Loading...
HomeMy WebLinkAbout9202_SouthFeltonsvilleMSW_GWMR_DIN28091_20160425 (2)Closed Feltonsville Landfill Facility Permit No. 92-03 Semi-Annual Sampling Report (April 2016 Sampling Event) Wake County Report Prepared June 2016 5400 Glenwood Ave, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 27, 2016 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: April 2016 Semi-Annual Groundwater Sampling Report Closed Feltonsville Landfill – Wake County Facility Permit No. 92-03 Dear Ms. Drummond: CDM Smith Inc., on behalf of Wake County, is submitting an electronic copy of the April 2016 semi-annual sampling event report. This letter report presents the results of the semi-annual sampling event that was recently completed at the Closed Feltonsville Landfill, and constitutes the first semi-annual sampling event for 2016. The current groundwater monitoring network consists of the following wells: MW-2, -4, -6, -8, -9, -10, -11, -12, -13, -14, -15, -16, -17, -18, -19, -20, -21, -22, -23, -24, -25, -26, -27, -28, and -29 as well as surface water sampling locations SW-1, -2, and -3. Monitoring wells MW-2, -6, -8, -9, -10, -11, -12, -13, -14, -15, -16, -17, -18, -19, -20, -28, and -29 monitor the closed Feltonsville landfill. The remaining wells (MW-4, -21, -22, -23, -24, -25, -26, and -27) monitor the old cells in the back of the landfill property. Field activities, sampling results for all wells and surface water locations, an evaluation of the groundwater corrective action effectiveness, and recommendations are discussed below. Field Activities Groundwater and surface water samples from the Closed Feltonsville Landfill were collected on April 25-27, 2016. Monitoring well and surface water sample locations are shown on Figure 1. Construction details for each monitoring well are summarized in Table 1. Samples were collected from the monitoring wells by use of a peristaltic pump or disposable, laboratory decontaminated bailers. Groundwater elevations were measured at each well prior to sampling using an electronic water level indicator with an accuracy of 0.01 feet and are presented in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are shown on Figure 1. The groundwater elevations and potentiometric contours were also used to estimate groundwater velocities at each well as presented in Table 2. Ms. Jaclynne Drummond June 27, 2016 Page 2 After depth to groundwater was determined, three well volumes of water were removed from each well prior to sampling to provide fresh formation water within the well water column. Each well volume and surface water sample was measured in the field for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential using a YSI-556 multi-parameter water quality meter and a HANNA HI 98703 turbidity meter. Wells that had elevated turbidity were allowed to stabilize prior to sample collection. The water quality parameters at the time of sampling are provided in Table 3. Sampling Results Groundwater and surface water samples were analyzed by ALS Environmental, Inc., located in Jacksonville, Florida, for the North Carolina Appendix I volatile organic compounds (VOCs) plus dichlorodifluoromethane and Appendix I metals plus mercury. Additional samples were collected from select monitoring wells to evaluate natural attenuation and to evaluate the effectiveness of the corrective action. Results of the additional sampling and an evaluation of natural attenuation are discussed in the next section of this report. In accordance with North Carolina Department of Environmental Quality - Solid Waste Section (SWS) guidelines the analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below SWS Limits (SWSLs). All monitoring wells and surface water locations for the closed Feltonsville Landfill had detections of analytes above the MDL with a majority of the detections below SWSLs. These detections were qualified as estimated or “J” flags. “B” flags, which indicate an analyte was detected in the method blank, were also reported. The following list indicates the analytes detected above the MDL at each sampling location. No “J” flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Quality Standard, Groundwater Protection Standard, or the 15A NCAC 02B Surface Water Quality Standard for Class C Waters. A complete summary of all detected and estimated concentrations for the March 2011 through the April 2016 sampling events, as well as historical detections of herbicides, pesticides, and polychlorinated biphenyls, is provided in Table 4. Laboratory data reports are provided in Appendix A. MW-2 (Background) Metals: Barium, Zinc Volatile Organic Compounds: None Detected MW-4 Metals: None Detected Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond June 27, 2016 Page 3 MW-6 Metals: Barium, Zinc Volatile Organic Compounds: 1,1-Dichloroethane MW-8 Inorganics: Barium, Chromium, Cobalt, Nickel, Sodium, Total Dissolved Solids Volatile Organic Compounds: None Detected MW-9 Inorganics: Barium, Cobalt, Copper, Sodium, Total Dissolved Solids Volatile Organic Compounds: Chloroethane, 1,1-Dichloroethane MW-10 Inorganics: Arsenic, Barium, Cobalt, Sodium, Total Dissolved Solids Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, Chloroethane, 1,1-Dichloroethane, Vinyl Chloride MW-11 Metals: Barium Volatile Organic Compounds: None Detected MW-12 Metals: Barium Volatile Organic Compounds: None Detected MW-13 Metals: Barium, Copper, Mercury, Zinc Volatile Organic Compounds: Benzene, Chlorobenzene, 1,4-Dichlorobenzene MW-14 Metals: Barium Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene MW-15 Metals: Barium, Mercury Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene MW-16 Metals: Arsenic, Barium Volatile Organic Compounds: Benzene, 1,1-Dichloroethane, Trichloroethene Ms. Jaclynne Drummond June 27, 2016 Page 4 MW-17 Metals: Arsenic, Barium Volatile Organic Compounds: 1,1-Dichloroethane MW-18 Metals: None Detected Volatile Organic Compounds: None Detected MW-19 Inorganics: Barium, Copper, Sodium, Total Dissolved Solids Volatile Organic Compounds: None Detected MW-20 Metals: Barium, Zinc Volatile Organic Compounds: None Detected MW-21 Metals: None Detected Volatile Organic Compounds: None Detected MW-22 Metals: Barium Volatile Organic Compounds: None Detected MW-23 Metals: Barium, Zinc Volatile Organic Compounds: None Detected MW-24 Metals: Barium, Zinc Volatile Organic Compounds: None Detected MW-25 Metals: Barium Volatile Organic Compounds: Benzene MW-26 Metals: Barium, Beryllium, Cobalt, Zinc Volatile Organic Compounds: Benzene Ms. Jaclynne Drummond June 27, 2016 Page 5 MW-27 Metals: Arsenic, Barium, Cobalt, Zinc Volatile Organic Compounds: 1,1-Dichloroethane MW-28 Metals: Barium Volatile Organic Compounds: None Detected MW-29 Inorganics: Barium, Beryllium, Chromium, Cobalt, Copper, Lead, Sodium, Vanadium, Zinc, Total Dissolved Solids Volatile Organic Compounds: None Detected SW-1 Metals: None Detected Volatile Organic Compounds: None Detected SW-2 Metals: Dry Volatile Organic Compounds: Dry SW-3 Metals: None Detected Volatile Organic Compounds: None Detected Equipment Blank Metals: None Detected Volatile Organic Compounds: None Detected Trip Blank Metals: Not analyzed Volatile Organic Compounds: None Detected “J” flags were not included in the previous list, but several sampling locations had “J” flag detections that exceeded the standards. The “J” flag constituents above the standards along with their location are listed below: Cobalt: MW-6, -11, -12, -13, -14, -15, -16, -17, -18, -19, -20, -21, -22, -23, and -24 Vanadium: MW-20 1,2-Dichloroethane MW-10 Ms. Jaclynne Drummond June 27, 2016 Page 6 Vinyl Chloride MW-9, and -16 The duplicate sample, labeled DUP, was collected from MW-19 and had similar concentrations to the MW-19 sample. The equipment blank had “J” flag detections of copper and acetone below the NC 2L Standard. No VOCs were detected in the trip blank above the detection limit. Table 5 presents a summary of all parameters detected during the April 2016 sampling event that exceeded the NC 2L or Groundwater Protection Standards. Monitored Natural Attenuation Sampling Additional groundwater samples were collected from the background well, MW-2, and downgradient monitoring wells MW-8, -9, -10, -12, -13, and -14. The samples were analyzed for alkalinity, biochemical oxygen demand, chemical oxygen demand, carbon dioxide, chloride, dissolved hydrogen, methane, ethane, ethene, volatile fatty acids (i.e. acetic, butyric, lactic, propionic, and pyruvic), nitrate, sulfate, sulfide, and total organic carbon. Ferrous iron was also analyzed using a HACH test field kit due to the short hold time (i.e. 15 minutes). These additional samples were collected to monitor for natural attenuation as part of the approved corrective action program as required by SWS guidelines. Additional samples were also collected from wells MW-19 and -29, which are located down-gradient of the injection area, in order to monitor the effectiveness of the injection. Sampling results are provided in Table 6 and trend figures of total detected VOCs for select wells are presented on Figures 2-10. Corrective Action via In situ Bioremediation Injection In accordance with the Corrective Action Plan that was approved by the SWS in a letter dated December 1, 2011, two in situ bioremediation injections have been completed. Phase I consisted of injecting sodium lactate into 5 injection wells upgradient of monitoring wells MW-8, -9, and -10 on June 18-21, 2012. A total of 1,268 gallons of a 10% sodium lactate solution were injected resulting in each well receiving approximately 254 gallons of the sodium lactate solution. Phase I post-injection samples were collected 1, 2, and 5 months after injection. During each sampling event, samples from MW-8, -9, -10, -19, and -29 were analyzed for the following field measurements: pH, temperature, oxidation-reduction potential, dissolved oxygen, conductivity, turbidity, nitrate, sulfate, ferrous iron, carbon dioxide, and alkalinity along with laboratory analyses of chlorides, chemical oxygen demand, VOCs, dissolved gases (i.e. methane, ethane, and ethene), sodium, and total dissolved solids. Volatile fatty acids were also collected during the 1 month post-injection sampling event. Additionally, samples were collected from MW-8, -9, and -10 and analyzed for bacterial population size and functional gene presence during the baseline and 5 month post-injection sampling events. Analytical results for each sampling event are summarized in Tables 4 and 6. Analytical results post-sodium lactate injection for MW-8, -9, and -10 indicated that bioremediation was occurring with no VOCs detected above NC 2L standards in MW-8 or -10, with the exception of 1,1- Ms. Jaclynne Drummond June 27, 2016 Page 7 dichloroethane detected in samples collected from MW-10 in July 2012. MW-9 had detections of 1,1- dichloroethane, tetrachloroethene, trichloroethene, and vinyl chloride above NC 2L standards, but contaminant concentrations were decreasing. DNA analyses revealed healthy populations of bacteria (Dehalococcoides sp) in MW-9 and -10 that continued to reduce contaminant concentrations. Bacterial populations in MW-8 decreased as a result of little to no VOCs being detected during the post-injection sampling. The Phase I injection of sodium lactate successfully caused degradation of trichloroethene and tetrachloroethene to daughter products using enhanced anaerobic bioremediation in the injection area. Although the Phase I injection reduced contaminant concentrations, a second injection was needed to supply a longer lasting source of electron donors. Biodegradation can be sustained for as long as sufficient concentrations of substrate remain in the groundwater. For this reason, emulsified vegetable oil was utilized in the Phase 2 injection as it is a slow-release compound, and therefore should release organic carbon into the groundwater for three to five years, depending on site conditions. During the Phase 2 injection, a 10% emulsified vegetable oil solution was injected into the injection wells on March 25-27, 2013. Injection at each well consisted of approximately 220 gallons of water containing approximately 22 gallons of the emulsified vegetable oil product. The emulsified vegetable oil product consisted of 60% emulsified vegetable oil and 4% sodium lactate by weight, which resulted in a total injection volume of 1,100 gallons of water and 110 gallons of emulsified vegetable oil product. Post-injection samples were collected 1, 4, 7, 10, and 12 months after injection. The April 2014 monitoring event concluded the post-injection monitoring. Analyses for each sampling event were similar to the Phase I events except that a DNA analyses to determine bacterial population size and functional gene presence was only done during the April 2014 sampling event. No VOCs have been detected above the standards in MW-8 since the November 2011 semi-annual sampling event. 1,1-Dichloroethane and an estimated concentration of vinyl chloride were detected above their respective NC 2L Standards in MW-9 during the April 2016 sampling event. The concentration of 1,1,-dichloroethane in MW-9 shows a decreasing trend. MW-10 had concentrations of benzene, 1,1-dichloroethane, vinyl chloride, and an estimated concentration of 1,2-dichloroethane above their respective NC 2L Standards. Benzene and 1,1-dichloroethane show a decreasing trend. No VOCs were detected in samples collected from bedrock monitoring well MW-19 during the April 2016 sampling event with the exception of an estimated concentration of o-xylene below the NC 2L Standard. Historically, VOCs have never been detected above the standards in monitoring well MW-19. MW-29, located at the compliance boundary, has not had any chlorinated ethenes detected above NC 2L Standards since May 2013. No VOCs were detected in samples collected from MW-29 during the April 2016 sampling event with the exception of an estimated concentration of 1,1-dichloroethane below the Ms. Jaclynne Drummond June 27, 2016 Page 8 NC 2L Standard. Concentrations of 1,1-dichloroethane have decreased following the injection events. 1,1-Dichloroethane had been detected below the NC 2L Standard since the January 2014 post-injection sampling event with the exception of the October 2014 semi-annual sampling event (7.2 parts per billion (ppb)) when it was detected slightly above the NC 2L Standard (6 ppb). Dechlorination of chlorinated ethenes from tetrachloroethene to ethene is ongoing. The geochemical data indicates favorable conditions for reductive dechlorination in samples collected from MW-9 and -10 during the April 2016 monitoring event. Healthy DHC populations are present based on the DNA analyses completed in April 2014. Additionally, as expected, concentrations of vinyl chloride have increased in monitoring wells MW-9 and -10. The concentration of ethane has increased in MW-9 and fluctuated in MW-10 following the injection events. Subsequent monitoring events will be evaluated to identify any trends. Recommendations Wake County will continue with the semi-annual assessment monitoring program. All wells will continue to be sampled for Appendix I VOCs plus dichlorodifluoromethane and Appendix I metals plus mercury. Samples collected from MW-2, -8, -9, -10, -12, -13, and -14 will also be analyzed for natural attenuation parameters. If you have any questions or require further explanation, do not hesitate to call me at 919-325-3500. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Elliot Cornell, WCSWM Facility Permit Number Monitoring Well Code Installation Date Latitude Longitude Geology of Screened Interval Total Depth (feet BTOC) Screened Interval (feet BTOC) Seal Interval (feet BTOC) Top of Casing Elevation (feet AMSL) Depth to Groundwater (feet BTOC) Groundwater Elevation (feet AMSL) Monitoring Well Diameter (inches) 92-03 MW-2 1994 35.68420 78.84301 Bedrock 60.0 50.0 - 60.0 48.0 - 50.0 366.03 28.54 337.49 2.0 92-03 MW-4 1994 35.68161 78.86000 Regolith 36.0 26.0 - 36.0 24.0 - 26.0 310.80 20.40 290.40 2.0 92-03 MW-6 1994 35.68380 78.84769 Bedrock 33.5 23.5 - 33.5 21.5 - 23.5 319.71 17.56 302.15 2.0 92-03 MW-8 1994 35.68394 78.85367 Regolith 45.7 35.7 - 45.7 33.7 - 35.7 287.72 11.56 276.16 2.0 92-03 MW-9 1994 35.68402 78.85362 Bedrock 37.2 27.2 - 37.2 25.2 - 27.2 285.83 9.45 276.38 2.0 92-03 MW-10 1994 35.68406 78.85358 Regolith 22.5 12.5 - 22.5 10.5 - 12.5 287.10 10.59 276.51 2.0 92-03 MW-11 1994 35.68314 78.85380 Regolith 23.8 13.8 - 23.8 10.8 - 13.8 282.80 6.37 276.43 2.0 92-03 MW-12 1994 35.68018 78.84787 Regolith 21.8 11.8 - 21.8 9.8 - 11.8 306.52 7.56 298.96 2.0 92-03 MW-13 1994 35.68013 78.84987 Regolith 23.3 13.3 - 23.3 11.3 - 13.3 305.93 13.58 292.35 2.0 92-03 MW-14 1994 35.68010 78.84994 Bedrock 39.8 29.8 - 39.8 27.8 - 29.8 305.29 12.97 292.32 2.0 92-03 MW-15 1994 35.68012 78.84990 Saprolite 41.0 31.0 - 41.0 29.0 - 31.0 305.64 13.36 292.28 2.0 92-03 MW-16 1994 35.68070 78.85300 Regolith 45.0 35.0 - 45.0 33.0 - 35.0 315.30 28.40 286.90 2.0 92-03 MW-17 1994 35.68141 78.85434 Regolith 28.5 18.5 - 28.5 16.5 - 18.5 291.58 14.42 277.16 2.0 92-03 MW-18 1994 35.68389 78.85087 Regolith 26.5 16.5 - 26.5 14.5 - 16.5 300.82 12.56 288.26 2.0 92-03 MW-19 6/10/1999 35.68405 78.85366 Bedrock 68.0 58.0 - 68.0 56.0 - 58.0 286.17 9.84 276.33 2.0 92-03 MW-20 6/10/1999 35.68456 78.85302 Regolith 28.5 13.5 - 28.5 11.5 - 13.5 285.80 8.55 277.25 2.0 92-03 MW-21 6/10/1999 35.68229 78.86262 Regolith 31.0 16.0 - 31.0 14.0 - 16.0 339.25 16.79 322.46 2.0 92-03 MW-22 6/10/1999 35.67984 78.86062 Regolith 28.5 13.5 - 28.5 11.5 - 13.5 299.39 11.75 287.64 2.0 92-03 MW-23 6/10/1999 35.68029 78.85884 Regolith 27.7 12.7 - 27.7 10.7 - 12.7 286.83 12.30 274.53 2.0 92-03 MW-24 6/10/1999 35.68179 78.85827 Regolith 31.0 16.0 - 31.0 14.0 - 16.0 295.04 8.45 286.59 2.0 92-03 MW-25 6/10/1999 35.68267 78.85769 Regolith 30.6 15.6 - 30.6 13.6 - 15.6 295.87 11.48 284.39 2.0 92-03 MW-26 6/9/1999 35.67795 78.85668 Regolith 20.0 7.0 - 20.0 5.0 - 7.0 282.95 5.70 277.25 2.0 92-03 MW-27 6/9/1999 35.67585 78.85661 Regolith 31.5 16.5 - 31.5 14.5 - 16.5 297.31 18.01 279.30 2.0 92-03 MW-28 6/10/1999 35.68378 78.84759 Bedrock 71.0 61.0 - 71.0 59.0 - 61.0 319.70 20.36 299.34 2.0 92-03 MW-29 2/21/2011 35.68420 78.85379 Regolith 25.3 15.3 - 25.3 13.3 - 15.3 284.76 8.65 276.11 2.0 Notes: 1. Groundwater elevations were measured on April 25, 2016. 2. AMSL - Above Mean Sea Level 3. BTOC - Below Top of Casing 4. Latitude and longitude are in decimal degrees (World Geodetic System 1983). Feltonsville Landfill - Wake County April 2016 Semi-Annual Sampling Event Monitoring Well Construction Summary Table 1 Page 1 of 1 June 2016 Table 2 Summary of Calculated Groundwater Flow Velocities April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County MW-2 0.42 0.019 0.13 6.00E-02 MW-6 0.42 0.025 0.05 2.08E-01 MW-8 2.63 0.019 0.13 3.85E-01 MW-9 0.33 0.019 0.05 1.25E-01 MW-10 0.52 0.019 0.13 7.67E-02 MW-11 0.42 0.019 0.13 6.05E-02 MW-12 0.42 0.019 0.25 3.14E-02 MW-13 1.24 0.015 0.05 3.60E-01 MW-14 0.26 0.018 0.05 9.21E-02 MW-15 2.00 0.018 0.18 1.98E-01 MW-16 0.42 0.016 0.05 1.31E-01 MW-17 0.42 0.017 0.13 5.49E-02 MW-18 6.43 0.021 0.08 1.66E+00 MW-19 1.84 0.019 0.13 2.69E-01 Notes: 1. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 2. The gradient and linear velocity values shown for MW-2 are based on the average of all the listed wells. Monitoring Well Code Hydraulic Conductivity (feet/day) Gradient Effective Porosity Average Linear Velocity (feet/day) Page 1 of 1 June 2016 pH Conductivity Temperature Turbidity DO ORP (S.U.)(mS/cm)(degrees Celsius)(NTUs)(mg/L)(mV) 92-03 MW-2 7.31 3,122 16.7 16 7.50 93.0 92-03 MW-4 7.29 290 16.3 88 7.93 67.4 92-03 MW-6 6.84 1,568 17.3 92 4.24 -17.7 92-03 MW-8 7.13 416 18.4 3 1.45 -40.8 92-03 MW-9 6.86 695 17.8 91 0.96 -47.4 92-03 MW-10 6.20 1,445 15.0 13 2.07 -36.5 92-03 MW-11 6.56 406 14.3 5 1.80 -38.8 92-03 MW-12 7.02 2,007 15.1 19 6.36 -44.0 92-03 MW-13 5.76 471 15.2 95 4.24 107.5 92-03 MW-14 6.27 733 17.0 9 2.97 43.6 92-03 MW-15 6.22 805 17.0 37 1.61 80.3 92-03 MW-16 6.33 427 18.8 17 2.02 12.6 92-03 MW-17 6.42 583 15.9 48 6.65 32.2 92-03 MW-18 7.15 1,557 16.8 59 4.57 -5.4 92-03 MW-19 7.69 345 18.2 4 1.94 21.2 92-03 MW-20 8.43 358 6.3 95 3.83 37.2 92-03 MW-21 6.69 162 16.3 162 8.11 99.6 92-03 MW-22 6.60 653 15.4 92 3.55 37.5 92-03 MW-23 7.12 2,171 15.1 13 3.94 -75.9 92-03 MW-24 6.34 2,210 16.4 10 2.93 -8.3 92-03 MW-25 6.83 1,937 15.5 22 6.42 60.1 92-03 MW-26 4.44 867 14.7 46 5.45 208.8 92-03 MW-27 6.62 825 17.3 32 4.49 -46.1 92-03 MW-28 7.11 1,036 20.5 41 6.87 47.0 92-03 MW-29 6.07 150 14.4 86 1.94 -45.9 92-03 SW-1 7.37 149 19.3 22 7.15 -22.5 92-03 SW-2 92-03 SW-3 6.28 180 18.7 27 7.11 -24.3 Notes: 1. Water quality measurements were collected from April 25-27, 2016. 2. SW - Surface Water 3. ORP - Oxidation Reduction Potential (mV - millivolt) 4. DO - Dissolved Oxygen (mg/L - milligrams per liter) 5. S.U. - Standard Units 6. NTUs - Nephelometric Turbidity Units 7. mS/cm - Microsiemens per centimeter 8. Turbidity measurements recorded at the time of sample collection. DRY Surface Water Sample Location Table 3 Water Quality Parameters Feltonsville Landfill - Wake County April 2016 Semi-Annual Sampling Event Facility Permit Number Monitoring Well Code Water Quality Measurements Page 1 of 1 June 2016 Table 4a Detected Groundwater Constituents - Inorganics April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Me r c u r y Ni c k e l Se l e n i u m Sil v e r So d i u m Th a l l i u m Va n a d i u m Zin c To t a l D i s s o l v e d S o l i d s 1*10 700 4*2 10 1*1,000 15 1 100 20 20 20,000*0.2*0.3*1,000 500,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 NE 5.5 25 10 NE MW-2 31-Mar-11 0.315J 169 10.7 4.55J 6.56JB 25.2 6.35J 9.35J 20.3J 34.9 MW-2 8-Nov-11 522 24.4 6.29J 16.9B 0.215 12.7J 16.0J 36.9 MW-2 4-Apr-12 159 18.3 7.27J MW-2 6-Nov-12 0.563J 401 2.39J 2.24J 1.97J 2.43J 8.83J MW-2 15-May-13 80J 0.2J 0.07J 0.5J 4J 34 MW-2 6-Nov-13 210 1.0J 0.2J 2J 0.4J 1J 5JB MW-2 9-Apr-14 150 0.3J 0.10J 2J 0.2J 0.04J 0.7J 2J 14J 5JB MW-2 28-Oct-14 2J 360 0.1J 0.2J 2J 0.02J 2J 2J 0.07J 4JB MW-2 5-May-15 0.7J 190 0.1J 1J 0.04J 1J 3JB MW-2 19-Nov-15 0.5J 650 2J 1J 4J 6J 0.06J 3J 2J 10 MW-2 26-Apr-16 250 20 MW-4 31-Mar-11 44.8J 1.98J 3.36JB 2.33J 2.10J 6.02J 20.9 MW-4 8-Nov-11 45.6J 2.27J 4.15JB 6.85J 17.8 MW-4 4-Apr-12 0.91J 38.8J 3.84J MW-4 6-Nov-12 1.10J 57.4J 2.85J 1.62J 2.58J 2.87J 3.48J 7.65J 11.1 MW-4 15-May-13 2J 50J 0.05J 2J 1.0J 2J 2J 2J 5JB MW-4 6-Nov-13 4J 90J 0.1J 6J 4J 11 4J 9J 12J 27 MW-4 9-Apr-14 2J 40J 1J 0.3J 1.0J 0.5J 0.02J 1.0J 6J 7JB MW-4 28-Oct-14 2J 70J 0.08J 4JB 2J 4J 3J 5J 0.09J 5J 16B MW-4 5-May-15 4J 80J 0.1J 0.1J 5J 2J 8J 4J 4J 5J 13B MW-4 19-Nov-15 2J 40J 0.1J 2J 0.6J 1J 1J 0.11J 2J 6J MW-4 26-Apr-16 50J 1J 0.4J 1J MW-6 1-Apr-11 277 10.3 4.70J 6.89JB 1.95J 6.29J 1.45J 22.3J 30.6 MW-6 9-Nov-11 225 5.93J 2.17J 14.9J 6.69J MW-6 4-Apr-12 0.254J 248 6.79J 1.49J 2.52J 2.18J 15.8J 7.07J MW-6 6-Nov-12 509 6.42J 1.16J 1.91J 2.60J 16.2J 18.4 MW-6 15-May-13 0.6J 280 0.8J 7J 1J 27J 2J 9JB MW-6 6-Nov-13 450 0.3J 0.2J 2J 1J 0.02J 19J 2J 6JB MW-6 9-Apr-14 1J 470 0.8J 0.3J 10 2J 0.04J 31J 3J 10J 27B MW-6 28-Oct-14 0.9J 530 0.4J 6J 2J 0.03J 26J 2J 9JB MW-6 5-May-15 1J 570 0.5J 0.4J 5J 3J 0.06J 25J 2J 13JB MW-6 18-Nov-15 0.5J 660 0.2J 2J 3J 4J 0.7J 20J 1J 11 MW-6 dup 18-Nov-15 1J 620 0.06J 0.2J 3J 3J 4J 0.8J 0.03J 20J 1J 12 MW-6 27-Apr-16 0.3J 1J 610 0.07J 0.3J 2JB 3JB 4J 0.8J 21J 1J 13 MW-8 30-Mar-11 0.749J 68.1J 0.497J 47.4 2.24J 9.89J 3.48J 11.2J 14.3J 14.1 MW-8 7-Nov-11 4.28J 41.3J 32.9 1.49J 2.83JB 1.99J 11.9J MW-8 4-Apr-12 0.574J 40.4J 31.4 2.35J 3.20J 10.0J MW-8 4-Jun-12 --------------------------8,290 ------200,000 MW-8 19-Jul-12 --------------------------10,100 ------240,000 MW-8 16-Aug-12 --------------------------8,600 ------170,000 MW-8 6-Nov-12 104 18.7 5.60J 13.2 52.3 10,000 5.13J 5.20J 110,000 MW-8 15-May-13 0.9J 3J 110 0.2J 0.4J 23 6J 115 0.5J 24J 9,520 12B 212,000 MW-8 31-Jul-13 --------------------------9,150 ------248,000 MW-8 6-Nov-13 0.3J 150 6J 2J 6J 24J 7,900 2JB 189,000 MW-8 16-Jan-14 --------------------------8,280 ------212,000 MW-8 10-Apr-14 0.6J 0.5J 130 0.3J 7J 3J 8J 0.2J 0.05J 34J 8,830 8J 14B 212,000 MW-8 29-Oct-14 0.5J 160 0.2J 11 4J 5J 0.3J 53 7,800 10B 181,000 MW-8 7-May-15 3.1J 0.6J 140 0.2J 9J 2J 9J 0.3J 0.02J 29J 7,900 5J 196,000 MW-8 19-Nov-15 1.3J 0.7J 190 0.6J 6J 7J 6J 0.3J 102 1J 15J 4J 178,000 MW-8 26-Apr-16 1J 200 20 10 9J 0.7J 0.03J 67 9,150 5J 196,000 MW-9 30-Mar-11 176 0.204J 8.41J 3.19J 9.17JB 3.09J 10.3J 5.39J 14.4 MW-9 7-Nov-11 147 0.136J 3.18J 1.28J 2.82JB 3.16J 35.9 MW-9 4-Apr-12 191 0.355J 10.1 3.92J 12 2.58J 11.6J 7.48J 20.2 MW-9 dup 4-Apr-12 180 0.293J 8.31J 3.38J 9.98J 10.2J 6.06J 31.1 MW-9 4-Jun-12 --------------------------11,400 ------280,000 MW-9 19-Jul-12 --------------------------38,600 ------1,100,000 MW-9 16-Aug-12 --------------------------28,500 ------650,000 MW-9 6-Nov-12 0.446J 2,110 0.546J 16.2 23.8 125 8.16J 144 4.15J 45,100 17.4J 36 970,000 MW-9 15-May-13 6J 1,320 0.2J 5J 25 57 4J 0.08J 65 2J 30,100 4J 15B 473,000 MW-9 dup 15-May-13 0.2J 7J 1,260 0.2J 3J 24 57 4J 0.07J 63 2J --2J 12B -- MW-9 31-Jul-13 --------------------------30,800 ------463,000 MW-9 6-Nov-13 8J 1,200 0.4J 0.1J 7J 21 65 7J 0.08J 47J 3J 23,600 0.1J 19J 27 431,000 MW-9 16-Jan-14 --------------------------21,800 ------427,000 MW-9 10-Apr-14 8J 1,060 0.1J 0.1J 1J 19 39 4J 0.07J 31J 2J 21,300 10J 11B 417,000 MW-9 dup 10-Apr-14 0.3J 10 1,050 0.1J 0.3J 1J 19 50 4J 0.06J 32J 2J --12J 17B -- MW-9 29-Oct-14 6J 820 0.1J 0.2J 2JB 14 29 5J 0.1J 32J 21,300 13B 375,000 MW-9 dup 29-Oct-14 6J 820 0.1J 0.2J 1JB 14 30 5J 0.04J 32J --10B -- MW-9 7-May-15 7J 1,000 0.3J 4J 16 29 8J 0.04J 33J 19,800 4J 15 389,000 MW-9 20-Nov-15 6J 810 0.06J 0.8J 12 18 7J 0.10J 25J 2J 3J 383,000 MW-9 27-Apr-16 6J 930 0.1J 0.4JB 13 11 6J 24J 1J 21,200 4J 403,000 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Page 1 of 21 June 2016 Table 4a Detected Groundwater Constituents - Inorganics April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Me r c u r y Ni c k e l Se l e n i u m Sil v e r So d i u m Th a l l i u m Va n a d i u m Zin c To t a l D i s s o l v e d S o l i d s 1*10 700 4*2 10 1*1,000 15 1 100 20 20 20,000*0.2*0.3*1,000 500,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 NE 5.5 25 10 NE North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-10 30-Mar-11 14.4 534 6.73J 51.6 2.63JB 2.93J 41.6J 2.01J MW-10 7-Nov-11 8.75J 476 0.141J 4.52J 11.4 1.64J 3.72JB 18.7J 3.30J 9.39J MW-10 4-Apr-12 10.2 596 4.97J 58.8 47.4J MW-10 4-Jun-12 --------------------------58,100 ------630,000 MW-10 19-Jul-12 --------------------------1,680,000 ------11,000,000 MW-10 16-Aug-12 --------------------------1,900,000 ------11,000,000 MW-10 6-Nov-12 34.2 2,050 2.94 67.6 42.5 152 34.7 0.349 107 7.64J 595,000 111 195 2,800,000 MW-10 dup 6-Nov-12 28.5 2,060 3.31 76.1 46.1 190 42.8 0.306 113 8.23J --127 231 -- MW-10 15-May-13 32 1,140 2.9 41 46 154 28 0.19J 77 2J 253,000 0.3J 84 269 1,100,000 MW-10 31-Jul-13 --------------------------121,000 ------680,000 MW-10 6-Nov-13 21 880 0.8J 0.1J 10 31 45 8J 0.06J 39J 3J 128,000 0.08J 31 55 794,000 MW-10 dup 6-Nov-13 22 1,040 1.6 0.4J 20 37 75 16 0.10J 50J 4J --0.1J 57 114 -- MW-10 16-Jan-14 --------------------------69,600 ------460,000 MW-10 10-Apr-14 16 310 0.08J 1J 14 2J 0.4J 0.07J 14J 50,400 7J 7JB 393,000 MW-10 26-Oct-14 13 720 0.2J 3J 21 12 3J 0.1J 23J 2J 86,300 24 670,000 MW-10 7-May-15 23 700 0.1J 2J 29 3J 0.6J 0.02J 36J 3J 77,800 6J 756,000 MW-10 20-Nov-15 25 730 0.1J 3J 21 7J 0.9J 0.05J 32J 3J 6J 680,000 MW-10 27-Apr-16 0.3J 34 850 0.1J 0.5JB 24 2J 0.2J 30J 2J 93,400 2J 832,000 MW-11 31-Mar-11 75.5J 9.29J MW-11 8-Nov-11 83.8J 1.08J 1.64J 14.7 MW-11 4-Apr-12 84.3J MW-11 6-Nov-12 93.2J 2.52J 1.55J 13.2 MW-11 15-May-13 0.6J 70J 0.5J 2J 0.8J 2J 3JB MW-11 6-Nov-13 0.8J 70J 1J 0.9J 2J 4JB MW-11 10-Apr-14 1J 70J 0.7J 0.5J 1J 0.3J 0.04J 2J 6J 8JB MW-11 29-Oct-14 0.6J 70J 0.4JB 0.9J 1J 0.2J 2J 5J MW-11 6-May-15 2J 110 0.05J 1J 8J 2J 0.5J 0.02J 4J 7JB MW-11 20-Nov-15 1J 70J 0.05J 0.2J 0.5J 5J 2J 0.2J 3J 1J 13 MW-11 27-Apr-16 1J 110 9J 0.8J 3J 4J MW-12 31-Mar-11 276 1.66JB 2.46J 9.68J 1.42J 10.1 MW-12 8-Nov-11 3.93J 115 3.02JB 6.15J MW-12 3-Apr-12 182 1.28J MW-12 5-Nov-12 123 MW-12 15-May-13 2J 170 0.9J 0.1J 0.3J 2J MW-12 6-Nov-13 4J 140 0.5J 0.2J 2J 1J MW-12 10-Apr-14 2J 230 0.9J 0.2J 0.6J 0.04J 2J 5J 4JB MW-12 28-Oct-14 2J 130 0.9JB 0.1J 0.5J 1J 2JB MW-12 6-May-15 2J 290 0.4J 0.1J 0.5J 0.05J 3J 3JB MW-12 20-Nov-15 6J 200 0.3J 0.6J 1J 2J MW-12 27-Apr-16 5J 330 0.08J 3J 1J 4J 1J 5J 1J 6J MW-13 31-Mar-11 576 2.30J 11.3 3.33JB 0.273 44.9J 3.48J 60.9 MW-13 8-Nov-11 4.70J 906 0.130J 1.21 3.08J 16.8 5.29J 53.2 7.77J 243 MW-13 3-Apr-12 4.41J 960 2.48J 17.0 4.64J 0.384 53.4 88.1 MW-13 5-Nov-12 757 0.633J 1.13J 10.4 8.36J 0.487 46.2J 4.12J 234 MW-13 16-May-13 2J 550 0.1J 0.6J 0.5J 9J 13 0.4J 0.35 36J 103 MW-13 7-Nov-13 0.9J 480 0.08J 0.2J 7J 4JB 0.15J 33J 36 MW-13 10-Apr-14 2J 590 0.1J 0.6J 0.3J 10.0 18 0.79 35J 6J 144 MW-13 28-Oct-14 2J 460 0.1J 1.7 6J 13 0.2J 0.21 30J 0.06J 265 MW-13 6-May-15 2J 610 0.1J 0.8J 0.2J 10 17 0.39 39J 98 MW-13 20-Nov-15 1J 500 0.1J 0.3J 0.3J 8J 13 0.50 32J 3J 48 MW-13 27-Apr-16 3J 620 0.1J 0.2J 0.3JB 9J 13 0.6J 0.51 35 58 MW-14 30-Mar-11 0.982J 36.3J 0.504J 2.89J 3.31JB 7.52J 13.0 MW-14 7-Nov-11 0.528J 5.60J 26.6J 2.00 1.91J 5.77J 5.42J MW-14 3-Apr-12 0.446J 178 2.38J 3.65J 8.28J 3.09J MW-14 5-Nov-12 0.299J 60.0J 3.59J 2.09J MW-14 16-May-13 1.5J 0.7J 70J 1.8 1J 1J 5J 0.02J 5J 5J MW-14 7-Nov-13 1.0J 0.6J 100J 2J 0.6J 0.9JB 5J 8J 7JB MW-14 10-Apr-14 1.9J 0.9J 90J 0.8J 1J 2J 5J 0.2J 0.09J 9J 15J 56.0 MW-14 28-Oct-14 0.3J 140 0.1J 0.4JB 0.5J 1J 5J 2JB MW-14 6-May-15 0.7J 0.8J 140 0.1J 1J 1J 7J 0.18J 10J 6JB MW-14 dup 6-May-15 1.4J 90 0.2J 1JB 1J 12 0.08J 6J 6J MW-14 20-Nov-15 0.9J 150 0.7J 0.7J 4J 0.08J 5J 1J 4J MW-14 27-Apr-16 0.4J 0.5J 240 3JB 2J 1J 0.12J 18J Page 2 of 21 June 2016 Table 4a Detected Groundwater Constituents - Inorganics April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Me r c u r y Ni c k e l Se l e n i u m Sil v e r So d i u m Th a l l i u m Va n a d i u m Zin c To t a l D i s s o l v e d S o l i d s 1*10 700 4*2 10 1*1,000 15 1 100 20 20 20,000*0.2*0.3*1,000 500,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 NE 5.5 25 10 NE North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-15 31-Mar-11 0.444J 118 1.11 2.91J 1.21J 8.29JB 2.42J 0.190J 23.9J 0.848J 4.56J 5.65J MW-15 8-Nov-11 118 0.700J 1.09J 16.5J 2.31J MW-15 5-Apr-12 1.01J 117 5.95J 18.7J MW-15 7-Nov-12 1.20J 133 18.3J 5.03J MW-15 16-May-13 1.3J 140 0.5J 1J 1J 14 0.3J 0.07J 21J MW-15 7-Nov-13 220 0.05J 0.1J 2J 4J 5JB 0.11J 34J MW-15 8-Apr-14 0.8J 160 1 0.5J 1J 4J 0.3J 0.08J 23J 2J 6J 7JB MW-15 27-Oct-14 1.6J 180 0.4J 0.2JB 2J 2J 0.2J 25J 4JB MW-15 5-May-15 1.0J 0.8J 210 0.4J 0.8J 4J 17 0.2J 0.08J 28J 5JB MW-15 18-Nov-15 0.4J 180 0.7J 0.3J 2J 2J 0.3J 0.03J 27J 1J 5J MW-15 27-Apr-16 280 0.07J 0.2J 5J 4J 7J 0.8J 0.21 32J 6J MW-16 1-Apr-11 10.8 451 4.40J 5.91J 2.72JB 10.3J 1.72J 6.35J MW-16 9-Nov-11 18.9 348 0.123J 6.12J 5.69J 4.97J 5.31J 7.05J 13.8 MW-16 5-Apr-12 0.267J 14.6 433 4.11J 5.20J 9.34J 2.68J MW-16 7-Nov-12 1.71J 11.1 436 2.64J 6.13J 3.98J 7.56J 5.46J MW-16 14-May-13 14 350 1J 6J 3J 0.8J 9J 3JB MW-16 5-Nov-13 16 260 1J 5J 1J 0.3J 4J 2J 7JB MW-16 8-Apr-14 13 300 0.3J 5J 1J 0.3J 0.02J 7J 2J 5J 6JB MW-16 27-Oct-14 10J 330 0.1J 0.2JB 5J 1J 0.4J 7J 5JB MW-16 5-May-15 13 280 1J 5J 3J 0.7J 0.03J 7J 2J 5JB MW-16 3-Nov-15 12 300 0.4J 5J 1JB 0.4J 7J 4J MW-16 27-Apr-16 12 330 0.7J 4J 0.5J 8J 1J 4J MW-17 1-Apr-11 12.0 111 2.02J 2.72J 4.04JB 5.52J 2.44J 3.16J 8.97J MW-17 9-Nov-11 13.3 190 0.183J 8.34J 5.52J 6.55J 7.49J 8.80J 10.6J 27.5 MW-17 5-Apr-12 5.59J 105 1.70J 2.00J 3.22J 5.18J 2.42J MW-17 7-Nov-12 0.226J 3.57J 156 1.93J 2.15J 1.78J 3.23J 4.98J 3.12J 7.49J MW-17 14-May-13 10J 120 0.08J 0.1J 2J 2J 3J 2J 5J 6JB MW-17 6-Nov-13 12 120 0.9J 1J 2J 0.6J 3J 5J 22 MW-17 10-Apr-14 8J 70J 0.3J 1J 1J 2J 0.7J 0.04J 3J 5J 9JB MW-17 28-Oct-14 8J 140 0.04J 2JB 3J 3J 2J 0.02J 6J 11 MW-17 5-May-15 11 140 0.2J 0.1J 5J 6J 7J 3J 9J 3J 24 MW-17 19-Nov-15 14 150 0.09J 0.1J 2J 7J 3J 2J 10J 1J 10J MW-17 26-Apr-16 11 110 0.2J 2J 4J 3J 1J 7J 9J MW-18 31-Mar-11 89.9J 1.90J 1.44J 2.78JB 9.44J 4.60J 2.44J 8.98J MW-18 8-Nov-11 104 1.33J 1.30J 2.53JB 8.05J 2.09J 8.83J MW-18 4-Apr-12 89.5J 1.44J 9.94J MW-18 6-Nov-12 104 12.1J 5.80J MW-18 15-May-13 2J 90J 0.3J 1J 1J 0.3J 13J MW-18 6-Nov-13 4J 120 0.2J 4J 4J 6J 2J 0.02J 18J 2J 6J 24 MW-18 10-Apr-14 2J 80J 0.5J 1J 2J 0.03J 15J 7J 6JB MW-18 28-Oct-14 2J 80J 1J 1J 14J 3J MW-18 5-May-15 2J 90J 0.3J 1J 2J 15J 4JB MW-18 19-Nov-15 2J 90J 0.4J 1J 1J 16J 1J 4J MW-18 26-Apr-16 1J 90J 0.4J 1J 2J 15J 4J MW-19 1-Apr-11 0.816J 127 0.492J 2.60J 5.65JB 3.62J 1.45J 4.26J 7.49J MW-19 9-Nov-11 0.701J 4.52J 169 0.431J 1.95J 2.11J 0.166J 6.52J 5.22J MW-19 5-Apr-12 2.30J 125 2.08J 6.00J 3.03J 2.78J 6.08J MW-19 4-Jun-12 --------------------------44,700 ------230,000 MW-19 19-Jul-12 --------------------------40,300 ------240,000 MW-19 16-Aug-12 --------------------------42,500 ------110,000 MW-19 7-Nov-12 1.88J 181 0.749J 4.97J 3.09J 6.14J 34,800 8.19J 21.2 130,000 MW-19 16-May-13 1.5J 1J 180 1 2J 2J 21 0.4J 5J 37,100 2J 5J 220,000 MW-19 31-Jul-13 --------------------------40,500 ------242,000 MW-19 7-Nov-13 2J 170 0.5J 0.1J 1JB 1J 36,800 4J 4JB 222,000 MW-19 16-Jan-14 --------------------------40,900 ------232,000 MW-19 9-Apr-14 1.0J 3J 150 0.4J 2J 10J 7J 0.4J 0.04J 12J 10,200 6J 10B 154,000 MW-19 29-Oct-14 4.1J 2J 150 0.9J 2JB 8J 4J 0.3J 10J 14,900 9JB 170,000 MW-19 7-May-15 3.2J 2J 220 0.09J 0.2J 3J 18 14 0.3J 0.03J 25J 7,900 2J 27 150,000 MW-19 20-Nov-15 1.3J 2J 150 0.08J 0.3J 3J 5J 5J 0.4J 10J 1J 3J 8J 134,000 MW-19 26-Apr-16 0.3J 1J 160 0.06J 2J 5J 19 0.2J 15J 7,900 8J 120,000 MW-19 (dup)26-Apr-16 0.4J 1J 160 0.07J 0.1J 2J 5J 20 0.2J 15J 8J Page 3 of 21 June 2016 Table 4a Detected Groundwater Constituents - Inorganics April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Me r c u r y Ni c k e l Se l e n i u m Sil v e r So d i u m Th a l l i u m Va n a d i u m Zin c To t a l D i s s o l v e d S o l i d s 1*10 700 4*2 10 1*1,000 15 1 100 20 20 20,000*0.2*0.3*1,000 500,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 NE 5.5 25 10 NE North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-20 1-Apr-11 4.27J 270 0.244J 19.8 11.1 18.6B 12.9 21.4J 1.53J 25.5 60.3 MW-20 9-Nov-11 6.55J 290 0.371J 24.2 14.1 16.6 14.4 23.1J 29.5 78.5 MW-20 5-Apr-12 0.722J 4.37J 162 4.66J 1.57J 4.30J 2.52J 4.25J 6.28J 9.31J MW-20 7-Nov-12 218 12.6 3.41J 5.42J 5.18J 9.29J 11.5J 24.7 MW-20 14-May-13 0.3J 3J 190 0.1J 11 3J 14 3J 9J 5J 19B MW-20 5-Nov-13 0.3J 4J 240 0.2J 0.1J 10 7J 11 5J 13J 0.08J 18J 47 MW-20 9-Apr-14 0.5J 2J 160 0.3J 3J 2J 568 2J 0.03J 5J 14J 51 MW-20 28-Oct-14 6J 450 0.3J 0.2J 7J 6J 46 3J 0.09J 10J 45 137 MW-20 5-May-15 0.6J 4J 220 0.2J 7J 5J 14 3J 9J 11J 38 MW-20 19-Nov-15 0.4J 3J 210 0.1J 6J 4J 9J 3J 8J 8J 26 MW-20 27-Apr-16 0.2J 4J 240 0.2J 7J 5J 8J 4J 9J 1J 28 MW-21 31-Mar-11 5.64J 68.2J 3.98J 2.59J 7.16JB 3.89J 5.66J 8.91J 21.6 MW-21 8-Nov-11 16.1 135 0.295J 12.7 7.88J 13.1 11.8B 13.2J 22.4J 48.7 MW-21 4-Apr-12 6.23J 58.1J 1.85J 2.48J 4.35J 3.08J 3.78J 6.78J 11.7 MW-21 6-Nov-12 3.19J 76.4J 3.52J 2.14J 4.73J 4.37J 3.13J 9.45J 18.3 MW-21 15-May-13 4J 70J 0.08J 2J 2J 4J 2J 3J 5J 9JB MW-21 6-Nov-13 2J 60J 0.06J 2J 1J 3JB 1J 2J 6J 7JB MW-21 9-Apr-14 6J 220 0.2J 7J 5J 11 5J 0.04J 10J 37 89 MW-21 28-Oct-14 3J 60J 0.04J 2JB 1J 3J 2J 2J 4J 7J MW-21 5-May-15 5J 100 0.2J 6J 3J 8J 4J 7J 13J 25 MW-21 19-Nov-15 2J 40J 0.05J 0.2J 1J 1J 3J 1J 2J 3J 7J MW-21 26-Apr-16 2J 60J 0.05J 1J 1J 2J 1J 2J 6J MW-22 31-Mar-11 192 4.64J 3.08J 7.81J 4.27J 6.41J 3.75J 7.30J 21.7 MW-22 8-Nov-11 4.30J 173 1.44J 2.21JB 1.82J 14.6 MW-22 4-Apr-12 4.66J 159 2.17J 3.18J 2.41J 2.38J 2.79J 3.14J 8.59J MW-22 6-Nov-12 4.70J 184 2.41J 1.47J 7.72J MW-22 15-May-13 3J 200 0.1J 0.7J 4J 4J 7J 2J 0.04J 7J 19B MW-22 6-Nov-13 3J 160 0.2J 0.9J 3J 3JB 0.3J 0.06J 3J 4JB MW-22 9-Apr-14 2J 240 0.2J 1J 2J 3J 0.6J 0.05J 4J 8J 9JB MW-22 28-Oct-14 3J 250 0.1J 0.5J 4JB 7J 7J 2J 0.11J 7J 3J 36 MW-22 5-May-15 4J 240 0.05J 1J 6J 3J 0.6J 0.06J 5J 7JB MW-22 19-Nov-15 4J 240 0.09J 2J 7J 5J 1J 0.03J 6J 1J 11 MW-22 26-Apr-16 5J 240 0.8J 5J 2J 0.8J 0.03J 5J 9J MW-23 31-Mar-11 159 1.06J 1.82J 2.33J 41.7 MW-23 8-Nov-11 4.39J 203 1.68J 3.78JB 3.38J MW-23 4-Apr-12 201 1.03J 2.76J 7.63J MW-23 5-Nov-12 MW-23 15-May-13 MW-23 5-Nov-13 MW-23 8-Apr-14 MW-23 27-Oct-14 MW-23 5-May-15 2J 270 0.3J 0.3J 0.9J 0.02J 2J 4JB MW-23 19-Nov-15 10 830 0.06J 3J 7J 5J 2J 9J 1J 20 MW-23 26-Apr-16 260 1J 0.05J 12 MW-24 1-Apr-11 35.1 653 0.918J 43.6 35.3 56B 38.8 0.916 66.1 9.82J 70.9 175 MW-24 dup 1-Apr-11 49.8 743 1.29 60.9 46.9 77.8B 54.9 0.649 86.7 10.1 99.0 251 MW-24 9-Nov-11 20.1 402 0.101J 8.94J 12.6 1.67J 7.00J 0.237 24.4J 8.52J 23.8 MW-24 5-Apr-12 0.297J 27.2 599 0.439J 16.8 19.5 19.9 11.2 0.708 34.3J 2.77J 31.7 64.3 MW-24 7-Nov-12 15.2 415 7.43J 11.7 3.44J 3.75J 0.192J 24.7J 2.24J 9.92J 26.2 MW-24 16-May-13 15 570 0.6J 0.3J 21 24 41 15 0.17J 45J 0.10J 43 132 MW-24 6-Nov-13 15 360 0.1J 3J 12 4JB 2J 0.04J 26J 2J 14B MW-24 8-Apr-14 9J 550 0.6J 0.4J 25 23 31 18 0.26 46J 0.05J 86 219 MW-24 27-Oct-14 11 410 0.2J 8J 14 9J 5J 0.12J 30J 49 MW-24 5-May-15 4J 160 0.7J 4J 1J 0.2J 11J 11JB MW-24 19-Nov-15 6J 200 0.05J 0.4J 1J 5J 3J 0.9J 0.02J 15J 1J 9J MW-24 25-Apr-16 7J 140 3J 2J 4J 1J 10J 18 MW-25 31-Mar-11 0.857J 836 1.17J 4.62J 8.85J 2.51J 9.05J MW-25 8-Nov-11 3.59J 903 3.49J 1.33J 2.62JB 6.03J 8.20J 18.3 MW-25 4-Apr-12 894 1.20J 4.53J 1.92J MW-25 6-Nov-12 963 4.55J 5.23J 5.51J MW-25 15-May-13 2J 900 0.2J 0.4J 0.8J 1J 0.3J 8J MW-25 6-Nov-13 2J 820 0.4J 0.7J 1JB 8J 2J MW-25 9-Apr-14 2J 830 0.4J 0.7J 1J 2J 0.3J 8J 3J 11J 9JB MW-25 28-Oct-14 2J 780 0.4J 0.6J 0.7J 8J 2J 3J MW-25 5-May-15 2J 820 0.3J 0.7J 1J 0.04J 8J 3JB MW-25 19-Nov-15 1J 890 0.4J 0.8J 2J 9J 1J 4J MW-25 26-Apr-16 830 0.7J 8J No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry Page 4 of 21 June 2016 Table 4a Detected Groundwater Constituents - Inorganics April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Me r c u r y Ni c k e l Se l e n i u m Sil v e r So d i u m Th a l l i u m Va n a d i u m Zin c To t a l D i s s o l v e d S o l i d s 1*10 700 4*2 10 1*1,000 15 1 100 20 20 20,000*0.2*0.3*1,000 500,000 6 10 100 1 1 10 10 10 10 0.2 50 10 10 NE 5.5 25 10 NE North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-26 31-Mar-11 161 1.31 0.522J 6.42J 31.1 9.24JB 6.33J 19.9J 4.19J 9.00J 70.1 MW-26 8-Nov-11 3.21J 230 1.66 1.75J 34.0 3.04JB 16.3J 2.58J 52.5 MW-26 4-Apr-12 364 2.12 1.78 60.2 4.53J 23.5J 30.4 MW-26 6-Nov-12 357 1.98 47.9 1.85J 21.2J 46.9 MW-26 15-May-13 0.5J 340 1.9 0.4J 0.4J 55 2J 0.3J 21J 25 MW-26 6-Nov-13 5J 400 1.8 0.4J 16 40 17 10J 0.04J 31J 0.07J 29 72 MW-26 9-Apr-14 330 1.6 0.4J 0.6J 56 2J 0.3J 0.03J 20J 5J 30B MW-26 28-Oct-14 1J 350 1.8 0.3J 0.4JB 50 2J 0.3J 0.04J 19J 25 MW-26 5-May-15 1J 300 1.6 0.3J 2J 47 3J 0.5J 0.05J 18J 2J 26 MW-26 19-Nov-15 0.6J 180 1.4 0.3J 1J 32 4J 0.7J 0.04J 13J 1J 27 MW-26 26-Apr-16 180 1.1 2J 29 2J 0.9J 0.03J 10J 36 MW-27 31-Mar-11 97.1J 0.63J 1.76J 1.15J 4.12JB 1.92J 0.33 1.97J 0.938J 3.51J 14.6 MW-27 8-Nov-11 9.70J 128 0.159J 6.51J 4.23J 5.94J 7.64JB 0.286 7.06J 9.22J 27.7 MW-27 4-Apr-12 4.27J 110 2.36J 1.46J 5.25J MW-27 6-Nov-12 139 1.21J 1.47J 1.71J 1.98J 2.02J 13.3J 8.97J MW-27 15-May-13 2J 110 1J 0.4J 1J MW-27 6-Nov-13 4J 150 0.1J 4J 4J 8J 3J 0.09J 8J 19J 25 MW-27 9-Apr-14 3J 120 0.2J 2J 2J 0.6J 0.12J 2J 7J 8JB MW-27 28-Oct-14 2J 140 0.7J 0.3J 1J 2J 2J MW-27 5-May-15 8J 150 3J 0.4J 0.05J 2J 3JB MW-27 19-Nov-15 3J 130 1J 0.4J 1J 1J 4J MW-27 26-Apr-16 18 160 11 0.02J 4J 10 MW-28 1-Apr-11 189 10.1 6.31J 11.2B 4.68J 9.03J 1.64J 25.8 47.0 MW-28 9-Nov-11 18.8 464 0.791J 47.1 25.5 30.3 14.2 34.0J 85.6 180 MW-28 5-Apr-12 2.96J 233 14.0 7.61J 12.6 5.46J 11.2J 30.2 51.4 MW-28 6-Nov-12 24.4 620 0.359J 21.7 11.0 19.7 9.09J 17.0J 2.19J 62.3 90.4 MW-28 15-May-13 13 1040 1.7 0.5J 67 52 65 32 0.04J 67 0.3J 291 683 MW-28 6-Nov-13 5J 300 0.4J 0.2J 15 12 16 6J 15J 2J 53 94 MW-28 9-Apr-14 1J 160 0.3J 2J 1J 144 0.6J 0.04J 3J 14J 31 MW-28 28-Oct-14 0.8J 150 3JB 1J 9J 0.5J 3J 6J 10 MW-28 5-May-15 1J 270 0.8J 0.5J 1J 2J 3JB MW-28 19-Nov-15 2J 190 0.1J 6J 3J 12 1J 5J 1J 13J 21 MW-28 26-Apr-16 5J 300 0.4J MW-29 1-Apr-11 193 4.92J 8.59J 7.77JB 2.27J 10.5J 1.16J 1.92J 13.1 MW-29 9-Nov-11 142 0.173J 2.53J 2.63J 2.50J 3.42J 2.96J 8.54J MW-29 dup 9-Nov-11 154 0.233J 4.47J 3.01J 3.09J 3.35J 4.95J 3.95J 16.5 MW-29 5-Apr-12 827 4.23 42.2 28.1 116 27.5 57.2 0.245J 28.7 186 MW-29 4-Jun-12 --------------------------9,800 ------190,000 MW-29 19-Jul-12 --------------------------12,900 ------260,000 MW-29 16-Aug-12 --------------------------13,500 ------160,000 MW-29 7-Nov-12 375 2.17 31.2 16.9 72.2 21.1 31.1J 13,400 0.136J 23.9J 132 220,000 MW-29 16-May-13 10J 2300 28.6 2.3 140 100 1610 193 0.29 200J 25,600 0.8J 575 1270 316,000 MW-29 31-Jul-13 --------------------------20,000 ------309,000 MW-29 7-Nov-13 7J 2330 25 2.4 150 100 360 176 0.29 190J 2J 22,700 0.8J 707 847 312,000 MW-29 16-Jan-14 --------------------------13,600 ------129,000 MW-29 9-Apr-14 7J 630 4.2 0.8J 68 32 71 33 0.16J 55 12,100 0.3J 124 168 268,000 MW-29 29-Oct-14 4J 330 1.5 0.5J 20 11 31 18 0.09J 21J 13,900 0.1J 47 74 228,000 MW29 6-May-15 7J 470 2.3 0.3J 35 19 50 20 0.06J 37J 12,100 0.2J 53 104 202,000 MW29 20-Nov-15 2J 250 1.1 1.4 14 7J 20 17 0.07J 15J 0.1J 41 87 160,000 MW29 27-Apr-16 350 1.5 0.2J 19 11 25 21 20J 11,000 0.1J 46 70 176,000 Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. J - Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section reporting limit. 4. B - Amount in prep blank > method detection limit 5. dup - Duplicate Sample 6. -- Not analyzed for 7. NE - Standard Not Established - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard - Indicates the result is below the detection limit - A sodium lactate injection was performed near MW-8, -9, and -10 on June 18-21, 2012. - An emulsified vegetable oil injection was performed near MW-8, -9, and -10 on March 25-27, 2013. Page 5 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 MW-2 31-Mar-11 1.5J MW-2 8-Nov-11 7.6 MW-2 4-Apr-12 0.65J MW-2 6-Nov-12 3.1J MW-2 15-May-13 MW-2 6-Nov-13 1.7J MW-2 9-Apr-14 8.1J 1.3J MW-2 28-Oct-14 1.9J MW-2 5-May-15 10J 2.7J 0.39J MW-2 19-Nov-15 9.1 MW-2 26-Apr-16 2.3J MW-4 31-Mar-11 1.3J MW-4 8-Nov-11 2.0J MW-4 4-Apr-12 0.51J 1.9J 0.45J MW-4 6-Nov-12 2.2J MW-4 15-May-13 0.52J 1.9J 0.32J 1.2J MW-4 6-Nov-13 2.7J MW-4 9-Apr-14 0.63J 2.2J 0.26J 0.65J MW-4 28-Oct-14 0.43J 2.4J 0.43J MW-4 5-May-15 0.64J 3.5J 0.51J MW-4 19-Nov-15 0.56J 3.1J 0.24J 0.44J 0.32J MW-4 26-Apr-16 0.50J 3.8J MW-6 1-Apr-11 1.0J MW-6 9-Nov-11 1.1J MW-6 4-Apr-12 1.4J MW-6 6-Nov-12 1.8J MW-6 15-May-13 0.93J 0.97J 0.77J 2.7J 5.6 0.24J 5.4 MW-6 6-Nov-13 3.0J MW-6 9-Apr-14 7.1J 0.60J 0.74J 0.31J 4.7J 5.4 4.1J 0.52J MW-6 28-Oct-14 0.28J 0.94J 0.42J 3.2J 3.6J 2.0J MW-6 5-May-15 0.77J 1.2J 2.6J 7.4 1.5J 4.5J 0.70J MW-6 18-Nov-15 0.74J 0.35J 0.36J 5.0J 1.1J MW-6 dup 18-Nov-15 0.68J 0.32J 0.37J 4.8J 1.1J MW-6 27-Apr-16 0.40J 0.70J 6.2 0.94J North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Page 6 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-8 30-Mar-11 7.8 3.8J 4.4 0.73J 1.2 1.5 4.3J MW-8 7-Nov-11 0.52J MW-8 4-Apr-12 4.1J 2.7J 0.38J 3.6 0.33J 0.55J 0.80J 3.3J MW-8 19-Jul-12 7.6J 0.72J 0.46J MW-8 16-Aug-12 MW-8 6-Nov-12 0.60J 0.41J MW-8 15-May-13 0.81J 0.47J MW-8 31-Jul-13 0.89J 0.72J 0.26J MW-8 6-Nov-13 MW-8 16-Jan-14 0.57J 0.38J MW-8 10-Apr-14 7.4J 0.97J 0.28J MW-8 29-Oct-14 0.52J 0.31J 0.20J 0.59J MW-8 7-May-15 11J 0.72J 0.96J 0.30J 0.40J MW-8 19-Nov-15 0.39J 0.67J 0.34J 0.22J 0.75J MW-8 26-Apr-16 1.5J 0.59J MW-9 30-Mar-11 1.8J 34 3.8J 5.9 6.5 0.67J 4.0J 5.0 6.60 MW-9 7-Nov-11 2.7J 36 3.4J 0.70J 4.2 4.6 3.8J 3.8 0.66J 4.3J MW-9 4-Apr-12 0.43J 1.2J 42 3.1J 0.66J 3.9 4.5 0.35J 4.9J 4.0 0.82J 3.5J MW-9 dup 4-Apr-12 0.42J 3.6J 46 3.3J 0.74J 6.4 4.9 0.47J 4.1J 4.0 0.94J 6.10 MW-9 19-Jul-12 140 0.54J 0.44J 2.8J 37 1.6J 0.49J 0.46 3.3 4.2J 3.2 0.81J 15 MW-9 16-Aug-12 120 6.0J 41 1.2J 0.86J 3.9J 2.4 1.3 16 MW-9 6-Nov-12 250 0.50J 6.1J 32 1.4J 0.87J 2.7 3.6J 2.5 0.6J 0.82J 37J 2.1J MW-9 15-May-13 0.96J 21 21 0.42J 2.2J 2.8J 0.63J 0.76J 28J 0.46J MW-9 dup 15-May-13 0.98J 16 20 2.2J 2.5J 0.54J 0.71J 28J 1.4J MW-9 31-Jul-13 0.75J 22 3.1J 1.9J 0.85J MW-9 6-Nov-13 32J 0.73J 19 12 1.7J 0.47J 1.5 4.2J 1.5J MW-9 16-Jan-14 24J 0.57J 19 4.9J 0.55J 1.6J 4.1 0.56J 0.74J MW-9 10-Apr-14 13J 0.71J 0.66J 20 17 0.17J 1.2J 2.3J 0.51J 2.6 1.4 MW-9 dup 10-Apr-14 23J 0.60J 0.59J 21 18 1.2J 2.4J 2.2 1.4 MW-9 29-Oct-14 6.4J 0.66J 0.47J 15 11 0.63J 0.41J 1.4J 0.98J MW-9 dup 29-Oct-14 8.9J 0.61J 0.47J 16 10 0.66J 0.04J 1.3J 1.09J 1.7 0.43J MW-9 7-May-15 1.1 16 1 19 2.0J 1.6J 1.3 0.91J MW-9 20-Nov-15 0.86J 0.61J 15 0.74J 11 0.52J 0.43J 1.0J 1.5J 0.31J 0.89J 0.47J MW-9 27-Apr-16 0.96J 0.74J 14 14 0.51JB 0.60J 0.41J 0.78J 0.53J Page 7 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-10 30-Mar-11 0.79J 2.5 11 43 0.56J 1.1 0.73J 1.2J 3.3J 3.2 MW-10 7-Nov-11 3.9J 3 1.5 15 53 0.43J 0.80J 3.1J 2.2 MW-10 4-Apr-12 6.4J 4.9 0.35J 2.5 54 0.38J 1.6 0.81J 0.51J 1.4J 2.8J 0.53J 1.1J 4.3 0.55J MW-10 19-Jul-12 840 8.5J 30 220 MW-10 16-Aug-12 5800 1,100 MW-10 6-Nov-12 780D 21D 4.2JD 330D MW-10 dup 6-Nov-12 700D 21D 3.9JD 310D MW-10 15-May-13 530.0 1.9 24 1.9J 0.33J 1.3J 1.7J 0.58J 0.16J 4.6 87J MW-10 31-Jul-13 2.4 0.63J 18 0.40J 0.78J 0.48J 0.25J 20 MW-10 6-Nov-13 2.1 1.2 21 3.0J 2.5 MW-10 dup 6-Nov-13 1.6 0.93J 18 2.4J 2.6 MW-10 16-Jan-14 6.6J 2.6 1.5 17 12 1.1 0.69J 1.1J 0.76J 1.4 2.2 MW-10 10-Apr-14 8.0J 2.8 0.31J 1.7 16 20 0.22J 1.4 1.3J 1.1J 0.92J 2.5 4.2 MW-10 29-Oct-14 2.4 0.25J 1.6 18 9.0 0.27J 0.48J 0.66J 0.43J 0.39J MW-10 7-May-15 6.6 0.82J 3.6 23 68.0 0.48J 0.36J 2 2.6J 2.9J 1.9J 2.33J 0.27J 4.5 MW-10 20-Nov-15 17J 4.1 1.4J 4.0 17 0.65J 46 0.42J 0.22J 1.5 1.1 2.0J 0.94J 0.86J 1.1J 0.34J 2.9 MW-10 27-Apr-16 17J 5.6 0.77J 4.3 27 44 0.48J 0.94JB 0.95J 2.9 MW-11 31-Mar-11 MW-11 8-Nov-11 MW-11 4-Apr-12 MW-11 6-Nov-12 MW-11 15-May-13 MW-11 6-Nov-13 MW-11 10-Apr-14 MW-11 29-Oct-14 MW-11 6-May-15 0.55J 0.40J MW-11 20-Nov-15 0.57J MW-11 27-Apr-16 7.3J Page 8 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-12 31-Mar-11 MW-12 8-Nov-11 MW-12 3-Apr-12 MW-12 5-Nov-12 MW-12 15-May-13 MW-12 6-Nov-13 MW-12 10-Apr-14 MW-12 28-Oct-14 MW-12 6-May-15 0.33J MW-12 20-Nov-15 7.8J 0.82J MW-12 27-Apr-16 MW-13 31-Mar-11 12.0 2.2 0.42J 1.4J MW-13 8-Nov-11 2.1 15.0 2.0 1.9J MW-13 3-Apr-12 2.4 17.0 3.0 2.3J MW-13 5-Nov-12 1.6 13.0 2.5 0.52J 1.4J MW-13 16-May-13 2.5 18 3.2 0.52J 2.4J MW-13 7-Nov-13 1.4 12 0.73J 1.7J MW-13 10-Apr-14 1.9 12 2.4 2.1J MW-13 28-Oct-14 1.4 13 2.1 1.3J MW-13 6-May-15 2 13 2.7 0.28J 2.3J 0.28J MW-13 20-Nov-15 1.2 9.0 1.9 0.63J 0.32J 1.4J MW-13 27-Apr-16 1.4 12 2.6 1.4J MW-14 30-Mar-11 MW-14 7-Nov-11 25J MW-14 3-Apr-12 0.38J 0.63J 1.2J MW-14 5-Nov-12 0.47J MW-14 16-May-13 0.46J MW-14 7-Nov-13 MW-14 10-Apr-14 0.23J MW-14 28-Oct-14 0.47J 0.41J 0.59J 0.19J MW-14 6-May-15 0.28J 0.40J 0.61J MW-14 dup 6-May-15 11J 0.37J 0.67J MW-14 20-Nov-15 8.2J 0.44J 0.95J 0.71J 1.2 1.1J 0.22J 0.53J MW-14 27-Apr-16 0.75J 3.3 1.2 1.4J 0.61J Page 9 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-15 31-Mar-11 MW-15 8-Nov-11 0.85J MW-15 5-Apr-12 0.59J MW-15 7-Nov-12 0.45J 0.48J 0.97J MW-15 16-May-13 0.35J 0.69J MW-15 7-Nov-13 1.0J MW-15 8-Apr-14 0.85J 0.58J 0.65J MW-15 27-Oct-14 1.1J 0.68J 0.96J MW-15 5-May-15 0.42J 3.1 1 0.58J 0.66J 0.47J MW-15 18-Nov-15 0.22J 1.7J 0.87J 1.3J 0.22J 0.54J MW-15 27-Apr-16 0.34J 5.3 1.5 1.2J 0.50J MW-16 1-Apr-11 6.2J 1.7 2.3J 6.6 5.1 1.8 MW-16 9-Nov-11 1.3 2.3J 5.1 4.3J 0.93J MW-16 5-Apr-12 21J 1.4 0.53J 1.9J 5.6 2.9J 2.0 1.7J MW-16 7-Nov-12 34J 1.5 0.56J 3.7J 6.8 0.74J 3.3J 5.5 3.6J MW-16 14-May-13 1.3 0.61J 2.4J 7.1 0.35J 3.3J 5.8 5.2J MW-16 5-Nov-13 1.2 2.5J 6.5 3.5J 2.9 MW-16 8-Apr-14 1.2 0.40J 3.5J 8.3 0.19J 0.92J 3.6J 4.4 3.3J MW-16 27-Oct-14 0.99J 0.35J 2.7J 6.2 0.81J 2.7J 3.7 2.5J MW-16 5-May-15 1.2 0.36J 0.48J 7.3 1.5J 3.5J 3.5 0.36J 2.5J MW-16 3-Nov-15 1.0 1.0J 6.5 0.17J 2.8J 3.9 0.38J 1.9J MW-16 27-Apr-16 1.0 0.39J 0.26J 1.3J 7.0 3.3J 2.0 0.49J MW-17 1-Apr-11 2.6J 21 3.5J MW-17 9-Nov-11 5.6J 17 2.8J MW-17 5-Apr-12 2.9J 19 2.3J 0.49J MW-17 7-Nov-12 3.6J 18 2.7J 0.43J MW-17 14-May-13 2.1J 14 2.1J MW-17 6-Nov-13 10 1.3J MW-17 10-Apr-14 6.7J 1.5J 10 1.3J MW-17 28-Oct-14 5.3J 12 2.1J 0.45J MW-17 5-May-15 19J 1.0J 0.85J 14 2.0J 0.41J MW-17 19-Nov-15 7.9J 0.84J 0.88J 16 0.31J 0.24J 2.7J 0.44J 1.0 MW-17 26-Apr-16 0.33J 10 1.4J Page 10 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-18 31-Mar-11 MW-18 8-Nov-11 MW-18 4-Apr-12 MW-18 6-Nov-12 MW-18 15-May-13 MW-18 6-Nov-13 MW-18 10-Apr-14 MW-18 28-Oct-14 MW-18 5-May-15 7.1J 0.52J MW-18 19-Nov-15 7.3J 0.29J MW-18 26-Apr-16 MW-19 1-Apr-11 0.64J MW-19 9-Nov-11 MW-19 5-Apr-12 1.0J MW-19 19-Jul-12 4.0J MW-19 16-Aug-12 MW-19 7-Nov-12 MW-19 16-May-13 230 MW-19 31-Jul-13 MW-19 7-Nov-13 MW-19 16-Jan-14 MW-19 9-Apr-14 MW-19 29-Oct-14 MW-19 7-May-15 12J MW-19 20-Nov-15 MW-19 26-Apr-16 0.33J MW-19 (dup)26-Apr-16 Page 11 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-20 1-Apr-11 MW-20 9-Nov-11 MW-20 5-Apr-12 MW-20 7-Nov-12 MW-20 14-May-13 MW-20 5-Nov-13 MW-20 9-Apr-14 9.3J 0.53J MW-20 28-Oct-14 MW-20 5-May-15 8.7J 0.50J MW-20 19-Nov-15 0.25J MW-20 27-Apr-16 MW-21 31-Mar-11 MW-21 8-Nov-11 MW-21 4-Apr-12 MW-21 6-Nov-12 MW-21 15-May-13 MW-21 6-Nov-13 MW-21 9-Apr-14 MW-21 28-Oct-14 MW-21 5-May-15 0.64J MW-21 19-Nov-15 MW-21 26-Apr-16 MW-22 31-Mar-11 MW-22 8-Nov-11 MW-22 4-Apr-12 MW-22 6-Nov-12 MW-22 15-May-13 MW-22 6-Nov-13 MW-22 9-Apr-14 MW-22 28-Oct-14 MW-22 5-May-15 0.97J MW-22 19-Nov-15 MW-22 26-Apr-16 Page 12 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-23 31-Mar-11 MW-23 8-Nov-11 MW-23 4-Apr-12 MW-23 5-Nov-12 MW-23 15-May-13 MW-23 5-Nov-13 MW-23 10-Apr-14 MW-23 27-Oct-14 MW-23 5-May-15 0.71J MW-23 19-Nov-15 23J 0.81J MW-23 26-Apr-16 6.0J MW-24 1-Apr-11 2.6 7.6 3.0 2.1J 7.8 1.2J MW-24 (dup)1-Apr-11 7.5 3.3 1.7J 7.6 1.2J MW-24 9-Nov-11 3.3 10 3.5 3.4J 9.9 1.3J MW-24 5-Apr-12 3.0 8.5 3.5 3.0J 8.6 1.0J 0.48J 0.42J MW-24 7-Nov-12 3.2 9.5 3.2 3.2J 9.0 MW-24 16-May-13 2.9 7.9 3.2 2.5J 7.8 0.31J 1.1J 0.62J 0.42J MW-24 6-Nov-13 2.5 6.4 2.6 3.2J 8.8 1.1J MW-24 8-Apr-14 1.4 3.6 1.7 2.2J 5.3 0.64J 0.20J MW-24 27-Oct-14 2.6 6.6 2.3 2.9J 9.0 1.2J 0.43J 0.33J MW-24 5-May-15 1.1 2.1J 1.1 0.48J 4.6J 1.6J 0.61J 0.25J MW-24 19-Nov-15 12J 1.4 3.6 1.3 5.0 0.27J 0.70J 0.21J MW-24 25-Apr-16 7.6J 0.25J 2.0J 0.54J MW-25 31-Mar-11 1.9J 3.4J MW-25 8-Nov-11 1.4J 3.2J MW-25 4-Apr-12 0.65J 2.9J 4.4J MW-25 6-Nov-12 0.78J 2.3J 3.9J MW-25 15-May-13 0.83J 2.3J 4.0J 1.2J MW-25 6-Nov-13 0.87J 3.2J MW-25 9-Apr-14 0.80J 2.7J 3.1J MW-25 28-Oct-14 0.87J 4.3J 2.6J MW-25 5-May-15 1.4 2.1J 0.77J 3.7J 1.6J MW-25 19-Nov-15 17J 1.2 2.7J 0.37J MW-25 26-Apr-16 12J 1.2 2.9J No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry No Sample Collected - Well was Dry Page 13 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-26 31-Mar-11 0.62J MW-26 8-Nov-11 1.4 0.91J MW-26 4-Apr-12 1.6 0.66J 1.1J 1.4J 0.49J MW-26 6-Nov-12 1.4 0.47J 0.83J 1.1J 0.60J MW-26 15-May-13 0.88J 0.54J 0.32J 0.57J MW-26 6-Nov-13 0.82J MW-26 9-Apr-14 1.5 0.69J 0.33J 1.4J 0.87J 0.66J MW-26 28-Oct-14 1.5 0.87J 0.37J 1.9J 0.97J 0.50J MW-26 5-May-15 16J 1.4 0.77J 0.84J 1.0J 1.6J 0.50J 0.21J MW-26 19-Nov-15 14J 1.3 1.1J 0.42J 0.71J 0.32J 0.39J MW-26 26-Apr-16 9.6J 1.4 1.5J 0.62J 0.70J MW-27 31-Mar-11 4.7J 1.4 4.1J MW-27 8-Nov-11 4.4J 1.2J 0.98J 1.7J MW-27 4-Apr-12 0.45J 5.8 1.1J 1.3 3.0J MW-27 6-Nov-12 0.46J 5.4 1.3J 1.1 1.4J MW-27 15-May-13 0.5J 5.5 2.5J 1.4J 0.32J 2.9J MW-27 6-Nov-13 6.1 5.0J MW-27 9-Apr-14 0.42J 5.7 0.67J 0.31J 2.3J MW-27 28-Oct-14 0.43J 6.1 1.4J 1.2J 0.26J 2.0J MW-27 5-May-15 9.1J 0.54J 0.50J 8.6 1.2J 1.6J 0.38J 2.8J MW-27 19-Nov-15 0.51J 7.8 1.2J 0.27J 1.0 0.65J 0.40J 0.37J 3.3J MW-27 26-Apr-16 0.44J 7.6 1.3J 0.88J 0.67J 0.37J MW-28 1-Apr-11 MW-28 9-Nov-11 MW-28 5-Apr-12 MW-28 6-Nov-12 MW-28 15-May-13 MW-28 6-Nov-13 MW-28 9-Apr-14 4.1J MW-28 28-Oct-14 1.2J MW-28 5-May-15 6.9J 8.2 0.44J MW-28 19-Nov-15 1.8J MW-28 26-Apr-16 1.8J 0.43J Page 14 of 21 June 2016 Table 4b Detected Groundwater Constituents - Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ac e t o n e Be n z e n e Ch l o r o b e n z e n e 1,4 - D i c h l o r o b e n z e n e Ch l o r o e t h a n e Ch l o r o f o r m Ch l o r o m e t h a n e 1,1 - D i c h l o r o e t h a n e 1,1 - D i c h l o r o e t h e n e 1,2 - D i c h l o r o e t h a n e 1,2 - D i c h l o r o p r o p a n e Et h y l b e n z e n e Me t h y l e n e C h l o r i d e Tr i c h l o r o f l u o r o m e t h a n e 4- M e t h y l - 2 - P e n t a n o n e Na p h t h a l e n e Te t r a c h l o r o e t h e n e 1, 1 , 1 - T r i c h l o r o e t h a n e ci s - 1 , 2 - D i c h l o r o e t h e n e Tr i c h l o r o e t h e n e m, p - X y l e n e s o- X y l e n e To t a l X y l e n e s To l u e n e Vi n y l C h l o r i d e ME K ( 2 - B u t a n o n e ) Dic h l o r o d i f l u o r o m e t h a n e 6,000 1 50 6 3,000 70 3 6 7 0.4 0.6 600 5 2,000 560*6 0.7 200 70 3 500 500 500 600 0.03 4,000 1,000 100 1 3 1 10 5 1 5 5 1 1 1 1 1 100 10 1 1 5 1 5 5 5 1 1 100 5 North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit MW-29 4-Mar-11 2.1J 1.6J 19 0.98J 1.8J 0.95J MW-29 1-Apr-11 1.3J 19 1.1J 0.76J 1.5 2.5J 1.2 0.61J 1.8J MW-29 9-Nov-11 2.1J 23 2.9J 1.0 0.89J MW-29 dup 9-Nov-11 2.0J 23 3.0J 0.93J 0.96J MW-29 5-Apr-12 1.5J 12 0.54J 0.58J 0.80J 1.2J 0.68J 1.1J MW-29 19-Jul-12 4.6J 0.45J 1.7J 21 2.6J 0.81J 0.66J MW-29 16-Aug-12 2.1J 20 2.4J 0.83J 0.49J MW-29 7-Nov-12 1.4J 18 0.45J 0.76J 2.6J 1.3 0.49J 0.68J MW-29 16-May-13 12J 0.27J 1.4J 12 0.49J 0.5J 1.8J 0.76J MW-29 31-Jul-13 0.26J 8.8J 7 0.78J 2.5J 1.5 MW-29 7-Nov-13 0.28J 3.4J 13 3.0J 0.68J MW-29 16-Jan-14 6.3J 0.27J MW-29 9-Apr-14 5.9J 0.89J MW-29 29-Oct-14 7.2 0.36J 1.2J 0.33J MW-29 6-May-15 9.4J 0.54J 1.7J 1.5J MW-29 20-Nov-15 MW-29 27-Apr-16 1.0J Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. J - Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section reporting limit 4. dup - Duplicate Sample - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard - Indicates the result is below the detection limit - A sodium lactate injection was performed near MW-8, -9, and -10 on June 18-21, 2012. - An emulsified vegetable oil injection was performed near MW-8, -9, and -10 on March 25-27, 2013. Page 15 of 21 June 2016 Table 4c Detected Groundwater Constituents - Pesticides, Herbicides, and PCBs Historical Results Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e 2, 4 - D 2, 4 , 5 - T P ( S i l v e x ) Alp h a - B H C Be t a - B H C De l t a - B H C Ga m m a - B H C ( L i n d a n e ) DD D 4,4 - D D T Die l d r i n Di n o s e b En d o s u l f a n I En d o s u l f a n I I En d r i n He p t a c h l o r E p o x i d e He p t a c h l o r Me t h o x y c h l o r 70 50 0.006*0.019*0.019*0.03 0.1 0.1 0.002 7*40 42*2 0.004 0.008 40 2 2 0.05 0.05 0.05 0.05 0.1 0.1 0.075 1 0.1 0.1 0.1 0.075 0.05 1 MW-2 16-Nov-04 MW-2 19-Apr-05 MW-2 8-Nov-05 MW-2 11-Apr-06 MW-2 7-Nov-06 MW-2 17-Apr-07 MW-2 6-Nov-07 MW-2 22-May-08 MW-2 2-Apr-09 0.418J MW-2 20-May-10 MW-2 31-Mar-11 MW-4 16-Nov-04 MW-4 19-Apr-05 MW-4 8-Nov-05 MW-4 11-Apr-06 MW-4 7-Nov-06 MW-4 17-Apr-07 MW-4 6-Nov-07 MW-4 21-May-08 0.125 MW-4 3-Apr-09 MW-4 20-May-10 MW-4 31-Mar-11 MW-6 16-Nov-04 MW-6 19-Apr-05 MW-6 8-Nov-05 MW-6 11-Apr-06 MW-6 7-Nov-06 MW-6 17-Apr-07 MW-6 6-Nov-07 MW-6 22-May-08 0.0163J 0.0272J** MW-6 3-Apr-09 MW-6 21-May-10 MW-6 1-Apr-11 MW-8 16-Nov-04 MW-8 19-Apr-05 MW-8 8-Nov-05 MW-8 11-Apr-06 MW-8 7-Nov-06 MW-8 17-Apr-07 MW-8 6-Nov-07 MW-8 22-May-08 0.0531J** MW-9 16-Nov-04 MW-9 19-Apr-05 MW-9 8-Nov-05 MW-9 11-Apr-06 MW-9 7-Nov-06 MW-9 17-Apr-07 MW-9 6-Nov-07 MW-9 23-May-08 0.0241J MW-9 2-Apr-09 MW-9 20-May-10 MW-9 30-Mar-11 Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard Page 16 of 21 June 2016 Table 4c Detected Groundwater Constituents - Pesticides, Herbicides, and PCBs Historical Results Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e 2, 4 - D 2, 4 , 5 - T P ( S i l v e x ) Alp h a - B H C Be t a - B H C De l t a - B H C Ga m m a - B H C ( L i n d a n e ) DD D 4,4 - D D T Die l d r i n Di n o s e b En d o s u l f a n I En d o s u l f a n I I En d r i n He p t a c h l o r E p o x i d e He p t a c h l o r Me t h o x y c h l o r 70 50 0.006*0.019*0.019*0.03 0.1 0.1 0.002 7*40 42*2 0.004 0.008 40 2 2 0.05 0.05 0.05 0.05 0.1 0.1 0.075 1 0.1 0.1 0.1 0.075 0.05 1Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-10 16-Nov-04 MW-10 19-Apr-05 MW-10 8-Nov-05 MW-10 11-Apr-06 MW-10 7-Nov-06 0.56J MW-10 17-Apr-07 MW-10 6-Nov-07 MW-10 23-May-08 0.0632 0.0253J MW-10 2-Apr-09 0.325J 0.066J 0.0399J MW-10 20-May-10 MW-10 30-Mar-11 MW-11 16-Nov-04 MW-11 19-Apr-05 MW-11 8-Nov-05 MW-11 11-Apr-06 MW-11 7-Nov-06 MW-11 17-Apr-07 MW-11 6-Nov-07 MW-11 23-May-08 0.0227J** MW-12 16-Nov-04 2.6 MW-12 19-Apr-05 MW-12 8-Nov-05 MW-12 11-Apr-06 MW-12 7-Nov-06 MW-12 17-Apr-07 MW-12 6-Nov-07 MW-12 22-May-08 0.0942 0.0539J 0.064J** MW-12 2-Apr-09 0.363J 0.0484J 0.0324J MW-12 20-May-10 0.19J MW-12 31-Mar-11 MW-13 16-Nov-04 MW-13 19-Apr-05 MW-13 8-Nov-05 MW-13 11-Apr-06 MW-13 7-Nov-06 MW-13 17-Apr-07 MW-13 6-Nov-07 MW-13 23-May-08 0.042J 0.0647J MW-13 2-Apr-09 0.0151J 0.0677J 0.032J 0.0125J MW-13 20-May-10 MW-13 31-Mar-11 MW-14 16-Nov-04 MW-14 19-Apr-05 MW-14 8-Nov-05 MW-14 11-Apr-06 MW-14 7-Nov-06 MW-14 17-Apr-07 MW-14 6-Nov-07 MW-14 23-May-08 0.0866J** Page 17 of 21 June 2016 Table 4c Detected Groundwater Constituents - Pesticides, Herbicides, and PCBs Historical Results Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e 2, 4 - D 2, 4 , 5 - T P ( S i l v e x ) Alp h a - B H C Be t a - B H C De l t a - B H C Ga m m a - B H C ( L i n d a n e ) DD D 4,4 - D D T Die l d r i n Di n o s e b En d o s u l f a n I En d o s u l f a n I I En d r i n He p t a c h l o r E p o x i d e He p t a c h l o r Me t h o x y c h l o r 70 50 0.006*0.019*0.019*0.03 0.1 0.1 0.002 7*40 42*2 0.004 0.008 40 2 2 0.05 0.05 0.05 0.05 0.1 0.1 0.075 1 0.1 0.1 0.1 0.075 0.05 1Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-15 16-Nov-04 MW-15 19-Apr-05 MW-15 8-Nov-05 MW-15 11-Apr-06 MW-15 7-Nov-06 MW-15 17-Apr-07 MW-15 6-Nov-07 0.077 0.059 MW-15 23-May-08 0.088J 0.0318J 0.092J** MW-15 (dup)23-May-08 0.0370J 0.069J** MW-15 3-Apr-09 0.0199J MW-15 (dup)3-Apr-09 0.504J 0.0236J MW-15 21-May-10 MW-15 31-Mar-11 MW-16 16-Nov-04 MW-16 19-Apr-05 MW-16 8-Nov-05 MW-16 11-Apr-06 MW-16 7-Nov-06 MW-16 17-Apr-07 MW-16 6-Nov-07 MW-16 21-May-08 0.152J 0.167 MW-16 3-Apr-09 0.293J MW-16 21-May-10 MW-16 1-Apr-11 MW-17 16-Nov-04 MW-17 19-Apr-05 MW-17 8-Nov-05 MW-17 11-Apr-06 MW-17 7-Nov-06 MW-17 17-Apr-07 MW-17 6-Nov-07 MW-17 23-May-08 0.0222J MW-17 1-Apr-09 MW-17 21-May-10 MW-17 1-Apr-11 MW-18 16-Nov-04 MW-18 19-Apr-05 MW-18 8-Nov-05 MW-18 11-Apr-06 MW-18 7-Nov-06 MW-18 17-Apr-07 MW-18 6-Nov-07 MW-18 22-May-08 0.17 0.0322J 0.128 MW-18 3-Apr-09 MW-18 20-May-10 MW-18 31-Mar-11 MW-19 16-Nov-04 MW-19 19-Apr-05 MW-19 8-Nov-05 MW-19 11-Apr-06 MW-19 7-Nov-06 MW-19 17-Apr-07 MW-19 6-Nov-07 MW-19 23-May-08 0.0149J** Page 18 of 21 June 2016 Table 4c Detected Groundwater Constituents - Pesticides, Herbicides, and PCBs Historical Results Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e 2, 4 - D 2, 4 , 5 - T P ( S i l v e x ) Alp h a - B H C Be t a - B H C De l t a - B H C Ga m m a - B H C ( L i n d a n e ) DD D 4,4 - D D T Die l d r i n Di n o s e b En d o s u l f a n I En d o s u l f a n I I En d r i n He p t a c h l o r E p o x i d e He p t a c h l o r Me t h o x y c h l o r 70 50 0.006*0.019*0.019*0.03 0.1 0.1 0.002 7*40 42*2 0.004 0.008 40 2 2 0.05 0.05 0.05 0.05 0.1 0.1 0.075 1 0.1 0.1 0.1 0.075 0.05 1Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-20 16-Nov-04 MW-20 19-Apr-05 MW-20 8-Nov-05 MW-20 11-Apr-06 MW-20 7-Nov-06 MW-20 17-Apr-07 MW-20 6-Nov-07 MW-20 22-May-08 0.0391J 0.061J** MW-20 3-Apr-09 MW-20 21-May-10 MW-20 1-Apr-11 MW-21 16-Nov-04 MW-21 19-Apr-05 MW-21 8-Nov-05 MW-21 11-Apr-06 MW-21 7-Nov-06 MW-21 17-Apr-07 MW-21 6-Nov-07 0.86J MW-21 22-May-08 0.0481J 0.201 MW-21 3-Apr-09 0.53J MW-21 20-May-10 MW-21 31-Mar-11 MW-22 16-Nov-04 MW-22 19-Apr-05 9.64 MW-22 8-Nov-05 MW-22 11-Apr-06 18.9 MW-22 7-Nov-06 MW-22 17-Apr-07 MW-22 6-Nov-07 MW-22 21-May-08 0.0415J 0.118J 0.0105J**0.0379J MW-22 3-Apr-09 MW-22 20-May-10 MW-22 31-Mar-11 MW-23 16-Nov-04 MW-23 19-Apr-05 MW-23 8-Nov-05 MW-23 11-Apr-06 MW-23 7-Nov-06 MW-23 17-Apr-07 MW-23 6-Nov-07 MW-23 21-May-08 0.0230J 0.0557J** MW-23 1-Apr-09 MW-23 20-May-10 MW-23 31-Mar-11 MW-24 16-Nov-04 MW-24 19-Apr-05 MW-24 8-Nov-05 MW-24 11-Apr-06 20.8 MW-24 7-Nov-06 MW-24 17-Apr-07 MW-24 6-Nov-07 0.073 MW-24 22-May-08 0.0693 0.1 0.0303J 0.0284J 0.114 MW-24 3-Apr-09 1.75 0.150J 0.0586J 0.0589J MW-24 21-May-10 MW-24 (dup)21-May-10 MW-24 1-Apr-11 MW-24 (dup)1-Apr-11 Page 19 of 21 June 2016 Table 4c Detected Groundwater Constituents - Pesticides, Herbicides, and PCBs Historical Results Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e 2, 4 - D 2, 4 , 5 - T P ( S i l v e x ) Alp h a - B H C Be t a - B H C De l t a - B H C Ga m m a - B H C ( L i n d a n e ) DD D 4,4 - D D T Die l d r i n Di n o s e b En d o s u l f a n I En d o s u l f a n I I En d r i n He p t a c h l o r E p o x i d e He p t a c h l o r Me t h o x y c h l o r 70 50 0.006*0.019*0.019*0.03 0.1 0.1 0.002 7*40 42*2 0.004 0.008 40 2 2 0.05 0.05 0.05 0.05 0.1 0.1 0.075 1 0.1 0.1 0.1 0.075 0.05 1Solid Waste Section Limit North Carolina 2L or Groundwater Protection Standard MW-25 16-Nov-04 MW-25 19-Apr-05 MW-25 8-Nov-05 MW-25 11-Apr-06 MW-25 7-Nov-06 MW-25 17-Apr-07 MW-25 6-Nov-07 MW-25 22-May-08 0.234 0.0466J 0.101 0.0452J 0.116 0.0141J MW-25 3-Apr-09 0.0113J 0.0202J MW-25 20-May-10 MW-25 31-Mar-11 MW-26 16-Nov-04 MW-26 19-Apr-05 MW-26 8-Nov-05 MW-26 11-Apr-06 MW-26 7-Nov-06 0.052 MW-26 17-Apr-07 MW-26 6-Nov-07 0.058 MW-26 21-May-08 0.0282J MW-26 3-Apr-09 0.176J 0.177J 0.438J MW-26 20-May-10 MW-26 31-Mar-11 MW-27 16-Nov-04 MW-27 19-Apr-05 MW-27 8-Nov-05 MW-27 11-Apr-06 MW-27 7-Nov-06 MW-27 17-Apr-07 MW-27 6-Nov-07 MW-27 21-May-08 0.0436J** MW-28 19-Apr-05 MW-28 8-Nov-05 MW-28 11-Apr-06 MW-28 7-Nov-06 MW-28 17-Apr-07 MW-28 6-Nov-07 MW-28 22-May-08 0.0484J** Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Groundwater Protection Standard 3. J - Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section reporting Limit. 4. B - Amount in prep blank > method detection limit 5. ** - Endosulfan I was also detected in the Method Blank and Equipment Blank at similar concentrations. 6. NS - Not Sampled; dup - Duplicate Sample - Concentration exceeds the 15A NCAC 02L .0202 or Groundwater Protection Standard - Indicates the result is below the detection limit Page 20 of 21 June 2016 Table 4d Detected Surface Water Constituents - Metals and Volatile Organic Compounds April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County An t i m o n y Ar s e n i c Ba r i u m Be r y l l i u m Ca d m i u m Ch r o m i u m Co b a l t Co p p e r Le a d Ni c k e l Se l e n i u m Sil v e r Va n a d i u m Zin c Ac e t o n e Ch l o r o m e t h a n e To l u e n e 640**10**200,000**6.5*0.15*24*4**2.7*0.54*16*5*0.06*NS 36*2,000*96**11* 6 10 100 1 1 10 10 10 10 50 10 10 25 10 100 1 1 SW-1 31-Mar-11 48.6J 1.11J 3.55J 3.02J 5.99J SW-1 8-Nov-11 43.3J 0.111J 2.90J 5.10J 4.98J SW-1 4-Apr-12 57.1J 3.18JB 1.84J SW-1 6-Nov-12 39.4J SW-1 14-May-13 60J 0.06J 0.4J 0.9J 1J 0.7J 0.8J 5JB SW-1 5-Nov-13 0.9J 50J 0.6J 3JB 0.7J 4JB SW-1 9-Apr-14 40J 0.9J 0.4J 2J 0.6J 0.8J 5J 7JB 8.1J SW-1 28-Oct-14 40J 0.4JB 0.4J 0.6J 0.6J SW-1 5-May-15 40J 0.4J 1J 0.2J 0.7J 3JB 0.73J SW-1 19-Nov-15 2J 70J 0.2J 0.5J 3J 2J 4J 3J 2J 1J 13J 16 SW-1 26-Apr-16 0.7J 40J 0.3J 1J 0.3J 0.6J 3J SW-2 30-Mar-11 86.1J 3.16J 1.24J 2.18J 16 SW-2 8-Nov-11 3.63J 55.8J 0.165J 3.42J 6.80J 12.3 SW-2 4-Apr-12 69.4J 2.66JB 2.04J 5.75J SW-2 6-Nov-12 3.37J 76.9J 2.30J 9.18J SW-2 14-May-13 1J 80J 0.1J 1J 2J 2J 2J 2J 3J 10B 0.21J SW-2 5-Nov-13 60J 0.1J 1J 0.6J 3JB 0.8J 1J 7J 11B SW-2 8-Apr-14 0.6J 50J 1J 0.6J 2J 1J 0.8J 6J 11B SW-2 27-Oct-14 30J 0.3JB 0.2J 1J 0.3J 5J SW-2 5-May-15 60J 0.2J 1J 0.8J 0.3J 0.7J 25 0.6J SW-2 18-Nov-15 0.2J 70J 0.04J 0.8J 0.5J 1J 0.3J 0.7J 1J 13 SW-2 25-Apr-16 SW-3 31-Mar-11 48.3J 1.10J 3.66J 2.05J 1.42J 3.42J 6.05J SW-3 8-Nov-11 3.99J 52.2J 0.141J 2.36J 3.50JB 8.01J 7.55J SW-3 4-Apr-12 46.7J 2.88JB SW-3 6-Nov-12 41.5J 1.62J SW-3 15-May-13 0.6J 40J 0.3J 0.8J 0.2J 0.5J 2JB SW-3 5-Nov-13 0.6J 40J 0.6J 0.4J 2JB 0.4J 1J 3J 6JB SW-3 8-Apr-14 50J 0.05J 1J 0.7J 2J 1J 1J 6J 10B SW-3 27-Oct-14 40J 0.4JB 0.5J 0.7J 0.2J 0.7J 2JB SW-3 5-May-15 0.8J 40J 0.3J 0.5J 1J 0.3J 0.7J 4JB 0.94J SW-3 18-Nov-15 50J 0.4J 0.6J 1J 0.2J 0.8J 3J SW-3 26-Apr-16 40J 0.3J 0.4J 1J 0.4J 0.7J 4JB Notes: 1. All units are in micrograms per liter (parts per billion). 2. * - Freshwater Aquatic Life Standard 3. ** - Human Health Standard 4. J - Indicates the analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section reporting limit 5. B - Amount in prep blank > method detection limit - Concentration exceeds the North Carolina 15A NCAC 02B Freshwater Aquatic Life or Human Health Standard for Class C Waters - Indicates the result is below the detection limit DRY Volatile Organic Compounds North Carolina 2B Freshwater Aquatic Life or Human Health Standard Solid Waste Section Limit Sa m p l e D a t e Su r f a c e W a t e r S a m p l e Co d e Metals Page 21 of 21 June 2016 Table 5 Constituents Detected Above Standards April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County MW-2 None Detected MW-4 None Detected MW-6 Cobalt*, 1,1-Dichloroethane MW-8 Chromium, Cobalt* MW-9 Barium, Cobalt*, Sodium*, 1,1-Dichloroethane, Vinyl Chloride MW-11 Cobalt* MW-12 Cobalt* MW-13 Cobalt*, Benzene MW-14 Cobalt* MW-15 Cobalt* MW-16 Arsenic, Cobalt*, Benzene, 1,1-Dichloroethane, Vinyl Chloride MW-17 Arsenic, Cobalt*, 1,1-Dichloroethane MW-18 Cobalt* MW-19 Cobalt* MW-20 Cobalt*, Vanadium* MW-21 Cobalt* MW-22 Cobalt* MW-23 Cobalt* MW-24 Cobalt* MW-25 Barium, Benzene MW-26 Cobalt*, Benzene MW-27 Arsenic, Cobalt*, 1,1-Dichloroethane MW-28 None Detected MW-29 Chromium, Cobalt*, Lead, Vanadium* Notes: 1. Bold - "J" value 2. (*) - Groundwater Protection Standard 3. TDS - Total Dissolved Solids APRIL 2016 PARAMETERS EXCEEDING THE NORTH CAROLINA 2L OR GROUNDWATER PROTECTION STANDARDMONITORING WELL CODE MW-10 Arsenic, Barium, Cobalt*, Sodium*, TDS, Benzene, 1,1-Dichloroethane, 1,2-Dichlorothane, Vinyl Chloride Page 1 of 1 June 2016 Table 6 Geochemical Data April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ox i d a t i o n R e d u c t i o n P o t e n t i a l (m V ) pH Di s s o l v e d O x y g e n Bi o c h e m i c a l O x y g e n D e m a n d Ch e m i c a l O x y g e n D e m a n d Me t h a n e ( u g / l ) Et h a n e ( u g / l ) Et h e n e ( u g / l ) Ch l o r i d e Nit r a t e Su l f a t e Su l f i d e To t a l O r g a n i c C a r b o n Al k a l i n i t y ( C a C O 3 ) Ca r b o n D i o x i d e Fe r r o u s I r o n Ac e t i c A c i d Bu t y r i c A c i d La c t i c A c i d Pr o p i o n i c A c i d Py r u v i c A c i d Di s s o l v e d H y d r o g e n ( n M ) NS NS NS NS NS NS NS NS NS 10,000 250,000 1,000 NS NS NS NS NS NS NS NS NS NS MW-2 31-Mar-11 154.5 6.82 3.52 <2 77 <0.49 <1.5 <1.6 560 0.084J 30J <0.01 4.4 160 5.1 0.095 <0.083 <0.16 <0.44 <0.18 <0.14 -- MW-2 8-Nov-11 298.0 9.11 6.63 <2 100 0.969J <1 <2.3 1,200BD 0.87J 19J <0.01 7.4 260D 27.3 0.040 0.98 <0.024 <0.062 <0.057 <0.061 -- MW-2 4-Apr-12 211.8 6.73 8.20 <2 67 <0.72 <1 <2.3 450BD 0.47J 33JB <0.01 2.1 150D 8.7 0.052 <0.04 <0.024 <0.062 <0.057 <0.061 -- MW-2 6-Nov-12 41.4 6.85 6.12 <2 180 <0.43 <0.2 <0.54 1,200BD 0.85J 23J <0.01 6.4 230D 29.3 <0.046 <0.031 <0.031 <0.095 <0.063 <0.010 -- MW-2 15-May-13 109.7 7.02 6.94 <4 22 <0.3 <0.061 <0.069 462 0.14J 35.2 <0.4 2.6 152 5.2 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 6-Nov-13 21.2 7.46 8.19 <4 46 0.34J <0.061 <0.069 834 0.54 32.5 <0.4 2.7 215 12 1.1*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 9-Apr-14 124.1 6.76 7.71 <2 52 <0.3 <0.061 <0.069 589 0.22 32.5 <0.4 5.1 162 8 0.0*1.40 <1.0 <0.50 <0.50 <0.25 -- MW-2 28-Oct-14 59.3 6.63 6.08 <4 430 <0.3 <0.061 <0.069 1,040 0.47 26.4 <0.4 5.7 232 13.0 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 5-May-15 69.1 6.75 6.01 <2 25 <0.3 <0.061 <0.069 785 0.9J 30.9 <0.4 4.3 175 6.0 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-2 19-Nov-15 130.2 6.89 6.60 <2.0 169 <0.30 <0.061 <0.069 1,480 0.8J 17.7 <0.4 12.5 274 19 0.0*<0.50 <1.0 <0.50 <0.50 <0.020 -- MW-2 26-Apr-16 93.0 7.31 7.50 <2.0 42 <0.30 <0.061 <0.069 756 0.24 26.1 <0.4 7.1 180 8.3 0.0*<0.50 <1.0 <0.50 <0.50 <0.020 -- MW-8 30-Mar-11 129.6 6.27 1.16 <2 <10 49.1 <1.5 <1.6 4.9J 0.08J 2.8J <0.01 1.1 180 507D <0.037 <0.083 <0.16 <0.44 <0.18 <0.14 2.1 MW-8 7-Nov-11 161.7 6.08 2.09 <2 <10 4.5 <1 <2.3 4.1JB 0.33J 2.4J <0.01 <0.28 120 62.2 0.033 1.1 <0.024 0.19 0.28 <0.061 1.0 MW-8 4-Apr-12 167.8 6.59 1.65 <2 <10 1,430D <1 <2.3 4.7JB 0.27J 2.2JB <0.01 0.54J 120 90.5 0.056 <0.04 <0.024 0.082 <0.057 <0.061 7.5 MW-8 19-Jul-12 -43.5 6.36 0.21 <2 21 7.32 <0.2 <0.54 4.1J 0.2*7*----144*182*2.4*3.4 <0.31 0.330 2.50 <0.01 -- MW-8 16-Aug-12 -56.1 5.85 0.59 <2 17 26.7 <0.2 <0.54 4.1J 0.3*1*----190*186*1.6*------------ MW-8 6-Nov-12 -63.4 6.31 0.93 <2 17 96.5D <0.2 <0.54 5.3B 0.7*2.40J <0.01 1.6 150 40.6 1.0*0.56 <0.031 <0.095 0.37 <0.010 4.5 MW-8 15-May-13 -59.4 5.12 1.43 34.7 20J 110.0 0.17J 0.35J 5.55 <0.03 0.63 <0.4 3.8 155 22 3.5*3.0 <1.0 <0.50 0.96J <0.25 64 MW-8 31-Jul-13 -33.8 7.12 0.96 --30 3,000 1.6 1.4 4.85 <0.03 0.52 ----191 15 2.8*23.0 <1.0 <0.50 <0.50 <0.25 -- MW-8 6-Nov-13 -81.4 7.27 0.81 <2 <16 600 <0.061 0.17J 4.15 <0.03 0.51 <0.4 0.5J 152 17 1.2*<0.50 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 16-Jan-14 -94.8 7.09 0.49 --<16 1,400 0.14J 0.10J 4.37 <0.03 0.48J ----168 18 0.8*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-8 10-Apr-14 -77.7 7.08 1.53 47.2 <16 200 <0.061 <0.069 4.9 0.15J 0.7J <0.4 1.9 154 12 0.0*1.9 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 29-Oct-14 -76.4 5.90 0.78 <4 <5 110 <0.061 0.10J 5.10 <0.03 1.1 <0.4 0.4J 138 23 0.5*<0.50 <1.0 <0.50 <0.50 <0.25 1.6 MW-8 7-May-15 -78.3 6.57 0.89 16.5 <16 210 <0.061 <0.069 5.70 <0.03 4.2B <0.4 1.0J 165 9.6 3.0*<0.50 <1.0 <0.50 <0.50 <0.25 18.0 MW-8 19-Nov-15 -7.9 6.18 2.79 3.1 <16 32 0.23 <0.069 5.3 0.09J 1.4 <0.4 0.5J 120 19 0.5*<0.50 <1.0 <0.50 <0.50 <0.020 12 MW-8 26-Apr-16 -40.8 7.13 1.45 <2.0 14J 890 0.31J <0.069 5.2 0.06J 1.3 <0.4 0.6J 141 12 3.0*<0.50 <1.0 <0.50 <0.50 <0.020 2.8 Solid Waste Section Limit Page 1 of 5 June 2016 Table 6 Geochemical Data April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ox i d a t i o n R e d u c t i o n P o t e n t i a l (m V ) pH Di s s o l v e d O x y g e n Bi o c h e m i c a l O x y g e n D e m a n d Ch e m i c a l O x y g e n D e m a n d Me t h a n e ( u g / l ) Et h a n e ( u g / l ) Et h e n e ( u g / l ) Ch l o r i d e Nit r a t e Su l f a t e Su l f i d e To t a l O r g a n i c C a r b o n Al k a l i n i t y ( C a C O 3 ) Ca r b o n D i o x i d e Fe r r o u s I r o n Ac e t i c A c i d Bu t y r i c A c i d La c t i c A c i d Pr o p i o n i c A c i d Py r u v i c A c i d Di s s o l v e d H y d r o g e n ( n M ) NS NS NS NS NS NS NS NS NS 10,000 250,000 1,000 NS NS NS NS NS NS NS NS NS NSSolid Waste Section Limit MW-9 30-Mar-11 51.8 6.08 0.90 <2 <10 29.1 <1.5 <1.6 9.9 7.0J 2.9J <0.01 1.0 210 219 0.078 <0.083 <0.16 <0.44 <0.18 <0.14 2.0 MW-9 7-Nov-11 1.1 6.11 1.21 <2 <10 174D <1 <2.3 9.9B 0.12J 2.9J <0.01 0.43J 200D 315D 0.10 1.4 <0.024 0.34 0.27 <0.061 1.6 MW-9 4-Apr-12 148.8 6.41 2.71 <2 29 310D <1 <2.3 12B 0.061J 2.8JB <0.01 0.80J 210D 342D 0.21 <0.04 <0.024 <0.062 0.12 <0.061 8.2 MW-9 19-Jul-12 -99.8 6.40 0.18 <2 690 602D <0.2 <0.54 17 0*6*----506*440*9.8*230 110 22 76 <0.01 -- MW-9 16-Aug-12 -112.9 6.31 0.58 <2 440 5,330D 1.24J 2.34J 15 1.5*9*----408*368*10.0*------------ MW-9 6-Nov-12 -109.6 6.36 1.06 >73 930 6,190D 1.04J 2.26J 23B 2.1*2.30J <0.01 310D 650D 88.1 3.8*230 180 <0.095 120 <0.01 39 MW-9 15-May-13 -71.4 5.72 1.27 198 961 4,400 2.2 1.7 36.8 <0.03 0.58 <1.6 163 312 71 7.8*71 8 <0.50 17 <0.25 11 MW-9 31-Jul-13 -55.2 6.49 1.21 --156 6,200 0.58J 0.16J 32.1 <0.03 0.57 ----367 220 11.3*30 2.9 <0.50 9.3 <0.25 -- MW-9 6-Nov-13 -52.2 6.49 0.89 58.7 125 8,600 0.96 0.40J 27.7 <0.03 0.53 <0.4 32.3 348 120 9.5*54 <1.0 <0.50 3.6 <0.25 9.8 MW-9 16-Jan-14 -128.5 6.40 0.28 --63 5,100 0.27J <0.069 24.2 <0.03 0.53 ----388 210 3.0*6.8 <1.0 <0.50 <0.50 <0.25 -- MW-9 10-Apr-14 -29.1 6.63 0.93 51.7 88 12,000 1.10 0.31J 25.4 <0.03 0.5J <0.4 16.8 325 110 3.5*32.0 <1.0 <0.50 <0.50 <0.25 4.0 MW-9 29-Oct-14 -90.3 5.40 1.39 25.3 72 9,700 1.1 0.21J 25.9 0.09J 0.8J <0.4 15.1 308 79 2.0*21 <1.0 <0.50 <0.50 <0.25 -- MW-9 7-May-15 -81.7 6.34 1.13 18.1 29 11,000 2.2 0.60J 28.9 <0.03 0.8BJ <0.4 8.7 374 62 1.0*10 <1.0 <0.50 <0.50 <0.25 7.8 MW-9 20-Nov-15 -51.4 6.18 1.97 9.5 24 6,400 0.93 <0.069 27.9 <0.03 0.6J <1.6 7.2 349 62 4.0*7.0 <1.0 <0.50 <0.50 <0.020 16 MW-9 27-Apr-16 -47.4 6.86 0.96 14.0 32 6,000 1.1 0.18J 31.1 <0.04 0.5J <0.8 7.1 325 72 3.0*8.4 <1.0 <0.50 <0.50 <0.020 5.1 MW-10 30-Mar-11 -33.1 5.81 1.29 <2 60 1,950 <1.5 <1.6 100 0.063J 12J <0.01 16 250 478 5.7 6.0 <0.16 <0.44 0.52 <0.14 2.0 MW-10 7-Nov-11 -76.5 5.82 1.29 <2 38 2,540D <1 <2.3 77B 0.052J 5.9J <0.01 8.9 250D 509D 1.1 <0.40 <0.024 <0.062 5.3 <0.061 0.92 MW-10 4-Apr-12 84.8 6.05 1.18 4.5 80 6,540D <1 <2.3 130BD 0.069J 11JB 0.17J 13 270D 653D 5.3 <0.04 <0.024 <0.062 8.8 <0.061 3.5 MW-10 19-Jul-12 -96.7 5.93 0.63 <2 13,000 1,590D <0.2 4.89 150 5*90*----1,650*2,080*30*1500 2000 220 1800 4.2 -- MW-10 16-Aug-12 -54.6 5.85 0.36 <2 13,000 1,470D <0.2 1.76J 140 4*30*----1,860*2,140*36*------------ MW-10 6-Nov-12 -48.6 5.74 1.15 >220 2,100 16,200D <0.2 <0.54 67B 4.6*61*<0.01 660D 1,800 442 12*210 45 <0.095 630D 0.43 4.2 MW-10 15-May-13 -54.9 5.65 1.28 195 1,250 4,200 0.22J 0.13J 63.1 0.03J 0.56 1.0J 597 729 340 17.2*120 33 1.1 86 <0.25 11 MW-10 31-Jul-13 -84.7 6.39 2.08 --265 5,300 0.098J 0.11J 108 <0.03 0.77 ----487 350 48.2*3.4 4.0 <0.50 <0.50 0.26J -- MW-10 6-Nov-13 -59.4 6.69 1.94 19.1 118 6,500 0.25J <0.069 77.6 0.15J 0.54 <0.4 30.6 662 300 8.2*4.4 <1.0 <0.50 <0.50 <0.25 3.4 MW-10 16-Jan-14 -114.4 6.16 0.31 --116 6,800 <0.061 0.08J 81.4 <0.03 1.95 ----308 400 1.75*<0.50 <1.0 <0.50 <0.50 0.41L -- MW-10 10-Apr-14 -38.5 6.15 2.19 12.7 59 7,600 0.13J 0.26J 78.9 <0.03 3.6 0.4J 14.7 226 400 2.5*<0.50 <1.0 <0.50 <0.50 <0.25 1.0 MW-10 29-Oct-14 -90.0 5.35 0.92 12.8 104 5,400 0.43J <0.069 93.7 0.08J 1.6 <0.4 16.8 505 240 2.5*1.0 <1.0 1.0 <0.50 0.29J 1.40 MW-10 7-May-15 -67.7 5.79 1.19 5.9 78 2,300 0.27J 0.32J 180.0 <0.03 7.3B <0.4 22.6 421 290 3.0*<0.50 <1.0 <0.50 <0.50 0.61 1.90 MW-10 20-Nov-15 -29.5 6.01 3.61 4.4 105 840 <0.061 <0.069 144 <0.3 9J <0.4 24.2 457 210 3.0*1.1 <1.0 <0.50 <0.50 <0.020 13 MW-10 27-Apr-16 -36.5 6.20 2.07 6.8 97 710 <0.061 <0.069 207 <0.04 13.2 <0.4 23.5 444 240 5.5*0.52J <1.0 <0.50 <0.50 1.0 2.8 Page 2 of 5 June 2016 Table 6 Geochemical Data April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ox i d a t i o n R e d u c t i o n P o t e n t i a l (m V ) pH Di s s o l v e d O x y g e n Bi o c h e m i c a l O x y g e n D e m a n d Ch e m i c a l O x y g e n D e m a n d Me t h a n e ( u g / l ) Et h a n e ( u g / l ) Et h e n e ( u g / l ) Ch l o r i d e Nit r a t e Su l f a t e Su l f i d e To t a l O r g a n i c C a r b o n Al k a l i n i t y ( C a C O 3 ) Ca r b o n D i o x i d e Fe r r o u s I r o n Ac e t i c A c i d Bu t y r i c A c i d La c t i c A c i d Pr o p i o n i c A c i d Py r u v i c A c i d Di s s o l v e d H y d r o g e n ( n M ) NS NS NS NS NS NS NS NS NS 10,000 250,000 1,000 NS NS NS NS NS NS NS NS NS NSSolid Waste Section Limit MW-12 31-Mar-11 130.6 6.62 1.49 <2 28 14.4 <1.5 <1.6 290 <0.025 14J <0.01 7.1 700 196 <0.037 11.0 1.10 <0.44 <0.18 <0.14 2.3 MW-12 8-Nov-11 -42.9 6.98 1.94 <2 23 45.1 <1 <2.3 160BD <0.025 12J <0.01 2.4 280D 69.9 <0.030 0.67 <0.024 <0.062 0.56 <0.061 0.88 MW-12 3-Apr-12 148.5 6.86 2.23 <2 34 20.2 <1 <2.3 240BD 0.045J 12JB <0.01 3.4 540D 177D 0.049 <0.04 <0.024 <0.062 0.87 <0.061 6.9 MW-12 5-Nov-12 -65.4 7.09 1.14 <2 17 26.7 <0.2 <0.54 150BD <0.025 11J <0.01 2.2 240D 66.7 <0.031 <0.031 <0.031 <0.095 0.24 <0.010 5.1 MW-12 15-May-13 1.7 6.25 1.75 <4 <16 6.9 <0.061 <0.069 223 0.18J 10.7 <0.4 4.6 523 110 0.0*<0.50 1.5J <0.50 <0.50 <0.25 0.74 MW-12 6-Nov-13 -19.7 7.09 1.25 <2 <16 13 <0.061 <0.069 179 <0.03 11.4 <0.4 2.8 351 60 1.0*<0.50 <1.0 <0.50 <0.50 <0.25 0.99 MW-12 10-Apr-14 14.9 6.99 3.33 <2 19J 4 <0.061 <0.069 258 0.17J 14.7 <0.4 5 651 140 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 0.89 MW-12 28-Oct-14 -42.4 5.81 0.91 <4 21 10.0 <0.061 <0.069 184 <0.03 13.3 <0.4 2.0 401 42 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 0.74 MW-12 6-May-15 4.1 6.73 1.18 <2 19J 22.0 <0.061 <0.069 245 <0.03 18.6 <0.4 5.5 736 120 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 2.60 MW-12 20-Nov-15 -23.2 6.68 6.11 <2.0 <16 3.6 <0.061 <0.069 169 <0.2 7.6 <1.6 3.3 288 24 0.5*2.4 <1.0 <0.50 <0.50 <0.020 29 MW-12 27-Apr-16 -44.0 7.02 6.36 <2.0 32 7.3 <0.061 <0.069 238 <0.08 21.0 0.8J 6.4 699 96 1.0*<0.50 <1.0 0.56J <0.50 <0.020 2.5 MW-13 20-May-10 74.4 6.14 1.69 <2 5 597 <0.4 <0.4 58 <0.025 4J <0.031 3.8 200 348 0.509 <0.083 <0.16 2.4 0.56 <0.14 1.2 MW-13 2-Nov-10 89.8 6.02 0.98 <2 20 418 <1.5 <1.6 63 <0.025 4.9J <0.01 4.8 220 365 0.13 <0.083 <0.16 <0.44 <0.18 <0.14 5.6 MW-13 31-Mar-11 99.9 5.70 1.58 <2 19 1,300 <1.5 <1.6 61 <0.025 5.5J <0.01 5.9 210 498 0.44 <0.083 <0.16 <0.44 <0.18 <0.14 2.2 MW-13 8-Nov-11 -20.4 5.76 3.81 <2 38 3,150D <1 <2.3 49B 0.170J 7.2J <0.01 8.6 250D 737D 0.16 0.72 <0.024 <0.062 <0.057 <0.061 0.96 MW-13 3-Apr-12 200.9 5.93 1.28 <2 48 2,260D <1 <2.3 45B 0.050J 8.7JB <0.01 6.0 250D 559D 0.47 <0.04 <0.024 <0.062 <0.057 <0.061 7.0 MW-13 5-Nov-12 50.7 5.84 1.07 <2 28 1,050D <0.2 <0.54 61B <0.025 6.80J <0.01 4.9 230D 993D <0.046 <0.031 <0.031 2.70 0.23 <0.010 5.7 MW-13 16-May-13 48.3 5.73 1.41 <4 27 410 <0.061 <0.069 48.4 0.14J 7.25 <0.4 5.8 237 450 0.7*<0.5 <1.0 <0.50 <0.50 <0.25 0.61 MW-13 7-Nov-13 35.2 5.92 1.24 <2 <16 190 <0.061 <0.069 66.0 0.18J 5.12 <0.4 3.3 253 550 0.2*<0.5 <1.0 <0.50 <0.50 <0.25 1.0 MW-13 10-Apr-14 90.4 5.94 2.64 <2 30 430 <0.061 <0.069 35.6 0.29 7 <0.4 7.1 178 --0.5*<0.5 <1.0 <0.50 <0.50 <0.25 2.0 MW-13 28-Oct-14 70.5 5.17 0.74 <4 33 150 <0.061 <0.069 47.9 0.14J 8.5 <0.4 5.3 263 350 0.0*<0.5 <1.0 <0.50 <0.50 <0.25 1 MW-13 6-May-15 42.5 5.10 1.09 <2 <16 270 <0.061 <0.069 39.3 0.12J 9.2B <0.4 6.7 197 300 0.0*<0.5 <1.0 <0.50 <0.50 <0.25 6 MW-13 20-Nov-15 119.4 5.49 6.40 <2.0 <16 100 <0.061 <0.069 32.7 0.37 6.3 <0.4 7.5 162 190 0.5*<0.50 <1.0 <0.50 <0.50 <0.020 22 MW-13 27-Apr-16 107.5 5.76 4.24 <2.0 20J 68 <0.061 <0.069 44.0 <0.04 8.8 <0.4 5.7 200 240 0.5*<0.50 <1.0 <0.50 <0.50 <0.020 2.8 Page 3 of 5 June 2016 Table 6 Geochemical Data April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ox i d a t i o n R e d u c t i o n P o t e n t i a l (m V ) pH Di s s o l v e d O x y g e n Bi o c h e m i c a l O x y g e n D e m a n d Ch e m i c a l O x y g e n D e m a n d Me t h a n e ( u g / l ) Et h a n e ( u g / l ) Et h e n e ( u g / l ) Ch l o r i d e Nit r a t e Su l f a t e Su l f i d e To t a l O r g a n i c C a r b o n Al k a l i n i t y ( C a C O 3 ) Ca r b o n D i o x i d e Fe r r o u s I r o n Ac e t i c A c i d Bu t y r i c A c i d La c t i c A c i d Pr o p i o n i c A c i d Py r u v i c A c i d Di s s o l v e d H y d r o g e n ( n M ) NS NS NS NS NS NS NS NS NS 10,000 250,000 1,000 NS NS NS NS NS NS NS NS NS NSSolid Waste Section Limit MW-14 30-Mar-11 108.1 6.69 2.25 <2 <10 0.57J <1.5 <1.6 6.7 0.76J 4.1J <0.01 0.6J 83 20.6 <0.037 <0.083 <0.16 <0.44 <0.18 <0.14 4.5 MW-14 7-Nov-11 18.2 6.78 1.06 6.7 25 299D <1 <2.3 11B 0.036J 4.8J 0.065J 5.5 70 <1.3 0.040 1.5 <0.024 0.069J <0.057 <0.061 0.95 MW-14 3-Apr-12 174.2 6.57 1.04 <2 19 282D <1 <2.3 62B <0.025 3.9JB <0.01 1.8 220D 170D 0.042 <0.04 <0.024 <0.062 0.19 <0.061 9.1 MW-14 5-Nov-12 -78.2 6.40 1.78 4 39 838D <0.2 1.19J 55B <0.025 4.6J 0.20J 8.1 120D 13.8 <0.046 <0.031 <0.031 2.30 1.30 <0.010 6.1 MW-14 16-May-13 30.6 6.18 1.11 2.9 <16 7.6 <0.061 <0.069 38.5 <0.03 4.22 <0.4 3.3 140 52 0.8*<0.50 <1.0 <0.50 <0.50 <0.25 5.1 MW-14 7-Nov-13 12.2 6.64 1.55 <4 <16 8.3 <0.061 <0.069 23.4 <0.03 3.09 <0.4 0.7J 173 93 0.0*<0.5 <1.0 <0.50 <0.50 <0.25 1.4 MW-14 10-Apr-14 36.8 6.47 2.25 <2 <16 23.0 <0.061 <0.069 25.7 0.16J 3.9 <0.4 1.6 158 --0.0*<0.5 <1.0 <0.50 <0.50 <0.25 2.8 MW-14 28-Oct-14 -7.1 5.64 0.77 5.2 <16 790 0.23J 1.0J 65.1 <0.03 1.8 0.6JB 4.8 225 56 0.5*<0.5 <1.0 <0.50 <0.50 <0.25 1.1 MW-14 6-May-15 -27.6 6.22 0.91 <2 <16 17 <0.061 <0.069 68.3 0.08J 3.6B <0.4 3.1 214 23 0.5*<0.5 <1.0 <0.50 <0.50 <0.25 4.6 MW-14 20-Nov-15 86.5 5.28 4.49 9.6 <16 730 0.14 0.52 77.7 <0.03 2.6 0.7J 7.2 212 53 0.5*1.0 <1.0 <0.50 <0.50 <0.020 31 MW-14 27-Apr-16 43.6 6.27 1.61 <2.0 <12 130 <0.061 <0.069 87.7 <0.04 4.5 0.4J 2.4 245 49 0.5*<0.50 <1.0 <0.50 <0.50 <0.020 23 MW-19 5-Apr-12 203.3 7.12 1.15 --<1 ---------------------------------- MW-19 19-Jul-12 -64.2 7.19 0.28 --<1 <0.43 <0.2 <0.54 15 0.2*2*----154*108*0.4*<0.031 <0.031 0.098J <0.063 0.022J -- MW-19 16-Aug-12 -18.4 6.80 0.27 --<10 <0.43 <0.2 <0.54 15 3.7*2*----140*120*0.2*------------ MW-19 6-Nov-12 -21.5 6.71 1.41 --17 7.27 <0.2 1.96J 13 4.1*11*----170*140*0.4*------------ MW-19 16-May-13 2.4 6.60 1.08 189 320 33 0.58J 0.41J 17 <0.03 0.79 1.7J 17.6 148 45 0.4*15 2.4 <0.50 4.9 <0.25 -- MW-19 31-Jul-13 -107.8 6.81 1.21 --29 1,200 0.30J 0.69J 21.4 <0.03 1.83 ----161 23 1.3*17 <1.0 <0.50 1.1 <0.25 -- MW-19 7-Nov-13 -32.8 7.65 1.19 <2 <16 1,200 1.1 0.084J 19.7 0.17J 2.99 <0.4 0.2J 157 110 0.5*<0.5 <1.0 <0.50 <0.50 <0.25 -- MW-19 16-Jan-14 -141.9 7.54 0.36 --<16 64 <0.061 <0.069 21.2 <0.03 3.18 ----162 6.9 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-19 9-Apr-14 -74.8 7.19 1.24 <2 29 1,800 0.14J 0.093J 4.6 <0.03 4.9 ----128 76 0.0*1.1 <1.0 <0.50 <0.50 <0.25 -- MW-19 29-Oct-14 -31.2 6.63 1.31 <4 19J 730 0.55J 1.60 8.9 <0.03 4.3 0.4JB 1.5 124 54 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-19 7-May-15 -22.4 7.21 1.38 3.9 <16 95 <0.061 <0.069 4.1 0.08J 7.0B <0.4 1.6 106 46 0.0*<0.50 <1.0 <0.50 <0.50 <0.25 18.0 MW-19 20-Nov-15 194.9 7.51 1.50 <2.0 <16 24 <0.061 <0.069 5.8 <0.03 5.0 <0.4 1.8 87.5 55 1.5*<0.50 <1.0 <0.50 <0.50 <0.020 12 MW-19 26-Apr-16 21.1 7.69 1.94 <2.0 15J 12 <0.061 <0.069 8.5 0.05J 6.7 <0.4 1.5 83.5 62 1.5*<0.50 <1.0 <0.50 <0.50 <0.020 260 Page 4 of 5 June 2016 Table 6 Geochemical Data April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County Mo n i t o r i n g W e l l C o d e Sa m p l e D a t e Ox i d a t i o n R e d u c t i o n P o t e n t i a l (m V ) pH Di s s o l v e d O x y g e n Bi o c h e m i c a l O x y g e n D e m a n d Ch e m i c a l O x y g e n D e m a n d Me t h a n e ( u g / l ) Et h a n e ( u g / l ) Et h e n e ( u g / l ) Ch l o r i d e Nit r a t e Su l f a t e Su l f i d e To t a l O r g a n i c C a r b o n Al k a l i n i t y ( C a C O 3 ) Ca r b o n D i o x i d e Fe r r o u s I r o n Ac e t i c A c i d Bu t y r i c A c i d La c t i c A c i d Pr o p i o n i c A c i d Py r u v i c A c i d Di s s o l v e d H y d r o g e n ( n M ) NS NS NS NS NS NS NS NS NS 10,000 250,000 1,000 NS NS NS NS NS NS NS NS NS NSSolid Waste Section Limit MW-29 5-Apr-12 113.4 6.54 0.83 --360 221D <1 <2.3 10B 1.9*6.0*----84*268*5.8*------------ MW-29 19-Jul-12 -102.8 6.46 0.18 --27 464D <0.2 <0.54 15 0.8*8*----220*292*4.2*4.5 <0.031 <0.095 1.80 <0.010 -- MW-29 16-Aug-12 -6.4 6.57 0.48 --17 219D <0.2 <0.54 14 2.6*4*----162*204*2.2*------------ MW-29 6-Nov-12 1.6 6.42 1.47 --37 59.8 <0.2 <0.54 13 9.2*14*----208*288*2.4*------------ MW-29 16-May-13 -1.4 5.49 0.98 154 620 300 <0.061 0.41J 11.1 <0.03 1.45 8.0 33.8 220 110 10.2*48 1.8J <0.50 21 <0.25 -- MW-29 31-Jul-13 -54.2 6.40 1.85 --81 3,000 0.41J 0.34J 14.0 <0.03 0.73 ----242 140 11.7*26 <1.0 <0.50 9.1 <0.25 -- MW-29 7-Nov-13 -42.4 6.74 1.21 5.7 55 4,300 0.064J 0.071J 17.6 <0.03 1.18 0.9J 15 301 6.6 9.8*3 <1.0 <0.50 <0.50 <0.25 -- MW-29 16-Jan-14 -119.2 5.65 0.47 --99 2,400 <0.061 <0.069 5.23 <0.03 7.67 ----49.1 50 1.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-29 9-Apr-14 -23.7 5.63 0.89 13.4 86 4,500 0.098J 0.098J 6.30 <0.03 4.4 ----107 79 1.0*<0.50 <1.0 <0.50 <0.50 <0.25 -- MW-29 29-Oct-14 -95.6 6.38 0.41 <70 54 2,700 <0.061 <0.069 11.80 <0.03 2.5 0.8JB 18.6 173 57 1.0*<0.50 <1.0 <0.50 <0.50 <0.25 1.0 MW-29 7-May-15 -39.1 5.72 1.88 5.6 48 120 <0.061 <0.069 8.1 <0.03 4.0B <0.4 8 94 56 0.5*<0.50 <1.0 <0.50 <0.50 <0.25 1.8 MW-29 20-Nov-15 76.7 5.49 2.71 2.1 74 2 <0.061 <0.069 7.0 <0.03 5.0 1.6J 14.4 34.3 32 3.0*<0.50 <1.0 <0.50 <0.50 <0.020 13 MW-29 27-Apr-16 -45.9 6.07 1.94 2.5 54 58 <0.061 <0.069 8.3 <0.04 2.3 <0.8 11.7 58.6 65 2.5*<0.50 <1.0 <0.50 <0.50 <0.020 2.6 Notes: 1. All units are in milligrams per liter (parts per million), unless otherwise noted. 2. ug/L - micrograms per liter 3. -- Not analyzed for 4. J - The analytical result is an estimated concentration between the laboratory method detection limit and the Solid Waste Section reporting limit. 5. D - The sample was analyzed at dilution. 6. B - The analyte was detected in the associated method blank. 7. mV - millivolt 8. nM - nanomoles per liter 9. * - Field analysis performed using a HACH kit. - A sodium lactate injection was performed near MW-8, -9, and -10 on June 18-21, 2012. - An emulsified vegetable oil injection was performed near MW-8, -9, and -10 on March 25-27, 2013. Page 5 of 5 June 2016 2 6 0 2 6 0 Figure 1: Potentiometric Surface Map 27 9 . 3 0 27 7 . 2 5 28 6 . 9 0 27 7 . 1 6 292.28298.96 29 2 . 3 2 292.35337.49 28 8 . 2 6 302.15 27 6 . 4 3 27 6 . 1 1 27 6 . 1 6 27 7 . 2 5 27 6 . 3 3 27 6 . 3 8 27 6 . 5 1 28 4 . 3 9 28 6 . 5 9 27 4 . 5 3 32 2 . 4 6 28 7 . 6 4 3 0 0 2 7 0 330320320330310 310 300300290 2 8 0 2 8 0 2 7 0 2 6 0 2 7 0 2 8 0 2 8 0 2 9 0 2 9 0 Fe l t o n s v i l l e C l o s e d Landfill LEGEND Groundwater Monitoring Well Surface Water Sample Location Potentiometric Contour 2 9 0 Notes:1. Groundwater elevations were measured on April 25 , 2016.2. Potentiometric contours are derived from previou s site investigations and adjusted based on the recent groundwater elevat ions. Ma p D a t a S o u r c e : F e b r u a r y 2 0 1 0 A e r i a l P h o t o g r a p h , W ak e C o u n t y , N o r t h C a r o l i n a O n e M a p Diabase Dike Location Inferred from Geophysical Data Width 31 feet/Depth 30 feet Di a b a s e D i k e Ol d C l o s e d Ce l l Ol d C l o s e d Ce l l 8 0 Ol d C l o s e d Ce l l (dashed where inferred) In j e c t i o n Ar e a 299.34 2 9 0 276.75 Groundwater Elevation 0 2 0 0 4 0 0 6 0 0 8 0 0 3 1 0 3 2 0 3 2 0 Figure 2 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 1 2 3 4 5 6 7 8 To t a l d e t e c t e d V O C ( p p b ) Date MW-12 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 3 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 5 10 15 20 25 30 To t a l d e t e c t e d V O C ( p p b ) Date MW-13 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 4 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 2 4 6 8 10 12 To t a l d e t e c t e d V O C ( p p b ) Date MW-14 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 5 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 2 4 6 8 10 12 14 16 18 To t a l d e t e c t e d V O C ( p p b ) Date MW-15 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 6 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 5 10 15 20 25 30 35 To t a l d e t e c t e d V O C ( p p b ) Date MW-16 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 7 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 20 40 60 80 100 120 140 160 To t a l d e t e c t e d V O C ( p p b ) Date MW-8 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n J u n e 2 0 1 2 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n M a r c h 20 1 3 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 8 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 20 40 60 80 100 120 140 160 180 To t a l d e t e c t e d V O C ( p p b ) Date MW-9 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n J u n e 2 0 1 2 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n M a r c h 20 1 3 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 9 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 100 200 300 400 500 600 To t a l d e t e c t e d V O C ( p p b ) Date MW-10 Total Detected VOCs MS W C l o s e d 1 9 9 8 C& D C l o s e d 2 0 0 5 LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n J u n e 2 0 1 2 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n M a r c h 20 1 3 Note:Acetone was omitted as it is a common laboratory contaminant. Figure 10 April 2016 Semi-Annual Sampling Event Feltonsville Landfill - Wake County 0 5 10 15 20 25 30 35 To t a l d e t e c t e d V O C ( p p b ) Date MW-29 Total Detected VOCs LF G R e c o v e r y Sy s t e m o n -li n e 2 0 1 1 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n J u n e 2 0 1 2 In s i t u b i o r e m e d i a t i o n i m p l e m e n t a t i o n M a r c h 20 1 3 Note:Acetone was omitted as it is a common laboratory contaminant. Appendix A Analytical Data May 12, 2016 Service Request No:J1603049 Daniel Forbes CDM Smith, Inc. 5400 Gleenwood Ave, Suite 400 Raleigh, NC 27612 All analyses were performed according to our laboratory’s quality assurance program. The test results meet requirements of the NELAP standards except as noted in the case narrative report. All results are intended to be considered in their entirety, and ALS Environmental is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any quantitative analysis will be supplied upon request. For your reference, these analyses have been assigned our service request number Enclosed are the results of the sample(s) submitted to our laboratory Laboratory Results for:Feltonsville Landfill Dear Daniel, April 28, 2016 J1603049. Please contact me if you have any questions. My extension is 4410. You may also contact me via email at Jerry.Allen@alsglobal.com. Respectfully submitted, ALS Group USA, Corp. dba ALS Environmental Jerry Allen Project Manager dba ALS Environmental ALS Group USA, Corp. ADDRESS FAXPHONE 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 +1 904 739 2011+1 904 739 2277 | Page 1 of 141 CLIENT ID:MW-2 Lab ID:J1603049-001 Analyte Results Flag MDL PQL Units Method Chloride 756 0.8 10 mg/L 300.0 Nitrate as Nitrogen 0.24 0.04 0.20 mg/L 300.0 Sulfate 26.1 0.06 1.0 mg/L 300.0 Barium, Total 250 0.3 100 ug/L 6010C Zinc, Total 20 J 20 100 ug/L 6020A Chloroform 2.3 J 0.35 5.0 ug/L 8260B Alkalinity as CaCO3, Total 180 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 180 5.0 5.0 mg/L SM 2320 B Carbon, Total Organic (TOC)7.1 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 42 12 20 mg/L SM21 5220 CLIENT ID:MW-4 Lab ID:J1603049-002 Analyte Results Flag MDL PQL Units Method Barium, Total 50 J 0.3 100 ug/L 6010C Chromium, Total 1 J 0.9 50 ug/L 6020A Cobalt, Total 0.4 J 0.2 50 ug/L 6020A Lead, Total 1 J 0.6 50 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)3.8 J 0.30 5.0 ug/L 8260B Chloroform 0.50 J 0.35 5.0 ug/L 8260B CLIENT ID:MW-8 Lab ID:J1603049-003 Analyte Results Flag MDL PQL Units Method Chloride 5.2 0.08 1.0 mg/L 300.0 Nitrate as Nitrogen 0.06 J 0.04 0.20 mg/L 300.0 Sulfate 1.3 0.06 1.0 mg/L 300.0 Barium, Total 200 0.3 100 ug/L 6010C Sodium, Total 9.15 0.04 0.50 mg/L 6010C Arsenic, Total 1 J 0.5 10 ug/L 6020A Chromium, Total 20 0.2 10 ug/L 6020A Cobalt, Total 10 0.03 10 ug/L 6020A Copper, Total 9 J 0.3 10 ug/L 6020A Lead, Total 0.7 J 0.2 10 ug/L 6020A Nickel, Total 67 0.5 50 ug/L 6020A Zinc, Total 5 J 2 10 ug/L 6020A Mercury, Total 0.03 J 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)1.5 J 0.30 5.0 ug/L 8260B 1,1-Dichloroethene (1,1-DCE)0.59 J 0.16 5.0 ug/L 8260B Alkalinity as CaCO3, Total 141 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 141 5.0 5.0 mg/L SM 2320 B Solids, Total Dissolved 196 10 10 mg/L SM 2540 C Carbon, Total Organic (TOC)0.6 J 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 14 J 12 20 mg/L SM21 5220 SAMPLE DETECTION SUMMARY Page 2 of 141 CLIENT ID:MW-17 Lab ID:J1603049-004 Analyte Results Flag MDL PQL Units Method Barium, Total 110 0.3 100 ug/L 6010C Arsenic, Total 11 J 0.9 20 ug/L 6020A Beryllium, Total 0.2 J 0.07 2.0 ug/L 6020A Chromium, Total 2 J 0.4 20 ug/L 6020A Cobalt, Total 4 J 0.06 20 ug/L 6020A Copper, Total 3 J 0.5 20 ug/L 6020A Lead, Total 1 J 0.3 20 ug/L 6020A Nickel, Total 7 J 1.0 100 ug/L 6020A Zinc, Total 9 J 4 20 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)10 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.33 J 0.16 1.0 ug/L 8260B cis-1,2-Dichloroethene 1.4 J 0.36 5.0 ug/L 8260B CLIENT ID:MW-18 Lab ID:J1603049-005 Analyte Results Flag MDL PQL Units Method Barium, Total 90 J 0.3 100 ug/L 6010C Arsenic, Total 1 J 0.5 10 ug/L 6020A Chromium, Total 0.4 J 0.2 10 ug/L 6020A Cobalt, Total 1 J 0.03 10 ug/L 6020A Copper, Total 2 J 0.3 10 ug/L 6020A Nickel, Total 15 J 0.5 50 ug/L 6020A Zinc, Total 4 J 2 10 ug/L 6020A CLIENT ID:MW-19 Lab ID:J1603049-006 Analyte Results Flag MDL PQL Units Method Chloride 8.5 0.08 1.0 mg/L 300.0 Nitrate as Nitrogen 0.05 J 0.04 0.20 mg/L 300.0 Sulfate 6.7 0.06 1.0 mg/L 300.0 Barium, Total 160 0.3 100 ug/L 6010C Sodium, Total 7.90 0.04 0.50 mg/L 6010C Antimony, Total 0.3 J 0.2 6.0 ug/L 6020A Arsenic, Total 1 J 0.5 10 ug/L 6020A Beryllium, Total 0.06 J 0.04 1.0 ug/L 6020A Chromium, Total 2 J 0.2 10 ug/L 6020A Cobalt, Total 5 J 0.03 10 ug/L 6020A Copper, Total 19 0.3 10 ug/L 6020A Lead, Total 0.2 J 0.2 10 ug/L 6020A Nickel, Total 15 J 0.5 50 ug/L 6020A Zinc, Total 8 J 2 10 ug/L 6020A o-Xylene 0.33 J 0.14 1.0 ug/L 8260B Alkalinity as CaCO3, Total 83.5 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 83.5 5.0 5.0 mg/L SM 2320 B SAMPLE DETECTION SUMMARY Page 3 of 141 CLIENT ID:MW-19 Lab ID:J1603049-006 Analyte Results Flag MDL PQL Units Method Solids, Total Dissolved 120 10 10 mg/L SM 2540 C Carbon, Total Organic (TOC)1.5 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 15 J 12 20 mg/L SM21 5220 CLIENT ID:MW-21 Lab ID:J1603049-007 Analyte Results Flag MDL PQL Units Method Barium, Total 60 J 0.3 100 ug/L 6010C Arsenic, Total 2 J 0.5 10 ug/L 6020A Beryllium, Total 0.05 J 0.04 1.0 ug/L 6020A Chromium, Total 1 J 0.2 10 ug/L 6020A Cobalt, Total 1 J 0.03 10 ug/L 6020A Copper, Total 2 J 0.3 10 ug/L 6020A Lead, Total 1 J 0.2 10 ug/L 6020A Nickel, Total 2 J 0.5 50 ug/L 6020A Zinc, Total 6 J 2 10 ug/L 6020A CLIENT ID:MW-22 Lab ID:J1603049-008 Analyte Results Flag MDL PQL Units Method Barium, Total 240 0.3 100 ug/L 6010C Arsenic, Total 5 J 0.9 20 ug/L 6020A Chromium, Total 0.8 J 0.4 20 ug/L 6020A Cobalt, Total 5 J 0.06 20 ug/L 6020A Copper, Total 2 J 0.5 20 ug/L 6020A Lead, Total 0.8 J 0.3 20 ug/L 6020A Nickel, Total 5 J 1.0 100 ug/L 6020A Zinc, Total 9 J 4 20 ug/L 6020A Mercury, Total 0.03 J 0.02 0.20 ug/L 7470A CLIENT ID:MW-23 Lab ID:J1603049-009 Analyte Results Flag MDL PQL Units Method Barium, Total 260 0.3 100 ug/L 6010C Cobalt, Total 1 J 0.2 50 ug/L 6020A Zinc, Total 12 J 8 50 ug/L 6020A Mercury, Total 0.05 J 0.02 0.20 ug/L 7470A Acetone 6.0 J 5.6 100 ug/L 8260B CLIENT ID:MW-24 Lab ID:J1603049-010 Analyte Results Flag MDL PQL Units Method Barium, Total 140 0.3 100 ug/L 6010C Arsenic, Total 7 J 3 50 ug/L 6020A Chromium, Total 3 J 0.9 50 ug/L 6020A Cobalt, Total 2 J 0.2 50 ug/L 6020A Copper, Total 4 J 2 50 ug/L 6020A SAMPLE DETECTION SUMMARY Page 4 of 141 CLIENT ID:MW-24 Lab ID:J1603049-010 Analyte Results Flag MDL PQL Units Method Lead, Total 1 J 0.6 50 ug/L 6020A Nickel, Total 10 J 3 250 ug/L 6020A Zinc, Total 18 J 8 50 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)2.0 J 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.25 J 0.16 1.0 ug/L 8260B Acetone 7.6 J 5.6 100 ug/L 8260B o-Xylene 0.54 J 0.14 1.0 ug/L 8260B CLIENT ID:MW-25 Lab ID:J1603049-011 Analyte Results Flag MDL PQL Units Method Barium, Total 830 0.3 100 ug/L 6010C Cobalt, Total 0.7 J 0.2 50 ug/L 6020A Nickel, Total 8 J 3 250 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)2.9 J 0.30 5.0 ug/L 8260B Acetone 12 J 5.6 100 ug/L 8260B Benzene 1.2 0.21 1.0 ug/L 8260B CLIENT ID:MW-26 Lab ID:J1603049-012 Analyte Results Flag MDL PQL Units Method Barium, Total 180 0.3 100 ug/L 6010C Beryllium, Total 1.1 J 0.2 5.0 ug/L 6020A Chromium, Total 2 J 0.9 50 ug/L 6020A Cobalt, Total 29 J 0.2 50 ug/L 6020A Copper, Total 2 J 2 50 ug/L 6020A Lead, Total 0.9 J 0.6 50 ug/L 6020A Nickel, Total 10 J 3 250 ug/L 6020A Zinc, Total 36 J 8 50 ug/L 6020A Mercury, Total 0.03 J 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)0.70 J 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.62 J 0.16 1.0 ug/L 8260B Acetone 9.6 J 5.6 100 ug/L 8260B Benzene 1.4 0.21 1.0 ug/L 8260B Chlorobenzene 1.5 J 0.16 3.0 ug/L 8260B CLIENT ID:MW-27 Lab ID:J1603049-013 Analyte Results Flag MDL PQL Units Method Barium, Total 160 0.3 100 ug/L 6010C Arsenic, Total 18 J 3 50 ug/L 6020A Cobalt, Total 11 J 0.2 50 ug/L 6020A Nickel, Total 4 J 3 250 ug/L 6020A Zinc, Total 10 J 8 50 ug/L 6020A Mercury, Total 0.02 J 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)7.6 0.30 5.0 ug/L 8260B SAMPLE DETECTION SUMMARY Page 5 of 141 CLIENT ID:MW-27 Lab ID:J1603049-013 Analyte Results Flag MDL PQL Units Method 1,1-Dichloroethene (1,1-DCE)1.3 J 0.16 5.0 ug/L 8260B Chloroform 0.44 J 0.35 5.0 ug/L 8260B cis-1,2-Dichloroethene 0.37 J 0.36 5.0 ug/L 8260B Tetrachloroethene (PCE)0.67 J 0.22 1.0 ug/L 8260B Trichlorofluoromethane 0.88 J 0.24 20 ug/L 8260B CLIENT ID:MW-28 Lab ID:J1603049-014 Analyte Results Flag MDL PQL Units Method Barium, Total 300 0.3 100 ug/L 6010C Arsenic, Total 5 J 3 50 ug/L 6020A Cobalt, Total 0.4 J 0.2 50 ug/L 6020A Chloroform 1.8 J 0.35 5.0 ug/L 8260B o-Xylene 0.43 J 0.14 1.0 ug/L 8260B CLIENT ID:DUP Lab ID:J1603049-015 Analyte Results Flag MDL PQL Units Method Barium, Total 160 0.3 100 ug/L 6010C Antimony, Total 0.4 J 0.2 6.0 ug/L 6020A Arsenic, Total 1 J 0.5 10 ug/L 6020A Beryllium, Total 0.07 J 0.04 1.0 ug/L 6020A Cadmium, Total 0.1 J 0.10 1.0 ug/L 6020A Chromium, Total 2 J 0.2 10 ug/L 6020A Cobalt, Total 5 J 0.03 10 ug/L 6020A Copper, Total 20 0.3 10 ug/L 6020A Lead, Total 0.2 J 0.2 10 ug/L 6020A Nickel, Total 15 J 0.5 50 ug/L 6020A Zinc, Total 8 J 2 10 ug/L 6020A CLIENT ID:SW-1 Lab ID:J1603049-017 Analyte Results Flag MDL PQL Units Method Barium, Total 40 J 0.3 100 ug/L 6010C Arsenic, Total 0.7 J 0.5 10 ug/L 6020A Cobalt, Total 0.3 J 0.03 10 ug/L 6020A Copper, Total 1 J 0.3 10 ug/L 6020A Lead, Total 0.3 J 0.2 10 ug/L 6020A Nickel, Total 0.6 J 0.5 50 ug/L 6020A Zinc, Total 3 J 2 10 ug/L 6020A CLIENT ID:SW-3 Lab ID:J1603049-018 Analyte Results Flag MDL PQL Units Method Barium, Total 40 J 0.3 100 ug/L 6010C Chromium, Total 0.3 J 0.2 10 ug/L 6020A Cobalt, Total 0.4 J 0.03 10 ug/L 6020A SAMPLE DETECTION SUMMARY Page 6 of 141 CLIENT ID:SW-3 Lab ID:J1603049-018 Analyte Results Flag MDL PQL Units Method Copper, Total 1 J 0.3 10 ug/L 6020A Lead, Total 0.4 J 0.2 10 ug/L 6020A Nickel, Total 0.7 J 0.5 50 ug/L 6020A Zinc, Total 4 J 2 10 ug/L 6020A SAMPLE DETECTION SUMMARY Page 7 of 141 CASE NARRATIVE J1603049 Date Received: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: 04/27/16 - 04/28/16 All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II data deliverables, including results of QC samples analyzed from this delivery group. When appropriate to the procedure, method blank results have been reported with each analytical test. Analytical procedures performed by the lab are validated in accordance with NELAC standards. Parameters that are included in the NELAC Fields of Testing but are not included in the lab’s NELAC accreditation are identified in the discussion of each analytical procedure. Sample Receipt Eighteen ground water samples  were received for analysis at ALS Environmental on 4/27/2016. The samples were received in good condition and consistent with the accompanying chain of custody form. Samples are refrigerated at <6°C upon receipt at the lab except for aqueous samples designated for metals analyses, which are stored at room temperature. Volatile Organic Analyses: No significant data anomalies were noted with this analysis. Semi-Volatile Organic Analyses: No significant data anomalies were noted with this analysis. Metals Analyses: ICP/AES results for Vanadium in samples J1603049-(5, 9, and 11) were excessively negative, indicating spectral interference. All associated QC passed parameters. Results should be considered estimated. Method 6020A: Sample(s) J1603049-(1, 2, 4, 8-14) required dilution due to the presence of matrix that interfered with internal standard recovery. The reporting limits are adjusted to reflect the dilution. General Chemistry Analyses: Method SM5210B/405.1: The recovery for Laboratory Control Sample was outside of the control criterion. The analysis could not be repeated because holding time for the test had expired. No further corrective action was possible. Method SM4500-S2 F (Sulfide): The Titrant for this analysis were expired in March 2016. After confirming all quality control samples, analysis was performed. There is no reason to believe there is an effect on the sample data values. Subcontracted Analytical Parameters: An aliquot of the samples were delivered to ALS in Rochester, NY for Organic Acids determination. The certified analytical report has been included in its entirety in this report. An aliquot of the samples were delivered to ENCO in Jacksonville, FL for RSK-175 determination. The certified analytical report has been included in its entirety in Appendix A: Subcontracted Analytical Results. 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com Approved by Date 5/12/2016 Page 8 of 141 State Certifications, Accreditations, and Licenses Agency Number Expire Date Department of Defense 66206 9/20/2016 Florida Department of Health E82502 6/30/2016 Georgia Department of Natural Resources 958 6/30/2016 Kentucky Division of Waste Management 63 6/30/2016 Louisiana Department of Environmental Quality 02086 6/30/2016 Maine Department of Health and Human Services 2015002 2/3/2017 North Carolina Department of Environment and Natural Resources 527 12/31/2016 Pennsylvania Department of Environmental Protection 68-04835 8/31/2016 South Carolina Department of Health and Environmental Control 96021001 6/30/2016 Texas Commision on Environmental Quality T104704197-16-8 5/31/2017 Virginia Environmental Accreditation Program 460191 12/14/2016 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com Page 9 of 141 +Possible Tedlar bag artifact. A TIC is a suspected aldol-condensation product B Analyte found in the associated method blank as well as in the sample. BC Reported results are not blank corrected. BH The back section of the tube yielded higher results than the front. BT Results indicated possible breakthrough; back section >=10% front section. C Result identification confirmed. D Compound identified in an analysis at a secondary dilution factor D Spike was diluted out DE Reported results are corrected for desorption efficiency. E Estimated value. Concentration above calibration range E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample. H1 Sample analysis performed past holding time. See case narrative. H2 Initial analysis within holding time. Reanalysis for the required dilution was past holding time. H3 Sample was received and analyzed past holding time. H4 Sample was extracted past required extraction holding time, but analyzed within analysis holding time. See case narrative. I Internal standard not within the specified limits. See case narrative. J Estimated Value. Concentration found below MRL. K A deflection in the QC ion may indicate interference with the quantitation of this ion. The concentration of this analyte should be considered as an estimate. K Analyte was detected above the method reporting limit prior to normalization. L1 Laboratory control sample recovery outside the specified limits; results may be biased high. L2 Laboratory control sample recovery outside the specified limits; results may be biased low. L3 Laboratory control sample recovery outside the specified limits. M Matrix interference; results may be biased high. M The duplicate injection precision not met. M1 Matrix interference due to coelution with a non-target compound; results may be biased high. N Presumptive evidence of a compound for TICs that have been identified based on a mass spectral library search. N The Matrix Spike sample recovery is not within control limits. See case narrative. P Indicates chlorodiphenyl ether interference present at the retention time of the target compound. P Pesticide/Aroclor target analyte > 40% difference for detected concentrations between GC columns Q Indicates as estimated value because the P and P + 2 theoretical abundance ratio does not meet method criteria. R Duplicate Precision not met. R1 Duplicate precision not within the specified limits; however, the results are below the MRL and considered estimated. S Surrogate recovery not within specified limits. Data Qualifiers Lab Standard Page 10 of 141 S The reported value was determined by the Method of Standard Additions (MSA). T Analyte is a tentatively identified compound, result is estimated. U Compound was analyzed for, but was not detected (ND). V1 The continuing calibration verification standard was outside (biased high) the specified limits for this compound. V2 The continuing calibration verification standard was outside (biased low) the specified limits for this compound. W Result quantified, but the corresponding peak was detected outside the generated retention time window. W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance. X See case narrative. Y Recovery outside limits Y The chromatogram resembles a petroleum product but does not match the calibration standard. Z The chromatogram does not resemble a petroleum product. i The MRL/MDL has been elevated due to a matrix interference. Data Qualifiers Lab Standard Page 11 of 141 ASTM American Society for Testing and Materials A2LA American Association for Laboratory Accreditation CARB California Air Resources Board CAS Number Chemical Abstract Service registry Number CFC Chlorofluorocarbon CFU Colony-Forming Unit DEC Department of Environmental Conservation DEQ Department of Environmental Quality DHS Department of Health Services DOE Department of Ecology DOH Department of Health EPA U. S. Environmental Protection Agency ELAP Environmental Laboratory Accreditation Program GC Gas Chromatography GC/MS Gas Chromatography/Mass Spectrometry LUFT Leaking Underground Fuel Tank M Modified MCL Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. MDL Method Detection Limit MPN Most Probable Number MRL Method Reporting Limit NA Not Applicable NC Not Calculated NCASI National Council of the Paper Industry for Air and Stream Improvement ND Not Detected NIOSH National Institute for Occupational Safety and Health PQL Practical Quantitation Limit RCRA Resource Conservation and Recovery Act SIM Selected Ion Monitoring TPH Total Petroleum Hydrocarbons tr Trace level is the concentration of an analyte that is less than the PQL but greater than or equal to the MDL. Acronyms ALS Laboratory Group Page 12 of 141 MW-2J1603049-001 4/26/2016 0730 MW-4J1603049-002 4/26/2016 0850 MW-8J1603049-003 4/26/2016 1410 MW-17J1603049-004 4/26/2016 1645 MW-18J1603049-005 4/26/2016 1100 MW-19J1603049-006 4/26/2016 1530 MW-21J1603049-007 4/26/2016 0910 MW-22J1603049-008 4/26/2016 0820 MW-23J1603049-009 4/26/2016 0810 MW-24J1603049-010 4/25/2016 1200 MW-25J1603049-011 4/26/2016 0840 MW-26J1603049-012 4/26/2016 0920 MW-27J1603049-013 4/26/2016 1010 MW-28J1603049-014 4/26/2016 1040 DUPJ1603049-015 4/26/2016 0800 Trip BlankJ1603049-016 4/25/2016 0000 SW-1J1603049-017 4/26/2016 1300 SW-3J1603049-018 4/26/2016 0940 Client:Wake County Solid Waste Management Service Request:J1603049 Project:Feltonsville Landfill SAMPLE CROSS-REFERENCE SAMPLE #CLIENT SAMPLE ID DATE TIME Printed 5/12/2016 8:30:04 AM Sample Summary Page 13 of 141 J1603049-001Lab Code: Sample Name:MW-2 Volatile Organic Compounds by GC/MS 04/26/16 07:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 01:035.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 01:031.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 01:033.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 01:031.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 01:035.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 01:035.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 01:032.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 01:0313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 01:031.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 01:035.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 01:031.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 01:031.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 01:031.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 01:03100 U2.22-Hexanone 2.2 1 05/06/16 01:0350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 01:03100 U5.6Acetone 5.6 1 05/06/16 01:03100 U 1.5Acrylonitrile 1.5 1 05/06/16 01:03200 U0.21Benzene 0.21 1 05/06/16 01:031.0 U 0.27Bromochloromethane 0.27 1 05/06/16 01:035.0 U0.22Bromodichloromethane 0.22 1 05/06/16 01:031.0 U 0.42Bromoform 0.42 1 05/06/16 01:033.0 U0.23Bromomethane 0.23 1 05/06/16 01:0310 U 2.4Carbon Disulfide 2.4 1 05/06/16 01:03100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 01:031.0 U 0.16Chlorobenzene 0.16 1 05/06/16 01:033.0 U0.52Chloroethane 0.52 1 05/06/16 01:0310 U 2.3Chloroform 0.35 1 05/06/16 01:035.0 J0.36Chloromethane 0.36 1 05/06/16 01:031.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 01:035.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 01:031.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 01:033.0 U0.36Dibromomethane 0.36 1 05/06/16 01:0310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 01:0320 U0.21Ethylbenzene 0.21 1 05/06/16 01:031.0 U 2.7Iodomethane 2.7 1 05/06/16 01:0310 U0.31m,p-Xylenes 0.31 1 05/06/16 01:032.0 U 0.21Methylene Chloride 0.21 1 05/06/16 01:035.0 U0.14o-Xylene 0.14 1 05/06/16 01:031.0 U 0.29Styrene 0.29 1 05/06/16 01:031.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 01:031.0 U 0.19Toluene 0.19 1 05/06/16 01:031.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 01:035.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 14 of 141 J1603049-001Lab Code: Sample Name:MW-2 Volatile Organic Compounds by GC/MS 04/26/16 07:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 01:031.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 01:03100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 01:031.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 01:0320 U1.9Vinyl Acetate 1.9 1 05/06/16 01:0350 U 0.36Vinyl Chloride 0.36 1 05/06/16 01:031.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 01:0372 - 1211031,2-Dichloroethane-d4 05/06/16 01:0386 - 1131054-Bromofluorobenzene 05/06/16 01:0386 - 112103Dibromofluoromethane 05/06/16 01:0388 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 15 of 141 J1603049-001Lab Code: Sample Name:MW-2 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 07:30 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007121,2-Dibromo-3-chloropropane (DBCP)0.00712 1 05/03/16 07:22 5/2/160.0203 U 0.007121,2-Dibromoethane (EDB)0.00712 1 05/03/16 07:22 5/2/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 07:2270 - 130801,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:15 AM 16-0000374636 rev 00Superset Reference: Page 16 of 141 J1603049-001Lab Code: Sample Name:MW-2 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/26/16 07:30 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 19:460.50 U 0.50Acetic Acid 0.50 1 04/29/16 19:461.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 19:462.0 U 0.50Lactic Acid 0.50 1 04/29/16 19:461.0 U0.50Propionic Acid 0.50 1 04/29/16 19:461.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:20 AM 16-0000374636 rev 00Superset Reference: Page 17 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 07:30 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-2 Lab Code:J1603049-001 Antimony, Total 05/05/16 23:09 05/02/1610260 U26020A ug/L Arsenic, Total 05/05/16 23:09 05/02/16105100 U56020A ug/L Barium, Total 05/03/16 20:51 05/03/1610.31002506010Cug/L Beryllium, Total 05/05/16 23:09 05/02/16100.410 U0.46020A ug/L Cadmium, Total 05/05/16 23:09 05/02/16101.010 U1.06020A ug/L Chromium, Total 05/05/16 23:09 05/02/16102100 U26020A ug/L Cobalt, Total 05/05/16 23:09 05/02/16100.3100 U0.36020A ug/L Copper, Total 05/05/16 23:09 05/02/16103100 U36020A ug/L Lead, Total 05/05/16 23:09 05/02/16102100 U26020A ug/L Mercury, Total 05/04/16 12:28 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:09 05/02/16105500 U56020A ug/L Selenium, Total 05/05/16 23:09 05/02/161020100 U206020A ug/L Silver, Total 05/03/16 20:51 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:09 05/02/16100.555 U0.56020A ug/L Vanadium, Total 05/03/16 20:51 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:09 05/02/161020100 J206020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:22 AM 16-0000374636 rev 00Superset Reference: Page 18 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 07:30 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-2 Lab Code:J1603049-001 Alkalinity as CaCO3, Total 04/27/16 21:23 NA15.05.0180SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 04/27/16 21:23 NA15.05.0180SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/27/16 07:00 NA12.02.0 U2.0 *SM 5210 B mg/L Carbon, Total Organic (TOC)04/29/16 14:36 NA10.061.07.1SM 5310 B mg/L Carbonate Alkalinity as CaCO3 04/27/16 21:23 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:07 05/05/161122042SM21 5220 D mg/L Chloride 04/27/16 19:00 NA100.810756300.0 mg/L Nitrate as Nitrogen 04/27/16 18:47 NA10.040.200.24300.0 mg/L Sulfate 04/29/16 03:02 NA10.061.026.1300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:28 AM 16-0000374636 rev 00Superset Reference: Page 19 of 141 J1603049-002Lab Code: Sample Name:MW-4 Volatile Organic Compounds by GC/MS 04/26/16 08:50 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 01:265.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 01:261.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 01:263.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 01:261.0 U3.81,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 01:265.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 01:265.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 01:262.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 01:2613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 01:261.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 01:265.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 01:261.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 01:261.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 01:261.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 01:26100 U2.22-Hexanone 2.2 1 05/06/16 01:2650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 01:26100 U5.6Acetone 5.6 1 05/06/16 01:26100 U 1.5Acrylonitrile 1.5 1 05/06/16 01:26200 U0.21Benzene 0.21 1 05/06/16 01:261.0 U 0.27Bromochloromethane 0.27 1 05/06/16 01:265.0 U0.22Bromodichloromethane 0.22 1 05/06/16 01:261.0 U 0.42Bromoform 0.42 1 05/06/16 01:263.0 U0.23Bromomethane 0.23 1 05/06/16 01:2610 U 2.4Carbon Disulfide 2.4 1 05/06/16 01:26100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 01:261.0 U 0.16Chlorobenzene 0.16 1 05/06/16 01:263.0 U0.52Chloroethane 0.52 1 05/06/16 01:2610 U 0.50Chloroform 0.35 1 05/06/16 01:265.0 J0.36Chloromethane 0.36 1 05/06/16 01:261.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 01:265.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 01:261.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 01:263.0 U0.36Dibromomethane 0.36 1 05/06/16 01:2610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 01:2620 U0.21Ethylbenzene 0.21 1 05/06/16 01:261.0 U 2.7Iodomethane 2.7 1 05/06/16 01:2610 U0.31m,p-Xylenes 0.31 1 05/06/16 01:262.0 U 0.21Methylene Chloride 0.21 1 05/06/16 01:265.0 U0.14o-Xylene 0.14 1 05/06/16 01:261.0 U 0.29Styrene 0.29 1 05/06/16 01:261.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 01:261.0 U 0.19Toluene 0.19 1 05/06/16 01:261.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 01:265.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 20 of 141 J1603049-002Lab Code: Sample Name:MW-4 Volatile Organic Compounds by GC/MS 04/26/16 08:50 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 01:261.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 01:26100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 01:261.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 01:2620 U1.9Vinyl Acetate 1.9 1 05/06/16 01:2650 U 0.36Vinyl Chloride 0.36 1 05/06/16 01:261.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 01:2672 - 1211021,2-Dichloroethane-d4 05/06/16 01:2686 - 1131054-Bromofluorobenzene 05/06/16 01:2686 - 112103Dibromofluoromethane 05/06/16 01:2688 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 21 of 141 J1603049-002Lab Code: Sample Name:MW-4 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 08:50 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007151,2-Dibromo-3-chloropropane (DBCP)0.00715 1 05/03/16 07:47 5/2/160.0204 U 0.007151,2-Dibromoethane (EDB)0.00715 1 05/03/16 07:47 5/2/160.0204 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 07:4770 - 130841,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:15 AM 16-0000374636 rev 00Superset Reference: Page 22 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 08:50 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-4 Lab Code:J1603049-002 Antimony, Total 05/05/16 23:15 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/05/16 23:15 05/02/165350 U36020A ug/L Barium, Total 05/03/16 21:01 05/03/1610.3100 J506010C ug/L Beryllium, Total 05/05/16 23:15 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/05/16 23:15 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/05/16 23:15 05/02/1650.950 J16020A ug/L Cobalt, Total 05/05/16 23:15 05/02/1650.250 J0.46020A ug/L Copper, Total 05/05/16 23:15 05/02/165250 U26020A ug/L Lead, Total 05/05/16 23:15 05/02/1650.650 J16020A ug/L Mercury, Total 05/04/16 12:29 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:15 05/02/1653250 U36020A ug/L Selenium, Total 05/05/16 23:15 05/02/165650 U66020A ug/L Silver, Total 05/03/16 21:00 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:15 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 21:00 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:15 05/02/165850 U86020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:22 AM 16-0000374636 rev 00Superset Reference: Page 23 of 141 J1603049-003Lab Code: Sample Name:MW-8 Volatile Organic Compounds by GC/MS 04/26/16 14:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 01:495.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 01:491.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 01:493.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 01:491.0 U1.51,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 01:495.0 J 0.591,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 01:495.0 J0.421,2,3-Trichloropropane 0.42 1 05/06/16 01:492.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 01:4913 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 01:491.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 01:495.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 01:491.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 01:491.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 01:491.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 01:49100 U2.22-Hexanone 2.2 1 05/06/16 01:4950 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 01:49100 U5.6Acetone 5.6 1 05/06/16 01:49100 U 1.5Acrylonitrile 1.5 1 05/06/16 01:49200 U0.21Benzene 0.21 1 05/06/16 01:491.0 U 0.27Bromochloromethane 0.27 1 05/06/16 01:495.0 U0.22Bromodichloromethane 0.22 1 05/06/16 01:491.0 U 0.42Bromoform 0.42 1 05/06/16 01:493.0 U0.23Bromomethane 0.23 1 05/06/16 01:4910 U 2.4Carbon Disulfide 2.4 1 05/06/16 01:49100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 01:491.0 U 0.16Chlorobenzene 0.16 1 05/06/16 01:493.0 U0.52Chloroethane 0.52 1 05/06/16 01:4910 U 0.35Chloroform 0.35 1 05/06/16 01:495.0 U0.36Chloromethane 0.36 1 05/06/16 01:491.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 01:495.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 01:491.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 01:493.0 U0.36Dibromomethane 0.36 1 05/06/16 01:4910 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 01:4920 U0.21Ethylbenzene 0.21 1 05/06/16 01:491.0 U 2.7Iodomethane 2.7 1 05/06/16 01:4910 U0.31m,p-Xylenes 0.31 1 05/06/16 01:492.0 U 0.21Methylene Chloride 0.21 1 05/06/16 01:495.0 U0.14o-Xylene 0.14 1 05/06/16 01:491.0 U 0.29Styrene 0.29 1 05/06/16 01:491.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 01:491.0 U 0.19Toluene 0.19 1 05/06/16 01:491.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 01:495.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 24 of 141 J1603049-003Lab Code: Sample Name:MW-8 Volatile Organic Compounds by GC/MS 04/26/16 14:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 01:491.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 01:49100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 01:491.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 01:4920 U1.9Vinyl Acetate 1.9 1 05/06/16 01:4950 U 0.36Vinyl Chloride 0.36 1 05/06/16 01:491.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 01:4972 - 1211011,2-Dichloroethane-d4 05/06/16 01:4986 - 1131054-Bromofluorobenzene 05/06/16 01:4986 - 112101Dibromofluoromethane 05/06/16 01:4988 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:05 AM 16-0000374636 rev 00Superset Reference: Page 25 of 141 J1603049-003Lab Code: Sample Name:MW-8 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 14:10 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007091,2-Dibromo-3-chloropropane (DBCP)0.00709 1 05/03/16 08:12 5/2/160.0202 U 0.007091,2-Dibromoethane (EDB)0.00709 1 05/03/16 08:12 5/2/160.0202 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 08:1270 - 130821,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:15 AM 16-0000374636 rev 00Superset Reference: Page 26 of 141 J1603049-003Lab Code: Sample Name:MW-8 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/26/16 14:10 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 20:330.50 U 0.50Acetic Acid 0.50 1 04/29/16 20:331.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 20:332.0 U 0.50Lactic Acid 0.50 1 04/29/16 20:331.0 U0.50Propionic Acid 0.50 1 04/29/16 20:331.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:20 AM 16-0000374636 rev 00Superset Reference: Page 27 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 14:10 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-8 Lab Code:J1603049-003 Antimony, Total 05/05/16 23:20 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/05/16 23:20 05/02/1610.510 J16020A ug/L Barium, Total 05/03/16 21:05 05/03/1610.31002006010Cug/L Beryllium, Total 05/05/16 23:20 05/02/1610.041.0 U0.046020A ug/L Cadmium, Total 05/05/16 23:20 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/05/16 23:20 05/02/1610.210206020Aug/L Cobalt, Total 05/05/16 23:20 05/02/1610.0310106020Aug/L Copper, Total 05/05/16 23:20 05/02/1610.310 J96020A ug/L Lead, Total 05/05/16 23:20 05/02/1610.210 J0.76020A ug/L Mercury, Total 05/04/16 12:31 05/02/1610.020.20 J0.037470A ug/L Nickel, Total 05/05/16 23:20 05/02/1610.550676020Aug/L Selenium, Total 05/05/16 23:20 05/02/161210 U26020A ug/L Silver, Total 05/03/16 21:05 05/03/1610.610 U0.66010C ug/L Sodium, Total 05/03/16 21:04 05/03/1610.040.509.156010C mg/L Thallium, Total 05/05/16 23:20 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 21:05 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:20 05/02/161210 J56020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:22 AM 16-0000374636 rev 00Superset Reference: Page 28 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 14:10 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-8 Lab Code:J1603049-003 Alkalinity as CaCO3, Total 04/27/16 21:31 NA15.05.0141SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 04/27/16 21:31 NA15.05.0141SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/27/16 07:00 NA12.02.0 U2.0 *SM 5210 B mg/L Carbon, Total Organic (TOC)04/29/16 14:50 NA10.061.0 J0.6SM 5310 B mg/L Carbonate Alkalinity as CaCO3 04/27/16 21:31 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:08 05/05/1611220 J14SM21 5220 D mg/L Chloride 04/27/16 19:13 NA10.081.05.2300.0 mg/L Nitrate as Nitrogen 04/27/16 19:13 NA10.040.20 J0.06300.0 mg/L Solids, Total Dissolved 04/29/16 12:09 NA11010196SM 2540 C mg/L Sulfate 04/29/16 03:15 NA10.061.01.3300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:28 AM 16-0000374636 rev 00Superset Reference: Page 29 of 141 J1603049-004Lab Code: Sample Name:MW-17 Volatile Organic Compounds by GC/MS 04/26/16 16:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 02:135.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 02:131.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 02:133.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 02:131.0 U101,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 02:135.0 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 02:135.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 02:132.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 02:1313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 02:131.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 02:135.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 02:131.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 02:131.0 U0.331,4-Dichlorobenzene 0.16 1 05/06/16 02:131.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 02:13100 U2.22-Hexanone 2.2 1 05/06/16 02:1350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 02:13100 U5.6Acetone 5.6 1 05/06/16 02:13100 U 1.5Acrylonitrile 1.5 1 05/06/16 02:13200 U0.21Benzene 0.21 1 05/06/16 02:131.0 U 0.27Bromochloromethane 0.27 1 05/06/16 02:135.0 U0.22Bromodichloromethane 0.22 1 05/06/16 02:131.0 U 0.42Bromoform 0.42 1 05/06/16 02:133.0 U0.23Bromomethane 0.23 1 05/06/16 02:1310 U 2.4Carbon Disulfide 2.4 1 05/06/16 02:13100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 02:131.0 U 0.16Chlorobenzene 0.16 1 05/06/16 02:133.0 U0.52Chloroethane 0.52 1 05/06/16 02:1310 U 0.35Chloroform 0.35 1 05/06/16 02:135.0 U0.36Chloromethane 0.36 1 05/06/16 02:131.0 U 1.4cis-1,2-Dichloroethene 0.36 1 05/06/16 02:135.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 02:131.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 02:133.0 U0.36Dibromomethane 0.36 1 05/06/16 02:1310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 02:1320 U0.21Ethylbenzene 0.21 1 05/06/16 02:131.0 U 2.7Iodomethane 2.7 1 05/06/16 02:1310 U0.31m,p-Xylenes 0.31 1 05/06/16 02:132.0 U 0.21Methylene Chloride 0.21 1 05/06/16 02:135.0 U0.14o-Xylene 0.14 1 05/06/16 02:131.0 U 0.29Styrene 0.29 1 05/06/16 02:131.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 02:131.0 U 0.19Toluene 0.19 1 05/06/16 02:131.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 02:135.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 30 of 141 J1603049-004Lab Code: Sample Name:MW-17 Volatile Organic Compounds by GC/MS 04/26/16 16:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 02:131.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 02:13100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 02:131.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 02:1320 U1.9Vinyl Acetate 1.9 1 05/06/16 02:1350 U 0.36Vinyl Chloride 0.36 1 05/06/16 02:131.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 02:1372 - 1211021,2-Dichloroethane-d4 05/06/16 02:1386 - 1131074-Bromofluorobenzene 05/06/16 02:1386 - 112100Dibromofluoromethane 05/06/16 02:1388 - 115104Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 31 of 141 J1603049-004Lab Code: Sample Name:MW-17 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 16:45 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007171,2-Dibromo-3-chloropropane (DBCP)0.00717 1 05/03/16 09:53 5/2/160.0205 U 0.007171,2-Dibromoethane (EDB)0.00717 1 05/03/16 09:53 5/2/160.0205 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 09:5370 - 130851,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:15 AM 16-0000374636 rev 00Superset Reference: Page 32 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 16:45 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-17 Lab Code:J1603049-004 Antimony, Total 05/05/16 23:25 05/02/1620.412 U0.46020A ug/L Arsenic, Total 05/05/16 23:25 05/02/1620.920 J116020A ug/L Barium, Total 05/03/16 21:10 05/03/1610.31001106010Cug/L Beryllium, Total 05/05/16 23:25 05/02/1620.072.0 J0.26020A ug/L Cadmium, Total 05/05/16 23:25 05/02/1620.22.0 U0.26020A ug/L Chromium, Total 05/05/16 23:25 05/02/1620.420 J26020A ug/L Cobalt, Total 05/05/16 23:25 05/02/1620.0620 J46020A ug/L Copper, Total 05/05/16 23:25 05/02/1620.520 J36020A ug/L Lead, Total 05/05/16 23:25 05/02/1620.320 J16020A ug/L Mercury, Total 05/04/16 12:32 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:25 05/02/1621.0100 J76020A ug/L Selenium, Total 05/05/16 23:25 05/02/162320 U36020A ug/L Silver, Total 05/03/16 21:10 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:25 05/02/1620.111 U0.16020A ug/L Vanadium, Total 05/03/16 21:10 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:25 05/02/162420 J96020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 33 of 141 J1603049-005Lab Code: Sample Name:MW-18 Volatile Organic Compounds by GC/MS 04/26/16 11:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 02:365.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 02:361.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 02:363.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 02:361.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 02:365.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 02:365.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 02:362.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 02:3613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 02:361.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 02:365.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 02:361.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 02:361.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 02:361.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 02:36100 U2.22-Hexanone 2.2 1 05/06/16 02:3650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 02:36100 U5.6Acetone 5.6 1 05/06/16 02:36100 U 1.5Acrylonitrile 1.5 1 05/06/16 02:36200 U0.21Benzene 0.21 1 05/06/16 02:361.0 U 0.27Bromochloromethane 0.27 1 05/06/16 02:365.0 U0.22Bromodichloromethane 0.22 1 05/06/16 02:361.0 U 0.42Bromoform 0.42 1 05/06/16 02:363.0 U0.23Bromomethane 0.23 1 05/06/16 02:3610 U 2.4Carbon Disulfide 2.4 1 05/06/16 02:36100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 02:361.0 U 0.16Chlorobenzene 0.16 1 05/06/16 02:363.0 U0.52Chloroethane 0.52 1 05/06/16 02:3610 U 0.35Chloroform 0.35 1 05/06/16 02:365.0 U0.36Chloromethane 0.36 1 05/06/16 02:361.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 02:365.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 02:361.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 02:363.0 U0.36Dibromomethane 0.36 1 05/06/16 02:3610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 02:3620 U0.21Ethylbenzene 0.21 1 05/06/16 02:361.0 U 2.7Iodomethane 2.7 1 05/06/16 02:3610 U0.31m,p-Xylenes 0.31 1 05/06/16 02:362.0 U 0.21Methylene Chloride 0.21 1 05/06/16 02:365.0 U0.14o-Xylene 0.14 1 05/06/16 02:361.0 U 0.29Styrene 0.29 1 05/06/16 02:361.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 02:361.0 U 0.19Toluene 0.19 1 05/06/16 02:361.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 02:365.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 34 of 141 J1603049-005Lab Code: Sample Name:MW-18 Volatile Organic Compounds by GC/MS 04/26/16 11:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 02:361.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 02:36100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 02:361.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 02:3620 U1.9Vinyl Acetate 1.9 1 05/06/16 02:3650 U 0.36Vinyl Chloride 0.36 1 05/06/16 02:361.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 02:3672 - 1211031,2-Dichloroethane-d4 05/06/16 02:3686 - 1131044-Bromofluorobenzene 05/06/16 02:3686 - 112101Dibromofluoromethane 05/06/16 02:3688 - 115101Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 35 of 141 J1603049-005Lab Code: Sample Name:MW-18 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 11:00 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007151,2-Dibromo-3-chloropropane (DBCP)0.00715 1 05/03/16 11:34 5/2/160.0204 U 0.007151,2-Dibromoethane (EDB)0.00715 1 05/03/16 11:34 5/2/160.0204 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 11:3470 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:15 AM 16-0000374636 rev 00Superset Reference: Page 36 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 11:00 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-18 Lab Code:J1603049-005 Antimony, Total 05/05/16 23:31 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/05/16 23:31 05/02/1610.510 J16020A ug/L Barium, Total 05/03/16 21:15 05/03/1610.3100 J906010C ug/L Beryllium, Total 05/05/16 23:31 05/02/1610.041.0 U0.046020A ug/L Cadmium, Total 05/05/16 23:31 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/05/16 23:31 05/02/1610.210 J0.46020A ug/L Cobalt, Total 05/05/16 23:31 05/02/1610.0310 J16020A ug/L Copper, Total 05/05/16 23:31 05/02/1610.310 J26020A ug/L Lead, Total 05/05/16 23:31 05/02/1610.210 U0.26020A ug/L Mercury, Total 05/04/16 12:34 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:31 05/02/1610.550 J156020A ug/L Selenium, Total 05/05/16 23:31 05/02/161210 U26020A ug/L Silver, Total 05/03/16 21:15 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:31 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 21:15 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:31 05/02/161210 J46020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 37 of 141 J1603049-006Lab Code: Sample Name:MW-19 Volatile Organic Compounds by GC/MS 04/26/16 15:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 03:005.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 03:001.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 03:003.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 03:001.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 03:005.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 03:005.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 03:002.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 03:0013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 03:001.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 03:005.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 03:001.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 03:001.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 03:001.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 03:00100 U2.22-Hexanone 2.2 1 05/06/16 03:0050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 03:00100 U5.6Acetone 5.6 1 05/06/16 03:00100 U 1.5Acrylonitrile 1.5 1 05/06/16 03:00200 U0.21Benzene 0.21 1 05/06/16 03:001.0 U 0.27Bromochloromethane 0.27 1 05/06/16 03:005.0 U0.22Bromodichloromethane 0.22 1 05/06/16 03:001.0 U 0.42Bromoform 0.42 1 05/06/16 03:003.0 U0.23Bromomethane 0.23 1 05/06/16 03:0010 U 2.4Carbon Disulfide 2.4 1 05/06/16 03:00100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 03:001.0 U 0.16Chlorobenzene 0.16 1 05/06/16 03:003.0 U0.52Chloroethane 0.52 1 05/06/16 03:0010 U 0.35Chloroform 0.35 1 05/06/16 03:005.0 U0.36Chloromethane 0.36 1 05/06/16 03:001.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 03:005.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 03:001.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 03:003.0 U0.36Dibromomethane 0.36 1 05/06/16 03:0010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 03:0020 U0.21Ethylbenzene 0.21 1 05/06/16 03:001.0 U 2.7Iodomethane 2.7 1 05/06/16 03:0010 U0.31m,p-Xylenes 0.31 1 05/06/16 03:002.0 U 0.21Methylene Chloride 0.21 1 05/06/16 03:005.0 U0.33o-Xylene 0.14 1 05/06/16 03:001.0 J 0.29Styrene 0.29 1 05/06/16 03:001.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 03:001.0 U 0.19Toluene 0.19 1 05/06/16 03:001.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 03:005.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 38 of 141 J1603049-006Lab Code: Sample Name:MW-19 Volatile Organic Compounds by GC/MS 04/26/16 15:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 03:001.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 03:00100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 03:001.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 03:0020 U1.9Vinyl Acetate 1.9 1 05/06/16 03:0050 U 0.36Vinyl Chloride 0.36 1 05/06/16 03:001.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 03:0072 - 1211021,2-Dichloroethane-d4 05/06/16 03:0086 - 1131104-Bromofluorobenzene 05/06/16 03:0086 - 112102Dibromofluoromethane 05/06/16 03:0088 - 11599Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:06 AM 16-0000374636 rev 00Superset Reference: Page 39 of 141 J1603049-006Lab Code: Sample Name:MW-19 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 15:30 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 11:59 5/2/160.0197 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 11:59 5/2/160.0197 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 11:5970 - 130781,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 40 of 141 J1603049-006Lab Code: Sample Name:MW-19 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/26/16 15:30 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 21:200.50 U 0.50Acetic Acid 0.50 1 04/29/16 21:201.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 21:202.0 U 0.50Lactic Acid 0.50 1 04/29/16 21:201.0 U0.50Propionic Acid 0.50 1 04/29/16 21:201.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:20 AM 16-0000374636 rev 00Superset Reference: Page 41 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 15:30 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-19 Lab Code:J1603049-006 Antimony, Total 05/05/16 23:36 05/02/1610.26.0 J0.36020A ug/L Arsenic, Total 05/05/16 23:36 05/02/1610.510 J16020A ug/L Barium, Total 05/03/16 21:20 05/03/1610.31001606010Cug/L Beryllium, Total 05/05/16 23:36 05/02/1610.041.0 J0.066020A ug/L Cadmium, Total 05/05/16 23:36 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/05/16 23:36 05/02/1610.210 J26020A ug/L Cobalt, Total 05/05/16 23:36 05/02/1610.0310 J56020A ug/L Copper, Total 05/05/16 23:36 05/02/1610.310196020Aug/L Lead, Total 05/05/16 23:36 05/02/1610.210 J0.26020A ug/L Mercury, Total 05/04/16 12:35 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:36 05/02/1610.550 J156020A ug/L Selenium, Total 05/05/16 23:36 05/02/161210 U26020A ug/L Silver, Total 05/03/16 21:20 05/03/1610.610 U0.66010C ug/L Sodium, Total 05/03/16 21:19 05/03/1610.040.507.906010C mg/L Thallium, Total 05/05/16 23:36 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 21:20 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:36 05/02/161210 J86020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 42 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 15:30 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-19 Lab Code:J1603049-006 Alkalinity as CaCO3, Total 04/27/16 21:44 NA15.05.083.5SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 04/27/16 21:44 NA15.05.083.5SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/27/16 07:00 NA12.02.0 U2.0 *SM 5210 B mg/L Carbon, Total Organic (TOC)04/29/16 17:58 NA10.061.01.5SM 5310 B mg/L Carbonate Alkalinity as CaCO3 04/27/16 21:44 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:09 05/05/1611220 J15SM21 5220 D mg/L Chloride 04/27/16 19:52 NA10.081.08.5300.0 mg/L Nitrate as Nitrogen 04/27/16 19:52 NA10.040.20 J0.05300.0 mg/L Solids, Total Dissolved 04/29/16 12:09 NA11010120SM 2540 C mg/L Sulfate 04/29/16 03:28 NA10.061.06.7300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:28 AM 16-0000374636 rev 00Superset Reference: Page 43 of 141 J1603049-007Lab Code: Sample Name:MW-21 Volatile Organic Compounds by GC/MS 04/26/16 09:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 03:235.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 03:231.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 03:233.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 03:231.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 03:235.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 03:235.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 03:232.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 03:2313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 03:231.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 03:235.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 03:231.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 03:231.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 03:231.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 03:23100 U2.22-Hexanone 2.2 1 05/06/16 03:2350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 03:23100 U5.6Acetone 5.6 1 05/06/16 03:23100 U 1.5Acrylonitrile 1.5 1 05/06/16 03:23200 U0.21Benzene 0.21 1 05/06/16 03:231.0 U 0.27Bromochloromethane 0.27 1 05/06/16 03:235.0 U0.22Bromodichloromethane 0.22 1 05/06/16 03:231.0 U 0.42Bromoform 0.42 1 05/06/16 03:233.0 U0.23Bromomethane 0.23 1 05/06/16 03:2310 U 2.4Carbon Disulfide 2.4 1 05/06/16 03:23100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 03:231.0 U 0.16Chlorobenzene 0.16 1 05/06/16 03:233.0 U0.52Chloroethane 0.52 1 05/06/16 03:2310 U 0.35Chloroform 0.35 1 05/06/16 03:235.0 U0.36Chloromethane 0.36 1 05/06/16 03:231.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 03:235.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 03:231.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 03:233.0 U0.36Dibromomethane 0.36 1 05/06/16 03:2310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 03:2320 U0.21Ethylbenzene 0.21 1 05/06/16 03:231.0 U 2.7Iodomethane 2.7 1 05/06/16 03:2310 U0.31m,p-Xylenes 0.31 1 05/06/16 03:232.0 U 0.21Methylene Chloride 0.21 1 05/06/16 03:235.0 U0.14o-Xylene 0.14 1 05/06/16 03:231.0 U 0.29Styrene 0.29 1 05/06/16 03:231.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 03:231.0 U 0.19Toluene 0.19 1 05/06/16 03:231.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 03:235.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:07 AM 16-0000374636 rev 00Superset Reference: Page 44 of 141 J1603049-007Lab Code: Sample Name:MW-21 Volatile Organic Compounds by GC/MS 04/26/16 09:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 03:231.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 03:23100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 03:231.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 03:2320 U1.9Vinyl Acetate 1.9 1 05/06/16 03:2350 U 0.36Vinyl Chloride 0.36 1 05/06/16 03:231.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 03:2372 - 1211051,2-Dichloroethane-d4 05/06/16 03:2386 - 1131054-Bromofluorobenzene 05/06/16 03:2386 - 112102Dibromofluoromethane 05/06/16 03:2388 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:07 AM 16-0000374636 rev 00Superset Reference: Page 45 of 141 J1603049-007Lab Code: Sample Name:MW-21 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 09:10 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007111,2-Dibromo-3-chloropropane (DBCP)0.00711 1 05/03/16 12:24 5/2/160.0203 U 0.007111,2-Dibromoethane (EDB)0.00711 1 05/03/16 12:24 5/2/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 12:2470 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 46 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 09:10 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-21 Lab Code:J1603049-007 Antimony, Total 05/05/16 23:41 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/05/16 23:41 05/02/1610.510 J26020A ug/L Barium, Total 05/03/16 21:25 05/03/1610.3100 J606010C ug/L Beryllium, Total 05/05/16 23:41 05/02/1610.041.0 J0.056020A ug/L Cadmium, Total 05/05/16 23:41 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/05/16 23:41 05/02/1610.210 J16020A ug/L Cobalt, Total 05/05/16 23:41 05/02/1610.0310 J16020A ug/L Copper, Total 05/05/16 23:41 05/02/1610.310 J26020A ug/L Lead, Total 05/05/16 23:41 05/02/1610.210 J16020A ug/L Mercury, Total 05/04/16 12:41 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 23:41 05/02/1610.550 J26020A ug/L Selenium, Total 05/05/16 23:41 05/02/161210 U26020A ug/L Silver, Total 05/03/16 21:25 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:41 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 21:25 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:41 05/02/161210 J66020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 47 of 141 J1603049-008Lab Code: Sample Name:MW-22 Volatile Organic Compounds by GC/MS 04/26/16 08:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 03:475.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 03:471.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 03:473.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 03:471.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 03:475.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 03:475.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 03:472.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 03:4713 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 03:471.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 03:475.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 03:471.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 03:471.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 03:471.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 03:47100 U2.22-Hexanone 2.2 1 05/06/16 03:4750 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 03:47100 U5.6Acetone 5.6 1 05/06/16 03:47100 U 1.5Acrylonitrile 1.5 1 05/06/16 03:47200 U0.21Benzene 0.21 1 05/06/16 03:471.0 U 0.27Bromochloromethane 0.27 1 05/06/16 03:475.0 U0.22Bromodichloromethane 0.22 1 05/06/16 03:471.0 U 0.42Bromoform 0.42 1 05/06/16 03:473.0 U0.23Bromomethane 0.23 1 05/06/16 03:4710 U 2.4Carbon Disulfide 2.4 1 05/06/16 03:47100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 03:471.0 U 0.16Chlorobenzene 0.16 1 05/06/16 03:473.0 U0.52Chloroethane 0.52 1 05/06/16 03:4710 U 0.35Chloroform 0.35 1 05/06/16 03:475.0 U0.36Chloromethane 0.36 1 05/06/16 03:471.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 03:475.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 03:471.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 03:473.0 U0.36Dibromomethane 0.36 1 05/06/16 03:4710 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 03:4720 U0.21Ethylbenzene 0.21 1 05/06/16 03:471.0 U 2.7Iodomethane 2.7 1 05/06/16 03:4710 U0.31m,p-Xylenes 0.31 1 05/06/16 03:472.0 U 0.21Methylene Chloride 0.21 1 05/06/16 03:475.0 U0.14o-Xylene 0.14 1 05/06/16 03:471.0 U 0.29Styrene 0.29 1 05/06/16 03:471.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 03:471.0 U 0.19Toluene 0.19 1 05/06/16 03:471.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 03:475.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:07 AM 16-0000374636 rev 00Superset Reference: Page 48 of 141 J1603049-008Lab Code: Sample Name:MW-22 Volatile Organic Compounds by GC/MS 04/26/16 08:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 03:471.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 03:47100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 03:471.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 03:4720 U1.9Vinyl Acetate 1.9 1 05/06/16 03:4750 U 0.36Vinyl Chloride 0.36 1 05/06/16 03:471.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 03:4772 - 1211051,2-Dichloroethane-d4 05/06/16 03:4786 - 1131074-Bromofluorobenzene 05/06/16 03:4786 - 112105Dibromofluoromethane 05/06/16 03:4788 - 11597Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:07 AM 16-0000374636 rev 00Superset Reference: Page 49 of 141 J1603049-008Lab Code: Sample Name:MW-22 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 08:20 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007171,2-Dibromo-3-chloropropane (DBCP)0.00717 1 05/03/16 12:50 5/2/160.0205 U 0.007171,2-Dibromoethane (EDB)0.00717 1 05/03/16 12:50 5/2/160.0205 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 12:5070 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 50 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 08:20 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-22 Lab Code:J1603049-008 Antimony, Total 05/05/16 23:47 05/02/1620.412 U0.46020A ug/L Arsenic, Total 05/05/16 23:47 05/02/1620.920 J56020A ug/L Barium, Total 05/03/16 21:30 05/03/1610.31002406010Cug/L Beryllium, Total 05/05/16 23:47 05/02/1620.072.0 U0.076020A ug/L Cadmium, Total 05/05/16 23:47 05/02/1620.22.0 U0.26020A ug/L Chromium, Total 05/05/16 23:47 05/02/1620.420 J0.86020A ug/L Cobalt, Total 05/05/16 23:47 05/02/1620.0620 J56020A ug/L Copper, Total 05/05/16 23:47 05/02/1620.520 J26020A ug/L Lead, Total 05/05/16 23:47 05/02/1620.320 J0.86020A ug/L Mercury, Total 05/04/16 12:42 05/02/1610.020.20 J0.037470A ug/L Nickel, Total 05/05/16 23:47 05/02/1621.0100 J56020A ug/L Selenium, Total 05/05/16 23:47 05/02/162320 U36020A ug/L Silver, Total 05/03/16 21:30 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/05/16 23:47 05/02/1620.111 U0.16020A ug/L Vanadium, Total 05/03/16 21:30 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 23:47 05/02/162420 J96020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 51 of 141 J1603049-009Lab Code: Sample Name:MW-23 Volatile Organic Compounds by GC/MS 04/26/16 08:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 04:105.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 04:101.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 04:103.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 04:101.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 04:105.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 04:105.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 04:102.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 04:1013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 04:101.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 04:105.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 04:101.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 04:101.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 04:101.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 04:10100 U2.22-Hexanone 2.2 1 05/06/16 04:1050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 04:10100 U6.0Acetone 5.6 1 05/06/16 04:10100 J 1.5Acrylonitrile 1.5 1 05/06/16 04:10200 U0.21Benzene 0.21 1 05/06/16 04:101.0 U 0.27Bromochloromethane 0.27 1 05/06/16 04:105.0 U0.22Bromodichloromethane 0.22 1 05/06/16 04:101.0 U 0.42Bromoform 0.42 1 05/06/16 04:103.0 U0.23Bromomethane 0.23 1 05/06/16 04:1010 U 2.4Carbon Disulfide 2.4 1 05/06/16 04:10100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 04:101.0 U 0.16Chlorobenzene 0.16 1 05/06/16 04:103.0 U0.52Chloroethane 0.52 1 05/06/16 04:1010 U 0.35Chloroform 0.35 1 05/06/16 04:105.0 U0.36Chloromethane 0.36 1 05/06/16 04:101.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 04:105.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 04:101.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 04:103.0 U0.36Dibromomethane 0.36 1 05/06/16 04:1010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 04:1020 U0.21Ethylbenzene 0.21 1 05/06/16 04:101.0 U 2.7Iodomethane 2.7 1 05/06/16 04:1010 U0.31m,p-Xylenes 0.31 1 05/06/16 04:102.0 U 0.21Methylene Chloride 0.21 1 05/06/16 04:105.0 U0.14o-Xylene 0.14 1 05/06/16 04:101.0 U 0.29Styrene 0.29 1 05/06/16 04:101.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 04:101.0 U 0.19Toluene 0.19 1 05/06/16 04:101.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 04:105.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:07 AM 16-0000374636 rev 00Superset Reference: Page 52 of 141 J1603049-009Lab Code: Sample Name:MW-23 Volatile Organic Compounds by GC/MS 04/26/16 08:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 04:101.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 04:10100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 04:101.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 04:1020 U1.9Vinyl Acetate 1.9 1 05/06/16 04:1050 U 0.36Vinyl Chloride 0.36 1 05/06/16 04:101.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 04:1072 - 1211041,2-Dichloroethane-d4 05/06/16 04:1086 - 1131014-Bromofluorobenzene 05/06/16 04:1086 - 112102Dibromofluoromethane 05/06/16 04:1088 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:08 AM 16-0000374636 rev 00Superset Reference: Page 53 of 141 J1603049-009Lab Code: Sample Name:MW-23 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 08:10 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007081,2-Dibromo-3-chloropropane (DBCP)0.00708 1 05/03/16 13:15 5/2/160.0202 U 0.007081,2-Dibromoethane (EDB)0.00708 1 05/03/16 13:15 5/2/160.0202 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 13:1570 - 130811,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 54 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 08:10 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-23 Lab Code:J1603049-009 Antimony, Total 05/06/16 00:03 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:03 05/02/165350 U36020A ug/L Barium, Total 05/03/16 21:46 05/03/1610.31002606010Cug/L Beryllium, Total 05/06/16 00:03 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/06/16 00:03 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:03 05/02/1650.950 U0.96020A ug/L Cobalt, Total 05/06/16 00:03 05/02/1650.250 J16020A ug/L Copper, Total 05/06/16 00:03 05/02/165250 U26020A ug/L Lead, Total 05/06/16 00:03 05/02/1650.650 U0.66020A ug/L Mercury, Total 05/04/16 12:50 05/02/1610.020.20 J0.057470A ug/L Nickel, Total 05/06/16 00:03 05/02/1653250 U36020A ug/L Selenium, Total 05/06/16 00:03 05/02/165650 U66020A ug/L Silver, Total 05/03/16 21:46 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:03 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 21:46 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:03 05/02/165850 J126020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:23 AM 16-0000374636 rev 00Superset Reference: Page 55 of 141 J1603049-010Lab Code: Sample Name:MW-24 Volatile Organic Compounds by GC/MS 04/25/16 12:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 04:335.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 04:331.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 04:333.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 04:331.0 U2.01,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 04:335.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 04:335.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 04:332.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 04:3313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 04:331.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 04:335.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 04:331.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 04:331.0 U0.251,4-Dichlorobenzene 0.16 1 05/06/16 04:331.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 04:33100 U2.22-Hexanone 2.2 1 05/06/16 04:3350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 04:33100 U7.6Acetone 5.6 1 05/06/16 04:33100 J 1.5Acrylonitrile 1.5 1 05/06/16 04:33200 U0.21Benzene 0.21 1 05/06/16 04:331.0 U 0.27Bromochloromethane 0.27 1 05/06/16 04:335.0 U0.22Bromodichloromethane 0.22 1 05/06/16 04:331.0 U 0.42Bromoform 0.42 1 05/06/16 04:333.0 U0.23Bromomethane 0.23 1 05/06/16 04:3310 U 2.4Carbon Disulfide 2.4 1 05/06/16 04:33100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 04:331.0 U 0.16Chlorobenzene 0.16 1 05/06/16 04:333.0 U0.52Chloroethane 0.52 1 05/06/16 04:3310 U 0.35Chloroform 0.35 1 05/06/16 04:335.0 U0.36Chloromethane 0.36 1 05/06/16 04:331.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 04:335.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 04:331.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 04:333.0 U0.36Dibromomethane 0.36 1 05/06/16 04:3310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 04:3320 U0.21Ethylbenzene 0.21 1 05/06/16 04:331.0 U 2.7Iodomethane 2.7 1 05/06/16 04:3310 U0.31m,p-Xylenes 0.31 1 05/06/16 04:332.0 U 0.21Methylene Chloride 0.21 1 05/06/16 04:335.0 U0.54o-Xylene 0.14 1 05/06/16 04:331.0 J 0.29Styrene 0.29 1 05/06/16 04:331.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 04:331.0 U 0.19Toluene 0.19 1 05/06/16 04:331.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 04:335.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:08 AM 16-0000374636 rev 00Superset Reference: Page 56 of 141 J1603049-010Lab Code: Sample Name:MW-24 Volatile Organic Compounds by GC/MS 04/25/16 12:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 04:331.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 04:33100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 04:331.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 04:3320 U1.9Vinyl Acetate 1.9 1 05/06/16 04:3350 U 0.36Vinyl Chloride 0.36 1 05/06/16 04:331.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 04:3372 - 1211031,2-Dichloroethane-d4 05/06/16 04:3386 - 1131064-Bromofluorobenzene 05/06/16 04:3386 - 112102Dibromofluoromethane 05/06/16 04:3388 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:08 AM 16-0000374636 rev 00Superset Reference: Page 57 of 141 J1603049-010Lab Code: Sample Name:MW-24 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/25/16 12:00 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007081,2-Dibromo-3-chloropropane (DBCP)0.00708 1 05/03/16 13:40 5/2/160.0202 U 0.007081,2-Dibromoethane (EDB)0.00708 1 05/03/16 13:40 5/2/160.0202 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 13:4070 - 130771,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 58 of 141 Client: 04/28/16 09:55 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/25/16 12:00 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-24 Lab Code:J1603049-010 Antimony, Total 05/06/16 00:08 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:08 05/02/165350 J76020A ug/L Barium, Total 05/03/16 21:51 05/03/1610.31001406010Cug/L Beryllium, Total 05/06/16 00:08 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/06/16 00:08 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:08 05/02/1650.950 J36020A ug/L Cobalt, Total 05/06/16 00:08 05/02/1650.250 J26020A ug/L Copper, Total 05/06/16 00:08 05/02/165250 J46020A ug/L Lead, Total 05/06/16 00:08 05/02/1650.650 J16020A ug/L Mercury, Total 05/04/16 12:51 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 00:08 05/02/1653250 J106020A ug/L Selenium, Total 05/06/16 00:08 05/02/165650 U66020A ug/L Silver, Total 05/03/16 21:51 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:08 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 21:51 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:08 05/02/165850 J186020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 59 of 141 J1603049-011Lab Code: Sample Name:MW-25 Volatile Organic Compounds by GC/MS 04/26/16 08:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 04:575.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 04:571.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 04:573.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 04:571.0 U2.91,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 04:575.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 04:575.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 04:572.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 04:5713 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 04:571.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 04:575.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 04:571.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 04:571.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 04:571.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 04:57100 U2.22-Hexanone 2.2 1 05/06/16 04:5750 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 04:57100 U12Acetone 5.6 1 05/06/16 04:57100 J 1.5Acrylonitrile 1.5 1 05/06/16 04:57200 U1.2Benzene 0.21 1 05/06/16 04:571.0 0.27Bromochloromethane 0.27 1 05/06/16 04:575.0 U0.22Bromodichloromethane 0.22 1 05/06/16 04:571.0 U 0.42Bromoform 0.42 1 05/06/16 04:573.0 U0.23Bromomethane 0.23 1 05/06/16 04:5710 U 2.4Carbon Disulfide 2.4 1 05/06/16 04:57100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 04:571.0 U 0.16Chlorobenzene 0.16 1 05/06/16 04:573.0 U0.52Chloroethane 0.52 1 05/06/16 04:5710 U 0.35Chloroform 0.35 1 05/06/16 04:575.0 U0.36Chloromethane 0.36 1 05/06/16 04:571.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 04:575.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 04:571.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 04:573.0 U0.36Dibromomethane 0.36 1 05/06/16 04:5710 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 04:5720 U0.21Ethylbenzene 0.21 1 05/06/16 04:571.0 U 2.7Iodomethane 2.7 1 05/06/16 04:5710 U0.31m,p-Xylenes 0.31 1 05/06/16 04:572.0 U 0.21Methylene Chloride 0.21 1 05/06/16 04:575.0 U0.14o-Xylene 0.14 1 05/06/16 04:571.0 U 0.29Styrene 0.29 1 05/06/16 04:571.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 04:571.0 U 0.19Toluene 0.19 1 05/06/16 04:571.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 04:575.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:08 AM 16-0000374636 rev 00Superset Reference: Page 60 of 141 J1603049-011Lab Code: Sample Name:MW-25 Volatile Organic Compounds by GC/MS 04/26/16 08:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 04:571.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 04:57100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 04:571.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 04:5720 U1.9Vinyl Acetate 1.9 1 05/06/16 04:5750 U 0.36Vinyl Chloride 0.36 1 05/06/16 04:571.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 04:5772 - 1211041,2-Dichloroethane-d4 05/06/16 04:5786 - 1131064-Bromofluorobenzene 05/06/16 04:5786 - 112102Dibromofluoromethane 05/06/16 04:5788 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:08 AM 16-0000374636 rev 00Superset Reference: Page 61 of 141 J1603049-011Lab Code: Sample Name:MW-25 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 08:40 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 14:06 5/2/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 14:06 5/2/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 14:0670 - 130871,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 62 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 08:40 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-25 Lab Code:J1603049-011 Antimony, Total 05/06/16 00:13 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:13 05/02/165350 U36020A ug/L Barium, Total 05/03/16 21:56 05/03/1610.31008306010Cug/L Beryllium, Total 05/06/16 00:13 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/06/16 00:13 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:13 05/02/1650.950 U0.96020A ug/L Cobalt, Total 05/06/16 00:13 05/02/1650.250 J0.76020A ug/L Copper, Total 05/06/16 00:13 05/02/165250 U26020A ug/L Lead, Total 05/06/16 00:13 05/02/1650.650 U0.66020A ug/L Mercury, Total 05/04/16 12:53 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 00:13 05/02/1653250 J86020A ug/L Selenium, Total 05/06/16 00:13 05/02/165650 U66020A ug/L Silver, Total 05/03/16 21:56 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:13 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 21:56 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:13 05/02/165850 U86020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 63 of 141 J1603049-012Lab Code: Sample Name:MW-26 Volatile Organic Compounds by GC/MS 04/26/16 09:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 05:205.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 05:201.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 05:203.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 05:201.0 U0.701,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 05:205.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 05:205.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 05:202.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 05:2013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 05:201.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 05:205.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 05:201.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 05:201.0 U0.621,4-Dichlorobenzene 0.16 1 05/06/16 05:201.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 05:20100 U2.22-Hexanone 2.2 1 05/06/16 05:2050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 05:20100 U9.6Acetone 5.6 1 05/06/16 05:20100 J 1.5Acrylonitrile 1.5 1 05/06/16 05:20200 U1.4Benzene 0.21 1 05/06/16 05:201.0 0.27Bromochloromethane 0.27 1 05/06/16 05:205.0 U0.22Bromodichloromethane 0.22 1 05/06/16 05:201.0 U 0.42Bromoform 0.42 1 05/06/16 05:203.0 U0.23Bromomethane 0.23 1 05/06/16 05:2010 U 2.4Carbon Disulfide 2.4 1 05/06/16 05:20100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 05:201.0 U 1.5Chlorobenzene 0.16 1 05/06/16 05:203.0 J0.52Chloroethane 0.52 1 05/06/16 05:2010 U 0.35Chloroform 0.35 1 05/06/16 05:205.0 U0.36Chloromethane 0.36 1 05/06/16 05:201.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 05:205.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 05:201.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 05:203.0 U0.36Dibromomethane 0.36 1 05/06/16 05:2010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 05:2020 U0.21Ethylbenzene 0.21 1 05/06/16 05:201.0 U 2.7Iodomethane 2.7 1 05/06/16 05:2010 U0.31m,p-Xylenes 0.31 1 05/06/16 05:202.0 U 0.21Methylene Chloride 0.21 1 05/06/16 05:205.0 U0.14o-Xylene 0.14 1 05/06/16 05:201.0 U 0.29Styrene 0.29 1 05/06/16 05:201.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 05:201.0 U 0.19Toluene 0.19 1 05/06/16 05:201.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 05:205.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 64 of 141 J1603049-012Lab Code: Sample Name:MW-26 Volatile Organic Compounds by GC/MS 04/26/16 09:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 05:201.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 05:20100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 05:201.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 05:2020 U1.9Vinyl Acetate 1.9 1 05/06/16 05:2050 U 0.36Vinyl Chloride 0.36 1 05/06/16 05:201.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 05:2072 - 1211041,2-Dichloroethane-d4 05/06/16 05:2086 - 1131074-Bromofluorobenzene 05/06/16 05:2086 - 112102Dibromofluoromethane 05/06/16 05:2088 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 65 of 141 J1603049-012Lab Code: Sample Name:MW-26 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 09:20 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 14:31 5/2/160.0196 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 14:31 5/2/160.0196 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 14:3170 - 130711,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 66 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 09:20 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-26 Lab Code:J1603049-012 Antimony, Total 05/06/16 00:19 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:19 05/02/165350 U36020A ug/L Barium, Total 05/03/16 22:01 05/03/1610.31001806010Cug/L Beryllium, Total 05/06/16 00:19 05/02/1650.25.0 J1.16020A ug/L Cadmium, Total 05/06/16 00:19 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:19 05/02/1650.950 J26020A ug/L Cobalt, Total 05/06/16 00:19 05/02/1650.250 J296020A ug/L Copper, Total 05/06/16 00:19 05/02/165250 J26020A ug/L Lead, Total 05/06/16 00:19 05/02/1650.650 J0.96020A ug/L Mercury, Total 05/04/16 12:55 05/02/1610.020.20 J0.037470A ug/L Nickel, Total 05/06/16 00:19 05/02/1653250 J106020A ug/L Selenium, Total 05/06/16 00:19 05/02/165650 U66020A ug/L Silver, Total 05/03/16 22:01 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:19 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 22:01 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:19 05/02/165850 J366020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 67 of 141 J1603049-013Lab Code: Sample Name:MW-27 Volatile Organic Compounds by GC/MS 04/26/16 10:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 05:445.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 05:441.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 05:443.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 05:441.0 U7.61,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 05:445.0 1.31,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 05:445.0 J0.421,2,3-Trichloropropane 0.42 1 05/06/16 05:442.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 05:4413 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 05:441.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 05:445.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 05:441.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 05:441.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 05:441.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 05:44100 U2.22-Hexanone 2.2 1 05/06/16 05:4450 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 05:44100 U5.6Acetone 5.6 1 05/06/16 05:44100 U 1.5Acrylonitrile 1.5 1 05/06/16 05:44200 U0.21Benzene 0.21 1 05/06/16 05:441.0 U 0.27Bromochloromethane 0.27 1 05/06/16 05:445.0 U0.22Bromodichloromethane 0.22 1 05/06/16 05:441.0 U 0.42Bromoform 0.42 1 05/06/16 05:443.0 U0.23Bromomethane 0.23 1 05/06/16 05:4410 U 2.4Carbon Disulfide 2.4 1 05/06/16 05:44100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 05:441.0 U 0.16Chlorobenzene 0.16 1 05/06/16 05:443.0 U0.52Chloroethane 0.52 1 05/06/16 05:4410 U 0.44Chloroform 0.35 1 05/06/16 05:445.0 J0.36Chloromethane 0.36 1 05/06/16 05:441.0 U 0.37cis-1,2-Dichloroethene 0.36 1 05/06/16 05:445.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 05:441.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 05:443.0 U0.36Dibromomethane 0.36 1 05/06/16 05:4410 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 05:4420 U0.21Ethylbenzene 0.21 1 05/06/16 05:441.0 U 2.7Iodomethane 2.7 1 05/06/16 05:4410 U0.31m,p-Xylenes 0.31 1 05/06/16 05:442.0 U 0.21Methylene Chloride 0.21 1 05/06/16 05:445.0 U0.14o-Xylene 0.14 1 05/06/16 05:441.0 U 0.29Styrene 0.29 1 05/06/16 05:441.0 U0.67Tetrachloroethene (PCE)0.22 1 05/06/16 05:441.0 J 0.19Toluene 0.19 1 05/06/16 05:441.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 05:445.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 68 of 141 J1603049-013Lab Code: Sample Name:MW-27 Volatile Organic Compounds by GC/MS 04/26/16 10:10 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 05:441.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 05:44100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 05:441.0 U 0.88Trichlorofluoromethane 0.24 1 05/06/16 05:4420 J1.9Vinyl Acetate 1.9 1 05/06/16 05:4450 U 0.36Vinyl Chloride 0.36 1 05/06/16 05:441.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 05:4472 - 1211031,2-Dichloroethane-d4 05/06/16 05:4486 - 1131024-Bromofluorobenzene 05/06/16 05:4486 - 112103Dibromofluoromethane 05/06/16 05:4488 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 69 of 141 J1603049-013Lab Code: Sample Name:MW-27 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 10:10 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 14:56 5/2/160.0199 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 14:56 5/2/160.0199 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 14:5670 - 130891,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 70 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 10:10 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-27 Lab Code:J1603049-013 Antimony, Total 05/06/16 00:24 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:24 05/02/165350 J186020A ug/L Barium, Total 05/03/16 22:06 05/03/1610.31001606010Cug/L Beryllium, Total 05/06/16 00:24 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/06/16 00:24 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:24 05/02/1650.950 U0.96020A ug/L Cobalt, Total 05/06/16 00:24 05/02/1650.250 J116020A ug/L Copper, Total 05/06/16 00:24 05/02/165250 U26020A ug/L Lead, Total 05/06/16 00:24 05/02/1650.650 U0.66020A ug/L Mercury, Total 05/04/16 13:00 05/02/1610.020.20 J0.027470A ug/L Nickel, Total 05/06/16 00:24 05/02/1653250 J46020A ug/L Selenium, Total 05/06/16 00:24 05/02/165650 U66020A ug/L Silver, Total 05/03/16 22:06 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:24 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 22:06 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:24 05/02/165850 J106020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 71 of 141 J1603049-014Lab Code: Sample Name:MW-28 Volatile Organic Compounds by GC/MS 04/26/16 10:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 06:075.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 06:071.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 06:073.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 06:071.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 06:075.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 06:075.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 06:072.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 06:0713 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 06:071.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 06:075.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 06:071.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 06:071.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 06:071.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 06:07100 U2.22-Hexanone 2.2 1 05/06/16 06:0750 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 06:07100 U5.6Acetone 5.6 1 05/06/16 06:07100 U 1.5Acrylonitrile 1.5 1 05/06/16 06:07200 U0.21Benzene 0.21 1 05/06/16 06:071.0 U 0.27Bromochloromethane 0.27 1 05/06/16 06:075.0 U0.22Bromodichloromethane 0.22 1 05/06/16 06:071.0 U 0.42Bromoform 0.42 1 05/06/16 06:073.0 U0.23Bromomethane 0.23 1 05/06/16 06:0710 U 2.4Carbon Disulfide 2.4 1 05/06/16 06:07100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 06:071.0 U 0.16Chlorobenzene 0.16 1 05/06/16 06:073.0 U0.52Chloroethane 0.52 1 05/06/16 06:0710 U 1.8Chloroform 0.35 1 05/06/16 06:075.0 J0.36Chloromethane 0.36 1 05/06/16 06:071.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 06:075.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 06:071.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 06:073.0 U0.36Dibromomethane 0.36 1 05/06/16 06:0710 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 06:0720 U0.21Ethylbenzene 0.21 1 05/06/16 06:071.0 U 2.7Iodomethane 2.7 1 05/06/16 06:0710 U0.31m,p-Xylenes 0.31 1 05/06/16 06:072.0 U 0.21Methylene Chloride 0.21 1 05/06/16 06:075.0 U0.43o-Xylene 0.14 1 05/06/16 06:071.0 J 0.29Styrene 0.29 1 05/06/16 06:071.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 06:071.0 U 0.19Toluene 0.19 1 05/06/16 06:071.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 06:075.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 72 of 141 J1603049-014Lab Code: Sample Name:MW-28 Volatile Organic Compounds by GC/MS 04/26/16 10:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 06:071.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 06:07100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 06:071.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 06:0720 U1.9Vinyl Acetate 1.9 1 05/06/16 06:0750 U 0.36Vinyl Chloride 0.36 1 05/06/16 06:071.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 06:0772 - 1211041,2-Dichloroethane-d4 05/06/16 06:0786 - 1131094-Bromofluorobenzene 05/06/16 06:0786 - 112103Dibromofluoromethane 05/06/16 06:0788 - 11598Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:09 AM 16-0000374636 rev 00Superset Reference: Page 73 of 141 J1603049-014Lab Code: Sample Name:MW-28 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 10:40 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007081,2-Dibromo-3-chloropropane (DBCP)0.00708 1 05/03/16 15:22 5/2/160.0202 U 0.007081,2-Dibromoethane (EDB)0.00708 1 05/03/16 15:22 5/2/160.0202 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 15:2270 - 130891,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 74 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 10:40 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-28 Lab Code:J1603049-014 Antimony, Total 05/06/16 00:30 05/02/1650.830 U0.86020A ug/L Arsenic, Total 05/06/16 00:30 05/02/165350 J56020A ug/L Barium, Total 05/03/16 22:30 05/03/1610.31003006010Cug/L Beryllium, Total 05/06/16 00:30 05/02/1650.25.0 U0.26020A ug/L Cadmium, Total 05/06/16 00:30 05/02/1650.55.0 U0.56020A ug/L Chromium, Total 05/06/16 00:30 05/02/1650.950 U0.96020A ug/L Cobalt, Total 05/06/16 00:30 05/02/1650.250 J0.46020A ug/L Copper, Total 05/06/16 00:30 05/02/165250 U26020A ug/L Lead, Total 05/06/16 00:30 05/02/1650.650 U0.66020A ug/L Mercury, Total 05/04/16 13:01 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 00:30 05/02/1653250 U36020A ug/L Selenium, Total 05/06/16 00:30 05/02/165650 U66020A ug/L Silver, Total 05/03/16 22:30 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 00:30 05/02/1650.328 U0.36020A ug/L Vanadium, Total 05/03/16 22:30 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 00:30 05/02/165850 U86020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 75 of 141 J1603049-015Lab Code: Sample Name:DUP Volatile Organic Compounds by GC/MS 04/26/16 08:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 06:305.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 06:301.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 06:303.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 06:301.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 06:305.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 06:305.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 06:302.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 06:3013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 06:301.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 06:305.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 06:301.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 06:301.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 06:301.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 06:30100 U2.22-Hexanone 2.2 1 05/06/16 06:3050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 06:30100 U5.6Acetone 5.6 1 05/06/16 06:30100 U 1.5Acrylonitrile 1.5 1 05/06/16 06:30200 U0.21Benzene 0.21 1 05/06/16 06:301.0 U 0.27Bromochloromethane 0.27 1 05/06/16 06:305.0 U0.22Bromodichloromethane 0.22 1 05/06/16 06:301.0 U 0.42Bromoform 0.42 1 05/06/16 06:303.0 U0.23Bromomethane 0.23 1 05/06/16 06:3010 U 2.4Carbon Disulfide 2.4 1 05/06/16 06:30100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 06:301.0 U 0.16Chlorobenzene 0.16 1 05/06/16 06:303.0 U0.52Chloroethane 0.52 1 05/06/16 06:3010 U 0.35Chloroform 0.35 1 05/06/16 06:305.0 U0.36Chloromethane 0.36 1 05/06/16 06:301.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 06:305.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 06:301.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 06:303.0 U0.36Dibromomethane 0.36 1 05/06/16 06:3010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 06:3020 U0.21Ethylbenzene 0.21 1 05/06/16 06:301.0 U 2.7Iodomethane 2.7 1 05/06/16 06:3010 U0.31m,p-Xylenes 0.31 1 05/06/16 06:302.0 U 0.21Methylene Chloride 0.21 1 05/06/16 06:305.0 U0.14o-Xylene 0.14 1 05/06/16 06:301.0 U 0.29Styrene 0.29 1 05/06/16 06:301.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 06:301.0 U 0.19Toluene 0.19 1 05/06/16 06:301.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 06:305.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 76 of 141 J1603049-015Lab Code: Sample Name:DUP Volatile Organic Compounds by GC/MS 04/26/16 08:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 06:301.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 06:30100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 06:301.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 06:3020 U1.9Vinyl Acetate 1.9 1 05/06/16 06:3050 U 0.36Vinyl Chloride 0.36 1 05/06/16 06:301.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 06:3072 - 1211021,2-Dichloroethane-d4 05/06/16 06:3086 - 1131044-Bromofluorobenzene 05/06/16 06:3086 - 112101Dibromofluoromethane 05/06/16 06:3088 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 77 of 141 J1603049-015Lab Code: Sample Name:DUP 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 08:00 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007161,2-Dibromo-3-chloropropane (DBCP)0.00716 1 05/03/16 16:12 5/2/160.0204 U 0.007161,2-Dibromoethane (EDB)0.00716 1 05/03/16 16:12 5/2/160.0204 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 16:1270 - 130841,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:16 AM 16-0000374636 rev 00Superset Reference: Page 78 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 08:00 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:DUP Lab Code:J1603049-015 Antimony, Total 05/06/16 01:07 05/02/1610.26.0 J0.46020A ug/L Arsenic, Total 05/06/16 01:07 05/02/1610.510 J16020A ug/L Barium, Total 05/03/16 22:46 05/03/1610.31001606010Cug/L Beryllium, Total 05/06/16 01:07 05/02/1610.041.0 J0.076020A ug/L Cadmium, Total 05/06/16 01:07 05/02/1610.101.0 J0.16020A ug/L Chromium, Total 05/06/16 01:07 05/02/1610.210 J26020A ug/L Cobalt, Total 05/06/16 01:07 05/02/1610.0310 J56020A ug/L Copper, Total 05/06/16 01:07 05/02/1610.310206020Aug/L Lead, Total 05/06/16 01:07 05/02/1610.210 J0.26020A ug/L Mercury, Total 05/04/16 13:03 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 01:07 05/02/1610.550 J156020A ug/L Selenium, Total 05/06/16 01:07 05/02/161210 U26020A ug/L Silver, Total 05/03/16 22:46 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 01:07 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 22:46 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 01:07 05/02/161210 J86020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:25 AM 16-0000374636 rev 00Superset Reference: Page 79 of 141 J1603049-016Lab Code: Sample Name:Trip Blank Volatile Organic Compounds by GC/MS 04/25/16 00:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 00:395.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 00:391.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 00:393.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 00:391.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 00:395.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 00:395.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 00:392.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 00:3913 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 00:391.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 00:395.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 00:391.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 00:391.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 00:391.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 00:39100 U2.22-Hexanone 2.2 1 05/06/16 00:3950 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 00:39100 U5.6Acetone 5.6 1 05/06/16 00:39100 U 1.5Acrylonitrile 1.5 1 05/06/16 00:39200 U0.21Benzene 0.21 1 05/06/16 00:391.0 U 0.27Bromochloromethane 0.27 1 05/06/16 00:395.0 U0.22Bromodichloromethane 0.22 1 05/06/16 00:391.0 U 0.42Bromoform 0.42 1 05/06/16 00:393.0 U0.23Bromomethane 0.23 1 05/06/16 00:3910 U 2.4Carbon Disulfide 2.4 1 05/06/16 00:39100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 00:391.0 U 0.16Chlorobenzene 0.16 1 05/06/16 00:393.0 U0.52Chloroethane 0.52 1 05/06/16 00:3910 U 0.35Chloroform 0.35 1 05/06/16 00:395.0 U0.36Chloromethane 0.36 1 05/06/16 00:391.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 00:395.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 00:391.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 00:393.0 U0.36Dibromomethane 0.36 1 05/06/16 00:3910 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 00:3920 U0.21Ethylbenzene 0.21 1 05/06/16 00:391.0 U 2.7Iodomethane 2.7 1 05/06/16 00:3910 U0.31m,p-Xylenes 0.31 1 05/06/16 00:392.0 U 0.21Methylene Chloride 0.21 1 05/06/16 00:395.0 U0.14o-Xylene 0.14 1 05/06/16 00:391.0 U 0.29Styrene 0.29 1 05/06/16 00:391.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 00:391.0 U 0.19Toluene 0.19 1 05/06/16 00:391.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 00:395.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 80 of 141 J1603049-016Lab Code: Sample Name:Trip Blank Volatile Organic Compounds by GC/MS 04/25/16 00:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 00:391.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 00:39100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 00:391.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 00:3920 U1.9Vinyl Acetate 1.9 1 05/06/16 00:3950 U 0.36Vinyl Chloride 0.36 1 05/06/16 00:391.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 00:3972 - 1211011,2-Dichloroethane-d4 05/06/16 00:3986 - 1131054-Bromofluorobenzene 05/06/16 00:3986 - 112101Dibromofluoromethane 05/06/16 00:3988 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 81 of 141 J1603049-017Lab Code: Sample Name:SW-1 Volatile Organic Compounds by GC/MS 04/26/16 13:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 06:545.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 06:541.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 06:543.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 06:541.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 06:545.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 06:545.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 06:542.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 06:5413 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 06:541.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 06:545.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 06:541.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 06:541.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 06:541.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 06:54100 U2.22-Hexanone 2.2 1 05/06/16 06:5450 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 06:54100 U5.6Acetone 5.6 1 05/06/16 06:54100 U 1.5Acrylonitrile 1.5 1 05/06/16 06:54200 U0.21Benzene 0.21 1 05/06/16 06:541.0 U 0.27Bromochloromethane 0.27 1 05/06/16 06:545.0 U0.22Bromodichloromethane 0.22 1 05/06/16 06:541.0 U 0.42Bromoform 0.42 1 05/06/16 06:543.0 U0.23Bromomethane 0.23 1 05/06/16 06:5410 U 2.4Carbon Disulfide 2.4 1 05/06/16 06:54100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 06:541.0 U 0.16Chlorobenzene 0.16 1 05/06/16 06:543.0 U0.52Chloroethane 0.52 1 05/06/16 06:5410 U 0.35Chloroform 0.35 1 05/06/16 06:545.0 U0.36Chloromethane 0.36 1 05/06/16 06:541.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 06:545.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 06:541.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 06:543.0 U0.36Dibromomethane 0.36 1 05/06/16 06:5410 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 06:5420 U0.21Ethylbenzene 0.21 1 05/06/16 06:541.0 U 2.7Iodomethane 2.7 1 05/06/16 06:5410 U0.31m,p-Xylenes 0.31 1 05/06/16 06:542.0 U 0.21Methylene Chloride 0.21 1 05/06/16 06:545.0 U0.14o-Xylene 0.14 1 05/06/16 06:541.0 U 0.29Styrene 0.29 1 05/06/16 06:541.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 06:541.0 U 0.19Toluene 0.19 1 05/06/16 06:541.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 06:545.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 82 of 141 J1603049-017Lab Code: Sample Name:SW-1 Volatile Organic Compounds by GC/MS 04/26/16 13:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 06:541.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 06:54100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 06:541.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 06:5420 U1.9Vinyl Acetate 1.9 1 05/06/16 06:5450 U 0.36Vinyl Chloride 0.36 1 05/06/16 06:541.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 06:5472 - 1211031,2-Dichloroethane-d4 05/06/16 06:5486 - 1131064-Bromofluorobenzene 05/06/16 06:5486 - 112101Dibromofluoromethane 05/06/16 06:5488 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:10 AM 16-0000374636 rev 00Superset Reference: Page 83 of 141 J1603049-017Lab Code: Sample Name:SW-1 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 13:00 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007041,2-Dibromo-3-chloropropane (DBCP)0.00704 1 05/03/16 16:37 5/2/160.0201 U 0.007041,2-Dibromoethane (EDB)0.00704 1 05/03/16 16:37 5/2/160.0201 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 16:3770 - 130761,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:17 AM 16-0000374636 rev 00Superset Reference: Page 84 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 13:00 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:SW-1 Lab Code:J1603049-017 Antimony, Total 05/06/16 01:12 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/06/16 01:12 05/02/1610.510 J0.76020A ug/L Barium, Total 05/03/16 22:51 05/03/1610.3100 J406010C ug/L Beryllium, Total 05/06/16 01:12 05/02/1610.041.0 U0.046020A ug/L Cadmium, Total 05/06/16 01:12 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/06/16 01:12 05/02/1610.210 U0.26020A ug/L Cobalt, Total 05/06/16 01:12 05/02/1610.0310 J0.36020A ug/L Copper, Total 05/06/16 01:12 05/02/1610.310 J16020A ug/L Lead, Total 05/06/16 01:12 05/02/1610.210 J0.36020A ug/L Mercury, Total 05/04/16 13:04 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 01:12 05/02/1610.550 J0.66020A ug/L Selenium, Total 05/06/16 01:12 05/02/161210 U26020A ug/L Silver, Total 05/03/16 22:51 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 01:12 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 22:51 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 01:12 05/02/161210 J36020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:25 AM 16-0000374636 rev 00Superset Reference: Page 85 of 141 J1603049-018Lab Code: Sample Name:SW-3 Volatile Organic Compounds by GC/MS 04/26/16 09:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 07:175.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 07:171.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 07:173.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 07:171.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 07:175.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 07:175.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 07:172.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 07:1713 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 07:171.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 07:175.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 07:171.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 07:171.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 07:171.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 07:17100 U2.22-Hexanone 2.2 1 05/06/16 07:1750 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 07:17100 U5.6Acetone 5.6 1 05/06/16 07:17100 U 1.5Acrylonitrile 1.5 1 05/06/16 07:17200 U0.21Benzene 0.21 1 05/06/16 07:171.0 U 0.27Bromochloromethane 0.27 1 05/06/16 07:175.0 U0.22Bromodichloromethane 0.22 1 05/06/16 07:171.0 U 0.42Bromoform 0.42 1 05/06/16 07:173.0 U0.23Bromomethane 0.23 1 05/06/16 07:1710 U 2.4Carbon Disulfide 2.4 1 05/06/16 07:17100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 07:171.0 U 0.16Chlorobenzene 0.16 1 05/06/16 07:173.0 U0.52Chloroethane 0.52 1 05/06/16 07:1710 U 0.35Chloroform 0.35 1 05/06/16 07:175.0 U0.36Chloromethane 0.36 1 05/06/16 07:171.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 07:175.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 07:171.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 07:173.0 U0.36Dibromomethane 0.36 1 05/06/16 07:1710 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 07:1720 U0.21Ethylbenzene 0.21 1 05/06/16 07:171.0 U 2.7Iodomethane 2.7 1 05/06/16 07:1710 U0.31m,p-Xylenes 0.31 1 05/06/16 07:172.0 U 0.21Methylene Chloride 0.21 1 05/06/16 07:175.0 U0.14o-Xylene 0.14 1 05/06/16 07:171.0 U 0.29Styrene 0.29 1 05/06/16 07:171.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 07:171.0 U 0.19Toluene 0.19 1 05/06/16 07:171.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 07:175.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:11 AM 16-0000374636 rev 00Superset Reference: Page 86 of 141 J1603049-018Lab Code: Sample Name:SW-3 Volatile Organic Compounds by GC/MS 04/26/16 09:40 NA ug/L Basis: Units: 8260BAnalysis Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 07:171.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 07:17100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 07:171.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 07:1720 U1.9Vinyl Acetate 1.9 1 05/06/16 07:1750 U 0.36Vinyl Chloride 0.36 1 05/06/16 07:171.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 07:1772 - 1211051,2-Dichloroethane-d4 05/06/16 07:1786 - 1131064-Bromofluorobenzene 05/06/16 07:1786 - 112103Dibromofluoromethane 05/06/16 07:1788 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:11 AM 16-0000374636 rev 00Superset Reference: Page 87 of 141 J1603049-018Lab Code: Sample Name:SW-3 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/26/16 09:40 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 17:03 5/2/160.0197 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 17:03 5/2/160.0197 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 17:0370 - 130801,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:17 AM 16-0000374636 rev 00Superset Reference: Page 88 of 141 Client: 04/27/16 10:05 J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/26/16 09:40 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:SW-3 Lab Code:J1603049-018 Antimony, Total 05/06/16 01:18 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/06/16 01:18 05/02/1610.510 U0.56020A ug/L Barium, Total 05/03/16 22:56 05/03/1610.3100 J406010C ug/L Beryllium, Total 05/06/16 01:18 05/02/1610.041.0 U0.046020A ug/L Cadmium, Total 05/06/16 01:18 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/06/16 01:18 05/02/1610.210 J0.36020A ug/L Cobalt, Total 05/06/16 01:18 05/02/1610.0310 J0.46020A ug/L Copper, Total 05/06/16 01:18 05/02/1610.310 J16020A ug/L Lead, Total 05/06/16 01:18 05/02/1610.210 J0.46020A ug/L Mercury, Total 05/04/16 13:06 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/06/16 01:18 05/02/1610.550 J0.76020A ug/L Selenium, Total 05/06/16 01:18 05/02/161210 U26020A ug/L Silver, Total 05/03/16 22:55 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/06/16 01:18 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 22:55 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/06/16 01:18 05/02/161210 J46020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:25 AM 16-0000374636 rev 00Superset Reference: Page 89 of 141 JQ1603516-05Lab Code: Sample Name:Method Blank Volatile Organic Compounds by GC/MS NA NA ug/L Basis: Units: 8260BAnalysis Method: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 00:165.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 00:161.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 00:163.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 00:161.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 00:165.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 00:165.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 00:162.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 00:1613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 00:161.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 00:165.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 00:161.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 00:161.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 00:161.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 00:16100 U2.22-Hexanone 2.2 1 05/06/16 00:1650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 00:16100 U5.6Acetone 5.6 1 05/06/16 00:16100 U 1.5Acrylonitrile 1.5 1 05/06/16 00:16200 U0.21Benzene 0.21 1 05/06/16 00:161.0 U 0.27Bromochloromethane 0.27 1 05/06/16 00:165.0 U0.22Bromodichloromethane 0.22 1 05/06/16 00:161.0 U 0.42Bromoform 0.42 1 05/06/16 00:163.0 U0.23Bromomethane 0.23 1 05/06/16 00:1610 U 2.4Carbon Disulfide 2.4 1 05/06/16 00:16100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 00:161.0 U 0.16Chlorobenzene 0.16 1 05/06/16 00:163.0 U0.52Chloroethane 0.52 1 05/06/16 00:1610 U 0.35Chloroform 0.35 1 05/06/16 00:165.0 U0.36Chloromethane 0.36 1 05/06/16 00:161.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 00:165.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 00:161.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 00:163.0 U0.36Dibromomethane 0.36 1 05/06/16 00:1610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 00:1620 U0.21Ethylbenzene 0.21 1 05/06/16 00:161.0 U 2.7Iodomethane 2.7 1 05/06/16 00:1610 U0.31m,p-Xylenes 0.31 1 05/06/16 00:162.0 U 0.21Methylene Chloride 0.21 1 05/06/16 00:165.0 U0.14o-Xylene 0.14 1 05/06/16 00:161.0 U 0.29Styrene 0.29 1 05/06/16 00:161.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 00:161.0 U 0.19Toluene 0.19 1 05/06/16 00:161.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 00:165.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:12 AM 16-0000374636 rev 00Superset Reference: Page 90 of 141 JQ1603516-05Lab Code: Sample Name:Method Blank Volatile Organic Compounds by GC/MS NA NA ug/L Basis: Units: 8260BAnalysis Method: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 00:161.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 00:16100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 00:161.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 00:1620 U1.9Vinyl Acetate 1.9 1 05/06/16 00:1650 U 0.36Vinyl Chloride 0.36 1 05/06/16 00:161.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 00:1672 - 1211021,2-Dichloroethane-d4 05/06/16 00:1686 - 1131054-Bromofluorobenzene 05/06/16 00:1686 - 112100Dibromofluoromethane 05/06/16 00:1688 - 115104Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:12 AM 16-0000374636 rev 00Superset Reference: Page 91 of 141 JQ1603355-01Lab Code: Sample Name:Method Blank 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography NA NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/02/16 21:44 5/2/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/02/16 21:44 5/2/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/02/16 21:4470 - 1301091,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:17 AM 16-0000374636 rev 00Superset Reference: Page 92 of 141 JQ1603357-01Lab Code: Sample Name:Method Blank 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography NA NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 08:37 5/2/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 08:37 5/2/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 08:3770 - 130991,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:17 AM 16-0000374636 rev 00Superset Reference: Page 93 of 141 RQ1604817-01Lab Code: Sample Name:Method Blank Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time NA NA mg/L Basis: Units: Organic AcidsAnalysis Method: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 14:190.50 U 0.50Acetic Acid 0.50 1 04/29/16 14:191.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 14:192.0 U 0.50Lactic Acid 0.50 1 04/29/16 14:191.0 U0.50Propionic Acid 0.50 1 04/29/16 14:191.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:20 AM 16-0000374636 rev 00Superset Reference: Page 94 of 141 Client: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:NA Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:Method Blank Lab Code:J1603049-MB Antimony, Total 05/05/16 22:59 05/02/1610.26.0 U0.26020A ug/L Arsenic, Total 05/05/16 22:59 05/02/1610.510 U0.56020A ug/L Barium, Total 05/03/16 20:40 05/03/1610.3100 U0.36010C ug/L Beryllium, Total 05/05/16 22:59 05/02/1610.041.0 U0.046020A ug/L Cadmium, Total 05/05/16 22:59 05/02/1610.101.0 U0.106020A ug/L Chromium, Total 05/05/16 22:59 05/02/1610.210 U0.26020A ug/L Cobalt, Total 05/05/16 22:59 05/02/1610.0310 U0.036020A ug/L Copper, Total 05/05/16 22:59 05/02/1610.310 U0.36020A ug/L Lead, Total 05/05/16 22:59 05/02/1610.210 U0.26020A ug/L Mercury, Total 05/04/16 12:25 05/02/1610.020.20 U0.027470A ug/L Nickel, Total 05/05/16 22:59 05/02/1610.550 U0.56020A ug/L Selenium, Total 05/05/16 22:59 05/02/161210 U26020A ug/L Silver, Total 05/03/16 20:40 05/03/1610.610 U0.66010C ug/L Sodium, Total 05/03/16 20:39 05/03/1610.040.50 U0.046010C mg/L Thallium, Total 05/05/16 22:59 05/02/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 20:40 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/05/16 22:59 05/02/161210 U26020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:25 AM 16-0000374636 rev 00Superset Reference: Page 95 of 141 Client: NA J1603049 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:NA General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:Method Blank Lab Code:J1603049-MB Alkalinity as CaCO3, Total 04/27/16 19:30 NA15.05.0 U5.0SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 04/27/16 19:30 NA15.05.0 U5.0SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/27/16 07:00 NA12.02.0 U2.0SM 5210 B mg/L Carbon, Total Organic (TOC)04/29/16 12:35 NA10.061.0 J0.09SM 5310 B mg/L Carbonate Alkalinity as CaCO3 04/27/16 19:30 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 13:56 05/05/1611220 U12SM21 5220 D mg/L Chloride 04/27/16 18:21 NA10.081.0 U0.08300.0 mg/L Nitrate as Nitrogen 04/27/16 18:21 NA10.040.20 U0.04300.0 mg/L Solids, Total Dissolved 04/29/16 12:09 NA11010 U10SM 2540 C mg/L Sulfate 04/29/16 00:26 NA10.061.0 U0.06300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/12/2016 8:30:29 AM 16-0000374636 rev 00Superset Reference: Page 96 of 141 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8260B Sample Name Lab Code 1,2-Dichloroethane-d4 4-Bromofluorobenzene Dibromofluoromethane 72 - 121 86 - 113 86 - 112 Volatile Organic Compounds by GC/MS MW-2 J1603049-001 103 105 103 MW-4 J1603049-002 103 105 102 MW-8 J1603049-003 101 105 101 MW-17 J1603049-004 100 107 102 MW-18 J1603049-005 101 104 103 MW-19 J1603049-006 102 110 102 MW-21 J1603049-007 102 105 105 MW-22 J1603049-008 105 107 105 MW-23 J1603049-009 102 101 104 MW-24 J1603049-010 102 106 103 MW-25 J1603049-011 102 106 104 MW-26 J1603049-012 102 107 104 MW-27 J1603049-013 103 102 103 MW-28 J1603049-014 103 109 104 DUP J1603049-015 101 104 102 Trip Blank J1603049-016 101 105 101 SW-1 J1603049-017 101 106 103 SW-3 J1603049-018 103 106 105 Lab Control Sample JQ1603516-03 101 100 99 Duplicate Lab Control Sample JQ1603516-04 101 99 98 Method Blank JQ1603516-05 100 105 102 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603049 dba ALS Environmental 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:13 AM Page 97 of 141 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8260B Sample Name Lab Code Toluene-d8 88 - 115 Volatile Organic Compounds by GC/MS MW-2 J1603049-001 102 MW-4 J1603049-002 102 MW-8 J1603049-003 103 MW-17 J1603049-004 104 MW-18 J1603049-005 101 MW-19 J1603049-006 99 MW-21 J1603049-007 103 MW-22 J1603049-008 97 MW-23 J1603049-009 102 MW-24 J1603049-010 102 MW-25 J1603049-011 102 MW-26 J1603049-012 103 MW-27 J1603049-013 102 MW-28 J1603049-014 98 DUP J1603049-015 103 Trip Blank J1603049-016 102 SW-1 J1603049-017 103 SW-3 J1603049-018 103 Lab Control Sample JQ1603516-03 101 Duplicate Lab Control Sample JQ1603516-04 101 Method Blank JQ1603516-05 104 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603049 dba ALS Environmental 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:13 AM Page 98 of 141 Duplicate Lab Control Sample JQ1603516-04 Lab Control Sample JQ1603516-03 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Volatile Organic Compounds by GC/MS Analysis Method:8260B NA ug/L Basis: Units: Analysis Lot:495094 05/05/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 55.4 50.01,1,1,2-Tetrachloroethane 30<1 77-118112 50.055.8 111 52.3 50.01,1,1-Trichloroethane (TCA)301 70-122104 50.051.8 105 51.6 50.01,1,2,2-Tetrachloroethane 30<1 66-135103 50.051.4 103 53.8 50.01,1,2-Trichloroethane 302 75-122105 50.052.7 108 56.5 50.01,1-Dichloroethane (1,1-DCA)30<1 79-117112 50.056.1 113 54.8 50.01,1-Dichloroethene (1,1-DCE)304 72-128114 50.056.8 110 51.6 50.01,2,3-Trichloropropane 302 70-123101 50.050.6 103 52.8 50.01,2-Dibromo-3-chloropropane (DBCP)305 60-122100 50.050.2 106 53.0 50.01,2-Dibromoethane (EDB)301 76-118105 50.052.4 106 56.0 50.01,2-Dichlorobenzene 304 81-115107 50.053.5 112 51.0 50.01,2-Dichloroethane 30<1 70-117103 50.051.4 102 53.2 50.01,2-Dichloropropane 302 79-117104 50.052.0 106 53.3 50.01,4-Dichlorobenzene 301 82-115108 50.053.9 107 49.3 J 50.02-Butanone (MEK)30<1 62-13899 50.049.3 J 99 50.0 J 50.02-Hexanone 301 74-12799 50.049.3 J 100 50.5 J 50.04-Methyl-2-pentanone (MIBK)302 77-12099 50.049.3 J 101 47.4 J 50.0Acetone 303 42-16198 50.048.8 J 95 50.1 J 50.0Acrylonitrile 302 63-132103 50.051.3 J 100 56.6 50.0Benzene 30<1 80-117113 50.056.3 113 55.4 50.0Bromochloromethane 30<1 78-118112 50.055.9 111 56.7 50.0Bromodichloromethane 301 75-118112 50.055.9 113 48.6 50.0Bromoform 302 63-12195 50.047.7 97 47.5 50.0Bromomethane 307 31-15389 50.044.3 95 50.1 J 50.0Carbon Disulfide 302 72-128102 50.051.2 J 100 52.1 50.0Carbon Tetrachloride 302 67-124102 50.051.1 104 55.2 50.0Chlorobenzene 302 83-118108 50.054.1 110 57.0 50.0Chloroethane 301 68-132113 50.056.4 114 55.8 50.0Chloroform 303 77-116109 50.054.3 112 50.2 50.0Chloromethane 302 60-12898 50.049.0 100 54.5 50.0cis-1,2-Dichloroethene 302 78-117107 50.053.3 109 49.7 50.0cis-1,3-Dichloropropene 301 80-11998 50.049.0 99 50.7 50.0Dibromochloromethane 302 74-12199 50.049.6 101 53.2 50.0Dibromomethane 301 76-117105 50.052.6 106 53.0 50.0Dichlorodifluoromethane 30<1 49-132106 50.052.9 106 58.3 50.0Ethylbenzene 301 82-119115 50.057.5 117 37.4 50.0Iodomethane 306 51-13771 50.035.4 75 103 100m,p-Xylenes 30<1 79-122103 100103 103 51.4 50.0Methylene Chloride 301 75-123101 50.050.7 103 51.4 50.0o-Xylene 302 80-119100 50.050.2 103 51.4 50.0Styrene 302 80-121101 50.050.6 103 58.1 50.0Tetrachloroethene (PCE)303 75-126112 50.056.1 116 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:12 AM Page 99 of 141 Duplicate Lab Control Sample JQ1603516-04 Lab Control Sample JQ1603516-03 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Volatile Organic Compounds by GC/MS Analysis Method:8260B NA ug/L Basis: Units: Analysis Lot:495094 05/05/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 56.9 50.0Toluene 302 52-152111 50.055.7 114 51.2 50.0trans-1,2-Dichloroethene 301 75-121101 50.050.7 102 50.3 50.0trans-1,3-Dichloropropene 302 76-11898 50.049.2 101 48.0 J 50.0trans-1,4-Dichloro-2-butene 303 10-19893 50.046.5 J 96 52.6 50.0Trichloroethene (TCE)301 78-122104 50.051.9 105 59.6 50.0Trichlorofluoromethane 301 58-134118 50.058.9 119 48.2 J 50.0Vinyl Acetate 302 36-16994 50.047.0 J 96 60.8 50.0Vinyl Chloride 303 69-138118 50.059.0 122 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:12 AM Page 100 of 141 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8011 Extraction Method:Method Sample Name Lab Code 1,1,1,2-Tetrachloroethane 70 - 130 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography MW-2 J1603049-001 80 MW-4 J1603049-002 84 MW-8 J1603049-003 82 MW-17 J1603049-004 85 MW-18 J1603049-005 83 MW-19 J1603049-006 78 MW-21 J1603049-007 83 MW-22 J1603049-008 83 MW-23 J1603049-009 81 MW-24 J1603049-010 77 MW-25 J1603049-011 87 MW-26 J1603049-012 71 MW-27 J1603049-013 89 MW-28 J1603049-014 89 DUP J1603049-015 84 SW-1 J1603049-017 76 SW-3 J1603049-018 80 Method Blank JQ1603355-01 109 Lab Control Sample JQ1603355-02 105 Method Blank JQ1603357-01 99 Lab Control Sample JQ1603357-02 99 MW-17 JQ1603357-03 90 MW-17 JQ1603357-04 91 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603049 dba ALS Environmental 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:18 AM Page 101 of 141 QA/QC Report ug/L J1603049-004 Basis:Lab Code: Units:Sample Name:MW-17 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 05/3/16 04/27/16 Date Collected:04/26/16 Method 8011 Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike JQ1603357-03 JQ1603357-04 Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/2/16Date Extracted: 1,2-Dibromo-3-chloropropane (DBCP)0.00711 U 0.237 0.255 93 0.215 0.254 85 65-135 10 20 1,2-Dibromoethane (EDB)0.00711 U 0.245 0.255 96 0.222 0.254 87 65-135 10 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:18 AM 16-0000374636 rev 00Superset Reference: Page 102 of 141 Duplicate Lab Control Sample RQ1604817-03 Lab Control Sample RQ1604817-02 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time Analysis Method:Organic Acids NA mg/L Basis: Units: Analysis Lot:494408 04/29/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 21.9 20.6Acetic Acid 304 70-130110 20.622.6 106 21.3 19.9Butanoic Acid (Butyric Acid)307 70-130115 19.922.9 107 21.3 20.0Lactic Acid 303 70-130109 20.021.8 106 20.9 20.0Propionic Acid 304 70-130109 20.021.8 104 2.06 2.01Pyruvic Acid 305 70-130107 2.012.16 102 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:21 AM Page 103 of 141 QA/QC Report ug/L J1603049-013 Basis:Lab Code: Units:Sample Name:MW-27 Inorganic Parameters Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 05/3/16 04/27/16 Date Collected:04/26/16 EPA 3005A 6010C Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike J1603049-013MS J1603049-013DMS Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/3/16Date Extracted: Barium, Total 160 670 500 102 670 500 101 75-125 <1 20 Silver, Total 0.6 U 523 500 105 520 500 104 75-125 <1 20 Vanadium, Total 1.0 U 996 1000 100 990 1000 99 75-125 <1 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:24 AM 16-0000374636 rev 00Superset Reference: Page 104 of 141 QA/QC Report ug/L J1603049-014 Basis:Lab Code: Units:Sample Name:MW-28 Inorganic Parameters Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 05/6/16 04/27/16 Date Collected:04/26/16 EPA 3005A 6020A Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike J1603049-014MS J1603049-014DMS Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/2/16Date Extracted: Antimony, Total 0.8 U 53 50 106 55 50 110 75-125 4 20 Arsenic, Total 5 J 55 50 101 54 50 99 75-125 2 20 Beryllium, Total 0.2 U 25.7 25.0 103 25.3 25.0 101 75-125 2 20 Cadmium, Total 0.5 U 20.3 20.0 101 20.3 20.0 102 75-125 <1 20 Chromium, Total 0.9 U 55 50 109 54 50 109 75-125 <1 20 Cobalt, Total 0.4 J 51 50 102 53 50 106 75-125 4 20 Copper, Total 2 U 53 50 105 52 50 103 75-125 2 20 Lead, Total 0.6 U 26 25 104 26 25 103 75-125 <1 20 Nickel, Total 3 U 100 100 103 110 100 105 75-125 2 20 Selenium, Total 6 U 102 100 102 104 100 104 75-125 2 20 Thallium, Total 0.3 U 10 10 104 10 10 100 75-125 3 20 Zinc, Total 8 U 272 250 109 281 250 112 75-125 3 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:25 AM 16-0000374636 rev 00Superset Reference: Page 105 of 141 QA/QC Report ug/L J1603049-008 Basis:Lab Code: Units:Sample Name:MW-22 Inorganic Parameters Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 05/4/16 04/27/16 Date Collected:04/26/16 Method 7470A Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike J1603049-008MS J1603049-008DMS Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/2/16Date Extracted: Mercury, Total 0.03 J 1.0 1.25 80 1.1 1.25 82 75-125 2 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:26 AM 16-0000374636 rev 00Superset Reference: Page 106 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603049-LCS 05/05/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Antimony, Total 80-120105 50.052.7 6020A Arsenic, Total 80-120101 5050.4 6020A Beryllium, Total 80-12098 25.024.5 6020A Cadmium, Total 80-12097 20.019.5 6020A Chromium, Total 80-120104 5051.8 6020A Cobalt, Total 80-120102 5050.9 6020A Copper, Total 80-120103 5051.5 6020A Lead, Total 80-120101 2525.3 6020A Nickel, Total 80-120101 100101 6020A Selenium, Total 80-120101 100101 6020A Thallium, Total 80-120104 10.010.4 6020A Zinc, Total 80-120102 250255 6020A 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:25 AM Page 107 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603049-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Barium, Total 80-120102 500511 6010C Silver, Total 80-120103 500514 6010C Vanadium, Total 80-120102 10001020 6010C 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:25 AM Page 108 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Sodium, Total 80-120100 25.025.1 6010C 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:25 AM Page 109 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603049-LCS 05/04/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Mercury, Total 80-120102 1.251.28 7470A 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:25 AM Page 110 of 141 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603049 04/26/16Date Collected: Date Received:04/27/16 04/27/16 - 04/29/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-8 mg/L Basis: Units: J1603049-003 NALab Code: Sample Name: RPD LimitPQLMDL Analysis Method RPD Duplicate Sample J1603049- 003DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Alkalinity as CaCO3, Total 2 5.0 5.0 141 138 140 20SM 2320 B Carbon, Total Organic (TOC)18 1.0 0.06 0.6 J 0.5 J 0.560 20SM 5310 B Chloride 2 1.0 0.08 5.2 5.1 5.11 20300.0 Nitrate as Nitrogen NC 0.20 0.04 0.06 J 0.04 U NC 20300.0 Solids, Total Dissolved 5 10 10 196 207 202 10SM 2540 C Bicarbonate Alkalinity as CaCO3 2 5.0 5.0 141 138 140 20SM 2320 B Carbonate Alkalinity as CaCO3 NC 5.0 5.0 5.0 U 5.0 U NC 20SM 2320 B Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:28 AM 16-0000374636 rev 00Superset Reference: Page 111 of 141 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603049 04/26/16Date Collected: Date Received:04/27/16 05/03/16 - 05/05/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-2 mg/L Basis: Units: J1603049-001 NALab Code: Sample Name: RPD LimitPQLMDLAnalysis Method RPD Duplicate Sample J1603049- 001DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Chemical Oxygen Demand, Total 3 20 12 42 41 41.4 5SM21 5220 D Sulfide, Total NC 2.0 0.4 0.4 U 0.4 U NC 20SM 4500-S2- F Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:29 AM 16-0000374636 rev 00Superset Reference: Page 112 of 141 ALS Group USA, Corp. QA/QC Report Analyte Name mg/L J1603049-003 Basis:Lab Code: Units:Sample Name:MW-8 General Chemistry Parameters Matrix Spike Summary Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 04/27/16 - 04/29/16 04/27/16 Date Collected:04/26/16 NA ResultSample Result Spike Amount % Rec Matrix Spike J1603049-003MS % Rec LimitsMethod dba ALS Environmental Carbon, Total Organic (TOC)0.6 45.1 50.0 89 *90-110SM 5310 B Chloride 5.2 27.8 25.0 90 90-110300.0 Nitrate as Nitrogen 0.06 4.29 5.00 85 *90-110300.0 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:28 AM 16-0000374636 rev 00Superset Reference: Page 113 of 141 ALS Group USA, Corp. QA/QC Report Analyte Name mg/L J1603049-001 Basis:Lab Code: Units:Sample Name:MW-2 General Chemistry Parameters Matrix Spike Summary Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603049 05/03/16 - 05/05/16 04/27/16 Date Collected:04/26/16 NA ResultSample Result Spike Amount % Rec Matrix Spike J1603049-001MS % Rec LimitsMethod dba ALS Environmental Chemical Oxygen Demand, Total 42 536 500 99 90-110SM21 5220 D Sulfide, Total 0.4 19.0 20.0 95 85-115SM 4500-S2- F Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/12/2016 8:30:29 AM 16-0000374636 rev 00Superset Reference: Page 114 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/27/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Alkalinity as CaCO3, Total 85-11591 250227 SM 2320 B 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 115 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/27/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Biochemical Oxygen Demand (BOD)84.5-115.484 *198166 SM 5210 B 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 116 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/29/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Carbon, Total Organic (TOC)90-11094 50.046.8 SM 5310 B 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 117 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 05/05/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Chemical Oxygen Demand, Total 95-10599 500494 SM21 5220 D 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 118 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/27/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Chloride 90-11090 25.022.6 300.0 Nitrate as Nitrogen 90-11097 5.004.83 300.0 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 119 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/29/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Solids, Total Dissolved 85-115105 300315 SM 2540 C 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 120 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 04/29/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Sulfate 90-11094 25.023.6 300.0 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 121 of 141 Analyte Name J1603049 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603049-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Sulfide, Total 85-11594 20.018.9 SM 4500-S2- F 16-0000374636 rev 00Superset Reference:Printed 5/12/2016 8:30:29 AM Page 122 of 141 Page 123 of 141 Page 124 of 141 Page 125 of 141 Page 126 of 141 Page 127 of 141 Appendix A: Subcontracted Parameters Page 128 of 141 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER LABORATORY REPORT May 11, 2016 Elliott Cornell Wake County Solid Waste Management 9025 Deponie Drive Raleigh, NC 27614 RE: Feltonsville Landfill Dear Elliott: Enclosed are the results of the samples submitted to our laboratory on April 29, 2016. For your reference, these analyses have been assigned our service request number J1603049. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Kate Aguilera Project Manager Page 129 of 141 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER Client: Wake County Solid Waste Management Service Request No: J1603049 Project: Feltonsville Landfill _______________________________________________________________________________ CASE NARRATIVE The samples were received intact under chain of custody at the Simi Valley facility on April 29, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the sample(s) at the time of sample receipt. Carbon Dioxide Analysis The samples were analyzed for carbon dioxide using a gas chromatograph equipped with a thermal conductivity detector (TCD). A known amount of liquid was displaced by injecting 8.0 milliliters of helium creating a headspace in the sample vial. Each sample vial was agitated using a sonic disrupter for fifteen minutes and then allowed to equilibrate for at least four hours. A volume of the headspace was withdrawn using a gas-tight syringe and analyzed using a manual injection technique. The amount of dissolved gases (carbon dioxide) in the original sample was calculated using Henry’s Law. This method was performed with guidance from RSK 175 as described in laboratory SOP VOA-DISGAS. This analyte is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP accreditation. Methane, Ethene and Ethane Analysis The samples were analyzed for methane, ethene, and ethane using a gas chromatograph equipped with a flame ionization detector (FID). A known amount of liquid was displaced by injecting 8.0 milliliters of helium creating a headspace in the sample vial. Each sample vial was agitated using a sonic disrupter for fifteen minutes and then allowed to equilibrate for at least two hours. A volume of the headspace was withdrawn using a gas-tight syringe and analyzed using a manual injection technique. The amount of dissolved gases (methane, ethene and ethane) in the original sample was calculated using Henry’s Law. This method was performed with guidance from RSK 175. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP accreditation. Any analytes flagged with an X are not included on the laboratory’s NELAP or DoD-ELAP accreditation. ______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory. Page 130 of 141 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER ALS Environmental – Simi Valley CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS Agency Web Site Number AIHA http://www.aihaaccreditedlabs.org 101661 Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694 DoD ELAP http://www.pjlabs.com/search-accredited-labs L15-398 Florida DOH (NELAP) http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020 Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp- services/labcert/labcert.htm 2014025 Minnesota DOH (NELAP) http://www.health.state.mn.us/accreditation 977273 New Jersey DEP (NELAP) http://www.nj.gov/dep/oqa/ CA009 New York DOH (NELAP) http://www.wadsworth.org/labcert/elap/elap.html 11221 Oregon PHD (NELAP) http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaborat oryAccreditation/Pages/index.aspx 4068-003 Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307 (Registration) Texas CEQ (NELAP) http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413- 15-6 Utah DOH (NELAP) http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201 5-5 Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946 Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification. Page 131 of 141 P a g e 1 3 2 o f 1 4 1 5/11/16 8:31 AMJ1603049_Wake County Solid Waste Management_Feltonsville Landfill.xls - Page 1 of 2 ALS Environmental Sample Acceptance Check Form Client:Wake County Solid Waste Management Work order:J1603049 Project:Feltonsville Landfill Sample(s) received on:4/29/16 Date opened:4/29/16 by:ADAVID Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A 1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to? Cooler Temperature: 0° C Blank Temperature: ° C  8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)?Sealing Lid? Were signature and date included? Were seals intact? 9  Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?  10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact? Are dual bed badges separated and individually capped and intact? Lab Sample ID Container Required Received Adjusted VOA Headspace Description pH *pH pH (Presence/Absence)Comments 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A The samples were received at ALS-JAX on 4/27/16 RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4) Wet Ice MC 5/02/2016 J1603049-003.19 J1603049-003.20 J1603049-006.04 Explain any discrepancies: (include lab sample ID numbers): J1603049-006.05 J1603049-006.06 MC 5/02/2016 Do containers have appropriate preservation, according to method/SOP or Client specified information? Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it? Receipt / Preservation J1603049-001.04 J1603049-001.05 J1603049-001.06 J1603049-001.18 J1603049-003.18 J1603049-001.19 J1603049-001.20 J1603049-003.04 J1603049-003.05 J1603049-003.06 MC 5/02/2016 Page 133 of 141 5/11/16 8:31 AMJ1603049_Wake County Solid Waste Management_Feltonsville Landfill.xls - Page 2 of 2 ALS Environmental Sample Acceptance Check Form Client:Wake County Solid Waste Management Work order:J1603049 Project:Feltonsville Landfill Sample(s) received on:4/29/16 Date opened:4/29/16 by:ADAVID Lab Sample ID Container Required Received Adjusted VOA Headspace Receipt / Preservation Description pH *pH pH (Presence/Absence)Comments 40ml VOA HCL A 40ml VOA HCL A 40ml VOA HCL A RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4) Explain any discrepancies: (include lab sample ID numbers): J1603049-006.18 J1603049-006.19 J1603049-006.20 Page 134 of 141 TCD_ALL.xls - Page No.:J1603049_RSK175-TCD_1605050914_SC.xls - RSK - TCD ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Project ID:Feltonsville Landfill ALS Project ID:J1603049 Carbon Dioxide Test Code:RSK 175 Instrument ID:HP5890A/GC10/TCD Date(s) Collected:4/26/16 Analyst:Mike Conejo Date Received:4/27/16 Matrix:Water Date Analyzed:5/3/16 Test Notes: Injection Client Sample ID ALS Sample ID Volume Result MRL MDL Data ml(s)µg/L µg/L µg/L Qualifier MW-2 J1603049-001 0.10 8,300 1,000 370 MW-8 J1603049-003 0.10 12,000 1,000 370 MW-19 J1603049-006 0.10 62,000 1,000 370 Method Control Sample P160503-MB 0.10 ND 1,000 370 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 135 of 141 TCD_ALL.xls - Page No.:J1603049_RSK175-TCD_1605050914_SC.xls - DLCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE / DUPLICATE LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Duplicate Lab Control Sample ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:P160503-DLCS Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/TCD Date Received:NA Analyst:Mike Conejo Date Analyzed:5/03/16 Matrix:Water Volume(s) Analyzed:NA ml(s) Test Notes: Spike Amount Result1 ALS CAS #Compound LCS / DLCS LCS DLCS % Recovery Acceptance RPD RPD Data ug/L ug/L ug/L LCS DLCS Limits Limit Qualifier 124-38-9 Carbon Dioxide 22,900 16,500 17,700 72 77 62-139 7 24 1 = The concentration shown includes a subtraction of the Method Control Sample value, even if the result is less than the MRL. Page 136 of 141 FID_ALL.xls - Page No.:J1603049_RSK175-FID_1605031350_SC.xls - Sample ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-2 ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603049-001 Test Code:RSK 175 Date Collected:4/26/16 Instrument ID:HP5890A/GC10/FID Date Received:4/27/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane ND 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 137 of 141 FID_ALL.xls - Page No.:J1603049_RSK175-FID_1605031350_SC.xls - Sample (3) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-8 ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603049-003 Test Code:RSK 175 Date Collected:4/26/16 Instrument ID:HP5890A/GC10/FID Date Received:4/27/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 890 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane 0.31 0.60 0.061 J ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL. Page 138 of 141 FID_ALL.xls - Page No.:J1603049_RSK175-FID_1605031350_SC.xls - Sample (6) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-19 ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603049-006 Test Code:RSK 175 Date Collected:4/26/16 Instrument ID:HP5890A/GC10/FID Date Received:4/27/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 12 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 139 of 141 FID_ALL.xls - Page No.:J1603049_RSK175-FID_1605031350_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Method Control Sample ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:P160502-MB Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/FID Date Received:NA Analyst:Mike Conejo Date Analyzed:5/02/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane ND 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 The Method Control Sample is laboratory water carried through the entire analytical process. ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 140 of 141 FID_ALL.xls - Page No.:J1603049_RSK175-FID_1605031350_SC.xls - DLCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE / DUPLICATE LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Duplicate Lab Control Sample ALS Project ID:J1603049 Client Project ID:Feltonsville Landfill ALS Sample ID:P160502-LCS P160502-DLCS Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/FID Date Received:NA Analyst:Mike Conejo Date Analyzed:5/02/16 Sample Type:Water Volume(s) Analyzed:NA ml(s) Test Notes: Spike Amount Result1 ALS CAS #Compound LCS / DLCS LCS DLCS % Recovery Acceptance RPD RPD Data µg/L µg/L µg/L LCS DLCS Limits Limit Qualifier 74-82-8 Methane 2.53 2.62 2.54 104 100 83-106 4 12 74-85-1 Ethene 4.40 5.49 5.26 125 120 86-143 4 13 74-84-0 Ethane 4.75 5.30 5.05 112 106 85-122 6 14 1 = The concentration shown includes a subtraction of the Method Control Sample value, even if the result is less than the MRL. Page 141 of 141 May 20, 2016 Service Request No:J1603103 Daniel Forbes CDM Smith, Inc. 5400 Gleenwood Ave, Suite 400 Raleigh, NC 27612 All analyses were performed according to our laboratory’s quality assurance program. The test results meet requirements of the NELAP standards except as noted in the case narrative report. All results are intended to be considered in their entirety, and ALS Environmental is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any quantitative analysis will be supplied upon request. For your reference, these analyses have been assigned our service request number Enclosed are the results of the sample(s) submitted to our laboratory Laboratory Results for:Feltonsville Landfill Dear Daniel, April 28, 2016 J1603103. Please contact me if you have any questions. My extension is 4410. You may also contact me via email at Jerry.Allen@alsglobal.com. Respectfully submitted, ALS Group USA, Corp. dba ALS Environmental Jerry Allen Project Manager dba ALS Environmental ALS Group USA, Corp. ADDRESS FAXPHONE 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 +1 904 739 2011+1 904 739 2277 | Page 1 of 131 CLIENT ID:MW-6 Lab ID:J1603103-001 Analyte Results Flag MDL PQL Units Method Barium, Total 610 0.3 100 ug/L 6010C Silver, Total 1 J 0.6 10 ug/L 6010C Antimony, Total 0.3 J 0.2 6.0 ug/L 6020A Arsenic, Total 1 J 0.5 10 ug/L 6020A Beryllium, Total 0.07 J 0.04 1.0 ug/L 6020A Cadmium, Total 0.3 J 0.10 1.0 ug/L 6020A Chromium, Total 2 BJ 0.2 10 ug/L 6020A Cobalt, Total 3 J 0.03 10 ug/L 6020A Copper, Total 4 J 0.3 10 ug/L 6020A Lead, Total 0.8 J 0.2 10 ug/L 6020A Nickel, Total 21 J 0.5 50 ug/L 6020A Zinc, Total 13 2 10 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)6.2 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.70 J 0.16 1.0 ug/L 8260B Chlorobenzene 0.40 J 0.16 3.0 ug/L 8260B cis-1,2-Dichloroethene 0.94 J 0.36 5.0 ug/L 8260B CLIENT ID:MW-9 Lab ID:J1603103-002 Analyte Results Flag MDL PQL Units Method Chloride 31.1 0.08 1.0 mg/L 300.0 Sulfate 0.5 J 0.06 1.0 mg/L 300.0 Barium, Total 930 0.3 100 ug/L 6010C Silver, Total 1 J 0.6 10 ug/L 6010C Sodium, Total 21.2 0.04 0.50 mg/L 6010C Arsenic, Total 6 J 0.5 10 ug/L 6020A Beryllium, Total 0.1 J 0.04 1.0 ug/L 6020A Chromium, Total 0.4 BJ 0.2 10 ug/L 6020A Cobalt, Total 13 0.03 10 ug/L 6020A Copper, Total 11 0.3 10 ug/L 6020A Lead, Total 6 J 0.2 10 ug/L 6020A Nickel, Total 24 J 0.5 50 ug/L 6020A Zinc, Total 4 J 2 10 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)14 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.74 J 0.16 1.0 ug/L 8260B Benzene 0.96 J 0.21 1.0 ug/L 8260B Chloroethane 14 0.52 10 ug/L 8260B cis-1,2-Dichloroethene 0.60 J 0.36 5.0 ug/L 8260B Methylene Chloride 0.51 BJ 0.21 5.0 ug/L 8260B o-Xylene 0.41 J 0.14 1.0 ug/L 8260B Toluene 0.78 J 0.19 1.0 ug/L 8260B Vinyl Chloride 0.53 J 0.36 1.0 ug/L 8260B Acetic Acid 8.4 0.50 1.0 mg/L Organic SAMPLE DETECTION SUMMARY Page 2 of 131 CLIENT ID:MW-9 Lab ID:J1603103-002 Analyte Results Flag MDL PQL Units Method Alkalinity as CaCO3, Total 325 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 325 5.0 5.0 mg/L SM 2320 B Solids, Total Dissolved 403 10 10 mg/L SM 2540 C Biochemical Oxygen Demand (BOD)14.0 2.0 2.0 mg/L SM 5210 B Carbon, Total Organic (TOC)7.1 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 32 12 20 mg/L SM21 5220 CLIENT ID:MW-10 Lab ID:J1603103-003 Analyte Results Flag MDL PQL Units Method Chloride 207 0.8 10 mg/L 300.0 Sulfate 13.2 0.06 1.0 mg/L 300.0 Barium, Total 850 0.3 100 ug/L 6010C Silver, Total 2 J 0.6 10 ug/L 6010C Sodium, Total 93.4 0.04 0.50 mg/L 6010C Antimony, Total 0.3 J 0.2 6.0 ug/L 6020A Arsenic, Total 34 0.5 10 ug/L 6020A Beryllium, Total 0.1 J 0.04 1.0 ug/L 6020A Chromium, Total 0.5 BJ 0.2 10 ug/L 6020A Cobalt, Total 24 0.03 10 ug/L 6020A Copper, Total 2 J 0.3 10 ug/L 6020A Lead, Total 0.2 J 0.2 10 ug/L 6020A Nickel, Total 30 J 0.5 50 ug/L 6020A Zinc, Total 2 J 2 10 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)44 0.30 5.0 ug/L 8260B 1,2-Dichloroethane 0.48 J 0.22 1.0 ug/L 8260B 1,4-Dichlorobenzene 4.3 0.16 1.0 ug/L 8260B Acetone 17 J 5.6 100 ug/L 8260B Benzene 5.6 0.21 1.0 ug/L 8260B Chlorobenzene 0.77 J 0.16 3.0 ug/L 8260B Chloroethane 27 0.52 10 ug/L 8260B cis-1,2-Dichloroethene 0.95 J 0.36 5.0 ug/L 8260B Methylene Chloride 0.94 BJ 0.21 5.0 ug/L 8260B Vinyl Chloride 2.9 0.36 1.0 ug/L 8260B Pyruvic Acid 1.0 0.020 0.50 mg/L Organic Acetic Acid 0.52 J 0.50 1.0 mg/L Organic Alkalinity as CaCO3, Total 444 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 444 5.0 5.0 mg/L SM 2320 B Solids, Total Dissolved 832 20 20 mg/L SM 2540 C Biochemical Oxygen Demand (BOD)6.8 2.0 2.0 mg/L SM 5210 B Carbon, Total Organic (TOC)23.5 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 97 12 20 mg/L SM21 5220 SAMPLE DETECTION SUMMARY Page 3 of 131 CLIENT ID:MW-11 Lab ID:J1603103-004 Analyte Results Flag MDL PQL Units Method Barium, Total 110 0.3 100 ug/L 6010C Arsenic, Total 1 J 0.5 10 ug/L 6020A Cobalt, Total 9 J 0.03 10 ug/L 6020A Copper, Total 0.8 J 0.3 10 ug/L 6020A Nickel, Total 3 J 0.5 50 ug/L 6020A Zinc, Total 4 J 2 10 ug/L 6020A Acetone 7.3 J 5.6 100 ug/L 8260B CLIENT ID:MW-12 Lab ID:J1603103-005 Analyte Results Flag MDL PQL Units Method Chloride 238 0.2 2.0 mg/L 300.0 Sulfate 21.0 0.2 2.0 mg/L 300.0 Barium, Total 330 0.3 100 ug/L 6010C Silver, Total 1 J 0.6 10 ug/L 6010C Arsenic, Total 5 J 0.5 10 ug/L 6020A Beryllium, Total 0.08 J 0.04 1.0 ug/L 6020A Chromium, Total 3 J 0.2 10 ug/L 6020A Cobalt, Total 1 J 0.03 10 ug/L 6020A Copper, Total 4 J 0.3 10 ug/L 6020A Lead, Total 1 J 0.2 10 ug/L 6020A Nickel, Total 5 J 0.5 50 ug/L 6020A Zinc, Total 6 J 2 10 ug/L 6020A Lactic Acid 0.56 J 0.50 1.0 mg/L Organic Alkalinity as CaCO3, Total 699 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 699 5.0 5.0 mg/L SM 2320 B Sulfide, Total 0.8 J 0.8 4.0 mg/L SM 4500-S2 Carbon, Total Organic (TOC)6.4 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 32 12 20 mg/L SM21 5220 CLIENT ID:MW-13 Lab ID:J1603103-006 Analyte Results Flag MDL PQL Units Method Chloride 44.0 0.08 1.0 mg/L 300.0 Sulfate 8.8 0.06 1.0 mg/L 300.0 Barium, Total 620 0.3 100 ug/L 6010C Arsenic, Total 3 J 0.5 10 ug/L 6020A Beryllium, Total 0.1 J 0.04 1.0 ug/L 6020A Cadmium, Total 0.2 J 0.10 1.0 ug/L 6020A Chromium, Total 0.3 BJ 0.2 10 ug/L 6020A Cobalt, Total 9 J 0.03 10 ug/L 6020A Copper, Total 13 0.3 10 ug/L 6020A Lead, Total 0.6 J 0.2 10 ug/L 6020A Nickel, Total 35 J 0.5 50 ug/L 6020A SAMPLE DETECTION SUMMARY Page 4 of 131 CLIENT ID:MW-13 Lab ID:J1603103-006 Analyte Results Flag MDL PQL Units Method Zinc, Total 58 2 10 ug/L 6020A Mercury, Total 0.51 0.02 0.20 ug/L 7470A 1,4-Dichlorobenzene 2.6 0.16 1.0 ug/L 8260B Benzene 1.4 0.21 1.0 ug/L 8260B Chlorobenzene 12 0.16 3.0 ug/L 8260B cis-1,2-Dichloroethene 1.4 J 0.36 5.0 ug/L 8260B Alkalinity as CaCO3, Total 200 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 200 5.0 5.0 mg/L SM 2320 B Carbon, Total Organic (TOC)5.7 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 20 J 12 20 mg/L SM21 5220 CLIENT ID:MW-14 Lab ID:J1603103-007 Analyte Results Flag MDL PQL Units Method Chloride 87.7 0.08 1.0 mg/L 300.0 Sulfate 4.5 0.06 1.0 mg/L 300.0 Barium, Total 240 0.3 100 ug/L 6010C Antimony, Total 0.4 J 0.2 6.0 ug/L 6020A Arsenic, Total 0.5 J 0.5 10 ug/L 6020A Chromium, Total 3 BJ 0.2 10 ug/L 6020A Cobalt, Total 2 J 0.03 10 ug/L 6020A Copper, Total 1 J 0.3 10 ug/L 6020A Nickel, Total 18 J 0.5 50 ug/L 6020A Mercury, Total 0.12 J 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)1.4 J 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 1.2 0.16 1.0 ug/L 8260B Benzene 0.75 J 0.21 1.0 ug/L 8260B Chlorobenzene 3.3 0.16 3.0 ug/L 8260B cis-1,2-Dichloroethene 0.61 J 0.36 5.0 ug/L 8260B Alkalinity as CaCO3, Total 245 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 245 5.0 5.0 mg/L SM 2320 B Sulfide, Total 0.4 J 0.4 2.0 mg/L SM 4500-S2 Carbon, Total Organic (TOC)2.4 0.06 1.0 mg/L SM 5310 B CLIENT ID:MW-15 Lab ID:J1603103-008 Analyte Results Flag MDL PQL Units Method Barium, Total 280 0.3 100 ug/L 6010C Beryllium, Total 0.07 J 0.04 1.0 ug/L 6020A Cadmium, Total 0.2 J 0.10 1.0 ug/L 6020A Chromium, Total 5 J 0.2 10 ug/L 6020A Cobalt, Total 4 J 0.03 10 ug/L 6020A Copper, Total 7 J 0.3 10 ug/L 6020A Lead, Total 0.8 J 0.2 10 ug/L 6020A SAMPLE DETECTION SUMMARY Page 5 of 131 CLIENT ID:MW-15 Lab ID:J1603103-008 Analyte Results Flag MDL PQL Units Method Nickel, Total 32 J 0.5 50 ug/L 6020A Zinc, Total 6 J 2 10 ug/L 6020A Mercury, Total 0.21 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)1.2 J 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 1.5 0.16 1.0 ug/L 8260B Benzene 0.34 J 0.21 1.0 ug/L 8260B Chlorobenzene 5.3 0.16 3.0 ug/L 8260B cis-1,2-Dichloroethene 0.50 J 0.36 5.0 ug/L 8260B CLIENT ID:MW-16 Lab ID:J1603103-009 Analyte Results Flag MDL PQL Units Method Barium, Total 330 0.3 100 ug/L 6010C Silver, Total 1 J 0.6 10 ug/L 6010C Arsenic, Total 12 0.5 10 ug/L 6020A Cadmium, Total 0.7 J 0.10 1.0 ug/L 6020A Cobalt, Total 4 J 0.03 10 ug/L 6020A Copper, Total 0.5 J 0.3 10 ug/L 6020A Nickel, Total 8 J 0.5 50 ug/L 6020A Zinc, Total 4 J 2 10 ug/L 6020A 1,1-Dichloroethane (1,1-DCA)7.0 0.30 5.0 ug/L 8260B 1,4-Dichlorobenzene 0.26 J 0.16 1.0 ug/L 8260B Benzene 1.0 0.21 1.0 ug/L 8260B Chlorobenzene 0.39 J 0.16 3.0 ug/L 8260B Chloroethane 1.3 J 0.52 10 ug/L 8260B cis-1,2-Dichloroethene 3.3 J 0.36 5.0 ug/L 8260B Trichloroethene (TCE)2.0 0.36 1.0 ug/L 8260B Vinyl Chloride 0.49 J 0.36 1.0 ug/L 8260B CLIENT ID:MW-20 Lab ID:J1603103-010 Analyte Results Flag MDL PQL Units Method Barium, Total 240 0.3 100 ug/L 6010C Vanadium, Total 1 J 1.0 25 ug/L 6010C Antimony, Total 0.2 J 0.2 6.0 ug/L 6020A Arsenic, Total 4 J 0.5 10 ug/L 6020A Beryllium, Total 0.2 J 0.04 1.0 ug/L 6020A Chromium, Total 7 J 0.2 10 ug/L 6020A Cobalt, Total 5 J 0.03 10 ug/L 6020A Copper, Total 8 J 0.3 10 ug/L 6020A Lead, Total 4 J 0.2 10 ug/L 6020A Nickel, Total 9 J 0.5 50 ug/L 6020A Zinc, Total 28 2 10 ug/L 6020A SAMPLE DETECTION SUMMARY Page 6 of 131 CLIENT ID:MW-29 Lab ID:J1603103-011 Analyte Results Flag MDL PQL Units Method Chloride 8.3 0.08 1.0 mg/L 300.0 Sulfate 2.3 0.06 1.0 mg/L 300.0 Barium, Total 350 0.3 100 ug/L 6010C Sodium, Total 11.0 0.04 0.50 mg/L 6010C Vanadium, Total 46 1.0 25 ug/L 6010C Arsenic, Total 3 J 0.5 10 ug/L 6020A Beryllium, Total 1.5 0.04 1.0 ug/L 6020A Cadmium, Total 0.2 J 0.10 1.0 ug/L 6020A Chromium, Total 19 0.2 10 ug/L 6020A Cobalt, Total 11 0.03 10 ug/L 6020A Copper, Total 25 0.3 10 ug/L 6020A Lead, Total 21 0.2 10 ug/L 6020A Nickel, Total 20 J 0.5 50 ug/L 6020A Thallium, Total 0.1 J 0.05 5.5 ug/L 6020A Zinc, Total 70 2 10 ug/L 6020A Mercury, Total 0.06 J 0.02 0.20 ug/L 7470A 1,1-Dichloroethane (1,1-DCA)1.0 J 0.30 5.0 ug/L 8260B Alkalinity as CaCO3, Total 58.6 5.0 5.0 mg/L SM 2320 B Bicarbonate Alkalinity as CaCO3 58.6 5.0 5.0 mg/L SM 2320 B Solids, Total Dissolved 176 10 10 mg/L SM 2540 C Biochemical Oxygen Demand (BOD)2.5 2.0 2.0 mg/L SM 5210 B Carbon, Total Organic (TOC)11.7 0.06 1.0 mg/L SM 5310 B Chemical Oxygen Demand, Total 54 12 20 mg/L SM21 5220 CLIENT ID:EQ BLANK Lab ID:J1603103-012 Analyte Results Flag MDL PQL Units Method Copper, Total 0.4 J 0.3 10 ug/L 6020A Acetone 12 J 5.6 100 ug/L 8260B SAMPLE DETECTION SUMMARY Page 7 of 131 CASE NARRATIVE J1603103 Date Received: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: 4/28/16 All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II data deliverables, including results of QC samples analyzed from this delivery group. When appropriate to the procedure, method blank results have been reported with each analytical test. Analytical procedures performed by the lab are validated in accordance with NELAC standards. Parameters that are included in the NELAC Fields of Testing but are not included in the lab’s NELAC accreditation are identified in the discussion of each analytical procedure. Sample Receipt Thirteen ground water samples  were received for analysis at ALS Environmental on 4/28/2016. The samples were received in good condition and consistent with the accompanying chain of custody form. Samples are refrigerated at <6°C upon receipt at the lab except for aqueous samples designated for metals analyses, which are stored at room temperature. Volatile Organic Analyses: Method Blank JQ1603518-05 contained a low level of dichloromethane above the Method Detection Limit (MDL), but less than the Method Reporting Limit (MRL). Samples exhibiting dichloromethane in approximately the same concentration as the method blank are flagged with a qualifier to indicate the results are estimated values. The method blank results may indicate the potential for a false positive. Semi-Volatile Organic Analyses: No significant data anomalies were noted with this analysis. Metals Analyses: No significant data anomalies were noted with this analysis. General Chemistry Analyses: Method 300.0 (Nitrate): The analysis of project J1603103 was performed past the recommended holding time due to analyst error. Efforts were made to analyze the sample(s) as soon as possible after problem was identified. However, the analysis of the sample (s) was performed hours past the recommended holding time. The data is flagged to indicate the holding time violation. Method 300.0: The Method Reporting Limit (MRL) for Nitrate for sample(s) J1603103-005 was elevated due to matrix interference from high sample conductivity. Method SM4500-S2 F: The Method Reporting Limit (MRL) for Sulfidefor sample(s) J1603103-(2,5,11) was elevated due to matrix interference. Method SM4500-S2 F (Sulfide): The Titrant for this analysis were expired in March 2016. After confirming all quality control samples, analysis was performed. There is no reason to believe there is an effect on the sample data values. Subcontracted Analytical Parameters: 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com Approved by Date 5/20/2016 Page 8 of 131 An aliquot of the samples were delivered to ALS in Rochester, NY for Organic Acids determination. The certified analytical report has been included in its entirety in this report. An aliquot of the samples were delivered to ENCO in Jacksonville, FL for RSK-175 determination. The certified analytical report has been included in its entirety in Appendix A: Subcontracted Analytical Results. 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com Approved by Date 5/20/2016 Page 9 of 131 State Certifications, Accreditations, and Licenses Agency Number Expire Date Department of Defense 66206 9/20/2016 Florida Department of Health E82502 6/30/2016 Georgia Department of Natural Resources 958 6/30/2016 Kentucky Division of Waste Management 63 6/30/2016 Louisiana Department of Environmental Quality 02086 6/30/2016 Maine Department of Health and Human Services 2015002 2/3/2017 North Carolina Department of Environment and Natural Resources 527 12/31/2016 Pennsylvania Department of Environmental Protection 68-04835 8/31/2016 South Carolina Department of Health and Environmental Control 96021001 6/30/2016 Texas Commision on Environmental Quality T104704197-16-8 5/31/2017 Virginia Environmental Accreditation Program 460191 12/14/2016 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 | 904-739-2277 | www.alsglobal.com Page 10 of 131 +Possible Tedlar bag artifact. A TIC is a suspected aldol-condensation product B Analyte found in the associated method blank as well as in the sample. BC Reported results are not blank corrected. BH The back section of the tube yielded higher results than the front. BT Results indicated possible breakthrough; back section >=10% front section. C Result identification confirmed. D Compound identified in an analysis at a secondary dilution factor D Spike was diluted out DE Reported results are corrected for desorption efficiency. E Estimated value. Concentration above calibration range E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample. H1 Sample analysis performed past holding time. See case narrative. H2 Initial analysis within holding time. Reanalysis for the required dilution was past holding time. H3 Sample was received and analyzed past holding time. H4 Sample was extracted past required extraction holding time, but analyzed within analysis holding time. See case narrative. I Internal standard not within the specified limits. See case narrative. J Estimated Value. Concentration found below MRL. K A deflection in the QC ion may indicate interference with the quantitation of this ion. The concentration of this analyte should be considered as an estimate. K Analyte was detected above the method reporting limit prior to normalization. L1 Laboratory control sample recovery outside the specified limits; results may be biased high. L2 Laboratory control sample recovery outside the specified limits; results may be biased low. L3 Laboratory control sample recovery outside the specified limits. M Matrix interference; results may be biased high. M The duplicate injection precision not met. M1 Matrix interference due to coelution with a non-target compound; results may be biased high. N Presumptive evidence of a compound for TICs that have been identified based on a mass spectral library search. N The Matrix Spike sample recovery is not within control limits. See case narrative. P Indicates chlorodiphenyl ether interference present at the retention time of the target compound. P Pesticide/Aroclor target analyte > 40% difference for detected concentrations between GC columns Q Indicates as estimated value because the P and P + 2 theoretical abundance ratio does not meet method criteria. R Duplicate Precision not met. R1 Duplicate precision not within the specified limits; however, the results are below the MRL and considered estimated. S Surrogate recovery not within specified limits. Data Qualifiers Lab Standard Page 11 of 131 S The reported value was determined by the Method of Standard Additions (MSA). T Analyte is a tentatively identified compound, result is estimated. U Compound was analyzed for, but was not detected (ND). V1 The continuing calibration verification standard was outside (biased high) the specified limits for this compound. V2 The continuing calibration verification standard was outside (biased low) the specified limits for this compound. W Result quantified, but the corresponding peak was detected outside the generated retention time window. W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance. X See case narrative. Y Recovery outside limits Y The chromatogram resembles a petroleum product but does not match the calibration standard. Z The chromatogram does not resemble a petroleum product. i The MRL/MDL has been elevated due to a matrix interference. Data Qualifiers Lab Standard Page 12 of 131 ASTM American Society for Testing and Materials A2LA American Association for Laboratory Accreditation CARB California Air Resources Board CAS Number Chemical Abstract Service registry Number CFC Chlorofluorocarbon CFU Colony-Forming Unit DEC Department of Environmental Conservation DEQ Department of Environmental Quality DHS Department of Health Services DOE Department of Ecology DOH Department of Health EPA U. S. Environmental Protection Agency ELAP Environmental Laboratory Accreditation Program GC Gas Chromatography GC/MS Gas Chromatography/Mass Spectrometry LUFT Leaking Underground Fuel Tank M Modified MCL Maximum Contaminant Level is the highest permissible concentration of a substance allowed in drinking water as established by the USEPA. MDL Method Detection Limit MPN Most Probable Number MRL Method Reporting Limit NA Not Applicable NC Not Calculated NCASI National Council of the Paper Industry for Air and Stream Improvement ND Not Detected NIOSH National Institute for Occupational Safety and Health PQL Practical Quantitation Limit RCRA Resource Conservation and Recovery Act SIM Selected Ion Monitoring TPH Total Petroleum Hydrocarbons tr Trace level is the concentration of an analyte that is less than the PQL but greater than or equal to the MDL. Acronyms ALS Laboratory Group Page 13 of 131 MW-6J1603103-001 4/27/2016 1515 MW-9J1603103-002 4/27/2016 1250 MW-10J1603103-003 4/27/2016 1325 MW-11J1603103-004 4/27/2016 1415 MW-12J1603103-005 4/27/2016 1120 MW-13J1603103-006 4/27/2016 1101 MW-14J1603103-007 4/27/2016 0930 MW-15J1603103-008 4/27/2016 0845 MW-16J1603103-009 4/27/2016 0745 MW-20J1603103-010 4/27/2016 1445 MW-29J1603103-011 4/27/2016 1215 EQ BLANKJ1603103-012 4/27/2016 1520 TRIP BLANK 2J1603103-013 4/27/2016 0000 Client:Wake County Solid Waste Management Service Request:J1603103 Project:Feltonsville Landfill SAMPLE CROSS-REFERENCE SAMPLE #CLIENT SAMPLE ID DATE TIME Printed 5/20/2016 8:50:54 AM Sample Summary Page 14 of 131 J1603103-001Lab Code: Sample Name:MW-6 Volatile Organic Compounds by GC/MS 04/27/16 15:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 13:095.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 13:091.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 13:093.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 13:091.0 U6.21,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 13:095.0 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 13:095.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 13:092.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 13:0913 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 13:091.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 13:095.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 13:091.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 13:091.0 U0.701,4-Dichlorobenzene 0.16 1 05/06/16 13:091.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 13:09100 U2.22-Hexanone 2.2 1 05/06/16 13:0950 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 13:09100 U5.6Acetone 5.6 1 05/06/16 13:09100 U 1.5Acrylonitrile 1.5 1 05/06/16 13:09200 U0.21Benzene 0.21 1 05/06/16 13:091.0 U 0.27Bromochloromethane 0.27 1 05/06/16 13:095.0 U0.22Bromodichloromethane 0.22 1 05/06/16 13:091.0 U 0.42Bromoform 0.42 1 05/06/16 13:093.0 U0.23Bromomethane 0.23 1 05/06/16 13:0910 U 2.4Carbon Disulfide 2.4 1 05/06/16 13:09100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 13:091.0 U 0.40Chlorobenzene 0.16 1 05/06/16 13:093.0 J0.52Chloroethane 0.52 1 05/06/16 13:0910 U 0.35Chloroform 0.35 1 05/06/16 13:095.0 U0.36Chloromethane 0.36 1 05/06/16 13:091.0 U 0.94cis-1,2-Dichloroethene 0.36 1 05/06/16 13:095.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 13:091.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 13:093.0 U0.36Dibromomethane 0.36 1 05/06/16 13:0910 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 13:0920 U0.21Ethylbenzene 0.21 1 05/06/16 13:091.0 U 2.7Iodomethane 2.7 1 05/06/16 13:0910 U0.31m,p-Xylenes 0.31 1 05/06/16 13:092.0 U 0.21Methylene Chloride 0.21 1 05/06/16 13:095.0 U0.14o-Xylene 0.14 1 05/06/16 13:091.0 U 0.29Styrene 0.29 1 05/06/16 13:091.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 13:091.0 U 0.19Toluene 0.19 1 05/06/16 13:091.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 13:095.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:55 AM 16-0000374637 rev 00Superset Reference: Page 15 of 131 J1603103-001Lab Code: Sample Name:MW-6 Volatile Organic Compounds by GC/MS 04/27/16 15:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 13:091.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 13:09100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 13:091.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 13:0920 U1.9Vinyl Acetate 1.9 1 05/06/16 13:0950 U 0.36Vinyl Chloride 0.36 1 05/06/16 13:091.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 13:0972 - 1211041,2-Dichloroethane-d4 05/06/16 13:0986 - 1131034-Bromofluorobenzene 05/06/16 13:0986 - 112104Dibromofluoromethane 05/06/16 13:0988 - 115101Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:55 AM 16-0000374637 rev 00Superset Reference: Page 16 of 131 J1603103-001Lab Code: Sample Name:MW-6 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 15:15 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007101,2-Dibromo-3-chloropropane (DBCP)0.00710 1 05/03/16 17:28 5/2/160.0203 U 0.007101,2-Dibromoethane (EDB)0.00710 1 05/03/16 17:28 5/2/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 17:2870 - 130811,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:04 AM 16-0000374637 rev 00Superset Reference: Page 17 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 15:15 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-6 Lab Code:J1603103-001 Antimony, Total 05/02/16 23:35 04/29/1610.26.0 J0.36020A ug/L Arsenic, Total 05/02/16 23:35 04/29/1610.510 J16020A ug/L Barium, Total 05/03/16 23:11 05/03/1610.31006106010Cug/L Beryllium, Total 05/02/16 23:35 04/29/1610.041.0 J0.076020A ug/L Cadmium, Total 05/02/16 23:35 04/29/1610.101.0 J0.36020A ug/L Chromium, Total 05/02/16 23:35 04/29/1610.210 BJ26020A ug/L Cobalt, Total 05/02/16 23:35 04/29/1610.0310 J36020A ug/L Copper, Total 05/02/16 23:35 04/29/1610.310 J46020A ug/L Lead, Total 05/02/16 23:35 04/29/1610.210 J0.86020A ug/L Mercury, Total 05/10/16 17:33 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/02/16 23:35 04/29/1610.550 J216020A ug/L Selenium, Total 05/02/16 23:35 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:11 05/03/1610.610 J16010C ug/L Thallium, Total 05/02/16 23:35 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:11 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/02/16 23:35 04/29/161210136020Aug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:12 AM 16-0000374637 rev 00Superset Reference: Page 18 of 131 J1603103-002Lab Code: Sample Name:MW-9 Volatile Organic Compounds by GC/MS 04/27/16 12:50 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 13:335.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 13:331.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 13:333.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 13:331.0 U141,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 13:335.0 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 13:335.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 13:332.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 13:3313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 13:331.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 13:335.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 13:331.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 13:331.0 U0.741,4-Dichlorobenzene 0.16 1 05/06/16 13:331.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 13:33100 U2.22-Hexanone 2.2 1 05/06/16 13:3350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 13:33100 U5.6Acetone 5.6 1 05/06/16 13:33100 U 1.5Acrylonitrile 1.5 1 05/06/16 13:33200 U0.96Benzene 0.21 1 05/06/16 13:331.0 J 0.27Bromochloromethane 0.27 1 05/06/16 13:335.0 U0.22Bromodichloromethane 0.22 1 05/06/16 13:331.0 U 0.42Bromoform 0.42 1 05/06/16 13:333.0 U0.23Bromomethane 0.23 1 05/06/16 13:3310 U 2.4Carbon Disulfide 2.4 1 05/06/16 13:33100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 13:331.0 U 0.16Chlorobenzene 0.16 1 05/06/16 13:333.0 U14Chloroethane 0.52 1 05/06/16 13:3310 0.35Chloroform 0.35 1 05/06/16 13:335.0 U0.36Chloromethane 0.36 1 05/06/16 13:331.0 U 0.60cis-1,2-Dichloroethene 0.36 1 05/06/16 13:335.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 13:331.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 13:333.0 U0.36Dibromomethane 0.36 1 05/06/16 13:3310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 13:3320 U0.21Ethylbenzene 0.21 1 05/06/16 13:331.0 U 2.7Iodomethane 2.7 1 05/06/16 13:3310 U0.31m,p-Xylenes 0.31 1 05/06/16 13:332.0 U 0.51Methylene Chloride 0.21 1 05/06/16 13:335.0 BJ0.41o-Xylene 0.14 1 05/06/16 13:331.0 J 0.29Styrene 0.29 1 05/06/16 13:331.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 13:331.0 U 0.78Toluene 0.19 1 05/06/16 13:331.0 J0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 13:335.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:55 AM 16-0000374637 rev 00Superset Reference: Page 19 of 131 J1603103-002Lab Code: Sample Name:MW-9 Volatile Organic Compounds by GC/MS 04/27/16 12:50 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 13:331.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 13:33100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 13:331.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 13:3320 U1.9Vinyl Acetate 1.9 1 05/06/16 13:3350 U 0.53Vinyl Chloride 0.36 1 05/06/16 13:331.0 J Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 13:3372 - 1211041,2-Dichloroethane-d4 05/06/16 13:3386 - 1131044-Bromofluorobenzene 05/06/16 13:3386 - 112101Dibromofluoromethane 05/06/16 13:3388 - 115101Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:55 AM 16-0000374637 rev 00Superset Reference: Page 20 of 131 J1603103-002Lab Code: Sample Name:MW-9 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 12:50 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007111,2-Dibromo-3-chloropropane (DBCP)0.00711 1 05/03/16 17:53 5/2/160.0203 U 0.007111,2-Dibromoethane (EDB)0.00711 1 05/03/16 17:53 5/2/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 17:5370 - 1301091,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:04 AM 16-0000374637 rev 00Superset Reference: Page 21 of 131 J1603103-002Lab Code: Sample Name:MW-9 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 12:50 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 22:050.50 U 8.4Acetic Acid 0.50 1 04/29/16 22:051.0 1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 22:052.0 U 0.50Lactic Acid 0.50 1 04/29/16 22:051.0 U0.50Propionic Acid 0.50 1 04/29/16 22:051.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 22 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 12:50 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-9 Lab Code:J1603103-002 Antimony, Total 05/02/16 23:41 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/02/16 23:41 04/29/1610.510 J66020A ug/L Barium, Total 05/03/16 23:16 05/03/1610.31009306010Cug/L Beryllium, Total 05/02/16 23:41 04/29/1610.041.0 J0.16020A ug/L Cadmium, Total 05/02/16 23:41 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/02/16 23:41 04/29/1610.210 BJ0.46020A ug/L Cobalt, Total 05/02/16 23:41 04/29/1610.0310136020Aug/L Copper, Total 05/02/16 23:41 04/29/1610.310116020Aug/L Lead, Total 05/02/16 23:41 04/29/1610.210 J66020A ug/L Mercury, Total 05/10/16 17:34 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/02/16 23:41 04/29/1610.550 J246020A ug/L Selenium, Total 05/02/16 23:41 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:16 05/03/1610.610 J16010C ug/L Sodium, Total 05/03/16 23:15 05/03/1610.040.5021.26010C mg/L Thallium, Total 05/02/16 23:41 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:16 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/02/16 23:41 04/29/161210 J46020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:12 AM 16-0000374637 rev 00Superset Reference: Page 23 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 12:50 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-9 Lab Code:J1603103-002 Alkalinity as CaCO3, Total 05/05/16 22:06 NA15.05.0325SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 22:06 NA15.05.0325SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.014.0SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 19:57 NA10.061.07.1SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 22:06 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:01 05/05/161122032SM21 5220 D mg/L Chloride 04/29/16 21:35 NA10.081.031.1300.0 mg/L Nitrate as Nitrogen 04/29/16 21:35 NA10.040.20 U0.04 *300.0 mg/L Solids, Total Dissolved 05/02/16 12:43 NA11010403SM 2540 C mg/L Sulfate 04/29/16 21:35 NA10.061.0 J0.5300.0 mg/L Sulfide, Total 05/03/16 14:14 NA20.84.0 U0.8SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 24 of 131 J1603103-003Lab Code: Sample Name:MW-10 Volatile Organic Compounds by GC/MS 04/27/16 13:25 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 13:565.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 13:561.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 13:563.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 13:561.0 U441,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 13:565.0 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 13:565.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 13:562.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 13:5613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 13:561.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 13:565.0 U0.481,2-Dichloroethane 0.22 1 05/06/16 13:561.0 J 0.191,2-Dichloropropane 0.19 1 05/06/16 13:561.0 U4.31,4-Dichlorobenzene 0.16 1 05/06/16 13:561.0 3.82-Butanone (MEK)3.8 1 05/06/16 13:56100 U2.22-Hexanone 2.2 1 05/06/16 13:5650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 13:56100 U17Acetone 5.6 1 05/06/16 13:56100 J 1.5Acrylonitrile 1.5 1 05/06/16 13:56200 U5.6Benzene 0.21 1 05/06/16 13:561.0 0.27Bromochloromethane 0.27 1 05/06/16 13:565.0 U0.22Bromodichloromethane 0.22 1 05/06/16 13:561.0 U 0.42Bromoform 0.42 1 05/06/16 13:563.0 U0.23Bromomethane 0.23 1 05/06/16 13:5610 U 2.4Carbon Disulfide 2.4 1 05/06/16 13:56100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 13:561.0 U 0.77Chlorobenzene 0.16 1 05/06/16 13:563.0 J27Chloroethane 0.52 1 05/06/16 13:5610 0.35Chloroform 0.35 1 05/06/16 13:565.0 U0.36Chloromethane 0.36 1 05/06/16 13:561.0 U 0.95cis-1,2-Dichloroethene 0.36 1 05/06/16 13:565.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 13:561.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 13:563.0 U0.36Dibromomethane 0.36 1 05/06/16 13:5610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 13:5620 U0.21Ethylbenzene 0.21 1 05/06/16 13:561.0 U 2.7Iodomethane 2.7 1 05/06/16 13:5610 U0.31m,p-Xylenes 0.31 1 05/06/16 13:562.0 U 0.94Methylene Chloride 0.21 1 05/06/16 13:565.0 BJ0.14o-Xylene 0.14 1 05/06/16 13:561.0 U 0.29Styrene 0.29 1 05/06/16 13:561.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 13:561.0 U 0.19Toluene 0.19 1 05/06/16 13:561.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 13:565.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 25 of 131 J1603103-003Lab Code: Sample Name:MW-10 Volatile Organic Compounds by GC/MS 04/27/16 13:25 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 13:561.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 13:56100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 13:561.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 13:5620 U1.9Vinyl Acetate 1.9 1 05/06/16 13:5650 U 2.9Vinyl Chloride 0.36 1 05/06/16 13:561.0 Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 13:5672 - 1211051,2-Dichloroethane-d4 05/06/16 13:5686 - 1131034-Bromofluorobenzene 05/06/16 13:5686 - 112102Dibromofluoromethane 05/06/16 13:5688 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 26 of 131 J1603103-003Lab Code: Sample Name:MW-10 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 13:25 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007161,2-Dibromo-3-chloropropane (DBCP)0.00716 1 05/03/16 18:18 5/2/160.0204 U 0.007161,2-Dibromoethane (EDB)0.00716 1 05/03/16 18:18 5/2/160.0204 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 18:1870 - 130701,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:04 AM 16-0000374637 rev 00Superset Reference: Page 27 of 131 J1603103-003Lab Code: Sample Name:MW-10 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 13:25 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 1.0Pyruvic Acid 0.020 1 04/29/16 23:400.50 0.52Acetic Acid 0.50 1 04/29/16 23:401.0 J1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 23:402.0 U 0.50Lactic Acid 0.50 1 04/29/16 23:401.0 U0.50Propionic Acid 0.50 1 04/29/16 23:401.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 28 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 13:25 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-10 Lab Code:J1603103-003 Antimony, Total 05/03/16 00:08 04/29/1610.26.0 J0.36020A ug/L Arsenic, Total 05/03/16 00:08 04/29/1610.510346020Aug/L Barium, Total 05/03/16 23:21 05/03/1610.31008506010Cug/L Beryllium, Total 05/03/16 00:08 04/29/1610.041.0 J0.16020A ug/L Cadmium, Total 05/03/16 00:08 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 00:08 04/29/1610.210 BJ0.56020A ug/L Cobalt, Total 05/03/16 00:08 04/29/1610.0310246020Aug/L Copper, Total 05/03/16 00:08 04/29/1610.310 J26020A ug/L Lead, Total 05/03/16 00:08 04/29/1610.210 J0.26020A ug/L Mercury, Total 05/10/16 17:36 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 00:08 04/29/1610.550 J306020A ug/L Selenium, Total 05/03/16 00:08 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:21 05/03/1610.610 J26010C ug/L Sodium, Total 05/03/16 23:20 05/03/1610.040.5093.46010C mg/L Thallium, Total 05/03/16 00:08 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:21 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:08 04/29/161210 J26020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:12 AM 16-0000374637 rev 00Superset Reference: Page 29 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 13:25 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-10 Lab Code:J1603103-003 Alkalinity as CaCO3, Total 05/05/16 22:13 NA15.05.0444SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 22:13 NA15.05.0444SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.06.8SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 20:14 NA10.061.023.5SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 22:13 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:04 05/05/161122097SM21 5220 D mg/L Chloride 04/29/16 22:01 NA100.810207300.0 mg/L Nitrate as Nitrogen 04/29/16 21:48 NA10.040.20 U0.04 *300.0 mg/L Solids, Total Dissolved 05/02/16 12:43 NA22020832SM 2540 C mg/L Sulfate 04/29/16 21:48 NA10.061.013.2300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 30 of 131 J1603103-004Lab Code: Sample Name:MW-11 Volatile Organic Compounds by GC/MS 04/27/16 14:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 14:195.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 14:191.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 14:193.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 14:191.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 14:195.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 14:195.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 14:192.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 14:1913 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 14:191.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 14:195.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 14:191.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 14:191.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 14:191.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 14:19100 U2.22-Hexanone 2.2 1 05/06/16 14:1950 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 14:19100 U7.3Acetone 5.6 1 05/06/16 14:19100 J 1.5Acrylonitrile 1.5 1 05/06/16 14:19200 U0.21Benzene 0.21 1 05/06/16 14:191.0 U 0.27Bromochloromethane 0.27 1 05/06/16 14:195.0 U0.22Bromodichloromethane 0.22 1 05/06/16 14:191.0 U 0.42Bromoform 0.42 1 05/06/16 14:193.0 U0.23Bromomethane 0.23 1 05/06/16 14:1910 U 2.4Carbon Disulfide 2.4 1 05/06/16 14:19100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 14:191.0 U 0.16Chlorobenzene 0.16 1 05/06/16 14:193.0 U0.52Chloroethane 0.52 1 05/06/16 14:1910 U 0.35Chloroform 0.35 1 05/06/16 14:195.0 U0.36Chloromethane 0.36 1 05/06/16 14:191.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 14:195.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 14:191.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 14:193.0 U0.36Dibromomethane 0.36 1 05/06/16 14:1910 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 14:1920 U0.21Ethylbenzene 0.21 1 05/06/16 14:191.0 U 2.7Iodomethane 2.7 1 05/06/16 14:1910 U0.31m,p-Xylenes 0.31 1 05/06/16 14:192.0 U 0.21Methylene Chloride 0.21 1 05/06/16 14:195.0 U0.14o-Xylene 0.14 1 05/06/16 14:191.0 U 0.29Styrene 0.29 1 05/06/16 14:191.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 14:191.0 U 0.19Toluene 0.19 1 05/06/16 14:191.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 14:195.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 31 of 131 J1603103-004Lab Code: Sample Name:MW-11 Volatile Organic Compounds by GC/MS 04/27/16 14:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 14:191.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 14:19100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 14:191.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 14:1920 U1.9Vinyl Acetate 1.9 1 05/06/16 14:1950 U 0.36Vinyl Chloride 0.36 1 05/06/16 14:191.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 14:1972 - 1211041,2-Dichloroethane-d4 05/06/16 14:1986 - 1131044-Bromofluorobenzene 05/06/16 14:1986 - 112102Dibromofluoromethane 05/06/16 14:1988 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 32 of 131 J1603103-004Lab Code: Sample Name:MW-11 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 14:15 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007131,2-Dibromo-3-chloropropane (DBCP)0.00713 1 05/03/16 18:43 5/2/160.0204 U 0.007131,2-Dibromoethane (EDB)0.00713 1 05/03/16 18:43 5/2/160.0204 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 18:4370 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:04 AM 16-0000374637 rev 00Superset Reference: Page 33 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 14:15 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-11 Lab Code:J1603103-004 Antimony, Total 05/03/16 00:13 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 00:13 04/29/1610.510 J16020A ug/L Barium, Total 05/03/16 23:30 05/03/1610.31001106010Cug/L Beryllium, Total 05/03/16 00:13 04/29/1610.041.0 U0.046020A ug/L Cadmium, Total 05/03/16 00:13 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 00:13 04/29/1610.210 U0.26020A ug/L Cobalt, Total 05/03/16 00:13 04/29/1610.0310 J96020A ug/L Copper, Total 05/03/16 00:13 04/29/1610.310 J0.86020A ug/L Lead, Total 05/03/16 00:13 04/29/1610.210 U0.26020A ug/L Mercury, Total 05/10/16 17:37 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 00:13 04/29/1610.550 J36020A ug/L Selenium, Total 05/03/16 00:13 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:30 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 00:13 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:30 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:13 04/29/161210 J46020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:12 AM 16-0000374637 rev 00Superset Reference: Page 34 of 131 J1603103-005Lab Code: Sample Name:MW-12 Volatile Organic Compounds by GC/MS 04/27/16 11:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 14:435.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 14:431.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 14:433.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 14:431.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 14:435.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 14:435.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 14:432.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 14:4313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 14:431.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 14:435.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 14:431.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 14:431.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 14:431.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 14:43100 U2.22-Hexanone 2.2 1 05/06/16 14:4350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 14:43100 U5.6Acetone 5.6 1 05/06/16 14:43100 U 1.5Acrylonitrile 1.5 1 05/06/16 14:43200 U0.21Benzene 0.21 1 05/06/16 14:431.0 U 0.27Bromochloromethane 0.27 1 05/06/16 14:435.0 U0.22Bromodichloromethane 0.22 1 05/06/16 14:431.0 U 0.42Bromoform 0.42 1 05/06/16 14:433.0 U0.23Bromomethane 0.23 1 05/06/16 14:4310 U 2.4Carbon Disulfide 2.4 1 05/06/16 14:43100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 14:431.0 U 0.16Chlorobenzene 0.16 1 05/06/16 14:433.0 U0.52Chloroethane 0.52 1 05/06/16 14:4310 U 0.35Chloroform 0.35 1 05/06/16 14:435.0 U0.36Chloromethane 0.36 1 05/06/16 14:431.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 14:435.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 14:431.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 14:433.0 U0.36Dibromomethane 0.36 1 05/06/16 14:4310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 14:4320 U0.21Ethylbenzene 0.21 1 05/06/16 14:431.0 U 2.7Iodomethane 2.7 1 05/06/16 14:4310 U0.31m,p-Xylenes 0.31 1 05/06/16 14:432.0 U 0.21Methylene Chloride 0.21 1 05/06/16 14:435.0 U0.14o-Xylene 0.14 1 05/06/16 14:431.0 U 0.29Styrene 0.29 1 05/06/16 14:431.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 14:431.0 U 0.19Toluene 0.19 1 05/06/16 14:431.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 14:435.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 35 of 131 J1603103-005Lab Code: Sample Name:MW-12 Volatile Organic Compounds by GC/MS 04/27/16 11:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 14:431.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 14:43100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 14:431.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 14:4320 U1.9Vinyl Acetate 1.9 1 05/06/16 14:4350 U 0.36Vinyl Chloride 0.36 1 05/06/16 14:431.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 14:4372 - 1211031,2-Dichloroethane-d4 05/06/16 14:4386 - 1131044-Bromofluorobenzene 05/06/16 14:4386 - 112102Dibromofluoromethane 05/06/16 14:4388 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:56 AM 16-0000374637 rev 00Superset Reference: Page 36 of 131 J1603103-005Lab Code: Sample Name:MW-12 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 11:20 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007091,2-Dibromo-3-chloropropane (DBCP)0.00709 1 05/03/16 19:08 5/2/160.0203 U 0.007091,2-Dibromoethane (EDB)0.00709 1 05/03/16 19:08 5/2/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 19:0870 - 130771,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:04 AM 16-0000374637 rev 00Superset Reference: Page 37 of 131 J1603103-005Lab Code: Sample Name:MW-12 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 11:20 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/30/16 00:260.50 U 0.50Acetic Acid 0.50 1 04/30/16 00:261.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/30/16 00:262.0 U 0.56Lactic Acid 0.50 1 04/30/16 00:261.0 J0.50Propionic Acid 0.50 1 04/30/16 00:261.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 38 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 11:20 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-12 Lab Code:J1603103-005 Antimony, Total 05/03/16 00:18 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 00:18 04/29/1610.510 J56020A ug/L Barium, Total 05/03/16 23:35 05/03/1610.31003306010Cug/L Beryllium, Total 05/03/16 00:18 04/29/1610.041.0 J0.086020A ug/L Cadmium, Total 05/03/16 00:18 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 00:18 04/29/1610.210 J36020A ug/L Cobalt, Total 05/03/16 00:18 04/29/1610.0310 J16020A ug/L Copper, Total 05/03/16 00:18 04/29/1610.310 J46020A ug/L Lead, Total 05/03/16 00:18 04/29/1610.210 J16020A ug/L Mercury, Total 05/10/16 17:39 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 00:18 04/29/1610.550 J56020A ug/L Selenium, Total 05/03/16 00:18 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:35 05/03/1610.610 J16010C ug/L Thallium, Total 05/03/16 00:18 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:36 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:18 04/29/161210 J66020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:12 AM 16-0000374637 rev 00Superset Reference: Page 39 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 11:20 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-12 Lab Code:J1603103-005 Alkalinity as CaCO3, Total 05/05/16 22:42 NA15.05.0699SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 22:42 NA15.05.0699SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.0 U2.0SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 20:28 NA10.061.06.4SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 22:42 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:06 05/05/161122032SM21 5220 D mg/L Chloride 04/29/16 22:14 NA20.22.0238300.0 mg/L Nitrate as Nitrogen 04/29/16 22:14 NA20.080.40 U0.08 *300.0 mg/L Sulfate 04/29/16 22:14 NA20.22.021.0300.0 mg/L Sulfide, Total 05/03/16 14:14 NA20.84.0 J0.8SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 40 of 131 J1603103-006Lab Code: Sample Name:MW-13 Volatile Organic Compounds by GC/MS 04/27/16 11:01 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 15:065.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 15:061.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 15:063.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 15:061.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 15:065.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 15:065.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 15:062.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 15:0613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 15:061.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 15:065.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 15:061.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 15:061.0 U2.61,4-Dichlorobenzene 0.16 1 05/06/16 15:061.0 3.82-Butanone (MEK)3.8 1 05/06/16 15:06100 U2.22-Hexanone 2.2 1 05/06/16 15:0650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 15:06100 U5.6Acetone 5.6 1 05/06/16 15:06100 U 1.5Acrylonitrile 1.5 1 05/06/16 15:06200 U1.4Benzene 0.21 1 05/06/16 15:061.0 0.27Bromochloromethane 0.27 1 05/06/16 15:065.0 U0.22Bromodichloromethane 0.22 1 05/06/16 15:061.0 U 0.42Bromoform 0.42 1 05/06/16 15:063.0 U0.23Bromomethane 0.23 1 05/06/16 15:0610 U 2.4Carbon Disulfide 2.4 1 05/06/16 15:06100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 15:061.0 U 12Chlorobenzene 0.16 1 05/06/16 15:063.0 0.52Chloroethane 0.52 1 05/06/16 15:0610 U 0.35Chloroform 0.35 1 05/06/16 15:065.0 U0.36Chloromethane 0.36 1 05/06/16 15:061.0 U 1.4cis-1,2-Dichloroethene 0.36 1 05/06/16 15:065.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 15:061.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 15:063.0 U0.36Dibromomethane 0.36 1 05/06/16 15:0610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 15:0620 U0.21Ethylbenzene 0.21 1 05/06/16 15:061.0 U 2.7Iodomethane 2.7 1 05/06/16 15:0610 U0.31m,p-Xylenes 0.31 1 05/06/16 15:062.0 U 0.21Methylene Chloride 0.21 1 05/06/16 15:065.0 U0.14o-Xylene 0.14 1 05/06/16 15:061.0 U 0.29Styrene 0.29 1 05/06/16 15:061.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 15:061.0 U 0.19Toluene 0.19 1 05/06/16 15:061.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 15:065.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:57 AM 16-0000374637 rev 00Superset Reference: Page 41 of 131 J1603103-006Lab Code: Sample Name:MW-13 Volatile Organic Compounds by GC/MS 04/27/16 11:01 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 15:061.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 15:06100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 15:061.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 15:0620 U1.9Vinyl Acetate 1.9 1 05/06/16 15:0650 U 0.36Vinyl Chloride 0.36 1 05/06/16 15:061.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 15:0672 - 1211051,2-Dichloroethane-d4 05/06/16 15:0686 - 1131054-Bromofluorobenzene 05/06/16 15:0686 - 112102Dibromofluoromethane 05/06/16 15:0688 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:57 AM 16-0000374637 rev 00Superset Reference: Page 42 of 131 J1603103-006Lab Code: Sample Name:MW-13 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 11:01 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007081,2-Dibromo-3-chloropropane (DBCP)0.00708 1 05/04/16 16:25 5/4/160.0202 U 0.007081,2-Dibromoethane (EDB)0.00708 1 05/04/16 16:25 5/4/160.0202 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 16:2570 - 130841,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 43 of 131 J1603103-006Lab Code: Sample Name:MW-13 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 11:01 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/30/16 01:130.50 U 0.50Acetic Acid 0.50 1 04/30/16 01:131.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/30/16 01:132.0 U 0.50Lactic Acid 0.50 1 04/30/16 01:131.0 U0.50Propionic Acid 0.50 1 04/30/16 01:131.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 44 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 11:01 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-13 Lab Code:J1603103-006 Antimony, Total 05/03/16 00:24 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 00:24 04/29/1610.510 J36020A ug/L Barium, Total 05/03/16 23:56 05/03/1610.31006206010Cug/L Beryllium, Total 05/03/16 00:24 04/29/1610.041.0 J0.16020A ug/L Cadmium, Total 05/03/16 00:24 04/29/1610.101.0 J0.26020A ug/L Chromium, Total 05/03/16 00:24 04/29/1610.210 BJ0.36020A ug/L Cobalt, Total 05/03/16 00:24 04/29/1610.0310 J96020A ug/L Copper, Total 05/03/16 00:24 04/29/1610.310136020Aug/L Lead, Total 05/03/16 00:24 04/29/1610.210 J0.66020A ug/L Mercury, Total 05/10/16 17:40 05/09/1610.020.200.517470A ug/L Nickel, Total 05/03/16 00:24 04/29/1610.550 J356020A ug/L Selenium, Total 05/03/16 00:24 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:56 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 00:24 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:56 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:24 04/29/161210586020Aug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 45 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 11:01 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-13 Lab Code:J1603103-006 Alkalinity as CaCO3, Total 05/05/16 22:50 NA15.05.0200SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 22:50 NA15.05.0200SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.0 U2.0SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 20:44 NA10.061.05.7SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 22:50 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:06 05/05/1611220 J20SM21 5220 D mg/L Chloride 04/29/16 23:06 NA10.081.044.0300.0 mg/L Nitrate as Nitrogen 04/29/16 23:06 NA10.040.20 U0.04 *300.0 mg/L Sulfate 04/29/16 23:06 NA10.061.08.8300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 46 of 131 J1603103-007Lab Code: Sample Name:MW-14 Volatile Organic Compounds by GC/MS 04/27/16 09:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 15:305.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 15:301.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 15:303.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 15:301.0 U1.41,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 15:305.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 15:305.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 15:302.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 15:3013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 15:301.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 15:305.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 15:301.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 15:301.0 U1.21,4-Dichlorobenzene 0.16 1 05/06/16 15:301.0 3.82-Butanone (MEK)3.8 1 05/06/16 15:30100 U2.22-Hexanone 2.2 1 05/06/16 15:3050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 15:30100 U5.6Acetone 5.6 1 05/06/16 15:30100 U 1.5Acrylonitrile 1.5 1 05/06/16 15:30200 U0.75Benzene 0.21 1 05/06/16 15:301.0 J 0.27Bromochloromethane 0.27 1 05/06/16 15:305.0 U0.22Bromodichloromethane 0.22 1 05/06/16 15:301.0 U 0.42Bromoform 0.42 1 05/06/16 15:303.0 U0.23Bromomethane 0.23 1 05/06/16 15:3010 U 2.4Carbon Disulfide 2.4 1 05/06/16 15:30100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 15:301.0 U 3.3Chlorobenzene 0.16 1 05/06/16 15:303.0 0.52Chloroethane 0.52 1 05/06/16 15:3010 U 0.35Chloroform 0.35 1 05/06/16 15:305.0 U0.36Chloromethane 0.36 1 05/06/16 15:301.0 U 0.61cis-1,2-Dichloroethene 0.36 1 05/06/16 15:305.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 15:301.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 15:303.0 U0.36Dibromomethane 0.36 1 05/06/16 15:3010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 15:3020 U0.21Ethylbenzene 0.21 1 05/06/16 15:301.0 U 2.7Iodomethane 2.7 1 05/06/16 15:3010 U0.31m,p-Xylenes 0.31 1 05/06/16 15:302.0 U 0.21Methylene Chloride 0.21 1 05/06/16 15:305.0 U0.14o-Xylene 0.14 1 05/06/16 15:301.0 U 0.29Styrene 0.29 1 05/06/16 15:301.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 15:301.0 U 0.19Toluene 0.19 1 05/06/16 15:301.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 15:305.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:57 AM 16-0000374637 rev 00Superset Reference: Page 47 of 131 J1603103-007Lab Code: Sample Name:MW-14 Volatile Organic Compounds by GC/MS 04/27/16 09:30 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 15:301.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 15:30100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 15:301.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 15:3020 U1.9Vinyl Acetate 1.9 1 05/06/16 15:3050 U 0.36Vinyl Chloride 0.36 1 05/06/16 15:301.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 15:3072 - 1211061,2-Dichloroethane-d4 05/06/16 15:3086 - 1131044-Bromofluorobenzene 05/06/16 15:3086 - 112102Dibromofluoromethane 05/06/16 15:3088 - 115101Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:57 AM 16-0000374637 rev 00Superset Reference: Page 48 of 131 J1603103-007Lab Code: Sample Name:MW-14 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 09:30 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007041,2-Dibromo-3-chloropropane (DBCP)0.00704 1 05/04/16 17:40 5/4/160.0201 U 0.007041,2-Dibromoethane (EDB)0.00704 1 05/04/16 17:40 5/4/160.0201 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 17:4070 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 49 of 131 J1603103-007Lab Code: Sample Name:MW-14 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 09:30 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/30/16 01:580.50 U 0.50Acetic Acid 0.50 1 04/30/16 01:581.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/30/16 01:582.0 U 0.50Lactic Acid 0.50 1 04/30/16 01:581.0 U0.50Propionic Acid 0.50 1 04/30/16 01:581.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 50 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 09:30 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-14 Lab Code:J1603103-007 Antimony, Total 05/03/16 00:40 04/29/1610.26.0 J0.46020A ug/L Arsenic, Total 05/03/16 00:40 04/29/1610.510 J0.56020A ug/L Barium, Total 05/04/16 00:01 05/03/1610.31002406010Cug/L Beryllium, Total 05/03/16 00:40 04/29/1610.041.0 U0.046020A ug/L Cadmium, Total 05/03/16 00:40 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 00:40 04/29/1610.210 BJ36020A ug/L Cobalt, Total 05/03/16 00:40 04/29/1610.0310 J26020A ug/L Copper, Total 05/03/16 00:40 04/29/1610.310 J16020A ug/L Lead, Total 05/03/16 00:40 04/29/1610.210 U0.26020A ug/L Mercury, Total 05/10/16 17:42 05/09/1610.020.20 J0.127470A ug/L Nickel, Total 05/03/16 00:40 04/29/1610.550 J186020A ug/L Selenium, Total 05/03/16 00:40 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:01 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 00:40 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/04/16 00:01 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:40 04/29/161210 U26020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 51 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 09:30 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-14 Lab Code:J1603103-007 Alkalinity as CaCO3, Total 05/05/16 23:03 NA15.05.0245SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 23:03 NA15.05.0245SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.0 U2.0SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 21:04 NA10.061.02.4SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 23:03 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:06 05/05/1611220 U12SM21 5220 D mg/L Chloride 04/29/16 23:45 NA10.081.087.7300.0 mg/L Nitrate as Nitrogen 04/29/16 23:45 NA10.040.20 U0.04 *300.0 mg/L Sulfate 04/29/16 23:45 NA10.061.04.5300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 J0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 52 of 131 J1603103-008Lab Code: Sample Name:MW-15 Volatile Organic Compounds by GC/MS 04/27/16 08:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 15:535.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 15:531.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 15:533.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 15:531.0 U1.21,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 15:535.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 15:535.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 15:532.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 15:5313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 15:531.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 15:535.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 15:531.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 15:531.0 U1.51,4-Dichlorobenzene 0.16 1 05/06/16 15:531.0 3.82-Butanone (MEK)3.8 1 05/06/16 15:53100 U2.22-Hexanone 2.2 1 05/06/16 15:5350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 15:53100 U5.6Acetone 5.6 1 05/06/16 15:53100 U 1.5Acrylonitrile 1.5 1 05/06/16 15:53200 U0.34Benzene 0.21 1 05/06/16 15:531.0 J 0.27Bromochloromethane 0.27 1 05/06/16 15:535.0 U0.22Bromodichloromethane 0.22 1 05/06/16 15:531.0 U 0.42Bromoform 0.42 1 05/06/16 15:533.0 U0.23Bromomethane 0.23 1 05/06/16 15:5310 U 2.4Carbon Disulfide 2.4 1 05/06/16 15:53100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 15:531.0 U 5.3Chlorobenzene 0.16 1 05/06/16 15:533.0 0.52Chloroethane 0.52 1 05/06/16 15:5310 U 0.35Chloroform 0.35 1 05/06/16 15:535.0 U0.36Chloromethane 0.36 1 05/06/16 15:531.0 U 0.50cis-1,2-Dichloroethene 0.36 1 05/06/16 15:535.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 15:531.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 15:533.0 U0.36Dibromomethane 0.36 1 05/06/16 15:5310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 15:5320 U0.21Ethylbenzene 0.21 1 05/06/16 15:531.0 U 2.7Iodomethane 2.7 1 05/06/16 15:5310 U0.31m,p-Xylenes 0.31 1 05/06/16 15:532.0 U 0.21Methylene Chloride 0.21 1 05/06/16 15:535.0 U0.14o-Xylene 0.14 1 05/06/16 15:531.0 U 0.29Styrene 0.29 1 05/06/16 15:531.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 15:531.0 U 0.19Toluene 0.19 1 05/06/16 15:531.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 15:535.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:57 AM 16-0000374637 rev 00Superset Reference: Page 53 of 131 J1603103-008Lab Code: Sample Name:MW-15 Volatile Organic Compounds by GC/MS 04/27/16 08:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 15:531.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 15:53100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 15:531.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 15:5320 U1.9Vinyl Acetate 1.9 1 05/06/16 15:5350 U 0.36Vinyl Chloride 0.36 1 05/06/16 15:531.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 15:5372 - 1211031,2-Dichloroethane-d4 05/06/16 15:5386 - 1131034-Bromofluorobenzene 05/06/16 15:5386 - 112101Dibromofluoromethane 05/06/16 15:5388 - 115101Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 54 of 131 J1603103-008Lab Code: Sample Name:MW-15 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 08:45 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007091,2-Dibromo-3-chloropropane (DBCP)0.00709 1 05/04/16 18:06 5/4/160.0203 U 0.007091,2-Dibromoethane (EDB)0.00709 1 05/04/16 18:06 5/4/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 18:0670 - 130831,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 55 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 08:45 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-15 Lab Code:J1603103-008 Antimony, Total 05/03/16 00:45 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 00:45 04/29/1610.510 U0.56020A ug/L Barium, Total 05/04/16 00:06 05/03/1610.31002806010Cug/L Beryllium, Total 05/03/16 00:45 04/29/1610.041.0 J0.076020A ug/L Cadmium, Total 05/03/16 00:45 04/29/1610.101.0 J0.26020A ug/L Chromium, Total 05/03/16 00:45 04/29/1610.210 J56020A ug/L Cobalt, Total 05/03/16 00:45 04/29/1610.0310 J46020A ug/L Copper, Total 05/03/16 00:45 04/29/1610.310 J76020A ug/L Lead, Total 05/03/16 00:45 04/29/1610.210 J0.86020A ug/L Mercury, Total 05/10/16 17:43 05/09/1610.020.200.217470A ug/L Nickel, Total 05/03/16 00:45 04/29/1610.550 J326020A ug/L Selenium, Total 05/03/16 00:45 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:06 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 00:45 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/04/16 00:06 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:45 04/29/161210 J66020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 56 of 131 J1603103-009Lab Code: Sample Name:MW-16 Volatile Organic Compounds by GC/MS 04/27/16 07:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 16:165.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 16:161.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 16:163.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 16:161.0 U7.01,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 16:165.0 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 16:165.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 16:162.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 16:1613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 16:161.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 16:165.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 16:161.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 16:161.0 U0.261,4-Dichlorobenzene 0.16 1 05/06/16 16:161.0 J 3.82-Butanone (MEK)3.8 1 05/06/16 16:16100 U2.22-Hexanone 2.2 1 05/06/16 16:1650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 16:16100 U5.6Acetone 5.6 1 05/06/16 16:16100 U 1.5Acrylonitrile 1.5 1 05/06/16 16:16200 U1.0Benzene 0.21 1 05/06/16 16:161.0 0.27Bromochloromethane 0.27 1 05/06/16 16:165.0 U0.22Bromodichloromethane 0.22 1 05/06/16 16:161.0 U 0.42Bromoform 0.42 1 05/06/16 16:163.0 U0.23Bromomethane 0.23 1 05/06/16 16:1610 U 2.4Carbon Disulfide 2.4 1 05/06/16 16:16100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 16:161.0 U 0.39Chlorobenzene 0.16 1 05/06/16 16:163.0 J1.3Chloroethane 0.52 1 05/06/16 16:1610 J 0.35Chloroform 0.35 1 05/06/16 16:165.0 U0.36Chloromethane 0.36 1 05/06/16 16:161.0 U 3.3cis-1,2-Dichloroethene 0.36 1 05/06/16 16:165.0 J0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 16:161.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 16:163.0 U0.36Dibromomethane 0.36 1 05/06/16 16:1610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 16:1620 U0.21Ethylbenzene 0.21 1 05/06/16 16:161.0 U 2.7Iodomethane 2.7 1 05/06/16 16:1610 U0.31m,p-Xylenes 0.31 1 05/06/16 16:162.0 U 0.21Methylene Chloride 0.21 1 05/06/16 16:165.0 U0.14o-Xylene 0.14 1 05/06/16 16:161.0 U 0.29Styrene 0.29 1 05/06/16 16:161.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 16:161.0 U 0.19Toluene 0.19 1 05/06/16 16:161.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 16:165.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 57 of 131 J1603103-009Lab Code: Sample Name:MW-16 Volatile Organic Compounds by GC/MS 04/27/16 07:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 16:161.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 16:16100 U2.0Trichloroethene (TCE)0.36 1 05/06/16 16:161.0 0.24Trichlorofluoromethane 0.24 1 05/06/16 16:1620 U1.9Vinyl Acetate 1.9 1 05/06/16 16:1650 U 0.49Vinyl Chloride 0.36 1 05/06/16 16:161.0 J Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 16:1672 - 1211041,2-Dichloroethane-d4 05/06/16 16:1686 - 1131054-Bromofluorobenzene 05/06/16 16:1686 - 112104Dibromofluoromethane 05/06/16 16:1688 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 58 of 131 J1603103-009Lab Code: Sample Name:MW-16 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 07:45 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/04/16 18:56 5/4/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/04/16 18:56 5/4/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 18:5670 - 130851,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 59 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 07:45 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-16 Lab Code:J1603103-009 Antimony, Total 05/03/16 00:51 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 00:51 04/29/1610.510126020Aug/L Barium, Total 05/04/16 00:10 05/03/1610.31003306010Cug/L Beryllium, Total 05/03/16 00:51 04/29/1610.041.0 U0.046020A ug/L Cadmium, Total 05/03/16 00:51 04/29/1610.101.0 J0.76020A ug/L Chromium, Total 05/03/16 00:51 04/29/1610.210 U0.26020A ug/L Cobalt, Total 05/03/16 00:51 04/29/1610.0310 J46020A ug/L Copper, Total 05/03/16 00:51 04/29/1610.310 J0.56020A ug/L Lead, Total 05/03/16 00:51 04/29/1610.210 U0.26020A ug/L Mercury, Total 05/10/16 17:49 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 00:51 04/29/1610.550 J86020A ug/L Selenium, Total 05/03/16 00:51 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:10 05/03/1610.610 J16010C ug/L Thallium, Total 05/03/16 00:51 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/04/16 00:10 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 00:51 04/29/161210 J46020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 60 of 131 J1603103-010Lab Code: Sample Name:MW-20 Volatile Organic Compounds by GC/MS 04/27/16 14:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 16:405.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 16:401.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 16:403.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 16:401.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 16:405.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 16:405.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 16:402.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 16:4013 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 16:401.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 16:405.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 16:401.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 16:401.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 16:401.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 16:40100 U2.22-Hexanone 2.2 1 05/06/16 16:4050 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 16:40100 U5.6Acetone 5.6 1 05/06/16 16:40100 U 1.5Acrylonitrile 1.5 1 05/06/16 16:40200 U0.21Benzene 0.21 1 05/06/16 16:401.0 U 0.27Bromochloromethane 0.27 1 05/06/16 16:405.0 U0.22Bromodichloromethane 0.22 1 05/06/16 16:401.0 U 0.42Bromoform 0.42 1 05/06/16 16:403.0 U0.23Bromomethane 0.23 1 05/06/16 16:4010 U 2.4Carbon Disulfide 2.4 1 05/06/16 16:40100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 16:401.0 U 0.16Chlorobenzene 0.16 1 05/06/16 16:403.0 U0.52Chloroethane 0.52 1 05/06/16 16:4010 U 0.35Chloroform 0.35 1 05/06/16 16:405.0 U0.36Chloromethane 0.36 1 05/06/16 16:401.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 16:405.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 16:401.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 16:403.0 U0.36Dibromomethane 0.36 1 05/06/16 16:4010 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 16:4020 U0.21Ethylbenzene 0.21 1 05/06/16 16:401.0 U 2.7Iodomethane 2.7 1 05/06/16 16:4010 U0.31m,p-Xylenes 0.31 1 05/06/16 16:402.0 U 0.21Methylene Chloride 0.21 1 05/06/16 16:405.0 U0.14o-Xylene 0.14 1 05/06/16 16:401.0 U 0.29Styrene 0.29 1 05/06/16 16:401.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 16:401.0 U 0.19Toluene 0.19 1 05/06/16 16:401.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 16:405.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 61 of 131 J1603103-010Lab Code: Sample Name:MW-20 Volatile Organic Compounds by GC/MS 04/27/16 14:45 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 16:401.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 16:40100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 16:401.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 16:4020 U1.9Vinyl Acetate 1.9 1 05/06/16 16:4050 U 0.36Vinyl Chloride 0.36 1 05/06/16 16:401.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 16:4072 - 1211041,2-Dichloroethane-d4 05/06/16 16:4086 - 1131044-Bromofluorobenzene 05/06/16 16:4086 - 112102Dibromofluoromethane 05/06/16 16:4088 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 62 of 131 J1603103-010Lab Code: Sample Name:MW-20 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 14:45 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007051,2-Dibromo-3-chloropropane (DBCP)0.00705 1 05/04/16 19:21 5/4/160.0201 U 0.007051,2-Dibromoethane (EDB)0.00705 1 05/04/16 19:21 5/4/160.0201 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 19:2170 - 130981,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 63 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 14:45 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-20 Lab Code:J1603103-010 Antimony, Total 05/03/16 00:56 04/29/1610.26.0 J0.26020A ug/L Arsenic, Total 05/03/16 00:56 04/29/1610.510 J46020A ug/L Barium, Total 05/04/16 00:36 05/03/1610.31002406010Cug/L Beryllium, Total 05/03/16 00:56 04/29/1610.041.0 J0.26020A ug/L Cadmium, Total 05/03/16 00:56 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 00:56 04/29/1610.210 J76020A ug/L Cobalt, Total 05/03/16 00:56 04/29/1610.0310 J56020A ug/L Copper, Total 05/03/16 00:56 04/29/1610.310 J86020A ug/L Lead, Total 05/03/16 00:56 04/29/1610.210 J46020A ug/L Mercury, Total 05/10/16 17:50 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 00:56 04/29/1610.550 J96020A ug/L Selenium, Total 05/03/16 00:56 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:36 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 00:56 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/04/16 00:36 05/03/1611.025 J16010C ug/L Zinc, Total 05/03/16 00:56 04/29/161210286020Aug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 64 of 131 J1603103-011Lab Code: Sample Name:MW-29 Volatile Organic Compounds by GC/MS 04/27/16 12:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 17:035.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 17:031.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 17:033.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 17:031.0 U1.01,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 17:035.0 J 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 17:035.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 17:032.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 17:0313 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 17:031.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 17:035.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 17:031.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 17:031.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 17:031.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 17:03100 U2.22-Hexanone 2.2 1 05/06/16 17:0350 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 17:03100 U5.6Acetone 5.6 1 05/06/16 17:03100 U 1.5Acrylonitrile 1.5 1 05/06/16 17:03200 U0.21Benzene 0.21 1 05/06/16 17:031.0 U 0.27Bromochloromethane 0.27 1 05/06/16 17:035.0 U0.22Bromodichloromethane 0.22 1 05/06/16 17:031.0 U 0.42Bromoform 0.42 1 05/06/16 17:033.0 U0.23Bromomethane 0.23 1 05/06/16 17:0310 U 2.4Carbon Disulfide 2.4 1 05/06/16 17:03100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 17:031.0 U 0.16Chlorobenzene 0.16 1 05/06/16 17:033.0 U0.52Chloroethane 0.52 1 05/06/16 17:0310 U 0.35Chloroform 0.35 1 05/06/16 17:035.0 U0.36Chloromethane 0.36 1 05/06/16 17:031.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 17:035.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 17:031.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 17:033.0 U0.36Dibromomethane 0.36 1 05/06/16 17:0310 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 17:0320 U0.21Ethylbenzene 0.21 1 05/06/16 17:031.0 U 2.7Iodomethane 2.7 1 05/06/16 17:0310 U0.31m,p-Xylenes 0.31 1 05/06/16 17:032.0 U 0.21Methylene Chloride 0.21 1 05/06/16 17:035.0 U0.14o-Xylene 0.14 1 05/06/16 17:031.0 U 0.29Styrene 0.29 1 05/06/16 17:031.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 17:031.0 U 0.19Toluene 0.19 1 05/06/16 17:031.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 17:035.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:58 AM 16-0000374637 rev 00Superset Reference: Page 65 of 131 J1603103-011Lab Code: Sample Name:MW-29 Volatile Organic Compounds by GC/MS 04/27/16 12:15 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 17:031.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 17:03100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 17:031.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 17:0320 U1.9Vinyl Acetate 1.9 1 05/06/16 17:0350 U 0.36Vinyl Chloride 0.36 1 05/06/16 17:031.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 17:0372 - 1211031,2-Dichloroethane-d4 05/06/16 17:0386 - 1131054-Bromofluorobenzene 05/06/16 17:0386 - 112103Dibromofluoromethane 05/06/16 17:0388 - 115104Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:59 AM 16-0000374637 rev 00Superset Reference: Page 66 of 131 J1603103-011Lab Code: Sample Name:MW-29 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 12:15 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007101,2-Dibromo-3-chloropropane (DBCP)0.00710 1 05/04/16 19:46 5/4/160.0203 U 0.007101,2-Dibromoethane (EDB)0.00710 1 05/04/16 19:46 5/4/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 19:4670 - 1301131,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 67 of 131 J1603103-011Lab Code: Sample Name:MW-29 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time 04/27/16 12:15 NA mg/L Basis: Units: Organic AcidsAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/30/16 02:430.50 U 0.50Acetic Acid 0.50 1 04/30/16 02:431.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/30/16 02:432.0 U 0.50Lactic Acid 0.50 1 04/30/16 02:431.0 U0.50Propionic Acid 0.50 1 04/30/16 02:431.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 68 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 12:15 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-29 Lab Code:J1603103-011 Antimony, Total 05/03/16 01:01 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 01:01 04/29/1610.510 J36020A ug/L Barium, Total 05/04/16 00:40 05/03/1610.31003506010Cug/L Beryllium, Total 05/03/16 01:01 04/29/1610.041.01.56020A ug/L Cadmium, Total 05/03/16 01:01 04/29/1610.101.0 J0.26020A ug/L Chromium, Total 05/03/16 01:01 04/29/1610.210196020Aug/L Cobalt, Total 05/03/16 01:01 04/29/1610.0310116020Aug/L Copper, Total 05/03/16 01:01 04/29/1610.310256020Aug/L Lead, Total 05/03/16 01:01 04/29/1610.210216020Aug/L Mercury, Total 05/10/16 17:52 05/09/1610.020.20 J0.067470A ug/L Nickel, Total 05/03/16 01:01 04/29/1610.550 J206020A ug/L Selenium, Total 05/03/16 01:01 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:40 05/03/1610.610 U0.66010C ug/L Sodium, Total 05/04/16 00:39 05/03/1610.040.5011.06010C mg/L Thallium, Total 05/03/16 01:01 04/29/1610.055.5 J0.16020A ug/L Vanadium, Total 05/04/16 00:40 05/03/1611.025466010Cug/L Zinc, Total 05/03/16 01:01 04/29/161210706020Aug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:14 AM 16-0000374637 rev 00Superset Reference: Page 69 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 12:15 General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:MW-29 Lab Code:J1603103-011 Alkalinity as CaCO3, Total 05/05/16 23:09 NA15.05.058.6SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 23:09 NA15.05.058.6SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.02.5SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 21:22 NA10.061.011.7SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 23:09 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 14:07 05/05/161122054SM21 5220 D mg/L Chloride 04/29/16 23:58 NA10.081.08.3300.0 mg/L Nitrate as Nitrogen 04/29/16 23:58 NA10.040.20 U0.04 *300.0 mg/L Solids, Total Dissolved 05/02/16 12:43 NA11010176SM 2540 C mg/L Sulfate 04/29/16 23:58 NA10.061.02.3300.0 mg/L Sulfide, Total 05/03/16 14:14 NA20.84.0 U0.8SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 70 of 131 J1603103-012Lab Code: Sample Name:EQ BLANK Volatile Organic Compounds by GC/MS 04/27/16 15:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 12:465.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 12:461.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 12:463.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 12:461.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 12:465.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 12:465.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 12:462.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 12:4613 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 12:461.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 12:465.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 12:461.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 12:461.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 12:461.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 12:46100 U2.22-Hexanone 2.2 1 05/06/16 12:4650 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 12:46100 U12Acetone 5.6 1 05/06/16 12:46100 J 1.5Acrylonitrile 1.5 1 05/06/16 12:46200 U0.21Benzene 0.21 1 05/06/16 12:461.0 U 0.27Bromochloromethane 0.27 1 05/06/16 12:465.0 U0.22Bromodichloromethane 0.22 1 05/06/16 12:461.0 U 0.42Bromoform 0.42 1 05/06/16 12:463.0 U0.23Bromomethane 0.23 1 05/06/16 12:4610 U 2.4Carbon Disulfide 2.4 1 05/06/16 12:46100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 12:461.0 U 0.16Chlorobenzene 0.16 1 05/06/16 12:463.0 U0.52Chloroethane 0.52 1 05/06/16 12:4610 U 0.35Chloroform 0.35 1 05/06/16 12:465.0 U0.36Chloromethane 0.36 1 05/06/16 12:461.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 12:465.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 12:461.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 12:463.0 U0.36Dibromomethane 0.36 1 05/06/16 12:4610 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 12:4620 U0.21Ethylbenzene 0.21 1 05/06/16 12:461.0 U 2.7Iodomethane 2.7 1 05/06/16 12:4610 U0.31m,p-Xylenes 0.31 1 05/06/16 12:462.0 U 0.21Methylene Chloride 0.21 1 05/06/16 12:465.0 U0.14o-Xylene 0.14 1 05/06/16 12:461.0 U 0.29Styrene 0.29 1 05/06/16 12:461.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 12:461.0 U 0.19Toluene 0.19 1 05/06/16 12:461.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 12:465.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:59 AM 16-0000374637 rev 00Superset Reference: Page 71 of 131 J1603103-012Lab Code: Sample Name:EQ BLANK Volatile Organic Compounds by GC/MS 04/27/16 15:20 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 12:461.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 12:46100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 12:461.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 12:4620 U1.9Vinyl Acetate 1.9 1 05/06/16 12:4650 U 0.36Vinyl Chloride 0.36 1 05/06/16 12:461.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 12:4672 - 1211051,2-Dichloroethane-d4 05/06/16 12:4686 - 1131064-Bromofluorobenzene 05/06/16 12:4686 - 112101Dibromofluoromethane 05/06/16 12:4688 - 115102Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:59 AM 16-0000374637 rev 00Superset Reference: Page 72 of 131 J1603103-012Lab Code: Sample Name:EQ BLANK 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography 04/27/16 15:20 NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007111,2-Dibromo-3-chloropropane (DBCP)0.00711 1 05/04/16 20:11 5/4/160.0203 U 0.007111,2-Dibromoethane (EDB)0.00711 1 05/04/16 20:11 5/4/160.0203 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 20:1170 - 130941,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 73 of 131 Client: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:04/27/16 15:20 Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:EQ BLANK Lab Code:J1603103-012 Antimony, Total 05/03/16 01:07 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/03/16 01:07 04/29/1610.510 U0.56020A ug/L Barium, Total 05/04/16 00:57 05/03/1610.3100 U0.36010C ug/L Beryllium, Total 05/03/16 01:07 04/29/1610.041.0 U0.046020A ug/L Cadmium, Total 05/03/16 01:07 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/03/16 01:07 04/29/1610.210 U0.26020A ug/L Cobalt, Total 05/03/16 01:07 04/29/1610.0310 U0.036020A ug/L Copper, Total 05/03/16 01:07 04/29/1610.310 J0.46020A ug/L Lead, Total 05/03/16 01:07 04/29/1610.210 U0.26020A ug/L Mercury, Total 05/10/16 17:53 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/03/16 01:07 04/29/1610.550 U0.56020A ug/L Selenium, Total 05/03/16 01:07 04/29/161210 U26020A ug/L Silver, Total 05/04/16 00:57 05/03/1610.610 U0.66010C ug/L Thallium, Total 05/03/16 01:07 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/04/16 00:57 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/03/16 01:07 04/29/161210 U26020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:14 AM 16-0000374637 rev 00Superset Reference: Page 74 of 131 J1603103-013Lab Code: Sample Name:TRIP BLANK 2 Volatile Organic Compounds by GC/MS 04/27/16 00:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 12:225.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 12:221.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 12:223.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 12:221.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 12:225.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 12:225.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 12:222.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 12:2213 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 12:221.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 12:225.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 12:221.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 12:221.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 12:221.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 12:22100 U2.22-Hexanone 2.2 1 05/06/16 12:2250 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 12:22100 U5.6Acetone 5.6 1 05/06/16 12:22100 U 1.5Acrylonitrile 1.5 1 05/06/16 12:22200 U0.21Benzene 0.21 1 05/06/16 12:221.0 U 0.27Bromochloromethane 0.27 1 05/06/16 12:225.0 U0.22Bromodichloromethane 0.22 1 05/06/16 12:221.0 U 0.42Bromoform 0.42 1 05/06/16 12:223.0 U0.23Bromomethane 0.23 1 05/06/16 12:2210 U 2.4Carbon Disulfide 2.4 1 05/06/16 12:22100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 12:221.0 U 0.16Chlorobenzene 0.16 1 05/06/16 12:223.0 U0.52Chloroethane 0.52 1 05/06/16 12:2210 U 0.35Chloroform 0.35 1 05/06/16 12:225.0 U0.36Chloromethane 0.36 1 05/06/16 12:221.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 12:225.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 12:221.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 12:223.0 U0.36Dibromomethane 0.36 1 05/06/16 12:2210 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 12:2220 U0.21Ethylbenzene 0.21 1 05/06/16 12:221.0 U 2.7Iodomethane 2.7 1 05/06/16 12:2210 U0.31m,p-Xylenes 0.31 1 05/06/16 12:222.0 U 0.21Methylene Chloride 0.21 1 05/06/16 12:225.0 U0.14o-Xylene 0.14 1 05/06/16 12:221.0 U 0.29Styrene 0.29 1 05/06/16 12:221.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 12:221.0 U 0.19Toluene 0.19 1 05/06/16 12:221.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 12:225.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:59 AM 16-0000374637 rev 00Superset Reference: Page 75 of 131 J1603103-013Lab Code: Sample Name:TRIP BLANK 2 Volatile Organic Compounds by GC/MS 04/27/16 00:00 NA ug/L Basis: Units: 8260BAnalysis Method: 04/28/16 09:55 J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 12:221.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 12:22100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 12:221.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 12:2220 U1.9Vinyl Acetate 1.9 1 05/06/16 12:2250 U 0.36Vinyl Chloride 0.36 1 05/06/16 12:221.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 12:2272 - 1211031,2-Dichloroethane-d4 05/06/16 12:2286 - 1131084-Bromofluorobenzene 05/06/16 12:2286 - 112107Dibromofluoromethane 05/06/16 12:2288 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:50:59 AM 16-0000374637 rev 00Superset Reference: Page 76 of 131 JQ1603518-05Lab Code: Sample Name:Method Blank Volatile Organic Compounds by GC/MS NA NA ug/L Basis: Units: 8260BAnalysis Method: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.191,1,1,2-Tetrachloroethane 0.19 1 05/06/16 11:595.0 U 0.171,1,1-Trichloroethane (TCA)0.17 1 05/06/16 11:591.0 U0.291,1,2,2-Tetrachloroethane 0.29 1 05/06/16 11:593.0 U 0.401,1,2-Trichloroethane 0.40 1 05/06/16 11:591.0 U0.301,1-Dichloroethane (1,1-DCA)0.30 1 05/06/16 11:595.0 U 0.161,1-Dichloroethene (1,1-DCE)0.16 1 05/06/16 11:595.0 U0.421,2,3-Trichloropropane 0.42 1 05/06/16 11:592.0 U 2.31,2-Dibromo-3-chloropropane (DBCP)2.3 1 05/06/16 11:5913 U0.461,2-Dibromoethane (EDB)0.46 1 05/06/16 11:591.0 U 0.481,2-Dichlorobenzene 0.48 1 05/06/16 11:595.0 U0.221,2-Dichloroethane 0.22 1 05/06/16 11:591.0 U 0.191,2-Dichloropropane 0.19 1 05/06/16 11:591.0 U0.161,4-Dichlorobenzene 0.16 1 05/06/16 11:591.0 U 3.82-Butanone (MEK)3.8 1 05/06/16 11:59100 U2.22-Hexanone 2.2 1 05/06/16 11:5950 U 1.14-Methyl-2-pentanone (MIBK)1.1 1 05/06/16 11:59100 U5.6Acetone 5.6 1 05/06/16 11:59100 U 1.5Acrylonitrile 1.5 1 05/06/16 11:59200 U0.21Benzene 0.21 1 05/06/16 11:591.0 U 0.27Bromochloromethane 0.27 1 05/06/16 11:595.0 U0.22Bromodichloromethane 0.22 1 05/06/16 11:591.0 U 0.42Bromoform 0.42 1 05/06/16 11:593.0 U0.23Bromomethane 0.23 1 05/06/16 11:5910 U 2.4Carbon Disulfide 2.4 1 05/06/16 11:59100 U0.34Carbon Tetrachloride 0.34 1 05/06/16 11:591.0 U 0.16Chlorobenzene 0.16 1 05/06/16 11:593.0 U0.52Chloroethane 0.52 1 05/06/16 11:5910 U 0.35Chloroform 0.35 1 05/06/16 11:595.0 U0.36Chloromethane 0.36 1 05/06/16 11:591.0 U 0.36cis-1,2-Dichloroethene 0.36 1 05/06/16 11:595.0 U0.20cis-1,3-Dichloropropene 0.20 1 05/06/16 11:591.0 U 0.21Dibromochloromethane 0.21 1 05/06/16 11:593.0 U0.36Dibromomethane 0.36 1 05/06/16 11:5910 U 0.23Dichlorodifluoromethane 0.23 1 05/06/16 11:5920 U0.21Ethylbenzene 0.21 1 05/06/16 11:591.0 U 2.7Iodomethane 2.7 1 05/06/16 11:5910 U0.31m,p-Xylenes 0.31 1 05/06/16 11:592.0 U 0.45Methylene Chloride 0.21 1 05/06/16 11:595.0 J0.14o-Xylene 0.14 1 05/06/16 11:591.0 U 0.29Styrene 0.29 1 05/06/16 11:591.0 U0.22Tetrachloroethene (PCE)0.22 1 05/06/16 11:591.0 U 0.19Toluene 0.19 1 05/06/16 11:591.0 U0.19trans-1,2-Dichloroethene 0.19 1 05/06/16 11:595.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:00 AM 16-0000374637 rev 00Superset Reference: Page 77 of 131 JQ1603518-05Lab Code: Sample Name:Method Blank Volatile Organic Compounds by GC/MS NA NA ug/L Basis: Units: 8260BAnalysis Method: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.23trans-1,3-Dichloropropene 0.23 1 05/06/16 11:591.0 U 2.2trans-1,4-Dichloro-2-butene 2.2 1 05/06/16 11:59100 U0.36Trichloroethene (TCE)0.36 1 05/06/16 11:591.0 U 0.24Trichlorofluoromethane 0.24 1 05/06/16 11:5920 U1.9Vinyl Acetate 1.9 1 05/06/16 11:5950 U 0.36Vinyl Chloride 0.36 1 05/06/16 11:591.0 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/06/16 11:5972 - 1211041,2-Dichloroethane-d4 05/06/16 11:5986 - 1131054-Bromofluorobenzene 05/06/16 11:5986 - 112103Dibromofluoromethane 05/06/16 11:5988 - 115103Toluene-d8 Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:01 AM 16-0000374637 rev 00Superset Reference: Page 78 of 131 JQ1603357-01Lab Code: Sample Name:Method Blank 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography NA NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/03/16 08:37 5/2/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/03/16 08:37 5/2/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/03/16 08:3770 - 130991,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:05 AM 16-0000374637 rev 00Superset Reference: Page 79 of 131 JQ1603443-01Lab Code: Sample Name:Method Blank 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography NA NA ug/L Basis: Units: 8011Analysis Method: MethodPrep Method: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate Analyzed Date ExtractedDil.MDLPQLResult 0.007001,2-Dibromo-3-chloropropane (DBCP)0.00700 1 05/04/16 14:19 5/4/160.0200 U 0.007001,2-Dibromoethane (EDB)0.00700 1 05/04/16 14:19 5/4/160.0200 U Surrogate Name Q% Rec Control Limits Date Analyzed 05/04/16 14:1970 - 1301021,1,1,2-Tetrachloroethane Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:06 AM 16-0000374637 rev 00Superset Reference: Page 80 of 131 RQ1604817-01Lab Code: Sample Name:Method Blank Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time NA NA mg/L Basis: Units: Organic AcidsAnalysis Method: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Analyte Name QDate AnalyzedDil.MDLPQLResult 0.020Pyruvic Acid 0.020 1 04/29/16 14:190.50 U 0.50Acetic Acid 0.50 1 04/29/16 14:191.0 U1.0Butanoic Acid (Butyric Acid)1.0 1 04/29/16 14:192.0 U 0.50Lactic Acid 0.50 1 04/29/16 14:191.0 U0.50Propionic Acid 0.50 1 04/29/16 14:191.0 U Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:09 AM 16-0000374637 rev 00Superset Reference: Page 81 of 131 Client: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:NA Inorganic Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:Method Blank Lab Code:J1603103-MB Antimony, Total 05/02/16 22:37 04/29/1610.26.0 U0.26020A ug/L Arsenic, Total 05/02/16 22:37 04/29/1610.510 U0.56020A ug/L Barium, Total 05/03/16 23:01 05/03/1610.3100 J26010C ug/L Beryllium, Total 05/02/16 22:37 04/29/1610.041.0 U0.046020A ug/L Cadmium, Total 05/02/16 22:37 04/29/1610.101.0 U0.106020A ug/L Chromium, Total 05/02/16 22:37 04/29/1610.210 J0.36020A ug/L Cobalt, Total 05/02/16 22:37 04/29/1610.0310 U0.036020A ug/L Copper, Total 05/02/16 22:37 04/29/1610.310 U0.36020A ug/L Lead, Total 05/02/16 22:37 04/29/1610.210 U0.26020A ug/L Mercury, Total 05/10/16 17:30 05/09/1610.020.20 U0.027470A ug/L Nickel, Total 05/02/16 22:37 04/29/1610.550 U0.56020A ug/L Selenium, Total 05/02/16 22:37 04/29/161210 U26020A ug/L Silver, Total 05/03/16 23:01 05/03/1610.610 U0.66010C ug/L Sodium, Total 05/03/16 23:00 05/03/1610.040.50 U0.046010C mg/L Thallium, Total 05/02/16 22:37 04/29/1610.055.5 U0.056020A ug/L Vanadium, Total 05/03/16 23:01 05/03/1611.025 U1.06010C ug/L Zinc, Total 05/02/16 22:37 04/29/161210 U26020A ug/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:14 AM 16-0000374637 rev 00Superset Reference: Page 82 of 131 Client: NA J1603103 Date Received: Date Collected: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project:NA General Chemistry Parameters Basis:NA Analysis MethodAnalyte Name QDate Analyzed Date ExtractedDil.MDLPQLResultUnits Sample Name:Method Blank Lab Code:J1603103-MB Alkalinity as CaCO3, Total 05/05/16 20:25 NA15.05.0 U5.0SM 2320 B mg/L Bicarbonate Alkalinity as CaCO3 05/05/16 20:25 NA15.05.0 U5.0SM 2320 B mg/L Biochemical Oxygen Demand (BOD)04/29/16 07:00 NA12.02.0 U2.0SM 5210 B mg/L Carbon, Total Organic (TOC)05/04/16 16:10 NA10.061.0 J0.3SM 5310 B mg/L Carbonate Alkalinity as CaCO3 05/05/16 20:25 NA15.05.0 U5.0SM 2320 B mg/L Chemical Oxygen Demand, Total 05/05/16 13:56 05/05/1611220 U12SM21 5220 D mg/L Chloride 04/29/16 21:10 NA10.081.0 U0.08300.0 mg/L Nitrate as Nitrogen 04/29/16 21:10 NA10.040.20 U0.04300.0 mg/L Solids, Total Dissolved 05/02/16 12:43 NA11010 U10SM 2540 C mg/L Sulfate 04/29/16 21:10 NA10.061.0 U0.06300.0 mg/L Sulfide, Total 05/03/16 14:14 NA10.42.0 U0.4SM 4500-S2- F mg/L Analytical Report ALS Group USA, Corp. dba ALS Environmental Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 83 of 131 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8260B Sample Name Lab Code 1,2-Dichloroethane-d4 4-Bromofluorobenzene Dibromofluoromethane 72 - 121 86 - 113 86 - 112 Volatile Organic Compounds by GC/MS MW-6 J1603103-001 104 103 104 MW-9 J1603103-002 101 104 104 MW-10 J1603103-003 102 103 105 MW-11 J1603103-004 102 104 104 MW-12 J1603103-005 102 104 103 MW-13 J1603103-006 102 105 105 MW-14 J1603103-007 102 104 106 MW-15 J1603103-008 101 103 103 MW-16 J1603103-009 104 105 104 MW-20 J1603103-010 102 104 104 MW-29 J1603103-011 103 105 103 EQ BLANK J1603103-012 101 106 105 TRIP BLANK 2 J1603103-013 107 108 103 Lab Control Sample JQ1603518-03 101 98 100 Duplicate Lab Control Sample JQ1603518-04 103 99 101 Method Blank JQ1603518-05 103 105 104 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 dba ALS Environmental 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:01 AM Page 84 of 131 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8260B Sample Name Lab Code Toluene-d8 88 - 115 Volatile Organic Compounds by GC/MS MW-6 J1603103-001 101 MW-9 J1603103-002 101 MW-10 J1603103-003 103 MW-11 J1603103-004 102 MW-12 J1603103-005 103 MW-13 J1603103-006 102 MW-14 J1603103-007 101 MW-15 J1603103-008 101 MW-16 J1603103-009 102 MW-20 J1603103-010 103 MW-29 J1603103-011 104 EQ BLANK J1603103-012 102 TRIP BLANK 2 J1603103-013 103 Lab Control Sample JQ1603518-03 99 Duplicate Lab Control Sample JQ1603518-04 100 Method Blank JQ1603518-05 103 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 dba ALS Environmental 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:01 AM Page 85 of 131 Duplicate Lab Control Sample JQ1603518-04 Lab Control Sample JQ1603518-03 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Volatile Organic Compounds by GC/MS Analysis Method:8260B NA ug/L Basis: Units: Analysis Lot:495104 05/06/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 52.8 50.01,1,1,2-Tetrachloroethane 302 77-118108 50.053.8 106 49.8 50.01,1,1-Trichloroethane (TCA)30<1 70-12299 50.049.6 100 52.5 50.01,1,2,2-Tetrachloroethane 302 66-135107 50.053.4 105 51.9 50.01,1,2-Trichloroethane 30<1 75-122104 50.052.2 104 53.9 50.01,1-Dichloroethane (1,1-DCA)30<1 79-117109 50.054.4 108 53.2 50.01,1-Dichloroethene (1,1-DCE)30<1 72-128105 50.052.7 106 53.5 50.01,2,3-Trichloropropane 303 70-123110 50.054.9 107 54.5 50.01,2-Dibromo-3-chloropropane (DBCP)304 60-122114 50.056.8 109 52.3 50.01,2-Dibromoethane (EDB)301 76-118106 50.053.0 105 51.8 50.01,2-Dichlorobenzene 301 81-115105 50.052.4 104 51.0 50.01,2-Dichloroethane 301 70-117101 50.050.4 102 51.3 50.01,2-Dichloropropane 30<1 79-117103 50.051.5 103 50.8 50.01,4-Dichlorobenzene 30<1 82-115102 50.051.0 102 55.1 J 50.02-Butanone (MEK)30<1 62-138111 50.055.7 J 110 54.0 50.02-Hexanone 304 74-127112 50.056.0 108 52.7 J 50.04-Methyl-2-pentanone (MIBK)303 77-120109 50.054.6 J 105 54.4 J 50.0Acetone 302 42-161111 50.055.4 J 109 53.7 J 50.0Acrylonitrile 304 63-132111 50.055.6 J 107 53.9 50.0Benzene 30<1 80-117108 50.053.8 108 53.3 50.0Bromochloromethane 302 78-118105 50.052.3 107 54.9 50.0Bromodichloromethane 30<1 75-118110 50.055.2 110 48.9 50.0Bromoform 301 63-12199 50.049.5 98 48.6 50.0Bromomethane 30<1 31-15396 50.048.2 97 47.4 J 50.0Carbon Disulfide 302 72-12893 50.046.5 J 95 50.2 50.0Carbon Tetrachloride 302 67-12499 50.049.5 100 51.6 50.0Chlorobenzene 301 83-118104 50.052.2 103 52.3 50.0Chloroethane 301 68-132106 50.052.9 105 53.5 50.0Chloroform 30<1 77-116106 50.053.0 107 48.6 50.0Chloromethane 30<1 60-12898 50.048.8 97 51.2 50.0cis-1,2-Dichloroethene 301 78-117104 50.052.0 102 46.7 50.0cis-1,3-Dichloropropene 301 80-11994 50.047.2 93 48.7 50.0Dibromochloromethane 30<1 74-12198 50.048.9 97 53.4 50.0Dibromomethane 304 76-117103 50.051.5 107 50.0 50.0Dichlorodifluoromethane 30<1 49-132100 50.050.1 100 53.3 50.0Ethylbenzene 30<1 82-119107 50.053.7 107 40.9 50.0Iodomethane 30<1 51-13782 50.041.3 82 97.7 100m,p-Xylenes 30<1 79-12297 10097.3 98 49.0 50.0Methylene Chloride 304 75-12394 50.047.2 98 47.4 50.0o-Xylene 302 80-11997 50.048.5 95 48.3 50.0Styrene 302 80-12199 50.049.4 96 54.2 50.0Tetrachloroethene (PCE)302 75-126107 50.053.3 108 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:00 AM Page 86 of 131 Duplicate Lab Control Sample JQ1603518-04 Lab Control Sample JQ1603518-03 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Volatile Organic Compounds by GC/MS Analysis Method:8260B NA ug/L Basis: Units: Analysis Lot:495104 05/06/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 52.9 50.0Toluene 30<1 52-152107 50.053.4 106 48.2 50.0trans-1,2-Dichloroethene 30<1 75-12196 50.048.0 96 47.4 50.0trans-1,3-Dichloropropene 301 76-11896 50.047.9 95 48.1 J 50.0trans-1,4-Dichloro-2-butene 302 10-19899 50.049.3 J 96 48.8 50.0Trichloroethene (TCE)30<1 78-12298 50.049.2 98 57.1 50.0Trichlorofluoromethane 30<1 58-134114 50.056.9 114 46.8 J 50.0Vinyl Acetate 303 36-16996 50.048.1 J 94 59.8 50.0Vinyl Chloride 301 69-138118 50.059.2 120 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:00 AM Page 87 of 131 Sample Matrix:Ground Water SURROGATE RECOVERY SUMMARY Analysis Method:8011 Extraction Method:Method Sample Name Lab Code 1,1,1,2-Tetrachloroethane 70 - 130 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography MW-6 J1603103-001 81 MW-9 J1603103-002 109 MW-10 J1603103-003 70 MW-11 J1603103-004 83 MW-12 J1603103-005 77 MW-13 J1603103-006 84 MW-14 J1603103-007 83 MW-15 J1603103-008 83 MW-16 J1603103-009 85 MW-20 J1603103-010 98 MW-29 J1603103-011 113 EQ BLANK J1603103-012 94 Method Blank JQ1603357-01 99 Lab Control Sample JQ1603357-02 99 Method Blank JQ1603443-01 102 Lab Control Sample JQ1603443-02 96 MW-13 JQ1603443-03 95 MW-13 JQ1603443-04 85 ALS Group USA, Corp. QA/QC Report Client: Project:Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 dba ALS Environmental 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:06 AM Page 88 of 131 QA/QC Report ug/L J1603103-006 Basis:Lab Code: Units:Sample Name:MW-13 1,2-Dibromoethane and 1,2-Dibromo-3-chloropropane by Microextraction and Gas Chromatography Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 05/4/16 04/28/16 Date Collected:04/27/16 Method 8011 Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike JQ1603443-03 JQ1603443-04 Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/4/16Date Extracted: 1,2-Dibromo-3-chloropropane (DBCP)0.00700 U 0.213 0.254 84 0.216 0.249 87 65-135 2 20 1,2-Dibromoethane (EDB)0.00700 U 0.223 0.254 88 0.222 0.249 89 65-135 <1 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:06 AM 16-0000374637 rev 00Superset Reference: Page 89 of 131 QA/QC Report mg/L J1603103-011 Basis:Lab Code: Units:Sample Name:MW-29 Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 04/30/16 04/28/16 Date Collected:04/27/16 Organic AcidsAnalysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike RQ1604817-04 RQ1604817-05 Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental Acetic Acid 0.50 U 22.9 20.6 111 25.0 20.6 121 30-147 9 30 Butanoic Acid (Butyric Acid)1.0 U 22.1 19.9 111 21.9 19.9 110 55-146 1 30 Lactic Acid 0.50 U 22.1 20.0 111 22.4 20.0 112 40-158 1 30 Propionic Acid 0.50 U 21.6 20.0 108 21.9 20.0 109 57-135 1 30 Pyruvic Acid 0.020 U 2.28 2.01 113 2.27 2.01 113 45-144 <1 30 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:10 AM 16-0000374637 rev 00Superset Reference: Page 90 of 131 Duplicate Lab Control Sample RQ1604817-03 Lab Control Sample RQ1604817-02 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Duplicate Lab Control Sample Summary Organic Acids in Aqueous Matrices by High Performance Liquid Chromatography (HPLC) 28 Day Hold Time Analysis Method:Organic Acids NA mg/L Basis: Units: Analysis Lot:494408 04/29/16 Spike AmountResult % Rec % RecResult Spike Amount % Rec Limits RPD RPD Limit dba ALS Environmental ALS Group USA, Corp. QA/QC Report 21.9 20.6Acetic Acid 304 70-130110 20.622.6 106 21.3 19.9Butanoic Acid (Butyric Acid)307 70-130115 19.922.9 107 21.3 20.0Lactic Acid 303 70-130109 20.021.8 106 20.9 20.0Propionic Acid 304 70-130109 20.021.8 104 2.06 2.01Pyruvic Acid 305 70-130107 2.012.16 102 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:10 AM Page 91 of 131 QA/QC Report ug/L J1603103-009 Basis:Lab Code: Units:Sample Name:MW-16 Inorganic Parameters Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 05/4/16 04/28/16 Date Collected:04/27/16 EPA 3005A 6010C Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike J1603103-009MS J1603103-009DMS Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 05/3/16Date Extracted: Barium, Total 330 840 500 103 840 500 103 75-125 <1 20 Silver, Total 1 J 518 500 103 520 500 104 75-125 <1 20 Vanadium, Total 1.0 U 997 1000 100 1000 1000 100 75-125 <1 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:13 AM 16-0000374637 rev 00Superset Reference: Page 92 of 131 QA/QC Report ug/L J1603103-002 Basis:Lab Code: Units:Sample Name:MW-9 Inorganic Parameters Duplicate Matrix Spike Summary NA Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 05/2/16 04/28/16 Date Collected:04/27/16 EPA 3005A 6020A Prep Method: Analysis Method: Analyte Name RPD LimitRPDResult Sample Result Spike Amount % Rec Matrix Spike J1603103-002MS J1603103-002DMS Duplicate Matrix Spike % Rec Spike AmountResult % Rec Limits ALS Group USA, Corp. dba ALS Environmental 04/29/16Date Extracted: Antimony, Total 0.2 U 51.8 50.0 104 53.9 50.0 108 75-125 4 20 Arsenic, Total 6 J 56 50 102 59 50 106 75-125 4 20 Beryllium, Total 0.1 J 25.1 25.0 100 26.9 25.0 107 75-125 7 20 Cadmium, Total 0.10 U 20.0 20.0 100 21.0 20.0 105 75-125 5 20 Chromium, Total 0.4 BJ 54 50 107 56 50 110 75-125 4 20 Cobalt, Total 13 55 50 85 59 50 92 75-125 7 20 Copper, Total 11 59 50 97 62 50 102 75-125 4 20 Lead, Total 6 J 31 25 102 32 25 106 75-125 3 20 Nickel, Total 24 J 112 100 87 118 100 94 75-125 6 20 Selenium, Total 2 U 105 100 104 108 100 108 75-125 3 20 Thallium, Total 0.05 U 10.3 10.0 103 10.5 10.0 105 75-125 2 20 Zinc, Total 4 J 223 250 88 236 250 93 75-125 6 20 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:14 AM 16-0000374637 rev 00Superset Reference: Page 93 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603103-LCS 05/02/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Antimony, Total 80-120106 50.053.1 6020A Arsenic, Total 80-120104 5051.8 6020A Beryllium, Total 80-120106 25.026.6 6020A Cadmium, Total 80-120102 20.020.3 6020A Chromium, Total 80-120108 5053.9 6020A Cobalt, Total 80-120100 5050.0 6020A Copper, Total 80-120103 5051.5 6020A Lead, Total 80-120105 2526.3 6020A Nickel, Total 80-12099 10099.0 6020A Selenium, Total 80-120105 100105 6020A Thallium, Total 80-120105 10.010.5 6020A Zinc, Total 80-120100 250249 6020A 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:14 AM Page 94 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603103-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Barium, Total 80-120103 500516 6010C Silver, Total 80-120104 500520 6010C Vanadium, Total 80-120102 10001030 6010C 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:14 AM Page 95 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Sodium, Total 80-120101 25.025.3 6010C 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:14 AM Page 96 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary Inorganic Parameters NA ug/L Basis: Units: Lab Control Sample J1603103-LCS 05/10/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Mercury, Total 80-12099 1.251.24 7470A 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:14 AM Page 97 of 131 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 04/27/16Date Collected: Date Received:04/28/16 04/29/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-12 mg/L Basis: Units: J1603103-005 NALab Code: Sample Name: RPD LimitPQLMDL Analysis Method RPD Duplicate Sample J1603103- 005DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Chloride <1 2.0 0.2 238 239 239 20300.0 Nitrate as Nitrogen NC 0.40 0.08 0.08 U 0.08 U NC 20300.0 Sulfate 2 2.0 0.2 21.0 21.4 21.2 20300.0 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 98 of 131 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 04/27/16Date Collected: Date Received:04/28/16 05/05/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-13 mg/L Basis: Units: J1603103-006 NALab Code: Sample Name: RPD LimitPQLMDL Analysis Method RPD Duplicate Sample J1603103- 006DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Alkalinity as CaCO3, Total <1 5.0 5.0 200 201 200 20SM 2320 B Bicarbonate Alkalinity as CaCO3 <1 5.0 5.0 200 201 200 20SM 2320 B Carbonate Alkalinity as CaCO3 NC 5.0 5.0 5.0 U 5.0 U NC 20SM 2320 B Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 99 of 131 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 04/27/16Date Collected: Date Received:04/28/16 05/02/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-29 mg/L Basis: Units: J1603103-011 NALab Code: Sample Name: RPD LimitPQLMDL Analysis Method RPD Duplicate Sample J1603103- 011DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Solids, Total Dissolved 3 10 10 176 181 179 10SM 2540 C Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 100 of 131 ALS Group USA, Corp. QA/QC Report Client: Project Sample Matrix:Ground Water Feltonsville Landfill Wake County Solid Waste Management Service Request:J1603103 04/27/16Date Collected: Date Received:04/28/16 05/03/16 - 05/05/16Date Analyzed: Replicate Sample Summary General Chemistry Parameters MW-9 mg/L Basis: Units: J1603103-002 NALab Code: Sample Name: RPD LimitPQLMDLAnalysis Method RPD Duplicate Sample J1603103- 002DUP Result Average Sample ResultAnalyte Name dba ALS Environmental Chemical Oxygen Demand, Total 2 20 12 32 32 31.8 5SM21 5220 D Sulfide, Total NC 4.0 0.8 0.8 U 0.8 U NC 20SM 4500-S2- F Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:18 AM 16-0000374637 rev 00Superset Reference: Page 101 of 131 ALS Group USA, Corp. QA/QC Report Analyte Name mg/L J1603103-005 Basis:Lab Code: Units:Sample Name:MW-12 General Chemistry Parameters Matrix Spike Summary Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 4/29/16 04/28/16 Date Collected:04/27/16 NA ResultSample Result Spike Amount % Rec Matrix Spike J1603103-005MS % Rec LimitsMethod dba ALS Environmental Chloride 238 280 50.0 83 #90-110300.0 Nitrate as Nitrogen 0.08 10.3 10.0 103 90-110300.0 Sulfate 21.0 69.5 50.0 97 90-110300.0 Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:17 AM 16-0000374637 rev 00Superset Reference: Page 102 of 131 ALS Group USA, Corp. QA/QC Report Analyte Name mg/L J1603103-002 Basis:Lab Code: Units:Sample Name:MW-9 General Chemistry Parameters Matrix Spike Summary Client: Project: Sample Matrix: Wake County Solid Waste Management Feltonsville Landfill Ground Water Service Request: Date Analyzed: Date Received: J1603103 05/03/16 - 05/05/16 04/28/16 Date Collected:04/27/16 NA ResultSample Result Spike Amount % Rec Matrix Spike J1603103-002MS % Rec LimitsMethod dba ALS Environmental Chemical Oxygen Demand, Total 32 538 500 101 90-110SM21 5220 D Sulfide, Total 0.8 37.6 40.0 94 85-115SM 4500-S2- F Results flagged with an asterisk (*) indicate values outside control criteria. Results flagged with a pound (#) indicate the control criteria is not applicable. Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded. Printed 5/20/2016 8:51:19 AM 16-0000374637 rev 00Superset Reference: Page 103 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/05/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Alkalinity as CaCO3, Total 85-11593 250233 SM 2320 B 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 104 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 04/29/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Biochemical Oxygen Demand (BOD)84.5-115.4111 198219 SM 5210 B 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 105 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/04/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Carbon, Total Organic (TOC)90-11095 50.047.6 SM 5310 B 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 106 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/05/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Chemical Oxygen Demand, Total 95-10599 500494 SM21 5220 D 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 107 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 04/29/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Chloride 90-11094 25.023.5 300.0 Nitrate as Nitrogen 90-110101 5.005.03 300.0 Sulfate 90-11094 25.023.4 300.0 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 108 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/02/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Solids, Total Dissolved 85-115100 300299 SM 2540 C 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 109 of 131 Analyte Name J1603103 Date Analyzed: Service Request: Ground Water Feltonsville Landfill Wake County Solid Waste Management Sample Matrix: Project: Client: Lab Control Sample Summary General Chemistry Parameters NA mg/L Basis: Units: Lab Control Sample J1603103-LCS 05/03/16 Spike AmountResult % Rec % Rec LimitsAnalytical Method dba ALS Environmental ALS Group USA, Corp. QA/QC Report Sulfide, Total 85-11594 20.018.9 SM 4500-S2- F 16-0000374637 rev 00Superset Reference:Printed 5/20/2016 8:51:18 AM Page 110 of 131 Page 111 of 131 Page 112 of 131 Page 113 of 131 Page 114 of 131 Appendix A: Subcontracted Parameters Page 115 of 131 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER LABORATORY REPORT May 12, 2016 Elliott Cornell Wake County Solid Waste Management 9025 Deponie Drive Raleigh, NC 27614 RE: Feltonsville Landfill Dear Elliott: Enclosed are the results of the samples submitted to our laboratory on April 29, 2016. For your reference, these analyses have been assigned our service request number J1603103. All analyses were performed according to our laboratory’s NELAP and DoD-ELAP-approved quality assurance program. The test results meet requirements of the current NELAP and DoD-ELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP and DoD-ELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. Results are intended to be considered in their entirety and apply only to the samples analyzed and reported herein. If you have any questions, please call me at (805) 526-7161. Respectfully submitted, ALS | Environmental Kate Aguilera Project Manager Page 116 of 131 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER Client: Wake County Solid Waste Management Service Request No: J1603103 Project: Feltonsville Landfill _______________________________________________________________________________ CASE NARRATIVE The samples were received intact under chain of custody at the Simi Valley facility on April 29, 2016 and were stored in accordance with the analytical method requirements. Please refer to the sample acceptance check form for additional information. The results reported herein are applicable only to the condition of the samples at the time of sample receipt. Carbon Dioxide Analysis The samples were analyzed for carbon dioxide using a gas chromatograph equipped with a thermal conductivity detector (TCD). A known amount of liquid was displaced by injecting 8.0 milliliters of helium creating a headspace in the sample vial. Each sample vial was agitated using a sonic disrupter for fifteen minutes and then allowed to equilibrate for at least four hours. A volume of the headspace was withdrawn using a gas-tight syringe and analyzed using a manual injection technique. The amount of dissolved gases (carbon dioxide) in the original sample was calculated using Henry’s Law. This method was performed with guidance from RSK 175 as described in laboratory SOP VOA-DISGAS. This analyte is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP accreditation. Methane, Ethene and Ethane Analysis The samples were analyzed for methane, ethene, and ethane using a gas chromatograph equipped with a flame ionization detector (FID). A known amount of liquid was displaced by injecting 8.0 milliliters of helium creating a headspace in the sample vial. Each sample vial was agitated using a sonic disrupter for fifteen minutes and then allowed to equilibrate for at least two hours. A volume of the headspace was withdrawn using a gas-tight syringe and analyzed using a manual injection technique. The amount of dissolved gases (methane, ethene and ethane) in the original sample was calculated using Henry’s Law. This method was performed with guidance from RSK 175. This method is included on the laboratory’s NELAP and DoD-ELAP scope of accreditation, however it is not part of the AIHA-LAP accreditation. Any analytes flagged with an X are not included on the laboratory’s NELAP or DoD-ELAP accreditation. ______________________________________________________________________________________ The results of analyses are given in the attached laboratory report. All results are intended to be considered in their entirety, and ALS Environmental (ALS) is not responsible for utilization of less than the complete report. Use of ALS Environmental (ALS)’s Name. Client shall not use ALS’s name or trademark in any marketing or reporting materials, press releases or in any other manner (“Materials”) whatsoever and shall not attribute to ALS any test result, tolerance or specification derived from ALS’s data (“Attribution”) without ALS’s prior written consent, which may be withheld by ALS for any reason in its sole discretion. To request ALS’s consent, Client shall provide copies of the proposed Materials or Attribution and describe in writing Client’s proposed use of such Materials or Attribution. If ALS has not provided written approval of the Materials or Attribution within ten (10) days of receipt from Client, Client’s request to use ALS’s name or trademark in any Materials or Attribution shall be deemed denied. ALS may, in its discretion, reasonably charge Client for its time in reviewing Materials or Attribution requests. Client acknowledges and agrees that the unauthorized use of ALS’s name or trademark may cause ALS to incur irreparable harm for which the recovery of money damages will be inadequate. Accordingly, Client acknowledges and agrees that a violation shall justify preliminary injunctive relief. For questions contact the laboratory. Page 117 of 131 2655 Park Center Dr., Suite A Simi Valley, CA 93065 T: +1 805 526 7161 F: +1 805 526 7270 www.alsglobal.com RIGHT SOLUTIONS | RIGHT PARTNER ALS Environmental – Simi Valley CERTIFICATIONS, ACCREDITATIONS, AND REGISTRATIONS Agency Web Site Number AIHA http://www.aihaaccreditedlabs.org 101661 Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0694 DoD ELAP http://www.pjlabs.com/search-accredited-labs L15-398 Florida DOH (NELAP) http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E871020 Maine DHHS http://www.maine.gov/dhhs/mecdc/environmental-health/water/dwp- services/labcert/labcert.htm 2014025 Minnesota DOH (NELAP) http://www.health.state.mn.us/accreditation 977273 New Jersey DEP (NELAP) http://www.nj.gov/dep/oqa/ CA009 New York DOH (NELAP) http://www.wadsworth.org/labcert/elap/elap.html 11221 Oregon PHD (NELAP) http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaborat oryAccreditation/Pages/index.aspx 4068-003 Pennsylvania DEP http://www.depweb.state.pa.us/labs 68-03307 (Registration) Texas CEQ (NELAP) http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704413- 15-6 Utah DOH (NELAP) http://www.health.utah.gov/lab/labimp/certification/index.html CA01627201 5-5 Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C946 Analyses were performed according to our laboratory’s NELAP and DoD-ELAP approved quality assurance program. A complete listing of specific NELAP and DoD-ELAP certified analytes can be found in the certifications section at www.alsglobal.com, or at the accreditation body’s website. Each of the certifications listed above have an explicit Scope of Accreditation that applies to specific matrices/methods/analytes; therefore, please contact the laboratory for information corresponding to a particular certification. Page 118 of 131 P a g e 1 1 9 o f 1 3 1 5/12/16 7:33 AMJ1603103_Wake County Solid Waste Management_Feltonsville Landfill.xls - Page 1 of 2 ALS Environmental Sample Acceptance Check Form Client:Wake County Solid Waste Management Work order:J1603103 Project:Feltonsville Landfill Sample(s) received on:4/29/16 Date opened:4/29/16 by:ADAVID Note: This form is used for all samples received by ALS. The use of this form for custody seals is strictly meant to indicate presence/absence and not as an indication of compliance or nonconformity. Thermal preservation and pH will only be evaluated either at the request of the client and/or as required by the method/SOP.Yes No N/A 1 Were sample containers properly marked with client sample ID? 2 Did sample containers arrive in good condition? 3 Were chain-of-custody papers used and filled out? 4 Did sample container labels and/or tags agree with custody papers? 5 Was sample volume received adequate for analysis? 6 Are samples within specified holding times? 7 Was proper temperature (thermal preservation) of cooler at receipt adhered to? Cooler Temperature: 0° C Blank Temperature: ° C  8 Were custody seals on outside of cooler/Box/Container? Location of seal(s)?Sealing Lid? Were signature and date included? Were seals intact? 9  Is there a client indication that the submitted samples are pH preserved? Were VOA vials checked for presence/absence of air bubbles?  10 Tubes: Are the tubes capped and intact? 11 Badges: Are the badges properly capped and intact? Are dual bed badges separated and individually capped and intact? Lab Sample ID Container Required Received Adjusted VOA Headspace Description pH *pH pH (Presence/Absence)Comments 40mL VOA NP 7 A 40mL VOA NP A 40mL VOA NP A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40mL VOA NP 7 A 40mL VOA NP A 40mL VOA NP A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40ml VOA NP 7 A 40mL VOA NP A 40mL VOA NP A The samples were received at ALS-JAX on 4/28/16 RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4) J1603103-002.11 J1603103-002.12 J1603103-003.01 J1603103-003.02 J1603103-003.03 MC 5/3/2016 Do containers have appropriate preservation, according to method/SOP or Client specified information? Does the client/method/SOP require that the analyst check the sample pH and if necessary alter it? Receipt / Preservation MC 5/2/2016 J1603103-002.01 J1603103-002.02 J1603103-002.03 J1603103-002.10 J1603103-003.10 MC 5/02/2016 MC 5/3/2016 J1603103-003.11 J1603103-003.12 J1603103-005.01 Explain any discrepancies: (include lab sample ID numbers): J1603103-005.02 J1603103-005.03 Wet Ice MC 5/3/2016 Page 120 of 131 5/12/16 7:33 AMJ1603103_Wake County Solid Waste Management_Feltonsville Landfill.xls - Page 2 of 2 ALS Environmental Sample Acceptance Check Form Client:Wake County Solid Waste Management Work order:J1603103 Project:Feltonsville Landfill Sample(s) received on:4/29/16 Date opened:4/29/16 by:ADAVID Lab Sample ID Container Required Received Adjusted VOA Headspace Receipt / Preservation Description pH *pH pH (Presence/Absence)Comments 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40mL VOA NP 7 A 40mL VOA NP A 40mL VOA NP A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40mL VOA NP 7 A 40mL VOA NP A 40mL VOA NP A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A 40mL VOA NP 7 A 40mL VOA NP A 40mL VOA NP A 40ml VOA HCL 1 A 40ml VOA HCL A 40ml VOA HCL A RSK - MEEPP, HCL (pH<2); RSK - CO2, (pH 5-8); Sulfur (pH>4) MC 5/2/2016 MC 5/2/2016 MC 5/2/2016 MC 5/3/2016 MC 5/3/2016 MC 5/3/2016 MC 5/2/2016 J1603103-006.02 J1603103-005.16 J1603103-005.17 J1603103-005.18 J1603103-011.01 J1603103-011.02 J1603103-007.01 J1603103-007.02 J1603103-007.03 J1603103-007.16 J1603103-006.01 J1603103-007.17 J1603103-007.18 J1603103-006.03 J1603103-006.16 J1603103-006.17 J1603103-006.18 J1603103-011.03 J1603103-011.10 J1603103-011.11 J1603103-011.12 Explain any discrepancies: (include lab sample ID numbers): Page 121 of 131 TCD_ALL.xls - Page No.:J1603103_RSK175-TCD_1605050917_SC.xls - RSK - TCD ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Project ID:Feltonsville Landfill ALS Project ID:J1603103 Carbon Dioxide Test Code:RSK 175 Instrument ID:HP5890A/GC10/TCD Date(s) Collected:4/27/16 Analyst:Mike Conejo Date Received:4/28/16 Matrix:Water Date Analyzed:5/3/16 Test Notes: Injection Client Sample ID ALS Sample ID Volume Result MRL MDL Data ml(s)µg/L µg/L µg/L Qualifier MW-9 J1603103-002 0.10 72,000 1,000 370 MW-10 J1603103-003 0.10 240,000 1,000 370 MW-12 J1603103-005 0.10 96,000 1,000 370 MW-13 J1603103-006 0.10 240,000 1,000 370 MW-14 J1603103-007 0.10 49,000 1,000 370 MW-29 J1603103-011 0.10 65,000 1,000 370 Method Control Sample P160503-MB 0.10 ND 1,000 370 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 122 of 131 TCD_ALL.xls - Page No.:J1603103_RSK175-TCD_1605050917_SC.xls - DLCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE / DUPLICATE LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Duplicate Lab Control Sample ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:P160503-DLCS Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/TCD Date Received:NA Analyst:Mike Conejo Date Analyzed:5/03/16 Matrix:Water Volume(s) Analyzed:NA ml(s) Test Notes: Spike Amount Result1 ALS CAS #Compound LCS / DLCS LCS DLCS % Recovery Acceptance RPD RPD Data ug/L ug/L ug/L LCS DLCS Limits Limit Qualifier 124-38-9 Carbon Dioxide 22,900 16,500 17,700 72 77 62-139 7 24 1 = The concentration shown includes a subtraction of the Method Control Sample value, even if the result is less than the MRL. Page 123 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (2) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-9 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-002 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 6,000 1.3 0.30 74-85-1 Ethene 0.18 1.0 0.069 J 74-84-0 Ethane 1.1 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. J = The result is an estimated concentration that is less than the MRL but greater than or equal to the MDL. Page 124 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (3) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-10 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-003 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 710 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 125 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (5) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-12 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-005 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 7.3 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 126 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (6) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-13 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-006 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 68 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 127 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (7) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-14 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-007 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 130 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 128 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - Sample (11) ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:MW-29 ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:J1603103-011 Test Code:RSK 175 Date Collected:4/27/16 Instrument ID:HP5890A/GC10/FID Date Received:4/28/16 Analyst:Mike Conejo Date Analyzed:5/2/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane 58 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 129 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - MBlank ALS ENVIRONMENTAL RESULTS OF ANALYSIS Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Method Control Sample ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:P160502-MB Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/FID Date Received:NA Analyst:Mike Conejo Date Analyzed:5/02/16 Sample Type:Water Volume(s) Analyzed:0.10 ml(s) Test Notes: CAS #Compound Result MRL MDL Data µg/L µg/L µg/L Qualifier 74-82-8 Methane ND 1.3 0.30 74-85-1 Ethene ND 1.0 0.069 74-84-0 Ethane ND 0.60 0.061 The Method Control Sample is laboratory water carried through the entire analytical process. ND = Compound was analyzed for, but not detected above the laboratory detection limit. MRL = Method Reporting Limit - The minimum quantity of a target analyte that can be confidently determined by the referenced method. Page 130 of 131 FID_ALL.xls - Page No.:J1603103_RSK175-FID_1605031353_SC.xls - DLCS ALS ENVIRONMENTAL LABORATORY CONTROL SAMPLE / DUPLICATE LABORATORY CONTROL SAMPLE SUMMARY Page 1 of 1 Client:Wake County Solid Waste Management Client Sample ID:Duplicate Lab Control Sample ALS Project ID:J1603103 Client Project ID:Feltonsville Landfill ALS Sample ID:P160502-LCS P160502-DLCS Test Code:RSK 175 Date Collected:NA Instrument ID:HP5890A/GC10/FID Date Received:NA Analyst:Mike Conejo Date Analyzed:5/02/16 Sample Type:Water Volume(s) Analyzed:NA ml(s) Test Notes: Spike Amount Result1 ALS CAS #Compound LCS / DLCS LCS DLCS % Recovery Acceptance RPD RPD Data µg/L µg/L µg/L LCS DLCS Limits Limit Qualifier 74-82-8 Methane 2.53 2.62 2.54 104 100 83-106 4 12 74-85-1 Ethene 4.40 5.49 5.26 125 120 86-143 4 13 74-84-0 Ethane 4.75 5.30 5.05 112 106 85-122 6 14 1 = The concentration shown includes a subtraction of the Method Control Sample value, even if the result is less than the MRL. Page 131 of 131 May 12, 2016 Service Request No:J1603109 Daniel Forbes CDM Smith, Inc. 5400 Gleenwood Ave, Suite 400 Raleigh, NC 27612 All analyses were performed according to our laboratory’s quality assurance program. The test results meet requirements of the NELAP standards except as noted in the case narrative report. All results are intended to be considered in their entirety, and ALS Environmental is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report. In accordance to the NELAC 2003 Standard, a statement on the estimated uncertainty of measurement of any quantitative analysis will be supplied upon request. For your reference, these analyses have been assigned our service request number Enclosed are the results of the sample(s) submitted to our laboratory Laboratory Results for:Feltonsville Landfill Dear Daniel, April 28, 2016 J1603109. Please contact me if you have any questions. My extension is 4410. You may also contact me via email at Jerry.Allen@alsglobal.com. Respectfully submitted, ALS Group USA, Corp. dba ALS Environmental Jerry Allen Project Manager dba ALS Environmental ALS Group USA, Corp. ADDRESS FAXPHONE 9143 Philips Highway, Suite 200, Jacksonville, FL 32256 +1 904 739 2011+1 904 739 2277 | Page 1 of 20 MW-8J1603109-001 4/26/2016 1445 MW-9J1603109-002 4/27/2016 1310 MW-10J1603109-003 4/27/2016 1350 MW-12J1603109-004 4/27/2016 1145 MW-13J1603109-005 4/27/2016 1035 MW-14J1603109-006 4/27/2016 0955 MW-19J1603109-007 4/26/2016 1605 MW-29J1603109-008 4/27/2016 1240 Client:Wake County Solid Waste Management Service Request:J1603109 Project:Feltonsville Landfill SAMPLE CROSS-REFERENCE SAMPLE #CLIENT SAMPLE ID DATE TIME Printed 5/12/2016 8:39:22 AM Sample Summary Page 2 of 20 Page 3 of 20 Page 4 of 20 Page 5 of 20 Page 6 of 20 Page 7 of 20 Page 8 of 20 Page 9 of 20 Page 10 of 20 Page 11 of 20 Page 12 of 20 Page 13 of 20 Page 14 of 20 Page 15 of 20 Page 16 of 20 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20 cdmsmith.com