13/2011 0.54 J 3.7 1.1 8.7 0.46 U 0.47 U 0.62 U NA 10/27/2011 0.71 J 5.0 1.1 12.5 0.46 U 0.47 U 0.65 J NA 4/12/2012 0.54 J 5.7 1.4 10.5 0.46 U 0.47 U 0.82 J NA 10/24/2012 0.57 J 4.91 1.4 9.01 0.46 U 0.47 U 0.68 J NA 4/10/2013 0.47 J 6.4 1.7 9.0 0.17 U 0.15 U 0.89 J NA 10/9/2013 0.38 J 6.0 1.4 7.5 0.46 U 0.47 U 0.62 U NA 4/9/2014 0.40 J 5.1 1.3 7.2 0.46 U 0.47 U 0.62 U NA 10/23/2014 0.32 U 5.7 1.1 5.4 0.46 U 0.47 U 0.62 U NA 4/22/2015 0.32 J 5.3 1.2 5.8 0.20 U 0.15 U 0.30 J I NA 10/14/2015 0.083 U 6.61 1.7 6.2 0.098 U 0.078 U 0.55 J NA 4/6/2016 0.083 U 6.8 1.6 4.6 0.098 U 0.078 U 0.097 U NA 10/12/2016 0.083 U 3.3 0.87 J 2.2 J 0.098 U 0.078 U 0.097 U NA 03/22/2017 0.083 U 5.5 1.6 4.5 J 0.098 U 0.078 U 0.097 U NA 10/10/2017 0.083 U 3.4 Jb 0.048 U 0.056 U 0.098 U 0.078 U 0.097 U NA 03/20/2018 0.083 U 6.1 1.7 3.1 J 0.098 U 0.078 U 0.097 U NA 10/17/2018 0.083 U 3.2 J 1.5 2.8 0.098 U 0.078 U 0.097 U 16 03/19/2019 0.083 U 4.5 1.4 2.3 0.098 U 0.078 U 0.097 U 18 10/22/2019 0.29 U 4.4 1.2 2.2 0.31 U 0.046 U 0.47 U 18 03/17/2020 0.29 U 3.6 1.1 1.8 0.31 U 0.046 U 0.47 U 17 10/12/2020 0.083 U 2.66 1.4 2.6 0.098 U 10.078 U 1 0.097 U 17 03/09/2021 0.083 U 5.46 1.36 2.22 0.098 U 1 0.078 U 1 0.097 U 16.3 10/19/2021 0.240 U 7.05 1.82 2.73 0.220 U 0.180 U 0.170 U 13.7 Five -Year Corrective Action Evaluation Report - 2021 Page 7 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 3 Summary of Historical Groundwater Analytical Data (Detected VOCs Above 2L Standard) Notes: Bold and Highlighted: Detected concentration is greater than the NC2L standard Italicized: Non -detected concentration is above one or more identified NC2L standard Sampling dates occurred while leachate extraction was active NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013 All nondetect results are reported at the method detection limit. lag/L: micrograms per liter J: Estimated value Jb: Estimated value. Compound is analyzed by USEPA 8270D and USEPA 8260D, the most protective result is reported. Ua: Compound analyzed for, but not detected above minimum detection limit. Compound is analyzed by USEPA 8270D and USEI U: Compound analyzed for, but not detected above minimum detection limit. ND: Nondetect result, method detection limit not previously reported. NA: Compound was not analyzed. 1,4-Dioxane analysis by USEPA 8260D SIM began in 2018. Five -Year Corrective Action Evaluation Report - 2021 Page 8 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01) Sample Dates Detected Volatile Organic Compounds Concentration in LT-01 (mg/L) Cumulative Flow at Gauge (gallons) Differential Flow (gallons) Mass Removed (pounds) Estimated Cumulative Mass Removed (pounds) Beginning Ending 9/1/2012 10/25/2012 1,4-Dichlorobenzene 0.0034 11,500 11,500 0.00033 4-Meth I-2 entanone (MIBK) 0.0021 J 0.00020 Acetone 0.0292 0.00280 Benzene 0.0021 0.00020 Chlorobenzene 0.0029 0.00028 cis-1,2-Dichloroethene 0.00063 J 0.00006 Dichlorodifluoro-methane 0.00093 J 0.00009 Eth (benzene 0.0102 0.00098 Naphthalene 0.0069 0.00066 Styrene 0.00033 J 0.00003 Toluene 0.003 0.00029 Total X lenes 10.0094 0.00090 Total 0.00681 0.00681 10/26/2012 4/11/2013 1,4-Dichlorobenzene 0.006 65,500 54,000 1 0.00270 Acetone 0.012 J 0.00540 Benzene 0.0011 0.00049 Carbon disulfide 0.0067 J 0.00301 Chlorobenzene 0.0024 J 0.00108 cis-1,2-Dichloroethene 0.00058 J 0.00026 Eth (benzene 0.0083 0.00373 Toluene 0.00059 J 0.00027 Total X lenes 0.0078 0.00351 Total 0.02045 0.02726 4/12/2013 10/8/2013 1,4-Dichlorobenzene 0.0055 114,737 1 1 49,237 0.00226 4-Meth I-2 entanone (MIBK) 0.0012 J 0.00049 Benzene 0.0020 0.00082 Chlorobenzene 0.0039 0.00160 cis-1,2-Dichloroethene 0.00080 J 0.00033 Eth lbenzen 10.0151 1 0.00619 Naphthalene 10.0184 1 0.00754 Toluene 10.0012 0.00049 Total X lenes 10.0090 H 0.00369 Total 0.02341 0.05067 10/9/2013 4/8/2014' 1,4-Dichlorobenzene 0.0056 164,437 49,700 0.00232 Benzene 0.0018 0.00075 Chlorobenzene 0.0051 0.00211 cis-1,2-Dichloroethene 0.00049 J 0.00020 Eth (benzene 0.0047 0.00195 Toluene 10.00041 J 0.00017 Total X lenes 10.0021 J 0.00087 Total 0.00836 0.05903 4/8/2014 10/23/2014 1,4-Dichlorobenzene 0.0053 200,148 35,710 0.00158 Benzene 0.0014 0.00042 Chlorobenzene 0.003 0.00089 cis-1,2-Dichloroethene 0.00049 J 0.00015 Eth (benzene 0.0027 0.00080 Toluene 10.00051 J 0.00015 Total X lenes 10.0014 J 0.00042 Total 0.00440 0.06343 10/23/2014 4/21/2015 1,2,3-Trimethyl benzene 0.00062 241,700 41,552 1,2,4-Trimethyl benzene 0.00076 0.00026 2-Chlorotoluene 0.00067 1,4-Dichlorobenzene 0.0059 Acetone 0.00790 -7=277- Benzene 0.0022 7 Chlorobenzene 0.003 0.00104 Eth (benzene 0.0056 4 I sopropylbenzene 0.0013 0.00045 Methy Tert-butyl- Ether 0.0013 45 Na thalene 0.024 n-Pro (benzene 0.00088 Tetrah drofuran 0.089 Toluene 0.00054 J0.0001 Vinyl Chloride 0.00038 Total X lenes 10.0030 J 4 TotaT- 0.05089 0.11432 4/21/2015 10/13/2015 1,4-Dichlorobenzene 0.00600 278,420 1 1 36,720 0.00183 2-Butanone 0.00960 J 0.00294 Benzene 0.00210 0.00064 Chlorobenzene 0.0040 0.00122 Eth (benzene 0.00710 0.00217 Naphthalene 10.021 1 0.00642 Tetrah drofuran 10.062 1 0.01896 Toluene 10.00058 J 0.00018 Total X lenes 10.0031 J 0.00095 Total 0.03531 0.14963 10/13/2015 4/5/2016 1,4-Dichlorobenzene 0.00590 337,398 1 58,978 0.00290 Benzene 0.00170 0.00083 Chlorobenzene 0.0038 0.00187 Eth (benzene 0.00500 0.00246 Toluene 0.00063 J 0.00031 Total X lenes 10.0025 1 J 0.00123 Total 0.00959 0.15922 4/5/2016 10/11/20162 No detected compounds. 352,745 15,347 0.00000 Total 0.00000 0.15922 Jackson County Closed Municipal Solid Waste Landfill Page 1 of 2 Jackson County, North Carolina December 2021 Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01) Sample Dates Detected Volatile Organic Compounds Concentration in LT-01 (mg/L) Cumulative Flow at Gauge (gallons) Differential Flow (gallons) Mass Removed (pounds) Estimated Cumulative Mass Removed (pounds) Beginning Ending 10/11/2016 3/21/2017 1,4-Dichlorobenzene 0.0046 355,947 3,202 0.00012 Acetone 0.0094 J 0.00025 Benzene 0.0015 0.00004 Chlorobenzene 0.0043 0.00011 Eth (benzene 0.0014 0.00004 Tetrah drofuran 0.066 0.00176 Total X lenes 0.0015 J 0.00004 Total 0.00237 0.16159 3/21/2017 10/11/2017 1,4-Dichlorobenzene 0.0041 386,495 30,548 0.00104 Acetone 0.0067 J 7 Acetonitrile 0.008 J 0.00204 Benzene 0.00061 0.00016 Chlorobenzene 0.0012 Eth lbenzen 10.00087 0.00022 Na hthalene 10.0012 Tetrah drofuran 10.12 5 Total 0.03630 0.19789 10/12/2017 10/18/2018' 1,4-Dichlorobenzene 0.0028 398,872 12,377 0.00029 Acetone 0.017 0.00175 Benzene 0.0012 0.00012 Chlorobenzene 0.0024 0.00025 Eth (benzene 0.0018 0.00019 Meth lene Chloride 10.00034 J 0.00004 Total X lenes 10.00098 J 0.00010 Total 0.0027 0.20062 10/18/2018 10/22/2019' 1,4-Dichlorobenzene 0.0037 407,807 8,936 0.00028 Acetone 0.006 0.00045 Benzene 0.0017 0.00013 Chlorobenzene 0.0038 0.00028 Eth (benzene 0.0016 0.00012 Toluene 10.00039 J 0.00003 Total X lenes 10.0017 J 0.00013 Total 0.0014 0.20203 10/22/2019 3/18/2020' 1,4-Dichlorobenzene 0.0056 539,644 131,836 0.00615 1,4-Dioxane 0.06 0.06585 Acetone 0.0064 0.00702 Benzene 0.0013 0.00143 Chlorobenzene 0.0032 0.00351 Eth (benzene 0.0027 0.00296 Methyl isobutyl ketone 0.00079 J 0.00087 Toluene 0.00070 0.00077 Total X lenes 0.00209 J 0.00229 Total 0.0886 0.29058 3/18/2020 10/14/2020' 1,2-Dichloroethene, cis- 0.00029 J 639,343 99,699 0.00024 1,3-Dichlorobenzene 0.00027 J 0.00022 1,4-Dichlorobenzene 0.0048 0.00398 1,4-Dioxane 0.058 0.04814 Acetone 0.011 0.00913 Acetonitri a (Et anenitri e) 0.0047 J 0.00390 Benzene 0.0024 0.00199 Chlorobenzene 0.0044 0.00365 Chloroethane 0.00047 J 0.00039 Eth (benzene 0.0018 0.00149 Naphthalene 0.013 0.01079 Tetrah drofuran 0.094 0.07802 Toluene 0.00079 0.00066 Total X lenes 0.0037 0.00307 Vinyl chloride 0.00022 J 0.00018 Total 0.1659 0.45645 10/14/2020 10/20/2021 1,4-Dichlorobenzene 0.00385 701,994 62,651 1,4-Dioxane 4 17 54 Acetone 4 4 5 Benzene 45 Chlorobenzene • 4 Eth (benzene 44 Naphthalene 10.0136 1 Tetrah drofuran 10.2035 Total X lenes 1U.UUZ8147 Total 0.1501 0.60659 Notes: 1. Totalizer readings were not recorded during the sampling event and the differential flow was calculated based on an interpolated totalizer reading using monthly readings taken by the Tuckaseigee Water and Sewer Authority (TWSA) for 3 months before and after the sample date. 2. No VOCs were detected in the leachate sample collected during the October 2016 sampling event. 3. In March 2018, the totalizer at the TWSA connection was replaced. During the March 2018 sampling event, Anchor QEA began reading an incorrect totalizer for the volume of extracted the leachate. Differential flow was calculated for the sample dates in the same manner as Note 1. This table has been updated to reflect the updated totalizer readings from previous groundwater monitoring reports. Total Xylenes represent the sum of m,p-Xylenes and o-Xylenes. Only detected volatile organic compounds (VOCs) in leachate sample LT-01 are included in the mass removal calculation Leachate extraction at the landfill was initiated on September 1, 2012. Connection to the TWSA sewer was completed on September 6, 2013. Up until the connection to the TWSA sewer, leachate was pumped into a temporary collection tank and then hauled off site. Extraction volume measurements for leachate hauled off site were recorded and provided by Jackson County staff. Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next sampling event occurs, and that the leachate removal system has a 100% removal and treatment efficiency. Differential flow represents the total flow between the LT-01 sample dates. Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the concentration by the differential flow for the specified period. Formula: ((concentrationrma/Ll)*(2.2e-6 Ib)/(0.264 oal))*(Differential flow). mg/L: milligrams per liter J: Indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit. Jackson County Closed Municipal Solid Waste Landfill Page 2 of 2 Jackson County, North Carolina December 2021 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 SW336 124-38-9 16887- 00-6 or SW301 I SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L Ng/L Ng/L nM pg/L Ng/L Ng/L Ng/L Ng/L Ng/L pg/L Ng/L Ng/L mg/L mg/L mg/L 10/26/2011 5.57 1.33 -31.5 NA 5,000 U 5,800 NA 200 U 5 U 5 U 2,060 12,100 NA NA 5,000 U 100 U NA NA NA 4/11/2012 5.80 1.19 -111.1 250 5,000 U 2,800 42 200 U 6.2 U 6.2 U 5,360 4,600 8,300 NA 5,000 U 100 U 0.062 J 0.022 J 0.058 J 10/23/2012 5.43 0.27 45.2 160 1,200 16,400 5.4 32 J 0.86 U 0.79 U 3,130 1,000 U 2,000 U 25,000 U 2,300 J 100 U 0.032 U 0.021 U 0.044 J 4/11/2013 6.03 0.31 2.6 150 1,000 U 20,000 1.8 20 U 0.86 U 0.79 U 1,550 7,500 2,800 25,000 U 3,000 J 100 U 2.3 U 1.8 U NA 10/8/2013 5.75 0.26 12.1 120 1,500 34,600 1.7 20 U 0.86 U 0.79 U 6,150 12,800 9,600 25,000 U 2,000 U 100 U NA NA NA 4/8/2014 5.85 1.87 17.2 280 1,100 27,500 0.90 20 U NA NA NA 23,300 6,000 36000 4000 J 100 U 0.08 0.15 NA 10/23/2014 5.91 1.20 41.5 320 1,200 25,700 NA 10 U 3.1 U 3.1 U 3,320 31,500 4,900 36,000 1,600 J 100 U 0.098 J 0.21 0.11 4/21/2015 2.08* 2.04 314.3 NA 740 J 15,000 NA 23 U 4.1 U 4.3 U 1,400 7,100 5,000 U 16,000 88 J 10 U 5.0 U NA 10/13/2015 5.75 1.03 66.4 360 510.1 15,000 NA 39 J 0.1 U 0.1 U 3,000 6,700 6,000 27,000 600 J 830 U 0.2 U 0.1 U 0.1 U 4/5/2016 6.05 4.42 57.5 220 820 J 65,000 NA 85 J 0.1 U 0.1 U 2,300 4,800 5,300 7,300 U 540 J 830 U 0.2 U 0.10 0.1 U MW-01 10/11/2016 5.83 0.99 66.1 290 880 J 36,000 NA 70 J 0.1 U 0.1 U 2,400 30,600 5,600 91,000 550.1 ND ND 0.96 0.10 U 03/21/2017 5.77 1.70 39.7 280 880 J 24,000 NA 17 U 0.1 U 0.1 U 1,700 11,800 1,800 J 29,000 J 820 J ND ND 0.1 U ND 10/11/2017 5.78 5.47 48.0 240 810 J 13,000 NA 110.1 0.1 U 0.1 U 1,200 10,600 1,800 J 17,000 U 200 U ND ND 0.13 0.2 U 03/21/2018 5.79 1.37 50.2 180 670J 6,600 NA 17J 0.1 U 0.1 U 620 20,900 3,900 28,000J 2000 ND ND 0.1 U ND 10/17/2018 5.59 2.08 89.7 300 N 880 J 12,000 NA 190 0.1 U,N 0.1 U,N 880 N 2,490 2,400 17,000 U 680 J 830 U ND 0.10 U,M3,M5 0.20 U,B 03/21/2019 5.96 1.53 45.3 280 850 J 37,000 NA 57 J 0.16 0.1 U 1,800 2,190 13,000 97,000 490 U 1200 J NA 0.91 0.22 10/24/2019 6.00 5.11 52.1 150 1,500 34,000 HT NA 54 U 0.10 U 0.10 U 740 1,770 8,400 53,000 480 U 16,000 ND 0.36 0.50 U 03/18/2020 6.05 2.94 21.6 270 N 1,100 35,000 HT NA 54 U 0.088 J,N 0.056 J,N 2700 N 9,070 10,000 38,000 J 480 U 830 U 0.085 U 49 J 120 U 10/14/2020 5.70 1.47 30.5 128 1,200 39,000 NA 45 U 0.075 U 0.12 U 4,000 1,780 3,100 24,000 J 560 U 830 U 0.053 U 0.45 J 5.4 03/10/2021 5.8 2.56 -11.3 108 1,110 38,900 NA 45 U 0.075 U 1 0.12 U 1,700 1,140 2,000 U 11,000 U 560 U 830 U 0.053 U 0.15 J 7.6 10/20/2021 5.601 2.071 27.11 NA 866 JI 32,900 NAI 76.0 U I NAI NAI NAI 1,8901 8,800 74,0001 540 U1 830 U1 NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 1 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 SW336 124-38-9 16887- 00-6 or SW301 SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L pg/L pg/L nM pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L Ng/L mg/L mg/L mg/L 10/27/2011 5.44 4.96 158.7 NA 28,500 500 U NA 200 U 5 U 5 U 5 U 3,700 NA NA 6,300 J 100 U NA NA NA 4/12/2012 6.28 4.30 -85.5 27 26,200 500 U 3.9 250 6.2 U 6.2 U 2.5 J 1,700 2,000 U NA 6,600 100 U 0 0.12 0.047 J 10/24/2012 5.63 3.74 165.6 45 20,000 500 U 0.89 290 J 0.86 U 0.79 U 11.5 4,000 2,000 U 25,000 U 8,100 J 100 U 0.032 U 0.08 0.01 U 4/10/2013 6.03 6.11 171.9 34 18,200 500 U 0.71 170 J 0.86 U 0.79 U 3.3 U 2,100 2,000 U 25,000 U 7,800 J 100 U 2.3 U 1.8 U NA 10/10/2013 5.84 0.95 104.5 36 22,300 500 U 0.78 21 J 0.86 U 0.79 U 658 5,300 2,000 U 25,000 U 8,800 J 100 U NA NA NA 4/9/2014 6.07 3.84 170.4 28 26,500 500 U 1.4 250 NA NA NA 3,000 2000 U 29,000 8800 J 100 U 0.050 J 0.09 0.12 10/23/2014 5.51 6.20 176.4 94 15,500 500 U NA 180 3.1 U 3.1 U 3.3 U 16,200 4,300 45,000 4,600 100 U 0.14 0.10 0.13 4/21/2015 5.14 5.74 286.7 NA 250,000 71 NA 2,200 J 4.1 U 4.3 U 7.5 J 1,600 5,000 U 3000 U 66,000 J NA 10 U 5.0 U NA 10/14/2015 6.18 7.30 236.4 80 22,000 39 U NA 98 J 0.1 U 0.1 U 0.5 U 1,100 J 1,200 J 100,000 11,000 J 6,600 U 0.2 U 0.15 0.1 U 4/6/2016 6.51 6.53 123.4 41 23,000 22 U NA 230 J 0.1 U 0.1 U 0.5 U 780 J 260 J 7,300 U 9,400 J 830 U 0.2 U 0.1 U 0.1 U MW-2 10/12/2016 6.59 4.38 139.8 53 18,000 71 U NA 140 J 0.18 0.1 U 0.5 U 5,600 260 J 94,000 8,600 J ND ND 0.38 0.10 U 03/22/2017 6.62 6.24 203.3 59 29,000 71 U NA 390 J 0.1 U 0.1 U 0.5 U 8,500 J 2,000 U 300,000 13000 J ND ND 0.13 ND 10/11/2017 6.26 7.47 189.2 67 820 J 37 J NA 150.1 0.1 U 0.1 U 8.7 2,600 2,000 U 17,000 U 670 J ND ND 0.44 0.2 U 03/21/2018 6.06 4.76 234.1 87 22,000 14 U NA 250 J 0.1 U 0.1 U 0.5 U 10,200 1,400 J 39,000 J 7600 ND ND 0.38 ND 10/18/2018 6.24 4.94 210.0 41 N 23,000 46 U NA 130 0.1 U,N 0.1 U,N 0.5 U,N 1,410 J 7,100 18,000 J 14,000 830 U ND 0.46 M3,M5 0.20 U,B 03/21/2019 6.19 8.01 279.3 54 19,000 46 U NA 340 0.1 U 0.1 U 0.5 U 2,440 1,000 J 27,000 J 10,000 1200 J NA 0.18 0.2 U 10/23/2019 6.34 10.45 123.1 49 27,000 51 HT,U NA 170 J 0.10 U 0.10 U 0.50 U 5,240 210 BB,U 19,000 J 21,000 830 U ND 0.35 0.50 U 03/18/2020 6.09 5.44 261.9 60 N 29,000 59 HT,J NA 530 0.005 U,N 0.0082 J,N 0.1 J,N 2,970 2,500 22,000 J 15,000 830 U 0.085 U 440 120 U 10/13/2020 7.1 # 5.08 -57.3 37.1 25,000 46 U NA 170 J 0.075 U 0.12 U 5 2,260 2,300 37,000 J 20,000 830 U 0.053 U 0.76 5.1 03/10/2021 6.0 6.23 137.9 29.6 19,100 50 U NA 355 0.075 U 1 0.12 U 4.3 J 4,960 4,000 11,000 U 10,400 830 U 0.11 U 0.39 J 13 10/20/2021 5.20 5.92 407.61 NAI 20,1001 80.0 J NAI 2551 NAI NAI NAI 1,4501 2,000 U 1 38,000 J 1 27,0001 4000 NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 2 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 SW336 124-38-9 16887- 00-6 or SW301 SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L Ng/L Ng/L nM Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L pg/L Ng/L Ng/L mg/L mg/L mg/L 10/26/2011 4.52 0.49 157.9 NA 46,700 500 U NA 410 J 5 U 5 U 56.8 15,000 NA NA 5,000 U 100 U NA NA NA 4/11/2012 5.53 0.25 134.6 190 37,000 500 U 170 3,200 6.2 U 6.2 U 21.8 5,500 2,000 U NA 5,000 U 100 U 0.081 J 0.056 J 0.068 J 10/23/2012 5.58 0.99 -109.3 150 50,600 500 U 0.74 560 J 0.86 U 0.79 U 6.5 J 11,800 2,000 U 25,000 U 2,700 J 100 U 0.22 0.021 U 0.01 U 4/10/2013 5.75 0.55 153.4 140 30,900 500 U 0.38 J 6,000 J 0.86 U 0.79 U 4.0 J 6,300 2,000 U 25,000 U 2,100 J 100 U 2.3 U 1.8 U NA 10/9/2013 5.51 0.26 104.3 270 38,900 500 U 59 2,000 J 0.86 U 0.79 U 79.2 14,500 2,000 U 29,000 2,200 J 100 U NA NA NA 4/8/2014 5.54 0.59 178.9 350 30,500 500 U 4.7 4,500 NA NA NA 12,200 2,000 U 36,000 3900 100 U 0.14 0.020J 0.098 J 10/22/2014 5.39 0.81 183.6 320 42,100 500 U 6.5 1,700 3.1 U 3.1 U 9.5 45,000 2,000 U 27,000 2,200 100 U 0.053 J 0.037 J 0.10 4/21/2015 3.29* 0.25 372.5 270 29,000 35 J 1.5 8,900 J 4.1 U 4.3 U 5.6 J 4,800 5,000 U 11,000 280JI 10 U 5.0 U NA 10/13/2015 5.63 1.28 325.7 220 39,000 39 U 5.4 3,200 J 0.02 U 0.02 U 1.1 2,000 J 5,100 11,000 J 1,300 J 830 U 0.2 U 0.1 U 0.1 U 4/5/2016 5.48 0.45 200.9 190 27,000 22 U 15 13,000 0.014 0.059 0.5 1,900 J 220 J 7,300 U 570 J 1,000 J 0.2 U 0.1 U 0.1 U MW-3 10/11/2016 5.60 0.64 204.1 380 40,000 71 U 38 3,600 J 0.036 0.170 0.78 22,000 520 J 38000 J 1,100 J ND ND 0.36 0.10 U 03/21/2017 5.58 1.59 259.5 380 40,000 140 J 51 1,900 J, B 0.018 0.042 3.30 10,500 120 J 14,000 U 2000 J ND ND 0.1 U ND 10/10/2017 5.57 2.82 284.8 340 32,000 17 J 21 6,900 0.01 U 0.026 4.6 6,100 600 J 73,000 850 J ND ND 0.10 0.52 03/21/2018 5.81 3.22 263.1 120 19,000 14 U 24 11,000 0.02 U 0.02 U 0.48 14,200 1,100 J 47,000 J 530 J ND ND 0.1 U ND 10/16/2018 5.63 0.34 244.1 200 N 31,000 46 U 38 11,000 0.2 U,D,N 0.2 U,D,N 0.98 D,N 2,380 100.1 26,000 J 1,700 J 830 U ND 0.39 M3,M5 0.20 U 03/20/2019 6.71 9.44 236.3 55 20,000 150.1 120 3,400 0.02 U 0.02 U 0.2 U 9,360 1900 J 48,000 J 7,200 1400 J NA 0.1 U 0.55 10/23/2019 5.87 0.83 263.7 260 31,000 51 HT,U 21 7,600 0.01 U 0.027 15 11,000 210 BB,U 23,000 J 4,400 35,000 ND 0.10 U 0.50 U 03/17/2020 6.79 8.00 242.1 49 N 15,000 51 HT,U 120 430 0.005 UN 0.013 J,N 0.2 J,N 6,160 300 J 22,000 J 6,200 830 U 0.085 U 48 J 120 U 10/13/2020 8.1 # 3.28 -112.4 14.7 8,500 46 U 43 8,300 0.075 U 0.12 U 3.5 4,680 2,000 J 35,000 J 4,000 830 U 0.072 J 0.95 4.8 03/09/2021 6.7 6.83 197.1 8.31 16,800 50 U 190 3,590 0.075 U 1 0.12 U 3.1 J 2,430 2,000 U 11,000 U 3,770 29,700 0.053 U 0.14 J 6.9 10/20/2021 5.201 0.831 545.81 NAI 32,5001 50.0 U NAI 3,7101 NAI NA NAI 2,410 2,000 U 41,000 J 1000 B 830 U NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 3 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 SW336 124-38-9 16887- 00-6 or SW301 SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L pg/L pg/L nM pg/L pg/L pg/L pg/L pg/L Ng/L pg/L pg/L Ng/L mg/L mg/L mg/L 10/27/2011 5.39 2.99 532.3 NA 92,600 500 U NA 2,500 J 5 U 5 U 1,410 172,000 NA NA 71,100 J 100 U NA NA NA 4/12/2012 5.66 1.09 6.8 240 71,700 500 U 62 7,700 6.2 U 6.2 U 544 6,500 2,000 U NA 10,000 U 100 U 0.11 0.031 J 0.063 J 10/24/2012 5.27 0.21 502.0 230 83,400 500 U 19 4,000 J 0.86 U 0.79 U 889 14,400 2,000 U 25,000 U 105,000 J 100 U 0.032 U 0.021 U 0.01 U 4/10/2013 5.56 1.40 186.2 250 46,200 500 U 20 14,600 0.86 U 0.79 U 9.1 8,600 2,000 U 25,000 U 62,500 J 100 U 2.3 U 1.8 U NA 10/9/2013 5.48 0.42 122.3 230 48,600 500 U s0 11,900 J 0.86 U 0.79 U 883 10,200 2,000 U 25,000 U 108,000 J 100 U NA NA NA 4/9/2014 5.63 0.44 220.7 190 42,700 500 U 7.8 8,200 NA NA NA 11,100 2,000 U 25,000 U 80,200 100 U 0.23 0.028J 0.13 10/22/2014 5.42 0.39 377.9 390 75,200 500 U 33 2,700 3.1 U 3.1 U 1,420 65,400 2,000 U 45,000 95,500 100 U 0.055 J 0.040 J 0.10 4/22/2015 3.90* 0.31 637.9 300 60,000 45 J 7.9 3,500 J 4.1 U 4.3 U 930 3,800 5,000 U 6,200 J 65,000 J 10 U 5.0 U NA 10/14/2015 5.66 0.53 347.9 360 72,000 39 U 11 2,200 J 0.023 0.01 U 460 2,900 J 370 J 18,000 J 70,000 J 1,000 J 0.2 U 0.1 U 0.1 U 4/6/2016 5.66 0.80 191.5 190 40,000 22 U 17 7,500 J 0.012 0.021 160 1,900 J 2,200 U 7,300 U 69,000 J 830 U 0.2 U 0.1 U 0.1 U MW-4 10/12/2016 5.77 0.50 159.5 340 81,000 71 U 230 950.1 0.043 0.024 570 26,200 1100.1 39000 J 80,000 J ND ND 0.58 0.10 U 03/22/2017 5.75 2.86 210.5 300 89,000 71 U 50 440 J 0.031 0.031 180 17,500 860 J 110,000 67000 J ND ND 0.1 U ND 10/10/2017 5.73 1.53 227.4 440 80,000 14 U 79 1,600 0.031 0.017 110 10,700 1,300 J 46,000 J 67,000 J ND ND 0.16 0.73 03/20/2018 5.80 4.61 535.7 320 61,000 14 U 220 3,900 J 0.032 0.01 U 59 24,200 2,000 U 38,000 J 56000 ND ND 0.1 U ND 10/16/2018 5.86 3.47 323.4 210 N 60,000 46 U 4.8 N 4,300 0.2 U,D,N 0.2 U,D,N 25 D,N 3,020 J 2,000 U 29,000 J 71,000 2,400 ND 0.45 M3,M5 0.20 U 03/19/2019 5.92 5.24 419.7 140 27,000 46 U 110 11,000 0.02 U 0.02 U 1 14 600 U 3,200 17,000 U 63,000 10001 NA 0.1 U 0.62 10/22/2019 5.89 6.42 359.4 330 47,000 51 HT,U 100 5,300 0.014 0.01 U 110 5,910 820 BB,J,B 10,000 U 78,000 11,000 ND 0.10 U 0.50 U 03/17/2020 5.84 2.02 506.2 220 N 30,000 51 HT,U 13 8,300 0.018 J,N 0.004 U,N 83 N 5,850 210 U 74,000 110,000 830 U 0.085 U 43 U 120 U 10/12/2020 5.75 2.11 302.8 99.3 24,000 46 U 10 6,500 0.075 U 0.12 U 390 2,050 380 J 13,000 J 91,000 830 U 0.053 U 0.54 4.8 03/09/2021 5.4 6.49 351.0 99.2 33,000 50 U 19 3,570 0.075 U 0.12 U 300 1,600 2,000 11,000 U 123,000 44,800 0.053 U 0.13 J 6.9 10/19/2021 5.701 5.621 518.31 NAI 61,7001 50.0 U NAI 1,7601 NAI NA NAI 2,390 2,000 HT 34,000 J 124,0001 830 U NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 4 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW3201 SW356 I SW336 1124-38-91 16887- 00-6 or SW301 I SW334 I SW338 SW419 74-84-0 74-85-1 1 74-82-8 7440-44-0 lorE-101951 SW316 SW317 14808-79-8 18496-25-81 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L Ng/L Ng/L nM pg/L pg/L Ng/L Ng/L Ng/L Ng/L pg/L Ng/L pg/L mg/L mg/L mg/L MW-5 10/26/2011 Not Sampled 4/12/2012 6.89 3.50 -130.9 170 82,300 1,200 NA 200 U 6.2 U 6.2 U 850 30,600 69,000 NA 5,000 U 100 U 0.14 0.031 J 0.086 J 10/24/2012 5.72 3.11 18.2 160 76,000 500 U NA 20 U 0.86 U 0.79 U 3.3 U 27,200 4,900 68,000 2,700 J 100 U 0.11 0.027 J 0.032 J 4/11/2013 6.85 2.42 -70.7 110 50,800 500 U 2.3 U 20 U 0.86 U 0.79 U 4,870 24,300 13,200 26,000 3,400 J 100 U 1.8 U 1 U NA 10/9/2013 6.82 2.67 -43.1 48 51,800 2,400 NA 20 U 0.86 U 0.79 U 7,760 25,700 11,200 40,000 2,000 U 100 U NA NA NA 4/9/2014 6.79 3.36 -99.5 76 54,600 2,800 NA 20 U NA NA NA 41,900 44,100 69,000 100 U 0.32 0.37 0.18 10/23/2014 6.48 3.51 -42.2 110 51,900 2,300 NA 10 U 3.1 U 3.1 U 2,210 48,400 16,700 72,000 1,500 J 100 U 0.54 0.24 0.28 4/22/2015 5.11 4.18 59.8 NA 46,000 25,000 NA 23 U 4.1 U 4.3 U 1,800 8,500 6,300 42,000 270 J 10 U 5.0 U NA 10/13/2015 6.67 2.68 -6.8 130 50,000 5,100 NA 58 J 0.24 0.40 1,900 10,700 14,000 82,000 960 J 3,300 U 0.2 U 0.11 0.20 4/6/2016 6.95 3.48 -28.2 62 43,000 22 U NA 50 J 0.34 0.21 3,900 8,700 3,600 34,000 J 240 U 830 U 0.2 U 0.1 U 0.1 U MW-SR 10/12/2016 6.34 3.24 37.8 89 50,000 6,000 NA 100.1 0.20 0.14 810 20,700 3,500 79,000 870 J ND ND 0.47 0.14 03/22/2017 6.37 4.51 -5.3 140 76,000 17,000 NA 310 J 0.21 0.28 3,300 12,700 1,200 J 33,000 J 2000 J ND ND 0.1 U ND 10/11/2017 5.98 6.21 104.0 130 74,000 1,400 NA 81 J 0.1 U 0.16 9.8 9,300 1,700 J 41,000 J 2,100 J ND ND 0.35 0.2 U 03/21/2018 6.47 1.04 11.8 130 60,000 7,100 NA 160 J 0.14 0.25 1,500 50,500 15,000 210,000 1100 ND ND 0.32 ND 10/17/2018 6.43 1.87 162.1 110 N 51,000 4800 J NA 120 0.36 N 0.16 N 1,900 N 6,680 11,000 45,000 J 490 U 830 U ND 0.15 M3,M5 0.27 B 03/20/2019 7.06 3.39 -85.8 61 44,000 46 U NA 100 0.28 0.10 2,500 10,500 4,400 44,000 J 490 U 830 U NA 0.17 0.2 U 10/23/2019 7.02 1.51 -55.5 58 61,000 2,000 HT NA 110.1 0.32 0.15 3,400 18,000 18,000 BB,B 58,000 480 U 30,000 ND 0.56 0.50 U 03/18/2020 7.12 1.50 -96.1 56 N 53,000 1500 HT NA 59 J 0.34 N 0.18 N 4,800 N 20,900 6,500 85,000 480 U 830 U 0.085 U 210 120 J 10/12/2020 6.82 1.43 -130.0 45.3 55,000 12,000 NA 75 J 0.075 U 0.12 U 3,700 7,050 5,200 42,000 J 560 U 5,000 0.053 U 4.2 J 50 03/09/2021 6.6 0.84 -129.9 1.46 51,700 50 U NA 78 J 0.57 J 0.6 J 2,300 4,360 12,000 65,000 560 U 830 U 0.53 U 1.2 U 74 10/19/2021 6.80 11 NAI 66,5001 7,6401 NAI 76.0 U NAI NAI NA 5,360 15,500 101,000 540 U 830 U1 NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 5 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 SW336 124-38-9 16887- 00-6 or SW301 I SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L pg/L pg/L nM pg/L pg/L pg/L pg/L pg/L Ng/L pg/L pg/L Ng/L mg/L mg/L mg/L 10/26/2011 5.40 1.46 -72.6 NA 5,000 U 10,300 NA 200 U 5 U 5 U 1,170 13,200 NA NA 5,000 U 100 U NA NA NA 4/11/2012 6.03 2.19 -108.4 220 5,000 U 13,200 31 200 U 6.2 U 6.2 U 313 4,600 2,000 U NA 5,000 U 100 U 0.096 J 0.019 J 0.049 J 10/23/2012 5.33 0.37 10.3 120 1,000 U 3,600 0.34 J 20 U 0.86 U 0.79 U 21 1,100 2,000 U 25,000 U 2,000 U 100 U 0.032 U 0.021 U 0.021 J 4/11/2013 5.40 0.39 93.4 240 1,000 U 1,400 12 20 U 0.86 U 0.79 U 314 9,600 2,000 U 25,000 U 2,100 J 100 U 2.3 U 1.8 U NA 10/8/2013 5.13 0.31 71.5 250 1,100 880 23 20 U 0.86 U 0.79 U 900 15,800 2,000 25,000 U 2,000 U 100 U NA NA NA 4/8/2014 5.32 0.70 97.4 380 1,000 U 1,100 3.7 20 U NA NA NA 11,400 2,000 U 25,000 U 2,200 100 U 0.12 0.020 J 0.11 10/22/2014 4.91 0.38 146.6 280 8001 1,500 1.3 20 U 3.1 U 3.1 U 607 37,800 2,000 U 25,000 U 1,500 J 100 U 0.031 J 0.030 J 0.072 J 4/21/2015 2.59* 0.39 166.0 260 640 J 6,200 65 23 U 4.1 U 4.3 U 720 4,300 5,000 U 7,200 J 32,000 J 10 U 5.0 U NA 10/13/2015 5.56 2.58 99.5 190 620 J 6,100 2.6 100.1 0.10 0.39 180 300 U 5,100 U 5,300 U 760 J 830 U 0.2 U 0.1 U 0.1 U 4/5/2016 5.21 0.54 243.0 200 960 J 140 J 4.1 780 J 0.01 U 0.047 11 1,500 U 1,700 J 7,300 U 1,600 J 830 U 0.2 U 0.22 0.20 MW-6 10/11/2016 5.33 0.78 172.2 220 870 J 71 U 57 130 J 0.01 U 0.057 28 14,500 1200 J 14,000 U 440 J ND ND 0.10 U 0.10 U 03/21/2017 5.63 3.44 121.0 270 1,100 4,500 29 77 J, B 0.1 U 0.130 11 9,600 920 J 14,000 U 9501 ND ND 0.1 U ND 10/11/2017 5.74 8.92 88.0 160 24,000 2,500 40 290 J 0.1 U 0.11 9.3 1,700 J 2,000 U 25,000 J 12,000 J ND ND 0.57 0.2 U 03/21/2018 5.59 1.81 155.2 260 830 J 3,000 NA 100.1 0.1 U 0.15 53 17,200 2,400 17,000 U 200 U ND ND 0.1 U ND 10/18/2018 5.21 7.13 294.9 110 N 860 J 47 J 15 N 780 0.2 U,D,N 0.2 U,D,N 0.48 D,N 1270 J 920 BB, J 17,000 U 490 U 830 U ND 0.43 M3,M5 0.20 U,B 03/21/2019 5.33 5.32 322.1 160 1,100 46 U 4.8 590 0.02 U 0.02 U 0.45 4,970 200 U 17,000 U 1,100 J 2700 NA 2.0 0.2 U 10/23/2019 5.34 3.24 301.9 250 1,100 51 HT,U 14 240 0.01 U 0.034 14 8,180 210 U,BB 10,000 U 710 J 30,000 ND 0.10 U 0.50 U 03/18/2020 5.14 5.81 279.0 280 N 1,000 51 HT,U NA 150 J 0.005 U,N 0.043 J,N 3.7 N 3,340 540 J 10,000 U 560 J 830 U 0.085 U 43 U 120 U 10/13/2020 7.1 # 1.55 -139.9 159 1,100 46 U 4.1 96 J 0.075 U 0.12 U 140 1,040 280 J 11,000 U 830 J 830 U 0.053 U 0.58 5.0 03/10/2021 5.0 1.42 262.4 150 350 U 50 U 22 45 U 0.075 U 1 0.24 J 25 500 U 2,000 U 11,000 U 560 U 39,600 0.053 U 0.13 J 6.6 10/20/2021 4.601 5.701 334.51 NAI 888 J 1 60.0 J NAI 76.0 U I NAI NA NAI 788 J 2,000 U 19,000 J 540 U 830 U NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 6 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Field Parameters MNA Parameters Volatile Fatty Acids Parameter PH Dissolved Oxygen Oxidation Reduction Potential Carbon Dioxide Chloride Ferrous Iron Hydrogen Nitrate Ethane Ethene Methane Total Organic Carbon BOD, 5 day Chemical Oxygen Demand Sulfate Sulfide Lactic Acid Acetic Acid Formic Acid CAS Number SW320 SW356 I SW336 124-38-9 16887- 00-6 or SW301 SW334 SW338 SW419 74-84-0 74-85-1 74-82-8 7440-44-0 1 or E-10195 SW316 SW317 14808-79-8 18496-25-8 SW415 SW416 NE SWSID 320 356 336 459 301 334 338 419 331 332 456 357 316 317 315 187 415 416 NE Well ID Collect Date SU mg/L mV mg/L pg/L pg/L nM pg/L Ng/L pg/L pg/L pg/L Ng/L pg/L pg/L Ng/L mg/L mg/L mg/L 10/27/2011 6.01 1.53 -51.0 NA 45,400 2,700 NA 200 U 5 U 5 U 1,360 13,200 NA NA 42,800 J 100 U NA NA NA 4/12/2012 6.41 0.72 -164.0 150 51,400 500 U 4.1 200 U 6.2 U 6.2 U 1,090 5,900 2,000 U NA 24,600 100 U 0.14 0.032 J 0.048 J 10/24/2012 5.72 0.43 81.6 120 48,600 1,800 16 20 U 0.86 U 1.0 J 1,200 12,500 2,000 U 25,000 U 27,200 J 100 U 0.033 J 0.021 U 0.01 U 4/10/2013 6.09 0.21 101.9 300 19,700 600 0.54 J 20 U 0.86 U 0.79 U 1,470 15,600 2,000 U 25,000 U 30,800 J 100 U 2.3 U 1.8 U NA 10/9/2013 5.98 0.34 91.5 98 52,600 500 U 47 20 U 0.86 U 0.79 U 1,410 16,600 2,000 25,000 U 29,200 J 100 U NA NA NA 4/9/2014 6.03 0.81 103.7 61 61,000 500 U 3.6 20 U NA NA NA 16,500 2,000 U 25,000 U 30,600 0.085J 0.011.1 0.12 10/23/2014 5.93 0.32 95.2 340 60,000 730 1.5 10 U 3.1 U 3.1 U 648 28,900 2,000 U 38,000 26,000 100 U 0.085 J 0.043 J 0.13 4/22/2015 4.36* 0.11 145.8 270 60,000 2,400 1.6 23 U 4.1 U 4.3 U 800 2,600 5,000 U 4,800 J 32,000 J 10 U 5.0 U NA 10/14/2015 6.03 1.97 148.5 200 68,000 330 2.0 58 J 0.028 0.070 110 1,800 J 2,400 J 20,000 J 27,000 J 1,600 J 0.2 U 0.1 U 0.1 U 4/6/2016 5.97 0.47 122.4 200 69,000 1901 7.2 150.1 0.053 0.095 140 1,500 J 2,200 U 7,300 U 27,000 J 1,000 J 0.2 U 0.1 U 0.1 U MW-7 10/12/2016 6.03 0.39 116.4 380 67,000 1901 41 200 J 0.099 0.240 180 25,100 160 J 29000 J 23,000 J ND ND 0.10 U 0.10 U 03/22/2017 6.03 1.12 134.2 350 71,000 290 9.6 911 0.150 0.220 340 9,000 120 J 14,000 U 23,000 J ND ND 0.1 U ND 10/10/2017 5.98 1.47 133.2 400 73,000 51 J 45 130 0.120 0.18 270 10,100 80J 33,000J 21,000 ND ND 0.17 0.56 03/20/2018 6.06 3.37 211.6 410 77,000 59 J 6.7 250 J 0.18 0.11 320 29,500 2,000 U 47,000 J 21,000 ND ND 0.1 U ND 10/17/2018 5.79 0.66 267.4 250 N 75,000 230 29 N 90.1 0.2 U 0.2 U,D,N 200 D,N 1100.1 2000 U 44,000 J 19,000 830 U ND 0.54 M3,M5 0.20 U,B 03/19/2019 6.09 2.02 155.8 210 78,000 46 U 46 65 J 0.081 0.10 190 600 U 240.1 17,000 U 22,000 1800 J NA 0.1 U 0.2 U 10/22/2019 6.11 1.16 193.8 490 75,000 74 HT,J 3.4 110.1 0.020 0.065 47 10,600 1,700 BB,J,B 13000 J 22,000 12,000 ND 0.10 U 0.50 U 03/17/2020 6.08 0.82 174.2 360 N 79,000 51 HT,U 52 94 J 0.11 N 0.093 J,N 280 N 7,110 210 U 19,000 J 28,000 830 U 0.085 U 43 U 120 U 10/12/2020 6.07 1.79 138.4 178 79,000 360 10 92 J 0.075 U 0.12 U 640 3,220 920 J 18,000 J 25,000 830 U 0.053 U 0.45 J 4.8 03/09/2021 5.7 1.79 147.5 133 82,500 190 J 9.2 45 U 0.21 J 0.2 J 470 2,890 2,000 12,000 J 27,300 36,200 0.053 U 0.12 U 7.5 10/20/2021 6.001 1.361 139.61 NAI 81,6001 370 NAI 76.0 U I NAI NA NAI 3,130�71 2,000 HT,U 29,000 J 23,0001 830 U1 NA NA NA Five -Year Corrective Action Evaluation Report - 2021 Page 7 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Table 5 Summary of Applicable Field Parameters and Monitored Natural Attenuation (MNA) Parameters Notes: Cas Number: A unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters SWS ID: Solid Waste Section Identification Number pg/L: micrograms per liter mg/L: milligrams per liter nM: nanomolar mv: millivolts U: A laboratory data qualifier used for parameters not detected at concentrations above the laboratory method detection limit. 2060: Indicates the compound was detected above laboratory method report limits J: A laboratory data qualifier used for parameters detected at estimated concentrations above the method detection limit but below the laboratory report limit. J: A qualifier assigned by Altamont to reflect a detected concentration that is greater than laboratory reporting limit but below the Solid Waste Section Limit (SWSL). 2.08*: These results are considered to be unreliable due to pH meter malfunction. NA: Not analyzed ND: Compound was analyzed but not detected above the laboratory method detection limit and the method detection limit was not reported in previous groundwater reports. B: a laboratory data qualifier used for parameters that were detected in the associated laboratory blank at a concentration greater than one half of the reporting limit. BB: a laboratory data qualifier used to indicate the blank is outside the control limits, but the validity of the data is not affected. D: a laboratory qualifier indicating that the analyte concentration was determined from a dilution. M3: a laboratory qualifier indicating that the matrix spike sample recovery was outside laboratory control limits. M5: a laboratory qualifier indicating that the matrix spike duplicate sample recovery was outside laboratory control limits. N: a laboratory qualifier indicating the laboratory does not hold NELAP/TNI accreditation for this method or analyte. HT: a laboratory data qualifier used to indicate the sample was received and analyzed outside of the hold time. # = sample analyzed in laboratory using EPA Method SM4500, because of field equipment malfunction. Five -Year Corrective Action Evaluation Report - 2021 Page 8 of 8 Jackson County Closed Municipal Solid Waste Landfill January 2022 Figures X . . . . . 4. 4� ter," J r LEGEND: SOURCES: 1. Basernap: USGS Topographic Maps - Greens C3 Site Parcel Boundary Creek and Whittier 7.5-minute Quadrangles 2. Parcel: Jackson County GIS 0 2,000 Feet Publish Date: 2021/12/29, 3:19 PM I User: scolquhoun Filepath: Q.\Jobs\JacksonCounty-NC-1480\Maps\2021\5-yr�_Review\AQ_Fig_l_Five-Year 2021.mxd kZANCHOR 0 EA Figure 1 Site Location Map Five -Year Corrective Action Evaluation - 2021 Jackson County Closed Municipal Solid Waste Landfill aries from oximate. Publish Date: 2022/01/04, 4:27 PM I User: scolquhoun Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2021\S-yr_Review\AQ_Fig_2_Five_Year_2021_v2.mxd '�Q_ ANCHOR Figure 2 ,1�/-�" QEASite Layout Map Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landfill CONNOR WILKEY WILKEY \�♦��' Leachate and landfill gas extraction system continue ft. .� to remove mass. Landfill gas is burned off using �•+sz flare system. Leachate extraction has been increasing •` since 2018 accompanied by increases in total mass removed. EW-8 -4 EW-6 See Figure 11. '\�EW-7 EW 5 1 WILKEY . EW-3R� EW 1R'.• EW-9 G J.0 eoeJ<°G EW 2R EW-10 •�'• `♦ AW-03 C' \0 0 1997.53); • '.� LT-01 EW.-4 cm os� '•• •' RGy PP / 0IZO.00 4 •.•. •: "MW-05R � �(,1984.81) V I, MW-04 �( e-- 1957) 000 0000 O 03G Publish Date: 2022/01/04, 4:29 PM I User: scolquhoun Filepath: Q:\Jobs\JacksonCounty_NC_1480\Maps\2021\S-yr_Review\AQ_Fig_3_Five_Year_2021.mxd ANCHOR OEA LEGEND: ® Saprolite Monitoring Well ® PWR Monitoring Well (4 Bedrock Monitoring Well Leachate/Landfill Gas Extraction Well Leachate Sample Location and Flow Equalization Tank O<21_ Standard -Declining Trends O>21_ Standard -Declining Trends >2L Standard -Generally Stable to Declining Trends — - Compliance Boundary --- Edge of Waste -3110- Generalized GW Flow Direction for Bedrock Generalized GW Flow Direction for PWR/Saprolite Stream 1- Property Boundary Road Elevation Contour (20-Foot Interval) NOTES: 1.Contours, roads, and parcel boundaries from Jackson County GIS. 2.Monitoring well locations are approximate. 3.Groundwater elevations and flow direction are updated on a semiannual basis every April and October following the sample collection events. 4.Groundwater flow direction based on groundwater elevations in feet in monitoring wells MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07. Direction calculated based on depth to water measured on October 19 and 20, 2021. 51ast names of property owners are shown in parcels that border the landfill property. 6. PWR: Partially Weathered Rock 0 0 200 Feet Figure 3 Generalized Groundwater Flow Direction and Concentration Trend Relative to Groundwater Standards Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landfill Tetrachloroethene (PCE) 5 4 �3 c 0 M c 2 c 0 v 1 0 I Q CT'1 2008 2010 2012 2014 2016 2018 2020 Date 14 12 10 c 0 8 M c 6 c 0 U 4 2 0 Trichloroethene (TCE) zee; 2077 2075 $ c 0 2073 a'>i w 2071 3 2069 o tiJ 2067 2065 J 4 \ c 0 3 c v o 2 U 1 0 2008 2010 2012 2014 2016 2018 2020 Date 2079 ZU.0 2077 17.5 15.0 2075 � o .2 J \ 0) 12.5 2073 T w o — 10.0 2071 c 7.5 2069 Do �7 5.0 2067 2.5 2065 0.0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py kZANCHOR QEA 611M 2077 2075 $ 01 2073 v w 2071 3 2069 0 P, 2067 2065 40 35 30 J 25 c 0 20 c c 15 0 V 10 5 0 Cis- 1,2-Dichloroethene 2008 2010 2012 2014 2016 2018 2020 Date 2079 20.0 2077 17.5 15.0 2075 = 0 0) 12.5 i 2073 v I= w 0 - 10.0 ' 2071 c 7.5 2069 0 U 5.0 ; 2067 i 1 2.5 ------------------ - -- 2065 0.0 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dioxane 2079 101 2077 2075 $ � o J 2073 > 100� w 0 2071 3 U c 0 2069 Do 10-1 2067 2065 79 77 75 c 0 73 rO v w 71 3 c 69 o 67 65 y Vinyl Chloride i 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 2079 2077 2075 $ c 0 2073 w 2071 3 2069 0 0 2067 2065 Figure 4 Hydrograph and Constituents of Concern vs. Time - MW-01 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll 5 4 J 0, �3 c 0 M c 2 c 0 U 1 H 14 12 10 c 0 8 c 0 6 c 0 U 4 2 0 2008 2010 2012 2014 2016 2018 2020 Date Benzene Tetrachloroethene (PCE) V --------- i i ----------------------- 2008 2010 2012 2014 2016 2018 2020 Date Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. 1990 1988 1986 1984 1982 .o 1980 > LU 1978 1976 1974 O 1972 1970 1968 1966 J 4 c 0 3 c v o 2 U 1 0 Trichloroethene (TCE) 2008 2010 2012 2014 2016 2018 2020 Date 90 ZU.0 , 58 17.5 B6 B4 15.0 c � � B2 .L 01 12.5 M BO a'� ; w o 78 10.0 12 76 0 � U 7.5 ; 74 0 0 OU---------------- T------------- -- -- ----- 72 5.0 70 58 2.5 ; 56 0.0 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dichlorobenzene Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 1990 1988 1986 1984 1982 .o 1980 v 1978 v 1976 3 1974 O 1972 1970 1968 1966 40 35 30 25 c 0 20 c c 15 0 U 10 5 0 Cis- 1,2-Dichloroethene 2008 2010 2012 2014 2016 2018 2020 Date 1990 20.0 1988 17.5 ' 1986 ; 1984 FS 15.0 1982 .o 0 12.5 1980 v ; w O ' 1978 — 10.0 1976 3 v 1974 a 7.5 p O U i 1972 5.0 1970 1968 2.5 ---------------------------- --- 1966 0.01 ' 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dioxane 1990 101 1988 1986 1984 1982 .o 1980 > 10° w r 1978 2' 1976 1974 0 U 0 O U 1972 10-1 1970 1968 1966 84 82 0 M 80 v w 78 76 74 O 72 0 70 68 66 Vinyl Chloride iL Y_ ---------- i 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 1990 1988 1986 1984 1982 .o 1980 1978 1976 1974 0 1972 0 1970 1968 1966 Figure 5 Hydrograph and Constituents of Concern vs. Time - MW-02 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll 5 4 J �3 c 0 M c 2 c 0 U 1 a 14 12 10 c 0 8 M c (tj 6 c 0 U 4 2 0 Tetrachloroethene (PCE) i 2008 2010 2012 2014 2016 2018 2020 Date 2009 2007 2005 $ 2003 0 2001 >) w 1999 a5 1997 c 1995 0 6 1993 1991 1989 Trichloroethene (TCE) 6 5 J 4 c 0 3 c v o 2 U 1 V J \ V 0 2008 2010 2012 2014 2016 2018 2020 Date LU.0 2009 2007 17.5 2005 15.0 2003 0 12.5 2001 > > 0) � w o 1999 a5 a 10.0 1997 � 2 c c 7.5 1995 0 0 U �7 5.0 1993 1991 2.5 1989 0.0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 2009 2007 2005 $ 2003 0 M 2001 v w 1999 v 1997 c 1995 0 6 1993 1991 1989 40 35 30 25 c 0 20 2 c a� c 15 0 U 10 5 0 Cis- 1,2-Dichloroethene 2008 2010 2012 2014 2016 2018 2020 Date 2 0.0 2009 2007 17.5 2005 15.0 2003 0 12.5 2001 > 'E� ; w 0 1999 v o 10.0 � 1997 c 7.5 1995 o U t7 5.0 1993 1991 2.5 ' 1989 0.0 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dioxane 2009 101 2007 2005 $ 2003 0 10° 2001 > w 1999 a, P � 1997 c 0 1995 0 U 10-1 1993 1991 1989 09 07 05 03 0 01 > v w 99 }, 97 c 95 0 0 0% 91 89 Vinyl Chloride 2009 2007 2005 $ 2003 0 2001 w 1999 1997 c 1995 0 1993 1991 1989 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date Figure 6 Hydrograph and Constituents of Concern vs. Time - MW-03 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll Tetrachloroethene (PCE) Trichloroethene (TCE) Cis- 1,2-Dichloroethene 5 4 J �3 c O M c 2 c O U I 14 12 10 c O 8 M c (tj 6 c O U 4 2 0 1958 6 5 1956 $ o J 4 a>i � 1954LU 3 � 3 c v 0 U O 2 O U 1952 1 1950 0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date 1958 20.0 17.5 1956_ 15.0 � o J � 0) 12.5 a>i � 1954 M 10.0 � c c 7.5 O o U 1952 5.0 2.5 1950 0.0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 1958 40 35 1956 $ 30 C 0 25 1954 20 � c c O 15 O U 1952 10 5 1950 0 2008 2010 2012 2014 2016 2018 2020 Date 1958 20.0 17.5 1956 : 15.0 � o � 0) 12.5 1 v 1954 10.0 v � c 7.5 O O U i 1952 5.0 2.5 ------------------- 1950 0.0 2008 2010 2012 2014 2016 2018 202C Date 1,4-Dioxane 1958 101 1956 $ C o � > 100 v � 1954 � 3 c U � C D U rZ O O 1952 6 U 10-1 1950 c O 2 o 6 N Vinyl Chloride I-q--------- ------------------- 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 1958 1956 c O a� 1954 3 C Z) O 1952 6 1950 Figure 7 Hydrograph and Constituents of Concern vs. Time - MW-04 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll J a c 0 c U c 0 U Tetrachloroethene (PCE) 5 0 2008 2010 2012 2014 2016 2018 2020 Date 14 12 10 c 0 8 M c 0 6 c 0 U 4 2 0 39 37 79 77 Trichloroethene (TCE) Cis- 1,2-Dichloroethene 6 5 J 4 c 0 3 c v o 2 U is I yjbj LU.0 17.5 1987 15.0 1985 0 .2 12.5 a>i 0) � w o 1983 � 10.0 � 2 c 1981 0 c 0 7.5 0 U �7 5.0 1979 2.5 1977 0.0 1989 40 35 1987 $ 30 1985 0 25 (U w O 1983 � 20 � c 1981 0 c 0 15 O U t7 10 1979 5 1977 0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 1989 20.0 i 17.5 i 1987 15.0 1985 0 LD 12.5 v 0) w g 1983 10.0 � c 1981 7.5 O O U t7 5.0 1979 -------------- {----------- - - -- 2.5 1977 0.0 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dioxane 1989 101 1987 1985 0 > 100 v w � O 1983 � 3 c 1981 0 U 0 10-1 1979 1977 37 35 c O v 33 w 79 Vinyl Chloride i --------------- ------------------------- 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 1989 1987 1985 0 a� w 1983 1981 ZS 0 1979 1977 Figure 8 Hydrograph and Constituents of Concern vs. Time - MW-05R Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll 5 4 �3 c O M c 2 c O U 1 H 14 12 10 c 0 8 M c (tj 6 c 0 U 4 2 0 Tetrachloroethene (PCE) 2008 2010 2012 2014 2016 2018 2020 Date Trichloroethene (TCE) cis- 1,2-Dichloroethene 2066 6 2066 40 2066 101 2064 2064 2064 35 2062 5 2062 2062 2060 $ 2060 $ 30 2060 $ 4 0) 25 2058 2058 2058 0 10o >� ° i > ° > 2056 "' 3 ------- - ------ --- --- ----- - _. 2056 "' 20 2056 LU 2054 3 v 2054 3 2054 _0 2052 c 0 2 2052 c 15 0 ' 2052 c 0 0 U 0 U 0 U 2050 2050 0 10 2050 0 10-1 1 2048 2048 5 2048 2046 2046 2046 0 0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date LUbb LU.0 2064 17.5 2062 Y 15.0 2060 J o 2058 \ 12.5 o w 2056 u � 10.0 2054 c 7.5 2052 o U 2050 5.0 2048 2.5 2046 0.0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Benzene 1,4-Dichlorobenzene Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 2066 20.0 2064 17.5 , 2062 15.0 2060 J 0 2058 12.5 v g10.0 2056 w v 2054 3 v 7.5 , 2052 0 U 2050 0 5.0 2048 2.5 -- --- ----------- -- -- 2046 0.0 2008 2010 2012 2014 2016 2018 2020 Date 1,4-Dioxane 64 62 60 58 0 56 a, 54 3 52 O 50 48 46 Vinyl Chloride i\\/II ------------------------- 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 2066 2064 2062 2060 0 2058 a� 2056 a� 2054 3 2052 0 2050 2048 2046 Figure 9 Hydrograph and Constituents of Concern vs. Time - MW-06 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll Tetrachloroethene (PCE) Trichloroethene (TCE) Cis- 1,2-Dichloroethene 5 4 M c 2 c O U 1 0 14 12 10 c O 8 M c 6 c O U 4 2 0 1954 6 5 1952 0 4 a>i � w O 3 � 3 c v 1950 � rZ 2 0 1 1948 0 1954 40 35 $ 30 1952 0 .Z_ 25 w O v � 20 � 3 c 1950 0 15 O U 0 10 5 1948 0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Date 1954 20.0 17.5 15.0 1952 0 .2 12.5 a>i 0) � 12 10.0 � c u 1950 0 7.5 O U �7 5.0 2.5 1948 0.0 1954 20.0 17.5 15.0 1952 0 .2 12.5 v 0) � — 10.0 o � c v 1950 0 7.5 O U 5.0 2.5 1948 0.0 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 2008 2010 2012 2014 2016 2018 2020 Date Date Date Benzene 1,4-Dichlorobenzene 1,4-Dioxane Notes: 1. Dashed horizontal lines represent the 2L groundwater standard. 2. Dashed vertical lines represent the start of leachate extraction 3. Non -detects plotted as an open symbol at the MDL. 4. Data presented is from semiannual sampling events from 2007 to 2021. Publish Date: 01/03/2022 15:11 PM I User: SYR-SCOL File Path: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\python\JacksonCounty-GW-Evaluation.py 1954 101 1952 0 > 100 v w rZ O � 3 c 1950 U rZ 0 O U 6 10-1 1948 1952 c O 1948 Y Vinyl Chloride 2008 2010 2012 2014 2016 2018 2020 Date Constituent Key with 2L Standards f Tetrachloroethene (PCE) (0.70 µg/L) Trichloroethene (TCE) (3 µg/L) cis-1,2-Dichloroethene (70 µg/L) f Vinyl Chloride (0.03 µg/L) f Benzene (1 µg/L) f 1,4-Dichlorobenzene (6 µg/L) 1,4-Dioxane (3 µg/L) Groundwater Elevation (ft) Leachate Extraction Start Date 1954 1952 0 1948 a� w Me Figure 10 Hydrograph and Constituents of Concern vs. Time - MW-07 Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landifll 0.35 140,000 0.30 120,000 0.25 I i 100,000 0.20 80,000 J \ v7 ° 61 — V C7 O> 0 0.15 60,000 O c F— a� V C ° V 0.10 AK 40,000 0.05 20,000 0.00 0 4/1/2012 8/14/2013 12/27/2014 5/10/2016 9/22/2017 2/4/2019 6/18/2020 10/31/2021 3/15/2023 Date ♦Total VOC Concentrations in Leachate Gallons Removed During Reporting Period Filepath: \\athena\Asheville\Projects\Jackson County`Reports - Groundwater\2021 Corrective Acation Evaluation Report\Figures\Figure 11 Leachate Extraction System Trends.docx ANCHOR Figure 11 0EA Leachate Extraction System Trends Five -Year Corrective Action Evaluation Report - 2021 Jackson County Closed Municipal Solid Waste Landfill Appendix A Extraction Well Boring Logs PROJECT: DILLSBORO PROJECT NO.: 102997 WELL NO.: Gw 1 DATE INSTALLED: 03/20/04 BACKFILL: 3 FT BENTONITE: 3 FT SOLID PIPE: 47 FT ABOVE: 5 FT BELOW: 42 FT BACKFILL MATERIALS: 27 FT BENTONITE: 3 FT PERT. PIPE: 25 FT GRAVEL: 31 FT BORING DIA.: 36 IN WELL DEPTH: 69 FT PROJECT NAME: DATE DRILLED: WELL NO: DILLSBORO 3/20/2004 GW 1 EMCON/OWT, Inc. PROJECT #: TOTAL DEPTH RECOVERY WELL BORING DETAIL 102997 69 FT DEPTH COMPOSITION DEGREE OF DECOMPOSITION AMOUNT OF MOISTURE COMMENTS 0-2 ' COVERXLAY NONE DRY 2=5 COVER/CLAY NONE DRY 5-10:.: COVER/CLAY SLIGHT DRY 10-15 HHT/DIRT/CARPET SLIGHT DRY 15-20 ` HHT/DIRT/CARPET SLIGHT DRY 20=25 HHT/FABRIC SLIGHT DRY 25-30 : HHT/FABRIC SLIGHT DRY 30-35 HHT/DIRT SLIGHT MOIST 35-40 HHT/D SLIGHT MOIST 4045.1 HHT/STEEL MOSTLY DRY 45-50 ' HHT/STEEL MOSTLY DRY 50-55 HHT/DIRT SLIGHT DRY 55-60` ' HHT/DIRT SLIGHT DRY i W65 HHT/DIRT SLIGHT DRY 65-70 r HHT/DIRT SLIGHT DRY '70-75 ` 75-80 80-85 85-90 90-95 95-100 1004.05 105410 110415 115420 120-125 1251130 4- f.110-135 DEPTH BELOW SLIP CAP 4 FT 3 FTI------------ 44FT1�------------� SLIP CAP u ..• • WELL ., 102997 DATE)•<, BACKFILL: 3 FT BENTONITE: 3 FT SOLID PIPE: 54 FT ABOVE: 4 FT BELOW: SOFT BACKFILL MATERIALS: 35 FT BENTONITE: 3 FT - PERF. PIPE: 30 FT ® GRAVEL: 38 FT' BORING DIA.: 36 IN WELL DEPTH: 82 FT 82 ®o ®o 3� aN PROJECT NAME: DATE DRILLED: WELL NO: Shaw DILLSBORO 3/17/2004 GW 2 EMCON/OWT, Inc. PROJECT #: TOTAL DEPTH RECOVERY WELL BORING DETAIL 102997 82 FT DEGREE OF AMOUNT OF DEPTH COMPOSITION DECOMPOSITION MOISTURE COMMENTS 0-2 COVER/CLAY NONE DRY 2-5 COVER/CLAY NONE DRY 5_1.0 ` HHT SLIGHT DRY 1045, HHT/WOOD/DIRT SLIGHT DRY 15-20`. HHT/WOOD/DIRT SLIGHT DRY 20,725: HHT/DIRT SLIGHT DRY 25=30 : HHT/DIRT SLIGHT DRY :30=35 HHT/DIRT SLIGHT MOIST 35-40 : HHT/DIRT SLIGHT MOIST :.40-45 HHT/DIRT SLIGHT MOIST 45-50: HHTIDIRT SLIGHT MOIST 50-55:. HHT/STEEL SLIGHT MOIST 55-60 HHT/STEEL SLIGHT MOIST 60765., HHT/DIRT MOSTLY MOIST 65-70 HHT/DIRT MOSTLY MOIST 70-75 HHT/DIRT SLIGHT MOIST :. 75-80 HHT/DIRT SLIGHT MOIST 80-85 HHT/DIRT SLIGHT MOIST 85,'90 '95 95=100 100405 105-110 110-1.15 115-120 120425 125430 130=135 SLIP � rnn ..• ;, ..OJECT NO • INSTALLED,1 1 BACKFILL: 4 FT BENTONITE: 3 FT SOLID PIPE: 63 FT ABOVE: 5 FT BELOW: 58 FT BACKFILL MATERIALS: 41 FT BENTONITE: 3 FT PERF. PIPE: 3® FT GRAVEL: 39 FT BORING DIA.: 3fi IN WELL DEPTH: 9® FT J EMCON/OWT, Inc. • RECOVERY WELL BORING DETAIL DEGREE OF AMOUNT OF DEPTH COMPOSITION DECOMPOSITION MOISTURE COMMENTS Iwo COVER/CLAY NONE DRY 2 5 = COVERICLAY NONE DRY 51`0 HHT/DIRT SLIGHT DRY � 5 HHT/TIRE SLIGHT DRY 52© HHT/TIRE SLIGHT DRY 20 2-a HHT/DIRT SLIGHT DRY 253i} HHT/DIRT SLIGHT DRY HHT/DIRT SLIGHT DRY 3540 HHT/DIRT SLIGHT DRY 445 HHT/DIRT SLIGHT DRY 45D== HHT/DIRT SLIGHT DRY 505 HHT/DIRT SLIGHT DRY 55 5y0 HHT/DIRT SLIGHT DRY r,&606y5 HHT/DIRT MOSTLY MOIST O HHT/DIRT MOSTLY MOIST 7075 HHT/TIRE/DIRT MOSTLY DRY 7580 HHT/TIRE/DIRT MOSTLY DRY 0$5= HHT/DIRT NONE DRY $590 HHT/DIRT NONE DRY 9095 95� 100 _ � iQ� 105 105110 1�15y 120} 120 �125^ 125� r0= �130i�35�. � American METHANE GAS EXTRACTION WELL INSTALLATION REPORT Enviromiiental 1�61� l Group Ltd. Site Name: JACKSON COUNTY Site Location SYLVA NC. Well No. GW-4 Date Installed 1/5/2005 J013#1-04-093 GEOTEXTILE ISI 2 FT BENTONITI fie-- SLIP CAP IS 6" SCH 40 PVC 36" USING IS 6 IN SDR 17 HDPE .AN ON SITE SOIL NTONITE HYDRATED OF SOLID PIPE=20 FT BELOW SURFACE )N SITE SOIL BENTONITE HYDRATED I OF SLOTTED PIPE=38 FT .ENGTH OF GRAVEL PACK=43 FT . PACK IS 1 TO 3 IN WASHED RIVER ROCK � CAF iS o IN SCH 80 PVC DEPTH OF WELL 60 FEET American METHANE GAS EXTRACTION WELL INSTALLATION REPORT Environmentat Group Ltd. Site Name: JACKSON COUNTY GEOTEXTILE ISI 2 FT BENTONIT Site Location SYLVA NC. Well No. GW-5 Date Installed 1/6/2005 JOB#1-04-093 �s- SLIP CAP IS 6" SCH 40 PVC 36" USING IS 6 IN SDR 17 HDPE :AN ON SITE SOIL NTONITE HYDRATED OF SOLID PIPE=20 FT BELOW SURFACE �N SITE SOIL BENTONITE HYDRATED I OF SLOTTED PIPE=28 FT .ENGTH OF GRAVEL PACK=33 FT _ PACK IS 1 TO 3 IN WASHED RIVER ROCK �CAPISBWSCH80PVC DEPTH OF WELL 50 FEET -. American METHANE GAS EXTRACTION WELL INSTALLATION REPORT Envirorunental Group Ltd. Site Name: JACKSON COUNTY GEOTEXTILE ISI 2 FT BENTONIT Site Location Well No, SYLVA NC. Date Installed 1/6l2005 JO B#1-04-093 (�a —SLIP CAP IS 6" SCH 40 PVC 36" USING IS 6 IN SDR 17 HDPE :AN ON SITE SOIL NTONITE HYDRATED OF SOLID PIPE=20 FT BELOW SURFACE �N SITE SOIL BENTONITE HYDRATED PACK EXTENDS 5 FT ABOVE PERFORATED PIPE I OF SLOTTED 0I173E=18 FT .ENGTH OF GRAVEL PACK=23 FT _ PACK IS 1 TO 3 IN WASHED RIVER ROCK � CAF IS 8 IN SCH 80 PVC DEPTH OF WELL 40 FEET American METHANE GAS EXTRACTION WELL INSTALLATION REPORT Environmental i l Group Ltd. Site Name: JACKSON COUNTY GEOTEXTILE ISM 2 FT BENTONIT 36" Site Location SYLVA NC. Well No. GW-7 Date Installed 116/2M) JOB#1-04-093 — SLIP CAP IS 6" SCH 40 PVC aSING IS 6 IN SDR 17 HDPE :AN ON SITE SOIL NTONITE HYDRATED OF SOLID PIPE=20 FT BELOW SURFACE �N SITE SOIL BENTONITE HYDRATED � OF SLOTTED PIPE=18 FT _ENGTH OF GRAVEL PACK=23 FT L PACK IS 1 TO 3 IN WASHED RIVER ROCK MCAPIS8INSCH80PVC DEPTH OF WELL 40 FEET American METHANE GAS EXTRACTION WELL INSTALLATION REPORT Erivironnlental p Group Ltd, Site Name: JACKSON COUNTY Site Location SYLVA NC. Well No. GW-8 Date Installed 1/6/2005 JOB#1-04-093 GEOTEXTILE IS' 2 FT BENTONI7 36" -- SLIP CAP IS 6" SCH 40 PVC aSING IS 6 IN SDR 17 HDPE .AN ON SITE SOIL NTONITE HYDRATED OF SOLID PIPE=20 FT BELOW SURFACE �N SITE SOIL BENTONITE HYDRATED _ PACK EXTENDS 5 FT ABOVE PERFORATED PIPE i OF SLOTTED 0I0E=38 FT _ENGTH OF GRAVEL PACK=43 FT L PACK IS 1 TO 3 IN WASHED RIVER ROCK M CAF IS 8 IN SCH 8C PVC DEPTH OF WELL 60 FEET 23 j� Ameriam METHANE GAS EXTRACTION WELL INSTALLATION! REPORT Enviromuental i I Group Lid. Site Name: JACKSON COUNTY GEOTEXTILE ISi 2 FT BENTONIT 36" Site Location Well No. SYLVA NC. Date Installed 1/5/2005 JOB#1-04-093 SLIP CAP IS 6" SCH 40 PVC _ CASING IS 6 IN SDR 17 HDPE CLEAN ON SITE SOIL BENTONITE HYDRATED NTH OF SOLID PIPE=20 FT BELOW SURFACE �N ON SITE SOIL OF BENTONITE HYDRATED VEL PACK EXTENDS 5 FT ABOVE PERFORATED PIPE 3TH OF SLOTTED PIPE=48 FT aL LENGTH OF GRAVEL PACK=53 FT VEL PACK IS 1 TO 3 IN WASHED RIVER ROCK TOM CAP IS S IN SCH 80 PVC AL DEPTH OF WELL 70 FEET