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HomeMy WebLinkAbout3402_Forsyth_HanesMillRoad_MSWLF_ASDMetals_FID1417685_20200630I pENR USE ONLY ❑Paper Report []Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Golder Associates NC, Inc. on behalf of the Winston-Salem/Forsyth County City/County Utilities Commission Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: David Y. Reedv II. PG Phone: (336) 852 -49 03 E-mail: dreedy@golder.com Facility name: Facility Address: Hanes Mill Road Landfill 325 Hanes Mill Road Winston-Salem, NC 27105 Environmental Status: (Check all that apply) Initial/Background Monitoring O Detection Monitoring e of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data O Surface water monitoring data NC Landfill Rule: Actual sampling dates (e.g., Facility Permit # (.0500 or .1600) October 20-24, 2006) 34-02 .1600 March 2-5, 2020 and May 12. 2020 R Assessment Monitoring Methane gas monitoring data Corrective action data (specify) Other(specify) Q Corrective Action Notification attached? IX No. No groundwater or surface water standards were exceeded. riYes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. David Y. Reedy II, PG Senior Hydrogeologist (336) 852-4903 Facili ive Na 1 Title (Area Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal G -30 - zazc saGcp,•:E. Signature - J-— Date Golder Associates NC, Inc., 5B Oak Branch Drive, Greensboro, NC 27407 Facility Representative Address C-2862 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 GOLDER REPORT Alternate Source Demonstration for Inorganic Constituents Hanes Mill Road Landfill, Permit No. 34-02 Submitted to: Jackie Drummond, Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management - Solid Waste Section 2090 US Highway 70 Swannanoa, North Carolina 28778 828-296-4706 Submitted by: Golder Associates NC, Inc. 5B Oak Branch Drive, Greensboro, North Carolina, USA 27407 +1 336 852-4903 19117535.701 June 30, 2020 June 30, 2020 Distribution List 1F!SfiMMWei Adam Rickett, Senior Project Supervisor, Winston-Salem/Forsyth City/County Utilities Commission, 325 Hanes Mill Road, Winston-Salem, NC 27105. 336-661-4900. adamr@cityofws.org. Gordon Dively, PE, Solid Waste Operations Manager, Winston-Salem/Forsyth City/County Utilities Commission, 325 Hanes Mill Road, Winston-Salem, NC 27105. 336-661-4900. charlesd@cityofws.org. Mike Plummer, PE, HDR, 440 South Church Street, 10th Floor, Charlotte, NC 28202, 704 338 6719. Michael. Plummer@hdrinc.com. (electronic copy) GOLDER June 30, 2020 19117535.701 Executive Summary On behalf of Winston-Salem / Forsyth County Utility Commission (WSFCU), Golder Associates NC, Inc. (Golder) is submitting the following Alternate Source Demonstration (ASD) at the Hanes Mill Road Landfill. This ASD has been prepared as proposed in the Update on Addressing Inorganic Exceedances; Request to Install Additional Background Groundwater Monitoring Wells (Update), which was approved by the North Carolina (NC) Department of Environmental Quality (DEQ) on September 17, 2018. The Update was issued in response to the Request for Additional Information (Request) issued by the North Carolina Department of Environmental Quality (NC DEQ), dated January 18, 2018 to address concentrations of barium and cobalt in the sample from monitoring well OW-3 at the closed unlined landfill; chromium, and cobalt in samples from monitoring wells MW-6, MW-7, and MW-11 at the closed Subtitle D landfill; and cobalt in the sample from monitoring well MW-19 at the active Subtitle D landfill, which were above their respective NC 2L Standards and Solid Waste Section Limits (SWSLs) during the September 2016 compliance monitoring event. The ASD has been prepared in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .1633(C)(3). The following evaluations indicate that the source of above -standard concentrations of constituents -of -concern (COCs) in groundwater samples collected from downgradient monitoring wells at the Hanes Mill Road Landfill are not related to a release from the waste management units at the facility: Barium has been detected in samples from OW-3 at concentrations that are typically more than 2 times higher than the concentrations detected in samples from the facility leachate collection system Chromium has been detected in samples from MW-11 at concentrations that are similar to the concentrations detected in samples from the facility leachate. Chromium has been detected in samples from the background wells at concentrations lower than the concentrations detected in MW-11. Therefore, a mixture of facility leachate and groundwater from the background wells is not likely to produce the concentrations observed in the samples from MW-11. Cobalt has been detected in samples from OW-3, MW-6, MW-7, and MW-19 at concentrations that are similar to or higher than the concentrations detected in samples from the facility leachate. Cobalt has been sporadically detected in samples from the background wells. Therefore, a mixture of facility leachate and groundwater from the background wells is not likely to produce the concentrations observed in the samples from OW-3, MW-6, MW-7, and MW-19. Ternary plots created to evaluate various combinations of cations are inconclusive, showing that the geochemistry of the facility leachate can be similar to wells OW-3, MW-6, and MW-19, but can also be similar to background wells MW-12 and MW-24 Published data indicate that the concentrations of the COCs detected in wells OW-3, MW-6, MW-7, MW-11, and MW-19 are within the range of naturally occurring concentrations in crystalline -rock groundwater in the Piedmont Physiographic Province. Time Series plots and Sen's Slope estimator plots show that all of the COCs show a declining trend in concentrations 4 GOLDER June 30, 2020 19117535.701 Intra-well statistics indicate that concentrations of the COCs at the closed Subtitle D landfill are below calculated background concentrations. Intra-well accounts for the spatial variability of the site. Intra-well statistics was not performed for OW-3 because the closed unlined landfill does not have a liner. Intra-well statistics was not performed for MW-19 at the active Subtitle D landfill because there is not currently enough groundwater analytical data from samples having turbidity of less than 10 Nephelometric Turbidity Units. Soil partitioning calculations using historic soil data indicate that the COCs are present in the facility soils at concentrations capable of generating concentrations in groundwater that has been detected in wells OW-3, MW-6, MW-7, MW-11, and MW-19 Based on the information above, the WSFCU proposes the following actions at the facility: No further action for the groundwater standard exceedances for barium and cobalt at OW-3 at the closed unlined landfill Implement groundwater protection standards (GPS) based on the intra-well statistical calculations as follows: GPS for chromium at MW-11 of 18.9 ug/L GPS for cobalt at MW-6 of 20.0 ug/L GPS for cobalt at MW-7 of 29.9 ug/L Allow additional 3 years to acquire additional cobalt data from MW-19 during routine sampling events to establish a GPS Based on the evaluations and conclusions presented herein, and in the absence of other indicators for a release of solid waste constituents to the uppermost aquifer, the WSFCU requests approval of this ASD and proposes no further actions other than the establishment of a GPS for cobalt at MW-19 at the end of the three-year period. GOLDER June 30, 2020 19117535.701 Table of Contents 1.0 INTRODUCTION.............................................................................................................................................1 1.1 Site Description and Background.........................................................................................................1 1.2 Compliance Monitoring History............................................................................................................1 2.0 HYDROGEOLOGIC SETTING.......................................................................................................................3 3.0 CONSTITUENTS OF CONCERN...................................................................................................................3 3.1 Closed Unlined Landfill........................................................................................................................3 3.1.1 Barium.............................................................................................................................................3 3.1.2 Cobalt..............................................................................................................................................4 3.2 Closed Subtitle D Landfill.....................................................................................................................4 3.2.1 Chromium........................................................................................................................................4 3.2.2 Cobalt..............................................................................................................................................4 3.3 Active Subtitle D Landfill......................................................................................................................5 3.3.1 Cobalt..............................................................................................................................................5 4.0 POTENTIAL SOURCES.................................................................................................................................5 4.1 Evaluation of the Waste Management Unit as a Potential Source......................................................5 4.1.1 Closed Unlined Landfill...................................................................................................................5 4.1.1.1 Evaluation of COCs.....................................................................................................................5 4.1.1.2 Evaluation of non-COCs..............................................................................................................6 4.1.2 Closed Subtitle D Landfill................................................................................................................7 4.1.2.1 Evaluation of COCs.....................................................................................................................7 4.1.2.2 Evaluation of Non-COCs..............................................................................................................7 4.1.3 Active Subtitle D Landfill.................................................................................................................8 4.1.3.1 Evaluation of COCs.....................................................................................................................8 4.1.3.2 Evaluation of Non-COCs..............................................................................................................8 4.1.4 Ternary Plots...................................................................................................................................9 4.2 Evaluation of Naturally Occurring Source..........................................................................................12 4.2.1 Published Data for Constituents of Concern.................................................................................12 ,> GOLDER iv June 30, 2020 19117535.701 4.2.2 Statistical Analysis of Constituents of Concern............................................................................13 4.2.3 Available Facility Soil Data............................................................................................................14 5.0 CONCLUSIONS............................................................................................................................................15 6.0 REFERENCES..............................................................................................................................................16 TABLES Table 1 Summary of Well Construction Information Table 2 Historical Static Water Level Data for the Closed Unlined Landfill Table 3 Historical Static Water Level Data for the Closed Subtitle D Landfill Table 4 Historical Static Water Level Data for the Active Subtitle D Landfill Table 5 Summary of Detected Constituents in Monitoring Wells Table 6 USGS National Geochemical Survey Database Summary Table 7 Summary of Statistical Analysis Table 8 Summary of Detected Constituents in Soil Samples Table 9 Summary of Partitioning Calculations Using Published Partitioning Coefficients FIGURES Figure 1 Ternary Plot of Sodium, Calcium, and Magnesium Figure 2 Ternary Plot of Iron, Calcium, and Sodium Figure 3 Ternary Plot of Iron, Manganese, and Barium Figure 4 Ternary Plot of Iron, Manganese, and Potassium Figure 5 Ternary Plot of Zinc, Cobalt, and Nickel Figure 6 Probability Plots of Groundwater -Quality Data for Siliciclastic-Rock and Crystalline -Rock in the Piedmont and Blue Ridge Physiographic Provinces DRAWINGS Drawing 1 Groundwater Surface Contour Map — March 02, 2020 APPENDICES Appendix A Time Series Plots Appendix B Sen's Slope Estimator Plots Appendix C Laboratory Certificates -of -Analysis Appendix D Statistical Analysis Worksheets 4 GOLDER v June 30, 2020 19117535.701 1.0 INTRODUCTION This report presents an alternate source demonstration (ASD) for detections of select inorganic compounds in compliance groundwater samples in excess of applicable water quality standards at the closed unlined, closed Subtitle D, and active Subtitle D waste management units at the Hanes Mill Road Landfill in Forsyth County (facility). This ASD was prepared on behalf of the Winston-Salem / Forsyth County Utility Commission (WSFCU), in general accordance with the requirements of Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B .1633(C)(3). This ASD has been prepared as proposed in the Update on Addressing Inorganic Exceedances; Request to Install Additional Background Groundwater Monitoring Wells (Update), which was approved by the North Carolina (NC) Department of Environmental Quality (DEQ) on September 17, 2018. The Update was issued in response to the Request for Additional Information (Request) issued by the North Carolina Department of Environmental Quality (NC DEQ), dated January 18, 2018 to address concentrations of barium and cobalt in the sample from monitoring well OW-3 at the closed unlined landfill; chromium, and cobalt in samples from monitoring wells MW-6, MW-7, and MW-11 at the closed Subtitle D landfill; and cobalt in the sample from monitoring well MW-19 at the active Subtitle D landfill, which were above their respective NC 2L Standards and Solid Waste Section Limits (SWSLs) during the September 2016 compliance monitoring event. 1.1 Site Description and Background The location of the facility is shown on the inlay on Drawing 1. As presented, the Hanes Mill Road Landfill is located within the boundaries and jurisdiction of the City of Winston-Salem, NC, off Hanes Mill Road. The WSFCU operates an approximately 500-acre landfill facility that consists of a closed unlined MSW facility, a closed Subtitle D MSW facility, and an active Subtitle D MSW facility. The facility has been in operation since 1972 under Permit Number 34-02. The closed facility operated as an unlined unit until 1995; between 1995 and 2005, the unit operated as a Subtitle D lined unit that `piggy -backed' over the unlined facility. The unlined and `piggy -backed' areas were closed in 2005. The WSFCU currently operates a Subtitle D facility west of the closed unit. The unlined MSW facility is subject to Assessment Monitoring and Corrective Action in accordance with .1634 through .1637 of the Solid Waste Management Rules (SWMR) and the Transition Plan for the facility. The closed Subtitle D facility and the active Subtitle D MSW facility are subject to water quality monitoring in accordance with the Detection Monitoring Program (.1633 of the SWMR). The landfill is bounded to the south by industrial development, to the north, west, and southwest by residential subdivisions and undeveloped wooded properties, and to the east by U.S. 52. Topographic relief at the landfill ranges from approximately 790 to 940 feet above mean sea level. Surface drainage from the facility is predominantly radial toward several streams along the northern and southern portions of the property that flow into Grassy Creek, which transects the property from north to south and separates the closed landfill and the active landfill. Grassy Creek drains into Mill Creek located south of the Hanes Mill Road Landfill. 1.2 Compliance Monitoring History The WSFCU monitors water quality at the closed, unlined MSW facility by monitoring 10 downgradient monitoring wells (OW-3, OW-4, OW-6, OW-71DA, OW-1 OD, OW-11, OW-12, OW-13D, OW-14D, and OW-17D) semi- annually. The upgradient monitoring well and surface water sampling points are shared with the `piggy -backed' closed Subtitle D unit as described below. According to correspondence from NC DEQ dated March 4, 2010, NC Appendix II parameters should be monitored once every two years with the next NC Appendix II event being conducted during the spring 2021 event. During the other semi-annual events, analysis of NC Appendix I plus `detects' is required. Based on the March 4, 2010, correspondence, the NC Appendix II detects include mercury, GOLDER June 30, 2020 19117535.701 tin, dichlorodifluoromethane, and naphthalene. According to correspondence from NC DEQ dated September 22, 2008, approval was granted to reduce the number of, and sampling frequency for, monitored natural attenuation (MNA) parameters and wells to include nitrate, sulfate, chloride, and total organic carbon for wells MW-1 RR, OW-3, OW-4, OW-10D, OW-12, OW-14D, and OW-17D. Every third year (next events in Marchand September 2021), methane, ethane, and ethene must also be analyzed semi-annually for monitored natural attenuation (MNA) wells, and every fifth year (next events in March and September 2021), hydrogen, sulfide, alkalinity, and volatile fatty acids must also be analyzed semi-annually. Based on recent sampling results for the unlined MSW facility, several volatile organic constituents (VOCs) continue to be detected at levels above applicable groundwater standards in samples from one or more monitoring wells. Based on these documented VOC exceedances of applicable groundwater standards, the WSFCU initiated corrective action. The WSFCU monitors water quality at the closed Subtitle D MSW facility by monitoring one upgradient monitoring well (MW-1RR), and six downgradient monitoring wells (MW-6, MW-6D, MW-7, MW-8, MW-9, and MW-11) semi- annually. Due to historical detections of 1, 1 -dichloroethene in MW-8 at concentrations above the groundwater standard, Assessment Monitoring was initiated for this facility and the first complete Assessment Monitoring background event was conducted in October 2009. The March 2011 event was the fourth of four background events for Assessment Monitoring. The background results indicated that no NC Appendix II constituents were detected above applicable groundwater protection standards in the groundwater at the closed, Subtitle D facility, with the exception of chromium, cobalt, and vanadium, which appear to be representative of background conditions. Per NCAC Subchapter 13B Rule.1634(e), the closed Subtitle D facility was to remain in the Assessment Monitoring Program until two consecutive NC Appendix II sampling events indicate that concentrations of all NC Appendix II groundwater concentrations below applicable standards. The September 2012 event was the second of these events; the results indicated that no Appendix II constituents were above background. Therefore, the closed Subtitle D facility reverted to the Detection Monitoring Program. Two upstream surface water monitoring points (NBC-1 and SW-3) and two downstream monitoring points (NBC-2 and SW-4) are used to monitor both of the closed units and are sampled semi-annually for analysis of NC Appendix I parameters. The WSFCU monitors water quality at the active Subtitle D facility by testing one upgradient monitoring well (MW-12), and seven downgradient monitoring wells (MW-13, MW-14, MW-15, MW-16, MW-17, MW-18, MW-19) semi-annually. Three former piezometers converted to monitoring wells (MW-20, MW-21, and MW-22) were added to the monitoring network as part of the Cell 3/4 expansion. Two surface water points (upstream point SW-1 and downstream point SW-2) are used to monitor the active facility. Samples from the wells and surface water monitoring points are analyzed for NC Appendix I VOCs. A composite leachate sample is collected semi- annually from the two leachate holding tanks for both lined units and analyzed for the approved NC leachate parameter list plus other required parameters. On November 3, 2016, Golder submitted the 14-Day Notification and Alternate Source Demonstration to the NC DEQ to address concentrations of barium and cobalt in the sample from monitoring well OW-3 at the closed unlined landfill; arsenic, chromium, and cobalt in samples from monitoring wells MW-6, MW-7, and MW-11 at the closed Subtitle D landfill; and cobalt in the sample from monitoring well MW-19 at the active Subtitle D landfill, which were above their respective NC 2L Standards and SWSLs during the September 2016. The NC DEQ responded with a Request forAdditional Information dated January 18, 2018, which was provided May 21, 2018, as Response to Alternate Source Demonstration -Request for Additional Information. Based on a follow up letter GOLDER June 30, 2020 19117535.701 from the NC DEQ dated June 8, 2018, two additional background wells (MW-23 and MW-24) were installed in November 2018 to collect additional analytical data over a two-year period to evaluate background concentrations of inorganic constituents at the closed unlined landfill, closed Subtitle D landfill, and the active Subtitle D landfill. A summary table of available well construction details is provided as Table 1. 2.0 HYDROGEOLOGIC SETTING Geologically, the facility is located within the Carolina Slate Belt of the central Piedmont Physiographic Province of North Carolina (NCGS, 1985 and 2004). The Carolina Slate Belt is comprised of late Proterozoic to Cambrian volcanic and sedimentary rocks that have been metamorphosed to lower greenschist facies by plutons (Butler and Secor, 1991). The facility is underlain primarily by the Ashe Formation, which consists of fine grained, thinly layered sulfidic biotite-muscovite gneiss interlayered with mica schist and phyllite. The Ashe Formation also consists of amphibolite and garnet amphibolite (HDR, 2003). The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, metamorphic intrusive rock. Groundwater occurs at depths ranging from approximately 3 to 62 feet below grade. Depth -to -water measurements obtained during the March 2020 monitoring event are summarized in Tables 2 through 4 and were used to prepare a groundwater surface contour map presented as an overlay on Drawing 1 As presented, the groundwater flow in the uppermost aquifer beneath the closed landfills is generally toward the southwest toward Grassy Creek, which separates the closed facility from the active facility. Groundwater flow in the uppermost aquifer beneath the active landfill is semi -radial, flowing primarily east toward Grassy Creek, but also north and south to tributaries of Grassy Creek. The groundwater contour map and interpreted flow directions are generally consistent with previously submitted groundwater contour maps and flow directions. The calculated hydraulic gradients and rates of groundwater flow are presented in the First Semi -Annual 2020 Water Quality Monitoring Event Report (Golder, 2020). 3.0 CONSTITUENTS OF CONCERN Based on the January 18, 2018, Request from the NC DEQ, the constituents of concern (COCs) include barium and cobalt in the sample from monitoring well OW-3 at the closed unlined landfill; chromium in samples from MW-11 and cobalt in samples from monitoring wells MW-6 and MW-7 at the closed Subtitle D landfill; and cobalt in the sample from monitoring well MW-19 at the active Subtitle D landfill, which were above their respective NC 2L Standards and SWSLs during the September 2016 compliance monitoring event. Analytical results for the COCs in groundwater samples are summarized in Table 5 with available historical data. The COCs for each landfill are discussed further in the following sections. 3.1 Closed Unlined Landfill 3.1.1 Barium As presented in Table 4, barium has been detected in the samples from OW-3 at concentrations above the laboratory practical quantification limit (PQL) and NC 2L Standard consistently since 2006. Barium concentrations have generally shown a declining trend in samples from OW-3. Similarly, barium has been detected in each of the closed unlined compliance wells, including background wells MW-1 RR, MW-12, MW-23, and MW-24. A time series plot of barium concentrations from the OW-3, the facility background wells, and facility leachate is included in Appendix A. The time series plot shows the visually declining concentrations of barium in the samples from OW-3. The visual declining trend is reinforced by a statistical trend analysis using Sen's Slope estimator for 4 GOLDER June 30, 2020 19117535.701 barium concentrations in samples from OW-3 in Appendix B, which indicates a significant decreasing trend. Table 5 and the barium time series plot also show that the concentrations of barium in the samples from OW-3 are typically two times higher than the concentrations detected in the samples from the facility leachate. 3.1.2 Cobalt As presented in Table 5, cobalt has been detected in the samples from OW-3 at concentrations above the PQL and NC 2L Standard consistently since 2006. Cobalt was detected at an estimated concentration below the PQL, but above the NC 2L Standard in the sample from OW-3 during the most recent sampling event in March 2020. Cobalt has been sporadically detected at background wells MW-1 RR, MW-12, and MW-24. A time series plot of cobalt concentrations from OW-3, MW-6, MW-19, the facility background wells, and facility leachate is included in Appendix A. The cobalt time series plot in Appendix A shows the visually declining concentrations of cobalt in samples from OW-3. The visually declining trend is reinforced by a statistical trend analysis using Sen's Slope estimator for cobalt concentrations in samples from OW-3 in Appendix B, which indicates a significant decreasing trend. In general, Table 5 and the cobalt time series plot show that the concentrations of cobalt in the samples from OW-3 are typically higher than the concentrations detected in the samples from the facility leachate. 3.2 Closed Subtitle D Landfill 3.2.1 Chromium As presented in Table 5, chromium has been detected in the samples from MW-11 at concentrations above the PQL and NC 2L Standard consistently since the baseline sampling was performed in 1997. In fact, the highest chromium concentration historically detected at MW-11 was before waste disposal, providing strong evidence that the historical concentrations are unrelated to a release from the closed Subtitle D landfill. Chromium has been detected in each of the closed Subtitle D compliance wells and background wells MW-1 RR, MW-12, MW-23, and MW-24. A time series plot of chromium concentrations from MW-11, the facility background wells, and facility leachate is included in Appendix A. The time series plot shows the visually declining concentrations of chromium in the samples from MW-11. The visually declining trend is reinforced by a statistical trend analysis using Sen's Slope estimator for chromium concentrations in samples from MW-11 in Appendix B, which indicates a decreasing trend. In general, Table 5 and the chromium time series plot show that the concentrations in the samples from MW-11 are similar to the concentration detected from the facility leachate. 3.2.2 Cobalt As presented in Table 5, cobalt has been detected in the samples from MW-6 at concentrations above the SWSL and NC 2L Standard consistently since the baseline sampling was performed in 1997. In fact, the highest cobalt concentration historically detected at MW-6 was pre -waste disposal, providing strong evidence that the historical concentrations are unrelated to a release from the closed Subtitle D landfill. Concentrations have generally shown a declining trend since the initial baseline event. Cobalt has also been detected in the samples from MW-7 at concentrations above the NC 2L Standard consistently since the baseline sampling was performed in 1997. The concentrations have fluctuated above and below the PQL. Similar to MW-6, the highest cobalt concentration historically detected at MW-7 was pre -waste disposal, also providing strong evidence that the historical concentrations are unrelated to a release from the closed Subtitle D landfill. Cobalt has been detected in all of the closed Subtitle D compliance wells and background wells MW-1 RR, MW-12, MW-23, and MW-24. The time series plot of cobalt in Appendix A shows the visually declining concentrations of cobalt in the samples from MW-6 and MW-7. The visually declining trend is reinforced by a statistical trend analysis using Sen's Slope estimator for cobalt concentrations in samples from MW-6 and MW-7 in Appendix B, which indicate decreasing trends. In 4 GOLDER 4 June 30, 2020 19117535.701 general, Table 5 and the cobalt time series plot show that the concentrations of cobalt in the samples from MW-6 are typically higher than the concentrations detected in the samples from the facility leachate and the samples from MW-7 are typically similar to the concentrations detected in the samples from the facility leachate. 3.3 Active Subtitle D Landfill 3.3.1 Cobalt As presented in Table 5, cobalt has been detected in the samples from MW-19 at concentrations above the PQL and NC 2L Standard consistently since 2008. Cobalt has been detected in samples from each of the facility monitoring wells except MW-20. The time series plot in Appendix A shows the visually declining concentrations of cobalt in samples from MW-19. The visually declining trend is reinforced by a statistical trend analysis using Sen's Slope estimator for cobalt concentrations in samples from MW-19 in Appendix B, which indicates a decreasing trend. In general, Table 5 and the cobalt time series plot show that the concentrations of cobalt in the samples from MW-19 are typically higher than the concentrations detected in the samples from the facility leachate. 4.0 POTENTIAL SOURCES The purpose of this ASD is to evaluate whether a source other than the waste management units is responsible for the exceedances of applicable groundwater standards in samples from downgradient monitoring wells as discussed in Section 3.0. Review of the facility operations and geologic setting identified the following hypothetical sources, to be evaluated herein, for the elevated inorganic constituent concentrations reported in groundwater samples collected from facility monitoring wells: The waste management units (i.e., a release from the waste management unit to the uppermost aquifer and subsurface transport of leachate to the areas where downgradient wells are located) Metals concentrations in naturally occurring soils and bedrock (i.e., dissolution and/or partitioning of metals from native soils and/or engineered placed materials to groundwater) These potential sources are further evaluated in the following sections. Evaluation of the Waste Management Unit as a Potential Source Based on a review of recent potentiometric surface data for the facility (Drawing 1) and the positioning of the monitoring wells near the downgradient extent of landfill cells, it is feasible that a release of solid waste constituents to groundwater could impact groundwater quality at downgradient monitoring wells. The closed unlined landfill is not constructed with a leachate collection system and a representative leachate sample could not be obtained; therefore, analytical data for composite leachate samples from the closed Subtitle D and active Subtitle D landfills were used to represent the character of the waste management units as a potential source of COC exceedances. A comparison of recent COC concentrations from recent samples from facility leachate, background wells, and downgradient wells with groundwater standard exceedances is presented in the following sections and summarized on Table 5 and the time series plots in Appendix A. 4.1.1 Closed Unlined Landfill 4.1.1.1 Evaluation of COCs Barium has typically been reported at a higher concentration in representative leachate samples than in samples from background monitoring wells. However, the concentrations of barium in downgradient groundwater samples 4 GOLDER June 30, 2020 19117535.701 from well OW-3 are typically twice the concentrations in samples from the facility leachate. Though mixing models could not be performed due to missing cations and anions, there would be no conceptual scenario in which the mixing of groundwater from the background wells and the facility leachate could produce concentrations higher than those observed in the facility leachate, as is the case with OW-3. Cobalt has historically been detected at higher concentrations in downgradient groundwater samples from OW-3 than samples from the representative leachate. More recently, the concentrations have been similar in samples from the facility leachate and OW-3. Cobalt has only sporadically been detected in the samples from the background wells and the concentrations have been less than those observed in samples from OW-3 and the facility leachate. Similar to barium, the concentrations of cobalt observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from OW-3. 4.1.1.2 Evaluation of non-COCs Comparisons of other inorganic constituents are provided below, though they are not COCs for this investigation. The comparisons of these constituents in the samples from OW-3, representative leachate, and the background wells may show trends to determine if OW-3 has been impacted by facility leachate. Antimony has consistently been detected in samples from the facility leachate since 1994, but has not been detected in the background wells or downgradient well OW-3 since 2016. The lack of downgradient antimony detections could indicate that water quality at OW-3 is not being influenced by the facility leachate. Chromium has historically been detected in the samples from downgradient well OW-3 at estimated concentrations, but has not been detected during the last three sampling events. Chromium has been detected at higher concentrations at primarily estimated concentrations in background wells MW-23 and MW-24. The detections of chromium in the samples from the facility leachate have been at quantifiable concentrations that have exceeded the concentration observed in OW-3 and the background wells. This comparison indicates that a mixing of groundwater from the background wells and facility leachate may be possible to generate the chromium concentrations observed in OW-3 Nickel has consistently been detected in samples from the representative leachate at concentrations higher than the background wells and OW-3. Nickel has only been sporadically detected in samples from background wells MW-1 RR and MW-24, but have consistently been detected in samples from MW-23 at concentrations lower than observed in samples from OW-3 and the facility leachate. This comparison indicates that a mixing of groundwater from the background wells and facility leachate may be possible to generate the nickel concentrations observed in OW-3. Thallium as been routinely detected in samples from OW-3 until the last four sampling events. Thallium has sporadically been detected in the representative leachate and the background wells. This comparison indicates that the thallium concentrations in the samples from OW-3 are likely naturally occurring. Vanadium has consistently been detected in the samples from the representative leachate and have been detected at lower concentrations in the background wells. Vanadium has not been detected in the samples from OW-3 since 2011. This could indicate that water quality at OW-3 is not being influenced by the facility leachate. Lastly, iron and manganese were analyzed from the June 2020 sampling event for the samples from the background wells, facility leachate, and OW-3, as part of this investigation (Appendix C). The concentrations of iron and manganese from the sample for OW-3 were higher than their respective concentrations from the sample of facility leachate and the background wells. The concentrations of iron and manganese observed in the 4 GOLDER June 30, 2020 19117535.701 background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from OW-3. In general, the collective findings presented above do not support a leachate impact as the source of the concentrations of barium and cobalt observed in OW-3. 4.1.2 Closed Subtitle D Landfill 4.1.2.1 Evaluation of COCs Chromium has typically been reported at a similar concentration in the samples from the facility leachate and background well MW-24. The facility leachate concentrations are typically higher than the concentrations from samples from background wells MW-1 RR, MW-12, and MW-23. The concentrations from MW-11 are similar to the concentrations from samples from the facility leachate and background well MW-24. The concentrations of chromium observed in background well MW-24 and the facility leachate could produce the concentrations detected in the samples from MW-11. The concentrations of chromium observed in background wells MW-1 RR, MW-12, MW-23 and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-11. It should be noted that wells MW-1 RR and MW-23 are located upgradient of the closed Subtitle D landfill and MW-11 and are more likely to represent the water quality that would be mixed with the facility leachate. The concentrations of chromium in the samples from MW-6 and MW-7 are similar to the concentrations observed in the samples from the background wells and lower than the concentration detected in the samples from the facility leachate. The concentrations of chromium observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-6 and MW-7. Cobalt has historically been detected at higher concentrations in samples from MW-6 than samples from the facility leachate. More recently, the concentrations have been similar in samples from the facility leachate and MW-6. Cobalt has historically been similar in concentration in samples from MW-7 and the facility leachate, which has continued to be the case. Cobalt has only sporadically been detected in the samples from the background wells and the concentrations have been less than those observed in samples from OW-3 and the facility leachate. The concentrations of cobalt observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-6 and MW-7. 4.1.2.2 Evaluation of Non-COCs Comparisons of other inorganic constituents are provided below, though they are not COCs for this investigation. Antimony has consistently been detected in samples from the facility leachate since 1994, but has not been detected in the background wells or the downgradient wells MW-6 and MW-7 since 2016. This could indicate that water quality at MW-6 and MW-7 is not being influenced by the facility leachate. Barium has typically been reported at higher concentrations in facility leachate samples than in samples from background monitoring wells. The concentrations of barium in samples from MW-6 are typically similar to higher than the concentrations in samples from the facility leachate. The concentrations of barium in samples from MW-7 and MW-11 are lower than the concentrations in samples from the facility leachate. The concentrations of barium observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-6, but may be able to produce concentrations detected in the samples from MW-7 and MW-11. 4 GOLDER June 30, 2020 19117535.701 Beryllium has consistently been detected at estimated concentrations in samples from well MW-7, but has only been sporadically detected in samples from the background wells, facility leachate, MW-7, and MW-11. The concentrations of beryllium observed in the background wells and the facility leachate could not produce the concentrations detected in the samples from MW-7. Nickel has consistently been detected in samples from the facility leachate at concentrations higher than the background wells and downgradient wells MW-6, MW-7, and MW-11. Well MW-6 has historically been non -detect for nickel and MW-7 has had sporadic detections. Nickel has routinely been detected in samples from MW-11 at concentration lower than those in samples from the facility leachate. This comparison indicates that a mixing of groundwater from the background wells and facility leachate to generate the nickel concentrations observed in in samples from MW-7 and MW-11 may be possible. Vanadium has consistently been detected in the samples from the facility leachate and have been detected at lower concentrations in the background wells. Recently, vanadium has not been detected in the samples from MW-6, MW-7, and MW-11. This could indicate that water quality at MW-6, MW-7, and MW-11 is not being influenced by the facility leachate. Lastly, iron and manganese were analyzed from the June 2020 sampling event for the samples from the background wells, facility leachate, and the downgradient wells MW-6 and MW-11, as part of this investigation (Appendix C). The concentrations of iron and manganese in the sample from MW-6 were higher than the respective concentrations from the sample of facility leachate. The concentrations of iron and manganese in the sample from MW-11 and the background wells were lower than the concentration in the sample from the facility leachate. The concentrations of iron and manganese observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-6, but could conceptually produce the concentrations in the samples from MW-11. In general, the collective findings presented above do not support a leachate impact as the source of the concentrations of chromium observed in the samples collected from MW-11 and cobalt observed in the samples collected from MW-6 and MW-7. 4.1.3 Active Subtitle D Landfill 4.1.3.1 Evaluation of COCs Cobalt has historically been detected at higher concentrations in samples from MW-19 than samples from the facility leachate. Cobalt has only sporadically been detected in the samples from the background wells and the concentrations have been less than those observed in samples from MW-19 and the facility leachate. The concentrations of cobalt observed in the background wells and the facility leachate could not conceptually produce the concentrations detected in the samples from MW-19. 4.1.3.2 Evaluation of Non-COCs Comparisons of other inorganic constituents are provided below, though they are not COCs for this investigation Antimony has consistently been detected in samples from the facility leachate since 1994, but has not been detected in the background wells since 2016 and has not been detected in the samples from MW-19 since 2009 This could indicate that water quality at MW-19 is not being influenced by the facility leachate. Barium has typically been reported at a higher concentration in facility leachate samples than in samples from background monitoring wells and MW-19. The concentrations of barium in samples from well MW-19 are similar to the concentrations in samples from the background wells. This comparison indicates that a mixing of 4 GOLDER June 30, 2020 19117535.701 groundwater from the background wells and facility leachate may be possible to generate the barium concentrations observed in MW-19. Chromium has sporadically been detected in the samples from MW-19 at estimated concentrations, but has not been detected during the last six sampling events. Chromium has been detected at higher concentrations at primarily estimated concentrations in background wells MW-23 and MW-24. The detections of chromium in the samples from the facility leachate have been at quantifiable concentrations that have exceeded the concentration observed in MW-19 and the background wells. This could indicate that water quality at MW-19 is not being influenced by the facility leachate. Nickel has consistently been detected in samples from the facility leachate at concentrations higher than the background wells and MW-19. The concentrations of nickel in the samples from MW-19 are similar to the concentrations detected in background well MW-23. This comparison indicates that a mixing of groundwater from the background wells and facility leachate may be possible to generate the nickel concentrations observed in MW-19. Vanadium has consistently been detected in the samples from the facility leachate and have been detected at lower concentrations in the background wells. Recently, vanadium has historically been detected in samples from MW-19 at concentrations similar to the background wells, but has not been detected in the samples from MW-19 during the last three sampling events. These recent events could indicate that water quality at MW-19 is not being influenced by the facility leachate. Lastly, iron and manganese were analyzed from the June 2020 sampling event for the samples from the background wells, facility leachate, and the MW-19, as part of this investigation (Appendix C). The concentrations of iron from samples MW-19 were higher than the concentrations from the sample of facility leachate and the background wells. This comparison indicates that a mixing of groundwater from the background wells and facility leachate may be possible to generate the iron concentrations observed in MW-19. The concentration of manganese in samples from MW-19 was lower than the concentration from the facility leachate, but higher than the concentration from the background wells. Due to the similarity in concentration of manganese in the samples from MW-19 and the facility leachate, it is unlikely that water quality at MW-19 is being impacted by the facility leachate. In general, the collective findings presented above does not support a leachate impact as the source of the concentrations of cobalt observed in MW-19. 4.1.4 Ternary Plots A ternary plot is a barycentric plot on three variables which sum to a constant and graphically depicts the ratios of three variables as positions in an equilateral triangle. To evaluate landfill leachate as a potential source of barium in samples from OW-3, chromium in samples from MW-11, and cobalt in samples from OW-3, MW-6, and MW-19, Golder prepared a series of ternary plots of various cations to illustrate the variability in the geochemistry of the water from the wells of interest, the background wells, and the facility leachate. The first plot evaluates sodium, magnesium, and calcium on Figure 1 below. The plot shows that the sample from MW-6 plots near to the sample from background well MW-1 RR. The sample from MW-19 blots between background wells MW-1 RR and MW-12. The sample from MW-11 plots near to background wells MW-23 and MW-24. The sample from OW-3 plots near the facility leachate sample, but shows a lower percentage of sodium. GOLDER June 30, 2020 Figure 1: Ternary plot of sodium, calcium, and magnesium O Mw-1RR O MW-12 MW-23 p 60 MW-24 0 OW-3 MW-1RR NW- a MW-6 % VW-11 fi MW_19 60 Mtn 19 o p ' Leachate P y0 TO, < Na' qq megn 19117535.701 The second plot evaluates iron, sodium, and calcium on Figure 2 below. The plot shows that the sample from MW-11 plots near to the sample from background well MW-1 RR. The sample from OW-3 once again plots near the facility leachate sample, but has a lower percentage of iron and a higher percentage of sodium. Samples from MW-6 and MW-19 each plot individually and show no relation to the background wells or the facility leachate. Figure 2: Ternary plot of iron, calcium, and sodium MW-IRR 0 MW-12 A MW-23 V MW-24 0 ow-3 ° MW-6 % MW-11 MW-19 • Leachate - Fe" % me(In The third plot evaluates iron, manganese, and barium on Figure 3. The plot shows that samples from MW-6 and MW-19 plot near to the facility leachate sample with higher percentages of iron and lower percentages of manganese. The sample from OW-3 plots by itself with the sample from background well MW-12 plotting between OW-3 and the facility leachate. The sample from MW-11 plots by itself with the sample from background well MW-24 plotting between MW-11 and the facility leachate. 4 GOLDER 10 June 30, 2020 Figure 3: Ternary plot of iron, manganese, and barium M MW_11 " MW_24 F `So vo d Fe" % megI G MW-1RR O MW-12 MW-23 0 MW-24 O OW-3 ° MW-6 % MW-11 MW-19 ■ Leachale 19117535.701 The fourth plot evaluates iron, manganese, and potassium on Figure 4 below. The plot shows background wells MW-12 and MW-24 plotting in close proximity to the facility leachate sample. The sample from MW-11 plots between background wells MW-1 RR and MW-23. Wells MW-6 and MW-19 plot close to one another with higher percentages of iron than the facility leachate sample. The sample from OW-3 plots by itself with higher percentages of iron and manganese and a lower percentage of potassium than the facility leachate sample. The sample from background well MW-12 plots between OW-3 and the facility leachate. Figure 4: Ternary plot of iron, manganese, and potassium 13 MW-1RR O MW-12 MW-23 MW-24 4 OW-3 o MW-6 H MW-11 MW-19 ■ Leaahale Fe'* % megll The fifth plot evaluates zinc, cobalt, and nickel on Figure 5 below. The sample from MW-11 plots close to background well MW-23. Samples from OW-3, MW-6, and MW19 plot individually and away from the facility leachate. Background wells MW-1 RR and MW-12 were non -detect for all three cations and are not plotted. GOLDER 11 June 30, 2020 19117535.701 Figure 5: Ternary plot of zinc, cobalt, and nickel it ' MVV-23 I MW-24 OW-3 8 ° MW-6 80 8 MW-1A MW-19 E LCiC11aAe 60 140�Z 2 Lea "Me i MW 4 PAW_23AV-11 r q6 �C E Zn" — % megn The results of the ternary plots are generally inconclusive. The plots on Figures 1 and 2 indicate that the sample from OW-3 has a similar geochemistry as the facility leachate, but plots on Figures 3, 4, and 5 do not indicate a similar geochemistry. Figure 3 indicates that the samples from MW-6 and MW-19 have a similar geochemistry as the facility leachate, but that is not confirmed on the plots on Figures 1, 2, 4, and 5. Figure 4 indicates that the samples from background wells MW-12 and MW-24 are most similar to the facility leachate and Figure 5 shows no similarities to the facility leachate and the samples from the background and downgradient wells. 4.2 Evaluation of Naturally Occurring Source The concentrations of barium in samples from OW-3, chromium in samples from MW-11, and cobalt in samples from OW-3, MW-6, MW-7, and MW-19 may be from natural sources such as non -impacted groundwater upstream of the wells of interest that have leached the inorganic constituents from soil and bedrock. In order to evaluate a natural source, published water quality data was researched and statistical analysis of facility water quality data was performed. 4.2.1 Published Data for Constituents of Concern Available published reports indicate that the COCs are found to be naturally occurring at concentrations similar to the detections in the downgradient wells of interest at the Hanes Mill Road Landfill. Probability plots of groundwater quality in Naturally Occurring Contaminants in the Piedmont and Blue Ridge Crystalline -Rock Aquifers and Piedmont Early Mesozoic Basin Siliciclastic-Rock Aquifers, Eastern United States, 1994-2008 were evaluated for the COCs (Chapman, 2013). The probability chart for barium shows that concentrations similar to those in samples from OW-3(-1000 ug/L) are expected to be exceeded in approximately ninety-five percent of the samples in crystalline -rock aquifers. The probability chart for chromium shows that concentrations similar to those in samples from MW-11(-10 ug/L) are expected to be exceeded in approximately fifty percent of the samples in crystalline -rock aquifers. The probability chart for cobalt shows that concentrations similar to those in samples from OW-3, MW-6, MW-7, and MW-19 (-20 ug/L) are expected to be exceeded in approximately forty percent of the samples in crystalline -rock aquifers. 4 GOLDER 12 June 30, 2020 19117535.701 Figure 6: Probability plots of groundwater -quality data for siliciclastic-rock and crystalline -rock in the Piedmont and Blue Ridge Physiographic Provinces (Chapman, 2013) EXPLANATION Crystalline siliciclastic 2,11M 1,000 5oa E 100 50 E E 10 m EXPLANATION Crystalline -` -�.— Silicinlastic 100 50 10 E 5 E 1 c� 05 t EXPLANATION Crystalline siliciclastic U.5 I 0 05 1.0 Frequency concentration was exceeded The United States Geological Survey (USGS) National Geochemical Survey Database was researched for the COCs. Twelve sediment samples collected within 20 miles of the Hanes Mill Road Landfill were present and the results are included as Table 6. As shown, barium concentrations range from 65 ppm to 2630 ppm. Chromium concentrations range from 3 ppm to 79 ppm and cobalt concentrations range from non -detect to 36 ppm. While a direct comparison between sediment sample concentrations and groundwater concentrations cannot be made, these data show that the aforementioned inorganic constituents do occur naturally in stream sediment. Therefore, they are likely to occur in subsurface soil at the Hanes Mill Road Landfill at concentrations that would account for the concentrations of these constituents in groundwater. 4.2.2 Statistical Analysis of Constituents of Concern The Summary of Statistical Analysis (Table 7) summarizes the statistical methods and results used to determine an appropriate background concentration for inorganic compounds detected at concentrations above the PQLs and NC 2L Standards or Interim Maximum Concentration (IMAC) in samples from downgradient monitoring wells at the closed unlined landfill, closed Subtitle D landfill, and active Subtitle D landfill during recent sampling events. The statistical analyses were completed using WQStat software in accordance with 40 CFR 258 and Title 15A NCAC 13B .1632(f) through (h). Per NC DEQ guidance, only samples that were collected with turbidity values of less than 10 Nephelometric Turbidity Units (NTU) were used in statistical analysis. The statistical summary sheets generated during the statistical analysis are included as Appendix D. Historical analytical data for barium, chromium, and cobalt from upgradient wells MW-1 RR, MW-12, MW-23, and MW-24 were used to perform inter -well statistics. These data were used to establish background concentrations for barium, chromium, and cobalt at the closed unlined landfill, closed Subtitle D, and active Subtitle D landfill. The inter -well background statistical limits for barium and chromium were based on upper parametric prediction limits and cobalt was based on the non -parametric prediction limit as allowed under Title 15A NCAC 13B .1632 (g)(3). The barium concentration in the sample from OW-3; the chromium concentration in the sample from MW-11; and the cobalt concentrations in the samples from OW-3, MW-6, MW-7, and MW-19 from the June 2020 sampling event were above the background concentrations calculated by inter -well statistical methods. It should be noted that pre -waste analytical data, which are higher than the current concentrations from the wells listed above, were not used in inter -well statistical analyses because turbidity values are not available for those results. .4li GOLDER 13 June 30, 2020 19117535.701 Inter -well statistics does not account for spatial variability of the aquifer. Intra-well statistics is a method to account for spatial variability per the Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Unified Guidance (EPA, 2009). The data sets utilized for intra-well statistics show downward concentration trends, which supports the use of this statistical method. As with the inter -well statistics, pre -waste analytical data were not used in intra-well statistical analyses because turbidity values are not available for those results. Intra- well statistics was not utilized for OW-3 since the closed unlined landfill is an unlined facility. However, the Sen's Slope estimator was utilized to evaluate the concentration trends of the COCs from OW-3 (Appendix B). The Sen's Slope estimator for barium and cobalt concentrations at OW-3 indicate significant downward trends of both constituents. Intra-well statistics was utilized for the chromium concentrations at MW-11 and cobalt concentrations at MW-6 and MW-7 at the closed Subtitle D landfill. The intra-well background statistical limits for chromium at MW-11 and cobalt at MW-6 and MW-7 were based on upper parametric prediction limits as allowed under Title 15A NCAC 13B .1632 (g)(3). The March 2020 concentrations for chromium at MW-11 and cobalt at MW-6 and MW-7 were determined to be below statistically determined background values. The Sen's Slope estimator was utilized to evaluate the concentration trends of chromium at MW-11 and cobalt at MW-6 and MW-7 (Appendix B). The Sen's Slope estimator for chromium at MW-11 and cobalt at MW-6 indicate significant downward trends. The Sen's Slope estimator for cobalt at MW-7 indicates downward trend in concentrations, but was determined to be statistically insignificant. Based on the intra-well statistical analysis included as Appendix D, the following well -specific groundwater protection standards (GPS) are proposed: GPS for chromium at MW 11 of 18.9 ug/L GPS for cobalt at MW 6 of 20.0 ug/L GPS for cobalt at MW 7 of 29.9 ug/L Intra-well statistics was not utilized for MW-19 at the active Subtitle D landfill because there was an insufficient amount of data for statistical evaluation from samples with turbidity values less than 10 NTU. However, the Sen's Slope estimator was utilized to evaluate the concentration trends of cobalt from MW-19 (Appendix B). The Sen's Slope Estimator for cobalt concentrations at MW-19 indicate significant downward trend; though, as stated, an insufficient amount of data is present to statistically evaluate the data. 4.2.3 Available Facility Soil Data Over the years, shallow soil samples have been collected at the Hanes Mill Road Landfill as part of various investigations. Analytical results of the COCs from soil samples that were initially collected to provide background concentrations are summarized as Table 8. The locations of the soil samples are shown on Drawing 1. The soil sample results show barium concentrations ranging from 66.1 to 148 milligrams per kilogram (mg/kg/dry), chromium concentrations ranging from 37.1 to 49.2 mg/kg/dry, and cobalt concentrations ranging from 5.26 to 15.7 mg/kg/dry. It should be noted that all of the cobalt concentrations exceeded the Protection of Groundwater Soil Remediation Goals and the Preliminary Residential Health -Based Goals. There is an apparent correlation between the measured soil COC concentrations from background soil samples and measured groundwater COC concentrations from samples from downgradient wells of interest. To evaluate reasonably expected concentrations of COCs in groundwater produced as a result of leaching from the soil samples, soil -to -groundwater partitioning calculations for barium, chromium, and cobalt were performed, 4 GOLDER 14 June 30, 2020 19117535.701 and are presented in Table 9. A literature search of partitioning coefficients (Kd) was performed, which resulted in wide range of Kd values for a given constituent, which are summarized in Table 9. Partitioning calculations were performed using the range of published Kd values and are presented as Table 9. The maximum concentrations of the COCs in historical groundwater samples for the facility are within or less than the simulated range utilizing the published Kd values, which indicates that the concentrations of the COCs in the soil samples is capable of leaching into groundwater at concentrations within the range observed in samples form OW-3, MW-6, MW-7, MW-11, and MW-19. This finding supports a hypothetical naturally occurring source of the COCs in groundwater. 5.0 CONCLUSIONS The following evaluations indicate that the source of above -standard concentrations of COCs in groundwater samples collected from downgradient monitoring wells at the Hanes Mill Road Landfill are not related to a release from the waste management units at the facility: Barium has been detected in samples from OW-3 at concentrations that are typically more than 2 times higher than the concentrations detected in samples from the representative leachate Chromium has been detected in samples from MW-11 at concentrations that are similar to the concentrations detected in samples from the facility leachate. Chromium has been detected in samples from the background wells at concentrations lower than the concentrations detected in MW-11. Therefore, a mixture of facility leachate and groundwater from the backgrounds is not likely to produce the concentrations observed in the samples from MW-11. Cobalt has been detected in samples from OW-3, MW-6, MW-7, and MW-19 at concentrations that are similar to higher than the concentrations detected in samples from the facility leachate. Cobalt has been sporadically detected in samples from the background wells. Therefore, a mixture of facility leachate and groundwater from the backgrounds is not likely to produce the concentrations observed in the samples from OW-3, MW-6, MW-7, and MW-19. The ternary plots are inconclusive showing that the geochemistry of the facility leachate can be similar to wells OW-3, MW-6, and MW-19, but can also be similar to background wells MW-12 and MW-24 Published data indicate that the concentrations of the COCs detected in wells OW-3, MW-6, MW-7, MW-11, and MW-19 are within the range of naturally occurring concentrations in crystalline -rock groundwater in the Piedmont Physiographic Province. Time Series plots and Sen's Slope estimator plots show that all of the COCs show a declining trend in concentrations Intra-well statistics indicate that concentrations of the COCs at the closed Subtitle D landfill are below calculated background concentrations. Intra-well accounts for the spatial variability of the site. Intra-well statistics was not performed for OW-3 because the closed unlined landfill does not have a liner. Intra-well statistics was not performed for MW-19 at the active Subtitle D landfill because there is not currently enough data with turbidity of less than 10 NTU. Soil partitioning calculations using historic soil data indicate that the COCs are present in the facility soils at concentrations capable of generating concentrations in groundwater that have been detected in wells OW-3, MW-6, MW-7, MW-11, and MW-19 GOLDER 15 June 30, 2020 19117535.701 Based on the information above, the WSFCU proposes the following actions at the facility: No further action for the groundwater standards for barium and cobalt at OW-3 at the closed unlined landfill Implement groundwater protection standards (GPS) based on the intra-well statistical calculations as follows: GPS for chromium at MW-11 of 18.9 ug/L GPS for cobalt at MW-6 of 20.0 ug/L GPS for cobalt at MW-7 of 29.9 ug/L Allow additional 3 years to acquire additional cobalt data from MW-19 during routine sampling events to establish a GPS Based on the evaluations and conclusions presented herein, and in the absence of other indicators for a release of solid waste constituents to the uppermost aquifer, the WSFCU requests approval of this ASD and proposes no further actions other than the establishment of a GPS for cobalt at MW-19 at the end of the three-year period. V.0 REFERENCES Allison, Jerry D. and Terry L. Allison. 2005. Partition Coefficients for Metals in Surface Water, Soil, and Waste. Office of Research and Development, United States Environmental Protection Agency. July. Butler, J.R., and D.T. Secor, Jr., 1991. The Central Piedmont (Chapter 4) in J.W. Horton, Jr. and V.A. Zullo, eds., The Geology of the Carolinas (Carolina Geological Society Fiftieth Anniversary Volume): The University of Tennessee Press, pp. 2, 4, 24, 36, 44-45. Chapman, Melinda J. and others. 2013. Naturally Occurring Contaminants in the Piedmont and Blue Ridge Crystalline -Rock Aquifers and Piedmont Early Mesozoic Basin SiIiciclastic-Rock Aquifers, Eastern United States, 1994-2008. National Water -Quality Assessment Program, United States Environmental Protection Agency. EPA. 1996. Soil Screening Guidance: Technical Background Document, Second Edition. Office of Emergency and Remedial Response, United States Environmental Protection Agency, Washington, D.C., Publication: 9355.4-17A. May. EPA. 2005b. Guidance for Developing Soil Screening Levels. Office of Solid Waste and Emergency Response, United States Environmental Protection Agency, Washington, D.C., OSWER Directive 9285.7-55. March. EPA. 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities - Unified Guidance, United States Environmental Protection Agency, Washington, D.C., EPA 530-R-09-007. March. EPA. 2018. Regional Screening Levels (RSL) Chemical -specific Supporting Table. https://www.epa.gov/risk/regional-screening-levels-rsIs-generic-tables. May. Golder Associates NC, Inc. 2013. Soil, Surface Water, and Groundwater Sampling Report; Hanes Mill Road Landfill, Permit No. 34-02. October 3. Golder Associates NC, Inc. 2016. Soil Sampling and Analysis Report; Hanes Mill Road Landfill, Permit No. 34-02. February 19. GOLDER 16 June 30, 2020 19117535.701 Golder Associates NC, Inc. 2016. Soil and Surface Water Sampling and Analysis Report; Hanes Mill Road Landfill, Permit No. 34-02. August 10. Golder Associates NC, Inc. 2020. First Semi -Annual 2018 Water Quality Monitoring Event Report; Hanes Mill Road Landfill, Permit No. 34-02. May 4. HDR, November 2003. Assessment of Corrective Measures Report, Hanes Landfill, Winston-Salem, North Carolina. Heath, Ralph C. 1982. Basic Ground -Water Hydrology. USGS Water Supply Paper 2220. NCGS (North Carolina Geologic Survey). 1985. Geologic Map of North Carolina. Shacklette, H.T., and J.G. Boerngen. 1984. Element Concentrations in Soils and Other Surficial Materials in the Conterminous United States. United States Geological Survey Professional Paper 1270. United States Government Printing Office. Stenge, D.L. and S.R. Peterson. 1989. Chemical Data Bases for the Multimedia Environmental Pollutant Assessment System (MEPAS): Version 1. Battelle Memorial Institute. December. USGS National Geochemical Survey Database, http://mrdata.usgs.gov/geochem/, 2016. GOLDER 17 June 30, 2020 Signature Page Golder Associates NC, Inc. David "Dusty" Y. Reedy II, PG Jeffrey D. Frazier, PG Senior Hydrogeologist Senior Consultant Engineering Lic. No. C-2862/Geology Lic. No. C-399 19117535.701 Golder Associates NC, Inc. is a licensed user of the Golder trademark, and an associated operating entity. Golder and the G logo are trademarks of Golder Associates Corporation. https://golderassociates.sharepoint.com/sites/123522/19117535 20192020 fy/phase 701 - asd addendum/200 deliverables/252 final/19117535.701-001-r-rev0-hanes_asd.docx 4 GOLDER 18 Tables June 2020 19117535.701 TABLE 1 Summary of Well Construction Information Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Ground Measuring Well Construction Coordinates Surface Point Well Well Screened Geologyof Diameter Depth Interval Screened Identification Date Elevation Elevation (in) (ft bgs) (ft bgs) Interval Northing Easting (ft AMSL) (ft AMSL) Closed Unlined Landfill Monitoring Wells MW-1RR 5/31/2001 891222.48 1620651.44 893.60 896.82 2 59.0 44.0-59.0 Bedrock OW-3 9/13/1994 888851.47 1620210.52 817.75 820.13 2 16.0 6.0-16.0 Saprolite OW-4 9/14/1994 888381.20 1619630.70 806.83 809.37 2 16.0 6.0-16.0 Saprolite OW-6 9/13/1994 890727.15 1618831.90 824.74 827.12 2 27.0 12.0-27.0 Saprolite OW-7DA 5/21/2001 888763.30 1618927.54 798.80 801.52 2 115.0 110.0-115.0 Bedrock OW-10D 5/3/2001 889765.20 1618759.62 817.30 820.09 2 80.0 75.0-80.0 Bedrock OW-11 9/15/1994 890240.94 1618632.60 804.47 806.69 2 16.0 6.0-16.0 Saprolite OW-12 8/1/1999 888315.57 1619056.47 798.40 800.14 2 15.0 5.0-15.0 Saprolite OW-13D 5/15/2001 889353.88 1618800.48 803.80 806.41 2 115.0 110.0-115.0 Bedrock OW-14D 5/21/2001 889587.90 1618501.92 801.20 803.95 2 80.0 70.0-80.0 Bedrock OW-17D 5/10/2001 888909.84 1618684.17 798.80 801.54 2 80.0 70.0-80.0 Bedrock Closed Subtitle D Landfill Monitoring Wells MW-1RR 5/31/2001 891222.48 1620651.44 893.60 896.82 2 59.0 44.0-59.0 Bedrock MW-6 1/20/1997 890347.86 1621345.34 865.60 867.78 2 35.0 20.0-35.0 Saprolite MW-6D 1/20/1997 890341.76 1621318.45 865.60 867.89 2 65.0 54.5-64.5 Saprollite/PWR MW-7 1/22/1997 891367.95 1619472.34 843.10 845.33 2 25.0 10.0-25.0 Saprolite MW-8 1/21/1997 891259.86 1619183.64 833.80 836.91 2 20.0 5.0-20.0 Saprolite MW-9 1/23/1997 891177.69 1619026.90 840.40 843.60 2 30.0 15.0-30.0 Saprollite/PWR MW-11 1/23/1997 890405.22 1616810.23 843.20 845.23 2 30.0 15.0-30.0 Saprolite MW-23 11/27/2018 892005.23 1620008.33 880.00 883.4 2 42.0 32.0-42.0 Saprolite Active Subtitle D Landfill Monitoring Wells MW-12 7/22/2002 890405.22 1616810.23 936.80 939.05 2 82.0 67.0-82.0 Bedrock MW-13 7/24/2002 889497.99 1618313.81 818.50 820.41 2 32.0 17.0-32.0 Saprolite MW-14 7/22/2002 888763.43 1618559.47 812.50 814.53 2 29.0 14.0-29.0 Saprolite MW-15 7/23/2002 888370.53 1618517.81 800.90 803.32 2 22.0 5.0-20.0 Saprolite MW-16 7/22/2002 887727.16 1618443.32 796.40 798.58 2 20.0 5.0-20.0 Saprolite MW-17 7/23/2002 887333.74 1617864.55 799.10 801.18 2 20.0 5.0-20.0 Saprolite MW-18 7/23/2002 887638.88 1617424.75 806.30 811.35 2 19.0 4.0-19.0 Saprollite/PWR MW-19 7/23/2002 887899.38 1617138.22 809.10 811.35 2 20.0 5.0-20.0 Saprolite MW-20 1/12/2009 888799.88 1616654.25 829.03 831.91 2 25.0 15.0-25.0 Saprolite MW-21 1/20/2009 889414.61 1616730.40 888.72 890.40 2 56.0 46.0-56.0 PWR MW-22 1/13/2009 889935.47 1618145.25 812.81 815.70 2 28.0 18.0-28.0 Saprolite MW-24 11/27/2018 891530.40 1616933.96 826.6 829.19 2 15.0 5.0-15.0 Saprolite Notes: ft AMSL = feet above mean sea level ft bgs = feet below ground surface PWR = partially weathered rock in = inches Well construction information collected from HDR historical reports. Well MW-9 was re -surveyed after repairs were made in September 2011. ,,> GOLDER 10f1 June 2020 19117535.701 TABLE 2 Historical Static Water Level Data for the Closed Unlined Landfill Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Closed Unlined Landfill Monitoring Wells MW-1RR OW-3 OW-4 OW-6 OW-7DA OW-10D OW-11 OW-12 OW-13D OW-14D OW-17D TOC Elevation 896.82 820.13 809.37 827.12 801.52 820.09 806.69 800.14 806.41 803.95 800.47 ft AMSL Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 11 /06/06 854.92 41.9 811.52 8.61 802.94 6.43 807.72 19.4 -- -- -- -- 802.37 4.32 794.50 5.64 799.79 6.62 799.83 4.12 795.40 5.07 03/19/08 853.80 43.02 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 12/01 /08 853.40 43.42 811.28 8.85 802.59 6.78 806.48 20.64 794.92 6.6 799.46 20.63 801.66 5.03 793.91 6.23 798.81 7.6 799.38 4.57 794.37 6.1 03/27/09 853.84 42.98 811.38 8.75 803.22 6.15 808.95 18.17 796.48 5.04 801.17 18.92 803.15 3.54 795.78 4.36 800.68 5.73 800.41 3.54 795.44 5.03 10/08/09 854.47 42.35 811.15 8.98 802.25 7.12 806.11 21.01 793.91 7.61 797.74 22.35 799.94 6.75 792.61 7.53 797.92 8.49 797.60 6.35 793.36 7.11 03/16/10 855.74 41.08 811.60 8.53 803.85 5.52 810.84 16.28 797.08 4.44 801.95 18.14 804.01 2.68 796.26 3.88 801.77 4.64 800.92 3.03 795.94 4.53 09/08/10 856.37 40.45 811.29 8.84 802.29 7.08 807.09 20.03 793.77 7.75 798.12 21.97 800.59 6.10 792.21 7.93 798.50 7.91 797.83 6.12 792.65 7.82 03/21/11 855.53 41.29 811.52 8.61 803.33 6.04 809.07 18.05 796.28 5.24 800.99 19.10 803.38 3.31 794.86 5.28 800.07 6.34 800.30 3.65 795.23 5.24 09/12/11 855.54 41.28 811.22 8.91 802.13 7.24 806.53 20.59 794.08 7.44 798.36 21.73 800.63 6.06 792.32 7.82 798.40 8.01 798.14 5.81 793.57 6.90 03/12/12 854.98 41.84 811.42 8.71 803.08 6.29 808.76 18.36 795.73 5.79 800.81 19.28 802.87 3.82 795.24 4.90 800.41 6.00 800.15 3.80 795.11 5.36 10/01/12 854.38 42.44 811.68 8.45 802.58 6.79 805.61 21.51 794.41 7.11 798.84 21.25 801.02 5.67 793.09 7.05 798.20 8.21 799.15 4.80 794.03 6.44 03/11/13 854.13 42.69 811.83 8.30 803.54 5.83 808.60 18.52 796.60 4.92 801.20 18.89 803.18 3.51 795.89 4.25 800.51 5.90 800.59 3.36 795.63 4.84 09/09/13 856.98 39.84 811.55 8.58 802.63 6.74 808.48 18.64 795.34 6.18 799.71 20.38 801.77 4.92 793.87 6.27 799.80 6.61 798.95 5.00 794.23 6.24 03/12/14 856.95 39.87 811.77 8.36 803.88 5.49 809.70 17.42 797.22 4.30 802.03 18.06 803.86 2.83 796.56 3.58 801.35 5.06 800.97 2.98 796.07 4.40 09/08/14 857.42 39.40 810.97 9.16 802.15 7.22 805.82 21.30 793.83 7.69 797.68 22.41 799.77 6.92 792.29 7.85 797.86 8.55 797.43 6.52 793.22 7.25 03/09/15 849.91 46.91 811.56 8.57 803.02 6.35 807.97 19.15 795.67 5.85 800.89 19.20 802.84 3.85 795.70 4.44 800.06 6.35 800.29 3.66 795.51 4.96 09/14/15 854.70 42.12 811.42 8.71 801.61 7.76 805.23 21.89 793.58 7.94 797.43 22.66 799.59 7.10 791.83 8.31 797.41 9.00 797.94 6.01 793.12 7.35 03/07/16 856.28 40.54 811.87 8.26 803.29 6.08 810.00 17.12 796.61 4.91 801.40 18.69 803.19 3.50 795.72 4.42 801.20 5.21 800.47 3.48 795.39 5.08 09/13/16 856.43 40.39 811.57 8.56 801.84 7.53 805.96 21.16 793.90 7.62 797.76 22.33 799.88 6.81 792.17 7.97 798.02 8.39 797.40 6.55 793.28 7.19 03/06/17 854.61 42.21 811.63 8.50 802.52 6.85 807.26 19.86 795.42 6.10 800.27 19.82 802.40 4.29 795.23 4.91 799.65 6.76 799.24 4.71 795.11 5.36 04/05/17 854.70 42.12 811.86 8.27 803.08 6.29 807.51 19.61 796.66 4.86 800.81 19.28 802.79 3.90 796.29 3.85 800.09 6.32 800.46 3.49 795.74 4.73 09/11/17 856.27 40.55 811.68 8.45 802.00 7.37 806.08 21.04 794.22 7.30 798.13 21.96 800.30 6.39 792.87 7.27 798.21 8.20 797.77 6.18 793.54 6.93 03/05/18 854.29 42.53 811.79 8.34 802.46 6.91 807.10 20.02 796.03 5.49 799.87 20.22 802.00 4.69 794.92 5.22 799.40 7.01 799.39 4.56 794.82 5.65 12/11/18 855.99 40.83 811.91 8.22 803.25 6.12 809.27 17.85 797.52 4.00 801.32 18.77 803.33 3.36 795.51 4.63 800.98 5.43 800.56 3.39 795.75 4.72 09/23/19 858.97 37.85 811.54 8.59 802.03 7.34 807.16 19.96 794.06 7.46 798.28 21.81 800.45 6.24 792.29 7.85 798.84 7.57 797.75 6.20 793.39 7.08 03/04/19 858.22 38.60 812.12 8.01 804.23 5.14 811.46 15.66 798.00 3.52 802.78 17.31 804.41 2.28 797.38 2.76 802.63 3.78 801.27 2.68 796.53 3.94 03/02/20 858.76 38.06 811.92 8.21 803.56 5.81 810.73 16.39 797.10 4.42 801.84 18.25 803.66 3.03 796.22 3.92 801.63 4.78 800.62 3.33 795.72 4.75 MEAN 855.47 41.35 811.58 8.55 802.82 6.55 807.90 19.22 795.54 5.98 799.95 20.14 802.04 4.65 794.44 5.70 799.70 6.71 799.42 4.53 794.70 5.77 MAXIMUM 858.97 46.91 812.12 9.16 804.23 7.76 811.46 21.89 798.00 7.94 802.78 22.66 804.41 7.10 797.38 8.31 802.63 9.00 801.27 6.55 796.53 7.82 MINIMUM 849.91 37.85 810.97 8.01 801.61 5.14 805.23 15.66 793.58 3.52 797.43 17.31 799.59 2.28 791.83 2.76 797.41 3.78 797.40 2.68 792.65 3.94 Notes: AMSL = above mean sea level ft = feet DTW - depth to water TOC = top of casing MW = monitoring well OW = observation well III,>GOLDER 1 of 1 June 2020 TABLE 3 Historical Static Water Level Data for the Closed Subtitle D Landfill Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina 19117535.701 Closed Subtitle D Landfill Monitoring Wells MW-6 MW-6D MW-7 MW-8 MW-9 MW-11 MW-23 TOC Elevation 867.78 867.89 845.33 836.91 843.60 845.23 883.40 ft AMSL Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 11 /06/06 839.72 28.06 839.36 28.53 829.10 16.23 825.91 11.00 822.51 21.09 825.45 19.78 -- -- 03/20/08 839.67 28.11 839.28 28.61 829.23 16.1 826.10 10.81 822.24 21.36 825.00 20.23 -- -- 12/02/08 838.85 28.93 838.51 29.38 828.60 16.73 825.63 11.28 821.53 22.07 823.68 21.55 -- -- 03/27/09 839.83 27.95 839.42 28.47 829.51 15.82 826.07 10.84 822.36 21.24 825.58 19.65 -- -- 10/08/09 838.86 28.92 838.50 29.39 827.96 17.37 824.91 12.00 821.27 22.33 823.91 21.32 -- -- 03/16/10 840.94 26.84 840.57 27.32 830.45 14.88 826.66 10.25 823.02 20.58 827.38 17.85 -- -- 09/08/10 839.56 28.22 839.15 28.74 828.37 16.96 825.04 11.87 821.27 22.33 824.65 20.58 -- -- 03/21/11 840.17 27.61 839.93 27.96 829.52 15.81 826.12 10.79 822.51 21.09 825.58 19.65 -- -- 09/12/11 839.27 28.51 839.03 28.86 827.91 17.42 825.06 11.85 819.95 23.65 824.02 21.21 -- -- 03/12/12 840.26 27.52 839.71 28.18 829.44 15.89 825.96 10.95 820.99 22.61 825.61 19.62 -- -- 10/01/12 839.08 28.70 838.76 29.13 828.24 17.09 825.60 11.31 820.10 23.50 823.48 21.75 -- -- 03/11/13 840.20 27.58 839.77 28.12 829.71 15.62 826.51 10.40 821.75 21.85 825.85 19.38 -- -- 09/09/13 840.24 27.54 839.78 28.11 829.18 16.15 825.64 11.27 820.48 23.12 825.80 19.43 -- -- 03/12/14 841.19 26.59 840.61 27.28 830.43 14.90 826.64 10.27 821.85 21.75 826.70 18.53 -- -- 09/08/14 839.87 27.91 839.60 28.29 828.36 16.97 825.25 11.66 819.99 23.61 823.78 21.45 -- -- 03/09/15 840.44 27.34 839.98 27.91 829.63 15.70 826.36 10.55 822.79 20.81 825.31 19.92 -- -- 09/14/15 838.98 28.80 838.60 29.29 827.29 18.04 824.60 12.31 819.65 23.95 823.08 22.15 -- -- 03/07/16 841.03 26.75 840.39 27.50 830.27 15.06 826.31 10.60 821.35 22.25 827.25 17.98 -- -- 09/13/16 839.62 28.16 839.22 28.67 827.91 17.42 824.78 12.13 819.72 23.88 822.80 22.43 -- -- 03/06/17 839.18 28.60 839.38 28.51 829.03 16.30 825.98 10.93 820.66 22.94 824.32 20.91 -- -- 09/11/17 839.63 28.15 839.21 28.68 828.56 16.77 825.56 11.35 820.06 23.54 823.86 21.37 -- -- 03/05/18 839.59 28.19 839.20 28.69 829.11 16.22 826.29 10.62 815.95 27.65 824.46 20.77 -- -- 12/11/18 840.74 27.04 840.33 27.56 830.06 15.27 826.86 10.05 821.75 21.85 826.64 18.59 844.69 38.71 03/04/19 842.02 25.76 841.62 26.27 831.90 13.43 827.36 9.55 822.75 20.85 829.26 15.97 847.44 35.96 09/23/19 840.52 27.26 840.13 27.76 828.44 16.89 825.40 11.51 819.92 23.68 824.42 20.81 846.17 37.23 03/02/20 842.13 25.65 841.69 26.20 830.66 14.67 826.65 10.26 822.21 21.39 828.64 16.59 846.60 36.80 MEAN 840.06 27.72 839.68 28.21 829.19 16.14 825.89 11.02 821.10 22.50 825.25 19.98 846.23 37.18 MAXIMUM 842.13 28.93 841.69 29.39 831.90 18.04 827.36 12.31 823.02 27.65 829.26 22.43 847.44 38.71 MINIMUM 838.85 25.65 838.50 26.20 827.29 13.43 824.60 9.55 815.95 20.58 822.80 15.97 844.69 35.96 Notes: AMSL = above mean sea level ft = feet DTW - depth to water TOC = top of casing MW = monitoring well OW = observation well MW-23 was installed in November 2018 and the groundwater elevation for December 2018 was measured on December 14, 2018. ,,> GOLDER 10f1 June 2020 19117535.701 TABLE 4 Historical Static Water Level Data for the Active Subtitle D Landfill Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Active Subtitle D Landfill Monitoring Wells MW-12 MW-13 MW-14 MW-15 MW-16 MW-17 MW-18 MW-19 MW-20 MW-21 MW-22 MW-24 TOC Elevation 939.05 820.41 814.53 803.32 798.58 801.18 808.5 811.35 831.91 890.40 815.70 829.19 ft AMSL Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 03/27/09 877.03 62.02 800.86 19.55 795.18 19.35 794.22 9.10 793.11 5.47 796.35 4.83 800.40 8.12 804.41 6.94 -- -- -- -- -- -- -- -- 10/08/09 877.51 61.54 798.90 21.51 793.83 20.70 792.85 10.47 791.23 7.35 795.01 6.17 800.18 8.34 804.25 7.10 -- -- -- -- -- -- -- -- 03/16/10 877.81 61.24 801.99 18.42 795.82 18.71 795.07 8.25 793.87 4.71 796.87 4.31 800.65 7.87 804.93 6.42 -- -- -- -- -- -- -- -- 09/08/10 879.54 59.51 799.46 20.95 793.73 20.80 792.67 10.65 790.91 7.67 795.48 5.70 799.92 8.60 804.02 7.33 -- -- -- -- -- -- -- -- 03/21 /11 879.69 59.36 801.10 19.31 794.22 20.31 793.51 9.81 793.14 5.44 796.57 4.61 800.43 8.09 804.31 7.04 819.74 12.17 845.58 44.82 801.85 13.85 -- -- 09/12/11 878.84 60.21 799.21 21.20 794.04 20.49 792.68 10.64 791.09 7.49 795.39 5.79 800.01 8.51 803.97 7.38 817.42 14.49 844.65 45.75 800.84 14.86 -- -- 03/12/12 878.25 60.80 800.61 19.80 794.97 19.56 793.93 9.39 792.76 5.82 796.56 4.62 800.32 8.20 804.33 7.02 819.12 12.79 843.83 46.57 802.06 13.64 -- -- 10/01 /12 877.41 61.64 798.93 21.48 794.42 20.11 794.21 9.11 791.59 6.99 796.07 5.11 800.08 8.44 804.14 7.21 817.82 14.09 843.89 46.51 800.29 15.41 -- -- 03/11 /13 877.09 61.96 800.79 19.62 795.39 19.14 794.34 8.98 793.19 5.39 796.58 4.60 801.48 7.04 804.48 6.87 816.30 15.61 843.15 47.25 802.21 13.49 -- -- 09/09/13 876.82 62.23 799.95 20.46 794.65 19.88 793.45 9.87 791.96 6.62 792.10 9.08 800.30 8.22 804.15 7.20 818.53 13.38 844.50 45.90 801.48 14.22 -- -- 03/12/14 878.10 60.95 801.13 19.28 796.17 18.36 795.49 7.83 793.93 4.65 797.06 4.12 800.90 7.62 805.09 6.26 821.76 10.15 845.42 44.98 802.82 12.88 -- -- 09/08/14 879.89 59.16 798.67 21.74 794.10 20.43 792.72 10.60 791.01 7.57 795.50 5.68 800.10 8.42 804.10 7.25 817.41 14.50 847.11 43.29 800.25 15.45 -- -- 03/09/15 879.86 59.19 800.37 20.04 795.40 19.13 794.39 8.93 793.53 5.05 796.80 4.38 800.63 7.89 804.55 6.80 820.34 11.57 845.55 44.85 802.10 13.60 -- -- 09/14/15 878.54 60.51 798.25 22.16 793.66 20.87 792.36 10.96 790.68 7.90 795.17 6.01 799.81 8.71 804.12 7.23 817.24 14.67 844.52 45.88 799.68 16.02 -- -- 03/07/16 877.93 61.12 801.26 19.15 795.43 19.10 794.51 8.81 793.49 5.09 796.85 4.33 800.53 7.99 804.35 7.00 819.75 12.16 845.00 45.40 802.62 13.08 -- -- 09/13/16 879.89 59.16 798.33 22.08 793.97 20.56 792.60 10.72 791.17 7.41 795.52 5.66 799.91 8.61 803.96 7.39 817.33 14.58 846.73 43.67 800.20 15.50 -- -- 03/06/17 879.59 59.46 799.77 20.64 795.01 19.52 793.92 9.40 792.89 5.69 796.27 4.91 800.29 8.23 804.28 7.07 819.05 12.86 845.31 45.09 801.52 14.18 -- -- 09/11 /17 879.05 60.00 798.61 21.80 794.13 20.40 792.87 10.45 791.56 7.02 795.77 5.41 800.05 8.47 803.97 7.38 816.93 14.98 845.48 44.92 800.22 15.48 -- -- 03/05/18 878.79 60.26 800.00 20.41 794.94 19.59 793.90 9.42 792.83 5.75 796.37 4.81 800.46 8.06 804.36 6.99 818.60 13.31 844.57 45.83 801.08 14.62 -- -- 12/11 /18 878.58 60.47 800.38 20.03 795.53 19.00 794.40 8.92 793.62 4.96 797.03 4.15 800.54 7.98 804.61 6.74 819.42 12.49 845.96 44.44 802.23 13.47 824.85 4.34 03/04/19 880.06 58.99 801.83 18.58 796.61 17.92 795.91 7.41 793.63 4.95 797.71 3.47 801.03 7.49 805.17 6.18 821.52 10.39 847.56 42.84 803.28 12.42 825.59 3.60 09/23/19 883.80 55.25 798.48 21.93 793.82 20.71 792.67 10.65 791.06 7.52 795.77 5.41 800.12 8.40 804.06 7.29 817.38 14.53 850.70 39.70 800.38 15.32 824.28 4.91 03/02/20 883.83 55.22 801.17 19.24 795.53 19.00 794.61 8.71 793.78 4.80 797.29 3.89 800.76 7.76 803.30 8.05 819.50 12.41 849.48 40.92 802.65 13.05 825.20 3.99 MEAN 879.04 60.01 800.00 20.41 794.81 19.72 793.79 9.53 792.44 6.14 796.09 5.09 800.39 8.13 804.30 7.05 818.69 13.22 845.74 44.66 801.46 14.24 824.98 4.21 MAXIMUM 883.83 62.23 801.99 22.16 796.61 20.87 795.91 10.96 793.93 7.90 797.71 9.08 801.48 8.71 805.17 8.05 821.76 15.61 850.70 47.25 803.28 16.02 825.59 4.91 MINIMUM 876.82 55.22 798.25 18.42 793.66 17.92 792.36 7.41 790.68 4.65 792.10 3.47 799.81 7.04 803.30 6.18 816.30 10.15 843.15 39.70 799.68 12.42 824.28 3.60 Notes: AMSL = above mean sea level ft = feet DTW - depth to water TOC = top of casing MW = monitoring well OW = observation well MW-24 was installed in November 2018 and the groundwater elevation for December 2018 was measured on December 17, 2018. ,,> GOLDER 1 of 1 June 2020 TABLE 5 19117535.701 Summary of Detected Constituents in Monitoring Wells Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Closed Closed Active Unlined & Active Detected MonitoringSample p NC2L/ Practical SWS Closed Subtitle D Supplemental Upgradient Unlined Down- Closed Subtitle D Downgradient Subtitle D Down- Constituents/Analytes Units Date IMAC EPA MCL MDL Quantitation Reporting Subtitle D U radient pg gradient gradient Leachate Blanks Limit Limit Upgradient MW-1 RR MW-12 MW-23 MW-24 OW-3 MW-6 MW-7 MW-11 MW-19 Antimony ug/L 10/07/09 1 6 -- -- 6 0.360 B ND -- -- 0.174 B 0.321 B 0.273 B 0.272 B 0.271 B 2.10 J 0.182 J ug/L 03/16/10 1 6 -- -- 6 ND ND -- -- ND ND ND ND ND 1.12 J ND ug/L 09/07/10 1 6 -- -- 6 ND ND -- -- ND 0.478 J ND ND ND ND ND ug/L 03/23/11 1 6 -- -- 6 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/12/11 1 6 -- -- 6 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/12/12 1 6 -- -- 6 ND 0.879 J -- -- ND 1.31 J 0.249 J ND ND 3.06 J ND ug/L 10/01/12 1 6 -- -- 6 0.454 B N D -- -- 0.368 B 0.835 J N D 0.384 J N D N D 0.27 J ug/L 03/12/13 1 6 -- -- 6 ND 1.01 J -- -- ND 0.921 J ND ND ND ND ND ug/L 09/10/13 1 6 -- -- 6 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 1 6 -- -- 6 ND 0.778 J -- -- ND 0.960 J 0.240 J ND ND ND ND ug/L 09/10/14 1 6 0.220 -- 6 ND 0.604 J -- -- 1.26 J 0.738 J ND ND ND 13.3 J ND ug/L 03/09/15 1 6 0.220 -- 6 ND 0.784 J -- -- ND 0.714 J ND ND ND 9.46 J ND ug/L 09/14/15 1 6 0.220 -- 6 0.515 J 0.288 J -- -- ND 2.20 J ND ND ND 133 ND ug/L 03/07/16 1 6 0.220 -- 6 0.437 B N D -- -- 0.621 B N D N D N D N D 16.2 J 0.655 J ug/L 09/13/16 1 6 0.220 -- 6 ND 0.718 J -- -- ND 0.658 J ND ND ND 28.4 ND ug/L 03/06/17 1 6 0.370 -- 6 ND ND -- -- ND ND ND ND ND 5.21 J ND ug/L 09/11/17 1 6 0.370 -- 6 ND ND -- -- ND ND ND ND ND 7.71 J ND ug/L 03/05/18 1 6 0.370 -- 6 ND ND -- -- ND ND ND ND ND 11.4 J ND ug/L 12/11/18 1 6 1.85 5 -- ND ND ND ND ND ND ND ND ND 6.37 J ND ug/L 03/05/19 1 6 0.740 2 -- ND ND ND ND ND ND ND ND ND 4.85 J ND (Background Sampling Event) ug/L 07/31/19 1 6 0.740 2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 1 6 0.740 2 -- ND ND ND ND ND ND ND ND ND 19.7 ND (Background Sampling Event) ug/L 11/25/19 1 6 0.740 2 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 1 6 0.740 2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 1 6 0.740 2 -- ND ND ND ND ND ND ND ND ND 11.6 ND (Background Sampling Event) ug/L 05/12/20 1 6 0.740 2 -- -- -- ND ND -- -- -- -- -- -- ND Arsenic ug/L 10/07/09 10 10 -- -- 10 ND ND -- -- ND 2.90 J ND ND ND 4.4 J ND ug/L 03/16/10 10 10 -- -- 10 3.39 J ND -- -- ND 4.11 B 3.44 B ND 3.74 J ND ND ug/L 09/07/10 10 10 -- -- 10 ND ND -- -- ND 7.51 J ND ND 4.36 J 2.84 J ND ug/L 03/23/11 10 10 -- -- 10 ND 3.11 J -- -- ND ND 3.17 J ND ND 5.49 J ND ug/L 09/12/11 10 10 -- -- 10 ND ND -- -- 4.42 B ND ND ND ND ND 3.35 J ug/L 03/12/12 10 10 -- -- 10 ND ND -- -- ND ND ND ND ND ND 4.07 J ug/L 10/01/12 10 10 -- -- 10 ND ND -- -- ND ND 5.95 B ND ND ND 3.73 J ug/L 03/12/13 10 10 -- -- 10 ND ND -- -- ND ND ND ND ND ND 3.32 J ug/L 09/10/13 10 10 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 10 10 -- -- 10 ND ND -- -- ND ND ND ND ND 12.1 ND ug/L 09/10/14 10 10 5.40 -- 10 ND ND -- -- ND ND ND ND ND 20.7 ND ug/L 03/09/15 10 10 5.40 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/14/15 10 10 5.40 -- 10 ND ND -- -- ND ND ND ND ND 107 ND ug/L 03/07/16 10 10 5.40 -- 10 ND ND -- -- 7.36 J ND ND ND ND 30.1 ND ug/L 09/13/16 10 10 5.40 -- 10 ND ND -- -- ND 13.5 ND ND ND 49.3 ND ug/L 03/06/17 10 10 8.00 -- 10 ND ND -- -- ND ND ND ND ND 13.2 J ND ug/L 09/11/17 10 10 6.80 -- 10 ND ND -- -- ND ND ND ND ND 11.2 ND ug/L 03/05/18 10 10 6.80 -- 10 ND ND -- -- ND ND ND ND ND 24.0 ND ug/L 12/11/18 10 10 7.60 10 -- ND ND ND ND ND ND ND ND ND ND ND ug/L 03/05/19 10 10 7.60 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 07/31/19 10 10 7.60 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 10 10 7.60 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 10 10 7.60 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 10 10 7.60 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 10 10 7.60 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 10 10 7.60 10 -- -- -- ND ND -- -- -- -- -- -- ND Barium ug/L 10/07/09 700 2000 -- -- 100 15.8 J 35.4 J -- -- 1170 156 154 162 67.3 J 312 1.72 J ug/L 03/16/10 700 2000 -- -- 100 15.0 J 32.4 J -- -- 987 486 95.2 J 149 93.9 J 351 ND ug/L 09/07/10 700 2000 -- -- 100 12.2 J 28 J -- -- 971 358 102 161 62.9 J 261 ND ug/L 03/23/11 700 2000 -- -- 100 19.8 J 37.0 J -- -- 1230 458 100 153 73.5 J 984 ND ug/L 09/12/11 700 2000 -- -- 100 13.3 J 36.4 J -- -- 1460 212 130 138 64.0 J 271 ND ug/L 03/12/12 700 2000 -- -- 100 15.2 J 29.1 J -- -- 1250 275 93.0 J 149 55.0 J 264 1.06 J ug/L 10/01/12 700 2000 -- -- 100 22.9 J 31.3 J -- -- 1260 189 119 136 43.8 J 194 1.27 J ug/L 03/12/13 700 2000 -- -- 100 12.9 J 37.0 J -- -- 1390 254 99.5 J 150 51.7 J 302 1.47 J ug/L 09/10/13 700 2000 -- -- 100 16.7 J 35.9 J -- -- 1280 425 108 130 52.9 J 300 1.15 J ug/L 03/11/14 700 2000 -- -- 100 17.3 J 30.6 J -- -- 1280 633 98.7 J 158 38.2 J 354 1.10 J ug/L 09/10/14 700 2000 1.00 -- 100 14.5 J 30.8 J -- -- 1170 590 118 129 60.8 J 804 2.55 J ug/L 03/09/15 700 2000 1.00 -- 100 17.6 J 33.7 J -- -- 1260 584 100 122 49.4 J 558 ND ug/L 09/14/15 700 2000 1.00 -- 100 17.7 J 34.3 J -- -- 1150 214 120 118 48.1 J 1510 1.22 J ug/L 03/07/16 700 2000 1.00 -- 100 27.6 J 35.7 J -- -- 1090 663 90.9 J 104 42.1 J 712 ND ug/L 09/13/16 700 2000 1.00 -- 100 20.9 J 36.4 J -- -- 993 520 108 108 47.2 J 792 1.08 J ug/L 03/06/17 700 2000 0.53 -- 100 20.0 J 38.8 J -- -- 1200 411 114 105 44.6 J 330 1.16 J ug/L 09/11/17 700 2000 1.00 -- 100 20.0 J 39.0 J -- -- 1080 312 99.3 J 94.6 J 48.5 J 327 3.00 J ug/L 03/05/18 700 2000 1.00 -- 100 17.0 J 36.5 J -- -- 1150 271 111 105 38.0 J 563 1.66 J ug/L 12/11/18 700 2000 1.10 10 -- 15.5 34.2 184 167 1170 602 95.4 114 45.4 343 ND ug/L 03/05/19 700 2000 1.10 10 -- 23.0 36.8 136 159 1220 599 91.4 140 25.5 418 1.20 J (Background Sampling Event) ug/L 07/31/19 700 2000 1.10 10 -- -- -- 104 175 -- -- -- -- -- -- ND ug/L 09/23/19 700 2000 1.10 10 -- 17.1 34.7 86.9 172 1160 1100 109 101 34.3 445 3.77 J (Background Sampling Event) ug/L 11/25/19 700 2000 1.10 10 -- -- -- 93.5 179 -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 700 2000 1.10 10 -- -- -- 83.9 176 -- -- -- -- -- -- ND ug/L 03/02/20 700 2000 1.10 10 -- 24.8 32.6 72.1 159 804 513 89.6 144 24.2 447 ND (Background Sampling Event) ug/L 05/12/20 700 2000 1.10 10 -- -- -- 85.2 181 -- -- -- -- -- -- ND Beryllium ug/L 10/07/09 4 4 -- -- 1 ND 0.172 J -- -- ND 0.420 B 0.255 B ND ND ND 0.101 J ug/L 03/16/10 4 4 -- -- 1 ND ND -- -- ND 0.308 J 0.311 J ND ND ND ND ug/L 09/07/10 4 4 -- -- 1 ND ND -- -- ND ND 0.162 J ND ND ND ND ug/L 03/23/11 4 4 -- -- 1 ND ND -- -- ND ND 0.235 J ND 0.182 J 0.772 J ND ug/L 09/12/11 4 4 -- -- 1 ND ND -- -- 0.137 J ND ND ND 0.110 J ND ND ug/L 03/12/12 4 4 -- -- 1 ND ND -- -- ND ND 0.285 J ND ND ND ND ug/L 10/01/12 4 4 -- -- 1 ND ND -- -- ND ND 0.172 J ND ND ND ND ug/L 03/12/13 4 4 -- -- 1 ND ND -- -- ND ND 0.208 J ND ND ND ND ug/L 09/10/13 4 4 -- -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 4 4 -- -- 1 ND ND -- -- ND ND 0.141 J ND ND ND ND ug/L 09/10/14 4 4 0.10 -- 1 ND ND -- -- ND ND 0.175 J ND 0.168 J ND ND ug/L 03/09/15 4 4 0.10 -- 1 ND ND -- -- ND ND 0.189 J ND ND ND ND ug/L 09/14/15 4 4 0.10 -- 1 0.202 B ND -- -- 0.336 B ND 0.330 B 0.102 B ND ND 0.244 J ug/L 03/07/16 4 4 0.10 -- 1 ND ND -- -- ND ND 0.256 J 0.135 J ' ND ND ND ug/L 09/13/16 4 4 0.10 -- 1 ND ND -- -- ND ND 0.291 J ND ND ND ND ug/L 03/06/17 4 4 0.12 -- 1 ND ND -- -- ND ND 0.246 J ND 0.161 J ND ND ug/L 09/11/17 4 4 0.130 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/05/18 4 4 0.130 -- 1 ND ND -- -- ND ND 0.222 J ND ND ND ND ug/L 12/11/18 4 4 0.160 1 -- ND ND ND ND ND ND 0.249 J ND ND ND ND ug/L 03/05/19 4 4 0.160 1 -- ND ND ND ND ND ND 0.289 J 0.186 J ND ND ND (Background Sampling Event) ug/L 07/31/19 4 4 0.160 1 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 4 4 0.160 1 -- ND ND ND ND ND ND 0.371 J ND ND ND ND (Background Sampling Event) ug/L 11/25/19 4 4 0.160 1 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 4 4 0.160 1 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 4 4 0.160 1 -- ND ND ND ND ND ND 0.223 J ND ND ND ND (Background Sampling Event) ug/L 05/12/20 4 4 0.160 1 -- -- -- ND ND -- -- -- -- -- -- ND Cadmium ug/L 10/07/09 2 5 -- -- 1 ND ND -- -- 0.499 J 0.534 J ND ND ND ND ND ug/L 03/16/10 2 5 -- -- 1 ND ND -- -- 0.507 J ND ND ND ND ND ND ug/L 09/07/10 2 5 -- -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/23/11 2 5 -- -- 1 ND ND -- -- 0.560 J ND ND ND ND ND ND ug/L 09/12/11 2 5 -- -- 1 ND ND -- -- 4.76 ND ND ND ND ND ND ug/L 03/12/12 2 5 -- -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 10/01/12 2 5 -- -- 1 ND ND -- -- ND ND ND ND ND ND 0.478 J ug/L 03/12/13 2 5 -- -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/10/13 2 5 -- -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 2 5 -- -- 1 ND ND -- -- 0.497 J ND ND ND ND ND ND ug/L 09/10/14 2 5 0.36 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/09/15 2 5 0.36 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/14/15 2 5 0.36 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/07/16 2 5 0.36 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/13/16 2 5 0.36 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/06/17 2 5 0.45 -- 1 ND 0.738 B -- -- 0.745 B ND ND ND ND ND 0.554 J ug/L 09/11/17 2 5 0.360 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/05/18 2 5 0.360 -- 1 ND ND -- -- ND ND ND ND ND ND ND ug/L 12/11/18 2 5 0.360 1 -- ND ND ND ND ND ND ND ND ND ND ND ug/L 03/05/19 2 5 0.360 1 -- ND ND ND ND ND ND ND ND 0.483 J ND ND (Background Sampling Event) ug/L 07/31/19 2 5 0.360 1 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 2 5 0.360 1 -- ND ND ND ND ND 0.716 J ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 2 5 0.360 1 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 2 5 0.360 1 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 2 5 0.360 1 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 2 5 0.360 1 -- -- -- ND ND -- -- -- -- -- -- ND Chromium ug/L 10/07/09 10 100 -- -- 10 1.00 J ND -- -- 6.61 J 4.87 J ND 10.9 2.72 J 5.32 J ND ug/L 03/16/10 10 100 -- -- 10 ND ND -- -- ND ND ND 12.1 ND 4.9 J ND ug/L 09/07/10 10 100 -- -- 10 ND ND -- -- ND ND ND 15.9 ND 2.9 J ND ug/L 03/23/11 10 100 -- -- 10 1.45 J ND -- -- 7.01 J 13.0 5.98 J 16.5 3.10 J 47.1 ND ug/L 09/12/11 10 100 -- -- 10 1.74 J ND -- -- 8.10 J 4.94 J 1.22 J 14.6 1.24 J 5.15 J ND ug/L 03/12/12 10 100 -- -- 10 ND ND -- -- 5.68 J 4.05 B ND 15.7 B 1.99 J 11.3 B ND ug/L 10/01/12 10 100 -- -- 10 5.18 J ND -- -- 2.71 J 3.08 J ND 15.0 ND 4.05 J ND ug/L 03/12/13 10 100 -- -- 10 1.36 J 1.18 J -- -- ND ND 1.39 J 16.7 ND 3.32 J ND ug/L 09/10/13 10 100 -- -- 10 ND ND -- -- 4.13 J ND ND 20.5 ND 5.29 J ND ug/L 03/11/14 10 100 -- -- 10 1.90 J ND -- -- ND ND ND 23.4 ND 15.3 ND ug/L 09/10/14 10 100 1.40 -- 10 ND ND -- -- 6.53 J 1.97 J ND 14.0 6.06 J 42 ND ug/L 03/09/15 10 100 1.40 -- 10 1.55 J ND -- -- 3.85 J 2.22 J ND 13.6 ND 50.9 ND ug/L 09/14/15 10 100 1.40 -- 10 ND ND -- -- 5.69 J 2.61 J ND 14.5 1.61 J 83.6 ND ug/L 03/07/16 10 100 1.40 -- 10 ND ND -- -- ND ND 1.49 J 11.2 ND 32.6 ND ug/L 09/13/16 10 100 1.40 -- 10 ND ND -- -- ND ND ND 14.3 ND 40.7 ND ug/L 03/06/17 10 100 1.10 -- 10 ND 1.31 J -- -- ND ND 1.92 J 13.9 1.15 J 15.5 ND ug/L 09/11/17 10 100 1.40 -- 10 ND ND -- -- 2.07 J ND ND 11.1 ND 8.79 J ND ug/L 03/05/18 10 100 1.40 -- 10 ND ND -- -- 1.45 J ND ND 10.9 ND 26.2 ND ug/L 12/11/18 10 100 1.40 10 -- ND ND 1.42 J 5.42 J 1.75 J ND 1.72 J 11.2 ND 9.31 J ND ug/L 03/05/19 10 100 1.40 10 -- ND ND 2.92 J 6.93 J ND ND 1.75 J 14.9 ND 14.6 ND (Background Sampling Event) ug/L 07/31/19 10 100 1.40 10 -- -- -- 5.52 J 10.0 -- -- -- -- -- -- ND ug/L 09/23/19 10 100 1.40 10 -- ND ND 3.82 J 7.81 J ND ND 1.61 J 10.7 ND 16.0 ND (Background Sampling Event) ug/L 11/25/19 10 100 1.40 10 -- -- -- 5.76 J 9.77 J -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 10 100 1.40 10 -- -- -- 5.10 J 9.73 J -- -- -- -- -- -- ND ug/L 03/02/20 10 100 1.40 10 -- ND ND 4.83 J 8.42 J ND ND 4.75 J 10.4 ND 10.4 ND (Background Sampling Event) ug/L 05/12/20 10 100 1.40 10 -- -- -- 4.97 J 10.1 -- -- -- -- -- -- ND 4r4> G 0 L D E R 1 of 3 June 2020 TABLE 5 19117535.701 Summary of Detected Constituents in Monitoring Wells Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Closed Closed Active Unlined & Active Detected MonitoringSample p NC2L/ Practical SWS Closed Subtitle D Supplemental Upgradient Unlined Down- Closed Subtitle D Downgradient Subtitle D Down- Constituents/Analytes Units Date IMAC EPA MCL MDL Quantitation Reporting Subtitle D U radient pg gradient gradient Leachate Blanks Limit Limit Upgradient MW-1 RR MW-12 MW-23 MW-24 OW-3 MW-6 MW-7 MW-11 MW-19 Cobalt ug/L 10/07/09 1 -- -- -- 10 ND 1.23 J -- -- 20.5 19.0 20.4 ND 28.0 4.24 J ND ug/L 03/16/10 1 -- -- -- 10 ND ND -- -- 25.6 18.4 4.49 J ND 22.6 4.35 J ND ug/L 09/07/10 1 -- -- -- 10 ND ND -- -- 16.6 15.7 14.9 ND 17.6 2.22 J ND ug/L 03/23/11 1 -- -- -- 10 N D N D -- -- 22.2 17.4 5.23 J N D 31.8 49.0 N D ug/L 09/12/11 1 -- -- -- 10 ND ND -- -- 57.0 17.3 23.9 ND 28.4 2.08 J ND ug/L 03/12/12 1 -- -- -- 10 ND ND -- -- 20.0 15.8 3.84 J ND 33.1 10.8 ND ug/L 10/01/12 1 -- -- -- 10 1.65 J ND -- -- 20.0 14.4 16.1 ND 24.1 2.40 J ND ug/L 03/12/13 1 -- -- -- 10 ND 1.14 J -- -- 19.4 14.5 4.24 J ND 30.6 4.86 J ND ug/L 09/10/13 1 -- -- -- 10 ND ND -- -- 18.3 15.5 4.62 J ND 25.8 5.00 J ND ug/L 03/11/14 1 -- -- -- 10 1.38 J ND -- -- 17.9 16.3 5.10 J ND 22.7 8.56 J ND ug/L 09/10/14 1 -- 1.10 -- 10 ND ND -- -- 15.9 18.0 19.0 ND 22.2 18.3 ND ug/L 03/09/15 1 -- 1.10 -- 10 ND ND -- -- 16.5 17.8 4.71 J ND 30.5 11.8 ND ug/L 09/14/15 1 -- 1.10 -- 10 ND 1.56 B -- -- 15.2 14.8 23.0 ND 23.4 104 ND ug/L 03/07/16 1 -- 1.10 -- 10 ND ND -- -- 12.7 16.0 4.45 J ND 22.5 14.2 ND ug/L 09/13/16 1 -- 1.10 -- 10 ND ND -- -- 10.7 16.5 14.5 ND 22.9 20.0 ND ug/L 03/06/17 1 -- 1.50 -- 10 ND ND -- -- 17.4 14.4 19.4 ND 25.8 8.1 J ND ug/L 09/11/17 1 -- 1.10 -- 10 ND ND -- -- 10.7 14.7 9.72 J ND 27.8 4.7 J ND ug/L 03/05/18 1 -- 1.10 -- 10 ND 1.62 B -- -- 12.8 13.9 16.0 ND 26.3 10.7 ND ug/L 12/11/18 1 -- 1.40 10 -- ND ND ND 1.98 J 10.8 15.2 3.85 J ND 25.1 7.02 J ND ug/L 03/05/19 1 -- 1.40 10 -- ND ND ND ND 16.2 14.4 4.28 J ND 20.3 10.7 ND (Background Sampling Event) ug/L 07/31/19 1 -- 1.40 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 1 -- 1.40 10 -- ND ND ND ND 11.5 17.0 12.7 ND 18.0 23.4 ND (Background Sampling Event) ug/L 11/25/19 1 -- 1.40 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 1 -- 1.40 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 1 -- 1.40 10 -- ND ND ND ND 7.51 J 13.7 4.28 J ND 18.3 6.59 J ND (Background Sampling Event) ug/L 05/12/20 1 -- 1.40 10 -- -- -- ND ND -- -- -- -- -- -- ND Copper ug/L 10/07/09 1000 1300# -- -- 10 ND ND -- -- ND ND ND ND 4.96 J ND ND ug/L 03/16/10 1000 1300# -- -- 10 ND ND -- -- ND ND ND ND 3.77 J ND ND ug/L 09/07/10 1000 1300# -- -- 10 1.67 J ND -- -- ND ND ND ND 2.95 J ND ND ug/L 03/23/11 1000 1300# -- -- 10 2.99 B ND -- -- ND 1.66 B 1.60 B ND 4.74 B 27.8 1.93 J ug/L 09/12/11 1000 1300# -- -- 10 2.96 B ND -- -- ND ND ND ND ND ND 2.06 J ug/L 03/12/12 1000 1300# -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 10/01/12 1000 1300# -- -- 10 5.98 J ND -- -- ND ND ND ND ND ND ND ug/L 03/12/13 1000 1300# -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/10/13 1000 1300# -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 1000 1300# -- -- 10 3.56 J ND -- -- ND ND ND ND ND ND ND ug/L 09/10/14 1000 1300# 1.60 -- 10 ND ND -- -- ND ND ND ND 1.67 J 1.88 J ND ug/L 03/09/15 1000 1300# 1.60 -- 10 1.96 B ND -- -- ND 2.51 B ND ND ND 2.85 B 2.93 J ug/L 09/14/15 1000 1300# 1.60 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/07/16 1000 1300# 1.60 -- 10 ND ND -- -- ND ND ND ND ND 1.76 J ND ug/L 09/13/16 1000 1300# 1.60 -- 10 2.41 B ND -- -- 2.19 B 1.83 B 1.77 B 1.66 B 1.84 B 4.62 B 3.72 J ug/L 03/06/17 1000 1300# 0.87 -- 10 ND ND -- -- ND ND ND ND ND ND 4.67 J ug/L 09/11/17 1000 1300" 1.60 -- 10 ND ND -- -- ND ND 1.68 B ND ND ND 5.64 J ug/L 03/05/18 1000 1300# 1.60 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 12/11/18 1000 1300# 1.60 10 -- ND ND ND ND ND ND 1.65 J ND 1.63 J ND ND ug/L 03/05/19 1000 1300# 1.60 10 -- 1.64 J ND ND ND ND ND ND ND ND 1.92 J ND (Background Sampling Event) ug/L 07/31/19 1000 1300# 1.60 10 -- -- -- 2.10 J 2.36 J -- -- -- -- -- -- ND ug/L 09/23/19 1000 1300# 1.60 10 -- 3.12 B ND ND ND ND ND ND ND ND ND 6.92 J (Background Sampling Event) ug/L 11/25/19 1000 1300# 1.60 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 1000 1300# 1.60 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 1000 1300# 1.60 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 1000 1300# 1.60 10 -- -- -- ND 1.96 J -- -- -- -- -- -- ND Lead ug/L 10/07/09 15 15 -- -- 10 ND ND -- -- 2.46 J 3.05 J ND ND 2.06 J ND ND ug/L 03/16/10 15 15 -- -- 10 ND ND -- -- 3.01 J 3.67 J ND ND ND 2.57 J ND ug/L 09/07/10 15 15 -- -- 10 ND ND -- -- 1.94 J 3.33 J ND ND ND 2.13 J ND ug/L 03/23/11 15 15 -- -- 10 ND ND -- -- ND 4.46 J ND ND 3.22 J 12.6 ND ug/L 09/12/11 15 15 -- -- 10 ND ND -- -- 3.55 J ND ND ND ND ND ND ug/L 03/12/12 15 15 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 10/01/12 15 15 -- -- 10 2.44 J ND -- -- 3.45 J ND ND ND ND ND ND ug/L 03/12/13 15 15 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/10/13 15 15 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 15 15 -- -- 10 ND ND -- -- ND 3.04 J ND ND ND 2.57 J ND ug/L 09/10/14 15 15 2.10 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/09/15 15 15 3.10 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/14/15 15 15 3.10 -- 10 ND ND -- -- ND ND ND ND ND 9.34 J ND ug/L 03/07/16 15 15 3.10 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/13/16 15 15 3.10 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/06/17 15 15 3.10 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/11/17 15 15 3.10 -- 10 ND ND -- -- ND 11.7 ND ND 3.28 J ND ND ug/L 03/05/18 15 15 3.10 -- 10 ND ND -- -- ND 4.40 J ND ND ND ND ND ug/L 12/11/18 15 15 3.10 10 -- ND ND ND ND ND 4.20 J ND ND ND 4.34 J ND ug/L 03/05/19 15 15 3.10 10 -- ND -- ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 07/31/19 15 15 3.10 10 -- -- ND 3.36 J 4.45 J -- -- -- -- -- -- ND ug/L 09/23/19 15 15 3.10 10 -- ND -- ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 15 15 3.10 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 15 15 3.10 10 -- -- ND ND ND -- -- -- -- -- -- ND ug/L 03/02/20 15 15 3.10 10 -- ND -- ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 15 15 3.10 10 -- -- -- ND ND -- -- -- -- -- -- ND Mercury ug/L 10/07/09 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- -- ND ug/L 03/16/10 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- -- ND ug/L 09/07/10 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/23/11 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/12/11 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/12/12 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 10/01/12 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/12/13 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/10/13 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/11/14 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/10/14 1 2 -- -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/09/15 1 2 0.17 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/14/15 1 2 0.17 -- 0.2 ND -- -- -- ND -- -- -- -- 0.341 ND ug/L 03/07/16 1 2 0.17 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/13/16 1 2 0.17 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/06/17 1 2 0.17 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 09/11/17 1 2 0.099 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 03/05/18 1 2 0.15 -- 0.2 ND -- -- -- ND -- -- -- -- ND ND ug/L 12/11/18 1 2 0.15 0.2 -- ND -- ND ND ND -- -- -- -- ND ND ug/L 03/05/19 1 2 0.15 0.2 -- ND -- ND ND ND -- -- -- -- ND ND (Background Sampling Event) ug/L 07/31/19 1 2 0.15 0.2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 1 2 0.15 0.2 -- ND -- ND ND ND -- -- -- -- ND ND (Background Sampling Event) ug/L 11/25/19 1 2 0.15 0.2 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 1 2 0.15 0.2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 1 2 0.15 0.2 -- ND -- ND ND ND -- -- -- -- ND ND (Background Sampling Event) ug/L 05/12/20 1 2 0.15 0.2 -- -- -- ND ND -- -- -- -- -- -- ND Nickel ug/L 10/07/09 100 -- -- -- 50 ND ND -- -- 21.3 J ND ND 8.85 J , 6.66 J 17.8 J ND ug/L 03/16/10 100 -- -- -- 50 ND ND -- -- 20.3 J ND ND 10.1 J 4.64 J 15.9 J ND ug/L 09/07/10 100 -- -- -- 50 ND ND -- -- 17.3 J ND ND 7.42 J 4.21 J 10.6 J ND ug/L 03/23/11 100 -- -- -- 50 1.92 J ND -- -- 24.4 J ND 5.12 8.61 J 7.27 J 65.3 ND ug/L 09/12/11 100 -- -- -- 50 2.09 J ND -- -- 84.6 ND 1.83 7.96 J ' 5.66 J 9.26 J ND ug/L 03/12/12 100 -- -- -- 50 ND ND -- -- 24.3 J ND ND J 8.47 B 6.49 J 12.2 B ND ug/L 10/01/12 100 -- -- -- 50 4.14 B ND -- -- 22.9 J ND 1.83 J 6.34 B 5.23 B 10.3 J 1.95 J ug/L 03/12/13 100 -- -- -- 50 ND ND -- -- 24.3 J ND 2.29 9.02 J 8.59 J 11.1 J ND ug/L 09/10/13 100 -- -- -- 50 ND ND -- -- 24.9 J ND ND B 8.87 J 4.67 J 11.9 J ND ug/L 03/11/14 100 -- -- -- 50 3.29 J ND -- -- 26.2 J ND 2.07 J 11.1 J ' 6.52 J 21.6 J ND ug/L 09/10/14 100 -- 1.80 -- 50 ND ND -- -- 19.5 J ND ND 4.72 J 6.6 J 62.0 ND ug/L 03/09/15 100 -- 1.80 -- 50 ND ND -- -- 23.1 J ND ND J 5.47 J 6.14 J 42.4 J ND ug/L 09/14/15 100 -- 1.80 -- 50 ND ND -- -- 21.7 J ND ND 5.75 J 4.74 J 128 ND ug/L 03/07/16 100 -- 1.80 -- 50 ND ND -- -- 17.9 J ND ND 7.31 J 5.1 J 50.2 ND ug/L 09/13/16 100 -- 1.80 -- 50 ND ND -- -- 15.6 J ND ND 5.94 J ' 5.57 J 61.7 ND ug/L 03/06/17 100 -- 1.10 -- 50 1.17 B 2.77 B -- -- 20.8 J ND 3.04 6.30 B 8.45 B 20.7 J 3.30 (1.79) J ug/L 09/11/17 100 -- 2.20 -- 50 ND ND -- -- 11.6 J ND ND 5.04 J 4.8 J 24.8 J ND ug/L 03/05/18 100 -- 2.20 -- 50 ND ND -- -- 15.8 J ND ND B 5.41 J 7.13 J 37.6 J ND ug/L 12/11/18 100 -- 2.20 10 -- ND ND 6.95 J 3.14 J 16.7 ND ND 7.14 J 8.28 J 20.2 ND ug/L 03/05/19 100 -- 2.20 10 -- ND ND 5.44 J ND 18.5 ND ND 11.0 4.13 J 38.1 ND (Background Sampling Event) ug/L 07/31/19 100 -- 2.20 10 -- -- -- 4.93 J 2.20 J -- -- -- -- -- -- ND ug/L 09/23/19 100 -- 2.20 10 -- ND ND 3.72 J ND 18.6 ND ND ND 4.01 J 37.3 ND (Background Sampling Event) ug/L 11/25/19 100 -- 2.20 10 -- -- -- 5.42 J ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 100 -- 2.20 10 -- -- -- 4.72 J 2.56 J -- -- -- -- -- -- ND ug/L 03/02/20 100 -- 2.20 10 -- ND ND 2.38 J ND 9.21 J ND 2.27 10.8 4.10 J 26.5 ND (Background Sampling Event) ug/L 05/12/20 100 -- 2.20 10 -- -- -- ND ND -- -- -- -- -- -- ND Selenium ug/L 10/07/09 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/16/10 20 50 -- -- 10 ND ND -- -- 7.79 J 1.07 J ND ND ND -- ND ug/L 09/07/10 20 50 -- -- 10 ND ND -- -- 5.13 B ND ND ND ND ND 3.38 J ug/L 03/23/11 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/12/11 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/12/12 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 10/01/12 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/12/13 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/10/13 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 20 50 -- -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/10/14 20 50 5.00 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/09/15 20 50 5.00 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/14/15 20 50 5.00 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/07/16 20 50 6.20 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 09/13/16 20 50 6.20 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/06/17 20 50 10.00 -- 10 ND ND -- -- ND ND ND ND ND ND 11.2 ug/L 09/11/17 20 50 0.910 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/05/18 20 50 6.20 -- 10 ND ND -- -- ND ND ND ND ND ND ND ug/L 12/11/18 20 50 6.20 10 -- ND ND ND ND ND ND ND ND ND ND ND ug/L 03/05/19 20 50 6.20 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 07/31/19 20 50 1.82 2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 20 50 6.20 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 20 50 6.20 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 20 50 6.20 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 20 50 6.20 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 20 50 6.20 10 -- -- -- ND ND -- -- -- -- -- -- ND 4r4> G 0 L D E R 2 of 3 June 2020 TABLE 5 19117535.701 Summary of Detected Constituents in Monitoring Wells Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina Closed Closed Active Unlined & Active Detected MonitoringSample p NC2L/ Practical SWS Closed Subtitle D Supplemental Upgradient Unlined Down- Closed Subtitle D Downgradient Subtitle D Down- Constituents/Analytes Units Date IMAC EPA MCL MDL Quantitation Reporting Subtitle D U radient pg gradient gradient Leachate Blanks Limit Limit Upgradient MW-1 RR MW-12 MW-23 MW-24 OW-3 MW-6 MW-7 MW-11 MW-19 Silver ug/L 10/07/09 20 100 -- -- 10 ND ND -- -- ND 4.27 J ND ND 2.17 J ND ND ug/L 03/16/10 20 100 -- -- 10 ND ND -- -- 2.05 J 2.74 J ND ND ND 5.36 J ND ug/L 09/07/10 20 100 -- -- 10 ND ND -- -- 2.78 J ND ND ND ND ND ND ug/L 03/23/11 20 100 -- -- 10 ND ND -- -- 3.41 J 4.45 J ND ND ND 3.64 J ND ug/L 09/12/11 20 100 -- -- 10 ND ND -- -- 2.21 J 3.88 J ND ND ND ND ND ug/L 03/12/12 20 100 -- -- 10 ND ND -- -- ND 4.15 J ND ND ND 2.81 J ND ug/L 10/01/12 20 100 -- -- 10 ND ND -- -- ND 2.04 J ND ND ND ND ND ug/L 03/12/13 20 100 -- -- 10 ND 2.21 J -- -- 5.03 J 4.51 J ND 1.92 J . 3.46 J 1.99 J ND ug/L 09/10/13 20 100 -- -- 10 ND ND -- -- 3.33 J 3.78 J ND ND ND 2.11 J ND ug/L 03/11/14 20 100 -- -- 10 ND ND -- -- 2.69 J ND ND ND ND ND ND ug/L 09/10/14 20 100 1.90 -- 10 2.91 J 2.21 J -- -- 5.90 J 3.22 J 2.38 ND 2.12 J ND ND ug/L 03/09/15 20 100 1.90 -- 10 ND ND -- -- 2.96 J ND 2.82 ND ND ND ND ug/L 09/14/15 20 100 1.90 -- 10 ND ND -- -- 3.35 J ND ND J ND ND ND ND ug/L 03/07/16 20 100 1.90 -- 10 ND ND -- -- ND ND ND J ND ND ND ND ug/L 09/13/16 20 100 1.90 -- 10 ND ND -- -- ND ND ND ND ND 2.09 J ND ug/L 03/06/17 20 100 0.74 -- 10 ND ND -- -- ND 0.879 J ND ND ND ND ND ug/L 09/11/17 20 100 1.90 -- 10 ND ND -- -- ND 3.46 J ND ND ND ND ND (Verification Event) ug/L 12/20/17 20 100 1.90 -- 10 -- -- -- -- -- -- -- -- -- -- ND ug/L 03/05/18 20 100 1.90 -- 10 ND ND -- -- 5.78 B ND ND ND ND ND 3.85 J ug/L 12/11/18 20 100 1.90 10 -- ND ND ND ND ND ND ND ND ND ND ND ug/L 03/05/19 20 100 1.90 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 07/31/19 20 100 1.90 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 20 100 1.90 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 20 100 1.90 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 20 100 1.90 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 20 100 1.90 10 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 20 100 1.90 10 -- -- -- ND ND -- -- -- -- -- -- ND Thallium ug/L 10/07/09 0.28 2 -- -- 5.5 ND 0.160 J -- -- 0.218 J ND ND ND ND ND ND ug/L 03/16/10 0.28 2 -- -- 5.5 ND ND -- -- 0.194 J ND ND ND ND ND ND ug/L 09/07/10 0.28 2 -- -- 5.5 ND ND -- -- 0.195 J ND ND ND ND 2.61 J ND ug/L 03/23/11 0.28 2 -- -- 5.5 ND ND -- -- ND ND ND ND ND 2.46 J ND ug/L 09/12/11 0.28 2 -- -- 5.5 ND ND -- -- 1.95 J ND ND ND ND 7.84 B ND ug/L 03/12/12 0.28 2 -- -- 5.5 ND ND -- -- 1.20 J 0.148 J ND ND ND ND ND ug/L 10/01/12 0.28 2 -- -- 5.5 ND ND -- -- 0.124 J ND ND ND ND ND ND ug/L 03/12/13 0.28 2 -- -- 5.5 ND ND -- -- 0.117 J ND ND ND ND ND ND ug/L 09/10/13 0.28 2 -- -- 5.5 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/11/14 0.28 2 -- -- 5.5 ND ND -- -- 0.116 J ND ND ND ND ND ND ug/L 09/10/14 0.28 2 0.11 -- 5.5 ND ND -- -- ND ND ND ND ND ND ND ug/L 03/09/15 0.28 2 0.11 -- 5.5 ND ND -- -- ND 0.113 J ND ND ND ND ND ug/L 09/14/15 0.28 2 0.11 -- 5.5 ND ND -- -- 0.127 J ND ND ND ND ND ND ug/L 03/07/16 0.28 2 0.11 -- 5.5 ND ND -- -- 0.118 J ND ND ND ND ND ND ug/L 09/13/16 0.28 2 0.11 -- 5.5 ND ND -- -- 0.118 J ND ND ND ND ND ND ug/L 03/06/17 0.28 2 0.11 -- 5.5 0.455 J ND -- -- 0.430 J 0.643 J 0.169 J 0.266 J . 0.294 J 4.90 J ND ug/L 09/11/17 0.28 2 0.11 -- 5.5 0.335 J 0.141 J -- -- 0.215 J 0.420 J 0.135 J 0.305 J 0.367 J 2.41 J ND ug/L 03/05/18 0.28 2 0.11 -- 5.5 ND ND -- -- 0.242 J 0.132 J ND ND ND ND ND ug/L 12/11/18 0.2 2 0.55 5 -- ND ND ND ND ND ND ND ND ND ND ND ug/L 03/05/19 0.2 2 0.22 2 -- 0.266 J ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 07/31/19 0.2 2 0.220 2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 0.2 2 0.220 2 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 11/25/19 0.2 2 0.220 2 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 0.2 2 0.220 2 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 0.2 2 0.220 2 -- ND ND ND ND ND ND ND ND ND ND ND (Background Sampling Event) ug/L 05/12/20 0.2 2 0.220 2 -- -- -- ND ND -- -- -- -- -- -- ND Tin ug/L 10/07/09 2000 -- -- -- 100 3.75 J -- -- -- 6.16 J -- -- -- -- -- ND ug/L 03/16/10 2000 -- -- -- 100 3.86 J -- -- -- 5.00 J -- -- -- -- -- ND ug/L 09/07/10 2000 -- -- -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 03/23/11 2000 -- -- -- 100 ND -- -- -- 5.63 J -- -- -- -- -- ND ug/L 09/12/11 2000 -- -- -- 100 4.90 J -- -- -- 5.01 J -- -- -- -- -- ND ug/L 03/12/12 2000 -- -- -- 100 4.26 J -- -- -- 4.22 J -- -- -- -- -- ND ug/L 10/01/12 2000 -- -- -- 100 4.46 J -- -- -- 4.45 J -- -- -- -- -- ND ug/L 03/12/13 2000 -- -- -- 100 4.03 J -- -- -- 6.93 J -- -- -- -- -- ND ug/L 09/10/13 2000 -- -- -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 03/11/14 2000 -- -- -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 09/10/14 2000 -- -- -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 03/09/15 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 09/14/15 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- 2.75 J ug/L 03/07/16 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 09/13/16 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 03/06/17 2000 -- 4.20 -- 100 7.50 J -- -- -- 7.07 J -- -- -- -- -- ND ug/L 09/11/17 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- 2.83 J ug/L 03/05/18 2000 -- 2.40 -- 100 ND -- -- -- ND -- -- -- -- -- ND ug/L 12/11/18 2000 -- 2.90 10 -- ND -- ND ND ND -- -- -- -- -- ND ug/L 03/05/19 2000 -- 2.90 10 -- ND -- ND ND ND -- -- -- -- -- 3.46 (Background Sampling Event) ug/L 07/31/19 2000 -- 2.90 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 09/23/19 2000 -- 2.90 10 -- ND -- ND ND ND -- -- -- -- -- 4.62 J (Background Sampling Event) ug/L 11/25/19 2000 -- 2.90 10 -- -- -- ND ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 2000 -- 2.90 10 -- -- -- ND ND -- -- -- -- -- -- ND ug/L 03/02/20 2000 -- 2.90 10 -- ND -- ND ND ND -- -- -- -- -- ND (Background Sampling Event) ug/L 05/12/20 2000 -- 2.90 10 -- -- -- ND ND -- -- -- -- -- -- ND Vanadium ug/L 10/07/09 0.3 -- -- -- 25 2.73 J 2.14 J -- -- ND ND ND ND 6.13 J 3.24 J ND ug/L 03/16/10 0.3 -- -- -- 25 3.11 J 1.83 J -- -- ND ND ND ND 5.23 J 6.48 J ND ug/L 09/07/10 0.3 -- -- -- 25 2.09 J 1.85 J -- -- ND ND ND ND 1.82 J 4.09 J ND ug/L 03/23/11 0.3 -- -- -- 25 3.57 J 2.01 J -- -- ND ND 2.02 J ND 5.19 J 107 ND ug/L 09/12/11 0.3 -- -- -- 25 2.79 J 1.92 J -- -- 4.23 J ND ND ND ND 1.54 J ND ug/L 03/12/12 0.3 -- -- -- 25 2.16 J ND -- -- ND ND ND ND ND 17.3 J ND ug/L 10/01/12 0.3 -- -- -- 25 6.67 J 1.64 J -- -- ND 2.01 J ND ND 2.62 J ND ND ug/L 03/12/13 0.3 -- -- -- 25 1.73 J 1.54 J -- -- ND ND ND ND 2.31 J 3.12 J ND ug/L 09/10/13 0.3 -- -- -- 25 1.81 J 2.21 J -- -- ND ND ND ND 1.73 J ND ND ug/L 03/11/14 0.3 -- -- -- 25 2.61 J 1.65 J -- -- ND ND ND ND 2.45 J 14.5 J ND ug/L 09/10/14 0.3 -- 1.40 -- 25 ND 1.53 J -- -- ND ND ND ND 4.00 J 21.5 J ND ug/L 03/09/15 0.3 -- 1.40 -- 25 1.99 J 1.59 J -- -- ND ND ND ND ND 8.12 J ND ug/L 09/14/15 0.3 -- 1.40 -- 25 2.16 J 2.01 J -- -- ND ND ND ND 4.87 J 96.2 ND ug/L 03/07/16 0.3 -- 1.40 -- 25 ND 2.25 J -- -- ND 2.08 J ND ND 3.09 J 23.0 J ND ug/L 09/13/16 0.3 -- 1.40 -- 25 1.72 J 2.29 J -- -- ND ND ND ND ND 27.3 ND ug/L 03/06/17 0.3 -- 0.50 -- 25 2.13 B 3.63 B -- -- ND 1.17 J 0.965 J 0.997 J 3.54 B 13.5 J .746 (0.50E J ug/L 09/11/17 0.3 -- 1.40 -- 25 ND 1.73 J -- -- ND 3.29 J ND ND 1.76 J 1.64 J ND ug/L 03/05/18 0.3 -- 1.40 -- 25 ND 3.37 B -- -- ND ND ND ND 3.42 B 20.8 J 1.40 ug/L 12/11/18 0.3 -- 1.40 10 -- 1.48 J 1.72 J ND 2.66 J ND 1.94 J ND ND 1.73 J 5.53 J ND ug/L 03/05/19 0.3 -- 1.40 10 -- ND 1.58 J ND 3.02 J ND ND ND ND ND 10.9 ND (Background Sampling Event) ug/L 07/31/19 0.3 -- 1.40 10 -- -- -- 2.45 J 4.22 J -- -- -- -- -- -- ND ug/L 09/23/19 0.3 -- 1.40 10 -- ND 1.86 J ND 3.84 J ND ND ND ND ND 29.3 ND (Background Sampling Event) ug/L 11/25/19 0.3 -- 1.40 10 -- -- -- 3.16 J 3.91 J -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 0.3 -- 1.40 10 -- -- -- ND 5.10 J -- -- -- -- -- -- ND ug/L 03/02/20 0.3 -- 1.40 10 -- ND 1.44 J ND 3.33 J ND ND ND ND ND 8.22 J ND (Background Sampling Event) ug/L 05/12/20 0.3 -- 1.40 10 -- -- -- ND 4.31 J -- -- -- -- -- -- ND Zinc ug/L 10/07/09 1000 5000* -- -- 10 ND ND -- -- 5.17 B 9.62 B 9.40 18.8 B 6.17 J 5.80 B 18.1 ug/L 03/16/10 1000 5000* -- -- 10 ND ND -- -- 6.89 J 5.61 J 6.74 17.6 6.21 J 14.4 ND ug/L 09/07/10 1000 5000* -- -- 10 ND ND -- -- 4.10 J 5.39 J 6.67 B 10.8 10.9 3.86 J ND ug/L 03/23/11 1000 5000* -- -- 10 10.2 ND -- -- 4.81 J ND 8.48 J 11.2 5.90 J 1140 ND ug/L 09/12/11 1000 5000* -- -- 10 ND ND -- -- 31.0 5.99 J 8.48 J 8.67 J ND ND ND ug/L 03/12/12 1000 5000* -- -- 10 ND ND -- -- ND 6.49 J 5.59 J 8.76 J ND 60.6 ND ug/L 10/01/12 1000 5000* -- -- 10 9.65 J ND -- -- ND 7.42 J 8.98 J 7.16 J ND 5.47 J ND ug/L 03/12/13 1000 5000* -- -- 10 ND ND -- -- ND ND 6.42 J 9.20 J. 3.80 J 8.01 J ND ug/L 09/10/13 1000 5000* -- -- 10 ND ND -- -- ND 7.03 J 7.60 J 20.2 4.64 J ND ND ug/L 03/11/14 1000 5000* -- -- 10 12.0 ND -- -- 6.15 J 7.88 J 8.46 J 12.9 4.33 J 21.4 ND ug/L 09/10/14 1000 5000* 3.80 -- 10 ND ND -- -- ND ND 7.72 J 10.9 3.90 J 38.0 ND ug/L 03/09/15 1000 5000* 3.80 -- 10 4.17 J ND -- -- ND 5.43 J 8.34 J 7.93 J ' ND 15.8 ND ug/L 09/14/15 1000 5000* 3.80 -- 10 ND 4.08 J -- -- ND 5.23 J 6.89 J 6.43 J , 4.61 J 426 ND ug/L 03/07/16 1000 5000* 3.80 -- 10 ND ND -- -- ND ND 5.52 J 12.4 ND 34.3 ND ug/L 09/13/16 1000 5000* 3.80 -- 10 ND ND -- -- ND 4.97 J 7.12 J 5.92 J ND 58.7 ND ug/L 03/06/17 1000 5000* 6.30 -- 10 ND ND -- -- ND ND 8.65 J 8.44 J ND 12.0 ND ug/L 09/11/17 1000 5000* 4.40 -- 10 ND ND -- -- 11.4 B ND 14.6 J 14.1 B' ND 8.71 B 8.94 J ug/L 03/05/18 1000 5000* 4.40 -- 10 ND ND -- -- ND ND 7.02 J 6.31 J, ND 14.8 ND ug/L 12/11/18 1000 5000* 4.40 10 -- ND ND 17.8 ND ND ND 5.84 B 7.98 J 13.2 7.54 J ND ug/L 03/05/19 1000 5000* 4.40 10 -- ND ND 13.1 ND ND ND 7.70 J 20.4 ND 18.0 ND (Background Sampling Event) ug/L 07/31/19 1000 5000* 4.40 10 -- -- -- 15.2 ND -- -- -- -- -- -- ND ug/L 09/23/19 1000 5000* 4.40 10 -- 4.81 J ND 10.7 ND 5.93 J ND ND J ND ND 38.8 ND (Background Sampling Event) ug/L 11/25/19 1000 5000* 4.40 10 -- -- -- 13.8 ND -- -- -- -- -- -- ND (Background Sampling Event) ug/L 01/28/20 1000 5000* 4.40 10 -- -- -- 7.20 J ND -- -- -- -- -- -- ND ug/L 03/02/20 1000 5000* 4.40 10 -- ND ND 6.31 J 5.42 J ND 9.17 J 6.37 J 18.8 ND 12.6 ND (Background Sampling Event) ug/L 05/12/20 1000 5000* 4.40 10 -- -- -- 13.3 ND -- -- -- -- -- -- ND Sodium ug/L 03/02/20 -- -- 400 500 -- 8680 4910 2500 10900 86400 10700 -- 2040 1580 267000 ND Iron ug/L 03/02/20 300 300 22 50 -- ND 480 77 145 23600 72200 -- 35.3 J 21400 15700 ND Manganese ug/L 03/02/20 50 50 1.0 2.0 -- 10.2 149 39 21 14400 9070 -- 6.29 1530 2300 ND Calcium ug/L 03/02/20 -- -- 39 100 -- 35900 8030 3230 15800 39200 69600 -- 6500 4280 97300 ND Magnesium ug/L 03/02/20 -- -- 29 100 -- 6400 2800 2190 8350 28500 19700 -- 5520 980 50200 ND Potassium ug/L 03/02/20 -- -- 150 500 -- 4520 1970 2080 1270 10100 6470 -- 1780 283 J 84500 ND Notes: mg/L = milligrams per liter ug/L = micrograms per liter nM = nano mols NC 2L = North Carolina Water Quality Standard IMAC = Interim Maximum Allowable Concentration EPA MCL = United States Environmental Protection Agency Maximum Contaminant Limit J = Prior to the December 2018 event, J flags are estimated values below the SWS Reporting limit B = blank -qualified data ND = not detected above the laboratory detection limit -- = no data or no limit established Beginning with the December 2018 event, J flags are estimated values between MDL and PQL. # = EPA Action Level * = EPA Secondary MCL Blanks = field, trip and method blanks Bold = concentrations above applicable GWPS and/or NC 2L have been bolded. Shaded = concentrations above applicable EPA MCL have been shaded. MDL = laboratory method detection limit Multiple laboratory method blanks were analyzed for barium, nickel, and vanadium during the March 2017 event. The first value in the Blanks column correspond to OW-3, OW-4, OW-10D, Historical data provided consists only of data since October 2009 and is not the complete historical record for the facility. The following diluions were noted for the March 2020 sampling event: antimony and thallium (all points) by 2X and chloride at OW-3 by 14X. OW-12, OW-14D and OW-17D. The second value in the Blanks J GOLDER 3 of 3 June 2020 TABLE 6 USGS National Geochemical Survey Database Summary Hanes mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina 19117535.701 NURE Record ID Lab ID Collection Date Datum Latitude Longitude Medium Source Units Barium Cobalt Chromium 5282810 C-110092 09/12/76 NAD27 35.9952 -80.2418 Sediment Stream ppm 2630 ND 8 5282822 C-110100 09/12/76 NAD27 35.9098 -80.2140 Sediment Stream ppm 1570 ND 3 5282670 C-110270 09/09/76 NAD27 35.9945 -80.0553 Sediment Stream ppm 174 12 7 5282584 C-110403 07/13/76 NAD27 35.9876 -80.5241 Sediment Stream ppm 65 36 79 5289680 C-110410 07/13/76 NAD27 36.2632 -80.2747 Sediment Stream ppm 1000 11 31 5289312 C-110490 07/14/76 NAD27 36.0003 -80.4473 Sediment Stream ppm 348 14 28 5289485 C-110871 07/21/76 NAD27 36.2239 -80.0316 Sediment Stream ppm 684 8 13 5289579 C-143129 07/11/76 NAD27 36.4035 -80.1033 Sediment Stream ppm 267 14 42 5289450 C-143367 07/17/76 NAD27 36.1168 -80.3382 Sediment Stream ppm 294 10 31 5289661 C-143413 07/12/76 NAD27 36.3345 -80.3890 Sediment Stream ppm 464 7 30 5289470 C-143440 07/17/76 NAD27 36.2319 -80.4357 Sediment Stream ppm 1090 5 27 5282800 C-144593 09/12/76 NAD27 35.9375 -80.3027 Sediment Stream ppm 2440 4 16 Average 919 10 26 Notes: 1. NURE = National Uranium Resource Evaluation 2. ID = identification 3. ND = non -detect 4. Inorganic analysis performed by ICP40. 5. ppm = parts per million 6. Sample locations are within 20 miles of the Hanes Mill Road Landfill 7. Source of data is the United States Geological Survey National Geochemical Survey Database. .41I,> GOLDER 10f1 June 2020 TABLE 7 Summary of Statistical Analysis Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina 19117535.701 Detected Monitoring Constituent Reporting Units Groundwater Standard Downgradient Monitoring Well Constituent Concentration Statistical Analysis Statistical Determination NC 2L IMAC Interwell Intrawell Closed Unlined Landfill Downgradient Monitoring Wells and Concentrations Barium ug/L 700 -- OW-3 804 154 -- SSI Cobalt ug/L 10 -- OW-3 7.51 J 1.98 -- SSI Closed Subtitle D Landfill Downgradient Monitoring Wells and Concentrations Chromium ug/L 10 -- MW-11 10.4 10.1 18.9 Not SSI (Intrawell) Cobalt ug/L -- 1 MW-6 13.7 1.98 20.0 Not SSI (Intrawell) MW-7 4.28 J 29.9 Not SSI (Intrawell) Active Subtitle D Landfill Downgradient Monitoring Wells and Concentrations Cobalt ug/L -- 1 1 MW-19 1 18.3 1 1.98 1 -- I SSI, not enough <10NTU data to run intrawell Notes: 1. Statistical worksheets are provided as Appendix C. 2. ug/L = micrograms per liter 3. NC 2L = North Carolina 2L Groundwater Standard 4. IMAC = North Carolina 2L Standard Interim Maximum Allowable Concentration 5. SSI = statistically significant increase 6. ND = not detected above laboratory detection limit 7. -- = not available 8. GPS = statistically calculated groundwater protection standard 9. North Carolina Appendix I Inorganic constituents detected above their respective Solid Waste Section Reporting Limit and Groundwater Standard in samples from downgradient monitoring wells were statistically evaluated. 10. The Previously Proposed GPS are from the May 21, 2018, Response to Alternate Source Demonstration - Request for Additional Information. G 0 L D E R 1of1 June 2020 TABLE 8 Summary of Detected Constituents in Soil Samples Hanes Mill Road Landfill, Permit No. 34-02 19117535.701 PRELIMINARY PRELIMINARY PROTECTION OF RESIDENTIAL INDUSTRIAL GROUNDWATER HEALTH -BASED HEALTH -BASED SOIL BACKGROUND BACKGROUND REMEDIATION REMEDIATION REMEDIATION (SEPTEMBER 12, (JANUARY 27, BACKGROUND PARAMETER UNITS GOALS GOALS GOALS 2013) 2016) (JULY 19, 2016) Barium mg/kg dry 3000 44000 580 66.1 125 148 Chromium mg/kg dry 24000 1000000 360000 37.1 37.2 49.2 Cobalt mg/kgmg/kg dry 4.6 70 0.9 5.26 15.7 14.7 Notes: mg/kg = milligrams per kilogram ND = not detected above laboratory method detection limit J = estimated concentration below the laboratory method reporting limit B = blank qualified -- = no data available S.U. = Standard Units Blanks = method blanks Bold = concentration exceeds Preliminary Residential Health -Based Remediation Goal Highlighted = concentration exceeds Protection of Groundwater Soil Remediation Goal " = concentration exceeds Preliminary Industial Health -Based Remediation Goal 1) Preliminary Residential and Industrial Health -Based Remediation Goals and Protection of Groundwater Soil Remediation Goals are from the Inactive Hazardous Sites Branch Preliminary Soil Remediation Goals Table, February 2013. 2) Background September 12, 2013 is from Golder, 2013. 3) Background January 27, 2016 is from Golder, February 2016. 4) Background July 19, 2016 is from Golder, August 2016. . 4,,> GOLDER 1 of 1 June 2020 TABLE 9 Summary of Partitioning Calculations Using Published Partitioning Coefficients Hanes Mill Road Landfill, Permit No. 34-02 Forsyth County, North Carolina 19117535.701 Kd* (mL/g) Calculated Groundwater Concentration (ug/L) MaximumObserved Minimum Maximum Soil Concentration Calculated Calculated Constituent Boring ID / Sample Name Burkhard Heuel- Stenge and Burkhard Heuel- Stenge and Concentration in (mg/kg) Allison and Allison EPA Allison and Allison EPA Groundwater Groundwater Fabianek Peterson Fabianek Peterson Compliance Well Concentration Concentration (ug/L) (ug/L) (ug/L) BACKGROUND (SEPTEMBER 12, 2013) 66.1 19441 -- 1612 125 Barium . . . . . . . . . . . . . . . . BACKGROUND (JANUARY 27, 2016) . . . . . . . 125 3.4 -- 41 530 . . . . . . . 36765 . . . . . . . -- . . . . . . . 3049 . . . . . . . 236 125 297561 1460 BACKGROUND (JULY 19, 2016) 12200 3588235 -- 297561 23019 BACKGROUND (SEPTEMBER 12, 2013) 37.1 9513 530 0.021 221 Chromium BACKGROUND (JANUARY 27, 2016) 37.2 3.9 70 1800000 168 9538 531 0.021 221 0.021 703 23.4 BACKGROUND (JULY 19, 2016) 49.2 12615 703 0.027 293 BACKGROUND (SEPTEMBER 12, 2013) 5.26 2505 87.7 117 2711 Cobalt BACKGROUND (JANUARY 27, 2016) 15.7 2.1 60 45 1.94 7476 262 349 8093 87.7 8093 57.0 BACKGROUND (JULY 19, 2016) 14.7 7000 245 327 7577 Notes: mg/kg = milligrams per kilogram ND = Not detected at or above the laboratory detection limit BGS = below ground surface Kd = soil to groundwater partitioning coefficient Kd values are from the following sources: 1. Partition Coefficients for Metals in Surface Water, Soil, and Waste (Allison and Allison, 2005) 2. Partition Coefficients (Kd) for the Modelling of Transport Processes of Radionuclides in Groundwater (Burkhard Heuel-Fabianek, 2014) 3. Regional Screening Levels (RSLs) - Generic Tables (EPA, 2018) 4. Chemical Data Bases for the Multimedia Environmental Polluntant Assessment System (MEPAS): Version 1 (Stenge and Peterson, 1989) ,,Iw> G0LDEF 1 of 1 Drawing 00 3 a a 0 N 0 0� 00 rn (M m 0 E m Z i7 04 N 00 NI L y Q d 3 3 sZ Y N N 0 0 U a E 0 • _ — • iam • iL1WO 797.10 GRASSY CREEK �j� •• '' -- � �� --- �� ;1 � : `►�� =sus .�,^�,,,.r- �� • - y „ ► - • • �r j WIN �� �,,, ,,w�►,,.:._ ,,,•,mow � ,.--�'""`_� �''�,. .er I - ME * FA • O I p� U Vim/ PIP L -..' 'EMBER 12, 1 : '• . �• i •i p '1 IC WIN I %rl MrW y i EXISTING 10-FOOT GROUND SURFACE CONTOUR EXISTING 2-FOOT GROUND SURFACE CONTOUR VICINITY MAP 10000 10000 20000 APPROXIMATE LIMITS OF WASTE SCALE FEET �.� PROPERTY LINE EXISTING ROAD 810 GROUNDWATER ELEVATION 10 FT CONTOURS GROUNDWATER FLOW ARROW o OW-3 MONITORING WELL AND IDENTIFICATION 811.92 ❑ SW-1 SURFACE WATER MONITORING POINT - H METHANE MONITORING POINT �- NM NOT MEASURED SOIL SAMPLE AND IDENTIFICATION NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET E3 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET 3. GROUNDWATER ELEVATIONS MEASURED ON MARCH 02, 2020. 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION (� FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, 1 ( GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5. GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL. THE GROUNDWATER FLOW DIRECTION IS GENERALLY PERPENDICULAR TO THE GROUNDWATER SURFACE CONTOURS, SIMILAR TO THE RELATIONSHIP L BETWEEN SURFACE WATER FLOW AND TOPOGRAPHIC CONTOURS. 6. BASE MAP PROVIDED BY BRADY SURVEYING COMPANY BASED ON JANUARY 4, 2013 AERIAL SURVEY. TOPOGRAPHY AND OTHER EXISTING SITE FEATURES INSIDE OF DASHED LINE UPDATED BASED ON L JANUARY 5, 2019 AERIAL SURVEY. I 7. COORDINATE SYSTEM IS N.C. STATE PLANE GRID. � 250 250 500 L SCALE FEET WINSTON SALEM / FORSYTH COUNTY CITY / COUNTY UTILITIES COMMISSION TOPOGRAPHY AND OTHER EXISTING SITE FEATURES INSIDE PROJECT DASHED LINE BASED ON JANUARY HANES MILL ROAD LANDFILL JANUARY 6, 2016 AERIAL SURVEY. EXISTING CONDITIONS OUTSIDE PERMIT NO. 34-02 OF DASHED LINE BASED ON JANUARY 4, 2014 AERIAL SURVEY. FORSYTH COUNTY, NORTH CAROLINA GROUNDWATER SURFACE CONTOUR MAP MARCH 02, 2020. II // CONSULTANT YYYY-MM-DD 2020-04-02 PREPARED HAC G 0 L D E R DESIGN NTT I REVIEW DYR GOLDER ASSOCIATES NC, INC. APPROVED R P K PROJECT No. PHASE DRAWING 19117535 701 0 L F L 1 i 0 APPENDIX A Time Series Plots WQStat Plus" v.9.4.32 2000 1600 1200 J 800 400 0 10/7/09 Time Series 11 /20/11 1 /2/14 2/15/16 3/30/18 5/12/20 Constituent: Barium Analysis Run 6/17/2020 9:45 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables ♦ MW-12 (bg) ■ MW-1 RR (bg) MW-23 (bg) ♦ MW-24 (bg) ♦ OW-3 ♦ Leachate WQStat Plus" v.9.4.32 Hollow symbols indicate censored values Time Series 90 72 54 J 7 36 18 11 /19/11 1 /1 /14 2/14/16 3/29/18 5/12/20 Constituent: Chromium Analysis Run 6/17/2020 9:46 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables ♦ MW-12 (bg) ■ MW-1 RR (bg) MW-23 (bg) ♦ MW-24 (bg) ♦ MW-11 ♦ Leachate WQStat Plus" v.9.4.32 Hollow symbols indicate censored values. 110 88 66 J 44 22 Time Series 11 /18/11 12/31 /13 2/14/16 3/29/18 5/12/20 Constituent: Cobalt Analysis Run 6/23/2020 9:58 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables MW-12 (bg) MW-1 RR (bg) MW-23 (bg) MW-24 (bg) OW-3 MW-11 MW-6 MW-19 Leachate MW-7 APPENDIX B Sen's Slope Estimator Plots WQStat Plus" v.9.4.32 2000 1600 1200 J 800 400 0 10/7/09 Sen's Slope Estimator OW-3 • • • n=18 Slope = -22 units per year. Mann -Kendall statistic = -64 critical = -63 Decreasing trend significant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Barium Analysis Run 6/17/2020 10:00 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 20 16 12 J 8' 4 0 10/6/09 Sen's Slope Estimator MW-11 • n=19 Slope =-0.3075 units per year. Mann -Kendall statistic = -67 critical = -68 Trend not sig- nificant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Chromium Analysis Run 6/17/2020 9:56 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables n=19 Slope =-0.3075 units per year. Mann -Kendall statistic = -67 critical = -68 Trend not sig- nificant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Chromium Analysis Run 6/17/2020 9:56 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Hollow symbols indicate censored values. 60 48 36 J 24 12 Sen's Slope Estimator OW-3 • a 0 10/7/09 n=18 Slope = -1.419 units per year. Mann -Kendall statistic = -94 critical = -63 Decreasing trend significant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Cobalt Analysis Run 6/17/2020 10:00 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 20 16 12 J 8' 4 0 10/6/09 Sen's Slope Estimator MW-6 • • • • • • n=21 Slope =-0.2812 units per year. Mann -Kendall statistic = -91 critical = -78 Decreasing trend significant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Cobalt Analysis Run 6/17/2020 10:01 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 30 24 18 J 12 6 0 10/6/09 Sen's Slope Estimator MW-7 • • . • • . • n=22 Slope =-0.08624 units per year. Mann -Kendall statistic = -30 critical = -84 Trend not sig- nificant at 98% confidence level (a = 0.01 per tail). 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Cobalt Analysis Run 6/23/2020 9:56 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 30 24 18 J 0) 12 6 0 4- 9/12/17 Sen's Slope Estimator MW-19 n = 5 Slope = -4.492 units per year. Mann -Kendall statistic = -8 critical = -10 Trend not sig- nificant at 98% confidence level (a = 0.01 per tail). 3/11 /18 9/7/18 3/7/19 9/3/19 3/2/20 Constituent: Cobalt Analysis Run 6/17/2020 10:01 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables APPENDIX C Laboratory Certificates -of - Analysis ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, June 2, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.403, Project Name/Desc: Hanes Mill LF- Active Sub D ENCO Workorder(s): CD03413 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, March 6, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 2 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW32 Lab ID: CD03413-01 Sampled: 03/03/20 09:45 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/30/20 03/09/20 09:10 03/12/20 12:18 EPA 6020E EPA 3005A 08/30/20 03/09/20 09:37 03/13/20 05:46 Client ID: 3402-MW19 Lab ID: CD03413-08 Sampled: 03/05/20 13:30 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 09/01/20 03/09/20 09:10 03/12/20 13:13 Client ID: 3402-MW19 Lab ID: CD03413-08RE1 Sampled: 03/05/20 13:30 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6020B EPA 3005A 09/01/20 03/09/20 09:37 05/12/20 12:42 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 12 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW32 Lab ID: CD03413-01 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 8030 39.0 100 ug/L EPA 6010D Iron - Total 480 22.0 50.0 ug/L EPA 6010D Magnesium - Total 2800 29.0 100 ug/L EPA 6010D Manganese - Total 149 1.00 2.00 ug/L EPA 6020E Potassium - Total 1970 150 500 ug/L EPA 6010D Sodium - Total 4910 400 500 ug/L EPA 6010D Client ID: 3402-MW39 Lab ID: CD03413-08 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 4280 39.0 100 ug/L EPA 6010D Iron - Total 21400 22.0 50.0 ug/L EPA 6010D Magnesium - Total 980 29.0 100 ug/L EPA 6010D Potassium - Total 283 J 150 500 ug/L EPA 6010D Sodium - Total 1580 400 500 ug/L EPA 6010D Client ID: 3402-MW39 Lab ID: CD03413-08RE3 Analvte Results Flag MDL PQL Units Method Notes Manganese - Total 1530 D 10.0 20.0 ug/L EPA 6020E FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 12 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW12 Lab Sample ID:CDO3413-01 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/03/20 09:45 Work Order: CD03413 Project: Hanes Mill LF- Active Sub D Sampled By: Nicolas Tejada/Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units LF MDL POLL Batch Method Analyzed Ay Notes Calcium [7440-70-2]^ 8030 ug/L 1 39.0 100 0009010 EPA 6010D 03/12/20 12:18 JDH Iron [7439-89-6]^ 480 ug/L 1 22.0 50.0 0009010 EPA 6010D 03/12/20 12:18 JDH Magnesium [7439-95-4]^ 2800 ug/L 1 29.0 100 0009010 EPA 6010D 03/12/20 12:18 JDH Manganese [7439-96-5]^ 149 ug/L 2 1.00 2.00 0009013 EPA 6020B 03/13/20 05:46 RLF Potassium [7440-09-7]^ 1970 ug/L 1 150 500 0009010 EPA 6010D 03/12/20 12:18 JDH Sodium [7440-23-5]^ 4910 ug/L 1 400 500 0009010 EPA 6010D 03/12/20 12:18 JDH Description: 3402-MW19 Lab Sample ID:CDO3413-08 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/05/20 13:30 Work Order: CD03413 Project: Hanes Mill LF- Active Sub D Sampled By: Nicolas Tejada/Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed By Notes Calcium [7440-70-2]^ 4280 ug/L 1 39.0 100 0009010 EPA 6010D 03/12/20 13:13 JDH Iron [7439-89-6]^ 21400 ug/L 1 22.0 50.0 0009010 EPA 6010D 03/12/20 13:13 JDH Magnesium [7439-95-4]^ 980 ug/L 1 29.0 100 0009010 EPA 6010D 03/12/20 13:13 JDH Manganese [7439-96-5]^ 1530 D ug/L 20 10.0 20.0 OE04025 EPA 6020E 05/12/20 12:42 RLF Potassium [7440-09-7]^ 283 J ug/L 1 150 500 0009010 EPA 6010D 03/12/20 13:13 JDH Sodium [7440-23-5]^ 1580 ug/L 1 400 500 0009010 EPA 6010D 03/12/20 13:13 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 12 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O1O - EPA 3OO5A Blank (0009010-BLK1) Prepared: 03/09/2020 09:10 Analyzed: 03/12/2020 11:42 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0009010-BSI) Prepared: 03/09/2020 09:10 Analyzed: 03/12/2020 11:58 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 1970 100 ug/L 2000 99 80-120 Iron 948 50.0 ug/L 1000 95 80-120 Magnesium 1940 100 ug/L 2000 97 80-120 Potassium 9740 500 ug/L 10000 97 80-120 Sodium 9710 500 ug/L 10000 97 80-120 Matrix Spike (0009010-MS1) Prepared: 03/09/2020 09:10 Analyzed: 03/12/2020 12:01 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 21300 100 ug/L 2000 20100 58 75-125 QM-07 Iron 991 50.0 ug/L 1000 102 89 75-125 Magnesium 8810 100 ug/L 2000 7360 73 75-125 QM-07 Potassium 11700 500 ug/L 10000 2130 96 75-125 Sodium 15600 500 ug/L 10000 6160 94 75-125 Matrix Spike Dup (0009010-MSD1) Prepared: 03/09/2020 09:10 Analyzed: 03/12/2020 12:04 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 21700 100 ug/L 2000 20100 80 75-125 2 20 Iron 1020 50.0 ug/L 1000 102 92 75-125 3 20 Magnesium 9120 100 ug/L 2000 7360 88 75-125 3 20 Potassium 12000 500 ug/L 10000 2130 98 75-125 2 20 Sodium 15800 500 ug/L 10000 6160 97 75-125 2 20 Post Spike (0009030-PSI) Prepared: 03/09/2020 09:10 Analyzed: 03/12/2020 12:07 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 21.5 0.100 mg/L 2.00 20.1 69 80-120 QM-08 Iron 1.10 0.0500 mg/L 1.00 0.102 100 80-120 Magnesium 8.80 0.100 mg/L 2.00 7.36 72 80-120 QM-08 Potassium 12.3 0.500 mg/L 10.0 2.13 102 80-120 Sodium 16.1 0.500 mg/L 10.0 6.16 99 80-120 Batch OCO9O13 - EPA 3OO5A Blank (0009013-BLK3) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:16 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese FINAL 0.500 U 1.00 ug/L This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 12 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O13 - EPA 3OO5A - Continued LCS (0009013-BS3) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:21 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 197 1.00 ug/L 200 99 80-120 Matrix Spike (0009013-MS1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:25 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 387 2.00 ug/L 400 3.02 96 75-125 Matrix Spike Dup (0009013-MSD1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:29 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 386 2.00 ug/L 400 3.02 96 75-125 0.03 20 Post Spike (0009013-PS1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:33 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 214 1.00 ug/L 200 1.51 106 75-125 Batch OEO4O25 - EPA 3OO5A Blank (OE04025-BLK3) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 11:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (OE04025-BS1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 11:59 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 220 1.00 ug/L 200 110 80-120 Matrix Spike (OE04025-MS1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:03 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 4660 E 1.00 ug/L 200 9070 NR 75-125 QM-07, QM-16 Matrix Spike Dup (OE04025-MSD1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:07 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 4220 E 1.00 ug/L 200 9070 NR 75-125 10 20 QM-07, QM-16 Post Spike (OE04025-PS3) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:12 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Manganese 4250 E 1.00 ug/L 200 9070 NR 75-125 QM-08, QM-16 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 12 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-16 Matrix spike recovery could not be calculated due to high concentration of analyte in source sample. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 of 12 I 7J f C 2z N N N N o N N N N N v v m A C'Y m m 3 2 a FD W s a m O O w m a (A W- A L" " cr m m t,> 0 0 a - v CDn ? w n o w p CD J m G) 0 8 C> W C3 G_ _ _ 1 C, G _ NNN _ CN § afp, _ - C7� _ ( o T Fif m 4 , Q CD C C G L � n � -4 r V -4 -1 rl V -1 'd V --4 n x x x x x x x x x x x 0 x x x x x x x x x x x � O O o � e � 6 1 826M Appendix 1,82501) SIM ID AaAS,80,80.Cd,Co,Cr,Cu,N I, Pb.Sb.Se, SA TI, V,Zn 1 ,0 °Nz N o n < 4, T j m O A Z �m z r n C N O f11 � � n SP o z ��w r �xn m o Ili A & S O m M -a o �O m rn 0 n z O n o m a £ � = O JvJ Q 1 �p C w m rn n C7 O N m v C, 0 Cr o Z cn w O (U P � cc C {p '3O p NCD x cn w' m � y _! Q T- n a W � Q n. � a Page 9 of 12 c y � w m m � � n ro y D n L a \ D n 6 � f � � m m' w o � � 3 � a 8 6 Q m m J� C6 m = Ln a W C+ m P w fA 2 W F 3 rn m m 0 C CD N N a n CA ro N G Ptr U] n In a m (F) n :r 0) c n, n W V 00 0 4 vaom = �Z N q a C N 9 C ro m cq 0 +•� a� v� ffi� M �. vQ 3 3 X= �,W r o� � 0 a a, m co CD D � � x cp o @ v 0 N ..J cr O z ❑ y W � ca m ro w M N � p O X X 82600 Appendix 1,62600 SIM ID m m rn A&As,S&,9e, Cd,Co, Cr,Cu,Nl,i$,5b,Se, Se,T I,V,Zn 0 2 a z z 0 W N 7 U7 7U A o C y CL n N n 0 v x v q a A m ro 4 0 N 0 v r :E ID 01 CD 3 WA fV X .�°° a CD A 0 3 Q- w C = a ° a Page 10 of 12 Sample Preservation Verification ENCO Cary Work Order: CD03413 Project: Client: Golder Associates, Inc. (G0007) Project #: Logged In: 06-Mar-20 13:54 �t Logged By: John C King Preservation Check Performed By: 4 1 Date/Time CD03413-01 ccO Hanes Mill LF- Active Sub D 19117535.403 Coat Type Pres (pH) Requirement pH Checked ! In Contrnl Datefrime pH Adjusted Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 Y I N/ NA Y I t(�y ! NA C D03413-02 Conn Type Pres (pH) Requirement pH Checked / In Control pH Adjusted Dateff1 ' Adjusted Reagent UsedlComments A 250mLP+HNO3 <2 ! N I NA Y 1 ,-N / NA C D03413-03 Conn Type Pres (pH) Requirement pH Checked / In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 (Y_, 1 N / NA Y /(NJ I NA C D03413-04 Cont Type Pres (PH) pH Checked I pH Adjusted DateFTm.e Reagent Used/Comments Requirement A Control Adjusted A 250mLP+HNO3 <2 Y I N / NA Y ! ,N / NA CD03413-05 Cora Type Pres (pH) Requirement pH Checked / In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 `(1 N / NA Y IL�V! NA B 250mLP+HNO3 <2 1 N/ NA Y 1 / NA CD03413-06 Cont Type Pres (PH) Requirement pH Checked / In Control pH Adjusted DatelTme Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 `Y 1 N / NA Y ! N '1 NA C D03413-07 Cont 'Type Pres (PH) Requirement pH Checked / In Control DateMme Adjusted pH Adjusted Reagent UsedlComments A 250mLP+HNO3 <2 / N / NA Y / ,) / NA CD03413-08 Co.J.. Type Pres (PH) pH Checked / pH Adjusted DateiTime Reagent Used/Comments Requirement n Control Adjusted A 250mLP+HNO3 <2 Y I N/ NA Y /0 ! NA C:IELMNTIPrintlwko_Preservation Check. rpt I Page 11 of 12 Sample Preservation Verification ENCO Cary Work Order: CD03413 Project: Hanes Mill LF- Active Sub D Client: Golder Associates, Inc. (GO007) Project #: 19117535.403 Logged In: 06-Mar-20 13:54 _ Logged By: John C King / Preservation Check Performed By: t"~ Date/Time: �6' 20 / kL' CD03413-09 Cont Type Pres (pH) Requirement pH Checked/ In Control pH Adjusted DatelTime Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 1 1 N 1 NA Y INN 1 NA CD03413-10 Cont Type Pres (pH) pH Checked I pH Adjusted DatelTme Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y I N I NA Y! I NA C D03413-11 Cont Ty0e Pres (pH) pH Checked / pH Adjusted Date/Tit e Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y! N I NA Y I ,N; 1 NA CD03413-12 Cont Type Pres (pH) pH Checked 1 pH Adjusted DateMme Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y 1 N/ NA Y! 1 NA C003413-13 Cont Type Pres (pH) pH Checked / pH Adjusted Daterrime Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y''! N / NA Y 1;N 1 NA C D03413-15 Cont Type Pres (PH) Requirement PH Checked ! in Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 [F] <2 1 N 1 NA Y 1 L� 1 NA CD03413-16 Cont Type Pres (pH) Requirement PH Checked f In Control pH Adjusted DateMme Adjusted Reagent Used/Comments A 250mLP+HNO3 [F] <2 - 1 N 1 NA Y /& / NA Rea ent Name ID 1 2 pH Strip ID:}/'�� Reagent Name ID 3 4 Reacient Name ID 5 6 C:IELMNTIPrintlwko_Preservation Check. rpt I Page 12 of 12 ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.102, Project Name/Desc: Hanes Mill LF- Closed Sub D ENCO Workorder(s): CD03415 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, March 6, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW6 (MS/MSD) Lab ID: CD03415-01 Sampled: 03/05/20 10:36 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 09/01/20 03/09/20 09:22 03/13/20 10:53 EPA 6010D EPA 3005A 09/01/20 03/09/20 09:22 03/13/20 11:03 Client ID: 3402-MW6 (MS/MSD) Lab ID: CD03415-01RE3 Sampled: 03/05/20 10:36 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6020E EPA 3005A 09/01/20 03/09/20 09:45 05/12/20 12:46 Client ID: 3402-MW11 Lab ID: CD03415-06 Sampled: 03/03/20 13:12 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/30/20 03/09/20 09:22 03/13/20 11:42 EPA 6020E EPA 3005A 08/30/20 03/09/20 09:45 03/13/20 04:38 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW6 (MS/MSD) Lab ID: CD03415-01 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 69600 39.0 100 ug/L EPA 6010D Iron - Total 72200 22.0 50.0 ug/L EPA 6010D Magnesium - Total 19700 29.0 100 ug/L EPA 6010D Potassium - Total 6470 150 500 ug/L EPA 6010D Sodium - Total 10700 400 500 ug/L EPA 6010D Client ID: 3402-MW6 (MS/MSD) Lab ID: CD03415-01RE3 Analvte Results Flag MDL PQL Units Method Notes Manganese - Total 9070 D 10.0 20.0 ug/L EPA 6020E Client ID: 3402-MW31 Lab ID: CD03415-06 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 6500 39.0 100 ug/L EPA 6010D Iron - Total 35.3 1 22.0 50.0 ug/L EPA 6010D Magnesium - Total 5520 29.0 100 ug/L EPA 6010D Manganese - Total 6.29 1.00 2.00 ug/L EPA 6020E Potassium - Total 1780 150 500 ug/L EPA 6010D Sodium - Total 2040 400 500 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 11 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW6 (MS/MSD) Lab Sample ID:CDO3415-01 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/05/20 10:36 Work Order: CD03415 Project: Hanes Mill LF- Closed Sub D Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units LF MDL POLL Batch Method Analyzed Ay Notes Calcium [7440-70-2]^ 69600 ug/L 1 39.0 100 0009011 EPA 6010D 03/13/20 10:53 JDH Iron [7439-89-6]^ 72200 ug/L 1 22.0 50.0 0009011 EPA 6010D 03/13/20 11:03 JDH Magnesium [7439-95-4]^ 19700 ug/L 1 29.0 100 0009011 EPA 6010D 03/13/20 11:03 JDH Manganese [7439-96-5]^ 9070 D ug/L 20 10.0 20.0 0009014 EPA 6020B 05/12/20 12:46 RLF Potassium [7440-09-7]^ 6470 ug/L 1 150 500 0009011 EPA 6010D 03/13/20 11:03 JDH Sodium [7440-23-5]^ 10700 ug/L 1 400 500 0009011 EPA 6010D 03/13/20 11:03 JDH Description: 3402-MWll Lab Sample ID:CDO3415-06 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/03/20 13:12 Work Order: CD03415 Project: Hanes Mill LF- Closed Sub D Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed By Notes Calcium [7440-70-2]^ 6500 ug/L 1 39.0 100 0009011 EPA 6010D 03/13/20 11:42 JDH Iron [7439-89-6]^ 35.3 J ug/L 1 22.0 50.0 0009011 EPA 6010D 03/13/20 11:42 JDH Magnesium [7439-95-4]^ 5520 ug/L 1 29.0 100 0009011 EPA 6010D 03/13/20 11:42 JDH Manganese [7439-96-5]^ 6.29 ug/L 2 1.00 2.00 0009014 EPA 6020E 03/13/20 04:38 RLF Potassium [7440-09-7]^ 1780 ug/L 1 150 500 0009011 EPA 6010D 03/13/20 11:42 JDH Sodium [7440-23-5]^ 2040 ug/L 1 400 500 0009011 EPA 6010D 03/13/20 11:42 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 11 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O11 - EPA 3OO5A Blank (0009011-BLK1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 10:29 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L Blank (0009011-BLK2) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 10:32 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0009011-BS3) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:06 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 2000 100 ug/L 2000 100 80-120 Iron 970 50.0 ug/L 1000 97 80-120 Magnesium 1940 100 ug/L 2000 97 80-120 Potassium 9730 500 ug/L 10000 97 80-120 Sodium 9710 500 ug/L 10000 97 80-120 Matrix Spike (0009011-MS1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:09 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 72900 100 ug/L 2000 69600 164 75-125 QM-07 Iron 73000 50.0 ug/L 1000 72200 82 75-125 Magnesium 22400 100 ug/L 2000 19700 133 75-125 QM-07 Potassium 16500 500 ug/L 10000 6470 101 75-125 Sodium 20900 500 ug/L 10000 10700 101 75-125 Matrix Spike Dup (0009011-MSD1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:12 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 72100 100 ug/L 2000 69600 123 75-125 1 20 Iron 93800 50.0 ug/L 1000 72200 NR 75-125 25 20 QM-07 Magnesium 22000 100 ug/L 2000 19700 113 75-125 2 20 Potassium 16500 500 ug/L 10000 6470 100 75-125 0.2 20 Sodium 20800 500 ug/L 10000 10700 101 75-125 0.3 20 Post Spike (0009011-PS1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:16 111 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 70.7 0.100 mg/L 2.00 69.6 52 80-120 QM-08 Iron 73.3 0.0500 mg/L 1.00 72.2 107 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 11 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O11 - EPA 3OO5A - Continued Post Spike (0009011-PS1) Continued Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:16 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Magnesium 21.9 0.100 mg/L 2.00 19.7 109 80-120 Potassium 16.7 0.500 mg/L 10.0 6.47 102 80-120 Sodium 20.9 0.500 mg/L 10.0 10.7 102 80-120 Batch OCO9O14 - EPA 3OO5A Blank (0009014-BLK3) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:28 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (0009014-BS1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:32 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 192 1.00 ug/L 200 96 80-120 Matrix Spike (0009014-MS1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:37 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 8010 E 2.00 ug/L 400 7400 153 75-125 QM-07, QM-16 Matrix Spike (0009014-MS2) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:41 Source: CD04266-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 819 2.00 ug/L 400 425 99 75-125 Matrix Spike Dup (0009014-MSD1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:45 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 7670 E 2.00 ug/L 400 7400 69 75-125 4 20 QM-07, QM-16 Matrix Spike Dup (0009014-MSD2) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:49 Source: CD04266-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 806 2.00 ug/L 400 425 95 75-125 2 20 Post Spike (0009014-PSI) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:54 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 3800 E 1.00 ug/L 200 3700 52 75-125 QM-08, QM-16 Batch OEO4O25 - EPA 3OO5A FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 11 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OEO4O25 - EPA 3OO5A - Continued Blank (OE04025-BLK1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 11:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L Matrix Spike (OE04025-MS1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:03 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 4660 E 1.00 ug/L 200 9070 NR 75-125 QM-07, QM-16 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 11 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-16 Matrix spike recovery could not be calculated due to high concentration of analyte in source sample. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of 11 0 3 f a m x v x m n D a m N \' v 1 y c H e c � c m Ja y v n m m N O m m N W W m OR n a a n -g @ m w 6 n CD sy m CJ� cr tt CD - � 3 N 13 --7 w G7 a c�► 3 O O O t7 Ctt� Q 3 OD rip 1O,� lO �_ m m Ln W S 5 S -4 V J s CD 0) n Q Z �S C) Ga t/lj r - m w N A ^-- N� � � W •-, m O � d 11l lam,,• tyli-��• v = O R1 2 Z a •.�- ? n '*�' o to m m i 3 ^J Y /\ 0 Y/`/ ,�j m m ? X D L cc X perp' Q r V u A V V •mil o, m N O UNMOOR ■©©©©l 8260DAppendix 1,8260D SIM ID Ag,As•BIa,Be,Cd,Cio Cr,Cu,NI,Pb,Sh,S®, 8sj1,V,Zn m ea [7 � d D Q V W a � a N � N v � h r � CO III O n m ]y � In c (d + ID ( m x c a D m r CD dC �r d CD - Page 10 of 11 Sample Preservation Verification ENCO Cary Work Order: CD03415 Project: Client: Golder Associates, Inc. (G0007) Project #: Logged In: 06-Mar-20 14,04 _ Logged By: Preservation Check Performed By: CDO3415-01 Hanes Mill LF- CIcsed Sub D 19117535.102 John C King Date/Time: Cont Type Pres (pH) pH Checked / pH Adjusted Date/Time Reagent Used/Comments In Control Adjusted A 250mLP+HNO3 <2 Y- / N ! NA Y IZ I NA B 250mLP+HNO3 <2 I N I NA Y 1�o 1 NA CD03415-02 Cont Type Pres (pH) Requirement pH Checked / In Control pH Adjusted Date/Time Reagent Used/Comments Adjusted A 250mLP+HNO3 <2 IY rl N / NA Y /:•T4, / NA CD03415-03 Cont Type. Pres (pH) Requirement pH Checked 1 I -Ip Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 / N / NA Y NA CD03415-04 Cant Type Pres (pH) Requirement pH Checked / In Control pH Adjusted DatelTime Adrusted Reagent Used/Comments A 250mLP+HNO3 <2 Y!/ N / NA Y ILv / NA CD03415-05 Cont Type Pres (pH) Requirement pH Checked/ In Control Tim Datele pH Adjusted Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 I N / NA Y I NA CD03415-06 Cont Type Pres (pH) Requirement pH Checked 1 In Control pH Adjusted DatelTime Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 (Y)1 N I NA Y I NA Rea ent Name ID 1 2 pH Strip ID: Reagent Name ID 3 4 Reagent Name ID 5 6 C IELMNT1PrmtlwkoWPreservationCheck. rpt Page 11 of 11 ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.401, Project Name/Desc: Hanes Mill LF- Closed Unlined ENCO Workorder(s): CD03416 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, March 3, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 9 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW1RR Lab ID: CD03416-01 Sampled: 03/02/20 14:25 Received: 03/03/20 13:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/29/20 EPA 6020E EPA 3005A 08/29/20 03/04/20 09:04 03/06/20 10:41 03/04/20 09:40 03/04/20 16:41 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 9 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW1RR Lab ID: CD03416-01 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 35900 39.0 100 ug/L EPA 6010D Magnesium - Total 6400 29.0 100 ug/L EPA 6010D Manganese - Total 10.2 1.00 2.00 ug/L EPA 6020E Potassium - Total 4520 150 500 ug/L EPA 6010D Sodium - Total 8680 400 500 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 9 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MWlRR Lab Sample ID:CDO3416-01 Received: 03/03/20 13:30 Matrix: Ground Water Sampled:03/02/20 14:25 Work Order: CD03416 Project: Hanes Mill LF- Closed Unlined Sampled By: Nicolas Tejada/Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed Ay Notes Calcium [7440-70-2]^ 35900 ug/L 1 39.0 100 0003040 EPA 6010D 03/06/20 10:41 JDH Iron [7439-89-6]^ 22.0 U ug/L 1 22.0 50.0 0003040 EPA 6010D 03/06/20 10:41 JDH Magnesium [7439-95-4]^ 6400 ug/L 1 29.0 100 0003040 EPA 6010D 03/06/20 10:41 JDH Manganese [7439-96-5]^ 10.2 ug/L 2 1.00 2.00 0004029 EPA 6020B 03/04/20 16:41 RLF Potassium [7440-09-7]^ 4520 ug/L 1 150 500 0003040 EPA 6010D 03/06/20 10:41 JDH Sodium [7440-23-5]^ 8680 ug/L 1 400 500 0003040 EPA 6010D 03/06/20 10:41 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 of 9 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO3O4O - EPA 3OO5A Blank (0003040-BLK1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:35 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L Blank (0003040-BLK2) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:38 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0003040-BS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:45 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 2040 100 ug/L 2000 102 80-120 Iron 992 50.0 ug/L 1000 99 80-120 Magnesium 1980 100 ug/L 2000 99 80-120 Potassium 9890 500 ug/L 10000 99 80-120 Sodium 9880 500 ug/L 10000 99 80-120 Matrix Spike (0003040-MS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:48 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 37100 100 ug/L 2000 35900 57 75-125 QM-07 Iron 1010 50.0 ug/L 1000 22.0 U 101 75-125 Magnesium 7980 100 ug/L 2000 6400 79 75-125 Potassium 14200 500 ug/L 10000 4520 97 75-125 Sodium 18300 500 ug/L 10000 8680 96 75-125 Matrix Spike Dup (0003040-MSD1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:51 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 37200 100 ug/L 2000 35900 62 75-125 0.3 20 QM-07 Iron 914 50.0 ug/L 1000 22.0 U 91 75-125 10 20 Magnesium 8050 100 ug/L 2000 6400 82 75-125 0.8 20 Potassium 14100 500 ug/L 10000 4520 96 75-125 0.5 20 Sodium 18300 500 ug/L 10000 8680 96 75-125 0.4 20 Post Spike (0003040-PS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:53 111 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 36.9 0.100 mg/L 2.00 35.9 45 80-120 QM-08 Iron 1.02 0.0500 mg/L 1.00 0.0150 100 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) Of 9 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO3O4O - EPA 3OO5A - Continued Post Spike (0003040-PS1) Continued Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:53 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Magnesium 8.09 0.100 mg/L 2.00 6.40 84 80-120 Potassium 14.6 0.500 mg/L 10.0 4.52 101 80-120 Sodium 18.8 0.500 mg/L 10.0 8.68 101 80-120 Batch OCO4O29 - EPA 3OO5A Blank (0004029-BLK3) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:11 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (0004029-BS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:16 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 196 1.00 ug/L 200 98 80-120 Matrix Spike (0004029-MS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:20 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 467 2.00 ug/L 400 71.6 99 75-125 Matrix Spike Dup (0004029-MSD1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:24 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 461 2.00 ug/L 400 71.6 97 75-125 1 20 Post Spike (0004029-PS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:29 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 235 1.00 ug/L 200 35.8 100 75-125 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 9 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 of 9 E n V VF ,Y 0 V CJ ' CC) OID c U) W 7p(1f? C] ' \ ¢ P - s a 0' O N 90 4 EMS 001 m U m 4 00E 8l`•' ns U d Z•£9£ XON m m OHo 1"1 2 ul Z•C9C N 9E OWN'DO£ ePPOILIO m d � a U �z'n'IL`�s`as o oS R$`4ci'IN'�3 rJ d'3'CJ oB's8'�Y �tl xFo at wls a0azs PeP��xa �° ODM' b xlpuoddv cowl; V. o � .� �o � U G •E x � y � U G LL y. m Cr) 3 (D f m Ln N o ° � n U a e- m C U N Cj b g l a 4! r Z m m = pp m CJ Lai '�4 p w S 0 0 a = d d ¢ to � N N 1 0 40 Q CD ((t •�, N z r c C n � �, MEM� m off' or^ a Q] d n� ¢ m c U a a U I 0 2 �F a m a Z ¢ v m m m m m a M o ro a a u m c N I a N Q N c v c c ¢ c S 4 U E ! „ 0 m m d Q � o m � � ro � aCo d � � CL E I Page 8 of f Sample Preservation Verification ENCO Cary Work Order: CD03416 Project: Client: Golder Associates, Inc. (GO007) Project # Logged In: 03-Mar-20 15:12 Logged By: Preservation Check Performed By: ' JW C D03416-01 Hanes Mill LF- Closed Unlined 19117535.401 Rachel Ann Yonish Date/Time: � Z� Cont yp Type #gyres (pH) Requirement pH Checked ! In Control ❑ateMime PH Adjusted Adjusted Reagent Used/Comments B 250mLP+H2SO4 <2 N A. NA Y / ^ / NA C 250mLP+HNO3 <2 Y 1 N I NA Y 1 N/ NA Rea ent Name ID 1 2 pH Strip ID: PH Strips COA0898 Rea ent Name ID 3 4 Rea ent Name ID 5 6 C,lelmnt\Prir ,G�%=i vationGheck.rpt I Page 9 of 9 1 ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.403, Project Name/Desc: Hanes Mill LF- Leachate ENCO Workorder(s): CD03418 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Tuesday, March 3, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of O (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-Leachate Lab ID: CD03418-01 Sampled: 03/02/20 15:35 Received: 03/03/20 13:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/29/20 EPA 6020E EPA 3005A 08/29/20 03/04/20 09:04 03/06/20 11:35 03/04/20 09:40 03/04/20 17:11 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 10 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-Leachate Lab ID: CD03418-01 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 97300 39.0 100 ug/L EPA 6010D Iron - Total 15700 22.0 50.0 ug/L EPA 6010D Magnesium - Total 50200 29.0 100 ug/L EPA 6010D Manganese - Total 2300 D 5.00 10.0 ug/L EPA 6020E Potassium - Total 84500 150 500 ug/L EPA 6010D Sodium - Total 267000 400 500 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 10 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-Leachate Lab Sample ID:CDO3418-01 Received: 03/03/20 13:30 Matrix: Waste Water Sampled:03/02/20 15:35 Work Order: CD03418 Project: Hanes Mill LF- Leachate Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed Ay Notes Calcium [7440-70-2]^ 97300 ug/L 1 39.0 100 0003040 EPA 6010D 03/06/20 11:35 JDH Iron [7439-89-6]^ 15700 ug/L 1 22.0 50.0 0003040 EPA 6010D 03/06/20 11:35 JDH Magnesium [7439-95-4]^ 50200 ug/L 1 29.0 100 0003040 EPA 6010D 03/06/20 11:35 JDH Manganese [7439-96-5]^ 2300 D ug/L 10 5.00 10.0 0004029 EPA 6020B 03/04/20 17:11 RLF Potassium [7440-09-7]^ 84500 ug/L 1 150 500 0003040 EPA 6010D 03/06/20 11:35 JDH Sodium [7440-23-5]^ 267000 ug/L 1 400 500 0003040 EPA 6010D 03/06/20 11:35 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 10 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO3O4O - EPA 3OO5A Blank (0003040-BLK1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:35 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L Blank (0003040-BLK2) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:38 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0003040-BS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:45 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 2040 100 ug/L 2000 102 80-120 Iron 992 50.0 ug/L 1000 99 80-120 Magnesium 1980 100 ug/L 2000 99 80-120 Potassium 9890 500 ug/L 10000 99 80-120 Sodium 9880 500 ug/L 10000 99 80-120 Matrix Spike (0003040-MS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:48 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 37100 100 ug/L 2000 35900 57 75-125 QM-07 Iron 1010 50.0 ug/L 1000 22.0 U 101 75-125 Magnesium 7980 100 ug/L 2000 6400 79 75-125 Potassium 14200 500 ug/L 10000 4520 97 75-125 Sodium 18300 500 ug/L 10000 8680 96 75-125 Matrix Spike Dup (0003040-MSD1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:51 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 37200 100 ug/L 2000 35900 62 75-125 0.3 20 QM-07 Iron 914 50.0 ug/L 1000 22.0 U 91 75-125 10 20 Magnesium 8050 100 ug/L 2000 6400 82 75-125 0.8 20 Potassium 14100 500 ug/L 10000 4520 96 75-125 0.5 20 Sodium 18300 500 ug/L 10000 8680 96 75-125 0.4 20 Post Spike (0003040-PS1) Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:53 111 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 36.9 0.100 mg/L 2.00 35.9 45 80-120 QM-08 Iron 1.02 0.0500 mg/L 1.00 0.0150 100 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 10 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO3O4O - EPA 3OO5A - Continued Post Spike (0003040-PS1) Continued Prepared: 03/04/2020 09:04 Analyzed: 03/06/2020 10:53 Source: CD03416-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Magnesium 8.09 0.100 mg/L 2.00 6.40 84 80-120 Potassium 14.6 0.500 mg/L 10.0 4.52 101 80-120 Sodium 18.8 0.500 mg/L 10.0 8.68 101 80-120 Batch OCO4O29 - EPA 3OO5A Blank (0004029-BLK3) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:11 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (0004029-BS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:16 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 196 1.00 ug/L 200 98 80-120 Matrix Spike (0004029-MS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:20 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 467 2.00 ug/L 400 71.6 99 75-125 Matrix Spike Dup (0004029-MSD1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:24 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 461 2.00 ug/L 400 71.6 97 75-125 1 20 Post Spike (0004029-PS1) Prepared: 03/04/2020 09:40 Analyzed: 03/04/2020 16:29 Source: CD03417-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 235 1.00 ug/L 200 35.8 100 75-125 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 10 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 of O E 0 V N 0 u r_ G7 3 0 cc 0 0 LLI cc 0 M U LL 0 z U N w 0 h Q Q 0 Q J Z 0 i W fN Z 0 U Z LU 2 z 0 cc Z LiJ U c m _0 c� F M m k Y U `MO a ° VI � �F� in w F �'�} _w "r EM 41 � m m N 0 37 ❑ (n H •r z .n r 1 J€ Q p � n � n in U � rt _ y Qo'tgZWS SSl ooe ej "„G jInvC r 3 O y �E ZT99- N 3O AIIJVN (`N $ c i o "_ OH U d nQ a a t/l Q w ° DozZ9WS Goo "IV BUM48 008 z r C U E N m N E o E o 2 5 m d`Z'£9£ XON� L'09£ ef�w'd ueA*WQs XipueddV 409Z9 V a in p C V N N � b E ro y V a r 0 �m o m a (r!� C m CL v v m IT�p us E T C V G J C C C m O z Z_ L) r i r o &. rn� U w q a o CL O a s m m m a N � Gi a m N 4 a a m N ° z � U W Off( o w m p [V J� d a � U a d m m 1i N 117 a v o N a: ] n 0 17 E 0 m �ti C 0 V L13o Q v E E Q Page 9of10 Sample Preservation Verification ENCO Cary FJ�ICO Work Order: CD03418 Client: Golder Associates, Inc. (G0007) Project: Hanes Mill LF- Leachate Project # 19117535,403 Logged In: 03-Mar-20 14:58 -- -- Logged By: Rachel Ann Yonish Preservation Check Performed By: CD03418-01 Cont Type Pies (pH) Requirement pH Checked/ In Control pH Adjusted DateMme Adjusted Reagent Used/Comments D 250mLP+H2SO4 <2 1 Y Y N 1. NA Y �' ! NA E 250mLP+HNO3 <2 Y N / NA Y NI1 NA Reacient Name ID 1 2 pH Strip ID: PH Strips COA089$ C:Ielmnt%Pril _.....--- ,,,0=1VCJL1VM neck.rpt Reagent Name ID 3 4 Rea ent Name ID 5 6 Page 10 of 10 ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.405, Project Name/Desc: Hanes Mill LF- Upgradient Wells ENCO Workorder(s): CD03419 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, March 6, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of O (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW23 Lab ID: CD03419-01 Sampled: 03/04/20 10:59 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/31/20 03/09/20 09:22 03/13/20 11:45 EPA 6020E EPA 3005A 08/31/20 03/09/20 09:45 03/13/20 04:42 Client ID: 3402-MW24 Lab ID: CD03419-02 Sampled: 03/04/20 13:40 Received: 03/06/20 13:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/31/20 03/09/20 09:22 03/13/20 11:48 EPA 6020E EPA 3005A 08/31/20 03/09/20 09:45 03/13/20 04:46 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 10 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW23 Lab ID: CD03419-01 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 3230 39.0 100 ug/L EPA 6010D Iron - Total 76.8 22.0 50.0 ug/L EPA 6010D Magnesium - Total 2190 29.0 100 ug/L EPA 6010D Manganese - Total 39.0 1.00 2.00 ug/L EPA 6020E Potassium - Total 2080 150 500 ug/L EPA 6010D Sodium - Total 2500 400 500 ug/L EPA 6010D Client ID: 3402-MW24 Lab ID: CD03419-02 Analvte Results Flag MDL PQL Units Method Notes Calcium - Total 15800 39.0 100 ug/L EPA 6010D Iron - Total 145 22.0 50.0 ug/L EPA 6010D Magnesium - Total 8350 29.0 100 ug/L EPA 6010D Manganese - Total 21.3 1.00 2.00 ug/L EPA 6020E Potassium - Total 1270 150 500 ug/L EPA 6010D Sodium - Total 10900 400 500 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 10 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW23 Lab Sample ID:CDO3419-01 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/04/20 10:59 Work Order: CD03419 Project: Hanes Mill LF- Upgradient Wells Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units LF MDL POLL Batch Method Analyzed Ay Notes Calcium [7440-70-2]^ 3230 ug/L 1 39.0 100 0009011 EPA 6010D 03/13/20 11:45 JDH Iron [7439-89-6]^ 76.8 ug/L 1 22.0 50.0 0009011 EPA 6010D 03/13/20 11:45 JDH Magnesium [7439-95-4]^ 2190 ug/L 1 29.0 100 0009011 EPA 6010D 03/13/20 11:45 JDH Manganese [7439-96-5]^ 39.0 ug/L 2 1.00 2.00 0009014 EPA 6020B 03/13/20 04:42 RLF Potassium [7440-09-7]^ 2080 ug/L 1 150 500 0009011 EPA 6010D 03/13/20 11:45 JDH Sodium [7440-23-5]^ 2500 ug/L 1 400 500 0009011 EPA 6010D 03/13/20 11:45 JDH Description: 3402-MW24 Lab Sample ID:CDO3419-02 Received: 03/06/20 13:45 Matrix: Ground Water Sampled:03/04/20 13:40 Work Order: CD03419 Project: Hanes Mill LF- Upgradient Wells Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed By Notes Calcium [7440-70-2]^ 15800 ug/L 1 39.0 100 0009011 EPA 6010D 03/13/20 11:48 JDH Iron [7439-89-6]^ 145 ug/L 1 22.0 50.0 0009011 EPA 6010D 03/13/20 11:48 JDH Magnesium [7439-95-4]^ 8350 ug/L 1 29.0 100 0009011 EPA 6010D 03/13/20 11:48 JDH Manganese [7439-96-5]^ 21.3 ug/L 2 1.00 2.00 0009014 EPA 6020E 03/13/20 04:46 RLF Potassium [7440-09-7]^ 1270 ug/L 1 150 500 0009011 EPA 6010D 03/13/20 11:48 JDH Sodium [7440-23-5]^ 10900 ug/L 1 400 500 0009011 EPA 6010D 03/13/20 11:48 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 10 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O11 - EPA 3OO5A Blank (0009011-BLK1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 10:29 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L Blank (0009011-BLK2) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 10:32 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0009011-BS3) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:06 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 2000 100 ug/L 2000 100 80-120 Iron 970 50.0 ug/L 1000 97 80-120 Magnesium 1940 100 ug/L 2000 97 80-120 Potassium 9730 500 ug/L 10000 97 80-120 Sodium 9710 500 ug/L 10000 97 80-120 Matrix Spike (0009011-MS1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:09 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 72900 100 ug/L 2000 69600 164 75-125 QM-07 Iron 73000 50.0 ug/L 1000 72200 82 75-125 Magnesium 22400 100 ug/L 2000 19700 133 75-125 QM-07 Potassium 16500 500 ug/L 10000 6470 101 75-125 Sodium 20900 500 ug/L 10000 10700 101 75-125 Matrix Spike Dup (0009011-MSD1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:12 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 72100 100 ug/L 2000 69600 123 75-125 1 20 Iron 93800 50.0 ug/L 1000 72200 NR 75-125 25 20 QM-07 Magnesium 22000 100 ug/L 2000 19700 113 75-125 2 20 Potassium 16500 500 ug/L 10000 6470 100 75-125 0.2 20 Sodium 20800 500 ug/L 10000 10700 101 75-125 0.3 20 Post Spike (0009011-PS1) Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:16 111 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 70.7 0.100 mg/L 2.00 69.6 52 80-120 QM-08 Iron 73.3 0.0500 mg/L 1.00 72.2 107 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 10 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO9O11 - EPA 3OO5A - Continued Post Spike (0009011-PS1) Continued Prepared: 03/09/2020 09:22 Analyzed: 03/13/2020 11:16 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Magnesium 21.9 0.100 mg/L 2.00 19.7 109 80-120 Potassium 16.7 0.500 mg/L 10.0 6.47 102 80-120 Sodium 20.9 0.500 mg/L 10.0 10.7 102 80-120 Batch OCO9O14 - EPA 3OO5A Blank (0009014-BLK3) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:28 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (0009014-BS1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:32 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 192 1.00 ug/L 200 96 80-120 Matrix Spike (0009014-MS1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:37 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 8010 E 2.00 ug/L 400 7400 153 75-125 QM-07, QM-16 Matrix Spike (0009014-MS2) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:41 Source: CD04266-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 819 2.00 ug/L 400 425 99 75-125 Matrix Spike Dup (0009014-MSD1) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:45 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 7670 E 2.00 ug/L 400 7400 69 75-125 4 20 QM-07, QM-16 Matrix Spike Dup (0009014-MSD2) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:49 Source: CD04266-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 806 2.00 ug/L 400 425 95 75-125 2 20 Post Spike (0009014-PSI) Prepared: 03/09/2020 09:45 Analyzed: 03/13/2020 03:54 Source: CD03415-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 3800 E 1.00 ug/L 200 3700 52 75-125 QM-08, QM-16 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 10 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-16 Matrix spike recovery could not be calculated due to high concentration of analyte in source sample. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 of 10 E D V N •V D V 3 (1) U, 016 O Q m s 0 J a � u ZJ m LL � O F W cc Lu U) z O U LJ r LU O 2 t N z�� Occ m r N LL 0 7 (.i ° � a Z ry m 0 wl ? 6 0 u ,6 -0 a N N N L N h L C m I Uj L U ( D LU o ir Y E z � N N m ID 9 � � Q U a iA g 5 U v ¢ ffi c a 2 m c IL m � O U OH x x Uz11I uS'0S x x J O � C a ° o ~ U v J n. m 0 to c� J LLLO N G � a U E r m 7 8 rn I ry V d m U aL a IZ Q7 N - m ~ � U Go � CD C"3 U ~ v o C: N m L Z 0d m ULa O u lL T m S S D ¢ E N CV o N 7F I I I I m r1 a a I C`0 / M / m V co , E E E ocnoMo d ro L) � U n Q o X a c U C' 3 3 0 v d m Sr �• m 'v Q 2 cr E E E R N m m m ° - l v c � m —A— � r.. 1 u ❑ C C7— a b m �3 m m t vPL ¢ .� LL � O7 ie u E Page 9 of 1 m Sample Preservation Verification ENCO Cary ENCO Work Order: CD03419 Client: Golder Associates, Inc. (G0007) Project: Hanes Mill LF- Upgradient Wells Project #: 19117535,405 Logged In: 06-Mar-20 14:08 ! Logged By: Rachel Ann Yonis f Preservation Check Performed By: W - Date/Time:_�� 1��ZZ� CD03419-01 Cont Type Pres (pH) Requirement pH Checked / In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 42 Y/ N/ •NA Y N I NA CD03419-02 Cont Type Pres (pH) pH Checked i pH Adjusted Date/Tirne Reagent Used/Comments Requirement In Contro3 Adjusted A 250mLP+HNO3 <2 Y !1 N / NA Y /� N ,I/ NA Rea ent Name ID 1 2 pH Strip ID: PH Strips COA0898 Rea ent Name ID 3 4 Reacient Name ID 5 6 C:lelmntlPrii..ivY�u_r- reservation Check, rpt IPage 10 of 10 1 )*, ENCO Laboratories Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.401, Project Name/Desc: Hanes Mill LF- Closed Unlined MNA ENCO Workorder(s): CD04050 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, March 4, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 11 (��Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-OW3 Lab ID: CD04050-01 Sampled: 03/03/20 10:40 Received: 03/04/20 13:20 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 08/30/20 03/05/20 13:56 03/11/20 14:10 Client ID: 3402-OW3 Lab ID: CD04050-01RE1 Sampled: 03/03/20 10:40 Received: 03/04/20 13:20 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6020B EPA 3005A 08/30/20 03/09/20 09:37 05/12/20 13:07 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 11 (��Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-OW3 Lab ID: CD04050-01 Anal a Results Flaa MDL Q Units Method Notes Calcium - Total 39200 39.0 100 ug/L EPA 6010D Iron - Total 23600 22.0 50.0 ug/L EPA 6010D Magnesium - Total 28500 29.0 100 ug/L EPA 6010D Potassium - Total 10100 150 500 ug/L EPA 6010D Sodium - Total 86400 400 500 ug/L EPA 6010D Client ID: 3402-OW3 Lab ID: CD04050-01RE1 Anal a Results Flaa MDL Q Units Method Notes Manganese - Total 14400 D 20.0 40.0 ug/L EPA 6020B FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 11 (��Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-OW3 Lab Sample ID:CD04050-01 Received: 03/04/20 13:20 Matrix: Ground Water Sampled:03/03/20 10:40 Work Order: CD04050 Project: Hanes Mill LF- Closed Unlined MNA Sampled By: Erik Vasko Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed _By Notes Calcium [7440-70-2]^ 39200 ug/L 1 39.0 100 0005037 EPA 6010D 03/11/20 14:10 ]DH Iron [7439-89-6]^ 23600 ug/L 1 22.0 50.0 0005037 EPA 6010D 03/11/20 14:10 ]DH Magnesium [7439-95-4]^ 28500 ug/L 1 29.0 100 0005037 EPA 6010D 03/11/20 14:10 ]DH Manganese [7439-96-5]^ 14400 D ug/L 40 20.0 40.0 OE04025 EPA 6020B 05/12/20 13:07 RLF Potassium [7440-09-7]^ 10100 ug/L 1 150 500 0005037 EPA 6010D 03/11/20 14:10 ]DH Sodium [7440-23-5]^ 86400 ug/L 1 400 500 0005037 EPA 6010D 03/11/20 14:10 ]DH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 5 Of 11 (��Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO5O37 - EPA 3OO5A Blank (0005037-BLKI) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:20 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L Blank (0005037-BLK2) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:24 Spike Source %REC RPD Analvte Result Flao POL Units Level Result %REC Limits RPD Limit Notes Calcium 39.0 U 100 ug/L Iron 22.0 U 50.0 ug/L Magnesium 29.0 U 100 ug/L Potassium 150 U 500 ug/L Sodium 400 U 500 ug/L LCS (0005037-BS1) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:31 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Calcium 1850 100 ug/L 2000 93 80-120 Iron 897 50.0 ug/L 1000 90 80-120 Magnesium 1900 100 ug/L 2000 95 80-120 Potassium 9500 500 ug/L 10000 95 80-120 Sodium 9420 500 ug/L 10000 94 80-120 Matrix Spike (0005037-MS1) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:34 Source: CD02316-06 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Calcium 59500 100 ug/L 2000 60100 NR 75-125 QM-07 Iron 3240 50.0 ug/L 1000 2670 57 75-125 QM-07 Magnesium 19000 100 ug/L 2000 17500 72 75-125 QM-07 Potassium 11000 500 ug/L 10000 2280 87 75-125 Sodium 19600 500 ug/L 10000 11200 85 75-125 Matrix Spike Dup (0005037-MSD1) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:37 Source: CD02316-06 Spike Source %REC RPD Analvte Result Flao POL Units Level Result %REC Limits RPD Limit Notes Calcium 63600 100 ug/L 2000 60100 177 75-125 7 20 QM-07 Iron 3530 50.0 ug/L 1000 2670 87 75-125 9 20 Magnesium 19500 100 ug/L 2000 17500 101 75-125 3 20 Potassium 11500 500 ug/L 10000 2280 92 75-125 4 20 Sodium 20600 500 ug/L 10000 11200 94 75-125 5 20 Post Spike (0005037-PS1) Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:40 Source: CD02316-06 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Calcium 61.6 0.100 mg/L 2.00 60.1 77 80-120 QM-08 Iron 3.54 0.0500 mg/L 1.00 2.67 87 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 6 of 11 www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OCO5O37 - EPA 3OO5A - Continued Post Spike (0005037-PSI) Continued Prepared: 03/05/2020 13:56 Analyzed: 03/11/2020 12:40 Source: CD02316-06 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Magnesium 19.2 0.100 mg/L 2.00 17.5 86 80-120 Potassium 11.9 0.500 mg/L 10.0 2.28 96 80-120 Sodium 20.6 0.500 mg/L 10.0 11.2 95 80-120 Batch OCO9O13 - EPA 3OO5A Blank (0009013-BLKI) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:16 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (0009013-BS1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:21 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Manganese 197 1.00 ug/L 200 99 80-120 Matrix Spike (0009013-MS1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:25 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flao POL Units Level Result %REC Limits RPD Limit Notes Manganese 387 2.00 ug/L 400 3.02 96 75-125 Matrix Spike Dup (0009013-MSD1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:29 Source: CD03413-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 386 2.00 ug/L 400 3.02 96 75-125 0.03 20 Post Spike (0009013-PS1) Prepared: 03/09/2020 09:37 Analyzed: 03/13/2020 05:33 Source: CD03413-OS Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Manganese 214 1.00 ug/L 200 1.51 106 75-125 Batch OEO4O25 - EPA 3OO5A Blank (OE04025-BLK3) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 11:47 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Manganese 0.500 U 1.00 ug/L LCS (OE04025-BSI) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 11:59 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 220 1.00 ug/L 200 110 80-120 Matrix Spike (OE04025-MS1) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:03 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 11 (��Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OEO4O25 - EPA 3OO5A - Continued Matrix Spike (OE04025-MS3) Continued Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:03 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Manganese 4660 E 1.00 ug/L 200 9070 NR 75-125 QM-07, QM-16 Matrix Spike Dup (OE04025-MSD3) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:07 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Manganese 4220 E 1.00 ug/L 200 9070 NR 75-125 10 20 QM-07, QM-16 Post Spike (OE04025-PS3) Prepared: 05/04/2020 13:11 Analyzed: 05/12/2020 12:12 Source: CD03415-01RE1 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Manganese 4250 E 1.00 ug/L 200 9070 NR 75-125 QM-08, QM-16 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 1 1 (��Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-16 Matrix spike recovery could not be calculated due to high concentration of analyte in source sample. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of 11 o 3 a_ N J Cl � � a m Tq 4— 8 m a m C. w m m m ' m b o a 0 M ow 0 B N 3 J_ a r' a a � C c0i � tD D w C*' � m v w o c m a1 m ro n - CDcr r (D m n N � a n n n tli 0 4 N 'D a)N ii A. I,. 0 (D O d m p =N m g Q �V v � m CD- CD asa o � ET a N N o n m m r) m N z b f'-' LA, n S Q Ti s Q g Ci a j PL c a� A m = m v� m' x x X X x x 82600 Appvndlx 1,826M o EAended,826W SIM ID v_ x K }� x }{ AgARB*,BQ,Cd,Cn,C.,Cu,Ni,Pb,$p,$e, 0 SASn,TI,V,Zn n x x X x X X Chloride 300,Nk to as N 353.2 v ado �� n x X X x x x Hg a �zs x x x x x x NOX 353.2 w a N. �Q 0 A �a x x x x x x Sulfate 300 I'FTOC W b x X x x x SM531OB I � p C Y [!3 W al O w m n .. m c CD t h o n 3 c) x � 3 ro p N y CD� o `" 3CD w 1 CL ^I� Page 10 of 11 Sample Preservation Verification ENCO Cary Work Order: CD04050 Project: Hanes Mill LF- Closed Unlined MNA Client: Golder Associates, Inc. (00007) Project # 19117535.401 Logged In: 04-Mar-20 14:32 Logged By: John C King Preservation Check Performed By: DatelTime: C D04050-01 Conn Type Pres (pH) pFl Checked / pH Adjusted Dateff`ime Reagent Used/Comments Requirement In Control Adjusted B 250mLP+H2SO4 <2 Y,-/ N / NA Y / / NA C 254mLP+HNO3 <2 d ! N / NA Y /, !' / NA CD04050-02 Cont Type Pres (pH) pH Checked / In Control pH Adjusted Datef ime Adjusted Reagent Used/Comments B 250mLP+H2304 —Requirement <2 l N / NA Y / / NA C 250mLP+HNO3 <2 Y / N / NA Y / ! NA Reagent Name ID 1 2 pH Strip ID:{»-� O _ Reaclent Name ID 3 4 Rea ent Name ID 5 6 C;IELMNTIPrintlwko_Preservation Check. rpt Page 11 of 11 } ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.405, Project Name/Desc: Hanes Mill LF- Upgradient Wells ENCO Workorder(s): CD07885 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, May 15, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 3 PROJECT NARRATIVE Date: 1 June 2020 Client: Golder Associates, Inc. (G0007) Project: Hanes Mill LF- Upgradient Wells Lab ID: CD07885 Overview (� �Eo www.encolabs.com Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in the QC Remarks section below. Quality Control Samples No Comments Selenium exceeded upper control limit for the continuing calibration verification sample. No Comments Other Comments The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of the report. Released By: Environmental Conservation Laboratories, Inc. Daniel Mays Project Manager FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 of 13 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW23 Lab ID: CD07885-01 Sampled: 05/12/20 15:30 Received: 05/15/20 13:15 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 11/08/20 05/22/20 11:14 05/27/20 13:26 EPA 6020E EPA 3005A 11/08/20 05/26/20 12:13 05/29/20 15:48 EPA 7470A EPA 7470A 06/09/20 05/20/20 12:50 05/21/20 16:59 Client ID: 3402-MW24 Lab ID: CD07885-02 Sampled: 05/12/20 16:40 Received: 05/15/20 13:15 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 11/08/20 05/22/20 11:14 05/27/20 13:28 EPA 6020E EPA 3005A 11/08/20 05/26/20 12:13 05/29/20 15:53 EPA 7470A EPA 7470A 06/09/20 05/20/20 12:50 05/21/20 17:02 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 13 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW23 Lab ID: CD07885-01 Analvte Results Flag MDL PQL Units Method Notes Barium - Total 85.2 1.10 10.0 ug/L EPA 6010D Chromium - Total 4.97 J 1.40 10.0 ug/L EPA 6010D Zinc - Total 13.3 4.40 10.0 ug/L EPA 6010D Client ID: 3402-MW24 Lab ID: CD07885-02 Analvte Results Flag MDL PQL Units Method Notes Barium - Total 181 1.10 10.0 ug/L EPA 6010D Chromium - Total 10.1 1.40 10.0 ug/L EPA 6010D Copper - Total 1.96 J 1.60 10.0 ug/L EPA 6010D Vanadium - Total 4.31 J 1.40 10.0 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 3 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW23 Lab Sample ID:CDO7885-01 Received: 05/15/20 13:15 Matrix: Ground Water Sampled:05/12/20 15:30 Work Order: CD07885 Project: Hanes Mill LF- Upgradient Wells Sampled By: Nicolas Tejada Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 OE20030 EPA 7470A 05/21/20 16:59 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Antimony[7440-36-O]^ 0.740 U ug/L 2 0.740 2.00 OE26023 EPA 6020B 05/29/20 15:48 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Barium [7440-39-3]^ 85.2 ug/L 1 1.10 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Beryllium [7440-41-7]1 0.160 U ug/L 1 0.160 1.00 OE22017 EPA 6010D 05/27/20 13:26 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 OE22017 EPA 6010D 05/27/20 13:26 JDH Chromium [7440-47-3]^ 4.97 J ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Cobalt [7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Nickel[7440-02-O]^ 2.20 U ug/L 1 2.20 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Silver [7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Thallium [7440-28-O]^ 0.220 U ug/L 2 0.220 2.00 OE26023 EPA 6020B 05/29/20 15:48 RLF Tin[7440-31-5]^ 2.90 U ug/L 1 2.90 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Vanadium [7440-62-2]1 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Zinc[7440-66-6]^ 13.3 ug/L 1 4.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 13 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW24 Lab Sample ID:CDO7885-02 Received: 05/15/20 13:15 Matrix: Ground Water Sampled:05/12/20 16:40 Work Order: CD07885 Project: Hanes Mill LF- Upgradient Wells Sampled By: Nicolas Tejada Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 OE20030 EPA 7470A 05/21/20 17:02 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Antimony[7440-36-O]^ 0.740 U ug/L 2 0.740 2.00 OE26023 EPA 6020B 05/29/20 15:53 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Barium [7440-39-3]^ 181 ug/L 1 1.10 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Beryllium [7440-41-7]1 0.160 U ug/L 1 0.160 1.00 OE22017 EPA 6010D 05/27/20 13:28 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 OE22017 EPA 6010D 05/27/20 13:28 JDH Chromium [7440-47-3]^ 10.1 ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Cobalt [7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Copper[7440-50-8]^ 1.96 J ug/L 1 1.60 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Nickel[7440-02-O]^ 2.20 U ug/L 1 2.20 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Silver [7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 OE26023 EPA 6020B 05/29/20 15:53 RLF Tin[7440-31-5]^ 2.90 U ug/L 1 2.90 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Vanadium [7440-62-2]^ 4.31 J ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Zinc [7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals by EPA 6000/7000 Series Methods - Quality Control Batch OE2003O - EPA 747OA Blank (OE20030-BLK1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:28 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 0.150 U 0.200 ug/L LCS (OE20030-BS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:31 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.06 0.200 ug/L 5.00 101 80-120 Matrix Spike (OE20030-MS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:41 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 4.99 0.200 ug/L 5.00 0.150 U 100 75-125 Matrix Spike Dup (OE20030-MSDS) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:43 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.16 0.200 ug/L 5.00 0.150 U 103 75-125 3 25 Post Spike (OE20030-PS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:46 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.40 0.200 ug/L 5.00 0.0310 107 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A Blank (OE22017-BLK3) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 11:55 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Lead 3.10 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Selenium 6.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Tin 2.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L LCS (OE22017-BSI) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:00 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Arsenic 215 10.0 ug/L 200 107 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A - Continued LCS (OE22017-BSI) Continued Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:00 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Barium 211 10.0 ug/L 200 106 80-120 Beryllium 20.7 1.00 ug/L 20.0 103 80-120 Cadmium 20.9 1.00 ug/L 20.0 104 80-120 Chromium 209 10.0 ug/L 200 104 80-120 Cobalt 218 10.0 ug/L 200 109 80-120 Copper 206 10.0 ug/L 200 103 80-120 Lead 215 10.0 ug/L 200 108 80-120 Nickel 208 10.0 ug/L 200 104 80-120 Selenium 222 10.0 ug/L 200 111 80-120 Silver 207 10.0 ug/L 200 104 80-120 Tin 211 10.0 ug/L 200 105 80-120 Vanadium 207 10.0 ug/L 200 104 80-120 Zinc 210 10.0 ug/L 200 105 80-120 Matrix Spike (OE22017-MS3) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:44 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 202 10.0 ug/L 200 7.60 U 101 75-125 Barium 233 10.0 ug/L 200 25.4 104 75-125 Beryllium 20.7 1.00 ug/L 20.0 0.160 U 104 75-125 Cadmium 20.1 1.00 ug/L 20.0 0.360 U 101 75-125 Chromium 208 10.0 ug/L 200 1.40 U 104 75-125 Cobalt 221 10.0 ug/L 200 6.16 107 75-125 Copper 212 10.0 ug/L 200 2.27 105 75-125 Lead 210 10.0 ug/L 200 3.10 U 105 75-125 Nickel 214 10.0 ug/L 200 9.12 103 75-125 Selenium 208 10.0 ug/L 200 6.20 U 104 75-125 Silver 211 10.0 ug/L 200 1.90 U 106 75-125 Tin 205 10.0 ug/L 200 2.90 U 103 75-125 Vanadium 208 10.0 ug/L 200 1.40 U 104 75-125 Zinc 219 10.0 ug/L 200 13.7 103 75-125 Matrix Spike Dup (OE22017-MSD1) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:47 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 193 10.0 ug/L 200 7.60 U 96 75-125 5 20 Barium 229 10.0 ug/L 200 25.4 102 75-125 2 20 Beryllium 20.3 1.00 ug/L 20.0 0.160 U 102 75-125 2 20 Cadmium 19.8 1.00 ug/L 20.0 0.360 U 99 75-125 1 20 Chromium 205 10.0 ug/L 200 1.40 U 102 75-125 2 20 Cobalt 217 10.0 ug/L 200 6.16 105 75-125 2 20 Copper 209 10.0 ug/L 200 2.27 104 75-125 1 20 Lead 206 10.0 ug/L 200 3.10 U 103 75-125 2 20 Nickel 211 10.0 ug/L 200 9.12 101 75-125 2 20 Selenium 190 10.0 ug/L 200 6.20 U 95 75-125 9 20 Silver 208 10.0 ug/L 200 1.90 U 104 75-125 2 20 Tin 200 10.0 ug/L 200 2.90 U 100 75-125 3 20 Vanadium 205 10.0 ug/L 200 1.40 U 102 75-125 2 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A - Continued Matrix Spike Dup (OE22017-MSDS) Continued Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:47 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Zinc 215 10.0 ug/L 200 13.7 100 75-125 2 20 Post Spike (OE22017-PS1) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:49 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 0.202 0.0100 mg/L 0.200 -0.0156 101 80-120 Barium 0.245 0.0100 mg/L 0.200 0.0254 110 80-120 Beryllium 0.0210 0.00100 mg/L 0.0200 -0.000169 105 80-120 Cadmium 0.0214 0.00100 mg/L 0.0200 -0.000641 107 80-120 Chromium 0.213 0.0100 mg/L 0.200 0.00108 106 80-120 Cobalt 0.222 0.0100 mg/L 0.200 0.00616 108 80-120 Copper 0.218 0.0100 mg/L 0.200 0.00227 108 80-120 Lead 0.213 0.0100 mg/L 0.200 -0.000525 106 80-120 Nickel 0.227 0.0100 mg/L 0.200 0.00912 109 80-120 Selenium 0.209 0.0100 mg/L 0.200 -0.0158 104 80-120 Silver 0.216 0.0100 mg/L 0.200 -0.00102 108 80-120 Tin 0.205 0.0100 mg/L 0.200 -0.00606 102 80-120 Vanadium 0.212 0.0100 mg/L 0.200 0.000507 106 80-120 Zinc 0.237 0.0100 mg/L 0.200 0.0137 112 80-120 Batch OE26O23 - EPA 3OO5A Blank (OE26023-BLK1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:38 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Selenium 0.910 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L LCS (OE26023-BS1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:42 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 20.4 1.00 ug/L 20.0 102 80-120 Selenium 20.5 1.00 ug/L 20.0 102 80-120 Thallium 20.2 1.00 ug/L 20.0 101 80-120 Matrix Spike (OE26023-MS3) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:46 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 41.2 2.00 ug/L 40.0 0.740 U 103 75-125 Selenium 41.1 2.00 ug/L 40.0 1.82 U 103 75-125 Thallium 39.4 2.00 ug/L 40.0 0.220 U 99 75-125 Matrix Spike Dup (OE26023-MSD1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:50 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 40.9 2.00 ug/L 40.0 0.740 U 102 75-125 0.6 20 Selenium 42.3 2.00 ug/L 40.0 1.82 U 106 75-125 3 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE26O23 - EPA 3OO5A - Continued Matrix Spike Dup (OE26023-MSDS) Continued Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:50 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Thallium 39.7 2.00 ug/L 40.0 0.220 U 99 75-125 0.6 20 Post Spike (OE26023-PS1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:55 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 22.4 1.00 ug/L 20.0 0.203 111 75-125 Selenium 21.9 1.00 ug/L 20.0 0.167 109 75-125 Thallium 21.6 1.00 ug/L 20.0 0.0149 108 75-125 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 13 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 of 13 3 a � � v N F ^l n O Cl -t m o. p U C G n 3 v ,n n o � x n � � o 6i m � O �o Lr m 3 0 s, (� -NJ r Le IRA � j J Fr v a A m� u� m a ro ro 'a n N I INS o '0 f a Cn r cp O o m wm m w rn x CD A CD m Q V m CD w N 3 CL r Page 12 of 13 Sample Preservation Verification ENCO Cary Work Order: CD07885 Client: -Golder Associates, Inc. (00007) Logged In15-May-20 15:32 Project: Hanes Mill LF- Upgradient Wells Project #: 19117535.405 Logged By: John C King Preservation Check Performed By: Date/Time: -/S G Mao CD07885-01 Cunt Type Pres (pH) pH Checked / pH Adjusted DatefTime Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y I N! NA Y /�1 NA CD07885-02 Cont Type Pres (pH) Requirement pH Checked ! In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 1'/I N I NA Y &I 1 NA Rea ent Name ID 1 2 pH Strip ID: Reagent Name ID 3 4 Rea ent Name ID 5 6 C aELMNT1Printlwko_PreservationCheck. rpt Page 13 of 13 ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, June 1, 2020 Golder Associates, Inc. (G0007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19117535.405, Project Name/Desc: Hanes Mill LF- Upgradient Wells ENCO Workorder(s): CD07885 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, May 15, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Daniel B. Mays Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 3 PROJECT NARRATIVE Date: 1 June 2020 Client: Golder Associates, Inc. (G0007) Project: Hanes Mill LF- Upgradient Wells Lab ID: CD07885 Overview (� �Eo www.encolabs.com Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in the QC Remarks section below. Quality Control Samples No Comments Selenium exceeded upper control limit for the continuing calibration verification sample. No Comments Other Comments The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of the report. Released By: Environmental Conservation Laboratories, Inc. Daniel Mays Project Manager FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 of 13 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 3402-MW23 Lab ID: CD07885-01 Sampled: 05/12/20 15:30 Received: 05/15/20 13:15 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 11/08/20 05/22/20 11:14 05/27/20 13:26 EPA 6020E EPA 3005A 11/08/20 05/26/20 12:13 05/29/20 15:48 EPA 7470A EPA 7470A 06/09/20 05/20/20 12:50 05/21/20 16:59 Client ID: 3402-MW24 Lab ID: CD07885-02 Sampled: 05/12/20 16:40 Received: 05/15/20 13:15 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 11/08/20 05/22/20 11:14 05/27/20 13:28 EPA 6020E EPA 3005A 11/08/20 05/26/20 12:13 05/29/20 15:53 EPA 7470A EPA 7470A 06/09/20 05/20/20 12:50 05/21/20 17:02 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 13 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 3402-MW23 Lab ID: CD07885-01 Analvte Results Flag MDL PQL Units Method Notes Barium - Total 85.2 1.10 10.0 ug/L EPA 6010D Chromium - Total 4.97 J 1.40 10.0 ug/L EPA 6010D Zinc - Total 13.3 4.40 10.0 ug/L EPA 6010D Client ID: 3402-MW24 Lab ID: CD07885-02 Analvte Results Flag MDL PQL Units Method Notes Barium - Total 181 1.10 10.0 ug/L EPA 6010D Chromium - Total 10.1 1.40 10.0 ug/L EPA 6010D Copper - Total 1.96 J 1.60 10.0 ug/L EPA 6010D Vanadium - Total 4.31 J 1.40 10.0 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 3 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW23 Lab Sample ID:CDO7885-01 Received: 05/15/20 13:15 Matrix: Ground Water Sampled:05/12/20 15:30 Work Order: CD07885 Project: Hanes Mill LF- Upgradient Wells Sampled By: Nicolas Tejada Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 OE20030 EPA 7470A 05/21/20 16:59 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Antimony[7440-36-O]^ 0.740 U ug/L 2 0.740 2.00 OE26023 EPA 6020B 05/29/20 15:48 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Barium [7440-39-3]^ 85.2 ug/L 1 1.10 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Beryllium [7440-41-7]1 0.160 U ug/L 1 0.160 1.00 OE22017 EPA 6010D 05/27/20 13:26 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 OE22017 EPA 6010D 05/27/20 13:26 JDH Chromium [7440-47-3]^ 4.97 J ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Cobalt [7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Nickel[7440-02-O]^ 2.20 U ug/L 1 2.20 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Silver [7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Thallium [7440-28-O]^ 0.220 U ug/L 2 0.220 2.00 OE26023 EPA 6020B 05/29/20 15:48 RLF Tin[7440-31-5]^ 2.90 U ug/L 1 2.90 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Vanadium [7440-62-2]1 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH Zinc[7440-66-6]^ 13.3 ug/L 1 4.40 10.0 OE22017 EPA 6010D 05/27/20 13:26 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) of 13 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 3402-MW24 Lab Sample ID:CDO7885-02 Received: 05/15/20 13:15 Matrix: Ground Water Sampled:05/12/20 16:40 Work Order: CD07885 Project: Hanes Mill LF- Upgradient Wells Sampled By: Nicolas Tejada Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 OE20030 EPA 7470A 05/21/20 17:02 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL P L Batch Method Analyzed Ay Notes Antimony[7440-36-O]^ 0.740 U ug/L 2 0.740 2.00 OE26023 EPA 6020B 05/29/20 15:53 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Barium [7440-39-3]^ 181 ug/L 1 1.10 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Beryllium [7440-41-7]1 0.160 U ug/L 1 0.160 1.00 OE22017 EPA 6010D 05/27/20 13:28 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 OE22017 EPA 6010D 05/27/20 13:28 JDH Chromium [7440-47-3]^ 10.1 ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Cobalt [7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Copper[7440-50-8]^ 1.96 J ug/L 1 1.60 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Nickel[7440-02-O]^ 2.20 U ug/L 1 2.20 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Silver [7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 OE26023 EPA 6020B 05/29/20 15:53 RLF Tin[7440-31-5]^ 2.90 U ug/L 1 2.90 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Vanadium [7440-62-2]^ 4.31 J ug/L 1 1.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH Zinc [7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 OE22017 EPA 6010D 05/27/20 13:28 JDH FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals by EPA 6000/7000 Series Methods - Quality Control Batch OE2003O - EPA 747OA Blank (OE20030-BLK1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:28 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 0.150 U 0.200 ug/L LCS (OE20030-BS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:31 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.06 0.200 ug/L 5.00 101 80-120 Matrix Spike (OE20030-MS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:41 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 4.99 0.200 ug/L 5.00 0.150 U 100 75-125 Matrix Spike Dup (OE20030-MSDS) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:43 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.16 0.200 ug/L 5.00 0.150 U 103 75-125 3 25 Post Spike (OE20030-PS1) Prepared: 05/20/2020 12:50 Analyzed: 05/21/2020 15:46 Source: CD07401-03 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Mercury 5.40 0.200 ug/L 5.00 0.0310 107 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A Blank (OE22017-BLK3) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 11:55 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Lead 3.10 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Selenium 6.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Tin 2.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L LCS (OE22017-BSI) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:00 Spike Source O/oREC RPD Analvte Result Flaq POL Units Level Result O/oREC Limits RPD Limit Notes Arsenic 215 10.0 ug/L 200 107 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 7 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A - Continued LCS (OE22017-BSI) Continued Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:00 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Barium 211 10.0 ug/L 200 106 80-120 Beryllium 20.7 1.00 ug/L 20.0 103 80-120 Cadmium 20.9 1.00 ug/L 20.0 104 80-120 Chromium 209 10.0 ug/L 200 104 80-120 Cobalt 218 10.0 ug/L 200 109 80-120 Copper 206 10.0 ug/L 200 103 80-120 Lead 215 10.0 ug/L 200 108 80-120 Nickel 208 10.0 ug/L 200 104 80-120 Selenium 222 10.0 ug/L 200 111 80-120 Silver 207 10.0 ug/L 200 104 80-120 Tin 211 10.0 ug/L 200 105 80-120 Vanadium 207 10.0 ug/L 200 104 80-120 Zinc 210 10.0 ug/L 200 105 80-120 Matrix Spike (OE22017-MS3) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:44 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 202 10.0 ug/L 200 7.60 U 101 75-125 Barium 233 10.0 ug/L 200 25.4 104 75-125 Beryllium 20.7 1.00 ug/L 20.0 0.160 U 104 75-125 Cadmium 20.1 1.00 ug/L 20.0 0.360 U 101 75-125 Chromium 208 10.0 ug/L 200 1.40 U 104 75-125 Cobalt 221 10.0 ug/L 200 6.16 107 75-125 Copper 212 10.0 ug/L 200 2.27 105 75-125 Lead 210 10.0 ug/L 200 3.10 U 105 75-125 Nickel 214 10.0 ug/L 200 9.12 103 75-125 Selenium 208 10.0 ug/L 200 6.20 U 104 75-125 Silver 211 10.0 ug/L 200 1.90 U 106 75-125 Tin 205 10.0 ug/L 200 2.90 U 103 75-125 Vanadium 208 10.0 ug/L 200 1.40 U 104 75-125 Zinc 219 10.0 ug/L 200 13.7 103 75-125 Matrix Spike Dup (OE22017-MSD1) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:47 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 193 10.0 ug/L 200 7.60 U 96 75-125 5 20 Barium 229 10.0 ug/L 200 25.4 102 75-125 2 20 Beryllium 20.3 1.00 ug/L 20.0 0.160 U 102 75-125 2 20 Cadmium 19.8 1.00 ug/L 20.0 0.360 U 99 75-125 1 20 Chromium 205 10.0 ug/L 200 1.40 U 102 75-125 2 20 Cobalt 217 10.0 ug/L 200 6.16 105 75-125 2 20 Copper 209 10.0 ug/L 200 2.27 104 75-125 1 20 Lead 206 10.0 ug/L 200 3.10 U 103 75-125 2 20 Nickel 211 10.0 ug/L 200 9.12 101 75-125 2 20 Selenium 190 10.0 ug/L 200 6.20 U 95 75-125 9 20 Silver 208 10.0 ug/L 200 1.90 U 104 75-125 2 20 Tin 200 10.0 ug/L 200 2.90 U 100 75-125 3 20 Vanadium 205 10.0 ug/L 200 1.40 U 102 75-125 2 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE22O17 - EPA 3OO5A - Continued Matrix Spike Dup (OE22017-MSDS) Continued Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:47 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Zinc 215 10.0 ug/L 200 13.7 100 75-125 2 20 Post Spike (OE22017-PS1) Prepared: 05/22/2020 11:14 Analyzed: 05/27/2020 12:49 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 0.202 0.0100 mg/L 0.200 -0.0156 101 80-120 Barium 0.245 0.0100 mg/L 0.200 0.0254 110 80-120 Beryllium 0.0210 0.00100 mg/L 0.0200 -0.000169 105 80-120 Cadmium 0.0214 0.00100 mg/L 0.0200 -0.000641 107 80-120 Chromium 0.213 0.0100 mg/L 0.200 0.00108 106 80-120 Cobalt 0.222 0.0100 mg/L 0.200 0.00616 108 80-120 Copper 0.218 0.0100 mg/L 0.200 0.00227 108 80-120 Lead 0.213 0.0100 mg/L 0.200 -0.000525 106 80-120 Nickel 0.227 0.0100 mg/L 0.200 0.00912 109 80-120 Selenium 0.209 0.0100 mg/L 0.200 -0.0158 104 80-120 Silver 0.216 0.0100 mg/L 0.200 -0.00102 108 80-120 Tin 0.205 0.0100 mg/L 0.200 -0.00606 102 80-120 Vanadium 0.212 0.0100 mg/L 0.200 0.000507 106 80-120 Zinc 0.237 0.0100 mg/L 0.200 0.0137 112 80-120 Batch OE26O23 - EPA 3OO5A Blank (OE26023-BLK1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:38 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Selenium 0.910 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L LCS (OE26023-BS1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:42 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 20.4 1.00 ug/L 20.0 102 80-120 Selenium 20.5 1.00 ug/L 20.0 102 80-120 Thallium 20.2 1.00 ug/L 20.0 101 80-120 Matrix Spike (OE26023-MS3) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:46 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 41.2 2.00 ug/L 40.0 0.740 U 103 75-125 Selenium 41.1 2.00 ug/L 40.0 1.82 U 103 75-125 Thallium 39.4 2.00 ug/L 40.0 0.220 U 99 75-125 Matrix Spike Dup (OE26023-MSD1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:50 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 40.9 2.00 ug/L 40.0 0.740 U 102 75-125 0.6 20 Selenium 42.3 2.00 ug/L 40.0 1.82 U 106 75-125 3 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 9 Of 13 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch OE26O23 - EPA 3OO5A - Continued Matrix Spike Dup (OE26023-MSDS) Continued Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:50 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Thallium 39.7 2.00 ug/L 40.0 0.220 U 99 75-125 0.6 20 Post Spike (OE26023-PS1) Prepared: 05/26/2020 12:13 Analyzed: 05/28/2020 15:55 Source: CD07401-03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 22.4 1.00 ug/L 20.0 0.203 111 75-125 Selenium 21.9 1.00 ug/L 20.0 0.167 109 75-125 Thallium 21.6 1.00 ug/L 20.0 0.0149 108 75-125 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 13 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 of 13 3 a � � v N F ^l n O Cl -t m o. p U C G n 3 v ,n n o � x n � � o 6i m � O �o Lr m 3 0 s, (� -NJ r Le IRA � j J Fr v a A m� u� m a ro ro 'a n N I INS o '0 f a Cn r cp O o m wm m w rn x CD A CD m Q V m CD w N 3 CL r Page 12 of 13 Sample Preservation Verification ENCO Cary Work Order: CD07885 Client: -Golder Associates, Inc. (00007) Logged In15-May-20 15:32 Project: Hanes Mill LF- Upgradient Wells Project #: 19117535.405 Logged By: John C King Preservation Check Performed By: Date/Time: -/S G Mao CD07885-01 Cunt Type Pres (pH) pH Checked / pH Adjusted DatefTime Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y I N! NA Y /�1 NA CD07885-02 Cont Type Pres (pH) Requirement pH Checked ! In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 1'/I N I NA Y &I 1 NA Rea ent Name ID 1 2 pH Strip ID: Reagent Name ID 3 4 Rea ent Name ID 5 6 C aELMNT1Printlwko_PreservationCheck. rpt Page 13 of 13 GOLDER Project Name: AGtAczs Hill —,ri►,ti� Iru�� Well ID: Well Diameter: Diameter: 2 inches Depth to Bottom: _gym G3 feet Pumping Rate: mUmin. Equipment: 1� 5 DATE: GROUNDWATER SAMPLING LOG Project No./Phasq No.: 1 "1 to- Sampler(s): _ 141w —N 1tgf4G - -QfN Initial Depth to Water: q-,c@( feet Water Column Thickness: feet System Volume: �14 % mL Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis OZ (mg/L) Temp. (CC) ORP (millivolts) DTW (feet) l(o .4 11.06. 13 I0.U'; Z, 1 3. g Z150. 0 5. to i,640 Lo ! M 4 . 6 46 13 (d Z 4 4- 4 S %k c;u 16�F0 I Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: �r yy�ly, to,,; Begin purging @ Ill Signature: QA/QC Sign Off: 1 Date: Date: ��-Z� GOLDER DATE: O -IZ- L;. GROUNDWATER SAMPLING LOG Project Name: _t'1G�11Q.� Ml. - zaj� j� r'y,,,i Project No./Phase No.: Well ID: M%AI _?-3 Sampler(s): _ co ( TE)V1 Well Diameter: 2 inches Initial Depth to Water: 3 .32 feet Depth to Bottom: e+5'k feet Water Column Thickness: `a3 feet Pumping Rate: "a mL/min. System Volume: Wad mL Equipment: _'4ST,_P�IU5—U,A .0 1A 4Q_._WatU_LQA t�._r * 6IyJc�1LDLJ , �L`I Time pH (S.U.) Sp. Cond. (US/cm) Turb (NTU) Dis 02 (mg/L) Temp. (°C) ORP (millivolts) DTW (feet) 44SJ zL 3.6 IOG S. 84 t5. I _ 36. (. I q -ss ZZ, a t. I 5. 1 G. I q4- Z 3 2JO 40. 0 w - � L i s } W--? ,S 3 6. +Z. i515 iE; z8 3 ZZ _0 S `Is IS a 21p. 3h. - 3 15fs 1 5 60 36i-3 11.8 5 5 ' Z16. 3e. I�3C 300.9 G.9 15 c 1 � I - Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: SAvxq , (c in purgin Signature: Date: OS- IZ-Z(eo RA1QC Sr§n Off: Date: 6 - 4 �- 7-C•ze: APPENDIX D Statistical Analysis Worksheet 10/7/2009 3/16/2010 9/7/2010 3/23/2011 9/12/2011 3/12/2012 10/1/2012 3/12/2013 9/10/2013 3/11/2014 9/10/2014 3/9/2015 9/14/2015 3/7/2016 9/13/2016 9/14/2016 3/6/2017 3/7/2017 9/11/2017 9/12/2017 3/5/2018 12/11/2018 3/5/2019 7/31/2019 9/23/2019 11 /25/2019 1 /28/2020 3/2/2020 5/12/2020 OW-3 1170 1230 1460 1260 1390 1280 1170 1260 1150 1090 993 1200 1080 1150 1170 1220 1160 804 MW-12 (bg) 35.4 32.4 28 37 36.4 29.1 31.3 37 35.9 30.6 30.8 33.7 34.3 35.7 36.4 38.8 39 36.5 34.2 36.8 34.7 32.6 Prediction Limit Constituent: Barium (ug/L) Analysis Run 6/24/2020 4:52 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables MW-1RR (bg) MW-23 (bg) MW-24 (bg) 12.2 19.8 13.3 12.9 16.7 14.5 17.6 17.7 27.6 20.9 20 20 17 15.5 23 17.1 24.8 184 167 136 159 104 175 86.9 172 93.5 179 83.9 176 72.1 159 85.2 181 WQStat Plus" v.9.4.32 30 24 18 J 0) 12 6 0 4-- 9/7/10 EPA 1989 Outlier Test MW-1 RR (bg) n=17 No statistical outliers found. Mean = 18.27 Std. dev. = 4.226 Critical Tn = 2.475 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.9593 Critical = 0.892 The distribution was found to be normally distrib- uted. 7/30/12 6/23/14 5/16/16 4/9/18 3/2/20 Constituent: Barium Analysis Run 6/16/2020 3:59 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 40 32 24 J 16 8 0 4- 10/7/09 EPA 1989 Outlier Test MW-12 (bg) n=22 No statistical outliers found. Mean = 34.39 Std. dev. = 3.016 Critical Tn = 2.603 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.9507 Critical = 0.911 The distribution was found to be normally distrib- uted. 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Barium Analysis Run 6/16/2020 4:08 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 200 160 120 J 0) 80 40 0 -k— 12/11/18 EPA 1989 Outlier Test MW-23 (bg) n = 8 No statistical outliers found. Mean = 105.7 Std. dev. = 36.99 Critical Tn = 2.032 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.8792 Critical = 0.818 (after natural log transforma- tion) The distribution was found to be log -normal. 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Barium Analysis Run 6/16/2020 4:00 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 200 160 120 J 80 40 0 -k— 12/11/18 EPA 1989 Outlier Test MW-24 (bg) n = 8 No statistical outliers found. Mean = 171 Std. dev. = 8.536 Critical Tn = 2.032 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.8962 Critical = 0.818 The distribution was found to be normally distrib- uted. 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Barium Analysis Run 6/16/2020 4:00 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Exceeds Limit: OW-3 2000 1600 1200 :11 R11 0 4- 10/7/09 Prediction Limit Interwell Parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 ♦ OW-3 Limit = 192.7 Background Data Summary: Mean=76.49, Std. Dev.=67.61, n=33. Seasonality was not detected with 95% confidence. Report alpha = 0.05. Most recent point compared to limit. Constituent: Barium Analysis Run 6/16/2020 4:12 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables Prediction Limit Constituent: Chromium (ug/L) Analysis Run 6/24/2020 4:47 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables MW-11 MW-12 (bg) MW-1RR (bg) MW-23 (bg) MW-24 (bg) 10/6/2009 10.9 10/7/2009 <1.4 3/15/2010 12.1 3/16/2010 <1.4 9/7/2010 15.9 <1.4 <1.4 3/22/2011 16.5 1.45 3/23/2011 <1.4 9/12/2011 <1.4 9/13/2011 14.6 1.74 3/12/2012 <1.4 10/1/2012 15 <1.4 3/ 12/2013 16.7 1.18 1.36 9/10/2013 <1.4 <1.4 3/11/2014 <1.4 9/9/2014 14 <1.4 9/10/2014 <1.4 3/9/2015 13.6 <1.4 <1.4 9/14/2015 14.5 <1.4 <1.4 3/7/2016 11.2 <1.4 <1.4 9/13/2016 <1.4 9/14/2016 <1.4 9/15/2016 14.3 3/6/2017 1.31 3/8/2017 13.9 <1.4 9/11/2017 <1.4 9/12/2017 11.1 <1.4 3/5/2018 10.9 <1.4 <1.4 12/11/2018 11.2 <1.4 <1.4 1.42 5.42 3/5/2019 14.9 <1.4 <1.4 2.92 6.93 7/31 /2019 5.52 10 9/23/2019 10.7 <1.4 <1.4 3.82 7.81 11/25/2019 5.76 9.77 1 /28/2020 5.1 9.73 3/2/2020 10.4 <1.4 <1.4 4.83 8.42 5/12/2020 4.97 10.1 WQStat Plus" v.9.4.32 2 1.6 1.2 J 0.8 0.4 0 4-- 9/7/10 EPA 1989 Outlier Test MW-1 RR (bg) n=17 No statistical outliers found. The distribution was not normalizable. Mean = 1.421 Std. dev. = 0.08385 Critical Tn = 2.475. After outlier removal: mean = 1.401, std. dev. = 0.01652, critical = 2.443; mean = 1.397, std. dev. = 0.01033, critical = 2.409. Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.3864 Critical = 0.892 7/30/12 6/23/14 5/16/16 4/9/18 3/2/20 Constituent: Chromium Analysis Run 6/16/2020 4:16 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 2 1.6 1.2 J 0.8 0.4 0 4- 10/7/09 EPA 1989 Outlier Test MW-12 (bg) n=22 No statistical outliers found. The distribution was not normalizable. Mean = 1.386 Std. dev. = 0.04982 Critical Tn = 2.603. After outlier removal: mean = 1.396, std. dev. = 0.01964, critical = 2.58. Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.3182 Critical = 0.911 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Chromium Analysis Run 6/16/2020 4:27 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 6 4.8 3.6 J 2.4 1.2 0 -k— 12/11/18 EPA 1989 Outlier Test MW-23 (bg) n = 8 Statistical outlier is drawn as solid. Mean = 4.293 Std. dev. = 1.484 Critical Tn = 2.032. After outlier removal: mean = 4.703, std. dev. = 0.999, critical = 1.938. Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.9013 Critical = 0.803 The distribution, after removal of outlier, was found to be normally dis- tributed. 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Chromium Analysis Run 6/16/2020 4:17 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 11 8.8 6.6 J 4.4 2.2 0 -k— 12/11/18 EPA 1989 Outlier Test MW-24 (bg) n = 8 No statistical outliers found. Mean = 8.523 Std. dev. = 1.706 Critical Tn = 2.032 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.8739 Critical = 0.818 The distribution was found to be normally distrib- uted. 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Chromium Analysis Run 6/16/2020 4:18 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Exceeds Limit: MW-11 20 16 12 3 0 4- 10/6/09 Prediction Limit Interwell Non -parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 ♦ MW-11 Limit = 10.1 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 54 background values. 62.96% NDs. Report alpha = 0.01818. Most recent point compared to limit. Seasonality was not detected with 95% confidence. Constituent: Chromium Analysis Run 6/16/2020 4:28 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 20 16 12 J 8 4 0 4- 10/6/09 EPA 1989 Outlier Test MW-11 n=19 No statistical outliers found. Mean = 13.28 Std. dev. = 2.12 Critical Tn = 2.532 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.9015 Critical = 0.901 The distribution was found to be normally distrib- uted. 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Chromium Analysis Run 6/16/2020 4:46 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Within Limit 19 15.2 11.4 7.6 0 4- 10/6/09 Prediction Limit Intrawell Parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 ■ MW-11 background ♦ MW-11 compliance Limit = 18.88 Background Data Summary: Mean=13.44, Std. Dev.=2.059, n=18. Insufficient data to test for seasonality: data were not deseasonalized. Report alpha = 0.01. Most recent point compared to limit. Constituent: Chromium Analysis Run 6/16/2020 4:47 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables Prediction Limit Constituent: Cobalt (ug/L) Analysis Run 6/24/2020 4:48 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables MW-12 (bg) MW-7 MW-6 OW-3 MW-1RR (bg) MW-19 MW-24 (bg) MW-23 (bg) 10/5/2009 1.23 10/6/2009 20.4 19 10/7/2009 20.5 3/15/2010 <1.1 4.49 18.4 9/7/2010 <1.1 14.9 15.7 <1.1 3/21/2011 <1.1 3/22/2011 5.23 17.4 <1.1 3/23/2011 22.2 9/12/2011 <1.1 57 9/13/2011 23.9 17.3 <1.1 3/12/2012 <1.1 3.84 15.8 10/1/2012 <1.1 16.1 14.4 20 3/11/2013 1.14 3/12/2013 4.24 14.5 19.4 <1.1 9/9/2013 <1.1 9/10/2013 4.62 15.5 18.3 <1.1 3/10/2014 <1.1 5.1 16.3 9/9/2014 <1.1 19 18 <1.1 9/10/2014 15.9 3/9/2015 <1.1 4.71 17.8 16.5 <1.1 9/14/2015 23 14.8 15.2 <1.1 3/7/2016 <1.1 4.45 16 <1.1 <1.1 9/13/2016 <1.1 9/14/2016 10.7 <1.1 9/15/2016 14.5 3/7/2017 17.4 3/8/2017 19.4 14.4 <1.1 3/9/2017 <1.1 9/11/2017 14.7 10.7 9/12/2017 <1.1 9.72 <1.1 27.8 3/5/2018 16 13.9 12.8 <1.1 12/11/2018 <1.1 3.85 15.2 10.8 <1.1 25.1 1.98 <1.1 3/5/2019 <1.1 4.28 14.4 16.2 <1.1 20.3 <1.1 <1.1 7/31/2019 <1.1 <1.1 9/23/2019 <1.1 12.7 17 11.5 <1.1 18 <1.1 <1.1 11/25/2019 <1.1 <1.1 1/28/2020 <1.1 <1.1 3/2/2020 <1.1 4.28 13.7 7.51 <1.1 18.3 <1.1 <1.1 5/12/2020 <1.1 <1.1 WQStat Plus" v.9.4.32 3 2.4 1.8 J 1.2 0.6 0 4-- 9/7/10 EPA 1989 Outlier Test MW-1 RR (bg) n=17 No statistical outliers found. The distribution was not normalizable. Mean = 1.1 Std. dev. = 0 Critical Tn = 2.475 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0 Critical = 0.892 7/30/12 6/23/14 5/16/16 4/9/18 3/2/20 Constituent: Cobalt Analysis Run 6/16/2020 4:31 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 2 1.6 1.2 J 0.8 0.4 0 4- 10/5/09 EPA 1989 Outlier Test MW-12 (bg) n=20 No statistical outliers found. The distribution was not normalizable. Mean = 1.109 Std. dev. = 0.02996 Critical Tn = 2.557. After outlier removal: mean = 1.102, std. dev. = 0.009177, critical = 2.532. Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.3269 Critical = 0.905 11 /4/11 12/3/13 1 /2/16 1 /31 /18 3/2/20 Constituent: Cobalt Analysis Run 6/16/2020 4:31 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 EPA 1989 Outlier Test MW-23 (bg) 3 2.4 1.8 1.2 0.6 0 12/11/18 n = 8 No statistical outliers found. The distribution was not normalizable. Mean = 1.4 Std. dev. = 0 Critical Tn = 2.032 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0 Critical = 0.818 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Cobalt Analysis Run 6/16/2020 4:32 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 2 1.6 1.2 J 0.8 0.4 0 -k— 12/11/18 EPA 1989 Outlier Test MW-24 (bg) n = 8 No statistical outliers found. The distribution was not normalizable. Mean = 1.472 Std. dev. = 0.2051 Critical Tn = 2.032 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.4186 Critical = 0.818 3/24/19 7/6/19 10/17/19 1 /29/20 5/12/20 Constituent: Cobalt Analysis Run 6/16/2020 4:32 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Hollow symbols indicate censored values. Exceeds Limit: OW-3, MW-6, MW-19 J 91 En &ez 24 12 0 10/6/09 Prediction Limit Interwell Non -parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 OW-3 ■ MW-6 C MW-19 Limit = 1.98 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 53 background values. 94.34% NDs. Report alpha = 0.05357. Individual comparison alpha = 0.01819. Most recent point for each compliance well compared to limit. Seasonality was not detected with 95% confidence. Constituent: Cobalt Analysis Run 6/16/2020 4:33 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 20 16 12 J 8 4 0 4- 10/6/09 EPA 1989 Outlier Test MW-6 n=21 No statistical outliers found. Mean = 15.91 Std. dev. = 1.587 Critical Tn = 2.58 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.939 Critical = 0.908 The distribution was found to be normally distrib- uted. 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Cobalt Analysis Run 6/16/2020 4:43 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 Within Limit 21 12.6 M 4.2 0 4- 10/6/09 Prediction Limit Intrawell Parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 ■ MW-6 background ♦ MW-6 compliance Limit = 20.04 Background Data Summary: Mean=16.03, Std. Dev.=1.543, n=20. Insufficient data to test for seasonality: data were not deseasonalized. Report alpha = 0.01. Most recent point compared to limit. Constituent: Cobalt Analysis Run 6/16/2020 4:44 PM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus" v.9.4.32 30 24 18 J 12 6 0 4- 10/6/09 EPA 1989 Outlier Test MW-7 n=22 No statistical outliers found. The distribution was not normalizable. Mean = 10.85 Std. dev. = 7.198 Critical Tn = 2.603 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.8245 Critical = 0.911 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 Constituent: Cobalt Analysis Run 6/23/2020 9:54 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables WQStat Plus'" v.9.4.32 Within Limit 30 24 18 12 on 0 4- 10/6/09 Prediction Limit Intrawell Parametric 11 /5/11 12/4/13 1 /3/16 2/1 /18 3/2/20 ■ MW-7 background ♦ MW-7 compliance Limit = 29.85 Background Data Summary: Mean=11.16, Std. Dev.=7.22, n=21. Insufficient data to test for seasonality: data were not deseasonalized. Report alpha = 0.01. Most recent point compared to limit. Constituent: Cobalt Analysis Run 6/23/2020 9:55 AM Facility: Hanes Mill Road Landfill Data File: Hanes Mill Stats Tables (� GOLDER golder.com