9202_Wake_EastWake_MSWLF_Oct21GW_FID1628632_202200104

East Wake Landfill
Facility Permit No. 9202-
MSWLF-1981
Semi -Annual Sampling Report
(October 2021 Sampling Event)
Wake County
Report
Prepared January 2022
WAKE
COUNTY
NORTH CAROLI NA

14` Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it am "PUM�c Records" as tlefinetl m NC General Statute 132-f. As such, Utece documents am
available for inspection and examination by any person upon request INC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring. off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(axi).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable ro: Compliance Unit, NCDENR-0WM, Solid Waste
Section, 1646 Mail Service Center Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal information
Name of entity submitting data (laboratory, consulbrk, facility owner)
Consultant - CDM Smith Inc.
Contact for questions about dab formatting. Include data preparses name, telephone number and E-mail address:
Name: Mathew F. Colon Phone: l919) 325-3500
E-mail: colonemfO.dmsm'th cum
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit# (.0500 or.1600) October 2044, 2006)
East Wake Landfill - Rigsbee
�igehttlefe North Carolina 2750
45
02-MSWLF-
20
.1600
October 19, 2021
Environmerdai Status: (Check all that apply)
Initial/Background Monitoring ❑x Detection Monitoring
of data submitted: (Check all that apply)
Groundwater monitoring data from monhomrg wells
Groundwater monitoring data from private water supply wells
Assessment Monitoring ❑ Corrective Action
❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a mtifiwfion of values exceeding a groumdwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of Me cause and significance of any concentration.
Yes, a notificafion of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and atiachmenb are true and comsat
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. 1 am aware that there
are significant penalties for making any false statement representation, or certification including the possibility of a fine and imprisonment.
1YL'ZEGeC_� I L+rN`t 1 t4t[Azz Affix NC "_-y e9 st Seal
Signature Date
5400 Glenwood Avenue Suite 100 Raleigh North Carolina 27612 {v' �F7.k�P n
Facility Representative Address
NC PE � z
NC PE Firm License Number (if applicable effective May 7, 2009) i/qToL.
Revised 612009 2`

Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]
January 4, 2022
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: October 2021 (Fall) Semi -Annual Groundwater Sampling Report
East Wake Landfill - Rigsbee Property
Facility Permit No. 9202-MSWLF-1981
Dear Ms. Drummond:
CDM Smith Inc. (CDM Smith), on behalf of Wake County (County), is submitting an electronic copy of
the October 2021 semi-annual sampling event report for the East Wake Landfill - Rigsbee Property
(Site). This letter report presents the results of the most recent semi-annual sampling event and
constitutes the second semi-annual sampling event for 2021. The approved groundwater monitoring
network consists of one background well (i.e., MW-01), and five downgradient monitoring wells (i.e.,
MW-02, -03, -04S, -04D, and -07). Field activities and sampling results are discussed below.
Background
The Site is located on two parcels. One of the parcels as shown on Figure 1 is owned by Carolyn
Properties, LLC and contains approximately 27 acres of waste. This parcel is referred to as the J.T.
Knott property and is currently part of the North Carolina Department of Environmental Quality's
Special Remediation Branch's Pre -Regulatory Landfill program. The background monitoring well for
the portion of the landfill located on the James Ervin Rigsbee (Rigsbee) property, MW-01, is located on
this parcel along with a private airport and several businesses.
The parcel owned by Mr. Rigsbee contains approximately 46 acres of waste located in two separate
areas as shown on Figure 1. This parcel borders the J.T. Knott property to the south and west. A large
portion of the parcel is used for cattle pasture and includes an explosive storage company and
associated storage and office trailers, a home with a detached garage and two barns, and a storage
area for abandoned automobiles. All monitoring wells for the Site, except for the background well, are
located on this parcel. This portion of the Site operated under Permit Number 92-02 until the two
waste disposal areas ceased operations in 1983 (Area C) and 1985 (Area D).
The two areas of waste located on the Rigsbee property are known as Areas C and D as shown on
Figure 1. Groundwater assessment for Area C is being conducted under the supervision of the Special
tD
WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES

Smith
Ms. Jaclynne Drummond
January 4, 2022
Page 2
Remediation Branch's Pre -Regulatory Landfill Unit after this area of waste was determined to be
eligible for the program in the fall of 2012.
Beginning in 2012, the County voluntarily collected groundwater samples semi-annually from the Area
C monitoring wells (i.e., MW-5, -6, -8, -9, and -10). On September 13, 2018, the Solid Waste Section
(SWS) approved the discontinuation of the groundwater monitoring of Area C, beginning with the fall
2018 sampling event.
Field Activities
Groundwater samples were collected on October 19, 2021, except from MW-2, by use of disposable,
laboratory decontaminated bailers. MW-2 was dry during the October 2021 sampling event.
Monitoring well sampling locations are presented on Figure 1. Well construction details are provided
in Table 1.
Groundwater elevations were measured at each well on October 18, 2021, prior to sampling and are
presented in Table 2. These groundwater elevations were used to construct potentiometric contours
for this sampling event and are presented on Figure 1. The groundwater elevations and
potentiometric contours were used to estimate the groundwater velocity at each well. Groundwater
velocity values are provided in Table 3.
After depth to groundwater was determined, three well volumes of water were removed from each
well prior to sampling to provide fresh formation water within the well water column. Each well
volume was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and
oxidation-reduction potential using a YSI-556 multi -parameter water quality meter and a HANNA HI
98703 turbidity meter. Wells with elevated turbidity (i.e., greater than 10 Nephelometric Turbidity
Units (NTUs)) were allowed to stabilize prior to sample collection. The water quality parameters at the
time of sampling are presented in Table 2.
Alternate Source Demonstration
On August 17, 2020, CDM Smith submitted an Alternate Source Demonstration (ASD) for the Site on
behalf of the County. The purpose of the ASD was to demonstrate that metals exceeding the 15A
NCAC 02L .0202 (NC 2L) Groundwater Standards or Interim Maximum Allowable Concentrations
(IMACs) are naturally occurring and not related to a release from the landfill. The ASD was prepared
using analytical data from the background monitoring well, MW-01, that was collected on a quarterly
basis from January 2018 to February 2020 to develop upper tolerance limits (UTLs) for specific
analytes that historically exceeded their respective NC 2L Groundwater Standard or IMAC. Based on
statistical analysis, a UTL of 2.82 parts per billion (ppb) was proposed for cobalt and a UTL of 2 ppb
was proposed for vanadium. The SWS approved these proposed UTLs on August 20, 2020.
iD

Smith
Ms. Jaclynne Drummond
January 4, 2022
Page 3
Sampling Results
Pace Analytical Services, LLC, located in West Columbia, South Carolina, analyzed the groundwater
samples for the North Carolina Appendix I volatile organic compounds and Appendix I metals. In a
letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples collected
from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS approved the
removal of 1,4-dioxane from the sampling program for all monitoring wells, with the exceptions of
MW-03, -045, and -4D, due to two consecutive non -detect events (October 2018 and April 2019).
Samples were collected from the wells requiring the 1,4-dioxane analysis during the October 2021
semi-annual sampling event. Sample results are provided below.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site
had detections of analytes above the MDL but below the LOQ that were qualified as estimated or "J"
flags. In samples collected from MW-04S and -04D, detections of barium had "D" flags, indicating that
the analyte was analyzed at a dilution greater than 1.
The following list indicates the analytes detected above the LOQ at each sampling location. No "J" flag
detections are provided. Underlined analytes exceeded the NC 2L Groundwater Standard, IMAC, or
UTL. There were no "J" flag detections that exceeded the standards in any monitoring well. A
complete summary of all detected and estimated concentrations for the October 2021 sampling event
is provided in Table 4. The laboratory analytical data report is provided in Appendix A.
MW-01 (Background)
Metals:
Volatile Organic Compounds
AREA D
MW-02
Barium, Beryllium
None Detected
Metals: Dry
Volatile Organic Compounds: Dry
MW-03
Metals: Barium, Lead
Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane
MW-04S
Metals: Barium, Cobalt, Copper, Lead, Nickel, Zinc
Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane,
1,4-Dioxane
0

Smith
Ms. Jaclynne Drummond
January 4, 2022
Page 4
MW-04D
Metals:
Volatile Organic Compounds
MW-07
Metals:
Volatile Organic Compounds
Barium, Cobalt, Lead
Chlorobenzene, 1,4-Dioxane
Barium, Beryllium, Cadmium, Zinc
None Detected
An equipment blank, trip blank, and duplicate sample were analyzed for quality control. Acetone was
detected as an estimated concentration in the equipment blank below its NC 2L Groundwater
Standard. No analytes were detected in the equipment or trip blanks above the MDL. The duplicate
sample, identified as DUP, was collected from MW-07 and had similar analyte concentrations as those
detected in MW-07. Table 5 presents a summary of all parameters detected during the November
2021 sampling event that exceeded the NC 2L Groundwater Standards, IMACs, or UTLs.
Additional metals samples were collected from all monitoring wells during the November 2021
sampling event for the laboratory to filter and analyze due to elevated turbidity (i.e., greater than 10
NTUs). Total metals that exceeded the NC 2L Groundwater Standards, IMACs, or UTLs in MW-04S,
-04D, and -07 were analyzed for dissolved metals to determine if turbidity was a contributing factor to
total reported metals.
Barium was detected in the dissolved metals samples collected from MW-04S and -04D above its NC
2L Groundwater Standard. Cobalt was detected in the dissolved metal samples collected from MW-
04S and -04D above its UTL. Additionally, cadmium was detected above its NC 2L Groundwater
Standard in the dissolved metal sample collected from MW-07. Based on qualitative and quantitative
evaluation of current and historic groundwater sampling data, the NC 2L Groundwater Standard,
IMAC, and UTL metal exceedances from the October 2021 sampling event were determined to be
indicative of naturally occurring background concentrations as opposed to a release from the landfill.
Dissolved metal sample results are provided in Table 4 and the laboratory report is provided in
Appendix A.
The County will continue with the semi-annual groundwater monitoring program for Area D. The
concentration of 1,4-dioxane will continue to be monitored in MW-03, -045, and -04D. The next
sampling event will be completed in the spring of 2022.
0

Smith
Ms. Jaclynne Drummond
January 4, 2022
Page 5
If you have any questions or require further explanation, do not hesitate to call me at [phone].
Very truly yours,
%&C 166L-f-
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
0

Notes:
1. bgs - Below Ground Surface
2. AMSL - Above Mean Sea Level
3. TOC - Top of Casing
4. Latitude and longitude - World Geodetic System 1984
CDIII�
Smith
Table 1
Well Construction Summary
East Wake - Area D
Permit Number 9202-MSWLF-1981
Page 1 of 1
January 2022

Table 2
Water Quality Parameters
October 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Number
Water Quality Parameters
Monitoring Well Code pH Conductivity Temperature Turbidity DO ORP
(S.U.) (PS/cm) (deg. C) (NTUs) (mg/L) (mVs)
Groundwater Elevations - Measured 10/18/2021
Depth to Groundwater
TOC Elevation
Groundwater Elevation
(feet AMSL) (feet bgs) (feet AMSL)
INWITIVININ, •'
Notes:
1. Water levels and water quality measurements were collected on October 18-19, 2021.
2. AMSL - Above Mean Sea Level
3. TOC - Top of Casing
4. bgs - Below Ground Surface
5. µS/cm - Microsiemens per centimeter
6. mg/L - Milligrams per liter
7. ORP - Oxidation -Reduction Potential
8. NTUs - Nephelometric Turbidity Units
9. mvs - Millivolts
10. S.U. - Standard Units
11. DO - Dissolved Oxygen
12. Monitoring wells with high turbidity were allowed to settle prior to sampling; turbidity shown in table was recorded at the time of sampling.
Smith Page 1 of 1 January 2022

Table 3
Summary of Calculated Groundwater Flow Velocities
October 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit
Number
9202-MSWLF-1981
Monitoring
Well Code
MW-01
Hydraulic Conductivity
(feet/day)
0.4927
Gradient
0.0205
Effective
Porosity
0.3
Average Linear Velocity
(feet/day)
3.36E-02
9202-MSWLF-1981
MW-02
0.4927
0.0261
0.3
4.29E-02
9202-MSWLF-1981
MW-03
0.4927
0.0238
0.3
3.90E-02
9202-MSWLF-1981
MW-04S
0.4927
0.0201
0.3
3.30E-02
9202-MSWLF-1981
MW-04D
0.4927
0.0200
0.3
3.28E-02
9202-MSWLF-1981
MW-07
0.4927
0.0124
0.3
2.04E-02
Notes:
1. Hydraulic conductivity and porosity are values from HDR's 2014 Fall Semi -Annual Report.
2. Hydraulic gradient was calculated using MW-1.
Smith Page 1 of 1 January 2022

Table 4
Detected Groundwater Constituents
October 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Monitoring.
Parameter Result Qualifier
Code IMAC, or UTL
Barium 140 700 1.3 µg/L
Beryllium 0.55 4* 0.15 µg/L
MW-01 Copper 1.3 J 1,000 1.3 µg/L
Lead 0.58 J 15 0.25 µg/L
Zinc 8.8 J 1,000 2.5 µg/L
Barium
420
700
1.3
µg/L
Copper
2.9
J
1,000
1.3
µg/L
Lead
1.6
15
0.25
µg/L
Nickel
3.5
J
100
1.3
µg/L
MW-03
Zinc
6.3
J
1,000
2.5
µg/L
Acetone
4.3
J
6,000
4.0
µg/L
Chlorobenzene
4.3
50
0.40
µg/L
1,4-Dichlorobenzene
0.90
6
0.40
µg/L
1,4-Dioxane
15
3
1.0
µg/L
Barium
770
D
700
6.3
µg/L
Barium (dissolved)
780
700
1.3
µg/L
Cadmium
0.16
J
2
0.50
µg/L
Cobalt
30
2.82**
1.3
µg/L
Cobalt (dissolved)
32
2.82**
1.3
µg/L
Copper
50
1,000
1.3
µg/L
Lead
2.2
15
0.25
µg/L
MW-04S
Nickel
20
100
1.3
µg/L
Zinc
13
1,000
2.5
µg/L
Acetone
4.6
J
6,000
4.0
µg/L
Benzene
0.53
1
0.40
µg/L
Chlorobenzene
8.6
50
0.40
µg/L
1,4-Dichlorobenzene
1.9
6
0.40
µg/L
1,1-Dichloroethane
0.67
6
0.40
µg/L
1,4-Dioxane
51
3
1.0
µg/L
Arsenic
1.3
J
10
0.50
µg/L
Barium
820
D
700
6.3
µg/L
Barium (dissolved)
740
700
1.3
µg/L
Cobalt
12
2.82**
1.3
µg/L
Cobalt (dissolved)
12
2.82**
1.3
µg/L
Copper
0.54
J
1,000
1.3
µg/L
M W-04D
Lead
12
15
0.25
µg/L
Zinc
8.1
J
1,000
2.5
µg/L
Acetone
6.7
J
6,000
4.0
µg/L
Chlorobenzene
2.8
50
0.40
µg/L
1,4-Dichlorobenzene
0.42
J
6
0.40
µg/L
1,4-Dioxane
20
3
1.0
µg/L
CDM Page 1 of 2 January 2022
Smith

Table 4
Detected Groundwater Constituents
October 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Notes:
1. All units are in micrograms per liter (parts per billion, µg/L).
2. Samples were collected on October 19, 2021. MW-02 was dry during the October 2021 sampling event and was
not sampled.
3. * - Interim Maximum Allowable Concentration (IMAC)
4. ** - The Upper Tolerance Limits (UTL) were calculated as part of the East Wake Alternate Source Demonstration
and were approved by the Solid Waste Section on August 20, 2020.
5. MDL - Method Detection Limit
6. dup - Duplicate Sample
7. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit
of quantitation.
8. D - Indicates the analyte was analyzed at a dilution greater than 1.
9. Dissolved metals samples were collected to evaluate the influence of turbidity on total metal concentrations.
10. ( ) Indicates the result is below the detection limit.
Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L), IMAC, or UTL.
CDM Page 2 of 2 January 2022
Smith

Table 5
Constituents Detected Above Standards
October 2021 Semi -Annual Sampling Event
East Wake Landfill - Area D
Permit Number 9202-MSWLF-1981
Facility Permit Number
Monitoring Well Code
October
North Carolina 2L, Interim Maximum Allowable Concentration,
9202-MSWLF-1981
MW-01
Upperor
None Detected
9202-MSWLF-1981
MW-02
DRY
9202-MSWLF-1981
MW-03
1,4-Dioxane
9202-MSWLF-1981
MW-04S
Barium, Cobalt**, 1,4-Dioxane
9202-MSWLF-1981
MW-04D
Barium, Cobalt**, 1,4-Dioxane
9202-MSWLF-1981
MW-07
Cadmium
Notes:
1. ** - The Upper Tolerance Limits were calculated as part of the East Wake Alternate Source Demonstration approved by
the Solid Waste Section on August 20, 2020.
Smith Page 1 of 1 January 2022

1
MW-02
238.50
MW-03
230.88
r I
1 ?1 ' L
t ,
Anea D
'BMW-04S
226.98 .r
MW-04D , k I
227.21
�• f
r q Carolyn Properties, LLC
t (J.T. Knott Property
y: - "MW-07k
1 1 249.7
�(
� Facility I �
' I Entrance
Ar C t I LEGEND
J Groundwater Monitoring Well
' J _ 243.52 Groundwater Elevation
\. Potentiometnc Contour
Notes: r\ ll• 240— contour Interval =l0 feet
1. Groundwater elevations were measured on G2tober 18, 2021 r (dashed where inferred)
2. Potentiometric contours are derivedfrom preNosite investigations- _.._ Property Line
and adjusted based on the recent groundwater el ations.
Map Data Source: August 2017 Aerial Photographr Li(pk :County, North Carolina OneMap.

Appendix A
Analytical Data

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: East Wake Landfill
Lot Number:WJ27064
Date Completed:11/23/2021
12/21 /2021 10:21 AM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�q a[cArFo f�
/747iR
TN I
AM Nauvue Acm^r mn BuaN
11 �
eOfFAi�
A C C R E D I T E D
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 49

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WJ27064
Revised Report 12/21/2021:
Per client, this PDF report has been revised to report the few VOA samples all on one result form
with the H flag reported for trans-1,4-Dichloro-2-butene. All other sample results are as reported
in the original PDF report. This report supersedes and replaces any prior reports issued under
this lot number.
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
VOA 8260D
Reanalysis of the following samples was performed outside of the analytical holding time for trans-1,4-
Dichloro-2-butene due to exceeding lower control limits in the ICV/ LCS and CCV: WJ27064-001 (MW-
03), WJ27064-002 (MW-04S), WJ27064-003 (MW-04D), WJ27064-004 (MW-07) , WJ27064-005 (MW-
01), WJ27064-006 (DUP), WJ27064-007 (EQ BLANK), and WJ27064-008 (TRIP BLANK). Analyte trans-
1,4-Dichloro-2-butene was reported with an "H" flag since the result is being reported from the Run 2 that
was analyzed outside holding time.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 49

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WJ27064
Project Name: East Wake Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-03
Aqueous
10/19/20210910
10/21/2021
002
MW-04S
Aqueous
10/19/20210930
10/21/2021
003
MW-04D
Aqueous
10/19/20210940
10/21/2021
004
MW-07
Aqueous
10/19/20210955
10/21/2021
005
MW-01
Aqueous
10/19/20211025
10/21/2021
006
DUP
Aqueous
10/19/20210800
10/21/2021
007
EQ BLANK
Aqueous
10/19/2021 1040
10/21/2021
008
TRIP BLANK
Aqueous
10/19/2021 1040
10/21/2021
(8 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 49

PACE ANALYTICAL SERVICES, LLC
Detection Summary
CDM Smith
Lot Number: WJ27064
Project Name: East Wake Landfill
Project Number:
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
MW-03
Aqueous
Acetone
8260D
4.3
J
ug/L
6
001
MW-03
Aqueous
Chlorobenzene
8260D
4.3
ug/L
6
001
MW-03
Aqueous
1,4-Dichlorobenzene
8260D
0.90
ug/L
6
001
MW-03
Aqueous
1,4-Dioxane
8260D (SIM)
15
ug/L
8
001
MW-03
Aqueous
Barium
6020B
420
ug/L
9
001
MW-03
Aqueous
Copper
6020B
2.9
J
ug/L
9
001
MW-03
Aqueous
Lead
6020B
1.6
ug/L
9
001
MW-03
Aqueous
Nickel
6020B
3.5
J
ug/L
9
001
MW-03
Aqueous
Zinc
6020B
6.3
J
ug/L
9
002
MW-04S
Aqueous
Acetone
8260D
4.6
J
ug/L
10
002
MW-04S
Aqueous
Benzene
8260D
0.53
ug/L
10
002
MW-04S
Aqueous
Chlorobenzene
8260D
8.6
ug/L
10
002
MW-04S
Aqueous
1,4-Dichlorobenzene
8260D
1.9
ug/L
10
002
MW-04S
Aqueous
1,1-Dichloroethane
8260D
0.67
ug/L
10
002
MW-04S
Aqueous
1,4-Dioxane
8260D (SIM)
51
ug/L
12
002
MW-04S
Aqueous
Barium
6020B
770
D
ug/L
13
002
MW-04S
Aqueous
Cadmium
6020B
0.16
J
ug/L
13
002
MW-04S
Aqueous
Cobalt
6020B
30
ug/L
13
002
MW-04S
Aqueous
Copper
6020B
50
ug/L
13
002
MW-04S
Aqueous
Lead
6020B
2.2
ug/L
13
002
MW-04S
Aqueous
Nickel
6020B
20
ug/L
13
002
MW-04S
Aqueous
Zinc
6020B
13
ug/L
13
003
MW-04D
Aqueous
Acetone
8260D
6.7
J
ug/L
14
003
MW-04D
Aqueous
Chlorobenzene
8260D
2.8
ug/L
14
003
MW-04D
Aqueous
1,4-Dichlorobenzene
8260D
0.42
J
ug/L
14
003
MW-04D
Aqueous
1,4-Dioxane
8260D (SIM)
20
ug/L
16
003
MW-04D
Aqueous
Arsenic
6020B
1.3
J
ug/L
17
003
MW-04D
Aqueous
Barium
6020B
820
D
ug/L
17
003
MW-04D
Aqueous
Cobalt
6020B
12
ug/L
17
003
MW-04D
Aqueous
Copper
6020B
10
ug/L
17
003
MW-04D
Aqueous
Lead
6020B
0.54
J
ug/L
17
003
MW-04D
Aqueous
Nickel
6020B
12
ug/L
17
003
MW-04D
Aqueous
Zinc
6020B
8.1
J
ug/L
17
004
MW-07
Aqueous
Barium
6020B
71
ug/L
20
004
MW-07
Aqueous
Beryllium
6020B
0.75
ug/L
20
004
MW-07
Aqueous
Cadmium
6020B
9.4
ug/L
20
004
MW-07
Aqueous
Copper
6020B
1.7
J
ug/L
20
004
MW-07
Aqueous
Lead
6020B
0.87
J
ug/L
20
004
MW-07
Aqueous
Zinc
6020B
140
ug/L
20
005
MW-01
Aqueous
Barium
6020B
140
ug/L
23
005
MW-01
Aqueous
Beryllium
6020B
0.55
ug/L
23
005
MW-01
Aqueous
Copper
6020B
1.3
J
ug/L
23
005
MW-01
Aqueous
Lead
6020B
0.58
J
ug/L
23
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 49

Detection Summary (Continued)
Lot Number: WJ27064
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
005 MW-01
Aqueous
Zinc
6020B
8.8
J
ug/L
23
006 DUP
Aqueous
Barium
6020B
64
ug/L
26
006 DUP
Aqueous
Beryllium
6020B
0.65
ug/L
26
006 DUP
Aqueous
Cadmium
6020B
7.6
ug/L
26
006 DUP
Aqueous
Copper
6020B
1.8
J
ug/L
26
006 DUP
Aqueous
Lead
6020B
0.86
J
ug/L
26
006 DUP
Aqueous
Zinc
6020B
120
ug/L
26
007 EQ BLANK
Aqueous
Acetone
8260D
4.0
J
ug/L
27
(51 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-001
Description: MW-03 Matrix: Aqueous
Date Sampled:10/19/2021 0910 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/20210312
JWO
20882
2 5030B 8260D
1 11/21/20212103 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.3
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
4.3
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.90
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-001
Description: MW-03 Matrix: Aqueous
Date Sampled:10/19/2021 0910 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/20210312 JWO
20882
2
5030B
8260D 1
11/21/20212103 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
107 70-130 H 93 70-130
101 70-130 H 107 70-130
101 70-130 H 105 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 49

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WJ27064-001
Description: MW-03 Matrix: Aqueous
Date Sampled:10/19/2021 0910 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/01/2021 2149 CAW 20857
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 15 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
83 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-001
Description: MW-03 Matrix: Aqueous
Date Sampled:10/19/2021 0910 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11 /03/2021 1829 BN W
Prep Date Batch
11 /02/2021 1210 20894
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
420
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.9
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.6
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
3.5
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
6.3
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-002
Description: MW-04S Matrix: Aqueous
Date Sampled:10/19/2021 0930 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/2021
0335 JWO
20882
2 5030B 8260D
1 11/21/20212128 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.6
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.53
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
8.6
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.9
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.67
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-002
Description: MW-04S Matrix: Aqueous
Date Sampled:10/19/2021 0930 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/2021 0335 JWO
20882
2
5030B
8260D 1
11/21/20212128 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
102 70-130 H 94 70-130
99 70-130 H 106 70-130
98 70-130 H 103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 49

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WJ27064-002
Description: MW-04S Matrix: Aqueous
Date Sampled:10/19/2021 0930 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/01/2021 2214 CAW 20857
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 51 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
81 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-002
Description: MW-04S Matrix: Aqueous
Date Sampled:10/19/2021 0930 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/03/2021 1831 BNW
6020B 5 11/04/2021 1030 BNW
Prep Date Batch
11/02/2021 1210 20894
11/02/2021 1210 20894
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
2.0 U
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
770 D
25
6.3
ug/L
2
Beryllium
7440-41-7 6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.16 J
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
30
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
50
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
2.2
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
20
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
13
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-003
Description: MW-04D Matrix: Aqueous
Date Sampled:10/19/2021 0940 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/2021
0358 JWO
20882
2 5030B 8260D
1 11/21/20212153 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
6.7
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
2.8
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.42
J
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-003
Description: MW-04D Matrix: Aqueous
Date Sampled:10/19/2021 0940 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/2021 0358 JWO
20882
2
5030B
8260D 1
11/21/20212153 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130 H 93 70-130
100 70-130 H 110 70-130
102 70-130 H 102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 49

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WJ27064-003
Description: MW-04D Matrix: Aqueous
Date Sampled:10/19/2021 0940 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/01/2021 2238 CAW 20857
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 20 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-003
Description: MW-04D Matrix: Aqueous
Date Sampled:10/19/2021 0940 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
2 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/03/2021 1833 BNW
6020B 5 11/04/2021 1032 BNW
Prep Date Batch
11/02/2021 1210 20894
11/02/2021 1210 20894
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Antimony
7440-36-0 6020B
2.0 U
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
1.3 J
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
820 D
25
6.3
ug/L
2
Beryllium
7440-41-7 6020B
0.40 U
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
0.50 U
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
5.0 U
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
12
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
10
5.0
1.3
ug/L
1
Lead
7439-92-1 6020B
0.54 J
1.0
0.25
ug/L
1
Nickel
7440-02-0 6020B
12
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
5.0 U
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
1.0 U
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
0.50 U
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
5.0 U
5.0
2.5
ug/L
1
Zinc
7440-66-6 6020B
8.1 J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-004
Description: MW-07 Matrix: Aqueous
Date Sampled:10/19/2021 0955 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/20210421
JWO
20882
2 5030B 8260D
1 11/21/20212217 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-004
Description: MW-07 Matrix: Aqueous
Date Sampled:10/19/2021 0955 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/20210421 JWO
20882
2
5030B
8260D 1
11/21/20212217 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
103 70-130 H 92 70-130
99 70-130 H 109 70-130
100 70-130 H 102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-004
Description: MW-07 Matrix: Aqueous
Date Sampled:10/19/2021 0955 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/03/2021 1839 BNW
Prep Date Batch
11/02/2021 1210 20894
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
71
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.75
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
9.4
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.7
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.87
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
140
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-005
Description: MW-01 Matrix: Aqueous
Date Sampled:10/19/2021 1025 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/20210444
JWO
20882
2 5030B 8260D
1 11/21/20212242 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-005
Description: MW-01 Matrix: Aqueous
Date Sampled:10/19/2021 1025 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/20210444 JWO
20882
2
5030B
8260D 1
11/21/20212242 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130 H 91 70-130
100 70-130 H 105 70-130
101 70-130 H 103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 22 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-005
Description: MW-01 Matrix: Aqueous
Date Sampled:10/19/2021 1025 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/03/2021 1841 BNW
Prep Date Batch
11/02/2021 1210 20894
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
140
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.55
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.58
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
8.8
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 23 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-006
Description: DUP Matrix: Aqueous
Date Sampled:10/19/2021 0800 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/02/2021
0507 JWO
20882
2 5030B 8260D
1 11/21/20212307 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-006
Description: DUP Matrix: Aqueous
Date Sampled:10/19/2021 0800 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/02/2021 0507 JWO
20882
2
5030B
8260D 1
11/21/20212307 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130 H 92 70-130
100 70-130 H 107 70-130
102 70-130 H 105 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-006
Description: DUP Matrix: Aqueous
Date Sampled:10/19/2021 0800 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/03/2021 1843 BNW
Prep Date Batch
11/02/2021 1210 20894
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
64
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.65
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
7.6
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.8
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.86
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
120
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 26 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-007
Description: EQ BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/01/20212259
JWO
20882
2 5030B 8260D
1 11/21/20212332 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
4.0
J
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 27 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-007
Description: EQ BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/01/20212259 JWO
20882
2
5030B
8260D 1
11/21/20212332 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130 H 91 70-130
99 70-130 H 107 70-130
98 70-130 H 105 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 28 of 49

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WJ27064-007
Description: EQ BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/01/2021 1606 CAW 20857
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
85 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 29 of 49

ICP-MS Metals
Client:CDM Smith Laboratory ID:WJ27064-007
Description: EQ BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11 /03/2021 1854 BN W
Prep Date Batch
11 /02/2021 1210 20894
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0
U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 30 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/01/20212322
JWO
20882
2 5030B 8260D
1 11/21/20212357 ECB
23291
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
UH
2.0
0.40
ug/L
2
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,3-Dichloropropane
142-28-9
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
L = LCS/LCSD
failure
H = Out of holding time W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 31 of 49

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:WJ27064-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run
Prep Method
Analytical Method Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D 1
11/01/20212322 JWO
20882
2
5030B
8260D 1
11/21/20212357 ECB
23291
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,4-Trimethylbenzene
95-63-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,3,5-Trimethylbenzene
108-67-8
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
98 70-130 H 94 70-130
97 70-130 H 112 70-130
99 70-130 H 105 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 32 of 49

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:WJ27064-008
Description: TRIP BLANK Matrix: Aqueous
Date Sampled:10/19/2021 1040 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D (SIM) 1 11/01/2021 1630 CAW 20857
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260D (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
85 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 33 of 49

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27064
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 34 of 49

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: WQ20857-001 Matrix: Aqueous
Batch:20857 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 11/01/2021 1441
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
84 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 35 of 49
QC Data for Lot Number: WJ27064

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: WQ20857-002 Matrix: Aqueous
Batch:20857 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
1,4-Dioxane 50 49 1 98 70-130 11/01/2021 1337
Surrogate
1,2-Dichloroethane-d4
LOQ = Limit of Quantitation
DL = Detection Limit
Acceptance
Q % Rec Limit
88 40-170
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 36 of 49
QC Data for Lot Number: WJ27064

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ20882-001 Matrix: Aqueous
Batch: 20882 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/01/2021 2153
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/01/2021 2153
Benzene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/01/2021 2153
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Dibromochloromethane
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,2-Dibromoethane (EDB)
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
Dibromomethane (Methylene bromide)
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,2-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,4-Dichlorobenzene
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,1-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,2-Dichloroethane
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
1,1-Dichloroethene
0.50
u
1
0.50
0.40
ug/L
11/01/2021 2153
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,3-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
2-Hexanone
10
U
1
10
2.0
ug/L
11/01/2021 2153
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/01/2021 2153
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/01/2021 2153
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Styrene
0.50
U
1
0.50
0.41
ug/L
11/01/2021 2153
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Toluene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 37 of 49
QC Data for Lot Number: WJ27064

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ20882-001 Matrix: Aqueous
Batch:20882 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,4-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
1,3,5-Trimethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/01/2021 2153
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/01/2021 2153
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/01/2021 2153
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 98 70-130
Toluene-d8 98 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27064
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 38 of 49

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ20882-002 Matrix: Aqueous
Batch:20882 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
85
1
85
60-140
11/01/2021 2047
Acrylonitrile
100
94
1
94
70-130
11/01/2021 2047
Benzene
50
49
1
97
70-130
11/01/2021 2047
Bromochloromethane
50
49
1
97
70-130
11/01/2021 2047
Bromodichloromethane
50
49
1
98
70-130
11/01/2021 2047
Bromoform
50
43
1
87
70-130
11/01/2021 2047
Bromomethane (Methyl bromide)
50
50
1
100
70-130
11/01/2021 2047
2-Butanone (MEK)
100
100
1
100
70-130
11/01/2021 2047
Carbon disulfide
50
47
1
94
70-130
11/01/2021 2047
Carbon tetrachloride
50
48
1
97
70-130
11/01/2021 2047
Chlorobenzene
50
48
1
96
70-130
11/01/2021 2047
Chloroethane
50
50
1
100
70-130
11/01/2021 2047
Chloroform
50
48
1
96
70-130
11/01/2021 2047
Chloromethane (Methyl chloride)
50
42
1
85
60-140
11/01/2021 2047
1,2-Dibromo-3-chloropropane (DBCP)
50
50
1
101
70-130
11/01/2021 2047
Dibromochloromethane
50
45
1
90
70-130
11/01/2021 2047
1,2-Dibromoethane (EDB)
50
50
1
100
70-130
11/01/2021 2047
Dibromomethane (Methylene bromide)
50
49
1
99
70-130
11/01/2021 2047
1,2-Dichlorobenzene
50
48
1
96
70-130
11/01/2021 2047
1,4-Dichlorobenzene
50
47
1
93
70-130
11/01/2021 2047
1,1-Dichloroethane
50
48
1
95
70-130
11/01/2021 2047
1,2-Dichloroethane
50
48
1
95
70-130
11/01/2021 2047
1,1-Dichloroethene
50
46
1
92
70-130
11/01/2021 2047
cis- 1,2-Dichloroethene
50
48
1
96
70-130
11/01/2021 2047
trans- 1,2-Dichloroethene
50
49
1
97
70-130
11/01/2021 2047
1,2-Dichloropropane
50
48
1
97
70-130
11/01/2021 2047
1,3-Dichloropropane
50
48
1
97
70-130
11/01/2021 2047
cis- 1,3-Dichloropropene
50
50
1
101
70-130
11/01/2021 2047
trans- 1,3-Dichloropropene
50
51
1
101
70-130
11/01/2021 2047
Ethylbenzene
50
49
1
98
70-130
11/01/2021 2047
2-Hexanone
100
99
1
99
70-130
11/01/2021 2047
Methyl iodide (lodomethane)
50
41
1
82
70-130
11/01/2021 2047
4-Methyl-2-pentanone
100
97
1
97
70-130
11/01/2021 2047
Methylene chloride
50
46
1
92
70-130
11/01/2021 2047
Styrene
50
52
1
104
70-130
11/01/2021 2047
1,1,1,2-Tetrachloroethane
50
50
1
100
70-130
11/01/2021 2047
1,1,2,2-Tetrachloroethane
50
49
1
98
70-130
11/01/2021 2047
Tetrachloroethene
50
49
1
99
70-130
11/01/2021 2047
Toluene
50
49
1
97
70-130
11/01/2021 2047
1,1,1-Trichloroethane
50
46
1
93
70-130
11/01/2021 2047
1,1,2-Trichloroethane
50
48
1
97
70-130
11/01/2021 2047
Trichloroethene
50
49
1
97
70-130
11/01/2021 2047
Trichlorofluoromethane
50
45
1
89
70-130
11/01/2021 2047
1,2,3-Trichloropropane
50
48
1
95
70-130
11/01/2021 2047
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 39 of 49
QC Data for Lot Number: WJ27064

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ20882-002
Matrix: Aqueous
Batch:20882
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil
% Rec
Limit
Analysis Date
1,2,4-Trimethylbenzene
50
50
1
100
70-130
11/01/2021 2047
1,3,5-Trimethylbenzene
50
50
1
101
70-130
11/01/2021 2047
Vinyl acetate
50
47
1
94
60-140
11/01/2021 2047
Vinyl chloride
50
52
1
105
70-130
11/01/2021 2047
Xylenes (total)
100
99
1
99
70-130
11/01/2021 2047
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 91 70-130
Toluene-d8 93 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27064
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 40 of 49

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ23291-001 Matrix: Aqueous
Batch:23291 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
trans- 1,4-Dichloro-2-butene 2.0 U 1 2.0 0.40 ug/L 11/21/2021 1602
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 95 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 101 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27064
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 41 of 49

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ23291-002
Matrix: Aqueous
Batch:23291
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
trans- 1,4-Dichloro-2-butene
50
46
1 92 70-130 11/21/2021 1511
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 96 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation U = Not detected at or above the LOD N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL P = The RPD between two GC columns exceeds 40 %
= RSD is out of criteria + = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27064
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 42 of 49

ICP-MS Metals - MB
Sample ID: WQ20894-001 Matrix: Aqueous
Batch: 20894 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/02/2021 1210
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/03/2021 1824
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/03/2021 1824
Barium
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/03/2021 1824
Cadmium
0.50
U
1
0.50
0.13
ug/L
11/03/2021 1824
Chromium
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Copper
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Lead
1.0
U
1
1.0
0.25
ug/L
11/03/2021 1824
Nickel
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Selenium
5.0
U
1
5.0
1.3
ug/L
11/03/2021 1824
Silver
1.0
U
1
1.0
0.25
ug/L
11/03/2021 1824
Thallium
0.50
U
1
0.50
0.15
ug/L
11/03/2021 1824
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/03/2021 1824
Zinc
10
U
1
10
2.5
ug/L
11/03/2021 1824
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 43 of 49
QC Data for Lot Number: WJ27064

ICP-MS Metals - LCS
Sample ID: WQ20894-002 Matrix: Aqueous
Batch: 20894 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/02/2021 1210
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
100
95
1
95
80-120
11/03/2021 1827
Arsenic
100
99
1
99
80-120
11/03/2021 1827
Barium
100
95
1
95
80-120
11/03/2021 1827
Beryllium
100
90
1
90
80-120
11/03/2021 1827
Cadmium
100
98
1
98
80-120
11/03/2021 1827
Chromium
100
100
1
101
80-120
11/03/2021 1827
Cobalt
100
96
1
96
80-120
11/03/2021 1827
Copper
100
100
1
103
80-120
11/03/2021 1827
Lead
100
96
1
96
80-120
11/03/2021 1827
Nickel
100
100
1
100
80-120
11/03/2021 1827
Selenium
100
94
1
94
80-120
11/03/2021 1827
Silver
100
92
1
92
80-120
11/03/2021 1827
Thallium
100
93
1
93
80-120
11/03/2021 1827
Vanadium
100
98
1
98
80-120
11/03/2021 1827
Zinc
100
97
1
97
80-120
11/03/2021 1827
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 44 of 49
QC Data for Lot Number: WJ27064

ICP-MS Metals - MS
Sample ID: WJ27064-006MS
Matrix: Aqueous
Batch: 20894
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
11/02/2021
1210
Sample
Spike
Amount
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q
Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
98
1
98
75-125
11/03/2021 1845
Arsenic
0.0
100
100
1
103
75-125
11/03/2021 1845
Barium
64
100
170
1
106
75-125
11/03/2021 1845
Beryllium
0.65
100
100
1
99
75-125
11/03/2021 1845
Cadmium
7.6
100
110
1
102
75-125
11/03/2021 1845
Chromium
0.0
100
110
1
105
75-125
11/03/2021 1845
Cobalt
0.0
100
100
1
102
75-125
11/03/2021 1845
Copper
1.8
100
110
1
108
75-125
11/03/2021 1845
Lead
0.86
100
100
1
99
75-125
11/03/2021 1845
Nickel
0.0
100
100
1
104
75-125
11/03/2021 1845
Selenium
0.0
100
100
1
101
75-125
11/03/2021 1845
Silver
0.0
100
95
1
95
75-125
11/03/2021 1845
Thallium
0.0
100
95
1
95
75-125
11/03/2021 1845
Vanadium
0.0
100
100
1
104
75-125
11/03/2021 1845
Zinc
120
100
230
1
108
75-125
11/03/2021 1845
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 45 of 49
QC Data for Lot Number: WJ27064

ICP-MS Metals - MSD
Sample ID: WJ27064-006MD
Matrix: Aqueous
Batch: 20894
Prep Method:
3005A
Analytical Method: 6020B
Prep Date:
11/02/2021 1210
Sample
Spike
Amount
Amount
Result
%Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
92
1
92
6.3
75-125
20
11/03/2021 1847
Arsenic
0.0
100
97
1
97
6.0
75-125
20
11/03/2021 1847
Barium
64
100
160
1
94
7.3
75-125
20
11/03/2021 1847
Beryllium
0.65
100
92
1
92
7.7
75-125
20
11/03/2021 1847
Cadmium
7.6
100
100
1
96
5.3
75-125
20
11/03/2021 1847
Chromium
0.0
100
99
1
99
6.5
75-125
20
11/03/2021 1847
Cobalt
0.0
100
95
1
95
6.3
75-125
20
11/03/2021 1847
Copper
1.8
100
100
1
103
5.3
75-125
20
11/03/2021 1847
Lead
0.86
100
94
1
93
5.8
75-125
20
11/03/2021 1847
Nickel
0.0
100
98
1
98
5.3
75-125
20
11/03/2021 1847
Selenium
0.0
100
98
1
98
2.8
75-125
20
11/03/2021 1847
Silver
0.0
100
90
1
90
5.2
75-125
20
11/03/2021 1847
Thallium
0.0
100
89
1
89
6.7
75-125
20
11/03/2021 1847
Vanadium
0.0
100
97
1
97
6.8
75-125
20
11/03/2021 1847
Zinc
120
100
220
1
95
5.6
75-125
20
11/03/2021 1847
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 46 of 49
QC Data for Lot Number: WJ27064

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 47 of 49

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive
West Columbia,
SC
29172
[phone]
Fax (803)
791-9111
www.pacelabs.com
Page 48
of 49

PACE ANALYTICAL SERVICES, LLC
Sam pleslieoalptCheckllst�SRQImEOOLSC-15) Revised:9/29/7() fO
aL,� pf+caf Issuing AuthDrity: Pace ENV - LVXL �, Page 1 of 1
Sample ]receipt Checklist ('R) J
Chun[; CDM SNET C041]Cr Tnsp x;uxl by:+dole= KDRW : ICU 4:'2021 Lct 4; W127Cy;?
Means ofrercipt: Paco I rlicnt I I UPS Ld FcdEx 06er;
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pH $trip 11). ' l '�:z Chlorkic Strip IV-. W6 Tesre,d 1 }y: KE Lkw
06 Final tentiprndum uIsnn receipt! T7crived (C:rrrrC tCd) mupcntorc upoil1'eceipt %Solid SllalrGup 1D: t` �
3.5 i3.5 0C NA fNA _C TkA1 NA .:C NA INA 1-C
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3. Tf ternperal:,rn: trf ur.:v cLrL?I4r c scx;eded 6.0"U, wRs Project -Manager T+fodfied?
PM Was WoliCed by: phmr? pmaiI!zaa±c-to-faoa (circle011e).
✓ Yes
No
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4- Ts the Lommcxmial t:cta c;r's packing slip at�ached to tkli€ :ijrrn°
✓ Yes
Na
5, W'cz;;propercusnody procodm s (re Unquishedlreceivetl) fill❑wed?
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W,rQ sampk; XS 1i36cd on the COC.?
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7. Were s:rnl,lc lira li7" on all sample containers'
J
Yes
No
R. Wm rA,1lwl.ion dulc & tirw ffind on the COC Y
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P. R's,.s collcction data & tiuie: listed on all sample con Lai iitr�?
F 'ies
❑ No
10. Did all ccmf hlerlabeliufo,t'lllatl4Jl (ID, date- Limo) kkw-;{: w1Lh ffi:,, .UC 7
Yzes
0
11. Fero tests t4 be perlorined 1i3ted on LTrC COC?
❑ Yes
❑ 1*n
12, Did all samples arrive in the prDper comairiers fiw emb of arWor hi goDd condition
(unhr{)kcn, lids on, etc,)'?
wA Ym
Ll No
13- Was adequate qarrei,le vtfl time available?
✓ Yer
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14- Were aLl v unpl :s T=eivpd witJ351 •4 the holding thliv tar 43 ILuurS, whia;hcvcr comos first?
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16- For VOA and RSK-171 s:,rn ploy, N zc bubbics present >'pea -sip" (W'fir l5mm in diameter)
in any crCthe VOA vialtt°
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17- Wer�a till I3kOimctah tutricllt samples received fit aPH c,f <. ?
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IR. Wcrc all cyanide samples received at apH> li and sulfide Samples re-uri+-ed i,L u pH :, 9':
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ru4Uttal chlorure f
❑ Yes
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2jO. Wcra clie il; rejiiafks, regtu-;La (i, mquzsL;d 4ilut.ons. MS. NISD der;k atitms. ,.
ocu�rectly t'adscribed Linen Llw COC iitudie conunent Section in T, MF.'
El Ycs
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21. Was the u_ate nuruher Iis;lcd on the t'cultainar label? IC4'eh, QuWLt 4
S91UVIQ Preserwadou (MuA N; uA mpLctcd for any sarn;slel:s) int-,vrrecely Prescvmd of with headspUCC-)
So-vr,ple(s) ra,k »'crti rcccivod incorrecdy pEe cocci and %Au adjutted at:rlrrtlutgiy
in saml}lo rccciVing with RA SnL of 6r0c, onu; H2SO4, HLN03. 1 ICI- KaCfl I whin* $]x ;i NA _
11mo of prc anal If m-isre Lh:m umi; l}rcruvRrive is needed, plam umu In Lhc oDmII1Cnt5 MrA .
Sarriple(s) NA wcro received with bubbly >6 mm in dia¢ncter_
Sa¢nplcs 3j x{ were received wiLh TRC = 0.5 Fng+L (1ft19 it atn) a nd w ,Tc
adjusted 9ccwdin;0, in sarnlale rtxviwjng with sadiron thiosul fate (Na,S,C}a) with Shealy lD: N.4
SR buruodu lraUs appliod Liy, kl""' Datc: LW27'2021
c ornmentS:
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 49 of 49

aceAnalytical
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: East Wake Landfill
Lot Number:WJ27069
Date Completed:12/16/2021
12/17/2021 12:10 AM
Approved and released by:
Project Manager II: Cathy S. Dover
=w�4 aecRFo���A4W-
TNI /
AM Amflvue Acm^rmm Fvu rj
('
4eOfFAi�
ACC R E OI TEO
TESTINGL aORlTOAY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 13

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: WJ27069
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation:
Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium,
Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, Fecal
Coliform SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-dichloroethane) EPA 524.2, Solid
Chemical Material: TOC Walkley-Black.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] whw.pacelabs.com
Page 2 of 13

PACE ANALYTICAL SERVICES, LLC
Sample Summary
CDM Smith
Lot Number: WJ27069
Project Name: East Wake Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-03
Aqueous
10/19/20210910
10/21/2021
002
MW-04S
Aqueous
10/19/20210930
10/21/2021
003
MW-04D
Aqueous
10/19/20210940
10/21/2021
004
MW-07
Aqueous
10/19/20210955
10/21/2021
005
MW-01
Aqueous
10/19/20211025
10/21/2021
006
DUP
Aqueous
10/19/20210800
10/21/2021
(6 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
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Page 3 of 13

ICP-MS
Client:CDM Smith Laboratory ID:WJ27069-002
Description: MW-04S Matrix: Aqueous
Date Sampled:10/19/2021 0930 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 12/15/2021 1603 BNW 12/14/2021 1008 25471
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved
Barium
7440-39-3
6020B
780
Dissolved
Cobalt
7440-48-4
6020B
32
5.0 1.3 ug/L 1
5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 13

ICP-MS
Client:CDM Smith Laboratory ID:WJ27069-003
Description: MW-04D Matrix: Aqueous
Date Sampled:10/19/2021 0940 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 12/15/2021 1606 BNW 12/14/2021 1008 25471
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved
Barium
7440-39-3
6020B
740
Dissolved
Cobalt
7440-48-4
6020B
12
5.0 1.3 ug/L 1
5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 13

ICP-MS
Client:CDM Smith Laboratory ID:WJ27069-004
Description: MW-07 Matrix: Aqueous
Date Sampled:10/19/2021 0955 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 12/15/2021 1609 BNW 12/14/2021 1008 25471
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cadmium
7440-43-9 6020B 5.7 0.50 0.13 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 13

ICP-MS
Client:CDM Smith Laboratory ID:WJ27069-006
Description: DUP Matrix: Aqueous
Date Sampled:10/19/2021 0800 Project Name: East Wake Landfill
Date Received:10/21/2021 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 12/15/2021 1612 BNW 12/14/2021 1008 25471
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cadmium
7440-43-9 6020B 8.0 0.50 0.13 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure
U = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1 S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 13

QC Summary
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) QC Data for Lot Number: WJ27069
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 13

ICP-MS - MB
Sample ID: WQ25471-001 Matrix: Aqueous
Batch: 25471 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 12/14/2021 1008
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Dissolved Barium
5.0
U
1
5.0
1.3
ug/L
12/15/2021 1501
Dissolved Cadmium
0.50
U
1
0.50
0.13
ug/L
12/15/2021 1501
Dissolved Cobalt
5.0
U
1
5.0
1.3
ug/L
12/15/2021 1501
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 13
QC Data for Lot Number: WJ27069

ICP-MS - LCS
Sample ID: WQ25471-002 Matrix: Aqueous
Batch: 25471 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 12/14/2021 1008
Spike
Amount
Result
%Rec
Parameter
(ug/L)
(ug/L) Q Dil
% Rec
Limit
Analysis Date
Dissolved Barium
100
98 1
98
80-120
12/15/2021 1504
Dissolved Cadmium
100
100 1
100
80-120
12/15/2021 1504
Dissolved Cobalt
100
99 1
99
80-120
12/15/2021 1504
LOQ = Limit of Quantitation
DL = Detection Limit
U = Not detected at or above the LOD
J = Estimated result < LOQ and > DL
= RSD is out of criteria
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 13
QC Data for Lot Number: WJ27069

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 13

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 13

PACE ANALYTICAL SERVICES, LLC
Samples Recalpt Checklist [SRC} (UFcojgc-15)
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Issuing Authority_ lli-4 CNV - WCUL Page 1 of !
Sample Receipt Checklist (SRC)
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1)}+�dpoc� i ' lAt fir_ n
Mfxn a or recei t: Pates Ciieut UPS
op, yaq No 1_ wcrc cl►Rt4tty seats res�nt �m tl>e ��o]cr2
V Yes No NA 2. If cu%No d sears were present we!N the intact and unbrnlccm7
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proper custody pr4:ed4r (te]i>�rluisJredlrcceive�) fol]p4�cd
Yes No
fi. Were Sand Ie I]>•s listed �n toe t't]C? ��, —
Yes l0
7_ %Vcj ; nan,Ple ilps fisted On all sample contslbers7
Ycs No
9. W; coik;c.ion d8ro & Onic lister? on the COC?
Yes Na'
9, Rras :nllcctiorl dHre &time rislel oa all sari Siccoutaulct
Y Er. N
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Foal ONO 1-2 Did dlI vHmaies mrive in the propm- cottreiners R-w each Est ancJur in ga:,d oonJisian
(unhroken,'J{I6on,Inc.)? _
0 Ycs . NO 11 WAs ad equ c sample v{IIrm"r' available?
Yrs t o I 4_ rttJ re all sArnples rexej%"d W� lh in 3I1 the holdi r cr. tine gar 48 h rsuts, 4 h:chcver comes : i rs I.
Yes J hfo 15- NVEre any t1rrrpJe3 contain" mJsS4&cxce35 Jiol-- one) n miles Not fisted ou [ Cr)
[7 Yea 0 N4 A 16• For VOA and RSK-175 saakpiaa, warn, k2bbl= preunt r `*21-sJsc" (/Vor 6nin1 ;r. diameter)
rn any o'"the. VOA wig Ile 7
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Ycs No N_A ]S,Jerrr all va.nlcrc s�lnplos recCivcd gt a k i i2 a�1d sulri sam 145 re�citiT i ae a pl1 9'r
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Yes 'V Ni) 21. Was the gunte niurlorJisted rns the container labcl7 Ifycs, QuElle
'rpmlaleFreserw�liau (M•�sl be onmplataJ J'�s,-arysamt Ie s mcprrocti
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lore of prt'�Crvation 1`'° _. If DIM than one p esel't'at ivc is needed, please nuts in '.he c«, rum-ouv hC low,
arnpie(s) ran
were. rccai-,aesl wirl: hu. bjqs >6 m7n in diameter_
ry .sari..} 11
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 13