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HomeMy WebLinkAbout3901_Granville_Oxford_Unit2_MSWLF_GW_FID1378348_20191202UDENR USE ONLY_�ftI ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event # NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646, Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Joyce Engineering, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@joyceengineering.com NC Landfill Rule: Actual sampling dates (e.g., Facility name Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Oxford Landfill Unit 2 6584 Landfill Rd. 3901- .1600 August 7-8, 2019; Oxford, NC 27565 MSWLF-2012 September 4, 2019 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells 1-1Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? BX No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 28 surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., PG Technical Consultant (336) 323-0092 a Code) Telephone Number 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal %, GCARO'���"1� SEAL 1349 = G G'FOLOG� %yAtESS � .••, Prepared For: Granville County Solid Waste Department P.O. Box go6 Oxford, North Carolina 27565 r'o11�t� �F C* A Mi 774 •' �ry''ATH . h ....CAR�.a....+.+. Submitted by: LaBella Associates (Joyce Engineering) 2211 West Meadow/view Rd. Suite 101 Greensboro, NC 27407 (336) 323-oog2 NC License No. C-0782 LaBeRa Powered by partnership. August 2019 SEMIANNUAL WATER QUALITY MONITORING REPORT OXFORD UNIT 2 LANDFILL Permit NO.3901 MSWLF 2012 NOVEMBER 2019 PROJECT NO. 21923S2.01.06 August 2019 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill Granville County, North Carolina TABLE OF CONTENTS ACRONYMS.............................................................................................................................................. III 1.0 INTRODUCTION .................................................................................................................................1 1.1 Site Background..........................................................................................................1 1.2 Site Conceptual Model................................................................................................1 1.2.1 Site Geology.............................................................................................................1 1.2.2 Site Hydrogeology....................................................................................................1 2.0 FACILITY MONITORING PROGRAM...................................................................................................2 2.1 Regulatory Status........................................................................................................2 2.2 Monitoring Network....................................................................................................3 2.3 Groundwater Monitoring Program.............................................................................3 2.4 Surface Water Monitoring Program...........................................................................4 3.0 AUGUST 2019 SEMIANNUAL SAMPLING EVENT.............................................................................4 3.1 Field Work....................................................................................................................4 3.1.1 Resample................................................................................................................. 5 3.2 Laboratory Analysis and Quality Control.................................................................... 5 4.0 DATA ANALYSIS AND STATISTICAL RESULTS................................................................................... 5 4.1 Analytical Results Groundwater.................................................................................6 4.1.1 Inorganic Analyses...................................................................................................6 4.1.2 Organic Analyses...................................................................................................... 6 4.1.3 Analytical Results for Surface Water......................................................................6 4.1.4 Statistical Methods..................................................................................................6 5.0 CONCLUSION .................................................................................................................................... 7 6.0 REFERENCES.............................................................. August 2019 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 i ........................................................... 7 LaBella Associates November 2019 August 2019 Semiannual Water Quality Monitoring Report Oxford Unit 2 Landfill Granville County, North Carolina TABLE OF CONTENTS (Continued) Tables Table 1 August 2019 Groundwater Elevations Table 2 August 2019 Estimated Hydraulic Gradients and Velocities Table 3 August 2019 Field Parameters Table 4 August 2019 Detections of Groundwater and Surface Water Constituents Figure Figure 1 Site Location Map (USGS Topographic Map) Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendices Appendix A Well Construction Details Appendix B Laboratory Analytical Reports and Field Data Logs Appendix C Historical Data Tables Table A3-1 Historical Groundwater Elevations Table A3-2 Historical Groundwater Constituents Table A3-3 Historical Surface Water Constituents Table A3-4 Historical Groundwater Field Parameters Table A3-5 Historical Surface Water Field Parameters August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 ii ACRONYMS ACM Assessment of Corrective Measures (report) AOC Area of Concern ASD Alternate Source Demonstration (report) C&D Construction and Demolition Waste CAP Corrective Action Plan (report) CAER Corrective Action Evaluation Report (report) CPVC Chlorinated Poly Vinyl Chloride CO2 Carbon Dioxide COC Contaminant of Concern DCA Dichloroethane DCE Dichloroethylene DENR See NCDEQ DEQ See NCDENR DH Dissolved Hydrogen DL Detection Limit (for laboratory data) DO Dissolved Oxygen EPA United States Environmental Protection Agency Fee+ Ferrous Iron GEU Gas Extraction Unit GPS Groundwater Protection Standards per NCSWMR rule .1634.g.5. GWPS Groundwater Protection Standards set by the NCDEQ-SWS for constituents with no NC2L standard. HASP Site -specific Health and Safety Plan HDPE High -density Polyethylene JE Joyce Engineering JOYCE Joyce Engineering LFG Landfill Gas LEL Lower Explosive Limit MNA Monitored Natural Attenuation MSW Municipal Solid Waste MW Monitoring Well NC 2B North Carolina Surface Water Standards found in 15A NCAC 213.0101 NC 2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202 NCAC North Carolina Administrative Code NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ) NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR) NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600) ND Not Detected (for laboratory data) NES Nature and Extent Study (report) 0&M Operations and Maintenance ORP Oxidation -Reduction Potential OSHA Occupational Health and Safety Association PCE Perch loroethylene (aka - tetrachloroethylene, tetra chloroethene) PVC Poly Vinyl Chloride August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 iii QL Quantitation Limit (for laboratory data) QRA Quantitative Risk Assessment (report) RL Reporting Limit (for laboratory data) SC Specific Conductance SSI Statistically Significant Increase (over background concentration) SWQS Surface Water Quality Standards SWS NCDEQ (or NCDENR) Division of Waste Management, Solid Waste Section SWSL North Carolina Solid Waste Section Reporting Limits (for laboratory data) TCE Trichloroethylene (aka - trichloroethene) TDS Total Dissolved Solids TOC Total Organic Carbon TSS Total Suspended Solids VC Vinyl Chloride VFA Volatile Fatty Acid VOC Volatile Organic Compound WQMP Water Quality Monitoring Plan (report) August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 iv 1.0 INTRODUCTION On behalf of Granville County, LaBella Associate PC, (LaBella, formerly Joyce Engineering Inc.) has prepared this Water Quality Monitoring Report for the Oxford Unit 2 Municipal Solid Waste Landfill, Solid Waste Permit Number 3901-MSWLF-2012 (facility), in accordance with the North Carolina Solid Waste Management Rules (NCSWMR) 15A NCAC 13B.1632. 1.1 Site Background The Oxford Landfill is located at 6584 Landfill Road, Oxford, Granville County, North Carolina, near the town of Kinton Fork (Figure 1). The facility is owned and operated by Granville County under Permit Number 3901-MSWLF-2012, issued by the North Carolina Department of Environmental Quality (NCDEQ) Solid Waste Section (SWS). The Oxford Landfill consists of two separate waste disposal units. Unit 1 is a former unlined municipal solid waste (MSW) landfill originally permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes, with a C&D landfill on top. Unit 2 is a Subtitle-D MSW landfill. Granville County received the Unit 2 Permit to Operate from the NCDEQ on February 19, 2013. The County began placing waste in Unit 2 on May 1, 2013. This report presents the results of the sampling conducted in Unit 2. 1.2 Site Conceptual Model 1.2.1 Site Geology The Oxford Landfill is located in the Carolina Slate Belt of the Piedmont Physiographic Province of North Carolina. The geologic province is characterized by rolling topography with a thick mantle of saprolite overlying late -Proterozoic and Paleozoic igneous and metamorphic bedrock. The Carolina Slate Belt is comprised of 550 to 650 million year old, metamorphosed sedimentary and volcanic rocks, intruded by granitic rocks. The Oxford Landfill is underlain by the Flat River Complex, a shallow intrusive complex of granitic composition, which comprises a large portion of the northern Carolina Slate Belt (Butler, 1991). The landfill is approximately 18 miles east of the Virgilina Synclinorium, approximately 10 miles west of the Nutbush Creek Fault Zone, and approximately 4 miles northwest of the Durham Basin (Butler, 1991). Previous investigations discovered limited exposures of competent, massive, gray to greenish gray meta -volcanic rock that is moderately fractured. Prominent fractures with near vertical dips and strike approximately N-20o- E (JOYCE, 2009b). Boring logs indicate that the depth to bedrock at Oxford Landfill ranges from 3 to 35 feet below ground surface. The overlying saprolite consists of brownish sandy to clayey silt (JOYCE, 2009b). 1.2.2 Site Hydrogeolo Groundwater in the Piedmont can occur in substantial volumes where the soil is thick, but groundwater is typically found in minimal volumes in bedrock, primarily restricted to fractures. Based on groundwater depth measurement, the water table under the area landfill was encountered in the unconfined aquifer that is mostly in the transition zone that consists of saprolite and highly fractured bedrock. This unconfined aquifer is pervasive across the site. The saturated portion of the uppermost aquifer beneath the landfill is vertically continuous to bedrock, and no confining layers have been encountered during permitting. There is a high degree of connectivity between the August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 1 saprolite and underlying fractured bedrock such that they behave as a single continuous aquifer. Groundwater elevations in Table 1 show that the depth to water ranged from 3 to 25 feet below grade in wells MW-7, MW-8, MW-9, MW-10, MW-11, and NES-2S. In general, the water table is near the saprolite/bedrock interface. Drawing 1 presents a groundwater potentiometric surface map based on static water level data obtained from both Unit 1 and Unit 2 monitoring wells on August 7- 8, 2019. As depicted in Drawing 1, the groundwater flows generally to the north beneath Unit 2. Depth to groundwater is measured in all compliance monitoring wells at the site prior to each sampling event. The groundwater elevations calculated relative to the surveyed measuring point (top of casing) for each monitoring well are summarized in Table 1. The groundwater elevation contours shown in Drawing 1 are based on data from the August 2019 semiannual sampling event. Groundwater flow beneath the Unit 2 Landfill is primarily to the north. Horizontal groundwater gradients were estimated from the August 2019 groundwater levels and are summarized in Tabie 2. Horizontal gradients (i) across the site ranged from 0.0187 to 0.0248 with an average of 0.0217. These values are consistent with previous estimates. Linear groundwater flow velocities for wells screened in saprolite were computed using the following modified Darcy equation: where: V = K1/ne , V = average linear velocity (feet/year), K = hydraulic conductivity (feet/day), i = horizontal hydraulic gradient, and ne = effective porosity. Under Unit 2, the water table is mostly below top of bedrock so flow is primarily in fractured bedrock; therefore, the hydraulic conductivity (K = 4.43 ft/day) was based on the geometric mean of values from slug tests conducted on bedrock wells at the facility in 2009 and the effective porosity (ne) value for fractured bedrock was estimated at 15%. Calculations for both Units are presented in Table 2. Under Unit 1, the water table is mostly above top of bedrock so flow is primarily in saprolite; therefore, the hydraulic conductivity (K = .0731 ft/day) was based on the geometric mean of values from slug tests conducted on saprolite wells at the facility in 2009 and the effective porosity (ne) value was estimated at 31% of the laboratory -determined porosity for soil samples from the facility. The average estimated linear groundwater flow velocity under Unit 2 is calculated to be approximately 267 feet per year. The modified Darcy equation for linear flow velocity makes the simplifying assumptions of a homogeneous, isotropic, porous aquifer. Flow in fractured bedrock is likely to be neither homogeneous nor isotropic, so the calculated velocity should be taken as a first - order approximation and velocities could vary locally by an order of magnitude. 2.0 FACILITY MONITORING PROGRAM 2.1 Regulatory Status The Granville County Oxford Unit 2 Landfill groundwater monitoring is completed in accordance with North Carolina Administrative Code Title 15A - Environmental Quality Chapter 13 Sub -Chapter B - August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 2 Solid Waste Management Rule (NCSWMR) § 1633 (Detection Monitoring Program). Statistical analyses of the laboratory data when required is prepared in accordance with the required compliance demonstration of the NCSWS Rule .1632(g), (h), and (i). 2.2 Monitoring Network Six groundwater monitoring wells comprise the compliance monitoring network at the Oxford Unit 2 Landfill. The compliance network includes monitoring wells MW-7 (the current facility background well), MW-8 (which monitors the leachate tank area), MW-9, MW-10, MW-11, and NES-2S. The locations of these wells are shown on Drawing 1. The following table summarizes the monitoring network and required analytical parameters for the two semiannual sampling events: Unit 2 Groundwater Monitoring Network Total Depth Lithology of Monitoring Well Date Installed Classification (feet) Screened Interval MW-7 7/28/08 Background 34.50 Saprolite MW-8 5/05/12 Compliance 22.74 Bedrock MW-9 10/06/08 Compliance 42.46 Bedrock MW-10 10/02/08 Compliance 33.11 Bedrock MW-11 10/05/08 Compliance 22.30 Bedrock Compliance (also NES-2S 5/11/04 performance for 21.5 Saprolite Unit 1) 2.3 Groundwater Monitoring Program In accordance with the January 2018 Water Quality Monitoring Plan for the facility, during both semiannual sampling events all monitoring wells are sampled for Appendix I of 40 CFR Part 258, from here on known as North Carolina Appendix I list of constituents and in accordance with the NCSWMR's May 29, 2018 Memo, 1,4-Dioxane was added to the list of parameters to be sampled. MW-7 also serves as the background well for the Unit 1 landfill and NES-2S also serves as a performance well under the Unit 1 Corrective Action Plan (CAP) for the facility. The monitoring well analytical programs for Unit 2 are summarized below and well construction details are presented in Appendix A. Groundwater Monitoring Program Monitoring Well Date Installed Classification Monitoring Program 1st SA Event Analyses 2nd SA Event Analyses MW-7 7/28/08 Background Assessment App.l, App.l, MW-8 5/05/12 Compliance Detection App.l, App.l, MW-9 10/06/08 Compliance Detection App.l, App.l, MW-10 10/02/08 Compliance Detection App.l, App.l, MW-11 10/05/08 Compliance Detection App.l, App.l, NES-2S 5/11/04 Compliance Detection COC COC August 2019 Semiannual Water Quality Monitoring Report La Bella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 3 2.4 Surface Water Monitoring Program There are two surface water sampling points associated with Unit 2: SW-3, and SW-4. Sampling point SW-3 is located upstream of Unit 2, Phase 1 on the perennial creek that runs along the east side of the new phase. SW-4 is located on the same perennial creek downstream of the new phase, but before the confluence of the perennial creek and the drainage channel from the west side of Unit 2. The surface water samples are analyzed for the NCSWMR Appendix I list of constituents and 1,4- Dioxane during both semiannual events. 3.0 AUGUST 2019 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On August 7-8, 2019, LaBella personnel visited Oxford Landfill to purge and sample monitoring wells MW-7, MW-8, MW-9, MW-10, MW-11 and NES-2S and to collect samples from surface points SW-3 and SW-4. Monitoring wells were purged and sampled using either a 12-volt submersible pump or disposable bailers. Field measurements of temperature, pH, specific conductivity, oxidation-reduction potential (ORP), dissolved oxygen, and turbidity were recorded in a field log for all monitoring wells and can be found in Table 3. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well ID (completed by laboratory or field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory or field personnel); • Chemical preservative (completed by the laboratory or field personnel); and • Requested chemical analysis (completed by the laboratory or field personnel). Groundwater samples from each monitoring well were collected within 24 hours of the final purge volume and were dispensed directly from the pump flow or bailer into the laboratory -provided containers. Immediately after collection, the samples were placed in a laboratory -provided cooler and preserved on ice. Field sampling logs are provided in Appendix B. Surface water samples from SW-3 and SW-4 were collected directly from stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory - prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field sampling logs are provided in Appendix B. August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 4 3.1.1 Resample On September 4, 2019 LaBella personnel were on site to resample monitoring well MW-10 for vanadium. MW-10 was purged and sampled using the same methods described above. 3.2 Laboratory Analysis and Quality Control The groundwater and surface water samples collected during the August 2019 and the September 2019 resampling evnetsemiannual sampling event were delivered to Pace Analytical Services Inc. of Huntersville, North Carolina under chain -of -custody protocol. Groundwater samples from the compliance wells and surface points were analyzed for NC Appendix I constituents and 1,4-Dioxane. According to the laboratory records, the water samples were received by the laboratory on August 9, 2019, in good condition, properly preserved, at proper temperatures, and within analysis hold times. In addition to samples collected for compliance monitoring at the Oxford Landfill, LaBella personnel collected a Field Blank as part of the August 2019 semiannual sampling event quality control and quality assurance (QA/QC) procedure. The Field Blank was analyzed for NC Appendix I and 1,4- Dioxane and was used as quality control in both Oxford Unit 1 and Unit 2. Also, as part of the QA/QC procedure, a Trip Blank that was prepared by the laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip Blank was analyzed to comply with both Oxford Unit 1 and Unit 2 NC Appendix I list of constituents and 1,4-Dioxane list of volatile organic compounds (VOCs). Upon receipt of the laboratory data package, LaBella personnel reviewed the following data: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the North Carolina Administrative Code 15A NCAC 2L.0202 (NC2L) Groundwater Standards or the SWS Groundwater Water Protection Standards (GWPS), or 15A NCAC 2B (NC 2B) Surface Water Standards; and • Detections above historical levels. The complete laboratory analytical reports are included in Appendix B. 4.0 DATA ANALYSIS AND STATISTICAL RESULTS The final results from the August 2019 groundwater and surface water sampling event were received from Pace Analytical on August 28, 2019. The final results for the September 2019 resampling of MW-10 were received from Pace Analytical on September 11, 2019. All laboratory analytical reports can be found in Appendix B. August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 5 4.1 Analytical Results Groundwater Table 4 summarizes the detections of constituents for the August 2019 semiannual sampling event and the September 2019 resampling event. Historical groundwater analytical results are presented in Appendix C (Table A3-2). Historical groundwater field parameters are summarized in Appendix C (Table A34). 4.1.1 Inorganic Analyses Four metals constituents were detected in the August 2019 semiannual sampling event in groundwater at a quantified concentration above the method reporting limit (MRL): Barium (MW-8, MW-9, MW-10, and MW-11); Copper (MW-8 and MW-10); iron and manganese (MW-7); and vanadium (MW-10). Vanadium was detected above the MRL and NC2L in monitoring well MW-10 during the August event but was not detected in the September resample, so the initial exceedance was refuted. 4.1.2 Organic Analyses No organic constituents were detected above the MRL or the MDL in any groundwater samples during the August 2019 sampling event. 4.1.3 Analytical Results for Surface Water Barium was detected at a quantified concentration above the laboratory MRL in surface water samples SW-3 and SW-4. Vanadium was detected at a quantified concentration above the laboratory MRL in surface water sample SW-4. Surface water analytical results from the site were compared to the 15A-NCAC-2B (NC-213) surface water standards for Class C waters (aquatic life and secondary recreation). No constituents were detected above the NC 2B standard for Class C waters. Table 4 includes the detected constituents is surface water samples for the August 2019 semiannual sampling event. The laboratory analytical reports, the laboratory quality assurance/quality control information, and the chains -of -custody for SW-3 and SW-4 are included in Appendix B. Historical surface water analytical results are presented in Appendix C (Table A3-3). Historical surface water field parameters are presented in Appendix C (Table A3-5). 4.1.4 Statistical Methods MW-7 is the current upgradient background well for both Unit 1 and Unit 2. Data from MW-7 from June 2011 to present may be used to determine statistical background concentrations for inorganic constituents detected at the facility. In addition to data from MW-7, pre -waste background sampling data from MW-8, MW-9, MW-10, MW-11, and MW-12 collected between June and October 2012 may also be included as background data for statistical analyses. The background data for inorganic constituents are evaluated in accordance with the procedures outlined in North Carolina Administrative Code 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentration exceeded the facility background concentrations using the Shapiro -Wilk Test, Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction Limits, and Poisson Prediction Limits as appropriate. Background data, tests for normality, outliers, Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the background data. The statistical test by which downgradient data are compared to facility background data is based upon the nature of the data and the number of data August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 6 values that are less than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one -tailed tests. Since there were no confirmed exceedances of groundwater protection standards, no statistical analyses were conducted as part of this report. 5.0 CONCLUSION Based on analytical results from the August 2019 monitoring event, the Granville County, Oxford Unit 2 Landfill will remain in the Detection Monitoring program as outlined in Title 15A NCAC 13B.1633. The next semiannual sampling event is tentatively scheduled for February 2020. 6.0 REFERENCES The references cited herein were used to prepare this document and may or may not be cited in the text of this report. Butler, J. Robert, and Secor, Jr., Donald T., 1991, The Central Piedmont, in Horton, J. W., Jr., and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press, p. 59-78. JOYCE, 2009a. Corrective Action Plan, Granville County Oxford Landfill. March 2009. JOYCE, 2009b. Hydrogeologic Reports, Granville County Oxford Landfill. October 2009. JOYCE, 2010a. Request for Background Well Replacement, Granville County Oxford Landfill, Permit # 39-01. October 25, 2010. JOYCE, 2010b. Corrective Action Evaluation Report and Alternate Source Demonstrations,Granville County Oxford C&D Over MSW Landfill, Permit # 39-01. November 29, 2010. JOYCE, 2013. Groundwater Background Monitoring Report Unit 2, Phase 1 MSWLF Expansion. January 4, 2013 North Carolina Department of Environment, Health, and Natural Resources, 1997. North Carolins Solid Waste Management Rules. 15 NCAC 13B.1600. January 1, 1997, with updates through April 2011. North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina Department of Natural Resources and Community Development, scale 1:500000. USEAP, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992. Woodward -Clyde Consultants, 1994. Transition Plan, Oxford Landfill Granville County, North Carolina. April 1994. August 2019 Semiannual Water Quality Monitoring Report LaBella Associates Oxford Unit 2 Landfill, Permit No. 3901-MSWLF-2012 November 2019 7 TABLES Table 1 August 2019 Groundwater Elevations Table 2 August 2019 Estimated Hydraulic Gradients and Velocities Table 3 August 2019 Field Parameters Table 4 August 2019 Detections of Groundwater and Surface Water Constituents TABLE 1: August 2019 Groundwater Elevations LOCATION TOC ELEVATION (Ft- AMSL) DEPTH TO GROUNDWATER (Ft- BTOC) WELL DEPTH (Ft- BTOC) GROUNDWATER ELEVATION (Ft- AMSL) MW-7 534.24 22.13 37.32 512.11 MW-8 503.31 3.16 28.00 500.15 MW-9 487.51 8.65 43.00 478.86 MW-10 484.92 9.17 32.90 475.75 MW-11 478.72 5.63 22.90 473.09 NES-2S 477.20 4.89 24.20 472.31 Notes TOC = Top of Casing Ft-BTOC = Feet below Top of Casing. Ft-AMSL = feet above mean sea level Granville County - Oxford Landfill, Unit 2 LaBella Associates Permit No. 39-01 MSWLF-2012 TABLE 2: Groundwater Gradients and Calculated Flow Rates Date of Water Table Measurements: August 7, 2019 FLOW LINE SEGMENT SEGMENT LENGTH (feet) FLOW DIRECTION SEGMENT BEGIN & END GW ELEVATION (feet-AMSL) HORIZ. GRADIENT i HYDRAULIC CONDUCTIVITY K (ft/day) EFFECTIVE POROSITY n e LINEAR VELOCITY V (ft/year) 1072 NE 0.0187 7.31E-02 0.31 1.61 480 1 1411 NNW 0.0248 4.43E+00 0.15 267 475 2 Average: 0.0217 Average: 134 Notes: Linear flow velocity: V = Kiln e (modified Darcy equation). Along Flow Path i 1 under Unit 1, the water table is mostly above top of bedrock, so flow is primarily in saprolite. 1 i Hydraulic conductivity (K) is based on the geometic mean of values from slug tests conducted on saprolite wells at the facility in 2009. Effective porosity (n e) value is estimated at 31% of the laboratory -determined porosity for soil samples from the facility. Along Flow Path i 2 under Unit 2, the water table is mostly below top of bedrock, so flow is primarily in fractured bedrock. i 2 Hydraulic conductivity (K) is based on the geometic mean of values from slug tests conducted on bedrock wells at the facility in 2009. Effective porosity (n e) value for fractured bedrock is estimated at 15%. Refer to Drawing 1 for flow line segments. Granville Co. - Oxford Landfill, Units 1 and 2 La Bella Associates Permit # 39-01 TABLE 3: August 2019 Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE pH 6.01 S.0 8/8/2019 Temperature 20.4 °C 8/8/2019 Conductivity 319.5 PS/Cm 8/8/2019 3901-MW7 Turbidity 6.31 NTU 8/8/2019 Dissolved Oxygen 2.43 mg/L 8/8/2019 Oxidation Reduction Potential 180.2 my 8/8/2019 Static Water Level 22.13 ft 8/8/2019 Well Depth 37.32 ft 8/8/2019 pH 7.55 S.0 8/8/2019 Temperature 20.0 °C 8/8/2019 Conductivity 211.8 PS/Cm 8/8/2019 3901-MW8 Turbidity 2.42 ntu 8/8/2019 Dissolved Oxygen 2.58 mg/L 8/8/2019 Oxidation Reduction Potential 125.5 my 8/8/2019 Static Water Level 3.16 ft 8/8/2019 Well Depth 28.00 ft 8/8/2019 pH 6.39 S.0 8/8/2019 Temperature 20.2 °C 8/8/2019 Conductivity 292.3 PS/Cm 8/8/2019 3901-MW9 Turbidity 8.58 NTU 8/8/2019 Dissolved Oxygen 1.55 mg/L 8/8/2019 Oxidation Reduction Potential 145.4 my 8/8/2019 Static Water Level 8.65 ft 8/8/2019 Well Depth 43.00 ft 8/8/2019 pH 6.34 S.0 8/8/2019 Temperature 20.0 °C 8/8/2019 Conductivity 132.7 PS/Cm 8/8/2019 3901-MW10 Turbidity 40.30 NTU 8/8/2019 Dissolved Oxygen 2.12 mg/L 8/8/2019 Oxidation Reduction Potential 166.1 my 8/8/2019 Static Water Level 9.17 ft 8/8/2019 Well Depth 31.50 ft 8/8/2019 pH 5.38 S.0 9/4/2019 Temperature 24.9 °C 9/4/2019 Conductivity 150.6 PS/Cm 9/4/2019 3901-MW10* Turbidity 0.95 NTU 9/4/2019 Dissolved Oxygen 0.44 mg/L 9/4/2019 Oxidation Reduction Potential 128.9 my 9/4/2019 Static Water Level 9.83 ft 9/4/2019 Well Depth 31.50 ft 9/4/2019 pH 6.32 S.0 8/8/2019 Temperature 23.2 °C 8/8/2019 Conductivity 133.9 PS/Cm 8/8/2019 3901-MW11 Turbidity 11.60 NTU 8/8/2019 Dissolved Oxygen 2.09 mg/L 8/8/2019 Oxidation Reduction Potential 178.3 my 8/8/2019 Static Water Level 5.63 ft 8/8/2019 Well Depth 22.90 ft 8/8/2019 Granville County- Oxford Unit 2 Landfill LaBella Associates Permit No. 3901 MSWLF-2012 Page 1 of 2 TABLE 3: August 2019 Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE pH 5.55 S.0 8/8/2019 Temperature 22.7 °C 8/8/2019 Conductivity 136.1 PS/Cm 8/8/2019 3901-NES2S Turbidity 1.44 NTU 8/8/2019 Dissolved Oxygen 0.50 mg/L 8/8/2019 Oxidation Reduction Potential 183.7 mV 8/8/2019 Static Water Level 4.89 ft 8/8/2019 Well Depth 24.20 ft 8/8/2019 pH 7.16 S.0 8/8/2019 Temperature 30.8 °C 8/8/2019 3901-SW1 Conductivity 66.5 PS/Cm 8/8/2019 Turbidity 74.47 NTU 8/8/2019 Dissolved Oxygen 1.56 mg/L 8/8/2019 Oxidation Reduction Potential 226.4 mV 8/8/2019 pH 6.34 S.0 8/8/2019 Temperature 25.2 °C 8/8/2019 3901-SW2 Conductivity 76.0 PS/Cm 8/8/2019 Turbidity 51.39 NTU 8/8/2019 Dissolved Oxygen 2.05 mg/L 8/8/2019 Oxidation Reduction Potential 243.5 mV 8/8/2019 pH 6.99 S.0 8/8/2019 Temperature 23.4 °C 8/8/2019 3901-SW3 Conductivity 58.0 PS/Cm 8/8/2019 Turbidity 28.51 NTU 8/8/2019 Dissolved Oxygen 1.64 mg/L 8/8/2019 Oxidation Reduction Potential 165.0 mV 8/8/2019 pH 6.30 S.0 8/8/2019 Temperature 23.4 °C 8/8/2019 Conductivity 72.2 PS/Cm 8/8/2019 3901-SW4 Turbidity 28.7 NTU 8/8/2019 Dissolved Oxygen 1.88 mg/L 8/8/2019 Oxidation Reduction Potential 189.3 mV 8/8/2019 Notes: mg/I = milligrams per liter. pg/I = micrograms per liter. °C= degrees Centigrade. pS/cm = microSemens per centimeter. S.U.= Standard Units. NTU = Nephelometric Turbidity Units. ft = feet. my = millivolts mg/L = milligrams per liter *= Sample collected during 9/4/19 resample Granville County- Oxford Unit 2 Landfill LaBella Associates Permit No. 3901 MSWLF-2012 Page 2 of 2 TABLE 4: August 2019 Detections of Groundwater and Surface Water Constituents NC2L/ SAMPLE ID PARAMETER RESULT UNITS MDL MRL DATE NC2B 3901-MW7 Barium 4.5 J pg/L 1 5 700 08/08/19 3901-MW7 Copper 2.5 J pg/L 2.1 5 1,000 08/08/19 3901-MW7 Iron 176 pg/L 19.5 50 300 08/08/19 3901-MW7 Manganese 6.0 pg/L 0.9 5 50 08/08/19 3901-MW7 Nickel 0.93 J pg/L 0.9 5 100 08/08/19 3901-MW7 Vanadium 2.2 J pg/L 1.3 5 0.3 08/08/19 3901-MW7 Alkalinity, Total as CaCO3 140,000 pg/L 5,000 5,000 NE 08/08/19 3901-MW7 Chloride 10,100 pg/L 500 1,000 250,000 08/08/19 3901-MW7 Sulfate 51,500 pg/L 500 1,000 250,000 08/08/19 3901-MW7 Total Dissolved Solids 256,000 pg/L 25,000 25,000 500,000 08/08/19 3901-MW8 Barium 40.2 pg/L 1 5 700 08/08/19 3901-MW8 Copper 8.3 pg/L 2.1 5 1,000 08/08/19 3901-MW9 Barium 71.4 pg/L 1 5 700 08/08/19 3901-MW10 Barium 60.5 pg/L 1 5 700 08/08/19 3901-MW10 Chromium 1.0 J pg/L 1 5 10 08/08/19 3901-MW10 Copper 6.9 pg/L 2.1 5 1,000 08/08/19 3901-MW10 Nickel 1.6 J pg/L 0.9 5 100 08/08/19 3901-MW10 Vanadium 5.3 pg/L 1.3 5 0.3 08/08/19 3901-MW10 Vanadium** ND pg/L 1.3 5 0.3 09/04/19 3901-MW11 Barium 30.1 pg/L 1 5 700 08/08/19 3901-MW11 Cobalt 1.2 J pg/L 1.1 5 1* 08/08/19 3901-MW11 Nickel 3.2 J pg/L 0.9 5 100 08/08/19 3901-MW11 Vanadium 1.8 J pg/L 1.3 5 0.3 08/08/19 3901-SW3 Barium 23.3 pg/L 1 5 21,000#T 08/08/19 3901-SW3 Copper 2.7 J pg/L 2.1 5 2.01#H 08/08/19 3901-SW3 Vanadium 3.3 J pg/L 1.3 5 NE 08/08/19 3901-SW3 Hardness, Total 17,400 pg/L 131 662 NE 08/08/19 3901-SW4 Arsenic 6.1 J pg/L 4.7 10 10# 08/08/19 3901-SW4 Barium 44.5 pg/L 1 5 21,000#T 08/08/19 3901-SW4 Chromium 2.2 J pg/L 1 5 11# 08/08/19 3901-SW4 Cobalt 2.9 J pg/L 1.1 5 1.6#T 08/08/19 3901-SW4 Copper 2.7 J pg/L 2.1 5 3.04#H 08/08/19 3901-SW4 Lead 1.6 J pg/L 1.6 5 0.62#H 08/08/19 3901-SW4 Nickel 1.9 J pg/L 0.9 5 17.82#H 08/08/19 3901-SW4 Vanadium 7.9 pg/L 1.3 5 NE 08/08/19 3901-SW4 Zinc 7.2 J pg/L 3.9 10 40.09#H 08/08/19 3901-SW4 Hardness, Total 28,200 pg/L 131 662 NE 08/08/19 NOTES: All Results in micorgrams per liter (pg/L) MDL = Method Detection Limit MRL = Method Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 IMAC* = NC Interim Maximum Allowable Concentration (for constituents with no NC2L) NC2B# = NC Surface Water Standard from 15A NCAC 2B #H = Hardness -based NC2B #T = NCTV = INC In -Stream Target Values (for constituents with no NC2B) #N = NRWQC = USEPA Nationally Recommended Water Quality Standards (for contituents with no NC2B or NCTV) NE= Not Established J = Estimated concentration below the MRL ** = Results of resampling event conducted on 9/04/2019. Bold values = Detections above the applicable stardards Granville County - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901 MSWLF-2012 FIGURE Figure 1 Site Location Map (USGS Topographic Map) 0 Soo 0 600 15 o o� a o �o - � ps o C� �F q T o S 1 soy Lewis 4 �` NIT z 0 500 "I \ Cam: s r o z� Q. Q 15 1 by O STERL_CA(THIN.BTo, Ap PE I o 1 00 Sao a O Mead 11 , emo ie Mrial Kinton R,\ p / V Parkl or 1Fk - P NOTE: U.S.G.S. 7.5 MINUTE TOPGRAPFiI 1 4000 QUADRANGLES FOR SATTERWHITE, STOVALL, EREA AND OXFORD, NORTH CAROLINA. 9rK it is avhustion of New York Education Law Article 145 Sec.7209, for any person, unless acting under the direction of a licenser landd architect, ISSUED FOR: pride LaBeLLa enalfthealtonal ringineerarlantlsurveyor ndsuryafter nteminanywatheIte theirsealandnng the ealutanarcedby'folloeer ytheirsunatures GROUNDWATER MONITORING REPORT altered; me anering amhltect. englncer, or lane surveyor shall aflk to the Item their seal and notatlon "aneree by' followed by their signature ana DRAWING NAME: date of such Atea9on, and aspecmcdescription ofthe abation. DRAWN BY: DATE: PROJECT NO.: Powered by partnership. SITE LOCATION MAP RWH 11/25/19 2182022 2211 W. MEADOWVIEW ROAD GREENSBORO, NC 27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: OXFORD LANDFILL � abellapc.com ©2019 LaBella Associates GRANVILLE COUNTY, NORTH CAROLINA L:\G—AII.\dwg\Oxford\, 2019 Labella Site Location Map.dwg DRAWING Drawing 1 Groundwater Potentiometric Surface Map 7 80 r 1 \ EN S 1D (ABANDONED \ \\� I I / oSJ \ �� ��\ �� \ — \ 1 I \ \ \ \ NM AREA�RVEYED IW TH11d— -1S /NS / / , i (� I /\ I THIS BOUNDARY CONSISTS,\\�475.75 1` \ \ _ \ / / \ \ \ \ �1 NE� �FSROUND SURVEY DATED MASH 2Oa3 \ I I APPROXIMATE MSW LANDFILL, / I / / / l I \\ \ I } J I j S-2D 472.31 WASTE / / \4 .33 490 498.3R \/ / Q`90 \ Qc$"� \ \ ��\ R 1 I / / ACCESS ROAD 467.68 \ I / 1 / �� �1 �/ 1II� r \I\l�1t\/ ,\ � \-//I\ I /J I\//II -/ / (� (\ % - �S���I III6III II1ItIIII IIIo IIIIIII �I IIII II II IIIIIIII III�I I—�III' I IIII I� I I l I— II1 I I�I IIII I I I( II\ ��I II—�IIII _IIIIII III I I�II�I I I'� I_ III_ I III II I II IIII I I I IIIII\ I, II/IIIIII,IIIIIIIII I I1_ � I IIII_ I► II II� \\ II IIII �_ I�II�IIIIIIIIIII IIIIIIII IIIII IIII I�— IIIIIIII I /I1I I. /\/ / II�IIII1�/ �IIII I/I / I1IIII I/I� i \ I\III— \/-o �/I/ /I�/%II �III I//iiI-I�I,II//�I/f ��� III �// /- ���///.II / /Ir,\/I I\!� \II\-\�//�\�\�i\�I \�/ i\\\ \�\ _�\��\\\ /�\ �\l\�\\ \�/�\�\/���// /\ /\�\\\ \�/\i\� ��/ � /�\ /\-\\ �\ i\\ \��—\/�\ \��/\�\�� \����� �\\\ <\\ �i -\\ . \s\ \%1�\ J�—� �\ < \�\.-\-—\�\_\_ \_/ ��—�\��\ �� (�\\J\�\�i-- _ _�><�� -\�=\\- \ am\\ \ `�- ��\--�\� _=�—\—\- —T -0\—I —�_ - \ —_ S— —\_1-8\��_\0/\� —\ c\ \_ �� -I\ \/ _—; I -=-__ — —_- \ �;_ _ _`I�\/ �_I � I— I \ II _I II -I I� _ II I -✓I _- II �I—III—IIII I IIIIIII——IIIIII II\I I 1 I -_ I II�II-o_► J�III\ I�— I _ IIf�I III— I _\ IOIII I �\ _1I—I II III —I �I,IIIIII_I� III1IIIIIII II1II I�III I\ I1�IJIII—IIII IIII�tIIIII�IIoI III1 II �1/III I II�I�II1III II III I_ III /II I III II —IIII I I I�ofIII IIIII� II II I IIII —III'_ I I I II I I—IJI I II III IIIIII IrIII IoII�I—III IIII I 1_ II II � I IIII III IIIII II I IIII I II IIII III\II I I III I I III I II I � IIIII III II I I IIIII II III II III I�IIIII II(I If \I II ITII II I III II II IIII III►IIIII IIII IIIIII II III I I IIII IIIII'III I/I III I IIII IIIII I I III II I I� II1� // 1 //1II IIII III IIII�IIII II( III I II I �IIIIIIIIIIIIIIIIIII 1IIIIIII III I IIIII IIII III I II I �IIIIIII�lII I I I I/II � IIIIIII IIIII/ �III1 �I IIII II,IIII II IIIl Ii/I /II 1I ItII -I , I - I I i I/\I/�II/1�11 I\1 I / // '� / �/�/1/ I_� / /\ �\�I�- / ����I/`I— \ I/I1/// / rI,/I I/�//�/l/I/ V/ /// / I°/I-i/ 1 1/ I/ � l -I // / ,,\ �V-1 ,�\ \ / �/\f���/ ///� ///, � , I // /��\I/�/// /�/i \ ///' I / ` 7✓////// //\ \/—//�//��-�— //// /o �/ �ti /4—\/ � - / J//—� I=— .I/�III / I ,1/1 I A-/°- �J-TAPPROXIM�- E N\,,1 D— L LIMITS OFWAS�� GPP o -T� I P _ 78I \II8 II�6 MW_6R499.0� 570/ i/ 590 ce // %, 5 r� -51 o� I � I — ROADO I��49\0IICo X GJill I\ S_ / It LEGEND 12AS4-;II I > P EXISTING 10'TO /P\OI IfG I R��I 1 � AP1Jl I HI/IC \ 1 )I CONTOUR \\I 1/ /1 1 I �\/\ \ \/ \I/ \/\ 510 -21 -3/ EXISTING 2'TOPOGRAPHIC CONTOUR 68 EXISTING ROAD P-1 490 GROUNDWATER SURFACE CONTOUR � (ABONED) FEET ABOVE MEAN SEA LEVEL (AMSL 1 ) l]J 1 I_ IIIIIII 503.93 \ / \� �\ \�\� _ \\\�J �y , — \ GROUNDWATER FLOW DIRECTION MW_X GROUNDWATER MONITORING WELL LOCATION I C /� — —�\\��/ / AND IDENTIFICATION oy �� f /- \� _ _ _ = / / I oil �- —_— % I II I' I 111 SURFACE MONITORING POINT LOCATION AND \ �t THIS BO RY--Q: N I�WS�// / I ' ` 11 ' I� / 1 / /� \ //T. \ \ SEGMENT USED FOR GRADIENT CALCULATION = � � 1 OF-6R0SURV ,ri1N�20�1 I _— — �/ _12 \ -10 �� \�� III / I I \ \ \ \ FLOW PATH LENGTH -9�-� \ � IIII / // / \ I . � \ \ / � I I J � ON 1,072 LF o I / z 1,411 LF \ QSW1 II �` Oil ON / 0N � � �� oN III ► ( ( / ,-- � 1 ,,� 510 / SEDIMENT BASIN SB 1 H \ \ I \ r s \ l I \ f , NOTES Jam,- o I I o / \ 1 \ ( I —"U5` 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET "� \ I \ IQ , I I \ \ o ON I ( \ / / / 2. GROUNDWATER CONTOUR INTERVAL = 10 FEET I 3. GROUNDWATER CONTOURS BASED ON LINEAR —MW-B� INTERPOLATION BETWEEN AND EXTRAPOLATION 500.01 I �� \ I I I I FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, 515.74 0 / / J AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL GROUNDWATER CONDITIONS. I I 1 f I nN GRAPHIC SCALE / 4. STATIC WATER LEVELS MEASURED ON 08/07/19. b \_50 — 00 / 20� — / (FEET) 1 LaBeLLa Powered by partnership. 2211 W. MEADOWVIEW ROAD GREENSBORO, NC 27407 PHONE: (336) 323-0092 labellapc.com \ T L © 2019 LaBella Associates GRANVILLE COUNTY OXFORD, NORTH CAROLINA OXFORD LANDFILL OXFORD , NORTH CAROLINA N0: DATE: DESCRIPTION: Revisions PROJECT NUMBER: 2182022 DRAWN BY: RH REVIEWED BY: AM ISSUED FOR: GROUNDWATER REPORT DATE: 09/19/19 DRAWING NAME GROUNDWATER SURFACE CONTOUR MAP AUGUST 7, 2019 DRAWING NUMBER: 1 APPENDICES Appendix A Well Construction Details Appendix B Laboratory Analytical Reports and Field Data Logs Appendix C Historical Data Tables Appendix Well Construction Details TABLE Al-01: Well Construction Details AR TD TD TOC Top Top Bottom Bottom GS Elev. TOC Screened DTW Well ID Date Installed Northing Easting (Bedrock) (Boring) (Well) Stick-up Screen Screen Screen Screen Comments (Ft AMSL) (Ft AMSL) SL) LIth010gy (Ft BTOC) (Ft-BGS) (Ft-BGS) (Ft-BTOC) (Ft-AGS) (Ft-BGS) (Ft-BTOC) (Ft-BGS) (Ft-BTOC) MW-7 07/28/08 953292.1160 2112043.4480 531.24 534.24 34.50 34.50 37.50 3.00 19.50 22.50 34.50 37.50 Saprolite 23.91 Background Well Units (former P-2) 05/05/12 MW-8 953360.2000 2111527.6910 500.57 503.31 1.00 25.00 20.00 2.74 10.00 12.74 20.00 22.74 Bedrock Artesian Unit 2 Compliance 07/18/12 MW-9 10/06/08 954799.7410 2112842.3890 485.05 487.51 1.50 40.00 43.00 2.46 20.00 22.46 40.00 42.46 Bedrock 8.30 Unit 2 Compliance (former P-9) MW-10 10/02/08 955136.0000 2112571.1750 481.81 484.92 6.00 30.00 32.90 3.11 15.00 18.11 30.00 33.11 Bedrock 8.15 Unit 2 Compliance (former P-10) MW-11 10/05/08 954795.8510 2111957.0410 476.43 478.72 6.00 20.00 22.90 2.30 5.00 7.30 20.00 22.30 Bedrock 6.80 Unit 2 Compliance (former P-13) 521.30 31.00 50.00 52.30 2.00 40.00 42.00 MW-12 08/01/08 954077.4350 2112567.4920 519.29 50.00 52.00 Bedrock 30.75 Unit 2 Background, not (former P-21) 477.20 9.00 21.50 11.00 13.67 sampled NES-2S 05/01/04 955091.2902 2111945.3411 474.53 24.17 2.67 21.00 23.67 Saprolite 9.14 Unit 2 Compliance and 474.72 477.43 21.50 Unit 1 Perfomance NES-21D 05/01/04 955081.7805 2111946.7398 66.50 69.21 2.71 51.00 53.71 66.00 68.71 Bedrock 5.00 Unit 1 Sentinel, not sampled for Unit 2 NOTES: AR = Auger Refusal (Estimate of depth to bedrock). TO = Total Depth (of boring or well/piezometer). TOC = Top of Casing. GS = Ground Surface. DTW = Depth to Water (as measured on 11/20/08). Ft-BGS = Feet below ground surface. Ft-AGS = Feet above ground surface. Ft-BTOC = Feet below TOC. Ft-AMSL = Feet above mean sea level. Granville Co., Oxford Landfill, Unit 2 Permit No. 3901-MSWLF-2012 La Bella Associates Appendix 8 Laboratory Analytical Reports and Field Data Logs aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 19, 2019 Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Dear Van Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 31 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Lab ID Sample ID Matrix Date Collected Date Received 92440784001 3901-MW8 Water 08/08/1910:36 08/09/1910:20 92440784002 3901-MW9 Water 08/08/1911:41 08/09/1910:20 92440784003 3901-MW10 Water 08/08/1911:15 08/09/1910:20 92440784004 3901-MW11 Water 08/08/1911:02 08/09/1910:20 92440784005 3901-SW3 Water 08/08/1911:55 08/09/1910:20 92440784006 3901-SW4 Water 08/08/1911:30 08/09/1910:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Oxford Compliance Unit 2 92440784 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92440784001 3901-MW8 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440784002 3901-MW9 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440784003 3901-MW10 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440784004 3901-MW11 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440784005 3901-SW3 EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440784006 3901-SW4 EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Lab Sample ID Method Client Sample ID Parameters 92440784001 3901-MW8 EPA 601 OD Barium EPA 601 OD Copper 92440784002 3901-MW9 EPA 601 OD Barium 92440784003 3901-MW10 EPA 601 OD Barium EPA 601 OD Chromium EPA 601 OD Copper EPA 601 OD Nickel EPA 601 OD Vanadium 92440784004 3901-MW11 EPA 601 OD Barium EPA 601 OD Cobalt EPA 601 OD Nickel EPA 601 OD Vanadium 92440784005 3901-SW3 EPA 601 OD Barium EPA 601 OD Copper EPA 601 OD Hardness, Total(SM 2340B) EPA 601 OD Vanadium 92440784006 3901-SW4 EPA 601 OD Arsenic EPA 601 OD Barium EPA 601 OD Chromium EPA 601 OD Cobalt EPA 601 OD Copper EPA 601 OD Lead EPA 601 OD Nickel EPA 601 OD Hardness, Total(SM 2340B) EPA 601 OD Vanadium EPA 601 OD Zinc Result Units Report Limit Analyzed 40.2 ug/L 5.0 08/17/19 00:21 8.3 ug/L 5.0 08/17/19 00:21 71.4 ug/L 5.0 08/17/19 00:33 60.5 ug/L 5.0 08/17/19 00:43 1.0J ug/L 5.0 08/17/19 00:43 6.9 ug/L 5.0 08/17/19 00:43 1.6J ug/L 5.0 08/17/19 00:43 5.3 ug/L 5.0 08/17/19 00:43 30.1 ug/L 5.0 08/17/19 00:46 1.2J ug/L 5.0 08/17/19 00:46 3.2J ug/L 5.0 08/17/19 00:46 1.8J ug/L 5.0 08/17/19 00:46 23.3 ug/L 5.0 08/17/19 00:49 2.7J ug/L 5.0 08/17/19 00:49 17400 ug/L 662 08/17/19 00:49 3.3J ug/L 5.0 08/17/19 00:49 6.1 J ug/L 10.0 08/17/19 00:52 44.5 ug/L 5.0 08/17/19 00:52 2.2J ug/L 5.0 08/17/19 00:52 2.9J ug/L 5.0 08/17/19 00:52 2.7J ug/L 5.0 08/17/19 00:52 1.6J ug/L 5.0 08/17/19 00:52 1.91 ug/L 5.0 08/17/19 00:52 28200 ug/L 662 08/17/19 00:52 7.9 ug/L 5.0 08/17/19 00:52 7.2J ug/L 10.0 08/17/19 00:52 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 5 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW8 Lab ID: 92440784001 Collected: 08/08/19 10:36 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:21 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:21 7440-38-2 40.2 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:21 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:21 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:21 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:21 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:21 7440-48-4 8.3 ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:21 7440-50-8 ND ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:21 7439-92-1 ND ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:21 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:21 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:21 7440-22-4 ND ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:21 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 21:43 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 21:24 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 21:24 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 21:24 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 21:24 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 21:24 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 21:24 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 21:24 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 21:24 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 21:24 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 21:24 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 21:24 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 21:24 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 21:24 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 21:24 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 21:24 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 21:24 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 21:24 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 21:24 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 21:24 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 21:24 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 21:24 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 21:24 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 21:24 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 21:24 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 21:24 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 21:24 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 21:24 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW8 Lab ID: 92440784001 Collected: 08/08/19 10:36 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 08/15/19 21:24 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 21:24 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 21:24 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 21:24 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 21:24 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 21:24 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 21:24 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 21:24 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 21:24 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 21:24 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 21:24 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 21:24 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 21:24 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 21:24 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 21:24 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 21:24 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 21:24 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 21:24 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 21:24 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 21:24 1330-20-7 105 % 70-130 1 08/15/19 21:24 460-00-4 100 % 70-130 1 08/15/19 21:24 17060-07-0 100 % 70-130 1 08/15/19 21:24 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1915:42 123-91-1 101 % 50-150 1 08/12/1915:42 17060-07-0 106 % 50-150 1 08/12/1915:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW9 Lab ID: 92440784002 Collected: 08/08/19 11:41 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:33 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:33 7440-38-2 71.4 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:33 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:33 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:33 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:33 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:33 7440-48-4 ND ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:33 7440-50-8 ND ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:33 7439-92-1 ND ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:33 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:33 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:33 7440-22-4 ND ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:33 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:33 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 21:47 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 21:42 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 21:42 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 21:42 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 21:42 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 21:42 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 21:42 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 21:42 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 21:42 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 21:42 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 21:42 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 21:42 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 21:42 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 21:42 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 21:42 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 21:42 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 21:42 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 21:42 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 21:42 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 21:42 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 21:42 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 21:42 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 21:42 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 21:42 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 21:42 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 21:42 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 21:42 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 21:42 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW9 Lab ID: 92440784002 Collected: 08/08/19 11:41 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 08/15/19 21:42 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 21:42 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 21:42 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 21:42 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 21:42 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 21:42 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 21:42 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 21:42 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 21:42 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 21:42 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 21:42 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 21:42 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 21:42 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 21:42 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 21:42 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 21:42 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 21:42 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 21:42 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 21:42 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 21:42 1330-20-7 103 % 70-130 1 08/15/19 21:42 460-00-4 100 % 70-130 1 08/15/19 21:42 17060-07-0 101 % 70-130 1 08/15/19 21:42 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1916:01 123-91-1 98 % 50-150 1 08/12/1916:01 17060-07-0 105 % 50-150 1 08/12/1916:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW10 Lab ID: 92440784003 Collected: 08/08/19 11:15 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:43 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:43 7440-38-2 60.5 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:43 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:43 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:43 7440-43-9 1.0J ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:43 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:43 7440-48-4 6.9 ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:43 7440-50-8 ND ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:43 7439-92-1 1.6J ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:43 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:43 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:43 7440-22-4 5.3 ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:43 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:43 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 21:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 21:59 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 21:59 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 21:59 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 21:59 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 21:59 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 21:59 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 21:59 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 21:59 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 21:59 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 21:59 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 21:59 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 21:59 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 21:59 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 21:59 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 21:59 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 21:59 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 21:59 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 21:59 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 21:59 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 21:59 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 21:59 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 21:59 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 21:59 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 21:59 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 21:59 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 21:59 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 21:59 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW10 Lab ID: 92440784003 Collected: 08/08/19 11:15 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 08/15/19 21:59 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 21:59 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 21:59 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 21:59 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 21:59 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 21:59 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 21:59 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 21:59 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 21:59 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 21:59 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 21:59 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 21:59 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 21:59 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 21:59 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 21:59 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 21:59 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 21:59 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 21:59 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 21:59 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 21:59 1330-20-7 104 % 70-130 1 08/15/19 21:59 460-00-4 101 % 70-130 1 08/15/19 21:59 17060-07-0 101 % 70-130 1 08/15/19 21:59 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1916:21 123-91-1 102 % 50-150 1 08/12/1916:21 17060-07-0 108 % 50-150 1 08/12/1916:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW11 Lab ID: 92440784004 Collected: 08/08/19 11:02 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:46 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:46 7440-38-2 30.1 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:46 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:46 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:46 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:46 7440-47-3 1.2J ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:46 7440-48-4 ND ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:46 7440-50-8 ND ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:46 7439-92-1 3.2J ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:46 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:46 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:46 7440-22-4 1.8J ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:46 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:46 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 21:58 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 22:16 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 22:16 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 22:16 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 22:16 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 22:16 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 22:16 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 22:16 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 22:16 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 22:16 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 22:16 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 22:16 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 22:16 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 22:16 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 22:16 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 22:16 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 22:16 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 22:16 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 22:16 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 22:16 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 22:16 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 22:16 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 22:16 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 22:16 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 22:16 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 22:16 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 22:16 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 22:16 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-MW11 Lab ID: 92440784004 Collected: 08/08/19 11:02 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 08/15/19 22:16 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 22:16 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 22:16 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 22:16 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 22:16 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 22:16 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 22:16 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 22:16 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 22:16 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 22:16 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 22:16 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 22:16 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 22:16 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 22:16 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 22:16 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 22:16 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 22:16 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 22:16 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 22:16 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 22:16 1330-20-7 103 % 70-130 1 08/15/19 22:16 460-00-4 101 % 70-130 1 08/15/19 22:16 17060-07-0 102 % 70-130 1 08/15/19 22:16 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1916:40 123-91-1 99 % 50-150 1 08/12/1916:40 17060-07-0 105 % 50-150 1 08/12/1916:40 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-SW3 Lab ID: 92440784005 Collected: 08/08/19 11:55 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:49 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:49 7440-38-2 23.3 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:49 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:49 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:49 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:49 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:49 7440-48-4 2.7J ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:49 7440-50-8 ND ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:49 7439-92-1 ND ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:49 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:49 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:49 7440-22-4 17400 ug/L 662 131 1 08/15/19 10:21 08/17/19 00:49 3.3J ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:49 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:49 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 22:06 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 22:34 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 22:34 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 22:34 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 22:34 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 22:34 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 22:34 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 22:34 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 22:34 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 22:34 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 22:34 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 22:34 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 22:34 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 22:34 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 22:34 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 22:34 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 22:34 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 22:34 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 22:34 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 22:34 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 22:34 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 22:34 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 22:34 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 22:34 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 22:34 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 22:34 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 22:34 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-SW3 Lab ID: 92440784005 Collected: 08/08/19 11:55 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.19 1 08/15/19 22:34 78-87-5 ND ug/L 1.0 0.30 1 08/15/19 22:34 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 22:34 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 22:34 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 22:34 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 22:34 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 22:34 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 22:34 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 22:34 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 22:34 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 22:34 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 22:34 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 22:34 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 22:34 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 22:34 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 22:34 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 22:34 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 22:34 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 22:34 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 22:34 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 22:34 1330-20-7 104 % 70-130 1 08/15/19 22:34 460-00-4 99 % 70-130 1 08/15/19 22:34 17060-07-0 101 % 70-130 1 08/15/19 22:34 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1916:59 123-91-1 100 % 50-150 1 08/12/1916:59 17060-07-0 105 % 50-150 1 08/12/1916:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-SW4 Lab ID: 92440784006 Collected: 08/08/19 11:30 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Date: 08/19/2019 01:06 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 10:21 08/17/19 00:52 7440-36-0 6.1J ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:52 7440-38-2 44.5 ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:52 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 10:21 08/17/19 00:52 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 10:21 08/17/19 00:52 7440-43-9 2.2J ug/L 5.0 1.0 1 08/15/19 10:21 08/17/19 00:52 7440-47-3 2.9J ug/L 5.0 1.1 1 08/15/19 10:21 08/17/19 00:52 7440-48-4 2.7J ug/L 5.0 2.1 1 08/15/19 10:21 08/17/19 00:52 7440-50-8 1.6J ug/L 5.0 1.6 1 08/15/19 10:21 08/17/19 00:52 7439-92-1 1.91 ug/L 5.0 0.90 1 08/15/19 10:21 08/17/19 00:52 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 10:21 08/17/19 00:52 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 10:21 08/17/19 00:52 7440-22-4 28200 ug/L 662 131 1 08/15/19 10:21 08/17/19 00:52 7.9 ug/L 5.0 1.3 1 08/15/19 10:21 08/17/19 00:52 7440-62-2 7.2J ug/L 10.0 3.9 1 08/15/19 10:21 08/17/19 00:52 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 22:10 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 22:51 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 22:51 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 22:51 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 22:51 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 22:51 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 22:51 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 22:51 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 22:51 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 22:51 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 22:51 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 22:51 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 22:51 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 22:51 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 22:51 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 22:51 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 22:51 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 22:51 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 22:51 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 22:51 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 22:51 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 22:51 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 22:51 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 22:51 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 22:51 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 22:51 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 22:51 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1 Page 16 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 Sample: 3901-SW4 Lab ID: 92440784006 Collected: 08/08/19 11:30 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 08/19/2019 01:06 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.19 1 08/15/19 22:51 78-87-5 ND ug/L 1.0 0.30 1 08/15/19 22:51 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 22:51 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 22:51 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 22:51 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 22:51 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 22:51 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 22:51 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 22:51 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 22:51 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 22:51 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 22:51 127-18-4 ND ug/L 1.0 0.24 1 08/15/19 22:51 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 22:51 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 22:51 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 22:51 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 22:51 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 22:51 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 22:51 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 22:51 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 22:51 1330-20-7 104 % 70-130 1 08/15/19 22:51 460-00-4 99 % 70-130 1 08/15/19 22:51 17060-07-0 102 % 70-130 1 08/15/19 22:51 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/12/1917:19 123-91-1 107 % 50-150 1 08/12/1917:19 17060-07-0 106 % 50-150 1 08/12/1917:19 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 QC Batch: 492378 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 METHOD BLANK: 2654936 Matrix: Water Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 08/17/19 00:05 Arsenic ug/L ND 10.0 4.7 08/17/19 00:05 Barium ug/L ND 5.0 1.0 08/17/19 00:05 Beryllium ug/L ND 1.0 0.20 08/17/19 00:05 Cadmium ug/L ND 1.0 0.40 08/17/19 00:05 Chromium ug/L ND 5.0 1.0 08/17/19 00:05 Cobalt ug/L ND 5.0 1.1 08/17/19 00:05 Copper ug/L ND 5.0 2.1 08/17/19 00:05 Hardness, Total(SM 2340B) ug/L ND 662 131 08/17/19 00:05 Lead ug/L ND 5.0 1.6 08/17/19 00:05 Nickel ug/L ND 5.0 0.90 08/17/19 00:05 Selenium ug/L ND 10.0 4.7 08/17/19 00:05 Silver ug/L ND 5.0 2.5 08/17/19 00:05 Vanadium ug/L ND 5.0 1.3 08/17/19 00:05 Zinc ug/L ND 10.0 3.9 08/17/19 00:05 LABORATORY CONTROL SAMPLE: 2654937 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 502 100 80-120 Arsenic ug/L 500 472 94 80-120 Barium ug/L 500 522 104 80-120 Beryllium ug/L 500 491 98 80-120 Cadmium ug/L 500 498 100 80-120 Chromium ug/L 500 499 100 80-120 Cobalt ug/L 500 496 99 80-120 Copper ug/L 500 510 102 80-120 Hardness, Total(SM 2340B) ug/L 33100 32300 98 80-120 Lead ug/L 500 492 98 80-120 Nickel ug/L 500 495 99 80-120 Selenium ug/L 500 482 96 80-120 Silver ug/L 250 248 99 80-120 Vanadium ug/L 500 492 98 80-120 Zinc ug/L 500 471 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2654938 MS 92440784001 Spike Units Result Conc. MSD Spike Conc. 2654939 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Antimony ug/L ND 500 500 488 500 98 100 75-125 2 20 Arsenic ug/L ND 500 500 466 474 93 94 75-125 2 20 Barium ug/L 40.2 500 500 542 546 100 101 75-125 1 20 Beryllium ug/L ND 500 500 478 481 96 96 75-125 1 20 Cadmium ug/L ND 500 500 490 498 98 100 75-125 2 20 Chromium ug/L ND 500 500 484 491 97 98 75-125 1 20 Cobalt ug/L ND 500 500 473 480 95 96 75-125 1 20 Copper ug/L 8.3 500 500 498 503 98 99 75-125 1 20 Hardness, Total(SM 2340B) ug/L 108000 33100 33100 136000 138000 85 91 75-125 1 Lead ug/L ND 500 500 473 479 95 96 75-125 1 20 Nickel ug/L ND 500 500 472 479 94 96 75-125 1 20 Selenium ug/L ND 500 500 492 504 98 100 75-125 2 20 Silver ug/L ND 250 250 242 244 97 98 75-125 1 20 Vanadium ug/L ND 500 500 479 486 96 97 75-125 1 20 Zinc ug/L ND 500 500 465 470 93 94 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 QC Batch: 492377 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 METHOD BLANK: 2654906 Matrix: Water Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 08/15/19 20:43 LABORATORY CONTROL SAMPLE: 2654907 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.7 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2654908 2654909 MS MSD 92440783001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.6 9.8 96 98 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 QC Batch: 492312 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 METHOD BLANK: 2654368 Matrix: Water Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 08/15/19 19:40 1,1,1-Trichloroethane ug/L ND 1.0 0.18 08/15/19 19:40 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 08/15/19 19:40 1,1,2-Trichloroethane ug/L ND 1.0 0.24 08/15/19 19:40 1,1-Dichloroethane ug/L ND 1.0 0.27 08/15/19 19:40 1,1-Dichloroethene ug/L ND 1.0 0.24 08/15/19 19:40 1,2,3-Trichloropropane ug/L ND 1.0 0.35 08/15/19 19:40 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 08/15/19 19:40 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 08/15/19 19:40 1,2-Dichlorobenzene ug/L ND 1.0 0.29 08/15/19 19:40 1,2-Dichloroethane ug/L ND 1.0 0.34 08/15/19 19:40 1,2-Dichloropropane ug/L ND 1.0 0.19 08/15/19 19:40 1,4-Dichlorobenzene ug/L ND 1.0 0.26 08/15/19 19:40 2-Butanone (MEK) ug/L ND 5.0 3.3 08/15/19 19:40 2-Hexanone ug/L ND 5.0 0.57 08/15/19 19:40 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 08/15/19 19:40 Acetone ug/L ND 25.0 6.2 08/15/19 19:40 Acrylonitrile ug/L ND 10.0 0.90 08/15/19 19:40 Benzene ug/L ND 1.0 0.15 08/15/19 19:40 Bromochloromethane ug/L ND 1.0 0.34 08/15/19 19:40 Bromodichloromethane ug/L ND 1.0 0.26 08/15/19 19:40 Bromoform ug/L ND 1.0 0.62 08/15/19 19:40 Bromomethane ug/L ND 2.0 0.62 08/15/19 19:40 Carbon disulfide ug/L ND 2.0 0.40 08/15/19 19:40 Carbon tetrachloride ug/L ND 1.0 0.22 08/15/19 19:40 Chlorobenzene ug/L ND 1.0 0.23 08/15/19 19:40 Chloroethane ug/L ND 1.0 0.49 08/15/19 19:40 Chloroform ug/L ND 5.0 2.3 08/15/19 19:40 Chloromethane ug/L ND 1.0 0.39 08/15/19 19:40 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 08/15/19 19:40 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 08/15/19 19:40 Dibromochloromethane ug/L ND 1.0 0.41 08/15/19 19:40 Dibromomethane ug/L ND 1.0 0.46 08/15/19 19:40 Ethylbenzene ug/L ND 1.0 0.26 08/15/19 19:40 lodomethane ug/L ND 20.0 12.5 08/15/19 19:40 Methylene Chloride ug/L ND 5.0 3.7 08/15/19 19:40 Styrene ug/L ND 1.0 0.27 08/15/19 19:40 Tetrachloroethene ug/L ND 1.0 0.16 08/15/19 19:40 Toluene ug/L ND 1.0 0.24 08/15/19 19:40 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 08/15/19 19:40 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 08/15/19 19:40 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 METHOD BLANK: 2654368 Matrix: Water Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 08/15/19 19:40 Trichloroethene ug/L ND 1.0 0.22 08/15/19 19:40 Trichlorofluoromethane ug/L ND 1.0 0.31 08/15/19 19:40 Vinyl acetate ug/L ND 2.0 1.4 08/15/19 19:40 Vinyl chloride ug/L ND 1.0 0.24 08/15/19 19:40 Xylene (Total) ug/L ND 1.0 0.63 08/15/19 19:40 1,2-Dichloroethane-d4 (S) % 99 70-130 08/15/19 19:40 4-Bromofluorobenzene (S) % 106 70-130 08/15/19 19:40 Toluene-d8 (S) % 101 70-130 08/15/19 19:40 LABORATORY CONTROL SAMPLE: Parameter 2654369 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.1 108 70-130 1,1,1-Trichloroethane ug/L 50 50.9 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.1 100 70-130 1,1,2-Trichloroethane ug/L 50 52.4 105 70-130 1,1-Dichloroethane ug/L 50 51.0 102 70-130 1,1-Dichloroethene ug/L 50 51.9 104 70-130 1,2,3-Trichloropropane ug/L 50 51.8 104 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.8 102 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.6 105 70-130 1,2-Dichlorobenzene ug/L 50 48.9 98 70-130 1,2-Dichloroethane ug/L 50 47.2 94 70-130 1,2-Dichloropropane ug/L 50 51.3 103 70-130 1,4-Dichlorobenzene ug/L 50 49.2 98 70-130 2-Butanone (MEK) ug/L 100 106 106 64-135 2-Hexanone ug/L 100 109 109 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 110 110 70-130 Acetone ug/L 100 104 104 61-157 Acrylonitrile ug/L 250 255 102 61-143 Benzene ug/L 50 51.7 103 70-130 Bromochloromethane ug/L 50 53.9 108 70-130 Bromodichloromethane ug/L 50 53.8 108 70-130lK Bromoform ug/L 50 55.3 111 70-130 Bromomethane ug/L 50 50.4 101 38-130 Carbon disulfide ug/L 50 47.7 95 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 50.1 100 70-130 Chloroethane ug/L 50 40.8 82 37-142 Chloroform ug/L 50 50.5 101 70-130 Chloromethane ug/L 50 46.1 92 48-130 cis-1,2-Dichloroethene ug/L 50 49.8 100 70-130 cis-1,3-Dichloropropene ug/L 50 56.2 112 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 31 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 LABORATORY CONTROL SAMPLE: 2654369 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 54.5 109 70-130 Dibromomethane ug/L 50 51.2 102 70-130 Ethylbenzene ug/L 50 51.3 103 70-130 lodomethane ug/L 100 78.4 78 40-1301K Methylene Chloride ug/L 50 47.6 95 67-132 Styrene ug/L 50 51.7 103 70-130 Tetrachloroethene ug/L 50 51.8 104 69-130 Toluene ug/L 50 50.1 100 70-130 trans-1,2-Dichloroethene ug/L 50 50.7 101 70-130 trans- 1,3-Dichloropropene ug/L 50 55.9 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 57.6 115 35-189 Trichloroethene ug/L 50 51.3 103 70-130 Trichlorofluoromethane ug/L 50 49.4 99 63-130 Vinyl acetate ug/L 100 114 114 55-143 Vinyl chloride ug/L 50 48.3 97 70-131 Xylene (Total) ug/L 150 155 103 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: 2654371 92440784006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.6 108 73-134 1,1,1-Trichloroethane ug/L ND 20 22.6 113 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.1 106 70-136 1,1,2-Trichloroethane ug/L ND 20 21.3 107 70-135 1,1-Dichloroethane ug/L ND 20 22.9 115 70-139 1,1-Dichloroethene ug/L ND 20 23.9 120 70-154 1,2,3-Trichloropropane ug/L ND 20 22.3 112 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 19.0 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.0 105 70-137 1,2-Dichlorobenzene ug/L ND 20 20.6 103 70-133 1,2-Dichloroethane ug/L ND 20 21.0 105 70-137 1,2-Dichloropropane ug/L ND 20 22.1 111 70-140 1,4-Dichlorobenzene ug/L ND 20 20.5 102 70-133 2-Butanone (MEK) ug/L ND 40 43.0 108 60-139 2-Hexanone ug/L ND 40 42.6 107 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 42.1 105 65-135 Acetone ug/L ND 40 53.0 132 60-148 Acrylonitrile ug/L ND 100 109 109 64-147 Benzene ug/L ND 20 22.8 114 70-151 Bromochloromethane ug/L ND 20 24.1 121 70-141 Bromodichloromethane ug/L ND 20 21.9 110 70-138 Bromoform ug/L ND 20 19.9 99 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 MATRIX SPIKE SAMPLE: Parameter 2654371 Units 92440784006 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 19.9 99 15-152 Carbon disulfide ug/L ND 20 25.3 127 69-149 Carbon tetrachloride ug/L ND 20 22.3 111 70-143 Chlorobenzene ug/L ND 20 21.1 105 70-138 Chloroethane ug/L ND 20 24.9 125 52-163 Chloroform ug/L ND 20 22.1 111 70-139 Chloromethane ug/L ND 20 28.6 143 41-139 M1 cis-1,2-Dichloroethene ug/L ND 20 22.3 111 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.7 114 70-137 Dibromochloromethane ug/L ND 20 20.6 103 70-134 Dibromomethane ug/L ND 20 20.8 104 70-138 Ethylbenzene ug/L ND 20 22.3 111 66-153 lodomethane ug/L ND 40 42.9 107 20-138 Methylene Chloride ug/L ND 20 22.3 111 42-159 Styrene ug/L ND 20 21.6 108 70-135 Tetrachloroethene ug/L ND 20 21.6 108 59-143 Toluene ug/L ND 20 21.6 108 59-148 trans-1,2-Dichloroethene ug/L ND 20 23.1 115 70-146 trans- 1,3-Dichloropropene ug/L ND 20 22.0 110 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 20.9 104 47-135 Trichloroethene ug/L ND 20 22.1 111 70-147 Trichlorofluoromethane ug/L ND 20 22.9 114 70-148 Vinyl acetate ug/L ND 40 45.5 114 49-151 Vinyl chloride ug/L ND 20 22.9 115 70-156 Xylene (Total) ug/L ND 60 66.2 110 63-158 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 2654370 Parameter Units 92440784005 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 SAMPLE DUPLICATE: 2654370 Parameter Units 92440784005 Result Dup Result 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND 10.2J Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 99 101 4-Bromofluorobenzene (S) % 104 104 Toluene-d8(S) % 101 100 Max RPD RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 QC Batch: 492032 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 METHOD BLANK: 2653245 Matrix: Water Associated Lab Samples: 92440784001, 92440784002, 92440784003, 92440784004, 92440784005, 92440784006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 08/12/19 12:09 1,2-Dichloroethane-d4 (S) % 97 50-150 08/12/19 12:09 Toluene-d8 (S) % 103 50-150 08/12/19 12:09 LABORATORY CONTROL SAMPLE: 2653246 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 18.9 94 70-130 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 103 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2653247 2653248 MS MSD 92440795005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 4.0 20 20 21.8 22.3 89 92 50-150 2 30 1,2-Dichloroethane-d4 (S) % 98 100 50-150 30 Toluene-d8 (S) % 102 102 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 31 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Oxford Compliance Unit 2 Pace Project No.: 92440784 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/19/2019 01:06 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 31 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Oxford Compliance Unit 2 92440784 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92440784001 3901-MW8 EPA 3010A 492378 EPA6010D 492489 92440784002 3901-MW9 EPA 3010A 492378 EPA6010D 492489 92440784003 3901-MW10 EPA 3010A 492378 EPA6010D 492489 92440784004 3901-MW11 EPA 3010A 492378 EPA6010D 492489 92440784005 3901-SW3 EPA 3010A 492378 EPA6010D 492489 92440784006 3901-SW4 EPA 3010A 492378 EPA6010D 492489 92440784001 3901-MW8 EPA 3010A 492377 EPA 6020B 492487 92440784002 3901-MW9 EPA 3010A 492377 EPA 6020B 492487 92440784003 3901-MW10 EPA 3010A 492377 EPA 6020B 492487 92440784004 3901-MW11 EPA 3010A 492377 EPA 6020B 492487 92440784005 3901-SW3 EPA 3010A 492377 EPA 6020B 492487 92440784006 3901-SW4 EPA 3010A 492377 EPA 6020B 492487 92440784001 3901-MW8 EPA 8260D 492312 92440784002 3901-MW9 EPA8260D 492312 92440784003 3901-MW10 EPA8260D 492312 92440784004 3901-MW11 EPA8260D 492312 92440784005 3901-SW3 EPA8260D 492312 92440784006 3901-SW4 EPA8260D 492312 92440784001 3901-MW8 EPA8260D Mod. 492032 92440784002 3901-MW9 EPA8260D Mod. 492032 92440784003 3901-MW10 EPA8260D Mod. 492032 92440784004 3901-MW11 EPA8260D Mod. 492032 92440784005 3901-SW3 EPA8260D Mod. 492032 92440784006 3901-SW4 EPA8260D Mod. 492032 Date: 08/19/2019 01:06 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 31 uocument Name: uocument nevaw: rear udiy /, c�aa Sample Condition Upon Receipt(SOUR) Page 1 of 2 ,:c3C�Aff�!ffGl Document No.: Issuing Authority: i F•CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville ( Raleigh[] Mechanicsville[] Sample Condition Client NaMe: up-OnReceipt Project 9: N, Courier: ❑F Ex []UPS ❑LISPS []Client ❑ Commercial [� ace ❑Other: Custody Seal Present? ❑Yes No Seals Intact? []Yes No Packing Material. Bubble Wrap Bubble Bags []None ❑ Other Therrhameier� 92TO48 Type of ice: et ❑Blue lii Gun {p: Cooler Terrip ('C): I , I .T Correction Factor: Add/Subtract ('C) 0.0 Cooler Temp Corrected ('C): USDA Regulated5oil (EI/N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? f—iYP,; FINn WO#:92440784 1111111111111111111111 92440784 Date/initials Person Examining Contints: Biological Tissue Fr�zen? []Yes[]Nol/A []None Tempshould be above freezing to VC ❑samples out of temp criteria. Samples on ice, cooling process hasbegun Did samples originate from a foreign source (internationally, inrhidingHawaii and Puerto RICo17 MYes 11No Comments/Discrepancy: Chain of CuStady Present? QY//es ❑No ❑N/A 1. Samples Arrived within Hold Time? .. [Des []No ❑N/A 2. Short Hold -Time Analysis (�72 hr.)? ❑Yes No ❑N/A 3. Rush Turn Around Time Requested? []Yes ®a ❑N/A 4. Sufficient Volume? a Yes ❑Na ❑N/A S. Correct Containers Used? lY ❑No []N/A 6. -Pace Containers Used? Yes []No ©N/A Containers Intact? 014's ©Nn [jN/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No 9f4/A 8. Sample Labels Match COC? es []No ❑N/A 9. -includes Date/Time/ID/Analysis Matrix: WI Head space in VOA Vials (>5-6mm)? []Yes []NO NJA 10, Trip Blank Present? []Yes ❑No 0�lA 11. Trip BlankCuStodY5ea15 Present? ❑Yes ❑No OH/A COMMENTS/SAMPLE DISCREPANCY Lot 10 of Iplit containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: NW19 Date/Time: Field Data Required? []Yes [—]No Date: Date: 3 1 1 7 Page 29 of 31 {,l�aceAnal�tical Luri umurl Lijuil nmciinji Lwni _o_ - -' - Document No.: Issuing Authority: F CAR CS-033-RevAfi Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/9015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Projectii WO# : 92440784 PM: NMG Due Date: 08/23/19 CLIENT: 92-Joyce Eng z p u v a "' z z z a a. z N z z = I M 'p v -a .z. N N a - � ? y N v L.f � 2 ' I ail y z '[7 a a a v ^ Z N 2 a v z z a E Z ¢ \ a z \ z Z Z N a a a �v a N v n # Z Z- ,� m LD n ry d m a a a A a n v v b m O a A m o 2 CL c a Q Z m O Q Z a v1 o n u c ? C c 0 7 a G N z Z z ra z f7 ' V O 14 r1Jrel -N Q `� vryi N a Q L ;� ? ,y, A a y z at z m m _ro a m ? C o E E E ¢ E 4 r`nv O q O O a as N W a Q J u G 0. M d d G- J G. Q a Q J > > lai N J J E a V J E E E E E 5 E ro «'. o ? E M E E E } E of o E E N Ln C3 Y+ — Ln N ,n N N S 7 _ e-/ —_ 'i N N = ri O N ' O O O It 0 .La S v1 .N-[ ❑ N to ry 1- r. ❑ V .� 3 N try 7 rl 7 vi ,il N Z r[ d �-1 U z x 7 vl ,s, Q x Ol F- 7 0 a 0 be a >9 F= F:. 4 en 7 a a 0 7 Q1 a d II a as 6 1-I i7 ri t7 Rt l7 ri U' 1+1 L7 M l7 l7 QI l7 r7 U O L? \ N a N 0. a L9 N Lo 0. Co m m b m a m m m m a a a a a a c >> o> n rn � m a c '\�. I - --- \ t z . I 3 XV 4 } 6 S � v 7 B 9 1D 11 INN 1 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon retelpt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot it ff Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Caroil na DEHNR Certuf cation 0 rce {I.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 30 of 31 o CHAIN -OF -CUSTODY 1 Analytical Request Document M The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. � Section A Sec!}on 8 Section C d Required Client Information: Required Project Information: Invoice Information: Company I La Bella Associates Reporl To. Van Burbach Allenticn: Jason Falls Page 1 Of 1 Address 2211 West Meadowvicw Rd Greensboro, NC 27407 Copy Tc�. Ml uel Vazquez Company Name: Granville County, Solid Waste Email To: i vburbach o teen ineerin com Purchase Order No. Address: P.O. Box 906, Oxford NC 27565 Regulatory Agency Phone: 336 323-0092 ax Client Project ID: Oxford Compliance Unit 2 Requested Due Date/TAT: 10 Da -Default Container Order Number: 3566-3 Slate! Location North Carolina Re uested Analysis Filtered CY!N MATRIx 011-19 Wljr, CODE DW — o U COLLECTED z 2 Preservatives SAMPLE ID W,etrr W:ialiWarir Proavcl SoVZid WT yyW P 51 m U O W One Character per box. 4n w,P' or wp „ — 0 w START END U w ~ N iy a > d c C (A-Z, 0-9 f. _) Sample Ids must be unique wr 41ner AR OT o D U a F z Q z m C' — N �' Q CL ?C p � o L rJ LLI T-- Ts X w a TIATZTIIE w O w a O 0 m is Q 0 C 'd r a = DATE TIME u- a x a 2 z 2 c� 2 0 2 z t m c 0 Q¢ U z U z V r= t>3 _ 1 1 3901-MWB wr G X X Ix I I I I I . 2 3901-MW9 wT IVVTIG G 1 1 114[ 7 >< Ix 3 3901-MW10 11 S 7 X X 4 3901-MW11 wT G LE 110Z % X X X C a 5 3901-SW3 wT G `5 �q 11 S5 X X X X q C� 6 3901-SW4 wr G q 8 I�i Iv. o X X X X C 7 8 S 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME CCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS G4ge1 lq ro: Lo ` MW-7, NES-2S. NES-2D are duplicates of samples from Oxford �/ If possible, only tun analayses once. but report far both. SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER: U o m z SIGNATURE of DATE Signed: �/+ 9 } —" z / �9 I- C= L) c i n r aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 20, 2019 Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Dear Van Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 38 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Lab ID Sample ID Matrix Date Collected Date Received 92440808001 3901-MW7 Water 08/08/1912:50 08/09/19 10:20 92440808002 3901 - Field Blank Water 08/08/19 20:05 08/09/19 10:20 92440808003 3901 - NES2S Water 08/08/19 14:52 08/09/19 10:20 92440808004 3901 - Trip Blank Water 08/06/19 05:45 08/09/19 10:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Oxford Unit 1&2 Blanks & Joint 92440808 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92440808001 3901-MW7 EPA 601OD IDS 16 PASI-A EPA 6020E JOR 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 2540C-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A SM 4500-CI-E-2011 KDF1 1 PASI-A 92440808002 3901 - Field Blank EPA 601 OD IDS 16 PASI-A EPA 6020E JOR 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 2540C-2011 NAL 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A SM 4500-CI-E-2011 KDF1 1 PASI-A 92440808003 3901 - NES2S EPA 8260D CL 5 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92440808004 3901 - Trip Blank EPA 8260D CL 51 PASI-C EPA 8260D Mod. LMB 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Oxford Unit 1&2 Blanks & Joint 92440808 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92440808001 3901-MW7 EPA 601 OD Barium 4.5J ug/L 5.0 08/19/19 00:43 EPA 601 OD Copper 2.5J ug/L 5.0 08/19/19 00:43 EPA 601 OD Iron 176 ug/L 50.0 08/19/19 00:43 EPA 601 OD Manganese 6.0 ug/L 5.0 08/19/19 00:43 EPA 601 OD Nickel 0.93J ug/L 5.0 08/19/19 00:43 EPA 601 OD Vanadium 2.2J ug/L 5.0 08/19/19 00:43 SM 2320B-2011 Alkalinity, Total as CaCO3 140000 ug/L 5000 08/15/19 23:43 SM 2540C-2011 Total Dissolved Solids 256000 ug/L 25000 08/12/19 13:46 EPA 300.0 Rev 2.1 1993 Sulfate 51500 ug/L 1000 08/11 /19 04:33 SM 4500-CI-E-2011 Chloride 10100 ug/L 1000 08/13/19 13:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901-MW7 Lab ID: 92440808001 Collected: 08/08/19 12:50 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane Date: 08/20/2019 03:24 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 17:10 08/19/19 00:43 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 17:10 08/19/19 00:43 7440-38-2 4.5J ug/L 5.0 1.0 1 08/15/19 17:10 08/19/19 00:43 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 17:10 08/19/19 00:43 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 17:10 08/19/19 00:43 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 17:10 08/19/19 00:43 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 17:10 08/19/19 00:43 7440-48-4 2.5J ug/L 5.0 2.1 1 08/15/19 17:10 08/19/19 00:43 7440-50-8 176 ug/L 50.0 19.5 1 08/15/19 17:10 08/19/19 00:43 7439-89-6 ND ug/L 5.0 1.6 1 08/15/19 17:10 08/19/19 00:43 7439-92-1 6.0 ug/L 5.0 0.90 1 08/15/19 17:10 08/19/19 00:43 7439-96-5 0.93J ug/L 5.0 0.90 1 08/15/19 17:10 08/19/19 00:43 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 17:10 08/19/19 00:43 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 17:10 08/19/19 00:43 7440-22-4 2.2J ug/L 5.0 1.3 1 08/15/19 17:10 08/19/19 00:43 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 17:10 08/19/19 00:43 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/1917:17 08/16/1913:49 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 08/12/1910:39 08/13/1912:43 7439-97-6 Analytical Method: EPA 8260D ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 08/16/19 01:09 67-64-1 0.90 1 08/16/19 01:09 107-13-1 0.15 1 08/16/19 01:09 71-43-2 0.34 1 08/16/19 01:09 74-97-5 0.26 1 08/16/19 01:09 75-27-4 0.62 1 08/16/19 01:09 75-25-2 0.62 1 08/16/19 01:09 74-83-9 3.3 1 08/16/19 01:09 78-93-3 0.40 1 08/16/19 01:09 75-15-0 0.22 1 08/16/19 01:09 56-23-5 0.23 1 08/16/19 01:09 108-90-7 0.49 1 08/16/19 01:09 75-00-3 2.3 1 08/16/19 01:09 67-66-3 0.39 1 08/16/19 01:09 74-87-3 0.26 1 08/16/19 01:09 96-12-8 0.41 1 08/16/19 01:09 124-48-1 0.26 1 08/16/19 01:09 106-93-4 0.46 1 08/16/19 01:09 74-95-3 0.29 1 08/16/19 01:09 95-50-1 0.26 1 08/16/19 01:09 106-46-7 0.54 1 08/16/19 01:09 110-57-6 0.27 1 08/16/19 01:09 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901-MW7 Lab ID: 92440808001 Collected: 08/08/19 12:50 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 2540C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate Date: 08/20/2019 03:24 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.34 1 08/16/19 01:09 107-06-2 ND ug/L 1.0 0.24 1 08/16/19 01:09 75-35-4 ND ug/L 1.0 0.29 1 08/16/19 01:09 156-59-2 ND ug/L 1.0 0.25 1 08/16/19 01:09 156-60-5 ND ug/L 1.0 0.19 1 08/16/19 01:09 78-87-5 ND ug/L 1.0 0.30 1 08/16/19 01:09 10061-01-5 ND ug/L 1.0 0.31 1 08/16/19 01:09 10061-02-6 ND ug/L 1.0 0.26 1 08/16/19 01:09 100-41-4 ND ug/L 5.0 0.57 1 08/16/19 01:09 591-78-6 ND ug/L 20.0 12.5 1 08/16/19 01:09 74-88-4 ND ug/L 5.0 3.7 1 08/16/19 01:09 75-09-2 ND ug/L 5.0 4.5 1 08/16/19 01:09 108-10-1 ND ug/L 1.0 0.27 1 08/16/19 01:09 100-42-5 ND ug/L 1.0 0.34 1 08/16/19 01:09 630-20-6 ND ug/L 1.0 0.22 1 08/16/19 01:09 79-34-5 ND ug/L 1.0 0.16 1 08/16/19 01:09 127-18-4 ND ug/L 10.0 1.9 1 08/16/19 01:09 109-99-9 ND ug/L 1.0 0.24 1 08/16/19 01:09 108-88-3 ND ug/L 1.0 0.18 1 08/16/19 01:09 71-55-6 ND ug/L 1.0 0.24 1 08/16/19 01:09 79-00-5 ND ug/L 1.0 0.22 1 08/16/19 01:09 79-01-6 ND ug/L 1.0 0.31 1 08/16/19 01:09 75-69-4 ND ug/L 1.0 0.35 1 08/16/19 01:09 96-18-4 ND ug/L 2.0 1.4 1 08/16/19 01:09 108-05-4 ND ug/L 1.0 0.24 1 08/16/19 01:09 75-01-4 ND ug/L 1.0 0.63 1 08/16/19 01:09 1330-20-7 105 % 70-130 1 08/16/19 01:09 460-00-4 102 % 70-130 1 08/16/19 01:09 17060-07-0 100 % 70-130 1 08/16/19 01:09 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/14/1914:56 123-91-1 107 % 50-150 1 08/14/1914:56 17060-07-0 104 % 50-150 1 08/14/1914:56 2037-26-5 Analytical Method: SM 2320B-2011 140000 ug/L 5000 5000 1 08/15/19 23:43 Analytical Method: SM 2540C-2011 256000 ug/L 25000 25000 1 08/12/1913:46 Analytical Method: EPA 300.0 Rev 2.1 1993 51500 ug/L 1000 500 1 08/11/19 04:33 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901-MW7 Lab ID: 92440808001 Collected: 08/08/19 12:50 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 10100 ug/L 1000 500 1 08/13/1913:45 16887-00-6 Date: 08/20/2019 03:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - Field Blank Lab ID: 92440808002 Collected: 08/08/19 20:05 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane Date: 08/20/2019 03:24 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 08/15/19 17:10 08/19/19 00:55 7440-36-0 ND ug/L 10.0 4.7 1 08/15/19 17:10 08/19/19 00:55 7440-38-2 ND ug/L 5.0 1.0 1 08/15/19 17:10 08/19/19 00:55 7440-39-3 ND ug/L 1.0 0.20 1 08/15/19 17:10 08/19/19 00:55 7440-41-7 ND ug/L 1.0 0.40 1 08/15/19 17:10 08/19/19 00:55 7440-43-9 ND ug/L 5.0 1.0 1 08/15/19 17:10 08/19/19 00:55 7440-47-3 ND ug/L 5.0 1.1 1 08/15/19 17:10 08/19/19 00:55 7440-48-4 ND ug/L 5.0 2.1 1 08/15/19 17:10 08/19/19 00:55 7440-50-8 ND ug/L 50.0 19.5 1 08/15/19 17:10 08/19/19 00:55 7439-89-6 ND ug/L 5.0 1.6 1 08/15/19 17:10 08/19/19 00:55 7439-92-1 ND ug/L 5.0 0.90 1 08/15/19 17:10 08/19/19 00:55 7439-96-5 ND ug/L 5.0 0.90 1 08/15/19 17:10 08/19/19 00:55 7440-02-0 ND ug/L 10.0 4.7 1 08/15/19 17:10 08/19/19 00:55 7782-49-2 ND ug/L 5.0 2.5 1 08/15/19 17:10 08/19/19 00:55 7440-22-4 ND ug/L 5.0 1.3 1 08/15/19 17:10 08/19/19 00:55 7440-62-2 ND ug/L 10.0 3.9 1 08/15/19 17:10 08/19/19 00:55 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 08/15/1917:17 08/16/1911:04 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 08/12/1910:39 08/13/1912:45 7439-97-6 Analytical Method: EPA 8260D ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.2 1 08/15/19 20:15 67-64-1 0.90 1 08/15/19 20:15 107-13-1 0.15 1 08/15/19 20:15 71-43-2 0.34 1 08/15/19 20:15 74-97-5 0.26 1 08/15/19 20:15 75-27-4 0.62 1 08/15/19 20:15 75-25-2 0.62 1 08/15/19 20:15 74-83-9 3.3 1 08/15/19 20:15 78-93-3 0.40 1 08/15/19 20:15 75-15-0 0.22 1 08/15/19 20:15 56-23-5 0.23 1 08/15/19 20:15 108-90-7 0.49 1 08/15/19 20:15 75-00-3 2.3 1 08/15/19 20:15 67-66-3 0.39 1 08/15/19 20:15 74-87-3 0.26 1 08/15/19 20:15 96-12-8 0.41 1 08/15/19 20:15 124-48-1 0.26 1 08/15/19 20:15 106-93-4 0.46 1 08/15/19 20:15 74-95-3 0.29 1 08/15/19 20:15 95-50-1 0.26 1 08/15/19 20:15 106-46-7 0.54 1 08/15/19 20:15 110-57-6 0.27 1 08/15/19 20:15 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - Field Blank Lab ID: 92440808002 Collected: 08/08/19 20:05 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 2540C Total Dissolved Solids Total Dissolved Solids 300.0 IC Anions 28 Days Sulfate Date: 08/20/2019 03:24 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.34 1 08/15/19 20:15 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 20:15 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 20:15 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 20:15 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 20:15 78-87-5 ND ug/L 1.0 0.30 1 08/15/19 20:15 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 20:15 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 20:15 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 20:15 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 20:15 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 20:15 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 20:15 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 20:15 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 20:15 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 20:15 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 20:15 127-18-4 ND ug/L 10.0 1.9 1 08/15/19 20:15 109-99-9 ND ug/L 1.0 0.24 1 08/15/19 20:15 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 20:15 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 20:15 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 20:15 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 20:15 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 20:15 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 20:15 108-05-4 ND ug/L 1.0 0.24 1 08/15/19 20:15 75-01-4 ND ug/L 1.0 0.63 1 08/15/19 20:15 1330-20-7 104 % 70-130 1 08/15/19 20:15 460-00-4 100 % 70-130 1 08/15/19 20:15 17060-07-0 102 % 70-130 1 08/15/19 20:15 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 08/14/1914:16 123-91-1 104 % 50-150 1 08/14/1914:16 17060-07-0 103 % 50-150 1 08/14/1914:16 2037-26-5 Analytical Method: SM 2320B-2011 ND ug/L 5000 5000 1 08/15/19 23:53 Analytical Method: SM 2540C-2011 ND ug/L 25000 25000 1 08/12/1913:46 Analytical Method: EPA 300.0 Rev 2.1 1993 ND ug/L 1000 500 1 08/11/19 04:48 14808-79-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - Field Blank Lab ID: 92440808002 Collected: 08/08/19 20:05 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride ND ug/L 1000 500 1 08/13/1913:48 16887-00-6 Date: 08/20/2019 03:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - NES2S Lab ID: 92440808003 Collected: 08/08/19 14:52 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D 1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/16/19 01:27 75-34-3 Vinyl chloride ND ug/L 1.0 0.24 1 08/16/19 01:27 75-01-4 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 08/16/19 01:27 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 08/16/19 01:27 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 08/16/19 01:27 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 08/14/19 15:16 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 108 % 50-150 1 08/14/19 15:16 17060-07-0 Toluene-d8 (S) 103 % 50-150 1 08/14/19 15:16 2037-26-5 Date: 08/20/2019 03:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - Trip Blank Lab ID: 92440808004 Collected: 08/06/19 05:45 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Date: 08/20/2019 03:24 PM Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 08/15/19 03:51 67-64-1 ND ug/L 10.0 0.90 1 08/15/19 03:51 107-13-1 ND ug/L 1.0 0.15 1 08/15/19 03:51 71-43-2 ND ug/L 1.0 0.34 1 08/15/19 03:51 74-97-5 ND ug/L 1.0 0.26 1 08/15/19 03:51 75-27-4 ND ug/L 1.0 0.62 1 08/15/19 03:51 75-25-2 ND ug/L 2.0 0.62 1 08/15/19 03:51 74-83-9 ND ug/L 5.0 3.3 1 08/15/19 03:51 78-93-3 ND ug/L 2.0 0.40 1 08/15/19 03:51 75-15-0 ND ug/L 1.0 0.22 1 08/15/19 03:51 56-23-5 ND ug/L 1.0 0.23 1 08/15/19 03:51 108-90-7 ND ug/L 1.0 0.49 1 08/15/19 03:51 75-00-3 ND ug/L 5.0 2.3 1 08/15/19 03:51 67-66-3 ND ug/L 1.0 0.39 1 08/15/19 03:51 74-87-3 ND ug/L 5.0 0.26 1 08/15/19 03:51 96-12-8 ND ug/L 1.0 0.41 1 08/15/19 03:51 124-48-1 ND ug/L 1.0 0.26 1 08/15/19 03:51 106-93-4 ND ug/L 1.0 0.46 1 08/15/19 03:51 74-95-3 ND ug/L 1.0 0.29 1 08/15/19 03:51 95-50-1 ND ug/L 1.0 0.26 1 08/15/19 03:51 106-46-7 ND ug/L 1.0 0.54 1 08/15/19 03:51 110-57-6 ND ug/L 1.0 0.27 1 08/15/19 03:51 75-34-3 ND ug/L 1.0 0.34 1 08/15/19 03:51 107-06-2 ND ug/L 1.0 0.24 1 08/15/19 03:51 75-35-4 ND ug/L 1.0 0.29 1 08/15/19 03:51 156-59-2 ND ug/L 1.0 0.25 1 08/15/19 03:51 156-60-5 ND ug/L 1.0 0.19 1 08/15/19 03:51 78-87-5 ND ug/L 1.0 0.30 1 08/15/19 03:51 10061-01-5 ND ug/L 1.0 0.31 1 08/15/19 03:51 10061-02-6 ND ug/L 1.0 0.26 1 08/15/19 03:51 100-41-4 ND ug/L 5.0 0.57 1 08/15/19 03:51 591-78-6 ND ug/L 20.0 12.5 1 08/15/19 03:51 74-88-4 ND ug/L 5.0 3.7 1 08/15/19 03:51 75-09-2 ND ug/L 5.0 4.5 1 08/15/19 03:51 108-10-1 ND ug/L 1.0 0.27 1 08/15/19 03:51 100-42-5 ND ug/L 1.0 0.34 1 08/15/19 03:51 630-20-6 ND ug/L 1.0 0.22 1 08/15/19 03:51 79-34-5 ND ug/L 1.0 0.16 1 08/15/19 03:51 127-18-4 ND ug/L 10.0 1.9 1 08/15/19 03:51 109-99-9 ND ug/L 1.0 0.24 1 08/15/19 03:51 108-88-3 ND ug/L 1.0 0.18 1 08/15/19 03:51 71-55-6 ND ug/L 1.0 0.24 1 08/15/19 03:51 79-00-5 ND ug/L 1.0 0.22 1 08/15/19 03:51 79-01-6 ND ug/L 1.0 0.31 1 08/15/19 03:51 75-69-4 ND ug/L 1.0 0.35 1 08/15/19 03:51 96-18-4 ND ug/L 2.0 1.4 1 08/15/19 03:51 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v2 Page 13 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 Sample: 3901 - Trip Blank Lab ID: 92440808004 Collected: 08/06/19 05:45 Received: 08/09/19 10:20 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Vinyl chloride ND ug/L 1.0 0.24 1 08/15/19 03:51 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 08/15/19 03:51 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 111 % 70-130 1 08/15/19 03:51 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-130 1 08/15/19 03:51 17060-07-0 Toluene-d8 (S) 105 % 70-130 1 08/15/19 03:51 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 08/14/19 14:36 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 107 % 50-150 1 08/14/19 14:36 17060-07-0 Toluene-d8 (S) 102 % 50-150 1 08/14/19 14:36 2037-26-5 Date: 08/20/2019 03:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 491690 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2651419 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 08/13/1912:07 LABORATORY CONTROL SAMPLE: 2651420 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 95 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2651421 2651422 MS MSD 92440783001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.2 2.3 86 93 75-125 8 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492603 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2655797 Associated Lab Samples: 92440808001, 92440808002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 08/19/19 00:30 Arsenic ug/L ND 10.0 4.7 08/19/19 00:30 Barium ug/L ND 5.0 1.0 08/19/19 00:30 Beryllium ug/L ND 1.0 0.20 08/19/19 00:30 Cadmium ug/L ND 1.0 0.40 08/19/19 00:30 Chromium ug/L ND 5.0 1.0 08/19/19 00:30 Cobalt ug/L ND 5.0 1.1 08/19/19 00:30 Copper ug/L ND 5.0 2.1 08/19/19 00:30 Iron ug/L ND 50.0 19.5 08/19/19 00:30 Lead ug/L ND 5.0 1.6 08/19/19 00:30 Manganese ug/L ND 5.0 0.90 08/19/19 00:30 Nickel ug/L ND 5.0 0.90 08/19/19 00:30 Selenium ug/L ND 10.0 4.7 08/19/19 00:30 Silver ug/L ND 5.0 2.5 08/19/19 00:30 Vanadium ug/L ND 5.0 1.3 08/19/19 00:30 Zinc ug/L ND 10.0 3.9 08/19/19 00:30 LABORATORY CONTROL SAMPLE: 2655798 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Iron ug/L Lead ug/L Manganese ug/L Nickel ug/L Selenium ug/L Silver ug/L Vanadium ug/L Zinc ug/L Spike Conc. LCS Result LCS % Rec % Rec Limits 500 518 104 80-120 500 498 100 80-120 500 512 102 80-120 500 514 103 80-120 500 506 101 80-120 500 508 102 80-120 500 513 103 80-120 500 514 103 80-120 5000 5130 103 80-120 500 510 102 80-120 500 512 102 80-120 500 508 102 80-120 500 504 101 80-120 250 255 102 80-120 500 515 103 80-120 500 507 101 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Oxford Unit 1&2 Blanks & Joint 92440808 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655799 2655800 MS MSD 92440808001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 510 505 102 101 75-125 1 20 Arsenic ug/L ND 500 500 495 489 99 98 75-125 1 20 Barium ug/L 4.5J 500 500 494 496 98 98 75-125 1 20 Beryllium ug/L ND 500 500 495 498 99 100 75-125 1 20 Cadmium ug/L ND 500 500 498 496 100 99 75-125 0 20 Chromium ug/L ND 500 500 499 498 100 100 75-125 0 20 Cobalt ug/L ND 500 500 489 485 98 97 75-125 1 20 Copper ug/L 2.5J 500 500 502 502 100 100 75-125 0 20 Iron ug/L 176 5000 5000 5160 5200 100 100 75-125 1 20 Lead ug/L ND 500 500 489 486 97 97 75-125 1 20 Manganese ug/L 6.0 500 500 505 502 100 99 75-125 1 20 Nickel ug/L 0.93J 500 500 482 479 96 96 75-125 1 20 Selenium ug/L ND 500 500 520 512 104 102 75-125 2 20 Silver ug/L ND 250 250 255 254 102 102 75-125 0 20 Vanadium ug/L 2.2J 500 500 514 510 102 102 75-125 1 20 Zinc ug/L ND 500 500 501 500 100 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492601 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2655785 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 08/16/1910:56 LABORATORY CONTROL SAMPLE: 2655786 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655787 2655788 MS MSD 92440808001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.9 10 99 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492152 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92440808004 METHOD BLANK: 2653683 Associated Lab Samples: 92440808004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 08/15/19 02:41 1,1,1-Trichloroethane ug/L ND 1.0 0.18 08/15/19 02:41 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 08/15/19 02:41 1,1,2-Trichloroethane ug/L ND 1.0 0.24 08/15/19 02:41 1,1-Dichloroethane ug/L ND 1.0 0.27 08/15/19 02:41 1,1-Dichloroethene ug/L ND 1.0 0.24 08/15/19 02:41 1,2,3-Trichloropropane ug/L ND 1.0 0.35 08/15/19 02:41 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 08/15/19 02:41 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 08/15/19 02:41 1,2-Dichlorobenzene ug/L ND 1.0 0.29 08/15/19 02:41 1,2-Dichloroethane ug/L ND 1.0 0.34 08/15/19 02:41 1,2-Dichloropropane ug/L ND 1.0 0.19 08/15/19 02:41 1,4-Dichlorobenzene ug/L ND 1.0 0.26 08/15/19 02:41 2-Butanone (MEK) ug/L ND 5.0 3.3 08/15/19 02:41 2-Hexanone ug/L ND 5.0 0.57 08/15/19 02:41 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 08/15/19 02:41 Acetone ug/L ND 25.0 6.2 08/15/19 02:41 Acrylonitrile ug/L ND 10.0 0.90 08/15/19 02:41 Benzene ug/L ND 1.0 0.15 08/15/19 02:41 Bromochloromethane ug/L ND 1.0 0.34 08/15/19 02:41 Bromodichloromethane ug/L ND 1.0 0.26 08/15/19 02:41 Bromoform ug/L ND 1.0 0.62 08/15/19 02:41 Bromomethane ug/L ND 2.0 0.62 08/15/19 02:41 Carbon disulfide ug/L ND 2.0 0.40 08/15/19 02:41 Carbon tetrachloride ug/L ND 1.0 0.22 08/15/19 02:41 Chlorobenzene ug/L ND 1.0 0.23 08/15/19 02:41 Chloroethane ug/L ND 1.0 0.49 08/15/19 02:41 Chloroform ug/L ND 5.0 2.3 08/15/19 02:41 Chloromethane ug/L ND 1.0 0.39 08/15/19 02:41 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 08/15/19 02:41 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 08/15/19 02:41 Dibromochloromethane ug/L ND 1.0 0.41 08/15/19 02:41 Dibromomethane ug/L ND 1.0 0.46 08/15/19 02:41 Ethylbenzene ug/L ND 1.0 0.26 08/15/19 02:41 lodomethane ug/L ND 20.0 12.5 08/15/19 02:41 Methylene Chloride ug/L ND 5.0 3.7 08/15/19 02:41 Styrene ug/L ND 1.0 0.27 08/15/19 02:41 Tetrachloroethene ug/L ND 1.0 0.16 08/15/19 02:41 Tetrahydrofuran ug/L ND 10.0 1.9 08/15/19 02:41 Toluene ug/L ND 1.0 0.24 08/15/19 02:41 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 08/15/19 02:41 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 METHOD BLANK: 2653683 Associated Lab Samples: 92440808004 Parameter Units trans- 1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2653684 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 106 70-130 110 70-130 104 70-130 MDL Analyzed 0.31 08/15/19 02:41 0.54 08/15/19 02:41 0.22 08/15/19 02:41 0.31 08/15/19 02:41 1.4 08/15/19 02:41 0.24 08/15/19 02:41 0.63 08/15/19 02:41 08/15/19 02:41 08/15/19 02:41 08/15/19 02:41 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 49.7 99 70-130 1,1,1-Trichloroethane ug/L 50 53.4 107 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.2 100 70-130 1,1,2-Trichloroethane ug/L 50 53.3 107 70-130 1,1-Dichloroethane ug/L 50 54.8 110 70-130 1,1-Dichloroethene ug/L 50 55.4 111 70-130 1,2,3-Trichloropropane ug/L 50 52.3 105 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.1 100 70-130 1,2-Dibromoethane (EDB) ug/L 50 49.6 99 70-130 1,2-Dichlorobenzene ug/L 50 43.9 88 70-130 1,2-Dichloroethane ug/L 50 51.6 103 70-130 1,2-Dichloropropane ug/L 50 52.2 104 70-130 1,4-Dichlorobenzene ug/L 50 43.5 87 70-130 2-Butanone (MEK) ug/L 100 118 118 64-135 2-Hexanone ug/L 100 106 106 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 115 115 70-130 Acetone ug/L 100 122 122 61-157 Acrylonitrile ug/L 250 286 114 61-143 Benzene ug/L 50 51.4 103 70-130 Bromochloromethane ug/L 50 55.3 111 70-130 Bromodichloromethane ug/L 50 54.0 108 70-130lK Bromoform ug/L 50 56.7 113 70-130 Bromomethane ug/L 50 47.4 95 38-130 Carbon disulfide ug/L 50 54.1 108 68-130 Carbon tetrachloride ug/L 50 50.6 101 70-130 Chlorobenzene ug/L 50 45.9 92 70-130 Chloroethane ug/L 50 40.7 81 37-142 F3,IK Chloroform ug/L 50 53.5 107 70-130 Chloromethane ug/L 50 51.8 104 48-130 v3 cis-1,2-Dichloroethene ug/L 50 53.6 107 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 LABORATORY CONTROL SAMPLE: 2653684 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 56.7 113 70-130 Dibromochloromethane ug/L 50 51.8 104 70-130 Dibromomethane ug/L 50 51.5 103 70-130 Ethylbenzene ug/L 50 47.2 94 70-130 lodomethane ug/L 100 116 116 40-130 Methylene Chloride ug/L 50 50.4 101 67-132 Styrene ug/L 50 49.1 98 70-130 Tetrachloroethene ug/L 50 45.4 91 69-130 Tetrahydrofuran ug/L 500 576 115 62-130 Toluene ug/L 50 50.0 100 70-130 trans-1,2-Dichloroethene ug/L 50 54.7 109 70-130 trans- 1,3-Dichloropropene ug/L 50 56.7 113 70-130 trans-1,4-Dichloro-2-butene ug/L 50 55.5 111 35-189 Trichloroethene ug/L 50 49.9 100 70-130 Trichlorofluoromethane ug/L 50 52.4 105 63-130 Vinyl acetate ug/L 100 127 127 55-143 Vinyl chloride ug/L 50 55.6 111 70-131 Xylene (Total) ug/L 150 145 97 70-130 1,2-Dichloroethane-d4 (S) % 111 70-130 4-Bromofluorobenzene (S) % 107 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE SAMPLE: 2653686 92440312004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.9 109 73-134 1,1,1-Trichloroethane ug/L ND 20 20.9 104 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 23.0 115 70-136 v1 1,1,2-Trichloroethane ug/L ND 20 23.7 118 70-135 1,1-Dichloroethane ug/L ND 20 19.4 97 70-139 1,1-Dichloroethene ug/L ND 20 22.4 112 70-154 1,2,3-Trichloropropane ug/L ND 20 17.2 86 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 22.2 111 70-137 1,2-Dichlorobenzene ug/L ND 20 20.6 103 70-133 1,2-Dichloroethane ug/L ND 20 19.5 96 70-137 1,2-Dichloropropane ug/L ND 20 23.0 115 70-140 1,4-Dichlorobenzene ug/L ND 20 19.7 98 70-133 2-Butanone (MEK) ug/L ND 40 47.9 120 60-139 2-Hexanone ug/L ND 40 45.7 114 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 48.6 121 65-135 Acetone ug/L ND 40 39.4 99 60-148 Acrylonitrile ug/L ND 100 87.5 88 64-147 Benzene ug/L ND 20 23.4 117 70-151 Bromochloromethane ug/L ND 20 17.6 88 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 MATRIX SPIKE SAMPLE: 2653686 92440312004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromodichloromethane ug/L ND 20 22.1 111 70-138 Bromoform ug/L ND 20 21.2 106 63-130 Bromomethane ug/L ND 20 13.2 66 15-152 v3 Carbon disulfide ug/L ND 20 22.3 111 69-149 Carbon tetrachloride ug/L ND 20 20.8 104 70-143 Chlorobenzene ug/L ND 20 21.1 105 70-138 Chloroethane ug/L ND 20 25.3 127 52-163 Chloroform ug/L ND 20 18.8 94 70-139 Chloromethane ug/L ND 20 20.5 103 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.9 100 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.8 104 70-137 Dibromochloromethane ug/L ND 20 19.8 99 70-134 Dibromomethane ug/L ND 20 19.8 99 70-138 Ethylbenzene ug/L ND 20 21.2 106 66-153 lodomethane ug/L ND 40 32.5 81 20-138 Methylene Chloride ug/L ND 20 18.1 91 42-159 Styrene ug/L ND 20 21.2 106 70-135 Tetrachloroethene ug/L ND 20 21.7 109 59-143 Tetrahydrofuran ug/L ND 200 200 100 70-133 Toluene ug/L ND 20 22.2 111 59-148 trans-1,2-Dichloroethene ug/L ND 20 21.4 107 70-146 trans- 1,3-Dichloropropene ug/L ND 20 20.7 104 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 17.5 87 47-135 v1 Trichloroethene ug/L ND 20 23.2 116 70-147 Trichlorofluoromethane ug/L ND 20 22.7 114 70-148 Vinyl acetate ug/L ND 40 42.7 107 49-151 Vinyl chloride ug/L ND 20 23.3 117 70-156 Xylene (Total) ug/L ND 60 64.0 107 63-158 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 97 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2653685 Parameter Units 92439777001 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 SAMPLE DUPLICATE: 2653685 Parameter Units 92439777001 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 v2 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 108 95 4-Bromofluorobenzene (S) % 110 100 Toluene-d8 (S) % 106 109 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492312 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92440808001, 92440808002, 92440808003 METHOD BLANK: 2654368 Matrix: Associated Lab Samples: 92440808001, 92440808002, 92440808003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 08/15/19 19:40 1,1,1-Trichloroethane ug/L ND 1.0 0.18 08/15/19 19:40 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 08/15/19 19:40 1,1,2-Trichloroethane ug/L ND 1.0 0.24 08/15/19 19:40 1,1-Dichloroethane ug/L ND 1.0 0.27 08/15/19 19:40 1,1-Dichloroethene ug/L ND 1.0 0.24 08/15/19 19:40 1,2,3-Trichloropropane ug/L ND 1.0 0.35 08/15/19 19:40 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 08/15/19 19:40 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 08/15/19 19:40 1,2-Dichlorobenzene ug/L ND 1.0 0.29 08/15/19 19:40 1,2-Dichloroethane ug/L ND 1.0 0.34 08/15/19 19:40 1,2-Dichloropropane ug/L ND 1.0 0.19 08/15/19 19:40 1,4-Dichlorobenzene ug/L ND 1.0 0.26 08/15/19 19:40 2-Butanone (MEK) ug/L ND 5.0 3.3 08/15/19 19:40 2-Hexanone ug/L ND 5.0 0.57 08/15/19 19:40 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 08/15/19 19:40 Acetone ug/L ND 25.0 6.2 08/15/19 19:40 Acrylonitrile ug/L ND 10.0 0.90 08/15/19 19:40 Benzene ug/L ND 1.0 0.15 08/15/19 19:40 Bromochloromethane ug/L ND 1.0 0.34 08/15/19 19:40 Bromodichloromethane ug/L ND 1.0 0.26 08/15/19 19:40 Bromoform ug/L ND 1.0 0.62 08/15/19 19:40 Bromomethane ug/L ND 2.0 0.62 08/15/19 19:40 Carbon disulfide ug/L ND 2.0 0.40 08/15/19 19:40 Carbon tetrachloride ug/L ND 1.0 0.22 08/15/19 19:40 Chlorobenzene ug/L ND 1.0 0.23 08/15/19 19:40 Chloroethane ug/L ND 1.0 0.49 08/15/19 19:40 Chloroform ug/L ND 5.0 2.3 08/15/19 19:40 Chloromethane ug/L ND 1.0 0.39 08/15/19 19:40 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 08/15/19 19:40 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 08/15/19 19:40 Dibromochloromethane ug/L ND 1.0 0.41 08/15/19 19:40 Dibromomethane ug/L ND 1.0 0.46 08/15/19 19:40 Ethylbenzene ug/L ND 1.0 0.26 08/15/19 19:40 lodomethane ug/L ND 20.0 12.5 08/15/19 19:40 Methylene Chloride ug/L ND 5.0 3.7 08/15/19 19:40 Styrene ug/L ND 1.0 0.27 08/15/19 19:40 Tetrachloroethene ug/L ND 1.0 0.16 08/15/19 19:40 Tetrahydrofuran ug/L ND 10.0 1.9 08/15/19 19:40 Toluene ug/L ND 1.0 0.24 08/15/19 19:40 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 08/15/19 19:40 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 METHOD BLANK: 2654368 Matrix: Associated Lab Samples: 92440808001, 92440808002, 92440808003 Blank Parameter Units Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 08/15/19 19:40 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 08/15/19 19:40 Trichloroethene ug/L ND 1.0 0.22 08/15/19 19:40 Trichlorofluoromethane ug/L ND 1.0 0.31 08/15/19 19:40 Vinyl acetate ug/L ND 2.0 1.4 08/15/19 19:40 Vinyl chloride ug/L ND 1.0 0.24 08/15/19 19:40 Xylene (Total) ug/L ND 1.0 0.63 08/15/19 19:40 1,2-Dichloroethane-d4 (S) % 99 70-130 08/15/19 19:40 4-Bromofluorobenzene (S) % 106 70-130 08/15/19 19:40 Toluene-d8 (S) % 101 70-130 08/15/19 19:40 LABORATORY CONTROL SAMPLE: Parameter 2654369 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.1 108 70-130 1,1,1-Trichloroethane ug/L 50 50.9 102 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.1 100 70-130 1,1,2-Trichloroethane ug/L 50 52.4 105 70-130 1,1-Dichloroethane ug/L 50 51.0 102 70-130 1,1-Dichloroethene ug/L 50 51.9 104 70-130 1,2,3-Trichloropropane ug/L 50 51.8 104 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.8 102 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.6 105 70-130 1,2-Dichlorobenzene ug/L 50 48.9 98 70-130 1,2-Dichloroethane ug/L 50 47.2 94 70-130 1,2-Dichloropropane ug/L 50 51.3 103 70-130 1,4-Dichlorobenzene ug/L 50 49.2 98 70-130 2-Butanone (MEK) ug/L 100 106 106 64-135 2-Hexanone ug/L 100 109 109 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 110 110 70-130 Acetone ug/L 100 104 104 61-157 Acrylonitrile ug/L 250 255 102 61-143 Benzene ug/L 50 51.7 103 70-130 Bromochloromethane ug/L 50 53.9 108 70-130 Bromodichloromethane ug/L 50 53.8 108 70-130lK Bromoform ug/L 50 55.3 111 70-130 Bromomethane ug/L 50 50.4 101 38-130 Carbon disulfide ug/L 50 47.7 95 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 50.1 100 70-130 Chloroethane ug/L 50 40.8 82 37-142 Chloroform ug/L 50 50.5 101 70-130 Chloromethane ug/L 50 46.1 92 48-130 cis-1,2-Dichloroethene ug/L 50 49.8 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 38 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 LABORATORY CONTROL SAMPLE: Parameter 2654369 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 56.2 112 70-130 Dibromochloromethane ug/L 50 54.5 109 70-130 Dibromomethane ug/L 50 51.2 102 70-130 Ethylbenzene ug/L 50 51.3 103 70-130 lodomethane ug/L 100 78.4 78 40-1301K Methylene Chloride ug/L 50 47.6 95 67-132 Styrene ug/L 50 51.7 103 70-130 Tetrachloroethene ug/L 50 51.8 104 69-130 Tetrahydrofuran ug/L 500 502 100 62-130 Toluene ug/L 50 50.1 100 70-130 trans-1,2-Dichloroethene ug/L 50 50.7 101 70-130 trans- 1,3-Dichloropropene ug/L 50 55.9 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 57.6 115 35-189 Trichloroethene ug/L 50 51.3 103 70-130 Trichlorofluoromethane ug/L 50 49.4 99 63-130 Vinyl acetate ug/L 100 114 114 55-143 Vinyl chloride ug/L 50 48.3 97 70-131 Xylene (Total) ug/L 150 155 103 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: Parameter 2654371 Units 92440784006 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.6 108 73-134 1,1,1-Trichloroethane ug/L ND 20 22.6 113 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.1 106 70-136 1,1,2-Trichloroethane ug/L ND 20 21.3 107 70-135 1,1-Dichloroethane ug/L ND 20 22.9 115 70-139 1,1-Dichloroethene ug/L ND 20 23.9 120 70-154 1,2,3-Trichloropropane ug/L ND 20 22.3 112 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 19.0 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.0 105 70-137 1,2-Dichlorobenzene ug/L ND 20 20.6 103 70-133 1,2-Dichloroethane ug/L ND 20 21.0 105 70-137 1,2-Dichloropropane ug/L ND 20 22.1 111 70-140 1,4-Dichlorobenzene ug/L ND 20 20.5 102 70-133 2-Butanone (MEK) ug/L ND 40 43.0 108 60-139 2-Hexanone ug/L ND 40 42.6 107 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 42.1 105 65-135 Acetone ug/L ND 40 53.0 132 60-148 Acrylonitrile ug/L ND 100 109 109 64-147 Benzene ug/L ND 20 22.8 114 70-151 Bromochloromethane ug/L ND 20 24.1 121 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 MATRIX SPIKE SAMPLE: 2654371 92440784006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromodichloromethane ug/L ND 20 21.9 110 70-138 Bromoform ug/L ND 20 19.9 99 63-130 Bromomethane ug/L ND 20 19.9 99 15-152 Carbon disulfide ug/L ND 20 25.3 127 69-149 Carbon tetrachloride ug/L ND 20 22.3 111 70-143 Chlorobenzene ug/L ND 20 21.1 105 70-138 Chloroethane ug/L ND 20 24.9 125 52-163 Chloroform ug/L ND 20 22.1 111 70-139 Chloromethane ug/L ND 20 28.6 143 41-139 M1 cis-1,2-Dichloroethene ug/L ND 20 22.3 111 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.7 114 70-137 Dibromochloromethane ug/L ND 20 20.6 103 70-134 Dibromomethane ug/L ND 20 20.8 104 70-138 Ethylbenzene ug/L ND 20 22.3 111 66-153 lodomethane ug/L ND 40 42.9 107 20-138 Methylene Chloride ug/L ND 20 22.3 111 42-159 Styrene ug/L ND 20 21.6 108 70-135 Tetrachloroethene ug/L ND 20 21.6 108 59-143 Tetrahydrofuran ug/L ND 200 208 104 70-133 Toluene ug/L ND 20 21.6 108 59-148 trans-1,2-Dichloroethene ug/L ND 20 23.1 115 70-146 trans- 1,3-Dichloropropene ug/L ND 20 22.0 110 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 20.9 104 47-135 Trichloroethene ug/L ND 20 22.1 111 70-147 Trichlorofluoromethane ug/L ND 20 22.9 114 70-148 Vinyl acetate ug/L ND 40 45.5 114 49-151 Vinyl chloride ug/L ND 20 22.9 115 70-156 Xylene (Total) ug/L ND 60 66.2 110 63-158 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 2654370 Parameter Units 92440784005 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 SAMPLE DUPLICATE: 2654370 Parameter Units 92440784005 Result Dup Result RPD Max RPD 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND 10.2J 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Tetrahydrofuran ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 99 101 4-Bromofluorobenzene (S) % 104 104 Toluene-d8 (S) % 101 100 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492255 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92440808001, 92440808002, 92440808003, 92440808004 METHOD BLANK: 2654104 Matrix: Water Associated Lab Samples: 92440808001, 92440808002, 92440808003, 92440808004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 08/14/19 13:56 1,2-Dichloroethane-d4 (S) % 103 50-150 08/14/19 13:56 Toluene-d8 (S) % 102 50-150 08/14/19 13:56 LABORATORY CONTROL SAMPLE: 2654105 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 102 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2654106 2654107 MS MSD 92440808001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 22.5 22.9 113 115 50-150 2 30 1,2-Dichloroethane-d4 (S) % 108 109 50-150 30 Toluene-d8 (S) % 104 103 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 492455 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2655145 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 5000 08/15/19 20:05 LABORATORY CONTROL SAMPLE: 2655146 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 54100 108 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655147 2655148 MS MSD 92440389006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 166 mg/L 50000 50000 228000 228000 125 123 80-120 0 25 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655149 2655150 MS MSD 92440914002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 33.0 mg/L 50000 50000 85300 85500 105 105 80-120 0 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 491699 Analysis Method: SM 2540C-2011 QC Batch Method: SM 2540C-2011 Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2651448 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Dissolved Solids ug/L ND 25000 25000 08/12/19 13:44 LABORATORY CONTROL SAMPLE: 2651449 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids ug/L 250000 264000 105 90-110 SAMPLE DUPLICATE: 2651450 92440286002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L 2450 mg/L 2540000 4 5 SAMPLE DUPLICATE: 2651451 92440783002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L ND ND 5 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 491562 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2651123 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 08/10/19 20:49 LABORATORY CONTROL SAMPLE: 2651124 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 51200 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2651125 2651126 MS MSD 92439980025 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 10.5 mg/L 50000 50000 62400 62800 104 105 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2651127 2651128 MS MSD 92440749011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L ND 50000 50000 53100 53000 104 104 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 QC Batch: 491908 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92440808001, 92440808002 METHOD BLANK: 2652640 Matrix: Water Associated Lab Samples: 92440808001, 92440808002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 08/13/1913:38 LABORATORY CONTROL SAMPLE: 2652641 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 20500 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2652642 2652643 MS MSD 92440795003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 66500 10000 10000 76300 75000 97 85 90-110 2 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 38 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Oxford Unit 1&2 Blanks & Joint Pace Project No.: 92440808 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS F3 The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the laboratory's control limits. The result is estimated. IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 38 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Oxford Unit 1&2 92440808 Blanks & Joint Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92440808001 3901-MW7 EPA 3010A 492603 EPA 6010D 492651 92440808002 3901 - Field Blank EPA 3010A 492603 EPA 6010D 492651 92440808001 3901-MW7 EPA 3010A 492601 EPA 6020B 492655 92440808002 3901 - Field Blank EPA 3010A 492601 EPA 6020B 492655 92440808001 3901-MW7 EPA 7470A 491690 EPA 7470A 491755 92440808002 3901 - Field Blank EPA 7470A 491690 EPA 7470A 491755 92440808001 3901-MW7 EPA 8260D 492312 92440808002 3901 - Field Blank EPA 8260D 492312 92440808003 3901 - NEWS EPA 8260D 492312 92440808004 3901 -Trip Blank EPA 8260D 492152 92440808001 3901-MW7 EPA 8260D Mod. 492255 92440808002 3901 - Field Blank EPA 8260D Mod. 492255 92440808003 3901 - NEWS EPA 8260D Mod. 492255 92440808004 3901 -Trip Blank EPA 8260D Mod. 492255 92440808001 3901-MW7 SM 2320B-2011 492455 92440808002 3901-Field Blank SM 2320B-2011 492455 92440808001 3901-MW7 SM 254OC-2011 491699 92440808002 3901-Field Blank SM 254OC-2011 491699 92440808001 3901-MW7 EPA 300.0 Rev 2.1 1993 491562 92440808002 3901 - Field Blank EPA 300.0 Rev 2.1 1993 491562 92440808001 3901-MW7 SM 4500-CI-E-2011 491908 92440808002 3901-Field Blank SM 4500-CI-E-2011 491908 Date: 08/20/2019 03:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 38 ,:aceMalyil`ca( uowment ivame. I -,.a. , 1, -- Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS.033-Rev.06 Pacetarolinas Quality Office -Laboratory receiving samples: Asheville 0 Eden❑ Greenwood ❑ Huntersville Lg Raleigh[] Mechanicsville❑ Saniple Condition Client NaMe: WO# : 92440808 Upon Receipt Project 9: bG`'' ` i !C�L `l- S�' ° G h��1:1 - II I II! I III I I I I I I III III Courier: []Fed Ex ❑UPS ❑USPS [—]Client ❑ Commercial ❑Kce ❑other: 92440808 Custcd Seal Present. / — y ? ❑Yes ❑r*% Seals Intact? ❑Yes �No �/[ Date/Initials Person Examining Contents:' ` q y Packing Material: �ble Wrap ©bubble Bags []None ❑ Other Biological Tissue Fjrp�zen? Therrrlometer, ,�_.,�� Des; [-]No [gK/A ft Gun lfl:���� Type of ice: QWet ❑Blue ❑None Coole►Temp('C): Zi,L CorrectionFactor: Add/Subtract (°C) 0,0 Z � Tempshould be above freezing to VC Cooler Ternp Corrected (' CI : []Samples outeftemp criteria. Samples on ice, coaling process has begun USDA Regulated Sail (ff N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign souice (internationally, l-1Yes ilNo inrludinsHawaii and Puerto Rlcol? FlYes 11Na Corhments/Discrepancy: , Chain of Custody Present? QYes ONO ❑N/A 1, /es Samples Arrived within Hold Time? _ E] []No ❑N/A 2, Short Hdld.FimeArta lysls [<72 hr.I? ❑Yes ❑Vb [I WA 3. Rush Tui•nAround Time Requested? Dyes; EIKI. ❑N/A 4. Sufficient Volume? By/. ❑No ❑N/A 5. Correct Containers Used? es [:]No ❑N/A 6. -Pace Containers Used? [:]NO❑N/A Containers Intact? �ees Ej' es ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? []Yes ❑Na /A S. Sample Lahels Match COV OY6 []NO []N/A 9. -Includes Hate/Time/ID/Anatysis Matrix: JAJ i Headspace in VOA Vials (>5-6mm)7 ❑Yes ❑No [DN/A 10. Trip Blank Present? ❑Yes []No 0J/A 11. Trip Blank Custody Seals Present? []yes []No ON,A COMMENTS/SAMPLE DISCREPANCY Field Data Required? [-]Yes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: oate/Time: 4Project Manager SCURF Revlew: �/_M Date:all Project Manager SRF Revlew: Date: f Page 36 of 38 l°' m sample conaition upon ere ceAnalyhca! Document No.: lssuing Authority: Pace Carolinas Quality Mice *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Cotiform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project # r W V# : 9244Q848 PM: NMG Due Date: 08/23/19 CLIENT: 92-Joyce Eng pH Adjustment Log for Preserved Samples Sample 1D Type of Preservative pH upon retelpt Date preservation adjusted Time preservation Amount of Preservative Lot d adjusted I added Note: Whenever there is a discrepancy affecting North Carolina campliance samePYohs farm will hesent to the North Carolina DEHNR Certirication office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 37 of 38 00 rm 0 DO M ZT N IL Section A Required Client Information: cormpany. I La Bella Associates Address. 12211 Wenl Meadowview Rd Greensboro, NC 27407 Email TO vburbachr7'2cAenoaineen Phone336 323092 Fx Requested Due DatelrAT: 10 Dav fDefaultl SAMPLE ID One Character per box. (A-Z, 0-91 , -y Sample Ids must be unique lu F- 1 3901-MW7 3901-NES2S 3901-Field Blank 3901-Trip Blank CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section a Section C Required Project Information: Invoice Information: Van on Burb Re To Pace : Of P ach Artentlon. Jason Falls Copy To Miguel Vazquez eon,pany Nalne Granville County, Solid Waste Address P_0. Box 906. Oxford NC 27565 w--. 1 Purchase Order No. Client Project ID: Oxford UnitS 1 &2 BlankS & Joint Container Order Number 3566-4 Re uested Analysis Filtere MATRIX CODE — nomkrn� WWrr nW V COLLECTED Z z Preservatives O W:rrra WT U Vl Wasrc WMr•r Wry _ P'n .. P in P: w N Vy rz S.118 d SL orl or ° v ii r START END y [� (� m ❑ L qr WIPC WP O ¢ CC� ~ C 0 r0 C r0 00 ¢ a Air AR ckn,•r O = w _ a_ (O O eT has4r TS X 7DATFFIMEDATE ~ F Z o N a }' Q d o ❑ a2F _O � _ L V _U a a a o o c Q Q U❑ c� ❑ 2o�z� TIME v¢, i i= z z g O Z z z Y j v T G X ?L X X Ix Ix X Y wT IS Z X X X wT G ZOO$ ►® X X X X X X wT C / 05015 4 9 10 11 12 ADDITIONALCOMMENTS RELINQUISHED BY I AFFILIATiON DATE TIME ACCEPTED/AFFILIATION DATE TIME C&D Parameters = Iron, Manganese, Mercury, C ). Sl�bc" ri cc e � 11-z 5'j��]�� i~0— Alkalinity, Chloride, Sulfate, TDS, and c• SAMPLER NAME AND SIGNATURE 1-71 PRINT Name of SAMPLER: L r, A� �r C SIGNATURE of SAMPLER: h t2 DATE Signed: / 1 Y ' �-7 A/- , Z7 r �5 North Carolina Dos 064 SAMPLE CONDITIONS aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 September 11, 2019 Van Burbach Joyce Engineering -NC 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Granville - Oxford Resample Pace Project No.: 92444302 Dear Van Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on September 05, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Gretta Eller, LaBella Associates, D.P.C. Ashley Martin, Labella Associates Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Granville - Oxford Resample Pace Project No.: 92444302 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 11 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Granville - Oxford Resample Pace Project No.: 92444302 Lab ID Sample ID Matrix Date Collected Date Received 92444302001 MW-10 Water 09/04/1913:32 09/05/1911:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Granville - Oxford Resample Pace Project No.: 92444302 Lab ID Sample ID 92444302001 MW-10 SAMPLE ANALYTE COUNT Method EPA 601 OD REPORT OF LABORATORY ANALYSIS Analytes Analysts Reported IDS Laboratory PAS I -A This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Granville - Oxford Resample Pace Project No.: 92444302 Sample: MW-10 Lab ID: 92444302001 Collected: 09/04/19 13:32 Received: 09/05/19 11:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Vanadium ND ug/L 5.0 1.3 1 09/06/19 19:03 09/10/19 07:57 7440-62-2 Date: 09/11/2019 07:11 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Granville - Oxford Resample Pace Project No.: 92444302 QC Batch: 496553 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92444302001 METHOD BLANK: 2674427 Matrix: Water Associated Lab Samples: 92444302001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vanadium ug/L ND 5.0 1.3 09/10/19 06:51 LABORATORY CONTROL SAMPLE: 2674428 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vanadium ug/L 500 479 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2674429 2674430 MS MSD 92444291001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vanadium ug/L 1.6J 500 500 518 506 103 101 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/11 /2019 07:11 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Granville - Oxford Resample Pace Project No.: 92444302 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/11 /2019 07:11 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 11 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Granville - Oxford Resample Pace Project No.: 92444302 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92444302001 MW-10 EPA 3010A 496553 EPA 6010D 496565 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/11 /2019 07:11 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 11 Document Name: Document Revised: February 7, 2018 m aC8ARc3�ytlff CcZ� Sample Condition Upon Receipt{SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality office Laboratory receiving samples: Asheville ❑ Eden❑ Client Name: Greenwood ❑ Huntersville Raleigh[] Mechanicsville❑ Custody Seal Present? ❑Yes ER110 Seals Intact? ❑Yes Qf WO#:92444302 92444302 Date/InitiafsPerson Examining Contents: =-'� 7—'�` Packing Material: ❑Bubble Wrap ❑Bubble Sags 911oone ❑ Other Blological T�i ue Frozen? Thermometter� ❑Yes ©No ❑N/A Iln uun ID: 92TO49 Type of Ice: Wet ❑Blue ❑None Cooler Temp ('Q: 0. Correction Factor: Add/Subtract (°C) 0.0 Cooler Tema Corrected VC),U. (i. Temp should be above freezing to 6°C piAw.p.s5$li eTe+nis CN{�LME. 3QnTpfe?E17'ieCe40*i!'+g'p14R3a has begun USDA Regulated Soll ((TN/A, water sample) Did samples ar^igi�te in a quarantine zone within the United States: CA, NY, or SC {check maps)? Did samples originate from a foreign source ('internationally, I IYpC I 'i n innli vlinn P.—ii —A .;--%I ram— M.— r Cam ments/04crepancy: Chain of Custody Present? 01(.' ❑N. ❑N/A 1. Samples Arrived within Hold Time? yes ❑No ❑N/A 2. Short Hold Time Analysis (02 hr.)? ❑yes 09-a ❑N/A 3. Rush Turn Around Time Requested? ❑Yes 21ro ❑N/A 4. Sufficient Volume? ❑r ❑No El N/A S. 6. _ Correct Containers Used? -Dfes ❑No ❑N/A Pace Containers Used:+ cly., ❑No ❑N/A Containers Intact? es ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? []Yes ❑No /A S. Sample Labels Match COC? -includes Datt/Time/ID,'Anaiysis Matrix: ` es ❑No ❑N/A 9. leadspaceinVOAVials(>5-6mmi? kT�rlp []Yes❑No N/A 10. I Wank Present? Trip Blank Custody Seals present? []Yes [—]Yes No ❑No ❑N/A If N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: _ _ OM10 Date: Project Manager SRF Review: &r'f_ �'� Date; Field Data Required? []Yes ❑No Page 9 of 11 Analytical Document Name: Sample Condition Upon Receipt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority, Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project 1# verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box Is to list number of bottle WO#:92444302 PM: NMG Due Date: 09/12/19 CLIENT: 92-Joyce Eng u z Z N a c 7 V p�J tT a c 7 u Val a c 7 _ N a c � 2 v 0 N = V V a 0 z S Y 2 ca a H u a N u T �. 2 O Z u a N D n l? � " ya N v a c 7 N y o U i U y W N a c = Gl N 2 a c O N 2 V O. 0 N 2 N u Z .0 E Q J � z U Z m N N f0 � z a c a Z v 0 Irt Y m a 19 � a ] z � A a«+ �' u a ♦n N = N a s N > c a ¢ d v a C 7 m a E N rl R a m F. E 1011 N rm c m 1 E G t �1 N 0. m a `w N r�l a m a E N H V d m a E N N M L m n 1 E r4 N C 6 m ro a J E N N 7 6 m a E v y 7 6 $ a w _ rl 7 4'1 a a ¢ a` _ rl 2 N i7 d E Q E a to N � 1+1 li a E Q ;; — ,..� Vt ai l7 a E ¢ E ry lit FA l4 a o 4 m 1:1 Q n1 l7 a a Oy - E O t 01 4 O > E O F a1 l7 > a O E �0 i 17 Ct l7 > ¢ O -� E O at [7 0 `m n N m •� a O n N .2 x U' \ > E N N b 1n m V1 E O N N d W a J E N N Q Rl 6 m E Q J E d O ~ 7 0 V' a c 0 VI E O N 7 V� vt >I " E ¢ J E a M l7 o 1 NN I 2 :3] N\\ 4 1. S 6 N\N 7 \N\.\ N\\ a ' 4 I 10 li 12 N \N1 I I N\� I pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon recelpt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot a Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a COPY of this form will hesent to the North Carolina DEHNR Certification Office (i.e. Out of hold, Incarrect preservative, out of temp, Incorrect containers. Page 10 of 11 �c�Malyfical Section A Required Client Information: Company: LaBella Associates D.P,C - IAddress: 2211 West MPar1—i— A.. Due Date ) SAMPLE ID One Character per box- IA-Z, 0-91, -j ME Sampie Ids must be unique LLJ I.- 1 MW-to 2 3 4 5 6 7 8 9 10 11 12 ADDMONALCOMMENTS CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section e Required Project Inforn ati Report To: Van Burba Copy To: i t? Purchase Order #: project Name: Gran Ile 'roiect #d m a rMTRix GOOE COLLECTED M Section C d Invoice Information: Page: t Of t Attention: L--t-s-;_, �n,c LWA Pace quote: Paces Project Manager. nia Pace Profile #, 3566 ❑linking water o U z Preservatives p r Warr T W Wa11e wamr V1w - ¢ w Protlud p S.,VSOI,d SL 0.1 CL START END F Wipe Wp Art AR Othm OT d O d fl ? Q m m y Ti:cuc TS X w z 0 T 4 LL N Q AT TIME DATE TIME a = 2 z z z C :2 O j WT q/y/lq ) Ssi I 1 X ._ RELINQUISHED BYI AFFILIATION DATE TIME PLER NAME AND SIGNATURE PRINT Name of SAMPLER SIGNATURE of SAMPLER: i1 ACCEPTED BY I AFFILIATION i I/ —Ot!aaZC DATE TIME Q, nI�,-- DATE Signed: (� i �� z SAMPLE CONDITIONS U + o a o `m n o_ m w $ z o �d �z C LaBella 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Telephone: (336) 323-0092 Facsimile: (336) 323-0093 WELL I.D.:�- WELL SAMPLING INFORMATION Project Name: Location: QX �G� (—rand qC\N Project No.: Z I$ Zo ZZ .a t 10Z Sampled By: Cjp,npSlebOar1il� A91n18►1 :Y1osY��t1 Date: 0% - ga - 2 O kc% Weather: 5 -t- G cJ,ILy Well Diameter: '1;n Static Water Level: Depth of Well: 10-}, 3a Length of Well Screen: Measuring Point: SOo O% We NX Depth to Top of Pump: Pump Type: Tubing Type: FIELD PARAMETER MEASUREMENT 2Z.1 3 Gal—lons =Conductivity Tuw-b—id—ity— Re—dox—� Alkalinity Iron (11) Comments to[ai n, Uip ciattons Purged Purge Time Purge Time End: Final Static Water Level: Start: 33S OBSERVATIONS Notes: �o..►.., plea lD bob- r1es 0-k 1ZS0 Cvz 53 okews L LaBella 2211W. Meadowview Rd Suite 101 Project Name: Location: Proiect No - Greensboro, NC 27407 Sampled By: Telephone: (336) 323-0092 Facsimile: (336) 323-0093 Date: WELL I.D.: M� --7 l/VtA�Weather: WELL SAMPLING INFORMATION Well Diameter: ?I �l Depth of Well: Measuring Point: Pump Type: FIELD PARAMETER&MEASUREMENT s. �i�n��► % � / A. AAa,--`,1 Q'� r Static Water Level: Length of Well Screen: Depth to Top of Pump: Tubing Type: Z2, ' --dallm ®® . • ��N6L»LAM=== Total Gallons Purged Purge Time Purge Time End Start: I,n OBSERVATIONS �'�40 2 """' (� bo{lie5 �Mple�i ai 1;oz CMN q� Final Static Water Level: Zz DATE: �lg/2f2IR � LaBeRa GROUND WATER SAMPLING LOG Project Name: Granville Co. -Oxford Unit 2 Project No. /Phase No.: 2182022.01/03 Well ID: MW-8 Sampler(s): S. Slebodnik / A. Martin Well Location: Next to leachate storage tank in gravel lot Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: For THREE Well Volumes: Actual Amount Purge Purged with: WCT X 0.653 WVX3 Sampled with: C Baile P Depth to Water before Sampling: 2 inches �I( feet 28.00 feet Zq.'M feet [DTB-DTW] L •-gallons gallons _ 2 gallons I Z. gallons imp Other: imp Other: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials Io2 ZD,O 7.1(,,, 208.2 Z.3z-, 1o(o O.q3 SS . o I o Zo Z o.1 7. z9 Zo$.3 Z • 10 10 s-. G Zz. i y ss �.C) ID31 Zo.0 7. y1 Zo<�.(,o Z, Sy ctS.q s. Sz 5S f 2. 0 103(::> 20. 0 7.55 Z I I .�5 2.5'g IZ� s' Z• y 2 �S Date of sample: ��19 Before SamplingIDS(, w, © "'7, SS 2 )l . `$ 0,59 25.S. Z, 1/21 , Cents (weather conditions, odor, color, silt, etc.): YI.C_� Lv PSt1� a ,� 11J A.5 .S► � � n lJ -t� �� s 0 ✓l. g �g Signature: 4��Mvwi Ak& —Date: nhfVzon • • • X•. OJAI�� 1.11,I •. . 7 - $� � � LaBelle DATE: gl GROUND WATER SAMPLING LOG Project Name: Granville Co. -Oxford Unit 2 Project No. /Phase No.: 2182022.01/03 Well ID: MW-9 Sampler(s): S. Slebodnik / A. Martin Well Location: Down hill in woods east of Unit 2 LF across access road Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): 2 inches � • 605 feet 43.00 feet q. 3S feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 (o gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = Inc.$ gallons Actual Amount Purged/Bailed: �J-� gallons Purged with: ciailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: 49-490 feet Gallons Time Temp (°C) pH Cond. (US/Cm) Dis.02 mg/L ORP my Turb. (ntu) Initials 01321 ►q,l 6.13 Zq(0.7 3.$I 201,o (o.L4I Am (C;l 13Z-7 I-7.0 . S3 310.5 ie. 59 Z11.q I9. S% Ann, II. Z I33H 1-1.6P Co.$l 3o5'.o 2.(,,q 21s.3 CoI.(o7 Anti. Gi - 1 . $C1 a) I o cis Date of sample: $%$l19 Before Sampling ILLLI I'Zo. Z (p. 39 ZR2. 3 • SS 14 6- y 43. s a I AM Comments (weather conditions, odor, color, silt, etc.): s svn n v ort t: Signature: L04dAeAMY Date: 915120ict I LaBeRaDATE: d7-glZD1�J GROUND WATER SAMPLING LOG Project Name: Granville Co. -Oxford Unit 2 Project No. /Phase No.: 2182022.01/03 Well ID: MW-10 Sampler(s): S. Slebodnik / A. Martin Well Location: Around sed pond north of Unit 2 LF Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: 2 inches L7, 17 ss eet WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witf 31.50 feet ZZ . 3 3 feet [DTB-DTW] = 3• gallons _ FFallons = 10•"? gallons 1aq gallons Depth to Water before Sampling: 9.1 % feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 1251 21• i 6.11 '57.( I.'�SI 1511 �.Z� AM 3.(, It5$ l-3•1 (o.1-7 )531 2,d5 15g3 ZZ,9Z A1A 7. 2 1305 Zo. 0 �' ZCo 1(00.0 2 . Z9 ! (02-.3 53. 30 4*M 10,16 1313 V3 (o.0% JR9.9 2, 05 1&q.0 g0Jq .Ann Date of sample: 5IC6119 Before Sampling I I ' S J zo. C� �, D. 30 b5 Comments (weather conditions, odor, color, silt, etc.): kt- Signature: Date: F161'Zoa QA/QC Sign Off: 1MAnRD_ Date: 00 LaBella 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Telephone: (336) 323-0092 Facsimile: (336) 323-0093 WELL I.D.: AM-10 WELL SAMPLING INFORMATION Project Name: Granville County — Oxford Resample Location: Oxford Landfill Project No.: 2182022 / phase 01 Sampled By: S. Slebodnik Date: 9/4/2019 Weather: DAf b Well Diameter: 2" Depth of Well: 31.50' Measuring Point: Pump Type: Geotech bladder pump FIELD PARAMETER MF,ASiTRF.MF.NT Static Water Level: Length of Well Screen: Depth to Top of Pump: Tubing Type: {�oytci a-�- fv h AJ - Gallons Turbidity Dissolved 02 Redox �, Alkalinity Comments iuLai Uniiuns rurgeu Purge Time Purge Time End: i 33Z Final Static Water Level: q A 95- Start: I 1 OBSERVATIONS Notes: DATE: g1 %- SI Za tq La BelLa GROUND WATER SAMPLING LOG Project Name: Granville Co. -Oxford Unit 2 Project No. /Phase No.: 2182022.01/03 Well ID: MW-11 Sampler(s): S. Slebodnik / A. Martin Well Location: Down hill next to stream across access road from Unit 2 LF Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): 2 inches Co 3 feet 22.90 feet 17. Z7 feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = �• S gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = $• y gallons Actual Amount Purged/Bailed: gallons Purged with: Bailer Pump Other: Sampled with: iler Pump Other: Depth to Water before Sampling: 5. SS feet Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials c� 1Z 27 Z0. 7 7. 0z 1 ?%.9 I gq.9 13. io 65 Z.S 1231 Iq.1 (9.7Z IZ$.& )-7q.3 Z71.q Z�S .S; (o 1Z35 g.Co (0- 5o I Zl . 7 Z. 5S 153, q 3zZ.q 55 16. q IZg0 15.5 Co.1N 127.1 Z. I Z 5,5 Date of sample: $lgl)q Before Sampling 1102 r?.s—.Zz (o, 32 1 133.E 1 Z.Oq !I -MS 1 !. 6c0 1 5S Comments (weather conditions, odor, color, silt, etc.): Signature: /A/ Date: �6/o/ QA/QC SignOff: /il �_ .t A M i.. Date:• • I L LaBella 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Telephone: (336) 323-0092 Facsimile: (336) 323-0093 WELL I.D.: t,�ES -i 7e:b WELL SAMPLING INFORMATION Project Name: C ,04%S E, e 6 C no d%*k%X n-4C'p,fa. %..M^A \\� Location: p x fxr4 Ln'AG l l Project No.: Z.1 $ zoo-L-O 1 O Z Sampled By: Sow -loon h"L sye boa rn i k As Inl� M lit }in Date: d4 - 0;;� - 201o1 Weather: $OS -+ SLAtV-11-1 Well Diameter: T% n Static Water Level: Depth of Well: 2 A .1,6 Length of Well Screen: Measuring Point: Tn0 F Depth to Top of Pump: Pump Type: `— Ge! + $�p�aclGd Q�„� Tubing Type: FIELD PARAMETER MEASUREMPNT 9w M. uo P�eeL T�A1r,ir� Ga-11—ons Purged i Turbidity Dissolved 02 Redo Comments VEV� Wow �_-�►�®��KESJ�Izw��_ i__-0 1►J 7 O� —auvua r uigcu Purge Time Purge Time End: Start: �L� -3 U OBSERVATIONS Notes: �D $okk�es sa.w,p�e� o�� ly5a ireZ�"� D•2S *-��lL 00Z , a-4-dUrops Final Static Water Level: lSSo (A. 1 z Zoe S ( emso�uc�l L�C)Vo er, so.+.�,r-a a�- 1S4AW DATE: 2 12 1 lot LaBetta SURFACE WATER MONITORING LOG Project Name: Granville Co. - Oxford Unit 2 Project/Task No.: 2182022.01 / 03 Surface Point ID: SW-3 Sampler(s): S. Slebodnik / A. Martin Location: Upstream from MW-9 behind Unit 2 LF Field Parameters: Time of Sampling: �,�C01:5 pH: q Temperature: 3.44 (° C) Conductivity: .6 (US/cm) Turbidity: S (ntu) Dissolved Oxygen �y (mg/L) Oxidation -Reduction Potential 0 (mv) Comments/Sample Description (weather conditions, odor, color, silt, Ilse wexo_� _r Wc,,-5 SOs -+— i)nn�j ors etc.): QA/QC Sign Off: Date: DATE: LaBetta SURFACE WATER MONITORING LOG Project Name: Granville Co. - Oxford Unit 2 Project/Task No.: 2182022.01 / 03 Surface Point ID: SWA Sampler(s): S. Slebodnik / A. Martin Location: Near where the stream intersects the path behind MW-10 Field Parameters: Time of Sampling: O pH: 0 Temperature: A (° C) Conductivity: Turbidity: Dissolved Oxygen n .z (US/cm) 1- (ntu) 1.39 (mg/L) Oxidation -Reduction Potential t S C I. 3 (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): �� ��� o r t,� rag C�l.l �t -�- s u n n v � ✓1 S % g / Iq Signature: . MI •19 Appendix C Historical Data Tables Table A3-1 Historical Groundwater Elevations Table A3-2 Historical Groundwater Constituents Table A3-3 Historical Surface Water Constituents Table A3-4 Historical Groundwater Field Parameters Table A3-5 Historical Surface Water Field Parameters TABLE A3-1: Historical Groundwater Elevations Background Downgradient Well ID: MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Well TOC Elev.: 534.24 503.31 487.51 484.92 478.72 477.20 Well Total Depth: 37.32 28.00 43.00 32.90 22.90 24.20 13-Jun-12 513.48 503.31 479.7 477.42 473.20 468.81 22-Aug-12 509.73 500.82 477.97 475.31 471.50 469.36 25-Sep-12 508.45 499.85 478.1 475.06 471.86 469.30 17-Oct-12 507.95 499.90 478 474.23 471.04 467.98 06-Aug-13 514.33 499.92 478.81 475.32 472.80 469.29 25-Feb-14 511.75 499.91 480.34 476.26 473.47 470.28 12-Aug-14 511.98 500.16 479.91 476.54 473.42 470.29 12-Mar-15 516.39 499.99 479.73 476.47 473.66 470.63 18-Aug-15 512.39 499.86 478.41 474.92 472.17 469.25 16-Feb-16 515.79 499.90 481.44 476.37 474.12 471.15 10-Aug-16 514.29 499.82 478.86 475.51 472.91 470.40 14-Feb-17 510.89 496.36 479.36 475.97 472.77 468.85 23-Aug-17 508.84 499.61 477.86 474.74 472.02 469.80 07-Feb-18 505.74 499.86 479.88 476.25 473.54 471.40 14-Aug-18 510.22 499.95 478.22 475.31 473.57* 470.81 05-Feb-19 515.74 500.01 480.72 476.63 474.03 472.18 07-Aug-19 512.11 500.15 478.86 475.75 473.09 472.31 *04-Sep-19 nm nm nm 475.09 nm nm Notes: TOC = top of casing. Water levels are measured from TOC. nm = not measured. Granville Co. - Oxford Landfill, Unit 2 Permit 3901-MSWLF-2012 All elevations are in feet above mean sea level. *=resampling event. LaBella Associates TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Inorganics Arsenic 12-Mar-15 EPA 6010 2.50 10.0 4.2 J ND ND ND ND ND ND NC 2L = 10 pg/L 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.50 10.0 ND ND 2.7 J ND 3.9 J ND ND 11-Aug-16 EPA 6010 2.50 10.0 ND ND ND 3.1 J 3.2 J ND ND 14-Feb-17 EPA 6010 5.00 10.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 6010 5.00 10.0 ND ND ND ND ND ND ND 6-Feb-18 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 6010D 5.00 10.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 6010D 5.00 10.0 ND ND ND ND ND ND ND 8-Aug-19 EPA 6010D 5.00 10.0 ND ND ND ND ND ND ND Barium 13-Jun-12 100 9.2 J 36.8 J 59.2 J 48.2 J 30.6 J 31.4 J ND 22-Aug-12 100 ND 37.3 J 60.9 J 58.9 J 85 J 28.2 J ND 25-Sep-12 100 10.3 J 40.8 J 64.2 J 72.7 J 43.8 J 30.5 J ND NC 2L = 700 pg/L 17-Oct-12 100 24.2 J 57.3 J 65.1 J 48.7 J 110 28 J ND 6-Aug-13 100 ND 37.1 J 66.5 J 36.8 J 28.5 J 24.8 J ND 25-Feb-14 100 ND 43.6 J 65 J 41.1 J 20.3 J 58.6 J ND 13-Aug-14 EPA 6010 5.00 100 6.2 J 52.7 J 72.7 J 40.7 J 19.7 J 21.7 J ND 12-Mar-15 EPA 6010 2.50 100 9.8 J 47.9 J 76.3 J 49.1 J 19.1 J 35.5 J ND 18-Aug-15 100 11.0 J 45.6 J 72.1 J 43.5 J 20.5 J 31.3 J ND 18-Feb-16 EPA 6010 2.50 100 14.8 J 59.5 J 76.1 J 54.2 J 31.8 J 28.6 J ND 11-Aug-16 EPA 6010 2.50 100 6.2 J 42.9 J 81 J 61.2 J 49.9 J 31.1 J ND 14-Feb-17 EPA 6010 2.50 100 11.8 J 41.9 J 89.0 J 46.2 J 40.8 J 27.6 J ND 23-Aug-17 EPA 6010 2.50 100 25.2 J 42.6 J 126.0 40.8 J 51.4 J 33.8 J ND 6-Feb-18 100 19.3 J 62.6 J 90.7 J 47.1 J 33.9 J 25.4 J ND 16-Aug-18 EPA 6010D 2.50 100 3.8 J 40.3 J 68.9 J 47.5 J NM 25.8 J ND 5-Feb-19 EPA 6010D 2.50 5.0 4.0 J 39.8 78.0 59.4 27.7 19.6 ND 8-Aug-19 EPA 6010D 2.50 5.0 4.5 J 40.2 71.4 60.5 30.1 ND ND Cadmium 23-Aug-17 EPA 6010 0.50 1.0 ND ND ND 0.56 J ND ND ND NC 2L = 2 pg/L 6-Feb-18 1.0 ND ND ND ND 0.59 J ND ND 16-Aug-18 EPA 6010D 0.50 1.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 6010D 0.50 1.0 ND ND ND ND ND ND ND 8-Aug-19 1 0.50 1.0 ND ND ND ND ND ND ND Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 1 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Chromium 13-Jun-12 10.0 ND ND ND 10.9 ND ND ND 22-Aug-12 10.0 ND ND ND 10.4 18.3 ND ND 25-Sep-12 10.0 ND ND ND 10.3 ND ND ND NC 2L = 10 pg/L 17-Oct-12 10.0 ND ND ND 15.8 20.9 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 10.0 ND ND ND 5.1 J ND ND ND 12-Mar-15 EPA 6010 2.50 10.0 ND 3.0 J ND ND ND ND ND 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.50 10.0 ND ND ND ND ND 3.00 J ND 11-Aug-16 EPA 6010 2.50 10.0 2.8 J ND ND 4.3 J 6.3 J ND ND 14-Feb-17 EPA 6010 2.50 10.0 ND ND ND ND 4.4 J ND ND 23-Aug-17 EPA 6010 2.50 10.0 ND ND ND ND 4.5 J ND ND 6-Feb-18 10.0 4.4 J ND ND ND ND ND ND 16-Aug-18 EPA 6010D 2.50 10.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 6010D 2.50 5.0 ND ND ND ND ND ND ND 1-Jan-00 5 2.50 5.0 ND ND ND 1 J ND ND ND Cobalt 13-Jun-12 10.0 ND ND ND ND ND ND ND 22-Aug-12 10.0 ND ND ND ND ND ND ND 25-Sep-12 10.0 ND ND ND ND ND ND ND GWPS = 1 pg/L 17-Oct-12 10.0 10.3 ND ND ND 12.4 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.00 10.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 2.50 10.0 ND ND ND ND ND 3.6 J ND 18-Aug-15 10.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 2.50 10.0 ND ND ND ND ND ND ND 11-Aug-16 EPA 6010 2.50 10.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 6010 2.50 10.0 ND ND ND ND ND 3.2 J ND 23-Aug-17 EPA 6010 2.50 10.0 ND ND ND ND ND ND ND 6-Feb-18 10.0 3.4 J ND ND ND ND ND ND 16-Aug-18 EPA 6010D 2.50 10.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 6010D 2.50 5.0 ND ND ND ND ND ND ND 8-Aug-19 EPA 6010D 2.50 5.0 ND ND ND ND 1.2 J ND ND Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 2 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Copper 13-Jun-12 10.0 ND ND ND 46 ND ND ND 22-Aug-12 10.0 ND ND ND 56.2 19.8 ND ND 25-Sep-12 10.0 7.4 J ND ND 63.6 5.7 J ND ND NC 2L = 1,000 pg/L 17-Oct-12 10.0 19.9 7.6 J ND 35.5 23.1 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND 7.9 J ND ND ND 13-Aug-14 EPA 6010 5.00 10.0 ND 11.6 ND 13.4 ND ND ND 12-Mar-15 EPA 6010 2.50 10.0 ND 47.0 ND 6.0 J ND 3.3 J ND 18-Aug-15 10.0 2.8 J 26.6 ND 12.3 ND 4.3 J ND 18-Feb-16 EPA 6010 2.50 10.0 ND 7.8 J ND ND ND ND ND 11-Aug-16 EPA 6010 2.50 10.0 ND 30.7 ND 14.6 4.5 J 2.7 J ND 14-Feb-17 EPA 6010 2.50 10.0 ND 16.6 3.2 J 9.9 J 4.9 J 3.9 J ND 23-Aug-17 EPA 6010 2.50 10.0 8.8 J 6.4 J ND 6.4 J 4.5 J ND ND 6-Feb-18 10.0 18.6 133 3.7 J 5.4 J ND ND ND 16-Aug-18 EPA 6010D 2.50 10.0 ND 24.7 ND 3.6 J NM ND ND 5-Feb-19 EPA 6010D 2.50 5.0 ND 11 ND 3 J ND ND ND 8-Aug-19 EPA 6010D 2.50 5.0 2.5 J 8.3 ND 6.9 ND ND ND Iron 6-Feb-18 300 9990 1500 1190 1670 1630 353 ND 16-Aug-18 EPA 6010D 25.00 300 340 --- - --- NM --- 27.8 J 5-Feb-19 EPA 6010D 25.00 50 183 --- --- --- --- --- ND 8-Aug-19 EPA 6010D 25.00 50 176 NC 2L = 300 pg/L (2/5/10) Lead 14-Feb-17 EPA 6010 2.50 10.0 ND ND ND ND 2.9 J ND ND NC 2L= 15 pg/L 23-Aug-17 EPA 6010 2.50 10.0 ND ND ND ND ND ND ND 6-Feb-18 EPA 6010 2.50 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 6010 2.50 10.0 ND ND ND ND NM ND ND Manganese 6-Feb-18 50.0 241 394 53.0 25.8 J 410 411 ND 16-Aug-18 EPA 6010D 2.50 50.0 6.7 J --- - --- NM --- ND 5-Feb-19 EPA 6010D 2.50 5.0 5.5 --- - - --- ND 8-Aug-19 EPA 6010D 2.50 5.0 6 NC 2L = 50 pg/L (2/5/10) Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 3 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Nickel 13-Jun-12 50.0 ND ND ND ND ND ND ND 22-Aug-12 50.0 ND ND ND ND 6.1 J ND ND 25-Sep-12 50.0 ND ND ND ND ND ND ND NC 2L = 100 pg/L 17-Oct-12 50.0 ND ND ND 6.9 J 8.9 J ND ND 6-Aug-13 50.0 ND ND ND ND ND ND ND 25-Feb-14 50.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.00 50.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 2.50 50.0 ND ND ND ND ND ND ND 18-Aug-15 50.0 ND ND ND ND 2.7 J ND ND 18-Feb-16 EPA 6010 2.50 50.0 ND ND ND ND 2.9 J ND ND 11-Aug-16 EPA 6010 2.50 50.0 ND ND ND ND 6.2 J ND ND 14-Feb-17 EPA 6010 2.50 50.0 ND ND ND ND 5.2 J ND ND 23-Aug-17 EPA 6010 2.50 50.0 5.2 J ND ND 2.8 J 5.8 J ND ND 6-Feb-18 50.0 5.9 J ND ND ND 3.4 J ND ND 16-Aug-18 EPA 6010D 2.50 50.0 ND ND ND ND NM ND ND 5-Feb-19 EPA6010D 2.50 5.0 ND ND ND ND 2.7 J ND ND 8-Aug-19 EPA6010D 2.50 5.0 0.93 J ND ND 1.6 J 3.2 J ND ND Thallium 13-Jun-12 5.5 ND ND ND ND ND ND ND 22-Aug-12 5.5 ND 6.8 6.8 ND ND ND ND 25-Sep-12 5.5 ND ND ND ND ND ND ND GWPS = 0.28 pg/L 17-Oct-12 5.5 ND ND ND ND ND ND ND 6-Aug-13 5.5 ND ND ND ND ND ND ND 25-Feb-14 5.5 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 5.40 5.5 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 5.00 5.5 ND ND ND ND ND ND ND 18-Aug-15 5.5 ND ND ND ND ND ND ND 18-Feb-16 EPA 6010 5.00 5.5 ND ND ND ND ND ND ND 11-Aug-16 EPA 6010 5.00 5.5 ND ND ND ND ND ND ND 14-Feb-17 EPA 6020B 0.02 5.5 0.039 J 0.059 J ND ND ND ND ND 23-Aug-17 EPA 6020B 0.02 5.5 0.04 J 0.044 J ND ND 0.021 J ND ND 6-Feb-18 0.10 ND 0.034 J ND ND ND ND ND 16-Aug-18 EPA 6020B 0.02 5.50 ND ND ND ND NM ND ND 5-Feb-19 EPA 6020B 0.06 0.10 ND ND ND ND ND ND ND 8-Aug-19 EPA 6020B 0.06 0.10 ND ND ND ND ND ND ND Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 4 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks Vanadium 13-Jun-12 25.0 5.2 J ND ND 27.8 17.3 J 11 J ND 22-Aug-12 25.0 ND ND ND 30.2 69.5 9 J ND 25-Sep-12 25.0 8.3 J ND ND 33.4 16.5 J 8.2 J ND GWPS = 0.3 pg/L 17-Oct-12 25.0 29.7 ND ND 19.5 J 63.8 6.2 J ND 6-Aug-13 25.0 ND ND ND ND 9.2 J ND ND 25-Feb-14 25.0 ND ND ND 10.2 J ND ND ND 13-Aug-14 EPA 6010 5.00 25.0 ND ND ND 11.8 J ND ND ND 12-Mar-15 EPA 6010 2.50 25.0 ND 4.4 J 7.3 J 5.0 J ND 6.7 J ND 18-Aug-15 25.0 6.1 J ND ND 6.5 J 3.6 J 9.1 J ND 18-Feb-16 EPA 6010 2.50 25.0 ND 2.9 J ND ND ND ND ND 11-Aug-16 EPA 6010 2.50 25.0 ND ND 5.8 J 10.0 J 14.3 J 6.6 J ND 14-Feb-17 EPA 6010 2.50 25.0 ND ND 5.2 J 4.0 J 9.1 J 5.4 J ND 23-Aug-17 EPA 6010 2.50 25.0 18.6 J ND 2.6 J 4.6 J 11.9 J 6.4 J ND 6-Feb-18 25.0 23.5 J 3.4 J 4.4 J 4.7 J 3.3 J ND ND 16-Aug-18 EPA 6010D 2.50 25.0 ND ND ND 2.9 J NM 2.5 J ND 5-Feb-19 EPA 6010D 2.50 5.0 ND ND ND 2.9 J ND ND ND 8-Aug-19 EPA 6010D 2.50 5.0 2.2 J ND ND 5.3 1.8 J ND ND Resample-> 4-Sep-19 EPA 6010D 1.30 5.0 NS NS NS ND NS NS NS Zinc 13-Jun-12 10.0 ND ND ND 10.5 ND ND ND 22-Aug-12 10.0 ND ND 32 31 21.9 10.6 ND 25-Sep-12 10.0 11.7 ND ND 14.8 ND ND ND NC 2L = 1,000 pg/L 17-Oct-12 10.0 32.5 ND ND 10.5 29 ND ND 6-Aug-13 10.0 ND ND ND ND ND ND ND 25-Feb-14 10.0 ND ND ND ND ND ND ND 13-Aug-14 EPA 6010 10.00 10.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 6010 5.00 10.0 9.8 B 10.9 B 10.7 B 8.7 B 7.8 B 9.9 B 6.1 J 18-Aug-15 10.0 8.9 B ND ND ND ND 5.2 B 11.5 J 18-Feb-16 EPA 6010 5.00 10.0 ND 13.1 ND ND ND 8.6 J ND 11-Aug-16 EPA 6010 5.00 10.0 7.2 J 5.4 J ND 19.5 11.7 8.7 J ND 14-Feb-17 EPA 6010 5.00 10.0 7.0 J 6.0 J 5.4 J 5.3 J 8.3 J 6.0 J ND 23-Aug-17 EPA 6010 5.00 10.0 18.0 ND 6.3 J 5.1 J 15.5 6.9 J ND 6-Feb-18 10.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 6010D 5.00 10.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 6010D 5.00 10.0 ND ND ND ND ND ND ND 8-Aug-19 EPA 6010D 5.00 10.0 ND ND ND ND ND ND ND Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 5 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL RL MW-7 MW-8 MW-9 MW-10 MW-11 NES-2S Blanks ORGANICS cis-1,2-Dichloroethene 18-Aug-15 EPA 8260 5.00 5.0 0.71 J 0.36 J ND ND ND ND ND NC 2L = 70 pg/L 18-Feb-16 EPA 8260 5.00 5.0 ND ND ND ND ND ND ND 11-Aug-16 EPA 8260 5.00 5.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 8260 0.19 5.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 8260 0.19 5.0 ND ND ND ND ND ND ND 6-Feb-18 EPA 8260 0.19 5.0 ND ND ND ND ND ND ND 16-Aug-18 EPA 8260B 0.19 5.0 ND ND ND ND NM ND ND 5-Feb-19 EPA8260B 0.29 1.0 ND ND ND ND ND ND ND 8-Aug-19 EPA8260B 0.29 1.0 ND ND ND ND ND ND ND Methylene Chloride 14-Feb-17 EPA 8260 0.97 1.0 ND ND ND ND ND ND 1.0 23-Aug-17 EPA 8260 0.97 1.0 ND ND ND ND ND ND 2.7 NC 2L= 3.0 pg/L 6-Feb-18 1.0 ND ND ND ND ND ND ND 16-Aug-18 EPA8260B 0.97 1.0 ND ND ND ND NM ND ND 5-Feb-19 EPA8260B 3.70 5.0 ND ND ND ND ND ND ND 8-Aug-19 EPA8260B 3.70 5.0 ND ND ND ND ND ND ND Trichlorofluoromethane 13-Jun-12 1.0 ND ND ND ND 0.8 B 0.85 B 0.74 J 22-Aug-12 1.0 ND ND ND ND ND ND ND NC 2L = 2,000 pg/L 25-Sep-12 1.0 ND ND ND ND ND ND ND 17-Oct-12 1.0 ND ND ND ND ND ND ND 6-Aug-13 1.0 ND ND ND ND ND ND ND 25-Feb-14 1.0 ND ND ND ND ND ND ND 13-Aug-14 2.0 ND ND ND ND ND ND ND 12-Mar-15 EPA 8260 0.20 1.0 ND ND ND ND ND ND ND 18-Aug-15 1.0 ND ND ND ND ND ND ND 18-Feb-16 EPA 8260 0.20 1.0 ND ND ND ND ND ND ND 11-Aug-16 EPA 8260 0.20 1.0 ND ND ND ND ND ND ND 14-Feb-17 EPA 8260 0.20 1.0 ND ND ND ND ND ND ND 23-Aug-17 EPA 8260 0.20 1.0 ND ND ND ND ND ND ND 6-Feb-18 1.0 ND ND ND ND ND ND ND 16-Aug-18 EPA8260B 0.20 1.0 ND ND ND ND NM ND ND 5-Feb-19 EPA8260B 0.31 1.0 ND ND ND ND ND ND ND 8-Aug-19 EPA8260B 0.31 1.0 ND ND ND ND ND ND ND 1,4-Dioxane (p-Dioxane) 16-Aug-18 EPA 8260B Mod. 1.90 2.0 ND ND ND ND NM ND ND 5-Feb-19 EPA 8260BMod. 1.90 2.0 ND ND ND ND ND ND ND NC 2L = 3 pg/L 8-Aug-19 EPA 8260B Mod. 1.90 2.0 ND ND ND ND ND ND ND Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 6 of 7 TABLE A3-2: Historical Groundwater Constituents Analyte Sample Date EPA Method DL I RL I MW-7 I MW-8 I MW-9 I MW-10 I MW-11 I NES-2S I Blanks Notes: All concentrations are in micrograms per liter (pg/L). RL = Reporting Limit (SWSL - December 2006 -2017; Lab MRL or PQL - 2017 to present). DL = Laboratory detection limit. J = Estimated value between the DL and the RL. B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks. ND = Not detected above laboratory reporting limit. NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. IMAC = Interim Maximum Allowable Concentration. When the NC 2L has not been established, the IMAC will be used. Bold values for groundwater are above the NC 2L Standards or IMACs. — = Well was not monitored and/or not reported. * Detections of c-1,2-DCE in MW-7 and MW-8 in August 2015 are suspect. The sample collected from MW-7 at the same time for Unit 1 showed no detected c-1,2-DCE. Granville Co. - Oxford Landfill, Unit 2 Labella Associates Permit No. 3901-MSWLF-2012 Page 7 of 7 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Inorganics Arsenic 12-Mar-15 EPA 6010 2.5 10.0 4.9 J 2.7 J ND ND ND NC 213 = 50 (05/01/07) 19-Aug-15 2.5 10.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND 11-Aug-16 EPA 6010 2.5 10.0 6.8 J 7.3 J ND ND ND 14-Feb-17 EPA 6010 5.0 10.0 ND ND ND ND ND 23-Aug-17 EPA 6010 5.0 10.0 ND Dry ND ND ND 6-Feb-18 5.0 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 5.0 10.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 5.0 10.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 4.7 10.0 5.1 J ND ND 6.1 J -- Barium 13-Aug-14 EPA 6010 5.0 100 47.4 J 43.9 J 22.1 J 33.9 J ND 12-Mar-15 EPA 6010 2.5 100 28.5 J 42 J 22.5 J 24.6 J ND NC 213 = NE (05/01/07) 19-Aug-15 2.5 100 37 J Dry 23.9 J 32.7 J ND 18-Feb-16 EPA 6010 2.5 100 58.2 J 55.0 J 22.0 J 26.3 J ND 11-Aug-16 EPA 6010 2.5 100 175 152 23.4 J 26.5 J ND 14-Feb-17 EPA 6010 2.5 100 285 38.2 J 18.6 J 21.4 J ND 23-Aug-17 EPA 6010 2.5 100 31.6 J Dry 32.3 J 33.3 J ND 6-Feb-18 2.5 100 22.4 J 33.5 J 23.7 J 32.3 J ND 16-Aug-18 EPA 6010D 2.5 100 19.1 J 28.3 J 24.2 J 38.2 J ND 5-Feb-19 EPA 6010D 2.5 5.0 47.6 30.7 22.9 23.1 ND 8-Aug-19 EPA 6010D 1.0 5.0 23 17.3 23.3 44.5 - Beryllium 11-Aug-16 EPA 6010 0.50 1.0 1.9 1.7 ND ND ND 14-Feb-17 EPA 6010 0.50 1.0 ND ND ND ND ND NC 2B = 6.5 ug/L 23-Aug-17 EPA 6010 0.50 1.0 ND Dry ND ND ND 6-Feb-18 0.50 1.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 0.50 1.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 0.50 1.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 0.20 1.0 ND ND ND ND -- Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012 Page 1 of 5 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Chromium 13-Aug-14 EPA 6010 5.0 10.0 10.8 10 J ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 4.0 J 3.1 J ND 2.6 J ND INC 2B = 50 pg/L (05/01/07) 19-Aug-15 2.5 10.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND NC 2B = 24 pg/L (3/01/16) 11-Aug-16 EPA 6010 2.5 10.0 63.0 55.1 5.2 J ND ND 13-Sep-16 2.5 10.0 13.8 (ND) DRY NS NS ND 14-Feb-17 EPA 6010 2.5 10.0 6.1 J 7.2 J 3.0 J ND ND 23-Aug-17 EPA 6010 2.5 10.0 7.0 J Dry ND ND ND 6-Feb-18 2.5 10.0 2.8 J 5.4 J ND 2.7 J ND 16-Aug-18 EPA 6010D 2.5 10.0 ND 3.2 J ND ND ND 5-Feb-19 EPA 6010D 2.5 5.0 3.0 J ND ND ND ND 8-Aug-19 EPA 6010D 1.0 5.0 2.6 J 2.1 J ND 2.2 J -- Cobalt 11-Aug-16 EPA 6010 2.5 10.0 16.7 12.7 ND ND ND 14-Feb-17 EPA 6010 2.5 10.0 4.0 J ND ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 ND Dry ND ND ND 6-Feb-18 2.5 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 2.5 10.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 1.1 5.0 1.4 J ND ND 2.9 J -- Copper 13-Aug-14 EPA 6010 5.0 10.0 9.6 J 7.7 J ND ND ND 12-Mar-15 EPA 6010 2.5 10.0 3.1 J 2.6 J ND ND ND NC 2B = 7 pg/L (05/01/07) 19-Aug-15 2.5 10.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 10.0 6.3 J 5.7 J ND ND ND NC 2B = 2.7 pg/L (3/01/16) 11-Aug-16 EPA 6010 2.5 10.0 39.9 34.5 ND ND ND Resample > 13-Sep-16 2.5 10.0 9.3 (2.5 B) B DRY NS NS 3.5 B 14-Feb-17 EPA 6010 2.5 10.0 5.8 J 5.2 J ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 4.5 J Dry ND ND ND 6-Feb-18 2.5 10.0 6.8 J 8.0 J 2.7 J 3.6 J ND 16-Aug-18 EPA 6010D 2.5 10.0 3.9 J 3.0 J ND ND ND 5-Feb-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 2.1 5.0 4.4 J 3.6 J 2.7 J 2.7 J -- Iron 6-Feb-18 25.0 300 NS NS 1520 2920 ND 16-Aug-18 EPA 6010D 25.0 300 3320 2750 --- --- 27.8 J 5-Feb-19 EPA 6010D 25.0 50 - - --- --- ND INC 2L = 300 pg/L (2/5/10) Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012 Page 2 of 5 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Lead 18-Feb-16 EPA 6010 2.5 10.0 4.0 B 2.6 B ND ND 2.7 J NC 2B = 25 (05/01/07) 11-Aug-16 EPA 6010 2.5 10.0 16.6 13.6 ND ND ND Resample > 13-Sep-16 2.5 10.0 4.1(2.6 J) J DRY NS NS ND 14-Feb-17 EPA 6010 2.5 10.0 2.5 J 2.5 J ND ND ND 23-Aug-17 EPA 6010 2.5 10.0 2.5 J Dry ND ND ND 6-Feb-18 2.5 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 2.5 10.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 1.6 5.0 ND ND ND 1.6 J --- Manganese 6-Feb-18 2.5 50.0 NS NS 11.6 J 25.8 J ND NC 2L = 50 pg/L (2/5/10) 16-Aug-18 EPA 6010D 2.5 50.0 176 45.2 J --- --- ND 5-Feb-19 EPA 6010D 2.5 5.0 - --- --- --- ND Nickel 13-Aug-14 EPA 6010 5.0 50.0 7.5 J 5.4 J ND ND ND 12-Mar-15 EPA 6010 2.5 50.0 3 J 2.8 J ND ND ND NC 2B = 88 pg/L (05/01/07) 19-Aug-15 2.5 50.0 ND Dry ND ND ND 18-Feb-16 EPA 6010 2.5 50.0 3.3 J 3.0 J ND ND ND 11-Aug-16 EPA 6010 2.5 50.0 22.8 J 19.4 J 2.8 J ND ND 14-Feb-17 EPA 6010 2.5 50.0 4.2 J 4.1 J ND ND ND 23-Aug-17 EPA 6010 2.5 50.0 3.7 J Dry ND ND ND 6-Feb-18 2.5 50.0 ND 3.2 J ND ND ND 16-Aug-18 EPA 6010D 2.5 50.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 2.5 5.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 0.9 5.0 2.9 J 1.8 J ND 1.9 J --- Selenium 11-Aug-16 EPA 6010 5.0 10.0 ND 6.0 J ND ND ND 14-Feb-17 EPA 6010 5.0 10.0 ND ND ND ND ND 23-Aug-17 EPA 6010 5.0 10.0 ND Dry ND ND ND 6-Feb-18 5.0 10.0 ND ND ND ND ND 16-Aug-18 EPA 6010D 5.0 10.0 ND ND ND ND ND 5-Feb-19 EPA 6010D 5.0 10.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 4.7 10.0 ND ND ND ND -- Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012 Page 3 of 5 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Vanadium 13-Aug-14 EPA 6010 5.0 25.0 18.0 J 18.2 J ND 9.3 J ND 12-Mar-15 EPA 6010 2.5 25.0 7.8 J 8.3 J 3.1 J 6.3 J ND NC 2B = NE (05/01/07) 19-Aug-15 2.5 25.0 2.8 J Dry 2.7 J 4.3 J ND 18-Feb-16 EPA 6010 2.5 25.0 6.4 J 6.1 J ND ND ND 11-Aug-16 EPA 6010 2.5 25.0 160 144 ND 2.7 J ND 14-Feb-17 EPA 6010 2.5 25.0 18.2 J 20.8 J ND ND ND 23-Aug-17 EPA 6010 2.5 25.0 20.5 J Dry 4.6 J ND ND 6-Feb-18 2.5 25.0 6.9 J 14.4 J 4.3 J 8.2 J ND 16-Aug-18 EPA 6010D 2.5 25.0 7.6 J 5.8 J 3.7 J ND ND 5-Feb-19 EPA 6010D 2.5 5.0 6.5 4.9 J ND ND ND 8-Aug-19 EPA 6010D 1.3 5.0 8.5 6.7 3.3 J 7.9 -- Zinc 13-Aug-14 EPA 6010 5.0 10.0 14.3 ND ND ND ND 12-Mar-15 EPA 6010 5.0 10.0 62.3 11.6 B 8.5 B 10.8 B 6.1 J NC 2B = 50 pg/L (05/01/07) 19-Aug-15 5.0 10.0 ND Dry ND ND 11.5 J 18-Feb-16 EPA 6010 5.0 10.0 13.0 11.0 ND ND ND NC 2B = 36 pg/L (03/01/16) 11-Aug-16 EPA 6010 5.0 10.0 66.4 54.1 13.0 5.6 J ND Resample > 13-Sep-16 5.0 10.0 14.5 (5.9 J) B DRY NS NS ND 14-Feb-17 EPA 6010 5.0 10.0 11.0 9.6 J 7.0 J ND ND 23-Aug-17 EPA 6010 5.0 10.0 7.6 J Dry ND ND ND 6-Feb-18 5.0 10.0 9.4 J 6.8 J ND ND ND 16-Aug-18 EPA 6010D 5.0 10.0 6.2 J ND ND ND ND 5-Feb-19 EPA 6010D 5.0 10.0 ND ND ND ND ND 8-Aug-19 EPA 6010D 3.9 10.0 7.3 J ND ND 7.2 J -- Hardness, Total(SM 2340B) 5-Feb-19 EPA 6010D 662 662 38800 55700 13800 17400 NM 8-Aug-19 EPA 6010D 131 662 19800 26400 17400 28200 - Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012 Page 4 of 5 TABLE A3-3: Historical Surface Water Constituents Analyte Sample Date EPA Method DL RL SW-1 SW-2 SW-3 SW-4 Blanks Organics 2-Hexanone 11-Aug-16 EPA 8260 0.46 50.0 1.2 J ND ND ND ND 14-Feb-17 EPA 8260 0.46 50.0 ND ND ND ND ND 23-Aug-17 EPA 8260 0.46 50.0 ND Dry ND ND ND 6-Feb-18 0.46 50.0 ND ND ND ND ND 16-Aug-18 EPA 8260B 0.46 50.0 ND ND ND ND ND 5-Feb-19 EPA 8260B 0.57 5.0 ND ND ND ND ND 8-Aug-19 EPA 8260D 0.57 5.0 ND ND ND ND — 1,4-Dioxane (p-Dioxane) 16-Aug-18 EPA 8260B Mod. 1.90 2.0 ND 4.5 ND ND ND 5-Feb-19 EPA 8260B Mod. 1.90 2.0 ND 5.9 ND ND ND 8-Aug-19 EPA 8260D Mod. 1.20 2.0 ND 2.6 ND ND -- Notes: All concentrations are in micrograms per liter (pg/L). RL = Reporting Limit (SWSL for December 2006 - present). DL = Laboratory detection limit. J = Estimated value between the DL and the RL. B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks. ND = Not detected above laboratory reporting limit. NS = Not sampled. NR = Not Reported. Dry =Surface water point considered to be dry. NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B. NE = Not established. Bold values for surface water are above the NC 2B. Surface waters are classified as fresh -water aquatic life. 9/13/16 RESAMPLE = Parenthesis indicate Dissolved concentrations. Granville Co. - Oxford Landfill, Unit 2 La Bella Associates Permit No. 3901-MSWLF-2012 Page 5 of 5 TABLE A3-4: Historical Groundwater Field Parameters PARAMETER SAMPLE DATE MW-7 MW-8 MW-9 MW-10 MW-11 NES-21D NES-2S pH 3/12/2015 6.53 7.45 6.96 6.73 6.8 -- 6.5 (S.U.) 8/18/2015 6.27 7.77 6.98 6.01 6.02 - 5.88 2/18/2016 6.89 7.45 7.11 6.93 6.46 - 6.13 8/10/2016 4.55 5.51 5.01 5.34 5.31 - 6.13 2/15/2017 6.52 7.90 7.43 6.04 6.14 - 6.42 8/23/2017 6.63 7.36 7.47 6.55 6.04 - 6.65 2/7/2018 6.51 7.68 7.53 6.31 7.00 - 5.86 8/16/2018 6.61 7.79 7.18 5.98 6.03* - 6.02 2/5/2019 6.32 8.16 7.24 6.73 6.04 8.06 6.18 8/8/2019 6.01 7.55 6.39 6.34 6.32 - 5.55 Resample -> 9/4/2019 --- - --- 5.38 --- - -- Temperature 3/12/2015 13.9 14.7 15.6 12.1 12.3 - 15.9 (° C) 8/18/2015 17.26 19.6 21.62 21.09 19.56 - 19.09 2/18/2016 12.8 15.6 14.7 12.6 12.1 - 11.3 8/10/2016 16.70 18.70 15.80 18.40 17.40 - 18.30 2/15/2017 12.00 14.80 14.70 14.60 13.40 - 11.60 8/23/2017 16.8 21.0 15.9 17.5 18.2 - 18.4 2/7/2018 14.9 14.55 15.1 12.8 12.7 - 11.3 8/16/2018 17.9 20.6 20.4 22.1 22.0* - 28.1 2/5/2019 15.9 17.0 15.2 13.3 15.1 17.4 18.8 8/8/2019 20.4 20.0 20.2 20.0 23.22 - 22.7 Resample -> 9/4/2019 --- - --- 24.9 -- - -- Conductivity 3/12/2015 123.4 193.8 285.7 141.2 84.8 - 114.2 (PS/cm) 8/18/2015 284 282 268 108 89 - 112 2/18/2016 250 195.8 290.3 166.7 122.9 - 95.7 8/10/2016 287.10 215.00 249.40 132.10 131.00 - 123.70 2/15/2017 239.00 182.70 268.40 83.40 108.30 - 112.40 8/23/2017 297.2 222.2 284.3 89.3 116.4 - 133.3 2/7/2018 285 187 277 43.0 95.0 - 107 8/16/2018 364.1 242.4 337.5 151.1 153.0* - 246.8 2/5/2019 305.1 226.3 282.7 161.6 127.5 347.8 133.1 8/8/2019 319.5 211.8 292.3 132.7 133.9 - 136.1 Resample -> 9/4/2019 --- - --- 150.6 -- - -- Turbidity 3/12/2015 5.33 15.2 25.1 9.2 9.57 - 8.75 (NTU) 8/18/2015 22.7 12.84 10.2 10.9 10.0 - 11.85 2/18/2016 8.25 10.25 11.2 11.25 25.4 - 8.55 8/10/2016 7.95 11.17 10.25 11.92 15.25 - 16.41 2/15/2017 4.54 4.44 10.78 9.10 12.45 - 5.25 8/23/2017 12.7 5.41 5.98 10.8 20.25 - 9.38 2/7/2018 15.4 16.69 17.05 30.0 27.18 - 18.06 8/16/2018 4.64 15.08 2.10 23.96 13.84* - 17.35 2/5/2019 6.57 5.96 3.49 20.20 16.90 0.99 3.05 8/8/2019 6.31 2.42 8.58 40.30 11.60 - 1.44 Resample -> 9/4/2019 --- - --- 0.95 -- - -- Dissolved Oxygen (mg/L) 8/8/2019 2.43 2.58 1.55 2.12 2.09 - 0.50 Resample -> 9/4/2019 --- - --- 0.44 --- - -- Oxidation Reduction Potential (mV) 8/8/2019 180.2 125.5 145.4 166.1 178.3 - 183.7 Resample --> 9/4/2019 --- - --- 128.9 --- - -- Notes: uS/cm = microSemens per centimeter. mg/L = milligrams per liter. °C= degrees Centigrade. mV = millivolts. S.U.= Standard Units. -= Data not available. NTU = Nephelometric Turbidity Units. Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012 TABLE A3-5: Historical Surface Water Field Parameters PARAMETER SAMPLE DATE SW-3 SW-4 pH 3/12/2015 7.25 6.94 (S.U) 8/18/2015 7.55 6.39 2/18/2016 7.35 6.88 8/10/2016 5.63 5.39 2/15/2017 7.01 6.35 8/23/2017 6.96 6.42 2/7/2018 6.75 6.25 8/16/2018 8.00 6.58 2/6/2019 7.61 7.44 8/8/2019 6.99 6.30 Temperature 3/12/2015 13.3 14.4 (° C) 8/18/2015 25.20 23.44 2/18/2016 10.8 10.2 8/10/2016 24.30 23.40 2/15/2017 10.90 6.90 8/23/2017 23.70 23.40 2/7/2018 8.95 8.25 8/16/2018 24.0 22.0 2/6/2019 13.7 11.7 8/8/2019 23.4 23.4 Conductivity 3/12/2015 39.3 46.3 (PS/cm) 8/18/2015 72 88 2/18/2016 33.7 36.4 8/10/2016 53.70 84.90 2/15/2017 51.00 45.70 8/23/2017 72.80 111.10 2/7/2018 40.0 47.0 8/16/2018 76.4 126.7 2/6/2019 43.8 52.1 8/8/2019 58.0 72.2 Turbidity 3/12/2015 17 37.7 (NTU) 8/18/2015 7.87 32.9 2/18/2016 13.1 43.5 8/10/2016 10.05 7.87 2/15/2017 11.70 5.80 8/23/2017 25.71 17.51 2/7/2018 22.45 44.03 8/16/2018 22.90 15.00 2/6/2019 16.70 27.50 8/8/2019 28.51 28.70 Dissolved Oxygen 8/8/2019 1.64 1.88 (mg/L) Oxidation Reduction Poten 8/8/2019 165.0 189.3 (mV) Notes: pS/cm = microSemens per centimeter. °C= degrees Centigrade. S.U.= Standard Units. NTU = Nephelometric Turbidity Units. Granville Co. - Oxford Landfill, Unit 2 LaBella Associates Permit No. 3901-MSWLF-2012