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HomeMy WebLinkAbout5001_Jackson_WesternCarolinaUniversity_MSWLF_Feb20GW_FID1395637_20200407wood. FEBRUARY 2020 SEMI-ANNUAL WATER QUALITY AND LANDFILL GAS MONITORING REPORT Western Carolina University Closed Municipal Solid Waste Landfill Monteith Gap Road Cullowhee, Jackson County, North Carolina 28723 NCDEQ Permit: 50-01 Prepared For: Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Prepared by: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 April 7, 2020 Wood Project 6252-15-0221 wood. Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, NC 28806 USA April 7, 2020 Mr. Roger Turk Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Subject: February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed Municipal Solid Waste Landfill Cullowhee, Jackson County, North Carolina NCDEQ Permit: 50-01 Wood Project 6252-15-0221 Dear Mr. Turk: T:828-252-8130 www.woodpic.com Wood Environment & Infrastructure Solutions, Inc. (Wood) is pleased to submit this February 2020 Water Quality and Landfill Gas Monitoring Report for Western Carolina University's (WCU's) closed municipal solid waste landfill located in Cullowhee, North Carolina. The scope of work for this monitoring event was described in Wood's Proposal for Environmental Services, dated April 25, 2019. Wood appreciates the opportunity to provide our environmental services to WCU. If you have any questions concerning this report, please contact us at (828) 252-8130, Sincerely, Wood Environment & Infrastructure Solutions, Inc. Rodney M. Clark, L.G. Technical Professional RMC/MEW;rmc Matthew E. Wallace, P.E. Principal Engineer cc: Ms. Jaclynne Drummond — NCDEQ Solid Waste Section, Asheville Regional Office Mr. Lee Hill — NCDEQ Solid Waste Section, Asheville Regional Office North Carolina Corporate Engineering License No. F-1253; Geology No. C-247 0 0 February 2020 Water Quality and Landfill Gas Monitoring Report April 7, 2020 WCU Closed MSWLF Wood Project 6252-15-0221 TABLE OF CONTENTS Page 1. Introduction..................................................................................................................................1 1.1. Site -Specific Information............................................................................................................................1 1.2. Background Information............................................................................................................................1 2. Field Activities..............................................................................................................................3 2.1. Landfill Gas Monitoring..............................................................................................................................3 2.2. Water Quality Monitoring..........................................................................................................................3 3. Results and Discussion................................................................................................................5 3.1. Landfill Gas.......................................................................................................................................................5 3.2. Groundwater and Surface Water............................................................................................................ 5 3.2.1. Appendix I VOCs....................................................................................................................................... 5 3.2.2. 1,4- D i oxa n e................................................................................................................................................. 6 3.2.3. Appendix I Metals....................................................................................................................................6 LIST OF TABLES 1 Landfill Gas Well Construction Details 2 Well Construction and Water Level Data — February 2020 3 Groundwater Quality Data — February 2020 4 Groundwater Analytical Results — February 2020 5 Surface Water Analytical Results — February 2020 6 Historical Groundwater Analytical Results 7 Historical Surface Water Analytical Results LIST OF FIGURES 1 Topographic Site Map 2 Site Map with Monitoring Locations APPENDICES A Landfill Gas Monitoring Data Form B Groundwater Sampling Logs C NCDEQ Environmental Monitoring Reporting Form D Laboratory Analytical Report February 2020 Water Quality and Landfill Gas Monitoring Report April 7, 2020 WCU Closed MSWLF Wood Project 6252-15-0221 1. INTRODUCTION This report documents field activities and results from the February 2020 water quality and landfill gas monitoring event at Western Carolina University's (WCU's) closed Municipal Solid Waste Landfill (MSWLF) located in Cullowhee, North Carolina (Site) as shown on Figure 1. 1.1. Site -Specific Information Site Name: WCU Closed MSWLF Facility Permit Number: Facility Latitude/Longitude Site Location Map: Facility Address: Facility Owner: 50-01 N 350 19' 30" / W 830 10' 55" Figure 1 Monteith Gap Road Cullowhee, North Carolina Jackson County Western Carolina University Attn. Mr. Roger Turk 3476 Old Cullowhee Road Cullowhee, North Carolina, 28723 (828) 227-3571 Primary Consultant: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 (828) 252-8130 1.2. Background Information WCU operated the MSWLF from approximately the 1960s until 1993. Jackson County also disposed of municipal solid waste at the landfill from approximately the early 1970s through the early 1980s. The landfill property is approximately 31.5 acres, approximately four acres of which contain the former landfill. The landfill was closed in accordance with the then applicable North Carolina Department of Environmental Quality (NCDEQ) closure standards (15A NCAC 13B 0.0510), and a closure letter was issued to WCU by NCDEQ on September 5, 1995. NCDEQ personnel conducted a facility audit on March 16, 2011 and determined that semi-annual water quality and landfill gas monitoring at the landfill must be performed in order for the landfill to be in compliance with the post -closure conditions identified in the 1995 closure letter. In response to the audit, a Landfill Gas Investigation Work Plan, which described the preliminary landfill gas investigation, as well as the 'full' landfill gas investigation, was submitted to NCDEQ on October 19, 2011, and approved by NCDEQ in a letter dated November 29, 2011. Wood February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 April 7, 2020 Environment & Infrastructure Solutions, Inc. (Wood) conducted the preliminary landfill gas investigation in January 2012 using the existing groundwater monitoring wells. NCDEQ indicated that when funding became available to WCU from the State of North Carolina, the 'full' landfill gas investigation was to be implemented. Wood has conducted semi-annual water quality monitoring since August 2011 and conducted semi-annual landfill gas monitoring utilizing the existing groundwater monitoring wells from August 2012 to November 2015 to comply with the post - closure conditions. The 'full' landfill gas investigation, including the installation of eight permanent landfill gas monitoring wells, was performed in February 2016. Quarterly landfill gas monitoring is now conducted. February 2020 Water Quality and Landfill Gas Monitoring Report April 7, 2020 WCU Closed MSWLF Wood Project 6252-15-0221 2. FIELD ACTIVITIES Wood personnel visited the Site on February 25, 2020 to conduct water quality monitoring and on February 26, 2020 to conduct landfill gas monitoring. 2.1. Landfill Gas Monitoring Wood personnel measured landfill gas at the eight landfill gas monitoring wells (LG-1, LG-2, LG-3S, LG-3D, LG-4, LG-5, LG-6 and LG-7) at the Site (Figure 2). The landfill gas monitoring wells are screened in the unsaturated zone and located between the landfill and the Site's property boundary (Table 1). The landfill gas monitoring wells are fitted with a slip cap and ball valve to allow for measurement of potential landfill gas. A calibrated gas monitoring instrument, a Landtec GEM 5000, was used to measure atmospheric barometric pressure, as well as the following landfill gas parameters: Methane (percent by volume) Oxygen (percent by volume) Carbon dioxide (percent by volume) The initial and stabilized readings for the above parameters were measured and recorded. The Solid Waste Section's Landfill Gas Monitoring Data Form was used to record measurements and other relevant information and is provided in Appendix A. 2.2. Water Quality Monitoring Wood personnel gauged static groundwater levels in the four Site monitoring wells (MW-1, MW-2, MW-3 and MW-4). Water levels were referenced to the top -of -casing at the wells. Depth to water measurements and water table elevations for the monitoring wells are presented in Table 2. The monitoring wells were purged and sampled using low -flow purging with a variable -speed submersible and/or peristaltic pumps and new polyethylene tubing. The tubing intake was lowered to within five feet of the bottom of the monitoring wells. The pumping rate was minimized to prevent excessive drawdown in the well and simulate the groundwater recharge rate, which was monitored using an electronic water level indicator. Water quality parameters (temperature, pH, specific conductance, dissolved oxygen, oxidation-reduction potential, and turbidity) were measured using a water quality meter equipped with a flow -through cell (Table 3). Groundwater samples were collected from the monitoring wells after the water quality parameters stabilized. The purged water was discharged to the ground surface in proximity to each well in a manner that precluded erosion or surface runoff. Copies of the groundwater sampling logs are provided in Appendix B. The submersible pump was decontaminated by washing the pump and electrical cable in an industrial detergent and distilled water solution. The pump was then rinsed with distilled water. An equipment blank sample, EB-1, was collected from the pump discharge by operating the pump in deionized water and pumping the water into sample containers. February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 April 7, 2020 Surface water samples, SW-1 and SW-2, were collected at the approximate locations depicted in Figure 2. The water samples were placed in laboratory -supplied containers, labeled with sampling information, packed in an ice -chilled cooler, and shipped with appropriate chain -of -custody records via overnight delivery to Waypoint Analytical (a North Carolina -accredited analytical laboratory). The samples were submitted for analysis of Appendix I volatile organic compounds (VOCs) according to Environmental Protection Agency (EPA) Method 8260, 1,4-dioxane via EPA Method 8260 SIM (selective ion monitoring), and Appendix I metals according to EPA Method 6020 (3030C preparation method). 4 February 2020 Water Quality and Landfill Gas Monitoring Report April 7, 2020 WCU Closed MSWLF Wood Project 6252-15-0221 3. RESULTS AND DISCUSSION The results of the water quality and landfill gas monitoring event are reported in the NCDEQ Environmental Monitoring Report Form that is provided in Appendix C and summarized in the following sections. 3.1. Landfill Gas The Site landfill gas monitoring wells were tested for methane, carbon dioxide and oxygen. Refer to the attached Landfill Gas Monitoring Data Form for the testing results. Concentrations of methane were not detected in the landfill gas monitoring wells. The regulatory limit for methane at a MSWLF property boundary is equal to the lower explosive limit of methane (15A NCAC 1313.1627 (d)). The recorded results from the eight landfill gas wells do not exceed this limit indicating that regulatory limits are not being exceeded at the Site's property boundary. 3.2. Groundwater and Surface Water Monitoring well MW-1 is the u pg rad ient/backg round monitoring well. The groundwater analytical results were compared to the North Carolina Groundwater Classification and Standards (15A NCAC 2L .0202, amended effective April 1, 2013), which includes applicable interim standards updated April 6, 2018, herein referred to as the "21- Groundwater Standards", and the EPA Maximum Contaminant Levels (MCLs) established in the National Primary Drinking Water Regulations, dated May 2009. The surface water analytical results were compared to the North Carolina Surface Water Quality Standards, Criteria and Protective Values (15A NCAC 213, summary tables, dated June 10, 2019), which include EPA's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health and North Carolina Protective Values for Surface Waters, herein referred to as the "Surface Water Standards." Analytical results from the February 2020 water quality monitoring event are presented in Tables 4 and 5, and historical analytical results are presented in Tables 6 and 7. The laboratory analytical report is included in Appendix D. 3.2.1. Appendix I VOCs Appendix I VOCs were not detected above the method detection limit (MDL) in the groundwater samples collected from monitoring wells MW-1 and MW-2. Four Appendix I VOCs were detected at concentrations above the MDL in the groundwater samples and duplicate (FD-1) collected from monitoring well MW-3 and four Appendix I VOCs were detected above the MDL in the groundwater sample collected from monitoring well MW-4. The detected VOC concentrations were below their respective 2L Groundwater Standards and EPA MCLs. Three Appendix I VOCs (acetone, chlorobenzene and 1,4-dichlorobenzene) were detected at concentrations above their respective MDLs in surface water sample SW-1. Two Appendix I VOCs (chlorobenzene and 1,4-dichlorobenzene) were detected at concentrations above their respective MDLs in surface water sample SW-2. The detected VOC concentrations were below their respective Surface Water Standards. February 2020 Water Quality and Landfill Gas Monitoring Report April 7, 2020 WCU Closed MSWLF Wood Project 6252-15-0221 3.2.2. 1,4-Dioxane 1,4-Dioxane was not detected above the MDL in the groundwater samples collected from monitoring wells MW-1 and MW-2. 1,4-Dioxane was detected at concentrations above its respective MDL in the groundwater samples collected from MW-3 (and duplicate FD-1) and MW-4 The groundwater 1,4-dioxane concentrations ranged from 1.6 (estimated) to 2.8 micrograms per liter (pg/L). The concentrations of 1,4-dioxane estimated or detected did not exceed the 2L Groundwater Standard. An EPA MCL is not currently established for 1,4-dioxane. 1,4-Dioxane was detected at concentrations above its respective MDL in the surface water samples collected from SW-1 and SW-2. The surface water 1,4-dioxane concentrations ranged from 1.8 pg/L (estimated) to 2.1 pg/L. The concentrations of 1,4-dioxane detected in SW-1 and SW-2 did not exceed the applicable Surface Water Standard of 80 pg/L. 3.2.3. Appendix I Metals Six Appendix I metals were detected above the MDLs in the groundwater samples, including the field duplicate sample FD-1, which was collected from MW-3. Five of the six Appendix I metals were detected at concentrations and/or estimated concentrations below their respective 2L Groundwater Standards. Cobalt was detected at concentrations above the MDL, but below the 2L Groundwater Standard in groundwater samples collected from MW-1, MW-2, and MW-4. Cobalt was detected at concentrations of 10 pg/L in both groundwater samples MW-3 and duplicate FD-1, which are greater than the 2L Groundwater Standard of 1 pg/L. An EPA MCL is not currently established for cobalt. Concentrations of Appendix I metals in groundwater samples have generally been lower than historic concentrations with less exceedances above applicable Standards since low -flow purging/sampling has been implemented. Low -flow purging/sampling techniques will continue to be used for the next semi-annual water quality monitoring event. Seven Appendix I metals were detected at concentrations above the MDLs in the surface water samples SW-1 and/or SW-2. Copper was detected at an estimated concentration of 5.1 pg/L, which exceeds its calculated Surface Water Standard for Freshwater Aquatic Life of 3.6, in the surface water sample collected from SW-1. 0 February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 TABLES April 7, 2020 TABLE 1 Landfill Gas Well Construction Details Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Landfill Gas Well Installation Date Drilling Method Well Material Well Depth (bgs) Screened Interval (bgs) Ground Surface Elevation Top of Casing Elevation Latitude Longitude LG-1 LG-2 2/17/2016 HSA HSA PVC PVC 18.0 5.0 - 17.8 5.0 - 19.7 2,243.52 2,207.23 2,246.35 35.3241 -83.1822 2/17/2016 20.0 2,209.97 35.3249 -83.1825 LG-3S 2/16/2016 HSA PVC 30.0 4.8 - 29.8 2,180.25 2,183.19 35.3261 -83.1831 LG-3D 2/16/2016 HSA PVC 66.2 36.0 - 66.0 2,180.25 2,183.14 35.3261 -83.1831 LG-4 2/18/2016 HSA PVC 7.9 4.9 - 7.7 2,125.80 2,128.58 35.3266 -83.1823 LG-5 2/18/2016 HSA PVC 30.4 5.3 - 30.1 2,166.48 2,169.12 35.3266 -83.1813 LG-6 2/18/2016 HSA PVC 10.7 5.6 - 10.4 2,208.23 2,210.92 35.3253 -83.1810 LG-7 2/17/2016 HSA PVC 35.3 5.2 - 35.0 2,266.43 2,269.08 35.3244 -83.1811 Notes: 1. Depths are in feet relative to ground surface (bgs). 2. Elevations are in feet relative to mean sea level. 3. HSA - hollow -stem auger; PVC - Schedule 40 polyvinyl chloride. Prepared By: RMC 3/6/20 Checked By: GLH 3/9/2020 TABLE 2 Well Construction Details and Water Level Data - February 2020 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Well Installation Date* Latitude Longitude Ground Surface Top of Casing Elevation Elevation Well Depth (feet MSL) (feet MSL) (feet BTOQ Depth to Water (feet BTOQ Groundwater Elevation (feet MSL) MW-1 1990 35.3240 -83.1811 2,302.50 2,306.01 93.28 69.88 2,236.13 MW-2 1990 35.3249 -83.1825 2,206.88 2,209.37 50.78 26.78 2,182.59 MW-3* 1990 35.3259 -83.1826 2,182.88 2,185.65 **62.92 48.48 2,137.17 MW-4 1990 35.3264 -83.1818 2,129.14 2,131.66 21.35 6.05 2,125.61 Notes: 1. Water levels were obtained on February 25, 2020. 2. * Actual date of well installation is not known, but monitoring wells were first sampled in March 1990 during closure activities (Law Engineering report dated January 16, 1991); screened interval depths are not known. 3. MSL - mean sea level; BTOC - below top of casing. 4. ** Well depth indicated in 2004 monitoring report (RETAW Corporation) indicates well depth is 71.7 feet. Prepared By: RMC 3/6/2020 Checked By: GLH 3/9/2020 TABLE 3 Groundwater Quality Data - February 2020 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Oxidation Reduction Dissolved Temperature Conductivity Potential Oxygen Turbidity Monitoring Well (°C) pH (MS/cm) (mv) (mg/L) (NTU) MW-1 12.45 5.17 0.018 400 14.27 *0.5 MW-2 12.57 5.83 0.092 285 2.94 *0.0 MW-3 13.48 5.93 0.285 -25 0.54 *0.0 M W-4 12.93 6.01 0.189 515 4.74 *0.0 Notes: 1. Groundwater quality data reported above collected prior to sample collection. 2. Water quality parameters were measured on February 25, 2020. 3. °C - degrees Celcius; mS/cm - milliSiemens per centimeter; my - millivolts; NTU - nephelometric turbidity units; mg/L - milligrams per liter. 4. *Turbidity readings lower than previous data. Attempted recalibration of water quality meter in field with autocal solution to 0.0 NTU. Prepared By: RMC 3/6/2020 Checked By: GLH 3/9/2020 TABLE 4 Groundwater Analytical Results - February 2020 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 2L Groundwater Standard EPA MCL MW-1 MW-2 MW-3 FD-1 (MW-3) MW-4 Appendix I VOCs and 1,4-Dioxane Benzene 1 5 <0.34 <0.34 0.40 J 0.45 J <0.34 Chlorobenzene 50 100 <0.34 <0.34 9.2 9.3 8.4 Chloroethane 3,000 NE <0.43 <0.43 <0.43 <0.43 0.68 1,4-Dichlorobenzene 6 75 <0.42 <0.42 2.3 2.2 2.3 cis- 1,2-Dichloroethylene 70 70 <0.40 <0.40 1.7 1.6 1.1 1,4-Dioxane 3 NE <0.14 <0.14 1.6 J 1.7 J 2.8 Appendix I Metals Antimony 1 6 2.3 BJ 2.1 BJ 2.1 BJ 2.1 BJ 2.0 BJ Barium 700 2,000 36 87 120 120 110 Chromium (total) 10 100 1.1 J 1.3 J <0.89 <0.90 <0.90 Cobalt 1 NE <0.69 <0.69 10 10 <0.69 Copper 1,000 1,300 4.7 J <4.6 <4.6 <4.6 <4.6 Nickel 1 100 NE 1 1.5 J 1.5 J 3.5 3.7 0.89 J Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation method. 3. Concentrations are in micrograms per liter (lag/L). 4. 2L Groundwater Standard - from 15A NCAC 2L, effective April 1, 2013, including Interim Maximum Allowable Concentrations. 5. EPA MCL - Environmental Protection Agency Maximum Contaminant Level. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated MDL. 9. J - concentration is estimated. 10. Bold concentrations indicate exceedance of the 2L Groundwater Standard. Prepared by: RMC 3/6/20 Checked by: GLH 3/11/20 TABLE 5 Surface Water Analytical Results - February 2020 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 NC Surface Water Standard (Freshwater Aquatic Life) NC Surface Water Standard EPA NRWQC (Human (Human Health) Health) NC Protective Values (Freshwater Aquatic Life) NC Protective Values (Human Health) SW-1 SW-2 Appendix I VOCs and 1,4-Dioxane Acetone Chlorobenzene NE NE NE NE NE NE 2,000 1,100,000 1.9 CCVLJ <0.70 NE 800 140 NE 2.8 1.5 1,4-Dichlorobenzene NE 900 100 NE 0.77 0.51 1,4-Dioxane NE NE NE 80 2.1 1.8 J Appendix I Metals Antimony NE NE 640 5,300 NE 2.0 BJ 2.0 BJ Barium NE NE NE 21,000 200,000 (t) 260 130 Cobalt NE NE NE 16 (acute) 4 3.9 3.3 Copper 3.6 (acute)* NE NE NE NE 5.11 <4.6 Lead 14 (acute)* NE NE NE NE 2.0 <0.44 Nickel 145 (acute)* NE 4,600 NE NE 4.3 1.2 J Zinc 1 36 (acute)* i NE I NE NE I NE 1 20 1 14 J Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I Metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation. 3. Concentrations are in micrograms per liter (pg/L). 4. NC Surface Water Standard - From 15A NCAC 2B (tables dated June 10, 2019). 5. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated method detection limit. 9. J - concentration is estimated; B - analyte is found in the associated blank at a concentration greater than half the laboratory reporting limit; CCVL - CCV result is below control limits, but within method parameters, and a standard at or below the reporting limit was analyzed and found acceptable. 10. Bold concentration indicates exceedance of NC Protective Value. 11. t - Based upon measurement of total recoverable metal. 12. * A hardness of 25 milligrams per liter was assumed to calculate the standard. Prepared By: RMC 3/6/20 Checked By: GLH 3/11/20 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Location Sample Date C 0 a Appendix I � c � GL O V N '"' VOCs � c � &- 0 V '"' 0 c °7 � s a 0 0 V Q O N rl V > _ X O G Appendix v I Metals 0 a v C 0 °° c N 0 i s v 0 R O i s v c a t +. d 0L. o t V N ,,, �" >+ = O E _ Q V ;: Q m E 7 - m I: 7 u 4a 41 0 I: E u '� _ N " Z 2 W i in _ `° � _ La > N MW-1 8/3/11 0.35 JB 390 63 B 28 180 T 38 0.88 J 0.98 J 160 212112 0.42 J B 62 1.7 3.5 J 0.79 JB 17 8/28/12 0.65 JB 0.32 J 270 0.35 J 0.59 J 8.2 JB 16 26 7.0 6.3 0.27 J 2.9 14 37 B 2/8/13 0.73 J 0.58 JB 530 0.84 J 0.59 J 17 B 42 64 19 17 0.34 J 0.48 J 0.64J 20 63 9/4/13 350 0.32 J 1.7 18 22 61 9.8 13 2.4 JB 0.15 J 26 80 2/19/14 0.20 J 39 0.054 J 0.16 J 0.26 J 1.1 J 0.20 J 0.47 J 0.074 J 6.0 J 9/9/14 3.7 0.38 J 45 0.096 J 0.16 J 1.4 2.8 J 0.53 J 0.67 JB 0.28 J 8.6 JA 6.1 JB 2/25/15 7.3 B /*0.27 J 0.64 J 110 0.14 J 1.1 2.1 J 0.63 J 0.91 J 0.83 J 26 6.8 J 11/6/15 - 0.082 J 0.78 J 40 0.14 J 0.11 J 4.3 B 0.53 J 2.0 J 0.52 J 1.0 J 0.042 J 0.17 J 3.9 J 3/2/16 - 0.21 J 2.6 B 37 0.59 J 6.3 B 0.16 J 1.9 J 0.39 J 3.0 0.045 J 0.12 J 13 B/*4.8 J 9/21/16 - 0.14 J 36 0.062 J 0.052 J 1.6 0.42 J 4.7 J 0.24 J 3.8 0.027 J 0.073 J 7.4 J 2/7/17 - 0.74J 37 0.14J 0.18J 0.97J 0.43J 4.5J 0.50J 0.96J 0.14J 0.26J 1.3J 5.2J 8/23/17 - 41 0.57 J 0.47 BL, J 1.8 J 0.17 J 0.39 J 0.86 J 0.15 J 24 3/15/18 - 1.0 B /*ND 48 B/*63 0.81 J 0.58 J 3.4 J 0.37 J 0.56 J 0.076 J 0.054 J 20 B /*21 8/21/18 - 110 0.12 J 0.076 J 14 5.9 13 2.6 37 0.034 J 3.1 17 3/25/19 2.9 B /*<0.19 54 0.88 J 0.68 J 1.7 J 0.62 J 2.1 0.022 J 16 8/20/19 4.2 J 32 1.6 J 13 J 2/25/20 2.3 BJ 36 1.1 J 4.7 J 1.5 J MW-2 8/3/11 0.48 J 0.22 J 130 0.20 J 2.0 1.8 1.2 J 0.59 J 2.5 0.54 J 0.076 J 0.76 J 3.8 J 9.5 J 2/2/12 0.93 JB 120 0.33 J 0.72 J 0.17 JB 2.3 0.064 J 0.26 J 9.3 J 8/28/12 0.46 JB 110 0.31 J 0.47 J 4.8 JB 0.62 J 1.5 J 0.50 J 2.5 0.040 J 3.0 2.5 J 11 B 2/8/13 100 0.16J 2.2B 0.31J 1.4J 0.15J 1.9J 0.21J 0.14J 0.16J 16 9/4/13 - 100 0.38 J 0.66 J 2.9 J 1.8 J 21 2/19/14 - 0.22 J 0.36 J 100 0.15 J 0.17 J 0.21 J 0.13 J 1.5 J 0.18 J 0.093 J 0.050 J 7.5 J 9/9/14 - 4.2 92 0.18J 0.26J 0.62J 1.2J 0.18J 1.5 JB 0.046J 0.35J 6.6JA 9.0JB 2/25/15 - 5.1 B /*0.22 J 62 1.6 2.7 7.0 1.2 1.7 J 12 33 11/6/15 - 0.075 J 100 0.11 J 0.13 J 3.6 B 3.0 2.8 J 0.69 J 1.7 J 0.039 J 0.15 J 5.3 J 3/2/16 - 0.12 J 3.4 B 100 0.60 J 5.5 B 0.16 J 1.8 J 0.27 J 1.6 J 1.3 0.051 J 0.099 J 0.37 J 12 B/*4.3 J 9/21/16 2.4 J - 0.12 J 110 0.095 J 1.1 0.28 J 8.6 0.19 J 2.6 0.018 J 0.059 J 8.6 J 2/7/17 - 0.59J 89 0.24J 0.28J 0.57J 0.33J 1.2J 0.43J 1.6J 0.60J 0.14J 0.37J 1.1J 5.3J 8/23/17 - 0.38 J 100 0.081 J 0.071 J 0.53 J 0.80 BL, J 2.3 J 0.21 J 1.3 J 0.50 J 0.17 J 28 3/15/18 - 0.95 BJ/*0.70 J 110 B /*110 0.069 J 0.75 J 0.66 J 2.5 J 0.13 J 1.8 J 0.075 J 0.035 J 16 B /*16 8/21/18 - 100 0.085 J 0.082 J 0.53 J 0.083 J 4.2 J 0.32 J 1.5 J 13 3/25/19 3.9 B /*0.22 J 110 0.085 J 0.48 J 0.49 J 3.4 J 0.39 J 1.7 J 0.085 J 16 8/20/19 89 1.7 J 19 J 2/25/20 2.1 BJ 87 1.3 J 1.5 J 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Page 1 of 2 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals a� c °7 c a � s � c � c t a +. d o c o 4a c41 N GL 0 R O &- O t V Q O _ R X >+ E I: I: U �+ N '1 = O 2 Monitoring Sample C y O O N v G = I: .2To 0. N 'O v C s N v � � _ M a M s o o a `-' d s R Location Date a °° U U 74 '"' > Q a to CO U U U U Z rn in I-- > N MW-3 8/3/11 78 1.0 15 0.66 4.9 9.5 0.49 J 1.0 150 0.89 J 1.3 8.5 1.7 J 0.59 J 5.1 1.5 0.15 J 1.1 3.0 J 46 2/2/12 6.6 0.79 7.1 3.4 4.8 0.34 J 0.72 JB 5.0 340 0.34 J 31 36 75 30 8.2 B 79 1.3 0.072 J 1.3 36 3,700 8/28/12 3.3 J 0.97 14 4.5 8.8 - 0.18 JB 0.97 J 130 0.48 J 4.7 JB 6.3 1.8 J 0.30 J 4.1 1.6 0.091 J 0.68 J 40 B 2/8/13 3.2 9.1 3.7 5.5 - 150 0.56 J 1.6 B 15 2.6 J 0.18 J 4.0 1.1 0.071 J 26 9/4/13 0.51 11 3.2 5.2 - 390 0.20 J 0.70 J 26 17 16 4.3 J 19 2.3 JB 50 95 2/19/14 0.71 12 3.7 6.4 - 0.13 J 0.37 J 150 0.073 J 0.37 J 7.3 2.1 J 0.33 J 2.5 0.77 J 0.068 J 0.054 J 1.8 J 18 9/9/14 0.61 12 4.1 4.5 - 3.4 130 0.076 J 0.24 J 9.0 1.6 J 0.19 J 3.0 B 0.16 J 9.5 JA 20 B 2/25/15 79 1.1 12 3.9 5.2 6.1 B /*0.41 J 1.2 340 0.28 J 2.1 14 13 20 4.8 16 0.83 J 0.074 J 0.38 J 38 120 11/6/15 250 1.1 17 0.53 4.9 5.6 1.2 390 0.23 J 1.1 25 B 16 25 6.3 19 1.1 0.058 J 0.33 J 54 120 3/2/16 5.4 0.59 10 2.3 4.0 0.095 J 3.1 B 120 0.048 J 0.43 J 5.2 B 6.2 1.4 J 0.34 J 1.5 J 4.5 0.048 J 0.035 J 12 B/*5.0 J 9/21/16 28 0.79 14 3.5 3.5 0.30 J 150 0.25 J 0.73 J 11 3.3 J 0.68 J 6.6 0.82 J 0.020 J 0.13 J 3.4 J 18 2/7/17 260 0.97 10 3.6 2.9 1.6 1.2 250 0.23 J 3.2 9.0 8.9 17 7.5 14 1.6 0.072 J 0.50 J 17 180 3/15/18 0.85 15 3.8 5.0 0.85BJ/*0.54 J 150 B /*150 0.46 J 13 4.1 280 13 0.51 J 67 1.2 J 0.074 J 0.38 J 0.90 J 300 B /*280 8/21/18 7.7 0.61 9.9 2.4 2.5 - 110 0.111 0.078 J 0.56 J 15 2.4 J 0.073 J 4.2 0.57 J 9.7 3/25/19 6.8 0.63 11 0.26 J 2.7 2.7 3.1 3.8 B /*<0.19 120 0.34 J 17 1.5 J 0.16 J 5.3 0.038 J 12 8/20/19 0.53 11 2.4 2.2 2.5 120 9.2 3.2 15 J 2/25/20 0.40 J 9.2 2.3 1.7 1.6 J 2.1 BJ 120 10 3.5 MW-4 8/3/11 0.67 15 0.53 5.4 4.8 - 0.27 J 0.31 J 210 0.36 J 4.4 1.9 3.5 J 1.4 2.3 0.91 J 0.060 J 0.35 J 7.4 11 2/2/12 1.5 0.73 0.52 0.44 J B 89 0.38 J 1.0 J 0.46 JB 0.19 J 14 8/28/12 3.5 1.6 1.1 - 120 0.37 J 5.9 JB 0.82 J 2.8 J 0.65 J 1.5 J 0.59 J 0.41 J 4.1 J 28 B 2/8/13 1.7 0.83 0.65 - 85 0.13 J 3.0 B 0.47 J 1.9 J 0.33 J 0.67 J 0.33 J 0.041 J 18 9/4/13 10.0 3.9 2.8 - 190 0.26 J 8.01 3.1 J 7.8 1.6 J 3.0 J 10 J 46 2/19/14 4.3 1.8 1.4 - 0.099 J 0.35 J 120 0.067 J 0.23 J 0.46 J 1.1 J 0.35 J 0.96 J 0.57 J 0.054 J 0.053 J 1.9 J 7.8 J 9/9/14 8.3 2.9 1.6 - 4.0 120 0.089 J 0.24 J 1.2 1.8 J 0.60 J 0.90 JB 0.11 J 12 A 5.9 JB 2/25/15 6.4 2.3 1.6 - 6.1 B /*0.21 J 90 0.19 J 0.47 J 1.11 0.30 J 1.5 J 8.3 J 11/6/15 4.6 1.5 0.89 - 100 0.074 J 0.19 J 9.2 B 0.16 J 0.95 J 0.28 J 2.1 0.97 J 0.041 J 0.10 J 3.2 J 3/2/16 6.6 2.6 1.5 - 0.084 J 3.7 B 120 0.60 J 4.3 B 0.099 J 1.3 J 0.20 J 0.46 J 0.85 J 0.045 J 0.032 J 9.5 B, J/*4.3 J 9/21/16 8.8 2.7 1.8 0.79 - 0.13 J 150 0.28 J 0.65 J 0.24 J 7.7 0.21 J 1.3 J 0.62 J 0.023 J 0.050 J 8.2 J 2/7/17 5.0 1.4 0.90 - 0.47 J 99 0.15 J 0.57 J 0.22 J 0.80 J 0.32 J 0.90 J 0.79 J 0.111 1.1 J 4.0 J 8/23/17 9.6 3.0 1.7 - 140 0.20 J 0.77 J 0.31 B, J 1.3 J 0.099 J 1.2 J 0.60 J 0.10 J 17 3/15/18 1.8 0.83 - 0.70 B1 /*0.20 J 90 B /*80 0.054 J 0.48 J 0.082 J 1.1 0.060 J 59 13 B /*13 8/21/18 2.6 0.98 110 0.13 J 0.094 J 1.2 0.85 J 3.0 J 1.0 1.11 2.6 21 3/25/19 4.3 1.9 0.70 3.6 3.6 B /*<0.19 110 0.14 J 0.62 J 0.47 J 1.11 0.22 J 0.84 J 0.020 J 14 8/20/19 0.42 J 11 2.9 1.8 3.7 130 1.7 J 1.8 J 16 J 2/25/20 8.4 0.68 2.3 1.1 2.8 2.0 BJ 110 0.89 J 2L GW Standard 6,000 1 50 3000 20 6 70 100 0.030 1 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 NE 600 75 70 100 2 1 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Notes: Prepared By: RMC 3/1/20 1. VOCs - volatile organic compounds according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Metals according to EPA Method 6020, using EPA Method 3030C preparation. Checked By: GLH 3/11/20 2. Concentrations are in micrograms per liter (Ng/L). 3. 2L GW Standard - 2L Groundwater Standard from 15A NCAC 2L, effective April 1, 2013 (including interim maximum allowable concentrations). EPA MCL - Envirommnetal Protection Agency's Maximum Contaminant Level. 4. NE - associated standard has not been established. 5. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 6. Blank cells indicate constituent not detected in sample above the MDL. 7. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample. 8. Bold concentrations indicate exceedance of 2L GW Standard or EPA MCL. 9. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit. 10. '-' constituent not analyzed. Page 2 of 2 TABLE 7 Historical Surface Water Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals G1 d = C c �. 0 7a _ -0 O o a, o N 0 VC _ O _ y O N t V O 6 O E •_ �_ GJ = L 3 MonitoringSample a c O 'i >' +r °' _ �' E O R Location Date Q CO u ri "v > ri Q Q CO m u u u u -J Z in in > SW-1 2/2/12 0.75 6.2 1.8 0.68 - 0.59 JB 250 6.5 1.2 J 0.20 JB 1.2 J 1.0 0.23 J 33 3/2/16 1.1 - 0.19 J 3.8 B 260 0.41 J 4.3 B 2.2 5.0 J 3.3 3.3 0.78 J 0.039 J 0.11 J 1.2 J 19 B/*21 8/21/18 6.4 - 0.44 J 240 0.16 J 0.13 J 0.49 J 4.8 7.2 3.4 5.8 0.076 J 2.4 14 2/25/19 2.2 0.66 4.1 B /*<0.20 J 190 0.16 J 2.5 4.1 J 1.5 3.2 0.084 J 29 2/25/20 1.9 CCVLJ 2.8 0.77 2.1 2.0 BJ 260 3.9 5.1 J 2.0 4.3 20 SW-2 8/3/11 2.0 0.96 1.1 - 0.23 J 250 1.0 12 1.2 J 0.080 J 1.7 J 1.0 0.064 J 0.30 J 0.67 J 12 212112 1.4 0.57 - 0.46 JB 0.22 J 170 5.5 0.25 JB 0.95 J 0.69 J 0.19 J 13 8/28/12 2.2 0.78 - 0.48 J 220 5.4 JB 9.4 0.56 J 1.7 J 1.0 0.37 J 1.1 J 14 B 2/8/13 1.6 0.55 - 0.97 JB 170 1.7 B 4.4 0.77 J 1.2 J 0.79 J 0.025 J 20 9/4/13 2.5 0.84 - 180 8.5 0.51 J 26 2/19/14 1.8 0.62 - 0.43 J 160 0.12 J 5.6 0.16 J 1.1 J 0.78 J 0.056 J 13 9/9/14 2.7 1.1 - 4.4 200 0.070 J 10 0.95 J 0.12 J 1.2 JB 0.089 J 9.6 JA 9.1 JB 2/25/15 2.1 0.90 - 6.3 B /*0.22 J 170 8.0 0.92 J 0.30 J 1.1 J 0.70 J 0.082 J 4.2 J 5.7 J 11/6/15 3.3 1.2 - 0.31 J 200 0.041 J 3.0 B 8.8 0.59 J 0.25 J 1.5 J 0.97 J 0.038 J 6.9 J 3/2/16 1.4 - 0.092 J 3.0 B 140 0.36 J 4.0 B 3.1 0.72 J 0.14 J 0.49 J 0.63 J 0.028 J 0.026 J 15 B/*8.9 J 9/21/16 3.3 1.0 - 0.33 J 220 0.054 J 0.043 J 10 0.077 J 0.95 J 0.91 J 0.019 J 0.060 J 1.7 J 2/7/17 1.4 0.59 - 0.45 J 180 7.8 0.12 J 1.0 J 1.5 0.047 J 3.2 J 8/23/17 2.0 0.74 - 390 0.90 J 16 B 0.69 J 0.17 J 2.2 0.48 J 0.069 J 17 3/15/18 1.1 - 0.90 BJ /*0.29 J 180 B /*170 4.1 4.0 J 0.24 J 1.1 J 18 B /*14 8/21/18 8.1 2.0 0.57 - 460 0.16 J 0.10 J 0.97 17.0 2.7 J 1.4 3.0 1.1 19 2/25/19 0.80 4.1 B /*<0.19 110 2.0 1.0 J 0.14 J 1.2 J 0.022 J 19 8/20/19 3.4 J 3.1 0.84 5.0 190 10 1.6 J 17 J 2/25/20 1.5 0.51 1.8 J 2.0 BJ 130 3.3 1.2 J 14 J NCSW Standard - 340 65 0.82 3.6 14 140 0.30 36 NE NE NE NE NE NE NE NE NE NE NE 5(t) NE NE Freshwater Aquatic Life (acute) (acute) (acute)** (acute)** (actute)** (acute)** (acute)** (acute)** NCSW Standard - NE 51 NE NE NE 2.4 NE NE 10 (t) NE NE NE NE NE NE NE NE NE NE NE NE NE Human Health EPA NRWQ - Human NE NE 800 900 NE NE NE 640 NE NE NE NE NE NE NE NE 4,600 4,200 NE 0.47 NE NE Health NCPV -Freshwater Aquatic 16 2,000 NE 140 100 NE NE NE NE NE 21,000 NE NE NE NE NE NE NE NE NE NE NE Life (acute) NCPV - Human Health 1,100,000 NE NE NE 720 NE 1 80 5,300 NE 200,000 (t) NE NE NE 4 NE NE NE NE NE NE NE NE TABLE 7 Historical Surface Water Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-diozane analyzed via EPA Method 8260B SIM 2. Concentrations are in micrograms per liter (pg/L). 3. NCSW Standard - North Carolina Surface Water Standards from 15A NCAC 2B (table dated June 10, 2019); a = acute 4. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health 5. NCPV - North Carolina Protective Values from table dated June 10, 2019 22, 2017. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents 8. Blank cells indicate constituent not detected in sample above the MDL. Metals anlyzed according to EPA Method 6020, using EPA Method 3030C preparation 9. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample; CCVL- continuing calibration verification result is below control limits, but within method parameters, and a standard at or below the reporting limit was analyzed and found acceptable. 10. Bold concentrations indicate exceedance of a Surface Water Standard. 11. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit 12. - indicates not analyzed. 13. ** A hardness of 25 milligrams per liter was assumed to calculate the standard. 14. t - based upon measurement of total recoverable metal. Prepared By: RMC 3/9/20 Checked By: GLH 3/11/20 February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 FIGURES April 7, 2020 �hth' BM LHT 1( * J rf �l N �- _ _ �~. I - i l^- . ��_- i_,...i� • h J`����--ti f /� ,gyp yBPI LHT Tr'-- • BM"LHT631. f .��� �� r � —may, Fpea � � �•S, �, •_..� +r Ir0i1Qf' / a %r l�'• .f /�.. ��; � �ti � _ f �i �� 'i• �_ I j. "ro r � _ 1. ��,_ •l - -. ' a' �� '�:� �� � ���� % _�_l` - •..,I{- '•.. l�Fi�l...'as + �f j�.l�`.,'- I _ •-`�,pp --=---f�¢a --�J r��a'���� f ������ f I dam% i /\��_ � \ �� - _O •�.a- 6 �•zsoa..fir E ~ 9_.�.`�\ \ �— ;� `� = �f�N si�y, IR" s • � :n� 'i �' =_, _ �\~� ,� . fir- _ ■°: -s r ♦ SYLVA SOUTH, N.C. QUADRANGLE 35083-C2-TF-024 N.C. DMA 4354 1 SW -SERIES V842 PRINTED 1946 PHOTOREVISED 1990 QUADRANGLE LOCATION NOTE: SITE BOUNDARY IS APPROXIMATE. CONTOUR INTERVAL 40 FEET GRAPHIC SCALE FEET wood 2,000 1,000 0 2,000 4,000 TOPOGRAPHIC SITE MAP DRAWN: RMC DATE: FEB. 2020 DFT CHECK: MEW SCALE: 1" = 2,000' WCU CLOSED MSWLF ENG CHECK: -- JOB: 6252-15-0221 MONTEITH GAP ROAD CULLOWHEE, NORTH CAROLINA APPROVAL: MEW FIG: 1 ' ice+ � � - ... '� - f - �� ` - � yrMt-,. j_ ` ;=•` �� _ - ct_" * is C' . IF - /� - _ r•� - Ll Tom. _ _ Ap ` -1- - `}y #�� x -- • r_• _� _ - - � #� �r%.mil • - -- ~ � ,ate ' �_-- ��. y"�� +# � ��' A �ij!„�� .% _ -- -� i Wz 961 LG— 5 p _ 3, F :. ' $ BMW-4 s. r ".T a' Ito, A LG— 3' - Sic. ♦ -.. . r . _ -ok f y a-- -� '� LG— 2AL e ►r, \ -r or �t .' arm-ap' F'�.. T- .. '> . - zNL '-,.411 M WTO - - Jam_ ♦ .,.� '+_ - yE._ »-S - _ ' - •.-- _.T ` - ��i • - am - `- - -.r AC-} t . . y - - -0 LEW lL•11 rr, = - 1 LEGEND GRAPHIC SCALE 180 0 180 360 r� Property Boundary 50—foot Property Boundary Buffer Landfill Extents +MW-1 Monitoring Well 00%Am— i �i Unnamed Tributary/Stream A LG-1 Landfill Gas Well Location Elevation Contour (10—foot interval) NOTE: Locations of depicted features are approximate. 1 INCH = 180 FT. (approximate) LANDFILL GAS AND MONITORING WELL LOCATIONS WCU CLOSED MSWLF wood. CULLOWHEE, NORTH CAROLINA DRAWN: RMC ENG CHECK: -- DATE: FEBRUARY 2020 JOB: 6252-15-0221 DFT CHECK: MEW APPROVAL: MEW SCALE: APPROX. 1" = 180' FIG: 2 REFERENCE: JACKSON COUNTY GIS. February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 LANDFILL GAS MONITORING DATA FORM April 7, 2020 NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: Thisform and any information attached to it are "Public Records"as defined in NC General Statute 132-1. As such, these documents are available fbr inspection and examination by any person upon request (NC General Statute 132-6). FacilityName: WtrU f swff:� Permit Number: � 01 Sampling Date: 2I Z64;�0 NC Landfill Rule (.0500 or .1600): 00500 Sample Collector Name & Position: ISQGGrtQrh i C✓ all /? Cf G4,,,l f—&�211bVdZ Gas Meter Type & Serial Number: (5GI"i 65605yq Gas Meter Calibration Date: Field Calibration Date & Time: Z /7f / Zb q: O0 Field Calibration Gas Type (15115 or 35150): 1.5 f 5 Field Calibration Gas Canister Expiration Date: j 2- Gas Meter Pump Rate: (3.57 a r Ambient Air Temperature: Barometric Pressure in, r mm Hg);Z �f� Weather Conditions: Gteocc o /,, 4tta►.1 Instructions: Under "Location or LFG Well", list monitoring well # or describe monitoring location (e.g., inside field office). Attach a test location map or drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % CH4 (by volume) to %LEL as follows: % methane (by volume)120 = %LEL, *Hydrogen Sulfide (H2S) gas monitoring may be required for Construction & Demolition Landfills (CDLFs). See individual permit conditions and/or Facility LFG monitoringplan. Location or LFG Well ID Sample Tube Purge Time of Day Time Pumped (sec) Initial % LEL Stabilized LEL % % CH4 ( volume ) % 02 (volume) % CO2 (volume) % H2S° (volume) NOTES �a IZ/ 15 60 0 0 0.0 22.L1 0.0 0 Z-4r.-1 60 14.10 60 0 0 0•o :ll.y 3-.3 0 r •z Go l:3 (5�0 0 o 0..0 2J.z4 1.1 GG -35' 60 114:56 (50 0 0 00 .17- -1 SS 0 4.G-3D 60 4'4S (50 0 0 010 15-13 -6,1 d Z-5;- - Y 60 15:60 60 O 0 C, >. 0 l :7. o 4i.Q a L- r-:,. -5 60 6o O 0 0-0 2-12- 1.5 0 LG 6 6'0 K: 30 60 0 0 C) 0 Z V3 1.7 0 G.G w 6'0 1545 60 0 0 0.0 19. q 2.Z1 Q NOTE: Ifneeded, attach additional data forms to include additional LFG monitoring data locations for the facility. ACTION Lrvr.LS: Methane: >1.25% by volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen Sulfide: >.1% by volume (inside structures) AND >4% by volume (at facility boundary) Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibi ' y of a fine and imprisonment. 1-10 SIGNATURE TITLE Revised — March 6, 2017 February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 /_1»4011911:41:3 GROUNDWATER SAMPLING LOGS April 7, 2020 FIELD INSTRUMENT.CALIBRATION RECORD Project Name: Western Carolina University - Closed MSWLF Date: —4 /,?,-- ' 'c� Project Number: 6252-15-0221.05 Name: • Water Quality Meter Calibration Standard Value Meter Value Acceptance Criteria Manufacturer: Q�pH: ".40el' SU (low) pH: el SU +1-10% of standard Model No.: pH: SU (mod) pH: SU +1-10% of standard Unit ID: -11ye 2, / *;r pH:SU (high) pH: SU +/-10% of standard Conductivity: mS/cm Conductivity: mSlcm +1- 10% of standard Thermometer Temperature: C. Temperature: C. +1- 2.0 C° Turbidity Meter Calibration Standard Value Meter Value Acceptance Criteria Manufacturer: NTU (low) NTU +1_ 10% of standard Model No.: sz, _ NTU (med) NTU +/- 10% of standard Unit ID: NTU (high) NTU +/-10% of standard NTU (high) NTU +/-10% of standard Photoionization Detector Acceptance Criteria Manufacturer: Background: ppmv Meter: ppmv within 5 ppmv of Zero Model No.: Span Gas: ppmv Meter: ppmv +1- 10% of standard Unit ID: Calibration Sources Source 4u�.�a� Value Lot Number Expiration Date pH (low) arSCA' 4ik 4. Q SU-f9?q1?C14 7 Ire1" . pH (med) �'d SU pH (high) SU Conductivity Pr 1541-�el.1 . V mS/cm #® Oro 6. 7-0 Turbidity (low) PA,4f— Ac.&Fcd) ®. G NTU tl O 6. 2'G Turbidity (med): NTU Turbidity (high): NTU Turbidity (high): NTU PID gas: ppmv Other: NOTES: .f If a meter reading is not within acceptance criteria, clean or replace probe and re -calibrate, or use a differe�.t meter if available. If project requirements necessitate use of the instrument, clearly document on all data sheets and log book entries that the parameter was not calibrated to the acceptance criteria. FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER 1 6252-15-0221.05 DATE WELL) SAMPLE NUMBER I A4W— I ACTIVITY TIME START C END I r: G TIME (sample time) QC SAMPLES COLLECTED ASSOCIATED TRIP BLANK ` {� WATER LEVEL 1 PUMP DATA INITIAL FINAL DTVV TdC DTW��TOC SCREENED INTERVAL Q 3 %� PUMP DEPTH VOLUME PURGED allons �. ft TdC SUBMERSIBLE PIUMPFVI PERISTALTIC PUMP �'y_ +1J�S���/�.V PURGE DATA + ' TIME DTW (rt) PURGE RATE Llmin TEMP C° H ORP (mV) SPECIFIC CONDUCTIVITY (mSICm) TURBIDITY (NTU) DO (m 1L CgMMENTS 16.•sz 1.ss 12-11 S . 6 3cta 0.0V9 100 cl .05 10: go. 3s 2.36 5.119 393 D o 1S 815.1 3.qo lcs: Z Z P I G.$ Q .. 0.01E 3S.1 9.8c �.�s; goc) o.o�S ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: SIGNATUR FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING ROJECT Western Carolina University JOB NUMBER 6252-15-0221.05 WELL I SAMPLE NUMBER I AOIW'-�ACTIVITY TIME 5TAR7 7- O END / 3 • IC SAMPLES COLLECTED (� A ASSOCIATED TRIP BLANK WATER LEVEL I PUMP DATA INITIAL FINAL VOLUME DTW• fi TOC DTW Q ft TOC PURGED gallbns SCREENED PUMP 'PT 13 J. SrJ. � DEPTH ti 44 9" S fl TOC INTERVAL DATE TIME (sample time) ;UBMERSIBLE PUMP r/ 'ERISTALTIP PUMP. 6604P!9 t�-)l 40 4z " PURGE DATA I TIME DTW H PORGE RATE Llmin TEMP C. H ORP (mV) SPECIFIC CONDUCTIVITY (mSICm) TURBIDITY (NTU) DO (m IL COMMENTS r:� ��• a.s rZ•41 1 ar3 3�.cs5 Z, ��Z 0.0 0.0 Z .� - j5-1wc ZS-71 0.05; (3-0 32. �, S S .S 3 �.�� o. 493 a. G 2• �� �. • �. Iz. S 3 zos G. 0.6 2.6 XSES: Appendix I VOCs via 8260, 1,4-DDiiooxane via 8260 SIM and Appendix I Metals via 6020 // SIGNATU a '` FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER 6252-15-0221.05 DATE T WELL I SAMPLE NUMBER � �/V' ACTIVITY TIME START QG END � . •�� TIME (sample time) QC SAMPLES COLLECTED', ASSOCIATED TRIP BLANK WATER LEVEL 1 PUMP DATA IJ DTW INITIAL Sr ft TdC DTW L Q. �o ft TOC PURGED `+" `� • 5 allans SCREENED PUMP INTERVAL MV TR .- (33. 3 3 . LG DEPTH /L,5? ft TOC SUBMERSIBLE PUMP= PERISTALTIC PUMP _ PURGE DATA TIME DTW (tt) PURGE RATE (Umin) TEMP (C° pH ORP (mV) SPECIFIC CONDUCTIVITY (mSlcm) TURBIDITY (NTU) DO (m IL COMMENTS e c � 0 T ` . -Z I . � . C�S "-27 0. 2-c . 006 0.0 0.0(7 r i ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: Co j��� E� " Aso' oo SIGNATURE: FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER F 6-252-15-0221,05 WELL I SAMPLE NUMBER Ml/(/- ACTIVITY TIME START .rv(� ENDf'2 �� // QC SAMPLES COLLECTED�ydej ASSOCIATED TRIP BLANK DATE Z ZS TIME E�•� (sample tlme} WATER LEVEL 1 PUMP DATA INITIAL //'. FINAL DTw f7. ft TOC DT V fl TOC PUMP SCREENED :. -41.3S DEPTH INTERVAL VOLUME PURGED �'}.5 allons '� .G� '`� ft TOC SUBMERSIBLE PUMP PERISTALTIC PUMP PURGE DATA TIME DTW n} PURGE RATE (Umin) TEMP H 4":' ORP mV SPECIFIC CONDUCTIVITY mSlcm TURBIDITY NTU DO m 1L COMMENTS a.®-79 .�.1 0.0465 s: 6.8o .'?Z 67.117 Igo 0.11-5 ./u� 4.1 .'r &. ® Q. rs3gG. 2.�s 6.i2 O. 0..0 0 (7-0i�1'J S22 O.Jgq I-O ®.- 4, ° 1Z ° 7-3 <. q 5z . 1 en G G. S ct---3 Srs 0.0 .z3 ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: 4�fo re�-A s - f -5. 330 SIGNATUR February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 APPENDIX C NCDEQ ENVIRONMENTAL MONITORING REPORTING FORM April 7, 2020 I IDENR USE ONLY: t ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No DoclEvent #: ANC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Rodney Clark Phone: 828-252-8130 E-mail: rodney.clark@waadplc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Western Carolina University Monteith Gap Road (State Road 1336) 50 D1 DA500 February 25 - 26, 2020 MSW Landfill Cullowhee, Jackson County, NC 28723 Environmental Status: (Check all that apply) ❑ I nitiallBaokg round Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells 0 Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledger the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Rodney Clark, LG Technical Professional II (828) 252-8130 Facill resent Name (Print) Title (Area Cade) Telephone Number Affix NC Lice g+i>�'��'i'BfA�i?.n al Geologist Seal Signature 1308 Patton Avenue, Asheville, NC 28806 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 612009 Date SEAL 46896— CKONBPS ��.v :-L .s 14 eF Q P February 2020 Water Quality and Landfill Gas Monitoring Report WCU Closed MSWLF Wood Project 6252-15-0221 /_1»4►1971:4191 LABORATORY ANALYTICAL REPORT April 7, 2020 ■ Way po�nt ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville) Rodney Clark 1308 Patton Avenue (Suite C) Asheville, NC 28806 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: WCU MSWLF Project No.: 50-01 Lab Submittal Date: 02/26/2020 Work Order: 0020393 Case Narrative 3/4/20 14:20 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, WAYPOINT ANALYTICAL a'__� Angela D. Overcash Senior Project Manager Data Qualifiers Key Reference: B Analyte is found in the associated blank at a concentration >1/2 RL. BL MB greater than one half of the RL, but the sample concentrations are less than the RL. CCVL CCV result is below control limits but within method parameters. A standard at or below the RL was analyzed and found acceptable. Result is reported but considered estimated. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 0Sample Waypoint ANALYTICAL Receipt Summary 03/04/2020 Work Order: 0020393 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-1 0020393-01 Water 02/25/20 11:00 02/26/20 13:30 MW-2 0020393-02 Water 02/25/20 13:30 02/26/20 13:30 MW-3 0020393-03 Water 02/25/20 14:45 02/26/20 13:30 MW-4 0020393-04 Water 02/25/20 16:00 02/26/20 13:30 SW-1 0020393-05 Water 02/25/20 12:00 02/26/20 13:30 SW-2 0020393-06 Water 02/25/20 15:30 02/26/20 13:30 EB-1 0020393-07 Water 02/25/20 15:00 02/26/20 13:30 FD-1 0020393-08 Water 02/25/20 0:00 02/26/20 13:30 TB-1 0020393-09 Water 02/25/20 0:00 02/26/20 13:30 Samples were received in good condition at 4.3 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 0Waypoi nt ANALYTICAL Summary of Detections W03/04 Work Order: 0020393 393 Prism ID Client ID Parameter Method Result Units 0020393-01 MW-1 Antimony 6020B 2.3 B, J ug/L 0020393-01 MW-1 Barium 6020B 36 ug/L 0020393-01 MW-1 Chromium 6020B 1.1 J ug/L 0020393-01 MW-1 Copper 6020B 4.7 J ug/L 0020393-01 MW-1 Nickel 6020B 1.5 J ug/L 0020393-02 MW-2 Antimony 6020B 2.1 B, J ug/L 0020393-02 MW-2 Barium 6020B 87 ug/L 0020393-02 MW-2 Chromium 6020B 1.3 J ug/L 0020393-02 MW-2 Nickel 6020B 1.5 J ug/L 0020393-03 MW-3 Antimony 6020B 2.1 B, J ug/L 0020393-03 MW-3 Barium 6020B 120 ug/L 0020393-03 MW-3 Cobalt 6020B 10 ug/L 0020393-03 MW-3 Nickel 6020B 3.5 ug/L 0020393-03 MW-3 1,4-Dichlorobenzene 8260D 2.3 ug/L 0020393-03 MW-3 Benzene 8260D 0.40 J ug/L 0020393-03 MW-3 Chlorobenzene 8260D 9.2 ug/L 0020393-03 MW-3 cis-1,2-Dichloroethylene 8260D 1.7 ug/L 0020393-03 MW-3 1,4-Dioxane 8260D SIM 1.6 J ug/L 0020393-04 MW-4 Antimony 6020B 2.0 B, J ug/L 0020393-04 MW-4 Barium 6020B 110 ug/L 0020393-04 MW-4 Nickel 6020B 0.89 J ug/L 0020393-04 MW-4 1,4-Dichlorobenzene 8260D 2.3 ug/L 0020393-04 MW-4 Chlorobenzene 8260D 8.4 ug/L 0020393-04 MW-4 Chloroethane 8260D 0.68 ug/L 0020393-04 MW-4 cis-1,2-Dichloroethylene 8260D 1.1 ug/L 0020393-04 MW-4 1,4-Dioxane 8260D SIM 2.8 ug/L 0020393-05 SW-1 Antimony 6020B 2.0 B, J ug/L 0020393-05 SW-1 Barium 6020B 260 ug/L 0020393-05 SW-1 Cobalt 6020B 3.9 ug/L 0020393-05 SW-1 Copper 6020B 5.1 J ug/L 0020393-05 SW-1 Lead 6020B 2.0 ug/L 0020393-05 SW-1 Nickel 6020B 4.3 ug/L 0020393-05 SW-1 Zinc 6020B 20 ug/L 0020393-05 SW-1 1,4-Dichlorobenzene 8260D 0.77 ug/L 0020393-05 SW-1 Acetone 8260D 1.9 CCVL, ug/L J 0020393-05 SW-1 Chlorobenzene 8260D 2.8 ug/L 0020393-05 SW-1 1,4-Dioxane 8260D SIM 2.1 ug/L 0020393-06 SW-2 Antimony 6020B 2.0 B, J ug/L 0020393-06 SW-2 Barium 6020B 130 ug/L 0020393-06 SW-2 Cobalt 6020E 3.3 ug/L 0020393-06 SW-2 Nickel 6020B 1.2 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 1 0 Waypoint ANALYTICAL Summary of Detections 03/04/202C Work Order: 0020393 Prism ID Client ID Parameter Method Result Units 0020393-06 SW-2 Zinc 6020B 14 J ug/L 0020393-06 SW-2 1,4-Dichlorobenzene 8260D 0.51 ug/L 0020393-06 SW-2 Chlorobenzene 8260D 1.5 ug/L 0020393-06 SW-2 1,4-Dioxane 8260D SIM 1.8 J ug/L 0020393-07 EB-1 Antimony 6020B 2.1 B, J ug/L 0020393-07 EB-1 Barium 6020B 8.7 J ug/L 0020393-07 EB-1 Nickel 6020B 1.3 J ug/L 0020393-08 FD-1 Antimony 6020B 2.1 B, J ug/L 0020393-08 FD-1 Barium 6020B 120 ug/L 0020393-08 FD-1 Cobalt 6020B 10 ug/L 0020393-08 FD-1 Nickel 6020B 3.7 ug/L 0020393-08 FD-1 1,4-Dichlorobenzene 8260D 2.2 ug/L 0020393-08 FD-1 Benzene 8260D 0.45 J ug/L 0020393-08 FD-1 Chlorobenzene 8260D 9.3 ug/L 0020393-08 FD-1 cis-1,2-Dichloroethylene 8260D 1.6 ug/L 0020393-08 FD-1 1,4-Dioxane 8260D SIM 1.7 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report it AL a • . 0 03/04/2020 - ._ ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-1 Attn: Rodney Clark Sample ID: 0020393-01 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 11:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.3 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 17:11 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 17:11 MMR POB0440 Barium 36 ug/L 100 9.9 3.1 1 6020B 2/28/20 17:11 MMR POB0440 Beryllium <0.29 ug/L 1 0.99 0.29 1 6020B 2/28/20 17:11 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 17:11 MMR POB0440 Chromium 1.1 J ug/L 10 3.0 0.90 1 6020B 2/28/20 17:11 MMR POB0440 Cobalt <0.69 ug/L 10 2.0 0.69 1 6020B 2/28/20 17:11 MMR POB0440 Copper 4.7 J ug/L 10 9.9 4.6 1 6020B 2/28/20 17:11 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 17:11 MMR POB0440 Nickel 1.5 J ug/L 50 3.0 0.82 1 6020B 2/28/20 17:11 MMR POB0440 Selenium <0.97 ug/L 10 5.0 0.97 1 6020B 2/28/20 17:11 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 17:11 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 17:11 MMR POB0440 Vanadium <1.4 ug/L 25 5.0 1.4 1 6020B 2/28/20 17:11 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 17:11 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 19:18 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:18 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 19:18 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 19:18 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 19:18 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 19:18 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 19:18 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 19:18 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 19:18 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 19:18 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 19:18 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:18 JLB P000013 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 19:18 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 19:18 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 19:18 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 19:18 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 19:18 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:18 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 19:18 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 19:18 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-1 Attn: Rodney Clark Sample ID: 0020393-01 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 11:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 19:18 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 19:18 JLB P000013 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 19:18 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 19:18 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 19:18 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:18 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 19:18 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 19:18 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 19:18 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 19:18 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:18 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 19:18 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 19:18 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 19:18 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 19:18 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 19:18 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 19:18 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 19:18 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 19:18 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:18 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 19:18 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 19:18 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 19:18 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 19:18 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 19:18 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 19:18 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 19:18 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 19:18 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 19:18 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 15:07 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-2 Attn: Rodney Clark Sample ID: 0020393-02 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 13:30 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.1 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 17:31 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 17:31 MMR POB0440 Barium 87 ug/L 100 9.9 3.1 1 6020B 2/28/20 17:31 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 17:31 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 17:31 MMR POB0440 Chromium 1.3 J ug/L 10 3.0 0.89 1 6020B 2/28/20 17:31 MMR POB0440 Cobalt <0.69 ug/L 10 2.0 0.69 1 6020B 2/28/20 17:31 MMR POB0440 Copper <4.6 ug/L 10 9.9 4.6 1 6020B 2/28/20 17:31 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 17:31 MMR POB0440 Nickel 1.5 J ug/L 50 3.0 0.82 1 6020B 2/28/20 17:31 MMR POB0440 Selenium <0.97 ug/L 10 4.9 0.97 1 6020B 2/28/20 17:31 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 17:31 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 17:31 MMR POB0440 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 2/28/20 17:31 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 17:31 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 19:52 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:52 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 19:52 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 19:52 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 19:52 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 19:52 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 19:52 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 19:52 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 19:52 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 19:52 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 19:52 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:52 JLB P000013 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 19:52 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 19:52 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 19:52 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 19:52 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 19:52 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:52 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 19:52 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 19:52 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-2 Attn: Rodney Clark Sample ID: 0020393-02 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 13:30 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 19:52 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 19:52 JLB P000013 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 19:52 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 19:52 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 19:52 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 19:52 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 19:52 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 19:52 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 19:52 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 19:52 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:52 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 19:52 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 19:52 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 19:52 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 19:52 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 19:52 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 19:52 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 19:52 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 19:52 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 19:52 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 19:52 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 19:52 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 19:52 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 19:52 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 19:52 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 19:52 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 19:52 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 19:52 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 19:52 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 107 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 15:32 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-3 Attn: Rodney Clark Sample ID: 0020393-03 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 14:45 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.1 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 17:38 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 17:38 MMR POB0440 Barium 120 ug/L 100 9.9 3.1 1 6020B 2/28/20 17:38 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 17:38 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 17:38 MMR POB0440 Chromium <0,89 ug/L 10 3.0 0.89 1 6020B 2/28/20 17:38 MMR POB0440 Cobalt 10 ug/L 10 2.0 0.69 1 6020B 2/28/20 17:38 MMR POB0440 Copper <4.6 ug/L 10 9.9 4.6 1 6020B 2/28/20 17:38 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 17:38 MMR POB0440 Nickel 3.5 ug/L 50 3.0 0.82 1 6020B 2/28/20 17:38 MMR POB0440 Selenium <0.97 ug/L 10 4.9 0.97 1 6020B 2/28/20 17:38 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 17:38 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 17:38 MMR POB0440 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 2/28/20 17:38 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 17:38 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 20:26 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 20:26 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 20:26 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 20:26 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 20:26 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 20:26 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 20:26 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 20:26 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 20:26 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 20:26 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 20:26 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 20:26 JLB P000013 1,4-Dichlorobenzene 2.3 ug/L 1 0.50 0.42 1 8260D 2/28/20 20:26 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 20:26 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 20:26 JLB P000013 Benzene 0.40 J ug/L 1 0.50 0.34 1 8260D 2/28/20 20:26 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 20:26 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 20:26 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 20:26 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 20:26 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report ■ A ff _ - • - ■ 0 03/04/2020 - - ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-3 Attn: Rodney Clark Sample ID: 0020393-03 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 14:45 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 20:26 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 20:26 JLB P000013 Chlorobenzene 9.2 ug/L 3 0.50 0.34 1 8260D 2/28/20 20:26 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 20:26 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 20:26 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 20:26 JLB P000013 cis-1,2-Dichloroethylene 1.7 ug/L 5 0.50 0.40 1 8260D 2/28/20 20:26 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 20:26 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 20:26 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 20:26 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 20:26 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 20:26 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 20:26 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 20:26 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 20:26 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 20:26 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 20:26 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 20:26 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 20:26 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 20:26 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 20:26 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 20:26 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 20:26 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 20:26 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 20:26 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 20:26 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 20:26 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 20:26 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 20:26 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 1.6 J ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 16:48 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-4 Attn: Rodney Clark Sample ID: 0020393-04 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 16:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.0 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 17:44 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 17:44 MMR POB0440 Barium 110 ug/L 100 9.9 3.1 1 6020B 2/28/20 17:44 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 17:44 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 17:44 MMR POB0440 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 2/28/20 17:44 MMR POB0440 Cobalt <0.69 ug/L 10 2.0 0.69 1 6020B 2/28/20 17:44 MMR POB0440 Copper <4.6 ug/L 10 9.9 4.6 1 6020B 2/28/20 17:44 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 17:44 MMR POB0440 Nickel 0.89 J ug/L 50 3.0 0.82 1 6020B 2/28/20 17:44 MMR POB0440 Selenium <0.97 ug/L 10 5.0 0.97 1 6020B 2/28/20 17:44 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 17:44 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 17:44 MMR POB0440 Vanadium <1.4 ug/L 25 5.0 1.4 1 6020B 2/28/20 17:44 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 17:44 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 21:00 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:00 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 21:00 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 21:00 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 21:00 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 21:00 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 21:00 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 21:00 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 21:00 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 21:00 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 21:00 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:00 JLB P000013 1,4-Dichlorobenzene 2.3 ug/L 1 0.50 0.42 1 8260D 2/28/20 21:00 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 21:00 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 21:00 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 21:00 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 21:00 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:00 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 21:00 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 21:00 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-4 Attn: Rodney Clark Sample ID: 0020393-04 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 16:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 21:00 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 21:00 JLB P000013 Chlorobenzene 8.4 ug/L 3 0.50 0.34 1 8260D 2/28/20 21:00 JLB P000013 Chloroethane 0.68 ug/L 10 0.50 0.43 1 8260D 2/28/20 21:00 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 21:00 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:00 JLB P000013 cis-1,2-Dichloroethylene 1.1 ug/L 5 0.50 0.40 1 8260D 2/28/20 21:00 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 21:00 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 21:00 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 21:00 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:00 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 21:00 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 21:00 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 21:00 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 21:00 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 21:00 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 21:00 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 21:00 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 21:00 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:00 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 21:00 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 21:00 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 21:00 JLB P000013 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 21:00 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 21:00 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 21:00 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 21:00 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 21:00 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 21:00 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 98 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 2.8 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 17:38 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: SW-1 Attn: Rodney Clark Sample ID: 0020393-05 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 12:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.0 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 18:04 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 18:04 MMR POB0440 Barium 260 ug/L 100 9.9 3.1 1 6020B 2/28/20 18:04 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 18:04 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 18:04 MMR POB0440 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 2/28/20 18:04 MMR POB0440 Cobalt 3.9 ug/L 10 2.0 0.69 1 6020B 2/28/20 18:04 MMR POB0440 Copper 5.1 J ug/L 10 9.9 4.6 1 6020B 2128/20 18:04 MMR POB0440 Lead 2.0 ug/L 10 0.99 0.44 1 6020B 2/28/20 18:04 MMR POB0440 Nickel 4.3 ug/L 50 3.0 0.82 1 6020B 2/28/20 18:04 MMR POB0440 Selenium <0.97 ug/L 10 5.0 0.97 1 6020B 2/28/20 18:04 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 18:04 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 18:04 MMR POB0440 Vanadium <1.4 ug/L 25 5.0 1.4 1 6020B 2/28/20 18:04 MMR POB0440 Zinc 20 ug/L 10 20 10 1 6020B 2/28/20 18:04 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 21:34 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:34 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 21:34 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 21:34 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 21:34 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 21:34 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 21:34 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 21:34 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 21:34 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 21:34 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 21:34 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:34 JLB P000013 1,4-Dichlorobenzene 0.77 ug/L 1 0.50 0.42 1 8260D 2/28/20 21:34 JLB P000013 Acetone 1.9 CC ug/L 100 5.0 0.70 1 8260D 2/28/20 21:34 JLB P000013 VL, J Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 21:34 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 21:34 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 21:34 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:34 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 21:34 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report ■ A ff _ - • - ■ 0 03/04/2020 - - ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: SW-1 Attn: Rodney Clark Sample ID: 0020393-05 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 12:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 21:34 JLB P000013 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 21:34 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 21:34 JLB P000013 Chlorobenzene 2.8 ug/L 3 0.50 0.34 1 8260D 2/28/20 21:34 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 21:34 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 21:34 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 21:34 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 21:34 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 21:34 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 21:34 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 21:34 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:34 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 21:34 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 21:34 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 21:34 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 21:34 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 21:34 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 21:34 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 21:34 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 21:34 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 21:34 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 21:34 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 21:34 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 21:34 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 21:34 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 21:34 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 21:34 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 21:34 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 21:34 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 21:34 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 96 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 2.1 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 15:57 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: SW-2 Attn: Rodney Clark Sample ID: 0020393-06 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 15:30 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.0 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 18:11 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 18:11 MMR POB0440 Barium 130 ug/L 100 9.9 3.1 1 6020B 2/28/20 18:11 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 18:11 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 18:11 MMR POB0440 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 2/28/20 18:11 MMR POB0440 Cobalt 3.3 ug/L 10 2.0 0.69 1 6020B 2/28/20 18:11 MMR POB0440 Copper <4.6 ug/L 10 9.9 4.6 1 6020B 2/28/20 18:11 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 18:11 MMR POB0440 Nickel 1.2 J ug/L 50 3.0 0.82 1 6020B 2/28/20 18:11 MMR POB0440 Selenium <0.97 ug/L 10 5.0 0.97 1 6020B 2/28/20 18:11 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 18:11 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 18:11 MMR POB0440 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 2/28/20 18:11 MMR POB0440 Zinc 14 J ug/L 10 20 10 1 6020B 2/28/20 18:11 MMR POB0440 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 22:08 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 22:08 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 22:08 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 22:08 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 22:08 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 22:08 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 22:08 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 22:08 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 22:08 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 22:08 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 22:08 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 22:08 JLB P000013 1,4-Dichlorobenzene 0.51 ug/L 1 0.50 0.42 1 8260D 2/28/20 22:08 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 22:08 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 22:08 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 22:08 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 22:08 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 22:08 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 22:08 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 22:08 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report ■ A ff _ - • - ■ 0 03/04/2020 - - ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: SW-2 Attn: Rodney Clark Sample ID: 0020393-06 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 15:30 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 22:08 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 22:08 JLB P000013 Chlorobenzene 1.5 ug/L 3 0.50 0.34 1 8260D 2/28/20 22:08 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 22:08 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 22:08 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 22:08 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 22:08 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 22:08 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 22:08 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 22:08 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 22:08 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 22:08 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 22:08 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 22:08 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 22:08 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 22:08 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 22:08 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 22:08 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 22:08 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 22:08 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 22:08 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 22:08 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 22:08 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 22:08 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 22:08 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 22:08 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 22:08 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 22:08 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 22:08 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 94 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 1.8 J ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 16:22 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: EB-1 Attn: Rodney Clark Sample ID: 0020393-07 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 15:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.1 B, J ug/L 6 2.9 0.91 1 6020B 2/28/20 18:17 MMR POB0440 Arsenic <0.82 ug/L 10 2.9 0.82 1 6020B 2/28/20 18:17 MMR POB0440 Barium 8.7 J ug/L 100 9.8 3.1 1 6020B 2/28/20 18:17 MMR POB0440 Beryllium <0.29 ug/L 1 0.98 0.29 1 6020B 2/28/20 18:17 MMR POB0440 Cadmium <0.62 ug/L 1 2.0 0.62 1 6020B 2/28/20 18:17 MMR POB0440 Chromium <0.89 ug/L 10 2.9 0.89 1 6020B 2/28/20 18:17 MMR POB0440 Cobalt <0.68 ug/L 10 2.0 0.68 1 6020B 2/28/20 18:17 MMR POB0440 Copper <4.6 ug/L 10 9.8 4.6 1 6020B 2/28/20 18:17 MMR POB0440 Lead <0.43 ug/L 10 0.98 0.43 1 6020B 2/28/20 18:17 MMR POB0440 Nickel 1.3 J ug/L 50 2.9 0.81 1 6020B 2/28/20 18:17 MMR POB0440 Selenium <0.96 ug/L 10 4.9 0.96 1 6020B 2/28/20 18:17 MMR POB0440 Silver <0.33 ug/L 10 0.98 0.33 1 6020B 2/28/20 18:17 MMR POB0440 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 2/28/20 18:17 MMR POB0440 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 2/28/20 18:17 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 18:17 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 17:02 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:02 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 17:02 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 17:02 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 17:02 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 17:02 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 17:02 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 17:02 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 17:02 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 17:02 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 17:02 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:02 JLB P000013 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 17:02 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 17:02 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 17:02 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 17:02 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 17:02 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:02 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 17:02 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 17:02 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 � Laboratory Report Way• nt 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: EB-1 Attn: Rodney Clark Sample ID: 0020393-07 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 15:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 17:02 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 17:02 JLB P000013 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 17:02 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 17:02 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 17:02 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:02 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 17:02 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 17:02 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 17:02 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 17:02 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:02 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 17:02 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 17:02 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 17:02 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 17:02 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 17:02 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 17:02 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 17:02 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 17:02 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:02 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 17:02 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 17:02 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 17:02 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 17:02 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 17:02 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 17:02 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 17:02 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 17:02 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 17:02 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 14:42 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: FD-1 Attn: Rodney Clark Sample ID: 0020393-08 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 00:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony 2.1 B, J ug/L 6 3.0 0.92 1 6020B 2/28/20 18:24 MMR POB0440 Arsenic <0.83 ug/L 10 3.0 0.83 1 6020B 2/28/20 18:24 MMR POB0440 Barium 120 ug/L 100 9.9 3.1 1 6020B 2/28/20 18:24 MMR POB0440 Beryllium <0,29 ug/L 1 0.99 0.29 1 6020B 2/28/20 18:24 MMR POB0440 Cadmium <0.63 ug/L 1 2.0 0.63 1 6020B 2/28/20 18:24 MMR POB0440 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 2/28/20 18:24 MMR POB0440 Cobalt 10 ug/L 10 2.0 0.69 1 6020B 2/28/20 18:24 MMR POB0440 Copper <4.6 ug/L 10 9.9 4.6 1 6020B 2/28/20 18:24 MMR POB0440 Lead <0.44 ug/L 10 0.99 0.44 1 6020B 2/28/20 18:24 MMR POB0440 Nickel 3.7 ug/L 50 3.0 0.82 1 6020B 2/28/20 18:24 MMR POB0440 Selenium <0.97 ug/L 10 5.0 0.97 1 6020B 2/28/20 18:24 MMR POB0440 Silver <0.33 ug/L 10 0.99 0.33 1 6020B 2/28/20 18:24 MMR POB0440 Thallium <0.83 ug/L 5.5 2.0 0.83 1 6020B 2/28/20 18:24 MMR POB0440 Vanadium <1.4 ug/L 25 5.0 1.4 1 6020B 2/28/20 18:24 MMR POB0440 Zinc <10 ug/L 10 20 10 1 6020B 2/28/20 18:24 MMR POB0440 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 17:36 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:36 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 17:36 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 17:36 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 17:36 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 17:36 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 17:36 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 17:36 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 17:36 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 17:36 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 17:36 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:36 JLB P000013 1,4-Dichlorobenzene 2.2 ug/L 1 0.50 0.42 1 8260D 2/28/20 17:36 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 17:36 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 17:36 JLB P000013 Benzene 0.45 J ug/L 1 0.50 0.34 1 8260D 2/28/20 17:36 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 17:36 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:36 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 17:36 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 17:36 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report ■ A ff _ - • - ■ 0 03/04/2020 - - ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: FD-1 Attn: Rodney Clark Sample ID: 0020393-08 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 00:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 17:36 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 17:36 JLB P000013 Chlorobenzene 9.3 ug/L 3 0.50 0.34 1 8260D 2/28/20 17:36 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 17:36 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 17:36 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 17:36 JLB P000013 cis-1,2-Dichloroethylene 1.6 ug/L 5 0.50 0.40 1 8260D 2/28/20 17:36 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 17:36 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 17:36 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 17:36 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:36 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 17:36 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 17:36 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 17:36 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 17:36 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 17:36 JLB P000013 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 17:36 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 17:36 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 17:36 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 17:36 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 17:36 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 17:36 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 17:36 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 17:36 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 17:36 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 17:36 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 17:36 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 17:36 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 17:36 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 1.7 J ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 17:13 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Laboratory Report Way• nt � 03/04/2020 poi ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: TB-1 Attn: Rodney Clark Sample ID: 0020393-09 1308 Patton Avenue (Suite C) Project No.: 50-01 Work Order: 0020393 Asheville, NC 28806 Sample Matrix: Water Time Collected: 02/25/20 00:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 16:28 JLB P000013 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 16:28 JLB P000013 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 16:28 JLB P000013 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 16:28 JLB P000013 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 2/28/20 16:28 JLB P000013 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 2/28/20 16:28 JLB P000013 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 2/28/20 16:28 JLB P000013 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 2/28/20 16:28 JLB P000013 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 2/28/20 16:28 JLB P000013 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 2/28/20 16:28 JLB P000013 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 16:28 JLB P000013 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 16:28 JLB P000013 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 2/28/20 16:28 JLB P000013 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 2/28/20 16:28 JLB P000013 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 2/28/20 16:28 JLB P000013 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 2/28/20 16:28 JLB P000013 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 2/28/20 16:28 JLB P000013 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 16:28 JLB P000013 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 2/28/20 16:28 JLB P000013 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 2/28/20 16:28 JLB P000013 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 2/28/20 16:28 JLB P000013 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 2/28/20 16:28 JLB P000013 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 2/28/20 16:28 JLB P000013 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 2/28/20 16:28 JLB P000013 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 2/28/20 16:28 JLB P000013 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 2/28/20 16:28 JLB P000013 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 2/28/20 16:28 JLB P000013 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 2/28/20 16:28 JLB P000013 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 2/28/20 16:28 JLB P000013 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 2/28/20 16:28 JLB P000013 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 16:28 JLB P000013 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 2/28/20 16:28 JLB P000013 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 2/28/20 16:28 JLB P000013 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 2/28/20 16:28 JLB P000013 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 2/28/20 16:28 JLB P000013 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 2/28/20 16:28 JLB P000013 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Waypoint ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Laboratory Report 03/04/2020 Client Sample ID: TB-1 Sample ID: 0020393-09 Work Order: 0020393 Time Collected: 02/25/20 00:00 Time Submitted: 02/26/20 13:30 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 2/28/20 16:28 JLB P000013 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 2/28/20 16:28 JLB P000013 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 2/28/20 16:28 JLB P000013 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 2/28/20 16:28 JLB P000013 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 2/28/20 16:28 JLB P000013 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 2/28/20 16:28 JLB P000013 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 2/28/20 16:28 JLB P000013 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 2/28/20 16:28 JLB P000013 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 2/28/20 16:28 JLB P000013 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 2/28/20 16:28 JLB P000013 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 2/28/20 16:28 JLB P000013 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 2/28/20 16:28 JLB P000013 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 2/28/20 16:28 JLB P000013 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 97 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 2/27/20 14:17 TBL POB0427 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 ■ Way po�nt ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P000013 - 5030B Blank (P000013-BLK1) Prepared &Analyzed: 02/28/20 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 2.0 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 2.0 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 2.0 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, INC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Waypor iInt ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P000013 - 5030B Reporting Result Limit Units Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P000013-BLK1) Prepared & Analyzed: 02/28/20 Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 49.8 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 52.4 ug/L 50.00 105 75-129 Surrogate: Toluene-d8 48.2 ug/L 50.00 96 77-123 LCS (P000013-BS1) Prepared &Analyzed: 02/28/20 1,1-Dichloroethylene 21.3 0.50 ug/L 20.00 106 70-154 Benzene 21.0 0.50 ug/L 20.00 105 77-128 Chlorobenzene 20.3 0.50 ug/L 20.00 102 78-119 Toluene 21.5 0.50 ug/L 20.00 108 76-131 Trichloroethylene 20.2 0.50 ug/L 20.00 101 77-133 Surrogate:4-Bromofluorobenzene 49.6 ug/L 50.00 99 80-124 Surrogate: Dibromofluoromethane 50.6 ug/L 50.00 101 75-129 Surrogate: Toluene-d8 48.3 ug/L 50.00 97 77-123 Matrix Spike (P000013-MS1) Source: 0020393-02 Prepared: 02/28/20 Analyzed: 02/29/20 1,1-Dichloroethylene 229 5.0 ug/L 200.0 BRL 114 65-162 Benzene 219 5.0 ug/L 200.0 BRL 110 73-131 Chlorobenzene 208 5.0 ug/L 200.0 BRL 104 76-119 Toluene 222 5.0 ug/L 200.0 BRL ill 72-135 Trichloroethylene 211 5.0 ug/L 200.0 BRL 105 72-133 Surrogate:4-Bromofluorobenzene 50.1 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 49.3 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 48.2 ug/L 50.00 96 77-123 Matrix Spike Dup (P000013-MSD1) Source: 0020393-02 Prepared: 02/28/20 Analyzed: 02/29/20 1,1-Dichloroethylene 219 5.0 ug/L 200.0 BRL 110 65-162 4 20 Benzene 216 5.0 ug/L 200.0 BRL 108 73-131 2 17 Chlorobenzene 209 5.0 ug/L 200.0 BRL 105 76-119 0.7 20 Toluene 220 5.0 ug/L 200.0 BRL 110 72-135 0.9 18 Trichloroethylene 205 5.0 ug/L 200.0 BRL 102 72-133 3 17 Surrogate:4-Bromofluorobenzene 47.7 ug/L 50.00 95 80-124 Surrogate: Dibromofluoromethane 50.0 ug/L 50.00 100 75-129 Surrogate: Toluene-d8 47.3 ug/L 50.00 95 77-123 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 ■ Way point ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Analyte Result Limit Units Batch POB0427 - 5030B Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (POB0427-BLK1) Prepared &Analyzed: 02/27/20 1,4-Dioxane BRL 2.0 ug/L LCS (POB0427-BS1) Prepared &Analyzed: 02/27/20 1,4-Dioxane 49.5 2.0 ug/L 50.00 99 55-145 Matrix Spike (POB0427-MS1) Source: 0020393-01 Prepared & Analyzed: 02/27/20 1,4-Dioxane 49.1 2.0 ug/L 50.00 BRL 98 55-145 Matrix Spike Dup (POB0427-MSD1) Source: 0020393-01 Prepared & Analyzed: 02/27/20 1,4-Dioxane 48.8 2.0 ug/L 50.00 BRL 98 55-145 0.7 30 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 ■ Way point ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Analyte Batch POB0440 - SM3030 C Reporting Result Limit Units Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (POB0440-BLK1) Prepared: 02/27/20 Analyzed: 02/28/20 Antimony 1.93 3.0 ug/L BL, J Arsenic BRL 3.0 ug/L Barium BRL 9.9 ug/L Beryllium BRL 0.99 ug/L Cadmium BRL 2.0 ug/L Chromium BRL 3.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 9.9 ug/L Lead BRL 0.99 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 0.99 ug/L Thallium BRL 2.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (POB0440-BSI) Prepared: 02/27/20 Analyzed: 02/28/20 Antimony 96.5 3.0 ug/L 100.0 96 80-120 B Arsenic 96.5 3.0 ug/L 100.0 97 80-120 Barium 99.9 10 ug/L 100.0 100 80-120 Beryllium 92.2 1.0 ug/L 100.0 92 80-120 Cadmium 99.7 2.0 ug/L 100.0 100 80-120 Chromium 98.1 3.0 ug/L 100.0 98 80-120 Cobalt 98.2 2.0 ug/L 100.0 98 80-120 Copper 99.2 10 ug/L 100.0 99 80-120 Lead 97.8 1.0 ug/L 100.0 98 80-120 Nickel 97.6 3.0 ug/L 100.0 98 80-120 Selenium 99.6 5.0 ug/L 100.0 100 80-120 Silver 100 1.0 ug/L 100.0 100 80-120 Thallium 88.6 2.0 ug/L 100.0 89 80-120 Vanadium 98.4 5.0 ug/L 100.0 98 80-120 Zinc 108 20 ug/L 100.0 108 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 ■ Way point ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POB0440 - SM3030 C Matrix Spike (POB0440-MS1) Source: 0020393-01 Prepared: 02/27/20 Analyzed: 02/28/20 Antimony 98.5 3.1 ug/L 100.0 2.29 96 75-125 B Arsenic 97.2 3.1 ug/L 100.0 BRL 97 75-125 Barium 137 10 ug/L 100.0 35.5 101 75-125 Beryllium 93.5 1.0 ug/L 100.0 BRL 94 75-125 Cadmium 102 2.0 ug/L 100.0 BRL 102 75-125 Chromium 101 3.1 ug/L 100.0 1.10 100 75-125 Cobalt 101 2.0 ug/L 100.0 BRL 101 75-125 Copper 106 10 ug/L 100.0 BRL 106 75-125 Lead 97.6 1.0 ug/L 100.0 BRL 98 75-125 Nickel 101 3.1 ug/L 100.0 1.53 100 75-125 Selenium 98.7 5.1 ug/L 100.0 BRL 99 75-125 Silver 101 1.0 ug/L 100.0 BRL 101 75-125 Thallium 89.0 2.0 ug/L 100.0 BRL 89 75-125 Vanadium 99.6 5.1 ug/L 100.0 BRL 100 75-125 Zinc 107 20 ug/L 100.0 BRL 107 75-125 Matrix Spike Dup (POB0440-MSD1) Source: 0020393-01 Prepared: 02/27/20 Analyzed: 02/28/20 Antimony 98.4 3.0 ug/L 100.0 2.29 96 75-125 0.09 20 B Arsenic 95.7 3.0 ug/L 100.0 BRL 96 75-125 2 20 Barium 134 10 ug/L 100.0 35.5 98 75-125 2 20 Beryllium 95.9 1.0 ug/L 100.0 BRL 96 75-125 3 20 Cadmium 101 2.0 ug/L 100.0 BRL 101 75-125 0.9 20 Chromium 99.7 3.0 ug/L 100.0 1.10 99 75-125 2 20 Cobalt 99.9 2.0 ug/L 100.0 BRL 100 75-125 0.8 20 Copper 104 10 ug/L 100.0 BRL 104 75-125 1 20 Lead 97.1 1.0 ug/L 100.0 BRL 97 75-125 0.5 20 Nickel 99.5 3.0 ug/L 100.0 1.53 98 75-125 2 20 Selenium 100 5.0 ug/L 100.0 BRL 100 75-125 2 20 Silver 101 1.0 ug/L 100.0 BRL 101 75-125 0.2 20 Thallium 87.9 2.0 ug/L 100.0 BRL 88 75-125 1 20 Vanadium 99.1 5.0 ug/L 100.0 BRL 99 75-125 0.6 20 Zinc 106 20 ug/L 100.0 BRL 106 75-125 1 20 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 ■ Way point ANALYTICAL Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Rodney Clark 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Level II QC Report 3/4/20 Work Order: 0020393 Time Submitted: 2/26/2020 1:30:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch POB0440 - SM3030 C Post Spike (POB0440-PS1) Source: 0020393-01 Prepared: 02/27/20 Analyzed: 02/28/20 Antimony 100 ug/L 100.0 2.29 98 80-120 B Arsenic 97.0 ug/L 100.0 -0.0129 97 80-120 Barium 130 ug/L 100.0 35.5 95 80-120 Beryllium 97.8 ug/L 100.0 0.0198 98 80-120 Cadmium 101 ug/L 100.0 0.0297 101 80-120 Chromium 101 ug/L 100.0 1.10 100 80-120 Cobalt 99.9 ug/L 100.0 0.365 100 80-120 Copper 105 ug/L 100.0 4.69 100 80-120 Lead 98.7 ug/L 100.0 0.143 99 80-120 Nickel 100 ug/L 100.0 1.53 99 80-120 Selenium 103 ug/L 100.0 -0.227 103 80-120 Silver 101 ug/L 100.0 0.0218 101 80-120 Thallium 95.1 ug/L 100.0 0.135 95 80-120 Vanadium 99.2 ug/L 100.0 -0.176 99 80-120 Zinc 110 ug/L 100.0 5.20 104 80-120 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final Date/Time 0020393-01 POB0440 50 mL 49.52 mL 02/27/20 14:22 0020393-02 POB0440 50 mL 49.35 mL 02/27/20 14:22 0020393-03 POB0440 50 mL 49.36 mL 02/27/20 14:22 0020393-04 POB0440 50 mL 49.65 mL 02/27/20 14:22 0020393-05 POB0440 50 mL 49.55 mL 02/27/20 14:22 0020393-06 POB0440 50 mL 49.67 mL 02/27/20 14:22 0020393-07 POB0440 50 mL 48.99 mL 02/27/20 14:22 0020393-08 POB0440 50 mL 49.59 mL 02/27/20 14:22 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0020393-01 P000013 10 mL 10 mL 02/28/20 9:19 0020393-02 P000013 10 mL 10 mL 02/28/20 9:19 0020393-03 P000013 10 mL 10 mL 02/28/20 9:19 0020393-04 P000013 10 mL 10 mL 02/28/20 9:19 0020393-05 P000013 10 mL 10 mL 02/28/20 9:19 0020393-06 P000013 10 mL 10 mL 02/28/20 9:19 0020393-07 P000013 10 mL 10 mL 02/28/20 9:19 0020393-08 P000013 10 mL 10 mL 02/28/20 9:19 0020393-09 P000013 10 mL 10 mL 02/28/20 9:19 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 0020393-01 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-02 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-03 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-04 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-05 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-06 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-07 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-08 POB0427 5 mL 5 mL 02/27/20 11:26 0020393-09 POB0427 5 mL 5 mL 02/27/20 11:26 This report should not be reproduced, except in its entirety, without the written consent of Waypoint Analytical. 449 Springbrook Road - P.O. 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