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HomeMy WebLinkAbout2020.09.30_COOA.p1_Q2_2020MassLoadAssessmentAppendicesAPPENDIX A Field Methods Appendix A 1 September 2020 APPENDIX A FIELD METHODS INTRODUCTION AND OBJECTIVES This appendix summarizes the field methods employed to conduct monitoring activities for total per- and polyfluoroalkyl substances (PFAS) mass loading to the Cape Fear River at and surrounding the Chemours Fayetteville Works, North Carolina site (the Site). The effort described herein was conducted by Geosyntec and Parsons in May 2020. The monitoring program includes collecting data on flow rates and PFAS concentrations from the PFAS transport pathways to the Cape Fear River. SCOPE OF WORK The scope of work involves four tasks: (1) collecting surface water and groundwater seep water samples for PFAS; (2) measuring flow rates at specified surface water and seep locations; (3) collecting a synoptic round of groundwater elevations from designated monitoring wells; and (4) collecting water samples for PFAS analysis from the designated monitoring wells. Field methods for each task are described below in the Methods section. Field forms collected during implementation of this scope of work are provided in Appendix D. The work was performed according to the project health and safety plan (HASP) prepared by Parsons (Parsons Health and Safety Plan Chemours Fayetteville Site, 2020). A Plan on Action Discussion (POAD) and Project Safety Analysis (PSA) was held prior to commencing field activities. The work was performed under Nationwide Permit 6 (United States Army Corps of Engineers, 2017). METHODS This section describes the field methods and procedures that were employed for collecting surface water and onsite seep samples, gauging stream flow, collection of groundwater elevations, water quality parameter assessment and sample collection. Surface Water and Onsite Seep Sample Collection Methods Surface Water and Onsite Seep Composite Sampling Methods Autosamplers were used to collect 24-hour integrated samples from various surface water bodies and onsite Seeps. The autosamplers collected sample aliquots once per hour. The sample tubing from the autosampler was positioned at minimum 2 inches above the bottom of the water body flow with the open end of the sample tubing pointed in the downstream direction to minimize the potential for sediment accumulation and uptake. Autosampler materials consisted of high-density polyethylene (HDPE) tubing, silicon tubing, and an HDPE sample reservoir. Water from the Appendix A 2 September 2020 sample reservoir was decanted into laboratory supplied bottles (e.g. 250-milliliter [mL] HDPE bottles for PFAS analysis) and then sent to an approved laboratory. Field parameters were measured twice for composite samples: once during composite sampling (collected directly from the water stream), and once after composite sampling (collected from the autosampler reservoir). The following water quality parameters were recorded: •pH; •Temperature (degrees Celsius [°C]); •Specific Conductivity (microsiemens per centimeter [µS/cm]); •Dissolved Oxygen (DO) (milligrams per liter [mg/L]); and, •Oxidation-Reduction Potential (ORP) (millivolts [mV]) Creek and Seep Water Grab Sampling Methods Where composite sample collection was not feasible due to access and other field conditions, creek and seep water samples were collected as grab samples. Laboratory-supplied 250 mL HDPE sample bottles were lowered into the flowing water of the creek to collect the sample. The bottles were lowered into the stream either using a properly decontaminated dip rod with bottle attached with a nylon zip tie, or in shallow streams, by hand. The bottle was lowered into the stream with the cap removed, open and facing oncoming flow. Where possible, the sample was collected from the middle of the stream. Care was taken to avoid collecting suspended solids or other materials in the sample. The following water quality parameters were measured after sample collection using water from the same location in the stream: •pH; •Temperature (°C); •Specific Conductivity (µS/cm); •DO (mg/L); and •ORP (mV). Cape Fear River Water Grab Sampling Methods Cape Fear River water samples were collected using a peristaltic pump and new dedicated HDPE tubing and dedicated silicone tubing for the pump head at each location. The tubing was lowered to the specified sampling depth below the water surface using an anchor weight and the tubing fastened to the anchor pointing upwards. Surface water was pumped directly from the submerged tubing through the pump head to a flow-through cell. Field parameters were monitored over a 5- minute interval, then the flow-through cell was disconnected, the tubing cut to provide a new, clean end and a grab sample was collected from the discharge of the peristaltic pump in new 250 mL laboratory-supplied HDPE bottles. The following water quality parameters were measured: •pH; •Temperature (°C); Appendix A 3 September 2020 •Specific Conductivity (µS/cm); •DO (mg/L); and •ORP (mV). Flow Gauging Methods Flow velocity was measured after sample collection at seep and creek locations specified in Table 2. Flow velocity was measured using flumes where they exist, otherwise flow velocity was measured via flow meters. Flumes Flumes are currently installed in Seep A, Seep B, Seep C, Seep D, and Old Outfall 002 under Nationwide Permit 38 (United States Army Corps of Engineers, June 2019). Where present, they were used to calculate flow based on the data collected by the level logger installed in the flume. Flow Velocity Gauging Where flumes are not installed (i.e., Willis Creek and Georgia Branch Creek), the flow rate of the stream was measured using a submersible flow meter. The flow meter was placed beneath the flowing stream along the cross section of the stream at regular intervals (e.g. every six inches) and the height of the water was recorded along with the recorded water velocity. These measurements were then used to calculate the volumetric flow of water passing through the structure based on the regular geometry and measured flow rates. Flow was measured using two to three transects to assess variability in estimated flow. Transects were selected that have fairly uniform cross sections that could be gauged with minimal disturbance. Synoptic Water Level Measurements Water level measurements for monitoring wells listed in Table 3 were collected during a single synoptic event. At each location, notes on well condition, weather, date and time of collection, depth to bottom of well and depth to water level from top of casing were recorded. Groundwater Sampling Methods Designated monitoring wells were monitored as part of the quarterly monitoring activities. These wells are listed in Table 3 and Figure 7. The groundwater samples were analyzed for the list of PFAS compounds listed in Table 1. Field equipment was inspected by the program on-Site supervisor and calibrated daily prior to use according to the manufacturer’s recommended guidelines. Field parameters were measured with a water quality meter after sample collection and included the following: •pH; •Temperature (°C); Appendix A 4 September 2020 •Specific Conductivity (µS/cm); •DO (mg/L); •ORP (mV); •Turbidity (nephelometric turbidity units [NTU]); and, •Color. Non-dedicated or non-disposable sampling equipment was decontaminated immediately before sample collection in the following manner: 1.De-ionized water rinse; 2.Scrub with de-ionized water containing non-phosphate detergent (i.e., Alconox®); and 3.De-ionized water rinse. Disposable equipment (e.g. gloves, tubing, etc.) was not reused. New sample containers were used for each sample. Groundwater samples were collected, where possible, using low-flow sampling techniques as discussed in detail in the Long-term Groundwater Monitoring Plan (Parsons, 2018) and briefly summarized here. 1. New disposable or dedicated HDPE tubing was placed at the midpoint of the well’s screened interval. 2.Water was purged through a flow-through cell attached to a water quality meter capable of measuring pH, temperature, specific conductivity, dissolved oxygen, and ORP. 3.Water was pumped using a peristaltic pump, with dedicated silicone tubing for the pump head, at wells with water level less than 30 feet. A submersible pump was used for wells with water level deeper than 30 feet. 4. Groundwater was pumped directly from submerged tubing through the pump head to a flow-through cell until field parameters (pH, temperature, specific conductivity, DO, ORP) were stabilized within ±10% over three consecutive readings within a five-minute interval. If field parameters stabilized, but turbidity remained stable yet elevated greater than 20 NTU, field personnel purged five well volumes prior to sample collection. 5. Water levels in the designated wells were monitored during purging so that minimum draw- down of the water column was maintained. 6.Once flow-through cell readings were stable, the flow-through cell was disconnected, the tubing cut to provide a new clean end and samples were collected from the discharge of the peristaltic pump in new 250 mL laboratory-supplied HDPE bottles. 7.Sample identification information (e.g., well/sample identification number, sample time and date, samplers’ names, preservative, and analytical parameters) were recorded on the bottle label with permanent ink after the sample was collected. 5 September 2020 Appendix A Sample Packing and Shipping Upon sample collection, each containerized sample was placed into an insulated sample cooler. Wet ice was placed around the sample containers within heavy-duty plastic bags within the sample cooler. A chain-of-custody form was completed by the field sample custodian for each sample shipment. Sample locations, sample identification numbers, description of samples, number of samples collected, and specific laboratory analyses were recorded on the chain-of-custody form. Field QA/QC Samples Field quality assurance/ quality control (QA/QC) samples were collected as discussed in detail in the Long-term Groundwater Monitoring Plan (Parsons, 2018) and summarized below: 1.For samples collected to be analyzed by Method Table 3+, three blind duplicate samples were collected; two in the February sampling event and one in the April sampling event. 2.For samples collected to be analyzed by Method Table 3+, three MS/MSD samples were collected; two in the February sampling event and one in the April sampling event. 3.For groundwater samples collected in February, equipment blanks and field blanks were collected daily. 4.For surface water samples collected in April, three equipment blanks were collected. REFERENCES Parsons, 2018. Long-term Groundwater Monitoring Plan. September 28, 2018. Parsons, 2020. Fayetteville Works Health and Safety Plan. United States Army Corps of Engineers. Nationwide Permit 6. 19 March 2017. http://saw- reg.usace.army.mil/NWP2017/2017NWP06.pdf. Accessed 30 January 2019. United States Army Corps of Engineers. Nationwide Permit 36, 06 June 2019. APPENDIX B Supplemental Analytical Tables TABLE B1 SEEP AND SURFACE WATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program CAP SW Sampling 2Q20 CAP SW SAMPLING 2Q20 CAP SW Sampling 2Q20 CAP SW Sampling 2Q20 CAP SW Sampling 2Q20 CAP SW Sampling 2Q20 Location ID CFR-BLADEN CFR-KINGS CFR-MILE-76 CFR-MILE-76 GBC-1 Intake River Water at Facility Field Sample ID CAP2Q20-CFR-BLADEN-051320 CAP2Q20-CFR-KINGS-051920 CAP2Q20-CFR-RM-76-051320 CAP2Q20-CFR-RM-76-051320-D CAP2Q20-GBC-1-051320 2R00513 Sample Date 5/13/2020 5/19/2020 5/13/2020 5/13/2020 5/13/2020 5/13/2020 QA/QC Field Duplicate Sample Delivery Group (SDG)320-60920-1 410-2520-1 320-60921-1 320-60921-1 320-60920-1 280-136659-1 Lab Sample ID 320-60920-6 410-2520-1 320-60921-1 320-60921-2 320-60920-5 280-136659-3Other PFAS (ng/L) 10:2 Fluorotelomer sulfonate <2 <5 <2 <2 <2 -- 11Cl-PF3OUdS <2 <2 <2 <2 <2 -- 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<20 <3 <20 <20 <20 -- 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<20 <2 <20 <20 <20 -- 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2 <3 <2 <2 <2 -- 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <4 <3 <4 <4 <4 -- 6:2 Fluorotelomer sulfonate <20 <5 <20 <20 <20 -- 9Cl-PF3ONS <2 <2 <2 <2 <2 -- ADONA <2.1 --<2.1 <2.1 <2.1 -- DONA --<2 -------- NaDONA <2.1 --<2.1 <2.1 <2.1 -- N-ethyl perfluorooctane sulfonamidoacetic acid <20 <3 <20 <20 <20 -- N-ethylperfluoro-1-octanesulfonamide <2 <5 UJ <2 <2 <2 -- N-methyl perfluoro-1-octanesulfonamide <2 <3 UJ <2 <2 <2 -- N-methyl perfluorooctane sulfonamidoacetic acid <20 <2 <20 <20 <20 -- Perfluorobutane Sulfonic Acid 4.7 3.4 4.7 5.3 2.4 -- Perfluorobutanoic Acid 5.6 <5 5.5 5.1 8.6 -- Perfluorodecane Sulfonic Acid <2 <2 <2 <2 <2 -- Perfluorodecanoic Acid <2 <2 <2 <2 <2 -- Perfluorododecane sulfonic acid (PFDoS)<2 <3 <2 <2 <2 -- Perfluorododecanoic Acid <2 <2 <2 <2 <2 -- Perfluoroheptane sulfonic acid (PFHpS)<2 <2 <2 <2 <2 -- Perfluoroheptanoic Acid ------------ Perfluorohexadecanoic acid (PFHxDA)<2 <3 <2 <2 <2 -- Perfluorohexane Sulfonic Acid 5.5 4.1 5.6 5.5 <2 -- Perfluorohexanoic Acid 15 14 15 16 3.1 -- Perfluorononanesulfonic acid <2 <2 <2 <2 <2 -- Perfluorononanoic Acid <2 <2 <2 <2 <2 -- Perfluorooctadecanoic acid <2 <3 <2 <2 <2 -- Perfluorooctane Sulfonamide <2 <2 <2 <2 <2 -- Perfluoropentane sulfonic acid (PFPeS)<2 <2 <2 <2 <2 -- Perfluoropentanoic Acid 12 9.2 11 13 8.4 -- Perfluorotetradecanoic Acid <2 <2 <2 <2 <2 -- Perfluorotridecanoic Acid <2 <2 <2 <2 <2 -- Perfluoroundecanoic Acid <2 <2 <2 <2 <2 -- PFOA 7.7 7 8 7.8 2.8 -- PFOS 15 11 15 14 <2 -- Total Other PFAS 66 49 65 67 25 ND TR0795 Page 1 of 3 September 2020 TABLE B1 SEEP AND SURFACE WATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 CAP SW Sampling 2Q20 OLDOF-1 OUTFALL 002 SEEP-B SEEP-C SEEP-D TARHEEL CAP2Q20-OLDOF-1-24-051420 CAP2Q20-OUTFALL 002-24-051420 CAP2Q20-SEEP-B-24-051420 CAP2Q20-SEEP-C-24-051420 CAP2Q20-SEEP-D-24-051420 CAP2Q20-CFR-TARHEEL-051420 5/14/2020 5/14/2020 5/14/2020 5/14/2020 5/14/2020 5/14/2020 410-2521-1 410-2521-1 410-2519-1 410-2519-1 410-2519-1 320-60921-1 410-2521-2 410-2521-1 410-2519-2 410-2519-3 410-2519-4 320-60921-3 <5 <5 <5 <5 <5 <2 <2 <2 <2 <2 <2 <2 <3 <3 <3 <3 <3 <20 <2 <2 <2 <2 <2 <20 <3 <3 <3 <3 <3 <2 <3 <3 <3 <3 <3 <4 <5 <5 <5 <5 <5 <20 <2 <2 <2 <2 <2 <2 ----------<2.1 <2 <2 <2 <2 <2 -- ----------<2.1 <3 <3 <3 <3 <3 <20 <5 <5 <5 <5 <5 <2 <3 <3 <3 <3 <3 <2 <2 <2 <2 <2 <2 <20 <2 3.8 <2 <2 <2 4.9 60 5.5 310 310 160 5.2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <3 <3 <3 <3 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 ------------ <3 <3 <3 <3 <3 <2 <2 4.2 <2 <2 <2 5.6 14 13 34 77 38 15 <2 <2 <2 <2 <2 <2 8.2 <2 7.8 <2 2.8 <2 <3 <3 <3 <3 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 120 19 980 1,400 680 12 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 30 7.1 15 17 11 7.9 2 11 <2 <2 <2 16 230 64 1,300 1,800 890 67 TR0795 Page 2 of 3 September 2020 TABLE B1 SEEP AND SURFACE WATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 CAP SW SAMPLING 2Q20 EB EB FBLK CAP2Q20-EB-PP-051920 CAP2Q20-EB-ISCO-052120 CAP2Q20-FB-051920 5/19/2020 5/21/2020 5/19/2020 Equipment Blank Equipment Blank Field Blank 410-2520-1 410-2520-1 410-2520-1 410-2520-3 410-2520-4 410-2520-2 <5 <5 <5 <2 <2 <2 Notes: <3 <3 <3 Bold - Analyte detected above associated reporting limit <2 <2 <2 ND - no listed analytes were detected above the associated reporting limits <3 <3 <3 ng/L - nanograms per liter <3 <3 <3 QA/QC - Quality assurance/ quality control <5 <5 <5 SDG - Sample Delivery Group <2 <2 <2 UJ – Analyte not detected. Reporting limit may not be accurate or precise. ------< - Analyte not detected above associated reporting limit. <2 <2 <2 ------ <3 <3 <3 <5 <5 <5 <3 <3 <3 <2 <2 <2 <2 <2 <2 <5 <5 <5 <2 <2 <2 <2 <2 <2 <3 <3 <3 <2 <2 <2 <2 <2 <2 ------ <3 <3 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <3 <3 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 ND ND ND TR0795 Page 3 of 3 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 Location ID BLADEN-1D BLADEN-1D LTW-01 LTW-02 LTW-03 LTW-04 Field Sample ID CAP2Q20-BLADEN-1D-050620 CAP2Q20-BLADEN-1D-050620-D CAP2Q20-LTW-01-050720 CAP2Q20-LTW-02-051220 CAP2Q20-LTW-03-051320 CAP2Q20-LTW-04-050820 Sample Date 5/6/2020 5/6/2020 5/7/2020 5/12/2020 5/13/2020 5/8/2020 QA/QC Field Duplicate Sample Delivery Group (SDG)320-60762-1 320-60762-1 320-60761-1 320-60920-1 320-60920-1 320-60791-1 Lab Sample ID 320-60762-4 320-60762-5 320-60761-2 320-60920-1 320-60920-2 320-60791-5Other PFAS (ng/L) 10:2 Fluorotelomer sulfonate <2 <2 <2 <2 <2 <2 11Cl-PF3OUdS <2 <2 <2 <2 <2 <2 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS)<20 <20 <20 <20 <20 <20 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS)<20 <20 <20 <20 <20 <20 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol <2 <2 <2 <2 <2 <2 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol <4 <4 <4 <4 <4 <4 6:2 Fluorotelomer sulfonate <20 <20 <20 <20 <20 <20 9Cl-PF3ONS <2 <2 <2 <2 <2 <2 ADONA <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 DONA ------------ NaDONA <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 N-ethyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20 <20 N-ethylperfluoro-1-octanesulfonamide <2 <2 <2 <2 <2 <2 N-methyl perfluoro-1-octanesulfonamide <2 <2 <2 <2 <2 <2 N-methyl perfluorooctane sulfonamidoacetic acid <20 <20 <20 <20 <20 <20 Perfluorobutane Sulfonic Acid <2 24 J 2.9 <2 <2 <2 Perfluorobutanoic Acid 4.4 4.5 150 54 140 410 Perfluorodecane Sulfonic Acid <2 <2 <2 <2 <2 <2 Perfluorodecanoic Acid <2 <2 <2 <2 <2 <2 Perfluorododecane sulfonic acid (PFDoS)<2 <2 <2 <2 <2 <2 Perfluorododecanoic Acid <2 <2 <2 <2 <2 <2 Perfluoroheptane sulfonic acid (PFHpS)<2 <2 <2 <2 <2 <2 Perfluoroheptanoic Acid <2 <2 49 11 22 62 Perfluorohexadecanoic acid (PFHxDA)<2 <2 <2 <2 <2 <2 Perfluorohexane Sulfonic Acid <2 <2 5.2 <2 <2 <2 Perfluorohexanoic Acid <2 <2 27 8.6 18 41 Perfluorononanesulfonic acid <2 <2 <2 <2 <2 <2 Perfluorononanoic Acid <2 <2 <2 <2 <2 <2 Perfluorooctadecanoic acid <2 <2 <2 <2 <2 <2 Perfluorooctane Sulfonamide <2 <2 <2 <2 <2 <2 Perfluoropentane sulfonic acid (PFPeS)<2 <2 <2 <2 <2 <2 Perfluoropentanoic Acid 4.8 4.8 400 210 770 1,400 Perfluorotetradecanoic Acid <2 <2 <2 <2 <2 <2 Perfluorotridecanoic Acid <2 <2 <2 <2 <2 <2 Perfluoroundecanoic Acid <2 <2 <2 <2 <2 <2 PFOA <2 <2 35 <2 <2 7.2 PFOS <2 <2 10 J <2 <2 <2 Total Other PFAS 9 33 680 280 950 1,900 TR0795 Page 1 of 6 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 LTW-05 PIW-1D PIW-3D PIW-7D PIW-7S PW-04 CAP2Q20-LTW-05-050820 CAP2Q20-PIW-1D-050720 CAP2Q20-PIW-3D-050720 CAP2Q20-PIW-7D-050820 CAP2Q20-PIW-7S-050820 CAP2Q20-PW-04-051320 5/8/2020 5/7/2020 5/7/2020 5/8/2020 5/8/2020 5/13/2020 320-60791-1 320-60761-1 320-60761-1 320-60791-1 320-60791-1 320-60920-1 320-60791-2 320-60761-4 320-60761-1 320-60791-4 320-60791-1 320-60920-3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <4 <4 <4 <4 <4 <4 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 ------------ <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <2 <2 3 <2 3.9 <2 210 64 68 120 300 8.6 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 350 16 32 61 86 7.5 <2 <2 <2 <2 <2 <2 <2 <2 4.4 <2 4.7 <2 70 10 24 18 45 3.2 <2 <2 <2 <2 <2 <2 <2 <2 4.3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 1,700 140 130 960 880 13 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2.6 7.4 35 <2 16 <2 <2 <2 11 <2 7.3 <2 2,300 240 310 1,200 1,300 32 TR0795 Page 2 of 6 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 PW-06 PW-07 PW-09 PW-11 PZ-22 SMW-10 CAP2Q20-PW-06-050620 CAP2Q20-PW-07-051420 CAP2Q20-PW-09-050720 CAP2Q20-PW-11-050720 CAP2Q20-PZ-22-050820 CAP2Q20-SMW-10-050720 5/6/2020 5/14/2020 5/7/2020 5/7/2020 5/8/2020 5/7/2020 320-60762-1 320-60920-1 320-60761-1 320-60761-1 320-60791-1 320-60761-1 320-60762-7 320-60920-4 320-60761-5 320-60761-3 320-60791-3 320-60761-7 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <4 <4 <4 <4 <4 <4 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 ------------ <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 12 24 <2 90 130 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 5.7 5.4 <2 210 32 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2.5 <2 <2 4.1 3.7 <2 23 19 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 11 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 16 16 <2 520 940 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 6.8 2.1 <2 31 <2 <2 <2 <2 <2 3.2 <2 <2 45 51 ND 890 1,100 ND TR0795 Page 3 of 6 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 SMW-11 SMW-12 EB EB EB EB CAP2Q20-SMW-11-050720 CAP2Q20-SMW-12-050620 CAP2Q20-EB-DV-050620 CAP2Q20-EB-PP-050620 CAP2Q20-EB-DV-050720 CAP2Q20-EB-PP-050720 5/7/2020 5/6/2020 5/6/2020 5/6/2020 5/7/2020 5/7/2020 Equipment Blank Equipment Blank Equipment Blank Equipment Blank 320-60761-1 320-60762-1 320-60762-1 320-60762-1 320-60761-1 320-60761-1 320-60761-6 320-60762-6 320-60762-2 320-60762-1 320-60761-9 320-60761-8 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <4 <4 <4 <4 <4 <4 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 ------------ <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 28 17 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 14 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 12 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 37 45 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 44 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 140 62 ND ND ND ND TR0795 Page 4 of 6 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 EB EB EB EB FBLK FBLK CAP2Q20-EB-PP-050820 CAP2Q20-EB-PP-051220 CAP2Q20-EB-PP-051320 CAP2Q20-EB-PP-051420 CAP2Q20-FB-050620 CAP2Q20-FB-050720 5/8/2020 5/12/2020 5/13/2020 5/14/2020 5/6/2020 5/7/2020 Equipment Blank Equipment Blank Equipment Blank Equipment Blank Field Blank Field Blank 320-60791-1 320-60920-1 320-60920-1 320-60920-1 320-60762-1 320-60761-1 320-60791-6 320-60920-7 320-60920-8 320-60920-9 320-60762-3 320-60761-10 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <4 <4 <4 <4 <4 <4 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 ------------ <2.1 <2.1 <2.1 <2.1 <2.1 <2.1 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <20 <20 <20 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 ND ND ND ND ND ND TR0795 Page 5 of 6 September 2020 TABLE B2 GROUNDWATER ANALYTICAL RESULTS - OTHER PFAS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Program Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample IDOther PFAS (ng/L) 10:2 Fluorotelomer sulfonate 11Cl-PF3OUdS 1H,1H,2H,2H-perfluorodecanesulfonate (8:2 FTS) 1H,1H,2H,2H-perfluorohexanesulfonate (4:2 FTS) 2-(N-ethyl perfluoro-1-octanesulfonamido)-ethanol 2-(N-methyl perfluoro-1-octanesulfonamido)-ethanol 6:2 Fluorotelomer sulfonate 9Cl-PF3ONS ADONA DONA NaDONA N-ethyl perfluorooctane sulfonamidoacetic acid N-ethylperfluoro-1-octanesulfonamide N-methyl perfluoro-1-octanesulfonamide N-methyl perfluorooctane sulfonamidoacetic acid Perfluorobutane Sulfonic Acid Perfluorobutanoic Acid Perfluorodecane Sulfonic Acid Perfluorodecanoic Acid Perfluorododecane sulfonic acid (PFDoS) Perfluorododecanoic Acid Perfluoroheptane sulfonic acid (PFHpS) Perfluoroheptanoic Acid Perfluorohexadecanoic acid (PFHxDA) Perfluorohexane Sulfonic Acid Perfluorohexanoic Acid Perfluorononanesulfonic acid Perfluorononanoic Acid Perfluorooctadecanoic acid Perfluorooctane Sulfonamide Perfluoropentane sulfonic acid (PFPeS) Perfluoropentanoic Acid Perfluorotetradecanoic Acid Perfluorotridecanoic Acid Perfluoroundecanoic Acid PFOA PFOS Total Other PFAS CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 CAP MW Sampling 2Q20 FBLK FBLK FBLK FBLK CAP2Q20-FB-050820 CAP2Q20-FB-051220 CAP2Q20-FB-051320 CAP2Q20-FB-051420 5/8/2020 5/12/2020 5/13/2020 5/14/2020 Field Blank Field Blank Field Blank Field Blank 320-60791-1 320-60920-1 320-60920-1 410-2521-1 320-60791-7 320-60920-10 320-60920-11 410-2521-3 <2 <2 <2 <5 Notes: <2 <2 <2 <2 Bold - Analyte detected above associated reporting limit <20 <20 <20 <3 ND - no listed analytes were detected above the associated reporting limits <20 <20 <20 <2 ng/L - nanograms per liter <2 <2 <2 <3 QA/QC - Quality assurance/ quality control <4 <4 <4 <3 SDG - Sample Delivery Group <20 <20 <20 <5 J - Analyte detected. Reported value may not be accurate or precise <2 <2 <2 <2 UJ – Analyte not detected. Reporting limit may not be accurate or precise. <2.1 <2.1 <2.1 <2.1 < - Analyte not detected above associated reporting limit. ------<2 <2.1 <2.1 <2.1 <2.1 <20 <20 <20 <3 <2 <2 <2 <5 <2 <2 <2 <3 <20 <20 <20 <2 <2 <2 <2 <2 <2 <2 <2 <5 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <3 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 ND ND ND ND TR0795 Page 6 of 6 September 2020 APPENDIX C Supplemental Flow Data TABLE C1 SEEP A FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:12:40 AM 1.69 0.564 155 4,640 5/13/2020 12:42:40 AM 1.66 0.557 149 4,470 5/13/2020 1:12:40 AM 1.65 0.550 145 4,340 5/13/2020 1:42:40 AM 1.68 0.562 153 4,590 5/13/2020 2:12:40 AM 1.69 0.564 154 4,630 5/13/2020 2:42:40 AM 1.71 0.571 159 4,780 5/13/2020 3:12:40 AM 1.72 0.576 163 4,890 5/13/2020 3:42:40 AM 1.70 0.570 159 4,760 5/13/2020 4:12:40 AM 1.76 0.590 174 5,210 5/13/2020 4:42:40 AM 1.71 0.573 161 4,830 5/13/2020 5:12:40 AM 1.78 0.597 179 5,360 5/13/2020 5:42:40 AM 1.71 0.572 160 4,800 5/13/2020 6:12:40 AM 1.77 0.593 176 5,290 5/13/2020 6:42:40 AM 1.72 0.574 162 4,850 5/13/2020 7:12:40 AM 1.78 0.596 178 5,350 5/13/2020 7:42:40 AM 1.72 0.574 161 4,840 5/13/2020 8:12:40 AM 1.74 0.584 169 5,060 5/13/2020 8:42:40 AM 1.71 0.573 161 4,830 5/13/2020 9:12:40 AM 1.73 0.579 165 4,960 5/13/2020 9:42:40 AM 1.72 0.577 163 4,900 5/13/2020 10:12:40 AM 1.74 0.581 167 5,000 5/13/2020 10:42:40 AM 1.73 0.580 166 4,970 5/13/2020 11:12:40 AM 1.75 0.584 169 5,080 5/13/2020 11:42:40 AM 1.77 0.591 174 5,230 5/13/2020 12:12:40 PM 1.69 0.565 155 4,660 5/13/2020 12:42:40 PM 1.78 0.597 179 5,360 5/13/2020 1:12:40 PM 1.72 0.575 162 4,870 5/13/2020 1:42:40 PM 1.78 0.595 177 5,320 5/13/2020 2:12:40 PM 1.73 0.580 166 4,970 5/13/2020 2:42:40 PM 1.74 0.582 168 5,030 5/13/2020 3:12:40 PM 1.67 0.558 150 4,510 5/13/2020 3:42:40 PM 1.72 0.574 162 4,850 5/13/2020 4:12:40 PM 1.64 0.547 142 4,270 5/13/2020 4:42:40 PM 1.74 0.582 167 5,020 5/13/2020 5:12:40 PM 1.72 0.576 163 4,890 5/13/2020 5:42:40 PM 1.71 0.573 161 4,830 5/13/2020 6:12:40 PM 1.72 0.575 162 4,870 5/13/2020 6:42:40 PM 1.73 0.579 165 4,960 5/13/2020 7:12:40 PM 1.76 0.588 172 5,150 5/13/2020 7:42:40 PM 1.72 0.575 162 2,430 5/13/2020 8:12:40 PM 1.75 0.585 170 5,090 5/13/2020 8:42:40 PM 1.72 0.576 163 4,890 TR0795 Page 1 of 3 September 2020 TABLE C1 SEEP A FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 9:12:40 PM 1.78 0.597 179 5,360 5/13/2020 9:42:40 PM 1.73 0.578 164 4,920 5/13/2020 10:12:40 PM 1.80 0.603 184 5,510 5/13/2020 10:42:40 PM 1.72 0.575 162 4,870 5/13/2020 11:12:40 PM 1.75 0.586 170 5,110 5/13/2020 11:42:40 PM 1.70 0.570 158 4,750 5/14/2020 12:12:40 AM 1.68 0.563 153 4,600 5/14/2020 12:42:40 AM 1.70 0.569 158 4,750 5/14/2020 1:12:40 AM 1.72 0.575 162 4,870 5/14/2020 1:42:40 AM 1.70 0.568 157 4,720 5/14/2020 2:12:40 AM 1.65 0.552 146 4,370 5/14/2020 2:42:40 AM 1.70 0.569 158 4,750 5/14/2020 3:12:40 AM 1.65 0.553 147 4,400 5/14/2020 3:42:40 AM 1.71 0.571 159 4,780 5/14/2020 4:12:40 AM 1.71 0.571 159 4,780 5/14/2020 4:42:40 AM 1.71 0.573 160 4,810 5/14/2020 5:12:40 AM 1.72 0.576 163 4,890 5/14/2020 5:42:40 AM 1.72 0.575 162 4,870 5/14/2020 6:12:40 AM 1.78 0.597 179 5,370 5/14/2020 6:42:40 AM 1.71 0.571 159 4,780 5/14/2020 7:12:40 AM 1.76 0.590 173 5,200 5/14/2020 7:42:40 AM 1.72 0.575 162 4,870 5/14/2020 8:12:40 AM 1.74 0.583 168 5,050 5/14/2020 8:42:40 AM 1.74 0.583 168 5,050 5/14/2020 9:12:40 AM 1.81 0.604 185 5,550 5/14/2020 9:42:40 AM 1.72 0.577 164 4,910 5/14/2020 10:12:40 AM 1.69 0.564 155 4,640 5/14/2020 10:42:40 AM 1.72 0.575 162 4,870 5/14/2020 11:12:40 AM 1.67 0.558 150 4,490 5/14/2020 11:42:40 AM 1.72 0.576 163 4,880 5/14/2020 12:12:40 PM 1.65 0.551 145 4,360 5/14/2020 12:42:40 PM 1.72 0.575 162 4,870 5/14/2020 1:12:40 PM 1.61 0.537 136 4,070 5/14/2020 1:42:40 PM 1.71 0.574 161 4,840 5/14/2020 2:12:40 PM 1.62 0.542 139 4,180 5/14/2020 2:42:40 PM 1.71 0.573 161 4,820 5/14/2020 3:12:40 PM 1.61 0.537 136 4,070 5/14/2020 3:42:40 PM 1.72 0.576 163 4,890 5/14/2020 4:12:40 PM 1.65 0.553 147 4,400 5/14/2020 4:42:40 PM 1.72 0.577 164 4,910 5/14/2020 5:12:40 PM 1.71 0.571 159 4,780 TR0795 Page 2 of 3 September 2020 TABLE C1 SEEP A FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 5:42:40 PM 1.72 0.575 162 4,870 5/14/2020 6:12:40 PM 1.69 0.565 155 4,640 5/14/2020 6:42:40 PM 1.72 0.574 161 4,840 5/14/2020 7:12:40 PM 1.73 0.580 166 4,980 5/14/2020 7:42:40 PM 1.72 0.574 161 4,840 5/14/2020 8:12:40 PM 1.79 0.600 181 5,440 5/14/2020 8:42:40 PM 1.71 0.571 159 4,780 5/14/2020 9:12:40 PM 1.76 0.588 172 5,160 5/14/2020 9:42:40 PM 1.72 0.576 163 4,880 5/14/2020 10:12:40 PM 1.79 0.599 180 5,410 5/14/2020 10:42:40 PM 1.71 0.574 161 4,840 5/14/2020 11:12:40 PM 1.73 0.579 165 4,950 5/14/2020 11:42:40 PM 1.70 0.570 159 4,760 Total 464,980 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous TR0795 Page 3 of 3 September 2020 TABLE C2SEEP B-TR1 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:17:05 AM 0.913 0.305 32.6 980 5/13/2020 12:47:05 AM 0.883 0.295 29.9 900 5/13/2020 1:17:05 AM 0.863 0.289 28.2 850 5/13/2020 1:47:05 AM 0.900 0.301 31.4 940 5/13/2020 2:17:05 AM 0.907 0.303 32.1 960 5/13/2020 2:47:05 AM 0.928 0.311 34.0 1,000 5/13/2020 3:17:05 AM 0.942 0.315 35.4 1,100 5/13/2020 3:47:05 AM 0.925 0.310 33.8 1,000 5/13/2020 4:17:05 AM 0.986 0.330 39.8 1,200 5/13/2020 4:47:05 AM 0.939 0.314 35.1 1,100 5/13/2020 5:17:05 AM 1.011 0.338 42.5 1,300 5/13/2020 5:47:05 AM 0.941 0.315 35.3 1,100 5/13/2020 6:17:05 AM 1.007 0.337 42.0 1,300 5/13/2020 6:47:05 AM 0.945 0.316 35.7 1,100 5/13/2020 7:17:05 AM 1.009 0.338 42.2 1,300 5/13/2020 7:47:05 AM 0.938 0.314 35.0 1,000 5/13/2020 8:17:05 AM 0.973 0.326 38.5 1,200 5/13/2020 8:47:05 AM 0.942 0.315 35.4 1,100 5/13/2020 9:17:05 AM 0.961 0.322 37.2 1,100 5/13/2020 9:47:05 AM 0.952 0.319 36.4 1,100 5/13/2020 10:17:05 AM 0.970 0.325 38.2 1,100 5/13/2020 10:47:05 AM 0.960 0.321 37.1 1,100 5/13/2020 11:17:05 AM 0.961 0.322 37.2 1,100 5/13/2020 11:47:05 AM 0.943 0.316 35.5 1,100 5/13/2020 12:17:05 PM 0.872 0.292 29.0 870 5/13/2020 12:47:05 PM 0.977 0.327 38.9 1,200 5/13/2020 1:17:05 PM 0.919 0.307 33.2 1,000 5/13/2020 1:47:05 PM 0.989 0.331 40.1 1,200 5/13/2020 2:17:05 PM 0.943 0.316 35.5 1,100 5/13/2020 2:47:05 PM 0.943 0.316 35.5 1,100 5/13/2020 3:17:05 PM 0.888 0.297 30.4 910 5/13/2020 3:47:05 PM 0.934 0.313 34.6 1,000 5/13/2020 4:17:05 PM 0.859 0.287 27.9 840 5/13/2020 4:47:05 PM 0.958 0.321 36.9 1,100 5/13/2020 5:17:05 PM 0.947 0.317 35.9 1,100 5/13/2020 5:47:05 PM 0.942 0.315 35.4 1,100 5/13/2020 6:17:05 PM 0.946 0.317 35.8 1,100 5/13/2020 6:47:05 PM 0.958 0.321 36.9 1,100 5/13/2020 7:17:05 PM 0.983 0.329 39.5 1,200 5/13/2020 7:47:05 PM 0.948 0.317 36.0 1,100 5/13/2020 8:17:05 PM 0.974 0.326 38.6 1,200 5/13/2020 8:47:05 PM 0.952 0.319 36.4 1,100 5/13/2020 9:17:05 PM 1.006 0.337 41.9 1,300 5/13/2020 9:47:05 PM 0.951 0.318 36.3 1,100 5/13/2020 10:17:05 PM 1.031 0.345 44.7 1,300 TR0795 Page 1 of 3 September 2020 TABLE C2SEEP B-TR1 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 10:47:05 PM 0.949 0.318 36.1 1,100 5/13/2020 11:17:05 PM 0.972 0.325 38.4 1,200 5/13/2020 11:47:05 PM 0.919 0.307 33.2 1,000 5/14/2020 12:17:05 AM 0.907 0.303 32.1 960 5/14/2020 12:47:05 AM 0.939 0.314 35.1 1,100 5/14/2020 1:17:05 AM 0.949 0.318 36.1 1,100 5/14/2020 1:47:05 AM 0.925 0.310 33.8 1,000 5/14/2020 2:17:05 AM 0.878 0.294 29.5 890 5/14/2020 2:47:05 AM 0.923 0.309 33.6 1,000 5/14/2020 3:17:05 AM 0.885 0.296 30.1 900 5/14/2020 3:47:05 AM 0.933 0.312 34.5 1,000 5/14/2020 4:17:05 AM 0.934 0.313 34.6 1,000 5/14/2020 4:47:05 AM 0.943 0.316 35.5 1,100 5/14/2020 5:17:05 AM 0.956 0.320 36.7 1,100 5/14/2020 5:47:05 AM 0.956 0.320 36.7 1,100 5/14/2020 6:17:05 AM 1.023 0.342 43.8 1,300 5/14/2020 6:47:05 AM 0.936 0.313 34.8 1,000 5/14/2020 7:17:05 AM 0.993 0.332 40.5 1,200 5/14/2020 7:47:05 AM 0.949 0.318 36.1 1,100 5/14/2020 8:17:05 AM 0.971 0.325 38.3 1,100 5/14/2020 8:47:05 AM 0.979 0.328 39.1 1,200 5/14/2020 9:17:05 AM 1.045 0.350 46.2 1,400 5/14/2020 9:47:05 AM 0.956 0.320 36.7 1,100 5/14/2020 10:17:05 AM 0.934 0.313 34.6 1,000 5/14/2020 10:47:05 AM 0.971 0.325 38.3 1,100 5/14/2020 11:17:05 AM 0.925 0.310 33.8 1,000 5/14/2020 11:47:05 AM 1.013 0.339 42.7 1,300 5/14/2020 12:17:05 PM 0.972 0.325 38.4 1,200 5/14/2020 12:47:05 PM 1.040 0.348 45.7 1,400 5/14/2020 1:17:05 PM 0.917 0.307 33.0 990 5/14/2020 1:47:05 PM 1.000 0.335 41.3 1,200 5/14/2020 2:17:05 PM 0.898 0.300 31.3 940 5/14/2020 2:47:05 PM 0.962 0.322 37.3 1,100 5/14/2020 3:17:05 PM 0.836 0.280 26.0 780 5/14/2020 3:47:05 PM 0.954 0.319 36.5 1,100 5/14/2020 4:17:05 PM 0.890 0.298 30.6 920 5/14/2020 4:47:05 PM 0.957 0.320 36.8 1,100 5/14/2020 5:17:05 PM 0.934 0.313 34.6 1,000 5/14/2020 5:47:05 PM 0.946 0.317 35.8 1,100 5/14/2020 6:17:05 PM 0.922 0.309 33.5 1,000 5/14/2020 6:47:05 PM 0.937 0.314 34.9 1,000 5/14/2020 7:17:05 PM 0.956 0.320 36.7 1,100 5/14/2020 7:47:05 PM 0.952 0.319 36.4 1,100 5/14/2020 8:17:05 PM 1.028 0.344 44.3 1,300 5/14/2020 8:47:05 PM 0.947 0.317 35.9 1,100 TR0795 Page 2 of 3 September 2020 TABLE C2SEEP B-TR1 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 9:17:05 PM 0.998 0.334 41.1 1,200 5/14/2020 9:47:05 PM 0.959 0.321 37.0 1,100 5/14/2020 10:17:05 PM 1.032 0.345 44.8 1,300 5/14/2020 10:47:05 PM 0.953 0.319 36.4 1,100 5/14/2020 11:17:05 PM 0.967 0.324 37.8 1,100 5/14/2020 11:47:05 PM 0.948 0.317 36.0 1,100 Total 104,730 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as TR0795 Page 3 of 3 September 2020 TABLE C3 SEEP B-TR2 FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:12:37 AM 0.852 0.285 27.3 820 5/13/2020 12:42:37 AM 0.826 0.276 25.2 760 5/13/2020 1:12:37 AM 0.806 0.270 23.7 710 5/13/2020 1:42:37 AM 0.837 0.280 26.1 780 5/13/2020 2:12:37 AM 0.837 0.280 26.1 780 5/13/2020 2:42:37 AM 0.852 0.285 27.3 820 5/13/2020 3:12:37 AM 0.877 0.293 29.4 880 5/13/2020 3:42:37 AM 0.854 0.286 27.5 820 5/13/2020 4:12:37 AM 0.907 0.303 32.1 960 5/13/2020 4:42:37 AM 0.861 0.288 28.1 840 5/13/2020 5:12:37 AM 0.929 0.311 34.1 1,000 5/13/2020 5:42:37 AM 0.863 0.289 28.2 850 5/13/2020 6:12:37 AM 0.928 0.311 34.0 1,000 5/13/2020 6:42:37 AM 0.865 0.289 28.4 850 5/13/2020 7:12:37 AM 0.944 0.316 35.6 1,100 5/13/2020 7:42:37 AM 0.875 0.293 29.2 880 5/13/2020 8:12:37 AM 0.913 0.305 32.6 980 5/13/2020 8:42:37 AM 0.89 0.298 30.6 920 5/13/2020 9:12:37 AM 0.919 0.307 33.2 1,000 5/13/2020 9:42:37 AM 0.915 0.306 32.8 980 5/13/2020 10:12:37 AM 0.927 0.310 33.9 1,000 5/13/2020 10:42:37 AM 0.932 0.312 34.4 1,000 5/13/2020 11:12:37 AM 0.931 0.312 34.3 1,000 5/13/2020 11:42:37 AM 0.925 0.310 33.8 1,000 5/13/2020 12:12:37 PM 0.854 0.286 27.5 820 5/13/2020 12:42:37 PM 0.967 0.324 37.8 1,100 5/13/2020 1:12:37 PM 0.921 0.308 33.4 1,000 5/13/2020 1:42:37 PM 1.01 0.338 42.3 1,300 5/13/2020 2:12:37 PM 0.97 0.325 38.2 1,100 5/13/2020 2:42:37 PM 0.962 0.322 37.3 1,100 5/13/2020 3:12:37 PM 0.867 0.290 28.6 860 5/13/2020 3:42:37 PM 0.903 0.302 31.7 950 5/13/2020 4:12:37 PM 0.802 0.268 23.4 700 5/13/2020 4:42:37 PM 0.89 0.298 30.6 920 5/13/2020 5:12:37 PM 0.879 0.294 29.6 890 5/13/2020 5:42:37 PM 0.884 0.296 30.0 900 5/13/2020 6:12:37 PM 0.878 0.294 29.5 890 5/13/2020 6:42:37 PM 0.892 0.298 30.7 920 5/13/2020 7:12:37 PM 0.913 0.305 32.6 980 5/13/2020 7:42:37 PM 0.873 0.292 29.1 870 5/13/2020 8:12:37 PM 0.899 0.301 31.4 940 5/13/2020 8:42:37 PM 0.867 0.290 28.6 860 5/13/2020 9:12:37 PM 0.924 0.309 33.7 1,000 TR0795 Page 1 of 3 September 2020 TABLE C3 SEEP B-TR2 FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 9:42:37 PM 0.865 0.289 28.4 850 5/13/2020 10:12:37 PM 0.933 0.312 34.5 1,000 5/13/2020 10:42:37 PM 0.857 0.287 27.7 830 5/13/2020 11:12:37 PM 0.882 0.295 29.9 900 5/13/2020 11:42:37 PM 0.84 0.281 26.3 790 5/14/2020 12:12:37 AM 0.824 0.276 25.0 750 5/14/2020 12:42:37 AM 0.852 0.285 27.3 820 5/14/2020 1:12:37 AM 0.873 0.292 29.1 870 5/14/2020 1:42:37 AM 0.854 0.286 27.5 820 5/14/2020 2:12:37 AM 0.811 0.271 24.0 720 5/14/2020 2:42:37 AM 0.861 0.288 28.1 840 5/14/2020 3:12:37 AM 0.812 0.272 24.1 720 5/14/2020 3:42:37 AM 0.857 0.287 27.7 830 5/14/2020 4:12:37 AM 0.847 0.283 26.9 810 5/14/2020 4:42:37 AM 0.849 0.284 27.1 810 5/14/2020 5:12:37 AM 0.868 0.290 28.6 860 5/14/2020 5:42:37 AM 0.859 0.287 27.9 840 5/14/2020 6:12:37 AM 0.919 0.307 33.2 1,000 5/14/2020 6:42:37 AM 0.837 0.280 26.1 780 5/14/2020 7:12:37 AM 0.899 0.301 31.4 940 5/14/2020 7:42:37 AM 0.862 0.288 28.1 840 5/14/2020 8:12:37 AM 0.897 0.300 31.2 940 5/14/2020 8:42:37 AM 0.92 0.308 33.3 1,000 5/14/2020 9:12:37 AM 0.995 0.333 40.7 1,200 5/14/2020 9:42:37 AM 0.933 0.312 34.5 1,000 5/14/2020 10:12:37 AM 0.907 0.303 32.1 960 5/14/2020 10:42:37 AM 0.956 0.320 36.7 1,100 5/14/2020 11:12:37 AM 0.906 0.303 32.0 960 5/14/2020 11:42:37 AM 0.977 0.327 38.9 1,200 5/14/2020 12:12:37 PM 0.92 0.308 33.3 1,000 5/14/2020 12:42:37 PM 0.994 0.333 40.6 1,200 5/14/2020 1:12:37 PM 0.904 0.302 31.8 950 5/14/2020 1:42:37 PM 1.043 0.349 46.0 1,400 5/14/2020 2:12:37 PM 0.938 0.314 35.0 1,000 5/14/2020 2:42:37 PM 0.98 0.328 39.2 1,200 5/14/2020 3:12:37 PM 0.834 0.279 25.8 780 5/14/2020 3:42:37 PM 0.927 0.310 33.9 1,000 5/14/2020 4:12:37 PM 0.845 0.283 26.7 800 5/14/2020 4:42:37 PM 0.916 0.306 32.9 990 5/14/2020 5:12:37 PM 0.883 0.295 29.9 900 5/14/2020 5:42:37 PM 0.9 0.301 31.4 940 5/14/2020 6:12:37 PM 0.87 0.291 28.8 860 5/14/2020 6:42:37 PM 0.888 0.297 30.4 910 TR0795 Page 2 of 3 September 2020 TABLE C3 SEEP B-TR2 FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 7:12:37 PM 0.907 0.303 32.1 960 5/14/2020 7:42:37 PM 0.891 0.298 30.6 920 5/14/2020 8:12:37 PM 0.956 0.320 36.7 1,100 5/14/2020 8:42:37 PM 0.86 0.288 28.0 840 5/14/2020 9:12:37 PM 0.906 0.303 32.0 960 5/14/2020 9:42:37 PM 0.871 0.291 28.9 870 5/14/2020 10:12:37 PM 0.932 0.312 34.4 1,000 5/14/2020 10:42:37 PM 0.859 0.287 27.9 840 5/14/2020 11:12:37 PM 0.883 0.295 29.9 900 5/14/2020 11:42:37 PM 0.871 0.291 28.9 870 Total 89,000 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous recording. TR0795 Page 3 of 3 September 2020 TABLE C4 SEEP B-2 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:19:42 AM 1.26 0.423 72.203 2,170 5/13/2020 12:49:42 AM 1.23 0.412 67.490 2,020 5/13/2020 1:19:42 AM 1.21 0.404 64.084 1,920 5/13/2020 1:49:42 AM 1.25 0.418 70.265 2,110 5/13/2020 2:19:42 AM 1.25 0.419 70.412 2,110 5/13/2020 2:49:42 AM 1.28 0.427 74.174 2,230 5/13/2020 3:19:42 AM 1.30 0.433 77.114 2,310 5/13/2020 3:49:42 AM 1.27 0.424 72.957 2,190 5/13/2020 4:19:42 AM 1.33 0.444 82.064 2,460 5/13/2020 4:49:42 AM 1.29 0.431 76.022 2,280 5/13/2020 5:19:42 AM 1.35 0.453 86.700 2,600 5/13/2020 5:49:42 AM 1.29 0.432 76.489 2,290 5/13/2020 6:19:42 AM 1.35 0.452 86.028 2,580 5/13/2020 6:49:42 AM 1.29 0.431 76.022 2,280 5/13/2020 7:19:42 AM 1.35 0.453 86.532 2,600 5/13/2020 7:49:42 AM 1.28 0.428 74.633 2,240 5/13/2020 8:19:42 AM 1.32 0.442 81.091 2,430 5/13/2020 8:49:42 AM 1.27 0.425 73.412 2,200 5/13/2020 9:19:42 AM 1.29 0.433 76.801 2,300 5/13/2020 9:49:42 AM 1.28 0.430 75.403 2,260 5/13/2020 10:19:42 AM 1.32 0.440 80.446 2,410 5/13/2020 10:49:42 AM 1.29 0.433 76.957 2,310 5/13/2020 11:19:42 AM 1.30 0.434 77.585 2,330 5/13/2020 11:49:42 AM 1.27 0.424 72.655 2,180 5/13/2020 12:19:42 PM 1.20 0.400 62.422 1,870 5/13/2020 12:49:42 PM 1.29 0.432 76.645 2,300 5/13/2020 1:19:42 PM 1.24 0.415 68.796 2,060 5/13/2020 1:49:42 PM 1.31 0.439 79.805 2,390 5/13/2020 2:19:42 PM 1.28 0.427 74.021 2,220 5/13/2020 2:49:42 PM 1.28 0.428 74.480 2,230 5/13/2020 3:19:42 PM 1.23 0.413 67.779 2,030 5/13/2020 3:49:42 PM 1.28 0.427 74.174 2,230 5/13/2020 4:19:42 PM 1.22 0.407 65.208 1,960 5/13/2020 4:49:42 PM 1.32 0.441 80.768 2,420 5/13/2020 5:19:42 PM 1.32 0.443 81.739 2,450 5/13/2020 5:49:42 PM 1.32 0.440 80.446 2,410 5/13/2020 6:19:42 PM 1.30 0.436 78.373 2,350 5/13/2020 6:49:42 PM 1.33 0.444 82.227 2,470 5/13/2020 7:19:42 PM 1.355 0.453 86.869 2,610 5/13/2020 7:49:42 PM 1.32 0.442 81.091 2,430 5/13/2020 8:19:42 PM 1.347 0.451 85.526 2,570 5/13/2020 8:49:42 PM 1.33 0.446 83.044 2,490 5/13/2020 9:19:42 PM 1.38 0.461 90.627 2,720 TR0795 Page 1 of 3 September 2020 TABLE C4 SEEP B-2 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 9:49:42 PM 1.33 0.444 82.064 2,460 5/13/2020 10:19:42 PM 1.41 0.473 96.992 2,910 5/13/2020 10:49:42 PM 1.33 0.444 82.227 2,470 5/13/2020 11:19:42 PM 1.34 0.448 84.362 2,530 5/13/2020 11:49:42 PM 1.29 0.432 76.645 2,300 5/14/2020 12:19:42 AM 1.28 0.429 75.249 2,260 5/14/2020 12:49:42 AM 1.30 0.436 78.531 2,360 5/14/2020 1:19:42 AM 1.32 0.440 80.446 2,410 5/14/2020 1:49:42 AM 1.27 0.425 73.108 2,190 5/14/2020 2:19:42 AM 1.227 0.411 66.915 2,010 5/14/2020 2:49:42 AM 1.27 0.426 73.716 2,210 5/14/2020 3:19:42 AM 1.23 0.413 67.779 2,030 5/14/2020 3:49:42 AM 1.29 0.431 76.022 2,280 5/14/2020 4:19:42 AM 1.29 0.432 76.645 2,300 5/14/2020 4:49:42 AM 1.30 0.434 77.427 2,320 5/14/2020 5:19:42 AM 1.31 0.438 79.326 2,380 5/14/2020 5:49:42 AM 1.31 0.437 79.007 2,370 5/14/2020 6:19:42 AM 1.38 0.462 91.321 2,740 5/14/2020 6:49:42 AM 1.29 0.431 75.867 2,280 5/14/2020 7:19:42 AM 1.35 0.450 85.193 2,560 5/14/2020 7:49:42 AM 1.29 0.431 76.022 2,280 5/14/2020 8:19:42 AM 1.324 0.443 81.739 2,450 5/14/2020 8:49:42 AM 1.34 0.448 84.032 2,520 5/14/2020 9:19:42 AM 1.40 0.467 93.776 2,810 5/14/2020 9:49:42 AM 1.30 0.436 78.215 2,350 5/14/2020 10:19:42 AM 1.27 0.425 73.412 2,200 5/14/2020 10:49:42 AM 1.30 0.434 77.585 2,330 5/14/2020 11:19:42 AM 1.26 0.422 71.753 2,150 5/14/2020 11:49:42 AM 1.31 0.437 78.848 2,370 5/14/2020 12:19:42 PM 1.24 0.416 69.234 2,080 5/14/2020 12:49:42 PM 1.30 0.436 78.215 2,350 5/14/2020 1:19:42 PM 1.202 0.402 63.389 1,900 5/14/2020 1:49:42 PM 1.32 0.441 80.929 2,430 5/14/2020 2:19:42 PM 1.24 0.416 69.088 2,070 5/14/2020 2:49:42 PM 1.322 0.442 81.414 2,440 5/14/2020 3:19:42 PM 1.20 0.402 63.250 1,900 5/14/2020 3:49:42 PM 1.33 0.445 82.880 2,490 5/14/2020 4:19:42 PM 1.27 0.424 72.655 2,180 5/14/2020 4:49:42 PM 1.34 0.449 84.694 2,540 5/14/2020 5:19:42 PM 1.32 0.443 81.739 2,450 5/14/2020 5:49:42 PM 1.34 0.447 83.702 2,510 5/14/2020 6:19:42 PM 1.31 0.438 79.326 2,380 5/14/2020 6:49:42 PM 1.337 0.447 83.866 2,520 TR0795 Page 2 of 3 September 2020 TABLE C4 SEEP B-2 FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 7:19:42 PM 1.36 0.454 87.375 2,620 5/14/2020 7:49:42 PM 1.33 0.446 83.372 2,500 5/14/2020 8:19:42 PM 1.42 0.474 97.716 2,930 5/14/2020 8:49:42 PM 1.32 0.442 81.414 2,440 5/14/2020 9:19:42 PM 1.38 0.460 90.282 2,710 5/14/2020 9:49:42 PM 1.33 0.444 82.390 2,470 5/14/2020 10:19:42 PM 1.41 0.471 96.272 2,890 5/14/2020 10:49:42 PM 1.32 0.443 81.577 2,450 5/14/2020 11:19:42 PM 1.34 0.447 83.537 2,510 5/14/2020 11:49:42 PM 1.32 0.442 81.253 2,440 Total 226,050 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous recording. TR0795 Page 3 of 3 September 2020 TABLE C5 SEEP C FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:05:26 AM 1.10 0.366 49.6 1,490 5/13/2020 12:35:26 AM 1.11 0.372 51.7 1,550 5/13/2020 1:05:26 AM 1.05 0.351 44.4 1,330 5/13/2020 1:35:26 AM 1.05 0.351 44.2 1,330 5/13/2020 2:05:26 AM 1.07 0.359 46.9 1,410 5/13/2020 2:35:26 AM 1.10 0.367 49.8 1,500 5/13/2020 3:05:26 AM 1.12 0.374 52.4 1,570 5/13/2020 3:35:26 AM 1.13 0.378 54.0 1,620 5/13/2020 4:05:26 AM 1.14 0.380 54.5 1,640 5/13/2020 4:35:26 AM 1.20 0.400 62.4 1,870 5/13/2020 5:05:26 AM 1.16 0.389 58.3 1,750 5/13/2020 5:35:26 AM 1.22 0.410 66.5 1,990 5/13/2020 6:05:26 AM 1.15 0.384 56.2 1,700 5/13/2020 6:35:26 AM 1.23 0.413 67.9 2,000 5/13/2020 7:05:26 AM 1.16 0.387 57.2 1,700 5/13/2020 7:35:26 AM 1.22 0.409 66.1 2,000 5/13/2020 8:05:26 AM 1.12 0.374 52.4 1,600 5/13/2020 8:35:26 AM 1.17 0.390 58.5 1,800 5/13/2020 9:05:26 AM 1.12 0.374 52.5 1,600 5/13/2020 9:35:26 AM 1.14 0.380 54.6 1,600 5/13/2020 10:05:26 AM 1.12 0.374 52.3 1,600 5/13/2020 10:35:26 AM 1.11 0.372 51.7 1,500 5/13/2020 11:05:26 AM 1.11 0.370 50.8 1,500 5/13/2020 11:35:26 AM 1.09 0.366 49.4 1,500 5/13/2020 12:05:26 PM 1.04 0.349 43.6 1,300 5/13/2020 12:35:26 PM 0.97 0.323 35.7 1,100 5/13/2020 1:05:26 PM 1.07 0.359 47.0 1,400 5/13/2020 1:35:26 PM 1.02 0.341 41.2 1,200 5/13/2020 2:05:26 PM 1.10 0.367 49.7 1,500 5/13/2020 2:35:26 PM 1.06 0.353 45.0 1,300 5/13/2020 3:05:26 PM 1.05 0.353 44.9 1,300 5/13/2020 3:35:26 PM 0.99 0.331 38.0 1,100 5/13/2020 4:05:26 PM 1.02 0.342 41.3 1,200 5/13/2020 4:35:26 PM 0.97 0.326 36.4 1,100 5/13/2020 5:05:26 PM 1.11 0.370 50.8 1,500 5/13/2020 5:35:26 PM 1.11 0.370 51.0 1,500 5/13/2020 6:05:26 PM 1.10 0.369 50.6 1,500 5/13/2020 6:35:26 PM 1.09 0.366 49.4 1,500 5/13/2020 7:05:26 PM 1.15 0.386 56.8 1,700 5/13/2020 7:35:26 PM 1.19 0.398 61.5 1,800 5/13/2020 8:05:26 PM 1.15 0.384 56.0 1,700 5/13/2020 8:35:26 PM 1.18 0.394 60.1 1,800 TR0795 Page 1 of 3 September 2020 TABLE C5 SEEP C FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 9:05:26 PM 1.17 0.392 59.2 1,800 5/13/2020 9:35:26 PM 1.23 0.410 66.8 2,000 5/13/2020 10:05:26 PM 1.19 0.398 61.5 1,800 5/13/2020 10:35:26 PM 1.25 0.419 70.7 2,100 5/13/2020 11:05:26 PM 1.14 0.381 55.1 1,700 5/13/2020 11:35:26 PM 1.15 0.385 56.7 1,700 5/14/2020 12:05:26 AM 1.08 0.360 47.4 1,400 5/14/2020 12:35:26 AM 1.07 0.359 47.1 1,400 5/14/2020 1:05:26 AM 1.12 0.374 52.3 1,600 5/14/2020 1:35:26 AM 1.11 0.371 51.2 1,500 5/14/2020 2:05:26 AM 1.06 0.356 46.0 1,400 5/14/2020 2:35:26 AM 1.02 0.341 40.9 1,200 5/14/2020 3:05:26 AM 1.06 0.355 45.5 1,400 5/14/2020 3:35:26 AM 1.03 0.343 41.8 1,300 5/14/2020 4:05:26 AM 1.11 0.370 50.8 1,500 5/14/2020 4:35:26 AM 1.11 0.371 51.3 1,500 5/14/2020 5:05:26 AM 1.11 0.372 51.8 1,600 5/14/2020 5:35:26 AM 1.13 0.377 53.4 1,600 5/14/2020 6:05:26 AM 1.16 0.388 57.6 1,700 5/14/2020 6:35:26 AM 1.25 0.417 69.7 2,100 5/14/2020 7:05:26 AM 1.14 0.381 55.1 1,700 5/14/2020 7:35:26 AM 1.20 0.400 62.4 1,900 5/14/2020 8:05:26 AM 1.13 0.376 53.3 1,600 5/14/2020 8:35:26 AM 1.12 0.376 53.0 1,600 5/14/2020 9:05:26 AM 1.18 0.394 60.2 1,800 5/14/2020 9:35:26 AM 1.23 0.411 66.9 2,000 5/14/2020 10:05:26 AM 1.08 0.362 48.1 1,400 5/14/2020 10:35:26 AM 1.05 0.350 44.1 1,300 5/14/2020 11:05:26 AM 1.07 0.357 46.5 1,400 5/14/2020 11:35:26 AM 1.00 0.334 38.9 1,200 5/14/2020 12:05:26 PM 1.07 0.357 46.2 1,400 5/14/2020 12:35:26 PM 1.00 0.335 39.2 1,200 5/14/2020 1:05:26 PM 1.03 0.346 42.7 1,300 5/14/2020 1:35:26 PM 0.95 0.317 34.0 1,000 5/14/2020 2:05:26 PM 1.05 0.351 44.3 1,330 5/14/2020 2:35:26 PM 0.96 0.320 34.7 1,000 5/14/2020 3:05:26 PM 1.02 0.341 40.9 1,200 5/14/2020 3:35:26 PM 0.91 0.303 30.2 910 5/14/2020 4:05:26 PM 1.06 0.355 45.7 1,370 5/14/2020 4:35:26 PM 1.00 0.335 39.3 1,180 5/14/2020 5:05:26 PM 1.10 0.369 50.6 1,520 5/14/2020 5:35:26 PM 1.09 0.363 48.4 1,500 5/14/2020 6:05:26 PM 1.09 0.365 49.1 1,470 5/14/2020 6:35:26 PM 1.09 0.365 49.1 1,470 TR0795 Page 2 of 3 September 2020 TABLE C5 SEEP C FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 7:05:26 PM 1.12 0.375 52.9 1,590 5/14/2020 7:35:26 PM 1.14 0.380 54.6 1,600 5/14/2020 8:05:26 PM 1.18 0.395 60.4 1,810 5/14/2020 8:35:26 PM 1.23 0.413 67.8 2,030 5/14/2020 9:05:26 PM 1.15 0.383 55.9 1,680 5/14/2020 9:35:26 PM 1.20 0.402 63.3 1,900 5/14/2020 10:05:26 PM 1.17 0.392 59.2 1,780 5/14/2020 10:35:26 PM 1.24 0.414 68.5 2,060 5/14/2020 11:05:26 PM 1.13 0.377 53.6 1,610 5/14/2020 11:35:26 PM 1.13 0.379 54.1 1,600 Total 148,360 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous recording. TR0795 Page 3 of 3 September 2020 TABLE C6 SEEP D FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)1 Notes 5/13/2020 12:16:51 AM 1.62 0.54 139 4,162 5/13/2020 12:46:51 AM 1.59 0.53 131 3,943 5/13/2020 1:16:51 AM 1.57 0.52 127 3,807 5/13/2020 1:46:51 AM 1.59 0.53 133 3,995 5/13/2020 2:16:51 AM 1.61 0.54 136 4,081 5/13/2020 2:46:51 AM 1.63 0.54 141 4,216 5/13/2020 3:16:51 AM 1.64 0.55 144 4,305 5/13/2020 3:46:51 AM 1.61 0.54 138 4,128 5/13/2020 4:16:51 AM 1.67 0.56 151 4,523 5/13/2020 4:46:51 AM 1.63 0.54 141 4,223 5/13/2020 5:16:51 AM 1.69 0.57 156 4,681 5/13/2020 5:46:51 AM 1.62 0.54 139 4,182 5/13/2020 6:16:51 AM 1.69 0.57 155 4,659 5/13/2020 6:46:51 AM 1.63 0.55 142 4,250 5/13/2020 7:16:51 AM 1.69 0.57 156 4,667 5/13/2020 7:46:51 AM 1.62 0.54 138 4,149 5/13/2020 8:16:51 AM 1.65 0.55 146 4,368 5/13/2020 8:46:51 AM 1.61 0.54 137 4,115 5/13/2020 9:16:51 AM 1.64 0.55 142 4,271 5/13/2020 9:46:51 AM 1.62 0.54 139 4,182 5/13/2020 10:16:51 AM 1.65 0.55 145 4,347 5/13/2020 10:46:51 AM 1.63 0.55 142 4,264 5/13/2020 11:16:51 AM 1.64 0.55 143 4,292 5/13/2020 11:46:51 AM 1.62 0.54 138 4,149 5/13/2020 12:16:51 PM 1.54 0.51 121 3,643 5/13/2020 12:46:51 PM 1.64 0.55 144 4,312 5/13/2020 1:16:51 PM 1.60 0.53 133 4,002 5/13/2020 1:46:51 PM 1.66 0.55 148 4,431 5/13/2020 2:16:51 PM 1.63 0.54 140 4,203 5/13/2020 2:46:51 PM 1.63 0.54 140 4,210 5/13/2020 3:16:51 PM 1.58 0.53 131 3,930 5/13/2020 3:46:51 PM 1.63 0.54 140 4,203 5/13/2020 4:16:51 PM 1.56 0.52 126 3,788 5/13/2020 4:46:51 PM 1.66 0.56 148 4,445 5/13/2020 5:16:51 PM 1.66 0.56 148 4,445 5/13/2020 5:46:51 PM 1.66 0.55 147 4,424 5/13/2020 6:16:51 PM 1.65 0.55 147 4,396 5/13/2020 6:46:51 PM 1.67 0.56 151 4,516 5/13/2020 7:16:51 PM 1.70 0.57 157 4,725 5/13/2020 7:46:51 PM 1.66 0.56 149 4,459 5/13/2020 8:16:51 PM 1.69 0.57 155 4,659 5/13/2020 8:46:51 PM 1.67 0.56 150 4,502 5/13/2020 9:16:51 PM 1.72 0.58 163 4,880 5/13/2020 9:46:51 PM 1.66 0.56 149 4,466 5/13/2020 10:16:51 PM 1.74 0.58 168 5,038 5/13/2020 10:46:51 PM 1.66 0.56 148 4,438 5/13/2020 11:16:51 PM 1.68 0.56 153 4,580 5/13/2020 11:46:51 PM 1.62 0.54 140 4,196 5/14/2020 12:16:51 AM 1.61 0.54 137 4,115 5/14/2020 12:46:51 AM 1.63 0.55 141 4,237 TR0795 Page 1 of 3 September 2020 TABLE C6 SEEP D FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)1 Notes 5/14/2020 1:16:51 AM 1.64 0.55 142 4,271 5/14/2020 1:46:51 AM 1.61 0.54 137 4,122 5/14/2020 2:16:51 AM 1.57 0.52 128 3,826 5/14/2020 2:46:51 AM 1.61 0.54 136 4,088 5/14/2020 3:16:51 AM 1.57 0.52 127 3,813 5/14/2020 3:46:51 AM 1.62 0.54 139 4,169 5/14/2020 4:16:51 AM 1.62 0.54 138 4,135 5/14/2020 4:46:51 AM 1.63 0.54 141 4,216 5/14/2020 5:16:51 AM 1.64 0.55 143 4,292 5/14/2020 5:46:51 AM 1.64 0.55 143 4,292 5/14/2020 6:16:51 AM 1.71 0.57 160 4,791 5/14/2020 6:46:51 AM 1.62 0.54 139 4,176 5/14/2020 7:16:51 AM 1.68 0.56 152 4,566 5/14/2020 7:46:51 AM 1.63 0.55 141 4,244 5/14/2020 8:16:51 AM 1.65 0.55 146 4,382 5/14/2020 8:46:51 AM 1.65 0.55 147 4,396 5/14/2020 9:16:51 AM 1.72 0.58 163 4,888 5/14/2020 9:46:51 AM 1.62 0.54 140 4,196 5/14/2020 10:16:51 AM 1.60 0.53 134 4,015 5/14/2020 10:46:51 AM 1.63 0.54 141 4,223 5/14/2020 11:16:51 AM 1.58 0.53 130 3,903 5/14/2020 11:46:51 AM 1.64 0.55 144 4,333 5/14/2020 12:16:51 PM 1.58 0.53 129 3,871 5/14/2020 12:46:51 PM 1.64 0.55 143 4,285 5/14/2020 1:16:51 PM 1.53 0.51 120 3,599 5/14/2020 1:46:51 PM 1.64 0.55 144 4,319 5/14/2020 2:16:51 PM 1.56 0.52 125 3,749 5/14/2020 2:46:51 PM 1.64 0.55 142 4,271 5/14/2020 3:16:51 PM 1.52 0.51 118 3,544 5/14/2020 3:46:51 PM 1.65 0.55 146 4,375 5/14/2020 4:16:51 PM 1.59 0.53 131 3,943 5/14/2020 4:46:51 PM 1.65 0.55 145 4,361 5/14/2020 5:16:51 PM 1.64 0.55 143 4,292 5/14/2020 5:46:51 PM 1.66 0.56 148 4,438 5/14/2020 6:16:51 PM 1.63 0.55 141 4,237 5/14/2020 6:46:51 PM 1.65 0.55 146 4,375 5/14/2020 7:16:51 PM 1.66 0.56 149 4,473 5/14/2020 7:46:51 PM 1.66 0.56 148 4,445 5/14/2020 8:16:51 PM 1.74 0.58 167 5,000 5/14/2020 8:46:51 PM 1.65 0.55 146 4,382 5/14/2020 9:16:51 PM 1.70 0.57 158 4,732 Level logger disturbed. Water level is average of the recordings before and after. 5/14/2020 9:46:51 PM 1.66 0.55 148 4,431 5/14/2020 10:16:51 PM 1.73 0.58 164 4,925 TR0795 Page 2 of 3 September 2020 TABLE C6 SEEP D FLUME DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)1 Notes 5/14/2020 10:46:51 PM 1.65 0.55 145 4,361 5/14/2020 11:16:51 PM 1.65 0.55 147 4,396 5/14/2020 11:46:51 PM 1.64 0.55 143 4,278 Total 411,617 Notes: Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals 1 - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous recording. TR0795 Page 3 of 3 September 2020 TABLE C7 OLD OUTFALL FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 12:01:17 AM 2.853 0.95 616 18,500 5/13/2020 12:31:17 AM 2.868 0.96 624 18,700 5/13/2020 1:01:17 AM 2.802 0.94 587 17,600 5/13/2020 1:31:17 AM 2.792 0.93 582 17,400 5/13/2020 2:01:17 AM 2.83 0.95 603 18,100 5/13/2020 2:31:17 AM 2.843 0.95 610 18,300 5/13/2020 3:01:17 AM 2.858 0.96 618 18,600 5/13/2020 3:31:17 AM 2.883 0.96 633 19,000 5/13/2020 4:01:17 AM 2.883 0.96 633 19,000 5/13/2020 4:31:17 AM 2.948 0.99 671 20,100 5/13/2020 5:01:17 AM 2.895 0.97 640 19,200 5/13/2020 5:31:17 AM 2.962 0.99 679 20,400 5/13/2020 6:01:17 AM 2.886 0.97 635 19,000 5/13/2020 6:31:17 AM 2.967 0.99 682 20,500 5/13/2020 7:01:17 AM 2.885 0.97 634 19,000 5/13/2020 7:31:17 AM 2.936 0.98 664 19,900 5/13/2020 8:01:17 AM 2.847 0.95 612 18,400 5/13/2020 8:31:17 AM 2.899 0.97 642 19,300 5/13/2020 9:01:17 AM 2.866 0.96 623 18,700 5/13/2020 9:31:17 AM 2.857 0.96 618 18,500 5/13/2020 10:01:17 AM 2.858 0.96 618 18,600 5/13/2020 10:31:17 AM 2.855 0.96 617 18,500 5/13/2020 11:01:17 AM 2.849 0.95 613 18,400 5/13/2020 11:31:17 AM 2.836 0.95 606 18,200 5/13/2020 12:01:17 PM 2.795 0.94 583 17,500 5/13/2020 12:31:17 PM 2.713 0.91 539 16,200 5/13/2020 1:01:17 PM 2.81 0.94 592 17,700 5/13/2020 1:31:17 PM 2.745 0.92 556 16,700 5/13/2020 2:01:17 PM 2.815 0.94 594 17,800 5/13/2020 2:31:17 PM 2.792 0.93 582 17,400 5/13/2020 3:01:17 PM 2.806 0.94 589 17,700 5/13/2020 3:31:17 PM 2.747 0.92 557 16,700 5/13/2020 4:01:17 PM 2.786 0.93 578 17,300 5/13/2020 4:31:17 PM 2.738 0.92 552 16,600 5/13/2020 5:01:17 PM 2.866 0.96 623 18,700 5/13/2020 5:31:17 PM 2.876 0.96 629 18,900 5/13/2020 6:01:17 PM 2.872 0.96 626 18,800 5/13/2020 6:31:17 PM 2.87 0.96 625 18,800 5/13/2020 7:01:17 PM 2.922 0.98 656 19,700 5/13/2020 7:31:17 PM 2.957 0.99 676 20,300 5/13/2020 8:01:17 PM 2.903 0.97 644 19,300 5/13/2020 8:31:17 PM 2.94 0.98 666 20,000 5/13/2020 9:01:17 PM 2.937 0.98 664 19,900 TR0795 Page 1 of 3 September 2020 TABLE C7 OLD OUTFALL FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/13/2020 9:31:17 PM 2.984 1.00 693 20,800 5/13/2020 10:01:17 PM 2.935 0.98 663 19,900 5/13/2020 10:31:17 PM 2.999 1.00 702 21,100 5/13/2020 11:01:17 PM 2.895 0.97 640 19,200 5/13/2020 11:31:17 PM 2.915 0.98 651 19,500 5/14/2020 12:01:17 AM 2.833 0.95 604 18,100 5/14/2020 12:31:17 AM 2.825 0.95 600 18,000 5/14/2020 1:01:17 AM 2.861 0.96 620 18,600 5/14/2020 1:31:17 AM 2.866 0.96 623 18,700 5/14/2020 2:01:17 AM 2.811 0.94 592 17,800 5/14/2020 2:31:17 AM 2.781 0.93 576 17,300 5/14/2020 3:01:17 AM 2.828 0.95 602 18,000 5/14/2020 3:31:17 AM 2.779 0.93 574 17,200 5/14/2020 4:01:17 AM 2.856 0.96 617 18,500 5/14/2020 4:31:17 AM 2.863 0.96 621 18,600 5/14/2020 5:01:17 AM 2.866 0.96 623 18,700 5/14/2020 5:31:17 AM 2.866 0.96 623 18,700 5/14/2020 6:01:17 AM 2.882 0.96 632 19,000 5/14/2020 6:31:17 AM 2.965 0.99 681 20,400 5/14/2020 7:01:17 AM 2.881 0.96 632 18,900 5/14/2020 7:31:17 AM 2.943 0.98 668 20,000 5/14/2020 8:01:17 AM 2.861 0.96 620 18,600 5/14/2020 8:31:17 AM 2.866 0.96 623 18,700 5/14/2020 9:01:17 AM 2.903 0.97 644 19,300 5/14/2020 9:31:17 AM 2.962 0.99 679 20,400 5/14/2020 10:01:17 AM 2.83 0.95 603 18,100 5/14/2020 10:31:17 AM 2.785 0.93 578 17,300 5/14/2020 11:01:17 AM 2.806 0.94 589 17,700 5/14/2020 11:31:17 AM 2.741 0.92 554 16,600 5/14/2020 12:01:17 PM 2.794 0.93 583 17,500 5/14/2020 12:31:17 PM 2.731 0.91 549 16,500 5/14/2020 1:01:17 PM 2.777 0.93 573 17,200 5/14/2020 1:31:17 PM 2.698 0.90 531 15,900 5/14/2020 2:01:17 PM 2.796 0.94 584 17,500 5/14/2020 2:31:17 PM 2.695 0.90 530 15,900 5/14/2020 3:01:17 PM 2.769 0.93 569 17,100 5/14/2020 3:31:17 PM 2.671 0.89 518 15,500 5/14/2020 4:01:17 PM 2.818 0.94 596 17,900 5/14/2020 4:31:17 PM 2.774 0.93 572 17,200 5/14/2020 5:01:17 PM 2.87 0.96 625 18,800 5/14/2020 5:31:17 PM 2.854 0.95 616 18,500 5/14/2020 6:01:17 PM 2.879 0.96 630 18,900 5/14/2020 6:31:17 PM 2.857 0.96 618 18,500 TR0795 Page 2 of 3 September 2020 TABLE C7 OLD OUTFALL FLUME DATAChemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Water Level (kPa) Water Level (ft) Flow Rate (gpm) Flow Volume (gal)* 5/14/2020 7:01:17 PM 2.9 0.97 643 19,300 5/14/2020 7:31:17 PM 2.914 0.98 651 19,500 5/14/2020 8:01:17 PM 2.954 0.99 675 20,200 5/14/2020 8:31:17 PM 3.018 1.01 714 21,400 5/14/2020 9:01:17 PM 2.926 0.98 658 19,700 5/14/2020 9:31:17 PM 2.984 1.00 693 20,800 5/14/2020 10:01:17 PM 2.951 0.99 673 20,200 5/14/2020 10:31:17 PM 3.016 1.01 712 21,400 5/14/2020 11:01:17 PM 2.891 0.97 637 19,100 5/14/2020 11:31:17 PM 2.9 0.97 643 19,300 Total 1,785,400 Acronyms: ft - feet gpm - gallons per minute gal - gallons kPa - kilopascals * - Flow volumes are calculated as the total volume of flow passing through the flume for the duration of the interval where the interval duration is calculated as the time between the present recording and the previous recording. TR0795 Page 3 of 3 September 2020 TABLE C8 WILLIS CREEK VOLUMETRIC DISCHARGE CALCULATIONS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Distance Along Measured Cross Section Measured Water Column Depth Measured Water Column Depth Calculated Creek Cell Area2 Measured Creek Velocity Calculated Discharge Through Creek Cell Area1 (ft)(in)(ft)(ft2)(ft/s)(ft3/s) West bank 0.00 0.00 0.0 0.00 bottom 5.00 2.00 0.17 0.42 0.18 0.13 middle 5.00 1.00 0.08 0.32 top 5.00 0.00 0.00 0.32 on edge of sandbank 10.00 1.00 0.08 0.24 top 10.00 0.00 0.00 0.28 bottom 15.00 2.00 0.17 1.67 0.50 1.72 middle 15.00 1.00 0.08 1.03 top 15.00 0.00 0.00 0.08 bottom 20.00 6.00 0.50 1.67 1.02 2.10 middle 20.00 3.00 0.25 1.26 top 20.00 0.00 0.00 0.55 bottom 25.00 6.00 0.50 2.50 0.23 3.90 middle 25.00 3.00 0.3 1.56 top 25.00 0.00 0.0 1.43 Associated Measurement Notes 7.85 Location: Chemours Fayetteville 3523 Station: Willis Creek 01 (SW-WC-01)222.29 Date: May 2020 Acronyms - - data not measured or calculated in - inches ft - feet ft2 - square feet ft/s - feet per second ft3/s - cubic feet per second gpm - gallons per minute Notes 2 Measurement cell areas are calculated assuming a trapezoidal geometry based on distances between Measurement points and the measured water column depths. A measurement cell is an areal section from the width of the river channel. Measurement Point Total Volumetric Discharge (ft3/s) (gpm) (L/s) 1 Discharge is calculated as product of creek velocity measured at the mid-depth (feet per second) times the cross sectional area of each measurement cell. TR0795 Page 1 of 1 September 2020 TABLE C9 GEORGIA BRANCH CREEK VOLUMETRIC DISCHARGE CALCULATIONS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Distance Along Measured Cross Section Measured Water Column Depth Measured Water Column Depth Calculated Creek Cell Area2 Measured Creek Velocity Calculated Discharge Through Creek Cell Area1 (ft)(in)(ft)(ft2)(ft/s)(ft3/s) top - sand bank 1 0 0 0 -0 - top 2 12 1 0 0 bottom 3 12 1 1 6 0 5.52 mid 4 24 2 0.2 0.92 top 5 24 2 0 0.99 top 6 36 3 0 0.31 bottom 7 48 4 0.4 2.1 0.65 2.0265 mid 8 48 4 0.2 1.01 top 9 48 4 0 1.04 bottom 10 60 5 0.5 0.45 0.86 0.387 mid 11 60 5 0.25 0.86 top 12 60 5 0 0.96 bottom 13 72 6 0.45 0.475 0.73 0.65075 mid 14 72 6 0.23 1.37 top 15 72 6 0 1.46 bottom 16 84 7 0.4 0.425 1.12 0.53125 mid 17 84 7 0.2 1.25 top 18 84 7 0 1.34 bottom 19 96 8 0.45 0.425 1.22 0.59075 mid 20 96 8 0.23 1.39 top 21 96 8 0 1.48 bottom 22 108 9 0.45 0.45 0.96 0.522 mid 23 108 9 0.23 1.16 top 24 108 9 0 1.36 bottom 25 120 10 0.5 0.475 0.86 0.69825 mid 26 120 10 0.25 1.47 top 27 120 10 0 1.47 bottom 28 132 11 0.45 0.475 0.76 0.52725 mid 29 132 11 0.23 1.11 top 30 132 11 0 1.53 bottom 31 144 12 0.3 0.375 0.55 0.2775 Measurement Point Station TR0795 Page 1 of 2 September 2020 TABLE C9 GEORGIA BRANCH CREEK VOLUMETRIC DISCHARGE CALCULATIONS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Distance Along Measured Cross Section Measured Water Column Depth Measured Water Column Depth Calculated Creek Cell Area2 Measured Creek Velocity Calculated Discharge Through Creek Cell Area1 (ft)(in)(ft)(ft2)(ft/s)(ft3/s) Measurement Point Station mid 32 144 12 0.15 0.74top331441200.77 sand bank 34 151 13 0 0.0875 0 0.06475 11.80 5294 334.03 Total Volumetric Discharge (ft3/s)(gpm) (L/s) TR0795 Associated Measurement Notes Location: Chemours Fayetteville Station: Georgia Branch 01 (SW-GB-01) Date: May 2020 Acronyms - - data not measured or calculated in - inches ft - feet ft2 - square feet ft/s - feet per second ft3/s - cubic feet per second Notes 1 Discharge is calculated as product of creek velocity measured at the mid-depth (feet per second) times the cross sectional area of each measurement cell. 2 Measurement cell areas are calculated assuming a trapezoidal geometry based on distances between Measurement points and the measured water column depths. A measurement cell is an areal section from the width of the river channel. 3 Discharge calculations do not include values for cells where negative flows were measured. Page 2 of 2 September 2020 TABLE C10 OUTFALL 002 FLOW RATE Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Outfall 002 Flow (MGD) Total Daily Volume (gal) Hours of Sample Collection Approximate Total Volume during 24 hour Sample Collection (gal) 5/13/2020 22.161 22,161,000 13.75 12,696,406 5/14/2020 22.607 22,607,000 10.25 9,655,073 24 22,351,479 Notes: Acronyms: gal - gallons MGD - millions of gallons per day 5/13/2020 10:17 am to 5/14/2020 10:17 am Daily flow rates collected from facility Discharge Monitoring Reports. Total flow volume for 24-hour temporal composite sample collected at 10:17 am on 5/14/2020 approximated based on flow rates for 5/13/2020 and 5/14/2020 TR0795 Page 1 of 1 September 2020 TABLE C11 RIVER FLOW RATES Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Pathway/ Location Sample Collection Timepoint Flow Gauging Location1 Travel Time Offset (hr)2 Adjusted Flow Gauging Timepoint Composite Sample 24-Hour Flow Volume (MGD)3 Grab Sample Instantaneous Flow Rate (ft3/s)4 Upstream River Water and Groundwater 5/13/2020 8:20 William O Huske Lock and Dam --5/13/2020 8:20 1,091 -- Tarheel (Composite Sample)5/14/2020 20:50 William O Huske Lock and Dam 9 5/15/2020 5:50 960 -- Tarheel (Grab Sample)5/14/2020 8:55 William O Huske Lock and Dam 9 5/13/2020 23:55 --1,540 Bladen Bluff 5/13/2020 18:15 William O Huske Lock and Dam 6 5/13/2020 12:15 --1,680 Kings Bluff 5/19/2020 9:25 Cape Fear River Lock and Dam #1 --5/19/2020 9:25 --1,670 Notes: Acronyms: ft3/s - cubic feet per second hr - hours MGD - millions of gallons per day 1 - Flow rate measured at USGS gauging station #02105500 located at William O Huske Lock & Dam and USGS gauging station # 02105769 located at Lock and Dam #1 near Kelly, North Carolina 2 - Flow rates measured at William O Huske Lock and Dam were used for mass loading assessments at Tarheel and Bladen Bluff sample locations. Travel times between William O Huske Lock and Dam and the downstream locations were estimated based on the results of a numerical model of the Cape Fear River developed by Geosyntec which developed a regression curve between the USGS reported gage heights at William O Huske Lock and Dam and travel times. 3 - Total flow volume for composite samples is based on measurements taken over 24-hour sample collection period. 4 - Instantaneous flow rate for grab samples is the recorded flow rate at the time of grab sample collection. TR0795 Page 1 of 1 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/12/2020 0:00 1810 12,186,000 1.96 0 5/12/2020 0:15 1800 12,118,000 1.95 0 5/12/2020 0:30 1800 12,118,000 1.95 0 5/12/2020 0:45 1800 12,118,000 1.95 0 5/12/2020 1:00 1800 12,118,000 1.95 0 5/12/2020 1:15 1800 12,118,000 1.95 0 5/12/2020 1:30 1800 12,118,000 1.95 0 5/12/2020 1:45 1800 12,118,000 1.95 0 5/12/2020 2:00 1800 12,118,000 1.95 0 5/12/2020 2:15 1800 12,118,000 1.95 0 5/12/2020 2:30 1800 12,118,000 1.95 0 5/12/2020 2:45 1800 12,118,000 1.95 0 5/12/2020 3:00 1790 12,051,000 1.94 0 5/12/2020 3:15 1790 12,051,000 1.94 0 5/12/2020 3:30 1790 12,051,000 1.94 0 5/12/2020 3:45 1790 12,051,000 1.94 0 5/12/2020 4:00 1790 12,051,000 1.94 0 5/12/2020 4:15 1790 12,051,000 1.94 0 5/12/2020 4:30 1790 12,051,000 1.94 0 5/12/2020 4:45 1790 12,051,000 1.94 0 5/12/2020 5:00 1790 12,051,000 1.94 0 5/12/2020 5:15 1770 11,916,000 1.93 0 5/12/2020 5:30 1790 12,051,000 1.94 0 5/12/2020 5:45 1770 11,916,000 1.93 0 5/12/2020 6:00 1770 11,916,000 1.93 0 5/12/2020 6:15 1770 11,916,000 1.93 0 5/12/2020 6:30 1770 11,916,000 1.93 0 5/12/2020 6:45 1770 11,916,000 1.93 0 5/12/2020 7:00 1770 11,916,000 1.93 0 5/12/2020 7:15 1770 11,916,000 1.93 0 5/12/2020 7:30 1760 11,849,000 1.92 0 5/12/2020 7:45 1760 11,849,000 1.92 0 5/12/2020 8:00 1760 11,849,000 1.92 0 5/12/2020 8:15 1770 11,916,000 1.93 0 5/12/2020 8:30 1770 11,916,000 1.93 0 5/12/2020 8:45 1760 11,849,000 1.92 0 5/12/2020 9:00 1770 11,916,000 1.93 0 5/12/2020 9:15 1770 11,916,000 1.93 0 5/12/2020 9:30 1770 11,916,000 1.93 0 5/12/2020 9:45 1770 11,916,000 1.93 0 5/12/2020 10:00 1790 12,051,000 1.94 0 5/12/2020 10:15 1760 11,849,000 1.92 0 5/12/2020 10:30 1760 11,849,000 1.92 0 5/12/2020 10:45 1800 12,118,000 1.95 0 5/12/2020 11:00 1770 11,916,000 1.93 0 5/12/2020 11:15 1790 12,051,000 1.94 0 5/12/2020 11:30 1790 12,051,000 1.94 0 5/12/2020 11:45 1760 11,849,000 1.92 0 5/12/2020 12:00 1760 11,849,000 1.92 0 5/12/2020 12:15 1790 12,051,000 1.94 0 TR0795 Page 1 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/12/2020 12:30 1770 11,916,000 1.93 0 5/12/2020 12:45 1770 11,916,000 1.93 0 5/12/2020 13:00 1760 11,849,000 1.92 0 5/12/2020 13:15 1770 11,916,000 1.93 0 5/12/2020 13:30 1770 11,916,000 1.93 0 5/12/2020 13:45 1760 11,849,000 1.92 0 5/12/2020 14:00 1760 11,849,000 1.92 0 5/12/2020 14:15 1760 11,849,000 1.92 0 5/12/2020 14:30 1770 11,916,000 1.93 0 5/12/2020 14:45 1760 11,849,000 1.92 0 5/12/2020 15:00 1740 11,714,000 1.91 0 5/12/2020 15:15 1740 11,714,000 1.91 0 5/12/2020 15:30 1730 11,647,000 1.9 0 5/12/2020 15:45 1740 11,714,000 1.91 0 5/12/2020 16:00 1740 11,714,000 1.91 0 5/12/2020 16:15 1740 11,714,000 1.91 0 5/12/2020 16:30 1740 11,714,000 1.91 0 5/12/2020 16:45 1730 11,647,000 1.9 0 5/12/2020 17:00 1730 11,647,000 1.9 0 5/12/2020 17:15 1720 11,580,000 1.89 0 5/12/2020 17:30 1720 11,580,000 1.89 0 5/12/2020 17:45 1720 11,580,000 1.89 0 5/12/2020 18:00 1700 11,445,000 1.88 0 5/12/2020 18:15 1690 11,378,000 1.87 0 5/12/2020 18:30 1700 11,445,000 1.88 0 5/12/2020 18:45 1700 11,445,000 1.88 0 5/12/2020 19:00 1700 11,445,000 1.88 0 5/12/2020 19:15 1700 11,445,000 1.88 0 5/12/2020 19:30 1690 11,378,000 1.87 0 5/12/2020 19:45 1690 11,378,000 1.87 0 5/12/2020 20:00 1690 11,378,000 1.87 0 5/12/2020 20:15 1690 11,378,000 1.87 0 5/12/2020 20:30 1690 11,378,000 1.87 0 5/12/2020 20:45 1690 11,378,000 1.87 0 5/12/2020 21:00 1690 11,378,000 1.87 0 5/12/2020 21:15 1680 11,311,000 1.86 0 5/12/2020 21:30 1690 11,378,000 1.87 0 5/12/2020 21:45 1680 11,311,000 1.86 0 5/12/2020 22:00 1680 11,311,000 1.86 0 5/12/2020 22:15 1680 11,311,000 1.86 0 5/12/2020 22:30 1660 11,176,000 1.85 0 5/12/2020 22:45 1660 11,176,000 1.85 0 5/12/2020 23:00 1660 11,176,000 1.85 0 5/12/2020 23:15 1660 11,176,000 1.85 0 5/12/2020 23:30 1660 11,176,000 1.85 0 5/12/2020 23:45 1660 11,176,000 1.85 0 5/13/2020 0:00 1660 11,176,000 1.85 0 5/13/2020 0:15 1660 11,176,000 1.85 0 5/13/2020 0:30 1660 11,176,000 1.85 0 5/13/2020 0:45 1660 11,176,000 1.85 0 TR0795 Page 2 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/13/2020 1:00 1660 11,176,000 1.85 0 5/13/2020 1:15 1660 11,176,000 1.85 0 5/13/2020 1:30 1660 11,176,000 1.85 0 5/13/2020 1:45 1660 11,176,000 1.85 0 5/13/2020 2:00 1660 11,176,000 1.85 0 5/13/2020 2:15 1650 11,109,000 1.84 0 5/13/2020 2:30 1650 11,109,000 1.84 0 5/13/2020 2:45 1660 11,176,000 1.85 0 5/13/2020 3:00 1660 11,176,000 1.85 0 5/13/2020 3:15 1660 11,176,000 1.85 0 5/13/2020 3:30 1660 11,176,000 1.85 0 5/13/2020 3:45 1660 11,176,000 1.85 0 5/13/2020 4:00 1660 11,176,000 1.85 0 5/13/2020 4:15 1660 11,176,000 1.85 0 5/13/2020 4:30 1660 11,176,000 1.85 0 5/13/2020 4:45 1660 11,176,000 1.85 0 5/13/2020 5:00 1660 11,176,000 1.85 0 5/13/2020 5:15 1660 11,176,000 1.85 0 5/13/2020 5:30 1660 11,176,000 1.85 0 5/13/2020 5:45 1660 11,176,000 1.85 0 5/13/2020 6:00 1660 11,176,000 1.85 0 5/13/2020 6:15 1680 11,311,000 1.86 0 5/13/2020 6:30 1680 11,311,000 1.86 0 5/13/2020 6:45 1660 11,176,000 1.85 0 5/13/2020 7:00 1680 11,311,000 1.86 0 5/13/2020 7:15 1660 11,176,000 1.85 0 5/13/2020 7:30 1660 11,176,000 1.85 0 5/13/2020 7:45 1660 11,176,000 1.85 0 5/13/2020 8:00 1680 11,311,000 1.86 0 5/13/2020 8:15 1680 11,311,000 1.86 0 5/13/2020 8:30 1660 11,176,000 1.85 0 5/13/2020 8:45 1660 11,176,000 1.85 0 5/13/2020 9:00 1680 11,311,000 1.86 0 5/13/2020 9:15 1680 11,311,000 1.86 0 5/13/2020 9:30 1680 11,311,000 1.86 0 5/13/2020 9:45 1680 11,311,000 1.86 0 5/13/2020 10:00 1680 11,311,000 1.86 0 5/13/2020 10:15 1680 11,311,000 1.86 0 5/13/2020 10:30 1680 11,311,000 1.86 0 5/13/2020 10:45 1680 11,311,000 1.86 0 5/13/2020 11:00 1680 11,311,000 1.86 0 5/13/2020 11:15 1690 11,378,000 1.87 0 5/13/2020 11:30 1680 11,311,000 1.86 0 5/13/2020 11:45 1680 11,311,000 1.86 0 5/13/2020 12:00 1680 11,311,000 1.86 0 5/13/2020 12:15 1680 11,311,000 1.86 0 5/13/2020 12:30 1680 11,311,000 1.86 0 5/13/2020 12:45 1680 11,311,000 1.86 0 5/13/2020 13:00 1680 11,311,000 1.86 0 5/13/2020 13:15 1660 11,176,000 1.85 0 TR0795 Page 3 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/13/2020 13:30 1660 11,176,000 1.85 0 5/13/2020 13:45 1680 11,311,000 1.86 0 5/13/2020 14:00 1680 11,311,000 1.86 0 5/13/2020 14:15 1660 11,176,000 1.85 0 5/13/2020 14:30 1680 11,311,000 1.86 0 5/13/2020 14:45 1660 11,176,000 1.85 0 5/13/2020 15:00 1660 11,176,000 1.85 0 5/13/2020 15:15 1660 11,176,000 1.85 0 5/13/2020 15:30 1660 11,176,000 1.85 0 5/13/2020 15:45 1650 11,109,000 1.84 0 5/13/2020 16:00 1650 11,109,000 1.84 0 5/13/2020 16:15 1660 11,176,000 1.85 0 5/13/2020 16:30 1650 11,109,000 1.84 0 5/13/2020 16:45 1650 11,109,000 1.84 0 5/13/2020 17:00 1650 11,109,000 1.84 0 5/13/2020 17:15 1640 11,041,000 1.83 0 5/13/2020 17:30 1620 10,907,000 1.82 0 5/13/2020 17:45 1620 10,907,000 1.82 0 5/13/2020 18:00 1620 10,907,000 1.82 0 5/13/2020 18:15 1620 10,907,000 1.82 0 5/13/2020 18:30 1610 10,839,000 1.81 0 5/13/2020 18:45 1610 10,839,000 1.81 0 5/13/2020 19:00 1600 10,772,000 1.8 0 5/13/2020 19:15 1600 10,772,000 1.8 0 5/13/2020 19:30 1600 10,772,000 1.8 0 5/13/2020 19:45 1580 10,637,000 1.79 0 5/13/2020 20:00 1580 10,637,000 1.79 0 5/13/2020 20:15 1580 10,637,000 1.79 0 5/13/2020 20:30 1580 10,637,000 1.79 0 5/13/2020 20:45 1570 10,570,000 1.78 0 5/13/2020 21:00 1570 10,570,000 1.78 0 5/13/2020 21:15 1560 10,503,000 1.77 0 5/13/2020 21:30 1560 10,503,000 1.77 0 5/13/2020 21:45 1540 10,368,000 1.76 0 5/13/2020 22:00 1540 10,368,000 1.76 0 5/13/2020 22:15 1540 10,368,000 1.76 0 5/13/2020 22:30 1530 10,301,000 1.75 0 5/13/2020 22:45 1540 10,368,000 1.76 0 5/13/2020 23:00 1530 10,301,000 1.75 0 5/13/2020 23:15 1530 10,301,000 1.75 0 5/13/2020 23:30 1530 10,301,000 1.75 0 5/13/2020 23:45 1520 10,233,000 1.74 0 5/14/2020 0:00 1520 10,233,000 1.74 0 5/14/2020 0:15 1510 10,166,000 1.73 0 5/14/2020 0:30 1510 10,166,000 1.73 0 5/14/2020 0:45 1510 10,166,000 1.73 0 5/14/2020 1:00 1510 10,166,000 1.73 0 5/14/2020 1:15 1510 10,166,000 1.73 0 5/14/2020 1:30 1490 10,031,000 1.72 0 5/14/2020 1:45 1490 10,031,000 1.72 0 TR0795 Page 4 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/14/2020 2:00 1490 10,031,000 1.72 0 5/14/2020 2:15 1480 9,964,000 1.71 0 5/14/2020 2:30 1480 9,964,000 1.71 0 5/14/2020 2:45 1480 9,964,000 1.71 0 5/14/2020 3:00 1480 9,964,000 1.71 0 5/14/2020 3:15 1480 9,964,000 1.71 0 5/14/2020 3:30 1480 9,964,000 1.71 0 5/14/2020 3:45 1470 9,896,700 1.7 0 5/14/2020 4:00 1470 9,896,700 1.7 0 5/14/2020 4:15 1470 9,896,700 1.7 0 5/14/2020 4:30 1470 9,896,700 1.7 0 5/14/2020 4:45 1460 9,829,400 1.69 0 5/14/2020 5:00 1460 9,829,400 1.69 0 5/14/2020 5:15 1460 9,829,400 1.69 0 5/14/2020 5:30 1460 9,829,400 1.69 0 5/14/2020 5:45 1440 9,694,700 1.68 0 5/14/2020 6:00 1440 9,694,700 1.68 0 5/14/2020 6:15 1440 9,694,700 1.68 0 5/14/2020 6:30 1440 9,694,700 1.68 0 5/14/2020 6:45 1440 9,694,700 1.68 0 5/14/2020 7:00 1440 9,694,700 1.68 0 5/14/2020 7:15 1430 9,627,400 1.67 0 5/14/2020 7:30 1430 9,627,400 1.67 0 5/14/2020 7:45 1430 9,627,400 1.67 0 5/14/2020 8:00 1430 9,627,400 1.67 0 5/14/2020 8:15 1430 9,627,400 1.67 0 5/14/2020 8:30 1420 9,560,100 1.66 0 5/14/2020 8:45 1420 9,560,100 1.66 0 5/14/2020 9:00 1420 9,560,100 1.66 0 5/14/2020 9:15 1430 9,627,400 1.67 0 5/14/2020 9:30 1420 9,560,100 1.66 0 5/14/2020 9:45 1420 9,560,100 1.66 0 5/14/2020 10:00 1420 9,560,100 1.66 0 5/14/2020 10:15 1430 9,627,400 1.67 0 5/14/2020 10:30 1420 9,560,100 1.66 0 5/14/2020 10:45 1420 9,560,100 1.66 0 5/14/2020 11:00 1420 9,560,100 1.66 0 5/14/2020 11:15 1420 9,560,100 1.66 0 5/14/2020 11:30 1410 9,492,800 1.65 0 5/14/2020 11:45 1410 9,492,800 1.65 0 5/14/2020 12:00 1410 9,492,800 1.65 0 5/14/2020 12:15 1410 9,492,800 1.65 0 5/14/2020 12:30 1390 9,358,100 1.64 0 5/14/2020 12:45 1390 9,358,100 1.64 0 5/14/2020 13:00 1390 9,358,100 1.64 0 5/14/2020 13:15 1390 9,358,100 1.64 0 5/14/2020 13:30 1380 9,290,800 1.63 0 5/14/2020 13:45 1380 9,290,800 1.63 0 5/14/2020 14:00 1390 9,358,100 1.64 0 5/14/2020 14:15 1380 9,290,800 1.63 0 TR0795 Page 5 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/14/2020 14:30 1390 9,358,100 1.64 0 5/14/2020 14:45 1390 9,358,100 1.64 0 5/14/2020 15:00 1390 9,358,100 1.64 0 5/14/2020 15:15 1380 9,290,800 1.63 0 5/14/2020 15:30 1380 9,290,800 1.63 0 5/14/2020 15:45 1390 9,358,100 1.64 0 5/14/2020 16:00 1380 9,290,800 1.63 0 5/14/2020 16:15 1390 9,358,100 1.64 0 5/14/2020 16:30 1380 9,290,800 1.63 0 5/14/2020 16:45 1380 9,290,800 1.63 0 5/14/2020 17:00 1380 9,290,800 1.63 0 5/14/2020 17:15 1380 9,290,800 1.63 0 5/14/2020 17:30 1380 9,290,800 1.63 0 5/14/2020 17:45 1380 9,290,800 1.63 0 5/14/2020 18:00 1380 9,290,800 1.63 0 5/14/2020 18:15 1380 9,290,800 1.63 0 5/14/2020 18:30 1370 9,223,500 1.62 0 5/14/2020 18:45 1380 9,290,800 1.63 0 5/14/2020 19:00 1370 9,223,500 1.62 0 5/14/2020 19:15 1370 9,223,500 1.62 0 5/14/2020 19:30 1360 9,156,100 1.61 0 5/14/2020 19:45 1350 9,088,800 1.6 0 5/14/2020 20:00 1360 9,156,100 1.61 0 5/14/2020 20:15 1360 9,156,100 1.61 0 5/14/2020 20:30 1350 9,088,800 1.6 0 5/14/2020 20:45 1350 9,088,800 1.6 0 5/14/2020 21:00 1350 9,088,800 1.6 0 5/14/2020 21:15 1350 9,088,800 1.6 0 5/14/2020 21:30 1350 9,088,800 1.6 0 5/14/2020 21:45 1330 8,954,200 1.59 0 5/14/2020 22:00 1360 9,156,100 1.61 0 5/14/2020 22:15 1350 9,088,800 1.6 0 5/14/2020 22:30 1350 9,088,800 1.6 0 5/14/2020 22:45 1350 9,088,800 1.6 0 5/14/2020 23:00 1350 9,088,800 1.6 0 5/14/2020 23:15 1350 9,088,800 1.6 0 5/14/2020 23:30 1350 9,088,800 1.6 0 5/14/2020 23:45 1350 9,088,800 1.6 0 5/15/2020 0:00 1350 9,088,800 1.6 0 5/15/2020 0:15 1350 9,088,800 1.6 0 5/15/2020 0:30 1350 9,088,800 1.6 0 5/15/2020 0:45 1350 9,088,800 1.6 0 5/15/2020 1:00 1350 9,088,800 1.6 0 5/15/2020 1:15 1350 9,088,800 1.6 0 5/15/2020 1:30 1330 8,954,200 1.59 0 5/15/2020 1:45 1350 9,088,800 1.6 0 5/15/2020 2:00 1330 8,954,200 1.59 0 5/15/2020 2:15 1330 8,954,200 1.59 0 5/15/2020 2:30 1330 8,954,200 1.59 0 5/15/2020 2:45 1330 8,954,200 1.59 0 TR0795 Page 6 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/15/2020 3:00 1330 8,954,200 1.59 0 5/15/2020 3:15 1330 8,954,200 1.59 0 5/15/2020 3:30 1320 8,886,800 1.58 0 5/15/2020 3:45 1320 8,886,800 1.58 0 5/15/2020 4:00 1320 8,886,800 1.58 0 5/15/2020 4:15 1320 8,886,800 1.58 0 5/15/2020 4:30 1320 8,886,800 1.58 0 5/15/2020 4:45 1320 8,886,800 1.58 0 5/15/2020 5:00 1310 8,819,500 1.57 0 5/15/2020 5:15 1320 8,886,800 1.58 0 5/15/2020 5:30 1310 8,819,500 1.57 0 5/15/2020 5:45 1310 8,819,500 1.57 0 5/15/2020 6:00 1320 8,886,800 1.58 0 5/15/2020 6:15 1310 8,819,500 1.57 0 5/15/2020 6:30 1310 8,819,500 1.57 0 5/15/2020 6:45 1310 8,819,500 1.57 0 5/15/2020 7:00 1310 8,819,500 1.57 0 5/15/2020 7:15 1310 8,819,500 1.57 0 5/15/2020 7:30 1310 8,819,500 1.57 0 5/15/2020 7:45 1310 8,819,500 1.57 0 5/15/2020 8:00 1300 8,752,200 1.56 0 5/15/2020 8:15 1300 8,752,200 1.56 0 5/15/2020 8:30 1310 8,819,500 1.57 0 5/15/2020 8:45 1310 8,819,500 1.57 0 5/15/2020 9:00 1310 8,819,500 1.57 0 5/15/2020 9:15 1310 8,819,500 1.57 0 5/15/2020 9:30 1310 8,819,500 1.57 0 5/15/2020 9:45 1300 8,752,200 1.56 0 5/15/2020 10:00 1300 8,752,200 1.56 0 5/15/2020 10:15 1290 8,684,900 1.55 0 5/15/2020 10:30 1300 8,752,200 1.56 0 5/15/2020 10:45 1300 8,752,200 1.56 0 5/15/2020 11:00 1300 8,752,200 1.56 0 5/15/2020 11:15 1300 8,752,200 1.56 0 5/15/2020 11:30 1300 8,752,200 1.56 0 5/15/2020 11:45 1300 8,752,200 1.56 0 5/15/2020 12:00 1290 8,684,900 1.55 0 5/15/2020 12:15 1300 8,752,200 1.56 0 5/15/2020 12:30 1300 8,752,200 1.56 0 5/15/2020 12:45 1300 8,752,200 1.56 0 5/15/2020 13:00 1300 8,752,200 1.56 0 5/15/2020 13:15 1300 8,752,200 1.56 0 5/15/2020 13:30 1300 8,752,200 1.56 0 5/15/2020 13:45 1300 8,752,200 1.56 0 5/15/2020 14:00 1300 8,752,200 1.56 0 5/15/2020 14:15 1300 8,752,200 1.56 0 5/15/2020 14:30 1290 8,684,900 1.55 0 5/15/2020 14:45 1300 8,752,200 1.56 0 5/15/2020 15:00 1290 8,684,900 1.55 0 5/15/2020 15:15 1290 8,684,900 1.55 0 TR0795 Page 7 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/15/2020 15:30 1290 8,684,900 1.55 0 5/15/2020 15:45 1290 8,684,900 1.55 0 5/15/2020 16:00 1270 8,550,200 1.54 0 5/15/2020 16:15 1290 8,684,900 1.55 0 5/15/2020 16:30 1290 8,684,900 1.55 0 5/15/2020 16:45 1290 8,684,900 1.55 0 5/15/2020 17:00 1300 8,752,200 1.56 0 5/15/2020 17:15 1300 8,752,200 1.56 0 5/15/2020 17:30 1290 8,684,900 1.55 0 5/15/2020 17:45 1300 8,752,200 1.56 0 5/15/2020 18:00 1300 8,752,200 1.56 0 5/15/2020 18:15 1300 8,752,200 1.56 0 5/15/2020 18:30 1310 8,819,500 1.57 0 5/15/2020 18:45 1310 8,819,500 1.57 0 5/15/2020 19:00 1310 8,819,500 1.57 0 5/15/2020 19:15 1310 8,819,500 1.57 0 5/15/2020 19:30 1310 8,819,500 1.57 0 5/15/2020 19:45 1310 8,819,500 1.57 0 5/15/2020 20:00 1310 8,819,500 1.57 0 5/15/2020 20:15 1310 8,819,500 1.57 0 5/15/2020 20:30 1310 8,819,500 1.57 0 5/15/2020 20:45 1310 8,819,500 1.57 0 5/15/2020 21:00 1310 8,819,500 1.57 0 5/15/2020 21:15 1310 8,819,500 1.57 0 5/15/2020 21:30 1300 8,752,200 1.56 0 5/15/2020 21:45 1300 8,752,200 1.56 0 5/15/2020 22:00 1300 8,752,200 1.56 0 5/15/2020 22:15 1300 8,752,200 1.56 0 5/15/2020 22:30 1300 8,752,200 1.56 0 5/15/2020 22:45 1300 8,752,200 1.56 0 5/15/2020 23:00 1300 8,752,200 1.56 0 5/15/2020 23:15 1300 8,752,200 1.56 0 5/15/2020 23:30 1290 8,684,900 1.55 0 5/15/2020 23:45 1310 8,819,500 1.57 0 5/16/2020 0:00 1300 8,752,200 1.56 0 5/16/2020 0:15 1300 8,752,200 1.56 0 5/16/2020 0:30 1300 8,752,200 1.56 0 5/16/2020 0:45 1300 8,752,200 1.56 0 5/16/2020 1:00 1300 8,752,200 1.56 0 5/16/2020 1:15 1300 8,752,200 1.56 0 5/16/2020 1:30 1300 8,752,200 1.56 0 5/16/2020 1:45 1300 8,752,200 1.56 0 5/16/2020 2:00 1300 8,752,200 1.56 0 5/16/2020 2:15 1290 8,684,900 1.55 0 5/16/2020 2:30 1290 8,684,900 1.55 0 5/16/2020 2:45 1300 8,752,200 1.56 0 5/16/2020 3:00 1300 8,752,200 1.56 0 5/16/2020 3:15 1290 8,684,900 1.55 0 5/16/2020 3:30 1290 8,684,900 1.55 0 5/16/2020 3:45 1270 8,550,200 1.54 0 TR0795 Page 8 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/16/2020 4:00 1290 8,684,900 1.55 0 5/16/2020 4:15 1290 8,684,900 1.55 0 5/16/2020 4:30 1290 8,684,900 1.55 0 5/16/2020 4:45 1270 8,550,200 1.54 0 5/16/2020 5:00 1270 8,550,200 1.54 0 5/16/2020 5:15 1270 8,550,200 1.54 0 5/16/2020 5:30 1270 8,550,200 1.54 0 5/16/2020 5:45 1270 8,550,200 1.54 0 5/16/2020 6:00 1270 8,550,200 1.54 0 5/16/2020 6:15 1270 8,550,200 1.54 0 5/16/2020 6:30 1290 8,684,900 1.55 0 5/16/2020 6:45 1270 8,550,200 1.54 0 5/16/2020 7:00 1270 8,550,200 1.54 0 5/16/2020 7:15 1260 8,482,900 1.53 0 5/16/2020 7:30 1270 8,550,200 1.54 0 5/16/2020 7:45 1260 8,482,900 1.53 0 5/16/2020 8:00 1260 8,482,900 1.53 0 5/16/2020 8:15 1260 8,482,900 1.53 0 5/16/2020 8:30 1260 8,482,900 1.53 0 5/16/2020 8:45 1260 8,482,900 1.53 0 5/16/2020 9:00 1270 8,550,200 1.54 0 5/16/2020 9:15 1260 8,482,900 1.53 0 5/16/2020 9:30 1270 8,550,200 1.54 0 5/16/2020 9:45 1270 8,550,200 1.54 0 5/16/2020 10:00 1270 8,550,200 1.54 0 5/16/2020 10:15 1260 8,482,900 1.53 0 5/16/2020 10:30 1270 8,550,200 1.54 0 5/16/2020 10:45 1270 8,550,200 1.54 0 5/16/2020 11:00 1290 8,684,900 1.55 0 5/16/2020 11:15 1270 8,550,200 1.54 0 5/16/2020 11:30 1290 8,684,900 1.55 0 5/16/2020 11:45 1270 8,550,200 1.54 0 5/16/2020 12:00 1290 8,684,900 1.55 0 5/16/2020 12:15 1290 8,684,900 1.55 0 5/16/2020 12:30 1290 8,684,900 1.55 0 5/16/2020 12:45 1290 8,684,900 1.55 0 5/16/2020 13:00 1290 8,684,900 1.55 0 5/16/2020 13:15 1290 8,684,900 1.55 0 5/16/2020 13:30 1270 8,550,200 1.54 0 5/16/2020 13:45 1290 8,684,900 1.55 0 5/16/2020 14:00 1290 8,684,900 1.55 0 5/16/2020 14:15 1290 8,684,900 1.55 0 5/16/2020 14:30 1290 8,684,900 1.55 0 5/16/2020 14:45 1290 8,684,900 1.55 0 5/16/2020 15:00 1290 8,684,900 1.55 0 5/16/2020 15:15 1290 8,684,900 1.55 0 5/16/2020 15:30 1300 8,752,200 1.56 0 5/16/2020 15:45 1290 8,684,900 1.55 0 5/16/2020 16:00 1290 8,684,900 1.55 0 5/16/2020 16:15 1290 8,684,900 1.55 0 TR0795 Page 9 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/16/2020 16:30 1270 8,550,200 1.54 0 5/16/2020 16:45 1290 8,684,900 1.55 0 5/16/2020 17:00 1290 8,684,900 1.55 0 5/16/2020 17:15 1290 8,684,900 1.55 0 5/16/2020 17:30 1270 8,550,200 1.54 0 5/16/2020 17:45 1290 8,684,900 1.55 0 5/16/2020 18:00 1290 8,684,900 1.55 0 5/16/2020 18:15 1290 8,684,900 1.55 0 5/16/2020 18:30 1270 8,550,200 1.54 0 5/16/2020 18:45 1270 8,550,200 1.54 0 5/16/2020 19:00 1290 8,684,900 1.55 0 5/16/2020 19:15 1270 8,550,200 1.54 0 5/16/2020 19:30 1290 8,684,900 1.55 0 5/16/2020 19:45 1270 8,550,200 1.54 0 5/16/2020 20:00 1270 8,550,200 1.54 0 5/16/2020 20:15 1270 8,550,200 1.54 0 5/16/2020 20:30 1260 8,482,900 1.53 0 5/16/2020 20:45 1270 8,550,200 1.54 0 5/16/2020 21:00 1260 8,482,900 1.53 0 5/16/2020 21:15 1260 8,482,900 1.53 0 5/16/2020 21:30 1260 8,482,900 1.53 0 5/16/2020 21:45 1260 8,482,900 1.53 0 5/16/2020 22:00 1260 8,482,900 1.53 0 5/16/2020 22:15 1250 8,415,600 1.52 0 5/16/2020 22:30 1250 8,415,600 1.52 0 5/16/2020 22:45 1250 8,415,600 1.52 0 5/16/2020 23:00 1250 8,415,600 1.52 0 5/16/2020 23:15 1250 8,415,600 1.52 0 5/16/2020 23:30 1250 8,415,600 1.52 0 5/16/2020 23:45 1250 8,415,600 1.52 0 5/17/2020 0:00 1250 8,415,600 1.52 0 5/17/2020 0:15 1250 8,415,600 1.52 0 5/17/2020 0:30 1250 8,415,600 1.52 0 5/17/2020 0:45 1250 8,415,600 1.52 0 5/17/2020 1:00 1250 8,415,600 1.52 0 5/17/2020 1:15 1240 8,348,200 1.51 0 5/17/2020 1:30 1240 8,348,200 1.51 0 5/17/2020 1:45 1250 8,415,600 1.52 0 5/17/2020 2:00 1240 8,348,200 1.51 0 5/17/2020 2:15 1240 8,348,200 1.51 0 5/17/2020 2:30 1240 8,348,200 1.51 0 5/17/2020 2:45 1240 8,348,200 1.51 0 5/17/2020 3:00 1250 8,415,600 1.52 0 5/17/2020 3:15 1240 8,348,200 1.51 0 5/17/2020 3:30 1240 8,348,200 1.51 0 5/17/2020 3:45 1240 8,348,200 1.51 0 5/17/2020 4:00 1240 8,348,200 1.51 0 5/17/2020 4:15 1240 8,348,200 1.51 0 5/17/2020 4:30 1240 8,348,200 1.51 0 5/17/2020 4:45 1230 8,280,900 1.5 0 TR0795 Page 10 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/17/2020 5:00 1230 8,280,900 1.5 0 5/17/2020 5:15 1230 8,280,900 1.5 0 5/17/2020 5:30 1230 8,280,900 1.5 0 5/17/2020 5:45 1230 8,280,900 1.5 0 5/17/2020 6:00 1230 8,280,900 1.5 0 5/17/2020 6:15 1230 8,280,900 1.5 0 5/17/2020 6:30 1230 8,280,900 1.5 0 5/17/2020 6:45 1230 8,280,900 1.5 0 5/17/2020 7:00 1230 8,280,900 1.5 0 5/17/2020 7:15 1230 8,280,900 1.5 0 5/17/2020 7:30 1230 8,280,900 1.5 0 5/17/2020 7:45 1230 8,280,900 1.5 0 5/17/2020 8:00 1230 8,280,900 1.5 0 5/17/2020 8:15 1230 8,280,900 1.5 0 5/17/2020 8:30 1230 8,280,900 1.5 0 5/17/2020 8:45 1230 8,280,900 1.5 0 5/17/2020 9:00 1230 8,280,900 1.5 0 5/17/2020 9:15 1230 8,280,900 1.5 0 5/17/2020 9:30 1230 8,280,900 1.5 0 5/17/2020 9:45 1230 8,280,900 1.5 0 5/17/2020 10:00 1230 8,280,900 1.5 0 5/17/2020 10:15 1240 8,348,200 1.51 0 5/17/2020 10:30 1230 8,280,900 1.5 0 5/17/2020 10:45 1230 8,280,900 1.5 0 5/17/2020 11:00 1230 8,280,900 1.5 0 5/17/2020 11:15 1230 8,280,900 1.5 0 5/17/2020 11:30 1230 8,280,900 1.5 0 5/17/2020 11:45 1230 8,280,900 1.5 0 5/17/2020 12:00 1230 8,280,900 1.5 0 5/17/2020 12:15 1230 8,280,900 1.5 0 5/17/2020 12:30 1220 8,213,600 1.49 0 5/17/2020 12:45 1230 8,280,900 1.5 0 5/17/2020 13:00 1230 8,280,900 1.5 0 5/17/2020 13:15 1230 8,280,900 1.5 0 5/17/2020 13:30 1220 8,213,600 1.49 0 5/17/2020 13:45 1230 8,280,900 1.5 0 5/17/2020 14:00 1230 8,280,900 1.5 0 5/17/2020 14:15 1230 8,280,900 1.5 0 5/17/2020 14:30 1240 8,348,200 1.51 0 5/17/2020 14:45 1240 8,348,200 1.51 0 5/17/2020 15:00 1230 8,280,900 1.5 0 5/17/2020 15:15 1230 8,280,900 1.5 0 5/17/2020 15:30 1240 8,348,200 1.51 0 5/17/2020 15:45 1220 8,213,600 1.49 0 5/17/2020 16:00 1240 8,348,200 1.51 0 5/17/2020 16:15 1230 8,280,900 1.5 0 5/17/2020 16:30 1240 8,348,200 1.51 0 5/17/2020 16:45 1230 8,280,900 1.5 0 5/17/2020 17:00 1220 8,213,600 1.49 0 5/17/2020 17:15 1220 8,213,600 1.49 0 TR0795 Page 11 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/17/2020 17:30 1230 8,280,900 1.5 0 5/17/2020 17:45 1220 8,213,600 1.49 0 5/17/2020 18:00 1230 8,280,900 1.5 0 5/17/2020 18:15 1220 8,213,600 1.49 0 5/17/2020 18:30 1210 8,146,300 1.48 0 5/17/2020 18:45 1220 8,213,600 1.49 0 5/17/2020 19:00 1210 8,146,300 1.48 0 5/17/2020 19:15 1220 8,213,600 1.49 0 5/17/2020 19:30 1220 8,213,600 1.49 0 5/17/2020 19:45 1220 8,213,600 1.49 0 5/17/2020 20:00 1210 8,146,300 1.48 0 5/17/2020 20:15 1210 8,146,300 1.48 0 5/17/2020 20:30 1220 8,213,600 1.49 0 5/17/2020 20:45 1220 8,213,600 1.49 0 5/17/2020 21:00 1220 8,213,600 1.49 0 5/17/2020 21:15 1220 8,213,600 1.49 0 5/17/2020 21:30 1210 8,146,300 1.48 0 5/17/2020 21:45 1210 8,146,300 1.48 0 5/17/2020 22:00 1210 8,146,300 1.48 0 5/17/2020 22:15 1210 8,146,300 1.48 0 5/17/2020 22:30 1210 8,146,300 1.48 0 5/17/2020 22:45 1210 8,146,300 1.48 0 5/17/2020 23:00 1210 8,146,300 1.48 0 5/17/2020 23:15 1210 8,146,300 1.48 0 5/17/2020 23:30 1210 8,146,300 1.48 0 5/17/2020 23:45 1210 8,146,300 1.48 0 5/18/2020 0:00 1210 8,146,300 1.48 0 5/18/2020 0:15 1210 8,146,300 1.48 0 5/18/2020 0:30 1210 8,146,300 1.48 0 5/18/2020 0:45 1210 8,146,300 1.48 0 5/18/2020 1:00 1210 8,146,300 1.48 0 5/18/2020 1:15 1210 8,146,300 1.48 0 5/18/2020 1:30 1210 8,146,300 1.48 0 5/18/2020 1:45 1210 8,146,300 1.48 0 5/18/2020 2:00 1220 8,213,600 1.49 0 5/18/2020 2:15 1220 8,213,600 1.49 0 5/18/2020 2:30 1210 8,146,300 1.48 0 5/18/2020 2:45 1210 8,146,300 1.48 0 5/18/2020 3:00 1220 8,213,600 1.49 0 5/18/2020 3:15 1200 8,078,900 1.47 0 5/18/2020 3:30 1210 8,146,300 1.48 0 5/18/2020 3:45 1210 8,146,300 1.48 0 5/18/2020 4:00 1210 8,146,300 1.48 0 5/18/2020 4:15 1210 8,146,300 1.48 0 5/18/2020 4:30 1210 8,146,300 1.48 0 5/18/2020 4:45 1200 8,078,900 1.47 0 5/18/2020 5:00 1200 8,078,900 1.47 0 5/18/2020 5:15 1200 8,078,900 1.47 0 5/18/2020 5:30 1210 8,146,300 1.48 0 5/18/2020 5:45 1200 8,078,900 1.47 0 TR0795 Page 12 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/18/2020 6:00 1210 8,146,300 1.48 0 5/18/2020 6:15 1210 8,146,300 1.48 0 5/18/2020 6:30 1210 8,146,300 1.48 0 5/18/2020 6:45 1200 8,078,900 1.47 0 5/18/2020 7:00 1210 8,146,300 1.48 0 5/18/2020 7:15 1200 8,078,900 1.47 0 5/18/2020 7:30 1200 8,078,900 1.47 0 5/18/2020 7:45 1200 8,078,900 1.47 0 5/18/2020 8:00 1200 8,078,900 1.47 0 5/18/2020 8:15 1210 8,146,300 1.48 0 5/18/2020 8:30 1230 8,280,900 1.5 0 5/18/2020 8:45 1200 8,078,900 1.47 0 5/18/2020 9:00 1210 8,146,300 1.48 0 5/18/2020 9:15 1210 8,146,300 1.48 0 5/18/2020 9:30 1200 8,078,900 1.47 0 5/18/2020 9:45 1210 8,146,300 1.48 0 5/18/2020 10:00 1220 8,213,600 1.49 0 5/18/2020 10:15 1220 8,213,600 1.49 0 5/18/2020 10:30 1220 8,213,600 1.49 0 5/18/2020 10:45 1220 8,213,600 1.49 0 5/18/2020 11:00 1220 8,213,600 1.49 0 5/18/2020 11:15 1200 8,078,900 1.47 0 5/18/2020 11:30 1220 8,213,600 1.49 0 5/18/2020 11:45 1210 8,146,300 1.48 0 5/18/2020 12:00 1210 8,146,300 1.48 0 5/18/2020 12:15 1220 8,213,600 1.49 0 5/18/2020 12:30 1210 8,146,300 1.48 0 5/18/2020 12:45 1210 8,146,300 1.48 0 5/18/2020 13:00 1210 8,146,300 1.48 0 5/18/2020 13:15 1200 8,078,900 1.47 0 5/18/2020 13:30 1200 8,078,900 1.47 0 5/18/2020 13:45 1200 8,078,900 1.47 0 5/18/2020 14:00 1200 8,078,900 1.47 0 5/18/2020 14:15 1210 8,146,300 1.48 0 5/18/2020 14:30 1210 8,146,300 1.48 0 5/18/2020 14:45 1210 8,146,300 1.48 0 5/18/2020 15:00 1210 8,146,300 1.48 0 5/18/2020 15:15 1210 8,146,300 1.48 0 5/18/2020 15:30 1210 8,146,300 1.48 0 5/18/2020 15:45 1220 8,213,600 1.49 0 5/18/2020 16:00 1210 8,146,300 1.48 0 5/18/2020 16:15 1220 8,213,600 1.49 0 5/18/2020 16:30 1210 8,146,300 1.48 0 5/18/2020 16:45 1210 8,146,300 1.48 0 5/18/2020 17:00 1220 8,213,600 1.49 0 5/18/2020 17:15 1220 8,213,600 1.49 0 5/18/2020 17:30 1220 8,213,600 1.49 0 5/18/2020 17:45 1220 8,213,600 1.49 0 5/18/2020 18:00 1210 8,146,300 1.48 0 5/18/2020 18:15 1210 8,146,300 1.48 0 TR0795 Page 13 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/18/2020 18:30 1210 8,146,300 1.48 0 5/18/2020 18:45 1210 8,146,300 1.48 0 5/18/2020 19:00 1210 8,146,300 1.48 0 5/18/2020 19:15 1210 8,146,300 1.48 0 5/18/2020 19:30 1220 8,213,600 1.49 0 5/18/2020 19:45 1210 8,146,300 1.48 0 5/18/2020 20:00 1210 8,146,300 1.48 0 5/18/2020 20:15 1210 8,146,300 1.48 0 5/18/2020 20:30 1200 8,078,900 1.47 0 5/18/2020 20:45 1210 8,146,300 1.48 0 5/18/2020 21:00 1210 8,146,300 1.48 0.02 5/18/2020 21:15 1210 8,146,300 1.48 0.04 5/18/2020 21:30 1210 8,146,300 1.48 0.03 5/18/2020 21:45 1210 8,146,300 1.48 0.02 5/18/2020 22:00 1210 8,146,300 1.48 0 5/18/2020 22:15 1210 8,146,300 1.48 0 5/18/2020 22:30 1210 8,146,300 1.48 0.01 5/18/2020 22:45 1210 8,146,300 1.48 0 5/18/2020 23:00 1220 8,213,600 1.49 0.02 5/18/2020 23:15 1220 8,213,600 1.49 0.04 5/18/2020 23:30 1220 8,213,600 1.49 0.01 5/18/2020 23:45 1230 8,280,900 1.5 0 5/19/2020 0:00 1220 8,213,600 1.49 0 5/19/2020 0:15 1220 8,213,600 1.49 0 5/19/2020 0:30 1220 8,213,600 1.49 0 5/19/2020 0:45 1220 8,213,600 1.49 0 5/19/2020 1:00 1220 8,213,600 1.49 0.01 5/19/2020 1:15 1240 8,348,200 1.51 0.07 5/19/2020 1:30 1240 8,348,200 1.51 0.06 5/19/2020 1:45 1240 8,348,200 1.51 0 5/19/2020 2:00 1250 8,415,600 1.52 0 5/19/2020 2:15 1250 8,415,600 1.52 0 5/19/2020 2:30 1250 8,415,600 1.52 0 5/19/2020 2:45 1270 8,550,200 1.54 0 5/19/2020 3:00 1250 8,415,600 1.52 0 5/19/2020 3:15 1250 8,415,600 1.52 0 5/19/2020 3:30 1260 8,482,900 1.53 0 5/19/2020 3:45 1260 8,482,900 1.53 0.02 5/19/2020 4:00 1260 8,482,900 1.53 0 5/19/2020 4:15 1260 8,482,900 1.53 0 5/19/2020 4:30 1260 8,482,900 1.53 0.03 5/19/2020 4:45 1260 8,482,900 1.53 0.01 5/19/2020 5:00 1270 8,550,200 1.54 0.06 5/19/2020 5:15 1270 8,550,200 1.54 0.13 5/19/2020 5:30 1270 8,550,200 1.54 0.04 5/19/2020 5:45 1270 8,550,200 1.54 0 5/19/2020 6:00 1270 8,550,200 1.54 0 5/19/2020 6:15 1270 8,550,200 1.54 0 5/19/2020 6:30 1270 8,550,200 1.54 0 5/19/2020 6:45 1270 8,550,200 1.54 0 TR0795 Page 14 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/19/2020 7:00 1290 8,684,900 1.55 0 5/19/2020 7:15 1290 8,684,900 1.55 0 5/19/2020 7:30 1290 8,684,900 1.55 0 5/19/2020 7:45 1270 8,550,200 1.54 0 5/19/2020 8:00 1290 8,684,900 1.55 0 5/19/2020 8:15 1300 8,752,200 1.56 0 5/19/2020 8:30 1300 8,752,200 1.56 0 5/19/2020 8:45 1300 8,752,200 1.56 0 5/19/2020 9:00 1310 8,819,500 1.57 0 5/19/2020 9:15 1310 8,819,500 1.57 0 5/19/2020 9:30 1310 8,819,500 1.57 0 5/19/2020 9:45 1310 8,819,500 1.57 0 5/19/2020 10:00 1320 8,886,800 1.58 0 5/19/2020 10:15 1320 8,886,800 1.58 0 5/19/2020 10:30 1320 8,886,800 1.58 0 5/19/2020 10:45 1310 8,819,500 1.57 0 5/19/2020 11:00 1310 8,819,500 1.57 0 5/19/2020 11:15 1320 8,886,800 1.58 0 5/19/2020 11:30 1320 8,886,800 1.58 0 5/19/2020 11:45 1330 8,954,200 1.59 0 5/19/2020 12:00 1320 8,886,800 1.58 0 5/19/2020 12:15 1330 8,954,200 1.59 0 5/19/2020 12:30 1350 9,088,800 1.6 0 5/19/2020 12:45 1330 8,954,200 1.59 0 5/19/2020 13:00 1350 9,088,800 1.6 0 5/19/2020 13:15 1360 9,156,100 1.61 0 5/19/2020 13:30 1360 9,156,100 1.61 0 5/19/2020 13:45 1360 9,156,100 1.61 0 5/19/2020 14:00 1370 9,223,500 1.62 0 5/19/2020 14:15 1370 9,223,500 1.62 0 5/19/2020 14:30 1390 9,358,100 1.64 0 5/19/2020 14:45 1380 9,290,800 1.63 0 5/19/2020 15:00 1390 9,358,100 1.64 0 5/19/2020 15:15 1390 9,358,100 1.64 0 5/19/2020 15:30 1380 9,290,800 1.63 0 5/19/2020 15:45 1380 9,290,800 1.63 0 5/19/2020 16:00 1390 9,358,100 1.64 0 5/19/2020 16:15 1410 9,492,800 1.65 0 5/19/2020 16:30 1420 9,560,100 1.66 0 5/19/2020 16:45 1410 9,492,800 1.65 0 5/19/2020 17:00 1420 9,560,100 1.66 0 5/19/2020 17:15 1420 9,560,100 1.66 0 5/19/2020 17:30 1420 9,560,100 1.66 0 5/19/2020 17:45 1430 9,627,400 1.67 0 5/19/2020 18:00 1430 9,627,400 1.67 0 5/19/2020 18:15 1430 9,627,400 1.67 0 5/19/2020 18:30 1440 9,694,700 1.68 0 5/19/2020 18:45 1460 9,829,400 1.69 0 5/19/2020 19:00 1470 9,896,700 1.7 0 5/19/2020 19:15 1470 9,896,700 1.7 0 TR0795 Page 15 of 16 September 2020 TABLE C12 FLOW DATA FOR W.O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/19/2020 19:30 1470 9,896,700 1.7 0 5/19/2020 19:45 1480 9,964,000 1.71 0 5/19/2020 20:00 1480 9,964,000 1.71 0 5/19/2020 20:15 1480 9,964,000 1.71 0 5/19/2020 20:30 1490 10,031,000 1.72 0 5/19/2020 20:45 1480 9,964,000 1.71 0 5/19/2020 21:00 1510 10,166,000 1.73 0 5/19/2020 21:15 1510 10,166,000 1.73 0 5/19/2020 21:30 1520 10,233,000 1.74 0 5/19/2020 21:45 1520 10,233,000 1.74 0 5/19/2020 22:00 1520 10,233,000 1.74 0 5/19/2020 22:15 1540 10,368,000 1.76 0 5/19/2020 22:30 1530 10,301,000 1.75 0 5/19/2020 22:45 1540 10,368,000 1.76 0.01 5/19/2020 23:00 1540 10,368,000 1.76 0.03 5/19/2020 23:15 1560 10,503,000 1.77 0.01 5/19/2020 23:30 1560 10,503,000 1.77 0.01 5/19/2020 23:45 1560 10,503,000 1.77 0 Notes Measurements are recorded from the USGS flow gauging station at the W.O. Huske Dam, ID 02105500 (USGS, 2020 ft3/sec - cubic feet per second ft - feet gal - gallons in - inches USGS - United States Geological Survey 1 - The minimum value recorded by a USGS raingage is 0.01 inches. Anything detected below this threshold is recorded as zero inches. TR0795 Page 16 of 16 September 2020 TABLE C13 FLOW DATA FOR LOCK #1 NR KELLY, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/18/2020 0:00 1640 11,041,218 15.37 0 5/18/2020 0:15 1630 10,973,894 15.36 0 5/18/2020 0:30 1640 11,041,218 15.37 0 5/18/2020 0:45 1630 10,973,893 15.36 0 5/18/2020 1:00 1640 11,041,218 15.37 0 5/18/2020 1:15 1630 10,973,893 15.36 0 5/18/2020 1:30 1640 11,041,218 15.37 0 5/18/2020 1:45 1640 11,041,218 15.37 0 5/18/2020 2:00 1640 11,041,218 15.37 0 5/18/2020 2:15 1610 10,839,244 15.35 0 5/18/2020 2:30 1640 11,041,218 15.37 0 5/18/2020 2:45 1640 11,041,218 15.37 0 5/18/2020 3:00 1630 10,973,893 15.36 0 5/18/2020 3:15 1610 10,839,245 15.35 0 5/18/2020 3:30 1630 10,973,893 15.36 0 5/18/2020 3:45 1630 10,973,893 15.36 0 5/18/2020 4:00 1640 11,041,218 15.37 0 5/18/2020 4:15 1640 11,041,218 15.37 0 5/18/2020 4:30 1610 10,839,244 15.35 0 5/18/2020 4:45 1640 11,041,218 15.37 0 5/18/2020 5:00 1640 11,041,218 15.37 0 5/18/2020 5:15 1640 11,041,218 15.37 0 5/18/2020 5:30 1640 11,041,218 15.37 0 5/18/2020 5:45 1630 10,973,893 15.36 0 5/18/2020 6:00 1640 11,041,218 15.37 0 5/18/2020 6:15 1630 10,973,894 15.36 0 5/18/2020 6:30 1630 10,973,893 15.36 0 5/18/2020 6:45 1630 10,973,893 15.36 0 5/18/2020 7:00 1630 10,973,894 15.36 0 5/18/2020 7:15 1640 11,041,218 15.37 0 5/18/2020 7:30 1630 10,973,893 15.36 0 5/18/2020 7:45 1610 10,839,245 15.35 0 5/18/2020 8:00 1610 10,839,244 15.35 0 5/18/2020 8:15 1610 10,839,244 15.35 0 5/18/2020 8:30 1640 11,041,218 15.37 0 5/18/2020 8:45 1630 10,973,893 15.36 0 5/18/2020 9:00 1640 11,041,218 15.37 0 5/18/2020 9:15 1640 11,041,218 15.37 0 5/18/2020 9:30 1580 10,637,271 15.33 0 5/18/2020 9:45 1640 11,041,218 15.37 0 5/18/2020 10:00 1630 10,973,894 15.36 0 5/18/2020 10:15 1640 11,041,218 15.37 0 5/18/2020 10:30 1610 10,839,244 15.35 0 5/18/2020 10:45 1610 10,839,245 15.35 0 5/18/2020 11:00 1610 10,839,244 15.35 0 5/18/2020 11:15 1630 10,973,893 15.36 0 5/18/2020 11:30 1630 10,973,894 15.36 0 5/18/2020 11:45 1630 10,973,893 15.36 0 5/18/2020 12:00 1610 10,839,244 15.35 0 5/18/2020 12:15 1610 10,839,245 15.35 0 TR0795 Page 1 of 4 September 2020 TABLE C13 FLOW DATA FOR LOCK #1 NR KELLY, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/18/2020 12:30 1610 10,839,244 15.35 0 5/18/2020 12:45 1610 10,839,244 15.35 0 5/18/2020 13:00 1610 10,839,245 15.35 0 5/18/2020 13:15 1610 10,839,244 15.35 0 5/18/2020 13:30 1610 10,839,244 15.35 0 5/18/2020 13:45 1610 10,839,245 15.35 0 5/18/2020 14:00 1600 10,771,920 15.34 0 5/18/2020 14:15 1580 10,637,271 15.33 0 5/18/2020 14:30 1600 10,771,920 15.34 0 5/18/2020 14:45 1580 10,637,271 15.33 0 5/18/2020 15:00 1580 10,637,271 15.33 0 5/18/2020 15:15 1580 10,637,271 15.33 0 5/18/2020 15:30 1580 10,637,271 15.33 0 5/18/2020 15:45 1580 10,637,271 15.33 0 5/18/2020 16:00 1570 10,569,947 15.32 0 5/18/2020 16:15 1580 10,637,271 15.33 0 5/18/2020 16:30 1580 10,637,271 15.33 0 5/18/2020 16:45 1570 10,569,947 15.32 0 5/18/2020 17:00 1570 10,569,946 15.32 0 5/18/2020 17:15 1560 10,502,622 15.31 0 5/18/2020 17:30 1570 10,569,947 15.32 0 5/18/2020 17:45 1560 10,502,622 15.31 0 5/18/2020 18:00 1560 10,502,622 15.31 0 5/18/2020 18:15 1560 10,502,622 15.31 0 5/18/2020 18:30 1560 10,502,622 15.31 0 5/18/2020 18:45 1540 10,367,973 15.3 0 5/18/2020 19:00 1540 10,367,973 15.3 0 5/18/2020 19:15 1540 10,367,973 15.3 0 5/18/2020 19:30 1540 10,367,973 15.3 0 5/18/2020 19:45 1540 10,367,973 15.3 0 5/18/2020 20:00 1540 10,367,973 15.3 0 5/18/2020 20:15 1530 10,300,648 15.29 0 5/18/2020 20:30 1530 10,300,649 15.29 0 5/18/2020 20:45 1530 10,300,648 15.29 0 5/18/2020 21:00 1530 10,300,648 15.29 0 5/18/2020 21:15 1510 10,166,000 15.28 0 5/18/2020 21:30 1510 10,165,999 15.28 0 5/18/2020 21:45 1510 10,165,999 15.28 0 5/18/2020 22:00 1540 10,367,973 15.3 0 5/18/2020 22:15 1500 10,098,675 15.27 0 5/18/2020 22:30 1710 11,512,489 15.42 0 5/18/2020 22:45 1610 10,839,245 15.35 0.17 5/18/2020 23:00 1580 10,637,271 15.33 0.01 5/18/2020 23:15 1600 10,771,920 15.34 0 5/18/2020 23:30 1580 10,637,271 15.33 0 5/18/2020 23:45 1580 10,637,271 15.33 0 5/19/2020 0:00 1580 10,637,271 15.33 0 5/19/2020 0:15 1570 10,569,947 15.32 0 5/19/2020 0:30 1580 10,637,271 15.33 0 5/19/2020 0:45 1580 10,637,271 15.33 0 TR0795 Page 2 of 4 September 2020 TABLE C13 FLOW DATA FOR LOCK #1 NR KELLY, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/19/2020 1:00 1580 10,637,271 15.33 0 5/19/2020 1:15 1570 10,569,946 15.32 0 5/19/2020 1:30 1570 10,569,946 15.32 0 5/19/2020 1:45 1580 10,637,271 15.33 0.02 5/19/2020 2:00 1580 10,637,271 15.33 0 5/19/2020 2:15 1600 10,771,920 15.34 0 5/19/2020 2:30 1600 10,771,920 15.34 0.01 5/19/2020 2:45 1600 10,771,920 15.34 0 5/19/2020 3:00 1600 10,771,920 15.34 0.01 5/19/2020 3:15 1600 10,771,920 15.34 0.03 5/19/2020 3:30 1600 10,771,920 15.34 0.07 5/19/2020 3:45 1600 10,771,920 15.34 0.01 5/19/2020 4:00 1600 10,771,920 15.34 0.04 5/19/2020 4:15 1600 10,771,920 15.34 0.05 5/19/2020 4:30 1600 10,771,920 15.34 0.03 5/19/2020 4:45 1610 10,839,245 15.35 0 5/19/2020 5:00 1610 10,839,244 15.35 0 5/19/2020 5:15 1610 10,839,244 15.35 0.02 5/19/2020 5:30 1610 10,839,245 15.35 0.08 5/19/2020 5:45 1610 10,839,244 15.35 0.07 5/19/2020 6:00 1610 10,839,244 15.35 0.14 5/19/2020 6:15 1610 10,839,245 15.35 0.03 5/19/2020 6:30 1630 10,973,893 15.36 0.01 5/19/2020 6:45 1630 10,973,893 15.36 0 5/19/2020 7:00 1640 11,041,218 15.37 0 5/19/2020 7:15 1630 10,973,893 15.36 0.01 5/19/2020 7:30 1640 11,041,218 15.37 0 5/19/2020 7:45 1640 11,041,218 15.37 0.01 5/19/2020 8:00 1640 11,041,218 15.37 0 5/19/2020 8:15 1670 11,243,191 15.39 0 5/19/2020 8:30 1670 11,243,192 15.39 0 5/19/2020 8:45 1680 11,310,516 15.4 0 5/19/2020 9:00 1700 11,445,165 15.41 0 5/19/2020 9:15 1650 11,108,543 15.38 0 5/19/2020 9:30 1670 11,243,191 15.39 0 5/19/2020 9:45 1700 11,445,165 15.41 0 5/19/2020 10:00 1680 11,310,516 15.4 0 5/19/2020 10:15 1680 11,310,516 15.4 0 5/19/2020 10:30 1710 11,512,489 15.42 0 5/19/2020 10:45 1700 11,445,165 15.41 0 5/19/2020 11:00 1710 11,512,489 15.42 0 5/19/2020 11:15 1710 11,512,489 15.42 0 5/19/2020 11:30 1730 11,647,139 15.43 0 5/19/2020 11:45 1730 11,647,138 15.43 0 5/19/2020 12:00 1730 11,647,138 15.43 0 5/19/2020 12:15 1740 11,714,463 15.44 0 5/19/2020 12:30 1710 11,512,489 15.42 0 5/19/2020 12:45 1710 11,512,489 15.42 0 5/19/2020 13:00 1710 11,512,490 15.42 0 5/19/2020 13:15 1710 11,512,489 15.42 0 TR0795 Page 3 of 4 September 2020 TABLE C13 FLOW DATA FOR LOCK #1 NR KELLY, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Date Time Flow Rate (ft3/sec)Flow Volume (gal)Gage Height (ft)Precipitation (in)1 5/19/2020 13:30 1710 11,512,489 15.42 0 5/19/2020 13:45 1730 11,647,139 15.43 0 5/19/2020 14:00 1710 11,512,489 15.42 0 5/19/2020 14:15 1730 11,647,138 15.43 0 5/19/2020 14:30 1710 11,512,490 15.42 0 5/19/2020 14:45 1730 11,647,138 15.43 0 5/19/2020 15:00 1740 11,714,463 15.44 0 5/19/2020 15:15 1730 11,647,139 15.43 0 5/19/2020 15:30 1740 11,714,463 15.44 0 5/19/2020 15:45 1760 11,849,112 15.45 0 5/19/2020 16:00 1760 11,849,112 15.45 0 5/19/2020 16:15 1760 11,849,112 15.45 0 5/19/2020 16:30 1760 11,849,112 15.45 0.02 5/19/2020 16:45 1740 11,714,463 15.44 0.01 5/19/2020 17:00 1760 11,849,112 15.45 0 5/19/2020 17:15 1770 11,916,436 15.46 0.01 5/19/2020 17:30 1760 11,849,112 15.45 0.03 5/19/2020 17:45 1770 11,916,436 15.46 0.02 5/19/2020 18:00 1760 11,849,112 15.45 0 5/19/2020 18:15 1770 11,916,437 15.46 0 5/19/2020 18:30 1770 11,916,436 15.46 0 5/19/2020 18:45 1770 11,916,436 15.46 0 5/19/2020 19:00 1770 11,916,437 15.46 0 5/19/2020 19:15 1770 11,916,436 15.46 0 5/19/2020 19:30 1790 12,051,085 15.47 0 5/19/2020 19:45 1770 11,916,437 15.46 0 5/19/2020 20:00 1790 12,051,085 15.47 0 5/19/2020 20:15 1790 12,051,085 15.47 0 5/19/2020 20:30 1790 12,051,086 15.47 0 5/19/2020 20:45 1790 12,051,085 15.47 0 5/19/2020 21:00 1790 12,051,085 15.47 0 5/19/2020 21:15 1790 12,051,086 15.47 0 5/19/2020 21:30 1790 12,051,085 15.47 0 5/19/2020 21:45 1790 12,051,085 15.47 0 5/19/2020 22:00 1800 12,118,410 15.48 0 5/19/2020 22:15 1790 12,051,085 15.47 0 5/19/2020 22:30 1790 12,051,085 15.47 0 5/19/2020 22:45 1800 12,118,410 15.48 0 5/19/2020 23:00 1790 12,051,085 15.47 0 5/19/2020 23:15 1800 12,118,410 15.48 0 5/19/2020 23:30 1820 12,253,059 15.49 0 5/19/2020 23:45 1800 12,118,410 15.48 0 Notes Measurements are recorded from the USGS flow gauging station at Lock #1 near Kelly, ID 02105769 (USGS, 2020). 1 - The minimum value recorded by a USGS raingage is 0.01 inches. Anything detected below this threshold is recorded as zero inches. ft3/sec - cubic feet per second ft - feet gal - gallons in - inches USGS - United States Geological Survey TR0795 Page 4 of 4 September 2020 APPENDIX D Field Forms Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-06-2020 Time:12:00 Water Volume = 19.3 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 12:15 19.37 250.00 0.33 6.24 0.18 22.80 7.00 Clear None 12:20 19.38 250.00 0.67 6.13 0.13 22.50 5.70 Clear None 12:25 19.37 250.00 1.00 5.99 0.11 21.40 5.37 Clear None 12:30 19.37 250.00 1.33 5.96 0.08 23.50 5.44 Clear None 12:35 19.37 250.00 1.65 5.81 0.08 24.40 5.71 Clear None 12:40 19.37 250.00 1.98 5.97 0.07 23.30 5.97 Clear None 12:45 19.37 250.00 2.31 6.04 0.07 28.40 6.45 Clear No 12:50 19.37 250.00 2.64 5.8 0.07 28.50 5.85 Clear None 12:55 19.37 250.00 2.97 5.76 0.06 27.90 5.84 Clear None 13:00 19.37 250.00 3.30 5.76 0.06 25.30 5.65 Clear None 13:05 19.37 250.00 3.63 5.8 0.06 24.60 5.33 Clear None 13:10 19.37 250.00 3.96 5.79 0.06 23.40 5.37 Clear None 13:15 19.37 250.00 4.29 5.75 0.06 23.10 6.03 Clear None 13:20 19.37 250.00 4.62 5.77 0.07 23.00 5.43 Clear None 13:25 19.37 250.00 5.75 0.07 22.80 5.45 Clear None 13:30 19.37 250.00 4.95 5.74 0.07 22.60 5.77 Clear None Sampling Data Zero HS: Method:Date: Time:13:40 Field Parameters a a Sample ID: DuplicateID: 0.06 21.42 0.06 21.33 0.07 21.27 0.06 21.31 0.06 21.19 0.07 21.00 0.06 22.26 0.07 20.98 0.07 20.60 0.07 20.76 0.07 21.15 0.07 21.03 0.07 21.04 0.07 21.08 RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey bottom of well Bladen-1D Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 7.6Total Volume Purged (gallons): Temp. oC 0.08 20.15 Initial Depth to Water (ft.): Temperature (F): -3.088 05-06-2020 Peristaltic Pump Temp.(oC)PFAS21.33 Screen Interval: 37 - 47 5.74pH STABILIZED PARAMETERS 0.06 5.77 Spec. Cond.(mS/cm) Turbidity (NTU) 70.00 250 mL poly NP DO (mg/L) ORP (mV) 0.07 22.60 CAP2Q20-Bladen-1D-050620 WEATHER CONDITIONS CAP2Q20--Bladen-1D-050620-D Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.08 21.06 Sunny None Wind (mph)8 Precipitation: Sky: Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:13:00 Water Volume = 15.81 28.73 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 0 16.01 250.00 0.33 3.86 0.15 136.40 41.61 Clear None 13:30 16.01 250.00 0.66 3.92 0.12 132.90 35.32 Clear None 13:35 16.01 250.00 0.99 3.96 0.13 128.90 16.38 Clear None 13:40 16.01 250.00 1.32 3.97 0.13 127.60 12.24 Clear None 13:45 16.01 250.00 1.65 3.96 0.17 125.40 5.82 Clear None 13:50 16.01 250.00 1.97 3.96 0.16 124.50 5.54 Clear No 13:55 16.01 250.00 2.31 3.96 0.15 124.60 6.62 Clear None 14:00 16.01 250.00 2.61 3.95 0.16 124.20 4.28 Clear None Sampling Data Zero HS: Method:Date: Time:14:05 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)6 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.12 17.96 DO (mg/L) ORP (mV) 0.16 124.20 CAP2Q20-LTW-01-050720 WEATHER CONDITIONS 64.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 2.067 05-07-2020 Temp.(oC)PFAS17.75 Screen Interval: 11.0-26.0 3.95pH STABILIZED PARAMETERS 0.13 4.28 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen LTW-01 Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 3Total Volume Purged (gallons): Temp. oC 0.12 18.06 0.12 18.02 0.12 18.02 0.13 17.92 0.13 17.79 0.13 17.77 0.13 17.75 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-12-2020 Time:12:51 Water Volume = 9.88 40.66 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 13:05 10.02 200.00 0.27 4.86 0.15 95.40 6.40 Clear None 13:10 10.00 200.00 0.50 4.9 0.09 91.10 3.35 Clear None 13:15 10.00 200.00 0.70 4.94 0.09 89.10 2.85 Clear None 13:20 10.00 200.00 0.95 4.93 0.09 87.10 2.03 Clear None 13:25 10.00 200.00 1.10 4.95 0.07 86.90 2.10 Clear None 13:30 10.00 200.00 1.30 4.94 0.06 84.90 2.12 Clear None 13:35 10.00 200.00 1.50 4.93 0.08 83.30 1.97 Clear None 13:40 10.00 200.00 1.70 4.94 0.08 84.10 2.08 Clear None 13:45 10.00 200.00 1.90 4.94 0.07 81.80 1.86 Clear None 13:50 10.00 200.00 2.10 4.95 0.08 80.60 2.12 Clear None 13:55 10.00 200.00 2.40 4.94 0.08 78.20 1.92 Clear None 14:00 10.00 200.00 2.70 4.95 0.11 80.30 2.39 Clear None 14:05 10.00 200.00 2.90 4.93 0.10 78.40 2.14 Clear None 14:10 10.00 200.00 3.10 4.95 0.10 78.20 2.15 Clear None Sampling Data Zero HS: Method:Date: Time:14:15 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)6 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.07 17.12 DO (mg/L) ORP (mV) 0.10 78.20 CAP2Q20-LTW-02-051220 WEATHER CONDITIONS 64.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 4.925 05-12-2020 Peristaltic Pump Temp.(oC)PFAS17.24 Screen Interval: 28.0-38.0 4.95pH STABILIZED PARAMETERS 0.07 2.15 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen LTW-02 Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 4.3Total Volume Purged (gallons): Temp. oC 0.07 17.00 0.07 17.09 0.07 17.05 0.07 17.04 0.07 17.03 0.07 17.07 0.07 17.10 0.07 17.10 0.07 17.17 0.07 17.23 0.07 17.18 0.07 17.19 0.07 17.24 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-13-2020 Time:10:25 Water Volume = 12.5 32.75 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 10:30 13.00 185.00 0.24 6.44 7.93 27.50 195.00 Clear No 10:35 13.04 185.00 0.24 6.43 7.86 30.50 210.01 Clear No 10:40 13.05 185.00 0.24 6.41 7.70 38.20 205.38 Clear No 10:45 13.10 185.00 0.24 6.39 7.58 45.20 196.63 Clear No 10:50 13.11 185.00 0.24 6.35 7.43 53.20 286.22 Clear No 10:55 13.12 185.00 0.24 6.31 7.34 58.00 310.58 Clear No 11:00 13.15 185.00 0.24 6.06 6.94 66.10 110.23 Clear No 11:05 13.15 185.00 0.24 6.03 6.84 68.50 57.05 Clear No 11:10 13.16 185.00 0.24 6.01 6.82 69.60 64.10 Clear No 11:15 13.15 185.00 0.24 5.86 6.78 70.40 152.34 Clear No 11:20 13.17 185.00 0.24 5.81 6.73 74.80 152.91 Clear No 11:25 13.19 185.00 0.24 5.79 6.67 74.60 143.57 Clear No 11:30 13.21 185.00 0.24 5.81 6.56 82.30 218.18 Clear No 11:35 13.23 185.00 5.79 6.46 87.10 215.78 Clear No 11:45 13.17 185.00 0.24 5.76 6.32 93.60 207.79 11:55 13.18 185.00 0.24 5.7 6.15 99.70 219.74 12:05 13.19 185.00 0.24 5.73 5.96 105.60 274.24 Clear No 12:15 13.18 185.00 0.24 5.95 5.67 108.70 211.44 Clear No 12:25 13.20 185.00 0.24 5.89 5.30 107.80 124.05 Clear No 12:35 13.18 185.00 0.24 5.71 5.10 112.70 67.77 Clear No 12:45 13.20 185.00 0.24 5.33 4.89 126.90 42.34 Clear No 12:55 13.21 185.00 0.24 5.23 4.63 138.00 9.05 Clear No 13:05 13.19 185.00 0.24 5.19 4.47 142.70 0.49 Clear No 13:10 13.23 185.00 0.24 5.2 4.31 150.60 0.07 Clear No 13:15 13.21 185.00 0.24 5.22 4.15 153.60 0.15 Clear No 13:20 13.19 185.00 0.24 5.07 4.05 158.20 0.00 Clear No 13:27 13.20 185.00 0.24 5.23 3.69 156.10 0.23 Clear No 13:30 13.23 185.00 0.24 5.24 3.66 154.13 0.25 Clear No 13:35 13.18 185.00 0.24 5.22 3.91 151.19 0.15 Clear No Sampling Data Zero HS: Method:Date: Time:13:30 Field Parameters a Comments SAMPLE SET PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.06 18.03 Initial Depth to Water (ft.): 3.24 05-13-2020 Peristaltic Pump Screen Interval: 15.0-30.0 5.22pH STABILIZED PARAMETERS 0.05 0.15 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHRIS LICHOROBIEC Tyler WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen LTW-03 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 10Total Volume Purged (gallons): Temp. oC 0.06 17.96 0.06 18.24 0.06 18.42 0.06 18.62 0.06 18.71 0.06 18.90 0.06 19.09 0.06 19.12 0.06 19.03 0.06 19.06 0.06 19.07 0.06 19.23 0.06 19.39 The following reading will be at 10 minute intervals due to the need of 0.06 19.70 0.06 19.90 0.06 20.34 0.06 21.36 0.06 23.28 0.06 24.33 0.05 25.00 0.05 26.36 0.05 27.16 Switch to five minute increments 0.05 28.03 0.05 28.47 0.05 29.05 Final parameters 0.05 31.23 0.05 34.07 0.05 34.15 a Sample ID: DuplicateID: Partly Cloudy None Wind (mph) Precipitation: Sky: Table 3+ DO (mg/L) ORP (mV) 3.91 151.19 CAP2Q20-LTW-03-051320 WEATHER CONDITIONS 65.00 250 mL poly NP Temperature (F): Temp.(oC)PFAS34.15 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-08-2020 Time:11:13 Water Volume = 8.33 27 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 11:25 11.81 500.00 4.44 0.19 30.90 33.78 11:30 11.00 4.45 0.18 27.10 32.23 11:35 11.15 4.51 0.16 25.60 34.04 11:40 11.33 4.46 0.14 26.30 34.86 11:45 11.51 4.54 0.15 26.10 24.59 11:50 11.57 4.5 0.13 26.60 23.32 11:55 11.67 4.52 0.12 46.80 23.88 12:00 11.75 4.52 0.12 38.10 23.74 12:05 11.83 4.52 0.12 35.30 17.35 12:10 11.89 4.54 0.11 31.60 16.97 12:15 11.97 4.48 0.12 29.20 10.35 12:20 12.01 4.58 0.12 28.20 9.64 12:25 12.97 4.54 0.12 28.70 9.90 Sampling Data Zero HS: Method:Date: Time:12:25 Field Parameters a a Sample ID: DuplicateID: Partly Cloudy None Wind (mph)5 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 95.00 18.27 DO (mg/L) ORP (mV) 0.12 28.70 CAP2Q20-LTW-04-050820 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 2.987 05-08-2020 Peristaltic Pump Temp.(oC)PFAS18.16 Screen Interval: 4.54pH STABILIZED PARAMETERS 89.78 9.90 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 JOEY VIDMAR WATER VOLUME CALCULATION Quarterly Tracy Ovbey 27 within screen Ltw-04 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 2.5Total Volume Purged (gallons): Temp. oC 95.14 18.14 94.31 18.07 95.64 17.88 93.20 17.86 94.64 17.82 96.41 17.95 95.70 18.01 88.85 18.10 89.78 18.16 92.97 18.08 90.07 18.19 92.05 18.23 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-08-2020 Time:14:48 Water Volume = 9.3 40 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 14:53 9.41 4.22 0.11 53.50 59.98 Clear No 14:57 9.41 4.23 0.08 52.30 52.55 Clear No 15:00 9.41 4.24 0.07 50.30 38.64 Clear No 15:04 9.41 4.25 0.06 48.50 20.39 Clear No 15:08 9.41 4.25 0.06 49.40 15.94 Clear No 15:12 9.41 4.26 0.05 48.80 10.11 Clear No 15:16 9.41 4.26 0.04 47.80 10.48 Clear No 15:20 9.41 4.26 0.04 47.70 5.55 Clear No 15:23 9.41 4.27 0.04 46.90 6.95 Clear No Sampling Data Zero HS: Method:Date: Time:15:30 Field Parameters a a Sample ID: DuplicateID: Cloudy None Wind (mph)14 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.12 17.83 DO (mg/L) ORP (mV) 0.04 46.90 CAP2Q20-LTW-05-050820 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 4.912 05-08-2020 Peristaltic Pump Temp.(oC)PFAS17.73 Screen Interval: 29.0-44.0 4.27pH STABILIZED PARAMETERS 0.12 6.95 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 JELANI GILL WATER VOLUME CALCULATION Quarterly Tracy Ovbey 38 within screen LTW-05 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 2.3Total Volume Purged (gallons): Temp. oC 0.12 17.78 0.12 17.64 0.12 17.58 0.12 17.70 0.12 17.73 0.12 17.58 0.12 17.70 0.12 17.58 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:10:25 Water Volume = 17.73 31.71 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 10:35 17.78 250.00 0.33 3.63 0.21 118.90 69.41 Clear None 10:40 17.78 250.00 0.66 3.63 0.12 121.30 40.88 Clear None 10:45 17.77 250.00 0.99 3.62 0.09 119.80 22.81 Clear None 10:50 17.77 250.00 1.32 3.62 0.07 122.20 11.95 Clear None 10:55 17.77 250.00 1.65 3.62 0.06 120.60 7.26 Clear None 11:00 17.77 250.00 1.98 3.62 0.06 120.50 5.27 Clear None 11:06 17.77 250.00 2.31 3.62 0.06 120.90 3.75 Cloudy None Sampling Data Zero HS: Method:Date: Time:11:10 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)8 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.20 16.45 DO (mg/L) ORP (mV) 0.06 120.90 CAP2Q20-PIW-1D-050720 WEATHER CONDITIONS 58.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 2.237 05-07-2020 Peristaltic Pump Temp.(oC)PFAS16.64 Screen Interval: 24.5 to 29.5 3.62pH STABILIZED PARAMETERS 0.20 3.75 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PIW-1D Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 3Total Volume Purged (gallons): Temp. oC 0.20 16.45 0.20 16.68 0.20 16.64 0.20 16.55 0.20 16.42 0.20 16.36 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:14:10 Water Volume = 16.75 26.8 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 14:20 17.13 270.00 0.34 4.48 0.13 122.00 17.89 Cloudy None 14:25 17.16 270.00 0.67 5.02 0.09 122.00 18.29 Clear None 14:30 17.17 270.00 1.00 4.75 0.04 114.20 4.92 Clear None 14:35 17.72 270.00 1.35 4.76 0.04 110.00 3.07 Clear None 14:40 17.17 270.00 1.70 4.75 0.04 108.00 3.68 Clear Clear Sampling Data Zero HS: Method:Date: Time:14:45 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)4 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.10 17.02 DO (mg/L) ORP (mV) 0.04 108.00 CAP2Q20-PIW-3D-050720 WEATHER CONDITIONS 66.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 1.608 05-07-2019 Temp.(oC)PFAS17.07 Screen Interval: 19 - 24 4.75pH STABILIZED PARAMETERS 0.10 3.68 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PIW-3D Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 2.8Total Volume Purged (gallons): Temp. oC 0.10 17.06 0.10 17.01 0.10 17.04 0.10 17.07 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-08-2020 Time:13:18 Water Volume = 5.55 34 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 13:35 5.55 4.32 0.09 51.90 11.97 Clear No 13:38 5.55 4.34 0.08 50.10 12.94 Clear No 13:43 5.55 4.37 0.06 46.00 12.37 Clear No 13:47 5.55 4.35 0.06 45.20 9.20 Clear No 13:51 5.55 4.36 0.05 43.40 5.49 Clear No 13:54 5.55 4.38 0.05 42.80 4.34 Clear No 13:59 5.55 4.37 0.04 42.20 4.63 Clear No 14:02 5.55 4.36 0.04 42.00 2.51 Clear No 14:05 5.55 4.35 0.04 41.70 3.51 Clear No Sampling Data Zero HS: Method:Date: Time:14:10 Field Parameters a a Sample ID: DuplicateID: Cloudy None Wind (mph)5 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.09 17.94 DO (mg/L) ORP (mV) 0.04 41.70 CAP2Q20-PIW-7D-050820 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 4.552 05-08-2020 Peristaltic Pump Temp.(oC)PFAS17.96 Screen Interval: 29 - 34 4.35pH STABILIZED PARAMETERS 0.09 3.51 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 JELANI GILL WATER VOLUME CALCULATION Quarterly Tracy Ovbey 32 within screen PIW-7D Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 2.3Total Volume Purged (gallons): Temp. oC 0.09 17.67 0.09 18.20 0.09 18.13 0.09 18.21 0.09 17.96 0.09 18.16 0.09 18.05 0.09 18.08 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-08-2020 Time:13:23 Water Volume = 5.24 18 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 13:30 5.44 200.00 5.08 0.28 34.50 14.95 13:35 5.44 200.00 5.05 0.17 20.00 12.16 13:40 5.44 200.00 5.06 0.14 18.30 16.26 13:45 5.44 200.00 5.09 0.11 15.60 14.42 13:50 5.44 200.00 5.11 0.09 12.90 9.51 13:55 5.44 200.00 5.11 0.09 12.00 8.04 14:00 5.44 200.00 5.11 0.08 8.40 6.02 14:05 5.44 200.00 5.11 0.08 6.70 6.15 14:10 5.44 200.00 5.11 0.07 3.30 3.18 14:15 5.44 200.00 5.1 0.07 0.20 4.81 14:20 5.44 200.00 5.1 0.07 0.00 2.09 14:25 5.44 200.00 5.14 0.07 0.00 2.40 14:30 5.44 200.00 5.13 0.07 0.00 2.66 Sampling Data Zero HS: Method:Date: Time:14:30 Field Parameters a a Sample ID: DuplicateID: Cloudy None Wind (mph)5 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.11 17.74 DO (mg/L) ORP (mV) 0.07 CAP2Q20-PIW-7S-050820 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 2.042 05-08-2020 Peristaltic Pump Temp.(oC)PFAS17.63 Screen Interval: 5.13pH STABILIZED PARAMETERS 0.11 2.66 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 JOEY VIDMAR Jelani gill WATER VOLUME CALCULATION Quarterly Tracy Ovbey 15 bottom of well Piw-7s Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 3.2Total Volume Purged (gallons): Temp. oC 0.11 17.83 0.11 18.10 0.11 18.02 0.11 18.41 0.11 18.24 0.11 18.11 0.11 17.94 0.11 17.81 0.11 17.63 0.11 17.82 0.11 18.00 0.11 17.80 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-11-2020 Time:12:30 Water Volume = 27.16 30.81 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 12:45 28.50 100.00 0.15 3.92 0.11 0.27 6.12 Clear None 12:50 28.92 100.00 0.30 3.93 0.11 47.00 18.90 Clear None 12:55 29.34 100.00 0.45 3.89 0.11 47.40 87.64 Cloudy None 13:00 29.95 100.00 0.60 3.89 0.10 48.70 69.23 Cloudy None 13:05 30.10 100.00 0.75 3.88 0.12 49.20 48.24 Cloudy None 13:10 30.81 100.00 Sampling Data Zero HS: Method:Date: Time: Field Parameters a a Sample ID: DuplicateID: Well went dry 0.31 19.81 0.34 19.67 0.38 19.74 RECORD OF WELL SAMPLING Well ran dry = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey bottom of well PW-04 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.27 19.57 Initial Depth to Water (ft.): Temperature (F): 0.584Peristaltic Pump Temp.(oC)PFAS Screen Interval: 17 - 27 pH STABILIZED PARAMETERS Spec. Cond.(mS/cm) Turbidity (NTU) 70.00 250 mL poly NP DO (mg/L) ORP (mV) CAP2Q20-PW-04-051320 WEATHER CONDITIONS Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.27 19.51 Sunny None Wind (mph)8 Precipitation: Sky: Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-12-2020 Time:11:15 Water Volume = 27.23 30.81 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 11:50 28.34 125.00 0.45 3.85 0.15 90.00 8.52 Clear None 11:55 28.93 125.00 0.60 3.84 0.11 92.30 16.95 Clear None 12:00 29.45 125.00 0.75 3.85 0.12 92.10 115.23 Cloudy None 12:05 29.97 125.00 0.90 3.84 0.13 94.20 52.59 Cloudy None 12:10 30.47 125.00 1.05 3.85 0.23 95.10 25.72 Clear None 12:15 30.81 125.00 1.25 3.85 0.54 95.70 163.37 Cloudy None Sampling Data Zero HS: Method:Date: Time: Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)6 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.29 18.19 DO (mg/L) ORP (mV) 0.54 95.70 CAP2Q20-PW-04-051320 WEATHER CONDITIONS 61.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 0.573Peristaltic Pump Temp.(oC)PFAS18.86 Screen Interval: 17 - 27 3.85pH STABILIZED PARAMETERS 0.37 163.37 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING Well ran dry = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey bottom of well PW-04 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.32 18.12 0.37 18.86 Well went dry 0.29 18.31 0.32 18.41 0.35 18.28 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-13-2020 Time:14:10 Water Volume = 27.2 30.8 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 14:25 27.20 150.00 4.65 4.57 57.30 0.30 Clear No 14:30 28.45 150.00 4.31 4.18 63.90 0.36 Sampling Data Zero HS: Method:Date: Time:14:25 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph) Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.05 36.45 DO (mg/L) ORP (mV) 4.18 63.90 CAP2Q20-PW-04-051320 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 0.576 05-13-2020 Peristaltic Pump Temp.(oC)PFAS36.45 Screen Interval: 17 - 27 4.31pH STABILIZED PARAMETERS 0.05 0.36 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHRIS LICHOROBIEC Tyler P WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PW-04 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 0Total Volume Purged (gallons): Temp. oC 0.05 34.81 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-06-2020 Time:14:55 Water Volume = 19.4 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 15:00 20.90 250.00 0.33 4.23 1.87 89.60 9.14 Clear None 15:05 20.92 250.00 0.66 4.17 1.80 88.30 6.99 Clear None 15:10 20.98 250.00 0.99 4.02 2.10 79.50 5.60 Clear None 15:15 20.98 250.00 1.32 4.01 2.13 77.00 5.04 Clear None 15:20 19.98 250.00 1.65 4.03 2.14 78.20 4.82 Clear None Sampling Data Zero HS: Method:Date: Time:15:25 Field Parameters a a Sample ID: DuplicateID: 0.05 18.42 0.05 18.26 0.05 17.82 RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PW-06 Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm 4.6Total Volume Purged (gallons): Temp. oC 0.05 17.95 Initial Depth to Water (ft.): Temperature (F): -3.104 05-06-2020 Peristaltic Pump Temp.(oC)PFAS17.82 Screen Interval: 19 - 29 4.03pH STABILIZED PARAMETERS 0.05 4.82 Spec. Cond.(mS/cm) Turbidity (NTU) 75.00 250 mL poly NP DO (mg/L) ORP (mV) 2.14 78.20 CAP2Q20-PW-06-050620 WEATHER CONDITIONS Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.05 18.46 Sunny None Wind (mph)8 Precipitation: Sky: Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-11-2020 Time:14:30 Water Volume = 36.71 41.78 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 14:41 5.04 7.67 59.90 349.78 Brown No Sampling Data Zero HS: Method:Date: Time: Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)4 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. First reading while bailing well dry DO (mg/L) ORP (mV) CAP2Q20-PW-07-051420 WEATHER CONDITIONS 70.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 0.811 Temp.(oC)PFAS Screen Interval: 28 - 38 pH STABILIZED PARAMETERS Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING Well ran dry = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey PW-07 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.05 21.58 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-12-2020 Time:14:46 Water Volume = 36.85 41.78 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 15:01 4.84 7.99 77.90 29.43 Clear None Sampling Data Zero HS: Method:Date: Time: Field Parameters a a Sample ID: DuplicateID: RECORD OF WELL SAMPLING Well ran dry = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 LUKE TART WATER VOLUME CALCULATION Quarterly Tracy Ovbey PW-07 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.04 19.65 Initial Depth to Water (ft.): Temperature (F): 0.789 Temp.(oC)PFAS19.65 Screen Interval: 28 - 38 4.84pH STABILIZED PARAMETERS 0.04 29.43 Spec. Cond.(mS/cm) Turbidity (NTU) 74.00 250 mL poly NP DO (mg/L) ORP (mV) 7.99 77.90 CAP2Q20-PW-07-051420 WEATHER CONDITIONS Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. First reading while bailing well dry, well went dry at 15:12 Sunny None Wind (mph)7 Precipitation: Sky: Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-14-2020 Time:09:25 Water Volume = 37.17 42.23 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 09:30 37.17 6.16 8.27 10.70 14.90 Cloudy No Sampling Data Zero HS: Method:Date: Time:09:35 Field Parameters a a Sample ID: DuplicateID: Partly Sunny None Wind (mph)3 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. DO (mg/L) ORP (mV) 8.27 10.70 CAP2Q20-PW-07-051420 WEATHER CONDITIONS 65.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 0.81 05-14-2020 Temp.(oC)PFAS20.01 Screen Interval: 28 - 38 6.16pH STABILIZED PARAMETERS 100.52 14.90 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHRIS LICHOROBIEC Joey Vidmar WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PW-07 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 100.52 20.01 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:13:23 Water Volume = 24.81 54 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 13:32 26.25 200.00 10.46 5.01 82.60 5.29 Clear No 13:37 27.20 200.00 10.32 5.10 80.50 5.43 Clear No 13:42 27.58 200.00 10.27 5.19 77.80 2.16 Clear No 13:47 27.74 200.00 10.32 5.12 75.40 1.49 Clear No Sampling Data Zero HS: Method:Date: Time:13:55 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)10 Precipitation: Sky: SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 5.12 75.40 CAP2Q20-PW-09-050720 WEATHER CONDITIONS 66.00 250 mL poly NP 4.67 05-07-2020 Low Flow: Geo Pump Temp.(oC)PFAS19.63 Screen Interval: 44 - 54 10.32pH STABILIZED PARAMETERS 1.49 Spec. Cond.(mS/cm) Turbidity (NTU) DO (mg/L) ORP (mV) = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHARLES PACE Joey Vidmar WATER VOLUME CALCULATION Quarterly Tracy Ovbey 39 above screen PW-09 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 6600Total Volume Purged (gallons): Temp. oC 0.00 20.69 Initial Depth to Water (ft.): Temperature (F): 0.00 19.91 0.00 19.63 RECORD OF WELL SAMPLING Comments 0.00 20.10 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:10:25 Water Volume = 32.81 67.53 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 10:55 32.84 420.00 0.55 4.05 0.11 114.70 8.88 Clear No 11:00 32.88 420.00 0.55 4.05 0.06 115.30 5.85 Clear No 11:05 32.86 420.00 0.55 4.03 0.01 114.20 6.10 Clear No 11:10 32.88 420.00 0.55 4.04 0.00 113.70 9.96 Clear No 11:15 32.89 420.00 0.55 4.04 0.00 111.10 6.69 Clear No Sampling Data Zero HS: Method:Date: Time:11:20 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)6 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.46 17.92 DO (mg/L) ORP (mV)111.10 CAP2Q20-PW-11-050720 WEATHER CONDITIONS 60.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 5.555 05-07-2020 Double valve pump Temp.(oC)PFAS17.90 Screen Interval: 53 - 63 4.04pH STABILIZED PARAMETERS 0.46 6.69 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 BRANDON WEIDNER CL WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen PW-11 Project Manager: Depth to Well Bottom (ft.): Other Spec. Cond. mS/cm 2.75Total Volume Purged (gallons): Temp. oC 0.45 17.82 0.46 17.91 0.46 17.93 0.46 17.90 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-08-2020 Time:11:14 Water Volume = 7.44 47.5 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 11:25 7.44 200.00 4.43 0.22 46.60 6.29 Clear No 11:30 200.00 4.46 0.16 47.90 3.03 Clear No 11:35 200.00 4.45 0.13 46.10 2.26 Clear No 11:40 200.00 4.43 0.11 45.90 2.18 Clear 11:45 200.00 4.45 0.10 44.50 1.83 Clear 11:50 200.00 4.41 0.09 44.50 1.75 Clear 11:55 200.00 4.42 0.09 48.10 1.81 Clear 12:00 200.00 4.44 0.08 44.40 1.78 Clear 12:04 200.00 4.44 0.08 43.60 1.76 Clear 12:10 200.00 4.46 0.08 44.00 1.75 Clear Sampling Data Zero HS: Method:Date: Time:12:15 Field Parameters a a Sample ID: DuplicateID: Partly Sunny None Wind (mph)5 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.11 17.96 DO (mg/L) ORP (mV) 0.08 44.00 CAP2Q20-PZ-22-050820 WEATHER CONDITIONS 63.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 0.361 05-08-2020 Peristaltic Pump Temp.(oC)PFAS17.83 Screen Interval: 36.0-46.0 4.46pH STABILIZED PARAMETERS 0.11 1.75 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville .75 JELANI GILL WATER VOLUME CALCULATION Quarterly Tracy Ovbey bottom of well PZ-22 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm 2.2Total Volume Purged (gallons): Temp. oC 0.11 17.65 0.11 17.85 0.11 17.70 0.11 17.60 0.11 17.75 0.11 17.83 0.11 17.51 0.11 17.63 0.11 17.71 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:09:54 Water Volume = 29.22 45 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 10:26 29.23 250.00 5.11 4.52 118.70 0.98 Clear No 10:31 29.24 250.00 5.02 3.16 122.70 1.05 Clear No 10:36 29.23 250.00 4.99 2.38 122.10 0.34 Clear No 10:41 29.23 250.00 4.98 1.80 120.50 0.00 Clear No 10:46 29.23 250.00 5.2 1.23 110.60 1.13 Clear No 10:51 29.23 250.00 5.33 0.53 98.60 0.61 Clear No 10:56 29.23 250.00 5.44 0.36 92.60 0.99 Clear No 11:01 23.93 250.00 5.41 0.27 87.90 1.58 Clear No 11:06 23.93 250.00 5.42 0.22 82.70 0.22 Clear No 11:10 29.23 250.00 5.46 0.18 77.00 0.01 Clear No 11:16 29.23 250.00 5.43 0.15 71.00 0.31 Clear No 11:21 29.23 250.00 5.43 0.12 65.90 1.63 Clear No 11:26 29.23 250.00 5.3 0.09 61.50 1.93 Clear No 11:31 29.23 250.00 5.07 0.08 57.00 0.37 Clear No 11:36 29.23 250.00 4.92 0.06 53.40 0.27 Clear No 11:41 29.23 250.00 5.34 0.05 51.90 0.03 Clear No Sampling Data Zero HS: Method:Date: Time:11:55 Field Parameters a a Sample ID: DuplicateID: 0.00 27.16 0.00 27.26 0.00 25.75 0.00 26.26 0.00 26.76 0.00 23.64 0.00 24.39 0.00 25.11 0.00 21.18 0.00 22.39 0.00 22.90 0.07 17.37 0.05 17.65 0.00 18.77 RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHARLES PACE Joey Vidmar WATER VOLUME CALCULATION Quarterly Tracy Ovbey above screen SMW-10 Project Manager: Depth to Well Bottom (ft.): Peristaltic Pump Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.07 17.33 Initial Depth to Water (ft.): Temperature (F): 2.525 05-07-2020 Low Flow: Geo Pump Temp.(oC)PFAS27.26 Screen Interval: 39 to 49 5.34pH STABILIZED PARAMETERS 0.03 Spec. Cond.(mS/cm) Turbidity (NTU) 57.00 250 mL poly NP DO (mg/L) ORP (mV) 0.05 51.90 CAP2Q20-SMW-10-050720 WEATHER CONDITIONS Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.07 17.31 Sunny None Wind (mph)13 Precipitation: Sky: Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-07-2020 Time:12:32 Water Volume = 13.53 23 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 12:42 13.66 400.00 4.6 4.49 115.40 29.67 Cloudy No 12:47 13.66 400.00 4.11 4.63 140.10 11.94 Clear No 12:52 13.66 400.00 3.74 4.76 150.60 7.51 Clear No 12:57 13.66 400.00 3.78 4.81 157.20 4.77 Clear No 13:02 13.68 400.00 3.85 4.86 161.10 6.56 Clear No Sampling Data Zero HS: Method:Date: Time:13:10 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)10 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.00 22.59 DO (mg/L) ORP (mV) 4.86 161.10 CAP2Q20-SMW-11-050720 WEATHER CONDITIONS 63.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 1.515 05-07-2020 Low Flow: Geo Pump Temp.(oC)PFAS21.49 Screen Interval: 13 to 23 3.85pH STABILIZED PARAMETERS 6.56 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 CHARLES PACE Joey Vidmar WATER VOLUME CALCULATION Quarterly Tracy Ovbey 18 within screen SMW-11 Project Manager: Depth to Well Bottom (ft.): Spec. Cond. mS/cm Total Volume Purged (gallons): Temp. oC 0.00 23.30 0.00 22.00 0.00 21.79 0.00 21.49 Site Name:Well ID: Well Diameter: Inches Samplers:Event: Purging Data Pump Depth: Pump Loc: Method:Date:05-06-2020 Time:12:25 Water Volume = 83.75 102.01 Time DTW Pump Rate Vol. pH DO Redox Turbidity Color Odor 24 hr. ft. ml/min. gal.mg/L mV NTU 14:00 83.75 350.00 0.92 3.67 0.43 64.00 2.39 Clear Yes 14:05 83.75 350.00 0.46 3.65 0.79 61.10 2.95 Clear Yes sulfur 14:10 83.75 350.00 0.46 3.69 0.78 56.20 2.25 Clear Yes sulfur 14:15 83.75 350.00 0.46 3.73 0.81 53.20 2.15 Clear Yes, sulfur 14:20 83.75 350.00 0.46 3.74 0.88 52.80 1.96 Clear Yes, sulfur 14:25 83.75 350.00 0.46 3.73 0.89 51.70 1.83 Clear Yes, sulfur Sampling Data Zero HS: Method:Date: Time:14:30 Field Parameters a a Sample ID: DuplicateID: Sunny None Wind (mph)13 Precipitation: Sky: Comments SAMPLE SET Table 3+ PFAS Parameter Method EPA 537 Modified PFAS Bottle Table 3 2-250 mL poly 250 mL poly NP NP Pres. 0.20 17.55 DO (mg/L) ORP (mV) 0.89 51.70 CAP2Q20-SMW-12-050620 WEATHER CONDITIONS 67.00 250 mL poly NP Initial Depth to Water (ft.): Temperature (F): 2.922 05-06-2020 Double valve pump Temp.(oC)PFAS17.51 Screen Interval: 88 to 98 3.73pH STABILIZED PARAMETERS 0.20 1.83 Spec. Cond.(mS/cm) Turbidity (NTU) RECORD OF WELL SAMPLING = (Total Depth of Well - Depth To Water ) x Casing Volume per Foot Chemours Fayetteville 2 BRANDON WEIDNER Chris L. WATER VOLUME CALCULATION Quarterly Tracy Ovbey within screen SMW-12 Project Manager: Depth to Well Bottom (ft.): Other Spec. Cond. mS/cm 3.234Total Volume Purged (gallons): Temp. oC 0.20 17.91 0.20 17.51 0.20 17.88 0.20 17.63 0.20 17.53 Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 18:15 6.71 8.24 13.00 11.77 19.84 Clear No Sampling Data Method: Pres. NP NP NP 75.00 Sunny None 5 Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville KEN STUART, Tracy Ovbey CFR-BLADEN Project Manager: Quarterly CAP EPA 537 Modified Comments Peri Pump Grab WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS GPS Location (if collected) Wind (mph) Precipitation: 05-13-2020 Latitude: 34.7720656358029 -78.7980093621451 Table 3 Table 3+ 0.09 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-CFR-BLADEN- 051320 Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-19-2020 09:25 6.65 6.44 25.30 21.44 21.71 Clear No Sampling Data Method: Pres. NP NP NP 68.00 Cloudy None 8 Insitu AquaTroll Marsh McBirney 14 Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:0 Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-KINGS Project Manager: Quarterly CAP EPA 537 Modified Comments Peri Pump Grab Method ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS GPS Location (if collected) Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: 05-19-2020 Latitude: 34.4062206 -78.2948724 Table 3 Table 3+ 0.10 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-CFR-KINGS- 051920 SAMPLE SET Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 08:20 6.99 7.58 -5.10 6.62 17.72 Clear None X Sampling Data Method: Pres. NP NP NP 52.00 Sunny None 6 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-CFR-RM-76- 051320 05-13-2020 liters per minute Latitude: 34.8537133355018 -78.8271112461377 Table 3 Table 3+ 0.12 Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate:0.25 SW SEEP SAMPLING RECORD Chemours Fayetteville KEN STUART, Luke Tart Tracy Ovbey CFR-RM-76 Project Manager: Quarterly CAP EPA 537 Modified Comments Peri Pump Grab Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-14-2020 08:55 6.95 8.01 -15.70 6.79 19.21 Clear No Sampling Data Method: Pres. NP NP NP 61.00 Sunny None 5 Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville KEN STUART, Tracy Ovbey CFR-TARHEEL Project Manager: Quarterly CAP EPA 537 Modified Comments Peri Pump Grab WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS GPS Location (if collected) Wind (mph) Precipitation: 05-14-2020 Latitude: 34.7448907513495 -78.7852952723194 Table 3 Table 3+ 0.11 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-CFR-TARHEEL- 051420 Site Name:Location ID: Samplers:Sampling Event: Date:Time: Spl Date Time pH DO Redox Turbidity Temp.Color Odor QA/QC mg/L mV NTU oC Sampling Data Pres. NP NP NP NP NP NP NP Sunny None Longitude: GPS Location (if collected) Table 3+ (21)(HL) Including HPFO-DA and PFHpA PFAS 250 mL poly 537 MOD (HOLD) 11:30 General Comments: Latitude: ISCO Composite Method 250 mL poly ISCO Start Date and Time: ISCO End Date and Time: Sampling Method: Spl ID CAP2Q20-TARHEEL-24-051420 Multi Meter Used: SAMPLE SET PFAS 250 mL poly BottleParameter 2-250 mL poly Wind (mph) Precipitation: SURFACE WATER SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER|Sampling CFR-TARHEEL Quarterly CAP Tracy Ovbey Event Type: Project Manager: 05-14-2020 20:50 Spec. Cond. µS/cm 05-18-2020 PFAS PFAS Temperature (F): Sky: Table 3+ (19)(LL) Table 3+ (20)(LL) WEATHER CONDITIONS PFAS 250 mL poly Table 3+ (19)(HL) PFAS 250 mL poly Table 3+ (21)(LL) Including HPFO-DA and PFHpA PFAS 250 mL poly Comments ALL PARAMETERS ANALYZED 537 Mod Including HFPO-DA; Table 3+ (20)(LL) 537 Mod Including HFPO-DA 05-14-2020 20:50 Multi Meter ID: 05-13-2020 21:50 Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 13:55 4.53 8.52 26.50 16.22 17.46 Clear None Sampling Data Method: Pres. NP NP NP 73.00 Sunny None 4 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-GBC-1-051320 05-13-2020 Latitude: 34.8149652639728 -78.8214334287483 Table 3 Table 3+ 0.10 Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey GBC-1 Project Manager: Quarterly CAP EPA 537 Modified Comments Bottle Grab Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 11:30 3.54 8.58 221.40 5.22 18.04 Clear None 05-14-2020 13:05 3.46 8.35 193.60 0.00 22.41 Clear None Sampling Data Sample Date:5/14/2020 Sample Time:13:05 Method: Sample ID: Pres. NP NP NP 70.00 Sunny None 4 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-13-2020 Latitude: 0 0 Table 3 Table 3+ 267.54 Longitude: Spec. Cond. mS/cm 520.780 GPS Location (if collected) Wind (mph) Precipitation: Comments Start parameters. 24H ISCO Composite WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gill Tracy Ovbey OLDOF-2 Project Manager: Quarterly CAP End parameters. CAP2Q20-OLDOF-1-24-051420 Temperature (F): Sky: Flow Rate: EPA 537 Modified Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 10:17 6.58 9.09 54.40 8.54 19.86 Clear None 05-14-2020 11:50 6.26 8.06 151.40 4.21 23.84 Clear None Sampling Data Sample Date:5/14/2020 Sample Time:11:50 Method: Sample ID: Pres. NP NP NP 65.00 Sunny None 2 Comments Start parameters. 24H ISCO Composite SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gill Tracy Ovbey OUTFALL 002 Project Manager: Quarterly CAP Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET 250 mL poly PFAS PFAS Temperature (F): Sky: EPA 537 Modified GPS Location (if collected) 666.000 ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) Flow Rate: Latitude: 0 0 Table 3 Table 3+ Longitude: End parameters. CAP2Q20-OUTFALL 002-24-051420 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-15-2020 125.70 Spec. Cond. mS/cm Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 5/13/2020 09:45 3.95 8.94 131.50 12.53 15.45 Clear No 5/14/2020 10:40 3.90 8.39 134.40 2.55 23.01 Clear No Sampling Data Sample Date:5/14/2020 Sample Time:10:45 Method: Sample ID: Pres. NP NP NP 61.00 Sunny None 2 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-15-2020 Latitude: 0 0 Table 3 Table 3+ 150.00 Longitude: Spec. Cond. mS/cm 229.440 GPS Location (if collected) Wind (mph) Precipitation: Comments Start parameters. 24H ISCO Composite WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J.Gills Tracy Ovbey SEEP-A-1 Project Manager: Quarterly CAP End parameters. CAP2Q20-SEEP-A-24-051420 Temperature (F): Sky: Flow Rate: EPA 537 Modified Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 10:25 4.41 7.63 65.60 10.15 16.38 Clear None 05-14-2020 11:20 4.05 8.17 148.20 1.31 23.03 Clear None Sampling Data Sample Date:5/14/2020 Sample Time:11:20 Method: Sample ID: Pres. NP NP NP 66.00 Sunny None 4 Comments Start parameters. 24H ISCO Composite SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gill Tracy Ovbey SEEP-B-1 Project Manager: Quarterly CAP Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET 250 mL poly PFAS PFAS Temperature (F): Sky: EPA 537 Modified GPS Location (if collected) 313.220 ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) Flow Rate: Latitude: 0 0 Table 3 Table 3+ Longitude: End parameters. CAP2Q20-SEEP-B-24-051420 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-15-2020 112.60 Spec. Cond. mS/cm Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 10:35 4.50 8.37 61.10 34.26 15.92 Clear None 05-14-2020 11:40 4.16 8.11 131.40 3.70 23.95 Clear None Sampling Data Sample Date:5/14/2020 Sample Time:11:40 Method: Sample ID: Pres. NP NP NP 67.00 Sunny None 4 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-13-2020 Latitude: 0 0 Table 3 Table 3+ 113.67 Longitude: Spec. Cond. mS/cm 239.890 GPS Location (if collected) Wind (mph) Precipitation: Comments Start parameters. 24H ISCO Composite WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gill Tracy Ovbey SEEP-C-1 Project Manager: Quarterly CAP End parameters CAP2Q20-SEEP-C-24-051420 Temperature (F): Sky: Flow Rate: EPA 537 Modified Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 10:55 3.92 8.44 77.40 23.55 16.52 Clear None 05-14-2020 12:15 3.86 8.25 175.80 0.01 22.77 Clear None Sampling Data Sample Date:5/14/2020 Sample Time:12:15 Method: Sample ID: Pres. NP NP NP 70.00 Sunny None 4 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-13-2020 Latitude: 0 0 Table 3 Table 3+ 157.87 Longitude: Spec. Cond. mS/cm 260.690 GPS Location (if collected) Wind (mph) Precipitation: Comments Start parameters. 24H ISCO Composite WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gill Tracy Ovbey SEEP-D-1 Project Manager: Quarterly CAP End parameters. CAP2Q20-SEEP-D-24-051420 Temperature (F): Sky: Flow Rate: EPA 537 Modified Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 5/13/2020 09:20 5.74 8.72 34.90 5.53 15.70 Murky No 5/14/2020 10:15 4.59 8.17 128.20 4.54 23.58 Clear No Sampling Data Sample Date:5/14/2020 Sample Time:10:15 Method: Sample ID: Pres. NP NP NP 64.00 Sunny None 4 Comments Start parameters. 24H ISCO Composite SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, J. Gills Tracy Ovbey WC-1 Project Manager: Quarterly CAP Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET 250 mL poly PFAS PFAS Temperature (F): Sky: EPA 537 Modified GPS Location (if collected) 150.510 ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) Flow Rate: Latitude: 0 0 Table 3 Table 3+ Longitude: End parameters. CAP2Q20-WC-1-24-051420 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID 05-13-2020 0.10 Spec. Cond. mS/cm Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 03-31-2020 12:00 Yes Sampling Data Method: Pres. NP NP NP Partly Sunny None PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-033120 03-31-2020 Latitude: 0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED Table 3 (Special); Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-02-2020 13:00 Sampling Data Method: Pres. NP NP NP Sunny None PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-48-040220 04-02-2020 Latitude: 0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED Table 3 (Special); Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 0:30 Sampling Data Method: Pres. NP NP NP 78.00 1.8 Sunny 78 None 0 9 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-040620 04-06-2020 Latitude: 0 0 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED 0 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-09-2020 06:30 Sampling Data Method: Pres. NP NP NP 72.00 Sunny None 14 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-040920 SAMPLE SET 04-09-2020 Latitude:0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-040920 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) SW SEEP SAMPLING RECORD Chemours Fayetteville 0 Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-19-2020 01:30 Sampling Data Method: Pres. NP NP NP 70.00 Sunny None 6 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-041920 SAMPLE SET 04-19-2020 Latitude:0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-041920 Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville 0 Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth BOTTOM half of water column (ft): Samples taken from:0 Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-22-2020 13:30 Sampling Data Method: Pres. NP NP NP 66.00 Sunny None 1 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-042220 SAMPLE SET 04-27-2020 Latitude:0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-042220 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-26-2020 00:49 Sampling Data Method: Pres. NP NP NP 72.00 Cloudy Rain Marsh McBirney Stream Depth BOTTOM half of water column (ft): Samples taken from: ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): GPS Location (if collected) 04-30-2020 Latitude: 0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-042620 SAMPLE SET Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 04-29-2020 11:49 Sampling Data Method: Pres. NP NP NP 72.00 Cloudy Rain Marsh McBirney Stream Depth BOTTOM half of water column (ft): Samples taken from: ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): GPS Location (if collected) 04-30-2020 Latitude: 0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-042920 SAMPLE SET Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-02-2020 23:49 Sampling Data Method: Pres. NP NP NP 86.00 7 Sunny 29 None 0 12 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-62-050220 05-04-2020 Latitude: 0 0 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-06-2020 11:49 Sampling Data Method: Pres. NP NP NP 68.00 Sunny None 8 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-050620 SAMPLE SET 05-06-2020 Latitude: 0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville , E. Helton Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth BOTTOM half of water column (ft): Samples taken from: ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-09-2020 11:49 Sampling Data Method: Pres. NP NP NP 67.00 Sunny None 15 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-050920 SAMPLE SET 05-09-2020 Latitude:0 0 Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-050920 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville 0 Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth BOTTOM half of water column (ft): Samples taken from:Isco Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-13-2020 09:49 Sampling Data Method: Pres. NP NP NP 75.00 0.9 Sunny 25 None 0 6 PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-051320 05-13-2020 Latitude: 0 0 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments No parameters collected. 3.5 Day Composite Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-14-2020 08:55 6.95 8.01 -15.70 6.79 19.21 Clear No Sampling Data Method: Pres. NP NP NP 61.00 Sunny None 5 Temperature (F): Sky: Flow Rate: SW SEEP SAMPLING RECORD Chemours Fayetteville KEN STUART, Tracy Ovbey CFR-TARHEEL Project Manager: Quarterly CAP EPA 537 Modified Comments Peri Pump Grab WEATHER CONDITIONS Method SAMPLE SET ALL PARAMETERS ANALYZED EPA 537 Modified; Table 3+(20) 250 mL poly PFAS PFAS GPS Location (if collected) Wind (mph) Precipitation: 05-14-2020 Latitude: 34.7448907513495 -78.7852952723194 Table 3 Table 3+ 0.11 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-CFR-TARHEEL- 051420 Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-16-2020 19:49 Sampling Data Method: Pres. NP NP NP Sunny 29 None 0 84 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-051620 SAMPLE SET 05-18-2020 Latitude:0 0 Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-051620 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC Maintenance Comment: Sampling Data Method: Pres. NP NP NP Marsh McBirney Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments No parameters taken WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: ALL PARAMETERS ANALYZED 0 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER Sampling CFR-TARHEEL Quarterly CAP Samples taken from: ISCO Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: 05-18-2020 Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CAP2Q20-TARHEEL-24- 051820 ISCO sample date/time SAMPLE SET 24H ISCO Composite Method 05-18-2020 11:30 Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-20-2020 08:49 Sampling Data Method: Pres. NP NP NP 65.00 Partly Cloudy 18 None 20 3 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-052020 SAMPLE SET 05-20-2020 Latitude:0 0 Temperature, deg C: Rain, mm: Table 3 Table 3+ Longitude: Spec. Cond. mS/cm GPS Location (if collected) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: EPA 537 Modified Comments Actual Sample ID: CFR-TARHEEL-83-052020 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) SW SEEP SAMPLING RECORD Chemours Fayetteville LUKE TART Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 7.41 7.09 59.10 41.76 21.35 Cloudy No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 80.00 Sunny None 4 Bailer Method 250 mL poly Samples taken from: Spl ID CFR-TARHEEL-052520 SAMPLE SET PFAS 250 mL poly BottleParameter 2-250 mL poly Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER|JELANI GILL Sampling CFR-TARHEEL Other Project Manager: Tracy Ovbey Event Type: 0 regular sampling date10:15 ISCO Start Date and Time:05-25-2020 Latitude: 53.17 Longitude: Spec. Cond. µS/cm WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments High River Sample ALL PARAMETERS ANALYZED Table 3+(20) Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 05-29-2020 09:10 7.80 3.39 18.80 99.24 22.77 Cloudy None Sampling Data Method: Pres. NP NP NP 24.00 14.92 Cloudy 24 Rain 32 Insitu AquaTroll Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-052920 SAMPLE SET 05-29-2020 Latitude: 34.7449454 -78.7850703 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 3060.00 Longitude: Spec. Cond. mS/cm River level GPS Location (if collected) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: EPA 537 Modified Comments Grab sample Bailer Method ALL PARAMETERS ANALYZED Table 3+(20) SW SEEP SAMPLING RECORD Chemours Fayetteville MEGAN JUNOD, Ken Stuart Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Samples taken from:0 Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): 706682 Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06-01-2020 14:25 8.11 6.26 -132.20 38.96 25.59 Murky None Yes Sampling Data Method: Pres. NP NP NP 75.00 Sunny None 3 Insitu AquaTroll Marsh McBirney Stream Depth BOTTOM half of water column (ft): Samples taken from: Bank Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER, Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments Sample taken from bailer on the bank of river since ISCO sampled is Bailer Method ALL PARAMETERS ANALYZED 0 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): GPS Location (if collected) 06-01-2020 Latitude: 0 0 Table 3 Table 3+ 211.70 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-060120 SAMPLE SET Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06-05-2020 10:55 8.73 0.00 26.50 26.94 26.17 Very lt tan No Sampling Data Method: Pres. NP NP NP 79.00 14.4 Partly Cloudy 32 None 42 8 Insitu AquaTroll Marsh McBirney Stream Depth BOTTOM half of water column (ft): Samples taken from: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS SW SEEP SAMPLING RECORD Chemours Fayetteville KEN STUART, Megan Junod Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River EPA 537 Modified Comments Grab sample, isco set and started on 060520 at 1106, for cycle 1 Peri Pump Grab Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): Photo after isco set GPS Location (if collected) 06-05-2020 Latitude:34.7449648 -78.7851074 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 10.09 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-060520 SAMPLE SET Site Name:Location ID: Samplers:Event: Date:Start Date:6/5/2020 Start Time:11:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06-08-2020 21:06 8.13 7.62 -47.00 6.12 17.93 Sampling Data Method: Pres. NP NP NP 83.00 Cloudy None Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-39-060820 SAMPLE SET 6/8/2020 Latitude:0 0 Table 3 Table 3+ 162.47 Longitude: Spec. Cond. mS/cm GPS Location (if collected) PFAS PFAS Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): EPA 537 Modified Comments No liquid from 6/6/20 1506 to 6/8/20 1106. Time in field notebook 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date:Start Date:6/8/2020 Start Time:22:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06-12-2020 08:06 7.96 8.30 27.90 6.09 14.19 Clear None Sampling Data Method: Pres. NP NP NP 17.00 4.8 Cloudy 17 Rain 33 7 Marsh McBirney PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-061220 SAMPLE SET PFAS PFAS 6/12/2020 Latitude:0 0 Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 0.19 Longitude: Spec. Cond. mS/cm GPS Location (if collected) Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Depth TOP half of water column (ft): EPA 537 Modified Comments 3.5 Day Composite Method ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER Tracy Ovbey CFR-TARHEEL Project Manager: Weekly River Stream Depth BOTTOM half of water column (ft): Samples taken from:ISCO Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: Total Water Depth (ft): Temperature (F): Sky: Flow Rate: WEATHER CONDITIONS Site Name:Location ID: Samplers:Event: Date:Start Date:06/12/20 Start Time:9:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06/15/20 19:06 8.51 8.02 -15.80 11.25 20.92 Cloudy None Maintenance Comment: Sampling Data Method: Pres. NP NP NP 66.00 9.5 Cloudy 19 None 30 5 Marsh McBirney Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments ALL PARAMETERS ANALYZED WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: Table 3+(20) 250 mL poly Velocity Meter ID: GPS Location (if collected) SW SEEP SAMPLING RECORD Chemours Fayetteville BRANDON WEIDNER Sampling CFR-TARHEEL Weekly River Project Manager: Tracy Ovbey Event Type: Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Stream Depth TOP half of water column (ft): 0.11 Longitude: Spec. Cond. mS/cm Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ ISCO PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-061520 SAMPLE SET 3.5 Day Composite Method 6/15/2020 Samples taken from: Site Name:Location ID: Samplers:Event: Date:Start Date:06/15/20 Start Time:20:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06/19/20 6:06 8.12 7.33 -10.60 29.09 22.45 Clear No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 80.00 10.5 Partly Cloudy 32 None 0 3 Insitu AquaTroll Marsh McBirney Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments ALL PARAMETERS ANALYZED WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: Table 3+(20) 250 mL poly 706682 Velocity Meter ID: GPS Location (if collected) SW SEEP SAMPLING RECORD Chemours Fayetteville LUKE TART, Sharon Moran Sampling CFR-TARHEEL Weekly River Project Manager: Tracy Ovbey Event Type: Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Stream Depth TOP half of water column (ft): 0.25 Longitude: Spec. Cond. mS/cm Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Isco PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-061920 SAMPLE SET 3.5 Day Composite Method 06-19-2020 Samples taken from: Site Name:Location ID: Samplers:Event: Date:Start Date:6/19/2020 Start Time:7:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 06/22/20 17:06 8.39 7.23 21.10 28.25 22.58 Clear None Maintenance Comment: Sampling Data Method: Pres. NP NP NP 88.00 9.9 Sunny 35 None 0 12 Insitu AquaTroll Marsh McBirney Total Water Depth (ft):GPS Location (if collected) Stream Velocity TOP half of water column (ft/sec):Stream Depth TOP half of water column (ft): Stream Velocity BOTTOM half of water column (ft/sec):Stream Depth BOTTOM half of water column (ft): Wind (mph) Multi Meter Used:Multi Meter ID:706682 Velocity Meter Used:Velocity Meter ID: Sky:Temperature, deg C: Precipitation:Rain, mm:Flow Rate: PFAS 250 mL poly Table 3+ WEATHER CONDITIONS Temperature (F):Staff gauge water level, ft: Parameter Bottle Method Table 3+(20) PFAS 2-250 mL poly EPA 537 Modified PFAS 250 mL poly Table 3 Longitude: Samples taken from:Isco SAMPLE SET ALL PARAMETERS ANALYZED CFR-TARHEEL-83-062220 0.07 Latitude: 3.5 Day Composite 6/22/2020 Spl ID Spec. Cond.Comments mS/cm SW SEEP SAMPLING RECORD Chemours Fayetteville CFR-TARHEEL Project Manager: Tracy Ovbey LUKE TART, Jacob Limpus Weekly River Event Type: Sampling Site Name:Location ID: Samplers:Event: Date:Start Date:06/22/20 Start Time:18:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 6/26/2020 4:06 7.64 9.29 98.80 11.41 16.79 Murky No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 80.00 2.75 Sunny 36.7 None 51 Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville JELANI GILL, Eric Helton Sampling CFR-TARHEEL Weekly River Samples taken from: Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: 06-26-2020 Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 0.07 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-062620 SAMPLE SET 3.5 Day Composite Method Site Name:Location ID: Samplers:Event: Date:Start Date:06/26/20 Start Time:5:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 6/29/2020 15:06 7.49 7.50 103.90 9.03 22.83 Murky No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 75.00 2 Sunny 23 None 7 6 Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Jacob Limpus Sampling CFR-TARHEEL Weekly River Samples taken from:0 Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: 07-02-2020 Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 0.08 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-83-062920 ISCO sample date/time SAMPLE SET 3.5 Day Composite Method Site Name:Location ID: Samplers:Event: Date:Start Date:06/29/20 Start Time:16:06 Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 7/2/2020 8:06 7.64 7.57 103.00 6.29 23.92 Murky No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 75.00 2 Sunny 23 None 7 6 Marsh McBirney Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Jacob Limpus Sampling CFR-TARHEEL Weekly River Samples taken from:0 Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): Velocity Meter ID: 07-02-2020 Latitude: Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ 0.08 Longitude: Spec. Cond. mS/cm PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-65-070220 ISCO sample date/time SAMPLE SET 3.5 Day Composite Method Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 6.52 7.30 111.60 3.48 25.61 Murky No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 77.00 1.7 Cloudy 24 Rain 60 4 Insitu AquaTroll PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-24-070320 SAMPLE SET 24H ISCO Composite Method 0.76 Longitude: Spec. Cond. mS/cm Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): 706720 Velocity Meter ID: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Jacob Limpus Sampling CFR-TARHEEL Weekly River Samples taken from:ISCO 07-03-2020 07:29 ISCO Start Date and Time:07-07-2020 Latitude: WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: 7/2/2020 8:29 Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 7.34 7.43 85.50 13.92 25.86 Murky No Maintenance Comment: Sampling Data Method: Pres. NP NP NP 77.00 1.7 Cloudy 24 Rain 60 4 Insitu AquaTroll PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-24-070720 SAMPLE SET 24H ISCO Composite Method 0.16 Longitude: Spec. Cond. mS/cm Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): 706720 Velocity Meter ID: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Jacob Limpus Sampling CFR-TARHEEL Weekly River Samples taken from:ISCO 07-07-2020 07:29 ISCO Start Date and Time:07-07-2020 Latitude: WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: 07-06-2020 08:29 Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments Site Name:Location ID: Samplers:Event: Date: Spl Date Time pH DO Redox Turbidity Temp.Color Odor Dup mg/L mV NTU oC 6.83 7.21 163.20 58.97 26.96 Murky No Dup Maintenance Comment: Sampling Data Method: Pres. NP NP NP 92.00 1.7 Sunny 36 None 71 4 Insitu AquaTroll PFAS 250 mL poly BottleParameter 2-250 mL poly Spl ID CFR-TARHEEL-24-071020 SAMPLE SET 24H ISCO Composite Method 0.19 Longitude: Spec. Cond. mS/cm Staff gauge water level, ft: Temperature, deg C: Rain, mm: Table 3 Table 3+ Wind (mph) Precipitation: Multi Meter Used: Velocity Meter Used: Multi Meter ID: Stream Velocity TOP half of water column (ft/sec): Stream Velocity BOTTOM half of water column (ft/sec): 706720 Velocity Meter ID: ALL PARAMETERS ANALYZED Table 3+(20) 250 mL poly SW SEEP SAMPLING RECORD Chemours Fayetteville CHARLES PACE, Jacob Limpus Sampling CFR-TARHEEL Weekly River Samples taken from:ISCO 07-10-2020 11:01 ISCO Start Date and Time:07-10-2020 Latitude: WEATHER CONDITIONS EPA 537 ModifiedPFAS PFAS Total Water Depth (ft): Temperature (F): Sky: 07-09-2020 12:01 Project Manager: Tracy Ovbey Event Type: GPS Location (if collected) Stream Depth TOP half of water column (ft): Stream Depth BOTTOM half of water column (ft): Flow Rate: Comments DUP Taken of this sample APPENDIX E Laboratory Reports and DVM Report ADQM Data Review Narrative - FAY CAP MW Sampling 2Q20.doc 1 of 3 ADQM DATA REVIEW NARRATIVE Site Chemours FAY – Fayetteville Project CAP MW Sampling 2Q20 Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates May 6 – 8, 2020 May 12 – 14, 2020 Analytical Protocol Laboratory Analytical Method Parameter(s) TestAmerica - Sacramento 537 Modified PFAS(1) TestAmerica - Sacramento Cl. Spec. Table 3 Compound SOP Table 3+ compounds 1 Perfluoroalkylsubstances, a list of 37 compounds including HFPO-DA. Sample Receipt The following items are noted for this data set: • All samples were received in satisfactory condition and within EPA temperature guidelines on: May 9, 2020 May 12, 2020 May 15, 2020 Data Review Please note the following byproduct parameter names have been updated as follows: Old CASN New CASN New Common Name Previous Common Name EVS1429 2416366-18-0 R-PSDA Byproduct 4 EVS1430 2416366-19-1 Hydrolyzed PSDA Byproduct 5 EVS1431 2416366-21-5 R-PSDCA Byproduct 6 29311-67-9 (unchanged) 29311-67-9 (unchanged) PS Acid PFESA-BP1 749836-20-2 (unchanged) 749836-20-2 (unchanged) Hydro-PS Acid PFESA-BP2 ADQM Data Review Narrative - FAY CAP MW Sampling 2Q20.doc 2 of 3 The electronic data submitted for this project was reviewed via the Data Verification Module (DVM) process. Overall the data is acceptable for use without qualification, except as noted below: • The laboratory reported HFPO-DA from both the 537 Modified and Table 3+ analysis for several samples. The best value field was populated to report the “better” result for each sample according to the following criteria: o The higher concentration of two detects was reported. o The detected value was reported when a detect and a non-detect result were evaluated. o The lower reporting limit was reported when two non-detect results were evaluated. • Some Table 3 results were qualified B and the reported results may be biased high, or false positives, due to a comparable concentration found in the associated equipment blank. • PFBS in one sample and the associated field duplicate sample have been qualified J as estimated due to poor field duplicate precision. See the Data Verification Module (DVM) Narrative Report for which samples were qualified, the specific reasons for qualification, and potential bias in reported results. Attachments The DVM Narrative report is attached. The lab reports due to a large page count are stored on an AECOM network shared drive and are available to be posted on external shared drives, or on a flash drive. ADQM Data Review Narrative - FAY CAP MW Sampling 2Q20.doc 3 of 3 Data Verification Module (DVM) The DVM is an internal review process used by the ADQM group to assist with the determination of data usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software (Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks: • Field and laboratory blank contamination • US EPA hold time criteria • Missing Quality Control (QC) samples • Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences (RPDs) between these spikes • Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD between these spikes • Surrogate spike recoveries for organic analyses • RPD between field duplicate sample pairs • RPD between laboratory replicates for inorganic analyses • Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab descriptors they are not to be used when evaluating the data. Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data evaluation qualifiers to analysis results, as warranted: Qualifier Definition B Not detected substantially above the level reported in the laboratory or field blanks. R Unusable result. Analyte may or may not be present in the sample. J Analyte present. Reported value may not be accurate or precise. UJ Not detected. Reporting limit may not be accurate or precise. The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank. If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier. DVM Narrative ReportContamination detected in equipment blank(s). Sample result does not differ significantly from the analyte concentration detected in the associatedequipment blank(s).LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP MW Sampling 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-PIW-1D-050720 05/07/2020 320-60761-4PFMOAA17 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.21PQLCAP2Q20-PIW-3D-050720 05/07/2020 320-60761-1PFMOAA5.1 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.21PQLCAP2Q20-PW-09-050720 05/07/2020 320-60761-5Hfpo Dimer Acid0.0050 UG/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.0020PQLCAP2Q20-PW-09-050720 05/07/2020 320-60761-5PFO2HxA0.0048 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.0020PQLCAP2Q20-PW-09-050720 05/07/2020 320-60761-5PFMOAA0.0080 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.0050PQLCAP2Q20-SMW-10-05072005/07/2020 320-60761-7PFMOAA0.040 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.0050PQLCAP2Q20-SMW-11-05072005/07/2020 320-60761-6PFO2HxA3.3 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.081PQLCAP2Q20-SMW-11-05072005/07/2020 320-60761-6PFO3OA0.62 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.058PQLCAP2Q20-SMW-11-05072005/07/2020 320-60761-6PFMOAA3.4 ug/LCl. Spec. Table 3Compound SOPBPFAS_DI_Prep0.21PQLPage 1 of 2 High relative percent difference (RPD) observed between field duplicate and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP MW Sampling 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-BLADEN-1D-050620-D05/06/2020 320-60762-5PerfluorobutaneSulfonic Acid0.024 UG/L537 ModifiedJ3535_PFC0.0020PQLPage 2 of 2 ADQM Data Review Narrative - FAY CAP SW Sampling 2Q20.doc 1 of 3 ADQM DATA REVIEW NARRATIVE Site Chemours FAY – Fayetteville Project CAP SW Sampling 2Q20 Project Reviewer Michael Aucoin, AECOM as a Chemours contractor Sampling Dates May 13- 14, 2020 May 18 – 19, 2020 May 21, 2020 Analytical Protocol Laboratory Analytical Method Parameter(s) TestAmerica - Sacramento 537 Modified PFAS(1) Eurofins Lancaster (Lancaster) EPA 537 Rev. 1.1 modified PFAS(1) TestAmerica - Sacramento Cl. Spec. Table 3 Compound SOP Table 3+ compounds Lancaster Cl. Spec. Table 3 Compound SOP Table 3+ compounds 1 Perfluoroalkylsubstances, a list of 36 or 37 compounds including HFPO-DA; TestAmerica reported NaDONA and ADONA while Lancaster reported DONA. Sample Receipt The following items are noted for this data set: • All samples were received in satisfactory condition and within EPA temperature guidelines on: May 15, 2020 May 22, 2020 Data Review Please note the following byproduct parameter names have been updated as follows: Old CASN New CASN New Common Name Previous Common Name EVS1429 2416366-18-0 R-PSDA Byproduct 4 EVS1430 2416366-19-1 Hydrolyzed PSDA Byproduct 5 ADQM Data Review Narrative - FAY CAP SW Sampling 2Q20.doc 2 of 3 EVS1431 2416366-21-5 R-PSDCA Byproduct 6 29311-67-9 (unchanged) 29311-67-9 (unchanged) PS Acid PFESA-BP1 749836-20-2 (unchanged) 749836-20-2 (unchanged) Hydro-PS Acid PFESA-BP2 The electronic data submitted for this project was reviewed via the Data Verification Module (DVM) process. Overall the data is acceptable for use without qualification, except as noted below: • The laboratory reported HFPO-DA from both the 537 Modified and Table 3+ analysis for several samples. The best value field was populated to report the “better” result for each sample according to the following criteria: o The higher concentration of two detects was reported. o The detected value was reported when a detect and a non-detect result were evaluated. o The lower reporting limit was reported when two non-detect results were evaluated. • Professional judgement was used to overwrite R qualifiers, indicating an unusable result, that were assigned by the DVM to non-detect results due to a very poor surrogate (isotope dilution analyte or IDA) recovery, for N-methyl perfluoro-1-octanesulfonamide and N-ethyl perfluoro-1-octanesulfonamide in two samples. Data quality is not considered affected by the laboratory if the IDA signal-to-noise ratio is greater than 10:1, which was achieved for all IDA in the samples. • Some analytical results have been qualified J as estimated, and non-detect results qualified UJ indicating an estimated reporting limit, due to a poor recovery of a lab control spike or matrix spike; and poor lab replicate precision. See the Data Verification Module (DVM) Narrative Report for which samples were qualified, the specific reasons for qualification, and potential bias in reported results. Attachments The DVM Narrative report is attached. The lab reports due to a large page count are stored on an AECOM network shared drive and are available to be posted on external shared drives, or on a flash drive. ADQM Data Review Narrative - FAY CAP SW Sampling 2Q20.doc 3 of 3 Data Verification Module (DVM) The DVM is an internal review process used by the ADQM group to assist with the determination of data usability. The electronic data deliverables received from the laboratory are loaded into the Locus EIM™ database and processed through a series of data quality checks, which are a combination of software (Locus EIM™ database Data Verification Module (DVM)) and manual reviewer evaluations. The data is evaluated against the following data usability checks: • Field and laboratory blank contamination • US EPA hold time criteria • Missing Quality Control (QC) samples • Matrix spike(MS)/matrix spike duplicate (MSD) recoveries and the relative percent differences (RPDs) between these spikes • Laboratory control sample(LCS)/control sample duplicate (LCSD) recoveries and the RPD between these spikes • Surrogate spike recoveries for organic analyses • RPD between field duplicate sample pairs • RPD between laboratory replicates for inorganic analyses • Difference / percent difference between total and dissolved sample pairs. There are two qualifier fields in EIM: Lab Qualifier is the qualifier assigned by the lab and may not reflect the usability of the data. This qualifier may have many different meanings and can vary between labs and over time within the same lab. Please refer to the laboratory report for a description of the lab qualifiers. As they are lab descriptors they are not to be used when evaluating the data. Validation Qualifier is the 3rd party formal validation qualifier if this was performed. Otherwise this field contains the qualifier resulting from the ADQM DVM review process. This qualifier assesses the usability of the data and may not equal the lab qualifier. The DVM applies the following data evaluation qualifiers to analysis results, as warranted: Qualifier Definition B Not detected substantially above the level reported in the laboratory or field blanks. R Unusable result. Analyte may or may not be present in the sample. J Analyte present. Reported value may not be accurate or precise. UJ Not detected. Reporting limit may not be accurate or precise. The Validation Status Code field is set to “DVM” if the ADQM DVM process has been performed. If the DVM has not been run, the field will be blank. If the DVM has been run (Validation Status Code equals “DVM”), use the Validation Qualifier. DVM Narrative ReportAssociated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-EB-PP-051920 05/19/2020 410-2520-3PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-EB-PP-051920 05/19/2020 410-2520-3PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-EB-PP-051920 05/19/2020 410-2520-3Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-EB-PP-051920 05/19/2020 410-2520-3Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3Hfpo Dimer Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3Hfpo Dimer Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051420 05/14/2020 410-2521-3Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051920 05/19/2020 410-2520-2PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051920 05/19/2020 410-2520-2PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051920 05/19/2020 410-2520-2Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-FB-051920 05/19/2020 410-2520-2Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 1 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1PFO4DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4R-PSDCA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4R-PSDCA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4PS Acid0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4PS Acid0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3PS Acid0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3PS Acid0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hydro-PS Acid0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-PSDCA0.0020 UG/LCl. Spec. Table 3CompoundUJPFAS_DI_Prep0.0020PQLPage 2 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit but above 10%. The actual detectionlimits may be higher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-PSDCA0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PS Acid0.0020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 3 of 13 Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit. The actual detection limits may behigher than reported.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PEPA0.020 UG/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PFO5DA0.0020 ug/LCl. Spec. Table 3Compound SOPUJPFAS_DI_Prep0.0020PQLPage 4 of 13 One or more surrogates had relative percent recovery (RPR) values less than the data rejection level. The reported result is consid-ered to be an estimated value.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1N-methyl perfluoro-1-octanesulfonamide0.0030 ug/L537 ModifiedUJ3535_PFC0.0030PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1N-ethylperfluoro-1-octanesulfonamide0.0050 UG/L537 ModifiedUJ3535_PFC0.0050PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5N-methyl perfluoro-1-octanesulfonamide0.0030 ug/LEPA 537 Rev.1.1 modifiedUJ3535_PFC0.0030PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5N-ethylperfluoro-1-octanesulfonamide0.0050 UG/LEPA 537 Rev.1.1 modifiedUJ3535_PFC0.0050PQLPage 5 of 13 Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-EVE0.047 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-EVE0.046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-PSDA0.073 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5R-PSDA0.072 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4R-PSDA0.016 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hydrolyzed PSDA0.046 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hydrolyzed PSDA0.045 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4R-EVE0.0049 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4R-EVE0.0055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-RM-76-05132005/13/2020 320-60921-1R-PSDA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-RM-76-05132005/13/2020 320-60921-1Hydrolyzed PSDA0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-RM-76-05132005/13/2020 320-60921-1Hydrolyzed PSDA0.0020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1R-PSDA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hydrolyzed PSDA0.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hydrolyzed PSDA0.031 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1R-EVE0.010 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 6 of 13 Associated MS and/or MSD analysis had relative percent recovery (RPR) values higher than the upper control limit. The reported result may be biasedhigh.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1R-PSDA0.020 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1R-PSDA0.021 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1R-EVE0.0059 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1R-EVE0.0056 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 7 of 13 Quality review criteria exceeded between the REP (laboratory replicate) and parent sample. The reported result may be imprecise.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4R-PSDA0.013 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2Hfpo Dimer Acid17 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-CFR-RM-76-05132005/13/2020 320-60921-1R-PSDA0.023 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hfpo Dimer Acid0.014 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1Hfpo Dimer Acid0.012 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1R-PSDA0.017 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1R-EVE0.0091 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PFO5DA0.60 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PFO5DA0.43 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLPage 8 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5Hydro-PS Acid0.0094 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5Hydro-PS Acid0.0091 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PFO3OA0.059 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5PFO3OA0.062 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5Hfpo Dimer Acid0.41 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-WC-1-24-05142005/14/2020 410-2519-5Hfpo Dimer Acid0.39 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4PFO4DA0.0025 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4PFO4DA0.0024 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3PFO3OA16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3PFO3OA14 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3Hydro-PS Acid0.45 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3Hydro-PS Acid0.43 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4Hfpo Dimer Acid26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4Hfpo Dimer Acid26 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4PFO3OA7.0 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4PFO3OA7.2 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLPage 9 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4Hydro-PS Acid0.28 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-D-24-05142005/14/2020 410-2519-4Hydro-PS Acid0.29 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hfpo Dimer Acid0.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-TARHEEL-24-05182005/18/2020 410-2521-4Hfpo Dimer Acid0.018 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1Hydro-PS Acid0.0034 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1Hydro-PS Acid0.0035 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1Hfpo Dimer Acid32 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1Hfpo Dimer Acid31 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1R-PSDCA0.061 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1R-PSDCA0.055 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1PS Acid6.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1PS Acid6.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1PFO3OA16 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1PFO3OA17 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1Hydro-PS Acid1.6 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-A-24-05142005/14/2020 410-2519-1Hydro-PS Acid1.6 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2Hfpo Dimer Acid22 UG/LCl. Spec. Table 3CompoundJPFAS_DI_Prep2.0PQLPage 10 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsSOPCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2R-PSDCA0.041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2R-PSDCA0.041 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2PS Acid1.1 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2PS Acid1.2 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2PFO3OA8.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2PFO3OA8.5 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2Hydro-PS Acid0.51 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-B-24-05142005/14/2020 410-2519-2Hydro-PS Acid0.52 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3Hfpo Dimer Acid38 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3Hfpo Dimer Acid39 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep2.0PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3R-PSDCA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-SEEP-C-24-05142005/14/2020 410-2519-3R-PSDCA0.026 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.020PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2Hfpo Dimer Acid9.3 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2Hfpo Dimer Acid9.6 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PS Acid0.52 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PS Acid0.45 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLPage 11 of 13 Associated LCS and/or LCSD analysis had relative percent recovery (RPR) values less than the lower control limit. The reported result may be biasedlow.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PFO4DA1.7 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2PFO4DA1.6 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2Hydro-PS Acid0.39 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OLDOF-1-24-05142005/14/2020 410-2521-2Hydro-PS Acid0.32 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.20PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1Hfpo Dimer Acid0.089 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1Hfpo Dimer Acid0.090 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1PS Acid0.0095 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-OUTFALL 002-24-05142005/14/2020 410-2521-1PS Acid0.0088 UG/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 12 of 13 Associated MS and/or MSD analysis had relative percent recovery (RPR) values less than the lower control limit but above the rejection limit. Thereported result may be biased low.LABSTATSValidation Options:Validation ReasonFayettevilleSite:Sampling Program:CAP SW SAMPLING 2Q20AnalyticalMethodAnalyteDateSampledPQLValidationQualifierLab Sample IDPre-prepMDLResult TypeField Sample IDPrepUnitsCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PFO4DA0.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLCAP2Q20-CFR-KINGS-05192005/19/2020 410-2520-1PFO4DA0.0021 ug/LCl. Spec. Table 3Compound SOPJPFAS_DI_Prep0.0020PQLPage 13 of 13 APPENDIX F Supporting Calculations – Onsite Groundwater Pathway Appendix F 1 September 2020 APPENDIX F SUPPORTING CALCULATIONS – ONSITE GROUNDWATER PATHWAY INTRODUCTION AND OBJECTIVE Based on the conceptual site model, the Black Creek Aquifer and the Flood Plain deposits at the river bank are the primary hydrogeologic units that are potentially in hydraulic connection with the Cape Fear River. The Cape Fear River stage is lower than the top of the Black Creek Aquifer, except during peak rainfall or flooding, indicating that the Cape Fear River is a discharge boundary for the aquifer. Onsite groundwater from the Black Creek Aquifer discharging to the Cape Fear River is therefore a potential pathway for per- and polyfluoroalkyl substances (PFAS) mass loading to the Cape Fear River. This pathway was identified as Transport Pathway Number 5 in the PFAS mass loading design in the. The objective of the supporting calculations presented in this appendix is to estimate PFAS mass loading from onsite groundwater discharge based on calculated PFAS mass flux for segments of the Black Creek Aquifer along the river frontage. APPROACH The PFAS mass loading from onsite groundwater discharge was estimated as follows. Supporting data are provided in Table F1: 1. The Cape Fear River frontage was divided into 8 segments (Figure F1). Each segment includes at least one groundwater monitoring well that is considered representative of the Black Creek Aquifer and that is included in the Corrective Action Plan (Geosyntec, 2019b). 2.The thickness of the Black Creek Aquifer (h) was estimated for each segment based on the segment length and the cross-sectional area of the Black Creek Aquifer, as determined by the three-dimensional hydrostratigraphic model of the Site, constructed using CTech’s Earth Volumetric Studio (EVS) software (Geosyntec, 2019b):ℎ= 𝐴𝐴𝑙𝑙 where h is the Black Creek Aquifer thickness [ft]; A is the cross-sectional area of the Black Creek Aquifer [ft2]; and l is the segment length [ft]. The EVS model output for each segment is presented in Figure F2. 3.The hydraulic gradient (i) was derived based on the groundwater level contour map. For each segment, the gradient was estimated based on the distance between contour lines in the vicinity of the river frontage (Figure F3): Appendix F 2 September 2020 𝑖𝑖= 𝛥𝛥ℎ𝑑𝑑 where i is the hydraulic gradient [ft/ft]; Δh is the head difference between two contour lines [ft]; and d is the estimated distance between the contour lines [ft] This approach is considered to best represent the likely groundwater fluxes discharging from the Black Creek Aquifer to the Cape Fear River. Based on hydrographs from wells along the river presented in Figure F4 hydraulic gradients in the aquifer are relatively constant over time. With the exception of large changes in the river level (over ten feet), these wells respond to river level fluctuation in a subdued manner. 4.The hydraulic conductivity (K) was estimated for each segment using the results of slug tests conducted for select monitoring wells representative of the Black Creek Aquifer. The range of slug test results for LTW-02, LTW-03, and LTW-05 were used to determine the hydraulic conductivity of segments 3, 4, and 7, respectively since these wells are located in the corresponding segments. For other segments where no slug tests were performed, the range of slug test results for the entire Black Creek Aquifer were used to determine the hydraulic conductivity. In both cases, the minimum hydraulic conductivity and the geometric mean hydraulic conductivity were used to calculate a range of mass flux values. Table F2 provides the results of the slug tests and the minimum and geometric mean hydraulic conductivities for each segment. 5.The total PFAS concentration for each segment was determined based on grab samples collected from monitoring wells. For segments with two wells, the average total PFAS concentration was used. PFAS analytical results for these groundwater samples are presented in Appendix B of this report. 6.Mass flux for each segment, representing the PFAS mass loading to the river from groundwater, was determined as follows:𝑄𝑄=𝑙𝑙ℎ𝐾𝐾𝑖𝑖𝐾𝐾𝐾𝐾 where Q is the mass flux [mg/sec]; l is the segment length [ft]; h is the Black Creek Aquifer thickness [ft]; K is the hydraulic conductivity of the aquifer [ft/sec]; i is the hydraulic gradient [ft/ft]; Appendix F 3 September 2020 C is the total PFAS concentration [ng/L]; and f is the conversion factor between cubic feet and liters and between ng and mg. 7.The total mass flux for the groundwater pathway was calculated as the sum of the individual mass flux results for the 8 segments. POTENTIAL FUTURE METHODOLOGY MODIFCATIONS Periodically, adjustments to this calculation methodology may be required based on changes in conditions or refinement of Site knowledge. REFERENCES Geosyntec, 2019. Corrective Action Plan. Chemours Fayetteville Works. December 2019. TABLE F1 ONSITE GROUNDWATER PATHWAY SUPPORTING DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Total Table 3+ Concentration4 (ng/L) Average Total Table 3+ Concentration for Segment (ng/L) Minimum Mass Discharge (mg/sec) Geometric Mean Mass Discharge (mg/sec) PIW-1S --1,150 13,400 11.7 20 450.7 0.044 1.8E-05 3.2E-04 --52,000 0.016 0.28 PIW-1D 5/7/2020 52,000 2 PIW-3D 5/7/2020 873 11,010 12.6 20 451.5 0.044 1.8E-05 3.2E-04 42,000 42,000 0.010 0.19 3 LTW-02 5/12/2020 875 5,560 6.35 20 663.1 0.030 3.0E-04 4.0E-04 59,000 59,000 0.084 0.11 4 LTW-03 5/13/2020 729 8,340 11.4 20 663.1 0.030 2.0E-05 4.6E-05 250,000 250,000 0.036 0.082 5 PZ-22 5/8/2020 656 15,200 23.2 20 926.5 0.022 1.8E-05 3.2E-04 270,000 270,000 0.045 0.81 PIW-7S 5/8/2020 524 16,000 30.5 20 926.5 0.022 1.8E-05 3.2E-04 130,000 175,000 0.031 0.55 PIW-7D 5/8/2020 220,000 7 LTW-05 5/8/2020 887 17,200 19.4 20 1,074.5 0.019 1.8E-05 4.8E-05 290,000 290,000 0.047 0.13 8 PW-11 5/7/2020 1,990 56,300 28.3 20 1,074.5 0.019 1.8E-05 3.2E-04 190,000 190,000 0.10 1.8 0.37 4.0 Notes 1 - Cross sectional areas were determined using the three-dimensional hydrostratigraphic model of the Site, constructed using CTech’s Earth Volumetric Studio (EVS) software (Figure H2) 2 - Vertical and horizontal distances for hydraulic gradient determined from groundwater level contour map for the May 2020 synoptic well gauging round (Figure F3). 3 - Hydraulic conductivity values are based on slug test results presented in Table F2. 4 - Attachment C does not include Perfluorohepthanoic acid (PFHpA). 5 - Detailed PFAS Concentrations provided in Table 10. ft - feet ft/sec - feet per second ft2 - square feet NAVD 88 - North American Vertical Gradient of 1988 ng/L - nanograms per liter -- - well not sampled 1 6 Hydraulic Gradient (ft/ft) Horizontal Distance Between Contours (ft)2 Groundwater Contour Elevation Difference (ft)2 Average Thickness of Black Creek Aquifer (ft) Cross-sectional Area of Black Creek Aquifer (ft2)1 Segment Length (ft)Sample Date Minimum Hydraulic Conductivity (ft/sec)3 WellSegment Total Total Table 3+ (17 Compounds) Geometric Mean Hydraulic Conductivity (ft/sec)3 TR0795 Page 1 of 2 September 2020 TABLE F1 ONSITE GROUNDWATER PATHWAY SUPPORTING DATA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. PIW-1S --1,150 13,400 11.7 20 450.7 0.044 1.8E-05 3.2E-04 PIW-1D 5/7/2020 2 PIW-3D 5/7/2020 873 11,010 12.6 20 451.5 0.044 1.8E-05 3.2E-04 3 LTW-02 5/12/2020 875 5,560 6.35 20 663.1 0.030 3.0E-04 4.0E-04 4 LTW-03 5/13/2020 729 8,340 11.4 20 663.1 0.030 2.0E-05 4.6E-05 5 PZ-22 5/8/2020 656 15,200 23.2 20 926.5 0.022 1.8E-05 3.2E-04 PIW-7S 5/8/2020 524 16,000 30.5 20 926.5 0.022 1.8E-05 3.2E-04 PIW-7D 5/8/2020 7 LTW-05 5/8/2020 887 17,200 19.4 20 1,074.5 0.019 1.8E-05 4.8E-05 8 PW-11 5/7/2020 1,990 56,300 28.3 20 1,074.5 0.019 1.8E-05 3.2E-04 Notes 1 - Cross sectional areas were determined using the three-dimensional hydrostratigraphic model of the Site, constructed using CTech’s Earth Volumetric Studio (EVS) software (Figure H2) 2 - Vertical and horizontal distances for hydraulic gradient determined from groundwater level contour map for the May 2020 synoptic well gauging round (Figure F3). 3 - Hydraulic conductivity values are based on slug test results presented in Table F2. 4 - Attachment C does not include Perfluorohepthanoic acid (PFHpA). 5 - Detailed PFAS Concentrations provided in Table 10. ft - feet ft/sec - feet per second ft2 - square feet NAVD 88 - North American Vertical Gradient of 1988 ng/L - nanograms per liter -- - well not sampled 1 6 Hydraulic Gradient (ft/ft) Horizontal Distance Between Contours (ft)2 Groundwater Contour Elevation Difference (ft)2 Average Thickness of Black Creek Aquifer (ft) Cross-sectional Area of Black Creek Aquifer (ft2)1 Segment Length (ft)Sample Date Minimum Hydraulic Conductivity (ft/sec)3 WellSegment Geometric Mean Hydraulic Conductivity (ft/sec)3 Total Table 3+ Concentration4 (ng/L) Average Total Table 3+ Concentration for Segment (ng/L) Minimum Mass Dicharge (mg/sec) Geometric Mean Mass Discharge (mg/sec) --52,000 0.016 0.28 52,000 42,000 42,000 0.010 0.19 60,000 60,000 0.085 0.11 260,000 260,000 0.037 0.086 270,000 270,000 0.045 0.81 140,000 180,000 0.032 0.56 220,000 290,000 290,000 0.047 0.13 190,000 190,000 0.10 1.8 0.37 4.0 Total Table 3+ (20 Compounds) Total TR0795 Page 2 of 2 September 2020 TABLE F2 HYDRAULIC CONDUCTIVITY RESULTS Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Segment Well Slug Test Observed Hydraulic Conductivity (ft/sec) Minimum Hydraulic Conductivity (ft/sec) Geometric Mean Hydraulic Conductivity (ft/sec) --BCA-01 T1 2.1E-04 2.1E-04 2.8E-04 T1*3.7E-04 T2 2.2E-04 T2*3.7E-04 T3 2.1E-04 T3*3.6E-04 T4 2.2E-04 T4*3.9E-04 --BCA-02 T1 4.6E-04 3.1E-04 5.4E-04 T1*1.0E-03 T2 4.2E-04 T2*9.1E-04 T3 3.4E-04 T3*7.4E-04 T4 3.3E-04 T4*7.4E-04 T5 3.1E-04 T5*6.8E-04 --BCA-04 T1 1.1E-03 1.1E-03 1.4E-03 T1*1.6E-03 T2 1.1E-03 T2*1.7E-03 T3 1.1E-03 T3*1.6E-03 T4 1.1E-03 T4*1.7E-03 T5 1.2E-03 T5*2.3E-03 3 LTW-02 T1 3.0E-04 3.0E-04 4.0E-04 T1*4.8E-04 T2 3.2E-04 T2*4.9E-04 T3 3.1E-04 T3*4.7E-04 T4 3.9E-04 T4*5.5E-04 T5 3.0E-04 T5*4.5E-04 4 LTW-03 T1 6.5E-05 2.00E-05 4.6E-05 T2 2.4E-05 T3 2.6E-05 T4 2.6E-04 T5 2.0E-05 7 LTW-05 T1 2.4E-05 1.8E-05 4.8E-05 T1*8.0E-05 T2 1.8E-05 T2*3.5E-05 T4 7.4E-05 T4*1.3E-04 Remaining Segments (1, 2, 5, 6, and 8) All BCA Wells ----1.8E-05 3.2E-04 Notes * - Screen length used for aquifer thickness BCA - Black Creek Aquifer ft/sec - feet per second TR0795 Page 1 of 1 September 2020 TABLE F3 ONSITE GROUNDWATER FLOW RATE Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Segment Cross-sectional Area of Black Creek Aquifer (ft2) Hydraulic Gradient (ft/ft)Minimum Hydraulic Conductivity (ft/sec) Geometric Mean Hydraulic Conductivity (ft/sec) Minimum Flow Rate (L/sec) Geometric Mean Flow Rate (L/sec) 13,400 0.044 1.8E-05 3.2E-04 0.30 5.40 2 11,010 0.044 1.8E-05 3.2E-04 0.25 4.43 3 5,560 0.030 3.0E-04 4.0E-04 1.42 1.88 4 8,340 0.030 2.0E-05 4.6E-05 0.14 0.33 5 15,200 0.022 1.8E-05 3.2E-04 0.17 2.98 16,000 0.022 1.8E-05 3.2E-04 0.18 3.14 7 17,200 0.019 1.8E-05 4.8E-05 0.16 0.43 8 56,300 0.019 1.8E-05 3.2E-04 0.53 9.5 Total 3.2 28 Notes Supporting data for cross-sectional area, hydraulic gradient, and hydraulic conductivity provided in Table F1. ft - feet ft/sec - feet per second ft2 - square feet L/sec - liters per second 1 6 TR0795 Page 1 of 1 September 2020 PPPPPPPPPPPPPPPP !'A !'A !'A !'A !'A !'A !'A !'A !'A !'A CapeFear RiverSeep D Old Outfall 002 Seep C Seep B Seep A Willis Creek PIW-1D LTW-03 PIW-1S PIW-7S LTW-02 LTW-05 PIW-7D PW-11 PZ-22 PIW-3D Segment 1 Segment 2 Segment 3 Segment 4 Segment 5 Segment 6 Segment 7 Segment 8 ³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Baseline Monitoring Workplan\TR0795_Black CreekAquiferSegmentsforGroundwaterPathway.mxd Last Revised: 7/29/2020 Author: jkasunicProjection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Black Creek Aquifer Segmentsfor Groundwater Pathway Chemours Fayetteville Works, North Carolina Figure F1RaleighSeptember 2020 1,000 0 1,000500 Feet Notes:1. Due to the scale of the map, pairs of wells that are in close proximity have been offset for visibility. Therefore, the placement of these wells on this map do not reflect their true geographic coordinates.2. The outline of Cape Fear River is approximate and is based on open data from ArcGIS Online and North Carolina Department of Environmental QualityOnline GIS.3. Basemap source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community. Legend !'A Surficial Aquifer !'A Floodplain Deposits !'A Black Creek Aquifer Observed Seep Nearby Tributary Site Boundary Transect Line 0.5 0 0.50.25 Miles ³ FigureF2Cross-Sections Along Cape Fear River Transect LineChemours Fayetteville Works, North CarolinaRaleighSeptember 2020Elevation (feet NAVD88)50403020100PIW-1S/D-1002505007501,000Elevation (feet NAVD88)50403020100-100250500750PIW-3DLTW-01Elevation (feet NAVD88)50403020100-100250500750LTW-02Segment 1Elevation (feet NAVD88)50403020100-100250500750LTW-03Elevation (feet NAVD88)50403020100-100250500LTW-04PZ-22Elevation (feet NAVD88)50403020100-100250500PIW7S/DElevation (feet NAVD88)50403020100-100250500750Elevation (feet NAVD88)50403020100PW-11-1002505007501,000 1,2501,5001,7502,000Segment 2Segment 3Segment 4Segment 5Segment 6Segment 7Segment 8Units(2)Floodplain DepositsBlack Creek Confining UnitBlack Creek AquiferUpper Cape Fear Confining UnitLegendWell screen(1)Notes:NAVD88 – feet North America Datum of 1988 Vertical Exaggeration = 10x1. Wells are projected onto the cross-section.Segment 1Segment 3Segment 2Segment 4Segment 5Segment 6Segment 7Segment 8Distance Along Transect Line (feet)Distance Along Transect Line (feet)Distance Along Transect Line (feet)Distance Along Transect Line (feet)Distance Along Transect Line (feet) Distance Along Transect Line (feet)Distance Along Transect Line (feet)Distance Along Transect Line (feet)NorthSouthNorthSouthNorthSouthNorthSouthNorthSouthNorthSouthNorthSouthLTW-05NorthSouthCape Fear River PPPPPPPPPPPPPPPP @A @A @A @A @A @A @A @A @A @A @A @A @A @A @A @A@A @A @A @A @A @A @A @A @A @A @A @A @A @A W illis Creek C a p e Fear Ri ver Seep A Seep B Seep C Seep D Old Outfall 002 Segment 1 0.044 Segment 2 0.044 Segment 3 0.030 Segment 4 0.030 Segment 5 0.022 Segment 6 0.022 Segment 7 0.019 Segment 8 0.019 BCA-0186.6 BCA-0274.56 BCA-03R100.16 BCA-04120.9 LTW-0138.03 LTW-0242.7 LTW-0340.6 LTW-0443.36 LTW-0542.72 PIW-10DR61.33 PIW-1S 33.99 PIW-2D 59.46 PIW-3D36.64 PIW-4D42.15 PIW-6S39.5 PIW-7D43.05 PIW-7S43.14 PIW-8D41.52PIW-9D42.47 PW-0948.05 PW-10R48.52 PW-1140.5 PW-1292.45 PW-13116.26 PW-1486.4 PW-15R76.31 PZ-2244.38 SMW-03B92.55 SMW-1047.04 SMW-1234.47 90807040 60 50 50 60 70 809040 Groundwater Elevation Map andHydraulic Gradients - May 2020 Chemours Fayetteville Works, North Carolina Figure F3Raleigh ³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Baseline Monitoring Workplan\TR0795_GW_Elevation_Map_and_Hydraulic_Conductivities_May2020.mxd Last Revised: 9/4/2020 Author: TIpSeptember 2020 Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US 1,000 0 1,000500 Feet Notes:ft - feetft NAVD88 - feet North American Vertical Datum 1988.1. Depth to water measurements collected on May 5, 2020 were used to generate contours.2. Ground surface elevation contours are derived from Lidar scans performed on December 1, 2019 and December 19, 2019 by Spectral Data Consultants, Inc. 3. Seep locations identified visually as reported in Geosyntec, 2019. Seeps andCreeks Investigation Report. Chemours Fayetteville Works. 26 August 2019.4. The hydraulic gradient was derived using the groundwater level contoursshown here, based on the distance between contour lines in the vicinity of the river frontage. Vertical and horizontal distances used to estimate hydraulic gradientare provided in Table F1.5. The outline of Cape Fear River is approximate and is based on open data from ArcGIS Online and North Carolina Department of Environmental Quality Online GIS (MajorHydro shapefile).6. Basemap source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community. 0.5 0 0.50.25 Miles ³ Legend @A Monitoring Well Groundwater Contours(ft NAVD88) - 10 feetinterval Potentiometric SurfaceInferred Observed Seep Nearby Tributary Ground SurfaceElevation Contour (ftNAVD88) - 5 ft interval Transect Line Site Boundary Segment 10.040 Hydraulic Gradient (ft/ft) Segment Number \\projectsitesb.geosyntec.com@SSL\DavWWWRoot\5\FWConsentOrder\Shared Documents\34 - P16 Quarterly Reports\01 - Quarterly Reports\2020 Q2\Report\Appendices\Appendix F\[Figure F4 - Hydrographs.xlsx]Figure F-4Hydrograph for Select Onsite Groundwater Monitoring Wells and W.O Huske Dam Chemours Fayetteville Works, North Carolina Figure F4RaleighSeptember 2020 Notes: ft -feet NAVD88 -North American Vertical Datum of 1988 NAVD88 -North American Vertical Datum of 1988 0 10 20 30 40 50 60 70 0 10 20 30 40 50 60 70 27-Oct-201827-Nov-201828-Dec-201828-Jan-201928-Feb-201931-Mar-20191-May-20191-Jun-20192-Jul-20192-Aug-20192-Sep-20193-Oct-20193-Nov-20194-Dec-20194-Jan-20204-Feb-20206-Mar-20206-Apr-20207-May-20207-Jun-20208-Jul-20208-Aug-20208-Sep-20209-Oct-2020W.O Huske Dam water level (ft NAVD88)Groundwater Elevation (ft NAVD88)Date LTW-01 LTW-02 LTW-05 PIW-1D PIW-2D PIW-3D PIW-4D PIW-7D PIW-7S PIW-8D LTW-03 LTW-04 PIW-6S PW-11 SMW-12 W.O. Huske Dam APPENDIX G Cape Fear River Mass Loading Calculations Appendix G 1 September 2020 APPENDIX G CAPE FEAR RIVER MASS LOADING CALCULATIONS This appendix presents the methodology for calculating three types of mass loads: 1.The total measured in-river PFAS mass load based on time-weighted concentration measurements of PFAS primarily from composite samples of Cape Fear River water and measured Cape Fear River flow volumes at the W.O. Huske Dam that are adjusted for travel times to the downstream monitoring location at the CFR-TARHEEL; 2.The total measured and estimated PFAS mass load captured by remedies implemented by Chemours; this is the load fraction that was prevented from reaching the Cape Fear River; and 3.The total measured Total PFAS mass load to the Cape Fear River defined as the sum of the measured in-river loads and the remedy prevented loads. The following sections detailed calculation methods for each type of mass load: Total, River and Captured Mass Loads. Total Mass Load Calculation Methodology The Total Mass Load is calculated following Equation 1 below: Equation 1: Total PFAS Mass Load 𝑀𝑀𝐶𝐶𝐶𝐶𝐶𝐶= 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶+𝑚𝑚𝐶𝐶𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅 where, 𝑀𝑀𝐶𝐶𝐶𝐶𝐶𝐶 = is the Baseline Mass Load of PFAS compounds in the Cape Fear River, including the mass load prevented from reaching the Cape Fear River by implemented remedies, measured in kg; 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶 = is the River Mass Load estimated using PFAS concentrations in samples taken in the Cape Fear River downstream of the Site where the river is well mixed and using measured river flow volumes; and 𝑚𝑚𝐶𝐶𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅𝑅 = is the Captured Mass Load prevented from reaching the Cape Fear River by remedies implemented by Chemours. The following subsections describe how the River and Captured Mass Loads are calculated. River Mass Load Calculation Methodology The River Mass Load is the estimated mass, in kilograms, that has reached the Cape Fear River over a period of time. The River Mass Load, 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶, is calculated using primarily composite Appendix G 2 September 2020 samples from the Cape Fear River and corresponding river flow volumes. The River Mass Load is calculated for a given time period following Equation 2 below: Equation 2: River Mass Load 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶= � � 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅× 𝑉𝑉𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛I𝑅𝑅=1𝑁𝑁𝑛𝑛=1 where, 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶 = is the Total PFAS mass load estimated from PFAS concentrations in samples taken in the Cape Fear River downstream of the Site where the river is well mixed and measured river flow volumes; 𝑛𝑛= represents individual time intervals during a monitoring period; 𝑁𝑁= is the total number of time intervals in a monitoring period; i = represents each of the PFAS constituents being evaluated; I = represents total number of PFAS constituents included in the summation; 𝑐𝑐𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅 = is the measured or estimated concentration of PFAS for each baseline mass loading time interval based on samples collected from the Cape Fear River; and 𝑉𝑉𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛 = is the volume of Cape Fear River water that flowed passed the sampling point during the baseline mass loading time interval. Calculation of Time-Weighted Average Concentrations During a time period, multiple samples will be collected, most of them being composite samples and some potentially being grab samples. The calculation methodology outlined here considers all collected samples in the time period, including cases where samples are collected contemporaneously with each other and cases where composite sample collection events do not occur successively, as is the case with twice weekly 24 hour composite samples. To facilitate this calculation the overall time period is separated into discrete time intervals with corresponding time-weighted concentrations calculated for each interval. The time intervals are defined as the duration in time between two sampling events, where sampling events consist of: •Beginning of a composite sample collection; •End of a composite sample collection; or •Collection of a grab sample. Equation 3 shows the formula used to calculate the total flow volume for each interval. 3 September 2020 Appendix G Equation 3: Mass Load Time Interval Concentration 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅= �𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅,𝑘𝑘× 𝑤𝑤𝑘𝑘𝐾𝐾 𝑘𝑘=1 = � 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅,𝑘𝑘𝑡𝑡𝑛𝑛𝑡𝑡𝑘𝑘∑𝑡𝑡𝑛𝑛𝑡𝑡𝑘𝑘𝐾𝐾𝑘𝑘=1 𝐾𝐾 𝑘𝑘=1 where, 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅 = is the measured or estimated concentration of PFAS for each baseline mass loading time interval based on samples collected from the Cape Fear River; 𝑛𝑛= represents individual time intervals during a monitoring period; i = represents each of the PFAS constituents being evaluated; k = represents a concentration sample considered in the mass load time interval; K = is the total number of concentration samples considered in the mass load time interval; 𝐶𝐶𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅,𝑘𝑘 = is the measured concentration of PFAS for each sample result considered in calculating the time-weighted average concentration for a mass load time interval; and 𝑤𝑤𝑘𝑘 = is the weighting factor calculated for and applied individually to each concentration, where, 𝑡𝑡𝑛𝑛 = the length of time of the mass load time interval; and 𝑡𝑡𝑘𝑘 = the length of time of the collected sample. For composite samples, 𝑡𝑡𝑘𝑘 is the total length of the composite sample collection period. If 𝑡𝑡𝑘𝑘<𝑡𝑡𝑛𝑛, i.e., the composite sample collection time is less than the interval time, or a grab sample was collected, then 𝑡𝑡𝑘𝑘 is set to equal the interval time for the purposes of concentration weighting. Calculation of Travel Time Adjusted Flow Volumes To calculate the mass load, river flow volumes are calculated for each time interval using United States Geological Survey (USGS) reported flows at the W.O. Huske Dam. A time offset is applied to the flow data to account for travel time for the flow passing the W.O. Huske Dam to reach the CFR-TARHEEL location. River flow passing the W.O. Huske is estimated to have a travel time between 2 and 12 hours to reach CFR-TARHEEL depending on river flow (e.g., the flow rate passing W.O. Huske Dam at 8 am will arrive at CFR-TARHEEL at 11 am for a 3 hour travel time). Travel times are estimated based on the results of a numerical model of the Cape Fear River which developed a regression curve between the USGS reported gage heights at W.O. Huske Dam and travel times. Equation 4 shows the formula used to calculate the time offset. The total volume of Appendix G 4 September 2020 flow for each mass loading interval is calculated as the sum of all individual flow measurements for an interval where each measurement multiplied by its corresponding 15-minute time duration. Equation 5 shows the formula used to calculate the total flow volume for each interval. Equation 4: Travel time offset W.O. Huske Dam to Tar Heel Ferry Road Bridge 𝑡𝑡𝑜𝑜𝑜𝑜𝑜𝑜𝑅𝑅𝑅𝑅𝑜𝑜=13,422 ∙ 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊−1 + 2.019 where, 𝑡𝑡𝑜𝑜𝑜𝑜𝑜𝑜𝑅𝑅𝑅𝑅𝑜𝑜 = is the travel time flow in the Cape Fear River takes in hours to pass from the W.O. Huske Dam to CFR-TARHEEL based on the measured flow in the Cape Fear River at the W.O. Huske Dam; 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊−1 = is the inverse of the measured flow rate of the Cape Fear River at W.O. Huske Dam for a given point in time in cubic feet per second (ft3/s); and 13,422 𝑎𝑎𝑛𝑛𝑎𝑎 2.019 = are constant values, which correspond to the slope and intercept of the regression line, respectively. Equation 5: Cape Fear River Flow Volume per Interval 𝑉𝑉𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛= � 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊,𝑛𝑛,𝑅𝑅+𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜× (𝑡𝑡𝑛𝑛,𝑅𝑅− 𝑡𝑡𝑛𝑛,𝑅𝑅−1)𝑀𝑀 𝑅𝑅=1 where, 𝑉𝑉𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛 = is the volume of Cape Fear River water that flowed past the sampling point during the baseline mass loading time interval; n = represents the baseline mass loading time intervals number for which the volume is being calculated; m = represents a 15-minute flow measurement recorded by the USGS station at W.O. Huske Dam during a baseline mass loading time interval “n”; M = the total number of 15-minute flow measurements recorded by the USGS station at W.O. Huske Dam during a baseline mass loading time interval “n”; 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊,𝑛𝑛,𝑅𝑅+𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜 = is the Cape Fear River flow rate (units of volume per time) at Tar Heel Ferry Road bridge based on the recorded values at W.O.Huske Dam and adjusted for travel time as described in Equation 4; and (𝑡𝑡𝑛𝑛,𝑅𝑅− 𝑡𝑡𝑛𝑛,𝑅𝑅−1 = is the length of time for the flow measurement durations (units of time reported typically in 15-minute intervals by USGS). Appendix G 5 September 2020 Complete Calculation of River Mass Load Based on all the calculation details described above, the full expanded version of the River Mass Load calculation is shown below in Equation 6. Equation 6: Expanded River Mass Load Calculation 𝑚𝑚𝐶𝐶𝐶𝐶𝐶𝐶= �� �𝑐𝑐𝐶𝐶𝐶𝐶𝐶𝐶,𝑛𝑛,𝑅𝑅,𝑘𝑘𝑘𝑘 𝑡𝑡𝑛𝑛𝑡𝑡𝑘𝑘∑𝑡𝑡𝑛𝑛𝑡𝑡𝑘𝑘𝑘𝑘�𝑄𝑄𝐶𝐶𝐶𝐶𝐶𝐶 𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊,𝑛𝑛,𝑅𝑅+𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜𝑜 ∙(𝑡𝑡𝑛𝑛,𝑅𝑅− 𝑡𝑡𝑛𝑛,𝑅𝑅−1)𝑅𝑅𝑅𝑅=I𝑅𝑅=1𝑛𝑛 Captured Mass Load Calculation Methodology Remedies to be implemented by Chemours (e.g. onsite seeps interim remedies, Outfall 002 remedy) will prevent PFAS mass loads from reaching the Cape Fear River. The specific methodology for estimating the prevented mass per remedy will be developed on a per remedy basis. The goal of such calculations will be to estimate for a given time period (i.e. one quarter) the PFAS mass diverted from reaching the Cape Fear River by the remedy that would have otherwise reached the Cape Fear River. Mass Discharge at Bladen Bluffs and Kings Bluff Intakes This subsection presents the methodology used to calculate mass discharge at Bladen Bluffs and Kings Bluff Intakes. Total PFAS mass discharge is calculated as: Equation 7: Mass Discharge at Bladen Bluffs and Kings Bluff Intakes 𝑀𝑀𝐵𝐵𝐵𝐵/𝐾𝐾𝐵𝐵= �𝑀𝑀𝑅𝑅=�𝐶𝐶𝑅𝑅× 𝑄𝑄 𝐼𝐼 𝑅𝑅=1 𝐼𝐼 𝑅𝑅=1 where, MBB/KB = Total PFAS mass in the downstream river locations (Bladen Bluffs or Kings Bluff Intakes) measured in mass per unit time [MT-1], typically mg/s; i = represents each of the PFAS constituents being evaluated; I = represents total number of PFAS constituents included in the summation of Total PFAS concentrations; Mi = mass load of each PFAS constituent i with measured units in mass per unit time [MT-1], typically mg/s; Appendix G 6 September 2020 Ci = concentration of each PFAS constituent i with measured units typically in nanograms per liter; and Q = volumetric flow rate with measured units in volume per time [L3T-1], typically liters per second (L/s). For Bladen Bluffs, the volumetric flow recorded at W.O. Huske Dam is adjusted for travel time using Equation 7. Equation 8: Travel time offset W.O. Huske Dam to Bladen Bluffs Intake 𝑡𝑡𝑜𝑜𝑜𝑜𝑜𝑜𝑅𝑅𝑅𝑅𝑜𝑜= 8,826 ∙ 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊−1 + 1.530 where, 𝑡𝑡𝑜𝑜𝑜𝑜𝑜𝑜𝑅𝑅𝑅𝑅𝑜𝑜 = is the travel time flow in the Cape Fear River takes in hours to pass from the W.O. Huske Dam to Bladen Bluffs Intake location based on the measured flow in the Cape Fear River at the W.O. Huske Dam; 𝑄𝑄𝑊𝑊𝑊𝑊𝑊𝑊𝑊𝑊−1 = is the inverse of the measured flow rate of the Cape Fear River at W.O. Huske Dam for a given point in time in cubic feet per second; and 8,826 𝑎𝑎𝑛𝑛𝑎𝑎 1.530 = are constant values, which correspond to the slope and intercept of the regression line, respectively. * * * * * * * APPENDIX H Supporting Calculations – Direct Aerial Deposition on Cape Fear River Appendix H 1 September 2020 APPENDIX H SUPPORTING CALCULATIONS – DIRECT AERIAL DEPOSITION ON CAPE FEAR RIVER INTRODUCTION AND OBJECTIVE Nine pathways (main report Table 14) were identified as potentially contributing to observed Cape Fear River per- and polyfluoroalkyl substances (PFAS) concentrations. These pathways include direct PFAS aerial deposition to the Cape Fear River. This pathway was identified as Transport Pathway Number 3 in the PFAS mass loading model. The mass discharge (mass per unit time measured in milligrams per second [mg/s]) from direct aerial deposition of PFAS to the Cape Fear River was estimated by scaling air deposition modeling results for Hexafluoropropylene oxide dimer acid (HFPO-DA; ERM, 2018). The objective of the supporting calculations presented in this appendix is to estimate aerially deposited PFAS directly on the Cape Fear River during a mass loading event. APPROACH HFPO-DA mass loading directly to the Cape Fear River was estimated using the reported aerial extent and deposition contours modeled for October 2018 (ERM, 2018). As depicted in (Table H1), the HFPO-DA air loading data (micrograms per meters squared [µg/m2]) provided from ERM (2018) was used to calculate the net hourly deposition rate (nanograms per meters squared per hour [ng/m2/hr]) using the Equation 1 below: Equation 1: Net Hourly Deposition Rate 𝐷𝐷𝐷𝐷𝑁𝑁𝑁𝑁𝑁𝑁= 𝑀𝑀𝑀𝑀𝐴𝐴𝐴𝐴𝐴𝐴𝑡𝑡𝐴𝐴𝐴𝐴𝐴𝐴 where: 𝐷𝐷𝐷𝐷𝑁𝑁𝑁𝑁𝑁𝑁 = Net hourly deposition rate with units of mass per area per time (M L-2 T-1), typically in ng/m2/hr; 𝑀𝑀𝑀𝑀𝐴𝐴𝐴𝐴𝐴𝐴 = Air mass loading of HFPO-DA with units of mass per area (M L-2), typically µg/m2; and 𝑡𝑡𝐴𝐴𝐴𝐴𝐴𝐴 = time that air mass loading was modeled (T), typically hours. Depositional area along the river was calculated using available data for river width and computed river lengths where deposition contours were modeled. Eighteen (18) sections (Figure H1) provided from FEMA (2007) were selected along the Cape Fear River to measure the average river width (m). As depicted in Figures H2 through H6, sections along the Cape Fear River with HFPO- DA concentrations contours ranging from 40 to 640 µg/m2 were selected, and the length of the Cape Fear River along each of the sections was measured. The average river width calculated in Table H2 and section lengths from Figures H2 through H6 were used to calculate section areas (m2) as described in Equation 2 below: 2 September 2020 Appendix H Equation 2: Cape Fear River Surface Area for Each Section 𝐴𝐴𝑠𝑠=𝑀𝑀𝑠𝑠× 𝑊𝑊𝑠𝑠 where, 𝐴𝐴𝑠𝑠 = total spatial area over which deposition occurs between contours (L2) in section “s”, typically in m2; s = section along the Cape Fear River with HFPO-DA concentrations contours ranging from 40 to 640 µg/m2 (five sections in total); 𝑀𝑀 = total length of river within section “s”, typically in m; and 𝑊𝑊𝑠𝑠 = average river width in section “𝑠𝑠”,typically in m. Start and end deposition rates (ng/m2/hr) for each section along the Cape Fear River will be estimated based on the deposition contours and corresponding net hourly deposition rate (Table B1); a combined deposition rate for each section will be calculated as the average of the start and end deposition rates. River velocity (meters per hour [m/hr]) will be estimated from measured flow rates from USGS (2020) and the calculated river cross sectional area. Section lengths will be used to calculate HFPO-DA travel time based on the river velocities in Table B3. The combined deposition rate (ng/m2/hr) from Table B1, section area (m2), and travel time (hr) will be used to calculate mass HFPO-DA deposited (ng) as follows in Equation 3 below. Equation 3: Total HFPO-DA Mass Discharge to Cape Fear River 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐻𝐻𝐻𝐻−𝐷𝐷𝐴𝐴=�𝐷𝐷𝐷𝐷𝐴𝐴𝐴𝐴𝐴𝐴,𝑠𝑠× 𝐴𝐴𝑠𝑠× 𝑡𝑡𝑠𝑠𝑆𝑆 𝑠𝑠=1 where, 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐻𝐻𝐻𝐻−𝐷𝐷𝐴𝐴 = total mass discharge of HFPO-DA into the river across all sections, with units of mass per time (M T-1), typically mg/s; s = section along the Cape Fear River with HFPO-DA concentrations contours ranging from 40 to 640 µg/m2; S = total number of sections along the Cape Fear River with HFPO-DA concentrations contours ranging from 40 to 640 µg/m2, five in total; 𝐷𝐷𝐷𝐷𝐴𝐴𝐴𝐴𝐴𝐴,𝑠𝑠 = average deposition rate based from the ERM model (2018) in section “s”, typically in ng/m2/hr; 𝐴𝐴𝑠𝑠 = spatial area over which deposition occurs in section “s”, typically in m2; and 𝑡𝑡𝑠𝑠 = travel time through the river length in section “s”, typically in hr. As reported in the Corrective Action Plan (Geosyntec 2019), ten offsite groundwater seeps south of Old Outfall 002 (Seeps E to M) were identified on the west bank of the Cape Fear River south of the Site. Seeps E to M were sampled in October 2019 and Seeps E to K were sampled in March Appendix H 3 September 2020 2020 and analyzed for PFAS. The results of both sampling events indicate that Seeps E to M show an aerial deposition PFAS signature (concentrations decrease in seeps more distant from the Site). Accordingly, the offsite seep data were used to build a relationship between HFPO-DA and other PFAS compounds (Figure H7). A scaling factor (Table H4) was used to estimate mass discharge of Total PFAS compounds to the Cape Fear River as shown in Equation 4. Table H5 shows the estimated mass discharges of HFPO-DA and Total PFAS compounds to the Cape Fear River. Equation 4: Total PFAS Mass Discharge to Cape Fear River 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐴𝐴𝑆𝑆= 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐻𝐻𝐻𝐻−𝐷𝐷𝐴𝐴× 𝐷𝐷 where, 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐴𝐴𝑆𝑆 = total mass discharge of PFAS compounds into the river, typically in mg/s; 𝑀𝑀𝐷𝐷𝐻𝐻𝐻𝐻𝐻𝐻𝐻𝐻−𝐷𝐷𝐴𝐴 = total mass discharge of HFPO-DA into the river, typically in mg/s; and 𝐷𝐷 = average ratio of measured HFPO-DA to PFAS compounds across the nine offsite seeps. REFERENCES ERM, 2018. Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. Federal Emergency Management Agency (FEMA), 2007. "A Report of Flood Hazards in Bladen County, North Carolina and Incorporated Areas." (2007) Flood Insurance Study, Federal Emergency Management Agency. North Carolina Flood Risk Information System Engineering Model. Cape Fear River ADJ. HEC-RAS 5.0.7. Geosyntec, 2019. Corrective Action Plan. Chemours Fayetteville Works. December 31, 2019. USGS, 2020. USGS 02105500 Cape Fear River at Wilm O Huske Lock near Tarheel, NC. Available at: https://waterdata.usgs.gov/nwis/uv?site_no=02105500 TABLE H1 NET HOURLY HFPO-DA DEPOSITION RATE Chemours Fayetteville Works, North Carolina Geosyntec Consultants NC P.C. Air Loading (µg/m2) Air Loading (ng/m2) Time (year) Time (hour) Net Hourly Deposition Rate (ng/m2/hr) 40 40,000 1 8,760 4.6 80 80,000 1 8,760 9.1 160 160,000 1 8,760 18.3 320 320,000 1 8,760 36.5 640 640,000 1 8,760 73.1 Notes: Groundwater Effects. 27 April 2018. 2. Air deposition contours are shown in Figures J-2 through J-6. 3. Net hourly deposition rates are used in the mass discharge calculations, Table J5. Abbreviations: HFPO-DA: Hexafluoropropylene oxide dimer acid; or dimer acid. µg/m2: micrograms per meter square. ng /L: nanograms per liter. ng/m2/hr: nanograms per meter square per hour. 1. HFPO-DA model values are from ERM (2018). Modeling Report: HFPO-DA Atmospheric Deposition and Screening TR0795 Page 1 of 1 September 2020 TABLE H2 ESTIMATION OF CAPE FEAR RIVER AVERAGE WIDTH Chemours Fayetteville Works, North Carolina Geosyntec Consultants NC P.C. Cross section ID*HEC-RAS Model Point ID**Easting (ft)Northing (ft)Cape Fear River Width at Cross Section (m) 0 2,052,368 399,949 1 2,052,366 399,949 2 2,052,334 399,946 3 2,052,254 399,938 4 2,052,155 399,928 5 2,052,095 399,922 6 2,052,093 399,922 18 2,053,460 394,655 19 2,053,436 394,649 20 2,053,281 394,613 21 2,053,277 394,612 22 2,053,180 394,590 23 2,053,079 394,566 24 2,052,977 394,543 25 2,052,949 394,536 26 2,052,924 394,531 7 2,053,113 396,901 8 2,053,070 396,895 9 2,052,990 396,886 10 2,052,891 396,874 11 2,052,831 396,867 12 2,052,815 396,865 21 2,053,373 393,937 22 2,053,349 393,931 23 2,053,271 393,913 24 2,053,174 393,891 25 2,053,115 393,877 26 2,053,081 393,869 13 2,053,209 394,897 14 2,053,130 394,878 15 2,053,032 394,854 16 2,052,974 394,840 17 2,052,961 394,837 31 2,053,769 390,652 32 2,053,729 390,645 33 2,053,643 390,630 34 2,053,602 390,623 35 2,053,572 390,618 27 2,053,560 392,482 28 2,053,430 392,455 29 2,053,370 392,443 30 2,053,322 392,433 1271 2,054,059 387,249 1272 2,054,022 387,215 1273 2,053,995 387,190 1274 2,053,946 387,145 1275 2,053,861 387,067 1276 2,053,812 387,023 1277 2,053,801 387,012 1278 2,053,727 386,945 612082 606667 616535 613542 610240 84 163 91 89 76*** 60*** 619506 614224 614517 72 101 TR0795 Page 1 of 3 September 2020 TABLE H2 ESTIMATION OF CAPE FEAR RIVER AVERAGE WIDTH Chemours Fayetteville Works, North Carolina Geosyntec Consultants NC P.C. Cross section ID*HEC-RAS Model Point ID**Easting (ft)Northing (ft)Cape Fear River Width at Cross Section (m) 1193 2,053,950 388,876 1194 2,053,902 388,874 1195 2,053,843 388,871 1196 2,053,717 388,866 1197 2,053,659 388,864 1198 2,053,650 388,863 1199 2,053,600 388,861 1271 2,054,059 387,249 1272 2,054,022 387,215 1273 2,053,995 387,190 1274 2,053,946 387,145 1275 2,053,861 387,067 1276 2,053,812 387,023 1277 2,053,801 387,012 1278 2,053,727 386,945 1498 2,057,643 382,269 1499 2,057,610 382,246 1500 2,057,556 382,208 1501 2,057,461 382,141 1502 2,057,408 382,103 1503 2,057,398 382,096 1504 2,057,358 382,067 1331 2,055,879 386,154 1332 2,055,812 386,120 1333 2,055,753 386,090 1334 2,055,647 386,037 1335 2,055,588 386,007 1336 2,055,566 385,996 1565 2,058,901 380,593 1566 2,058,830 380,549 1567 2,058,774 380,515 1568 2,058,675 380,453 1569 2,058,619 380,418 1570 2,058,518 380,356 1406 2,056,453 383,857 1407 2,056,356 383,798 1408 2,056,301 383,763 1409 2,056,202 383,702 1410 2,056,146 383,667 1411 2,056,113 383,647 1717 2,060,560 377,186 1718 2,060,482 377,157 1719 2,060,421 377,134 1720 2,060,312 377,094 1721 2,060,250 377,071 1722 2,060,232 377,065 1644 2,059,549 379,003 1645 2,059,534 378,996 1646 2,059,474 378,970 1647 2,059,368 378,923 1648 2,059,308 378,896 1649 2,059,275 378,881 2042 2,061,270 371,304 2043 2,061,246 371,290 2044 2,061,179 371,252 2045 2,061,092 371,203 2046 2,061,042 371,174 2047 2,060,966 371,131 608468 602061 594185 596259 587968 606667 600052 604474 597968 116 104 100 84 93 107 101 87 95 TR0795 Page 2 of 3 September 2020 TABLE H2 ESTIMATION OF CAPE FEAR RIVER AVERAGE WIDTH Chemours Fayetteville Works, North Carolina Geosyntec Consultants NC P.C. Cross section ID*HEC-RAS Model Point ID**Easting (ft)Northing (ft)Cape Fear River Width at Cross Section (m) 1825 2,060,295 374,663 1826 2,060,270 374,661 1827 2,060,201 374,658 1828 2,060,079 374,653 1829 2,060,010 374,650 1830 2,059,995 374,649 1931 2,060,424 373,459 1932 2,060,378 373,442 1933 2,060,372 373,439 1934 2,060,311 373,416 1935 2,060,202 373,376 1936 2,060,140 373,353 1937 2,060,097 373,336 99 Notes: *Cross sections locations are shown in Figure J-1. **Model point ID: are locations with northing, easting, and river depths provided in the HEC-RAS model. 1. Data provided from: "A Report of Flood Hazards in Bladen County, North Carolina and Incorporated Areas." RiverADJ. HEC-RAS 5.0.7. (2007) Flood Insurance Study, Federal Emergency Management Agency. North Carolina Flood Risk Information System Engineering Model. Cape Fear RiverADJ. HEC-RAS 5.0.7. 2. The horizontal datum is North American Datum 1983 projected into North Carolina East State Plane (3200). 3. The vertical datum is North American Datum 1988 projected into North Carolina East State Plane (3200). Abbreviations: ft: feet m: meter Average River Cross Section Width (m) = 591595 590322 100 91 TR0795 Page 3 of 3 September 2020 TABLE H3 SUMMARY OF FLOW IN CAPE FEAR RIVER AT WILM O'HUSKE LOCK NR TARHEEL, NC Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC, P.C. Date USGS Reported Average Discharge1 (cfs) USGS Reported Average Gage Height1 (ft) USGS Reported Total Precipitation1,2 (inches) USGS Reported Average Discharge (L/s) Measured River Width (ft) Estimated River Depth (ft)Z Value3 Calculated Total Cross Sectional Area (ft2) Calculated River Velocity (ft/s) 5/13/2020 1,639 1.83 0.00 46,416 323 18 2 5,258 0.3 5/14/2020 1,412 1.65 0.00 39,997 323 18 2 5,213 0.3 Average River Velocity:0.3 Notes: 1) Measurements are recorded from the USGS flow gauging station at the W.O. Huske Dam, ID 02105500 (USGS, 2020). 2) The minimum value recorded by a USGS raingage is 0.01 inches. Anything detected below this threshold is recorded as 0 inches. 3) Z value is an estimated factor used to compute total cross sectional area from river depth. cfs: cubic feet per second. ft: feet. ft2: feet squared. ft/s: feet per second L/s: Liter per second. mph: miles per hour. USGS - United States Geological Survey. TR0795 Page 1 of 1 September 2020 TABLE H4 RATIO OF OTHER PFAS COMPOUNDS TO HFPO-DA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Location ID SEEP-E SEEP-E SEEP-F SEEP-F SEEP-G SEEP-G SEEP-H Field Sample ID SEEP-E-0930 Seep E-030420 SEEP-F-0923 Seep F-030420 SEEP-G-0911 Seep G-030420 SEEP-H-0905 Sample Date 10/22/2019 3/4/2020 10/22/2019 3/4/2020 10/22/2019 3/4/2020 10/22/2019 QA/QC -------------- Sample Delivery Group (SDG) 320-55576-1 2091227 320-55576-1 2091227 320-55576-1 2091227 320-55576-1 Lab Sample ID 320-55576-1 1274949 320-55576-2 1274953 320-55576-3 1274957 320-55576-4 Table 3+ SOP (ng/L) Hfpo Dimer Acid 1,200 950 1,100 1,100 700 730 550 PFMOAA 480 J 390 900 730 190 220 140 PFO2HxA 800 470 810 640 470 410 350 PFO3OA 170 83 130 110 57 56 28 PFO4DA 83 17 7.3 9.1 9 7.9 <2 PFO5DA 46 <2 <2 <2 <2 <2 <2 PMPA 2,300 1,800 2,800 2,100 1,500 1,500 1,200 PEPA 710 600 870 710 490 520 360 PS Acid (Formerly PFESA-BP1)<2 <2 <2 <2 <2 <2 <2 Hydro-PS Acid (Formerly PFESA-BP2)90 24 9.6 10 22 11 16 R-PSDA (Formerly Byproduct 4)220 J 53 J 92 68 J 79 J 44 J 39 J Hydrolyzed PSDA (Formerly Byproduct 5)2.1 J <2 <2.9 <2 <2 <2 <2 R-PSDCA (Formerly Byproduct 6)<2 <2 <2 <2 <2 <2 <2 NVHOS 15 6 12 8 5.4 5 4.3 EVE Acid <2 <2 <2 <2 <2 <2 <2 Hydro-EVE Acid 7.7 2.3 2 <2 <2 <2 <2 R-EVE 76 20 60 40 39 28 21 J PES <2 <2 <2.3 <2 <2 <2 <2 PFECA B <2 <2 <3 <2 <2 <2 <2 PFECA-G <2 <2 <2 <2 <2 <2 <2 Total Table 3+ (17 Compounds) (ng/L)5,900 4,300 6,600 5,400 3,400 3,500 2,600 Total Table 3+ (20 Compounds) (ng/L)6,200 4,400 6,800 5,500 3,600 3,500 2,700 Ratio of Total Table 3+ (17 Compounds) to HFPO-DA 4.9 4.5 6.0 4.9 4.9 4.8 4.7 Ratio of Total Table 3+ (20 Compounds) to HFPO-DA 5.2 4.6 6.2 5.0 5.1 4.8 4.9 Average Ratio of Total Table 3+ (17 Compounds) to HFPO-DA 4.87 Average Ratio of Total Table 3+ (20 Compounds) to HFPO-DA 5.03 TR0795 Page 1 of 3 September 2020 TABLE H4 RATIO OF OTHER PFAS COMPOUNDS TO HFPO-DA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample ID Table 3+ SOP (ng/L) Hfpo Dimer Acid PFMOAA PFO2HxA PFO3OA PFO4DA PFO5DA PMPA PEPA PS Acid (Formerly PFESA-BP1) Hydro-PS Acid (Formerly PFESA-BP2) R-PSDA (Formerly Byproduct 4) Hydrolyzed PSDA (Formerly Byproduct 5) R-PSDCA (Formerly Byproduct 6) NVHOS EVE Acid Hydro-EVE Acid R-EVE PES PFECA B PFECA-G Total Table 3+ (17 Compounds) (ng/L) Total Table 3+ (20 Compounds) (ng/L) Ratio of Total Table 3+ (17 Compounds) to HFPO-DA Ratio of Total Table 3+ (20 Compounds) to HFPO-DA Average Ratio of Total Table 3+ (17 Compounds) to HFPO-DA Average Ratio of Total Table 3+ (20 Compounds) to HFPO-DA SEEP-H SEEP-I SEEP-I SEEP-J SEEP-J SEEP-K SEEP-K Seep H-030420 SEEP-I-0856 Seep I-030420 SEEP-J-0843 Seep J-030420 SEEP-K-0835 Seep K-030420 3/4/2020 10/22/2019 3/4/2020 10/22/2019 3/4/2020 10/22/2019 3/4/2020 -------------- 2091227 320-55576-1 2091227 320-55576-1 2091227 320-55576-1 2091227 1274961 320-55576-5 1274965 320-55576-6 1274969 320-55576-7 1274973 540 570 470 580 250 640 490 180 130 200 180 J 140 160 210 330 300 280 350 J 130 320 230 30 17 18 120 J 16 41 28 <2 <2 <2 58 4.7 11 5 <2 <2 <2 20 J 2.2 4.8 <2 1,100 1,200 1,100 810 J 660 1,300 1,000 360 390 390 260 200 400 350 <2 <2 <2 <2 <2 <2 <2 9.3 12 12 37 6.9 70 16 30 J 53 J 36 110 J 23 130 J 49 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 3.7 4.4 4.5 8.1 J 2.8 5.2 4.7 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2.7 <2 3.5 <2 20 23 J 17 16 13 46 J 25 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 <2 2,600 2,600 2,500 2,400 1,400 3,000 2,300 2,600 2,700 2,500 2,600 1,400 3,100 2,400 4.8 4.6 5.3 4.1 5.6 4.7 4.7 4.8 4.7 5.3 4.5 5.6 4.8 4.9 4.87 5.03 TR0795 Page 2 of 3 September 2020 TABLE H4 RATIO OF OTHER PFAS COMPOUNDS TO HFPO-DA Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC P.C. Location ID Field Sample ID Sample Date QA/QC Sample Delivery Group (SDG) Lab Sample ID Table 3+ SOP (ng/L) Hfpo Dimer Acid PFMOAA PFO2HxA PFO3OA PFO4DA PFO5DA PMPA PEPA PS Acid (Formerly PFESA-BP1) Hydro-PS Acid (Formerly PFESA-BP2) R-PSDA (Formerly Byproduct 4) Hydrolyzed PSDA (Formerly Byproduct 5) R-PSDCA (Formerly Byproduct 6) NVHOS EVE Acid Hydro-EVE Acid R-EVE PES PFECA B PFECA-G Total Table 3+ (17 Compounds) (ng/L) Total Table 3+ (20 Compounds) (ng/L) Ratio of Total Table 3+ (17 Compounds) to HFPO-DA Ratio of Total Table 3+ (20 Compounds) to HFPO-DA Average Ratio of Total Table 3+ (17 Compounds) to HFPO-DA Average Ratio of Total Table 3+ (20 Compounds) to HFPO-DA SEEP-L SEEP-M SEEP-L-0825 SEEP-M-0818 10/22/2019 10/22/2019 ---- 320-55576-1 320-55576-1 320-55576-8 320-55576-9 520 570 Notes: 130 100 Bold - Analyte detected above associated reporting limit 220 190 J - Analyte detected. Reported value may not be accurate or precise 18 15 ng/L - nanograms per liter 2.7 <2 QA/QC - Quality assurance/ quality control <2 <2 SOP - standard operating procedure 1,200 1,300 < - Analyte not detected above associated reporting limit. 350 410 <2 <2 44 28 120 J 78 J <2 <2 <2 <2 5.9 5.6 <2 <2 <2 <2 44 J 26 J <2 <2 <2 <2 <2 <2 2,500 2,600 2,700 2,700 4.8 4.6 5.2 4.7 4.87 5.03 TR0795 Page 3 of 3 September 2020 TABLE H5 CALCULATION OF HFPO-DA DEPOSITED MASS AND MASS FLUX Chemours Fayetteville Works, North Carolina Geosyntec Consultants NC P.C. Section1 Depositon Rate at Section Start (µg/m2/yr) Depositon Rate at Section End (µg/m2/yr) Start Deposition Rate2 (ng/m2/hr) End Deposition Rate2 (ng/m2/hr) Average Deposition Rate (ng/m2/hr) Section Distance3 (m) Average River Width4 (m) Section Area (m2) Estimated River Velocity5 (ft/s) Estimated River Velocity (m/hr) Estimated Travel Time (hr) Calculated Mass Deposited (mg) Calculated Mass Discharge (mg/s) Center 160 160 18.3 18.3 18 903 98.6 89,028 0.3 319.7 2.8 4.6 0.00045 Up River Section 1 160 80 18.3 9.1 14 490 98.6 48,300 0.3 319.7 1.5 1.0 0.00018 Up River Section 2 80 40 9.1 4.6 6.8 909 98.6 89,570 0.3 319.7 2.8 1.7 0.00017 Down River Section 1 160 80 18.3 9.1 14 586 98.6 57,813 0.3 319.7 1.8 1.5 0.00022 Down River Section 2 80 40 9.1 4.6 6.8 565 98.6 55,672 0.3 319.7 1.8 0.7 0.00011 Total HFPO-DA:0.0011 Total Table 3+ (17 Compounds):0.01 Total Table 3+ (20 Compounds):0.01 Notes: 1River sections for air deposition calculations are shown in Figures H2 through H6. 2Based on model deposition rate, Table H1. 3Section distances are measured in GIS, presented in Figures H2 through H6. 4Calculations for the average river width are presented in Table H2. 5River velocity is calculated as an average from USGS discharge data between May 13 to 14, 2020, Table H3. HFPO-DA: Hexafluoropropylene oxide dimer acid; or dimer acid µg/m2/yr: micrograms per meter square per year ft/s: feet per second hr: hours m/hr: meters per hour m: meter m2: meter square mg/s: milligrams per second mg: milligrams ng/m2/hr: nanograms per meter square per hour TR0795 Page 1 of 1 September 2020 591595 616535 619506 602061604474 608468 587968614517 590322600052596259 594185597968610240606667612082 613542 614224 Cape Fear River Cross Sections Locations Chemours Fayetteville Works, North Carolina Figure H1 Notes:1. Cape Fear River cross section locations obtained from "A Report of Flood Hazards in Bladen County, North Carolina and Incorporated Areas." (2007) Flood Insurance Study, Federal Emergency Management Agency. North Carolina Flood Risk Information System Engineering Model. Cape Fear RiverADJ. HEC-RAS 5.0.7.2. Cross sections used for calculation of average river widths for calculation of aerial mass loading.Raleigh, NC 1 0 10.5 Miles ³ September 2020 Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend Cross Section Length (m): 903.00 Measurement of Cape Fear River Length at Center Section Chemours Fayetteville Works, North Carolina Figure Notes:HFPO-DA - Hexafluoropropylene oxide dimer acid; or dimer acid; or GenX µg / m2/yr - micrograms per square meter per year HFPO-DA deposition model contours for October 2018 from ERM, 2018, Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. 1 0 10.5 Miles ³ Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend ite Boundary 40 µg/m2/yr 80 µg/m2/yr 160 µg/m2/yr 320 µg/m2/yr 640 µg/m2/yr H2 Modeled Deposition Contours, October 2018 Scenario September 2020 Raleigh, NC Raleigh, NC Length (m): 489.90 Measurement of Cape Fear River Length at Up-River Section 1 Chemours Fayetteville Works, North Carolina Figure Notes:HFPO-DA - Hexafluoropropylene oxide dimer acid; or dimer acid; or GenX µg /m2/yr - micrograms per square meter per year HFPO-DA deposition model contours for October 2018 from ERM, 2018, Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. 1 0 10.5 Miles ³ Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend Site Boundary Modeled Deposition Contours, October 2018 Scenario 40 µg/m2/yr 80 µg/m2/yr 160 µg/m2/yr 320 µg/m2/yr 640 µg/m2/yr H3Raleigh, NC September 2020 Length (m): 908.05 Measurement of Cape Fear River Length at Up-River Section 2 Chemours Fayetteville Works, North Carolina Figure Notes:HFPO-DA - Hexafluoropropylene oxide dimer acid; or dimer acid; or GenX µg / m2/yr - micrograms per square meter HFPO-DA deposition model contours for October 2018 from ERM, 2018, Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. 1 0 10.5 Miles ³ Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend Site Boundary Modeled Deposition Contours, October 2018 Scenario 40 µg/m2/yr 80 µg/m2/yr 160 µg/m2/yr 320 µg/m2/yr 640 µg/m2/yr H4Raleigh, NC September 2020 Length (m): 586.39 Measurement of Cape Fear River Length at Down-River Section 1 Chemours Fayetteville Works, North Carolina Figure Notes:HFPO-DA - Hexafluoropropylene oxide dimer acid; or dimer acid; or GenX µg /m2/yr - micrograms per square meter per year HFPO-DA deposition model contours for October 2018 from ERM, 2018, Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. Raleigh, NC 1 0 10.5 Miles ³ Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend Site Boundary Modeled Deposition Contours, October 2018 Scenario 40 µg/m2/yr 80 µg/m2/yr 160 µg/m2/yr 320 µg/m2/yr 640 µg/m2/yr H5September 2020 Length (m): 564.68 Measurement of Cape Fear River Length at Down-River Section 2 Chemours Fayetteville Works, North Carolina Figure Notes:HFPO-DA - Hexafluoropropylene oxide dimer acid; or dimer acid; or GenX µg /m2/yr - micrograms per square meter per year HFPO-DA deposition model contours for October 2018 from ERM, 2018, Modeling Report: HFPO-DA Atmospheric Deposition and Screening Groundwater Effects. 27 April 2018. Raleigh, NC 1 0 10.5 Miles ³ Projection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US Legend Site Boundary Modeled Deposition Contours, October 2018 Scenario 40 µg/m2/yr 80 µg/m2/yr 160 µg/m2/yr 320 µg/m2/yr 640 µg/m2/yr H6September 2020 !( !( !( !( !( !( !( !(!(Cape Fear RiverSEEP-E SEEP-F SEEP-G SEEP-H SEEP-I SEEP-J SEEP-K SEEP-LSEEP-M Old Outfall 00 2 Willis Creek Georgi a B r a n c h C r e e k Figure H7Raleigh ³Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Baseline Monitoring Workplan\TR0795_Offsite_Seep_Locations.mxd Last Revised: 7/30/2020 Author: jkasunicProjection: NAD 1983 StatePlane North Carolina FIPS 3200 Feet; Units in Foot US 1,000 0 1,000500 FeetLegend Observed Seep Nearby Tributary Site Boundary Notes:1. Seep E to M samples were collected where the seeps enteredthe Cape Fear River. Their locations on this figure have beenslightly adjusted to facilitate interpretation so that they do notappear to be in the Cape Fear River.2. The outline of Cape Fear River is approximate and is basedon open data from ArcGIS Online and North CarolinaDepartment of Environmental Quality Online GIS (MajorHydroshapefile).3. Basemap Source: Esri, DigitalGlobe, GeoEye, EarthstarGeographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN,and the GIS User Community Chemours Fayetteville Works, North Carolina Southwestern Offsite Seeps Locations September 2020 September 2020 APPENDIX I Supporting Calculations –Adjacent and Downstream Offsite Groundwater Appendix I 1 September 2020 APPENDIX I ADJACENT AND DOWNSTREAM OFFSITE GROUNDWATER This appendix presents the methodology for calculating the PFAS mass discharge from adjacent and downstream offsite groundwater to the Cape Fear River. PFAS detected in offsite groundwater originate from aerial deposition which has occurred in all directions from the Site (CAP Geosyntec, 2019g). These aerially deposited PFAS have subsequently infiltrated to groundwater and migrate towards the Cape Fear River where they lead to upstream, adjacent and downstream offsite groundwater PFAS mass. The upstream offsite groundwater PFAS mass discharge is estimated relatively simply by using measured river flows and concentrations at River Mile 76 upstream of the Site. Here only the upstream offsite groundwater PFAS mass discharge is present in the river at this location. Conversely, the adjacent and downstream offsite groundwater PFAS mass discharge is difficult to measure directly since many PFAS mass discharges from all other pathways are present in the river where these offsite groundwater contributions join the river. Additionally, downstream offsite groundwater has a relatively small component of the Total PFAS mass discharge making its additional contributions to the total discharge difficult to distinguish from other discharges already present. Therefore, since PFAS mass discharge from offsite groundwater upstream, adjacent, and downstream of the Site follow the same dynamics (deposition, infiltration, migration, discharge) the adjacent and downstream PFAS mass discharge is scaled from the upstream offsite groundwater mass discharge estimate. The downstream offsite groundwater loadings are scaled to the upstream offsite groundwater loadings based on the length of river adjacent and downstream of the Site known to be in contact with offsite groundwater containing PFAS compared to the length of the river upstream also in contact with offsite groundwater containing PFAS. The volume of river flow is assumed to be constant immediately upstream and downstream of the Site for the purposes of this calculation. This adjacent and downstream offsite mass discharge is calculated using Equation 1 below: Equation 1: Total Mass Discharge Adjacent and Downstream Offsite Groundwater 𝑀𝑀𝑀𝑀𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎−𝑔𝑔𝑔𝑔= ��𝐶𝐶𝑢𝑢𝑢𝑢−𝑔𝑔𝑔𝑔,𝑖𝑖× 𝑄𝑄𝐶𝐶𝐶𝐶𝐶𝐶� × 𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎 𝐼𝐼 𝑖𝑖=1 where, 𝑀𝑀𝑀𝑀𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎−𝑔𝑔𝑔𝑔 = represents the Total PFAS discharge from adjacent and downstream offsite groundwater to the Cape Fear River, units in mass per unit volume [ML-3], typically milligram per second; i = represents each of the PFAS constituents listed in Table I1; Appendix I 2 September 2020 I = represents total number of PFAS constituents included in the summation of Total PFAS concentrations; 𝐶𝐶𝑢𝑢𝑢𝑢−𝑔𝑔𝑔𝑔,𝑖𝑖 = represents the upstream concentration of each PFAS constituent i from measured units in mass per unit volume [ML-3], typically nanograms per liter; 𝑄𝑄𝐶𝐶𝐶𝐶𝐶𝐶 = represents the volumetric flow in the Cape Fear River as reported by the United States Geological Survey gage at the W.O. Huske Dam, station ID 02105500 with units used in the equation expressed as volume per time [L3T-1], typically liters per second; and 𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎 = represents the unitless scaling factor to adjust offsite upstream groundwater mass discharge to offsite adjacent and downstream mass discharge. Where 𝑓𝑓𝑢𝑢𝑢𝑢−𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎 is calculated following Equation 2 below: Equation 2: Offsite Upstream Groundwater to Adjacent and Downstream Offsite Groundwater Mass Discharge Scaling Factor 𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎= 𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎𝑎𝑎𝑎𝑎+ 2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑢𝑢𝑢𝑢 where, 𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎𝑎𝑎𝑎𝑎 = represents the length of the Cape Fear River adjacent to the Site (i.e., the east bank of the Cape Fear River opposite the Site) where PFAS have been detected in offsite groundwater within one mile of the river. 2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎 = represents the length of the Cape Fear River downstream of the Site where PFAS have been detected in offsite groundwater within one mile of the river. This quantity is multiplied by two (2) as the river has two downstream sides (east and west) from which groundwater discharge can reach the Cape Fear River (adjacent only has one side, east). 2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑢𝑢𝑢𝑢 = represents the length of the Cape Fear River upstream of the Site where PFAS have been detected in offsite groundwater within one mile of the river. This quantity is multiplied by two (2) as the river has two upstream sides (east and west) from which groundwater discharge can reach the Cape Fear River (adjacent only has one side, east). Figure I1 displays the quantities used in calculating the scaling factor 𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎 on a map of the Cape Fear River and Table I-1 provides a calculation of 𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎. TABLE I1 OFFSITE AND ADJACENT DOWNSTREAM GROUNDWATER MASS DISCHARGE SCALING FACTOR Chemours Fayetteville Works, North Carolina Geosyntec Consultants of NC, PC Item Value Unit l CFR-up 14.2 miles l CFR-adj 1.7 miles l CFR-d 4.5 miles f adj-d 0.38 -- Calculation Notes for Offsite Upstream Groundwater to Offsite Adjacent and Downstream Groundwater Mass Discharge Scaling Factor𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎=𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎𝑎𝑎𝑎𝑎+ 2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑢𝑢𝑢𝑢where,𝑓𝑓𝑎𝑎𝑎𝑎𝑎𝑎−𝑎𝑎=represents the unitless scaling factor to adjust offsite upstream groundwater mass discharge to offsite adjacent and downstream mass discharge. 𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎𝑎𝑎𝑎𝑎= represents the length of the Cape Fear River adjacent to the Site (i.e. the east bank of the Cape Fear River opposite the Site) where PFAS have been detected in offsite groundwater within one mile of the river.2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑎𝑎= represents the length of the Cape Fear River downstream of the Site where PFAS have been detected in offsite groundwater within one mile of the river. This quantity is multiplied by two (2) as the river has two downstream sides (east and west) from which groundwater discharge can reach the Cape Fear River (adjacent only has one side, east).2𝑙𝑙𝐶𝐶𝐶𝐶𝐶𝐶−𝑢𝑢𝑢𝑢= represents the length of the Cape Fear River upstream of the Site where PFAS have been detected in offsite groundwater within one mile of the river. This quantity is multiplied by two (2) as the river has two upstream sides (east and west) from which groundwater discharge can reach the Cape Fear River (adjacent only has one side, east). TR0795 Page 1 of 1 September 2020 !5 !5 !5 ChemoursFayettevilleWorks Tar Heel Ferry RoadBridge CFR-BLADEN Mile 76 4.5 Miles Downstream of Old Outfall 14.2 Miles Upstream of Site 1.6 Miles Adjacent of Site Estimated Extents of Offsite Groundwater Contributions to Cape Fear River Attachment C PFAS Mass Loads Chemours Fayetteville Works, North Carolina Figure I1Raleigh Path: P:\PRJ\Projects\TR0795\Database and GIS\GIS\Baseline Monitoring Workplan\TR0795_1MileResidentialDetects.mxd; jkasunic; 07/27/2020September 2020 ³ 2 0 21 Miles Notes:Basemap sources: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User Community. Projection: WGS 1984 Web Mercator Auxiliary Sphere; Units in Meter Legend Offsite Groundwater Sampling Location with Detected Result !5 Selected Prior Cape Fear River Sampling Locations Detected Results within 1 mile of Cape Fear River Chemours Fayetteville Works Cape Fear River