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HomeMy WebLinkAbout5002_JacksonCounty_MSWLF_Oct20GW_FID1525972_20210119Data - Email CD (data loaded: Yes / No ) Doc/Event #: INC DENR I i Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form_ Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for Inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each Individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM. Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QEA of North Carolina, PLLC Contact for questions about data formatting. Include data preparees name, telephone number and E-mail address: Name: Alec Macbeth Phone: 828-281-3350 E-mail: amacbeth@anchorgea.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Jackson County Municipal Solid US Highway 441 5"2 .1600 October 12, 13, and 14, 2020 Waste Landfill Dillsboro, North Carolina 28725 Environmental Status: (Check all that apply) Initial/Background Monitoring F1 Detection Monitoring © Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) Natural Attenuation Parameters Other(specify) Notification attached? ® No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment Alec Macbeth, PG Senior Scientist 828-281,3350 Facility Representative Na e(Print) Title (Area Code) Telephone January 16, 2021 Affix NC L Signature Date 231 Haywood Street, Asheville, North Carolina 28801 Facility Representative Address P-1649 i q .?so .• R FP �yti., Seal NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 ti9 r •may January 2021 ANCHOR Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 QEA `'`'" Fall 2020 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department January 2021 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Fall 2020 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department 401 Grindstaff Cove Road Sylva, North Carolina 28779 Alec Macbeth, PG Project Geologist Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Number: C01480-01.02 \\ashevil I el \ash eville\Projects\Ja ckson County\Reports - Groundwater\2020\02 -Fall\Text\Semiannual Water Quality Report_Fall 2020_clean.docx TABLE OF CONTENTS 1 Introduction............................................................................................................................1 2 Semiannual Monitoring.......................................................................................................2 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling............................................2 2.1.1 Monitoring Well Purging and Sampling Methods.....................................................................2 2.1.2 Surface Water Sampling Methods......................................................................................................3 2.1.3 Leachate Sampling Methods.................................................................................................................4 2.1.4 Domestic Well Sampling Methods.....................................................................................................4 2.2 Sample Handling, Documentation, and Analysis.........................................................................................4 3 Findings.................................................................................................................................. 7 3.1 Groundwater...................................................................................................................................................................7 3.1.1 Field Parameters...........................................................................................................................................8 3.1.2 Appendix II Metals (Total).......................................................................................................................8 3.1.3 Appendix II Metals (Dissolved).............................................................................................................9 3.1.4 Appendix II VOCs and 1,4-Dioxane....................................................................................................9 3.1.5 Appendix II SVOCs...................................................................................................................................10 3.1.6 Appendix II Pesticides.............................................................................................................................10 3.1.7 Appendix II Herbicides...........................................................................................................................10 3.1.8 Appendix II PCBs.......................................................................................................................................10 3.1.9 Natural Attenuation Parameters.......................................................................................................10 3.2 Surface Water..............................................................................................................................................................11 3.2.1 Field Parameters........................................................................................................................................11 3.2.2 Appendix II Metals...................................................................................................................................11 3.2.3 Appendix II VOCs and 1,4-Dioxane.................................................................................................12 3.2.4 Appendix II SVOCs, Pesticides, Herbicides, and PCBs............................................................12 3.3 Leachate.........................................................................................................................................................................12 3.4 Domestic Well.............................................................................................................................................................12 3.4.1 Field Parameters........................................................................................................................................13 3.4.2 VOCs................................................................................................................................................................13 3.5 Groundwater Flow Directions..............................................................................................................................13 4 Summary...............................................................................................................................14 4.1 Groundwater Quality...............................................................................................................................................14 4.1.1 Appendix II Metals...................................................................................................................................14 Fall 2020 Semiannual Water Quality Monitoring Report i January 2021 4.1.2 Appendix II Volatile Organic Compounds and 1,4-Dioxane...............................................14 4.1.3 Field Parameters and Other Constituents....................................................................................14 4.2 Surface Water Quality.............................................................................................................................................15 4.3 Leachate Quality.........................................................................................................................................................15 4.4 Domestic Well Water Quality..............................................................................................................................15 5 Future Activities...................................................................................................................16 6 References.............................................................................................................................17 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Well Construction Details and Corresponding Elevations Table 3 Analytical Summary Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01) FIGURES Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Generalized Groundwater Flow Direction Figure 4 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-01) Figure 5 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-01) Figure 6 Hydrograph and Vinyl Chloride Concentration vs. Time (Monitoring Well MW-01) Figure 7 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-04) Figure 8 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-05R) Figure 9 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-07) Figure 10 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-07) Figure 11 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-07) APPENDICES Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Fall 2020 Semiannual Water Quality Monitoring Report ii January 2021 ABBREVIATIONS pg/L micrograms per liter PS/cm microsiemens per centimeter AM Analytical Method bgs below ground surface BOD biochemical oxygen demand CAER Corrective Action Evaluation Report CAP Corrective Action Plan CFR Code of Federal Regulations COD chemical oxygen demand DENR North Carolina Department of Environment and Natural Resources DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration MDL method detection limit mg/L milligrams per liter MNA monitored natural attenuation MSWLF Municipal Solid Waste Landfill mV millivolts NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation reduction potential PCBs polychlorinated biphenyls PWR partially weathered rock SC specific conductivity Site Closed Municipal Solid Waste Landfill, approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74) SM Standard Method SU standard unit SVOCs semivolatile organic compounds SWS Solid Waste Section TOC total organic carbon TWSA Tuckasegee Water & Sewer Authority VOC volatile organic compound Waypoint Waypoint Analytical Laboratories Fall 2020 Semiannual Water Quality Monitoring Report iii January 2021 Introduction The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (the Site) approximately 0.75 mile west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM), Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County. The landfill permit requires semiannual monitoring of groundwater and surface water quality. Since October 2007, when Anchor QEA of North Carolina, PLLC, began performing water quality monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level concentrations of constituents that exceed groundwater quality standards. In response to the continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was submitted to the North Carolina Department of Environment and Natural Resources (DENR; now the DEQ) on September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was implemented upon approval by the DENR, as recorded in the September 1, 2011 letter regarding "Approval of the County's Corrective Action Plan" (DENR 2011). The implemented remedy includes the extraction of leachate through dedicated submersible pumps installed within landfill gas extraction wells and disposal of the leachate into the Tuckasegee Water & Sewer Authority (TWSA) collection system. In addition to the leachate extraction, groundwater natural attenuation parameters are monitored, and natural attenuation processes are evaluated. As discussed in the CAP, a corrective action evaluation report is prepared every 5 years. The evaluation report analyzes the progress of the approved corrective action remedy based on semiannual water quality monitoring data. The remedy was implemented in a phased approach, with full implementation occurring on September 6, 2013. The first Five -Year Corrective Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016 (Altamont 2016), concluded that the current conditions of the monitored natural attenuation (MNA) parameters and Site geochemical parameters allow for the slow degradation of the select contaminants identified in the CAER. The second CAER is scheduled to be submitted in fall 2021. This report serves as the second semiannual water quality monitoring report for 2020. The report provides an evaluation of groundwater and surface water quality. The water quality monitoring network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water monitoring, this report includes analysis of the extracted leachate and one domestic water well. The water samples collected from selected monitoring points during the fall sampling event were analyzed for a range of parameters, as presented in Section 2.2 and Table 1. The fall 2020 sampling event was performed on October 12, 13, and 14, 2020, and is being reported in accordance with requirements stipulated in the DEQ Solid Waste Management Rules codified under Title 15A, Subchapter 13B of the North Carolina Administrative Code (NCAC). Fall 2020 Semiannual Water Quality Monitoring Report 1 January 2021 2 Semiannual Monitoring 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface water sample locations (SW-01 and SW-02), leachate sample location (LT-01), and domestic well (DW-01) were sampled on October 12, 13, and 14, 2020, by Anchor QEA. Static groundwater level measurements and field parameter data are included on the sampling logs presented in Appendix A. Field equipment calibration logs for the YSI Professional Plus Multiparameter Water Quality Meter and the Hach 2100Q Turbidimeter are also provided in Appendix A. The full suite of groundwater and surface water laboratory analytical results is presented in the laboratory analysis reports in Appendix B. Monitoring wells MW-01 and MW-06 are considered to be the Site's upgradient monitoring wells; MW-03 and MW-05R are located in the midgradient portion of the Site; and MW-02, MW-04, and MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the monitoring wells range from 40 to 110 feet below ground surface (bgs). The geology of the screened intervals of the monitoring wells is as follows: • Saprolite': MW-04 and MW-05R • Partially Weathered Rock (PWR)Z: MW-03 • Bedrock3: MW-01, MW-02, MW-06, and MW-07 The locations of the monitoring wells, surface water samples, leachate, and domestic well sample locations are shown in Figure 2. 2.7.7 Monitoring Well Purging and Sampling Methods Before the monitoring wells were sampled, the static water level was gauged in each well, and an initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]). Due to a field equipment malfunction, field pH measurements collected on October 13, 2020, were not considered representative of groundwater quality and samples were submitted to the laboratory for pH analysis. Therefore, the pH values discussed in the text of this report for monitoring wells MW-01, MW-03, and MW-06 are based on laboratory results. Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock. z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite. 3 Bedrock is solid competent rock that underlies saprolite and partially weathered rock. Fall 2020 Semiannual Water Quality Monitoring Report 2 January 2021 Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the monitoring wells and collect groundwater samples. The total depth, condition of the casing, and groundwater recharge rate determined the purging and sample collection method employed at each monitoring well. Four of the monitoring wells (MW-03, MW-04, MW-06, and MW-07) were purged using low -flow techniques in accordance with the procedures described by the U.S. Environmental Protection Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996). During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had generally stabilized for three consecutive readings. The required stabilization criteria are determined by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater Sampling (EPA 2017) and are summarized as follows: • pH values within ±0.1 standard unit (SU) • SC values within ±5% • Temperature, DO, and turbidity values within ±10% • ORP values within ±10 millivolts (mV) Once the parameters had stabilized, a groundwater sample was collected by field personnel wearing a new pair of nitrile gloves, using laboratory -supplied sample containers. Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged and sampled using disposable bailers. The wells were purged of three successive well volumes or purged dry, whichever occurred first. Monitoring well MW-02 was purged dry on October 12 and sampled on October 13, 2020, after the well had sufficient time to recharge. Monitoring well MW- 05R was purged dry in the morning on October 12 and sampled later that day after the well had sufficient time to recharge. Monitoring well MW-01 was purged and sampled on October 14, 2020. A round of field parameters was measured and recorded at the start of purging and after each consecutive well volume had been purged. Field parameter data are shown in the well sampling logs included in Appendix A. 2.7.2 Surface Water Sampling Methods Surface water samples SW-01 and SW-02 were collected on October 14, 2020, at designated locations from the Tuckasegee River, which is adjacent to and southwest of the landfill (Figure 2). Sampling location SW-01 is assumed to represent surface water quality upstream of the landfill, and sampling location SW-02 is assumed to represent surface water quality downstream of the landfill. One round of field parameters was measured and recorded at each surface water sampling location Fall 2020 Semiannual Water Quality Monitoring Report 3 January 2021 immediately prior to collecting the sample (Appendix A). The surface water samples were collected in laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves. 2. 7.3 Leachate Sampling Methods Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells EW-1 R, EW-2R, EW-3R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization tank, which is connected to the TWSA wastewater collection system. The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab sample of leachate (LT-01) was acquired on October 14, 2020, by collecting a sample as the leachate entered the flow equalization tank. One round of field parameters was measured and recorded after the sample was collected (Appendix A). 2.1.4 Domestic Well Sampling Methods The domestic well water sample (DW-01, owned by Mr. Frank Wilkie) was collected on October 14, 2020, from an outside spigot at the residence located at 318 Joe Wilkey Road, bordering the northern boundary of the landfill (Figure 2). The well was purged of 30 gallons prior to sample collection. One round of field parameters was measured and recorded after the 30 gallons had been purged. The domestic well water sample was collected in laboratory -provided sample containers by field personnel wearing a new pair of nitrile gloves. Attempts to sample the second domestic water well (DW-2, owned by Mr. Joshua Bulla at 138 Joe Wilkey Road) were unsuccessful because the owner could not be contacted. 2.2 Sample Handling, Documentation, and Analysis It should be noted that during most semiannual sampling events at the Jackson County Landfill, water quality samples are submitted for Appendix I parameters only. A larger suite of Appendix II parameters as noted below are analyzed for during the fall sampling event only on a biannual basis. Field parameters and additional observations pertaining to the Site sampling locations are provided in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water, leachate, and domestic well water sample was immediately placed on ice in a sample cooler for transport to Waypoint Analytical Laboratories (Waypoint), a North Carolina -certified laboratory in Charlotte, North Carolina. The groundwater samples collected from the monitoring wells were analyzed for the following parameters (Table 1): • Appendix II metals, including mercury, using EPA Methods 6020B and 7470A • Appendix II volatile organic compounds (VOCs), using EPA Method 8260D Fall 2020 Semiannual Water Quality Monitoring Report 4 January 2021 • 1,4-Dioxane, using EPA Method 8260DSIM • Appendix II semivolatile organic compounds (SVOCs), using EPA Method 8270D • Appendix II herbicides, using EPA Method 8151A • Appendix II pesticides, using EPA Methods 8081 B and 8141 B • Appendix II polychlorinated biphenyls (PCBs), using EPA method 8082A • MNA parameters: — Alkalinity, using Standard Method (SM) 2320B — Biochemical oxygen demand (BOD; 5-day), using SM 5210B — Volatile fatty acids, carbon dioxide, ethane, ethene, and methane, using Analytical Method (AM) 20GAX — Hydrogen (only in MW-03, MW-04, MW-06, and MW-07), using AM20GAX — Chemical oxygen demand (COD), using SM 5220D — Chloride, nitrate, and sulfate, using EPA Method 9056A — Ferrous iron, using SM 3500-Fe D — Sulfide, using SM 4500-5 F — Cyanide, using SM 4500-CN-E — Total organic carbon (TOC), using SM 9060A — Nitrate as N, chloride, and sulfate, using EPA Methods 9056A The surface water samples were analyzed for the following parameters: • Appendix II metals, including mercury, using EPA Methods 6020B and 7470A • Appendix II VOCs, using EPA Method 8260D • 1,4-Dioxane, using EPA Method 8260DSIM • Hardness, using SM2340C • Appendix II SVOCs, using EPA Method 8270D • Appendix II herbicides, using EPA Method 8151A • Appendix II pesticides, using EPA Methods 8081 B and 8141 B • Appendix II PCBs, using EPA method 8082A The leachate sample was analyzed for the following parameters: • Appendix II VOCs, using EPA Method 8260D • 1,4-Dioxane, using EPA Method 8260DSIM • Appendix II metals, using EPA Method 6020B The domestic well sample was analyzed for the following parameters: • VOCs, using EPA Method 524.2 Fall 2020 Semiannual Water Quality Monitoring Report 5 January 2021 Proper chain -of -custody documentation procedures were followed during collection and transportation of each sample (Appendix B). Two trip blank samples for quality control/quality assurance purposes were included in the sample coolers and analyzed for Appendix I VOCs when applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses performed on the samples are summarized in Table 1. Fall 2020 Semiannual Water Quality Monitoring Report 6 January 2021 3 Findings The field parameter data and laboratory analytical results for the groundwater samples (from monitoring wells MW-01 through MW-07), surface water samples (SW-01 and SW-02), leachate sample (LT-01), and domestic well sample (DW-01) collected at the landfill are included in Appendices A and B. The results are also submitted separately to the DEQ DWM SWS in the Electronic Data Deliverable format (DEQ 2020). The laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections are values reported by the laboratory as less than the method detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or " Y' Qualified: A "J" qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit. The method reporting limit is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Groundwater Quality Standard: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 2L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202 [c]). For the purposes of this report, groundwater standards were taken from the October 15, 2018 list published by the North Carolina SWS (DEQ 2018b). 2B Standard: Detections of analytes in surface water samples were compared to the surface -water quality standards 2B standards, defined in 15A NCAC 2B. Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 3 summarizes detected concentrations of analytes that exceeded their respective 2L standard, IMAC, or 2B standard. 3.1 Groundwater Measured field parameters and analytical results for groundwater samples collected from the monitoring wells during the fall 2020 sampling event are discussed in the following sections and summarized in Table 3. Fall 2020 Semiannual Water Quality Monitoring Report 7 January 2021 3.7.7 Field Parameters Field parameter measurements were obtained from all site monitoring wells (MW-01, MW-02, MW- 03, MW-04, MW-05R, MW-06, and MW-07). The pH readings ranged from 5.70 SU in MW-01 to 7.1 SU in MW-06. Of these monitoring wells, the pH values for MW-01, MW-04, and MW-07 were less than the 2L Standard pH range of 6.5 to 8.5 SU. Turbidity ranged from 3.94 nephelometric turbidity units (NTU) in MW-04 to more than 1,000 NTU in MW-02. Generally, the higher values were measured at the monitoring wells (MW-01, MW-02, and MW-05R) that were purged and sampled using the bailer method (Section 2.1.1). The bailers were lowered gently to minimize water column disturbance when the samples were collected. Dissolved oxygen (DO) concentrations at the Site ranged from 1.43 milligram per liter (mg/L) in monitoring well MW-05R to 5.08 mg/L in monitoring well MW-02. SC concentrations at the Site ranged from 52.8 microsiemens per centimeter (pS/cm) in monitoring well MW-06 to 758 pS/cm in monitoring well MW-07.ORP concentrations at the Site ranged from -139.9 mV in monitoring well MW-06 to 302.8 mV in monitoring well MW-04. (As noted on the groundwater sampling logs [Appendix A], the ORP values reported for monitoring wells MW-02 and MW-06 may not be representative of groundwater quality because of equipment malfunction.) Groundwater standards are not established for DO, SC, or ORP. 3.7.2 Appendix 11 Metals (Total) Fourteen metals were detected in one or more of the monitoring well samples. Six of these metals, chromium, cobalt, mercury, selenium, thallium, and vanadium, were detected at concentrations above their respective NC21- and/or IMAC water quality standards in one or more of the groundwater samples. Cobalt was detected at a concentration that exceeded its IMAC (1 microgram per liter [pg/L]) in groundwater samples collected from MW-01, MW-02, MW-04, MW-05R, MW-06, and MW-07. Cobalt concentrations in these samples ranged from an estimated 1 A pg/L (MW-07) to 160 pg/L (MW-01). As noted in Section 2.1, the latter monitoring well is considered to represent upgradient conditions. The second upgradient well (MW-06) also showed an exceedance of cobalt (9 pg/L). Historically, cobalt has been present at concentrations that exceed its applicable water quality standard in groundwater samples from each of the seven monitoring wells. Mercury was detected at a concentration exceeding its 2L standard (1 pg/L) in groundwater samples collected from MW-01 (1.1 pg/L), MW-03 (1.1 pg/L), and MW-06 (1.3 pg/L). Additionally, chromium (61 pg/L), selenium (42 pg/L), thallium (estimated 0.96 pg/L), and vanadium (71 pg/L) were detected at concentrations exceeding their respective NC 2L and/or IMAC standards (10 pg/L, 20 pg/L, 0.2 pg/L, and 0.3 pg/L, respectively) in groundwater sample collected from MW-02. These metals have historically been present at concentrations exceeding their water quality standard Fall 2020 Semiannual Water Quality Monitoring Report 8 January 2021 in samples collected from multiple groundwater monitoring wells at the Site. However, the elevated turbidity value measured in the MW-02 sample may have affected the metal concentrations reported here. During the spring 2020 sampling event, MW-02 showed a turbidity of 15.5 NTU with consistently lower concentrations of these metals. 3.7.3 Appendix 11 Metals (Dissolved) Laboratory -filtered analysis of Appendix II metals were performed for monitoring well samples MW-02 and MW-05R because of their elevated turbidity readings (>1,000 NTU and 53.7 NTU, respectively) during sample collection. The reported concentrations for the dissolved metals were consistently lower than the total unfiltered metals analytical results in MW-02, with no exceedances of the groundwater water protection standards. The dissolved metals results for MW-05 were comparable to the associated total unfiltered metal analysis (Table 3). 3.7.4 Appendix 11 VOCs and 7,4-Dioxane Nineteen VOCs were detected in one or more of the monitoring wells (Table 3). Four of these VOCs (1,4-dichlorobenzene; 1,4-dioxane; benzene; and vinyl chloride) were detected at concentrations that exceeded their respective 2L standards in the groundwater samples collected from one or more monitoring wells. Concentration -versus -time graphs (trend plots) were created for the monitoring wells that have historically exhibited VOC concentrations that exceed the associated 2L standards (Figures 4 through 11). The detected concentration of 1,4-dichlorobenzene exceeded its 2L standard (6 pg/L) in monitoring wells MW-01 (9.8 pg/L) and MW-05R (6.8 pg/L). The historical 1,4-dichlorobenzene concentration trend in MW-01 remains relatively stable (Figure 4). The detected concentrations of 1,4-dioxane equaled or exceeded its 2L standard (3 pg/L) in MW-04 (3.4 pg/L), MW-05R (3.5 pg/L), and MW-07 (17 pg/L). 1,4-Dioxane was not detected in monitoring wells MW-01, MW-03 or MW-06. Trend plots for 1,4-dioxane concentrations in MW-04, MW-05R, and MW-07 show stable concentrations (Figures 7, 8, and 10). Benzene was detected at concentrations that slightly exceed its 2L standard of 1 pg/L in MW-01 (1.5 pg/L) and MW-07 (1.4 pg/L). Overall, historical benzene concentration trends in monitoring wells MW-01 and MW-07 have been stable and slightly exceed the 2L standard (Figures 5 and 11). The concentration of vinyl chloride in the sample collected from one monitoring well, MW-01, (estimated 0.31 pg/L) slightly exceeded the compound's 2L standard (0.03 pg/L). A trend plot for vinyl chloride concentrations in MW-01 shows consistently low concentrations of the constituent (Figure 6). Fall 2020 Semiannual Water Quality Monitoring Report 9 January 2021 A review of historical groundwater data indicates that the VOCs (1,4-dichlorobenzene; 1,4-dioxane, benzene; and vinyl chloride) exhibiting concentrations that exceed the 2L standards during the fall 2020 sampling event have been detected at relatively consistent concentrations for the past several years. As described in Section 3.2.3, historical surface water samples from the Tuckasegee River, which may receive discharge from the saprolite groundwater -bearing zone, have consistently shown no detections of these compounds, or other VOCs. 3. 7.5 Appendix 11 SVOCs Five SVOCs (1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,4-dichlorobenzene, dibenzofuran, and diethyl phthalate) were detected in one or more of the monitoring wells on Site during the fall 2020 water quality monitoring event (Table 3). None of these detections exceeded their respective 2L or IMAC standards. The analytical results of 1,4-dichlorobenzene reported under the VOC analysis are discussed in Section 3.1.3. 3. 7.6 Appendix 11 Pesticides Two pesticides (beta-BHC and gamma-BHC) were detected at concentrations above their respective water quality standards (Table 3) in the groundwater samples collected from two of the monitoring wells during the fall 2020 water quality monitoring event. These exceedances represent the second time these compounds have been detected during a monitoring event. These compounds were last sampled for in fall 2018. Beta-BHC was detected at an estimated concentration above the IMAC (0.02 pg/L) in monitoring well MW-06 (0.14 pg/L). This compound was not detected in other monitoring wells. Gamma-BHC exceeded the 2L standard (0.03 pg/L) in monitoring well MW-01 (0.051 pg/L). This parameter was detected but did not exceed its 2L standard in MW-05R. 3. 7.7 Appendix 11 Herbicides Two pesticides (silvex and 2,4-dichlorophenoxyacetic acid) were detected in one or more of the monitoring wells during the fall 2020 water quality monitoring event (Table 3). Neither of these detections exceeded their respective 2L standards. 3. 7.8 Appendix 11 PCBs No PCBs were detected in any of the groundwater samples collected during the fall 2020 water quality monitoring event. 3.1.9 Natural Attenuation Parameters During this sampling event, the groundwater samples were analyzed for MNA parameters as described in Section 2.2 (Table 1). The results of these analyses are summarized in Table 3. These parameters were detected in one or more groundwater samples collected from the monitoring wells. Many of these parameters do not have established groundwater standards. Of the parameters that Fall 2020 Semiannual Water Quality Monitoring Report 10 January 2021 do have established groundwater standards, chloride, cyanide, and sulfate, there were no exceedances (or detections in the case of cyanide). An in-depth analysis of the MNA parameters that apply to the Site's select contaminants was presented in the first Five -Year CAER (Altamont 2016). The CAER concluded that the MNA data provide evidence that reductive degradation and aerobic degradation are occurring in different portions of the Site. The dataset of the MNA parameters collected from spring 2017 to spring 2021 will be used in the second Five -Year CAER (scheduled for fall 2021) to evaluate the degradation processes at the Site. 3.2 Surface Water The following sections summarize the measured field parameters and analytical results associated with the two surface water samples collected during the fall 2020 sampling event. 3.2. 7 Field Parameters The pH readings for the upstream (SW-01) and downstream (SW-02) surface water samples collected during the fall 2020 sampling event were 6.36 and 6.60 SU, respectively. The pH readings for both surface water samples were within the 2B standard range of 6.0 to 9.0 SU. The turbidity values measured in SW-01 (36.9 NTU) and SW-02 (29.0 NTU) were less than the 2B standard, which is established at less than or equal to 50 NTU for the receiving water in streams not designated as trout waters. DO was measured at a concentration of 10.35 mg/L in SW-01 and 10.67 mg/L in SW-02. The 2B standard is established as greater than or equal to 6 mg/L; thus, each sample is within the acceptable DO range. SC concentrations in surface water samples SW-01 and SW-02 were recorded at 36.7 and 26.7 pS/cm, respectively. ORP values for SW-01 and SW-02 were 127.9 and 153.6 mV, respectively. These concentrations of SC and ORP are consistent with historical data for both surface water samples. 2B standards do not exist for these parameters. 3.2.2 Appendix 11 Metals Six metals were detected in both surface water sampling locations. Of these metals, only one (lead) was detected at a concentration that slightly exceeded its 2B standard of 0.2 pg/L. Lead was detected in upstream location SW-1 at an estimated 0.3 pg/L and downstream location SW-2 at an estimated 0.38 pg/L. Fall 2020 Semiannual Water Quality Monitoring Report 11 January 2021 3.2.3 Appendix 11 VOCs and 7,4-Dioxane One VOC, naphthalene, was detected but did not exceed its 2B standard in the surface water sampling location, SW-01. There were no other VOC detections or exceedances in either of the surface water sampling locations. 3.2.4 Appendix 11 SVOCs, Pesticides, Herbicides, and PCBs No SVOCs, pesticides, herbicides, or PCBs were detected in any of the surface water samples collected during the fall 2020 water quality monitoring event. 3.3 Leachate Eight metals (arsenic [2.9 pg/L], barium [500 pg/L], chromium [2.5 pg/L], cobalt [3.8 pg/L], mercury [0.23 pg/L], nickel [20 pg/L], selenium [estimated 0.79 pg/L], and vanadium [estimated 2.4 pg/L]) were detected in the leachate sample (LT-01). Seventeen VOCs (cis-1,2-dichloroethene [estimated 0.29 pg/L]; 1,3-dichlorobenzene [estimated 0.27 pg/L]; 1,4-dichlorobenzene [4.8 pg/L]; 1,4-dioxane [58 pg/L]; acetone [11 pg/L]; acetonitrile [estimated 4.7 J pg/L]; benzene [2A pg/L]; chlorobenzene [4.4 pg/L]; chloroethane [estimated 0.47 pg/L]; ethylbenzene [1.8 pg/L]; m,p-xylene [1.7 pg/L]; naphthalene [13 pg/L]; o-xylene [2.0 pg/L]; tetrahydrofuran [94 pg/L]; toluene [0.79 pg/L]; and vinyl chloride [estimated 0.22 pg/L]) were detected in the leachate sample (LT-01). On September 1, 2012, leachate extraction was initiated following installation of leachate extraction pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Due to a temporary malfunction with the leachate flow meter between October 2017 and March 2018, there is a gap in the mass removal calculations represented in Table 4. Therefore, the total volume of leachate removed since September 2012 is not known. However, based on readings taken from the leachate totalizer during the October 2020 monitoring events, approximately 98,790 gallons of leachate were discharged through a permanent connection to the TWSA between March 19 and October 14, 2020 (Table 4). In fall 2013, the active portion of the approved corrective action remedy was initiated. Based on the leachate analytical results for the sample collected on October 14, 2020, Anchor QEA estimates that approximately 0.17 pounds of VOCs was removed with the extracted leachate between the March and October 2020 sampling events. Mass removal calculations are included in Table 4. 3.4 Domestic Well The following sections summarize measured field parameters and analytical results associated with the domestic well water sample collected during the fall 2020 sampling event. Fall 2020 Semiannual Water Quality Monitoring Report 12 January 2021 3.4.7 Field Parameters The pH reading for the domestic well sample (DW-01) was 6.46 SU, which isjust outside of the 2L standard range of 6.5 to 8.5 SU. Turbidity measured in DW-01 was 4.3 NTU. DO was measured at a concentration of 7.74 mg/L in DW-01. SC and ORP values in DW-01 were recorded at 70.5 pS/cm and 186.7 mV, respectively. These parameters do not have established water quality standards. 3.4.2 VOCs No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. 3.5 Groundwater Flow Directions Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three of the bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is located southwest of the landfill (Figure 3). The fall 2020 water level data collected from these four bedrock wells were used to determine the generalized bedrock groundwater flow direction, which is to the southwest (Figure 3). PWR monitoring well MW-03 and saprolite monitoring wells MW-04 and MW-05R (Figure 3) are located in the south-central and southern parts of the landfill, respectively. The fall 2020 water level data collected from monitoring wells MW-03, MW-04, and MW-05R (Table 2) indicate that groundwater flow direction in the combined saprolite and PWR zones is generally to the south- southwest, toward the Tuckasegee River (Figure 3). Fall 2020 Semiannual Water Quality Monitoring Report 13 January 2021 4 Summary The second semiannual water quality monitoring event of 2020 for the Site was performed on October 12, 13, and 14, 2020. Appendices A and B and Table 3 provide detailed analytical results and field data summarizing the groundwater, surface water, and leachate quality at the landfill. 4.1 Groundwater Quality 4. 7. 7 Appendix 11 Metals Six metals (chromium, cobalt, mercury, selenium, thallium, and vanadium) were detected at concentrations that exceeded their associated groundwater quality standards in one or more of the monitoring wells (Table 3). Cobalt concentrations exceeded its 2L standard in all of the collected groundwater samples excluding MW-03 but including the upgradient monitoring wells, MW-01 and MW-06. These results are consistent with historical data. The results for the two groundwater samples (MW-02 and MW-05R) submitted for dissolved filtered metals showed significantly lower or comparable metals concentrations than the total unfiltered samples. 4. 7.2 Appendix 11 Volatile Organic Compounds and 1,4-Dioxane Four VOCs (1,4-dichlorobe nzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at concentrations that exceeded their respective 2L standards (Table 3) in one or more monitoring wells, including 1,4-dichlorobenzene, benzene, and vinyl chloride in the upgradient monitoring well MW-01. Trend plots for samples from monitoring wells that had VOC concentrations that exceeded their 2L standards (Figures 4 through 11) show relatively stable concentrations with time. 4. 7.3 Field Parameters and Other Constituents Three of the seven of the samples collected from the monitoring wells had pH readings outside of the 2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are characteristic of the natural groundwater quality of the region. Turbidity readings ranged from 3.94 NTU (MW-04) to more than 1,000 NTU (MW-02). Natural attenuation parameters (alkalinity, BOD, COD, chloride, cyanide, nitrate as N, sulfate, sulfide, TOC, ferrous iron, hydrogen, methane, acetic acid, formic acid, lactic acid, propionic acid, and carbon dioxide) were detected at various concentrations in groundwater samples collected from one or more of the monitoring wells. Natural attenuation parameters are being monitored to fulfill CAP requirements; further evaluation of these parameters will be performed in the second Five -Year CAER (scheduled for fall 2021). Fall 2020 Semiannual Water Quality Monitoring Report 14 January 2021 Five Appendix II SVOCs (1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,4-dichlorobenzene, dibenzofuran, and diethyl phthalate) were detected in one or more of the monitoring wells but exceeded their respective 2L or IMAC standards. Two Appendix II Pesticides (beta-BHC in MW-06 and gamma-BHC in MW-01) were detected at concentrations above their respective water quality standards in the groundwater samples collected from two of the monitoring wells during the fall 2020 water quality monitoring event. This represents the second time these compounds have been detected during a monitoring event. Two Appendix II Pesticides (Silvex and 2,4-dichlorophenoxyacetic acid) were detected in one or more of the monitoring wells but did not exceed their respective 2L standards. No Appendix II PCBs were detected in the groundwater samples collected during the fall 2020 water quality monitoring event. 4.2 Surface Water Quality One metal, lead, was detected at a concentration that exceeded its applicable 2B standard for surface water during this monitoring event. Concentrations in the upstream sample exceeded concentrations in the downstream sample for all metals that were detected. No VOCs were detected at concentrations that exceeded the applicable surface water standards. Field parameters measured in both surface water samples, including pH, turbidity, and DO, were within the 2B standards established for these parameters. Based on these data, the groundwater migrating from the landfill toward the Tuckasegee River does not appear to be impacting surface water quality with regard to metals and VOCs. 4.3 Leachate Quality The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for Appendix I VOCs and 1,4-dioxane. Seventeen VOCs were detected in the leachate sample (Table 3). There are no established water quality standards for leachate. 1,4-Dioxane was detected at 58 pg/L, which is higher than the detected concentrations of the compound in the monitoring well groundwater samples. This is the first sampling event where 1,4 dioxane was analyzed for in the leachate. 4.4 Domestic Well Water Quality No VOCs were detected at concentrations that exceeded their respective MDLs in the domestic well water samples. Fall 2020 Semiannual Water Quality Monitoring Report 15 January 2021 5 Future Activities Anchor QEA will continue to monitor the water quality on a semiannual basis at the Site. During spring 2021, domestic well owners will be contacted, and groundwater samples will be collected from domestic wells if permitted by the well owner, and if possible, based on well pump operability. Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring wells, surface water monitoring points, and leachate flow equalization tank during spring 2021 and fall 2021. In addition to the MNA parameters that were added to the monitoring requirements as part of the CAP, the analytical suites associated with the current and future sampling events are outlined in the 2011 CAP (Altamont 2011) and the first Five -Year CAER (Altamont 2016). The upcoming sampling event parameters are as follows: Sampling Event Analytical Suite (not inclusive of natural attenuation parameters) Appendix I VOCs (including 1,4-dioxane) Spring 2021 Appendix I Metals Sulfide Appendix 11 VOCs (including 1,4-dioxane) Fall 2021 Appendix 11 Metals Sulfide The second Five -Year CAER is scheduled for fall 2021. This evaluation will include a detailed analysis of the contaminant and MNA parameter trends to assess effectiveness of the MNA program. This report will also include an evaluation of MW-01 and MW-06 as representative background wells at the Site. Fall 2020 Semiannual Water Quality Monitoring Report 16 January 2021 6 References Altamont (Altamont Environmental, Inc.), 2010.Assessment of Corrective Measures. Prepared for the North Carolina Department of Environment and Natural Resources. September 7, 2010. Altamont, 2011. Corrective Action Plan. Prepared fort he North Carolina Department of Environment and Natural Resources. June 30, 2011. Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for the North Carolina Department of Environmental Quality. October 31, 2016. DENR (North Carolina Department of Environmental and Natural Resources), 2011. Letter to: Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan. September 1, 2011. DEQ (North Carolina Department of Environmental Quality), 2018a. Memorandum to: Solid Waste Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding: 1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods. May 29, 2018. DEQ, 2018b. "Groundwater Protection Compliance Standards — Constituents List". Last modified October 15, 2018. Available at: https://edocs.deq.nc.gov/WasteManagement/0/edoc/1257181/SWS EnviroMonitoring Const ituents List.pdf?searchid=13f8efbl-eel 1-485a-b03f-718f2287b271 DEQ, 2020. Memorandum Re: New Electronic Data Deliverable (EDD) Format. July 20, 2020. EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. OSWER, EPA/540/5-95/504. EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling. April 26, 2017. Fall 2020 Semiannual Water Quality Monitoring Report 17 January 2021 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Location ID Date Collected Sample ID Appendix II VOCs 1,4-Dioxane Appendix II Metals Mercury Appendix II SVOCs Apendix II Herbicides Appendix II Pesticides Appendix II PCBs EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A EPA 8270D EPA 8151A EPA 8081 B and 8141 B EPA 8082A MW-01 10/14/2020 MW-01-20201014 X X X X X X X X MW-02 10/13/2020 MW-02-20201013 X X X X X X X X MW-03 10/13/2020 MW-03-20201013 X X X X X X X X MW-04 10/12/2020 MW-04-20201012 X X X X X X X X MW-05R 10/12/2020 MW-05R-20201012 X X X X X X X X MW-06 10/13/2020 MW-06-20201013 X X X X X X X X MW-07 10/12/2020 MW-07-20201012 X X X X X X X X Surface Water, Leachate, Domestic Well, and Quality Control Samples Location ID Date Collected Sample ID Appendix II VOCs 1,4-Dioxane Appendix II Metals Mercury Calcium, Magnesium, Hardness Appendix II SVOCs Apendix II Herbicides Appendix II Pesticides Appendix II PCBs VOCs EPA 8260D EPA 8260D SIM EPA 6020B EPA 7470A EPA 200.7 EPA 8270D EPA 8151A EPA 8081 B and 8141 B EPA 8082A EPA 524.2 DW-01 10/14/2020 DW-01-20201014 X LT-01 10/14/2020 LT-01-20201014 X X X SW-01 10/14/2020 SW-01-20201014 X X X X X X X X X SW-02 10/14/2020 SW-02-20201014 X X X X X X X X X TB-01 10/12/2020 TB-202010120000 X TB-02 10/13/2020 TB-202010130000 X TB-03 10/14/2020 TB-202010130000 X Groundwater and Surface Water Samples: Monitored Natural Attenuation Parameters Location ID Date Collected Sample ID COD BOD Ferrous Iron Total Alkalinity to pH 4.5 Nitrate as N Chloride Sulfate TOC Sulfide Cyanide Volatile Fatty Acids Carbon Dioxide Ethane, Ethene, Methane Dissolved Hydrogen SM 5220D SM 5210B SM 3500-Fe D SM 2320B EPA 9056A SM 9060A SM4500-S F SM 4500-CN-E AM20GAX MW-01 10/14/2020 MW-01-20201014 X X X X X X X X X X X X X MW-02 10/13/2020 MW-02-20201013 X X X X X X X X X X X X X MW-03 10/13/2020 MW-03-20201013 X X X X X X X X X X X X X X MW-04 10/12/2020 MW-04-20201012 X X X X X X X X X X X X X X MW-05R 10/12/2020 MW-05R-20201012 X X X X X X X X X X X X X MW-06 10/13/2020 MW-06-20201013 X X X X X X X X X X X X X X MW-07 10/12/2020 MW-07-20201012 X X X X X X X X X X X X X X Notes: Appendix II constituents were analyzed per Title 40 Code of Federal Regulations, Part 258. Blank cell: Analysis was not performed on that sample. AM: Analytical Method BOD: biochemical oxygen demand COD: chemical oxygen demand EPA: U.S. Environmental Protection Agency (method) PCBs: Polychlorinated biphenyls SIM: Selective Ion Monitoring SM: Standard Method SVOCs: Semi -volatile organic compounds TB: Trip Blank TOC: total organic carbon VOC: volatile organic compound Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 2 Well Construction Details and Corresponding Elevations Stick Up Depth to Depth to Elevation of Ground (feet Depth To Approximate Approximate Top of Bottom of Top Elevation Bottom of Surface TOC above Total Well Water Depth to Top of Bedrock Screened Screened of Screened Screened Geology of Source of Well Elevation Elevation ground Depth (feet below Groundwater Bedrock Elevation Interval Interval Interval Interval Screened Construction Facility Permit Well ID Date Drilled (feet) (feet) surface) (feet bgs) TOC) Elevation (feet) (feet bgs) (feet) (feet bgs) (feet bgs) (feet) (feet) Interval Information MW-01 04/23/1992 2,169.40 2,171.42 2.0 110.5 92.91 2,078.51 83.0 2,086.40 95.0 110.0 2,074.40 2,059.40 Bedrock MW-02 04/22/1992 2,013.15 2,015.38 2.3 60.7 39.50 1,975.88 13.0 2,000.15 45.0 60.0 1,968.15 1,953.15 Bedrock Partially S&ME, Inc. MW-03 04/21/1992 2,044.16 2,045.53 1.3 65.5 43.76 2,001.77 57.0 1,987.16 48.5 63.5 1,995.66 1,980.66 Weathered Rock 50-02 MW-04 04/21/1992 1,978.68 1,980.77 2.0 43.0 27.28 1,953.49 NA NA 25.0 40.0 1,953.68 1,938.68 Saprolite MW-05R 01/26/2012 2,027.98 2,030.95 2.8 54.0 43.58 1,987.37 NA NA 44.0 54.0 1,983.98 1,973.98 Saprolite MW-06 03/23/2004 2,136.58 2,139.57 3.0 94.0 76.04 2,063.53 47.6 2,088.98 84.6 94.6 2,051.98 2,041.98 Bedrock Altamont Environmental, Inc. MW-07 07/30/2010 1,978.71 1,981.29 2.6 95.0 30.73 1,950.56 44.0 1,935.00 70.0 95.0 1,908.71 1,883.71 Bedrock Notes: Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc. Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveying, PA. Depth to water was measured on October 12, 13, and 14, 2020 (Appendix A). Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., boring logs completed April 21 through 23, 1992. Depth to bedrock and screened interval for MW-06 was taken from an Altamont Environmental, Inc., boring log completed March 23, 2004. Depth to bedrock and screened interval for MW-07 was taken from an Altamont Environmental, Inc., boring log completed July 30, 2010. Depth to bedrock and screened interval for MW-05R was taken from an Altamont Environmental, Inc., boring log completed January 26, 2012. Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05. Monitoring well MW-05R was surveyed by Wes Cole Land Surveying, PA, on September 28, 2012. bgs: below ground surface NA: not applicable TOC: top of casing Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 3 Analytical Summary Domestic Well Sample Leachate Sample Monitoring Well Samples Surface Water Samples QC Samples Location ID DW-01 LT-01 MW-01 MW-02 MW-03 MW-04 MW-05R MW-06 MW-07 SW-01 SW-02 FieldQC FieIdQC FieIdQC Sample ID DW-01- 20201014 LT-01- 20201014 MW-01- 20201014 MW-02- 20201013 MW-03- 20201013 MW-04- 20201012 MW-0511- 20201012 MW-06- 20201013 MW-07- 20201012 SW-01- 20201014 SW-02- 20201014 TB- 202010120000 TB- 202010130000 TB - 202010140000 Sample Date 10/14/2020 10/14/2020 10/14/2020 10/13/2020 10/13/2020 10/12/2020 10/12/2020 10/13/2020 10/12/2020 10/14/2020 10/14/2020 10/12/2020 10/13/2020 10/14/2020 Sample Type N N N N N N N N N N N TB TB TB Matrix WG WG WG WG WG WG WG WG WG WS WS WQ WQ WQ X 730117.7 730041.8 729526.4 728841.4 729285.1 729406 729649.3 729170.4 729395.8 729383.4 728409 Y 618143.8 617628.1 618129.2 617869.4 617628.9 617105.4 617259.7 618177.5 617118.8 616840.8 618322.7 Method NC2L NC2L IMAC NC213 Conventional Parameters Water Level Depth (ft) Field Measure -- -- 92.91 39.5 43.76 27.28 43.58 76.04 30.73 -- -- - - Temperature (field) (°C) Field Measure 16.1 20.2 15.8 18 17.9 17 26.3 16.5 16.8 15.7 16.1 - - pH (field) (SU) Field Measure/SM4500 6.5-8.5 6.0-9.0 6.46 6.88 5.7 7.1 # 8.11 S.7S 6.82 7.11 6.07 6.36 6.6 -- - Turbidity (field) (NTU) Field Measure :550 7.74 8.2 10 >1,000 5.19 3.94 53.7 5.99 7.06 36.9 29 -- - Dissolved oxygen (field) Field Measure >_6 4.86 1.67 1.47 5.08 3.28 2.11 1.43 1.55 1.79 10.35 10.67 -- - Specific Conductivity (field) (µS/cm) Field Measure 70.5 3384 210.3 218.4 324 424.1 668 52.8 758 36.7 26.7 -- -- ORP (mV) Field Measure 186.7 -85.1 30.5 -57.3 -112.4 302.8 -130 -139.9 138.4 127.9 153.6 -- -- Hardness as CaCO3 (mg/L) SM2340C -- -- -- -- Monitored Natural Attenuation Results Alkalinity, Total (µg/L) SM2320B 20000 100000 55000 140000 64000 240000 24000 250000 Biochemical oxygen demand (mg/L) SM5210B -- -- 3.1 2.3 2 J 0.38 J 5.2 0.28 J 0.92 J -- -- -- -- Chemical oxygen demand (mg/L) SM5220C -- -- 24 J 37 J 35 J 13 J 42 J 11 U 18 J -- -- -- -- Chloride (mg/L) SW9056A 250 230 -- -- 1.2 25 8.5 24 55 1.1 79 -- -- -- -- Cyanide (mg/L) 9014 70 0.014 U 0.014 U 0.014 U 0.014 U 0.014 U 0.014 U 0.014 U Nitrate as nitrogen (mg/L) SW9056A -- -- 0.045 U 0.17 J 8.3 6.5 0.075 J 0.096 J 0.092 J -- -- -- -- Sulfate (mg/L) SW9056 250 -- -- 0.56 U 20 4 91 0.56 U 0.83 J 25 -- -- -- -- Sulfide (mg/L) SM4500S2F -- -- 0.83 U 0.83 U 0.83 U 0.83 U 5 0.83 U 0.83 U -- -- -- -- Total organic carbon (mg/L) SM5310B -- -- 1.78 2.26 4.68 2.05 7.05 1.04 3.22 -- -- -- -- Ferrous iron (µg/L) SM3500FEB 1000 -- -- 39000 46 U 46 U 46 U 12000 46 U 360 -- -- -- -- - Hydrogen (nM) EPA RSK-175 -- -- 43 10 -- 4.1 10 Methane (µg/L) AM20GAX -- -- 4000 5 3.5 390 3700 140 640 -- -- -- -- -- Acetic acid (mg/L) AM23G 5000 -- -- 0.45 J 0.76 0.95 0.54 4.2 J 0.58 0.45 J -- -- -- -- -- Formic acid (mg/L) AM23G -- -- 5.4 5.1 4.8 4.8 50 5 4.8 -- -- -- -- -- Lactic Acid (mg/L) AM23G 0.053 U 0.053 U 0.072 J 0.053 U 0.53 U 0.053 U 0.53 U Propionic Acid (mg/L) AM23G 0.053 U 0.053 J 0.056 J 0.053 U 0.53 U 0.054 J 0.53 U Carbon dioxide (µg/L) AM20GAX -- -- 128000 37100 14700 99300 45300 159000 178000 -- -- -- -- -- Appendix II Metals, Total (Ng/L) Arsenic SW6020 10 10 -- 2.9 0.17 U 7.5 0.31 J 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U 0.17 U -- -- -- Barium SW6020 700 21000 -- 500 100 250 110 81 110 47 390 16 16 -- -- - Beryllium SW6020 4 -- 0.19 U 0.19 U 1.6 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U 0.19 U -- -- -- Cadmium SW6020 2 *0.21 -- 0.16 U 0.17 J 0.16 U 0.16 U 0.24 J 0.16 U 0.16 U 0.16 U 0.16 U 0.16 U -- -- -- Chromium SW6020 10 *6.63 -- 2.S 0.99 J 61 0.86 J 0.79 U 0.79 U 0.79 U 0.9 J 0.86 J 0.94 J -- -- -- Cobalt SW6020 1 -- 3.8 160 60 0.59 J 1.7 J 8.3 9 1.4 J 0.52 U 0.52 U -- -- -- Copper SW6020 1000 *0.72 -- 3.8 U 3.8 U 61 3.8 J 3.8 U 5.5 J 3.8 U 3.8 U 3.8 U 3.8 U -- -- - Lead SW6020 15 *0.09 -- 0.26 U 0.26 U 14 0.26 U 0.26 U 0.26 U 0.26 U 0.26 U 0.3 J 0.38 J -- -- -- Mercury SW7470 1 -- 0.23 1.1 0.87 1.1 1 0.73 1.3 0.53 1.1 0.95 -- -- -- Nickel SW6020 100 *4.30 -- 20 16 44 0.96 J 1 J 2.7 J 3.4 7.1 1.5 J 1.5 J -- -- - Selenium SW6020 20 5 -- 0.79 J 1 J 42 0.74 U 2.3 J 0.85 J 0.74 U 0.74 U 0.74 U 0.85 J -- -- - Thallium SW6020 0.2 0.38 U 0.38 U 0.96 J 0.38 U 0.38 U 0.38 U 0.38 U 0.38 U 0.38 U 0.38 U Vanadium SW6020 0.3 2.4 J 7.3 U 71 7.3 U 7.3 U 7.3 U 7.3 U 7.3 U 1.3 U 1.3 U Zinc SW6020 1000 *9.72 -- 6.9 U 11 J 140 6.9 U 6.9 U 18 J 20 J 6.9 U 6.9 U 6.9 U -- -- -- Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 3 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 3 Analytical Summary Domestic Well Sample Leachate Sample Monitoring Well Samples Surface Water Samples QC Samples Location ID DW-01 LT-01 MW-01 MW-02 MW-03 MW-04 MW-05R MW-06 MW-07 SW-01 SW-02 FieldQC FieIdQC FieIdQC Sample ID DW-01- 20201014 LT-01- 20201014 MW-01- 20201014 MW-02- 20201013 MW-03- 20201013 MW-04- 20201012 MW-0511- 20201012 MW-06- 20201013 MW-07- 20201012 SW-01- 20201014 SW-02- 20201014 TB- 202010120000 TB- 202010130000 TB - 202010140000 Sample Date 10/14/2020 10/14/2020 10/14/2020 10/13/2020 10/13/2020 10/12/2020 10/12/2020 10/13/2020 10/12/2020 10/14/2020 10/14/2020 10/12/2020 10/13/2020 10/14/2020 Sample Type N N N N N N N N N N N TB TB TB Matrix WG WG WG WG WG WG WG WG WG WS WS WQ WQ WQ X 730117.7 730041.8 729526.4 728841.4 729285.1 729406 729649.3 729170.4 729395.8 729383.4 728409 Y 618143.8 617628.1 618129.2 617869.4 617628.9 617105.4 617259.7 618177.5 617118.8 616840.8 618322.7 Method NC2L NC2L IMAC NC213 Appendix II Metals, Dissolved (Ng/L) Antimony SW6020 1 -- - -- 0.49 U -- - 0.49 U - -- 0.49 U 0.54 J -- - Arsenic SW6020 10 10 -- -- -- 0.17 U -- - 0.17 U - -- 0.17 U 0.17 U -- - - Barium SW6020 700 21000 -- -- -- 24 -- - 60 - -- 12 10 -- -- - Cobalt SW6020 1 -- -- -- 0.52 U -- -- 8.3 - -- 0.52 U 0.52 U -- -- - Nickel SW6020 100 -4.30 -- -- -- 0.81 J -- -- 1.4 J -- -- 0.51 U 0.51 U -- -- - Selenium SW6020 20 5 -- -- -- 1.3 J -- -- 0.74 U -- -- 0.74 U 0.74 U -- -- -- Zinc SW6020 1000 -9.72 -- -- -- 6.9 U -- -- 181 -- -- 6.9 U 6.9 U -- -- -- Appendix II Volatile Organic Compounds (VOCs) and 1,4-Dioxane (Ng/L) 1,1-Dichloroethane SW8260 6 100 0.00050 U 0.083 U 2.8 0.29 J 0.083 U 0.083 U 0.083 U 1.4 0.083 U 0.083 U 0.083 U 0.083 U 0.083 U 0.083 U 1,2,4-Trichlorobenzene SW8260 70 0.076 0.00050 U 0.13 U 0.13 U 0.13 U 0.13 U 0.13 U 0.13 U 0.13 U 0.23 J 0.73 U 0.73 U 0.13 U 0.13 U 0.13 U 1,2-Dichlorobenzene SW8260 20 400 0.00050 U 0.076 U 0.22 J 0.076 U 0.076 U 0.076 U 0.076 U 0.076 U 0.5 0.076 U 0.076 U 0.076 U 0.076 U 0.076 U 1,2-Dichloroethene, cis- SW8260 70 720 0.00050 U 0.29 J 4.5 0.38 J 0.056 U 0.46 J 0.41 J 1.4 2.6 0.056 U 0.056 U 0.056 U 0.056 U 0.056 U 1,3-Dichlorobenzene SW8260 200 -- 0.27 J 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 0.054 U 1,4-Dichlorobenzene SW8260 6 56 0.00050 U 4.8 9.8 0.05 U 0.05 U 0.85 0.89 2.6 6.8 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 1,4-Dioxane SW8260 3 -- 58 0.14 U 2.8 0.14 U 3.4 3.5 0.14 U 17 0.14 U 0.14 U -- -- -- Acetone SW8260 6000 2000 -- 11 5.7 0.31 U 0.31 U 0.31 U 0.31 U 0.31 U 0.31 U 0.31 U 0.31 U 3.2 J 3 J 3 J Acetonitrile (Ethanenitrile) SW8260 -- 4.7 J 3 U 3 U 3 U 3 U 3 U 3 U 3 U 3 U 3 U 3 U 3 U 3 U Benzene SW8260 1 51 0.00050 U 2.4 1.5 0.048 U 0.048 U 0.048 U 0.048 U 0.26 J 1.4 0.048 U 0.048 U 0.048 U 0.048 U 0.048 U Chlorobenzene SW8260 50 140 0.00050 U 4.4 1.9 0.062 U 0.062 U 0.69 0.67 0.41 J 6.1 0.062 U 0.062 U 0.062 U 0.062 U 0.062 U Chloroethane SW8260 3000 -- 0.47 J 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U Dichlorodifluoromethane SW8260 1000 -- 0.11 U 0.11 U 0.11 U 0.11 U 0.23 J 0.3 J 0.11 U 0.11 U 0.11 U 0.11 U 0.11 U 0.11 U 0.11 U Ethylbenzene SW8260 600 97 0.00050 U 1.8 0.33 J 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U 0.061 U m,p-Xylene SW8260 500 500 -- 1.7 0.83 J 0.21 J 0.37 J 0.31 J 0.27 J 0.37 J 0.42 J 0.12 U 0.12 U 0.12 U 0.12 U 0.12 U Naphthalene SW8260 6 -- 13 0.3 U 0.3 U 0.3 U 0.3 J 0.3 U 0.3 U 0.3 U 0.87 J 0.3 U 0.3 U 0.3 U 0.3 U o-Xylene SW8260 500 400 -- 2 0.26 J 0.044 U 0.044 U 0.044 U 0.044 U 0.29 J 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U Tetrachloroethene (PCE) SW8260 0.7 3.3 0.00050 U 0.098 U 0.48 J 0.098 U 0.098 U 0.098 U 0.098 U 0.25 J 0.098 U 0.098 U 0.098 U 0.098 U 0.098 U 0.098 U Tetrahydrofuran SW8260 -- 94 1.1 U 1.1 U 1.1 U 1.1 U 1.1 U 1.1 U 1.6 J 1.1 U 1.1 U 1.1 U 1.1 U 1.1 U Toluene SW8260 600 0.36 0.00050 U 0.79 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U 0.044 U Total Xylene SW8260 0.0010 U 3.7 1.11 0.21 J 0.37 J 0.31 J 0.27 J 0.66 J 0.42 J 0.15 U 0.15 U 0.15 U 0.15 U 0.15 U Trichloroethene (TCE) SW8260 3 30 0.00050 U 0.078 U 0.57 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U 0.078 U Vinyl chloride SW8260 0.03 2.4 0.00050 U 0.22 J 0.31 J 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U 0.097 U Appendix II Semivolatile Organic Compounds (SVOCs) (Ng/L) 1,2-Dichlorobenzene SW8270 20 470 -- -- 0.661 U 0.647 U 0.843 0.629 U 0.629 U 0.699 U 0.629 U 0.839 U 0.647 U -- -- -- 1,3-Dichlorobenzene SW8270 200 -- -- 0.516 U 0.505 U 0.791 0.491 U 0.491 U 0.545 U 0.491 U 0.654 U 0.505 U -- -- -- 1,4-Dichlorobenzene SW8270 6 56 -- -- 4.94 0.597 U 0.746 0.58 U 3.41 0.779 2.66 0.773 U 0.597 U -- -- -- Dibenzofuran SW8270 28 -- -- 0.444 U 0.435 U 0.427 U 0.423 U 0.518 0.47 U 0.423 U 0.564 U 0.435 U -- -- -- Diethyl phthalate SW8270 6000 -- -- 1.16 4.65 0.59 U 0.585 U 2.28 0.709 0.585 U 0.78 U 0.602 U -- -- -- Appendix II Pesticides (Ng/L) Hexachlorocyclohexane (BHC), beta- SW8081 0.02 -- -- 0.011 U 0.011 U 0.011 U 0.011 U 0.011 U 0.14 0.011 U 0.011 U 0.011 U -- -- -- Hexachlorocyclohexane (BHC), gamma- (Lindane) SW8081 0.03 -- -- 0.051 0.0063 U 0.0062 U 0.0062 U 0.01 J 0.0062 U 0.0061 U 0.0061 U 0.0062 U -- -- -- Appendix II Herbicides (pg/L) 2,4,5-TP (Silvex) SW8151 50 -- -- 0.01634 U 0.01634 U 0.01634 U 0.01634 U 0.08098 0.01634 U 0.01634 U 0.01634 U 0.01634 U -- -- -- 2,4-D (2,4-Dichlorophenoxyacetic acid) SW8151 70 -- -- 0.3728 0.2078 U 0.2078 U 0.2078 U 0.2078 U 0.2078 U 0.2078 U 0.2078 U 0.2078 U -- -- -- Fall 2020 Semiannual Water Quality Monitoring Report Page 2 of 3 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 3 Analytical Summary Notes: 'Detected concentration is greater than NC2L or NC2L IMAC standard Detected concentration is greater than NC213 standard Bold: Detected result Italicized: Non -detected concentration is above one or more identified NC2L standard *: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017). NC26: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 213 — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health. NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. All nondetect results are reported at the method detection limit. Appendix II: per 40 Code of Federal Regulations Part 258 Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (US Survey Feet). --: not sampled °C: degrees Celsius Ng/L: micrograms per liter ft:feet IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. N: The laboratory does not hold NELAP/TNI accreditation for thi method or analyte J: Estimated value mg/L: milligrams per liter mv: millivolts N: normal environmental sample NTU: nephelometric turbidity unit ORP: oxidation-reduction potential SU: standard unit SW: surface water TB: Trip Blank U: Compound analyzed for, but not detected above minimum detection limit WG: groundwater sample WQ: water quality I = sample analyzed in laboratory using EPA Method SM4500, because of field equipment malfunction Fall 2020 Semiannual Water Quality Monitoring Report Page 3 of 3 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01) Sample Dates Detected Volatile Organic Compounds Concentration in LT-01 (mg/L) Cumulative Flow at Gauge (gallons) Differential Flow (gallons) Mass Removed (pounds) Estimated Cumulative Mass Removed (pounds) Beginning Ending 09/01/2012 10/25/2012 1,4-Dichlorobenzene 0.0034 11,500 11,500 0.00033 4-Meth I-2- entanone (MIBK) 0.0021 J 0.00020 Acetone 0.0292 0.00280 Benzene 0.0021 0.00020 Chlorobenzene 0.0029 0.00028 cis- 1,2-Dichloroethene 0.00063 J 0.00006 Dichlorodifluoro-methane 0.00093 J 0.00009 Eth (benzene 0.0102 0.00098 Naphthalene 0.0069 0.00066 Styrene 0.00033 J 0.00003 Toluene 0.003 0.00029 X lene (Total) 10.0094 0.00090 Total 0.00682 0.00682 10/26/2012 04/11/2013 1,4-Dichlorobenzene 0.006 65,500 54,000 0.00270 Acetone 0.012 J 0.00540 Benzene 0.0011 0.00049 Carbon disulfide 0.0067 J 0.00301 Chlorobenzene 0.0024 J 0.00108 cis- 1,2-Dichloroethene 0.00058 J 0.00026 Eth (benzene 0.0083 0.00373 Toluene 0.00059 J 0.00027 X lene (Total) 0.0078 0.00351 Total 0.02045 0.02727 04/12/2013 10/08/2013 1,4-Dichlorobenzene 0.0055 114,737 49,237 0.00226 4-Meth I-2- entanone (MIBK) 0.0012 J 0.00049 Benzene 0.0020 0.00082 Chlorobenzene 0.0039 0.00160 cis- 1,2-Dichloroethene 0.00080 J 0.00033 Eth (benzene 0.0151 0.00619 Naphthalene 0.0184 0.00754 Toluene 0.0012 0.00049 X lene (Total) 0.0090 0.00369 Total 0.02341 0.05068 10/09/2013 04/08/2014 1,4-Dichlorobenzene 0.0056 168,821 54,084 0.00252 Benzene 0.0018 0.00081 Chlorobenzene 0.0051 0.00230 cis- 1,2-Dichloroethene 0.00049 J 0.00022 Eth (benzene 0.0047 0.00212 Toluene 10.00041 1 J 0.00018 X lene (Total) 10.0021 1 J 0.00095 Total 0.00910 0.05978 04/08/2014 10/23/2014 1,4-Dichlorobenzene 0.0053 179,652 10,831 0.00048 Benzene 0.0014 0.00013 Chlorobenzene 0.003 0.00027 cis- 1,2-Dichloroethene 0.00049 J 0.00004 Eth (benzene 10.0027 0.00024 Toluene 10.00051 1 J 0.00005 X lene (Total) 10.0014 1 J 0.00013 Total 0.00133 0.06111 10/23/2014 04/21/2015 1,2,3-Trimethyl benzene 0.00062 219,965 40,313 1,2,4-Trimethyl benzene 0.00076 0.00026 2-Chlorotoluene 0.00067 0.00022 1,4-Dichlorobenzene 0.0059 0.00198 Acetone 0.00790 0.00265 Benzene 0.0022 0.00074 Chlorobenzene 0.003 0.00101 Eth (benzene 0.0056 0.00188 Isopropyl benzene 0.0013 0.00044 Methy Tert-but I -Ether 0.0013 0.00044 Na thalene 0.024 0.00806 n-Propylbenzene 0.00088 0.00030 Tetrah drofuran 0.089 0.02988 Toluene 0.00054 J 0.00018 Vin I Chloride 0.00038 J 0.00013 X lene (Total) 10.0030 J 0.00101 Total 0.04937 0.11048 04/21/2015 10/13/2015 1,4-Dichlorobenzene 0.00600 256,685 36,720 0.00183 2-Butanone 0.00960 J 0.00294 Benzene 0.00210 0.00064 Chlorobenzene 0.0040 0.00122 Ethylbenzene 0.00710 0.00217 m, -X lenes 0.0014 0.00043 Naphthalene 0.021 0.00642 o-X lene 0.0017 0.00052 Tetrah drofuran 0.062 0.01896 Toluene 0.00058 J 0.00018 Total X lenes 0.0031 J 0.00095 Total 0.03626 0.14674 10/13/2015 04/05/2016 1,4-Dichlorobenzene 0.00590 315,663 1 58,978 0.00290 Benzene 0.00170 0.00083 Chlorobenzene 0.0038 0.00187 Eth (benzene 0.00500 0.00246 m, -X lenes 0.0010 0.00049 o-X lene 10.0015 1 0.00074 Toluene 10.00063 1 J 0.00031 Total X lenes 10.0025 1 J 0.00123 Total 0.01082 0.15756 04/05/2016 10/11/20161 No detected compounds. 331,010 1 15,347 0.00000 Total 0.00000 0.15756 Fall 2020 Semiannual Water Quality Monitoring Report Page 1 of 2 Jackson County Closed Municipal Solid Waste Landfill January 2021 Table 4 Mass Removal Calculations for Volatile Organic Compounds (VOCs) Detected in the Leachate Sample (LT-01) Sample Dates Detected Volatile Organic Compounds Concentration in LT-01 (mg/L) Cumulative Flow at Gauge (gallons) Differential Flow (gallons) Mass Removed (pounds) Estimated Cumulative Mass Removed (pounds) Beginning Ending 10/11/2016 03/21/2017 1,4-Dichlorobenzene 0.0046 334,212 3,202 0.00012 Acetone 0.0094 J 0.00025 Benzene 0.0015 0.00004 Chlorobenzene 0.0043 0.00011 Eth (benzene 0.0014 0.00004 m, -X lenes 0.0006 J 0.00002 o-X lene 0.00092 0.00002 Tetrah drofuran 10.066 1 0.00176 Total X lenes 10.0015 1 J 0.00004 Total 0.00241 0.15997 03/21/2017 10/11/2017 1,4-Dichlorobenzene 0.0041 364,76054 0. 4 Acetone 0.0067 J 0.00170 Acetonitrile 0.008 J Benzene 0.00061 Chlorobenzene 0.0012 0.00031 Eth (benzene 10.00087 0.00022 Naphthalene 10.0012 0.00031 Tetrahydrofuran 10.12 0.03053 Total 0.03630 0.19627 Issue with totalizer between October 2017 and March 2018 03/21/2018 10/18/2018 1,4-Dichlorobenzene 0.0028 1,784,710 159,341 0.00372 Acetone 0.017 0.02256 Benzene 0.0012 0.00159 Chlorobenzene 0.0024 0.00318 Eth (benzene 0.0018 0.00239 m, -X lenes 0.00038 J 0.00050 Methylene Chloride 0.00034 J 0.00045 o-X lene 0.00060 0.00080 X lenes, Total 0.00098 J 0.00130 Total 0.04 0.23 10/18/2018 10/22/2019 1,4-Dichlorobenzene 0.0037 2,045,960 261,250 0.00805 Acetone 0.006 1 0.01305 Benzene 0.0017 0.00370 Chlorobenzene 0.0038 0.00827 Eth (benzene 0.0016 0.00348 o-X lene 10.00110 1 0.00239 Toluene 10.00039 1 J 0.00085 X lenes, Total 10.0017 1 J 0.00370 Total 0.04 0.28 10/22/2019 03/18/2020 1,4-Dichlorobenzene 0.0056 2,139,992 94,032 0.00438 1,4-Dioxane 0.06 0.04697 Acetone 0.0064 0.00501 Benzene 0.0013 0.00102 Chlorobenzene 0.0032 0.00250 Eth (benzene 0.0027 0.00211 m, -X lenes 0.00089 J 0.00070 Methyl isobut I ketone 0.00079 J 0.00062 o-X lene 0.00120 0.00094 Toluene 0.00070 0.00055 Total 0.06 0.34 03/18/2020 10/14/2020 1,2-Dichloroethene, cis- 0.00029 J 2,238,782 98,790 0.00024 1,3-Dichlorobenzene 0.00027 J 0.00022 1,4-Dichlorobenzene 0.0048 0.00395 1,4-Dioxane 0.058 0.04770 Acetone 0.011 0.00905 Acetonitri e (Et anenrtn e) 0.0047 J 0.00387 Benzene 0.0024 0.00197 Chlorobenzene 0.0044 0.00362 Chloroethane 0.00047 J 0.00039 Eth (benzene 0.0018 0.00148 m, -X lene 0.0017 0.00140 Naphthalene 0.013 0.01069 o-X lene 0.002 0.00164 Tetrah drofuran 0.094 0.07731 Toluene 0.00079 0.00065 Total X lene 0.0037 0.00304 Vinyl chloride 0.00022 J 0.00018 Total 0.17 0.51 N otes: 1. No VOCs were detected in the leachate sample collected during the October 2016 sampling event. Only detected volatile organic compounds (VOCs) in leachate sample LT-01 are included in the mass removal calculation. Leachate extraction at the landfill was initiated on September 1, 2012. Extraction volume measurements were recorded and provided by Jackson County staff. Anchor QEA bases mass removal calculations on the assumption that the VOCs concentration in one sampling event is representative of leachate quality until the next sampling event occurs, and that the leachate removal system has a 100% removal and treatment efficiency. Due to a malfunction with the leachate totalizer, there is a gap in total volume calcuations between October 11, 2017 and March 21, 2018. Represents the total flow between the LT-01 sample dates. Estimated cumulative mass removed and treated is estimated based upon a conversion of milligrams to pounds and liters to gallons and the multiplication of the concentration by the differential flow for the specified period. mg/L: milligrams per liter J: Indicates laboratory estimated concentration is above the adjusted method detection limit and below the adjusted reporting limit. Fall 2020 Semiannual Water Quality Monitoring Report Page 2 of 2 Jackson County Closed Municipal Solid Waste Landfill January 2021 Figures LI UA �� 1(� _'� � _., „� • `� +lf# III. ---• �� � � r„ `L•i �:L.` �y��� f � i ///�/ it 2 \1 �JP\ f l LEGEND: SOURCES: 1. BaUSGS Topographic Maps Greens ® Site Parcel Boundary Creekk and Whittier 7.5-minute Quadrangles 2. Parcel: Jackson County GIS 0 2,000 Feet Publish Date: 2020/11/23, 8:10 AM I User: alesueur Filepath:\\orcas\gisVobs\)acksonCounty_NC_1480\Maps\2020\FallWQ\AQ_Fig01_JacksonCounty_SpringWQ2020_SiteLocationMap.mxd )P, ANCHOR Figure 1 Q E A Site Location Map Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill -02 le MW-03 LT-01 VkV9 1 n MW-05R G11 , I MW-07 MW-04 s • 5W-01 O G u 4 LF LEGEND: NOTE: 41- Sample locations are approximate. Monitoring Well — Road Landfill Gas Extraction Well Elevation Contour (-Foot SOURCES: Ct20Ft Interval) � Aerial Imagery: Esri Online Services ® Domestic Well Sample Location 0 Property Boundary Contours, Roads, and Parcels: Jackson County GIS Leachate Sample Location and Flow Equalization Tank 0 Surface Water Sample Location Publish Date: 2020/11/23, 8:12 AM I User: alesueur Filepath:\\orcas\gisVobs\JacksonCounty_NC_1480\Maps\2020\FaIIWQ\AQ_Fig02_JacksonCounty_SpringWQ2020_SampleLocationMap.mxd n 0 500 Feet 11 kZANCHOR Figure 2 QEA-- Site Layout Map Anchor QEA of North Carolina, PLLC Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill LEGEND: ® Saprolite Monitoring Well — Stream ® PWR Monitoring Well — Road ® Bedrock Monitoring Well Elevation Contour (20-Foot Interval) Property Boundary (2,001.77) Groundwater Elevation (October 12, 13, and 14, 2020) immAi-nti \ 2100 CONN 27g0 2120 aGS"C' O ta\`��eGtOG� t Ge � feat Q� dot •MW-03 0 (2,001.77) N 2�AO 60 Z c 3 Cqt o Q w° MW-07 \ ,950.56) MW-04 (1,953.49) WILKEY 218 •MW-05R i 2020 0987.37) NOTES: 1. Monitoring well locations are approximate. 2. Groundwater elevations and flow direction are updated on a semiannual basis following sample collection events in March and October. 3. Groundwater flow direction is based on groundwater elevations from all Site monitoring wells. Direction is calculated based on depth to water measured on October 12, 13, and 14, 2020. 4. Last names of property owners are shown in parcels that border the landfill property. 5. PWR: partially weathered rock 6. Groundwater elevation in feet (North American Vertical Datum 1988) Publish Date: 2020/11/23, 8:22 AM I User: alesueur Filepath:\\orcas\gis\lobs\JacksonCounty_NC_1480\Maps\2020\FallWQ\AQ_Fig03_JacksonCounty_SpringWQ2020_GroundwaterElevationMap.mxd WILKEY WILKEY 0 N / Y SOURCES: 1. Elevation contours, roads, and parcels: Jackson County GIS 2. Groundwater elevations: calculated from surveys performed by Davenport & Associates, Inc. (MW-01, MW-02, MW-03, MW-04, and MW-06) and Wes Cole Land Surveying, PA (MW-05R and MW-07) WILKEY 2100 0 0 200 Feet N 0 Z}� ANCHOR Figure 3 QEA—`-�" Generalized Groundwater Flow Direction Anchor QEA of North Carolina, PLLC Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill Figure 4 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-01) 20 in 16 J a1 14 0 r 12 a V _ 0 10 a, a, = 8 a, 0 6 s0 V G 4 2 X r` r` co Co M M O O — N O O O O O N M m � � v2 u2 R R r: w 02 rn rn o 0 N N O O OO O O O O O CD O O N N N N N N N N N N N O N O CD N N CD N N N O N O E. N N CD O CD E. CD CDO N N N N N N O N N 0- U 0- U 0- U 0- U 0- U 0- Q 0 Q 0 < 0 Q 0 Q 0 Q U 0 0- U Q 0 0- U 0- < 0 Q U 0 0- U < 0 M U M U M U 2 0 g 0 2 0 M U 2 0 Notes: 1. NCH (2013) Standard = 6 micrograms per liter (µg/L) g Samp lin Date O 1,4-Dichlorobenzene 2. "J" indicates result is estimated by laboratory. NC2L (2013) Standard 3. "<" indicates result is less than method detection limit. 4. Oct 2017 result reported in semivolatile organic compound list. t Groundwater Elevation 2080 2078 INIYL a 2074 o a a W 2072 r 3 2070 3 0 1.2 2066 2064 Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 January 2021 Figure 5 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-01) 12 10 2 X r` r` e0 00 M rn o o N N m m t � 2 �2 R R w ao rn rn o 0 O O O O O O N N O O O O O O O O CD CD O O CD CD CD E. CD O CD E. CD CDO O N N N N N N N N N N N N N N N N N N N N N N N N N N N N Q U Q UQ U Q U U Q U Q U Q U 0-U Q U M U M U U M U �(< �( Q 0 Q 0 0 Q 0 Q 0 Q 0 Q 0 0 Q 0 0 2 0 g 0 0 2 0 Notes: 1. NC21- (2013) Standard = 1 microgram per liter (µg/L) Sampling Date O Benzene 2. "J' indicates result is estimated by laboratory. NC2L (2013) Standard 3. "U" indicates result is less than method detection limit. *Groundwater Elevation 2080.00 2078.00 2076.00 2074.00 2072.000 2070.00`i W 3 2068.00= 0 L W 2066.00 2064.00 Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 January 2021 Figure 6 Hydrograph and Vinyl Chloride Concentration vs. Time (Monitoring Well MW-01) 1• 1 _ 0.7 0 0.6 - <0.58 L r C 0.5 C O V 0.4 L 0 s 0.3 0.1 0 ISI 2078 g1XIII d a 2074 0 a W 2072 3 0.31 1 2070 c n 1` r` 00 a0 M M O O N N M M 'IT Iq u> Ln lfl lfl r- r` 00 a0 M M O O O O O O O O O O O O N N N N N N N N N N O O N N O O N N O N O O N N O N O N O . O O O O O O N N N N N N O O N N Q U V V V Q V a o a o a o a o a o V Q o Q V a o a V o a V o Q a U o ro V ro V co V 2 o 2 o 2 o fu V 2 o Notes: 1. NC2L (2013) Standard = 0.03 micrograms per liter (µg/L) Sampling p g Date Vinyl chloride 2. "J" indicates result is estimated by laboratory. NC21- (2013) Standard 3. " < " indicates result is less than method detection limit 0 Groundwater Elevation 1.E 2066 2064 Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 January 2021 Figure 7 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-04) 12 WE 2 X ao _rn a, O O O N N N U U L (O 0 Notes: 1. NC21- (2018) Standard 2L Standard = 3 micrograms per liter (µg/L) Sampling Date Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 O O N N O O N N i U fp V > 0 O 1,4-Dioxane NC2L (2018) Standard *Groundwater Elevation (feet) 1960 1955 1950 1945 W L _ 1940 0 L to 1935 1930 January 2021 Figure 8 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-0511) 10.0 .E :e O , 5.0 d = 4.0 O V 3.0 M x O p 2.0 1.0 M 00 _rn _rn O N O O O O N N N N O g O g Notes: 1. NCH (2018) Standard = 3 micrograms per liter (µg/L) Sampling Date Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 O N O N v O O 1,4-Dioxane NC2L (2018) Standard *Groundwater Elevation 1988 1986 a, 1984 a O .a 1982 „—°', a� �a 1980 C= 0 0 iGy%111111111111111 1976 January 2021 Figure 9 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-07) 8.0 6.0 c 4.0 u 2.0 C 11 N N n2 M It � L2 l2 lR lR O O O O O O O O O O O (D N N N N N N N N N N N N Q V Q V Q V Q V Q V Q V a o a o a o a o a o a o Notes: Sampling Date 1. NC21- (2013) Standard = 6 micrograms per liter (µg/L) 2. "J" indicates result is estimated by laboratory Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 r` r` W 00 Ol 61 O O N N O O O O O O O O N N N N N N N N M V (6 V (p V (6 V o o o o 1,4-Dichlorobenzene NC2L (2013) Standard 0 Groundwater Elevation 1951 1951 1950 1950 0 1949 a, W L 1949 3 _ 1948 0 ID 1948 1947 1947 January 2021 Figure 10 Hydrograph and 1,4-Dioxane Concentration vs. Time (Monitoring Well MW-07) 30 25 20 I 02 rn rn CD 0 0 0 0 0 0 N N N N N V 6 U c0 U 0 g O g 0 Notes: 1. NC21- (2018) Standard = 3 micrograms per liter (µg/L) Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Sampling Date 1,4-Dioxane NC2L (2018) Standard 4 Groundwater Elevation 1951 1951 1950 1950 1949 1949 1948 1948 January 2021 Figure 11 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-07) 2 flu 1.6 J 1.4 0 1.2 L _ GJ 1 0 v a 0.8 N _ GJ ca 1A 0.2 A N N m_ m2 v L2 �2 �2 �2 o 0 O O O O O O O O O O O O O O lV O O O O O fV O N N N N N N N N N N N N rQ N N N N N N N Q V Q O Q U Q V Q O Q O Q Q U O Q U Q V Q O Q O (6 V g O c6 V (6 U c6 O g O U U O Sampling Date Benzene Notes: 1. NC2L (2013) Standard = 1 microgram per liter (µg/L) NC2L (2013) Standard 2. "<" indicates result is less than method detection limit. --*—Groundwater Elevation 1951 1951 1950 0 1950 „°—,' a, _ 1949 c 0 1949 1948 Fall 2020 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 January 2021 Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets I ANCHOR C,2EA Nell Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Date: y `� Project Number: - Q� Weather. o. Sampling Personnel: �. _ Sample Time: Well ID: MW-01 Well Depth in Feet (WD): 110.5 ft TOC Well Diameter. 2 inches Water Level in Feet (WL): q1.9 I feet Type of Casing: pVC _ Length of Water Column: ITS S feet Measuring Point: TOC (WD) - (WL) = (LWC) Flush Mount /Stick-U One Casing Volume: DI gallons Comments: r ,V. (LWC) x (WCV) Three Casing Volumes:. gallons v� Actual Volume Purged: e - gallons Tagged bottom at: 6 ft Time: Measuring Point:-b C/ Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Lisserim bpecuric PM tbu4 uxt"ation 7 Gallons Oxygen Cond. report to 0.1 Reduction Turbidity Reading Time Purged Temp ('C) (mg/L) (PS/cm) S.U. Potential (NTU) Comments .3 -33 1 etc; 2 QL2— 3.� 5 �• c' 6 3 1 5: 1 4e �.f e 4 V 1 ;. � 5 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: Pad: .-Lock: A�✓—'Vegetation: Access: Sampling Personnel Signature: Date: �I c� �1" 4-1-Notes: Well Casing Volumes defined in Table 2 of t gion 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedure - Groundwater Sampling last revised April 26, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization. °C: degrees Celsius uS/cm: micro-Siemen per centimeter ag/L: milligrams per liter Method Reference: Temperature: SM 2550 B-2010 DO: SM 4500 O G-2011 mV: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Specific conductivity: EPA Method 120.1, Rev. 1982 pH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR Well Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Date: to l , G Project Number: I Mep ,U0 _ Weather: �UGTr✓-if- H�G — Sampling Personnel: _ Sample Time: : Ic Well ID: MW-02 Well Depth in Feet (WD): 60.70 ft TOC Well Diameter. 2 inches _ Water Level in Feet (WL):3C( 5-0 feet Type of Casing: pVC _ Length of Water Column: '7—i. feet Measuring Point: TOC (WD) - (WL) = (LWC) Flush Moun / Stick -Up One Casing Volume: 3.51 gallons Comments: (LWC) x (WCV) Three Casing Volumes: to gallons L Actual Volume Purged: gallons Tagged bottom at: CU. qh ft Time: 100Z Measuring Point- —i 1! Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1A7 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grund€os Other. LASSOrvftil Pe Gallons Oxygen Cond. report to 0. T Reduction Turbidity Reading Time Purged Temp (°C) (mg/L) (PS/cm) S.U. Potential (NTU) Comments 3 I6bC/ ^i.Z 1, "It 4 0�� — 5 ,� `p0I b�s© --t+ 0V �1 6 ' 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Protective Casing: Pad: 1_ Lock: Vegetation: Access: Sampling Personnel Signature: �~ Date: Notes: Well Casing Volumes defined in Table of a Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedu - GroundwaterSomp(inq last revised Apr, 6, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization. 'C: degrees Celsius mV: millivolt uS/cm: micro-Siemen per centimeter NTU: nephelometric turbidity units �,p j ng/L: milligrams per liter S.U.: Standard Units T t 6�,1/� 1� L Method Reference: Specific conductivity: EPA Method 120.1, Rev. 1982 Temperature: SM 2550 B-2010 pH: SM 4500-H' B-2011 DO: SM 4500 O G-2011 Page 1 of 1 VL �� la,0 10; ANCHOR ow -Flow Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Project Number: _ Location: Imo; l Date: Sampling Personnel: ` _ Weather: Well ID: MW-03 Arrive at Well: Screen Interval: 48.5-63.5 ft bgs Start Time: Depth to Water: `�� _ft Sample Time: Measuring Point: TOC Finish Sample Time: Depth of Pump Intake: 50 ft Leave Well: Drawdown Set: qLt ft Pump Used (circle): Peristaltic Bladder Other (describe): Well Diameter: 2 in Comments: 1AAC*"V1rr" Pure Rate: wt1A VW(A(D ,'<�� I a 1 Total Purge Volume: Tagged bottom at: L' 0, ft Time: 2v Pumpspeed:AjS 13s fill,3q S pH (S.U.) Time DTW (feet) Temp ("C) DO (mg/L) Specific Cond. (pS) report O.T S.U. ORP (mV) Turbidity (NTU) p ptoo I i I . - ice. _• 6Y ' --■ A lei Sampling Personnel Signature: Date: Notes: Q-1-1, LI-11 V Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity,- +/- 3% Conductivity; +/- 0.1 pH unit; +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) Samples are analyzed immediately upon collection, pS: micro-Siemen mv: millivolt °C: degrees Celsius f 7/� ♦ NTU: nephelometric turbidity units bgs: below ground surface F '� t1 `� lnr ORP: oxidation reduction potential DO: dissolved oxygenFh*eAr ; ^ a� S.U: standard units mg/L: milligrams per liter C, " v ��r v p toc: top of casing Method Reference: C1. + VL `a LVIJ►✓ ` emperature: SM 2550 B-2010 Specific conductivity: EPA Method 1201, Rev. 1982 + JO: SM 4500 O G-2011(� \ `� t pH: SM 4500-H* B-2011 Page 1 of 1 ANCHOR QEA.' %ow -Flow Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Location: U MS6&_61 No Sampling Personnel: kvi AL, Well ID: MW-04 Screen Interval: 25-40 ft bgs Depth to Water: G . ft Measuring Point: TQC Depth of Pump Intake: 35 ft Drawdown Set: ? � 1 -3 ft Pump Used (circle): Peristaltic Bladder Other (describe): Comments: 3 iq� L340 �+� �f F <�Vp "UTK 6ttio _ Tagged bottom at: 4 d ft Time:�0� Project Number: CO (LtM )� • 0 v �o Date: 10 C4 qu Weather. /VLOAA�S Arrive at Well: �Z Start Time: Sample Time: l '%jC6 Finish Sample Time: 0 Leave Well: (if 10 Well Diameter: 2 in Purge Rate: m— wt,iy� Total volume Purged: '1_ ,77S Pumpspeed: As 10 �Stt ?-5 Time DTW (feet) Temp (°C) DO (mg/L) Specific Cond. (pS) PH (S.U.) reportS0 0.1 S U. ORP (mV) Turbidity (NTU) 3 1?7 .50 (-1i 5 g, bq t q fig- b .-3I f�. a --= _ 05: �21 S.1S 5, 3 �5 0. a -o ±U5 - - 3- to .55 ay 19 a. 6(1101 P-5 Tp-30 an 0 �� 3 5. 5, Ile ,45 5 35 C 3 5 _q 0 q. i qaq. 5 1 3 a. Sampling Personnel Signature: Date: 1 �/ v—/ Notes: LI C" L/ Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) Samples are analyzed immediately upon collection. pS: micro-Siemen °C: degrees Celsius bgs: below ground surface DO: dissolved oxygen mg/L: milligrams per liter Method Reference: -emperature: SM 2550 B-2010 60: SM 4500 0 G-2011 mv: millivolt NTU: nephelometric turbidity units ORP: oxidation reduction potential _$ S.U.: standard units toc: top of casing Specific conductivity: EPA Method 120.1, Rev. 1982 PH: SM 4500-H' B-2011 Page 1 of 1 61i ANCHOR QEA Well Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Date: 0 Project Number:_���(�`'�t•Q� Weather. �1dU1S Sampling Personnel: t Sample Time: Well ID: MW-05R Well Depth in Feet (WD): 54.0 feet TOC Well,Diameter: 2 inch Water Level in Feet (WL): k feet Type of Casing: PVC Length of Water Column: 10 s `Ia feet Measuring Point: TOC (WD) - (WL) = (LWC) Flush Mount Stick Up One Casing Volume: 1,677 gallons Comments: (LWC) x (WCV) Three Casing Volumes: C gallons Actual Volume Purged: gallons Tagged bottom at:, f, ffTOC ft Time: a5 Measuring Point: T Well Casing Volumes (WCV) 1" = 0.04 Gal/Ft 2" = 0.16 Gal/Ft 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.47 Gal/Ft 8" = 2.61 Gal/Ft 12" = 5.87 Gal/Ft Purge Method: Bailer-Disp. I Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Sample Method: Bailer-Dis . Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. LIMORRM mmic-ITIC PH [".1 x d son Gallons Oxygen Cond. report to 0.1 Reduction Turbidity Reading Time Purged Temp (°C) (mg/L) (PS/cm) S.U. Potential (NTU) Comments 1 , f', I 0. - '? ,A-/ b •-1 1.13 - (la , U T Lj L JLLY J3 Y 4 we it dry a -a vi yt 5 ^' 1. q 6 7 8 9 10 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic LA 1 i a YL 125 mL Plastic 40 mL Glass 1 L Glass F S Other Protective Casing: Pad: Lock: Vegetatio Access: VV-c) f (jN I Sampling Personnel Signature: r Date: iv L. Notes: Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedure - Groundwater 5ampiing last revised April 26, 2017. Samples are analyzed immediately upon collection. Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization. °C: degrees Celsius uS/cm: micro-Siemen per centimeter ng/L: milligrams per liter Method Reference: Temperature: SM 2550 B-2010 DO: SM 4500 0 G-2011 mV: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Specific conductivity: EPA Method 120.1, Rev. 1982 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR It ..v QEA Low -Flow Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Location: l�i��5fj t �t-/ Sampling Personnel: Well ID: Mw-06 Screen Interval: 84-94 ft bgs Depth to Water: _4(f, 0 L ft Measuring Point: TQC Depth of Pump Intake: 93 ft ft Drawdown Set: ft Pump Used (circle): Peristaltic Bladder Other (describe): Comments: �'� Project Number: Date: Weather: L i Arrive at Well: !�?J Start Time: Sample Time: Finish Sample Time: N `0 Leave Well:N4V Well Diameter. 2 _ in $�C Stv�OZ/YO " 11{ Tagged bottom at ft Time:1 urgeValww heed: Time DTW (feet) Temp (°C) DO (mg/L) Specific Cond. (NS) PH (S.U.) reportto O.l S.U. ORP (mV) Turbidity (NTU) ` 34 19, Y `tr 6L G - LZ' 5-T� 3 00 _�,,52�,_� 1 �t3 S, 4 i1154 `.Ii3r$ r 6 1301 !G .T1`` o '0 r -1 0 © 3���" t 3 , 'L t ti< % G Z i t,5-+ S3,1 10,z - 3 1 d ,Z7. 116, ".-s sz, Fr l Sampling Personnel Signature: Date: I v .. Notes: J Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity; +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) Samples are analyzed immediately upon collection. �( 0'V1 i pS: micro-Siemen mv: millivolt f l V °C: degrees Celsius NTU: nephelometric turbidity units J A � ,...., , , ; ,jam bgs: below ground surface ORP: oxidation reduction potential ` �J ��/V C�, R DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing Method Reference: Temperature: SM 2560 6-2010 Specific conductivity: EPA Method 120.1, Rev, 1982 DO: SM 4600 0 G-2011 pH: SM 4500-H' B-2011 L Page 1 of 1 ANCHOR � QEA Low -Flow Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: ,Jackson County Dlllsboro Landfill Location: P! o5 AO" 6X/ Sampling Personnel: M(: AL Well ID: MW-07 Screen Interval: 70-95 ft bgs Depth to Water. )0,1 3 ft Measuring Point: TQC Depth of Pump Intake: 85 ft Drawdown Set: _'3t.qq^ ft Pump Used (circle): Peristaltic Bladder Other (describe): Comments:_ 6('Ri stfw WUS'C" IV Project Number: Co tLf go c(, 0 a - Date: 100 Z (2G Weather..0 ?1 rC',sf -70 vfr r Arrive at Well: L03 Start Time: W Sample Time: Finish Sample Time: fi7 Leave Well: ("a 70 Well Diameter: 2 in Pure Rate: 250 +nL eVA •. Total Purge Volume: Tagged bottom at: t Time: E S�� Pump speed: 14 di5 70 jaj, Time DTWjj(feet) Temp (°C) DO (mg/L) Specific Cond. (pS) PH (S.U.) report to 0.1 S.U. ORP (m1) Turbidity (NTU) a Y j l . I 144 10.3 s 30 ��� -° i !�-��- �• — t oC (3� �� Wtg 1 3131 to �— lo ?_ AS g, -0i0 Sampling Personnel Signature: Date: (7 0—/ Notes: s ' Stabilization (3 successive readings, 3 minutes apart): within +/- 10% DO and turbidity,, +/- 3% Conductivity, +/- 0.1 pH unit,' +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2017) Samples are analyzed immediately upon collection. pS: micro-Siemen °C: degrees Celsius bgs: below ground surface DO: dissolved oxygen mg/L: milligrams per liter Method Reference: Temperature: SM 2550 B-2010 D0: SM 4500 0 G-2011 mv: millivolt NTU: nephelometric turbidity units ORP: oxidation reduction potential S.U.: standard units toc: top of casing Specific conductivity: EPA Method 120.1, Rev. 1982 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR surface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Project Number.. f �1l"lI]s� �� %1 Sampling Personnel:Q Sample Name: SW_01 Comments: Upstream of landfill Date: Weather: �vrr Sample Method: Grab Syringe Pump Bailer-Disp. Other Dissolved Time Temp (°C) Oxygen (mg/L) Specific Cond. (PS/cm) pH (S.U.) report to 0. J S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments 11� IA Sampling Container Number of Containers Requested Analysis 500 mL Plastic 1 �iFrys 250 mL Plastic ZeA ei t 125 mL Plastic 40 mL Glass co VC o ^ 1 L Glassy Other Vegetation: Sampling Personnel Signature: Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius PS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mv: millivolt NTU• nephelometric turbidity units Access: k Date: Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 S.U.: standard units f Se ri Page 1 of 1 A Z /A��NCHOR 1v[i: A C_06-16.i aurface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Project Number. a. Lqn .■ � .,�J _ Sampling Personnel: _ �y— I'S �Y v Sample Name: SW-02 comments: Downstream of landfill Date: Weather: AA Iu Sample Method: Grab Syringe Pump Bailer-Disp. Other. Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. (PS/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 1 01 125 mL Plastic 40mLGlass A Mao ®� ao S`�- 1 L Glass Other Vegetation: Access: Sampling Personnel Signature: �� Date: �� ( tq V Notes: (r Samples are analyzed immediately upon collection. °C: degrees Celsius PS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H ` B-2011 r- Page 1 of 1 ,�z ANCHOR tiQEA Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Date: Project Number. GQ 14 �Ib C)t- 02 Weather o-t. Sampling Personnel: llla k Sample Name: DW-01 Comments: Purged 30 gallons prior to sampling. Wilkey residence. Sample Method(Grab Syringe Pump Bailer-Disp. Other. Temp rimeVC) Specific Cond. (PS) Dissolved Oxygen pH (S.U.) (mg/L) report to 0.7 S.U. Oxidation i Reduction Potential (m1) Turbidity (NTU) Comments pryry Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic V V 40 mL Glass 1 L Glass Other Vegetation: Access: Sampling Personnel Signature: Date: ( V 1 1 K I Notes: A / Method Reference: NS: micro-Siemen per cubic centimlerF/ Temperature: SM 2550 B-2010 "C: degrees Celsius Specific conductivity: EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mv: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units S.U.: standard units Page 1 of 1 ANCHOR `Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson County Dillsboro Landfill Project Number: Sampling Personnel: Sample Name: LT-01 Date: Weather: C/Iyzt/ Comments: collected from leachate tank _ ✓e. S/ r' vuh., 6.1) Sample Meth Grab Syringe Pump Bailer-Disp. Other: Time Temp VC) Specific Cond. (PS) Dissolved Oxygen pH (S.U.) (mg/L) report to 0.1 S.U. Oxidation Reduction Potential (m%o Turbidity (NTU) Comments Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plasticij 125 mL Plastic 40 mL Glass (� " 1 L Glass Other Vegetation: V Access: Sampling Personnel Signature: Date: Notes: NS: micro-Siemen per cubic centimeter °C: degrees Celsius mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR kpvLv QEA Equipment Documentation and Instrument Calibration Data Sheet CALIBRATION DOCUMENTATION Project Name: Jackson County Dillsboro Landfill Person Conducting Calibration: Project Number: (0Ig4;'1[)sD(.02--' Date of Calibration: Project Location: a RC kodYO j� Date of Field Measurements:16 EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company Select Turbidimeter: Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Instrument Reading Instrument Reading (Hach 2100Q) (HF Scientific MicroTPW) 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 NTU Calibration Expiration t �i Date: Cal: .� Cal: i Cal: - Cal: Cal: Cal: Time: i Time: ii - Time: Time: Time: Time: Calibration *Pre -Analysis Meas: Time: *Pre -Analysis m Time: Verification: Check (10 NTU): �� s `�' f' Check (10 NTU): *Post -Analysis Meas: Time: st-Analysis Meas: Time: Check (10 NTU): � Q Fc*ck (10 NTU): YSI Professional Plus Multiparameter Meter (s/n 118131101802) Instrument Readings Calibration Lot No. & Expiration Date Initial: Cal: mmHg: Temperature (°C): Time: Dissolved Oxygen l . � o � q` r tit � � � y q / � IV G D pH 7 S.U. initial- pHmVx Cal: �7 3, f pHmV: "— Time: � � 06 •�] report to 0.1 S.U. ;� 1 pH 4 S.U. initial "[ 0 1 pHmV: pHmV: " Cal: pHmV: ' Time: ® /� �{ report to 0.7 S.U. • V pH 10 S.U. Initial: I C pHmV: Cal: L1.11 pHmV: Time: � ��y I ( I report to 0.7 S. U. (� 1 QC* PH 7 S.U. report AM Time: Mea Mid Day Time: Check: PM Time: Check dS to 0.1 S.U. � 1,—T Spec. Cond. Initial: Cal: Time: Time: 1 y� 31 0 V 1W o 1 Slcm QC*: AM Time: Meas/:: Mid Day Time: Check: PM Time: Check: �h D ��r PS/cm % Recovery= ,}�.�h ORPmV � Initial: Cal: t emperature (°C): -rime: a . JD.' Signature: /'-� Date: j V Notes:tl Revision 3, 04/30/20, MHF 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 5. * QC check must be performed prior to sampling and following completion of sampling, at a minimum. 6. % Recovery = (Value Obtained, pS/cm _ True Value, pS/cm) x 100 Method Reference: Temp: SM 2550 B-2010 I Conductivity: EPA Method 720.1 1 DO: SM 4500 O G-2017 I pH: SM 4500-H+B-2017 I Turbidity: SM 2730 B-2077 I Page 1 of 1 ANCHOR C QEA � Equipment Documentation and Instrument Calibration Data Sheet Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 CALIBRATION DOCUMENTATION Project Name: Jackson County Dillsboro Landfill Person Conducting Calibration: Project Number. Date of Calibration: �-?7 Project Location: N1.16`60v, f4c, Date of Field Measurements: a?' EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental �ompan Select Turbidimeter: Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) rand. Doe7.vle�e, vwiil'c l� �n o N c�ead%� s CQ r✓i �,Ye 6 w-lu. IWU 1vK'Ol,�ia' b W� Of ('R.Inirt � Instrument Reading Instrument Reading (Hach 2100Q) (HF Scientific MicroTPW) 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 N Calibration Expiration l� it Date: Cal: q q Cal: An 0 Cal: 91 cp Cal: Cal: Time: Time: r.` IJ Time:. �� Time: Time: Time: Calibration *Pre -Analysis Meas: t L. ® Time: �� *Pre -Analysis as: Time: Verification.- Check (10 NTU): Check (10 N *Post -Analysis Meas: Time: y P�-1 *Post -Analysis Meas: Time: Check 00 NTU): , a- Check (10 NTU): YSI Professional Plus Multiparameter Meter (s/n 18B701802) Instrument Readings Calibration Lot No. & Expiration Date Dissolved Oxygen Initial: K:6 It Cal: jw c � mmHg: 3,u u � Temperature,(°C): Time: jT tib '1�� PH 7 S.U. Initial`: pQ( pHmV: Cal: pHmV: Time: report to 0.1 S. U. pH 4 S.U. Initial: T pHmV: ✓ Cal: L 0 V ✓ pHmV: - � Time: _ I _ - report to 0.1 S.U. E I l/°J,�_71•'f� prt 10 S.U. Initial- u pHmV.Cal: 1 v ®1 pHmV: / Time: V f report to 0.1 S.U. 'I . 1 V QC* pH 7 S.U. report AM Time: Meas: Mid Day Time: Check: PM Time: Check: to 0.1 S.U. Spec.ffC��ond. o V Initial:( 0 Cal: j Time: V Ns/cm D QC*: AM Time: Meas: Mid Day Time: Check: PM Time: Check: ��rr�� n Woo uS/cm V"l,0 % Recovery= yh, ORP V mV Initial(: Mop �-4Vr� Cal: �°� Temperature (°C): , Time: } V Signature: 11J A Date: Notes: Ll 99 ,,y� Revision 3, 04/3D/20, l :J l�/13�N `,�� af� 4 - --) 1. Electronic equip nt calibrated according to the manufacturer's operation manual. j� 2. Specific Conductivity should be calibrated according to values representative of historic range. + �v V a �+ 3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 5. * QC check must be performed prior to sampling and following completion of sampling, at a minimum. 6. % Recovery = (Value Obtained, pS/cm + True Value, pS/cm) x 100 Method Reference: Temp: SM 2550 B-2070 l Conductivity. EPA Method 720.7 l DO: SM 4500 O G-207 7 1 pH: SM 4500-H+B-2011 I Turbidity: SM 2730 B-2011 Page 1 of 1 ANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 CALIBRATION DOCUMENTATION -�/ _ Project Name: Jackson County DillSboro Landfill Person Conducting Calibration: 12 Yin Y' LJ 1- Project Number: 00i L4,R a-C(.(2 Z Date of Calibration: 110 Project Location: })}�(/ Date of Field Measurements: EQUIPMENT DOCUMENTATION Rental sample analysis equipment or meters used to take measurements: Equipment Type Brand Serial Number Date of Use Rental Company � 1 L ect Turbidimeter. Hach 2100Q (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Instrument Reading Instrument Reading (Hach 21000) (HF Scientific MicroTPW) 10 NTU 20 NTU 100 NTU 800 NTU 1,000 NTU 10.0 NTU 0.02 NTU Calibration Expiration Mal 11141 AU) Date: Cal: 11D1 C Cal: r1 (! Cal: Cal: Cal: Cal: - J Time: Y,1S Time: , Time: �71;�.' C-� Time: Time: �. Time: Calibration Verification: *Pre -Analysis Check (10 NTU): Meas: ( A0 Time: *Pre -Analysis Check (10 NTU): Meas. '' Time: *Post -Analysis Check (10 NTU): Meas• I �' Time• 77 �Jo *Post -Anal s Check NTU): Meas: Time: YSI Professional Plus Multiparameter Meter (s/n 1813101802) Instrument Readings Calibration Lot No. & Expiration Date Dissolved Oxygen InIal: 6 �1 Cal: + O 41 mmHg: 1 � © Temperature °C): / Ti PH 7 S.U. report to 0.1 S.U. Initial r �J ,, pHmV: Cal: 1� 7. G V pHmV: Timef, PH 4 S.U. report to 0.1 S.U. Initi9k. -) 1 pHmV: Cal:4 (� U pHmV: Time; _ �� 7 r/ -7 a r,' PH 10 S.U. report to 0.1 S.U. Initia;V :( pHmV: Cal: f 1l pHmV: Time Z V Z, QC* pH 7 S.U. report to 0.1 S.U. A ime: Mea,,;, ,. Mid Day Time: Check: PM Time: Check: �� L Spec. Cond. ao U S/crn Initiel:� 1illVV�� Cal'1®, 0 iV{ Tim 73 O !z ( / QC*: t l! /p�� pp�'� l 6 V S/cm AM Time:e:: '% MQas V 1i Mid Day Time: Check: PM Time: Check: y 03/L % Recovery= ORP �� mV it Inrti Calj�)%l L `� V Temperature °C): 1� i Time: -� r/ 7-1 Signature: Date: ZQ l Notes: L__!_ Revision 3, 04/30/20, MHF 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10%of the true value. If QC readings are out of range, the instrument needs to be recalibrated. 5. " QC check must be performed prior to sampling and following completion of sampling, at a minimum. 6. % Recovery = (Value Obtained, pS/cm + True Value, pS/cm) x 100 Method Reference: Temp: SM 2550 B-2010 I Conductivity. EPA Method 720.7 I DO: SM 4500 0 G-2071 l pH: SM 4500-H+B-2077 I Turbidity: SM 2130 B-2071 0!4� Page 1 of 1 Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Way poi nt ANALYTICAL Anchor QEA of North Carolina, PLLC Alec Macbeth 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill 2020 Fall Project No.: 50-02 Lab Submittal Date: 10/13/2020 Work Order: 0100161 Case Narrative 11 /30/20 10:34 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Dissolved hydrogen, Carbon dioxide, dissolved gasses and volatile fatty acids analyses were subcontracted to Pace/GCAL. Laboratory report is attached. Waypoint Summary of Detections does not include subcontracted data. Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a,j Angela D. Overcash Senior Project Manager This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 84 Data Qualifiers Key Reference: A ECCV failed low. Samples were re -analyzed with confirming results. Initial data reported. BRL BRL CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. DC The RPD between the primary and confirmation column concentrations is greater than 40. The result is reported from the primary column. HT Sample received and analyzed outside of the hold time. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L Parameter reported with possible low bias. LCS recovery below the QC limit. L2 LCSD recovery outside of the QC limits. LCS recovery within the limits. No further action taken. LCD2 LCS/LCSD RPD Value outside of the control limits. LCS and LCSD Values within the control limits. LH High LCS recovery. Analyte not detected in the sample(s). No further action taken. MI Matrix spike outside of the control limits. Matrix interference suspected. SE Surrogate recovery outside of the QC limits due to emulsion. SR Surrogate recovery outside of the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 84 1 Q Waypoint.. ANALYTICAL Sample Receipt Summary 11 /30/2020 Work Order: 0100161 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-04-20201012 0100161-01 Water MW-05R-20201012 0100161-02 Water MW-07-20201012 0100161-03 Water TB-202010120000 0100161-04 Water Samples were received in good condition at 2.1 degrees C unless otherwise noted 10/12/20 13:00 10/12/20 14:34 10/12/20 10:57 10/12/20 0:00 10/13/20 8:25 10/13/20 8:25 10/13/20 8:25 10/13/20 8:25 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 84 Way poi nt ANALYTICAL Summary of Detections 11/30/202C Work Order: 0100161 Prism ID Client ID Parameter Method Result Units 0100161-01 MW-04-20201012 Chloride 9056A 24000 ug/L 0100161-01 MW-04-20201012 Nitrate as N 9056A 6500 ug/L 0100161-01 MW-04-20201012 Sulfate 9056A 91000 ug/L 0100161-01 MW-04-20201012 Biochemical Oxygen Demand SM5210 B 380 J ug/L 0100161-01 MW-04-20201012 Chemical Oxygen Demand SM5220 D 13000 J ug/L 0100161-01 MW-04-20201012 Total Alkalinity to pH 4.5 SM2320 B 64000 ug/L 0100161-01 MW-04-20201012 Mercury 7470A 1.0 ug/L 0100161-01 MW-04-20201012 Barium 6020B 81 ug/L 0100161-01 MW-04-20201012 Cadmium 6020B 0.24 J ug/L 0100161-01 MW-04-20201012 Cobalt 6020B 1.7 J ug/L 0100161-01 MW-04-20201012 Nickel 6020B 1.0 J ug/L 0100161-01 MW-04-20201012 Selenium 6020B 2.3 J ug/L 0100161-01 MW-04-20201012 TOC 531OC-2011 2.05 mg/L 0100161-01 MW-04-20201012 1,4-Dichlorobenzene 8260D 0.85 ug/L 0100161-01 MW-04-20201012 Chlorobenzene 8260D 0.69 ug/L 0100161-01 MW-04-20201012 cis-1,2-Dichloroethylene 8260D 0.46 J ug/L 0100161-01 MW-04-20201012 Dichlorodifluoromethane 8260D 0.23 J ug/L 0100161-01 MW-04-20201012 Hexachlorobutadiene 8260D 0.20 J ug/L 0100161-01 MW-04-20201012 m,p-Xylenes 8260D 0.31 J ug/L 0100161-01 MW-04-20201012 Naphthalene 8260D 0.30 J ug/L 0100161-01 MW-04-20201012 Xylenes, total 8260D 0.31 J ug/L 0100161-01 MW-04-20201012 1,4-Dioxane 8260D SIM 3.4 ug/L 0100161-02 MW-05R-20201012 Chloride 9056A 55000 ug/L 0100161-02 MW-05R-20201012 Nitrate as N 9056A 75 J ug/L 0100161-02 MW-05R-20201012 Barium 6020B 60 ug/L 0100161-02 MW-05R-20201012 Cobalt 6020B 8.3 ug/L 0100161-02 MW-05R-20201012 Nickel 6020B 1.4 J ug/L 0100161-02 MW-05R-20201012 Zinc 6020B 18 J ug/L 0100161-02 MW-05R-20201012 Biochemical Oxygen Demand SM5210 B 5200 ug/L 0100161-02 MW-05R-20201012 Chemical Oxygen Demand SM5220 D 42000 J ug/L 0100161-02 MW-05R-20201012 Ferrous Iron SM3500-Fe B 12000 HT ug/L 0100161-02 MW-05R-20201012 Sulfide SM4500-S F 5000 ug/L 0100161-02 MW-05R-20201012 Total Alkalinity to pH 4.5 SM2320 B 240000 ug/L 0100161-02 MW-05R-20201012 gamma-BHC 8081B 0.010 DC, J ug/L 0100161-02 MW-05R-20201012 2,4,5-TP (Silvex) 8151A 0.08098 J pg/L 0100161-02 MW-05R-20201012 1,4-Dichlorobenzene 8270D 3.41 J pg/L 0100161-02 MW-05R-20201012 Dibenzofuran 8270D 0.518 J pg/L 0100161-02 MW-05R-20201012 Diethyl phthalate 8270D 2.28 J pg/L 0100161-02 MW-05R-20201012 Mercury 7470A 0.73 ug/L 0100161-02 MW-05R-20201012 Barium 6020B 110 ug/L 0100161-02 MW-05R-20201012 Cobalt 6020B 8.3 ug/L 0100161-02 MW-05R-20201012 Copper 6020B 5.5 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 84 Waypoint. ANALYTICAL Summary of Detections 11/30/202C Work Order: 0100161 Prism ID Client ID Parameter Method Result Units 0100161-02 MW-05R-20201012 Nickel 6020B 2.7 J ug/L 0100161-02 MW-05R-20201012 Selenium 6020B 0.85 J ug/L 0100161-02 MW-05R-20201012 Zinc 6020B 18 J ug/L 0100161-02 MW-05R-20201012 TOC 531OC-2011 7.05 mg/L 0100161-02 MW-05R-20201012 1,4-Dichlorobenzene 8260D 0.89 ug/L 0100161-02 MW-05R-20201012 Chlorobenzene 8260D 0.67 ug/L 0100161-02 MW-05R-20201012 cis-1,2-Dichloroethylene 8260D 0.41 J ug/L 0100161-02 MW-05R-20201012 Dichlorodifluoromethane 8260D 0.30 J ug/L 0100161-02 MW-05R-20201012 m,p-Xylenes 8260D 0.27 J ug/L 0100161-02 MW-05R-20201012 Xylenes, total 8260D 0.27 .1 ug/L 0100161-02 MW-05R-20201012 1,4-Dioxane 8260D SIM 3.5 ug/L 0100161-03 MW-07-20201012 Chloride 9056A 79000 ug/L 0100161-03 MW-07-20201012 Nitrate as N 9056A 92 J ug/L 0100161-03 MW-07-20201012 Sulfate 9056A 25000 ug/L 0100161-03 MW-07-20201012 Biochemical Oxygen Demand SM5210 B 920 J ug/L 0100161-03 MW-07-20201012 Chemical Oxygen Demand SM5220 D 18000 J ug/L 0100161-03 MW-07-20201012 Ferrous Iron SM3500-Fe B 360 HT ug/L 0100161-03 MW-07-20201012 Total Alkalinity to pH 4.5 SM2320 B 250000 ug/L 0100161-03 MW-07-20201012 1,4-Dichlorobenzene 8270D 2.66 J pg/L 0100161-03 MW-07-20201012 Mercury 7470A 0.53 ug/L 0100161-03 MW-07-20201012 Barium 6020B 390 ug/L 0100161-03 MW-07-20201012 Chromium 6020B 0.90 J ug/L 0100161-03 MW-07-20201012 Cobalt 6020B 1.4 J ug/L 0100161-03 MW-07-20201012 Nickel 6020B 7.1 ug/L 0100161-03 MW-07-20201012 TOC 531OC-2011 3.22 mg/L 0100161-03 MW-07-20201012 1,2,4-Trichoorobenzene 8260D 0.23 J ug/L 0100161-03 MW-07-20201012 1,2-Dichlorobenzene 8260D 0.50 ug/L 0100161-03 MW-07-20201012 1,4-Dichlorobenzene 8260D 6.8 ug/L 0100161-03 MW-07-20201012 Benzene 8260D 1.4 ug/L 0100161-03 MW-07-20201012 Chlorobenzene 8260D 6.1 ug/L 0100161-03 MW-07-20201012 cis-1,2-Dichloroethylene 8260D 2.6 ug/L 0100161-03 MW-07-20201012 m,p-Xylenes 8260D 0.42 J ug/L 0100161-03 MW-07-20201012 Tetrahydrofuran 8260D 1.6 J ug/L 0100161-03 MW-07-20201012 Xylenes, total 8260D 0.42 .1 ug/L 0100161-03 MW-07-20201012 1,4-Dioxane 8260D SIM 17 ug/L 0100161-04 TB-202010120000 Acetone 8260D 3.2 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 84 Laboratory Report IL A i • . 0 11 /30/2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 24000 ug/L NE 1000 350 1 9056A 10/13/20 19:25BMS POJ0221 Nitrate as N 6500 ug/L 10000 200 45 1 9056A 10/13/20 19:25BMS POJ0221 Sulfate 91000 ug/L 250000 2000 560 1 9056A 10/13/20 19:25BMS POJ0221 General Chemistry Parameters Biochemical Oxygen Demand 380 J ug/L NE 2000 210 1 SM5210 B 10/14/20 9:18 ENM POJ0276 Chemical Oxygen Demand 13000 J ug/L NE 50000 11000 1 SM5220 D 10/16/20 11:18SLS POJ0304 Cyanide <14 ug/L 10 25 14 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron <46 HT ug/L NE 200 46 1 SM3500-Fe B 10/13/20 11:14ENM POJ0199 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02ENM POJ0337 Total Alkalinity to pH 4.5 64000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD A 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081 B 10/14/20 20:31NMB POJ0214 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/14/20 20:31NMB POJ0214 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/14/20 20:31NMB POJ0214 Aldrin <0.015 ug/L 0.05 0.051 0.015 1 8081 B 10/14/20 20:31NMB POJ0214 alpha-BHC <0.0064 ug/L 0.05 0.051 0.0064 1 8081 B 10/14/20 20:31NMB POJ0214 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/14/20 20:31NMB POJ0214 beta-BHC <0.011 ug/L 0.05 0.051 0.011 1 8081 B 10/14/20 20:31NMB POJ0214 Chlordane <0.18 ug/L 0.5 0.51 0.18 1 8081 B 10/14/20 20:31NMB POJ0214 delta-BHC <0.0083 ug/L 0.05 0.051 0.0083 1 8081 B 10/14/20 20:31NMB POJ0214 Dieldrin <0.014 ug/L 0.002 0.051 0.014 1 8081 B 10/14/20 20:31NMB POJ0214 Endosulfan 1 <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/14/20 20:31NMB POJ0214 Endosulfan 11 <0.012 ug/L 0.1 0.051 0.012 1 8081 B 10/14/20 20:31NMB POJ0214 Endosulfan Sulfate <0.017 ug/L 0.1 0.051 0.017 1 8081 B 10/14/20 20:31NMB POJ0214 Endrin <0.014 ug/L 0.1 0.051 0.014 1 8081 B 10/14/20 20:31NMB POJ0214 Endrin Aldehyde <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/14/20 20:31NMB POJ0214 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/14/20 20:31NMB POJ0214 gamma-BHC <0.0062 ug/L 0.05 0.051 0.0062 1 8081 B 10/14/20 20:31NMB POJ0214 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/14/20 20:31NMB POJ0214 Heptachlor <0.013 ug/L 0.05 0.051 0.013 1 8081 B 10/14/20 20:31NMB POJ0214 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081 B 10/14/20 20:31NMB POJ0214 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/14/20 20:31NMB POJ0214 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/14/20 20:31NMB POJ0214 Surrogate Recovery Control Limits Decachlorobiphenyl 17 % 13-186 Tetrachloro-m-xylene 41 % 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 84 Laboratory Report • � 11 /30/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Polychlorinated Biphenyls (PCBs) by GC/ECD A Aroclor 1016 <0.21 ug/L NE 0.51 0.21 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1232 <0.16 ug/L NE 0.51 0.16 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1242 <0.14 ug/L NE 0.51 0.14 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1248 <0.14 ug/L NE 0.51 0.14 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1254 <0.16 ug/L NE 0.51 0.16 1 8082A 10/14/20 20:31NMB POJ0214 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/14/20 20:31NMB POJ0214 Surrogate Recovery Control Limits Tetrachloro-m-xylene 40 % 30-161 Decachlorobiphenyl 18 % 32-178 Total Metals SE Mercury 1.0 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:02EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 15:48JAB POJ0239 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/23/20 15:48JAB POJ0239 Barium 81 ug/L 100 2.0 0.81 1 6020B 10/23/20 15:48JAB POJ0239 Beryllium <0.19 CCV ug/L 1 1.0 0.19 1 6020B 10/23/20 15:48JAB POJ0239 Cadmium 0.24 J ug/L 1 1.0 0.16 1 6020B 10/23/20 15:48JAB POJ0239 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/23/20 15:48JAB POJ0239 Cobalt 1.7 J ug/L 10 2.0 0.52 1 6020B 10/23/20 15:48JAB POJ0239 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/23/20 15:48JAB POJ0239 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/23/20 15:48JAB POJ0239 Nickel 1.0 J ug/L 50 3.0 0.51 1 6020B 10/23/20 15:48JAB POJ0239 Selenium 2.3 J ug/L 10 5.0 0.74 1 6020B 10/23/20 15:48JAB POJ0239 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 18:33JAB POJ0490 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/23/20 15:48JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 15:48JAB POJ0239 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 15:48JAB POJ0239 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/23/20 15:48JAB POJ0239 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 17:27JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 17:27JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 17:27JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 17:27JLB POJ0321 1, 1 -Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 17:27JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 17:27JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 17:27JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 17:27JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 17:27JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 17:27JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 17:27JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 17:27JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 17:27JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 17:27JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 17:27JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 17:27JLB POJ0321 1,4-Dichlorobenzene 0.85 ug/L 1 0.50 0.050 1 8260D 10/21/20 17:27JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 17:27JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 17:27JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 17:27JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 17:27JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 17:27JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 17:27JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 17:27JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 17:27JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 17:27JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 17:27JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 17:27JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 17:27JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 17:27JLB POJ0321 Chlorobenzene 0.69 ug/L 3 0.50 0.062 1 8260D 10/21/20 17:27JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 17:27JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 17:27JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 17:27JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 17:27JLB POJ0321 cis-1,2-Dichloroethylene 0.46 J ug/L 2 0.50 0.056 1 8260D 10/21/20 17:27JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 17:27JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 17:27JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 17:27JLB POJ0321 Dichlorodifluoromethane 0.23 J ug/L 5 5.0 0.11 1 8260D 10/21/20 17:27JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 17:27JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 17:27JLB POJ0321 Hexachlorobutadiene 0.20 J ug/L 10 2.0 0.16 1 8260D 10/21/20 17:27JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 17:27JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 84 . Laboratory Report • � Waynt.. 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID m,p-Xylenes 0.31 J ug/L NE 1.0 0.12 1 8260D 10/21/20 17:27JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 17:27JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 17:27JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 17:27JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 17:27JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 17:27JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 17:27JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 17:27JLB POJ0321 Naphthalene 0.30 J ug/L 10 1.0 0.30 1 8260D 10/21/20 17:27JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 17:27JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 17:27JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 17:27JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 17:27JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 17:27JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 17:27JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 17:27JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 17:27JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 17:27JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 17:27JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 17:27JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 17:27JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 17:27JLB POJ0321 Xylenes, total 0.31 J ug/L 5 1.5 0.15 1 8260D 10/21/20 17:27JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 100 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 3.4 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 20:23ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 1,4-Naphthoquinone <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 1-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 2-Acetylaminofluorene <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 2-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 3-Methylcholanthrene <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 4-Aminobiphenyl <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 5-Nitro-o-toluidine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 7,12-D1methyl benz(a)anthrace ne <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Diallate <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Hexachloropropene <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Isosafrole <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Kepone <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Methapyrilene <10 Ng/L 20 10 1 8270D 10/20/20 17:23BGV L517325 N-Nitrosomethylethyl amine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 N-Nitrosopiperidine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 N-Nitrosopyrrolidine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 o-Toluidine <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 p-Dimethylaminoazobenzene <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 p-Phenylenediamine <10 L pg/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Pronamide <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Safrole <10 Ng/L 10 10 1 8270D 10/20/20 17:23BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/21/20 1:33 VIC L517362 2,4,5-TP (Silvex) <0.01634 Ng/L 0.1 0.01634 1 8151A 10/21/20 1:33 VIC L517362 2,4-D <0.2078 Ng/L 0.25 0.2078 1 8151A 10/21/20 1:33 VIC L517362 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/21/20 1:33 VIC L517362 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/21/20 1:33 VIC L517362 Dicamba <0.057 Ng/L 0.1 0.057 1 8151A 10/21/20 1:33 VIC L517362 Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/21/20 1:33 VIC L517362 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/21/20 1:33 VIC L517362 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/21/20 1:33 VIC L517362 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/21/20 1:33 VIC L517362 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/21/20 1:33 VIC L517362 Surrogate Recovery Control Limits DCAA 55.8 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene <0.317 Ng/L 5 0.317 1 8270D 10/19/20 18:53CCB L517230 1,2,4-Trichlorobenzene <0.482 Ng/L 5 0.482 1 8270D 10/19/20 18:53CCB L517230 1,2-Dichlorobenzene <0.629 Ng/L 5 0.629 1 8270D 10/19/20 18:53CCB L517230 1,3-Dichlorobenzene <0.491 Ng/L 5 0.491 1 8270D 10/19/20 18:53CCB L517230 1,4-Dichlorobenzene <0.58 Ng/L 5 0.58 1 8270D 10/19/20 18:53CCB L517230 2,3,4,6-Tetrachlorophenol <0.355 Ng/L 5 0.355 1 8270D 10/19/20 18:53CCB L517230 2,4,5-Trichlorophenol <0.35 Ng/L 5 0.35 1 8270D 10/19/20 18:53CCB L517230 2,4,6-Trichlorophenol <0.344 Ng/L 5 0.344 1 8270D 10/19/20 18:53CCB L517230 2,4-Dichlorophenol <1.52 Ng/L 5 1.52 1 8270D 10/19/20 18:53CCB L517230 2,4-Dimethylphenol <0.674 Ng/L 5 0.674 1 8270D 10/19/20 18:53CCB L517230 2,4-Dinitrophenol <4.85 pg/L 10 4.85 1 8270D 10/19/20 18:53CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 84 ® Laboratory Report IL AL i • . 11 /30/2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 2,4-Dinitrotoluene <0.403 pg/L 5 0.403 1 8270D 10/19/20 18:53CCB L517230 2,6-Dichlorophenol <0.703 pg/L 5 0.703 1 8270D 10/19/20 18:53CCB L517230 2,6-Dinitrotoluene <0.413 pg/L 5 0.413 1 8270D 10/19/20 18:53CCB L517230 2-Chloronaphthalene <0.476 pg/L 5 0.476 1 8270D 10/19/20 18:53CCB L517230 2-Chlorophenol <0.736 pg/L 5 0.736 1 8270D 10/19/20 18:53CCB L517230 2-Methyl naphthalene <0.485 pg/L 2 0.485 1 8270D 10/19/20 18:53CCB L517230 2-Methylphenol <0.721 pg/L 5 0.721 1 8270D 10/19/20 18:53CCB L517230 2-Nitroaniline <0.574 pg/L 5 0.574 1 8270D 10/19/20 18:53CCB L517230 2-Nitrophenol <0.606 pg/L 5 0.606 1 8270D 10/19/20 18:53CCB L517230 3&4 Methylphenol <0.691 pg/L 5 0.691 1 8270D 10/19/20 18:53CCB L517230 3,3' Dimethylbenzidine <1.88 pg/L 10 1.88 1 8270D 10/19/20 18:53CCB L517230 3,3'-Dichlorobenzidine <3.74 pg/L 10 3.74 1 8270D 10/19/20 18:53CCB L517230 3-Nitroaniline <1.53 pg/L 10 1.53 1 8270D 10/19/20 18:53CCB L517230 4,6-Dinitro-2-methylphenol <3.47 pg/L 10 3.47 1 8270D 10/19/20 18:53CCB L517230 4-Bromophenyl phenyl ether <0.5 pg/L 5 0.5 1 8270D 10/19/20 18:53CCB L517230 4-Chloro-3-methylphenol <0.503 pg/L 5 0.503 1 8270D 10/19/20 18:53CCB L517230 4-Chloroaniline <0.526 pg/L 5 0.526 1 8270D 10/19/20 18:53CCB L517230 4-Chlorophenyl phenyl ether <0.479 pg/L 5 0.479 1 8270D 10/19/20 18:53CCB L517230 4-Nitroaniline <0.74 pg/L 5 0.74 1 8270D 10/19/20 18:53CCB L517230 4-Nitrophenol <1.39 pg/L 10 1.39 1 8270D 10/19/20 18:53CCB L517230 Acenaphthene <0.422 pg/L 2 0.422 1 8270D 10/19/20 18:53CCB L517230 Acenaphthylene <0.429 pg/L 2 0.429 1 8270D 10/19/20 18:53CCB L517230 Acetophenone <0.686 pg/L 5 0.686 1 8270D 10/19/20 18:53CCB L517230 Aniline <0.316 pg/L 5 0.316 1 8270D 10/19/20 18:53CCB L517230 Anthracene <0.467 pg/L 2 0.467 1 8270D 10/19/20 18:53CCB L517230 Benzidine <0.689 pg/L 20 0.689 1 8270D 10/19/20 18:53CCB L517230 Benzo(a)anthracene <0.427 pg/L 2 0.427 1 8270D 10/19/20 18:53CCB L517230 Benzo(a)pyrene <1 pg/L 2 1 1 8270D 10/19/20 18:53CCB L517230 Benzo(b)fluoranthene <0.941 pg/L 2 0.941 1 8270D 10/19/20 18:53CCB L517230 Benzo(q,h,i)perylene <1.36 pg/L 2 1.36 1 8270D 10/19/20 18:53CCB L517230 Benzo(k)fluoranthene <0.752 pg/L 2 0.752 1 8270D 10/19/20 18:53CCB L517230 Benzoic Acid <5 pg/L 10 5 1 8270D 10/19/20 18:53CCB L517230 Benzyl alcohol <3.01 pg/L 10 3.01 1 8270D 10/19/20 18:53CCB L517230 Bis(2-Chloroethoxy)methane <0.433 pg/L 5 0.433 1 8270D 10/19/20 18:53CCB L517230 Bis(2-Chloroethyl)ether <0.447 pg/L 5 0.447 1 8270D 10/19/20 18:53CCB L517230 Bis(2-Chloroisopropyl)ether <0.546 pg/L 5 0.546 1 8270D 10/19/20 18:53CCB L517230 Bis(2-ethylhexyl)phthalate <3.66 pg/L 5 3.66 1 8270D 10/19/20 18:53CCB L517230 Butyl benzyl phthalate <4.59 pg/L 5 4.59 1 8270D 10/19/20 18:53CCB L517230 Carbazole <0.476 pg/L 5 0.476 1 8270D 10/19/20 18:53CCB L517230 Chrysene <0.731 pg/L 2 0.731 1 8270D 10/19/20 18:53CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-04-20201012 Attn: Alec Macbeth Sample ID: 0100161-01 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 13:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID D1benz(a,h)anthrace ne <0.252 Ng/L 2 0.252 1 8270D 10/19/20 18:53CCB L517230 Dibenzofuran <0.423 Ng/L 5 0.423 1 8270D 10/19/20 18:53CCB L517230 Diethyl phthalate <0.585 Ng/L 5 0.585 1 8270D 10/19/20 18:53CCB L517230 Dimethyl phthalate <0.51 Ng/L 5 0.51 1 8270D 10/19/20 18:53CCB L517230 Di-n-butyl phthalate <1.58 Ng/L 5 1.58 1 8270D 10/19/20 18:53CCB L517230 Di-n-Octyl Phthalate <1.72 Ng/L 5 1.72 1 8270D 10/19/20 18:53CCB L517230 Fluoranthene <0.406 Ng/L 2 0.406 1 8270D 10/19/20 18:53CCB L517230 Fluorene <0.444 Ng/L 2 0.444 1 8270D 10/19/20 18:53CCB L517230 Hexachlorobenzene <2.57 Ng/L 5 2.57 1 8270D 10/19/20 18:53CCB L517230 Hexachlorobutadiene <0.405 Ng/L 5 0.405 1 8270D 10/19/20 18:53CCB L517230 Hexachlorocyclopentadiene <2.34 Ng/L 5 2.34 1 8270D 10/19/20 18:53CCB L517230 Hexachloroethane <0.277 pg/L 5 0.277 1 8270D 10/19/20 18:53CCB L517230 Indeno(1,2,3-cd)pyrene <1.01 Ng/L 2 1.01 1 8270D 10/19/20 18:53CCB L517230 Isophorone <0.36 Ng/L 5 0.36 1 8270D 10/19/20 18:53CCB L517230 Naphthalene <0.484 Ng/L 2 0.484 1 8270D 10/19/20 18:53CCB L517230 Nitrobenzene <0.531 Ng/L 5 0.531 1 8270D 10/19/20 18:53CCB L517230 N-Nitrosodiethylamine <0.4 Ng/L 5 0.4 1 8270D 10/19/20 18:53CCB L517230 N-Nitrosodimethylamine <0.249 Ng/L 5 0.249 1 8270D 10/19/20 18:53CCB L517230 N-Nitroso-di-n-butylamine <0.752 Ng/L 5 0.752 1 8270D 10/19/20 18:53CCB L517230 N-Nitroso-di-n-propylamine <0.334 pg/L 5 0.334 1 8270D 10/19/20 18:53CCB L517230 N-Nitrosodiphenylamine <0.783 pg/L 10 0.783 1 8270D 10/19/20 18:53CCB L517230 Pentachlorophenol <2.45 Ng/L 10 2.45 1 8270D 10/19/20 18:53CCB L517230 Phenanthrene <0.464 Ng/L 2 0.464 1 8270D 10/19/20 18:53CCB L517230 Phenol <0.389 Ng/L 5 0.389 1 8270D 10/19/20 18:53CCB L517230 Pyrene <1.04 pg/L 2 1.04 1 8270D 10/19/20 18:53CCB L517230 Pyridine <0.678 pg/L 10 0.678 1 8270D 10/19/20 18:53CCB L517230 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 27.3 % 39-110 SR 2-Fluorobiphenyl 42.7 % 24-93 2-Fluorophenol 19 % 10-44 4-Terphenyl-d14 112 % 35-126 Nitrobenzene-d5 43.5 % 20-91 Phenol-d6 13.4 % 7-32 Total Organic Carbon TOC 2.05 mg/L 1 0.498 1 531OC-2011 10/24/20 13:09DDB L518399 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 55000 ug/L NE 1000 350 1 9056A 10/13/20 22:03BMS POJ0221 Nitrate as N 75 J ug/L 10000 200 45 1 9056A 10/13/20 22:03BMS POJ0221 Sulfate <560 ug/L 250000 2000 560 1 9056A 10/13/20 22:03BMS POJ0221 Dissolved Metals Mercury <0.034 ug/L 0.20 0.034 1 7470A 10/15/20 17:08EDV POJ0259 Antimony <0.49 ug/L 2.0 0.49 1 6020B 10/23/20 14:12JAB POJ0218 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 10/23/20 14:12JAB POJ0218 Barium 60 ug/L 100 10 0.81 1 6020B 10/23/20 14:12JAB POJ0218 Beryllium <0.19 ug/L 1.0 0.19 1 6020B 10/23/20 14:12JAB POJ0218 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 10/23/20 14:12JAB POJ0218 Chromium <0.79 ug/L 2.0 0.79 1 6020B 10/23/20 14:12JAB POJ0218 Cobalt 8.3 ug/L 2.0 0.52 1 6020B 10/23/20 14:12JAB POJ0218 Copper <3.8 ug/L 10 3.8 1 6020B 10/23/20 14:12JAB POJ0218 Lead <0.26 ug/L 1.0 0.26 1 6020B 10/23/20 14:12JAB POJ0218 Nickel 1.4 J ug/L 50 3.0 0.51 1 6020B 10/23/20 14:12JAB POJ0218 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 14:12JAB POJ0218 Silver <0.11 ug/L 1.0 0.11 1 6020B 10/23/20 14:12JAB POJ0218 Thallium <0.57 ug/L 2.0 0.57 1 6020B 10/23/20 14:12JAB POJ0218 Tin <1.8 ug/L 5.0 1.8 1 6020B 10/23/20 14:12JAB POJ0218 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 14:12JAB POJ0218 Zinc 18 J ug/L 20 6.9 1 6020B 10/23/20 14:12JAB POJ0218 General Chemistry Parameters Biochemical Oxygen Demand 5200 ug/L NE 2000 210 1 SM5210 B 10/14/20 9:18 ENM POJ0276 Chemical Oxygen Demand 42000 J ug/L NE 50000 11000 1 SM5220 D 10/16/20 11:18SLS POJ0304 Cyanide <14 ug/L 10 25 14 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron 12000 HT ug/L NE 1000 230 5 SM3500-Fe B 10/13/20 11:14 ENM POJ0199 Sulfide 5000 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02 ENM POJ0337 Total Alkalinity to pH 4.5 240000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD A 4,4'-DDD <0.026 ug/L 0.1 0.10 0.026 1 8081 B 10/16/20 8:28 NMB POJ0214 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/16/20 8:28 NMB POJ0214 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/16/20 8:28 NMB POJ0214 Aldrin <0.015 ug/L 0.05 0.050 0.015 1 8081 B 10/16/20 8:28 NMB POJ0214 alpha-BHC <0.0063 ug/L 0.05 0.050 0.0063 1 8081 B 10/16/20 8:28 NMB POJ0214 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/16/20 8:28 NMB POJ0214 beta-BHC <0.011 ug/L 0.05 0.050 0.011 1 8081 B 10/16/20 8:28 NMB POJ0214 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Chlordane <0.18 ug/L 0.5 0.50 0.18 1 8081 B 10/16/20 8:28 NMB POJ0214 delta-BHC <0.0082 ug/L 0.05 0.050 0.0082 1 8081 B 10/16/20 8:28 NMB POJ0214 Dieldrin <0.014 ug/L 0.002 0.050 0.014 1 8081 B 10/16/20 8:28 NMB POJ0214 Endosulfan I <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:28 NMB POJ0214 Endosulfan 11 <0.012 ug/L 0.1 0.050 0.012 1 8081 B 10/16/20 8:28 NMB POJ0214 Endosulfan Sulfate <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:28 NMB POJ0214 Endrin <0.014 ug/L 0.1 0.050 0.014 1 8081 B 10/16/20 8:28 NMB POJ0214 Endrin Aldehyde <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:28 NMB POJ0214 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/16/20 8:28 NMB POJ0214 gamma-BHC 0.010 DC, ug/L 0.05 0.050 0.0061 1 8081B 10/16/20 8:28 NMB POJ0214 J trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/16/20 8:28 NMB POJ0214 Heptachlor <0.013 ug/L 0.05 0.050 0.013 1 8081 B 10/16/20 8:28 NMB POJ0214 Heptachlor Epoxide <0.022 ug/L 0.075 0.10 0.022 1 8081 B 10/16/20 8:28 NMB POJ0214 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/16/20 8:28 NMB POJ0214 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/16/20 8:28 NMB POJ0214 Surrogate Recovery Control Limits Decachlorobiphenyl 38 % 13-186 Tetrachloro-m-xylene 77 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD A Aroclor 1016 <0.21 ug/L NE 0.50 0.21 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1232 <0.16 ug/L NE 0.50 0.16 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1242 <0.14 ug/L NE 0.50 0.14 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1248 <0.14 ug/L NE 0.50 0.14 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1254 <0.16 ug/L NE 0.50 0.16 1 8082A 10/16/20 8:28 NMB POJ0214 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/16/20 8:28 NMB POJ0214 Surrogate Recovery Control Limits Tetrachloro-m-xylene 76 % 30-161 Decachlorobiphenyl 41 % 32-178 Total Metals Mercury 0.73 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 14:51 EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 16:08JAB POJ0239 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/23/20 14:12JAB POJ0239 Barium 110 ug/L 100 2.0 0.81 1 6020B 10/23/20 16:08JAB POJ0239 Beryllium <0.19 CCV ug/L 1 1.0 0.19 1 6020B 10/23/20 14:12JAB POJ0239 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/23/20 14:12JAB POJ0239 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/23/20 14:12JAB POJ0239 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Cobalt 8.3 ug/L 10 2.0 0.52 1 6020B 10/23/20 14:12JAB POJ0239 Copper 5.5 J ug/L 10 10 3.8 1 6020B 10/23/20 16:08JAB POJ0239 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/23/20 14:12JAB POJ0239 Nickel 2.7 J ug/L 50 3.0 0.51 1 6020B 10/23/20 16:08JAB POJ0239 Selenium 0.85 J ug/L 10 5.0 0.74 1 6020B 10/23/20 16:08JAB POJ0239 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 18:26JAB POJ0490 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/23/20 16:08JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 14:12JAB POJ0239 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 14:12JAB POJ0239 Zinc 18 J ug/L 10 20 6.9 1 6020B 10/23/20 14:12JAB POJ0239 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 18:01JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 18:01JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 18:01JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 18:01JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 18:01JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 18:01JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 18:01JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 18:01JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 18:01JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 18:01JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 18:01JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 18:01JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 18:01JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 18:01JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 18:01JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 18:01JLB POJ0321 1,4-Dichlorobenzene 0.89 ug/L 1 0.50 0.050 1 8260D 10/21/20 18:01JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 18:01JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 18:01JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 18:01JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 18:01JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 18:01JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 18:01JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 18:01JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 18:01JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 18:01JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 18:01JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 18:01JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 18:01JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 18:01JLB POJ0321 Chlorobenzene 0.67 ug/L 3 0.50 0.062 1 8260D 10/21/20 18:01JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 18:01JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 18:01JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 18:01JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 18:01JLB POJ0321 cis-1,2-Dichloroethylene 0.41 J ug/L 2 0.50 0.056 1 8260D 10/21/20 18:01JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 18:01JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 18:01JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 18:01JLB POJ0321 Dichlorodifluoromethane 0.30 J ug/L 5 5.0 0.11 1 8260D 10/21/20 18:01JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 18:01JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 18:01JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 18:01JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 18:01JLB POJ0321 m,p-Xylenes 0.27 J ug/L NE 1.0 0.12 1 8260D 10/21/20 18:01JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 18:01JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 18:01JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 18:01JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 18:01JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 18:01JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 18:01JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 18:01JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 18:01JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 18:01JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 18:01JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 18:01JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 18:01JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 18:01JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 18:01JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 18:01JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 18:01JLB POJ0321 trans- 1,4-Dich loro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 18:01JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 18:01JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 18:01JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 18:01JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 18:01JLB POJ0321 Xylenes, total 0.27 J ug/L 5 1.5 0.15 1 8260D 10/21/20 18:01JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 101 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 3.5 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 20:48ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 1,4-Naphthoqu!none <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 1-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 2-Acetylaminofluorene <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 2-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 3-Methylcholanthrene <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 4-Aminobiphenyl <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 5-Nitro-o-toluidine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 7,12-Dimethyl benz(a)anthrace ne <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Diallate <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Hexachloropropene <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Isosafrole <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Kepone <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Methapyrilene <10 Ng/L 20 10 1 8270D 10/20/20 17:45BGV L517325 N-Nitrosomethylethylamine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 N-Nitrosopiperidine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 N-Nitrosopyrrolidine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 o-Toluidine <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 p-Dimethylaminoazobenzene <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 p-Phenylenediamine <10 L Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Pronamide <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Safrole <10 Ng/L 10 10 1 8270D 10/20/20 17:45BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/21/20 0:16 VIC L517362 2,4,5-TP (Silvex) 0.08098 J Ng/L 0.1 0.01634 1 8151A 10/21/20 0:16 VIC L517362 2,4-D <0.2078 Ng/L 0.25 0.2078 1 8151A 10/21/20 0:16 VIC L517362 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/21/20 0:16 VIC L517362 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/21/20 0:16 VIC L517362 Dicamba <0.057 Ng/L 0.1 0.057 1 8151A 10/21/20 0:16 VIC L517362 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/21/20 0:16 VIC L517362 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/21/20 0:16 VIC L517362 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/21/20 0:16 VIC L517362 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/21/20 0:16 VIC L517362 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/21/20 0:16 VIC L517362 Surrogate Recovery Control Limits DCAA 73.3 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene <0.317 Ng/L 5 0.317 1 8270D 10/19/20 19:11 CCB L517230 1,2,4-Trichlorobenzene <0.482 Ng/L 5 0.482 1 8270D 10/19/20 19:11 CCB L517230 1,2-Dichlorobenzene <0.629 Ng/L 5 0.629 1 8270D 10/19/20 19:11 CCB L517230 1,3-Dichlorobenzene <0.491 pg/L 5 0.491 1 8270D 10/19/20 19:11 CCB L517230 1,4-Dichlorobenzene 3.41 j Ng/L 5 0.58 1 8270D 10/19/20 19:11 CCB L517230 2,3,4,6-Tetrachlorophenol <0.355 Ng/L 5 0.355 1 8270D 10/19/20 19:11 CCB L517230 2,4,5-Trichlorophenol <0.35 Ng/L 5 0.35 1 8270D 10/19/20 19:11 CCB L517230 2,4,6-Trichlorophenol <0.344 Ng/L 5 0.344 1 8270D 10/19/20 19:11 CCB L517230 2,4-Dichlorophenol <1.52 Ng/L 5 1.52 1 8270D 10/19/20 19:11 CCB L517230 2,4-Dimethylphenol <0.674 Ng/L 5 0.674 1 8270D 10/19/20 19:11 CCB L517230 2,4-Dinitrophenol <4.85 Ng/L 10 4.85 1 8270D 10/19/20 19:11 CCB L517230 2,4-Dinitrotoluene <0.403 Ng/L 5 0.403 1 8270D 10/19/20 19:11 CCB L517230 2,6-Dichlorophenol <0.703 Ng/L 5 0.703 1 8270D 10/19/20 19:11 CCB L517230 2,6-Dinitrotoluene <0.413 Ng/L 5 0.413 1 8270D 10/19/20 19:11 CCB L517230 2-Chloronaphthalene <0.476 pg/L 5 0.476 1 8270D 10/19/20 19:11 CCB L517230 2-Chlorophenol <0.736 Ng/L 5 0.736 1 8270D 10/19/20 19:11 CCB L517230 2-Methyl naphthalene <0.485 Ng/L 2 0.485 1 8270D 10/19/20 19:11 CCB L517230 2-Methylphenol <0.721 Ng/L 5 0.721 1 8270D 10/19/20 19:11 CCB L517230 2-Nitroaniline <0.574 Ng/L 5 0.574 1 8270D 10/19/20 19:11 CCB L517230 2-Nitrophenol <0.606 Ng/L 5 0.606 1 8270D 10/19/20 19:11 CCB L517230 3&4 Methylphenol <0.691 Ng/L 5 0.691 1 8270D 10/19/20 19:11 CCB L517230 3,3' Dimethylbenzidine <1.88 Ng/L 10 1.88 1 8270D 10/19/20 19:11 CCB L517230 3,3'-Dichlorobenzidine <3.74 pg/L 10 3.74 1 8270D 10/19/20 19:11 CCB L517230 3-Nitroaniline <1.53 pg/L 10 1.53 1 8270D 10/19/20 19:11 CCB L517230 4,6-Dinitro-2-methylphenol <3.47 Ng/L 10 3.47 1 8270D 10/19/20 19:11 CCB L517230 4-Bromophenyl phenyl ether <0.5 Ng/L 5 0.5 1 8270D 10/19/20 19:11 CCB L517230 4-Chloro-3-methylphenol <0.503 Ng/L 5 0.503 1 8270D 10/19/20 19:11 CCB L517230 4-Chloroaniline <0.526 pg/L 5 0.526 1 8270D 10/19/20 19:11 CCB L517230 4-Chlorophenyl phenyl ether <0.479 Ng/L 5 0.479 1 8270D 10/19/20 19:11 CCB L517230 4-Nitroaniline <0.74 Ng/L 5 0.74 1 8270D 10/19/20 19:11 CCB L517230 4-Nitrophenol <1.39 Ng/L 10 1.39 1 8270D 10/19/20 19:11 CCB L517230 Acenaphthene <0.422 Ng/L 2 0.422 1 8270D 10/19/20 19:11 CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 84 ® Laboratory Report IL AL i • . 11 /30/2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acenaphthylene <0.429 pg/L 2 0.429 1 8270D 10/19/20 19:11 CCB L517230 Acetophenone <0.686 pg/L 5 0.686 1 8270D 10/19/20 19:11 CCB L517230 Aniline <0.316 pg/L 5 0.316 1 8270D 10/19/20 19:11 CCB L517230 Anthracene <0.467 pg/L 2 0.467 1 8270D 10/19/20 19:11 CCB L517230 Benzidine <0.689 pg/L 20 0.689 1 8270D 10/19/20 19:11 CCB L517230 Benzo(a)anthracene <0.427 pg/L 2 0.427 1 8270D 10/19/20 19:11 CCB L517230 Benzo(a)pyrene <1 pg/L 2 1 1 8270D 10/19/20 19:11 CCB L517230 Benzo(b)fluoranthene <0.941 pg/L 2 0.941 1 8270D 10/19/20 19:11 CCB L517230 Benzo(g,hJ)perylene <1.36 pg/L 2 1.36 1 8270D 10/19/20 19:11 CCB L517230 Benzo(k)fluoranthene <0.752 pg/L 2 0.752 1 8270D 10/19/20 19:11 CCB L517230 Benzoic Acid <5 pg/L 10 5 1 8270D 10/19/20 19:11 CCB L517230 Benzyl alcohol <3.01 pg/L 10 3.01 1 8270D 10/19/20 19:11 CCB L517230 Bis(2-Chloroethoxy)methane <0.433 pg/L 5 0.433 1 8270D 10/19/20 19:11 CCB L517230 Bis(2-Chloroethyl)ether <0.447 pg/L 5 0.447 1 8270D 10/19/20 19:11 CCB L517230 Bis(2-Chloroisopropyl)ether <0.546 pg/L 5 0.546 1 8270D 10/19/20 19:11 CCB L517230 Bis(2-ethylhexyl)phthalate <3.66 pg/L 5 3.66 1 8270D 10/19/20 19:11 CCB L517230 Butyl benzyl phthalate <4.59 pg/L 5 4.59 1 8270D 10/19/20 19:11 CCB L517230 Carbazole <0.476 pg/L 5 0.476 1 8270D 10/19/20 19:11 CCB L517230 Chrysene <0.731 pg/L 2 0.731 1 8270D 10/19/20 19:11 CCB L517230 Dibenz(a,h)anthracene <0.252 pg/L 2 0.252 1 8270D 10/19/20 19:11 CCB L517230 Dibenzofuran 0.518 j pg/L 5 0.423 1 8270D 10/19/20 19:11 CCB L517230 Diethyl phthalate 2.28 j pg/L 5 0.585 1 8270D 10/19/20 19:11 CCB L517230 Dimethyl phthalate <0.51 pg/L 5 0.51 1 8270D 10/19/20 19:11 CCB L517230 Di-n-butyl phthalate <1.58 pg/L 5 1.58 1 8270D 10/19/20 19:11 CCB L517230 Di-n-Octyl Phthalate <1.72 pg/L 5 1.72 1 8270D 10/19/20 19:11 CCB L517230 Fluoranthene <0.406 pg/L 2 0.406 1 8270D 10/19/20 19:11 CCB L517230 Fluorene <0.444 pg/L 2 0.444 1 8270D 10/19/20 19:11 CCB L517230 Hexachlorobenzene <2.57 pg/L 5 2.57 1 8270D 10/19/20 19:11 CCB L517230 Hexachlorobutadiene <0.405 pg/L 5 0.405 1 8270D 10/19/20 19:11 CCB L517230 Hexachlorocyclopentadiene <2.34 pg/L 5 2.34 1 8270D 10/19/20 19:11 CCB L517230 Hexachloroethane <0.277 pg/L 5 0.277 1 8270D 10/19/20 19:11 CCB L517230 Indeno(1,2,3-cd)pyrene <1.01 pg/L 2 1.01 1 8270D 10/19/20 19:11 CCB L517230 Isophorone <0.36 pg/L 5 0.36 1 8270D 10/19/20 19:11 CCB L517230 Naphthalene <0.484 pg/L 2 0.484 1 8270D 10/19/20 19:11 CCB L517230 Nitrobenzene <0.531 pg/L 5 0.531 1 8270D 10/19/20 19:11 CCB L517230 N-Nitrosodiethylamine <0.4 pg/L 5 0.4 1 8270D 10/19/20 19:11 CCB L517230 N-Nitrosodimethylamine <0.249 pg/L 5 0.249 1 8270D 10/19/20 19:11 CCB L517230 N-Nitroso-di-n-butylamine <0.752 pg/L 5 0.752 1 8270D 10/19/20 19:11 CCB L517230 N-Nitroso-di-n-propylamine <0.334 pg/L 5 0.334 1 8270D 10/19/20 19:11 CCB L517230 N-Nitrosodiphenylamine <0.783 pg/L 10 0.783 1 8270D 10/19/20 19:11 CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 84 Laboratory Report • � 11 /30/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-05R-20201012 Attn: Alec Macbeth Sample ID: 0100161-02 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 14:34 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Pentachlorophenol <2.45 Ng/L Phenanthrene <0.464 Ng/L Phenol <0.389 Ng/L Pyrene <1.04 Ng/L Pyridine <0.678 ua/L Total Organic Carbon TOC 7.05 mg/L 10 2.45 1 8270D 10/19/20 19:11 CCB L517230 2 0.464 1 8270D 10/19/20 19:11 CCB L517230 5 0.389 1 8270D 10/19/20 19:11 CCB L517230 2 1.04 1 8270D 10/19/20 19:11 CCB L517230 10 0.678 1 8270D 10/19/20 19:11 CCB L517230 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 49 % 39-110 2-Fluorobiphenyl 43.5 % 24-93 2-Fluorophenol 23.7 % 10-44 4-Terphenyl-d14 104 % 35-126 Nitrobenzene-d5 47.2 % 20-91 Phenol-d6 15.7 % 7-32 1 0.498 1 531 OC-2011 10/24/20 13:47 DDB L518399 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 84 Laboratory Report • � 11 /30/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 79000 ug/L NE 1000 350 1 9056A 10/13/20 19:41 BMS POJ0221 Nitrate as N 92 J ug/L 10000 200 45 1 9056A 10/13/20 19:41 BMS POJ0221 Sulfate 25000 ug/L 250000 2000 560 1 9056A 10/13/20 19:41 BMS POJ0221 General Chemistry Parameters Biochemical Oxygen Demand 920 J ug/L NE 2000 210 1 SM5210 B 10/14/20 9:18 ENM POJ0276 Chemical Oxygen Demand 18000 J ug/L NE 50000 11000 1 SM5220 D 10/19/20 11:56SLS POJ0361 Cyanide <14 ug/L 10 25 14 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron 360 HT ug/L NE 200 46 1 SM3500-Fe B 10/13/20 11:14 ENM POJ0199 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02ENM POJ0337 Total Alkalinity to pH 4.5 250000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD A 4,4'-DDD <0.026 ug/L 0.1 0.10 0.026 1 8081 B 10/16/20 8:41 NMB POJ0214 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/16/20 8:41 NMB POJ0214 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/16/20 8:41 NMB POJ0214 Aldrin <0.015 ug/L 0.05 0.050 0.015 1 8081 B 10/16/20 8:41 NMB POJ0214 alpha-BHC <0.0063 ug/L 0.05 0.050 0.0063 1 8081 B 10/16/20 8:41 NMB POJ0214 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/16/20 8:41 NMB POJ0214 beta-BHC <0.011 ug/L 0.05 0.050 0.011 1 8081 B 10/16/20 8:41 NMB POJ0214 Chlordane <0.18 ug/L 0.5 0.50 0.18 1 8081 B 10/16/20 8:41 NMB POJ0214 delta-BHC <0.0082 ug/L 0.05 0.050 0.0082 1 8081 B 10/16/20 8:41 NMB POJ0214 Dieldrin <0.014 ug/L 0.002 0.050 0.014 1 8081 B 10/16/20 8:41 NMB POJ0214 Endosulfan 1 <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:41 NMB POJ0214 Endosulfan 11 <0.012 ug/L 0.1 0.050 0.012 1 8081 B 10/16/20 8:41 NMB POJ0214 Endosulfan Sulfate <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:41 NMB POJ0214 Endrin <0.014 ug/L 0.1 0.050 0.014 1 8081 B 10/16/20 8:41 NMB POJ0214 Endrin Aldehyde <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/16/20 8:41 NMB POJ0214 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/16/20 8:41 NMB POJ0214 gamma-BHC <0.0061 ug/L 0.05 0.050 0.0061 1 8081 B 10/16/20 8:41 NMB POJ0214 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/16/20 8:41 NMB POJ0214 Heptachlor <0.013 ug/L 0.05 0.050 0.013 1 8081 B 10/16/20 8:41 NMB POJ0214 Heptachlor Epoxide <0.022 ug/L 0.075 0.10 0.022 1 8081 B 10/16/20 8:41 NMB POJ0214 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/16/20 8:41 NMB POJ0214 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/16/20 8:41 NMB POJ0214 Surrogate Recovery Control Limits Decachlorobiphenyl 34 % 13-186 Tetrachloro-m-xylene 72 % 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 84 Laboratory Report • � 11 /30/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Polychlorinated Biphenyls (PCBs) by GC/ECD A Aroclor 1016 <0.21 ug/L NE 0.50 0.21 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1232 <0.16 ug/L NE 0.50 0.16 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1242 <0.14 ug/L NE 0.50 0.14 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1248 <0.14 ug/L NE 0.50 0.14 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1254 <0.16 ug/L NE 0.50 0.16 1 8082A 10/16/20 8:41 NMB POJ0214 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/16/20 8:41 NMB POJ0214 Surrogate Recovery Control Limits Tetrachloro-m-xylene 72 % 30-161 Decachlorobiphenyl 35 % 32-178 Total Metals Mercury 0.53 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:06EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 16:15JAB POJ0239 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/23/20 16:15JAB POJ0239 Barium 390 ug/L 100 2.0 0.81 1 6020B 10/23/20 16:15JAB POJ0239 Beryllium <0.19 CCV ug/L 1 1.0 0.19 1 6020B 10/23/20 16:15JAB POJ0239 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/23/20 16:15JAB POJ0239 Chromium 0.90 J ug/L 10 2.0 0.79 1 6020B 10/23/20 16:15JAB POJ0239 Cobalt 1.4 J ug/L 10 2.0 0.52 1 6020B 10/23/20 16:15JAB POJ0239 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/23/20 16:15JAB POJ0239 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/23/20 16:15JAB POJ0239 Nickel 7.1 ug/L 50 3.0 0.51 1 6020B 10/23/20 16:15JAB POJ0239 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 16:15JAB POJ0239 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 18:06JAB POJ0490 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/23/20 16:15JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 16:15JAB POJ0239 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 16:15JAB POJ0239 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/23/20 16:15JAB POJ0239 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 18:35JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 18:35JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 18:35JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 18:35JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 18:35JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 18:35JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 18:35JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 18:35JLB POJ0321 1,2,4-Trichlorobenzene 0.23 J ug/L 10 1.0 0.13 1 8260D 10/21/20 18:35JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 18:35JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 18:35JLB POJ0321 1,2-Dichlorobenzene 0.50 ug/L 5 0.50 0.076 1 8260D 10/21/20 18:35JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 18:35JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 18:35JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 18:35JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 18:35JLB POJ0321 1,4-Dichlorobenzene 6.8 ug/L 1 0.50 0.050 1 8260D 10/21/20 18:35JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 18:35JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 18:35JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 18:35JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 18:35JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 18:35JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 18:35JLB POJ0321 Benzene 1.4 ug/L 1 0.50 0.048 1 8260D 10/21/20 18:35JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 18:35JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 18:35JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 18:35JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 18:35JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 18:35JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 18:35JLB POJ0321 Chlorobenzene 6.1 ug/L 3 0.50 0.062 1 8260D 10/21/20 18:35JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 18:35JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 18:35JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 18:35JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 18:35JLB POJ0321 cis-1,2-Dichloroethylene 2.6 ug/L 2 0.50 0.056 1 8260D 10/21/20 18:35JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 18:35JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 18:35JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 18:35JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 18:35JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 18:35JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 18:35JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 18:35JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 18:35JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 84 . Laboratory Report • � Waynt.. 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID m,p-Xylenes 0.42 J ug/L NE 1.0 0.12 1 8260D 10/21/20 18:35JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 18:35JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 18:35JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 18:35JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 18:35JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 18:35JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 18:35JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 18:35JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 18:35JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 18:35JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 18:35JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 18:35JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 18:35JLB POJ0321 Tetrahydrofuran 1.6 J ug/L NE 10 1.1 1 8260D 10/21/20 18:35JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 18:35JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 18:35JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 18:35JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 18:35JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 18:35JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 18:35JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 18:35JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 18:35JLB POJ0321 Xylenes, total 0.42 J ug/L 5 1.5 0.15 1 8260D 10/21/20 18:35JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 17 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 21:13ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 1,4-Naphthoquinone <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 1-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 2-Acetylaminofluorene <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 2-Naphthylamine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 3-Methylcholanthrene <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 4-Aminobiphenyl <10 Ng/L 10 10 1 8270D 10/20/20 18:07 BGV L517325 5-Nitro-o-toluidine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 7,12-D1methyl benz(a)anthrace ne <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Diallate <10 Ng/L 10 10 1 8270D 10/20/20 18:07 BGV L517325 Hexachloropropene <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Isosafrole <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Kepone <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Methapyrilene <10 Ng/L 20 10 1 8270D 10/20/20 18:07BGV L517325 N-Nitrosomethylethyl amine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 N-Nitrosopiperidine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 N-Nitrosopyrrolidine <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 o-Toluidine <10 Ng/L 10 10 1 8270D 10/20/20 18:07 BGV L517325 p-Dimethylaminoazobenzene <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 p-Phenylenediamine <10 L pg/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Pronamide <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Safrole <10 Ng/L 10 10 1 8270D 10/20/20 18:07BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/20/20 23:25VIC L517362 2,4,5-TP (Silvex) <0.01634 Ng/L 0.1 0.01634 1 8151A 10/20/20 23:25VIC L517362 2,4-D <0.2078 Ng/L 0.25 0.2078 1 8151A 10/20/20 23:25VIC L517362 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/20/20 23:25VIC L517362 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/20/20 23:25VIC L517362 Dicamba <0.057 Ng/L 0.1 0.057 1 8151A 10/20/20 23:25VIC L517362 Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/20/20 23:25VIC L517362 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/20/20 23:25VIC L517362 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/20/20 23:25VIC L517362 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/20/20 23:25VIC L517362 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/20/20 23:25VIC L517362 Surrogate Recovery Control Limits DCAA 51.2 % 20-150 Semivolatile Organic Compounds - GUMS 1,2,4,5-Tetrachlorobenzene <0.317 Ng/L 5 0.317 1 8270D 10/19/20 19:30CCB L517230 1,2,4-Trichlorobenzene <0.482 Ng/L 5 0.482 1 8270D 10/19/20 19:30CCB L517230 1,2-Dichlorobenzene <0.629 Ng/L 5 0.629 1 8270D 10/19/20 19:30CCB L517230 1,3-Dichlorobenzene <0.491 Ng/L 5 0.491 1 8270D 10/19/20 19:30CCB L517230 1,4-Dichlorobenzene 2.66 j Ng/L 5 0.58 1 8270D 10/19/20 19:30CCB L517230 2,3,4,6-Tetrachlorophenol <0.355 Ng/L 5 0.355 1 8270D 10/19/20 19:30CCB L517230 2,4,5-Trichlorophenol <0.35 Ng/L 5 0.35 1 8270D 10/19/20 19:30CCB L517230 2,4,6-Trichlorophenol <0.344 Ng/L 5 0.344 1 8270D 10/19/20 19:30CCB L517230 2,4-Dichlorophenol <1.52 Ng/L 5 1.52 1 8270D 10/19/20 19:30CCB L517230 2,4-Dimethylphenol <0.674 Ng/L 5 0.674 1 8270D 10/19/20 19:30CCB L517230 2,4-Dinitrophenol <4.85 Ng/L 10 4.85 1 8270D 10/19/20 19:30CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 84 ® Laboratory Report IL AL i • . 11 /30/2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 2,4-Dinitrotoluene <0.403 pg/L 5 0.403 1 8270D 10/19/20 19:30CCB L517230 2,6-Dichlorophenol <0.703 pg/L 5 0.703 1 8270D 10/19/20 19:30CCB L517230 2,6-Dinitrotoluene <0.413 pg/L 5 0.413 1 8270D 10/19/20 19:30CCB L517230 2-Chloronaphthalene <0.476 pg/L 5 0.476 1 8270D 10/19/20 19:30CCB L517230 2-Chlorophenol <0.736 pg/L 5 0.736 1 8270D 10/19/20 19:30CCB L517230 2-Methyl naphthalene <0.485 pg/L 2 0.485 1 8270D 10/19/20 19:30CCB L517230 2-Methylphenol <0.721 pg/L 5 0.721 1 8270D 10/19/20 19:30CCB L517230 2-Nitroaniline <0.574 pg/L 5 0.574 1 8270D 10/19/20 19:30CCB L517230 2-Nitrophenol <0.606 pg/L 5 0.606 1 8270D 10/19/20 19:30CCB L517230 3&4 Methylphenol <0.691 pg/L 5 0.691 1 8270D 10/19/20 19:30CCB L517230 3,3' Dimethylbenzidine <1.88 pg/L 10 1.88 1 8270D 10/19/20 19:30CCB L517230 3,3'-Dichlorobenzidine <3.74 pg/L 10 3.74 1 8270D 10/19/20 19:30CCB L517230 3-Nitroaniline <1.53 pg/L 10 1.53 1 8270D 10/19/20 19:30CCB L517230 4,6-Dinitro-2-methylphenol <3.47 pg/L 10 3.47 1 8270D 10/19/20 19:30CCB L517230 4-Bromophenyl phenyl ether <0.5 pg/L 5 0.5 1 8270D 10/19/20 19:30CCB L517230 4-Chloro-3-methylphenol <0.503 pg/L 5 0.503 1 8270D 10/19/20 19:30CCB L517230 4-Chloroaniline <0.526 pg/L 5 0.526 1 8270D 10/19/20 19:30CCB L517230 4-Chlorophenyl phenyl ether <0.479 pg/L 5 0.479 1 8270D 10/19/20 19:30CCB L517230 4-Nitroaniline <0.74 pg/L 5 0.74 1 8270D 10/19/20 19:30CCB L517230 4-Nitrophenol <1.39 pg/L 10 1.39 1 8270D 10/19/20 19:30CCB L517230 Acenaphthene <0.422 pg/L 2 0.422 1 8270D 10/19/20 19:30CCB L517230 Acenaphthylene <0.429 pg/L 2 0.429 1 8270D 10/19/20 19:30CCB L517230 Acetophenone <0.686 pg/L 5 0.686 1 8270D 10/19/20 19:30CCB L517230 Aniline <0.316 pg/L 5 0.316 1 8270D 10/19/20 19:30CCB L517230 Anthracene <0.467 pg/L 2 0.467 1 8270D 10/19/20 19:30CCB L517230 Benzidine <0.689 pg/L 20 0.689 1 8270D 10/19/20 19:30CCB L517230 Benzo(a)anthracene <0.427 pg/L 2 0.427 1 8270D 10/19/20 19:30CCB L517230 Benzo(a)pyrene <1 pg/L 2 1 1 8270D 10/19/20 19:30CCB L517230 Benzo(b)fluoranthene <0.941 pg/L 2 0.941 1 8270D 10/19/20 19:30CCB L517230 Benzo(q,h,i)perylene <1.36 pg/L 2 1.36 1 8270D 10/19/20 19:30CCB L517230 Benzo(k)fluoranthene <0.752 pg/L 2 0.752 1 8270D 10/19/20 19:30CCB L517230 Benzoic Acid <5 pg/L 10 5 1 8270D 10/19/20 19:30CCB L517230 Benzyl alcohol <3.01 pg/L 10 3.01 1 8270D 10/19/20 19:30CCB L517230 Bis(2-Chloroethoxy)methane <0.433 pg/L 5 0.433 1 8270D 10/19/20 19:30CCB L517230 Bis(2-Chloroethyl)ether <0.447 pg/L 5 0.447 1 8270D 10/19/20 19:30CCB L517230 Bis(2-Chloroisopropyl)ether <0.546 pg/L 5 0.546 1 8270D 10/19/20 19:30CCB L517230 Bis(2-ethylhexyl)phthalate <3.66 pg/L 5 3.66 1 8270D 10/19/20 19:30CCB L517230 Butyl benzyl phthalate <4.59 pg/L 5 4.59 1 8270D 10/19/20 19:30CCB L517230 Carbazole <0.476 pg/L 5 0.476 1 8270D 10/19/20 19:30CCB L517230 Chrysene <0.731 pg/L 2 0.731 1 8270D 10/19/20 19:30CCB L517230 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 84 . Laboratory Report • � Waynt.� 11 /30/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-07-20201012 Attn: Alec Macbeth Sample ID: 0100161-03 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 10:57 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID D1benz(a,h)anthrace ne <0.252 Ng/L 2 0.252 1 8270D 10/19/20 19:30CCB L517230 Dibenzofuran <0.423 Ng/L 5 0.423 1 8270D 10/19/20 19:30CCB L517230 Diethyl phthalate <0.585 Ng/L 5 0.585 1 8270D 10/19/20 19:30CCB L517230 Dimethyl phthalate <0.51 Ng/L 5 0.51 1 8270D 10/19/20 19:30CCB L517230 Di-n-butyl phthalate <1.58 Ng/L 5 1.58 1 8270D 10/19/20 19:30CCB L517230 Di-n-Octyl Phthalate <1.72 Ng/L 5 1.72 1 8270D 10/19/20 19:30CCB L517230 Fluoranthene <0.406 Ng/L 2 0.406 1 8270D 10/19/20 19:30CCB L517230 Fluorene <0.444 Ng/L 2 0.444 1 8270D 10/19/20 19:30CCB L517230 Hexachlorobenzene <2.57 Ng/L 5 2.57 1 8270D 10/19/20 19:30CCB L517230 Hexachlorobutadiene <0.405 Ng/L 5 0.405 1 8270D 10/19/20 19:30CCB L517230 Hexachlorocyclopentadiene <2.34 Ng/L 5 2.34 1 8270D 10/19/20 19:30CCB L517230 Hexachloroethane <0.277 pg/L 5 0.277 1 8270D 10/19/20 19:30CCB L517230 Indeno(1,2,3-cd)pyrene <1.01 Ng/L 2 1.01 1 8270D 10/19/20 19:30CCB L517230 Isophorone <0.36 Ng/L 5 0.36 1 8270D 10/19/20 19:30CCB L517230 Naphthalene <0.484 Ng/L 2 0.484 1 8270D 10/19/20 19:30CCB L517230 Nitrobenzene <0.531 Ng/L 5 0.531 1 8270D 10/19/20 19:30CCB L517230 N-Nitrosodiethylamine <0.4 Ng/L 5 0.4 1 8270D 10/19/20 19:30CCB L517230 N-Nitrosodimethylamine <0.249 Ng/L 5 0.249 1 8270D 10/19/20 19:30CCB L517230 N-Nitroso-di-n-butylamine <0.752 Ng/L 5 0.752 1 8270D 10/19/20 19:30CCB L517230 N-Nitroso-di-n-propylamine <0.334 pg/L 5 0.334 1 8270D 10/19/20 19:30CCB L517230 N-Nitrosodiphenylamine <0.783 pg/L 10 0.783 1 8270D 10/19/20 19:30CCB L517230 Pentachlorophenol <2.45 Ng/L 10 2.45 1 8270D 10/19/20 19:30CCB L517230 Phenanthrene <0.464 Ng/L 2 0.464 1 8270D 10/19/20 19:30CCB L517230 Phenol <0.389 Ng/L 5 0.389 1 8270D 10/19/20 19:30CCB L517230 Pyrene <1.04 pg/L 2 1.04 1 8270D 10/19/20 19:30CCB L517230 Pyridine <0.678 pg/L 10 0.678 1 8270D 10/19/20 19:30CCB L517230 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 47.4 % 39-110 2-Fluorobiphenyl 43.4 % 24-93 2-Fluorophenol 25.1 % 10-44 4-Terphenyl-d14 103 % 35-126 Nitrobenzene-d5 46.6 % 20-91 Phenol-d6 17.6 % 7-32 Total Organic Carbon TOC 3.22 mg/L 1 0.498 1 531OC-2011 10/24/20 14:24DDB L518399 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 84 Laboratory Report • � 11 /30/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010120000 Attn: Alec Macbeth Sample ID: 0100161-04 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 00:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 15:45JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 15:45JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 15:45JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 15:45JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 15:45JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 15:45JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 15:45JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 15:45JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 15:45JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 15:45JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 15:45JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 15:45JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 15:45JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 15:45JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 15:45JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 15:45JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 15:45JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 15:45JLB POJ0321 Acetone 3.2 J ug/L 100 5.0 0.31 1 8260D 10/21/20 15:45JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 15:45JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 15:45JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 15:45JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 15:45JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 15:45JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 15:45JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 15:45JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 15:45JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 15:45JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 15:45JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 15:45JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 15:45JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 15:45JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 15:45JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 15:45JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 15:45JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 15:45JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 84 Laboratory Report A i • .0 11 /30/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010120000 Attn: Alec Macbeth Sample ID: 0100161-04 231 Haywood Street Project No.: 50-02 Work Order: 0100161 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/12/20 00:00 Time Submitted: 10/13/20 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 15:45JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 15:45JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 15:45JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 15:45JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 15:45JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 15:45JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 15:45JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 15:45JLB POJ0321 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/21/20 15:45JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 15:45JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 15:45JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 15:45JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 15:45JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 15:45JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 15:45JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 15:45JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 15:45JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 15:45JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 15:45JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 15:45JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 15:45JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 15:45JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 15:45JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 15:45JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 15:45JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 15:45JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 15:45JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 15:45JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 15:45JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 15:45JLB POJ0321 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/21/20 15:45JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 107 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 84 (2) Way po Int ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene 0.290 1.0 ug/L J 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L Acetone BRL 5.0 ug/L Acetonitrile BRL 10 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Allyl Chloride (3-Chloropropylene) BRL 10 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L Chloroprene BRL 10 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 5.0 ug/L Ethyl Methacrylate BRL 10 ug/L Ethylbenzene BRL 0.50 ug/L Hexachlorobutadiene 0.220 2.0 ug/L J Isobutyl alcohol BRL 50 ug/L m,p-Xylenes 0.250 1.0 ug/L J Methacrylonitrile BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 84 Waypoint ' ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared & Analyzed: 10/21/20 Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methyl Methacrylate BRL 10 ug/L Methylene Chloride BRL 1.0 ug/L Naphthalene BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Propionitrile (Ethyl Cyanide) BRL 10 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total 0.250 1.5 ug/L J Surrogate:4-Bromofluorobenzene 50.3 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 53.8 ug/L 50.00 108 75-129 Surrogate: Toluene-d8 49.6 ug/L 50.00 99 77-123 LCS (POJ0321-BS1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.5 0.50 ug/L 20.00 108 79-134 1,1,1-Trichloroethane 21.3 0.50 ug/L 20.00 106 75-136 1,1,2,2-Tetrachloroethane 21.0 0.50 ug/L 20.00 105 62-127 1,1,2-Trichloroethane 21.6 0.50 ug/L 20.00 108 70-140 1,1-Dichloroethane 21.6 0.50 ug/L 20.00 108 78-130 1,1-Dichloroethylene 21.2 0.50 ug/L 20.00 106 70-154 1, 1 -Dichloropropylene 22.0 0.50 ug/L 20.00 110 71-136 1,2,3-Trichloropropane 21.2 1.0 ug/L 20.00 106 71-127 1,2,4-Trichlorobenzene 20.4 1.0 ug/L 20.00 102 66-139 1,2-Dibromo-3-chloropropane 22.9 2.0 ug/L 20.00 114 63-134 1,2-Dibromoethane 21.3 0.50 ug/L 20.00 107 77-135 1,2-Dichlorobenzene 21.3 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 21.6 0.50 ug/L 20.00 108 68-131 1,2-Dichloropropane 21.9 0.50 ug/L 20.00 110 77-130 1,3-Dichlorobenzene 21.5 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 22.0 0.50 ug/L 20.00 110 76-132 1,4-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 75-126 2,2-Dichloropropane 23.8 2.0 ug/L 20.00 119 29-149 Acetone 39.6 5.0 ug/L 40.00 99 40-166 Acetonitrile 19.4 10 ug/L 20.00 97 70-130 Acrolein 45.9 20 ug/L 40.00 115 70-130 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 84 Waypoint ' ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Acrylonitrile 42.3 20 ug/L 40.00 106 81-127 Allyl Chloride (3-Chloropropylene) 19.4 10 ug/L 20.00 97 70-130 Benzene 22.7 0.50 ug/L 20.00 114 77-128 Bromochloromethane 22.1 0.50 ug/L 20.00 110 78-135 Bromodichloromethane 21.7 0.50 ug/L 20.00 108 76-138 Bromoform 22.4 1.0 ug/L 20.00 112 71-135 Bromomethane 21.0 1.0 ug/L 20.00 105 41-168 Carbon disulfide 21.1 5.0 ug/L 20.00 106 59-135 Carbon Tetrachloride 21.7 0.50 ug/L 20.00 109 72-142 Chlorobenzene 22.0 0.50 ug/L 20.00 110 78-119 Chloroethane 21.5 0.50 ug/L 20.00 107 57-142 Chloroform 21.0 0.50 ug/L 20.00 105 77-130 Chloromethane 20.5 0.50 ug/L 20.00 102 47-145 Chloroprene 19.7 10 ug/L 20.00 98 70-130 cis-1,2-Dichloroethylene 22.5 0.50 ug/L 20.00 113 76-141 cis-1,3-Dichloropropylene 22.4 0.50 ug/L 20.00 112 65-140 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 Dibromomethane 21.8 0.50 ug/L 20.00 109 76-138 Dichlorodifluoromethane 25.2 5.0 ug/L 20.00 126 28-163 Ethyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 Ethylbenzene 22.7 0.50 ug/L 20.00 114 80-127 Hexachlorobutadiene 20.1 2.0 ug/L 20.00 100 61-134 Isobutyl alcohol 24.0 50 ug/L 20.00 120 70-130 J m,p-Xylenes 48.4 1.0 ug/L 40.00 121 77-133 Methacrylonitrile 19.5 10 ug/L 20.00 98 70-130 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 114 64-137 Methyl Ethyl Ketone (2-Butanone) 20.2 5.0 ug/L 20.00 101 71-134 Methyl Iodide 23.5 5.0 ug/L 20.00 118 70-130 Methyl Isobutyl Ketone 23.8 5.0 ug/L 20.00 119 69-134 Methyl Methacrylate 20.3 10 ug/L 20.00 102 70-130 Methylene Chloride 20.7 1.0 ug/L 20.00 103 73-131 Naphthalene 21.0 1.0 ug/L 20.00 105 64-136 o-Xylene 22.8 0.50 ug/L 20.00 114 78-128 Propionitrile (Ethyl Cyanide) 22.1 10 ug/L 20.00 110 70-130 Styrene 23.3 0.50 ug/L 20.00 116 78-129 Tetrachloroethylene 21.2 0.50 ug/L 20.00 106 80-129 Tetrahydrofuran 22.3 10 ug/L 20.00 112 70-130 Toluene 22.5 0.50 ug/L 20.00 113 76-131 trans- 1,2-Dichloroethylene 21.6 0.50 ug/L 20.00 108 76-135 trans- 1,3-Dichloropropylene 23.1 0.50 ug/L 20.00 116 67-140 trans-1,4-Dichloro-2-butene 21.1 10 ug/L 20.00 105 70-130 Trichloroethylene 21.3 0.50 ug/L 20.00 107 77-133 Trichlorofluoromethane 22.6 0.50 ug/L 20.00 113 62-148 Vinyl acetate 26.3 2.0 ug/L 20.00 131 34-167 Vinyl chloride 22.4 0.50 ug/L 20.00 112 57-141 Xylenes, total 71.2 1.5 ug/L 60.00 119 77-133 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 84 Waypoint ' ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Surrogate:4-Bromofluorobenzene 48.4 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.3 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.0 ug/L 50.00 100 77-123 LCS Dup (POJ0321-BSDI) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.4 0.50 ug/L 20.00 107 79-134 0.6 20 1,1,1-Trichloroethane 20.5 0.50 ug/L 20.00 102 75-136 4 20 1,1,2,2-Tetrachloroethane 20.7 0.50 ug/L 20.00 103 62-127 2 20 1,1,2-Trichloroethane 21.4 0.50 ug/L 20.00 107 70-140 1 20 1,1-Dichloroethane 20.4 0.50 ug/L 20.00 102 78-130 5 20 1,1-Dichloroethylene 20.2 0.50 ug/L 20.00 101 70-154 5 20 1, 1 -Dichloropropylene 21.0 0.50 ug/L 20.00 105 71-136 5 20 1,2,3-Trichloropropane 21.1 1.0 ug/L 20.00 106 71-127 0.6 20 1,2,4-Trichlorobenzene 20.7 1.0 ug/L 20.00 103 66-139 1 20 1,2-Dibromo-3-chloropropane 21.7 2.0 ug/L 20.00 108 63-134 5 20 1,2-Dibromoethane 20.9 0.50 ug/L 20.00 104 77-135 2 20 1,2-Dichlorobenzene 20.5 0.50 ug/L 20.00 103 78-128 4 20 1,2-Dichloroethane 21.1 0.50 ug/L 20.00 106 68-131 2 20 1,2-Dichloropropane 21.3 0.50 ug/L 20.00 107 77-130 3 20 1,3-Dichlorobenzene 21.1 0.50 ug/L 20.00 105 77-125 2 20 1,3-Dichloropropane 21.3 0.50 ug/L 20.00 106 76-132 3 20 1,4-Dichlorobenzene 20.4 0.50 ug/L 20.00 102 75-126 2 20 2,2-Dichloropropane 21.4 2.0 ug/L 20.00 107 29-149 11 20 Acetone 39.2 5.0 ug/L 40.00 98 40-166 1 20 Acetonitrile 21.5 10 ug/L 20.00 107 70-130 10 20 Acrolein 46.1 20 ug/L 40.00 115 70-130 0.5 20 Acrylonitrile 42.2 20 ug/L 40.00 105 81-127 0.4 20 Allyl Chloride (3-Chloropropylene) 18.8 10 ug/L 20.00 94 70-130 3 20 Benzene 21.8 0.50 ug/L 20.00 109 77-128 4 20 Bromochloromethane 20.5 0.50 ug/L 20.00 103 78-135 7 20 Bromodichloromethane 20.8 0.50 ug/L 20.00 104 76-138 4 20 Bromoform 21.5 1.0 ug/L 20.00 107 71-135 4 20 Bromomethane 19.7 1.0 ug/L 20.00 99 41-168 6 20 Carbon disulfide 20.5 5.0 ug/L 20.00 102 59-135 3 20 Carbon Tetrachloride 20.9 0.50 ug/L 20.00 105 72-142 4 20 Chlorobenzene 21.2 0.50 ug/L 20.00 106 78-119 4 20 Chloroethane 20.2 0.50 ug/L 20.00 101 57-142 6 20 Chloroform 20.6 0.50 ug/L 20.00 103 77-130 2 20 Chloromethane 20.0 0.50 ug/L 20.00 100 47-145 2 20 Chloroprene 18.8 10 ug/L 20.00 94 70-130 5 20 cis-1,2-Dichloroethylene 20.4 0.50 ug/L 20.00 102 76-141 10 20 cis-1,3-Dichloropropylene 21.9 0.50 ug/L 20.00 110 65-140 2 20 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 0.1 20 Dibromomethane 21.3 0.50 ug/L 20.00 107 76-138 2 20 Dichlorodifluoromethane 24.2 5.0 ug/L 20.00 121 28-163 4 20 Ethyl Methacrylate 19.4 10 ug/L 20.00 97 70-130 1 20 Ethylbenzene 22.0 0.50 ug/L 20.00 110 80-127 3 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS Dup (POJ0321-BSD1) Prepared &Analyzed: 10/21/20 Hexachlorobutadiene 19.9 2.0 ug/L 20.00 99 61-134 1 20 Isobutyl alcohol 21.3 50 ug/L 20.00 106 70-130 12 20 1 m,p-Xylenes 47.1 1.0 ug/L 40.00 118 77-133 3 20 Methacrylonitrile 19.2 10 ug/L 20.00 96 70-130 2 20 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 113 64-137 0.3 20 Methyl Ethyl Ketone (2-Butanone) 19.7 5.0 ug/L 20.00 98 71-134 3 20 Methyl Iodide 22.6 5.0 ug/L 20.00 113 70-130 4 20 Methyl Isobutyl Ketone 22.7 5.0 ug/L 20.00 113 69-134 5 20 Methyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 3 20 Methylene Chloride 19.8 1.0 ug/L 20.00 99 73-131 5 20 Naphthalene 21.4 1.0 ug/L 20.00 107 64-136 2 20 o-Xylene 22.3 0.50 ug/L 20.00 112 78-128 2 20 Propionitrile (Ethyl Cyanide) 19.9 10 ug/L 20.00 100 70-130 10 20 Styrene 22.7 0.50 ug/L 20.00 113 78-129 3 20 Tetrachloroethylene 20.4 0.50 ug/L 20.00 102 80-129 4 20 Tetrahydrofuran 22.0 10 ug/L 20.00 110 70-130 2 20 Toluene 21.6 0.50 ug/L 20.00 108 76-131 4 20 trans-1,2-Dichloroethylene 20.6 0.50 ug/L 20.00 103 76-135 5 20 trans-1,3-Dichloropropylene 22.2 0.50 ug/L 20.00 ill 67-140 4 20 trans-1,4-Dichloro-2-butene 19.6 10 ug/L 20.00 98 70-130 7 20 Trichloroethylene 21.2 0.50 ug/L 20.00 106 77-133 0.7 20 Trichlorofluoromethane 21.4 0.50 ug/L 20.00 107 62-148 6 20 Vinyl acetate 25.7 2.0 ug/L 20.00 129 34-167 2 20 Vinyl chloride 21.2 0.50 ug/L 20.00 106 57-141 5 20 Xylenes, total 69.4 1.5 ug/L 60.00 116 77-133 2 20 Surrogate:4-Bromofluorobenzene 48.3 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.5 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.3 ug/L 50.00 101 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0316 - 5030B Blank (POJ0316-BLK1) Prepared & Analyzed: 10/16/20 1,4-Dioxane BRL 2.0 ug/L LCS (POJ0316-BS1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.5 2.0 ug/L 50.00 95 55-145 LCS Dup (POJ0316-BSD1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.1 2.0 ug/L 50.00 94 55-145 0.7 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC Blank (POJ0214-BLK1) Prepared & Analyzed: 10/14/20 4,4'-DDD BRL 0.10 ug/L 4,4'-DDE BRL 0.10 ug/L 4,4'-DDT BRL 0.10 ug/L Aldrin BRL 0.050 ug/L alpha-BHC BRL 0.050 ug/L cis -Chlordane BRL 0.10 ug/L beta-BHC BRL 0.050 ug/L Chlordane BRL 0.50 ug/L delta-BHC 0.0100 0.050 ug/L J Dieldrin BRL 0.050 ug/L Endosulfan I BRL 0.050 ug/L Endosulfan II BRL 0.050 ug/L Endosulfan Sulfate BRL 0.050 ug/L Endrin BRL 0.050 ug/L Endrin Aldehyde BRL 0.050 ug/L Endrin Ketone BRL 0.10 ug/L gamma-BHC BRL 0.050 ug/L trans -Chlordane BRL 0.10 ug/L Heptachlor BRL 0.050 ug/L Heptachlor Epoxide BRL 0.10 ug/L Methoxychlor BRL 0.10 ug/L Toxaphene BRL 1.0 ug/L Surrogate: Decachlorobiphenyl 0.760 ug/L 1.000 76 13-186 Surrogate: Tetrachloro-m-xylene 0.530 ug/L 1.000 53 40-134 LCS (POJ0214-BS1) Prepared &Analyzed: 10/14/20 4,4'-DDD 0.730 0.10 ug/L 1.000 73 56-143 4,4'-DDE 0.710 0.10 ug/L 1.000 71 57-135 4,4'-DDT 0.770 0.10 ug/L 1.000 77 51-143 Aldrin 0.630 0.050 ug/L 1.000 63 45-134 alpha-BHC 0.710 0.050 ug/L 1.000 71 54-138 cis -Chlordane 0.690 0.10 ug/L 1.000 69 60-129 beta-BHC 0.670 0.050 ug/L 1.000 67 56-136 delta-BHC 0.700 0.050 ug/L 1.000 70 52-142 Dieldrin 0.720 0.050 ug/L 1.000 72 60-136 Endosulfan 1 0.700 0.050 ug/L 1.000 70 62-126 Endosulfan II 0.730 0.050 ug/L 1.000 73 52-135 Endosulfan Sulfate 0.680 0.050 ug/L 1.000 68 62-133 Endrin 0.800 0.050 ug/L 1.000 80 60-138 Endrin Aldehyde 0.670 0.050 ug/L 1.000 67 51-132 Endrin Ketone 0.710 0.10 ug/L 1.000 71 58-134 gamma-BHC 0.690 0.050 ug/L 1.000 69 59-134 trans -Chlordane 0.650 0.10 ug/L 1.000 65 56-136 Heptachlor 0.670 0.050 ug/L 1.000 67 54-130 Heptachlor Epoxide 0.700 0.10 ug/L 1.000 70 61-133 Methoxychlor 0.760 0.10 ug/L 1.000 76 54-145 Surrogate: Decachlorobiphenyl 0.630 ug/L 1.000 63 13-186 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC LCS (POJ0214-BS1) Prepared &Analyzed: 10/14/20 Surrogate: Tetrachloro-m-xylene 0.770 ug/L 1.000 77 40-134 LCS (POJ0214-BS2) Prepared & Analyzed: 10/14/20 Chlordane 8.90 0.50 ug/L 10.00 89 62-140 Surrogate: Decachlorobiphenyl 0.690 ug/L 1.000 69 13-186 Surrogate: Tetrachloro-m-xylene 0.730 ug/L 1.000 73 40-134 LCS (POJ0214-BS3) Prepared & Analyzed: 10/14/20 Toxaphene 7.66 1.0 ug/L 10.00 77 33-134 Surrogate: Decachlorobiphenyl 0.500 ug/L 1.000 50 13-186 Surrogate: Tetrachloro-m-xylene 0.610 ug/L 1.000 61 40-134 LCS Dup (POJ0214-BSD1) Prepared &Analyzed: 10/14/20 4,4'-DDD 0.730 0.10 ug/L 1.000 73 56-143 0 30 4,4'-DDE 0.710 0.10 ug/L 1.000 71 57-135 0 30 4,4'-DDT 0.770 0.10 ug/L 1.000 77 51-143 0 30 Aldrin 0.630 0.050 ug/L 1.000 63 45-134 0 30 alpha-BHC 0.700 0.050 ug/L 1.000 70 54-138 1 30 cis -Chlordane 0.680 0.10 ug/L 1.000 68 60-129 1 30 beta-BHC 0.650 0.050 ug/L 1.000 65 56-136 3 30 delta-BHC 0.690 0.050 ug/L 1.000 69 52-142 1 30 Dieldrin 0.720 0.050 ug/L 1.000 72 60-136 0 30 Endosulfan 1 0.700 0.050 ug/L 1.000 70 62-126 0 30 Endosulfan 11 0.730 0.050 ug/L 1.000 73 52-135 0 30 Endosulfan Sulfate 0.680 0.050 ug/L 1.000 68 62-133 0 30 Endrin 0.800 0.050 ug/L 1.000 80 60-138 0 30 Endrin Aldehyde 0.670 0.050 ug/L 1.000 67 51-132 0 30 Endrin Ketone 0.720 0.10 ug/L 1.000 72 58-134 1 30 gamma-BHC 0.690 0.050 ug/L 1.000 69 59-134 0 30 trans -Chlordane 0.650 0.10 ug/L 1.000 65 56-136 0 30 Heptachlor 0.670 0.050 ug/L 1.000 67 54-130 0 30 Heptachlor Epoxide 0.690 0.10 ug/L 1.000 69 61-133 1 30 Methoxychlor 0.760 0.10 ug/L 1.000 76 54-145 0 30 Surrogate: Decachlorobiphenyl 0.650 ug/L 1.000 65 13-186 Surrogate: Tetrachloro-m-xylene 0.730 ug/L 1.000 73 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC Matrix Spike (POJ0214-MS1) Source: 0100161-01 Prepared & Analyzed: 10/14/20 4,4'-DDD BRL 0.20 ug/L BRL 56-143 4,4'-DDE BRL 0.20 ug/L BRL 57-135 4,4'-DDT BRL 0.20 ug/L BRL 51-143 Aldrin BRL 0.10 ug/L BRL 45-134 alpha-BHC BRL 0.10 ug/L BRL 54-138 cis -Chlordane BRL 0.20 ug/L BRL 60-129 beta-BHC BRL 0.10 ug/L BRL 56-136 Chlordane BRL 1.0 ug/L BRL 62-140 delta-BHC BRL 0.10 ug/L BRL 52-142 Dieldrin BRL 0.10 ug/L BRL 60-136 Endosulfan I BRL 0.10 ug/L BRL 62-126 Endosulfan II BRL 0.10 ug/L BRL 52-135 Endosulfan Sulfate BRL 0.10 ug/L BRL 62-133 Endrin BRL 0.10 ug/L BRL 60-138 Endrin Aldehyde BRL 0.10 ug/L BRL 51-132 Endrin Ketone BRL 0.20 ug/L BRL 58-134 gamma-BHC BRL 0.10 ug/L BRL 59-134 trans -Chlordane BRL 0.20 ug/L BRL 56-136 Heptachlor BRL 0.10 ug/L BRL 54-130 Heptachlor Epoxide BRL 0.20 ug/L BRL 61-133 Methoxychlor BRL 0.20 ug/L BRL 54-145 Toxaphene BRL 2.0 ug/L BRL 33-134 Surrogate: Decachlorobiphenyl 1.52 ug/L 2.000 76 13-186 Surrogate: Tetrachloro-m-xylene 1.32 ug/L 2.000 66 40-134 Matrix Spike Dup (POJ0214-MSD1) Source: 0100161-01 Prepared & Analyzed: 10/14/20 4,4'-DDD BRL 0.24 ug/L BRL 56-143 30 4,4'-DDE BRL 0.24 ug/L BRL 57-135 30 4,4'-DDT BRL 0.24 ug/L BRL 51-143 30 Aldrin BRL 0.12 ug/L BRL 45-134 30 alpha-BHC BRL 0.12 ug/L BRL 54-138 30 cis -Chlordane BRL 0.24 ug/L BRL 60-129 30 beta-BHC BRL 0.12 ug/L BRL 56-136 30 Chlordane BRL 1.2 ug/L BRL 62-140 30 delta-BHC BRL 0.12 ug/L BRL 52-142 30 Dieldrin BRL 0.12 ug/L BRL 60-136 30 Endosulfan I BRL 0.12 ug/L BRL 62-126 30 Endosulfan II BRL 0.12 ug/L BRL 52-135 30 Endosulfan Sulfate BRL 0.12 ug/L BRL 62-133 30 Endrin BRL 0.12 ug/L BRL 60-138 30 Endrin Aldehyde BRL 0.12 ug/L BRL 51-132 30 Endrin Ketone BRL 0.24 ug/L BRL 58-134 30 gamma-BHC BRL 0.12 ug/L BRL 59-134 30 trans -Chlordane BRL 0.24 ug/L BRL 56-136 30 Heptachlor BRL 0.12 ug/L BRL 54-130 30 Heptachlor Epoxide BRL 0.24 ug/L BRL 61-133 30 Methoxychlor BRL 0.24 ug/L BRL 54-145 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC Matrix Spike Dup (POJ0214-MSD1) Source: 0100161-01 Prepared & Analyzed: 10/14/20 Toxaphene BRL 2.4 ug/L BRL 33-134 30 Surrogate: Decachlorobiphenyl 1.69 ug/L 2.381 71 13-186 Surrogate: Tetrachloro-m-xylene 1.55 ug/L 2.381 65 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC Blank (POJ0214-BLK1) Prepared & Analyzed: 10/14/20 Aroclor 1016 BRL 0.50 ug/L Aroclor 1221 BRL 1.0 ug/L Aroclor 1232 BRL 0.50 ug/L Aroclor 1242 BRL 0.50 ug/L Aroclor 1248 BRL 0.50 ug/L Aroclor 1254 BRL 0.50 ug/L Aroclor 1260 BRL 1.0 ug/L Surrogate: Tetrachloro-m-xylene 0.510 ug/L 1.000 51 30-161 Surrogate: Decachlorobiphenyl 0.790 ug/L 1.000 79 32-178 LCS (POJ0214-BS4) Prepared & Analyzed: 10/14/20 Aroclor 1016 6.83 0.50 ug/L 10.00 68 50-114 Aroclor 1221 BRL 1.0 ug/L 15-178 Aroclor 1232 BRL 0.50 ug/L 10-215 Aroclor 1242 BRL 0.50 ug/L 39-150 Aroclor 1248 BRL 0.50 ug/L 38-158 Aroclor 1254 BRL 0.50 ug/L 29-131 Aroclor 1260 7.90 1.0 ug/L 10.00 79 10-127 Surrogate: Tetrachloro-m-xylene 0.510 ug/L 1.000 51 30-161 Surrogate: Decachlorobiphenyl 0.800 ug/L 1.000 80 32-178 Matrix Spike (POJ0214-MS1) Source: 0100161-01 Prepared & Analyzed: 10/14/20 Aroclor 1016 12.7 1.0 ug/L 20.00 BRL 63 50-114 Aroclor 1221 BRL 2.0 ug/L BRL 15-178 Aroclor 1232 BRL 1.0 ug/L BRL 10-215 Aroclor 1242 BRL 1.0 ug/L BRL 39-150 Aroclor 1248 BRL 1.0 ug/L BRL 38-158 Aroclor 1254 BRL 1.0 ug/L BRL 29-131 Aroclor 1260 14.3 2.0 ug/L 20.00 BRL 72 10-127 Surrogate: Tetrachloro-m-xylene 1.32 ug/L 2.000 66 30-161 Surrogate: Decachlorobiphenyl 1.52 ug/L 2.000 76 32-178 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Asheville, NC 28801 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0214 - 3510C GC Matrix Spike Dup (POJ0214-MSD1) Source: 0100161-01 Prepared & Analyzed: 10/14/20 Aroclor 1016 16.0 1.2 ug/L 23.81 BRL 67 50-114 23 50 Aroclor 1221 BRL 2.4 ug/L BRL 15-178 50 Aroclor 1232 BRL 1.2 ug/L BRL 10-215 50 Aroclor 1242 BRL 1.2 ug/L BRL 39-150 50 Aroclor 1248 BRL 1.2 ug/L BRL 38-158 50 Aroclor 1254 BRL 1.2 ug/L BRL 29-131 50 Aroclor 1260 17.7 2.4 ug/L 23.81 BRL 74 10-127 21 50 Surrogate: Tetrachloro-m-xylene 1.55 ug/L 2.381 65 30-161 Surrogate: Decachlorobiphenyl 1.69 ug/L 2.381 71 32-178 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0239 - 3005A Blank (POJ0239-BLK1) Prepared: 10/15/20 Analyzed: 10/23/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 2.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Thallium BRL 2.0 ug/L Tin BRL 5.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (POJ0239-BS1) Prepared: 10/15/20 Analyzed: 10/23/20 Antimony 103 2.0 ug/L 100.0 103 80-120 Arsenic 96.8 1.0 ug/L 100.0 97 80-120 Barium 99.1 2.0 ug/L 100.0 99 80-120 Beryllium 93.3 1.0 ug/L 100.0 93 80-120 Cadmium 98.1 1.0 ug/L 100.0 98 80-120 Chromium 96.2 2.0 ug/L 100.0 96 80-120 Cobalt 100 2.0 ug/L 100.0 100 80-120 Copper 97.5 10 ug/L 100.0 97 80-120 Lead 98.4 1.0 ug/L 100.0 98 80-120 Nickel 98.4 3.0 ug/L 100.0 98 80-120 Selenium 93.8 5.0 ug/L 100.0 94 80-120 Thallium 96.8 2.0 ug/L 100.0 97 80-120 Tin 102 5.0 ug/L 100.0 102 80-120 Vanadium 96.5 5.0 ug/L 100.0 97 80-120 Zinc 94.1 20 ug/L 100.0 94 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Batch POJ0239 - 3005A Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Matrix Spike (POJ0239-MS1) Source: 0100161-01 Prepared: 10/15/20 Analyzed: 10/23/20 Antimony 107 2.0 ug/L 100.0 BRL 107 75-125 Arsenic 96.7 1.0 ug/L 100.0 BRL 97 75-125 Barium 174 2.0 ug/L 100.0 80.6 93 75-125 Beryllium 97.7 1.0 ug/L 100.0 BRL 98 75-125 Cadmium 99.1 1.0 ug/L 100.0 0.236 99 75-125 Chromium 96.7 2.0 ug/L 100.0 BRL 97 75-125 Cobalt 98.1 2.0 ug/L 100.0 1.68 96 75-125 Copper 96.2 10 ug/L 100.0 BRL 96 75-125 Lead 100 1.0 ug/L 100.0 BRL 100 75-125 Nickel 95.4 3.0 ug/L 100.0 1.00 94 75-125 Selenium 96.0 5.0 ug/L 100.0 2.30 94 75-125 Thallium 98.5 2.0 ug/L 100.0 BRL 99 75-125 Tin 104 5.0 ug/L 100.0 BRL 104 75-125 Vanadium 98.5 5.0 ug/L 100.0 BRL 98 75-125 Zinc 94.8 20 ug/L 100.0 BRL 95 75-125 Matrix Spike Dup (POJ0239-MSD1) Source: 0100161-01 Prepared: 10/15/20 Analyzed: 10/23/20 Antimony 109 2.0 ug/L 100.0 BRL 109 75-125 1 20 Arsenic 96.5 1.0 ug/L 100.0 BRL 97 75-125 0.2 20 Barium 178 2.0 ug/L 100.0 80.6 97 75-125 2 20 Beryllium 103 1.0 ug/L 100.0 BRL 103 75-125 5 20 Cadmium 101 1.0 ug/L 100.0 0.236 101 75-125 2 20 Chromium 97.6 2.0 ug/L 100.0 BRL 98 75-125 0.9 20 Cobalt 98.3 2.0 ug/L 100.0 1.68 97 75-125 0.2 20 Copper 97.2 10 ug/L 100.0 BRL 97 75-125 1 20 Lead 101 1.0 ug/L 100.0 BRL 101 75-125 0.7 20 Nickel 96.9 3.0 ug/L 100.0 1.00 96 75-125 2 20 Selenium 92.8 5.0 ug/L 100.0 2.30 90 75-125 3 20 Thallium 99.1 2.0 ug/L 100.0 BRL 99 75-125 0.6 20 Tin 106 5.0 ug/L 100.0 BRL 106 75-125 3 20 Vanadium 99.7 5.0 ug/L 100.0 BRL 100 75-125 1 20 Zinc 95.6 20 ug/L 100.0 BRL 96 75-125 0.8 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0239 - 3005A Post Spike (POJ0239-PS1) Source: 0100161-01 Prepared: 10/15/20 Analyzed: 10/23/20 Antimony 102 ug/L 100.0 0.0480 102 80-120 Arsenic 96.7 ug/L 100.0 0.0980 97 80-120 Barium 173 ug/L 100.0 80.6 92 80-120 Beryllium 92.0 ug/L 100.0 0.0340 92 80-120 Cadmium 101 ug/L 100.0 0.236 101 80-120 Chromium 98.5 ug/L 100.0 0.0970 98 80-120 Cobalt 99.0 ug/L 100.0 1.68 97 80-120 Copper 97.7 ug/L 100.0 0.532 97 80-120 Lead 101 ug/L 100.0 0.0310 101 80-120 Nickel 96.7 ug/L 100.0 1.00 96 80-120 Selenium 96.8 ug/L 100.0 2.30 95 80-120 Thallium 99.3 ug/L 100.0 0.139 99 80-120 Tin 104 ug/L 100.0 0.0990 104 80-120 Vanadium 100 ug/L 100.0 -0.444 100 80-120 Zinc 97.4 ug/L 100.0 3.87 93 80-120 Batch POJ0374 - 7470A Blank (POJ0374-BLK1) Prepared & Analyzed: 10/20/20 Mercury BRL 0.20 ug/L LCS (POJ0374-BS1) Prepared &Analyzed: 10/20/20 Mercury 8.17 0.20 ug/L 9.375 87 80-120 Matrix Spike (POJ0374-MS1) Source: 0100161-02 Prepared & Analyzed: 10/20/20 Mercury 5.75 0.20 ug/L 9.375 0.727 54 80-120 MI This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Analyte Reporting Result Limit Units Spike Source Level Result %REC %REC RPD Limits RPD Limit Notes Batch POJ0374 - 7470A Matrix Spike Dup (POJ0374-MSD1) Source: 0100161-02 Prepared & Analyzed: 10/20/20 Mercury Post Spike (POJ0374-PS1) 5.67 0.20 ug/L Source: 0100161-02 9.375 0.727 53 Prepared & Analyzed: 10/20/20 80-120 1 20 MI Mercury Batch POJ0490 - 3005A 3.41 ug/L 5.000 0.679 55 85-115 MI Blank (POJ0490-BLK1) Prepared & Analyzed: 10/27/20 Silver BRL 1.0 ug/L LCS (POJ0490-BS1) Prepared &Analyzed: 10/27/20 Silver 97.6 1.0 ug/L 100.0 98 80-120 Matrix Spike (POJ0490-MS1) Source: 0100161-03 Prepared & Analyzed: 10/27/20 Silver 99.2 1.0 ug/L 100.0 BRL 99 75-125 Matrix Spike Dup (POJ0490-MSD1) Source: 0100161-03 Prepared & Analyzed: 10/27/20 Silver 99.5 1.0 ug/L 100.0 BRL 99 75-125 0.2 20 Post Spike (POJ0490-PS1) Source: 0100161-03 Prepared: 10/27/20 Analyzed: 10/28/20 Silver 99.3 ug/L 100.0 0.00300 99 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0218 - 3005A Blank (POJ0218-BLK1) Prepared: 10/14/20 Analyzed: 10/23/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L Thallium BRL 2.0 ug/L Tin BRL 5.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (POJ0218-BS1) Prepared: 10/14/20 Analyzed: 10/23/20 Antimony 94.6 2.0 ug/L 100.0 95 80-120 Arsenic 91.5 1.0 ug/L 100.0 92 80-120 Barium 91.9 10 ug/L 100.0 92 80-120 Beryllium 89.1 1.0 ug/L 100.0 89 80-120 Cadmium 97.3 1.0 ug/L 100.0 97 80-120 Chromium 93.6 2.0 ug/L 100.0 94 80-120 Cobalt 92.7 2.0 ug/L 100.0 93 80-120 Copper 91.1 10 ug/L 100.0 91 80-120 Lead 95.8 1.0 ug/L 100.0 96 80-120 Nickel 92.1 3.0 ug/L 100.0 92 80-120 Selenium 96.5 5.0 ug/L 100.0 96 80-120 Silver 45.6 1.0 ug/L 100.0 46 80-120 L Thallium 95.0 2.0 ug/L 100.0 95 80-120 Tin 97.9 5.0 ug/L 100.0 98 80-120 Vanadium 92.4 5.0 ug/L 100.0 92 80-120 Zinc 89.2 20 ug/L 100.0 89 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0259 - 7470A Blank (POJ0259-BLK1) Prepared & Analyzed: 10/15/20 Mercury BRL 0.20 ug/L LCS (POJ0259-BS1) Prepared &Analyzed: 10/15/20 Mercury 9.44 0.20 ug/L 9.375 101 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0221 - NO PREP Blank (POJ0221-BLK1) Prepared & Analyzed: 10/13/20 Chloride BRL 1000 ug/L Nitrate as N BRL 200 ug/L Sulfate BRL 2000 ug/L LCS (POJ0221-BS1) Prepared &Analyzed: 10/13/20 Chloride 40900 1000 ug/L 40000 102 80-120 Nitrate as N 3970 210 ug/L 4000 99 80-120 Sulfate 41100 2100 ug/L 40000 103 80-120 Matrix Spike (POJ0221-MS1) Source: 0100161-03 Prepared & Analyzed: 10/13/20 Chloride 119000 1000 ug/L 40000 78800 102 80-120 Nitrate as N 3950 210 ug/L 4000 92.4 97 80-120 Sulfate 65700 2100 ug/L 40000 25200 101 80-120 Matrix Spike Dup (POJ0221-MSD1) Source: 0100161-03 Prepared & Analyzed: 10/13/20 Chloride 119000 1000 ug/L 40000 78800 101 80-120 0.3 15 Nitrate as N 3930 210 ug/L 4000 92.4 96 80-120 0.5 15 Sulfate 65700 2100 ug/L 40000 25200 101 80-120 0.008 15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 84 Level II QC Report 0int 11/30/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0199 - NO PREP Blank (POJ0199-BLK1) Prepared & Analyzed: 10/13/20 Ferrous Iron BRL 200 ug/L LCS (POJ0199-BS1) Prepared &Analyzed: 10/13/20 Ferrous Iron 1840 200 ug/L 2000 92 90-110 Matrix Spike (POJ0199-MS1) Source: 0100161-03 Prepared & Analyzed: 10/13/20 Ferrous Iron 2220 200 ug/L 2000 355 93 80-120 HT Matrix Spike Dup (POJ0199-MSD1) Source: 0100161-03 Prepared & Analyzed: 10/13/20 Ferrous Iron 2180 200 ug/L 2000 355 91 80-120 2 20 HT Batch POJ0276 - NO PREP Blank (POJ0276-BLK1) Prepared & Analyzed: 10/14/20 Biochemical Oxygen Demand BRL 2000 ug/L LCS (POJ0276-BS1) Prepared &Analyzed: 10/14/20 Biochemical Oxygen Demand 189000 2000 ug/L 198000 95 84.6-115.4 Batch POJ0304 - NO PREP Blank (POJ0304-BLK1) Prepared & Analyzed: 10/16/20 Chemical Oxygen Demand BRL 50000 ug/L LCS (POJ0304-BS1) Prepared &Analyzed: 10/16/20 Chemical Oxygen Demand 501000 50000 ug/L 500000 100 90-110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 84 • 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Batch POJ0304 - NO PREP Level II QC Report 11 /30/20 Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Project No: 50-02 Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Matrix Spike (POJ0304-MS1) Source: 0100161-02 Prepared & Analyzed: 10/16/20 Chemical Oxygen Demand 532000 50000 ug/L 500000 42300 98 80-120 Matrix Spike Dup (POJ0304-MSD1) Source: 0100161-02 Prepared & Analyzed: 10/16/20 Chemical Oxygen Demand 521000 50000 ug/L 500000 42300 96 80-120 2 20 Batch POJ0337 - SM4500-S C Blank (POJ0337-BLK1) Prepared & Analyzed: 10/19/20 Sulfide BRL 2000 ug/L LCS (POJ0337-BS1) Prepared &Analyzed: 10/19/20 Sulfide 7900 2000 ug/L 10000 79 70-122 Matrix Spike (POJ0337-MS1) Source: 0100161-01 Prepared & Analyzed: 10/19/20 Sulfide 8300 2000 ug/L 10000 BRL 83 70-130 Matrix Spike Dup (POJ0337-MSD1) Source: 0100161-01 Prepared & Analyzed: 10/19/20 Sulfide 8600 2000 ug/L 10000 BRL 86 70-130 4 20 Batch POJ0341 - NO PREP Blank (POJ0341-BLK1) Prepared & Analyzed: 10/19/20 Total Alkalinity to pH 4.5 BRL 5000 ug/L LCS (POJ0341-BS1) Prepared &Analyzed: 10/19/20 Total Alkalinity to pH 4.5 249000 5000 ug/L 90-110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0357 - 9010C Blank (POJ0357-BLK1) Prepared & Analyzed: 10/20/20 Cyanide BRL 25 ug/L LCS (POJ0357-BS1) Prepared &Analyzed: 10/20/20 Cyanide 96.5 25 ug/L 100.0 96 85-115 Batch POJ0361 - NO PREP Blank (POJ0361-BLK1) Prepared & Analyzed: 10/19/20 Chemical Oxygen Demand BRL 50000 ug/L LCS (POJ0361-BSI) Prepared &Analyzed: 10/19/20 Chemical Oxygen Demand 498000 50000 ug/L 90-110 Matrix Spike (POJ0361-MS1) Source: 0100161-03 Prepared & Analyzed: 10/19/20 Chemical Oxygen Demand 475000 50000 ug/L 18000 80-120 Matrix Spike Dup (POJ0361-MSD1) Source: 0100161-03 Prepared & Analyzed: 10/19/20 Chemical Oxygen Demand 487000 50000 ug/L 18000 80-120 2 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 84 • 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 8270 Extended List - Quality Control Analyte Batch L517325 - 3510C Level II QC Report 11 /30/20 Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Project No: 50-02 Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes BSD (0100161 LCSD-L517325) Source: 0100161 LCS-L517Prepared: 10/19/20 Analyzed: 10/21/20 5-Nitro-o-toluidine 48.6 10.0 pg/L 50 45.1 97.2 20-120 7.4 20 Kepone 60 10.0 pg/L 50 53.4 120 20-120 11.6 20 Isosafrole 43.9 10.0 pg/L 50 41.9 87.8 20-120 4.6 20 Hexachloropropene 22.6 10.0 pg/L 50 18.9 45.2 20-120 17.8 20 Methapyrilene 49.8 10.0 pg/L 50 35.1 99.6 20-120 34.6 20 LCD2 7,12-Dimethylbenz(a)anthracene 58.1 10.0 pg/L 50 48.7 116 20-120 17.6 20 p-Dimethylaminoazobenzene 61.3 10.0 pg/L 50 51.1 123 20-120 18.1 20 L2 Diallate 48.4 10.0 pg/L 50 48.3 96.8 20-120 0.2 20 N-Nitrosomethylethylamine 27.4 10.0 pg/L 50 26.2 54.8 20-120 4.4 20 N-Nitrosopiperidine 34.1 10.0 pg/L 50 33.6 68.2 20-120 1.4 20 o-Toluidine 29.9 10.0 pg/L 50 29.4 59.8 20-120 1.6 20 p-Phenylenediamine 0 10.0 pg/L 50 0 0 20-120 0 20 L Safrole 39.9 10.0 pg/L 50 39.7 79.8 20-120 0.5 20 Pronamide 56.1 10.0 pg/L 50 51 112 20-120 9.5 20 4-Aminobiphenyl 38.8 10.0 pg/L 50 37 77.6 20-120 4.7 20 N-Nitrosopyrrolidine 34.3 10.0 pg/L 50 34.4 68.6 20-120 0.2 20 3-Methylcholanthrene 57.1 10.0 pg/L 50 53 114 20-120 7.4 20 2-Acetylaminofluorene 49.1 10.0 pg/L 50 53.1 98.2 20-120 7.8 20 2-Naphthylamine 20.3 10.0 pg/L 50 22.7 40.6 20-120 11.1 20 1-Naphthylamine 28.8 10.0 pg/L 50 28.9 57.6 20-120 0.3 20 1,3,5-Trinitrobenzene 65.8 10.0 pg/L 50 60.4 132 20-120 8.5 20 LH 1,4-Naphthoquinone 44.6 10.0 pg/L 50 41.7 89.2 20-120 6.7 20 BS (0100161 LCS-L517325) Prepared: 10/19/20 Analyzed: 10/21/20 N-Nitrosomethylethylamine 26.2 10.0 pg/L 50 52.4 20-120 o-Toluidine 29.4 10.0 pg/L 50 58.8 20-120 Isosafrole 41.9 10.0 pg/L 50 83.8 20-120 Kepone 53.4 10.0 pg/L 50 107 20-120 p-Dimethylaminoazobenzene 51.1 10.0 pg/L 50 102 20-120 Methapyrilene 35.1 10.0 pg/L 50 70.2 20-120 p-Phenylenediamine 0 10.0 pg/L 50 0 20-120 L 1-Naphthylamine 28.9 10.0 pg/L 50 57.8 20-120 N-Nitrosopiperidine 33.6 10.0 pg/L 50 67.2 20-120 N-Nitrosopyrrolidine 34.4 10.0 pg/L 50 68.8 20-120 1,4-Naphthoquinone 41.7 10.0 pg/L 50 83.4 20-120 2-Naphthylamine 22.7 10.0 pg/L 50 45.4 20-120 4-Aminobiphenyl 37 10.0 pg/L 50 74 20-120 3-Methylcholanthrene 53 10.0 pg/L 50 106 20-120 Safrole 39.7 10.0 pg/L 50 79.4 20-120 5-Nitro-o-toluidine 45.1 10.0 pg/L 50 90.2 20-120 7,12-Dimethylbenz(a)anthracene 48.7 10.0 pg/L 50 97.4 20-120 2-Acetylaminofluorene 53.1 10.0 pg/L 50 106 20-120 Pronamide 51 10.0 pg/L 50 102 20-120 Diallate 48.3 10.0 pg/L 50 96.6 20-120 1,3,5-Trinitrobenzene 60.4 10.0 pg/L 50 121 20-120 LH Hexachloropropene 18.9 10.0 pg/L 50 37.8 20-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 8270 Extended List - Quality Control Analyte Batch L517325 - 3510C Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes BILK (0100161 LRB-L517325) Prepared: 10/19/20 Analyzed: 10/20/20 p-Phenylenediamine BRL 10.0 pg/L - 1,3,5-Trinitrobenzene BRL 10.0 pg/L o-Toluidine BRL 10.0 pg/L Pronamide BRL 10.0 pg/L Safrole BRL 10.0 pg/L p-Dimethylaminoazobenzene BRL 10.0 pg/L 2-Acetylaminofluorene BRL 10.0 pg/L N-Nitrosopyrrolidine BRL 10.0 pg/L 1,4-Naphthoquinone BRL 10.0 pg/L 4-Aminobiphenyl BRL 10.0 pg/L 5-Nitro-o-toluidine BRL 10.0 pg/L 7,12-Dimethylbenz(a)anthracene BRL 10.0 pg/L Diallate BRL 10.0 pg/L 3-Methylcholanthrene BRL 10.0 pg/L Hexachloropropene BRL 10.0 pg/L Isosafrole BRL 10.0 pg/L Kepone BRL 10.0 pg/L 1-Naphthylamine BRL 10.0 pg/L Methapyrilene BRL 20.0 pg/L N-Nitrosomethylethylamine BRL 10.0 pg/L N-Nitrosopiperidine BRL 10.0 pg/L 2-Naphthylamine BRL 10.0 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Phenoxy Acid Herbicides - GC/ECD - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517362 - 8151A BSD (0100161 LCSD-L517362) Source: 0100161 LCS-L517Prepared: 10/19/20 Analyzed: 10/20/20 MCPA 250.8 18.98 pg/L 500 200.4 50.1 20-120 22.3 20 LCD2 Dichlorprop 2.547 0.07959 pg/L 5 2.019 50.9 20-120 23.1 20 LCD2 Dalapon 3.626 0.5149 pg/L 12.5 4.011 29 20-120 10 20 Dicamba 0.255 0.05700 pg/L 0.5 0.2384 51 20-120 6.7 20 Dinoseb 1.507 0.02698 pg/L 2.5 1.16 60.2 20-120 26 20 LCD2 2,4-DB 2.624 0.1364 pg/L 5 2.123 52.4 20-120 21.1 20 LCD2 2,4-D 2.493 0.2078 pg/L 5 1.997 49.8 20-120 22 20 LCD2 MCPP 301.9 11.75 pg/L 500 258.1 60.3 20-120 15.6 20 Picloram 0.6016 0.04528 pg/L 1.25 0.4532 48.1 20-120 28.1 20 LCD2 2,4,5-TP (Silvex) 0.2371 0.01634 pg/L 0.5 0.187 47.4 20-120 23.6 20 LCD2 2,4,5-T 0.2697 0.01002 pg/L 0.5 0.2279 53.9 20-120 16.8 20 Surrogate: DCAA 1.393 ug/L 2.5 1.156 55.7 20-150 BS (0100161 LCS-L517362) Prepared: 10/19/20 Analyzed: 10/20/20 MCPP 258.1 11.75 pg/L 500 51.6 20-120 MCPA 200.4 18.98 pg/L 500 40 20-120 Dinoseb 1.16 0.02698 pg/L 2.5 46.4 20-120 Dichlorprop 2.019 0.07959 pg/L 5 40.3 20-120 Dicamba 0.2384 0.05700 pg/L 0.5 47.6 20-120 Picloram 0.4532 0.04528 pg/L 1.25 36.2 20-120 2,4,5-TP (Silvex) 0.187 0.01634 pg/L 0.5 37.4 20-120 2,4,5-T 0.2279 0.01002 pg/L 0.5 45.5 20-120 Dalapon 4.011 0.5149 pg/L 12.5 32 20-120 2,4-D 1.997 0.2078 pg/L 5 39.9 20-120 2,4-DB 2.123 0.1364 pg/L 5 42.4 20-120 Surrogate: DCAA 1.156 ug/L 2.5 46.2 20-150 BLK (0100161 LRB-L517362) Prepared: 10/19/20 Analyzed: 10/20/20 Dicamba BRL 0.1000 pg/L - 2,4,5-T BRL 0.03000 pg/L 2,4,5-TP (Silvex) BRL 0.1000 pg/L MCPP BRL 50.00 pg/L 2,4-D BRL 0.2500 pg/L 2,4-DB BRL 0.1000 pg/L Dinoseb BRL 0.1000 pg/L Dalapon BRL 0.5500 pg/L Dichlorprop BRL 0.1000 pg/L MCPA BRL 50.00 pg/L Picloram BRL 0.1000 pg/L - Surrogate: DCAA 1.286 ug/L 2.5 51.4 20-150 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BSD (0100161 LCSD-L517230) Source: 0100161 LCS-L517Prepared & Analyzed: 10/19/20 4,6-Dinitro-2-methylphenol 35.7 3.47 pg/L 50 47.1 71.4 27-128 27.5 20 LCD2 Dimethyl phthalate 36.4 0.510 pg/L 50 33 72.8 34-123 9.7 20 3,3' Dimethylbenzidine 76.3 1.88 pg/L 200 55.8 38.1 6-192 31 20 LCD2 Diethyl phthalate 36.5 0.585 pg/L 50 33.6 73 36-130 8.2 20 3,3'-Dichlorobenzidine 112 3.74 pg/L 150 95.9 74.6 6-192 15.4 20 Chrysene 36 0.731 pg/L 50 32.3 72 30-124 10.8 20 3-Nitroaniline 36.9 1.53 pg/L 50 32.3 73.8 28-142 13.2 20 Dibenz(a,h)anthrace ne 34.2 0.252 pg/L 50 29.9 68.4 27-124 13.4 20 3&4 Methylphenol 26.8 0.691 pg/L 50 23.7 53.6 21-96 12.2 20 Dibenzofuran 36.3 0.423 pg/L 50 33.2 72.6 40-108 8.9 20 Di-n-butyl phthalate 37 1.58 pg/L 50 34.5 74 19-158 6.9 20 2-Nitrophenol 32.4 0.606 pg/L 50 28.6 64.8 25-114 12.4 20 Di-n-Octyl Phthalate 44.9 1.72 pg/L 50 36.4 89.8 29-136 20.9 20 LCD2 2-Nitroaniline 38.4 0.574 pg/L 50 35 76.8 32-127 9.2 20 Fluoranthene 39 0.406 pg/L 50 36 78 28-127 8 20 2-Methylphenol 25 0.721 pg/L 50 22 50 22-97 12.7 20 Fluorene 34.1 0.444 pg/L 50 31.4 68.2 41-116 8.2 20 4-Bromophenyl phenyl ether 36.7 0.500 pg/L 50 33.4 73.4 31-124 9.4 20 Hexachlorobenzene 36.2 2.57 pg/L 50 33.6 72.4 18-136 7.4 20 Bis(2-Chloroisopropyl)ether 22.2 0.546 pg/L 50 19.4 44.4 28-108 13.4 20 Hexachlorobutadiene 25.5 0.405 pg/L 50 22.5 51 22-109 12.5 20 Hexachlorocyclopentadiene 12.1 2.34 pg/L 50 13.9 24.2 10-102 13.8 20 2-Methyl naphthalene 32.1 0.485 pg/L 50 29.7 64.2 34-108 7.7 20 Hexachloroethane 21.7 0.277 pg/L 50 19 43.4 16-107 13.2 20 Anthracene 36.1 0.467 pg/L 50 33.8 72.2 34-128 6.5 20 Benzo(b)fluoranthene 41.4 0.941 pg/L 50 38.4 82.8 36-131 7.5 20 Aniline 22.1 0.316 pg/L 50 18.1 44.2 16-133 19.9 20 Benzo(g,h,i)perylene 33.7 1.36 pg/L 50 30.6 67.4 26-123 9.6 20 Acetophenone 31.3 0.686 pg/L 50 27.2 62.6 25-108 14 20 Benzo(k)fluoranthene 43.7 0.752 pg/L 50 34.5 87.4 32-132 23.5 20 LCD2 Acenaphthylene 32.8 0.429 pg/L 50 29.7 65.6 37-114 9.9 20 Benzoic Acid 18.9 5.00 pg/L 150 30.6 12.6 11-68 47.2 20 LCD2 Acenaphthene 31.1 0.422 pg/L 50 27.4 62.2 38-117 12.6 20 Bis(2-ethylhexyl)phthalate 37.9 3.66 pg/L 50 37.4 75.8 21-162 1.3 20 Bis(2-Chloroethoxy)methane 30.7 0.433 pg/L 50 27.3 61.4 20-126 11.7 20 Benzo(a)pyrene 35.5 1.00 pg/L 50 30.9 71 34-131 13.8 20 4-Nitrophenol 11.3 1.39 pg/L 50 10.6 22.6 1-76 6.3 20 Bis(2-Chloroethyl)ether 28.8 0.447 pg/L 50 25.1 57.6 16-122 13.7 20 4-Nitroaniline 53.9 0.740 pg/L 50 52.8 108 23-139 2 20 N-Nitrosodiphenylamine 31 0.783 pg/L 50 27.7 62 45-135 11.2 20 4-Chlorophenyl phenyl ether 34.8 0.479 pg/L 50 32.5 69.6 39-110 6.8 20 4-Chloroaniline 28.7 0.526 pg/L 50 24.4 57.4 24-127 16.1 20 Benzidine 49.1 0.689 pg/L 150 37.5 32.7 2-176 26.7 20 LCD2 Butyl benzyl phthalate 38.1 4.59 pg/L 50 39.7 76.2 33-142 4.1 20 Carbazole 42.2 0.476 pg/L 50 39.1 84.4 20-147 7.6 20 4-Chloro-3-methylphenol 36.3 0.503 pg/L 50 32.5 72.6 35-117 11 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 55 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BSD (0100161 LCSD-L517230) Source: 0100161 LCS-L517Prepared & Analyzed: 10/19/20 Benzyl alcohol 23.8 3.01 pg/L 50 20.5 47.6 20-109 14.8 20 1,3-Dichlorobenzene 24.2 0.491 pg/L 50 20.6 48.4 21-102 16 20 2,4-Dinitrophenol 77.8 4.85 pg/L 150 103 51.8 10-132 27.8 20 LCD2 Pentachlorophenol 48.7 2.45 pg/L 50 49.5 97.4 17-142 1.6 20 N-Nitrosodiethylamine 32.6 0.400 pg/L 50 28.1 65.2 25-107 14.8 20 2,4-Dimethylphenol 33.7 0.674 pg/L 50 30.2 67.4 34-105 10.9 20 N-Nitrosodimethylamine 15.1 0.249 pg/L 50 12.8 30.2 14-84 16.4 20 2,4-Dinitrotoluene 35.3 0.403 pg/L 50 33.4 70.6 24-147 5.5 20 2,4-Dichlorophenol 25.7 1.52 pg/L 50 23.3 51.4 32-110 9.7 20 Phenanthrene 36.1 0.464 pg/L 50 33.2 72.2 40-120 8.3 20 2-Chorophenol 28.4 0.736 pg/L 50 25 56.8 27-102 12.7 20 1,4-Dichlorobenzene 24.8 0.580 pg/L 50 21.3 49.6 24-99 15.1 20 N-Nitroso-di-n-butylamine 30 0.752 pg/L 50 26.5 60 25-126 12.3 20 N-Nitroso-di-n-propylamine 28.9 0.334 pg/L 50 25.3 57.8 29-114 13.2 20 2,4,5-Trichlorophenol 39.4 0.350 pg/L 50 35.1 78.8 26-118 11.5 20 2,3,4,6-Tetrachlorophenol 38.5 0.355 pg/L 50 35.7 77 28-118 7.5 20 Phenol 11.9 0.389 pg/L 50 10.5 23.8 11-55 12.5 20 Pyrene 33 1.04 pg/L 50 40.7 66 20-154 20.8 20 LCD2 Pyridine 15.7 0.678 pg/L 50 12.9 31.4 10-71 19.5 20 2,6-Dinitrotoluene 36.8 0.413 pg/L 50 33.5 73.6 36-125 9.3 20 1,2-Dichlorobenzene 25.5 0.629 pg/L 50 22.5 51 26-100 12.5 20 2-Chloronaphthalene 29.5 0.476 pg/L 50 26 59 29-137 12.6 20 Benzo(a)anthracene 35.3 0.427 pg/L 50 32.5 70.6 36-127 8.2 20 Indeno(1,2,3-cd)pyrene 40.4 1.01 pg/L 50 33.1 80.8 22-126 19.8 20 1,2,4,5-Tetrachlorobenzene 30.2 0.317 pg/L 50 26.8 60.4 28-110 11.9 20 Isophorone 26.6 0.360 pg/L 50 23.3 53.2 31-116 13.2 20 2,6-Dichlorophenol 35.5 0.703 pg/L 50 31.1 71 25-112 13.2 20 Naphthalene 28 0.484 pg/L 50 24.7 56 33-108 12.5 20 2,4,6-Trichlorophenol 38.5 0.344 pg/L 50 34.3 77 26-115 11.5 20 1,2,4-Trichlorobenzene 27.3 0.482 pg/L 50 24.3 54.6 23-106 11.6 20 Nitrobenzene 30 0.531 pg/L 50 26.3 60 27-117 13.1 20 Surrogate:2-Fluorophenol 23.5 pg/L 100 20.2 23.5 10-44 Surrogate:2-Fluorobiphenyl 45 pg/L 100 43.6 45 24-93 Surrogate:4-Terphenyl-d14 55.2 pg/L 100 74.7 55.2 35-126 Surrogate: 2,4,6-Tribromophenol 67.8 pg/L 100 63.3 67.8 39-110 Surrogate: Phenol-d6 16.4 pg/L 100 14.8 16.4 7-32 Surrogate: Nitrobenzene-d5 49.7 pg/L 100 47.4 49.7 20-91 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 56 of 84 • 0 Waypoint ANALYTICAL Level II QC Report 11 /30/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100161 Attn: Alec Macbeth Time Submitted: 10/13/2020 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BS (0100161 LCS-L517230) Prepared & Analyzed: 10/19/20 Benzo(g,h,i)perylene 30.6 1.36 pg/L 50 61.2 26-123 Benzo(a)pyrene 30.9 1.00 pg/L 50 61.8 34-131 Bis(2-Chloroisopropyl)ether 19.4 0.546 pg/L 50 38.8 28-108 Bis(2-Chloroethyl)ether 25.1 0.447 pg/L 50 50.2 16-122 Phenanthrene 33.2 0.464 pg/L 50 66.4 40-120 Bis(2-Chloroethoxy)methane 27.3 0.433 pg/L 50 54.6 20-126 Phenol 10.5 0.389 pg/L 50 21 11-55 Benzyl alcohol 20.5 3.01 pg/L 50 41 20-109 Pyrene 40.7 1.04 pg/L 50 81.4 20-154 Benzo(k)fluoranthene 34.5 0.752 pg/L 50 69 32-132 Benzoic Acid 30.6 5.00 pg/L 150 20.4 11-68 Benzo(b)fluoranthene 38.4 0.941 pg/L 50 76.8 36-131 Dimethyl phthalate 33 0.510 pg/L 50 66 34-123 Hexachloroethane 19 0.277 pg/L 50 38 16-107 Hexachlorocyclopentadiene 13.9 2.34 pg/L 50 27.8 10-102 Hexachlorobutadiene 22.5 0.405 pg/L 50 45 22-109 Indeno(1,2,3-cd)pyrene 33.1 1.01 pg/L 50 66.2 22-126 Hexachlorobenzene 33.6 2.57 pg/L 50 67.2 18-136 Isophorone 23.3 0.360 pg/L 50 46.6 31-116 Fluorene 31.4 0.444 pg/L 50 62.8 41-116 Naphthalene 24.7 0.484 pg/L 50 49.4 33-108 Fluoranthene 36 0.406 pg/L 50 72 28-127 Di-n-Octyl Phthalate 36.4 1.72 pg/L 50 72.8 29-136 Nitrobenzene 26.3 0.531 pg/L 50 52.6 27-117 Carbazole 39.1 0.476 pg/L 50 78.2 20-147 Pentachlorophenol 49.5 2.45 pg/L 50 99 17-142 N-Nitrosodiethylamine 28.1 0.400 pg/L 50 56.2 25-107 Diethyl phthalate 33.6 0.585 pg/L 50 67.2 36-130 Dibenzofuran 33.2 0.423 pg/L 50 66.4 40-108 Dibenz(a,h)anthrace ne 29.9 0.252 pg/L 50 59.8 27-124 N-Nitrosodimethylamine 12.8 0.249 pg/L 50 25.6 14-84 Pyridine 12.9 0.678 pg/L 50 25.8 10-71 N-Nitroso-di-n-butylamine 26.5 0.752 pg/L 50 53 25-126 Chrysene 32.3 0.731 pg/L 50 64.6 30-124 N-Nitroso-di-n-propylamine 25.3 0.334 pg/L 50 50.6 29-114 Butyl benzyl phthalate 39.7 4.59 pg/L 50 79.4 33-142 Bis(2-ethylhexyl)phthalate 37.4 3.66 pg/L 50 74.8 21-162 N-Nitrosodiphenylamine 27.7 0.783 pg/L 50 55.4 45-135 Di-n-butyl phthalate 34.5 1.58 pg/L 50 69 19-158 2-Nitrophenol 28.6 0.606 pg/L 50 57.2 25-114 4-Bromophenyl phenyl ether 33.4 0.500 pg/L 50 66.8 31-124 2-Methylphenol 22 0.721 pg/L 50 44 22-97 2,4-Dinitrophenol 103 4.85 pg/L 150 68.6 10-132 4-Nitroaniline 52.8 0.740 pg/L 50 106 23-139 4-Chlorophenyl phenyl ether 32.5 0.479 pg/L 50 65 39-110 2,4,5-Trichlorophenol 35.1 0.350 pg/L 50 70.2 26-118 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 57 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BS (0100161 LCS-L517230) Prepared & Analyzed: 10/19/20 2,6-Dichlorophenol 31.1 0.703 pg/L 50 62.2 25-112 2-Nitroaniline 35 0.574 pg/L 50 70 32-127 2,3,4,6-Tetrachlorophenol 35.7 0.355 pg/L 50 71.4 28-118 4-Chloro-3-methyl phenol 32.5 0.503 pg/L 50 65 35-117 4-Nitrophenol 10.6 1.39 pg/L 50 21.2 1-76 2-Chorophenol 25 0.736 pg/L 50 50 27-102 2,4,6-Trichlorophenol 34.3 0.344 pg/L 50 68.6 26-115 2,4-Dinitrotoluene 33.4 0.403 pg/L 50 66.8 24-147 4,6-Dinitro-2-methylphenol 47.1 3.47 pg/L 50 94.2 27-128 2,4-Dichlorophenol 23.3 1.52 pg/L 50 46.6 32-110 3-Nitroaniline 32.3 1.53 pg/L 50 64.6 28-142 3&4 Methylphenol 23.7 0.691 pg/L 50 47.4 21-96 3,3'-Dichlorobenzidine 95.9 3.74 pg/L 150 63.9 6-192 2,4-Dimethylphenol 30.2 0.674 pg/L 50 60.4 34-105 3,3' Dimethylbenzidine 55.8 1.88 pg/L 200 27.9 6-192 4-Chloroaniline 24.4 0.526 pg/L 50 48.8 24-127 Aniline 18.1 0.316 pg/L 50 36.2 16-133 Benzidine 37.5 0.689 pg/L 150 25 2-176 1,2,4,5-Tetrachlorobenzene 26.8 0.317 pg/L 50 53.6 28-110 Anthracene 33.8 0.467 pg/L 50 67.6 34-128 1,2,4-Trichlorobenzene 24.3 0.482 pg/L 50 48.6 23-106 1,2-Dichlorobenzene 22.5 0.629 pg/L 50 45 26-100 1,4-Dichlorobenzene 21.3 0.580 pg/L 50 42.6 24-99 Acetophenone 27.2 0.686 pg/L 50 54.4 25-108 Acenaphthylene 29.7 0.429 pg/L 50 59.4 37-114 1,3-Dichlorobenzene 20.6 0.491 pg/L 50 41.2 21-102 2-Methyl naphthalene 29.7 0.485 pg/L 50 59.4 34-108 Acenaphthene 27.4 0.422 pg/L 50 54.8 38-117 Benzo(a)anthracene 32.5 0.427 pg/L 50 65 36-127 2,6-Dinitrotoluene 33.5 0.413 pg/L 50 67 36-125 2-Chloronaphthalene 26 0.476 pg/L 50 52 29-137 Surrogate: Phenol-d6 14.8 Ng/L 100 14.8 7-32 Surrogate: Nitrobenzene-d5 47.4 pg/L 100 47.4 20-91 Surrogate: 2,4,6-Tribromophenol 63.3 Ng/L 100 63.3 39-110 Surrogate:2-Fluorobiphenyl 43.6 Ng/L 100 43.6 24-93 Surrogate:2-Fluorophenol 20.2 Ng/L 100 20.2 10-44 Surrogate:4-Terphenyl-d14 74.7 Ng/L 100 74.7 35-126 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 58 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BILK (0100161 LRB-11-517230) Prepared & Analyzed: 10/19/20 Indeno(1,2,3-cd)pyrene BRL 2.00 pg/L 2,4-Dinitrophenol BRL 10.0 pg/L 2-Chlorophenol BRL 5.00 pg/L 2,4-Dinitrotoluene BRL 5.00 pg/L 2,6-Dichlorophenol BRL 5.00 pg/L Isophorone BRL 5.00 pg/L Nitrobenzene BRL 5.00 pg/L 2,6-Dinitrotoluene BRL 5.00 pg/L Naphthalene BRL 2.00 pg/L 2-Chloronaphthalene BRL 5.00 pg/L 2,3,4,6-Tetrachlorophenol BRL 5.00 pg/L Pyridine BRL 10.0 pg/L 1,2,4,5-Tetrachlorobenzene BRL 5.00 pg/L Pyrene BRL 2.00 pg/L 1,2,4-Trichlorobenzene BRL 5.00 pg/L 1,2-Dichlorobenzene BRL 5.00 pg/L Phenol BRL 5.00 pg/L 1,3-Dichlorobenzene BRL 5.00 pg/L 1,4-Dichlorobenzene BRL 5.00 pg/L Pentachlorophenol BRL 10.0 pg/L N-Nitrosodiphenylamine BRL 10.0 pg/L N-Nitroso-di-n-propylamine BRL 5.00 pg/L 2,4,5-Trichlorophenol BRL 5.00 pg/L 2-Methylphenol BRL 5.00 pg/L N-Nitroso-di-n-butylamine BRL 5.00 pg/L N-Nitrosodimethylamine BRL 5.00 pg/L 2,4-Dichlorophenol BRL 5.00 pg/L 2,4-Dimethylphenol BRL 5.00 pg/L N-Nitrosodiethylamine BRL 5.00 pg/L Phenanthrene BRL 2.00 pg/L Acenaphthylene BRL 2.00 pg/L Hexachloroethane BRL 5.00 pg/L Butyl benzyl phthalate BRL 5.00 pg/L 2-Methyl naphthalene BRL 2.00 pg/L 4-Chlorophenyl phenyl ether BRL 5.00 pg/L Bis(2-Chloroisopropyl)ether BRL 5.00 pg/L 4-Nitroaniline BRL 5.00 pg/L Bis(2-Chloroethyl)ether BRL 5.00 pg/L 4-Nitrophenol BRL 10.0 pg/L Bis(2-Chloroethoxy)methane BRL 5.00 pg/L 4-Chloro-3-methylphenol BRL 5.00 pg/L Acenaphthene BRL 2.00 pg/L 4-Chloroaniline BRL 5.00 pg/L Benzoic Acid BRL 10.0 pg/L Benzo(k)fluoranthene BRL 2.00 pg/L Acetophenone BRL 5.00 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 59 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517230 - 3510C BILK (0100161 LRB-11-517230) Prepared & Analyzed: 10/19/20 Benzo(g,h,i)perylene BRL 2.00 pg/L Aniline BRL 5.00 pg/L Anthracene BRL 2.00 pg/L Benzo(b)fluoranthene BRL 2.00 pg/L Benzo(a)pyrene BRL 2.00 pg/L Benzidine BRL 20.0 pg/L Benzo(a)anthracene BRL 2.00 pg/L Benzyl alcohol BRL 10.0 pg/L 2-Nitrophenol BRL 5.00 pg/L Hexachlorocyclopentadiene BRL 5.00 pg/L Hexachlorobutadiene BRL 5.00 pg/L Hexachlorobenzene BRL 5.00 pg/L 2,4,6-Trichlorophenol BRL 5.00 pg/L Fluorene BRL 2.00 pg/L Fluoranthene BRL 2.00 pg/L Bis(2-ethylhexyl)phthalate BRL 5.00 pg/L Di-n-Octyl Phthalate BRL 5.00 pg/L Carbazole BRL 5.00 pg/L Dibenzofuran BRL 5.00 pg/L Chrysene BRL 2.00 pg/L 4-Bromophenyl phenyl ether BRL 5.00 pg/L 2-Nitroaniline BRL 5.00 pg/L Dibenz(a,h)anthrace ne BRL 2.00 pg/L Di-n-butyl phthalate BRL 5.00 pg/L 3-Nitroaniline BRL 10.0 pg/L 3,3'-Dichlorobenzidine BRL 10.0 pg/L Diethyl phthalate BRL 5.00 pg/L Dimethyl phthalate BRL 5.00 pg/L 3,3' Dimethylbenzidine BRL 10.0 pg/L 3&4 Methylphenol BRL 5.00 pg/L 4,6-Dinitro-2-methylphenol BRL 10.0 pg/L - Surrogate: Phenol-d6 16.3 Ng/L 100 16.3 7-32 Surrogate: 2,4,6-Tribromophenol 68.5 ug/L 100 68.5 39-110 Surrogate: Nitrobenzene-d5 54.3 Ng/L 100 54.3 20-91 Surrogate:4-Terphenyl-d14 71.7 Ng/L 100 71.7 35-126 Surrogate:2-Fluorobiphenyl 47.9 Ng/L 100 47.9 24-93 Surrogate:2-Fluorophenol 24.2 Ng/L 100 24.2 10-44 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 60 of 84 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Organic Carbon - Quality Control Analyte Batch L518399 - 531 OC-2011 Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 11 /30/20 Work Order: 0100161 Time Submitted: 10/13/2020 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes MSD (0100161 L 90962-MSD-L518399) Source: 0100161 L 90962-hPrepared: 10/23/20 Analyzed: 10/24/20 TOC 8.77 0.522 mg/L 5.26 8.56 105 70-130 2.4 MS (0100161 L 90962-MS-L518399) Source: 0100161-03 Prepared: 10/23/20 Analyzed: 10/24/20 TOC 8.56 0.522 mg/L 5.26 3.22 101 70-130 BS (0100161 LCS-L518399) Prepared: 10/23/20 Analyzed: 10/24/20 TOC 5.23 0.498 mg/L 5 105 85-115 BILK (0100161 LRB-L518399) Prepared: 10/23/20 Analyzed: 10/24/20 TOC BRL 1.00 mg/L - 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 61 of 84 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100161-02 POJ0218 50 mL 50 mL 10/14/20 10:20 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100161-02 POJ0259 20 mL 30 mL 10/15/20 11:56 Prep Method: 9010C Lab Number Batch Initial Final Date/Time 0100161-01 POJ0357 50 mL 50 mL 10/20/20 8:10 0100161-02 POJ0357 50 mL 50 mL 10/20/20 8:10 0100161-03 POJ0357 50 mL 50 mL 10/20/20 8:10 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 0100161-01 POJ0337 200 mL 200 mL 10/19/20 11:02 0100161-02 POJ0337 200 mL 200 mL 10/19/20 11:02 0100161-03 POJ0337 200 mL 200 mL 10/19/20 11:02 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100161-01 POJ0214 990 mL 10 mL 10/14/20 11:30 0100161-02 POJ0214 1000 mL 10 mL 10/14/20 11:30 0100161-03 POJ0214 1000 mL 10 mL 10/14/20 11:30 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100161-01 POJ0214 990 mL 10 mL 10/14/20 11:30 0100161-02 POJ0214 1000 mL 10 mL 10/14/20 11:30 0100161-03 POJ0214 1000 mL 10 mL 10/14/20 11:30 Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100161-01 POJ0239 50 mL 50 mL 10/15/20 7:44 0100161-01 POJ0490 50 mL 50 mL 10/27/20 7:00 0100161-02 POJ0239 50 mL 50 mL 10/15/20 7:44 0100161-02 POJ0490 50 mL 50 mL 10/27/20 7:00 0100161-02 POJ0239 50 mL 50 mL 10/15/20 7:44 0100161-03 POJ0239 50 mL 50 mL 10/15/20 7:44 0100161-03 POJ0490 50 mL 50 mL 10/27/20 7:00 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100161-01 POJ0374 20 mL 30 mL 10/20/20 11:55 0100161-02 POJ0374 20 mL 30 mL 10/20/20 11:55 0100161-03 POJ0374 20 mL 30 mL 10/20/20 11:55 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100161-01 POJ0321 10 mL 10 mL 10/21/20 10:00 0100161-02 POJ0321 10 mL 10 mL 10/21/20 10:00 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 62 of 84 Sample Extraction Data Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100161-03 POJ0321 10 mL 10 mL 10/21/20 10:00 0100161-04 POJ0321 10 mL 10 mL 10/21/20 10:00 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100161-01 POJ0316 5 mL 5 mL 10/16/20 10:00 0100161-02 POJ0316 5 mL 5 mL 10/16/20 10:00 0100161-03 POJ0316 5 mL 5 mL 10/16/20 10:00 Sample Extraction Data Prep Method: 3510C Lab Number Batch Initial Final Date/Time 0100161-01 L517325 10/19/20 15:45 0100161-02 L517325 10/19/20 15:45 0100161-03 L517325 10/19/20 15:45 Prep Method: 8151A Lab Number Batch Initial Final Date/Time 0100161-01 L517362 10/19/20 17:11 0100161-02 L517362 10/19/20 17:11 0100161-03 L517362 10/19/20 17:11 Prep Method: 3510C Lab Number Batch Initial Final Date/Time 0100161-01 L517230 10/19/20 11:30 0100161-02 L517230 10/19/20 11:30 0100161-03 L517230 10/19/20 11:30 Prep Method: 5310C-2011 Lab Number Batch Initial Final Date/Time 0100161-01 L518399 10/23/20 14:11 0100161-02 L518399 10/23/20 14:11 0100161-03 L518399 10/23/20 14:11 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 63 of 84 Subcontracted Analyses The following analyses were subcontracted to Pace Analytical Gulf Coast Lab Number Analysis 0100161-01 Carbon Dioxide AM20GAX 0100161-01 Hydrogen AM20GAX 0100161-01 Methane, Ethane, Ethene (AM20GAX) 0100161-01 Volatile Fatty Acids (Sub) 0100161-02 Carbon Dioxide AM20GAX 0100161-02 Hydrogen AM20GAX 0100161-02 Methane, Ethane, Ethene (AM20GAX) 0100161-02 Volatile Fatty Acids (Sub) 0100161-03 Carbon Dioxide AM20GAX 0100161-03 Hydrogen AM20GAX 0100161-03 Methane, Ethane, Ethene (AM20GAX) 0100161-03 Volatile Fatty Acids (Sub) The following analyses were subcontracted to Waypoint Analytical Lab Number Analysis O100161-01 8270 (App. II) 0100161-01 Herbicides (Sub) 0100161-01 TOC (Sub) 0100161-02 8270 (App. I1) 0100161-02 Herbicides (Sub) O100161-02 TOC (Sub) 0100161-03 8270 (App. I1) 0100161-03 Herbicides (Sub) 0100161-03 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 64 of 84 CHAIN OF CUSTODY RECORD LAB USE ONLY Waypoint PAGE A 1 PROPER BILLING: YES NO N/A — OF QUOTE # TO ENSURE Samples INTACT upon arrival? � ANALYTICAL fit- Project Name: �'�JTl �� Received IN ICE? 449 Sprone 7 brook41529 Road • Charlotte, NC 28217 Phone 704/529-6364 Fax: 704/525-0409 Short Hold Anal sis Yes No T Project: Yes No y (Yes) ) J ( ( ) PROPER PRESERVATIVES indicated? *Please ATTACH any p ct specific reporting (QC LEVEL 1 II III I Received WITHIN HOLDING TIMES? 1� Client Company Name: provisions and/or QC Requirements CUSTODY SEALS INTACT? Report To/Contact Name:i.C. MCAT Invoice To - VOLATILES rec'd W/OUT HEADSPACE? ��qy Reporting Address: ' QQ / woo(A� Address: ( PROPER CONTAINERS use ? f TEMP: Therm ID:_��ii Observed 4 �C/Corr. Z'� �C Phone: R}�?��� 50 Fax (Yes)(No): Purchase Order No./Billing -6 a ® PERSONNEL Reference TO BE FILLEDIN BY CJ�IENT/SAMPLING Email Address: Requested Due Date ❑ 1 Day ❑ 2 Da ❑ 3 Days ❑ 4 Days ❑ 5 Days '5 Certification: NC SC EDD Type: PDF Excel Other "Working Days" ❑ 6-9 Days Crd'Standard 10 days ❑ Rush Work Must Be Pre Approved Other N/A� Site Location Name: 3LlGLt-SOA C/>1. ��..{�� Samples received after 15:00 will be processed next business da y. Site Location Physical Address: DI tl ob", WC/ Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES NO (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY WAYPOINT ANALYTICAL, LLC TO CLIENT) SarrTles Iced Upon Collection: - YES_NO CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- ALY Ij �ED ` J "TYPE SAMPLE DESCRIPTION COLLECTED MILITARY WATER, OR TIVESiV A �v ID NO. HOURS SLUDGE) SEE BELOW NO. SIZE Q� O RkK-6+40,Na1a' [o[ka iv JbDD VJ vIZA%►OS '-2,3 V&, `lOu.S'., &OOL it x, Mli�05�.'�3010(2' g-2�o101�0 [d �o b0 66 1r✓ V 4 u Rq liiqi�11111 1 • • Sampler's Signature ampled By (Print Name) 1 1 Affiliation LAB USE ONLY Upon relinquishing, s Chain of Custody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be Site Arrival Time: submitted in writing tot Wa o' t Analytical Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished By: (Signatur Received B ' ignature) Da Military/Hours Additional Comments: Site Departure Time: RBlinquished y: (Sig ture) Received By: (Signatu ) Date gg Field Tech Fee: l Relin ' hed By: i at� ceived For Waypoint Analytical By: Date Mileage: Metho of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTA ION THE LABO ORY. COCK3roUp No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEI ED qT THE LABORATOR . a - ❑ Fed Ex ❑ UPS ❑ Hand -delivered ❑ Waypoint Analytical Field Service ❑ Other —19A • 1 • NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA:.. BRW LD LANDFILL _OTHER: ❑ NC ❑ sc ❑ NC ❑ sc NC LA ❑ NC ❑ SC �C ❑ SC ❑ NC ❑ SC ❑ NC ❑ Sc C :1SC ❑ NC ❑ SC Page 65 of 84 ❑ ❑ ❑ ❑ ❑— �0— ❑ *rnkMAurvo T Mc rnnoc. Tr _ Tnflnn-I inn.4 r-.,_• v^A 17-- u., A Q---- I CHAIN -OF -CUSTODY Analytical Request Document �aceAnalytieal` Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields LAB USE ONLY -Affix Workorder/Login Label Here or List Pace Workorder Number or MTJL Log -in Number Here ALL SHADED AREAS are for LAB USE ONLY Company: � NG Billing Information: U wv " `'� Address: �+ �@ d ( Container Preservative Type ** Lab Project Manager: Report To: Email To: ** Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate, (6) methanol, (7) sodium bisulfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate, (C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other �J Copy To: t CJ Site Collection Info/Address: Analyses Lab Profile/Line: Customer Project Name/Number: I � -SO-C"C I l l✓W/ V L State: County/City: Time Zone Collected: NI 16LCY W [ ] PT [ ] MT [ ] CT ET � y N 4 /J � 19 of S 1 'r'( r 1� Lab Sample Receipt checklist: Custody Seals Present/Intact Y N NA Custody Signatures Present Y N NA Collector Signature Present Y N NA Bottles Intact Y N NA correct Bottles Y N NA Sufficient Volume Y N NA Samples Received on Ice Y N NA VOA - Headspace Acceptable Y N NA USDA Regulated Soils Y N NA Samples in Holding Time Y N NA Residual Chlorine Present Y N NA Cl Strips: Sample pH Acceptable Y N NA pH Strips: Sulfide Present Y N NA Lead Acetate Strips: LAB USE ONLY: Lab Sample # /Comments: Phone: Email: Site/Facility ID #: Compliance Monitoring? 14 Yes [ ] No Collected By (print): Purchase Order #: Quote #: —Dt s�L DW PWS ID #: DW Location Code: C011ecte y na e): Turnaround Date Required: Immediately Packed on Ice: a. [ ]No Sampl Disposal: [ ispose as appropriate [ ] Return [ ] Archive: [ ] Hold: Rush: [ ] Same Day [ ] Next Day [ ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day (Expedite Charges Apply) Field Filtered (if applicable): [ ] Yes [ -4l 0 Analysis: * Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW), Product (P), Soil/Solid [SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT) Customer Sample ID Matrix * Comp / Grab Collected (or Composite Start) Composite End Res Cl # of Ctns Date Time Date Time NL-U�'-�av►ol� v�Jt/k C ►'Dla 8Y, I X M, V _ "a-0 1pl y to t oS S x Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: We Blue Dry None SHORT HOLDS PRESENT (<72 hours): Y N N/A Lab Sample Temperature Info: Temp Blank Received: Y N NA ThermID#: Cooler 1 Temp Upon Receipt: oC Cooler 1 Therm Corr. Factor: oC Cooler 1 Corrected Temp: oC Comments: Packing Material Use Lab Tracking #: 2594653 Radchem sample(s) screened (<500 cpm): Y N NA Samples received via: FEDEX UPS Client Courier Pace Courier Relinquished /Co an : (Signature) Date/Time: Received%�/CCoom�pany: (Signature) Date/Time:) MTJL LAB USE ONLY Table #: Acctnum: Template: Prel gin: 11610'rquisg—ed bb company: (Signature) 1 Date/Time: I y ' / u c�� Received by/Company: TS n—atture) AQ " � Date/Time: V'3 Trip Blank Received: Y N NA HCL McOH TSP Other Relinquished by/Company: (Signature) Date/Time: hJ 0 Received by/Compa . ( gna re) t� ; Date/Time: 0 li •��"�l� l: �L PM: Non Conformance{ YES / NO Page 66 of 84 aceAna lytical D eliver To LELAP CERTIFICATE 116JM ER: 01955 D DO -ELAP ACCREDITNTIO MUM ER: 74960 ANALYTICAL RESULTS A ngie Overcash W aypoint Analytical 4 49 Springbrook Road PO Box 240543 C harlotte, NC 28224 7 04 529 6364 PERFCIRM D BY Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 10/26/2020 Report # 220101613 Project 0100161 dditional Recipients ONE V ISO PJLA '� 7426 Wst ny DOD ELAF f Pace G If Coast Report#: 220101613 1 Page 67 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 eport Date: @/26/2020 Laboratory Endersem nt Saar le analysis was perfoon d in accordance with approveden thodologies provided by the Envirorun ntal Protection Agency or other recognized agencies. The sW les and their corresponding extracts will bean intained for a period of 30 days unless otherwise arranged. Following this retention period the sgan les will be disposed in accordance with Pace G If Coast's Standar¢ O erating Procedures. Corn on Abbreviations that m y be Utilized in this Report ND ndicates the result was Not Detected at the specified reporting lim t NO Indicates the saran le did not ignite when prelim nary test perfoon d for EPPeM thod 1030 DO ndicates the result was Dialed O t IM ndicates the result was subject tcbM trix Interference TNTC ndicateslthe result was Too Nam rous To Count SUBC ndicates the analysis was Sub -Contracted FLD ndicates the analysib was perfoen d in the Field DL etection Liim t D no im t of Detection L @O im t of Q antitation RE e-analysis R CF PLC cEG Confien tion H 00:01 eported ER a *n equivalent to 12:00 AM Reporting Flags that m y be Utilized in this Report J or I ndicates the result is between the[M L andQO J DO flag on analyte in the parent saran le fo0VDW D outside acceptance criteria U ndicates the cgan ound was analyzed for bdt not detected B or V ndicatesl the analyte was detected in the associatedBM thod Blank Q Indicates a non-cqun liarf£Q Result (See Q Flag Application Report) ndicates a non-cqun liant or not applicablCQ rebovery or RPD — see narrative E rganics - The result is estbn ted because it @xceeded the instruen nt calibration range E etals - % diference for the serial dilution is M0% L eporting Lim is adjusted toen et risk -based I5h t. P PD between priffn ry and confian tion resulfds greater than 40 DL iluted analysis — when appended[Bo Client Saran le ID Saar le receipt at Pace G If Coast is docum nted through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written perm ssion of Pace G If Coast. The results contained within this report relate only to the s;frn les reported. The docuen nted results are presented within this report. This report pertains only to the sawn les listed in the Report Sawn le Scam ary and should be retained as a peon nent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the infoon tion contained in this report is prohibited. I certify that this data package is in cgan Hance with The NELAC Institute (TNI) Standard 2009 and teen and conditions of the contract and Statem nt of ft rk both technically and for cgan leteness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the cgnn uter readable data subm tted has been authorized by the Q ality Assuranceam nager or his/her designee, as verified by the following signature. Estbn ted uncertainty ofen asureEn nt is available upon request. This report is in cgzn liance with the DO SQ M as specified in the contract if applicable. Authorized Signature Pace G If Coast Report 220101613 Pace G If Coast Report#: 220101613 1 Page 68 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 Certifications eport Date: @/26/2020 Certification ertification Nuhi er [DO ELAP 4960 Alabam 1955 Arkansas 8-0655 Colorado 1955 Delaware 1955 Florida 87854 G orgia 1955 Hawaii 1955 Idaho 1955 Illinois 00048 Indiana 1955 Kansas -10354 Kentucky 5 Louisiana 1955 M r land 1955 M ssachusetts 1955 M chi an 1955 M ssissippi 1955 M ssouri 1955 M ntana /A Nebraska 1955 NeveM xico 1955 North Carolina 18 North Dakota -195 O lahem 403 South Carolina 3006001 South Dakota 1955 Tennessee 1955 Texas 104704178 Veom nt 1955 Virginia 60215 M shin ton 929 USDA Soil Perm t 330-16-00234 Pace G If Coast Report#: 220101613 1 Page 69 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 Case Narrative Client: Waypoint Analytical Report: 220101613 eport Date: @/26/2020 Pace Analytical G If Coast received and analyzed the spm le(s) listed on the Report Spm le Smn ary page of this report. Receipt of the spm le(s) is docem nted by the attached chain of custody. This applies only to the spm le(s) listed in this report. No spm le integrity or quality control exceptions were identified unless noted below. LYO ATILEA G S CHVRO ATO RAPHY In the AMPOG X analysis for analytical batch 695200p M thane was detected at an estim ted concentration in theem thod blank. This is probable laboratory contem nation. Pace G If Coast Report#: 220101613 1 Page 70 of 84 aceAnaly�ical® r Report#: 20101613 Project ID: @00161 eport Date: m/26/2020 pSa rya lens u m ry LAB ID Client ID atrix ollect Date/Tien 22010161301 W-04-20201012 22010161302 W-04-20201012 (1-12) 22010161303 W-05R-20201012 22010161304 W-07-20201012 22010161305 W-07-20201012 (1-12) Alb 0/12/202013:00 ubdble Strip 0/12/2020 13:00 Mbr 0/12/202014:34 Nbr 0/12/202010:57 ubdble Strip 0/12/2020 10:57 eceive Date/Time 0/ 14/2020 15:05 0/14/202015:05 B 0/ 14/2020 15:05 0/14/2020 15:05 0/14/202015:05 B Pace G If Coast Report#: 220101613 1 Page 71 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 eport Date: @/26/2020 a nSum ry ofpCom ounds Detected Collect Date 10/12/2020 13:00 LAB ID 22010161301 I M-04-20201012 Receive Date 10/14/2020 15:05 M trix VVd ter EPA RSK-175 CAS# aram ter Result DL @O P Units 124-38-9 arbon Dioxide 9300 29340 18000 ug/L AM 3G CAS# aram ter esult L @O P Units 64-19-7 cetic Acid .54 .12 A 0.50 ig /L 64-18-6 orin c Acid .8 .055 F 0.50 ig /L 2A% OG X CAS# aram ter esult L @O P Units 74-82-8 ethane 90 .5 M 5.0 ug/L Collect Date 10/12/2020 13:00 LAB ID 22010161302 I M-04-20201012 (H2) Receive Date 10/14/2020 15:05 M trix Bubble Strip 2A% OG X CAS# aram ter Result DL @O P Units 1333-74-0 ydrogen 0 H 0.49 1.9 nM Collect Date 10/12/2020 14:34 LAB ID 22010161303 I M-05R-20201012 Receive Date 10/14/2020 15:05 M trix V\5 ter EPA RSK-175 CAS# aram ter 124-38-9 arbon Dioxide AM 3G CAS# aram ter 64-19-7 cetic Acid Result DL @O P Units 5300 2590 18000 ug/L esult L QO P Units .2J .2 A 5.0 Kj /L Pace G If Coast Report#: 220101613 1 Page 72 of 84 Report#: 20101613 aceAnalytica! Project ID: 000161 eport Date: m/26/2020 a nSum ry ofpCom ounds Detected Collect Date 10/12/2020 14:34 LAB ID 22010161303 I M-05R-20201012 Receive Date 10/14/2020 15:05 M trix VVa ter 2AM 3G (Continued) CAS# aram ter Result DL @O P Units 64-18-6 ortn c Acid 0 0.55 F 5.0 ig /L 2A% OG X CAS# aram ter esult L GO P Units 74-82-8 ethane 700 .5 M 5.0 ug/L Collect Date 10/12/2020 10:57 LAB ID 22010161304 I M-07-20201012 Receive Date 10/14/2020 15:05 M trix VVa ter EPA RSK-175 CAS# aram ter Result 124-38-9 arbon Dioxide 78000 2AM 3G CAS# aram ter esult 64-19-7 cetic Acid .45J 64-18-6 orin c Acid .8 2A% OG X CAS# aram ter esult 74-82-8 ethane 40 DL @O P Units 2530 18000 ug/L L QO P Units .12 A 0.50 ig /L 055 F 0.50 ig /L L QO P Units .5 M 5.0 ug/L Pace G If Coast Report#: 220101613 1 Page 73 of 84 aceAnaly�ical® r Report#: 20101613 Project ID: @00161 eport Date: m/26/2020 a nSum ry ofpCom ounds Detected Collect Date 10/12/2020 10:57 LAB ID 22010161305 I M-07-20201012 (H2) Receive Date 10/14/2020 15:05 M trix Bubble Strip 2AM OG X CAS# aram ter 1333-74-0 ydrogen Result DL 0 H 0.49 QO P Units 1.9 nM Pace G If Coast Report#: 220101613 1 Page 74 of 84 aceAnaly�ical® r Report#: 20101613 Project ID: (000161 pSam le Results eport Date: m/26/2020 Collect Date 10/12/2020 13:00 LAB ID 22010161301 I M-04-20201012 Receive Date 10/14/2020 15:05 M trix VVd ter 'A RSK-175 Prep Date rep Batch repEM thod P ilution nagrsis Date A y D nalytical Batch NA NA A 0 0/22/202011:13 Rvl 95300 6 CAS# aram ter 124-38-9 arbon Dioxide 2AM 3G Result DL GO P Units 9300 2940 18000 ug/L Prep Date rep Batch repdM thod P ilution naPysis Date A y D nalytical Batch NA NA A 0/22/202010:32 S 95177 6 N CAS# aram ter 64-19-7 cetic Acid 107-92-6 utyric Acid 64-18-6 orin c Acid 142-62-1 exanoic Acid 646-07-1 -Hexanoic Acid 503-74-2 -Pentanoic Acid 50-21-5 actic Acid 109-52-4 entanoic Acid 79-09-4 ropionic Acid 127-17-3 yruvic Acid 2A% OG X 1 esult L 410 P Units .54 .12 A 0.50 ig /L 058U .058 0.50 gn /L .8 .055 F 0.50 ig /L 058U .098 0.50 gn /L 056U .056 0.50 gn /L 061 U .061 0.50 gn /L 053U .053 L 0.50 gn /L 056U .086 0.50 gn /L 053U .053 P 0.50 gn /L 060U .060 0.50 gn /L Prep Date rep Batch repdVl thod P ilution niitysis Date A y D nalytical Batch NA NA A 0/21/202017:52 CK2 95200 6 N CAS# aram ter 74-84-0 thane 74-85-1 thene 74-82-8 ethane A 1 esult L 00 P Units 075U .075 E 1.0 ug/L .121-1 .12 E 1.0 ug/L 90 .5 M 5.0 ug/L Pace G If Coast Report#: 220101613 1 Page 75 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 eport Date: @/26/2020 pSam le Results Collect Date 10/12/2020 13:00 LAB ID 22010161302 I M-04-20201012 (H2) Receive Date 10/14/2020 15:05 M trix Bubble Strip 2AP i X Prep Date rep Batch repeM thod P ilution naPysis Date A y D nalytical Batch NA NA A 0/22/202018:03 VE 95308 6 N CAS# aram ter 1333-74-0 ydrogen 1 Result DL GO P Units 0 H 0.49 1.9 nM Collect Date 10/12/2020 14:34 LAB ID 22010161303 M-05R-20201012 Receive Date 10/14/2020 15:05 M trix VUa ter PA RSK-175 Prep Date rep Batch repdVl thod P ilution nail rsis Date A y D nalytical Batch Ja NA NA A 0 0/22/202011:18 Rvl 95300 6 CAS# 124-38-9 2AM 3G aram ter arbon Dioxide Result DL GO P Units 5300 29340 18000 ug/L Prep Date rep Batch repeM thod P ilution naPysis Date A y D nalytical Batch NA NA A 0 0/22/202011:25 S 95177 6 N CAS# aram ter 64-19-7 cetic Acid 107-92-6 utyric Acid 64-18-6 orin c Acid 142-62-1 exanoic Acid 646-07-1 -Hexanoic Acid 503-74-2 -Pentanoic Acid 50-21-5 actic Acid 109-52-4 entanoic Acid 79-09-4 ropionic Acid 127-17-3 yruvic Acid 2A% OG X Result DL QO P Units .2J 1.2 A 5.0 aq /L .58U OE38 5.0 gn /L 0 0.55 F 5.0 ig /L .58U OM 5.0 gn /L .561-1 Oi56 5.0 gn /L .61 U Oi61 5.0 gn /L .53U 0.53 L 5.0 gn /L .561-1 0P56 5.0 gn /L .53U 0.53 P 5.0 gn /L .60U Of80 5.0 gn /L Prep Date rep Batch repdVl thod P ilution nfflysis Date A y D nalytical Batch NA NA A 0/21/202018:04 CK2 95200 6 N CAS# aram ter 74-84-0 thane A 1 esult L 00 P Units 075U .075 E 1.0 ug/L Pace G If Coast Report#: 220101613 1 Page 76 of 84 acmnalytical Report#: 20101613 Project ID: 000161 pSam le Results eport Date: m/26/2020 Collect Date 10/12/2020 14:34 LAB ID 22010161303 M 05R-20201012 Receive Date 10/14/2020 15:05 M trix VVa ter 2Ar X (Continued) Prep Date rep Batch repEM thod P ilution nfflysis Date A y D nalytical Batch NA NA A 0/21/202018:04 CK2 95200 6 N CAS# arass ter 74-85-1 thene 74-82-8 thane Result DL QO P .12U 0.12 E 1.0 700 2.5 M 5.0 Collect Date 10/12/2020 10:57 LAB ID 22010161304 M 07-20201012 Receive Date 10/14/2020 15:05 M trix VVa ter RSK-175 Prep Date rep Batch repdV1 thod P ilution naFjsis Date A y D nalytical Batch NA NA A 0 0/22/202011:29 Rvl 95300 6 CAS# aram ter 124-38-9 arbon Dioxide 2AM 3G Result DL @O P Units 78000 2930 18000 ug/L Prep Date rep Batch repeM thod P ilution naFysis Date A y D nalytical Batch NA NA A 0/22/202012:18 OS 95177 6 N CAS# arms+ ter 64-19-7 cetic Acid 107-92-6 utyric Acid 64-18-6 orin c Acid 142-62-1 exanoic Acid 646-07-1 -Hexanoic Acid 503-74-2 -Pentanoic Acid 50-21-5 actic Acid 109-52-4 entanoic Acid 79-09-4 ropionic Acid 127-17-3 yruvic Acid 1 esult L CIO P Units .45J .12 A 0.50 g /L 058U .058 0.50 gn /L .8 .055 F 0.50 g /L 058U .0198 0.50 gn /L 056U .056 0.50 gn /L 061 U .061 0.50 gn /L 053U .053 L 0.50 gn /L 056U .0136 0.50 gn /L 053U .053 P 0.50 gn /L 060U 090 0.50 gn /L Pace G If Coast Report#: 220101613 1 Page 77 of 84 aceAnaly�ical® r Report#: 20101613 Project ID: @00161 pSam le Results eport Date: m/26/2020 Collect Date 10/12/2020 10:57 LAB ID 22010161304 M 07-20201012 Receive Date 10/14/2020 15:05 M trix VVa ter 2Ar X Prep Date rep Batch repdN thod P ilution ndTysis Date A y D nalytical Batch NA NA A 0/21/202018:16 CK2 95200 6 N CAS# aram ter 74-84-0 thane 74-85-1 thene 74-82-8 thane A 1 esult L @O P Units 075U .075 E 1.0 ug/L .12U .12 E 1.0 ug/L 40 .5 M 5.0 ug/L Collect Date 10/12/2020 10:57 LAB ID 22010161305 M 07-20201012 (H2) Receive Date 10/14/2020 15:05 dJl trix Bubble Strip 2Ar X Prep Date rep Batch repeM thod P ilution naPysis Date A y D nalytical Batch NA NA A 0/22/202018:15 VE 95308 6 N CAS# aram ter 1333-74-0 ydrogen 1 Result DL QO P Units 0 H 0.49 1.9 nM Pace G If Coast Report#: 220101613 1 Page 78 of 84 ac6Anaoical Report#: 20101613 11!® r Project ID: @00161 C G Voldtiles Q nSum ry eport Date: @/26/2020 Analytical Batch Client ID MB695300 LCS695300 LCSD695300 695300 LAB ID 2099792 2099793 2099794 Senn le Type W LCS LCSD Prep Date Analysis Date 10/22/20 09:47 10/22/20 09:56 10/22/20 10:01 aM trix Wa ter Wa ter Wa ter EPA RSK-175 Units ug/L I Spike Result ,n Control Spike Result 'R RPD RPD Result DLI Added Lim ts'R 1 Added Lim t Carbon Dioxide 24-38-9 27UI 1271 87001 9070 11041 38 - 147 1 7001 9570 1-001 5 1 0 Pace G If Coast Report#: 220101613 1 Page 79 of 84 ac6Anaoical Report#: 20101613 11!® Project ID: @00161 G neral CherEstryO rfbum ry eport Date: @/26/2020 Analytical Batch Client ID MB695177 LCS695177 LCSD695177 695177 LAB ID 2099261 2099262 2099263 Selnn le Type W LCS LCSD Prep Date Analysis Date 10/22/20 09:38 10/22/20 08:45 10/22/20 20:46 aM trix VVa ter VVa ter VVa ter ARM 3G Units gn /L Spike Result IR Control Spike Result 1R RPD RPD Result DL Added Lim tS(R Added Lim t Acetic Acid 4-19-7 .12U 0.12 2.0 2.0 99 A - 130 .0 C2.0 101 3 0 Butyric Acid 07-92-6 .058U 0.058 2.0 2.0 102 70 - 130 C .0 2.1 103 1 0 Form c Acid 4-18-6 .055U 0.055 2.0 2.0 100 70-130 0 .0 2.0 101 1 0 Hexanoic Acid 42-62-1 .058U 0.058 2.0 1.9 97 A - 130 C .0 2.0 100 3 0 i-Hexanoic Acid 46-07-1 .056U 0.056 2.0 2.0 99 A - 130 C .0 2.0 101 2 0 i-Pentanoic Acid 03-74-2 .061 U 0.061 2.0 2.0 102 70 - 130 C .0 2.1 103 1 0 Lactic Acid 0-21-5 .053U 0.053 2.0 1.9 96 A - 130 0 .0 1.9 97 1 0 Pentanoic Acid 09-52-4 .056U 0.056 2.0 2.0 98 A - 130 C .0 2.0 99 1 0 Propionic Acid 9-09-4 .053U 0.053 2.0 2.0 100 70-130 0 .0 2.0 102 2 0 Pyruvic Acid 27-17-3 .060U 0.060 2.0 1.7 87 A - 130 C .0 1.8 89 2 0 Pace G If Coast Report#: 220101613 1 Page 80 of 84 ac6Anaoical Report#: 20101613 11!® Project ID: @00161 G neral Unrom togrOphyQ nSum ry eport Date: @/26/2020 Analytical Batch Client ID MB695308 LCS695308 LCSD695308 695308 LAB ID 2099843 2099844 2099845 Senn le Type LCS LCSD Prep Date Analysis Date 10/22/20 16:01 10/22/20 16:13 10/22/20 16:25 aM trix ARM AG X Units nM Spike I Result Control Spike Result `R I RPD I RPD I Result DLI Added Lim tsR I Added Lim t Hydrogen 333-74-0 .49U 1 0.491 121 12 199 1 70 - 130 1 210 1211021 0 Analytical Batch Client ID MB695200 LCS695200 LCSD695200 695200 LAB ID 2099339 2099340 2099341 Senn le Type W LCS LCSD Prep Date Analysis Date 10/21/20 15:05 10/21/20 13:42 10/21/20 13:54 aM trix Wa ter V\1a ter VUa ter ARM AOG X Units ug/L Spike I Result IR Control Spike Result IR RPD RPD Result DL Added Lim is R Added Lim t Ethane 74-84-0 .075U 0.075 100 99 98 A - 130 0 00 110 109 11 1 0 Ethene 74-85-1 .12U 0.12 140 140 95 A - 130 40 050 106 11 1 0 thane 74-82-8 .2J 2.5 490 460 94 70-130 90 510 104 9 3 4 0 Pace G If Coast Report#: 220101613 1 Page 81 of 84 O Q � ❑ v o o v LA th U J tJ O N O Q 3 Ol 40 C> b b b b A A A A A A A 4i x e > x � d m t m 8 e 4 4 0 o W rn rn a w c c a o 0 o c o rab Cl Co 0 Cl w .a -0 ^d (nr• -o ::� O-7e 4 N ❑� w O tJ ro Y'tino p jo toW Q 0.f Q a L C w Pace G If Coast Report#: 220101613 Page 16 of 18 0 2:I?D 1 ^n uv cQ (D eo W Si 00, Pace G If Coast Report#: 220101613 n n nx [ � nxr 6 'C7 gRL W m O 7 CL a s n o iv' t> o ra p eo' b n rp 0 CD v w N N m m s b a o 0 o a c v o 0 o a w c c 0 6 6 ¢ 0 t+, rS r ¢ 0 o O O c o 0 0 a o 0 0 Z.� Ln U. o a ? k. Z w �, w w Li �1 -4 -d vi J w i„ w U, 4� A A 4. L4 1a o c c c C7 O 4 O Z C" oa �n 41 n 0, 1 w ro w LA W a 0 C n w nmO n 0 r h n pop r r0 T 0 0 3 � N [l1 a i] o rn N w � 6 z > Page 17 of 18 a �.paiyres p SFM LE RECEIVING CHECKLIST IINNYIIIIIIVI SAMPLE DELIVERY GROUP 220101613 CHECKLIST ES O Client PM RWe ransport Method T Samples received with proper thermal preservation? 0 ❑ PrisniabNC- Waypoint F®E X Analytical Radioactivity is <1600 cpm? If no, record cpm value in notes section. COC relinquished and complete (including samplelDs, collect times, and sampler)? 0 Q Profileftm er Received By 284507 N/bane, Dodie Ni All containers received in good condition and within hold time? All sample labels and containers received match the chain of custody? 0 0 Line(Item s) Receive Date(s) 2 - Hydrogen 10/14/20 6 - VFA, IVY. CC2 Preservative added to any containers? 0 If received, was headspace for VOC water containers < 6mm? 0 Samples collected in containers provided by Pace Gulf Coast? 0 COOLERS DISCREPANCIES LAB PRESERVATIONS Airbill Tberei m ter ID: E26 pTem °C None None 771788277750 1.0 NOTES Revision 1.6 Page 1 of 1 Pace G If Coast Report#: 220101613 Page 18 of 18 Way poi nt ANALYTICAL Anchor QEA of North Carolina, PLLC Alec Macbeth 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill 2020 Fall Project No.: 50-02 Lab Submittal Date: 10/14/2020 Work Order: 0100174 Case Narrative 12/31/20 13:17 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a,-1 Angela D. Overcash Senior Project Manager This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 62 Data Qualifiers Key Reference: CCV CCV result is above the control limits. Analyte not detected in the sample. No further action taken. DC The RPD between the primary and confirmation column concentrations is greater than 40. The result is reported from the primary column. DID Difference between sample dilutions is greater than 30%. HA Sample analyzed outside of hold time. HT Sample received and analyzed outside of the hold time. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L Parameter reported with possible low bias. LCS recovery below the QC limit. LCD2 LCS/LCSD RPD Value outside of the control limits. LCS and LCSD Values within the control limits. LH High LCS recovery. Analyte not detected in the sample(s). No further action taken. MI Matrix spike outside of the control limits. Matrix interference suspected. SR Surrogate recovery outside of the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 62 1 Q Waypoint.. ANALYTICAL Sample Receipt Summary 12/31 /2020 Work Order: 0100174 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-02-20201013 0100174-01 Water MW-03-20201013 0100174-02 Water MW-06-20201013 0100174-03 Water TB-202010130000 0100174-04 Water Samples were received in good condition at 2.0 degrees C unless otherwise noted 10/13/20 14:50 10/13/20 10:29 10/13/20 13:15 10/13/20 0:00 10/14/20 9:10 10/14/20 9:10 10/14/20 9:10 10/14/20 9:10 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 62 Way poi nt ANALYTICAL Summary of Detections 12/31/202C Work Order: 0100174 Prism ID Client ID Parameter Method Result Units 0100174-01 MW-02-20201013 Chloride 9056A 25000 ug/L 0100174-01 MW-02-20201013 Nitrate as N 9056A 170 J ug/L 0100174-01 MW-02-20201013 Sulfate 9056A 20000 ug/L 0100174-01 MW-02-20201013 Barium 6020B 24 ug/L 0100174-01 MW-02-20201013 Beryllium 6020B 0.20 J ug/L 0100174-01 MW-02-20201013 Nickel 6020B 0.81 J ug/L 0100174-01 MW-02-20201013 Selenium 6020B 1.3 J ug/L 0100174-01 MW-02-20201013 Biochemical Oxygen Demand SM5210 B 2300 ug/L 0100174-01 MW-02-20201013 Chemical Oxygen Demand SM5220 D 37000 J ug/L 0100174-01 MW-02-20201013 pH SM4500-H B 7.1 HT pH Units 0100174-01 MW-02-20201013 Temperature SM2550 B 20.5 HT °C 0100174-01 MW-02-20201013 Total Alkalinity to pH 4.5 SM2320 B 55000 ug/L 0100174-01 MW-02-20201013 Diethyl phthalate 8270D 4.65 J pg/L 0100174-01 MW-02-20201013 Mercury 7470A 0.87 ug/L 0100174-01 MW-02-20201013 Arsenic 6020B 7.5 ug/L 0100174-01 MW-02-20201013 Barium 6020B 250 ug/L 0100174-01 MW-02-20201013 Beryllium 6020B 1.6 ug/L 0100174-01 MW-02-20201013 Chromium 6020B 61 ug/L 0100174-01 MW-02-20201013 Cobalt 6020B 60 ug/L 0100174-01 MW-02-20201013 Copper 6020B 61 ug/L 0100174-01 MW-02-20201013 Lead 6020B 14 ug/L 0100174-01 MW-02-20201013 Nickel 6020B 44 ug/L 0100174-01 MW-02-20201013 Selenium 6020B 42 ug/L 0100174-01 MW-02-20201013 Silver 6020B 0.11 J ug/L 0100174-01 MW-02-20201013 Thallium 6020B 0.96 .1 ug/L 0100174-01 MW-02-20201013 Vanadium 6020B 71 ug/L 0100174-01 MW-02-20201013 Zinc 6020B 140 ug/L 0100174-01 MW-02-20201013 TOC 531OC-2011 2.26 mg/L 0100174-01 MW-02-20201013 1,1-Dichloroethane 8260D 0.29 J ug/L 0100174-01 MW-02-20201013 cis-1,2-Dichloroethylene 8260D 0.38 J ug/L 0100174-01 MW-02-20201013 m,p-Xylenes 8260D 0.21 J ug/L 0100174-01 MW-02-20201013 Xylenes, total 8260D 0.21 J ug/L 0100174-01 MW-02-20201013 1,4-Dioxane 8260D SIM 2.8 ug/L 0100174-02 MW-03-20201013 Chloride 9056A 8500 ug/L 0100174-02 MW-03-20201013 Nitrate as N 9056A 8300 ug/L 0100174-02 MW-03-20201013 Sulfate 9056A 4000 ug/L 0100174-02 MW-03-20201013 Biochemical Oxygen Demand SM5210 B 2000 DID ug/L 0100174-02 MW-03-20201013 Chemical Oxygen Demand SM5220 D 35000 J ug/L 0100174-02 MW-03-20201013 pH SM4500-H B 8.1 HT pH Units 0100174-02 MW-03-20201013 Temperature SM2550 B 20.3 HT °C 0100174-02 MW-03-20201013 Total Alkalinity to pH 4.5 SM2320 B 140000 ug/L 0100174-02 MW-03-20201013 1,2-Dichlorobenzene 8270D 0.843 J pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 62 Waypoint. ANALYTICAL Summary of Detections 12/31/202C Work Order: 0100174 Prism ID Client ID Parameter Method Result Units 0100174-02 MW-03-20201013 1,3-Dichlorobenzene 8270D 0.791 J pg/L 0100174-02 MW-03-20201013 1,4-Dichlorobenzene 8270D 0.746 J pg/L 0100174-02 MW-03-20201013 Mercury 7470A 1.1 ug/L 0100174-02 MW-03-20201013 Arsenic 6020B 0.31 J ug/L 0100174-02 MW-03-20201013 Barium 6020B 110 ug/L 0100174-02 MW-03-20201013 Chromium 6020B 0.86 J ug/L 0100174-02 MW-03-20201013 Cobalt 6020B 0.59 J ug/L 0100174-02 MW-03-20201013 Copper 6020B 3.8 J ug/L 0100174-02 MW-03-20201013 Nickel 6020B 0.96 J ug/L 0100174-02 MW-03-20201013 TOC 531OC-2011 4.68 mg/L 0100174-02 MW-03-20201013 m,p-Xylenes 8260D 0.37 J ug/L 0100174-02 MW-03-20201013 Xylenes, total 8260D 0.37 J ug/L 0100174-03 MW-06-20201013 Chloride 9056A 1100 ug/L 0100174-03 MW-06-20201013 Nitrate as N 9056A 96 J ug/L 0100174-03 MW-06-20201013 Sulfate 9056A 830 J ug/L 0100174-03 MW-06-20201013 Biochemical Oxygen Demand SM5210 B 280 J ug/L 0100174-03 MW-06-20201013 pH SM4500-H B 7.1 HT pH Units 0100174-03 MW-06-20201013 Temperature SM2550 B 20.0 HT °C 0100174-03 MW-06-20201013 Total Alkalinity to pH 4.5 SM2320 B 24000 ug/L 0100174-03 MW-06-20201013 beta-BHC 8081B 0.14 DC ug/L 0100174-03 MW-06-20201013 1,4-Dichlorobenzene 8270D 0.779 .1 pg/L 0100174-03 MW-06-20201013 Diethyl phthalate 8270D 0.709 J pg/L 0100174-03 MW-06-20201013 Mercury 7470A 1.3 ug/L 0100174-03 MW-06-20201013 Barium 6020B 47 ug/L 0100174-03 MW-06-20201013 Cobalt 6020B 9.0 ug/L 0100174-03 MW-06-20201013 Nickel 6020B 3.4 ug/L 0100174-03 MW-06-20201013 Zinc 6020B 20 ug/L 0100174-03 MW-06-20201013 TOC 531OC-2011 1.04 mg/L 0100174-03 MW-06-20201013 1,1-Dichloroethane 8260D 1.4 ug/L 0100174-03 MW-06-20201013 1,4-Dichlorobenzene 8260D 2.6 ug/L 0100174-03 MW-06-20201013 Benzene 8260D 0.26 J ug/L 0100174-03 MW-06-20201013 Chlorobenzene 8260D 0.41 J ug/L 0100174-03 MW-06-20201013 cis-1,2-Dichloroethylene 8260D 1.4 ug/L 0100174-03 MW-06-20201013 m,p-Xylenes 8260D 0.37 .1 ug/L 0100174-03 MW-06-20201013 o-Xylene 8260D 0.29 J ug/L 0100174-03 MW-06-20201013 Tetrachloroethylene 8260D 0.25 J ug/L 0100174-03 MW-06-20201013 Xylenes, total 8260D 0.66 J ug/L 0100174-04 TB-202010130000 Acetone 8260D 3.0 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 62 Laboratory Report IL A i • . 0 12/31/2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 25000 ug/L NE 1000 350 1 9056A 10/14/20 18:39BMS POJ0250 Nitrate as N 170 J ug/L 10000 200 45 1 9056A 10/14/20 18:39BMS POJ0250 Sulfate 20000 ug/L 250000 2000 560 1 9056A 10/14/20 18:39BMS POJ0250 Dissolved Metals Mercury <0.034 HA ug/L 0.20 0.034 1 7470A 12/28/20 16:31MMR POL0504 Antimony <0.49 ug/L 2.0 0.49 1 6020B 12/30/20 22:3WAB POL0558 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 12/30/20 22:30JAB POL0558 Barium 24 ug/L 100 10 0.81 1 6020B 12/30/20 22:30JAB POL0558 Beryllium 0.20 J ug/L 1.0 0.19 1 6020B 12/30/20 22:30JAB POL0558 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 12/30/20 22:30JAB POL0558 Chromium <0.79 ug/L 2.0 0.79 1 6020B 12/30/20 22:30JAB POL0558 Cobalt <0.52 ug/L 2.0 0.52 1 6020B 12/30/20 22:30JAB POL0558 Copper <3.8 ug/L 10 3.8 1 6020B 12/30/20 22:30JAB POL0558 Lead <0.26 ug/L 1.0 0.26 1 6020B 12/30/20 22:30JAB POL0558 Nickel 0.81 J ug/L 50 3.0 0.51 1 6020B 12/30/20 22:30JAB POL0558 Selenium 1.3 J ug/L 10 5.0 0.74 1 6020B 12/30/20 22:30JAB POL0558 Silver <0.11 ug/L 1.0 0.11 1 6020B 12/30/20 22:30JAB POL0558 Thallium <0.57 ug/L 2.0 0.57 1 6020B 12/30/20 22:30JAB POL0558 Tin <1.8 ug/L 5.0 1.8 1 6020B 12/30/20 22:30JAB POL0558 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 12/30/20 22:30JAB POL0558 Zinc <6.9 ug/L 20 6.9 1 6020B 12/30/20 22:30JAB POL0558 General Chemistry Parameters Biochemical Oxygen Demand 2300 ug/L NE 2000 210 1 SM5210 B 10/14/20 17:01 ENM POJ0276 Chemical Oxygen Demand 37000 J ug/L NE 50000 11000 1 SM5220 D 10/19/20 11:56SLS POJ0361 Cyanide <0.014 mg/L 10 0.025 0.014 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron <46 HT ug/L NE 200 46 1 SM3500-Fe B 10/15/20 9:51 ENM POJ0282 pH 7.1 HT pH Units NE 1 SM4500-H B 12/18/20 11:30CLB POL0392 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02ENM POJ0337 Temperature 20.5 HT °C 1 SM2550 B 12/18/20 11:30CLB POL0392 Total Alkalinity to pH 4.5 55000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081 B 10/19/20 11:57NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/19/20 11:57NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/19/20 11:57NMB POJ0286 Aldrin <0.016 ug/L 0.05 0.052 0.016 1 8081 B 10/19/20 11:57NMB POJ0286 alpha-BHC <0.0065 ug/L 0.05 0.052 0.0065 1 8081 B 10/19/20 11:57NMB POJ0286 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 11:57NMB POJ0286 beta-BHC <0.011 ug/L 0.05 0.052 0.011 1 8081 B 10/19/20 11:57NMB POJ0286 Chlordane <0.19 ug/L 0.5 0.52 0.19 1 8081 B 10/19/20 11:57NMB POJ0286 delta-BHC <0.0085 ug/L 0.05 0.052 0.0085 1 8081 B 10/19/20 11:57NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.052 0.014 1 8081 B 10/19/20 11:57NMB POJ0286 Endosulfan I <0.016 ug/L 0.1 0.052 0.016 1 8081 B 10/19/20 11:57NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.052 0.012 1 8081 B 10/19/20 11:57NMB POJ0286 Endosulfan Sulfate <0.017 ug/L 0.1 0.052 0.017 1 8081 B 10/19/20 11:57NMB POJ0286 Endrin <0.014 ug/L 0.1 0.052 0.014 1 8081 B 10/19/20 11:57NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.052 0.016 1 8081 B 10/19/20 11:57NMB POJ0286 Endrin Ketone <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 11:57NMB POJ0286 gamma-BHC <0.0063 ug/L 0.05 0.052 0.0063 1 8081 B 10/19/20 11:57NMB POJ0286 trans -Chlordane <0.024 ug/L NE 0.10 0.024 1 8081 B 10/19/20 11:57NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.052 0.013 1 8081 B 10/19/20 11:57NMB POJ0286 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081 B 10/19/20 11:57NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 11:57NMB POJ0286 Toxaphene <0.36 ug/L 1.5 1.0 0.36 1 8081 B 10/19/20 11:57NMB POJ0286 Surrogate Recovery Control Limits Decachlorobiphenyl 51 % 13-186 Tetrachloro-m-xylene 70 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.22 ug/L NE 0.52 0.22 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.52 0.16 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.52 0.14 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.52 0.14 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.52 0.16 1 8082A 10/19/20 11:57NMB POJ0286 Aroclor 1260 <0.51 ug/L NE 1.0 0.51 1 8082A 10/19/20 11:57NMB POJ0286 Surrogate Recovery Control Limits Tetrachloro-m-xylene 68 % 30-161 Decachlorobiphenyl 53 % 32-178 Total Metals Mercury 0.87 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:26EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 16:35JAB POJ0239 Arsenic 7.5 ug/L 10 1.0 0.17 1 6020B 10/23/20 16:35JAB POJ0239 Barium 250 ug/L 100 2.0 0.81 1 6020B 10/23/20 16:35JAB POJ0239 Beryllium 1.6 ug/L 1 1.0 0.19 1 6020B 10/27/20 11:44JAB POJ0239 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/23/20 16:35JAB POJ0239 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 62 . Laboratory Report • � Waynt.� 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chromium 61 ug/L 10 2.0 0.79 1 6020B 10/23/20 16:35JAB POJ0239 Cobalt 60 ug/L 10 2.0 0.52 1 6020B 10/23/20 16:35JAB POJ0239 Copper 61 ug/L 10 10 3.8 1 6020B 10/23/20 16:35JAB POJ0239 Lead 14 ug/L 10 1.0 0.26 1 6020B 10/23/20 16:35JAB POJ0239 Nickel 44 ug/L 50 3.0 0.51 1 6020B 10/23/20 16:35JAB POJ0239 Selenium 42 ug/L 10 5.0 0.74 1 6020B 10/23/20 16:35JAB POJ0239 Silver 0.11 J ug/L 10 1.0 0.11 1 6020B 10/27/20 18:40JAB POJ0490 Thallium 0.96 J ug/L 5.5 2.0 0.38 1 6020B 10/23/20 16:35JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 16:35JAB POJ0239 Vanadium 71 ug/L 25 5.0 1.3 1 6020B 10/23/20 16:35JAB POJ0239 Zinc 140 ug/L 10 20 6.9 1 6020B 10/23/20 16:35JAB POJ0239 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 19:09JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 19:09JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 19:09JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 19:09JLB POJ0321 1,1-Dichloroethane 0.29 J ug/L 5 0.50 0.083 1 8260D 10/21/20 19:09JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 19:09JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 19:09JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 19:09JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 19:09JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 19:09JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 19:09JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 19:09JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 19:09JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 19:09JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 19:09JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 19:09JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 19:09JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 19:09JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 19:09JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 19:09JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 19:09JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 19:09JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 19:09JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 19:09JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 19:09JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 19:09JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 19:09JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 19:09JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 19:09JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 19:09JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 19:09JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 19:09JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 19:09JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 19:09JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 19:09JLB POJ0321 cis-1,2-Dichloroethylene 0.38 J ug/L 2 0.50 0.056 1 8260D 10/21/20 19:09JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 19:09JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 19:09JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 19:09JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 19:09JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 19:09JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 19:09JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 19:09JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 19:09JLB POJ0321 m,p-Xylenes 0.21 J ug/L NE 1.0 0.12 1 8260D 10/21/20 19:09JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 19:09JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 19:09JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 19:09JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 19:09JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 19:09JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 19:09JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 19:09JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 19:09JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 19:09JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 19:09JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 19:09JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 19:09JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 19:09JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 19:09JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 19:09JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 19:09JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 19:09JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 19:09JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 62 . Laboratory Report • � Waynt.� 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 19:09JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 19:09JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 19:09JLB POJ0321 Xylenes, total 0.21 J ug/L 5 1.5 0.15 1 8260D 10/21/20 19:09JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 107 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 2.8 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 21:38ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 L517325 1,4-Naphthoqu!none U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 1-Naphthylamine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 2-Acetylaminofluorene U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 2-Naphthylamine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 3-Methylcholanthrene U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 4-Aminobiphenyl U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 5-Nitro-o-toluidine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 7,12-Dimethyl benz(a)anthrace ne U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Diallate U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Hexachloropropene U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Isosafrole U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Kepone U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 Methapyrilene U Ng/L 20.6 10.3 1 8270D 10/20/20 18:29BGV L517325 N-Nitrosomethylethylamine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 N-Nitrosopiperidine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 N-Nitrosopyrrolidine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 o-Toluidine U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 p-Dimethylaminoazobenzene U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 p-Phenylenediamine U L Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Pronamide U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29BGV L517325 Safrole U Ng/L 10.3 10.3 1 8270D 10/20/20 18:29 BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T U Ng/L 0.03 0.01002 1 8151A 10/21/20 0:42 VIC L517362 2,4,5-TP (Silvex) U Ng/L 0.1 0.01634 1 8151A 10/21/20 0:42 VIC L517362 2,4-D U Ng/L 0.25 0.2078 1 8151A 10/21/20 0:42 VIC L517362 2,4-DB U Ng/L 0.1 0.1364 1 8151A 10/21/20 0:42 VIC L517362 Dalapon U Ng/L 0.55 0.5149 1 8151A 10/21/20 0:42 VIC L517362 Dicamba U Ng/L 0.1 0.057 1 8151A 10/21/20 0:42 VIC L517362 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 62 . Laboratory Report • � Waynt.� 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Dichlorprop U Ng/L 0.1 0.07959 1 8151A 10/21/20 0:42 VIC L517362 Dinoseb U Ng/L 0.1 0.02698 1 8151A 10/21/20 0:42 VIC L517362 MCPA U Ng/L 50 18.98 1 8151A 10/21/20 0:42 VIC L517362 MCPP U Ng/L 50 11.75 1 8151A 10/21/20 0:42 VIC L517362 Picloram U Ng/L 0.1 0.04528 1 8151A 10/21/20 0:42 VIC L517362 Surrogate Recovery Control Limits DCAA 66.2 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene U Ng/L 5.15 0.326 1 8270D 10/20/20 18:29BGV L517328 1,2,4-Trichlorobenzene U Ng/L 5.15 0.496 1 8270D 10/20/20 18:29BGV L517328 1,2-Dichlorobenzene U Ng/L 5.15 0.647 1 8270D 10/20/20 18:29BGV L517328 1,3-Dichlorobenzene U pg/L 5.15 0.505 1 8270D 10/20/20 18:29BGV L517328 1,4-Dichlorobenzene U Ng/L 5.15 0.597 1 8270D 10/20/20 18:29BGV L517328 2,3,4,6-Tetrachlorophenol U Ng/L 5.15 0.365 1 8270D 10/20/20 18:29 BGV L517328 2,4,5-Trichlorophenol U Ng/L 5.15 0.36 1 8270D 10/20/20 18:29 BGV L517328 2,4,6-Trichlorophenol U Ng/L 5.15 0.354 1 8270D 10/20/20 18:29 BGV L517328 2,4-Dichlorophenol U Ng/L 5.15 1.57 1 8270D 10/20/20 18:29BGV L517328 2,4-Dimethylphenol U Ng/L 5.15 0.694 1 8270D 10/20/20 18:29BGV L517328 2,4-Dinitrophenol U Ng/L 10.3 5 1 8270D 10/20/20 18:29BGV L517328 2,4-Dinitrotoluene U Ng/L 5.15 0.415 1 8270D 10/20/20 18:29BGV L517328 2,6-Dichlorophenol U Ng/L 5.15 0.724 1 8270D 10/20/20 18:29BGV L517328 2,6-Dinitrotoluene U Ng/L 5.15 0.425 1 8270D 10/20/20 18:29BGV L517328 2-Chloronaphthalene U Ng/L 5.15 0.49 1 8270D 10/20/20 18:29BGV L517328 2-Chlorophenol U Ng/L 5.15 0.758 1 8270D 10/20/20 18:29BGV L517328 2-Methyl naphthalene U Ng/L 2.06 0.499 1 8270D 10/20/20 18:29BGV L517328 2-Methylphenol U Ng/L 5.15 0.742 1 8270D 10/20/20 18:29BGV L517328 2-Nitroaniline U Ng/L 5.15 0.591 1 8270D 10/20/20 18:29BGV L517328 2-Nitrophenol U Ng/L 5.15 0.624 1 8270D 10/20/20 18:29 BGV L517328 3&4 Methylphenol U Ng/L 5.15 0.711 1 8270D 10/20/20 18:29BGV L517328 3,3' Dimethylbenzidine U Ng/L 10.3 1.94 1 8270D 10/20/20 18:29 BGV L517328 3,3'-Dichlorobenzidine U Ng/L 10.3 3.85 1 8270D 10/20/20 18:29BGV L517328 3-Nitroaniline U Ng/L 10.3 1.58 1 8270D 10/20/20 18:29BGV L517328 4,6-Dinitro-2-methylphenol U Ng/L 10.3 3.57 1 8270D 10/20/20 18:29BGV L517328 4-Bromophenyl phenyl ether U Ng/L 5.15 0.515 1 8270D 10/20/20 18:29BGV L517328 4-Chloro-3-methylphenol U Ng/L 5.15 0.518 1 8270D 10/20/20 18:29BGV L517328 4-Chloroaniline U Ng/L 5.15 0.541 1 8270D 10/20/20 18:29BGV L517328 4-Chlorophenyl phenyl ether U Ng/L 5.15 0.493 1 8270D 10/20/20 18:29 BGV L517328 4-Nitroaniline U Ng/L 5.15 0.762 1 8270D 10/20/20 18:29BGV L517328 4-Nitrophenol U Ng/L 10.3 1.43 1 8270D 10/20/20 18:29 BGV L517328 Acenaphthene U Ng/L 2.06 0.434 1 8270D 10/20/20 18:29 BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 62 ® Laboratory Report IL AL i • . 12/31 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acenaphthylene U pg/L 2.06 0.441 1 8270D 10/20/20 18:29BGV L517328 Acetophenone U pg/L 5.15 0.706 1 8270D 10/20/20 18:29BGV L517328 Aniline U pg/L 5.15 0.325 1 8270D 10/20/20 18:29BGV L517328 Anthracene U pg/L 2.06 0.481 1 8270D 10/20/20 18:29BGV L517328 Benzidine U pg/L 20.6 0.709 1 8270D 10/20/20 18:29BGV L517328 Benzo(a)anthracene U pg/L 2.06 0.439 1 8270D 10/20/20 18:29BGV L517328 Benzo(a)pyrene U pg/L 2.06 1.03 1 8270D 10/20/20 18:29BGV L517328 Benzo(b)fluoranthene U pg/L 2.06 0.969 1 8270D 10/20/20 18:29BGV L517328 Benzo(g,hJ)perylene U pg/L 2.06 1.4 1 8270D 10/20/20 18:29BGV L517328 Benzo(k)fluoranthene U pg/L 2.06 0.774 1 8270D 10/20/20 18:29BGV L517328 Benzoic Acid U pg/L 10.3 5.15 1 8270D 10/20/20 18:29 BGV L517328 Benzyl alcohol U pg/L 10.3 3.1 1 8270D 10/20/20 18:29BGV L517328 Bis(2-Chloroethoxy)methane U pg/L 5.15 0.445 1 8270D 10/20/20 18:29BGV L517328 Bis(2-Chloroethyl)ether U pg/L 5.15 0.46 1 8270D 10/20/20 18:29BGV L517328 Bis(2-Chloroisopropyl)ether U pg/L 5.15 0.562 1 8270D 10/20/20 18:29BGV L517328 Bis(2-ethylhexyl)phthalate U pg/L 5.15 3.77 1 8270D 10/20/20 18:29BGV L517328 Butyl benzyl phthalate U pg/L 5.15 4.73 1 8270D 10/20/20 18:29BGV L517328 Carbazole U pg/L 5.15 0.49 1 8270D 10/20/20 18:29BGV L517328 Chrysene U pg/L 2.06 0.752 1 8270D 10/20/20 18:29BGV L517328 Dibenz(a,h)anthracene U pg/L 2.06 0.259 1 8270D 10/20/20 18:29BGV L517328 Dibenzofuran U pg/L 5.15 0.435 1 8270D 10/20/20 18:29BGV L517328 Diethyl phthalate 4.65 j pg/L 5.15 0.602 1 8270D 10/20/20 18:29BGV L517328 Dimethyl phthalate U pg/L 5.15 0.525 1 8270D 10/20/20 18:29BGV L517328 Di-n-butyl phthalate U pg/L 5.15 1.62 1 8270D 10/20/20 18:29BGV L517328 Di-n-Octyl Phthalate U pg/L 5.15 1.77 1 8270D 10/20/20 18:29BGV L517328 Fluoranthene U pg/L 2.06 0.418 1 8270D 10/20/20 18:29BGV L517328 Fluorene U pg/L 2.06 0.457 1 8270D 10/20/20 18:29BGV L517328 Hexachlorobenzene U pg/L 5.15 2.65 1 8270D 10/20/20 18:29BGV L517328 Hexachlorobutadiene U pg/L 5.15 0.417 1 8270D 10/20/20 18:29BGV L517328 Hexachlorocyclopentadiene U pg/L 5.15 2.41 1 8270D 10/20/20 18:29BGV L517328 Hexachloroethane U pg/L 5.15 0.285 1 8270D 10/20/20 18:29BGV L517328 Indeno(1,2,3-cd)pyrene U pg/L 2.06 1.04 1 8270D 10/20/20 18:29BGV L517328 Isophorone U pg/L 5.15 0.37 1 8270D 10/20/20 18:29BGV L517328 Naphthalene U pg/L 2.06 0.498 1 8270D 10/20/20 18:29BGV L517328 Nitrobenzene U pg/L 5.15 0.546 1 8270D 10/20/20 18:29BGV L517328 N-Nitrosodiethylamine U pg/L 5.15 0.412 1 8270D 10/20/20 18:29BGV L517328 N-Nitrosodimethylamine U pg/L 5.15 0.256 1 8270D 10/20/20 18:29BGV L517328 N-Nitroso-di-n-butylamine U pg/L 5.15 0.774 1 8270D 10/20/20 18:29BGV L517328 N-Nitroso-di-n-propylamine U pg/L 5.15 0.344 1 8270D 10/20/20 18:29BGV L517328 N-Nitrosodiphenylamine U pg/L 10.3 0.806 1 8270D 10/20/20 18:29BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-02-20201013 Attn: Alec Macbeth Sample ID: 0100174-01 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 14:50 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Pentachlorophenol U Ng/L Phenanthrene U Ng/L Phenol U Ng/L Pyrene U Ng/L Pyridine U ua/L Total Organic Carbon TOC 2.26 mg/L 10.3 2.52 1 8270D 10/20/20 18:29BGV L517328 2.06 0.477 1 8270D 10/20/20 18:29BGV L517328 5.15 0.4 1 8270D 10/20/20 18:29BGV L517328 2.06 1.07 1 8270D 10/20/20 18:29BGV L517328 10.3 0.698 1 8270D 10/20/20 18:29BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 21.5 % 39-110 SR 2-Fluorobiphenyl 42.3 % 24-93 2-Fluorophenol 8.3 % 10-44 SR 4-Terphenyl-d14 13.3 % 35-126 SR Nitrobenzene-d5 45.4 % 20-91 Phenol-d6 8.3 % 7-32 1 0.498 1 531OC-2011 10/22/20 2:13 DDB L517921 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 8500 ug/L NE 1000 350 1 9056A 10/14/20 18:23BMS POJ0250 Nitrate as N 8300 ug/L 10000 200 45 1 9056A 10/14/20 18:23BMS POJ0250 Sulfate 4000 ug/L 250000 2000 560 1 9056A 10/14/20 18:23BMS POJ0250 General Chemistry Parameters Biochemical Oxygen Demand 2000 Chemical Oxygen Demand 35000 Cyanide <0.014 Ferrous Iron <46 pH 8.1 Sulfide <830 Temperature 20.3 Total Alkalinity to pH 4.5 140000 Organochlorine Pesticides by GC/ECD DD J HT HT HT ug/L ug/L mg/L ug/L pH Units ug/L °C ug/L NE NE 10 NE NE 1000 NE 2000 50000 0.025 200 2000 5000 210 11000 0.014 46 830 770 1 1 5 1 1 1 1 1 SM5210 B SM5220 D 9014 SM3500-Fe B SM4500-H B SM4500-S F SM2550 B SM2320 B 10/14/20 17:01 ENM 10/19/20 11:56SLS 10/20/20 12:30BMS 10/15/20 9:51 ENM 12/18/20 11:30CL13 10/19/20 11:02ENM 12/18/20 11:30CL13 10/19/20 11:40 CLB POJ0276 POJ0361 POJ0357 POJ0282 POL0392 POJ0337 POL0392 POJ0341 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081 B 10/19/20 12:10NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/19/20 12:10NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/19/20 12:10NMB POJ0286 Aldrin <0.015 ug/L 0.05 0.051 0.015 1 8081 B 10/19/20 12:10NMB POJ0286 alpha-BHC <0.0064 ug/L 0.05 0.051 0.0064 1 8081 B 10/19/20 12:10NMB POJ0286 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 12:10NMB POJ0286 beta-BHC <0.011 ug/L 0.05 0.051 0.011 1 8081 B 10/19/20 12:10NMB POJ0286 Chlordane <0.18 ug/L 0.5 0.51 0.18 1 8081 B 10/19/20 12:10NMB POJ0286 delta-BHC <0.0083 ug/L 0.05 0.051 0.0083 1 8081 B 10/19/20 12:10NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.051 0.014 1 8081 B 10/19/20 12:10NMB POJ0286 Endosulfan 1 <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 12:10NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.051 0.012 1 8081 B 10/19/20 12:10NMB POJ0286 Endosulfan Sulfate <0.017 ug/L 0.1 0.051 0.017 1 8081 B 10/19/20 12:10NMB POJ0286 Endrin <0.014 ug/L 0.1 0.051 0.014 1 8081 B 10/19/20 12:10NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 12:10NMB POJ0286 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 12:10NMB POJ0286 gamma-BHC <0.0062 ug/L 0.05 0.051 0.0062 1 8081 B 10/19/20 12:10NMB POJ0286 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/19/20 12:10NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.051 0.013 1 8081 B 10/19/20 12:10NMB POJ0286 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081 B 10/19/20 12:10NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 12:10NMB POJ0286 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/19/20 12:10NMB POJ0286 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Decachlorobiphenyl 58 % 13-186 Tetrachloro-m-xylene 67 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.21 ug/L NE 0.51 0.21 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:10NMB POJ0286 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/19/20 12:10NMB POJ0286 Total Metals Surrogate Recovery Control Limits Tetrachloro-m-xylene 65 % 30-161 Decachlorobiphenyl 60 % 32-178 Mercury 1.1 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:30EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 16:42JAB POJ0239 Arsenic 0.31 J ug/L 10 1.0 0.17 1 6020B 10/23/20 16:42JAB POJ0239 Barium 110 ug/L 100 2.0 0.81 1 6020B 10/23/20 16:42JAB POJ0239 Beryllium <0.19 CCV ug/L 1 1.0 0.19 1 6020B 10/23/20 17:37JAB POJ0239 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/23/20 16:42JAB POJ0239 Chromium 0.86 J ug/L 10 2.0 0.79 1 6020B 10/23/20 16:42JAB POJ0239 Cobalt 0.59 J ug/L 10 2.0 0.52 1 6020B 10/23/20 16:42JAB POJ0239 Copper 3.8 J ug/L 10 10 3.8 1 6020B 10/23/20 16:42JAB POJ0239 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/23/20 16:42JAB POJ0239 Nickel 0.96 J ug/L 50 3.0 0.51 1 6020B 10/23/20 16:42JAB POJ0239 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 16:42JAB POJ0239 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 18:46JAB POJ0490 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/23/20 16:42JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 16:42JAB POJ0239 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 16:42JAB POJ0239 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/23/20 16:42JAB POJ0239 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 19:43JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 19:43JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 19:43JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 19:43JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 19:43JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 19:43JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 19:43JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 19:43JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 19:43JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 19:43JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 19:43JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 19:43JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 19:43JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 19:43JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 19:43JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 19:43JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 19:43JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 19:43JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 19:43JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 19:43JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 19:43JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 19:43JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 19:43JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 19:43JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 19:43JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 19:43JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 19:43JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 19:43JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 19:43JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 19:43JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 19:43JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 19:43JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 19:43JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 19:43JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 19:43JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 19:43JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 19:43JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 19:43JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 19:43JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 19:43JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 19:43JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 19:43JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 19:43JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 19:43JLB POJ0321 m,p-Xylenes 0.37 J ug/L NE 1.0 0.12 1 8260D 10/21/20 19:43JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 19:43JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 19:43JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 19:43JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 19:43JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 19:43JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 19:43JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 19:43JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 19:43JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 19:43JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 19:43JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 19:43JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 19:43JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 19:43JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 19:43JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 19:43JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 19:43JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 19:43JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 19:43JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 19:43JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 19:43JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 19:43JLB POJ0321 Xylenes, total 0.37 J ug/L 5 1.5 0.15 1 8260D 10/21/20 19:43JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 110 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 22:03ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 1,4-Naphthoquinone U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 1-Naphthylamine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 2-Acetylaminofluorene U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 2-Naphthylamine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 3-Methylcholanthrene U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 4-Aminobiphenyl U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 5-Nitro-o-toluidine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 7,12-D1methyl benz(a)anthrace ne U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Diallate U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Hexachloropropene U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Isosafrole U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Kepone U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Methapyrilene U Ng/L 20.2 10.1 1 8270D 10/20/20 18:51 BGV L517325 N-Nitrosomethylethylamine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 N-Nitrosopiperidine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 N-Nitrosopyrrolidine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 o-Toluidine U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 p-Dimethylaminoazobenzene U pg/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 p-Phenylenediamine U L Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Pronamide U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Safrole U Ng/L 10.1 10.1 1 8270D 10/20/20 18:51 BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T U Ng/L 0.03 0.01002 1 8151A 10/20/20 23:51 VIC L517362 2,4,5-TP (Silvex) U Ng/L 0.1 0.01634 1 8151A 10/20/20 23:51 VIC L517362 2,4-D U Ng/L 0.25 0.2078 1 8151A 10/20/20 23:51 VIC L517362 2,4-DB U Ng/L 0.1 0.1364 1 8151A 10/20/20 23:51 VIC L517362 Dalapon U Ng/L 0.55 0.5149 1 8151A 10/20/20 23:51 VIC L517362 Dicamba U Ng/L 0.1 0.057 1 8151A 10/20/20 23:51 VIC L517362 Dichlorprop U Ng/L 0.1 0.07959 1 8151A 10/20/20 23:51 VIC L517362 Dinoseb U Ng/L 0.1 0.02698 1 8151A 10/20/20 23:51 VIC L517362 MCPA U Ng/L 50 18.98 1 8151A 10/20/20 23:51 VIC L517362 MCPP U Ng/L 50 11.75 1 8151A 10/20/20 23:51 VIC L517362 Picloram U Ng/L 0.1 0.04528 1 8151A 10/20/20 23:51 VIC L517362 Surrogate Recovery Control Limits DCAA 57.5 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene U Ng/L 5.05 0.32 1 8270D 10/20/20 18:51 BGV L517328 1,2,4-Trichlorobenzene U Ng/L 5.05 0.486 1 8270D 10/20/20 18:51 BGV L517328 1,2-Dichlorobenzene 0.843 j Ng/L 5.05 0.635 1 8270D 10/20/20 18:51 BGV L517328 1,3-Dichlorobenzene 0.791 j Ng/L 5.05 0.495 1 8270D 10/20/20 18:51 BGV L517328 1,4-Dichlorobenzene 0.746 j Ng/L 5.05 0.585 1 8270D 10/20/20 18:51 BGV L517328 2,3,4,6-Tetrachlorophenol U Ng/L 5.05 0.358 1 8270D 10/20/20 18:51 BGV L517328 2,4,5-Trichlorophenol U Ng/L 5.05 0.353 1 8270D 10/20/20 18:51 BGV L517328 2,4,6-Trichlorophenol U Ng/L 5.05 0.347 1 8270D 10/20/20 18:51 BGV L517328 2,4-Dichlorophenol U Ng/L 5.05 1.54 1 8270D 10/20/20 18:51 BGV L517328 2,4-Dimethylphenol U Ng/L 5.05 0.68 1 8270D 10/20/20 18:51 BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 62 ® Laboratory Report IL AL i • . 12/31 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 2,4-Dinitrophenol U pg/L 10.1 4.9 1 8270D 10/20/20 18:51 BGV L517328 2,4-Dinitrotoluene U pg/L 5.05 0.407 1 8270D 10/20/20 18:51 BGV L517328 2,6-Dichlorophenol U pg/L 5.05 0.71 1 8270D 10/20/20 18:51 BGV L517328 2,6-Dinitrotoluene U pg/L 5.05 0.417 1 8270D 10/20/20 18:51 BGV L517328 2-Chloronaphthalene U pg/L 5.05 0.48 1 8270D 10/20/20 18:51 BGV L517328 2-Chlorophenol U pg/L 5.05 0.743 1 8270D 10/20/20 18:51 BGV L517328 2-Methyl naphthalene U pg/L 2.02 0.489 1 8270D 10/20/20 18:51 BGV L517328 2-Methylphenol U pg/L 5.05 0.728 1 8270D 10/20/20 18:51 BGV L517328 2-Nitroaniline U pg/L 5.05 0.579 1 8270D 10/20/20 18:51 BGV L517328 2-Nitrophenol U pg/L 5.05 0.612 1 8270D 10/20/20 18:51 BGV L517328 3&4 Methylphenol U pg/L 5.05 0.697 1 8270D 10/20/20 18:51 BGV L517328 3,3' Dimethylbenzidine U pg/L 10.1 1.9 1 8270D 10/20/20 18:51 BGV L517328 3,3'-Dichlorobenzidine U pg/L 10.1 3.78 1 8270D 10/20/20 18:51 BGV L517328 3-Nitroaniline U pg/L 10.1 1.55 1 8270D 10/20/20 18:51 BGV L517328 4,6-Dinitro-2-methylphenol U pg/L 10.1 3.5 1 8270D 10/20/20 18:51 BGV L517328 4-Bromophenyl phenyl ether U pg/L 5.05 0.505 1 8270D 10/20/20 18:51 BGV L517328 4-Chloro-3-methylphenol U pg/L 5.05 0.508 1 8270D 10/20/20 18:51 BGV L517328 4-Chloroaniline U pg/L 5.05 0.531 1 8270D 10/20/20 18:51 BGV L517328 4-Chlorophenyl phenyl ether U pg/L 5.05 0.483 1 8270D 10/20/20 18:51 BGV L517328 4-Nitroaniline U pg/L 5.05 0.747 1 8270D 10/20/20 18:51 BGV L517328 4-Nitrophenol U pg/L 10.1 1.4 1 8270D 10/20/20 18:51 BGV L517328 Acenaphthene U pg/L 2.02 0.426 1 8270D 10/20/20 18:51 BGV L517328 Acenaphthylene U pg/L 2.02 0.433 1 8270D 10/20/20 18:51 BGV L517328 Acetophenone U pg/L 5.05 0.692 1 8270D 10/20/20 18:51 BGV L517328 Aniline U pg/L 5.05 0.319 1 8270D 10/20/20 18:51 BGV L517328 Anthracene U pg/L 2.02 0.471 1 8270D 10/20/20 18:51 BGV L517328 Benzidine U pg/L 20.2 0.695 1 8270D 10/20/20 18:51 BGV L517328 Benzo(a)anthracene U pg/L 2.02 0.431 1 8270D 10/20/20 18:51 BGV L517328 Benzo(a)pyrene U pg/L 2.02 1.01 1 8270D 10/20/20 18:51 BGV L517328 Benzo(b)fluoranthene U pg/L 2.02 0.95 1 8270D 10/20/20 18:51 BGV L517328 Benzo(q,hJ)perylene U pg/L 2.02 1.37 1 8270D 10/20/20 18:51 BGV L517328 Benzo(k)fluoranthene U pg/L 2.02 0.759 1 8270D 10/20/20 18:51 BGV L517328 Benzoic Acid U pg/L 10.1 5.05 1 8270D 10/20/20 18:51 BGV L517328 Benzyl alcohol U pg/L 10.1 3.04 1 8270D 10/20/20 18:51 BGV L517328 Bis(2-Chloroethoxy)methane U pg/L 5.05 0.437 1 8270D 10/20/20 18:51 BGV L517328 Bis(2-Chloroethyl)ether U pg/L 5.05 0.451 1 8270D 10/20/20 18:51 BGV L517328 Bis(2-Chloroisopropyl)ether U pg/L 5.05 0.551 1 8270D 10/20/20 18:51 BGV L517328 Bis(2-ethylhexyl)phthalate U pg/L 5.05 3.7 1 8270D 10/20/20 18:51 BGV L517328 Butyl benzyl phthalate U pg/L 5.05 4.64 1 8270D 10/20/20 18:51 BGV L517328 Carbazole U pg/L 5.05 0.48 1 8270D 10/20/20 18:51 BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 62 . Laboratory Report • � Waynt.� 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-03-20201013 Attn: Alec Macbeth Sample ID: 0100174-02 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 10:29 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chrysene U Ng/L 2.02 0.738 1 8270D 10/20/20 18:51 BGV L517328 D1benz(a,h)anthrace ne U Ng/L 2.02 0.254 1 8270D 10/20/20 18:51 BGV L517328 Dibenzofuran U Ng/L 5.05 0.427 1 8270D 10/20/20 18:51 BGV L517328 Diethyl phthalate U Ng/L 5.05 0.59 1 8270D 10/20/20 18:51 BGV L517328 Dimethyl phthalate U Ng/L 5.05 0.515 1 8270D 10/20/20 18:51 BGV L517328 Di-n-butyl phthalate U Ng/L 5.05 1.59 1 8270D 10/20/20 18:51 BGV L517328 Di-n-Octyl Phthalate U Ng/L 5.05 1.74 1 8270D 10/20/20 18:51 BGV L517328 Fluoranthene U Ng/L 2.02 0.41 1 8270D 10/20/20 18:51 BGV L517328 Fluorene U Ng/L 2.02 0.448 1 8270D 10/20/20 18:51 BGV L517328 Hexachlorobenzene U Ng/L 5.05 2.6 1 8270D 10/20/20 18:51 BGV L517328 Hexachlorobutadiene U Ng/L 5.05 0.409 1 8270D 10/20/20 18:51 BGV L517328 Hexachlorocyclopentadiene U pg/L 5.05 2.36 1 8270D 10/20/20 18:51 BGV L517328 Hexachloroethane U Ng/L 5.05 0.279 1 8270D 10/20/20 18:51 BGV L517328 Indeno(1,2,3-cd)pyrene U Ng/L 2.02 1.02 1 8270D 10/20/20 18:51 BGV L517328 Isophorone U Ng/L 5.05 0.363 1 8270D 10/20/20 18:51 BGV L517328 Naphthalene U Ng/L 2.02 0.488 1 8270D 10/20/20 18:51 BGV L517328 Nitrobenzene U Ng/L 5.05 0.536 1 8270D 10/20/20 18:51 BGV L517328 N-Nitrosodiethylamine U Ng/L 5.05 0.404 1 8270D 10/20/20 18:51 BGV L517328 N-Nitrosodimethylamine U Ng/L 5.05 0.251 1 8270D 10/20/20 18:51 BGV L517328 N-Nitroso-di-n-butylamine U pg/L 5.05 0.759 1 8270D 10/20/20 18:51 BGV L517328 N-Nitroso-di-n-propylamine U pg/L 5.05 0.337 1 8270D 10/20/20 18:51 BGV L517328 N-Nitrosodiphenylamine U Ng/L 10.1 0.79 1 8270D 10/20/20 18:51 BGV L517328 Pentachlorophenol U Ng/L 10.1 2.47 1 8270D 10/20/20 18:51 BGV L517328 Phenanthrene U Ng/L 2.02 0.468 1 8270D 10/20/20 18:51 BGV L517328 Phenol U pg/L 5.05 0.392 1 8270D 10/20/20 18:51 BGV L517328 Pyrene U Ng/L 2.02 1.05 1 8270D 10/20/20 18:51 BGV L517328 Pyridine U Ng/L 10.1 0.684 1 8270D 10/20/20 18:51 BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 22.7 % 39-110 SR 2-Fluorobiphenyl 39.6 % 24-93 2-Fluorophenol 9.7 % 10-44 SR 4-Terphenyl-d14 16.4 % 35-126 SR Nitrobenzene-d5 44.2 % 20-91 Phenol-d6 8.1 % 7-32 Total Organic Carbon TOC 4.68 mg/L 1 0.498 1 531OC-2011 10/22/20 2:51 DDB L517921 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 1100 ug/L NE 1000 350 1 9056A 10/14/20 17:36BMS POJ0250 Nitrate as N 96 J ug/L 10000 200 45 1 9056A 10/14/20 17:36BMS POJ0250 Sulfate 830 J ug/L 250000 2000 560 1 9056A 10/14/20 17:36BMS POJ0250 General Chemistry Parameters Biochemical Oxygen Demand 280 J ug/L NE 2000 210 1 SM5210 B 10/14/20 17:01 ENM POJ0276 Chemical Oxygen Demand <11000 ug/L NE 50000 11000 1 SM5220 D 10/19/20 11:56SLS POJ0361 Cyanide <0.014 mg/L 10 0.025 0.014 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron <46 HT ug/L NE 200 46 1 SM3500-Fe B 10/15/20 9:51 ENM POJ0282 pH 7.1 HT pH Units NE 1 SM4500-H B 12/18/20 11:30CLB POL0392 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02ENM POJ0337 Temperature 20.0 HT °C 1 SM2550 B 12/18/20 11:30CLB POL0392 Total Alkalinity to pH 4.5 24000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081 B 10/19/20 12:22NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/19/20 12:22NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/19/20 12:22NMB POJ0286 Aldrin <0.015 ug/L 0.05 0.051 0.015 1 8081 B 10/19/20 12:22NMB POJ0286 alpha-BHC <0.0064 ug/L 0.05 0.051 0.0064 1 8081 B 10/19/20 12:22NMB POJ0286 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 12:22NMB POJ0286 beta-BHC 0.14 DC ug/L 0.05 0.051 0.011 1 8081 B 10/19/20 12:22NMB POJ0286 Chlordane <0.18 ug/L 0.5 0.51 0.18 1 8081 B 10/19/20 12:22NMB POJ0286 delta-BHC <0.0083 ug/L 0.05 0.051 0.0083 1 8081 B 10/19/20 12:22NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.051 0.014 1 8081 B 10/19/20 12:22NMB POJ0286 Endosulfan 1 <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 12:22NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.051 0.012 1 8081 B 10/19/20 12:22NMB POJ0286 Endosulfan Sulfate <0.017 ug/L 0.1 0.051 0.017 1 8081 B 10/19/20 12:22NMB POJ0286 Endrin <0.014 ug/L 0.1 0.051 0.014 1 8081 B 10/19/20 12:22NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 12:22NMB POJ0286 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 12:22NMB POJ0286 gamma-BHC <0.0062 ug/L 0.05 0.051 0.0062 1 8081 B 10/19/20 12:22NMB POJ0286 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/19/20 12:22NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.051 0.013 1 8081 B 10/19/20 12:22NMB POJ0286 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081 B 10/19/20 12:22NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 12:22NMB POJ0286 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/19/20 12:22NMB POJ0286 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Decachlorobiphenyl 55 % 13-186 Tetrachloro-m-xylene 67 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.21 ug/L NE 0.51 0.21 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:22NMB POJ0286 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/19/20 12:22NMB POJ0286 Total Metals Surrogate Recovery Control Limits Tetrachloro-m-xylene 68 % 30-161 Decachlorobiphenyl 58 % 32-178 Mercury 1.3 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:34EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/23/20 16:49JAB POJ0239 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/23/20 16:49JAB POJ0239 Barium 47 ug/L 100 2.0 0.81 1 6020B 10/23/20 16:49JAB POJ0239 Beryllium <0.19 CCV ug/L 1 1.0 0.19 1 6020B 10/23/20 16:49JAB POJ0239 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/23/20 16:49JAB POJ0239 Chromium <0.79 ug/L 10 2.0 0.79 1 6020B 10/23/20 16:49JAB POJ0239 Cobalt 9.0 ug/L 10 2.0 0.52 1 6020B 10/23/20 16:49JAB POJ0239 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/23/20 16:49JAB POJ0239 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/23/20 16:49JAB POJ0239 Nickel 3.4 ug/L 50 3.0 0.51 1 6020B 10/23/20 16:49JAB POJ0239 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/23/20 16:49JAB POJ0239 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 19:07JAB POJ0490 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/23/20 16:49JAB POJ0239 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/23/20 16:49JAB POJ0239 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/23/20 16:49JAB POJ0239 Zinc 20 ug/L 10 20 6.9 1 6020B 10/23/20 16:49JAB POJ0239 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 20:17JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 20:17JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 20:17JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 20:17JLB POJ0321 1,1-Dichloroethane 1.4 ug/L 5 0.50 0.083 1 8260D 10/21/20 20:17JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 20:17JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 20:17JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 20:17JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 20:17JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 20:17JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 20:17JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 20:17JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 20:17JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 20:17JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 20:17JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 20:17JLB POJ0321 1,4-Dichlorobenzene 2.6 ug/L 1 0.50 0.050 1 8260D 10/21/20 20:17JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 20:17JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 20:17JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 20:17JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 20:17JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 20:17JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 20:17JLB POJ0321 Benzene 0.26 J ug/L 1 0.50 0.048 1 8260D 10/21/20 20:17JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 20:17JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 20:17JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 20:17JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 20:17JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 20:17JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 20:17JLB POJ0321 Chlorobenzene 0.41 J ug/L 3 0.50 0.062 1 8260D 10/21/20 20:17JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 20:17JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 20:17JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 20:17JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 20:17JLB POJ0321 cis-1,2-Dichloroethylene 1.4 ug/L 2 0.50 0.056 1 8260D 10/21/20 20:17JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 20:17JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 20:17JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 20:17JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 20:17JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 20:17JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 20:17JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 20:17JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 62 . Laboratory Report • � Waynt.. 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 20:17JLB POJ0321 m,p-Xylenes 0.37 J ug/L NE 1.0 0.12 1 8260D 10/21/20 20:17JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 20:17JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 20:17JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 20:17JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 20:17JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 20:17JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 20:17JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 20:17JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 20:17JLB POJ0321 o-Xylene 0.29 J ug/L NE 0.50 0.044 1 8260D 10/21/20 20:17JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 20:17JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 20:17JLB POJ0321 Tetrachloroethylene 0.25 J ug/L 1 0.50 0.098 1 8260D 10/21/20 20:17JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 20:17JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 20:17JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 20:17JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 20:17JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 20:17JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 20:17JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 20:17JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 20:17JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 20:17JLB POJ0321 Xylenes, total 0.66 J ug/L 5 1.5 0.15 1 8260D 10/21/20 20:17JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 22:29ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 1,4-Naphthoquinone U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 1-Naphthylamine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 2-Acetylaminofluorene U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 2-Naphthylamine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 3-Methylcholanthrene U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 4-Aminobiphenyl U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 5-Nitro-o-toluidine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 7,12-D1methyl benz(a)anthrace ne U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Diallate U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Hexachloropropene U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Isosafrole U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Kepone U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Methapyrilene U Ng/L 22.2 11.1 1 8270D 10/20/20 19:13BGV L517325 N-Nitrosomethylethyl amine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 N-Nitrosopiperidine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 N-Nitrosopyrrolidine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 o-Toluidine U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 p-Dimethylaminoazobenzene U pg/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 p-Phenylenediamine U L Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Pronamide U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Safrole U Ng/L 11.1 11.1 1 8270D 10/20/20 19:13BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T U Ng/L 0.03 0.01002 1 8151A 10/21/20 1:07 VIC L517362 2,4,5-TP (Silvex) U Ng/L 0.1 0.01634 1 8151A 10/21/20 1:07 VIC L517362 2,4-D U Ng/L 0.25 0.2078 1 8151A 10/21/20 1:07 VIC L517362 2,4-DB U Ng/L 0.1 0.1364 1 8151A 10/21/20 1:07 VIC L517362 Dalapon U Ng/L 0.55 0.5149 1 8151A 10/21/20 1:07 VIC L517362 Dicamba U Ng/L 0.1 0.057 1 8151A 10/21/20 1:07 VIC L517362 Dichlorprop U Ng/L 0.1 0.07959 1 8151A 10/21/20 1:07 VIC L517362 Dinoseb U Ng/L 0.1 0.02698 1 8151A 10/21/20 1:07 VIC L517362 MCPA U Ng/L 50 18.98 1 8151A 10/21/20 1:07 VIC L517362 MCPP U Ng/L 50 11.75 1 8151A 10/21/20 1:07 VIC L517362 Picloram U Ng/L 0.1 0.04528 1 8151A 10/21/20 1:07 VIC L517362 Surrogate Recovery Control Limits DCAA 62.6 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene U Ng/L 5.56 0.352 1 8270D 10/20/20 19:13BGV L517328 1,2,4-Trichlorobenzene U Ng/L 5.56 0.535 1 8270D 10/20/20 19:13BGV L517328 1,2-Dichlorobenzene U Ng/L 5.56 0.699 1 8270D 10/20/20 19:13BGV L517328 1,3-Dichlorobenzene U Ng/L 5.56 0.545 1 8270D 10/20/20 19:13BGV L517328 1,4-Dichlorobenzene 0.779 j Ng/L 5.56 0.644 1 8270D 10/20/20 19:13BGV L517328 2,3,4,6-Tetrachlorophenol U Ng/L 5.56 0.394 1 8270D 10/20/20 19:13BGV L517328 2,4,5-Trichlorophenol U Ng/L 5.56 0.389 1 8270D 10/20/20 19:13BGV L517328 2,4,6-Trichlorophenol U Ng/L 5.56 0.382 1 8270D 10/20/20 19:13BGV L517328 2,4-Dichlorophenol U Ng/L 5.56 1.69 1 8270D 10/20/20 19:13BGV L517328 2,4-Dimethylphenol U Ng/L 5.56 0.749 1 8270D 10/20/20 19:13BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 62 ® Laboratory Report IL AL i • . 12/31 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 2,4-Dinitrophenol U pg/L 11.1 5.38 1 8270D 10/20/20 19:13BGV L517328 2,4-Dinitrotoluene U pg/L 5.56 0.448 1 8270D 10/20/20 19:13BGV L517328 2,6-Dichlorophenol U pg/L 5.56 0.781 1 8270D 10/20/20 19:13BGV L517328 2,6-Dinitrotoluene U pg/L 5.56 0.459 1 8270D 10/20/20 19:13BGV L517328 2-Chloronaphthalene U pg/L 5.56 0.529 1 8270D 10/20/20 19:13BGV L517328 2-Chlorophenol U pg/L 5.56 0.818 1 8270D 10/20/20 19:13BGV L517328 2-Methyl naphthalene U pg/L 2.22 0.538 1 8270D 10/20/20 19:13BGV L517328 2-Methylphenol U pg/L 5.56 0.801 1 8270D 10/20/20 19:13BGV L517328 2-Nitroaniline U pg/L 5.56 0.638 1 8270D 10/20/20 19:13BGV L517328 2-Nitrophenol U pg/L 5.56 0.673 1 8270D 10/20/20 19:13BGV L517328 3&4 Methylphenol U pg/L 5.56 0.768 1 8270D 10/20/20 19:13BGV L517328 3,3' Dimethylbenzidine U pg/L 11.1 2.09 1 8270D 10/20/20 19:13BGV L517328 3,3'-Dichlorobenzidine U pg/L 11.1 4.15 1 8270D 10/20/20 19:13BGV L517328 3-Nitroaniline U pg/L 11.1 1.7 1 8270D 10/20/20 19:13BGV L517328 4,6-Dinitro-2-methylphenol U pg/L 11.1 3.85 1 8270D 10/20/20 19:13BGV L517328 4-Bromophenyl phenyl ether U pg/L 5.56 0.556 1 8270D 10/20/20 19:13BGV L517328 4-Chloro-3-methylphenol U pg/L 5.56 0.559 1 8270D 10/20/20 19:13BGV L517328 4-Chloroaniline U pg/L 5.56 0.584 1 8270D 10/20/20 19:13BGV L517328 4-Chlorophenyl phenyl ether U pg/L 5.56 0.532 1 8270D 10/20/20 19:13BGV L517328 4-Nitroaniline U pg/L 5.56 0.822 1 8270D 10/20/20 19:13BGV L517328 4-Nitrophenol U pg/L 11.1 1.54 1 8270D 10/20/20 19:13BGV L517328 Acenaphthene U pg/L 2.22 0.468 1 8270D 10/20/20 19:13BGV L517328 Acenaphthylene U pg/L 2.22 0.476 1 8270D 10/20/20 19:13BGV L517328 Acetophenone U pg/L 5.56 0.762 1 8270D 10/20/20 19:13BGV L517328 Aniline U pg/L 5.56 0.351 1 8270D 10/20/20 19:13BGV L517328 Anthracene U pg/L 2.22 0.518 1 8270D 10/20/20 19:13BGV L517328 Benzidine U pg/L 22.2 0.764 1 8270D 10/20/20 19:13BGV L517328 Benzo(a)anthracene U pg/L 2.22 0.473 1 8270D 10/20/20 19:13BGV L517328 Benzo(a)pyrene U pg/L 2.22 1.11 1 8270D 10/20/20 19:13BGV L517328 Benzo(b)fluoranthene U pg/L 2.22 1.04 1 8270D 10/20/20 19:13BGV L517328 Benzo(q,hJ)perylene U pg/L 2.22 1.51 1 8270D 10/20/20 19:13BGV L517328 Benzo(k)fluoranthene U pg/L 2.22 0.834 1 8270D 10/20/20 19:13BGV L517328 Benzoic Acid U pg/L 11.1 5.55 1 8270D 10/20/20 19:13 BGV L517328 Benzyl alcohol U pg/L 11.1 3.34 1 8270D 10/20/20 19:13BGV L517328 Bis(2-Chloroethoxy)methane U pg/L 5.56 0.481 1 8270D 10/20/20 19:13BGV L517328 Bis(2-Chloroethyl)ether U pg/L 5.56 0.497 1 8270D 10/20/20 19:13BGV L517328 Bis(2-Chloroisopropyl)ether U pg/L 5.56 0.607 1 8270D 10/20/20 19:13BGV L517328 Bis(2-ethylhexyl)phthalate U pg/L 5.56 4.07 1 8270D 10/20/20 19:13BGV L517328 Butyl benzyl phthalate U pg/L 5.56 5.11 1 8270D 10/20/20 19:13BGV L517328 Carbazole U pg/L 5.56 0.529 1 8270D 10/20/20 19:13BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 62 . Laboratory Report • � Waynt.� 12/31/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-06-20201013 Attn: Alec Macbeth Sample ID: 0100174-03 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 13:15 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chrysene U Ng/L 2.22 0.811 1 8270D 10/20/20 19:13BGV L517328 D1benz(a,h)anthrace ne U Ng/L 2.22 0.279 1 8270D 10/20/20 19:13BGV L517328 Dibenzofuran U Ng/L 5.56 0.47 1 8270D 10/20/20 19:13BGV L517328 Diethyl phthalate 0.709 j Ng/L 5.56 0.65 1 8270D 10/20/20 19:13BGV L517328 Dimethyl phthalate U Ng/L 5.56 0.567 1 8270D 10/20/20 19:13BGV L517328 Di-n-butyl phthalate U Ng/L 5.56 1.75 1 8270D 10/20/20 19:13BGV L517328 Di-n-Octyl Phthalate U Ng/L 5.56 1.91 1 8270D 10/20/20 19:13BGV L517328 Fluoranthene U Ng/L 2.22 0.45 1 8270D 10/20/20 19:13BGV L517328 Fluorene U Ng/L 2.22 0.492 1 8270D 10/20/20 19:13BGV L517328 Hexachlorobenzene U Ng/L 5.56 2.86 1 8270D 10/20/20 19:13BGV L517328 Hexachlorobutadiene U Ng/L 5.56 0.45 1 8270D 10/20/20 19:13BGV L517328 Hexachlorocyclopentadiene U Ng/L 5.56 2.6 1 8270D 10/20/20 19:13BGV L517328 Hexachloroethane U Ng/L 5.56 0.308 1 8270D 10/20/20 19:13BGV L517328 Indeno(1,2,3-cd)pyrene U Ng/L 2.22 1.12 1 8270D 10/20/20 19:13BGV L517328 Isophorone U Ng/L 5.56 0.4 1 8270D 10/20/20 19:13BGV L517328 Naphthalene U Ng/L 2.22 0.537 1 8270D 10/20/20 19:13BGV L517328 Nitrobenzene U Ng/L 5.56 0.59 1 8270D 10/20/20 19:13BGV L517328 N-Nitrosodiethylamine U pg/L 5.56 0.444 1 8270D 10/20/20 19:13BGV L517328 N-Nitrosodimethylamine U Ng/L 5.56 0.276 1 8270D 10/20/20 19:13BGV L517328 N-Nitroso-di-n-butylamine U Ng/L 5.56 0.836 1 8270D 10/20/20 19:13BGV L517328 N-Nitroso-di-n-propylamine U Ng/L 5.56 0.371 1 8270D 10/20/20 19:13BGV L517328 N-Nitrosodiphenylamine U Ng/L 11.1 0.869 1 8270D 10/20/20 19:13BGV L517328 Pentachlorophenol U Ng/L 11.1 2.72 1 8270D 10/20/20 19:13BGV L517328 Phenanthrene U Ng/L 2.22 0.515 1 8270D 10/20/20 19:13BGV L517328 Phenol U Ng/L 5.56 0.432 1 8270D 10/20/20 19:13BGV L517328 Pyrene U Ng/L 2.22 1.15 1 8270D 10/20/20 19:13BGV L517328 Pyridine U Ng/L 11.1 0.752 1 8270D 10/20/20 19:13BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 26.2 % 39-110 SR 2-Fluorobiphenyl 46.2 % 24-93 2-Fluorophenol 12.7 % 10-44 4-Terphenyl-d14 21.9 % 35-126 SR Nitrobenzene-d5 50 % 20-91 Phenol-d6 10.3 % 7-32 Total Organic Carbon TOC 1.04 mg/L 1 0.498 1 531OC-2011 10/22/20 3:29 DDB L517921 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 62 Laboratory Report • � 12/31/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010130000 Attn: Alec Macbeth Sample ID: 0100174-04 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 00:00 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 16:19JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 16:19JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 16:19JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 16:19JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 16:19JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 16:19JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 16:19JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 16:19JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 16:19JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 16:19JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 16:19JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 16:19JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 16:19JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 16:19JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 16:19JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 16:19JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 16:19JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 16:19JLB POJ0321 Acetone 3.0 J ug/L 100 5.0 0.31 1 8260D 10/21/20 16:19JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 16:19JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 16:19JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 16:19JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 16:19JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 16:19JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 16:19JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 16:19JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 16:19JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 16:19JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 16:19JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 16:19JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 16:19JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 16:19JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 16:19JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 16:19JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 16:19JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 16:19JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 62 Laboratory Report A i • .0 12/31/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010130000 Attn: Alec Macbeth Sample ID: 0100174-04 231 Haywood Street Project No.: 50-02 Work Order: 0100174 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/13/20 00:00 Time Submitted: 10/14/20 09:10 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 16:19JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 16:19JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 16:19JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 16:19JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 16:19JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 16:19JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 16:19JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 16:19JLB POJ0321 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/21/20 16:19JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 16:19JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 16:19JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 16:19JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 16:19JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 16:19JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 16:19JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 16:19JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 16:19JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 16:19JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 16:19JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 16:19JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 16:19JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 16:19JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 16:19JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 16:19JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 16:19JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 16:19JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 16:19JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 16:19JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 16:19JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 16:19JLB POJ0321 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/21/20 16:19JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 106 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 62 (2) Way po Int ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene 0.290 1.0 ug/L J 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L Acetone BRL 5.0 ug/L Acetonitrile BRL 10 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Allyl Chloride (3-Chloropropylene) BRL 10 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L Chloroprene BRL 10 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 5.0 ug/L Ethyl Methacrylate BRL 10 ug/L Ethylbenzene BRL 0.50 ug/L Hexachlorobutadiene 0.220 2.0 ug/L J Isobutyl alcohol BRL 50 ug/L m,p-Xylenes 0.250 1.0 ug/L J Methacrylonitrile BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 62 Waypoint ' ANALYTICAL Level II QC Report 12/31/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared & Analyzed: 10/21/20 Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methyl Methacrylate BRL 10 ug/L Methylene Chloride BRL 1.0 ug/L Naphthalene BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Propionitrile (Ethyl Cyanide) BRL 10 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total 0.250 1.5 ug/L J Surrogate:4-Bromofluorobenzene 50.3 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 53.8 ug/L 50.00 108 75-129 Surrogate: Toluene-d8 49.6 ug/L 50.00 99 77-123 LCS (POJ0321-BS1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.5 0.50 ug/L 20.00 108 79-134 1,1,1-Trichloroethane 21.3 0.50 ug/L 20.00 106 75-136 1,1,2,2-Tetrachloroethane 21.0 0.50 ug/L 20.00 105 62-127 1,1,2-Trichloroethane 21.6 0.50 ug/L 20.00 108 70-140 1,1-Dichloroethane 21.6 0.50 ug/L 20.00 108 78-130 1,1-Dichloroethylene 21.2 0.50 ug/L 20.00 106 70-154 1, 1 -Dichloropropylene 22.0 0.50 ug/L 20.00 110 71-136 1,2,3-Trichloropropane 21.2 1.0 ug/L 20.00 106 71-127 1,2,4-Trichlorobenzene 20.4 1.0 ug/L 20.00 102 66-139 1,2-Dibromo-3-chloropropane 22.9 2.0 ug/L 20.00 114 63-134 1,2-Dibromoethane 21.3 0.50 ug/L 20.00 107 77-135 1,2-Dichlorobenzene 21.3 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 21.6 0.50 ug/L 20.00 108 68-131 1,2-Dichloropropane 21.9 0.50 ug/L 20.00 110 77-130 1,3-Dichlorobenzene 21.5 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 22.0 0.50 ug/L 20.00 110 76-132 1,4-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 75-126 2,2-Dichloropropane 23.8 2.0 ug/L 20.00 119 29-149 Acetone 39.6 5.0 ug/L 40.00 99 40-166 Acetonitrile 19.4 10 ug/L 20.00 97 70-130 Acrolein 45.9 20 ug/L 40.00 115 70-130 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 62 Waypoint ' ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/31/20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Acrylonitrile 42.3 20 ug/L 40.00 106 81-127 Allyl Chloride (3-Chloropropylene) 19.4 10 ug/L 20.00 97 70-130 Benzene 22.7 0.50 ug/L 20.00 114 77-128 Bromochloromethane 22.1 0.50 ug/L 20.00 110 78-135 Bromodichloromethane 21.7 0.50 ug/L 20.00 108 76-138 Bromoform 22.4 1.0 ug/L 20.00 112 71-135 Bromomethane 21.0 1.0 ug/L 20.00 105 41-168 Carbon disulfide 21.1 5.0 ug/L 20.00 106 59-135 Carbon Tetrachloride 21.7 0.50 ug/L 20.00 109 72-142 Chlorobenzene 22.0 0.50 ug/L 20.00 110 78-119 Chloroethane 21.5 0.50 ug/L 20.00 107 57-142 Chloroform 21.0 0.50 ug/L 20.00 105 77-130 Chloromethane 20.5 0.50 ug/L 20.00 102 47-145 Chloroprene 19.7 10 ug/L 20.00 98 70-130 cis-1,2-Dichloroethylene 22.5 0.50 ug/L 20.00 113 76-141 cis-1,3-Dichloropropylene 22.4 0.50 ug/L 20.00 112 65-140 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 Dibromomethane 21.8 0.50 ug/L 20.00 109 76-138 Dichlorodifluoromethane 25.2 5.0 ug/L 20.00 126 28-163 Ethyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 Ethylbenzene 22.7 0.50 ug/L 20.00 114 80-127 Hexachlorobutadiene 20.1 2.0 ug/L 20.00 100 61-134 Isobutyl alcohol 24.0 50 ug/L 20.00 120 70-130 J m,p-Xylenes 48.4 1.0 ug/L 40.00 121 77-133 Methacrylonitrile 19.5 10 ug/L 20.00 98 70-130 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 114 64-137 Methyl Ethyl Ketone (2-Butanone) 20.2 5.0 ug/L 20.00 101 71-134 Methyl Iodide 23.5 5.0 ug/L 20.00 118 70-130 Methyl Isobutyl Ketone 23.8 5.0 ug/L 20.00 119 69-134 Methyl Methacrylate 20.3 10 ug/L 20.00 102 70-130 Methylene Chloride 20.7 1.0 ug/L 20.00 103 73-131 Naphthalene 21.0 1.0 ug/L 20.00 105 64-136 o-Xylene 22.8 0.50 ug/L 20.00 114 78-128 Propionitrile (Ethyl Cyanide) 22.1 10 ug/L 20.00 110 70-130 Styrene 23.3 0.50 ug/L 20.00 116 78-129 Tetrachloroethylene 21.2 0.50 ug/L 20.00 106 80-129 Tetrahydrofuran 22.3 10 ug/L 20.00 112 70-130 Toluene 22.5 0.50 ug/L 20.00 113 76-131 trans- 1,2-Dichloroethylene 21.6 0.50 ug/L 20.00 108 76-135 trans- 1,3-Dichloropropylene 23.1 0.50 ug/L 20.00 116 67-140 trans-1,4-Dichloro-2-butene 21.1 10 ug/L 20.00 105 70-130 Trichloroethylene 21.3 0.50 ug/L 20.00 107 77-133 Trichlorofluoromethane 22.6 0.50 ug/L 20.00 113 62-148 Vinyl acetate 26.3 2.0 ug/L 20.00 131 34-167 Vinyl chloride 22.4 0.50 ug/L 20.00 112 57-141 Xylenes, total 71.2 1.5 ug/L 60.00 119 77-133 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 62 Waypoint ' ANALYTICAL Level II QC Report 12/31/20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Surrogate:4-Bromofluorobenzene 48.4 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.3 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.0 ug/L 50.00 100 77-123 LCS Dup (POJ0321-BSDI) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.4 0.50 ug/L 20.00 107 79-134 0.6 20 1,1,1-Trichloroethane 20.5 0.50 ug/L 20.00 102 75-136 4 20 1,1,2,2-Tetrachloroethane 20.7 0.50 ug/L 20.00 103 62-127 2 20 1,1,2-Trichloroethane 21.4 0.50 ug/L 20.00 107 70-140 1 20 1,1-Dichloroethane 20.4 0.50 ug/L 20.00 102 78-130 5 20 1,1-Dichloroethylene 20.2 0.50 ug/L 20.00 101 70-154 5 20 1, 1 -Dichloropropylene 21.0 0.50 ug/L 20.00 105 71-136 5 20 1,2,3-Trichloropropane 21.1 1.0 ug/L 20.00 106 71-127 0.6 20 1,2,4-Trichlorobenzene 20.7 1.0 ug/L 20.00 103 66-139 1 20 1,2-Dibromo-3-chloropropane 21.7 2.0 ug/L 20.00 108 63-134 5 20 1,2-Dibromoethane 20.9 0.50 ug/L 20.00 104 77-135 2 20 1,2-Dichlorobenzene 20.5 0.50 ug/L 20.00 103 78-128 4 20 1,2-Dichloroethane 21.1 0.50 ug/L 20.00 106 68-131 2 20 1,2-Dichloropropane 21.3 0.50 ug/L 20.00 107 77-130 3 20 1,3-Dichlorobenzene 21.1 0.50 ug/L 20.00 105 77-125 2 20 1,3-Dichloropropane 21.3 0.50 ug/L 20.00 106 76-132 3 20 1,4-Dichlorobenzene 20.4 0.50 ug/L 20.00 102 75-126 2 20 2,2-Dichloropropane 21.4 2.0 ug/L 20.00 107 29-149 11 20 Acetone 39.2 5.0 ug/L 40.00 98 40-166 1 20 Acetonitrile 21.5 10 ug/L 20.00 107 70-130 10 20 Acrolein 46.1 20 ug/L 40.00 115 70-130 0.5 20 Acrylonitrile 42.2 20 ug/L 40.00 105 81-127 0.4 20 Allyl Chloride (3-Chloropropylene) 18.8 10 ug/L 20.00 94 70-130 3 20 Benzene 21.8 0.50 ug/L 20.00 109 77-128 4 20 Bromochloromethane 20.5 0.50 ug/L 20.00 103 78-135 7 20 Bromodichloromethane 20.8 0.50 ug/L 20.00 104 76-138 4 20 Bromoform 21.5 1.0 ug/L 20.00 107 71-135 4 20 Bromomethane 19.7 1.0 ug/L 20.00 99 41-168 6 20 Carbon disulfide 20.5 5.0 ug/L 20.00 102 59-135 3 20 Carbon Tetrachloride 20.9 0.50 ug/L 20.00 105 72-142 4 20 Chlorobenzene 21.2 0.50 ug/L 20.00 106 78-119 4 20 Chloroethane 20.2 0.50 ug/L 20.00 101 57-142 6 20 Chloroform 20.6 0.50 ug/L 20.00 103 77-130 2 20 Chloromethane 20.0 0.50 ug/L 20.00 100 47-145 2 20 Chloroprene 18.8 10 ug/L 20.00 94 70-130 5 20 cis-1,2-Dichloroethylene 20.4 0.50 ug/L 20.00 102 76-141 10 20 cis-1,3-Dichloropropylene 21.9 0.50 ug/L 20.00 110 65-140 2 20 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 0.1 20 Dibromomethane 21.3 0.50 ug/L 20.00 107 76-138 2 20 Dichlorodifluoromethane 24.2 5.0 ug/L 20.00 121 28-163 4 20 Ethyl Methacrylate 19.4 10 ug/L 20.00 97 70-130 1 20 Ethylbenzene 22.0 0.50 ug/L 20.00 110 80-127 3 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS Dup (POJ0321-BSD1) Prepared &Analyzed: 10/21/20 Hexachlorobutadiene 19.9 2.0 ug/L 20.00 99 61-134 1 20 Isobutyl alcohol 21.3 50 ug/L 20.00 106 70-130 12 20 1 m,p-Xylenes 47.1 1.0 ug/L 40.00 118 77-133 3 20 Methacrylonitrile 19.2 10 ug/L 20.00 96 70-130 2 20 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 113 64-137 0.3 20 Methyl Ethyl Ketone (2-Butanone) 19.7 5.0 ug/L 20.00 98 71-134 3 20 Methyl Iodide 22.6 5.0 ug/L 20.00 113 70-130 4 20 Methyl Isobutyl Ketone 22.7 5.0 ug/L 20.00 113 69-134 5 20 Methyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 3 20 Methylene Chloride 19.8 1.0 ug/L 20.00 99 73-131 5 20 Naphthalene 21.4 1.0 ug/L 20.00 107 64-136 2 20 o-Xylene 22.3 0.50 ug/L 20.00 112 78-128 2 20 Propionitrile (Ethyl Cyanide) 19.9 10 ug/L 20.00 100 70-130 10 20 Styrene 22.7 0.50 ug/L 20.00 113 78-129 3 20 Tetrachloroethylene 20.4 0.50 ug/L 20.00 102 80-129 4 20 Tetrahydrofuran 22.0 10 ug/L 20.00 110 70-130 2 20 Toluene 21.6 0.50 ug/L 20.00 108 76-131 4 20 trans-1,2-Dichloroethylene 20.6 0.50 ug/L 20.00 103 76-135 5 20 trans-1,3-Dichloropropylene 22.2 0.50 ug/L 20.00 ill 67-140 4 20 trans-1,4-Dichloro-2-butene 19.6 10 ug/L 20.00 98 70-130 7 20 Trichloroethylene 21.2 0.50 ug/L 20.00 106 77-133 0.7 20 Trichlorofluoromethane 21.4 0.50 ug/L 20.00 107 62-148 6 20 Vinyl acetate 25.7 2.0 ug/L 20.00 129 34-167 2 20 Vinyl chloride 21.2 0.50 ug/L 20.00 106 57-141 5 20 Xylenes, total 69.4 1.5 ug/L 60.00 116 77-133 2 20 Surrogate:4-Bromofluorobenzene 48.3 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.5 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.3 ug/L 50.00 101 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0316 - 5030B Blank (POJ0316-BLK1) Prepared & Analyzed: 10/16/20 1,4-Dioxane BRL 2.0 ug/L LCS (POJ0316-BS1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.5 2.0 ug/L 50.00 95 55-145 LCS Dup (POJ0316-BSD1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.1 2.0 ug/L 50.00 94 55-145 0.7 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Blank (POJ0286-BLK1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD BRL 0.10 ug/L 4,4'-DDE BRL 0.10 ug/L 4,4'-DDT BRL 0.10 ug/L Aldrin BRL 0.050 ug/L alpha-BHC BRL 0.050 ug/L cis -Chlordane BRL 0.10 ug/L beta-BHC BRL 0.050 ug/L Chlordane BRL 0.50 ug/L delta-BHC BRL 0.050 ug/L Dieldrin BRL 0.050 ug/L Endosulfan I BRL 0.050 ug/L Endosulfan II BRL 0.050 ug/L Endosulfan Sulfate BRL 0.050 ug/L Endrin BRL 0.050 ug/L Endrin Aldehyde BRL 0.050 ug/L Endrin Ketone BRL 0.10 ug/L gamma-BHC BRL 0.050 ug/L trans -Chlordane BRL 0.10 ug/L Heptachlor BRL 0.050 ug/L Heptachlor Epoxide BRL 0.10 ug/L Methoxychlor BRL 0.10 ug/L Toxaphene BRL 1.0 ug/L Surrogate: Decachlorobiphenyl 0.560 ug/L 1.000 56 13-186 Surrogate: Tetrachloro-m-xylene 0.630 ug/L 1.000 63 40-134 LCS (POJ0286-BS1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD 0.690 0.10 ug/L 1.000 69 56-143 4,4'-DDE 0.700 0.10 ug/L 1.000 70 57-135 4,4'-DDT 0.740 0.10 ug/L 1.000 74 51-143 Aldrin 0.640 0.050 ug/L 1.000 64 45-134 alpha-BHC 0.680 0.050 ug/L 1.000 68 54-138 cis -Chlordane 0.680 0.10 ug/L 1.000 68 60-129 beta-BHC 0.640 0.050 ug/L 1.000 64 56-136 delta-BHC 0.680 0.050 ug/L 1.000 68 52-142 Dieldrin 0.710 0.050 ug/L 1.000 71 60-136 Endosulfan 1 0.690 0.050 ug/L 1.000 69 62-126 Endosulfan II 0.710 0.050 ug/L 1.000 71 52-135 Endosulfan Sulfate 0.670 0.050 ug/L 1.000 67 62-133 Endrin 0.790 0.050 ug/L 1.000 79 60-138 Endrin Aldehyde 0.630 0.050 ug/L 1.000 63 51-132 Endrin Ketone 0.670 0.10 ug/L 1.000 67 58-134 gamma-BHC 0.670 0.050 ug/L 1.000 67 59-134 trans -Chlordane 0.670 0.10 ug/L 1.000 67 56-136 Heptachlor 0.670 0.050 ug/L 1.000 67 54-130 Heptachlor Epoxide 0.690 0.10 ug/L 1.000 69 61-133 Methoxychlor 0.710 0.10 ug/L 1.000 71 54-145 Surrogate: Decachlorobiphenyl 0.500 ug/L 1.000 50 13-186 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC LCS (POJ0286-BS1) Prepared: 10/16/20 Analyzed: 10/19/20 Surrogate: Tetrachloro-m-xylene 0.730 ug/L 1.000 73 40-134 LCS (POJ0286-BS2) Prepared: 10/16/20 Analyzed: 10/19/20 Chlordane 7.87 0.50 ug/L 10.00 79 62-140 Surrogate: Decachlorobiphenyl 0.580 ug/L 1.000 58 13-186 Surrogate: Tetrachloro-m-xylene 0.630 ug/L 1.000 63 40-134 LCS (POJ0286-BS3) Prepared: 10/16/20 Analyzed: 10/19/20 Toxaphene 9.00 1.0 ug/L 10.00 90 33-134 Surrogate: Decachlorobiphenyl 0.510 ug/L 1.000 51 13-186 Surrogate: Tetrachloro-m-xylene 0.690 ug/L 1.000 69 40-134 LCS Dup (POJ0286-BSD1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD 0.660 0.10 ug/L 1.000 66 56-143 4 30 4,4'-DDE 0.670 0.10 ug/L 1.000 67 57-135 4 30 4,4'-DDT 0.710 0.10 ug/L 1.000 71 51-143 4 30 Aldrin 0.610 0.050 ug/L 1.000 61 45-134 5 30 alpha-BHC 0.660 0.050 ug/L 1.000 66 54-138 3 30 cis -Chlordane 0.650 0.10 ug/L 1.000 65 60-129 5 30 beta-BHC 0.570 0.050 ug/L 1.000 57 56-136 12 30 delta-BHC 0.620 0.050 ug/L 1.000 62 52-142 9 30 Dieldrin 0.680 0.050 ug/L 1.000 68 60-136 4 30 Endosulfan 1 0.670 0.050 ug/L 1.000 67 62-126 3 30 Endosulfan 11 0.690 0.050 ug/L 1.000 69 52-135 3 30 Endosulfan Sulfate 0.630 0.050 ug/L 1.000 63 62-133 6 30 Endrin 0.750 0.050 ug/L 1.000 75 60-138 5 30 Endrin Aldehyde 0.600 0.050 ug/L 1.000 60 51-132 5 30 Endrin Ketone 0.650 0.10 ug/L 1.000 65 58-134 3 30 gamma-BHC 0.640 0.050 ug/L 1.000 64 59-134 5 30 trans -Chlordane 0.640 0.10 ug/L 1.000 64 56-136 5 30 Heptachlor 0.640 0.050 ug/L 1.000 64 54-130 5 30 Heptachlor Epoxide 0.670 0.10 ug/L 1.000 67 61-133 3 30 Methoxychlor 0.680 0.10 ug/L 1.000 68 54-145 4 30 Surrogate: Decachlorobiphenyl 0.560 ug/L 1.000 56 13-186 Surrogate: Tetrachloro-m-xylene 0.680 ug/L 1.000 68 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Matrix Spike (POJ0286-MS1) Source: 0100174-01 Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD BRL 0.22 ug/L BRL 56-143 4,4'-DDE BRL 0.22 ug/L BRL 57-135 4,4'-DDT BRL 0.22 ug/L BRL 51-143 Aldrin BRL 0.11 ug/L BRL 45-134 alpha-BHC BRL 0.11 ug/L BRL 54-138 cis -Chlordane BRL 0.22 ug/L BRL 60-129 beta-BHC BRL 0.11 ug/L BRL 56-136 Chlordane BRL 1.1 ug/L BRL 62-140 delta-BHC BRL 0.11 ug/L BRL 52-142 Dieldrin BRL 0.11 ug/L BRL 60-136 Endosulfan I BRL 0.11 ug/L BRL 62-126 Endosulfan II BRL 0.11 ug/L BRL 52-135 Endosulfan Sulfate BRL 0.11 ug/L BRL 62-133 Endrin BRL 0.11 ug/L BRL 60-138 Endrin Aldehyde BRL 0.11 ug/L BRL 51-132 Endrin Ketone BRL 0.22 ug/L BRL 58-134 gamma-BHC BRL 0.11 ug/L BRL 59-134 trans -Chlordane BRL 0.22 ug/L BRL 56-136 Heptachlor BRL 0.11 ug/L BRL 54-130 Heptachlor Epoxide BRL 0.22 ug/L BRL 61-133 Methoxychlor BRL 0.22 ug/L BRL 54-145 Toxaphene BRL 2.2 ug/L BRL 33-134 Surrogate: Decachlorobiphenyl 1.00 ug/L 2.222 45 13-186 Surrogate: Tetrachloro-m-xylene 1.58 ug/L 2.222 71 40-134 Matrix Spike Dup (POJ0286-MSD1) Source: 0100174-01 Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD BRL 0.22 ug/L BRL 56-143 30 4,4'-DDE BRL 0.22 ug/L BRL 57-135 30 4,4'-DDT BRL 0.22 ug/L BRL 51-143 30 Aldrin BRL 0.11 ug/L BRL 45-134 30 alpha-BHC BRL 0.11 ug/L BRL 54-138 30 cis -Chlordane BRL 0.22 ug/L BRL 60-129 30 beta-BHC BRL 0.11 ug/L BRL 56-136 30 Chlordane BRL 1.1 ug/L BRL 62-140 30 delta-BHC BRL 0.11 ug/L BRL 52-142 30 Dieldrin BRL 0.11 ug/L BRL 60-136 30 Endosulfan I BRL 0.11 ug/L BRL 62-126 30 Endosulfan II BRL 0.11 ug/L BRL 52-135 30 Endosulfan Sulfate BRL 0.11 ug/L BRL 62-133 30 Endrin BRL 0.11 ug/L BRL 60-138 30 Endrin Aldehyde BRL 0.11 ug/L BRL 51-132 30 Endrin Ketone BRL 0.22 ug/L BRL 58-134 30 gamma-BHC BRL 0.11 ug/L BRL 59-134 30 trans -Chlordane BRL 0.22 ug/L BRL 56-136 30 Heptachlor BRL 0.11 ug/L BRL 54-130 30 Heptachlor Epoxide BRL 0.22 ug/L BRL 61-133 30 Methoxychlor BRL 0.22 ug/L BRL 54-145 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Matrix Spike Dup (POJ0286-MSD1) Source: 0100174-01 Prepared: 10/16/20 Analyzed: 10/19/20 Toxaphene BRL 2.2 ug/L BRL 33-134 30 Surrogate: Decachlorobiphenyl 1.31 ug/L 2.222 59 13-186 Surrogate: Tetrachloro-m-xylene 1.47 ug/L 2.222 66 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Blank (POJ0286-BLK1) Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 BRL 0.50 ug/L Aroclor 1221 BRL 1.0 ug/L Aroclor 1232 BRL 0.50 ug/L Aroclor 1242 BRL 0.50 ug/L Aroclor 1248 BRL 0.50 ug/L Aroclor 1254 BRL 0.50 ug/L Aroclor 1260 BRL 1.0 ug/L Surrogate: Tetrachloro-m-xylene 0.610 ug/L 1.000 61 30-161 Surrogate: Decachlorobiphenyl 0.580 ug/L 1.000 58 32-178 LCS (POJ0286-BS4) Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 6.63 0.50 ug/L 10.00 66 50-114 Aroclor 1221 BRL 1.0 ug/L 15-178 Aroclor 1232 BRL 0.50 ug/L 10-215 Aroclor 1242 BRL 0.50 ug/L 39-150 Aroclor 1248 BRL 0.50 ug/L 38-158 Aroclor 1254 BRL 0.50 ug/L 29-131 Aroclor 1260 7.65 1.0 ug/L 10.00 76 10-127 Surrogate: Tetrachloro-m-xylene 0.620 ug/L 1.000 62 30-161 Surrogate: Decachlorobiphenyl 0.690 ug/L 1.000 69 32-178 Matrix Spike (POJ0286-MS1) Source: 0100174-01 Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 15.2 1.1 ug/L 22.22 BRL 68 50-114 Aroclor 1221 BRL 2.2 ug/L BRL 15-178 Aroclor 1232 BRL 1.1 ug/L BRL 10-215 Aroclor 1242 BRL 1.1 ug/L BRL 39-150 Aroclor 1248 BRL 1.1 ug/L BRL 38-158 Aroclor 1254 BRL 1.1 ug/L BRL 29-131 Aroclor 1260 15.0 2.2 ug/L 22.22 BRL 68 10-127 Surrogate: Tetrachloro-m-xylene 1.58 ug/L 2.222 71 30-161 Surrogate: Decachlorobiphenyl 1.00 ug/L 2.222 45 32-178 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Asheville, NC 28801 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Matrix Spike Dup (POJ0286-MSD1) Source: 0100174-01 Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 14.4 1.1 ug/L 22.22 BRL 65 50-114 6 50 Aroclor 1221 BRL 2.2 ug/L BRL 15-178 50 Aroclor 1232 BRL 1.1 ug/L BRL 10-215 50 Aroclor 1242 BRL 1.1 ug/L BRL 39-150 50 Aroclor 1248 BRL 1.1 ug/L BRL 38-158 50 Aroclor 1254 BRL 1.1 ug/L BRL 29-131 50 Aroclor 1260 15.7 2.2 ug/L 22.22 BRL 71 10-127 5 50 Surrogate: Tetrachloro-m-xylene 1.47 ug/L 2.222 66 30-161 Surrogate: Decachlorobiphenyl 1.31 ug/L 2.222 59 32-178 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0239 - 3005A Blank (POJ0239-BLK1) Prepared: 10/15/20 Analyzed: 10/23/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 2.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Thallium BRL 2.0 ug/L Tin BRL 5.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (POJ0239-BS1) Prepared: 10/15/20 Analyzed: 10/23/20 Antimony 103 2.0 ug/L 100.0 103 80-120 Arsenic 96.8 1.0 ug/L 100.0 97 80-120 Barium 99.1 2.0 ug/L 100.0 99 80-120 Beryllium 93.3 1.0 ug/L 100.0 93 80-120 Cadmium 98.1 1.0 ug/L 100.0 98 80-120 Chromium 96.2 2.0 ug/L 100.0 96 80-120 Cobalt 100 2.0 ug/L 100.0 100 80-120 Copper 97.5 10 ug/L 100.0 97 80-120 Lead 98.4 1.0 ug/L 100.0 98 80-120 Nickel 98.4 3.0 ug/L 100.0 98 80-120 Selenium 93.8 5.0 ug/L 100.0 94 80-120 Thallium 96.8 2.0 ug/L 100.0 97 80-120 Tin 102 5.0 ug/L 100.0 102 80-120 Vanadium 96.5 5.0 ug/L 100.0 97 80-120 Zinc 94.1 20 ug/L 100.0 94 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0374 - 7470A Blank (POJ0374-BLK1) Prepared & Analyzed: 10/20/20 Mercury BRL 0.20 ug/L LCS (POJ0374-BS1) Prepared &Analyzed: 10/20/20 Mercury 8.17 0.20 ug/L 9.375 87 80-120 Batch POJ0490 - 3005A Blank (POJ0490-BLK1) Prepared & Analyzed: 10/27/20 Silver BRL 1.0 ug/L LCS (POJ0490-BS1) Prepared &Analyzed: 10/27/20 Silver 97.6 1.0 ug/L 100.0 98 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 62 Level II QC Report 0int 12/31/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Dissolved Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POL0504 - 7470A Blank (POL0504-BLK1) Prepared & Analyzed: 12/28/20 Mercury BRL 0.20 ug/L LCS (POL0504-BS1) Prepared &Analyzed: 12/28/20 Mercury 9.67 0.20 ug/L 9.375 103 80-120 Matrix Spike (POL0504-MS1) Source: 0100174-01 Prepared & Analyzed: 12/28/20 Mercury 6.23 0.20 ug/L 9.375 BRL 66 80-120 MI Matrix Spike Dup (POL0504-MSD1) Source: 0100174-01 Prepared & Analyzed: 12/28/20 Mercury 6.17 0.20 ug/L 9.375 BRL 66 80-120 0.9 20 MI Post Spike (POL0504-PS1) Source: 0100174-01 Prepared & Analyzed: 12/28/20 Mercury 2.73 ug/L 3.750-0.00536 73 85-115 MI Batch POL0558 - 3005A Blank (POL0558-BLK1) Prepared & Analyzed: 12/30/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium 1.22 5.0 ug/L J Silver BRL 1.0 ug/L Thallium BRL 2.0 ug/L Tin BRL 5.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POL0558 - 3005A LCS (POL0558-BS1) Prepared &Analyzed: 12/30/20 Antimony 86.6 2.0 ug/L 100.0 87 80-120 Arsenic 97.2 1.0 ug/L 100.0 97 80-120 Barium 98.0 10 ug/L 100.0 98 80-120 Beryllium 95.8 1.0 ug/L 100.0 96 80-120 Cadmium 99.0 1.0 ug/L 100.0 99 80-120 Chromium 101 2.0 ug/L 100.0 101 80-120 Cobalt 100 2.0 ug/L 100.0 100 80-120 Copper 97.1 10 ug/L 100.0 97 80-120 Lead 97.6 1.0 ug/L 100.0 98 80-120 Nickel 99.0 3.0 ug/L 100.0 99 80-120 Selenium 105 5.0 ug/L 100.0 105 80-120 Silver 97.8 1.0 ug/L 100.0 98 80-120 Thallium 96.9 2.0 ug/L 100.0 97 80-120 Tin 96.2 5.0 ug/L 100.0 96 80-120 Vanadium 97.8 5.0 ug/L 100.0 98 80-120 Zinc 93.2 20 ug/L 100.0 93 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0250 - NO PREP Blank (POJ0250-BLK1) Prepared & Analyzed: 10/14/20 Chloride BRL 1000 ug/L Nitrate as N BRL 200 ug/L Sulfate BRL 2000 ug/L LCS (POJ0250-BS1) Prepared &Analyzed: 10/14/20 Chloride 41200 1000 ug/L 40000 103 80-120 Nitrate as N 4010 210 ug/L 4000 100 80-120 Sulfate 41400 2100 ug/L 40000 104 80-120 Matrix Spike (POJ0250-MS1) Source: 0100174-03 Prepared & Analyzed: 10/14/20 Chloride 42600 1000 ug/L 40000 1100 104 80-120 Nitrate as N 4110 210 ug/L 4000 96.3 100 80-120 Sulfate 43700 2100 ug/L 40000 828 107 80-120 Matrix Spike Dup (POJ0250-MSD1) Source: 0100174-03 Prepared & Analyzed: 10/14/20 Chloride 42200 1000 ug/L 40000 1100 103 80-120 0.9 15 Nitrate as N 4050 210 ug/L 4000 96.3 99 80-120 1 15 Sulfate 43000 2100 ug/L 40000 828 105 80-120 2 15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 62 • 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Batch POJ0276 - NO PREP Level II QC Report 12/31 /20 Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Project No: 50-02 Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (POJ0276-BLK1) Prepared & Analyzed: 10/14/20 Biochemical Oxygen Demand BRL 2000 ug/L LCS (POJ0276-BS1) Prepared &Analyzed: 10/14/20 Biochemical Oxygen Demand 189000 2000 ug/L 198000 95 84.6-115.4 Batch POJ0282 - NO PREP Blank (POJ0282-BLK1) Prepared & Analyzed: 10/15/20 Ferrous Iron BRL 200 ug/L LCS (POJ0282-BSI) Prepared &Analyzed: 10/15/20 Ferrous Iron 1930 200 ug/L 2000 96 90-110 Matrix Spike (POJ0282-MS1) Source: 0100174-03 Prepared & Analyzed: 10/15/20 Ferrous Iron 1880 200 ug/L 2000 BRL 94 80-120 HT Matrix Spike Dup (POJ0282-MSD1) Source: 0100174-03 Prepared & Analyzed: 10/15/20 Ferrous Iron 1860 200 ug/L 2000 BRL 93 80-120 0.6 20 HT Batch POJ0337 - SM4500-S C Blank (POJ0337-BLK1) Prepared & Analyzed: 10/19/20 Sulfide BRL 2000 ug/L LCS (POJ0337-BS1) Prepared &Analyzed: 10/19/20 Sulfide 7900 2000 ug/L 10000 79 70-122 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0341 - NO PREP Blank (POJ0341-BLK1) Prepared & Analyzed: 10/19/20 Total Alkalinity to pH 4.5 BRL 5000 ug/L LCS (POJ0341-BS1) Prepared &Analyzed: 10/19/20 Total Alkalinity to pH 4.5 249000 5000 ug/L 90-110 Batch POJ0357 - 901OC Blank (POJ0357-BLK1) Prepared & Analyzed: 10/20/20 Cyanide BRL 0.025 mg/L LCS (POJ0357-BS1) Prepared &Analyzed: 10/20/20 Cyanide 0.0965 0.025 mg/L 0.1000 96 85-115 Batch POJ0361 - NO PREP Blank (POJ0361-BLK1) Prepared & Analyzed: 10/19/20 Chemical Oxygen Demand BRL 50000 ug/L LCS (POJ0361-BS1) Prepared &Analyzed: 10/19/20 Chemical Oxygen Demand 498000 50000 ug/L 90-110 Batch POL0392 - NO PREP LCS (POL0392-BS1) Prepared &Analyzed: 12/18/20 pH 6.87 pH Units 6.870 100 98.5-101.5 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 62 • 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POL0392 - NO PREP Duplicate (POL0392-DUP1) Source: 0100174-03 Prepared &Analyzed: 12/18/20 pH 7.10 pH Units 7.12 0.281 10 HT Temperature 20.0 °C 20.0 0.00 20 HT This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 62 0int- Level II QC Report Waypo 12/31/20 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 8270 Extended List - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517325 - 3510C BSD (0100174 LCSD-L517325) Source: 0100174 LCS-L517Prepared: 10/19/20 Analyzed: 10/21/20 5-Nitro-o-toluidine 48.6 10.0 pg/L 50 45.1 97.2 20-120 7.4 20 o-Toluidine 29.9 10.0 pg/L 50 29.4 59.8 20-120 1.6 20 3-Methylcholanthrene 57.1 10.0 pg/L 50 53 114 20-120 7.4 20 4-Aminobiphenyl 38.8 10.0 pg/L 50 37 77.6 20-120 4.7 20 N-Nitrosopyrrolidine 34.3 10.0 pg/L 50 34.4 68.6 20-120 0.2 20 N-Nitrosopiperidine 34.1 10.0 pg/L 50 33.6 68.2 20-120 1.4 20 N-Nitrosomethylethylamine 27.4 10.0 pg/L 50 26.2 54.8 20-120 4.4 20 7,12-Dimethylbenz(a)anthracene 58.1 10.0 pg/L 50 48.7 116 20-120 17.6 20 Methapyrilene 49.8 10.0 pg/L 50 35.1 99.6 20-120 34.6 20 LCD2 2-Naphthylamine 20.3 10.0 pg/L 50 22.7 40.6 20-120 11.1 20 Hexachloropropene 22.6 10.0 pg/L 50 18.9 45.2 20-120 17.8 20 p-Phenylenediamine 0 10.0 pg/L 50 0 0 20-120 0 20 L Diallate 48.4 10.0 pg/L 50 48.3 96.8 20-120 0.2 20 Pronamide 56.1 10.0 pg/L 50 51 112 20-120 9.5 20 p-Dimethylaminoazobenzene 61.3 10.0 pg/L 50 51.1 123 20-120 18.1 20 LH Safrole 39.9 10.0 pg/L 50 39.7 79.8 20-120 0.5 20 Kepone 60 10.0 pg/L 50 53.4 120 20-120 11.6 20 2-Acetylaminofluorene 49.1 10.0 pg/L 50 53.1 98.2 20-120 7.8 20 1-Naphthylamine 28.8 10.0 pg/L 50 28.9 57.6 20-120 0.3 20 1,3,5-Trinitrobenzene 65.8 10.0 pg/L 50 60.4 132 20-120 8.5 20 LH Isosafrole 43.9 10.0 pg/L 50 41.9 87.8 20-120 4.6 20 1,4-Naphthoquinone 44.6 10.0 pg/L 50 41.7 89.2 20-120 6.7 20 BS (0100174 LCS-L517325) Prepared: 10/19/20 Analyzed: 10/21/20 Isosafrole 41.9 10.0 pg/L 50 83.8 20-120 Kepone 53.4 10.0 pg/L 50 107 20-120 Safrole 39.7 10.0 pg/L 50 79.4 20-120 Methapyrilene 35.1 10.0 pg/L 50 70.2 20-120 p-Dimethylaminoazobenzene 51.1 10.0 pg/L 50 102 20-120 Pronamide 51 10.0 pg/L 50 102 20-120 N-Nitrosopiperidine 33.6 10.0 pg/L 50 67.2 20-120 p-Phenylenediamine 0 10.0 pg/L 50 0 20-120 L N-Nitrosopyrrolidine 34.4 10.0 pg/L 50 68.8 20-120 o-Toluidine 29.4 10.0 pg/L 50 58.8 20-120 N-Nitrosomethylethylamine 26.2 10.0 pg/L 50 52.4 20-120 5-Nitro-o-toluidine 45.1 10.0 pg/L 50 90.2 20-120 2-Naphthylamine 22.7 10.0 pg/L 50 45.4 20-120 3-Methylcholanthrene 53 10.0 pg/L 50 106 20-120 4-Aminobiphenyl 37 10.0 pg/L 50 74 20-120 1-Naphthylamine 28.9 10.0 pg/L 50 57.8 20-120 2-Acetylaminofluorene 53.1 10.0 pg/L 50 106 20-120 1,4-Naphthoquinone 41.7 10.0 pg/L 50 83.4 20-120 7,12-Dimethylbenz(a)anthracene 48.7 10.0 pg/L 50 97.4 20-120 Diallate 48.3 10.0 pg/L 50 96.6 20-120 Hexachloropropene 18.9 10.0 pg/L 50 37.8 20-120 1,3,5-Trinitrobenzene 60.4 10.0 pg/L 50 121 20-120 LH This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 8270 Extended List - Quality Control Analyte Batch L517325 - 3510C Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes BILK (0100174 LRB-L517325) Prepared: 10/19/20 Analyzed: 10/20/20 Safrole U 10.0 pg/L - 1,4-Naphthoquinone U 10.0 pg/L 2-Naphthylamine U 10.0 pg/L Kepone U 10.0 pg/L p-Phenylenediamine U 10.0 pg/L Hexachloropropene U 10.0 pg/L p-Dimethylaminoazobenzene U 10.0 pg/L 1,3,5-Trinitrobenzene U 10.0 pg/L 2-Acetylaminofluorene U 10.0 pg/L Pronamide U 10.0 pg/L Methapyrilene U 20.0 pg/L 1-Naphthylamine U 10.0 pg/L o-Toluidine U 10.0 pg/L Isosafrole U 10.0 pg/L Diallate U 10.0 pg/L 7,12-Dimethylbenz(a)anthracene U 10.0 pg/L N-Nitrosomethylethylamine U 10.0 pg/L 5-Nitro-o-toluidine U 10.0 pg/L 4-Aminobiphenyl U 10.0 pg/L N-Nitrosopiperidine U 10.0 pg/L N-Nitrosopyrrolidine U 10.0 pg/L 3-Methylcholanthrene U 10.0 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Phenoxy Acid Herbicides - GC/ECD - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517362 - 8151A BSD (0100174 LCSD-L517362) Source: 0100174 LCS-L517Prepared: 10/19/20 Analyzed: 10/20/20 2,4,5-T 0.2697 0.01002 pg/L 0.5 0.2279 53.9 20-120 16.8 20 2,4-D 2.493 0.2078 pg/L 5 1.997 49.8 20-120 22 20 LCD2 Dalapon 3.626 0.5149 pg/L 12.5 4.011 29 20-120 10 20 Dichlorprop 2.547 0.07959 pg/L 5 2.019 50.9 20-120 23.1 20 LCD2 2,4-DB 2.624 0.1364 pg/L 5 2.123 52.4 20-120 21.1 20 LCD2 Dinoseb 1.507 0.02698 pg/L 2.5 1.16 60.2 20-120 26 20 LCD2 Dicamba 0.255 0.05700 pg/L 0.5 0.2384 51 20-120 6.7 20 MCPA 250.8 18.98 pg/L 500 200.4 50.1 20-120 22.3 20 LCD2 MCPP 301.9 11.75 pg/L 500 258.1 60.3 20-120 15.6 20 Picloram 0.6016 0.04528 pg/L 1.25 0.4532 48.1 20-120 28.1 20 LCD2 2,4,5-TP (Silvex) 0.2371 0.01634 pg/L 0.5 0.187 47.4 20-120 23.6 20 LCD2 Surrogate: DCAA 1.393 ug/L 2.5 1.156 55.7 20-150 BS (0100174 LCS-L517362) Prepared: 10/19/20 Analyzed: 10/20/20 MCPA 200.4 18.98 pg/L 500 40 20-120 Dinoseb 1.16 0.02698 pg/L 2.5 46.4 20-120 MCPP 258.1 11.75 pg/L 500 51.6 20-120 Dichlorprop 2.019 0.07959 pg/L 5 40.3 20-120 Dicamba 0.2384 0.05700 pg/L 0.5 47.6 20-120 Picloram 0.4532 0.04528 pg/L 1.25 36.2 20-120 2,4-D 1.997 0.2078 pg/L 5 39.9 20-120 Dalapon 4.011 0.5149 pg/L 12.5 32 20-120 2,4,5-T 0.2279 0.01002 pg/L 0.5 45.5 20-120 2,4-DB 2.123 0.1364 pg/L 5 42.4 20-120 2,4,5-TP (Silvex) 0.187 0.01634 pg/L 0.5 37.4 20-120 Surrogate: DCAA 1.156 ug/L 2.5 46.2 20-150 BLK (0100174 LRB-L517362) Prepared: 10/19/20 Analyzed: 10/20/20 2,4,5-TP (Silvex) U 0.1000 pg/L - Picloram U 0.1000 pg/L 2,4,5-T U 0.03000 pg/L Dicamba U 0.1000 pg/L MCPP U 50.00 pg/L MCPA U 50.00 pg/L 2,4-DB U 0.1000 pg/L Dinoseb U 0.1000 pg/L Dichlorprop U 0.1000 pg/L Dalapon U 0.5500 pg/L 2,4-D U 0.2500 pg/L - Surrogate: DCAA 1.286 ug/L 2.5 51.4 20-150 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BSD (0100174 LCSD-L517328) Source: 0100174 LCS-L517Prepared & Analyzed: 10/19/20 3,3'-Dichlorobenzidine 112 3.74 pg/L 150 95.9 74.6 6-192 15.4 20 Dimethyl phthalate 36.4 0.510 pg/L 50 33 72.8 34-123 9.7 20 3,3' Dimethylbenzidine 76.3 1.88 pg/L 200 55.8 38.1 6-192 31 20 LCD2 Diethyl phthalate 36.5 0.585 pg/L 50 33.6 73 36-130 8.2 20 Dibenzofuran 36.3 0.423 pg/L 50 33.2 72.6 40-108 8.9 20 3-Nitroaniline 36.9 1.53 pg/L 50 32.3 73.8 28-142 13.2 20 Benzidine 49.1 0.689 pg/L 150 37.5 32.7 2-176 26.7 20 LCD2 Dibenz(a,h)anthrace ne 34.2 0.252 pg/L 50 29.9 68.4 27-124 13.4 20 Hexachlorobenzene 36.2 2.57 pg/L 50 33.6 72.4 18-136 7.4 20 4,6-Dinitro-2-methylphenol 35.7 3.47 pg/L 50 47.1 71.4 27-128 27.5 20 LCD2 Di-n-butyl phthalate 37 1.58 pg/L 50 34.5 74 19-158 6.9 20 2-Nitrophenol 32.4 0.606 pg/L 50 28.6 64.8 25-114 12.4 20 Di-n-Octyl Phthalate 44.9 1.72 pg/L 50 36.4 89.8 29-136 20.9 20 LCD2 2-Nitroaniline 38.4 0.574 pg/L 50 35 76.8 32-127 9.2 20 2-Methylphenol 25 0.721 pg/L 50 22 50 22-97 12.7 20 Fluoranthene 39 0.406 pg/L 50 36 78 28-127 8 20 4-Bromophenyl phenyl ether 36.7 0.500 pg/L 50 33.4 73.4 31-124 9.4 20 2-Methyl naphthalene 32.1 0.485 pg/L 50 29.7 64.2 34-108 7.7 20 4-Nitrophenol 11.3 1.39 pg/L 50 10.6 22.6 1-76 6.3 20 Hexachlorobutadiene 25.5 0.405 pg/L 50 22.5 51 22-109 12.5 20 Hexachlorocyclopentadiene 12.1 2.34 pg/L 50 13.9 24.2 10-102 13.8 20 Fluorene 34.1 0.444 pg/L 50 31.4 68.2 41-116 8.2 20 Benzyl alcohol 23.8 3.01 pg/L 50 20.5 47.6 20-109 14.8 20 2-Chlorophenol 28.4 0.736 pg/L 50 25 56.8 27-102 12.7 20 Benzo(a)pyrene 35.5 1.00 pg/L 50 30.9 71 34-131 13.8 20 Benzo(b)fluoranthene 41.4 0.941 pg/L 50 38.4 82.8 36-131 7.5 20 Anthracene 36.1 0.467 pg/L 50 33.8 72.2 34-128 6.5 20 Benzo(g,h,i)perylene 33.7 1.36 pg/L 50 30.6 67.4 26-123 9.6 20 Aniline 22.1 0.316 pg/L 50 18.1 44.2 16-133 19.9 20 Acetophenone 31.3 0.686 pg/L 50 27.2 62.6 25-108 14 20 Benzo(k)fluoranthene 43.7 0.752 pg/L 50 34.5 87.4 32-132 23.5 20 LCD2 Acenaphthylene 32.8 0.429 pg/L 50 29.7 65.6 37-114 9.9 20 Bis(2-Chloroisopropyl)ether 22.2 0.546 pg/L 50 19.4 44.4 28-108 13.4 20 Acenaphthene 31.1 0.422 pg/L 50 27.4 62.2 38-117 12.6 20 Chrysene 36 0.731 pg/L 50 32.3 72 30-124 10.8 20 Bis(2-Chloroethoxy)methane 30.7 0.433 pg/L 50 27.3 61.4 20-126 11.7 20 Bis(2-Chloroethyl)ether 28.8 0.447 pg/L 50 25.1 57.6 16-122 13.7 20 4-Nitroaniline 53.9 0.740 pg/L 50 52.8 108 23-139 2 20 4-Chlorophenyl phenyl ether 34.8 0.479 pg/L 50 32.5 69.6 39-110 6.8 20 Bis(2-ethylhexyl)phthalate 37.9 3.66 pg/L 50 37.4 75.8 21-162 1.3 20 Butyl benzyl phthalate 38.1 4.59 pg/L 50 39.7 76.2 33-142 4.1 20 4-Chloroaniline 28.7 0.526 pg/L 50 24.4 57.4 24-127 16.1 20 Carbazole 42.2 0.476 pg/L 50 39.1 84.4 20-147 7.6 20 4-Chloro-3-methylphenol 36.3 0.503 pg/L 50 32.5 72.6 35-117 11 20 Benzoic Acid 18.9 5.00 pg/L 150 30.6 12.6 11-68 47.2 20 LCD2 Phenanthrene 36.1 0.464 pg/L 50 33.2 72.2 40-120 8.3 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BSD (0100174 LCSD-L517328) Source: 0100174 LCS-L517Prepared & Analyzed: 10/19/20 2,4-Dichlorophenol 25.7 1.52 pg/L 50 23.3 51.4 32-110 9.7 20 N-Nitrosodiethylamine 32.6 0.400 pg/L 50 28.1 65.2 25-107 14.8 20 N-Nitrosodimethylamine 15.1 0.249 pg/L 50 12.8 30.2 14-84 16.4 20 N-Nitroso-di-n-butylamine 30 0.752 pg/L 50 26.5 60 25-126 12.3 20 N-Nitroso-di-n-propylamine 28.9 0.334 pg/L 50 25.3 57.8 29-114 13.2 20 2,4,5-Trichlorophenol 39.4 0.350 pg/L 50 35.1 78.8 26-118 11.5 20 N-Nitrosodiphenylamine 31 0.783 pg/L 50 27.7 62 45-135 11.2 20 2,3,4,6-Tetrachlorophenol 38.5 0.355 pg/L 50 35.7 77 28-118 7.5 20 2,4-Dimethylphenol 33.7 0.674 pg/L 50 30.2 67.4 34-105 10.9 20 1,4-Dichlorobenzene 24.8 0.580 pg/L 50 21.3 49.6 24-99 15.1 20 2,4,6-Trichlorophenol 38.5 0.344 pg/L 50 34.3 77 26-115 11.5 20 1,3-Dichlorobenzene 24.2 0.491 pg/L 50 20.6 48.4 21-102 16 20 Phenol 11.9 0.389 pg/L 50 10.5 23.8 11-55 12.5 20 Benzo(a)anthracene 35.3 0.427 pg/L 50 32.5 70.6 36-127 8.2 20 1,2-Dichlorobenzene 25.5 0.629 pg/L 50 22.5 51 26-100 12.5 20 3&4 Methylphenol 26.8 0.691 pg/L 50 23.7 53.6 21-96 12.2 20 Pyrene 33 1.04 pg/L 50 40.7 66 20-154 20.8 20 L 1,2,4-Trichlorobenzene 27.3 0.482 pg/L 50 24.3 54.6 23-106 11.6 20 1,2,4,5-Tetrachlorobenzene 30.2 0.317 pg/L 50 26.8 60.4 28-110 11.9 20 Pyridine 15.7 0.678 pg/L 50 12.9 31.4 10-71 19.5 20 Pentachlorophenol 48.7 2.45 pg/L 50 49.5 97.4 17-142 1.6 20 Naphthalene 28 0.484 pg/L 50 24.7 56 33-108 12.5 20 2,6-Dichlorophenol 35.5 0.703 pg/L 50 31.1 71 25-112 13.2 20 Isophorone 26.6 0.360 pg/L 50 23.3 53.2 31-116 13.2 20 2,6-Dinitrotoluene 36.8 0.413 pg/L 50 33.5 73.6 36-125 9.3 20 Nitrobenzene 30 0.531 pg/L 50 26.3 60 27-117 13.1 20 2-Chloronaphthalene 29.5 0.476 pg/L 50 26 59 29-137 12.6 20 2,4-Dinitrotoluene 35.3 0.403 pg/L 50 33.4 70.6 24-147 5.5 20 2,4-Dinitrophenol 77.8 4.85 pg/L 150 103 51.8 10-132 27.8 20 LCD2 Hexachloroethane 21.7 0.277 pg/L 50 19 43.4 16-107 13.2 20 Indeno(1,2,3-cd)pyrene 40.4 1.01 pg/L 50 33.1 80.8 22-126 19.8 20 Surrogate:2-Fluorophenol 23.5 pg/L 100 20.2 23.5 10-44 Surrogate:2-Fluorobiphenyl 45 pg/L 100 43.6 45 24-93 Surrogate: Phenol-d6 16.4 pg/L 100 14.8 16.4 7-32 Surrogate:4-Terphenyl-d14 55.2 pg/L 100 74.7 55.2 35-126 Surrogate: 2,4,6-Tribromophenol 67.8 pg/L 100 63.3 67.8 39-110 Surrogate: Nitrobenzene-d5 49.7 pg/L 100 47.4 49.7 20-91 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 62 • 0 Waypoint ANALYTICAL Level II QC Report 12/31 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100174 Attn: Alec Macbeth Time Submitted: 10/14/2020 9:10:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BS (0100174 LCS-L517328) Prepared & Analyzed: 10/19/20 Isophorone 23.3 0.360 pg/L 50 46.6 31-116 Phenol 10.5 0.389 pg/L 50 21 11-55 Fluorene 31.4 0.444 pg/L 50 62.8 41-116 Phenanthrene 33.2 0.464 pg/L 50 66.4 40-120 Benzyl alcohol 20.5 3.01 pg/L 50 41 20-109 Bis(2-Chloroethoxy)methane 27.3 0.433 pg/L 50 54.6 20-126 Hexachlorobenzene 33.6 2.57 pg/L 50 67.2 18-136 Benzoic Acid 30.6 5.00 pg/L 150 20.4 11-68 Indeno(1,2,3-cd)pyrene 33.1 1.01 pg/L 50 66.2 22-126 Benzo(k)fluoranthene 34.5 0.752 pg/L 50 69 32-132 Benzo(g,h,i)perylene 30.6 1.36 pg/L 50 61.2 26-123 Pyrene 40.7 1.04 pg/L 50 81.4 20-154 Pyridine 12.9 0.678 pg/L 50 25.8 10-71 Benzo(b)fluoranthene 38.4 0.941 pg/L 50 76.8 36-131 Hexachloroethane 19 0.277 pg/L 50 38 16-107 Benzo(a)pyrene 30.9 1.00 pg/L 50 61.8 34-131 Hexachlorobutadiene 22.5 0.405 pg/L 50 45 22-109 Dimethyl phthalate 33 0.510 pg/L 50 66 34-123 N-Nitrosodiethylamine 28.1 0.400 pg/L 50 56.2 25-107 Diethyl phthalate 33.6 0.585 pg/L 50 67.2 36-130 Di-n-butyl phthalate 34.5 1.58 pg/L 50 69 19-158 N-Nitrosodimethylamine 12.8 0.249 pg/L 50 25.6 14-84 Dibenzofuran 33.2 0.423 pg/L 50 66.4 40-108 Dibenz(a,h)anthrace ne 29.9 0.252 pg/L 50 59.8 27-124 Di-n-Octyl Phthalate 36.4 1.72 pg/L 50 72.8 29-136 Pentachlorophenol 49.5 2.45 pg/L 50 99 17-142 Hexachlorocyclopentadiene 13.9 2.34 pg/L 50 27.8 10-102 Bis(2-Chloroethyl)ether 25.1 0.447 pg/L 50 50.2 16-122 Carbazole 39.1 0.476 pg/L 50 78.2 20-147 Nitrobenzene 26.3 0.531 pg/L 50 52.6 27-117 N-Nitroso-di-n-propylamine 25.3 0.334 pg/L 50 50.6 29-114 Butyl benzyl phthalate 39.7 4.59 pg/L 50 79.4 33-142 Naphthalene 24.7 0.484 pg/L 50 49.4 33-108 Fluoranthene 36 0.406 pg/L 50 72 28-127 Bis(2-ethylhexyl)phthalate 37.4 3.66 pg/L 50 74.8 21-162 Bis(2-Chloroisopropyl)ether 19.4 0.546 pg/L 50 38.8 28-108 N-Nitrosodiphenylamine 27.7 0.783 pg/L 50 55.4 45-135 N-Nitroso-di-n-butylamine 26.5 0.752 pg/L 50 53 25-126 Chrysene 32.3 0.731 pg/L 50 64.6 30-124 2,4-Dinitrophenol 103 4.85 pg/L 150 68.6 10-132 2,4,5-Trichlorophenol 35.1 0.350 pg/L 50 70.2 26-118 4-Chlorophenyl phenyl ether 32.5 0.479 pg/L 50 65 39-110 4-Chloroaniline 24.4 0.526 pg/L 50 48.8 24-127 2,4,6-Trichlorophenol 34.3 0.344 pg/L 50 68.6 26-115 4-Bromophenyl phenyl ether 33.4 0.500 pg/L 50 66.8 31-124 2,4-Dichlorophenol 23.3 1.52 pg/L 50 46.6 32-110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 55 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BS (0100174 LCS-L517328) Prepared & Analyzed: 10/19/20 4,6-Dinitro-2-methylphenol 47.1 3.47 pg/L 50 94.2 27-128 2,4-Dimethylphenol 30.2 0.674 pg/L 50 60.4 34-105 3-Nitroaniline 32.3 1.53 pg/L 50 64.6 28-142 3,3'-Dichlorobenzidine 95.9 3.74 pg/L 150 63.9 6-192 4-Nitroaniline 52.8 0.740 pg/L 50 106 23-139 3&4 Methylphenol 23.7 0.691 pg/L 50 47.4 21-96 4-Chloro-3-methylphenol 32.5 0.503 pg/L 50 65 35-117 2-Nitrophenol 28.6 0.606 pg/L 50 57.2 25-114 2-Nitroaniline 35 0.574 pg/L 50 70 32-127 2,4-Dinitrotoluene 33.4 0.403 pg/L 50 66.8 24-147 2-Methylphenol 22 0.721 pg/L 50 44 22-97 Benzo(a)anthracene 32.5 0.427 pg/L 50 65 36-127 2,6-Dichlorophenol 31.1 0.703 pg/L 50 62.2 25-112 2,6-Dinitrotoluene 33.5 0.413 pg/L 50 67 36-125 2-Methyl naphthalene 29.7 0.485 pg/L 50 59.4 34-108 2-Chloronaphthalene 26 0.476 pg/L 50 52 29-137 2-Chorophenol 25 0.736 pg/L 50 50 27-102 3,3' Dimethylbenzidine 55.8 1.88 pg/L 200 27.9 6-192 1,4-Dichlorobenzene 21.3 0.580 pg/L 50 42.6 24-99 1,2-Dichlorobenzene 22.5 0.629 pg/L 50 45 26-100 Acetophenone 27.2 0.686 pg/L 50 54.4 25-108 Aniline 18.1 0.316 pg/L 50 36.2 16-133 Acenaphthene 27.4 0.422 pg/L 50 54.8 38-117 1,3-Dichlorobenzene 20.6 0.491 pg/L 50 41.2 21-102 Acenaphthylene 29.7 0.429 pg/L 50 59.4 37-114 1,2,4-Trichlorobenzene 24.3 0.482 pg/L 50 48.6 23-106 Anthracene 33.8 0.467 pg/L 50 67.6 34-128 Benzidine 37.5 0.689 pg/L 150 25 2-176 2,3,4,6-Tetrachlorophenol 35.7 0.355 pg/L 50 71.4 28-118 1,2,4,5-Tetrachlorobenzene 26.8 0.317 pg/L 50 53.6 28-110 4-Nitrophenol 10.6 1.39 pg/L 50 21.2 1-76 Surrogate: Phenol-d6 14.8 Ng/L 100 14.8 7-32 Surrogate: Nitrobenzene-d5 47.4 pg/L 100 47.4 20-91 Surrogate: 2,4,6-Tribromophenol 63.3 Ng/L 100 63.3 39-110 Surrogate:2-Fluorophenol 20.2 Ng/L 100 20.2 10-44 Surrogate:2-Fluorobiphenyl 43.6 Ng/L 100 43.6 24-93 Surrogate:4-Terphenyl-d14 74.7 Ng/L 100 74.7 35-126 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 56 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BILK (0100174 LRB-11-517328) Prepared & Analyzed: 10/19/20 Indeno(1,2,3-cd)pyrene U 2.00 pg/L 1,2,4-Trichlorobenzene U 5.00 pg/L 2,6-Dichlorophenol U 5.00 pg/L 2,6-Dinitrotoluene U 5.00 pg/L Phenol U 5.00 pg/L Pyrene U 2.00 pg/L Naphthalene U 2.00 pg/L 1,2-Dichlorobenzene U 5.00 pg/L Isophorone U 5.00 pg/L 2,4-Dinitrotoluene U 5.00 pg/L Pyridine U 10.0 pg/L 1,2,4,5-Tetrachlorobenzene U 5.00 pg/L Phenanthrene U 2.00 pg/L N-Nitrosodiphenylamine U 10.0 pg/L N-Nitroso-di-n-propylamine U 5.00 pg/L 2,4,5-Trichlorophenol U 5.00 pg/L Pentachlorophenol U 10.0 pg/L N-Nitroso-di-n-butylamine U 5.00 pg/L 2-Methyl naphthalene U 2.00 pg/L Hexachloroethane U 5.00 pg/L N-Nitrosodimethylamine U 5.00 pg/L Nitrobenzene U 5.00 pg/L 1,4-Dichlorobenzene U 5.00 pg/L 2,4-Dichlorophenol U 5.00 pg/L 1,3-Dichlorobenzene U 5.00 pg/L N-Nitrosodiethylamine U 5.00 pg/L 2,4-Dimethylphenol U 5.00 pg/L 2,3,4,6-Tetrachlorophenol U 5.00 pg/L 2,4-Dinitrophenol U 10.0 pg/L 2,4,6-Trichlorophenol U 5.00 pg/L Acenaphthylene U 2.00 pg/L 2-Chloronaphthalene U 5.00 pg/L Butyl benzyl phthalate U 5.00 pg/L Hexachlorobenzene U 5.00 pg/L 4-Chlorophenyl phenyl ether U 5.00 pg/L 4-Nitroaniline U 5.00 pg/L Bis(2-Chloroisopropyl)ether U 5.00 pg/L Bis(2-Chloroethyl)ether U 5.00 pg/L 4-Nitrophenol U 10.0 pg/L Bis(2-Chloroethoxy)methane U 5.00 pg/L 4-Chloro-3-methylphenol U 5.00 pg/L Acenaphthene U 2.00 pg/L 4-Chloroaniline U 5.00 pg/L Benzoic Acid U 10.0 pg/L Acetophenone U 5.00 pg/L Benzo(k)fluoranthene U 2.00 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 57 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BILK (0100174 LRB-11-517328) Prepared & Analyzed: 10/19/20 Benzo(g,h,i)perylene U 2.00 pg/L Aniline U 5.00 pg/L Anthracene U 2.00 pg/L Benzo(b)fluoranthene U 2.00 pg/L Benzidine U 20.0 pg/L Benzo(a)pyrene U 2.00 pg/L Benzo(a)anthracene U 2.00 pg/L Benzyl alcohol U 10.0 pg/L Di-n-Octyl Phthalate U 5.00 pg/L 2-Chorophenol U 5.00 pg/L Hexachlorocyclopentadiene U 5.00 pg/L Hexachlorobutadiene U 5.00 pg/L 3&4 Methylphenol U 5.00 pg/L Fluorene U 2.00 pg/L 2-Methylphenol U 5.00 pg/L Bis(2-ethylhexyl)phthalate U 5.00 pg/L Fluoranthene U 2.00 pg/L Carbazole U 5.00 pg/L Dibenzofuran U 5.00 pg/L 4-Bromophenyl phenyl ether U 5.00 pg/L Chrysene U 2.00 pg/L 2-Nitroaniline U 5.00 pg/L 4,6-Dinitro-2-methylphenol U 10.0 pg/L 2-Nitrophenol U 5.00 pg/L 3-Nitroaniline U 10.0 pg/L 3,3'-Dichlorobenzidine U 10.0 pg/L Diethyl phthalate U 5.00 pg/L 3,3' Dimethylbenzidine U 10.0 pg/L Dimethyl phthalate U 5.00 pg/L Di-n-butyl phthalate U 5.00 pg/L Dibenz(a,h)anthrace ne U 2.00 pg/L - Surrogate: Phenol-d6 16.3 Ng/L 100 16.3 7-32 Surrogate: Nitrobenzene-d5 54.3 pg/L 100 54.3 20-91 Surrogate: 2,4,6-Tribromophenol 68.5 Ng/L 100 68.5 39-110 Surrogate:4-Terphenyl-d14 71.7 Ng/L 100 71.7 35-126 Surrogate:2-Fluorobiphenyl 47.9 Ng/L 100 47.9 24-93 Surrogate:2-Fluorophenol 24.2 Ng/L 100 24.2 10-44 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 58 of 62 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Organic Carbon - Quality Control Analyte Batch L517921 - 531 OC-2011 Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/31 /20 Work Order: 0100174 Time Submitted: 10/14/2020 9:10:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes MSD (0100174 L 91642-MSD-L517921) Source: 0100174 L 91642-hPrepared: 10/21/20 Analyzed: 10/22/20 TOC 7.6 0.522 mg/L 5.26 7.34 103 70-130 3.4 20 MS (0100174 L 91642-MS-L517921) Prepared: 10/21/20 Analyzed: 10/22/20 TOC 7.34 0.522 mg/L 5.26 98 70-130 BS (0100174 LCS-L517921) Prepared &Analyzed: 10/21/20 TOC 5.24 0.498 mg/L 5 105 85-115 BILK (0100174 LRB-L517921) Prepared & Analyzed: 10/21/20 TOC U 1.00 mg/L - This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 59 of 62 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100174-01 POL0558 50 mL 50 mL 12/30/20 14:30 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100174-01 POL0504 20 mL 30 mL 12/28/20 10:50 Prep Method: 9010C Lab Number Batch Initial Final Date/Time 0100174-01 POJ0357 50 mL 50 mL 10/20/20 8:10 0100174-02 POJ0357 50 mL 50 mL 10/20/20 8:10 0100174-03 POJ0357 50 mL 50 mL 10/20/20 8:10 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 0100174-01 POJ0337 200 mL 200 mL 10/19/20 11:02 0100174-02 POJ0337 200 mL 200 mL 10/19/20 11:02 0100174-03 POJ0337 200 mL 200 mL 10/19/20 11:02 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100174-01 POJ0286 970 mL 10 mL 10/16/20 10:15 0100174-02 POJ0286 990 mL 10 mL 10/16/20 10:15 0100174-03 POJ0286 990 mL 10 mL 10/16/20 10:15 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100174-01 POJ0286 970 mL 10 mL 10/16/20 10:15 0100174-02 POJ0286 990 mL 10 mL 10/16/20 10:15 0100174-03 POJ0286 990 mL 10 mL 10/16/20 10:15 Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100174-01 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-01 POJ0490 50 mL 50 mL 10/27/20 7:00 0100174-01 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-02 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-02 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-02 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-02 POJ0490 50 mL 50 mL 10/27/20 7:00 0100174-03 POJ0239 50 mL 50 mL 10/15/20 7:44 0100174-03 POJ0490 50 mL 50 mL 10/27/20 7:00 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 0100174-01 POJ0374 20 mL 30 mL 10/20/20 11:55 0100174-02 POJ0374 20 mL 30 mL 10/20/20 11:55 0100174-03 POJ0374 20 mL 30 mL 10/20/20 11:55 Prep Method: 5030E Lab Number Batch Initial Final Date/Time This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 60 of 62 Sample Extraction Data Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100174-01 POJ0321 10 mL 10 mL 10/21/20 10:00 0100174-02 POJ0321 10 mL 10 mL 10/21/20 10:00 0100174-03 POJ0321 10 mL 10 mL 10/21/20 10:00 0100174-04 POJ0321 10 mL 10 mL 10/21/20 10:00 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100174-01 POJ0316 5 mL 5 mL 10/16/20 10:00 0100174-02 POJ0316 5 mL 5 mL 10/16/20 10:00 0100174-03 POJ0316 5 mL 5 mL 10/16/20 10:00 Sample Extraction Data Prep Method:3510C Lab Number Batch Initial Final Date/Time 0100174-01 L517325 10/19/20 15:45 0100174-02 L517325 10/19/20 15:45 0100174-03 L517325 10/19/20 15:45 Prep Method: 8151A Lab Number Batch Initial Final Date/Time 0100174-01 L517362 10/19/20 17:11 0100174-02 L517362 10/19/20 17:11 0100174-03 L517362 10/19/20 17:11 Prep Method: 3510C Lab Number Batch Initial Final Date/Time 0100174-01 L517328 10/19/20 15:45 0100174-02 L517328 10/19/20 15:45 0100174-03 L517328 10/19/20 15:45 Prep Method: 5310C-2011 Lab Number Batch Initial Final Date/Time 0100174-01 L517921 10/21/20 14:36 0100174-02 L517921 10/21/20 14:36 0100174-03 L517921 10/21/20 14:36 Subcontracted Analyses The following analyses were subcontracted to Waypoint Analytical, LLC Lab Number Analysis 0100174-01 8270 (App. II) 0100174-01 Herbicides (Sub) 0100174-01 TOC (Sub) 0100174-02 8270 (App. 11) 0100174-02 Herbicides (Sub) 0100174-02 TOC (Sub) 0100174-03 8270 (App. II) 0100174-03 Herbicides (Sub) 0100174-03 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 61 of 62 Waypoint ANALYTICAL 449 Springbrook Road • Charlotte, NC 28217 Phone 704/529-6364 Fax: 704/525-0409 Client Company Name: Vckor QeA 61F WC - Report To/Contact Name' W fir_ Lu'.Qr:+e° Reporting Address: hE!(,gy-dJA &A, r CHAIN OF CUSTODY RECORD PAGE t` OF I --QUOTE # TO ENSURE PROPER BILLING: Project Name: 1ALX-- An Short Hold Analysis (Yes) No) UST Project: (Yes) *Please ATTACH any pr specific reporting (QC LEVEL I II III IV) Provisions and/or QC Requirements Invoice To: n__ Address: YES NO N/A Samples INTACT upon arrival? f Received IN ICE? PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES rec'd W/OUT HEADSPACE? ✓ PROPER CONTAINERS used? TEMP: Therm ID:_ I �j IS Observed?- • 0 *C /Corr. Z - Z) *C Phone: 1?5 el)-", V Fax (Yes)(No): Purchase Order No./Billing ReferenceLnl 6(90 —M .0Z TO BE FILLED IN BY C� IENT/SAMPLING PERSONNEL Email Address: AVlA t.C� ►&''<1,� Ar.'I EDD Type: PDF Excel Other Pcc.('r.4M Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days "Working Days" ❑ 6-9 Days )"ndard 10 days ❑ h Work Must Be Certification' NC - Z SC --�� Site Location Name: r)(k/_.rGS21VM �, �� pre Samples received after 15:00 will be processed next business day. y. Turnaround Other N/A Site Location Physical Address: QS 1 ( C 4,p baG time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO_ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING ERVIPJ=S Samples Iced Upon Collection: YES, RENDERED BY WAYPOINT ANALYTICAL, LLC TO CLIENT) CLIENT DATE TIME COLLECTED MATRIX SAMPLE CONTAINER \�y�V ISgEQ S jD SAMPLE DESCRIPTION COLLECTED MILITARY (SOIL, WATER, OR PRESERVA- TIMES �i��+ -Uy �� .^v ate Q� y a ` ( ID NO. *TYPE NO. SIZE HOURS SLUDGE) SEE BELOW �/U AL b I,/J�i{ta/ i ? �+ ` Y. jC � "' F11>\f- �•- t' ",� (3 .� I3 �� Of, �( Z� ! � � x � ' � � l>11� • fi rZV ©i'3D0 3 30000 hi Zi 40MA- RO X L Sampler's Signature Sampled By (Print Name) MdawioAffiliation dTKaw GAG" LAB USE ONLY Upon relinquishin , his Chain of Custody is your authorization for Waypoint Analytical to proceed with the analyses as requested above. Any changes must be submitted in writin the W point Analytical Project Manager. There will be charges for any changes after analyses have been initialized. Site Arrival Time: Relinquished By: (Sign re) Received By: (' ) Date / Military/Hours Additional Comments: Site Departure Time: \ ReIinqui y: (SiWe Rec . ed By: (S' nature) Date Field Tech Fee: Relinqu' d By: (Si alure Received For Wayp int Analytical By: D/a V Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FOR TRANSPORTATI O HE LABO RY. CO Grou o. RY SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL R VE AT THE LABORATOSEE ❑ Fed Ex ❑ UPS O ? o� REVERSE FOR ❑ Hand -delivered ❑ Waypoint Analytical Field Service El Other TERMS & CONDITIONS NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: BRWNFLD —LANDFILL ❑ NC ❑ SC ElNC ❑ SC �Ic ❑ SC ❑ NC ❑ SC Nc ❑ SC ❑ NC C]sc ❑ NC El SC C ❑ Sc OTHER: ❑ NC ❑ SC Page 62 of 6211 CI Is. D' dl *CONTAINER TYPE Rr?nI=-Q- A - Amh— r = rl—r r_- r_i -.- o - olefin• TI = T.fl—1 inwrl r`.- vnn A.. I--;� 17^— Ll— �____• Way poi nt ANALYTICAL Anchor QEA of North Carolina, PLLC Alec Macbeth 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill 2020 Fall Project No.: 50-02 Lab Submittal Date: 10/15/2020 Work Order: 0100203 Case Narrative 12/1/20 8:48 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Dissolved hydrogen, Carbon dioxide, dissolved gasses and volatile fatty acids analyses were subcontracted to Pace/GCAL. Laboratory report is attached. 524 analysis was subcontracted to Pace Huntersville. Laboratory report is attached. Waypoint Summary of Detections does not include subcontracted data. Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a -,--,I Angela D. Overcash Senior Project Manager This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 96 Data Qualifiers Key Reference: BRL BRL HT Sample received and analyzed outside of the hold time. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L Parameter reported with possible low bias. LCS recovery below the QC limit. LCD2 LCS/LCSD RPD Value outside of the control limits. LCS and LCSD Values within the control limits. LH High LCS recovery. Analyte not detected in the sample(s). No further action taken. SR Surrogate recovery outside of the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 96 0 Waypo i nt .. ANALYTICAL Sample Receipt Summary 12/01 /2020 Work Order: 0100203 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-01-20201014 0100203-01 Water 10/14/20 12:00 10/15/20 8:45 LT-01-20201014 0100203-02 Water 10/14/20 12:25 10/15/20 8:45 SW-01-20201014 0100203-03 Water 10/14/20 13:00 10/15/20 8:45 SW-02-20201014 0100203-04 Water 10/14/20 13:30 10/15/20 8:45 DW-01-20201014 0100203-05 Drinking Water 10/14/20 14:00 10/15/20 8:45 TB-202010140000 0100203-06 Water 10/14/20 0:00 10/15/20 8:45 MW-02-20201013 0100203-07 Water 10/13/20 14:50 10/15/20 8:45 MW-03-20201013 0100203-08 Water 10/13/20 10:29 10/15/20 8:45 MW-06-20201013 0100203-09 Water 10/13/20 13:15 10/15/20 8:45 Samples were received in good condition at 2.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 96 Way poi nt ANALYTICAL Summary of Detections 12/01/202C Work Order: 0100203 Prism ID Client ID Parameter Method Result Units 0100203-01 MW-01-20201014 Chloride 9056A 1200 ug/L 0100203-01 MW-01-20201014 Biochemical Oxygen Demand SM5210 B 3100 ug/L 0100203-01 MW-01-20201014 Chemical Oxygen Demand SM5220 D 24000 J ug/L 0100203-01 MW-01-20201014 Ferrous Iron SM3500-Fe B 39000 HT ug/L 0100203-01 MW-01-20201014 Total Alkalinity to pH 4.5 SM2320 B 100000 ug/L 0100203-01 MW-01-20201014 gamma-BHC 8081B 0.051 ug/L 0100203-01 MW-01-20201014 2,4-D 8151A 0.3728 pg/L 0100203-01 MW-01-20201014 1,4-Dichlorobenzene 8270D 4.94 J pg/L 0100203-01 MW-01-20201014 Diethyl phthalate 8270D 1.16 J pg/L 0100203-01 MW-01-20201014 Mercury 7470A 1.1 ug/L 0100203-01 MW-01-20201014 Barium 6020B 100 ug/L 0100203-01 MW-01-20201014 Cadmium 6020B 0.17 J ug/L 0100203-01 MW-01-20201014 Chromium 6020B 0.99 J ug/L 0100203-01 MW-01-20201014 Cobalt 6020B 160 ug/L 0100203-01 MW-01-20201014 Nickel 6020B 16 ug/L 0100203-01 MW-01-20201014 Selenium 6020B 1.0 J ug/L 0100203-01 MW-01-20201014 Zinc 6020B 11 J ug/L 0100203-01 MW-01-20201014 TOC 531OC-2011 1.78 mg/L 0100203-01 MW-01-20201014 1,1-Dichloroethane 8260D 2.8 ug/L 0100203-01 MW-01-20201014 1,2-Dichlorobenzene 8260D 0.22 J ug/L 0100203-01 MW-01-20201014 1,4-Dichlorobenzene 8260D 9.8 ug/L 0100203-01 MW-01-20201014 Acetone 8260D 5.7 ug/L 0100203-01 MW-01-20201014 Benzene 8260D 1.5 ug/L 0100203-01 MW-01-20201014 Chlorobenzene 8260D 1.9 ug/L 0100203-01 MW-01-20201014 cis-1,2-Dichloroethylene 8260D 4.5 ug/L 0100203-01 MW-01-20201014 Ethylbenzene 8260D 0.33 J ug/L 0100203-01 MW-01-20201014 m,p-Xylenes 8260D 0.83 J ug/L 0100203-01 MW-01-20201014 o-Xylene 8260D 0.26 J ug/L 0100203-01 MW-01-20201014 Tetrachloroethylene 8260D 0.48 .1 ug/L 0100203-01 MW-01-20201014 Trichloroethylene 8260D 0.57 ug/L 0100203-01 MW-01-20201014 Vinyl chloride 8260D 0.31 J ug/L 0100203-01 MW-01-20201014 Xylenes, total 8260D 1.1 J ug/L 0100203-02 LT-01-20201014 Mercury 7470A 0.23 ug/L 0100203-02 LT-01-20201014 Arsenic 6020B 2.9 ug/L 0100203-02 LT-01-20201014 Barium 6020B 500 ug/L 0100203-02 LT-01-20201014 Chromium 6020B 2.5 ug/L 0100203-02 LT-01-20201014 Cobalt 6020B 3.8 ug/L 0100203-02 LT-01-20201014 Nickel 6020B 20 ug/L 0100203-02 LT-01-20201014 Selenium 6020B 0.79 J ug/L 0100203-02 LT-01-20201014 Vanadium 6020B 2.4 J ug/L 0100203-02 LT-01-20201014 1,3-Dichlorobenzene 8260D 0.27 J ug/L 0100203-02 LT-01-20201014 1,4-Dichlorobenzene 8260D 4.8 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 96 Waypoint. ANALYTICAL Summary of Detections 12/01/202C Work Order: 0100203 Prism ID Client ID Parameter Method Result Units 0100203-02 LT-01-20201014 Acetone 8260D 11 ug/L 0100203-02 LT-01-20201014 Acetonitrile 8260D 4.7 J ug/L 0100203-02 LT-01-20201014 Benzene 8260D 2.4 ug/L 0100203-02 LT-01-20201014 Chlorobenzene 8260D 4.4 ug/L 0100203-02 LT-01-20201014 Chloroethane 8260D 0.47 J ug/L 0100203-02 LT-01-20201014 cis-1,2-Dichloroethylene 8260D 0.29 J ug/L 0100203-02 LT-01-20201014 Ethylbenzene 8260D 1.8 ug/L 0100203-02 LT-01-20201014 m,p-Xylenes 8260D 1.7 ug/L 0100203-02 LT-01-20201014 Naphthalene 8260D 13 ug/L 0100203-02 LT-01-20201014 o-Xylene 8260D 2.0 ug/L 0100203-02 LT-01-20201014 Tetrahydrofuran 8260D 94 ug/L 0100203-02 LT-01-20201014 Toluene 8260D 0.79 ug/L 0100203-02 LT-01-20201014 Vinyl chloride 8260D 0.22 J ug/L 0100203-02 LT-01-20201014 Xylenes, total 8260D 3.7 ug/L 0100203-02 LT-01-20201014 1,4-Dioxane 8260D SIM 58 ug/L 0100203-03 SW-01-20201014 Barium 6020B 12 ug/L 0100203-03 SW-01-20201014 Hardness SM2340 C 5000 ug/L 0100203-03 SW-01-20201014 Mercury 7470A 1.1 ug/L 0100203-03 SW-01-20201014 Barium 6020B 16 ug/L 0100203-03 SW-01-20201014 Chromium 6020B 0.86 J ug/L 0100203-03 SW-01-20201014 Lead 6020B 0.30 J ug/L 0100203-03 SW-01-20201014 Nickel 6020B 1.5 J ug/L 0100203-03 SW-01-20201014 Naphthalene 8260D 0.87 J ug/L 0100203-04 SW-02-20201014 Antimony 6020B 0.54 J ug/L 0100203-04 SW-02-20201014 Barium 6020B 10 ug/L 0100203-04 SW-02-20201014 Hardness SM2340 C 5500 ug/L 0100203-04 SW-02-20201014 Mercury 7470A 0.95 ug/L 0100203-04 SW-02-20201014 Barium 6020B 16 ug/L 0100203-04 SW-02-20201014 Chromium 6020B 0.94 J ug/L 0100203-04 SW-02-20201014 Lead 6020B 0.38 J ug/L 0100203-04 SW-02-20201014 Nickel 6020B 1.5 J ug/L 0100203-04 SW-02-20201014 Selenium 6020B 0.85 J ug/L 0100203-06 TB-202010140000 Acetone 8260D 3.0 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 96 Laboratory Report IL A i • . 0 12/01/2020 ANALYTICAL Anchor QEAof North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 1200 ug/L NE 1000 350 1 9056A 10/15/20 11:50BMS POJ0299 Nitrate as N <45 ug/L 10000 200 45 1 9056A 10/15/20 11:50BMS POJ0299 Sulfate <560 ug/L 250000 2000 560 1 9056A 10/15/20 11:50BMS POJ0299 General Chemistry Parameters Biochemical Oxygen Demand 3100 ug/L NE 2000 210 1 SM5210 B 10/15/20 15:55ENM POJ0340 Chemical Oxygen Demand 24000 J ug/L NE 50000 11000 1 SM5220 D 10/19/20 11:56SLS POJ0361 Cyanide <14 ug/L 10 25 14 5 9014 10/20/20 12:30BMS POJ0357 Ferrous Iron 39000 HT ug/L NE 5000 1200 25 SM3500-Fe B 10/15/20 9:51 ENM POJ0282 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 10/19/20 11:02ENM POJ0337 Total Alkalinity to pH 4.5 100000 ug/L NE 5000 770 1 SM2320 B 10/19/20 11:40 CLB POJ0341 Organochlorine Pesticides by GC/ECD 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081B 10/19/20 12:35NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081B 10/19/20 12:35NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081B 10/19/20 12:35NMB POJ0286 Aldrin <0.016 ug/L 0.05 0.051 0.016 1 8081B 10/19/20 12:35NMB POJ0286 alpha-BHC <0.0064 ug/L 0.05 0.051 0.0064 1 8081B 10/19/20 12:35NMB POJ0286 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081B 10/19/20 12:35NMB POJ0286 beta-BHC <0.011 ug/L 0.05 0.051 0.011 1 8081B 10/19/20 12:35NMB POJ0286 Chlordane <0.18 ug/L 0.5 0.51 0.18 1 8081B 10/19/20 12:35NMB POJ0286 delta-BHC <0.0084 ug/L 0.05 0.051 0.0084 1 8081B 10/19/20 12:35NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.051 0.014 1 8081B 10/19/20 12:35NMB POJ0286 Endosulfan 1 <0.016 ug/L 0.1 0.051 0.016 1 8081B 10/19/20 12:35NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.051 0.012 1 8081B 10/19/20 12:35NMB POJ0286 Endosulfan Sulfate <0.017 ug/L 0.1 0.051 0.017 1 8081B 10/19/20 12:35NMB POJ0286 Endrin <0.014 ug/L 0.1 0.051 0.014 1 8081B 10/19/20 12:35NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.051 0.016 1 8081B 10/19/20 12:35NMB POJ0286 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081B 10/19/20 12:35NMB POJ0286 gamma-BHC 0.051 ug/L 0.05 0.051 0.0062 1 8081B 10/19/20 12:35NMB POJ0286 trans -Chlordane <0.024 ug/L NE 0.10 0.024 1 8081B 10/19/20 12:35NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.051 0.013 1 8081B 10/19/20 12:35NMB POJ0286 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081B 10/19/20 12:35NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081B 10/19/20 12:35NMB POJ0286 Toxaphene <0.36 ug/L 1.5 1.0 0.36 1 8081B 10/19/20 12:35NMB POJ0286 Surrogate Recovery Control Limits Decachlorobiphenyl 44 % 13-186 Tetrachloro-m-xylene 77 % 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.21 ug/L NE 0.51 0.21 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 12:35NMB POJ0286 Aroclor 1260 <0.51 ug/L NE 1.0 0.51 1 8082A 10/19/20 12:35NMB POJ0286 Total Metals Surrogate Tetrachloro-m-xylene Decachlorobiphenyl Recovery Control Limits 77 % 30-161 46 % 32-178 Mercury 1.1 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:37EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/24/20 7:49 JAB POJ0312 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/24/20 7:49 JAB POJ0312 Barium 100 ug/L 100 2.0 0.81 1 6020B 10/24/20 7:49 JAB POJ0312 Beryllium <0.19 ug/L 1 1.0 0.19 1 6020B 10/27/20 15:09JAB POJ0312 Cadmium 0.17 J ug/L 1 1.0 0.16 1 6020B 10/24/20 7:49 JAB POJ0312 Chromium 0.99 J ug/L 10 2.0 0.79 1 6020B 10/27/20 22:04JAB POJ0491 Cobalt 160 ug/L 10 2.0 0.52 1 6020B 10/24/20 7:49 JAB POJ0312 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/24/20 7:49 JAB POJ0312 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/24/20 7:49 JAB POJ0312 Nickel 16 ug/L 50 3.0 0.51 1 6020B 10/24/20 7:49 JAB POJ0312 Selenium 1.0 J ug/L 10 5.0 0.74 1 6020B 10/24/20 7:49 JAB POJ0312 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 22:04JAB POJ0491 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/24/20 7:49 JAB POJ0312 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/27/20 22:04JAB POJ0491 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/24/20 7:49 JAB POJ0312 Zinc 11 J ug/L 10 20 6.9 1 6020B 10/24/20 7:49 JAB POJ0312 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 20:51JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 20:51JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 20:51JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 20:51JLB POJ0321 1,1-Dichloroethane 2.8 ug/L 5 0.50 0.083 1 8260D 10/21/20 20:51JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 20:51JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 20:51JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 20:51JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 20:51JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 20:51JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 20:51JLB POJ0321 1,2-Dichlorobenzene 0.22 J ug/L 5 0.50 0.076 1 8260D 10/21/20 20:51JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 20:51JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 20:51JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 20:51JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 20:51JLB POJ0321 1,4-Dichlorobenzene 9.8 ug/L 1 0.50 0.050 1 8260D 10/21/20 20:51JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 20:51JLB POJ0321 Acetone 5.7 ug/L 100 5.0 0.31 1 8260D 10/21/20 20:51JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 20:51JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 20:51JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 20:51JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 20:51JLB POJ0321 Benzene 1.5 ug/L 1 0.50 0.048 1 8260D 10/21/20 20:51JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 20:51JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 20:51JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 20:51JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 20:51JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 20:51JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 20:51JLB POJ0321 Chlorobenzene 1.9 ug/L 3 0.50 0.062 1 8260D 10/21/20 20:51JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 20:51JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 20:51JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 20:51JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 20:51JLB POJ0321 cis-1,2-Dichloroethylene 4.5 ug/L 2 0.50 0.056 1 8260D 10/21/20 20:51JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 20:51JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 20:51JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 20:51JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 20:51JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 20:51JLB POJ0321 Ethylbenzene 0.33 J ug/L 1 0.50 0.061 1 8260D 10/21/20 20:51JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 20:51JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 20:51JLB POJ0321 m,p-Xylenes 0.83 J ug/L NE 1.0 0.12 1 8260D 10/21/20 20:51JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 96 . Laboratory Report • � Waynt.. 12/01/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 20:51JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 20:51JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 20:51JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 20:51JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 20:51JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 20:51JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 20:51JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 20:51JLB POJ0321 o-Xylene 0.26 J ug/L NE 0.50 0.044 1 8260D 10/21/20 20:51JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 20:51JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 20:51JLB POJ0321 Tetrachloroethylene 0.48 J ug/L 1 0.50 0.098 1 8260D 10/21/20 20:51JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 20:51JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 20:51JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 20:51JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 20:51JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 20:51JLB POJ0321 Trichloroethylene 0.57 ug/L 1 0.50 0.078 1 8260D 10/21/20 20:51JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 20:51JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 20:51JLB POJ0321 Vinyl chloride 0.31 J ug/L 1 0.50 0.097 1 8260D 10/21/20 20:51JLB POJ0321 Xylenes, total 1.1 J ug/L 5 1.5 0.15 1 8260D 10/21/20 20:51JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 22:54ANG POJ0316 8270 Extended List 1,3,5-Trinitrobenzene <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 1,4-Naphthoquinone <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 1-Naphthylamine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 2-Acetylaminofluorene <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 2-Naphthylamine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 3-Methylcholanthrene <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 4-Aminobiphenyl <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 5-Nitro-o-toluidine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 7,12-Dimethyl benz(a)anthrace ne <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Diallate <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Hexachloropropene <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Isosafrole <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Kepone <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Methapyrilene <10.6 Ng/L 21.1 10.6 1 8270D 10/20/20 19:35BGV L517325 WIN itrosomethylethyl amine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 N-Nitrosopiperidine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 N-Nitrosopyrrolidine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 o-Toluidine <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 p-Dimethylaminoazobenzene <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 p-Phenylenediamine <10.5 L Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Pronamide <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Safrole <10.5 Ng/L 10.5 10.5 1 8270D 10/20/20 19:35BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/22/20 17:19VIC L517923 2,4,5-TP (Silvex) <0.01634 Ng/L 0.1 0.01634 1 8151A 10/22/20 17:19VIC L517923 2,4-D 0.3728 Ng/L 0.25 0.2078 1 8151A 10/22/20 17:19VIC L517923 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/22/20 17:19VIC L517923 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/22/20 17:19VIC L517923 Dicamba <0.057 Ng/L 0.25 0.057 1 8151A 10/22/20 17:19VIC L517923 Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/22/20 17:19VIC L517923 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/22/20 17:19VIC L517923 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/22/20 17:19VIC L517923 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/22/20 17:19VIC L517923 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/22/20 17:19VIC L517923 Surrogate Recovery Control Limits DCAA 51.2 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene <0.333 Ng/L 5.26 0.333 1 8270D 10/20/20 19:35BGV L517328 1,2,4-Trichlorobenzene <0.507 Ng/L 5.26 0.507 1 8270D 10/20/20 19:35BGV L517328 1,2-Dichlorobenzene <0.661 Ng/L 5.26 0.661 1 8270D 10/20/20 19:35BGV L517328 1,3-Dichlorobenzene <0.516 Ng/L 5.26 0.516 1 8270D 10/20/20 19:35BGV L517328 1,4-Dichlorobenzene 4.94 j Ng/L 5.26 0.61 1 8270D 10/20/20 19:35BGV L517328 2,3,4,6-Tetrachlorophenol <0.373 Ng/L 5.26 0.373 1 8270D 10/20/20 19:35BGV L517328 2,4,5-Trichlorophenol <0.368 Ng/L 5.26 0.368 1 8270D 10/20/20 19:35BGV L517328 2,4,6-Trichlorophenol <0.361 Ng/L 5.26 0.361 1 8270D 10/20/20 19:35BGV L517328 2,4-Dichlorophenol <1.6 Ng/L 5.26 1.6 1 8270D 10/20/20 19:35BGV L517328 2,4-Dimethylphenol <0.709 Ng/L 5.26 0.709 1 8270D 10/20/20 19:35BGV L517328 2,4-Dinitrophenol <5.09 Ng/L 10.5 5.09 1 8270D 10/20/20 19:35BGV L517328 2,4-Dinitrotoluene <0.423 Ng/L 5.26 0.423 1 8270D 10/20/20 19:35BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 96 ® Laboratory Report IL AL i • . 12/01 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 2,6-Dichlorophenol <0.739 pg/L 5.26 0.739 1 8270D 10/20/20 19:35BGV L517328 2,6-Dinitrotoluene <0.434 pg/L 5.26 0.434 1 8270D 10/20/20 19:35BGV L517328 2-Chloronaphthalene <0.5 pg/L 5.26 0.5 1 8270D 10/20/20 19:35BGV L517328 2-Chlorophenol <0.774 pg/L 5.26 0.774 1 8270D 10/20/20 19:35BGV L517328 2-Methyl naphthalene <0.511 pg/L 2.11 0.511 1 8270D 10/20/20 19:35BGV L517328 2-Methylphenol <0.758 pg/L 5.26 0.758 1 8270D 10/20/20 19:35BGV L517328 2-Nitroaniline <0.603 pg/L 5.26 0.603 1 8270D 10/20/20 19:35BGV L517328 2-Nitrophenol <0.637 pg/L 5.26 0.637 1 8270D 10/20/20 19:35BGV L517328 3&4 Methylphenol <0.726 pg/L 5.26 0.726 1 8270D 10/20/20 19:35BGV L517328 3,3' Dimethylbenzidine <1.97 pg/L 10.5 1.97 1 8270D 10/20/20 19:35BGV L517328 3,3'-Dichlorobenzidine <3.93 pg/L 10.5 3.93 1 8270D 10/20/20 19:35BGV L517328 3-Nitroaniline <1.61 pg/L 10.5 1.61 1 8270D 10/20/20 19:35BGV L517328 4,6-Dinitro-2-methylphenol <3.64 pg/L 10.5 3.64 1 8270D 10/20/20 19:35BGV L517328 4-Bromophenyl phenyl ether <0.526 pg/L 5.26 0.526 1 8270D 10/20/20 19:35BGV L517328 4-Chloro-3-methylphenol <0.529 pg/L 5.26 0.529 1 8270D 10/20/20 19:35BGV L517328 4-Chloroaniline <0.553 pg/L 5.26 0.553 1 8270D 10/20/20 19:35BGV L517328 4-Chlorophenyl phenyl ether <0.503 pg/L 5.26 0.503 1 8270D 10/20/20 19:35BGV L517328 4-Nitroaniline <0.778 pg/L 5.26 0.778 1 8270D 10/20/20 19:35BGV L517328 4-Nitrophenol <1.46 pg/L 10.5 1.46 1 8270D 10/20/20 19:35BGV L517328 Acenaphthene <0.445 pg/L 2.11 0.445 1 8270D 10/20/20 19:35BGV L517328 Acenaphthylene <0.452 pg/L 2.11 0.452 1 8270D 10/20/20 19:35BGV L517328 Acetophenone <0.721 pg/L 5.26 0.721 1 8270D 10/20/20 19:35BGV L517328 Aniline <0.332 pg/L 5.26 0.332 1 8270D 10/20/20 19:35BGV L517328 Anthracene <0.492 pg/L 2.11 0.492 1 8270D 10/20/20 19:35BGV L517328 Benzidine <0.726 pg/L 21.1 0.726 1 8270D 10/20/20 19:35BGV L517328 Benzo(a)anthracene <0.45 pg/L 2.11 0.45 1 8270D 10/20/20 19:35BGV L517328 Benzo(a)pyrene <1.06 pg/L 2.11 1.06 1 8270D 10/20/20 19:35BGV L517328 Benzo(b)fluoranthene <0.992 pg/L 2.11 0.992 1 8270D 10/20/20 19:35BGV L517328 Benzo(q,hJ)perylene <1.43 pg/L 2.11 1.43 1 8270D 10/20/20 19:35BGV L517328 Benzo(k)fluoranthene <0.793 pg/L 2.11 0.793 1 8270D 10/20/20 19:35BGV L517328 Benzoic Acid <5.25 pg/L 10.5 5.25 1 8270D 10/20/20 19:35BGV L517328 Benzyl alcohol <3.16 pg/L 10.5 3.16 1 8270D 10/20/20 19:35BGV L517328 Bis(2-Chloroethoxy)methane <0.455 pg/L 5.26 0.455 1 8270D 10/20/20 19:35BGV L517328 Bis(2-Chloroethyl)ether <0.47 pg/L 5.26 0.47 1 8270D 10/20/20 19:35BGV L517328 Bis(2-Chloroisopropyl)ether <0.574 pg/L 5.26 0.574 1 8270D 10/20/20 19:35BGV L517328 Bis(2-ethylhexyl)phthalate <3.85 pg/L 5.26 3.85 1 8270D 10/20/20 19:35BGV L517328 Butyl benzyl phthalate <4.83 pg/L 5.26 4.83 1 8270D 10/20/20 19:35BGV L517328 Carbazole <0.5 pg/L 5.26 0.5 1 8270D 10/20/20 19:35BGV L517328 Chrysene <0.771 pg/L 2.11 0.771 1 8270D 10/20/20 19:35BGV L517328 Dibenz(a,h)anthracene <0.265 pg/L 2.11 0.265 1 8270D 10/20/20 19:35BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 96 . Laboratory Report • � Waynt.� 12/01/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: MW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-01 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Dibenzofuran <0.444 Ng/L 5.26 0.444 1 8270D 10/20/20 19:35BGV L517328 Diethyl phthalate 1.16 j Ng/L 5.26 0.615 1 8270D 10/20/20 19:35BGV L517328 Dimethyl phthalate <0.536 pg/L 5.26 0.536 1 8270D 10/20/20 19:35BGV L517328 Di-n-butyl phthalate <1.66 Ng/L 5.26 1.66 1 8270D 10/20/20 19:35BGV L517328 Di-n-Octyl Phthalate <1.81 Ng/L 5.26 1.81 1 8270D 10/20/20 19:35BGV L517328 Fluoranthene <0.428 Ng/L 2.11 0.428 1 8270D 10/20/20 19:35BGV L517328 Fluorene <0.468 Ng/L 2.11 0.468 1 8270D 10/20/20 19:35BGV L517328 Hexachlorobenzene <2.7 Ng/L 5.26 2.7 1 8270D 10/20/20 19:35BGV L517328 Hexachlorobutadiene <0.426 Ng/L 5.26 0.426 1 8270D 10/20/20 19:35BGV L517328 Hexachlorocyclopentadiene <2.46 Ng/L 5.26 2.46 1 8270D 10/20/20 19:35BGV L517328 Hexachloroethane <0.291 Ng/L 5.26 0.291 1 8270D 10/20/20 19:35BGV L517328 Indeno(1,2,3-cd)pyrene <1.07 Ng/L 2.11 1.07 1 8270D 10/20/20 19:35BGV L517328 Isophorone <0.378 Ng/L 5.26 0.378 1 8270D 10/20/20 19:35BGV L517328 Naphthalene <0.51 Ng/L 2.11 0.51 1 8270D 10/20/20 19:35BGV L517328 Nitrobenzene <0.558 Ng/L 5.26 0.558 1 8270D 10/20/20 19:35BGV L517328 N-Nitrosodiethylamine <0.42 Ng/L 5.26 0.42 1 8270D 10/20/20 19:35BGV L517328 N-Nitrosodimethylamine <0.261 Ng/L 5.26 0.261 1 8270D 10/20/20 19:35BGV L517328 N-Nitroso-di-n-butylamine <0.791 pg/L 5.26 0.791 1 8270D 10/20/20 19:35BGV L517328 N-Nitroso-di-n-propylamine <0.351 Ng/L 5.26 0.351 1 8270D 10/20/20 19:35BGV L517328 N-Nitrosodiphenylamine <0.822 Ng/L 10.5 0.822 1 8270D 10/20/20 19:35BGV L517328 Pentachlorophenol <2.57 Ng/L 10.5 2.57 1 8270D 10/20/20 19:35BGV L517328 Phenanthrene <0.489 Ng/L 2.11 0.489 1 8270D 10/20/20 19:35BGV L517328 Phenol <0.409 Ng/L 5.26 0.409 1 8270D 10/20/20 19:35BGV L517328 Pyrene <1.1 Ng/L 2.11 1.1 1 8270D 10/20/20 19:35BGV L517328 Pyridine <0.711 pg/L 10.5 0.711 1 8270D 10/20/20 19:35BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 21.7 % 39-110 SR 2-Fluorobiphenyl 45.3 % 24-93 2-Fluorophenol 10.1 % 10-44 4-Terphenyl-d14 20 % 35-126 SR Nitrobenzene-d5 49.7 % 20-91 Phenol-d6 9.3 % 7-32 Total Organic Carbon TOC 1.78 mg/L 1 0.498 1 531OC-2011 10/24/20 17:34DDB L518400 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: LT-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-02 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:25 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury 0.23 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:41 EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/24/20 7:55 JAB POJ0312 Arsenic 2.9 ug/L 10 1.0 0.17 1 6020B 10/24/20 7:55 JAB POJ0312 Barium 500 ug/L 100 2.0 0.81 1 6020B 10/24/20 7:55 JAB POJ0312 Beryllium <0.19 ug/L 1 1.0 0.19 1 6020B 10/27/20 15:15JAB POJ0312 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/24/20 7:55 JAB POJ0312 Chromium 2.5 ug/L 10 2.0 0.79 1 6020B 10/27/20 22:10JAB POJ0491 Cobalt 3.8 ug/L 10 2.0 0.52 1 6020B 10/24/20 7:55 JAB POJ0312 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/24/20 7:55 JAB POJ0312 Lead <0.26 ug/L 10 1.0 0.26 1 6020B 10/24/20 7:55 JAB POJ0312 Nickel 20 ug/L 50 3.0 0.51 1 6020B 10/24/20 7:55 JAB POJ0312 Selenium 0.79 J ug/L 10 5.0 0.74 1 6020B 10/24/20 7:55 JAB POJ0312 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 22:1OJAB POJ0491 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/24/20 7:55 JAB POJ0312 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/27/20 22:1OJAB POJ0491 Vanadium 2.4 J ug/L 25 5.0 1.3 1 6020B 10/24/20 7:55 JAB POJ0312 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/24/20 7:55 JAB POJ0312 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 21:24JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 21:24JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 21:24JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 21:24JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 21:24JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 21:24JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 21:24JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 21:24JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 21:24JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 21:24JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 21:24JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 21:24JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 21:24JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 21:24JLB POJ0321 1,3-Dichlorobenzene 0.27 J ug/L 5 0.50 0.054 1 8260D 10/21/20 21:24JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 21:24JLB POJ0321 1,4-Dichlorobenzene 4.8 ug/L 1 0.50 0.050 1 8260D 10/21/20 21:24JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 21:24JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: LT-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-02 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:25 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acetone 11 ug/L 100 5.0 0.31 1 8260D 10/21/20 21:24JLB POJ0321 Acetonitrile 4.7 J ug/L 55 10 3.0 1 8260D 10/21/20 21:24JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 21:24JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 21:24JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 21:24JLB POJ0321 Benzene 2.4 ug/L 1 0.50 0.048 1 8260D 10/21/20 21:24JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 21:24JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 21:24JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 21:24JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 21:24JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 21:24JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 21:24JLB POJ0321 Chlorobenzene 4.4 ug/L 3 0.50 0.062 1 8260D 10/21/20 21:24JLB POJ0321 Chloroethane 0.47 J ug/L 10 0.50 0.22 1 8260D 10/21/20 21:24JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 21:24JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 21:24JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 21:24JLB POJ0321 cis-1,2-Dichloroethylene 0.29 J ug/L 2 0.50 0.056 1 8260D 10/21/20 21:24JLB POJ0321 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 21:24JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 21:24JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 21:24JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 21:24JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 21:24JLB POJ0321 Ethylbenzene 1.8 ug/L 1 0.50 0.061 1 8260D 10/21/20 21:24JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 21:24JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 21:24JLB POJ0321 m,p-Xylenes 1.7 ug/L NE 1.0 0.12 1 8260D 10/21/20 21:24JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 21:24JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 21:24JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 21:24JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 21:24JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 21:24JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 21:24JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 21:24JLB POJ0321 Naphthalene 13 ug/L 10 1.0 0.30 1 8260D 10/21/20 21:24JLB POJ0321 o-Xylene 2.0 ug/L NE 0.50 0.044 1 8260D 10/21/20 21:24JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 21:24JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 21:24JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 96 . Laboratory Report • � Waynt.� 12/01/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: LT-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-02 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 12:25 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 21:24JLB POJ0321 Tetrahydrofuran 94 ug/L NE 10 1.1 1 8260D 10/21/20 21:24JLB POJ0321 Toluene 0.79 ug/L 1 0.50 0.044 1 8260D 10/21/20 21:24JLB POJ0321 trans-1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 21:24JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 21:24JLB POJ0321 trans-1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 21:24JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 21:24JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 21:24JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 21:24JLB POJ0321 Vinyl chloride 0.22 J ug/L 1 0.50 0.097 1 8260D 10/21/20 21:24JLB POJ0321 Xylenes, total 3.7 ug/L 5 1.5 0.15 1 8260D 10/21/20 21:24JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 106 % 75-129 Toluene-d8 100 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 58 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 23:19ANG POJ0316 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Dissolved Metals Mercury <0.034 ug/L 0.20 0.034 1 7470A 10/21/20 15:59EDV POJ0394 Antimony <0.49 ug/L 2.0 0.49 1 6020B 10/28/20 12:25JAB POJ0496 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 10/28/20 12:25JAB POJ0496 Barium 12 ug/L 100 10 0.81 1 6020B 10/28/20 12:25JAB POJ0496 Beryllium <0.19 ug/L 1.0 0.19 1 6020B 10/28/20 12:25JAB POJ0496 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 10/28/20 12:25JAB POJ0496 Chromium <0.79 ug/L 2.0 0.79 1 6020B 10/28/20 12:25JAB POJ0496 Cobalt <0.52 ug/L 2.0 0.52 1 6020B 10/28/20 12:25JAB POJ0496 Copper <3.8 ug/L 10 3.8 1 6020B 10/28/20 12:25JAB POJ0496 Lead <0.26 ug/L 1.0 0.26 1 6020B 10/28/20 12:25JAB POJ0496 Nickel <0.51 ug/L 50 3.0 0.51 1 6020B 10/28/20 12:25JAB POJ0496 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/28/20 12:25JAB POJ0496 Silver <0.11 ug/L 1.0 0.11 1 6020B 10/28/20 12:25JAB POJ0496 Thallium <0.57 ug/L 2.0 0.57 1 6020B 10/28/20 12:25JAB POJ0496 Tin <1.8 ug/L 5.0 1.8 1 6020B 10/28/20 12:25JAB POJ0496 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/28/20 12:25JAB POJ0496 Zinc <6.9 ug/L 20 6.9 1 6020B 10/28/20 12:25JAB POJ0496 General Chemistry Parameters Hardness 5000 ug/L 5000 570 1 SM2340 C 10/15/20 15:43BMS POJ0269 Organochlorine Pesticides by GC/ECD 4,4'-DDD <0.026 ug/L 0.1 0.10 0.026 1 8081 B 10/19/20 12:48NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/19/20 12:48NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/19/20 12:48NMB POJ0286 Aldrin <0.015 ug/L 0.05 0.050 0.015 1 8081 B 10/19/20 12:48NMB POJ0286 alpha-BHC <0.0063 ug/L 0.05 0.050 0.0063 1 8081 B 10/19/20 12:48NMB POJ0286 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 12:48NMB POJ0286 beta-BHC <0.011 ug/L 0.05 0.050 0.011 1 8081 B 10/19/20 12:48NMB POJ0286 Chlordane <0.18 ug/L 0.5 0.50 0.18 1 8081 B 10/19/20 12:48NMB POJ0286 delta-BHC <0.0082 ug/L 0.05 0.050 0.0082 1 8081 B 10/19/20 12:48NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.050 0.014 1 8081 B 10/19/20 12:48NMB POJ0286 Endosulfan 1 <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/19/20 12:48NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.050 0.012 1 8081 B 10/19/20 12:48NMB POJ0286 Endosulfan Sulfate <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/19/20 12:48NMB POJ0286 Endrin <0.014 ug/L 0.1 0.050 0.014 1 8081 B 10/19/20 12:48NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.050 0.016 1 8081 B 10/19/20 12:48NMB POJ0286 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081B 10/19/20 12:48NMB POJ0286 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID gamma-BHC <0.0061 ug/L 0.05 0.050 0.0061 1 8081 B 10/19/20 12:48NMB POJ0286 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081B 10/19/20 12:48NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.050 0.013 1 8081B 10/19/20 12:48NMB POJ0286 Heptachlor Epoxide <0.022 ug/L 0.075 0.10 0.022 1 8081B 10/19/20 12:48NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081B 10/19/20 12:48NMB POJ0286 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081B 10/19/20 12:48NMB POJ0286 Surrogate Recovery Control Limits Decachlorobiphenyl 62 % 13-186 Tetrachloro-m-xylene 56 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.21 ug/L NE 0.50 0.21 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.50 0.16 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.50 0.14 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.50 0.14 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.50 0.16 1 8082A 10/19/20 12:48NMB POJ0286 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/19/20 12:48NMB POJ0286 Surrogate Recovery Control Limits Tetrachloro-m-xylene 56 % 30-161 Decachlorobiphenyl 64 % 32-178 Total Metals Mercury 1.1 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:45EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/24/20 8:02 JAB POJ0312 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/24/20 8:02 JAB POJ0312 Barium 16 ug/L 100 2.0 0.81 1 6020B 10/24/20 8:02 JAB POJ0312 Beryllium <0.19 ug/L 1 1.0 0.19 1 6020B 10/27/20 15:22JAB POJ0312 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/24/20 8:02 JAB POJ0312 Chromium 0.86 J ug/L 10 2.0 0.79 1 6020B 10/27/20 22:17JAB POJ0491 Cobalt <0.52 ug/L 10 2.0 0.52 1 6020B 10/24/20 8:02 JAB POJ0312 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/24/20 8:02 JAB POJ0312 Lead 0.30 J ug/L 10 1.0 0.26 1 6020B 10/24/20 8:02 JAB POJ0312 Nickel 1.5 J ug/L 50 3.0 0.51 1 6020B 10/24/20 8:02 JAB POJ0312 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/24/20 8:02 JAB POJ0312 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 22:17JAB POJ0491 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/24/20 8:02 JAB POJ0312 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/27/20 22:17JAB POJ0491 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/24/20 8:02 JAB POJ0312 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/24/20 8:02 JAB POJ0312 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 21:58JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 21:58JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 21:58JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 21:58JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 21:58JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 21:58JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 21:58JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 21:58JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 21:58JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 21:58JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 21:58JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 21:58JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 21:58JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 21:58JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 21:58JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 21:58JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 21:58JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 21:58JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 21:58JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 21:58JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 21:58JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 21:58JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 21:58JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 21:58JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 21:58JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 21:58JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 21:58JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 21:58JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 21:58JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 21:58JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 21:58JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 21:58JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 21:58JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 21:58JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 21:58JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 21:58JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 96 . Laboratory Report • � Waynt.. 12/01/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 21:58JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 21:58JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 21:58JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 21:58JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 21:58JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 21:58JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 21:58JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 21:58JLB POJ0321 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/21/20 21:58JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 21:58JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 21:58JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 21:58JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 21:58JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 21:58JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 21:58JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 21:58JLB POJ0321 Naphthalene 0.87 J ug/L 10 1.0 0.30 1 8260D 10/21/20 21:58JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 21:58JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 21:58JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 21:58JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 21:58JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 21:58JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 21:58JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 21:58JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 21:58JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 21:58JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 21:58JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 21:58JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 21:58JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 21:58JLB POJ0321 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/21/20 21:58JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 110 % 75-129 Toluene-d8 100 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/16/20 23:44ANG POJ0316 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 8270 Extended List 1,3,5-Tri n itrobenzene <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 1,4-Naphthoquinone <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 1-Naphthylamine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 2-Acetylaminofluorene <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 2-Naphthylamine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 3-Methylcholanthrene <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 4-Aminobiphenyl <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 5-Nitro-o-toluidine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 7,12-D1methyl benz(a)anthrace ne <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Diallate <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Hexachloropropene <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Isosafrole <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Kepone <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Methapyrilene <13.4 Ng/L 26.7 13.4 1 8270D 10/20/20 19:57BGV L517325 N-Nitrosomethylethyl amine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 N-Nitrosopiperidine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 N-Nitrosopyrrolidine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 o-Toluidine <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 p-Dimethylaminoazobenzene <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 p-Phenylenediamine <13.3 L Ng/L 13.3 13.3 1 8270D 10/20/20 19:57 BGV L517325 Pronamide <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Safrole <13.3 Ng/L 13.3 13.3 1 8270D 10/20/20 19:57BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/22/20 17:45VIC L517923 2,4,5-TP (Silvex) <0.01634 Ng/L 0.1 0.01634 1 8151A 10/22/20 17:45VIC L517923 2,4-D <0.2078 Ng/L 0.25 0.2078 1 8151A 10/22/20 17:45VIC L517923 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/22/20 17:45VIC L517923 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/22/20 17:45VIC L517923 Dicamba <0.057 Ng/L 0.25 0.057 1 8151A 10/22/20 17:45VIC L517923 Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/22/20 17:45VIC L517923 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/22/20 17:45VIC L517923 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/22/20 17:45VIC L517923 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/22/20 17:45VIC L517923 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/22/20 17:45VIC L517923 Surrogate Recovery Control Limits DCAA 48.1 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene <0.422 Ng/L 6.67 0.422 1 8270D 10/20/20 19:57BGV L517328 1,2,4-Trichlorobenzene <0.642 Ng/L 6.67 0.642 1 8270D 10/20/20 19:57BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 96 ® Laboratory Report IL AL i • . 12/01 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,2-Dichlorobenzene <0.839 pg/L 6.67 0.839 1 8270D 10/20/20 19:57BGV L517328 1,3-Dichlorobenzene <0.654 pg/L 6.67 0.654 1 8270D 10/20/20 19:57BGV L517328 1,4-Dichlorobenzene <0.773 pg/L 6.67 0.773 1 8270D 10/20/20 19:57BGV L517328 2,3,4,6-Tetrachlorophenol <0.473 pg/L 6.67 0.473 1 8270D 10/20/20 19:57BGV L517328 2,4,5-Trichlorophenol <0.466 pg/L 6.67 0.466 1 8270D 10/20/20 19:57BGV L517328 2,4,6-Trichlorophenol <0.458 pg/L 6.67 0.458 1 8270D 10/20/20 19:57BGV L517328 2,4-Dichlorophenol <2.03 pg/L 6.67 2.03 1 8270D 10/20/20 19:57BGV L517328 2,4-Dimethylphenol <0.899 pg/L 6.67 0.899 1 8270D 10/20/20 19:57BGV L517328 2,4-Dinitrophenol <6.45 pg/L 13.3 6.45 1 8270D 10/20/20 19:57BGV L517328 2,4-Dinitrotoluene <0.537 pg/L 6.67 0.537 1 8270D 10/20/20 19:57BGV L517328 2,6-Dichlorophenol <0.937 pg/L 6.67 0.937 1 8270D 10/20/20 19:57BGV L517328 2,6-Dinitrotoluene <0.55 pg/L 6.67 0.55 1 8270D 10/20/20 19:57BGV L517328 2-Chloronaphthalene <0.634 pg/L 6.67 0.634 1 8270D 10/20/20 19:57BGV L517328 2-Chlorophenol <0.981 pg/L 6.67 0.981 1 8270D 10/20/20 19:57BGV L517328 2-Methyl naphthalene <0.647 pg/L 2.67 0.647 1 8270D 10/20/20 19:57BGV L517328 2-Methylphenol <0.961 pg/L 6.67 0.961 1 8270D 10/20/20 19:57BGV L517328 2-Nitroaniline <0.765 pg/L 6.67 0.765 1 8270D 10/20/20 19:57BGV L517328 2-Nitrophenol <0.808 pg/L 6.67 0.808 1 8270D 10/20/20 19:57BGV L517328 3&4 Methylphenol <0.921 pg/L 6.67 0.921 1 8270D 10/20/20 19:57BGV L517328 3,3' Dimethylbenzidine <2.5 pg/L 13.3 2.5 1 8270D 10/20/20 19:57BGV L517328 3,3'-Dichlorobenzidine <4.97 pg/L 13.3 4.97 1 8270D 10/20/20 19:57BGV L517328 3-Nitroaniline <2.03 pg/L 13.3 2.03 1 8270D 10/20/20 19:57BGV L517328 4,6-Dinitro-2-methylphenol <4.62 pg/L 13.3 4.62 1 8270D 10/20/20 19:57BGV L517328 4-Bromophenyl phenyl ether <0.667 pg/L 6.67 0.667 1 8270D 10/20/20 19:57BGV L517328 4-Chloro-3-methylphenol <0.671 pg/L 6.67 0.671 1 8270D 10/20/20 19:57BGV L517328 4-Chloroaniline <0.701 pg/L 6.67 0.701 1 8270D 10/20/20 19:57BGV L517328 4-Chlorophenyl phenyl ether <0.638 pg/L 6.67 0.638 1 8270D 10/20/20 19:57BGV L517328 4-Nitroaniline <0.987 pg/L 6.67 0.987 1 8270D 10/20/20 19:57BGV L517328 4-Nitrophenol <1.85 pg/L 13.3 1.85 1 8270D 10/20/20 19:57BGV L517328 Acenaphthene <0.563 pg/L 2.67 0.563 1 8270D 10/20/20 19:57BGV L517328 Acenaphthylene <0.572 pg/L 2.67 0.572 1 8270D 10/20/20 19:57BGV L517328 Acetophenone <0.915 pg/L 6.67 0.915 1 8270D 10/20/20 19:57BGV L517328 Aniline <0.421 pg/L 6.67 0.421 1 8270D 10/20/20 19:57BGV L517328 Anthracene <0.623 pg/L 2.67 0.623 1 8270D 10/20/20 19:57BGV L517328 Benzidine <0.919 pg/L 26.7 0.919 1 8270D 10/20/20 19:57BGV L517328 Benzo(a)anthracene <0.57 pg/L 2.67 0.57 1 8270D 10/20/20 19:57BGV L517328 Benzo(a)pyrene <1.34 pg/L 2.67 1.34 1 8270D 10/20/20 19:57BGV L517328 Benzo(b)fluoranthene <1.26 pg/L 2.67 1.26 1 8270D 10/20/20 19:57BGV L517328 Benzo(g,hJ)perylene <1.81 pg/L 2.67 1.81 1 8270D 10/20/20 19:57BGV L517328 Benzo(k)fluoranthene <1 pg/L 2.67 1 1 8270D 10/20/20 19:57BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 96 ® Laboratory Report IL AL i • . 12/01 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-01-20201014 Attn: Alec Macbeth Sample ID: 0100203-03 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Benzoic Acid <6.65 pg/L 13.3 6.65 1 8270D 10/20/20 19:57 BGV L517328 Benzyl alcohol <4 pg/L 13.3 4 1 8270D 10/20/20 19:57BGV L517328 Bis(2-Chloroethoxy)methane <0.577 pg/L 6.67 0.577 1 8270D 10/20/20 19:57BGV L517328 Bis(2-Chloroethyl)ether <0.596 pg/L 6.67 0.596 1 8270D 10/20/20 19:57BGV L517328 Bis(2-Chloroisopropyl)ether <0.728 pg/L 6.67 0.728 1 8270D 10/20/20 19:57BGV L517328 Bis(2-ethylhexyl)phthalate <4.88 pg/L 6.67 4.88 1 8270D 10/20/20 19:57BGV L517328 Butyl benzyl phthalate <6.13 pg/L 6.67 6.13 1 8270D 10/20/20 19:57BGV L517328 Carbazole <0.634 pg/L 6.67 0.634 1 8270D 10/20/20 19:57BGV L517328 Chrysene <0.975 pg/L 2.67 0.975 1 8270D 10/20/20 19:57BGV L517328 Dibenz(a,h)anthracene <0.336 pg/L 2.67 0.336 1 8270D 10/20/20 19:57BGV L517328 Dibenzofuran <0.564 pg/L 6.67 0.564 1 8270D 10/20/20 19:57BGV L517328 Diethyl phthalate <0.78 pg/L 6.67 0.78 1 8270D 10/20/20 19:57BGV L517328 Dimethyl phthalate <0.68 pg/L 6.67 0.68 1 8270D 10/20/20 19:57BGV L517328 Di-n-butyl phthalate <2.1 pg/L 6.67 2.1 1 8270D 10/20/20 19:57BGV L517328 Di-n-Octyl Phthalate <2.3 pg/L 6.67 2.3 1 8270D 10/20/20 19:57BGV L517328 Fluoranthene <0.542 pg/L 2.67 0.542 1 8270D 10/20/20 19:57BGV L517328 Fluorene <0.592 pg/L 2.67 0.592 1 8270D 10/20/20 19:57BGV L517328 Hexachlorobenzene <3.43 pg/L 6.67 3.43 1 8270D 10/20/20 19:57BGV L517328 Hexachlorobutadiene <0.54 pg/L 6.67 0.54 1 8270D 10/20/20 19:57BGV L517328 Hexachlorocyclopentadiene <3.12 pg/L 6.67 3.12 1 8270D 10/20/20 19:57BGV L517328 Hexachloroethane <0.369 pg/L 6.67 0.369 1 8270D 10/20/20 19:57BGV L517328 Indeno(1,2,3-cd)pyrene <1.35 pg/L 2.67 1.35 1 8270D 10/20/20 19:57BGV L517328 Isophorone <0.48 pg/L 6.67 0.48 1 8270D 10/20/20 19:57BGV L517328 Naphthalene <0.646 pg/L 2.67 0.646 1 8270D 10/20/20 19:57BGV L517328 Nitrobenzene <0.708 pg/L 6.67 0.708 1 8270D 10/20/20 19:57BGV L517328 N-Nitrosodiethylamine <0.533 pg/L 6.67 0.533 1 8270D 10/20/20 19:57BGV L517328 N-Nitrosodimethylamine <0.332 pg/L 6.67 0.332 1 8270D 10/20/20 19:57BGV L517328 N-Nitroso-di-n-butylamine <1 pg/L 6.67 1 1 8270D 10/20/20 19:57BGV L517328 N-Nitroso-di-n-propylamine <0.445 pg/L 6.67 0.445 1 8270D 10/20/20 19:57BGV L517328 N-Nitrosodiphenylamine <1.04 pg/L 13.3 1.04 1 8270D 10/20/20 19:57BGV L517328 Pentachlorophenol <3.26 pg/L 13.3 3.26 1 8270D 10/20/20 19:57BGV L517328 Phenanthrene <0.619 pg/L 2.67 0.619 1 8270D 10/20/20 19:57BGV L517328 Phenol <0.518 pg/L 6.67 0.518 1 8270D 10/20/20 19:57BGV L517328 Pyrene <1.39 pg/L 2.67 1.39 1 8270D 10/20/20 19:57BGV L517328 Pyridine <0.901 pg/L 13.3 0.901 1 8270D 10/20/20 19:57BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 27.5 % 39-110 SR 2-Fluorobiphenyl 41.6 % 24-93 2-Fluorophenol 11.8 % 10-44 4-Terphenyl-d14 41.8 % 35-126 Nitrobenzene-d5 44.6 % 20-91 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 96 0 Way poi nt. ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill 2020 Fall Project No.: 50-02 Sample Matrix: Water Laboratory Report 12/01/2020 Client Sample ID: SW-01-20201014 Sample ID: 0100203-03 Work Order: 0100203 Time Collected: 10/14/20 13:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Phenol-d6 10.3 % 7-32 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Dissolved Metals Mercury <0.034 ug/L 0.20 0.034 1 7470A 10/21/20 16:18EDV POJ0394 Antimony 0.54 J ug/L 2.0 0.49 1 6020B 10/28/20 12:45JAB POJ0496 Arsenic <0.17 ug/L 1.0 0.17 1 6020B 10/28/20 12:45JAB POJ0496 Barium 10 ug/L 100 10 0.81 1 6020B 10/28/20 12:45JAB POJ0496 Beryllium <0.19 ug/L 1.0 0.19 1 6020B 10/28/20 12:45JAB POJ0496 Cadmium <0.16 ug/L 1.0 0.16 1 6020B 10/28/20 12:45JAB POJ0496 Chromium <0.79 ug/L 2.0 0.79 1 6020B 10/28/20 12:45JAB POJ0496 Cobalt <0.52 ug/L 2.0 0.52 1 6020B 10/28/20 12:45JAB POJ0496 Copper <3.8 ug/L 10 3.8 1 6020B 10/28/20 12:45JAB POJ0496 Lead <0.26 ug/L 1.0 0.26 1 6020B 10/28/20 12:45JAB POJ0496 Nickel <0.51 ug/L 50 3.0 0.51 1 6020B 10/28/20 12:45JAB POJ0496 Selenium <0.74 ug/L 10 5.0 0.74 1 6020B 10/28/20 12:45JAB POJ0496 Silver <0.11 ug/L 1.0 0.11 1 6020B 10/28/20 12:45JAB POJ0496 Thallium <0.57 ug/L 2.0 0.57 1 6020B 10/28/20 12:45JAB POJ0496 Tin <1.8 ug/L 5.0 1.8 1 6020B 10/28/20 12:45JAB POJ0496 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/28/20 12:45JAB POJ0496 Zinc <6.9 ug/L 20 6.9 1 6020B 10/28/20 12:45JAB POJ0496 General Chemistry Parameters Hardness 5500 ug/L 5000 570 1 SM2340 C 10/15/20 15:43BMS POJ0269 Organochlorine Pesticides by GC/ECD 4,4'-DDD <0.027 ug/L 0.1 0.10 0.027 1 8081 B 10/19/20 13:01NMB POJ0286 4,4'-DDE <0.022 ug/L 0.1 0.10 0.022 1 8081 B 10/19/20 13:01NMB POJ0286 4,4'-DDT <0.018 ug/L 0.1 0.10 0.018 1 8081 B 10/19/20 13:01NMB POJ0286 Aldrin <0.015 ug/L 0.05 0.051 0.015 1 8081 B 10/19/20 13:01NMB POJ0286 alpha-BHC <0.0064 ug/L 0.05 0.051 0.0064 1 8081 B 10/19/20 13:01NMB POJ0286 cis -Chlordane <0.019 ug/L NE 0.10 0.019 1 8081 B 10/19/20 13:01NMB POJ0286 beta-BHC <0.011 ug/L 0.05 0.051 0.011 1 8081 B 10/19/20 13:01NMB POJ0286 Chlordane <0.18 ug/L 0.5 0.51 0.18 1 8081 B 10/19/20 13:01NMB POJ0286 delta-BHC <0.0083 ug/L 0.05 0.051 0.0083 1 8081 B 10/19/20 13:01NMB POJ0286 Dieldrin <0.014 ug/L 0.002 0.051 0.014 1 8081 B 10/19/20 13:01NMB POJ0286 Endosulfan 1 <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 13:01NMB POJ0286 Endosulfan 11 <0.012 ug/L 0.1 0.051 0.012 1 8081 B 10/19/20 13:01NMB POJ0286 Endosulfan Sulfate <0.017 ug/L 0.1 0.051 0.017 1 8081 B 10/19/20 13:01NMB POJ0286 Endrin <0.014 ug/L 0.1 0.051 0.014 1 8081 B 10/19/20 13:01NMB POJ0286 Endrin Aldehyde <0.016 ug/L 0.1 0.051 0.016 1 8081 B 10/19/20 13:01NMB POJ0286 Endrin Ketone <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 13:01NMB POJ0286 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 96 . Laboratory Report • Waynt.� � 12/01/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID gamma-BHC <0.0062 ug/L 0.05 0.051 0.0062 1 8081 B 10/19/20 13:01NMB POJ0286 trans -Chlordane <0.023 ug/L NE 0.10 0.023 1 8081 B 10/19/20 13:01NMB POJ0286 Heptachlor <0.013 ug/L 0.05 0.051 0.013 1 8081 B 10/19/20 13:01NMB POJ0286 Heptachlor Epoxide <0.023 ug/L 0.075 0.10 0.023 1 8081 B 10/19/20 13:01NMB POJ0286 Methoxychlor <0.018 ug/L NE 0.10 0.018 1 8081 B 10/19/20 13:01NMB POJ0286 Toxaphene <0.35 ug/L 1.5 1.0 0.35 1 8081 B 10/19/20 13:01NMB POJ0286 Surrogate Recovery Control Limits Decachlorobiphenyl 73 % 13-186 Tetrachloro-m-xylene 73 % 40-134 Polychlorinated Biphenyls (PCBs) by GC/ECD Aroclor 1016 <0.21 ug/L NE 0.51 0.21 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1221 <0.11 ug/L NE 1.0 0.11 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1232 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1242 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1248 <0.14 ug/L NE 0.51 0.14 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1254 <0.16 ug/L NE 0.51 0.16 1 8082A 10/19/20 13:01NMB POJ0286 Aroclor 1260 <0.50 ug/L NE 1.0 0.50 1 8082A 10/19/20 13:01NMB POJ0286 Surrogate Recovery Control Limits Tetrachloro-m-xylene 71 % 30-161 Decachlorobiphenyl 76 % 32-178 Total Metals Mercury 0.95 ug/L 0.2 0.20 0.034 1 7470A 10/20/20 15:49EDV POJ0374 Antimony <0.49 ug/L 6 2.0 0.49 1 6020B 10/24/20 8:09 JAB POJ0312 Arsenic <0.17 ug/L 10 1.0 0.17 1 6020B 10/24/20 8:09 JAB POJ0312 Barium 16 ug/L 100 2.0 0.81 1 6020B 10/24/20 8:09 JAB POJ0312 Beryllium <0.19 ug/L 1 1.0 0.19 1 6020B 10/27/20 15:29JAB POJ0312 Cadmium <0.16 ug/L 1 1.0 0.16 1 6020B 10/24/20 8:09 JAB POJ0312 Chromium 0.94 J ug/L 10 2.0 0.79 1 6020B 10/27/20 22:24JAB POJ0491 Cobalt <0.52 ug/L 10 2.0 0.52 1 6020B 10/24/20 8:09 JAB POJ0312 Copper <3.8 ug/L 10 10 3.8 1 6020B 10/24/20 8:09 JAB POJ0312 Lead 0.38 J ug/L 10 1.0 0.26 1 6020B 10/24/20 8:09 JAB POJ0312 Nickel 1.5 J ug/L 50 3.0 0.51 1 6020B 10/24/20 8:09 JAB POJ0312 Selenium 0.85 J ug/L 10 5.0 0.74 1 6020B 10/24/20 8:09 JAB POJ0312 Silver <0.11 ug/L 10 1.0 0.11 1 6020B 10/27/20 22:24JAB POJ0491 Thallium <0.38 ug/L 5.5 2.0 0.38 1 6020B 10/24/20 8:09 JAB POJ0312 Tin <1.8 ug/L 100 5.0 1.8 1 6020B 10/27/20 22:24JAB POJ0491 Vanadium <1.3 ug/L 25 5.0 1.3 1 6020B 10/24/20 8:09 JAB POJ0312 Zinc <6.9 ug/L 10 20 6.9 1 6020B 10/24/20 8:09 JAB POJ0312 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 22:32JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 22:32JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 22:32JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 22:32JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 22:32JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 22:32JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 22:32JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 22:32JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 22:32JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 22:32JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 22:32JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 22:32JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 22:32JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 22:32JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 22:32JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 22:32JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 22:32JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 22:32JLB POJ0321 Acetone <0.31 ug/L 100 5.0 0.31 1 8260D 10/21/20 22:32JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 22:32JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 22:32JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 22:32JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 22:32JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 22:32JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 22:32JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 22:32JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 22:32JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 22:32JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 22:32JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 22:32JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 22:32JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 22:32JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 22:32JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 22:32JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 22:32JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 22:32JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 22:32JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 22:32JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 22:32JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 22:32JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 22:32JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 22:32JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 22:32JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 22:32JLB POJ0321 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/21/20 22:32JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 22:32JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 22:32JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 22:32JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 22:32JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 22:32JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 22:32JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 22:32JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 22:32JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 22:32JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 22:32JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 22:32JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 22:32JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 22:32JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 22:32JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 22:32JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 22:32JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 22:32JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 22:32JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 22:32JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 22:32JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 22:32JLB POJ0321 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/21/20 22:32JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 111 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 10/17/20 0:09ANG POJ0316 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 8270 Extended List 1,3,5-Tri n itrobenzene <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 1,4-Naphthoquinone <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 1-Naphthylamine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 2-Acetylaminofluorene <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 2-Naphthylamine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 3-Methylcholanthrene <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 4-Aminobiphenyl <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 5-Nitro-o-toluidine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 7,12-D1methyl benz(a)anthrace ne <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Diallate <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Hexachloropropene <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Isosafrole <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Kepone <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19 BGV L517325 Methapyrilene <10.3 Ng/L 20.6 10.3 1 8270D 10/20/20 20:19BGV L517325 N-Nitrosomethylethyl amine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 N-Nitrosopiperidine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 N-Nitrosopyrrolidine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 o-Toluidine <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 p-Dimethylaminoazobenzene <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 p-Phenylenediamine <10.3 L Ng/L 10.3 10.3 1 8270D 10/20/20 20:19 BGV L517325 Pronamide <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Safrole <10.3 Ng/L 10.3 10.3 1 8270D 10/20/20 20:19BGV L517325 Phenoxy Acid Herbicides - GC/ECD 2,4,5-T <0.01002 Ng/L 0.03 0.01002 1 8151A 10/22/20 18:10VIC L517923 2,4,5-TP (Silvex) <0.01634 Ng/L 0.1 0.01634 1 8151A 10/22/20 18:10VIC L517923 2,4-D <0.2078 Ng/L 0.25 0.2078 1 8151A 10/22/20 18:10VIC L517923 2,4-DB <0.1364 Ng/L 0.1 0.1364 1 8151A 10/22/20 18:10VIC L517923 Dalapon <0.5149 Ng/L 0.55 0.5149 1 8151A 10/22/20 18:10VIC L517923 Dicamba <0.057 Ng/L 0.25 0.057 1 8151A 10/22/20 18:10VIC L517923 Dichlorprop <0.07959 Ng/L 0.1 0.07959 1 8151A 10/22/20 18:10VIC L517923 Dinoseb <0.02698 Ng/L 0.1 0.02698 1 8151A 10/22/20 18:10VIC L517923 MCPA <18.98 Ng/L 50 18.98 1 8151A 10/22/20 18:10VIC L517923 MCPP <11.75 Ng/L 50 11.75 1 8151A 10/22/20 18:10VIC L517923 Picloram <0.04528 Ng/L 0.1 0.04528 1 8151A 10/22/20 18:10VIC L517923 Surrogate Recovery Control Limits DCAA 55.7 % 20-150 Semivolatile Organic Compounds - GC/MS 1,2,4,5-Tetrachlorobenzene <0.326 Ng/L 5.15 0.326 1 8270D 10/20/20 20:19BGV L517328 1,2,4-Trichlorobenzene <0.496 Ng/L 5.15 0.496 1 8270D 10/20/20 20:19BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 96 ® Laboratory Report IL AL i • . 12/01 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 1,2-Dichlorobenzene <0.647 pg/L 5.15 0.647 1 8270D 10/20/20 20:19BGV L517328 1,3-Dichlorobenzene <0.505 pg/L 5.15 0.505 1 8270D 10/20/20 20:19BGV L517328 1,4-Dichlorobenzene <0.597 pg/L 5.15 0.597 1 8270D 10/20/20 20:19BGV L517328 2,3,4,6-Tetrachlorophenol <0.365 pg/L 5.15 0.365 1 8270D 10/20/20 20:19BGV L517328 2,4,5-Trichlorophenol <0.36 pg/L 5.15 0.36 1 8270D 10/20/20 20:19BGV L517328 2,4,6-Trichlorophenol <0.354 pg/L 5.15 0.354 1 8270D 10/20/20 20:19BGV L517328 2,4-Dichlorophenol <1.57 pg/L 5.15 1.57 1 8270D 10/20/20 20:19BGV L517328 2,4-Dimethylphenol <0.694 pg/L 5.15 0.694 1 8270D 10/20/20 20:19BGV L517328 2,4-Dinitrophenol <5 pg/L 10.3 5 1 8270D 10/20/20 20:19BGV L517328 2,4-Dinitrotoluene <0.415 pg/L 5.15 0.415 1 8270D 10/20/20 20:19BGV L517328 2,6-Dichlorophenol <0.724 pg/L 5.15 0.724 1 8270D 10/20/20 20:19BGV L517328 2,6-Dinitrotoluene <0.425 pg/L 5.15 0.425 1 8270D 10/20/20 20:19BGV L517328 2-Chloronaphthalene <0.49 pg/L 5.15 0.49 1 8270D 10/20/20 20:19BGV L517328 2-Chlorophenol <0.758 pg/L 5.15 0.758 1 8270D 10/20/20 20:19BGV L517328 2-Methyl naphthalene <0.499 pg/L 2.06 0.499 1 8270D 10/20/20 20:19BGV L517328 2-Methylphenol <0.742 pg/L 5.15 0.742 1 8270D 10/20/20 20:19BGV L517328 2-Nitroaniline <0.591 pg/L 5.15 0.591 1 8270D 10/20/20 20:19BGV L517328 2-Nitrophenol <0.624 pg/L 5.15 0.624 1 8270D 10/20/20 20:19BGV L517328 3&4 Methylphenol <0.711 pg/L 5.15 0.711 1 8270D 10/20/20 20:19BGV L517328 3,3' Dimethylbenzidine <1.94 pg/L 10.3 1.94 1 8270D 10/20/20 20:19BGV L517328 3,3'-Dichlorobenzidine <3.85 pg/L 10.3 3.85 1 8270D 10/20/20 20:19BGV L517328 3-Nitroaniline <1.58 pg/L 10.3 1.58 1 8270D 10/20/20 20:19BGV L517328 4,6-Dinitro-2-methylphenol <3.57 pg/L 10.3 3.57 1 8270D 10/20/20 20:19BGV L517328 4-Bromophenyl phenyl ether <0.515 pg/L 5.15 0.515 1 8270D 10/20/20 20:19BGV L517328 4-Chloro-3-methylphenol <0.518 pg/L 5.15 0.518 1 8270D 10/20/20 20:19BGV L517328 4-Chloroaniline <0.541 pg/L 5.15 0.541 1 8270D 10/20/20 20:19BGV L517328 4-Chlorophenyl phenyl ether <0.493 pg/L 5.15 0.493 1 8270D 10/20/20 20:19BGV L517328 4-Nitroaniline <0.762 pg/L 5.15 0.762 1 8270D 10/20/20 20:19BGV L517328 4-Nitrophenol <1.43 pg/L 10.3 1.43 1 8270D 10/20/20 20:19BGV L517328 Acenaphthene <0.434 pg/L 2.06 0.434 1 8270D 10/20/20 20:19BGV L517328 Acenaphthylene <0.441 pg/L 2.06 0.441 1 8270D 10/20/20 20:19BGV L517328 Acetophenone <0.706 pg/L 5.15 0.706 1 8270D 10/20/20 20:19BGV L517328 Aniline <0.325 pg/L 5.15 0.325 1 8270D 10/20/20 20:19BGV L517328 Anthracene <0.481 pg/L 2.06 0.481 1 8270D 10/20/20 20:19BGV L517328 Benzidine <0.709 pg/L 20.6 0.709 1 8270D 10/20/20 20:19BGV L517328 Benzo(a)anthracene <0.439 pg/L 2.06 0.439 1 8270D 10/20/20 20:19BGV L517328 Benzo(a)pyrene <1.03 pg/L 2.06 1.03 1 8270D 10/20/20 20:19BGV L517328 Benzo(b)fluoranthene <0.969 pg/L 2.06 0.969 1 8270D 10/20/20 20:19BGV L517328 Benzo(g,hJ)perylene <1.4 pg/L 2.06 1.4 1 8270D 10/20/20 20:19BGV L517328 Benzo(k)fluoranthene <0.774 pg/L 2.06 0.774 1 8270D 10/20/20 20:19BGV L517328 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 96 ® Laboratory Report IL AL i • . 12/01 /2020 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: SW-02-20201014 Attn: Alec Macbeth Sample ID: 0100203-04 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Benzoic Acid <5.15 pg/L 10.3 5.15 1 8270D 10/20/20 20:19 BGV L517328 Benzyl alcohol <3.1 pg/L 10.3 3.1 1 8270D 10/20/20 20:19BGV L517328 Bis(2-Chloroethoxy)methane <0.445 pg/L 5.15 0.445 1 8270D 10/20/20 20:19BGV L517328 Bis(2-Chloroethyl)ether <0.46 pg/L 5.15 0.46 1 8270D 10/20/20 20:19BGV L517328 Bis(2-Chloroisopropyl)ether <0.562 pg/L 5.15 0.562 1 8270D 10/20/20 20:19BGV L517328 Bis(2-ethylhexyl)phthalate <3.77 pg/L 5.15 3.77 1 8270D 10/20/20 20:19BGV L517328 Butyl benzyl phthalate <4.73 pg/L 5.15 4.73 1 8270D 10/20/20 20:19BGV L517328 Carbazole <0.49 pg/L 5.15 0.49 1 8270D 10/20/20 20:19BGV L517328 Chrysene <0.752 pg/L 2.06 0.752 1 8270D 10/20/20 20:19BGV L517328 Dibenz(a,h)anthracene <0.259 pg/L 2.06 0.259 1 8270D 10/20/20 20:19BGV L517328 Dibenzofuran <0.435 pg/L 5.15 0.435 1 8270D 10/20/20 20:19BGV L517328 Diethyl phthalate <0.602 pg/L 5.15 0.602 1 8270D 10/20/20 20:19BGV L517328 Dimethyl phthalate <0.525 pg/L 5.15 0.525 1 8270D 10/20/20 20:19BGV L517328 Di-n-butyl phthalate <1.62 pg/L 5.15 1.62 1 8270D 10/20/20 20:19BGV L517328 Di-n-Octyl Phthalate <1.77 pg/L 5.15 1.77 1 8270D 10/20/20 20:19BGV L517328 Fluoranthene <0.418 pg/L 2.06 0.418 1 8270D 10/20/20 20:19BGV L517328 Fluorene <0.457 pg/L 2.06 0.457 1 8270D 10/20/20 20:19BGV L517328 Hexachlorobenzene <2.65 pg/L 5.15 2.65 1 8270D 10/20/20 20:19BGV L517328 Hexachlorobutadiene <0.417 pg/L 5.15 0.417 1 8270D 10/20/20 20:19BGV L517328 Hexachlorocyclopentadiene <2.41 pg/L 5.15 2.41 1 8270D 10/20/20 20:19BGV L517328 Hexachloroethane <0.285 pg/L 5.15 0.285 1 8270D 10/20/20 20:19BGV L517328 Indeno(1,2,3-cd)pyrene <1.04 pg/L 2.06 1.04 1 8270D 10/20/20 20:19BGV L517328 Isophorone <0.37 pg/L 5.15 0.37 1 8270D 10/20/20 20:19BGV L517328 Naphthalene <0.498 pg/L 2.06 0.498 1 8270D 10/20/20 20:19BGV L517328 Nitrobenzene <0.546 pg/L 5.15 0.546 1 8270D 10/20/20 20:19BGV L517328 N-Nitrosodiethylamine <0.412 pg/L 5.15 0.412 1 8270D 10/20/20 20:19BGV L517328 N-Nitrosodimethylamine <0.256 pg/L 5.15 0.256 1 8270D 10/20/20 20:19BGV L517328 N-Nitroso-di-n-butylamine <0.774 pg/L 5.15 0.774 1 8270D 10/20/20 20:19BGV L517328 N-Nitroso-di-n-propylamine <0.344 pg/L 5.15 0.344 1 8270D 10/20/20 20:19BGV L517328 N-Nitrosodiphenylamine <0.806 pg/L 10.3 0.806 1 8270D 10/20/20 20:19BGV L517328 Pentachlorophenol <2.52 pg/L 10.3 2.52 1 8270D 10/20/20 20:19BGV L517328 Phenanthrene <0.477 pg/L 2.06 0.477 1 8270D 10/20/20 20:19BGV L517328 Phenol <0.4 pg/L 5.15 0.4 1 8270D 10/20/20 20:19BGV L517328 Pyrene <1.07 pg/L 2.06 1.07 1 8270D 10/20/20 20:19BGV L517328 Pyridine <0.698 pg/L 10.3 0.698 1 8270D 10/20/20 20:19BGV L517328 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 45.3 % 39-110 2-Fluorobiphenyl 40.6 % 24-93 2-Fluorophenol 15.6 % 10-44 4-Terphenyl-d14 35 % 35-126 Nitrobenzene-d5 44 % 20-91 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 96 0 Way poi nt. ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill 2020 Fall Project No.: 50-02 Sample Matrix: Water Laboratory Report 12/01/2020 Client Sample ID: SW-02-20201014 Sample ID: 0100203-04 Work Order: 0100203 Time Collected: 10/14/20 13:30 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Phenol-d6 11.9 % 7-32 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 96 Laboratory Report • � 12/01/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010140000 Attn: Alec Macbeth Sample ID: 0100203-06 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 00:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260D 10/21/20 16:53JLB POJ0321 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 16:53JLB POJ0321 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260D 10/21/20 16:53JLB POJ0321 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 16:53JLB POJ0321 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 16:53JLB POJ0321 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260D 10/21/20 16:53JLB POJ0321 1, 1 -Dichloropropylene <0.051 ug/L 5 0.50 0.051 1 8260D 10/21/20 16:53JLB POJ0321 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260D 10/21/20 16:53JLB POJ0321 1,2,4-Trichlorobenzene <0.13 ug/L 10 1.0 0.13 1 8260D 10/21/20 16:53JLB POJ0321 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260D 10/21/20 16:53JLB POJ0321 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260D 10/21/20 16:53JLB POJ0321 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 16:53JLB POJ0321 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260D 10/21/20 16:53JLB POJ0321 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 16:53JLB POJ0321 1,3-Dichlorobenzene <0.054 ug/L 5 0.50 0.054 1 8260D 10/21/20 16:53JLB POJ0321 1,3-Dichloropropane <0.043 ug/L 1 0.50 0.043 1 8260D 10/21/20 16:53JLB POJ0321 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260D 10/21/20 16:53JLB POJ0321 2,2-Dichloropropane <0.11 ug/L 15 2.0 0.11 1 8260D 10/21/20 16:53JLB POJ0321 Acetone 3.0 J ug/L 100 5.0 0.31 1 8260D 10/21/20 16:53JLB POJ0321 Acetonitrile <3.0 ug/L 55 10 3.0 1 8260D 10/21/20 16:53JLB POJ0321 Acrolein <0.20 ug/L 53 20 0.20 1 8260D 10/21/20 16:53JLB POJ0321 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260D 10/21/20 16:53JLB POJ0321 Allyl Chloride (3-Chloropropylene) <0.75 ug/L 10 10 0.75 1 8260D 10/21/20 16:53JLB POJ0321 Benzene <0.048 ug/L 1 0.50 0.048 1 8260D 10/21/20 16:53JLB POJ0321 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260D 10/21/20 16:53JLB POJ0321 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 16:53JLB POJ0321 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260D 10/21/20 16:53JLB POJ0321 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260D 10/21/20 16:53JLB POJ0321 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260D 10/21/20 16:53JLB POJ0321 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260D 10/21/20 16:53JLB POJ0321 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260D 10/21/20 16:53JLB POJ0321 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260D 10/21/20 16:53JLB POJ0321 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260D 10/21/20 16:53JLB POJ0321 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 16:53JLB POJ0321 Chloroprene <0.86 ug/L 20 10 0.86 1 8260D 10/21/20 16:53JLB POJ0321 cis- 1,2-Dichloroethylene <0.056 ug/L 2 0.50 0.056 1 8260D 10/21/20 16:53JLB POJ0321 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 32 of 96 Laboratory Report A i • .0 12/01/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Client Sample ID: TB-202010140000 Attn: Alec Macbeth Sample ID: 0100203-06 231 Haywood Street Project No.: 50-02 Work Order: 0100203 Asheville, NC 28801 Sample Matrix: Water Time Collected: 10/14/20 00:00 Time Submitted: 10/15/20 08:45 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260D 10/21/20 16:53JLB POJ0321 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260D 10/21/20 16:53JLB POJ0321 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260D 10/21/20 16:53JLB POJ0321 Dichlorodifluoromethane <0.11 ug/L 5 5.0 0.11 1 8260D 10/21/20 16:53JLB POJ0321 Ethyl Methacrylate <0.26 ug/L 10 10 0.26 1 8260D 10/21/20 16:53JLB POJ0321 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260D 10/21/20 16:53JLB POJ0321 Hexachlorobutadiene <0.16 ug/L 10 2.0 0.16 1 8260D 10/21/20 16:53JLB POJ0321 Isobutyl alcohol <20 ug/L 100 50 20 1 8260D 10/21/20 16:53JLB POJ0321 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260D 10/21/20 16:53JLB POJ0321 Methacrylonitrile <0.57 ug/L 100 10 0.57 1 8260D 10/21/20 16:53JLB POJ0321 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260D 10/21/20 16:53JLB POJ0321 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260D 10/21/20 16:53JLB POJ0321 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260D 10/21/20 16:53JLB POJ0321 Methyl Isobutyl Ketone <1.0 ug/L 100 5.0 1.0 1 8260D 10/21/20 16:53JLB POJ0321 Methyl Methacrylate <0.27 ug/L 30 10 0.27 1 8260D 10/21/20 16:53JLB POJ0321 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260D 10/21/20 16:53JLB POJ0321 Naphthalene <0.30 ug/L 10 1.0 0.30 1 8260D 10/21/20 16:53JLB POJ0321 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260D 10/21/20 16:53JLB POJ0321 Propionitrile (Ethyl Cyanide) <2.1 ug/L 150 10 2.1 1 8260D 10/21/20 16:53JLB POJ0321 Styrene <0.047 ug/L 1 0.50 0.047 1 8260D 10/21/20 16:53JLB POJ0321 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260D 10/21/20 16:53JLB POJ0321 Tetrahydrofuran <1.1 ug/L NE 10 1.1 1 8260D 10/21/20 16:53JLB POJ0321 Toluene <0.044 ug/L 1 0.50 0.044 1 8260D 10/21/20 16:53JLB POJ0321 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260D 10/21/20 16:53JLB POJ0321 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260D 10/21/20 16:53JLB POJ0321 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260D 10/21/20 16:53JLB POJ0321 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260D 10/21/20 16:53JLB POJ0321 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260D 10/21/20 16:53JLB POJ0321 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260D 10/21/20 16:53JLB POJ0321 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260D 10/21/20 16:53JLB POJ0321 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260D 10/21/20 16:53JLB POJ0321 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 112 % 75-129 Toluene-d8 100 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 33 of 96 (2) Way po Int ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 1211120 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene 0.290 1.0 ug/L J 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L Acetone BRL 5.0 ug/L Acetonitrile BRL 10 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Allyl Chloride (3-Chloropropylene) BRL 10 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L Chloroprene BRL 10 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 5.0 ug/L Ethyl Methacrylate BRL 10 ug/L Ethylbenzene BRL 0.50 ug/L Hexachlorobutadiene 0.220 2.0 ug/L J Isobutyl alcohol BRL 50 ug/L m,p-Xylenes 0.250 1.0 ug/L J Methacrylonitrile BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 34 of 96 Waypoint ' ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B Blank (POJ0321-BLK1) Prepared & Analyzed: 10/21/20 Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methyl Methacrylate BRL 10 ug/L Methylene Chloride BRL 1.0 ug/L Naphthalene BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Propionitrile (Ethyl Cyanide) BRL 10 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total 0.250 1.5 ug/L J Surrogate:4-Bromofluorobenzene 50.3 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 53.8 ug/L 50.00 108 75-129 Surrogate: Toluene-d8 49.6 ug/L 50.00 99 77-123 LCS (POJ0321-BS1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.5 0.50 ug/L 20.00 108 79-134 1,1,1-Trichloroethane 21.3 0.50 ug/L 20.00 106 75-136 1,1,2,2-Tetrachloroethane 21.0 0.50 ug/L 20.00 105 62-127 1,1,2-Trichloroethane 21.6 0.50 ug/L 20.00 108 70-140 1,1-Dichloroethane 21.6 0.50 ug/L 20.00 108 78-130 1,1-Dichloroethylene 21.2 0.50 ug/L 20.00 106 70-154 1, 1 -Dichloropropylene 22.0 0.50 ug/L 20.00 110 71-136 1,2,3-Trichloropropane 21.2 1.0 ug/L 20.00 106 71-127 1,2,4-Trichlorobenzene 20.4 1.0 ug/L 20.00 102 66-139 1,2-Dibromo-3-chloropropane 22.9 2.0 ug/L 20.00 114 63-134 1,2-Dibromoethane 21.3 0.50 ug/L 20.00 107 77-135 1,2-Dichlorobenzene 21.3 0.50 ug/L 20.00 106 78-128 1,2-Dichloroethane 21.6 0.50 ug/L 20.00 108 68-131 1,2-Dichloropropane 21.9 0.50 ug/L 20.00 110 77-130 1,3-Dichlorobenzene 21.5 0.50 ug/L 20.00 107 77-125 1,3-Dichloropropane 22.0 0.50 ug/L 20.00 110 76-132 1,4-Dichlorobenzene 20.8 0.50 ug/L 20.00 104 75-126 2,2-Dichloropropane 23.8 2.0 ug/L 20.00 119 29-149 Acetone 39.6 5.0 ug/L 40.00 99 40-166 Acetonitrile 19.4 10 ug/L 20.00 97 70-130 Acrolein 45.9 20 ug/L 40.00 115 70-130 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 35 of 96 Waypoint ' ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Acrylonitrile 42.3 20 ug/L 40.00 106 81-127 Allyl Chloride (3-Chloropropylene) 19.4 10 ug/L 20.00 97 70-130 Benzene 22.7 0.50 ug/L 20.00 114 77-128 Bromochloromethane 22.1 0.50 ug/L 20.00 110 78-135 Bromodichloromethane 21.7 0.50 ug/L 20.00 108 76-138 Bromoform 22.4 1.0 ug/L 20.00 112 71-135 Bromomethane 21.0 1.0 ug/L 20.00 105 41-168 Carbon disulfide 21.1 5.0 ug/L 20.00 106 59-135 Carbon Tetrachloride 21.7 0.50 ug/L 20.00 109 72-142 Chlorobenzene 22.0 0.50 ug/L 20.00 110 78-119 Chloroethane 21.5 0.50 ug/L 20.00 107 57-142 Chloroform 21.0 0.50 ug/L 20.00 105 77-130 Chloromethane 20.5 0.50 ug/L 20.00 102 47-145 Chloroprene 19.7 10 ug/L 20.00 98 70-130 cis-1,2-Dichloroethylene 22.5 0.50 ug/L 20.00 113 76-141 cis-1,3-Dichloropropylene 22.4 0.50 ug/L 20.00 112 65-140 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 Dibromomethane 21.8 0.50 ug/L 20.00 109 76-138 Dichlorodifluoromethane 25.2 5.0 ug/L 20.00 126 28-163 Ethyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 Ethylbenzene 22.7 0.50 ug/L 20.00 114 80-127 Hexachlorobutadiene 20.1 2.0 ug/L 20.00 100 61-134 Isobutyl alcohol 24.0 50 ug/L 20.00 120 70-130 J m,p-Xylenes 48.4 1.0 ug/L 40.00 121 77-133 Methacrylonitrile 19.5 10 ug/L 20.00 98 70-130 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 114 64-137 Methyl Ethyl Ketone (2-Butanone) 20.2 5.0 ug/L 20.00 101 71-134 Methyl Iodide 23.5 5.0 ug/L 20.00 118 70-130 Methyl Isobutyl Ketone 23.8 5.0 ug/L 20.00 119 69-134 Methyl Methacrylate 20.3 10 ug/L 20.00 102 70-130 Methylene Chloride 20.7 1.0 ug/L 20.00 103 73-131 Naphthalene 21.0 1.0 ug/L 20.00 105 64-136 o-Xylene 22.8 0.50 ug/L 20.00 114 78-128 Propionitrile (Ethyl Cyanide) 22.1 10 ug/L 20.00 110 70-130 Styrene 23.3 0.50 ug/L 20.00 116 78-129 Tetrachloroethylene 21.2 0.50 ug/L 20.00 106 80-129 Tetrahydrofuran 22.3 10 ug/L 20.00 112 70-130 Toluene 22.5 0.50 ug/L 20.00 113 76-131 trans- 1,2-Dichloroethylene 21.6 0.50 ug/L 20.00 108 76-135 trans- 1,3-Dichloropropylene 23.1 0.50 ug/L 20.00 116 67-140 trans-1,4-Dichloro-2-butene 21.1 10 ug/L 20.00 105 70-130 Trichloroethylene 21.3 0.50 ug/L 20.00 107 77-133 Trichlorofluoromethane 22.6 0.50 ug/L 20.00 113 62-148 Vinyl acetate 26.3 2.0 ug/L 20.00 131 34-167 Vinyl chloride 22.4 0.50 ug/L 20.00 112 57-141 Xylenes, total 71.2 1.5 ug/L 60.00 119 77-133 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 36 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS (POJ0321-BSI) Prepared &Analyzed: 10/21/20 Surrogate:4-Bromofluorobenzene 48.4 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.3 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.0 ug/L 50.00 100 77-123 LCS Dup (POJ0321-BSD1) Prepared &Analyzed: 10/21/20 1,1,1,2-Tetrachloroethane 21.4 0.50 ug/L 20.00 107 79-134 0.6 20 1,1,1-Trichloroethane 20.5 0.50 ug/L 20.00 102 75-136 4 20 1,1,2,2-Tetrachloroethane 20.7 0.50 ug/L 20.00 103 62-127 2 20 1,1,2-Trichloroethane 21.4 0.50 ug/L 20.00 107 70-140 1 20 1,1-Dichloroethane 20.4 0.50 ug/L 20.00 102 78-130 5 20 1,1-Dichloroethylene 20.2 0.50 ug/L 20.00 101 70-154 5 20 1,1-Dichloropropylene 21.0 0.50 ug/L 20.00 105 71-136 5 20 1,2,3-Trichloropropane 21.1 1.0 ug/L 20.00 106 71-127 0.6 20 1,2,4-Trichlorobenzene 20.7 1.0 ug/L 20.00 103 66-139 1 20 1,2-Dibromo-3-chloropropane 21.7 2.0 ug/L 20.00 108 63-134 5 20 1,2-Dibromoethane 20.9 0.50 ug/L 20.00 104 77-135 2 20 1,2-Dichlorobenzene 20.5 0.50 ug/L 20.00 103 78-128 4 20 1,2-Dichloroethane 21.1 0.50 ug/L 20.00 106 68-131 2 20 1,2-Dichloropropane 21.3 0.50 ug/L 20.00 107 77-130 3 20 1,3-Dichlorobenzene 21.1 0.50 ug/L 20.00 105 77-125 2 20 1,3-Dichloropropane 21.3 0.50 ug/L 20.00 106 76-132 3 20 1,4-Dichlorobenzene 20.4 0.50 ug/L 20.00 102 75-126 2 20 2,2-Dichloropropane 21.4 2.0 ug/L 20.00 107 29-149 11 20 Acetone 39.2 5.0 ug/L 40.00 98 40-166 1 20 Acetonitrile 21.5 10 ug/L 20.00 107 70-130 10 20 Acrolein 46.1 20 ug/L 40.00 115 70-130 0.5 20 Acrylonitrile 42.2 20 ug/L 40.00 105 81-127 0.4 20 Allyl Chloride (3-Chloropropylene) 18.8 10 ug/L 20.00 94 70-130 3 20 Benzene 21.8 0.50 ug/L 20.00 109 77-128 4 20 Bromochloromethane 20.5 0.50 ug/L 20.00 103 78-135 7 20 Bromodichloromethane 20.8 0.50 ug/L 20.00 104 76-138 4 20 Bromoform 21.5 1.0 ug/L 20.00 107 71-135 4 20 Bromomethane 19.7 1.0 ug/L 20.00 99 41-168 6 20 Carbon disulfide 20.5 5.0 ug/L 20.00 102 59-135 3 20 Carbon Tetrachloride 20.9 0.50 ug/L 20.00 105 72-142 4 20 Chlorobenzene 21.2 0.50 ug/L 20.00 106 78-119 4 20 Chloroethane 20.2 0.50 ug/L 20.00 101 57-142 6 20 Chloroform 20.6 0.50 ug/L 20.00 103 77-130 2 20 Chloromethane 20.0 0.50 ug/L 20.00 100 47-145 2 20 Chloroprene 18.8 10 ug/L 20.00 94 70-130 5 20 cis-1,2-Dichloroethylene 20.4 0.50 ug/L 20.00 102 76-141 10 20 cis-1,3-Dichloropropylene 21.9 0.50 ug/L 20.00 110 65-140 2 20 Dibromochloromethane 21.2 0.50 ug/L 20.00 106 75-134 0.1 20 Dibromomethane 21.3 0.50 ug/L 20.00 107 76-138 2 20 Dichlorodifluoromethane 24.2 5.0 ug/L 20.00 121 28-163 4 20 Ethyl Methacrylate 19.4 10 ug/L 20.00 97 70-130 1 20 Ethylbenzene 22.0 0.50 ug/L 20.00 110 80-127 3 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 37 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0321 - 5030B LCS Dup (POJ0321-BSD1) Prepared &Analyzed: 10/21/20 Hexachlorobutadiene 19.9 2.0 ug/L 20.00 99 61-134 1 20 Isobutyl alcohol 21.3 50 ug/L 20.00 106 70-130 12 20 1 m,p-Xylenes 47.1 1.0 ug/L 40.00 118 77-133 3 20 Methacrylonitrile 19.2 10 ug/L 20.00 96 70-130 2 20 Methyl Butyl Ketone (2-Hexanone) 22.7 5.0 ug/L 20.00 113 64-137 0.3 20 Methyl Ethyl Ketone (2-Butanone) 19.7 5.0 ug/L 20.00 98 71-134 3 20 Methyl Iodide 22.6 5.0 ug/L 20.00 113 70-130 4 20 Methyl Isobutyl Ketone 22.7 5.0 ug/L 20.00 113 69-134 5 20 Methyl Methacrylate 19.7 10 ug/L 20.00 99 70-130 3 20 Methylene Chloride 19.8 1.0 ug/L 20.00 99 73-131 5 20 Naphthalene 21.4 1.0 ug/L 20.00 107 64-136 2 20 o-Xylene 22.3 0.50 ug/L 20.00 112 78-128 2 20 Propionitrile (Ethyl Cyanide) 19.9 10 ug/L 20.00 100 70-130 10 20 Styrene 22.7 0.50 ug/L 20.00 113 78-129 3 20 Tetrachloroethylene 20.4 0.50 ug/L 20.00 102 80-129 4 20 Tetrahydrofuran 22.0 10 ug/L 20.00 110 70-130 2 20 Toluene 21.6 0.50 ug/L 20.00 108 76-131 4 20 trans-1,2-Dichloroethylene 20.6 0.50 ug/L 20.00 103 76-135 5 20 trans-1,3-Dichloropropylene 22.2 0.50 ug/L 20.00 ill 67-140 4 20 trans-1,4-Dichloro-2-butene 19.6 10 ug/L 20.00 98 70-130 7 20 Trichloroethylene 21.2 0.50 ug/L 20.00 106 77-133 0.7 20 Trichlorofluoromethane 21.4 0.50 ug/L 20.00 107 62-148 6 20 Vinyl acetate 25.7 2.0 ug/L 20.00 129 34-167 2 20 Vinyl chloride 21.2 0.50 ug/L 20.00 106 57-141 5 20 Xylenes, total 69.4 1.5 ug/L 60.00 116 77-133 2 20 Surrogate:4-Bromofluorobenzene 48.3 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.5 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 50.3 ug/L 50.00 101 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 38 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0316 - 5030B Blank (POJ0316-BLK1) Prepared & Analyzed: 10/16/20 1,4-Dioxane BRL 2.0 ug/L LCS (POJ0316-BS1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.5 2.0 ug/L 50.00 95 55-145 LCS Dup (POJ0316-BSD1) Prepared &Analyzed: 10/16/20 1,4-Dioxane 47.1 2.0 ug/L 50.00 94 55-145 0.7 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 39 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Blank (POJ0286-BLK1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD BRL 0.10 ug/L 4,4'-DDE BRL 0.10 ug/L 4,4'-DDT BRL 0.10 ug/L Aldrin BRL 0.050 ug/L alpha-BHC BRL 0.050 ug/L cis -Chlordane BRL 0.10 ug/L beta-BHC BRL 0.050 ug/L Chlordane BRL 0.50 ug/L delta-BHC BRL 0.050 ug/L Dieldrin BRL 0.050 ug/L Endosulfan I BRL 0.050 ug/L Endosulfan II BRL 0.050 ug/L Endosulfan Sulfate BRL 0.050 ug/L Endrin BRL 0.050 ug/L Endrin Aldehyde BRL 0.050 ug/L Endrin Ketone BRL 0.10 ug/L gamma-BHC BRL 0.050 ug/L trans -Chlordane BRL 0.10 ug/L Heptachlor BRL 0.050 ug/L Heptachlor Epoxide BRL 0.10 ug/L Methoxychlor BRL 0.10 ug/L Toxaphene BRL 1.0 ug/L Surrogate: Decachlorobiphenyl 0.560 ug/L 1.000 56 13-186 Surrogate: Tetrachloro-m-xylene 0.630 ug/L 1.000 63 40-134 LCS (POJ0286-BS1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD 0.690 0.10 ug/L 1.000 69 56-143 4,4'-DDE 0.700 0.10 ug/L 1.000 70 57-135 4,4'-DDT 0.740 0.10 ug/L 1.000 74 51-143 Aldrin 0.640 0.050 ug/L 1.000 64 45-134 alpha-BHC 0.680 0.050 ug/L 1.000 68 54-138 cis -Chlordane 0.680 0.10 ug/L 1.000 68 60-129 beta-BHC 0.640 0.050 ug/L 1.000 64 56-136 delta-BHC 0.680 0.050 ug/L 1.000 68 52-142 Dieldrin 0.710 0.050 ug/L 1.000 71 60-136 Endosulfan 1 0.690 0.050 ug/L 1.000 69 62-126 Endosulfan II 0.710 0.050 ug/L 1.000 71 52-135 Endosulfan Sulfate 0.670 0.050 ug/L 1.000 67 62-133 Endrin 0.790 0.050 ug/L 1.000 79 60-138 Endrin Aldehyde 0.630 0.050 ug/L 1.000 63 51-132 Endrin Ketone 0.670 0.10 ug/L 1.000 67 58-134 gamma-BHC 0.670 0.050 ug/L 1.000 67 59-134 trans -Chlordane 0.670 0.10 ug/L 1.000 67 56-136 Heptachlor 0.670 0.050 ug/L 1.000 67 54-130 Heptachlor Epoxide 0.690 0.10 ug/L 1.000 69 61-133 Methoxychlor 0.710 0.10 ug/L 1.000 71 54-145 Surrogate: Decachlorobiphenyl 0.500 ug/L 1.000 50 13-186 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 40 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Organochlorine Pesticides by GC/ECD - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC LCS (POJ0286-BS1) Prepared: 10/16/20 Analyzed: 10/19/20 Surrogate: Tetrachloro-m-xylene 0.730 ug/L 1.000 73 40-134 LCS (POJ0286-BS2) Prepared: 10/16/20 Analyzed: 10/19/20 Chlordane 7.87 0.50 ug/L 10.00 79 62-140 Surrogate: Decachlorobiphenyl 0.580 ug/L 1.000 58 13-186 Surrogate: Tetrachloro-m-xylene 0.630 ug/L 1.000 63 40-134 LCS (POJ0286-BS3) Prepared: 10/16/20 Analyzed: 10/19/20 Toxaphene 9.00 1.0 ug/L 10.00 90 33-134 Surrogate: Decachlorobiphenyl 0.510 ug/L 1.000 51 13-186 Surrogate: Tetrachloro-m-xylene 0.690 ug/L 1.000 69 40-134 LCS Dup (POJ0286-BSD1) Prepared: 10/16/20 Analyzed: 10/19/20 4,4'-DDD 0.660 0.10 ug/L 1.000 66 56-143 4 30 4,4'-DDE 0.670 0.10 ug/L 1.000 67 57-135 4 30 4,4'-DDT 0.710 0.10 ug/L 1.000 71 51-143 4 30 Aldrin 0.610 0.050 ug/L 1.000 61 45-134 5 30 alpha-BHC 0.660 0.050 ug/L 1.000 66 54-138 3 30 cis -Chlordane 0.650 0.10 ug/L 1.000 65 60-129 5 30 beta-BHC 0.570 0.050 ug/L 1.000 57 56-136 12 30 delta-BHC 0.620 0.050 ug/L 1.000 62 52-142 9 30 Dieldrin 0.680 0.050 ug/L 1.000 68 60-136 4 30 Endosulfan 1 0.670 0.050 ug/L 1.000 67 62-126 3 30 Endosulfan 11 0.690 0.050 ug/L 1.000 69 52-135 3 30 Endosulfan Sulfate 0.630 0.050 ug/L 1.000 63 62-133 6 30 Endrin 0.750 0.050 ug/L 1.000 75 60-138 5 30 Endrin Aldehyde 0.600 0.050 ug/L 1.000 60 51-132 5 30 Endrin Ketone 0.650 0.10 ug/L 1.000 65 58-134 3 30 gamma-BHC 0.640 0.050 ug/L 1.000 64 59-134 5 30 trans -Chlordane 0.640 0.10 ug/L 1.000 64 56-136 5 30 Heptachlor 0.640 0.050 ug/L 1.000 64 54-130 5 30 Heptachlor Epoxide 0.670 0.10 ug/L 1.000 67 61-133 3 30 Methoxychlor 0.680 0.10 ug/L 1.000 68 54-145 4 30 Surrogate: Decachlorobiphenyl 0.560 ug/L 1.000 56 13-186 Surrogate: Tetrachloro-m-xylene 0.680 ug/L 1.000 68 40-134 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 41 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Polychlorinated Biphenyls (PCBs) by GC/ECD - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0286 - 3510C GC Blank (POJ0286-BLK1) Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 BRL 0.50 ug/L Aroclor 1221 BRL 1.0 ug/L Aroclor 1232 BRL 0.50 ug/L Aroclor 1242 BRL 0.50 ug/L Aroclor 1248 BRL 0.50 ug/L Aroclor 1254 BRL 0.50 ug/L Aroclor 1260 BRL 1.0 ug/L Surrogate: Tetrachloro-m-xylene 0.610 ug/L 1.000 61 30-161 Surrogate: Decachlorobiphenyl 0.580 ug/L 1.000 58 32-178 LCS (POJ0286-BS4) Prepared: 10/16/20 Analyzed: 10/19/20 Aroclor 1016 6.63 0.50 ug/L 10.00 66 50-114 Aroclor 1221 BRL 1.0 ug/L 15-178 Aroclor 1232 BRL 0.50 ug/L 10-215 Aroclor 1242 BRL 0.50 ug/L 39-150 Aroclor 1248 BRL 0.50 ug/L 38-158 Aroclor 1254 BRL 0.50 ug/L 29-131 Aroclor 1260 7.65 1.0 ug/L 10.00 76 10-127 Surrogate: Tetrachloro-m-xylene 0.620 ug/L 1.000 62 30-161 Surrogate: Decachlorobiphenyl 0.690 ug/L 1.000 69 32-178 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 42 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0312 - 3005A Blank (POJ0312-BLK1) Prepared: 10/16/20 Analyzed: 10/24/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 2.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel 0.697 3.0 ug/L J Selenium BRL 5.0 ug/L Thallium BRL 2.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (POJ0312-BS1) Prepared: 10/16/20 Analyzed: 10/24/20 Antimony 113 2.0 ug/L 100.0 113 80-120 Arsenic 97.2 1.0 ug/L 100.0 97 80-120 Barium 93.2 2.0 ug/L 100.0 93 80-120 Beryllium 104 1.0 ug/L 100.0 104 80-120 Cadmium 101 1.0 ug/L 100.0 101 80-120 Cobalt 99.6 2.0 ug/L 100.0 100 80-120 Copper 98.6 10 ug/L 100.0 99 80-120 Lead 101 1.0 ug/L 100.0 101 80-120 Nickel 99.0 3.0 ug/L 100.0 99 80-120 Selenium 94.9 5.0 ug/L 100.0 95 80-120 Thallium 98.7 2.0 ug/L 100.0 99 80-120 Vanadium 99.9 5.0 ug/L 100.0 100 80-120 Zinc 95.2 20 ug/L 100.0 95 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 43 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0374 - 7470A Blank (POJ0374-BLK1) Prepared & Analyzed: 10/20/20 Mercury BRL 0.20 ug/L LCS (POJ0374-BS1) Prepared &Analyzed: 10/20/20 Mercury 8.17 0.20 ug/L 9.375 87 80-120 Batch POJ0491 - 3005A Blank (POJ0491-BLK1) Prepared & Analyzed: 10/27/20 Chromium BRL 2.0 ug/L Silver BRL 1.0 ug/L Tin BRL 5.0 ug/L LCS (POJ0491-BS1) Prepared &Analyzed: 10/27/20 Chromium 93.0 2.0 ug/L 100.0 93 80-120 Silver 97.8 1.0 ug/L 100.0 98 80-120 Tin 99.3 5.0 ug/L 100.0 99 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 44 of 96 Level II QC Report 0int 12/1/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Dissolved Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0394 - 7470A Blank (POJ0394-BLK1) Prepared &Analyzed: 10/21/20 Mercury BRL 0.20 ug/L LCS (POJ0394-BS1) Prepared &Analyzed: 10/21/20 Mercury 8.50 0.20 ug/L 9.375 91 80-120 Matrix Spike (POJ0394-MS1) Source: 0100203-03 Prepared & Analyzed: 10/21/20 Mercury 8.52 0.20 ug/L 9.375 BRL 91 80-120 Matrix Spike Dup (POJ0394-MSD1) Source: 0100203-03 Prepared &Analyzed: 10/21/20 Mercury 8.50 0.20 ug/L 9.375 BRL 91 80-120 0.3 20 Post Spike (POJ0394-PS1) Source: 0100203-03 Prepared &Analyzed: 10/21/20 Mercury 4.47 ug/L 5.000-0.000620 89 85-115 Batch POJ0496 - 3005A Blank (POJ0496-BLK1) Prepared: 10/27/20 Analyzed: 10/28/20 Antimony BRL 2.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L Thallium BRL 2.0 ug/L Tin BRL 5.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 45 of 96 Level II QC Report 0int 12/1/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Dissolved Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0496 - 3005A LCS (POJ0496-BS1) Prepared: 10/27/20 Analyzed: 10/28/20 Antimony 88.3 2.0 ug/L 100.0 88 80-120 Arsenic 92.1 1.0 ug/L 100.0 92 80-120 Barium 97.5 10 ug/L 100.0 98 80-120 Beryllium 90.5 1.0 ug/L 100.0 91 80-120 Cadmium 97.2 1.0 ug/L 100.0 97 80-120 Chromium 93.1 2.0 ug/L 100.0 93 80-120 Cobalt 93.6 2.0 ug/L 100.0 94 80-120 Copper 90.8 10 ug/L 100.0 91 80-120 Lead 93.6 1.0 ug/L 100.0 94 80-120 Nickel 92.1 3.0 ug/L 100.0 92 80-120 Selenium 96.4 5.0 ug/L 100.0 96 80-120 Silver 94.0 1.0 ug/L 100.0 94 80-120 Thallium 93.5 2.0 ug/L 100.0 93 80-120 Tin 94.9 5.0 ug/L 100.0 95 80-120 Vanadium 93.5 5.0 ug/L 100.0 94 80-120 Zinc 95.4 20 ug/L 100.0 95 80-120 Matrix Spike (POJ0496-MS1) Source: 0100203-03 Prepared: 10/27/20 Analyzed: 10/28/20 Antimony 88.2 2.0 ug/L 100.0 BRL 88 75-125 Arsenic 92.9 1.0 ug/L 100.0 BRL 93 75-125 Barium 110 10 ug/L 100.0 11.6 98 75-125 Beryllium 98.7 1.0 ug/L 100.0 BRL 99 75-125 Cadmium 96.3 1.0 ug/L 100.0 BRL 96 75-125 Chromium 94.3 2.0 ug/L 100.0 BRL 94 75-125 Cobalt 95.1 2.0 ug/L 100.0 BRL 95 75-125 Copper 92.5 10 ug/L 100.0 BRL 93 75-125 Lead 96.3 1.0 ug/L 100.0 BRL 96 75-125 Nickel 93.1 3.0 ug/L 100.0 BRL 93 75-125 Selenium 98.9 5.0 ug/L 100.0 BRL 99 75-125 Silver 94.4 1.0 ug/L 100.0 BRL 94 75-125 Thallium 94.7 2.0 ug/L 100.0 BRL 95 75-125 Tin 94.4 5.0 ug/L 100.0 BRL 94 75-125 Vanadium 94.3 5.0 ug/L 100.0 BRL 94 75-125 Zinc 98.5 20 ug/L 100.0 BRL 99 75-125 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 46 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Dissolved Metals - Quality Control Analyte Batch POJ0496 - 3005A Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Matrix Spike Dup (POJ0496-MSD1) Source: 0100203-03 Prepared: 10/27/20 Analyzed: 10/28/20 Antimony 89.9 2.0 ug/L 100.0 BRL 90 75-125 2 20 Arsenic 90.8 1.0 ug/L 100.0 BRL 91 75-125 2 20 Barium 109 10 ug/L 100.0 11.6 97 75-125 1 20 Beryllium 97.2 1.0 ug/L 100.0 BRL 97 75-125 2 20 Cadmium 98.0 1.0 ug/L 100.0 BRL 98 75-125 2 20 Chromium 92.8 2.0 ug/L 100.0 BRL 93 75-125 2 20 Cobalt 94.4 2.0 ug/L 100.0 BRL 94 75-125 0.7 20 Copper 91.9 10 ug/L 100.0 BRL 92 75-125 0.6 20 Lead 94.8 1.0 ug/L 100.0 BRL 95 75-125 1 20 Nickel 92.2 3.0 ug/L 100.0 BRL 92 75-125 0.9 20 Selenium 97.2 5.0 ug/L 100.0 BRL 97 75-125 2 20 Silver 93.6 1.0 ug/L 100.0 BRL 94 75-125 0.9 20 Thallium 94.2 2.0 ug/L 100.0 BRL 94 75-125 0.5 20 Tin 96.2 5.0 ug/L 100.0 BRL 96 75-125 2 20 Vanadium 93.1 5.0 ug/L 100.0 BRL 93 75-125 1 20 Zinc 98.5 20 ug/L 100.0 BRL 99 75-125 0.009 20 Post Spike (POJ0496-PS1) Source: 0100203-03 Prepared: 10/27/20 Analyzed: 10/28/20 Antimony 92.0 ug/L 100.0 0.394 92 80-120 Arsenic 93.3 ug/L 100.0 0.114 93 80-120 Barium 115 ug/L 100.0 11.6 103 80-120 Beryllium 95.2 ug/L 100.0 0.101 95 80-120 Cadmium 100 ug/L 100.0 0.00500 100 80-120 Chromium 95.6 ug/L 100.0 0.00100 96 80-120 Cobalt 96.2 ug/L 100.0 0.0220 96 80-120 Copper 93.8 ug/L 100.0 0.268 94 80-120 Lead 97.5 ug/L 100.0 0.0680 97 80-120 Nickel 95.5 ug/L 100.0 0.180 95 80-120 Selenium 101 ug/L 100.0 0.247 101 80-120 Silver 96.6 ug/L 100.0 0.0100 97 80-120 Thallium 96.6 ug/L 100.0 0.0350 97 80-120 Tin 98.5 ug/L 100.0 0.153 98 80-120 Vanadium 94.1 ug/L 100.0 0.0710 94 80-120 Zinc 103 ug/L 100.0 3.18 100 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 47 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0299 - NO PREP Blank (POJ0299-BLK1) Prepared & Analyzed: 10/15/20 Chloride BRL 1000 ug/L Nitrate as N BRL 200 ug/L Sulfate BRL 2000 ug/L LCS (POJ0299-BS1) Prepared &Analyzed: 10/15/20 Chloride 41100 1000 ug/L 40000 103 80-120 Nitrate as N 4000 210 ug/L 4000 100 80-120 Sulfate 41500 2100 ug/L 40000 104 80-120 Matrix Spike (POJ0299-MS1) Source: 0100203-01 Prepared & Analyzed: 10/15/20 Chloride 42300 1000 ug/L 40000 1170 103 80-120 Nitrate as N 4000 210 ug/L 4000 BRL 100 80-120 Sulfate 42200 2100 ug/L 40000 BRL 105 80-120 Matrix Spike Dup (POJ0299-MSD1) Source: 0100203-01 Prepared & Analyzed: 10/15/20 Chloride 42100 1000 ug/L 40000 1170 102 80-120 0.5 15 Nitrate as N 3980 210 ug/L 4000 BRL 99 80-120 0.6 15 Sulfate 41900 2100 ug/L 40000 BRL 105 80-120 0.6 15 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 48 of 96 Level II QC Report 0int 12/1/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0269 - NO PREP Blank (POJ0269-BLK1) Prepared & Analyzed: 10/15/20 Hardness BRL 5000 ug/L LCS (POJ0269-BS1) Prepared &Analyzed: 10/15/20 Hardness 50000 5000 ug/L 50000 100 90-110 Matrix Spike (POJ0269-MS1) Source: 0100203-04 Prepared & Analyzed: 10/15/20 Hardness 15500 5000 ug/L 10000 5500 100 80-120 Matrix Spike Dup (POJ0269-MSD1) Source: 0100203-04 Prepared & Analyzed: 10/15/20 Hardness 15000 5000 ug/L 10000 5500 95 80-120 3 20 Batch POJ0282 - NO PREP Blank (POJ0282-BLK1) Prepared & Analyzed: 10/15/20 Ferrous Iron BRL 200 ug/L LCS (POJ0282-BS1) Prepared &Analyzed: 10/15/20 Ferrous Iron 1930 200 ug/L 2000 96 90-110 Batch POJ0337 - SM4500-S C Blank (POJ0337-BLK1) Prepared & Analyzed: 10/19/20 Sulfide BRL 2000 ug/L LCS (POJ0337-BS1) Prepared &Analyzed: 10/19/20 Sulfide 7900 2000 ug/L 10000 79 70-122 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 49 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0340 - NO PREP Blank (POJ0340-BLK1) Prepared & Analyzed: 10/15/20 Biochemical Oxygen Demand BRL 2000 ug/L LCS (POJ0340-BS1) Prepared &Analyzed: 10/15/20 Biochemical Oxygen Demand 194000 2000 ug/L 198000 98 84.6-115.4 Batch POJ0341 - NO PREP Blank (POJ0341-BLK1) Prepared & Analyzed: 10/19/20 Total Alkalinity to pH 4.5 BRL 5000 ug/L LCS (POJ0341-BSI) Prepared &Analyzed: 10/19/20 Total Alkalinity to pH 4.5 249000 5000 ug/L 90-110 Batch POJ0357 - 9010C Blank (POJ0357-BLK1) Prepared & Analyzed: 10/20/20 Cyanide BRL 25 ug/L LCS (POJ0357-BS1) Prepared &Analyzed: 10/20/20 Cyanide 96.5 25 ug/L 100.0 96 85-115 Matrix Spike (POJ0357-MS1) Source: 0100203-01 Prepared & Analyzed: 10/20/20 Cyanide 95.0 25 ug/L 100.0 BRL 95 80-120 Matrix Spike Dup (POJ0357-MSD1) Source: 0100203-01 Prepared & Analyzed: 10/20/20 Cyanide 112 25 ug/L 100.0 BRL 112 80-120 16 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 50 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POJ0361 - NO PREP Blank (POJ0361-BLK1) Prepared & Analyzed: 10/19/20 Chemical Oxygen Demand BRL 50000 ug/L LCS (POJ0361-BS1) Prepared &Analyzed: 10/19/20 Chemical Oxygen Demand 498000 50000 ug/L 90-110 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 51 of 96 0int- Level II QC Report Waypo 12/1/20 ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 8270 Extended List - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517325 - 3510C BSD (0100203 LCSD-L517325) Source: 0100203 LCS-L517Prepared: 10/19/20 Analyzed: 10/21/20 2-Acetylaminofluorene 49.1 10.0 pg/L 50 53.1 98.2 20-120 7.8 20 N-Nitrosomethylethylamine 27.4 10.0 pg/L 50 26.2 54.8 20-120 4.4 20 4-Aminobiphenyl 38.8 10.0 pg/L 50 37 77.6 20-120 4.7 20 7,12-Dimethylbenz(a)anthracene 58.1 10.0 pg/L 50 48.7 116 20-120 17.6 20 N-Nitrosopiperidine 34.1 10.0 pg/L 50 33.6 68.2 20-120 1.4 20 3-Methylcholanthrene 57.1 10.0 pg/L 50 53 114 20-120 7.4 20 Isosafrole 43.9 10.0 pg/L 50 41.9 87.8 20-120 4.6 20 Diallate 48.4 10.0 pg/L 50 48.3 96.8 20-120 0.2 20 Methapyrilene 49.8 10.0 pg/L 50 35.1 99.6 20-120 34.6 20 LCD2 o-Toluidine 29.9 10.0 pg/L 50 29.4 59.8 20-120 1.6 20 5-Nitro-o-toluidine 48.6 10.0 pg/L 50 45.1 97.2 20-120 7.4 20 p-Dimethylaminoazobenzene 61.3 10.0 pg/L 50 51.1 123 20-120 18.1 20 LH N-Nitrosopyrrolidine 34.3 10.0 pg/L 50 34.4 68.6 20-120 0.2 20 Kepone 60 10.0 pg/L 50 53.4 120 20-120 11.6 20 p-Phenylenediamine 0 10.0 pg/L 50 0 0 20-120 0 20 L 1-Naphthylamine 28.8 10.0 pg/L 50 28.9 57.6 20-120 0.3 20 Pronamide 56.1 10.0 pg/L 50 51 112 20-120 9.5 20 1,4-Naphthoquinone 44.6 10.0 pg/L 50 41.7 89.2 20-120 6.7 20 Hexachloropropene 22.6 10.0 pg/L 50 18.9 45.2 20-120 17.8 20 1,3,5-Trinitrobenzene 65.8 10.0 pg/L 50 60.4 132 20-120 8.5 20 LH Safrole 39.9 10.0 pg/L 50 39.7 79.8 20-120 0.5 20 2-Naphthylamine 20.3 10.0 pg/L 50 22.7 40.6 20-120 11.1 20 BS (0100203 LCS-L517325) Prepared: 10/19/20 Analyzed: 10/21/20 Kepone 53.4 10.0 pg/L 50 107 20-120 Isosafrole 41.9 10.0 pg/L 50 83.8 20-120 Methapyrilene 35.1 10.0 pg/L 50 70.2 20-120 N-Nitrosomethylethylamine 26.2 10.0 pg/L 50 52.4 20-120 N-Nitrosopiperidine 33.6 10.0 pg/L 50 67.2 20-120 o-Toluidine 29.4 10.0 pg/L 50 58.8 20-120 p-Dimethylaminoazobenzene 51.1 10.0 pg/L 50 102 20-120 p-Phenylenediamine 0 10.0 pg/L 50 0 20-120 L Pronamide 51 10.0 pg/L 50 102 20-120 Safrole 39.7 10.0 pg/L 50 79.4 20-120 N-Nitrosopyrrolidine 34.4 10.0 pg/L 50 68.8 20-120 7,12-Dimethylbenz(a)anthracene 48.7 10.0 pg/L 50 97.4 20-120 3-Methylcholanthrene 53 10.0 pg/L 50 106 20-120 2-Acetylaminofluorene 53.1 10.0 pg/L 50 106 20-120 4-Aminobiphenyl 37 10.0 pg/L 50 74 20-120 5-Nitro-o-toluidine 45.1 10.0 pg/L 50 90.2 20-120 2-Naphthylamine 22.7 10.0 pg/L 50 45.4 20-120 Hexachloropropene 18.9 10.0 pg/L 50 37.8 20-120 1-Naphthylamine 28.9 10.0 pg/L 50 57.8 20-120 Diallate 48.3 10.0 pg/L 50 96.6 20-120 1,4-Naphthoquinone 41.7 10.0 pg/L 50 83.4 20-120 1,3,5-Trinitrobenzene 60.4 10.0 pg/L 50 121 20-120 LH This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 52 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 8270 Extended List - Quality Control Analyte Batch L517325 - 3510C Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes BLK (0100203 LRB-L517325) Prepared: 10/19/20 Analyzed: 10/20/20 N-Nitrosomethylethylamine BRL 10.0 pg/L - 1,4-Naphthoquinone BRL 10.0 pg/L Pronamide BRL 10.0 pg/L p-Dimethylaminoazobenzene BRL 10.0 pg/L 2-Acetylaminofluorene BRL 10.0 pg/L 2-Naphthylamine BRL 10.0 pg/L Safrole BRL 10.0 pg/L p-Phenylenediamine BRL 10.0 pg/L Diallate BRL 10.0 pg/L 1-Naphthylamine BRL 10.0 pg/L o-Toluidine BRL 10.0 pg/L Isosafrole BRL 10.0 pg/L Kepone BRL 10.0 pg/L Methapyrilene BRL 20.0 pg/L 7,12-Dimethylbenz(a)anthracene BRL 10.0 pg/L 1,3,5-Trinitrobenzene BRL 10.0 pg/L 5-Nitro-o-toluidine BRL 10.0 pg/L N-Nitrosopiperidine BRL 10.0 pg/L 4-Aminobiphenyl BRL 10.0 pg/L N-Nitrosopyrrolidine BRL 10.0 pg/L 3-Methylcholanthrene BRL 10.0 pg/L Hexachloropropene BRL 10.0 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 53 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Phenoxy Acid Herbicides - GC/ECD - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517923 - 8151A BSD (0100203 LCSD-L517923) Source: 0100203 LCS-L517Prepared: 10/21/20 Analyzed: 10/22/20 2,4-D 3.125 0.2078 pg/L 5 2.515 62.5 20-120 21.6 20 LCD2 Dicamba 0.3084 0.05700 pg/L 0.5 0.2569 61.6 20-120 18.2 20 Dalapon 3.799 0.5149 pg/L 12.5 2.931 30.3 20-120 25.7 20 LCD2 Dichlorprop 3.184 0.07959 pg/L 5 2.557 63.6 20-120 21.8 20 LCD2 Dinoseb 1.749 0.02698 pg/L 2.5 1.391 69.9 20-120 22.8 20 LCD2 2,4-DB 4.446 0.1364 pg/L 5 3.118 88.9 20-120 35.1 20 LCD2 MCPA 310.5 18.98 pg/L 500 247.3 62.1 20-120 22.6 20 LCD2 MCPP 366.9 11.75 pg/L 500 304.1 73.3 20-120 18.7 20 2,4,5-T 0.3553 0.01002 pg/L 0.5 0.2808 71 20-120 23.4 20 LCD2 Picloram 0.7292 0.04528 pg/L 1.25 0.5291 58.3 20-120 31.8 20 LCD2 2,4,5-TP (Silvex) 0.2916 0.01634 pg/L 0.5 0.2363 58.3 20-120 20.9 20 LCD2 Surrogate: DCAA 1.588 ug/L 2.5 1.276 63.5 20-150 BS (0100203 LCS-L517923) Prepared: 10/21/20 Analyzed: 10/22/20 MCPA 247.3 18.98 pg/L 500 49.4 20-120 Dinoseb 1.391 0.02698 pg/L 2.5 55.6 20-120 MCPP 304.1 11.75 pg/L 500 60.8 20-120 Dichlorprop 2.557 0.07959 pg/L 5 51.1 20-120 Picloram 0.5291 0.04528 pg/L 1.25 42.3 20-120 Dicamba 0.2569 0.05700 pg/L 0.5 51.3 20-120 2,4,5-TP (Silvex) 0.2363 0.01634 pg/L 0.5 47.2 20-120 2,4,5-T 0.2808 0.01002 pg/L 0.5 56.1 20-120 2,4-D 2.515 0.2078 pg/L 5 50.3 20-120 2,4-DB 3.118 0.1364 pg/L 5 62.3 20-120 Dalapon 2.931 0.5149 pg/L 12.5 23.4 20-120 Surrogate: DCAA 1.276 ug/L 2.5 51 20-150 BLK (0100203 LRB-L517923) Prepared: 10/21/20 Analyzed: 10/22/20 MCPP BRL 50.00 pg/L - Picloram BRL 0.1000 pg/L 2,4,5-TP (Silvex) BRL 0.1000 pg/L Dalapon BRL 0.5500 pg/L Dicamba BRL 0.2500 pg/L 2,4,5-T BRL 0.03000 pg/L MCPA BRL 50.00 pg/L 2,4-D BRL 0.2500 pg/L 2,4-DB BRL 0.1000 pg/L Dichlorprop BRL 0.1000 pg/L Dinoseb BRL 0.1000 pg/L - Surrogate: DCAA 1.455 ug/L 2.5 58.2 20-150 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 54 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BSD (0100203 LCSD-L517328) Source: 0100203 LCS-L517Prepared & Analyzed: 10/19/20 2-Methylphenol 25 0.721 pg/L 50 22 50 22-97 12.7 20 Fluoranthene 39 0.406 pg/L 50 36 78 28-127 8 20 2-Nitroaniline 38.4 0.574 pg/L 50 35 76.8 32-127 9.2 20 Benzyl alcohol 23.8 3.01 pg/L 50 20.5 47.6 20-109 14.8 20 Bis(2-Chloroethoxy)methane 30.7 0.433 pg/L 50 27.3 61.4 20-126 11.7 20 Di-n-Octyl Phthalate 44.9 1.72 pg/L 50 36.4 89.8 29-136 20.9 20 2-Nitrophenol 32.4 0.606 pg/L 50 28.6 64.8 25-114 12.4 20 Fluorene 34.1 0.444 pg/L 50 31.4 68.2 41-116 8.2 20 Hexachloroethane 21.7 0.277 pg/L 50 19 43.4 16-107 13.2 20 Hexachlorobenzene 36.2 2.57 pg/L 50 33.6 72.4 18-136 7.4 20 2-Methyl naphthalene 32.1 0.485 pg/L 50 29.7 64.2 34-108 7.7 20 Acenaphthene 31.1 0.422 pg/L 50 27.4 62.2 38-117 12.6 20 Benzo(a)anthracene 35.3 0.427 pg/L 50 32.5 70.6 36-127 8.2 20 Anthracene 36.1 0.467 pg/L 50 33.8 72.2 34-128 6.5 20 Hexachlorocyclopentadiene 12.1 2.34 pg/L 50 13.9 24.2 10-102 13.8 20 3,3'-Dichlorobenzidine 112 3.74 pg/L 150 95.9 74.6 6-192 15.4 20 2-Chloronaphthalene 29.5 0.476 pg/L 50 26 59 29-137 12.6 20 Acenaphthylene 32.8 0.429 pg/L 50 29.7 65.6 37-114 9.9 20 2-Chlorophenol 28.4 0.736 pg/L 50 25 56.8 27-102 12.7 20 4-Nitroaniline 53.9 0.740 pg/L 50 52.8 108 23-139 2 20 Bis(2-ethylhexyl)phthalate 37.9 3.66 pg/L 50 37.4 75.8 21-162 1.3 20 Butyl benzyl phthalate 38.1 4.59 pg/L 50 39.7 76.2 33-142 4.1 20 4-Chlorophenyl phenyl ether 34.8 0.479 pg/L 50 32.5 69.6 39-110 6.8 20 Carbazole 42.2 0.476 pg/L 50 39.1 84.4 20-147 7.6 20 4-Chloro-3-methyl phenol 36.3 0.503 pg/L 50 32.5 72.6 35-117 11 20 Bis(2-Chloroisopropyl)ether 22.2 0.546 pg/L 50 19.4 44.4 28-108 13.4 20 4-Bromophenyl phenyl ether 36.7 0.500 pg/L 50 33.4 73.4 31-124 9.4 20 Chrysene 36 0.731 pg/L 50 32.3 72 30-124 10.8 20 Diethyl phthalate 36.5 0.585 pg/L 50 33.6 73 36-130 8.2 20 Dibenz(a,h)anthrace ne 34.2 0.252 pg/L 50 29.9 68.4 27-124 13.4 20 4-Nitrophenol 11.3 1.39 pg/L 50 10.6 22.6 1-76 6.3 20 3-Nitroaniline 36.9 1.53 pg/L 50 32.3 73.8 28-142 13.2 20 Dibenzofuran 36.3 0.423 pg/L 50 33.2 72.6 40-108 8.9 20 2,4-Dinitrotoluene 35.3 0.403 pg/L 50 33.4 70.6 24-147 5.5 20 Bis(2-Chloroethyl)ether 28.8 0.447 pg/L 50 25.1 57.6 16-122 13.7 20 Indeno(1,2,3-cd)pyrene 40.4 1.01 pg/L 50 33.1 80.8 22-126 19.8 20 Dimethyl phthalate 36.4 0.510 pg/L 50 33 72.8 34-123 9.7 20 3,3' Dimethylbenzidine 76.3 1.88 pg/L 200 55.8 38.1 6-192 31 20 Di-n-butyl phthalate 37 1.58 pg/L 50 34.5 74 19-158 6.9 20 3&4 Methylphenol 26.8 0.691 pg/L 50 23.7 53.6 21-96 12.2 20 4,6-Dinitro-2-methylphenol 35.7 3.47 pg/L 50 47.1 71.4 27-128 27.5 20 1,3-Dichlorobenzene 24.2 0.491 pg/L 50 20.6 48.4 21-102 16 20 N-Nitroso-di-n-butylamine 30 0.752 pg/L 50 26.5 60 25-126 12.3 20 2,6-Dinitrotoluene 36.8 0.413 pg/L 50 33.5 73.6 36-125 9.3 20 N-Nitroso-di-n-propylamine 28.9 0.334 pg/L 50 25.3 57.8 29-114 13.2 20 2,4,5-Trichlorophenol 39.4 0.350 pg/L 50 35.1 78.8 26-118 11.5 20 LCD2 LCD2 LCD2 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 55 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BSD (0100203 LCSD-L517328) Source: 0100203 LCS-L517Prepared & Analyzed: 10/19/20 2,3,4,6-Tetrachlorophenol 38.5 0.355 pg/L 50 35.7 77 28-118 7.5 20 Pentachlorophenol 48.7 2.45 pg/L 50 49.5 97.4 17-142 1.6 20 1,4-Dichlorobenzene 24.8 0.580 pg/L 50 21.3 49.6 24-99 15.1 20 Benzo(b)fluoranthene 41.4 0.941 pg/L 50 38.4 82.8 36-131 7.5 20 Aniline 22.1 0.316 pg/L 50 18.1 44.2 16-133 19.9 20 Benzo(a)pyrene 35.5 1.00 pg/L 50 30.9 71 34-131 13.8 20 Phenol 11.9 0.389 pg/L 50 10.5 23.8 11-55 12.5 20 Benzidine 49.1 0.689 pg/L 150 37.5 32.7 2-176 26.7 20 LCD2 1,2-Dichlorobenzene 25.5 0.629 pg/L 50 22.5 51 26-100 12.5 20 1,2,4-Trichlorobenzene 27.3 0.482 pg/L 50 24.3 54.6 23-106 11.6 20 Pyrene 33 1.04 pg/L 50 40.7 66 20-154 20.8 20 LCD2 1,2,4,5-Tetrachlorobenzene 30.2 0.317 pg/L 50 26.8 60.4 28-110 11.9 20 Pyridine 15.7 0.678 pg/L 50 12.9 31.4 10-71 19.5 20 Phenanthrene 36.1 0.464 pg/L 50 33.2 72.2 40-120 8.3 20 Nitrobenzene 30 0.531 pg/L 50 26.3 60 27-117 13.1 20 Isophorone 26.6 0.360 pg/L 50 23.3 53.2 31-116 13.2 20 2,6-Dichlorophenol 35.5 0.703 pg/L 50 31.1 71 25-112 13.2 20 Benzoic Acid 18.9 5.00 pg/L 150 30.6 12.6 11-68 47.2 20 LCD2 Naphthalene 28 0.484 pg/L 50 24.7 56 33-108 12.5 20 4-Chloroaniline 28.7 0.526 pg/L 50 24.4 57.4 24-127 16.1 20 Benzo(k)fluoranthene 43.7 0.752 pg/L 50 34.5 87.4 32-132 23.5 20 LCD2 N-Nitrosodiphenylamine 31 0.783 pg/L 50 27.7 62 45-135 11.2 20 Hexachlorobutadiene 25.5 0.405 pg/L 50 22.5 51 22-109 12.5 20 2,4,6-Trichlorophenol 38.5 0.344 pg/L 50 34.3 77 26-115 11.5 20 N-Nitrosodiethylamine 32.6 0.400 pg/L 50 28.1 65.2 25-107 14.8 20 N-Nitrosodimethylamine 15.1 0.249 pg/L 50 12.8 30.2 14-84 16.4 20 Acetophenone 31.3 0.686 pg/L 50 27.2 62.6 25-108 14 20 2,4-Dimethylphenol 33.7 0.674 pg/L 50 30.2 67.4 34-105 10.9 20 2,4-Dinitrophenol 77.8 4.85 pg/L 150 103 51.8 10-132 27.8 20 LCD2 Benzo(g,h,i)perylene 33.7 1.36 pg/L 50 30.6 67.4 26-123 9.6 20 2,4-Dichlorophenol 25.7 1.52 pg/L 50 23.3 51.4 32-110 9.7 20 Surrogate:4-Terphenyl-d14 55.2 pg/L 100 74.7 55.2 35-126 Surrogate:2-Fluorophenol 23.5 pg/L 100 20.2 23.5 10-44 Surrogate:2-Fluorobiphenyl 45 Ng/L 100 43.6 45 24-93 Surrogate: 2,4,6-Tribromophenol 67.8 pg/L 100 63.3 67.8 39-110 Surrogate: Phenol-d6 16.4 Ng/L 100 14.8 16.4 7-32 Surrogate: Nitrobenzene-d5 49.7 Ng/L 100 47.4 49.7 20-91 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 56 of 96 • 0 Waypoint ANALYTICAL Level II QC Report 12/1 /20 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Work Order: 0100203 Attn: Alec Macbeth Time Submitted: 10/15/2020 8:45:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BS (0100203 LCS-L517328) Prepared & Analyzed: 10/19/20 Benzo(a)anthrace ne 32.5 0.427 pg/L 50 65 36-127 Benzoic Acid 30.6 5.00 pg/L 150 20.4 11-68 Benzo(a)pyrene 30.9 1.00 pg/L 50 61.8 34-131 Benzyl alcohol 20.5 3.01 pg/L 50 41 20-109 Benzo(k)fluoranthene 34.5 0.752 pg/L 50 69 32-132 Bis(2-Chloroethoxy)methane 27.3 0.433 pg/L 50 54.6 20-126 Bis(2-Chloroethyl)ether 25.1 0.447 pg/L 50 50.2 16-122 Benzo(b)fluoranthene 38.4 0.941 pg/L 50 76.8 36-131 Benzo(g,h,i)perylene 30.6 1.36 pg/L 50 61.2 26-123 Bis(2-Chloroisopropyl)ether 19.4 0.546 pg/L 50 38.8 28-108 N-Nitrosodiphenylamine 27.7 0.783 pg/L 50 55.4 45-135 Hexachlorobutadiene 22.5 0.405 pg/L 50 45 22-109 Nitrobenzene 26.3 0.531 pg/L 50 52.6 27-117 N-Nitrosodiethylamine 28.1 0.400 pg/L 50 56.2 25-107 N-Nitrosodimethylamine 12.8 0.249 pg/L 50 25.6 14-84 Isophorone 23.3 0.360 pg/L 50 46.6 31-116 N-Nitroso-di-n-propylamine 25.3 0.334 pg/L 50 50.6 29-114 Indeno(1,2,3-cd)pyrene 33.1 1.01 pg/L 50 66.2 22-126 Pentachlorophenol 49.5 2.45 pg/L 50 99 17-142 Phenanthrene 33.2 0.464 pg/L 50 66.4 40-120 Phenol 10.5 0.389 pg/L 50 21 11-55 Pyrene 40.7 1.04 pg/L 50 81.4 20-154 Pyridine 12.9 0.678 pg/L 50 25.8 10-71 N-Nitroso-di-n-butylamine 26.5 0.752 pg/L 50 53 25-126 Di-n-butyl phthalate 34.5 1.58 pg/L 50 69 19-158 Butyl benzyl phthalate 39.7 4.59 pg/L 50 79.4 33-142 Carbazole 39.1 0.476 pg/L 50 78.2 20-147 Chrysene 32.3 0.731 pg/L 50 64.6 30-124 Dibenz(a,h)anthrace ne 29.9 0.252 pg/L 50 59.8 27-124 Dibenzofuran 33.2 0.423 pg/L 50 66.4 40-108 Naphthalene 24.7 0.484 pg/L 50 49.4 33-108 Dimethyl phthalate 33 0.510 pg/L 50 66 34-123 Bis(2-ethylhexyl)phthalate 37.4 3.66 pg/L 50 74.8 21-162 Di-n-Octyl Phthalate 36.4 1.72 pg/L 50 72.8 29-136 Fluoranthene 36 0.406 pg/L 50 72 28-127 Fluorene 31.4 0.444 pg/L 50 62.8 41-116 Hexachlorobenzene 33.6 2.57 pg/L 50 67.2 18-136 Hexachlorocyclopentadiene 13.9 2.34 pg/L 50 27.8 10-102 Hexachloroethane 19 0.277 pg/L 50 38 16-107 Diethyl phthalate 33.6 0.585 pg/L 50 67.2 36-130 2,4-Dimethylphenol 30.2 0.674 pg/L 50 60.4 34-105 4-Chloroaniline 24.4 0.526 pg/L 50 48.8 24-127 2,4,5-Trichlorophenol 35.1 0.350 pg/L 50 70.2 26-118 4-Chloro-3-methylphenol 32.5 0.503 pg/L 50 65 35-117 2-Methyl naphthalene 29.7 0.485 pg/L 50 59.4 34-108 4,6-Dinitro-2-methylphenol 47.1 3.47 pg/L 50 94.2 27-128 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 57 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BS (0100203 LCS-L517328) Prepared & Analyzed: 10/19/20 2,4,6-Trichlorophenol 34.3 0.344 pg/L 50 68.6 26-115 3-Nitroaniline 32.3 1.53 pg/L 50 64.6 28-142 2,4-Dichlorophenol 23.3 1.52 pg/L 50 46.6 32-110 3,3'-Dichlorobenzidine 95.9 3.74 pg/L 150 63.9 6-192 2,3,4,6-Tetrachlorophenol 35.7 0.355 pg/L 50 71.4 28-118 3&4 Methylphenol 23.7 0.691 pg/L 50 47.4 21-96 4-Bromophenyl phenyl ether 33.4 0.500 pg/L 50 66.8 31-124 2-Nitrophenol 28.6 0.606 pg/L 50 57.2 25-114 2,4-Dinitrophenol 103 4.85 pg/L 150 68.6 10-132 2-Nitroaniline 35 0.574 pg/L 50 70 32-127 2-Methylphenol 22 0.721 pg/L 50 44 22-97 2,4-Dinitrotoluene 33.4 0.403 pg/L 50 66.8 24-147 2,6-Dichlorophenol 31.1 0.703 pg/L 50 62.2 25-112 2,6-Dinitrotoluene 33.5 0.413 pg/L 50 67 36-125 2-Chloronaphthalene 26 0.476 pg/L 50 52 29-137 2-Chorophenol 25 0.736 pg/L 50 50 27-102 3,3' Dimethylbenzidine 55.8 1.88 pg/L 200 27.9 6-192 1,2,4-Trichlorobenzene 24.3 0.482 pg/L 50 48.6 23-106 Acetophenone 27.2 0.686 pg/L 50 54.4 25-108 4-Chlorophenyl phenyl ether 32.5 0.479 pg/L 50 65 39-110 1,2-Dichlorobenzene 22.5 0.629 pg/L 50 45 26-100 Acenaphthene 27.4 0.422 pg/L 50 54.8 38-117 Aniline 18.1 0.316 pg/L 50 36.2 16-133 Anthracene 33.8 0.467 pg/L 50 67.6 34-128 Acenaphthylene 29.7 0.429 pg/L 50 59.4 37-114 1,3-Dichlorobenzene 20.6 0.491 pg/L 50 41.2 21-102 1,2,4,5-Tetrachlorobenzene 26.8 0.317 pg/L 50 53.6 28-110 4-Nitroaniline 52.8 0.740 pg/L 50 106 23-139 4-Nitrophenol 10.6 1.39 pg/L 50 21.2 1-76 Benzidine 37.5 0.689 pg/L 150 25 2-176 1,4-Dichlorobenzene 21.3 0.580 pg/L 50 42.6 24-99 Surrogate: Nitrobenzene-d5 47.4 Ng/L 100 47.4 20-91 Surrogate: Phenol-d6 14.8 pg/L 100 14.8 7-32 Surrogate: 2,4,6-Tribromophenol 63.3 Ng/L 100 63.3 39-110 Surrogate:2-Fluorophenol 20.2 Ng/L 100 20.2 10-44 Surrogate:2-Fluorobiphenyl 43.6 Ng/L 100 43.6 24-93 Surrogate:4-Terphenyl-d14 74.7 Ng/L 100 74.7 35-126 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 58 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BILK (0100203 LRB-L517328) Prepared & Analyzed: 10/19/20 Nitrobenzene BRL 5.00 pg/L 1,2,4-Trichlorobenzene BRL 5.00 pg/L Pyridine BRL 10.0 pg/L 2,4-Dinitrotoluene BRL 5.00 pg/L Naphthalene BRL 2.00 pg/L 2,6-Dichlorophenol BRL 5.00 pg/L Hexachloroethane BRL 5.00 pg/L 1,2,4,5-Tetrachlorobenzene BRL 5.00 pg/L 1,2-Dichlorobenzene BRL 5.00 pg/L Indeno(1,2,3-cd)pyrene BRL 2.00 pg/L Isophorone BRL 5.00 pg/L 2,6-Dinitrotoluene BRL 5.00 pg/L Pyrene BRL 2.00 pg/L 1,3-Dichlorobenzene BRL 5.00 pg/L 2,3,4,6-Tetrachlorophenol BRL 5.00 pg/L N-Nitrosodiphenylamine BRL 10.0 pg/L Pentachlorophenol BRL 10.0 pg/L N-Nitroso-di-n-propylamine BRL 5.00 pg/L 2,4,5-Trichlorophenol BRL 5.00 pg/L Phenanthrene BRL 2.00 pg/L 1,4-Dichlorobenzene BRL 5.00 pg/L N-Nitroso-di-n-butylamine BRL 5.00 pg/L N-Nitrosodimethylamine BRL 5.00 pg/L 2,4,6-Trichlorophenol BRL 5.00 pg/L 2,4-Dichlorophenol BRL 5.00 pg/L N-Nitrosodiethylamine BRL 5.00 pg/L Phenol BRL 5.00 pg/L 2,4-Dimethylphenol BRL 5.00 pg/L 2,4-Dinitrophenol BRL 10.0 pg/L 2-Chloronaphthalene BRL 5.00 pg/L Benzyl alcohol BRL 10.0 pg/L 2-Chlorophenol BRL 5.00 pg/L 4-Chloro-3-methyl phenol BRL 5.00 pg/L Hexachlorobenzene BRL 5.00 pg/L 4-Chloroaniline BRL 5.00 pg/L Bis(2-ethylhexyl)phthalate BRL 5.00 pg/L 4-Chlorophenyl phenyl ether BRL 5.00 pg/L Bis(2-Chloroisopropyl)ether BRL 5.00 pg/L Bis(2-Chloroethyl)ether BRL 5.00 pg/L 4-Nitroaniline BRL 5.00 pg/L Bis(2-Chloroethoxy)methane BRL 5.00 pg/L 4-Bromophenyl phenyl ether BRL 5.00 pg/L Carbazole BRL 5.00 pg/L Benzoic Acid BRL 10.0 pg/L Acenaphthene BRL 2.00 pg/L Acenaphthylene BRL 2.00 pg/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 59 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill 2020 Fall Attn: Alec Macbeth 231 Haywood Street Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Asheville, NC 28801 Semivolatile Organic Compounds - GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch L517328 - 3510C BILK (0100203 LRB-11-517328) Prepared & Analyzed: 10/19/20 Benzo(k)fluoranthene BRL 2.00 pg/L Acetophenone BRL 5.00 pg/L Benzo(g,h,i)perylene BRL 2.00 pg/L Benzo(b)fluoranthene BRL 2.00 pg/L Anthracene BRL 2.00 pg/L Benzidine BRL 20.0 pg/L Benzo(a)pyrene BRL 2.00 pg/L 4-Nitrophenol BRL 10.0 pg/L 2-Nitroaniline BRL 5.00 pg/L Hexachlorocyclopentadiene BRL 5.00 pg/L Hexachlorobutadiene BRL 5.00 pg/L Aniline BRL 5.00 pg/L 2-Methyl naphthalene BRL 2.00 pg/L Benzo(a)anthracene BRL 2.00 pg/L Fluorene BRL 2.00 pg/L Butyl benzyl phthalate BRL 5.00 pg/L Fluoranthene BRL 2.00 pg/L Chrysene BRL 2.00 pg/L Diethyl phthalate BRL 5.00 pg/L 4,6-Dinitro-2-methylphenol BRL 10.0 pg/L Dibenz(a,h)anthrace ne BRL 2.00 pg/L 2-Methylphenol BRL 5.00 pg/L 3-Nitroaniline BRL 10.0 pg/L Di-n-Octyl Phthalate BRL 5.00 pg/L 3,3'-Dichlorobenzidine BRL 10.0 pg/L 3,3' Dimethylbenzidine BRL 10.0 pg/L Dimethyl phthalate BRL 5.00 pg/L Di-n-butyl phthalate BRL 5.00 pg/L 3&4 Methylphenol BRL 5.00 pg/L 2-Nitrophenol BRL 5.00 pg/L Dibenzofuran BRL 5.00 pg/L - Surrogate: Phenol-d6 16.3 Ng/L 100 16.3 7-32 Surrogate: Nitrobenzene-d5 54.3 pg/L 100 54.3 20-91 Surrogate: 2,4,6-Tribromophenol 68.5 Ng/L 100 68.5 39-110 Surrogate:4-Terphenyl-d14 71.7 Ng/L 100 71.7 35-126 Surrogate:2-Fluorobiphenyl 47.9 Ng/L 100 47.9 24-93 Surrogate:2-Fluorophenol 24.2 Ng/L 100 24.2 10-44 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 60 of 96 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Organic Carbon - Quality Control Analyte Batch L518400 - 531 OC-2011 Project: Jackson Cty Landfill 2020 Fall Project No: 50-02 Level II QC Report 12/1 /20 Work Order: 0100203 Time Submitted: 10/15/2020 8:45:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes MSD (0100203 G 84826-MSD-L518400) Source: 0100203 G 84826-rPrepared: 10/23/20 Analyzed: 10/25/20 TOC 19.9 0.522 mg/L 5.26 20.2 91 70-130 1.4 20 MS (0100203 G 84826-MS-L518400) Prepared: 10/23/20 Analyzed: 10/25/20 TOC 20.2 0.522 mg/L 5.26 97 70-130 BS (0100203 LCS-L518400) Prepared: 10/23/20 Analyzed: 10/24/20 TOC 5.24 0.498 mg/L 5 105 85-115 BILK (0100203 LRB-L518400) Prepared: 10/23/20 Analyzed: 10/24/20 TOC BRL 1.00 mg/L - This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 61 of 96 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100203-03 POJ0496 50 mL 50 mL 10/27/20 9:15 0100203-04 POJ0496 50 mL 50 mL 10/27/20 9:15 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100203-03 POJ0394 20 mL 30 mL 10/21/20 11:39 0100203-04 POJ0394 20 mL 30 mL 10/21/20 11:39 Prep Method: 9010C Lab Number Batch Initial Final Date/Time 0100203-01 POJ0357 50 mL 50 mL 10/20/20 8:10 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 0100203-01 POJ0337 200 mL 200 mL 10/19/20 11:02 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100203-01 POJ0286 980 mL 10 mL 10/16/20 10:15 0100203-03 POJ0286 1000 mL 10 mL 10/16/20 10:15 0100203-04 POJ0286 990 mL 10 mL 10/16/20 10:15 Prep Method: 3510C GC Lab Number Batch Initial Final Date/Time 0100203-01 POJ0286 980 mL 10 mL 10/16/20 10:15 0100203-03 POJ0286 1000 mL 10 mL 10/16/20 10:15 0100203-04 POJ0286 990 mL 10 mL 10/16/20 10:15 Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0100203-01 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-01 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-01 POJ0491 50 mL 50 mL 10/27/20 7:00 0100203-02 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-02 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-02 POJ0491 50 mL 50 mL 10/27/20 7:00 0100203-03 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-03 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-03 POJ0491 50 mL 50 mL 10/27/20 7:00 0100203-04 POJ0491 50 mL 50 mL 10/27/20 7:00 0100203-04 POJ0312 50 mL 50 mL 10/16/20 8:32 0100203-04 POJ0312 50 mL 50 mL 10/16/20 8:32 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0100203-01 POJ0374 20 mL 30 mL 10/20/20 11:55 0100203-02 POJ0374 20 mL 30 mL 10/20/20 11:55 0100203-03 POJ0374 20 mL 30 mL 10/20/20 11:55 0100203-04 POJ0374 20 mL 30 mL 10/20/20 11:55 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 62 of 96 Sample Extraction Data Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0100203-01 POJ0321 10 mL 10 mL 10/21/20 10:00 0100203-02 POJ0321 10 mL 10 mL 10/21/20 10:00 0100203-03 POJ0321 10 mL 10 mL 10/21/20 10:00 0100203-04 POJ0321 10 mL 10 mL 10/21/20 10:00 0100203-06 POJ0321 10 mL 10 mL 10/21/20 10:00 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 0100203-01 POJ0316 5 mL 5 mL 10/16/20 10:00 0100203-02 POJ0316 5 mL 5 mL 10/16/20 10:00 0100203-03 POJ0316 5 mL 5 mL 10/16/20 10:00 0100203-04 POJ0316 5 mL 5 mL 10/16/20 10:00 Sample Extraction Data Prep Method: 3510C Lab Number Batch Initial Final Date/Time 0100203-01 L517325 10/19/20 15:45 0100203-03 L517325 10/19/20 15:45 0100203-04 L517325 10/19/20 15:45 Prep Method: 8151A Lab Number Batch Initial Final Date/Time 0100203-01 L517923 10/21/20 16:30 0100203-03 L517923 10/21/20 16:30 0100203-04 L517923 10/21/20 16:30 Prep Method: 3510C Lab Number Batch Initial Final Date/Time 0100203-01 L517328 10/19/20 15:45 0100203-03 L517328 10/19/20 15:45 0100203-04 L517328 10/19/20 15:45 Prep Method: 5310C-2011 Lab Number Batch Initial Final Date/Time 0100203-01 L518400 10/23/20 14:11 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 63 of 96 Subcontracted Analyses The following analyses were subcontracted to Pace Analytical Gulf Coast Lab Number Analysis 0100203-01 Carbon Dioxide AM20GAX 0100203-01 Methane, Ethane, Ethene (AM20GAX) 0100203-01 Volatile Fatty Acids (Sub) 0100203-07 Carbon Dioxide AM20GAX 0100203-07 Methane, Ethane, Ethene (AM20GAX) 0100203-07 Volatile Fatty Acids (Sub) 0100203-08 Carbon Dioxide AM20GAX 0100203-08 Hydrogen AM20GAX 0100203-08 Methane, Ethane, Ethene (AM20GAX) 0100203-08 Volatile Fatty Acids (Sub) 0100203-09 Carbon Dioxide AM20GAX 0100203-09 Hydrogen AM20GAX 0100203-09 Methane, Ethane, Ethene (AM20GAX) 0100203-09 Volatile Fatty Acids (Sub) The following analyses were subcontracted to Pace Analytical, Inc Lab Number 0100203-05 Analysis 524.2 (Sub) The following analyses were subcontracted to Waypoint Analytical Lab Number Analysis 0100203-01 8270 (App. II) 0100203-01 Herbicides (Sub) 0100203-01 TOC (Sub) 0100203-03 8270 (App.11) 0100203-03 Herbicides (Sub) 0100203-04 8270 (App.11) 0100203-04 Herbicides (Sub) This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 64 of 96 O` o ei o 0 LU z �� Z I I I I I I I Z I NI O Z W O }�U Z M qU) d W w a O F Z Z- n�¢ Z O rn c'• c F= ¢ W N ap0i > U F m o a � i f` v a 2 Z z` m C� . d 4 Z Z O U w Cl) 2 Q z Q U wI-W dz E ++ C c L Z z a O co UO a) W C v J G O u a w 0 w w~ 1i M V d u~i yc U) w 0-Of U> ILH cl a,_ a/ O y= N _ } W W ..> U W O J a S 0 r J CI om J U) C a o O a CL '^ � O C V C D 0 H Z d \' N d W O V.Lu u } O a Z� = O =U� EQa LL z 0 Q c 2 u S G) U) d N W O @ U) V p O 0) Q O O O a a = a > v IL to . C Q n N to 0 N C Z tV a; a O� J Q 10 X U U li •O Q�M �Z 0 q aoQ m o Ecn . ac Z Z v in Oi �a o E E U a 0 F c 0) Q Q U � � n7 T v1 'O ` ❑ �a W. W. 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'm u :; a) a) a m o$ ELE Page 66 of 96 E v o o F a x° a "_ -� aceAna lytical LELAP CERTIFICATE NUMBER: 01955 DOD -FLAP ACCREDITATION NUMBER: 74960 ANALYTICAL RESULTS PERFORMED BY Pace Analytical Gulf Coast 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 10/29/2020 Report k 230101903 11111111111111111111 Project 0100203 Deliver To Additional Recipients Angie Overcash NONE Waypoint Analytical 449 Springbrook Road PO Box 240543 Charlotte, NC 28224 704 529 6364 I25 At 1. 1 SO PJ� �o Testing Doi} EIAP Kcnto $vTAA1 Pace Gulf Coast Report#: 220101903 1 Page 67 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of Pace Gulf Coast. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature Pace Gulf Coast Report 220101903 Pace Gulf Coast Report#: 220101903 1 Page 68 of 96 Report#: 220101903 aceAnaly�ical® r Project ID: 0100203 Certifications Report Date: 10/29/2020 Certification Certification Number DOD ELAP 74960 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washington C929 USDA Soil Permit P330-16-00234 Pace Gulf Coast Report#: 220101903 1 Page 69 of 96 Report#: 220101903 ZeAnalytical® Project ID: 0100203 Report Date: 10/29/2020 Case Narrative Client: Waypoint Analytical Report: 220101903 Pace Analytical Gulf Coast received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. VOLATILES GAS CHROMATOGRAPHY In the AM20GAX analysis for analytical batch 695200, Methane was detected at an estimated concentration in the method blank. This is probable laboratory contamination. Pace Gulf Coast Report#: 220101903 1 Page 70 of 96 ZeAnalytical® Report#: Project ID: 220101903 0100203 Report Date: 10/29/2020 Sample Summary LAB ID Client ID Matrix Collect Date/Time Receive Date/Time 22010190301 MW-01-20201014 Water 10/14/202012:00 10/16/2020 12:36 22010190302 MW-02-20201013 Water 10/13/202014:50 10/16/2020 12:36 22010190303 MW-03-20201013 Water 10/13/202010:29 10/16/2020 12:36 22010190304 MW-06-20201013 Water 10/13/202013:15 10/16/2020 12:36 22010190305 MW-03-20201013 (1-12) Bubble Strip 10/13/2020 10:29 10/16/2020 12:36 22010190306 MW-06-20201013 (1-12) Bubble Strip 10/13/2020 13:15 10/16/2020 12:36 Pace Gulf Coast Report#: 220101903 1 Page 71 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Summary of Compounds Detected Collect Date 10/14/2020 12:00 LAB ID 22010190301 MW-01-20201014 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 128000 2540 18000 ug/L AM23G CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.45J 0.12 0.50 mg/L 64-18-6 Formic Acid 5.4 0.055 0.50 mg/L AM20GAX CAS# Parameter Result DL LOQ Units 74-82-8 Methane 4000 2.5 5.0 ug/L Collect Date 10/13/2020 14:50 LAB ID 22010190302 MW-02-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 CAS# Parameter 124-38-9 Carbon Dioxide AM23G CAS# Parameter 64-19-7 Acetic Acid 64-18-6 Formic Acid 79-09-4 Propionic Acid AM20GAX CAS# Parameter 74-82-8 Methane Result DL LOQ Units 37100 2540 18000 ug/L Result DL LOQ Units 0.76 0.12 0.50 mg/L 5.1 0.055 0.50 mg/L 0.053.1 0.053 0.50 mg/L Result DL LOQ Units 5.0 2.5 5.0 ug/L Pace Gulf Coast Report#: 220101903 1 Page 72 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Summary of Compounds Detected Collect Date 10/13/2020 10:29 LAB ID 22010190303 MW-03-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 CAS# Parameter Result DL LOQ Units 124-38-9 Carbon Dioxide 14700 635 4500 ug/L AM23G CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.95 0.12 0.50 mg/L 64-18-6 Formic Acid 4.8 0.055 0.50 mg/L 50-21-5 Lactic Acid 0.072J 0.053 0.50 mg/L 79-09-4 Propionic Acid 0.056J 0.053 0.50 mg/L AM20GAX CAS# Parameter Result DL LOQ Units 74-82-8 Methane 3.5,1 2.5 5.0 ug/L Collect Date 10/13/2020 13:15 LAB ID 22010190304 MW-06-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 CAS# Parameter 124-38-9 Carbon Dioxide AM23G CAS# Parameter 64-19-7 Acetic Acid 64-18-6 Formic Acid 79-09-4 Propionic Acid Result DL LOQ Units 159000 2540 18000 ug/L Result DL LOQ Units 0.58 0.12 0.50 mg/L 5.0 0.055 0.50 mg/L 0.054J 0.053 0.50 mg/L Pace Gulf Coast Report#: 220101903 1 Page 73 of 96 aceAnaly�ical® r Report#: 220101903 Project ID: 0100203 Report Date: 10/29/2020 Summary of Compounds Detected Collect Date 10/13/2020 13:15 LAB ID 22010190304 MW-06-20201013 Receive Date 10/16/2020 12:36 Matrix Water AM20GAX CAS# Parameter Result DL LOQ Units 74-82-8 Methane 140 2.5 5.0 ug/L Collect Date 10/13/2020 10:29 LAB ID 22010190305 MW-03-20201013 (H2) Receive Date 10/16/2020 12:36 Matrix Bubble Strip AM20GAX CAS# Parameter Result DL LOQ Units 1333-74-0 Hydrogen 43 0.49 1.9 nM Collect Date 10/13/2020 13:15 LAB ID 22010190306 MW-06-20201013 (H2) Receive Date 10/16/2020 12:36 Matrix Bubble Strip AM20GAX CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 4.1 0.49 1.9 nM Pace Gulf Coast Report#: 220101903 1 Page 74 of 96 Report#: 220101903 (ac6AnalXical' Project ID: 0100203 Report Date: 10/29/2020 Sample Results Collect Date 10/14/2020 12:00 LAB ID 22010190301 MW-01-20201014 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 20 10/27/202011:57 BMR 695686 CAS# 124-38-9 AM23G Parameter Result DL LOQ Units Carbon Dioxide 128000 2540 18000 ug/L Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/2020 06:51 MOS 695547 CAS# Parameter Result DL 64-19-7 Acetic Acid 0.45J 0.12 107-92-6 Butyric Acid 0.058U 0.058 64-18-6 Formic Acid 5.4 0.055 142-62-1 Hexanoic Acid 0.058U 0.058 646-07-1 i-Hexanoic Acid 0.056U 0.056 503-74-2 i-Pentanoic Acid 0.061 U 0.061 50-21-5 Lactic Acid 0.053U 0.053 109-52-4 Pentanoic Acid 0.056U 0.056 79-09-4 Propionic Acid 0.053U 0.053 127-17-3 Pyruvic Acid 0.060LI 0.060 /_1 L 101IZa—i'VEVI LOQ Units 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L 0.50 mg/L Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/21/202018:28 JCK2 695200 CAS# Parameter Result DL LOQ Units 74-84-0 Ethane 0.075U 0.075 1.0 ug/L 74-85-1 Ethene 0.12U 0.12 1.0 ug/L 74-82-8 Methane 4000 2.5 5.0 ug/L Pace Gulf Coast Report#: 220101903 1 Page 75 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Sample Results Collect Date 10/13/2020 14:50 LAB ID 22010190302 MW-02-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 20 10/27/202012:02 BMR 695686 CAS# 124-38-9 AM23G Parameter Result DL LOQ Units Carbon Dioxide 37100 2540 18000 ug/L Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/2020 07:45 MOS 695547 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.76 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.1 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.053U 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.053J 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/21/202018:40 JCK2 695200 CAS# Parameter Result DL LOQ Units 74-84-0 Ethane 0.075U 0.075 1.0 ug/L 74-85-1 Ethene 0.12U 0.12 1.0 ug/L 74-82-8 Methane 5.0 2.5 5.0 ug/L Pace Gulf Coast Report#: 220101903 1 Page 76 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Sample Results Collect Date 10/13/2020 10:29 LAB ID 22010190303 MW-03-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 5 10/27/202012:17 BMR 695686 CAS# 124-38-9 AM23G Parameter Result DL LOQ Units Carbon Dioxide 14700 635 4500 ug/L Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/2020 08:38 MOS 695547 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.95 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 4.8 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.072J 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.056J 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/21/202018:52 JCK2 695200 CAS# Parameter Result DL LOQ Units 74-84-0 Ethane 0.075U 0.075 1.0 ug/L 74-85-1 Ethene 0.12U 0.12 1.0 ug/L 74-82-8 Methane 3.5,1 2.5 5.0 ug/L Pace Gulf Coast Report#: 220101903 1 Page 77 of 96 Report#: 220101903 ZeAnaly�ical® Project ID: 0100203 Report Date: 10/29/2020 Sample Results Collect Date 10/13/2020 13:15 LAB ID 22010190304 MW-06-20201013 Receive Date 10/16/2020 12:36 Matrix Water EPA RSK-175 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 20 10/27/202012:22 BMR 695686 CAS# 124-38-9 AM23G Parameter Result DL LOQ Units Carbon Dioxide 159000 2540 18000 ug/L Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/2020 09:32 MOS 695547 CAS# Parameter Result DL LOQ Units 64-19-7 Acetic Acid 0.58 0.12 0.50 mg/L 107-92-6 Butyric Acid 0.058U 0.058 0.50 mg/L 64-18-6 Formic Acid 5.0 0.055 0.50 mg/L 142-62-1 Hexanoic Acid 0.058U 0.058 0.50 mg/L 646-07-1 i-Hexanoic Acid 0.056U 0.056 0.50 mg/L 503-74-2 i-Pentanoic Acid 0.061 U 0.061 0.50 mg/L 50-21-5 Lactic Acid 0.053U 0.053 0.50 mg/L 109-52-4 Pentanoic Acid 0.056U 0.056 0.50 mg/L 79-09-4 Propionic Acid 0.054J 0.053 0.50 mg/L 127-17-3 Pyruvic Acid 0.060U 0.060 0.50 mg/L AM20GAX Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/21/202019:04 JCK2 695200 CAS# Parameter Result DL LOQ Units 74-84-0 Ethane 0.075U 0.075 1.0 ug/L 74-85-1 Ethene 0.12U 0.12 1.0 ug/L 74-82-8 Methane 140 2.5 5.0 ug/L Pace Gulf Coast Report#: 220101903 1 Page 78 of 96 aceAnaly�ical® r Report#: 220101903 Project ID: 0100203 Sample Results Report Date: 10/29/2020 Collect Date 10/13/2020 10:29 LAB ID 22010190305 MW-03-20201013 (H2) Receive Date 10/16/2020 12:36 Matrix Bubble Strip At %X Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/202012:27 AWE 695596 CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ 43 0.49 1.9 Collect Date 10/13/2020 13:15 LAB ID 22010190306 MW-06-20201013 (H2) Receive Date 10/16/2020 12:36 Matrix Bubble Strip At \X Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 10/26/202012:39 AWE 695596 CAS# Parameter 1333-74-0 Hydrogen Result DL LOQ Units 4.1 0.49 1.9 nM Pace Gulf Coast Report#: 220101903 1 Page 79 of 96 11!26Analytical r Report#: 220101903 Project ID: 0100203 GC Volatiles QC Summary Report Date: 10/29/2020 Analytical Batch Client ID MB695686 LCS695686 LCSD695686 695686 LAB ID 2102274 2102275 2102276 Sample Type MB LCS LCSD Prep Date Analysis Date 10/27/20 09:35 10/27/20 09:46 10/27/20 09:56 Matrix Water Water Water EPA RSK-175 Units ug/L Spike Result %R I Control Spike Result I %R RPD RPD Result DLI Added Limits%R 1 Added Limit Carbon Dioxide 124-38-9 127U 1 1271 87001 83401 96 1 38 - 147 1 87001 8250 95 1 1 1 40 Pace Gulf Coast Report#: 220101903 1 Page 80 of 96 11!26Analytical Report#: 220101903 Project ID: 0100203 General Chemistry QC Summary Report Date: 10/29/2020 Analytical Batch Client ID MB695547 LCS695547 695547 LAB ID 2101734 2101735 Sample Type MB LCS Prep Date Analysis Date 10/25/20 18:24 10/25/20 17:30 Matrix Water Water AM23G Units mg/L Spike Result %R Control Result DL Added Limits%R Acetic Acid 64-19-7 0.12U 0.12 2.0 1.9 97 70 - 130 Butyric Acid 107-92-6 0.058U 0.058 2.0 2.0 99 70 - 130 Formic Acid 64-18-6 0.055U 0.055 2.0 2.0 98 70 - 130 Hexanoic Acid 142-62-1 0.058U 0.058 2.0 1.9 96 70 - 130 i-Hexanoic Acid 646-07-1 0.056U 0.056 2.0 2.0 98 70 - 130 i-Pentanoic Acid 503-74-2 0.061 U 0.061 2.0 2.0 100 70 - 130 Lactic Acid 50-21-5 0.053U 0.053 2.0 1.9 94 70 - 130 Pentanoic Acid 109-52-4 0.056U 0.056 2.0 1.9 95 70 - 130 Propionic Acid 79-09-4 0.053U 0.053 2.0 2.0 99 70 - 130 Pyruvic Acid 127-17-3 0.060U 0.060 2.0 1.7 85 70 - 130 Pace Gulf Coast Report#: 220101903 1 Page 81 of 96 11!26Analytical Report#: 220101903 Project ID: 0100203 General Chromatography QC Summary Report Date: 10/29/2020 Analytical Batch Client ID MB695596 LCS695596 LCSD695596 695596 LAB ID 2101937 2101938 2101939 Sample Type MB LCS LCSD Prep Date Analysis Date 10/26/20 11:01 10/26/20 11:14 10/26/20 11:26 Matrix AM20GAX Units nM Spike Result I %R I Control I Spike Result %R RPD RPD Result DLI Added Limits%R 1 Added Limit Hydrogen 1333-74-0 0.49U 1 0.491 121 10186 1 70 - 130 1 121 9.9184 1 3 1 20 Analytical Batch Client ID MB695200 LCS695200 LCSD695200 695200 LAB ID 2099339 2099340 2099341 Sample Type MB LCS LCSD Prep Date Analysis Date 10/21/20 15:05 10/21/20 13:42 10/21/20 13:54 Matrix Water Water Water AM20GAX Units ug/L Spike Result %R Control Spike Result %R RPD Result DL Added Limits%R Added Ethane 74-84-0 0.075U 0.075 100 99 98 70 - 130 100 110 109 11 T20 Ethene 74-85-1 0.12U 0.12 140 140 95 70-130 140 150 106 11 Methane 74-82-8 3.2J 2.5 490 460 94 70-130 490 510 104 9 Pace Gulf Coast Report#: 220101903 1 Page 82 of 96 m ,-<<4- r� Client 11): PrismLablSIC - Waypoint Analytical 0 SDG: 220101903 - - Way pNoi nt PM: RWe -7­2 1 1�/ ) 3 V460 SUBCONTRACT ORDER 467 Certification: NELAC USAGE Waypoint Analytical NC x SC_ Other 0100203 SENDING LABORATORY: RECEIVING LABORATORN': Waypoint Analytical Pace Analytical Guif Coast P. C. Box 240543 10781 Coursey Blvd Charlotte, NC 28224-0543 Baton Rouge, LA 70816 Phone: 800-529-6364 Phone :(225) 769-4900 Fax: 704-525-0409 Fax: (225) 767-5717 Project Manager: Angela D. Cvercash Need 5 day TAT Analysis Due Expires Laboratory ID Comments Sample la: 0100203-01 Water S2mpled:10114/20 12:00 11LV-01-20201014 'l Volatile Fatty Acids (Sub) 10/21/20 12:00 Methane. Ethane. Ethene (AM2 10/15/20 12:00 Carbon Dioxide AM20GAX 10/28/20 12:00 Containers Supplied: -7), �oL4P,Iflo-S Sample 10: 0100203-07 Water Sampled:10113120 14:50 MW-02-20201013 Carbon Dioxide AM20GAX 10/27/20 14:50 Volatile Fatty Acids (Sub) 10/20/20 14:50 Methane. Ethane, Ethene (AM2 10/1400 14:50 Containers Supplied, Sample ID: 0100203-09 Water Sampied:10/13/20 10.29 MW-03-20201013 Volatile Fatty Acids {Sub} 10/20/20 10:29 Hydrogen AM20GAX 10/27/20 10:29 Carbon Dioxide AM20GAX 10/27/20 10:29 Methane. Ethane. Ethene (AM2 10/14/20 I0:29 Co tns - Supplied, x Cav,�:-���u {D �S- Date Received By Date By 3 a Date Released By Date Received By Date Released By Date Received By Date Page 1 of 2 0 rl- Page 83 of 96 1 Analysis 0 w SUBCONTRACT ORDER V3 — t U (Lr ] Certification: NELAC USAGE Waypoint Analytical NC SC Other 0100203 Due Expires Laboratory 1D Comments Sample 117: 0100203-09 Water Sampled:10113120 13.15 MW-06-20201013 Volatile Fatty Acids (Sub) 10/20/20 13:15 Methane, Ethane, Ethene (AM2 10/14/20 13:15 Hydrogen AM20GAX 10/27/20 13:15 Carbon Dioxide AM200AX 10/27/20 13:15 Containers Supplied: J CdL' �fk 'l"q ny Released Client ID- PrismLabNC - Waypoint Analytical SDG: 220101903 11 iiiiiiiiiiiiiiiiih i��PM: RWe IIII111111�1I1ill1li )0'IS 2U r-C de Released By Date Received By Date Released By Date Received By Date 3.C) Page 2 of 2 Page 84 of 96 1 2 ❑ ❑ ❑ ❑ ❑ N J U W 2 U Z W U W W J Q 2 7 / ❑ ❑ Q N 0 N rs�l � z ¥ O f k / > 7 � � w 2 / / k = e e 2 q \ § / ƒ / E / E f s / � / f Cl. % % / & a)o k / ( E � 2 / / * s / 2 / ƒ / e § a » & ) _/ ¥ -a/ � \ ƒ E Cl. � E � � e o E / 7 k 7 \ CD kv Ln 2 / 2 % § E / f � / ƒ o / CD CD \ k � � f / U E ƒ % § / U 5 \ � n �k k I § / � g \ \ / 2 Page 85 of 96 1 15C-ta.Analytical WmV.paeelahs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 October 23, 2020 Robbi A. Jones Prism Laboratories, Inc. P.O. Box 240543 Charlotte, NC 28224 RE: Project: 0100203 Pace Project No.: 92500841 Dear Robbi Jones: Enclosed are the analytical results for sample(s) received by the laboratory on October 16, 2020. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Ormond Beach If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Angela Overcash, Prism REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 96 15C-ta.Analytical WmV.paeelahs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: 0100203 Pace Project No.: 92500841 Pace Analytical Services Ormond Beach 8 East Tower Circle, Ormond Beach, FL 32174 Montana Certification #: Cert 0074 Alaska DEC- CS/UST/LUST Nebraska Certification: NE-OS-28-14 Alabama Certification #: 41320 New Hampshire Certification M 2958 Arizona Certification# AZ0819 New Jersey Certification M FL022 Colorado Certification: FL NELAC Reciprocity New York Certification #: 11608 Connecticut Certification #: PH-0216 North Carolina Environmental Certificate #: 667 Delaware Certification: FL NELAC Reciprocity North Carolina Certification #: 12710 Florida Certification #: E83079 North Dakota Certification #: R-216 Georgia Certification #: 955 Ohio DEP 87780 Guam Certification: FL NELAC Reciprocity Oklahoma Certification #: D9947 Hawaii Certification: FL NELAC Reciprocity Pennsylvania Certification #: 68-00547 Illinois Certification #: 200068 Puerto Rico Certification M FL01264 Indiana Certification: FL NELAC Reciprocity South Carolina Certification: #96042001 Kansas Certification #: E-10383 Tennessee Certification #: TN02974 Kentucky Certification #: 90050 Texas Certification: FL NELAC Reciprocity Louisiana Certification #: FL NELAC Reciprocity US Virgin Islands Certification: FL NELAC Reciprocity Louisiana Environmental Certificate M 05007 Virginia Environmental Certification #: 460165 Maryland Certification: #346 West Virginia Certification #: 9962C Michigan Certification #: 9911 Wisconsin Certification #: 399079670 Mississippi Certification: FL NELAC Reciprocity Wyoming (EPA Region 8): FL NELAC Reciprocity Missouri Certification M 236 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 87 of 96 15C-ta.Analytical WmV.paeelabs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: 0100203 Pace Project No.: 92500841 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92500841001 0100203-05 EPA 524.2 JLR 24 PASI-O PASI-O = Pace Analytical Services - Ormond Beach REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 88 of 96 15C-ta.Analytical WmV.paeelabs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: 0100203 Pace Project No.: 92500841 Sample: 0100203-05 Lab ID: 92500841001 Collected: 10/14/20 14:00 Received: 10/16/20 10:05 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Pace Analytical Services - Ormond Beach Benzene ND mg/L 0.00050 1 10/20/20 13:06 71-43-2 Carbon tetrachloride ND mg/L 0.00050 1 10/20/20 13:06 56-23-5 Chlorobenzene ND mg/L 0.00050 1 10/20/20 13:06 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 1 10/20/20 13:06 95-50-1 1,4-Dichlorobenzene ND mg/L 0.00050 1 10/20/20 13:06 106-46-7 1,2-Dichloroethane ND mg/L 0.00050 1 10/20/20 13:06 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 1 10/20/20 13:06 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.00050 1 10/20/20 13:06 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.00050 1 10/20/20 13:06 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 1 10/20/20 13:06 78-87-5 Ethylbenzene ND mg/L 0.00050 1 10/20/20 13:06 100-41-4 Methylene Chloride ND mg/L 0.0010 1 10/20/20 13:06 75-09-2 Styrene ND mg/L 0.00050 1 10/20/20 13:06 100-42-5 Tetrachloroethene ND mg/L 0.00050 1 10/20/20 13:06 127-18-4 Toluene ND mg/L 0.00050 1 10/20/20 13:06 108-88-3 1,2,4-Trichlorobenzene ND mg/L 0.00050 1 10/20/20 13:06 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 1 10/20/20 13:06 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 1 10/20/20 13:06 79-00-5 Trichloroethene ND mg/L 0.00050 1 10/20/20 13:06 79-01-6 Vinyl chloride ND mg/L 0.00050 1 10/20/20 13:06 75-01-4 Xylene (Total) ND mg/L 0.0010 1 10/20/20 13:06 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 10/20/20 13:06 460-00-4 Toluene-d8 (S) 96 % 70-130 1 10/20/20 13:06 2037-26-5 1,2-Dichlorobenzene-d4 (S) 100 % 70-130 1 10/20/20 13:06 2199-69-1 Date: 10/23/2020 05:56 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 89 of 96 15C-ta.Analytical www.pacelahs.l:am Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 0100203 Pace Project No.: 92500841 QC Batch: 674985 Analysis Method: EPA 524.2 QC Batch Method: EPA 524.2 Analysis Description: 524.2 MSV Laboratory: Pace Analytical Services - Ormond Beach Associated Lab Samples: 92500841001 METHOD BLANK: 3671469 Associated Lab Samples: 92500841001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Qualifiers 1,1,1-Trichloroethane mg/L ND 0.00050 10/20/20 11:23 1,1,2-Trichloroethane mg/L ND 0.00050 10/20/20 11:23 1,1-Dichloroethene mg/L ND 0.00050 10/20/20 11:23 1,2,4-Trichlorobenzene mg/L ND 0.00050 10/20/20 11:23 1,2-Dichlorobenzene mg/L ND 0.00050 10/20/20 11:23 1,2-Dichloroethane mg/L ND 0.00050 10/20/20 11:23 1,2-Dichloropropane mg/L ND 0.00050 10/20/20 11:23 1,4-Dichlorobenzene mg/L ND 0.00050 10/20/20 11:23 Benzene mg/L ND 0.00050 10/20/20 11:23 Carbon tetrachloride mg/L ND 0.00050 10/20/20 11:23 Chlorobenzene mg/L ND 0.00050 10/20/20 11:23 cis-1,2-Dichloroethene mg/L ND 0.00050 10/20/20 11:23 Ethylbenzene mg/L ND 0.00050 10/20/20 11:23 Methylene Chloride mg/L ND 0.0010 10/20/20 11:23 Styrene mg/L ND 0.00050 10/20/20 11:23 Tetrachloroethene mg/L ND 0.00050 10/20/20 11:23 Toluene mg/L ND 0.00050 10/20/20 11:23 trans-1,2-Dichloroethene mg/L ND 0.00050 10/20/20 11:23 Trichloroethene mg/L ND 0.00050 10/20/20 11:23 Vinyl chloride mg/L ND 0.00050 10/20/20 11:23 Xylene (Total) mg/L ND 0.0010 10/20/20 11:23 1,2-Dichlorobenzene-d4 (S) % 101 70-130 10/20/20 11:23 4-Bromofluorobenzene (S) % 96 70-130 10/20/20 11:23 Toluene-d8 (S) % 100 70-130 10/20/20 11:23 LABORATORY CONTROL SAMPLE & LCSD: Parameter 3671470 Units Spike Conc. 3671471 LCS LCSD Result Result LCS LCSD % Rec % Rec % Rec Limits RPD Max RPD Qualifiers 1,1,1-Trichloroethane mg/L 0.04 0.035 0.038 86 95 70-130 9 20 1,1,2-Trichloroethane mg/L 0.04 0.036 0.038 90 94 70-130 4 20 1,1-Dichloroethene mg/L 0.04 0.035 0.039 87 98 70-130 12 20 1,2,4-Trichlorobenzene mg/L 0.04 0.036 0.038 91 96 70-130 5 20 1,2-Dichlorobenzene mg/L 0.04 0.035 0.037 88 91 70-130 3 20 1,2-Dichloroethane mg/L 0.04 0.036 0.038 90 95 70-130 6 20 1,2-Dichloropropane mg/L 0.04 0.036 0.037 90 93 70-130 4 20 1,4-Dichlorobenzene mg/L 0.04 0.033 0.034 82 85 70-130 4 20 Benzene mg/L 0.04 0.036 0.039 89 97 70-130 8 20 Carbon tetrachloride mg/L 0.04 0.036 0.040 89 99 70-130 11 20 Chlorobenzene mg/L 0.04 0.035 0.037 88 92 70-130 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2020 05:56 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 96 15C-ta.Analytical www.pacelahs.l:am Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: 0100203 Pace Project No.: 92500841 LABORATORY CONTROL SAMPLE & LCSD: 3671470 3671471 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers cis-1,2-Dichloroethene mg/L 0.04 0.034 0.038 86 96 70-130 11 20 Ethylbenzene mg/L 0.04 0.036 0.038 90 94 70-130 5 20 Methylene Chloride mg/L 0.04 0.034 0.038 86 96 70-130 11 20 Styrene mg/L 0.04 0.036 0.038 91 95 70-130 4 20 Tetrachloroethene mg/L 0.04 0.037 0.038 92 95 70-130 4 20 Toluene mg/L 0.04 0.035 0.036 87 91 70-130 4 20 trans-1,2-Dichloroethene mg/L 0.04 0.034 0.038 86 96 70-130 12 20 Trichloroethene mg/L 0.04 0.035 0.037 89 93 70-130 5 20 Vinyl chloride mg/L 0.04 0.056 0.063 140 158 70-130 12 20 L1 Xylene (Total) mg/L 0.12 0.11 0.11 90 94 70-130 5 20 1,2-Dichlorobenzene-d4 (S) % 101 99 70-130 4-Bromofluorobenzene (S) % 103 102 70-130 Toluene-d8 (S) % 99 103 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2020 05:56 PM without the written consent of Pace Analytical Services, LLC. pari Page 91 of 96 15C-ta.Analytical WmV.paeelahs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: 0100203 Pace Project No.: 92500841 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2020 05:56 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 96 15C-ta.Analytical WmV.paeelabs.eam Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: 0100203 Pace Project No.: 92500841 Lab ID 92500841001 Sample ID 0100203-05 QUALITY CONTROL DATA CROSS REFERENCE TABLE QC Batch Method EPA 524.2 QC Batch Analytical Method 674985 REPORT OF LABORATORY ANALYSIS Analytical Batch This report shall not be reproduced, except in full, Date: 10/23/2020 05:56 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 96 Document Name: Document Revised: February 7, 2013 8ceAnayical Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: f F•CAR-Cs-033-Rev,D6 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ Sample... Client Name:upon Receipt Project #WO# : 92500841 Courier: QFed Ex COPS ❑USPS Client ❑ Commerciai ❑Pace ❑Other: 92500841 f l I1111 1111 1 1 Custody Seal Present? MY s i 71No seats Intact? myes nNo Date/hItlals Person Examining Contents: 1 't Packing Material: Bubble Wrap QBubble Bags ❑None ❑ other Thermometer: 92TO61 Tvpe of Ice: ❑Wet []Blue ❑IR Gun ID: Cooler Temp (°C): ! ( Correction Factor: Add/Subtract (°C) 4.0 Cooler Temp Corrected (°C): USDA Regulated Soil (Q`N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Biological Time Frozen? []Yesf❑No ❑N/A [-]None Temp should be above freezing to VC ❑Samples outof temp criteria, samples on ice, cooling process has begun Did samples originate from a foreign source;IntemationallV, Includln¢ Hawall and Puerto RICO]? FlYes 17No Comments/Discrepancy: Chain of Custody Present? ❑Yes (:]No []NIA 1, Samples Arrived within Nold Timed DYes' ❑No ❑N/A 2, Rush Turn Around Time Requested? ❑Yes ONO ❑NIA 4. Sufficient Volume? ❑Yes . ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? ❑Ye.s ❑Yes []NO []No ❑N/A ❑NIA 6. Containers Intact? Ones []No , ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes Orvo ❑N/A 8. Sample Labels Match CDC? ❑Yes ❑No ❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: r Headspace in VOA Vials (>S-Gmm)? ❑Yes ❑NO ❑N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Des QNo ONo []N/A ❑N/A 11, COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATIONJRESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Lot ID of split containers: Date: Date: Field Data Requ"d? Dyes []NO Page 94 of 96 Document Name: Cocument iieviseci: February 7, 201a Sample Condition ULwn Aecei tISCVFj Page 1 of 2 �acs AnalyUcal Document No.: Issuing Authority: *Check mavk top half of box If pH and/or dechtorination Is verified and within the acceptance range for preservation samples. Esceptlorts: VOA, Collforrn, TOC, Oil and Grease, DRO/9015 (water) DOC, LLMS "Bottom half of box Is to list number of bottle Project A WO# : 925008 1 PM: MW8 Due Date: 10/23/20 CLIENT: 92-Prism :A a z a 2 CL 2 z b yt) r'•a i Z N V V V V a I Q 0 a y y vai i y71 w�� V n N N y `-' Z �R \ C1 .� N N .] U 4 C R C C C U T o Z Q O ,a CL n C E Q Z a ? a } C A Z O a1 C 7 7 Q C N Y Z N 2 3 C U i N S _r a a .+ m m M a ro rl a E 4 EE E n E a W1 N Q d O OR } 4 O > °d v s s a G E a E a E d , i E E J E E a d E Q v 1 .L E > E E E � t: d i � vEi E E E o E N Ln O N r N M ,.., N .+ to ,++ q d 4 q �O !J � m N .�i Q T ~ • � •7i ANT m � 1Ma�� M 1 C1 � Obi 41 pp 'V 6Wa � � l0 m m m m ® m to 1 I 3 4 6 8 L NN NN .�NN -N 9 10 INS. 11 -1 PH Adjustment Log for Preserved Samples Sample 10 Type Of Rratervative pH upon receipt Elate preservation adiusted Time preservation Amount of Preservative Lot k adiwW added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form wilt beient to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, inc orrect containers. Page 95 of 96 IN l� fE'f Waypoint ANALYTICAL SUBCONTRACT ORDER � �1 � 1 71-1 Certification: NELAC_ USACE Waypoint Analytical NC x SC_ Other 0100203 SENDING LABORXFORY: RECEIVING LABORATORY: Waypoint Analytical P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax: 704-525-0409 Project Manager: Angela D. Overcash Pace Analytical, Inc 9800 Kincey Avenue Suite 100 Huntersville, NC 28078 Phone :(704) 875-9092 Fax: (704) 875-9091 Need 5 day TAT Analysis Due Expires Laboratory ID Comments Sample ID: 0100203-05 Water Sampled:10/14/20 14:00 DW-01-20201014 524.2 (Sub) Containers Supplied 10/28/20 14:00 '}mod-(X Released By L 'Date Rec " d By Date Released By Date Received By Date Released By Date Rccci; ed 13c Date Released By Date Received By Date Page 1 of 1 yrrs`rsz`