NCD003162542_Badin Business Park_Corrective Action_20200413

Badin Business Park LLC c/o Alcoa Corporation 201 Isabella Street Suite 500 Pittsburgh, PA 15212-5858 USA Tel: [phone]

April 13, 2020
Robert C. McDaniel
Facility Management Branch Hazardous Waste Section North Carolina Department of Environmental Quality 217 West Jones Street
Raleigh, North Carolina 27603
Re: Data Summary - Little Mountain Creek Quarterly Surface Water Sampling Events Badin Business Park (f/k/a Alcoa - Badin Works) Badin, North Carolina
EPA ID: NCD 003 162 542
Dear Mr. McDaniel: This Data Summary is being provided to the North Carolina Department of Environmental Quality
(NCDEC) as per the April 3, 2018 Revised Investigative Work Plan for the Phase 4 and 5
Corrective Measures Study, Alcoa/Badin Landfill, and Former Ball Field (Work Plan) for the Badin Business Park LLC site, formerly known as the Alcoa Badin Works facility. Specifically, this document presents a summary of analytical results from four consecutive quarterly sampling events in Little Mountain Creek per the objective to address the instream monitoring study
requirements of the September 29, 2017 Final National Pollutant Discharge Elimination System
(NPDES) Renewal Permit, Condition A (8). Surface water samples were collected from five locations within Little Mountain Creek; sample locations are presented on Figure 1. The first sampling event was conducted in July 2018 in
conjunction with a comprehensive site investigation. Analytical results were reported in the
December 5, 2018, Investigative Report for the Little Mountain Creek Area. Subsequent sampling events were performed in October 2018, January 2019, and April 2019. Constituents that were analyzed on a consistent basis during the sampling program included:
• pH and Hardness;
• Total Arsenic and Total Lead;
• Total Fluoride; and
• Total Cyanide. Analytical results, methods, comparative standard criteria, sample locations, and collection date/time for each quarterly event are listed in Tables 1 through 4. Laboratory reports and
completed chain-of-custody (COC) forms for the initial sampling event were provided in the
previously referenced December 5, 2018 report; analytical reports and COC forms for the second, third and fourth events are included in Appendix A. Values for pH ranged from 6.8 to 7.81 and hardness ranged from 15.4 to 39.2 milligrams per liter,
with no exceedences of the 15A NCAC 2B Standards.
Robert C. McDaniel Little Mountain Creek Quarterly Surface Water Sampling Events
April 13, 2020 Arsenic analytical results were not reported at detectable levels above its respective method detection limit (MDL) for any of the samples. Lead analytical results were not reported at detectable at levels above its respective MDL for 23 of the 24 samples; one sample result (ABL-
SW008-F005) was reported as an estimated value that was below the hardness-dependent 15A
NCAC 2B Standard, however lead was not detected at a concentration above its MDL for the duplicate sample (ABL-SW008-D005) at this location. Total fluoride results for each of the 21 samples were not reported at quantifiable levels and were
thus estimated at concentrations between the laboratory’s reporting limit (RL) and the MDL; all
results were below the 15A NCAC 2B Standard. Total cyanide results for 22 of the 24 samples were not reported at estimated or quantifiable levels above its respective MDL. For the other two samples (ABL-SW010-F006, Quarter 2 and
ABL-SW009-F008, Quarter 4), cyanide concentrations were estimated at 5.5 micrograms per liter
(ug/l), and 4 ug/l, respectively. Furthermore, regarding cyanide analysis, the United States Environmental Protection Agency (EPA) has recently promulgated ASTM D7511 method as an approved method codified in 40 CFR
Part 136.3, Table 1b – List of Approved Inorganic Test Procedures, for the analysis of cyanide in
surface waters under the Clean Water Act. Based on extensive data acquisition at various locations over multiple years, both EPA and ASTM have concluded that distillation/colorimetric methods, such as EPA 335.4 or EPA 9012B, are susceptible to interferences primarily due to the presence of sulfides, thiosulfate and thiocyanide. Such interferences often lead to false positives or positive
bias in the sample as compared to the ligand-exchange/amperometry based methods, such as
ASTM D7511. Those false positive interferences are most likely magnified at estimated or quantified values closer to MDLs. Many analytical laboratories are now certified to perform ASTM D7511 as an approved method for surface water compliance monitoring; we understand that one or more laboratories are obtaining certification for this method in North Carolina.

Should you have any questions or comments, please contact Jason Mibroda of Alcoa at [phone] at your convenience. Sincerely,
Ronald M. Morosky Director, Corporate Remediation
Attachments Figure 1; Tables 1, 2, 3 and 4; Appendix A cc: Qais Banihani, NCDEQ Julie Grzyb, NCDEQ Robyn Gross, Alcoa Jason Mibroda, Alcoa
Michael W. Worden, CEC, Inc.
Robert C. McDaniel Little Mountain Creek Quarterly Surface Water Sampling Events
April 13, 2020

Figure

Robert C. McDaniel Little Mountain Creek Quarterly Surface Water Sampling Events
April 13, 2020

Tables

Table 1
Little Mountain Creek Surface Water Sample Analytical Results - Quarter 1 (July 2018)
Alcoa/Badin Municipal Landfill
Badin Business Park Facility
Badin, North Carolina
Sample ID Method CAS Units
15A NCAC 2B
Surface Water
StandardABL-SW011-F005 ABL-SW012-F005ABL-SW009-F005 ABL-SW010-F005ABL-SW008-D005ABL-SW008-F005
Location
Date
Time
pH SU 6.0-9.0
Fluoride EPA 300.0 16984-48-8 mg/l 1.8
Cyanide EPA 9012B 57-12-5 mg/l ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 0.005
Arsenic EPA 200.7 7440-38-2 mg/l ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 0.34
Hardness, Total (SM 2340B) EPA 200.7 mg/l 100
Lead EPA 200.7 7439-92-1 mg/l ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 0.0209
Table adapted from Table 2-3 of December 5, 2018 Investigative Report for the Little Mountain Creek Area
Sample times inadvertently left off laboratory chain of custody. Sample times as recorded on bottles were documented in field book.
ND - The analyte was not detected above laboratory detection limits. Subscript indicates compound-specific MDL in mg/kg.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
NE - Not established.
The 15A NCAC 2B standard for acute lead is calculated as hardness dependent using the a hardness value of 36 mg/l.
9:25 9:558:25 8:50
Downstream from
NC740 LMC near Western SCA
LMC Upstream of the
ABL
7/12/2018 7/12/2018 7/12/2018
LMC at Eastern SCA
Ditch
7/12/2018
LMC at Middle SCA
Ditch
7/12/2018
Downstream from
NC740
7/12/2018
37.8
0.0026 J
0.088 J 0.087 J
38.5
7:30
7.47 7.39
7:10
7.42 7.55 7.31 7.04
0.078 J 0.074 J 0.078 J 0.082 J
36.6 36 37.3 39.2
Table 2
Little Mountain Creek Surface Water Sample Analytical Results - Quarter 2 (October 2018)
Alcoa/Badin Municipal Landfill
Badin Business Park Facility
Badin, North Carolina
Sample ID Method CAS Units
15A NCAC 2B
Surface Water
StandardABL-SW008-D006 ABL-SW009-F006 ABL-SW010-F006 ABL-SW011-F006 ABL-SW012-F006ABL-SW008-F006
Location
Date
Time
pH SU 6.0-9.0
P EPA 300.0 16984-48-8 mg/l 1.8
Cyanide EPA 9012B 57-12-5 mg/l ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 0.005
Arsenic EPA 200.7 7440-38-2 mg/l ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 0.34
Hardness, Total (SM 2340B) EPA 200.7 mg/l 100
Lead EPA 200.7 7439-92-1 mg/l ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 0.01091
ND - The analyte was not detected above laboratory detection limits. Subscript indicates compound-specific MDL in mg/kg.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
The 15A NCAC 2B standard for acute lead is calculated as hardness dependent using the a hardness value of 20.2 mg/l.
10/15/201810/15/2018
6.8
15:15 15:20 11:45 11:55 12:05 12:15
6.82 6.82 6.87 6.82 6.84
10/15/2018 10/15/2018
0.0055 J
10/15/2018 10/15/2018
Downstream from
NC740
Downstream from
NC740
LMC at Eastern SCA
Ditch
LMC at Middle SCA
Ditch LMC near Western SCA
LMC Upstream of the
ABL
0.051 J 0.052 J0.064 J 0.058 J 0.057 J 0.067 J
20.9 21.320.220.920.320.5
Table 3
Little Mountain Creek Surface Water Sample Analytical Results - Quarter 3 (January 2019)
Alcoa/Badin Municipal Landfill
Badin Business Park Facility
Badin, North Carolina
Sample ID Method CAS Units
15A NCAC 2B
Surface Water
StandardABL-SW012-F007ABL-SW008-F007 ABL-SW008-D007 ABL-SW009-F007 ABL-SW010-F007 ABL-SW011-F007
Location
Date
Time
pH SU 6.0-9.0
Fluoride EPA 300.0 16984-48-8 mg/l ND 0.05 ND 0.05 ND 0.05 1.8
Cyanide EPA 9012B 57-12-5 mg/l ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 0.005
Arsenic EPA 200.7 7440-38-2 mg/l ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 0.34
Hardness, Total (SM 2340B) EPA 200.7 mg/l 100
Lead EPA 200.7 7439-92-1 mg/l ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 0.01171
ND - The analyte was not detected above laboratory detection limits. Subscript indicates compound-specific MDL in mg/kg.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
The 15A NCAC 2B standard for acute lead is calculated as hardness dependent using the a hardness value of 21.5 mg/l.
1/30/2019 1/30/2019 1/30/2019
Downstream from
NC740
Downstream from
NC740
LMC at Eastern SCA
Ditch
LMC at Middle SCA
Ditch LMC near Western SCA
LMC Upstream of the
ABL
1/30/2019 1/30/2019
7.35 7.81 7.68
14:30
1/30/2019
14:55 15:00 14:15 14:20 14:25
0.063 J 0.081 J 0.051 J
7.58 7.58 7.71
22.622 21.8 21.3 21.5 21.7
Table 4
Little Mountain Creek Surface Water Sample Analytical Results - Quarter 4 (April 2019)
Alcoa/Badin Municipal Landfill
Badin Business Park Facility
Badin, North Carolina
Sample ID Method CAS Units
15A NCAC 2B
Surface Water
StandardABL-SW009-F008 ABL-SW010-F008 ABL-SW011-F008 ABL-SW012-F008ABL-SW008-F008 ABL-SW008-D008
Location
Date
Time
pH SU 6.0-9.0
Fluoride EPA 300.0 16984-48-8 mg/l 1.8
Cyanide EPA 9012B 57-12-5 mg/l ND 0.004 ND 0.004 ND 0.004 ND 0.004 ND 0.004 0.005
Arsenic EPA 200.7 7440-38-2 mg/l ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 ND 0.005 0.34
Hardness, Total (SM 2340B) EPA 200.7 mg/l 100
Lead EPA 200.7 7439-92-1 mg/l ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 ND 0.0025 0.00802
ND - The analyte was not detected above laboratory detection limits. Subscript indicates compound-specific MDL in mg/kg.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
The 15A NCAC 2B standard for acute lead is calculated as hardness dependent using the a hardness value of 15.4 mg/l.
15.4 15.8 16.2 16.2 15.5 16
0.0040 J
0.065 J 0.061 J 0.061 J
4/10/20194/10/2019
0.067 J 0.066 J 0.075 J
7.38
10:50 10:55 12:10 12:20 12:30 12:45
7.02 7.02 7.26 7.28 7.38
4/10/2019 4/10/20194/10/2019 4/10/2019
Downstream from
NC740
Downstream from
NC740
LMC at Eastern SCA
Ditch
LMC at Middle SCA
Ditch LMC near Western SCA
LMC Upstream of the
ABL
Robert C. McDaniel Little Mountain Creek Quarterly Surface Water Sampling Events
April 13, 2020

Appendix A
Laboratory Reports and Chain of Custody Forms
#=CL#
January 29, 2019
LIMS USE: FR - MICHAEL WORDEN
LIMS OBJECT ID: 92403757
92403757
Project:
Pace Project No.:
RE:
Michael W. Worden
Environeering, Inc.
16100 Cairnway
Suite 320
Houston, TX 77084
Little Mountain Creek - SW
Dear Michael Worden:
Enclosed are the analytical results for sample(s) received by the laboratory on October 16, 2018.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
This revision was issued on 1/29/19 to report results to the MDL, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Lab ID Sample ID Matrix Date Collected Date Received
92403757001 ABL-SW008-F006 Water 10/15/18 15:15 10/16/18 15:45
92403757002 ABL-SW008-D006 Water 10/15/18 15:20 10/16/18 15:45
92403757003 ABL-SW009-F006 Water 10/15/18 11:45 10/16/18 15:45
92403757004 ABL-SW010-F006 Water 10/15/18 11:55 10/16/18 15:45
92403757005 ABL-SW011-F006 Water 10/15/18 12:05 10/16/18 15:45
92403757006 ABL-SW012-F006 Water 10/15/18 12:15 10/16/18 15:45
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92403757001 ABL-SW008-F006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
92403757002 ABL-SW008-D006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
92403757003 ABL-SW009-F006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
92403757004 ABL-SW010-F006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
92403757005 ABL-SW011-F006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
92403757006 ABL-SW012-F006 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW008-F006 Lab ID:92403757001 Collected:10/15/18 15:15 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 03:40 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 03:40 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)20900 ug/L 10/19/18 03:4010/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.064J mg/L 10/19/18 08:33 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 10/26/18 11:57 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW008-D006 Lab ID:92403757002 Collected:10/15/18 15:20 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 03:59 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 03:59 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)20500 ug/L 10/19/18 03:5910/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.058J mg/L 10/19/18 08:51 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 10/26/18 11:59 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW009-F006 Lab ID:92403757003 Collected:10/15/18 11:45 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 04:02 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 04:02 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)20300 ug/L 10/19/18 04:0210/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.057J mg/L 10/19/18 09:08 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 10/26/18 12:00 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW010-F006 Lab ID:92403757004 Collected:10/15/18 11:55 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 04:05 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 04:05 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)20900 ug/L 10/19/18 04:0510/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.067J mg/L 10/19/18 09:25 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide 0.0055J mg/L 10/26/18 12:01 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW011-F006 Lab ID:92403757005 Collected:10/15/18 12:05 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 04:08 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 04:08 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)20200 ug/L 10/19/18 04:0810/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.051J mg/L 10/19/18 09:42 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 10/26/18 12:02 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Sample:ABL-SW012-F006 Lab ID:92403757006 Collected:10/15/18 12:15 Received:10/16/18 15:45 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 10/19/18 04:12 7440-38-210/18/18 01:4210.0 5.0 1
Lead ND ug/L 10/19/18 04:12 7439-92-110/18/18 01:425.0 2.5 1
Hardness, Total(SM 2340B)21300 ug/L 10/19/18 04:1210/18/18 01:426626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.052J mg/L 10/19/18 10:00 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 10/26/18 12:03 57-12-510/25/18 10:210.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/29/2019 02:34 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
436836
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2403175
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Matrix:Water
AnalyzedMDL
Arsenic ug/L ND 10.0 10/19/18 03:345.0
Hardness, Total(SM 2340B)ug/L ND 662 10/19/18 03:34662
Lead ug/L ND 5.0 10/19/18 03:342.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2403176LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 463500 93 85-115
Hardness, Total(SM 2340B)ug/L 3310033100 100 85-115
Lead ug/L 469500 94 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2403177MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92403757001
2403178
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 93 70-13093 1 20500ND468465
Hardness, Total(SM 2340B)ug/L 33100 101 70-130101 0 2033100209005420054400
Lead ug/L 500 94 70-13094 1 20500ND472469
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
436945
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2403642
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Matrix:Water
AnalyzedMDL
Fluoride mg/L ND 0.10 10/19/18 01:560.050
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2403643LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.72.5 107 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2403644MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92403671009
2403645
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L R12.5 97 90-110110 12 102.5ND 2.5 2.8
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2403646MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92403673001
2403647
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L M12.5 89 90-11092 3 102.5ND 2.3 2.4
REPORT OF LABORATORY ANALYSIS
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Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
438062
EPA 9012B
EPA 9012B
EPA 9012B Cyanide
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2408483
Associated Lab Samples:92403757001, 92403757002, 92403757003, 92403757004, 92403757005, 92403757006
Matrix:Water
AnalyzedMDL
Cyanide mg/L ND 0.0080 10/26/18 11:510.0040
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2408484LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.0990.1 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2408485MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92403916001
2408486
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 100 75-125104 4 200.1ND 0.10 0.11
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2408487MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92403757001
2408488
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 102 75-12599 3 200.1ND 0.10 0.10
REPORT OF LABORATORY ANALYSIS
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Page 13 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92403757
Little Mountain Creek - SW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92403757001 436836 436882ABL-SW008-F006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757002 436836 436882ABL-SW008-D006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757003 436836 436882ABL-SW009-F006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757004 436836 436882ABL-SW010-F006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757005 436836 436882ABL-SW011-F006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757006 436836 436882ABL-SW012-F006 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92403757001 436945ABL-SW008-F006 EPA 300.0 Rev 2.1 1993
92403757002 436945ABL-SW008-D006 EPA 300.0 Rev 2.1 1993
92403757003 436945ABL-SW009-F006 EPA 300.0 Rev 2.1 1993
92403757004 436945ABL-SW010-F006 EPA 300.0 Rev 2.1 1993
92403757005 436945ABL-SW011-F006 EPA 300.0 Rev 2.1 1993
92403757006 436945ABL-SW012-F006 EPA 300.0 Rev 2.1 1993
92403757001 438062 438395ABL-SW008-F006 EPA 9012B EPA 9012B
92403757002 438062 438395ABL-SW008-D006 EPA 9012B EPA 9012B
92403757003 438062 438395ABL-SW009-F006 EPA 9012B EPA 9012B
92403757004 438062 438395ABL-SW010-F006 EPA 9012B EPA 9012B
92403757005 438062 438395ABL-SW011-F006 EPA 9012B EPA 9012B
92403757006 438062 438395ABL-SW012-F006 EPA 9012B EPA 9012B
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
February 06, 2019
LIMS USE: FR - MICHAEL WORDEN
LIMS OBJECT ID: 92416092
92416092
Project:
Pace Project No.:
RE:
Michael W. Worden
Environeering, Inc.
16100 Cairnway
Suite 320
Houston, TX 77084
Little Mountain Creek (SW)
Dear Michael Worden:
Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Lab ID Sample ID Matrix Date Collected Date Received
92416092001 ABL-SW008-F007 Water 01/30/19 14:55 02/01/19 10:23
92416092002 ABL-SW008-D007 Water 01/30/19 15:00 02/01/19 10:23
92416092003 ABL-SW009-F007 Water 01/30/19 14:15 02/01/19 10:23
92416092004 ABL-SW0010-F007 Water 01/30/19 14:20 02/01/19 10:23
92416092005 ABL-SW0011-F007 Water 01/30/19 14:25 02/01/19 10:23
92416092006 ABL-SW0012-F007 Water 01/30/19 14:30 02/01/19 10:23
REPORT OF LABORATORY ANALYSIS
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Page 3 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92416092001 ABL-SW008-F007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
92416092002 ABL-SW008-D007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
92416092003 ABL-SW009-F007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
92416092004 ABL-SW0010-F007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
92416092005 ABL-SW0011-F007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
92416092006 ABL-SW0012-F007 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
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Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW008-F007 Lab ID:92416092001 Collected:01/30/19 14:55 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 19:27 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 19:27 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)22000 ug/L 02/04/19 19:2702/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.063J mg/L 02/05/19 16:10 16984-48-8 M1,R10.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:12 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW008-D007 Lab ID:92416092002 Collected:01/30/19 15:00 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 19:52 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 19:52 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)21800 ug/L 02/04/19 19:5202/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.081J mg/L 02/05/19 19:07 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:13 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW009-F007 Lab ID:92416092003 Collected:01/30/19 14:15 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 19:55 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 19:55 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)21300 ug/L 02/04/19 19:5502/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.051J mg/L 02/05/19 19:23 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:14 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW0010-F007 Lab ID:92416092004 Collected:01/30/19 14:20 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 19:58 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 19:58 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)21500 ug/L 02/04/19 19:5802/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/05/19 19:39 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:15 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW0011-F007 Lab ID:92416092005 Collected:01/30/19 14:25 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 20:01 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 20:01 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)21700 ug/L 02/04/19 20:0102/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/05/19 19:55 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:19 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 9 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Sample:ABL-SW0012-F007 Lab ID:92416092006 Collected:01/30/19 14:30 Received:02/01/19 10:23 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 02/04/19 20:04 7440-38-202/03/19 08:2310.0 5.0 1
Lead ND ug/L 02/04/19 20:04 7439-92-102/03/19 08:235.0 2.5 1
Hardness, Total(SM 2340B)22600 ug/L 02/04/19 20:0402/03/19 08:236626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride ND mg/L 02/05/19 20:11 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 02/06/19 13:20 57-12-502/04/19 16:270.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456036
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2488590
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Matrix:Water
AnalyzedMDL
Arsenic ug/L ND 10.0 02/04/19 19:205.0
Hardness, Total(SM 2340B)ug/L ND 662 02/04/19 19:20662
Lead ug/L ND 5.0 02/04/19 19:202.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2488591LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 476500 95 85-115
Hardness, Total(SM 2340B)ug/L 3170033100 96 85-115
Lead ug/L 474500 95 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488592MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416092001
2488593
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 98 70-13095 3 20500ND488473
Hardness, Total(SM 2340B)ug/L 33100 98 70-13093 3 2033100220005450052900
Lead ug/L 500 94 70-13092 2 20500ND473462
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488594MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416211002
2488595
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 94 70-13094 0 20500ND470469
Hardness, Total(SM 2340B)ug/L 33100 97 70-13099 1 2033100462007820078900
Lead ug/L 500 93 70-13093 0 20500ND466467
REPORT OF LABORATORY ANALYSIS
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Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456294
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2489642
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Matrix:Water
AnalyzedMDL
Fluoride mg/L ND 0.10 02/05/19 11:220.050
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2489643LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.42.5 94 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2489644MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416255003
2489645
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L M1,R12.5 105 90-110163 36 102.50.62 3.3 4.7
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2489646MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416092001
2489647
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L M1,R12.5 111 90-11094 17 102.50.063J 2.8 2.4
REPORT OF LABORATORY ANALYSIS
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Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
456123
EPA 9012B
EPA 9012B
EPA 9012B Cyanide
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2488856
Associated Lab Samples:92416092001, 92416092002, 92416092003, 92416092004, 92416092005, 92416092006
Matrix:Water
AnalyzedMDL
Cyanide mg/L ND 0.0080 02/06/19 13:000.0040
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2488857LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.100.1 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488858MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416091001
2488859
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 81 75-12599 19 200.1ND 0.084 0.10
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2488860MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92416092004
2488861
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 99 75-12598 0 200.1ND 0.10 0.10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/06/2019 04:36 PM
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Page 13 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92416092
Little Mountain Creek (SW)
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92416092001 456036 456055ABL-SW008-F007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092002 456036 456055ABL-SW008-D007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092003 456036 456055ABL-SW009-F007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092004 456036 456055ABL-SW0010-F007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092005 456036 456055ABL-SW0011-F007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092006 456036 456055ABL-SW0012-F007 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92416092001 456294ABL-SW008-F007 EPA 300.0 Rev 2.1 1993
92416092002 456294ABL-SW008-D007 EPA 300.0 Rev 2.1 1993
92416092003 456294ABL-SW009-F007 EPA 300.0 Rev 2.1 1993
92416092004 456294ABL-SW0010-F007 EPA 300.0 Rev 2.1 1993
92416092005 456294ABL-SW0011-F007 EPA 300.0 Rev 2.1 1993
92416092006 456294ABL-SW0012-F007 EPA 300.0 Rev 2.1 1993
92416092001 456123 456273ABL-SW008-F007 EPA 9012B EPA 9012B
92416092002 456123 456273ABL-SW008-D007 EPA 9012B EPA 9012B
92416092003 456123 456273ABL-SW009-F007 EPA 9012B EPA 9012B
92416092004 456123 456273ABL-SW0010-F007 EPA 9012B EPA 9012B
92416092005 456123 456273ABL-SW0011-F007 EPA 9012B EPA 9012B
92416092006 456123 456273ABL-SW0012-F007 EPA 9012B EPA 9012B
REPORT OF LABORATORY ANALYSIS
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Page 15 of 18
Page 16 of 18
Page 17 of 18
Page 18 of 18
#=CL#
April 23, 2019
LIMS USE: FR - MICHAEL WORDEN
LIMS OBJECT ID: 92424938
92424938
Project:
Pace Project No.:
RE:
Michael W. Worden
Environeering, Inc.
16100 Cairnway
Suite 320
Houston, TX 77084
LITTLE MOUNTAIN CREEK-SW
Dear Michael Worden:
Enclosed are the analytical results for sample(s) received by the laboratory on April 10, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Angela Baioni
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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Page 1 of 20
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 20
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Lab ID Sample ID Matrix Date Collected Date Received
92424938001 ABL-SW008-F008 Water 04/10/19 10:50 04/10/19 16:11
92424938002 ABL-SW008-D008 Water 04/10/19 10:55 04/10/19 16:11
92424938003 ABL-SW009-F008 Water 04/10/19 12:10 04/10/19 16:11
92424938004 ABL-SW010-F008 Water 04/10/19 12:20 04/10/19 16:11
92424938005 ABL-SW011-F008 Water 04/10/19 12:30 04/10/19 16:11
92424938006 ABL-SW012-F008 Water 04/10/19 12:45 04/10/19 16:11
REPORT OF LABORATORY ANALYSIS
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Page 3 of 20
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92424938001 ABL-SW008-F008 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
92424938002 ABL-SW008-D008 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
92424938003 ABL-SW009-F008 EPA 200.7 Rev 4.4 1994 3 PASI-ASH1
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
92424938004 ABL-SW010-F008 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
92424938005 ABL-SW011-F008 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
92424938006 ABL-SW012-F008 EPA 200.7 Rev 4.4 1994 3 PASI-ADS
EPA 300.0 Rev 2.1 1993 1 PASI-ACDC
EPA 9012B 1 PASI-ANAL
REPORT OF LABORATORY ANALYSIS
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Page 4 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW008-F008 Lab ID:92424938001 Collected:04/10/19 10:50 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/21/19 22:52 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/21/19 22:52 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)15400 ug/L 04/21/19 22:5204/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.067J mg/L 04/12/19 04:13 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 04/16/19 15:26 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW008-D008 Lab ID:92424938002 Collected:04/10/19 10:55 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/21/19 22:55 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/21/19 22:55 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)15800 ug/L 04/21/19 22:5504/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.066J mg/L 04/12/19 04:28 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide 0.0041J mg/L 04/16/19 15:28 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW009-F008 Lab ID:92424938003 Collected:04/10/19 12:10 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/19/19 19:10 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/19/19 19:10 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)16200 ug/L 04/19/19 19:1004/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.075J mg/L 04/12/19 04:43 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide 0.0040J mg/L 04/16/19 15:29 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW010-F008 Lab ID:92424938004 Collected:04/10/19 12:20 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/21/19 22:58 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/21/19 22:58 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)16200 ug/L 04/21/19 22:5804/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.065J mg/L 04/11/19 17:24 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 04/16/19 15:30 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW011-F008 Lab ID:92424938005 Collected:04/10/19 12:30 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/21/19 23:01 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/21/19 23:01 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)15500 ug/L 04/21/19 23:0104/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.061J mg/L 04/11/19 18:12 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 04/16/19 15:31 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 9 of 20
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Sample:ABL-SW012-F008 Lab ID:92424938006 Collected:04/10/19 12:45 Received:04/10/19 16:11 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994200.7 MET ICP
Arsenic ND ug/L 04/21/19 23:04 7440-38-204/18/19 15:3010.0 5.0 1
Lead ND ug/L 04/21/19 23:04 7439-92-104/18/19 15:305.0 2.5 1
Hardness, Total(SM 2340B)16000 ug/L 04/21/19 23:0404/18/19 15:306626621
Analytical Method: EPA 300.0 Rev 2.1 1993300.0 IC Anions 28 Days
Fluoride 0.061J mg/L 04/11/19 18:28 16984-48-80.10 0.050 1
Analytical Method: EPA 9012B Preparation Method: EPA 9012B9012B Cyanide, Total
Cyanide ND mg/L 04/16/19 15:32 57-12-504/15/19 16:560.0080 0.0040 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
470228
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Associated Lab Samples:92424938001, 92424938002, 92424938004, 92424938005, 92424938006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2553042
Associated Lab Samples:92424938001, 92424938002, 92424938004, 92424938005, 92424938006
Matrix:Water
AnalyzedMDL
Arsenic ug/L ND 10.0 04/21/19 22:305.0
Hardness, Total(SM 2340B)ug/L ND 662 04/21/19 22:30662
Lead ug/L ND 5.0 04/21/19 22:302.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2553043LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 483500 97 85-115
Hardness, Total(SM 2340B)ug/L 3180033100 96 85-115
Lead ug/L 493500 99 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2553044MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424936001
2553045
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 100 70-130102 2 20500ND502511
Hardness, Total(SM 2340B)ug/L 33100 98 70-13092 2 20331006940010200099700
Lead ug/L 500 94 70-13095 1 20500ND472474
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2553046MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92425515003
2553047
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 104 70-130101 3 20500ND521508
Hardness, Total(SM 2340B)ug/L 33100 100 70-13094 2 2033100586009170089800
Lead ug/L 500 100 70-13097 2 205005.7 504 492
REPORT OF LABORATORY ANALYSIS
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Page 11 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
470229
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Associated Lab Samples:92424938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2553048
Associated Lab Samples:92424938003
Matrix:Water
AnalyzedMDL
Arsenic ug/L ND 10.0 04/19/19 18:255.0
Hardness, Total(SM 2340B)ug/L ND 662 04/19/19 18:25662
Lead ug/L ND 5.0 04/19/19 18:252.5
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2553049LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 448500 90 85-115
Hardness, Total(SM 2340B)ug/L 3230033100 98 85-115
Lead ug/L 468500 94 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2553050MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424696002
2553051
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 96 70-13096 0 20500ND483482
Hardness, Total(SM 2340B)ug/L 33100 99 70-130100 0 2033100204005320053300
Lead ug/L 500 95 70-13095 0 20500ND476476
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2553052MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424943003
2553053
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 96 70-13095 1 20500<10.0 481 475
Hardness, Total(SM 2340B)ug/L 33100 104 70-130104 0 2033100252005960059700
Lead ug/L 500 98 70-13098 0 20500<5.0 490 489
REPORT OF LABORATORY ANALYSIS
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Page 12 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
468703
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92424938001, 92424938002, 92424938003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2545586
Associated Lab Samples:92424938001, 92424938002, 92424938003
Matrix:Water
AnalyzedMDL
Fluoride mg/L ND 0.10 04/11/19 20:270.050
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2545587LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.52.5 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2545588MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424527011
2545589
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 102 90-110104 1 102.5ND 2.6 2.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2545590MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424940005
2545591
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 102 90-110105 2 102.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/23/2019 05:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
468706
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Associated Lab Samples:92424938004, 92424938005, 92424938006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2545596
Associated Lab Samples:92424938004, 92424938005, 92424938006
Matrix:Water
AnalyzedMDL
Fluoride mg/L ND 0.10 04/11/19 16:520.050
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2545597LABORATORY CONTROL SAMPLE:
LCSSpike
Fluoride mg/L 2.32.5 92 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2545598MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424938004
2545599
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Fluoride mg/L 2.5 99 90-11099 0 102.50.065J 2.5 2.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/23/2019 05:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 20
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
469302
EPA 9012B
EPA 9012B
EPA 9012B Cyanide
Associated Lab Samples:92424938001, 92424938002, 92424938003, 92424938004, 92424938005, 92424938006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:2548645
Associated Lab Samples:92424938001, 92424938002, 92424938003, 92424938004, 92424938005, 92424938006
Matrix:Water
AnalyzedMDL
Cyanide mg/L ND 0.0080 04/16/19 15:220.0040
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2548646LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide mg/L 0.110.1 106 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2548647MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92424938001
2548648
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 107 75-125109 1 200.1ND 0.11 0.11
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
2548649MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92425038002
2548650
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide mg/L 0.1 107 75-125103 4 200.1ND 0.11 0.10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/23/2019 05:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 20
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/23/2019 05:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 20
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92424938
LITTLE MOUNTAIN CREEK-SW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92424938001 470228 470311ABL-SW008-F008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938002 470228 470311ABL-SW008-D008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938003 470229 470312ABL-SW009-F008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938004 470228 470311ABL-SW010-F008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938005 470228 470311ABL-SW011-F008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938006 470228 470311ABL-SW012-F008 EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92424938001 468703ABL-SW008-F008 EPA 300.0 Rev 2.1 1993
92424938002 468703ABL-SW008-D008 EPA 300.0 Rev 2.1 1993
92424938003 468703ABL-SW009-F008 EPA 300.0 Rev 2.1 1993
92424938004 468706ABL-SW010-F008 EPA 300.0 Rev 2.1 1993
92424938005 468706ABL-SW011-F008 EPA 300.0 Rev 2.1 1993
92424938006 468706ABL-SW012-F008 EPA 300.0 Rev 2.1 1993
92424938001 469302 469620ABL-SW008-F008 EPA 9012B EPA 9012B
92424938002 469302 469620ABL-SW008-D008 EPA 9012B EPA 9012B
92424938003 469302 469620ABL-SW009-F008 EPA 9012B EPA 9012B
92424938004 469302 469620ABL-SW010-F008 EPA 9012B EPA 9012B
92424938005 469302 469620ABL-SW011-F008 EPA 9012B EPA 9012B
92424938006 469302 469620ABL-SW012-F008 EPA 9012B EPA 9012B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/23/2019 05:53 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 20
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