3902_Granville_Butner_MSWLF_Feb21GW_FID1584629_20210602

LaBella
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June 2, 2021
Ms. Jaclynne Drummond
Dept. of Environmental and Natural Resources
Solid Waste Section
Asheville Regional Office
2090 US Highway 70
Swannanoa, NC 28778
Via Email: [e-mail]
RE: Quality Monitoring Report — February 2021 Event
Granville County — Butner Landfill, Permit No. 39-02
Project No. 2203013, Phase 06
Dear Jackie:
On behalf of Granville County, LaBella Associates is submitting this Water Quality Monitoring Report
(WQMR) for the Butner Landfill (Permit No. 39-02) via email. If you have any questions, please contact
Miguel Vazquez at (336) [e-mail]. Thank you.
Respectfully submitted,
LaBella Associates
rr.itt�
Elina Wright
Environmental Field Technichian
Enclosure
cc: Jason Falls, Granville County
2211 W. Meadowview Road #101 1 Greensboro, NC 27407 p [phone]
www.LabeLLapc.com

Yes / No ) Doc/Event #:
Signatu'm' Date
2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-0782
NC PE Firm License Number (if applicable effective May 1, 2009)
'NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1 As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Elina Wright Phone: [phone]
E-mail: [e-mail]
INC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Butner Landfill State Road 1004 39-02 .1600 February 11, 2021
Butner, NC
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑ Detection Monitoring X❑ Assessment Monitoring ❑X Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑
Groundwater monitoring data from private water supply wells 0
Leachate monitoring data
Surface water monitoring data ❑
Methane gas monitoring data
Corrective action data (specify) MNA Data
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Miguel A Vazquez, PG Senior Technical Consultant [phone]
(Print) Title (Area Code) Telephone Number
(
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Prepared For:
Granville County
Solid Waste Department
P.O. Box 906
Oxford, North Carolina 27565
�7746.
SuDinitted by:
LaBella Associates (Joyce Engineering)
2211 West Meadowview Rd.
Suite 101
Greensboro, NC 27407
[phone]
NC License No. C-0782
LaBeRa
Powered by partnership.
FEBRUARY 2021 WATER QUALITY MONITORING REPORT
BUTNER LANDFILL
Permit No. 39-02
June 2021
Project no. 2203013/06

February 2021 Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS
I_T110910119AK
1.0
INTRODUCTION................................................................................................................................1
1.1
Site Information..............................................................................................................................1
1.2
Site Geology.....................................................................................................................................1
1.3
Regulatory Status............................................................................................................................1
2.0
FACILITY MONITORING PROGRAM.................................................................................................2
2.1
Groundwater Monitoring Program.................................................................................................2
2.2
Surface Water Monitoring Program...............................................................................................3
3.0
February 2021 SAMPLING EVENT.................................................................................................3
3.1
Field Work........................................................................................................................................3
3.3
Laboratory Analyses and Quality Control.......................................................................................3
4.0
ANALYTICAL RESULTS AND STATISTICAL ANALYSES....................................................................4
4.1
Analytical Results for Groundwater and Comparisons to Standards..........................................4
4.1.1
Inorganic Analyses...............................................................................................................4
4.1.2 Organic Analyses..................................................................................................................2
4.2 Statistical Analyses.........................................................................................................................2
4.2.1 Statistical Methods..............................................................................................................2
4.2.2 Results of Statistical Analyses............................................................................................2
4.3
Analytical Results for Surface Water and Comparisons to Standards........................................3
5.0
HYDROGEOLOGICAL CONDITIONS.................................................................................................3
6.0
CORRECTIVE ACTION EVALUATION................................................................................................4
6.1
Monitored Natural Attenuation Parameters..................................................................................4
6.2
Phytoremediation............................................................................................................................4
6.3
Evaluation of Plume Stability and Trends......................................................................................4
7.0
CONCLUSIONS.................................................................................................................................5
8.0
REFERENCES...................................................................................................................................5
Granville County- Butner Landfill, Permit No. 39-02 La Bella Associates
February 2021 Water Quality Monitoring Report

Tables
Chants
Figure
February 2021 Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (Continued)
Table 1 February 2021 Groundwater Elevations
Table 2 February 2021 Field Parameters
Table 3 February 2021 Detected Constituents in Groundwater and Surface Water
Table 4 February 2021 Exceedances of Groundwater Standards
Table 5 February 2021 Hydraulic Gradients and Groundwater Flow Velocities
Table 6 February 2021 Monitored Natural Attenuation Parameters
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time
Figure 1 Site Location Map
Drawings
Drawing 1 Groundwater Potentiometric Surface Map
Appendices
Appendix A
Monitoring Well Construction Data
Appendix B
Field Data Logs
Appendix C
Laboratory Analytical Reports and Chains of Custody
Appendix D
Historical Groundwater Elevations
Appendix E
Historical Constituents in Groundwater
Appendix F
Historical Constituents in Surface Water
Appendix G
Historical Monitoring Natural Attenuation Parameters
Granville County - Butner Landfill, Permit No. 39-02 La Bella Associates
February 2021 Water Quality Monitoring Report

ACRONYMS
ACM Assessment of Corrective Measures (Report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site -specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
IMAC Interim maximum Allowable Concentration
JOYCE Joyce Engineering
LaBella LaBella Associates PC
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC213 North Carolina Surface Water Standards found in 15A NCAC 213
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 1313.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
0&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
RL Reporting Limit (for laboratory data)
SWS Solid Waste Section (of NCDENR/NCDEQ)
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)
Granville County - Butner Landfill, Permit No. 39-02 LaBella Associates
February 2021 Water Quality Monitoring Report

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the town of Butner, in Granville County, North Carolina (Figure 1). The Butner facility started
receiving solid waste prior to May 1973. Permit Number 39-02, was issued by the State of North
Carolina on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the
present, a small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.
In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the Butner
Landfill entered an Assessment Monitoring Program in December of 1997 as a result of detections
of volatile organic compounds and pesticides above Title 15A of the North Carolina Administrative
Code Subchapter 2L (NC2L) Groundwater Standards. An Assessment of Corrective Measures (ACM)
was initiated in 2003, and then suspended by North Carolina Department of Environment and
Natural Resources (NCDENR) [now the North Carolina Department of Environmental Quality
(NCDEQ)] since there had been no more NC2L exceedances. The Nature and Extent Study (NES) and
ACM recommenced in 2007 when apparent volatile organic compound (VOC) exceedances of the
NC2L Standards began to appear; however, they were again suspended when it was determined that
the apparent exceedances were not statistically significant increases (SSIs) above background. An
ACM was reinitiated after an exceedance of benzene in monitoring well MW-2R in December 2012,
and was submitted to NCDENR in May 2013. Approval of the ACM was granted in a letter from
NCDENR dated June 27, 2013. A Corrective Action Plan (CAP) for monitored natural attenuation
(MNA) plus phytoremediation was submitted to NCDENR on May 23, 2014, and was approved by
NCDENR on June 18, 2014.
1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the area
consists of rolling hills that support farmland and forest. The majority of the landfill area is underlain
by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into greenish grey
foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford Formation
(conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina Slate Belt
felsic volcanic rocks. There is no exposure of the Sanford Formation at the site; however, float
material consisting of grey, coarse -grained sandstone with quartz pebbles was observed. Diabase
dikes have also been observed in the vicinity of the site. Geologic descriptions were taken from GAI
Consultants' Groundwater and Surface Water Monitoring System report (GAI, 1994).
1.3 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance with
NCSWMR §.1634-.1637. The site is currently in Assessment Monitoring and a Corrective Action
Monitoring Program. Groundwater samples are collected semiannually and analyzed in accordance
with the approved Corrective Action Plan. Surface water samples are collected and sampled for
Appendix i of 40 CFR Part 258, from here on known as North Carolina (NC) Appendix I list of
constituents during each sampling event.
February 2021 Water Quality Monitoring Report La Bella Associates
Granville County - Butner Landfill, Permit No. 39-02
1

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Seven active groundwater monitoring wells comprise the monitoring network at the Butner Landfill:
MW-1R (facility background well), MW-213, MW-3R, MW-4, MW-5, MW-6, and NES-1(which was
installed as part of a Nature and Extent Study on November 14, 2007). The following table
summarizes the monitoring network and required analytical parameters. A summary of well
construction details is provided in Appendix A.
Groundwater Monitoring Network
Total
Lithology
1st SA
Monitoring
Date
Classification
Monitoring
Depth
of
Event
2nd SA Event
Well
Installed
Program
(feet)
Screened
Analyses
Analyses
Interval
Assessment
App. 11,
App. I + Det.
MW-1R
4/21/94
Background
/CAMP
45.1
Saprolite
MNA*
plus 1,4-
Dioxane
Compliance/
Assessment
App. 11,
App. I + Det.
MW-2R
4/12/94
Performance
/CAMP
19.0
Saprolite
MNA
plus 1,4-
Dioxane, MNA
Compliance/
Assessment
App. 11,
App. I + Det.
MW-3R
4/14/94
Performance
/CAMP
37.2
Bedrock
MNA
plus 1,4-
Dioxane, MNA
MW-4
4/18/94
Compliance
Detection
31.5
Bedrock
App. I
App. I plus
1,4-Dioxane
MW-5
4/18/94
Compliance
Detection
23.4
Saprolite
App. I
App. I plus
1,4-Dioxane
MW-6
4/19/94
Compliance
Detection
31.7
Saprolite/
App I
App. I plus
Bedrock
1,4-Dioxane
NES-1
11/14/07
Nature &
Sentinel
33.0
Saprolite/
COCs,
COCs
Extent
Bedrock
MNA*
Notes:
App. I = NCSWMR Appendix I list of constituents plus 1,4-Dioxane.
App. II = NCSWMR Appendix II list of constituents plus 1,4-Dioxane.
App. I + Det. = App. I list plus detected App. II constituents.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation parameters.
CAMP = Corrective Action Monitoring Plan.
Current Appendix II detected constituents: Tin.
Current COCs: Benzene, 1,4-dioxane, cobalt.
MINA Field Parameters: Temperature, pH, specific conductance, oxidation reduction potential, turbidity, dissolved
oxygen, and ferrous iron. Dissolved carbon dioxide will be tested during both events every third year (next in
2022).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride, biological oxygen demand
(BOD), chemical oxygen demand (COD), and total organic carbon (TOC). Dissolved hydrogen, volatile fatty acids,
sulfide, ethane and ethene are analyzed during both events every third year (next in 2022).
MNA* parameters are only required annually for MW-1R & NES-1.
February 2021 Water Quality Monitoring Report
Granville County - Butner Landfill, Permit No. 39-02
2
La Bella Associates

2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994, at the Butner
Landfill. The surface water sample points SW-1 and SW-2 are located respectively upstream and
downstream of the facility, along an unnamed tributary of Picture Creek. The surface water samples
are analyzed for the NC Appendix I list of constituents plus 1,4-dioxane during both semiannual
events.
3.0 February 2021 SAMPLING EVENT
3.1 Field Work
On February 11, 2021, LaBella Associates PC (LaBella) personnel visited the Butner Landfill to purge
and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. All
monitoring wells were purged and sampled using new, disposable bailers or low -flow sampled via
submersible pump and flow cell. An electronic water level meter was used to take the depth to water
to the nearest 0.01 foot. Calculated groundwater elevations can be found in Table 1.
Measurements of temperature, pH, turbidity, dissolved oxygen, oxidation reduction potential (ORP),
and conductivity were recorded in a field log. Ferrous Iron was also measured for monitoring wells
MW-2R and MW-3R for this sampling event and recorded in the field log. Prior to sampling,
laboratory -supplied containers were prepared with the following information:
• Monitoring well number (completed by laboratory/field personnel),
• Date and time of sample collection (completed by laboratory/field personnel),
• Initials of sampling personnel (completed by laboratory/field personnel),
• Project name and number (completed by the laboratory/field personnel),
• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers or tubing
into the provided laboratory containers, within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory provided cooler and preserved on ice. Field Logs
are provided in Appendix B and field parameters are summarized in Table 2.
Surface water points SW-1 and SW-2 were also sampled during the February 2021 event. SW-1
sample was unable to be analyzed due to misplacement. Field Logs are included in Appendix B and
field parameters are summarized in Table 2.
3.3 Laboratory Analyses and Quality Control
Pace Analytical Services, Inc. of Huntersville, North Carolina, analyzed the February 2021,
groundwater and surface water samples under chain -of -custody control. The groundwater samples
from monitoring wells MW-1R, MW-2R, and MW-3R were analyzed for the NC Appendix II list of
constituents, plus 1,4-dioxane. Groundwater samples from monitoring wells MW-1R, MW-2R,
MW-3R and NES-1 were also analyzed for MNA parameters. Additionally, groundwater from
monitoring well NES-1 was analyzed for benzene, cobalt and vanadium as constituents of concern.
The groundwater samples from monitoring wells MW-4, MW-5, and MW-6 were analyzed for the NC
Appendix I list of constituents plus 1,4-Dioxane.
February 2021 Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02
3

The surface water samples from SW-2 were analyzed for NC Appendix I constituents plus 1,4-dioxane
and hardness during the February 2021 event. According to the Laboratory Sample Conditions and
Verification reports, the water samples were received by the laboratory on February 12, 2021 in
good condition, properly preserved, at proper temperatures, and within analysis hold times.
In addition to samples collected for compliance monitoring at the Butner Landfill, LaBella personnel
collected a Field Blank for the February 2021 Sampling Event as part of the Quality Control/Quality
Assurance program. The Field Blank was analyzed for the NC Appendix I constituents plus 1,4-
dioxane and tin. Also, a Trip Blank that was prepared by the laboratory accompanied the volatile
sampling containers to and from the laboratory. The Trip Blank was analyzed for the NC Appendix I
volatile organic compounds plus 1,4-dioxane. The complete laboratory analytical reports are
included in Appendix C.
Upon receipt of the laboratory data package, LaBella personnel reviewed the following data for:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
• Blank qualified data (B-flags);
• Detections above Groundwater Protection Standards (GPS) as defined in NCSWMR §
.1634(g), which are generally either the Groundwater Standards found in 15A NCAC 2L.0202
(NC2L), the Interim Maximum Allowable Concentrations (IMAC), or a NCDEQ-approved
statistical background value;
• Detections above NC Surface Water Standards established in 15A NCAC 2B (NC2B); and
• Detections that are above historical levels.
The complete laboratory analytical reports and the chains of custody from the February 2021
Sampling Event are included in Appendix C. The historical groundwater elevation data are presented
in Appendix D. Historical analytical results for groundwater and surface water are presented in
Appendices E and F, respectively.
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the method
reportable limit (MRL) or practical quantitation limit (PQL) in one or more wells during the February
2021 Sampling Event:
• barium,
• cadmium,
• cobalt,
• copper,
• nickel,
• vanadium,
• tin, and
• zinc.
Table 3 summarizes all of the detections from the February 2021 Sampling Event.
February 2021 Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02
4

Cobalt was detected in exceedance of the IMAC in MW-2R and MW-5. Vanadium was detected in
exceedance of the IMAC in MW-4 and NES-1. The results for cobalt in MW-2R and MW-5 are
consistent with historical data. Exceedances of groundwater standards from the February 2021
Sampling Event are summarized in Table 4.
No other inorganic constituents were detected above their NC2L/IMAC during the February 2021
sampling event. The laboratory analytical reports and the chains of custody are included in
Appendix C. Complete historical analytical results for inorganic constituents are included in
Appendix E.
4.1.2 Organic Analyses
Chlorobenzene, chloroethane, 1,2-dichlorobenzene, 1,4-dichlorobe nzene, and 1,4-dioxane, benzene,
naphthalene, and vinyl chloride were detected in one or more monitoring wells at quantified
concentrations above the method reportable limit (MRL) or practical quantitation limit (PQL) during
the February 2021 sampling event. Table 3 summarizes all of the detections from the February
2021 Sampling Event. These results are consistent with historical data as shown in Appendix E.
Concentrations of 1,4-dioxane in exceedance of its NC2L standard were reported in monitoring wells
MW-2R, MW-3R, and MW-4. Benzene was detected above the NC2L Standard in MW-2R. The
benzene in MW-2R is consistent with historical data and has been addressed in the ACM, approved
in June 2013, and the CAP, approved in June 2014. Exceedances of groundwater standards from
the February 2021 Sampling Event are summarized in Table 4.
No other organic constituents were detected above their GPS during the February 2021 sampling
event. The laboratory analytical reports and the chains of custody are included in Appendix C.
Historical analytical results for organic constituents are presented in Appendix E.
4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up -gradient background well for the facility. Data from
MW-1R between September 1994 and February 2021 have been used to determine interwell
statistical background concentrations for constituents detected at the facility.
The background data are evaluated using the Shapiro-Francia Test of Normality, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction
Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the
background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one -tailed tests. The data are evaluated to
determine the appropriate procedure for calculation of the background value for each parameter.
4.2.2 Results of Statistical Analvses
No statistical analyses were performed for this event.
February 2021 Water Quality Monitoring Report La Bella Associates
Granville County - Butner Landfill, Permit No. 39-02
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4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water point SW-2 was sampled during the February 2021 Sampling Event. Four Appendix I
constituents were detected above the MRL in the SW-2 samples. Barium, chromium, nickel and 1,4-
dioxane were detected but were below NC213 standards. The detections in surface water samples
are included in Table 3 and historical surface water data are presented in Appendix G.
5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks northeast
of the landfill. Groundwater flow direction at deeper levels within the fractured bedrock is controlled
by fracture orientation.
Depth to groundwater was measured in the compliance monitoring wells at the site prior to purging.
The groundwater elevations were calculated relative to the surveyed measuring point (top of casing)
for each monitoring well. A groundwater surface contour map, developed with static water level data
obtained on February 11, 2020, is presented as Drawing 1. The static water elevations depict
groundwater flow to the southeast. The historical groundwater elevations are summarized in
Table 1.
Horizontal groundwater gradients along a representative flow path was estimated from the February
2021 groundwater contours shown on Drawing 1 and are summarized in Table 5. The average
horizontal hydraulic gradient (i) across the site was approximately 0.04
Linear groundwater flow velocities were computed using the modified Darcy equation:
Where:
V = Ki/ne
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from single
well aquifer test commonly known as slug -tests conducted in 1994 (GAI, 1994) was used in these
calculations. The average effective porosity (ne = 18%) based on 90% of reported total porosity for
soils (GAI, 1994). Although the regolith and bedrock are hydraulically connected, the effective
porosity generally decreases with depth into the underlying fractured bedrock. Groundwater flow
direction beneath the landfill is predominantly to the southeast. The calculated flow velocity was 5.3
feet/yea r.
Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for this
site.
February 2021 Water Quality Monitoring Report La Bella Associates
Granville County - Butner Landfill, Permit No. 39-02
3

6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Monitoring wells MW-1R, MW-2R, MW-3R and NES-1 were analyzed for the following MNA
parameters during the February 2021 sampling event:
MNA Field Parameters: Temperature, pH, conductivity, oxidation reduction potential,
turbidity, dissolved oxygen, and ferrous iron. (Dissolved carbon dioxide is analyzed every 3rd
year)
MNA Laboratory Parameters: Alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC), methane,
ethane, ethane and dissolved hydrogen.
The current MNA parameter data are presented in Table 6 and the and historical MNA parameters
are included in Appendix G, and the laboratory analytical report for MNA parameters for the February
2021 sampling event is included in Appendix C. Based on response from NCSWMR to the first
Corrective Action Evaluation Report (CAER) submitted in December 2016, changes to the CAP were
implemented starting with the February 2017 event and the following parameters are now monitored
during both sampling events every third year:
• Dissolved carbon dioxide,
• dissolved hydrogen,
• sulfide,
• volatile fatty acids,
• dissolved methane,
• ethene, and
• ethane.
The next time these parameters will be monitored will be in February 2022.
6.2 Phytoremediation
The seventh phytoremediation tree survey for the Butner Landfill was conducted on July 30th, 2020.
The CAP requires annual tree surveys and the next survey will be scheduled for summer 2021.
6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R). There were no benzene detections prior to December 2006; however,
from December 2006 to present, benzene in MW-2R has fluctuated between 1 pg/I and 2 pg/I and
shows a slight downward trend overall; however, the last few events suggest a recent upward trend
but the
February sampling event may have started a downward trend again. From December 2007 to
present, benzene in MW-3R has fluctuated between 0.3 pg/L and 0.7 pg/L and shows a slight
upward trend. Benzene in MW-4 has fluctuated between non -detect and 0.4 pg/L. Over the last two
years, benzene in MW-4 has not been detected. Also, the chart suggests that there is seasonal
fluctuation on the benzene concentrations.
February 2021 Water Quality Monitoring Report La Bella Associates
Granville County - Butner Landfill, Permit No. 39-02
4

The benzene concentrations from the February 2021 Sampling Event, although lower than the
previous (August 2019) event, are within the range of historical fluctuations. Since there have been
no detections of benzene in either the surface water or sentinel well NES-1, there is no indication
that the plume in migrating toward the property boundary. The plume appears to be stable.
Chart 2 presents a plot of the cobalt concentrations versus time in the monitoring wells where it has
been detected in exceedance of the GPS (MW-2R and MW-5). Cobalt in MW-2R has ranged between
non -detection and 38.0 pg/I, but has been consistently between 8.3 and 10.7 pg/I since August
2014. Cobalt in MW-5 has fluctuated between non -detection and 251 pg/I, with large fluctuations
that appear to have a seasonal component (lower in winter and higher in summer); however, there
are inconsistencies (the highest historical concentration was in June 2002). There is no apparent
increasing or decreasing trend for cobalt in either well.
7.0 CONCLUSIONS
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site.
Benzene was detected above the NC2L in MW-2R during the February 2021 sampling event. Review
of MNA parameter data, plume stability, and benzene trends indicate that the selected remedies of
natural attenuation and phytoremediation are adequately controlling the plume.
Cobalt was detected in MW-2R and MW-5 above its corresponding IMAC. This exceedance is
consistent with historical detections. Cobalt has been added to the COC list.
Vanadium was detected above the IMAC in MW-4 and NES-1. The exceedance is consistent with
historical detections. Vanadium was not detected in any other wells during the February 2021
sampling event. An Alternate Source Demonstration (ASD) to determine the statistical background
for vanadium is recommended. If the vanadium in MW-4 is above the statistical background, it
should be added to the COC list.
Analyte 1,4-dioxane was detected above the NC2L standard in MW-2R, MW-3R, and MW-4. Analyte
1,4-Dioxane has been added to the COC list. The facility will remain in Assessment Monitoring and
Corrective Action.
8.0 REFERENCES
GAI Consultants - NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System, Granville
County, Butner Landfill, NC Permit No. 39-02. June, 1994.
Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County, Permit
No. 39-02. May 2014.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN Natural
Attenuation Decision Support System User's Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington DC.
EPA/600/R-96/087. August 1996.
February 2021 Water Quality Monitoring Report La Bella Associates
Granville County - Butner Landfill, Permit No. 39-02
5

Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN Natural
Attenuation Decision Support System, Version 1.4 Revisions. United States Environmental
Protection Agency, Office of Research and Development, Washington DC. July 1997.
North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.
NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste
Management Facilities. March 2007.
February 2021 Water Quality Monitoring Report
Granville County - Butner Landfill, Permit No. 39-02
9
La Bella Associates

TABLES
Table 1 February 2021 Groundwater Elevations
Table 2 February 2021 Field Parameters
Table 3 February 2021 Detected Constituents in Groundwater and Surface Water
Table 4 February 2021 Exceedances of Groundwater Standards
Table 5 February 2021 Hydraulic Gradients and Groundwater Flow Velocities
Table 6 February 2021 Monitored Natural Attenuation Parameters

TABLE 1: February 2021 Groundwater Elevations
Location
Date
TOC Elevation
(Ft AMSL)
Depth to
Groundwater
(Ft BTOC)
Lithology
Well Depth
(Ft BTOC)
Groundwater
Elevation
(Ft AMSL)
MW-1R
2/11/2021
460.51
38.80
Bedrock
56
421.71
MW-2R
2/11/2021
331.60
1.67
Alluvial/
18.85
329.93
Residual
MW-3R
2/11/2021
330.96
1.34
Saprolite
35.83
329.62
MW-4
2/11/2021
340.80
4.21
Bedrock
31.43
336.59
MW-5
2/11/2021
343.88
7.71
Saprolite
23.52
336.17
MW-6
2/11/2021
362.53
7.01
Bedrock
32.63
355.52
NES-1
2/11/2021
328.40
10.30
Bedrock
32.8
318.10
Notes:
Butner Landfill, Granville County
Permit # 39-02
TOC = Top of casing
Ft = feet
BTOC = Below TOC AMSL = Above mean sea level
BGS = Below ground surface
LaBella Associates

TABLE 2: February 2021 Field Parameters
WELL ID
PARAMETER
I RESULTS
UNTILS
SAMPLE DATE
Groundwater
MW-1R
pH
5.65
S.0
2/11/2021
Temperature
15.1
°C
Conductivity
85.2
us/cm
Turbidity
9.00
NTU
Dissolved Oxygen
1.75
mg/L
Ferrous Iron
0
mg/L
Oxidation Reduction Potential
166.8
mV
Static Water Level
38.8
ft
Well Depth
56.00
ft
MW-2R
pH
6.13
S.0
2/11/2021
Temperature
12.4
°C
Conductivity
1251
pS/cm
Turbidity
21.0
NTU
Dissolved Oxygen
1.05
mg/L
Ferrous Iron
1.5
mg/L
Oxidation Reduction Potential
4.1
mV
Static Water Level
1.67
ft
Well Depth
18.85
ft
MW-3R
pH
6.45
S.0
2/11/2021
Temperature
13.6
°C
Conductivity
1004
us/cm
Turbidity
2.65
NTU
Dissolved Oxygen
0.40
mg/L
Ferrous Iron
0.5
mg/L
Oxidation Reduction Potential
34.8
mV
Static Water Level
1.34
ft
Well Depth
35.83
ft
MW-4
pH
5.94
S.0
2/11/2021
Temperature
11.8
°C
Conductivity
838
pS/cm
Turbidity
3.31
NTU
Dissolved Oxygen
7.40
mg/L
Oxidation Reduction Potential
197.4
mV
Static Water Level
4.21
ft
Well Depth
31.43
ft
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 Page 1 of 2

TABLE 2: February 2021 Field Parameters
WELL ID
PARAMETER
I RESULTS
UNTILS
SAMPLE DATE
Groundwater
MW-5
pH
6.3
S.0
2/11/2021
Temperature
11.5
°C
Conductivity
211.3
PS/cm
Turbidity
12.3
NTU
Dissolved Oxygen
5.41
mg/L
Oxidation Reduction Potential
?
mV
Static Water Level
7.71
ft
Well Depth
23.52
ft
M W-6
pH
6.15
S.0
2/11/2021
Temperature
11.3
°C
Conductivity
323.8
PS/CM
Turbidity
7.08
NTU
Dissolved Oxygen
3.23
mg/L
Oxidation Reduction Potential
278.8
mV
Static Water Level
7.01
ft
Well Depth
32.63
ft
NES-1
pH
4.38
S.0
2/11/2021
Temperature
14.0
°C
Conductivity
65.9
PS/CM
Turbidity
65.7
NTU
Dissolved Oxygen
2.18
mg/L
Ferrous Iron
0
mg/L
Oxidation Reduction Potential
284.5
mV
Static Water Level
10.3
ft
Well Depth
36.10
ft
Surface
Water
SW-1
pH
7.36
S.0
2/11/2021
Temperature
7.5
°C
Conductivity
75.2
PS/cm
Turbidity
25.6
NTU
Dissolved Oxygen
10.20
mg/L
Oxidation Reduction Potential
177.8
mV
SW-2
pH
5.28
S.0
2/11/2021
Temperature
7.9
°C
Conductivity
91.3
PS/cm
Turbidity
19.5
NTU
Dissolved Oxygen
10.14
mg/L
Oxidation Reduction Potential
78.5
mV
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 Page 2 of 2

TABLE 3: Detected Constituents in Groundwater
WELL ID PARAMETER RESULT QUALIFIER METHOD MDL MRL STANDARD SOURCE UNITS COLLECT DATE
Groundwater
Arsenic
4.9
1
EPA 6010D
4.7
10
10
INCH
pg/L
MW-1R
Barium
5.3
EPA 6010D
3.5
5
700
NC 2L
pg/L
2/11/2021
Chromium
4.1
1
EPA 6010D
3.7
5
10
NC21-
pig/L
Zinc
12.9
EPA 6010D
9.5
10
1000
NC 2L
pg/L
Arsenic
10
1
EPA 6010D
4.7
10
10
NC 2L
pg/L
Barium
116
EPA 6010D
3.5
5
700
NC 2L
pg/L
Cadmium
0.65
1
EPA 6010D
0.4
1
2
NC 2L
pg/L
Chromium
4
J
EPA 6010D
3.7
5
10
NC 2L
pg/L
Cobalt
10.8
EPA 6010D
3.6
5
1
IMAC
pg/L
Nickel
91.8
EPA 6010D
3.5
5
100
NC 2L
pg/L
MW-2R
Tin
30.1
EPA 6010D
4.7
5
2,000
IMAC
pg/L
2/11/2021
1,2-Dichlorobenzene
1.1
EPA 8260D
0.29
1
20
NC21-
pg/L
1,4-Dichlorobenzene
1.9
EPA8260D
0.26
1
6
NC21-
pg/L
1,4-Dioxane (p-Dioxane)
118
EPA 8260D Mod.
2.3
4
3
NC 2L
pg/L
Benzene
1.8
EPA8260D
0.15
1
1
NC 2L
pg/L
Chlorobenzene
15.1
EPA 8260D
0.23
1
50
NC 2L
pg/L
Chloroethane
1.2
EPA8260D
0.49
1
3000
NC 2L
pg/L
Naphthalene
3.7
EPA8260D
0.35
1
6
NC21-
pg/L
Barium
74.4
EPA 6010D
3.5
5
700
NC 2L
pg/L
Cadmium
0.69
1
EPA 6010D
0.4
1
2
NC 2L
pg/L
Copper
84.8
EPA 6010D
4.3
5
1000
NC 2L
pg/L
Nickel
21.4
EPA 6010D
3.5
5
100
NC 2L
pg/L
Tin
8
EPA 6010D
4.7
5
2,000
IMAC
pg/L
MW-3R
1,2-Dichlorobenzene
0.83
J
EPA8260D
0.29
1
20
NC21-
pg/L
2/11/2021
1,4-Dichlorobenzene
0.76
1
EPA8260D
0.26
1
6
NC21-
pg/L
1,4-Dioxane (p-Dioxane)
53.1
EPA 8260D Mod.
1.2
2
3
NC 2L
pg/L
Chlorobenzene
7.3
EPA8260D
0.23
1
50
NC21-
pg/L
Chloroethane
0.98
J,v1
EPA8260D
0.49
1
3000
NC21-
pg/L
Vinyl chloride
0.53
1
EPA8260D
0.24
1 1
0.03
1 NC 2L
pg/L
Cadmium
1.1
EPA 6010D
0.4
1
2
NC 2L
pg/L
Copper
9.6
EPA 6010D
4.3
5
1000
NC 2L
pg/L
Nickel
13.5
EPA 60101D
3.5
5
100
NC 2L
pg/L
MW-4
Vanadium
13.4
EPA 601013
3.9
5
0.3
IMAC
pg/L
2/11/2021
1,4-Dioxane (p-Dioxane)
40.6
EPA 8260D Mod.
1.2
2
3
NC 2L
pg/L
Chlorobenzene
2.2
EPA 8260D
0.23
1
50
NC21-
pg/L
Chloroethane
1.3
vi
EPA8260D
0.49
1
3000
NC21-
pg/L
Barium
161
EPA 6010D
3.5
1 5
700
NC 2L
pg/L
MW-5
Cobalt
18.6
EPA 6010D
3.6
5
1
IMAC
pg/L
2/11/2021
Nickel
3.9
1
EPA 6010D
3.5
5
100
NC 2L
pg/L
1,4-Dioxane (p-Dioxane)
1.8
1
EPA 8260D Mod.
1.2
2
3
NC 2L
pg/L
NES-1
Cobalt
3.8
1
EPA 6010D
3.6
5
1
IMAC
pg/L
2/11/2021
Vanadium
7.2
EPA 6010D
3.9
5
0.3
IMAC
pg/L
Surtace water
Barium
31.2
EPA 6010D
3.5
5
21000
ISTV
pg/L
Chromium
4
1
EPA 6010D
3.7
5
15850.34
NC 0213*
pg/L
SW-2
Nickel
4.4
1
EPA 6010D
3.5
5
13274.28
NC 02B*
pg/L
2/11/2021
i,4-Dioxane (p-Dioxane)
3
EPA 8260D Mod.
1.2
2
80
ISTV
pg/L
Hardness, Total(SM 2340B)
70000
EPA 6010D
131
662
100000
NC 02B
pg/L
NOTES: All Results in micorgrams per liter (pg/L).
GPS = Water Protection Standard
MDL = Method Detection Level .
MRL = Method Reporting Limit.
1 = Estimated concentration belowthe MRL.
NC21- = NC Groundwater Standard from 15A NCAC 2L.0202.
IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
Bold = GPS Exceedance.
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 1 La Bella Associates

TABLE 4: Exceedances of Groundwater Standards
WELL ID PARAMETER RESULT QUALIFIER METHOD I MDL MRL I STANDARD SOURCE UNITS COLLECT DATE
Groundwater
Cobalt
10.8
EPA 6010D
3.6
5
1
IMAC
pg/L
MW-2R
1,4-Dioxane (p-Dioxane)
118
EPA 8260D Mod.
2.3
4
3
NC 2L
pg/L
2/11/2021
Benzene
1.8
EPA 8260D
0.15
1
1
NC 2L
pg/L
MW-3R
1,4-Dioxane (p-Dioxane)
53.1
EPA 8260D Mod.
1.2
2
3
NC 2L
pg/L
2/11/2021
MW-4
Vanadium
13.4
EPA 6010D
3.9
5
0.3
IMAC
pg/L
2/11/2021
1,4-Dioxane (p-Dioxane)
40.6
EPA 8260D Mod.
1.2
2
3
NC 2L
pg/L
MW-5
Cobalt
18.6
EPA 6010D
3.6
5
1
IMAC
pg/L
2/11/2021
NES-1
Vanadium
7.2
EPA 6010D
3.9
5
0.3
IMAC
pg/L
2/11/2021
NOTES: All Results in micorgrams per liter (pg/L).
GPS = Water Protection Standard
MDL = Method Detection Level .
MRL = Method Reporting Limit.
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 Page 1 of 1

TABLE 5: Hydraulic Gradients and Groundwater Flow Velocities
Based on Water Level Data obtained on: February 11, 2021
GROUND-
HORIZ.
HYDRAULIC
EFFECTIVE
LINEAR
GRADIENT
FLOW LINE
FLOW
WATER
GRADIENT
CONDUCTIVITY
POROSITY
VELOCITY
CALCULATION
LENGTH
DIRECTION
ELEVATION
1
K
n e
V
SEGMENT
(feet)
(feet)
(ft/day)
(ft/year)
1
2133
NE
325
0.042
6.18E-02
0.18
5.3
Notes:
Hydraulic conductivity (K) value is the average of results from slug -tests conducted in 1994 (GAI, 1994).
Effective Porosity (n e ) based on average of 90% of reported Total Porosity (GAI, 1995) for site soils.
Linear flow velocity: V = Kiln e (modified Darcy equation).
See Drawing 1 for Flow Segment.
Granville County, Butner Landfill LaBella Associates
Permit No. 39-02

TABLE 6: February 2021 Monitored Natural Attenuation Parameters
PARAMETER
WELL ID
RESULT
UNITS
METHOD
MDL
MRL
DATE
Chloride
MW-1R
3,670
ug/L
EPA 300.0 Rev 2.11993
600
1,000
2/11/2021
Chloride
MW-2R
201,000 M1
ug/L
EPA 300.0 Rev 2.11993
2,400
4,000
2/11/2021
Chloride
MW-3R
148,000
ug/L
EPA 300.0 Rev 2.11993
1,800
3,000
2/11/2021
Chloride
NES-1
4,060
ug/L
EPA 300.0 Rev 2.11993
600
1,000
2/11/2021
Sulfate
MW-1R
1,410
ug/L
EPA 300.0 Rev 2.11993
500
1,000
2/11/2021
Sulfate
MW-2R
NO
ug/L
EPA 300.0 Rev 2.11993
500
1,000
2/11/2021
Sulfate
MW-3R
819 J
ug/L
EPA 300.0 Rev 2.11993
500
1,000
2/11/2021
Sulfate
NES-1
5,920
ug/L
EPA 300.0 Rev 2.11993
500
1,000
2/11/2021
Nitrogen, Nitrate
MW-1R
56.5
ug/L
EPA 353.2 Rev 2.0 1993
10
40
2/11/2021
Nitrogen, Nitrate
MW-2R
NO
ug/L
EPA 353.2 Rev 2.0 1993
10
40
2/11/2021
Nitrogen, Nitrate
MW-3R
58.7
ug/L
EPA 353.2 Rev 2.0 1993
10
40
2/11/2021
Nitrogen, Nitrate
NES-1
4,650
ug/L
EPA 353.2 Rev 2.0 1993
50
200
2/11/2021
Ethane
MW-1R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethane
MW-2R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethane
MW-3R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethane
NES-1
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethene
MW-1R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethene
MW-2R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethene
MW-3R
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Ethene
NES-1
NS
ug/L
RSK 175 Modified
1
10
2/11/2021
Methane
MW-1R
NO
ug/L
RSK 175 Modified
3
10
2/11/2021
Methane
MW-2R
6,660
ug/L
RSK 175 Modified
3
10
2/11/2021
Methane
MW-3R
519
ug/L
RSK 175 Modified
3
10
2/11/2021
Methane
NES-1
NO
ug/L
RSK 175 Modified
3
10
2/11/2021
Alkalinity, Total as CaCO3
MW-1R
53,900
ug/L
SM 2320B-2011
5,000
5,000
2/11/2021
Alkalinity, Total as CaC04
MW-2R
875,000
ug/L
SM 2320B-2011
5,000
5,000
2/11/2021
Alkalinity, Total as CaCO5
MW-3R
724,000
ug/L
SM 2320B-2011
5,000
5,000
2/11/2021
Alkalinity, Total as CaCO6
NES-1
NO
ug/L
SM 2320B-2011
5,000
5,000
2/11/2021
Sulfide
MW-1R
NS
ug/L
SM 4500-S2D-2011
50
100
2/11/2021
Sulfide
MW-2R
NS
ug/L
SM 4500-S2D-2011
50
100
2/11/2021
Sulfide
MW-3R
NS
ug/L
SM 4500-S2D-2011
50
100
2/11/2021
Sulfide
NES-1
NS
ug/L
SM 4500-S2D-2011
50
100
2/11/2021
BOD, 5 day
MW-1R
NO
ug/L
SM 521OB-2011
2,000
2,000
2/11/2021
BOD, 5 day
MW-2R
9,870 B3
ug/L
SM 521OB-2011
2,000
2,000
2/11/2021
BOD, 5 day
MW-3R
ND
ug/L
SM 521OB-2011
2,000
2,000
2/11/2021
BOD, 5 day
NES-1
ND
ug/L
SM 521OB-2011
2,000
2,000
2/11/2021
Chemical Oxygen Demand
MW-1R
ND
ug/L
SM 5220D-2011
12,500
25,000
2/11/2021
Chemical Oxygen Demand
MW-2R
108,000
ug/L
SM 5220D-2011
12,500
25,000
2/11/2021
Chemical Oxygen Demand
MW-3R
38,000
ug/L
SM 5220D-2011
12,500
25,000
2/11/2021
Chemical Oxygen Demand
NES-1
ND
ug/L
SM 5220D-2011
12,500
25,000
2/11/2021
Total Organic Carbon
MW-1R
ND
ug/L
SM 531OB-2011
500
1,000
2/11/2021
Total Organic Carbon
MW-2R
28,200
ug/L
SM 531OB-2011
500
1,000
2/11/2021
Total Organic Carbon
MW-3R
7,680
ug/L
SM 531OB-2011
500
1,000
2/11/2021
Total Organic Carbon
NES-1
1,610
ug/L
SM 531OB-2011
500
1,000
2/11/2021
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 1 LaBella Associates

CHARTS
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time

2.0
1.8
1.6
C
O
6 1.2
c
N
U
C
O
C
N
N
C
m
1.0
0.8
0.6
0.4
0.2
0.0
r-
O O
UA �
Q ii
r 00 00 0)
O O O O
bA � bA Q
Q ii Q ii
O O O -1 -1 N N M m ;I- L0 Ln (0 (0 r- � ao ao 0) 0) O o r1
O 11 c-I c I -1 11 .-I ci rl c I c-I c I .-I ci c-I c-I c-I c-I c-I ci c-I N N N
bA � bA � bA � CA 4 bA 4 bA 4 bA � bA � bA � bA 9 bA 9 bA 4
N N N O N N O N O N N N N N N
Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

Chart 2: Cobalt Concentration vs. Time in MW-2R & MW-5
275
250
225
200
100
75
50
25
0
V1 V1 l� lD I� n W W O1 Q1 O O e-1 � N N M M V � i!1 111 l0 l0 I� n W W O1 O1 O O N ti N N M M a s V1 V1 l0 l0 1� n W 00 Q1 O1 O O c-1
Ol Ol Q1 Ol Ol Ol Ql Ol Ol Ol O O O O O O O O O O O O O O O O O O O O ti ti ti ti '-I ti ti ti ti ti �--i ti ti ti ti ti � ti ti ti N N N
-a b0 -D W -a b0 -a by -a b0 -a by -D W -D by -D b0 9 by -D w Q b0 -a b0 9 M -D b0 -a by -a b0 -D bD -a b0 -D by -D w -a W -a b0 4 M -a b0 Q b0 -a
OJ 3 N 3 N O Ol O N 3 N 3 N O N 3 N 3 N 3 N O Ul 3 N O N 3 N O U/ 3 N O N 3 N O Ul 3 N O U/ 3 N O U1 3 N O Ul 3 N
LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

FIGURE
Figure 1 Site Location Map

L•\GranMle\Ewq\Butner\, Site location Mape.dwa

DRAWINGS
Drawing 1 Groundwater Potentiometric Surface Map

LaBeLLa
Powered by partnership.
J �� — ��\ \ - \ \ \ \ \ _ \_ \ —\
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
labellapc.com
MW
/ \ \ \\\ \\\\ \\_ \\\ \ \ \ \ \ \ ��
©2020 LaBella Associates
/352.3$i /
\
GRANVILLE COUNTY
I I 1
w \ I I I I I 1 \ I l o I I \ /
oo� \ \ 01 I I �I I I I ICn o /
OXFORD, NORTH CAROLINA
_ \ -QO\ \ / / / // M -3 Cl)/// / I I I I I � I � � I I LEGEND
IIII I I I I / I I I
I
G III I 4 130 — EXISTING 10' TOPOGRAPHIC CONTOUR
G \ I I I I I 11 I 15.p51
) ) III I I I I I I EXISTING 2' TOPOGRAPHIC CONTOUR
\
\ \ \
\
\ Z "` `Y- • ` APPROXIMAT
LIMITS OF WAS
APPROXIMATE LIMITS OF WASTE
Ir
\ 70
380 GROUNDWATER SURFACE CONTOUR
f ( ((FEET ABOVE MEAN SEA LEVEL)
GROUNDWATER FLOW DIRECTION WITH
p GRADIENT CALCULATION SEGMENT
=li\�\\\\\�_-_----_�-\ \\\ 11 \ \ II \ I 1 \\\ I
/
/ .�\ \\ \ I EXISTING ROAD
CENTERLINE OF STREAM
GROUNDWATER MONITORING WELL
4WJ3
0R 3-LOCATION AND IDENTIFICATIONs� ELEV
SEGMENT USED FOR GRADIENTMW-2R
O-
BUTNER LANDFI
LL/
CALCULATIONS
2796 OLD NC 75329.75
BUTNER,NORTH CARLINA
GAS PROBE LOCATION AND GP-1 IDENTIFICATION
-, ��
\ o -
-� \ \\ GI GAS VENT
gW_1 SURFACE WATER MONITORING POINT
(NM) NOT MEASURED
FLOW PATH LENGTH
NO:
DATE:
DESCRIPTION:
Revisions
2,133 LF
PROJECT NUMBER:
2182022
DRAWN BY:
REVIEWED BY:
-
MW 1
4`1�.43 \ \ I > \• r \ I I \ I I I I I 1 l , \\\\ \
l l I \ a I \ \ I \ \ \ \ \ \ I I I I \ \ \ \ \ \ \ \\\\ 0
W I \ \ \ \ \ I I \ \ y�\ \
6'I I I \ \ I I I \ \
\
c9 CA \_
c3► I I \\ ' \ \
� \ \ -
1\\\\ \\\\\IIII I \\ �\ III \\
MAV
ISSUED FOR:
GROUNDWATER REPORT
NOTES
DATE:
3/12/21
=
1. TOPOGRAPHIC CONTOUR INTERVAL 2 FEET
\ / 7-1I \\ _\
\ \ \ �\ _
— — / T GP-4 / / / J I I \ \\\ \ \ I I \ \ 2. GROUNDWATER SURFACE CONTOUR INTERVAL 10 FEET
DRAWING NAME:
T r — 7- I \ _ \ \ \ 1 \ \ 3. STATIC WATER LEVELS MEASURED ON 02/11/21.
GP-5\ \ \ R X \ \ \
POTENTIOMETRIC
_
Llt`� 4. GROUNDWATER CONTOURS BASED ON KNOWN DATA,
G-6 \F� T \ \ \\ \ \ \ \ \ TOPOGRAPHIC CONTOURS, LINEAR INTERPOLATION AND
EXTRAPOLATION FROM KNOWN FIELD CONDITIONS.
SURFACE MAP
5. ELEVATION RELATIVE TO MEAN SEA LEVEL.
FEBRUARY 11 2021
- \ 6. GROUNDWATER ELEVATION IS BASED ON A WELL SURVEY
PERFORMED IN APRIL 2008
7. TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
DRAWING NUMBER:
2007 DATA OBTAINED FROM NCDOT WEBSITE.
\ — \ GRAP I SSA
0 \ 1 0 20 \ \ 8. BOUNDARY SURVEY PROVIDED BY BATEMAN CIVIL SURVEY
— COMPANY DATED MARCH 15, 2013.
I �

APPENDICES
Appendix A
Appendix B
Appendix C
Appendix D
Appendix E
Appendix F
Appendix G
Monitoring Well Construction Data
Field Data Logs
Laboratory Analytical Reports and Chains of Custody
Historical Groundwater Elevations
Historical Constituents in Groundwater
Historical Constituents in Surface Water
Historical Monitoring Natural Attenuation Parameters

Appendix A
Monitoring Well Construction Data

Appendix A: Well Construction Details
Surface
TOC
Top of
Top of
Bottom of
Water
Depth to
Geologic
Construction
Driller's
Permit #
Well ID
Latitude
Longitude
Total Depth
Comments
Elevation
Elevation
Casing
Screen
Screen
Level*
Bedrock
Unit**
Date
Reg. #
Ft-AMSL
Ft-AMSL
Ft-AGS
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Fractured
background well
39-02
MW-1 R
N360 09' 55.49"
W780 45' 37.80"
461.01
461.01
0.00
41.00
56.00
56.00
41.00
30.00
4/21/1994
446
Bedrock
replacement
Weathered
compliance well
39-02
MW-2 R
N360 09' 38.57"
W780 45' 34.97"
326.60
328.94
2.34
3.85
18.85
18.85
2.60
13.00
4/12/1994
446
Bedrock
replacement
Fractured
compliance well
39-02
MW-3 R
N360 09' 38.58"
W780 45' 34.85"
328.77
330.95
2.18
25.83
35.83
35.83
3.00
13.00
4/14/1994
446
Bedrock
replacement
Fractured
39-02
MW-4
N360 09' 38.93"
W780 45' 30.15"
338.97
340.92
1.95
16.43
31.43
31.43
9.80
13.00
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-5
N360 09' 39.35"
W780 45' 23.77"
341.88
344.00
2.12
8.52
23.52
23.52
12.80
17.00
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-6
N360 09' 47.00"
W780 45' 25.47"
360.80
362.80
2.00
17.63
32.63
32.63
11.70
21.20
4/19/1994
446
compliance well
Bedrock
Fractured
nature & extent
3902
NES-1
N360 09' 35.65"
W780 45' 31.59"
326.22
328.72
2.50
15.00
30.00
30.00
22.00
26.00
11/14/2007
2675
Bedrock
study well
Notes:
TOC = Top of Casing.
Ft-AMSL = Feet above mean sea level.
Ft-AGS = Feet above ground surface.
Ft-BTOC = Feet below TOC.
*Water Level from TOC, approx. 24 hours after drilling.
**Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Typical Monitoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Monitoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007 and field observations.
Locations and elevations from March 2013 survey.
Butner Landfill, Granville County
Permit # 39-02
LaBella Associates

Appendix 8
Field Data Logs

LaBeRa 0- Project Name: nal -'j &AI) c
.-,, Location:
2211W. Meadowview Rd Suite 101 Project No.: o�030) 3
Greensboro, NC 27407 Sampled By: tj (�o K. ts4-e3
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: rn W -I- P-1 Weather: Ll()'S
�' - M, MEN U1991 is Own
Well Diameter: Static Water Level:
Depth of Well: 56.00 Length nl+'Well Sc
Measuring Point: -&-!2 -T.Z>C
-
Purge Time
Start: tdC
t' . -
Depth to Top of Pump:
Tubing Type:
rbidity
qTU)
Dissolved 02 Redox
(mg/L) (MV)
+10%
+/- 10 MV I
).q
00
I&ro-s
Final Static Water Level:
Notes:
Purge Time End: �� I
g1111a?- 0;;4

�] LaBeRa
Project Name: 6(aA wN e — I`<7 )+o e�
Location:
2211W. Meadowview Rd Suite 101
Project No.:
.501
�� /
0 3qq
Greensboro, NC 27407
Sampled By:
U617 h.{-
E3 �e5
Telephone: [phone]
.
Facsimile: [phone]
Date:
'�
2ja
WELL I.D.: VJ-2 P�
Weather:
yp�s
r4i%1
AM
NN
Well Diameter:
Static Water Level:
Depth of Well:
Length of Well Screen:
Measuring Point: -rp G
Depth to Top of Pump:
�----
Pump Type:
Tubing Type:
lolls
Purge Time Purge Time End: Final Static Water Level:
� �Start:�+ �I6 2 I �N
Notes: Fe J .
w k (Ae 10 G r-h- c-leS -�J oQ-hA j' i n GJQ.4rr

�-, LaBella
2211W. Meadowview Rd Suite 101
Greensboro, NC 27407
Telephone: [phone]
Facsimile: [phone] WELL I.D.: /,,/11w —
Project Name:
Location:
Project No.:
Sampled By:
6ecm'j I le - &A,
_
Date: �2-/]V
Weather: q v'S
Well Diameter:
Static Water Level. 1,
Depth of Well: 3�,�j Length of Well Screen:
Measuring Point: I-pC Depth to Top of Pump:
Pump Typc: U T
Ala PIICn50Ufl Tubing Type:
Gallons
Purged
Nam
a ons urge
Purge Time l� Purge Time End: Final Static Water Level:
t`art: 1
Notes: / ..�.._ ._ . ...,.,._ ..�,..� _. ....._ ...< _._,..�.......�.,�..�:..,u,.y_a�.:.. ��

0 LaBetta
DATE: a / I ) r�� I
GROUND WATER SAMPLING LOG
Project Name: (9(Qnvi11f' Project No. /Task No.: aQo3®13/O j
Well ID: -M W - LI Sampler(s): Lam. WNP—
Well Location:
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well
2 inches
q, 21 feet
31 •y3 feet
feet [DTB-DTW]
WCT X 0.163 = q• V gallons
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
gallons
" 102 gallons
gallons
Purged with: Bailer Pump Other:
Sampled with: Bai er Pump
nn Other:
b
Depth to Water before Sampling: , q feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/Cm )
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
�l
I CT`i
rs ,��
1036
l�'��
IB-, �
�.
—
�/0
a —
—
--
Date of sample:
22 U
Before Sampling
16 30
11,F
S-,g ('
Comments (weather conditions, odor, color, silt, etc.):
qo's rain
Signature: F" Date:
QA/QC Sign Off: Date: ��

DATE: 11��0�
C LaBella
GROUND WATER SAMPLING LOG
Project Name: G con vAe-� Project No. /Task No.:'Q'q -S,,ef
Well ID: MO S Sampler(s): K,EsAQ n-
Well Location:
Well Diameter: 2 inches
Initial Depth to Water (DTW): -T-71 feet
Depth to Bottom (DTB): -'? 3.5a feet
Water Column Thickness (WCT): - If feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well
WCT X 0.163 = 9.51 gallons
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witt
=
gallons
= 1-7
gallons
5.'1`I
gallons
Depth to Water before Sampling: OS feet
Gallons
Time
Temp
(°C)
pH
Cond.
(us/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
COgy6
I-°�
�.�S�I
i55• 6
y,S6
a3H.e
III
0�.5-7
Gq q 9,
rs,.
C�,Iq
ISo.9
3.ti8
�S6oF
���
ague
4g3.
s,Sq
196.`7
'>I6va
P
Date of sample:f�'
:11 ; 1
Before Sampling
7 ,
Comments (weather conditions, odor, color, silt, etc.):
4-/0 's rare,
Signature: 9 Date: 'g-`1(a0A
QA/QC Sign Off: Date:

DATE:
�- LaBett
GROUND WATER SAMPLING LOG
Project Name: Cn(acw (16 - ► `�lP� Project No. /Task No.: Z o C �o S
Well ID: 1 r I Sampler(s): YIS�Ifa,
Well Location:
Well Diameter:
Initial Depth to Water (DTW)
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
2 inches
�- feet
6� feet
�2_ feet [DTB-DTW]
L1- IF gallons
= gallons
gallons
3� gallons
Purged with: <Jailer Pump Other:
Sampled with: �e Pump Other:
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
ry,s
�.39
�(��7
S,'.o
18�0
0916
6923
.9a
a,og, 6
3s
[Date
of sample:
Before Sampling
ko 0
U , 3
r s
3a3&a
3,9 3
a7$:S:'-
Comments (weather conditions, odor, color, silt, etc.):
�
/I
Signature'• Date: a/ 09
QA/QC Sign Off: Date: AO

LaBella
Project Name:
Location:
2211W. Meadowview Rd Suite 101
Prc.jcct No.:
Greensboro, NC 27407
Sampled By:
Telephone: [phone]
Facsimile: [phone]
Date:
WELL I.D.: \ �
Weather:
a-030 6'3
KX-5
0"s 60 A
.
p
Well Diameter:
�\�
Static Water Level:
Depth of Well:
36, �b
Length of Well Screen:
•�
Measuring Point:
Tp C
Depth to Top of Pump:
Pump Type:
�M
(Y1eAgp(ISeZYI
Tubing Type:
e
MART ENT:
'bidity
Dissolved Oz
1 Redox
4TU)
On * L)
(mV)
+ 10%n
+/- 10 mV
O
H
' ° C,
6 `�
'off
o
I
L
•
L
p2
g,
Alkalinity I Iron
Purge Time 13� Purge Time )rnd:
Start: a 1;0-� Final Static Water Level:
y �aj �`°
'. •�`iis_ ` �Y�F '� •,1 �erf..d.5.°�w:sn�.v r ►i..
Notes:
Comments
y
� w
I
Q.D

DATE: �'?%/ I
P..., LaBetta
SURFACE WATER MONITORING LOG
Project Name: ` qqAg i I �e Q AAe57_ Project/Task No.: -2aa 3 01 S /a3
Surface Point ID: �� ' Sampler(s):_�'
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
16g02
-7, 36
L' 5-
(0C)
75,
(US/cm)
(ntu)
10,20
(mg/L)
1_7•7a
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
yo'S ra"
Summary/Sketch of Sampling Location
9
Signature:
QA/QC Sign Off: k4 -E rWW
Date:
Date:�7
rf 7$ w—cm4r1e,

P. LaBetta
DATE: "Y 1I120;'? (
SURFACE WATER MONITORING LOG
Project Name: G(Q(1VtM e a_j)Pf_ Project/Task No.: ar;LO'�013
Surface Point ID: < �'> � Sampler(s):
Location:
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
1,19
S,a-g
(0C)
(US/CM)
(ntu)
lD, ILA /
'J
(mg/L)
(mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
Litz 5 t`n
Signature:_', !"� 7i' Date: 'q/ 111I
QA/QC Sign Off: Date: (�2(.qA

Appendix C
Laboratory Analytical Reports and Chains of Custody

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 22, 2021
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 12, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/7j"4w'
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92522105001
3902-MW1R
Water
02/11/2113:07
02/12/21
10:47
92522105002
3902-MW2R
Water
02/11/2111:35
02/12/21
10:47
92522105003
3902-MW3R
Water
02/11/2110:41
02/12/21
10:47
92522105004
3902-MW4
Water
02/11/2116:30
02/12/21
10:47
92522105005
3902-MW5
Water
02/11/2116:14
02/12/21
10:47
92522105006
3902-MW6
Water
02/11/2116:00
02/12/21
10:47
92522105007
3902-NES1
Water
02/11/2114:56
02/12/21
10:47
92522105008
3902-FIELD BLANK
Water
02/11/21
17:17
02/12/21
10:47
92522105009
3902-SW2
Water
02/11/2115:18
02/12/21
10:47
92522105010
3902-TRIP BLANK
Water
02/11/21
07:00
02/12/21
10:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
BUTNER LANDFILL COMPLIANCE
92522105
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92522105001
3902-MW1R
EPA 601OD
KQ
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
BSH
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105002
3902-MW2R
EPA 601 OD
KQ
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
BSH
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105003
3902-MW3R
EPA 601 OD
KQ
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8260D
BSH
66
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105004
3902-MW4
EPA 601 OD
KQ
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105005
3902-MW5
EPA 601 OD
KQ
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105006
3902-MW6
EPA 601 OD
KQ
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105007
3902-NES1
EPA 601 OD
KQ
2
PASI-A
92522105008
3902-FIELD BLANK
EPA 601 OD
KQ
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105009
3902-SW2
EPA 601 OD
KQ
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
BSH
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92522105010
3902-TRIP BLANK
EPA 8260D
BSH
50
PASI-C
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
EPA 8260D Mod.
REPORT OF LABORATORY ANALYSIS
LMB
PASI-C
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leAnalyiical
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9800 Kincey Ave. Suite 100
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[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
BUTNER LANDFILL COMPLIANCE
92522105
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92522105001
3902-MW1 R
EPA 6010D
Arsenic
4.9J
ug/L
10.0
02/21/2116:07
EPA 6010D
Barium
5.3
ug/L
5.0
02/21/2116:07
EPA 6010D
Chromium
4.1J
ug/L
5.0
02/21/2116:07
EPA 6010D
Zinc
12.9
ug/L
10.0
02/21/2116:07
92522105002
3902-MW2R
EPA 6010D
Arsenic
10J
ug/L
10.0
02/21/2116:10
EPA 6010D
Barium
116
ug/L
5.0
02/21/2116:10
EPA 6010D
Cadmium
0.65J
ug/L
1.0
02/21/2116:10
EPA 6010D
Chromium
4.OJ
ug/L
5.0
02/21/2116:10
EPA 6010D
Cobalt
10.8
ug/L
5.0
02/21/2116:10
EPA 6010D
Nickel
91.8
ug/L
5.0
02/21/2116:10
EPA 6010D
Tin
30.1
ug/L
5.0
02/21/2116:10
EPA 8260D
Benzene
1.8
ug/L
1.0
02/16/21 06:58
EPA 8260D
Chlorobenzene
15.1
ug/L
1.0
02/16/21 06:58
EPA 8260D
Chloroethane
1.2
ug/L
1.0
02/16/21 06:58
EPA 8260D
1,2-Dichlorobenzene
1.1
ug/L
1.0
02/16/21 06:58
EPA 8260D
1,4-Dichlorobenzene
1.9
ug/L
1.0
02/16/21 06:58
EPA 8260D
Naphthalene
3.7
ug/L
1.0
02/16/21 06:58
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
118
ug/L
4.0
02/15/21 16:55
92522105003
3902-MW3R
EPA 6010D
Barium
74.4
ug/L
5.0
02/21/2116:14
EPA 6010D
Cadmium
0.69J
ug/L
1.0
02/21/2116:14
EPA 6010D
Copper
84.8
ug/L
5.0
02/21/2116:14
EPA 6010D
Nickel
21.4
ug/L
5.0
02/21/2116:14
EPA 6010D
Tin
8.0
ug/L
5.0
02/21/2116:14
EPA 8260D
Chlorobenzene
7.3
ug/L
1.0
02/16/21 07:16
EPA 8260D
Chloroethane
0.98J
ug/L
1.0
02/16/21 07:16 v1
EPA 8260D
1,2-Dichlorobenzene
0.83J
ug/L
1.0
02/16/21 07:16
EPA 8260D
1,4-Dichlorobenzene
0.76J
ug/L
1.0
02/16/21 07:16
EPA 8260D
Vinyl chloride
0.53J
ug/L
1.0
02/16/21 07:16
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
53.1
ug/L
2.0
02/15/21 16:35
92522105004
3902-MW4
EPA 6010D
Cadmium
1.1
ug/L
1.0
02/21/2116:17
EPA 6010D
Copper
9.6
ug/L
5.0
02/21/2116:17
EPA 6010D
Nickel
13.5
ug/L
5.0
02/21/2116:17
EPA 6010D
Vanadium
13.4
ug/L
5.0
02/21/2116:17
EPA 8260D
Chlorobenzene
2.2
ug/L
1.0
02/16/21 07:35
EPA 8260D
Chloroethane
1.3
ug/L
1.0
02/16/21 07:35 v1
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
40.6
ug/L
2.0
02/15/21 16:15
92522105005
3902-MW5
EPA 6010D
Barium
161
ug/L
5.0
02/21/2116:20
EPA 6010D
Cobalt
18.6
ug/L
5.0
02/21/2116:20
EPA 6010D
Nickel
3.9J
ug/L
5.0
02/21/2116:20
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
1.8J
ug/L
2.0
02/15/21 15:37
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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9800 Kincey Ave. Suite 100
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[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
BUTNER LANDFILL COMPLIANCE
92522105
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92522105007
3902-NES1
EPA 6010D
Cobalt
3.8J
ug/L
5.0
02/21/2116:27
EPA 6010D
Vanadium
7.2
ug/L
5.0
02/21/2116:27
92522105009
3902-SW2
EPA 6010D
Barium
31.2
ug/L
5.0
02/21/2116:33
EPA 6010D
Chromium
4.OJ
ug/L
5.0
02/21/2116:33
EPA 6010D
Nickel
4AJ
ug/L
5.0
02/21/2116:33
EPA 6010D
Hardness, Total(SM 2340B)
70000
ug/L
662
02/21/21 16:33
EPA8260D Mod.
1,4-Dioxane (p-Dioxane)
3.0
ug/L
2.0
02/15/21 15:56
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW1R Lab ID: 92522105001 Collected: 02/11/21 13:07 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:07
7440-36-0
Arsenic
4.9.1
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:07
7440-38-2
Barium
5.3
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:07
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:07
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:07
7440-43-9
Chromium
4.1J
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:07
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:07
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:07
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:07
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:07
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:07
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:07
7440-22-4
Tin
ND
ug/L
5.0
4.7
1
02/18/2109:52
02/21/2116:07
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:07
7440-62-2
Zinc
12.9
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:07
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2122:33
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/15/2116:29 02/16/2116:08 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
10.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
5.0
6.2
1
02/16/21 09:05
67-64-1
30.4
1
02/16/21 09:05
75-05-8
2.7
1
02/16/21 09:05
107-02-8
0.90
1
02/16/21 09:05
107-13-1
0.28
1
02/16/21 09:05
107-05-1
0.15
1
02/16/21 09:05
71-43-2
0.34
1
02/16/21 09:05
74-97-5
0.26
1
02/16/21 09:05
75-27-4
0.62
1
02/16/21 09:05
75-25-2
0.62
1
02/16/21 09:05
74-83-9
3.3
1
02/16/21 09:05
78-93-3
0.40
1
02/16/21 09:05
75-15-0
0.22
1
02/16/21 09:05
56-23-5
0.23
1
02/16/21 09:05
108-90-7
0.49
1
02/16/21 09:05
75-00-3
2.3
1
02/16/21 09:05
67-66-3
0.39
1
02/16/21 09:05
74-87-3
1.7
1
02/16/21 09:05
126-99-8
0.26
1
02/16/21 09:05
96-12-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 8 of 44

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW1R Lab ID: 92522105001 Collected: 02/11/21 13:07 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.41
1
02/16/2109:05
124-48-1
ND
ug/L
1.0
0.26
1
02/16/2109:05
106-93-4
ND
ug/L
1.0
0.46
1
02/16/2109:05
74-95-3
ND
ug/L
1.0
0.29
1
02/16/2109:05
95-50-1
ND
ug/L
1.0
0.22
1
02/16/2109:05
541-73-1
ND
ug/L
1.0
0.26
1
02/16/2109:05
106-46-7
ND
ug/L
1.0
0.54
1
02/16/2109:05
110-57-6
ND
ug/L
1.0
0.23
1
02/16/2109:05
75-71-8
ND
ug/L
1.0
0.27
1
02/16/2109:05
75-34-3
ND
ug/L
1.0
0.34
1
02/16/2109:05
107-06-2
ND
ug/L
1.0
0.24
1
02/16/2109:05
75-35-4
ND
ug/L
1.0
0.29
1
02/16/2109:05
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2109:05
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2109:05
78-87-5
ND
ug/L
1.0
0.16
1
02/16/2109:05
142-28-9
ND
ug/L
1.0
0.27
1
02/16/2109:05
594-20-7
ND
ug/L
1.0
0.21
1
02/16/2109:05
563-58-6
ND
ug/L
1.0
0.30
1
02/16/2109:05
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2109:05
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2109:05
100-41-4
ND
ug/L
1.0
0.51
1
02/16/2109:05
97-63-2
ND
ug/L
5.0
0.57
1
02/16/2109:05
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2109:05
74-88-4
ND
ug/L
100
66.4
1
02/16/2109:05
78-83-1
ND
ug/L
10.0
1.9
1
02/16/2109:05
126-98-7
ND
ug/L
5.0
3.7
1
02/16/2109:05
75-09-2
ND
ug/L
2.0
0.46
1
02/16/2109:05
80-62-6
ND
ug/L
5.0
4.5
1
02/16/2109:05
108-10-1
ND
ug/L
1.0
0.35
1
02/16/2109:05
91-20-3
ND
ug/L
20.0
1.8
1
02/16/2109:05
107-12-0
ND
ug/L
1.0
0.27
1
02/16/2109:05
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2109:05
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2109:05
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2109:05
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2109:05
108-88-3
ND
ug/L
1.0
0.22
1
02/16/2109:05
120-82-1
ND
ug/L
1.0
0.18
1
02/16/2109:05
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2109:05
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2109:05
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2109:05
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2109:05
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2109:05
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2109:05
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2109:05
1330-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 44

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW1R
Parameters
Lab ID: 92522105001 Collected:
Report
Results Units Limit
02/11/21 13:07
MDL DF
Received: 02/12/21 10:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Surrogates
4-Bromofluorobenzene (S)
102 % 70-130
1
02/16/21 09:05
460-00-4
1,2-Dichloroethane-d4 (S)
118 % 70-130
1
02/16/21 09:05
17060-07-0
Toluene-d8 (S)
100 % 70-130
1
02/16/21 09:05
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
02/15/21 14:58
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98 % 70-130
1
02/15/21 14:58
17060-07-0
Toluene-d8 (S)
100 % 66-133
1
02/15/21 14:58
2037-26-5
Date: 02/22/2021 04:16 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 10 of 44

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW2R Lab ID: 92522105002 Collected: 02/11/21 11:35 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:10
7440-36-0
Arsenic
10J
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:10
7440-38-2
Barium
116
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:10
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:10
7440-41-7
Cadmium
0.65J
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:10
7440-43-9
Chromium
4.0.1
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:10
7440-47-3
Cobalt
10.8
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:10
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:10
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:10
7439-92-1
Nickel
91.8
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:10
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:10
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:10
7440-22-4
Tin
30.1
ug/L
5.0
4.7
1
02/18/2109:52
02/21/2116:10
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:10
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:10
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2122:55
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/15/2116:29 02/16/2116:10 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
10.0
ND
ug/L
2.0
1.8
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
15.1
ug/L
1.0
1.2
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
5.0
6.2
1
02/16/21 06:58
67-64-1
30.4
1
02/16/21 06:58
75-05-8
2.7
1
02/16/21 06:58
107-02-8
0.90
1
02/16/21 06:58
107-13-1
0.28
1
02/16/21 06:58
107-05-1
0.15
1
02/16/21 06:58
71-43-2
0.34
1
02/16/21 06:58
74-97-5
0.26
1
02/16/21 06:58
75-27-4
0.62
1
02/16/21 06:58
75-25-2
0.62
1
02/16/21 06:58
74-83-9
3.3
1
02/16/21 06:58
78-93-3
0.40
1
02/16/21 06:58
75-15-0
0.22
1
02/16/21 06:58
56-23-5
0.23
1
02/16/21 06:58
108-90-7
0.49
1
02/16/21 06:58
75-00-3
2.3
1
02/16/21 06:58
67-66-3
0.39
1
02/16/21 06:58
74-87-3
1.7
1
02/16/21 06:58
126-99-8
0.26
1
02/16/21 06:58
96-12-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW2R Lab ID: 92522105002 Collected: 02/11/21 11:35 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.41
1
02/16/2106:58
124-48-1
ND
ug/L
1.0
0.26
1
02/16/2106:58
106-93-4
ND
ug/L
1.0
0.46
1
02/16/2106:58
74-95-3
1.1
ug/L
1.0
0.29
1
02/16/2106:58
95-50-1
ND
ug/L
1.0
0.22
1
02/16/2106:58
541-73-1
1.9
ug/L
1.0
0.26
1
02/16/2106:58
106-46-7
ND
ug/L
1.0
0.54
1
02/16/2106:58
110-57-6
ND
ug/L
1.0
0.23
1
02/16/2106:58
75-71-8
ND
ug/L
1.0
0.27
1
02/16/2106:58
75-34-3
ND
ug/L
1.0
0.34
1
02/16/2106:58
107-06-2
ND
ug/L
1.0
0.24
1
02/16/2106:58
75-35-4
ND
ug/L
1.0
0.29
1
02/16/2106:58
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2106:58
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2106:58
78-87-5
ND
ug/L
1.0
0.16
1
02/16/2106:58
142-28-9
ND
ug/L
1.0
0.27
1
02/16/2106:58
594-20-7
ND
ug/L
1.0
0.21
1
02/16/2106:58
563-58-6
ND
ug/L
1.0
0.30
1
02/16/2106:58
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2106:58
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2106:58
100-41-4
ND
ug/L
1.0
0.51
1
02/16/2106:58
97-63-2
ND
ug/L
5.0
0.57
1
02/16/2106:58
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2106:58
74-88-4
ND
ug/L
100
66.4
1
02/16/2106:58
78-83-1
ND
ug/L
10.0
1.9
1
02/16/2106:58
126-98-7
ND
ug/L
5.0
3.7
1
02/16/2106:58
75-09-2
ND
ug/L
2.0
0.46
1
02/16/2106:58
80-62-6
ND
ug/L
5.0
4.5
1
02/16/2106:58
108-10-1
3.7
ug/L
1.0
0.35
1
02/16/2106:58
91-20-3
ND
ug/L
20.0
1.8
1
02/16/2106:58
107-12-0
ND
ug/L
1.0
0.27
1
02/16/2106:58
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2106:58
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2106:58
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2106:58
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2106:58
108-88-3
ND
ug/L
1.0
0.22
1
02/16/2106:58
120-82-1
ND
ug/L
1.0
0.18
1
02/16/2106:58
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2106:58
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2106:58
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2106:58
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2106:58
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2106:58
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2106:58
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2106:58
1330-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW2R
Parameters
Lab ID: 92522105002 Collected:
Report
Results Units Limit
02/11/21 11:35
MDL DF
Received: 02/12/21 10:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Surrogates
4-Bromofluorobenzene (S)
103 % 70-130
1
02/16/21 06:58
460-00-4
1,2-Dichloroethane-d4 (S)
116 % 70-130
1
02/16/21 06:58
17060-07-0
Toluene-d8 (S)
99 % 70-130
1
02/16/21 06:58
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
118 ug/L 4.0
2.3 2
02/15/21 16:55
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98 % 70-130
2
02/15/21 16:55
17060-07-0
Toluene-d8 (S)
98 % 66-133
2
02/15/21 16:55
2037-26-5
Date: 02/22/2021 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW3R Lab ID: 92522105003 Collected: 02/11/21 10:41 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:14
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:14
7440-38-2
Barium
74.4
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:14
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:14
7440-41-7
Cadmium
0.69.1
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:14
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:14
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:14
7440-48-4
Copper
84.8
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:14
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:14
7439-92-1
Nickel
21.4
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:14
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:14
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:14
7440-22-4
Tin
8.0
ug/L
5.0
4.7
1
02/18/2109:52
02/21/2116:14
7440-31-5
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:14
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:14
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation
Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2123:12
7440-28-0
7470 Mercury
Mercury
8260D MSV Low Level Landfill
Acetone
Acetonitrile
Acrolein
Acrylonitrile
Allyl chloride
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Chloroprene
1,2-Dibromo-3-chloropropane
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Pace Analytical Services -Asheville
ND ug/L 0.20 0.12 1 02/15/2116:29 02/16/2116:17 7439-97-6
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
ND
ug/L
50.0
ND
ug/L
10.0
ND
ug/L
10.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
2.0
ND
ug/L
1.0
7.3
ug/L
1.0
0.98J
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
5.0
6.2
1
02/16/21 07:16
67-64-1
30.4
1
02/16/21 07:16
75-05-8
2.7
1
02/16/21 07:16
107-02-8
0.90
1
02/16/21 07:16
107-13-1
0.28
1
02/16/21 07:16
107-05-1
0.15
1
02/16/21 07:16
71-43-2
0.34
1
02/16/21 07:16
74-97-5
0.26
1
02/16/21 07:16
75-27-4
0.62
1
02/16/21 07:16
75-25-2
0.62
1
02/16/21 07:16
74-83-9
3.3
1
02/16/21 07:16
78-93-3
0.40
1
02/16/21 07:16
75-15-0
0.22
1
02/16/21 07:16
56-23-5
0.23
1
02/16/21 07:16
108-90-7
0.49
1
02/16/21 07:16
75-00-3
2.3
1
02/16/21 07:16
67-66-3
0.39
1
02/16/21 07:16
74-87-3
1.7
1
02/16/21 07:16
126-99-8
0.26
1
02/16/21 07:16
96-12-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 14 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW3R Lab ID: 92522105003 Collected: 02/11/21 10:41 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
Ethyl methacrylate
2-Hexanone
lodomethane
Isobutanol
Methacrylonitrile
Methylene Chloride
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
1.0
0.41
1
02/16/2107:16
124-48-1
ND
ug/L
1.0
0.26
1
02/16/2107:16
106-93-4
ND
ug/L
1.0
0.46
1
02/16/2107:16
74-95-3
0.83J
ug/L
1.0
0.29
1
02/16/2107:16
95-50-1
ND
ug/L
1.0
0.22
1
02/16/2107:16
541-73-1
0.76J
ug/L
1.0
0.26
1
02/16/2107:16
106-46-7
ND
ug/L
1.0
0.54
1
02/16/2107:16
110-57-6
ND
ug/L
1.0
0.23
1
02/16/2107:16
75-71-8
ND
ug/L
1.0
0.27
1
02/16/2107:16
75-34-3
ND
ug/L
1.0
0.34
1
02/16/2107:16
107-06-2
ND
ug/L
1.0
0.24
1
02/16/2107:16
75-35-4
ND
ug/L
1.0
0.29
1
02/16/2107:16
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2107:16
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2107:16
78-87-5
ND
ug/L
1.0
0.16
1
02/16/2107:16
142-28-9
ND
ug/L
1.0
0.27
1
02/16/2107:16
594-20-7
ND
ug/L
1.0
0.21
1
02/16/2107:16
563-58-6
ND
ug/L
1.0
0.30
1
02/16/2107:16
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2107:16
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2107:16
100-41-4
ND
ug/L
1.0
0.51
1
02/16/2107:16
97-63-2
ND
ug/L
5.0
0.57
1
02/16/2107:16
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2107:16
74-88-4
ND
ug/L
100
66.4
1
02/16/2107:16
78-83-1
ND
ug/L
10.0
1.9
1
02/16/2107:16
126-98-7
ND
ug/L
5.0
3.7
1
02/16/2107:16
75-09-2
ND
ug/L
2.0
0.46
1
02/16/2107:16
80-62-6
ND
ug/L
5.0
4.5
1
02/16/2107:16
108-10-1
ND
ug/L
1.0
0.35
1
02/16/2107:16
91-20-3
ND
ug/L
20.0
1.8
1
02/16/2107:16
107-12-0
ND
ug/L
1.0
0.27
1
02/16/2107:16
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2107:16
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2107:16
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2107:16
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2107:16
108-88-3
ND
ug/L
1.0
0.22
1
02/16/2107:16
120-82-1
ND
ug/L
1.0
0.18
1
02/16/2107:16
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2107:16
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2107:16
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2107:16
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2107:16
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2107:16
108-05-4
0.53J
ug/L
1.0
0.24
1
02/16/2107:16
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2107:16
1330-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW3R
Parameters
Lab ID: 92522105003 Collected:
Report
Results Units Limit
02/11/21 10:41
MDL DF
Received: 02/12/21 10:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Surrogates
4-Bromofluorobenzene (S)
102 % 70-130
1
02/16/21 07:16
460-00-4
1,2-Dichloroethane-d4 (S)
116 % 70-130
1
02/16/21 07:16
17060-07-0
Toluene-d8 (S)
99 % 70-130
1
02/16/21 07:16
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
53.1 ug/L 2.0
1.2 1
02/15/21 16:35
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
101 % 70-130
1
02/15/21 16:35
17060-07-0
Toluene-d8 (S)
100 % 66-133
1
02/15/21 16:35
2037-26-5
Date: 02/22/2021 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW4 Lab ID: 92522105004 Collected: 02/11/21 16:30 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:17
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:17
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:17
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:17
7440-41-7
Cadmium
1.1
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:17
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:17
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:17
7440-48-4
Copper
9.6
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:17
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:17
7439-92-1
Nickel
13.5
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:17
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:17
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:17
7440-22-4
Vanadium
13.4
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:17
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:17
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2123:17
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/16/21 07:35
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/16/21 07:35
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/16/21 07:35
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/16/21 07:35
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/16/21 07:35
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/16/21 07:35
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/16/21 07:35
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/16/21 07:35
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/16/21 07:35
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/16/21 07:35
56-23-5
Chlorobenzene
2.2
ug/L
1.0
0.23
1
02/16/21 07:35
108-90-7
Chloroethane
1.3
ug/L
1.0
0.49
1
02/16/21 07:35
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/16/21 07:35
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/16/21 07:35
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/16/21 07:35
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/16/21 07:35
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/16/21 07:35
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/16/21 07:35
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/16/21 07:35
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/16/21 07:35
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/16/21 07:35
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/16/21 07:35
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/16/21 07:35
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/16/21 07:35
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
v1
Page 17 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW4 Lab ID: 92522105004 Collected: 02/11/21 16:30 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/16/2107:35
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2107:35
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2107:35
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2107:35
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2107:35
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2107:35
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2107:35
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2107:35
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2107:35
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2107:35
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2107:35
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2107:35
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2107:35
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2107:35
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2107:35
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2107:35
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2107:35
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2107:35
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2107:35
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2107:35
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2107:35
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2107:35
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2107:35
1330-20-7
101
%
70-130
1
02/16/2107:35
460-00-4
115
%
70-130
1
02/16/2107:35
17060-07-0
99
%
70-130
1
02/16/2107:35
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
40.6
ug/L
2.0
1.2
1
02/15/2116:15
123-91-1
100
%
70-130
1
02/15/2116:15
17060-07-0
100
%
66-133
1
02/15/21 16:15
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW5 Lab ID: 92522105005 Collected: 02/11/21 16:14 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:20
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:20
7440-38-2
Barium
161
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:20
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:20
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:20
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:20
7440-47-3
Cobalt
18.6
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:20
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:20
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:20
7439-92-1
Nickel
3.9.1
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:20
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:20
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:20
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:20
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:20
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2123:21
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/16/21 07:53
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/16/21 07:53
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/16/21 07:53
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/16/21 07:53
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/16/21 07:53
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/16/21 07:53
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/16/21 07:53
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/16/21 07:53
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/16/21 07:53
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/16/21 07:53
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/16/21 07:53
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/16/21 07:53
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/16/21 07:53
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/16/21 07:53
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/16/21 07:53
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/16/21 07:53
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/16/21 07:53
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/16/21 07:53
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/16/21 07:53
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/16/21 07:53
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/16/21 07:53
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/16/21 07:53
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/16/21 07:53
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/16/21 07:53
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
v1
Page 19 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW5 Lab ID: 92522105005 Collected: 02/11/21 16:14 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/16/2107:53
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2107:53
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2107:53
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2107:53
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2107:53
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2107:53
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2107:53
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2107:53
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2107:53
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2107:53
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2107:53
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2107:53
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2107:53
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2107:53
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2107:53
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2107:53
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2107:53
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2107:53
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2107:53
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2107:53
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2107:53
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2107:53
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2107:53
1330-20-7
102
%
70-130
1
02/16/2107:53
460-00-4
116
%
70-130
1
02/16/2107:53
17060-07-0
100
%
70-130
1
02/16/2107:53
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
1.8J
ug/L
2.0
1.2
1
02/15/2115:37
123-91-1
97
%
70-130
1
02/15/2115:37
17060-07-0
100
%
66-133
1
02/15/21 15:37
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW6 Lab ID: 92522105006 Collected: 02/11/21 16:00 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:23
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:23
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:23
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:23
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:23
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:23
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:23
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:23
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:23
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:23
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:23
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:23
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:23
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:23
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2123:25
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/16/21 08:11
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/16/21 08:11
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/16/21 08:11
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/16/21 08:11
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/16/21 08:11
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/16/21 08:11
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/16/21 08:11
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/16/21 08:11
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/16/21 08:11
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/16/21 08:11
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/16/21 08:11
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/16/21 08:11
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/16/21 08:11
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/16/21 08:11
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/16/21 08:11
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/16/21 08:11
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/16/21 08:11
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/16/21 08:11
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/16/21 08:11
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/16/21 08:11
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/16/21 08:11
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/16/21 08:11
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/16/21 08:11
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/16/21 08:11
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
v1
Page 21 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-MW6 Lab ID: 92522105006 Collected: 02/11/21 16:00 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/16/2108:11
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2108:11
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2108:11
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2108:11
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2108:11
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2108:11
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2108:11
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2108:11
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2108:11
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2108:11
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2108:11
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2108:11
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2108:11
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2108:11
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2108:11
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2108:11
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2108:11
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2108:11
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2108:11
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2108:11
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2108:11
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2108:11
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2108:11
1330-20-7
102
%
70-130
1
02/16/2108:11
460-00-4
116
%
70-130
1
02/16/2108:11
17060-07-0
100
%
70-130
1
02/16/2108:11
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
02/15/2115:17
123-91-1
98
%
70-130
1
02/15/2115:17
17060-07-0
101
%
66-133
1
02/15/21 15:17
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-NES1
Lab ID: 92522105007 Collected:
02/11/21 14:56
Received: 02/12/21 10:47 Matrix: Water
Report
Parameters
Results Units Limit
MDL DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Cobalt
3.8J ug/L 5.0
3.6 1
02/18/2109:52 02/21/2116:27 7440-48-4
Vanadium
7.2 ug/L 5.0
3.9 1
02/18/2109:52 02/21/2116:27 7440-62-2
Date: 02/22/2021 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-FIELD BLANK Lab ID: 92522105008 Collected: 02/11/21 17:17 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:30
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:30
7440-38-2
Barium
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:30
7440-39-3
Beryllium
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:30
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:30
7440-43-9
Chromium
ND
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:30
7440-47-3
Cobalt
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:30
7440-48-4
Copper
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:30
7440-50-8
Lead
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:30
7439-92-1
Nickel
ND
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:30
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:30
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:30
7440-22-4
Vanadium
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:30
7440-62-2
Zinc
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:30
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA
3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1
02/19/2102:25
02/21/2123:30
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/16/21 08:29
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/16/21 08:29
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/16/21 08:29
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/16/21 08:29
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/16/21 08:29
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/16/21 08:29
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/16/21 08:29
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/16/21 08:29
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/16/21 08:29
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/16/21 08:29
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/16/21 08:29
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/16/21 08:29
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/16/21 08:29
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/16/21 08:29
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/16/21 08:29
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/16/21 08:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/16/21 08:29
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/16/21 08:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/16/21 08:29
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/16/21 08:29
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/16/21 08:29
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/16/21 08:29
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/16/21 08:29
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/16/21 08:29
75-35-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
v1
Page 24 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-FIELD BLANK Lab ID: 92522105008 Collected: 02/11/21 17:17 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.29
1
02/16/2108:29
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2108:29
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2108:29
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2108:29
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2108:29
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2108:29
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2108:29
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2108:29
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2108:29
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2108:29
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2108:29
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2108:29
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2108:29
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2108:29
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2108:29
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2108:29
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2108:29
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2108:29
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2108:29
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2108:29
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2108:29
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2108:29
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2108:29
1330-20-7
102
%
70-130
1
02/16/2108:29
460-00-4
118
%
70-130
1
02/16/2108:29
17060-07-0
99
%
70-130
1
02/16/2108:29
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
ND
ug/L
2.0
1.2
1
02/15/2114:39
123-91-1
96
%
70-130
1
02/15/2114:39
17060-07-0
102
%
66-133
1
02/15/21 14:39
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-SW2 Lab ID: 92522105009 Collected: 02/11/21 15:18 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Pace Analytical Services -Asheville
ND
ug/L
5.0
3.0
1
02/18/2109:52
02/21/2116:33
7440-36-0
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:33
7440-38-2
31.2
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:33
7440-39-3
ND
ug/L
1.0
0.70
1
02/18/2109:52
02/21/2116:33
7440-41-7
ND
ug/L
1.0
0.40
1
02/18/2109:52
02/21/2116:33
7440-43-9
4.0.1
ug/L
5.0
3.7
1
02/18/2109:52
02/21/2116:33
7440-47-3
ND
ug/L
5.0
3.6
1
02/18/2109:52
02/21/2116:33
7440-48-4
ND
ug/L
5.0
4.3
1
02/18/2109:52
02/21/2116:33
7440-50-8
ND
ug/L
5.0
4.5
1
02/18/2109:52
02/21/2116:33
7439-92-1
4.4J
ug/L
5.0
3.5
1
02/18/2109:52
02/21/2116:33
7440-02-0
ND
ug/L
10.0
4.7
1
02/18/2109:52
02/21/2116:33
7782-49-2
ND
ug/L
5.0
2.5
1
02/18/2109:52
02/21/2116:33
7440-22-4
70000
ug/L
662
131
1
02/18/21 09:52
02/21/21 16:33
ND
ug/L
5.0
3.9
1
02/18/2109:52
02/21/2116:33
7440-62-2
ND
ug/L
10.0
9.5
1
02/18/2109:52
02/21/2116:33
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Pace Analytical Services
-Asheville
Thallium
ND
ug/L
0.10
0.050
1 02/19/2102:25
02/21/2123:34
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND
ug/L
25.0
6.2
1
02/16/21 08:47
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/16/21 08:47
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/16/21 08:47
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/16/21 08:47
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/16/21 08:47
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/16/21 08:47
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/16/21 08:47
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/16/21 08:47
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/16/21 08:47
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/16/21 08:47
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/16/21 08:47
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/16/21 08:47
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/16/21 08:47
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/16/21 08:47
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
02/16/21 08:47
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/16/21 08:47
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/16/21 08:47
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/16/21 08:47
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/16/21 08:47
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/16/21 08:47
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/16/21 08:47
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/16/21 08:47
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/16/21 08:47
107-06-2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
v1
Page 26 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-SW2 Lab ID: 92522105009 Collected: 02/11/21 15:18 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services
- Charlotte
ND
ug/L
1.0
0.24
1
02/16/2108:47
75-35-4
ND
ug/L
1.0
0.29
1
02/16/2108:47
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2108:47
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2108:47
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2108:47
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2108:47
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2108:47
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2108:47
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2108:47
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2108:47
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2108:47
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2108:47
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2108:47
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2108:47
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2108:47
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2108:47
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2108:47
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2108:47
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2108:47
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2108:47
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2108:47
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2108:47
108-05-4
ND
ug/L
1.0
0.24
1
02/16/2108:47
75-01-4
ND
ug/L
1.0
0.63
1
02/16/2108:47
1330-20-7
102
%
70-130
1
02/16/2108:47
460-00-4
118
%
70-130
1
02/16/2108:47
17060-07-0
101
%
70-130
1
02/16/2108:47
2037-26-5
Analytical Method: EPA 8260D Mod.
Pace Analytical Services
- Charlotte
3.0
ug/L
2.0
1.2
1
02/15/2115:56
123-91-1
99
%
70-130
1
02/15/2115:56
17060-07-0
99
%
66-133
1
02/15/21 15:56
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 27 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-TRIP BLANK Lab ID: 92522105010 Collected: 02/11/21 07:00 Received: 02/12/21 10:47 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropene
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Date: 02/22/2021 04:16 PM
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
ND
ug/L
25.0
6.2
1
02/16/2100:19
67-64-1
ND
ug/L
10.0
0.90
1
02/16/2100:19
107-13-1
ND
ug/L
1.0
0.15
1
02/16/2100:19
71-43-2
ND
ug/L
1.0
0.34
1
02/16/2100:19
74-97-5
ND
ug/L
1.0
0.26
1
02/16/2100:19
75-27-4
ND
ug/L
1.0
0.62
1
02/16/2100:19
75-25-2
ND
ug/L
2.0
0.62
1
02/16/2100:19
74-83-9
ND
ug/L
5.0
3.3
1
02/16/2100:19
78-93-3
ND
ug/L
2.0
0.40
1
02/16/2100:19
75-15-0
ND
ug/L
1.0
0.22
1
02/16/2100:19
56-23-5
ND
ug/L
1.0
0.23
1
02/16/2100:19
108-90-7
ND
ug/L
1.0
0.49
1
02/16/2100:19
75-00-3
ND
ug/L
5.0
2.3
1
02/16/2100:19
67-66-3
ND
ug/L
1.0
0.39
1
02/16/2100:19
74-87-3
ND
ug/L
5.0
0.26
1
02/16/2100:19
96-12-8
ND
ug/L
1.0
0.41
1
02/16/2100:19
124-48-1
ND
ug/L
1.0
0.26
1
02/16/2100:19
106-93-4
ND
ug/L
1.0
0.46
1
02/16/2100:19
74-95-3
ND
ug/L
1.0
0.29
1
02/16/2100:19
95-50-1
ND
ug/L
1.0
0.26
1
02/16/2100:19
106-46-7
ND
ug/L
1.0
0.54
1
02/16/2100:19
110-57-6
ND
ug/L
1.0
0.27
1
02/16/2100:19
75-34-3
ND
ug/L
1.0
0.34
1
02/16/2100:19
107-06-2
ND
ug/L
1.0
0.24
1
02/16/2100:19
75-35-4
ND
ug/L
1.0
0.29
1
02/16/2100:19
156-59-2
ND
ug/L
1.0
0.25
1
02/16/2100:19
156-60-5
ND
ug/L
1.0
0.19
1
02/16/2100:19
78-87-5
ND
ug/L
1.0
0.30
1
02/16/2100:19
10061-01-5
ND
ug/L
1.0
0.31
1
02/16/2100:19
10061-02-6
ND
ug/L
1.0
0.26
1
02/16/2100:19
100-41-4
ND
ug/L
5.0
0.57
1
02/16/2100:19
591-78-6
ND
ug/L
20.0
12.5
1
02/16/2100:19
74-88-4
ND
ug/L
5.0
3.7
1
02/16/2100:19
75-09-2
ND
ug/L
5.0
4.5
1
02/16/2100:19
108-10-1
ND
ug/L
1.0
0.27
1
02/16/2100:19
100-42-5
ND
ug/L
1.0
0.34
1
02/16/2100:19
630-20-6
ND
ug/L
1.0
0.22
1
02/16/2100:19
79-34-5
ND
ug/L
1.0
0.16
1
02/16/2100:19
127-18-4
ND
ug/L
1.0
0.24
1
02/16/2100:19
108-88-3
ND
ug/L
1.0
0.18
1
02/16/2100:19
71-55-6
ND
ug/L
1.0
0.24
1
02/16/2100:19
79-00-5
ND
ug/L
1.0
0.22
1
02/16/2100:19
79-01-6
ND
ug/L
1.0
0.31
1
02/16/2100:19
75-69-4
ND
ug/L
1.0
0.35
1
02/16/2100:19
96-18-4
ND
ug/L
2.0
1.4
1
02/16/2100:19
108-05-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 28 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Sample: 3902-TRIP BLANK
Parameters
Lab ID: 92522105010 Collected:
Report
Results Units Limit
02/11/21 07:00
MDL DF
Received: 02/12/21 10:47 Matrix: Water
Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Vinyl chloride
ND ug/L 1.0
0.24 1
02/16/21 00:19
75-01-4
Xylene (Total)
ND ug/L 1.0
0.63 1
02/16/21 00:19
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
100 % 70-130
1
02/16/21 00:19
460-00-4
1,2-Dichloroethane-d4 (S)
111 % 70-130
1
02/16/21 00:19
17060-07-0
Toluene-d8 (S)
98 % 70-130
1
02/16/21 00:19
2037-26-5
8260D MSV SIM
Analytical Method: EPA 8260D Mod.
Pace Analytical Services - Charlotte
1,4-Dioxane (p-Dioxane)
ND ug/L 2.0
1.2 1
02/15/21 14:19
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96 % 70-130
1
02/15/21 14:19
17060-07-0
Toluene-d8 (S)
102 % 66-133
1
02/15/21 14:19
2037-26-5
Date: 02/22/2021 04:16 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 29 of 44

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
QC Batch: 600090 Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522105001, 92522105002, 92522105003
METHOD BLANK: 3163756 Matrix: Water
Associated Lab Samples: 92522105001, 92522105002, 92522105003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Mercury ug/L ND 0.20 0.12 02/16/2115:39
LABORATORY CONTROL SAMPLE: 3163757
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.3 92 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3163758 3163759
MS MSD
92521830001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND 2.5 2.5 2.3 2.2 91 89 75-125 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 30 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
QC Batch: 600757 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105007,
92522105008,92522105009
METHOD BLANK: 3166451 Matrix: Water
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105007,
92522105008,92522105009
Parameter
Units
Antimony
ug/L
Arsenic
ug/L
Barium
ug/L
Beryllium
ug/L
Cadmium
ug/L
Chromium
ug/L
Cobalt
ug/L
Copper
ug/L
Hardness, Total(SM 2340B)
ug/L
Lead
ug/L
Nickel
ug/L
Selenium
ug/L
Silver
ug/L
Tin
ug/L
Vanadium
ug/L
Zinc
ug/L
LABORATORY CONTROL SAMPLE: 3166452
Parameter
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
Blank
Result
Reporting
Limit
MDL
Analyzed Qualifiers
ND
5.0
3.0
02/22/21 12:21
ND
10.0
4.7
02/22/21 12:21
ND
5.0
3.5
02/22/21 12:21
ND
1.0
0.70
02/22/21 12:21
ND
1.0
0.40
02/22/21 12:21
ND
5.0
3.7
02/22/21 12:21
ND
5.0
3.6
02/22/21 12:21
ND
5.0
4.3
02/22/21 12:21
ND
662
131
02/22/21 12:21
ND
5.0
4.5
02/22/21 12:21
ND
5.0
3.5
02/22/21 12:21
ND
10.0
4.7
02/22/21 12:21
ND
5.0
2.5
02/22/21 12:21
ND
5.0
4.7
02/22/21 12:21
ND
5.0
3.9
02/22/21 12:21
ND
10.0
9.5
02/22/21 12:21
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
ug/L
500
471
94
80-120
ug/L
500
462
92
80-120
ug/L
500
476
95
80-120
ug/L
500
475
95
80-120
ug/L
500
472
94
80-120
ug/L
500
484
97
80-120
ug/L
500
476
95
80-120
ug/L
500
498
100
80-120
ug/L
33100
31800
96
80-120
ug/L
500
469
94
80-120
ug/L
500
476
95
80-120
ug/L
500
466
93
80-120
ug/L
250
237
95
80-120
ug/L
500
465
93
80-120
ug/L
500
488
98
80-120
ug/L
500
459
92
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 31 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
MATRIX SPIKE & MATRIX SPIKE
Parameter
DUPLICATE: 3166453
MS
92521850001 Spike
Units Result Conc.
MSD
Spike
Conc.
3166454
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Antimony
ug/L
ND
500
500
494
506
99
101
75-125
2
20
Arsenic
ug/L
ND
500
500
493
498
98
99
75-125
1
20
Barium
ug/L
4.1J
500
500
484
497
96
99
75-125
3
20
Beryllium
ug/L
ND
500
500
486
498
97
100
75-125
3
20
Cadmium
ug/L
ND
500
500
494
505
99
101
75-125
2
20
Chromium
ug/L
ND
500
500
487
502
97
100
75-125
3
20
Cobalt
ug/L
ND
500
500
480
492
96
98
75-125
2
20
Copper
ug/L
4AJ
500
500
501
518
99
103
75-125
3
20
Hardness, Total(SM 2340B)
ug/L
179000
33100
33100
202000
207000
70
87
75-125
3
Lead
ug/L
ND
500
500
481
491
96
98
75-125
2
20
Nickel
ug/L
ND
500
500
482
492
96
98
75-125
2
20
Selenium
ug/L
ND
500
500
515
529
103
106
75-125
3
20
Silver
ug/L
ND
250
250
244
250
98
100
75-125
3
20
Tin
ug/L
ND
500
500
486
499
97
100
75-125
3
20
Vanadium
ug/L
ND
500
500
494
513
98
102
75-125
4
20
Zinc
ug/L
ND
500
500
476
487
95
97
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 32 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
QC Batch: 601155 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009
METHOD BLANK: 3168326 Matrix: Water
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.050 02/21/2121:33
LABORATORY CONTROL SAMPLE: 3168327
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10.1 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3168328 3168329
MS MSD
92522105001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.1 10.3 101 103 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 33 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
QC Batch: 600063 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009,92522105010
METHOD BLANK: 3163524 Matrix: Water
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009,92522105010
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
02/16/21 00:01
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
02/16/21 00:01
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
02/16/21 00:01
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
02/16/21 00:01
1,1-Dichloroethane
ug/L
ND
1.0
0.27
02/16/21 00:01
1,1-Dichloroethene
ug/L
ND
1.0
0.24
02/16/21 00:01
1,1-Dichloropropene
ug/L
ND
1.0
0.21
02/16/21 00:01
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
02/16/21 00:01
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.22
02/16/21 00:01
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
02/16/21 00:01
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
02/16/21 00:01
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
02/16/21 00:01
1,2-Dichloroethane
ug/L
ND
1.0
0.34
02/16/21 00:01
1,2-Dichloropropane
ug/L
ND
1.0
0.19
02/16/21 00:01
1,3-Dichlorobenzene
ug/L
ND
1.0
0.22
02/16/21 00:01
1,3-Dichloropropane
ug/L
ND
1.0
0.16
02/16/21 00:01
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
02/16/21 00:01
2,2-Dichloropropane
ug/L
ND
1.0
0.27
02/16/21 00:01
2-Butanone (MEK)
ug/L
ND
5.0
3.3
02/16/21 00:01
2-Hexanone
ug/L
ND
5.0
0.57
02/16/21 00:01
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
02/16/21 00:01
Acetone
ug/L
ND
25.0
6.2
02/16/21 00:01
Acetonitrile
ug/L
ND
50.0
30.4
02/16/21 00:01
Acrolein
ug/L
ND
10.0
2.7
02/16/21 00:01 IH,IK
Acrylonitrile
ug/L
ND
10.0
0.90
02/16/21 00:01
AIIyl chloride
ug/L
ND
2.0
0.28
02/16/21 00:01
Benzene
ug/L
ND
1.0
0.15
02/16/21 00:01
Bromochloromethane
ug/L
ND
1.0
0.34
02/16/21 00:01
Bromodichloromethane
ug/L
ND
1.0
0.26
02/16/21 00:01
Bromoform
ug/L
ND
1.0
0.62
02/16/21 00:01
Bromomethane
ug/L
ND
2.0
0.62
02/16/21 00:01
Carbon disulfide
ug/L
ND
2.0
0.40
02/16/21 00:01
Carbon tetrachloride
ug/L
ND
1.0
0.22
02/16/21 00:01
Chlorobenzene
ug/L
ND
1.0
0.23
02/16/21 00:01
Chloroethane
ug/L
ND
1.0
0.49
02/16/21 00:01
Chloroform
ug/L
ND
5.0
2.3
02/16/21 00:01
Chloromethane
ug/L
ND
1.0
0.39
02/16/21 00:01 v1
Chloroprene
ug/L
ND
5.0
1.7
02/16/21 00:01
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
02/16/21 00:01
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
METHOD BLANK: 3163524 Matrix: Water
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009,92522105010
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
02/16/21 00:01
Dibromochloromethane
ug/L
ND
1.0
0.41
02/16/21 00:01
Dibromomethane
ug/L
ND
1.0
0.46
02/16/21 00:01
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
02/16/21 00:01
Ethyl methacrylate
ug/L
ND
1.0
0.51
02/16/21 00:01
Ethylbenzene
ug/L
ND
1.0
0.26
02/16/21 00:01
lodomethane
ug/L
ND
20.0
12.5
02/16/21 00:01
Isobutanol
ug/L
ND
100
66.4
02/16/21 00:01
Methacrylonitrile
ug/L
ND
10.0
1.9
02/16/21 00:01
Methyl methacrylate
ug/L
ND
2.0
0.46
02/16/21 00:01
Methylene Chloride
ug/L
ND
5.0
3.7
02/16/21 00:01
Naphthalene
ug/L
ND
1.0
0.35
02/16/21 00:01
Propionitrile
ug/L
ND
20.0
1.8
02/16/21 00:01
Styrene
ug/L
ND
1.0
0.27
02/16/21 00:01
Tetrachloroethene
ug/L
ND
1.0
0.16
02/16/21 00:01
Toluene
ug/L
ND
1.0
0.24
02/16/21 00:01
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
02/16/21 00:01
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
02/16/21 00:01
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
02/16/21 00:01
Trichloroethene
ug/L
ND
1.0
0.22
02/16/21 00:01
Trichlorofluoromethane
ug/L
ND
1.0
0.31
02/16/21 00:01
Vinyl acetate
ug/L
ND
2.0
1.4
02/16/21 00:01
Vinyl chloride
ug/L
ND
1.0
0.24
02/16/21 00:01
Xylene (Total)
ug/L
ND
1.0
0.63
02/16/21 00:01
1,2-Dichloroethane-d4 (S)
%
110
70-130
02/16/21 00:01
4-Bromofluorobenzene (S)
%
102
70-130
02/16/21 00:01
Toluene-d8 (S)
%
99
70-130
02/16/21 00:01
LABORATORY CONTROL SAMPLE:
3163525
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
46.0
92
70-130
1,1,1-Trichloroethane
ug/L
50
47.2
94
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
43.3
87
70-130
1,1,2-Trichloroethane
ug/L
50
45.5
91
70-130
1,1-Dichloroethane
ug/L
50
48.5
97
70-130
1,1-Dichloroethene
ug/L
50
51.0
102
70-132
1,1-Dichloropropene
ug/L
50
47.1
94
70-131
1,2,3-Trichloropropane
ug/L
50
43.9
88
70-130
1,2,4-Trichlorobenzene
ug/L
50
44.8
90
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
43.9
88
70-132
1,2-Dibromoethane (EDB)
ug/L
50
45.1
90
70-130
1,2-Dichlorobenzene
ug/L
50
47.4
95
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 44

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
LABORATORY CONTROL SAMPLE: 3163525
Parameter
QUALITY CONTROL DATA
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,2-Dichloroethane
ug/L
50
47.4
95
70-130
1,2-Dichloropropane
ug/L
50
45.9
92
70-130
1,3-Dichlorobenzene
ug/L
50
48.0
96
70-130
1,3-Dichloropropane
ug/L
50
45.9
92
70-130
1,4-Dichlorobenzene
ug/L
50
47.2
94
70-130
2,2-Dichloropropane
ug/L
50
47.0
94
70-130
2-Butanone (MEK)
ug/L
100
92.5
92
70-133
2-Hexanone
ug/L
100
83.1
83
70-130
4-Methyl-2-pentanone (MIBK)
ug/L
100
84.5
84
70-130
Acetone
ug/L
100
96.8
97
70-144
Acetonitrile
ug/L
500
468
94
68-134
Acrolein
ug/L
250
208
83
32-2001H,IK
Acrylonitrile
ug/L
250
223
89
70-130
Allyl chloride
ug/L
50
46.8
94
70-134
Benzene
ug/L
50
44.4
89
70-130
Bromochloromethane
ug/L
50
48.5
97
70-130
Bromodichloromethane
ug/L
50
45.3
91
70-130
Bromoform
ug/L
50
45.0
90
70-131
Bromomethane
ug/L
50
51.6
103
30-177
Carbon disulfide
ug/L
50
49.6
99
70-133
Carbon tetrachloride
ug/L
50
44.9
90
70-130
Chlorobenzene
ug/L
50
45.2
90
70-130
Chloroethane
ug/L
50
46.6
93
46-131
Chloroform
ug/L
50
47.2
94
70-130
Chloromethane
ug/L
50
47.9
96
49-130
Chloroprene
ug/L
50
49.9
100
70-130
cis-1,2-Dichloroethene
ug/L
50
47.2
94
70-130
cis-1,3-Dichloropropene
ug/L
50
47.5
95
70-130
Dibromochloromethane
ug/L
50
47.3
95
70-130
Dibromomethane
ug/L
50
45.3
91
70-130
Dichlorodifluoromethane
ug/L
50
46.1
92
52-134
Ethyl methacrylate
ug/L
50
46.6
93
70-130
Ethylbenzene
ug/L
50
44.3
89
70-130
lodomethane
ug/L
100
104
104
47-140
Isobutanol
ug/L
1000
920
92
62-136
Methacrylonitrile
ug/L
500
459
92
70-130
Methyl methacrylate
ug/L
50
44.3
89
70-130
Methylene Chloride
ug/L
50
48.9
98
68-130
Naphthalene
ug/L
50
43.4
87
70-133
Propionitrile
ug/L
500
449
90
70-130
Styrene
ug/L
50
45.0
90
70-130
Tetrachloroethene
ug/L
50
43.1
86
70-130
Toluene
ug/L
50
44.2
88
70-130
trans-1,2-Dichloroethene
ug/L
50
48.0
96
70-130
trans- 1,3-Dichloropropene
ug/L
50
46.1
92
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
68.5
137
25-200
Trichloroethene
ug/L
50
44.8
90
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 44

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
LABORATORY CONTROL SAMPLE:
3163525
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Trichlorofluoromethane
ug/L
50
45.3
91
61-130
Vinyl acetate
ug/L
100
110
110
70-140
Vinyl chloride
ug/L
50
45.2
90
59-142
Xylene (Total)
ug/L
150
133
89
70-130
1,2-Dichloroethane-d4 (S)
%
101
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3163526
MS
92522105001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
3163527
MS
Result
MSD MS
Result % Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20
20.1
20.9
101
104
70-135
4
30
1,1,1-Trichloroethane
ug/L
ND
20
20
22.1
23.0
111
115
70-148
4
30
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
19.2
19.3
96
97
70-131
1
30
1,1,2-Trichloroethane
ug/L
ND
20
20
20.1
20.7
100
103
70-136
3
30
1,1-Dichloroethane
ug/L
ND
20
20
22.4
23.1
112
116
70-147
3
30
1,1-Dichloroethene
ug/L
ND
20
20
24.3
24.6
122
123
70-158
1
30
1,1-Dichloropropene
ug/L
ND
20
20
22.4
22.5
112
112
70-149
0
30
1,2,3-Trichloropropane
ug/L
ND
20
20
19.4
20.1
97
101
67-137
4
30
1,2,4-Trichlorobenzene
ug/L
ND
20
20
19.1
19.2
95
96
70-139
1
30
1,2-Dibromo-3-
ug/L
ND
20
20
18.9
18.6
95
93
69-136
1
30
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
19.6
20.1
98
100
70-137
2
30
1,2-Dichlorobenzene
ug/L
ND
20
20
21.3
21.4
106
107
70-133
1
30
1,2-Dichloroethane
ug/L
ND
20
20
21.8
22.0
109
110
67-138
1
30
1,2-Dichloropropane
ug/L
ND
20
20
20.9
21.6
104
108
70-138
3
30
1,3-Dichlorobenzene
ug/L
ND
20
20
21.7
21.7
108
109
70-133
0
30
1,3-Dichloropropane
ug/L
ND
20
20
20.6
21.0
103
105
70-136
2
30
1,4-Dichlorobenzene
ug/L
ND
20
20
21.3
21.5
106
107
70-133
1
30
2,2-Dichloropropane
ug/L
ND
20
20
23.3
23.8
116
119
52-155
2
30
2-Butanone (MEK)
ug/L
ND
40
40
38.9
40.2
97
100
61-147
3
30
2-Hexanone
ug/L
ND
40
40
37.2
37.5
93
94
67-139
1
30
4-Methyl-2-pentanone
ug/L
ND
40
40
37.8
37.4
95
93
67-136
1
30
(MIBK)
Acetone
ug/L
ND
40
40
41.5
41.5
104
104
55-159
0
30
Acetonitrile
ug/L
ND
200
200
215
214
107
107
66-145
1
30
Acrolein
ug/L
ND
100
100
159
161
159
161
10-200
1
30 IH,IK
Acrylonitrile
ug/L
ND
100
100
101
101
101
101
68-140
0
30
Allyl chloride
ug/L
ND
20
20
21.9
23.2
110
116
70-147
6
30
Benzene
ug/L
ND
20
20
20.6
21.4
103
107
67-150
4
30
Bromochloromethane
ug/L
ND
20
20
21.4
23.0
107
115
70-146
7
30
Bromodichloromethane
ug/L
ND
20
20
20.0
21.0
100
105
70-138
5
30
Bromoform
ug/L
ND
20
20
17.9
18.6
89
93
57-138
4
30
Bromomethane
ug/L
ND
20
20
26.9
27.8
134
139
10-200
3
30
Carbon disulfide
ug/L
ND
20
20
23.0
23.4
115
117
70-152
2
30
Results presented on this page are in the units
indicated by the "Units" column except where
an alternate unit is presented to the right of the result.
REPORT
OF LABORATORY ANALYSIS
This report shall
not be reproduced,
except in full,
Date: 02/22/2021 04:16 PM
without
the written
consent of Pace Analytical
Services, LLC.
Page 37 of 44

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3163526
3163527
MS
MSD
92522105001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Carbon tetrachloride
ug/L
ND
20
20
21.4
22.1
107
111
70-147
3
30
Chlorobenzene
ug/L
ND
20
20
20.7
21.1
103
105
70-137
2
30
Chloroethane
ug/L
ND
20
20
23.9
24.5
120
122
51-166
2
30 v1
Chloroform
ug/L
ND
20
20
21.5
22.2
107
111
70-144
3
30
Chloromethane
ug/L
ND
20
20
22.1
22.3
111
111
24-161
1
30
Chloroprene
ug/L
ND
20
20
23.4
24.2
117
121
70-143
4
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.0
22.6
110
113
67-148
3
30
cis-1,3-Dichloropropene
ug/L
ND
20
20
20.7
21.6
104
108
70-142
4
30
Dibromochloromethane
ug/L
ND
20
20
20.2
20.7
101
103
68-138
2
30
Dibromomethane
ug/L
ND
20
20
20.0
20.4
100
102
70-134
2
30
Dichlorodifluoromethane
ug/L
ND
20
20
21.2
21.7
106
109
43-155
3
30
Ethyl methacrylate
ug/L
ND
20
20
20.9
20.7
105
103
70-137
1
30
Ethylbenzene
ug/L
ND
20
20
20.2
20.8
101
104
68-143
3
30
lodomethane
ug/L
ND
40
40
46.4
47.4
116
119
20-161
2
30
Isobutanol
ug/L
ND
400
400
370
364
92
91
44-145
2
30
Methacrylonitrile
ug/L
ND
200
200
211
213
105
107
67-139
1
30
Methyl methacrylate
ug/L
ND
20
20
20.3
20.4
101
102
70-130
1
30
Methylene Chloride
ug/L
ND
20
20
22.6
23.3
113
116
64-148
3
30
Naphthalene
ug/L
ND
20
20
19.7
19.5
99
98
57-150
1
30
Propionitrile
ug/L
ND
200
200
205
202
103
101
70-138
2
30
Styrene
ug/L
ND
20
20
19.8
21.1
99
106
70-136
6
30
Tetrachloroethene
ug/L
ND
20
20
19.7
20.0
99
100
70-139
2
30
Toluene
ug/L
ND
20
20
20.4
20.9
102
105
47-157
3
30
trans-1,2-Dichloroethene
ug/L
ND
20
20
22.7
23.6
113
118
70-149
4
30
trans-1,3-Dichloropropene
ug/L
ND
20
20
20.4
21.0
102
105
70-138
3
30
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20
21.5
21.6
108
108
31-145
0
30
Trichloroethene
ug/L
ND
20
20
20.7
21.1
104
105
70-149
2
30
Trichlorofluoromethane
ug/L
ND
20
20
22.7
23.2
113
116
61-154
2
30
Vinyl acetate
ug/L
ND
40
40
49.5
49.6
124
124
48-156
0
30
Vinyl chloride
ug/L
ND
20
20
21.2
21.9
106
109
55-172
3
30
Xylene (Total)
ug/L
ND
60
60
61.1
62.5
102
104
66-145
2
30
1,2-Dichloroethane-d4 (S)
%
111
110
70-130
4-Bromofluorobenzene (S)
%
99
99
70-130
Toluene-d8 (S)
%
99
99
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 38 of 44

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
QC Batch: 600029 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92522105001, 92522105002, 92522105003, 92522105004, 92522105005, 92522105006, 92522105008,
92522105009,92522105010
METHOD BLANK: 3163273
Matrix:
Water
Associated Lab Samples:
92522105001, 92522105002, 92522105003,
92522105004, 92522105005, 92522105006, 92522105008,
92522105009,92522105010
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 02/15/21 09:47
1,2-Dichloroethane-d4 (S)
%
101
70-130
02/15/21 09:47
Toluene-d8 (S)
%
97
66-133
02/15/21 09:47
LABORATORY CONTROL SAMPLE: 3163274
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.1 101 70-130
1,2-Dichloroethane-d4 (S) % 98 70-130
Toluene-d8 (S) % 95 66-133
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3163275 3163276
Parameter
1,4-Dioxane (p-Dioxane)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
MS
92522105001 Spike
Units Result Conc.
ug/L ND 20
MSD
Spike MS MSD MS
MSD
% Rec
Max
Conc. Result Result % Rec
% Rec
Limits
RPD RPD Qual
20 20.7 20.0 103
100
64-141
3 30
95
94
70-130
30
94
93
66-133
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC.
Page 39 of 44

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 44

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: BUTNER LANDFILL COMPLIANCE
Pace Project No.: 92522105
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92522105001
3902-MW1 R
EPA 3010A
600757
EPA 6010D
601029
92522105002
3902-MW2R
EPA 3010A
600757
EPA 6010D
601029
92522105003
3902-MW3R
EPA 3010A
600757
EPA 6010D
601029
92522105004
3902-MW4
EPA 3010A
600757
EPA 6010D
601029
92522105005
3902-MW5
EPA 3010A
600757
EPA 6010D
601029
92522105006
3902-MW6
EPA 3010A
600757
EPA 6010D
601029
92522105007
3902-NES1
EPA 3010A
600757
EPA 6010D
601029
92522105008
3902-FIELD BLANK
EPA 3010A
600757
EPA 6010D
601029
92522105009
3902-SW2
EPA 3010A
600757
EPA 6010D
601029
92522105001
3902-MW1R
EPA 3010A
601155
EPA 6020B
601173
92522105002
3902-MW2R
EPA 3010A
601155
EPA 6020B
601173
92522105003
3902-MW3R
EPA 3010A
601155
EPA 6020B
601173
92522105004
3902-MW4
EPA 3010A
601155
EPA 6020B
601173
92522105005
3902-MW5
EPA 3010A
601155
EPA 6020B
601173
92522105006
3902-MW6
EPA 3010A
601155
EPA 6020B
601173
92522105008
3902-FIELD BLANK
EPA 3010A
601155
EPA 6020B
601173
92522105009
3902-SW2
EPA 3010A
601155
EPA 6020B
601173
92522105001
3902-MW1 R
EPA 7470A
600090
EPA 7470A
600115
92522105002
3902-MW2R
EPA 7470A
600090
EPA 7470A
600115
92522105003
3902-MW3R
EPA 7470A
600090
EPA 7470A
600115
92522105001
3902-MW1R
EPA 8260D
600063
92522105002
3902-MW2R
EPA 8260D
600063
92522105003
3902-MW3R
EPA 8260D
600063
92522105004
3902-MW4
EPA 8260D
600063
92522105005
3902-MW5
EPA 8260D
600063
92522105006
3902-MW6
EPA 8260D
600063
92522105008
3902-FIELD BLANK
EPA 8260D
600063
92522105009
3902-SW2
EPA 8260D
600063
92522105010
3902-TRIP BLANK
EPA 8260D
600063
92522105001
3902-MW1 R
EPA 8260D Mod.
600029
92522105002
3902-MW2R
EPA 8260D Mod.
600029
92522105003
3902-MW3R
EPA 8260D Mod.
600029
92522105004
3902-MW4
EPA 8260D Mod.
600029
92522105005
3902-MW5
EPA 8260D Mod.
600029
92522105006
3902-MW6
EPA 8260D Mod.
600029
92522105008
3902-FIELD BLANK
EPA 8260D Mod.
600029
92522105009
3902-SW2
EPA 8260D Mod.
600029
92522105010
3902-TRIP BLANK
EPA 8260D Mod.
600029
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/22/2021 04:16 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 44

Document Name: Document Revised: October 28, 2020
Sample Condition Upon Receipt(SCUR) Page 1 of 2
� aCeAnalytical Document No.: Issuing Authority:
+' F-CAR-CS-033-Rev.07 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville 0 Raleigh❑ Mechanicsville❑ Atlanta[:] Kernersville❑
Sample Condition Client Name: WO# : 925221Q5
Upon Receipt y f ` Project
rn�oll (A s �'e 1111111111111111111111
Courier: ❑FedEx "❑UPS ❑USPS ❑ClientCommercial Pace ❑Other:
92522105
Custody Seal Present? Des �SNo Seals Intact? ❑Yes ONo
Date/Initials Person Examining Contents: L'
Packing Material, ❑Bubble Wrap QBubble Bags ❑None ❑ Other BiologicaIT' s a frozen?
Thermometer: 92TO64 ❑Yes ❑No}N/A
r IR Gun ID: ❑Wet ❑Blue ❑None
I �1 Type of Ice:
Correction Factor:
Cooler Temp: '' �" Add/Subtract (°C) -0.1 Temp should be above freezing to 6°C
! ❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected ('C): c� ' ! has begun
USDA Regulated Soil (-aN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
inrludina Hawaii and Puortn WcoS) MYes -71No
Comm ents/1]Iscrepancy:
Chain of Custody Present?
jtSyes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
yes
No
❑N/A
2.
5hort Hold Time Analysis (<72 hr.)?
❑Yes
❑No
t5N/A
3.
Rush Turn Around Time Requested?
[]Yes
[:]No
13WA
4.
Sufficient Volume?
tLYas
CJNO
❑N/A
5.
Correct Containers Used?
Yes
❑No
❑N/A
6.
-Pace Containers Used?
Yes
❑No
❑N/A
Containers Intact?
�'es
[:]No
❑N/A
7.
Dissolved anaiysis: Samples Field Filtered?
❑Yes
❑No
&N/A
8.
Sample Labels Match COC?
`I✓ , _ es
BNo
❑N/A
wv
bid d { re"
-Includes bate/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
QYes
�SNo
❑N/A
10,
Trip Blank Present?
Yes
[-]No
❑N/A
11,
Trip Blank Custody Seals Present?
-71�es
❑No
[]N/A
COMMENTS/SAMPL DISCREPANCY '� I'n �1�Field Data Required? ❑Yes ❑No
.v��
CLIENT NOTIFICATION/RESOLUTION
Person Contacted: Date/Time:
Project Manager SCURF Review:
Lot ID of split Containers:
Date:
Project Manager SRF Review:
Date:
Page 42 of 44

Document Name: Document Revised: October 28, ZUZU
Sample Condition Upon Receipt(SOUR) Page 2 of 2
aceAnalytieal Document No : Issuing Authority:
F-CAR-CS-033-Rev.07 I Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechiorina#ion is Project
verified and within the acceptance range for preservation
samples.
Exceptlons: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottles
WO#:92522105
PM: NMG Due Date: 02/26/21
CLIENT: 92-Joyce Eng
R
E
w
V
Z
z
9
M
>
a
E
,-1
7
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Type of Preservative
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Date preservation adjusted
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adjusted
Amount of Preservative
added
Lot N
Note: Wheneuer there is a discrepancy affecting North Carolina compliance samples, a copy or this rorm will ne semto the North Larohna late-INg t;ertrricauon uncce (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 43 of 44

Section A
Section B
Rnnnir d Prni—t Infnrmati—
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section C
Invoice Information:
Page : i Of t
Company: LaBella Associates
Report To: Van Burbach
Attention: Jason Falls
Address: 2211 West Meadowview Rd
Copy To: Miguel Vazquez
Company Name: Granville County, Solid Waste
Greensboro, NC 27407
Address: P.O. Box 906, Oxford NC 27565
Re ulato Agency
Email TO: vburbach io ceen ineering. Com
Purchase Order No.
Phone: [phone] IFax
Client Proiect ID: Butner Landfill Compliance
State I Location
Requested Due DaterrAT: 10 Da Default
Container Order Number:
3566-6 3
North Carolina
Requested
An
lysis
Filtered
YIN
a
Z
MATRIX CODE
°
COLLECTED
=
Preservatives
DrinWng W.1v DW
v
u
U
2
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1-
U
to
_
Waste Water WW
Praduet P
SAMPLE ID S..VS.I.d SL
_
Q
START
END
0
O
U
w
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TIME
n
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U
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Z
Z
1
3902-MWIR
wT
G
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7
t�,
%�
X
X
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3902-MW2R
wr
G
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�
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12
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RELINQUISHED BY I AFFILIATION
DATE
TIME ACCEPTED BY I AFFILIATION
DATE
TIME
SAMPLE;CONDITIONS
ire ticc s ����s-3
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SAMPLER NAME AND SIGNATURE
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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 25, 2021
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill MNA
Pace Project No.: 92522062
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 12, 2021. The results relate only
to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
/7j"4w'
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill MNA
Pace Project No.: 92522062
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification M E87648
North Carolina Drinking Water Certification M 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill MNA
Pace Project No.: 92522062
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92522062001
3902-MW2R
Water
02/11/2111:35
02/12/2110:47
92522062002
3902-MW3R
Water
02/11/2110:41
02/12/2110:47
92522062003
3902-MW-1R
Water
02/11/2113:07
02/12/2110:47
92522062004
3902-NES-1
Water
02/11/2114:56
02/12/2110:47
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 22

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill MNA
92522062
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92522062001
3902-MW2R
RSK 175 Modified
MAD
1
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
NFW
1
PASI-A
EPA 300.0 Rev 2.1 1993
JLH
2
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2011
JLH
1
PASI-A
92522062002
3902-MW3R
RSK 175 Modified
MAD
1
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
NFW
1
PASI-A
EPA 300.0 Rev 2.1 1993
JLH
2
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2011
JLH
1
PASI-A
92522062003
3902-MW-1 R
RSK 175 Modified
MAD
1
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
NFW
1
PASI-A
EPA 300.0 Rev 2.1 1993
JLH
2
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2011
JLH
1
PASI-A
92522062004
3902-NES-1
RSK 175 Modified
MAD
1
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
JLH
2
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 5310B-2011
JLH
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Butner Landfill MNA
Pace Project No.: 92522062
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92522062001
3902-MW2R
RSK 175 Modified
Methane
6660
ug/L
10.0
02/12/21 18:47
SM 2320B-2011
Alkalinity, Total as CaCO3
875000
ug/L
5000
02/19/21 21:43
SM 521OB-2011
BOD, 5 day
9870
ug/L
2000
02/18/21 01:19 B3
EPA 300.0 Rev 2.1 1993
Chloride
201000
ug/L
4000
02/16/21 16:29 M1
SM 5220D-2011
Chemical Oxygen Demand
108000
ug/L
25000
02/23/21 05:26
SM 531OB-2011
Total Organic Carbon
28200
ug/L
1000
02/25/21 00:30
92522062002
3902-MW3R
RSK 175 Modified
Methane
519
ug/L
10.0
02/12/21 19:02
SM 2320B-2011
Alkalinity, Total as CaCO3
724000
ug/L
5000
02/19/21 21:54
EPA 300.0 Rev 2.1 1993
Chloride
148000
ug/L
3000
02/16/21 17:13
EPA 300.0 Rev 2.1 1993
Sulfate
819J
ug/L
1000
02/16/21 10:37
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
58.7
ug/L
40.0
02/12/21 22:02
SM 5220D-2011
Chemical Oxygen Demand
38000
ug/L
25000
02/23/21 05:26
SM 531OB-2011
Total Organic Carbon
7680
ug/L
1000
02/25/21 00:47
92522062003
3902-MW-1 R
SM 2320B-2011
Alkalinity, Total as CaCO3
53900
ug/L
5000
02/19/21 22:05
EPA 300.0 Rev 2.1 1993
Chloride
3670
ug/L
1000
02/16/21 10:52
EPA 300.0 Rev 2.1 1993
Sulfate
1410
ug/L
1000
02/16/21 10:52
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
56.5
ug/L
40.0
02/12/21 22:03
92522062004
3902-NES-1
EPA 300.0 Rev 2.1 1993
Chloride
4060
ug/L
1000
02/16/21 11:06
EPA 300.0 Rev 2.1 1993
Sulfate
5920
ug/L
1000
02/16/21 11:06
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
4650
ug/L
40.0
02/12/21 22:05
SM 531OB-2011
Total Organic Carbon
1610
ug/L
1000
02/25/21 02:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92522062
Sample: 3902-MW2R
Lab ID: 92522062001 Collected:
02/11/21
11:35
Received: 02/12/21 10:47 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
6660 ug/L 10.0
3.4
1
02/12/21 18:47
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
875000 ug/L 5000
5000
1
02/19/21 21:43
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
9870 ug/L 2000
2000
1
02/13/21 04:46 02/18/21 01:19
B3
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
201000 ug/L 4000
2400
4
02/16/2116:29
16887-00-6 M1
Sulfate
ND ug/L 1000
500
1
02/16/2109:54
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
02/12/21 21:59
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
108000 ug/L 25000
12500
1
02/23/21 02:36 02/23/21 05:26
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
28200 ug/L 1000
500
1
02/25/21 00:30
7440-44-0
Date: 02/25/2021 03:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92522062
Sample: 3902-MW3R
Lab ID: 92522062002 Collected:
02/11/21 10:41
Received: 02/12/21 10:47 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
519 ug/L 10.0
3.4
1
02/12/21 19:02
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
724000 ug/L 5000
5000
1
02/19/21 21:54
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND ug/L 2000
2000
1
02/13/21 04:46 02/18/21 01:12
B3
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
148000 ug/L 3000
1800
3
02/16/2117:13
16887-00-6
Sulfate
8191 ug/L 1000
500
1
02/16/2110:37
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
58.7 ug/L 40.0
10.0
1
02/12/21 22:02
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
38000 ug/L 25000
12500
1
02/23/21 02:36 02/23/21 05:26
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
7680 ug/L 1000
500
1
02/25/21 00:47
7440-44-0
Date: 02/25/2021 03:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92522062
Sample: 3902-MWAR
Lab ID: 92522062003 Collected:
02/11/21 13:07
Received: 02/12/21 10:47 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L 10.0
3.4
1
02/12/2119:17
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
53900 ug/L 5000
5000
1
02/19/21 22:05
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND ug/L 2000
2000
1
02/13/21 04:46 02/18/21 01:32
B3
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
3670 ug/L 1000
600
1
02/16/2110:52
16887-00-6
Sulfate
1410 ug/L 1000
500
1
02/16/2110:52
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
56.5 ug/L 40.0
10.0
1
02/12/21 22:03
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L 25000
12500
1
02/23/21 02:36 02/23/21 05:26
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
ND ug/L 1000
500
1
02/25/21 01:41
7440-44-0
Date: 02/25/2021 03:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 22

leAnalyiical
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9800 Kincey Ave. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92522062
Sample: 3902-NES-1
Lab ID: 92522062004 Collected:
02/11/21 14:56
Received: 02/12/21 10:47 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Methane
ND ug/L 10.0
3.4
1
02/12/2119:33
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
ND ug/L 5000
5000
1
02/19/21 22:15
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND ug/L 2000
2000
1
02/13/21 11:27 02/18/21 11:18
B2,B3
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
Chloride
4060 ug/L 1000
600
1
02/16/2111:06
16887-00-6
Sulfate
5920 ug/L 1000
500
1
02/16/2111:06
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
4650 ug/L 40.0
10.0
1
02/12/21 22:05
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND ug/L 25000
12500
1
02/23/21 02:36 02/23/21 05:27
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
1610 ug/L 1000
500
1
02/25/21 02:31
7440-44-0
Date: 02/25/2021 03:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 599730 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
METHOD BLANK: 3161597
Matrix:
Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
Methane
ug/L
ND
10.0
3.4 02/12/2113:10
LABORATORY CONTROL SAMPLE:
3161598
Spike
LCS LCS
% Rec
Parameter
Units
Conc.
Result % Rec
Limits Qualifiers
Methane
ug/L
396
388 98
70-130
MATRIX SPIKE SAMPLE: 3162954
35611042002 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Methane ug/L 180 396 616 110 70-130
SAMPLE DUPLICATE: 3162953
35611042001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L 792 773 2 20
SAMPLE DUPLICATE: 3162955
92521864001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Methane ug/L 110 99.7 10 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 601242 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
METHOD BLANK: 3168535 Matrix: Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L ND 5000 5000 02/19/21 20:17
LABORATORY CONTROL SAMPLE: 3168536
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L 50000 51300 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3168537 3168538
MS MSD
92522942011 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 16.9 mg/L 50000 50000 70100 70100 106 106 80-120 0 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3168539 3168540
MS MSD
92522564001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 51600 52200 103 104 80-120 1 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 599835 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002, 92522062003
METHOD BLANK: 3162386 Matrix: Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day ug/L ND 2000 2000 02/18/21 00:28 B3
LABORATORY CONTROL SAMPLE:
3162388
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000
215000 109 84.6-115 B3
SAMPLE DUPLICATE: 3162389
92521761001
Dup Max
Parameter
Units
Result
Result RPD RPD Qualifiers
BOD, 5 day
ug/L
170 mg/L
171000 1 25 B3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 599869 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062004
METHOD BLANK: 3162454 Matrix: Water
Associated Lab Samples: 92522062004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
BOD, 5 day ug/L ND 2000 2000 02/18/21 10:37 B3
LABORATORY CONTROL SAMPLE:
3162455
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000
211000 107 84.6-115 B3
SAMPLE DUPLICATE: 3162456
92522068002
Dup Max
Parameter
Units
Result
Result RPD RPD Qualifiers
BOD, 5 day
ug/L
104 mg/L
96600 7 25 B3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 599864
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002,
92522062003, 92522062004
METHOD BLANK: 3162432
Matrix: Water
Associated Lab Samples: 92522062001, 92522062002,
92522062003, 92522062004
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Chloride ug/L
ND 1000
600 02/16/2105:34
Sulfate ug/L
ND 1000
500 02/16/2105:34
LABORATORY CONTROL SAMPLE: 3162433
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Chloride ug/L
50000 51500
103
90-110
Sulfate ug/L
50000 52300
105
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3162434 3162435
MS MSD
92521875004
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride ug/L 45.7 mg/L
50000 50000 96100
96200
101 101 90-110
0 10
Sulfate ug/L 8560
50000 50000 60400
60600
104 104 90-110
0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3162436 3162437
MS MSD
92522062001
Spike Spike MS
MSD
MS MSD % Rec
Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits
RPD RPD Qual
Chloride ug/L 201000
50000 50000 246000
246000
89 91 90-110
0 10 M1
Sulfate ug/L ND
50000 50000 52400
53600
104 107 90-110
2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 599818 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
METHOD BLANK: 3162326 Matrix: Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Nitrate ug/L ND 40.0 10.0 02/12/21 21:55
LABORATORY CONTROL SAMPLE: 3162327
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate ug/L 1500 1520 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3162328 3162329
MS MSD
92522062001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L ND 1500 1500 1450 1440 97 96 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 601776 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
METHOD BLANK: 3170980 Matrix: Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chemical Oxygen Demand ug/L ND 25000 12500 02/23/21 05:22
LABORATORY CONTROL SAMPLE: 3170981
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand ug/L 750000 761000 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3170982 3170983
MS MSD
92522170001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L ND 100000 100000 124000 126000 106 109 90-110 2 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3170984 3170985
MS MSD
92522170002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 47.0 mg/L 100000 100000 151000 144000 104 97 90-110 5 3 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92522062
QC Batch: 600137 Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
METHOD BLANK: 3163890 Matrix: Water
Associated Lab Samples: 92522062001, 92522062002, 92522062003, 92522062004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Total Organic Carbon ug/L ND 1000 500 02/24/21 20:01
LABORATORY CONTROL SAMPLE: 3163891
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Organic Carbon ug/L 25000 24200 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3163892 3163893
MS MSD
92522145001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 5.4 mg/L 25000 25000 29700 30000 97 98 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3163894 3163895
MS MSD
92522062002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 7680 25000 25000 32600 33000 100 101 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 22

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Butner Landfill MNA
Pace Project No.: 92522062
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
B2 Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.
B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/25/2021 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 22

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill MNA
92522062
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92522062001
3902-MW2R
RSK 175 Modified
599730
92522062002
3902-MW3R
RSK 175 Modified
599730
92522062003
3902-MW-1 R
RSK 175 Modified
599730
92522062004
3902-NES-1
RSK 175 Modified
599730
92522062001
3902-MW2R
SM 2320B-2011
601242
92522062002
3902-MW3R
SM 2320B-2011
601242
92522062003
3902-MW-1 R
SM 2320E-2011
601242
92522062004
3902-NES-1
SM 2320E-2011
601242
92522062001
3902-MW2R
SM 5210B-2011
599835
SM 5210B-2011
599861
92522062002
3902-MW3R
SM 5210B-2011
599835
SM 5210B-2011
599861
92522062003
3902-MW-1R
SM 5210B-2011
599835
SM 5210B-2011
599861
92522062004
3902-NES-1
SM 5210E-2011
599869
SM 5210B-2011
599877
92522062001
3902-MW2R
EPA 300.0 Rev 2.1 1993
599864
92522062002
3902-MW3R
EPA 300.0 Rev 2.1 1993
599864
92522062003
3902-MW-1 R
EPA 300.0 Rev 2.1 1993
599864
92522062004
3902-NES-1
EPA 300.0 Rev 2.1 1993
599864
92522062001
3902-MW2R
EPA 353.2 Rev 2.0 1993
599818
92522062002
3902-MW3R
EPA 353.2 Rev 2.0 1993
599818
92522062003
3902-MW-1 R
EPA 353.2 Rev 2.0 1993
599818
92522062004
3902-NES-1
EPA 353.2 Rev 2.0 1993
599818
92522062001
3902-MW2R
SM 5220D-2011
601776
SM 5220D-2011
601800
92522062002
3902-MW3R
SM 5220D-2011
601776
SM 5220D-2011
601800
92522062003
3902-MW-1R
SM 5220D-2011
601776
SM 5220D-2011
601800
92522062004
3902-NES-1
SM 5220D-2011
601776
SM 5220D-2011
601800
92522062001
3902-MW2R
SM 5310B-2011
600137
92522062002
3902-MW3R
SM 5310B-2011
600137
92522062003
3902-MW-1 R
SM 5310E-2011
600137
92522062004
3902-NES-1
SM 5310E-2011
600137
Date: 02/25/2021 03:57 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 22

Document name: Document Revised: October 28, 2020
Sample Condition Upon Receipt(SCUR) Page 1 of 2
ceAnalytical' Document No.: Issuing Authority:
` F-CAR-CS-033•Rev.07 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersvil'ieQ Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersviile❑
Sample Condition Itent Name;
Upon �( )�1.� Project Wall : 92522062
Courier: 'QFed Ex [:]UPS ❑LISPS ❑Client �� Ill Ii �� III III �Ii
❑ Commercial Pace ❑Other: I j
92522062
Custody Seal Present? ❑Yes �SNo Seals Intact? ❑Yes ��la
oate/Initials Person Examining Content,.) -
Packing Material: ❑Bubble Wrap -©bubble Bags ❑None ❑ Other Biological Tissue Frozen?
[]Yes ❑No E]N/A
Therm meter: �yvet ❑Blue [—]None
7"IR Gun ID: 92TO64 Type of Ice:
7 2 Correction Factor:
Cooler Temp: } Add/Subtract (°C) -0.1 Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
Cooler Temp Corrected (°C): has begun
USDA Regulated Soil (E] N/A, water sample)
Did sampke3ior'iginate in a quarantine zone within the united States: CA, NY, or SC (check maps)? Did samples originate from a foreign source [in ernationally,
Flvpa � 1Nn includine Hawaii and Puerto Rico]? nYes No
Comments/Dlscrepa n cy:
Chain of Custody Present?
�11es
[:]NO
❑NIA
1.
Samples Arrived within Hold Time?
yes
[]No
❑N/A
2.
Short Hold Time Analysis (c72 hr.)?
[]Yes
❑No
'N/A
3.
Rush Turn Around Time Requested?
❑Yes
❑No
[]N/A
4.
Sufficient Volume?
ryes
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers used?
Yes
I-Yes
❑No
❑No
[-]N/A
❑N/A
6.
Containers Intact?
Yes
[:]No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
[]Yes
[-]No
/A
8.
Sample Labels Match COC?
-includes Date/Time/ID/Analysis Matrix:
Yes
❑No
❑N/A
9.
headspace in VOA Vials (>5-6mm)?
❑yes
bNo
N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
QYes
❑Yes
El N oN,
❑No
N/A
N/A
11,
COMMENTS/SAMPLE DISCREPANCY
Field Data Required? Dyes []No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: pate;
Project Manager SRF Review: Date:
Page 20 of 22

Document Revised: Uctooer [n, LVLU
Page 2 of 2
��aceAnaVical'
Document Name:
Sample Condition upon Recei
Document No.:
F-CAR-CS-033-f1 ay.07
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/6015 (water) OOC, LLHg
"Bottom half of box is to fist number of bottles
Issuing Authority:
Pace Carolinas Quality Office
Project If IWO#:92522062
PM: NMG Due Date: 02/26/21
CLIENT: 92-Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted I Time preservation I Amount of Preservative Lot a
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Cerlification Office {i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 21 of 22

51
.laaceAWIcal•
ww.rueires.cox
Section.A
Required Client Information:
Company: La Bella Associates, D.P.C. - NC
Address: 2211 West Meadow iew Rd
Greensboro, NC 27407
Email: vburbach labellapc,com
Phone: (336j707-3874 Fax
Requested Due pate:
SAMPLE ID
One Character per box.
#
to-Z, 0-9 1, -)
2
Sample Ids must be unique
W
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3902-MW2R
.2
3902-MW3R
3
3902-MW-1R
4
3902-NES-1
5
6
7
8
9
10
11
ADDITIONAL COMMENTS
Section B
Required Project
information:
Report
TD, Van
Burbach
Copy To.
Purchase Order M
Project Name,
Butner Landfill MNA
Project #
MATRIX
CODE
a
° COI
❑rknking Water DW q
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CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
N
P Y� �
Section C @
a
Invoice Information: Pa e : 1 Of 1
Attention'.
company Name:
Address _ Regulatory Agency
Pace Quote.
Pace Project Manager: nico€e.gasiorowski pacelabs.com, State! Location
Pace Profile #; 3566-2
NC
Requested Analysis Filtered YfN
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Appendix D
Historical Groundwater Elevations

APPENDIX D: Historical Groundwater Elevations
Well ID:
Background
Downgradient
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Well TOC Elev.:
460.51
331.60
330.96
340.80
343.88
362.53
328.40
Well Depth:
56.00
18.85
35.83
31.43
23.52
32.63
32.80
21-Aug-99
418.68
329.13
328.06
330.50
330.83
352.10
NI
16-Nov-99
419.75
325.38
324.51
331.53
334.33
352.97
NI
10-May-00
424.53
329.60
328.83
334.15
334.49
355.72
NI
26-Oct-00
419.21
329.26
328.15
331.33
330.94
352.78
NI
18-Apr-01
418.76
329.42
328.63
333.57
334.36
354.22
NI
26-Oct-01
412.53
329.04
327.94
330.57
330.23
350.92
NI
13-Jun-02
413.70
328.38
327.41
330.21
330.29
351.04
NI
19-Nov-02
413.40
329.25
328.35
331.57
337.17
350.94
NI
27-Jun-03
423.61
329.57
328.93
334.24
333.99
355.21
NI
29-Dec-03
420.23
329.70
329.11
334.49
334.78
354.92
NI
30-Jun-04
418.81
329.38
328.48
332.26
331.39
353.10
NI
28-Dec-04
418.02
329.50
328.91
333.45
334.14
355.14
NI
29-Jun-05
418.81
329.10
329.26
331.62
330.90
352.76
NI
29-Dec-05
413.38
329.29
328.71
332.78
334.27
351.52
NI
27-Jun-06
414.75
329.17
328.40
332.18
333.56
353.43
NI
28-Dec-06
415.54
329.40
328.86
333.57
335.24
354.02
NI
12-Jul-07
438.64
328.69
327.97
331.31
330.52
352.30
NI
18-Dec-07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
8-Jul-08
414.52
329.20
326.00
331.46
330.85
351.03
NM
17-Dec-08
412.79
329.39
328.84
333.15
335.03
350.82
NM
9-Jul-09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
16-Dec-09
418.11
329.55
329.09
334.57
336.94
352.87
NM
24-Jun-10
422.42
329.41
328.77
333.65
333.15
353.62
NM
13-Dec-10
415.96
329.49
328.85
332.81
330.34
350.08
NM
20-Jun-11
416.00
328.95
328.18
336.77
331.38
351.83
NM
5-Dec-11
412.94
329.31
328.65
332.32
329.51
349.87
NM
11-Jun-12
414.56
329.10
328.35
332.52
331.33
351.75
312.50
12-Dec-12
412.83
329.19
328.36
331.67
330.35
349.48
NM
1-May-13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
5-Aug-13
417.97
329.02
328.41
333.32
332.83
353.01
NM
24-Feb-14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
11-Aug-14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
10-Mar-15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
17-Aug-15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
17-Feb-16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
9-Aug-16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
13-Feb-17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
22-Aug-17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
5-Feb-18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
14-Aug-18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
4-Feb-19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
6-Aug-19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
12-Feb-20
417.43
329.75
329.30
335.65
336.08
352.38
317.67
27-Aug-20
418.84
329.18
328.55
333.42
330.48
351.34
310.90
11-Feb-21
421.71
329.93
329.62
336.59
336.17
355.52
318.10
Notes: TOC = Top of casing.
Elevations in feet above mean sea level.
Granville County -Butner Landfill
Permit No. 39-02
NM = Water level not measured.
NI = Well not yet installed.
LaBella Associates

Appendix E
Historical Constituents in Groundwater

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
INORGANICS
Antimony
8-Sep-94
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
30
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
30
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
30
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
30
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
30
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
30
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
30
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
30
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
30
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
30
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
30
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
30
ND
80.0
38.0
32.0
33.0
31.0
---
---
26-Oct-00
---
30
30.0
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
30
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
30
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
30
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
30
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
30
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
30
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
30
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
6
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 1.4 pg/L (10/23/07)
19-Dec-07
---
6
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
6
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.6
6.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
2.6
6.0
ND
ND
ND
2.9 J
ND
ND
---
ND
IMAC = 1 pg/L (8/1/10)
13-Dec-10
2.6
6.0
ND
ND
3.0 J
ND
2.8 J
ND
---
ND
20-Jun-11
5.0
6.0
ND
ND
ND
ND
6.0
ND
---
ND
5-Dec-11
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
6.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
6.0
8.8
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
6.0
ND
10.5
8.0
ND
ND
ND
---
ND
10-Mar-15
3.8
6.0
ND
7.1
6.5
3.9 J
ND
ND
---
ND
18-Aug-15
3.8
6.0
ND
6.2
4.8 J
4.1 J
ND
ND
---
ND
16-Feb-16
3.8
6.0
ND
9.9
6.5
4.3 J
ND
ND
---
ND
9-Aug-16
3.8
6.0
ND
7.7
ND
ND
ND
ND
---
ND
13-Feb-17
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
3.9
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
3.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
Arsenic
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-J u n-97
---
10
6.0 J
15.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
5.0 J
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
2.0 J
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
4.1 J
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
10
ND
4.9 J
ND
ND
ND
ND
---
ND
17-Dec-08
2.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
2.7
10.0
ND
13.5
10.9
5.6 J
ND
4.0 J
ND
ND
16-Dec-09
2.7
10.0
ND
10.6
6.4 J
5.0 J
ND
3.6 J
---
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
2.7
10.0
ND
11.8
8.1 J
8.2 J
3.3 J
3.1 J
---
ND
Resample >
12-Aug-10
2.7
10.0
---
---
7.2 J
---
---
---
---
ND
Resample >
31-Aug-10
2.7
10.0
---
15.4
---
---
---
---
---
ND
13-Dec-10
2.7
10.0
ND
4.9 J
2.7 J
5.4 J
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
5.6 J
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
6.4 J
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
4.1 J
5.4 J
ND
ND
3.1 J
3.2 J
---
3.0 J
18-Aug-15
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
5.1 J
13-Feb-17
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
---
ND
4-Feb-19
5.0
10.0
ND
5.7 J
ND
ND
ND
ND
---
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
4.7
10.0
4.9 J
10.0 J
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Barium
8-Sep-94
---
500
ND
270
ND
ND
830
860
---
---
1-Dec-94
---
500
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
500
ND
ND
ND
ND
510
ND
---
---
2-Mar-95
---
500
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
500
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
500
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
500
ND
82.0
30.0
ND
15.0
ND
---
---
17-Jun-97
---
500
200
320
37.0
17.0
210
31.0
---
---
1-Dec-97
---
500
61.0
180
43.0
46.0
220
33.0
---
---
20-May-98
---
500
30.0
150
45.0
13.0
180
22.0
---
---
19-Nov-98
---
500
48.0
120
42.0
ND
380
12.0
---
---
21-J u 1-99
---
500
N D
N D
N D
N D
N D
N D
---
---
16-Nov-99
---
500
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
500
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
500
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
500
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
500
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
500
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
500
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
500
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
500
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
500
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
5.2 J
120
64.9
1.5 J
64.1
1.8 J
---
0.20 J
12-Jul-07
---
100
2.5 J
129
65.7 J
1.1 J
77.0 J
1.3 J
---
ND
NC 2L = 2,000 pg/L (10/23/07)
19-Dec-07
---
100
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
11.7
8-J u 1-08
---
100
5.8 J
102
58.4 J
1.1 B
57.9 J
1.2 B
---
0.29 J
17-Dec-08
0.20
100
2.7 B
92.9 J
53.1 B
1.2 B
55.5 J
1.1 B
---
10.7 J
9-Ju1-09
0.20
100
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
17.6 J
16-Dec-09
0.20
100
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
---
17.1 J
NC 2L = 700 pg/L (02/05/10)
24-Jun-10
0.20
100
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
---
27.3 J
13-Dec-10
0.20
100
4.3 B
122
67.9 J
1.3 B
90.6 J
1.5 B
---
12.1 J
20-Jun-11
5.0
100
ND
108
70.7 J
ND
84.7 J
ND
---
ND
5-Dec-11
5.0
100
ND
118
73.0 J
ND
90.6 J
ND
---
ND
11-Jun-12
5.0
100
ND
138
65.2 J
ND
76.4 J
ND
61.3 J
ND
12-Dec-12
5.0
100
ND
113
64.7 J
ND
73.6 J
ND
---
ND
1-May-13
5.0
100
ND
118
69.1 J
ND
84.2 J
ND
81.2 J
ND
5-Aug-13
5.0
100
ND
111
65.1 J
ND
95.6 J
ND
---
ND
24-Feb-14
5.0
100
ND
93.8 J
44.8 J
ND
139
ND
ND
ND
12-Aug-14
5.0
100
ND
125
66.4 J
ND
121
ND
---
ND
10-Mar-15
2.5
100
3.0 J
109
61.8 J
ND
116
ND
---
ND
18-Aug-15
2.5
100
4.4 J
119
63.1 J
ND
81.3 J
ND
---
ND
16-Feb-16
2.5
100
5.2 J
123
72.7 J
3.0 J
126
ND
---
ND
9-Aug-16
2.5
100
4.5 J
123
73.3 J
ND
109
ND
---
ND
13-Feb-17
2.5
100
7.8 J
112
68.3 J
ND
151
5.6 J
---
ND
22-Aug-17
2.5
100
ND
102
64.5 J
ND
99.9 J
ND
---
ND
5-Feb-18
2.5
100
8.0 J
117
73.5 J
ND
161
ND
---
ND
13-Aug-18
2.5
100
3.8 J
116
67.6 J
ND
103
ND
---
ND
4-Feb-19
2.5
5.0
ND
104
44.3
ND
110
ND
---
ND
7-Aug-19
1.0
5.0
5.4
113
73.8
1.2 J
95.1
1.9 J
---
ND
12-Feb-20
1.0
5.0
3.6 J
110
56.2
2.5 J
147
1.6 J
---
ND
27-Aug-20
3.5
5.0
4.5 J
127
83.2
ND
128
ND
---
ND
11-Feb-21
3.5
5.0
5.3
116
74.4
ND
161
ND
---
ND
Beryllium
8-Sep-94
---
2
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
2
ND
ND
ND
ND
4.0
ND
---
---
9-Feb-95
---
2
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
2
ND
ND
ND
ND
2.0
ND
---
---
15-N ov-95
---
2
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
2
ND
ND
ND
ND
6.0
ND
---
---
22-Nov-96
---
2
ND
ND
ND
ND
3.0
ND
---
---
17-J u n-97
---
2
2.0
3.0
ND
ND
1.0
ND
---
---
1-Dec-97
---
2
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
2
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
2
ND
ND
ND
ND
2.0
ND
---
---
21-J u 1-99
---
2
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
2
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
2
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
2
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
2
N D
12.0
N D
N D
N D
N D
---
---
2 7-Oct-01
---
2
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
2
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
2
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
2
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 4 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.10
1.0
ND
ND
ND
ND
0.14 J
ND
---
ND
9-Ju1-09
0.10
1.0
ND
0.18 J
0.22 J
0.17 J
ND
ND
0.23 J
ND
16-Dec-09
0.10
1.0
ND
0.15 J
0.17 J
0.15 J
0.25 J
ND
---
ND
24-Jun-10
0.10
1.0
ND
ND
0.27 J
0.16 J
ND
ND
---
ND
13-Dec-10
0.10
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
0.57 J
ND
---
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.20
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.20
1.0
0.27 J
ND
ND
ND
ND
0.21 J
---
ND
27-Aug-20
0.70
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.70
1.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cadmium
8-Sep-94
---
1
ND
ND
ND
ND
ND
4.0
---
---
1-Dec-94
---
1
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
1
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
1
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
1
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
1
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
1
ND
ND
ND
ND
ND
ND
---
---
17-J u n-97
---
1
ND
3.0
1.0
ND
ND
ND
---
---
1-Dec-97
---
1
ND
2.0
ND
ND
ND
ND
---
---
20-May-98
---
1
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
1
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
1
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
1
N D
3.0
3.0
N D
2.0
N D
---
---
10-May-00
---
1
5.0
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
1
N D
2.0
N D
N D
N D
N D
---
---
18-A p r-01
---
1
N D
11.0
N D
N D
N D
N D
---
---
2 7-Oct-01
---
1
N D
N D
N D
N D
N D
N D
---
---
13-J u n-02
---
1
N D
2.0
N D
N D
N D
N D
---
---
19-N ov-02
---
1
2.0
2.0
N D
N D
2.0
N D
---
---
27-Jun-03
---
1
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
1
ND
1.0
ND
ND
ND
ND
---
ND
30-Jun-04
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
1
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.75 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
1
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
0.50
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
16-Dec-09
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2 pg/L (02/05/10)
24-Jun-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.40
1.0
ND
ND
ND
0.48 J
ND
ND
---
ND
12-Feb-20
0.40
1.0
ND
ND
ND
0.69 J
ND
ND
---
ND
27-Aug-20
0.40
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.40
1.0
ND
0.7 J
0.7 J
1.10
ND
ND
---
ND
Chromium
8-Sep-94
---
10
8.0
44.0
ND
6.0
48.0
80.0
---
---
1-Dec-94
---
10
14.0
ND
ND
ND
18.0
ND
---
---
9-Feb-95
---
10
14.0
ND
ND
10.0
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
10
13.0
13.0
ND
ND
ND
ND
---
---
28-May-96
---
10
33.0
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
3.0
ND
ND
ND
ND
3.0
---
---
17-J u n-97
---
10
57.0
43.0
ND
3.0
2.0
6.0
---
---
1-Dec-97
---
10
29.0
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
10.0
3.0
ND
ND
12.0
ND
---
---
19-N ov-98
---
10
17.0
3.0
ND
ND
5.0
ND
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
12.0
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
2.0 B
ND
ND
ND
ND
1.1 B
1.4 J
8-J u 1-08
---
10
N D
0.54 J
0.58 J
N D
N D
N D
---
N D
17-Dec-08
0.40
10.0
0.73 J
1.8 J
0.96 J
ND
0.96 J
0.70 J
---
ND
9-J u 1-09
0.40
10.0
1.2 J
2.4 J
1.1 J
1.6 J
0.68 J
0.53 J
4.8 J
N D
16-Dec-09
0.40
10.0
1.3 J
ND
ND
ND
0.95 J
ND
---
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
0.40
10.0
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
---
0.71 J
13-Dec-10
0.40
10.0
2.5 J
1.3 J
1.8 J
0.69 J
0.57 J
1.2 J
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
8.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
5.2 J
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
2.7 J
ND
ND
ND
6.7 J
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
2.8 B
2.8 B
ND
ND
ND
ND
---
2.9 J
13-Feb-17
2.5
10.0
ND
2.6 J
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
1.0
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
1.0
5.0
1.5 J
ND
ND
1.1 J
ND
ND
---
ND
27-Aug-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
3.7
5.0
4.1 J
4 J
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cobalt
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
11.0
ND
13.0
16.0
22.0
ND
---
---
9-Feb-95
---
10
20.0
14.0
ND
48.0
39.0
ND
---
---
2-Mar-95
---
10
16.0
21.0
ND
29.0
121.0
ND
---
---
15-Nov-95
---
10
20.0
21.0
ND
ND
27.0
ND
---
---
28-May-96
---
10
30.0
16.0
ND
ND
122
ND
---
---
22-Nov-96
---
10
6.0
13.0
ND
4.7
93.0
ND
---
---
17-J u n-97
---
10
130
38.0
ND
6.0
45.0
3.0
---
---
1-Dec-97
---
10
32.0
21.0
ND
12.0
36.0
4.0
---
---
20-May-98
---
10
15.0
16.0
2.0
9.0
100
3.0
---
---
19-Nov-98
---
10
21.0
16.0
2.0
7.0
180
3.0
---
---
21-J u 1-99
---
10
N D
16.0
N D
N D
100
N D
---
---
16-N ov-99
---
10
N D
15.0
N D
N D
38.0
N D
---
---
10-May-00
---
10
N D
17.0
N D
N D
61.0
N D
---
---
26-Oct-00
---
10
N D
15.0
N D
N D
N D
N D
---
---
18-Apr-01
---
10
N D
27.0
N D
N D
74.0
N D
---
---
27-Oct-01
---
10
N D
12.0
N D
N D
47.0
N D
---
---
13-J u n-02
---
10
N D
14.0
N D
N D
251
N D
---
---
19-Nov-02
---
10
ND
10.0
ND
ND
57.0
ND
---
---
27-Jun-03
---
10
ND
15.0
ND
ND
75.0
ND
---
---
30-Dec-03
---
10
ND
17.0
ND
ND
52.0
ND
---
ND
30-Jun-04
---
10
ND
16.0
ND
ND
31.0
ND
---
ND
29-Dec-04
---
10
ND
11.0
ND
ND
46.0
ND
---
ND
29-Jun-05
---
10
ND
11.0
ND
ND
43.0
ND
---
ND
29-Dec-05
---
10
ND
12.0
ND
ND
30.0
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
72.5
ND
---
ND
29-Dec-06
---
10
ND
11.4
ND
ND
37.5
ND
---
ND
12-Jul-07
---
10
ND
11.8
ND
2.7
58.4
ND
---
ND
IMAC = 70 pg/L (10/23/07)
19-Dec-07
---
10
2.5 B
ND
ND
2.0 B
103
2.6 B
8.0 B
1.8 J
8-J u 1-08
---
10
10.3 B
12.1 B
2.0 B
9.0 B
130
4.8 B
---
6.2 J
17-Dec-08
0.60
10.0
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
---
2.5 J
9-Ju1-09
0.60
10.0
ND
6.2 J
ND
ND
100
ND
2.2 J
ND
16-Dec-09
0.60
10.0
ND
4.7 J
ND
ND
6.6 J
ND
---
ND
24-Jun-10
0.60
10.0
ND
16.3
ND
ND
25.0
ND
---
ND
IMAC = 1 pg/L (2/05/10)
13-Dec-10
0.60
10.0
2.5 B
15.5
ND
ND
{129)
{ND)
---
1.6 {1.0 J) J
20-Jun-11
5.0
10.0
ND
14.2
ND
ND
81.8
ND
---
ND
5-Dec-11
5.0
10.0
ND
12.7
ND
ND
146
ND
---
ND
Resample >
25-Jan-12
5.0
10.0
---
---
---
---
47.5
---
---
ND
11-Jun-12
5.0
10.0
ND
14.2
ND
ND
101
ND
ND
ND
12-Dec-12
5.0
10.0
ND
11.3
ND
ND
113
ND
---
ND
1-May-13
5.0
10.0
ND
24.3
ND
ND
34.0
ND
ND
ND
5-Aug-13
5.0
10.0
ND
24.7
ND
ND
50.9
ND
---
ND
24-Feb-14
5.0
10.0
ND
18.4
ND
ND
9.6 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
9.4 J
ND
ND
46.3
ND
---
ND
10-Mar-15
2.5
10.0
ND
8.7 J
ND
ND
39.2
ND
---
ND
18-Aug-15
2.5
10.0
ND
9.3 J
ND
ND
116
ND
---
ND
16-Feb-16
2.5
10.0
ND
10.0
ND
ND
13.1
ND
---
ND
9-Aug-16
2.5
10.0
ND
10.0 J
ND
ND
144
ND
---
ND
13-Feb-17
2.5
10.0
ND
8.3 J
ND
ND
78.7
ND
---
ND
22-Aug-17
2.5
10.0
ND
7.4 J
ND
ND
51.1
ND
---
ND
5-Feb-18
2.5
10.0
ND
8.3 J
ND
ND
172
ND
---
ND
13-Aug-18
2.5
10.0
ND
10.7
ND
ND
97.7
ND
---
ND
4-Feb-19
2.5
5.0
ND
9.9
ND
ND
24.0
ND
---
ND
7-Aug-19
1.1
5.0
ND
11.3
ND
ND
127
ND
ND
ND
12-Feb-20
1.1
5.0
ND
7.5
ND
ND
11.4
ND
1.1 J
ND
27-Aug-20
3.6
5.0
ND
9.7
ND
ND
88.7
ND
ND
ND
11-Feb-21
3.6
5.0
ND
10.8
ND
ND
18.6
ND
3.8 J
ND
Copper
8-Sep-94
---
200
ND
ND
ND
ND
ND
660
---
---
1-Dec-94
---
200
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
200
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
200
ND
ND
ND
ND
ND
ND
---
---
15-Nov-95
---
200
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
200
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
200
ND
ND
32.0
13.0
100
ND
---
---
17-Jun-97
---
200
34.0
350
13.0
37.0
28.0
77.0
---
---
1-Dec-97
---
200
19.0
72.0
14.0
88.0
15.0
34.0
---
---
20-May-98
---
200
12.0
48.0
380
41.0
53.0
28.0
---
---
19-Nov-98
---
200
10.0
ND
410
28.0
53.0
14.0
---
---
21-J u 1-99
---
200
N D
N D
N D
N D
N D
N D
---
---
16-Nov-99
---
200
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
200
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
200
N D
N D
N D
N D
N D
N D
---
---
18-Apr-01
---
200
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
200
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
200
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
200
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
200
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
200
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
200
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
N D
N D
11.3
5.50 J
10.4
1.90 B
---
0.60 J
12-Jul-07
---
10
ND
ND
13.4
7.90
2.6 J
ND
---
ND
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
---
10
2.0 B
ND
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
9.8
8-J u 1-08
---
10
0.64 J
N D
12.1
3.7 J
8.5 J
N D
---
N D
17-Dec-08
0.30
10.0
0.80 J
13.6
10.2
3.9 J
11.9
0.37 J
---
N D
9-Ju1-09
0.30
10.0
ND
ND
6.3 J
ND
5.7 J
ND
8.8 J
ND
16-Dec-09
0.30
10.0
N D
N D
9.2 J
1.6 J
5.7 J
N D
---
N D
24-Jun-10
0.30
10.0
ND
ND
10
1.2 J
5.1 J
ND
---
ND
13-Dec-10
0.30
10.0
1.1 B
N D
13.6
5.8 J
5.6 J
0.59 B
---
0.49 J
20-Jun-11
5.0
10.0
ND
ND
15.3
8.1 J
8.7 J
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
16.9
10.0 J
7.6 J
ND
---
ND
11-Jun-12
5.0
10.0
ND
10.7
12.2
6.3 J
7.4 J
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
11.6
8.5 J
10.4
ND
---
ND
1-May-13
5.0
10.0
ND
ND
13.6
5.8 J
9.6 J
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
14.3
ND
10.2
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
12.2
ND
5.1 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
10.5
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
8.7 J
ND
15.5
ND
---
ND
18-Aug-15
2.5
10.0
N D
N D
6.7 J
5.6 J
10.1
N D
---
N D
NC 2L = 50 pg/L (06/01/2016)
16-Feb-16
2.5
10.0
ND
ND
7.8 J
ND
5.1 J
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
5.4 J
ND
7.8 J
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
6.8 J
4.3 J
14.5
9.4 J
---
ND
22-Aug-17
2.5
10.0
ND
ND
6.5 J
ND
5.7 J
4.4 J
---
ND
5-Feb-18
2.5
10.0
ND
6.5 J
9.0 J
5.5 J
12.4
2.6 J
---
ND
13-Aug-18
2.5
10.0
ND
5.5 J
12.2
3.7 J
48.8
ND
---
ND
4-Feb-19
2.5
5.0
ND
3.0 J
5.4
8.0
4.3 J
ND
---
ND
7-Aug-19
2.1
5.0
ND
3.5 J
6.0
7.2
4.4 J
2.3 J
---
ND
12-Feb-20
2.1
5.0
ND
ND
9.8
12.7
3.3 J
ND
---
ND
27-Aug-20
4.3
5.0
ND
ND
5.3
13.5
5.6
ND
---
ND
11-Feb-21
4.3
5.0
ND
ND
84.8
9.6
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-11R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Lead
8-Sep-94
---
10
ND
13.0
ND
N D
30.0
36.0
---
---
1-Dec-94
---
10
11.0
ND
ND
ND
36.0
ND
---
---
9-Feb-95
---
10
ND
ND
ND
10.0
37.0
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
44.0
ND
---
---
15-N ov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
42.0
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
13.0
ND
---
---
17-J u n-97
---
10
20.0
29.0
ND
ND
13.0
ND
---
---
1-Dec-97
---
10
8.0
14.0
ND
5.0
14.0
ND
---
---
20-May-98
---
10
ND
6.0
ND
6.0
21.0
ND
---
---
19-N ov-98
---
10
5.0
ND
ND
ND
58.0
ND
---
---
21-J u 1-99
---
10
N D
12.0
14.0
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-J u n-02
---
10
11.0
N D
N D
N D
N D
N D
---
---
19-N ov-02
---
10
N D
N D
N D
N D
12.0
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
2.1 J
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 15 pg/L (10/23/07)
19-Dec-07
---
10
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
2.8 J
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
4.6 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
1.6
5.0
ND
2.0 J
ND
ND
ND
ND
---
ND
12-Feb-20
1.6
5.0
1.9 J
2.1 J
2.1 J
2.8 J
3.1 J
2.3 J
---
ND
27-Aug-20
4.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
4.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
Mercury
1-Dec-97
---
0.5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
0.5
N D
N D
N D
N D
N D
N D
---
---
16-Nov-99
---
0.5
N D
0.59
0.65
0.65
0.76
N D
---
---
10-May-00
---
0.5
---
N D
N D
N D
N D
---
---
---
26-Oct-00
---
0.5
---
N D
N D
N D
N D
---
---
---
18-A p r-01
---
0.5
---
N D
N D
N D
N D
---
---
---
13-J u n-02
---
0.5
---
N D
N D
N D
N D
---
---
---
2 7-Jun-03
---
0.5
---
N D
N D
N D
N D
---
---
---
30-Dec-03
---
0.5
---
---
---
---
---
---
---
30-Jun-04
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
---
---
---
---
---
29-Jun-05
---
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
---
---
---
28-Jun-06
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
---
---
---
12-Jul-07
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 1.05 pg/L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-Ju1-08
---
0.2
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
---
---
---
---
---
---
---
9-Jul-09
0.070
0.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
---
---
---
---
NC 2L = 1 pg/L (02/05/10)
24-Jun-10
0.070
0.20
ND
ND
ND
ND
ND
0.098 J
---
ND
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.10
0.20
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.10
0.20
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.10
0.20
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.10
0.20
ND
ND
ND
---
---
---
---
ND
22-Aug-17
0.10
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.10
0.20
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.10
0.20
ND
ND
ND
---
---
---
---
ND
11-Feb-21
0.12
0.20
ND
ND
ND
---
---
---
---
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Nickel
8-Sep-94
---
50
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
50
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
50
ND
72
ND
ND
ND
ND
---
---
2-Mar-95
---
50
ND
100
ND
ND
ND
ND
---
---
15-N ov-95
---
50
ND
61.0
ND
ND
ND
ND
---
---
28-May-96
---
50
ND
85.0
ND
ND
ND
ND
---
---
22-Nov-96
---
50
ND
72.0
ND
ND
ND
ND
---
---
17-Jun-97
---
50
75
98.0
ND
ND
ND
ND
---
---
1-Dec-97
---
50
ND
89.0
ND
ND
ND
ND
---
---
20-May-98
---
50
ND
91.0
ND
ND
ND
ND
---
---
19-N ov-98
---
50
ND
83.0
ND
ND
ND
ND
---
---
21-J u 1-99
---
50
N D
109
N D
N D
N D
N D
---
---
16-Nov-99
---
50
ND
122
ND
ND
ND
ND
---
---
10-May-00
---
50
N D
104
N D
N D
N D
N D
---
---
26-Oct-00
---
50
N D
93.0
N D
N D
N D
N D
---
---
18-A p r-01
---
50
N D
107
N D
N D
N D
N D
---
---
27-Oct-01
---
50
N D
92.0
N D
N D
N D
N D
---
---
13-J u n-02
---
50
N D
98.0
N D
N D
N D
N D
---
---
19-N ov-02
---
50
N D
74.0
N D
N D
N D
N D
---
---
2 7-Jun-03
---
50
N D
85.0
N D
N D
N D
N D
---
---
30-Dec-03
---
50
N D
100
N D
N D
N D
N D
---
N D
30-Jun-04
---
50
ND
120 (81.0)
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
100
ND
ND
ND
ND
---
ND
29-Jun-05
---
50
ND
150
ND
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
96.0
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
88.7
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
N D
94.7
30.1
14.2
8.9 J
N D
---
N D
12-Jul-07
---
50
ND
99.0
30.6 J
13.9 J
13.7 J
ND
---
ND
NC 2L = 100 pg/L (10/23/07)
19-Dec-07
---
50
ND
83.4
23.7
11.0
18.3
ND
11.4
ND
8-Ju1-08
---
50
ND
76.0
28.1 J
11.5 J
27.0 J
ND
---
ND
17-Dec-08
1.7
50.0
ND
75.5
27.8 J
12.2 J
11.0 B
ND
---
2.4 J
9-Ju1-09
1.7
50.0
2.2 J
93.5
29.4 J
11.7 J
23.2 J
ND
13.1 J
ND
16-Dec-09
1.7
50.0
N D
81.2
28.2 J
11.8 B
2.6 B
N D
---
3.0 J
24-Jun-10
1.7
50.0
ND
76.3
19.7 J
9.0 J
7.0 J
4.5 J
---
ND
13-Dec-10
1.7
50.0
N D
83.0
23.5 J
6.8 B
20.7 J
N D
---
2.7 J
20-Jun-11
5.0
50.0
ND
78.8
30.1 J
11.2 J
15.3 J
ND
---
ND
5-Dec-11
5.0
50.0
N D
89.1
32.8 J
11.7 J
24.3 J
N D
---
N D
11-Jun-12
5.0
50.0
ND
91.8
28.9 J
10.0 J
17.3 J
ND
ND
ND
12-Dec-12
5.0
50.0
N D
91.8
29.2 J
9.3 J
21.1 J
N D
---
N D
1-May-13
5.0
50.0
ND
89.6
31.9 J
10.4 J
5.7 J
ND
ND
ND
5-Aug-13
5.0
50.0
ND
87.9
28.1 J
9.0 J
8.4 J
ND
---
ND
24-Feb-14
5.0
50.0
ND
83.1
16.7 J
10.4 J
ND
ND
ND
ND
12-Aug-14
5.0
50.0
ND
97.9
29 J
12.9 J
13.2 J
ND
---
ND
10-Mar-15
2.5
50.0
ND
91.9
32.9 J
12.3 J
8.2 J
ND
---
ND
18-Aug-15
2.5
50.0
N D
98.0
28.0 J
11.9 J
26.2 J
5.4 J
---
N D
16-Feb-16
2.5
50.0
N D
92.0
35.4 J
12.7 J
3.7 J
N D
---
N D
9-Aug-16
2.5
50.0
3.3 J
88.9
29.0 J
12.2 J
30.7 J
N D
---
N D
13-Feb-17
2.5
50.0
N D
89.6
30.4 J
13.5 J
16.2 J
N D
---
N D
22-Aug-17
2.5
50.0
ND
84.2
28.2 J
12.3 J
13.5 J
ND
---
ND
5-Feb-18
2.5
50.0
N D
87.6
29.8 J
11.7 J
28.5 J
N D
---
N D
13-Aug-18
2.5
50.0
ND
88.9
29.0 J
12.3 J
21.9 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
85.7
17.4
10.7
5.5
ND
---
ND
7-Aug-19
0.90
5.0
ND
92.6
27.8
11.7
18.7
ND
---
ND
12-Feb-20
0.90
5.0
1.1 J
89.9
20.5
13.2
3.4 J
N D
---
N D
27-Aug-20
3.50
5.0
ND
99.1
19.5
12.2
18.1
ND
---
ND
11-Feb-21
3.50
5.0
ND
91.8
21.4
13.5
3.9 J
ND
---
ND
Selenium
8-Sep-94
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
20
N D
N D
N D
N D
N D
N D
---
---
9-Feb-95
---
20
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
20
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
20
N D
N D
N D
N D
N D
N D
---
---
28-May-96
---
20
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
20
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
20
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
20
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
20
N D
N D
N D
N D
N D
N D
---
---
21-J u 1-99
---
20
N D
N D
N D
N D
36.0
N D
---
---
16-N ov-99
---
20
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
20
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
20
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
20
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
20
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
20
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
20
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
20
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
20
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
20
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
10
ND
11.5
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.8
10
4.8 B
5.1 B
4.8 B
ND
ND
ND
---
4.9 J
9-Ju1-09
3.8
10
ND
ND
4.2 J
ND
ND
ND
ND
ND
16-Dec-09
3.8
10
ND
ND
ND
5.1 J
ND
ND
---
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
3.8
10
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
5.0
10
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
4.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Silver
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
8.0
ND
ND
ND
3.0
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
15.0
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 17.5 pg/L (10/23/07)
19-Dec-07
---
10
ND
0.57 J
0.60 J
0.55 J
ND
0.33 J
ND
ND
8-J u 1-08
---
10
N D
2.7 J
2.3 J
1.1 J
0.22 J
0.69 J
---
0.12 J
17-Dec-08
0.10
10.0
0.13 J
1.8 J
1.4 J
0.85 J
0.12 J
0.51 J
---
N D
9-J u 1-09
0.10
10.0
N D
0.84 J
0.63 J
0.45 J
N D
0.11 J
N D
N D
16-Dec-09
0.10
10.0
0.12 J
2.0 J
1.6 J
1.0 J
0.12 J
0.52 J
---
N D
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.10
10.0
ND
0.38 J
0.33 J
0.35 J
ND
ND
---
ND
13-Dec-10
0.10
10.0
0.15 B
1.3 J
0.99 J
0.45 B
{ND)
{ND)
---
6.21 {0.19 J J
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
2.5
5.0
ND
ND
ND
ND
ND
ND
---
ND
Thallium
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
ND
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
10
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-J u n-97
---
10
ND
3.0
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
10.0 J
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
22.0
13.0
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
23.0
20.0
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
25.7
12.6
ND
ND
ND
---
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 0.28 pg/L (10/23/07)
19-Dec-07
---
5.5
ND
4.0 J
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
5.5
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
3.0
5.5
ND
3.2 J
3.2 J
ND
ND
ND
---
ND
9-Ju1-09
3.0
5.5
ND
ND
ND
4.1 J
ND
ND
ND
ND
16-Dec-09
3.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
3.0
5.5
ND
ND
5.2 J
3.1 J
ND
ND
---
ND
IMAC = 0.2 pg/L (10/1/10)
13-Dec-10
3.0
5.5
ND
ND
7.7
ND
ND
ND
---
ND
20-Jun-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
18-Aug-15
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
9-Aug-16
5.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.02
5.5
0.023 J
0.040 J
ND
ND
0.035 J
ND
---
ND
22-Aug-17
0.02
5.5
ND
ND
ND
ND
0.033 J
ND
---
ND
5-Feb-18
0.03
0.1
ND
ND
ND
ND
0.047 J
ND
---
ND
13-Aug-18
0.02
5.5
ND
ND
ND
ND
0.037 J
ND
---
ND
4-Feb-19
0.06
0.1
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.060
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.060
0.10
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Tin
1-Dec-97
---
100
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
16-N ov-99
---
100
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
100
---
ND
ND
ND
ND
---
---
---
18-A p r-01
---
100
---
ND
ND
ND
ND
---
---
---
27-Oct-01
---
100
---
---
---
---
---
---
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-Nov-02
---
100
---
---
---
---
---
---
---
---
27-Jun-03
---
100
ND
149
127
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
41.1
14.4
3.2 J
ND
ND
---
ND
12-Jul-07
---
100
ND
35.2 J
13.9 J
5.2 J
ND
ND
---
ND
19-Dec-07
---
100
ND
33.6
7.4
ND
ND
ND
ND
ND
8-J u 1-08
---
100
4.4 J
28.6 J
15.1 J
5.4 J
3.0 J
3.6 J
---
N D
17-Dec-08
1.8
100
ND
22.5 J
9.2 J
ND
ND
ND
---
ND
9-Ju1-09
1.8
100
ND
21.4 J
8.6 J
ND
ND
ND
---
ND
16-Dec-09
1.8
100
ND
26.3 J
10.7 J
ND
ND
ND
---
ND
IMAC = 2100 pg/L (02/05/10)
24-Jun-10
1.8
100
ND
23.4 J
10.7 J
3.2 J
2.2 J
1.9 J
---
ND
13-Dec-10
1.8
100
ND
30.3 J
12.1 J
5.8 J
ND
ND
---
ND
20-Jun-11
5.0
100
ND
26.8 J
13.8 J
ND
ND
ND
---
ND
5-Dec-11
5.0
100
ND
25.8 J
13.9 J
ND
ND
ND
---
ND
11-Jun-12
5.0
100
ND
22.2 J
9.0 J
ND
ND
ND
ND
ND
12-Dec-12
5.0
100
ND
30.0 J
13.2 J
ND
ND
ND
---
ND
1-May-13
5.0
100
ND
25.8 J
12.2 J
ND
ND
ND
---
ND
5-Aug-13
5.0
100
ND
22.7 J
12.5 J
ND
ND
ND
---
ND
24-Feb-14
5.0
100
ND
26.7 J
11.7 J
9.8 J
ND
ND
ND
ND
12-Aug-14
5.0
100
ND
30.7 J
8.2 J
ND
ND
ND
---
ND
10-Mar-15
2.5
100
ND
28.7 J
11.1 J
ND
ND
ND
---
ND
18-Aug-15
2.5
100
ND
27.7 J
7.5 J
ND
ND
ND
---
ND
16-Feb-16
2.5
100
ND
28.6 J
10.4 J
---
---
---
---
ND
9-Aug-16
2.5
100
ND
20.9 J
5.4 J
---
---
---
---
ND
13-Feb-17
2.5
100
ND
25.5 B
7.8 B
---
---
---
---
3.6 J,
22-Aug-17
2.5
100
ND
17.2 J
5.3 J
---
---
---
---
ND
5-Feb-18
2.5
100
ND
20.3 J
9.5 J
---
---
---
---
ND
13-Aug-18
2.5
100
ND
22.2 J
7.4 J
---
---
ND
---
ND
4-Feb-19
2.5
5.0
ND
24.8
5.5
---
---
---
---
ND
7-Aug-19
1.6
5.0
ND
29.3
9.7
---
---
---
---
ND
12-Feb-20
1.6
5.0
ND
26.0
5.8
---
---
---
---
ND
27-Aug-20
4.7
5.0
ND
27.6
5.1
---
---
---
---
ND
11-Feb-21
4.7
5.0
ND
30.1
8.0
---
---
---
---
---
Vanadium
8-Sep-94
---
40
ND
ND
ND
ND
ND
130
---
---
1-Dec-94
---
40
63.0
ND
ND
45.0
ND
ND
---
---
9-Feb-95
---
40
ND
ND
ND
ND
ND
ND
---
---
2-M a r-95
---
40
41.0
ND
ND
45.0
ND
ND
---
---
15-N ov-95
---
40
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
40
83.0
ND
ND
ND
ND
ND
---
---
22-N ov-96
---
40
7.0
17
ND
21.0
ND
ND
---
---
17-J u n-97
---
40
450
560
ND
19.0
ND
ND
---
---
1-Dec-97
---
40
62.0
88.0
ND
41.0
ND
10.0
---
---
20-May-98
---
40
25.0
15.0
ND
10.0
5.0
ND
---
---
19-Nov-98
---
40
33.0
29.0
5.0
16.0
9.0
5.0
---
---
21-J u 1-99
---
40
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
40
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
40
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
40
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
40
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
40
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
40
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
40
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
40
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
40
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
40
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
25
2.7 J
N D
N D
14.5
N D
1.0 J
---
N D
12-Jul-07
---
25
ND
ND
ND
19.4 J
ND
ND
---
ND
IMAC = 3.5 pg/L (10/23/07)
19-Dec-07
---
25
2.2 B
2.2 B
ND
15.7 J
3.0 B
1.2 B
4.0 J
0.62 J
8-J u 1-08
---
25
2.6 J
2.4 J
N D
14.6 J
1.4 J
1.2 J
---
0.20 J
17-Dec-08
0.20
25.0
1.9 B
2.3 B
N D
13.9 J
2.5 B
1.2 B
---
0.76 J
9-Jul-09
0.20
25.0
3.9 B
9.7 J
2.5 B
18.4 J
2.9 B
2.2 B
8.5 J
1.30 J
16-Dec-09
0.20
25.0
2.0 B
4.4 J
1.3 B
14.0 J
2.2 B
1.5 B
---
0.53 J
24-Jun-10
0.20
25.0
1.8 J
4.4 J
1.5 J
13.3 J
2.2 J
1.3 J
---
ND
IMAC = 0.3 pg/L (10/1/10)
13-Dec-10
0.20
25.0
3.2 J
3.6 J
0.35 B
16.6 J
1.8 B
1.0 B
---
0.36 J
20-Jun-11
5.0
25.0
ND
ND
ND
14.5 J
ND
ND
---
ND
5-Dec-11
5.0
25.0
ND
ND
ND
13.5 J
ND
ND
---
ND
11-Jun-12
5.0
25.0
ND
18.0 J
ND
12.3 J
ND
ND
ND
ND
12-Dec-12
5.0
25.0
ND
ND
ND
13.6 J
ND
ND
---
ND
1-May-13
5.0
25.0
ND
ND
ND
6.3 J
ND
ND
ND
ND
5-Aug-13
5.0
25.0
ND
ND
ND
10.2 J
ND
ND
---
ND
24-Feb-14
5.0
25.0
ND
ND
ND
12.9 J
ND
ND
ND
ND
12-Aug-14
5.0
25.0
ND
ND
ND
18.6 J
ND
ND
---
ND
10-Mar-15
2.5
25.0
3.1 J
11.6 J
6.2 J
13.4 J
ND
ND
---
ND
18-Aug-15
2.5
25.0
3.4 J
6.8 J
3.6 J
19.6 J
2.8 J
ND
---
ND
16-Feb-16
2.5
25.0
2.7 J
3.3 J
ND
14.4 J
ND
ND
---
ND
9-Aug-16
2.5
25.0
2.5 J
3.5 J
ND
21.2 J
ND
ND
---
ND
13-Feb-17
2.5
25.0
4.4 J
4.1 J
ND
18.4 J
3.0 J
2.9 J
---
ND
22-Aug-17
2.5
25.0
ND
6.6 J
ND
20.6 J
2.6 J
ND
---
ND
5-Feb-18
2.5
25.0
3.6 J
4.4 J
ND
17.6 J
ND
2.5 J
---
ND
13-Aug-18
2.5
25.0
ND
5.3 J
ND
20.4 J
2.9 J
ND
---
ND
4-Feb-19
2.5
5.0
ND
3.5 J
ND
12.0
ND
ND
---
ND
7-Aug-19
1.3
5.0
2.6 J
4.1 J
1.9 J
22.1
1.7 J
2.4 J
---
ND
12-Feb-20
1.3
5.0
ND
ND
ND
17.0
ND
1.4 J
---
ND
27-Aug-20
3.9
5.0
ND
ND
ND
21.1
ND
ND
6.8
ND
11-Feb-21
3.9
5.0
ND
ND
ND
13.4
ND
ND
7.2
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Zinc
8-Sep-94
---
50
110
160
ND
ND
320
430
---
---
1-Dec-94
---
50
132
ND
ND
70
164
ND
---
---
9-Feb-95
---
50
144
89
ND
91
79
74
---
---
2-Mar-95
---
50
67
ND
ND
ND
111
ND
---
---
15-Nov-95
---
50
ND
50
ND
ND
ND
ND
---
---
28-May-96
---
50
136
ND
ND
ND
122
ND
---
---
22-Nov-96
---
50
79.0
48.0
28.0
ND
38.0
ND
---
---
17-Jun-97
---
50
370
410
33.0
39.0
36.0
69.0
---
---
1-Dec-97
---
50
140
110
11.0
45.0
34.0
30.0
---
---
20-May-98
---
50
70.0
63.0
23.0
31.0
47.0
34.0
---
---
19-Nov-98
---
50
61.0
33.0
21.0
17.0
53.0
10.0
---
---
21-J u 1-99
---
50
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
50
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
50
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
50
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
50
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
50
N D
N D
N D
N D
N D
N D
---
---
13-J u n-02
---
50
N D
N D
N D
N D
382
N D
---
---
19-N ov-02
---
50
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
50
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
50
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
50
ND
ND
ND
66.0
ND
ND
---
ND
29-Jun-05
---
50
ND
54.0
56.0
ND
ND
ND
---
ND
29-Dec-05
---
50
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
50
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
50
8.0 J
N D
N D
4.1 J
4.3 J
4.1 J
---
N D
12-Jul-07
---
10
9.6 J
ND
ND
ND
ND
ND
---
ND
NC 2L = 1,050 pg/L (10/23/07)
19-Dec-07
---
10
4.3 B
14.3 B
6.3 B
ND
ND
ND
2.4 B
102
8-J u 1-08
---
10
5.9 B
N D
N D
N D
4.1 B
N D
---
1.2 J
17-Dec-08
0.40
10.0
2.4 B
6.3 J
ND
ND
4.6 J
0.60 B
---
0.49 J
9-Ju1-09
0.40
10.0
3.4 B
ND
ND
ND
ND
ND
6.1 B
1.6 J
16-Dec-09
0.40
10.0
4.6 B
ND
ND
ND
7.4 B
ND
---
7.7 J
NC 2L = 1,000 pg/L (02/05/10)
24-Jun-10
0.40
10.0
0.58 J
ND
ND
ND
ND
1.3 J
---
ND
13-Dec-10
0.40
10.0
4.5 B
ND
ND
ND
ND
ND
---
6.7 J
20-Jun-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
10.0
10.0
ND
ND
ND
ND
ND
ND
---
12.4
11-Jun-12
10.0
10.0
ND
20.9
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10.0
ND
ND
ND
ND
11.8
ND
10.0
ND
5-Aug-13
10.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10.0
ND
ND
ND
ND
16.9
ND
---
ND
18-Aug-15
5.0
10.0
7.4 J
ND
ND
ND
5.2 J
ND
---
ND
16-Feb-16
5.0
10.0
14.5
16.7
17.8
46.1
5.9 J
ND
---
ND
9-Aug-16
5.0
10.0
12.0
7.7 J
ND
ND
ND
ND
---
ND
13-Feb-17
5.0
10.0
12.3
ND
ND
ND
9.8 J
6.0 J
---
ND
22-Aug-17
5.0
10.0
ND
6.3 J
ND
ND
ND
ND
---
ND
5-Feb-18
5.0
10.0
6.7 J
17.9
ND
ND
ND
ND
---
ND
13-Aug-18
5.0
10.0
ND
ND
ND
ND
8.1 J
ND
---
ND
4-Feb-19
5.0
10.0
6.8 J
ND
5.0 J
ND
ND
ND
---
ND
7-Aug-19
3.9
10.0
8.3 J
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.9
10.0
4.3 J
ND
ND
ND
4.5 J
ND
---
ND
27-Aug-20
9.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
9.5
10.0
12.9
ND
ND
ND
ND
ND
---
ND
Cyanide
9-Ju1-09
5.0
10
ND
ND
ND
ND
46.9
ND
ND
ND
Resample >
28-Sep-09
5.0
10
---
---
---
---
ND
---
---
ND
NC 2L = 70 pg/L (10/23/07)
16-Dec-09
---
---
---
---
---
---
---
---
---
---
24-Jun-10
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
---
---
Resample >
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
5.0
10.0
ND
6.4 J
ND
ND
8.7 J
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5.5 J
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
5.0
10.0
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
---
5.6 J
16-Feb-16
4.0
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
4.0
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
4.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
4.0
10.0
ND
ND
ND
---
---
---
---
ND
4-Feb-19
6.0
8.0
ND
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 9 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
ORGANICS
Acetone
27-Oct-01
---
100
244 B
109 B
ND
130 B
128 B
476 B
---
479
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
4.5 J
8-Ju1-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
20.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
20.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.2
100
ND
ND
ND
ND
ND
ND
---
2.8 J
NC 2L = 6,000 pg/L (02/05/10)
24-Jun-10
2.2
100
ND
18.5 B
6.5 B
ND
2.2 B
ND
---
7.7 J
13-Dec-10
2.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
2.2
100
ND
ND
ND
ND
ND
2.4 B
---
3.9 J
5-Dec-11
2.2
100
ND
2.3 B
ND
ND
ND
ND
---
8.8 J
11-Jun-12
2.2
100
ND
3.5 B
ND
ND
ND
ND
ND
4.7 J
12-Dec-12
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
100
ND
ND
ND
ND
ND
ND
ND
14.6 J
5-Aug-13
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
25.7 J
12-Aug-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
22.0 J
10-Mar-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
6.2
25
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
6.2
25.0
ND
ND
ND
ND
ND
ND
---
ND
Benzene
8-Sep-94
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
ND
ND
ND
ND
---
---
9-Feb-95
---
5
ND
ND
ND
ND
ND
ND
---
---
2-M a r-95
---
5
ND
ND
ND
ND
ND
ND
---
---
15-N ov-95
---
5
ND
ND
ND
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
5
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
5
ND
ND
ND
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
5
ND
ND
ND
ND
ND
ND
---
---
16-N ov-99
---
5
ND
ND
ND
ND
ND
ND
---
---
10-May-00
---
5
ND
ND
ND
ND
ND
ND
---
---
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
---
18-A p r-01
---
5
ND
ND
ND
ND
ND
ND
---
---
2 7-Oct-01
---
5
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
1.5
ND
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
1.2
---
---
---
---
---
ND
12-Jul-07
---
1
ND
1.9
ND
ND
ND
ND
---
ND
NC 2L = 1 pg/L (10/23/07)
19-Dec-07
---
1
ND
1.8
0.48 J
0.26 J
ND
ND
ND
ND
8-J u 1-08
---
1
ND
1.4
0.51 J
0.32 J
ND
ND
---
ND
17-Dec-08
0.25
1.0
ND
1.7
0.54 J
ND
ND
ND
---
ND
9-Jul-09
0.25
1.0
ND
1.7
0.34 J
ND
ND
ND
ND
ND
16-Dec-09
0.25
1.0
ND
1.7
0.60 J
0.29 J
ND
ND
---
ND
24-Jun-10
0.25
1.0
ND
0.77 J
0.49 J
0.33 J
ND
ND
---
ND
13-Dec-10
0.25
1.0
ND
1.8
0.59 J
0.37 J
ND
ND
---
ND
Resample >
8-Feb-11
0.25
1.0
---
1.4
---
---
---
---
---
ND
20-Jun-11
0.25
1.0
ND
1.7
0.60 J
0.39 J
ND
ND
---
ND
5-Dec-11
0.25
1.0
ND
1.4
0.69 J
0.40 J
ND
ND
---
ND
11-Jun-12
0.25
1.0
ND
ND
0.51 J
ND
ND
ND
ND
ND
12-Dec-12
0.25
1.0
ND
1.6
0.73 J
0.32 J
ND
ND
---
ND
Resample >
10-Jan-13
0.25
1.0
ND
1.4
---
---
---
---
ND
ND
1-May-13
0.25
1.0
ND
1.3
0.56 J
0.27 J
ND
ND
ND
ND
5-Aug-13
0.25
1.0
ND
1.6
0.64 J
0.44 J
ND
ND
---
ND
24-Feb-14
0.25
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
12-Aug-14
0.25
1.0
ND
1.7
0.61 J
0.25 J
ND
ND
ND
ND
10-Mar-15
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
18-Aug-15
0.25
1.0
ND
1.5
0.66 J
0.32 J
ND
ND
---
ND
16-Feb-16
0.25
1.0
ND
1.3
0.56 J
ND
ND
ND
ND
ND
9-Aug-16
0.25
1.0
ND
1.4
0.53 J
0.29 J
ND
ND
ND
ND
13-Feb-17
0.25
1.0
ND
1.2
0.61 J
ND
ND
ND
ND
ND
22-Aug-17
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
5-Feb-18
0.25
1.0
ND
1.2
0.67 J
ND
ND
ND
ND
ND
13-Aug-18
0.25
1.0
ND
1.3
0.61 J
0.29 J
ND
ND
ND
ND
4-Feb-19
0.15
1.0
ND
1.6
ND
ND
ND
ND
ND
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.15
1.0
ND
1.7
0.54 J
0.30 J
ND
ND
ND
ND
12-Feb-20
0.15
1.0
ND
1.5
ND
ND
ND
ND
ND
ND
27-Aug-20
0.15
1.0
ND
1.9
0.49 J
ND
ND
ND
ND
ND
11-Feb-21
0.15
1.0
ND
1.8
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 10 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Bromomethane
17-Dec-08
0.29
10.0
ND
ND
0.58 J
ND
ND
ND
---
ND
9-Ju1-09
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 10 pg/L (8/1/10)
13-Dec-10
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.62
2.0
N D
N D
N D
ND
N D
N D
---
N D
12-Feb-20
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.62
2.0
ND
ND
ND
ND
ND
ND
---
ND
2-Butanone (MEK)
17-Dec-08
0.96
100
ND
ND
ND
ND
1.2 J
ND
---
ND
NC 2L = 4,200 pg/L (10/23/07)
9-Ju1-09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 4,000 pg/L (02/05/10)
24-Jun-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
8-May-13
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
3.30
5
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
3.3
5.0
ND
ND
ND
ND
ND
ND
---
ND
Carbon Disulfide
17-Jun-97
---
100
ND
64.0
ND
ND
ND
ND
---
---
1-Dec-97
---
100
ND
5.0
8.0
ND
ND
ND
---
---
20-May-98
---
100
ND
7.5
6.2
ND
ND
ND
---
---
19-N ov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
100
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
100
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
100
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
100
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
100
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
100
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
100
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.4
2
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.40
2.0
N D
N D
N D
N D
N D
N D
---
N D
12-Feb-20
0.40
2.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.40
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.40
2.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 11 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chlorobenzene
8-Sep-94
---
5
ND
10.0
7.0
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
7.0
ND
ND
ND
---
---
9-Feb-95
---
5
ND
13.0
8.0
6.0
ND
ND
---
---
2-Mar-95
---
5
ND
12.0
9.0
ND
ND
ND
---
---
15-N ov-95
---
5
ND
14.0
8.0
9.0
ND
ND
---
---
28-May-96
---
5
ND
15.0
9.0
10.0
ND
ND
---
---
22-N ov-96
---
5
ND
15.0
ND
11.0
ND
ND
---
---
17-J u n-97
---
5
ND
19.0
11.0
14.0
ND
ND
---
---
1-Dec-97
---
5
ND
17.0
9.0
14.0
ND
ND
---
---
20-May-98
---
5
ND
20.0
8.6
12.0
ND
ND
---
---
19-N ov-98
---
5
ND
17.2
9.2
10.0
ND
ND
---
---
21-J u 1-99
---
5
N D
14.0
10.0
11.0
N D
N D
---
---
16-N ov-99
---
5
N D
16.0
10.0
8.0
N D
N D
---
---
10-May-00
---
5
N D
17.0
11.0
10.0
N D
N D
---
---
26-Oct-00
---
5
N D
16.0
12.0
9.0
N D
N D
---
---
18-A p r-01
---
5
N D
16.0
13.0
6.0
N D
N D
---
---
27-Oct-01
---
0.5
N D
17.0
12.0
9.0
N D
N D
---
---
13-J u n-02
---
0.5
N D
16.0
11.0
8.0
N D
N D
---
---
19-N ov-02
---
0.5
N D
18.0
15.0
9.0
N D
N D
---
---
27-Jun-03
---
0.5
ND
17.7
13.3
7.4
ND
ND
---
ND
30-Dec-03
---
5
N D
20.0
15.0
6.1
N D
N D
---
N D
30-Jun-04
---
5
ND
18.0
15.0
9.9
ND
ND
---
ND
29-Dec-04
---
5
ND
19.0
16.0
9.4
ND
ND
---
ND
29-Jun-05
---
5
ND
15.0
13.0
8.0
ND
ND
---
ND
29-Dec-05
---
5
ND
18.0
16.0
5.0
ND
ND
---
ND
28-Jun-06
---
5
ND
16.5
10.8
7.8
ND
ND
---
ND
29-Dec-06
---
3
N D
17.0
17.0
4.2
N D
N D
---
N D
12-Jul-07
---
3
ND
17.0
16.0
ND
ND
ND
---
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
---
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
8-J u 1-08
---
3
N D
17.2
17.4
6.5
N D
N D
---
N D
17-Dec-08
0.23
3.0
N D
15.9
15.6
2.6 J
N D
N D
---
N D
9-Ju1-09
0.23
3.0
ND
16.1
17.2
6.1
ND
ND
ND
ND
16-Dec-09
0.23
3.0
ND
15.5
17.7
4.8
ND
ND
---
ND
24-Jun-10
0.23
3.0
ND
8.3
15.7
6.3
ND
ND
---
ND
13-Dec-10
0.23
3.0
N D
17.7
18.2
6.4
N D
N D
---
0.28 J
20-Jun-11
0.23
3.0
ND
16.3
17.2
6.7
ND
ND
---
ND
5-Dec-11
0.23
3.0
ND
14.2
17.0
5.8
ND
ND
---
ND
11-Jun-12
0.23
3.0
ND
12.0
14.8
4.4
ND
ND
ND
ND
12-Dec-12
0.23
3.0
ND
15.8
17.9
4.5
ND
ND
---
ND
1-May-13
0.23
3.0
ND
14.0
16.6
3.0 J
ND
ND
ND
ND
5-Aug-13
0.23
3.0
ND
14.4
15.9
4.6
ND
ND
---
ND
24-Feb-14
0.23
3.0
ND
16.3
2.5 J
1.4 J
ND
ND
ND
ND
12-Aug-14
0.23
3.0
ND
15.6
18.3
3.6
ND
ND
ND
ND
10-Mar-15
0.23
3.0
ND
16.0
17.0
2.1 J
ND
ND
ND
ND
18-Aug-15
0.23
3.0
ND
12.8
17.6
4.3
ND
ND
---
ND
16-Feb-16
0.23
3.0
ND
13.5
16.4
1.5 J
ND
ND
ND
ND
9-Aug-16
0.23
3.0
ND
13.5
16.9
4.2
ND
ND
---
ND
13-Feb-17
0.23
3.0
ND
13.6
18.0
1.3 J
ND
ND
---
ND
22-Aug-17
0.23
3.0
ND
14.2
19.9
4.2
ND
ND
---
ND
5-Feb-18
0.23
3.0
ND
13.5
17.3
0.54 J
ND
ND
---
ND
13-Aug-18
0.23
3.0
ND
14.5
22.2
3.4
ND
ND
---
ND
4-Feb-19
0.23
1.0
ND
13.6
0.35 J
1.3
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.23
1.0
N D
10.2
16.9
N D
N D
N D
---
N D
12-Feb-20
0.23
1.0
ND
ND
ND
2.0
ND
ND
---
ND
27-Aug-20
0.23
1.0
ND
16.1
17.5
4.1
0.32 J
ND
---
ND
11-Feb-21
0.23
1.0
ND
15.1
7.3
2.2
ND
ND
---
ND
Chloroethane
1-Dec-97
---
10
ND
5.0
2.0
2.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
10
N D
N D
N D
N D
N D
N D
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
10
ND
2.2
1.9
ND
ND
ND
---
ND
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2,800 pg/L (10/23/07)
19-Dec-07
---
10
ND
1.9
1.9
1.5
ND
ND
ND
ND
8-J u 1-08
---
10
N D
2.2 J
2.5 J
1.8 J
N D
N D
---
N D
17-Dec-08
0.54
10.0
N D
1.6 J
N D
N D
N D
N D
---
N D
9-Jul-09
0.54
10.0
ND
ND
ND
3.8 J
ND
ND
ND
ND
16-Dec-09
0.54
10.0
ND
ND
2.2 J
2.0 J
ND
ND
---
ND
NC 2L = 3,000 pg/L (02/05/10)
24-Jun-10
0.54
10.0
ND
ND
2.1 J
2.0 J
ND
ND
---
ND
13-Dec-10
0.54
10.0
ND
1.8 J
2.0 J
1.7 J
ND
ND
---
ND
20-Jun-11
0.54
10.0
ND
1.2 J
2.2 J
2.0 J
ND
ND
---
ND
5-Dec-11
0.54
10.0
ND
1.3 J
2.0 J
1.7 J
ND
ND
---
ND
11-Jun-12
0.54
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.54
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.54
10.0
ND
ND
1.9 J
2.7 J
ND
ND
ND
ND
5-Aug-13
0.54
10.0
ND
ND
2.0 J
2.2 J
ND
ND
---
ND
24-Feb-14
0.54
10.0
ND
1.1 J
0.82 J
ND
ND
ND
ND
ND
12-Aug-14
0.54
10.0
ND
1.1 J
1.50 J
1.1 J
ND
ND
ND
ND
10-Mar-15
0.54
10.0
ND
1.0 J
1.80 J
0.81 J
ND
ND
ND
ND
18-Aug-15
0.54
10.0
ND
1.2 J
2.0 J
3.7 J
ND
ND
---
ND
16-Feb-16
0.54
10.0
ND
1.1 J
1.8 J
0.79 J
ND
ND
ND
ND
9-Aug-16
0.54
10.0
ND
0.68 J
2.4 J
1.5 J
ND
ND
---
ND
13-Feb-17
0.54
10.0
ND
0.76 J
1.6 J
1.1 J
ND
ND
---
ND
22-Aug-17
0.54
10.0
ND
1.3 J
2.0 J
1.6 J
ND
ND
---
ND
5-Feb-18
0.54
10.0
ND
1.7 J
1.7 J
0.68 J
ND
ND
---
ND
13-Aug-18
0.54
10.0
ND
1.2 J
2.4 J
1.40 J
ND
ND
---
ND
4-Feb-19
0.49
1.0
ND
1.3
ND
0.79 J
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.49
1.0
ND
0.94 J
1.9
1.3
ND
ND
---
ND
12-Feb-20
0.49
1.0
ND
1.6
1.3
1.5
ND
ND
---
ND
27-Aug-20
0.49
1.0
ND
0.87 J
1.5
1.1
ND
ND
---
ND
11-Feb-21
0.49
1.0
ND
1.2
1.0 I,v
1.3 v1
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 12 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chloromethane
9-Jul-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2.6 pg/L (10/23/07)
16-Dec-09
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.11
1.0
ND
ND
ND
ND
ND
0.11 J
---
ND
NC 2L = 3 pg/L (02/05/10)
13-Dec-10
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
0.25 J
12-Aug-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.11
1.0
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
---
0.18 J
22-Aug-17
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichlorobenzene
1-Dec-97
---
5
ND
3.0
2.0
1.0
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
5
ND
2.4
2.3
ND
ND
ND
---
---
21-J u 1-99
---
5
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
5
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
5
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
5
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
5
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
5
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
5
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
1.5
2.3
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
1.4 J
1.7 J
0.31 J
ND
ND
---
ND
NC 2L = 24 pg/L (10/23/07)
19-Dec-07
---
5
ND
1.6
2.0
0.37 J
ND
ND
ND
ND
8-J u 1-08
---
5
N D
1.6 J
2.0 J
0.39 J
N D
N D
---
N D
17-Dec-08
0.30
5.0
ND
1.4 J
1.9 J
ND
ND
ND
---
ND
9-Jul-09
0.30
5.0
ND
1.6 J
2.0 J
0.36 J
ND
ND
ND
ND
16-Dec-09
0.30
5.0
N D
1.6 J
2.0 J
0.33 J
N D
N D
---
N D
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.30
5.0
ND
0.96 J
1.7 J
0.31 J
ND
ND
---
ND
13-Dec-10
0.30
5.0
ND
1.9 J
1.9 J
0.43 J
ND
ND
---
ND
20-Jun-11
0.30
5.0
ND
1.5 J
1.7 J
0.37 J
ND
ND
---
ND
5-Dec-11
0.30
5.0
ND
1.3 J
1.6 J
ND
ND
ND
---
ND
11-Jun-12
0.30
5.0
ND
1.0 J
1.5 J
ND
ND
ND
ND
ND
12-Dec-12
0.30
5.0
ND
1.3 J
1.7 J
ND
ND
ND
---
ND
1-May-13
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
ND
ND
5-Aug-13
0.30
5.0
ND
1.2 J
1.6 J
0.30 J
ND
ND
---
ND
24-Feb-14
0.30
5.0
ND
1.4 J
0.64 J
ND
ND
ND
ND
ND
12-Aug-14
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
ND
ND
10-Mar-15
0.30
5.0
ND
1.1 J
1.1 J
ND
ND
ND
ND
ND
18-Aug-15
0.30
5.0
ND
0.88 J
1.3 J
ND
ND
ND
---
ND
16-Feb-16
0.30
5.0
ND
1.1 J
1.4 J
ND
ND
ND
ND
ND
9-Aug-16
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
13-Feb-17
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
---
ND
22-Aug-17
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
---
ND
5-Feb-18
0.30
5.0
ND
1.0 J
1.4 J
ND
ND
ND
---
ND
13-Aug-18
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
---
ND
4-Feb-19
0.29
1.0
ND
1.0 J
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.29
1.0
ND
0.62 J
1.2
ND
ND
ND
---
ND
12-Feb-20
0.29
1.0
ND
0.82 J
0.71 J
ND
ND
ND
---
ND
27-Aug-20
0.29
1.0
ND
1.20
1.3
ND
ND
ND
---
ND
11-Feb-21
0.29
1.0
ND
1.10
0.83 J
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 13 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,4-Dichlorobenzene
8-Sep-94
---
5
ND
ND
5.0
ND
ND
ND
---
---
1-Dec-94
---
5
ND
ND
5.0
ND
ND
ND
---
---
9-Feb-95
---
5
ND
8.0
6.0
ND
ND
ND
---
---
2-Mar-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
15-N ov-95
---
5
ND
7.0
6.0
ND
ND
ND
---
---
28-May-96
---
5
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
---
17-J u n-97
---
5
ND
7.6
6.2
ND
ND
ND
---
---
1-Dec-97
---
5
ND
6.0
5.0
4.0
ND
ND
---
---
20-May-98
---
5
ND
7.6
ND
ND
ND
ND
---
---
19-N ov-98
---
5
ND
3.7
2.8
ND
ND
ND
---
---
21-J u 1-99
---
5
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
5
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
5
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
5
N D
5.0
6.0
N D
N D
N D
---
---
18-A p r-01
---
5
N D
N D
5.0
6.0
N D
N D
---
---
2 7-Oct-01
---
5
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
5
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
3
ND
3.0
3.3
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
3
---
3.2
3.3
---
---
---
---
ND
12-Jul-07
---
1
ND
3.3
2.9
0.31 J
ND
ND
---
ND
NC 2L = 1.4 pg/L (10/23/07)
19-Dec-07
---
1
ND
3.0
2.7
ND
ND
ND
ND
ND
8-Ju1-08
---
1
ND
3.0
2.4
ND
ND
ND
---
ND
17-Dec-08
0.33
1.0
N D
2.9
2.5
N D
N D
N D
---
N D
9-Ju1-09
0.33
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.33
1.0
ND
2.8
2.2
ND
ND
ND
---
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.33
1.0
ND
1.6
ND
ND
ND
ND
---
ND
13-Dec-10
0.33
1.0
ND
3.1
1.9
ND
ND
ND
---
ND
20-Jun-11
0.33
1.0
ND
2.7
1.6
ND
ND
ND
---
ND
5-Dec-11
0.33
1.0
ND
2.2
1.4
ND
ND
ND
---
ND
11-Jun-12
0.33
1.0
ND
1.8
1.4
ND
ND
ND
ND
ND
12-Dec-12
0.33
1.0
ND
2.4
1.3
ND
ND
ND
---
ND
1-May-13
0.33
1.0
ND
2.1
1.2
ND
ND
ND
ND
ND
5-Aug-13
0.33
1.0
ND
2.0
1.3
ND
ND
ND
---
ND
24-Feb-14
0.33
1.0
ND
2.2
1.8
ND
ND
ND
ND
ND
12-Aug-14
0.33
1.0
ND
2.4
1.3
ND
ND
ND
ND
ND
10-Mar-15
0.33
1.0
ND
2.2
1.1
ND
ND
ND
ND
ND
18-Aug-15
0.33
1.0
ND
1.5
1.1
ND
ND
ND
---
ND
16-Feb-16
0.33
1.0
ND
2.0
1.0
ND
ND
ND
ND
ND
9-Aug-16
0.33
1.0
ND
1.9
1.0
ND
ND
ND
---
ND
13-Feb-17
0.33
1.0
ND
1.9
0.90 J
ND
ND
ND
---
ND
22-Aug-17
0.33
1.0
ND
1.9
0.96 J
ND
ND
ND
---
ND
5-Feb-18
0.33
1.0
ND
1.6
1.1
ND
ND
ND
---
ND
13-Aug-18
0.33
1.0
ND
1.9
1.1
ND
ND
ND
---
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.26
1.0
ND
2.1
1.4
ND
ND
ND
---
ND
11-Feb-21
0.26
1.0
ND
1.9
0.8 J
ND
ND
ND
---
ND
Trans-1,4-Dichloro-2-Butene
20-May-98
---
100
ND
ND
5.1
ND
ND
ND
---
---
19-N ov-98
---
100
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
100
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
100
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
100
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
100
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
100
N D
N D
N D
N D
N D
N D
---
---
27-Oct-01
---
100
N D
N D
N D
N D
N D
N D
---
---
19-N ov-02
---
100
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
100
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = NE pg/L
19-Dec-07
---
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.5
1
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.54
1.0
N D
N D
N D
N D
N D
N D
---
N D
12-Feb-20
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,4-Dioxane (p-Dioxane)
13-Aug-18
1.9
10
ND
88.0
53.1
40.7
2.0 J
ND
---
ND
NC 2L = 3 pg/L (2017)
4-Feb-19
1.9
2
ND
132
49.6
49.8
ND
ND
ND
ND
14-Aug-19 for MW-6 >
7-Aug-19
1.2
2.0
ND
98.1
51.7
32.7
3.1
ND
---
ND
12-Feb-20
1.2
2.0
ND
98.2
44.4
36.0
ND
ND
---
ND
27-Aug-20
1.2
2.0
ND
113
50.0
39.3
3.0
ND
ND
ND
11-Feb-21
1.2
2.0
ND
118
53.1
40.6
1.8 J
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 14 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,1-Dichloroethane
1-Dec-97
---
5
ND
ND
1.0
ND
ND
ND
---
---
20-May-98
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
5
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
5
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
5
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
5
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
5
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
5
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
5
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
5
ND
ND
0.36 J
0.52 J
ND
ND
---
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
---
5
ND
ND
ND
0.57 J
ND
ND
ND
ND
8-Ju1-08
---
5
ND
ND
ND
0.60 J
ND
ND
---
ND
17-Dec-08
0.32
5.0
ND
ND
ND
0.51 J
ND
ND
---
ND
9-Ju1-09
0.32
5.0
ND
ND
ND
0.84 J
ND
ND
ND
ND
16-Dec-09
0.32
5.0
ND
ND
ND
0.73 J
ND
ND
---
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
13-Dec-10
0.32
5.0
ND
ND
ND
0.60 J
ND
ND
---
ND
20-Jun-11
0.32
5.0
ND
ND
ND
0.63 J
ND
ND
---
ND
5-Dec-11
0.32
5.0
ND
ND
ND
0.67 J
ND
ND
---
ND
11-Jun-12
0.32
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.32
5.0
ND
ND
ND
0.61 J
ND
ND
---
ND
1-May-13
0.32
5.0
ND
ND
ND
0.62 J
ND
ND
ND
ND
8-May-13
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
24-Feb-14
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
12-Aug-14
0.32
5.0
ND
ND
ND
0.47 J
ND
ND
ND
ND
10-Mar-15
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
18-Aug-15
0.32
5.0
ND
ND
ND
0.49 J
ND
ND
---
ND
16-Feb-16
0.32
5.0
ND
ND
ND
0.45 J
ND
ND
ND
ND
9-Aug-16
0.32
5.0
ND
ND
ND
0.34 J
ND
ND
---
ND
13-Feb-17
0.32
5.0
ND
ND
ND
0.33 J
ND
ND
---
ND
22-Aug-17
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
---
ND
5-Feb-18
0.32
5.0
ND
ND
ND
0.38 J
ND
ND
---
ND
13-Aug-18
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
---
ND
4-Feb-19
0.27
1.0
ND
ND
ND
0.36 J
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.27
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.27
1.0
ND
ND
ND
0.33 J
ND
ND
---
ND
27-Aug-20
0.27
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.27
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichloroethane
17-Dec-08
0.12
1.0
ND
ND
0.15 J
ND
ND
ND
---
ND
NC 2L = 0.38 pg/L (10/23/07)
9-Jul-09
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
0.19 J
16-Dec-09
0.12
1.0
ND
ND
0.14 J
ND
ND
ND
---
ND
NC 2L = 0.4 pg/L (02/05/10)
24-Jun-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.12
1.0
ND
ND
ND
ND
0.18 J
ND
---
ND
11-Jun-12
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.12
1.0
ND
ND
ND
ND
-0.20 J
ND
---
0.20 (ND) J
1-May-13
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.24
1.0
ND
ND
0.33 J
0.29 J
0.36 J
ND
---
---
16-Feb-16
0.24
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.24
1.0
0.25 J
ND
0.37 J
ND
0.43 J
ND
---
ND
13-Aug-18
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.34
1.0
N D
N D
N D
ND
N D
N D
---
N D
12-Feb-20
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.34
1.0
ND
ND
ND
ND
ND
ND
---
ND
Ethylbenzene
17-Dec-08
0.30
1.0
ND
0.31 J
ND
ND
ND
ND
---
ND
NC 2L = 550 pg/L (10/23/07)
9-Jul-09
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 15 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Isobutanol
24-Jun-10
35.0
100
ND
59.0 J
ND
ND
ND
ND
---
ND
NC 2 L = NE p g/ L (02/05/10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
35.0
100
ND
39.5 J
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
35.0
100.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
35.0
100
ND
ND
ND
---
---
---
---
ND
16-Feb-16
35.0
100
ND
42.5 J
ND
---
---
---
---
ND
13-Feb-17
35.0
100
ND
ND
ND
---
---
---
---
ND
22-Aug-17
35.0
100
ND
ND
ND
---
---
---
---
ND
5-Feb-18
35.0
100
ND
ND
ND
---
---
---
---
ND
4-Feb-19
66.4
100
ND
ND
ND
---
---
---
---
ND
11-Feb-21
66.4
100
ND
ND
ND
---
---
---
---
---
Methylene Chloride
9-Ju1-09
0.97
2.0
ND
ND
ND
ND
ND
ND
ND
9.6
NC 2L = 4.3 pg/L (10/23/07)
16-Dec-09
0.97
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.97
1.0
ND
19.0
ND
ND
ND
ND
---
ND
Resample >
12-Aug-10
0.97
1.0
---
ND
---
---
---
---
---
ND
NC 2L = 5 pg/L (02/05/10)
13-Dec-10
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.97
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.97
1.0
1.3
1.1
1.6
ND
ND
ND
ND
ND
16-Feb-16
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.97
1.0
ND
ND
1.0 B
ND
ND
ND
---
2.2 B
13-Feb-17
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.97
1.0
ND
ND
ND
ND
ND
ND
---
1.4 C
5-Feb-18
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.97
1.0
ND
ND
ND
ND
ND
ND
---
6.6
4-Feb-19
3.70
5.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
Naphthalene
8-Ju1-08
---
10
ND
3.8 J
ND
ND
ND
ND
---
ND
NC 2L = 21 p g/ L (10/ 2 3/ 0 7)
17-Dec-08
---
---
---
---
---
---
---
---
---
---
9-Jul-09
0.24
10.0
ND
2.4 J
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
---
---
---
---
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.24
10.0
ND
7.4 J
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.24
10.0
ND
4.6 J
ND
ND
ND
ND
---
0.39 J
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.2
10.0
ND
4.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.24
10.0
ND
5.1 J
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.24
10.0
ND
5.8 J
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10- M a r-15
0.2
10
ND
5.4 J
ND
---
---
---
---
ND
16-Feb-16
0.2
10
ND
5.7 J
ND
---
---
---
---
ND
13-Feb-17
0.2
10
ND
6.1 J
ND
---
---
---
---
ND
22-Aug-17
0.2
10
ND
7.0 J
0.45 J
---
---
---
---
ND
5-Feb-18
0.2
10
ND
5.7 J
ND
---
---
---
---
ND
4-Feb-19
0.4
1
ND
4.2
ND
---
---
---
---
ND
11-Feb-21
0.4
1
ND
3.7
ND
---
---
---
---
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 16 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Toluene
20-May-98
---
5
ND
ND
8.1
ND
ND
ND
---
---
19-N ov-98
---
5
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
5
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
5
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
5
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
5
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
5
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
5
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
5
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
5
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
-
30-Dec-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
1
ND
0.49 B
ND
ND
ND
ND
---
0.34 J
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
---
1
ND
0.51 J
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
1
ND
0.39 J
ND
ND
1.3
ND
---
ND
17-Dec-08
0.26
1.0
1.4
1.6
ND
ND
11.7
ND
---
ND
9-Ju1-09
0.26
1.0
ND
0.46 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.26
1.0
ND
0.42 J
ND
ND
ND
ND
---
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.26
1.0
ND
0.54 J
ND
ND
ND
ND
---
ND
20-Jun-11
0.26
1.0
ND
0.34 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.26
1.0
ND
0.28 J
ND
ND
0.30 J
ND
---
ND
11-Jun-12
0.26
1.0
ND
0.28 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.26
1.0
ND
0.29 J
ND
ND
0.36 J
ND
---
ND
1-May-13
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.26
1.0
ND
0.29 J
ND
ND
ND
ND
---
ND
24-Feb-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.26
1.0
ND
0.33 J
ND
ND
ND
ND
---
ND
13-Feb-17
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.26
1.0
ND
ND
ND
ND
0.44 J
ND
---
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
12-Feb-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 17 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vinyl Chloride
8-Sep-94
---
10
ND
ND
12.0
ND
ND
ND
---
---
1-Dec-94
---
10
ND
ND
13.0
ND
ND
ND
---
---
9-Feb-95
---
10
ND
ND
15.0
ND
ND
ND
---
---
2-Mar-95
---
10
ND
ND
14.0
ND
ND
ND
---
---
15-N ov-95
---
10
ND
ND
11.0
ND
ND
ND
---
---
28-May-96
---
10
ND
ND
ND
ND
ND
ND
---
---
22-Nov-96
---
10
ND
ND
ND
ND
ND
ND
---
---
17-Jun-97
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-97
---
10
ND
ND
7.0
4.0
ND
ND
---
---
20-May-98
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-98
---
10
ND
ND
ND
ND
ND
ND
---
---
21-J u 1-99
---
10
N D
N D
N D
N D
N D
N D
---
---
16-N ov-99
---
10
N D
N D
N D
N D
N D
N D
---
---
10-May-00
---
10
N D
N D
N D
N D
N D
N D
---
---
26-Oct-00
---
10
N D
N D
N D
N D
N D
N D
---
---
18-A p r-01
---
10
N D
N D
N D
N D
N D
N D
---
---
2 7-Oct-01
---
10
N D
N D
N D
N D
N D
N D
---
---
13-Jun-02
---
10
ND
ND
ND
ND
ND
ND
---
---
19-N ov-02
---
10
N D
N D
N D
N D
N D
N D
---
---
27-Jun-03
---
10
ND
ND
ND
ND
ND
ND
---
---
30-Dec-03
---
10
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
5.5
ND
ND
0.98 J
ND
ND
ND
---
ND
Resample >
23-Feb-07
---
5.5
---
---
1.0
---
---
---
---
ND
12-Jul-07
---
1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.015 pg/L (10/23/07)
19-Dec-07
---
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
1
ND
ND
0.76 J
ND
ND
ND
---
ND
17-Dec-08
0.62
1.0
ND
ND
0.76 J
ND
ND
ND
---
ND
9-Ju1-09
0.62
1.0
ND
ND
0.99 J
ND
ND
ND
ND
ND
16-Dec-09
0.62
1.0
ND
ND
0.81 J
ND
ND
ND
---
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.62
1.0
ND
ND
0.77 J
ND
ND
ND
---
ND
13-Dec-10
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.62
1.0
ND
ND
0.63 J
ND
ND
ND
---
ND
13-Aug-18
0.62
1.0
ND
ND
0.72 J
ND
ND
ND
---
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.24
1.0
ND
ND
1.1
ND
ND
ND
---
ND
Resample >
4-Sep-19
0.24
1.0
--
--
ND
--
--
--
---
ND
12-Feb-20
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.24
1.0
ND
ND
1.1
ND
ND
ND
---
ND
Resample >
30-Sep-20
0.24
1.0
---
---
ND
---
---
---
---
ND
11-Feb-21
0.24
1.0
ND
ND
0.53 J
ND
ND
ND
---
ND
Xylene (Total)
29-Dec-06
---
5
ND
1.4
ND
ND
ND
ND
---
ND
12-Jul-07
---
4
ND
1.2 J
ND
ND
ND
ND
---
ND
NC 2L = 530 pg/L (10/23/07)
19-Dec-07
---
4
ND
2.0
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
4
ND
1.1 J
ND
ND
ND
ND
---
ND
17-Dec-08
0.66
2.0
1.4 J
2.7
ND
ND
ND
ND
---
ND
9-Ju1-09
0.66
2.0
ND
1.5 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.66
2.0
ND
2.2
ND
ND
ND
ND
---
ND
NC 2L = 500 pg/L (02/05/10)
24-Jun-10
0.66
2.0
ND
0.73 J
ND
ND
ND
ND
---
ND
13-Dec-10
0.66
2.0
ND
2.0
ND
ND
ND
ND
---
ND
20-Jun-11
0.66
2.0
ND
1.4 J
ND
ND
ND
ND
---
ND
5-Dec-11
0.66
2.0
ND
1.1 J
ND
ND
ND
ND
---
ND
11-Jun-12
0.66
2.0
ND
0.91 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.66
5.0
ND
0.97 J
ND
ND
ND
ND
---
ND
1-May-13
0.66
5.0
ND
0.68 J
ND
ND
ND
ND
ND
ND
5-Aug-13
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19 for MW-6 >
7-Aug-19
0.63
1.0
ND
N D
ND
ND
ND
ND
---
ND
12-Feb-20
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
27-Aug-20
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Feb-21
0.63
1.0
ND
ND
ND
ND
ND
ND
---
ND
Bis(2-Ethylhexyl)phthalate
24-Feb-14
0.79
15.0
2.6 J
ND
ND
ND
ND
ND
ND
ND
NC 2L = 3 pg/L (2/5/10)
15-Apr-14
0.79
15.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10- M a r-15
0.5
15.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.9
15.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.9
15.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
2.3
15.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.4
15.6
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.4
6.0
ND
ND
ND
---
---
---
---
ND
N-Nitroso-di-n-butylamine
24-Feb-14
7.5
10.0
ND
ND
ND
8.6 J
ND
ND
ND
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10- M a r-15
1.3
10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
2.2
10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
2.2
10
ND
ND
ND
---
---
---
---
ND
22-Aug-17
1.6
10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
1.6
10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
2.2
10
ND
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 18 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Benzo(g,h,i)perylene
20-Jun-11
0.4
10.0
ND
ND
ND
ND
ND
1.4 J
---
ND
NC 2 L = 200 pg/ L (2/5/ 10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.38
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.4
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.4
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
2.1
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.2
10.4
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.8
10.0
ND
ND
ND
---
---
---
---
ND
Dibenz(a,h)anthracene
20-Jun-11
0.55
10.0
ND
ND
ND
ND
ND
1.5 J
---
ND
NC 2 L = 0.005 pg/ L (2/5/ 10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.6
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.6
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.1
10.4
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.9
10.0
ND
ND
ND
---
---
---
---
ND
Fluorene
24-Jun-10
3.8
12.2
ND
4.3 J
ND
ND
ND
ND
---
ND
Resample >
12-Aug-10
3.1
10.0
---
ND
---
---
---
---
---
ND
NC 2 L = 300 pg/ L (2/5/ 10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.2
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.21
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
1.0
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.2
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.2
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
1.6
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
1.6
10.4
N D
ND
ND
---
---
---
---
ND
4-Feb-19
3.0
10.0
N D
ND
ND
---
---
---
---
ND
Indeno(1,2,3-cd)pyrene
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
1.3 J
---
ND
NC 2 L = 0.05 p g/ L (2/5/ 10)
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
---
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.5
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.3
10.0
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.3
10.0
ND
ND
ND
---
---
---
---
ND
22-Aug-17
2.0
10.0
ND
ND
ND
---
---
---
---
ND
5-Feb-18
2.1
10.4
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.7
10.0
ND
ND
ND
---
---
---
---
ND
2-Methylnaphthalene
24-Jun-10
5.1
12.2
ND
38.9
ND
ND
ND
ND
---
ND
Resample>
12-Aug-10
4.2
10
---
ND
---
---
---
---
---
ND
NC 2 L = 30 pg/ L (02/05/ 10)
13-Dec-10
---
---
---
---
---
---
---
---
---
---
20-Jun-11
0.3
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
1.0
10.0
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.3
10.0
N D
ND
ND
---
---
---
---
ND
13-Feb-17
0.3
10.0
N D
ND
ND
---
---
---
---
ND
22-Aug-17
1.4
10.0
N D
ND
ND
---
---
---
---
ND
5-Feb-18
1.5
10.4
N D
ND
ND
---
---
---
---
ND
4-Feb-19
2.8
10.0
N D
ND
ND
---
---
---
---
ND
Phorate
18-Apr-01
---
10
---
3.2
ND
ND
ND
---
---
---
27-Oct-01
---
5
N D
8.1
ND
N D
ND
ND
---
---
27-Oct-01
---
0.5
---
8.1
1.3
ND
ND
---
---
---
13-J u n-02
---
5
N D
ND
ND
ND
ND
ND
---
---
13-J u n-02
---
0.5
---
ND
ND
ND
ND
---
---
---
19-N ov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
---
5
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
---
---
---
---
---
28-Jun-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
---
---
---
---
---
12-Jul-07
---
10
ND
ND
ND
ND
ND
ND
---
ND
NC 2 L = 1.4 pg/ L (10/23/07)
19-Dec-07
---
---
---
---
---
---
---
---
ND
---
8-JuI-08
---
10
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
---
---
---
---
---
9-JuI-09
6.6
22.2
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
---
---
---
---
---
---
NC 2L = 1 pg/L (02/05/10)
24-Jun-10
6.5
24.1
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
---
---
---
---
---
---
20-Jun-11
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
---
---
---
---
---
---
---
---
---
---
11-Jun-12
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
---
---
---
---
---
---
1-May-13
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
5.4
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
1O-M a r-15
0.8
10.0
N D
ND
ND
---
---
---
---
ND
16-Feb-16
1.1
10.0
N D
ND
ND
---
---
---
---
ND
13-Feb-17
1.1
10.0
N D
ND
ND
---
---
---
---
ND
22-Aug-17
1.7
10.0
N D
ND
ND
---
---
---
---
ND
5-Feb-18
1.8
10.4
N D
ND
ND
---
---
---
---
ND
4-Feb-19
1.1
10.0
N D
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 19 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Beta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.16
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
12- D e c-12
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.050
ND
0.052
ND
N D
ND
ND
---
ND
Resample >
15-Apr-14
0.050
0.050
---
ND
---
---
---
---
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-Ma r-15
0.1
0.1
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.1
0.1
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.1
0.1
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.1
0.1
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.1
0.1
ND
ND
ND
---
---
---
---
ND
Delta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.090
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
---
---
ND
---
---
---
---
---
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-Ma r-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
---
---
ND
gamma-BHC (Lindane)
27-Jun-03
---
1.05
ND
0.085
ND
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.2 pg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
0.50
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.01
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.00021
0.010
ND
ND
0.052
ND
ND
ND
---
ND
Resample >
12-Aug-10
0.00020
0.010
---
---
ND
---
---
---
---
ND
13-Dec-10
0.00020
0.050
ND
ND
0.013 J
ND
ND
ND
---
ND
20-Jun-11
0.00020
0.050
ND
ND
0.066
ND
ND
ND
---
ND
Resample >
28-Jul-11
0.00020
0.010
---
---
ND
---
---
---
---
ND
5-Dec-11
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
---
---
ND
Heptachlor
27-Jun-03
---
1.05
ND
0.03
0.17
ND
ND
ND
---
ND
30-Dec-03
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.0078 pg/L (10/23/07)
19-Dec-07
---
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Ju1-08
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.02
0.1
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.008 pg/L (02/05/10)
24-Jun-10
0.0015
0.010
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
0.0500
0.0015
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.050
0.0015
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.050
0.056
ND
0.062
ND
ND
ND
ND
---
ND
Resample >
25-Jan-12
0.050
0.0500
---
ND
---
---
---
---
---
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.050
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.050
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.050
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.052
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.050
ND
ND
ND
---
---
---
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 20 of 21

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
2,4-D
27-Jun-03
---
3
---
5.9
ND
ND
ND
---
---
---
30-Dec-03
---
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
---
2
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
---
2
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
---
2
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
---
2
ND
ND
ND
ND
ND
ND
ND
ND
8-Apr-08
---
2
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
9-Ju1-09
---
2.0
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.11
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.23
2.1
ND
ND
ND
ND
ND
ND
---
ND
10-Dec-10
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Dec-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.22
2.0
N D
N D
N D
---
---
---
---
N D
10-Mar-15
0.24
2.1
N D
N D
N D
---
---
---
---
N D
18-Aug-15
0.24
2.1
N D
N D
N D
---
---
---
---
N D
16-Feb-16
0.23
1.0
N D
N D
N D
---
---
---
---
N D
9-Aug-16
0.24
1.0
N D
N D
N D
---
---
---
---
N D
13-Feb-17
0.22
0.9
N D
N D
N D
---
---
---
---
N D
22-Aug-17
0.24
1.0
N D
N D
N D
---
---
---
---
N D
5-Feb-18
0.24
1.0
N D
N D
N D
---
---
---
---
N D
4-Feb-19
1.60
5.0
N D
N D
N D
---
---
---
---
N D
4,4'-DDD
11-Jun-12
0.05
0.05
ND
ND
0.13
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
ND
---
---
---
---
---
NC 2L = 0.1 p g/ L (2/5/ 10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
4,4'-DDT
11-Jun-12
0.05
0.05
ND
ND
0.10
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
---
---
0.063 J
---
---
---
---
---
NC 2L = 0.1 p g/ L (2/5/ 10)
12-Dec-12
---
---
---
---
---
---
---
---
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
---
---
---
---
---
---
---
---
---
---
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
---
---
---
---
---
---
---
---
---
---
10-M a r-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
Dinoseb
10-Mar-15
0.061
1.1
ND
ND
0.11 J
---
---
---
---
ND
16-Feb-16
0.058
0.19
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.057
0.19
ND
ND
ND
---
---
---
---
ND
22-Aug-17
0.062
0.20
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.061
0.20
ND
ND
ND
---
---
---
---
ND
4-Feb-19
1.200
5.00
ND
ND
ND
---
---
---
---
ND
Endrin aldehyde
11-Jun-12
0.050
0.050
ND
ND
0.14
ND
ND
ND
---
---
NC 2L= 2 (2/5/10)
12-Dec-12
0.050
0.10
ND
ND
ND
ND
ND
ND
---
---
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
5-Aug-13
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.10
ND
ND
ND
---
---
---
---
ND
10-Mar-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
18-Aug-15
0.050
0.10
ND
ND
ND
---
---
---
---
ND
16-Feb-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
9-Aug-16
0.050
0.10
ND
ND
ND
---
---
---
---
ND
13-Feb-17
0.050
0.10
ND
ND
ND
---
---
---
---
ND
5-Feb-18
0.052
0.10
ND
ND
ND
---
---
---
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
---
---
---
---
ND
Diethyl phthalate
4-Feb-19
2.00
10.00
ND
7.1 J
ND
---
---
---
---
ND
Endosulfan I
4-Feb-19
0.05
0.05
---
0.078
0.19
---
---
---
---
---
Dichlorodifluoromethane
5-Feb-18
0.21
5.0
ND
0.36 J
ND
---
---
---
---
ND
4-Feb-19
0.23
1.0
ND
ND
ND
---
---
---
---
ND
11-Feb-21
0.23
1.0
ND
ND
ND
---
---
---
---
---
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
IMAC = Interim Maximum Allowable Concetration (for constituents with no NC2L).
Bold values for groundwater are above the NC 2L Standards or IMAC.
--- = Well was not monitored and/or not reported.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 21 of 21

Appendix F
Historical Constituents in Surface Water

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
NC2B = 10 pg/L (03/28/08)
12/13/10
2.7
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
3.0 J
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
EPA 6010
5.0
10.0
ND
ND
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
ND
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
---
08/07/19
EPA 6010D
4.7
10.0
ND
ND
ND
02/12/20
EPA 6010D
4.7
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
4.7
10.0
---
ND
---
Barium
11/22/96
---
500
37.0
37.0
---
06/17/97
---
500
37.0
62.0
---
12/01/97
---
500
53.0
45.0
---
05/20/98
---
500
24.0
69.0
---
11/19/98
---
500
ND
100.0
---
07/21/99
---
500
ND
ND
---
11/16/99
---
500
ND
ND
---
05/10/00
---
500
ND
ND
---
10/26/00
---
500
ND
ND
---
04/18/01
---
500
ND
ND
---
10/27/01
---
500
ND
ND
---
06/13/02
---
500
---
---
---
11/19/02
---
500
ND
ND
---
06/27/03
---
500
ND
ND
---
12/30/03
---
500
ND
ND
ND
06/30/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
12/29/04
---
500
ND
ND
ND
06/29/05
---
500
ND
ND
ND
12/29/05
---
500
ND
ND
ND
06/28/06
---
500
ND
ND
ND
12/29/06
---
100
37.5
40.6
0.20 J
07/12/07
---
100
33.3 J
---
ND
12/19/07
---
100
52.6 B
149.0
11.7
07/08/08
---
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 J
12.1 J
06/20/11
5.0
100
40.3 J
93.0 J
ND
12/05/11
5.0
100
32.9 J
59.0 J
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 J
79.8 J
ND
02/24/14
5.0
100
29.0 J
30.4 J
ND
08/12/14
EPA 6010
5.0
100
---
121
ND
03/10/15
EPA 6010
2.5
100
29.0 J
32.1 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
100
33.1 J
33.5 J
ND
08/09/16
EPA 6010
2.5
100
43.3 J
105
ND
02/13/17
EPA 6010
2.5
100
45.3 J
60.4 J
ND
08/22/17
EPA 6010
2.5
100
39.7 J
88.7 J
ND
02/05/18
EPA 6010
2.5
100
32.5 J
29.1 J
ND
08/13/18
EPA 6010D
2.5
100
70.0 J
86.6 J
ND
02/04/19
EPA 6010D
2.5
5
29.1
33.1
---
ISTV = 21,000 pg/L
08/07/19
EPA 6010D
1.0
5.0
70.0
94.4
ND
02/12/20
EPA 6010D
1.0
5.0
27.6
30.3
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
3.5
5.0
---
31.20
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Beryllium
07/08/08
---
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
NC2B = 6.5 pg/L (02/05/10)
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
EPA 6010
1.0
1.0
---
ND
ND
03/10/15
EPA 6010
0.50
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
0.50
1.0
ND
ND
ND
08/09/16
EPA 6010
0.50
1.0
ND
ND
ND
02/13/17
EPA 6010
0.50
1.0
ND
ND
ND
08/22/17
EPA 6010
0.50
1.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
0.50
1.0
ND
ND
ND
08/13/18
EPA 6010D
0.50
1.0
ND
ND
ND
02/04/19
EPA 6010D
0.50
1.0
ND
ND
---
08/07/19
EPA 6010D
0.20
1.0
ND
ND
ND
02/12/20
EPA 6010D
0.20
1.0
0.21 J
0.25 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
0.7
1.0
---
ND
---
Chromium
06/17/97
---
10.0
ND
3.00
---
12/01/97
---
10.0
ND
ND
---
05/20/98
---
10.0
ND
ND
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
ND
---
11/ 16/99
---
10.0
ND
ND
---
05/ 10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/ 18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
2.20 B
2.60 B
1.40 J
NC2B = 50 pg/L (03/28/08)
07/08/08
---
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 J
2.60 J
ND
07/09/09
0.4
10.0
2.6 J
1.2 J
ND
12/16/09
0.4
10.0
4.1 J
3.4 J
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
2.90 J
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
6.9 J
7.9 J
ND
NC2B = Hardness Dependant
08/13/18
EPA 6010D
2.5
10.0
5.9 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
1.0
5.0
ND
ND
ND
02/12/20
EPA 6010D
1.0
5.0
5.3
4.7 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
3.7
5.0
---
4.00 J
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Cobalt
05/20/98
---
10
2.0
2.0
---
11/19/98
---
10
ND
3.0
---
07/21/99
---
10
ND
ND
---
11/ 16/99
---
10
ND
ND
---
05/ 10/00
---
10
ND
ND
---
10/26/00
---
10
ND
ND
---
04/ 18/01
---
10
ND
ND
---
10/27/01
---
10.0
ND
22.0
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
10.0
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
4.2 B
1.20 B
1.8 J
07/08/08
---
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
NC2B = NE pg/L (03/24/10)
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
{4.4} B
{ND}
1.6 {1.0 J} J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resample >
01/25/12
5.0
10.0
---
---
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
ISTV = 4 pg/L
08/07/19
EPA 6010D
1.1
5.0
2.5 J
ND
ND
02/12/20
EPA 6010D
1.1
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
3.6
5.0
---
ND
---
Copper
12/29/06
---
10.0
1.3 B
1.10 B
0.60 J
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
5.3 B
ND
9.8
NC2B = 7 pg/L (03/28/08)
07/08/08
---
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/ 13/ 10
0.3
10.0
0.31 B
ND
0.49 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
3.8 J
3.8 J
ND
08/13/18
EPA 6010D
2.5
10.0
4.1 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
2.1
5.0
3.2 J
3.3 J
ND
02/12/20
EPA 6010D
2.1
5.0
3.9 J
3.4 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
4.3
5.0
---
ND
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Lead
05/20/98
---
10.0
ND
8.00
---
11/19/98
---
10.0
ND
ND
---
07/21/99
---
10.0
ND
10.0
---
11/ 16/99
---
10.0
ND
ND
---
05/ 10/00
---
10.0
ND
ND
---
10/26/00
---
10.0
ND
ND
---
04/ 18/01
---
10.0
ND
ND
---
10/27/01
---
10.0
ND
ND
---
06/13/02
---
10.0
---
---
---
11/19/02
---
10.0
ND
ND
---
06/27/03
---
10.0
ND
ND
---
12/30/03
---
10.0
ND
ND
ND
06/30/04
---
10.0
ND
ND
ND
12/29/04
---
10.0
ND
ND
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
10.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
ND
ND
ND
NC2B = 25 pg/L (03/28/08)
07/08/08
---
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
1.6
5.0
2.2 J
ND
ND
02/12/20
EPA 6010D
1.6
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
4.5
5.0
---
ND
---
Nickel
12/29/04
---
50.0
ND
50.0 (ND)
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
2.9 J
ND
07/12/07
---
50.0
3.8 J
---
ND
12/19/07
---
50.0
6.0
31.5
ND
NC2B = 25 pg/L (03/28/08)
07/08/08
---
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13.8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
EPA 6010
5.0
50.0
---
20.3 J
ND
03/10/15
EPA 6010
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
EPA 6010
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
EPA 6010
2.5
50.0
ND
7.3 J
ND
08/22/17
EPA 6010
2.5
50.0
ND
16.3 J
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
50.0
5.3 J
4.4 J
ND
08/13/18
EPA 6010D
2.5
50.0
7.3 J
12.4 J
ND
02/04/19
EPA 6010D
2.5
5.0
ND
2.7 J
---
08/07/19
EPA 6010D
0.90
5.0
8.8
14.8
ND
02/12/20
EPA 6010D
0.90
5.0
3.1 J
4.6 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
3.5
5.0
---
4.40 J
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
sW-1
SW-2
Blanks
Silver
07/12/07
---
10.0
2.20 J
---
ND
12/19/07
---
10.0
ND
0.34 J
ND
NC2B = 0.06 pg/L (03/28/08)
07/08/08
---
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
{ND)
{0.28) B
0.21 {0.19 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
---
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
---
08/07/19
EPA 6010D
2.5
5.0
ND
ND
ND
02/12/20
EPA 6010D
2.5
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
2.5
5.0
---
ND
---
Thallium
12/29/04
---
10.0
ND
10.0 (ND)
ND
06/29/05
---
10.0
ND
ND
ND
12/29/05
---
10.0
ND
ND
ND
06/28/06
---
10.0
ND
ND
ND
12/29/06
---
6.00
ND
ND
ND
07/12/07
---
5.5
ND
---
ND
12/19/07
---
5.5
3.60 J
ND
ND
07/08/08
---
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
NC2B = NE (03/24/10)
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
EPA 6010
5.4
5.5
---
ND
ND
03/10/15
EPA 6010
5.0
5.5
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
5.5
ND
ND
ND
08/09/16
EPA 6010
5.0
5.5
ND
ND
ND
02/13/17
EPA 6020B
0.020
5.5
ND
ND
ND
08/22/17
EPA 6020B
0.020
5.5
ND
ND
ND
02/05/18
EPA 6020B
0.028
0.10
ND
ND
ND
08/13/18
EPA 6020B
0.020
5.50
ND
ND
ND
02/04/19
EPA 6020B
0.060
0.10
ND
ND
---
08/07/19
EPA 6020B
0.060
0.10
ND
ND
ND
02/12/20
EPA 6020B
0.060
0.10
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6020B
0.1
0.1
---
ND
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Vanadium
12/29/06
---
25.0
1.60 J
2.00 J
ND
07/12/07
---
25.0
4.60 J
---
ND
12/19/07
---
25.0
3.30 J
1.40 B
0.62 J
NC2B = NE pg/L (03/28/08)
07/08/08
---
25.0
5.20 J
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 J
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.50 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
EPA 6010
5.0
25.0
---
ND
ND
03/10/15
EPA 6010
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
EPA 6010
2.5
25.0
2.9 J
2.8 J
ND
02/13/17
EPA 6010
2.5
25.0
ND
ND
ND
08/22/17
EPA 6010
2.5
25.0
2.8 J
ND
ND
02/05/18
EPA 6010
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
EPA 6010D
2.5
25.0
8.3 J
3.1 J
ND
02/04/19
EPA 6010D
2.5
5.0
2.9 J
2.7 J
---
08/07/19
EPA 6010D
1.3
5.0
1.4 J
2.3 J
ND
02/12/20
EPA 6010D
1.3
5.0
4.5 J
5.0
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
3.9
5.0
---
ND
---
Zinc
11/22/96
---
50.0
11.0
ND
---
06/17/97
---
50.0
ND
ND
---
12/01/97
---
50.0
20.0
ND
---
05/20/98
---
50.0
20.0
28.0
---
11/19/98
---
50.0
ND
ND
---
07/21/99
---
50.0
ND
ND
---
11/16/99
---
50.0
ND
ND
---
05/10/00
---
50.0
ND
ND
---
10/26/00
---
50.0
ND
ND
---
04/ 18/01
---
50.0
ND
ND
---
10/27/01
---
50.0
ND
ND
---
06/13/02
---
50.0
---
---
---
11/19/02
---
50.0
ND
ND
---
06/27/03
---
50.0
ND
ND
---
12/30/03
---
50.0
ND
ND
ND
06/30/04
---
50.0
ND
ND
ND
12/29/04
---
50.0
ND
ND
ND
06/29/05
---
50.0
ND
ND
ND
12/29/05
---
50.0
ND
ND
ND
06/28/06
---
50.0
ND
ND
ND
12/29/06
---
50.0
ND
ND
ND
07/12/07
---
10.0
ND
---
ND
12/19/07
---
10.0
24.6 B
ND
102
NC2B = 50 pg/L (03/28/08)
07/08/08
---
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
EPA 6010
10.0
10.0
---
ND
ND
03/10/15
EPA 6010
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 6010
5.0
10.0
7.0 J
ND
ND
08/09/16
EPA 6010
5.0
10.0
ND
ND
ND
02/13/17
EPA 6010
5.0
10.0
ND
5.2 J
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
NC2B = Hardness Dependant
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
---
08/07/19
EPA 6010D
3.9
10.0
ND
ND
ND
02/12/20
EPA 6010D
3.9
10.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
9.5
10.0
---
ND
---
Hardness, Total(SM 2340B)
02/04/19
EPA 6010D
662
662
57.1
85.3
---
08/07/19
EPA 6010D
131
662
316
460
ND
02/12/20
EPA 6010D
131
662
18300
60200
---
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 6010D
131.0
662.0
---
70000.00
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
ORGANICS
Acetone
10/27/01
---
100
168.0 B
337.0 B
479.0
06/13/02
---
100
---
---
---
06/13/02
---
100
---
---
---
11/19/02
---
100
ND
ND
---
06/27/03
---
100
ND
ND
---
12/30/03
---
100
ND
ND
ND
06/30/04
---
100
ND
ND
ND
12/29/04
---
100
ND
ND
ND
06/29/05
---
100
ND
ND
ND
12/29/05
---
100
ND
ND
ND
06/28/06
---
100
ND
ND
ND
12/29/06
---
100
ND
ND
ND
07/12/07
---
100
ND
---
ND
12/19/07
---
100
12.70 B
ND
4.50 J
NC2B = 2,000 pg/L (03/28/08)
07/08/08
---
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
NC2B = NE (03/24/10)
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
EPA 8260
10.0
100
---
ND
22.0 J
03/10/15
EPA 8260
10.0
100
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
10.0
100
ND
ND
ND
08/09/16
EPA 8260
10.0
100
ND
ND
ND
02/13/17
EPA 8260
10.0
100
ND
ND
ND
08/22/17
EPA 8260
10.0
100
ND
ND
ND
02/05/18
EPA 8260
10.0
100
ND
ND
ND
08/13/18
EPA 8260B
10.0
100
ND
ND
ND
02/04/19
EPA 8260B
6.2
25
ND
ND
---
ISTV = 2000 pg/L
08/07/19
EPA 8260D
6.2
25.0
ND
ND
ND
02/12/20
EPA 8260D
6.2
25.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 8260D
6.2
25.0
---
ND
---
Chlorobenzene
06/27/03
---
5.0
ND
7.20
ND
12/30/03
---
5.0
ND
ND
ND
06/30/04
---
5.0
ND
ND
ND
12/29/04
---
5.0
ND
ND
ND
06/29/05
---
5.0
ND
ND
ND
12/29/05
---
5.0
ND
ND
ND
06/28/06
---
5.0
ND
ND
ND
12/29/06
---
3.0
ND
ND
ND
07/12/07
---
3.0
ND
---
ND
12/19/07
---
3.0
ND
ND
ND
NC2B = 130 pg/L (03/28/08)
07/08/08
---
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
EPA 8260
0.23
3.0
---
ND
ND
03/10/15
EPA 8260
0.23
3.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.23
3.0
ND
ND
ND
08/09/16
EPA 8260
0.23
3.0
ND
ND
ND
02/13/17
EPA 8260
0.23
3.0
ND
ND
ND
08/22/17
EPA 8260
0.23
3.0
ND
ND
ND
02/05/18
EPA 8260
0.23
3.0
ND
ND
ND
08/13/18
EPA 8260B
0.23
3.0
ND
ND
ND
02/04/19
EPA 8260B
0.23
1.0
ND
ND
---
08/07/19
EPA 8260D
0.23
1.0
ND
ND
ND
02/12/20
EPA 8260D
0.23
1.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 8260D
0.2
1.0
---
ND
---
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 8

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
NC213 = NE (03/24/10)
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
EPA 8260
0.11
1.0
---
ND
ND
03/10/15
EPA 8260
0.11
1.0
ND
ND
ND
08/18/15
---
---
Dry
Dry
---
02/16/16
EPA 8260
0.11
1.0
ND
ND
ND
08/09/16
EPA 8260
0.11
1.0
ND
ND
ND
02/13/17
EPA 8260
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
EPA 8260
0.11
1.0
ND
ND
ND
02/05/18
EPA 8260
0.11
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.11
1.0
ND
ND
ND
02/04/19
EPA 8260B
0.39
1.0
ND
ND
---
08/07/19
EPA 8260D
0.39
1.0
ND
ND
ND
02/12/20
EPA 8260D
0.39
1.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 8260D
0.4
1.0
---
ND
---
1,4-Dioxane (p-Dioxane)
08/13/18
EPA 8260B Mod.
1.9
2.0
ND
14.1
ND
02/04/19
EPA 8260B Mod.
1.9
2.0
ND
ND
---
ISTV = 80 pg/L
08/07/19
EPA 8260D Mod.
1.2
2.0
10.50
22.3
ND
02/12/20
EPA 8260D Mod.
1.2
2.0
ND
1.2 J
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 8260D Mod.
1.2
2.0
---
3.00
---
Methylene Chloride
08/09/16
EPA 8260
0.97
1.0
ND
ND
2.20 J
02/13/17
EPA 8260
0.97
1.0
ND
ND
ND
NC 2L = 5 pg/L (2/5/10)
08/22/17
EPA 8260
0.97
1.0
ND
ND
1.4 C9
02/05/18
EPA 8260
0.97
1.0
ND
ND
ND
08/13/18
EPA 8260B
0.97
1.0
ND
ND
6.60
02/04/19
EPA 8260B
3.7
5.0
ND
ND
---
ISTV = 11,000 pg/L
08/07/19
EPA 8260D
3.7
5.0
ND
ND
ND
02/12/20
EPA 8260D
3.7
5.0
ND
ND
ND
08/27/20
---
---
Dry
Dry
---
02/11/21
EPA 8260D
3.7
5.0
-
ND
---
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC213 = North Carolina Surface Water Standards from 15A NCAC 213.0101
ISTV = NC In -stream Target Values (for constituents with no NC213).
NE = Not established.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 8

Appendix G
Historical Monitoring Natural Attenuation Parameters

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Temperature
12/30/03
°C
- -
15.4
11.1 11.2 12.5 13.6 14.2
-
(FP)
12/19/07
°C
- -
12.3
12.5 13.1 14.4 14.9 14.4
13.3
05/01/13
°C
- -
15.7
13.7 15.1 14.4 14.2 14.2
12.5
08/14/14
°C
- -
17.8
18.0 19.2 19.4 16.8 17.2
16.0
03/10/15
°C
- -
17.3
16.0 15.9 13.8 13.3 13.7
16.1
08/18/15
°C
- -
16.43
17.78 17.79 17.25 16.47 16.64
16.05
02/16/16
°C
- -
14.6
13.8 14.4 14.0 12.0 13.4
13.1
08/09/16
°C
- -
16.4
17.3 19.4 18.2 17.1 16.8
17.9
02/13/17
°C
- -
14.8
14.4 14.9 15.7 14.1 15.3
15.2
08/22/17
°C
- -
17.4
17.9 17.9 17.5 17.4 16.6
17.8
02/05/18
°C
- -
13.06
11.66 13.05 14.46 13.83 14.53
12.25
08/13/18
°C
- -
17.4
21.1 18.2 19.3 20.6 18.4
16.6
02/04/19
°C
- -
13.2
15.5 16.5 14.9 14.5 15.4
13.7
08/06/19
°C
- -
17.0
22.7 17.6 19.9 17.3 18.2
16.0
Resample -->
08/14/19
°C
- -
-
- - - - 24.3
-
02/12/20
°C
- -
17.2
14.3 14.8 16.5 15.1 16.4
14.8
08/27/20
°C
- -
17.2
18.9 19.9 22.2 20.3 21.1
20.1
Resample -->
09/30/20
°C
- -
-
- 19.3 - - -
-
02/11/21
°C
- -
15.1
12.4 13.6 11.8 11.5 11.3
14.0
pH
12/30/03
SU
- -
7.31
6.54 6.81 6.90 7.24 7.29
-
(FP)
12/19/07
SU
- -
6.89
6.90 7.07 6.87 7.39 6.67
7.64
05/01/13
SU
- -
7.32
6.37 6.61 6.42 6.92 7.13
6.10
08/14/14
SU
- -
5.84
6.36 6.96 6.79 7.00 6.48
5.59
03/10/15
SU
- -
6.11
6.37 6.56 6.30 6.25 6.55
5.68
08/18/15
SU
- -
5.12
6.68 6.48 6.76 7.03 6.78
4.94
02/16/16
SU
- -
6.15
6.15 6.61 6.69 7.14 6.10
6.52
08/09/16
SU
- -
4.79
5.05 5.30 5.06 4.41 5.75
6.46
02/13/17
SU
- -
6.10
6.55 6.76 6.78 6.24 7.37
6.23
08/22/17
SU
- -
6.58
6.46 6.45 6.98 7.53 7.16
7.16
02/05/18
SU
- -
7.11
6.80 7.01 7.33 7.22 7.54
5.53
08/13/18
SU
- -
6.30
6.45 6.64 6.38 7.15 7.03
5.54
02/04/19
SU
- -
6.17
6.44 7.16 6.87 6.07 7.02
5.13
08/06/19
SU
- -
8.84
6.17 6.49 6.69 7.44 7.49
6.79
Resample -->
08/14/19
SU
- -
-
- - - - 6.47
-
02/12/20
SU
- -
5.63
4.88 6.30 6.73 6.27 7.10
8.72
08/27/20
SU
- -
5.08
6.13 6.42 6.45 6.71 6.73
5.48
Resample -->
09/30/20
SU
- -
-
- 6.57 - - -
-
02/11/21
SU
- -
5.65
6.13 6.45 5.94 6.30 6.15
4.38
Conductivity
12/19/07
pS/cm
- -
96
1,964 1,591 1,245 - -
510
(FP)
05/01/13
pS/cm
- -
111
1,587 1,357 1,150 195 594
69.6
08/14/14
pS/cm
- -
231
1,897 1,534 1,413 522 565
172.6
03/10/15
pS/cm
- -
90
996 1,277 1,186 106 504
114
08/18/15
pS/cm
- -
134
1,630 1,680 1,244 617 534
83
02/16/16
pS/cm
- -
72.4
1,611 1,369 1,234 164 474
78.2
08/09/16
pS/cm
- -
100.7
1,924 1,535 1,475 660 600
95.6
02/13/17
pS/cm
- -
68.0
1,535 1,314 1,155 272 508
89.6
08/22/17
pS/cm
- -
77.1
1,752 1,350 1,446 755 560
175
02/05/18
pS/cm
- -
80.0
1,460 1,247 1,230 676 633
50.0
08/13/18
pS/cm
- -
101.2
2,013 1,608 1,569 870 620
131.2
02/04/19
pS/cm
- -
107.9
1,692 1,266 1,364 276.1 546.0
91.6
08/06/19
pS/cm
- -
113.4
1,719 1,307 1,287 775.0 545.3
98.5
Resample -->
08/14/19
pS/cm
- -
-
- - - - 559
-
02/12/20
pS/cm
- -
94.8
1,946 1,475 1,471 276.9 588.3
95.5
08/27/20
pS/cm
- -
82.4
1,601 1,217 1,335 773.0 577.0
140.5
Resample -->
09/30/20
pS/cm
- -
-
- 1,409 - - -
-
02/11/21
pS/cm
- -
85.2
1,251.0 1,004.0 838.0 211.3 323.8
65.9
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Redox Potential
12/30/03
mV
- -
257.2
76.2
207.6
212.7
187.3
123.6
-
ORP
12/19/07
mV
- -
146
45.0
142
134
-
-
138
(FP)
05/01/13
mV
- -
111.7
-26.7
55.2
120.5
-
-
227.1
08/14/14
mV
- -
115.8
-37.2
86.9
-
-
-
-
03/10/15
mV
- -
87.0
0.8
56.3
-
-
-
96.7
08/18/15
mV
- -
134.7
-96.3
-68.8
-33.9
-49.9
-
182.8
02/16/16
mV
- -
111.7
-47.3
16.9
-
-
-
173.4
08/09/16
mV
- -
56.0
-43.1
-6.9
-
-
-
-
02/13/17
mV
- -
87.4
0.8
-16.5
-
-
-
-
08/22/17
mV
- -
102.9
-37.1
87.0
-
-
-
116.7
02/05/18
mV
- -
57.1
29.5
49.4
-
-
-
109.2
08/13/18
mV
- -
117.9
-60.5
-49.3
-
-
64.4
28.4
02/04/19
mV
- -
197.7
-64.3
132.2
-
9.6
-
281.2
08/06/19
mV
- -
164.7
-69.3
-33.7
171.6
188.6
232.6
231.8
Resample -->
08/14/19
mV
- -
-
-
-
-
-
237.6
-
02/12/20
mV
- -
336.5
33.4
22.4
254.5
299.9
282.0
245.6
08/27/20
mV
- -
242.7
-10.8
12.4
190.3
196.5
188.0
240.6
Resample -->
09/30/20
mV
- -
-
-
232.3
-
-
-
-
02/11/21
mV
- -
166.8
4.1
34.8
197.4
-
278.8
284.5
Dissolved Oxygen
12/30/03
mg/L
- -
9.49
4.84
-
-
-
-
-
DO
12/19/07
mg/L
- -
-
1.88
1.44
3.21
-
-
0.70
(FP)
05/01/13
mg/L
- -
4.40
1.37
1.79
4.65
-
-
2.90
08/14/14
mg/L
- -
4.44
3.26
2.48
-
-
-
2.80
03/10/15
mg/L
- -
3.84
1.47
1.80
-
-
-
1.85
08/18/15
mg/L
- -
4.95
5.75
1.30
-
3.79
-
1.77
02/16/16
mg/L
- -
4.45
3.66
2.51
-
-
-
3.72
08/09/16
mg/L
- -
3.17
2.87
2.29
-
-
-
-
02/13/17
mg/L
- -
5.37
3.16
2.14
-
-
-
-
08/22/17
mg/L
- -
5.43
2.24
4.02
-
-
-
5.86
02/05/18
mg/L
- -
8.08
6.61
9.16
-
-
-
8.36
08/13/18
mg/L
- -
6.31
3.20
2.35
-
-
4.80
3.91
02/04/19
mg/L
- -
1.26
1.82
4.17
-
4.17
-
1.63
08/06/19
mg/L
- -
3.77
0.32
0.26
4.55
5.30
2.76
3.04
Resample -->
08/14/19
mg/L
- -
-
-
-
-
-
1.95
-
02/12/20
mg/L
- -
5.11
0.65
1.36
4.30
3.48
2.44
6.37
08/27/20
mg/L
- -
0.63
0.22
0.48
5.04
6.22
4.14
3.16
Resample -->
09/30/20
mg/L
- -
-
-
2.00
-
-
-
-
02/11/21
mg/L
- -
1.75
1.05
0.40
7.40
5.41
3.23
2.18
Dissolved CO2
12/19/07
mg/L
- -
25.0
365
175
295
-
-
60
(FP)
05/01/13
mg/L
- -
30.0
245
125
225
-
-
45
08/14/14
mg/L
- -
60.0
390
185
-
-
-
75
03/10/15
mg/L
- -
50.0
110
75
-
-
-
50
08/18/15
mg/L
- -
30.0
275
125
-
-
-
60
02/16/16
mg/L
- -
30.0
210
230
-
-
-
20
08/09/16
mg/L
- -
-
185
210
-
-
-
-
02/13/17
mg/L
- -
-
-
-
-
-
-
-
08/22/17
mg/L
- -
-
-
-
-
-
-
-
02/05/18
mg/L
- -
-
-
-
-
-
-
-
08/13/18
mg/L
- -
-
-
-
-
-
-
-
02/04/19
mg/L
- -
75.0
-
130.0
-
-
-
-
08/06/19
mg/L
- -
-
475.0
250.0
-
-
-
-
02/12/20
mg/L
- -
-
260.0
-
-
-
-
-
08/27/20
mg/L
- -
-
-
-
-
-
-
-
02/11/21
mg/L
- -
-
-
-
-
-
-
-
Butner Landfill, Granville Co.
Permit No. 39-02 Page 2 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5 MW-6
NES-1
Fe, Ferrous (+2)
12/30/03
mg/L
-
-
ND
1.5
ND
ND
0.22 ND
-
(FP)
12/19/07
mg/L
-
-
ND
7.2
ND
ND
- -
0.2
05/01/13
mg/L
-
-
ND
1.0
ND
ND
- -
ND
08/14/14
mg/L
-
-
ND
2.5
ND
-
- -
ND
03/10/15
mg/L
-
-
ND
5.3
ND
-
- -
ND
08/18/15
mg/L
-
-
ND
4.5
1.0
-
- -
ND
02/16/16
mg/L
-
-
ND
4.0
1.3
-
- -
ND
08/09/16
mg/L
-
-
-
3.1
1.0
-
- -
-
02/13/17
mg/L
-
-
ND
3.0
1.5
-
- -
-
08/22/17
mg/L
-
-
ND
3.5
1.5
-
- -
ND
02/05/18
mg/L
-
-
ND
4.0
0.5
-
- -
ND
08/13/18
mg/L
-
-
ND
5.5
0.2
-
- -
-
02/04/19
mg/L
-
-
ND
-
ND
-
- -
-
08/06/19
mg/L
-
-
-
3.5
0.5
-
- -
-
02/12/20
mg/L
-
-
-
1.0
0.5
-
- -
-
08/27/20
mg/L
-
-
-
4.5
1.0
-
- -
-
02/11/21
mg/L
-
-
0
1.5
0.5
-
- -
0.0
Alkalinity (as CaCO3)
12/30/03
mg/L
9.00
10.0
37.0
800
690
640
68.0 350
-
12/19/07
mg/L
-
5.00
39.0
763
726
619
- -
190
05/01/13
mg/L
1.00
5.00
43.4
757
660
645
- -
10.4
08/14/14
mg/L
1.00
5.00
41.1
784
661
-
- -
14.5
03/10/15
mg/L
1.00
5.00
38.0
744
653
-
- -
8.8
08/18/15
mg/L
1.00
5.00
37.8
772
664
-
- -
10.3
02/16/16
mg/L
1.00
5.00
41.2
792
741
-
- -
8.73
08/09/16
mg/L
1.00
5.00
-
783
629
-
- -
-
02/13/17
mg/L
1.00
5.00
37.9
753
654
-
- -
8.79
08/22/17
mg/L
1.00
5.00
42.4
766
678
-
- -
10.2
02/05/18
mg/L
1.00
5.00
44.4
821
752
-
- -
7.52
08/13/18
mg/L
1.00
5.00
-
768
722
-
- -
-
02/04/19
mg/L
1.00
5.00
62.0
856
638
-
- -
7.02
08/06/19
mg/L
5.00
5.00
-
839
754
-
- -
-
02/02/20
mg/L
5.00
5.00
-
818
646
-
- -
-
08/27/20
mg/L
5.00
5.00
47.6
909
735
-
- -
-
02/11/21
mg/L
5.00
5.00
53.9
875
724
-
- -
ND
Chloride
12/30/03
mg/L
0.200
1.00
3.50
280
170
82.0
13.0 44.0
-
12/19/07
mg/L
-
5.00
ND
13.1
297
89.1
- -
7.90
NC 2L = 250,000 pg/L
05/01/13
mg/L
0.50
1.00
3.54
258
180
123
- -
2.85
(250 mg/L)
08/14/14
mg/L
0.50
1.00
5.53
264
144
-
- -
5.00
03/10/15
mg/L
0.50
1.00
3.80
266
194
-
- -
4.09
08/18/15
mg/L
0.50
1.00
4.69
267
178
-
- -
3.90
02/16/16
mg/L
0.50
1.00
3.92
274
186
-
- -
3.24
08/09/16
mg/L
0.50
1.00
-
269
191
-
- -
-
02/13/17
mg/L
0.50
1.00
3.45
309
215
-
- -
5.09
08/22/17
mg/L
0.50
1.00
3.73
318
214
-
- -
5.86
02/05/18
mg/L
0.50
1.00
3.92
280
205
-
- -
2.52
08/13/18
mg/L
0.50
1.00
-
221
165
-
- -
-
02/04/19
mg/L
0.50
1.00
3.42
221
147
-
- -
4.52
08/06/19
mg/L
2.40
4.00
-
203
154
-
- -
-
02/12/20
mg/L
2.40
4.00
-
224
153
-
- -
-
08/27/20
mg/L
2.40
4.00
3.84
208
148
-
- -
5.33
02/11/21
mg/L
2.40
4.00
3.67
201
148
-
- -
4.06
Butner Landfill, Granville Co.
Permit No. 39-02 Page 3 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Hydrogen
05/01/13
nM
0.074 0.60
0.400
0.630 0.610 0.500 - -
0.470
08/14/14
nM
0.13 0.60
1.4
1.6 5.4 - - -
1.4
03/10/15
nM
0.13 0.60
1.2
1.4 1.4 1.0 - -
1.4
08/18/15
nM
0.13 0.60
1.7
2.2 1.7 - - -
1.5
02/16/16
nM
0.13 0.60
2.0
1.7 1.9 - - -
1.5
08/09/16
nM
0.13 0.60
-
1.5 1.6 - - -
-
02/13/17
nM
- -
-
- - - - -
-
08/22/17
nM
- -
-
- - - - -
-
02/05/18
nM
- -
-
- - - - -
-
08/13/18
nM
- -
-
- - - - -
-
02/04/19
nM
0.65 1.0
6.7
7.6 7.4 - - -
6.8
08/06/19
nM
0.75 1.0
-
2.0 5.4 - - -
-
02/12/20
nM
- -
-
5.8 2.7 - - -
-
08/27/20
nM
0.49 0.49
-
1.0 J 1.2 J - - -
-
Resample -->
09/10/20
nM
0.49 1.9
1.8
- - - - -
2.4
02/11/21
nM
- -
-
- - - - -
-
Nitrate-N
12/30/03
mg/L
0.020 0.050
0.120
ND ND ND ND 0.13
-
12/19/07
mg/L
- 0.100
ND
ND ND ND - -
13.0
05/01/13
mg/L
0.001 10.0
0.163
ND ND ND - -
3.58
08/14/14
mg/L
0.001 10.0
0.115 J
ND ND - - -
2.02 J
03/10/15
mg/L
0.001 10.0
0.252 J
ND ND - - -
2.56 J
08/18/15
mg/L
0.001 10.0
0.124 J
ND ND - - -
3.27 J
02/16/16
mg/L
0.001 10.0
0.36 J
ND ND - - -
2.54 J
08/09/16
mg/L
0.001 10.0
-
ND ND - - -
-
02/13/17
mg/L
0.001 10.0
0.248 J
0.189 J ND - - -
2.63 J
08/22/17
mg/L
0.001 10.0
0.118 J
0.0186 J 0.0451 J - - -
4.06 J
02/05/18
mg/L
0.010 10.0
0.310 J
ND 0.0120 J - - -
1.15 J
08/13/18
mg/L
0.050 0.1
-
ND ND - - -
-
02/04/19
mg/L
0.050 0.1
0.196
ND 0.113 - - -
6.5
08/06/19
mg/L
0.010 0.0
-
ND ND - - -
-
02/12/20
mg/L
0.010 0.0
-
0.069 0.362 - - -
-
08/27/20
mg/L
0.050 0.1
ND
ND ND - - -
6.34
02/11/21
mg/L
0.01 0.04
0.0565
ND 0.0587 - - -
4.65
Sulfate
12/30/03
mg/L
0.0600 2.00
ND
ND ND 2.60 9.60 9.00
-
12/19/07
mg/L
- 5.00
ND
ND ND ND - -
36.8
NC 2L = 250,000 pg/L
05/01/13
mg/L
1.00 250
ND
ND ND 4.69 - -
10.7
(250 mg/L)
08/14/14
mg/L
1.00 250
1.08 J
1.2 J ND - - -
5.84 J
03/10/15
mg/L
1.00 250
1.52 J
1.13 J 1.52 J - - -
7.04 J
08/18/15
mg/L
1.00 250
1.56 J
1.31 J 2.49 J - - -
524 J
02/16/16
mg/L
1.0 250
1.5 J
1.7 J 1.8 J - - -
10.0 J
08/09/16
mg/L
1.00 250
-
1.22 J 1.75 J - - -
-
02/13/17
mg/L
1.00 250
1.53 J
1.59 J 1.78 J - - -
11.9 J
08/22/17
mg/L
1.00 250
ND
ND 0.626 J - - -
11.2 J
02/05/18
mg/L
0.500 250
ND
ND 0.627 J - - -
7.48 J
08/13/18
mg/L
0.500 250
ND
ND 0.630 J - - -
-
02/04/19
mg/L
0.500 250
1.15
ND 1.10 - - -
6.75
08/06/19
mg/L
0.500 1
-
ND 0.711 J - - -
-
02/12/20
mg/L
0.500 1
-
ND 0.58 J - - -
-
08/27/20
mg/L
0.500 1
ND
ND ND - - -
5.21
02/11/21
mg/L
0.500 1
1.41
ND 0.819 - - -
5.92
Butner Landfill, Granville Co.
Permit No. 39-02 Page 4 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Sulfide
08/14/14
mg/L
0.05 1.00
ND
ND ND - - -
ND
03/10/15
mg/L
0.05 1.00
ND
ND ND - - -
ND
08/18/15
mg/L
0.05 1.00
ND
ND ND - - -
1.0
02/16/16
mg/L
0.05 1.00
ND
ND ND - - -
ND
08/09/16
mg/L
0.05 1.00
-
ND ND - - -
-
02/13/17
mg/L
0.05 1.00
ND
ND ND - - -
-
08/22/17
mg/L
0.05 1.00
ND
ND ND - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
0.05 1
ND
ND ND - - -
ND
08/06/19
mg/L
0.05 0.1
-
ND ND - - -
-
02/12/20
mg/L
0.05 0.1
-
0.083 J ND - - -
-
08/27/20
mg/L
0.05 0.1
ND
ND ND - - -
ND
02/11/21
mg/L
- -
-
- - - - -
-
Total Organic Carbon
12/19/07
mg/L
- 1.0 *
2.9
54.3 23.2 17.2 - -
7.20
05/01/13
mg/L
0.50 1.00
2.24
29.5 30.0 19.4 - -
5.74
08/14/14
mg/L
0.50 1.00
ND
229 25.5 - - -
8.39
03/10/15
mg/L
0.50 1.00
O.781J
34.8 9.54 - - -
1.88
08/18/15
mg/L
0.50 1.00
O.917J
32.9 9.86 - - -
27.80
02/16/16
mg/L
0.50 1.00
1.500
27.6 8.46 - - -
40.90
08/09/16
mg/L
0.50 1.00
-
29.4 9.53 - - -
-
02/13/17
mg/L
0.50 1.00
ND
28.5 9.72 - - -
1.36
08/22/17
mg/L
0.50 1.00
ND
29.1 9.92 - - -
1.71
02/05/18
mg/L
0.50 1.00
ND
25.9 11.4 - - -
4.24
08/13/18
mg/L
0.50 1.00
ND
25.8 10.2 - - -
ND
02/04/19
mg/L
0.50 1.00
ND
27.9 8.02 - - -
1.6
08/06/19
mg/L
2.50 5.00
-
33.3 15.1 - - -
-
02/12/20
mg/L
2.50 5.00
-
25.4 7.46 - - -
-
08/27/20
mg/L
0.50 1.00
0.689 J
29.8 8.19 - - -
0.916 J
02/11/21
mg/L
0.50 1.00
ND
28.2 7.68 - - -
1.61
Biochemical Oxygen Demand
08/14/14
mg/L
2.00 2.00
ND
83.4 2.49 - - -
-
BOD (5-day)
03/10/15
mg/L
2.00 2.00
2.55
10.6 ND - - -
ND
08/18/15
mg/L
2.00 2.00
2.22
11.8 2.0 - - -
2.00
02/16/16
mg/L
2.00 2.00
ND
60.0 6.6 - - -
ND
08/09/16
mg/L
2.00 2.00
-
11.6 ND - - -
-
02/13/17
mg/L
2.00 2.00
ND
9.50 J ND - - -
ND
08/22/17
mg/L
2.00 2.00
ND
ND ND - - -
ND
02/05/18
mg/L
2.00 2.00
ND
5.6 ND - - -
ND
08/13/18
mg/L
2.00 2.00
ND
71.8 3.56 - - -
ND
02/04/19
mg/L
2.00 2.00
ND
7.5 ND - - -
ND
08/06/19
mg/L
2.00 2.00
-
8.0 ND - - -
-
02/12/20
mg/L
2.00 2.00
-
6.3 ND - - -
-
08/27/20
mg/L
2.00 2.00
ND
9.45 ND - - -
ND
02/11/21
mg/L
2.00 2.00
ND
9.87 ND - - -
ND
Butner Landfill, Granville Co.
Permit No. 39-02 Page 5 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5 MW-6
NES-1
Chemical Oxygen Demand
08/14/14
mg/L
12.5
25.0
ND
132.0
ND
-
- -
50.00
COD
03/10/15
mg/L
12.5
25.0
15.0J
235.0
96.0
-
- -
ND
08/18/15
mg/L
12.5
25.0
25.0
110.0
756.0
-
- -
25.00
02/16/16
mg/L
12.5
25.0
ND
295.0
50.0
-
- -
ND
08/09/16
mg/L
12.5
25.0
-
131.0
50.0
-
- -
-
02/13/17
mg/L
12.5
25.0
17.0 J
119.0
43.0
-
- -
22.0 J
08/22/17
mg/L
12.5
25.0
ND
121.0
74.0
-
- -
16.0 J
02/05/18
mg/L
12.5
25.0
ND
113.0
51.0
-
- -
46.0
08/13/18
mg/L
12.5
25.0
ND
112.0
73.9
-
- -
ND
02/04/19
mg/L
12.5
25.0
ND
101.0
26.5
-
- -
ND
08/06/19
mg/L
12.5
25.0
-
123.0
45.5
-
- -
-
02/12/20
mg/L
12.5
25.0
-
160.0
36.1
-
- -
-
08/27/20
mg/L
12.5
25.0
ND
112.00
35.9
-
- -
ND
02/11/21
mg/L
12.5
25.0
ND
108
38.0
-
- -
ND
Dissolved Ethane
12/30/03
mg/L
0.0002
0.0010
ND
ND
ND
ND
ND ND
-
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
- -
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
ND
ND
- -
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
0.0036 J
-
- -
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
-
- -
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
-
- -
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
-
- -
ND
08/09/16
mg/L
0.0031
0.0062
-
1.6 J
2.6 J
-
- -
-
02/13/17
mg/L
-
-
-
-
-
-
- -
-
08/22/17
mg/L
-
-
-
-
-
-
- -
-
02/05/18
mg/L
-
-
-
-
-
-
- -
-
08/13/18
mg/L
-
-
-
-
-
-
- -
-
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.0100
ND
2.0 J
.0041 J
-
- -
ND
02/12/20
mg/L
0.0012
0.0100
ND
0.0026 J
0.0026 J
-
- -
ND
08/27/20
mg/L
0.001
0.0100
ND
ND
ND
-
- -
ND
02/11/21
mg/L
-
-
-
-
-
-
- -
-
Dissolved Ethene
12/01/03
mg/L
0.0003
0.0010
ND
ND
ND
ND
ND ND
-
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
- -
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
0.0017
ND
- -
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
ND
-
- -
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
-
- -
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
-
- -
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
-
- -
ND
08/09/16
mg/L
0.0031
0.0062
-
ND
ND
-
- -
-
02/13/17
mg/L
-
-
-
-
-
-
- -
-
08/22/17
mg/L
-
-
-
-
-
-
- -
-
02/05/18
mg/L
-
-
-
-
-
-
- -
-
08/13/18
mg/L
-
-
-
-
-
-
- -
-
02/04/19
mg/L
0.001
0.001
ND
ND
ND
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.01
ND
ND
.0016 J
-
- -
ND
02/12/20
mg/L
0.0012
0.01
ND
0.0027 J
ND
-
- -
ND
08/27/20
mg/L
0.001
0.01
ND
ND
ND
-
- -
ND
02/11/21
mg/L
-
-
-
-
-
-
- -
-
Butner Landfill, Granville Co.
Permit No. 39-02 Page 6 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
0.0002 0.0010
ND
0.660 0.130 0.0099 0.0010 ND
-
12/19/07
mg/L
- 10.0
ND
0.116 0.186 ND - -
ND
05/01/13
mg/L
0.0033 0.0066
ND
0.0379 0.100 0.0337 - -
ND
08/14/14
mg/L
0.0033 0.0066
ND
1.29 0.284 - - -
ND
03/10/15
mg/L
0.0033 0.0066
0.0072
0.996 0.158 - - -
ND
08/18/15
mg/L
0.0033 0.0066
0.0027
2.16 0.316 - - -
0.0013
02/16/16
mg/L
0.0033 0.0066
0.007 J
0.87 0.098 - - -
0.0016 J
08/09/16
mg/L
0.0033 0.0066
-
1.85 0.206 - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
0.001 0.0010
ND
27.2 ND ND ND ND
ND
08/06/19
mg/L
0.0034 0.0100
ND
5.0 0.486 - - -
ND
02/12/20
mg/L
0.0034 0.0100
ND
4.5 0.376 - - -
ND
08/27/20
mg/L
0.0034 0.0100
ND
6.0 0.497 - - -
ND
02/11/21
mg/L
0.0034 0.0100
ND
6.66 0.519 - - -
ND
Pyruvic Acid
12/19/07
mg/L
- -
2.50
ND 1.50 2.00 - -
1.20
05/01/13
mg/L
2 10
ND
ND ND ND - -
ND
08/14/14
mg/L
0.77 10
ND
ND ND - - -
ND
03/10/15
m g/ L
0.77 10
0.41J
0.41J 0.41J - - -
0.41J
08/18/15
mg/L
0.77 10
ND
ND ND - - -
ND
02/16/16
mg/L
0.77 10
ND
ND ND - - -
ND
08/09/16
mg/L
0.77 10
-
ND ND - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
- -
ND
ND ND - - -
ND
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.06 0.06
ND
ND ND - - -
ND
02/11/21
mg/L
- -
-
- - - - -
-
Lactic Acid
12/19/07
mg/L
ND
5.40 11.9 3.10 - -
ND
05/01/13
mg/L
2.3 25
ND
ND ND ND - -
ND
08/14/14
mg/L
2.5 25
4.2 J
ND ND - - -
ND
03/10/15
mg/L
2.5 25
ND
ND ND - - -
ND
08/18/15
mg/L
2.5 25
ND
ND ND - - -
ND
02/16/16
mg/L
2.5 25
ND
ND ND - - -
ND
08/09/16
mg/L
2.5 25
-
ND ND - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
0.043 0.20
ND
ND 0.087 J - - -
ND
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.053 0.053
ND
ND ND - - -
ND
02/11/21
mg/L
- -
-
- - - - -
-
Butner Landfill, Granville Co.
Permit No. 39-02 Page 7 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Acetic Acid
12/19/07
mg/L
ND
ND ND ND - -
ND
05/01/13
mg/L
1.8 5
ND
ND ND ND - -
ND
08/14/14
mg/L
0.81 5.0
ND
ND ND - - -
ND
03/10/15
mg/L
0.81 5.0
ND
ND ND - - -
ND
08/18/15
mg/L
0.81 5.0
ND
ND 0.97 J - - -
ND
02/16/16
mg/L
0.81 5.0
ND
ND ND - - -
ND
08/09/16
mg/L
0.81 5.0
-
ND ND - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
0.028 0.10
ND
0.097 J 0.34 - - -
ND
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.12 0.12
0.530
4.7 J 0.53 - - -
0.56
02/11/21
mg/L
- -
-
- - - - -
-
Propionic Acid
12/19/07
mg/L
ND
63.7 38.3 12.8 - -
ND
05/01/13
mg/L
1 5
ND
ND ND ND - -
ND
08/14/14
mg/L
0.66 5.0
ND
ND ND - - -
ND
03/10/15
mg/L
0.66 5.0
ND
ND ND - - -
ND
08/18/15
mg/L
0.66 5.0
ND
ND ND - - -
ND
02/16/16
mg/L
0.66 5.0
ND
ND ND - - -
ND
08/09/16
mg/L
0.66 5.0
-
ND ND - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
0.004 0.10
-
0.0058 J 0.0045 J - - -
-
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.053 0.053
ND
ND ND - - -
ND
02/11/21
mg/L
- -
-
- - - - -
-
Butyric Acid
12/19/07
mg/L
ND
ND ND ND - -
ND
05/01/13
mg/L
0.87 5
ND
ND ND ND - -
ND
08/14/14
mg/L
0.70 5.0
ND
ND ND - - -
ND
03/10/15
mg/L
0.70 5.0
ND
ND ND - - -
ND
08/18/15
mg/L
0.70 5.0
ND
ND ND - - -
ND
02/16/16
mg/L
0.70 5.0
ND
ND ND - - -
ND
08/09/16
mg/L
0.70 5.0
-
ND ND - - -
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
0.011 0.10
-
0.22 ND - - -
-
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.058 0.058
ND
ND 0.066 J - - -
ND
02/11/21
mg/L
- -
-
- - - - -
-
Formic Acid
08/06/19
mg/L
0.086 0.50
-
1.10 1.60 - - -
-
02/12/20
mg/L
- -
-
- - - - -
-
08/27/20
mg/L
0.055 0.055
4.9
45.0 4.8 - - -
5.1
02/11/21
mg/L
- -
-
- - - - -
-
Butner Landfill, Granville Co.
Permit No. 39-02 Page 8 of 9
LaBella Associates

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Total Volatile Fatty Acids
12/19/07
mg/L
- -
2.50
69.10 51.70 17.90 - -
1.20
(sum of above 6 acids)
05/01/13
mg/L
- -
ND
ND ND - - -
ND
08/14/14
mg/L
- -
4.2 J
ND ND - - -
ND
03/10/15
mg/L
- -
ND
ND ND - - -
ND
08/18/15
mg/L
- -
ND
ND 0.97 J - - -
ND
02/16/16
mg/L
- -
ND
ND ND - - -
ND
08/09/16
mg/L
- -
-
ND ND - - -
-
02/13/17
mg/L
- -
-
- - - - -
-
08/22/17
mg/L
- -
-
- - - - -
-
02/05/18
mg/L
- -
-
- - - - -
-
08/13/18
mg/L
- -
-
- - - - -
-
02/04/19
mg/L
- -
-
- - - - -
-
08/06/19
mg/L
- -
-
1.32 1.94 - - -
-
02/12/20
mg/L
- -
-
- - -
-
08/27/20
mg/L
- -
5.43
49.70 5.40 - - -
5.66
02/11/21
mg/L
- -
-
- - - - -
-
NOTES:
DL = laboratory detection limit. mg/L = milligrams per liter
RL = laboratory reporting limit. my = millivolt
ND = not detected above detection limit. SU = standard unit
J = estimated concentration between the DL and the RL. nM = nano -Molar
- = not analyzed or not applicable.
°C = degress Celcius
pS/cm = micro-Siemen per centimeter
ntu = nephelometric turbidity units
Butner Landfill, Granville Co.
Permit No. 39-02 Page 9 of 9
LaBella Associates