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HomeMy WebLinkAbout5802_Madison_MSWLF_March20GW_FID1417199_20200625pNL+: ❑P�r Re;.ort []Electronic Data- Email CD pats loaded: Yes / No Doc/Event #. C DENK Environmental Monitoring Division of Waste Management - Solid Waste Reportin Form Notice: This foim and any rnf ai ation aftached to It are "Pul5lic Reco s as defined in NC Gin-eraal Statute f 32-1._As such t�iese�ents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. .Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QF-A of North Carolina, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Alec Macbeth E-mail: amacbethManchoroea.00m Facility name: Facility Address: Madison County Closed Solid (89 Long Branch Road Waste Facility Marshall, NC 28753 Phone: 828-281-3350 NC Landfill Rule: Actual sampling dates (e.g., Facility Permit # (.0500 or .1600) October 20-24, 2006) 58-02 .0500 Ma rch 26, 2020 Environmental Status: (Check all that apply) Initiai/Background Monitoring 0 Detection Monitoring Assessment Monitoring T. ,e of data submitted: (Check all that apply) X Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data ❑ Other(specify) . Surface water monitoring data 0 Corrective Action Notification attached? _ RNo. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 213 surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. :Certification - - - - ---- - - -- - - - - - - --- — - -- - - o the best of my knowledge, the information reportea and statements made on this data su m tia and arl.ac' ments are true an-; correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and Imprisonment. Alec Macbeth. PG Projec tGeologis t Fa ' i Representative Name (Print) i tte tY ep T. A__ _y Va June 25, 2020 Signature �'�1+� ►'1►� Date 231 Haywood Street Asheville, North Carolina 28806 Facility Representative Address P-1649 NC PE.Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 828-281.3350 (Area Code) Telephone Number Affix NC Licensed/ Processional Geologist Seal #1 CAI? �. SEAL 6 Cj f� c 2205 �•; u, ��� • FR PA1y�- oe��, atteao� June 2020 Madison County Closed Solid Waste Facility, Permit No. 58-02 ti9 INZANCHOR QEA Spring 2020 Semiannual Water Quality Monitoring Report Prepared for Madison County, North Carolina June 2020 Madison County Closed Solid Waste Facility, Permit No. 58-02 Spring 2020 Semiannual Water Quality Monitoring Report Prepared for Madison County, North Carolina Post Office Box 579 Marshall, North Carolina 28753 Alec Macbeth, Macbeth, PG = �r SEAL nt ?2205 Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Ashen, North Carolina 28801 L. r �t Project dumber: C91 50001.01 �(�f: �'� \\ashevillel\asheville\Projects\Madison County\Re �/►J�$- dosed\Text\5802_Madison Closed Spring 2020 Semiannual Water Quality Report _062520.docx �j�0, TABLE OF CONTENTS 1 Introduction 2 Methods 1 2 2.1 Monitoring Well Sampling Methods...........................................................................................................2 2.1.1 Monitoring Wells MW-01 OLD and BG SPRING OLD...........................................................2 2.1.2 Monitoring Wells MW-02 OLD, MW-03 OLD, and MW-04 OLD......................................2 2.2 Surface Water Sampling Methods................................................................................................................3 2.3 Sample Handling, Documentation, and Analysis....................................................................................3 3 Findings........................................................................................................................................4 3.1 Groundwater.........................................................................................................................................................4 3.1.1 Field Parameters..................................................................................................................................5 3.1.2 RCRA Metals..........................................................................................................................................5 3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................5 3.2 Surface Water.......................................................................................................................................................6 3.2.1 Field Parameters..................................................................................................................................6 3.2.2 RCRA Metals..........................................................................................................................................6 3.2.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................6 3.3 Site Hydrogeology..............................................................................................................................................6 4 Summary......................................................................................................................................7 4.1 Future Activities...................................................................................................................................................7 5 References...................................................................................................................................8 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Summary of Detected Constituents FIGURES Figure 1 Site Location Map Figure 2 Sample Location Map APPENDICES Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation Spring 2020 Semiannual Water Quality Monitoring Report i June 2020 ABBREVIATIONS µg/L micrograms per liter µS/cm microsiemens per centimeter Closed Landfill closed municipal solid waste landfill DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration MDL method detection limit mg/L milligrams per liter MRL method reporting limit mV millivolt NCAC North Carolina Administrative Code NTU nephelometric turbidity unit ORP oxidation-reduction potential RCRA Resource Conservation and Recovery Act SC specific conductivity SESD EPA Region 4 Science and Ecosystem Support Division SU standard unit SWS Solid Waste Section TOC top of well casing VOC volatile organic compound Spring 2020 Semiannual Water Quality Monitoring Report ii June 2020 Introduction The Madison County Solid Waste Department maintains a closed municipal solid waste landfill (Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road (State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1. The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM), under Permit No. 58-02 (the permit), which requires semiannual monitoring of groundwater and surface water quality. This report, prepared by Anchor QEA of North Carolina, PLLC, is being submitted in accordance with monitoring requirements for the Closed Landfill as stipulated in the permit, with regulations codified in the DEQ Solid Waste Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina Administrative Code (15A North Carolina Administrative Code [NCAC] 13B .1600). This report describes the first semiannual groundwater and surface water quality monitoring event performed in 2020. The water quality monitoring network for the Closed Landfill consists of four monitoring wells (MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background groundwater quality sampling location (BG SPRING OLD), and two surface water sampling locations (SW-01 OLD [upstream] and SW-02 OLD [downstream]) located along Profitt Branch (Figure 2). Monitoring wells MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the western part of the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower elevations within topographic drainages in the southern part of the landfill parcel and are screened in the upper saturated zone. The water sample collected from background sampling location BG SPRING OLD is treated as a groundwater sample for the following reasons: • Groundwater does not discharge to the ground surface at the sampling point. • Construction of the sampling point is similar to that of a temporary monitoring well and is located upslope and upgradient of a springhead. • The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground surface with a screened interval from which groundwater is collected and recharges. Anchor QEA personnel attempted to contact the resident of the property owned by Mrs. J.V. Edwards (99 Log Branch Road, Marshall, North Carolina) but were unsuccessful. As such, Anchor QEA did not collect a sample from the residential well (DW-01) owned by Mrs. Edwards during the spring 2020 sampling event. Spring 2020 Semiannual Water Quality Monitoring Report 1 June 2020 2 Methods Groundwater samples and a surface water sample were collected at the Closed Landfill by Anchor QEA personnel on March 26, 2020. 2.1 Monitoring Well Sampling Methods Prior to groundwater sample collection from the monitoring wells, the static water level was measured and recorded to calculate the volume of water within the well. At each sample location, an initial round of field parameters (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], oxidation-reduction potential [ORP], turbidity, and temperature) was measured and recorded. Water level measurements, field parameters, and observations pertaining to water quality are included in the sampling logs in Appendix A. 2. 7. 7 Monitoring Wells MW-01 OLD and BG SPRING OLD Following initial field parameter collection, groundwater monitoring well MW-01 OLD and sampling point BG SPRING OLD were each purged using a new disposable polyethylene bailer. MW-01 OLD and BG SPRING OLD were purged and sampled with a disposable bailer due to poor well access, which inhibited the use of pump, controller, and associated tubing. As each consecutive well volume was removed with the bailer, an additional round of groundwater parameters was recorded. Each well was purged until a minimum of three well volumes had been removed and field parameters had stabilized, or until the well had been bailed dry. All groundwater samples were collected by a technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into laboratory -supplied sample containers. 2. 7.2 Monitoring Wells MW-02 OLD, MW-03 OLD, and MW-04 OLD Monitoring wells MW-02 OLD, MW-03 OLD, and MW-04 OLD were purged and sampled with a bladder pump using low -flow techniques in accordance with the procedures described in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (Puls and Barcelona 1996). During purging, pH, SC, DO, ORP, turbidity, and temperature were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had stabilized for three consecutive readings. The following required stabilization criteria have been established by the U.S. Environmental Protection Agency (EPA) Region 4 Science and Ecosystem Support Division Operating Procedure: Groundwater Sampling (EPA SESD 2017): • pH values within ± 0.1 unit • SC values within ± 5% • Temperature, DO, and turbidity values within ± 10% Spring 2020 Semiannual Water Quality Monitoring Report 2 June 2020 Following stabilization of these parameters, a groundwater sample was collected by a technician wearing a new pair of non -reactive nitrile gloves. Each sample was placed directly into laboratory -supplied sample containers. 2.2 Surface Water Sampling Methods Surface water samples SW-01 OLD and SW-02 OLD are collected semiannually at designated locations along Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a westerly direction (Figure 2). The surface water sample collected at the SW-01 OLD location is interpreted to represent surface water quality upstream of the Closed Landfill, and the surface water sample collected at the SW-02 OLD location is interpreted to represent surface water quality downstream of the Closed Landfill. For the samples SW-01 OLD and SW-02 OLD, field parameters, including temperature, pH, SC, DO, ORP, and turbidity were measured and recorded at the surface water sampling location prior to sample collection (Appendix A). The one surface water sample was collected and transferred into laboratory -supplied sample containers by a technician wearing a new pair of non -reactive nitrile gloves. 2.3 Sample Handling, Documentation, and Analysis Field parameters and additional observations pertaining to water quality sampling at the Closed Landfill sampling locations are provided in the sampling logs in Appendix A. Following sample collection, groundwater and surface water samples were immediately placed on ice in sample coolers for transport to Waypoint Laboratories, Inc. (Waypoint), a laboratory certified in North Carolina and located in Raleigh, North Carolina. Anchor QEA submitted all collected groundwater and surface water samples to Waypoint for the following analyses: Appendix I volatile organic compounds (VOCs), using EPA Method 8260B - Appendix I parameters are identified in Appendix I of the Code of Federal Regulations, Title 40, Part 258 (40 Code of Federal Regulations 258). • 1,4-Dioxane, using EPA Method 8260SIM • Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6010D and 7470A A summary of laboratory analyses performed on the samples is provided in Table 1. One trip blank, provided by the laboratory and stored in the sample cooler, was analyzed for Appendix I VOCs. Proper chain -of -custody documentation procedures were followed during collection and transport of each sample. The laboratory analytical reports and chain -of -custody documentation are included in Appendix B. Spring 2020 Semiannual Water Quality Monitoring Report 3 June 2020 3 Findings The field parameter data and laboratory analytical results for the groundwater, surface water, and trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively, and are also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data Deliverable format (DENR 2014). All laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections are values reported by the laboratory as "below method detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that can be accurately determined by the referenced method. • Groundwater Quality Standards: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 02L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMAQ for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202). For the purposes of this report, groundwater standards were taken from the October 15, 2018 list published by the North Carolina SWS (DEQ 2018). • 2B Standard: Detections of analytes in surface water samples were compared to the surface water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 2 summarizes the field parameter results and laboratory analytical results for detected constituents. The following discussion outlines constituents detected at concentrations that exceeded their respective groundwater quality standards or 2B standards. 3.1 Groundwater The following sections summarize the results of field parameter and laboratory analyses of groundwater samples collected on March 26, 2020. Spring 2020 Semiannual Water Quality Monitoring Report 4 June 2020 3. 7. 7 Field Parameters The pH readings obtained from monitoring wells MW-01 OLD, MW-03 OLD, MW-04 OLD, and BG-SPRING OLD (6.24 to 6.42 standard units [SU]) were less than the range for pH (6.5 to 8.5 SU) specified in the 2L standard (Table 2). The pH reading obtained from monitoring wells MW-02 OLD (6.81 SU) was within the 2L standard. Turbidity in the monitoring wells ranged from 1.02 nephelometric turbidity units (NTU) in monitoring well MW-03 OLD to 233 NTU in BG SPRING OLD. Measured DO values ranged from 1.37 milligrams per liter (mg/L) in MW-03 OLD to 8.35 mg/L in MW-02 OLD. SC values ranged from 105.5 microsiemens per centimeter (pS/cm) in BG SPRING OLD to 868 pS/cm in MW-03 OLD. ORP values in the monitoring wells ranged from -58.7 millivolts (mV) in MW-03 OLD to 233 mV in BG SPRING OLD (Table 2). These parameters do not have established groundwater quality standards. Concentrations of field parameters are generally consistent with historical concentrations. 3. 7.2 RCRA Metals Five metals (arsenic, barium, chromium, lead, and selenium) were detected in groundwater samples collected from one or more monitoring wells (Table 2). Two of these metals, barium and chromium, were detected at concentrations that exceeded their associated groundwater protection standards. Barium exceeded its 2L standard of 700 micrograms per liter (pg/L) in the samples collected from MW-03 OLD (810 pg/L) and MW-04 OLD (720 pg/L). Chromium exceeded its 2L standard of 10 pg/L in one well, BG SPRING OLD (11 pg/L). This well represents background water quality and the presence of chromium may not be associated with the landfill. In addition, the sample showed an elevated turbidity value which may affect the reported metal concentrations. The fall 2019 sampling event showed lower metal concentrations and a lower turbidity value in the BG-SPRING OLD sample (Anchor QEA 2020). The spring 2019 sampling event, however, showed similar metal concentrations as well as an elevated turbidity value (Anchor QEA 2019). 3. 7.3 Appendix 1 VOCs and 1,4-Dioxone Twelve VOCs (1,1-dichloroethane; 1,2-dichlorobenzene; cis- 1,2-dichloroethene; 1,4-dichlorobenzene; 1,4-dioxane; acetone; benzene; chlorobenzene; chloroethane; ethylbenzene; tetra hydrofu ran; and vinyl chloride) were detected in groundwater samples collected from one or more of the monitoring wells (Table 2). Of the detected compounds, two (benzene and vinyl chloride) were detected at concentrations that exceeded the associated groundwater quality standard. The benzene exceedance occurred in MW-03 OLD (2 pg/L) and vinyl chloride exceedance occurred in MW-01 OLD (0.41 J pg/L). The VOC detections are generally consistent with historical data. Spring 2020 Semiannual Water Quality Monitoring Report 5 June 2020 3.2 Surface Water The following sections summarize the results of laboratory and field parameter analyses of surface water samples SW-01 OLD and SW-02 OLD. 3.2. 7 Field Parameters The pH readings collected from SW-01 OLD and SW-02 OLD were 7.59 and 7.82 SU, respectively. The readings were within the 2B standard range established at 6 to 9 SU. The turbidity readings collected from SW-01 OLD and SW-02 OLD were 35.6 and 62.8 NTU, respectively. SW-02 OLD exceeded the 2B standard of 50 NTUs. These turbidity readings may have been affected by heavy rainfall approximately 48 hours prior to the sampling event. The DO readings collected from SW-01 OLD and SW-02 OLD were 11.62 and 12.55 mg/L, respectively. The values are within the 2B standard for Class C waters (greater than or equal to 5 mg/L). The SC measurements in SW-01 OLD and SW-02 OLD were recorded at 105.9 and 135.1 pS/cm, respectively. The ORP values for these samples were recorded at 151.6 and 94.3 mV (Table 2). These parameters do not have established surface water quality standards. 3.2.2 RCRA Metals Three metals (barium, chromium, and lead) were detected in the surface water samples. Lead was the only constituent that exceeded its respective calculated 2B standard of 0.76 pg/L at location SW-01 OLD (0.84 J pg/L) and SW-02 OLD (0.87 J pg/L) (Table 2). SW-01 OLD is the upstream sampling location. 3.2.3 Appendix 1 VOCs and 1,4-Dioxane Acetone was the only VOC detected in the samples collected from SW-01 OLD and SW-02 OLD at 5.2 and 3.3 pg/L respectively, which are less than the 2B standard of 2,000 kg/L. Acetone is a common laboratory artifact. No other VOCs were detected in the surface water sample. 3.3 Site Hydrogeology Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 3.91, 6.39, 35.72, and 38.05 feet below the top of the well casing (TOC), respectively (Appendix A). The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the shallow groundwater is interpreted to generally mimic topography, flowing primarily southward toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an elevation of approximately 2,100 feet above mean sea level and slopes downward toward Profitt Branch. Spring 2020 Semiannual Water Quality Monitoring Report 6 June 2020 4 Summary Anchor QEA completed the first semiannual water quality monitoring event of 2020 at the Closed Landfill on March 26, 2020. Table 1 summarizes the sampling and analyses that were performed. Table 2, the field sampling logs (Appendix A), and the Waypoint Reports of Laboratory Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and surface water quality at the Closed Landfill. The following bullets summarize the results of the sampling event: • The detected concentration of barium exceeded its 2L standard of 700 pg/L in the samples collected from two of the monitoring wells, MW-03 OLD (810 pg/L) and MW-04 OLD (720 pg/L). • The detected concentration of chromium from BG SPRING OLD exceeded its 2L standard of 10 pg/L (11 pg/L). BG SPRING OLD represents the background well at the Closed Landfill. Therefore, the presence of chromium may not be associated with the landfill. The sample from this monitoring well also exhibited several other metals in addition to the chromium exceedance. These metal detections may be associated with the sample's elevated turbidity (233 NTUs; Table 2). • Two VOCs, benzene (2 pg/L) and vinyl chloride (0.41 J pg/L) were detected in the samples collected from MW-03 OLD and MW-01 OLD respectively, at concentrations exceeding the associated groundwater quality standards (2L standards). • The measured depths to groundwater in the upper saturated zone within the topographic drainages at the landfill ranged from 3.91 to 6.39 feet below TOC. The groundwater depths in the bedrock monitoring wells at top of the ridge ranged from 35.72 to 38.05 feet TOC. The shallow groundwater is interpreted to generally mimic topography, flowing primarily southward toward Profitt Branch. 4.1 Future Activities Anchor QEA will continue to measure field parameters and collect water quality samples from groundwater and surface water monitoring points associated with the Closed Landfill. Water quality samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled for October 2020. Spring 2020 Semiannual Water Quality Monitoring Report 7 June 2020 5 References Anchor QEA (Anchor QEA of North Carolina, PLLC), 2019. Spring 2019 Semiannual Water Quality Monitoring Report, Madison County Closed Solid Waste Facility, Permit No. 58-02, June 30, 2019. Anchor QEA, 2020. Fall 2019 Semiannual Water Quality Monitoring Report, Madison County Closed Solid Waste Facility, Permit No. 58-02, January 6, 2020. DENR (North Carolina Department of Environmental and Natural Resources, Division of Waste Management), 2014. Memorandum Re: Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal, November 5, 2014. DEQ (North Carolina Department of Environmental Quality), 2018. "Groundwater Protection Compliance Standards — Constituents List". Last modified October 15, 2018. Available at: https://edocs.deq.nc.gov/WasteM a nag ement/0/edoc/1257181/SWS EnviroMonitoring Const ituents List.pdf?searchid=13f8efbl-eel 1-485a-b03f-718f2287b271 EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017. Operating Procedure: Groundwater Sampling. April 26, 2017. Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. Prepared for the U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response. EPA/540/5-95/504. April 1996. Spring 2020 Semiannual Water Quality Monitoring Report 8 June 2020 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Facility Permit Well ID Collect Date Sample ID Appendix I VOCs 1,4-Dioxane RCRA Metals EPA 8260B EPA 8260B SIM EPA 6020B EPA 7470A 58-02 MW-01 OLD 03/26/2020 MW-01 OLD-20200326 X X X 58-02 MW-02 OLD 03/26/2020 MW-02 OLD-20200326 X X X 58-02 MW-03 OLD 03/26/2020 MW-03 OLD-20200326 X X X 58-02 MW-04 OLD 03/26/2020 MW-04 OLD-20200326 X X X 58-02 BG SPRING OLD 03/26/2020 BG SPRING OLD-20200326 X X X Surface Water Samples Facility Permit Location ID Collect Date Sample ID Appendix I VOCs 1,4-Dioxane RCRA Metals Total Hardness EPA 8260B EPA 8260B SIM EPA 6020B EPA 7470A EPA SM 2340C 58-02 SW-01 OLD 03/26/2020 SW-01 OLD-20200326 X X X X 58-02 SW-02 OLD 03/26/2020 SW-02 OLD-20200326 X X X X Quality Control Samples Facility Permit ID Collect Date Sample ID Appendix I VOCs EPA 8260B 58-02 TRIP BLANK 03/26/2020 TB-20200326 X Notes: Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258). A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event. EPA: U.S. Environmental Protection Agency RCRA: Resource Conservation and Recovery Act SM: standard method SIM: selective ion monitoring VOC: volatile organic compound Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 1 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 June 2020 Table 2 Summary of Detected Constituents Field Parameters Water Level Depth (feet Temperature ('Q Dissolved oxygen (mg/L ORP (nnV) Turbidity (NTU) pH (SU) Specific Conductivity (µv Other Hardness as CaCO3 Metals (Ng/L) Arsenic Barium Chromium Lead Selenium Volatile Organics (Ng/L) 1,1-Dichloroethane 1,2-Dichlorobenzene 1,2-Dichloroethene, cis- 1,4-Dichlorobenzene 1,4-Dioxane Acetone Benzene Chlorobenzene Chloroethane Ethylbenzene Tetra hyd rofu ra n Vinyl chloride NC2L Method NC21- IMAC )Q Field Measure Field Measure Field Measure Field Measure Field Measure Field Measure 6.5-8.5 m) Field Measure SM2340C SW6020 10 SW6020 700 SW6020 10 SW6020 15 SW6020 20 SW8260 6 SW8260 20 SW8260 70 SW8260 6 SW8260 3 SW8260 6000 SW8260 1 SW8260 50 SW8260 3000 SW8260 600 SW8260 SW8260 0.03 Location ID Sample ID Sample Date Sample Type Matrix NC2B BG SPRING OLD BG SPRING OLD - 20200326 3/26/2020 N WG Groundwater Samples Surface Water Samples QC Sample MW-01 OLD MW-02 OLD MW-03 OLD MW-04 OLD SW-01 OLD SW-02 OLD Field QC MW-01 OLD- 20200326 MW-02 OLD- 20200326 MW-03 OLD- 20200326 MW-04 OLD- 20200326 SW-01 OLD- 20200326 SW-02 OLD- 20200326 TB-20200326 3/26/2020 3/26/2020 3/26/2020 3/26/2020 3/26/2020 3/26/2020 3/26/2020 N N N N N N TB WG WG WG WG WS WS WQ 3.92 3.91 6.39 35.72 38.05 11.8 11.1 11.9 15.3 16.8 >_5.0 4.18 2.39 8.35 1.37 2.73 213.7 48 218.2 -58.7 70.2 <50 233 127 4.2 1.02 10 6.0-9.0 6.24 6.25 6.81 6.42 6.31 105.5 391.8 212.8 868 822 10 0.77 J 0.71 J 0.34 U 0.34 U 0.34 U 21000 130 350 57 810 720 *30.63 11 5.1 0.9U 0.9U 0.9U *0.76 2.6 1.7 0.44 U 0.44 U 0.61 J 5 1.4 J 1.5 1 0.98 U 0.98 U 0.98 U 100 0.29 U 0.3 J 0.78 0.29 U 0.29 U 0.28 U 0.28 J 0.28 U 0.28 U 0.28 U 720 0.4U 1.1 0.4U 0.4U 0.4U 56 0.42 U 2.3 0.42 U 3.8 2 0.14U 2.6 0.14U 0.14U 0.14U 2000 0.7 U 2.7 2.9 0.7 U 3.1 51 0.34 U 0.43 J 0.34 U 2 0.54 140 0.34 U 1.5 0.34 U 6.6 4.3 0.43 U 0.5 0.43 U 0.65 0.87 97 0.31U 0.31U 0.31U 2 0.31U 0.68U 0.68U 0.68U 1.11 1.4J 2.4 0.47U 0.41J 0.47U 0.47U 0.47U 11.5 11.62 151.6 35.6 7.59 105.9 38 0.34 U 66 1.6 J 0.84 J 0.98 U 0.29 U 0.28 U 0.4 U 0.42 U 0.14 U 5.2 0.34 U 0.34 U 0.43 U 0.31 U 0.68 U 0.41 U 11.4 12.55 94.3 62.8 7.82 135.1 30 0.34 U 50 2.4 J 0.87 J 0.98 U 0.29 U 0.28 U 0.4 U 0.42 U 0.14 U 3.3 0.34 U 0.34 U 0.43 U 0.31 U 0.68 U 0.41 U 0.29 U 0.28 U 0.4 U 0.42 U 0.14 U 0.7 U 0.34 U 0.34 U 0.43 U 0.31 U 0.68 U 0.41 U Spring 2020 Semiannual Water Quality Monitoring Report Page 1 of 2 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 June 2020 Table 2 Summary of Detected Constituents Notes: Detected concentration is greater than NC2L (2013) or IMAC (2013) screening level Detected concentration is greater than NC213 screening level Bold: Detected result Italicized: Non -detected concentration is above one or more identified screening levels *: NC213 surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017). µg/L: micrograms per liter NC2B: surface water standard per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B — Surface Water and Wetland Standards (last amended in September 2017), or the standard obtained from the EPA Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health. NC2L: Subchapter 2L — Groundwater Classifications and Standards, Department of Environmental Quality (Amended April 1, 2013). Groundwater standard from North Carolina Administrative Code, Title 15A. All nondetect results are reported at the method detection limit. Appendix I: indicates volatile organic compounds and metals per 40 Code of Federal Regulations Part 258 Horizontal coordinate datum is NAD 1983 State Plane North Carolina FIPS 3200 (U.S. Survey Feet). °C: degrees Celsius µg/LL micrograms per liter µs/cm: microsiemens per centimeter CaCO3: calcium carbonate IMAC: Interim Maximum Allowable Concentration. IMAC concentrations are listed in Appendix #1 of the 2L. J: laboratory qualifier used to indicate a detection at estimated concentrations greater than the minimum detection limit (MDL) but less than the laboratory's method reporting limit (MRL) mg/L: milligrams per liter mv: millivolts N: normal environmental sample NTU: nephelometric turbidity unit ORP: oxidation-reduction potential SU: standard unit TB: Trip Blank TOC: top of casing U: Compound analyzed for, but not detected above detection limit WG: groundwater WS: surface water WQ: water quality Spring 2020 Semiannual Water Quality Monitoring Report Page 2 of 2 Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 June 2020 Figures ;alp 4 _ CcM rye Madison Sem O s" v .1., \ � - � °O , . % ('N • 7 / 1. � , •.._ + sloe— /� � v, �/ \� •.moo .✓,}� - - /. • lam,✓ � „ `" l-• � -,.1 � ?-= j 1' LEGEND: SOURCES: Basemap: USGS 1:24,000 Scale Topo Maps, Marshall 0 2,000 Landfill Parcel Quadrangle, 1990 Parcels: Madison County GIS Feet Publish Date: 2020/05/14, 6:26 PM I User: adowell Filepath: Q:\Jobs\MadisonCounty_NC_1500\Maps\2020\AQ_F01_SiteLocationMap_ClosedLF_SpringWQ2020.mxd ANCHOR Figure 1 0EA=_- Site Location Map Anchor QEA of North Carolina, PLLC Spring 2020 Semiannual Water Quality Report Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 .� r" t✓ ". 1��� +4 y' ".� r FI ` k l LEGEND: Monitoring Well Location Residential Well Location (Not Sampled in Spring 2020 Because Owner Could Not be Contacted) - Surface Water Sample Location NOTE: Monitoring well and surface water samples are Q Landfill Parcel Boundary approximate. Elevation Contours (10-Foot Interval) SOURCES: Basemap: NC One Map 2018 Roads Contours and Roads: NCDOT Streams Streams: NC OneMap Parcel Boundary: Madison County GIS T 0 400 Feet Publish Date: 2020/06/08, 4:20 PM I User: alesueur Filepath:\\orcas\gis\Jobs\MadisonCounty_NC_1500\Maps\2020\AQ_F02_SampleLocation Map_Closed LF_SpringWQ2020.mxd ANCHOR Figure 2 QEA- Sample Location Map Anchor QEA of North Carolina, PLLC Spring 2020 Semiannual Water Quality Report Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data Sheets kZANCHOR QEA Well Sampling Log Date: �f2,�J 1.2o Well Name: MW-01 OLD Project Name: Madison County Landfill - Closed 11 Project Number: C91500-01.01 Task 02 Weather: Sampling Personnel: C. Lohmeyer / M. Kemp Sample Time: Well Information: Well Depth in Feet (WD): 20.8 Well Diameter: 2" Water Level in Feet (WL):� Type of Casing: PVC Length of Water Column: 1 fe, k"01 feet Screen Interval: -- (WD) - (WL) = (LWC) Flush Mount / t Up One Casing Volume: Z r S 7 gallons Comments: (LWC) x (WCV) Three Casing Volumes: �s gallons Tagged Actual Volume Purged: gallons bottom at Well Casing Volumes (WCV) 1" = 0.041 Gal/Ft 2" - .17 Ga /Ft 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft ailer-Disp. Purge Method: (Bailer-Dis Ba eflon Dedicated Pump Whale Pump Grundfos Other. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: OxldaHon Gallons Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity Reading Time Purged CC) Oxygen (mg/L) (pS/cm) reportto 0.7 S.U. Potential (mV) (NTU) Comments 1 (0to.. 0 istl.l. 3 f A,r, [110 3'Z 4 44"k,r (p Z. qS- i! Z? 5 6 7 j 8 9 10 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per centimeter mg/L. milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing: Pad: __(2Y I Lock: Vegetatiori Access: Sampling Personnel Signature: Date: initial if well information and sampling data has been verified _ well was tagged after sampling was complete ANCHORIt fll� QEA Low -Flow Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name:�� �� }�� Project Number: Location: Date: GJ$i1R )V �+ Sampling Personnel: `1 �>� 4,, _ Weather: Well ID: M f1� �j(r� — Arrive at Well: Screen Interval: _ bgs Start Time: Depth to Water. �A toc Sample Time: Stickup: ! Finish Sample Time: Depth of Pump Intake: — 3 S toc Leave Well: Drawdown Set: T 0 toc Well Diameter: Pump Used (circle): Pe&ic Bladder Other (description): Comments: ? vv �A �', �,s�V •• Ol� 6l — 3.1Z-16 �►tf� _ Tci3 _ 02 r S—br j"101) Dp� JPS oq L f S �Ei ss �Lm Time DTW (feet) Temp (°C) Specific Cond. (pS) DO (mg/L) PH (S.U.) report to 0.1 S.U. ORP (mV) Turbidity (NTU) 012- E, 21$, (a 90 11 o1� TW) L ? I ig.y_. 9 (9132- 2-12. -7 %•4I2, 013, I1.9 ��-.� ,35 2-L 3.17 Ji# .7- IL L 441 n'. 7- `13-3 PO 21-1 Y tz �.�r 2��. Z 4(.2.a - Time between recharge during sample collection: Sampling Personnel Signature: Date: �D Notes: Stabilization 3 successive readings, 3 minutes apart: within +/- 10% DO and turbidity, +/- 3% Conductivity,, +/- 0.7 pH unit +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. uS: micro-Siemen °C: degrees Celsius bgs: below ground surface DO: dissolved oxygen mg/L: milligrams per liter mv: millivolt NTU: nephelometdc turbidity units ORP: oxidation reduction potential S.U.: standard units toc: top of casing Page 1 of 1 ANCHOR QEA Low -Flow Sampling Log Date: ;: f Well Name: MW-03 OLD Project Name: Madison County Landfill - Closed Project Number: C91500-01.01 Task 02 Location: Marshall, NC Personnel: C. Lohmeyer / M. Kemp Weather: 5-� . Well Information: Screen Interval: 44-49 _ bgs Arrive at Well: CQ Depth to Water: 3 toc Start Time: Well Diameter: 2 _ in Sample Time: LO3 Pump Intake: 45 toc Finish Sample Time: elf Drawdown Set: toc Leave Well: GB l 0 Pump Used (circle): Peristaltic Bladder Other (description): Comments: Purge Rate: Tagged bottom at: 49.0 Total Purge Volume: Pump Speed: 72-1 Time DTW (feet) Temp VQ DO (mg/L) Specific Cond. (p5) pH (S.U.) report to D.T. ORP (mV) Turbidity (NTU) Comments - J�5-?- 3 Ljo Z - A& 1. 3 q - 3 7 �k - -� �31 - � s(,,La . 6.39 _` -0 io -7 —s2 - 2 $ la . t 9(07 (vey ( s-j. k -'D .�a _ 2 1 i 1-2 4 . 2 1 0-5-D -_LQ-5..3. S 5" IS-S 35- e- 3 o.R b Time between recharge during sample collection: Sampling Personnel Signature: Date: Notes: Stabilization 3 successive readings, 3 minutes apart: within +/- 70% DO and turbidity, +/- 3% Conductivity,, +/- 0.7 pH unit; +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. VS: micro-Siemen °C: degrees Celsius bgs: below ground surface DO: dissolved oxygen mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units ORP: oxidation reduction potential S.U.: standard units toc: top of casing initial if well information and sampling data has been verified _ well was tagged after sampling was complete kZANCHOR QEA Low -Flow Sampling Log Date: � I ?J, I7 r7 Well Name: MW-04 OLD Project Name: Madison County Landfill - Closed Project Number: C 1500-01.01 Task 02 Location: Marshall, NC Personnel: C. Lohmeyer / M. Kemp Weather: ��31SWth Well Information: Screen Interval: 70-90 bgs Arrive at Well: (()5 Depth to Water: r 115 toc Start Time: Well Diameter: 2 in Sample Time:--" — Pump Intake: 80 toc Finish Sample Time: ( f Sly Drawdown Set: toc Leave Well:45, Pump Used (circle): Peristaltic Bladder Other (description): Comments: Purge Rate: 1 0 L�wti�� Tagged bottom at: Total Purge Volume: N Pump Speed: d Time DTW Temp (feet) (°C) DO (mg/0 Specific Cond. (PS) pH (S.U.) ORP report to 0.1. (mN) Turbidity (NTU) Comments f f07-T.010`[ i "J.— He- l'o` (VA47.i7� ISk. 7._ I W6.7 T 2-- [v� 3 7,01 2 ? 2��3 t 3 -o 94 �. 2 12 c42 , 1.2 ff -. G (lo . -21 2 (o `� o. 1 .3� 70 - a Time between recharge during sample collection: Sampling Personnel Signature: Date: Notes: Stabilization 3 successive readings, 3 minutes apart: within +/- 70% DO and turbidity,- +/- 3% Conductivity, +/- 0.1 pH unit,• +/- 10 mV (or ORP from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. NS: micro-Siemen mv: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing initial if well information and sampling data has been verified well was tagged after sampling was complete ANCHOR QEA Well Sampling Log Date: '1� i 7A, /�_,, Well Name: BIG -SPRING OLD Project Name: Madison County Landfill - Closed Project Number: C91500-01.01 Task 02 — Weather. Sampling Personnel: C. Lohmeyer / M. Kemp Sample Time: Well Information: Well Depth in Feet (WD): 14.3 Well Diameter: 2" Water Level in Feet (WL): q <2— Type of Casing: PVC Length of Water Column: • 3 g feet Screen Interval: -- (WD) - (WL) = (LWC) Flush Mount / Stick -Up One Casing Volume: I . 7 gallons Comments: (LWC) x (WCV) Three Casing Volumes: 5 Z gallons Tagged Actual Volume Purged: A,- gallons �� bottom at: Well Casing Volumes (WCV) 1" = 0.041 Gal/Ft 2" = 17 Gal/ 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft Purge Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other: Oxidation Gallons Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity Reading Time . Purged (°C) Oxygen (mg/L) (PS/cm) report to 0.1 S.U. Potential (mV) (NTU) Comments 1 2 !2 Z� .i�. 0-©. —�. 0 ( ,a . 2 ( �G 11 b iP, �J_]_ ( �1e. 2 2(0 - 4_...1..L. �r 24.-7 23 5 6 7 8 9 10 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius uS/cm: micro-Siemen per centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing: V Pad: ✓ Lock: Vegetation: _X_ Access: — Fes` Sampling Personnel Signature: Date: ur"j initial if well information and sampling data has been verified _ well was tagged after sampling was complete 4-0 ANCHOR QE Surface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Madison County Landfill - Closed Project Number: C91500-01.01 Task 02 Sampling Personnel: C. LOhmeyer / M. Kemp Sample Name: SW-01 OLD Comments: �� 3 Date: Weather. +� W Sample Method: Grab Syringe Pump Bailer-Disp. Other: Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. his/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments 1,2-oSl 11. S 1 I.- ry z -7, sq l sl (,-2 �b Sampling Container Number of Containers Requested Analysis 300 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass Lo L4 1 L Glass Other Vegetation:Access: Sampling Personnel Signature: 01 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Date: Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR QFA �. iurface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Madison County Landfill - Closed Project Number: C91500-01.01 Task 02 Sampling Personnel: C. Lohmeyer / M. Kemp Sample Name: SW-02 OLD Comments: 3 Date: 1.7 Weather: (� Sample Method: Grab Syringe Pump Bailer-Disp. Other: Time Temp (°C) Dissolved Oxygen (mg/L) Specific Cond. (PS/cm) pH (S.U.) report to 0.1 S.U. Oxidation Reduction Potential (mV) Turbidity (NTU) Comments l Sampling Container Number of Containers Requested Analysis i00 mL Plastic 250 mL Plastic 2 y a �_ V1. 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: Sampling Personnel Signature:CP::::Ii Date: 3 1 Z'W v0 Notes: Samples are analyzed immediately upon collection. 'C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mv. millivolt NTU: nephelometric turbidity units S.U.: standard units Method Reference: Temperature: SM 2550 B-2010 Specific conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH: SM 4500-H' B-2011 Page 1 of 1 Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation Way poi nt ANALYTICAL Anchor QEA of North Carolina, PLLC Alec Macbeth 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Madison Closed Landfill Lab Submittal Date: 03/27/2020 Work Order: 0030354 Case Narrative 4/6/20 11:21 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a,j Angela D. Overcash Senior Project Manager Data Qualifiers Key Reference: CCVL CCV result is below control limits but within method parameters. A standard at or below the RL was analyzed and found acceptable. Result is reported but considered estimated. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). M Matrix spike outside of the control limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 32 0Sample Waypoint.. ANALYTICAL Receipt Summary 04/06/2020 Work Order: 0030354 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-01 OLD 20200326 0030354-01 Water 03/26/20 10:09 03/27/20 8:35 MW-02 OLD 20200326 0030354-02 Water 03/26/20 9:35 03/27/20 8:35 MW-03 OLD 20200326 0030354-03 Water 03/26/20 10:53 03/27/20 8:35 MW-04 OLD 20200326 0030354-04 Water 03/26/20 11:28 03/27/20 8:35 BG-SPRING OLD 20200326 0030354-05 Water 03/26/20 12:56 03/27/20 8:35 SW-02 OLD - 20200326 0030354-06 Water 03/26/20 12:05 03/27/20 8:35 SW-01 OLD - 20200326 0030354-07 Water 03/26/20 11:50 03/27/20 8:35 TB-20200326 0030354-08 Water 03/26/20 0:00 03/27/20 8:35 Samples were received in good condition at 2.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 32 Summary of Detections Way 04/06/202C poi nt Work Order: 0030354 ANALYTICAL Prism ID Client ID Parameter Method Result Units 0030354-01 MW-01 OLD 20200326 Arsenic 6020B 0.71 J ug/L 0030354-01 MW-01 OLD 20200326 Barium 6020B 350 ug/L 0030354-01 MW-01 OLD 20200326 Chromium 6020B 5.1 ug/L 0030354-01 MW-01 OLD 20200326 Lead 6020B 1.7 ug/L 0030354-01 MW-01 OLD 20200326 Selenium 6020B 1.5 J ug/L 0030354-01 MW-01 OLD 20200326 1,1-Dichloroethane 8260D 0.30 J ug/L 0030354-01 MW-01 OLD 20200326 1,2-Dichlorobenzene 8260D 0.28 J ug/L 0030354-01 MW-01 OLD 20200326 1,4-Dichlorobenzene 8260D 2.3 ug/L 0030354-01 MW-01 OLD 20200326 Acetone 8260D 2.7 CCVL, ug/L J 0030354-01 MW-01 OLD 20200326 Benzene 8260D 0.43 J ug/L 0030354-01 MW-01 OLD 20200326 Chlorobenzene 8260D 1.5 ug/L 0030354-01 MW-01 OLD 20200326 Chloroethane 8260D 0.50 ug/L 0030354-01 MW-01 OLD 20200326 cis-1,2-Dichloroethylene 8260D 1.1 ug/L 0030354-01 MW-01 OLD 20200326 Vinyl chloride 8260D 0.41 J ug/L 0030354-01 MW-01 OLD 20200326 1,4-Dioxane 8260D SIM 2.6 ug/L 0030354-02 MW-02 OLD 20200326 Barium 6020B 57 ug/L 0030354-02 MW-02 OLD 20200326 1,1-Dichloroethane 8260D 0.78 ug/L 0030354-02 MW-02 OLD 20200326 Acetone 8260D 2.9 CCVL, ug/L J 0030354-03 MW-03 OLD 20200326 Barium 6020B 810 ug/L 0030354-03 MW-03 OLD 20200326 1,4-Dichlorobenzene 8260D 3.8 ug/L 0030354-03 MW-03 OLD 20200326 Benzene 8260D 2.0 ug/L 0030354-03 MW-03 OLD 20200326 Chlorobenzene 8260D 6.6 ug/L 0030354-03 MW-03 OLD 20200326 Chloroethane 8260D 0.65 ug/L 0030354-03 MW-03 OLD 20200326 Ethylbenzene 8260D 2.0 ug/L 0030354-03 MW-03 OLD 20200326 Tetrahydrofuran 8260D 1.1 J ug/L 0030354-04 MW-04 OLD 20200326 Barium 6020B 720 ug/L 0030354-04 MW-04 OLD 20200326 Cadmium 6020B 0.22 J ug/L 0030354-04 MW-04 OLD 20200326 Lead 6020B 0.61 J ug/L 0030354-04 MW-04 OLD 20200326 1,4-Dichlorobenzene 8260D 2.0 ug/L 0030354-04 MW-04 OLD 20200326 Acetone 8260D 3.1 CCVL, ug/L J 0030354-04 MW-04 OLD 20200326 Benzene 8260D 0.54 ug/L 0030354-04 MW-04 OLD 20200326 Chlorobenzene 8260D 4.3 ug/L 0030354-04 MW-04 OLD 20200326 Chloroethane 8260D 0.87 ug/L 0030354-04 MW-04 OLD 20200326 Tetrahydrofuran 8260D 1.4 J ug/L 0030354-05 BG-SPRING OLD 20200326 Arsenic 6020B 0.77 J ug/L 0030354-05 BG-SPRING OLD 20200326 Barium 6020B 130 ug/L 0030354-05 BG-SPRING OLD 20200326 Chromium 6020B 11 ug/L 0030354-05 BG-SPRING OLD 20200326 Lead 6020B 2.6 ug/L 0030354-05 BG-SPRING OLD 20200326 Selenium 6020B 1.4 J ug/L 0030354-06 SW-02 OLD - 20200326 Hardness SM2340 C 30000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 32 (D Way po 0nt. ANALYTICAL Summary of Detections 04/06/202C Work Order: 0030354 Prism ID Client ID Parameter Method Result Units 0030354-06 SW-02 OLD - 20200326 Barium 6020B 50 ug/L 0030354-06 SW-02 OLD - 20200326 Chromium 6020B 2.4 J ug/L 0030354-06 SW-02 OLD - 20200326 Lead 6020B 0.87 J ug/L 0030354-06 SW-02 OLD - 20200326 Acetone 8260D 3.3 CCVL, ug/L J 0030354-07 SW-01 OLD - 20200326 Hardness SM2340 C 38000 ug/L 0030354-07 SW-01 OLD - 20200326 Barium 6020B 66 ug/L 0030354-07 SW-01 OLD - 20200326 Chromium 6020B 1.6 J ug/L 0030354-07 SW-01 OLD - 20200326 Lead 6020B 0.84 J ug/L 0030354-07 SW-01 OLD - 20200326 Acetone 8260D 5.2 CCVL ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 32 Way poi nt.. ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Project: Madison Closed Landfill Sample Matrix: Water Laboratory Report 04/06/2020 Client Sample ID: MW-01 OLD 20200326 Sample ID: 0030354-01 Work Order: 0030354 Time Collected: 03/26/20 10:09 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/30/20 13:52 JAB P000561 Arsenic 0.71 J ug/L 10 1.0 0.34 1 6020B 3/31/20 21:17 MMR P000556 Barium 350 ug/L 100 10 3.2 1 6020B 3/31/20 21:17 MMR P000556 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 3/31/20 21:17 MMR P000556 Chromium 5.1 ug/L 10 3.0 0.90 1 6020B 3/31/20 21:17 MMR P000556 Lead 1.7 ug/L 10 1.0 0.44 1 6020B 3/31/20 21:17 MMR P000556 Selenium 1.5 J ug/L 10 5.0 0.98 1 6020B 3/31/20 21:17 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:17 MMR P000556 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 16:38 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 16:38 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 16:38 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 16:38 JLB P000545 1,1-Dichloroethane 0.30 J ug/L 5 0.50 0.29 1 8260D 3/27/20 16:38 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 16:38 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 16:38 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 16:38 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 16:38 JLB P000545 1,2-Dichlorobenzene 0.28 J ug/L 5 0.50 0.28 1 8260D 3/27/20 16:38 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 16:38 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 16:38 JLB P000545 1,4-Dichlorobenzene 2.3 ug/L 1 0.50 0.42 1 8260D 3/27/20 16:38 JLB P000545 Acetone 2.7 CC ug/L 100 5.0 0.70 1 8260D 3/27/20 16:38 JLB P000545 VL, J Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 16:38 JLB P000545 Benzene 0.43 J ug/L 1 0.50 0.34 1 8260D 3/27/20 16:38 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 16:38 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 16:38 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 16:38 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 16:38 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 16:38 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 16:38 JLB P000545 Chlorobenzene 1.5 ug/L 3 0.50 0.34 1 8260D 3/27/20 16:38 JLB P000545 Chloroethane 0.50 ug/L 10 0.50 0.43 1 8260D 3/27/20 16:38 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 16:38 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 16:38 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-01 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-01 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 10:09 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis-1,2-Dichloroethylene 1.1 ug/L 5 0.50 0.40 1 8260D 3/27/20 16:38 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 16:38 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 16:38 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 16:38 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 16:38 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 16:38 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 16:38 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 16:38 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 16:38 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 16:38 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 16:38 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 16:38 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 16:38 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 16:38 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 16:38 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 16:38 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 16:38 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 16:38 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 16:38 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 16:38 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 16:38 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 16:38 JLB P000545 Vinyl chloride 0.41 J ug/L 1 0.50 0.41 1 8260D 3/27/20 16:38 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 16:38 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 2.6 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 14:44 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-02 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-02 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 09:35 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/30/20 13:56 JAB P000561 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 20:57 MMR P000556 Barium 57 ug/L 100 10 3.2 1 6020B 3/31/20 20:57 MMR P000556 Cadmium <0,22 ug/L 1 1.0 0.22 1 6020B 3/31/20 20:57 MMR P000556 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 3/31/20 20:57 MMR P000556 Lead <0.44 ug/L 10 1.0 0.44 1 6020B 3/31/20 20:57 MMR P000556 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 3/31/20 20:57 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 20:57 MMR P000556 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:03 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:03 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:03 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:03 JLB P000545 1,1-Dichloroethane 0.78 ug/L 5 0.50 0.29 1 8260D 3/27/20 17:03 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:03 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 17:03 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 17:03 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 17:03 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 17:03 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:03 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:03 JLB P000545 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:03 JLB P000545 Acetone 2.9 CC ug/L 100 5.0 0.70 1 8260D 3/27/20 17:03 JLB P000545 VL, J Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 17:03 JLB P000545 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 3/27/20 17:03 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 17:03 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:03 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 17:03 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 17:03 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 17:03 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 17:03 JLB P000545 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:03 JLB P000545 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 3/27/20 17:03 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 17:03 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-02 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-02 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 09:35 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:03 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 17:03 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 17:03 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 17:03 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 17:03 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:03 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 17:03 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 17:03 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 17:03 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 17:03 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 17:03 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 17:03 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 17:03 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 17:03 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:03 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 17:03 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 17:03 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 17:03 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 17:03 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 17:03 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 17:03 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 17:03 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 17:03 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:03 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 17:03 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 15:10 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-03 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-03 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 10:53 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/31/20 10:59 JAB P000574 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:23 MMR P000556 Barium 810 ug/L 100 10 3.2 1 6020B 3/31/20 21:23 MMR P000556 Cadmium <0,22 ug/L 1 1.0 0.22 1 6020B 3/31/20 21:23 MMR P000556 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 3/31/20 21:23 MMR P000556 Lead <0.44 ug/L 10 1.0 0.44 1 6020B 3/31/20 21:23 MMR P000556 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 3/31/20 21:23 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:23 MMR P000556 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:27 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:27 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:27 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:27 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 17:27 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:27 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 17:27 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 17:27 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 17:27 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 17:27 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:27 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:27 JLB P000545 1,4-Dichlorobenzene 3.8 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:27 JLB P000545 Acetone <0.70 CCVL ug/L 100 5.0 0.70 1 8260D 3/27/20 17:27 JLB P000545 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 17:27 JLB P000545 Benzene 2.0 ug/L 1 0.50 0.34 1 8260D 3/27/20 17:27 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 17:27 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:27 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 17:27 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 17:27 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 17:27 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 17:27 JLB P000545 Chlorobenzene 6.6 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:27 JLB P000545 Chloroethane 0.65 ug/L 10 0.50 0.43 1 8260D 3/27/20 17:27 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 17:27 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:27 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 17:27 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-03 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-03 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 10:53 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 17:27 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 17:27 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 17:27 JLB P000545 Ethylbenzene 2.0 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:27 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 17:27 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 17:27 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 17:27 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 17:27 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 17:27 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 17:27 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 17:27 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 17:27 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:27 JLB P000545 Tetrahydrofuran 1.1 J ug/L NE 10 0.68 1 8260D 3/27/20 17:27 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 17:27 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 17:27 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 17:27 JLB P000545 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 17:27 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 17:27 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 17:27 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 17:27 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:27 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 17:27 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 15:35 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 32 Laboratory Report • � 04/06/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-04 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 11:28 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/31/20 11:03 JAB P000574 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:30 MMR P000556 Barium 720 ug/L 100 10 3.2 1 6020B 3/31/20 21:30 MMR P000556 Cadmium 0.22 J ug/L 1 1.0 0.22 1 6020B 3/31/20 21:30 MMR P000556 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 3/31/20 21:30 MMR P000556 Lead 0.61 J ug/L 10 1.0 0.44 1 6020B 3/31/20 21:30 MMR P000556 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 3/31/20 21:30 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:30 MMR P000556 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:52 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:52 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:52 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:52 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 17:52 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 17:52 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 17:52 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 17:52 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 17:52 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 17:52 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:52 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:52 JLB P000545 1,4-Dichlorobenzene 2.0 ug/L 1 0.50 0.42 1 8260D 3/27/20 17:52 JLB P000545 Acetone 3.1 CC ug/L 100 5.0 0.70 1 8260D 3/27/20 17:52 JLB P000545 VL, J Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 17:52 JLB P000545 Benzene 0.54 ug/L 1 0.50 0.34 1 8260D 3/27/20 17:52 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 17:52 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:52 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 17:52 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 17:52 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 17:52 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 17:52 JLB P000545 Chlorobenzene 4.3 ug/L 3 0.50 0.34 1 8260D 3/27/20 17:52 JLB P000545 Chloroethane 0.87 ug/L 10 0.50 0.43 1 8260D 3/27/20 17:52 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 17:52 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 17:52 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-04 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 11:28 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 17:52 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 17:52 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 17:52 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 17:52 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:52 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 17:52 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 17:52 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 17:52 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 17:52 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 17:52 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 17:52 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 17:52 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 17:52 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 17:52 JLB P000545 Tetrahydrofuran 1.4 J ug/L NE 10 0.68 1 8260D 3/27/20 17:52 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 17:52 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 17:52 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 17:52 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 17:52 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 17:52 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 17:52 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 17:52 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 17:52 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 17:52 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 16:00 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: BG-SPRING OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-05 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 12:56 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/31/20 11:07 JAB P000574 Arsenic 0.77 J ug/L 10 1.0 0.34 1 6020B 3/31/20 21:36 MMR P000556 Barium 130 ug/L 100 10 3.2 1 6020B 3/31/20 21:36 MMR P000556 Cadmium <0,22 ug/L 1 1.0 0.22 1 6020B 3/31/20 21:36 MMR P000556 Chromium 11 ug/L 10 3.0 0.90 1 6020B 3/31/20 21:36 MMR P000556 Lead 2.6 ug/L 10 1.0 0.44 1 6020B 3/31/20 21:36 MMR P000556 Selenium 1.4 J ug/L 10 5.0 0.98 1 6020B 3/31/20 21:36 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:36 MMR P000556 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 18:17 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:17 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 18:17 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 18:17 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 18:17 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 18:17 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 18:17 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 18:17 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 18:17 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 18:17 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 18:17 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:17 JLB P000545 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 18:17 JLB P000545 Acetone <0.70 CCVL ug/L 100 5.0 0.70 1 8260D 3/27/20 18:17 JLB P000545 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 18:17 JLB P000545 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 3/27/20 18:17 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 18:17 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:17 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 18:17 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 18:17 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 18:17 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 18:17 JLB P000545 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 18:17 JLB P000545 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 3/27/20 18:17 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 18:17 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:17 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 18:17 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: BG-SPRING OLD 20200326 Attn: Alec Macbeth Sample ID: 0030354-05 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 12:56 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 18:17 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 18:17 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 18:17 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:17 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 18:17 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 18:17 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 18:17 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 18:17 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 18:17 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 18:17 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 18:17 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 18:17 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:17 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 18:17 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 18:17 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 18:17 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 18:17 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 18:17 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 18:17 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 18:17 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 18:17 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 18:17 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 18:17 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 97 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 16:25 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-02 OLD - 20200326 Attn: Alec Macbeth Sample ID: 0030354-06 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 12:05 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 30000 ug/L 10000 1100 1 SM2340 C 4/1/20 16:30 BMS POD0017 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/30/20 13:40 JAB P000561 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:43 MMR P000556 Barium 50 ug/L 100 10 3.2 1 6020B 3/31/20 21:43 MMR P000556 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 3/31/20 21:43 MMR P000556 Chromium 2.4 J ug/L 10 3.0 0.90 1 6020B 3/31/20 21:43 MMR P000556 Lead 0.87 J ug/L 10 1.0 0.44 1 6020B 3/31/20 21:43 MMR P000556 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 3/31/20 21:43 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 21:43 MMR P000556 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 18:41 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:41 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 18:41 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 18:41 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 18:41 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 18:41 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 18:41 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 18:41 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 18:41 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 18:41 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 18:41 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:41 JLB P000545 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 18:41 JLB P000545 Acetone 3.3 CC ug/L 100 5.0 0.70 1 8260D 3/27/20 18:41 JLB P000545 VL, J Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 18:41 JLB P000545 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 3/27/20 18:41 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 18:41 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:41 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 18:41 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 18:41 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 18:41 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 18:41 JLB P000545 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 18:41 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-02 OLD - 20200326 Attn: Alec Macbeth Sample ID: 0030354-06 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 12:05 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 3/27/20 18:41 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 18:41 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 18:41 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 18:41 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 18:41 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 18:41 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 18:41 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:41 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 18:41 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 18:41 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 18:41 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 18:41 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 18:41 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 18:41 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 18:41 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 18:41 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 18:41 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 18:41 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 18:41 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 18:41 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 18:41 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 18:41 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 18:41 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 18:41 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 18:41 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 18:41 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 18:41 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 16:50 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-01 OLD - 20200326 Attn: Alec Macbeth Sample ID: 0030354-07 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 11:50 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 38000 ug/L 5000 570 1 SM2340 C 4/1/20 16:30 BMS POD0017 Total Metals Mercury <0.034 ug/L 0.2 0.20 0.034 1 7470A 3/31/20 10:48 JAB P000574 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 22:03 MMR P000556 Barium 66 ug/L 100 10 3.2 1 6020B 3/31/20 22:03 MMR P000556 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 3/31/20 22:03 MMR P000556 Chromium 1.6 J ug/L 10 3.0 0.90 1 6020B 3/31/20 22:03 MMR P000556 Lead 0.84 J ug/L 10 1.0 0.44 1 6020B 3/31/20 22:03 MMR P000556 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 3/31/20 22:03 MMR P000556 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 3/31/20 22:03 MMR P000556 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 19:06 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 19:06 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 19:06 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 19:06 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 19:06 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 19:06 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 19:06 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 19:06 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 19:06 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 19:06 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 19:06 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 19:06 JLB P000545 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 19:06 JLB P000545 Acetone 5.2 CC ug/L 100 5.0 0.70 1 8260D 3/27/20 19:06 JLB P000545 VL Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 19:06 JLB P000545 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 3/27/20 19:06 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 19:06 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 19:06 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 19:06 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 19:06 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 19:06 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 19:06 JLB P000545 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 19:06 JLB P000545 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 3/27/20 19:06 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 32 Laboratory Report A i • .0 04/06/2020 - -ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: SW-01 OLD - 20200326 Attn: Alec Macbeth Sample ID: 0030354-07 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 11:50 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 19:06 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 19:06 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 19:06 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 19:06 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 19:06 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 19:06 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 19:06 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 19:06 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 19:06 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 19:06 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 19:06 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 19:06 JLB P000545 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 19:06 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 19:06 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 19:06 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 19:06 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 19:06 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 19:06 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 19:06 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 19:06 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 19:06 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 19:06 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 19:06 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 19:06 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 19:06 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 19:06 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 99 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 17:15 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 32 Laboratory Report • � 04/06/2020 PA Waynt.� ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: TB-20200326 Attn: Alec Macbeth Sample ID: 0030354-08 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 00:00 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 15:49 JLB P000545 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 15:49 JLB P000545 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 15:49 JLB P000545 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 15:49 JLB P000545 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 3/27/20 15:49 JLB P000545 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 3/27/20 15:49 JLB P000545 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 3/27/20 15:49 JLB P000545 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 3/27/20 15:49 JLB P000545 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 3/27/20 15:49 JLB P000545 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 3/27/20 15:49 JLB P000545 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 15:49 JLB P000545 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 15:49 JLB P000545 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 3/27/20 15:49 JLB P000545 Acetone <0.70 CCVL ug/L 100 5.0 0.70 1 8260D 3/27/20 15:49 JLB P000545 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 3/27/20 15:49 JLB P000545 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 3/27/20 15:49 JLB P000545 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 3/27/20 15:49 JLB P000545 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 15:49 JLB P000545 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 3/27/20 15:49 JLB P000545 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 3/27/20 15:49 JLB P000545 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 3/27/20 15:49 JLB P000545 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 3/27/20 15:49 JLB P000545 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 3/27/20 15:49 JLB P000545 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 3/27/20 15:49 JLB P000545 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 3/27/20 15:49 JLB P000545 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 3/27/20 15:49 JLB P000545 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 3/27/20 15:49 JLB P000545 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 3/27/20 15:49 JLB P000545 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 3/27/20 15:49 JLB P000545 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 3/27/20 15:49 JLB P000545 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 15:49 JLB P000545 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 3/27/20 15:49 JLB P000545 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 3/27/20 15:49 JLB P000545 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 3/27/20 15:49 JLB P000545 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 3/27/20 15:49 JLB P000545 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 3/27/20 15:49 JLB P000545 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 32 . Laboratory Report • � Waynt.� 04/06/2020 poi ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: TB-20200326 Attn: Alec Macbeth Sample ID: 0030354-08 231 Haywood Street Work Order: 0030354 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/26/20 00:00 Time Submitted: 03/27/20 08:35 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 3/27/20 15:49 JLB P000545 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 3/27/20 15:49 JLB P000545 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 3/27/20 15:49 JLB P000545 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 3/27/20 15:49 JLB P000545 Tetrahydrofuran <0.68 ug/L NE 10 0.68 1 8260D 3/27/20 15:49 JLB P000545 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 3/27/20 15:49 JLB P000545 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 3/27/20 15:49 JLB P000545 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 3/27/20 15:49 JLB P000545 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 3/27/20 15:49 JLB P000545 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 3/27/20 15:49 JLB P000545 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 3/27/20 15:49 JLB P000545 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 3/27/20 15:49 JLB P000545 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 3/27/20 15:49 JLB P000545 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 3/27/20 15:49 JLB P000545 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 3/27/20 14:19 TBL P000537 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 32 (2) Way po Int ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000545 - 5030B Blank (P000545-BLK1) Prepared &Analyzed: 03/27/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone 0.700 5.0 ug/L J Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 2.0 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 2.0 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 2.0 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 32 • 0 Waypoint ANALYTICAL Level II QC Report 4/6/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0030354 Attn: Alec Macbeth Time Submitted: 3/27/2020 8:35:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000545 - 5030B Blank (P000545-BLK1) Prepared & Analyzed: 03/27/20 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 50.9 ug/L 50.00 102 80-124 Surrogate: Dibromofluoromethane 51.0 ug/L 50.00 102 75-129 Surrogate: Toluene-d8 49.2 ug/L 50.00 98 77-123 LCS (P000545-BS1) Prepared &Analyzed: 03/27/20 1,1,1,2-Tetrachloroethane 17.4 0.50 ug/L 20.00 87 79-134 1,1,1-Trichloroethane 17.0 0.50 ug/L 20.00 85 75-136 1,1,2,2-Tetrachloroethane 17.9 0.50 ug/L 20.00 90 62-127 1,1,2-Trichloroethane 17.9 0.50 ug/L 20.00 89 70-140 1,1-Dichloroethane 17.3 0.50 ug/L 20.00 87 78-130 1,1-Dichloroethylene 16.8 0.50 ug/L 20.00 84 70-154 1,2,3-Trichloropropane 17.3 1.0 ug/L 20.00 87 71-127 1,2-Dibromo-3-chloropropane 17.6 2.0 ug/L 20.00 88 63-134 1,2-Dibromoethane 16.8 0.50 ug/L 20.00 84 77-135 1,2-Dichlorobenzene 19.0 0.50 ug/L 20.00 95 78-128 1,2-Dichloroethane 16.5 0.50 ug/L 20.00 82 68-131 1,2-Dichloropropane 17.5 0.50 ug/L 20.00 87 77-130 1,4-Dichlorobenzene 18.2 0.50 ug/L 20.00 91 75-126 Acetone 28.9 5.0 ug/L 40.00 72 40-166 Acrylonitrile 37.8 20 ug/L 40.00 94 81-127 Benzene 17.6 0.50 ug/L 20.00 88 77-128 Bromochloromethane 18.2 2.0 ug/L 20.00 91 78-135 Bromodichloromethane 17.6 0.50 ug/L 20.00 88 76-138 Bromoform 17.5 1.0 ug/L 20.00 88 71-135 Bromomethane 21.9 1.0 ug/L 20.00 109 41-168 Carbon disulfide 17.1 5.0 ug/L 20.00 85 59-135 Carbon Tetrachloride 16.4 2.0 ug/L 20.00 82 72-142 Chlorobenzene 17.6 0.50 ug/L 20.00 88 78-119 Chloroethane 21.1 0.50 ug/L 20.00 106 57-142 Chloroform 17.4 0.50 ug/L 20.00 87 77-130 Chloromethane 18.3 0.50 ug/L 20.00 91 47-145 cis-1,2-Dichloroethylene 17.1 0.50 ug/L 20.00 86 76-141 cis-1,3-Dichloropropylene 17.2 0.50 ug/L 20.00 86 65-140 Dibromochloromethane 16.6 0.50 ug/L 20.00 83 75-134 Dibromomethane 17.2 2.0 ug/L 20.00 86 76-138 Ethylbenzene 17.1 0.50 ug/L 20.00 86 80-127 m,p-Xylenes 35.0 1.0 ug/L 40.00 87 77-133 Methyl Butyl Ketone (2-Hexanone) 16.8 5.0 ug/L 20.00 84 64-137 Methyl Ethyl Ketone (2-Butanone) 17.2 5.0 ug/L 20.00 86 71-134 Methyl Iodide 17.0 5.0 ug/L 20.00 85 70-130 Methyl Isobutyl Ketone 16.9 5.0 ug/L 20.00 84 69-134 Methylene Chloride 15.7 1.0 ug/L 20.00 79 73-131 o-Xylene 17.5 0.50 ug/L 20.00 87 78-128 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 32 • 0 Waypoint ANALYTICAL Level II QC Report 4/6/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0030354 Attn: Alec Macbeth Time Submitted: 3/27/2020 8:35:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000545 - 5030B LCS (P000545-BS1) Prepared &Analyzed: 03/27/20 Styrene 17.5 0.50 ug/L 20.00 88 78-129 Tetrachloroethylene 17.5 0.50 ug/L 20.00 88 80-129 Tetrahydrofuran 17.1 10 ug/L 20.00 85 70-130 Toluene 17.5 0.50 ug/L 20.00 87 76-131 trans-1,2-Dichloroethylene 16.9 0.50 ug/L 20.00 85 76-135 trans-1,3-Dichloropropylene 17.2 0.50 ug/L 20.00 86 67-140 trans-1,4-Dichloro-2-butene 14.2 10 ug/L 20.00 71 70-130 Trichloroethylene 17.6 0.50 ug/L 20.00 88 77-133 Trichlorofluoromethane 20.1 0.50 ug/L 20.00 101 62-148 Vinyl acetate 19.5 2.0 ug/L 20.00 97 34-167 Vinyl chloride 19.3 0.50 ug/L 20.00 96 57-141 Xylenes, total 52.4 1.5 ug/L 60.00 87 77-133 Surrogate:4-Bromofluorobenzene 50.5 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 50.5 ug/L 50.00 101 75-129 Surrogate: Toluene-d8 49.3 ug/L 50.00 99 77-123 Matrix Spike (P000545-MS1) Source: 0030354-01 Prepared & Analyzed: 03/27/20 1,1,1,2-Tetrachloroethane 170 5.0 ug/L 200.0 BRL 85 78-134 1,1,1-Trichloroethane 169 5.0 ug/L 200.0 BRL 84 67-145 1,1,2,2-Tetrachloroethane 174 5.0 ug/L 200.0 BRL 87 68-123 1,1,2-Trichloroethane 170 5.0 ug/L 200.0 BRL 85 75-134 1,1-Dichloroethane 171 5.0 ug/L 200.0 BRL 86 75-134 1,1-Dichloroethylene 166 5.0 ug/L 200.0 BRL 83 65-162 1,2,3-Trichloropropane 168 10 ug/L 200.0 BRL 84 73-122 1,2-Dibromo-3-chloropropane 176 20 ug/L 200.0 BRL 88 64-133 1,2-Dibromoethane 164 5.0 ug/L 200.0 BRL 82 80-129 1,2-Dichlorobenzene 189 5.0 ug/L 200.0 BRL 95 80-125 1,2-Dichloroethane 162 5.0 ug/L 200.0 BRL 81 69-129 1,2-Dichloropropane 171 5.0 ug/L 200.0 BRL 85 75-131 1,4-Dichlorobenzene 181 5.0 ug/L 200.0 BRL 90 76-124 Acetone 262 50 ug/L 400.0 BRL 66 40-162 Acrylonitrile 395 200 ug/L 400.0 BRL 99 78-129 Benzene 174 5.0 ug/L 200.0 BRL 87 73-131 Bromochloromethane 180 20 ug/L 200.0 BRL 90 78-135 Bromodichloromethane 172 5.0 ug/L 200.0 BRL 86 74-138 Bromoform 160 10 ug/L 200.0 BRL 80 72-130 Bromomethane 58.5 10 ug/L 200.0 BRL 29 41-173 M Carbon disulfide 173 50 ug/L 200.0 BRL 87 59-138 Carbon Tetrachloride 164 20 ug/L 200.0 BRL 82 66-149 Chlorobenzene 174 5.0 ug/L 200.0 BRL 87 76-119 Chloroethane 241 5.0 ug/L 200.0 BRL 120 52-153 Chloroform 172 5.0 ug/L 200.0 BRL 86 74-136 Chloromethane 179 5.0 ug/L 200.0 BRL 89 39-155 cis-1,2-Dichloroethylene 169 5.0 ug/L 200.0 BRL 85 74-144 cis-1,3-Dichloropropylene 166 5.0 ug/L 200.0 BRL 83 64-132 Dibromochloromethane 166 5.0 ug/L 200.0 BRL 83 77-131 Dibromomethane 168 20 ug/L 200.0 BRL 84 76-136 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 32 • 0 Waypoint ANALYTICAL Level II QC Report 4/6/20 Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0030354 Attn: Alec Macbeth Time Submitted: 3/27/2020 8:35:OOAM 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000545 - 5030B Matrix Spike (P000545-MS1) Ethylbenzene m,p-Xylenes Methyl Butyl Ketone (2-Hexanone) Methyl Ethyl Ketone (2-Butanone) Methyl Iodide Methyl Isobutyl Ketone Methylene Chloride o-Xylene Styrene Tetrachloroethylene Tetrahydrofuran Toluene trans-1,2-Dichloroethylene trans-1,3-Dichloropropylene trans-1,4-Dichloro-2-butene Trichloroethylene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylenes, total Surrogate: 4-Bromofluorobenzene Surrogate: Dibromofluoromethane Surrogate: Toluene-d8 Matrix Spike Dup (P000545-MSD1) 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethylene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon Tetrachloride Source:0030354-01 168 5.0 ug/L 344 10 ug/L 157 50 ug/L 166 50 ug/L 93.4 50 ug/L 161 50 ug/L 155 10 ug/L 171 5.0 ug/L 167 5.0 ug/L 173 5.0 ug/L 156 100 ug/L 172 5.0 ug/L 171 5.0 ug/L 161 5.0 ug/L 108 100 ug/L 175 5.0 ug/L 212 5.0 ug/L 198 20 ug/L 192 5.0 ug/L 515 15 ug/L 51.4 ug/L 51.3 ug/L 49.7 ug/L Source:0030354-01 166 5.0 ug/L 165 5.0 ug/L 168 5.0 ug/L 172 5.0 ug/L 165 5.0 ug/L 161 5.0 ug/L 163 10 ug/L 164 20 ug/L 162 5.0 ug/L 183 5.0 ug/L 159 5.0 ug/L 167 5.0 ug/L 177 5.0 ug/L 260 50 ug/L 389 200 ug/L 170 5.0 ug/L 176 20 ug/L 166 5.0 ug/L 160 10 ug/L 80.4 10 ug/L 165 50 ug/L 162 20 ug/L Prepared & Analyzed: 03/27/20 200.0 BRL 84 400.0 BRL 86 200.0 BRL 79 200.0 BRL 83 200.0 BRL 47 200.0 BRL 80 200.0 BRL 78 200.0 BRL 85 200.0 BRL 84 200.0 BRL 86 200.0 BRL 78 200.0 BRL 86 200.0 BRL 86 200.0 BRL 81 200.0 BRL 54 200.0 BRL 88 200.0 BRL 106 200.0 BRL 99 200.0 BRL 96 600.0 BRL 86 50.00 103 50.00 103 50.00 99 Prepared & Analyzed: 03/27/20 200.0 BRL 83 200.0 BRL 83 200.0 BRL 84 200.0 BRL 86 200.0 BRL 83 200.0 BRL 81 200.0 BRL 82 200.0 BRL 82 200.0 BRL 81 200.0 BRL 92 200.0 BRL 80 200.0 BRL 83 200.0 BRL 88 400.0 BRL 65 400.0 BRL 97 200.0 BRL 85 200.0 BRL 88 200.0 BRL 83 200.0 BRL 80 200.0 BRL 40 200.0 BRL 83 200.0 BRL 81 78-130 66-144 65-130 65-137 70-130 64-137 71-134 75-131 77-128 76-130 70-130 72-135 73-141 64-137 70-130 72-133 61-152 80-154 54-146 66-144 80-124 75-129 77-123 78-134 3 19 67-145 2 18 68-123 4 19 75-134 1 18 75-134 3 18 65-162 3 20 73-122 3 18 64-133 7 25 80-129 1 19 80-125 3 16 69-129 2 17 75-131 2 17 76-124 2 17 40-162 1 23 78-129 2 20 73-131 2 17 78-135 2 17 74-138 4 19 72-130 0.2 22 41-173 32 33 59-138 5 27 66-149 1 23 M M M This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 32 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000545 - 5030B Matrix Spike Dup (P000545-MSD1) Source: 0030354-01 Prepared & Analyzed: 03/27/20 Chlorobenzene 167 5.0 ug/L 200.0 BRL 84 76-119 4 20 Chloroethane 219 5.0 ug/L 200.0 BRL 110 52-153 9 24 Chloroform 168 5.0 ug/L 200.0 BRL 84 74-136 2 19 Chloromethane 171 5.0 ug/L 200.0 BRL 86 39-155 4 20 cis-1,2-Dichloroethylene 167 5.0 ug/L 200.0 BRL 83 74-144 1 17 cis-1,3-Dichloropropylene 163 5.0 ug/L 200.0 BRL 82 64-132 2 18 Dibromochloromethane 162 5.0 ug/L 200.0 BRL 81 77-131 2 21 Dibromomethane 167 20 ug/L 200.0 BRL 84 76-136 0.5 18 Ethylbenzene 162 5.0 ug/L 200.0 BRL 81 78-130 4 18 m,p-Xylenes 332 10 ug/L 400.0 BRL 83 66-144 4 19 Methyl Butyl Ketone (2-Hexanone) 157 50 ug/L 200.0 BRL 78 65-130 0.1 23 Methyl Ethyl Ketone (2-Butanone) 162 50 ug/L 200.0 BRL 81 65-137 3 23 Methyl Iodide 115 50 ug/L 200.0 BRL 57 70-130 20 20 M Methyl Isobutyl Ketone 159 50 ug/L 200.0 BRL 79 64-137 1 24 Methylene Chloride 153 10 ug/L 200.0 BRL 77 71-134 1 17 o-Xylene 167 5.0 ug/L 200.0 BRL 83 75-131 2 20 Styrene 165 5.0 ug/L 200.0 BRL 82 77-128 2 17 Tetrachloroethylene 164 5.0 ug/L 200.0 BRL 82 76-130 5 20 Tetrahydrofuran 159 100 ug/L 200.0 BRL 79 70-130 2 20 Toluene 168 5.0 ug/L 200.0 BRL 84 72-135 3 18 trans-1,2-Dichloroethylene 165 5.0 ug/L 200.0 BRL 82 73-141 4 18 trans-1,3-Dichloropropylene 164 5.0 ug/L 200.0 BRL 82 64-137 2 21 trans-1,4-Dichloro-2-butene 110 100 ug/L 200.0 BRL 55 70-130 2 20 M Trichloroethylene 171 5.0 ug/L 200.0 BRL 86 72-133 2 17 Trichlorofluoromethane 200 5.0 ug/L 200.0 BRL 100 61-152 6 27 Vinyl acetate 194 20 ug/L 200.0 BRL 97 80-154 2 18 Vinyl chloride 188 5.0 ug/L 200.0 BRL 94 54-146 2 25 Xylenes, total 499 15 ug/L 600.0 BRL 83 66-144 3 20 Surrogate:4-Bromofluorobenzene 50.6 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 50.9 ug/L 50.00 102 75-129 Surrogate: Toluene-d8 49.3 ug/L 50.00 99 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 32 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000537 - 5030B Blank (P000537-BLK1) Prepared & Analyzed: 03/27/20 1,4-Dioxane BRL 2.0 ug/L LCS (P000537-BS1) Prepared &Analyzed: 03/27/20 1,4-Dioxane 49.3 2.0 ug/L 50.00 99 55-145 Matrix Spike (P000537-MS1) Source: 0030354-01 Prepared & Analyzed: 03/27/20 1,4-Dioxane 48.7 2.0 ug/L 50.00 2.58 92 55-145 Matrix Spike Dup (P000537-MSD1) Source: 0030354-01 Prepared & Analyzed: 03/27/20 1,4-Dioxane 49.8 2.0 ug/L 50.00 2.58 94 55-145 2 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 32 Level II QC Report 0int 4/6/20 Waypo ANALYTICAL Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Work Order: 0030354 Attn: Alec Macbeth Time Submitted: 3/27/2020 8:35:OOAM 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000556 - 3005A Blank (P000556-BLK1) Prepared: 03/30/20 Analyzed: 03/31/20 Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 3.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L LCS (P000556-BS1) Prepared: 03/30/20 Analyzed: 03/31/20 Arsenic 101 1.0 ug/L 100.0 101 80-120 Barium 96.8 10 ug/L 100.0 97 80-120 Cadmium 100 1.0 ug/L 100.0 100 80-120 Chromium 99.4 3.0 ug/L 100.0 99 80-120 Lead 99.6 1.0 ug/L 100.0 100 80-120 Selenium 108 5.0 ug/L 100.0 108 80-120 Silver 101 1.0 ug/L 100.0 101 80-120 Matrix Spike (P000556-MS1) Source: 0030354-02 Prepared: 03/30/20 Analyzed: 03/31/20 Arsenic 102 1.0 ug/L 100.0 BRL 102 75-125 Barium 150 10 ug/L 100.0 57.1 93 75-125 Cadmium 102 1.0 ug/L 100.0 BRL 102 75-125 Chromium 101 3.0 ug/L 100.0 BRL 101 75-125 Lead 99.7 1.0 ug/L 100.0 BRL 100 75-125 Selenium 110 5.0 ug/L 100.0 BRL 110 75-125 Silver 101 1.0 ug/L 100.0 BRL 101 75-125 Matrix Spike Dup (P000556-MSD1) Source: 0030354-02 Prepared: 03/30/20 Analyzed: 03/31/20 Arsenic 101 1.0 ug/L 100.0 BRL 101 75-125 0.7 20 Barium 156 10 ug/L 100.0 57.1 99 75-125 4 20 Cadmium 101 1.0 ug/L 100.0 BRL 101 75-125 0.7 20 Chromium 99.1 3.0 ug/L 100.0 BRL 99 75-125 2 20 Lead 99.8 1.0 ug/L 100.0 BRL 100 75-125 0.1 20 Selenium 105 5.0 ug/L 100.0 BRL 105 75-125 5 20 Silver 101 1.0 ug/L 100.0 BRL 101 75-125 0.6 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 32 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Madison Closed Landfill Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000556 - 3005A Post Spike (P000556-PS1) Source: 0030354-02 Prepared: 03/30/20 Analyzed: 03/31/20 Arsenic 98.1 ug/L 100.0 0.0530 98 80-120 Barium 158 ug/L 100.0 57.1 101 80-120 Cadmium 106 ug/L 100.0 0.0870 106 80-120 Chromium 96.4 ug/L 100.0 0.159 96 80-120 Lead 101 ug/L 100.0 0.323 101 80-120 Selenium 107 ug/L 100.0 0.231 106 80-120 Silver 102 ug/L 100.0 0.0100 102 80-120 Batch P000561 - 7470A Blank (P000561-BLK1) Prepared &Analyzed: 03/30/20 Mercury BRL 0.20 ug/L LCS (P000561-BS1) Prepared &Analyzed: 03/30/20 Mercury 9.87 0.20 ug/L 9.375 105 80-120 Matrix Spike (P000561-MS1) Source: 0030354-06 Prepared & Analyzed: 03/30/20 Mercury 9.92 0.20 ug/L 9.375 BRL 106 80-120 Matrix Spike Dup (P000561-MSD1) Source: 0030354-06 Prepared & Analyzed: 03/30/20 Mercury 9.33 0.20 ug/L 9.375 BRL 99 80-120 6 20 Batch P000574 - 7470A Blank (P000574-BLK1) Prepared &Analyzed: 03/31/20 Mercury BRL 0.20 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 32 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Madison Closed Landfill Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000574 - 7470A LCS (P000574-BSI) Prepared &Analyzed: 03/31/20 Mercury 9.13 0.20 ug/L 9.375 97 80-120 Matrix Spike (P000574-MS1) Source: 0030354-07 Prepared &Analyzed: 03/31/20 Mercury 9.41 0.20 ug/L 9.375 BRL 100 80-120 Matrix Spike Dup (P000574-MSD1) Source: 0030354-07 Prepared & Analyzed: 03/31/20 Mercury 9.48 0.20 ug/L 9.375 BRL 101 80-120 0.8 20 Post Spike (P000574-PS1) Source: 0030354-07 Prepared &Analyzed: 03/31/20 Mercury 4.89 ug/L 5.000 0.0126 97 85-115 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 32 1 0 Waypoint ANALYTICAL Anchor QEA of North Carolina, PLLC Attn: Alec Macbeth 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Project: Madison Closed Landfill Level II QC Report 4/6/20 Work Order: 0030354 Time Submitted: 3/27/2020 8:35:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POD0017 - NO PREP Blank (POD0017-BLK1) Prepared &Analyzed: 04/01/20 Hardness BRL 5000 ug/L LCS (POD0017-BS1) Prepared &Analyzed: 04/01/20 Hardness 50500 5000 ug/L 50000 101 90-110 Duplicate (POD0017-DUP1) Source: 0030354-07 Prepared &Analyzed: 04/01/20 Hardness 38500 5000 ug/L 38000 1 200 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 32 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 0030354-01 P000556 50 mL 50 mL 03/30/20 7:46 0030354-02 P000556 50 mL 50 mL 03/30/20 7:46 0030354-03 P000556 50 mL 50 mL 03/30/20 7:46 0030354-04 P000556 50 mL 50 mL 03/30/20 7:46 0030354-05 P000556 50 mL 50 mL 03/30/20 7:46 0030354-06 P000556 50 mL 50 mL 03/30/20 7:46 0030354-07 P000556 50 mL 50 mL 03/30/20 7:46 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 0030354-01 P000561 20 mL 30 mL 03/30/20 9:01 0030354-02 P000561 20 mL 30 mL 03/30/20 9:01 0030354-03 P000574 20 mL 30 mL 03/31/20 6:25 0030354-04 P000574 20 mL 30 mL 03/31/20 6:25 0030354-05 P000574 20 mL 30 mL 03/31/20 6:25 0030354-06 P000561 20 mL 30 mL 03/30/20 9:01 0030354-07 P000574 20 mL 30 mL 03/31/20 6:25 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0030354-01 P000545 10 mL 10 mL 03/27/20 10:00 0030354-02 P000545 10 mL 10 mL 03/27/20 10:00 0030354-03 P000545 10 mL 10 mL 03/27/20 10:00 0030354-04 P000545 10 mL 10 mL 03/27/20 10:00 0030354-05 P000545 10 mL 10 mL 03/27/20 10:00 0030354-06 P000545 10 mL 10 mL 03/27/20 10:00 0030354-07 P000545 10 mL 10 mL 03/27/20 10:00 0030354-08 P000545 10 mL 10 mL 03/27/20 10:00 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 0030354-01 P000537 5 mL 5 mL 03/27/20 10:05 0030354-02 P000537 5 mL 5 mL 03/27/20 10:05 0030354-03 P000537 5 mL 5 mL 03/27/20 10:05 0030354-04 P000537 5 mL 5 mL 03/27/20 10:05 0030354-05 P000537 5 mL 5 mL 03/27/20 10:05 0030354-06 P000537 5 mL 5 mL 03/27/20 10:05 0030354-07 P000537 5 mL 5 mL 03/27/20 10:05 0030354-08 P000537 5 mL 5 mL 03/27/20 10:05 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. 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