2020.10.23_CCO.p11.2_SedimentCharacterizationReport

SEDIMENT
CHARACTERIZATION REPORT

Prepared for
The Chemours Company FC, LLC
22828 NC Highway 87 Fayetteville, NC 28306

Prepared by
Geosyntec Consultants of NC, P.C.
2501 Blue Ridge Road, Suite 430
Raleigh, NC 27607
Geosyntec Project Number TR0795

October 2020
DocuSign Envelope ID: 8800A63A-E749-4873-B884-70B4A6EC7363

TR0795A ii October 2020
TABLE OF CONTENTS
EXECUTIVE SUMMARY ........................................................................................... viii
1 INTRODUCTION ................................................................................................ 1
2 SETTING AND APPROACH .............................................................................. 2
3 SCOPE AND METHODS .................................................................................... 3
3.1 Sampling Locations ..................................................................................... 4
3.2 Sampling Methods ....................................................................................... 4
3.2.1 Sediment Sampling Procedures....................................................... 4
3.2.2 Surface Water Sampling Procedures ............................................... 5
3.3 Analytical Methods...................................................................................... 6
3.4 Sampling Conditions ................................................................................... 6
4 SAMPLING RESULTS........................................................................................ 7
4.1 Data Quality ................................................................................................. 7
4.2 Analysis of Cape Fear River Sediment ........................................................ 9
4.2.1 Geotechnical Properties in Sediment .............................................. 9
4.2.2 Cape Fear River Table 3+ PFAS in Sediment .............................. 10
4.2.3 Cape Fear River Method 537M PFAS in Sediment ...................... 10
4.3 Analysis of Cape Fear River Surface Water .............................................. 11
4.3.1 Cape Fear River Table 3+ PFAS Sampling Results ..................... 11
4.3.2 Cape Fear River Method 537M PFAS Sampling Results ............. 12
5 DISCUSSION ..................................................................................................... 12
5.1 Cape Fear River Sediment Grainsize and TOC Data ................................ 13
5.2 Table 3+ and Method 537M PFAS Distribution in Sediment ................... 14
5.3 Table 3+ and Method 537M PFAS Distribution in Surface Water ........... 15
5.4 Comparison of Sediment Results to Human Health and Ecological Screening Level Exposure Assessments ............................................................. 17
5.4.1 Data Comparison: Human Health SLEA ..................................... 17
5.4.2 Ecological SLEA Data Comparison.............................................. 20
6 SUMMARY ........................................................................................................ 22
7 REFERENCES ................................................................................................... 24

TR0795A iii October 2020

LIST OF TABLES
Table 1: Summary of Sediment Samples Collected
Table 2: Summary of Surface Water Samples Collected
Table 3: Summary of Field-Collected Surface Water Parameters
Table 4: River Conditions During Sampling and Surface Water Table 3+ Mass
Discharge
Table 5A: Sediment Table 3+ PFAS Analytical Results
Table 5B: Sediment Method 537M PFAS Analytical Results
Table 5C: Sediment Geotechnical Data Results
Table 6A: Surface Water Table 3+ PFAS Analytical Results
Table 6B: Surface Water Method 537M PFAS Analytical Results
Table 6C: Other Surface Water Analytical Results
Table 7: HFPO-DA Surface Water Data Comparison Between Human Health SLEA and Sediment Characterization
Table 8: HFPO-DA Concentrations in Cape Fear River Sediment
Table 9: Comparison of Table 3+ PFAS Profiles: Sediment Characterization vs. Ecological SLEA

TR0795A iv October 2020
LIST OF FIGURES
Figure 1: Cape Fear River Watershed and Downstream Drinking Water Intakes
Figure 2: Site Location Map
Figure 3a: Sampling Segments CFR-RM-20
Figure 3b: Sampling Segments CFR-RM-52
Figure 3c: Sampling Segments CFR-RM-76 and CFR-RM-77
Figure 3d: Sampling Segments CFR-RM-84
Figure 3e: Sampling Segments CFR-RM-100
Figure 3f: Sampling Segments CFR-RM-116
Figure 3g: Sampling Segments CFR-RM-132
Figure 3h: Sampling Segments CFR-RM-149
Figure 4: Cape Fear River Flow and Precipitation at Lillington, Lock and Dam #3, and Lock and Dam #1
Figure 5: PFAS Compounds Detected in Sediment above Reporting Limits
Figure 6a: PFAS Analytes Detected in Surface Water above Reporting Limits
Figure 6b: PFAS Mass Discharge for Analytes Detected in Surface Water above Reporting Limits
Figure 7a: Sediment Grain Size Distribution
Figure 7b: Correlation between TOC, Clay, and Silt in Bank and Mid-channel Sample
Figure 7c: Sediment Grain Size and TOC Data
Figure 7d: Sediment Grain Size and PFAS Data
Figure 7e: Sediment Grain Size, TOC, and PFAS Data
Figure 8: River Mixing Profiles and HFPO-DA Plots
Figure 9: River Mixing Profiles and PFAS Plots

LIST OF APPENDICES
Appendix A: Field Forms
Appendix B: Laboratory white books and reports

TR0795A v October 2020
ACRONYMS AND ABBREVIATIONS
ASTM American Society for Testing and Materials
CFRW Cape Fear River Watch
cfs cubic feet per second
CTE central tendency exposure
DO dissolved oxygen
DQOs data quality objectives
DVM data verification module
EIM Environnemental Information Management
EPC Exposure Point Concentration
EU Exposure Unit
HFPO-DA hexafluoropropylene oxide dimer acid
HHSLEA Human Health Ecological Screening Level Exposure
Assessment
HQ Hazard quotients
NCDEQ North Carolina Department of Environmental Quality
NCDHHS North Carolina Department of Health and Human Services
ng/L nanograms per liter
µg/kg micrograms per kilogram
NVHOS perfluoromethoxysulfonic acid
ORP oxygen/reduction potential
Parsons Parsons of NC
PFAS per- and polyfluoroalkyl substances
PFMOAA perfluoro-2-methoxyaceticacid
PFOA perfluorooctanoic acid
PFOS perfluorooctane Sulfonate
PFO2HxA perfluoro(3,5-dioxahexanoic) acid
PFO3OA perfluoro(3,5,7-trioxaoctanoic) acid

TR0795A vi October 2020
PFO4DA perfluoro(3,5,7,9-tetraoxadecanoic) acid
PFO5DA perfluoro-3,5,7,9,11-pentaoxadodecanoic acid
PMPA perfluoromethoxypropyl carboxylic acid
POTW publicly owned treatment works
PS Acid phosphatidylserine
R-PSDA ethanesulfonic acid,
1,1,2,2-tetrafluoro-2 -1,2,2,3,3-pentafluoro-1-(trifluoromethyl)
propoxy
RME Reasonable Maximum Exposure
RPD relative percent differences
SLEA Screening Level Exposure Assessment
SOP standard operating procedure
TOC Total organic carbon
USEPA United States Environmental Protection Agency
USGS United States Geologic Society
WWTP wastewater treatment plant

TR0795A vii October 2020
EXECUTIVE SUMMARY
This report was prepared by Geosyntec Consultants of NC, P.C. (Geosyntec) for The
Chemours Company, FC, LLC (Chemours) pursuant to Paragraph 11.2 of the executed
Consent Order (CO) dated 25 February 2019 among the North Carolina Department of
Environmental Quality (NCDEQ), Cape Fear River Watch (CFRW), and the Chemours
Company FC, LLC (Chemours). Paragraph 11.2 requires an assessment of the nature and
extent of perfluoroalkyl and polyfluoroalkyl substances (PFAS) in sediment in the Cape
Fear River originating from the Facility.
PFAS are a category of chemicals comprised of many thousands of compounds (Wang et
al., 2017). PFAS compounds are widely detected in environmental samples across the
country and are introduced into watersheds via common sources including discharge from
industrial processes, effluent from wastewater treatment plants, leachate from landfills,
and releases of firefighting foams (ITRC, 2020; Hu et al., 2016). This sampling program
evaluated the nature and extent of PFAS in the Cape Fear River which can be analyzed
by two methods currently available: Method 537M and the Table 3+ Method. Method
537M PFAS compounds are often associated with effluents from wastewater treatment
plants and firefighting foams, amongst other sources. Table 3+ Method PFAS compounds
are often related to operations at the Chemours Fayetteville Works Site (the Site).
Surface water and sediment samples were collected in the Cape Fear River from nine
transects along the length of the River in May and June 2020 to evaluate PFAS
concentrations upstream of, adjacent to, and downstream of the Site. Sediment and
surface water samples were analyzed by the Table 3+ Method and Method 537M.
Sediment samples were also analyzed for geotechnical properties including grainsize and
total organic carbon content.
Sediment samples were collected from riverbank and mid-channel River segments. A
higher relative percentage of fine-grained sediment was found in riverbank samples
compared mid-channel samples (see inset figure below), consistent with expected river
dynamics where banks with lower water velocities are more depositional than thalweg1
areas with higher water velocities. Higher fines contents were also associated with higher
total organic carbon contents. Many compounds preferentially adsorb to finer grained
sediments (often the total organic carbon component), which makes grain size

1 The thalweg is a line connecting the deepest points of successive cross-sections along the course of a
river.

TR0795A viii October 2020
distributions and total organic carbon concentrations indicators of areas with potential
sediment impacts (ITRC, 2014).
The inset figure below shows PFAS detections were generally found in finer grained
sediment with higher total organic carbon concentrations. Method 537M PFAS were
detected above reporting limits in sediment from all nine transects; Table 3+ PFAS were
detected above reporting limits in sediment in three transects, which were located
alongside the Site and in a depositional area downstream of the Site.

Sediment Grain Size, Total Organic Carbon, and PFAS Data
Method 537M PFAS have been identified in upstream sources collected by NCDEQ and
the PFAST Network (NCDEQ, 2020; PFAST Network, 2020). In general, the presence
of Method 537M PFAS in the watershed is consistent with known patterns of PFAS
contributions to watersheds from upgradient sources such as effluent from wastewater
treatment plants, leachate from landfills, and releases of firefighting foams (ITRC, 2020;
Hu et al., 2016). In this program, Method 537M PFAS were detected in surface water
above reporting limits at each sampling transect. The total concentration of Method 537M
PFAS did not change meaningfully upstream or downstream of the Site. Past
investigations conducted by Chemours have also demonstrated that Method 537M PFAS
do not increase in concentration from immediately upstream to downstream of the Site
(Geosyntec, 2018). Table 3+ PFAS were detected in surface water above reporting limits
at each sampling transect with concentrations becoming highest downstream of the Site

TR0795A ix October 2020
where Site inputs of Table 3+ PFAS to the Cape Fear River are well mixed across the
river water column.
The sediment and surface water samples collected in this program were compared to data
collected and interpretations made in the 2019 Human Health and Ecological SLEAs
(Geosyntec, 2019a). The results of this program are consistent with the findings of the
SLEAs that, based on presently available information for HFPO-DA exposures
quantified, there are no anticipated hazards to human or ecological receptors from
exposures to HFPO-DA in surface water or sediment. Concentrations of HFPO-DA were
below the 140 ng/L HFPO-DA provisional health goal (NCDEQ and North Carolina
Department of Health and Human Services [NCDHHS], 2018). Additionally, in the Cape
Fear River, the combined concentrations of PFOA and PFOS (Method 537M) in surface
water from all locations sampled in this program were below the 70 ng/L USEPA
Lifetime Health Advisory level (USEPA, 2016b, 2016c).

TR0795 1 October 2020
1 INTRODUCTION
Geosyntec Consultants of NC, P.C. (Geosyntec) has prepared this Sediment
Characterization report for The Chemours Company, FC, LLC (Chemours) pursuant to
requirements of Paragraph 11.2 of the executed Consent Order (CO) among Chemours,
North Carolina Department of Environmental Quality (NCDEQ) and Cape Fear River
Watch (CFRW) dated 25 February 2019. Chemours operates the Fayetteville Works
facility in Bladen County, North Carolina (the Site).
In August 2019, pursuant to requirements of CO Paragraph 11.2, Geosyntec developed a
plan to assess the nature and extent of per- and polyfluoroalkyl substances (PFAS)
contamination originating from the Site in Cape Fear River sediments; the Plan was
amended following one round of comments by NCDEQ and accepted by NCDEQ in April
2020 (Sediment Characterization Plan, Geosyntec, 2020a). This Characterization Plan
included the selection of transects for collection of sediment and surface water samples
upstream, adjacent to, and downstream of the Site, as well as near raw water intakes of
downstream public water utilities. The Sediment Characterization Plan described the
intended sampling locations and methods.
The objective of this Sediment Characterization Report is to describe the findings of
surface water and sediment samples collected during the Sediment Characterization
(referred to herein as “this program”) of the Cape Fear River. Data collected were used
to assess Total Table 3+ and Method 537M per- and polyfluoroalkyl substances (PFAS)
in the Cape Fear River sediment and surface water. The Table 3+ Method was developed
by Chemours and its analytical laboratory partners. Certain compounds analyzed by the
Table 3+ method were identified by non-targeted analysis of samples collected from the
Site; non-targeted analysis is a specialized analytical approach that evaluates samples for
the presence of unknown compounds. Based on the non-targeted analysis results, the
Table 3+ method was then developed to enable a targeted analytical method to analyze
for these PFAS. Presently, the grouping of PFAS referred to as Table 3+ are analyzed by
the Table 3+ Method, and PFAS referred to as Method 537M are analyzed by a
modification to the EPA Method 537.
The remainder of this report is organized as follows:
• Setting and Approach – This section describes the approach used to achieve the
CO objectives for the Sediment Characterization and the reason for selecting each
sampling transect in the Cape Fear River;
• Scope and Methods – This section describes the sampling performed and
methods used in the sampling activities;

TR0795 2 October 2020
• Sampling Results – This section presents the results of the Cape Fear River
Table 3+ PFAS and Method 537M sampling in Sediment and Surface Water;
• Discussion of Sampling Results – This section describes river sediment transport
dynamics, then analyzes the results of Cape Fear River sediment and surface water
sampling results including sediment grainsize, Total organic carbon (TOC) and
PFAS data, and provides an interpretation of results with regard to the Human
Health and Ecological Screening Level Exposure Assessments (SLEAs); and
• Summary – This section summarizes the objectives and findings of this report.
2 SETTING AND APPROACH
The Cape Fear River flows 191 miles from its start at the confluence of the Deep and
Haw Rivers to its mouth in the Atlantic Ocean near the city of Wilmington, NC (Figure 1).
Along its course, the Cape Fear River receives contributions from a variety of sources
including the Little River, various creeks, direct groundwater discharge to the Cape Fear
River, and discharges from multiple publicly owned treatment works (POTWs). The Site
is located approximately 76 miles from the confluence of the Deep and Haw Rivers
(Figure 2).
The objective of this Characterization was to assess the nature and extent of PFAS
originating from the Site to Cape Fear River sediments. To achieve this objective, samples
were collected from Cape Fear River sediments and surface water in upstream,
Site-adjacent, and downstream reaches of the Cape Fear River. This approach was
detailed in the NCDEQ-approved Sediment Characterization Plan (Geosyntec, 2020a).
Nine transects (Figure series 3a-h) were selected for sampling; the reason for selecting
each transect is as follows:
• Cape Fear River Mile 202: Intended to be collected near the surface water sample
collected at River Mile 20 in June 2018. This transect was selected to be
representative of background conditions. It is located near United States Geologic
Society (USGS) Stream Gage 02102500 and Harnett County's drinking water
intake.
• Cape Fear River Mile 52: Intended to be collected near the surface water sample
collected at River Mile 52 in June 2018. This transect was selected to be

2 River miles are numbered from upstream to downstream. River Mile Zero corresponds with the beginning of the Cape Fear River.

TR0795 3 October 2020
representative of background conditions. It is located near the City of
Fayetteville's drinking water intake.
• Cape Fear River Mile 76: Transect collected directly upstream of the confluence
with Willis Creek. This transect was intended to be collected near the CFR-05
surface water samples collected September 2017 and May 2018. This transect is
considered adjacent to the Site.
• Cape Fear River Mile 77: Transect located immediately downstream of Outfall
002, upstream of dam. This transect is considered adjacent to the Site.
• Cape Fear River Mile 84: Intended to be collected near the surface water sample
collected at River Mile 84 in June 2018 in which the highest concentration of
Hexafluoropropylene Oxide Dimer Acid (HFPO-DA) was detected above
reporting limits during the June 2018 surface water sampling event. This transect
is downstream of Site; and located upstream of and within 1,000 feet of the Bladen
Bluff Drinking Water Intake (River Mile 84.8).
• Cape Fear River Mile 100: Intended to be collected near the surface water sample
collected at River Mile 100 in June 2018. This transect is downstream of Site. The
Elizabethtown Wastewater Treatment Plant (WWTP) outfall discharge is located
near this sample.
• Cape Fear River Mile 116: Intended to be collected near the surface water sample
collected at River Mile 116 in June 2018. This transect is downstream of Site.
• Cape Fear River Mile 132: Intended to be collected near the surface water sample
collected at River Mile 132 in June 2018. This transect is downstream of Site.
Sample co-located with the Kings Bluff Intake Canal operated by the Lower Cape
Fear Sewer and Water Authority and distributes water to CFPUA (New Hanover
county), Brunswick County and Pender County.
• Cape Fear River Mile 149: Located downstream of Cape Fear River Lock and
Dam #1 and Kings Bluff Intake Canal, located 42 miles upstream from where the
Cape Fear River empties into the Atlantic Ocean. This transect is 72 river miles
downstream of Site.
3 SCOPE AND METHODS
For this Characterization, sampling was conducted by Geosyntec and Parsons of NC
(Parsons) staff in May and June 2020. The scope of the sampling programs and methods
employed to collect field data are summarized below.

TR0795 4 October 2020
3.1 Sampling Locations
Transect locations were field-adjusted so at least one sample along each transect was
confirmed to contain at least 20% fine-grained material (confirmed by field-sieving with
a #200 mesh screen). Each transect was then divided into three segments. Facing
upstream, the left bank segment was given an “A” designation, the mid-channel segment
was given a “B” designation and, and the right bank segment was given a “C” designation
(Figure series 3a-h). Collectively samples from “A” and “C” segments are referred to as
bank samples while samples from the “B” segments are referred to as mid-channel
samples.
Water column samples were collected from the mid-channel segment (“B” designation)
in each transect. Where water depths exceeded 3 feet, two water column samples were
collected, one from one to two feet above the sediment surface, and one from the
approximate midpoint of the water column (this occurred at 7 transects; Table 2). Where
water depths were shallower than 3 feet, one water column sample was collected from
the approximate midpoint of the water column (this occurred at two transects; Table 2).
Surficial sediment samples were collected from each segment along each transect (“A”,
“B”, and “C” designations). Samples were collected from the sediment surface to a depth
of approximately four inches.
Transects were located in the main Cape Fear River channel except for the transect at
River Mile 149, which was located in a secondary flow channel from the main channel.
Sampling segments are shown in Figure series 3a-h. Sample segment coordinates, which
were recorded by a Garmin Glo GPS unit, are provided in Table 1.
3.2 Sampling Methods
3.2.1 Sediment Sampling Procedures
Sediment sampling was conducted in general accordance with United States
Environmental Protection Agency (USEPA) standard operating procedure (SOP)
SESDPROC-200-R3 Sediment Sampling (USEPA, 2014) and the approved
Characterization Plan (Geosyntec, 2020a).
Sediment samples were collected from all segments with a Wildco® stainless steel petite
ponar (referred to herein as a ponar), except for one sample which was composed of tight
clay which the ponar could not penetrate; this sample was hand collected from sediment
just above the waterline using a stainless-steel spoon (River Mile 116, segment “A”). At
the request of NCDEQ, duplicate samples from three segments were additionally

TR0795 5 October 2020
collected using a push-tube device (River Miles 76, 84, and 149). Split samples were
collected at River Miles 52 and 149 using a ponar. Additional material was collected from
sediment segments collected from “A”, “B”, and “C” segments from River Miles 100,
116, and 149 for split sampling with NCDEQ.
Sediment samples were collected from the sediment surface to a depth of approximately
4 inches below the sediment surface. The minimum acceptable recovery was two inches
of material depth retained in the sampler for a grab sample to be retained for compositing.
Multiple grab samples were collected using the specified sampling device to obtain
sufficient material to satisfy sample volume requirements as specified in the
Characterization Plan (Geosyntec, 2020a). The grab samples were composited together
in a decontaminated stainless-steel container and homogenized using a decontaminated
stainless-steel spoon prior to filling sample bottles. Large materials present in the
sediment (e.g., gravel, vegetation) were avoided when filling sample bottles. Sediment
texture and other relevant observations were noted on field forms (Appendix A). Each
sampling container was capped, labeled, and stored on ice (4 ± 2°C). Sampling details are
provided in Table 1.
3.2.2 Surface Water Sampling Procedures
Water column sampling was conducted in general accordance with USEPA SOP
SESDPROC-201-R4 Surface Water Sampling (USEPA, 2016a) and the approved
Characterization Plan (Geosyntec, 2020a). Water column samples were collected from
the mid-channel (“B”) segment of each transect and were collected prior to sediment
sample collection at the same segment. Sampling details are provided in Table 2.
Sampling depths were selected as described in Section 3.1. A total of 16 surface water
samples were collected.
Water column samples were collected using a peristaltic pump, new dedicated
high-density polyethylene tubing, and new dedicated silicone tubing for the pump head
at each sample. The tubing was lowered to the sampling depth using an anchor weight
and the fastened tubing was pointed upwards at the tubing intake. Surface water was
pumped directly from the submerged tubing through the pump head to a flow-through
cell. Field parameters (turbidity, pH, temperature, specific conductance, dissolved
oxygen [DO], oxygen/reduction potential [ORP]) were recorded until parameters
stabilized (Table 3). The flow-through cell was then disconnected, the end of the tubing
previously connected to the flow-through cell was cut off, and grab samples were
collected from the discharge of the peristaltic pump into new, laboratory-supplied
bottleware. Each sampling container was capped, labeled, and stored on ice (4 ± 2°C).

TR0795 6 October 2020
3.3 Analytical Methods
Sediment samples were analyzed by the following methods:
• PFAS by Method 537M and Table 3+;
• Grain size by American Society for Testing and Materials (ASTM) D422-63;
• Moisture content by ASTM D2216-90; and
• TOC by Lloyd Khan.
Water column samples were analyzed by the following methods:
• PFAS compounds by Method 537M and Table 3+;
• Total suspended solids by ASTM 2540 D-1997; and
• Dissolved organic carbon and TOC by SW-846 9060A.
Samples were shipped to either Eurofins Lancaster Laboratories, Inc. or TestAmerica
Laboratories, Inc. for analysis.
3.4 Sampling Conditions
Surface water and sediment sampling was intended to target base flow conditions, and
the Work Plan stated sampling would not occur within 72 hours of a rain event. Base flow
conditions were further defined as no more than 0.3 inches of cumulative rainfall over the
preceding 72 hours3 and a gage height specified at the nearest USGS gage coinciding
with typical base flow conditions4.
As a result of several rain events which occurred during the sampling schedule, sampling
was delayed several times and was conducted over a span of 43 days (Tables 1 and 2);
additionally, samples were not always collected sequentially upstream to downstream.
The results presented herein should be viewed with the consideration that the samples
were collected over this timespan. During the 43 day period, River flow rates ranged from
678 to 26,194 cubic feet per second (cfs); sampling was conducted during flow rates of

3 as measured at the nearest Cape Fear River rain gage. Baseline conditions were monitored according to
the USGS website for W.O. Huske Lock (STPN7) and Lock & Dam #1 (CPFN7). Forecasted precipitation
for each location was monitored according to the USGS National Water Information System website for
W.O. Huske Lock (02105500) and Lock & Dam #1 (02105769).
4 Flow rates used were measured at the nearest gage. The flow rates corresponding to stage heights of
approximately 4.5 feet for the W.O. Huske Dam and 17.9 feet at Lock & Dam #1.

TR0795 7 October 2020
approximately 700 to approximately 8,900 cfs (Figure 4; Table 4). Sampling dates and
other details for each sampling segment are provided in Tables 1 and 2, and a summary
of Cape Fear River flow rates is provided in Table 4.
4 SAMPLING RESULTS
This section presents results from the sampling activities described in Section 3.
Specifically, this section describes data quality regarding data included in this report and
then describes the analytical and geotechnical results from the sampling program.
4.1 Data Quality
The analytical data were reviewed using the Data Verification Module (DVM) within the
Locus™ Environmental Information Management (EIM) system, a commercial software
program used to manage data. Following the DVM process, a manual review of the data
was conducted. The DVM and the manually reviewed results were combined in a data
review narrative report for each set of sample results, which were consistent with Stage 2b
of the USEPA Guidance for Labeling Externally Validated Laboratory Analytical Data
for Superfund Use (USEPA-540-R-08-005, 2009). The narrative report summarizes
which samples were qualified (if any), the specific reasons for the qualification, and any
potential bias in reported results (Appendix B). The data usability, in view of the project’s
data quality objectives (DQOs), was assessed, and the data were entered into the EIM
system.
The data were evaluated by the DVM against the following data usability checks:
• Hold time criteria;
• Field and laboratory blank contamination;
• Completeness of quality assurance/quality control samples;
• Matrix spike/matrix spike duplicate recoveries and the relative percent differences
(RPD) between these spikes;
• Laboratory control sample/control sample duplicate recoveries and the RPD
between these spikes;
• Surrogate spike recoveries for organic analyses; and
• RPD between field duplicate sample pairs.
A manual review of the data was also conducted, which included a review of
instrument-related quality control results for calibration standards, blanks, and recoveries.

TR0795 8 October 2020
The data review process (DVM plus manual review) applied the following data
evaluation qualifiers to the analytical results as required:
• J Analyte present, reported value may not be accurate or precise;
• UJ Analyte not present below the reporting limit, reporting limit may not be
accurate or precise; and
• B Analyte present in a blank sample, reported value may have a high bias.
Results are reported in the data validation white book (Appendix B).
Following the automated and manual data validation reported in the white book,
additional manual validation was conducted:
• Chromatograms for all analytes in all field samples were reviewed for peak shape
and retention time against the peak shape and retention time of the appropriate
standards;
• Calibration for PMPA and PFMOAA were verified (recalculated);
• Approximately 10% of the PMPA and PFMOAA detections in the field samples
were verified (recalculated);
• Non-detects for all compounds were verified via visual examination of the
chromatograms.
This additional manual validation revealed no further data quality issues.
The DQOs were met for the analytical results for accuracy and precision. The data
collected are believed to be complete, representative and comparable, with the exception
of three compounds: R-PSDA, Hydrolyzed PSDA, and R-EVE. As reported in the Matrix
Interference During Analysis of Table 3+ Compounds memorandum (Geosyntec, 2020b),
matrix interference studies conducted by the analytical laboratory (TestAmerica
Laboratories, Inc., Sacramento) have shown that the quantitation of these three
compounds (R-PSDA, Hydrolyzed PSDA, and R-EVE) is inaccurate due to interferences
by the sample matrix, and that the interference results in over-estimation of these
concentrations. Consequently, all results above the reporting limit for R-PSDA,
Hydrolyzed PSDA, and R-EVE in the sediment and surface water results have been J-
qualified as estimated.
Given the matrix interference issues, Total Table 3+ PFAS concentrations are calculated
and presented two ways in this report: (i) summing over 17 of the 20 Table 3+ compounds
“Total Table 3+ (sum of 17 compounds)”, i.e., excluding results of R-PSDA, Hydrolyzed

TR0795 9 October 2020
PSDA, and R-EVE, and (ii) summing over 20 of the Table 3+ compounds “Total
Table 3+ (sum of 20 compounds)”. Expressing these data as a range represents possible
values of what these results might be without matrix interferences. In other words, the
sum of the 17 compounds is an underestimate of the actual value while the sum of the 20
compounds is likely an overestimate of the actual value.
HFPO-DA can be analyzed by either Method 537M or by the Table 3+ Method. The
laboratory selects the method depending on their current analyte lists; results from both
methods are considered accurate and comparable. For this sample set, HFPO-DA was
analyzed in some samples by Method 537M and in some samples by both methods. If
HFPO-DA was measured by both methods, the reported concentration was determined as
follows: the higher concentration was reported when both results were detected above
reporting limits; the detected value was reported when one result was detected and the
other was a not detected above reporting limits, and; the lower reporting limit was
reported when both results were not detected above reporting limits. In this Report,
regardless of the method used for analysis, HFPO-DA is grouped with Table 3+
compounds for totaling concentrations in tables and figures in order to be consistent with
past reports.
4.2 Analysis of Cape Fear River Sediment
Samples collected in this program were intended to be collected during baseline
conditions (see Section 3.4), and as a result, samples were collected over approximately
six weeks. The Cape Fear River flow varied during the sampling period (Figure 4).
Sampling dates, flow conditions, concentrations at each segment, and surface water mass
discharge are provided in Table 3. Sampling results are provided in Tables 5A, 5B, and
5C.
4.2.1 Geotechnical Properties in Sediment
Sediment samples ranged from 97% coarse grained (sand + gravel fractions), at the mid-
channel segment at River Mile 76 to 11% coarse grained (89% fine grained) in the
secondary channel where River Mile 149 was collected (“C” segment; Table 5C). In
general, samples collected in the mid-channel segments contained coarser grained
material than samples collected along bank (“A” and “C”) segments.
TOC ranged from below the reporting limit at mid-channel segments at River Mile 77
and River Mile 132 to 33,000 mg/kg at River Mile 116 (“C” segment). TOC was generally
observed to be higher in bank (“A” and “C”) segment samples than in mid-channel (“B”)
segment samples (Table 5C). Transects with the highest TOC content (River Miles 76,

TR0795 10 October 2020
77, and 149) were also the transects with the highest fines contents (River Miles 76, 77,
84, and 149).
4.2.2 Cape Fear River Table 3+ PFAS in Sediment
Of the nine transects sampled, Table 3+ compounds were detected above reporting limits
in sediment samples from three transects: River Miles 76 and 77, which are adjacent to
the Site, and River Mile 149, which is downstream of the Site (Figure 5). The highest
concentrations of Table 3+ compounds were found in sediment samples from River
Mile 77. Table 3+ compounds were not detected above reporting limits in sediment
upstream from the Site or in any mid-channel sample from any transect. The
concentrations of Total Table 3+ (20 or 17 compounds) ranged from below the reporting
limits in several samples to a maximum concentration of 18.4 micrograms per kilogram
(µg/kg) at River Mile 77 (“A” segment, collected on the western riverbank, alongside the
facility). The highest individual compound concentration was
perfluoro-2-methoxyaceticacid (PFMOAA) at 9.9 µg/kg from the sample collected at
River Mile 149 (“C” segment). In total, eight of the 20 Table 3+ compounds (including
HFPO-DA) were detected above reporting limits in samples from this event (Table 5A).
The distribution of PFAS in sediment is further discussed in Section 5.
4.2.3 Cape Fear River Method 537M PFAS in Sediment
In contrast to Table 3+ compounds, Method 537M compounds were detected above
reporting limits in samples from each of the nine transects sampled including areas
upstream of, adjacent to, and downstream of the Site. The highest total concentration was
detected at River Mile 149 (Figure 5). Generally, Method 537M concentrations were
lower or not detected above the reporting limit in mid-channel (“B”) segments. The total
concentrations of Method 537M PFAS ranged from below the reporting limits in several
samples to a maximum concentration of 33.36 µg/kg at River Mile 149 (“C” segment).
The greatest number of Method 537M PFAS detected above reporting limits at a segment
was 17 compounds, from River Mile 76 (“A” segment); River Mile 76 is adjacent to the
Site and downstream of the city of Fayetteville and the farther upstream location RM-52
(Figure 3c).
The most frequently detected above reporting limits and highest measured Method 537M
PFAS was 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol found both upstream and
downstream of the Site. It was detected above reporting limits in 22 of the 32 sediment
samples analyzed and it was detected in at least one segment along each transect,
including upstream of, adjacent to, and downstream of the Site. The highest detection was

TR0795 11 October 2020
at River Mile 100 “C” segment (opposite the Elizabethtown WWTP) at 15 µg/kg
(Table 5B). In total, 19 of the 35 Method 537M compounds were detected above reporting
limits in samples collected from this event (Table 5B).
The distribution of PFAS in sediment are further discussed in Section 5.
4.3 Analysis of Cape Fear River Surface Water
Samples collected in this program were intended to be collected during baseline
conditions (see Section 3.4), and as a result, samples were collected over a span of 43
days. The Cape Fear River flow varied during the sampling period. Sampling dates, flow
conditions, and concentrations at each segment are provided in Table 2 and Figure 4.
Sampling results are provided in Tables 6A, 6B, and 6C.
Samples were collected at two depths in seven of the nine transects (as described in
Section 3.1). Table 3+ concentrations were similar between the two sampling depths
(Table 6A).
4.3.1 Cape Fear River Table 3+ PFAS Sampling Results
Table 3+ PFAS were detected above the reporting limit in all surface water samples
collected during the sampling program, spanning from River Mile 20 through River
Mile 149. Concentrations varied by River Mile (Figure 6a). However, mass discharge is
greater downstream of the Site, as shown in Figure 6b. Results are listed in Table 6A.
Fewer Table 3+ compounds were detected above the reporting limit in the samples
collected upstream of the Site relative to samples collected downstream. Analytes
detected above reporting limits in upstream samples were limited to three compounds5;
the analytes detected above reporting limits in downstream samples ranged from six to
10 compounds, with several compounds6 found in every downstream sample.
The concentrations of Total Table 3+ (17 and 20 compounds) ranged from 2.4 nanograms
per liter (ng/L) at River Mile 77 (18 feet below water surface) to a maximum
concentration of 131 ng/L at River Mile 100 (17 feet below water surface). The highest
individual Table 3+ compound concentration was perfluoromethoxypropyl carboxylic
acid (PMPA) at 42 ng/L from the sample collected at River Mile 100 (17 feet below water

5 Perfluoromethoxysulfonic Acid [NVHOS], perfluoromethoxypropyl carboxylic acid [PMPA], and Ethanesulfonic acid, 1,1,2,2-tetrafluoro-2-[1,2,2,3,3-pentafluoro-1-(trifluoromethyl)propoxy] [R-PSDA] 6 HFPO-DA, Perfluoro-2-methoxyaceticacid [PFMOAA], Perfluoro(3,5-dioxahexanoic) Acid [PFO2HxA], Perfluoro(3,5,7-trioxaoctanoic) Acid [PFO3OA], and 1,2,2,3,3-pentafluoro-1-(trifluoromethyl)propoxy [Hydrolyzed PSDA]

TR0795 12 October 2020
surface). In total, 10 Table 3+ compounds (including HFPO-DA) were reported in
samples from this event (Table 6A).
The distribution of PFAS in surface water are further discussed in Section 5.
4.3.2 Cape Fear River Method 537M PFAS Sampling Results
Method 537M were detected above the reporting limit in all surface water samples
collected during the sampling program, spanning from River Mile 20 through River
Mile 149. Several Method 537M compounds were detected in relatively consistent
concentrations above the reporting limit in the surface water samples from River Mile 20
through River Mile 149 (Figure 6a). Results are listed in Table 6B.
Compounds detected above the reporting limit were Perfluorobutane Sulfonic Acid,
Perfluorobutanoic Acid, Perfluoroheptanoic Acid, Perfluorooctanoic Acid (PFOA), and
Perfluorooctane Sulfonate (PFOS). There were no other Method 537M compounds
detected above reporting limits.
Total Method 537M compounds ranged from 48.5 ng/L at River Mile 149 (1.5 feet below
water surface) to a maximum concentration of 72.5 ng/L at River Mile 52 (1.6 feet below
water surface). The highest individual Method 537M compound concentration was PFOS
at River Mile 84 (18 feet below water surface) at 15 ng/L (Table 6B). PFOS is not
produced or used at the Site or present in Site process water samples (Chemours, 2019;
Geosyntec, 2019f).
The distribution of PFAS in surface water are further discussed in Section 5.
5 DISCUSSION
Along its course, the Cape Fear River receives contributions from a variety of sources
which have associated PFAS discharges, including the Little River, various creeks, direct
groundwater discharge to the Cape Fear River, and discharges from multiple POTWs and
industrial dischargers (NCDEQ, 2020; PFAST Network, 2020). Between River Miles 76
and 77, there are several Site-related inputs into the Cape Fear River which have also
been identified as sources of PFAS to the River7. The Cape Fear River then transports
dissolved-phase chemicals from these inputs (Geosyntec, 2020c) and also transports and,
subsequently deposits, sediments suspended in the water column.

7 Site-related impacts include Willis Creek, onsite Seeps, Old Outfall 002, and onsite groundwater, all of which have been identified as transport pathways of PFAS to the Cape Fear River (Geosyntec, 2019a, 2019b, 2020e)

TR0795 13 October 2020
This section presents a summary of the Cape Fear River sediment grainsize data, a
discussion of the distributions of Table 3+ and Method 537M PFAS detected in sediment
samples and surface water samples, and a contextualization of the results of this program
relative to the 2019 Human Health and Ecological Screening Level Exposure
Assessments (Geosyntec, 2019a).
5.1 Cape Fear River Sediment Grainsize and TOC Data
The distribution of riverbed sediments in the Cape Fear River is a product of the
underlying geology, sediment load inputs, and water velocities in the Cape Fear River.
Water generally flows fastest in the thalweg (i.e., the deepest point of river cross section)
and is a function of channel slope (i.e. gradient of the river), channel width, and flow,
which results in higher water velocities in areas with steeper terrain or a narrower channel
and lower water velocities in flatter-areas or areas with a wider channel. Where water
carrying suspended sediment moves from a high-velocity environment to a
lower-velocity environment, sediment is often deposited, and erosion is less likely to
occur.
Samples collected during this program indicate a higher relative percentage of
fine-grained material is distributed along the banks of the Cape Fear River (“A” and “C”
segments) compared with the center channel (Figure 7a). Consistent with expected river
dynamics, faster currents in the center channel appear to prevent finer grained sediment
accumulation in the center channel sections of the Cape Fear River.
The transect segment with the highest proportion of silts and clays (i.e., fine grained
material) sampled in this program was at River Mile 149 (“C” segment bank sample;
Figure 7a, Table 5C). The proportion of fines (combined clay and silt fractions of 89%)
found in this area of River Mile 149 suggests that this is a depositional environment. The
River Mile 149 transect is off the main channel of the River in a secondary flow channel
that likely experiences lower water velocities. Bathymetry data from the US Army Corps
of Engineers indicates the slope of the Cape Fear River Channel is essentially zero for six
miles upstream and five miles downstream of this sampling transect, which will reduce
water velocities in this area. Additionally, water velocities in this reach of the Cape Fear
River are expected to be further reduced due to backwater effects from strong tidal
currents nearer the mouth of the Cape Fear River (Bowen et. al, 2009). All of these factors
contribute to the depositional environment at this location.
Riverbank samples from River Miles 76, 77, and 84 also contained relatively elevated
proportions of fines (over 60%). Transects at River Miles 76 and 77 are upstream of and

TR0795 14 October 2020
potentially influenced by the W.O. Huske Dam; the Dam may create areas of lower water
velocity upstream of the Dam in which suspended sediments may deposit.
TOC content in Cape Fear River sediments is generally correlated with finer sediment
grain sizes (Figure 7b); this is consistent with expectations, as TOC is often associated
with finer particulates (Horowitz, 1991). TOC was observed to be higher in bank (“A”
and “C”) segment samples than in mid-channel (“B”) segment samples (Figures 7b and
7c). Transects with the highest TOC content (River Miles 76, 77, and 149) were also the
transects with the highest fines content (Figure 7c).
Contaminants in river systems are more likely to be found in finer-grained, higher organic
content sediment than in sediment which is coarser grained with lower organic content
(ITRC, 2014). This association is due to contaminants preferentially adsorbing to finer
grained sediments, often the TOC component, which makes TOC and grain size
distribution potential indicators of areas of sediment impacts (ITRC, 2014). Literature
suggests that PFAS compounds, especially longer-chained PFAS, have a greater potential
for adsorption to particulate matter in the environment (Kucharzyk et al, 2017).
5.2 Table 3+ and Method 537M PFAS Distribution in Sediment
Table 3+ PFAS were detected above reporting limits at three of the nine sampling
transects: River Miles 76 and 77, which are adjacent to the Site, and River Mile 149,
which is downstream of the Site. Table 3+ compounds were only detected above reporting
limits in bank samples. As noted in Section 5.1, River Miles 76 and 77 may have some
depositional areas due to influences of the W.O. Huske Dam, and River Mile 149 is
expected to be depositional environment. Upstream of the Site, transects at River Miles
20 and 52 were in areas with coarser grained sediment which are not expected to be
depositional areas.
Eight individual Table 3+ PFAS were detected above reporting limits from the bank (“A”
and “C”) segments at the transects at River Miles 76 and 778. At the River Mile 76
sampling transect, Table 3+ PFAS were detected above reporting limits in both “A” and
“C” bank segments with the higher concentration from the western shore (Site-adjacent)
sample (segment “A”); the Total Table 3+ PFAS at segment “A” was 15.9 µg/kg; at
segment “C”, the Total Table 3+ concentration was 5.9 µg/kg. At River Mile 77,

8 Compounds detected above reporting limits were HFPO-DA, PFMOAA, PFO2HxA, PFO3OA, PFO4DA, PFO5DA, PMPA, PS Acid.

TR0795 15 October 2020
Table 3+ PFAS were only detected above reporting limits in the western shore segment
(“A”) with a total concentration of 18.4 µg/kg.
Table 3+ PFAS were not detected above the reporting limit in samples from the next four
downstream transects (River Miles 84, 100, 116, and 132). Table 3+ PFAS were detected
above reporting limits in one bank segment at River Mile 149 (“C” segment) with a
maximum concentration among the three samples collected at this segment of 13.64
µg/kg.
In contrast to Table 3+ PFAS, Method 537M PFAS compounds were detected above
reporting limits in samples from each of the nine transect sampled, including areas
upstream of, adjacent to, and downstream of the Site. The highest concentration sample
was at River Mile 149, segment “C”, at 33.36 µg/kg. This is the same sample location
which had downstream detections of Table 3+ PFAS above reporting limits, further
confirming the depositional nature of this segment.
The segment with the greatest number of Method 537M PFAS was River Mile 76,
segment “A” with 17 compounds detected above reporting limits followed by River
Mile 76, segment “C”, and River Mile 77 segment “C” both with 11 compounds detected
above reporting limits. As noted earlier, River Miles 76 and 77 are potentially located in
a depositional environment, particularly compared to the next upstream location at River
Mile 52 where far fewer fines were present in the sediment samples. Upstream watershed
data from POTWs and industrial discharges (NCDEQ, 2020) and upstream watershed
water data collected by the PFAST Network (2020) indicate that all the compounds
detected in sediment at River Miles 76 and 77 were positively identified in upstream
samples with the exception of two compounds, which were not analyzed in the referenced
assessments9. These detections are consistent with known patterns of PFAS
contamination to watersheds and upgradient source types such as wastewater treatment
plants, landfills, and releases of firefighting foams (ITRC, 2020; Hu et al., 2016). These
upstream detections suggest the potential for deposition and accumulation of these
compounds in the more depositional environments of River Miles 76 and 77.
5.3 Table 3+ and Method 537M PFAS Distribution in Surface Water
Sampling during this program was intended to target base flow conditions, as noted in
Sections 3.4 and 4.3. Due to the weather conditions during the sampling schedule,

9 The two compounds not quantitated in upstream samples collected by NCDEQ or the PFAST Network were 2-(N-ethylperfluoro-1-octanesulfonamido)-ethanol and 2-(N-methylperfluoro-1-octanesulfonamido)-ethanol.

TR0795 16 October 2020
sampling was delayed several times and was conducted over a span of 43 days (Tables 1
and 2). During this time, the flows in the Cape Fear River varied considerably (Figure 4;
Table 4).
Variation in flow directly affects the concentrations of PFAS measured in samples, as a
large fraction of the Table 3+ PFAS mass load in the Cape Fear River comes from onsite
transport pathways which are unaffected by River stage (Onsite Seeps and Old Outfall
002 [Geosyntec, 2020d]). These PFAS loads will then mix in the Cape Fear River and
final concentrations will be a factor of the volume of water present in the River. More
water in the Cape Fear River (i.e., higher River flows) will lead to lower PFAS
concentrations.
Table 3+ PFAS were detected above the reporting limit in the surface water samples
collected during the sampling program, spanning from River Mile 20 through River
Mile 149 (Table 6A). Table 3+ analytes PFAS PMPA, perfluoromethoxysulfonic acid
(NVHOS), and R-PSDA were detected above reporting limits in transects located at River
Miles 20, 52, and 76. Beginning at River Mile 77 and continuing downstream, a greater
number of Table 3+ PFAS compounds were detected above reporting limits in surface
water samples. While concentrations varied by River Mile (Figure 6a), the mass discharge
of well-mixed Cape Fear River samples downstream of the Site (i.e., River Mile 84 to
River Mile 149) was relatively constant (between 7 and 10 milligrams per second for 17
Table 3+ compounds; between 8 and 11 mg/s for 20 Table 3+ compounds), with the
exception of one measurement with a higher value at River Mile 116 (Table 4; Figure
6b).
The sample collected at River Mile 77 had the lowest concentration and second lowest
calculated mass discharge over the sampling program (Figures 6a and 6b). The lower
concentrations and mass load at River Mile 77 may be related to incomplete mixing of
the Cape Fear River directly adjacent to the Site; inputs from the Site are not fully mixed
into the Cape Fear River until further downstream nearer River Mile 81 (Figure 8) .
Similar to past investigations (Geosyntec 2018, 2020c), Method 537M compounds were
detected above the reporting limit throughout the length of the sampled Cape Fear River.
These compounds have been detected above reporting limits in past sampling events in
the Deep and Haw Rivers which meet to form the Cape Fear River (Geosyntec, 2018,
2020c). Consistent with past sampling results, Method 537M concentrations remained
relatively constant directly upstream, adjacent to and downstream of the Site (Figure 6a;
Figure 9).

TR0795 17 October 2020
5.4 Comparison of Sediment Results to Human Health and Ecological Screening
Level Exposure Assessments
The information and results of the 2019 SLEA (Geosyntec, 2019a) were used to provide
context for the newly collected PFAS data with respect to potential human and ecological
hazards. As discussed in the SLEA (Geosyntec, 2019a), the lack of available toxicity
information inhibits the full quantification of potential risks for the majority of Table 3+
PFAS. Sufficient toxicity information is available only for HFPO-DA to perform hazard
characterization.
The data collected to support the Sediment Characterization were not intended to provide
a revised hazard characterization in the Human Health or Ecological components of the
Screening Level Exposure Assessment (HHSLEA and Eco-SLEA; SLEA, Geosyntec
2019a). Also of note, the extent of the Sediment Characterization along the Cape Fear
River was more expansive than that applied in the 2019 Screening Level Exposure
Assessment (SLEA, Geosyntec 2019a).
5.4.1 Data Comparison: Human Health SLEA
Overall, the surface water data from this program exhibit lower associated concentrations
of HFPO-DA when compared with data underpinning the 2019 SLEA. Differences
between the assessment discussed here and the 2019 SLEA are that first, fish tissue
sampling was not part of this sampling program, so no new data were available. The
second difference is that this evaluation also considers direct contact with sediment as a
line of evidence for understanding human health components. In light of available data,
this comparative assessment focuses on surface water exposures, with an ancillary
consideration for sediment and fish complete exposure pathways.
The following notes describe how this comparison was performed:
• Data collected from this program at River Mile 52 were compared to data
underpinning SLEA Exposure Unit (EU) 13, representing conditions upgradient
from the facility, based on Cape Fear River flow;
• Data collected from this program at River Miles 76 and 77 were compared to
data underpinning SLEA EU14, representing River conditions adjacent to the
facility;
• Data collected from this program at River Mile 84 were compared to data
underpinning SLEA EU16, in an assessment of downgradient conditions at the
Bladen Bluffs surface water intake; and

TR0795 18 October 2020
• Data collected from this program River Mile 132 were compared to data
underpinning SLEA EU17, in an assessment of far downgradient conditions at
the Kings Bluff surface water intake.
• Data collected from River Miles 20, 100, 116 and 149 represent investigation
areas not previously assessed within the context of the SLEA.
Surface Water
Surface water data collected during this program generally exhibit an order of magnitude
lower level of HFPO-DA than the data used in the 2019 SLEA (Table 7). In the 2019
SLEA, the reasonable maximum exposure (RME)-based exposure point concentration
(EPC) represents either an upper-bound estimate on the mean or the maximum detected
concentration (Table 7). In recognition of dynamic conditions in a river, including
fluctuating flow volumes and flow rates as well as sediment and suspended particle
loading, the preferred metric for this comparison is the central tendency exposure
(CTE)-based EPC, which reflects the dataset mean. In an assessment of the CTE EPCs,
the trends in comparison between the surface water data sets from this program and the
2019 SLEA are consistent, with the more recent data reflecting an order of magnitude
lower HFPO-DA concentration.
In a refinement of the assessment outlined above, comparing the 2019 SLEA total dataset
with the corresponding data from this program, the SLEA dataset was queried to isolate
only data from the 2019 sampling year. Based on this comparison, the surface water data
from this program still represent a substantive decrease in recorded HFPO-DA
concentrations in Cape Fear River surface water, with the concentrations from this
program reported as less than half those associated with the 2019 data averages (in
corresponding EUs) (Table 7).
Combined concentrations of PFOA and PFOS in surface water from all locations sampled
in this program were below the 70 ng/L USEPA Lifetime Health Advisory level (USEPA,
2016b, 2016c). Combined PFOA and PFOS concentrations ranged from 17.8 ng/L (River
Mile 20) to 22.2 ng/L (River Mile 84).
Concentrations of HFPO-DA were below the 140 ng/L HFPO-DA provisional health goal
(NCDEQ and NCDHHS, 2018). Surface water HFPO-DA concentrations ranged from
below reporting limits to 15 ng/L (River Mile 100). HFPO-DA was only reported in
samples downstream of the Fayetteville Works facility.

TR0795 19 October 2020
HHSLEA – Sediment
Sediment data collected during this program are summarized for HFPO-DA and are
presented in Table 8. HFPO-DA was detected above reporting limits in only three
transects. HFPO-DA was detected above reporting limits in three of four samples from
River Mile 76 and one of three samples from River Mile 77, both transects are considered
facility-adjacent. The highest reported transect-specific EPC HFPO-DA occurred at
River Mile 77 at a concentration of 2.5 µg/kg. HFPO-DA was also detected above
reporting limits downstream at River Mile 149 in one of five samples, at a maximum
detected concentration of 0.34 µg/kg , a value nearly an order of magnitude less than the
levels associated with the facility-adjacent transects.
HHSLEA – 2020 Data Impact on Risk Characterization
As discussed in the SLEA (Geosyntec, 2019a), the lack of available toxicity information
inhibits the full quantification of potential risks for the majority of Table 3+ PFAS.
Neither surface water nor sediment exposures to HFPO-DA, based on conditions assessed
in the 2019 SLEA or based on data from this program, contribute unacceptable exposures
to relevant human populations based on the USEPA target hazard index. Complete
exposure pathways associated with these contact media are several orders of magnitude
below the driving pathways of concern.
Recreational user direct contact with sediment was not a component of the complete
exposure pathways in the human health component of the 2019 SLEA and fish tissue data
were not collected in this program. Surface water data results were the line of evidence
supporting an assessment of potential impact on the 2019 SLEA outcomes.
Surface water data collected in this program are associated with HFPO-DA
concentrations that are lower than surface water concentrations evaluated in the 2019
SLEA. The findings of the SLEA did not indicate excess hazard levels for the maximally
exposed population (e.g., recreational child) and the reduced concentrations evident in
the data from this program suggest even lower associated hazard.
In the 2019 SLEA, recreational population direct contact hazards associated with
HFPO-DA in Cape Fear River surface water were greatest for a child recreator.
Associated child recreator hazard was greatest at EU16, where fish tissue data were
available to support consumption exposure; however, surface water exposure-alone for
this population, based on HFPO-DA, was greatest in EU14, adjacent to the site. In EU14,
RME-child recreator hazard based on surface water direct contact was calculated to be
4.8E-04, a value roughly 4 orders of magnitude below USEPA’s target hazard quotient
of unity and the threshold to define unacceptable exposure. Based on lower recorded

TR0795 20 October 2020
HFPO-DA level results in surface water data from this program, associated hazard for a
child recreator is projected to be lower, approximately 2.7E-05.
The highest recorded concentration of HFPO-DA in the sediment dataset from this
program occurred at River Mile 77, with a concentration of 2.5 µg/kg. Presuming
consideration of recreational parameter values consistent with a child recreator (e.g., 12
days/year, body weight of 15 kg, exposure duration of 6 years) in combination with a
conservative sediment incidental ingestion rate consistent with residential soil
(i.e., 200 mg/day), associated HFPO-DA hazard is approximately 1.1E-05. At River
Mile 77, the total surface water and sediment hazard attributable to a recreational child is
approximately 3.8E-05, a value more than 10,000 times lower EPA’s hazard threshold of
one.
Fish tissue data were not collected at River Mile 77 (coincident with EU14); however, if
recreational child fish tissue hazard (0.1) is taken from River Mile 86 (coincident with
EU16), and added to the updated surface water (2.7E-05) and sediment (3.8E-05) hazards
calculated for River Mile 77, cumulative hazard for HFPO-DA is 0.1, a value equal to
the highest projected hazard for this population in the 2019 SLEA and below EPA’s
hazard threshold of one.
5.4.2 Ecological SLEA Data Comparison
PFAS Profiles
The profile of Table 3+ PFAS detected above reporting limits in surface water in this
program was similar to those detected above reporting limits in the Eco-SLEA dataset in
2019. PEPA was newly detected above reporting limits in the sediment characterization
program surface water samples, but R-EVE was not detected above reporting limits,
having been previously detected above reporting limits in the SLEA dataset (Table 9).
In the Eco-SLEA dataset, only HFPO-DA had been detected above reporting limits in the
surface sediment samples collected adjacent to the facility (n = 6). Additional Table 3+
PFAS were detected above reporting limits in sediment samples from this program
(Table 9). Many of the Table 3+ PFAS detected above reporting limits in sediment that
were not previously detected above reporting limits are consistent with those previously
detected above reporting limits in fish, including PFOMAA,
perfluoro(3,5,7,9-tetraoxadecanoic) acid (PFO4DA),
perfluoro-3,5,7,9,11-pentaoxadodecanoic acid (PFO5DA), PMPA, and R-EVE.
However, perfluoro(3,5-dioxahexanoic) acid (PFO2HxA),
perfluoro(3,5,7-trioxaoctanoic) acid (PFO3OA), and phosphatidylserine (PS Acid) have
been detected above reporting limits in sediment samples from this program but were not

TR0795 21 October 2020
detected above reporting limits in fish samples from the 2019 Eco-SLEA. The relative
uptake of PFAS from sediment versus surface water for various fish species is not well
understood at this time.
Potential Hazard from HFPO-DA Exposures
Concentrations of HFPO-DA were generally consistent with those included in the Offsite
Aquatic EU of the SLEA (maximum concentration in the SLEA dataset was also 15 ng/L
HFPO-DA). This program covered a larger area than the Aquatic EU in the Eco-SLEA;
concentrations of HFPO-DA in surface water samples from within this EU (River
Miles 76 and 77) are significantly lower in comparison with data in the SLEA (2.2 ng/L
vs. 15 ng/L). These concentrations are orders of magnitude below the Probable No Effect
Concentrations for aquatic-life exposure to HFPO-DA (108,000 ng/L) and do not suggest
aquatic-life risks due to HFPO-DA. Even the highest concentration of Total Table 3+
PFAS (130 ng/L) are well below this benchmark.
Concentrations of HFPO-DA in sediments were also consistent between the Eco-SLEA
and this program and are well below the available benchmarks for benthic toxicity (518
µg/kg dry weight).
Hazard quotients (HQs) for aquatic wildlife in the Eco-SLEA ranged from 0.018 to
0.0000018 for HFPO-DA; indicating daily exposures lower by more than 10 to 100,000
times the available toxicity benchmarks for HFPO-DA. Given the similar range of
concentrations in both sediment and surface water, these new data do not indicate a
potential for wildlife risks from HFPO-DA.
Table 3+ PFAS as a Component of Total PFAS
As discussed in the Eco-SLEA (2019), a number of recent studies have evaluated the
presence of both Tale 3+ PFAS and non-site associated PFAS (primarily perfluoroalkyl
acids) in biota in the Cape Fear River Estuary (Robuck et al. 2019; Guillette et al. 2019).
These studies found that in shore birds, Striped bass, and American alligators, PFOS was
the predominant PFAS in tissue samples. The sediment data also support that PFOS is
widely detected above reporting limits in sediment, resulting in bioaccumulation in the
Cape Fear River food web. The current understanding of relative bioaccumulation
potential indicates that PFOS continues to be one of the most bioaccumulative of the
PFAS studied (Conder et al. 2020) indicating that it will likely to remain an ecological
risk-driver in the Cape Fear River system.

TR0795 22 October 2020
6 SUMMARY
Surface water and sediment samples were collected from nine transects along the length
of the Cape Fear River in May and June 2020. These samples were collected to evaluate
the nature and extent of PFAS upstream of, adjacent to, and downstream of the Site in the
Cape Fear River.
Across the sampling program, a higher relative percentage of fine-grained material was
located in riverbank sediment samples compared with the mid-channel samples,
consistent with expected river dynamics where banks with lower water velocities are
more depositional. Sediment sampling locations with higher fines contents were also
associated with higher TOC contents. Contaminants preferentially adsorb to finer grained
sediments, often the TOC component, which makes TOC and grain size distribution
indicators of areas with potential sediment impacts (ITRC, 2014). The sediment sample
with the highest fines content was observed in a bank sample at River Mile 149. This
transect is off the main channel of the River in a secondary flow channel that likely
experiences lower water velocities. Bank samples from River Miles 76 and 77 also
contained relatively elevated proportions of fines (over 60%), possibly due to their
location upstream of the W.O. Huske Dam, which may create areas of lower water
velocity upstream of the Dam in which suspended sediments deposit. These two transects
are downstream of the city of Fayetteville and adjacent to the Site, and the banks of these
transects indicate more depositional conditions than upstream bank sampling locations.
Table 3+ PFAS were detected above reporting limits in sediment from the riverbanks at
these areas that appear to be depositional with higher fines contents: River Miles 76 and
77, which are adjacent to the Site, and River Mile 149, which is downstream of the Site.
Across the sampling program, Method 537M compounds were detected in sediment from
all nine sampled transects. All of the Method 537M compounds detected in sediment at
River Miles 76 and 77 were positively identified in upstream aqueous samples collected
by NCDEQ and the PFAST Network, with the exception of two compounds, which were
not analyzed in the referenced assessments (NCDEQ, 2020; PFAST Network, 2020).
Detected compounds are consistent with known patterns of PFAS contributions to
watersheds from upgradient sources such as effluent from wastewater treatment plants,
leachate from landfills, and releases of firefighting foams (ITRC, 2020; Hu et al., 2016).
The fraction of total PFAS (Method 537M and Table 3+ combined) comprised of Table
3+ compounds in sediment is approximately 40% at River Miles 76 and 77, and 29% at
River Mile 149.

TR0795 23 October 2020
Table 3+ PFAS were detected in surface water above reporting limits at each sampling
transect. Concentrations generally vary based on the flow of the Cape Fear River,
resulting in a relatively constant mass discharge downstream of the Site. Method 537M
PFAS were detected above reporting limits in surface water samples along the length of
the Cape Fear River. The total concentration of Method 537M PFAS did not change
meaningfully upstream or downstream of the Site.
The sediment and surface water samples collected in this program were evaluated and
compared to data collected and interpretations made in the 2019 Human Health and
Ecological SLEAs. The results of this program are consistent with the findings of the
SLEAs that, based on presently available information for HFPO-DA exposures
quantified, there are no anticipated hazards to human or ecological receptors from
exposures to HFPO-DA in surface water or sediment. Concentrations of HFPO-DA were
below the 140 ng/L HFPO-DA provisional health goal (NCDEQ and NCDHHS, 2018).
Additionally, in the Cape Fear River, the combined concentrations of PFOA and PFOS
(Method 537M) in surface water from all locations sampled in this program were below
the 70 ng/L USEPA Lifetime Health Advisory level (USEPA, 2016b, 2016c).

TR0795 24 October 2020
7 REFERENCES
AECOM, 2018. Poly and Perfluoroalkyl Substance Quality Assurance Project Plan for
the Chemours Corporate Remediation Group. August, 2018.
Bowen, J.D., Negusse, S., Goodman, J.M., Duclaud, B., Robin, M. and Williams, J.,
2009. Development And Use Of A Three-Dimensional Water Quality Model To
Predict Dissolved Oxygen Concentrations In The Lower Cape Fear River Estuary,
North Carolina. Department of Civil and Environmental Engineering, University
of North Carolina at Charlotte. Prepared for NCDENR.
Chemours, 2020. Chemours Fayetteville Works NPDES Permit Application Update. July
2019.
Conder, J.M. Arblaster, J.A. Larson, E.S. Brown, J.B. Higgins, C. 2020. Guidance for
Evaluating Ecological Risks to Threatened and Endangered Species at AFFF
Impacted Sites. SERDP Project ER-18 1614.
https://www.serdp-estcp.org/Program-Areas/Environmental-Restoration/ER18-1
614/ER18-1614
Geosyntec, 2018. Assessment of the Chemical and Spatial Distribution of PFAS in the
Cape Fear River. Chemours Fayetteville Works. 17 September 2018.
Geosyntec, 2019a. Ecological Screening Level Exposure Assessment (SLEA) of
Table 3+ PFAS, Chemours Fayetteville Works. December.
Geosyntec, 2019b. Corrective Action Plan. Chemours Fayetteville Works.
Geosyntec, 2019c. On and Offsite Assessment (Version 2). Chemours Fayetteville
Works. October 31, 2019.
Geosyntec, 2019d. Cape Fear River PFAS Loading Reduction Plan. Chemours
Fayetteville Works. 26 August 2019. Attachment 5: HFPO-DA Loading
Reductions Estimate.
Geosyntec, 2019e. Cape Rear River PFAS Mass Loading Model Assessment and
Paragraph 11.1 Characterization of PFAS at Intakes. Chemours Fayetteville
Works. 26 August 2019.
Geosyntec, 2019f. Characterization of PFAS in Process and Non-Process Wastewater and
Stormwater. Quarterly Report #1. July 31, 2019.
Geosyntec, 2020a. Sediment Characterization Plan. Prepared for The Chemours
Company, FC, LLC.

TR0795 25 October 2020
Geosyntec, 2020b. Matrix Interference During Analysis of Table 3+ Compounds
memorandum. Prepared for The Chemours Company, FC, LLC.
Geosyntec, 2020c. Cape Fear River Surface Water Sampling Report. Prepared for The
Chemours Company, FC, LLC.
Geosyntec, 2020d. Cape Fear River PFAS Mass Loading Assessment – Second Quarter
2020 Report. Chemours Fayetteville Works. September 2020.
Guillette, T., Polera, M., Belcher, S., 2019. Ecological impacts of novel and legacy per
and polyfluoroalkyl substances (PFAS) in Coastal North Carolina. Society of
Environmental Toxicology and Chemistry North America 40th Annual Meeting.
Presentation.
Horowitz, A.J., 1991. A primer on sediment-trace element chemistry (Vol. 2). Chelsea:
Lewis Publishers.
Hu, X.C., Andrews, D.Q., Lindstrom, A.B., Bruton, T.A., Schaider, L.A., Grandjean, P.,
Lohmann, R., Carignan, C.C., Blum, A., Balan, S.A. and Higgins, C.P., 2016.
Detection of poly-and perfluoroalkyl substances (PFASs) in US drinking water
linked to industrial sites, military fire training areas, and wastewater treatment
plants. Environmental science & technology letters, 3(10), pp.344-350.
Interstate Technology Regulatory Council (ITRC), 2014. Contaminated Sediments
Remediation: Remedy Selection for Contaminated Sediments.
https://clu-in.org/download/contaminantfocus/sediments/Sediment-ITRC-CS-2.p
df
ITRC, 2020. History and Use of Per- and Polyfluoroalkyl Substances (PFAS) found in
the Environment. https://pfas-dev.itrcweb.org/wp-
content/uploads/2020/10/history_and_use_508_2020Aug_Final.pdf . Accessed
21 October 2020.
Kucharzyk, K.H., et al., Novel treatment technologies for PFAS compounds: A critical
review, Journal of Environmental Management (2017),
http://dx.doi.org/10.1016/j.jenvman.2017.08.016
NCDEQ, 2020, Emerging Compound Facility Sampling.
(1) https://deq.nc.gov/news/key-issues/emerging-compounds/managing-
emerging-compounds-water
(2)
https://ncdenr.maps.arcgis.com/apps/instant/attachmentviewer/index.html?appid
=ed308373c97e4a23a29210fa53a3d404. Accessed 4 October 2020.

TR0795 26 October 2020
Parsons, 2018. Health and Safety Plan Chemours Fayetteville Site.
PFAST Network, 2020. NC PFAST Network Water Testing Information, Team 1 PFAS
Water Testing Reports by Site (Round 1), Data and Tools.
https://ncpfastnetwork.com/data-and-tools/. Accessed 13, October 2020.
Robuck, AR. 2019. Tissue-specific distribution of legacy and emerging per- and
polyfluoroalkyl substances in seabirds from Atlantic offshore and coastal
environments. Society of Environmental Toxicology and Chemistry Focused
Topic Meeting on PFAS. Durham NC August. Poster.
USEPA, 2009. National Primary Drinking Water Regulation. United State Environmental
Protection Agency.
USEPA, 2009. Guidance for Labelling Externally Validated Laboratory Analytical Data
for Superfund Use. EPA-540-R-08-005, 2009. Stage 2b.
USEPA, 2014. Region 4. Operating Procedure: Sediment Sampling. EPA SOP
SESDPROC-200-R3. August 2014.
USEPA, 2016. Region 4. Operating Procedure: Surface Water Sampling. EPA SOP
SESDPROC-201-R4. September 2016.
USEPA 2016b. Drinking Water Health Advisory for Perfluorooctanoic Acid (PFOA).
USEPA 822-R-16-005.
USEPA, 2016c. Drinking Water Health Advisory for Perfluorooctane Sulfonate (PFOS).
USEPA, 2016d. Fact Sheet: PFOA & PFOS Drinking Water Health Advisories.
https://www.epa.gov/sites/production/files/2016-06/documents/drinkingwaterhe
althadvisories_pfoa_pfos_updated_5.31.16.pdf
United States Army Corps of Engineers. Nationwide Permit 6. 19 March 2017.
http://saw-reg.usace.army.mil/NWP2017/2017NWP06.pdf. Accessed 30 January
2019.
Wang, Zhanyun; DeWitt, Jamie; Higgins, Christopher; and Cousins, Ian. 2017.
Environmental Science & Technology. 51 (5), 2508-2518 DOI:
10.1021/acs.est.6b04806 https://pubs.acs.org/doi/pdf/10.1021/acs.est.6b04806

TABLES

TABLE 1
SUMMARY OF SEDIMENT SAMPLES COLLECTED
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC, PC
Sample Location
Code Segment
Latitude
(Decimal
Degrees)
Longitude
(Decimal
Degrees)
Sample Date
Days from
Start of
Program
Water Column
Height (ft)1 Sampling Device Sample ID
RM-20 A 35.3977667 -78.773850 05/18/2020 0 1.5 Ponar FAY-SED-RM-20-A-05182020
RM-20 B 35.3981333 -78.773350 05/18/2020 0 15.4 Ponar FAY-SED-RM-20-B-05182020
RM-20 C 35.3984333 -78.773233 05/18/2020 0 2.6 Ponar FAY-SED-RM-20-C-05182020
RM-52 A 35.1076167 -78.856583 05/18/2020 0 1 Ponar FAY-SED-RM-52-A-05182020
RM-52 B 35.1074833 -78.856400 05/18/2020 0 3.2 Ponar FAY-SED-RM-52-B-05182020
RM-52 C 35.1075667 -78.856067 05/18/2020 0 0.54 Ponar FAY-SED-RM-52-C-05182020
RM-76 A 34.8517667 -78.827133 06/09/2020 22 0.54 Ponar FAY-SED-RM-76-A-06092020
RM-76 B 34.8515833 -78.826667 06/09/2020 22 24 Ponar FAY-SED-RM-76-B-06092020
RM-76 C 34.8517167 -78.826350 06/09/2020 22 3.53 Ponar FAY-SED-RM-76-C-06092020
RM-76 A 34.8517667 -78.827133 06/09/2020 22 0.54 Push-tube FAY-SED-RM-76-A-06092020-PT
RM-77 A 34.8384167 -78.823733 06/10/2020 23 1.73 Ponar FAY-SED-RM-77-A-06102020
RM-77 B 34.8384500 -78.823283 06/10/2020 23 20.8 Ponar FAY-SED-RM-77-B-06102020
RM-77 C 34.8384333 -78.822767 06/10/2020 23 4.4 Ponar FAY-SED-RM-77-C-06102020
RM-84 A 34.7724333 -78.798533 06/10/2020 23 0.25 Ponar FAY-SED-RM-84-A-06102020
RM-84 B 34.7722500 -78.798033 06/10/2020 23 20 Ponar FAY-SED-RM-84-B-06102020
RM-84 C 34.7725833 -78.797767 06/10/2020 23 0.8 Ponar FAY-SED-RM-84-C-06102020
RM-84 C 34.7725833 -78.797767 06/10/2020 23 0.8 Push-tube FAY-SED-RM-84-C-06102020-PT
RM-100 A 34.6275667 -78.562333 06/29/2020 42 2 Ponar FAY-SED-RM-100-A-06292020
RM-100 B 34.6277167 -78.562417 06/29/2020 42 10.9 Ponar FAY-SED-RM-100-B-06292020
RM-100 C 34.6281667 -78.562283 06/29/2020 42 2.5 Ponar FAY-SED-RM-100-C-06292020
RM-116 A 34.5344000 -78.439917 06/29/2020 42 0.17 Stainless steel spoon2 FAY-SED-RM-116-A-06292020
RM-116 B 34.5343667 -78.439483 06/29/2020 42 15 Ponar FAY-SED-RM-116-B-06292020
RM-116 C 34.5345000 -78.439100 06/29/2020 42 2.3 Ponar FAY-SED-RM-116-C-06292020
RM-132 A 34.4063667 -78.295200 06/11/2020 24 3.9 Ponar FAY-SED-RM-132-A-06112020
RM-132 B 34.4064833 -78.294700 06/11/2020 24 12 Ponar FAY-SED-RM-132-B-06112020
RM-132 C 34.4068833 -78.294383 06/11/2020 24 3.1 Ponar FAY-SED-RM-132-C-06112020
RM-149 A 34.3519167 -78.083883 06/30/2020 43 3.9 Ponar FAY-SED-RM-149-A-06302020
RM-149 B 34.3520667 -78.084100 06/30/2020 43 2.5 Ponar FAY-SED-RM-149-B-06302020
RM-149 C 34.3521833 -78.084283 06/30/2020 43 1.8 Ponar FAY-SED-RM-149-C-06302020
RM-149 C 34.3521833 -78.084283 06/30/2020 43 1.8 Push-tube FAY-SED-RM-149-C-06302020-PT
Notes:
mg/s -milligrams per second
PT -Indicates sample was collected using a push-tube device.
Samples from RM-100, -132, and -149 were split with NC DEQ.
1 Field measurement of water column
2 Sediment was collected at this location using a stainless-steel spoon due to a clay layer that was impenetrable
TR0795 Page 1 of 1 October 2020
TABLE 2
SUMMARY OF SURFACE WATER SAMPLES COLLECTED
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC, PC
Sample Location
Code Segment
Latitude
(Decimal
Degrees)
Longitude
(Decimal
Degrees)
Water Sample
Collection
Depth (ft)
Sample Date
Days from
Start of
Program
Sample ID
RM-20 B 35.3981333 -78.773350 6.7 5/18/2020 0 FAY-SW-RM-20-B-6.7-05182020
RM-20 B 35.3981333 -78.773350 20 5/18/2020 0 FAY-SW-RM-20-B-20-05182020
RM-52 1 B 35.1074833 -78.856400 1.6 5/18/2020 0 FAY-SW-RM-52-B-1.6-05182020
RM-76 B 34.8515833 -78.826667 13 6/9/2020 22 FAY-SW-RM-76-B-13-06092020
RM-76 B 34.8515833 -78.826667 21 6/9/2020 22 FAY-SW-RM-76-B-21-06092020
RM-77 B 34.8384500 -78.823283 10 6/9/2020 22 FAY-SW-RM-77-B-10-06102020
RM-77 B 34.8384500 -78.823283 18 6/9/2020 22 FAY-SW-RM-77-B-18-06102020
RM-84 B 34.7722500 -78.798033 10 6/10/2020 23 FAY-SW-RM-84-B-10-06102020
RM-84 B 34.7722500 -78.798033 18 6/10/2020 23 FAY-SW-RM-84-B-18-06102020
RM-100 B 34.6277167 -78.562417 9.5 6/29/2020 42 FAY-SW-RM-100-B-9.5-06292020
RM-100 B 34.6277167 -78.562417 17 6/29/2020 42 FAY-SW-RM-100-B-17-06292020
RM-116 B 34.5343667 -78.439483 7.5 6/29/2020 42 FAY-SW-RM-116-B-7.5-06292020
RM-116 B 34.5343667 -78.439483 13 6/29/2020 42 FAY-SW-RM-116-B-13-06292020
RM-132 B 34.4064833 -78.294700 6 6/11/2020 24 FAY-SW-RM-132-B-6-06112020
RM-132 B 34.4064833 -78.294700 10 6/11/2020 24 FAY-SW-RM-132-B-10-06112020
RM-149 1 B 34.3520667 -78.084100 1.5 6/30/2020 43 FAY-SW-RM-149-B-1.5-06302020
Notes:
ft -feet
mg/s -milligrams per second
Samples from RM-100, -132, and -149 were split with North Carolina Department of Environmental Quality.
1 One sample at this location due to limited depth
TR0795 Page 1 of 1 October 2020
TABLE 3
SURFACE WATER FIELD PARAMETERS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location Date Sample Time Latitude Longitude pH (S.U.)
Dissolved
Oxygen
(mg/L)
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Specific
Conductivity
(mS/cm)
Temperature
(°C)Color Odor
FAY-SW-RM20-B-6.7-051820 05/18/20 17:45 35.3980941 -78.773434 7.61 8.86 83.40 3.14 0.00 25.74 Clear No
FAY-SW-RM20-B-12-051820 05/18/20 18:00 35.3980941 -78.773434 8.05 9.23 74.60 3.22 0.110 24.35 Clear No
FAY-SW-RM52-B-1.6-051820 05/18/20 13:45 35.1075280 -78.856326 7.33 7.39 29.50 5.10 0.11 24.14 Clear No
FAY-SW-RM76-B-13-060920 06/09/20 12:30 34.8516700 -78.826670 7.10 6.75 32.20 33.29 0.10 26.66 Light Brown None
FAY-SW-RM76-B-21-060920 06/09/20 12:00 34.8516700 -78.826670 6.90 6.65 50.00 48.80 0.160 27.05 Light Brown None
FAY-SW-RM77-B-10-060920 06/09/20 15:45 34.9186100 -78.926940 6.55 6.90 69.70 31.31 0.10 26.31 Light Brown None
FAY-SW-RM77-B-18-060920 06/09/20 15:45 34.9186100 -78.926940 6.36 6.92 78.50 58.34 0.100 25.74 Light Brown None
FAY-SW-RM84-B-10-061020 06/10/20 14:00 34.8597200 -79.028330 7.03 6.85 30.70 18.55 0.09 27.62 Light Brown None
FAY-SW-RM84-B-18-061020 06/10/20 14:00 34.8597200 -79.028330 7.04 6.86 22.70 18.37 0.090 26.68 Light Brown None
FAY-SW-RM100-B-9.5-62920 06/29/20 09:15 34.6279471 -78.562135 6.23 6.27 132.80 16.24 0.09 26.28 Murky None
FAY-SW-RM100-B-17-062920 06/29/20 09:15 34.6279471 -78.562135 7.12 7.66 38.40 18.77 0.090 26.64 Murky None
FAY-SW-RM116-B-7.5-062920 06/29/20 13:30 34.5343908 -78.439541 6.48 5.63 116.30 16.30 0.08 29.38 Murky None
FAY-SW-RM116-B-13-062920 06/29/20 13:30 34.5343908 -78.439541 6.44 5.70 125.10 16.35 0.080 27.58 Murky None
FAY-SW-RM132-B-6-061120 06/11/20 09:45 34.5077800 -78.472780 6.42 5.25 100.10 21.19 0.10 26.44 Light Brown None
FAY-SW-RM132-B-10-061120 06/11/20 09:45 34.5077800 -78.472780 6.52 5.30 122.60 20.60 0.100 26.02 Light Brown None
FAY-SW-RM149-B-1.5-063020 06/30/20 09:30 34.3520565 -78.084179 6.47 5.05 24.00 8.89 0.07 27.43 Murky None
Notes:
°C - Degrees Celsius
mg/L - Milligrams per liter
mS/cm - Millisiemens per centimeter
mV - Millivolts
NTU - Nephelometric Turbidity units
S.U. - standard units
TR0795 Page 1 of 1 October 2020
TABLE 4
SAMPLING LOCATION RIVER FLOW VELOCITIES
AND SURFACE WATER TABLE 3+ MASS DISCHARGE
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC, PC
Sample Location
Code Segment Sample Date
Days from
Start of
Program
Sample
Collection
Time (24-hour
clock)
Water Column
Height (ft)1
Estimated
River Flow2
(cfs)
Total Table 3+
(17)
Concentrations
(µg/kg)
Water Sample
Collection
Depth (ft)1
Sample Date
Days from
Start of
Program
Sample
Collection
Time (24-hour
clock)
Estimated
River Flow2
(cfs)
Total Table 3+
(17)
Concentrations
(ng/L)
Table 3+ (17)
Mass
Discharge
(mg/s)
Total Table 3+
(20)
Concentrations
(ng/L)
Table 3+ (20)
Mass
Discharge
(mg/sec)
RM-20 A 05/18/2020 0 19:00 1.5 700 ND
6.7 5/18/2020 0 17:45 678 35.5 0.7 35.5 0.7
20 5/18/2020 0 18:00 678 39.1 0.8 39.1 0.8
RM-20 C 05/18/2020 0 16:50 2.6 700 ND
RM-52 A 05/18/2020 0 11:38 1 1,200 ND
RM-52 B 05/18/2020 0 14:00 3.2 1,200 ND 1.6 5/18/2020 0 13:45 1,200 32.0 1.1 51 1.0
RM-52 C 05/18/2020 0 13:00 0.5 1,200 ND
RM-76 A 06/09/2020 22 10:15 0.54 8,900 6.8
13 6/9/2020 22 12:30 8,270 22.0 5.2 22 0.4
21 6/9/2020 22 12:00 8,420 23.0 5.5 23 0.4
RM-76 C 06/09/2020 22 14:45 3.5 7,700 5.9
RM-76 A 06/09/2020 22 10:15 0.54 7,900 15.9
RM-77 A 06/10/2020 23 08:00 1.7 5,000 18.4
10 6/9/2020 22 15:45 7,360 2.4 0.5 2.4 0.0
18 6/9/2020 22 15:45 7,360 4.8 1.0 4.8 0.1
RM-77 C 06/10/2020 23 08:45 4.4 5,000 ND
RM-84 A 06/10/2020 23 16:00 0.25 5,500 ND
10 6/10/2020 23 14:00 5,290 47.5 7.1 55.5 1.1
18 6/10/2020 23 14:00 5,290 51.5 7.7 64 1.2
RM-84 06/10/2020 23 12:30 0.8 5,500 ND
RM-84 06/10/2020 23 13:15 0.8 5,200 ND
RM-100 A 06/29/2020 42 11:15 2 2,900 ND
9.5 6/29/2020 42 09:15 2,900 110.8 9.1 124.1 2.4
17 6/29/2020 42 09:15 2,900 117.5 9.6 130.6 2.5
RM-100 C 06/29/2020 42 08:30 2.5 2,900 ND
RM-116 A 06/29/2020 42 15:00 0.17 3,900 ND
7.5 6/29/2020 42 13:30 3,910 87.0 9.6 100.4 1.9
13 6/29/2020 42 13:30 3,910 102.3 11.3 113.3 2.2
RM-116 C 06/29/2020 42 13:00 2.3 3,900 ND
RM-132 A 06/11/2020 24 11:45 3.9 6,400 ND
6 6/11/2020 24 09:45 6,460 40.2 7.4 49.5 1.0
10 6/11/2020 24 09:45 6,460 40.2 7.4 52 1.0
RM-132 C 06/11/2020 24 12:30 3.1 6,400 ND
RM-149 A 06/30/2020 43 10:45 3.9 3,500 ND
RM-149 B 06/30/2020 43 10:00 2.5 3,500 ND 1.5 6/30/2020 43 09:30 3,510 85.3 8.5 88 1.7
RM-149 C 06/30/2020 43 08:00 1.8 3,500 1.1 / 13.5
RM-149 C 06/30/2020 43 08:00 1.8 3,500 13.6
Surface Water
22
RM-20 B 05/18/2020 0 18:45 15.4 700 ND
Sediment Sampling
23
06/09/2020BRM-76
ND5,00020.809:002306/10/2020BRM-77
ND7,9002413:45
06/10/2020BRM-84
ND2,90010.910:004206/29/2020BRM-100
C
ND5,4002014:45
06/29/2020BRM-116
ND6,4001211:152406/11/2020BRM-132
ND3,9001514:0042
Notes:
ft -feet
mg/s -milligrams per second
cfs -cubic feet per second
µg/kg -microgram per kilogram
ng/L -nanogram per liter
ND -Compounds not detected above the reporting limit.
1 Water column height and collection depth measured in the field.
2 Flow rate at the time of sample collection for River Mile 20 was obtained from the USGS gauge at Lillington (#02102500). For River
Miles 52, 76, 77, 84, 100, flow rate was obtained from USGS gauge at Huske Dam (#02105500). For River Miles 116, 132, and 149, flow
TR0795 Page 1 of 1 October 2020
TABLE 5A
SEDIMENT TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Location in Transect A B C A A B C A A B C
Field Sample ID FAY-SED-RM20-
A-051820
FAY-SED-RM20-B-
051820
FAY-SED-RM20-
C-051820
FAY-SED-RM52-
A-051820
FAY-SED-RM52-
A-051820-D
FAY-SED-RM52-B-
051820
FAY-SED-RM52-
C-051820
FAY-SED-RM76-
A-060920
FAY-SED-RM76-
A-060920-PT
FAY-SED-RM76-B-
060920
FAY-SED-RM76-
C-060920
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020
QA/QC Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Table 3+ Lab SOP (µg/kg)
Hfpo Dimer Acid*<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 2 J 2.2 <0.25 2.2
PFMOAA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
PFO2HxA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ 3.3 J 7.6 J <1 UJ 1.8 J
PFO3OA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ 2.2 J <1 UJ <1 UJ
PFO4DA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ 1.4 J <1 UJ <1 UJ
PFO5DA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ 1.4 J <1 UJ <1 UJ
PMPA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ 1.5 J 1.1 J <1 UJ 1.9 J
PEPA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
PS Acid <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
Hydro-PS Acid <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
R-PSDA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
Hydrolyzed PSDA <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
R-PSDCA <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
NVHOS <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
EVE Acid <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
Hydro-EVE Acid <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
R-EVE <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ
PES <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
PFECA B <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
PFECA-G <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ
Total Table 3+ (17 compounds)0 0 0 0 0 0 0 6.8 15.9 0 5.9
Total Table 3+ (20 compounds)0 0 0 0 0 0 0 6.8 15.9 0 5.9
TR0795 Page 1 of 4 October 2020
TABLE 5A
SEDIMENT TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Table 3+ Lab SOP (µg/kg)
Hfpo Dimer Acid*
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ (17 compounds)
Total Table 3+ (20 compounds)
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 116
A B C A B C C A B C A
FAY-SED-RM77-
A-061020
FAY-SED-RM77-B-
061020
FAY-SED-RM77-
C-061020
FAY-SED-RM84-
A-061020
FAY-SED-RM84-B-
061020
FAY-SED-RM84-
C-061020
FAY-SED-RM84-
C-061020-PT
FAY-SED-RM100-
A-062020
FAY-SED-RM100-
B-062920
FAY-SED-RM100-
C-062920
FAY-SED-RM116-
A-062920
6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/29/2020 6/29/2020 6/29/2020 6/29/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
2.5 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 UJ <0.25
7.3 J <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
3.9 J <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
1.6 J <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
1.3 J <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
1.8 J <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 <2 <2 <2
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 UJ <2 <2 <2 <2
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
<1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 UJ <1 <1 <1 <1
18.4 0 0 0 0 0 0 0 0 0 0
18.4 0 0 0 0 0 0 0 0 0 0
TR0795 Page 2 of 4 October 2020
TABLE 5A
SEDIMENT TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Table 3+ Lab SOP (µg/kg)
Hfpo Dimer Acid*
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ (17 compounds)
Total Table 3+ (20 compounds)
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
B C A B C A B C C C
FAY-SED-RM116-
B-062920
FAY-SED-RM116-
C-062920
FAY-SED-RM132-
A-061120
FAY-SED-RM132-
B-061120
FAY-SED-RM132-
C-061120
FAY-SED-RM149-
A-063020
FAY-SED-RM149-
B-063020
FAY-SED-RM149-
C-063020
FAY-SED-RM149-
C-063020-D
FAY-SED-RM149-
C-063020-PT
6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/11/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample
<0.25 <0.25 <0.25 <0.25 <0.25 <1 <0.25 <0.28 <0.42 0.34
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 9.9
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 2.2
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1.2 <1 <1 <1.6 <1.2
<1 <1 <1 UJ <1 UJ <1 UJ <1.1 <1 <1 <1.5 <1.1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 1.1 1.5 1.2
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1.3 <1
<2 <2 <2 UJ <2 UJ <2 UJ <2 <2 <2 <2.2 <2
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<2 <2 <2 UJ <2 UJ <2 UJ <2 <2 <2 <2 <2
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1 <1
<1 <1 <1 UJ <1 UJ <1 UJ <1 <1 <1 <1.3 <1
0 0 0 0 0 0 0 1.1 1.5 13.64
0 0 0 0 0 0 0 1.1 1.5 13.64
TR0795 Page 3 of 4 October 2020
TABLE 5A
SEDIMENT TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Table 3+ Lab SOP (µg/kg)
Hfpo Dimer Acid*
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ (17 compounds)
Total Table 3+ (20 compounds)
N/A N/A N/A N/A N/A N/A
N/A N/A N/A N/A N/A N/A
EQBLK-1-051820 EQBLK-2-060920 EQBLK-3-061020 EQBLK-4-061120 FAY-EQBLK-5-062920 FAY-EQBLK-6-063020
5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank
<0.002 0.0036 <0.002 <0.002 <0.002 <0.002
<0.005 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.01 <0.013 <0.013 <0.013 <0.013 <0.013
<0.02 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
0 0.0036 0 0 0 0
0 0.0036 0 0 0 0
Notes:Bold -Analyte detected above associated reporting limit.B -Analyte detected in an associated blank.J -Analyte detected. Reported value may not be accurate or precise.< -Analyte not detected above associated reporting limit for PFAS or above the associated detection limit for TOC, TSS, DOC.UJ -Analyte not detected. Reporting limit may not be accurate or precise.QA/QC -Quality assurance/Quality controlSOP -Standard Operating Procedures"A"-Facing upstream, left bank location in transect."B"-Middle of channel location in transect."C"-Facing upstream, right bank location in transect.µg/kg -micrograms per kilogram"-PT" in the sample ID indicates sample was collected with a push tube.
TR0795 Page 4 of 4 October 2020
TABLE 5B
SEDIMENT METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Location in Transect A B C A A B C A A B C
Field Sample ID FAY-SED-RM20-
A-051820
FAY-SED-RM20-B-
051820
FAY-SED-RM20-
C-051820
FAY-SED-RM52-
A-051820
FAY-SED-RM52-
A-051820-D
FAY-SED-RM52-B-
051820
FAY-SED-RM52-
C-051820
FAY-SED-RM76-
A-060920
FAY-SED-RM76-
A-060920-PT
FAY-SED-RM76-B-
060920
FAY-SED-RM76-
C-060920
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020
QA/QC Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Method 537M Lab SOP (µg/kg)
10:2 Fluorotelomer sulfonate <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
11Cl-PF3OUdS <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 0.8 4.2 2.1 0.23 J 0.24 J <0.2 UJ <0.2 UJ 2.8 J 1.3 <0.2 2.3
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <0.2 <0.2 0.38 0.24 J 0.26 J <0.2 UJ <0.2 UJ 0.77 J 1.2 <0.2 1.1
6:2 Fluorotelomer sulfonate <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
9Cl-PF3ONS <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
DONA <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002
N-ethyl perfluorooctane sulfonamidoacetic acid <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
N-ethylperfluoro-1-octanesulfonamide <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2 <0.2 <0.2 <0.2
N-methyl perfluoro-1-octanesulfonamide <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2 <0.2 <0.2 <0.2
N-methyl perfluorooctane sulfonamidoacetic acid <2 <2 <2 <2 <2 <2 <2 <2 2 <2 <2
Perfluorobutane Sulfonic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluorobutanoic Acid <0.2 <0.2 0.33 <0.2 <0.2 <0.2 <0.2 0.64 J 0.41 0.23 0.59
Perfluorodecane Sulfonic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.26 <0.2 <0.2
Perfluorodecanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.44 J 1.8 <0.2 <0.2
Perfluorododecane sulfonic acid (PFDoS)<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluorododecanoic Acid <0.2 <0.2 0.25 <0.2 <0.2 <0.2 <0.2 0.61 J 1.5 <0.2 0.32
Perfluoroheptane sulfonic acid (PFHpS)<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluoroheptanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.42 <0.2 <0.2
Perfluorohexadecanoic acid (PFHxDA)<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluorohexane Sulfonic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.27 J 0.3 <0.2 <0.2
Perfluorohexanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.25 <0.2 <0.2
Perfluorononanesulfonic acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluorononanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.22 J 1 <0.2 <0.2
Perfluorooctadecanoic acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluorooctane Sulfonamide <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluoropentane sulfonic acid (PFPeS)<0.2 <0.2 <0.2 <0.2 UJ <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2
Perfluoropentanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.24 <0.2 <0.2
Perfluorotetradecanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.43 <0.2 <0.2
Perfluorotridecanoic Acid <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.21 J 0.57 <0.2 <0.2
Perfluoroundecanoic Acid <0.2 <0.2 0.31 <0.2 <0.2 <0.2 <0.2 0.58 J 1.8 <0.2 0.29
PFOA <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 0.33 J 1.4 <0.2 <0.2
PFOS 0.58 <0.5 1 <0.5 UJ 0.57 J <0.5 <0.5 2.7 J 8.9 <0.5 2
Total Method 537 PFAS 1.38 0 4.37 0.47 1.07 0 0 9.57 23.78 0.23 6.60
TR0795 Page 1 of 4 October 2020
TABLE 5B
SEDIMENT METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Method 537M Lab SOP (µg/kg)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Total Method 537 PFAS
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 116
A B C A B C C A B C A
FAY-SED-RM77-
A-061020
FAY-SED-RM77-B-
061020
FAY-SED-RM77-
C-061020
FAY-SED-RM84-
A-061020
FAY-SED-RM84-B-
061020
FAY-SED-RM84-
C-061020
FAY-SED-RM84-
C-061020-PT
FAY-SED-RM100-
A-062020
FAY-SED-RM100-
B-062920
FAY-SED-RM100-
C-062920
FAY-SED-RM116-
A-062920
6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/29/2020 6/29/2020 6/29/2020 6/29/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 UJ <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 UJ <2
4.5 <0.2 2.3 J 2.6 <0.2 3.1 3.1 0.47 <0.2 15 J <0.2
3.9 <0.2 1.5 J 0.8 <0.2 0.91 0.57 <0.2 <0.2 2.3 J <0.2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 UJ <2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002 UJ <0.0002
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 UJ <2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
11 <2 4.6 J <2 <2 <2 <2 <2 <2 <2 UJ <2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
0.39 <0.2 0.47 J 0.65 <0.2 0.6 0.45 0.22 <0.2 0.52 J <0.2
0.3 <0.2 0.28 J <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
0.25 <0.2 0.23 J 0.33 <0.2 0.28 0.37 <0.2 <0.2 0.26 J <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
1.1 <0.2 0.62 J 0.53 <0.2 0.46 0.62 <0.2 <0.2 0.5 J <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 0.24 0.23 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
0.38 <0.2 0.52 J <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
0.38 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 UJ <0.2
0.52 <0.2 0.21 J <0.2 <0.2 <0.2 0.21 <0.2 <0.2 0.21 J <0.2
0.77 <0.2 0.9 J 0.45 <0.2 0.33 0.47 <0.2 <0.2 0.52 J <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 0.21 0.33 <0.2 <0.2 <0.2 UJ <0.2
4.7 <0.5 1.4 J 2.9 <0.5 2.3 2.8 <0.5 <0.5 2.3 J 0.68
28.19 0 13.03 8.26 0 8.43 9.16 0.69 0 21.61 0.68
TR0795 Page 2 of 4 October 2020
TABLE 5B
SEDIMENT METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Method 537M Lab SOP (µg/kg)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Total Method 537 PFAS
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
B C A B C A B C C C
FAY-SED-RM116-
B-062920
FAY-SED-RM116-
C-062920
FAY-SED-RM132-
A-061120
FAY-SED-RM132-
B-061120
FAY-SED-RM132-
C-061120
FAY-SED-RM149-
A-063020
FAY-SED-RM149-
B-063020
FAY-SED-RM149-
C-063020
FAY-SED-RM149-
C-063020-D
FAY-SED-RM149-
C-063020-PT
6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/11/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample
<0.2 <0.2 <0.2 <0.2 <0.2 <0.66 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.29 <0.2 <0.2 <0.2 <0.2
<2 <2 <2 <2 <2 <3.3 <2 <2 <2 <2
<2 <2 <2 <2 <2 <4.9 <2 <2 <2 <2
<0.2 1.7 1.4 J <0.2 2.5 5.2 0.48 5.8 7 J <0.2
<0.2 <0.2 0.56 J <0.2 0.65 <0.93 <0.2 <0.2 <0.27 UJ 4.1
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.35 <0.2 <0.2 <0.2 <0.2
<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.00024 <0.0002 <0.0002 <0.0002 <0.0002
<2 <2 <2 <2 <2 <4.9 <2 <2 <2 10
<0.2 <0.2 <0.2 <0.2 <0.2 <0.32 UJ <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.54 UJ <0.2 <0.2 <0.2 <0.2
<2 <2 <2 <2 2.2 <5.1 <2 2 3.2 14
<0.2 <0.2 <0.2 <0.2 <0.2 <0.33 <0.2 <0.2 <0.2 <0.2
<0.2 0.44 0.38 J <0.2 0.58 2.3 0.2 0.58 0.72 0.53
<0.2 <0.2 <0.2 <0.2 <0.2 <0.51 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.29 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.79 <0.2 <0.2 <0.23 <0.2
<0.2 <0.2 0.23 J <0.2 0.48 <0.88 <0.2 0.37 0.56 0.4
<0.2 <0.2 <0.2 <0.2 <0.2 <0.46 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.38 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.58 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.41 <0.2 0.24 0.32 J 0.28 J
<0.2 <0.2 <0.2 <0.2 <0.2 <0.55 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.26 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.47 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.37 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <1.1 <0.2 <0.21 <0.31 1.5
<0.2 <0.2 <0.2 <0.2 <0.2 <0.26 <0.2 <0.2 <0.2 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <1 <0.2 <0.2 <0.29 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.71 <0.2 <0.2 0.23 <0.2
<0.2 <0.2 <0.2 <0.2 <0.2 <0.67 <0.2 0.21 0.29 0.28
<0.2 <0.2 <0.2 <0.2 0.36 <0.47 <0.2 0.31 J 0.44 0.47
<0.2 0.26 <0.2 <0.2 <0.2 <1.1 <0.2 <0.22 <0.33 <0.23
<0.5 1 0.59 J <0.5 1.4 3.1 <0.5 1.4 2 1.8
0 3.40 3.16 0 8.17 10.60 0.68 11.11 14.76 33.36
TR0795 Page 3 of 4 October 2020
TABLE 5B
SEDIMENT METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Method 537M Lab SOP (µg/kg)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Total Method 537 PFAS
N/A N/A N/A N/A N/A N/A
N/A N/A N/A N/A N/A N/A
EQBLK-1-051820 EQBLK-2-060920 EQBLK-3-061020 EQBLK-4-061120 FAY-EQBLK-5-062920 FAY-EQBLK-6-063020
5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.004 <0.004 <0.004 <0.004 <0.004 <0.004
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.002 <0.002 UJ <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.02 <0.02 <0.02 <0.02 <0.02 <0.02
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
<0.002 <0.002 <0.002 <0.002 <0.002 <0.002
0 0 0 0 0 0
NotesBold-Analyte detected above associated reporting limit.B -Analyte detected in an associated blank.J -Analyte detected. Reported value may not be accurate or precise.
< -Analyte not detected above associated reporting limit for PFAS or above the associated detection limit for TOC, TSS, DOC.UJ -Analyte not detected. Reporting limit may not be accurate or precise.
QA/QC -Quality assurance/Quality control
SOP -Standard Operating Procedures
"A"-Facing upstream, left bank location in transect."B"-Middle of channel location in transect."C"-Facing upstream, right bank location in transect.µg/kg -micrograms per kilogram
"-PT" in the sample ID indicates sample was collected with a push tube.
TR0795 Page 4 of 4 October 2020
TABLE 5C
SEDIMENT GEOTECHNICAL DATA RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Location in Transect A B C A A B C A A B C
Field Sample ID FAY-SED-RM20-
A-051820
FAY-SED-RM20-
B-051820
FAY-SED-RM20-
C-051820
FAY-SED-RM52-
A-051820
FAY-SED-RM52-
A-051820-D
FAY-SED-RM52-
B-051820
FAY-SED-RM52-
C-051820
FAY-SED-RM76-
A-060920
FAY-SED-RM76-
A-060920-PT
FAY-SED-RM76-
B-060920
FAY-SED-RM76-
C-060920
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020
QA/QC Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Geotechnical Parameters (% unless noted otherwise)
Total Organic Carbon (mg/kg)2,500 3,000 21,000 4,100 3,700 1,600 4,000 24,000 17,000 1,700 22,000
Percent Moisture 33 J 22 J 56 J 23 J 33 J 22 J 23 J 53 43 24 53
Percent Solids 67 J 78 J 44 J 78 J 67 J 78 J 77 J 48 57 76 47
Clay 2.5 0.9 11 5.8 6.1 1.1 7.7 22 31 1 19
Silt 7.2 14 38 12 J 6.7 J 4.3 20 47 46 2 40
Sand 90 74 49 82 87 94 65 32 24 97 41
Coarse Sand 0.2 16 0.7 0.7 J 0.3 J 1.5 5.1 2.9 0.4 0.2 1
Medium Sand 3.9 50 2.8 1.4 1.4 74 18 3 3.7 66 1.3
Fine Sand 86 8.5 45 80 86 19 42 26 20 31 38
Gravel 0 11 2.7 0 0 0.7 7 0 0 0 0
Sieve Size 3 inch - percent finer 100 100 100 100 100 100 100 100 100 100 100
Sieve Size 2 inch - percent finer 100 100 100 100 100 100 100 100 100 100 100
Sieve Size 1.5 inch - percent finer 100 100 100 100 100 100 100 100 100 100 100
Sieve Size 1 inch - percent finer 100 100 100 100 100 100 100 100 100 100 100
Sieve Size 0.75 inch - percent finer 100 100 100 100 100 100 100 100 100 100 100
Sieve Size 0.375 inch - percent finer 100 95 100 100 100 100 96 100 100 100 100
Sieve Size #4 - percent finer 100 89 97 100 100 99 93 100 100 100 100
Sieve Size #10 - percent finer 100 73 97 99 100 98 88 97 100 100 99
Sieve Size #20 - percent finer 99 45 95 99 100 79 81 96 99 92 98
Sieve Size #40 - percent finer 96 23 94 98 98 24 70 94 96 34 98
Sieve Size #60 - percent finer 63 19 91 76 74 6.6 55 92 94 5 96
Sieve Size #80 - percent finer 35 18 87 52 47 5.9 46 87 91 3.3 89
Sieve Size #100 - percent finer 24 17 81 39 34 5.5 40 83 88 3.1 82
Sieve Size #200 - percent finer 9.7 15 49 18 13 5.3 28 69 76 3 59
Hydrometer Reading 1 - Percent Finer 4.8 1.7 22 9.7 10 1.5 20 37 57 1.5 34
Hydrometer Reading 2 - Percent Finer 3.6 1.3 18 9.1 9.3 1.5 16 35 48 1 30
Hydrometer Reading 3 - Percent Finer 3.1 1.3 16 8 8.2 1.1 13 31 41 1 26
Hydrometer Reading 4 - Percent Finer 2.5 1.3 13 6.9 7.1 1.1 9.8 26 34 1 22
Hydrometer Reading 5 - Percent Finer 2.5 0.9 11 5.8 6.1 1.1 7.7 22 31 1 19
Hydrometer Reading 6 - Percent Finer 1.8 0.8 7.8 3.4 4.4 1 4.4 16 23 1 15
Hydrometer Reading 7 - Percent Finer 1.2 0.8 5.7 2.3 2.8 0.5 2.8 11 16 0.5 10
TR0795 Page 1 of 4 October 2020
TABLE 5C
SEDIMENT GEOTECHNICAL DATA RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Geotechnical Parameters (% unless noted otherwise)
Total Organic Carbon (mg/kg)
Percent Moisture
Percent Solids
Clay
Silt
Sand
Coarse Sand
Medium Sand
Fine Sand
Gravel
Sieve Size 3 inch - percent finer
Sieve Size 2 inch - percent finer
Sieve Size 1.5 inch - percent finer
Sieve Size 1 inch - percent finer
Sieve Size 0.75 inch - percent finer
Sieve Size 0.375 inch - percent finer
Sieve Size #4 - percent finer
Sieve Size #10 - percent finer
Sieve Size #20 - percent finer
Sieve Size #40 - percent finer
Sieve Size #60 - percent finer
Sieve Size #80 - percent finer
Sieve Size #100 - percent finer
Sieve Size #200 - percent finer
Hydrometer Reading 1 - Percent Finer
Hydrometer Reading 2 - Percent Finer
Hydrometer Reading 3 - Percent Finer
Hydrometer Reading 4 - Percent Finer
Hydrometer Reading 5 - Percent Finer
Hydrometer Reading 6 - Percent Finer
Hydrometer Reading 7 - Percent Finer
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Cape Fear River
Mile 116
A B C A B C C A B C A
FAY-SED-RM77-
A-061020
FAY-SED-RM77-
B-061020
FAY-SED-RM77-
C-061020
FAY-SED-RM84-
A-061020
FAY-SED-RM84-
B-061020
FAY-SED-RM84-
C-061020
FAY-SED-RM84-
C-061020-PT
FAY-SED-RM100-
A-062020
FAY-SED-RM100-
B-062920
FAY-SED-RM100-
C-062920
FAY-SED-RM116-
A-062920
6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/10/2020 6/29/2020 6/29/2020 6/29/2020 6/29/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
20,000 <1,000 18,000 30,000 960 J 16,000 26,000 20,000 1,100 18,000 25,000
44 J 23 J 51 J 55 J 21 J 54 J 52 J 30 J 22 J 47 J 33 J
56 J 77 J 49 J 45 J 79 J 47 J 48 J 70 J 78 J 53 J 67 J
26 1 24 30 1.6 22 35 3.5 1 19 30
53 2 39 52 2.7 43 40 1.6 3.7 39 42
21 94 38 18 90 35 25 95 95 42 29
1.2 6.6 1.5 1.7 6.7 1.4 1.3 0.1 1.3 0.4 0
2.2 60 1.2 1.9 74 2.5 4.1 0.7 61 3.4 1.7
18 27 35 14 8.9 31 20 94 33 38 27
0 3.4 0 0 5.7 0 0 0 0 0 0
100 100 100 100 100 100 100 100 100 100 100
100 100 100 100 100 100 100 100 100 100 100
100 100 100 100 100 100 100 100 100 100 100
100 100 100 100 100 100 100 100 100 100 100
100 100 100 100 100 100 100 100 100 100 100
100 100 100 100 96 100 100 100 100 100 100
100 97 100 100 94 100 100 100 100 100 100
99 90 99 98 88 99 99 100 99 100 100
98 73 98 97 53 97 97 100 80 98 100
97 30 97 96 13 96 95 99 38 96 98
93 5.9 95 95 5.9 92 91 85 10 93 97
90 3.5 87 93 4.8 85 87 44 6.3 83 94
87 3.2 81 91 4.6 79 84 22 5.2 75 89
79 3 62 82 4.4 65 75 5.1 4.6 59 71
46 1.9 38 53 2.1 36 59 5.2 1.4 34 60
42 1.4 35 47 1.6 35 51 5.2 1.4 32 45
34 1.4 31 43 1.6 31 44 4.6 1.4 28 40
30 1 27 36 1.6 26 40 4.6 1.4 25 35
26 1 24 30 1.6 22 35 3.5 1 19 30
20 0.5 18 22 1.1 17 26 2.4 0.5 14 24
14 0.5 12 16 0.6 12 18 1.8 0.5 9.8 19
TR0795 Page 2 of 4 October 2020
TABLE 5C
SEDIMENT GEOTECHNICAL DATA RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Geotechnical Parameters (% unless noted otherwise)
Total Organic Carbon (mg/kg)
Percent Moisture
Percent Solids
Clay
Silt
Sand
Coarse Sand
Medium Sand
Fine Sand
Gravel
Sieve Size 3 inch - percent finer
Sieve Size 2 inch - percent finer
Sieve Size 1.5 inch - percent finer
Sieve Size 1 inch - percent finer
Sieve Size 0.75 inch - percent finer
Sieve Size 0.375 inch - percent finer
Sieve Size #4 - percent finer
Sieve Size #10 - percent finer
Sieve Size #20 - percent finer
Sieve Size #40 - percent finer
Sieve Size #60 - percent finer
Sieve Size #80 - percent finer
Sieve Size #100 - percent finer
Sieve Size #200 - percent finer
Hydrometer Reading 1 - Percent Finer
Hydrometer Reading 2 - Percent Finer
Hydrometer Reading 3 - Percent Finer
Hydrometer Reading 4 - Percent Finer
Hydrometer Reading 5 - Percent Finer
Hydrometer Reading 6 - Percent Finer
Hydrometer Reading 7 - Percent Finer
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149
Cape Fear River
Mile 149 N/A
B C A B C A B C C C N/A
FAY-SED-RM116-
B-062920
FAY-SED-RM116-
C-062920
FAY-SED-RM132-
A-061120
FAY-SED-RM132-
B-061120
FAY-SED-RM132-
C-061120
FAY-SED-RM149-
A-063020
FAY-SED-RM149-
B-063020
FAY-SED-RM149-
C-063020
FAY-SED-RM149-
C-063020-D
FAY-SED-RM149-
C-063020-PT EQBLK-1-051820
6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/11/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020 6/30/2020 5/18/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Duplicate Field Sample Equipment Blank
18,000 33,000 17,000 <1,000 19,000 28,000 3,400 29,000 ------
23 J 43 J 43 25 51 62 J 31 J 62 J 75 J 63 J --
78 J 57 J 57 75 49 38 J 69 J 38 J 25 J 37 J --
0.5 15 17 1.3 25 30 5.8 34 ------
6.2 25 42 3.5 32 50 12 55 ------
93 60 40 95 41 19 82 10 ------
1.6 0.2 0.6 0.1 0.1 0.2 0.1 0.2 ------
70 1.7 12 54 2 2.2 0.7 2.2 ------
21 58 28 41 39 17 81 7.8 ------
0 0 1.3 0.5 2.6 0 0 0.7 ------
100 100 100 100 100 100 100 100 ------
100 100 100 100 100 100 100 100 ------
100 100 100 100 100 100 100 100 ------
100 100 100 100 100 100 100 100 ------
100 100 100 100 100 100 100 100 ------
100 100 100 100 98 100 100 100 ------
100 100 99 100 97 100 100 99 ------
98 100 98 99 97 100 100 99 ------
78 99 95 92 97 99 100 98 ------
28 98 87 45 95 98 99 97 ------
8.9 90 78 9.2 87 97 94 96 ------
7.4 73 75 5.1 75 95 69 95 ------
7 61 73 4.9 68 93 40 94 ------
6.8 40 59 4.9 56 81 18 89 ------
0.9 27 38 2.2 45 54 12 58 ------
0.9 26 33 2.2 42 47 9.8 55 ------
0.5 23 26 1.8 33 40 8.6 48 ------
0.5 20 20 1.8 28 35 6.9 41 ------
0.5 15 17 1.3 25 30 5.8 34 ------
0.07 11 12 0.9 19 24 4.1 27 ------
0.07 8.6 8.7 0.9 14 16 2.9 17 ------
TR0795 Page 3 of 4 October 2020
TABLE 5C
SEDIMENT GEOTECHNICAL DATA RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Location ID
Location in Transect
Field Sample ID
Sample Date
QA/QC
Geotechnical Parameters (% unless noted otherwise)
Total Organic Carbon (mg/kg)
Percent Moisture
Percent Solids
Clay
Silt
Sand
Coarse Sand
Medium Sand
Fine Sand
Gravel
Sieve Size 3 inch - percent finer
Sieve Size 2 inch - percent finer
Sieve Size 1.5 inch - percent finer
Sieve Size 1 inch - percent finer
Sieve Size 0.75 inch - percent finer
Sieve Size 0.375 inch - percent finer
Sieve Size #4 - percent finer
Sieve Size #10 - percent finer
Sieve Size #20 - percent finer
Sieve Size #40 - percent finer
Sieve Size #60 - percent finer
Sieve Size #80 - percent finer
Sieve Size #100 - percent finer
Sieve Size #200 - percent finer
Hydrometer Reading 1 - Percent Finer
Hydrometer Reading 2 - Percent Finer
Hydrometer Reading 3 - Percent Finer
Hydrometer Reading 4 - Percent Finer
Hydrometer Reading 5 - Percent Finer
Hydrometer Reading 6 - Percent Finer
Hydrometer Reading 7 - Percent Finer
N/A N/A N/A N/A N/A
N/A N/A N/A N/A N/A
EQBLK-2-060920 EQBLK-3-061020 EQBLK-4-061120 FAY-EQBLK-5-062920 FAY-EQBLK-6-063020
6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Equipment Blank Equipment Blank Equipment Blank Equipment Blank Equipment Blank
<1.1 <1.1 <1.1 2.8 J 2.4 J
<0.35 <0.35 <0.35 <0.35 0.39 J
<350,000 500,000 J <350,000 <350,000 <350,000
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
----------
Notes
B -Analyte detected in an associated blank.
J -Analyte detected. Reported value may not be accurate or precise.
< -Analyte not detected above associated reporting limit for PFAS or above the associated detection
limit for TOC, TSS, DOC.
UJ -Analyte not detected. Reporting limit may not be accurate or precise.
QA/QC -Quality assurance/Quality control
SOP -Standard Operating Procedures
"A"-Facing upstream, left bank location in transect.
"B"-Middle of channel location in transect.
"C"-Facing upstream, right bank location in transect.
mg/kg -miligrams per kilogram
"--" indicates analysis not performed.
TR0795 Page 4 of 4 October 2020
TABLE 6A
SURFACE WATER TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Field Sample ID FAY-SW-RM-20-
B-6.7-05182020
FAY-SW-RM-20-
B-20-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-76-
B-13-06092020
FAY-SW-RM-76-
B-21-06092020
FAY-SW-RM-77-
B-10-06092020
FAY-SW-RM-77-
B-18-06092020
FAY-SW-RM-84-
B-10-06102020
FAY-SW-RM-84-
B-18-06102020
FAY-SW-RM-100-
B-9.5-06292020
Sample Depth from Surface (ft)6.7 12 1.6 1.6 13 21 10 18 10 18 9.5
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020 6/10/2020 6/10/2020 6/29/2020
QA/QC Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Table 3+ Lab SOP (ng/L)
Hfpo Dimer Acid <2 <2 <2 <2 <2 <2 <2 2.2 11 J 11 15
PFMOAA <5 <5 <5 <5 <2 <2 UJ <2 <2 18 J 18 24 J
PFO2HxA <2 <2 <2 <2 <2 <2 2.4 2.6 15 16 23
PFO3OA <2 <2 <2 <2 <2 <2 <2 <2 3.5 3.4 5.3
PFO4DA <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2.6
PFO5DA <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
PMPA 28 31 27 28 22 23 <13 <13 <13 <13 34
PEPA <20 <20 <20 <20 <2 <2 <2 <2 <2 3.1 4.9
PS Acid <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
Hydro-PS Acid <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
R-PSDA <2 <2 19 J 21 J <2 <2 <2 <2 <2 3.8 J 3.7 J
Hydrolyzed PSDA <2 <2 <2 <2 <2 <2 <2 <2 8 J 8.7 J 9.6 J
R-PSDCA <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
NVHOS 7.5 8.1 5 4.6 <2 <2 <2 <2 <2 <2 2
EVE Acid <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
Hydro-EVE Acid <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
R-EVE <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
PES <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
PFECA B <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
PFECA-G <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
Total Table 3+ (17 compounds)35.5 39.1 32 32.6 22 23 2.4 4.8 47.5 51.5 110.8
Total Table 3+ (20 compounds)35.5 39.1 51 53.6 22 23 2.4 4.8 55.5 64 124.1
TR0795 Page 1 of 3 October 2020
TABLE 6A
SURFACE WATER TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Table 3+ Lab SOP (ng/L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ (17 compounds)
Total Table 3+ (20 compounds)
Cape Fear River
Mile 100
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149 N/A N/A N/A N/A N/A
FAY-SW-RM-100-
B-17-06292020
FAY-SW-RM-116-
B-7.5-06292020
FAY-SW-RM-116-
B-13-06292020
FAY-SW-RM-132-
B-6-06112020
FAY-SW-RM-132-
B-10-06112020
FAY-SW-RM-149-
B-1.5-06302020 TBLK-1-051820 TBLK-2-060920 TBLK-3-061020 TBLK-4-061120 FAY-TBLK-5-
062920
17 7.5 13 6 10 1.5 N/A N/A N/A N/A N/A
6/29/2020 6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/30/2020 5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Trip Blank Trip Blank Trip Blank Trip Blank Trip Blank
14 13 12 5.9 6 11 <2 <2 <4 <2 <2
26 24 23 17 J 18 27 J <5 <2 <2 <2 <2
23 21 20 14 13 21 <2 <2 <2 <2 <2
5.7 4.3 4.4 3.3 3.2 4.6 <2 <2 <2 <2 <2
<2 <2 2.1 <2 <2 2.1 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
42 21 37 <13 <13 17 <10 <13 <13 <13 <13
4.5 3.7 3.8 <2 <2 2.6 <20 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
3.6 J 2.4 J 3.0 J 4.8 J 6.6 J <2 <2 <2 <2 <2 <2
9.5 J 11 J 8.0 J 4.5 J 5.2 J 2.7 J <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
2.3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
117.5 87 102.3 40.2 40.2 85.3 0 0 0 0 0
130.6 100.4 113.3 49.5 52 88 0 0 0 0 0
TR0795 Page 2 of 3 October 2020
TABLE 6A
SURFACE WATER TABLE 3+
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Table 3+ Lab SOP (ng/L)
Hfpo Dimer Acid
PFMOAA
PFO2HxA
PFO3OA
PFO4DA
PFO5DA
PMPA
PEPA
PS Acid
Hydro-PS Acid
R-PSDA
Hydrolyzed PSDA
R-PSDCA
NVHOS
EVE Acid
Hydro-EVE Acid
R-EVE
PES
PFECA B
PFECA-G
Total Table 3+ (17 compounds)
Total Table 3+ (20 compounds)
N/A N/A N/A N/A N/A N/A N/A
FAY-TBLK-6-
063020 FBLK-1-051820 FBLK-2-060920 FBLK-3-061020 FBLK-4-061120 FAY-FBLK-5-
062920
FAY-FBLK-6-
063020
N/A N/A N/A N/A N/A N/A N/A
6/30/2020 5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Trip Blank Field Blank Field Blank Field Blank Field Blank Field Blank Field Blank
<2 <2 <2 <2 <2 <2 <2
<2 <5 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<13 <10 <13 <13 <13 <13 <13
<2 <20 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
0 0 0 0 0 0 0
0 0 0 0 0 0 0
Notes:
Bold -Analyte detected above associated reporting limit.
B -Analyte detected in an associated blank.
J -Analyte detected. Reported value may not be accurate or precise.
< -Analyte not detected above associated reporting limit for PFAS or above the associated
detection limit for TOC, TSS, DOC.
UJ -Analyte not detected. Reporting limit may not be accurate or precise.
QA/QC -Quality assurance/Quality control
SOP -Standard Operating Procedures
ng/L -nanograms per liter
TR0795 Page 3 of 3 October 2020
TABLE 6B
SURFACE WATER METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Field Sample ID FAY-SW-RM-20-
B-6.7-05182020
FAY-SW-RM-20-
B-20-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-76-
B-13-06092020
FAY-SW-RM-76-
B-21-06092020
FAY-SW-RM-77-
B-10-06092020
FAY-SW-RM-77-
B-18-06092020
FAY-SW-RM-84-
B-10-06102020
FAY-SW-RM-84-
B-18-06102020
FAY-SW-RM-100-
B-9.5-06292020
Sample Depth from Surface (ft)6.7 12 1.6 1.6 13 21 10 18 10 18 9.5
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020 6/10/2020 6/10/2020 6/29/2020
QA/QC Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
11Cl-PF3OUdS <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<20 <20 <20 <20 <20 <20 <20 UJ <20 UJ <20 <20 <20
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<20 <20 <20 <20 <20 <20 <20 UJ <20 UJ <20 <20 <20
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <4 <4 <4 <4 <4 <4 <4 UJ <4 UJ <4 <4 <4
6:2 Fluorotelomer sulfonate <20 <20 <20 <20 <20 <20 <20 UJ <20 UJ <20 <20 <20
9Cl-PF3ONS <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
DONA <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
N-ethyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20 <20 <20 UJ <20 UJ <20 <20 <20
N-ethylperfluoro-1-octanesulfonamide <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 UJ <2 UJ <2
N-methyl perfluoro-1-octanesulfonamide <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 UJ <2
N-methyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20 <20 <20 UJ <20 UJ <20 <20 <20
Perfluorobutane Sulfonic Acid 4 4.1 4.4 4.3 3.9 4 4.1 J 4.3 J 4.3 J 4.1 4.4
Perfluorobutanoic Acid 5.8 5.7 6.1 6 6.5 6.4 5.3 J 5.3 J 6.4 J 6.3 J 5.5
Perfluorodecane Sulfonic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluorodecanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluorododecane sulfonic acid (PFDoS)<2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 UJ <2 <2
Perfluorododecanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluoroheptane sulfonic acid (PFHpS)<2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluoroheptanoic Acid 7 8.1 7.3 7.2 5.9 5.9 6.7 J 6 J 6.1 J 6.2 3.6
Perfluorohexadecanoic acid (PFHxDA)<2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2 UJ
Perfluorohexane Sulfonic Acid 3.4 3.4 5.6 5.7 3.6 3.8 4.4 J 3.4 J 4 J 4 4.3
Perfluorohexanoic Acid 14 14 14 14 11 11 13 J 11 J 11 J 11 7.6
Perfluorononanesulfonic acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluorononanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluorooctadecanoic acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2 UJ
Perfluorooctane Sulfonamide <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluoropentane sulfonic acid (PFPeS)<2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluoropentanoic Acid 10 11 13 12 8.9 8.8 10 J 9.6 J 9.5 J 9.6 7.9
Perfluorotetradecanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluorotridecanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
Perfluoroundecanoic Acid <2 <2 <2 <2 <2 <2 <2 UJ <2 UJ <2 <2 <2
PFOA 8.3 6.8 7.1 6.9 7.6 7.3 7.8 J 8.1 J 7.2 J 7.2 7.3
PFOS 11 11 15 14 13 14 14 J 14 J 14 J 15 14
Total Method 537 PFAS 63.5 64.1 72.5 70.1 60.4 61.2 65.3 61.7 62.5 63.4 54.6
TR0795 Page 1 of 3 October 2020
TABLE 6B
SURFACE WATER METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Total Method 537 PFAS
Cape Fear River
Mile 100
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149 N/A N/A N/A N/A N/A
FAY-SW-RM-100-
B-17-06292020
FAY-SW-RM-116-
B-7.5-06292020
FAY-SW-RM-116-
B-13-06292020
FAY-SW-RM-132-
B-6-06112020
FAY-SW-RM-132-
B-10-06112020
FAY-SW-RM-149-
B-1.5-06302020 TBLK-1-051820 TBLK-2-060920 TBLK-3-061020 TBLK-4-061120 FAY-TBLK-5-
062920
17 7.5 13 6 10 1.5 N/A N/A N/A N/A N/A
6/29/2020 6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/30/2020 5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Trip Blank Trip Blank Trip Blank Trip Blank Trip Blank
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<4 <4 <4 <4 <4 <4 <4 <4 <4 <4 <4
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2 <2 UJ <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20
4.6 4 4 3.8 3.8 3.8 <2 <2 <2 <2 <2
5.2 5.1 5.2 5.5 5.8 4.7 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 UJ <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
3.8 3.6 3.5 5.4 5.6 3.1 <2 <2 <2 <2 <2
<2 UJ <2 UJ <2 UJ <2 <2 <2 UJ <2 <2 <2 <2 <2
4.5 4.2 4.2 3.5 3.6 4.4 <2 <2 <2 <2 <2
7.6 6.9 6.7 11 10 6.5 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 UJ <2 UJ <2 UJ <2 <2 <2 UJ <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
7.6 7.6 7.4 8.6 8.6 6.8 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2
7.4 6.7 6.6 7.3 7.6 6.2 <2 <2 <2 <2 <2
14 13 14 14 14 13 <2 <2 <2 <2 <2
54.7 51.1 51.6 59.1 59 48.5 0 0 0 0 0
TR0795 Page 2 of 3 October 2020
TABLE 6B
SURFACE WATER METHOD 537M
PFAS ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Other PFAS (ng/L)
10:2 Fluorotelomer sulfonate
11Cl-PF3OUdS
1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)
1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)
2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol
2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol
6:2 Fluorotelomer sulfonate
9Cl-PF3ONS
DONA
N-ethyl perfluorooctane sulfonamidoacetic acid
N-ethylperfluoro-1-octanesulfonamide
N-methyl perfluoro-1-octanesulfonamide
N-methyl perfluorooctane sulfonamidoacetic acid
Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluorodecane Sulfonic Acid
Perfluorodecanoic Acid
Perfluorododecane sulfonic acid (PFDoS)
Perfluorododecanoic Acid
Perfluoroheptane sulfonic acid (PFHpS)
Perfluoroheptanoic Acid
Perfluorohexadecanoic acid (PFHxDA)
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluorononanesulfonic acid
Perfluorononanoic Acid
Perfluorooctadecanoic acid
Perfluorooctane Sulfonamide
Perfluoropentane sulfonic acid (PFPeS)
Perfluoropentanoic Acid
Perfluorotetradecanoic Acid
Perfluorotridecanoic Acid
Perfluoroundecanoic Acid
PFOA
PFOS
Total Method 537 PFAS
N/A N/A N/A N/A N/A N/A N/A
FAY-TBLK-6-
063020 FBLK-1-051820 FBLK-2-060920 FBLK-3-061020 FBLK-4-061120 FAY-FBLK-5-
062920
FAY-FBLK-6-
063020
N/A N/A N/A N/A N/A N/A N/A
6/30/2020 5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Trip Blank Field Blank Field Blank Field Blank Field Blank Field Blank Field Blank
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20
<20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2
<4 <4 <4 <4 <4 <4 <4
<20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20
<2 <2 <2 UJ <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<20 <20 <20 <20 <20 <20 <20
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
<2 <2 <2 <2 <2 <2 <2
0 0 0 0 0 0 0
Notes:
Bold -Analyte detected above associated reporting limit.
B -Analyte detected in an associated blank.
J -Analyte detected. Reported value may not be accurate or precise.
< -Analyte not detected above associated reporting limit for PFAS or
above the associated detection limit for TOC, TSS, DOC.
UJ -Analyte not detected. Reporting limit may not be accurate or
precise.
QA/QC -Quality assurance/Quality control
SOP -Standard Operating Procedures
ng/L -nanograms per liter
TR0795 Page 3 of 3 October 2020
TABLE 6C
OTHER SURFACE WATER ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID Cape Fear River
Mile 20
Cape Fear River
Mile 20
Cape Fear River
Mile 52
Cape Fear River
Mile 52
Cape Fear River
Mile 76
Cape Fear River
Mile 76
Cape Fear River
Mile 77
Cape Fear River
Mile 77
Cape Fear River
Mile 84
Cape Fear River
Mile 84
Cape Fear River
Mile 100
Cape Fear River
Mile 100
Field Sample ID FAY-SW-RM-20-
B-6.7-05182020
FAY-SW-RM-20-
B-20-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-52-
B-1.6-05182020
FAY-SW-RM-76-
B-13-06092020
FAY-SW-RM-76-
B-21-06092020
FAY-SW-RM-77-
B-10-06092020
FAY-SW-RM-77-
B-18-06092020
FAY-SW-RM-84-
B-10-06102020
FAY-SW-RM-84-
B-18-06102020
FAY-SW-RM-100-
B-9.5-06292020
FAY-SW-RM-100-
B-17-06292020
Sample Depth from Surface (ft)6.7 12 1.6 1.6 13 21 10 18 10 18 9.5 17
Sample Date 5/18/2020 5/18/2020 5/18/2020 5/18/2020 6/9/2020 6/9/2020 6/9/2020 6/9/2020 6/10/2020 6/10/2020 6/29/2020 6/29/2020
QA/QC Field Sample Field Sample Field Sample Duplicate Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample Field Sample
Other Parameters (mg/L)
Total Suspended Solids <1.1 30 2.8 J 2.8 J 37 59 28 50 22 17 17 J 13 B
Total Organic Carbon 5.4 5.6 5.1 5.4 6.3 6.2 6.3 6.4 6.5 5.4 9.8 9.5
Dissolved Organic Carbon 5.2 5 4.7 4.7 6.4 6.5 6.2 6.2 6.2 5.6 5.1 9.9
TR0795 Page 1 of 3 October 2020
TABLE 6C
OTHER SURFACE WATER ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Other Parameters (mg/L)
Total Suspended Solids
Total Organic Carbon
Dissolved Organic Carbon
Cape Fear River
Mile 116
Cape Fear River
Mile 116
Cape Fear River
Mile 132
Cape Fear River
Mile 132
Cape Fear River
Mile 149 N/A N/A N/A N/A N/A N/A N/A
FAY-SW-RM-116-
B-7.5-06292020
FAY-SW-RM-116-
B-13-06292020
FAY-SW-RM-132-
B-6-06112020
FAY-SW-RM-132-
B-10-06112020
FAY-SW-RM-149-
B-1.5-06302020 TBLK-1-051820 TBLK-2-060920 TBLK-3-061020 TBLK-4-061120 FAY-TBLK-5-
062920
FAY-TBLK-6-
063020 FBLK-1-051820
7.5 13 6 10 1.5 N/A N/A N/A N/A N/A N/A N/A
6/29/2020 6/29/2020 6/11/2020 6/11/2020 6/30/2020 5/18/2020 6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020 5/18/2020
Field Sample Field Sample Field Sample Field Sample Field Sample Trip Blank Trip Blank Trip Blank Trip Blank Trip Blank Trip Blank Field Blank
9.2 B 18 J 18 23 3.6 B --------------
10 10 8.3 8.3 11 --------------
11 11 8.5 8.2 11 --------------
TR0795 Page 2 of 3 October 2020
TABLE 6C
OTHER SURFACE WATER ANALYTICAL RESULTS
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC P.C.
Location ID
Field Sample ID
Sample Depth from Surface (ft)
Sample Date
QA/QC
Other Parameters (mg/L)
Total Suspended Solids
Total Organic Carbon
Dissolved Organic Carbon
N/A N/A N/A N/A N/A
FBLK-2-060920 FBLK-3-061020 FBLK-4-061120 FAY-FBLK-5-
062920
FAY-FBLK-6-
063020
N/A N/A N/A N/A N/A
6/9/2020 6/10/2020 6/11/2020 6/29/2020 6/30/2020
Field Blank Field Blank Field Blank Field Blank Field Blank
<1.1 <1.1 <1.1 1.2 J <1.1 UJ
<0.35 <0.35 <0.35 <0.35 <0.35
<0.35 <0.35 <0.35 <0.35 <0.35
Notes:
B -Analyte detected in an associated blank.
J -Analyte detected. Reported value may not be accurate or precise.
< -Analyte not detected above associated reporting limit for PFAS or above the associated detection limit for total organic carbon,
total suspended solids, dissolved organic carbon.
UJ -Analyte not detected. Reporting limit may not be accurate or precise.
QA/QC -Quality assurance/Quality control
SOP -Standard Operating Procedures
mg/L -miligrams per liter
FS -Field Sample
TR0795 Page 3 of 3 October 2020
TABLE 7
HFPO-DA SURFACE WATER DATA COMPARISON
BETWEEN HUMAN HEALTH SLEA AND SEDIMENT CHARACTERIZATION
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC, PC
Sample Location
Code
Relevant
Exposure Unit
Average
HFPO-DA
(ng/L)
Number of
detects
averaged
CTE EPC*
(ng/L)
RME EPC**
(ng/L)
Average from
2019 samples
only (ng/L)
Detects/
Samples
Collected in
2019
RM-20 --<2 0 --------
RM-52 EU13 <2 0 5 5 5 1/5
RM-76 EU14 <2 0 23 34.98 5.98 9/12
RM-77 EU14 2.2 1 23 34.98 5.98 9/12
RM-84 EU16 11 2 133.6 318.6 32.7 3/3
RM-100 --14.5 2 --------
RM-116 --12.5 2 --------
RM-132 EU17 5.95 2 16.38 18.65 18.9 41/41
RM-149 --11 1 --------
Notes:
*CTE EPC - central tendency exposure point concentration, corresponding to the arithmetic average concentration
Sediment Characterization
Data (2020) -
Surface Water Samples
Surface Water EPC from
SLEA
**RME EPC - reasonable maximum exposure point concentration, corresponding to either the 95% upper
confidence limit on the mean or the maximum detected concentration if the UCL could not be reliably calculated.
2019 Surface Water Samples
TR0795 Page 1 of 1 October 2020
TABLE 8
HFPO-DA CONCENTRATIONS
IN CAPE FEAR RIVER SEDIMENT
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants NC, PC
Sample Location Code Relevant Exposure Unit Average HFPO-DA
(µg/kg)Number of Detects Averaged
RM-20 --<0.25 0/3
RM-52 EU13 <0.25 0/4
RM-76 EU14 2.13 3/4
RM-77 EU14 2.5 1/3
RM-84 EU16 <0.25 0/4
RM-100 --<0.25 0/3
RM-116 --<0.25 0/3
RM-132 EU17 <0.25 0/3
RM-149 --0.34 1/5
Notes
*Concentration of HFPODA in sediment samples (in µg/kg) divided by concentration of HFPODA in surface water samples (in
ng/L), where one liter of water is assumed to weigh one kilogram. The higher this number is, the higher sediment concentrations
are relative to surface water concentrations.
TR0795 Page 1 of 1 October 2020
TABLE 9
COMPARISON OF TABLE 3+ PFAS PROFILES
SEDIMENT CHARACTERIZATION VS. ECOLOGICAL SLEA
Chemours Fayetteville Works, North Carolina
Geosyntec Consultants of NC P.C.
Maximum FOD Maximum FOD Maximum FOD Maximum FOD
Table 3+ Lab SOP ng/L %ng/L %µg/kg %µg/kg %
HFPO Dimer Acid 15 53%15 78%2.5 15%2.6 17%
PFMOAA 27 47%71 67%9.9 6%ND 0%
PFO2HxA 23 58%25 100%7.6 15%ND 0%
PFO3OA 5.7 47%6 33%2.2 6%ND 0%
PFO4DA 2.6 16%2 11%1.4 3%ND 0%
PFO5DA ND 0%ND 0%1.4 3%ND 0%
PMPA 42 58%19 33%1.9 21%ND 0%
PEPA 4.9 32%ND 0%0 0%ND 0%
PS Acid ND 0%ND 0%1.8 3%ND 0%
Hydro-PS Acid ND 0%ND 0%0 0%ND 0%
R-PSDA 21 47%9 89%0 0%ND 0%
Hydrolyzed PSDA 11 47%19 67%0 0%ND 0%
R-PSDCA ND 0%ND 0%0 0%ND 0%
NVHOS 8.1 32%7 100%0 0%ND 0%
EVE Acid ND 0%ND 0%0 0%ND 0%
Hydro-EVE Acid ND 0%ND 0%0 0%ND 0%
R-EVE ND 0%4 78%12 3%ND 0%
PES ND 0%ND 0%0 0%ND 0%
PFECA B ND 0%ND 0%0 0%ND 0%
PFECA-G ND 0%ND 0%0 0%ND 0%
Notes:
Eco -SLEA reflects data from the Cape Fear River Exposure Unit of the Ecological Screening Level Exposure Assessment.
FOD - frequency of detection
µg/kg - micrograms per kilogram
ng/L - nanograms per liter
ND - not detected above reporting limit
Surface Water Sediment
2020 Eco-SLEA 2020 Eco-SLEA
TR0795 Page 1 of 1 October 2020

FIGURES

^_
!(
!(
!(!(
!(
!(
!(
!(
!(
Kings Bluff Intake Canal
ChemoursFayettevilleWorks
Start ofCape FearRiver
Wilmington
Fayetteville
Raleigh
Bladen BluffsIntake
W.O. Huske Dam
Greensboro
Tar HeelFerry RoadBridge
Virginia
NorthCarolina
SouthCarolina
CFR-RM-20
CFR-RM-52
CFR-RM-76
CFR-RM-77CFR-RM-84
CFR-RM-100CFR-RM-116
CFR-RM-132
CFR-RM-149
Sources: Esri, Garmin, USGS, NPS
Cape Fear River Watershed and Downstream Drinking Water Intakes
Chemours Fayetteville Works, North Carolina
Figure
1Raleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\TR0795_Cape Fear River Watershed and Downstream Intakes.mxd; TIp; 10/02/2020October 2020
³Deep R
i
verH awRiv
er
LittleRiver
CapeFearRiver
20 0 2010 Miles
Note:Basemap sources: Esri, DigitalGlobe, GeoEye, EarthstarGeographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community.
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Legend
!(Sediment Sample
^_Chemours Fayetteville Works
Upper Basin
Middle Basin
Lower Basin
")
")
")
!(
!(
Willis Creek
Old Outfall 002Cape Fear RiverOutfall 002
W.O. Huske Dam
Site River Water Intake
NC Highway 87Seep A
Seep B
Seep C
Seep D
GBCTributary1GeorgiaBranchCreek
CFR-RM-76
CFR-RM-77
Site Location Map
Figure
2Raleigh
1,000 0 1,000500 Feet
³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\TR0795_SiteLocation.mxd Last Revised: 10/2/2020 Author: TIpOctober 2020
Notes:1. Both sediment and surface water samples were collected at the indicated location.2. The outline of Cape Fear River is approximate and is based on open data from ArcGIS Online and North Carolina Department ofEnvironmental Quality Online GIS (MajorHydro shapefile).3. Basemap sources: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GISUser Community
Chemours Fayetteville Works, North Carolina
Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US
Legend
!(Sediment Sample¹
")Site Features
Site Boundary
Nearby Tributary
Observed Seep (Natural Drainage)
Site Conveyance Network
Areas at Site
Chemours Monomers IXM
Former DuPont PMDF Area
Wastewater Treatment Plant
Kuraray SentryGlas®Leased Area
Kuraray Trosifol®Leased Area
DuPont Polyvinyl FluorideLeased Area
Chemours PolymerProcessing Aid Area Power - Filtered andDemineralized WaterProductionKuraray Laboratory
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake ""
!(
!(
!(
RM-20-A RM-20-B
RM-20-CRM-20-B-6.7RM-20-B-20
Sampling SegmentsCFR-RM-20Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3aRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake "
!(
!(!(
RM-52-A
RM-52-B
RM-52-C
RM-52-B-1.6
Sampling SegmentsCFR-RM-52Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3bRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake
""
""
!(!(!(!(
!(!(!(WillisCre
e
k
RM-76-B
RM-76-CRM-76-A
RM-77-A
RM-77-B
RM-77-C
RM-76-B-21RM-76-B-13
RM-77-B-18RM-77-B-10
Sampling SegmentsCFR-RM-76 and CFR-RM-77Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3cRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
Observed Seep
³
8 0 84 Miles
500 0 500250 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake ""
!(
!(
!(!(
XW
RM-84-A
RM-84-B
RM-84-C
RM-84-B-10RM-84-B-18
Bladen BluffDrinking WaterWithdrawal
Sampling SegmentsCFR-RM-84Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3dRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake
""
!(
!(
!(
RM-100-A
RM-100-B
RM-100-CRM-100-B-9.5RM-100-B-17
Sampling SegmentsCFR-RM-100Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3eRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake
""!(!(!(RM-116-A
RM-116-B
RM-116-C
RM-116-B-7.5RM-116-B-13
Sampling SegmentsCFR-RM-116Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3fRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake
#*
""!(!(
!(
XW
RM-132-A RM-132-B
RM-132-C
RM-132-B-6RM-132-B-10
02105769
Kings Bluff IntakeDrinking WaterWithdrawal
Sampling SegmentsCFR-RM-132Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3gRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
#*
#*
#*
#*
!(
!(
!(!(
!(
!(
!(
!(
!(
XW
XW
XW
XW
Chemours FayettevilleWorks
W.O. Huske Dam
CFR-RM-20
CFR-RM-52
CFR-RM-76 CFR-RM-77
CFR-RM-84
CFR-RM-100
CFR-RM-116
CFR-RM-132
CFR-RM-149
02102500
02105769
02104000
02105500
Bladen BluffDrinking WaterWithdrawal
Kings BluffIntake DrinkingWater Withdrawal
Harnett CountyDrinkingWater Intake
City of FayettevilleDrinking Water Intake
"!(!(!(!(
RM-149-ARM-149-B
RM-149-C
RM-149-B-1.5
Sampling SegmentsCFR-RM-149Chemours Fayetteville WorksFayetteville, North Carolina
Figure
3hRaleigh
Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Sediment Characterization Workplan\SamplingLocation CFR_All.mxd; NBarNahoum; 10/15/2020October 2020
Notes:1. Sediment and surface water samples were collected in May and June 2020. Locations shown are approximate.2. Sample IDs shown here are abbreviations (e.g. RM-20-A indicates Cape Fear River Mile 20, location A). See Report for full sample IDs.3. The depth at which surface water samples were collected (in feet below water surface) is indicated at the end of the location ID (e.g. RM-77-B-10 was collected 10 feet below the water surface).4. City of Fayetteville drinking water intake location is provided by EPA STOrage and RETrieval (STORET) Data Warehouse. Harnett County drinking water intake location is based on information in Harnett Regional Water's Water Quality Report 2018.5. Basemap source provided by ESRI OpenStreetMap contributors, and the GIS User Community.
Legend
!(Sediment Sample
"Surface Water Sample
#*USGS Stream Gauge
XW Drinking Water Intake (Approximate)
Cape Fear River
³
8 0 84 Miles
400 0 400200 Feet
\\projectsitesb.geosyntec.com@SSL\DavWWWRoot\5\FWConsentOrder\Shared Documents\11.2 - Sediment Characterization\4.0 Deliverables\20201016 FINAL Report\Figures\FiguCape Fear River Flow and Precipitation
at Lillington, Lock and Dam #3 and Lock and Dam #1
Chemours Fayetteville Works, North Carolina
Figure
4RaleighOctober 2020
0
10,000
20,000
30,000
Average Daily Flow (cfs)Lillington
0
1
2
3
4
05,00010,00015,00020,00025,00030,000
Average Daily Precipitation (inches)Average Daily Flow (cfs)Lock and Dam #1
Notes:1. cfs-cubic feets per second2. Figures represent average daily flow and average daily precipitation values. obtainedfrom United States Geological Survey station numbers 2102500 (Lillington), 2105500(Lock & Dam #3), and 2105769 (Lock & Dam #1).3. Lock and Dam #3 is also called W.O. Huske Dam.4. Highlighted dates indicates when sampling activities occurred near the gauge.
00.511.522.53
05,00010,00015,00020,00025,00030,000
Average Daily Precipitation (inches)Average Daily Flow (cfs)Lock and Dam #3RM-20RM-52RM-76RM-77RM-84RM-132RM-100RM-116RM-149
PFAS Compounds Detected in Sediment above
Reporting Limits
The Chemours Company, FC, LLC.
Figure
5RaleighOctober 2020
Notes:1. µg/kg-micrograms per kilogram2. "RM-20" notation represents Cape Fear River Mile 20.3. Bars represent the maximum concentrations of analytes detected above reporting limitsfrom samples collected along a transect at each river mile location (i.e. the individual samplewith the highest concentrations for a PFAS grouping in a transect is plotted here).4. Date of sample collection is indicated underneath location labels.5. The Site is located approximately between River Miles 76 and 77.6. Samples with concentrations not detected above the reporting limit are not shown.
0
5
10
15
20
25
30
35
40
RM-20 RM-52 RM-76 RM-77 RM-84 RM-100 RM-116 RM-132 RM-149Maximum Concentration (µg/kg)537 Modified Table 3+ (20)Table 3+ (17)
Direction of River Flow
05/18/20 06/09/20 06/10/20 06/29/20 06/11/20 06/30/20
Site
PFAS Analytes Detected in
Surface Water above Reporting Limits
The Chemours Company, FC, LLC.
Figure
6aRaleighOctober 2020
Notes:1. ng/L:nanograms per liter2. "RM-20" notation represents Cape Fear River Mile 20.3.Bars represent the maximum concentrations of analytes detected above reporting limits
from samples collected along a transect at each river mile location.4. Date of sample collection is indicated underneath location labels.5. The Site is located approximately between River Miles 76 and 77.6. Samples with concentrations not detected above the reporting limit are not shown.
***
0
20
40
60
80
100
120
140
160
RM-20 RM-52 RM-76 RM-77 RM-84 RM-100 RM-116 RM-132 RM-149Method 537M Concentrations (ng/L)Perfluorobutane Sulfonic Acid
Perfluorobutanoic Acid
Perfluoroheptanoic Acid
Perfluorohexane Sulfonic Acid
Perfluorohexanoic Acid
Perfluoropentanoic Acid
PFOA
PFOS
0
20
40
60
80
100
120
140
160
RM-20 RM-52 RM-76 RM-77 RM-84 RM-100 RM-116 RM-132 RM-149Table 3+ Concentrations (ng/L)PMPA
R-PSDA
NVHOS
PFMOAA
HFPO Dimer Acid
PFO2HxA
PFO3OA
PFO4DA
PEPA
Hydrolyzed PSDA
Direction of River Flow
05/18/20 06/29/2006/09/20 06/10/20 06/11/20 06/30/20
Table 3+ compounds
observed upstream of Site
Table 3+ compounds
only observed downstream of Site
Site
PFAS Mass Discharge for Analytes Detected in
Surface Water above Reporting Limits
The Chemours Company, FC, LLC.
Figure
6bRaleighOctober 2020
Notes:1. mg/s: milligrams per second2. "RM-20" notation represents Cape Fear River Mile 20.3. Bars represent the maximum concentrations of analytes detected above reporting limitsfrom samples collected along a transect at each river mile location4. Date of sample collection is indicated underneath location labels.5. The Site is located approximately between River Miles 76 and 77.6. Samples with concentrations not detected above the reporting limit are not shown.
Direction of River Flow
0
2
4
6
8
10
12
14
16
RM-20 RM-52 RM-76 RM-77 RM-84 RM-100 RM-116 RM-132 RM-149Table 3+ Mass Discharge (mg/s) PMPA
R-PSDA
NVHOS
PFMOAA
HFPO Dimer Acid
PFO2HxA
PFO3OA
PFO4DA
PEPA
Hydrolyzed PSDA
Table 3+ compounds observed upstream of Site
Table 3+ compounds only observed downstream of Site
Site
Sediment Grain Size Distribution
The Chemours Company, FC, LLC.
Figure
7aRaleighOctober 2020
Direction of River Flow
Notes:1. Naming convention follows format River Mile, Sample Location, eg, "RM-20-Mid"notation represents Cape Fear River Mile 20, middle channel sample.2. "Banks" -Represents an average of the results from samples collectedalong the riverbanks.3. The Site is located approximately between River Miles 76 and 77.
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%PercentageClay
Silt
Sand
Gravel
Mid-channel Samples Bank Samples
Site Site
Correlation between TOC, Clay, and Silt in
Bank and Mid-channel Samples
The Chemours Company, FC, LLC.
Figure
7bRaleighOctober 2020
Notes:1. g/kg -grams per kilogram2. % indicates percentage3. TOC -Total Organic Carbon4. Clay and Silt composition indicates total percent of sample comprisedof clay+silt fractions.
0
5
10
15
20
25
30
35
0 10 20 30 40 50 60 70 80 90 100Total Organic Carbon Concentrations (g/kg)Clay & Silt Composition (%)
Bank Samples Mid-channel Samples
Sediment Grain Size and TOC Data
The Chemours Company, FC, LLC.
Figure
7cRaleighOctober 2020
0
5
10
15
20
25
30
35
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%Total Organic Carbon Concentrations (g/kg)PercentageGravel Sand Silt Clay Total Organic Carbon
Direction of River Flow
Notes:1. g/kg-grams per kilogram2. TOC -Total Organic Carbon3. Naming convention follows format River Mile, Sample Location, eg, "RM-20-Mid"notation represents Cape Fear River Mile 20, middle channel sample.4. Bars are separated by middle channel samples and the maximum TOC and PFASconcentrations between samples collected from the banks of a transect.5. The Site is located approximately between River Miles 76 and 77.6. Samples with concentrations not detected above the reporting limit are not shown.
Mid-channel Samples Bank Samples
Site Site
Sediment Grain Size and PFAS Data
The Chemours Company, FC, LLC.
Figure
7dRaleighOctober 2020
0
5
10
15
20
25
30
35
40
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%PFAS Concentrations (µg/kg)PercentageGravel Sand Silt Clay Total Table 3+Total 537
Direction of River Flow
Notes:1. µg/kg-micrograms per kilogram2. Naming convention follows format River Mile, Sample Location, eg, "RM-20-Mid"notation represents Cape Fear River Mile 20, middle channel sample.3. Bars are separated by middle channel samples and the maximum PFAS concentrationsbetween samples collected from the banks of a transect.4. The Site is located approximately between River Miles 76 and 77.5. Non-detect values are assigned a value of zero for the summation of Table 3+ and 537Mdata. Where all compounds were not detected above reporting limits in a sample, resultsare plotted as zero with open symbols. See tables for reporting limits.
Mid-channel Samples Bank Samples
Site Site
Sediment Grain Size, TOC, and PFAS Data
The Chemours Company, FC, LLC.
Figure
7eRaleighOctober 2020
0
5
10
15
20
25
30
35
0%
10%
20%
30%
40%
50%
60%
70%
80%
90%
100%Total Organic Carbon Concentrations (g/kg)PFAS Concentrations (µg/kg)PercentageGravel Sand Silt Clay Total Table 3+Total 537 Total Organic Carbon
Direction of River Flow
Notes:1. g/kg -grams per kilogram2. µg/kg -micrograms per kilogram3. TOC -Total Organic Carbon4. Naming convention follows format River Mile, Sample Location, eg, "RM-20-Mid"notation represents Cape Fear River Mile 20, middle channel sample.5. Bars are separated by middle channel samples and the maximum TOC and PFAS
concentrations between samples collected from the banks of a transect.6. The Site is located approximately between River Miles 76 and 77.7. Non-detect values are assigned a value of zero for the summation of Table 3+ and 537Mdata. Where all compounds were not detected above reporting limits in a sample, results
are plotted as zero with open symbols. See tables for reporting limits.
Mid-channel Samples Bank Samples
Site Site
Raleigh October 2020
Figure
8
River Mixing Profiles and HFPO-DA Plots
The Chemours Company, FC, LLC.
Direction of River Flow
0
100
200
300
66 68 70 72 74 76 78 80 82 84HFPO-DA Concentration (ng/L)Cape Fear River Miles
0
100
200
300
66 68 70 72 74 76 78 80 82 84HFPO-DA Concentration (ng/L)West
Center Top
Center Middle
East
Non-Detect
Site River Boundary
W.O. Huske Dam
Old Outfall 002
Bladen Bluffs
CFR-TARHEEL
West(Site side)East
West EastCenterTop
CenterMiddle
Detailed river sampling locationsNotes:
1. cfs -cubic feet per second
2.ng/L -Nanograms per liter
3. HFPO-DA -Hexafluoropropylene
Oxide Dimer Acid
4. Non-detects were assigned a
value of zero for plotting purposes.
September 2017
River Flow: 787-859 cfs
May 2018
River Flow: 2060-3090 cfs Bladen BluffsBladen BluffsCFR-TARHEELCFR-TARHEELOld Outfall002Old Outfall002
River Mixing Profiles and PFAS Plots
The Chemours Company, FC, LLC.
Figure
9RaleighOctober 2020
Notes:
1. cfs -cubic feet per second
2. ng/L -nanograms per liter
0
100
200
300
66 68 70 72 74 76 78 80 82 84September 2017 Total 537M PFAS Concentrations (ng/L)West
Center Top
Center Middle
East
Site River Boundary
W.O. Huske Dam
Old Outfall 002
Bladen Bluffs
CFR-TARHEEL
September 2017
River Flow: 787-859 cfs
0
100
200
300
66 68 70 72 74 76 78 80 82 84May 2018 Total 537M PFAS Concentrations (ng/L)Cape Fear River Miles Bladen BluffsCFR-TARHEELOld Outfall002Bladen BluffsCFR-TARHEELOld Outfall002May 2018
River Flow: 2060-3090 cfs
West(Site side)East
West EastCenterTop
CenterMiddle
Detailed river sampling locations

APPENDIX A

Field Forms

Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
6.70 FAY-SW-RM20-B-6.7-
051820 05-18-2020 17:45 7.61 8.86 83.40 3.14 25.74 Clear No
12.00 FAY-SW-RM20-B-12-
051820 05-18-2020 18:00 8.05 9.23 74.60 3.22 24.35 Clear No
Sampling Data
Method:
Pres.
NP
NP
NP
73.00
Cloudy
None
5
Insitu AquaTroll
Marsh
McBirney
13
0.06 3
0.22 9
PFAS 250 mL poly
BottleParameter
2-250 mL poly
05-18-2020
Latitude: 35.3980941346322
-78.7734335538273
Table 3
Table 3+
0.00
Longitude:
Spec.
Cond.
mS/cm
0.110
GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3 (Special); Table 3+(20)
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
CHARLES PACE, Tracy Ovbey
CFR_RM-20
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
Velocity Meter ID:
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
1.60 FAY-SW-RM52-B-1.6-
051820 05-18-2020 13:45 7.33 7.39 29.50 5.10 24.14 Clear No DUP;MS;REP
0.00 FAY-SW-RM52-B-0-
051820 05-18-2020 13:28
Sampling Data
Method:
Pres.
NP
NP
NP
75.00
Cloudy
None
8
Insitu AquaTroll
Marsh
McBirney
3
0.74 1.6
0.71 2.2
PFAS 250 mL poly
BottleParameter
2-250 mL poly
05-18-2020
fps
Latitude: 35.1075280373297
-78.8563264932504
Table 3
Table 3+
0.11
Longitude:
Spec.
Cond.
mS/cm
RM52 sample location, please note for reference the power lines GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3 (Special); Table 3+(20)
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
CHARLES PACE, Ken Stuart Tracy Ovbey
CFR-RM-52
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
To shallow for bottom sample just
took mid. Call Matt V to confirm.
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
Velocity Meter
ID:
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
13.00 FAY-SW-RM76-B-13-
060920 06-09-2020 12:30 7.10 6.75 32.20 33.29 26.66 Light brown None
21.00 FAY-SW-RM76-B-21-
060920 06-09-2020 12:00 6.90 6.65 50.00 48.80 27.05 Light brown No MS; Rep
Sampling Data
Method:
Pres.
NP
NP
NP
86.00
Sunny
None
2
Insitu AquaTroll
Marsh
McBirney
24
1.62 5
1.42 19
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: FH950.1
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate: 0.25
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
LUKE TART, Curt Burdorf Tracy Ovbey
CFR-RM-76
Project Manager: Sediment Characterization
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
06-09-2020
liters per minute
Latitude: 34.85167
078.82667
Table 3
Table 3+
0.10
Longitude:
Spec.
Cond.
mS/cm
0.160
PFAS 250 mL poly
BottleParameter
2-250 mL poly
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
10.00 FAY-SW-RM77-B-10-
060920 06-09-2020 15:45 6.55 6.90 69.70 31.31 26.31 Light brown No
18.00 FAY-SW-RM77-B-18-
060920 06-09-2020 15:45 6.36 6.92 78.50 58.34 25.74 Light Brown No
Sampling Data
Method:
Pres.
NP
NP
NP
80.00
Sunny
None
3
Insitu AquaTroll
Marsh
McBirney
20
1.77 4
1.53 16
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: FH950.1
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate: 0.25
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
LUKE TART, Curt Burdorf Tracy Ovbey
CFR-RM-77
Project Manager: Sediment Characterization
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
06-09-2020
liters per minute
Latitude: 34.91861
78.92694
Table 3
Table 3+
0.10
Longitude:
Spec.
Cond.
mS/cm
0.100
PFAS 250 mL poly
BottleParameter
2-250 mL poly
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
10.00 FAY-SW-RM84-B-10-
061020 06-10-2020 14:00 7.03 6.85 30.70 18.55 27.62 Light Brown No MS; REP
18.00 FAY-SW-RM84-B-18-
061020 06-10-2020 14:00 7.04 6.86 22.70 18.37 26.68 Light Brown No
Sampling Data
Method:
Pres.
NP
NP
NP
90.00
Sunny
None
3
Insitu AquaTroll
Marsh
McBirney
20
1.75 4
1.55 16
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: FH950.1
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:0.25
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
LUKE TART, Curt Burdorf Tracy Ovbey
CFR-RM-84
Project Manager: Sediment Characterization
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
06-10-2020
liters per minute
Latitude: 034.85972
079.02833
Table 3
Table 3+
0.09
Longitude:
Spec.
Cond.
mS/cm
0.090
PFAS 250 mL poly
BottleParameter
2-250 mL poly
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
9.50 FAY-SW-RM100-B-9.5-
062920 06-29-2020 09:15 6.23 6.27 132.80 16.24 26.28 Murky No MS; Rep
17.00 FAY-SW-RM100-B-17-
062920 06-29-2020 09:15 7.12 7.66 38.40 18.77 26.64 Murky No
Sampling Data
Method:
Pres.
NP
NP
NP
89.00
Sunny
None
Insitu AquaTroll
Marsh
McBirney
19
1.2 4
0.84 15
PFAS 250 mL poly
BottleParameter
2-250 mL poly
06-29-2020
Latitude: 34.6279470592119
-78.5621349783768
Table 3
Table 3+
0.09
Longitude:
Spec.
Cond.
mS/cm
0.090
River Left GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3 (Special); Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
CHARLES PACE, Luke Tart Tracy Ovbey
CFR-RM-100
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: 045626
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
7.50 FAY-SW-RM116-B-7.5-
062920 06-29-2020 13:30 6.48 5.63 116.30 16.30 29.38 Murky No
13.00 FAY-SW-RM116-B-13-
062920 06-29-2020 13:30 6.44 5.70 125.10 16.35 27.58 Murky No
Sampling Data
Method:
Pres.
NP
NP
NP
89.00
Sunny
Rain
Insitu AquaTroll
Marsh
McBirney
15
1.24 3
0.94 12
PFAS 250 mL poly
BottleParameter
2-250 mL poly
06-29-2020
Latitude: 34.5343908369782
-78.439541046458
Table 3
Table 3+
0.08
Longitude:
Spec.
Cond.
mS/cm
0.080
River Right GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3 (Special); Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
CHARLES PACE, Luke Tart Tracy Ovbey
CFR-RM-116
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: 045626
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
6.00 FAY-SW-RM132-B-6-
061120 06-11-2020 09:45 6.42 5.25 100.10 21.19 26.44 Light brown No MS; Rep
10.00 FAY-SW-RM132-B-10-
061120 06-11-2020 09:45 6.52 5.30 122.60 20.60 26.02 Light brown No
Sampling Data
Method:
Pres.
NP
NP
NP
75.00
Cloudy
None
8
Insitu AquaTroll
Marsh
McBirney
12
1.43 2.5
1.32 9.5
PFAS 250 mL poly
BottleParameter
2-250 mL poly
06-11-2020
liters per minute
Latitude: 034.50778
078.47278
Table 3
Table 3+
0.10
Longitude:
Spec.
Cond.
mS/cm
0.100
GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
LUKE TART, Curt Burdorf Tracy Ovbey
CFR-RM-132
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: Boat
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706720
Velocity Meter ID: FH950.1
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate: 0.25
Site Name:Location ID:
Samplers:Event:
Date:
Spl Depth Spl ID Spl Date Time pH DO Redox Turbidity
Temp.Color Odor Dup
mg/L mV NTU
oC
1.50 FAY-SW-RM149-B-1.5-
063020 06-30-2020 09:30 6.47 5.05 24.00 8.89 27.43 Murky No MS; Rep
Sampling Data
Method:
Pres.
NP
NP
NP
80.00
Sunny
None
Insitu AquaTroll
Marsh
McBirney
2
0.45 1
0.34 2.45
PFAS 250 mL poly
BottleParameter
2-250 mL poly
06-30-2020
Latitude: 34.3520564617334
-78.084179403603
Table 3
Table 3+
0.07
Longitude:
Spec.
Cond.
mS/cm
River Right GPS Location (if collected)
Wind (mph)
Precipitation:
Multi Meter Used:
Velocity Meter Used:
Multi Meter ID:
EPA 537 Modified
Comments
Peri Pump Grab
WEATHER CONDITIONS
Method
SAMPLE SET ALL PARAMETERS ANALYZED
EPA 537 Modified; Table 3 (Special); Table 3+(20); TSS; TOC; DOC
250 mL poly
PFAS
PFAS
SURFACE WATER/SEEP SAMPLING RECORD
Chemours Fayetteville
CHARLES PACE, Luke Tart Tracy Ovbey
CFR-RM-149
Project Manager: Sediment Characterization
Stream Depth TOP half of water column (ft):
Stream Depth BOTTOM half of water column (ft):
Samples taken from: 0
No bottom sample, too shallow
Stream Velocity TOP half of water column (ft/sec):
Stream Velocity BOTTOM half of water column (ft/sec):
706682
Velocity Meter ID: 045626
Total Water Depth (ft):
Temperature (F):
Sky:
Flow Rate:

APPENDIX B

Laboratory White Books and Reports

APPENDIX B: DATA REVIEW NARRATIVES AND
LABORATORY REPORTS

Data review narratives are included in this appendix. Due to file size limits, analytical laboratory
reports could be provided separately upon request.

ADQM Data Review Narrative - FAY Sed Char Sampling update2.doc 1 of 3
ADQM DATA REVIEW
NARRATIVE

Site Chemours FAY – Fayetteville

Project Sediment Characterization Sampling (update 2)

Project Reviewer Michael Aucoin, AECOM as a Chemours contractor

Sampling Dates May 18, 2020
June 9 - 11, 2020
June 29 – 30, 2020

Analytical Protocol

Laboratory Analytical Method Parameter(s)
TestAmerica - Sacramento 537 Modified PFAS1
TestAmerica - Sacramento Cl. Spec. Table 3
Compound SOP
Table 3+ compounds
TestAmerica - Burlington ASTM D422-63 Grain Size
TestAmerica - Burlington LLOYD KAHN Total Organic Carbon
TestAmerica - Denver 9060A Total Organic Carbon
TestAmerica - Denver 9060A Dissolved Organic Carbon
TestAmerica - Denver 2540 D-1997 Total Suspended Solids
TestAmerica - Sacramento ASTM D2216-90 Percent Moisture
TestAmerica - Sacramento ASTM D2216-90 Percent Solids

1 Perfluoroalkylsubstances, a list of 36 compounds including HFPO-DA.

Sample Receipt

The following items are noted for this data set:

• All samples were received in satisfactory condition and within EPA temperature guidelines on:

May 21 - 22, 2020
June 11 - 13, 2020
July 2, 2020

Data Review

The electronic data submitted for this project was reviewed via the Data Verification Module (DVM)
process.

Overall the data is acceptable for use without qualification, except as noted below:
ADQM Data Review Narrative - FAY Sed Char Sampling update2.doc 2 of 3

• The laboratory reported HFPO-DA from both the 537 Modified and Table 3+ analysis for each
sample. The best value field was populated to report the “better” result for each sample
according to the following criteria:
o The higher concentration of two detects was reported.
o The detected value was reported when a detect and a non-detect result were evaluated.
o The lower reporting limit was reported when two non-detect results were evaluated.
• The R-EVE result for sample FAY-SED-RM149-C-063020-D (320-62363-8) was revised by the
laboratory to show a non-detect result as the original result was a false positive. A revised lab
report was received from the laboratory.
• Professional judgement was used to overwrite R qualifiers, indicating an unusable result, that
were assigned by the DVM due to a very poor surrogate (isotope dilution analyte or IDA)
recovery, and preparation or analysis hold time that was exceeded by more than two times. The
qualifier was updated to UJ, indicating an estimated reporting limit, because the target
compounds are generally recognized to be stable for an extended time period. In the case of the
IDA recovery, data quality is not considered affected by the laboratory if the IDA signal-to-noise
ratio is greater than 10:1, which was achieved for all IDA in the samples.
• Results for HFPO-DA in one water sample and TSS in three water samples were qualified B and
the reported results may be biased high, or false positives, due to comparable concentrations
found in associated equipment rinsate or laboratory method blanks.
• The laboratory applied an I qualifier to indicate where the transition mass ratio for the indicated
analyte was outside of the established ratio limit. The qualitative identification of the analyte has
some degree of uncertainty. However, analyst judgement was used to positively identify the
analyte and the reviewer applied a J validation qualifier, indicating that the associated result
should be considered to be an EMPC (estimated maximum possible concentration).
• Due to uncertainty from observed matrix effects during the analysis of R-PSDA, Hydrolyzed
PSDA and R-EVE, a J-qualifier has been added to all positive results in the data set, if not already
qualified by the DVM and even if there was no matrix spike analyzed for that particular sample,
and the results should be considered to be estimated values.
• Analytical results have been qualified J as estimated, and non-detect results qualified UJ
indicating an estimated reporting limit, due to a poor surrogate or matrix spike recovery; sample
preparation or analysis which exceeded the laboratory established hold time; and poor field
duplicate or lab replicate precision. See the Data Verification Module (DVM) Narrative Report
for which samples were qualified, the specific reasons for qualification, and potential bias in
reported results.
• The non-PFAS results for samples were reported by the laboratory to the method detection limit
(MDL); results reported between the MDL and the practical quantitation limit (PQL) are qualified
J and are considered to be estimated values.

Attachments

The DVM Narrative report is attached. The lab reports due to a large page count are stored on an
AECOM network shared drive and are available to be posted on external shared drives, or on a flash
drive.
ADQM Data Review Narrative - FAY Sed Char Sampling update2.doc 3 of 3
Data Verification Module (DVM)

The DVM is an internal review process used by the ADQM group to assist with the determination of data
usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™
database and processed through a series of data quality checks, which are a combination of software
(Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is
evaluated against the following data usability checks:
• Field and laboratory blank contamination
• US EPA hold time criteria
• Missing Quality Control (QC) samples
• Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences
(RPDs) between these spikes
• Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD
between these spikes
• Surrogate spike recoveries for organic analyses
• RPD between field duplicate sample pairs
• RPD between laboratory replicates for inorganic analyses
• Difference / percent difference between total and dissolved sample pairs.

There are two qualifier fields in EIM:
Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This
qualifier may have many different meanings and can vary between labs and over time within the same
lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab
descriptors they are not to be used when evaluating the data.

Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this
field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses
the usability of the data and may not equal the lab qualifier. The DVM applies the following data
evaluation qualifiers to analysis results, as warranted:

Qualifier Definition
B Not detected substantially above the level reported in the laboratory
or field blanks.
R Unusable result. Analyte may or may not be present in the sample.
J Analyte present. Reported value may not be accurate or precise.
UJ Not detected. Reporting limit may not be accurate or precise.

The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM
has not been run, the field will be blank.

If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier.

DVM Narrative ReportContamination detected in equipment blank(s). Sample result does not differ significantly from the analyte concentration detected in the associatedequipment blank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM100-B-17-06292006/29/2020280-138238-2Total SuspendedSolids13MG/L1.12540 D-1997B4.0MDLFAY-SW-RM116-B-7.5-06292006/29/2020280-138238-4Total SuspendedSolids9.2MG/L1.12540 D-1997B4.0MDLFAY-SW-RM84-B-18-06102006/09/2020320-61742-5Hfpo Dimer Acid0.0097UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.0020PQLPage 1 of 56
Contamination detected in Method Blank(s). Sample result does not differ significantly from the analyte concentration detected in the associated methodblank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM149-B-1.5-06302006/30/2020280-138238-5Total SuspendedSolids3.6MG/L1.12540 D-1997B4.0MDLPage 2 of 56
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Nondetects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM116-B-13-06292006/29/2020320-62360-3Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM116-B-13-06292006/29/2020320-62360-3Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM100-B-17-06292006/29/2020320-62360-2Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM100-B-17-06292006/29/2020320-62360-2Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM116-B-7.5-06292006/29/2020320-62360-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM116-B-7.5-06292006/29/2020320-62360-4Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM84-B-18-06102006/09/2020320-61742-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SED-RM149-A-06302006/30/2020320-62363-11N-methyl perfluoro-1-octanesulfonamide0.54UG/KG537 ModifiedUJShake_Bath_14D0.54PQLFAY-SED-RM149-A-06302006/30/2020320-62363-11N-ethylperfluoro-1-octanesulfonamide0.32UG/KG537 ModifiedUJShake_Bath_14D0.32PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6N-methyl perfluoro-1-octanesulfonamide0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6N-ethylperfluoro-1-octanesulfonamide0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLPage 3 of 56
The analysis hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-FBLK-6-06302006/30/2020280-138238-7Total SuspendedSolids1.1MG/L1.12540 D-1997UJ4.0MDLPage 4 of 56
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM76-B-21-06092006/09/2020320-61697-4PFMOAA0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLFAY-SW-RM76-B-21-06092006/09/2020320-61697-4PFMOAA0.0020ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Perfluoropentanesulfonic acid (PFPeS)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 5 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM77-B-10-06092006/09/2020320-61745-510:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5N-methylperfluorooctanesulfonamidoacetic acid0.020UG/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-56:2 Fluorotelomersulfonate0.020ug/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5N-ethylperfluorooctanesulfonamidoacetic acid0.020UG/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-51H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.020ug/L537 ModifiedUJ3535_PFC0.020PQLPage 6 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM77-B-10-06092006/09/2020320-61745-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-59Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-51H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.020ug/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-511Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-410:2 Fluorotelomersulfonate0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Hfpo Dimer Acid0.0040UG/L537 ModifiedUJ3535_PFC0.0040PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluorooctadecanoicacid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM84-B-18-06102006/09/2020320-61742-5N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFBLK-2-06092006/09/2020320-61742-7N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLTBLK-2-06092006/09/2020320-61742-9N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4NEtPFOSA (trial)0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluoroheptanesulfonic acid (PFHpS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorononanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorotetradecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 7 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM77-B-18-06092006/09/2020320-61745-41H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)0.020ug/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluorohexadecanoicacid (PFHxDA)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluorononanesulfonic acid0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorotridecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorooctaneSulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-49Cl-PF3ONS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-41H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)0.020ug/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-411Cl-PF3OUdS0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluorododecanesulfonic acid (PFDoS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4DONA0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluoroundecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4N-methylperfluorooctanesulfonamidoacetic acid0.020UG/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.0040ug/L537 ModifiedUJ3535_PFC0.0040PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluoropentanesulfonic acid (PFPeS)0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-46:2 Fluorotelomersulfonate0.020ug/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4N-ethylperfluorooctanesulfonamidoacetic acid0.020UG/L537 ModifiedUJ3535_PFC0.020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorodecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorodecaneSulfonic Acid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLPage 8 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorododecanoicAcid0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4N-methyl perfluoro-1-octanesulfonamide0.0020ug/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLEQBLK-2-06092006/09/2020320-61742-8N-ethylperfluoro-1-octanesulfonamide0.0020UG/L537 ModifiedUJ3535_PFC0.0020PQLFAY-SED-RM100-C-06292006/29/2020320-62363-110:2 Fluorotelomersulfonate0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Hfpo Dimer Acid0.25UG/KG537 ModifiedUJShake_Bath_14D0.25PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorooctadecanoicacid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoropentanoicAcid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluoropentanesulfonic acid (PFPeS)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-16:2 Fluorotelomersulfonate2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-ethylperfluorooctanesulfonamidoacetic acid2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorohexanoicAcid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorobutaneSulfonic Acid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoroheptanoicAcid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluoroheptanesulfonic acid (PFHpS)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorononanoicAcid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorotetradecanoicAcid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-11H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-ethylperfluoro-1-octanesulfonamide0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorohexadecanoicacid (PFHxDA)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorononanesulfonic acid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLPage 9 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorooctaneSulfonamide0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-19Cl-PF3ONS0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-11H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-111Cl-PF3OUdS0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorododecanesulfonic acid (PFDoS)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1DONA0.2ng/g537 ModifiedUJShake_Bath_14D0.2PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-methylperfluorooctanesulfonamidoacetic acid2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-methyl perfluoro-1-octanesulfonamide0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFOA0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorodecaneSulfonic Acid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorohexaneSulfonic Acid0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFOA(trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorobutaneSulfonic Acid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorohexaneSulfonic Acid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorooctaneSulfonamide (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Hfpo Dimer Acid (trial)0.25UG/KG537 ModifiedUJShake_Bath_14D0.25PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-ethylperfluorooctanesulfonamidoacetic acid(TRIAL)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1N-methylperfluorooctanesulfonamidoacetic acid(TRIAL)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorotetradecanoicacid (TRIAL)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLPage 10 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM100-C-06292006/29/2020320-62363-1NMePFOSAE (trial)1.3UG/KG537 ModifiedUJShake_Bath_14D1.3PQLFAY-SED-RM100-C-06292006/29/2020320-62363-16:2 FTS (trial)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1DONA (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1F-53B Major (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1F-53B Minor (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1NEtPFOSA (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1NMePFOSA (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFDS (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFDoS (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFHpS (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFHxDA (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorononanesulfonic acid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorooctadecanoicacid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFPeS (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoropentanoicAcid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorohexanoicAcid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoroheptanoicAcid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorononanoicAcid (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-110:2 FTS (trial)0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-18:2 FTS (trial)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM100-C-06292006/29/2020320-62363-14:2 FTS (trial)2.0UG/KG537 ModifiedUJShake_Bath_14D2.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 11 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM132-A-06112006/11/2020320-61777-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 12 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM132-A-06112006/11/2020320-61777-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 13 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM132-B-06112006/11/2020320-61777-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-B-06112006/11/2020320-61777-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 14 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM132-C-06112006/11/2020320-61777-4R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-C-06112006/11/2020320-61777-4PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 15 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM132-A-06112006/11/2020320-61777-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFOS0.50UG/KG537 ModifiedUJShake_Bath_14D0.50PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFOS (trial)0.50UG/KG537 ModifiedUJShake_Bath_14D0.50PQLFAY-SED-RM52-B-05182005/18/2020320-61072-52-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM52-B-05182005/18/2020320-61072-52-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM52-C-05182005/18/2020320-61072-62-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM52-C-05182005/18/2020320-61072-62-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.20UG/KG537 ModifiedUJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 16 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-A-06092006/09/2020320-61697-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 17 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 18 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-B-06092006/09/2020320-61697-2NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 19 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-B-06092006/09/2020320-61697-2Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-B-06092006/09/2020320-61697-2PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 20 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-C-06092006/09/2020320-61697-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 21 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-B-06102006/10/2020320-61745-2NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 22 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-B-06102006/10/2020320-61745-2Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 23 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-C-06102006/10/2020320-61745-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 24 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM84-A-06102006/10/2020320-61742-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 25 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM84-B-06102006/10/2020320-61742-2PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 26 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 27 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-C-06102006/10/2020320-61745-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 28 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM84-C-06102006/10/2020320-61742-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 29 of 56
The preparation hold time for this sample was exceeded. The reporting limit may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 30 of 56
One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reported result isconsidered to be anestimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM149-C-063020-D06/30/2020320-62363-82-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.27UG/KG537 ModifiedUJShake_Bath_14D0.27PQLPage 31 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM20-A-05182005/18/2020320-61076-3NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 32 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM20-A-05182005/18/2020320-61076-3Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 33 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM20-B-05182005/18/2020320-61076-2EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 34 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM20-C-05182005/18/2020320-61076-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLPage 35 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 36 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-A-05182005/18/2020320-61072-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 37 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 38 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-B-05182005/18/2020320-61072-5PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6NVHOS1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PES1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PMPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFECA B1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLPage 39 of 56
The preparation hold time for this sample was exceeded by a factor of 2. The reported non-detect result is considered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-C-05182005/18/2020320-61072-6R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PEPA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFO2HxA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFO3OA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFO4DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFO5DA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFMOAA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6Hydro-PS Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6Hydro-EVE Acid1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6PFECA-G1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4R-PSDA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4Hydrolyzed PSDA2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4R-PSDCA1.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D1.0PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4R-EVE2.0UG/KGCl. Spec. Table 3Compound SOPUJShake_Bath_14D2.0PQLPage 40 of 56
Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluoroundecanoicAcid0.58UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorononanoicAcid0.22UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM149-C-06302006/30/2020320-62363-7PerfluoroundecanoicAcid0.31UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Hydrolyzed PSDA0.0080UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Hydrolyzed PSDA0.0075UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5Hydrolyzed PSDA0.0027UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5Hydrolyzed PSDA0.0027UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1R-PSDA0.0037UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1R-PSDA0.0033UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1Hydrolyzed PSDA0.0096UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1Hydrolyzed PSDA0.0092UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5R-PSDA0.0048UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5R-PSDA0.0040UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5Hydrolyzed PSDA0.0045UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5Hydrolyzed PSDA0.0043UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM52-B-1.6-05182005/18/2020320-61072-2R-PSDA0.019UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM52-B-1.6-05182005/18/2020320-61072-2R-PSDA0.017UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 41 of 56
High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-A-051820-D05/18/2020200-53737-2Silt6.7%ASTM D422-63J0MDLFAY-SED-RM52-A-051820-D05/18/2020200-53737-2Coarse Sand0.3%ASTM D422-63J0MDLFAY-SED-RM52-A-05182005/18/2020200-53737-1Silt12.3%ASTM D422-63J0MDLFAY-SED-RM52-A-05182005/18/2020200-53737-1Coarse Sand0.7%ASTM D422-63J0MDLPage 42 of 56
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorooctaneSulfonamide0.52UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorotridecanoicAcid0.21UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFOS (trial)1.6UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Perfluorobutanoic Acid(trial)0.54UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorodecanoicAcid (trial)0.23UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluoroundecanoicAcid (trial)0.90UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorododecanoicAcid (trial)0.69UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorooctaneSulfonamide (trial)0.52UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3N-methylperfluorooctanesulfonamidoacetic acid(TRIAL)5.6UG/KG537 ModifiedJShake_Bath_14D2.0PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorotridecanoicAcid (TRIAL)0.20UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3NEtPFOSAE (trial)2.2UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3NMePFOSAE (trial)1.6UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFDS (trial)0.28UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorododecanoicAcid0.62UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorodecanoicAcid0.23UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluorodecaneSulfonic Acid0.28UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Perfluorobutanoic Acid0.47UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-32-(N-methyl perfluoro-1-octanesulfonamido)-ethanol1.5UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-32-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol2.3UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3PFOS1.4UG/KG537 ModifiedJShake_Bath_14D0.50PQLPage 43 of 56
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-C-06102006/10/2020320-61745-3PerfluoroundecanoicAcid0.90UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3N-methylperfluorooctanesulfonamidoacetic acid4.6UG/KG537 ModifiedJShake_Bath_14D2.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol2.8UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFOS2.7UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFOS (trial)2.8UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFOA(trial)0.33UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Perfluorobutanoic Acid(trial)0.64UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorononanoicAcid (trial)0.21UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorodecanoicAcid (trial)0.44UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluoroundecanoicAcid (trial)0.60UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorododecanoicAcid (trial)0.62UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorohexaneSulfonic Acid (trial)0.27UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hfpo Dimer Acid (trial)2.0UG/KG537 ModifiedJShake_Bath_14D0.25PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorotridecanoicAcid (TRIAL)0.22UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1NEtPFOSAE (trial)2.9UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1NMePFOSAE (trial)0.77UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorotridecanoicAcid0.21UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorododecanoicAcid0.61UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFOA0.33UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorodecanoicAcid0.44UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PerfluorohexaneSulfonic Acid0.27UG/KG537 ModifiedJShake_Bath_14D0.20PQLPage 44 of 56
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM76-A-06092006/09/2020320-61697-1Perfluorobutanoic Acid0.64UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.77UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1Hfpo Dimer Acid2.0UG/KG537 ModifiedJShake_Bath_14D0.25PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PerfluorododecanoicAcid0.23UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Perfluorobutanoic Acid0.38UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.56UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFOS (trial)0.58UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1Perfluorobutanoic Acid(trial)0.39UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PerfluorododecanoicAcid (trial)0.23UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1NMePFOSAE (trial)0.56UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1PFOS0.59UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Hfpo Dimer Acid0.011UG/L537 ModifiedJ3535_PFC0.0040PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluoropentanoicAcid0.0095UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorohexanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFOA0.0072UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorohexaneSulfonic Acid0.0040UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Perfluorobutanoic Acid0.0064UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorobutaneSulfonic Acid0.0043UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluoroheptanoicAcid0.0061UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFOS (trial)0.014UG/L537 ModifiedJ3535_PFC0.0020PQLPage 45 of 56
Only one surrogate has relative percent recovery (RPR) values outside control limits and the parameter is a PFC (Detects).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFOA(trial)0.0070UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Perfluorobutanoic Acid(trial)0.0064UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluoropentanoicAcid (trial)0.0096UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorohexanoicAcid (trial)0.011UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluoroheptanoicAcid (trial)0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorobutaneSulfonic Acid (trial)0.0042UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PerfluorohexaneSulfonic Acid (trial)0.0041UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4Hfpo Dimer Acid (trial)0.011UG/L537 ModifiedJ3535_PFC0.0040PQLFAY-SW-RM84-B-18-06102006/09/2020320-61742-5Perfluorobutanoic Acid0.0063UG/L537 ModifiedJ3535_PFC0.0020PQLPage 46 of 56
Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM149-C-06302006/30/2020320-62363-7NEtPFOSAE (trial)3.2UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-1NEtPFOSAE (trial)1.4UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM132-A-06112006/11/2020320-61777-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol1.4UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1NEtPFOSAE (trial)15UG/KG537 ModifiedJShake_Bath_14D0.66PQLFAY-SW-RM100-B-9.5-06292006/29/2020280-138238-1Total SuspendedSolids17MG/L1.12540 D-1997J4.0MDLFAY-FBLK-5-06292006/29/2020280-138238-6Total SuspendedSolids1.2MG/L1.12540 D-1997J4.0MDLPage 47 of 56
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6Percent Moisture52.2%D2216-90J0.1PQLFAY-SED-RM84-C-061020-PT06/10/2020320-61742-6Percent Solids47.8%D2216-90J0.1PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3Percent Moisture53.5%D2216-90J0.1PQLFAY-SED-RM84-C-06102006/10/2020320-61742-3Percent Solids46.5%D2216-90J0.1PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2Percent Moisture20.7%D2216-90J0.1PQLFAY-SED-RM84-B-06102006/10/2020320-61742-2Percent Solids79.3%D2216-90J0.1PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1Percent Moisture44.4%D2216-90J0.1PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1Percent Solids55.6%D2216-90J0.1PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1Percent Moisture55.2%D2216-90J0.1PQLFAY-SED-RM84-A-06102006/10/2020320-61742-1Percent Solids44.8%D2216-90J0.1PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Percent Moisture50.9%D2216-90J0.1PQLFAY-SED-RM77-C-06102006/10/2020320-61745-3Percent Solids49.1%D2216-90J0.1PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2Percent Moisture22.8%D2216-90J0.1PQLFAY-SED-RM77-B-06102006/10/2020320-61745-2Percent Solids77.2%D2216-90J0.1PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6Percent Moisture23.1%D2216-90J0.1PQLFAY-SED-RM52-C-05182005/18/2020320-61072-6Percent Solids76.9%D2216-90J0.1PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5Percent Moisture22.0%D2216-90J0.1PQLFAY-SED-RM52-B-05182005/18/2020320-61072-5Percent Solids78.0%D2216-90J0.1PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4Percent Moisture32.7%D2216-90J0.1PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4Percent Solids67.3%D2216-90J0.1PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Percent Solids77.5%D2216-90J0.1PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1Percent Moisture22.5%D2216-90J0.1PQLFAY-SED-RM20-C-05182005/18/2020320-61076-1Percent Moisture56.1%D2216-90J0.1PQLPage 48 of 56
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM20-C-05182005/18/2020320-61076-1Percent Solids43.9%D2216-90J0.1PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2Percent Moisture21.8%D2216-90J0.1PQLFAY-SED-RM20-B-05182005/18/2020320-61076-2Percent Solids78.2%D2216-90J0.1PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3Percent Moisture33.1%D2216-90J0.1PQLFAY-SED-RM20-A-05182005/18/2020320-61076-3Percent Solids66.9%D2216-90J0.1PQLFAY-SED-RM149-C-063020-D06/30/2020320-62363-8Percent Moisture75.4%D2216-90J0.1PQLFAY-SED-RM149-C-063020-D06/30/2020320-62363-8Percent Solids24.6%D2216-90J0.1PQLFAY-SED-RM149-C-063020-PT06/30/2020320-62363-9Percent Moisture63.4%D2216-90J0.1PQLFAY-SED-RM149-C-063020-PT06/30/2020320-62363-9Percent Solids36.6%D2216-90J0.1PQLFAY-SED-RM149-A-06302006/30/2020320-62363-11Percent Moisture62.3%D2216-90J0.1PQLFAY-SED-RM149-A-06302006/30/2020320-62363-11Percent Solids37.7%D2216-90J0.1PQLFAY-SED-RM149-B-06302006/30/2020320-62363-10Percent Moisture30.6%D2216-90J0.1PQLFAY-SED-RM149-B-06302006/30/2020320-62363-10Percent Solids69.4%D2216-90J0.1PQLFAY-SED-RM149-C-06302006/30/2020320-62363-7Percent Moisture62.0%D2216-90J0.1PQLFAY-SED-RM149-C-06302006/30/2020320-62363-7Percent Solids38.0%D2216-90J0.1PQLFAY-SED-RM116-A-06292006/29/2020320-62363-6Percent Moisture32.8%D2216-90J0.1PQLFAY-SED-RM116-A-06292006/29/2020320-62363-6Percent Solids67.2%D2216-90J0.1PQLFAY-SED-RM116-B-06292006/29/2020320-62363-5Percent Moisture22.5%D2216-90J0.1PQLFAY-SED-RM116-B-06292006/29/2020320-62363-5Percent Solids77.5%D2216-90J0.1PQLFAY-SED-RM116-C-06292006/29/2020320-62363-4Percent Moisture43.2%D2216-90J0.1PQLFAY-SED-RM116-C-06292006/29/2020320-62363-4Percent Solids56.8%D2216-90J0.1PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Percent Solids53.0%D2216-90J0.1PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Percent Moisture47.0%D2216-90J0.1PQLPage 49 of 56
The analysis hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM100-A-06202006/29/2020320-62363-3Percent Moisture29.8%D2216-90J0.1PQLFAY-SED-RM100-A-06202006/29/2020320-62363-3Percent Solids70.2%D2216-90J0.1PQLFAY-SED-RM100-B-06292006/29/2020320-62363-2Percent Moisture22.1%D2216-90J0.1PQLFAY-SED-RM100-B-06292006/29/2020320-62363-2Percent Solids77.9%D2216-90J0.1PQLFAY-SW-RM116-B-13-06292006/29/2020280-138238-3Total SuspendedSolids18MG/L1.12540 D-1997J4.0MDLFAY-EQBLK-5-06292006/29/2020280-138238-8Total SuspendedSolids2.8MG/L1.12540 D-1997J4.0MDLFAY-EQBLK-6-06302006/30/2020280-138238-9Total SuspendedSolids2.4MG/L1.12540 D-1997J4.0MDLPage 50 of 56
Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFMOAA0.018ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM84-B-10-06102006/09/2020320-61742-4PFMOAA0.019ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5PFMOAA0.027ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM-149-B-1.5-06302006/30/2020320-62360-5PFMOAA0.029ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1PFMOAA0.024ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM100-B-9.5-06292006/29/2020320-62360-1PFMOAA0.024ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5PFMOAA0.017ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLFAY-SW-RM132-B-6-06112006/11/2020320-61777-5PFMOAA0.017ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 51 of 56
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM77-A-06102006/10/2020320-61745-1PFMOAA7.3UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PMPA1.1UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PS Acid1.8UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFO2HxA3.9UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PFO3OA1.6UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM77-A-06102006/10/2020320-61745-1PMPA1.3UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PFO2HxA1.8UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFO2HxA7.6UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFO3OA2.2UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFO4DA1.4UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-060920-PT06/09/2020320-61697-6PFO5DA1.4UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-C-06092006/09/2020320-61697-3PMPA1.9UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO2HxA3.3UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PFO2HxA3.1UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PMPA1.5UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLFAY-SED-RM76-A-06092006/09/2020320-61697-1PMPA1.5UG/KGCl. Spec. Table 3Compound SOPJShake_Bath_14D1.0PQLPage 52 of 56
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM52-A-051820-D05/18/2020320-61072-42-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.26UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-42-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.24UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM52-A-051820-D05/18/2020320-61072-4PFOS0.57UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1NEtPFOSAE (trial)0.25UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM52-A-05182005/18/2020320-61072-1NMePFOSAE (trial)0.25UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM52-A-05182005/18/2020320-61072-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol0.24UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM52-A-05182005/18/2020320-61072-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol0.23UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorodecanoicAcid (trial)0.27UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoroundecanoicAcid (trial)0.54UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorododecanoicAcid (trial)0.49UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorotridecanoicAcid (TRIAL)0.21UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorobutanoic Acid(trial)0.51UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1Perfluorobutanoic Acid0.52UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorodecanoicAcid0.26UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-12-(N-methyl perfluoro-1-octanesulfonamido)-ethanol2.3UG/KG537 ModifiedJShake_Bath_14D1.2PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFOS (trial)2.3UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorotridecanoicAcid0.21UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluorododecanoicAcid0.50UG/KG537 ModifiedJShake_Bath_14D0.20PQLPage 53 of 56
The preparation hold time for this sample was exceeded. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM100-C-06292006/29/2020320-62363-12-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol15UG/KG537 ModifiedJShake_Bath_14D0.63PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PFOS2.3UG/KG537 ModifiedJShake_Bath_14D0.50PQLFAY-SED-RM100-C-06292006/29/2020320-62363-1PerfluoroundecanoicAcid0.52UG/KG537 ModifiedJShake_Bath_14D0.20PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PFOA0.0081UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorohexaneSulfonic Acid0.0034UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4Perfluorobutanoic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorobutaneSulfonic Acid0.0043UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluoroheptanoicAcid0.0060UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluorohexanoicAcid0.011UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PerfluoropentanoicAcid0.0096UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-18-06092006/09/2020320-61745-4PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorohexaneSulfonic Acid0.0044UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5Perfluorobutanoic Acid0.0053UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorobutaneSulfonic Acid0.0041UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluoroheptanoicAcid0.0067UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PFOA0.0078UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluorohexanoicAcid0.013UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PerfluoropentanoicAcid0.010UG/L537 ModifiedJ3535_PFC0.0020PQLFAY-SW-RM77-B-10-06092006/09/2020320-61745-5PFOS0.014UG/L537 ModifiedJ3535_PFC0.0020PQLPage 54 of 56
One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SED-RM149-C-063020-D06/30/2020320-62363-82-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol7.0UG/KG537 ModifiedJShake_Bath_14D0.20PQLPage 55 of 56
The result is estimated since the concentration is between the method detection limit and practical quantitation limit.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:Sediment Characterization SamplingAnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResultTypeField Sample IDPrepUnitsFAY-SW-RM52-B-1.6-05182005/18/2020280-136897-1Total SuspendedSolids2.8MG/L1.12540 D-1997J4.0MDLFAY-SW-RM52-B-1.6-051820-D05/18/2020280-136897-2Total SuspendedSolids2.8MG/L1.12540 D-1997J4.0MDLEQBLK-3-061020-Z06/10/2020200-53950-19ZDissolved OrganicCarbon500UG/L3509060AJ1000MDLFAY-EQBLK-6-06302006/30/2020280-138238-9Carbon0.39MG/L0.359060AJ1.0MDLFAY-SED-RM84-B-06102006/10/2020200-53950-8Total Organic Carbon960MG/KG684LLOYD KAHNJ1000MDLPage 56 of 56