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HomeMy WebLinkAbout0201_Alexander_MSWLF_CDLF_July2020GW_FID1615833_20211004Data - Email CD (data loaded: Yes / No NC DENR Division of Waste Management - Solid Waste Notice: This form and any information attached to it are "Public Records" as defined in NC Gene available for inspection and examination by any person upon request (NC General Statute 132-6). vent IV .Reporting For As such, these documents are !restrticti®ns: Prepare one form for each individually monitored unit • Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g, naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Municipal Engineering Services Co., PP. Name: Jonathan Pfohl E-mail: jpfohl@mesoo.com Facility name: Facility Address: Alexander County Active C&D and 2500 Paynes Dairy Road Closed Unlined MSWLF Taylorsviile, NC 28681 Phone: {919}772-5393 Environmental Status: (Check all that apply) Initiai!BackgroundMoriitoring ® Detection Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitorinq data NC Landfill Rule: Actual sampling dates (e_g., ity Permit # (.0500 or .1600) October 20-24, 2006) 1 1 .1600 FJulyI4�17, 2020 Assessment Monitoring ® Corrective Action Methane gas monitoring data Corrective action data (specify) MNA,Phyto. & LFG Extraction Other(specify) Notification attached? iSe: No groundwater or surface water standards were exceeded. � Yes, a notification of values exceeding a groundwater or surface water standard is attached_ it includes a list of groundwater and surface water monitoring -points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or INC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding anexplosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification '< To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true an correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Senior Project Manager (919) 772-5393 Facility Representative Name (Print) Title (Area Code) Telephone Number (� 6 !S �® �p Affix NC Licensed/ Professional Geologist Se _\ ®®t`®e,arrrl�®®® Signature Date ,®® �H Cq ®�� al j P.O. Box 97, Garner NC 27529 + 'Q Facility Representative Address NOR SE 600 +3f0 C-0281 S •, i N;A';�,�, o` NC PE Firm License Number (if applicable effective May 11 2009)®,,°•ga,�PPdEre� •� roo Revised 6/2009 �P�'�®/���rR�146 ®���� Semi -Annual Water Quality Monitoring Report with Corrective Action Update July 2020 Prepared for Alexander County Active Construction and Demolition Landfill Closed Unlined Landfill Jonathan Pfohl Environmental Specialist jpfohlkmesco.com Taylorsville, North Carolina Permit No. 02-01 Prepared by Municipal Engineering Services Company, P.A. P.O. BOX 97 Garner, North Carolina MESCO Project Number: G20003.0 MUNICIPAL ENGINEERING AnEi'��SERVICES COMPANY., P.A. 68 SHIPWASH DRIVE, GARNER, NC 27529 -PHONE! 919.772.5393 P.O. Box 349, BOONE, NC 28607 - PHONE: 828-262.1767 LICENSE NumaER: C-13281 Introduction On behalf of Alexander County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report with Corrective Action Update for an event performed at the Alexander County active construction and demolition (C&D) and closed municipal solid waste landfill (MSWLF) between July 14-17, 2020. NCDENR Solid Waste Rules 15A NCAC 13B.1632 requires that Alexander County provide this report to the NC Solid Waste Section (SWS) on a semi-annual basis. Laboratory analytical results indicate that samples collected from 19 wells contained between one and four constituents above laboratory reporting limits and regulatory compliance Standards. Metal detections are believed to be naturally occurring. The source of VOCs is likely anthropogenic. VOC concentrations continue to decrease over time and distance. A metal was detected in an elevated concentration in three surface water samples. Corrective action to remediate VOCs in groundwater is ongoing within the four areas of concern (AOC) with updated information presented herein. A Corrective Action Evaluation Report (CAER) (DIN:27584) dated April 3, 2017 concluded groundwater quality has improved. The SWS approved that corrective action may continue as proposed and implementation of the contingency plan is not required. Background The Alexander County active C&D and closed MSWLF, is located at 2500 Paynes Dairy Road near Taylorsville North Carolina. The total waste footprint encompasses approximately 24 acres situated on 283 contiguous acres. The site location topographic map is depicted in the attached Sheet 1. The closed MSWLF ceased operation prior to 1998 and the C&D landfill continues operation on the eastern unit of the closed MSWLF. Both landfill areas are treated as a single unit in this report. Water quality has been monitored at this facility on at least a semi-annual basis since 1990. MESCO submitted two Assessment and Corrective Action (ACM) reports dated August 27, 2002 and April 11, 2008. MESCO then developed a Corrective Action Plan -Revision I (CAP -Rev 1) on February 6, 2009. In response to improved water quality and changing geochemical conditions the originally selected remediation approach was amended by MESCO in a Corrective Action Plan -Addendum (CAP -Add) dated December 20, 2010. Groundwater remediation efforts have been implemented at the four distinct areas of concern (AOCs) which are identified as MW-lB, MW-16, MW-24 and MW-26. Remediation technologies initiated to date with reference to their respective AOC include monitored natural attenuation (MNA) (MW-16, MW-24, MW-26), phytoremediation (MW-24), enhanced bioremediation via substrate injection (MW-26) and landfill gas (LFG) extraction (MW-1B). Following establishment of the two-year MNA baseline MESCO completed a CAER (DIN 13596) on March 22, 2011. Based on improved water quality conditions as demonstrated in the CAER the parameters and frequencies of future monitoring events were established by the SWS CAER review response (DIN 14150) dated June 16, 2011. A second CAP -Add was submitted by MESCO dated May 30, 2013 as requested by the SWS in a letter entitled Compliance Boundary (Relevant Point of Compliance) (DIN 18502) dated February 18, 2013. A Request for Appendix II Groundwater Monitoring Modification (DIN 20137) was submitted by MESCO dated November 8, 2013 which was subsequently approved by the SWS (DIN 20144) on November 13, 2013. A second CAER (DIN:27584) dated April 3, 2017 concluded that attenuation is occurring and no corrective actions other than what has already been initiated are planned at this time as approved by the NC SWS (DIN: 27678). 1 As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, corrective action update, ground/surface water characterization, and findings. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, time -series graph, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedures MESCO personnel performed this sampling event following the parameters and frequency established in the Water Quality Monitoring Plan (WQMP) dated August 11, 2016. The water quality monitoring program includes a combination of detection, assessment and corrective action monitoring with specifically defined analysis. Water samples were collected from all monitoring locations outlined in the CAP -Add and CAER with the exception of MW-IA; which has been chronically dry and two wells (MW-3 and MW-7) which are exempt from testing during the summer event. Monitoring locations are depicted on the potentiometric map (Sheet 2). Sampling was performed per the protocols outlined in the WQMP. A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping or bailing was utilized to purge the wells a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from previously designated locations along discharge features. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper chain of custody (C-O-C) protocols and within the specified hold times for each analysis. Field Parameter Data Field parameters were recorded including depth to water, pH, specific conductance, temperature, hardness and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix A. Laboratory Results Pace Analytical Services Inc. (PACE) of Huntersville/Asheville, NC performed the laboratory analyses. Groundwater, surface water and quality control samples were tested for a mix of Appendix I paramaters, mercury and MNA performance constituents as prescribed in the approved water quality monitoring plan. Water samples were analyzed to the Method Detection Limits (MDL) and reported to the Reporting Limit (RL) which are both established by the laboratory. Any value above the adjusted MDL and below the RL was flagged as a "j-qualifier" which the laboratory defines as an estimated concentration. Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. A sampling and analysis table summarizing the locations, laboratory, target analytes and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. 2 Quality Control Samples Barium was detected in the EB sample. Barium was not detected above allowable Standards in any sample; therefore, the presence of the artifact contaminant is largely inconsequential. Groundwater Samples Detected Above Standards Table 5 summarizes constituents detected in groundwater and QC samples compared to groundwater compliance standards which include Interim Maximum Allowable Concentrations (IMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Metals One to three total recoverable forms of metals were detected above their respective RL and NC 2L Standard/IMAC Value in samples collected from 18 wells as summarized below. Metals Detected in Groundwater Samples Above RL and NC 2L Standard/IMAC Values Cadmium Chromium Cobalt Thallium Lead Mercury Vanadium 2L/IMAC 2 10 1 0.28 15 1 0.3 MW-1 8.7 MW-lB 53.9 2.3 MW-2 677 0.3 MW-4R 104 MW-6 8.6 MW-9 356 MW-11 123 MW-12 56.8 MW-12D 2.7 Mw-13 3.3 MW-14 157 38.8 304 MW-15 12.4 2.6 59 MW-16 272 MW-17 15 MW-19 3.5 MW-26 64.9 MW-33 8.1 MW-34 5.6 concentrations in ug/L 3 VOCs Benzene was detected above the RL and 2L Standard (1.0 ug/L) in samples collected from MW-5 (2.2), MW-9 (1. 1), MW-11 (2.6), MW-12 (1.4) and MW-15 (3.1). 1,4-dichlorobenzene was also found in sample MW-11 at 6.5 ug/L which is above the NC 2L Standard (6 ug/L). A bar graph and table comparing the most recent levels of VOCs exceeding the 2L Standard compared to their respective maximum observed levels is presented on Figure 1. A site map depicting the spatial distribution of VOC concentrations exceeding the 2L Standard during this sampling event is shown in Sheet 2. Surface Water Samples Detected Above Standards Attached Table 6 summarizes constituents that were detected above the MDL compared to compliance values listed in the current version of the Division of Water Quality Surface Water Quality Tables. SW- 4R contained cadmium (2.2 ug/L) and copper (5.8 ug/L) which are above their respective 2B Standard (1.23 ug/L and 5.67 ug/L). SW-6 also contained cadmium at 1.3 ug/L which is above its calculated 2B Standard 0.67 ug/L. Groundwater and Surface Water Characterization At the landfill, groundwater flow direction generally mirrors topography, thus flow direction is from higher to lower elevations as shown on the potentiometric map included as Sheet 2. Locally, groundwater flow is expected to be generally westerly toward the Lower Little River, and southerly toward the Catawba River. Groundwater linear velocity rates calculated using modified Darcy's equation varied greatly and were slower in the upper bedrock fracture system than the less prominent regolith (Table 7). Streams at designated monitoring points were visually observed to be of normal seasonal volume, flow rate and low turbidity. Hydrogeologic parameters appear generally consistent with historical observations. Corrective Action Update Groundwater remediation continues to be implemented at the four AOCs designated in the CAP -Add. General background information and activities performed since the CAER and last semi-annual event are briefly presented in the following sections. MNA Analysis (ADCs MW-16, MW-24, MW-26) Semi-annual MNA monitoring of 14 wells for the full suite of SWS recommended parameters was initiated on June 30, 2009 and performed during four consecutive semi-annual events to establish a baseline per the CAP -Revision 1. The number of wells requiring MNA analysis was reduced to 10. The parameters and frequency were also amended per the SWS CAER review response (DIN 14150) dated June 16, 2011. MNA data collected during this event is presented on Table 5. Following an acquisition of a 15.7 acre parcel from Crescent Resources on March 3, 2011, extension of the eastern relative point of compliance downgradient of AOC MW-16 has been approved with conditions by the SWS on February 18, 2013 (DIN:18502). Recordation of Survey Plat titled Survey for Notice of Contaminated Site Alexander County Landfill and A Notice and SWS approved Declaration of Perpetual Land Use Restrictions for this parcel has remained at the Alexander County Register of Deeds Office 4 since November 13, 2012. Alexander County purchased another 2.15 acre parcel that adjoins the NE corner with deed recorded on 3/26/18 which effectively increases the relevant compliance boundary in a NE direction. The SWS approved CAP -Add and CAER (2017) clarifies that groundwater remediation of AOC MW-16 will remain as MNA, rather than other technologies described in the preceding CAP -Add. Phytoremediation (AOC MW-24) County personnel planted approximately 200 hybrid poplar trees over an approximate one acre area between MW-7 and MW-12 in May 2010 in an effort to phytoremediate groundwater in the MW-24 AOC. The County continued to maintain the fence -enclosed stand during this semi-annual period which included supplemental watering and eradication of competing vegetation. Total cumulative VOC concentrations in AOC MW-24 during this event have decreased 61% compared to its respective 2 year baseline established in 2010 and a statistical decreasing trend is evident. Assessment of the phytoremediation area which includes tree measurements and downloading groundwater fluctuation from dedicated transducers was performed by MESCO personnel on July 16, 2020. The majority of the trees appear to be dying or have died; therefore, Alexander County should consider replanting some trees. Enhanced Bioremediation via Substrate Injection (AOC MW-26) In an attempt to remediate benzene as detected in MW-26, Bac-9 was injected 50 ft upgradient in IW-1 on February 17, 2011 following conditions in the Underground Injection Control (UIC) Permit WI0300160. The UIC permit was recently renewed and as directed by the UIC post -injection water quality monitoring of MW-3, MW-11, MW-26, MW-27 and MW-31 is required on a semi-annual basis. Benzene has fallen below slightly below the 2L Standard during this event. Contaminants remain within allowable levels at MW-31 located along the MW-26 flow path beyond the compliance boundary. Most recent levels of total VOCs compared to the baseline established during the four events prior to injection exhibited a reduction both upgradient (-53%) and downgradient (-89%) of the injection point. Most recently, total cumulative VOCs from all samples in AOC MW-26 decreased 62% and benzene concentrations fell 43% compared to the baseline averages established during the four events performed over the two years preceding the injection (Figure 2). Further injections are not planned at this time. Landfill Gas Extraction (AOC MW-M) Three LFG extraction wells (MEW-1, MEW-2, MEW-3) were installed screening the majority of the vadose zone at the northern border of the closed landfill in the vicinity of the scalehouse. MEW-1 was installed on August 17, 2010 with MEW-2 and MEW-3 installed on October 20, 2010. Well control heads were plumbed to a header pipe by the County which was connected to a soil vacuum extraction (SVE) unit on July 5, 2012. An active LFG blower system pilot study was performed by MESCO between June 14, 2012 and July 12, 2012 to evaluate the effectiveness a vacuum would have on reducing levels of LFG in the soil which may remediate the low-level VOCs detected in groundwater hydraulically upgradient of the landfill. A comparison of LFG concentrations and pressures before and after vacuum start-up indicated the system is capable of eliminating LFG migration at all locations monitored within AOC MW-1B. The active LFG Collection Control System (LFGCCS) has been in continuous operation since November 1, 2012 and been verified and documented by MESCO personnel on at least a quarterly basis to be mitigating LFG migration through the vadose at all locations monitored beyond the extraction wells. Improvement in groundwater quality has also been observed in response to implementation of the LFG extraction system as summarized below and shown on Figure 3. 5 Decreased Contaminants Since LFG Extraction Began We11ID Dissolved Methane(%) Benzene (%) Total VOCs (%) MW-1 -92 -86 -84 MW-1B -99 -97 -97 The LFGCCS is planned to remain in operation and will continue to be monitored and assessed on a quarterly basis. Findings During this event there were 24 instances of metals detected in quantifiable concentrations above NC 2L/lMAC values which is typical for this site. Cobalt continues to be the most prevalent metal detected and was found in 46% of the samples. The source of metals is believed to be a product of erosion of natural deposits except for mercury which is believed to be transported via LFG. The semi-annual laboratory results indicate that dissolved phase VOCs, consisting primarily of benzene and a few chlorinated solvents, continue to be detected in groundwater samples collected within 270 feet of the waste boundary. All VOCs detected during this event remain within their own respective historically identified range. Total VOC concentrations have not exhibit an increasing trend over time site -wide and in each of the AOCs. Statistical Mann Kendall trend analysis performed at both a 90% and 95% confidence interval indicates a downward trend of total cumulative VOC concentrations at every AOC (Appendix Q. Total VOC concentrations during this event, compared to their own respective averages calculated during the two year baseline period (ended in 2010), indicate a reduction in each of the AOC's as shown on Figure 4 and summarized below. Total Cumulative VOCs Baseline Average Compared to July 2020 AOC 11 Total VOCs Baseline (ug/L) Total VOCs July 2020 ff (ug/L) Reduction (%) Statistical Trend AOC MW-1B 12.16 0.94 -92 11 Downward AOC MW-16 12.14 11 6.49 -47 Downward AOC MW-24 7.92 3.08 -61 Downward AOC MW-26 30.24 12.30 -59 Downward AOC Undesignated 12.39 6.18 -50 Downward All Wells 14.58 6.05 -58 Downward 2 Evaluation of current water quality data continues to support assertions drawn in previous reports. VOCs persist in the upper portion of the aquifer but concentrations continue to decrease over time and distance away from the landfill. MNA data and previous screening models indicate that the plumes within each AOC are stabilizing and/or decreasing and there is evidence that natural attenuation is ongoing at the facility. Implementation of the corrective action measures coupled with natural attenuation is expected to decrease VOC concentrations in groundwater over time. Closing Water quality monitoring and corrective action is planned to continue in December 2020. Notwithstanding any changes targeting of the full Appendix II list of constituents is planned to occur again during the Spring of 2022. 7 Sheets Topographic Map with Site Location Alexander County Active C&D and Closed MSWLF 'rv��o ar.7e oevewr.r�f o�� -xe irvreRiov 2500 Paynes Dairy Road Taylorsville, NC 28681 Lat:35-15-18.7246 Long:-81-08-51.51.32 Northing:767009.09 Easting:1363506.43 tN rLANDFILL PROPERTY QUADRANGLELEGEND ROAD CLASSIFICATION Primary highway, Light -duty road, hard or hard surface .............. improved surface .... ___ Secondary highway, hard surface ............ Unimproved road..._________ 0 Interstate Route 0 U. S. Route O State Route 0 1/2 1 MILE SHEET 1 \ I 1 \ 1 _ _\\ \\ \\ \\ \ I I I I I / / // \ \\ \\ I \I 11 /' / / \\ \ \ \ \ \ \ 1 I / -� /� --__ \\\ \ \ \ l \1 \ 1 1 / / /'/ : /' .-- -------\\, '\\` \ \ \ `\ \ \\ \ \ \ I. I r MW-20 ,' W-19 ) ; 11 I MW-1B - / , ,' -, \` ` \ ` -, ` ` \ \\` ` \ \ \ \ GWE=1008.47 GWE=1045.90 MW 18 / / / - I-,-,,---- --\ ` \ \` \ \ \ \ ` \ \ \\ N. \ \ - GWE=1024.14 , / I 14i.,}� GWE=1039.44 ,,/,,/ �/ �/ �/ ,' ,' ,, �/ `_-'`\ \\ �;♦♦ `\\ \ \ \ \ \\ \\\\ \ ` \ \ 1 t ---F- / hY^ - , / "/ /I . ��• ti �� ' - - \ \ \� I \ I .-\mac . IX I0111, -\ 1 4�4".- - - "So oel I 1�, - _ _ `41110 to /-'-i--/ -' /' , / - �/' 11 / '/ MW-21 \\; \ \ \\ `\` \ - I I I I \\ I I /--j 1 /• \\ / '' - \` \ �' / - / / / - - - - / / - - ♦ GWE=964.15 MW-17 \ \ ` ` \\ \` \` \_ `� t 1 ' ' 11\ C\ ' I \ 1 7,♦��l � ♦/ GWE=104 6� / / /� \ \ \ /5�� / i ,.�/�/' //� - �,' --' --'--- -'' /'/ -'' --' -' 11� GWE=976.01 .\\\ 1 I 1 1 \\ \I \ \\ I 1\ (\ \ / I ♦u ,/ /l t `__- -- / l ♦1♦ / , / / - , - - - - - -/ / , --- - ai l ♦ I I \ \ \ .•-�- ♦♦ - \ — — ,• ;:>i _ \ �♦ ♦♦ \ \ \ \ ,�___-MEW-3 //// /' / / ,//' W. .' /' ' ---- i '-- ,,a ,- ♦/ '- - --- /-i i i '- MW-15 \ \\ \ \ \`\\ 1 \ \ \\ 1 ) \\_ -.� / OL // r I '. /� / I A-Ir• I 1 i .' - ' \ I �♦ , , -/ Benzene - 3.1 u /I \\ I t i I \ I 1 i _; - -o • _ ��� iy 1 l / /,//' ..1 i' . �/'-- - --� -'�'/ \ 7 t / // /' =:.:'-' ' ` ` `\� \ \ \ 1 ' 41 1 __�� i I I 1 -' -'- - MEW-1 . = -- - l;i �•• 1\ I i i i i \ ` \ \ / - // /' /'.' ' '--' /' - - ', ,- - ; l + l ' /' / i _i- MW-15 - - 1 \ „ \ 1 I ,_"\ \ 4 6 ,J \ S � �� •• \\ A ` I I 1 \ \\ `\\\-�_- --///-' - -' - - - - -- l , / / , / / / - 010 .�I- ---� - / / MEW-2 '---- _—� \ / \ '--- , /. / / , - - ' - --- -' -' ' - -' ,I / / 1 1 / / / / / -- -- / 'lam 3 __ - _-�' "/ / / / I �\ II 11 -- \� �\\ / I I I I - `\- `�� _ -,i / . / / /'/' -' /'-'' -' - \l , l l l I '/ / l / - .� / GWE=1000.47 - - - - \ - ---_- \ I I \'-� - = -' -' / (/ / / / ( 1 1 (1 1 i ' / i ,/ = 40 =__';%' - 0 r_- ��l\ 1 __-----___ \ \ / I I I I I LFG VENTING SYSTEM - -- -.MW22 I / I 1 / - --/ -= - - - - l \ t 1 — --i' -- \,\\\- l / I l I I l ■ ------- - - - -/'G - - - --- - - -- WE 944.24 , I \ I \ I vel i - - - , , - \ \ I / ■ - �i-'/--i /' i'�/'-'' -'- -- -/' / / - - - - - - -- --_ --_ _ - ---' - - - - / / //, \ 1 \ I I III I { 11 ,ice/ �- - _ // / 1 \ \O - \ -- / - _-___- \ \\ \\\ \ / % / / / _----- / ' - / ' - - - / / /' / I 1 1 I l I I I 1 ///� - - - - - = �- 7 ` I I /'/ ' I I '/ / / \\ \\ \ / % / ■ --- , , - . - -/ - -' ' -- - --'� / I / / / / I 1 I 1 O\ \ 1 // /, -'i-- -' - --- - r / /I \\\\ , \ 1 \ - 1 I , \ \ / / / / ----,/-, -, . -'-/ -'- / / ,/ / / l I I I \ / /'/ '/'/ /' - -/ _-/ / / I \\\1 / // / \ I 1 1 I / - - \\ \ \\ \�\\ / , / / / ■ ---------' -- . . ,/,/�- -' - '--' -- --� / / �, ' , / ,/ , / I 1 1 /,/ /// ,'/ j' ,i',-' r / , 1 `6 O / \ I I I� / / _\ \ / / , ■ ------__--''- - --'-'-// -'--- i-'-''' -'- -- - �� / / /♦♦ ,' , , / -- / / // //// /, / / / , -\ 1^ I /It / / \ I / . \I \` \ / �� / It CLOSED _ ` \\ / / / / / ■ -'-''-'-' /' '�,---, '--'-''//-'--2� / / / ♦`/ / / /// ' - I ///�'/' %/% // l� �`..11 ! / // , / I / / I \ "-- \ i //// / MSWLF `\ \ I I , / / / / / ■ - - - -- - / / \\ J // \ / / \ \ \ I , f \ / / / / ------- --------'- /- - / f r// / / / - r �/ // /// , / \ ` --/ i I I / // -/ __-- - \ III \ / , , / / / ■ -- - I - , ),)/ " / / I I I - -:I::-"- I ,,, -�- /I / 1-1 -,< \ -- -- \ \ I / / / / / / / ''- ♦ / - //', / / "/ /' / ' / ' I ' / /� / /- ,/ -/ - , I , III N/ / / / -------------''--'' -------' -'/ /' - \ / ♦ / - / / ' -i , ( / / - I I - , - / / I I 1 ---------- _ ---- - 4 ♦♦ //, , //, /// / /// // I j / 1-1 �/' II`I /%" i'-/' -/%' / // / - I I I I � � j 111 I ' / // / I//// \ \\\ \ \ \ \ ------------ ---- -'' MW-23 ♦ / I / / / - / �ii / �! �__) / / ��_- �> / / / - 1Q- - --, i / I I I I j I YII I I I / I � I 9� / // / / \ \\ \---------------- i -- - - / / / MWE 960. l i / , / //// / % \ _s/ _7 / / ,-i' l '' -- / ----- / / I /III I % l I I 'T I I /, // / ■ --I GWE-93 �9IF // / / // / \ / O --------------- - l I / / / / / I I I / / / // / ■ / / / \ \1\ `\ `\`�\ \ \` ` `\\- - ` ' ' l . 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I I I , �� / I \ r / / l / rf / / / CLOSED / - I I 1 I . / . , -, ------ // / /i l i l i \ \,\ / , , / -\ \� / , / / / , /' , /i -� � , - - -/'' /�� - / l / / 'YC / / // I I t \ \ /ii' ' �_\ _------------ / / / IIII I \W, / \ / , / , / , / , , / ' / //' / �i' MSWLF / _ // -, _ \___ y\\ l l 1 r / / / / / / -� /� /' / --' ' ,/ ' /. i, ' / / \ow , /// // -, _ - /// GWE=1012.46, /'/// // l l� - \\ ' -' ,i' -� \� \�! l / / / i / / / // /, / / -, ,, , - 'i , / / , , / / /, // , I I / / / / ) / / / / / - , _ __?I, -------------- -/, / / / l/, l \ MW 34 \\ / / /// / ,O'/ /,'/, ,'-,/, / '♦' ,ii'i'-'i'i / , / / / , `/ - s I 1 \ 1 / / \ \ , ,// /„/ - ,_ -__\ -_ ------ // / ,' // /,// /,ll ■ GWE=1006.47 / / , - ,- / /, / - , / , r--, \ / / / /' - - / // ,r 1, // / / / / , I j // , \ / / , , , , / //,/ ,,/„ /,, , - ,-,' / , / / , . , --- --- I I \ \ \ / / / / /.- \ / ,�'i / / / / ,'// / / / // , / / l / / / // - ,-, / , - , -, / I \ \ / // / / // / M � ,�" ( ACTIVE C&D OVER 1 \ \ \ I \ \ / / , / /„ / '/ -- -- 1 , / / / / / / /i / „ 11 -IMP , /, / / / / / / ' , ' /,// / -' / --,- / i I I I ' I I I I I \ ( I I I 1 1 I \ \\ III \ / /„ ,- j// // / - _ - � \ \ --1, // / / /// / / r I I / , / / / / / / / , // /, / / / / / , I If,/ // �/ kk ) 1 I \\ \ \ \ \ \ 1 I I I \ , ,-- ,,�-,/ r _---- '___- \ \� �`___ - / -/ / i / /ii , / / l \\ is / / // / / / , // / / // ///' //'�,/ '� "' /' .�/ \ \\', \% \ \ \ \ \ \ \ I I I I I/ \ \ ----- `.- /j/ // ----- -, /-''j0�-- _\ \ -, /�/ / GWE=1008.55 / 1 �W MW6 \ \ \ \ \ \ \ I I I I I I \ \ \ /''\ /' -i , �' _ \ ` \ ' ' /'/' - Ut 11 /'// /�l \ • �\, --- SW-4R ' / / / / . / / / // , / / / / / /, /// / i'' /''/ / / 4i' ! .// 'i'/' / /-', \ \ \ \ \ \ \ ---- (- ---- I I I 1 1 I I It \ \ ,- /j\/ - -/ / _/ / / -- /--' \ \ \\� ' 'i/ ' / / / / . / SW-6 ---I'll ___/ / / / / / / / , //, //, / /, ////, , /, / FILL AREA 2 I 1 \ \ \\ \\ \ \- J I I \ \ -- / -'I/ // / , - //- / % { < < [ _ / I / / -' / /'/ / /,i, / / / / / // / / / / / / /, //, / / / / / ' /I- / ' / /� / 1 000 I I I I I I \ \\\\ \ \ \ \ \ \ \ ( I 1 I \ \ \ \ \ -- - - / / / - - / I'll / ----' l I ` \ �. y'� 1 I I , / / ' ' / I / l ,,' -- / /// /// //// /// /// /// //, / / -- // / I \\\\ Imo\ \\------- t \\\ \ - -- / ////-i -/-,/ ;- ', �/ ( ' \ J-C.. _/ I / ,/ /// - II , / ,, r/ 1 \\ 1 \ ---- /,,/ / . , / ,- / I , - `(-Jc{ , I I 1 / - , /, / / -/,� 1 , Il 1, l/ -'----_ / / / / / , / / / / , / / / / / M / 1 1 ! I I I \ 11 \`1NII 7\ \ \__ \ -\, / - - , / / -�/ /I'll// / 'i/ ' i \ \ \ \ \ _ _ I I 1 1 I 1 / l lI, / / l l l / //'-_-___ _-'\ / / / / / / / '' / / / / / // % / I I l / /l l / / / I / / l I i I I I l- \- __- I \\\ \1 \ \ �\ \ -------------------- ' /, / / /, / /'i/ / // / -'i-,' , I \ \ \ \ \ \ �\ / I I I / , 11/ / / / ,i''-' --\ ' /I// '''/ I/// //// I/ l // I , !l / / I I / _-_- I I I L�Q ` \\\ \\ \ \`_____ ) 1 \ ---=-"\�"' /-'i/ /-// / /-, /'yII \ \\ \ ` / ' 1 I' / // //'/ 1I1� //// I I 1 _ /'i' .' / / / ii' /' /' \ \ \ \`{ `\ \ _ \ \ 1 I I I / I l / / / / I I I I \\ \� \ \\� \ \ \\------------ --- I I I \ ` ____ 1070 \ `\ , �• / / / /i/ 1 \ / I I I / / I l �i-/--i�--_-_ __\ , // 1 I f 1 / I / f I I 'III I l , , I I 1 /■ l / / / / - 1 \ \\\ \\ \ ------------------- ---- `-_-_-\__-__—_---�-- - - _-\ / /, , -/, , // /// , 1 \ \ \t� \ \ \ St \� I / / / / / / ---- -\ \ / , / I I I III I I t I / / I I I 1 1 I I MW-13 I 9 I 1 1 1 \ \ \ \\ \`__ - 1 \ __ - --' /'/ / . , // ///' , " / /- \ \ \ \ \ `>�' \\ r� / I I I I 1 / / / I I l I l l \ \- / / I I I I I I / I I 1 I 1 4 t - 0 C1 ---' I I l t j . \ \ ` \ `\\ -------------------- `------- \ \---_ ,- -;-/ / / -/i' i/ / // / , /�,/, / \ \ \ \\ \ \ \\ O \ 1 1 ) 1 I / /' % / l I l / // --- \ \'i I l r 1 I I I I I j 1 I I 1 j ' I / / I I ' I ' I I GWE=967.86 1 I 1 \-- /' I I I \\ \\\\ \----------------------------� _ �\ ___-,'' =, ' /// / , /i / / %^1 \\ \ \ \\ \\ \\ \\ 1 I ,/ // , // I l I 1 I \ \ _ /, / // / \ \ \ / / / 1 I / I '/ - / -- -�� ` \ \ I I I I I { I I I I I I I , / , I I I 1 \ \ - �- - ---_ -____ ____-_- _-_-_-_-_-_-_-_ _- \ \ \ ! / / I I / / / - _ \ \ \ I l I I I I I // / I I I , o / I -� \ \\\ `\`___ ----__ --- - \`-- _ _ -//'�, ,, ///, /„ / , \ \ \ \ \ \ \ I 1 1 / 1, / I I ,' /' , \ \ I I III I I'' 1 / I I I ■ I I \i�l I \ 1 \ \\\ \\ V -\ - / l 1 -------------------------��- \ _ 1060 , .',�� ///, /„ / / , ,, I \ \ \ \ \\ \ \ \ \ \ l I l l / / -�I III 1 I I / / _ \ \ I I I I I I I I I I,/( / / / I I I J I 1 I v1\ \ \ �� V \ _ - _ -/ , /// / ' ;� n \ \ \ \ \ / /� Ill / --- \ I I I I ■ 1 I I l \ \ 10 0 ��__` / ,' / ) ,- `\ \\` ` ` _\--= -\ . ,',:',:-c//,/ / //, I/ / 1, \ \ \\ \\ \\ \ \ \ l / I / , MW-33 //. , I l 1 I I I I /, / / / , --- \ \ I 1 I I l I I I I / l ■ I I I 1 I \ O / / /---------------------- - --\ --=- , t_--- ''%'/%' / ii'\/i -ii'/ /, i ,�'�) /` \ \ \ \ \ \ \ / , , ,,....... ♦ I I I Ill / '- / '''-- ` \ \ \\�� I I 1 I I l l I I lilt 1 I I I I •I 1 ' I \ \ -- _ - _ ________________'-----\_ _ --' / ` \ \ \ \ / / l/ GWE=994.53 / I l I I III / / - \ \ I I I I I I I , � \ \ I I 1 I 1 \ �3Q; \ ` - \ -------------________ -= _ - __ 1050 �-'--- , / / / / / //�\ \ \ \ \ \ \ \ \ / / /, / , / i I I I I / / \ \ \ \ I I 1 ' I ' 1 (\ \ \ \ 1 t 1 ♦' ( \ \ \ \\ \ `-/ ` �\ �'-' /-c-------- - __ ---- - "\-\ -\ \---- - _ _ / / , / / /' -i %%'/ii' ll// \ ` \ \ \ `\ `\ \ MW-10 M / / / / / /l I l lI / , l / l / a 1 I 1 I I 1 I I �_. , / / \ \ I � 0 \- --'---------- - / MW-4R \ / M /„ ---_ \ \ I I I ,, I I \\ \\ \ \ \ , 1 \ I 1 \ \ \ ` h\�\ _-- ��; �_ - -_---MW-3=�� 1 \ \_�---------- / / , , / , \ \ \ , / /, / / / I' I I I I I /// ' /' \ \ \ \`\ 1 1 1 1 I \ \ \ \ \ \ \ \ \ 1 \ \ \ \ `\ `� \ - --- - MW7� _ ------ - ` \ \ \_-------- _1U40-- -' I, , / / // /// - / / \ \ \ \ ,\ GWE=1004.58 / , / / / / / / I I I 11 J _ I I __ _� ) - -- -- ` ------------------- ------ _ / ,// /// / / / /\ GWE=,q, 91 \ 1 . lI l 1, , l II 1 1 1 I 1 --- / I /// / -,-- \- \\`� \` ' ' \ I I 1 \ \ \ \ \ \ \ \ \ \ \ _--------------- ----- / /// / / / ' - \ `\ \ \ \` / \ I 1 \ I \ \ \ \ \ \ `- _ I r GWE=999.39 ------ / / / \ \ \ It \\ \ \\-�--__ GWE-972.52 1 1 \ / ,, / / / \ \ \ \ \ I \ / /�' / / I I / , /, ----_ \ \� \ \ \ \ \� \ \ , 1 1 \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ ♦ \ \ \- \ -I/ - ��--�: l _ ------------------ 1030 1 1 I I I ■ f / / / / I IIll ' c� ` _- - / - %/ /// �/ / \ ` ` I II 1 \\ \ I I I I I \I. ■ l l l , ,i / 1 l I I I It / / \ \ \\ \ 1 I I\ \\\ \ \ \ \ \ \ \ \ \ , ,^t \ - _ ;-. /// /// / I/ \\1 11 ) I I I 1 ■ / / l ll l,l , / ,/, ,l,l 11 IJ 1 / / / //---- _ \ \, \� \\`\\\ 'i I I 1 \ \ \ \ \ \ \ \ \ \ \ \\ \ \ ` \ �`\ `\ \\ \ 1 �l , ` ` � ' I / \'%/ l ` \ / ___ ------ - _ --_--- , i i j/ // / / I , 111 I 1 I 1 1 , I I l 1 1 \ \ / , / / l 1, l l I, // /,/, III 1 111) I I I I ' J ' / ' `� ��\ \\ \� \ \\` IIII 1 \IIII \ I \ \\ I I \ \ \\\\ \, \ \\ \ \\ �� �\ ,-_\ --' \\ \ I , T —/— 1 — r' / l \ l /' II ��i / _ /r -------------------- - __--__ �i -' //, / I - \\ / l l I I I I I I I I I I \ \ \\ / l / l / / 1 1 1 I I I I _ ---- _ I _� I 1 \ \ \ \ \ \ / / --- / / I 1 / / I I III I I / /' \\`�\-`� \\\\\ \ \ \ \ \ \ 1 I I I I \ \ \ \ --� / / / / -/ / / / - - _-- , // /� I I I I I 1 I I }--= \ ■ / , / , / I I j j I I I I J I / \\\ \\ \ \ \ \ \ \ I \ \ \ \ \ \♦ _� \ _ a / (/ / , / - I' \ I! 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IW-1 - / / / / ,- / rs 1 - l l j I 1 ' \ \ \ ` `\ `\ , / , / / / / , , , \ I I I I I I I 1 \ \ \ \ \ \\ \ ` 1 \ \ \ \ I \ L_-------� / \ ••■ .:�; �!/' ,' (' MW27 , // 11 I ( / , / 1 1- I I y \ \ \ ` , - / / /'/ / '' '' / 1 I III 1 1 1 \ \ \ \ - - \ \ \ \ \ — /- '7 / GWE=970.81 M I 1 I 1 =\ 1 I, \ \ / / / / I I 1 I Ill' 1 I 1 \ I \ \ \ \ \ \ \ \ \ \ I III I / / / I I I I I I IN' \ \ \ \ \ \ \ / / / / / / / / / , Z I I ' ` \ `\ `\\ ` \ :-- _-- ��: ` \ \ , ------- GWE=945.64 \ I \ ' \ \ \ \ \ \ l //, ♦ , _gg � I I / / / 1 I I I 1 \ III \ \ \ \ \ / / /, / / / /„ , \ I I I \ \ \ \ �- ___ -__ -_ \ \ _-- \ \ \ \. � _- � / y P-2O-__-_-- l I I 1 I I III-\1 1 I l\ \\ \ \\ \ \ / / / , , // ' '� I I I \I\1 \ \ \ _ 0 � GWE=973.66 I I' 1 \` \ \ \ `\ `\ \ -__ \ \\` \` ` \ ----__ \ \\\\\ \ \ \ \ \ \ \ \ / -I / � IW O P-3 /^ -----_ I I \ 1 / / - , I I I �♦ \ \ I \ \ \ \ \ I \ / / / // /'/ "�' ' // I4 1 1 I t I ' 11 I' 1 \I I / 1 \ \\ \ `\ \ \\ -_-___ \ \`\`\\ \` \�--------_-_- '\ \ .\ \\\ \ �\ \ \ \ s . \ \ \ -- i' , / //\/ ♦��`� v __ - I I' / / I I I I t 111, I 1 \ \ \ I 1 / / // / // / / / I I I I I I \ \ \ \ \\\ \ \ \ \` \ `\ \ \ \ \ \\ \ \ \ -_, -, , I,, / J� , I _---_---- _ - \ \ I I t I I / / , ' I 1 I Ill I yl♦_ \ \ \ \ \ \ \ \ \ \ \ I I , /, / / / / /// / / /i 1 I I I l J J I 1 I I I 1 , t 1 1 \ \ \ ` \ \ _ _ \ \ \ ` \` \ - -_---- \ \ \ \ \ \ \ \ \ \ \ \ \ \ _-- / I V / ♦♦ P-1 t I I r_--_ ----- \ \ `\ \ 1 I I I I I I I , / ' 1 III 1 ,\ \ \ 1 1 I I / / / / / / /// / / / / I I I I 1 I 1 I I 1 \ \ \ \ \ - �\\ \ \ \ \ -----_-_ ` \ \ \ \ \ \ \ \ \ \ — — -�' / / / __ --- , \ \ \ 1 I \ .-�\ 1 t t III yI�^^ I I - \ \ \ \ \ I J 1 / / I I I I I l 1 \ \ \ ` - _ \ \ \\ \ \ - \ \ \ \ \ \ \ \ \� " / /i I / / •• l ///,- --- 10pO ♦ J 1 1 I I 1 / / \ I I • r111 II \\\ \ \\ \ 1 I I , I I / I I I / ,/ / ,/// -/ ,- / -I I I l I I I I I I I 1 1 I t 1 1 \ �11 111 I \ I / I 1 // , _ t I I I 1 1 \ /- / / / 1--'__--- --_ I III I11 I I \' I l 1 / / I / / //// / �/ /' 1 1 1 I 1 1 ' I I I / / / -t I I I l 1 \ \ ��-_-------_-_� � \ \ \ \\ \ ��- ----_� \ \ \ \ \ ` \ \ \ � I /I I 1 I I I I I � ■ \ ' \\\ \ \, I I I I I l /I / / I ( ' l 1 /ll / / --I 1 I 1 I I l I J I 1 t1 1 1 \ \ s \ \ \ \ \ ` ` ` ` ` , l /// / 'i - MW26 ` >s 1 ll'1 / l I I I I I / i�, 1 I 1 I \ \ I I / / I \ \ \ \ \ \ ` \ ` \ \ \ '___-_\ \` // \ 7�♦• I /-��� � �-�- ----_� -_� l I I I I I I •• \ I I 1 11 111111111 1 \ \\ \ I 1 / I 1 / / � / 1 I 1 I I 1 \ \ \ \ \ . 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LL I 7 \ I, 1I l\ I 1\ 1 1 1 I I 1/ / 1 1 Ill l� / , I I I 1 l 1 1 I _-\\\\\\ \\\ \ \ \\ \\ \\ \ . \ \ 11 t- O -/III / / / / / / I 1/, 1 - � 11•� I i 1 I / 1 1 I'' I \\ \111 Illl I I I / I1, O 1 / - = 1 I I I I I I I 1 1 l \ �,\ \`\ �; `\ 1 ` \ \ \ \ \ -- It o / , I 1 - / 1 I 1 I 1 / tI I� I I 1 I111 \ I I I 1 I I I / .�I Ill lI , I 1 I I \ 1 / I 1 Il \\ \ 11 II \ 1 1\1 It'll 1 I 1 ll l / l I I 1 ���---- // )\ S-. \ \ \\ \ 1 \ \ \ 1 '\�\� /--' / / II//II 1 ' 1 /' / I I I I I I 1 / I d 1 II lip `\ IIII � \ 11 tI I j1 I l ll I I 1 1 IIII \ ,/ --' /- , \ 1 1 , 1 _ / I I / I 1 1 \ 11 t \ 1 11 111 I11I 1 \ t ( I / , ,I I I , I / / I I I I I 1 \ \ \ \ -- MW-25 \ \ \ \ I \ \ - � t l_--' -/ / // / � / / \ lllll, I ' �� _� l / I I I I 1 I / op 1 t IIII IIII \ \ \ I I J I � / / I I 1 \ \ \ \ I \ \ 1 \ ., , , / / / / , / \ / I ---- \ / \ 111 II \ I /l I Jill IIII I11 I'll 111 I I I t ,I I I I " I '/'I Ill' I/ , 1 I I I I I I I \\ \\ \ \\ \ .J I 1 1 11 I / 1 1 \ \ \\ -i-'/ ' '/'-, -,' - \ 116.`� ( 1 1 I , -- I .O�' / 1 / / , / / I I �\ / / / / / / \ 1 I nI \\ 1\ / I I III I111 1 11 \ IIII I 1 1 1 1 II I I I I l� / I, 1 \ \ \ \ LEGEND '- , / / . - . 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U Ln rl- ❑ W N w m U m I Z N =1 U Z � Z W W Ln Z W Z m Z W Q 0 U L7 0 J W m m 0) 0 'I m = N X0 3 m — 0 rn a co to 0- Fa dc Z O J Cj O LL Ex Wa cj aC4 O W J Z I LLI LL Z Lr- LLI CL u- 0 CL III uj Lr- 0 z LLI CL Q J Lu 0 QQ z 0 PZ LLI Lu U SCALE: AS SHOWN DATE: 9101120 DRWN. BY J. PFOHL CJI BY. PROJECT NUMBER G20004.0 DRAWING NO. I SHEET NO. SHEET 2 1 OF 1 Figures Figure 1 VOC 2L Exceedance Comparisons Histograms VOCs >21- Std (July 2020 Compared to Maximum) 12 10 8 J OA 7 6 4 2 0 �/1 Ol rl N l0 ■ BENZENE Max ■ 1,4-DCB Max BENZENE July 2020 1,4-DCB July 2020 Parameter Name 2L Std. MW-5 MW-9 MW-11 MW-12 MW-15 MW-16 Jul-20 Max Jul-20 Max Jul-20 Max Jul-20 Max Jul-20 Max Jul-20 Max Benzene 1 2.2 6.1 1.1 1.7 2.6 7.8 1.4 8.2 3.1 5.3 0.32 4.9 1,4-Dichlorobenzene 6 6.5 11.6 Maximum=Highest ever reported (1995 through July 2020) Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 2 Total VOCs and Benzene Concentrations Pre/Post Injection Comparison in AOC MW-26 June 30, 2009 - July 17, 2020 Cumulative VOCs Benzene Time Series Graph IND shown 0) W 9l n fD a B 4 B v a d + d• o-........' n 2L o fl_.... B N Sawle Dale rMW.11 DMW-% IMW47 L".33MWA1 Total VOCs & Benzene Concentrations Pre/Post Injection Comparison in AOC MW-26 nyuraullu Gradient In Relation to Injection Well (IW-1) Well ID June 2009 (ug/L) Dec. 2009 (ug/L) July 2010 (ug/L) Dec. 2010 (ug/L) Events Preceding Total Cumulative VOCs Benzene All VOCs Benzene All VOCs Benzene All VOCs Benzene All VOCs Benzene All VOCs Benzene July 2020 (ug/L) Change (ug/L) Change % July 2020 (ug/L) Change (ug/L) Change % Up MW-3 61.66 8.10 43.03 7.20 31.50 6.00 37.04 6.10 43.31 6.85 10.2' -33.00 -76 4.40' -2.45 -36 Up MW-11 53.28 5.00 46.25 4.50 40.81 5.90 43.20 4.20 45.89 4.90 22.45 -51.00 -48 2.60 -2.30 -47 Up MW-27 1 23.70 1 0.00 20.20 0.00 24.60 0.00 28.00 0.00 24.13 0.00 20.20 -3.93 -16 0.00 1 0.00 1 0 Subtotal Upgradient 138.64 13.10 109.48 11.70 96.91 11.90 108.24 10.30 113.32 11.75 52.85 -60.47 -53 7.00 1 -4.75 -40 Down 1MW26 39.40 1.40 20.00 1.40 39.50 3.20 30.75 1.60 32.41 1.90 3.72 -28.69 -89 <0.15 -3.72 -96 Down 1MW-31 0.00 0.00 0.00 0.00 0.00 0.00 4.61 0.00 1.15 0.00 0.00 -1.15 -100 0.46 0.46 100 Subtotal Downgradient 39.40 1.40 20.00 1.40 39.50 3.20 35.36 1.60 33.57 1.90 3.72 -29.85 -89 0.46 -3.26 -61 Up&Down Gradient Total 178.04 14.50 129.48 13.10 136.41 15.10 143.60 1 11.90 146.88 13.65 56.57 -90.31 -62 7.85 -5.80 43 = Concentrations shown for MW-3 from previous event (December 2019) since not required during July 2020 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 3 Histograms of Parameters in LFG Extraction Area (AOC-MW 1 B) E>issolvecl Methane in Groundwater J fa WEFO1 JUNE JUNE OEC JUNE JAN JULV OEC JUNE OEG JUNE OEC JUNE OEC 2 0 1 2 2 0 1 3 2 0 14 2 0 1 4 20 1 5 2 0 1 6 2 0 1 6 2 0 1 6 2 0 1 7 2 0 1 7 2 0 1 8 2 0 1 8 2 0 1 9 2 0 1 9 (Pre) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) (Post) � MW-1 MW-16 Benzene Cumulative VOCs O REDUCTION SINCE LFG EXTRACTION BEGAN WELL ID DISSOLVED METHANE BENZENE TOTAL VOCS N N N MW-1 -97 -86 -84 [MM-1 B -99 -97 -97 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 4 Total VOC Concentrations Histograms Baseline (June 24, 2009-December 9, 2010) Compared to July 2020 35 30 25 J rn 20 15 10 TOTAL VOC(s) BASELINE AVERAGE COMPARED TO JULY 2020 MW-iS VW-16 MW-26 MW-24 UNDESIGNATED SITEWIDE AREA OF CONCERN ■ BASELINE AVERAGE ■ July 2020 AOC ID WELL ID TOTAL VOC(s) BASELINE AVERAGE (June 2009- Dec. 2010) (ug/1) TOTAL VOC(s) LATEST July 2020 (ug/1) DIFFERENCE BETWEEN LATEST AND BASELINE (ug/L) DIFFERENCE BETWEEN LATEST AND BASELINE (ova) STATISTICAL TREND` Between June 2009 - Dec. 2019 MW-1 27.86 2.07 -25.79 -93 1Downwardl MW-1A NS NS NS NS ++No Trend++ MW-1 B MW-1 B 17.31 1.68 -15.63 -90 1DOWnwardl MW-18 0.00 0.00 0.00 0 HNo Trend++ MW-19 3.48 0.00 -3.48 -100 ++No Trend++ AOC AVG 12.16 0.94 -11.23 -92 1DOWnwardl MW-5 19.84 19.03 -0.81 -4 TUpwardT MW-10 3.24 4.16 0.92 28 ++No Trend++ MW-16 45.06 15.77 -29.29 -65 1DOWnwardl MW-16 MW-32 0.00 0.00 0.00 0 HNo Trend++ MW-33 4.40 0.00 -4.40 -100 ++No Trend++ MW-34 0.30 0.00 -0.30 -100 HNo Trend++ AOC AVG 12.14 6.49 -5.65 -47 HNo Trend++ MW-6 0.00 0.00 0.00 0 ++No Trend++ MW-7 15.27 11.6 D.19 -3.67 -24 1Downwardl MW-12 34.39 9.98 -24.41 -71 1DOWnwardl MW-12D 1.00 0.00 -1.00 -100 ++No Trend++ MW-24 MW-13 1.59 0.00 -1.59 -100 HNo Trend++ MW-24 3.18 0.00 -3.18 -100 1DOWnwardl MW-25 0.00 0.00 0.00 0 ++No Trend++ AOC AVG 7.92 3.08 -4.84 -61 1Downwardl MW-3 45.47 10.2 - -35.27 -78 1DOWnwardl MW-11 47.84 22.45 -25.39 -53 1Downwardl MW-26 32.41 3.72 -28.69 -89 HNo Trend++ MW-26 MW-27 24.32 20.20 -4.12 -17 �Downwardl MW-31 1.15 4.91 3.76 327 ++No Trend++ AOC AVG 30.24 12.30 -17.94 -59 1Downwardl MW-2 30.99 2.51 -28.48 -92 HNo Trend++ MW-4R 26.73 22.70 -4.03 -15 1Downwardl MW-9 19.55 17.55 -2.00 -10 1Downwardl MW-14 17.81 1.10 -16.71 -94 HNo Trend++ Undesignated MW-15 13.38 16.17 2.79 20 HNo Trend++ (No MW-17 10.55 1.50 -9.05 -86 ++No Trend++ Remediation) MW-20 0.69 0.30 -0.39 -56 HNo Trend++ MW-21 0.77 0.00 -0.77 -100 ++No Trend++ MW-22 2.70 0.00 -2.70 -100 ++No Trend++ MW-23 0.68 0.00 -0.68 -100 HNo Trend++ AOC AVG 12.39 6.18 -6.20 -50 1Downwardl ALL WELLS ALL WELLS AVG 14.58 6.05 -8.53 -58 1Downwardl NS = Not sampled since dry * = Statistical trend analysis of all events between June 2009 and June 2019 via Mann Kendall Trend Analysis at both a 90 % or 95 % Confidence Level. See Appendix C. D-s= MW-3 and MW-7 not sampled since exempt. Data from previous event (12/19) used for calculations Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Tables Table 1 Groundwater Monitoring Well Construction Table July 14-17, 2020 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of Casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 9/14/90 2 40.00 25.00 15 Soil & Rock 1080.54 1077.98 1047.60 32.94 35.8389 -81.1478 MWAA 9/30/94 2 47.50 32.50 15 Soil & Rock 1085.32 1083.28 1041.97 43.35 35.8389 -81.1478 MWAB 5/21/03 2 61.00 46.00 15 Rock 1082.56 1079.56 1045.90 36.66 35.8391 -81.1478 MW-2 9/6/90 2 30.00 15.00 15 Soil 1004.48 1002.28 983.85 20.63 35.8376 -81.1524 MW-3 9/19/90 2 33.00 13.00 20 Soil & Rock 1024.73 1024.23 999.39 25.34 35.8365 -81.1503 MW-4R 9/30/94 2 20.50 5.50 15 Soil & Rock 1012.64 1008.54 997.91 14.73 35.8366 -81.1479 MW-5 9/16/94 2 48.80 33.80 15 Soil & Rock 1051.26 1049.01 1012.46 38.80 35.8373 -81.1465 MW-6 9/29/94 2 41.00 26.00 15 Rock 1010.79 1008.29 982.95 27.84 35.8369 -81.1364 MW-7 9/29/94 2 53.00 38.00 15 Rock 1009.24 1005.84 972.52 36.72 35.8364 -81.1522 MW-9 10/24/00 2 31.50 16.50 15 Rock 996.27 993.76 985.12 11.15 35.8361 -81.1481 MW-10 10/25/00 2 91.00 76.00 15 Rock 1040.80 1037.83 1004.58 36.22 35.8366 -81.1469 MW-11 10/24/00 2 56.00 41.00 15 Rock 1011.96 1008.98 972.35 39.61 35.8359 -81.1505 MW-12 10/23/00 2 66.50 51.50 15 Soil 1007.35 1004.46 958.62 48.73 35.3577 -81.1525 MW-12D 6/9/00 2 100.00 90.00 10 Rock 1008.46 1006.03 951.13 57.33 35.3577 -81.1525 MW-13 10/25/00 2 60.50 45.50 15 Rock 1004.56 1001.63 967.86 36.70 35.8368 -81.1532 MW-14 10/26/00 2 40.50 25.50 15 Soil & Rock 997.44 994.06 960.24 37.20 35.8376 -81.1525 MW-15 10/25/00 2 35.00 20.00 15 Soil & Rock 1023.44 1020.81 1000.47 22.97 35.8385 -81.1508 MW-16 12/20/07 2 40.25 25.25 15 Rock 1037.56 1034.94 1008.55 29.01 35.8371 -81.1465 MW-17 6/10/03 2 22.30 7.30 15 Rock 991.16 988.36 976.01 15.15 35.8386 -81.1511 MW-18 12/19/07 2 56.70 41.70 15 Rock 1084.33 1081.52 1039.44 44.89 35.8392 -81.1467 MW-19 12/20/07 2 63.92 48.92 15 Rock 1071.48 1068.67 1024.15 47.33 35.8391 -81.1487 MW-20 12/20/07 2 63.55 48.55 15 Rock 1046.92 1044.19 1008.47 38.45 35.8391 -81.1502 MW-21 12/19/07 2 41.05 26.05 15 Rock 990.00 987.08 964.15 25.85 35.8386 -81.1514 MW-22 12/19/07 2 18.12 8.12 10 Rock 958.97 956.21 944.24 14.73 35.8381 -81.1524 MW-23 12/19/07 2 21.54 6.54 15 Soil 950.48 947.83 933.95 16.53 35.8376 -81.1529 MW-24 12/20/07 2 35.35 20.35 15 Soil 974.04 971.29 945.64 28.40 35.8356 -81.1533 MW-25 12/19/07 2 44.48 29.48 15 Rock 981.93 979.93 957.73 24.20 35.8353 -81.1528 MW-26 12/20/07 2 49.80 34.80 15 Rock 990.69 988.08 968.46 22.23 35.8354 -81.1504 MW-27 12/20/07 2 49.82 34.82 15 Rock 992.19 989.19 973.66 18.53 35.8356 -81.1493 MW-31 8/16/10 2 32.56 17.56 15 Soil 985.42 982.42 967.53 17.89 35.8348 -81.1506 MW-32 8/16/10 2 42.70 27.7 15 Rock 1025.26 1022.26 993.91 31.35 35.8361 -81.1469 MW-33 4/27/13 2 21.38 6.38 15 PWR 1007.40 1004.40 994.53 12.87 35.8367 -81.1462 MW-34 4/27/13 2 21.19 6.19 15 PWR 1014.60 1011.60 1006.47 8.13 35.8373 -81.1459 IW-1 2/14/11 4 52.44 37.44 15 Rock 990.44 987.44 970.81 19.63 35,8356 -81.1504 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) PWR = partially weathered rock Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations July 14-17, 2020 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Effective Comments MW-1 Yes Yes Yes Yes No Yes LFG odor MW-1A No Yes Yes Yes Yes Yes Did not recharge adequately for sample MW-1 B Yes Yes Yes Yes Yes Yes MW-2 Yes Yes Yes Yes Yes Yes MW-3 Yes Yes Yes Yes Yes Yes MW-4R Yes Yes Yes Yes Yes Yes Purge water odor MW-5 Yes Yes Yes Yes Yes Yes Case previously repaired datum may have changed MW-6 Yes Yes Yes Yes Yes Yes MW-7 Yes Yes Yes Yes Yes Yes MW-9 Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11 Yes Yes Yes Yes Yes Yes MW-12 Yes Yes Yes Yes Yes Yes MW-12D Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes Yes MW-14 Yes Yes Yes Yes Yes Yes MW-15 Yes Yes Yes Yes Yes Yes MW-16 Yes Yes Yes Yes Yes Yes MW-17 Yes Yes Yes No Yes Yes Well case hinge broken off MW-18 Yes Yes Yes Yes Yes Yes Purge water turbid MW-19 Yes Yes Yes Yes Yes Yes MW-20 Yes Yes Yes Yes Yes Yes Purge water turbid MW-21 Yes Yes Yes Yes Yes Yes MW-22 Yes Yes Yes Yes Yes Yes Pad slightly cracked MW-23 Yes Yes Yes Yes Yes Yes MW-24 Yes Yes Yes Yes Yes Yes MW-25 Yes Yes Yes Yes Yes Yes MW-26 Yes Yes Yes Yes Yes Yes MW-27 Yes Yes Yes Yes Yes Yes MW-31 Yes Yes Yes Yes Yes Yes MW-32 Yes Yes Yes Yes Yes Yes MW-33 Yes Yes Yes Yes Yes Yes MW-34 Yes Yes Yes Yes Yes Yes IW-1 Yes Yes Yes Yes Yes Yes Injection well. Not sampled this event. SW-3 Yes - - - - - Low gage height and flow rate SW-4R Yes - - - - - Very low gage height and flow rate SW-5 Yes - - - - - Low gage height and flow rate SW-6 Yes - - - - Very low gage height and flow rate Any unusual field conditions, observations, or events: LFG extraction system operating in AOC MW-1 B which is typical. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 3 Field Parameter Data Summary July 14-17, 2020 Parameter Water Depth Water Elevation TOC Elevation Temp. pH Specific Conductance Hardness Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm mg/L NTU MW-1 32.94 1047.60 1080.54 16.7 6.21 4 354 NR 21.3 MW-1 B 36.66 1045.90 1082.56 16.1 5.31 46 NR 0.68 MW-2 20.63 983.85 1004.48 14.8 5.89 198 NR 0.75 MW-3 25.34 999.39 1024.73 NR NR NR NR NR MW-4R 14.73 997.91 1012.64 17.3 6.22 475 NR 22.0 MW-5 38.80 1012.46 1051.26 16.1 6.24 413 NR 11.6 MW-6 27.84 982.95 1010.79 15.7 5.95 203 NR 0.35 MW-7 36.72 972.52 1009.24 NR NR NR NR NR MW-9 11.15 985.12 996.27 16.7 6.40 618 NR 15.1 MW-10 36.22 1004.58 1040.80 16.1 7.14 541 NR 23.6 MW-11 39.61 972.35 1011.96 17.3 5.44 784 NR 35.8 MW-12 48.73 958.62 1007.35 18.2 5.87 373 NR 67.0 MW-12D 57.33 951.13 1008.46 16.3 6.05 911 NR 55.1 MW-13 36.70 967.86 1004.56 15.0 5.98 158 NR 4.37 MW-14 37.20 960.24 997.44 16.3 5.90 94 NR 8.76 MW-15 22.97 1000.47 1023.44 14.8 6.10 147 NR 10.2 MW-16 29.01 1008.55 1037.56 15.1 5.67 153 NR 7.75 MW-17 15.15 976.01 991.16 14.1 5.07 73 NR 0.16 MW-18 44.89 1039.44 1084.33 15.7 5.64 16 NR 0.53 MW-19 47.33 1024.15 1071.48 15.3 6.86 348 NR 11.5 MW-20 38.45 1008.47 1046.92 15.5 5.64 46 NR 1.33 MW-21 25.85 964.15 990.00 14.3 5.43 53 NR 0.52 MW-22 14.73 944.24 958.97 13.9 5.72 40 NR 7.63 MW-23 16.53 933.95 950.48 13.6 5.25 49 NR 2.53 MW-24 28.40 945.64 974.04 16.2 6.21 55 NR 1.51 MW-25 24.20 957.73 981.93 15.1 6.15 67 NR 1.36 MW-26 22.23 968.46 990.69 16.4 6.79 605 NR 65.1 MW-27 18.53 973.66 992.19 16.7 6.95 511 NR 1.67 MW-31 17.89 967.53 985.42 15.4 6.56 151 NR 0.33 MW-32 31.35 993.91 1025.256 15.2 6.02 50 NR 9.16 MW-33 12.87 994.53 1007.40 14.1 5.08 41 NR 0.54 MW-34 8.13 1006.47 1014.60 14.4 5.75 387 NR 1.13 IW-1 19.63 970.81 990.44 NR NR NR NR NR Minimum 8.13 933.95 950.48 13.6 5.07 16 NR 0.16 Average 28.45 985.47 1013.92 15.6 5.98 265 NR 13.0 Maximum 57.33 1047.60 1084.33 18.2 7.14 911 NR 67.0 SW-3 - - - 20.3 7.44 56 60 3.05 SW-4R - - - 18.5 7.32 79 40 6.19 SW-5 - - - 20.5 7.15 64 40 3.20 SW-6 - - - 19.5 7.09 39 20 7.32 Minimum - - - 18.5 7.09 39 20 3.05 Average - - - 19.7 7.25 60 40 4.94 Maximum - - - 20.5 7.44 79 60 7.32 NR = No Reading Attempted Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 4 Sampling and Analysis Summary July 15-17, 2020 App. I Other App II MNA Parameters Field Parameters 0 w C y ;V .T+ (6 c 2 7 (6 C U a 0_ 7 ;' N :E C lC N w N � '6 O U 0 LL N N E '2 7 'p UU U >O H Q fA In U m Z H 2 U a H 0 0 0 o U) W m 0 o 0 � o L0 U m N N O O Q N 00 Q N N O V 00 O u07 m m LWL a W a_ w O Cl 2 o 2 O O N o o Lo 2 Y 2 2 � -0 -0 Y Q ch Lo LO M s v a a o Method J Co J J J J W J co U U !n J LL LL LL LL LL MW-1 x x x x x x x x MW-1A Not sampled since dry which is typical of this well MW-1 B x x x x x x x x x MW-2 x x x x x x x MW-3 MW-4R x x x x x x x MW-5 x x x x x x x x x x x x x x x MW-6 x x x x x x x x x x x x x x x MW-7 MW-9 x x x x x x x MW-10 x x x x x x x MW-11 x x x x x x x x x x x x x x x MW-12 x x x x x x x x x x x x x x x MW-12D x x x x x x x x x x x x x x x MW-13 x x x x x x x MW-14 x x x x x x x MW-15 x x x x x x x x MW-16 x x x x x x x x x x x x x x x MW-17 x x x x x x x MW-18 x x x x x x x MW-19 x x x x x x x MW-20 x x x x x x x MW-21 x x x x x x x MW-22 x x x x x x x MW-23 x x x x x x x MW-24 x x x x x x x x x x x x x x x MW-25 x x x x x x x x x x x x x x x MW-26 x x x x x x x x x x x x x x x MW-27 x x x x x x x x x x x x x x x MW-31 x x x x x x x x x x x x x x x MW-32 x x x x x x x MW-33 x x x x x x x MW-34 x x x x x x x SW-3 x x x x x x x x SW-4R x x x x x x x x SW-5 x x x x x x x x SW-6 x x x x x x x x EB x x x FB XT x App I & II = Appendix I & II constituents listed in current 40 CFR 258 Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 5 Groundwater and Quality Control Sample Detections July 15-17, 2020 21LSTANDARD MW-18 MW-1 MW-16 MW-2 MW-4R MW-5 MW-6 MW-9 MW-10 MW-11 MW-12 MW-12D MW-13 MW-14 I MW-15 MW-16 I MW-17 MW-19 MW-20 MW-21 I MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-31 MW-32 MW-33 MW-34 EB FIBParameter Name MDL RL IMAC VALUE MCL BG I S S S S S S S S S S S S S I S S I S I S I S S S S S S S S S S S S QC QC Metals (Target d 40CFR 258 Appendix I & Mercu Antimony, total 3 5 1 6 3.5 J Arsenic, total 4.7 10 10 10 7.3 J 5.5 J Barium, total 3.5 5 700 2000 5.9 26.4 47.8 45.6 119 117 24.8 217 5.2 172 122 12.4 14 136 74.7 52.4 62.2 20.9 47.1 21.5 57.7 26.8 53.7 50.8 81.2 52.6 108 5.7 17.6 18.4 - Cadmium, total 0.4 1 2 5 1.3 2 2 0.54 J 0.62 J 1.2 2 2.7 (N) 3.3 (N) 1.4 3.5 (N) 0.41 J 0.53 J 0.54 J 2.1 (N) 0.45 J 0.63 J 0.76 J 5.6 (N) 1.6 -- Chromium, total 3.7 5 10 100 157 (N) 12.4 (N) Cobalt, total 3.6 5 1 NE 8.7 (N) 53.9 (N) 677 (N) 104 (N) 8.6 (N) 356 (N) 123 (N) 56.8 (N) 4.7 J 272 (N) 15 (N) 4.2 J 64.9 (N) 8.1 (N) Copper, total 4.3 5 1000 1300 4.7 J 5.2 4.8 J 7.5 4.6 J 5.1 62.9 7.7 5.1 Lead, total 4.5 5 1 15 15 38.8 (N) Mercury, total 0.12 0.2 1 2 - -- 2.3 (N) -- 2.6 (N) -- -- Nickel, total 3.5 5 100 NE 3.6 J 5.3 12.7 5.8 55.8 13.1 9.1 7.1 42.1 15 10.1 4.1 J 5.9 10.1 3.9 J 4.6 J Selenium, total 4.7 10 20 50 6.6 J 5.3 J Thallium, total 0.05 0.1 0.28 2 0.054 J 0.088 J 0.3 (N) 0.22 0.16 0.15 0.066 J 0.08 J 0.076 J 0.051 J 0.072 J 0.1 0.058 J Vanadium, total 3.9 5 0.3 NE 304 (N) 59 (N) Zinc, total 9.5 10 1000 NE 21.6 15.7 13 25.4 67.6 791 60.1 11.1 VOCs (Targeted 40CFR 258 Appendix I 1,1-Dichloroethane 0.27 1 6 NE 0.7 J 2.4 0.37 J 0.49 J 1.3 1,2-Dichlorobenzene 0.29 1 20 NE 0.45 J 1,4-Dichlorobenzene 0.26 1 6 75 1.7 1.1 0.69 J 2.1 1.9 2.4 6.5 (L) 1.9 1.1 0.45 J 0.82 J 2 Acetone 6.2 25 6000 NE 11.4 J 12.6 J Benzene 0.15 1 1 5 0.37 J 0.54 J 0.8 J 2.2 (L) 1.1 (L) 0.96 J 2.6 (L) 1.4 (L) 3.1 (L) 0.32 J 0.46 J Chlorobenzene 0.23 1 50 100 0.28 J 0.85 J 0.55 J 1.3 1.7 0.79 J 0.24 J 0.45 J Chloroethane 0.49 1 3000 NE 0.65 J 0.78 J 0.76 J cis-1,2-Dichloroethene 0.29 1 70 70 0.58 J 1 6.2 11.7 11.6 3.2 11.2 1 5.4 1.1 7.9 2.4 1.5 0.3 J 2.9 20.2 2 Tetrachloroethene 0.16 1 67 5 0.57 J Toluene 0.24 1 600 1000 0.28 J Trichloroethene 0.22 1 3 5 1 1.2 MINA Performance Parameters Alkalinity 5000 5000 NE NE 144000 282000 95500 450000 9580 10000 113000a 200 Chloride 500 1000 250000 NE 4310 3290 104000 32800 81100 12500 21800 2730 29400 90000D 125000 250000 NE NE 26200 66500 26900 29200 23900 J700 JIron, ferrous 840 5000 NE NE -- -- -- -- -- 16800 -- -- 31800 3600 390 J -- -- -- 2500 -- -- -- -- -- -- 1300-- ethane 3.4 10 NE NE 510 Nitrate as N 10 40 NE NE -- -- -- -- -- 457 -- -- 73.1 177 -- -- -- -- -- -- -- -- -- 194 816 60 -- Sulfate 500 1000 250000 NE 735J 1300 2590 4190 4770 160 55030 4720 43J Sulfide 50 100 NE NE -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 70.7 J-- TOC 500 1000 NE NE 1830 808 J 7250 4030 4030 1410 849 J 810 J 3710 520 - Notes: Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established. Bold Above RL and Established 21JIMAC/ recognized by NC SWS as regulatory groundwater Standard Highlighted Above Established MCL Drinking Water Std. (No regulatory significance) BG = Background Well Sample, S = Sentinel Well Sample MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J' qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration MCL = Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism. A definitive source of the detections was not determined as part of this report. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 6 Surface Water Sample Detections July 16, 2020 Parameter Name MDL NC 2B STD1 EPA NRWQCZ NC ISTV3 a MC' SW-3 SW-4111 I SW-5 I SW-6 Downstream I Downstream Downstream Downstream Targeted 40CFR 258 Appendix I & 1,4-Dioxane Barium, total 3.5 NE NE 21,000 2000 26.9 40.1 22.8 17.3 Cadmium, total 0.4 1.76 NE NE 5 0.46 J 1.3 1.23 2.2 0.67 1.3 Copper, total 4.3 5.67 NE NE 1300 5.8 Thallium, total 0.05 NE 0.47 NE 0.28 0.095 J Vanadium, total 3.9 NE NE NE NE 12.2 Zinc, total 9.5 53.91 NE NE NE 16.9 Hardness as CaCo3 (Field Measured) Hardness m /L 20 NE NE NE NE F 60 1 40 40 20 Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". Red Bold Above 2B Std. Above Established Federal MCL Primary Drinking Water Std. Receiving surface water is Catawba River (11-(67)) Class WS-IV 03040102 (8-Digit HUC). NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes. 2B Standards from All Waters (C & SC) or Class C. 2B Standard for cadmium, coDDer and zinc from calculations for acute exposure based on measured hardness values. Cadmium 2B Standard calculation:WER*[(1.136672-[In hardness](0.041838))*eA(0.9151[In hardness]-3.1485)] Copper 2B Standard calculation:WER*[0.960*eA(0.9422[ln hardness]-1.700)] Zinc 2B Standard calculation:WER*[0.986*eA{0.8473[ln hardness]+0.884)] 2 EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses 3 NC ISTV= North Carolina In -Stream Target Value. Established per language in 15A NCAC 02B .0202 & .0208. Contact DWR staff for further information. NC PV for barium fresh water All waters (Class C), for cobalt & 1,4-Dioxane All waters Fresh & Salt (Class C & SC) ° MCL= Maximum Contaminant Level. Federal Primary "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 7 Hydrogeologic Proporties at Monitoring Well Locations July 14-17, 2020 Monitoring Well Hydraulic Conductivity (cm/sec) Effective Porosity N Hydraulic Gradient (ft/ft) Average Linear Velocity Rate (ft/yr) Flow Direction Depth to Groundwater (ft BTOC) Groundwater Potentiometric Elevation (ft amsl) Screened Interval Lithology MW-2 3.70E-06 28 0.67 9 S54E 20.63 983.85 UC MW-12 n/a 28 0.04 n/a N81 W 48.73 958.62 UC MW-16 8.72E-04 17 0.06 303 S27E 29.01 1008.55 UC MW-17 n/a 17 0.24 n/a S49E 15.15 976.01 UC MW-21 3.77E-03 28 0.26 3666 S31 E 25.85 964.15 UC MW-22 6.04E-04 28 0.18 399 S55E 14.73 944.24 UC MW-23 9.83E-04 28 0.22 793 S33E 16.53 933.95 UC MW-24 1.33E-02 28 0.09 4636 N72W 28.40 945.64 UC MW-31 n/a 28 0.09 n/a S85W 17.89 967.53 UC MW-33 n/a 28 0.06 n/a S31 E 12.87 994.53 UC MW-34 n/a 28 0.02 n/a S57E 8.13 1006.47 UC Minimum 3.70E-06 17 0.02 9 - 8.13 933.95 - Average 3.26E-03 26 0.17 1634 - 21.63 971.23 - Maximum 1.33E-02 28 0.67 4636 - 48.73 1008.55 - MW-1 5.60E-05 10 0.13 75 N38W 32.94 1047.60 UC/UBR MW-3 3.90E-06 10 0.16 7 S16W 25.34 999.39 UC/UBR MW-4R 4.90E-04 10 0.09 441 S28W 14.73 997.91 UC/UBR MW-5 6.40E-05 28 0.06 15 S40E 38.80 1012.46 UC/UBR MW-14 n/a 10 0.43 n/a S48E 37.20 960.24 UC/UBR MW-15 n/a 10 0.03 n/a S44E 22.97 1000.47 UC/UBR Minimum 3.90E-06 10 0.03 7 - 14.73 960.24 - Average 1.53E-04 13 0.15 134 - 28.66 1003.01 - Maximum 4.90E-04 28 0.43 441 - 38.80 1047.60 - MW-1 B n/a 10 0.08 n/a N35W 36.66 1045.90 UBR MW-6 2.40E-05 10 0.11 28 N86W 26.27 982.95 UBR MW-7 1.60E-06 10 0.17 3 S13W 36.72 972.52 UBR MW-9 n/a 10 0.07 n/a S51 E 11.15 985.12 UBR MW-11 n/a 10 0.10 n/a S35W 39.61 972.35 UBR MW-13 n/a 10 0.21 n/a S85W 36.70 967.86 UBR MW-19 1.92E-06 10 0.09 2 S54E 47.33 1024.15 UBR MW-20 5.49E-05 10 0.06 36 S47W 38.45 1008.47 UBR MW-25 5.41 E-05 10 0.04 22 S67W 24.20 957.73 UBR MW-26 1.16E-04 10 0.10 126 S70W 22.23 968.46 UBR MW-27 2.83E-05 10 0.08 22 S05W 18.53 973.66 UBR MW-32 n/a 10 0.07 n/a S09E 31.35 993.91 UBR Minimum 1.60E-06 10 0.04 2 - 11.15 957.73 - Average 4.01 E-05 10 0.10 34 - 30.77 987.76 - Maximum 1.16E-04 10 0.21 126 - 47.33 1045.90 - MW-10 n/a 10 0.04 n/a S18E 36.22 1004.58 LBR MW-12D n/a 10 n/a n/a n/a 57.33 951.13 LBR MW-18 1.19E-04 10 0.06 n/a N10W 44.89 1039.44 LBR Minimum 1.19E-04 10 0.04 - - 36.22 951.13 - Average 1.19E-04 10 0.05 - - 46.15 998.38 - Maximum 1.19E-04 10 0.06 - - 57.33 1039.44 - NOTE: Values for hydraulic conductivity obtained from GAI Consultants Sampling Report (April, 1995) & MESCO ACM Report (2008). Average Linear Groundwater Velocities calculated only for UC & UBR wells with hydraulic conductivity values. UC = Unconfined/saprolite; UBR = Upper Bedrock fracture system; LBR = Lower Bedrock fracture system. Wells screened in LBR not utilized for flow directions/gradients. Hydrologic Gradient calculated from potentiometrc elevations recorded on July 14-17, 2020. Flow rate (Q) calculated via modified Darcy's equation: K= hydraulic conductivity - _ ri A n a = effective porosity fZg dh= head difference d1= horizontal distance Alexander County Active C&D and Closed MSWLF Page 1 of 1 Appendix A Field Sampling Parameter Data Sheet(s) OTIamu"sA Project: Alexander Co Closed MSWLF & Active C&D LF Samplers: Page _1_of 2 E. Lambert Sampling Parameters Water Quality Parameters Depth to Depth to Water Specific p CH4 MonitoringPure Pure Water Sample Sample (BTOP) Volume Sample Total CO2 DO OR Temp. Cond. TDSmc Gas Point Date Time BTOP ( ) Date Time Sam le Purged Type Comments Depth (m9/I) (mg/L) P pH (mg/L) Vapors Pre -Purge (Gal) Yp LDuring Expected (us/cm I— (ppm) Time 71 . . F 40 MW-1 , elk 48,5 MW-1 B = r i 61 — `_. 1 1 v 30 �. — MW-2,,j -- MW-3 NS NS Z, '� NS NS NS - - _ - `/ %6 MW-4R / u i rE49. _ ' MW-5 7 j MVG�-6 MW-7 NS NS� NS NS NS 31.5 U 711; ( = MW-9 1 , , _91 — — MW-10 P 56 MW-11% - MW-12 f�rf 66.5 I u �� 102.5 r MW-121D z 1 131 — — _ . 7/1 60.5 MW-13 J 40.5 7 MW-14;'j% __ _ 35 iG -Y MW-15 �_/' 40.25 MW-16 / { , 15 - r. 1, 22.3 ' MW-17 : � .€, - MW-18 , , � . t .; 56.7 < Li7r f Mf F'x t 63.92 1 o MW-19 C _ Comments SS B=Stainless Steel Baler, D B=Disposable, Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Sampling D�xa Sheet —..,.,—�,�r� �� `..��..'� f�=-� ,....,.r... ...�... Project: Alexander Co Closed MSWLF &Active C&D LF Samplers: Page_2_of_2 E. Lambert Sampling Parameters Water Quality Parameters Depth to Monitoring Purge Purge Depth to Water Sample Sample Water Volume Goes Total DO OR Temp. Specific Hard- :o CH4 ' Gas Point Date Time (BTOP) Date Time (BTOP) Purged Sample 'Type Dry Comments Depth CO2 P pH © Cond. Hess � Va ors pm Pre -Purge Sample (Gal) During Expected (mg/i) (mg/L) (us/cm (mg/L) � Time Purge (pP ) MW-20 j.f �. ' t � ? �, -- j � � ' �� °� 63.55 ;'� '-; , �'`_' 3 � � �°� 41.05 "� a MW-21 { � � t` � �' e ✓ � � a ��.�� ` ' (u'`_�. i � ,� ,� .� L � ____�� �� 18.12 ,. � MW-22 �., � � � z ` r^ - MW-23 t ` � �e '� - - �~ r'`,i 21.54 � c �� MW-24 ��'� � if (- � `9 _ � -' , ' I 35.35 � � � i ,f � ' 44.48 � —_ `� MW-25 � �f;. ' ,� � ���,� �'' W-26 �� ; � �� � � � � � ' � 49.8 ��� � � , � � � 9. M :a � �. � �- 1� MW-27 ,��� �,��,�..� 1 � V' � % `_ 49.82 �� �- � � f, r',/j �� � � ' �� � ` ' 32.56 f �- r MW-31 � , ; � MW-32 � ;� � , r- � ��r l e �� �� �`��, 21.38 �� ;�- MW-33 (mot � % C' ,` MW-34 i (, ,{ , �� I .� rc� 21.19 _ � - �+ u ,- _ 4> G�' `— , SW-4R - - - - - _ n F. _. % ,�, — .-_ �. EB - - - ���` i ' � ,_ - - - - - - - - - - - - - - FB - - - i1' -- - - - - - _ - - - - - - o .. _fit:;;.,.. - _ i � ; �� _._._ ____ - - - - — - - - - - - - - - - Comments SS B=Stainless Steel Baler, D B-Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample obtained Appendix B Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 30, 2020 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Alexander LF - SWS Pace Project No.: 92486765 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on July 17, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF - SWS Pace Project No.: 92486765 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Alexander LF - SWS Pace Project No.: 92486765 Lab ID Sample ID Matrix Date Collected Date Received 92486765001 MW-6 Water 07/15/20 13:25 07/17/20 06:17 92486765002 MW-6 NITRATE Water 07/16/20 11:06 07/17/20 06:17 92486765003 MW-16 Water 07/16/20 08:58 07/17/20 06:17 92486765004 MW-26 Water 07/16/20 13:14 07/17/20 06:17 92486765005 MW-27 Water 07/16/20 10:09 07/17/20 06:17 92486765006 MW-31 Water 07/16/20 13:24 07/17/20 06:17 92486765007 MW-5 Water 07/16/20 08:28 07/17/20 06:17 92486765008 MW-10 Water 07/16/20 09:15 07/17/20 06:17 92486765009 MW-13 Water 07/15/20 13:20 07/17/20 06:17 92486765010 MW-14 Water 07/15/20 13:50 07/17/20 06:17 92486765011 MW-15 Water 07/15/20 12:41 07/17/20 06:17 92486765012 MW-17 Water 07/15/20 12:35 07/17/20 06:17 92486765013 MW-18 Water 07/15/20 16:04 07/17/20 06:17 92486765014 MW-19 Water 07/15/20 15:45 07/17/20 06:17 92486765015 MW-20 Water 07/15/20 13:11 07/17/20 06:17 92486765016 MW-21 Water 07/15/20 12:30 07/17/20 06:17 92486765017 MW-22 Water 07/15/20 12:50 07/17/20 06:17 92486765018 MW-23 Water 07/15/20 12:55 07/17/20 06:17 92486765019 MW-32 Water 07/15/20 09:21 07/17/20 06:17 92486765020 MW-33 Water 07/15/20 09:10 07/17/20 06:17 92486765021 MW-34 Water 07/15/20 08:45 07/17/20 06:17 92486765022 SW-3 Water 07/16/20 09:58 07/17/20 06:17 92486765023 SW-4R Water 07/16/20 13:08 07/17/20 06:17 92486765024 SW-5 Water 07/16/20 09:35 07/17/20 06:17 92486765025 SW-6 Water 07/16/20 08:53 07/17/20 06:17 92486765026 MW-1 Water 07/15/20 15:33 07/17/20 06:17 92486765027 MW-1 B Water 07/15/20 15:53 07/17/20 06:17 92486765028 MW-2 Water 07/15/20 13:43 07/17/20 06:17 92486765029 MW-4R Water 07/16/20 09:44 07/17/20 06:17 92486765030 MW-9 Water 07/16/20 09:50 07/17/20 06:17 92486704001 MW-11 Water 07/17/20 08:12 07/17/20 12:16 92486704002 MW-12D Water 07/17/20 08:27 07/17/20 12:16 92486704003 MW-24 Water 07/17/20 08:48 07/17/20 12:16 92486704004 MW-25 Water 07/17/20 08:40 07/17/20 12:16 92486704005 MW-12 Water 07/17/20 08:20 07/17/20 12:16 92486704006 EB Water 07/17/20 09:18 07/17/20 12:16 92486704007 FB Water 07/17/20 09:23 07/17/20 12:16 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF - SWS 92486765 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92486765001 MW-6 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D SAS 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765002 MW-6 NITRATE EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A 92486765003 MW-16 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765004 MW-26 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765005 MW-27 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF - SWS Pace Project No.: 92486765 Lab ID Sample ID Method Analysts Analytes Reported Laboratory SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765006 MW-31 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765007 MW-5 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486765008 MW-10 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765009 MW-13 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D SAS 51 PASI-C 92486765010 MW-14 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF - SWS 92486765 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D SAS 51 PASI-C 92486765011 MW-15 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92486765012 MW-17 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765013 MW-18 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765014 MW-19 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765015 MW-20 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765016 MW-21 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765017 MW-22 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765018 MW-23 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765019 MW-32 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765020 MW-33 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765021 MW-34 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765022 SW-3 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF - SWS Pace Project No.: 92486765 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D CL 51 PASI-C 92486765023 SW-4R EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765024 SW-5 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765025 SW-6 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765026 MW-1 RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765027 MW-1B RSK 175 Modified MAD 1 PASI-C EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 7470A SOO 1 PASI-A EPA 8260D CL 51 PASI-C 92486765028 MW-2 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765029 MW-4R EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486765030 MW-9 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92486704001 MW-11 EPA 601 OD RDT 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF - SWS 92486765 Analytes Lab ID Sample ID Method Analysts Reported Laboratory SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486704002 MW-12D EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486704003 MW-24 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486704004 MW-25 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486704005 MW-12 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF - SWS Pace Project No.: 92486765 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 8260D GAW 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 NAL 1 PASI-A SM 4500-S2D-2011 LMS1 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 CJH1 1 PASI-A SM 4500-CI-E-2011 MDW 1 PASI-A SM 5220D-2011 LMS1 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92486704006 EB EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 51 PASI-C 92486704007 FB EPA 8260D CL 51 PASI-C PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-6 Lab ID: 92486765001 Collected: 07/15/20 13:25 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:48 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:48 7440-38-2 Barium 24.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:48 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:48 7440-41-7 Cadmium 1.2 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:48 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:48 7440-47-3 Cobalt 8.6 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:48 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:48 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:48 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:48 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:48 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:48 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:48 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:48 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:30 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 09:11 67-64-1 v1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 09:11 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 09:11 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 09:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 09:11 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 09:11 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 09:11 74-83-9 IK,v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 09:11 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 09:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 09:11 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 09:11 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 09:11 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 09:11 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 09:11 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 09:11 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 09:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 09:11 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 09:11 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 09:11 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 09:11 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 09:11 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 09:11 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 09:11 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 09:11 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-6 Lab ID: 92486765001 Collected: 07/15/20 13:25 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 09:11 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 09:11 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 09:11 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 09:11 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 09:11 10061-02-6 ND ug/L 150 56.2 1 07/24/20 09:11 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 09:11 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 09:11 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 09:11 74-88-4 ND ug/L 5.0 3.7 1 07/24/20 09:11 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 09:11 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 09:11 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 09:11 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 09:11 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 09:11 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 09:11 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 09:11 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 09:11 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 09:11 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 09:11 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 09:11 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 09:11 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 09:11 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 09:11 1330-20-7 105 % 70-130 1 07/24/20 09:11 460-00-4 102 % 70-130 1 07/24/20 09:11 17060-07-0 103 % 70-130 1 07/24/20 09:11 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville ND ug/L 5000 5000 1 07/22/2016:38 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 07/21/2015:06 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:09 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 1300 ug/L 1000 500 1 07/22/20 08:28 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 H3,N2 Page 11 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-6 Lab ID: 92486765001 Collected: 07/15/20 13:25 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 3290 ug/L 1000 500 1 07/27/2019:59 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:37 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 808J ug/L 1000 500 1 07/24/20 08:25 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-6 NITRATE Lab ID: 92486765002 Collected: 07/16/20 11:06 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 457 ug/L 40.0 10.0 1 07/18/20 01:20 14797-55-8 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-16 Lab ID: 92486765003 Collected: 07/16/20 08:58 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:51 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:51 7440-38-2 Barium 52.4 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:51 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:51 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:51 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:51 7440-47-3 Cobalt 272 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:51 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:51 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:51 7439-92-1 Nickel 10.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:51 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:51 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:51 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:51 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:51 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.076J ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:38 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 12.6J ug/L 25.0 6.2 1 07/25/20 13:14 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 13:14 107-13-1 Benzene 0.32J ug/L 1.0 0.15 1 07/25/20 13:14 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 13:14 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 13:14 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 13:14 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 13:14 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 13:14 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 13:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 13:14 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 13:14 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 13:14 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 13:14 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 13:14 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 13:14 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 13:14 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 13:14 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 13:14 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 13:14 95-50-1 1,4-Dichlorobenzene 0.45J ug/L 1.0 0.26 1 07/25/20 13:14 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 13:14 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 13:14 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 13:14 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 13:14 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. L1 IK,v1 v3 M1 M1 Page 14 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-16 Lab ID: 92486765003 Collected: 07/16/20 08:58 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.4 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 150 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 0.29 1 07/25/20 13:14 156-59-2 0.25 1 07/25/20 13:14 156-60-5 0.19 1 07/25/20 13:14 78-87-5 0.30 1 07/25/20 13:14 10061-01-5 0.31 1 07/25/20 13:14 10061-02-6 56.2 1 07/25/20 13:14 123-91-1 0.26 1 07/25/20 13:14 100-41-4 0.57 1 07/25/20 13:14 591-78-6 12.5 1 07/25/20 13:14 74-88-4 3.7 1 07/25/20 13:14 75-09-2 4.5 1 07/25/20 13:14 108-10-1 0.27 1 07/25/20 13:14 100-42-5 0.34 1 07/25/20 13:14 630-20-6 0.22 1 07/25/20 13:14 79-34-5 0.16 1 07/25/20 13:14 127-18-4 0.24 1 07/25/20 13:14 108-88-3 0.18 1 07/25/20 13:14 71-55-6 0.24 1 07/25/20 13:14 79-00-5 0.22 1 07/25/20 13:14 79-01-6 0.31 1 07/25/20 13:14 75-69-4 0.35 1 07/25/20 13:14 96-18-4 1.4 1 07/25/20 13:14 108-05-4 0.24 1 07/25/20 13:14 75-01-4 0.63 1 07/25/20 13:14 1330-20-7 97 % 70-130 105 % 70-130 100 % 70-130 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville ND ug/L 5000 5000 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 2.5 mg/L 0.50 0.084 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 4770 ug/L 1000 500 I 1 0 I 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/25/20 13:14 460-00-4 07/25/20 13:14 17060-07-0 07/25/20 13:14 2037-26-5 5erlf��af��e1IVAE! 07/21 /20 15:09 M1 M1 M1 M1 M1 M1 M1 MS H3,N2 07/22/20 22:29 18496-25-8 M 1 07/22/20 08:42 14808-79-8 Page 15 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-16 Parameters Lab ID: 92486765003 Collected: Report Results Units Limit 07/16/20 08:58 MDL DF Received: 07/17/20 06:17 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 07/18/20 01:17 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 12500 ug/L 1000 500 1 07/27/20 20:00 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:37 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1410 ug/L 1000 500 1 07/24/20 08:43 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-26 Lab ID: 92486765004 Collected: 07/16/20 13:14 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:54 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:54 7440-38-2 Barium 81.2 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:54 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:54 7440-41-7 Cadmium 2.1 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:54 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:54 7440-47-3 Cobalt 64.9 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:54 7440-48-4 Copper 5.1 ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:54 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:54 7439-92-1 Nickel 10.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:54 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:54 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:54 7440-62-2 Zinc 11.1 ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.10 ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:45 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 08:21 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 08:21 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 08:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 08:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 08:21 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 08:21 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 08:21 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 08:21 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 08:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 08:21 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 08:21 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 08:21 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 08:21 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 08:21 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 08:21 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 08:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 08:21 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 08:21 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 08:21 95-50-1 1,4-Dichlorobenzene 0.82J ug/L 1.0 0.26 1 07/25/20 08:21 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 08:21 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 08:21 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 08:21 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 08:21 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 17 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-26 Lab ID: 92486765004 Collected: 07/16/20 13:14 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.9 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 150 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 0.29 1 07/25/20 08:21 156-59-2 0.25 1 07/25/20 08:21 156-60-5 0.19 1 07/25/20 08:21 78-87-5 0.30 1 07/25/20 08:21 10061-01-5 0.31 1 07/25/20 08:21 10061-02-6 56.2 1 07/25/20 08:21 123-91-1 0.26 1 07/25/20 08:21 100-41-4 0.57 1 07/25/20 08:21 591-78-6 12.5 1 07/25/20 08:21 74-88-4 3.7 1 07/25/20 08:21 75-09-2 4.5 1 07/25/20 08:21 108-10-1 0.27 1 07/25/20 08:21 100-42-5 0.34 1 07/25/20 08:21 630-20-6 0.22 1 07/25/20 08:21 79-34-5 0.16 1 07/25/20 08:21 127-18-4 0.24 1 07/25/20 08:21 108-88-3 0.18 1 07/25/20 08:21 71-55-6 0.24 1 07/25/20 08:21 79-00-5 0.22 1 07/25/20 08:21 79-01-6 0.31 1 07/25/20 08:21 75-69-4 0.35 1 07/25/20 08:21 96-18-4 1.4 1 07/25/20 08:21 108-05-4 0.24 1 07/25/20 08:21 75-01-4 0.63 1 07/25/20 08:21 1330-20-7 105 % 70-130 94 % 70-130 104 % 70-130 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 113000 ug/L 5000 5000 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 1.3 mg/L 0.50 0.084 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville 70.7J ug/L 100 50.0 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 4720 ug/L 1000 500 I 1 0 I 0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 07/25/20 08:21 460-00-4 07/25/20 08:21 17060-07-0 07/25/20 08:21 2037-26-5 ;lr,0�apkilE 07/21 /20 15:11 H3, N2 07/22/20 22:30 18496-25-8 M 1 07/22/20 09:52 14808-79-8 Page 18 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-26 Parameters Lab ID: 92486765004 Collected: Report Results Units Limit 07/16/20 13:14 MDL DF Received: 07/17/20 06:17 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 07/18/20 01:21 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 29400 ug/L 1000 500 1 07/27/20 20:01 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 23900J ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:38 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 3710 ug/L 1000 500 1 07/24/20 09:03 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-27 Lab ID: 92486765005 Collected: 07/16/20 10:09 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:57 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:57 7440-38-2 Barium 52.6 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:57 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:57 7440-41-7 Cadmium 0.45J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:57 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:57 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:57 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:57 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:57 7439-92-1 Nickel 3.9J ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:57 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:57 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:57 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:57 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:53 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 13:32 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 13:32 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 13:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 13:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 13:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 13:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 13:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 13:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 13:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 13:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 13:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 13:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 13:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 13:32 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 13:32 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 13:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 13:32 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 13:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 13:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 13:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 13:32 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 13:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 13:32 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 13:32 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. L1 IK,v1 Page 20 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-27 Lab ID: 92486765005 Collected: 07/16/20 10:09 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 20.2 ug/L 1.0 0.29 1 07/25/2013:32 156-59-2 ND ug/L 1.0 0.25 1 07/25/2013:32 156-60-5 ND ug/L 1.0 0.19 1 07/25/2013:32 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 13:32 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2013:32 10061-02-6 ND ug/L 150 56.2 1 07/25/2013:32 123-91-1 ND ug/L 1.0 0.26 1 07/25/2013:32 100-41-4 ND ug/L 5.0 0.57 1 07/25/2013:32 591-78-6 ND ug/L 20.0 12.5 1 07/25/2013:32 74-88-4 ND ug/L 5.0 3.7 1 07/25/2013:32 75-09-2 ND ug/L 5.0 4.5 1 07/25/2013:32 108-10-1 ND ug/L 1.0 0.27 1 07/25/2013:32 100-42-5 ND ug/L 1.0 0.34 1 07/25/2013:32 630-20-6 ND ug/L 1.0 0.22 1 07/25/2013:32 79-34-5 ND ug/L 1.0 0.16 1 07/25/2013:32 127-18-4 ND ug/L 1.0 0.24 1 07/25/2013:32 108-88-3 ND ug/L 1.0 0.18 1 07/25/2013:32 71-55-6 ND ug/L 1.0 0.24 1 07/25/2013:32 79-00-5 ND ug/L 1.0 0.22 1 07/25/2013:32 79-01-6 ND ug/L 1.0 0.31 1 07/25/2013:32 75-69-4 ND ug/L 1.0 0.35 1 07/25/2013:32 96-18-4 ND ug/L 2.0 1.4 1 07/25/2013:32 108-05-4 ND ug/L 1.0 0.24 1 07/25/2013:32 75-01-4 ND ug/L 1.0 0.63 1 07/25/2013:32 1330-20-7 98 % 70-130 1 07/25/2013:32 460-00-4 106 % 70-130 1 07/25/2013:32 17060-07-0 101 % 70-130 1 07/25/2013:32 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 46600 ug/L 5000 5000 1 07/23/2015:18 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 07/21/2015:14 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:31 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 3880 ug/L 1000 500 1 07/22/2010:06 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-27 Parameters Lab ID: 92486765005 Collected: Report Results Units Limit 07/16/20 10:09 MDL DF Received: 07/17/20 06:17 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 204 ug/L 40.0 10.0 1 07/18/20 01:18 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 29500 ug/L 1000 500 1 07/27/20 20:10 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:38 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1650 ug/L 1000 500 1 07/24/20 09:20 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-31 Lab ID: 92486765006 Collected: 07/16/20 13:24 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:13 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:13 7440-38-2 Barium 108 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:13 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:13 7440-41-7 Cadmium 0.63J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:13 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:13 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:13 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:13 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:13 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:13 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:13 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:13 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.058J ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:00 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 08:40 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 08:40 107-13-1 Benzene 0.46J ug/L 1.0 0.15 1 07/25/20 08:40 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 08:40 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 08:40 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 08:40 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 08:40 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 08:40 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 08:40 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 08:40 56-23-5 Chlorobenzene 0.45J ug/L 1.0 0.23 1 07/25/20 08:40 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 08:40 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 08:40 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 08:40 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 08:40 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 08:40 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 08:40 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 08:40 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 08:40 95-50-1 1,4-Dichlorobenzene 2.0 ug/L 1.0 0.26 1 07/25/20 08:40 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 08:40 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 08:40 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 08:40 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 08:40 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 23 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-31 Lab ID: 92486765006 Collected: 07/16/20 13:24 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 2.0 ug/L 1.0 0.29 1 07/25/20 08:40 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 08:40 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 08:40 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 08:40 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 08:40 10061-02-6 ND ug/L 150 56.2 1 07/25/20 08:40 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 08:40 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 08:40 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 08:40 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 08:40 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 08:40 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 08:40 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 08:40 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 08:40 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 08:40 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 08:40 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 08:40 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 08:40 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 08:40 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 08:40 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 08:40 96-18-4 ND ug/L 2.0 1.4 1 07/25/20 08:40 108-05-4 ND ug/L 1.0 0.24 1 07/25/20 08:40 75-01-4 ND ug/L 1.0 0.63 1 07/25/20 08:40 1330-20-7 105 % 70-130 1 07/25/20 08:40 460-00-4 91 % 70-130 1 07/25/20 08:40 17060-07-0 105 % 70-130 1 07/25/20 08:40 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 39200 ug/L 5000 5000 1 07/23/2015:29 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 07/21/2015:16 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:31 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 843J ug/L 1000 500 1 07/22/2010:20 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-31 Parameters Lab ID: 92486765006 Collected: Report Results Units Limit 07/16/20 13:24 MDL DF Received: 07/17/20 06:17 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 460 ug/L 40.0 10.0 1 07/18/20 01:22 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 22900 ug/L 1000 500 1 07/27/20 20:11 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 14700J ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:38 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1520 ug/L 1000 500 1 07/24/20 09:37 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-5 Lab ID: 92486765007 Collected: 07/16/20 08:28 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:17 7440-36-0 Arsenic 7.3J ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:17 7440-38-2 Barium 117 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:17 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:17 7440-41-7 Cadmium 0.62J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:17 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:17 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:17 7440-48-4 Copper 5.2 ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:17 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:17 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:17 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:17 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:17 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:08 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 13:50 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 13:50 107-13-1 Benzene 2.2 ug/L 1.0 0.15 1 07/25/20 13:50 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 13:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 13:50 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 13:50 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 13:50 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 13:50 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 13:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 13:50 56-23-5 Chlorobenzene 0.551 ug/L 1.0 0.23 1 07/25/20 13:50 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 13:50 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 13:50 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 13:50 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 13:50 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 13:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 13:50 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 13:50 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 13:50 95-50-1 1,4-Dichlorobenzene 1.9 ug/L 1.0 0.26 1 07/25/20 13:50 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 13:50 110-57-6 1,1-Dichloroethane 2.4 ug/L 1.0 0.27 1 07/25/20 13:50 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 13:50 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 13:50 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. L1 IK,v1 Page 26 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-5 Lab ID: 92486765007 Collected: 07/16/20 08:28 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 11.7 ug/L 1.0 0.29 1 07/25/2013:50 156-59-2 ND ug/L 1.0 0.25 1 07/25/2013:50 156-60-5 ND ug/L 1.0 0.19 1 07/25/2013:50 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 13:50 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2013:50 10061-02-6 ND ug/L 150 56.2 1 07/25/2013:50 123-91-1 ND ug/L 1.0 0.26 1 07/25/2013:50 100-41-4 ND ug/L 5.0 0.57 1 07/25/2013:50 591-78-6 ND ug/L 20.0 12.5 1 07/25/2013:50 74-88-4 ND ug/L 5.0 3.7 1 07/25/2013:50 75-09-2 ND ug/L 5.0 4.5 1 07/25/2013:50 108-10-1 ND ug/L 1.0 0.27 1 07/25/2013:50 100-42-5 ND ug/L 1.0 0.34 1 07/25/2013:50 630-20-6 ND ug/L 1.0 0.22 1 07/25/2013:50 79-34-5 ND ug/L 1.0 0.16 1 07/25/2013:50 127-18-4 0.28J ug/L 1.0 0.24 1 07/25/2013:50 108-88-3 ND ug/L 1.0 0.18 1 07/25/2013:50 71-55-6 ND ug/L 1.0 0.24 1 07/25/2013:50 79-00-5 ND ug/L 1.0 0.22 1 07/25/2013:50 79-01-6 ND ug/L 1.0 0.31 1 07/25/2013:50 75-69-4 ND ug/L 1.0 0.35 1 07/25/2013:50 96-18-4 ND ug/L 2.0 1.4 1 07/25/2013:50 108-05-4 ND ug/L 1.0 0.24 1 07/25/2013:50 75-01-4 ND ug/L 1.0 0.63 1 07/25/2013:50 1330-20-7 98 % 70-130 1 07/25/2013:50 460-00-4 107 % 70-130 1 07/25/2013:50 17060-07-0 102 % 70-130 1 07/25/2013:50 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 144000 ug/L 5000 5000 1 07/23/2015:56 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 16.8 mg/L 5.0 0.84 10 07/21/2015:57 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:32 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 735J ug/L 1000 500 1 07/22/2010:34 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-5 Parameters Lab ID: 92486765007 Collected: Report Results Units Limit 07/16/20 08:28 MDL DF Received: 07/17/20 06:17 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 07/18/20 01:10 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 4310 ug/L 1000 500 1 07/27/20 20:11 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 26200 ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:38 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 1830 ug/L 1000 500 1 07/24/20 09:59 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-10 Lab ID: 92486765008 Collected: 07/16/20 09:15 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:20 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:20 7440-38-2 Barium 5.2 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:20 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:20 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:20 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:20 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:20 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:20 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:20 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:20 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:20 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:20 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:20 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:20 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:23 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 10:11 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 10:11 107-13-1 Benzene 0.96J ug/L 1.0 0.15 1 07/25/20 10:11 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 10:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 10:11 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 10:11 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 10:11 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 10:11 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 10:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 10:11 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 10:11 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 10:11 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 10:11 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 10:11 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 10:11 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 10:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 10:11 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 10:11 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 10:11 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 10:11 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 10:11 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 10:11 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 10:11 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 10:11 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 29 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-10 Lab ID: 92486765008 Collected: 07/16/20 09:15 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 3.2 ug/L 1.0 0.29 1 07/25/2010:11 156-59-2 ND ug/L 1.0 0.25 1 07/25/2010:11 156-60-5 ND ug/L 1.0 0.19 1 07/25/2010:11 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 10:11 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2010:11 10061-02-6 ND ug/L 150 56.2 1 07/25/2010:11 123-91-1 ND ug/L 1.0 0.26 1 07/25/2010:11 100-41-4 ND ug/L 5.0 0.57 1 07/25/2010:11 591-78-6 ND ug/L 20.0 12.5 1 07/25/2010:11 74-88-4 ND ug/L 5.0 3.7 1 07/25/2010:11 75-09-2 ND ug/L 5.0 4.5 1 07/25/2010:11 108-10-1 ND ug/L 1.0 0.27 1 07/25/2010:11 100-42-5 ND ug/L 1.0 0.34 1 07/25/2010:11 630-20-6 ND ug/L 1.0 0.22 1 07/25/2010:11 79-34-5 ND ug/L 1.0 0.16 1 07/25/2010:11 127-18-4 ND ug/L 1.0 0.24 1 07/25/2010:11 108-88-3 ND ug/L 1.0 0.18 1 07/25/2010:11 71-55-6 ND ug/L 1.0 0.24 1 07/25/2010:11 79-00-5 ND ug/L 1.0 0.22 1 07/25/2010:11 79-01-6 ND ug/L 1.0 0.31 1 07/25/2010:11 75-69-4 ND ug/L 1.0 0.35 1 07/25/2010:11 96-18-4 ND ug/L 2.0 1.4 1 07/25/2010:11 108-05-4 ND ug/L 1.0 0.24 1 07/25/2010:11 75-01-4 ND ug/L 1.0 0.63 1 07/25/2010:11 1330-20-7 102 % 70-130 1 07/25/2010:11 460-00-4 91 % 70-130 1 07/25/2010:11 17060-07-0 104 % 70-130 1 07/25/2010:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-13 Lab ID: 92486765009 Collected: 07/15/20 13:20 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:23 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:23 7440-38-2 Barium 14.0 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:23 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:23 7440-41-7 Cadmium 3.3 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:23 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:23 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:23 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:23 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:23 7439-92-1 Nickel 7.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:23 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:23 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:23 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:23 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:23 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:30 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 09:29 67-64-1 v1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 09:29 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 09:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 09:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 09:29 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 09:29 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 09:29 74-83-9 IK,v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 09:29 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 09:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 09:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 09:29 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 09:29 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 09:29 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 09:29 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 09:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 09:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 09:29 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 09:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 09:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 09:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 09:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 09:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 09:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 09:29 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-13 Lab ID: 92486765009 Collected: 07/15/20 13:20 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 09:29 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 09:29 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 09:29 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 09:29 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 09:29 10061-02-6 ND ug/L 150 56.2 1 07/24/20 09:29 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 09:29 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 09:29 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 09:29 74-88-4 ND ug/L 5.0 3.7 1 07/24/20 09:29 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 09:29 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 09:29 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 09:29 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 09:29 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 09:29 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 09:29 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 09:29 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 09:29 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 09:29 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 09:29 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 09:29 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 09:29 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 09:29 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 09:29 1330-20-7 95 % 70-130 1 07/24/20 09:29 460-00-4 102 % 70-130 1 07/24/20 09:29 17060-07-0 101 % 70-130 1 07/24/20 09:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 Page 32 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-14 Lab ID: 92486765010 Collected: 07/15/20 13:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 13:49 7440-36-0 Arsenic 5.5J ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 13:49 7440-38-2 Barium 136 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 13:49 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 13:49 7440-41-7 Cadmium 1.4 ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 13:49 7440-43-9 Chromium 157 ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 13:49 7440-47-3 Cobalt 4.7.1 ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 13:49 7440-48-4 Copper 62.9 ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 13:49 7440-50-8 Lead 38.8 ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 13:49 7439-92-1 Nickel 42.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 13:49 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 13:49 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 13:49 7440-22-4 Vanadium 304 ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 13:49 7440-62-2 Zinc 791 ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 13:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.066J ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:49 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 09:47 67-64-1 v1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 09:47 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 09:47 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 09:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 09:47 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 09:47 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 09:47 74-83-9 IK,v2 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 09:47 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 09:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 09:47 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 09:47 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 09:47 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 09:47 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 09:47 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 09:47 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 09:47 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 09:47 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 09:47 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 09:47 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 09:47 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 09:47 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 09:47 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 09:47 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 09:47 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-14 Lab ID: 92486765010 Collected: 07/15/20 13:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.1 ug/L 1.0 0.29 1 07/24/20 09:47 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 09:47 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 09:47 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 09:47 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 09:47 10061-02-6 ND ug/L 150 56.2 1 07/24/20 09:47 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 09:47 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 09:47 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 09:47 74-88-4 ND ug/L 5.0 3.7 1 07/24/20 09:47 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 09:47 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 09:47 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 09:47 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 09:47 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 09:47 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 09:47 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 09:47 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 09:47 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 09:47 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 09:47 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 09:47 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 09:47 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 09:47 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 09:47 1330-20-7 99 % 70-130 1 07/24/20 09:47 460-00-4 97 % 70-130 1 07/24/20 09:47 17060-07-0 101 % 70-130 1 07/24/20 09:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 Page 34 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-15 Lab ID: 92486765011 Collected: 07/15/20 12:41 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 13:52 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 13:52 7440-38-2 Barium 74.7 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 13:52 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 13:52 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 13:52 7440-43-9 Chromium 12.4 ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 13:52 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 13:52 7440-48-4 Copper 7.7 ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 13:52 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 13:52 7439-92-1 Nickel 15.0 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 13:52 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 13:52 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 13:52 7440-22-4 Vanadium 59.0 ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 13:52 7440-62-2 Zinc 60.1 ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 13:52 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.080J ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 00:57 7440-28-0 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 07/30/2020 05:17 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 2.6 ug/L 0.20 0.12 1 07/21 /20 16:35 07/22/20 14:29 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 3.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 0.24J ug/L 1.0 0.76J ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.1 ug/L 1.0 6.2 1 07/25/20 13:14 67-64-1 0.90 1 07/25/20 13:14 107-13-1 0.15 1 07/25/20 13:14 71-43-2 0.34 1 07/25/20 13:14 74-97-5 0.26 1 07/25/20 13:14 75-27-4 0.62 1 07/25/20 13:14 75-25-2 0.62 1 07/25/20 13:14 74-83-9 3.3 1 07/25/20 13:14 78-93-3 0.40 1 07/25/20 13:14 75-15-0 0.22 1 07/25/20 13:14 56-23-5 0.23 1 07/25/20 13:14 108-90-7 0.49 1 07/25/20 13:14 75-00-3 2.3 1 07/25/20 13:14 67-66-3 0.39 1 07/25/20 13:14 74-87-3 0.26 1 07/25/20 13:14 96-12-8 0.41 1 07/25/20 13:14 124-48-1 0.26 1 07/25/20 13:14 106-93-4 0.46 1 07/25/20 13:14 74-95-3 0.29 1 07/25/20 13:14 95-50-1 0.26 1 07/25/20 13:14 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-15 Lab ID: 92486765011 Collected: 07/15/20 12:41 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/25/2013:14 110-57-6 v2 1.3 ug/L 1.0 0.27 1 07/25/2013:14 75-34-3 ND ug/L 1.0 0.34 1 07/25/2013:14 107-06-2 ND ug/L 1.0 0.24 1 07/25/2013:14 75-35-4 7.9 ug/L 1.0 0.29 1 07/25/2013:14 156-59-2 ND ug/L 1.0 0.25 1 07/25/2013:14 156-60-5 ND ug/L 1.0 0.19 1 07/25/2013:14 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 13:14 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2013:14 10061-02-6 ND ug/L 150 56.2 1 07/25/2013:14 123-91-1 ND ug/L 1.0 0.26 1 07/25/2013:14 100-41-4 ND ug/L 5.0 0.57 1 07/25/2013:14 591-78-6 ND ug/L 20.0 12.5 1 07/25/2013:14 74-88-4 ND ug/L 5.0 3.7 1 07/25/2013:14 75-09-2 ND ug/L 5.0 4.5 1 07/25/2013:14 108-10-1 ND ug/L 1.0 0.27 1 07/25/2013:14 100-42-5 ND ug/L 1.0 0.34 1 07/25/2013:14 630-20-6 ND ug/L 1.0 0.22 1 07/25/2013:14 79-34-5 0.57J ug/L 1.0 0.16 1 07/25/2013:14 127-18-4 ND ug/L 1.0 0.24 1 07/25/2013:14 108-88-3 ND ug/L 1.0 0.18 1 07/25/2013:14 71-55-6 ND ug/L 1.0 0.24 1 07/25/2013:14 79-00-5 1.2 ug/L 1.0 0.22 1 07/25/2013:14 79-01-6 ND ug/L 1.0 0.31 1 07/25/2013:14 75-69-4 ND ug/L 1.0 0.35 1 07/25/2013:14 96-18-4 ND ug/L 2.0 1.4 1 07/25/2013:14 108-05-4 ND ug/L 1.0 0.24 1 07/25/2013:14 75-01-4 ND ug/L 1.0 0.63 1 07/25/2013:14 1330-20-7 103 % 70-130 1 07/25/2013:14 460-00-4 95 % 70-130 1 07/25/2013:14 17060-07-0 103 % 70-130 1 07/25/2013:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-17 Lab ID: 92486765012 Collected: 07/15/20 12:35 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:32 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:32 7440-38-2 Barium 62.2 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:32 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:32 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:32 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:32 7440-47-3 Cobalt 15.0 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:32 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:32 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:32 7439-92-1 Nickel 4.1J ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:32 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:32 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:32 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:32 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:32 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.051J ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 08:03 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 13:32 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 13:32 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 13:32 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 13:32 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 13:32 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 13:32 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 13:32 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 13:32 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 13:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 13:32 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 13:32 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 13:32 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 13:32 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 13:32 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 13:32 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 13:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 13:32 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 13:32 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 13:32 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 13:32 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 13:32 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 13:32 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 13:32 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 13:32 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 37 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-17 Lab ID: 92486765012 Collected: 07/15/20 12:35 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.5 ug/L 1.0 0.29 1 07/25/2013:32 156-59-2 ND ug/L 1.0 0.25 1 07/25/2013:32 156-60-5 ND ug/L 1.0 0.19 1 07/25/2013:32 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 13:32 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2013:32 10061-02-6 ND ug/L 150 56.2 1 07/25/2013:32 123-91-1 ND ug/L 1.0 0.26 1 07/25/2013:32 100-41-4 ND ug/L 5.0 0.57 1 07/25/2013:32 591-78-6 ND ug/L 20.0 12.5 1 07/25/2013:32 74-88-4 ND ug/L 5.0 3.7 1 07/25/2013:32 75-09-2 ND ug/L 5.0 4.5 1 07/25/2013:32 108-10-1 ND ug/L 1.0 0.27 1 07/25/2013:32 100-42-5 ND ug/L 1.0 0.34 1 07/25/2013:32 630-20-6 ND ug/L 1.0 0.22 1 07/25/2013:32 79-34-5 ND ug/L 1.0 0.16 1 07/25/2013:32 127-18-4 ND ug/L 1.0 0.24 1 07/25/2013:32 108-88-3 ND ug/L 1.0 0.18 1 07/25/2013:32 71-55-6 ND ug/L 1.0 0.24 1 07/25/2013:32 79-00-5 ND ug/L 1.0 0.22 1 07/25/2013:32 79-01-6 ND ug/L 1.0 0.31 1 07/25/2013:32 75-69-4 ND ug/L 1.0 0.35 1 07/25/2013:32 96-18-4 ND ug/L 2.0 1.4 1 07/25/2013:32 108-05-4 ND ug/L 1.0 0.24 1 07/25/2013:32 75-01-4 ND ug/L 1.0 0.63 1 07/25/2013:32 1330-20-7 103 % 70-130 1 07/25/2013:32 460-00-4 94 % 70-130 1 07/25/2013:32 17060-07-0 103 % 70-130 1 07/25/2013:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-18 Lab ID: 92486765013 Collected: 07/15/20 16:04 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 21:36 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:36 7440-38-2 Barium 5.9 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:36 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 21:36 7440-41-7 Cadmium 1.3 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 21:36 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 21:36 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 21:36 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 21:36 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 21:36 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 21:36 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 21:36 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 21:36 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 21:36 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 21:36 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.054J ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 08:29 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 13:51 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 13:51 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 13:51 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 13:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 13:51 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 13:51 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 13:51 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 13:51 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 13:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 13:51 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 13:51 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 13:51 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 13:51 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 13:51 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 13:51 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 13:51 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 13:51 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 13:51 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 13:51 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 13:51 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 13:51 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 13:51 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 13:51 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 13:51 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 39 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-18 Lab ID: 92486765013 Collected: 07/15/20 16:04 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2013:51 156-59-2 ND ug/L 1.0 0.25 1 07/25/2013:51 156-60-5 ND ug/L 1.0 0.19 1 07/25/2013:51 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 13:51 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2013:51 10061-02-6 ND ug/L 150 56.2 1 07/25/2013:51 123-91-1 ND ug/L 1.0 0.26 1 07/25/2013:51 100-41-4 ND ug/L 5.0 0.57 1 07/25/2013:51 591-78-6 ND ug/L 20.0 12.5 1 07/25/2013:51 74-88-4 ND ug/L 5.0 3.7 1 07/25/2013:51 75-09-2 ND ug/L 5.0 4.5 1 07/25/2013:51 108-10-1 ND ug/L 1.0 0.27 1 07/25/2013:51 100-42-5 ND ug/L 1.0 0.34 1 07/25/2013:51 630-20-6 ND ug/L 1.0 0.22 1 07/25/2013:51 79-34-5 ND ug/L 1.0 0.16 1 07/25/2013:51 127-18-4 ND ug/L 1.0 0.24 1 07/25/2013:51 108-88-3 ND ug/L 1.0 0.18 1 07/25/2013:51 71-55-6 ND ug/L 1.0 0.24 1 07/25/2013:51 79-00-5 ND ug/L 1.0 0.22 1 07/25/2013:51 79-01-6 ND ug/L 1.0 0.31 1 07/25/2013:51 75-69-4 ND ug/L 1.0 0.35 1 07/25/2013:51 96-18-4 ND ug/L 2.0 1.4 1 07/25/2013:51 108-05-4 ND ug/L 1.0 0.24 1 07/25/2013:51 75-01-4 ND ug/L 1.0 0.63 1 07/25/2013:51 1330-20-7 104 % 70-130 1 07/25/2013:51 460-00-4 95 % 70-130 1 07/25/2013:51 17060-07-0 103 % 70-130 1 07/25/2013:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-19 Lab ID: 92486765014 Collected: 07/15/20 15:45 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 14:13 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:13 7440-38-2 Barium 20.9 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:13 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 14:13 7440-41-7 Cadmium 3.5 ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 14:13 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 14:13 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 14:13 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 14:13 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 14:13 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:13 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 14:13 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 14:13 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 14:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:16 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 14:09 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 14:09 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 14:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 14:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 14:09 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 14:09 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 14:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 14:09 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 14:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 14:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 14:09 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 14:09 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 14:09 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 14:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 14:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 14:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 14:09 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 14:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 14:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 14:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 14:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 14:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 14:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 14:09 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 41 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-19 Lab ID: 92486765014 Collected: 07/15/20 15:45 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2014:09 156-59-2 ND ug/L 1.0 0.25 1 07/25/2014:09 156-60-5 ND ug/L 1.0 0.19 1 07/25/2014:09 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 14:09 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2014:09 10061-02-6 ND ug/L 150 56.2 1 07/25/2014:09 123-91-1 ND ug/L 1.0 0.26 1 07/25/2014:09 100-41-4 ND ug/L 5.0 0.57 1 07/25/2014:09 591-78-6 ND ug/L 20.0 12.5 1 07/25/2014:09 74-88-4 ND ug/L 5.0 3.7 1 07/25/2014:09 75-09-2 ND ug/L 5.0 4.5 1 07/25/2014:09 108-10-1 ND ug/L 1.0 0.27 1 07/25/2014:09 100-42-5 ND ug/L 1.0 0.34 1 07/25/2014:09 630-20-6 ND ug/L 1.0 0.22 1 07/25/2014:09 79-34-5 ND ug/L 1.0 0.16 1 07/25/2014:09 127-18-4 ND ug/L 1.0 0.24 1 07/25/2014:09 108-88-3 ND ug/L 1.0 0.18 1 07/25/2014:09 71-55-6 ND ug/L 1.0 0.24 1 07/25/2014:09 79-00-5 ND ug/L 1.0 0.22 1 07/25/2014:09 79-01-6 ND ug/L 1.0 0.31 1 07/25/2014:09 75-69-4 ND ug/L 1.0 0.35 1 07/25/2014:09 96-18-4 ND ug/L 2.0 1.4 1 07/25/2014:09 108-05-4 ND ug/L 1.0 0.24 1 07/25/2014:09 75-01-4 ND ug/L 1.0 0.63 1 07/25/2014:09 1330-20-7 101 % 70-130 1 07/25/2014:09 460-00-4 95 % 70-130 1 07/25/2014:09 17060-07-0 103 % 70-130 1 07/25/2014:09 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-20 Lab ID: 92486765015 Collected: 07/15/20 13:11 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:11 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:11 7440-38-2 Barium 47.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:11 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:11 7440-41-7 Cadmium 0.41J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:11 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:11 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:11 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:11 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:11 7439-92-1 Nickel 5.9 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:11 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:11 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:11 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:20 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 14:27 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 14:27 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 14:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 14:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 14:27 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 14:27 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 14:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 14:27 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 14:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 14:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 14:27 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 14:27 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 14:27 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 14:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 14:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 14:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 14:27 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 14:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 14:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 14:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 14:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 14:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 14:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 14:27 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 43 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-20 Lab ID: 92486765015 Collected: 07/15/20 13:11 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 0.30J ug/L 1.0 0.29 1 07/25/2014:27 156-59-2 ND ug/L 1.0 0.25 1 07/25/2014:27 156-60-5 ND ug/L 1.0 0.19 1 07/25/2014:27 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 14:27 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2014:27 10061-02-6 ND ug/L 150 56.2 1 07/25/2014:27 123-91-1 ND ug/L 1.0 0.26 1 07/25/2014:27 100-41-4 ND ug/L 5.0 0.57 1 07/25/2014:27 591-78-6 ND ug/L 20.0 12.5 1 07/25/2014:27 74-88-4 ND ug/L 5.0 3.7 1 07/25/2014:27 75-09-2 ND ug/L 5.0 4.5 1 07/25/2014:27 108-10-1 ND ug/L 1.0 0.27 1 07/25/2014:27 100-42-5 ND ug/L 1.0 0.34 1 07/25/2014:27 630-20-6 ND ug/L 1.0 0.22 1 07/25/2014:27 79-34-5 ND ug/L 1.0 0.16 1 07/25/2014:27 127-18-4 ND ug/L 1.0 0.24 1 07/25/2014:27 108-88-3 ND ug/L 1.0 0.18 1 07/25/2014:27 71-55-6 ND ug/L 1.0 0.24 1 07/25/2014:27 79-00-5 ND ug/L 1.0 0.22 1 07/25/2014:27 79-01-6 ND ug/L 1.0 0.31 1 07/25/2014:27 75-69-4 ND ug/L 1.0 0.35 1 07/25/2014:27 96-18-4 ND ug/L 2.0 1.4 1 07/25/2014:27 108-05-4 ND ug/L 1.0 0.24 1 07/25/2014:27 75-01-4 ND ug/L 1.0 0.63 1 07/25/2014:27 1330-20-7 103 % 70-130 1 07/25/2014:27 460-00-4 95 % 70-130 1 07/25/2014:27 17060-07-0 101 % 70-130 1 07/25/2014:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-21 Lab ID: 92486765016 Collected: 07/15/20 12:30 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:14 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:14 7440-38-2 Barium 21.5 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:14 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:14 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:14 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:14 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:14 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:14 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:14 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:14 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:14 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:14 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 14:45 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 14:45 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 14:45 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 14:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 14:45 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 14:45 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 14:45 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 14:45 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 14:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 14:45 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 14:45 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 14:45 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 14:45 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 14:45 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 14:45 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 14:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 14:45 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 14:45 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 14:45 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 14:45 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 14:45 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 14:45 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 14:45 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 14:45 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 45 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-21 Lab ID: 92486765016 Collected: 07/15/20 12:30 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2014:45 156-59-2 ND ug/L 1.0 0.25 1 07/25/2014:45 156-60-5 ND ug/L 1.0 0.19 1 07/25/2014:45 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 14:45 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2014:45 10061-02-6 ND ug/L 150 56.2 1 07/25/2014:45 123-91-1 ND ug/L 1.0 0.26 1 07/25/2014:45 100-41-4 ND ug/L 5.0 0.57 1 07/25/2014:45 591-78-6 ND ug/L 20.0 12.5 1 07/25/2014:45 74-88-4 ND ug/L 5.0 3.7 1 07/25/2014:45 75-09-2 ND ug/L 5.0 4.5 1 07/25/2014:45 108-10-1 ND ug/L 1.0 0.27 1 07/25/2014:45 100-42-5 ND ug/L 1.0 0.34 1 07/25/2014:45 630-20-6 ND ug/L 1.0 0.22 1 07/25/2014:45 79-34-5 ND ug/L 1.0 0.16 1 07/25/2014:45 127-18-4 ND ug/L 1.0 0.24 1 07/25/2014:45 108-88-3 ND ug/L 1.0 0.18 1 07/25/2014:45 71-55-6 ND ug/L 1.0 0.24 1 07/25/2014:45 79-00-5 ND ug/L 1.0 0.22 1 07/25/2014:45 79-01-6 ND ug/L 1.0 0.31 1 07/25/2014:45 75-69-4 ND ug/L 1.0 0.35 1 07/25/2014:45 96-18-4 ND ug/L 2.0 1.4 1 07/25/2014:45 108-05-4 ND ug/L 1.0 0.24 1 07/25/2014:45 75-01-4 ND ug/L 1.0 0.63 1 07/25/2014:45 1330-20-7 105 % 70-130 1 07/25/2014:45 460-00-4 93 % 70-130 1 07/25/2014:45 17060-07-0 103 % 70-130 1 07/25/2014:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-22 Lab ID: 92486765017 Collected: 07/15/20 12:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:18 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:18 7440-38-2 Barium 57.7 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:18 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:18 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:18 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:18 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:18 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:18 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:18 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:18 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:18 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:18 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:27 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 10:29 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 10:29 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 10:29 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 10:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 10:29 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 10:29 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 10:29 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 10:29 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 10:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 10:29 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 10:29 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 10:29 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 10:29 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 10:29 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 10:29 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 10:29 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 10:29 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 10:29 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 10:29 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 10:29 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 10:29 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 10:29 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 10:29 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 10:29 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 47 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-22 Lab ID: 92486765017 Collected: 07/15/20 12:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2010:29 156-59-2 ND ug/L 1.0 0.25 1 07/25/2010:29 156-60-5 ND ug/L 1.0 0.19 1 07/25/2010:29 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 10:29 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2010:29 10061-02-6 ND ug/L 150 56.2 1 07/25/2010:29 123-91-1 ND ug/L 1.0 0.26 1 07/25/2010:29 100-41-4 ND ug/L 5.0 0.57 1 07/25/2010:29 591-78-6 ND ug/L 20.0 12.5 1 07/25/2010:29 74-88-4 ND ug/L 5.0 3.7 1 07/25/2010:29 75-09-2 ND ug/L 5.0 4.5 1 07/25/2010:29 108-10-1 ND ug/L 1.0 0.27 1 07/25/2010:29 100-42-5 ND ug/L 1.0 0.34 1 07/25/2010:29 630-20-6 ND ug/L 1.0 0.22 1 07/25/2010:29 79-34-5 ND ug/L 1.0 0.16 1 07/25/2010:29 127-18-4 ND ug/L 1.0 0.24 1 07/25/2010:29 108-88-3 ND ug/L 1.0 0.18 1 07/25/2010:29 71-55-6 ND ug/L 1.0 0.24 1 07/25/2010:29 79-00-5 ND ug/L 1.0 0.22 1 07/25/2010:29 79-01-6 ND ug/L 1.0 0.31 1 07/25/2010:29 75-69-4 ND ug/L 1.0 0.35 1 07/25/2010:29 96-18-4 ND ug/L 2.0 1.4 1 07/25/2010:29 108-05-4 ND ug/L 1.0 0.24 1 07/25/2010:29 75-01-4 ND ug/L 1.0 0.63 1 07/25/2010:29 1330-20-7 101 % 70-130 1 07/25/2010:29 460-00-4 91 % 70-130 1 07/25/2010:29 17060-07-0 105 % 70-130 1 07/25/2010:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-23 Lab ID: 92486765018 Collected: 07/15/20 12:55 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:21 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:21 7440-38-2 Barium 26.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:21 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:21 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:21 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:21 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:21 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:21 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:21 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:21 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:21 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:21 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:31 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 10:48 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 10:48 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 10:48 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 10:48 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 10:48 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 10:48 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 10:48 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 10:48 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 10:48 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 10:48 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 10:48 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 10:48 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 10:48 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 10:48 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 10:48 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 10:48 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 10:48 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 10:48 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 10:48 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 10:48 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 10:48 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 10:48 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 10:48 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 10:48 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 49 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-23 Lab ID: 92486765018 Collected: 07/15/20 12:55 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2010:48 156-59-2 ND ug/L 1.0 0.25 1 07/25/2010:48 156-60-5 ND ug/L 1.0 0.19 1 07/25/2010:48 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 10:48 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2010:48 10061-02-6 ND ug/L 150 56.2 1 07/25/2010:48 123-91-1 ND ug/L 1.0 0.26 1 07/25/2010:48 100-41-4 ND ug/L 5.0 0.57 1 07/25/2010:48 591-78-6 ND ug/L 20.0 12.5 1 07/25/2010:48 74-88-4 ND ug/L 5.0 3.7 1 07/25/2010:48 75-09-2 ND ug/L 5.0 4.5 1 07/25/2010:48 108-10-1 ND ug/L 1.0 0.27 1 07/25/2010:48 100-42-5 ND ug/L 1.0 0.34 1 07/25/2010:48 630-20-6 ND ug/L 1.0 0.22 1 07/25/2010:48 79-34-5 ND ug/L 1.0 0.16 1 07/25/2010:48 127-18-4 ND ug/L 1.0 0.24 1 07/25/2010:48 108-88-3 ND ug/L 1.0 0.18 1 07/25/2010:48 71-55-6 ND ug/L 1.0 0.24 1 07/25/2010:48 79-00-5 ND ug/L 1.0 0.22 1 07/25/2010:48 79-01-6 ND ug/L 1.0 0.31 1 07/25/2010:48 75-69-4 ND ug/L 1.0 0.35 1 07/25/2010:48 96-18-4 ND ug/L 2.0 1.4 1 07/25/2010:48 108-05-4 ND ug/L 1.0 0.24 1 07/25/2010:48 75-01-4 ND ug/L 1.0 0.63 1 07/25/2010:48 1330-20-7 104 % 70-130 1 07/25/2010:48 460-00-4 93 % 70-130 1 07/25/2010:48 17060-07-0 104 % 70-130 1 07/25/2010:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-32 Lab ID: 92486765019 Collected: 07/15/20 09:21 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 14:19 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:19 7440-38-2 Barium 5.7 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:19 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 14:19 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 14:19 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 14:19 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 14:19 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 14:19 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 14:19 7439-92-1 Nickel 4.6J ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:19 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 14:19 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 14:19 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 14:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:35 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 11:06 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 11:06 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 11:06 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 11:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 11:06 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 11:06 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 11:06 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 11:06 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 11:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 11:06 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 11:06 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 11:06 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 11:06 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 11:06 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 11:06 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 11:06 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 11:06 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 11:06 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 11:06 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 11:06 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 11:06 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 11:06 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 11:06 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 11:06 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 51 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-32 Lab ID: 92486765019 Collected: 07/15/20 09:21 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2011:06 156-59-2 ND ug/L 1.0 0.25 1 07/25/2011:06 156-60-5 ND ug/L 1.0 0.19 1 07/25/2011:06 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 11:06 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2011:06 10061-02-6 ND ug/L 150 56.2 1 07/25/2011:06 123-91-1 ND ug/L 1.0 0.26 1 07/25/2011:06 100-41-4 ND ug/L 5.0 0.57 1 07/25/2011:06 591-78-6 ND ug/L 20.0 12.5 1 07/25/2011:06 74-88-4 ND ug/L 5.0 3.7 1 07/25/2011:06 75-09-2 ND ug/L 5.0 4.5 1 07/25/2011:06 108-10-1 ND ug/L 1.0 0.27 1 07/25/2011:06 100-42-5 ND ug/L 1.0 0.34 1 07/25/2011:06 630-20-6 ND ug/L 1.0 0.22 1 07/25/2011:06 79-34-5 ND ug/L 1.0 0.16 1 07/25/2011:06 127-18-4 ND ug/L 1.0 0.24 1 07/25/2011:06 108-88-3 ND ug/L 1.0 0.18 1 07/25/2011:06 71-55-6 ND ug/L 1.0 0.24 1 07/25/2011:06 79-00-5 ND ug/L 1.0 0.22 1 07/25/2011:06 79-01-6 ND ug/L 1.0 0.31 1 07/25/2011:06 75-69-4 ND ug/L 1.0 0.35 1 07/25/2011:06 96-18-4 ND ug/L 2.0 1.4 1 07/25/2011:06 108-05-4 ND ug/L 1.0 0.24 1 07/25/2011:06 75-01-4 ND ug/L 1.0 0.63 1 07/25/2011:06 1330-20-7 103 % 70-130 1 07/25/2011:06 460-00-4 91 % 70-130 1 07/25/2011:06 17060-07-0 104 % 70-130 1 07/25/2011:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-33 Lab ID: 92486765020 Collected: 07/15/20 09:10 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:34 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:34 7440-38-2 Barium 17.6 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:34 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:34 7440-41-7 Cadmium 0.76J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:34 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:34 7440-47-3 Cobalt 8.1 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:34 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:34 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:34 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:34 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:34 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:34 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:34 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:34 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:39 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 15:04 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 15:04 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 15:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 15:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 15:04 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 15:04 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 15:04 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 15:04 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 15:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 15:04 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 15:04 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 15:04 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 15:04 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 15:04 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 15:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 15:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 15:04 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 15:04 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 15:04 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 15:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 15:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 15:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 15:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 15:04 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 53 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-33 Lab ID: 92486765020 Collected: 07/15/20 09:10 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2015:04 156-59-2 ND ug/L 1.0 0.25 1 07/25/2015:04 156-60-5 ND ug/L 1.0 0.19 1 07/25/2015:04 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 15:04 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2015:04 10061-02-6 ND ug/L 150 56.2 1 07/25/2015:04 123-91-1 ND ug/L 1.0 0.26 1 07/25/2015:04 100-41-4 ND ug/L 5.0 0.57 1 07/25/2015:04 591-78-6 ND ug/L 20.0 12.5 1 07/25/2015:04 74-88-4 ND ug/L 5.0 3.7 1 07/25/2015:04 75-09-2 ND ug/L 5.0 4.5 1 07/25/2015:04 108-10-1 ND ug/L 1.0 0.27 1 07/25/2015:04 100-42-5 ND ug/L 1.0 0.34 1 07/25/2015:04 630-20-6 ND ug/L 1.0 0.22 1 07/25/2015:04 79-34-5 ND ug/L 1.0 0.16 1 07/25/2015:04 127-18-4 ND ug/L 1.0 0.24 1 07/25/2015:04 108-88-3 ND ug/L 1.0 0.18 1 07/25/2015:04 71-55-6 ND ug/L 1.0 0.24 1 07/25/2015:04 79-00-5 ND ug/L 1.0 0.22 1 07/25/2015:04 79-01-6 ND ug/L 1.0 0.31 1 07/25/2015:04 75-69-4 ND ug/L 1.0 0.35 1 07/25/2015:04 96-18-4 ND ug/L 2.0 1.4 1 07/25/2015:04 108-05-4 ND ug/L 1.0 0.24 1 07/25/2015:04 75-01-4 ND ug/L 1.0 0.63 1 07/25/2015:04 1330-20-7 105 % 70-130 1 07/25/2015:04 460-00-4 93 % 70-130 1 07/25/2015:04 17060-07-0 103 % 70-130 1 07/25/2015:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-34 Lab ID: 92486765021 Collected: 07/15/20 08:45 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 14:22 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:22 7440-38-2 Barium 18.4 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:22 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 14:22 7440-41-7 Cadmium 5.6 ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 14:22 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 14:22 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 14:22 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 14:22 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 14:22 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:22 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:22 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 14:22 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 14:22 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 14:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:42 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 11:24 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 11:24 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 11:24 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 11:24 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 11:24 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 11:24 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 11:24 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 11:24 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 11:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 11:24 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 11:24 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 11:24 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 11:24 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 11:24 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 11:24 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 11:24 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 11:24 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 11:24 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 11:24 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 11:24 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 11:24 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 11:24 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 11:24 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 11:24 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 55 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-34 Lab ID: 92486765021 Collected: 07/15/20 08:45 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/2011:24 156-59-2 ND ug/L 1.0 0.25 1 07/25/2011:24 156-60-5 ND ug/L 1.0 0.19 1 07/25/2011:24 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 11:24 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2011:24 10061-02-6 ND ug/L 150 56.2 1 07/25/2011:24 123-91-1 ND ug/L 1.0 0.26 1 07/25/2011:24 100-41-4 ND ug/L 5.0 0.57 1 07/25/2011:24 591-78-6 ND ug/L 20.0 12.5 1 07/25/2011:24 74-88-4 ND ug/L 5.0 3.7 1 07/25/2011:24 75-09-2 ND ug/L 5.0 4.5 1 07/25/2011:24 108-10-1 ND ug/L 1.0 0.27 1 07/25/2011:24 100-42-5 ND ug/L 1.0 0.34 1 07/25/2011:24 630-20-6 ND ug/L 1.0 0.22 1 07/25/2011:24 79-34-5 ND ug/L 1.0 0.16 1 07/25/2011:24 127-18-4 ND ug/L 1.0 0.24 1 07/25/2011:24 108-88-3 ND ug/L 1.0 0.18 1 07/25/2011:24 71-55-6 ND ug/L 1.0 0.24 1 07/25/2011:24 79-00-5 ND ug/L 1.0 0.22 1 07/25/2011:24 79-01-6 ND ug/L 1.0 0.31 1 07/25/2011:24 75-69-4 ND ug/L 1.0 0.35 1 07/25/2011:24 96-18-4 ND ug/L 2.0 1.4 1 07/25/2011:24 108-05-4 ND ug/L 1.0 0.24 1 07/25/2011:24 75-01-4 ND ug/L 1.0 0.63 1 07/25/2011:24 1330-20-7 101 % 70-130 1 07/25/2011:24 460-00-4 92 % 70-130 1 07/25/2011:24 17060-07-0 105 % 70-130 1 07/25/2011:24 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-3 Lab ID: 92486765022 Collected: 07/16/20 09:58 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:40 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:40 7440-38-2 Barium 26.9 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:40 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:40 7440-41-7 Cadmium 0.46J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:40 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:40 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:40 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:40 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:40 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:40 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:40 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:40 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:40 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:40 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:54 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 08:58 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 08:58 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 08:58 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 08:58 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 08:58 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 08:58 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 08:58 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 08:58 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 08:58 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 08:58 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 08:58 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 08:58 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 08:58 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 08:58 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 08:58 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 08:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 08:58 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 08:58 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 08:58 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 08:58 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 08:58 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 08:58 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 08:58 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 08:58 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 57 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-3 Lab ID: 92486765022 Collected: 07/16/20 09:58 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/20 08:58 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 08:58 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 08:58 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 08:58 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 08:58 10061-02-6 ND ug/L 150 56.2 1 07/25/20 08:58 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 08:58 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 08:58 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 08:58 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 08:58 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 08:58 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 08:58 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 08:58 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 08:58 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 08:58 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 08:58 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 08:58 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 08:58 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 08:58 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 08:58 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 08:58 96-18-4 ND ug/L 2.0 1.4 1 07/25/20 08:58 108-05-4 ND ug/L 1.0 0.24 1 07/25/20 08:58 75-01-4 ND ug/L 1.0 0.63 1 07/25/20 08:58 1330-20-7 102 % 70-130 1 07/25/20 08:58 460-00-4 93 % 70-130 1 07/25/20 08:58 17060-07-0 104 % 70-130 1 07/25/20 08:58 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-4R Lab ID: 92486765023 Collected: 07/16/20 13:08 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:44 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:44 7440-38-2 Barium 40.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:44 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:44 7440-41-7 Cadmium 2.2 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:44 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:44 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:44 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:44 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:44 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:44 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:44 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:44 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:44 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/28/20 23:58 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 09:16 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 09:16 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 09:16 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 09:16 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 09:16 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 09:16 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 09:16 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 09:16 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 09:16 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 09:16 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 09:16 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 09:16 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 09:16 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 09:16 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 09:16 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 09:16 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 09:16 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 09:16 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 09:16 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 09:16 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 09:16 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 09:16 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 09:16 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 09:16 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. IK v3 v2 Page 59 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-4R Lab ID: 92486765023 Collected: 07/16/20 13:08 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/20 09:16 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 09:16 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 09:16 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 09:16 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 09:16 10061-02-6 ND ug/L 150 56.2 1 07/25/20 09:16 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 09:16 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 09:16 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 09:16 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 09:16 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 09:16 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 09:16 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 09:16 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 09:16 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 09:16 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 09:16 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 09:16 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 09:16 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 09:16 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 09:16 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 09:16 96-18-4 ND ug/L 2.0 1.4 1 07/25/20 09:16 108-05-4 ND ug/L 1.0 0.24 1 07/25/20 09:16 75-01-4 ND ug/L 1.0 0.63 1 07/25/20 09:16 1330-20-7 100 % 70-130 1 07/25/20 09:16 460-00-4 95 % 70-130 1 07/25/20 09:16 17060-07-0 104 % 70-130 1 07/25/20 09:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-5 Lab ID: 92486765024 Collected: 07/16/20 09:35 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:47 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:47 7440-38-2 Barium 22.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:47 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:47 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:47 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:47 7440-47-3 Cobalt 12.1 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:47 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:47 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:47 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:47 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:47 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:47 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:01 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 09:53 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 09:53 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 09:53 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 09:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 09:53 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 09:53 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 09:53 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 09:53 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 09:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 09:53 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 09:53 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 09:53 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 09:53 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 09:53 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 09:53 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 09:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 09:53 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 09:53 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 09:53 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 09:53 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 09:53 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 09:53 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 09:53 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 09:53 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 61 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-5 Lab ID: 92486765024 Collected: 07/16/20 09:35 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/20 09:53 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 09:53 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 09:53 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 09:53 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 09:53 10061-02-6 ND ug/L 150 56.2 1 07/25/20 09:53 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 09:53 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 09:53 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 09:53 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 09:53 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 09:53 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 09:53 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 09:53 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 09:53 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 09:53 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 09:53 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 09:53 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 09:53 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 09:53 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 09:53 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 09:53 96-18-4 ND ug/L 2.0 1.4 1 07/25/20 09:53 108-05-4 ND ug/L 1.0 0.24 1 07/25/20 09:53 75-01-4 ND ug/L 1.0 0.63 1 07/25/20 09:53 1330-20-7 103 % 70-130 1 07/25/20 09:53 460-00-4 92 % 70-130 1 07/25/20 09:53 17060-07-0 105 % 70-130 1 07/25/20 09:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-6 Lab ID: 92486765025 Collected: 07/16/20 08:53 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:50 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:50 7440-38-2 Barium 17.3 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:50 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:50 7440-41-7 Cadmium 1.3 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:50 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:50 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:50 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:50 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:50 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:50 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:50 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:50 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:05 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 09:34 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 09:34 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/25/20 09:34 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 09:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 09:34 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 09:34 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 09:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 09:34 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 09:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 09:34 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/25/20 09:34 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 09:34 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 09:34 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 09:34 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 09:34 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 09:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 09:34 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 09:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 09:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/25/20 09:34 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 09:34 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 09:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 09:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 09:34 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. IK v2 Page 63 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: SW-6 Lab ID: 92486765025 Collected: 07/16/20 08:53 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/25/20 09:34 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 09:34 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 09:34 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 09:34 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 09:34 10061-02-6 ND ug/L 150 56.2 1 07/25/20 09:34 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 09:34 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 09:34 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 09:34 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 09:34 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 09:34 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 09:34 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 09:34 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 09:34 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 09:34 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 09:34 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 09:34 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 09:34 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 09:34 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 09:34 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 09:34 96-18-4 ND ug/L 2.0 1.4 1 07/25/20 09:34 108-05-4 ND ug/L 1.0 0.24 1 07/25/20 09:34 75-01-4 ND ug/L 1.0 0.63 1 07/25/20 09:34 1330-20-7 103 % 70-130 1 07/25/20 09:34 460-00-4 92 % 70-130 1 07/25/20 09:34 17060-07-0 104 % 70-130 1 07/25/20 09:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MWA Lab ID: 92486765026 Collected: 07/15/20 15:33 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane 510 ug/L 10.0 3.4 1 07/18/2017:52 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 14:25 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:25 7440-38-2 Barium 26.4 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:25 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 14:25 7440-41-7 Cadmium 2.0 ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 14:25 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 14:25 7440-47-3 Cobalt 8.7 ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 14:25 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 14:25 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 14:25 7439-92-1 Nickel 3.6J ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:25 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 14:25 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 14:25 7440-62-2 Zinc 21.6 ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 14:25 7440-66-6 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 07/30/2020 05:17 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville ND ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:09 7440-28-0 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 0.37J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.7 ug/L 1.0 6.2 1 07/25/20 15:22 67-64-1 0.90 1 07/25/20 15:22 107-13-1 0.15 1 07/25/20 15:22 71-43-2 0.34 1 07/25/20 15:22 74-97-5 0.26 1 07/25/20 15:22 75-27-4 0.62 1 07/25/20 15:22 75-25-2 0.62 1 07/25/20 15:22 74-83-9 3.3 1 07/25/20 15:22 78-93-3 0.40 1 07/25/20 15:22 75-15-0 0.22 1 07/25/20 15:22 56-23-5 0.23 1 07/25/20 15:22 108-90-7 0.49 1 07/25/20 15:22 75-00-3 2.3 1 07/25/20 15:22 67-66-3 0.39 1 07/25/20 15:22 74-87-3 0.26 1 07/25/20 15:22 96-12-8 0.41 1 07/25/20 15:22 124-48-1 0.26 1 07/25/20 15:22 106-93-4 0.46 1 07/25/20 15:22 74-95-3 0.29 1 07/25/20 15:22 95-50-1 0.26 1 07/25/20 15:22 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 65 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-1 Lab ID: 92486765026 Collected: 07/15/20 15:33 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.54 1 07/25/2015:22 110-57-6 v2 ND ug/L 1.0 0.27 1 07/25/2015:22 75-34-3 ND ug/L 1.0 0.34 1 07/25/2015:22 107-06-2 ND ug/L 1.0 0.24 1 07/25/2015:22 75-35-4 ND ug/L 1.0 0.29 1 07/25/2015:22 156-59-2 ND ug/L 1.0 0.25 1 07/25/2015:22 156-60-5 ND ug/L 1.0 0.19 1 07/25/2015:22 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 15:22 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2015:22 10061-02-6 ND ug/L 150 56.2 1 07/25/2015:22 123-91-1 ND ug/L 1.0 0.26 1 07/25/2015:22 100-41-4 ND ug/L 5.0 0.57 1 07/25/2015:22 591-78-6 ND ug/L 20.0 12.5 1 07/25/2015:22 74-88-4 ND ug/L 5.0 3.7 1 07/25/2015:22 75-09-2 ND ug/L 5.0 4.5 1 07/25/2015:22 108-10-1 ND ug/L 1.0 0.27 1 07/25/2015:22 100-42-5 ND ug/L 1.0 0.34 1 07/25/2015:22 630-20-6 ND ug/L 1.0 0.22 1 07/25/2015:22 79-34-5 ND ug/L 1.0 0.16 1 07/25/2015:22 127-18-4 ND ug/L 1.0 0.24 1 07/25/2015:22 108-88-3 ND ug/L 1.0 0.18 1 07/25/2015:22 71-55-6 ND ug/L 1.0 0.24 1 07/25/2015:22 79-00-5 ND ug/L 1.0 0.22 1 07/25/2015:22 79-01-6 ND ug/L 1.0 0.31 1 07/25/2015:22 75-69-4 ND ug/L 1.0 0.35 1 07/25/2015:22 96-18-4 ND ug/L 2.0 1.4 1 07/25/2015:22 108-05-4 ND ug/L 1.0 0.24 1 07/25/2015:22 75-01-4 ND ug/L 1.0 0.63 1 07/25/2015:22 1330-20-7 101 % 70-130 1 07/25/2015:22 460-00-4 93 % 70-130 1 07/25/2015:22 17060-07-0 103 % 70-130 1 07/25/2015:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MWAB Lab ID: 92486765027 Collected: 07/15/20 15:53 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Pace Analytical Services - Charlotte Methane ND ug/L 10.0 3.4 1 07/18/2018:07 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 22:56 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:56 7440-38-2 Barium 47.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:56 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 22:56 7440-41-7 Cadmium 2.0 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 22:56 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 22:56 7440-47-3 Cobalt 53.9 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 22:56 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 22:56 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 22:56 7439-92-1 Nickel 5.3 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 22:56 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 22:56 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 22:56 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 22:56 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 22:56 7440-66-6 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Date: 07/30/2020 05:17 PM Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville 0.088J ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:13 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A Pace Analytical Services -Asheville 2.3 ug/L 0.20 0.12 1 07/21 /20 16:35 07/22/20 14:32 7439-97-6 Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 6.2 1 07/25/20 15:59 67-64-1 0.90 1 07/25/20 15:59 107-13-1 0.15 1 07/25/20 15:59 71-43-2 0.34 1 07/25/20 15:59 74-97-5 0.26 1 07/25/20 15:59 75-27-4 0.62 1 07/25/20 15:59 75-25-2 0.62 1 07/25/20 15:59 74-83-9 3.3 1 07/25/20 15:59 78-93-3 0.40 1 07/25/20 15:59 75-15-0 0.22 1 07/25/20 15:59 56-23-5 0.23 1 07/25/20 15:59 108-90-7 0.49 1 07/25/20 15:59 75-00-3 2.3 1 07/25/20 15:59 67-66-3 0.39 1 07/25/20 15:59 74-87-3 0.26 1 07/25/20 15:59 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 67 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-1B Lab ID: 92486765027 Collected: 07/15/20 15:53 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.41 1 07/25/2015:59 124-48-1 ND ug/L 1.0 0.26 1 07/25/2015:59 106-93-4 ND ug/L 1.0 0.46 1 07/25/2015:59 74-95-3 ND ug/L 1.0 0.29 1 07/25/2015:59 95-50-1 1.1 ug/L 1.0 0.26 1 07/25/2015:59 106-46-7 ND ug/L 1.0 0.54 1 07/25/2015:59 110-57-6 v2 ND ug/L 1.0 0.27 1 07/25/2015:59 75-34-3 ND ug/L 1.0 0.34 1 07/25/2015:59 107-06-2 ND ug/L 1.0 0.24 1 07/25/2015:59 75-35-4 0.581 ug/L 1.0 0.29 1 07/25/2015:59 156-59-2 ND ug/L 1.0 0.25 1 07/25/2015:59 156-60-5 ND ug/L 1.0 0.19 1 07/25/2015:59 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 15:59 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2015:59 10061-02-6 ND ug/L 150 56.2 1 07/25/2015:59 123-91-1 ND ug/L 1.0 0.26 1 07/25/2015:59 100-41-4 ND ug/L 5.0 0.57 1 07/25/2015:59 591-78-6 ND ug/L 20.0 12.5 1 07/25/2015:59 74-88-4 ND ug/L 5.0 3.7 1 07/25/2015:59 75-09-2 ND ug/L 5.0 4.5 1 07/25/2015:59 108-10-1 ND ug/L 1.0 0.27 1 07/25/2015:59 100-42-5 ND ug/L 1.0 0.34 1 07/25/2015:59 630-20-6 ND ug/L 1.0 0.22 1 07/25/2015:59 79-34-5 ND ug/L 1.0 0.16 1 07/25/2015:59 127-18-4 ND ug/L 1.0 0.24 1 07/25/2015:59 108-88-3 ND ug/L 1.0 0.18 1 07/25/2015:59 71-55-6 ND ug/L 1.0 0.24 1 07/25/2015:59 79-00-5 ND ug/L 1.0 0.22 1 07/25/2015:59 79-01-6 ND ug/L 1.0 0.31 1 07/25/2015:59 75-69-4 ND ug/L 1.0 0.35 1 07/25/2015:59 96-18-4 ND ug/L 2.0 1.4 1 07/25/2015:59 108-05-4 ND ug/L 1.0 0.24 1 07/25/2015:59 75-01-4 ND ug/L 1.0 0.63 1 07/25/2015:59 1330-20-7 103 % 70-130 1 07/25/2015:59 460-00-4 93 % 70-130 1 07/25/2015:59 17060-07-0 103 % 70-130 1 07/25/2015:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 68 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-2 Lab ID: 92486765028 Collected: 07/15/20 13:43 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony 3.5J ug/L 5.0 3.0 1 07/25/20 02:10 07/27/20 14:28 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:28 7440-38-2 Barium 45.6 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:28 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/27/20 14:28 7440-41-7 Cadmium 0.54J ug/L 1.0 0.40 1 07/25/20 02:10 07/27/20 14:28 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/27/20 14:28 7440-47-3 Cobalt 677 ug/L 5.0 3.6 1 07/25/20 02:10 07/27/20 14:28 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/27/20 14:28 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/27/20 14:28 7439-92-1 Nickel 12.7 ug/L 5.0 3.5 1 07/25/20 02:10 07/27/20 14:28 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/27/20 14:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/27/20 14:28 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/27/20 14:28 7440-62-2 Zinc 15.7 ug/L 10.0 9.5 1 07/25/20 02:10 07/27/20 14:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.30 ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:17 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 11:42 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 11:42 107-13-1 Benzene 0.54J ug/L 1.0 0.15 1 07/25/20 11:42 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 11:42 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 11:42 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 11:42 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 11:42 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 11:42 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 11:42 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 11:42 56-23-5 Chlorobenzene 0.28J ug/L 1.0 0.23 1 07/25/20 11:42 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/25/20 11:42 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 11:42 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 11:42 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 11:42 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 11:42 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 11:42 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 11:42 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 11:42 95-50-1 1,4-Dichlorobenzene 0.69J ug/L 1.0 0.26 1 07/25/20 11:42 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 11:42 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/25/20 11:42 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 11:42 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 11:42 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. v2 Page 69 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-2 Lab ID: 92486765028 Collected: 07/15/20 13:43 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 1.0 ug/L 1.0 0.29 1 07/25/2011:42 156-59-2 ND ug/L 1.0 0.25 1 07/25/2011:42 156-60-5 ND ug/L 1.0 0.19 1 07/25/2011:42 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 11:42 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2011:42 10061-02-6 ND ug/L 150 56.2 1 07/25/2011:42 123-91-1 ND ug/L 1.0 0.26 1 07/25/2011:42 100-41-4 ND ug/L 5.0 0.57 1 07/25/2011:42 591-78-6 ND ug/L 20.0 12.5 1 07/25/2011:42 74-88-4 ND ug/L 5.0 3.7 1 07/25/2011:42 75-09-2 ND ug/L 5.0 4.5 1 07/25/2011:42 108-10-1 ND ug/L 1.0 0.27 1 07/25/2011:42 100-42-5 ND ug/L 1.0 0.34 1 07/25/2011:42 630-20-6 ND ug/L 1.0 0.22 1 07/25/2011:42 79-34-5 ND ug/L 1.0 0.16 1 07/25/2011:42 127-18-4 ND ug/L 1.0 0.24 1 07/25/2011:42 108-88-3 ND ug/L 1.0 0.18 1 07/25/2011:42 71-55-6 ND ug/L 1.0 0.24 1 07/25/2011:42 79-00-5 ND ug/L 1.0 0.22 1 07/25/2011:42 79-01-6 ND ug/L 1.0 0.31 1 07/25/2011:42 75-69-4 ND ug/L 1.0 0.35 1 07/25/2011:42 96-18-4 ND ug/L 2.0 1.4 1 07/25/2011:42 108-05-4 ND ug/L 1.0 0.24 1 07/25/2011:42 75-01-4 ND ug/L 1.0 0.63 1 07/25/2011:42 1330-20-7 101 % 70-130 1 07/25/2011:42 460-00-4 95 % 70-130 1 07/25/2011:42 17060-07-0 102 % 70-130 1 07/25/2011:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-4R Lab ID: 92486765029 Collected: 07/16/20 09:44 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 23:16 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 23:16 7440-38-2 Barium 119 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 23:16 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 23:16 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 23:16 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 23:16 7440-47-3 Cobalt 104 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 23:16 7440-48-4 Copper 4.7J ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 23:16 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 23:16 7439-92-1 Nickel 5.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 23:16 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 23:16 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 23:16 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 23:16 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 23:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:20 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone 11.4J ug/L 25.0 6.2 1 07/25/20 14:08 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 14:08 107-13-1 Benzene 0.80J ug/L 1.0 0.15 1 07/25/20 14:08 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 14:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 14:08 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 14:08 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 14:08 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 14:08 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 14:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 14:08 56-23-5 Chlorobenzene 0.85J ug/L 1.0 0.23 1 07/25/20 14:08 108-90-7 Chloroethane 0.65J ug/L 1.0 0.49 1 07/25/20 14:08 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 14:08 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 14:08 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 14:08 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 14:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 14:08 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 14:08 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 14:08 95-50-1 1,4-Dichlorobenzene 2.1 ug/L 1.0 0.26 1 07/25/20 14:08 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 14:08 110-57-6 1,1-Dichloroethane 0.70J ug/L 1.0 0.27 1 07/25/20 14:08 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 14:08 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 14:08 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. L1 IK,v1 Page 71 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-4R Lab ID: 92486765029 Collected: 07/16/20 09:44 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 6.2 ug/L 1.0 0.29 1 07/25/2014:08 156-59-2 ND ug/L 1.0 0.25 1 07/25/2014:08 156-60-5 ND ug/L 1.0 0.19 1 07/25/2014:08 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 14:08 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2014:08 10061-02-6 ND ug/L 150 56.2 1 07/25/2014:08 123-91-1 ND ug/L 1.0 0.26 1 07/25/2014:08 100-41-4 ND ug/L 5.0 0.57 1 07/25/2014:08 591-78-6 ND ug/L 20.0 12.5 1 07/25/2014:08 74-88-4 ND ug/L 5.0 3.7 1 07/25/2014:08 75-09-2 ND ug/L 5.0 4.5 1 07/25/2014:08 108-10-1 ND ug/L 1.0 0.27 1 07/25/2014:08 100-42-5 ND ug/L 1.0 0.34 1 07/25/2014:08 630-20-6 ND ug/L 1.0 0.22 1 07/25/2014:08 79-34-5 ND ug/L 1.0 0.16 1 07/25/2014:08 127-18-4 ND ug/L 1.0 0.24 1 07/25/2014:08 108-88-3 ND ug/L 1.0 0.18 1 07/25/2014:08 71-55-6 ND ug/L 1.0 0.24 1 07/25/2014:08 79-00-5 ND ug/L 1.0 0.22 1 07/25/2014:08 79-01-6 ND ug/L 1.0 0.31 1 07/25/2014:08 75-69-4 ND ug/L 1.0 0.35 1 07/25/2014:08 96-18-4 ND ug/L 2.0 1.4 1 07/25/2014:08 108-05-4 ND ug/L 1.0 0.24 1 07/25/2014:08 75-01-4 ND ug/L 1.0 0.63 1 07/25/2014:08 1330-20-7 97 % 70-130 1 07/25/2014:08 460-00-4 105 % 70-130 1 07/25/2014:08 17060-07-0 98 % 70-130 1 07/25/2014:08 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-9 Lab ID: 92486765030 Collected: 07/16/20 09:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 23:19 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 23:19 7440-38-2 Barium 217 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 23:19 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 23:19 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 23:19 7440-43-9 Chromium ND ug/L 50.0 36.6 10 07/25/20 02:10 07/27/20 14:31 7440-47-3 Cobalt 356 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 23:19 7440-48-4 Copper 4.8J ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 23:19 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 23:19 7439-92-1 Nickel 55.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 23:19 7440-02-0 Selenium 6.6J ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 23:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 23:19 7440-22-4 Vanadium ND ug/L 50.0 39.3 10 07/25/20 02:10 07/27/20 14:31 7440-62-2 Zinc 13.0 ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 23:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.22 ug/L 0.10 0.050 1 07/25/20 01:24 07/29/20 00:24 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/25/20 14:26 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/25/20 14:26 107-13-1 Benzene 1.1 ug/L 1.0 0.15 1 07/25/20 14:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/25/20 14:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/25/20 14:26 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/25/20 14:26 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/25/20 14:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/25/20 14:26 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/25/20 14:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/25/20 14:26 56-23-5 Chlorobenzene 1.3 ug/L 1.0 0.23 1 07/25/20 14:26 108-90-7 Chloroethane 0.78J ug/L 1.0 0.49 1 07/25/20 14:26 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/25/20 14:26 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/25/20 14:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/25/20 14:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/25/20 14:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/25/20 14:26 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/25/20 14:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/25/20 14:26 95-50-1 1,4-Dichlorobenzene 2.4 ug/L 1.0 0.26 1 07/25/20 14:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/25/20 14:26 110-57-6 1,1-Dichloroethane 0.37J ug/L 1.0 0.27 1 07/25/20 14:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/25/20 14:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/25/20 14:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. L1 IK,v1 Page 73 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-9 Lab ID: 92486765030 Collected: 07/16/20 09:50 Received: 07/17/20 06:17 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 11.6 ug/L 1.0 0.29 1 07/25/2014:26 156-59-2 ND ug/L 1.0 0.25 1 07/25/2014:26 156-60-5 ND ug/L 1.0 0.19 1 07/25/2014:26 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 14:26 10061-01-5 ND ug/L 1.0 0.31 1 07/25/2014:26 10061-02-6 ND ug/L 150 56.2 1 07/25/2014:26 123-91-1 ND ug/L 1.0 0.26 1 07/25/2014:26 100-41-4 ND ug/L 5.0 0.57 1 07/25/2014:26 591-78-6 ND ug/L 20.0 12.5 1 07/25/2014:26 74-88-4 ND ug/L 5.0 3.7 1 07/25/2014:26 75-09-2 ND ug/L 5.0 4.5 1 07/25/2014:26 108-10-1 ND ug/L 1.0 0.27 1 07/25/2014:26 100-42-5 ND ug/L 1.0 0.34 1 07/25/2014:26 630-20-6 ND ug/L 1.0 0.22 1 07/25/2014:26 79-34-5 ND ug/L 1.0 0.16 1 07/25/2014:26 127-18-4 ND ug/L 1.0 0.24 1 07/25/2014:26 108-88-3 ND ug/L 1.0 0.18 1 07/25/2014:26 71-55-6 ND ug/L 1.0 0.24 1 07/25/2014:26 79-00-5 ND ug/L 1.0 0.22 1 07/25/2014:26 79-01-6 ND ug/L 1.0 0.31 1 07/25/2014:26 75-69-4 ND ug/L 1.0 0.35 1 07/25/2014:26 96-18-4 ND ug/L 2.0 1.4 1 07/25/2014:26 108-05-4 ND ug/L 1.0 0.24 1 07/25/2014:26 75-01-4 ND ug/L 1.0 0.63 1 07/25/2014:26 1330-20-7 99 % 70-130 1 07/25/2014:26 460-00-4 105 % 70-130 1 07/25/2014:26 17060-07-0 101 % 70-130 1 07/25/2014:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 74 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-11 Lab ID: 92486704001 Collected: 07/17/20 08:12 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:12 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:12 7440-38-2 Barium 172 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:12 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:12 7440-41-7 Cadmium ND ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:12 7440-43-9 Chromium ND ug/L 25.0 18.3 5 07/25/20 02:10 07/27/20 13:46 7440-47-3 Cobalt 123 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:12 7440-48-4 Copper 7.5 ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:12 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:12 7439-92-1 Nickel 13.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:12 7440-02-0 Selenium 5.3J ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:12 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:12 7440-62-2 Zinc 25.4 ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.16 ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 22:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 22:10 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 22:10 107-13-1 Benzene 2.6 ug/L 1.0 0.15 1 07/24/20 22:10 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 22:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 22:10 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 22:10 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 22:10 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 22:10 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 22:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 22:10 56-23-5 Chlorobenzene 1.7 ug/L 1.0 0.23 1 07/24/20 22:10 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 22:10 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 22:10 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 22:10 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 22:10 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 22:10 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 22:10 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 22:10 74-95-3 1,2-Dichlorobenzene 0.45J ug/L 1.0 0.29 1 07/24/20 22:10 95-50-1 1,4-Dichlorobenzene 6.5 ug/L 1.0 0.26 1 07/24/20 22:10 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 22:10 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 22:10 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 22:10 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 22:10 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-11 Lab ID: 92486704001 Collected: 07/17/20 08:12 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 11.2 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 150 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 0.29 1 07/24/20 22:10 156-59-2 0.25 1 07/24/20 22:10 156-60-5 0.19 1 07/24/20 22:10 78-87-5 0.30 1 07/24/20 22:10 10061-01-5 0.31 1 07/24/20 22:10 10061-02-6 56.2 1 07/24/20 22:10 123-91-1 0.26 1 07/24/20 22:10 100-41-4 0.57 1 07/24/20 22:10 591-78-6 12.5 1 07/24/20 22:10 74-88-4 IL 3.7 1 07/24/20 22:10 75-09-2 4.5 1 07/24/20 22:10 108-10-1 0.27 1 07/24/20 22:10 100-42-5 0.34 1 07/24/20 22:10 630-20-6 0.22 1 07/24/20 22:10 79-34-5 0.16 1 07/24/20 22:10 127-18-4 0.24 1 07/24/20 22:10 108-88-3 0.18 1 07/24/20 22:10 71-55-6 0.24 1 07/24/20 22:10 79-00-5 0.22 1 07/24/20 22:10 79-01-6 0.31 1 07/24/20 22:10 75-69-4 0.35 1 07/24/20 22:10 96-18-4 1.4 1 07/24/20 22:10 108-05-4 0.24 1 07/24/20 22:10 75-01-4 0.63 1 07/24/20 22:10 1330-20-7 101 % 70-130 100 % 70-130 100 % 70-130 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 282000 ug/L 5000 5000 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 31.8 mg/L 12.5 2.1 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 2590 ug/L 1000 500 1 07/24/20 22:10 460-00-4 1 07/24/20 22:10 17060-07-0 1 07/24/20 22:10 2037-26-5 fi elrlf��af��e1<iM- M! 25 07/21/2016:08 H3,N2 1 07/22/20 22:34 18496-25-8 1 07/22/20 07:18 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-11 Lab ID: 92486704001 Collected: 07/17/20 08:12 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate ND ug/L 40.0 10.0 1 07/18/20 15:00 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 104000 ug/L 5000 2500 5 07/27/2019:51 16887-00-6 M1 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 66500 ug/L 25000 12500 1 07/21/20 17:20 07/22/20 15:51 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 7250 ug/L 1000 500 1 07/24/20 05:21 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 77 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12D Lab ID: 92486704002 Collected: 07/17/20 08:27 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:32 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:32 7440-38-2 Barium 122 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:32 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:32 7440-41-7 Cadmium 2.0 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:32 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:32 7440-47-3 Cobalt 56.8 ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:32 7440-48-4 Copper 4.6.1 ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:32 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:32 7439-92-1 Nickel 9.1 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:32 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:32 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:32 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:32 7440-62-2 Zinc 67.6 ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:32 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.15 ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 22:19 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 22:28 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 22:28 107-13-1 Benzene 1.4 ug/L 1.0 0.15 1 07/24/20 22:28 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 22:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 22:28 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 22:28 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 22:28 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 22:28 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 22:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 22:28 56-23-5 Chlorobenzene 0.79J ug/L 1.0 0.23 1 07/24/20 22:28 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 22:28 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 22:28 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 22:28 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 22:28 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 22:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 22:28 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 22:28 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 22:28 95-50-1 1,4-Dichlorobenzene 1.9 ug/L 1.0 0.26 1 07/24/20 22:28 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 22:28 110-57-6 1,1-Dichloroethane 0.49J ug/L 1.0 0.27 1 07/24/20 22:28 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 22:28 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 22:28 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12D Lab ID: 92486704002 Collected: 07/17/20 08:27 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte 5.4 ug/L 1.0 0.29 1 07/24/20 22:28 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 22:28 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 22:28 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 22:28 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 22:28 10061-02-6 ND ug/L 150 56.2 1 07/24/20 22:28 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 22:28 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 22:28 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 22:28 74-88-4 IL ND ug/L 5.0 3.7 1 07/24/20 22:28 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 22:28 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 22:28 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 22:28 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 22:28 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 22:28 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 22:28 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 22:28 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 22:28 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 22:28 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 22:28 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 22:28 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 22:28 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 22:28 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 22:28 1330-20-7 100 % 70-130 1 07/24/20 22:28 460-00-4 99 % 70-130 1 07/24/20 22:28 17060-07-0 100 % 70-130 1 07/24/20 22:28 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 95500 ug/L 5000 5000 1 07/22/2017:04 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 3.6 mg/L 1.0 0.17 2 07/21/2015:32 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:34 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 4190 ug/L 1000 500 1 07/22/20 07:32 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 79 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12D Parameters Lab ID: 92486704002 Collected: Report Results Units Limit 07/17/20 08:27 MDL DF Received: 07/17/20 12:16 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 73.1 ug/L 40.0 10.0 1 07/18/20 15:05 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 32800 ug/L 1000 500 1 07/27/20 20:30 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 26900 ug/L 25000 12500 1 07/21/20 17:20 07/22/20 15:52 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 4030 ug/L 1000 500 1 07/24/20 05:41 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 80 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-24 Lab ID: 92486704003 Collected: 07/17/20 08:48 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:35 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:35 7440-38-2 Barium 53.7 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:35 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:35 7440-41-7 Cadmium 0.53J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:35 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:35 7440-47-3 Cobalt 4.2J ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:35 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:35 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:35 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:35 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:35 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:35 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:35 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:04 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 22:46 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 22:46 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 22:46 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 22:46 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 22:46 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 22:46 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 22:46 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 22:46 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 22:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 22:46 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 22:46 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 22:46 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 22:46 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 22:46 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 22:46 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 22:46 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 22:46 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 22:46 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 22:46 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 22:46 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 22:46 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 22:46 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 22:46 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 22:46 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-24 Lab ID: 92486704003 Collected: 07/17/20 08:48 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 22:46 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 22:46 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 22:46 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 22:46 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 22:46 10061-02-6 ND ug/L 150 56.2 1 07/24/20 22:46 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 22:46 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 22:46 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 22:46 74-88-4 IL ND ug/L 5.0 3.7 1 07/24/20 22:46 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 22:46 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 22:46 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 22:46 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 22:46 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 22:46 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 22:46 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 22:46 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 22:46 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 22:46 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 22:46 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 22:46 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 22:46 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 22:46 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 22:46 1330-20-7 100 % 70-130 1 07/24/20 22:46 460-00-4 100 % 70-130 1 07/24/20 22:46 17060-07-0 100 % 70-130 1 07/24/20 22:46 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 9580 ug/L 5000 5000 1 07/22/2017:13 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 07/21/2015:01 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:34 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 1600 ug/L 1000 500 1 07/22/20 07:46 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-24 Parameters Lab ID: 92486704003 Collected: Report Results Units Limit 07/17/20 08:48 MDL DF Received: 07/17/20 12:16 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 194 ug/L 40.0 10.0 1 07/18/20 15:07 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 21800 ug/L 1000 500 1 07/27/2019:55 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand 29200 ug/L 25000 12500 1 07/21/20 17:20 07/22/20 15:52 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 849J ug/L 1000 500 1 07/24/20 06:01 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 83 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-25 Lab ID: 92486704004 Collected: 07/17/20 08:40 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:38 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:38 7440-38-2 Barium 50.8 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:38 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:38 7440-41-7 Cadmium 0.54J ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:38 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:38 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:38 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:38 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:38 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:38 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:38 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:38 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium 0.072J ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:12 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 21:52 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 21:52 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 21:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 21:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 21:52 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 21:52 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 21:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 21:52 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 21:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 21:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 21:52 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 21:52 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 21:52 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 21:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 21:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 21:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 21:52 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 21:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 21:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 21:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 21:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 21:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 21:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 21:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 84 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-25 Lab ID: 92486704004 Collected: 07/17/20 08:40 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 21:52 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 21:52 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 21:52 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 21:52 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 21:52 10061-02-6 ND ug/L 150 56.2 1 07/24/20 21:52 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 21:52 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 21:52 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 21:52 74-88-4 IL ND ug/L 5.0 3.7 1 07/24/20 21:52 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 21:52 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 21:52 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 21:52 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 21:52 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 21:52 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 21:52 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 21:52 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 21:52 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 21:52 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 21:52 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 21:52 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 21:52 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 21:52 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 21:52 1330-20-7 100 % 70-130 1 07/24/20 21:52 460-00-4 97 % 70-130 1 07/24/20 21:52 17060-07-0 101 % 70-130 1 07/24/20 21:52 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 10000 ug/L 5000 5000 1 07/22/2017:20 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville ND mg/L 0.50 0.084 1 07/21/2015:04 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:35 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville 5030 ug/L 1000 500 1 07/22/20 08:00 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 85 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-25 Parameters Lab ID: 92486704004 Collected: Report Results Units Limit 07/17/20 08:40 MDL DF Received: 07/17/20 12:16 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 816 ug/L 40.0 10.0 1 07/18/20 15:06 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 2730 ug/L 1000 500 1 07/27/2019:57 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 07/21/20 17:20 07/22/20 15:52 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 810J ug/L 1000 500 1 07/24/20 06:20 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12 Lab ID: 92486704005 Collected: 07/17/20 08:20 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:41 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:41 7440-38-2 Barium 12.4 ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:41 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:41 7440-41-7 Cadmium 2.7 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:41 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:41 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:41 7440-48-4 Copper 5.1 ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:41 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:41 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:41 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:41 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:41 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:19 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 23:04 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 23:04 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 23:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 23:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 23:04 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 23:04 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 23:04 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 23:04 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 23:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 23:04 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 23:04 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 23:04 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 23:04 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 23:04 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 23:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 23:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 23:04 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 23:04 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 23:04 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 23:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 23:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 23:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 23:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 23:04 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12 Lab ID: 92486704005 Collected: 07/17/20 08:20 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 23:04 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 23:04 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 23:04 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 23:04 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 23:04 10061-02-6 ND ug/L 150 56.2 1 07/24/20 23:04 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 23:04 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 23:04 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 23:04 74-88-4 IL ND ug/L 5.0 3.7 1 07/24/20 23:04 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 23:04 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 23:04 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 23:04 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 23:04 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 23:04 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 23:04 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 23:04 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 23:04 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 23:04 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 23:04 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 23:04 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 23:04 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 23:04 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 23:04 1330-20-7 101 % 70-130 1 07/24/20 23:04 460-00-4 101 % 70-130 1 07/24/20 23:04 17060-07-0 100 % 70-130 1 07/24/20 23:04 2037-26-5 Analytical Method: SM 2320B-2011 Pace Analytical Services -Asheville 450000 ug/L 5000 5000 1 07/22/2017:53 Analytical Method: SM 3500-Fe B-2011 Pace Analytical Services -Asheville 0.39J mg/L 0.50 0.084 1 07/21/2015:06 H3,N2 Analytical Method: SM 4500-S2D-2011 Pace Analytical Services -Asheville ND ug/L 100 50.0 1 07/22/20 22:36 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 Pace Analytical Services -Asheville ND ug/L 1000 500 1 07/22/20 08:14 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 88 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: MW-12 Parameters Lab ID: 92486704005 Collected: Report Results Units Limit 07/17/20 08:20 MDL DF Received: 07/17/20 12:16 Matrix: Water Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 177 ug/L 40.0 10.0 1 07/18/20 15:04 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 81100 ug/L 5000 2500 5 07/27/20 20:32 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Pace Analytical Services -Asheville Chemical Oxygen Demand ND ug/L 25000 12500 1 07/23/20 17:10 07/24/20 15:37 531013 TOC Analytical Method: SM 531 OB-2011 Pace Analytical Services -Asheville Total Organic Carbon 4030 ug/L 1000 500 1 07/24/20 06:38 7440-44-0 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 89 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: EB Lab ID: 92486704006 Collected: 07/17/20 09:18 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Pace Analytical Services -Asheville Antimony ND ug/L 5.0 3.0 1 07/25/20 02:10 07/26/20 20:44 7440-36-0 Arsenic ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:44 7440-38-2 Barium ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:44 7440-39-3 Beryllium ND ug/L 1.0 0.70 1 07/25/20 02:10 07/26/20 20:44 7440-41-7 Cadmium 1.6 ug/L 1.0 0.40 1 07/25/20 02:10 07/26/20 20:44 7440-43-9 Chromium ND ug/L 5.0 3.7 1 07/25/20 02:10 07/26/20 20:44 7440-47-3 Cobalt ND ug/L 5.0 3.6 1 07/25/20 02:10 07/26/20 20:44 7440-48-4 Copper ND ug/L 5.0 4.3 1 07/25/20 02:10 07/26/20 20:44 7440-50-8 Lead ND ug/L 5.0 4.5 1 07/25/20 02:10 07/26/20 20:44 7439-92-1 Nickel ND ug/L 5.0 3.5 1 07/25/20 02:10 07/26/20 20:44 7440-02-0 Selenium ND ug/L 10.0 4.7 1 07/25/20 02:10 07/26/20 20:44 7782-49-2 Silver ND ug/L 5.0 2.5 1 07/25/20 02:10 07/26/20 20:44 7440-22-4 Vanadium ND ug/L 5.0 3.9 1 07/25/20 02:10 07/26/20 20:44 7440-62-2 Zinc ND ug/L 10.0 9.5 1 07/25/20 02:10 07/26/20 20:44 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Pace Analytical Services -Asheville Thallium ND ug/L 0.10 0.050 1 07/25/20 01:24 07/27/20 23:27 7440-28-0 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Acetone ND ug/L 25.0 6.2 1 07/24/20 20:03 67-64-1 Acrylonitrile ND ug/L 10.0 0.90 1 07/24/20 20:03 107-13-1 Benzene ND ug/L 1.0 0.15 1 07/24/20 20:03 71-43-2 Bromochloromethane ND ug/L 1.0 0.34 1 07/24/20 20:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.26 1 07/24/20 20:03 75-27-4 Bromoform ND ug/L 1.0 0.62 1 07/24/20 20:03 75-25-2 Bromomethane ND ug/L 2.0 0.62 1 07/24/20 20:03 74-83-9 2-Butanone (MEK) ND ug/L 5.0 3.3 1 07/24/20 20:03 78-93-3 Carbon disulfide ND ug/L 2.0 0.40 1 07/24/20 20:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.22 1 07/24/20 20:03 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 07/24/20 20:03 108-90-7 Chloroethane ND ug/L 1.0 0.49 1 07/24/20 20:03 75-00-3 Chloroform ND ug/L 5.0 2.3 1 07/24/20 20:03 67-66-3 Chloromethane ND ug/L 1.0 0.39 1 07/24/20 20:03 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 5.0 0.26 1 07/24/20 20:03 96-12-8 Dibromochloromethane ND ug/L 1.0 0.41 1 07/24/20 20:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.26 1 07/24/20 20:03 106-93-4 Dibromomethane ND ug/L 1.0 0.46 1 07/24/20 20:03 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.29 1 07/24/20 20:03 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.26 1 07/24/20 20:03 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 0.54 1 07/24/20 20:03 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.27 1 07/24/20 20:03 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.34 1 07/24/20 20:03 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.24 1 07/24/20 20:03 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: EB Lab ID: 92486704006 Collected: 07/17/20 09:18 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 1.0 0.29 1 07/24/20 20:03 156-59-2 ND ug/L 1.0 0.25 1 07/24/20 20:03 156-60-5 ND ug/L 1.0 0.19 1 07/24/20 20:03 78-87-5 ND ug/L 1.0 0.30 1 07/24/20 20:03 10061-01-5 ND ug/L 1.0 0.31 1 07/24/20 20:03 10061-02-6 ND ug/L 150 56.2 1 07/24/20 20:03 123-91-1 ND ug/L 1.0 0.26 1 07/24/20 20:03 100-41-4 ND ug/L 5.0 0.57 1 07/24/20 20:03 591-78-6 ND ug/L 20.0 12.5 1 07/24/20 20:03 74-88-4 IL ND ug/L 5.0 3.7 1 07/24/20 20:03 75-09-2 ND ug/L 5.0 4.5 1 07/24/20 20:03 108-10-1 ND ug/L 1.0 0.27 1 07/24/20 20:03 100-42-5 ND ug/L 1.0 0.34 1 07/24/20 20:03 630-20-6 ND ug/L 1.0 0.22 1 07/24/20 20:03 79-34-5 ND ug/L 1.0 0.16 1 07/24/20 20:03 127-18-4 ND ug/L 1.0 0.24 1 07/24/20 20:03 108-88-3 ND ug/L 1.0 0.18 1 07/24/20 20:03 71-55-6 ND ug/L 1.0 0.24 1 07/24/20 20:03 79-00-5 ND ug/L 1.0 0.22 1 07/24/20 20:03 79-01-6 ND ug/L 1.0 0.31 1 07/24/20 20:03 75-69-4 ND ug/L 1.0 0.35 1 07/24/20 20:03 96-18-4 ND ug/L 2.0 1.4 1 07/24/20 20:03 108-05-4 ND ug/L 1.0 0.24 1 07/24/20 20:03 75-01-4 ND ug/L 1.0 0.63 1 07/24/20 20:03 1330-20-7 101 % 70-130 1 07/24/20 20:03 460-00-4 98 % 70-130 1 07/24/20 20:03 17060-07-0 100 % 70-130 1 07/24/20 20:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 91 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: FB Lab ID: 92486704007 Collected: 07/17/20 09:23 Received: 07/17/20 12:16 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 07/30/2020 05:17 PM Analytical Method: EPA 8260D Pace Analytical Services - Charlotte ND ug/L 25.0 6.2 1 07/25/20 07:27 67-64-1 ND ug/L 10.0 0.90 1 07/25/20 07:27 107-13-1 ND ug/L 1.0 0.15 1 07/25/20 07:27 71-43-2 ND ug/L 1.0 0.34 1 07/25/20 07:27 74-97-5 ND ug/L 1.0 0.26 1 07/25/20 07:27 75-27-4 ND ug/L 1.0 0.62 1 07/25/20 07:27 75-25-2 ND ug/L 2.0 0.62 1 07/25/20 07:27 74-83-9 ND ug/L 5.0 3.3 1 07/25/20 07:27 78-93-3 ND ug/L 2.0 0.40 1 07/25/20 07:27 75-15-0 ND ug/L 1.0 0.22 1 07/25/20 07:27 56-23-5 ND ug/L 1.0 0.23 1 07/25/20 07:27 108-90-7 ND ug/L 1.0 0.49 1 07/25/20 07:27 75-00-3 ND ug/L 5.0 2.3 1 07/25/20 07:27 67-66-3 ND ug/L 1.0 0.39 1 07/25/20 07:27 74-87-3 ND ug/L 5.0 0.26 1 07/25/20 07:27 96-12-8 ND ug/L 1.0 0.41 1 07/25/20 07:27 124-48-1 ND ug/L 1.0 0.26 1 07/25/20 07:27 106-93-4 ND ug/L 1.0 0.46 1 07/25/20 07:27 74-95-3 ND ug/L 1.0 0.29 1 07/25/20 07:27 95-50-1 ND ug/L 1.0 0.26 1 07/25/20 07:27 106-46-7 ND ug/L 1.0 0.54 1 07/25/20 07:27 110-57-6 ND ug/L 1.0 0.27 1 07/25/20 07:27 75-34-3 ND ug/L 1.0 0.34 1 07/25/20 07:27 107-06-2 ND ug/L 1.0 0.24 1 07/25/20 07:27 75-35-4 ND ug/L 1.0 0.29 1 07/25/20 07:27 156-59-2 ND ug/L 1.0 0.25 1 07/25/20 07:27 156-60-5 ND ug/L 1.0 0.19 1 07/25/20 07:27 78-87-5 ND ug/L 1.0 0.30 1 07/25/20 07:27 10061-01-5 ND ug/L 1.0 0.31 1 07/25/20 07:27 10061-02-6 ND ug/L 150 56.2 1 07/25/20 07:27 123-91-1 ND ug/L 1.0 0.26 1 07/25/20 07:27 100-41-4 ND ug/L 5.0 0.57 1 07/25/20 07:27 591-78-6 ND ug/L 20.0 12.5 1 07/25/20 07:27 74-88-4 ND ug/L 5.0 3.7 1 07/25/20 07:27 75-09-2 ND ug/L 5.0 4.5 1 07/25/20 07:27 108-10-1 ND ug/L 1.0 0.27 1 07/25/20 07:27 100-42-5 ND ug/L 1.0 0.34 1 07/25/20 07:27 630-20-6 ND ug/L 1.0 0.22 1 07/25/20 07:27 79-34-5 ND ug/L 1.0 0.16 1 07/25/20 07:27 127-18-4 ND ug/L 1.0 0.24 1 07/25/20 07:27 108-88-3 ND ug/L 1.0 0.18 1 07/25/20 07:27 71-55-6 ND ug/L 1.0 0.24 1 07/25/20 07:27 79-00-5 ND ug/L 1.0 0.22 1 07/25/20 07:27 79-01-6 ND ug/L 1.0 0.31 1 07/25/20 07:27 75-69-4 ND ug/L 1.0 0.35 1 07/25/20 07:27 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 92 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF - SWS Pace Project No.: 92486765 Sample: FB Parameters Lab ID: Results 92486704007 Units Collected: Report Limit 07/17/20 09:23 MDL DF Received: 07/17/20 12:16 Matrix: Water Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Pace Analytical Services - Charlotte Vinyl acetate ND ug/L 2.0 1.4 1 07/25/20 07:27 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 07/25/20 07:27 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 07/25/20 07:27 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 07/25/20 07:27 460-00-4 1,2-Dichloroethane-d4 (S) 92 % 70-130 1 07/25/20 07:27 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 07/25/20 07:27 2037-26-5 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 93 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554237 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486765026, 92486765027 METHOD BLANK: 2944736 Matrix: Water Associated Lab Samples: 92486765026, 92486765027 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 3.4 07/18/2012:46 LABORATORY CONTROL SAMPLE: 2944737 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Methane ug/L 396 379 96 70-130 MATRIX SPIKE SAMPLE: 2944739 92486624002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Methane ug/L 21.6 396 386 92 70-130 SAMPLE DUPLICATE: 2944738 92486624001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 10.7 10.7 0 20 SAMPLE DUPLICATE: 2944740 92486722013 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554744 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765011, 92486765027 METHOD BLANK: 2946986 Matrix: Water Associated Lab Samples: 92486765011, 92486765027 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 07/22/2013:54 LABORATORY CONTROL SAMPLE: 2946987 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2946988 2946989 MS MSD 92486836012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 3.0 2.9 120 118 75-125 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555776 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007, 92486765008, 92486765009, 92486765010,92486765011,92486765012,92486765013 METHOD BLANK: 2951812 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007, 92486765008, 92486765009, 92486765010,92486765011,92486765012,92486765013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 07/26/20 20:06 Arsenic ug/L ND 10.0 4.7 07/26/20 20:06 Barium ug/L ND 5.0 3.5 07/26/20 20:06 Beryllium ug/L ND 1.0 0.70 07/26/20 20:06 Cadmium ug/L ND 1.0 0.40 07/26/20 20:06 Chromium ug/L ND 5.0 3.7 07/26/20 20:06 Cobalt ug/L ND 5.0 3.6 07/26/20 20:06 Copper ug/L ND 5.0 4.3 07/26/20 20:06 Lead ug/L ND 5.0 4.5 07/26/20 20:06 Nickel ug/L ND 5.0 3.5 07/26/20 20:06 Selenium ug/L ND 10.0 4.7 07/26/20 20:06 Silver ug/L ND 5.0 2.5 07/26/20 20:06 Vanadium ug/L ND 5.0 3.9 07/26/20 20:06 Zinc ug/L ND 10.0 9.5 07/26/20 20:06 LABORATORY CONTROL SAMPLE: Parameter 2951813 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 461 92 80-120 Arsenic ug/L 500 471 94 80-120 Barium ug/L 500 481 96 80-120 Beryllium ug/L 500 476 95 80-120 Cadmium ug/L 500 467 93 80-120 Chromium ug/L 500 473 95 80-120 Cobalt ug/L 500 471 94 80-120 Copper ug/L 500 490 98 80-120 Lead ug/L 500 472 94 80-120 Nickel ug/L 500 471 94 80-120 Selenium ug/L 500 469 94 80-120 Silver ug/L 250 229 92 80-120 Vanadium ug/L 500 467 93 80-120 Zinc ug/L 500 435 87 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Alexander LF - SWS 92486765 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951814 2951815 MS MSD 92486704001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 482 473 96 95 75-125 2 20 Arsenic ug/L ND 500 500 499 501 99 100 75-125 0 20 Barium ug/L 172 500 500 674 663 100 98 75-125 2 20 Beryllium ug/L ND 500 500 497 484 99 97 75-125 3 20 Cadmium ug/L ND 500 500 498 489 100 98 75-125 2 20 Chromium ug/L ND 500 500 471 459 94 92 75-125 3 20 Cobalt ug/L 123 500 500 611 595 98 94 75-125 3 20 Copper ug/L 7.5 500 500 512 506 101 100 75-125 1 20 Lead ug/L ND 500 500 480 468 96 94 75-125 3 20 Nickel ug/L 13.1 500 500 494 483 96 94 75-125 2 20 Selenium ug/L 5.3J 500 500 512 506 101 100 75-125 1 20 Silver ug/L ND 250 250 246 239 98 96 75-125 3 20 Vanadium ug/L ND 500 500 478 462 96 92 75-125 4 20 Zinc ug/L 25.4 500 500 491 476 93 90 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555777 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765014, 92486765015, 92486765016, 92486765017, 92486765018, 92486765019, 92486765020, 92486765021,92486765022,92486765023,92486765024,92486765025,92486765026,92486765027, 92486765028,92486765029,92486765030 METHOD BLANK: 2951816 Matrix: Water Associated Lab Samples: 92486765014, 92486765015, 92486765016, 92486765017, 92486765018, 92486765019, 92486765020, 92486765021,92486765022,92486765023,92486765024,92486765025,92486765026,92486765027, 92486765028,92486765029,92486765030 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 07/26/20 21:52 Arsenic ug/L ND 10.0 4.7 07/26/20 21:52 Barium ug/L ND 5.0 3.5 07/26/20 21:52 Beryllium ug/L ND 1.0 0.70 07/26/20 21:52 Cadmium ug/L ND 1.0 0.40 07/26/20 21:52 Chromium ug/L ND 5.0 3.7 07/26/20 21:52 Cobalt ug/L ND 5.0 3.6 07/26/20 21:52 Copper ug/L ND 5.0 4.3 07/26/20 21:52 Lead ug/L ND 5.0 4.5 07/26/20 21:52 Nickel ug/L ND 5.0 3.5 07/26/20 21:52 Selenium ug/L ND 10.0 4.7 07/26/20 21:52 Silver ug/L ND 5.0 2.5 07/26/20 21:52 Vanadium ug/L ND 5.0 3.9 07/26/20 21:52 Zinc ug/L ND 10.0 9.5 07/26/20 21:52 LABORATORY CONTROL SAMPLE: Parameter 2951817 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 491 98 80-120 Arsenic ug/L 500 485 97 80-120 Barium ug/L 500 505 101 80-120 Beryllium ug/L 500 499 100 80-120 Cadmium ug/L 500 491 98 80-120 Chromium ug/L 500 491 98 80-120 Cobalt ug/L 500 495 99 80-120 Copper ug/L 500 503 101 80-120 Lead ug/L 500 490 98 80-120 Nickel ug/L 500 498 100 80-120 Selenium ug/L 500 486 97 80-120 Silver ug/L 250 243 97 80-120 Vanadium ug/L 500 490 98 80-120 Zinc ug/L 500 482 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Alexander LF - SWS 92486765 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951818 2951819 MS MSD 92486765014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 496 513 99 103 75-125 3 20 Arsenic ug/L ND 500 500 510 511 102 102 75-125 0 20 Barium ug/L 20.9 500 500 524 528 101 101 75-125 1 20 Beryllium ug/L ND 500 500 502 516 100 103 75-125 3 20 Cadmium ug/L 3.5 500 500 507 496 101 99 75-125 2 20 Chromium ug/L ND 500 500 505 499 101 100 75-125 1 20 Cobalt ug/L ND 500 500 491 500 98 100 75-125 2 20 Copper ug/L ND 500 500 516 508 103 101 75-125 1 20 Lead ug/L ND 500 500 488 492 98 98 75-125 1 20 Nickel ug/L ND 500 500 493 500 98 100 75-125 1 20 Selenium ug/L ND 500 500 516 514 103 103 75-125 0 20 Silver ug/L ND 250 250 247 248 99 99 75-125 0 20 Vanadium ug/L ND 500 500 503 506 100 101 75-125 1 20 Zinc ug/L ND 500 500 468 491 93 98 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555779 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007, 92486765008, 92486765009, 92486765010,92486765011 METHOD BLANK: 2951824 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007, 92486765008, 92486765009, 92486765010,92486765011 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 07/27/20 21:12 LABORATORY CONTROL SAMPLE: 2951825 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.3 103 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951826 2951827 MS MSD 92486704002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.15 10 10 10.9 10.9 108 107 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555780 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765012, 92486765013, 92486765014, 92486765015, 92486765016, 92486765017, 92486765018, 92486765019,92486765020,92486765021,92486765022,92486765023,92486765024,92486765025, 92486765026,92486765027,92486765028,92486765029,92486765030 METHOD BLANK: 2951828 Matrix: Water Associated Lab Samples: 92486765012, 92486765013, 92486765014, 92486765015, 92486765016, 92486765017, 92486765018, 92486765019,92486765020,92486765021,92486765022,92486765023,92486765024,92486765025, 92486765026,92486765027,92486765028,92486765029,92486765030 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.050 07/28/20 07:55 LABORATORY CONTROL SAMPLE: 2951829 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951830 2951831 MS MSD 92486765012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.051J 10 10 10.3 10.6 103 106 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554968 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486765001, 92486765009, 92486765010 METHOD BLANK: 2947888 Matrix: Associated Lab Samples: 92486765001, 92486765009, 92486765010 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/24/20 05:38 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/24/20 05:38 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/24/20 05:38 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/24/20 05:38 1,1-Dichloroethane ug/L ND 1.0 0.27 07/24/20 05:38 1,1-Dichloroethene ug/L ND 1.0 0.24 07/24/20 05:38 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/24/20 05:38 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/24/20 05:38 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/24/20 05:38 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/24/20 05:38 1,2-Dichloroethane ug/L ND 1.0 0.34 07/24/20 05:38 1,2-Dichloropropane ug/L ND 1.0 0.19 07/24/20 05:38 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/24/20 05:38 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/24/20 05:38 2-Butanone (MEK) ug/L ND 5.0 3.3 07/24/20 05:38 2-Hexanone ug/L ND 5.0 0.57 07/24/20 05:38 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/24/20 05:38 Acetone ug/L ND 25.0 6.2 07/24/20 05:38 Acrylonitrile ug/L ND 10.0 0.90 07/24/20 05:38 Benzene ug/L ND 1.0 0.15 07/24/20 05:38 Bromochloromethane ug/L ND 1.0 0.34 07/24/20 05:38 Bromodichloromethane ug/L ND 1.0 0.26 07/24/20 05:38 Bromoform ug/L ND 1.0 0.62 07/24/20 05:38 Bromomethane ug/L ND 2.0 0.62 07/24/20 05:38 Carbon disulfide ug/L ND 2.0 0.40 07/24/20 05:38 Carbon tetrachloride ug/L ND 1.0 0.22 07/24/20 05:38 Chlorobenzene ug/L ND 1.0 0.23 07/24/20 05:38 Chloroethane ug/L ND 1.0 0.49 07/24/20 05:38 Chloroform ug/L ND 5.0 2.3 07/24/20 05:38 Chloromethane ug/L ND 1.0 0.39 07/24/20 05:38 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/24/20 05:38 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/24/20 05:38 Dibromochloromethane ug/L ND 1.0 0.41 07/24/20 05:38 Dibromomethane ug/L ND 1.0 0.46 07/24/20 05:38 Ethylbenzene ug/L ND 1.0 0.26 07/24/20 05:38 lodomethane ug/L ND 20.0 12.5 07/24/20 05:38 Methylene Chloride ug/L ND 5.0 3.7 07/24/20 05:38 Styrene ug/L ND 1.0 0.27 07/24/20 05:38 Tetrachloroethene ug/L ND 1.0 0.16 07/24/20 05:38 Toluene ug/L ND 1.0 0.24 07/24/20 05:38 Qualifiers v1 I K,v2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 METHOD BLANK: 2947888 Matrix: Water Associated Lab Samples: 92486765001, 92486765009, 92486765010 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/24/20 05:38 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/24/20 05:38 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/24/20 05:38 Trichloroethene ug/L ND 1.0 0.22 07/24/20 05:38 Trichlorofluoromethane ug/L ND 1.0 0.31 07/24/20 05:38 Vinyl acetate ug/L ND 2.0 1.4 07/24/20 05:38 v1 Vinyl chloride ug/L ND 1.0 0.24 07/24/20 05:38 Xylene (Total) ug/L ND 1.0 0.63 07/24/20 05:38 1,2-Dichloroethane-d4 (S) % 102 70-130 07/24/20 05:38 4-Bromofluorobenzene (S) % 102 70-130 07/24/20 05:38 Toluene-d8 (S) % 104 70-130 07/24/20 05:38 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 42.9 86 70-130 1,1,1-Trichloroethane ug/L 50 47.0 94 70-130 1,1,2,2-Tetrachloroethane ug/L 50 45.8 92 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 47.7 95 70-130 1,1-Dichloroethene ug/L 50 48.2 96 70-130 1,2,3-Trichloropropane ug/L 50 47.1 94 70-130 1,2-Dibromo-3-chloropropane ug/L 50 46.1 92 70-130 1,2-Dibromoethane (EDB) ug/L 50 44.8 90 70-130 1,2-Dichlorobenzene ug/L 50 46.5 93 70-130 1,2-Dichloroethane ug/L 50 45.6 91 70-130 1,2-Dichloropropane ug/L 50 49.3 99 70-130 1,4-Dichlorobenzene ug/L 50 46.1 92 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1210 121 59-169 2-Butanone (MEK) ug/L 100 96.2 96 64-135 2-Hexanone ug/L 100 94.5 95 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.9 94 70-130 Acetone ug/L 100 118 118 61-157 v1 Acrylonitrile ug/L 250 247 99 61-143 Benzene ug/L 50 45.7 91 70-130 Bromochloromethane ug/L 50 47.7 95 70-130 Bromodichloromethane ug/L 50 43.8 88 70-130 Bromoform ug/L 50 42.6 85 70-130 Bromomethane ug/L 50 60.9 122 38-130lK,v3 Carbon disulfide ug/L 50 49.7 99 68-130 Carbon tetrachloride ug/L 50 47.3 95 70-130 Chlorobenzene ug/L 50 43.0 86 70-130 Chloroethane ug/L 50 38.0 76 37-142 Chloroform ug/L 50 46.8 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 155 Pace Analytical Services, LLC 9800 lCtaac,Analyfical ® Kiney Ave. Suite 100 Huntersville, NC 28078 0788 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 LABORATORY CONTROL SAMPLE: Parameter 2947889 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Chloromethane ug/L 50 39.2 78 48-130 cis-1,2-Dichloroethene ug/L 50 47.6 95 70-130 cis-1,3-Dichloropropene ug/L 50 48.2 96 70-130 Dibromochloromethane ug/L 50 43.8 88 70-130 Dibromomethane ug/L 50 46.7 93 70-130 Ethylbenzene ug/L 50 43.2 86 70-130 lodomethane ug/L 100 73.2 73 40-130 Methylene Chloride ug/L 50 46.5 93 67-132 Styrene ug/L 50 42.8 86 70-130 Tetrachloroethene ug/L 50 43.2 86 69-130 Toluene ug/L 50 44.9 90 70-130 trans-1,2-Dichloroethene ug/L 50 45.9 92 70-130 trans- 1,3-Dichloropropene ug/L 50 43.5 87 70-130 trans-1,4-Dichloro-2-butene ug/L 50 39.7 79 35-189 Trichloroethene ug/L 50 46.9 94 70-130 Trichlorofluoromethane ug/L 50 43.7 87 63-130 Vinyl acetate ug/L 100 106 106 55-143 v1 Vinyl chloride ug/L 50 49.8 100 70-131 Xylene (Total) ug/L 150 130 87 70-130 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE SAMPLE: Parameter 2947890 Units 92486757025 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 18.1 91 73-134 1,1,1-Trichloroethane ug/L ND 20 20.4 102 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 18.8 94 70-136 1,1,2-Trichloroethane ug/L ND 20 20.0 100 70-135 1,1-Dichloroethane ug/L ND 20 20.5 103 70-139 1,1-Dichloroethene ug/L ND 20 23.2 116 70-154 1,2,3-Trichloropropane ug/L ND 20 18.4 92 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 16.9 85 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 18.9 94 70-137 1,2-Dichlorobenzene ug/L ND 20 18.8 94 70-133 1,2-Dichloroethane ug/L ND 20 19.6 98 70-137 1,2-Dichloropropane ug/L ND 20 20.8 104 70-140 1,4-Dichlorobenzene ug/L ND 20 18.6 93 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 466 117 53-168 2-Butanone (MEK) ug/L ND 40 38.7 97 60-139 2-Hexanone ug/L ND 40 37.5 94 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 36.5 91 65-135 Acetone ug/L ND 40 46.9 117 60-148 v1 Acrylonitrile ug/L ND 100 93.4 93 64-147 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 MATRIX SPIKE SAMPLE: 2947890 92486757025 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Benzene ug/L ND 20 20.2 101 70-151 Bromochloromethane ug/L ND 20 20.6 103 70-141 Bromodichloromethane ug/L ND 20 17.9 90 70-138 Bromoform ug/L ND 20 16.3 82 63-130 Bromomethane ug/L ND 20 24.8 124 15-152 IK,v3 Carbon disulfide ug/L ND 20 22.4 112 69-149 Carbon tetrachloride ug/L ND 20 19.8 99 70-143 Chlorobenzene ug/L ND 20 19.1 96 70-138 Chloroethane ug/L ND 20 17.4 87 52-163 Chloroform ug/L ND 20 21.9 109 70-139 Chloromethane ug/L ND 20 16.0 80 41-139 cis-1,2-Dichloroethene ug/L ND 20 21.1 106 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.9 104 70-137 Dibromochloromethane ug/L ND 20 17.2 86 70-134 Dibromomethane ug/L ND 20 20.1 101 70-138 Ethylbenzene ug/L ND 20 19.3 97 66-153 Iodomethane ug/L ND 40 19.2J 48 20-138 Methylene Chloride ug/L ND 20 20.9 104 42-159 Styrene ug/L ND 20 19.1 96 70-135 Tetrachloroethene ug/L ND 20 19.7 98 59-143 Toluene ug/L ND 20 19.4 97 59-148 trans-1,2-Dichloroethene ug/L ND 20 21.0 105 70-146 trans- 1,3-Dichloropropene ug/L ND 20 18.8 94 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 16.2 81 47-135 Trichloroethene ug/L ND 20 20.9 104 70-147 Trichlorofluoromethane ug/L ND 20 19.6 98 70-148 Vinyl acetate ug/L ND 40 42.4 106 49-151 v1 Vinyl chloride ug/L ND 20 20.7 104 70-156 Xylene (Total) ug/L ND 60 56.5 94 63-158 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 103 70-130 SAMPLE DUPLICATE: 2947891 92486757026 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 SAMPLE DUPLICATE: 2947891 Parameter Units 92486757026 Result Dup Result RPD Max RPD Qualifiers 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 v1 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 301K,v2 Carbon disulfide ug/L ND 2.5 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 v1 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 104 99 4-Bromofluorobenzene (S) % 100 100 Toluene-d8 (S) % 102 102 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555217 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486765011,92486765012,92486765013,92486765014,92486765015,92486765016,92486765017, 92486765018,92486765019,92486765020,92486765021,92486765026,92486765027,92486765028 METHOD BLANK: 2949021 Matrix: Water Associated Lab Samples: 92486765011,92486765012,92486765013,92486765014,92486765015,92486765016,92486765017, 92486765018,92486765019,92486765020,92486765021,92486765026,92486765027,92486765028 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/25/20 06:50 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/25/20 06:50 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/25/20 06:50 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/25/20 06:50 1,1-Dichloroethane ug/L ND 1.0 0.27 07/25/20 06:50 1,1-Dichloroethene ug/L ND 1.0 0.24 07/25/20 06:50 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/25/20 06:50 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/25/20 06:50 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/25/20 06:50 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/25/20 06:50 1,2-Dichloroethane ug/L ND 1.0 0.34 07/25/20 06:50 1,2-Dichloropropane ug/L ND 1.0 0.19 07/25/20 06:50 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/25/20 06:50 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/25/20 06:50 2-Butanone (MEK) ug/L ND 5.0 3.3 07/25/20 06:50 2-Hexanone ug/L ND 5.0 0.57 07/25/20 06:50 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/25/20 06:50 Acetone ug/L ND 25.0 6.2 07/25/20 06:50 Acrylonitrile ug/L ND 10.0 0.90 07/25/20 06:50 Benzene ug/L ND 1.0 0.15 07/25/20 06:50 Bromochloromethane ug/L ND 1.0 0.34 07/25/20 06:50 Bromodichloromethane ug/L ND 1.0 0.26 07/25/20 06:50 Bromoform ug/L ND 1.0 0.62 07/25/20 06:50 Bromomethane ug/L ND 2.0 0.62 07/25/20 06:50 Carbon disulfide ug/L ND 2.0 0.40 07/25/20 06:50 Carbon tetrachloride ug/L ND 1.0 0.22 07/25/20 06:50 Chlorobenzene ug/L ND 1.0 0.23 07/25/20 06:50 Chloroethane ug/L ND 1.0 0.49 07/25/20 06:50 Chloroform ug/L ND 5.0 2.3 07/25/20 06:50 Chloromethane ug/L ND 1.0 0.39 07/25/20 06:50 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/25/20 06:50 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/25/20 06:50 Dibromochloromethane ug/L ND 1.0 0.41 07/25/20 06:50 Dibromomethane ug/L ND 1.0 0.46 07/25/20 06:50 Ethylbenzene ug/L ND 1.0 0.26 07/25/20 06:50 lodomethane ug/L ND 20.0 12.5 07/25/20 06:50 Methylene Chloride ug/L ND 5.0 3.7 07/25/20 06:50 Styrene ug/L ND 1.0 0.27 07/25/20 06:50 Tetrachloroethene ug/L ND 1.0 0.16 07/25/20 06:50 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 METHOD BLANK: 2949021 Matrix: Water Associated Lab Samples: 92486765011,92486765012,92486765013,92486765014,92486765015,92486765016,92486765017, 92486765018,92486765019,92486765020,92486765021,92486765026,92486765027,92486765028 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 07/25/20 06:50 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/25/20 06:50 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/25/20 06:50 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/25/20 06:50 v2 Trichloroethene ug/L ND 1.0 0.22 07/25/20 06:50 Trichlorofluoromethane ug/L ND 1.0 0.31 07/25/20 06:50 Vinyl acetate ug/L ND 2.0 1.4 07/25/20 06:50 Vinyl chloride ug/L ND 1.0 0.24 07/25/20 06:50 Xylene (Total) ug/L ND 1.0 0.63 07/25/20 06:50 1,2-Dichloroethane-d4 (S) % 92 70-130 07/25/20 06:50 4-Bromofluorobenzene (S) % 104 70-130 07/25/20 06:50 Toluene-d8 (S) % 102 70-130 07/25/20 06:50 LABORATORY CONTROL SAMPLE: Parameter 2949022 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 50.8 102 70-130 1,1,1-Trichloroethane ug/L 50 50.2 100 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.5 99 70-130 1,1,2-Trichloroethane ug/L 50 53.5 107 70-130 1,1-Dichloroethane ug/L 50 49.9 100 70-130 1,1-Dichloroethene ug/L 50 52.0 104 70-130 1,2,3-Trichloropropane ug/L 50 48.0 96 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.5 103 70-130 1,2-Dibromoethane (EDB) ug/L 50 54.7 109 70-130 1,2-Dichlorobenzene ug/L 50 53.3 107 70-130 1,2-Dichloroethane ug/L 50 48.7 97 70-130 1,2-Dichloropropane ug/L 50 55.0 110 70-130 1,4-Dichlorobenzene ug/L 50 53.0 106 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1050 105 59-169 2-Butanone (MEK) ug/L 100 106 106 64-135 2-Hexanone ug/L 100 102 102 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 98.2 98 70-130 Acetone ug/L 100 98.9 99 61-157 Acrylonitrile ug/L 250 261 104 61-143 Benzene ug/L 50 52.2 104 70-130 Bromochloromethane ug/L 50 52.4 105 70-130 Bromodichloromethane ug/L 50 51.4 103 70-130 Bromoform ug/L 50 51.7 103 70-130 Bromomethane ug/L 50 46.6 93 38-130 Carbon disulfide ug/L 50 46.3 93 68-130 Carbon tetrachloride ug/L 50 53.9 108 70-130 Chlorobenzene ug/L 50 50.7 101 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 LABORATORY CONTROL SAMPLE: Parameter 2949022 Units Spike LCS Conc. Result Chloroethane ug/L 50 Chloroform ug/L 50 Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 45.7 91 37-142 48.8 98 70-130 42.6 85 48-130 49.0 98 70-130 55.3 111 70-130 55.0 110 70-130 54.8 110 70-130 51.1 102 70-130 89.3 89 40-130 50.8 102 67-132 54.1 108 70-130 51.0 102 69-130 48.7 97 70-130 50.4 101 70-130 51.7 103 70-130 39.6 79 35-189 v3 54.9 110 70-130 44.6 89 63-130 98.8 99 55-143 51.3 103 70-131 156 104 70-130 94 70-130 99 70-130 98 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949023 MS 92486993006 Spike Parameter Units Result Conc. MSD Spike Conc. 2949024 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 11.8 18.5 59 93 73-134 45 30 M1,R1 1,1,1-Trichloroethane ug/L ND 20 20 13.4 20.3 67 102 82-143 41 30 M1,R1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 10.8 16.7 54 84 70-136 42 30 M1,R1 1,1,2-Trichloroethane ug/L ND 20 20 11.8 18.0 59 90 70-135 41 30 M1,R1 1,1-Dichloroethane ug/L ND 20 20 12.7 18.6 63 93 70-139 38 30 M1,R1 1,1-Dichloroethene ug/L ND 20 20 13.2 19.2 66 96 70-154 37 30 M1,R1 1,2,3-Trichloropropane ug/L ND 20 20 11.2 17.5 56 87 71-137 44 30 M1,R1 1,2-Dibromo-3- ug/L ND 20 20 12.0 18.8 60 94 65-134 44 30 M1,R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 11.7 17.5 59 88 70-137 40 30 M1,R1 1,2-Dichlorobenzene ug/L ND 20 20 11.1 17.3 55 86 70-133 44 30 M1,R1 1,2-Dichloroethane ug/L ND 20 20 13.3 19.6 66 98 70-137 38 30 M1,R1 1,2-Dichloropropane ug/L ND 20 20 11.6 17.6 58 88 70-140 41 30 M1,R1 1,4-Dichlorobenzene ug/L ND 20 20 11.2 16.8 56 84 70-133 40 30 M1,R1 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 251 335 63 84 53-168 28 30 2-Butanone (MEK) ug/L ND 40 40 23.7 36.4 59 91 60-139 42 30 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949023 2949024 MS MSD 92486993006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2-Hexanone ug/L ND 40 40 22.6 34.7 57 87 65-138 42 30 M1,R1 4-Methyl-2-pentanone ug/L ND 40 40 22.8 34.4 57 86 65-135 41 30 M1,R1 (MIBK) Acetone ug/L ND 40 40 27.1 39.3 68 98 60-148 37 30 R1 Acrylonitrile ug/L ND 100 100 62.6 92.8 63 93 64-147 39 30 M1,R1 Benzene ug/L ND 20 20 11.7 17.4 59 87 70-151 39 30 M1,R1 Bromochloromethane ug/L ND 20 20 12.5 19.0 63 95 70-141 41 30 M1,R1 Bromodichloromethane ug/L ND 20 20 11.1 17.4 56 87 70-138 44 30 M1,R1 Bromoform ug/L ND 20 20 11.3 18.1 56 90 63-130 46 30 M1,R1 Bromomethane ug/L ND 20 20 14.3 20.4 71 102 15-152 36 30 R1 Carbon disulfide ug/L ND 20 20 12.1 17.7 61 88 69-149 37 30 M1,R1 Carbon tetrachloride ug/L ND 20 20 13.2 19.4 66 97 70-143 38 30 M1,R1 Chlorobenzene ug/L ND 20 20 11.4 17.0 57 85 70-138 39 30 M1,R1 Chloroethane ug/L ND 20 20 16.4 24.4 82 122 52-163 39 30 IK,R1 Chloroform ug/L ND 20 20 12.9 19.6 65 98 70-139 41 30 M1,R1 Chloromethane ug/L ND 20 20 10.3 15.2 52 76 41-139 38 30 R1,v3 cis-1,2-Dichloroethene ug/L ND 20 20 12.5 18.3 63 92 70-141 38 30 M1,R1 cis-1,3-Dichloropropene ug/L ND 20 20 12.5 19.1 63 95 70-137 42 30 M1,R1 Dibromochloromethane ug/L ND 20 20 12.0 18.4 60 92 70-134 42 30 M1,R1 Dibromomethane ug/L ND 20 20 12.1 18.4 61 92 70-138 41 30 M1,R1 Ethylbenzene ug/L ND 20 20 11.6 17.1 58 85 66-153 38 30 M1,R1 lodomethane ug/L ND 40 40 21.0 34.0 52 85 20-138 48 30 R1 Methylene Chloride ug/L ND 20 20 12.6 18.5 63 92 42-159 38 30 R1 Styrene ug/L ND 20 20 11.6 17.0 58 85 70-135 38 30 M1,R1 Tetrachloroethene ug/L ND 20 20 11.2 17.5 56 87 59-143 44 30 M1,R1 Toluene ug/L ND 20 20 11.9 17.5 60 88 59-148 38 30 R1 trans-1,2-Dichloroethene ug/L ND 20 20 13.3 19.2 66 96 70-146 36 30 M1,R1 trans-1,3-Dichloropropene ug/L ND 20 20 12.3 18.6 62 93 70-135 40 30 M1,R1 trans-1,4-Dichloro-2-butene ug/L ND 20 20 9.1 13.9 45 69 47-135 42 30 M1,R1 Trichloroethene ug/L ND 20 20 12.0 18.3 60 91 70-147 41 30 M1,R1 Trichlorofluoromethane ug/L ND 20 20 13.3 19.5 66 97 70-148 38 30 M1,R1 Vinyl acetate ug/L ND 40 40 24.1 36.3 60 91 49-151 40 30 R1 Vinyl chloride ug/L ND 20 20 11.1 16.0 55 80 70-156 37 30 M1,R1 Xylene (Total) ug/L ND 60 60 34.7 51.4 58 86 63-158 39 30 MS,RS 1,2-Dichloroethane-d4 (S) % 113 113 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 99 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555554 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006 METHOD BLANK: 2950518 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/24/20 19:09 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/24/20 19:09 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/24/20 19:09 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/24/20 19:09 1,1-Dichloroethane ug/L ND 1.0 0.27 07/24/20 19:09 1,1-Dichloroethene ug/L ND 1.0 0.24 07/24/20 19:09 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/24/20 19:09 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/24/20 19:09 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/24/20 19:09 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/24/20 19:09 1,2-Dichloroethane ug/L ND 1.0 0.34 07/24/20 19:09 1,2-Dichloropropane ug/L ND 1.0 0.19 07/24/20 19:09 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/24/20 19:09 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/24/20 19:09 2-Butanone (MEK) ug/L ND 5.0 3.3 07/24/20 19:09 2-Hexanone ug/L ND 5.0 0.57 07/24/20 19:09 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/24/20 19:09 Acetone ug/L ND 25.0 6.2 07/24/20 19:09 Acrylonitrile ug/L ND 10.0 0.90 07/24/20 19:09 Benzene ug/L ND 1.0 0.15 07/24/20 19:09 Bromochloromethane ug/L ND 1.0 0.34 07/24/20 19:09 Bromodichloromethane ug/L ND 1.0 0.26 07/24/20 19:09 Bromoform ug/L ND 1.0 0.62 07/24/20 19:09 Bromomethane ug/L ND 2.0 0.62 07/24/20 19:09 Carbon disulfide ug/L ND 2.0 0.40 07/24/20 19:09 Carbon tetrachloride ug/L ND 1.0 0.22 07/24/20 19:09 Chlorobenzene ug/L ND 1.0 0.23 07/24/20 19:09 Chloroethane ug/L ND 1.0 0.49 07/24/20 19:09 Chloroform ug/L ND 5.0 2.3 07/24/20 19:09 Chloromethane ug/L ND 1.0 0.39 07/24/20 19:09 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/24/20 19:09 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/24/20 19:09 Dibromochloromethane ug/L ND 1.0 0.41 07/24/20 19:09 Dibromomethane ug/L ND 1.0 0.46 07/24/20 19:09 Ethylbenzene ug/L ND 1.0 0.26 07/24/20 19:09 lodomethane ug/L ND 20.0 12.5 07/24/20 19:09 IL Methylene Chloride ug/L ND 5.0 3.7 07/24/20 19:09 Styrene ug/L ND 1.0 0.27 07/24/20 19:09 Tetrachloroethene ug/L ND 1.0 0.16 07/24/20 19:09 Toluene ug/L ND 1.0 0.24 07/24/20 19:09 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 METHOD BLANK: 2950518 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486704006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/24/20 19:09 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/24/20 19:09 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/24/20 19:09 Trichloroethene ug/L ND 1.0 0.22 07/24/20 19:09 Trichlorofluoromethane ug/L ND 1.0 0.31 07/24/20 19:09 Vinyl acetate ug/L ND 2.0 1.4 07/24/20 19:09 Vinyl chloride ug/L ND 1.0 0.24 07/24/20 19:09 Xylene (Total) ug/L ND 1.0 0.63 07/24/20 19:09 1,2-Dichloroethane-d4 (S) % 99 70-130 07/24/20 19:09 4-Bromofluorobenzene (S) % 100 70-130 07/24/20 19:09 Toluene-d8 (S) % 99 70-130 07/24/20 19:09 LABORATORY CONTROL SAMPLE: 2950519 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.5 101 70-130 1,1,1-Trichloroethane ug/L 50 48.8 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.3 101 70-130 1,1,2-Trichloroethane ug/L 50 50.5 101 70-130 1,1-Dichloroethane ug/L 50 47.9 96 70-130 1,1-Dichloroethene ug/L 50 48.1 96 70-130 1,2,3-Trichloropropane ug/L 50 49.5 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 56.2 112 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.7 103 70-130 1,2-Dichlorobenzene ug/L 50 51.5 103 70-130 1,2-Dichloroethane ug/L 50 48.1 96 70-130 1,2-Dichloropropane ug/L 50 48.7 97 70-130 1,4-Dichlorobenzene ug/L 50 50.4 101 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1060 106 59-169 2-Butanone (MEK) ug/L 100 92.9 93 64-135 2-Hexanone ug/L 100 108 108 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 70-130 Acetone ug/L 100 101 101 61-157 Acrylonitrile ug/L 250 226 90 61-143 Benzene ug/L 50 48.3 97 70-130 Bromochloromethane ug/L 50 50.1 100 70-130 Bromodichloromethane ug/L 50 47.2 94 70-130 Bromoform ug/L 50 52.4 105 70-130 Bromomethane ug/L 50 52.8 106 38-130 Carbon disulfide ug/L 50 43.9 88 68-130 Carbon tetrachloride ug/L 50 49.7 99 70-130 Chlorobenzene ug/L 50 48.5 97 70-130 Chloroethane ug/L 50 41.3 83 37-142 Chloroform ug/L 50 47.7 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 LABORATORY CONTROL SAMPLE: Parameter 2950519 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 40.3 81 48-130 47.9 96 70-130 52.0 104 70-130 52.4 105 70-130 51.8 104 70-130 48.0 96 70-130 84.1 84 40-130IL 46.3 93 67-132 52.0 104 70-130 49.8 100 69-130 47.2 94 70-130 49.0 98 70-130 50.5 101 70-130 53.3 107 35-189 50.1 100 70-130 45.5 91 63-130 103 103 55-143 47.0 94 70-131 147 98 70-130 93 70-130 100 70-130 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2950520 MS 92486993012 Spike Parameter Units Result Conc. MSD Spike Conc. 2950521 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 20.4 20.2 102 101 73-134 1 30 1,1,1-Trichloroethane ug/L ND 20 20 21.0 20.7 105 104 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 18.5 18.6 93 93 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 19.8 19.3 99 97 70-135 2 30 1,1-Dichloroethane ug/L ND 20 20 20.2 20.4 101 102 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 21.7 21.5 108 108 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 18.9 19.1 95 96 71-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 20.9 19.7 104 99 65-134 6 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 20.0 20.1 100 100 70-137 0 30 1,2-Dichlorobenzene ug/L ND 20 20 20.7 20.6 104 103 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 18.7 19.1 94 95 70-137 2 30 1,2-Dichloropropane ug/L ND 20 20 20.3 20.2 101 101 70-140 0 30 1,4-Dichlorobenzene ug/L ND 20 20 20.6 20.3 103 101 70-133 2 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 403 376 101 94 53-168 7 30 2-Butanone (MEK) ug/L ND 40 40 33.6 32.2 84 80 60-139 4 30 2-Hexanone ug/L ND 40 40 38.7 36.3 97 91 65-138 6 30 4-Methyl-2-pentanone ug/L ND 40 40 37.8 36.7 94 92 65-135 3 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2950520 2950521 MS MSD 92486993012 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 40 40 35.4 34.8 88 87 60-148 2 30 Acrylonitrile ug/L ND 100 100 91.0 90.2 91 90 64-147 1 30 Benzene ug/L ND 20 20 20.8 20.7 104 103 70-151 1 30 Bromochloromethane ug/L ND 20 20 20.9 21.5 104 108 70-141 3 30 Bromodichloromethane ug/L ND 20 20 18.4 18.2 92 91 70-138 1 30 Bromoform ug/L ND 20 20 19.1 18.8 96 94 63-130 2 30 Bromomethane ug/L ND 20 20 21.4 21.6 107 108 15-152 1 30 Carbon disulfide ug/L ND 20 20 20.5 20.6 103 103 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 21.1 21.0 106 105 70-143 0 30 Chlorobenzene ug/L ND 20 20 20.4 20.2 102 101 70-138 1 30 Chloroethane ug/L ND 20 20 21.6 22.2 108 111 52-163 3 30 Chloroform ug/L ND 20 20 20.0 20.6 100 103 70-139 3 30 Chloromethane ug/L ND 20 20 17.6 17.6 88 88 41-139 0 30 v3 cis-1,2-Dichloroethene ug/L ND 20 20 19.9 20.7 100 104 70-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.2 20.6 106 103 70-137 2 30 Dibromochloromethane ug/L ND 20 20 20.3 20.0 101 100 70-134 1 30 Dibromomethane ug/L ND 20 20 20.9 20.6 105 103 70-138 2 30 Ethylbenzene ug/L ND 20 20 20.5 20.6 103 103 66-153 0 30 lodomethane ug/L ND 40 40 38.1 40.0 95 100 20-138 5 30 IL Methylene Chloride ug/L ND 20 20 19.5 19.9 98 100 42-159 2 30 Styrene ug/L ND 20 20 21.0 21.1 105 105 70-135 1 30 Tetrachloroethene ug/L ND 20 20 20.9 20.7 104 104 59-143 1 30 Toluene ug/L ND 20 20 20.2 20.0 101 100 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.0 21.7 105 109 70-146 4 30 trans-1,3-Dichloropropene ug/L ND 20 20 20.2 20.0 101 100 70-135 1 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 16.9 16.1 84 81 47-135 5 30 Trichloroethene ug/L ND 20 20 21.3 20.9 107 105 70-147 2 30 Trichlorofluoromethane ug/L ND 20 20 19.8 20.1 99 101 70-148 2 30 Vinyl acetate ug/L ND 40 40 38.0 37.6 95 94 49-151 1 30 Vinyl chloride ug/L ND 20 20 18.7 19.5 93 97 70-156 4 30 Xylene (Total) ug/L ND 60 60 62.4 62.6 104 104 63-158 0 30 1,2-Dichloroethane-d4 (S) % 97 95 70-130 4-Bromofluorobenzene (S) % 100 101 70-130 Toluene-d8 (S) % 98 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555728 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486704007,92486765004,92486765006,92486765008,92486765022,92486765023,92486765024, 92486765025 METHOD BLANK: 2951427 Matrix: Water Associated Lab Samples: 92486704007, 92486765004, 92486765006, 92486765008, 92486765022, 92486765023, 92486765024, 92486765025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/25/20 07:08 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/25/20 07:08 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/25/20 07:08 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/25/20 07:08 1,1-Dichloroethane ug/L ND 1.0 0.27 07/25/20 07:08 1,1-Dichloroethene ug/L ND 1.0 0.24 07/25/20 07:08 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/25/20 07:08 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/25/20 07:08 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/25/20 07:08 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/25/20 07:08 1,2-Dichloroethane ug/L ND 1.0 0.34 07/25/20 07:08 1,2-Dichloropropane ug/L ND 1.0 0.19 07/25/20 07:08 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/25/20 07:08 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/25/20 07:08 2-Butanone (MEK) ug/L ND 5.0 3.3 07/25/20 07:08 2-Hexanone ug/L ND 5.0 0.57 07/25/20 07:08 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/25/20 07:08 Acetone ug/L ND 25.0 6.2 07/25/20 07:08 Acrylonitrile ug/L ND 10.0 0.90 07/25/20 07:08 Benzene ug/L ND 1.0 0.15 07/25/20 07:08 Bromochloromethane ug/L ND 1.0 0.34 07/25/20 07:08 Bromodichloromethane ug/L ND 1.0 0.26 07/25/20 07:08 Bromoform ug/L ND 1.0 0.62 07/25/20 07:08 Bromomethane ug/L ND 2.0 0.62 07/25/20 07:08 Carbon disulfide ug/L ND 2.0 0.40 07/25/20 07:08 Carbon tetrachloride ug/L ND 1.0 0.22 07/25/20 07:08 Chlorobenzene ug/L ND 1.0 0.23 07/25/20 07:08 Chloroethane ug/L ND 1.0 0.49 07/25/20 07:08 Chloroform ug/L ND 5.0 2.3 07/25/20 07:08 Chloromethane ug/L ND 1.0 0.39 07/25/20 07:08 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/25/20 07:08 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/25/20 07:08 Dibromochloromethane ug/L ND 1.0 0.41 07/25/20 07:08 Dibromomethane ug/L ND 1.0 0.46 07/25/20 07:08 Ethylbenzene ug/L ND 1.0 0.26 07/25/20 07:08 lodomethane ug/L ND 20.0 12.5 07/25/20 07:08 Methylene Chloride ug/L ND 5.0 3.7 07/25/20 07:08 Styrene ug/L ND 1.0 0.27 07/25/20 07:08 Tetrachloroethene ug/L ND 1.0 0.16 07/25/20 07:08 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 115 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 METHOD BLANK: 2951427 Matrix: Water Associated Lab Samples: 92486704007,92486765004,92486765006,92486765008,92486765022,92486765023,92486765024, 92486765025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.24 07/25/20 07:08 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/25/20 07:08 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/25/20 07:08 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/25/20 07:08 v2 Trichloroethene ug/L ND 1.0 0.22 07/25/20 07:08 Trichlorofluoromethane ug/L ND 1.0 0.31 07/25/20 07:08 Vinyl acetate ug/L ND 2.0 1.4 07/25/20 07:08 Vinyl chloride ug/L ND 1.0 0.24 07/25/20 07:08 Xylene (Total) ug/L ND 1.0 0.63 07/25/20 07:08 1,2-Dichloroethane-d4 (S) % 91 70-130 07/25/20 07:08 4-Bromofluorobenzene (S) % 105 70-130 07/25/20 07:08 Toluene-d8 (S) % 104 70-130 07/25/20 07:08 LABORATORY CONTROL SAMPLE: Parameter 2951428 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.1 106 70-130 1,1,1-Trichloroethane ug/L 50 50.5 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.8 102 70-130 1,1,2-Trichloroethane ug/L 50 53.9 108 70-130 1,1-Dichloroethane ug/L 50 50.8 102 70-130 1,1-Dichloroethene ug/L 50 52.0 104 70-130 1,2,3-Trichloropropane ug/L 50 49.5 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.2 104 70-130 1,2-Dibromoethane (EDB) ug/L 50 56.3 113 70-130 1,2-Dichlorobenzene ug/L 50 53.9 108 70-130 1,2-Dichloroethane ug/L 50 49.9 100 70-130 1,2-Dichloropropane ug/L 50 56.1 112 70-130 1,4-Dichlorobenzene ug/L 50 53.4 107 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1040 104 59-169 2-Butanone (MEK) ug/L 100 110 110 64-135 2-Hexanone ug/L 100 105 105 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 100 100 70-130 Acetone ug/L 100 102 102 61-157 Acrylonitrile ug/L 250 264 106 61-143 Benzene ug/L 50 52.0 104 70-130 Bromochloromethane ug/L 50 53.3 107 70-130 Bromodichloromethane ug/L 50 51.2 102 70-130 Bromoform ug/L 50 53.5 107 70-130 Bromomethane ug/L 50 40.6 81 38-130 Carbon disulfide ug/L 50 47.6 95 68-130 Carbon tetrachloride ug/L 50 54.4 109 70-130 Chlorobenzene ug/L 50 52.6 105 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 116 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 LABORATORY CONTROL SAMPLE: Parameter 2951428 Units Spike LCS Conc. Result Chloroethane ug/L 50 Chloroform ug/L 50 Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits Qualifiers 47.4 95 37-142 50.1 100 70-130 42.5 85 48-130 49.8 100 70-130 55.8 112 70-130 56.8 114 70-130 55.1 110 70-130 52.2 104 70-130 86.9 87 40-130 51.5 103 67-132 56.3 113 70-130 52.1 104 69-130 49.2 98 70-130 51.5 103 70-130 51.7 103 70-130 39.2 78 35-189 v3 54.8 110 70-130 46.0 92 63-130 101 101 55-143 51.9 104 70-131 158 106 70-130 98 70-130 101 70-130 98 70-130 MATRIX SPIKE SAMPLE: Parameter 2951429 Units 92486765023 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 16.7 83 73-134 1,1,1-Trichloroethane ug/L ND 20 19.6 98 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 15.7 79 70-136 1,1,2-Trichloroethane ug/L ND 20 16.7 83 70-135 1,1-Dichloroethane ug/L ND 20 18.2 91 70-139 1,1-Dichloroethene ug/L ND 20 18.8 94 70-154 1,2,3-Trichloropropane ug/L ND 20 16.3 81 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 16.8 84 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 17.5 88 70-137 1,2-Dichlorobenzene ug/L ND 20 15.6 78 70-133 1,2-Dichloroethane ug/L ND 20 18.5 92 70-137 1,2-Dichloropropane ug/L ND 20 16.3 82 70-140 1,4-Dichlorobenzene ug/L ND 20 15.9 79 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 318 80 53-168 2-Butanone (MEK) ug/L ND 40 34.6 86 60-139 2-Hexanone ug/L ND 40 32.2 81 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 33.0 82 65-135 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 117 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 MATRIX SPIKE SAMPLE: Parameter 2951429 Units 92486765023 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Acetone ug/L ND 40 38.0 95 60-148 Acrylonitrile ug/L ND 100 86.0 86 64-147 Benzene ug/L ND 20 16.8 84 70-151 Bromochloromethane ug/L ND 20 17.5 87 70-141 Bromodichloromethane ug/L ND 20 16.5 82 70-138 Bromoform ug/L ND 20 16.7 84 63-130 Bromomethane ug/L ND 20 18.9 94 15-152 Carbon disulfide ug/L ND 20 17.1 85 69-149 Carbon tetrachloride ug/L ND 20 19.1 96 70-143 Chlorobenzene ug/L ND 20 16.3 82 70-138 Chloroethane ug/L ND 20 23.2 116 52-1631K Chloroform ug/L ND 20 18.2 91 70-139 Chloromethane ug/L ND 20 14.5 73 41-139 v3 cis-1,2-Dichloroethene ug/L ND 20 17.8 89 70-141 cis-1,3-Dichloropropene ug/L ND 20 17.7 88 70-137 Dibromochloromethane ug/L ND 20 16.4 82 70-134 Dibromomethane ug/L ND 20 17.2 86 70-138 Ethylbenzene ug/L ND 20 16.6 83 66-153 lodomethane ug/L ND 40 31.1 78 20-138 Methylene Chloride ug/L ND 20 18.2 91 42-159 Styrene ug/L ND 20 15.7 79 70-135 Tetrachloroethene ug/L ND 20 16.8 84 59-143 Toluene ug/L ND 20 16.8 84 59-148 trans-1,2-Dichloroethene ug/L ND 20 18.2 91 70-146 trans- 1,3-Dichloropropene ug/L ND 20 17.7 89 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 14.1 71 47-135 Trichloroethene ug/L ND 20 17.8 89 70-147 Trichlorofluoromethane ug/L ND 20 19.2 96 70-148 Vinyl acetate ug/L ND 40 33.9 85 49-151 Vinyl chloride ug/L ND 20 15.8 79 70-156 Xylene (Total) ug/L ND 60 50.0 83 63-158 1,2-Dichloroethane-d4 (S) % 115 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8(S) % 101 70-130 SAMPLE DUPLICATE: 2951430 92486765025 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 118 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 SAMPLE DUPLICATE: 2951430 Parameter Units 92486765025 Result Dup Result RPD Max RPD 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 301K Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 v2 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 92 109 4-Bromofluorobenzene (S) % 103 97 Toluene-d8 (S) % 104 101 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 119 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555748 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92486765003, 92486765005, 92486765007, 92486765029, 92486765030 METHOD BLANK: 2951628 Matrix: Water Associated Lab Samples: 92486765003, 92486765005, 92486765007, 92486765029, 92486765030 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 07/25/20 06:21 1,1,1-Trichloroethane ug/L ND 1.0 0.18 07/25/20 06:21 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 07/25/20 06:21 1,1,2-Trichloroethane ug/L ND 1.0 0.24 07/25/20 06:21 1,1-Dichloroethane ug/L ND 1.0 0.27 07/25/20 06:21 1,1-Dichloroethene ug/L ND 1.0 0.24 07/25/20 06:21 1,2,3-Trichloropropane ug/L ND 1.0 0.35 07/25/20 06:21 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 07/25/20 06:21 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 07/25/20 06:21 1,2-Dichlorobenzene ug/L ND 1.0 0.29 07/25/20 06:21 1,2-Dichloroethane ug/L ND 1.0 0.34 07/25/20 06:21 1,2-Dichloropropane ug/L ND 1.0 0.19 07/25/20 06:21 1,4-Dichlorobenzene ug/L ND 1.0 0.26 07/25/20 06:21 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 07/25/20 06:21 2-Butanone (MEK) ug/L ND 5.0 3.3 07/25/20 06:21 2-Hexanone ug/L ND 5.0 0.57 07/25/20 06:21 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 07/25/20 06:21 Acetone ug/L ND 25.0 6.2 07/25/20 06:21 Acrylonitrile ug/L ND 10.0 0.90 07/25/20 06:21 Benzene ug/L ND 1.0 0.15 07/25/20 06:21 Bromochloromethane ug/L ND 1.0 0.34 07/25/20 06:21 Bromodichloromethane ug/L ND 1.0 0.26 07/25/20 06:21 Bromoform ug/L ND 1.0 0.62 07/25/20 06:21 Bromomethane ug/L ND 2.0 0.62 07/25/20 06:21 Carbon disulfide ug/L ND 2.0 0.40 07/25/20 06:21 Carbon tetrachloride ug/L ND 1.0 0.22 07/25/20 06:21 Chlorobenzene ug/L ND 1.0 0.23 07/25/20 06:21 Chloroethane ug/L ND 1.0 0.49 07/25/20 06:21 Chloroform ug/L ND 5.0 2.3 07/25/20 06:21 Chloromethane ug/L ND 1.0 0.39 07/25/20 06:21 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 07/25/20 06:21 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 07/25/20 06:21 Dibromochloromethane ug/L ND 1.0 0.41 07/25/20 06:21 Dibromomethane ug/L ND 1.0 0.46 07/25/20 06:21 Ethylbenzene ug/L ND 1.0 0.26 07/25/20 06:21 lodomethane ug/L ND 20.0 12.5 07/25/20 06:21 Methylene Chloride ug/L ND 5.0 3.7 07/25/20 06:21 Styrene ug/L ND 1.0 0.27 07/25/20 06:21 Tetrachloroethene ug/L ND 1.0 0.16 07/25/20 06:21 Toluene ug/L ND 1.0 0.24 07/25/20 06:21 Qualifiers IK,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 120 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 METHOD BLANK: 2951628 Matrix: Water Associated Lab Samples: 92486765003, 92486765005, 92486765007, 92486765029, 92486765030 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,2-Dichloroethene ug/L ND 1.0 0.25 07/25/20 06:21 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 07/25/20 06:21 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 07/25/20 06:21 Trichloroethene ug/L ND 1.0 0.22 07/25/20 06:21 Trichlorofluoromethane ug/L ND 1.0 0.31 07/25/20 06:21 Vinyl acetate ug/L ND 2.0 1.4 07/25/20 06:21 Vinyl chloride ug/L ND 1.0 0.24 07/25/20 06:21 Xylene (Total) ug/L ND 1.0 0.63 07/25/20 06:21 1,2-Dichloroethane-d4 (S) % 102 70-130 07/25/20 06:21 4-Bromofluorobenzene (S) % 98 70-130 07/25/20 06:21 Toluene-d8 (S) % 101 70-130 07/25/20 06:21 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130 1,1,1-Trichloroethane ug/L 50 53.0 106 70-130 1,1,2,2-Tetrachloroethane ug/L 50 46.5 93 70-130 1,1,2-Trichloroethane ug/L 50 49.4 99 70-130 1,1-Dichloroethane ug/L 50 47.4 95 70-130 1,1-Dichloroethene ug/L 50 48.4 97 70-130 1,2,3-Trichloropropane ug/L 50 46.3 93 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.6 103 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.3 101 70-130 1,2-Dichlorobenzene ug/L 50 48.8 98 70-130 1,2-Dichloroethane ug/L 50 51.1 102 70-130 1,2-Dichloropropane ug/L 50 47.6 95 70-130 1,4-Dichlorobenzene ug/L 50 48.8 98 70-130 1,4-Dioxane (p-Dioxane) ug/L 1000 920 92 59-169 2-Butanone (MEK) ug/L 100 93.0 93 64-135 2-Hexanone ug/L 100 91.0 91 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 90.3 90 70-130 Acetone ug/L 100 100 100 61-157 Acrylonitrile ug/L 250 235 94 61-143 Benzene ug/L 50 47.5 95 70-130 Bromochloromethane ug/L 50 50.2 100 70-130 Bromodichloromethane ug/L 50 50.0 100 70-130 Bromoform ug/L 50 52.1 104 70-130 Bromomethane ug/L 50 71.6 143 38-130 L1 Carbon disulfide ug/L 50 45.4 91 68-130 Carbon tetrachloride ug/L 50 52.5 105 70-130 Chlorobenzene ug/L 50 47.3 95 70-130 Chloroethane ug/L 50 49.0 98 37-142 IK,v1 Chloroform ug/L 50 49.6 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 121 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 LABORATORY CONTROL SAMPLE: Parameter 2951629 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 Methylene Chloride ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 50 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 100 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits 40.3 81 48-130 48.5 97 70-130 50.5 101 70-130 53.8 108 70-130 49.8 100 70-130 47.3 95 70-130 101 101 40-130 47.1 94 67-132 49.2 98 70-130 47.5 95 69-130 46.3 93 70-130 50.1 100 70-130 50.1 100 70-130 41.5 83 35-189 48.4 97 70-130 47.6 95 63-130 99.6 100 55-143 46.7 93 70-131 144 96 70-130 102 70-130 102 70-130 95 70-130 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951630 MS 92486765003 Spike Parameter Units Result Conc. MSD Spike Conc. 2951631 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 14.3 15.5 71 77 73-134 8 30 M1 1,1,1-Trichloroethane ug/L ND 20 20 16.2 16.8 81 84 82-143 4 30 M1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 13.1 14.1 65 71 70-136 7 30 M1 1,1,2-Trichloroethane ug/L ND 20 20 14.5 14.8 72 74 70-135 2 30 1,1-Dichloroethane ug/L ND 20 20 15.3 16.1 76 80 70-139 5 30 1,1-Dichloroethene ug/L ND 20 20 15.9 16.9 79 84 70-154 6 30 1,2,3-Trichloropropane ug/L ND 20 20 14.0 14.2 70 71 71-137 1 30 M1 1,2-Dibromo-3- ug/L ND 20 20 14.8 15.8 74 79 65-134 7 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 14.1 15.0 71 75 70-137 6 30 1,2-Dichlorobenzene ug/L ND 20 20 13.8 14.0 69 70 70-133 2 30 M1 1,2-Dichloroethane ug/L ND 20 20 15.6 16.5 78 82 70-137 5 30 1,2-Dichloropropane ug/L ND 20 20 14.3 14.9 72 74 70-140 4 30 1,4-Dichlorobenzene ug/L 0.45J 20 20 14.1 14.4 68 70 70-133 2 30 M1 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 276 290 69 73 53-168 5 30 2-Butanone (MEK) ug/L ND 40 40 28.1 32.3 70 81 60-139 14 30 2-Hexanone ug/L ND 40 40 26.9 27.9 67 70 65-138 4 30 4-Methyl-2-pentanone ug/L ND 40 40 27.6 28.3 69 71 65-135 2 30 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 122 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2951630 2951631 MS MSD 92486765003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L 12.6J 40 40 43.4 44.8 77 81 60-148 3 30 Acrylonitrile ug/L ND 100 100 73.2 78.0 73 78 64-147 6 30 Benzene ug/L 0.32J 20 20 14.4 15.1 70 74 70-151 5 30 Bromochloromethane ug/L ND 20 20 14.8 15.9 74 79 70-141 7 30 Bromodichloromethane ug/L ND 20 20 14.0 14.1 70 71 70-138 1 30 Bromoform ug/L ND 20 20 14.0 14.8 70 74 63-130 6 30 Bromomethane ug/L ND 20 20 16.9 17.8 85 89 15-152 5 30 Carbon disulfide ug/L ND 20 20 14.2 15.2 71 76 69-149 7 30 Carbon tetrachloride ug/L ND 20 20 15.7 16.6 79 83 70-143 5 30 Chlorobenzene ug/L ND 20 20 14.0 14.7 70 73 70-138 5 30 Chloroethane ug/L ND 20 20 19.4 20.6 97 103 52-163 6 30 IK Chloroform ug/L ND 20 20 15.6 16.5 78 82 70-139 5 30 Chloromethane ug/L ND 20 20 12.3 12.7 61 64 41-139 4 30 v3 cis-1,2-Dichloroethene ug/L 2.4 20 20 17.2 17.9 74 77 70-141 4 30 cis-1,3-Dichloropropene ug/L ND 20 20 15.1 15.8 76 79 70-137 4 30 Dibromochloromethane ug/L ND 20 20 15.0 15.4 75 77 70-134 2 30 Dibromomethane ug/L ND 20 20 15.2 15.4 76 77 70-138 1 30 Ethylbenzene ug/L ND 20 20 14.1 14.6 70 73 66-153 4 30 lodomethane ug/L ND 40 40 24.6 26.1 62 65 20-138 6 30 Methylene Chloride ug/L ND 20 20 15.0 15.8 75 79 42-159 5 30 Styrene ug/L ND 20 20 5.5 5.1 28 26 70-135 7 30 M1 Tetrachloroethene ug/L ND 20 20 14.5 15.5 72 78 59-143 7 30 Toluene ug/L ND 20 20 14.4 14.7 72 74 59-148 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 15.6 16.6 78 83 70-146 6 30 trans-1,3-Dichloropropene ug/L ND 20 20 14.9 15.6 75 78 70-135 4 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 13.1 11.9 66 60 47-135 10 30 Trichloroethene ug/L ND 20 20 14.7 15.5 74 78 70-147 5 30 Trichlorofluoromethane ug/L ND 20 20 15.9 16.9 79 85 70-148 7 30 Vinyl acetate ug/L ND 40 40 19.1 19.5 48 49 49-151 2 30 M1 Vinyl chloride ug/L ND 20 20 12.8 14.0 64 70 70-156 8 30 M1 Xylene (Total) ug/L ND 60 60 42.0 44.0 70 73 63-158 5 30 MS 1,2-Dichloroethane-d4 (S) % 108 109 70-130 4-Bromofluorobenzene (S) % 100 101 70-130 Toluene-d8 (S) % 99 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554930 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004 METHOD BLANK: 2947675 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 07/22/20 13:58 LABORATORY CONTROL SAMPLE: 2947676 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 51100 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2947677 2947678 MS MSD 92487100001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 68.0 mg/L 50000 50000 121000 117000 106 98 80-120 3 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2947679 2947680 MS MSD 92486127019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L ND 50000 50000 48800 48600 98 97 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 124 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555277 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765005, 92486765006, 92486765007 METHOD BLANK: 2949267 Matrix: Water Associated Lab Samples: 92486765005, 92486765006, 92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 07/23/20 12:20 LABORATORY CONTROL SAMPLE: 2949268 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 46100 92 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949269 2949270 MS MSD 92487370005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 25.8 mg/L 50000 50000 74200 74800 97 98 80-120 1 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949271 2949272 MS MSD 92486765006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 39200 50000 50000 96500 94700 114 111 80-120 2 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 125 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554687 Analysis Method: SM 3500-Fe B-2011 QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003 METHOD BLANK: 2946575 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron, Ferrous mg/L ND 0.50 0.084 07/21/20 14:35 N2 LABORATORY CONTROL SAMPLE: 2946576 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron, Ferrous mg/L 1.5 1.5 101 90-110 N2 SAMPLE DUPLICATE: 2946577 92486344001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L ND ND 10 H3,N2 SAMPLE DUPLICATE: 2946578 92486344002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L ND ND 10 H3,N2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 126 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554689 Analysis Method: SM 3500-Fe B-2011 QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765004, 92486765005, 92486765006, 92486765007 METHOD BLANK: 2946579 Matrix: Water Associated Lab Samples: 92486765004, 92486765005, 92486765006, 92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron, Ferrous mg/L ND 0.50 0.084 07/21/20 15:09 N2 LABORATORY CONTROL SAMPLE: 2946580 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron, Ferrous mg/L 1.5 1.5 102 90-110 N2 SAMPLE DUPLICATE: 2946581 92486765004 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L 1.3 1.3 1 10 H3,N2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 127 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555070 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765001 METHOD BLANK: 2948466 Matrix: Water Associated Lab Samples: 92486765001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 07/22/20 21:53 LABORATORY CONTROL SAMPLE: 2948467 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 474 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2948468 2948469 MS MSD 92486757003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 218 233 44 47 80-120 7 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2948470 2948471 MS MSD 92486757004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 212 225 35 37 80-120 6 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 128 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555071 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765003, 92486765004, 92486765005,92486765006,92486765007 METHOD BLANK: 2948473 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765003, 92486765004, 92486765005,92486765006,92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 07/22/20 22:28 LABORATORY CONTROL SAMPLE: 2948474 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 521 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2948475 2948476 MS MSD 92486765003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 98.3J 105 18 19 80-120 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2948477 2948478 MS MSD 92486765004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L 70.7J 500 500 380 394 62 65 80-120 4 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 129 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554618 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 METHOD BLANK: 2946214 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 07/22/20 04:44 LABORATORY CONTROL SAMPLE: 2946215 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 49100 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2946216 2946217 MS MSD 92486722014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 4.4 mg/L 50000 50000 54000 54200 99 100 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2946218 2946219 MS MSD 92486765003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 4770 50000 50000 54600 54500 100 99 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 130 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554202 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486765002, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007 METHOD BLANK: 2944594 Matrix: Water Associated Lab Samples: 92486765002, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 07/18/20 01:07 LABORATORY CONTROL SAMPLE: 2944595 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1590 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2944598 2944599 MS MSD 92486765007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 837 822 56 55 90-110 2 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 131 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554236 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005 METHOD BLANK: 2944729 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 07/18/20 14:58 LABORATORY CONTROL SAMPLE: 2944730 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1540 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2944731 2944732 MS MSD 92486704001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 591 584 39 39 90-110 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 132 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 556027 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 METHOD BLANK: 2952895 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 07/27/2019:45 LABORATORY CONTROL SAMPLE: 2952896 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 20800 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2952897 2952898 MS MSD 92487550002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 119 mg/L 10000 10000 124000 123000 51 43 90-110 1 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2952899 2952900 MS MSD 92486704001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 104000 10000 10000 116000 118000 117 140 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 133 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 554475 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004 METHOD BLANK: 2945745 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 07/22/20 15:47 LABORATORY CONTROL SAMPLE: 2945746 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 765000 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2945749 2945750 MS MSD 92486365002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 3130 mg/L 100000 100000 3200000 3200000 70 70 90-110 0 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2947409 2947410 MS MSD 92486724001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 358 mg/L 100000 100000 456000 456000 98 98 90-110 0 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 134 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555408 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704005, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007 METHOD BLANK: 2950012 Matrix: Water Associated Lab Samples: 92486704005, 92486765001, 92486765003, 92486765004, 92486765005, 92486765006, 92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 07/24/20 15:32 LABORATORY CONTROL SAMPLE: 2950013 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 758000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2950014 2950015 MS MSD 92487100002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 114000 121000 97 104 90-110 6 3 R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2950016 2950017 MS MSD 92487100003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 114000 107000 108 101 90-110 6 3 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 135 of 155 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF - SWS Pace Project No.: 92486765 QC Batch: 555247 Analysis Method: SM 531 OB-2011 QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 METHOD BLANK: 2949102 Matrix: Water Associated Lab Samples: 92486704001, 92486704002, 92486704003, 92486704004, 92486704005, 92486765001, 92486765003, 92486765004,92486765005,92486765006,92486765007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Organic Carbon ug/L ND 1000 500 07/24/20 01:21 LABORATORY CONTROL SAMPLE: 2949103 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon ug/L 25000 25400 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949104 2949105 MS MSD 92485528006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L ND 25000 25000 26200 26200 103 103 90-110 0 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2949106 2949107 MS MSD 92485528007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L 0.64J 25000 25000 26900 24800 105 97 90-110 8 10 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 136 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Alexander LF - SWS Pace Project No.: 92486765 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS H3 Sample was received or analysis requested beyond the recognized method holding time. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration. The reported results should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 137 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Alexander LF - SWS Pace Project No.: 92486765 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486765026 MW-1 RSK 175 Modified 554237 92486765027 MWA B RSK 175 Modified 554237 92486704001 MW-11 EPA 3010A 555776 EPA 6010D 555793 92486704002 MW-12D EPA 3010A 555776 EPA 6010D 555793 92486704003 MW-24 EPA 3010A 555776 EPA 6010D 555793 92486704004 MW-25 EPA 3010A 555776 EPA 6010D 555793 92486704005 MW-12 EPA 3010A 555776 EPA 6010D 555793 92486704006 EB EPA 3010A 555776 EPA 6010D 555793 92486765001 MW-6 EPA 3010A 555776 EPA 6010D 555793 92486765003 MW-16 EPA 3010A 555776 EPA 6010D 555793 92486765004 MW-26 EPA 3010A 555776 EPA 6010D 555793 92486765005 MW-27 EPA 3010A 555776 EPA 6010D 555793 92486765006 MW-31 EPA 3010A 555776 EPA 6010D 555793 92486765007 MW-5 EPA 3010A 555776 EPA 6010D 555793 92486765008 MW-10 EPA 3010A 555776 EPA 6010D 555793 92486765009 MW-13 EPA 3010A 555776 EPA 6010D 555793 92486765010 MW-14 EPA 3010A 555776 EPA 6010D 555793 92486765011 MW-15 EPA 3010A 555776 EPA 6010D 555793 92486765012 MW-17 EPA 3010A 555776 EPA 6010D 555793 92486765013 MW-18 EPA 3010A 555776 EPA 6010D 555793 92486765014 MW-19 EPA 3010A 555777 EPA 6010D 555792 92486765015 MW-20 EPA 3010A 555777 EPA 6010D 555792 92486765016 MW-21 EPA 3010A 555777 EPA 6010D 555792 92486765017 MW-22 EPA 3010A 555777 EPA 6010D 555792 92486765018 MW-23 EPA 3010A 555777 EPA 6010D 555792 92486765019 MW-32 EPA 3010A 555777 EPA 6010D 555792 92486765020 MW-33 EPA 3010A 555777 EPA 6010D 555792 92486765021 MW-34 EPA 3010A 555777 EPA 6010D 555792 92486765022 SW-3 EPA 3010A 555777 EPA 6010D 555792 92486765023 SW-4R EPA 3010A 555777 EPA 6010D 555792 92486765024 SW-5 EPA 3010A 555777 EPA 6010D 555792 92486765025 SW-6 EPA 3010A 555777 EPA 6010D 555792 92486765026 MW-1 EPA 3010A 555777 EPA 6010D 555792 92486765027 MWA B EPA 3010A 555777 EPA 6010D 555792 92486765028 MW-2 EPA 3010A 555777 EPA 6010D 555792 92486765029 MW-4R EPA 3010A 555777 EPA 6010D 555792 92486765030 MW-9 EPA 3010A 555777 EPA 6010D 555792 92486704001 MW-11 EPA 3010A 555779 EPA 6020B 555791 92486704002 MW-12D EPA 3010A 555779 EPA 6020B 555791 92486704003 MW-24 EPA 3010A 555779 EPA 6020B 555791 92486704004 MW-25 EPA 3010A 555779 EPA 6020B 555791 92486704005 MW-12 EPA 3010A 555779 EPA 6020B 555791 92486704006 EB EPA 3010A 555779 EPA 6020B 555791 92486765001 MW-6 EPA 3010A 555779 EPA 6020B 555791 92486765003 MW-16 EPA 3010A 555779 EPA 6020B 555791 92486765004 MW-26 EPA 3010A 555779 EPA 6020B 555791 92486765005 MW-27 EPA 3010A 555779 EPA 6020B 555791 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 138 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Alexander LF - SWS 92486765 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486765006 MW-31 EPA 3010A 555779 EPA 6020B 555791 92486765007 MW-5 EPA 3010A 555779 EPA 6020B 555791 92486765008 MW-10 EPA 3010A 555779 EPA 6020B 555791 92486765009 MW-13 EPA 3010A 555779 EPA 6020B 555791 92486765010 MW-14 EPA 3010A 555779 EPA 6020B 555791 92486765011 MW-15 EPA 3010A 555779 EPA 6020B 555791 92486765012 MW-17 EPA 3010A 555780 EPA 6020B 555790 92486765013 MW-18 EPA 3010A 555780 EPA 6020B 555790 92486765014 MW-19 EPA 3010A 555780 EPA 6020B 555790 92486765015 MW-20 EPA 3010A 555780 EPA 6020B 555790 92486765016 MW-21 EPA 3010A 555780 EPA 6020B 555790 92486765017 MW-22 EPA 3010A 555780 EPA 6020B 555790 92486765018 MW-23 EPA 3010A 555780 EPA 6020B 555790 92486765019 MW-32 EPA 3010A 555780 EPA 6020B 555790 92486765020 MW-33 EPA 3010A 555780 EPA 6020B 555790 92486765021 MW-34 EPA 3010A 555780 EPA 6020B 555790 92486765022 SW-3 EPA 3010A 555780 EPA 6020B 555790 92486765023 SW-4R EPA 3010A 555780 EPA 6020B 555790 92486765024 SW-5 EPA 3010A 555780 EPA 6020B 555790 92486765025 SW-6 EPA 3010A 555780 EPA 6020B 555790 92486765026 MW-1 EPA 3010A 555780 EPA 6020B 555790 92486765027 MWA B EPA 3010A 555780 EPA 6020B 555790 92486765028 MW-2 EPA 3010A 555780 EPA 6020B 555790 92486765029 MW-4R EPA 3010A 555780 EPA 6020B 555790 92486765030 MW-9 EPA 3010A 555780 EPA 6020B 555790 92486765011 MW-15 EPA 7470A 554744 EPA 7470A 554811 92486765027 MWA B EPA 7470A 554744 EPA 7470A 554811 92486704001 MW-11 EPA 8260D 555554 92486704002 MW-12D EPA 8260D 555554 92486704003 MW-24 EPA 8260D 555554 92486704004 MW-25 EPA 8260D 555554 92486704005 MW-12 EPA 8260D 555554 92486704006 EB EPA 8260D 555554 92486704007 FB EPA 8260D 555728 92486765001 MW-6 EPA 8260D 554968 92486765003 MW-16 EPA 8260D 555748 92486765004 MW-26 EPA 8260D 555728 92486765005 MW-27 EPA 8260D 555748 92486765006 MW-31 EPA 8260D 555728 92486765007 MW-5 EPA 8260D 555748 92486765008 MW-10 EPA 8260D 555728 92486765009 MW-13 EPA 8260D 554968 92486765010 MW-14 EPA 8260D 554968 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 139 of 155 laceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Alexander LF - SWS Pace Project No.: 92486765 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486765011 MW-15 EPA 8260D 555217 92486765012 MW-17 EPA 8260D 555217 92486765013 MW-18 EPA 8260D 555217 92486765014 MW-19 EPA 8260D 555217 92486765015 MW-20 EPA 8260D 555217 92486765016 MW-21 EPA 8260D 555217 92486765017 MW-22 EPA 8260D 555217 92486765018 MW-23 EPA 8260D 555217 92486765019 MW-32 EPA 8260D 555217 92486765020 MW-33 EPA 8260D 555217 92486765021 MW-34 EPA 8260D 555217 92486765022 SW-3 EPA 8260D 555728 92486765023 SW-4R EPA 8260D 555728 92486765024 SW-5 EPA 8260D 555728 92486765025 SW-6 EPA 8260D 555728 92486765026 MW-1 EPA 8260D 555217 92486765027 MW-1B EPA 8260D 555217 92486765028 MW-2 EPA 8260D 555217 92486765029 MW-4R EPA 8260D 555748 92486765030 MW-9 EPA 8260D 555748 92486704001 MW-11 SM 2320B-2011 554930 92486704002 MW-12D SM 2320B-2011 554930 92486704003 MW-24 SM 2320B-2011 554930 92486704004 MW-25 SM 2320B-2011 554930 92486704005 MW-12 SM 2320B-2011 554930 92486765001 MW-6 SM 2320B-2011 554930 92486765003 MW-16 SM 2320B-2011 554930 92486765004 MW-26 SM 2320B-2011 554930 92486765005 MW-27 SM 2320B-2011 555277 92486765006 MW-31 SM 2320B-2011 555277 92486765007 MW-5 SM 2320B-2011 555277 92486704001 MW-11 SM 3500-Fe B-2011 554687 92486704002 MW-12D SM 3500-Fe B-2011 554687 92486704003 MW-24 SM 3500-Fe B-2011 554687 92486704004 MW-25 SM 3500-Fe B-2011 554687 92486704005 MW-12 SM 3500-Fe B-2011 554687 92486765001 MW-6 SM 3500-Fe B-2011 554687 92486765003 MW-16 SM 3500-Fe B-2011 554687 92486765004 MW-26 SM 3500-Fe B-2011 554689 92486765005 MW-27 SM 3500-Fe B-2011 554689 92486765006 MW-31 SM 3500-Fe B-2011 554689 92486765007 MW-5 SM 3500-Fe B-2011 554689 92486704001 MW-11 SM 4500-S2D-2011 555071 92486704002 MW-12D SM 4500-S2D-2011 555071 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 140 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Alexander LF - SWS 92486765 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486704003 MW-24 SM 4500-S2D-2011 555071 92486704004 MW-25 SM 4500-S2D-2011 555071 92486704005 MW-12 SM 4500-S2D-2011 555071 92486765001 MW-6 SM 4500-S2D-2011 555070 92486765003 MW-16 SM 4500-S2D-2011 555071 92486765004 MW-26 SM 4500-S2D-2011 555071 92486765005 MW-27 SM 4500-S2D-2011 555071 92486765006 MW-31 SM 4500-S2D-2011 555071 92486765007 MW-5 SM 4500-S2D-2011 555071 92486704001 MW-11 EPA 300.0 Rev 2.1 1993 554618 92486704002 MW-12D EPA 300.0 Rev 2.1 1993 554618 92486704003 MW-24 EPA 300.0 Rev 2.1 1993 554618 92486704004 MW-25 EPA 300.0 Rev 2.1 1993 554618 92486704005 MW-12 EPA 300.0 Rev 2.1 1993 554618 92486765001 MW-6 EPA 300.0 Rev 2.1 1993 554618 92486765003 MW-16 EPA 300.0 Rev 2.1 1993 554618 92486765004 MW-26 EPA 300.0 Rev 2.1 1993 554618 92486765005 MW-27 EPA 300.0 Rev 2.1 1993 554618 92486765006 MW-31 EPA 300.0 Rev 2.1 1993 554618 92486765007 MW-5 EPA 300.0 Rev 2.1 1993 554618 92486704001 MW-11 EPA 353.2 Rev 2.0 1993 554236 92486704002 MW-12D EPA 353.2 Rev 2.0 1993 554236 92486704003 MW-24 EPA 353.2 Rev 2.0 1993 554236 92486704004 MW-25 EPA 353.2 Rev 2.0 1993 554236 92486704005 MW-12 EPA 353.2 Rev 2.0 1993 554236 92486765002 MW-6 NITRATE EPA 353.2 Rev 2.0 1993 554202 92486765003 MW-16 EPA 353.2 Rev 2.0 1993 554202 92486765004 MW-26 EPA 353.2 Rev 2.0 1993 554202 92486765005 MW-27 EPA 353.2 Rev 2.0 1993 554202 92486765006 MW-31 EPA 353.2 Rev 2.0 1993 554202 92486765007 MW-5 EPA 353.2 Rev 2.0 1993 554202 92486704001 MW-11 SM 4500-CI-E-2011 556027 92486704002 MW-12D SM 4500-CI-E-2011 556027 92486704003 MW-24 SM 4500-CI-E-2011 556027 92486704004 MW-25 SM 4500-CI-E-2011 556027 92486704005 MW-12 SM 4500-CI-E-2011 556027 92486765001 MW-6 SM 4500-CI-E-2011 556027 92486765003 MW-16 SM 4500-CI-E-2011 556027 92486765004 MW-26 SM 4500-CI-E-2011 556027 92486765005 MW-27 SM 4500-CI-E-2011 556027 92486765006 MW-31 SM 4500-CI-E-2011 556027 92486765007 MW-5 SM 4500-CI-E-2011 556027 92486704001 MW-11 SM 5220D-2011 554475 SM 5220D-2011 555067 92486704002 MW-12D SM 5220D-2011 554475 SM 5220D-2011 555067 92486704003 MW-24 SM 5220D-2011 554475 SM 5220D-2011 555067 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/30/2020 05:17 PM without the written consent of Pace Analytical Services, LLC. Page 141 of 155 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Alexander LF - SWS 92486765 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92486704004 MW-25 SM 5220D-2011 554475 SM 5220D-2011 555067 92486704005 MW-12 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765001 MW-6 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765003 MW-16 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765004 MW-26 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765005 MW-27 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765006 MW-31 SM 5220D-2011 555408 SM 5220D-2011 555712 92486765007 MW-5 SM 5220D-2011 555408 SM 5220D-2011 555712 92486704001 MW-11 SM 5310B-2011 555247 92486704002 MW-12D SM 5310B-2011 555247 92486704003 MW-24 SM 5310B-2011 555247 92486704004 MW-25 SM 5310B-2011 555247 92486704005 MW-12 SM 5310B-2011 555247 92486765001 MW-6 SM 5310B-2011 555247 92486765003 MW-16 SM 5310B-2011 555247 92486765004 MW-26 SM 5310B-2011 555247 92486765005 MW-27 SM 5310B-2011 555247 92486765006 MW-31 SM 5310B-2011 555247 92486765007 MW-5 SM 5310B-2011 555247 Date: 07/30/2020 05:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 142 of 155 Document Name: Document Revised: February 7, 2019 aceAnalytical Sample Condition Upon Receipt(SCUR) Page I of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.DE Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] ConditionSample Client Name:Upon Receipt , O# 924Q6%65 ll-- /I l'1 [(✓i 1 Cni +vl � i�v1 k I11 r YI � i1 Project Mw V ❑ Commercial ❑face x UP5 ❑Other: ❑Client 111111 FIN / 92466765 C1410Ay Seal Present? nYes I V1No Seals Intact? MYes FI No Date/Initials Person Exarnlning Contents:OV Za712d Packing Material: LABubble Wrap it/ Bubble Bags LJNone LJ Othet Thermomete �-,� FIR 92TO61 Type of Ice: L3dwet ❑slue FIR Gun ID: Cooler Temp (°CJ: O•1 ),G, Correction Factor: Add/Subtract J°C) 0.0 Co Temp Corrected (°C):O, k i • J i 411�1A Regulated Sail (EN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? f-lYaa FIN. Bioiogleal Tissue Fr en? ❑Nona ❑Yes []No ' /A Temp should be above freezing to 6°C ❑sarnpies out of temp criteria Samples on ice, cooling process has tegun Did samples originate frcm a foreign source pnternationally, Inrludlno Hawall and Piiprtn Wrn)7 FIIYea r7Nn Comments/DlscrepanCy: Chain of Custody Present? Yes Q.No ❑N/A 1. Samples Arrived within Hold Time? R<s ON. ❑N/A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes No ❑N/A 3. Rush Turn Around Time Requested? []Yes 0�'a N/A 4. Sufficient Volume? Yes ❑No ❑NIA S. Correct Containers Used? -Pace Containers Used? Err es [:]No []No [:]NIA ❑NIA 6. Containers Intact? ds [:]No []N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes v No ❑N/A S. Sample Labels Match COC? Yes ❑ND ❑N/A 9. -Includes DateMme/ID/Analysis Matrix: hV i Headspace in VOA Vials (55-6mm)? ❑Yes G] N0 [—]N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes O�No No ❑N/A ❑N/A 11. COMMENTS/SAMPLE 01SCREPANCY CLIENT NOTIFICAT Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Lot ID of split containers: Date: Date: Field Date Required? Elves [:]No Page 143 of 155 Document Name, Document Revised: February 7, 2018 Sample Condition upon Recelpt(SCUR) Page 1 of 2 ace Analytical Document No.: issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination Is Project P WO#� : 92 Q6765 verified and within the acceptance range for preservation f wU "TV G l PM: F1MB Due Date: 07/31/20 samples. Exceptions: VOA, Caliform, TOC, oil and Grease, DRO/9015 (water) DOC, r1Hg / CLIENT- 92—Mun ieipa l **Bottom half of box Is to list number of bottle s Z a d N a D a E N 7 a in z d Z a d C j i E 0 7 . �- m z v Z v; aJ n 2 E O 7 m z a a N a a y m N v Y O T 'Ea E n ry V7 a m N v = ¢ nl Z = E N 2 a in Z °il a m u 4 N i E n N N a I'm iV r+ n = n O Z s. E Ln N V i N n G 7 W M 0 v 3 u z w 0 a a E a v = � 7 H t7 d ry v T n E `m - ,� 2 M �7 d d 2 v v n r E Q of n ry 7 em t7 d N v 2 n' v OM = a E v = � N .r l7 a N V Y a 0fn Y E ¢ E o N V7 in l7 a V S z E o ry �y O 4 l7 d Z 4 O > E o 4 2 in l7 t] ¢ ? O N ro Q O > E 0 c/ 1- l7 ] ? Q O € '1 � ai 7 K 0 a. ¢ O > E 'T 4 s 0 L7 O 4 ? y '� m u 00 Y Q O 7 Z �+ l7 a « 0 A M .M.. 3G C7 ] m j ¢ z ? ;� S GJ y N E n rvi & en z fL v m J E o N N d ut n m in v U N_ Z u c N eq M rL m ' y v awl v E Q E r� 7 c K 6 ? !� a c w E a N 7 t9 w7 i .p a 2 a E ¢ E o i in in NN 2 fI I 1 I I \\ \. \ \N 3 iX\ N \N a N N \N3 5 { i j 3 i\N I 6 1\ l \ N I 8 I 9 l 10 3 11 12 pH Adjustment Log for Preserved Samples Sample IQ Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot a adjusted added Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will be s?nt to the North Carolina 4EHNR Certification Officeji.e. Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 144 of 155 Analytical' Document Name: Sample Condition Upon Retell Document No.: F-CAR-CS-033-Rev,06 Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office "Check mark top half of box If pH and/or dechiorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, coliform, TOC, Cil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project # WO# : 92486765 #2PM: RMB Due Date: 07/31/20 — CLIENT: 92—Municipal %C 2 di N m a c m J E rNl 7 a m 1 Z m N d a c 7 u A J E f�tl fo a m ? ai a` a c 7 a J E k,f1 i m 2 ° t: H a n C �y a H a Ira N o v O N = J E N 6 CA N _ a m O z = N d E N 6 O z sal ¢ N N N d E a m v ry rl a ! 2 O Z N S E a co v v C _? m a r 7 o E v ... = ? 2 v c 7 M Q l7 Q x a V I a ¢ ° t7 ¢ < Z v v a c E ¢ U' Q N a " a Q v S 'J ; iA a7 ¢ V a a D r� V+ E Q c yr l9 Q Z V z v a E ¢ E O ++ N ¢ t7 Q Q z U x ¢ O J E 2 l7 0 y rn N ,rvo Z q Q H V > ¢ z o C Q D E 0 > ¢ 2 a O rrM _ Q Q J E d 0 Y M a L1 a"-i 1r a m a Y O } ZCL a+ m S a } .w. u � y Z p o v = y J v, a N R v R a N N J E o N 4 VI M n N N x 2 u 10 a J E 0 N a m al v a 7 v E ¢ rl G S7 Q @ A 4 - m a e 7 rp C E L J 0 0p N 1 {7 p1 y 1 2 i " XV, \N Z I I 1 3 7 1 5 N N\� e N\N 3 7 3 B � � 9 I 3N\ 10 i pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot It adjusted I added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form w+II beimt to the North Carolina DEHNR Certification Office (Le. Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 145 of 155 Document Name: Document Revised: February 7, 2018 ace Analytical Sample Condition Upon Recelpt(SOUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.05 Pace Carolinas Quality Office *Check mark top half of box If pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions, VOA, Conform, TOC, Oil and Grease, DRO/BOSS (water) DOC, LLHg **Bottom half of box Is to list number of bottle Project ii IWO# : 92456765 PM: AMB Due Date: pc CLIENT: 92-Munic07/31/20 ipal E E � 2 a j u a E ,N-i O a a m 2 c. cc v a E N 7 Cn a m a u a E N 7 N a m m a n A rl .y a m x x O O ^� Z = n a E E N pis 2 C m a a m m a q 2 N i rNi N v a z Y a .~-I � a m , E 3y 1 ski {� 3 v v n Q = .� 7 t7 a N a u ¢ n = •+ L7 a 2 a Q E 4 ,n N rn M L? a v S ry a E _ of l7 a v x a 7 O i Q G N M M l7 a V x z d 4 E o ry III l7 a Q z a Q U u o _ a ; O '�^ Q O E l7 U > = Z n ¢ E CD OI �7 > Z a 4 d EM G l7 0 o ? "7 o `n a ¢ b > e N a y a � L7 � > I < V �a E rn a v, z Y a cr J E o *. N a LnN " a O _R a E a n+ m a 2 v 7or E ¢ E 7 O a N c v E CM r7 ? m Z N 4 E 7 m 1 N 4 3 2N\X � 3 V 1-/ 2 I i X X 3 4 1 `K" 5 6 7 8 9 14 11 12 IN\ pH Adjustment log for Preserved Samples Sample ID Type of preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot q Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cartincation Orrice tr.e, Out of hold, Incorrect preservative, out of temp, incorrect Containers. Page 146 of 155 Q IrEIVI# m v, ro 7 a 3 v o 3 N 7 y ❑ _ m D�—N�n m C7 3 Cn ❑ y aDJ' u IV ° > n'3 U' x m is CD n �mm' r ow c o c t o 3 Q ❑ P % a X I m` cn (D L/ CD SD N • t ^ 5 a v a" n u g D A ` v A. n rn v c1 o � o MATRIX COOS (see valid miles to left} z 3 y 2 v >v 0 0- 0 0 a 0 a Q 0 G] SAMPLE TYPE (G-GRAH C=COMP) m ❑ J =3 V C1 D T En � > a W r t o `_� W O C J`� ^ ca S to v� r n n 1 p C z m �Z m m m 1 m m D Z p �_ ❑ � � z m m m ,� m 7p 1 SAMPLE TEMP AT COLLECTION C m w y y Q o C OF CONTAINERS m Llnpreserved 0 v 0, p o N - a o J H2SO4 p m z a ' k HNO3 w c HCI C., u' ° NaOH w q m � .1 �1 cn h m > m Na25203 N Methanol m ❑ v m ro Other j j Anakyses Test YIN n T m Z. x x x x x x x Ix Ix x x VOCs Appendix 1 z ❑ > Y -� m x x x x x x x x x x x x TotaY Metals App_ 1 z O A m m S2 `z x x x Alkalinly z D a x x x x Sulfate z x x x x SuKde z a m m m -e x x x x Cnloride z Ix x x x TOC z o *y x x x x coo+1 z a x x x x Ferrous Iron z ry g m z 0 o m a m x x x X Nitrale z m t o Z2 TEMP in C F L x x x x x x x x x x x x 1,4Oioxane ANON-SIM} z � a m ° o J x Mercury z Received on Ice (YIN) a o�1 z us y ea Cooler (Y1N p % Samples Intact C' �! �v,j CD- _ C)n 7T n QZ C „ EX ❑ 0. w "'3 m G) ❑ O O D C m ,C D � Page 147 of 155 a a m C) A C) A N ITEM# n s ❑F �' 61 a a ❑ a � F. m n } � 2 D n N -U .{rr� 3 C', q fl wD -i N m - N 3 x v a l,/ p Song �ED0 Sl1 ID vO°a q m; r n h s I► r 1v n v m o E m ry A 0 0 0 p x T o N dED cn m 4— i jlr, _ b m N it n e x ^ � v •j � f7 4 C] 77 a C"f A N m �a m � v a y n l o o_ w o ❑ o a m a m y � 0 i Tc� �i MATRIX CONE (sea yMid codes to left) {° Z � � z 0 m ❑ J y 0 0 C) C) 0 GI 0 0 C3 C) C) C) SAMPLE TYPE (G=GRAR C=COMP) H v � 7 O m m n a m = D b A A y v, m Or rn m p Q 1 n -z+ z z V z O c� rrnn m m h tl I D+ m m m 0 o L z z � D b Cr m r m A b r m a G) z 1 -bi m m SAMPLE TEMP AT COLLECTION 1 f 1 c A rn [n p n xOF CONTAINERS "n m m b n a n b m Unpreserved m- o o S n H2SO4 m n m m o � n HNo3 HCICD zi m o � NaOH w m n Na2S263 CD� 1C m Melhanof u7 m a � m Other Analyses Test YIN r r r m z x x X X X x x x x x x x VOCsApperrdfx 1 z q x x x x X x x x x x x x Total Metals App. 1 z A m m O y z m u z a `i n X x X x x x Alkalinty w z 'a V x x x x x x Sulfale z 5 m x x x x x x Sulfide z w 66 b Z 7+ x x X X X X I Chloride Qj n. z x x x x x x TOC x 1x x x x COD a z A _ g z z z m n x x x x x x Ferrous Iron z X x X X x x Nitrate X x x x x x x x x x x x 1,4-Oioxene(non-SIM) o z w n ' Y a y TEMP m C 3 r In w Received on {ce - (YIN) � o z 2 � us lwy ea Confer YIN � o - -w w Samples Intad (YIN) m Page 148 of 155 w � n p � r 3 T r A -q z Z z � 3 a m m m S y N z M v N D ❑ r r z m m m m }' r m P m m m Pin lived on YIN) Rly— ed Cooler pies Intact I 4 wNw1NNN ITEM# w C. w N Z- 1 o in A w m P3 m 'n m VJ any y tJ n r 6 m a x c ' P;E O a a D m _ 50 _ a > w Z a 3 L r m MATRIX CODE (see valid miles la left) SAnMP'LETYPE (G-GRAB C=CAMP) O cn m n I i n m 1 O a (T- m 0 Om m i ❑ m m SAMPLE TEMP AT COLLECTION B OF CONTAINERS v m p n a rn -i ca N m „ N N SD n o � rl O � O O CD 3 <b . m a Unpreserved B m a H2SO4 m n m m HNO3rD m HClfom r' m NaOH Na2S203 U Methanol Other Analyses -Test VQCsAppendix 1 2 Total Metals App- 1 z 1,40ioxane (non -SW GOD Ferrous Iron Nilrale Methane (Dissolved) a � z �' Z o a' Page 149 of 155 + Document Name: Sample Condltton Doan Ren Laboratory receiving samples: Asheville [] Eden[] Greenwood ❑ Hurttersvilie oecumairt Revised: February 7, 2013 Page 1 of 2 �tring�nst{t . Pace Carolinas Quality Office Ralelgod Mechanicsville❑ " r Client Name: project WO# : 92486704 Laurier: ❑Fed Ex ❑ Ps ❑USP ❑Client ❑ Commerclai ❑Pace ❑Other: 1111111111111111111111 92486704 Custody Seal Present? ❑Yes []No Seals Intact? ❑Yes []No 4ateflnitials Pelson Examining, Contents: I/t� Packing Materials []Bubble Wrap ❑aubhle Bags ❑None ❑ Other 6lafegica1 rmue Frozen? Thermometer. of Ice: ❑Wet ❑Blue 9R Gun la: �_L! ❑Y� [JNo []NIA ❑None Cooler Temp j'Q Correction Factor: Ad tra Q 0, �7 5 f Temp should be above freezing is b°C Cooler Temp- Corrected ('C): Demos mtofsemperRerra.Samples onice, Cooling process has begun USDA Regulated Solf (KN/A, water sample) Dfd samples originate In a quarantine tone within the United States: CA, NY, or SC (check maps)? rl,-- riu_ pfd sampfs oeglnate tram a foreign source {interragomgy, n d ��U—I -ri Pea m. W-171 )Yee MNn Comments/Discre panty: Chain cf Custody Present? es ❑No ❑P41A 1 1. Samples Areived within hold Time? ❑Ne N/A ? Short Hold Time Analysts,(<7Z hr.}? es []No ❑N/A 3. Rush Turn Around Time Requested? 0yes to ❑N!A 4• SLAC!ent Volume? es []No ❑NIA 5. Correct Containers Used? -Pace Centafr.ers Used? Yes �rn u ❑No []NO ©NIA 5. Containers Intact? es ❑No ❑N!A 7. Ulssolved analysts: Samples Field Filtered? Oyu No N/A E• Sample Ldbc15 Match CCC? -Includes Darc/Tirne/ID/Analysis Vfatrac: �7^es ! ©No QN/A 9. Headspace in VOA Vials (>5-6mm)? []yes (-]No /A 10. Trip Blank Present? ❑Yes ❑No '54N/x 11m COMMEN-TS/SAMPLE 1315CRVANCY Lot 10 of split Containers: Cif EYT NOTIFICATION/RESOLUTION Person contacted; Project Manager SCURF Review: 1 i Project Manager SRF Review: fN Cate/Time: Field Dan Required? ❑Yes ❑No Date: � 1 I oats: --� 1 ezA I Z .lam Page 150 of 1 et � %11 Documarrt Name: *Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples. Eeceptforu: VOA, Colffarm, TOC, Off and Grease, DRO(8015 (water) DOC, LL4g "*Bottom half of box is to list number of bottle document ft0ed: February 1, Page 1 of 2 Pace Carolinas Quaw OfRw- J Project # WO# : 92486704 PM: AMB Due Date: 07/31/20 CLIENT: 92-Municipal v a 3 m 7J C u a. E `-� rq 3 sl 1 m Z m 9 c a E N 0. m Z aqr N s eL pO6 '� 1 m ry q• vq a O V ' = y „� r, a y� 6 'pS m 0 R. 2 m d N Z a m $ a+ °� {y, N N S m ^ = a V a E .�-I It m c A' ,� a C n 1�1 LL ks b m Z v o dE ° rl l7 a N a r� H l7 a m y ? a E 4 E 0 a p 6 E a y� '7 f7 a ^� V S o n EE d G uNj U a = z o M i7 a a 0 > E IT ate! 'U a ? yf r l+q a O > E b o~� 5:J 7 z a O E Y 9�1 3 a, a 3 m O s m O a � = E } al a° Z q m (V1 l� 7 3 ? & E yP. lf1 r a 2� a u N VI [NV N m a O n z u 9 a a n Is�l m •a y a v E ¢ J g $ z 9 H Z m n r a 7 c a N E E �7 0�f o f T I X� 3 \�:i I N 3 -77 4, 2 1 5 i f l 3 1 H 1\N 6 3 7 4 I N A I I I INN - 9 �a N\NN I N III -N -1 \NN V I N pH Adjustment tog for Preserved Samples Sample [E] Type of Preservative pH upon recctpt Gate presarvatfon adjusted Time preservaltan adjusted Amount of Preservative added lot f Note: wrianaver trere is aOut of held, inearrert preservative, out of temp, Incorrect cantalners, Page 151 of 155 ceAnaloicaf �.��x.• racnbrs. rurr S A VM%OTr %0&.-rWW I Wr Cllett; hn A'�sra� r, r'�_ f ' x PM: RMB Due Date: 07/31 /20 rd y�O,_ :_ f t v i CLIENT: 92-Municipal I I 1. If Chain -of -Custody (COC) is not received: contact client and if necessary, fill out a COC and Indicate that it was filled out by I lab personnel. Note issues on this NCF. I 2. If COC Is Incomplete, check applicabile Issues below and add details where appropriate.. Collecllon date/time missing or Analyses or analytes: missing or I Samples listed on COC do not match samples Incorrect clarification needed received (missing, additional, etc. Sample IDs on COC do not I match sample labels Required trip blanks were not received Re dired signatures are missing Gommentsluetalls/Utter Issues not listed above: 3. Samole intearity issues: check at)Dlieable issues below and add details where anorcorlate: Samples: Condition needs to be brought to Sam les: Past holding time lab ersonnel's attention detalis below Preservation: Im ro er Temperature: not within acceptance criteria (typically Samples: Not field filtered Containers: Broken or compromised 0 6C Samples: Insufficient volume received Containers: Incorrect Temperature: Samples arrived frozen Samples: Cooler damaged or Custody Seals: Missing or compromised on compromised samples, trip blanks or coolers Vials received with im ro er heads ace Samples: contain chlorine or sulfides Packing Material: lnsu{ficient/im ro er Other: Comments/ Deta Its: 4. If Samples not Dreserved nrooeriv and SamDle Receivina adiusts DH. add details below: Sample ID: low - t DateMme: 2 1 Amountit a pres added: Preserved by; InWai and Final H: & d Lot # of pres added: ogtIll - ,7I � >S Sample ID: rM jZ DatelTlme: �mazo 13,66 Amount/type pres added: r- 2 5 4 0 z u{ ✓ Preserved by: Initial and Final p OI Lot# of res added: (-)q2215-a S Sample ID: Date/Time: Amounlitype pres added: Preserved by: Initial and Final H: I Lot # of pros added: 5. Client Contact: It client is contacted for any Issue listed above, fill in details below: Client: Contactedper: PM Initials: Date/Time: Client Comments/Instructions: F-ALL-C-011-rev.00, 05Ju12018 4C Nage q 52 or 1 w ITEM# 0 30 G) z :7. 0 b Coil . U\a -4aa S :3 CD C. ev CD R AU 0 04 0 ;D 0 0 0 N N MATfUXCOCE (kaavai-.d"d'sLfiJ-fl) Z Cu 0 10 In 10 it n 4) 0 10 1 0 up-> r.AmFLrz-ryf-E (G=GRAE C-COUP) is 1X, A 71 ��l 22 R! I j F rd E r- z Z I " �g 1 M I .. m 1 z A Vaq rn V SAMPLE TEMP AT COLLECTIBN CC CONTAINERS -0 -0 Unpresarved . t 3 Fn H2804 W ez 'Lai UN03 L 53 NsQH > Nfa28203 Methanol ra Other K n to >< x x x Ix 1>< x VCCs Apponifig I M x >4 x x x x Ix Ix x Total Melals App. I Tmqftqy z .59 x X 74 Alkalinly X x x >4 sulfate z TIK xa X x Ix JSU[rd z X Ix 1(morlde x X I x ITOC z ti. !w! x X >g COD X X 1>4 Ferrcus Iran z a f P Nitrate it W dD x x x x x x x x x x x x i,,I.DioAane (NON -Sim) TEMP in C X Mercury z K, ■ 2 0 Received an lcu !YIN) Ted Samples frilact (YIN) - J 0 "Co x 0 > z 6 C) In C F 0 rn G) o O M'— W < CID 05 a 0 rr C) fl) r 0 M CL 02 n_ Page 153 Of 1155 Page 154 of 1 ITEM# e .'ti ra i T1, Lut I� c 4 m i v 3 1 }� w �r 4 � W�NtdATRIx GOC£ (see va%d todai re loll) 07 C7 D !7 G) 0 L) 0 L7 G) G) SAMPLETYPE (G-GAAA C•CUP) 1 vh y ._„ n n .I ai m p n O G 1 ry o •..�5 a Y m Ylq_lalr- z D 0 ' Ti m m O C7 �? o " o m a Z 1 Y ; m o r m m p -� SAUPI-i TEkIP A7 COLLECTION nO r�,s iOF CONTAINERS I �, .:,� Unpreserved v m a 1 p _• s}1 'fi FC H250a � 8 m o3 —q "� m 0 HNO3 � m a$ S a 0 a � m D FOCI m a i - n a 0 0 n NaOH m Na2S203 u m'C Malharrol 1D m Z ' Other p1 . % x x X x x x x x x VOCs Append'ec 1 2 %_'. ryCD 0 A m f++ a x x x x x x Total Metals App. 1 z \� N .a " x%% x x x x x x x x 1,4.Oioxane(nonSIM. z a VJ N p ^- C }c Alkalinly z ~•r- x Sutfale z k r- S IA: x Sulfide z _ ;y XI I lChlorkle z StC @ rt x N TOG 2 _ z 9d n _ X Ctlt] z n - X Ix Ferrous Iran Nitrate z �' 3 TEMP in C - h X Malhane(Qissohred) Mercury z Reseivedon tca(YIN) ':+ t�''• Jy CUSFC y 5ealedo ler u - w Samples intact !N) " s a Page 155 of 1 Appendix C Statistical Analyses Calculations Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-16) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 36.8 84.83 -48.03 0 1 33.76 84.83 -51.07 0 2 41.36 84.83 -43.47 0 3 35.7 84.83 -49.13 0 4 44.37 84.83 -40.46 0 5 32.61 84.83 -52.22 0 6 42.67 84.83 -42.16 0 7 32.08 84.83 -52.75 0 8 21.71 84.83 -63.12 0 9 17.19 84.83 -67.64 0 10 16.35 84.83 -68.48 0 11 21.87 84.83 -62.96 0 12 13.66 84.83 -71.17 0 13 8.45 84.83 -76.38 0 14 13.51 84.83 -71.32 0 15 8.35 84.83 -76.48 0 16 10.26 84.83 -74.57 0 17 7.2 84.83 -77.63 0 18 2.31 84.83 -82.52 0 19 6.28 84.83 -78.55 0 20 4.84 84.83 -79.99 0 21 3.75 84.83 -81.08 0 22 33.76 36.8 -3.04 0 23 41.36 36.8 4.56 1 23 35.7 36.8 -1.1 1 24 44.37 36.8 7.57 2 24 32.61 36.8 -4.19 2 25 42.67 36.8 5.87 3 25 32.08 36.8 -4.72 3 26 21.71 36.8 -15.09 3 27 17.19 36.8 -19.61 3 28 16.35 36.8 -20.45 3 29 21.87 36.8 -14.93 3 30 13.66 36.8 -23.14 3 31 8.45 36.8 -28.35 3 32 13.51 36.8 -23.29 3 33 8.35 36.8 -28.45 3 34 10.26 36.8 -26.54 3 35 7.2 36.8 -29.6 3 36 2.31 36.8 -34.49 3 37 6.28 36.8 -30.52 3 38 4.84 36.8 -31.96 3 39 3.75 36.8 -33.05 3 40 41.36 33.76 7.6 4 40 35.7 33.76 1.94 5 40 44.37 33.76 10.61 6 40 32.61 33.76 -1.15 6 41 42.67 33.76 8.91 7 41 32.08 33.76 -1.68 7 42 21.71 33.76 -12.05 7 43 17.19 33.76 -16.57 7 44 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 1 Alexander Co CDLF over MSWLF Cumulative VOCs 16.35 33.76 -17.41 7 45 21.87 33.76 -11.89 7 46 13.66 33.76 -20.1 7 47 8.45 33.76 -25.31 7 48 13.51 33.76 -20.25 7 49 8.35 33.76 -25.41 7 50 10.26 33.76 -23.5 7 51 7.2 33.76 -26.56 7 52 2.31 33.76 -31.45 7 53 6.28 33.76 -27.48 7 54 4.84 33.76 -28.92 7 55 3.75 33.76 -30.01 7 56 35.7 41.36 -5.66 7 57 44.37 41.36 3.01 8 57 32.61 41.36 -8.75 8 58 42.67 41.36 1.31 9 58 32.08 41.36 -9.28 9 59 21.71 41.36 -19.65 9 60 17.19 41.36 -24.17 9 61 16.35 41.36 -25.01 9 62 21.87 41.36 -19.49 9 63 13.66 41.36 -27.7 9 64 8.45 41.36 -32.91 9 65 13.51 41.36 -27.85 9 66 8.35 41.36 -33.01 9 67 10.26 41.36 -31.1 9 68 7.2 41.36 -34.16 9 69 2.31 41.36 -39.05 9 70 6.28 41.36 -35.08 9 71 4.84 41.36 -36.52 9 72 3.75 41.36 -37.61 9 73 44.37 35.7 8.67 10 73 32.61 35.7 -3.09 10 74 42.67 35.7 6.97 11 74 32.08 35.7 -3.62 11 75 21.71 35.7 -13.99 11 76 17.19 35.7 -18.51 11 77 16.35 35.7 -19.35 11 78 21.87 35.7 -13.83 11 79 13.66 35.7 -22.04 11 80 8.45 35.7 -27.25 11 81 13.51 35.7 -22.19 11 82 8.35 35.7 -27.35 11 83 10.26 35.7 -25.44 11 84 7.2 35.7 -28.5 11 85 2.31 35.7 -33.39 11 86 6.28 35.7 -29.42 11 87 4.84 35.7 -30.86 11 88 3.75 35.7 -31.95 11 89 32.61 44.37 -11.76 11 90 42.67 44.37 -1.7 11 91 32.08 44.37 -12.29 11 92 21.71 44.37 -22.66 11 93 17.19 44.37 -27.18 11 94 16.35 44.37 -28.02 11 95 21.87 44.37 -22.5 11 96 13.66 44.37 -30.71 11 97 8.45 44.37 -35.92 11 98 13.51 44.37 -30.86 11 99 8.35 44.37 -36.02 11 100 10.26 44.37 -34.11 11 101 7.2 44.37 -37.17 11 102 2.31 44.37 -42.06 11 103 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 2 Alexander Co CDLF over MSWLF Cumulative VOCs 6.28 44.37 -38.09 11 104 4.84 44.37 -39.53 11 105 3.75 44.37 -40.62 11 106 42.67 32.61 10.06 12 106 32.08 32.61 -0.53 12 107 21.71 32.61 -10.9 12 108 17.19 32.61 -15.42 12 109 16.35 32.61 -16.26 12 110 21.87 32.61 -10.74 12 111 13.66 32.61 -18.95 12 112 8.45 32.61 -24.16 12 113 13.51 32.61 -19.1 12 114 8.35 32.61 -24.26 12 115 10.26 32.61 -22.35 12 116 7.2 32.61 -25.41 12 117 2.31 32.61 -30.3 12 118 6.28 32.61 -26.33 12 119 4.84 32.61 -27.77 12 120 3.75 32.61 -28.86 12 121 32.08 42.67 -10.59 12 122 21.71 42.67 -20.96 12 123 17.19 42.67 -25.48 12 124 16.35 42.67 -26.32 12 125 21.87 42.67 -20.8 12 126 13.66 42.67 -29.01 12 127 8.45 42.67 -34.22 12 128 13.51 42.67 -29.16 12 129 8.35 42.67 -34.32 12 130 10.26 42.67 -32.41 12 131 7.2 42.67 -35.47 12 132 2.31 42.67 -40.36 12 133 6.28 42.67 -36.39 12 134 4.84 42.67 -37.83 12 135 3.75 42.67 -38.92 12 136 21.71 32.08 -10.37 12 137 17.19 32.08 -14.89 12 138 16.35 32.08 -15.73 12 139 21.87 32.08 -10.21 12 140 13.66 32.08 -18.42 12 141 8.45 32.08 -23.63 12 142 13.51 32.08 -18.57 12 143 8.35 32.08 -23.73 12 144 10.26 32.08 -21.82 12 145 7.2 32.08 -24.88 12 146 2.31 32.08 -29.77 12 147 6.28 32.08 -25.8 12 148 4.84 32.08 -27.24 12 149 3.75 32.08 -28.33 12 150 17.19 21.71 -4.52 12 151 16.35 21.71 -5.36 12 152 21.87 21.71 0.16 13 152 13.66 21.71 -8.05 13 153 8.45 21.71 -13.26 13 154 13.51 21.71 -8.2 13 155 8.35 21.71 -13.36 13 156 10.26 21.71 -11.45 13 157 7.2 21.71 -14.51 13 158 2.31 21.71 -19.4 13 159 6.28 21.71 -15.43 13 160 4.84 21.71 -16.87 13 161 3.75 21.71 -17.96 13 162 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 3 Alexander Co CDLF over MSWLF Cumulative VOCs 16.35 17.19 -0.84 13 163 21.87 17.19 4.68 14 163 13.66 17.19 -3.53 14 164 8.45 17.19 -8.74 14 165 13.51 17.19 -3.68 14 166 8.35 17.19 -8.84 14 167 10.26 17.19 -6.93 14 168 7.2 17.19 -9.99 14 169 2.31 17.19 -14.88 14 170 6.28 17.19 -10.91 14 171 4.84 17.19 -12.35 14 172 3.75 17.19 -13.44 14 173 21.87 16.35 5.52 15 173 13.66 16.35 -2.69 15 174 8.45 16.35 -7.9 15 175 13.51 16.35 -2.84 15 176 8.35 16.35 -8 15 177 10.26 16.35 -6.09 15 178 7.2 16.35 -9.15 15 179 2.31 16.35 -14.04 15 180 6.28 16.35 -10.07 15 181 4.84 16.35 -11.51 15 182 3.75 16.35 -12.6 15 183 13.66 21.87 -8.21 15 184 8.45 21.87 -13.42 15 185 13.51 21.87 -8.36 15 186 8.35 21.87 -13.52 15 187 10.26 21.87 -11.61 15 188 7.2 21.87 -14.67 15 189 2.31 21.87 -19.56 15 190 6.28 21.87 -15.59 15 191 4.84 21.87 -17.03 15 192 3.75 21.87 -18.12 15 193 8.45 13.66 -5.21 15 194 13.51 13.66 -0.15 15 195 8.35 13.66 -5.31 15 196 10.26 13.66 -3.4 15 197 7.2 13.66 -6.46 15 198 2.31 13.66 -11.35 15 199 6.28 13.66 -7.38 15 200 4.84 13.66 -8.82 15 201 3.75 13.66 -9.91 15 202 13.51 8.45 5.06 16 202 8.35 8.45 -0.1 16 203 10.26 8.45 1.81 17 203 7.2 8.45 -1.25 17 204 2.31 8.45 -6.14 17 205 6.28 8.45 -2.17 17 206 4.84 8.45 -3.61 17 207 3.75 8.45 -4.7 17 208 8.35 13.51 -5.16 17 209 10.26 13.51 -3.25 17 210 7.2 13.51 -6.31 17 211 2.31 13.51 -11.2 17 212 6.28 13.51 -7.23 17 213 4.84 13.51 -8.67 17 214 3.75 13.51 -9.76 17 215 10.26 8.35 1.91 18 215 7.2 8.35 -1.15 18 216 2.31 8.35 -6.04 18 217 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 4 Alexander Co CDLF over MSWLF Cumulative VOCs 6.28 8.35 -2.07 18 218 4.84 8.35 -3.51 18 219 3.75 8.35 -4.6 18 220 7.2 10.26 -3.06 18 221 2.31 10.26 -7.95 18 222 6.28 10.26 -3.98 18 223 4.84 10.26 -5.42 18 224 3.75 10.26 -6.51 18 225 2.31 7.2 -4.89 18 226 6.28 7.2 -0.92 18 227 4.84 7.2 -2.36 18 228 3.75 7.2 -3.45 18 229 6.28 2.31 3.97 19 229 4.84 2.31 2.53 20 229 3.75 2.31 1.44 21 229 4.84 6.28 -1.44 21 230 3.75 6.28 -2.53 21 231 3.75 4.84 -1.09 21 232 S Statistic = 21 - 232 = -211 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 5 Alexander Co CDLF over MSWLF Z-Score =-5.5462 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 6 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-16) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 58.96 74.55 -15.59 0 1 63.2 74.55 -11.35 0 2 75.84 74.55 1.29 1 2 70.57 74.55 -3.98 1 3 79.21 74.55 4.66 2 3 62.32 74.55 -12.23 2 4 59.16 74.55 -15.39 2 5 69.08 74.55 -5.47 2 6 58.34 74.55 -16.21 2 7 71.17 74.55 -3.38 2 8 89.27 74.55 14.72 3 8 76.95 74.55 2.4 4 8 67.17 74.55 -7.38 4 9 74.17 74.55 -0.38 4 10 72.75 74.55 -1.8 4 11 55.67 74.55 -18.88 4 12 50.36 74.55 -24.19 4 13 58.09 74.55 -16.46 4 14 49.71 74.55 -24.84 4 15 63.46 74.55 -11.09 4 16 56.66 74.55 -17.89 4 17 38.96 74.55 -35.59 4 18 63.2 58.96 4.24 5 18 75.84 58.96 16.88 6 18 70.57 58.96 11.61 7 18 79.21 58.96 20.25 8 18 62.32 58.96 3.36 9 18 59.16 58.96 0.2 10 18 69.08 58.96 10.12 11 18 58.34 58.96 -0.62 11 19 71.17 58.96 12.21 12 19 89.27 58.96 30.31 13 19 76.95 58.96 17.99 14 19 67.17 58.96 8.21 15 19 74.17 58.96 15.21 16 19 72.75 58.96 13.79 17 19 55.67 58.96 -3.29 17 20 50.36 58.96 -8.6 17 21 58.09 58.96 -0.87 17 22 49.71 58.96 -9.25 17 23 63.46 58.96 4.5 18 23 56.66 58.96 -2.3 18 24 38.96 58.96 -20 18 25 75.84 63.2 12.64 19 25 70.57 63.2 7.37 20 25 79.21 63.2 16.01 21 25 62.32 63.2 -0.88 21 26 59.16 63.2 -4.04 21 27 69.08 63.2 5.88 22 27 58.34 63.2 -4.86 22 28 71.17 63.2 7.97 23 28 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 7 Alexander Co CDLF over MSWLF Cumulative VOCs 89.27 63.2 26.07 24 28 76.95 63.2 13.75 25 28 67.17 63.2 3.97 26 28 74.17 63.2 10.97 27 28 72.75 63.2 9.55 28 28 55.67 63.2 -7.53 28 29 50.36 63.2 -12.84 28 30 58.09 63.2 -5.11 28 31 49.71 63.2 -13.49 28 32 63.46 63.2 0.26 29 32 56.66 63.2 -6.54 29 33 38.96 63.2 -24.24 29 34 70.57 75.84 -5.27 29 35 79.21 75.84 3.37 30 35 62.32 75.84 -13.52 30 36 59.16 75.84 -16.68 30 37 69.08 75.84 -6.76 30 38 58.34 75.84 -17.5 30 39 71.17 75.84 -4.67 30 40 89.27 75.84 13.43 31 40 76.95 75.84 1.11 32 40 67.17 75.84 -8.67 32 41 74.17 75.84 -1.67 32 42 72.75 75.84 -3.09 32 43 55.67 75.84 -20.17 32 44 50.36 75.84 -25.48 32 45 58.09 75.84 -17.75 32 46 49.71 75.84 -26.13 32 47 63.46 75.84 -12.38 32 48 56.66 75.84 -19.18 32 49 38.96 75.84 -36.88 32 50 79.21 70.57 8.64 33 50 62.32 70.57 -8.25 33 51 59.16 70.57 -11.41 33 52 69.08 70.57 -1.49 33 53 58.34 70.57 -12.23 33 54 71.17 70.57 0.6 34 54 89.27 70.57 18.7 35 54 76.95 70.57 6.38 36 54 67.17 70.57 -3.4 36 55 74.17 70.57 3.6 37 55 72.75 70.57 2.18 38 55 55.67 70.57 -14.9 38 56 50.36 70.57 -20.21 38 57 58.09 70.57 -12.48 38 58 49.71 70.57 -20.86 38 59 63.46 70.57 -7.11 38 60 56.66 70.57 -13.91 38 61 38.96 70.57 -31.61 38 62 62.32 79.21 -16.89 38 63 59.16 79.21 -20.05 38 64 69.08 79.21 -10.13 38 65 58.34 79.21 -20.87 38 66 71.17 79.21 -8.04 38 67 89.27 79.21 10.06 39 67 76.95 79.21 -2.26 39 68 67.17 79.21 -12.04 39 69 74.17 79.21 -5.04 39 70 72.75 79.21 -6.46 39 71 55.67 79.21 -23.54 39 72 50.36 79.21 -28.85 39 73 58.09 79.21 -21.12 39 74 49.71 79.21 -29.5 39 75 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 8 Alexander Co CDLF over MSWLF Cumulative VOCs 63.46 79.21 -15.75 39 76 56.66 79.21 -22.55 39 77 38.96 79.21 -40.25 39 78 59.16 62.32 -3.16 39 79 69.08 62.32 6.76 40 79 58.34 62.32 -3.98 40 80 71.17 62.32 8.85 41 80 89.27 62.32 26.95 42 80 76.95 62.32 14.63 43 80 67.17 62.32 4.85 44 80 74.17 62.32 11.85 45 80 72.75 62.32 10.43 46 80 55.67 62.32 -6.65 46 81 50.36 62.32 -11.96 46 82 58.09 62.32 -4.23 46 83 49.71 62.32 -12.61 46 84 63.46 62.32 1.14 47 84 56.66 62.32 -5.66 47 85 38.96 62.32 -23.36 47 86 69.08 59.16 9.92 48 86 58.34 59.16 -0.82 48 87 71.17 59.16 12.01 49 87 89.27 59.16 30.11 50 87 76.95 59.16 17.79 51 87 67.17 59.16 8.01 52 87 74.17 59.16 15.01 53 87 72.75 59.16 13.59 54 87 55.67 59.16 -3.49 54 88 50.36 59.16 -8.8 54 89 58.09 59.16 -1.07 54 90 49.71 59.16 -9.45 54 91 63.46 59.16 4.3 55 91 56.66 59.16 -2.5 55 92 38.96 59.16 -20.2 55 93 58.34 69.08 -10.74 55 94 71.17 69.08 2.09 56 94 89.27 69.08 20.19 57 94 76.95 69.08 7.87 58 94 67.17 69.08 -1.91 58 95 74.17 69.08 5.09 59 95 72.75 69.08 3.67 60 95 55.67 69.08 -13.41 60 96 50.36 69.08 -18.72 60 97 58.09 69.08 -10.99 60 98 49.71 69.08 -19.37 60 99 63.46 69.08 -5.62 60 100 56.66 69.08 -12.42 60 101 38.96 69.08 -30.12 60 102 71.17 58.34 12.83 61 102 89.27 58.34 30.93 62 102 76.95 58.34 18.61 63 102 67.17 58.34 8.83 64 102 74.17 58.34 15.83 65 102 72.75 58.34 14.41 66 102 55.67 58.34 -2.67 66 103 50.36 58.34 -7.98 66 104 58.09 58.34 -0.25 66 105 49.71 58.34 -8.63 66 106 63.46 58.34 5.12 67 106 56.66 58.34 -1.68 67 107 38.96 58.34 -19.38 67 108 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 9 Alexander Co CDLF over MSWLF Cumulative VOCs 89.27 71.17 18.1 68 108 76.95 71.17 5.78 69 108 67.17 71.17 -4 69 109 74.17 71.17 3 70 109 72.75 71.17 1.58 71 109 55.67 71.17 -15.5 71 110 50.36 71.17 -20.81 71 111 58.09 71.17 -13.08 71 112 49.71 71.17 -21.46 71 113 63.46 71.17 -7.71 71 114 56.66 71.17 -14.51 71 115 38.96 71.17 -32.21 71 116 76.95 89.27 -12.32 71 117 67.17 89.27 -22.1 71 118 74.17 89.27 -15.1 71 119 72.75 89.27 -16.52 71 120 55.67 89.27 -33.6 71 121 50.36 89.27 -38.91 71 122 58.09 89.27 -31.18 71 123 49.71 89.27 -39.56 71 124 63.46 89.27 -25.81 71 125 56.66 89.27 -32.61 71 126 38.96 89.27 -50.31 71 127 67.17 76.95 -9.78 71 128 74.17 76.95 -2.78 71 129 72.75 76.95 -4.2 71 130 55.67 76.95 -21.28 71 131 50.36 76.95 -26.59 71 132 58.09 76.95 -18.86 71 133 49.71 76.95 -27.24 71 134 63.46 76.95 -13.49 71 135 56.66 76.95 -20.29 71 136 38.96 76.95 -37.99 71 137 74.17 67.17 7 72 137 72.75 67.17 5.58 73 137 55.67 67.17 -11.5 73 138 50.36 67.17 -16.81 73 139 58.09 67.17 -9.08 73 140 49.71 67.17 -17.46 73 141 63.46 67.17 -3.71 73 142 56.66 67.17 -10.51 73 143 38.96 67.17 -28.21 73 144 72.75 74.17 -1.42 73 145 55.67 74.17 -18.5 73 146 50.36 74.17 -23.81 73 147 58.09 74.17 -16.08 73 148 49.71 74.17 -24.46 73 149 63.46 74.17 -10.71 73 150 56.66 74.17 -17.51 73 151 38.96 74.17 -35.21 73 152 55.67 72.75 -17.08 73 153 50.36 72.75 -22.39 73 154 58.09 72.75 -14.66 73 155 49.71 72.75 -23.04 73 156 63.46 72.75 -9.29 73 157 56.66 72.75 -16.09 73 158 38.96 72.75 -33.79 73 159 50.36 55.67 -5.31 73 160 58.09 55.67 2.42 74 160 49.71 55.67 -5.96 74 161 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 10 Alexander Co CDLF over MSWLF Cumulative VOCs 63.46 55.67 7.79 75 161 56.66 55.67 0.99 76 161 38.96 55.67 -16.71 76 162 58.09 50.36 7.73 77 162 49.71 50.36 -0.65 77 163 63.46 50.36 13.1 78 163 56.66 50.36 6.3 79 163 38.96 50.36 -11.4 79 164 49.71 58.09 -8.38 79 165 63.46 58.09 5.37 80 165 56.66 58.09 -1.43 80 166 38.96 58.09 -19.13 80 167 63.46 49.71 13.75 81 167 56.66 49.71 6.95 82 167 38.96 49.71 -10.75 82 168 56.66 63.46 -6.8 82 169 38.96 63.46 -24.5 82 170 38.96 56.66 -17.7 82 171 S Statistic = 82 - 171 = -89 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 11 Alexander Co CDLF over MSWLF Z-Score=-2.32412 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 12 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-24) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 43 63.53 -20.53 0 1 32.22 63.53 -31.31 0 2 76.57 63.53 13.04 1 2 51.69 63.53 -11.84 1 3 68.44 63.53 4.91 2 3 55.065 63.53 -8.465 2 4 61.89 63.53 -1.64 2 5 58.98 63.53 -4.55 2 6 49.41 63.53 -14.12 2 7 62.79 63.53 -0.74 2 8 54.44 63.53 -9.09 2 9 60.12 63.53 -3.41 2 10 40.99 63.53 -22.54 2 11 32.385 63.53 -31.145 2 12 53.78 63.53 -9.75 2 13 45.88 63.53 -17.65 2 14 42.54 63.53 -20.99 2 15 23.82 63.53 -39.71 2 16 19.82 63.53 -43.71 2 17 17.85 63.53 -45.68 2 18 37.48 63.53 -26.05 2 19 21.58 63.53 -41.95 2 20 32.22 43 -10.78 2 21 76.57 43 33.57 3 21 51.69 43 8.69 4 21 68.44 43 25.44 5 21 55.065 43 12.065 6 21 61.89 43 18.89 7 21 58.98 43 15.98 8 21 49.41 43 6.41 9 21 62.79 43 19.79 10 21 54.44 43 11.44 11 21 60.12 43 17.12 12 21 40.99 43 -2.01 12 22 32.385 43 -10.615 12 23 53.78 43 10.78 13 23 45.88 43 2.88 14 23 42.54 43 -0.46 14 24 23.82 43 -19.18 14 25 19.82 43 -23.18 14 26 17.85 43 -25.15 14 27 37.48 43 -5.52 14 28 21.58 43 -21.42 14 29 76.57 32.22 44.35 15 29 51.69 32.22 19.47 16 29 68.44 32.22 36.22 17 29 55.065 32.22 22.845 18 29 61.89 32.22 29.67 19 29 58.98 32.22 26.76 20 29 49.41 32.22 17.19 21 29 62.79 32.22 30.57 22 29 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 13 Alexander Co CDLF over MSWLF Cumulative VOCs 54.44 32.22 22.22 23 29 60.12 32.22 27.9 24 29 40.99 32.22 8.77 25 29 32.385 32.22 0.165 26 29 53.78 32.22 21.56 27 29 45.88 32.22 13.66 28 29 42.54 32.22 10.32 29 29 23.82 32.22 -8.4 29 30 19.82 32.22 -12.4 29 31 17.85 32.22 -14.37 29 32 37.48 32.22 5.26 30 32 21.58 32.22 -10.64 30 33 51.69 76.57 -24.88 30 34 68.44 76.57 -8.13 30 35 55.065 76.57 -21.505 30 36 61.89 76.57 -14.68 30 37 58.98 76.57 -17.59 30 38 49.41 76.57 -27.16 30 39 62.79 76.57 -13.78 30 40 54.44 76.57 -22.13 30 41 60.12 76.57 -16.45 30 42 40.99 76.57 -35.58 30 43 32.385 76.57 -44.185 30 44 53.78 76.57 -22.79 30 45 45.88 76.57 -30.69 30 46 42.54 76.57 -34.03 30 47 23.82 76.57 -52.75 30 48 19.82 76.57 -56.75 30 49 17.85 76.57 -58.72 30 50 37.48 76.57 -39.09 30 51 21.58 76.57 -54.99 30 52 68.44 51.69 16.75 31 52 55.065 51.69 3.375 32 52 61.89 51.69 10.2 33 52 58.98 51.69 7.29 34 52 49.41 51.69 -2.28 34 53 62.79 51.69 11.1 35 53 54.44 51.69 2.75 36 53 60.12 51.69 8.43 37 53 40.99 51.69 -10.7 37 54 32.385 51.69 -19.305 37 55 53.78 51.69 2.09 38 55 45.88 51.69 -5.81 38 56 42.54 51.69 -9.15 38 57 23.82 51.69 -27.87 38 58 19.82 51.69 -31.87 38 59 17.85 51.69 -33.84 38 60 37.48 51.69 -14.21 38 61 21.58 51.69 -30.11 38 62 55.065 68.44 -13.375 38 63 61.89 68.44 -6.55 38 64 58.98 68.44 -9.46 38 65 49.41 68.44 -19.03 38 66 62.79 68.44 -5.65 38 67 54.44 68.44 -14 38 68 60.12 68.44 -8.32 38 69 40.99 68.44 -27.45 38 70 32.385 68.44 -36.055 38 71 53.78 68.44 -14.66 38 72 45.88 68.44 -22.56 38 73 42.54 68.44 -25.9 38 74 23.82 68.44 -44.62 38 75 19.82 68.44 -48.62 38 76 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 14 Alexander Co CDLF over MSWLF Cumulative VOCs 17.85 68.44 -50.59 38 77 37.48 68.44 -30.96 38 78 21.58 68.44 -46.86 38 79 61.89 55.065 6.825 39 79 58.98 55.065 3.915 40 79 49.41 55.065 -5.655 40 80 62.79 55.065 7.725 41 80 54.44 55.065 -0.625 41 81 60.12 55.065 5.055 42 81 40.99 55.065 -14.075 42 82 32.385 55.065 -22.68 42 83 53.78 55.065 -1.285 42 84 45.88 55.065 -9.185 42 85 42.54 55.065 -12.525 42 86 23.82 55.065 -31.245 42 87 19.82 55.065 -35.245 42 88 17.85 55.065 -37.215 42 89 37.48 55.065 -17.585 42 90 21.58 55.065 -33.485 42 91 58.98 61.89 -2.91 42 92 49.41 61.89 -12.48 42 93 62.79 61.89 0.9 43 93 54.44 61.89 -7.45 43 94 60.12 61.89 -1.77 43 95 40.99 61.89 -20.9 43 96 32.385 61.89 -29.505 43 97 53.78 61.89 -8.11 43 98 45.88 61.89 -16.01 43 99 42.54 61.89 -19.35 43 100 23.82 61.89 -38.07 43 101 19.82 61.89 -42.07 43 102 17.85 61.89 -44.04 43 103 37.48 61.89 -24.41 43 104 21.58 61.89 -40.31 43 105 49.41 58.98 -9.57 43 106 62.79 58.98 3.81 44 106 54.44 58.98 -4.54 44 107 60.12 58.98 1.14 45 107 40.99 58.98 -17.99 45 108 32.385 58.98 -26.595 45 109 53.78 58.98 -5.2 45 110 45.88 58.98 -13.1 45 111 42.54 58.98 -16.44 45 112 23.82 58.98 -35.16 45 113 19.82 58.98 -39.16 45 114 17.85 58.98 -41.13 45 115 37.48 58.98 -21.5 45 116 21.58 58.98 -37.4 45 117 62.79 49.41 13.38 46 117 54.44 49.41 5.03 47 117 60.12 49.41 10.71 48 117 40.99 49.41 -8.42 48 118 32.385 49.41 -17.025 48 119 53.78 49.41 4.37 49 119 45.88 49.41 -3.53 49 120 42.54 49.41 -6.87 49 121 23.82 49.41 -25.59 49 122 19.82 49.41 -29.59 49 123 17.85 49.41 -31.56 49 124 37.48 49.41 -11.93 49 125 21.58 49.41 -27.83 49 126 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 15 Alexander Co CDLF over MSWLF Cumulative VOCs 54.44 62.79 -8.35 49 127 60.12 62.79 -2.67 49 128 40.99 62.79 -21.8 49 129 32.385 62.79 -30.405 49 130 53.78 62.79 -9.01 49 131 45.88 62.79 -16.91 49 132 42.54 62.79 -20.25 49 133 23.82 62.79 -38.97 49 134 19.82 62.79 -42.97 49 135 17.85 62.79 -44.94 49 136 37.48 62.79 -25.31 49 137 21.58 62.79 -41.21 49 138 60.12 54.44 5.68 50 138 40.99 54.44 -13.45 50 139 32.385 54.44 -22.055 50 140 53.78 54.44 -0.66 50 141 45.88 54.44 -8.56 50 142 42.54 54.44 -11.9 50 143 23.82 54.44 -30.62 50 144 19.82 54.44 -34.62 50 145 17.85 54.44 -36.59 50 146 37.48 54.44 -16.96 50 147 21.58 54.44 -32.86 50 148 40.99 60.12 -19.13 50 149 32.385 60.12 -27.735 50 150 53.78 60.12 -6.34 50 151 45.88 60.12 -14.24 50 152 42.54 60.12 -17.58 50 153 23.82 60.12 -36.3 50 154 19.82 60.12 -40.3 50 155 17.85 60.12 -42.27 50 156 37.48 60.12 -22.64 50 157 21.58 60.12 -38.54 50 158 32.385 40.99 -8.605 50 159 53.78 40.99 12.79 51 159 45.88 40.99 4.89 52 159 42.54 40.99 1.55 53 159 23.82 40.99 -17.17 53 160 19.82 40.99 -21.17 53 161 17.85 40.99 -23.14 53 162 37.48 40.99 -3.51 53 163 21.58 40.99 -19.41 53 164 53.78 32.385 21.395 54 164 45.88 32.385 13.495 55 164 42.54 32.385 10.155 56 164 23.82 32.385 -8.565 56 165 19.82 32.385 -12.565 56 166 17.85 32.385 -14.535 56 167 37.48 32.385 5.095 57 167 21.58 32.385 -10.805 57 168 45.88 53.78 -7.9 57 169 42.54 53.78 -11.24 57 170 23.82 53.78 -29.96 57 171 19.82 53.78 -33.96 57 172 17.85 53.78 -35.93 57 173 37.48 53.78 -16.3 57 174 21.58 53.78 -32.2 57 175 42.54 45.88 -3.34 57 176 23.82 45.88 -22.06 57 177 19.82 45.88 -26.06 57 178 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 16 Alexander Co CDLF over MSWLF Cumulative VOCs 17.85 45.88 -28.03 57 179 37.48 45.88 -8.4 57 180 21.58 45.88 -24.3 57 181 23.82 42.54 -18.72 57 182 19.82 42.54 -22.72 57 183 17.85 42.54 -24.69 57 184 37.48 42.54 -5.06 57 185 21.58 42.54 -20.96 57 186 19.82 23.82 -4 57 187 17.85 23.82 -5.97 57 188 37.48 23.82 13.66 58 188 21.58 23.82 -2.24 58 189 17.85 19.82 -1.97 58 190 37.48 19.82 17.66 59 190 21.58 19.82 1.76 60 190 37.48 17.85 19.63 61 190 21.58 17.85 3.73 62 190 21.58 37.48 -15.9 62 191 S Statistic = 62 - 191 = -129 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 17 Alexander Co CDLF over MSWLF Z-Score=-3.38054 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 18 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-26) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 129.48 178.04 -48.56 0 1 136.41 178.04 -41.63 0 2 160.84 178.04 -17.2 0 3 137.92 178.04 -40.12 0 4 124.62 178.04 -53.42 0 5 112.2 178.04 -65.84 0 6 128.11 178.04 -49.93 0 7 112.47 178.04 -65.57 0 8 95.58 178.04 -82.46 0 9 128.48 178.04 -49.56 0 10 133.23 178.04 -44.81 0 11 134.77 178.04 -43.27 0 12 69.28 178.04 -108.76 0 13 105.42 178.04 -72.62 0 14 106.75 178.04 -71.29 0 15 72.54 178.04 -105.5 0 16 94.62 178.04 -83.42 0 17 91.51 178.04 -86.53 0 18 60 178.04 -118.04 0 19 69.25 178.04 -108.79 0 20 56.74 178.04 -121.3 0 21 61.48 178.04 -116.56 0 22 136.41 129.48 6.93 1 22 160.84 129.48 31.36 2 22 137.92 129.48 8.44 3 22 124.62 129.48 -4.86 3 23 112.2 129.48 -17.28 3 24 128.11 129.48 -1.37 3 25 112.47 129.48 -17.01 3 26 95.58 129.48 -33.9 3 27 128.48 129.48 -1 3 28 133.23 129.48 3.75 4 28 134.77 129.48 5.29 5 28 69.28 129.48 -60.2 5 29 105.42 129.48 -24.06 5 30 106.75 129.48 -22.73 5 31 72.54 129.48 -56.94 5 32 94.62 129.48 -34.86 5 33 91.51 129.48 -37.97 5 34 60 129.48 -69.48 5 35 69.25 129.48 -60.23 5 36 56.74 129.48 -72.74 5 37 61.48 129.48 -68 5 38 160.84 136.41 24.43 6 38 137.92 136.41 1.51 7 38 124.62 136.41 -11.79 7 39 112.2 136.41 -24.21 7 40 128.11 136.41 -8.3 7 41 112.47 136.41 -23.94 7 42 95.58 136.41 -40.83 7 43 128.48 136.41 -7.93 7 44 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 19 Alexander Co CDLF over MSWLF Cumulative VOCs 133.23 136.41 -3.18 7 45 134.77 136.41 -1.64 7 46 69.28 136.41 -67.13 7 47 105.42 136.41 -30.99 7 48 106.75 136.41 -29.66 7 49 72.54 136.41 -63.87 7 50 94.62 136.41 -41.79 7 51 91.51 136.41 -44.9 7 52 60 136.41 -76.41 7 53 69.25 136.41 -67.16 7 54 56.74 136.41 -79.67 7 55 61.48 136.41 -74.93 7 56 137.92 160.84 -22.92 7 57 124.62 160.84 -36.22 7 58 112.2 160.84 -48.64 7 59 128.11 160.84 -32.73 7 60 112.47 160.84 -48.37 7 61 95.58 160.84 -65.26 7 62 128.48 160.84 -32.36 7 63 133.23 160.84 -27.61 7 64 134.77 160.84 -26.07 7 65 69.28 160.84 -91.56 7 66 105.42 160.84 -55.42 7 67 106.75 160.84 -54.09 7 68 72.54 160.84 -88.3 7 69 94.62 160.84 -66.22 7 70 91.51 160.84 -69.33 7 71 60 160.84 -100.84 7 72 69.25 160.84 -91.59 7 73 56.74 160.84 -104.1 7 74 61.48 160.84 -99.36 7 75 124.62 137.92 -13.3 7 76 112.2 137.92 -25.72 7 77 128.11 137.92 -9.81 7 78 112.47 137.92 -25.45 7 79 95.58 137.92 -42.34 7 80 128.48 137.92 -9.44 7 81 133.23 137.92 -4.69 7 82 134.77 137.92 -3.15 7 83 69.28 137.92 -68.64 7 84 105.42 137.92 -32.5 7 85 106.75 137.92 -31.17 7 86 72.54 137.92 -65.38 7 87 94.62 137.92 -43.3 7 88 91.51 137.92 -46.41 7 89 60 137.92 -77.92 7 90 69.25 137.92 -68.67 7 91 56.74 137.92 -81.18 7 92 61.48 137.92 -76.44 7 93 112.2 124.62 -12.42 7 94 128.11 124.62 3.49 8 94 112.47 124.62 -12.15 8 95 95.58 124.62 -29.04 8 96 128.48 124.62 3.86 9 96 133.23 124.62 8.61 10 96 134.77 124.62 10.15 11 96 69.28 124.62 -55.34 11 97 105.42 124.62 -19.2 11 98 106.75 124.62 -17.87 11 99 72.54 124.62 -52.08 11 100 94.62 124.62 -30 11 101 91.51 124.62 -33.11 11 102 60 124.62 -64.62 11 103 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 20 Alexander Co CDLF over MSWLF Cumulative VOCs 69.25 124.62 -55.37 11 104 56.74 124.62 -67.88 11 105 61.48 124.62 -63.14 11 106 128.11 112.2 15.91 12 106 112.47 112.2 0.27 13 106 95.58 112.2 -16.62 13 107 128.48 112.2 16.28 14 107 133.23 112.2 21.03 15 107 134.77 112.2 22.57 16 107 69.28 112.2 -42.92 16 108 105.42 112.2 -6.78 16 109 106.75 112.2 -5.45 16 110 72.54 112.2 -39.66 16 111 94.62 112.2 -17.58 16 112 91.51 112.2 -20.69 16 113 60 112.2 -52.2 16 114 69.25 112.2 -42.95 16 115 56.74 112.2 -55.46 16 116 61.48 112.2 -50.72 16 117 112.47 128.11 -15.64 16 118 95.58 128.11 -32.53 16 119 128.48 128.11 0.37 17 119 133.23 128.11 5.12 18 119 134.77 128.11 6.66 19 119 69.28 128.11 -58.83 19 120 105.42 128.11 -22.69 19 121 106.75 128.11 -21.36 19 122 72.54 128.11 -55.57 19 123 94.62 128.11 -33.49 19 124 91.51 128.11 -36.6 19 125 60 128.11 -68.11 19 126 69.25 128.11 -58.86 19 127 56.74 128.11 -71.37 19 128 61.48 128.11 -66.63 19 129 95.58 112.47 -16.89 19 130 128.48 112.47 16.01 20 130 133.23 112.47 20.76 21 130 134.77 112.47 22.3 22 130 69.28 112.47 -43.19 22 131 105.42 112.47 -7.05 22 132 106.75 112.47 -5.72 22 133 72.54 112.47 -39.93 22 134 94.62 112.47 -17.85 22 135 91.51 112.47 -20.96 22 136 60 112.47 -52.47 22 137 69.25 112.47 -43.22 22 138 56.74 112.47 -55.73 22 139 61.48 112.47 -50.99 22 140 128.48 95.58 32.9 23 140 133.23 95.58 37.65 24 140 134.77 95.58 39.19 25 140 69.28 95.58 -26.3 25 141 105.42 95.58 9.84 26 141 106.75 95.58 11.17 27 141 72.54 95.58 -23.04 27 142 94.62 95.58 -0.96 27 143 91.51 95.58 -4.07 27 144 60 95.58 -35.58 27 145 69.25 95.58 -26.33 27 146 56.74 95.58 -38.84 27 147 61.48 95.58 -34.1 27 148 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 21 Alexander Co CDLF over MSWLF Cumulative VOCs 133.23 128.48 4.75 28 148 134.77 128.48 6.29 29 148 69.28 128.48 -59.2 29 149 105.42 128.48 -23.06 29 150 106.75 128.48 -21.73 29 151 72.54 128.48 -55.94 29 152 94.62 128.48 -33.86 29 153 91.51 128.48 -36.97 29 154 60 128.48 -68.48 29 155 69.25 128.48 -59.23 29 156 56.74 128.48 -71.74 29 157 61.48 128.48 -67 29 158 134.77 133.23 1.54 30 158 69.28 133.23 -63.95 30 159 105.42 133.23 -27.81 30 160 106.75 133.23 -26.48 30 161 72.54 133.23 -60.69 30 162 94.62 133.23 -38.61 30 163 91.51 133.23 -41.72 30 164 60 133.23 -73.23 30 165 69.25 133.23 -63.98 30 166 56.74 133.23 -76.49 30 167 61.48 133.23 -71.75 30 168 69.28 134.77 -65.49 30 169 105.42 134.77 -29.35 30 170 106.75 134.77 -28.02 30 171 72.54 134.77 -62.23 30 172 94.62 134.77 -40.15 30 173 91.51 134.77 -43.26 30 174 60 134.77 -74.77 30 175 69.25 134.77 -65.52 30 176 56.74 134.77 -78.03 30 177 61.48 134.77 -73.29 30 178 105.42 69.28 36.14 31 178 106.75 69.28 37.47 32 178 72.54 69.28 3.26 33 178 94.62 69.28 25.34 34 178 91.51 69.28 22.23 35 178 60 69.28 -9.28 35 179 69.25 69.28 -0.03 35 180 56.74 69.28 -12.54 35 181 61.48 69.28 -7.8 35 182 106.75 105.42 1.33 36 182 72.54 105.42 -32.88 36 183 94.62 105.42 -10.8 36 184 91.51 105.42 -13.91 36 185 60 105.42 -45.42 36 186 69.25 105.42 -36.17 36 187 56.74 105.42 -48.68 36 188 61.48 105.42 -43.94 36 189 72.54 106.75 -34.21 36 190 94.62 106.75 -12.13 36 191 91.51 106.75 -15.24 36 192 60 106.75 -46.75 36 193 69.25 106.75 -37.5 36 194 56.74 106.75 -50.01 36 195 61.48 106.75 -45.27 36 196 94.62 72.54 22.08 37 196 91.51 72.54 18.97 38 196 60 72.54 -12.54 38 197 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 22 Alexander Co CDLF over MSWLF Cumulative VOCs 69.25 72.54 -3.29 38 198 56.74 72.54 -15.8 38 199 61.48 72.54 -11.06 38 200 91.51 94.62 -3.11 38 201 60 94.62 -34.62 38 202 69.25 94.62 -25.37 38 203 56.74 94.62 -37.88 38 204 61.48 94.62 -33.14 38 205 60 91.51 -31.51 38 206 69.25 91.51 -22.26 38 207 56.74 91.51 -34.77 38 208 61.48 91.51 -30.03 38 209 69.25 60 9.25 39 209 56.74 60 -3.26 39 210 61.48 60 1.48 40 210 56.74 69.25 -12.51 40 211 61.48 69.25 -7.77 40 212 61.48 56.74 4.74 41 212 S Statistic = 41 - 212 = -171 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 23 Alexander Co CDLF over MSWLF Z-Score =-4.48978 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 24 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (UNDGNTD) Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 66.57 161.23 -94.66 0 1 93 161.23 -68.23 0 2 180.22 161.23 18.99 1 2 99.9 161.23 -61.33 1 3 145.94 161.23 -15.29 1 4 94.55 161.23 -66.68 1 5 109.63 161.23 -51.6 1 6 118.06 161.23 -43.17 1 7 98.06 161.23 -63.17 1 8 89.36 161.23 -71.87 1 9 116.46 161.23 -44.77 1 10 93.51 161.23 -67.72 1 11 44.28 161.23 -116.95 1 12 83.59 161.23 -77.64 1 13 75.37 161.23 -85.86 1 14 69.51 161.23 -91.72 1 15 109.38 161.23 -51.85 1 16 58.09 161.23 -103.14 1 17 89.59 161.23 -71.64 1 18 78.62 161.23 -82.61 1 19 21.54 161.23 -139.69 1 20 61.83 161.23 -99.4 1 21 93 66.57 26.43 2 21 180.22 66.57 113.65 3 21 99.9 66.57 33.33 4 21 145.94 66.57 79.37 5 21 94.55 66.57 27.98 6 21 109.63 66.57 43.06 7 21 118.06 66.57 51.49 8 21 98.06 66.57 31.49 9 21 89.36 66.57 22.79 10 21 116.46 66.57 49.89 11 21 93.51 66.57 26.94 12 21 44.28 66.57 -22.29 12 22 83.59 66.57 17.02 13 22 75.37 66.57 8.8 14 22 69.51 66.57 2.94 15 22 109.38 66.57 42.81 16 22 58.09 66.57 -8.48 16 23 89.59 66.57 23.02 17 23 78.62 66.57 12.05 18 23 21.54 66.57 -45.03 18 24 61.83 66.57 -4.74 18 25 180.22 93 87.22 19 25 99.9 93 6.9 20 25 145.94 93 52.94 21 25 94.55 93 1.55 22 25 109.63 93 16.63 23 25 118.06 93 25.06 24 25 98.06 93 5.06 25 25 89.36 93 -3.64 25 26 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 25 Alexander Co CDLF over MSWLF Cumulative VOCs 116.46 93 23.46 26 26 93.51 93 0.51 27 26 44.28 93 -48.72 27 27 83.59 93 -9.41 27 28 75.37 93 -17.63 27 29 69.51 93 -23.49 27 30 109.38 93 16.38 28 30 58.09 93 -34.91 28 31 89.59 93 -3.41 28 32 78.62 93 -14.38 28 33 21.54 93 -71.46 28 34 61.83 93 -31.17 28 35 99.9 180.22 -80.32 28 36 145.94 180.22 -34.28 28 37 94.55 180.22 -85.67 28 38 109.63 180.22 -70.59 28 39 118.06 180.22 -62.16 28 40 98.06 180.22 -82.16 28 41 89.36 180.22 -90.86 28 42 116.46 180.22 -63.76 28 43 93.51 180.22 -86.71 28 44 44.28 180.22 -135.94 28 45 83.59 180.22 -96.63 28 46 75.37 180.22 -104.85 28 47 69.51 180.22 -110.71 28 48 109.38 180.22 -70.84 28 49 58.09 180.22 -122.13 28 50 89.59 180.22 -90.63 28 51 78.62 180.22 -101.6 28 52 21.54 180.22 -158.68 28 53 61.83 180.22 -118.39 28 54 145.94 99.9 46.04 29 54 94.55 99.9 -5.35 29 55 109.63 99.9 9.73 30 55 118.06 99.9 18.16 31 55 98.06 99.9 -1.84 31 56 89.36 99.9 -10.54 31 57 116.46 99.9 16.56 32 57 93.51 99.9 -6.39 32 58 44.28 99.9 -55.62 32 59 83.59 99.9 -16.31 32 60 75.37 99.9 -24.53 32 61 69.51 99.9 -30.39 32 62 109.38 99.9 9.48 33 62 58.09 99.9 -41.81 33 63 89.59 99.9 -10.31 33 64 78.62 99.9 -21.28 33 65 21.54 99.9 -78.36 33 66 61.83 99.9 -38.07 33 67 94.55 145.94 -51.39 33 68 109.63 145.94 -36.31 33 69 118.06 145.94 -27.88 33 70 98.06 145.94 -47.88 33 71 89.36 145.94 -56.58 33 72 116.46 145.94 -29.48 33 73 93.51 145.94 -52.43 33 74 44.28 145.94 -101.66 33 75 83.59 145.94 -62.35 33 76 75.37 145.94 -70.57 33 77 69.51 145.94 -76.43 33 78 109.38 145.94 -36.56 33 79 58.09 145.94 -87.85 33 80 89.59 145.94 -56.35 33 81 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 26 Alexander Co CDLF over MSWLF Cumulative VOCs 78.62 145.94 -67.32 33 82 21.54 145.94 -124.4 33 83 61.83 145.94 -84.11 33 84 109.63 94.55 15.08 34 84 118.06 94.55 23.51 35 84 98.06 94.55 3.51 36 84 89.36 94.55 -5.19 36 85 116.46 94.55 21.91 37 85 93.51 94.55 -1.04 37 86 44.28 94.55 -50.27 37 87 83.59 94.55 -10.96 37 88 75.37 94.55 -19.18 37 89 69.51 94.55 -25.04 37 90 109.38 94.55 14.83 38 90 58.09 94.55 -36.46 38 91 89.59 94.55 -4.96 38 92 78.62 94.55 -15.93 38 93 21.54 94.55 -73.01 38 94 61.83 94.55 -32.72 38 95 118.06 109.63 8.43 39 95 98.06 109.63 -11.57 39 96 89.36 109.63 -20.27 39 97 116.46 109.63 6.83 40 97 93.51 109.63 -16.12 40 98 44.28 109.63 -65.35 40 99 83.59 109.63 -26.04 40 100 75.37 109.63 -34.26 40 101 69.51 109.63 -40.12 40 102 109.38 109.63 -0.25 40 103 58.09 109.63 -51.54 40 104 89.59 109.63 -20.04 40 105 78.62 109.63 -31.01 40 106 21.54 109.63 -88.09 40 107 61.83 109.63 -47.8 40 108 98.06 118.06 -20 40 109 89.36 118.06 -28.7 40 110 116.46 118.06 -1.6 40 111 93.51 118.06 -24.55 40 112 44.28 118.06 -73.78 40 113 83.59 118.06 -34.47 40 114 75.37 118.06 -42.69 40 115 69.51 118.06 -48.55 40 116 109.38 118.06 -8.68 40 117 58.09 118.06 -59.97 40 118 89.59 118.06 -28.47 40 119 78.62 118.06 -39.44 40 120 21.54 118.06 -96.52 40 121 61.83 118.06 -56.23 40 122 89.36 98.06 -8.7 40 123 116.46 98.06 18.4 41 123 93.51 98.06 -4.55 41 124 44.28 98.06 -53.78 41 125 83.59 98.06 -14.47 41 126 75.37 98.06 -22.69 41 127 69.51 98.06 -28.55 41 128 109.38 98.06 11.32 42 128 58.09 98.06 -39.97 42 129 89.59 98.06 -8.47 42 130 78.62 98.06 -19.44 42 131 21.54 98.06 -76.52 42 132 61.83 98.06 -36.23 42 133 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 27 Alexander Co CDLF over MSWLF Cumulative VOCs 116.46 89.36 27.1 43 133 93.51 89.36 4.15 44 133 44.28 89.36 -45.08 44 134 83.59 89.36 -5.77 44 135 75.37 89.36 -13.99 44 136 69.51 89.36 -19.85 44 137 109.38 89.36 20.02 45 137 58.09 89.36 -31.27 45 138 89.59 89.36 0.23 46 138 78.62 89.36 -10.74 46 139 21.54 89.36 -67.82 46 140 61.83 89.36 -27.53 46 141 93.51 116.46 -22.95 46 142 44.28 116.46 -72.18 46 143 83.59 116.46 -32.87 46 144 75.37 116.46 -41.09 46 145 69.51 116.46 -46.95 46 146 109.38 116.46 -7.08 46 147 58.09 116.46 -58.37 46 148 89.59 116.46 -26.87 46 149 78.62 116.46 -37.84 46 150 21.54 116.46 -94.92 46 151 61.83 116.46 -54.63 46 152 44.28 93.51 -49.23 46 153 83.59 93.51 -9.92 46 154 75.37 93.51 -18.14 46 155 69.51 93.51 -24 46 156 109.38 93.51 15.87 47 156 58.09 93.51 -35.42 47 157 89.59 93.51 -3.92 47 158 78.62 93.51 -14.89 47 159 21.54 93.51 -71.97 47 160 61.83 93.51 -31.68 47 161 83.59 44.28 39.31 48 161 75.37 44.28 31.09 49 161 69.51 44.28 25.23 50 161 109.38 44.28 65.1 51 161 58.09 44.28 13.81 52 161 89.59 44.28 45.31 53 161 78.62 44.28 34.34 54 161 21.54 44.28 -22.74 54 162 61.83 44.28 17.55 55 162 75.37 83.59 -8.22 55 163 69.51 83.59 -14.08 55 164 109.38 83.59 25.79 56 164 58.09 83.59 -25.5 56 165 89.59 83.59 6 57 165 78.62 83.59 -4.97 57 166 21.54 83.59 -62.05 57 167 61.83 83.59 -21.76 57 168 69.51 75.37 -5.86 57 169 109.38 75.37 34.01 58 169 58.09 75.37 -17.28 58 170 89.59 75.37 14.22 59 170 78.62 75.37 3.25 60 170 21.54 75.37 -53.83 60 171 61.83 75.37 -13.54 60 172 109.38 69.51 39.87 61 172 58.09 69.51 -11.42 61 173 89.59 69.51 20.08 62 173 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 28 Alexander Co CDLF over MSWLF Cumulative VOCs 78.62 69.51 9.11 63 173 21.54 69.51 -47.97 63 174 61.83 69.51 -7.68 63 175 58.09 109.38 -51.29 63 176 89.59 109.38 -19.79 63 177 78.62 109.38 -30.76 63 178 21.54 109.38 -87.84 63 179 61.83 109.38 -47.55 63 180 89.59 58.09 31.5 64 180 78.62 58.09 20.53 65 180 21.54 58.09 -36.55 65 181 61.83 58.09 3.74 66 181 78.62 89.59 -10.97 66 182 21.54 89.59 -68.05 66 183 61.83 89.59 -27.76 66 184 21.54 78.62 -57.08 66 185 61.83 78.62 -16.79 66 186 61.83 21.54 40.29 67 186 S Statistic = 67 - 186 = -119 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 29 Alexander Co CDLF over MSWLF Z-Score =-3.11643 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 30 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: ALL WELLS Original Data (Not Transformed) Non -Detects Replaced with 112 DL 95% Confidence Level Xj Xk Xj - Xk Positives Negatives 342.78 562.18 -219.4 0 1 368.21 562.18 -193.97 0 2 536.03 562.18 -26.15 0 3 395.274 562.18 -166.906 0 4 452.515 562.18 -109.665 0 5 361.245 562.18 -200.935 0 6 412.981 562.18 -149.199 0 7 390.266 562.18 -171.914 0 8 333.937 562.18 -228.243 0 9 366.65 562.18 -195.53 0 10 390.529 562.18 -171.651 0 11 379.611 562.18 -182.569 0 12 237.257 562.18 -324.923 0 13 285.937 562.18 -276.243 0 14 327.426 562.18 -234.754 0 15 234.72 562.18 -327.46 0 16 307.16 562.18 -255.02 0 17 250.61 562.18 -311.57 0 18 221.43 562.18 -340.75 0 19 202.64 562.18 -359.54 0 20 177.26 562.18 -384.92 0 21 187.6 562.18 -374.58 0 22 368.21 342.78 25.43 1 22 536.03 342.78 193.25 2 22 395.274 342.78 52.494 3 22 452.515 342.78 109.735 4 22 361.245 342.78 18.465 5 22 412.981 342.78 70.201 6 22 390.266 342.78 47.486 7 22 333.937 342.78 -8.843 7 23 366.65 342.78 23.87 8 23 390.529 342.78 47.749 9 23 379.611 342.78 36.831 10 23 237.257 342.78 -105.523 10 24 285.937 342.78 -56.843 10 25 327.426 342.78 -15.354 10 26 234.72 342.78 -108.06 10 27 307.16 342.78 -35.62 10 28 250.61 342.78 -92.17 10 29 221.43 342.78 -121.35 10 30 202.64 342.78 -140.14 10 31 177.26 342.78 -165.52 10 32 187.6 342.78 -155.18 10 33 536.03 368.21 167.82 11 33 395.274 368.21 27.064 12 33 452.515 368.21 84.305 13 33 361.245 368.21 -6.965 13 34 412.981 368.21 44.771 14 34 390.266 368.21 22.056 15 34 333.937 368.21 -34.273 15 35 366.65 368.21 -1.56 15 36 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 31 Alexander Co CDLF over MSWLF Cumulative VOCs 390.529 368.21 22.319 16 36 379.611 368.21 11.401 17 36 237.257 368.21 -130.953 17 37 285.937 368.21 -82.273 17 38 327.426 368.21 -40.784 17 39 234.72 368.21 -133.49 17 40 307.16 368.21 -61.05 17 41 250.61 368.21 -117.6 17 42 221.43 368.21 -146.78 17 43 202.64 368.21 -165.57 17 44 177.26 368.21 -190.95 17 45 187.6 368.21 -180.61 17 46 395.274 536.03 -140.756 17 47 452.515 536.03 -83.515 17 48 361.245 536.03 -174.785 17 49 412.981 536.03 -123.049 17 50 390.266 536.03 -145.764 17 51 333.937 536.03 -202.093 17 52 366.65 536.03 -169.38 17 53 390.529 536.03 -145.501 17 54 379.611 536.03 -156.419 17 55 237.257 536.03 -298.773 17 56 285.937 536.03 -250.093 17 57 327.426 536.03 -208.604 17 58 234.72 536.03 -301.31 17 59 307.16 536.03 -228.87 17 60 250.61 536.03 -285.42 17 61 221.43 536.03 -314.6 17 62 202.64 536.03 -333.39 17 63 177.26 536.03 -358.77 17 64 187.6 536.03 -348.43 17 65 452.515 395.274 57.241 18 65 361.245 395.274 -34.029 18 66 412.981 395.274 17.707 19 66 390.266 395.274 -5.008 19 67 333.937 395.274 -61.337 19 68 366.65 395.274 -28.624 19 69 390.529 395.274 -4.745 19 70 379.611 395.274 -15.663 19 71 237.257 395.274 -158.017 19 72 285.937 395.274 -109.337 19 73 327.426 395.274 -67.848 19 74 234.72 395.274 -160.554 19 75 307.16 395.274 -88.114 19 76 250.61 395.274 -144.664 19 77 221.43 395.274 -173.844 19 78 202.64 395.274 -192.634 19 79 177.26 395.274 -218.014 19 80 187.6 395.274 -207.674 19 81 361.245 452.515 -91.27 19 82 412.981 452.515 -39.534 19 83 390.266 452.515 -62.249 19 84 333.937 452.515 -118.578 19 85 366.65 452.515 -85.865 19 86 390.529 452.515 -61.986 19 87 379.611 452.515 -72.904 19 88 237.257 452.515 -215.258 19 89 285.937 452.515 -166.578 19 90 327.426 452.515 -125.089 19 91 234.72 452.515 -217.795 19 92 307.16 452.515 -145.355 19 93 250.61 452.515 -201.905 19 94 221.43 452.515 -231.085 19 95 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 32 Alexander Co CDLF over MSWLF Cumulative VOCs 202.64 452.515 -249.875 19 96 177.26 452.515 -275.255 19 97 187.6 452.515 -264.915 19 98 412.981 361.245 51.736 20 98 390.266 361.245 29.021 21 98 333.937 361.245 -27.308 21 99 366.65 361.245 5.405 22 99 390.529 361.245 29.284 23 99 379.611 361.245 18.366 24 99 237.257 361.245 -123.988 24 100 285.937 361.245 -75.308 24 101 327.426 361.245 -33.819 24 102 234.72 361.245 -126.525 24 103 307.16 361.245 -54.085 24 104 250.61 361.245 -110.635 24 105 221.43 361.245 -139.815 24 106 202.64 361.245 -158.605 24 107 177.26 361.245 -183.985 24 108 187.6 361.245 -173.645 24 109 390.266 412.981 -22.715 24 110 333.937 412.981 -79.044 24 111 366.65 412.981 -46.331 24 112 390.529 412.981 -22.452 24 113 379.611 412.981 -33.37 24 114 237.257 412.981 -175.724 24 115 285.937 412.981 -127.044 24 116 327.426 412.981 -85.555 24 117 234.72 412.981 -178.261 24 118 307.16 412.981 -105.821 24 119 250.61 412.981 -162.371 24 120 221.43 412.981 -191.551 24 121 202.64 412.981 -210.341 24 122 177.26 412.981 -235.721 24 123 187.6 412.981 -225.381 24 124 333.937 390.266 -56.329 24 125 366.65 390.266 -23.616 24 126 390.529 390.266 0.263 25 126 379.611 390.266 -10.655 25 127 237.257 390.266 -153.009 25 128 285.937 390.266 -104.329 25 129 327.426 390.266 -62.84 25 130 234.72 390.266 -155.546 25 131 307.16 390.266 -83.106 25 132 250.61 390.266 -139.656 25 133 221.43 390.266 -168.836 25 134 202.64 390.266 -187.626 25 135 177.26 390.266 -213.006 25 136 187.6 390.266 -202.666 25 137 366.65 333.937 32.713 26 137 390.529 333.937 56.592 27 137 379.611 333.937 45.674 28 137 237.257 333.937 -96.68 28 138 285.937 333.937 -48 28 139 327.426 333.937 -6.511 28 140 234.72 333.937 -99.217 28 141 307.16 333.937 -26.777 28 142 250.61 333.937 -83.327 28 143 221.43 333.937 -112.507 28 144 202.64 333.937 -131.297 28 145 177.26 333.937 -156.677 28 146 187.6 333.937 -146.337 28 147 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 33 Alexander Co CDLF over MSWLF Cumulative VOCs 390.529 366.65 23.879 29 147 379.611 366.65 12.961 30 147 237.257 366.65 -129.393 30 148 285.937 366.65 -80.713 30 149 327.426 366.65 -39.224 30 150 234.72 366.65 -131.93 30 151 307.16 366.65 -59.49 30 152 250.61 366.65 -116.04 30 153 221.43 366.65 -145.22 30 154 202.64 366.65 -164.01 30 155 177.26 366.65 -189.39 30 156 187.6 366.65 -179.05 30 157 379.611 390.529 -10.918 30 158 237.257 390.529 -153.272 30 159 285.937 390.529 -104.592 30 160 327.426 390.529 -63.103 30 161 234.72 390.529 -155.809 30 162 307.16 390.529 -83.369 30 163 250.61 390.529 -139.919 30 164 221.43 390.529 -169.099 30 165 202.64 390.529 -187.889 30 166 177.26 390.529 -213.269 30 167 187.6 390.529 -202.929 30 168 237.257 379.611 -142.354 30 169 285.937 379.611 -93.674 30 170 327.426 379.611 -52.185 30 171 234.72 379.611 -144.891 30 172 307.16 379.611 -72.451 30 173 250.61 379.611 -129.001 30 174 221.43 379.611 -158.181 30 175 202.64 379.611 -176.971 30 176 177.26 379.611 -202.351 30 177 187.6 379.611 -192.011 30 178 285.937 237.257 48.68 31 178 327.426 237.257 90.169 32 178 234.72 237.257 -2.537 32 179 307.16 237.257 69.903 33 179 250.61 237.257 13.353 34 179 221.43 237.257 -15.827 34 180 202.64 237.257 -34.617 34 181 177.26 237.257 -59.997 34 182 187.6 237.257 -49.657 34 183 327.426 285.937 41.489 35 183 234.72 285.937 -51.217 35 184 307.16 285.937 21.223 36 184 250.61 285.937 -35.327 36 185 221.43 285.937 -64.507 36 186 202.64 285.937 -83.297 36 187 177.26 285.937 -108.677 36 188 187.6 285.937 -98.337 36 189 234.72 327.426 -92.706 36 190 307.16 327.426 -20.266 36 191 250.61 327.426 -76.816 36 192 221.43 327.426 -105.996 36 193 202.64 327.426 -124.786 36 194 177.26 327.426 -150.166 36 195 187.6 327.426 -139.826 36 196 307.16 234.72 72.44 37 196 250.61 234.72 15.89 38 196 221.43 234.72 -13.29 38 197 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 34 Alexander Co CDLF over MSWLF Cumulative VOCs 202.64 234.72 -32.08 38 198 177.26 234.72 -57.46 38 199 187.6 234.72 -47.12 38 200 250.61 307.16 -56.55 38 201 221.43 307.16 -85.73 38 202 202.64 307.16 -104.52 38 203 177.26 307.16 -129.9 38 204 187.6 307.16 -119.56 38 205 221.43 250.61 -29.18 38 206 202.64 250.61 -47.97 38 207 177.26 250.61 -73.35 38 208 187.6 250.61 -63.01 38 209 202.64 221.43 -18.79 38 210 177.26 221.43 -44.17 38 211 187.6 221.43 -33.83 38 212 177.26 202.64 -25.38 38 213 187.6 202.64 -15.04 38 214 187.6 177.26 10.34 39 214 S Statistic = 39 - 214 = -175 Tied GroulValue Members Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 6/18/2019 1 12/17/2019 1 7/15/2020 1 There are 0 time periods with multiple data A B=0 C=0 D=0 E=0 F=0 a = 25806 b = 95634 c = 1012 Group Variance = 1433.67 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 35 Alexander Co CDLF over MSWLF Z-Score =-4.59542 Comparison Level at 95% confidence level =-1.65463 (downward trend) Cumulative VOCs Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 36