5802_Madison_MSWLF_March21GW_FID1584539_20210528

ENR USE ONLY []Paper Report []Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
C DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste ReDortina Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information _
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Chuck Pippin Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Madison County Closed Solid 1389 Long Branch Road 58-02 .0500 March 3-4, 2021
Waste Facility Marshall, NC 28753
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring ❑X Detection Monitoring Assessment Monitoring Corrective Action
e of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data
Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify)
Leachate monitoring data
X Surface water monitoringdata Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Chuck Pippin, P.G. Project Manager 828-281-3350
Facility Representati a Title (Area Code) Telephone Number
5/19/21 Affix NC Licensed/ Professional Geologist Seal
Signature Date �pw��N1Nf �h
ar c M CA.e %-
231 Haywood Street Asheville, North Carolina 28801
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
SAL ` y
n
1587
05/19/21,�
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y4�,/4 S G • p�QQ p�
Revised 612009

May 2021
Madison County Closed Solid Waste Facility, Permit No. 58-02
Spring 2021
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

May 2021
Madison County Closed Solid Waste Facility, Permit No. 58-02
Spring 2021
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
Chuck Pippin, PG
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Melanie Kemp
Project Number: C01500-01.01
\\a sheville1\Asheville\Projects\Madison County\Reports\2021\01_Spring 2021\58-02 Closed\Senior Review\5802_Madison Closed -March 2021
Semiannual Water Quality Report.docx

TABLE OF CONTENTS
1 Introduction....................................................................................................................1
2 Methods......................................................................................................................... 2
2.1 Monitoring Well Sampling Methods......................................................................................................2
2.1.1 Monitoring Well BG SPRING OLD............................................................................................2
2.1.2 Monitoring Wells MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD .......... 2
2.2 Surface Water Sampling Methods..........................................................................................................3
2.3 Sample Handling, Documentation, and Analysis...............................................................................3
3 Findings..........................................................................................................................5
3.1 Groundwater.................................................................................................................................................5
3.1.1 Field Parameters............................................................................................................................6
3.1.2 RCRA Metals...................................................................................................................................6
3.1.3 Appendix I VOCs and 1,4-Dioxane..........................................................................................6
3.2 Surface Water................................................................................................................................................7
3.2.1 Field Parameters............................................................................................................................7
3.2.2 RCRA Metals...................................................................................................................................7
3.2.3 Appendix I VOCs and 1,4-Dioxane..........................................................................................7
3.3 Site Hydrogeology.......................................................................................................................................7
4 Summary........................................................................................................................9
4.1 Future Activities............................................................................................................................................9
5 References.....................................................................................................................10
TABLES
Table 1 Summaryof Laboratory Analyses Performed on Samples
Table 2 Summary of Detected Constituents
FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets
Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation
Spring 2021 Semiannual
Water Quality Monitoring Report i May 2021

ABBREVIATIONS
µg/L
micrograms per liter
µmhos/cm
micromhos per centimeter
Closed Landfill
closed municipal solid waste landfill
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
DWM
Division of Waste Management
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentration
MDL
method detection limit
mg/L
milligrams per liter
MRL
method reporting limit
mV
millivolt
NCAC
North Carolina Administrative Code
NTU
nephelometric turbidity unit
ORP
oxidation-reduction potential
RCRA
Resource Conservation and Recovery Act
SC
specific conductivity
SESD
EPA Region 4 Science and Ecosystem Support Division
SU
standard unit
SWS
Solid Waste Section
TOC
top of well casing
VOC
volatile organic compound
Spring 2021 Semiannual
Water Quality Monitoring Report ii May 2021

1 Introduction
The Madison County Solid Waste Department maintains a closed municipal solid waste landfill
(Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road
(State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1.
The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ),
Division of Waste Management (DWM), under Permit No. 58-02 (the permit), which requires
semiannual monitoring of groundwater and surface water quality. This report, prepared by
Anchor QEA of North Carolina, PLLC, is being submitted in accordance with monitoring requirements
for the Closed Landfill as stipulated in the permit, with regulations codified in the DEQ Solid Waste
Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina Administrative
Code (15A North Carolina Administrative Code [NCAC] 13B .1600).
This report describes the first semiannual groundwater and surface water quality monitoring event
performed in 2021. The water quality monitoring network for the Closed Landfill consists of four
monitoring wells (MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background
groundwater quality sampling location (BG SPRING OLD), and two surface water sampling locations
(SW-01 OLD [upstream] and SW-02 OLD [downstream]) located along Profitt Branch (Figure 2).
Monitoring wells MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the
western part of the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower
elevations within topographic drainages in the southern part of the landfill parcel and are screened
in the upper saturated zone.
The water sample collected from background sampling location BG SPRING OLD is treated as a
groundwater sample for the following reasons:
• Groundwater does not discharge to the ground surface at the sampling point.
• Construction of the sampling point is similar to that of a temporary monitoring well and is
located upslope and upgradient of a springhead.
• The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground
surface with a screened interval from which groundwater is collected and recharges.
Anchor QEA personnel attempted to contact the resident of the property owned by Mrs. J.V. Edwards
(99 Log Branch Road, Marshall, North Carolina) but were unsuccessful. Because of the unsuccessful
attempt to contact Mrs. Edwards, coupled with COVID-19 concerns, Anchor QEA did not collect a
sample from the residential well (DW-01 OLD) owned by Mrs. Edwards during the spring 2021
sampling event. Anchor QEA will coordinate with Madison County to ensure contact with the
Edwards family for the Fall 2021 sampling event.
Spring 2021 Semiannual
Water Quality Monitoring Report 1 May 2021

2 Methods
Groundwater samples and a surface water sample were collected at the Closed Landfill by
Anchor QEA personnel on March 3 and 4, 2021.
2.1 Monitoring Well Sampling Methods
Prior to groundwater sample collection from the monitoring wells, the static water level was
measured and recorded to calculate the volume of water within the well.
At each sample location, an initial round of field parameters (consisting of pH, specific conductivity
[SC], dissolved oxygen [DO], oxidation-reduction potential [ORP], turbidity, and temperature) was
measured and recorded. Water level measurements, field parameters, and observations pertaining to
water quality are included in the sampling logs in Appendix A.
2. 7. 7 Monitoring Well BG SPRING OLD
Due to poor well access, which inhibited the use of pump, controller, and associated tubing for
purging the well, sampling point BG SPRING OLD was purged using a new disposable polyethylene
bailer. Following initial field parameter collection, as each consecutive well volume was removed with
the bailer, a round of groundwater field parameters was recorded.
The well was purged until a minimum of three well volumes had been removed and field parameters
had stabilized, or until the well had been bailed dry. All groundwater samples were collected by a
technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into
laboratory -supplied sample containers.
2. 7.2 Monitoring Wells MW-0 7 OLD, MW-02 OLD, MW-03 OLD, and
MW-04 OLD
Monitoring wells MW-01 OLD and MW-02 OLD were purged and sampled with a peristaltic pump.
MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump. These wells were
purged using low -flow techniques in accordance with the procedures described in Low -Flow
(Minimal Drawdown) Ground -Water Sampling Procedures (Puts and Barcelona 1996).
During purging, pH, SC, DO, ORP, turbidity, and temperature were measured and recorded
approximately every 3 minutes. Well purging continued until these parameters had stabilized for
three consecutive readings. The following required stabilization criteria have been established by the
U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division
Operating Procedure: Groundwater Sampling (EPA SESD 2017):
• pH values within ± 0.1 unit
• SC values within ± 5%
Spring 2021 Semiannual
Water Quality Monitoring Report 2 May 2021

• Temperature, DO, and turbidity values within ± 10%
Following stabilization of these parameters, a groundwater sample was collected by a technician
wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into
laboratory -supplied sample containers.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 OLD and SW-02 OLD are collected semiannually at designated
locations along Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a
westerly direction (Figure 2). The surface water sample collected at the SW-01 OLD location is
interpreted to represent surface water quality upstream of the Closed Landfill, and the surface water
sample collected at the SW-02 OLD location is interpreted to represent surface water quality
downstream of the Closed Landfill.
For the samples SW-01 OLD and SW-02 OLD, field parameters, including temperature, pH, SC, DO,
ORP, and turbiditywere measured and recorded at the surface water sampling location priorto
sample collection (Appendix A). The one surface water sample was collected and transferred into
laboratory -supplied sample containers by a technician wearing a new pair of non -reactive nitrile gloves.
2.3 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to water quality sampling at the
Closed Landfill sampling locations are provided in the sampling logs in Appendix A.
Following sample collection, groundwater and surface water samples were immediately placed on ice
in sample coolers for transportto Waypoint Laboratories, Inc. (Waypoint), a laboratory certified in
North Carolina and located in Charlotte, North Carolina.
Anchor QEA submitted all collected groundwater and surface water samples to Waypoint for the
following analyses:
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260B
- Appendix I parameters are identified in Appendix I of the Code of Federal Regulations,
Title 40, Part 258 (40 Code of Federal Regulations 258).
• 1,4-Dioxane, using EPA Method 8260SIM
• Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6010D
and 7470A
- In addition to this "totals" metal analysis, if the associated turbidity was measured at a
value that exceeded 10 nephelometric turbidity units (NTU), the laboratory was
Spring 2021 Semiannual
Water Quality Monitoring Report 3 May 2021

requested to filter the associated sample, run the metals analysis, and report the
dissolved metal concentrations (in addition to the total metals analysis)
• Hardness, using EPA method SM2340C; surface water samples only
A summary of laboratory analyses performed on the samples is provided in Table 1.One trip blank,
provided bythe laboratory and stored in the sample cooler, was analyzed for Appendix I VOCs.
Proper chain -of -custody documentation procedures were followed during collection and transport of
each sample. The laboratory analytical reports and chain -of -custody documentation are included in
Appendix B.
Spring 2021 Semiannual
Water Quality Monitoring Report 4 May 2021

3 Findings
The field parameter data and laboratory analytical results for the groundwater, surface water, and
trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively,
and are also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable format (DEQ 2020).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections are values reported by the laboratory as "below method
detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The MDL is the
minimum concentration of a substance that can be measured and reported by a laboratory
with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "J" Qualified: A "J" qualifier is used by the laboratoryfor parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that
can be accurately determined by the referenced method.
• Groundwater Quality Standards: Detected concentrations of constituents in groundwater
samples were compared to applicable North Carolina groundwater quality standards. For
most constituents, this standard is the 2L standard, defined in 15A NCAC 02L .0202. Detected
concentrations of analytes in groundwater with no established 2L standard were compared to
the interim maximum allowable concentrations (IMAC) for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L .0202). For the purposes of this report, groundwater
standards were taken from the October 15, 2018 list published by the North Carolina SWS
(DEQ 2018).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 2 summarizes the field parameter results and laboratory analytical results for detected
constituents. The following discussion outlines constituents detected at concentrations that
exceeded their respective groundwater quality standards or 2B standards.
3.1 Groundwater
The following sections summarize the results of field parameter and laboratory analyses of
groundwater samples collected on March 3 and 4, 2021.
Spring 2021 Semiannual
Water Quality Monitoring Report 5 May 2021

3. 7. 7 Field Parameters
The pH reading obtained from monitoring wells MW-01 OLD (6.3 standard units [SU]), MW-03 OLD
(6.3 SU), MW-04 OLD (6.3 SU), and BG SPRING OLD (6.3 SU) were less than the range for pH (6.5 to
8.5 SU) specified in the 2L standard (Table 2). The pH readings obtained from monitoring well
MW-02 OLD (6.9 SU) was within the 2L standard.
Turbidity in the monitoring wells ranged from 4.12 NTU in monitoring well MW-03 OLD to 292 NTU
in BG SPRING OLD. Measured DO values ranged from 0.45 milligrams per liter (mg/L) in MW-01 OLD
to 5.78 mg/L in MW-02 OLD. SC values ranged from 131.2 micromhos per centimeter (pmhos/cm) in
BG SPRING OLD to 968 pmhos/cm in MW-03 OLD. ORP values in the monitoring wells ranged
from -88.5 millivolts (mV) in MW-03 OLD to 196.1 mV in BG SPRING OLD (Table 2). These parameters
do not have established groundwater quality standards.
The field parameters measured for this sampling event are generally consistent with historical data.
3. 7.2 RCRA Metals
Four metals (arsenic, barium, chromium, and lead) were detected in groundwater samples collected
from one or more monitoring wells (Table 2). Barium, was detected at concentrations that exceeded
its associated groundwater protection standard of 700 micrograms per liter (pg/L) in the samples
collected from MW-03 OLD (864 pg/L) and MW-04 OLD (736 pg/L). Chromium was detected at a
concentration that exceeded its associated groundwater protection standard of 10 pg/L in the
sample collected from BG SPRING OLD (11.2 pg/L). These findings are consistent with recent
historical data: in fall 2020, barium exceedances were reported in MW-03 OLD and MW-04 OLD.
In spring 2020, a chromium exceedance was reported in BG SPRING OLD.
Samples collected from BG SPRING OLD and MW-01 OLD were analyzed for laboratory -filtered
metals due to turbidity readings of greater than 10 NTU. In the samples collected and analyzed for
dissolved metals, only barium was detected above its MDLs, but below its 2L standard.
3. 7.3 Appendixl VOCs and 7,4-Dioxane
Twenty VOCs (1,1-dichloroethane; cis- 1,2-dichloroethene; trans-1,2-dichloroethene; 1,4-dioxane;
methyl butyl ketone; acetone; benzene; chlorobenzene; chloroethane; ethylbenzene, m,p-xylene,
methyl ethyl ketone, o-xylene, tetra hyd rofura n; toluene; total xylene; trichloroethene; vinyl chloride;
1,2-dichlorobenzene; and 1,4-dichlorobenzene) were detected in groundwater samples collected
from one or more of the monitoring wells (Table 2). Of the detected compounds, two (benzene and
vinyl chloride) were detected at concentrations that exceeded their associated groundwater quality
standard. Benzene was detected in monitoring well MW-03 OLD at a concentration of 2.37 pg/L,
above its 2L standard of 1 pg/L. Vinyl chloride was detected in monitoring well MW-01 OLD at a
concentration of 0.717 pg/L, which exceeded its 2L standard of 0.03 pg/L.
Spring 2021 Semiannual
Water Quality Monitoring Report 6 May 2021

The VOC detections are generally consistent with recent historical data. During the fall 2020
sampling event, vinyl chloride was also reported in MW-01 OLD at a concentration of 0.91 pg/L,
above its 2L standard. 1,4-Dioxane, which was detected in the fall 2020 above its 2L standard in
MW-01 OLD, was not detected during this sampling event. Benzene was detected in spring 2020
at 2 pg/L in exceedance of its 2L standard (1 pg/L) in MW-03 OLD (Anchor QEA 2020a; 2020b).
3.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 OLD and SW-02 OLD.
3.27 Field Parameters
The pH readings collected from SW-01 OLD and SW-02 OLD were 7.8 and 7.6 SU, respectively. The
readings were within the 2B standard range established at 6 to 9 SU. The turbidity readings collected
from SW-01 OLD and SW-02 OLD were 29.7 and 24.4 NTU, respectively. The readings were within the
2B standard established of less than 50 NTU. The DO readings collected from SW-01 OLD and SW-02
OLD were 11.54 and 11.35 mg/L, respectively. The values are within the 2B standard for Class C
waters (greater than or equal to 5 mg/L). The SC measurements in SW-01 OLD and SW-02 OLD were
recorded at 182 and 135.4 pmhos/cm, respectively. The ORP values for these samples were recorded
at 182.3 and 166.5 mV (Table 2). These parameters do not have established surface water quality
standards.
3.2.2 RCRA Metals
Four metals (arsenic, barium, chromium, and lead) were detected in the surface water samples. There
were no detections that exceeded 2B standards in either of the surface water samples.
3.2.3 Appendixl VOCs and 7,4-Dioxane
No VOCs were detected in either of the surface water samples.
3.3 Site Hydrogeology
Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD,
MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 5.02, 6.64, 35.75, and 37.55 feet
below the top of the well casing (TOC), respectively (Appendix A).
The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit
an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the
shallow groundwater is interpreted to generally mimic topography, flowing primarily southward
toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an
Spring 2021 Semiannual
Water Quality Monitoring Report 7 May 2021

elevation of approximately 2,100 feet above mean sea level and slopes downward toward
Profitt Branch.
Spring 2021 Semiannual
Water Quality Monitoring Report 8 May 2021

4 Summary
Anchor QEA completed the firsts emiannua I water quality monitoring event of 2021 at the
Closed Landfill on March 3 and 4, 2021. Table 1 summarizes the sampling and analyses that were
performed. Table 2, the field sampling logs (Appendix A), and the Waypoint Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and
surface water quality at the Closed Landfill. The following bullets summarize the results of the
sampling event:
• The detected concentration of barium exceeded its 2L standard of 700 pg/L in the samples
collected from two of the monitoring wells, MW-03 OLD (864 pg/L) and MW-04 OLD
(736 pg/L).
• The detected concentration of chromium exceeded its 2L standard of 10 pg/L in the sample
collected from BG SPRING OLD (11.2 pg/L).
• Benzene (2.37 pg/L) was detected in the sample collected from MW-01 OLD at a
concentration exceeding its associated groundwater quality standard (2L standards) of 1 pg/L.
• Vinyl chloride (0.717 pg/L) was detected in the sample collected from MW-03 OLD at a
concentration exceeding its associated groundwater quality standard (2L standards) of
0.03 pg/L.
• In the surface water samples, no metals were detected at concentrations that exceeded the
associated 2B standards. No VOCs were detected in the surface water samples.
• The measured depths to groundwater in the upper saturated zone within the topographic
drainages atthe landfill ranged from 5.02 to 6.64 feet below TOC. The groundwater depths in
the bedrock monitoring wells at top of the ridge ranged from 35.75 to 37.55 feet TOC. The
shallow groundwater is interpreted to generally mimic topography, flowing primarily
southward toward Profitt Branch.
4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater and surface water monitoring points associated with the Closed Landfill. Water quality
samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and
Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled
for October 2021.
Spring 2021 Semiannual
Water Quality Monitoring Report 9 May 2021

5 References
Anchor QEA (Anchor QEA of North Carolina, PLLC). 2020a. Fall 2020 Semiannual Water Quality
Monitoring Report, December 2020.
Anchor QEA (Anchor QEA of North Carolina, PLLC). 2020b. Spring 2020 Semiannual Water Quality
Monitoring Report, June 2020.
DEQ (North Carolina Department of Environmental Quality), 2018. "Groundwater Protection
Compliance Standards — Constituents List". Last modified October 15, 2018. Available at:
htti2s://edocs.deg.nc.gov/WasteManaciement/0/edoc/1257181/SWS EnviroMonitoring Const
ituents List. pdf?searchid=13f8efb1-eel 1-485a-b03f-718f2287b271
DEQ, 2020. Memorandum Re: New Electronic Data Deliverable (EDD) Format, July 20, 2020.
EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017.
Operating Procedure. Groundwater Sampling. April 26, 2017.
Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling
Procedures. Prepared for the U.S. Environmental Protection Agency, Office of Solid Waste and
Emergency Response. EPA/540/5-95/504. April 1996.
Spring 2021 Semiannual
Water Quality Monitoring Report 10 May 2021

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Facility Permit
Well ID
Collect Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
EPA 8260B
EPA 8260B SIM
EPA 6020B
EPA 7470A
58-02
MW-01 OLD
3/3/2021
MW-01 OLD-20210303
X
X
X
58-02
MW-02 OLD
3/3/2021
MW-02 OLD-20210303
X
X
X
58-02
MW-03 OLD
3/4/2021
MW-03 OLD-20210304
X
X
X
58-02
MW-04 OLD
3/4/2021
MW-04 OLD-20210304
X
X
X
58-02
BG SPRING OLD
3/3/2021
BG SPRING OLD-20210303
X
X
X
Surface Water Samples
Facility Permit
Location ID
Collect Date
Sample ID
Appendix I VOCs
1,4-Dioxane
RCRA Metals
Total Hardness
EPA 8260B
EPA 8260B SIM
EPA 6020B
EPA 7470A
EPA SM 2340C
58-02
SW-01 OLD
3/3/2021
SW-01 OLD-20210303
X
X
X
X
58-02
SW-02 OLD
3/3/2021
SW-02 OLD-20210303
X
X
X
X
Quality Control Samples
Facility Permit
ID
Collect Date
Sample ID
Appendix I VOCs
EPA 8260B
58-02
TRIP BLANK
3/4/2021
TB-202103040001
X
Notes:
Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258).
A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event.
EPA: U.S. Environmental Protection Agency
RCRA: Resource Conservation and Recovery Act
SM: standard method
SIM: selective ion monitoring
VOC: volatile organic compound
Spring 2021 Semiannual Water Quality Monitoring Report Page 1 of 1
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 May 2021

Table 2
Summary of Detected Constituents
Location ID
Sample ID
Sample Date
Sample Type
Matrix
X
Y
NC2L
Method NC21- IMAC NC213
Groundwater Samples
Surface Water
Samples
QC Sample
BG SPRING OLD
MW-01 OLD
MW-02 OLD
MW-03 OLD
MW-04 OLD
SW-01 OLD
SW-02 OLD
Field QC
BG SPRING OLD-
20210303
MW-01 OLD-
20210303
MW-02 OLD-
20210303
MW-03 OLD-
20210304
MW-04 OLD-
20210304
SW-01 OLD-
20210303
SW-02 OLD -
20210303
TB-202103040001
3/3/2021
3/3/2021
3/3/2021
3/4/2021
3/4/2021
3/3/2021
3/3/2021
3/4/2021
N
N
N
N
N
N
N
TB
WG
WG
WG
WG
WG
WS
WS
WQ
917884.7
917267.7
917989.3
917134.3
917135.2
918644.2
916592.4
768038.1
766244.6
765984.1
766754.9
766695.2
766458.9
766226.2
Field
Parameters
Water Level Depth (feet TOC)
Field Measure
--
--
--
3.97
5.02
6.64
35.75
37.55
--
--
Temperature (°C)
Field Measure
--
--
--
11
11.4
14.2
15
20.2
8.9
8.9
--
Dissolved oxygen (mg/L)
Field Measure
--
--
>_5.0
4.29
0.45
5.78
1.74
2.47
11.54
11.35
--
ORP (mV)
Field Measure
--
--
--
196.1
-14.6
192.1
-88.5
30.2
182.3
166.5
--
Turbidity (NTU)
Field Measure
--
--
<50
292
83.4
7.06
4.12
9.12
29.7
24.4
--
pH (SU)
Field Measure
6.5-8.5
--
6.0-9.0
6.3
6.3
6.9
6.3
6.3
7.8
7.6
--
Specific Conductivity (µmhos/cm)
Field Measure
--
--
--
131.2
599.3
232.6
968
890
182
135.4
--
Other (Ng/L)
Hardness as Cam,
SM2340C
--
-- -- -- -- -- --
-- 38 30 --
Metals (Ng/L)
Arsenic
SW6020
10
--
10
1.04
0.786 J
0.17 U
0.189 J
0.263 J
0.212 J
0.2 J
--
Barium
SW6020
700
--
21000
130
502
58.3
864
736
75.1
51
--
Chromium
SW6020
10
--
*38.01
11.2
0.79 U
0.79 U
0.79 U
0.79 U
2.83
1.73 J
--
Lead
SW6020
15
--
*1.03
2.89
0.26 U
0.26 U
0.26 U
0.38 J
0.467 J
0.467 J
--
Metals, Dissolved (Ng/L)
Barium
SW6020B
1 700
1
1 21000
1 60.6
1269
1--
--
--
61.8
44.4
--
Volatile
Organics (Ng/L)
1,1-Dichloroethane
SW8260D
6
--
100
0.083 U
0.456J
0.514
0.083 U
0.083 U
0.083 U
0.083 U
0.083 U
1,2-Dichloroethene, cis-
SW8260D
70
--
720
0.056 U
1.84
0.056 U
0.056 U
0.322 J
0.056 U
0.056 U
0.056 U
1,2-Dichloroethene, trans-
SW8260D
100
--
4000
0.094 U
0.209 J
0.094 U
0.094 U
0.094 U
0.094 U
0.094 U
0.094 U
1,4-Dioxane
SW8260DSIM
3
--
--
0.139 U
2.16
0.139 U
0.139 U
0.139 U
0.139 U
0.139 U
--
2-Hexanone (Methyl butyl ketone)
SW8260D
--
40
--
0.065 U
0.065 U
0.368 J
0.065 U
0.709 J
0.065 U
0.065 U
0.065 U
Acetone
SW8260D
6000
--
2000
0.31 U
0.31 U
0.31 U
0.31 U
1.8 J
0.31 U
0.31 U
1.85 J
Benzene
SW8260D
1
--
51
0.048 U
0.753
0.048 U
2.37
0.53
0.048 U
0.048 U
0.048 U
Chlorobenzene
SW8260D
50
--
140
0.062 U
2.46
0.062 U
7.76
3.51
0.062 U
0.062 U
0.062 U
Chloroethane
SW8260D
3000
--
--
0.22 U
0.616
0.22 U
0.525
1.27
0.22 U
0.22 U
0.22 U
Ethylbenzene
SW8260D
600
--
97
0.061 U
0.061 U
0.061 U
3.53
0.221 J
0.061 U
0.061 U
0.061 U
m,p-Xylene
SW8260D
500
--
550
0.12 U
0.12 U
0.12 U
0.494 J
0.87 J
0.12 U
0.12 U
0.12 U
Methyl ethyl ketone (2-Butanone)
SW8260D
4000
--
26000
0.24 U
0.24 U
0.886 J
0.24 U
1.92 J
0.24 U
0.24 U
0.24 U
o-Xylene
SW8260D
500
--
400
0.044 U
0.044 U
0.044 U
0.509
0.326 J
0.044 U
0.044 U
0.044 U
Tetrahydrofuran
SW8260D
--
--
--
1.1 U
1.1 U
1.1 U
1.1 U
1.52 J
1.1 U
1.1 U
1.1 U
Toluene
SW8260D
600
--
0.36
0.044 U
0.044 U
0.044 U
0.044 U
0.359 J
0.044 U
0.044 U
0.044 U
Total Xylene
SW8260D
--
--
--
0.044 U
0.044 U
0.044 U
1 J
1.2 J
0.044 U
0.044 U
0.044 U
Trichloroethene (TCE)
I SW8260D
1 3
1
30
0.078 U
0.311 J
0.292 J
0.078 U
0.078 U
0.078 U
0.078 U
0.078 U
Vinyl chloride
I SW8260D
1 0.03
1
2.4
1 0.097 U
0.717
0.097 U
0.097 U
0.097 U
0.097 U
0.097 U
0.097 U
Semivolatile Organics (Ng/L)
Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 May 2021

Table 2
Summary of Detected Constituents
Location ID
Sample ID
Sample Date
Sample Type
Matrix
X
Y
NC2L
Method NC2L IMAC NC2B
Groundwater Samples
Surface Water
Samples
QC Sample
BG SPRING OLD
MW-01 OLD
MW-02 OLD
MW-03 OLD
MW-04 OLD
SW-01 OLD
SW-02 OLD
Field QC
BG SPRING OLD-
20210303
MW-01 OLD-
20210303
MW-02 OLD-
20210303
MW-03 OLD-
20210304
MW-04 OLD-
20210304
SW-01 OLD-
20210303
SW-02 OLD -
20210303
TB-202103040001
3/3/2021
3/3/2021
3/3/2021
3/4/2021
3/4/2021
3/3/2021
3/3/2021
3/4/2021
N
N
N
N
N
N
N
TB
WG
WG
WG
WG
WG
WS
WS
WQ
917884.7
917267.7
917989.3
917134.3
917135.2
918644.2
916592.4
768038.1
766244.6
765984.1
766754.9
766695.2
766458.9
766226.2
1,2-Dichlorobenzene
SW8260D
1 20
1 -
--
0.076 U
0.421 J
0.076 U
0.203 J
0.076 U
0.076 U
0.076 U
0.076 U
1,4-Dichlorobenzene
SW8260D
1 6
1 --
1 56
0.05 U
3.16
0.05 U
4.07
1.04
0.05 U
0.05 U
0.05 U
N otes:
Detected concentration is greater than NC2L (2013) or IMAC (2013) screening level
Detected concentration is greater than NC213 screening level
Bold: Detected result
Italicized: The non -detect concentration limit is above one or more identified screening levels
*: NC213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality,
Ng/L: micrograms per liter
NC213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 213 — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for Aquatic
NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A.
All nondetect results are reported at the method detection limit.
Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (U.S. Survey Feet).
°C: degrees Celsius
pg/LL micrograms per liter
pmhos/cm: micromhos per centimeter
CaCO3: calcium carbonate
IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L.
J: laboratory qualifier used to indicate a detection at estimated concentrations greater than the minimum detection limit (MDL) but less than the laboratory's method reporting limit (MRL)
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NTU: nephelometric turbidity unit
ORP: oxidation-reduction potential
SU: standard unit
TB: Trip Blank
TOC: top of casing
U: Compound analyzed for, but not detected above detection limit
WG: groundwater
WS: surface water
WQ: water quality
Spring 2020 Semiannual Water Quality Monitoring Report Page 2 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 May 2021

Table 2
Summary of Detected Constituents
Notes:
Detected concentration is greater than NC2L (2013) or IMAC (2013) screening level
Detected concentration is greater than NC26 screening level
Bold: Detected result
Italicized: Non -detected concentration is above one or more identified screening levels
*: NC213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality,
Subchapter 213 - Surface Water and Wetland Standards (last amended September 2017).
Ng/L: micrograms per liter
NC213: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 213 — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for Aquatic
Life and Human Health.
NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A.
All nondetect results are reported at the method detection limit.
Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258
Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (U.S. Survey Feet).
°C: degrees Celsius
Ng/LL micrograms per liter
pmhos/cm: micromhos per centimeter
CaCO3: calcium carbonate
IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L.
J: laboratory qualifier used to indicate a detection at estimated concentrations greater than the minimum detection limit (MDL) but less than the laboratory's method reporting limit (MRL)
mg/L: milligrams per liter
mv: millivolts
N: normal environmental sample
NTU: nephelometric turbidity unit
ORP: oxidation-reduction potential
SU: standard unit
TB: Trip Blank
TOC: top of casing
U: Compound analyzed for, but not detected above detection limit
WG: groundwater
WS: surface water
WQ: water quality
Spring 2020 Semiannual Water Quality Monitoring Report Page 3 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 May 2021

Figures

AR YJI/V C�
Semn
O -
I
12
^C�11HL
v (t
Y.
• �� I r +moo "� � � O • —
f
f l , also
LEGEND: SOURCES:
Basemap: USGS 1:24,000 Scale Topo Maps, "000
® Landfill Parcel Marshall Quadrangle, 1990
Parcels: Madison County GIS Feet
Publish Date: 2021/03/24, 8:34 AM I User: alesueur
Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1 500\Maps\2021\SpringWaterQuality\AQ_F01_SiteLocationMap_ClosedLF_SpringWQ2021.mxd
ANCHOR Figure 1
QEA- Site Location Map
Anchor QEA of North Carolina, PLLC
Spring 2021 Semiannual Water Quality Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02

w IF
a '< ties
g
�
MW-03 OLD
LEGEND:
NOTE:
Monitoring well and surface water samples are
Monitoring Well Location
0 Landfill Parcel Boundary
approximate.
0
Elevation Contours
Residential Well Location
(10-Foot Interval)
SOURCES:
(Not Sampled in Spring 2020
Basemap: NC OneMap 2018
because Owner Could Not
— Roads
Contours and Roads: NCDOT
0 400
be Contacted)
— Streams
Streams: NC OneMap
Parcel Boundary: Madison County GIS
Surface Water Sample Location
Feet
Publish Date: 2021/03/24, 4:12 PM I User: alesueur
Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1 500\Maps\2021\SpringWaterQuality\AQ_F02_SampleLocationMap_ClosedLF_SpringWQ2021.mxd
ANCHOR
Figure 2
QEA�`�.;"
Anchor QEA of North Carolina, PLLC
Sample Location Map
Spring 2021 Semiannual Water Quality Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02

AppendixA
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

,� ANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Low -Flow Sampling Log
well ID: MW-01 OLD
Project Name:
Project Number.
Project Location:
Sample Collector(s):
Well Diameter:
Screen Interval:
Well Depth (as constructed):
Depth to Water:
Measuring Point:
Depth of Pump Intake:
Pump Used (circle):
Comments:
Madison County Closed Landfill
C01500-01.01
Marshall, NC
S G
2
NSA
20.8
5. U a..
TOC
17
Peristaltic Bladder
C Gp� 6eAa 1'4 /Z�
�—
Date:
Weather:
Facility ID or Permit # (if applicable):
_ Sample ID (on COQ:
in Arrive at Well:
ft bgs Start Time:
ft bgs Sample Time:
ft Leave Well:
Well Type:
ft Tagged Bottom:
Other (describe):
Q �_
513171
506�"
58-02
MW-01 OLD- ZO-24 0 30'5
Z
j 3
o
A ick Up ❑Flush Mount
a� ft at (time): l� .
Purge Rate: Z'04
Total Volume Purged:
Pump Speed:
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S. U.
Oxidation
Reduction
Potential (mN)
Turbidity (NTU)
tr24,3
Sr35
1 k,
613
6r
2 t
over c4%—,
I rz-10
11f6
0"6'r
Co1,j7
".?
-s:C
696
►53
72-
V l - 7
0,17
Yq . 5"
' 3
--'1 z-.Z
1 4
15�5`
F-w;'�Sr
i.
O.fY
1
6.3
-ts.
1,7
S3
f, 72
L5-k4 3
6­ 3
Sample Analyst Signature:
Sample Analyst
Name:
YKV�,L
Date: '3r
Notes: V ..
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity; +/- 0.7 pH unit,• +/- 70 MV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original tent is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 NS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv. millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

Anchor QEA of North Carc.'na, PLLC
,. ANCHOR
QED
231 Haywcod Street
Asheville, North Carolina 28801
I aw-Flow Sampling Log
C,(&
Well ID: MW-02 bi lk
Project Name: Madison County ZloeVl5ng Landfill
Project Number: C01500-01.01
Project Location: Marshall, NC
Sample Collector(s):�r S('
Well Diameter. 2 mqk_
Screen Interval:.--' N
Well Depth (as constructed):
Depth to Water: �r yl f�
Measuring Point: TOC
Depth of Pump Intake: G
Pump Used (circle): i� Peristaltic Bladder
Comments: _
Date:
Facility ID or Permit # (if applicable):
Sample ID (on COQ:
in Arrive at Well:
ft bgs Start Time:
ft bgs Sample Time:
ft Leave Well:
Well Type:
ft Tagged Bottom:
Other (describe):
5 3
Weather.
58-01
MW-02- �1i(
14 00
_N I5
i- -
, fl
❑Stick Up ❑Flush Mount Stick up
(.�?J�� ft at (time): t.
Purge Rate:j111+�
Total Volume Purged:
Pump Speed:
Time
DTW (feet)
Temperature (°C)
Dissolved Oxygen
(mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
report to 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity (NTU)
1141
1q,
Y -
a3 _
t
,
qA
uss
i
o
a33,�
i
tY
1494
q. 3
ILt;�
5 85
9-31)1-1
�i `/
. l to
Jq
17- 3
0� 3
yt,
14133
IF
�L
Sample Analyst Signature:
—
Sample Analyst
Name: '! V��'
Date: �✓ :a
Notes:
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- a i pH unit, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mV: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA
Anchor QEA of North Carclina, PLLC
231 Haywood Street
Asheville, North Caro;ina 28801
w-Flow Sampling Log
Well ID: MW-03 OLD
Project Name:
Madison County Closed Landfill
Date:
Project Number:
C01500-01.01
—
Weather.
Project Location:
Marshall, NC
Facility ID or Permit # (if applicable):
58-02
Sample Collector(s): �L�
Sample ID (on COQ:
MW-03 OLD -
Well Diameter:
2
in
Arrive at Well:
64150
Screen Interval:
44 - 49
ft bgs
Start Time:
L
Well Depth (as constructed):
49
ft bgs
Sample Time:
Depth to Water.
ft
Leave Well:
16 5 C
Measuring Point:
TOC
Well Type:
AStick Up
oFlush Mount
Depth of Pump Intake:
45
ft
Tagged Bottom:
ft
at (time):
i
Pump Used (circle):
Peristaltic Bladder
Other (describe):
Purge Rate -
Comments:
�+' `'
}�
Total Volume Purged: cv
l VC
Pump Speed:
(7 Tt r
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
DTw (feet)
Temperature ('C)
(mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (m1)
Turbidity (NTU)
0
5.3
6151
3
-- 4.
1013
, (
.a
w
.�
-:.IS,
Y
At,
55
i i
,3�"441
D
I '
5
3
- 5.
'3.16OS
�,
-: a-
, 0-
3LD
16,
to 7
n
-1/
I a.
'2 3
�37-
Sample Analyst Signature:
_
Sample Analyst
Name:
Date:
et��
y�
Notes
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3%Conductivity, +/- 0.7 pH unit +/- 10 mV forORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original tent is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number SU5
5. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
a -
Page 1

ANCHOR
QEA'
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
r ^w-Flow Sampling Log
Well ID: MW-04 OLD
Project Name:
Madison County Closed Landfill
Date:
Project Number:
C01500-01.01
Weather.
[r a S
Project Location:
Marshall, NC
Facility ID or Permit # (if applicable):
58-02
Sample Collector(s):
Y-1 ,Srj
Sample ID (on COC):
MW-04 OLD-
1�4O3
Well Diameter.
Z
_
in
Arrive at Well:
Screen Interval:
70 - 90
ft bgs
Start Time:
I 1 l g
Well Depth (as constructed):
90
ft bgs
Sample Time:
' 5'
Depth to Water:
';-. -5 2
ft
Leave Well:
12 z V
Measuring Point:
TOC
Well Type:
NStick Up
❑Flush Mount
Depth of Pump Intake:
S0
ft
Tagged Bottom:
�� . 1 ft
at (time):
Pump Used (circle):
Peristaltic
Bladder
Other (describe):
Purge Rater
Comments:
�,�,(,� r
i ` F r rcw:— a" W-414
ice—
Total Volume Purged:
_
—
— —
Pump Speed:
f ' 6 i- 097
Specific
Oxidation
Dissolved Oxygen
Conductivity
pH (S.U.)
Reduction
Time
(feet)
Temperature ('C)
(mg/L)
(pp'mhos/cm)
report 0.1 S.U.
Potential (m1)
Turbidity (NTU)
`
(DTW
tto
�_
c
I�
Tir-
(
ll.7
he
c
%'_
S~,
iXV
.3i, f
zo. 9
`7 a
q0i
C
2.
7t,3
37.fi
I$,-
-S_ ,` V
�trv_
611 1
-7.3A
i i 3r
'3Z q
17, ;L
6. Jt
Z0, 5'
s _
tk:36
37,q
1,9, i
'S. ly
SN
6.1
2.3. Y
8
�
f I (1
t 6/. 4-1
3.00
i!?�'
6.
ire
3•
IR
.Y�
� �
Z'S.
1el,
2, 2
Y9
6,
ASS
Q -
1(`1
Z�� j--
Z. 7
'? et, v
J
Sample Analyst Signature:
Sample Analyst
Name:
r
Date:
1 �L
3 4
Notes: tir ---
I
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity, +/- 3% Conductivity; +/- 0.7 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
S. 1 pmho/cm = 1 pS/cm
Abbreviations:
Method Reference:
°C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter ft: feet
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOC: top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

kZANCHOR
QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Well Sampling Log
(Well ID: BG SPRING OLD
f Projed Name:
Madison County Closed Landfill
Date:
Project Number.
C01500-01.01
Weather.
a �S
ProjectLocation:
Marshall, NC Facility
ID or Permit # (if applicable):
58-02
Sample Collector(s):
"V�(CalI./
Sample ID (on COC):
BG SPRING OLD- ft?10 6a
Well Diameter.
2 in
Sample Time:
Screen Interval:
N/A ft bgs
Measuring Point:
TOC
Well Depth (WD):
14.3
ft TOC
Well Type:
I§Stick Up ❑Flush Mount
Water Level in Feet (WLy.
r�
ft TOC
Comments:
r (a,,6VAuq KLw
Length of Water Column (LWQ:
l Q A33
ft; (WD - WL)
One Casing Volume:
gallons; (LWC x WCV)
Three Casing Volumes:
5
gallons
Actual Volume Purged:
gallons
Tagged Bottom:
ft at (time): 1301
Three Casing Volumes:
gallons
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Gal 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft
8" = 2.61 Gal/Ft
12" = 5.87 Gal/Ft
Purge Method:
[Bailer-DispjBailer-Teflon
Bailer -Di sp Bailer -Teflon Dedicated Pump
Whale Pump Grundfos
Other.
Sample Method:
Dedicated Pump
Whale Pumo Grundfos
Other*
Oxidation
Dissolved
Specific
pH (S.U.)
Reduction
Gallons
Temperature
Oxygen
Conductivity
report to 0.1
Potential
Turbidity
Reading
Time
Purged
VC)
(mg/L)
(pmhos/cm)
S.U.
(m{)
(NTU)
Comments
1
t (r l
,-: 1 1
3
63
226 , C
Z6,,
2
r
I I I
ZO
3
I zs'Z
�►o
uc 7
5', , 0
Co.
2n 7.
3 O
4
12- LZ
11110
1'Z11
(3'tZ
3
` Fir
z�tZ
5
�G 0 w
7
8
9
10
Sampling Container
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
1 L Glass
Other
Protective Casing: Pad:
Sample Analysts
Signature: ti
Number of Containers
Lock: Vegetation: Access:
Analysts
Name:
Requested Analysis
`� Vvr q Date: 03
Notes
1: Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,, +/- 3% Conductivity, +/- 0.1 pH unit,, +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017)
2. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
3. Samples are analyzed immediately upon collection.
4. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
'C: degrees Celsius S.U.: standard units
Temperature: SM 2550 B-2010
ymhos/cm: micromhos per centimeter ft: feet
Specific conductivity. EPA Method 120.1, Rev. 1982
mg/L: milligrams per liter in: inches
DO: SM 4500 O G-2011
mv: millivolt bgs: below ground surface
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units TOO top of casing
Turbidity: SM 2130 B-2011
Page 1 of 1

e-
li
ANCHOR
.., QEA
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Surface Water Sampling Log
Location ID: SW-01 OLD
Project Name: Madison County Closed Landfill
Project Number: C01500-01.01
Project Location: Marshall, NC
Sample Collector(s): AY- /"' SL
Comments: Upstream of landfill ^
Date: Q 3lp 3
Weather: �jC9S
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): SW-01 OLD- Oqrto30?j
Sample Method (circle
one):
Grab Syringe
Pump
Bailer-Disp. Other:
Time
Temperature
VC)
Dissolved
Oxygen (mg/L)
Specific
Conductivity
(pmhos/cm)
pH (S.U.)
reportto 0.1 S.U.
Oxidation
Reduction
Potential (mV)
Turbidity
(NTU)
Comments
Hq2'
tV,C,>
�, g
1-9Z
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastici�-
250 mL Plastic
�����W+'�� I�t/V`C�►'II.V
125 mL Plastic
40 mL Glass
o. S
1 L Glass
law
Other
Vegetation: 00405
05
Access: l7 I�
01 Sample Analyst J Sample Analyst Signature: ��f Name: 1-2,/� - (c/ PL° J Date
Notes:
1. Documentation errors are to be crossed out with a single line. so the oriainal text is still leaible, followed by the staff members initials and date
2. Samples are analyzed immediately upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
Method Reference:
°C: degrees Celsius
Temperature: SM 2550 B-2010
pmhos/cm: micromhos per centimeter
Specific conductivity: EPA Method 120.1, Rev. 1982
mg/L milligrams per liter
DO: SM 4500 O G-2011
mV: millivolt
pH: SM 4500-H' B-2011
NTU: nephelometric turbidity units
Turbiditv: SM 2130 B-2011
S.U.: standard units
Page 1 of 1

It Pl-
ANCHOR
QEA
Surface Water Sampling Log
Project Name: Madison County Closed Landfill
Project Number: C01500-01.01
Project Location: Marshall, NC
Sample Collector(s): Y yn 5
Comments: Downstream of landfill
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Location ID: SW-02 OLD
Date:
Weather: �lj�t.Vl pJ
Facility ID or Permit # (if applicable): 58-02
Sample ID (on COC): SW-02 OLD- anima rya 03
f Sample Method (circle
Ij one):
Grab
Syringe
Pump
Bailer-Disp. Other.
Specific
Oxidation
Temperature
Dissolved
Conductivity
pH (S.U.)
Reduction Turbidity
Time VQ
Oxygen (mg/L)
(pmhos/cm)
report to 0.1 S.U.
Potential (m1) (NTU) Comments
Sampling Container
Number of Containers
Requested Analysis
500 mL Plastic
250 mL Plastic
T-
125 mL Plastic
40 mi. Glass
a-o o, g"9q—e,6 Si OPU
1 L Glass
Other
Vegetation: U�/1r n,�
Ypvfj�
Access:N i
Sample Analyst Signature:
Sample Analyst
Name:
Date: -3)3/
1. Documentation errors are tb be fi�ossed out with a sinale line. so the orioinal text is still leaible. followed by the staff members initials and date
2. Samples are analyzed imm�c[ ely upon collection.
3. NC Field Laboratory Certificate Number 5445
Abbreviations:
°C: degrees Celsius
pmhos/cm: micromhos per centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 0 G-2011
PH: SM 4500-H* B-2011
Turbiditv: SM 2130 B-2011
Page 1 of 1

Qo�
ANCHOR.
QEA YC14VJ
Project Name Maalson county Operating Landfill
ProjectNumber. C01500-01.01
Project Location: Marshall, NC
Facility ID or Permit # (if applicable): 58-01
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
Select Turbidimeter. Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Analyst Conducting Calibration:
Date of Calibration:
Date of Field Measurements:
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Instrument Readings
Instrument Readings
(Hach 21000)
(HF Scientific MicroTPW)
Cal Std Information
10 NTU
20 NTU
100 NTU
800 NTU
1,000 NTU
10.0 NTU
0.02 NTU
r
c
Expiration Date
(
I ( '
Cal (NTU): 9` v f3
Cal (NTU):
Cal (NTU): [fir
S
Cal (NTU):
Cal (NTU):
Cal (NTU):_
,� Time: r „
Time: 06 ��
Time:
bb '
Time:
Time:
rime:
Calibration
*Pre -Analysis
Result (NTU):
I D
Time:
3T
*Pre -Analysis
Result (NTU):
Time:
Verification:
Check (10 NTU):
r
Check (10 NTU):
*Post -Analysis
ResultINTU):
Time:
*Post -Analysis
Result (NTU):
Time:
Check (10 NTU):
1 l
6&�'�
Check [ 10 NTU):
YSI Professional Plus Multiparameter Meter (s/n 188101802)
Cal Std Information
Instrument Readings
Date
Lot#
Open
Exp. Date
Dissolved Oxygen
Initial (%):
`
Cal (%: �� ��
mmHg:
Temperature ('C):
Time: c
4
(% saturation
24,
r
DO (Site #2,
Initial (%:
I
Cal M: ,
mmH
Temp.Rrature (°C):
Time:
if a licable *
ed,
IiQW.A 1 `��.
l
Result (%):I �M `�
Time:
Result (%):
Time:
Result (%):
Initial.*,,, �
pHmV,.
Cal (S.U):Il
pHmV: �a�
Time: _5�c,
py�y
1,t.Lc t
ppHo0.1
report to 0.1 S.U.iJ�
'�
J
i
pH o S.0.1
report to0.1S.U.
Initial:
LA t�
pHmV:
Cal (S.U. `
pHmV: J
bic I
Time:
�
�40+
tit/
`�Y(J
�l(�
pH 10 S.U.
Initial:
pHmV: �j
`1 "{.
Cal (S.Ll
pHmV:
Time,-,,7
t
report to0.7S.U.
o
rD
QC** pH 7 S.U.
report to 0.1 S.U.
Time:
l(l
Result (S.U.):
It,r
Time: (�
�- ''J
Result (S.U.):
•D��
Time,
Result (S.U.):
Spec. Cond.
Initial:
p
l
Cal (pmhos/cm):
t.
Time: y
G
CGF
1,000 mhos/cm
l V
I"
1
% Recove =
s
QC** Spec Cond.
Time: �(
Result (p°m�hooss/cm):
Timte�
Result (pmhos/s/cm):
Time:
Result (pmhos/cm):
1,000 pmhos/cm
% Recove =
ORP 200 mV
Initial:
b3. 47
Cal:
• �r
Temperature (yC):
Time: % �j
/�
rem
VV ✓
.'-e'
✓'�
Analyst Signature: "/f � I Analyst Name: irKd (.rvv i-t '�'��0 Date: 5 ) TDI'31
Notes:.. --
Revision 6, 12/20/20, MAK
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows : Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. *when performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at
each sample site prior to analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value, If QC readings are out of range, the
instrument needs to be recalibrated.
6. ** QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot # as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm , True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pm ho/cm = 1 pS/cm
Abbreviations:
Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units
Temperature: SM 2550 B-2010
°C: degrees Celsius ORP: oxidation reduction potential
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: dissolved oxygen s/n: serial number
DO: SM 4500 0 G-2011
mg/L• milligrams per liter S.U.: standard units
pH: SM 4500-H' B-2011
mv: millivolt Spec. Cond.: Specific Conductivity
Turbidity: SM 2130 B-2011
Page 1 of 1

ANCHOR
QEA
Project Name: Madison County Closed Landfill Analyst Conducting Calibration:
Project Number: C01500-01.01 Date of Calibration:
Project Location: Marshall, NC Date of Field Measurements:
Facility ID or Permit # (if applicable): 58-02
EQUIPMENT DOCUMENTATION
Rental sample analysis equipment or meters used to take measurements:
ullment Type I Brand I Serial Number I Date of Use I Rental Companv f
Select Turbidimeter.
Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Instrument Readings
Instrument
(Hach 2100Q)
(HF Scientific
Cal Still Information
10 NTU
20 NTU 100 NTU
800 NTU
11000 NTU
10.0 NTU
Lot #:
a 3 171
Expiration Date:
(,(
(.(.
Cal (NTU): Cal (NT :
Cal (NT ):
Cal (NTU):
Cal (NTU):
Time: 03• Time:
J J
V J
Time: 3
C�
Time:
Time:
Calibration
"Pre -Analysis
Result (NTU): Time:
-
'Pre -Analysis
Result
Verification:
Check (10 NTU):
A 30
Check (1NT 0 U):
"Post -Analysis
Result (NTU): Time:; ..
'Post-Analysi
Result (NTU):
Check (10 NTU):
Check ( TU):
YSI Professional Plus Multiparameter Meter (s/n 8101802)
Instrument Readings
Dissolved Oxygen
(% saturation)
Initial (%):
Cal M:h�
mmHg:
Temp rature (°Q:
Time:
DO (Site #2,
if a lira ble •
Initial (%):
Cal (%):q ^ G
U
mmH
�y
Tempe*ature):
(r _ 7
Time: l rt /fir (,
V V "f
Time: �
1 1
Resu{tia Y`
of "l D
Time:
ResulA
,
Time: .� f Result (%):
O K
pH 7 S.U.
report to 0.1 S.U.
Initial: h
�t d
pHmV: ,
Cal ISU ):
1,
pHmV:
'.�-3—i if
Time:
.
PH 4 S.U.
report to0.1S.U.,�
Initia'
pHmV: 1] h
Cal (S.U),
pHmV-
Time:
3
pH 10 S.U.
report to0.1S.U.
Initial://��
v1
pHmV: j /�
�4 �"( •3
Cal (S.U.): O
pHmV:
Timer
QC" pH 7 S.U.
rer-ort to 0.1 S.U.
Time: b
Fs
Resul U.:
. b
Tim
Result .Ulf
Time: Result (S.U.):
Spec. Cond.
Initial:
r
Cal (pmhos/cm):
Time: "]G
1,000 mhos/cm
`� ✓o
�J
% Recovery=
QC" Spec. Cond.
Time:
Result0{lmhos/cm):
(y V 3 QI
Time: � � �
'-'r
Result (pmhos/ m):
� �
Time: Result (pmhos/cm):
1,000 pmhos/cm
�
% Recovery= 1
1 0 " 6-
ORP 200 mV
Initial:
l q-4,5
Cal: �/�]�
g U0 , 0
Temperature (IC):
IS, S
Time: ]
J? z
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
0.02
(NTU):
Cal Std Information
Lot # ..� � Exp.
4al
Wo
Analyst Signature: Analyst Name: CW6 Mt,� -�p Date: 3r1+
Notes f
Revision 6, 12/20/20, J00eAK
1. Instruments shall be calibrated in accordance with the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows : Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks.
4. •When performing DO analyses at multiple sample sites (i.e. project/facility locations), the DO probe must be calibrated at each sample site priorto analysis.
5. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
6. — QC check must be performed prior to sampling and following completion of sampling, at a minimum. QC checks must be performed with calibration standard from a separate lot as the initial QC.
7. % Recovery = (Value Obtained, pmhos/cm + True Value, pmhos/cm) x 100
8. NC Field Laboratory Certificate Number 5445
9. Documentation errors are to be crossed out with a single line, so the original text is still legible, followed by the staff members initials and date
10. Unless otherwise noted, all DO calibrations and measurements are performed at 0 ppt Salinity.
11. 1 pmho/cm = 1 PS/cm i
Abbreviations: Method Reference:
pmhos/cm: micromhos per centimeter NTU: nephelometric turbidity units Temperature: SM 2550 B-2010
'C., degrees Celsius ORP: oxidation reduction potential Specific conductivity. EPA Method 120.1, Rev. 1962
DO: dissolved oxygen s/n: serial number DO: SM 4500 O G-2011
mg/L: milligrams per liter S.U.: standard units pH: SM 4500-H' B-2011
mV: millivolt Spec. Cond.: Specific Conductivity Turbidity. SM 2130 B 2011
5J�
Page 1 of 1

Appendix
Report of Laboratory Analysis and
Chain -of -Custody Documentation

Waypointo
ANALYTICAL
3/22/2021
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville, NC, 28801
449 5pringbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Ref: Analytical Testing
Lab Report Number: 21-064-0025
Client Project Description: Madison County Closed LF
Site: 58-02
Project Number: 58-02
Dear Chuck Pippin:
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/5/2021 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2012) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
a,j
Angela D Overcash
Senior Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 54

Waypoint.0
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2021
North Carolina
State Program
402
12/31/2021
South Carolina
State Program
99012
07/31/2021
South Carolina
State Program
99012
12/31/2020
Page 1 of 1 00016/21-064-0025
Page 2 of 54

Waypoint.(2)
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointana lyti ca Isom
Sample Summary Table
Report Number: 21-064-0025
Client Project Description: Madison County Closed LF
Lab No Client Sample ID Matrix Date Collected Date Received
93978
MW-01 OLD-20210303
Aqueous
03/03/2021
15:38
03/05/2021
09:40
93979
MW-02 OLD-20210303
Aqueous
03/03/2021
14:33
03/05/2021
09:40
93980
MW-03 OLD-20210304
Aqueous
03/04/2021
10:37
03/05/2021
09:40
93981
MW-04 OLD-20210304
Aqueous
03/04/2021
11:48
03/05/2021
09:40
93982
BG SPRING OLD-20210303
Aqueous
03/03/2021
12:57
03/05/2021
09:40
93983
SW-01 OLD-20210303
Aqueous
03/03/2021
14:42
03/05/2021
09:40
93984
SW-02 OLD-20210303
Aqueous
03/03/2021
13:24
03/05/2021
09:40
93985
TB-202103040001
Aqueous
03/04/2021
13:00
03/05/2021
09:40
Page 3 of 54

Waypoint. (2)
449 Springbrook
Rd, Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.waypointana lyti ca I som
Summary of Detected Analytes
Project:
Madison County Closed LF
Report Number:
21-064-0025
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-01
V 93978
OLD-20210303
6020B
Arsenic
0.786
pq/L
0.170
03/08/202122:52
J
6020B
Barium
502
Ng/L
0.810
03/08/202122:52
6020B
Dissolved Barium
269
pq/L
0.810
03/12/2021 23:49
8260D
Benzene
0.753
pg/L
0.048
03/09/202115:22
8260D
Chlorobenzene
2.46
pq/L
0.062
03/09/202115:22
8260D
Chloroethane
0.616
pg/L
0.220
03/09/202115:22
8260D
1,2-Dichlorobenzene
0.421
pq/L
0.076
03/09/202115:22
J
8260D
1,4-Dichlorobenzene
3.16
pg/L
0.050
03/09/202115:22
8260D
1,1-Dichloroethane
0.456
pq/L
0.083
03/09/202115:22
J
8260D
cis- 1,2-Dichloroethene
1.84
pg/L
0.056
03/09/202115:22
8260D
trans-1,2-Dichloroethene
0.209
pq/L
0.094
03/09/202115:22
J
8260D
Trichloroethene
0.311
pg/L
0.078
03/09/202115:22
J
8260D
Vinyl Chloride
0.717
pq/L
0.097
03/09/2021 15:22
8260D SIM
1,4-Dioxane
2.16
Ng/L
0.139
03/08/2021 17:16
MW-02
V 93979
OLD-20210303
6020B
Barium
58.3
pq/L
0.810
03/08/202123:30
8260D
1,1-Dichloroethane
0.514
Ng/L
0.083
03/09/202115:45
8260D
2-Hexanone
0.368
pq/L
0.065
03/09/202115:45
J
8260D
Methyl Ethyl Ketone (MEK)
0.886
Ng/L
0.240
03/09/2021 15:45
J
8260D
Trichloroethene
0.292
pq/L
0.078
03/09/202115:45
J
MW-03
V 93980
OLD-20210304
6020B
Arsenic
0.189
Ng/L
0.170
03/09/202100:02
J
6020B
Barium
864
pq/L
0.810
03/09/202100:02
8260D
Benzene
2.37
pg/L
0.048
03/09/202116:09
8260D
Chlorobenzene
7.76
pq/L
0.062
03/09/202116:09
8260D
Chloroethane
0.525
pg/L
0.220
03/09/202116:09
8260D
1,2-Dichlorobenzene
0.203
pq/L
0.076
03/09/202116:09
J
8260D
1,4-Dichlorobenzene
4.07
pg/L
0.050
03/09/202116:09
8260D
Ethylbenzene
3.53
pq/L
0.061
03/09/202116:09
8260D
o-Xylene
0.509
pg/L
0.044
03/09/202116:09
8260D
m,p-Xylene
0.494
pq/L
0.120
03/09/202116:09
J
8260D
Xylene (Total)
1.00
Ng/L
0.044
03/09/2021 16:09
J
MW-04
V 93981
OLD-20210304
6020B
Arsenic
0.263
pq/L
0.170
03/09/202100:09
J
6020B
Barium
736
Ng/L
0.810
03/09/202100:09
Page 4 of 54

Waypoint. (2)
449 Springbrook
Rd, Charlotte, NC
28217
Main 704.529.6364
ANALYTICAL
www.waypointana lyti ca I som
Summary of Detected Analytes
Project:
Madison County Closed LF
Report Number:
21-064-0025
Client Sample ID
Lab Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed
Qualifiers
MW-04
V 93981
OLD-20210304
6020B
Lead
0.380
pq/L
0.260
03/09/202100:09
J
8260D
Acetone
1.80
Ng/L
0.310
03/09/2021 16:33
J
8260D
Benzene
0.530
pq/L
0.048
03/09/2021 16:33
8260D
Chlorobenzene
3.51
pg/L
0.062
03/09/2021 16:33
8260D
Chloroethane
1.27
pq/L
0.220
03/09/2021 16:33
8260D
1,4-Dichlorobenzene
1.04
pg/L
0.050
03/09/2021 16:33
8260D
cis-1,2-Dichloroethene
0.322
pq/L
0.056
03/09/2021 16:33
J
8260D
Ethylbenzene
0.221
pg/L
0.061
03/09/2021 16:33
J
8260D
2-Hexanone
0.709
pq/L
0.065
03/09/2021 16:33
J
8260D
Methyl Ethyl Ketone (MEK)
1.92
pg/L
0.240
03/09/2021 16:33
J
8260D
Tetrahydrofuran
1.52
pq/L
1.10
03/09/2021 16:33
J
8260D
Toluene
0.359
pg/L
0.044
03/09/2021 16:33
J
8260D
o-Xylene
0.326
pq/L
0.044
03/09/2021 16:33
J
8260D
m,p-Xylene
0.870
Ng/L
0.120
03/09/2021 16:33
J
8260D
Xylene (Total)
1.20
pg/L
0.044
03/09/2021 16:33
J
BG SPRING
V 93982
OLD-20210303
6020B
Arsenic
1.04
Ng/L
0.170
03/09/202100:15
6020B
Barium
130
pq/L
0.810
03/09/202100:15
6020B
Dissolved Barium
60.6
Ng/L
0.810
03/12/2021 23:55
6020B
Chromium
11.2
pq/L
0.790
03/09/202100:15
6020B
Lead
2.89
Ng/L
0.260
03/09/202100:15
SW-01
V 93983
OLD-20210303
2340C-2011
Hardness
48000
pq/L
1140
03/11/2021 12:00
6020B
Arsenic
0.212
Ng/L
0.170
03/09/202100:22
J
6020B
Barium
75.1
pq/L
0.810
03/09/202100:22
6020B
Dissolved Barium
61.8
pg/L
0.810
03/13/2021 00:02
6020B
Chromium
2.83
pq/L
0.790
03/09/202100:22
6020B
Lead
0.467
pg/L
0.260
03/09/202100:22
J
SW-02
V 93984
OLD-20210303
2340C-2011
Hardness
40500
pq/L
570
03/11/2021 12:00
6020B
Arsenic
0.200
Ng/L
0.170
03/09/202100:28
J
6020B
Barium
51.0
pq/L
0.810
03/09/202100:28
6020B
Dissolved Barium
44.4
Ng/L
0.810
03/13/2021 00:21
6020B
Chromium
1.73
pq/L
0.790
03/09/202100:28
J
6020B
Lead
0.467
Ng/L
0.260
03/09/202100:28
J
Page 5 of 54

Waypoint. (2) 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointana lyti ca I som
Summary of Detected Analytes
Project: Madison County Closed LF
Report Number: 21-064-0025
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
TB-202103040001 V 93985
8260D Acetone
1.85 uq/L
0.310 03/09/202114:58 J
Page 6 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93978
Sample ID: MW-01 OLD-20210303
Matrix: Aqueous
Sampled: 3/3/2021 15:38
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Arsenic
0.7863
Ng/L
0.170
1.00
1
03/08/2122:52
MMR
6020E
Dissolved Arsenic
<0.170
ug/L
0.170
1.00
1
03/12/21 23:49
MMR
6020B
Barium
502
Ng/L
0.810
10.0
1
03/08/2122:52
MMR
6020E
Dissolved Barium
269
ug/L
0.810
10.0
1
03/12/21 23:49
MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/08/2122:52
MMR
6020E
Dissolved Cadmium
<0.160
ug/L
0.160
1.00
1
03/12/21 23:49
MMR
6020B
Chromium
<0.790
Ng/L
0.790
2.00
1
03/08/2122:52
MMR
6020E
Dissolved Chromium
<0.790
ug/L
0.790
2.00
1
03/12/21 23:49
MMR
6020B
Lead
<0.260
Ng/L
0.260
1.00
1
03/08/2122:52
MMR
6020E
Dissolved Lead
<0.260
ug/L
0.260
1.00
1
03/12/21 23:49
MMR
6020B
Mercury (Total)
<0.0500
Ng/L
0.0500
0.300
1
03/09/21 17:03
EDV
7470A
Dissolved Mercury
<0.0300
ug/L
0.0300
0.200
1
03/15/21 14:51
EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/09/2122:43
MMR
6020E
Dissolved Selenium
<0.740
ug/L
0.740
5.00
1
03/12/21 23:49
MMR
6020B
Silver
<0.110
Ng/L
0.110
1.00
1
03/08/2122:52
MMR
6020E
Dissolved Silver
<0.110
ug/L
0.110
1.00
1
03/12/21 23:49
MMR
6020B
1,4-Dioxane
2.16
Ng/L
0.139
2.00
1
03/08/21 17:16
TBL
8260D SIM
Surrogate:4-Bromofluorobenzene
96.4
Limits:70-130%
1 03/08/2117:16 TBL
V1363
Qualifiers/ DF Dilution Factor
Definitions L Limit Exceeded
J Estimated value
MQL Method Quantitation Limit
Page 7 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93978
Matrix: Aqueous
Sample ID: MW-01 OLD-20210303
Sampled:
3/3/2021 15:38
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 15:22
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 15:22
JLB
V1489
Benzene
0.753
Ng/L
0.048
0.500
1
03/09/21 15:22
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 15:22
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 15:22
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 15:22
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 15:22
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 15:22
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 15:22
JLB
V1489
Chlorobenzene
2.46
ug/L
0.062
0.500
1
03/09/21 15:22
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 15:22
JLB
V1489
Chloroethane
0.616
ug/L
0.220
0.500
1
03/09/21 15:22
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 15:22
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 15:22
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 15:22
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
ug/L
0.170
2.00
1
03/09/21 15:22
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 15:22
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 15:22
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 15:22
JLB
V1489
1,2-Dichlorobenzene
0.4213
pg/L
0.076
0.500
1
03/09/21 15:22
JLB
V1489
1,4-Dichlorobenzene
3.16
Ng/L
0.050
0.500
1
03/09/21 15:22
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 15:22
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 8 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93978
Matrix: Aqueous
Sample ID: MW-01 OLD-20210303
Sampled:
3/3/2021 15:38
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.4563
Ng/L
0.083
0.500
1
03/09/21 15:22
JLB
V1489
1,2-Dichloroethane
<0.066
pg/L
0.066
0.500
1
03/09/21 15:22
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 15:22
JLB
V1489
cis- 1,2-Dich loroethene
1.84
pg/L
0.056
0.500
1
03/09/21 15:22
JLB
V1489
trans-1,2-Dichloroethene
0.2093
Ng/L
0.094
0.500
1
03/09/21 15:22
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 15:22
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 15:22
JLB
V1489
trans-1,3-Dichloropropene
<0.070
pg/L
0.070
0.500
1
03/09/21 15:22
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 15:22
JLB
V1489
Ethylbenzene
<0.061
pg/L
0.061
0.500
1
03/09/21 15:22
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 15:22
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
pg/L
0.240
5.00
1
03/09/21 15:22
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 15:22
JLB
V1489
Methylene Chloride
<0.083
pg/L
0.083
1.00
1
03/09/21 15:22
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 15:22
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
pg/L
0.110
0.500
1
03/09/21 15:22
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 15:22
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 15:22
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 15:22
JLB
V1489
Toluene
<0.044
pg/L
0.044
0.500
1
03/09/21 15:22
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 15:22
JLB
V1489
1,1,2-Trichloroethane
<0.066
pg/L
0.066
0.500
1
03/09/21 15:22
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 9 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025
Lab No : 93978
Sample ID: MW-01 OLD-20210303
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 3/3/2021 15:38
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
0.3113
Ng/L
0.078
0.500
1
03/09/21 15:22 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062
0.500
1
03/09/21 15:22 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140
1.00
1
03/09/21 15:22 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060
2.00
1
03/09/21 15:22 JLB
V1489
Vinyl Chloride
0.717
Ng/L
0.097
0.500
1
03/09/21 15:22 JLB
V1489
o-Xylene
<0.044
ug/L
0.044
0.500
1
03/09/21 15:22 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120
1.00
1
03/09/21 15:22 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044
0.500
1
03/09/21 15:22
V1489
Surrogate:4-Bromofluorobenzene
100
Limits:80-124%
1 03/09/21 15:22 JLB
V1489
Surrogate: Dibromofluoromethane
102
Limits:
75-129%
1 03/09/21 15:22 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
95.2
Limits:
63-136%
1 03/09/21 15:22 JLB
V1489
Surrogate: Toluene-d8
98.4
Limits:
77-123%
1 03/09/21 15:22 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 10 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93979
Sample ID: MW-02 OLD-20210303
Matrix: Aqueous
Sampled: 3/3/2021 14:33
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Arsenic
<0.170
Ng/L
0.170
1.00
1
03/08/2123:30 MMR
6020E
Barium
58.3
ug/L
0.810
10.0
1
03/08/2123:30 MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/08/2123:30 MMR
6020E
Chromium
<0.790
ug/L
0.790
2.00
1
03/08/2123:30 MMR
6020B
Lead
<0.260
Ng/L
0.260
1.00
1
03/08/2123:30 MMR
6020E
Mercury (Total)
<0.0500
ug/L
0.0500
0.300
1
03/09/21 17:07 EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/09/2123:22 MMR
6020E
Silver
<0.110
ug/L
0.110
1.00
1
03/08/2123:30 MMR
6020B
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/08/21 17:41 TBL
8260D SIM
Surrogate: 4- Bromofl uo ro benzene
108
Limits:70-130%
1 03/08/2117:41 TBL
V1363
Qualifiers/ DF Dilution Factor
Definitions L Limit Exceeded
J Estimated value
MQL Method Quantitation Limit
Page 11 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93979
Matrix: Aqueous
Sample ID: MW-02 OLD-20210303
Sampled:
3/3/2021 14:33
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 15:45
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 15:45
JLB
V1489
Benzene
<0.048
Ng/L
0.048
0.500
1
03/09/21 15:45
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 15:45
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 15:45
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 15:45
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 15:45
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 15:45
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 15:45
JLB
V1489
Chlorobenzene
<0.062
ug/L
0.062
0.500
1
03/09/21 15:45
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 15:45
JLB
V1489
Chloroethane
<0.220
ug/L
0.220
0.500
1
03/09/21 15:45
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 15:45
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 15:45
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 15:45
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
pg/L
0.170
2.00
1
03/09/21 15:45
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 15:45
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 15:45
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 15:45
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 15:45
JLB
V1489
1,4-Dichlorobenzene
<0.050
Ng/L
0.050
0.500
1
03/09/21 15:45
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 15:45
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 12 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93979
Matrix: Aqueous
Sample ID: MW-02 OLD-20210303
Sampled:
3/3/2021 14:33
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
0.514
Ng/L
0.083
0.500
1
03/09/21 15:45
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 15:45
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 15:45
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 15:45
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 15:45
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 15:45
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 15:45
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 15:45
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 15:45
JLB
V1489
Ethylbenzene
<0.061
ug/L
0.061
0.500
1
03/09/21 15:45
JLB
V1489
2-Hexanone
0.3683
Ng/L
0.065
5.00
1
03/09/21 15:45
JLB
V1489
Methyl Ethyl Ketone (MEK)
0.8863
ug/L
0.240
5.00
1
03/09/21 15:45
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 15:45
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 15:45
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 15:45
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
ug/L
0.110
0.500
1
03/09/21 15:45
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 15:45
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 15:45
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 15:45
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 15:45
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 15:45
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 15:45
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 13 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025
Lab No : 93979
Sample ID: MW-02 OLD-20210303
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 3/3/2021 14:33
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
0.2923
Ng/L
0.078
0.500
1
03/09/21 15:45 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062
0.500
1
03/09/21 15:45 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140
1.00
1
03/09/21 15:45 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060
2.00
1
03/09/21 15:45 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097
0.500
1
03/09/21 15:45 JLB
V1489
o-Xylene
<0.044
ug/L
0.044
0.500
1
03/09/21 15:45 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120
1.00
1
03/09/21 15:45 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044
0.500
1
03/09/21 15:45
V1489
Surrogate:4-Bromofluorobenzene
99.8
Limits:80-124%
1 03/09/21 15:45 JLB
V1489
Surrogate: Dibromofluoromethane
101
Limits:
75-129%
1 03/09/21 15:45 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
94.4
Limits:
63-136%
1 03/09/21 15:45 JLB
V1489
Surrogate: Toluene-d8
98.2
Limits:
77-123%
1 03/09/21 15:45 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 14 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93980
Sample ID: MW-03 OLD-20210304
Matrix: Aqueous
Sampled: 3/4/2021 10:37
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Arsenic
0.1893
Ng/L
0.170
1.00
1
03/09/2100:02 MMR
6020E
Barium
864
ug/L
0.810
10.0
1
03/09/2100:02 MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/09/2100:02 MMR
6020E
Chromium
<0.790
ug/L
0.790
2.00
1
03/09/2100:02 MMR
6020B
Lead
<0.260
Ng/L
0.260
1.00
1
03/09/2100:02 MMR
6020E
Mercury (Total)
<0.0500
ug/L
0.0500
0.300
1
03/09/21 17:10 EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/09/2123:47 MMR
6020E
Silver
<0.110
ug/L
0.110
1.00
1
03/09/2100:02 MMR
6020B
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/08/21 18:06 TBL
8260D SIM
Surrogate: 4- Bromofl uo ro benzene
112
Limits:70-130%
1 03/08/2118:06 TBL
V1363
Qualifiers/ DF Dilution Factor
Definitions L Limit Exceeded
J Estimated value
MQL Method Quantitation Limit
Page 15 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93980
Matrix: Aqueous
Sample ID: MW-03 OLD-20210304
Sampled:
3/4/2021 10:37
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 16:09
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 16:09
JLB
V1489
Benzene
2.37
Ng/L
0.048
0.500
1
03/09/21 16:09
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 16:09
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 16:09
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 16:09
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 16:09
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 16:09
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 16:09
JLB
V1489
Chlorobenzene
7.76
ug/L
0.062
0.500
1
03/09/21 16:09
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 16:09
JLB
V1489
Chloroethane
0.525
ug/L
0.220
0.500
1
03/09/21 16:09
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 16:09
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 16:09
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 16:09
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
ug/L
0.170
2.00
1
03/09/21 16:09
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 16:09
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 16:09
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 16:09
JLB
V1489
1,2-Dichlorobenzene
0.2033
pg/L
0.076
0.500
1
03/09/21 16:09
JLB
V1489
1,4-Dichlorobenzene
4.07
Ng/L
0.050
0.500
1
03/09/21 16:09
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 16:09
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 16 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93980
Matrix: Aqueous
Sample ID: MW-03 OLD-20210304
Sampled:
3/4/2021 10:37
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:09
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:09
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:09
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 16:09
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 16:09
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 16:09
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 16:09
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 16:09
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 16:09
JLB
V1489
Ethylbenzene
3.53
ug/L
0.061
0.500
1
03/09/21 16:09
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 16:09
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
ug/L
0.240
5.00
1
03/09/21 16:09
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 16:09
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 16:09
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 16:09
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
ug/L
0.110
0.500
1
03/09/21 16:09
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 16:09
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 16:09
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 16:09
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 16:09
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 16:09
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:09
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 17 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025
Lab No : 93980
Sample ID: MW-03 OLD-20210304
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 3/4/2021 10:37
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.078
Ng/L
0.078
0.500
1
03/09/21 16:09 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062
0.500
1
03/09/21 16:09 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140
1.00
1
03/09/21 16:09 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060
2.00
1
03/09/21 16:09 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097
0.500
1
03/09/21 16:09 JLB
V1489
o-Xylene
0.509
ug/L
0.044
0.500
1
03/09/21 16:09 JLB
V1489
m,p-Xylene
0.4943
Ng/L
0.120
1.00
1
03/09/21 16:09 JLB
V1489
Xylene (Total)
1.003
ug/L
0.044
0.500
1
03/09/21 16:09
V1489
Surrogate:4-Bromofluorobenzene
100
Limits:80-124%
1 03/09/21 16:09 JLB
V1489
Surrogate: Dibromofluoromethane
99.4
Limits:
75-129%
1 03/09/21 16:09 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
95.4
Limits:
63-136%
1 03/09/21 16:09 JLB
V1489
Surrogate: Toluene-d8
98.8
Limits:
77-123%
1 03/09/21 16:09 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 18 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93981
Sample ID : MW-04 OLD-20210304
Matrix: Aqueous
Sampled: 3/4/2021 11:48
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Method
Arsenic
0.2633
Ng/L
0.170
1.00
1
03/09/2100:09 MMR
6020E
Barium
736
ug/L
0.810
10.0
1
03/09/2100:09 MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/09/2100:09 MMR
6020E
Chromium
<0.790
ug/L
0.790
2.00
1
03/09/2100:09 MMR
6020B
Lead
0.3803
Ng/L
0.260
1.00
1
03/09/2100:09 MMR
6020E
Mercury (Total)
<0.0500
ug/L
0.0500
0.300
1
03/09/21 17:14 EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/09/2123:54 MMR
6020E
Silver
<0.110
ug/L
0.110
1.00
1
03/09/2100:09 MMR
6020B
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/08/21 18:32 TBL
8260D SIM
Surrogate: 4- Bromofl uo ro benzene
110
Limits:70-130%
1 03/08/2118:32 TBL
V1363
Qualifiers/ DF Dilution Factor
Definitions L Limit Exceeded
J Estimated value
MQL Method Quantitation Limit
Page 19 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93981
Matrix: Aqueous
Sample ID : MW-04 OLD-20210304
Sampled:
3/4/2021 11:48
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
1.803
Ng/L
0.310
5.00
1
03/09/21 16:33
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 16:33
JLB
V1489
Benzene
0.530
Ng/L
0.048
0.500
1
03/09/21 16:33
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 16:33
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 16:33
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 16:33
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 16:33
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 16:33
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 16:33
JLB
V1489
Chlorobenzene
3.51
ug/L
0.062
0.500
1
03/09/21 16:33
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 16:33
JLB
V1489
Chloroethane
1.27
ug/L
0.220
0.500
1
03/09/21 16:33
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 16:33
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 16:33
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 16:33
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
ug/L
0.170
2.00
1
03/09/21 16:33
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 16:33
JLB
V1489
Dibromomethane
<0.065
ug/L
0.065
0.500
1
03/09/21 16:33
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 16:33
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 16:33
JLB
V1489
1,4-Dichlorobenzene
1.04
Ng/L
0.050
0.500
1
03/09/21 16:33
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 16:33
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 20 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93981
Matrix: Aqueous
Sample ID : MW-04 OLD-20210304
Sampled:
3/4/2021 11:48
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:33
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:33
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:33
JLB
V1489
cis- 1,2-Dich loroethene
0.3223
ug/L
0.056
0.500
1
03/09/21 16:33
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 16:33
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 16:33
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 16:33
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 16:33
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 16:33
JLB
V1489
Ethylbenzene
0.2213
ug/L
0.061
0.500
1
03/09/21 16:33
JLB
V1489
2-Hexanone
0.7093
Ng/L
0.065
5.00
1
03/09/21 16:33
JLB
V1489
Methyl Ethyl Ketone (MEK)
1.921
ug/L
0.240
5.00
1
03/09/21 16:33
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 16:33
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 16:33
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 16:33
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
ug/L
0.110
0.500
1
03/09/21 16:33
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 16:33
JLB
V1489
Tetrachloroethene
<0.098
ug/L
0.098
0.500
1
03/09/21 16:33
JLB
V1489
Tetrahydrofuran
1.523
Ng/L
1.10
10.0
1
03/09/21 16:33
JLB
V1489
Toluene
0.3593
ug/L
0.044
0.500
1
03/09/21 16:33
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 16:33
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:33
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 21 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025
Lab No : 93981
Sample ID : MW-04 OLD-20210304
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 3/4/2021 11:48
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.078
Ng/L
0.078
0.500
1
03/09/21 16:33 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062
0.500
1
03/09/21 16:33 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140
1.00
1
03/09/21 16:33 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060
2.00
1
03/09/21 16:33 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097
0.500
1
03/09/21 16:33 JLB
V1489
o-Xylene
0.3263
ug/L
0.044
0.500
1
03/09/21 16:33 JLB
V1489
m,p-Xylene
0.8703
Ng/L
0.120
1.00
1
03/09/21 16:33 JLB
V1489
Xylene (Total)
1.203
ug/L
0.044
0.500
1
03/09/21 16:33
V1489
Surrogate:4-Bromofluorobenzene
99.4
Limits:80-124%
1 03/09/21 16:33 JLB
V1489
Surrogate: Dibromofluoromethane
99.0
Limits:
75-129%
1 03/09/21 16:33 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
92.6
Limits:
63-136%
1 03/09/21 16:33 JLB
V1489
Surrogate: Toluene-d8
99.2
Limits:
77-123%
1 03/09/21 16:33 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 22 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93982
Sample ID: BG SPRING OLD-20210303
Matrix: Aqueous
Sampled: 3/3/2021 12:57
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Arsenic
1.04
Ng/L
0.170
1.00
1
03/09/2100:15
MMR
6020E
Dissolved Arsenic
<0.170
ug/L
0.170
1.00
1
03/12/21 23:55
MMR
6020B
Barium
130
Ng/L
0.810
10.0
1
03/09/2100:15
MMR
6020E
Dissolved Barium
60.6
ug/L
0.810
10.0
1
03/12/21 23:55
MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/09/2100:15
MMR
6020E
Dissolved Cadmium
<0.160
ug/L
0.160
1.00
1
03/12/21 23:55
MMR
6020B
Chromium
11.2
Ng/L
0.790
2.00
1
03/09/2100:15
MMR
6020E
Dissolved Chromium
<0.790
ug/L
0.790
2.00
1
03/12/21 23:55
MMR
6020B
Lead
2.89
Ng/L
0.260
1.00
1
03/09/2100:15
MMR
6020E
Dissolved Lead
<0.260
ug/L
0.260
1.00
1
03/12/21 23:55
MMR
6020B
Mercury (Total)
<0.0500
Ng/L
0.0500
0.300
1
03/09/21 17:18
EDV
7470A
Dissolved Mercury
<0.0300
ug/L
0.0300
0.200
1
03/15/21 14:55
EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/10/2100:00
MMR
6020E
Dissolved Selenium
<0.740
ug/L
0.740
5.00
1
03/12/21 23:55
MMR
6020B
Silver
<0.110
Ng/L
0.110
1.00
1
03/09/2100:15
MMR
6020E
Dissolved Silver
<0.110
ug/L
0.110
1.00
1
03/12/21 23:55
MMR
6020B
1,4-Dioxane
<0.139
Ng/L
0.139
2.00
1
03/08/21 18:57
TBL
8260D SIM
Surrogate: 4- Bromofl uo ro benzene
104
Limits:70-130%
1 03/08/2118:57 TBL
V1363
Qualifiers/ DF Dilution Factor
Definitions L Limit Exceeded
I Estimated value
MQL Method Quantitation Limit
Page 23 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93982
Matrix: Aqueous
Sample ID: BG SPRING OLD-20210303
Sampled:
3/3/2021 12:57
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 16:56
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 16:56
JLB
V1489
Benzene
<0.048
Ng/L
0.048
0.500
1
03/09/21 16:56
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 16:56
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 16:56
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 16:56
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 16:56
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 16:56
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 16:56
JLB
V1489
Chlorobenzene
<0.062
ug/L
0.062
0.500
1
03/09/21 16:56
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 16:56
JLB
V1489
Chloroethane
<0.220
ug/L
0.220
0.500
1
03/09/21 16:56
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 16:56
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 16:56
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 16:56
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
pg/L
0.170
2.00
1
03/09/21 16:56
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 16:56
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 16:56
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 16:56
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 16:56
JLB
V1489
1,4-Dichlorobenzene
<0.050
Ng/L
0.050
0.500
1
03/09/21 16:56
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 16:56
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 24 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93982
Matrix: Aqueous
Sample ID: BG SPRING OLD-20210303
Sampled:
3/3/2021 12:57
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:56
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:56
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 16:56
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 16:56
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 16:56
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 16:56
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 16:56
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 16:56
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 16:56
JLB
V1489
Ethylbenzene
<0.061
ug/L
0.061
0.500
1
03/09/21 16:56
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 16:56
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
ug/L
0.240
5.00
1
03/09/21 16:56
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 16:56
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 16:56
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 16:56
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
pg/L
0.110
0.500
1
03/09/21 16:56
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 16:56
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 16:56
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 16:56
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 16:56
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 16:56
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 16:56
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 25 of 54

•
Waypdint0 449 Springbrook Rd, Charlotte, .5 282&
Main 704.529.636�
ANALYTICAL
01015
Anchor QEA of North Carolina, PLLC
Chuck Pippin
231 Haywood Street
Asheville , NC 28801
www.waypointana lyti ca Isom
Project ID :
Project Madison County Closed LF
Report Date : 03/22/2021
Information : Received : 03/05/2021
Report Number : 21-064-0025
Lab No : 93982
Sample ID: BG SPRING OLD-20210303
REPOR T OF A NA L YSIS
Matrix: Aqueous
Sampled: 3/3/2021 12:57
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time By
Analytical
Analyzed
Batch
Trichloroethene
<0.078
Ng/L
0.078
0.500
1
03/09/21 16:56 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062
0.500
1
03/09/21 16:56 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140
1.00
1
03/09/21 16:56 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060
2.00
1
03/09/21 16:56 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097
0.500
1
03/09/21 16:56 JLB
V1489
o-Xylene
<0.044
ug/L
0.044
0.500
1
03/09/21 16:56 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120
1.00
1
03/09/21 16:56 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044
0.500
1
03/09/21 16:56
V1489
Surrogate:4-Bromofluorobenzene
97.8
Limits:80-124%
1 03/09/21 16:56 JLB
V1489
Surrogate: Dibromofluoromethane
98.8
Limits:
75-129%
1 03/09/21 16:56 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
96.0
Limits:
63-136%
1 03/09/21 16:56 JLB
V1489
Surrogate: Toluene-d8
98.2
Limits:
77-123%
1 03/09/21 16:56 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 26 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025
REPORT OF ANAL YSIS
Lab No : 93983
Matrix: Aqueous
Sample ID: SW-01 OLD-20210303
Sampled:
3/3/2021 14:42
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Arsenic
0.2123
Ng/L
0.170
1.00
1
03/09/2100:22
MMR
6020E
Dissolved Arsenic
<0.170
ug/L
0.170
1.00
1
03/13/21 00:02
MMR
6020B
Barium
75.1
Ng/L
0.810
10.0
1
03/09/2100:22
MMR
6020E
Dissolved Barium
61.8
ug/L
0.810
10.0
1
03/13/21 00:02
MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/09/2100:22
MMR
6020E
Dissolved Cadmium
<0.160
ug/L
0.160
1.00
1
03/13/21 00:02
MMR
6020B
Chromium
2.83
Ng/L
0.790
2.00
1
03/09/2100:22
MMR
6020E
Dissolved Chromium
<0.790
ug/L
0.790
2.00
1
03/13/21 00:02
MMR
6020B
Lead
0.4673
Ng/L
0.260
1.00
1
03/09/2100:22
MMR
6020E
Dissolved Lead
<0.260
ug/L
0.260
1.00
1
03/13/21 00:02
MMR
6020B
Mercury (Total)
<0.0500
Ng/L
0.0500
0.300
1
03/09/21 17:22
EDV
7470A
Dissolved Mercury
<0.0300
ug/L
0.0300
0.200
1
03/15/21 14:59
EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/10/2100:20
MMR
6020E
Dissolved Selenium
<0.740
ug/L
0.740
5.00
1
03/13/21 00:02
MMR
6020B
Silver
<0.110
Ng/L
0.110
1.00
1
03/09/2100:22
MMR
6020E
Dissolved Silver
<0.110
ug/L
0.110
1.00
1
03/13/21 00:02
MMR
6020B
Hardness
48000
Ng/L
1140
10000
1
03/11/21 12:00
SLS
2340C-2011
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
03/08/21 19:22
TBL
8260D SIM
Surrogate:4-Bromofluorobenzene
108
Limits:70-130%
1 03/08/2119:22 TBL
V1363
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions L Limit Exceeded
MQL
Method Quantitation Limit
Page 27 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93983
Matrix: Aqueous
Sample ID: SW-01 OLD-20210303
Sampled:
3/3/2021 14:42
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 17:20
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 17:20
JLB
V1489
Benzene
<0.048
Ng/L
0.048
0.500
1
03/09/21 17:20
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 17:20
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 17:20
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 17:20
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 17:20
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 17:20
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 17:20
JLB
V1489
Chlorobenzene
<0.062
ug/L
0.062
0.500
1
03/09/21 17:20
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 17:20
JLB
V1489
Chloroethane
<0.220
ug/L
0.220
0.500
1
03/09/21 17:20
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 17:20
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 17:20
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 17:20
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
pg/L
0.170
2.00
1
03/09/21 17:20
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 17:20
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 17:20
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 17:20
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 17:20
JLB
V1489
1,4-Dichlorobenzene
<0.050
Ng/L
0.050
0.500
1
03/09/21 17:20
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 17:20
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 28 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93983
Matrix: Aqueous
Sample ID: SW-01 OLD-20210303
Sampled:
3/3/2021 14:42
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 17:20
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 17:20
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 17:20
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 17:20
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 17:20
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 17:20
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 17:20
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 17:20
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 17:20
JLB
V1489
Ethylbenzene
<0.061
ug/L
0.061
0.500
1
03/09/21 17:20
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 17:20
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
ug/L
0.240
5.00
1
03/09/21 17:20
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 17:20
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 17:20
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 17:20
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
pg/L
0.110
0.500
1
03/09/21 17:20
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 17:20
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 17:20
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 17:20
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 17:20
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 17:20
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 17:20
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 29 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93983 Matrix: Aqueous
Sample ID: SW-01 OLD-20210303 Sampled: 3/3/2021 14:42
Analytical Method: 8260D Prep Batch(es): V1488 03/09/21 09:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Trichloroethene
<0.078
Ng/L
0.078 0.500
1
03/09/21 17:20 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062 0.500
1
03/09/21 17:20 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140 1.00
1
03/09/21 17:20 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060 2.00
1
03/09/21 17:20 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097 0.500
1
03/09/21 17:20 JLB
V1489
o-Xylene
<0.044
ug/L
0.044 0.500
1
03/09/21 17:20 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120 1.00
1
03/09/21 17:20 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044 0.500
1
03/09/21 17:20
V1489
Surrogate:4-Bromofluorobenzene
99.0
Limits:80-124%
1 03/09/21 17:20 JLB
V1489
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 03/09/21 17:20 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
96.6
Limits: 63-136%
1 03/09/21 17:20 JLB
V1489
Surrogate: Toluene-d8
98.2
Limits: 77-123%
1 03/09/21 17:20 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 30 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025
REPORT OF ANAL YSIS
Lab No : 93984
Matrix: Aqueous
Sample ID: SW-02 OLD-20210303
Sampled:
3/3/2021 13:24
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Arsenic
0.2003
Ng/L
0.170
1.00
1
03/09/2100:28
MMR
6020E
Dissolved Arsenic
<0.170
ug/L
0.170
1.00
1
03/13/21 00:21
MMR
6020B
Barium
51.0
Ng/L
0.810
10.0
1
03/09/2100:28
MMR
6020E
Dissolved Barium
44.4
ug/L
0.810
10.0
1
03/13/21 00:21
MMR
6020B
Cadmium
<0.160
Ng/L
0.160
1.00
1
03/09/2100:28
MMR
6020E
Dissolved Cadmium
<0.160
ug/L
0.160
1.00
1
03/13/21 00:21
MMR
6020B
Chromium
1.733
Ng/L
0.790
2.00
1
03/09/2100:28
MMR
6020E
Dissolved Chromium
<0.790
ug/L
0.790
2.00
1
03/13/21 00:21
MMR
6020B
Lead
0.4673
Ng/L
0.260
1.00
1
03/09/2100:28
MMR
6020E
Dissolved Lead
<0.260
ug/L
0.260
1.00
1
03/13/21 00:21
MMR
6020B
Mercury (Total)
<0.0500
Ng/L
0.0500
0.300
1
03/09/21 17:26
EDV
7470A
Dissolved Mercury
<0.0300
ug/L
0.0300
0.200
1
03/15/21 15:03
EDV
7470A
Selenium
<0.740
Ng/L
0.740
5.00
1
03/10/2100:26
MMR
6020E
Dissolved Selenium
<0.740
ug/L
0.740
5.00
1
03/13/21 00:21
MMR
6020B
Silver
<0.110
Ng/L
0.110
1.00
1
03/09/2100:28
MMR
6020E
Dissolved Silver
<0.110
ug/L
0.110
1.00
1
03/13/21 00:21
MMR
6020B
Hardness
40500
Ng/L
570
5000
1
03/11/21 12:00
SLS
2340C-2011
1,4-Dioxane
<0.139
ug/L
0.139
2.00
1
03/08/21 19:47
TBL
8260D SIM
Surrogate:4-Bromofluorobenzene
108
Limits:70-130%
1 03/08/2119:47 TBL
V1363
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions L Limit Exceeded
MQL
Method Quantitation Limit
Page 31 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93984
Matrix: Aqueous
Sample ID: SW-02 OLD-20210303
Sampled:
3/3/2021 13:24
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
<0.310
Ng/L
0.310
5.00
1
03/09/21 17:44
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 17:44
JLB
V1489
Benzene
<0.048
Ng/L
0.048
0.500
1
03/09/21 17:44
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 17:44
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 17:44
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 17:44
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 17:44
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 17:44
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 17:44
JLB
V1489
Chlorobenzene
<0.062
ug/L
0.062
0.500
1
03/09/21 17:44
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 17:44
JLB
V1489
Chloroethane
<0.220
ug/L
0.220
0.500
1
03/09/21 17:44
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 17:44
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 17:44
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 17:44
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
pg/L
0.170
2.00
1
03/09/21 17:44
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 17:44
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 17:44
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 17:44
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 17:44
JLB
V1489
1,4-Dichlorobenzene
<0.050
Ng/L
0.050
0.500
1
03/09/21 17:44
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 17:44
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 32 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93984
Matrix: Aqueous
Sample ID: SW-02 OLD-20210303
Sampled:
3/3/2021 13:24
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 17:44
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 17:44
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 17:44
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 17:44
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 17:44
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 17:44
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 17:44
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 17:44
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 17:44
JLB
V1489
Ethylbenzene
<0.061
ug/L
0.061
0.500
1
03/09/21 17:44
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 17:44
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
ug/L
0.240
5.00
1
03/09/21 17:44
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 17:44
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 17:44
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 17:44
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
pg/L
0.110
0.500
1
03/09/21 17:44
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 17:44
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 17:44
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 17:44
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 17:44
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 17:44
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 17:44
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 33 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93984 Matrix: Aqueous
Sample ID: SW-02 OLD-20210303 Sampled: 3/3/2021 13:24
Analytical Method: 8260D Prep Batch(es): V1488 03/09/21 09:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Trichloroethene
<0.078
Ng/L
0.078 0.500
1
03/09/21 17:44 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062 0.500
1
03/09/21 17:44 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140 1.00
1
03/09/21 17:44 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060 2.00
1
03/09/21 17:44 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097 0.500
1
03/09/21 17:44 JLB
V1489
o-Xylene
<0.044
ug/L
0.044 0.500
1
03/09/21 17:44 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120 1.00
1
03/09/21 17:44 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044 0.500
1
03/09/21 17:44
V1489
Surrogate:4-Bromofluorobenzene
97.8
Limits:80-124%
1 03/09/21 17:44 JLB
V1489
Surrogate: Dibromofluoromethane
99.4
Limits: 75-129%
1 03/09/21 17:44 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
94.6
Limits: 63-136%
1 03/09/21 17:44 JLB
V1489
Surrogate: Toluene-d8
97.6
Limits: 77-123%
1 03/09/21 17:44 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 34 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93985
Matrix: Aqueous
Sample ID : TB-202103040001
Sampled:
3/4/2021 13:00
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
Acetone
1.853
Ng/L
0.310
5.00
1
03/09/21 14:58
JLB
V1489
Acrylonitrile
<0.200
ug/L
0.200
20.0
1
03/09/21 14:58
JLB
V1489
Benzene
<0.048
Ng/L
0.048
0.500
1
03/09/21 14:58
JLB
V1489
Bromochloromethane
<0.140
ug/L
0.140
0.500
1
03/09/21 14:58
JLB
V1489
Bromodichloromethane
<0.062
Ng/L
0.062
0.500
1
03/09/21 14:58
JLB
V1489
Bromoform
<0.040
ug/L
0.040
1.00
1
03/09/21 14:58
JLB
V1489
Bromomethane
<0.180
Ng/L
0.180
1.00
1
03/09/21 14:58
JLB
V1489
Carbon Disulfide
<0.075
ug/L
0.075
5.00
1
03/09/21 14:58
JLB
V1489
Carbon Tetrachloride
<0.110
Ng/L
0.110
0.500
1
03/09/21 14:58
JLB
V1489
Chlorobenzene
<0.062
ug/L
0.062
0.500
1
03/09/21 14:58
JLB
V1489
Chlorodibromomethane
<0.081
Ng/L
0.081
0.500
1
03/09/21 14:58
JLB
V1489
Chloroethane
<0.220
ug/L
0.220
0.500
1
03/09/21 14:58
JLB
V1489
Chloroform
<0.076
Ng/L
0.076
0.500
1
03/09/21 14:58
JLB
V1489
Chloromethane
<0.079
ug/L
0.079
0.500
1
03/09/21 14:58
JLB
V1489
Di -Isopropyl Ether (DIPE)
<0.960
Ng/L
0.960
5.00
1
03/09/21 14:58
JLB
V1489
1,2-Dibromo-3-Chloropropane
<0.170
pg/L
0.170
2.00
1
03/09/21 14:58
JLB
V1489
1,2-Dibromoethane
<0.051
Ng/L
0.051
0.500
1
03/09/21 14:58
JLB
V1489
Dibromomethane
<0.065
pg/L
0.065
0.500
1
03/09/21 14:58
JLB
V1489
trans-1,4-Dichloro-2-butene
<0.120
Ng/L
0.120
10.0
1
03/09/21 14:58
JLB
V1489
1,2-Dichlorobenzene
<0.076
pg/L
0.076
0.500
1
03/09/21 14:58
JLB
V1489
1,4-Dichlorobenzene
<0.050
Ng/L
0.050
0.500
1
03/09/21 14:58
JLB
V1489
Dichlorodifluoromethane
<0.110
pg/L
0.110
5.00
1
03/09/21 14:58
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 35 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93985
Matrix: Aqueous
Sample ID : TB-202103040001
Sampled:
3/4/2021 13:00
Analytical Method: 8260D
Prep Batch(es):
V1488
03/09/21 09:00
Prep Method: 5030E
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Batch
1,1-Dichloroethane
<0.083
Ng/L
0.083
0.500
1
03/09/21 14:58
JLB
V1489
1,2-Dichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 14:58
JLB
V1489
1,1-Dichloroethene
<0.083
Ng/L
0.083
0.500
1
03/09/21 14:58
JLB
V1489
cis- 1,2-Dich loroethene
<0.056
ug/L
0.056
0.500
1
03/09/21 14:58
JLB
V1489
trans-1,2-Dichloroethene
<0.094
Ng/L
0.094
0.500
1
03/09/21 14:58
JLB
V1489
1,2-Dichloropropane
<0.110
ug/L
0.110
0.500
1
03/09/21 14:58
JLB
V1489
cis- 1,3-Dich loropropene
<0.079
Ng/L
0.079
0.500
1
03/09/21 14:58
JLB
V1489
trans-1,3-Dichloropropene
<0.070
ug/L
0.070
0.500
1
03/09/21 14:58
JLB
V1489
1,4-Dioxane
<14.0
Ng/L
14.0
150
1
03/09/21 14:58
JLB
V1489
Ethylbenzene
<0.061
ug/L
0.061
0.500
1
03/09/21 14:58
JLB
V1489
2-Hexanone
<0.065
Ng/L
0.065
5.00
1
03/09/21 14:58
JLB
V1489
Methyl Ethyl Ketone (MEK)
<0.240
ug/L
0.240
5.00
1
03/09/21 14:58
JLB
V1489
4-Methyl-2-Pentanone
<1.00
Ng/L
1.00
5.00
1
03/09/21 14:58
JLB
V1489
Methylene Chloride
<0.083
ug/L
0.083
1.00
1
03/09/21 14:58
JLB
V1489
Styrene
<0.047
Ng/L
0.047
0.500
1
03/09/21 14:58
JLB
V1489
1,1,1,2-Tetrachloroethane
<0.110
pg/L
0.110
0.500
1
03/09/21 14:58
JLB
V1489
1,1,2,2-Tetrachloroethane
<0.036
Ng/L
0.036
0.500
1
03/09/21 14:58
JLB
V1489
Tetrachloroethene
<0.098
pg/L
0.098
0.500
1
03/09/21 14:58
JLB
V1489
Tetrahydrofuran
<1.10
Ng/L
1.10
10.0
1
03/09/21 14:58
JLB
V1489
Toluene
<0.044
ug/L
0.044
0.500
1
03/09/21 14:58
JLB
V1489
1,1,1-Trichloroethane
<0.061
Ng/L
0.061
0.500
1
03/09/21 14:58
JLB
V1489
1,1,2-Trichloroethane
<0.066
ug/L
0.066
0.500
1
03/09/21 14:58
JLB
V1489
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 36 of 54

Waypoint. 0 449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL www.waypointanalytical.com
01015 Project ID
Anchor QEA of North Carolina, PLLC Project Madison County Closed LF
Chuck Pippin Report Date : 03/22/2021
231 Haywood Street Information : Received : 03/05/2021
Asheville , NC 28801
Report Number : 21-064-0025 REPOR T OF A NA L YSIS
Lab No : 93985 Matrix: Aqueous
Sample ID : TB-202103040001 Sampled: 3/4/2021 13:00
Analytical Method: 8260D Prep Batch(es): V1488 03/09/21 09:00
Prep Method: 5030E
Test Results Units MDL MQL DF Date / Time By Analytical
Analyzed Batch
Trichloroethene
<0.078
Ng/L
0.078 0.500
1
03/09/21 14:58 JLB
V1489
Trichlorofluoromethane
<0.062
ug/L
0.062 0.500
1
03/09/21 14:58 JLB
V1489
1,2,3-Trichloropropane
<0.140
Ng/L
0.140 1.00
1
03/09/21 14:58 JLB
V1489
Vinyl Acetate
<0.060
ug/L
0.060 2.00
1
03/09/21 14:58 JLB
V1489
Vinyl Chloride
<0.097
Ng/L
0.097 0.500
1
03/09/21 14:58 JLB
V1489
o-Xylene
<0.044
ug/L
0.044 0.500
1
03/09/21 14:58 JLB
V1489
m,p-Xylene
<0.120
Ng/L
0.120 1.00
1
03/09/21 14:58 JLB
V1489
Xylene (Total)
<0.044
ug/L
0.044 0.500
1
03/09/21 14:58
V1489
Surrogate:4-Bromofluorobenzene
98.4
Limits:80-124%
1 03/09/21 14:58 JLB
V1489
Surrogate: Dibromofluoromethane
101
Limits: 75-129%
1 03/09/21 14:58 JLB
V1489
Surrogate: 1,2-Dichloroethane - d4
95.8
Limits: 63-136%
1 03/09/21 14:58 JLB
V1489
Surrogate: Toluene-d8
97.6
Limits: 77-123%
1 03/09/21 14:58 JLB
V1489
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 37 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Analytical Batch:
V1548
Analysis Method:
2340C-2011
Analysis Description:
Total Hardness
Lab Reagent Blank
LRB
Matrix: AQU
Associated Lab Samples:
93983, 93984
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Hardness
pg/L
<570 570
5000
03/11/21 12:00
Laboratory Control Sample
LCS
Spike
LCS
LCS %Rec % Rec
Parameter
Units
Conc.
Result
Limits
Hardness
pg/L
50000
51500
103 90-110
Duplicate
V 93984-DUP
Result DUP
RPD Max RPD
Analyzed
Parameter
Units
Result
Hardness
pg/L
40500 41500
2.4 20
03/11/21 12:00
Date: 03/22/2021 02:49 PM Page 1 of 15
Page 38 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1323
QC Analytical Batch(es): V1417,V1460
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V1323
Matrix: AQU
Associated Lab Samples:
93978
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
pg/L
<0.170
0.170
1.00
03/08/2119:38
Barium
pg/L
<0.810
0.810
10.0
03/08/2119:38
Cadmium
pg/L
<0.160
0.160
1.00
03/08/2119:38
Chromium
pg/L
<0.790
0.790
2.00
03/08/2119:38
Lead
pg/L
<0.260
0.260
1.00
03/08/21 19:38
Selenium
pg/L
<0.740
0.740
5.00
03/09/2119:37
Silver
pg/L
<0.110
0.110
1.00
03/08/2119:38
Laboratory Control Sample
LCS-V1323
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
pg/L
100
95.0
95.0
80-120
Barium
pg/L
100
101
101
80-120
Cadmium
pg/L
100
99.9
100
80-120
Chromium
pg/L
100
100
100
80-120
Lead
pg/L
100
98.7
99.0
80-120
Selenium
pg/L
100
101
101
80-120
Silver
pg/L
100
99.0
99.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 94039-MS-V1323
V 94039-MSD-V1323
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result
Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Arsenic
pg/L
0.367
100
100 93.3
93.7 93.0
94.0
75-125 0.4 20.0
Barium
pg/L
39.3
100
100 139
137 100
98.0
75-125 1.4 20.0
Cadmium
pg/L
< 0.160
100
100 101
99.3 101
99.0
75-125 1.6 20.0
Chromium
pg/L
< 0.790
100
100 97.8
95.0 98.0
95.0
75-125 2.9 20.0
Date:
03/22/2021 02:49 PM
Page 2 of 15
Page 39 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1323
QC Analytical Batch(es): V1417,V1460
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 94039-MS-V1323
V 94039-MSD-V1323
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
ug/L
0.267 100
100 98.4
97.8 98.0
98.0 75-125 0.6 20.0
Selenium
ug/L
< 0.740 100
100 105
101 105
101 75-125 3.8 20.0
Silver
ug/L
< 0.110 100
100 100
98.5 100
99.0 75-125 1.5 20.0
Post Digestion Spike
V 94039-PDS-V1323
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Arsenic
ug/L
49.1
98.0
03/08/2120:17
Barium
ug/L
69.4
100
03/08/2120:17
Cadmium
ug/L
49.4
99.0
03/08/2120:17
Chromium
ug/L
49.5
99.0
03/08/2120:17
Lead
ug/L
47.9
96.0
03/08/21 20:17
Selenium
ug/L
50.7
101
03/09/2120:15
Silver
ug/L
49.4
99.0
03/08/2120:17
Date: 03/22/2021 02:49 PM Page 3 of 15
Page 40 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1325
QC Analytical Batch(es): V1417,V1460
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V1325
Matrix: AQU
Associated Lab Samples:
93979, 93980, 93981, 93982,
93983, 93984
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Arsenic
pg/L
<0.170
0.170
1.00
03/08/2122:58
Barium
pg/L
<0.810
0.810
10.0
03/08/2122:58
Cadmium
pg/L
<0.160
0.160
1.00
03/08/2122:58
Chromium
pg/L
<0.790
0.790
2.00
03/08/2122:58
Lead
pg/L
<0.260
0.260
1.00
03/08/21 22:58
Selenium
pg/L
<0.740
0.740
5.00
03/09/2123:03
Silver
pg/L
<0.110
0.110
1.00
03/08/2122:58
Laboratory Control Sample
LCS-V1325
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Arsenic
pg/L
100
92.1
92.0
80-120
Barium
pg/L
100
99.6
100
80-120
Cadmium
pg/L
100
100
100
80-120
Chromium
pg/L
100
96.7
97.0
80-120
Lead
pg/L
100
97.6
98.0
80-120
Selenium
pg/L
100
97.8
98.0
80-120
Silver
pg/L
100
98.5
99.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 93979-MS-V1325
V 93979-MSD-V1325
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result
Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Arsenic
pg/L
< 0.170
100
100 90.7
93.0 91.0
93.0
75-125 2.5 20.0
Barium
pg/L
58.3
100
100 155
161 97.0
103
75-125 3.7 20.0
Cadmium
pg/L
< 0.160
100
100 101
102 101
102
75-125 0.9 20.0
Chromium
pg/L
< 0.790
100
100 95.3
97.4 95.0
97.0
75-125 2.1 20.0
Date:
03/22/2021 02:49 PM
Page 4 of 15
Page 41 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1325
QC Analytical Batch(es): V1417,V1460
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Matrix Spike & Matrix Spike
Duplicate
V 93979-MS-V1325
V 93979-MSD-V1325
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Lead
ug/L
< 0.260 100
100 95.5
98.3 96.0
98.0 75-125 2.8 20.0
Selenium
ug/L
< 0.740 100
100 98.8
96.9 99.0
97.0 75-125 1.9 20.0
Silver
ug/L
< 0.110 100
100 98.3
100 98.0
100 75-125 1.7 20.0
Post Digestion Spike
V 93979-PDS-V1325
PDS
%
Analyzed
Parameter
Units
Result
Recovery
Arsenic
ug/L
48.5
97.0
03/08/2123:50
Barium
ug/L
76.7
97.0
03/08/2123:50
Cadmium
ug/L
49.4
99.0
03/08/2123:50
Chromium
ug/L
47.8
96.0
03/08/2123:50
Lead
ug/L
47.6
95.0
03/08/21 23:50
Selenium
ug/L
48.8
98.0
03/09/2123:41
Silver
ug/L
49.7
99.0
03/08/2123:50
Date: 03/22/2021 02:49 PM Page 5 of 15
Page 42 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1688
QC Analytical Batch(es): V1695
QC Prep Batch Method:
3005A
Analysis Method:
6020B
Analysis Description:
Metals Analyses
Lab Reagent Blank
LRB-V1688
Matrix: AQU
Associated Lab Samples:
93978, 93982, 93983, 93984
Blank
MDL
MQL
Analyzed
Parameter
Units
Result
Dissolved Arsenic
pg/L
<0.170
0.170
1.00
03/12/21 21:45
Dissolved Barium
pg/L
<0.810
0.810
10.0
03/12/21 21:45
Dissolved Cadmium
pg/L
<0.160
0.160
1.00
03/12/21 21:45
Dissolved Chromium
pg/L
<0.790
0.790
2.00
03/12/21 21:45
Dissolved Lead
pg/L
<0.260
0.260
1.00
03/12/21 21:45
Dissolved Selenium
pg/L
<0.740
0.740
5.00
03/12/21 21:45
Dissolved Silver
pg/L
<0.110
0.110
1.00
03/12/21 21:45
Laboratory Control Sample
LCS-V1688
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Dissolved Arsenic
pg/L
100
93.2
93.0
80-120
Dissolved Barium
pg/L
100
94.6
95.0
80-120
Dissolved Cadmium
pg/L
100
99.6
100
80-120
Dissolved Chromium
pg/L
100
98.6
99.0
80-120
Dissolved Lead
pg/L
100
97.6
98.0
80-120
Dissolved Selenium
pg/L
100
99.8
100
80-120
Dissolved Silver
pg/L
100
97.4
97.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 93965-V1633-MS-V1688 V 93965-V1633-MSD-V1688
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result
Conc.
Spike
Result %Rec
%Rec
Limits RPD RPD
Conc.
Dissolved Arsenic
pg/L
< 0.170
100
100 92.6
92.1 93.0
92.0
75-125 0.5 20.0
Dissolved Barium
pg/L
57.6
100
100 151
155 93.0
97.0
75-125 2.6 20.0
Dissolved Cadmium
pg/L
< 0.160
100
100 96.7
97.9 97.0
98.0
75-125 1.2 20.0
Dissolved Chromium
pg/L
< 0.790
100
100 96.6
97.5 97.0
98.0
75-125 0.9 20.0
Date: 03/22/2021 02:49 PM Page 6 of 15
Page 43 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed LF
Report No: 21-064-0025
QC Prep: V1688 QC Analytical Batch(es): V1695
QC Prep Batch Method: 3005A Analysis Method: 6020B
Analysis Description: Metals Analyses
Matrix Spike & Matrix Spike Duplicate V 93965-V1633-MS-V1688 V 93965-V1633-MSD-V1688
MS Spike MSD MS Result MSD MS MSD %Rec Max
Parameter Units Result Conc. Spike Result %Rec %Rec Limits RPD RPD
Conc.
Dissolved Lead
ug/L
< 0.260 100 100 97.3 96.0 97.0 96.0 75-125 1.3 20.0
Dissolved Selenium
ug/L
< 0.740 100 100 93.6 98.0 94.0 98.0 75-125 4.5 20.0
Dissolved Silver
ug/L
< 0.110 100 100 96.3 97.7 96.0 98.0 75-125 1.4 20.0
Post Digestion Spike
V 93965-V1633-PDS-V1688
Parameter
PDS 0/0
Units Result Recovery
Analyzed
Dissolved Arsenic
ug/L
51.7
103
03/12/21 22:17
Dissolved Barium
ug/L
82.5
105
03/12/21 22:17
Dissolved Cadmium
ug/L
51.7
103
03/12/21 22:17
Dissolved Chromium
ug/L
51.2
102
03/12/21 22:17
Dissolved Lead
ug/L
51.1
102
03/12/21 22:17
Dissolved Selenium
ug/L
49.5
99.0
03/12/21 22:17
Dissolved Silver
ug/L
51.4
103
03/12/21 22:17
Date: 03/22/2021 02:49 PM Page 7 of 15
Page 44 of 54

•
Waypoint,
449 Springbrook Rd, Ch
Charlotte, NC 28217
Main 704.529.6364
ANALYTICAL
www.waypoi ntana lytica l.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed
LF
Report No: 21-064-0025
QC Prep: V1421
QC Analytical Batch(es): V1496
QC Prep Batch Method: 7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury Analysis - CVAA
Lab Reagent Blank
LRB-V1421
Matrix: AQU
Associated Lab Samples: 93978, 93979, 93980, 93981, 93982, 93983, 93984
Blank MDL
MQL
Analyzed
Parameter Units
Result
Mercury (Total) pg/L
<0.0500 0.0500
0.300
03/09/21 16:24
Laboratory Control Sample
LCS-V1421
Spike
LCS
LCS %Rec % Rec
Parameter Units
Conc.
Result
Limits
Mercury (Total) pg/L
9.38
9.61
103 80-120
Matrix Spike & Matrix Spike Duplicate
V 93975-MS-V1421
V 93975-MSD-V1421
MS Spike
MSD MS Result
MSD MS MSD %Rec Max
Parameter Units
Result Conc.
Spike
Result %Rec %Rec Limits RPD RPD
Conc.
Mercury (Total) pg/L
<0.0500 9.38
9.38 9.81
9.71 105 104 80-120 1.0 20
Post Digestion Spike
V 93975-PDS-V1421
PDS
%
Analyzed
Parameter Units
Result
Recovery
Mercury (Total) pg/L
4.95
106
03/09/21 16:44
Date: 03/22/2021 02:49 PM Page 8 of 15
Page 45 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1703
QC Analytical Batch(es): V1708
QC Prep Batch Method:
7470A
Analysis Method:
7470A
Analysis Description:
Total Aqueous Mercury
Analysis - CVAA
Lab Reagent Blank
LRB-V1703
Matrix: AQU
Associated Lab Samples:
93978, 93982, 93983,
93984
Blank MDL
MQL
Analyzed
Parameter
Units
Result
Dissolved Mercury
pg/L
0.000 0.000
0.200
03/15/21 13:22
Laboratory Control Sample
LCS-V1703
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
Dissolved Mercury
pg/L
9.38
9.09
97.0
80-120
Matrix Spike & Matrix Spike Duplicate
V 92809-V1666-MS-V1703 V 92809-V1666-MSD-V1703
MS Spike
MSD MS Result
MSD MS
MSD %Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec Limits RPD RPD
Conc.
Dissolved Mercury
pg/L
<0.0300 9.38
9.38 9.06
9.05 97.0
97.0 80-120 0.1 20
Date: 03/22/2021 02:49 PM Page 9 of 15
Page 46 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1362
QC Analytical Batch(es): V1363
QC Prep Batch Method:
5030B
Analysis Method:
8260D SIM
Analysis Description:
Volatile Organic Compounds -
GC/MS
Lab Reagent Blank
LRB-V1362
Matrix: AQU
Associated Lab Samples:
93978, 93979, 93980, 93981, 93982, 93983, 93984
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
1,4-Dioxane
pg/L
<0.139 0.139
2.00
03/08/2111:49
4-Bromofluorobenzene (S)
03/08/21 11:49
109
70-130
Laboratory Control Sample
LCS-V1362
Spike
LCS
LCS %Rec
% Rec
Parameter
Units
Conc.
Result
Limits
1,4-Dioxane
pg/L
50.0
51.7
103
70-130
4-Bromofluorobenzene (S)
114
70-130
Matrix Spike & Matrix Spike Duplicate
V 93965-MS-V1362
V 93965-MSD-V1362
MS Spike
MSD MS Result
MSD MS
MSD
%Rec Max
Parameter
Units
Result Conc.
Spike
Result %Rec
%Rec
Limits RPD
Conc.
1,4-Dioxane
pg/L
< 0.139 50.0
50.0 49.2
49.4 98.4
98.8
70-130
4-Bromofluorobenzene (S)
119
116
70-130
Date: 03/22/2021 02:49 PM Page 10 of 15
Page 47 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed LF
Report No: 21-064-0025
QC Prep: V1488
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V1489
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V1488 Matrix: AQU
Associated Lab Samples: 93978, 93979, 93980, 93981, 93982, 93983, 93984, 93985
Blank MDL MQL Analyzed % % Rec
Parameter Units Result Recovery Limits
Acetone
pg/L
<0.310
0.310
5.00
03/09/21 13:47
Acrylonitrile
pg/L
<0.200
0.200
20.0
03/09/21 13:47
Benzene
pg/L
<0.048
0.048
0.500
03/09/21 13:47
Bromochloromethane
pg/L
<0.140
0.140
0.500
03/09/21 13:47
Bromodichloromethane
pg/L
<0.062
0.062
0.500
03/09/21 13:47
Bromoform
pg/L
<0.040
0.040
1.00
03/09/21 13:47
Bromomethane
pg/L
<0.180
0.180
1.00
03/09/21 13:47
Carbon Disulfide
pg/L
<0.075
0.075
5.00
03/09/21 13:47
Carbon Tetrachloride
pg/L
<0.110
0.110
0.500
03/09/21 13:47
Chlorobenzene
pg/L
<0.062
0.062
0.500
03/09/21 13:47
Chlorodibromomethane
pg/L
<0.081
0.081
0.500
03/09/21 13:47
Chloroethane
pg/L
<0.220
0.220
0.500
03/09/21 13:47
Chloroform
pg/L
<0.076
0.076
0.500
03/09/21 13:47
Chloromethane
pg/L
<0.079
0.079
0.500
03/09/21 13:47
Di -Isopropyl Ether (DIPE)
pg/L
<0.960
0.960
5.00
03/09/21 13:47
1,2-Dibromo-3-Chloropropane
pg/L
<0.170
0.170
2.00
03/09/21 13:47
1,2-Dibromoethane
pg/L
<0.051
0.051
0.500
03/09/21 13:47
Dibromomethane
pg/L
<0.065
0.065
0.500
03/09/21 13:47
trans-1,4-Dichloro-2-butene
pg/L
<0.120
0.120
10.0
03/09/21 13:47
1,2-Dichlorobenzene
pg/L
<0.076
0.076
0.500
03/09/21 13:47
1,4-Dichlorobenzene
pg/L
<0.050
0.050
0.500
03/09/21 13:47
Dichlorodifluoromethane
pg/L
<0.110
0.110
5.00
03/09/21 13:47
1,1-Dichloroethane
pg/L
<0.083
0.083
0.500
03/09/21 13:47
1,2-Dichloroethane
pg/L
<0.066
0.066
0.500
03/09/21 13:47
1,1-Dichloroethene
pg/L
<0.083
0.083
0.500
03/09/21 13:47
cis-1,2-Dichloroethene
pg/L
<0.056
0.056
0.500
03/09/21 13:47
trans-1,2-Dichloroethene
pg/L
<0.094
0.094
0.500
03/09/21 13:47
Date:
03/22/2021 02:49 PM
Page 11 of 15
Page 48 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed LF
Report No: 21-064-0025
QC Prep: V1488
QC Prep Batch Method: 5030B
QC Analytical Batch(es): V1489
Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Lab Reagent Blank LRB-V1488 Matrix: AQU
Associated Lab Samples: 93978, 93979, 93980, 93981, 93982, 93983, 93984, 93985
Blank
MDL
MQL
Analyzed
% % Rec
Parameter
Units
Result
Recovery Limits
1,2-Dichloropropane
pg/L
<0.110
0.110
0.500
03/09/21 13:47
cis-1,3-Dichloropropene
pg/L
<0.079
0.079
0.500
03/09/21 13:47
trans-1,3-Dichloropropene
pg/L
<0.070
0.070
0.500
03/09/21 13:47
1,4-Dioxane
pg/L
<14.0
14.0
150
03/09/21 13:47
Ethylbenzene
pg/L
<0.061
0.061
0.500
03/09/21 13:47
2-Hexanone
pg/L
<0.065
0.065
5.00
03/09/21 13:47
Methyl Ethyl Ketone (MEK)
pg/L
<0.240
0.240
5.00
03/09/21 13:47
4-Methyl-2-Pentanone
pg/L
<1.00
1.00
5.00
03/09/21 13:47
Methylene Chloride
pg/L
<0.083
0.083
1.00
03/09/21 13:47
Styrene
pg/L
<0.047
0.047
0.500
03/09/21 13:47
1,1,1,2-Tetrachloroethane
pg/L
<0.110
0.110
0.500
03/09/21 13:47
1,1,2,2-Tetrachloroethane
pg/L
<0.036
0.036
0.500
03/09/21 13:47
Tetrachloroethene
pg/L
<0.098
0.098
0.500
03/09/21 13:47
Tetrahydrofuran
pg/L
<1.10
1.10
10.0
03/09/21 13:47
Toluene
pg/L
<0.044
0.044
0.500
03/09/21 13:47
1,1,1-Trichloroethane
pg/L
<0.061
0.061
0.500
03/09/21 13:47
1,1,2-Trichloroethane
pg/L
<0.066
0.066
0.500
03/09/21 13:47
Trichloroethene
pg/L
<0.078
0.078
0.500
03/09/21 13:47
Trichlorofluoromethane
pg/L
<0.062
0.062
0.500
03/09/21 13:47
1,2,3-Trichloropropane
pg/L
<0.140
0.140
1.00
03/09/21 13:47
Vinyl Acetate
pg/L
<0.060
0.060
2.00
03/09/21 13:47
Vinyl Chloride
pg/L
<0.097
0.097
0.500
03/09/21 13:47
o-Xylene
pg/L
<0.044
0.044
0.500
03/09/21 13:47
m,p-Xylene
pg/L
<0.120
0.120
1.00
03/09/21 13:47
4-Bromofluorobenzene (S)
03/09/21 13:47
99.4 80-124
Dibromofluoromethane (S)
03/09/21 13:47
102 75-129
1,2-Dichloroethane - d4 (S)
03/09/21 13:47
97.6 63-136
Date:
03/22/2021 02:49 PM
Page 12 of 15
Page 49 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1488
QC Analytical Batch(es): V1489
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Lab Reagent Blank
LRB-V1488
Matrix: AQU
Associated Lab Samples:
93978, 93979, 93980, 93981, 93982, 93983, 93984, 93985
Blank MDL
MQL
Analyzed
%
% Rec
Parameter
Units
Result
Recovery
Limits
Toluene-d8 (S)
03/09/21 13:47
98.8
77-123
Laboratory Control Sample
& LCSD
LCS-V1488 LCSD-V1488
Spike
LCS
LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result
Result
%Rec
a/o Rec
Limits
RPD
Max
RPD
Acetone
pg/L
40.0
37.7
36.8
94.2
92.0
40-166
2.4
20.0
Acrylonitrile
pg/L
40.0
46.1
44.2
115
111
81-127
4.2
20.0
Benzene
pg/L
20.0
21.1
20.4
106
102
77-128
3.3
20.0
Bromochloromethane
pg/L
20.0
21.7
21.4
109
107
78-135
1.3
20.0
Bromodichloromethane
pg/L
20.0
21.4
20.4
107
102
76-138
4.7
20.0
Bromoform
pg/L
20.0
21.7
20.4
109
102
71-135
6.1
20.0
Bromomethane
pg/L
20.0
23.5
21.8
118
109
41-168
7.5
20.0
Carbon Disulfide
pg/L
20.0
20.8
19.9
104
99.5
59-135
4.4
20.0
Carbon Tetrachloride
pg/L
20.0
21.6
20.5
108
103
72-142
5.2
20.0
Chlorobenzene
pg/L
20.0
20.8
20.3
104
102
78-119
2.4
20.0
Chlorodibromomethane
pg/L
20.0
21.4
20.7
107
104
75-134
3.3
20.0
Chloroethane
pg/L
20.0
20.0
19.6
100
98.0
57-142
2.0
20.0
Chloroform
pg/L
20.0
21.1
20.4
106
102
77-130
3.3
20.0
Chloromethane
pg/L
20.0
19.7
18.7
98.5
93.5
47-145
5.2
20.0
Di -Isopropyl Ether (DIPE)
pg/L
20.0
21.6
20.8
108
104
60-154
3.7
20.0
1,2-Dibromo-3-Chloropropane pg/L
20.0
22.1
20.7
111
104
63-134
6.5
20.0
1,2-Dibromoethane
pg/L
20.0
21.1
20.7
106
104
77-135
1.9
20.0
Dibromomethane
pg/L
20.0
21.3
21.0
107
105
76-138
1.4
20.0
trans-1,4-Dichloro-2-butene
pg/L
20.0
21.2
21.6
106
108
70-130
1.8
20.0
1,2-Dichlorobenzene
pg/L
20.0
21.2
20.9
106
105
78-128
1.4
20.0
1,4-Dichlorobenzene
pg/L
20.0
20.5
20.6
103
103
75-126
0.4
20.0
Date: 03/22/2021 02:49 PM Page 13 of 15
Page 50 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID: Anchor QEA of North Carolina, PLLC
Project Description: Madison County Closed LF
Report No: 21-064-0025
QC Prep: V1488 QC Analytical Batch(es): V1489
QC Prep Batch Method: 5030B Analysis Method: 8260D
Analysis Description: Volatile Organic Compounds - GC/MS
Laboratory Control Sample & LCSD LCS-V1488 LCSD-V1488
Parameter
Units
Spike
Conc.
LCS
Result
LCSD
Result
LCS
%Rec
LCSD
% Rec
% Rec
Limits
RPD
Max
RPD
Dichlorodifluoromethane
pg/L
20.0
19.0
18.0
95.0
90.0
28-163
5.4
20.0
1,1-Dichloroethane
pg/L
20.0
21.4
20.7
107
104
70-130
3.3
20.0
1,2-Dichloroethane
pg/L
20.0
21.7
20.7
109
104
68-131
4.7
20.0
1,1-Dichloroethene
pg/L
20.0
21.4
20.7
107
104
70-154
3.3
20.0
cis-1,2-Dichloroethene
pg/L
20.0
21.2
20.5
106
103
76-141
3.3
20.0
trans-1,2-Dichloroethene
pg/L
20.0
21.3
20.4
107
102
76-135
4.3
20.0
1,2-Dichloropropane
pg/L
20.0
21.4
20.5
107
103
77-130
4.2
20.0
cis-1,3-Dichloropropene
pg/L
20.0
21.7
21.0
109
105
65-140
3.2
20.0
trans-1,3-Dichloropropene
pg/L
20.0
21.8
21.1
109
106
67-140
3.2
20.0
1,4-Dioxane
pg/L
200
202
189
101
94.5
70-130
6.6
20.0
Ethylbenzene
pg/L
20.0
20.5
19.7
103
98.5
80-127
3.9
20.0
2-Hexanone
pg/L
20.0
20.3
18.1
102
90.5
64-137
11.4
20.0
Methyl Ethyl Ketone (MEK)
pg/L
20.0
21.9
20.0
110
100
71-134
9.0
20.0
4-Methyl-2-Pentanone
pg/L
20.0
20.7
19.2
104
96.0
69-134
7.5
20.0
Methylene Chloride
pg/L
20.0
21.2
20.9
106
105
73-131
1.4
20.0
Styrene
pg/L
20.0
20.9
20.6
105
103
78-129
1.4
20.0
1,1,1,2-Tetrachloroethane
pg/L
20.0
21.0
20.3
105
102
79-134
3.3
20.0
1,1,2,2-Tetrachloroethane
pg/L
20.0
21.2
20.2
106
101
62-127
4.8
20.0
Tetrachloroethene
pg/L
20.0
21.5
20.7
108
104
80-129
3.7
20.0
Tetrahydrofuran
pg/L
20.0
20.0
18.7
100
93.5
70-130
6.7
20.0
Toluene
pg/L
20.0
21.3
20.5
107
103
76-131
3.8
20.0
1,1,1-Trichloroethane
pg/L
20.0
21.4
20.4
107
102
75-135
4.7
20.0
1,1,2-Trichloroethane
pg/L
20.0
21.5
20.8
108
104
70-140
3.3
20.0
Trichloroethene
pg/L
20.0
21.7
21.0
109
105
77-133
3.2
20.0
Trichlorofluoromethane
pg/L
20.0
22.1
20.7
111
104
62-148
6.5
20.0
1,2,3-Trichloropropane
pg/L
20.0
21.5
21.2
108
106
71-127
1.4
20.0
Date: 03/22/2021 02:49 PM Page 14 of 15
Page 51 of 54

Waypointo
ANALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Quality Control Data
Client ID:
Anchor QEA of North Carolina, PLLC
Project Description:
Madison County Closed LF
Report No:
21-064-0025
QC Prep:
V1488
QC Analytical Batch(es): V1489
QC Prep Batch Method:
5030B
Analysis Method:
8260D
Analysis Description:
Volatile
Organic Compounds - GC/MS
Laboratory Control Sample
& LCSD
LCS-V1488 LCSD-V1488
Spike
LCS LCSD
LCS
LCSD
% Rec
Parameter
Units
Conc.
Result Result
%Rec
% Rec
Limits
RPD
Max
RPD
Vinyl Acetate
pg/L
20.0
22.9 21.7
115
109
34-167
5.3
20.0
Vinyl Chloride
pg/L
20.0
20.7 19.6
104
98.0
57-141
5.4
20.0
o-Xylene
pg/L
20.0
20.9 20.3
105
102
78-128
2.9
20.0
m,p-Xylene
pg/L
40.0
43.6 42.0
109
105
77-133
3.7
20.0
4-Bromofluorobenzene (S)
99.8
100
80-124
Dibromofluoromethane (S)
101
98.4
75-129
1,2-Dichloroethane - d4 (S)
104
102
63-136
Toluene-d8 (S)
99.6
99.0
77-123
Date: 03/22/2021 02:49 PM Page 15 of 15
Page 52 of 54

WayPAoint.
NALYTICAL
449 Springbrook Rd, Charlotte, NC 28217
Main 704.529.6364
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 01015
Customer Name: Anchor QEA of North Carolina, PLLC
Report Number: 21-064-0025
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
® Other :
Thermometer ID:
CK
IRT-15 1.3C
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
F
Custody seals intact on shipping container/cooler?
0 Yes
0 No
I* Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
I* Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample Iabel(s)?
0 Yes
0 No
COC properly completed
® Yes
0 No
Samples in proper containers?
0 Yes
0 No
Sample containers intact?
® Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
0 Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
0 Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
* N/A
F_ High concentration container (48 hr) F Low concentration EnCore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
0 No
Comments:
Signature: Talon J Yelton Date & Time: 03/05/2021 13:34:39
Page 53 of 54

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Page 54 of 54
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