Loading...
HomeMy WebLinkAbout3404_Forsyth_Kernersville_MSWLF_Jan2021GW_FID1580001_20210517ENR USE ONLY []Paper Report []Electronic Data - Email CD (data loaded: Yes / No Doe/Event #: _ ' C DENR " Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name: Laura Robertson Elliott, PG Phone: 919.238.0422 (p) / 919.451.9710 (c) E-mail: lelliott@withersravenel.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Town of Kemersville Landfill Freeman Road 34-04 .0500 January 13, 2021 Kernersvilie, NC 27284 Environmental Status: (Check all that apply) Initial/Background Monitoring Q Detection Monitoring FAssessment Monitoring Corrective Action T of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data X Surface water monitoringdata Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Mark Brown, LG, PG, RSM Senior Geologist 919.608.4582 Facility Re resent tiv ame (Print) Title (Area Code) Telephone Number May 17, 2021 Affix NC Licensed/ Professional Geologist Seal Signature i Date 424 GalfirnordDairy Road, Suite C, Greensboro, NC 27409 Facility Representative Address C-082 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 o r WithersRavenel Our People. Your Success. May 17, 2021 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: January 2021 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.39 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached January 2021 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the January 2021 sampling event, and historic data from the semiannual sampling event performed January 2021. Also attached is the North Carolina Environmental Monitoring Reporting Form for the January 2021 monitoring event. Please contact me at lelliott@withersravenel.com with comments, questions, or requests. Sincerely WithersRavenel Laura R. Elliott, PG Project Geologist Attachment C: Brad Beeson -Town of Kernersville, Solid Waste Superintendent 424 Gallimore Dairy Road, Suite C I Greensboro, NC 27409 t: 336.605.3009 1 f: 919.467.6008 1 www.withersravenel.com I License No. C-0832 Asheville I Cary I Greensboro I Pittsboro I Raleigh I Wilmington ■■ WithersRavenel ki 0 Our People. Your Success. JANUARY 2021 WATER QUALITY MONITORING REPORT Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By: WithersRavenel, Inc. 424 Gallimore Dairy Road, Suite C Greensboro, North Carolina 27409 WR Project #: 06140180.39 May 17, 2021 Laura R. Elliott, PG Project Geologist Mark Brown, LG, PG, RSM Senior Geologist ■■ WithersRavenel .. Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION................................................................................................................................. 1 1.1 Site Information............................................................................................................................... 1 1.2 Site Geology and Hydrogeology.................................................................................................. 1 1.3 Regulatory Status............................................................................................................................ 1 2.0 FACILITY MONITORING PROGRAM............................................................................................. 2 2.1 Groundwater Monitoring Program.............................................................................................. 2 2.2 Surface Water Monitoring Program............................................................................................ 2 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT .............................................. 3 3.1 Field Services.................................................................................................................................... 3 3.2 Quality Control................................................................................................................................ 4 4.0 ANALYTICAL RESULTS...................................................................................................................... 4 4.1 Groundwater....................................................................................................................................4 4.2 Surface Water.................................................................................................................................. 5 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION ............................................ 5 5.1 MNA Parameters............................................................................................................................. 5 6.0 FINDINGS.............................................................................................................................................2 7.0 REFERENCES....................................................................................................................................... 2 Page i of ii ■■ WithersRavenel .. Our People. Your Success. Figures Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map January 2021 Figure 3B Potentiometric Map July 2020 Figure 4 Groundwater 2L/GWP Exceedances Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents Appendices Appendix I Laboratory Analytical Reports and Field Notes Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Page ii of ii ■■ WithersRavenel .. Our People. Your Success. 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina Quadrangle (Quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM), Solid Waste Section (Section) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft. • An effective porosity value (n) of 30 percent was estimated. • Hydraulic conductivity (I) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville (Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring ("Appendix I") and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "2L Standards"); or, when a 2L Standard is not established, the Section's Groundwater Protection Standards (GWPs) or Interim Maximum Allowable Concentrations (IMACs). January 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 May 2021 Page 1 of 6 ■■ WithersRavenel ■ o Our People. Your Success. Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the Section requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013 response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE's Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now doing business as the North Carolina Department of Environmental Quality (NCDEQ). 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2R, MW-3S, MW-3D, MW-4, and MW-5R are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2R, MW-3S, MW-3D, MW-4 and MW-6 are also periodically monitored for the following Monitored Natural Attenuation (MNA) constituents: • Nitrate, sulfate, chloride, sulfide, alkalinity, and • Total organic carbon (TOC); Groundwater samples collected semiannually are analyzed for the Appendix I list of constituents and periodically for the above -referenced MNA parameters. Sample analyses are then compared to the 2L Standards or IMACs or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semi-annually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. These surface water monitoring points are summarized below, along with their current monitoring program status. January 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 May 2021 Page 2 of 6 ■■ WithersRavenel .. Our People. Your Success. Surface Water Designation Classification SW-1 Upstream/Compliance SW-2 Compliance SW-3 Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters of NC as listed in 15A NCAC 2B (2B Standards). 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT 3.1 Field Services On January 13, 2021, WithersRavenel (WR) personnel mobilized to the facility to purge and sample monitoring wells MW-1, MW-2R MW-3S, MW-3D, MW-4, MW-5R, and MW-6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01-foot. Due to the lack of water encountered within the well, monitoring well MW-1 was measured for static water level only. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, the most recent sampling event (January 2021) data are illustrated on some of the figures. Figure 3A, Potentiometric Map (January 2021) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the January 2021 sampling event. Figure 313, Potentiometric Map (July 2020) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2020 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of East Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2021. The monitoring wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation-reduction potential, and turbidity, were recorded in the site -specific sampling forms after purging and before sampling. Groundwater Sampling Methods Groundwater samples from each monitoring well were collected directly from a submersible pump or decanted from disposable bailers into the laboratory -prepared and -provided containers immediately after purging. Samples were then placed into laboratory -provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina -certified laboratory (Pace Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in the Appendix to this report. January 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 May 2021 Page 3 of 6 ■■ WithersRavenel %0 Our People. Your Success. Surface Water Sampling Methods Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overfill the preserved sample containers (which could lead to preservative loss) and avoid sample -induced turbidity. Samples were collected initially from the downstream sample location (previously designated SW-2 by others), and in sequence upstream, SW-3 and then SW-1 to reduce potential turbidity in the samples (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Laboratories under standard COC protocol. 3.2 Quality Control One Field Blank was collected by WR personnel as part of the January 2021 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Field Blank was analyzed for the Appendix I list of constituents only, while the Trip Blank was analyzed for VOCs only. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to the respective 2L Standards or GWPs where appropriate. As shown on Table 4, Groundwater Analytical Results, the following organic and/or inorganic constituents were detected in groundwater samples during the January 2021 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations detected above the 2L Standard or GWPs are illustrated in bold font. Constituent Referenced Standard Compliance Wells (2L/GWP) MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6 Benzene 1.0 9.00 3.23 0.328 J 0.571 J 0.379 J <1.00 <1.00 1,1-Dichloroethane 6.0 1.15 10.0 0.429 J 1.51 1.39 <1.00 <1.00 1,2-Dichloroethane 0.4 2.42 J 0.526 J 0.230 0589 J 0.106 J <1.00 <1.00 1,2-Dichloropropane 0.6 <1.00 3.76 0.295 J 1.02 0.281 J <1.00 <1.00 Vinyl chloride 0.03 3.57 3.77 1.51 8.48 11.6 <1.00 <1.00 Cadmium 2 3.12 <2.00 3.82 <2.00 <2.00 <2.00 <2.00 Lead 15 <6.00 <6.00 <6.00 <6.00 <6.00 50.0 <6.00 Vanadium 0.3 6.25 J <20.0 15.8 <20.0 <20.0 61.1 Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain -of -custody records are included in the Appendix. January 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 May 2021 Page 4 of 6 ■■ WithersRavenel .. Our People. Your Success. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. No analytes were detected at concentrations above the 2B Standards in surface water samples collected during the January 2021 sampling event. The results were consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain -of -custody records are included in the Appendix. 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, and MW-4. MNA field (geochemical) parameters included: • Temperature • pH • Specific conductance • Oxidation-reduction potential (ORP) • Turbidity; and • Dissolved oxygen. Laboratory parameters included: • Biological Oxygen Demand (BOD) • Chemical Oxygen Demand (COD) • Dissolved hydrogen • Nitrate • Sulfate • Chloride • Alkalinity as CaCO3 • Sulfide • Total Organic Carbon (TOC) • Ethane, ethene, and methane; and • Volatile fatty acids. In correspondence with the Section in June 2020, the Section indicated that MNA sampling would not be required until after preparation and submittal of a new Corrective Action Evaluation Report in July 2021. As such, the full list of MNA parameters were not analyzed during the January 2021 sampling event. MNA parameters analyzed during the January 2021 sampling event are presented on Table 6, Summary of MNA Constituents, and included: • Alkalinity as CaCO3 • Chloride • Nitrogen, Nitrate • Sulfate • Sulfide, and • Total Organic Carbon (TOC) Laboratory reports and field data forms are included in the Appendix. Analysis of the full list of MNA parameters will begin again in January and July 2022. January 2021 Water Quality Monitoring Report WR Project Number 06140180.39 Town of Kernersville Closed Landfill, Permit 34-04 May 2021 Page 5 of 6 ■■ WithersRavenel .. Our People. Your Success. 6.0 FINDINGS Target analytes detected above their respective 2L Standards and/or GWPs in groundwater samples collected during the January 2021 sampling event appear to generally be consistent with previous events. In addition, there were no target analytes detected in the surface water samples at concentrations above their respective 2B Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for July 2021. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Drummond, Jaclynne. "Re: Closed Town of Kernersville MSW Landfill - WQ Parameter Clarification 06140180.33" Message to Laura Elliott, June 29, 2020. E-mail. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina WithersRavenel, Inc.; July 2020 Water Quality Monitoring Report, Town of Kernersville Landfill Permit 34-04, August 31, 2020. January 2021 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.39 May 2021 Page 2 of 6 FIGURES D 0, m �1 WASTE DISPOSAL BOUNDARY ACILI OUNDARV RD xI �A, GEC �4 { .��.. �_,: GRAPHIC SCALD-' RIC 0 500 1000 2Q 1 inch = 1000 ft. 1 VVYN Vr 1%tKNr-KJV1LLr- DRAWN BY: SCALE FIGURE ND.: W i t h e rs Ra ve n e l CLOSED LANDFILL - PERMIT #34-04 MDF 1"=1000 1 1/ Engineers Planners Surveyors GOODWILL CHURCH ROAD APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, GUILFORD/FORSYTH COUNTY, NC 115 MacKenan Drive l Cary. NC 275111 t: 919A69.3340 I license #:C-08321 v"v"'<.withemravenel.com GENERAL LOCATION MAP SMB 04/20/2021 06140180.39 IC�IAL-011D�I�OItl,SS-Sm /SS Le"M 11-1� rK 20MEmia\iftenls Er i J 1019V0190918_19ete.Me- IF— S 2020 - BO MY. ASIEY GOODWILL CHURCH ROAD fFf / _44 it LEGEND ^f� y` �" : FACILITY BOUNDARY ROAD;;. �., ' hi� q' ' 'tip• WASTE DISPOSAL BOUNDARY ' MW-6 GROUNDWATER MONITORING WELL - MW-1 G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM � 3 L FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY SW-2 MW-3D GIS DEPARTMENTS. MW-4 MW-3S MW-2R MW-5 SW-3 � 0 SW-1 GRAPHIC SCALE '^ 0 150 300 600 1 inch = 300 ft. w DRAWN BY: SCALE: FIGURE NO.: WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL -PERMIT 34-04 MDF 1"=300' 2 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD WATER QUALITY SAMPLE LOCATIONS MAP APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA us MarKeran DriveI wry. NC vsu I e: eie.aee.asao 1 license s: c-osaz I www.wane.s.--l.com SM B 04/15/2021 06140180.39 IL:%I4kI4-0I8Ih I40IlDM-Sne 033 L-Wil. Senka M 2020XC-!,.',I a le OM DePwweeY X*0 Even . 2012V0120218_13eeel - r m & 2020 - BIU MI. ASmM j?o A D W ., ■■ Wi thersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 .. Engineers I Planners I Surveyors GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 Mx!([nan Dr:mrc I Cary, NC 275I11 t IMA469.33401 Il� t. C�0832 1 GOODWILL CHURCH ROAD LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY L�gfl10111111.1Di►►►IsrIa a►►«30u0]:Nu14ATIV►aII I (761.96) GROUNDWATER SURFACE ELEVATION I NOTES: POTENTIOMETRIC MAP (JANUARY 2021) W,14i1h01W\I401W-%-am &* U-M S-i - rK GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFOR❑ AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: LRE 1"=300 3A APPROVED BY: DATE: PROJECT NO.: 5MB 04/15/2021 06140180.39 6y—Vw— '-ME . Lrr 10. 2M - BLOIL L F� qti Ro A D "60 �S \ S (752.62) M 3D M W-4 (754.22) MW 3S (751.10) U Un 765 770 t 4, 00 i fJJ h 4. MW-1 (DRY) >>c 1p 0 IvIW-2R (759.17) V01 Ln 0 0 MW-5 (768.57) MW-6 (788.90) GOODWILL CHURCH ROAD F, y LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY ,Ii� GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. y4 ~ GRAPHIC SCALE 0 150 300 600 o�ff r w 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 POTENTIOMETRIC MAP LRE 1"=300' 3B 1/ Engineers I Planners I Surveyors GOODWILL CHURCH ROAD (JULY 2020) APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 115 MacKenan Drive Cary, NC 27511 t 919.469.3340 license #: C-0832 SMB 08/21/2020 06140180.39 MN,14k14 -01!D\140180M— -- &M L..M SwW— FM 202ftOnAa\ m - A,ao! 76 9070' — MJX f. WN F� �Q MW-3D 1,2-DICHLORQETHANE O 1,2-DICHLOROPROPANE A p VINYL CHLORIDE MW-4 VINYL CHLORIDE M W -35 CADMIUM VINYLCHLORIDE JAN. 2021 JULY 2020 11.6 10A JAN. 2021 JULY 2020 0,656 J 0.711 J 1.02 1.11 8.81 10.2 GOODWILL CHURCH ROAD MW-6 MW-1 _ MW-6 JAN. 2021 JULY 2020 ALL COMPOUNDS BELOW 2L STANDARDS `%4V MW-1 JAN. 2021 JULY 2020 BENZENE 9.00 DRY ~ CADMIUM 3.12 DRY : 1,4-DICHLOROBENZENE 15.9 DRY S-W-tMW W-3D 1.2-DICHLOROETHANE 2.42 DRY cis-1,2-DICHLOROETHENE 112 DRY -4 .ti 1.2-DICHLORQPROPANE 2.55 DRY MW-3S MW-ZR MW-$ } 7NTETRACHLOROETHENE VINYLCHLORIDE 0,736 3.57 DRY DRY SW-3 G JAN. 2021 JULY 2020 3.82 < 2.00 1.51 1.85 MW-2R JAN. 2021 JULY 2020 BENZENE 3.23 3.81 1,1-DICHLOROETHANE 9.98 12.0 1,2-DICHLOROPROPANE 3.76 4.46 TRICHLOROETHENE 1.46 2.09 TETRACHLOROETHENE 0.313 J 0.507 J VINYLCHLORIDE 3.77 4.17 JAN. 2021 JULY 2020 50.0 78.9 LEGEND FACILITY BOUNDARY - - - WASTE DISPOSAL BOUNDARY ,Q� SHALLOW MONITORING WELL & DEEP MONITORING WELL N OTES: SURFACE WATER SAMPLE LOCATION 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DETECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. GRAPHIC SCALE lw!!1�50 3�0 �D 1 inch = 300 R. - ■ Withers Rave n e l TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GROUNDWATER 2L STANDARDIGWP EXCEEDANCES DRAJscY: SC1A'E:300' FIGURE 144 �. Engineers I Planners 15urveyors GOODWILL CHURCH ROAD MAP APPROVED BY: DATE: PROJECT NO.: KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA 17�M,��N�nan Orvc I Cary. NC 27511 j:- 919469.33401 lic-b'C-0&32I SMB 102/04/2019 06140180.24 TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 1/13/2021 GROUNDWATER SCREENED TOP OF CASING DEPTH WELL ID INTERVAL ELEVATION SURFACE (ft-bTOC) (feet above MSL) WATERR ELEVATION (ft-bTOC) (feet above MSL) MW-1 24.96 - 34.96 806.42 30.62 775.8 MW-2R 3.18 - 13.18 762.19 2.38 759.81 MW-3S 14.00 - 24.00 764.57 12.89 751.68 MW-3D 36.96 - 56.96 764.56 11.23 753.33 MW-4 4.40 - 14.40 760.26 5.44 754.82 MW-5 6.36 - 11.36 773.32 3.75 769.57 MW-6 10.46 - 20.46 804.87 14.56 790.31 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) 4) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 1 of 1 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY 1/8/2020 DRY DRY 7/15/2020 DRY DRY 1/13/2021 30.62 775.80 MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 1/8/2020 3.17 759.02 7/15/2020 3.02 759.17 1/13/2021 2.38 759.81 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 13.96 750.61 1/8/2020 1 13.23 751.34 7/15/2020 13.47 751.10 1/13/2021 12.89 751.68 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 1 of 3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA W R Project # 06140180.39 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-31D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 1/8/2020 11.68 752.88 7/15/2020 11.94 752.62 1/13/2021 11.23 753.33 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 1 754.37 1/8/2020 5.71 754.55 7/15/2020 6.04 1 754.22 1/13/2021 5.44 1 754.82 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 2of3 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA W R Project # 06140180.39 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 1/8/2020 3.54 769.78 7/15/2020 4.75 768.57 1/13/2021 3.75 769.57 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 1 787.38 7/24/ 2019 16.51 1 788.36 1/8/2020 17.19 787.68 7/15/2020 15.97 1 788.90 1/13/2021 14.56 790.31 Notes: 1) All measurements are in feet. 2) Elevation data is relative to Mean Sea Level. 3) Depth to water measured in feet below top of casing. 4) NM = Not Measured 3of3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 6010 Contaminant Of Concern o E ++ Q •� o0 _ L m _2 E 'C U ' o i U ±+ fC -0 U i Q. Q U -a Y V Z _� .r N v> E C > u N CAS # 7440-36-0 7440-39-3 7440-41 7 7440-43 9 7440-47 3 7440-48 4 7440-50 8 7439-92 1 7440-02-0 7782-49-2 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 1/13/2020 4.43 J 214 1.59 J 3.12 2.63 J 69.5 23.4 B BDL 7.26 J 8.85 J 6.25 J 795 MW-2R 1/13/2020 5.04 J 210 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL MW-3S 1/13/2020 BDL 152 0.466 J 3.82 2.20 J 9.14 J 15.2 B BDL 4.78 J BDL 15.8 J 229 MW-3D 1/13/2020 BDL 44.6 BDL BDL BDL BDL 3.96 BJ BDL BDL BDL BDL BDL DUP (MW-3D) 1/13/2020 BDL 45.9 BDL BDL BDL BDL 4.77 J BDL BDL BDL BDL BDL MW-4 1/13/2020 BDL 99.9 0.656 J BDL 7.01 J 2.48 J 4.68 J BDL 2.74 J I BDL BDL 8.49 J MW-5R 1/13/2020 BDL 145 1.81 J BDL 9.54 J 15.9 33.0 3.89 J BDL 61.1 141 MW-6 1/13/2020 6.62 J 67.0 BDL BDL 1.61 J BDL BDL BDL BDL BDL BDL 12.7 J Trip Blank 1/13/2020 NA NA NA NA NA NA NA NA NA NA NA NA 2L Standard/GWP (µg/L) 13 700 43 2 10 13 1,000 15 100 20 0.33 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. 8) BDL = Below (Method)_Detection_Limits NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Exceeds 2L Standard or GWP Qualifiers B The same analyte is found in the associated blank. J The identification of the analyte is acceptable; the reported value is an estimate. Page 1 of 3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 8260 a� v CD v c c o Contaminant Of Concern N N C, o 0 c r- c a�i a=i u N 0 0 0 0 t s o O o O u 41 _ C O O O u u u u cV ri C m O O 0 0 0 V u Gl t t CV Q m U) U U ri V4 ri ri CAS # 67-64-1 71-43-2 135-98-8 108-90-7 75-00-3 95-50-1 106-46-7 75-34-3 107-06-2 156-59-2 156-60-5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 1/13/2020 32.5 J a.00 0.137 J 0.252 J BDL 0.293 J 15.9 1.15 2.42 112 0.448 J MW-2R 1/13/2020 BDL 3.23 BDL 0.124 J BDL 0.136 J 4.22 0.526 J 27.1 0.815 J MW-3S 1/13/2020 161 0.328 J BDL 1.34 J 0.451 J BDL 1.55 0.429 J 0.230 J 1.35 BDL MW-3D 1/13/2020 BDL 0.571 J BDL 0.597 J 0.427 J 0.117 J 4.43 1 1.51 0.589 J 11.5 BDL DUP (MW-3D) 1/13/2020 BDL 0.607 J BDL 0.596 J 0.481 J BDL 4.56 1.56 0.656 J 11.8 BDL MW-4 1/13/2020 BDL 0.379 J BDL 0.144 J 0.739 J BDL 2.21 1.39 0.106 J 16.0 BDL MW-5R 1/13/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL MW-6 1/13/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL Trip Blank 1/13/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2L Standard/GWP (µg/L) 6,000 1 70 50 3,000 20 6 6 0.4 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protectior 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) BDL = Below (Method)_Detection_Limits NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Exceeds 2L Standard or GWP Qualifiers B The same analyte is found in the associated blank. J The identification of the analyte is acceptable; the reported value is an estimate. Page 2 of 3 TABLE 4 GROUNDWATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 8260 a.+ W N N N >Z O Contaminant Of Concern o a a m a D +� c C a ° � a� O N O N -a •i 0 N Q. � E E E O u C6.L v O. o ~ t :EN C O 'L H •� H 'L H t U H O j, Q. O Q. i u Ch N N C ri 0 LLJJ Q. L Z ri ri ri i X CAS # 78-87-5 108-20-3 100-41-4 98-82-8 99-87-6 1634-04 4 91-20-3 127-18-4 108-88-3 79-01-6 95-63-6 526-73-8 108-67-8 75-01-4 1330-20 7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qua MW-1 1/13/2020 2.55 0.280 J BDL 0.363 J 0.264 J 1.60 3.42 J U.736 J 0.391 J 1.01 1.93 0.192 J 2.91 3.57 4.34 MW-2R 1/13/2020 3.76 0.234 J BDL 0.272 J BDL 0.323 J BDL 0.313 J BDL 1.46 BDL 0.138 J BDL 3.77 BDL MW-3S 1/13/2020 0.295 J BDL BDL BDL BDL 0.162 J BDL BDL BDL BDL BDL BDL BDL 1.51 BDL MW-3D 1/13/2020 1.02 BDL BDL BDL BDL 0.351 J BDL BDL BDL BDL BDL BDL BDL 8.48 BDL DUP (MW-3D) 1/13/2020 1.00 J BDL BDL BDL BDL 0.337 J BDL BDL BDL BDL BDL BDL BDL 8.81 BDL MW-4 1/13/2020 0.281 J BDL BDL BDL BDL 0.236 J BDL BDL BDL BDL BDL BDL BDL 11.6 BDL MW-5R 1/13/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL MW-b 1/13/2020 BDL BDL 0.217 J BDL BDL BDL BDL BDL 1.80 BDL BDL BDL BDL BDL BDL Trip Blank 1/13/2020 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2L Standard/GWP (µg/L) 0.6 70 600 70 NE 20 6 0.7 600 3 400 NE 400 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) BDL = Below (Method)_Detection_Limits NA Not Analyzed by Method Shown Result Result Exceeds Laboratory Detection Limit Result Exceeds 2L Standard or GWP Qualifiers B The same analyte is found in the associated blank. J The identification of the analyte is acceptable; the reported value is an estimate. Page 3 of 3 TABLES SURFACE WATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 6010 Contaminant Of Concern T E in > u c Q Q f6 ca N co f6 U t U O U O U Z Ln M H > IV CAS # 7440-36-0 7440-38-2 7440-39-3 1 7440-41-7 1 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 1 7440-28-0 1 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 1/13/2021 BDL BDL 30.4 BDL BDL 2.02 J 1.07 J BDL BDL BDL BDL BDL BDL BDL BDL SW-2 1/13/2021 BDL BDL 33.0 BDL BDL 1.87 J 1.15 J BDL BDL BDL BDL BDL BDL BDL BDL SW-3 1/13/2021 BDL BDL 30.6 BDL BDL BDL 1.23 J BDL BDL BDL BDL BDL BDL BDL t_tBtD 213 Standard (µg7. 1,000 65.0 0.82* 183.07* NE 3.64* 13.88* 144.92* 0.3* 1 36.2* Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. * Hardness -Dependent 15A NCAC 02B Water Quality Standard, Calculated with default in -stream hardness of 25 mg/L 4) BDL = Below (Method) Detection Limits NA Not Analyzed by Method Shown Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2B Standard J The identification of the analyte is acceptable; the reported value is an estimate. Page 1 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JULY 2020) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA8260 a� c a 0 v c a G a 0 ("i -I-- Contaminant Of Concern c LU s a, Cl) v v ra c ai y c _ L E E C v E 0 C aci N O L O 0 0 O 0 0 o +C+ U N E O E O E O 3 m O O O O u Q Q d M ca co m C� M U t V L I U t I V t I U N Iri CAS # 67-64-1 107-13-1 71-43-2 1 75-27-4 75-25-2 74-83-9 78-93-3 56-23-5 108-90-7 1 75-00-3 1 67-66-3 1 74-87-3 1 96-12-8 ell ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL I I BDL I BDL BDL SW-2 1/13/2021 BDL BDL BDL I I BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL SW-3 1/13/2021 BDL BDL BDL I I BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 213 Standard (µg/L) 1.19 11 NEI NE NE NE 0.254 488 NE NE NE NE N otes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 4) BDL = Below (Method) Detection Limits NA Not Analyzed by Method Shown Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2B Standard J The identification of the analyte is acceptable; the reported value is an estimate. Page 2 of 4 TABLE 5 SURFACE WATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 8260 v c y CL cCL c a 7 v v O W C N y +L+ N a.2 O G/ C N W N t N C p O. U G1 N N f0 f6 N G1 Q CL Contaminant Of Concern ; v ° y 0 2 E 0 ° �,� 0 0 v a� v o v a o u v E E v o 0 0 0 0 o s u 0 z u c O O ;= p O L O L O L O L O L 0 N O t 0 CM N C u u u u u u ri v 0 0 0 0 0 IA 0 0 14 VI 0 14 IA T N N = N r-I N r-I w fp6 N w L ri 14 0 14 - yii ri a" i -F +L+ 14 U aL+ W CAS # 96-12-8 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 1 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 1 10061-02-6 1 100-41-4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL SW 2 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL SW-3 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 213 Standard (µg/L) NE NE E NE 488 488 NE NE NE NE NE NE NE NE NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 4) BDL = Below (Method) Detection Limits NA Not Analyzed by Method Shown Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2B Standard J The identification of the analyte is acceptable; the reported value is an estimate. Page 3 of 4 TABLES SURFACE WATER ANALYTICAL RESULTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method EPA 8260 Y m � � v c c t t c c� o O y s s v E Contaminant Of Concern 0 v c o ^oo v c U U N o U U v `p k7 E N >• L ++ y C N N L U Gl � � 0 o 0 o t U in G1 -0 t N cy y N p C O G a -I r-I N N In a-i e-i F- F- a-i e-i F i X CAS # 591-78-6 74-88-4 75-09-2 108-10-1 1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-6 1 79-00-5 1 79-01-6 1 75-69-4 1 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 1/13/2021 BDL BDL I BDL BDL T BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL SW 2 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL SW-3 1/13/2021 BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL BDL 2B Standard (µg/L) NE NE NE NE NE 1 0.7 11 NE NE 2.5 NE 0.025 NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. BDL = Below (Method) Detection Limits NA Not Analyzed by Method Shown Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2B Standard J The identification of the analyte is acceptable; the reported value is an estimate. Page 4 of 4 TABLE 6 SUMMARY OF MNA CONSTITUENTS (JANUARY 2021) (Detections Only) TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.39 Analytical Method SM 2320B SM 4500-S2D SM 4500-CI-E EPA 353.2 EPA 300.0 SM 5310B co Contaminant Of Concern M Y J, ba p o Q0U Ln U zz Ln I°U� CAS # NA 18496-25-8 16887-00-6 NA 14808-79-8 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-2R 1/13/2021 135,000 BDL 9,560 63.1 J 812 J 983 MW-3S 1/13/2021 152,000 BDL 34,600 BDL 949 J 3,590 MW-3D 1/13/2021 164,000 BDL 23,600 BDL 960 J 1,160 B MW-4 1/13/2021 169,000 BDL 21,100 BDL 728 1 J 1,230 1 B P1 MW-6 1/13/2021 16,300 BDL 1,360 66.1 J 5,390 1 1,360 1 B 2L Standard/GWP (µg/L) NE NE 250,000 10,0002 250,000 NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 4) NE = Not Established 5) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 6) BDL = Below (Method) Detection Limit NA Not Analyzed by Method Shown Qualifiers Result Result Exceeds Laboratory Detection Limit B The same analyte is found in the associated blank. Result Result Exceeds 2L Standard or GWP J The identification of the analyte is acceptable; the reported value is an estimate. P1 RPD value not applicable for sampline concentrations less than 5 time the reporting limit APPENDIX I Laboratory Analytical Reports and Field Notes I aceAnalXical o ANALYTICAL REPORT National Center for Testing &Innovation January 22, 2021 Withers & Ravenel Eng. - Standard Sample Delivery Group: L1306272 Samples Received: 01/14/2021 Project Number: 06140180.39 Description: Kernersville Landfill Site: KERNERSVILLE CLOSED LF Report To: Laura Elliott 115 MacKenan Drive Cary, NC 27511 Entire Report Reviewed By: 4�41 Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and 16 ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. a ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 1 of 52 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Fn Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 5 Sr: Sample Results 6 FS MW-1 L1306272-01 6 [Cn] MW-2 L1306272-02 8 MW-3S L1306272-03 11 FSr MW-31D L1306272-04 14 MW-4 L1306272-05 17 RC MW-5 L1306272-06 20 �GI MW-6 L1306272-07 22 SW-1 L1306272-08 25 rAl SW-2 L1306272-09 27 SW-3 L1306272-10 29 FSC DUP L1306272-11 31 TRIP BLANK L1306272-12 33 Qc: Quality Control Summary 35 Wet Chemistry by Method 2320 B-2011 35 Wet Chemistry by Method 4500S2 D-2011 36 Wet Chemistry by Method 9056A 37 Wet Chemistry by Method 9060A 39 Metals (ICP) by Method 6010D 41 Volatile Organic Compounds (GC/MS) by Method 8260D 45 GI: Glossary of Terms 49 Al: Accreditations & Locations 50 Sc: Sample Chain of Custody 51 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 2 of 52 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-1 L1306272-01 GW Laura Elliott 01/13/2113:50 01/14/2109:00 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Metals (ICP) by Method 6010D WG1606978 1 01/18/2119:47 01/19/2121:16 JDG Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2119:32 01/15/2119:32 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time MW-2 L1306272-02 GW Laura Elliott 01/13/2111:15 01/14/2109:00 4 n Method Batch Dilution Preparation Analysis Analyst Location date/time FSrdate/time Wet Chemistry by Method 2320 B-2011 WG1605904 1 01/15/2111:33 01/15/2111:33 SL Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1607763 1 01/20/2117:23 01/20/2117:23 CO Mt. Juliet, TN s QC Wet Chemistry by Method 9056A WG1605591 1 01/14/2120:18 01/14/2120:18 GB Mt. Juliet, TN Wet Chemistry by Method 9060A WG1605984 1 01/17/2106:10 01/17/2106:10 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1606978 1 01/18/2119:47 01/19/2121:19 JDG Mt. Juliet, TN G� Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2119:53 01/15/2119:53 BMB Mt. Juliet, TN $A� Collected by Collected date/time Received date/time MW-3S L1306272-03 GW Laura Elliott 01/13/2110:15 01/14/2109:00 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1605904 1 01/15/2111:41 01/15/2111:41 SL Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1607763 1 01/20/2117:23 01/20/2117:23 CO Mt. Juliet, TN Wet Chemistry by Method 9056A WG1605591 1 01/14/21 20:34 01/14/21 20:34 GB Mt. Juliet, TN Wet Chemistry by Method 9060A WG1605984 1 01/17/21 06:34 01/17/21 06:34 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1606978 1 01/18/2119:47 01/19/21 21:22 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/21 20:14 01/15/21 20:14 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3D L1306272-04 GW Laura Elliott 01/13/2111:15 01/14/2109:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1605904 1 01/15/2112:04 01/15/2112:04 SL Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1607763 1 01/20/2117:23 01/20/2117:23 CO Mt. Juliet, TN Wet Chemistry by Method 9056A WG1605591 1 01/14/2120:50 01/14/2120:50 GB Mt. Juliet, TN Wet Chemistry by Method 9060A WG1605984 1 01/17/2106:53 01/17/2106:53 MJA Mt. Juliet, TN Metals (ICP) by Method 6010D WG1606978 1 01/18/2119:47 01/19/2121:24 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2120:35 01/15/2120:35 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1306272-05 GW Laura Elliott 01/13/2110:15 01/14/2109:00 Method Wet Chemistry by Method 2320 B-2011 Wet Chemistry by Method 4500S2 D-2011 Wet Chemistry by Method 9056A Wet Chemistry by Method 9060A Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D Batch Dilution Preparation Analysis date/time date/time WG1605904 1 01/15/2112:13 01/15/2112:13 WG1607763 1 01/20/2117:23 01/20/2117:23 WG1605591 1 01/14/2121:07 01/14/2121:07 WG1605985 1 01/15/2119:28 01/15/2119:28 WG1606979 1 01/18/2122:54 01/19/2115:39 WG1606386 1 01/15/2120:56 01/15/2120:56 Analyst SL CO GB VRP EL BMB Location Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 3 of 52 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-5 L1306272-06 GW Laura Elliott 01/13/2114:30 01/14/2109:00 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Metals (ICP) by Method 6010D WG1606979 1 01/18/2122:54 01/19/2115:41 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2121:16 01/15/2121:16 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time MW-6 L1306272-07 GW Laura Elliott 01/13/2113:30 01/14/2109:00 4 n Method Batch Dilution Preparation Analysis Analyst Location date/time FSrdate/time Wet Chemistry by Method 2320 B-2011 WG1605904 1 01/15/2112:21 01/15/2112:21 SL Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1607763 1 01/20/2117:23 01/20/2117:23 CO Mt. Juliet, TN 6 QC Wet Chemistry by Method 9056A WG1605591 1 01/14/2121:56 01/14/2121:56 GB Mt. Juliet, TN Wet Chemistry by Method 9060A WG1605985 1 01/15/2120:05 01/15/2120:05 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1606979 1 01/18/2122:54 01/19/2115:44 EL Mt. Juliet, TN G� Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2121:37 01/15/2121:37 BMB Mt. Juliet, TN $AI Collected by Collected date/time Received date/time SW-1 L1306272-08 GW Laura Elliott 01/13/2111:55 01/14/2109:00 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1606979 1 01/18/2122:54 01/19/2115:47 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/21 21:58 01/15/21 21:58 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time SW-2 L1306272-09 GW Laura Elliott 01/13/2111:30 01/14/2109:00 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1606979 1 01/18/2122:54 01/19/2115:55 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1606386 1 01/15/2122:18 01/15/2122:18 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time SW-3 L1306272-10 GW Laura Elliott 01/13/2111:50 01/14/2109:00 Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D DUP L1306272-11 GW Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D TRIP BLANK L1306272-12 GW Method Volatile Organic Compounds (GC/MS) by Method 8260D Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1606979 1 01/18/2122:54 01/19/2115:58 EL Mt. Juliet, TN WG1606386 1 01/15/2122:41 01/15/2122:41 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 01/13/2111:20 01/14/2109:00 Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1606979 1 01/18/2122:54 01/19/2116:01 EL Mt. Juliet, TN WG1606386 1 01/15/2123:00 01/15/2123:00 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time Laura Elliott 01/13/2100:00 01/14/2109:00 Batch Dilution Preparation Analysis Analyst Location date/time date/time WG1606386 1 01/15/2115:02 01/15/2115:02 JAH Mt. Juliet, TN ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1306272 01/22/21 00:38 4 of 52 CASE NARRATIVE ONE LAB. NATIONWIDE. FP1 All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FTChave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. FSr FC-1 4�j �GI Heather J Wagner FAI Project Manager FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 5 of 52 M W-1 SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 13:50 L1306272 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 4.43 J 4.30 10.0 1 01/19/202121:16 WG1606978 Arsenic J 4.40 10.0 1 01/19/202121:16 WG1606978 Barium 214 0.736 5.00 1 01/19/202121:16 WG1606978 Beryllium 1.59 J 0.330 2.00 1 01/19/202121:16 WG1606978 Cadmium 3.12 0.479 2.00 1 01/19/202121:16 WG1606978 Chromium 2.63 J 1.40 10.0 1 01/19/202121:16 WG1606978 Cobalt 69.5 0.840 10.0 1 01/19/202121:16 WG1606978 Copper 23.4 B 3.68 10.0 1 01/19/202121:16 WG1606978 Lead J 2.99 6.00 1 01/19/202121:16 WG1606978 Nickel 7.26 J 1.61 10.0 1 01/19/202121:16 WG1606978 Selenium 8.85 J 7.35 10.0 1 01/19/202121:16 WG1606978 Silver J 1.54 5.00 1 01/19/202121:16 WG1606978 Thallium J 4.31 10.0 1 01/19/202121:16 WG1606978 Vanadium 6.25 J 4.99 20.0 1 01/19/202121:16 WG1606978 Zinc 795 6.52 50.0 1 01/19/202121:16 WG1606978 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Acetone Acrolein Acrylonitrile Benzene Bromobenzene Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec -Butyl benzene ter[-Butylbenzene Carbon tetrachloride Chlorobenzene Chlorodibromomethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-Chloropropane 1,2-Dibromoethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time 32.5 J 11.3 50.0 1 01/15/202119:32 J 2.54 50.0 1 01/15/202119:32 U 0.671 10.0 1 01/15/202119:32 9.00 0.0941 1.00 1 01/15/202119:32 U 0.118 1.00 1 01/15/202119:32 J 0.136 1.00 1 01/15/202119:32 J 0.129 1.00 1 01/15/202119:32 J 0.605 5.00 1 01/15/202119:32 J 0.157 1.00 1 01/15/202119:32 0.137 J 0.125 1.00 1 01/15/202119:32 U 0.127 1.00 1 01/15/202119:32 J 0.128 1.00 1 01/15/202119:32 0.252 J 0.116 1.00 1 01/15/202119:32 J 0.140 1.00 1 01/15/202119:32 U 0.192 5.00 1 01/15/202119:32 J 0.111 5.00 1 01/15/202119:32 J 0.960 2.50 1 01/15/202119:32 J 0.106 1.00 1 01/15/202119:32 J 0.114 1.00 1 01/15/202119:32 J 0.276 5.00 1 01/15/202119:32 U 0.126 1.00 1 01/15/202119:32 J 0.122 1.00 1 01/15/202119:32 0.293 J 0.107 1.00 1 01/15/202119:32 J 0.110 1.00 1 01/15/202119:32 15.9 0.120 1.00 1 01/15/202119:32 J 0.374 5.00 1 01/15/202119:32 1.15 0.100 1.00 1 01/15/202119:32 2.42 0.0819 1.00 1 01/15/202119:32 J 0.188 1.00 1 01/15/202119:32 112 0.126 1.00 1 01/15/202119:32 0.448 J 0.149 1.00 1 01/15/202119:32 2.55 0.149 1.00 1 01/15/202119:32 J 0.142 1.00 1 01/15/202119:32 U 0.110 1.00 1 01/15/202119:32 J 0.111 1.00 1 01/15/202119:32 U 0.118 1.00 1 01/15/202119:32 Batch WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 FP1 FTc FSS 4 Cn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 6 of 52 ONE LAB. NATIONWIDE. MW-1 SAMPLE RESULTS - 01 Collected date/time: 01/13/21 13:50 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-T ri c h l o ro eth a n e 1,1,2-Trich I oroetha n e Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tri methyl benzen e 1,2,3-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride Xylenes, Total (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time IJ 0.161 1.00 1 01/15/202119:32 0.280 J 0.105 1.00 1 01/15/202119:32 U 0.137 1.00 1 01/15/202119:32 IJ 0.337 1.00 1 01/15/202119:32 0.363 J 0.105 1.00 1 01/15/202119:32 0.264 1_ 0.120 1.00 1 01/15/202119:32 IJ 1.19 10.0 1 01/15/202119:32 J 0.430 5.00 1 01/15/202119:32 IJ 0.478 10.0 1 01/15/202119:32 1.60 0.101 1.00 1 01/15/202119:32 3.42 J 1.00 5.00 1 01/15/202119:32 IJ 0.0993 1.00 1 01/15/202119:32 IJ 0.118 1.00 1 01/15/202119:32 IJ 0.147 1.00 1 01/15/202119:32 IJ 0.133 1.00 1 01/15/202119:32 J 0.180 1.00 1 01/15/202119:32 0.736 J 0.300 1.00 1 01/15/202119:32 0.391 1_ 0.278 1.00 1 01/15/202119:32 IJ 0.230 1.00 1 01/15/202119:32 IJ 0.481 1.00 1 01/15/202119:32 IJ 0.149 1.00 1 01/15/202119:32 IJ 0.158 1.00 1 01/15/202119:32 1.01 0.190 1.00 1 01/15/202119:32 J 0.160 5.00 1 01/15/202119:32 IJ 0.237 2.50 1 01/15/202119:32 1.93 0.322 1.00 1 01/15/202119:32 0.192 J 0.104 1.00 1 01/15/202119:32 2.91 0.104 1.00 1 01/15/202119:32 3.57 0.234 1.00 1 01/15/202119:32 4.34 0.174 3.00 1 01/15/202119:32 98.4 80.0-120 011151202119:32 101 77.0-126 011151202119:32 98.5 70.0-130 011151202119:32 Batch WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 Fp FTc FS Fn FC] F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 7 of 52 MW-2 SAMPLE RESULTS - 02 Collected date/time: 01/13/21 11:15 L1306272 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 135000 8450 Sample Narrative: L1306272-02 WG1605904: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 01/15/202111:33 WG1605904 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 01/20/202117:23 WG1607763 Result Qualifier MDL Analyte ug/I _ ug/I Chloride 9560 379 Nitrate 63.1 J 48.0 Sulfate 812 J 594 Wet Chemistry by Method 9060A RDL Dilution Analysis Batch ug/I date / time 1000 1 01/14/202120:18 WG1605591 100 1 01/14/202120:18 WG1605591 5000 1 01/14/202120:18 WG1605591 ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc 7G1 FAI FSC Result Analyte ug/I TOC (Total Organic Carbon) 983 Metals (ICP) by Method 6010D Qualifier B J MDL ug/I 102 RDL ug/I 1000 Dilution Analysis date / time 1 01/17/202106:10 Batch WG1605984 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 5.04 J 4.30 10.0 1 01/19/202121:19 WG1606978 Arsenic J 4.40 10.0 1 01/19/202121:19 WG1606978 Barium 210 0.736 5.00 1 01/19/202121:19 WG1606978 Beryllium J 0.330 2.00 1 01/19/202121:19 WG1606978 Cadmium IJ 0.479 2.00 1 01/19/202121:19 WG1606978 Chromium J 1.40 10.0 1 01/19/202121:19 WG1606978 Cobalt IJ 0.840 10.0 1 01/19/202121:19 WG1606978 Copper J 3.68 10.0 1 01/19/202121:19 WG1606978 Lead U 2.99 6.00 1 01/19/202121:19 WG1606978 Nickel J 1.61 10.0 1 01/19/202121:19 WG1606978 Selenium U 7.35 10.0 1 01/19/202121:19 WG1606978 Silver J 1.54 5.00 1 01/19/202121:19 WG1606978 Thallium U 4.31 10.0 1 01/19/202121:19 WG1606978 Vanadium J 4.99 20.0 1 01/19/202121:19 WG1606978 Zinc U 6.52 50.0 1 01/19/202121:19 WG1606978 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein J 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 3.23 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane J 0.136 1.00 Bromoform J 0.129 1.00 Bromomethane J 0.605 5.00 n-Butylbenzene J 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 1 01/15/202119:53 WG1606386 SDG: DATE/TIME: PAGE: L1306272 01/22/21 00:38 8 of 52 ONE LAB. NATIONWIDE. MW-2 SAMPLE RESULTS - 02 Collected date/time: 01/13/21 11:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 01/15/202119:53 WG1606386 tert-Butylbenzene U 0.127 1.00 1 01/15/202119:53 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202119:53 WG1606386 Chlorobenzene 0.124 J 0.116 1.00 1 01/15/202119:53 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202119:53 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202119:53 WG1606386 Chloroform U 0.111 5.00 1 01/15/202119:53 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202119:53 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202119:53 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202119:53 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202119:53 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202119:53 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202119:53 WG1606386 1,2-Dichlorobenzene 0.136 J 0.107 1.00 1 01/15/202119:53 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202119:53 WG1606386 1,4-Dichlorobenzene 4.22 0.120 1.00 1 01/15/202119:53 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202119:53 WG1606386 1,1-Dichloroethane 9.98 0.100 1.00 1 01/15/202119:53 WG1606386 1,2-Dichloroethane 0.526 1_ 0.0819 1.00 1 01/15/202119:53 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202119:53 WG1606386 cis-1,2-Dichloroethene 27.1 0.126 1.00 1 01/15/202119:53 WG1606386 trans-1,2-Dichloroethene 0.815 J 0.149 1.00 1 01/15/202119:53 WG1606386 1,2-Dichloropropane 3.76 0.149 1.00 1 01/15/202119:53 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202119:53 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202119:53 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202119:53 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202119:53 WG1606386 2,2-Dichloropropane U 0.161 1.00 1 01/15/202119:53 WG1606386 Di -isopropyl ether 0.234 J_ 0.105 1.00 1 01/15/202119:53 WG1606386 Ethylbenzene U 0.137 1.00 1 01/15/202119:53 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202119:53 WG1606386 Isopropylbenzene 0.272 J 0.105 1.00 1 01/15/202119:53 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202119:53 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202119:53 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202119:53 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202119:53 WG1606386 Methyl tert-butyl ether 0.323 J_ 0.101 1.00 1 01/15/202119:53 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202119:53 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202119:53 WG1606386 Styrene U 0.118 1.00 1 01/15/202119:53 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202119:53 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202119:53 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202119:53 WG1606386 Tetrachloroethene 0.313 J 0.300 1.00 1 01/15/202119:53 WG1606386 Toluene U 0.278 1.00 1 01/15/202119:53 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202119:53 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202119:53 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202119:53 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202119:53 WG1606386 Trichloroethene 1.46 0.190 1.00 1 01/15/202119:53 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202119:53 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202119:53 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202119:53 WG1606386 1,2,3-Trimethyl benzene 0.138 J 0.104 1.00 1 01/15/202119:53 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202119:53 WG1606386 Vinyl chloride 3.77 0.234 1.00 1 01/15/202119:53 WG1606386 FP1 FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 9 of 52 MW-2 SAMPLE RESULTS - 02 Collected date/time: 01/13/21 11:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 01/15/202119:53 WG1606386 (S) Toluene-d8 98.3 80.0-120 011151202119:53 WG1606386 (S) 4-Bromof/uorobenzene 102 77.0-126 011151202119:53 WG1606386 (S)1,2-Dich/oroethone-d4 97.1 70.0-130 011151202119:53 WG1606386 Cp FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 PAGE: 10 of 52 ■ MW-3S SAMPLE RESULTS - 03 Collected date/time: 01/13/21 10:15 L1306272 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Alkalinity 152000 8450 20000 1 01/15/202111:41 WG1605904 Sample Narrative: L1306272-03 WG1605904: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 01/20/202117:23 WG1607763 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 34600 379 1000 1 01/14/202120:34 WG1605591 Nitrate J 48.0 100 1 01/14/202120:34 WG1605591 Sulfate 949 J 594 5000 1 01/14/202120:34 WG1605591 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc 7G1 FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time TOC (Total Organic Carbon) 3590 102 1000 1 01/17/202106:34 WG1605984 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 01/19/202121:22 WG1606978 Arsenic J 4.40 10.0 1 01/19/202121:22 WG1606978 Barium 152 0.736 5.00 1 01/19/202121:22 WG1606978 Beryllium 0.466 J 0.330 2.00 1 01/19/202121:22 WG1606978 Cadmium 3.82 0.479 2.00 1 01/19/202121:22 WG1606978 Chromium 2.20 J 1.40 10.0 1 01/19/202121:22 WG1606978 Cobalt 9.14 J 0.840 10.0 1 01/19/202121:22 WG1606978 Copper 15.2 B 3.68 10.0 1 01/19/202121:22 WG1606978 Lead J 2.99 6.00 1 01/19/202121:22 WG1606978 Nickel 4.78 J 1.61 10.0 1 01/19/202121:22 WG1606978 Selenium J 7.35 10.0 1 01/19/202121:22 WG1606978 Silver J 1.54 5.00 1 01/19/202121:22 WG1606978 Thallium U 4.31 10.0 1 01/19/202121:22 WG1606978 Vanadium 15.8 J 4.99 20.0 1 01/19/202121:22 WG1606978 Zinc 229 6.52 50.0 1 01/19/202121:22 WG1606978 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone 161 11.3 50.0 1 01/15/202120:14 WG1606386 Acrolein J 2.54 50.0 1 01/15/202120:14 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202120:14 WG1606386 Benzene 0.328 J 0.0941 1.00 1 01/15/202120:14 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202120:14 WG1606386 Bromodichloromethane J 0.136 1.00 1 01/15/202120:14 WG1606386 Bromoform J 0.129 1.00 1 01/15/202120:14 WG1606386 Bromomethane J 0.605 5.00 1 01/15/202120:14 WG1606386 n-Butylbenzene J 0.157 1.00 1 01/15/202120:14 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 11 of 52 ONE LAB. NATIONWIDE. MW-3S SAMPLE RESULTS - 03 Collected date/time: 01/13/21 10:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 01/15/202120:14 WG1606386 tert-Butylbenzene U 0.127 1.00 1 01/15/202120:14 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202120:14 WG1606386 Chlorobenzene 1.34 0.116 1.00 1 01/15/202120:14 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202120:14 WG1606386 Chloroethane 0.451 J 0.192 5.00 1 01/15/202120:14 WG1606386 Chloroform U 0.111 5.00 1 01/15/202120:14 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202120:14 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202120:14 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202120:14 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202120:14 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202120:14 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202120:14 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202120:14 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202120:14 WG1606386 1,4-Dichlorobenzene 1.55 0.120 1.00 1 01/15/202120:14 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202120:14 WG1606386 1,1-Dichloroethane 0.429 J 0.100 1.00 1 01/15/202120:14 WG1606386 1,2-Dichloroethane 0.230 1_ 0.0819 1.00 1 01/15/202120:14 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202120:14 WG1606386 cis-1,2-Dichloroethene 1.35 0.126 1.00 1 01/15/202120:14 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202120:14 WG1606386 1,2-Dichloropropane 0.295 J_ 0.149 1.00 1 01/15/202120:14 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202120:14 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202120:14 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202120:14 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202120:14 WG1606386 2,2-Dichloropropane U 0.161 1.00 1 01/15/202120:14 WG1606386 Di -isopropyl ether U 0.105 1.00 1 01/15/202120:14 WG1606386 Ethylbenzene U 0.137 1.00 1 01/15/202120:14 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202120:14 WG1606386 Isopropylbenzene U 0.105 1.00 1 01/15/202120:14 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202120:14 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202120:14 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202120:14 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202120:14 WG1606386 Methyl tert-butyl ether 0.162 J_ 0.101 1.00 1 01/15/202120:14 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202120:14 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202120:14 WG1606386 Styrene U 0.118 1.00 1 01/15/202120:14 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202120:14 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202120:14 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202120:14 WG1606386 Tetrachloroethene U 0.300 1.00 1 01/15/202120:14 WG1606386 Toluene U 0.278 1.00 1 01/15/202120:14 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202120:14 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202120:14 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202120:14 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202120:14 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202120:14 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202120:14 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202120:14 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202120:14 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202120:14 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202120:14 WG1606386 Vinyl chloride 1.51 0.234 1.00 1 01/15/202120:14 WG1606386 FP1 FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 12 of 52 MW-3S SAMPLE RESULTS - 03 Collected date/time: 01/13/21 10:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 01/15/202120:14 WG1606386 (S) Toluene-d8 97.1 80.0-120 011151202120:14 WG1606386 (S) 4-Bromof/uorobenzene 102 77.0-126 011151202120:14 WG1606386 (S)1,2-Dich/oroethone-d4 95.6 70.0-130 011151202120:14 WG1606386 Cp FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 PAGE: 13 of 52 MW-3D SAMPLE RESULTS - 04 Collected date/time: 01/13/21 11:15 L1306272 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 164000 8450 Sample Narrative: L1306272-04 WG1605904: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 01/15/202112:04 WG1605904 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 01/20/202117:23 WG1607763 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Chloride 23600 379 1000 1 01/14/202120:50 WG1605591 Nitrate J 48.0 100 1 01/14/202120:50 WG1605591 Sulfate 960 J 594 5000 1 01/14/202120:50 WG1605591 Wet Chemistry by Method 9060A ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] Rc �GI FAI FSC Result Analyte ug/I TOC (Total Organic Carbon) 1160 Metals (ICP) by Method 6010D Qualifier B MDL ug/I 102 RDL ug/I 1000 Dilution Analysis date / time 1 01/17/202106:53 Batch WG1605984 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 01/19/202121:24 WG1606978 Arsenic J 4.40 10.0 1 01/19/202121:24 WG1606978 Barium 44.6 0.736 5.00 1 01/19/202121:24 WG1606978 Beryllium J 0.330 2.00 1 01/19/202121:24 WG1606978 Cadmium IJ 0.479 2.00 1 01/19/202121:24 WG1606978 Chromium J 1.40 10.0 1 01/19/202121:24 WG1606978 Cobalt U 0.840 10.0 1 01/19/202121:24 WG1606978 Copper 3.96 B J 3.68 10.0 1 01/19/202121:24 WG1606978 Lead U 2.99 6.00 1 01/19/202121:24 WG1606978 Nickel J 1.61 10.0 1 01/19/202121:24 WG1606978 Selenium U 7.35 10.0 1 01/19/202121:24 WG1606978 Silver J 1.54 5.00 1 01/19/202121:24 WG1606978 Thallium U 4.31 10.0 1 01/19/202121:24 WG1606978 Vanadium J 4.99 20.0 1 01/19/202121:24 WG1606978 Zinc U 6.52 50.0 1 01/19/202121:24 WG1606978 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein J 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.571 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane J 0.136 1.00 Bromoform J 0.129 1.00 Bromomethane J 0.605 5.00 n-Butylbenzene J 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis date / time Batch 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 1 01/15/202120:35 WG1606386 SDG: DATE/TIME: PAGE: L1306272 01/22/21 00:38 14 of 52 ONE LAB. NATIONWIDE. MW-3D SAMPLE RESULTS - 04 Collected date/time: 01/13/21 11:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 01/15/202120:35 WG1606386 tert-Butylbenzene U 0.127 1.00 1 01/15/202120:35 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202120:35 WG1606386 Chlorobenzene 0.597 J 0.116 1.00 1 01/15/202120:35 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202120:35 WG1606386 Chloroethane 0.427 J 0.192 5.00 1 01/15/202120:35 WG1606386 Chloroform U 0.111 5.00 1 01/15/202120:35 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202120:35 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202120:35 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202120:35 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202120:35 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202120:35 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202120:35 WG1606386 1,2-Dichlorobenzene 0.117 J 0.107 1.00 1 01/15/202120:35 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202120:35 WG1606386 1,4-Dichlorobenzene 4.43 0.120 1.00 1 01/15/202120:35 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202120:35 WG1606386 1,1-Dichloroethane 1.51 0.100 1.00 1 01/15/202120:35 WG1606386 1,2-Dichloroethane 0.589 1_ 0.0819 1.00 1 01/15/202120:35 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202120:35 WG1606386 cis-1,2-Dichloroethene 11.5 0.126 1.00 1 01/15/202120:35 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202120:35 WG1606386 1,2-Dichloropropane 1.02 0.149 1.00 1 01/15/202120:35 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202120:35 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202120:35 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202120:35 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202120:35 WG1606386 2,2-Dichloropropane U 0.161 1.00 1 01/15/202120:35 WG1606386 Di -isopropyl ether U 0.105 1.00 1 01/15/202120:35 WG1606386 Ethylbenzene U 0.137 1.00 1 01/15/202120:35 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202120:35 WG1606386 Isopropylbenzene U 0.105 1.00 1 01/15/202120:35 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202120:35 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202120:35 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202120:35 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202120:35 WG1606386 Methyl tert-butyl ether 0.351 J_ 0.101 1.00 1 01/15/202120:35 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202120:35 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202120:35 WG1606386 Styrene U 0.118 1.00 1 01/15/202120:35 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202120:35 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202120:35 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202120:35 WG1606386 Tetrachloroethene U 0.300 1.00 1 01/15/202120:35 WG1606386 Toluene U 0.278 1.00 1 01/15/202120:35 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202120:35 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202120:35 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202120:35 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202120:35 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202120:35 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202120:35 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202120:35 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202120:35 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202120:35 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202120:35 WG1606386 Vinyl chloride 8.48 0.234 1.00 1 01/15/202120:35 WG1606386 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 15 of 52 MW-3D SAMPLE RESULTS - 04 Collected date/time: 01/13/21 11:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 01/15/202120:35 WG1606386 (S) Toluene-d8 98.8 80.0-120 011151202120:35 WG1606386 (S 4-Bromof/uorobenzene 101 77.0-126 011151202120:35 WG1606386 (S 1,2-Dich/oroethone-d4 96.9 70.0-130 011151202120:35 WG1606386 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 PAGE: 16 of 52 MW-4 SAMPLE RESULTS - 05 Collected date/time: 01/13/21 10:15 L1306272 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 169000 8450 Sample Narrative: L1306272-05 WG1605904: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 01/15/202112:13 WG1605904 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 01/20/202117:23 WG1607763 Result Qualifier MDL Analyte ug/I ug/I Chloride 21100 379 Nitrate J 48.0 Sulfate 728 J 594 Wet Chemistry by Method 9060A RDL Dilution Analysis Batch ug/I date / time 1000 1 01/14/202121:07 WG1605591 100 1 01/14/202121:07 WG1605591 5000 1 01/14/202121:07 WG1605591 ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc 7G1 FAI FSC Result Analyte ug/I TOC (Total Organic Carbon) 1230 Metals (ICP) by Method 6010D Qualifier B P1 MDL ug/I 102 RDL ug/I 1000 Dilution Analysis date / time 1 01/15/202119:28 Batch WG1605985 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony U 4.30 10.0 1 01/19/202115:39 WG1606979 Arsenic J 4.40 10.0 1 01/19/202115:39 WG1606979 Barium 99.9 0.736 5.00 1 01/19/202115:39 WG1606979 Beryllium 0.656 J 0.330 2.00 1 01/19/202115:39 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:39 WG1606979 Chromium 7.01 J 1.40 10.0 1 01/19/202115:39 WG1606979 Cobalt 2.48 J 0.840 10.0 1 01/19/202115:39 WG1606979 Copper 4.68 J 3.68 10.0 1 01/19/202115:39 WG1606979 Lead U 2.99 6.00 1 01/19/202115:39 WG1606979 Nickel 2.74 J 1.61 10.0 1 01/19/202115:39 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:39 WG1606979 Silver J 1.54 5.00 1 01/19/202115:39 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:39 WG1606979 Vanadium J 4.99 20.0 1 01/19/202115:39 WG1606979 Zinc 8.49 J 6.52 50.0 1 01/19/202115:39 WG1606979 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein J 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene 0.379 J 0.0941 1.00 Bromobenzene U 0.118 1.00 Bromodichloromethane J 0.136 1.00 Bromoform J 0.129 1.00 Bromomethane J 0.605 5.00 n-Butylbenzene J 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 1 01/15/202120:56 WG1606386 SDG: DATE/TIME: PAGE: L1306272 01/22/21 00:38 17 of 52 ONE LAB. NATIONWIDE. MW-4 SAMPLE RESULTS - 05 Collected date/time: 01/13/21 10:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 01/15/202120:56 WG1606386 tert-Butylbenzene U 0.127 1.00 1 01/15/202120:56 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202120:56 WG1606386 Chlorobenzene 0.144 J 0.116 1.00 1 01/15/202120:56 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202120:56 WG1606386 Chloroethane 0.739 J 0.192 5.00 1 01/15/202120:56 WG1606386 Chloroform U 0.111 5.00 1 01/15/202120:56 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202120:56 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202120:56 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202120:56 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202120:56 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202120:56 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202120:56 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202120:56 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202120:56 WG1606386 1,4-Dichlorobenzene 2.21 0.120 1.00 1 01/15/202120:56 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202120:56 WG1606386 1,1-Dichloroethane 1.39 0.100 1.00 1 01/15/202120:56 WG1606386 1,2-Dichloroethane 0.106 J 0.0819 1.00 1 01/15/202120:56 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202120:56 WG1606386 cis-1,2-Dichloroethene 16.0 0.126 1.00 1 01/15/202120:56 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202120:56 WG1606386 1,2-Dichloropropane 0.281 J_ 0.149 1.00 1 01/15/202120:56 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202120:56 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202120:56 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202120:56 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202120:56 WG1606386 2,2-Dichloropropane U 0.161 1.00 1 01/15/202120:56 WG1606386 Di -isopropyl ether U 0.105 1.00 1 01/15/202120:56 WG1606386 Ethylbenzene U 0.137 1.00 1 01/15/202120:56 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202120:56 WG1606386 Isopropylbenzene U 0.105 1.00 1 01/15/202120:56 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202120:56 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202120:56 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202120:56 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202120:56 WG1606386 Methyl tert-butyl ether 0.236 J_ 0.101 1.00 1 01/15/202120:56 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202120:56 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202120:56 WG1606386 Styrene U 0.118 1.00 1 01/15/202120:56 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202120:56 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202120:56 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202120:56 WG1606386 Tetrachloroethene U 0.300 1.00 1 01/15/202120:56 WG1606386 Toluene U 0.278 1.00 1 01/15/202120:56 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202120:56 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202120:56 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202120:56 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202120:56 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202120:56 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202120:56 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202120:56 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202120:56 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202120:56 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202120:56 WG1606386 Vinyl chloride 11.6 0.234 1.00 1 01/15/202120:56 WG1606386 FP1 FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 18 of 52 MW-4 SAMPLE RESULTS - 05 Collected date/time: 01/13/21 10:15 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 01/15/202120:56 WG1606386 (S) Toluene-d8 98.9 80.0-120 011151202120:56 WG1606386 (S) 4-Bromof/uorobenzene 99.6 77.0-126 011151202120:56 WG1606386 (S)1,2-Dich/oroethone-d4 96.8 70.0-130 011151202120:56 WG1606386 Cp FTc FSS 4 Cn Fc 7G1 FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 PAGE: 19 of 52 M W - 5 SAMPLE RESULTS - 06 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 14:30 L1306272 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 01/19/202115:41 WG1606979 FTc Arsenic U 4.40 10.0 1 01/19/202115:41 WG1606979 Barium 145 0.736 5.00 1 01/19/202115:41 WG1606979 F Beryllium 1.81 J 0.330 2.00 1 01/19/202115:41 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:41 WG1606979 Chromium 9.54 J 1.40 10.0 1 01/19/202115:41 WG1606979 4 Cfl Cobalt 15.9 0.840 10.0 1 01/19/202115:41 WG1606979 Copper 33.0 3.68 10.0 1 01/19/202115:41 WG1606979 Lead 50.0 2.99 6.00 1 01/19/202115:41 WG1606979 Nickel 3.89 J 1.61 10.0 1 01/19/202115:41 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:41 WG1606979 6 QC Silver U 1.54 5.00 1 01/19/202115:41 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:41 WG1606979 7GI Vanadium 61.1 4.99 20.0 1 01/19/202115:41 WG1606979 Zinc 141 6.52 50.0 1 01/19/202115:41 WG1606979 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 01/15/202121:16 WG1606386 Acrolein U 2.54 50.0 1 01/15/202121:16 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202121:16 WG1606386 Benzene U 0.0941 1.00 1 01/15/202121:16 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202121:16 WG1606386 Bromodichloromethane U 0.136 1.00 1 01/15/202121:16 WG1606386 Bromoform U 0.129 1.00 1 01/15/202121:16 WG1606386 Bromomethane U 0.605 5.00 1 01/15/202121:16 WG1606386 n-Butylbenzene U 0.157 1.00 1 01/15/202121:16 WG1606386 sec -Butyl benzene U 0.125 1.00 1 01/15/202121:16 WG1606386 ter[-Butylbenzene U 0.127 1.00 1 01/15/202121:16 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202121:16 WG1606386 Chlorobenzene U 0.116 1.00 1 01/15/202121:16 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202121:16 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202121:16 WG1606386 Chloroform U 0.111 5.00 1 01/15/202121:16 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202121:16 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202121:16 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202121:16 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202121:16 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202121:16 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202121:16 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202121:16 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202121:16 WG1606386 1,4-Dichlorobenzene U 0.120 1.00 1 01/15/202121:16 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202121:16 WG1606386 1,1-Dichloroethane U 0.100 1.00 1 01/15/202121:16 WG1606386 1,2-Dichloroethane U 0.0819 1.00 1 01/15/202121:16 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202121:16 WG1606386 cis-1,2-Dichloroethene U 0.126 1.00 1 01/15/202121:16 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202121:16 WG1606386 1,2-Dichloropropane U 0.149 1.00 1 01/15/202121:16 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202121:16 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202121:16 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202121:16 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202121:16 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 20 of 52 ONE LAB. NATIONWIDE. MW-5 SAMPLE RESULTS - 06 Collected date/time: 01/13/21 14:30 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 97.9 (S) 4-Bromof/uorobenzene 101 (S) 1,2-Dich/oroethane-d4 96.2 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.161 1.00 1 01/15/202121:16 WG1606386 0.105 1.00 1 01/15/202121:16 WG1606386 0.137 1.00 1 01/15/202121:16 WG1606386 0.337 1.00 1 01/15/202121:16 WG1606386 0.105 1.00 1 01/15/202121:16 WG1606386 0.120 1.00 1 01/15/202121:16 WG1606386 1.19 10.0 1 01/15/202121:16 WG1606386 0.430 5.00 1 01/15/202121:16 WG1606386 0.478 10.0 1 01/15/202121:16 WG1606386 0.101 1.00 1 01/15/202121:16 WG1606386 1.00 5.00 1 01/15/202121:16 WG1606386 0.0993 1.00 1 01/15/202121:16 WG1606386 0.118 1.00 1 01/15/202121:16 WG1606386 0.147 1.00 1 01/15/202121:16 WG1606386 0.133 1.00 1 01/15/202121:16 WG1606386 0.180 1.00 1 01/15/202121:16 WG1606386 0.300 1.00 1 01/15/202121:16 WG1606386 0.278 1.00 1 01/15/202121:16 WG1606386 0.230 1.00 1 01/15/202121:16 WG1606386 0.481 1.00 1 01/15/202121:16 WG1606386 0.149 1.00 1 01/15/202121:16 WG1606386 0.158 1.00 1 01/15/202121:16 WG1606386 0.190 1.00 1 01/15/202121:16 WG1606386 0.160 5.00 1 01/15/202121:16 WG1606386 0.237 2.50 1 01/15/202121:16 WG1606386 0.322 1.00 1 01/15/202121:16 WG1606386 0.104 1.00 1 01/15/202121:16 WG1606386 0.104 1.00 1 01/15/202121:16 WG1606386 0.234 1.00 1 01/15/202121:16 WG1606386 0.174 3.00 1 01/15/202121:16 WG1606386 80.0-120 01/15/202121:16 WG1606386 77.0-126 01/15/202121:16 WG1606386 70.0-130 01/15/202121:16 WG1606386 Fp FTc FS Fn N FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 21 of 52 MW-6 SAMPLE RESULTS - 07 Collected date/time: 01/13/21 13:30 L1306272 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL Analyte ug/I ug/I Alkalinity 16300 J 8450 Sample Narrative: L1306272-07 WG1605904: Endpoint pH 4.5 Headspace Wet Chemistry by Method 4500S2 D-2011 RDL Dilution Analysis Batch ug/I date / time 20000 1 01/15/202112:21 WG1605904 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Sulfide U Wet Chemistry by Method 9056A 25.0 50.0 1 01/20/202117:23 WG1607763 Result Qualifier MDL Analyte ug/I ug/I Chloride 1360 379 Nitrate 66.1 J 48.0 Sulfate 5390 594 Wet Chemistry by Method 9060A RDL Dilution Analysis Batch ug/I date / time 1000 1 01/14/202121:56 WG1605591 100 1 01/14/202121:56 WG1605591 5000 1 01/14/202121:56 WG1605591 ONE LAB. NATIONWIDE. FP1 FTc FSS [Cn] N Rc �GI FAI FSC Result Analyte ug/I TOC (Total Organic Carbon) 1360 Metals (ICP) by Method 6010D Qualifier B MDL ug/I 102 RDL ug/I 1000 Dilution Analysis date / time 1 01/15/202120:05 Batch WG1605985 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Antimony 6.62 J 4.30 10.0 1 01/19/202115:44 WG1606979 Arsenic J 4.40 10.0 1 01/19/202115:44 WG1606979 Barium 67.0 0.736 5.00 1 01/19/202115:44 WG1606979 Beryllium J 0.330 2.00 1 01/19/202115:44 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:44 WG1606979 Chromium 1.61 J 1.40 10.0 1 01/19/202115:44 WG1606979 Cobalt U 0.840 10.0 1 01/19/202115:44 WG1606979 Copper J 3.68 10.0 1 01/19/202115:44 WG1606979 Lead U 2.99 6.00 1 01/19/202115:44 WG1606979 Nickel J 1.61 10.0 1 01/19/202115:44 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:44 WG1606979 Silver J 1.54 5.00 1 01/19/202115:44 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:44 WG1606979 Vanadium J 4.99 20.0 1 01/19/202115:44 WG1606979 Zinc 12.7 J 6.52 50.0 1 01/19/202115:44 WG1606979 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Analyte ug/I ug/I ug/I Acetone U 11.3 50.0 Acrolein J 2.54 50.0 Acrylonitrile U 0.671 10.0 Benzene J 0.0941 1.00 Bromobenzene J 0.118 1.00 Bromodichloromethane J 0.136 1.00 Bromoform J 0.129 1.00 Bromomethane J 0.605 5.00 n-Butylbenzene J 0.157 1.00 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 Dilution Analysis Batch date / time 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 1 01/15/202121:37 WG1606386 SDG: DATE/TIME: PAGE: L1306272 01/22/21 00:38 22 of 52 ONE LAB. NATIONWIDE. MW-6 SAMPLE RESULTS - 07 Collected date/time: 01/13/21 13:30 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time sec -Butyl benzene U 0.125 1.00 1 01/15/202121:37 WG1606386 tert-Butylbenzene U 0.127 1.00 1 01/15/202121:37 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202121:37 WG1606386 Chlorobenzene U 0.116 1.00 1 01/15/202121:37 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202121:37 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202121:37 WG1606386 Chloroform U 0.111 5.00 1 01/15/202121:37 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202121:37 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202121:37 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202121:37 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202121:37 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202121:37 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202121:37 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202121:37 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202121:37 WG1606386 1,4-Dichlorobenzene U 0.120 1.00 1 01/15/202121:37 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202121:37 WG1606386 1,1-Dichloroethane U 0.100 1.00 1 01/15/202121:37 WG1606386 1,2-Dichloroethane U 0.0819 1.00 1 01/15/202121:37 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202121:37 WG1606386 cis-1,2-Dichloroethene U 0.126 1.00 1 01/15/202121:37 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202121:37 WG1606386 1,2-Dichloropropane U 0.149 1.00 1 01/15/202121:37 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202121:37 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202121:37 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202121:37 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202121:37 WG1606386 2,2-Dichloropropane U 0.161 1.00 1 01/15/202121:37 WG1606386 Di -isopropyl ether U 0.105 1.00 1 01/15/202121:37 WG1606386 Ethylbenzene 0.217 J 0.137 1.00 1 01/15/202121:37 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202121:37 WG1606386 Isopropylbenzene U 0.105 1.00 1 01/15/202121:37 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202121:37 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202121:37 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202121:37 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202121:37 WG1606386 Methyl tert-butyl ether U 0.101 1.00 1 01/15/202121:37 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202121:37 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202121:37 WG1606386 Styrene U 0.118 1.00 1 01/15/202121:37 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202121:37 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202121:37 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202121:37 WG1606386 Tetrachloroethene U 0.300 1.00 1 01/15/202121:37 WG1606386 Toluene 1.80 0.278 1.00 1 01/15/202121:37 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202121:37 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202121:37 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202121:37 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202121:37 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202121:37 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202121:37 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202121:37 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202121:37 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202121:37 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202121:37 WG1606386 Vinyl chloride U 0.234 1.00 1 01/15/202121:37 WG1606386 FP1 FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 23 of 52 MW-6 SAMPLE RESULTS - 07 Collected date/time: 01/13/21 13:30 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Xylenes, Total U 0.174 3.00 1 01/15/202121:37 WG1606386 (S) Toluene-d8 100 80.0-120 011151202121:37 WG1606386 (S) 4-Bromof/uorobenzene 101 77.0-126 01/15/202121:37 WG1606386 (S)1,2-Dich/oroethone-d4 95.9 70.0-130 01/15/202121:37 WG1606386 Cp FTc FSS 4 Cn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 PAGE: 24 of 52 SW-1 SAMPLE RESULTS - 08 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 11:55 L1306272 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 01/19/202115:47 WG1606979 FTc Arsenic U 4.40 10.0 1 01/19/202115:47 WG1606979 Barium 30.4 0.736 5.00 1 01/19/202115:47 WG1606979 F Beryllium U 0.330 2.00 1 01/19/202115:47 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:47 WG1606979 Chromium 2.02 J 1.40 10.0 1 01/19/202115:47 WG1606979 4 Cfl Cobalt 1.07 J 0.840 10.0 1 01/19/202115:47 WG1606979 Copper U 3.68 10.0 1 01/19/202115:47 WG1606979 Lead U 2.99 6.00 1 01/19/202115:47 WG1606979 Nickel U 1.61 10.0 1 01/19/202115:47 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:47 WG1606979 6 QC Silver U 1.54 5.00 1 01/19/202115:47 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:47 WG1606979 GI Vanadium U 4.99 20.0 1 01/19/202115:47 WG1606979 Zinc U 6.52 50.0 1 01/19/202115:47 WG1606979 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 01/15/202121:58 WG1606386 Acrolein U 2.54 50.0 1 01/15/202121:58 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202121:58 WG1606386 Benzene U 0.0941 1.00 1 01/15/202121:58 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202121:58 WG1606386 Bromodichloromethane U 0.136 1.00 1 01/15/202121:58 WG1606386 Bromoform U 0.129 1.00 1 01/15/202121:58 WG1606386 Bromomethane U 0.605 5.00 1 01/15/202121:58 WG1606386 n-Butylbenzene U 0.157 1.00 1 01/15/202121:58 WG1606386 sec -Butyl benzene U 0.125 1.00 1 01/15/202121:58 WG1606386 ter[-Butylbenzene U 0.127 1.00 1 01/15/202121:58 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202121:58 WG1606386 Chlorobenzene U 0.116 1.00 1 01/15/202121:58 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202121:58 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202121:58 WG1606386 Chloroform U 0.111 5.00 1 01/15/202121:58 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202121:58 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202121:58 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202121:58 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202121:58 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202121:58 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202121:58 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202121:58 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202121:58 WG1606386 1,4-Dichlorobenzene U 0.120 1.00 1 01/15/202121:58 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202121:58 WG1606386 1,1-Dichloroethane U 0.100 1.00 1 01/15/202121:58 WG1606386 1,2-Dichloroethane U 0.0819 1.00 1 01/15/202121:58 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202121:58 WG1606386 cis-1,2-Dichloroethene U 0.126 1.00 1 01/15/202121:58 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202121:58 WG1606386 1,2-Dichloropropane U 0.149 1.00 1 01/15/202121:58 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202121:58 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202121:58 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202121:58 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202121:58 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 25 of 52 ONE LAB. NATIONWIDE. SW-1 SAMPLE RESULTS - 08 Collected date/time: 01/13/21 11:55 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 99.1 (S) 4-Bromof/uorobenzene 99.0 (S) 1,2-Dich/oroethane-d4 96.8 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.161 1.00 1 01/15/202121:58 WG1606386 0.105 1.00 1 01/15/202121:58 WG1606386 0.137 1.00 1 01/15/202121:58 WG1606386 0.337 1.00 1 01/15/202121:58 WG1606386 0.105 1.00 1 01/15/202121:58 WG1606386 0.120 1.00 1 01/15/202121:58 WG1606386 1.19 10.0 1 01/15/202121:58 WG1606386 0.430 5.00 1 01/15/202121:58 WG1606386 0.478 10.0 1 01/15/202121:58 WG1606386 0.101 1.00 1 01/15/202121:58 WG1606386 1.00 5.00 1 01/15/202121:58 WG1606386 0.0993 1.00 1 01/15/202121:58 WG1606386 0.118 1.00 1 01/15/202121:58 WG1606386 0.147 1.00 1 01/15/202121:58 WG1606386 0.133 1.00 1 01/15/202121:58 WG1606386 0.180 1.00 1 01/15/202121:58 WG1606386 0.300 1.00 1 01/15/202121:58 WG1606386 0.278 1.00 1 01/15/202121:58 WG1606386 0.230 1.00 1 01/15/202121:58 WG1606386 0.481 1.00 1 01/15/202121:58 WG1606386 0.149 1.00 1 01/15/202121:58 WG1606386 0.158 1.00 1 01/15/202121:58 WG1606386 0.190 1.00 1 01/15/202121:58 WG1606386 0.160 5.00 1 01/15/202121:58 WG1606386 0.237 2.50 1 01/15/202121:58 WG1606386 0.322 1.00 1 01/15/202121:58 WG1606386 0.104 1.00 1 01/15/202121:58 WG1606386 0.104 1.00 1 01/15/202121:58 WG1606386 0.234 1.00 1 01/15/202121:58 WG1606386 0.174 3.00 1 01/15/202121:58 WG1606386 80.0-120 01/15/202121:58 WG1606386 77.0-126 01/15/202121:58 WG1606386 70.0-130 01/15/202121:58 WG1606386 FP FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 26 of 52 SW-2 SAMPLE RESULTS - 09 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 11:30 L1306272 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 01/19/202115:55 WG1606979 FTc Arsenic U 4.40 10.0 1 01/19/202115:55 WG1606979 Barium 33.0 0.736 5.00 1 01/19/202115:55 WG1606979 F Beryllium U 0.330 2.00 1 01/19/202115:55 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:55 WG1606979 Chromium 1.87 J 1.40 10.0 1 01/19/202115:55 WG1606979 4 Cfl Cobalt 1.15 J 0.840 10.0 1 01/19/202115:55 WG1606979 Copper U 3.68 10.0 1 01/19/202115:55 WG1606979 Lead U 2.99 6.00 1 01/19/202115:55 WG1606979 Nickel U 1.61 10.0 1 01/19/202115:55 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:55 WG1606979 6 QC Silver U 1.54 5.00 1 01/19/202115:55 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:55 WG1606979 7GI Vanadium U 4.99 20.0 1 01/19/202115:55 WG1606979 Zinc U 6.52 50.0 1 01/19/202115:55 WG1606979 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 01/15/202122:18 WG1606386 Acrolein U 2.54 50.0 1 01/15/202122:18 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202122:18 WG1606386 Benzene U 0.0941 1.00 1 01/15/202122:18 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202122:18 WG1606386 Bromodichloromethane U 0.136 1.00 1 01/15/202122:18 WG1606386 Bromoform U 0.129 1.00 1 01/15/202122:18 WG1606386 Bromomethane U 0.605 5.00 1 01/15/202122:18 WG1606386 n-Butylbenzene U 0.157 1.00 1 01/15/202122:18 WG1606386 sec -Butyl benzene U 0.125 1.00 1 01/15/202122:18 WG1606386 ter[-Butylbenzene U 0.127 1.00 1 01/15/202122:18 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202122:18 WG1606386 Chlorobenzene U 0.116 1.00 1 01/15/202122:18 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202122:18 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202122:18 WG1606386 Chloroform U 0.111 5.00 1 01/15/202122:18 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202122:18 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202122:18 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202122:18 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202122:18 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202122:18 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202122:18 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202122:18 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202122:18 WG1606386 1,4-Dichlorobenzene U 0.120 1.00 1 01/15/202122:18 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202122:18 WG1606386 1,1-Dichloroethane U 0.100 1.00 1 01/15/202122:18 WG1606386 1,2-Dichloroethane U 0.0819 1.00 1 01/15/202122:18 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202122:18 WG1606386 cis-1,2-Dichloroethene U 0.126 1.00 1 01/15/202122:18 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202122:18 WG1606386 1,2-Dichloropropane U 0.149 1.00 1 01/15/202122:18 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202122:18 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202122:18 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202122:18 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202122:18 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 27 of 52 ONE LAB. NATIONWIDE. SW-2 SAMPLE RESULTS - 09 Collected date/time: 01/13/21 11:30 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 100 (S) 4-Bromof/uorobenzene 99.1 (S)1,2-Dich/oroethane-d4 96.1 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.161 1.00 1 01/15/202122:18 WG1606386 0.105 1.00 1 01/15/202122:18 WG1606386 0.137 1.00 1 01/15/202122:18 WG1606386 0.337 1.00 1 01/15/202122:18 WG1606386 0.105 1.00 1 01/15/202122:18 WG1606386 0.120 1.00 1 01/15/202122:18 WG1606386 1.19 10.0 1 01/15/202122:18 WG1606386 0.430 5.00 1 01/15/202122:18 WG1606386 0.478 10.0 1 01/15/202122:18 WG1606386 0.101 1.00 1 01/15/202122:18 WG1606386 1.00 5.00 1 01/15/202122:18 WG1606386 0.0993 1.00 1 01/15/202122:18 WG1606386 0.118 1.00 1 01/15/202122:18 WG1606386 0.147 1.00 1 01/15/202122:18 WG1606386 0.133 1.00 1 01/15/202122:18 WG1606386 0.180 1.00 1 01/15/202122:18 WG1606386 0.300 1.00 1 01/15/202122:18 WG1606386 0.278 1.00 1 01/15/202122:18 WG1606386 0.230 1.00 1 01/15/202122:18 WG1606386 0.481 1.00 1 01/15/202122:18 WG1606386 0.149 1.00 1 01/15/202122:18 WG1606386 0.158 1.00 1 01/15/202122:18 WG1606386 0.190 1.00 1 01/15/202122:18 WG1606386 0.160 5.00 1 01/15/202122:18 WG1606386 0.237 2.50 1 01/15/202122:18 WG1606386 0.322 1.00 1 01/15/202122:18 WG1606386 0.104 1.00 1 01/15/202122:18 WG1606386 0.104 1.00 1 01/15/202122:18 WG1606386 0.234 1.00 1 01/15/202122:18 WG1606386 0.174 3.00 1 01/15/202122:18 WG1606386 80.0-120 01/15/202122.18 WG1606386 77.0-126 01/15/202122.18 WG1606386 70.0-130 01/15/202122.18 WG1606386 Fp FTc FS Fn N FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 28 of 52 SW-3 SAMPLE RESULTS - 10 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 11:50 L1306272 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 01/19/202115:58 WG1606979 FTc Arsenic U 4.40 10.0 1 01/19/202115:58 WG1606979 Barium 30.6 0.736 5.00 1 01/19/202115:58 WG1606979 F Beryllium U 0.330 2.00 1 01/19/202115:58 WG1606979 Cadmium U 0.479 2.00 1 01/19/202115:58 WG1606979 Chromium U 1.40 10.0 1 01/19/202115:58 WG1606979 4 Cfl Cobalt 1.23 J 0.840 10.0 1 01/19/202115:58 WG1606979 Copper U 3.68 10.0 1 01/19/202115:58 WG1606979 Lead U 2.99 6.00 1 01/19/202115:58 WG1606979 Nickel U 1.61 10.0 1 01/19/202115:58 WG1606979 Selenium U 7.35 10.0 1 01/19/202115:58 WG1606979 6 QC Silver U 1.54 5.00 1 01/19/202115:58 WG1606979 Thallium U 4.31 10.0 1 01/19/202115:58 WG1606979 GI Vanadium U 4.99 20.0 1 01/19/202115:58 WG1606979 Zinc U 6.52 50.0 1 01/19/202115:58 WG1606979 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 01/15/202122:41 WG1606386 Acrolein U 2.54 50.0 1 01/15/202122:41 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202122:41 WG1606386 Benzene U 0.0941 1.00 1 01/15/202122:41 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202122:41 WG1606386 Bromodichloromethane U 0.136 1.00 1 01/15/202122:41 WG1606386 Bromoform U 0.129 1.00 1 01/15/202122:41 WG1606386 Bromomethane U 0.605 5.00 1 01/15/202122:41 WG1606386 n-Butylbenzene U 0.157 1.00 1 01/15/202122:41 WG1606386 sec -Butyl benzene U 0.125 1.00 1 01/15/202122:41 WG1606386 ter[-Butylbenzene U 0.127 1.00 1 01/15/202122:41 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202122:41 WG1606386 Chlorobenzene U 0.116 1.00 1 01/15/202122:41 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202122:41 WG1606386 Chloroethane U 0.192 5.00 1 01/15/202122:41 WG1606386 Chloroform U 0.111 5.00 1 01/15/202122:41 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202122:41 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202122:41 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202122:41 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202122:41 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202122:41 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202122:41 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202122:41 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202122:41 WG1606386 1,4-Dichlorobenzene U 0.120 1.00 1 01/15/202122:41 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202122:41 WG1606386 1,1-Dichloroethane U 0.100 1.00 1 01/15/202122:41 WG1606386 1,2-Dichloroethane U 0.0819 1.00 1 01/15/202122:41 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202122:41 WG1606386 cis-1,2-Dichloroethene U 0.126 1.00 1 01/15/202122:41 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202122:41 WG1606386 1,2-Dichloropropane U 0.149 1.00 1 01/15/202122:41 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202122:41 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202122:41 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202122:41 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202122:41 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 29 of 52 ONE LAB. NATIONWIDE. SW-3 SAMPLE RESULTS - 10 Collected date/time: 01/13/21 11:50 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-T ri c h l o ro eth a n e 1,1,2-Trich I oroetha n e Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tri methyl benzen e 1,2,3-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride Xylenes, Total (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time IJ 0.161 1.00 1 01/15/202122:41 IJ 0.105 1.00 1 01/15/202122:41 U 0.137 1.00 1 01/15/202122:41 IJ 0.337 1.00 1 01/15/202122:41 U 0.105 1.00 1 01/15/202122:41 J 0.120 1.00 1 01/15/202122:41 IJ 1.19 10.0 1 01/15/202122:41 J 0.430 5.00 1 01/15/202122:41 IJ 0.478 10.0 1 01/15/202122:41 J 0.101 1.00 1 01/15/202122:41 IJ 1.00 5.00 1 01/15/202122:41 IJ 0.0993 1.00 1 01/15/202122:41 IJ 0.118 1.00 1 01/15/202122:41 IJ 0.147 1.00 1 01/15/202122:41 U 0.133 1.00 1 01/15/202122:41 IJ 0.180 1.00 1 01/15/202122:41 U 0.300 1.00 1 01/15/202122:41 IJ 0.278 1.00 1 01/15/202122:41 U 0.230 1.00 1 01/15/202122:41 IJ 0.481 1.00 1 01/15/202122:41 U 0.149 1.00 1 01/15/202122:41 IJ 0.158 1.00 1 01/15/202122:41 IJ 0.190 1.00 1 01/15/202122:41 J 0.160 5.00 1 01/15/202122:41 IJ 0.237 2.50 1 01/15/202122:41 J 0.322 1.00 1 01/15/202122:41 IJ 0.104 1.00 1 01/15/202122:41 J 0.104 1.00 1 01/15/202122:41 IJ 0.234 1.00 1 01/15/202122:41 IJ 0.174 3.00 1 01/15/202122:41 100 80.0-120 011151202122.41 99.4 77.0-126 011151202122.41 96.3 70.0-130 011151202122.41 Batch WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 WG1606386 FP FTc FS Fn N FC] F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 30 of 52 D U P SAMPLE RESULTS - 11 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 11:20 L1306272 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 4.30 10.0 1 01/19/202116:01 WG1606979 FTc Arsenic U 4.40 10.0 1 01/19/202116:01 WG1606979 Barium 45.9 0.736 5.00 1 01/19/202116:01 WG1606979 F Beryllium U 0.330 2.00 1 01/19/202116:01 WG1606979 Cadmium U 0.479 2.00 1 01/19/202116:01 WG1606979 Chromium U 1.40 10.0 1 01/19/202116:01 WG1606979 4 Cfl Cobalt U 0.840 10.0 1 01/19/202116:01 WG1606979 Copper 4.77 J 3.68 10.0 1 01/19/202116:01 WG1606979 Lead U 2.99 6.00 1 01/19/202116:01 WG1606979 Nickel U 1.61 10.0 1 01/19/202116:01 WG1606979 Selenium U 7.35 10.0 1 01/19/202116:01 WG1606979 6 QC Silver U 1.54 5.00 1 01/19/202116:01 WG1606979 Thallium U 4.31 10.0 1 01/19/202116:01 WG1606979 GI Vanadium U 4.99 20.0 1 01/19/202116:01 WG1606979 Zinc U 6.52 50.0 1 01/19/202116:01 WG1606979 rAl Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 11.3 50.0 1 01/15/202123:00 WG1606386 Acrolein U 2.54 50.0 1 01/15/202123:00 WG1606386 Acrylonitrile U 0.671 10.0 1 01/15/202123:00 WG1606386 Benzene 0.607 J 0.0941 1.00 1 01/15/202123:00 WG1606386 Bromobenzene U 0.118 1.00 1 01/15/202123:00 WG1606386 Bromodichloromethane U 0.136 1.00 1 01/15/202123:00 WG1606386 Bromoform U 0.129 1.00 1 01/15/202123:00 WG1606386 Bromomethane U 0.605 5.00 1 01/15/202123:00 WG1606386 n-Butylbenzene U 0.157 1.00 1 01/15/202123:00 WG1606386 sec -Butyl benzene U 0.125 1.00 1 01/15/202123:00 WG1606386 ter[-Butylbenzene U 0.127 1.00 1 01/15/202123:00 WG1606386 Carbon tetrachloride U 0.128 1.00 1 01/15/202123:00 WG1606386 Chlorobenzene 0.596 J 0.116 1.00 1 01/15/202123:00 WG1606386 Chlorodibromomethane U 0.140 1.00 1 01/15/202123:00 WG1606386 Chloroethane 0.481 J 0.192 5.00 1 01/15/202123:00 WG1606386 Chloroform U 0.111 5.00 1 01/15/202123:00 WG1606386 Chloromethane U 0.960 2.50 1 01/15/202123:00 WG1606386 2-Chlorotoluene U 0.106 1.00 1 01/15/202123:00 WG1606386 4-Chlorotoluene U 0.114 1.00 1 01/15/202123:00 WG1606386 1,2-Dibromo-3-Chloropropane U 0.276 5.00 1 01/15/202123:00 WG1606386 1,2-Dibromoethane U 0.126 1.00 1 01/15/202123:00 WG1606386 Dibromomethane U 0.122 1.00 1 01/15/202123:00 WG1606386 1,2-Dichlorobenzene U 0.107 1.00 1 01/15/202123:00 WG1606386 1,3-Dichlorobenzene U 0.110 1.00 1 01/15/202123:00 WG1606386 1,4-Dichlorobenzene 4.56 0.120 1.00 1 01/15/202123:00 WG1606386 Dichlorodifluoromethane U 0.374 5.00 1 01/15/202123:00 WG1606386 1,1-Dichloroethane 1.56 0.100 1.00 1 01/15/202123:00 WG1606386 1,2-Dichloroethane 0.656 J 0.0819 1.00 1 01/15/202123:00 WG1606386 1,1-Dichloroethene U 0.188 1.00 1 01/15/202123:00 WG1606386 cis-1,2-Dichloroethene 11.8 0.126 1.00 1 01/15/202123:00 WG1606386 trans-1,2-Dichloroethene U 0.149 1.00 1 01/15/202123:00 WG1606386 1,2-Dichloropropane 1.00 J 0.149 1.00 1 01/15/202123:00 WG1606386 1,1-Dichloropropene U 0.142 1.00 1 01/15/202123:00 WG1606386 1,3-Dichloropropane U 0.110 1.00 1 01/15/202123:00 WG1606386 cis-1,3-Dichloropropene U 0.111 1.00 1 01/15/202123:00 WG1606386 trans-1,3-Dichloropropene U 0.118 1.00 1 01/15/202123:00 WG1606386 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 31 of 52 ONE LAB. NATIONWIDE. DUP SAMPLE RESULTS - 11 Collected date/time: 01/13/21 11:20 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 2,2-Dichloropropane U 0.161 1.00 1 01/15/202123:00 WG1606386 Di -isopropyl ether U 0.105 1.00 1 01/15/202123:00 WG1606386 Ethylbenzene U 0.137 1.00 1 01/15/202123:00 WG1606386 Hexachloro-1,3-butadiene U 0.337 1.00 1 01/15/202123:00 WG1606386 Isopropylbenzene U 0.105 1.00 1 01/15/202123:00 WG1606386 p-Isopropyltoluene U 0.120 1.00 1 01/15/202123:00 WG1606386 2-Butanone (MEK) U 1.19 10.0 1 01/15/202123:00 WG1606386 Methylene Chloride U 0.430 5.00 1 01/15/202123:00 WG1606386 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 1 01/15/202123:00 WG1606386 Methyl tert-butyl ether 0.337 J_ 0.101 1.00 1 01/15/202123:00 WG1606386 Naphthalene U 1.00 5.00 1 01/15/202123:00 WG1606386 n-Propylbenzene U 0.0993 1.00 1 01/15/202123:00 WG1606386 Styrene U 0.118 1.00 1 01/15/202123:00 WG1606386 1,1,1,2-Tetrachloroethane U 0.147 1.00 1 01/15/202123:00 WG1606386 1,1,2,2-Tetrachloroethane U 0.133 1.00 1 01/15/202123:00 WG1606386 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1 01/15/202123:00 WG1606386 Tetrachloroethene U 0.300 1.00 1 01/15/202123:00 WG1606386 Toluene U 0.278 1.00 1 01/15/202123:00 WG1606386 1,2,3-Trichlorobenzene U 0.230 1.00 1 01/15/202123:00 WG1606386 1,2,4-Trichlorobenzene U 0.481 1.00 1 01/15/202123:00 WG1606386 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202123:00 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202123:00 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202123:00 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202123:00 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202123:00 WG1606386 1,2,4-Trimethylbenzene U 0.322 1.00 1 01/15/202123:00 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202123:00 WG1606386 1,3,5-Trimethyl benzene U 0.104 1.00 1 01/15/202123:00 WG1606386 Vinyl chloride 8.81 0.234 1.00 1 01/15/202123:00 WG1606386 Xylenes, Total U 0.174 3.00 1 01/15/202123:00 WG1606386 (S Toluene-d8 101 80.0-120 011151202123:00 WG1606386 (S) 4-Bromof/uorobenzene 98.9 77.0-126 011151202123.00 WG1606386 (S)1,2-Dich/oroethone-d4 100 70.0-130 011151202123.00 WG1606386 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 32 of 52 TRIP BLANK SAMPLE RESULTS - 12 ONE LAB. NATIONWIDE. Collected date/time: 01/13/21 00:00 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U ter[-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U ACCOUNT: Withers & Ravenel Eng. - Standard Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 11.3 50.0 1 01/15/202115:02 WG1606386 2.54 50.0 1 01/15/202115:02 WG1606386 0.671 10.0 1 01/15/202115:02 WG1606386 0.0941 1.00 1 01/15/202115:02 WG1606386 0.118 1.00 1 01/15/202115:02 WG1606386 0.136 1.00 1 01/15/202115:02 WG1606386 0.129 1.00 1 01/15/202115:02 WG1606386 0.605 5.00 1 01/15/202115:02 WG1606386 0.157 1.00 1 01/15/202115:02 WG1606386 0.125 1.00 1 01/15/202115:02 WG1606386 0.127 1.00 1 01/15/202115:02 WG1606386 0.128 1.00 1 01/15/202115:02 WG1606386 0.116 1.00 1 01/15/202115:02 WG1606386 0.140 1.00 1 01/15/202115:02 WG1606386 0.192 5.00 1 01/15/202115:02 WG1606386 0.111 5.00 1 01/15/202115:02 WG1606386 0.960 2.50 1 01/15/202115:02 WG1606386 0.106 1.00 1 01/15/202115:02 WG1606386 0.114 1.00 1 01/15/202115:02 WG1606386 0.276 5.00 1 01/15/202115:02 WG1606386 0.126 1.00 1 01/15/202115:02 WG1606386 0.122 1.00 1 01/15/202115:02 WG1606386 0.107 1.00 1 01/15/202115:02 WG1606386 0.110 1.00 1 01/15/202115:02 WG1606386 0.120 1.00 1 01/15/202115:02 WG1606386 0.374 5.00 1 01/15/202115:02 WG1606386 0.100 1.00 1 01/15/202115:02 WG1606386 0.0819 1.00 1 01/15/202115:02 WG1606386 0.188 1.00 1 01/15/202115:02 WG1606386 0.126 1.00 1 01/15/202115:02 WG1606386 0.149 1.00 1 01/15/202115:02 WG1606386 0.149 1.00 1 01/15/202115:02 WG1606386 0.142 1.00 1 01/15/202115:02 WG1606386 0.110 1.00 1 01/15/202115:02 WG1606386 0.111 1.00 1 01/15/202115:02 WG1606386 0.118 1.00 1 01/15/202115:02 WG1606386 0.161 1.00 1 01/15/202115:02 WG1606386 0.105 1.00 1 01/15/202115:02 WG1606386 0.137 1.00 1 01/15/202115:02 WG1606386 0.337 1.00 1 01/15/202115:02 WG1606386 0.105 1.00 1 01/15/202115:02 WG1606386 0.120 1.00 1 01/15/202115:02 WG1606386 1.19 10.0 1 01/15/202115:02 WG1606386 0.430 5.00 1 01/15/202115:02 WG1606386 0.478 10.0 1 01/15/202115:02 WG1606386 0.101 1.00 1 01/15/202115:02 WG1606386 1.00 5.00 1 01/15/202115:02 WG1606386 0.0993 1.00 1 01/15/202115:02 WG1606386 0.118 1.00 1 01/15/202115:02 WG1606386 0.147 1.00 1 01/15/202115:02 WG1606386 0.133 1.00 1 01/15/202115:02 WG1606386 0.180 1.00 1 01/15/202115:02 WG1606386 0.300 1.00 1 01/15/202115:02 WG1606386 0.278 1.00 1 01/15/202115:02 WG1606386 0.230 1.00 1 01/15/202115:02 WG1606386 0.481 1.00 1 01/15/202115:02 WG1606386 PROJECT: SDG: DATE/TIME: 06140180.39 L1306272 01/22/21 00:38 FP1 FTc FSS 4 Cn FC] F FAI FSC PAGE: 33 of 52 ONE LAB. NATIONWIDE. TRIP BLANK SAMPLE RESULTS - 12 Collected date/time: 01/13/21 00:00 L1306272 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.149 1.00 1 01/15/202115:02 WG1606386 1,1,2-Trichloroethane U 0.158 1.00 1 01/15/202115:02 WG1606386 Trichloroethene U 0.190 1.00 1 01/15/202115:02 WG1606386 Trichlorofluoromethane U 0.160 5.00 1 01/15/202115:02 WG1606386 1,2,3-Trichloropropane U 0.237 2.50 1 01/15/202115:02 WG1606386 1,2,4-Trimethylbenzene J 0.322 1.00 1 01/15/202115:02 WG1606386 1,2,3-Trimethyl benzene U 0.104 1.00 1 01/15/202115:02 WG1606386 1,3,5-Trimethyl benzene J 0.104 1.00 1 01/15/202115:02 WG1606386 Vinyl chloride U 0.234 1.00 1 01/15/202115:02 WG1606386 Xylenes, Total J 0.174 3.00 1 01/15/202115:02 WG1606386 (S Toluene-d8 101 80.0-120 01/15/202115:02 WG1606386 (S) 4-Bromof/uorobenzene 103 77.0-126 01/15/202115:02 WG1606386 (S 1,2-Dich/oroethane-d4 97.5 70.0-130 01/15/202115:02 WG1606386 Fp FTc FS Fn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 34 of 52 WG1605904 QUALITY CONTROL SUMMARY Wet Chemistry by Method 2320 B-2011 L1306272-02,03,04,05,07 Method Blank (MB) (MB) R3612998-1 01/15/21 09:54 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Alkalinity U 8450 20000 Sample Narrative: BLANK: Endpoint pH 4.5 L1306189-01 Original Sample (OS) • Duplicate (DUP) (OS) L1306189-01 01/15/2110:21 • (DUP) R3612998-2 01/15/21 10:33 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 168000 165000 1 1.29 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 L1306363-08 Original Sample (OS) • Duplicate (DUP) (OS) L1306363-08 01/15/21 13:10 • (DUP) R3612998-4 01/15/21 13:18 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 446000 447000 1 0.281 20 Sample Narrative: OS: Endpoint pH 4.5 Headspace DUP: Endpoint pH 4.5 Laboratory Control Sample (LCS) (LCS) R3612998-3 01/15/21 11:49 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Alkalinity 100000 98300 98.3 90.0-110 Sample Narrative: LCS: Endpoint pH 4.5 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 35 of 52 WG1607763 Wet Chemistry by Method 450052 D-2011 Method Blank (MB) (MB) R3614526-1 01/20/21 17:22 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Sulfide U 25.0 MB RDL ug/1 50.0 L1306272-02 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1306272-02,03,04,05,07 (OS) L1306272-02 01/20/21 17:23 • (DUP) R3614526-3 01/20/21 17:23 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U U 1 0.000 20 L1306700-09 Original Sample (OS) • Duplicate (DUP) (OS) L1306700-09 01/20/21 17:26 • (DUP) R3614526-6 01/20/21 17:26 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide 40.0 43.0 1 7.23 J 20 Laboratory Control Sample (LCS) (LCS) R3614526-2 01/20/21 17:23 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Sulfide 500 527 105 Rec. Limits LCS Qualifier 85.0-115 L1306303-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1306303-04 01/20/21 17:24 • (MS) R3614526-4 01/20/21 17:24 • (MSD) R3614526-5 01/20/21 17:24 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Sulfide 1000 33.0 801 773 76.8 74.0 1 80.0-120 J6 J6 3.56 ONE LAB. NATIONWIDE. RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 36 of 52 WG1605591 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3613054-1 01/14/21 10:40 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Chloride U 379 Nitrate U 48.0 Sulfate U 594 L1306214-01 Original Sample (OS) • Duplicate (DUP) MB RDL ug/I 1000 100 5000 QUALITY CONTROL SUMMARY L1306272-02,03,04,05,07 (OS) L1306214-01 01/14/21 17:34 • (DUP) R3613054-3 01/14/21 17:50 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Chloride 22700 22800 1 0.226 15 Nitrate 5480 5490 1 0.159 15 Sulfate 32800 32800 1 0.0131 15 L1306303-05 Original Sample (OS) • Duplicate (DUP) (OS) L1306303-05 01/15/21 01:13 • (DUP) R3613054-7 01/15/21 01:30 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/1 % % Chloride U U 1 0.000 15 Nitrate U U 1 0.000 15 Sulfate U U 1 0.000 15 Laboratory Control Sample (LCS) (LCS) R3613054-2 01/14/21 10:56 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Chloride 40000 39800 99.4 Nitrate 8000 8120 102 Sulfate 40000 39300 98.1 Rec. Limits LCS Qualifier 80.0-120 80.0-120 80.0-120 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 37 of 52 WG1605591 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A L1306272-02,03,04,05,07 L13O6214-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. (OS) L1306214-02 01/14/21 18:39 • (MS) R3613054-4 01/14/21 18:55 • (MSD) R3613054-5 01/14/21 19:12 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I Ug/I ug/I ug/I % % % % % Chloride 50000 21000 72500 72800 103 104 1 80.0-120 0.440 15 Nitrate 5000 6280 11700 11700 108 109 1 80.0-120 E E 0.357 15 Sulfate 50000 31500 82000 82400 101 102 1 80.0-120 0.458 15 L1306303-04 Original Sample (OS) • Matrix Spike (MS) (OS) L1306303-04 01/14/21 23:51 • (MS) R3613054-6 01/15/21 00:08 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I Ug/I ug/I % % Chloride 50000 19300 71400 104 1 80.0-120 Nitrate 5000 U 5030 101 1 80.0-120 Sulfate 50000 127000 168000 82.1 1 80.0-120 E FP1 FTC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 38 of 52 WG1605984 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9060A 1-1306272-02,03,04 Method Blank (MB) (MB) R3613478-1 01/16/21 17:14 MB Result MB Qualifier MB MDL MB ROL Analyte ug/I ug/I ug/I TOC (Total Organic Carbon) 242 J 102 1000 L1305482-01 Original Sample (OS) • Duplicate (DUP) (OS) L1305482-01 01/16/21 20:02 • (DUP) R3613478-3 01/16/21 20:19 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC (Total Organic Carbon) 1040 1030 1 1.45 20 L1305482-02 Original Sample (OS) • Duplicate (DUP) (OS) L1305482-02 01/16/21 22:09 • (DUP) R3613478-4 01/16/21 22:27 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC (Total Organic Carbon) 798 698 1 13.4 J 20 Laboratory Control Sample (LCS) (LCS) R3613478-2 01/16/21 18:22 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % TOC (Total Organic Carbon) 75000 75700 101 Rec. Limits LCS Qualifier 85.0-115 L1305610-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1305610-01 01/16/21 22:52 • (MS) R3613478-5 01/16/21 23:22 • (MSD) R3613478-6 01/16/21 23:55 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte ug/I ug/I ug/I ug/I % % TOC (Total Organic Carbon) 50000 11200 61200 62700 100 103 Dilution Rec. Limits MS Qualifier MSD Qualifier RPD 1 80.0-120 2.45 L1306208-08 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. RPD Limits 20 — I Cp FTc FSS 4 — Cn FSr — �GI FAI [Sc (OS) L1306208-08 01/17/21 04:27 • (MS) R3613478-7 01/17/21 04:53 • (MSD) R3613478-8 01/17/21 05:27 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % TOC (Total Organic Carbon) 50000 6510 54600 55900 96.1 98.8 1 80.0-120 2.44 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 39 of 52 WG1605985 Wet Chemistry by Method 9060A Method Blank (MB) (MB) R3613221-1 01/15/21 17:47 MB Result MB Qualifier MB MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 268 J 102 MB ROL ug/I 1000 L1306272-05 Original Sample (OS) • Duplicate (DUP) (OS) L1306272-05 01/15/21 19:28 • (DUP) R3613221-3 01/15/21 19:46 Original Result DUP Result Dilution DUP RPD Analyte ug/I ug/I % TOC (Total Organic Carbon) 1230 907 1 30.5 L1306518-02 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1306272-05,07 DUP Qualifier DUP RPD Limits J P1 20 (OS) L1306518-02 01/15/21 23:38 • (DUP) R3613221-6 01/16/21 00:05 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC (Total Organic Carbon) 11200 10900 1 2.72 20 Laboratory Control Sample (LCS) (LCS) R3613221-2 01/15/21 18:35 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % TOC (Total Organic Carbon) 75000 74900 99.9 Rec. Limits LCS Qualifier 85.0-115 L1306272-07 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1306272-07 01/15/21 20:05 • (MS) R3613221-4 01/15/21 20:33 • (MSD) R3613221-5 01/15/21 21:01 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC (Total Organic Carbon) 50000 1360 51200 48300 99.7 93.9 1 80.0-120 5.89 L1306518-14 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1306518-14 01/16/21 06:58 • (MS) R3613221-7 01/16/21 07:27 • (MSD) R3613221-8 01/16/21 07:57 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC (Total Organic Carbon) 50000 2140 48700 50600 93.1 96.9 1 80.0-120 3.79 ONE LAB. NATIONWIDE. RPD Limits 20 RPD Limits o� 20 ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1306272 01/22/21 00:38 40 of 52 WG1606978 Metals (ICP) by Method 6010D Method Blank (MB) (MB) R3614181-1 01/19/21 21:33 MB Result Analyte ug/I Antimony U Arsenic U Barium 1.37 Beryllium U Cadmium U Chromium U Cobalt U Copper 4.27 Lead U Nickel U Selenium U Silver U Thallium U Vanadium U Zinc U MB Qualifier J J Laboratory Control Sample (LCS) MB MDL ug/I 4.30 4.40 0.736 0.330 0.479 1.40 0.840 3.68 2.99 1.61 7.35 1.54 4.31 4.99 6.52 MB RDL ug/I 10.0 10.0 5.00 2.00 2.00 10.0 10.0 10.0 6.00 10.0 10.0 5.00 10.0 20.0 50.0 QUALITY CONTROL SUMMARY -1306272-01,02,03,04 ONE LAB. NATIONWIDE. (LCS) R3614181-2 01/19/21 21:35 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Antimony 1000 939 93.9 80.0-120 Arsenic 1000 927 92.7 80.0-120 Barium 1000 957 95.7 80.0-120 Beryllium 1000 958 95.8 80.0-120 Cadmium 1000 923 92.3 80.0-120 Chromium 1000 935 93.5 80.0-120 Cobalt 1000 969 96.9 80.0-120 Copper 1000 986 98.6 80.0-120 Lead 1000 952 95.2 80.0-120 Nickel 1000 953 95.3 80.0-120 Selenium 1000 951 95.1 80.0-120 Silver 200 175 87.4 80.0-120 Thallium 1000 969 96.9 80.0-120 Vanadium 1000 955 95.5 80.0-120 Zinc 1000 923 92.3 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 41 of 52 FP1 FTC FSS 4 Cn FSr �GI FAI FSC WG1606978 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D 1-1306272-01,02,03,04 L13O6189-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1306189-01 01/19/21 21:38 • (MS) R3614181-4 01/19/21 21:44 • (MSD) R3614181-5 01/19/21 21:46 Spike Amount Original Result MS Result MSD Result MS Rec. Analyte ug/I ug/I ug/I ug/I % Antimony 1000 U 948 935 94.8 Arsenic 1000 5.36 941 936 93.5 Barium 1000 99.3 1030 1030 93.3 Beryllium 1000 0.390 957 954 95.6 Cadmium 1000 U 925 922 92.5 Chromium 1000 1.59 922 923 92.1 Cobalt 1000 U 968 968 96.8 Copper 1000 5.74 997 985 99.1 Lead 1000 U 958 951 95.8 Nickel 1000 1.67 948 950 94.6 Selenium 1000 U 957 954 95.7 Silver 200 U 177 176 88.3 Thallium 1000 U 966 965 96.6 Vanadium 1000 U 957 957 95.7 Zinc 1000 U 911 911 91.1 ONE LAB. NATIONWIDE. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 93.5 1 75.0-125 1.32 20 93.1 1 75.0-125 0.436 20 92.9 1 75.0-125 0.394 20 95.4 1 75.0-125 0.255 20 92.2 1 75.0-125 0.314 20 92.2 1 75.0-125 0.130 20 96.8 1 75.0-125 0.0238 20 97.9 1 75.0-125 1.15 20 95.1 1 75.0-125 0.708 20 94.8 1 75.0-125 0.235 20 95.4 1 75.0-125 0.371 20 87.8 1 75.0-125 0.568 20 96.5 1 75.0-125 0.127 20 95.7 1 75.0-125 0.0103 20 91.1 1 75.0-125 0.0466 20 FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 42 of 52 WG1606979 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Metals (ICP) by Method 6010D 1-1306272-05,06,07,08,09,10,11 Method Blank (MB) (MB) R3614176-1 01/19/21 15:23 MB Result Analyte ug/I Antimony U Arsenic U Barium U Beryllium U Cadmium U Chromium U Cobalt U Copper U Lead U Nickel U Selenium U Silver U Thallium U Vanadium U Zinc U MB Qualifier Laboratory Control Sample (LCS) MB MDL ug/I 4.30 4.40 0.736 0.330 0.479 1.40 0.840 3.68 2.99 1.61 7.35 1.54 4.31 4.99 6.52 MB RDL ug/I 10.0 10.0 5.00 2.00 2.00 10.0 10.0 10.0 6.00 10.0 10.0 5.00 10.0 20.0 50.0 (LCS) R3614176-2 01/19/21 15:25 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Antimony 1000 949 94.9 80.0-120 Arsenic 1000 937 93.7 80.0-120 Barium 1000 971 97.1 80.0-120 Beryllium 1000 974 97.4 80.0-120 Cadmium 1000 941 94.1 80.0-120 Chromium 1000 948 94.8 80.0-120 Cobalt 1000 973 97.3 80.0-120 Copper 1000 982 98.2 80.0-120 Lead 1000 963 96.3 80.0-120 Nickel 1000 965 96.5 80.0-120 Selenium 1000 956 95.6 80.0-120 Silver 200 172 86.1 80.0-120 Thallium 1000 964 96.4 80.0-120 Vanadium 1000 970 97.0 80.0-120 Zinc 1000 947 94.7 80.0-120 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 43 of 52 FP1 FTC FSS 4 Cn FSr �GI FAI FSC WG1606979 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D 1-1306272-05,06,07,08,09,10,11 L13O6459-03 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1306459-03 01/19/2115:28 • (MS) R3614176-4 01/19/21 15:33 • (MSD) R3614176-5 01/19/2115:36 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte ug/I ug/I ug/I ug/I % % Antimony 1000 U 953 950 95.3 95.0 Arsenic 1000 10.0 943 950 93.3 94.0 Barium 1000 102 1050 1060 95.1 95.7 Beryllium 1000 0.384 972 975 97.2 97.5 Cadmium 1000 U 934 937 93.4 93.7 Chromium 1000 U 944 938 94.4 93.8 Cobalt 1000 3.16 986 984 98.3 98.1 Copper 1000 U 967 982 96.7 98.2 Lead 1000 U 955 957 95.5 95.7 Nickel 1000 2.83 979 975 97.6 97.2 Selenium 1000 U 962 961 96.2 96.1 Silver 200 U 170 169 85.2 84.6 Thallium 1000 U 958 957 95.8 95.7 Vanadium 1000 U 964 970 96.4 97.0 Zinc 1000 U 956 954 95.6 95.4 ONE LAB. NATIONWIDE. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 75.0-125 0.293 20 1 75.0-125 0.750 20 1 75.0-125 0.561 20 1 75.0-125 0.297 20 1 75.0-125 0.296 20 1 75.0-125 0.626 20 1 75.0-125 0.215 20 1 75.0-125 1.47 20 1 75.0-125 0.264 20 1 75.0-125 0.358 20 1 75.0-125 0.168 20 1 75.0-125 0.638 20 1 75.0-125 0.104 20 1 75.0-125 0.598 20 1 75.0-125 0.203 20 FP1 FTC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 44 of 52 WG1606386 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1306272-01,02,03,04,05,06,07,08,09,10,11,12 Method Blank (MB) (MB) R3613075-2 01/15/21 14:10 MB Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U MB Qualifier MB MDL ug/I MB RDL ug/I 11.3 50.0 2.54 50.0 0.671 10.0 0.0941 1.00 0.118 1.00 0.136 1.00 0.129 1.00 0.605 5.00 0.157 1.00 0.125 1.00 0.127 1.00 0.128 1.00 0.116 1.00 0.140 1.00 0.192 5.00 0.111 5.00 0.960 2.50 0.106 1.00 0.114 1.00 0.276 5.00 0.126 1.00 0.122 1.00 0.107 1.00 0.110 1.00 0.120 1.00 0.374 5.00 0.100 1.00 0.0819 1.00 0.188 1.00 0.126 1.00 0.149 1.00 0.149 1.00 0.142 1.00 0.110 1.00 0.111 1.00 0.118 1.00 0.161 1.00 0.105 1.00 0.137 1.00 0.337 1.00 FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 45 of 52 WG1606386 Volatile Organic Compounds (GC/MS) by Method 8260D Method Blank (MB) QUALITY CONTROL SUMMARY L1306272-01,02,03,04,05,06,07,08,09,10,11,12 (MB) R3613075-2 01/15/21 14:10 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Isopropylbenzene U 0.105 1.00 p-Isopropyltoluene U 0.120 1.00 2-Butanone (MEK) U 1.19 10.0 Methylene Chloride U 0.430 5.00 4-Methyl-2-pentanone (MIBK) U 0.478 10.0 Methyl tert-butyl ether U 0.101 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.0993 1.00 Styrene U 0.118 1.00 1,1,1,2-Tetrachloroethane U 0.147 1.00 1,1,2,2-Tetrachloroethane U 0.133 1.00 Tetrachloroethene U 0.300 1.00 Toluene U 0.278 1.00 1,1,2-Trichlorotrifluoroethane U 0.180 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.481 1.00 1,1,1-Trichloroethane U 0.149 1.00 1,1,2-Trichloroethane U 0.158 1.00 Trichloroethene U 0.190 1.00 Trichlorofluoromethane U 0.160 5.00 1,2,3-Trichloropropane U 0.237 2.50 1,2,3-Trimethyl benzene U 0.104 1.00 1,2,4-Trimethylbenzene U 0.322 1.00 1,3,5-Trimethyl benzene U 0.104 1.00 Vinyl chloride U 0.234 1.00 Xylenes, Total U 0.174 3.00 (S) Toluene-d8 99.7 80.0-120 (S) 4-Bromof/uorobenzene 102 77.0-126 (S) 1,2-Dich/oroethone-d4 96.9 70.0-130 Laboratory Control Sample (LCS) (LCS) R3613075-1 01/15/21 13:08 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Acetone 25.0 23.9 95.6 Acrolein 25.0 28.4 114 Acrylonitrile 25.0 26.1 104 Benzene 5.00 4.75 95.0 Rec. Limits LCS Qualifier 19.0-160 10.0-160 55.0-149 70.0-123 ONE LAB. NATIONWIDE. FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.39 L1306272 01/22/21 00:38 46 of 52 WG1606386 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1306272-01,02,03,04,05,06,07,08,09,10,11,12 Laboratory Control Sample (LCS) (LCS) R3613075-1 01/15/21 13:08 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Bromobenzene 5.00 4.80 96.0 73.0-121 Bromodichloromethane 5.00 4.69 93.8 75.0-120 Bromoform 5.00 4.72 94.4 68.0-132 Bromomethane 5.00 4.72 94.4 10.0-160 n-Butylbenzene 5.00 4.79 95.8 73.0-125 sec -Butyl benzene 5.00 4.84 96.8 75.0-125 tert-Butylbenzene 5.00 4.80 96.0 76.0-124 Carbon tetrachloride 5.00 4.62 92.4 68.0-126 Chlorobenzene 5.00 4.94 98.8 80.0-121 Chlorodibromomethane 5.00 4.67 93.4 77.0-125 Chloroethane 5.00 4.53 90.6 47.0-150 Chloroform 5.00 4.76 95.2 73.0-120 Chloromethane 5.00 5.05 101 41.0-142 2-Chlorotoluene 5.00 4.84 96.8 76.0-123 4-Chlorotoluene 5.00 4.88 97.6 75.0-122 1,2-Dibromo-3-Chloropropane 5.00 5.35 107 58.0-134 1,2-Dibromoethane 5.00 4.96 99.2 80.0-122 Dibromomethane 5.00 4.94 98.8 80.0-120 1,2-Dichlorobenzene 5.00 5.01 100 79.0-121 1,3-Dichlorobenzene 5.00 4.78 95.6 79.0-120 1,4-Dichlorobenzene 5.00 4.98 99.6 79.0-120 Dichlorodifluoromethane 5.00 4.54 90.8 51.0-149 1,1-Dichloroethane 5.00 4.80 96.0 70.0-126 1,2-Dichloroethane 5.00 4.87 97.4 70.0-128 1,1-Dichloroethene 5.00 4.68 93.6 71.0-124 cis-1,2-Dichloroethene 5.00 4.79 95.8 73.0-120 trans-1,2-Dichloroethene 5.00 4.72 94.4 73.0-120 1,2-Dichloropropane 5.00 4.79 95.8 77.0-125 1,1-Dichloropropene 5.00 4.73 94.6 74.0-126 1,3-Dichloropropane 5.00 5.24 105 80.0-120 cis-1,3-Dichloropropene 5.00 4.88 97.6 80.0-123 trans-1,3-Dichloropropene 5.00 4.90 98.0 78.0-124 2,2-Dichloropropane 5.00 4.94 98.8 58.0-130 Di -isopropyl ether 5.00 4.95 99.0 58.0-138 Ethylbenzene 5.00 5.08 102 79.0-123 Hexachloro-1,3-butadiene 5.00 5.28 106 54.0-138 Isopropylbenzene 5.00 5.01 100 76.0-127 p-Isopropyltoluene 5.00 4.98 99.6 76.0-125 2-Butanone (MEK) 25.0 24.5 98.0 44.0-160 Methylene Chloride 5.00 4.84 96.8 67.0-120 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.39 SDG: DATE/TIME: PAGE: L1306272 01/22/21 00:38 47 of 52 FP1 FTC FSS [Cn] FSr �GI FAI FSC WG1606386 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) (LCS) R3613075-1 01/15/21 13:08 Spike Amount LCS Result Analyte ug/I ug/I 4-Methyl-2-pentanone (MIBK) 25.0 27.3 Methyl tert-butyl ether 5.00 5.16 Naphthalene 5.00 6.62 n-Propylbenzene 5.00 4.72 Styrene 5.00 5.04 1,1,1,2-Tetrachloroethane 5.00 5.16 1,1,2,2-Tetrachloroethane 5.00 5.14 Tetrachloroethene 5.00 4.91 Toluene 5.00 4.95 1,1,2-Trichlorotrifluoroethane 5.00 4.43 1,2,3-Trichlorobenzene 5.00 6.37 1,2,4-Trichlorobenzene 5.00 5.43 1,1,1-Trichloroethane 5.00 4.63 1,1,2-Trichloroethane 5.00 5.00 Trichloroethene 5.00 4.86 Trichlorofluoromethane 5.00 4.46 1,2,3-Trichloropropane 5.00 5.16 1,2,3-Trimethylbenzene 5.00 5.00 1,2,4-Trimethylbenzene 5.00 4.95 1,3,5-Trimethyl benzene 5.00 4.85 Vinyl chloride 5.00 4.47 Xylenes, Total 15.0 15.1 (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 QUALITY CONTROL SUMMARY L1306272-01,02,03,04,05,06,07,08,09,10,11,12 LCS Rec. Rec. Limits LCS Qualifier 109 68.0-142 103 68.0-125 132 54.0-135 94.4 77.0-124 101 73.0-130 103 75.0-125 103 65.0-130 98.2 72.0-132 99.0 79.0-120 88.6 69.0-132 127 50.0-138 109 57.0-137 92.6 73.0-124 100 80.0-120 97.2 78.0-124 89.2 59.0-147 103 73.0-130 100 77.0-120 99.0 76.0-121 97.0 76.0-122 89.4 67.0-131 101 79.0-123 101 80.0-120 103 77.0-126 99.5 70.0-130 ONE LAB. NATIONWIDE. FP1 FTC FSS [Cn] FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 48 of 52 GLOSSARY OF TERMS ONE LAB. NATIONWIDE. Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL RDL Rec. RPD SDG (S) U Analyte Dilution Limits Original Sample Method Detection Limit. Reported Detection Limit. Recovery. Relative Percent Difference. Sample Delivery Group. FP1 FTC FSS [Cn] FSr Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be F detected in all environmental media. C Not detected at the Reporting Limit (or MDL where applicable). The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the rA laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal I9 for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or SC duplicated within these ranges. The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. E The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial calibration (ICAL). J The identification of the analyte is acceptable; the reported value is an estimate. J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low. P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 49 of 52 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN, 37122 Alabama 40660 Nebraska NE-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TN002 California 2932 New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida _ E87487 North Carolina' _ DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois _ 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhodelsland LA000356 Kentucky' 6 KY90010 South Carolina 84004002 Kentucky z 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas 5 LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TN003 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A21LA A21LA— ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A21LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Pace Analytical National 1313 Point Mallard Parkway SE Suite B Decatur, AL, 35601 Alabama 40160 ANSI National Accreditation Board L2239 Pace Analytical National 660 Bercut Dr. Ste. C Sacramento, CA, 95811 California 2961 Oregon CA300002 Minnesota 006-999-465 Washington C926 North Dakota R-214 Pace Analytical National 6000 South Eastern Avenue Ste 9A Las Vegas, NV, 89119 Nevada NV009412021-1 Pace Analytical National 1606 E. Brazos Street Suite D Victoria, TX, 77901 Texas T104704328-20-18 ' Drinking Water ' Underground Storage Tanks ' Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable FP1 FTc FSS [Cn] FSr RC R, FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.39 L1306272 01/22/21 00:38 50 of 52 Withers & Ravenel Eng. - Standard 115 MacKenan Drive Cary, NC 27511 Report to: Laura Elliott Billing Information- Accounts Payable LPCrhk' 115 MacKenan Drive Cary, NC 27511 LP To: lelii"withersravenel.com 0. O Z Project Descriptiom, City/State , / f Please Circl Q Q Kernersville Landfill Collected: k�l."r < PT MT CT ET a e Client Project # Lab Project # C _ + Phone: 914-469-3340 THRAVS KERNERSVIiI Z E 7- led by (print): L+ l r 5edia dby (signatur : tJv`�'tely Packed an Ice N _ Y Sample ID IV 1 W L-11 VJ - 5 --- �- I Matrix: S - Soil AIR -Air F - filter ;W - Groundwater 8 - Bioassay VW - WasteWater IW • Drinking Water IT - Other _ by: (SigrCature) 1111 w - r ure) Relinquished by : (Signature) 05140180.39 WI s a 0 w ❑ ut tr M Site/Facility ID # P.O. # g ja& � 06140180.24 v E Q en O rV O Q W a A E Rush? (Lab MUST Be Notified) Quote R Same Day Five Day N Z E Q Next Day _ 5 Day (Rad Only) Date Results Needed u N E Two Day 10 Day (Rad Only) No.QJ Z O _ Three Day Z� 2 Q _ of 0 .c U _1 e � ? ry U f4 Comp/Grab Matrix • Depth Date Time 'ntrs O GW 1 3 4 X -- X Gw X X GW I X X GW �� X X r GW X X GW 4 X X �- GW X x GW 4 X X GW 4 X X Ev GW _ l n 4 X --- X :hain of Custody Page 1 ❑f' !2ceAwlyticalo 170651eban Mon Rd 4�r_ ountlubePhone:615.758.5852 Phone,800-767.5859Fax. 615-758-5859 SDG # 146 Acctnum: WITHRAVS Template:T170822 Prelogin: P820603 PM: 873 - Heather ] Wagner PB:-G- Shipped Via FedEX Ground Remarks Sample # (lab only) �-t 0 ,z 11 tWj temarks: 5�1e Receipt c e N pH Temp eac Seal Present/Intact: _ P Y CDC Signed/Accurate; _N Flow Other _v}1 Bottles arrive intact: _,dii TN Correct bottles used: sufficient volume sent: Aonlicable re Samples nedvia: Tracking# ;f r� —UPS _ FedEx —Courier v0A Zero Headspace: Y N FLeSeFva[ion Cartect/Checked: �N RaSB Screen <7.5 mR/hr: Date: Time: Recei by f5ignaturo) Trip Blank Received: / No IA Ia / �eath/MTBR _N v Date: Time: Received by )Signature) T of Bottles R� d: If preservation required by Login: Date/Time Date: Time: Received for lab by`- (Signal /A / iliJ N /f/ f�/ Date: ' f y/!mil Time: d d Hold: ConditiD NCF /C/ Billing Information: Withers & Ravenel Eng. - Standard Accounts Payable Lhk' 115 MacKenan Drive 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 Report to; Email TO: Ielllott@withersravenel.com Laura Elliott Project Description: City/State Please Circles Kernersville Landfill 1 Collected: PT MT CT Client Project it tab project # Phone: 919-469-3340 06140180.39 WITHRAVS-KERNERSVILL Collected by (print); k site/Facility ID # P C p / . + 06140180,24 Colle ed by (signature): Rush? (Lab MUST a Nou i Quote N Cn . ,� Same Day _Five Day I Next Day _ 5 Day (Rad only) bate Results Needed I edlately / —Two Day _ 10 Day (Rad Only) /�� ll ( Packed on ice N Y _ Three Day `! s 1 S I ID Comp/Grab I Matrix • Depth Date Time amp e _GW. GW GW GW - GW GW - GW Matrix: i - Soil AIR - Air F - Filter W - Groundwater B - Bioassay, 'W - wastewater W - Drinking Water T - Other e�ingpished by: (SignaWre) by: Samples rejdrned vla: —UPS _✓ FedEx _Courier Date Time Relinquished by: (Signature) IDate; ng # (Signatu Received by: (Sign Receivedfor'a" 3 3 3 3 3 An I 1 n Chaln of Custody Page --2--of 2� aceAnalytical' NadxW (�rrlr av Twlr.p a mevt,:.- 1206$ tebanon Rd+ Q. Mount lullet, TN 37121 V-4• Z Phone: z d Q Phone 800-767-589) Fax-515.758-6859 �.. __ _ + SDG # 3�� OFF E S 0 d O z Table # p u t a Acctnum: WITHRAVS E ry w Template T170822 rrq z E o Prelogin: P820603 'a; O PM: 873 - Heather J Wagner O (D PB: 16 -b a W 0 N hipped Via: FedEX Ground OSC = co _ Aenarts Sample xpabonlyl W Q tN f^ ? X - X - - -� X X X - X X X X X X X X X X X X tCOC pH Temp Sample Receipt Checkiist COc Seal Present/intact: N --- - — _NP �f�r Signed/Accuratt?: i N Flow Other Bottles arrive intact: 3.1D _N Correct bottles used: _N Sufficient volume sent: N If Aool:cable / VGA Zero Headspace: �,A N Preservation Correct/Checked: _N � Trip Blank Received: Yes / No RAD Screen <0.5 mR/kLr: N HCL / NleoH TOR T oC Bottles Received: if preservation required by Login: Date/Time ¢} Datte• Time: l V /z/r✓ o?:04) Hold: Condition: NCF /C fto NOOur P-o�al?. Your Success Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-1 Site Name Kernersville Closed Landfill Date j V' _rLf Well Depth Xr 37, Depth to Water Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Elliott, M. Maltba Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L °C S/cm) (standard mV NTU Other Parameters Sampled at _]`�� Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time 8260 VOCs HCL 40 ml VOAs glass 14 Days 1 Liter glass 7 Days 6010 Metals Nitric Acid 250 ml plastic 180 Days 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days ii yy P1' f N Al- 1111.E 1 1_r � t�41 11f .. :C'It" -A ri Well Volume Calculation 1 " well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gal Ions/ft- x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.xls Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-2 Site Name Kernersville Closed Landfill Date Well Depth 13 Depth to Water — Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Elliott, M. Maltba Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (frorn TOC) (Gals.) m /L °C S/cm) (standard mV NTU 0. ► .� Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 1 1 Cj 125 ml plastic 1 Liter glass 28 Days 7 days 1 l 1 Liter glass 7 Days vvell volume calculation 1 " well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of SLicce— Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-3S Site Name Kernersville Closed Landfill Date 1 / 1 3121 Well Depth 24 Depth to Water 21 ,P,9 Well Diameter 2" Casing Material PVC Screen Length 10 Well Water Volume Sampling Crew S. Powell, L. Elliott, M. Ma/tba Pump Type bailer Tubing Type Intake set at Weather Conditions 3' a lam, Be, Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC nH nRP Ti irhirli+„ Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Calculation 1 " well [well depth -depth to water] x 0.0408 gallons/ft, x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallonslft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.xis ��'11 �1�'r.]Ci+�'nf Page 1 of 3 Our Peoole. Your Success Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-3D Site Name Kernersville Closed Landfill Date 2 / Well Depth 57 Depth to Water I Well Diameter 2" Casing Material PVC Screen Length 20 Well Water Volume [�5' Sampling'Crew S. Powell. L. Elliott. M. Maltba Pump Type Grundfos Tubing Type poly Intake set at Weather Conditions G4 c"/- Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidit Other Parameters Sampled at ,� Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to l by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days NOTE: DUPLICATE SAMPLE Well Volume Calculation 1"well [well deplhdepthtowater] x 0.0408 gallons/ft. x 3 = 0.124/ft.= 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well (well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.xls Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-4 Site Name Kernersville Closed Landfill Date I — J 3. Well Depth 14 Depth to Waterer C Well Diameter 2" Casing Material PVC Screen h 10 Well Water Volume Sampling Crew S. Powell. L. Elliott. Mafl Pump Type bailer Tubing Type Intake set at Weather Conditions Notes (eg odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L °C) S/cm standard) (mV) (NTU Tj caner rarameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at (Analysis VOCs NO2, SO4, Cl-, Alk, TOC METALS SULFIDE Preservative HCL Nitric Acid �1 Bottle ware 40 ml VOAs glass 1 Liter glass 250 ml plastic 125 ml plastic 1 Liter glass 1 Liter glass Number of Bottles Hold Time 14 Days 7 Days 180 Days 28 Days 7 days 7 Days vveu volume k a[culai]on 1 " well [well depth -depth to water] X 2" well[well depth -depth to water]& .Sty X -'r well [well depth -depth to water] X 0.0408 gallons/ft. x 3 = 0.124/ft. = 0.163 gallons/ft. x 3 = 0.489/ft = 4•1 :a�j 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.xls 40 withersRavent Page 1 of 1 . • Our People, Your Succesz Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-5 Site Name Kernersville Closed Landfill Date J - C3 - 22 _ Well Depth 11 Depth to Water Well Diameter " Casing Material PVC ScrerLerrgtti 5 Well Water Volume Sampling Crew S. Powell, L. Elliott, `. Maltba �i. Pump Type bailer Tubingg7ype Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidit} 24 Hr. from TOC Gals. m /L °C(PS/cm) standard) (mV) NTU Other Parameters Sampled at Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to Iby at Analysis Preservative Bottle ware Number of Bottles Hold Time 8260 VOCs HCL 40 ml VOAs glass 14 Days None 1 Liter glass 7 Days 6010 Metals Nitric Acid 250 ml plastic 180 Days 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days well volume ua]cu]avon 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft._ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = c3 j ep 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.x1s Page 1 of 1 Job Number 6140180.39 Groundwater Sampling Form State ID Well ID MW-6 Site Name Kernersville Closed Landfill Date — !3- 2- Well Depth 20 Depth to Watery Well Diameter 2" Casing Material PVC Screen LenWh 10 Well Water Volume Sampling Crew S. Powell, L. Elliott, g. N1alib Pump Type bailer Tubing Type Intake set at Weather Conditions ; '' sonom Notes (eg. odor or color) ci Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals. m /L) °C S/cm) (standard mV NTU 0 2 CP CP 13 , v �7 h , Other Parameters Sampled at 1330 Parameters taken with YSI PRO PLUS & TURBIDITY METER Samples delivered to by at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days NO2, SO4, Cl-, Alk, TOC None 1 Liter glass 7 Days METALS Nitric Acid 250 ml plastic 180 Days SULFIDE 125 ml plastic 28 Days 1 Liter glass 7 days 1 Liter glass 7 Days Well Volume Calculation 1 " well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. = 0.163 gallons/ft. x 3 = 0.489./ft = 0.653 gallons/ft. x 3 = 1.959/ft = N:\14\14-0180\140180.39-Supp #39 Landfill Services FYE 2021\Enviro\Field Notes\KCLF GW Sampling Form 2020.xls APPENDIX II Historical Summary Tables (2009-2014) TABLE 1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 L 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da l i 851 SW 0.04 1.73 0.30 0.20 785 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) O1-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 J GAPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) O1-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 J 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 1 370 128 41.2 J 98.4 J 113 ND O1-Nov-11 5.0 100 --- 125 413 132 41.7 J 111 72.1 J ND O1-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) OI-Jun-10 0.2 1.0 --- 0.6 J 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 J 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 --- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND O1-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND O1-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND O1-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 J --- 0.099 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 .I 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 1 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L = 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 .I 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 .I 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 1 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 1 ND 0.9 1 --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 1 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 1 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 J GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 .I NC 2L = 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 J 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 -- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 J 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND 10.42) J 0.94 B 0.38 B ND ND 0.30 {ND} J 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1/11/10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1,1-Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 J 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 J 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 J 3.0 J 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 J 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 J 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 J 0.81 J ND ND ND 1,1-Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7} 14.2 59.5 22.1 ND 0.21 {ND} J 07-Nov-12 0.103 5.00 --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 J --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.30 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L= 600 µg/L (1/11/10) 01-Nov-11 0.26 1.0 -- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L = 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 .1 ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 J 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 1 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 020 25.0 0.67 B 0.37 B 0.62 B 0.26 1 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) 01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov-14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 J NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 J 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 1 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 1 Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 1 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- N D ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product I 1 I 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine I 2 I 2 I 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination I 2 0 I 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 1 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 1 0 0 0 1, 1 -Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) 1 Daughter product of chloroform 2 0 0 Based on data collected in November 2014. Total Points Awarded : 23 11 mg/L = miligrams per liter mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering