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HomeMy WebLinkAbout7407_Pitt_CandDLandfillInc_20191017_GW_FID1359974wood. WATER QUALITY MONITORING REPORT J U N E 2019 SEMIANNUAL SAMPLING EVENT CONSTRUCTION AND DEMOLITION DEBRIS LANDFILL, PITT COUNTY FACILITY PERMIT NO. 7407-CDLF-2001, 2009 Prepared For: C&D Landfill, Inc. Prepared By: Wood Environment & Infrastructure Solutions, Inc. Wood Project No.: 6480-19-9035 October 14, 2019 I� wood. October 14, 2019 Ms. Jackie Drummond, Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 2090 US Highway 70 Swannanoa, North Carolina 28778 Subject: C&D Landfill, Inc., Phases 1 and 2 Facility Permit Number 7407-CDLF-2001, 2009 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No.: 6480-19-9035 Dear Ms. Drummond: On behalf of C&D Landfill, Inc., Wood Environment & Infrastructure Solutions, Inc. (Wood; formerly Amec Foster Wheeler) is submitting the enclosed Water Quality Monitoring Report for the June 2019 semiannual monitoring event. The monitoring event was performed between June 13 and 19, 2019. This sampling event included analyzing groundwater samples from each of the active wells for Appendix II constituents, natural attenuation parameters, and 1,4-dioxane. This report provides details of the field activities, laboratory analyses, and presents conclusions and recommendations based on current and historical data. The next semiannual monitoring event is scheduled for December 2019. Please call Sheri Knox at 919-381-9913 if you have any questions or comments. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Damian Hriciga, PG Senior Geologist Enclosed: Water Quality Monitoring Report cc: Wayne Bell David Garrett Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 Tel: (919) 381-9900 / Fax: (919) 381-9901 www.woodplc.com Licensure: NC Engineering F-1253 / NC Geology C-247 ,:�4, �, /<� Sheri Knox, PE, PMP Associate Project Manager 0 0 0 Electronic Data - Email CD Doc/Event #: ' 'NC DENR ' ' Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Sheri Knox Phone: 919.389.9913 E-mail: sheri.knox(a)woodplc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) C&D Landfill, Inc. 802 Recycling Lane 7406-CDLF- .0500 June 12, 13, 18, 19, 2019 CDLF Phases 1&@ Greenville, NC 27834 2001, 2009 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data ❑ Surface water monitoring data Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Damian Hricig$ Senior Geologist 919.381.9000 Facilityfteprese tiv Name (Print) Title Signature Date 4021 Stirrup Creek Drive, Suite 100, Durham, NC 27703 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) (Area Code) Telephone N Affix NC*1p QCY =.2 Seal o,..A, a ai)nnn wood. WATER QUALITY MONITORING REPORT JUNE 2019 SEMIANNUAL SAMPLING EVENT CONSTRUCTION AND DEMOLITION DEBRIS LANDFILL, PITT COUNTY FACILITY PERMIT NO. 7407-CDLF-2001, 2009 Prepared For: C&D Landfill, Inc. 802 Recycling Lane Greenville, North Carolina 27834 (252) 757-0023 Prepared By: Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 (919) 381-9900 Woodplc.com Registered in North Carolina Engineering and Land Surveying License No. F-1253 Wood Project No.: 6480-19-9035 Damian Hriciga, PG Senior Geologist Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 Tel: (919) 381-9900 / Fax: (919) 381-9901 www.woodplc.com Licensure: NC Engineering F-1253 / NC Geology C-247 October 14, 2019 Sheri Knox, PE, PMP Associate Project Manager 0 0 0 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 Table of Contents wood. 1.0 INTRODUCTION...............................................................................................................1 2.0 GROUNDWATER AND SURFACE WATER MONITORING ACTIVITIES ..........................2 3.0 GROUNDWATER LEVELS AND FLOW.............................................................................3 4.0 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS................................3 4.1 Volatile Organic Compounds (VOCs).................................................................3 4.2 Semi -Volatile Organic Compounds (SVOCs) and Pesticides .............................4 4.3 Metals...................................................................................................................4 4.4 Inorganics and other Constituents.....................................................................5 5.0 DISCUSSION OF CONTAMINANTS OF CONCERN.........................................................6 5.1.1 Volatile Organic Compounds...................................................................... 6 5.1.2 Appendix I and 11 Metals............................................................................. 7 6.0 CONCLUSIONS................................................................................................................7 TABLES Table 1— Groundwater Level and Flow Data —June 2019 Table 2 — Summary of Field Parameters —June 2019 Table 3 — Summary of Groundwater Analytical Data — VOCs, SVOCs, and other Contaminants — June 2019 Table 4 — Summary of Surface Water Analytical Data — June 2019 Table 5 — Summary of Groundwater Analytical Data, Metals, Inorganics, and other Constituents — June 2019 Table 6 — Summary of Natural Attenuation Parameters — June 2019 FIGURES Figure 1 — Site Location Map Figure 2 — Monitoring Well and Surface Water Sampling Location Map Figure 3 — Groundwater Elevation Map — June 2019 Figure 4 — Groundwater and Surface Water Standard Exceedance Map — June 2019 APPENDICES Appendix A — Laboratory Analytical Reports Appendix B — Historical Analytical Data and Groundwater Elevations Appendix C — Mann -Kendall Trend Analyses LJ Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 1.0 INTRODUCTION wood. C&D Landfill, Inc. owns and operates the Construction and Demolition Debris Landfill located at 802 Recycling Lane, Greenville, Pitt County, North Carolina (Site; Figure 1). Phase 1 became operational in 2001 and Phase 2 became operational in 2009. The landfill is permitted by the North Carolina Department of Environmental Quality (NCDEQ), Division of Waste Management (DWM), Solid Waste Section (SWS) under Permits 7407-CDLF-2001 and 7407-CDLF-2009. Groundwater and surface water monitoring have been performed at Phase 1 since May 2001, and at Phase 2 since August 2009. Both phases are in the assessment stage of the Assessment and Corrective Action Program for C&DLF Facilities and Units. An Assessment of Corrective Actions (ACM) Report was prepared in October 2017 and monitoring data is currently being evaluated to select a corrective action. This report presents the results of the first semiannual monitoring event for year 2019, and the fourth semiannual analysis of parameters to evaluate monitored natural attenuation (MNA). Analytical data are compared to Groundwater Protections Standards (GWPSs) and Surface Water Protections Standards (SWPSs). GWPSs are either the 15A NCAC 02L .0202 Groundwater Standards (2L Groundwater Standards) or Interim Maximum Allowable Concentrations (IMACs). SWPSs include the 15A NCAC 02B Water Quality Standards for Surface Water (2B Surface Water Standards), North Carolina In -Stream Target Values for Surface Waters (Target Values) or EPA National Recommended Water Quality Criteria for Aquatic Life & Human Health, as appropriate. Phases 1 and 2 of the landfill are separated by a channelized central drainage feature that originates onsite and predates either phase of the landfill. Phase 2 is located north of the drainage feature, while Phase 1 is located to the south. Both phases are isolated from their surroundings by tributaries to Grindle Creek and wetlands. Permitting studies have established the adjacent water bodies as on -site discharge points for the uppermost aquifer. Downgradient areas consist of agricultural and wooded marshland leading to Grindle Creek and on to the Tar River. Much of the downgradient area is beneath the 100-year flood level and is not anticipated to undergo development. No groundwater users have been identified down gradient of the site. The groundwater in the uppermost aquifer is intercepted by the surface streams within and just beyond the facility boundary. The October 2017 ACM Report identified an Area of Concern (AOC) centered on the channelized drainage feature where volatile organic compounds (VOCs) have been reported in groundwater samples. The AOC originates north of the drainage feature, along the south side of Phase 2, and extends south from the drainage feature near MW-8 to the southwest corner of Phase 1 near MW-3S. In 2014 and 2015, an Alternate Source Demonstration (ASD) was performed that focused on the soils within and near the drainage feature, however, the results were inconclusive. The groundwater monitoring network consists of 12 wells within Phase 1 and 10 wells within Phase 2. Within Phase 1 there is one upgradient, background well (MW-1S), eight downgradient compliance wells (MW-2S, MW-3S, MW- 4, MW-5, MW-6, MW-7, MW-3A, and MW-8), and three deeper wells (MW-1D, MW-2D, and MW-3D). Within Phase 2 there are three upgradient wells (MW-9A [background], MW-16, and MW-17), six down gradient compliance (MW-10, MW-11, MW-12S, MW-13, MW-14S, and MW-15), and one deeper well (MW-14D). Well construction data is summarized in Table 1 and well locations are illustrated in Figure 2. Four surface water sampling locations have been defined at the Site (SW-1, SW-2, SW-3, and SW-4). Sampling locations SW-1 and SW-2 monitor the tributary on the south side of Phase 1, which originates offsite to the east with SW-1 monitoring background conditions. Sampling locations SW-3 and SW-4 monitor the tributary (itself partially channelized) on the west side of Phase 2, which originates offsite to the north with SW-4 monitoring background. The surface water sampling locations are illustrated in Figure 2. Page 1 0 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 2.0 GROUNDWATER AND SURFACE WATER MONITORING ACTIVITIES wood. Groundwater and surface water monitoring activities were conducted by Environment 1, Inc. (Environment 1) and are summarized in this section as reported by Environment 1. Groundwater samples were collected from 22 groundwater monitoring wells and 4 surface water sampling locations between June 13 and 19, 2019. The sampling event was conducted in accordance with the Sampling and Analysis Plan dated May 2008, the Groundwater Assessment Work Plan dated June 2009, and the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling. Prior to sampling the monitoring wells, the wellheads were inspected and the depth to water in each was were measured using an electronic water level meter. Depth to water measurements were recorded after a sufficient time for water levels within the wells to have equilibrated with atmospheric pressure. Groundwater was purged and sampled using a peristaltic pump and low -flow methodology. Temperature, pH, dissolved oxygen, oxidation/reduction potential (ORP), and turbidity were measured and recorded. Surface water samples were collected by direct submersion of sample containers into the streams at designated locations. Field parameters measured during the collection of groundwater and surface water samples are summarized in Table 2. Each sample was placed into laboratory -supplied sample bottles by a technician wearing new nitrile gloves. The samples were preserved according to the requirements for the type of analysis, chilled, and returned to Environment 1 in Greenville, North Carolina within the appropriate holding times under chain -of -custody protocols. Environment 1 is a North Carolina certified water quality laboratory (Certification 10). The laboratory analyzed each groundwater sample for the constituents listed in 40 CFR Part 258 Appendix II (Appendix II), plus tetrahydrofuran. Additionally, each groundwater sample was analyzed for 1,4-dioxane in accordance with the SWS May 29, 2018 memorandum. Each surface water sample was analyzed for the constituents in 40 CFR Part 258 Appendix I (Appendix I), plus tetrahydrofuran. In addition to the potential contaminants listed above, each groundwater sample was analyzed for parameters to assess the potential of the aquifer to naturally attenuate contaminant concentrations. To obtain baseline values, each sample was analyzed for the full suite of natural attenuation parameters per the MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities. The parameters included: • Carbon Dioxide • Ethene • Sulfate • Nitrate • Total Organic Carbon (TOC) • Chemical Oxygen Demand (COD) • Alkalinity • Hardness • Methane • Ethane • Sulfide • Hydrogen* • Biological Oxygen Demand (BOD) • Total Dissolved Residue • Volatile Fatty Acids • Iron *Samples from monitoring wells MW-6, MW-7, MW-8, and MW-12 could not be analyzed for hydrogen due to frothing. Page 2 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 3.0 GROUNDWATER LEVELS AND FLOW wood. Depth to groundwater measurements were collected at 22 wells during the June 2019 monitoring event. Excepting MW-4 where an anomalously low measurement was collected during the previous event, groundwater elevations decreased from between 0.37 feet to 2.15 feet across the Site relative to those measured in December 2018. The horizontal direction of groundwater flow was generally to the south-southeast and locally away from the landfill phases, which is consistent with historical observations. Groundwater elevation contours are illustrated on Figure 3. Estimated values for hydraulic conductivity and porosity, as well as the horizontal hydraulic gradients and groundwater flow velocities, are presented in Table 1. The horizontal hydraulic gradients near MW-3A, MW-10, MW-11, and MW-12S were calculated based on data from Figure 3 and vary from approximately 0.002 to 0.014 (ft/ft; Table 1). Comparison of elevation data at MW-2S and MW-2D, and MW-3S and MW-3D indicated the presence of downward vertical gradients of -0.03 ft/ft, at both well pairs. Vertical gradients at the site are typically downward. 4.0 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS Reported concentrations of groundwater constituents were compared to the 2L Groundwater Standards or IMACs. Concentrations of surface water constituents were compared to the 2B Surface Water Standards or other applicable water quality criteria for Class C surface waters. Reported concentrations that are greater than the laboratory method detection limit (MDL), but less than the laboratory method reporting limit (MRL) are estimated and are indicated with a "J" qualifier. Note that for tabulated data prior to the discontinuation of the Solid Waste Section Limit (SWSL) in 2018, "J" qualified data indicates that a concentration was greater than the MDL, but less than the SWSL. Contaminants are summarized below and discussed in Section 5 in context with historical data and natural attenuation parameters as appropriate. The laboratory reports, with chain -of -custody documentation and the electronic data deliverables (EDDs) are included in Appendix A. Historical analytical results for selected contaminants are summarized in Appendix B. 4.1 Volatile Organic Compounds (VOCs) Volatile organic compounds (VC)Cs) in groundwater samples reported at concentrations that exceeded their GWPSs during the June 2019 monitoring event included benzene, vinyl chloride (VC), and 1,4-dioxane (Table 3 and Figure 4). Reported benzene concentrations exceeded the 1 pg/L 2L Groundwater Standard in the samples from MW-8 (1.17 pg/L), MW-10 (2.26 pg/L), MW-11 (1.89 pg/L), and MW-12S (2.52 pg/L). Reported VC concentrations exceeded the 0.03 pg/L 2L Groundwater Standard in the samples from MW-10 (1.77 pg/L), MW-11 (0.69 pg/L), MW-12S (3.33 pg/L), and MW-14S (0.13 J pg/L). Reported 1,4-dioxane concentrations exceeded the 3 pg/L 2L Groundwater Standard in the samples from MW-2S (11.9 pg/L), MW-3S (176 pg/L), MW-3A (66.9 pg/L ), MW-5 (74.2 pg/L), MW-6 (40.1 pg/L ), MW-7 (17 pg/L ), MW- 8 (94.7 pg/L ), MW-10 (10.7 pg/L), MW-11 (9.21 pg/L), and MW-12S (32.8 pg/L). Page 3 0 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. Other VOCs that were reported in June 2019 at concentrations below their 2L Groundwater Standards included: • Acetone • 1,4-Dichlorobenzene • Cis- 1,2-Dichloroethene • Ethylbenzene • Naphthalene • 1,1-Dichloroethane • 1,2-Dichloroethane • 1,2-Dichloropropane • Chloromethane • Toluene In addition to the VOCs noted above, tetrahydrofuran was reported in the samples from 20 wells at concentrations ranging from a J-flagged estimated 0.5 J pg/L (MW-17) to 64.9 pg/L (MW-12S). Analysis for this constituent is required because the VOC is a common constituent of groundwater at construction and debris landfills; however, a GWPS has not been established for tetrahydrofuran. In the surface water samples, toluene was reported at a concentration of 9.47 pg/L in the sample from location SW-1, below the 11 pg/L 2B Standard (Table 4). Tetrahydrofuran was reported in each surface water sample at concentrations ranging from 0.4 J pg/L (SW-4) to 1.14 pg/L (SW-3). No other VOCs were not reported in the surface water samples collected during the July 2019 monitoring event. 4.2 Semi -Volatile Organic Compounds (SVOCs) and Pesticides Based on the laboratory analytical report, concentrations of semi -volatile organic compounds (SVOCs) did not exceed GWPSs in groundwater samples collected during the June 2019 monitoring event (Table 3 and Figure 4). Estimated J-flagged concentrations of acenaphthene (8.1 J pg/L) and fluorene (5.31 J pg/L) that did not exceed their 2L Groundwater Standards were reported in the sample from MW-3S. No other SVOC concentrations were reported in the groundwater samples collected during the June 2019 monitoring event. The 0.068 pg/L concentration of the pesticide Beta-BHC reported in the sample collected from MW-12S exceeded the 0.02 pg/L IMAC (Table 3 and Figure 4). The pesticide Endrin aldehyde was reported in the samples from MW- 2S and MW-3A at concentrations below the 2L Groundwater Standard of 2 pg/L. No other pesticide concentrations were reported in the groundwater samples collected during the June 2019 monitoring event. 4.3 Metals Based on the laboratory analytical report, metals concentrations in groundwater samples that exceeded GWPSs during the June 2019 monitoring event included antimony, arsenic, barium, cobalt, chromium, iron, manganese and vanadium (Table 5). Concentrations that exceeded the GWPSs are summarized below. • The antimony concentration reported in the sample from MW-12S (2.9 pg/L) exceeded the 1 pg/L 2L Groundwater Standard. • Arsenic concentrations reported in the samples from MW-3S (20 pg/L), MW-3A (11 pg/L), MW-6 (11 pg/L), MW-8 (19 pg/L), and MW-12S (54 pg/L) exceeded the 10 pg/L 2L Groundwater Standard. Barium concentrations reported in the samples from MW-6 (776 pg/L) and MW-12S (759 pg/L) exceeded the 700 pg/L 2L Groundwater Standard. Page 4 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. • Cobalt concentrations reported in the samples from MW-2S (1.3 pg/L), MW-3S (2.9 pg/L), MW-3A (6 pg/L), MW-5 (4 pg/L), MW-6 (3.5 pg/L), MW-7 (8 pg/L), MW-8 (3.8 pg/L), MW-10 (1.9 pg/L), and MW-12S (3.2 pg/L) exceeded the 1 pg/L IMAC. • Chromium concentrations reported in the samples from MW-3S (24 pg/L), MW-7 (14 pg/L), MW-8 (21 pg/L), MW-10 (19 pg/L) and MW-12S (55 pg/L) exceeded the 10 pg/L 2L Groundwater Standard. • Iron concentrations reported in the samples from MW-1S (683 pg/L), MW-11D (2,960 pg/L), MW-2S (10,502 pg/L), MW-3S (26,669 pg/L), MW-3A (28,630 pg/L), MW-4 (5,330 pg/L), MW-5 (14,743 pg/L), MW-6 (21,195 pg/L), MW-7 (34,722 pg/L), MW-8 (41,130 pg/L), MW-9A (2,527 pg/L), MW-11 (19,952 pg/L), MW-12S (2,164 pg/L), MW-13 (5,680 pg/L), MW-14S (8,173 pg/L), MW-15 (6,850 pg/L ), MW-16 (28,823 pg/L), and MW-17 (2,619 pg/L) exceeded the 300 pg/L 2L Groundwater Standard. • Manganese concentrations reported in the samples from MW-11D (207 pg/L), MW-2S (211 pg/L), MW-3S (433 pg/L), MW-3A (790 pg/L), MW-4 (93 pg/L), MW-5 (442 pg/L), MW-6 (692 pg/L), MW-7 (365 pg/L), MW-8 (1,041 pg/L), MW-9A (113 pg/L), MW-10 (158 pg/L) MW-11 (244 pg/L), MW-12S (511 pg/L), MW- 13 (59 pg/L), MW-14S (527 pg/L), MW-15 (97 pg/L ), MW-16 (173 pg/L), and MW-17 (149 pg/L) exceeded the 50 pg/L 2L Groundwater Standard. • Vanadium concentrations reported in the samples from MW-1S (1.5 pg/L), MW-2S (0.6 J pg/L), MW-3S (5.9 pg/L), MW-3A (2.5 pg/L), MW-4 (2.7 pg/L), MW-5 (2.8 pg/L), MW-6 (6.2 pg/L), MW-7 (2.9 pg/L), MW-8 (3.1 pg/L), MW-9A (0.54 J pg/L), MW-10 (9.5 pg/L), MW-11 (3.2 pg/L), MW-12S (40 pg/L), MW-13 (1.5 pg/L), MW-14S (4.2 pg/L), MW-15 (5.7 pg/L ), MW-16 (11.9 pg/L), and MW-17 (2.9 pg/L) exceeded the 0.3 pg/L IMAC. Metals concentrations did not exceed their SWPSs in surface water samples collected during the June 2019 monitoring event (Table 4). 4.4 Inorganics and other Constituents Inorganics and other groundwater constituents reported by the laboratory at concentrations that exceeded GWPSs during the June 2019 monitoring event included chloride, sulfate, and total dissolved residue (TDR). Concentrations that exceeded the GWPSs are summarized below. The chloride concentration reported in the sample from MW-12S (260,000 pg/L) exceeded the 250,000 pg/L 2L Groundwater Standard. • The sulfate concentrations reported in the samples from MW-2S (346,000 pg/L) and MW-16 (612,000 pg/L) exceeded the 250,000 pg/L 2L Groundwater Standard. • The total dissolved residue concentrations reported in the samples from MW-2S (882,000 pg/L), MW-3S (2,000,000 pg/L), MW-3A (1,090,000 pg/L), MW-5 (1,450,000 pg/L)), MW-6 (1,630,000 pg/L), MW-7 (1,470,000 pg/L), MW-8 (2,160,000 pg/L), MW-10 (1,780,000 pg/L), MW-11 (902,000 pg/L), MW-12S (2,150,000 pg/L), MW-14S (603,000 pg/L) and MW-16 (1,310,000 pg/L) exceeded the 500,000 pg/L 2L Groundwater Standard. Page 5 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. The laboratory reported a sulfide concentration of 849 J pg/L in the groundwater sample from MW-10. A GWPS has not been established for sulfide. Inorganics concentrations in groundwater samples are summarized in Table 5. 5.0 DISCUSSION OF CONTAMINANTS OF CONCERN Contaminants of concern identified in the 2017 ACM Report are discussed in the following sections with historical context and in relation to natural attenuation parameters in the following sections. Mann -Kendall statistical analysis was used to assess trends in selected VOC concentrations over time since November 2015. The Mann -Kendall analysis documentation, which includes time versus concentration graphs, is provided in Appendix C. 5.1.1 Volatile Organic Compounds Benzene has historically been reported in samples from wells MW-3A, MW-3S, MW-8, and MW-12S at concentrations that exceed the 2L Groundwater Standard. Benzene has also been reported in samples from MW- 10 since May 2016 and MW-11 since December 2017. Mann -Kendall trend analysis of concentrations in samples from MW-3A, MW-3S, MW-8, and MW-12S since November 2015 indicate that concentrations are probably increasing in MW-125, stable at MW-3S, and MW-8, and that trends cannot be identified at MW-3A (i.e., similar to stable). While reports of benzene in samples from MW-10 and MW-11 are a recent occurrence, Mann Kendall analysis indicates that since benzene was first reported in the wells no trend is evident at MW-10 and concentrations at MW-11 are stable. Data from these wells will continue to be evaluated to determine if the recently reported concentrations are indicative of a long-term increasing trend. The Mann -Kendall analysis documentation is provided in Appendix C. Field measurements and natural attenuation parameters reported during the June 2019 monitoring event suggest that groundwater conditions at wells where benzene is reported are somewhat reducing and not conducive to aerobic biodegradation of benzene; however the absence of increasing concentration trends (with the possible exception of MW-12S) suggests that benzene is naturally attenuating at these locations at a rate roughly equivalent to the "input" of mass to the aquifer system. Vinyl chloride (VC) concentrations that exceed the 2L Groundwater Standard have been reported consistently in samples from MW-12S since 2012 and MW-10 since 2016. Mann -Kendall trend analysis indicates that VC concentrations over the past three years are stable at MW-12S and a trend cannot be identified at MW-10. Sporadic exceedances have also been reported in samples from MW-3A, MW-3S, MW-6, MW-7, and MW-8. VC was reported in the samples from MW-11 and MW-14S for the first time in June 2019. The Mann -Kendall analysis documentation is provided in Appendix C. VC in groundwater is often the result of the reduction of larger chlorinated ethenes, such as trichloroethylene (TCE) and cis-1,2-dichloroethylene (cis-1,2-DCE). Based on the historical presence of these compounds at the Site and considering the reducing groundwater conditions observed, this reduction appears to be the source of VC at the Site and is evidence of natural attenuation processes. The current absence of larger chlorinated ethenes in groundwater samples and the lack of increasing VC concertation trends suggests that additional VC source mass may not be present, and that the VC is attenuating naturally. 1,4-Dioxane concentrations exceeded the 2L Groundwater Standard in shallow samples from across the Site with the exceptions of the wells on the western and northern sides of Phase 2. The highest concentrations were reported in samples from MW-3S (176 pg/L) and MW-8 (94.7 pg/L) within the AOC. 1,4-dioxane was commonly used as Page 6 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. stabilizer for other VOCs, but the compound can be found in a variety of household products and materials. The June 2019 sampling event was second event in which samples were analyzed for 1,4-dioxane and reported concentrations in groundwater were generally consistent with those reported in December 2018. However, a minimum of four samples is necessary to estimate a trend. 1,4-dioxane was not reported in surface water samples during either the December 2018 or July 2019 sampling events. 5.1.2 Appendix I and 11 Metals Each of the metals discussed below occur naturally at the Site and are present in background samples. Changes in the concentrations of these metals likely reflect changing groundwater conditions beneath the landfill and may result from the reducing conditions indicated by field measurements and other natural attenuation parameters. Arsenic has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, and MW-12S. Currently, samples from MW-3S, MW-3A, MW-6, MW-8, and MW-12S were reported to contain arsenic concentrations above its 2L Standard. Barium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-3S, MW-6, MW-7, and MW-12S. Currently, samples from MW-6 and MW-12S were reported to contain barium concentrations above its 2L Standard. Chromium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Historically, elevated chromium concentrations reported in samples from several wells decreased over time to below the 2L Groundwater Standard. More recently, chromium concentrations reported in samples from MW-3S, MW-5, MW-7, MW-8, MW-10, and MW-12S have exceeded the 2L Groundwater Standard. Currently, samples from MW-3S, MW-7, MW-8, MW-10, and MW-12S were reported to contain chromium concentrations above its 2L Standard. Cobalt has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Reported cobalt concentrations typically exceed the IMAC in samples from MW-2S, MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-12S, and MW-14S. Currently, samples from MW- 2S, MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-10, and MW-12S were reported to contain cobalt concentrations above its 2L Standard. Vanadium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Reported concentrations fluctuate over time and generally exceed the low 0.3 pg/L IMAC; however, exceedances are less frequent in the deep wells. Higher concentrations are reported in samples from MW-12S more consistently than in samples from other wells. 6.0 CONCLUSIONS The VOC benzene and VC are consistently reported at concentrations exceeding their 2L Groundwater Standards in samples from shallow site monitoring wells, particularly within and around the AOC; however, these concentrations have generally been stable over recent years and appear to be attenuating naturally. Probably increasing benzene concentrations at MW-12S may be one exception; however, concentrations remain within an order of magnitude of the 2L Groundwater Standard. Recently reported benzene concentrations at MW-11 are Page 7 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. currently stable and will continue to be evaluated to determine if they are indicative of a long-term increasing trend. Groundwater samples have been analyzed for 1,4-dioxane using EPA Method 8260 SIM since December 2018 and reported concentrations have exceeded the 2L Groundwater Standard in wells along the southern sided of Phase 2 and across Phase 1. VOC concentration trends in groundwater will continue to be monitored. Reported VOC concentrations did not exceed SWPSs in surface water samples. Various SVOC concentrations are reported sporadically in samples from shallow monitoring wells, but the concentrations do not typically exceed GWPSs. SVOC concentration trends will continue to be monitored. Concentrations of the pesticide Beta-BHC, and occasionally others, are reported sporadically in in samples from shallow monitoring wells but the concentrations do not typically exceed GWPSs. The trends for these pesticides will continue to be evaluated. Several metals are reported in samples from shallow monitoring wells at concentrations that exceed their 2L Groundwater Standards. These metals can occur naturally at the Site, and the elevated concentrations are likely related to the moderately reducing groundwater conditions indicated by the natural attenuation monitoring. Trends in groundwater conditions at the Site, and their effect on metals concentrations will continue to be evaluated. Groundwater and surface water monitoring will continue on a semi-annual schedule in accordance with the Assessment and Corrective Action Program. Wood is currently in discussions with the SWS regarding selection of corrective measures. Page 8 0 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 TABLES wood. Table 1 Groundwater Level and Flow Data - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Well ID MW-is (Well #1) TOC Elevation (feet MSL) 20.91 Well Depth (feet BGS) 13 Screened Interval (feet BGS) 3 - 13 Depth To Water (feet TOC) 8.11 Water Level Elevation (feet M S Q 12.80 MW-2S (Well #2) 21.44 1 13 3 - 13 10.75 10.69 MW-3S (Well #3) 23.02 18 8-18 11.90 11.12 MW-3A 21.93 20 5 -20 11.20 10.73 MW-4 18.42 13 3 - 13 6.80 11.62 MW-5 17.90 18 3 -18 6.00 11.90 MW-6 20.03 13 3 -13 9.42 10.61 MW-7 19.40 13 3 -13 8.75 10.65 MW-8 21.21 18 3 -18 9.50 11.71 MW-9A 20.58 20 5 -20 6.54 14.04 MW-10 16.61 20 5 -20 3.79 12.82 MW-11 14.49 20 5 -20 4.54 9.95 MW-12S 16.18 20 5 -20 4.72 11.46 MW-13 20.69 20 5 -20 8.48 12.21 MW-14S 16.60 20 15 -20 4.00 12.60 MW-15 19.67 20 15 -20 6.39 13.28 MW-16 NA 20 NA 7.51 NA MW-17 20.74 20 15 -20 8.30 12.44 MW-14D 17.45 40 35 - 40 6.15 11.30 MW-1D 21.14 50 40 - 50 8.64 12.50 MW-2D 21.80 49 39 - 49 12.55 9.25 MW-3D 22.83 50 40 - 50 12.65 10.18 Page 1 of 2 Table 1 Groundwater Level and Flow Data - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Water Level Reference Vertical Horizontal Elevation Elevation Change Change K I Well ID (feet MSQ (feet MSQ (feet) (feet) .. .. v .. MW-3A 10.73 11 0.27 20 0.805 0.08 0.014 0.1358 MW-10 12.82 13 0.18 115 0.116 0.05 0.002 0.0036 MW-11 9.95 10 0.05 25 0.009 0.04 0.002 0.0005 MW-12S 11.46 12 1 0.54 85 1 0.322 10.06 1 0.006 1 0.0341 Notes: Depth To Water was measured between June 13 and 19, 2019. TOC = top of casing. BGS = below ground surface MSL = mean sea level K - hydraulic conductivity. Values obtained from slug testing performed by EFM, Inc. n - effective porosity. Values approximated based on grain size data from Phase II Design Hydrogeologic Report. I - hydraulic gradient. Determined by dividing head change by horizontal distance to nearest contour line at each well location. v - flow rate; GW flow rate calculated based on the modified Darcy equation: v = (K*I)/n. Page 2 of 2 Table 2 Summary of Field Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina or Surface Water Location GWPS 'ield 6.5 - 8.5 Conductivity at NE Temperature NE TurbidityWell MIJKDissolved NE NE NE MW-1 S 6.5 532 19 3.96 102 970 MW-2S 6.5 1,311 20 2.50 40 870 MW-3S 6.8 3,782 21 6.40 -85 920 MW-3A 6.8 2,013 17 5.62 -12 990 MW-4 6.5 814 19 6.5 55 1,470 MW-5 6.6 2,266 21 7.8 46 2,420 MW-6 6.7 2,851 19 1.9 -70 1,800 MW-7 6.8 2,908 19 5.0 -112 1,450 MW-8 6.7 3,957 21 7.2 -105 1,560 MW-9A 6.7 556 23 7.67 122 670 MW-10 6.3 2,803 22 5.68 -158 3,410 MW-11 6.8 1,010 26 5.80 -52 620 MW-12S 6.6 4,190 26 6.28 -50 1,030 MW-13 6.2 516 24 8.44 15 1,220 MW-14S 6.6 310 22 24.5 54 MW-15 7.4 368 23 4.17 91 100 MW-16 6.6 1,851 23 7.73 46 MW-17 6.2 439 23 3.14 50 130 MW-14D 7.4 524 23 1.10 81 MW-1 D 7.2 403 18 5.88 80 3,760 MW-21D 8.0 456 19 3.04 61 640 MW-31D 7.9 567 18 2.33 91 1,260 SWPS 6-9 NE NE 50 NE NE SW-1 6.5 356 20 213 NS NS SW-2 6.9 314 21 6.2 NS NS SW-3 6.6 362 23 17 NS NS SW-4 6.6 143 24 24 NS NS NOTES: Groundwater samples were collected between June 13 - 19, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) Surface Water Standard = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters, EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Life, or North Carolina Protective Values for Surface Waters Bold font indicates concentration exceeds GWPS. NE = Not Established. S.U. = Standard Units. PS/cm = microsiemens per centimeter. NTU = Nephelometric Turbidity Units. Pagc 1 of 1 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte . . -J� it Parameter IL Acetone GWPS 6,000 qW ��hase (Well #1) (Well #2) (Well #3) MW-3A MW-4 9.06 U 9.06 U 9.0r- " 9.06 U 9.06 U 1 Monitoring Wle��� MW-5 MW-6 MW-7 9.06 U 9.06 U 9.06 U MW-8 9.06 U MW-113 9.06 U MW-213 9.06 U MW-313 9.06 U Benzene 1 0.24 U 0.24 U 0.89 J 1.00 0.30 J 0.24 U 0.24 U 0.31 J 1.17 0.24 U 0.24 U 0.24 U 1,4-Dichlorobenzene 6 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 1,1-Dichloroethane 6 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 0.2U 1,2-Dichloroethane 0.4 0.02 b 0.02 U 0.11 J 0.13 J 0.02 J 0.07 J 0.02 J 0.02 J 0.06 J 0.02 U 0.02 U 0.02 U Cis-1,2-Dichloroethene 70 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U VOCs 1,2-Dichloropropane 0.6 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U (Ng/L) Ethylbenzene 600 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Chloromethane 3 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 1.97 J Naphthalene 6 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 1.34 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Toluene 600 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 1.09 0.23 U 0.23 U Vinyl chloride 0.03 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U Tetrahydrofuran NE 0.62 J 3.94 26.60 8.44 2.44 6.80 14.40 27.00 28.10 43.30 0.51 J 0.52 J 1,4-Dioxane 3 2.71 U 11.90 176.00 66.90 2.71 U 74.20 40.10 17.00 94.70 2.71 U 2.71 U 2.71 U SVOCs Acenaphthene 80 2.66 U 2.66 U 8.1 J 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U (Ng/L) Fluorene 300 2.95 U 2.95 U 5.31 J 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U Pesticides Beta-BHC* 0.02 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U (Ng/L) Endrin Aldehyde 2 0.068 U 0.079 J 0.068 U 0.069 J 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U Page 1 of 3 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina rAnalyte . .Parameter I •� VOCs (pg/L) Acetone 6,000 T 9.06 U 9.06 U 9.06 U 12.60 J 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U 9.06 U Benzene 1 0.24 U 2.26 1.89 2.S2 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 0.24 U 1,4-Dichlorobenzene 6 0.39 U 0.39 U 0.39 U 0.57 J 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 1,1-Dichloroethane 6 0.2 U 0.40 J 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 0.2 U 1,2-Dichloroethane 0.4 0.02 U 0.40 0.18 J 0.19 J 0.02 U 0.02 U 0.02 U 0.04 J 0.02 U 0.02 U Cis-1,2-Dichloroethene 70 0.25 U 0.35 J 0.25 U 0.40 J 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dichloropropane 0.6 0.04 U 0.26 0.08 J 0.11 J 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U Ethylbenzene 600 0.21 U 0.36 J 0.21 U 0.22 J 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U 0.21 U Chloromethane 3 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U 0.77 U Naphthalene 6 0.47 U 1.14 J 0.47 U 0.94 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Toluene 600 0.23 U 0.23 U 0.23 U 0.46 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U Vinyl chloride 0.03 0.12 U 1.77 0.69 3.33 0.12 U 0.13 J 0.12 U 0.12 U 0.12 U 0.12 U Tetrahydrofuran NE 0.67 J 29.00 17.30 64.90 1.47 0.81 J 0.39 U 0.59 J 0.50 J 0.39 U 1,4-Dioxane 3 2.71 U 10.70 9.21 32.80 2.71 U 2.71 U 2.71 U 2.71 U 2.71 U 2.71 U SVOCs (pg/L) Acenaphthene 80 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U Fluorene 300 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U 2.95 U Pesticides (pg/L) Beta-BHC* 0.02 0.031 U 0.031 U 0.031 U 0.068 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U 0.031 U Endrin Aldehyde 2 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U 0.068 U Page 2 of 3 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina NOTES: Table 3 lists analytes detected in the groundwater samples. Please refer to Environment 1, Incorporated laboratory analysis report for further details. Groundwater samples were collected between June 13 - 19, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. ND = Not Detected. NE = Not Established. Bold font indicates concentration exceeds 2L Standard or IMAC. * indicates associates GWPS is an IMAC Page 3 of 3 Table 4 Summary of Surface Water Analytical Data - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Surface Sample LocajjjjjjNNjj&1ytiical Res Parameter Water Metals (Ng/L) Antimony 640 0.05 J 0.05 J 0.07 J 0.08 J Arsenic 10 1.5 J 0.95 J 1.9 J 1.1 J Barium 21,000 76.7 78.2 121 71.5 Beryllium 6.5 0.20 J 0.08 J 0.12 J 0.12 J Cadmium 2 0.05 J 0.02 J 0.03 J 0.02 U Cobalt 4 0.56 J 0.33 J 0.67 J 0.36 J Chromium 50 5.1 0.74 J 1.7 J 0.72 J Copper 7 2.2 J 0.62 J 0.96 J 1.1 J Lead 25 3.9 J 0.63 J 2.5 J 1.1 J Nickel 88 1.8 J 0.88 J 1.6 J 0.81 J Selenium 5 0.87 J 0.45 J 0.65 J 0.38 J Silver 0.06 0.05 U 0.05 U 0.05 U Thallium 0.47 0.05 U 0.05 U 0.05 U Vanadium NE 9.4 0.92 J 2.4 3.1 Zinc 50 13 5.0 J 8.2 J 4.8 J VOCs (Ng/L) Toluene 11 9.47 0.23 U 0.23 U 0.23 U Tetrahydrofuran NE 0.73 J 1.10 1.14 0.40 J NOTES: Table 4 lists detected compounds in the surface water. Please refer to Environment 1, Incorporated laboratory report for further details. Surface water samples were collected on June 13, 2019. Surface Water Standard = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters, EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Life, or North Carolina Protective Values for Surface Waters J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U = indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. NE = Not Established. Bold font indicates analyte detection above the Surface Water Standard. Page 1 of 1 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina June 2019 Analyte Group Antimony* 1 0.67 J 0.09 1 0.17 J 0.14 J 0.06 J Phase 1 Monitoring Wells 0.26 J 0.15 J 0.1 J 0.24 J 0.04 J 0.03 1 0.04 J Arsenic 10 0.68 J 5.3 20 11 1.5 J 7 11 9 19 1.5 J 0.06 J 0.27 J Barium 700 31.3 94.7 502 238 167 280 776 524 608 28.1 15.2 9.2 J Beryllium* 4 0.05 U 0.05 J 0.06 J 0.06 J 0.13 J 0.09 J 0.07 J 0.06 J 0.08 J 0.05 U 0.05 U 0.05 U Cadmium 2 0.07 J 0.06 J 0.02 U 0.02 U 0.07 J 0.14 J 0.13 J 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U Cobalt* 1 0.18 J 1.3 2.9 6 0.57 J 4 3.5 8 3.8 0.07 J 0.09 J 0.03 J Chromium 10 0.37 J 2 J 24 9.3 3.8 J 7.5 7.1 14 21 0.15 U 0.15 U 0.15 U Copper 1,000 3.1 J 0.56 J 2.2 J 1 J 0.39 J 1.1 J 0.98 J 2 J 2 J 1 J 0.61 J 0.73 J Iron 300 683 10,502 26,669 28,630 5,330 14,743 21,195 34,722 41,130 2,960 145 98 Metals Lead 15 0.6 J 0.04 J 0.03 U 0.03 U 0.05 J 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U (pg/L) Manganese 50 7.5 J 211 433 790 93 442 692 365 1,041 207 8.2 J 0.33 J Mercury 1 0.06 J 0.08 J 0.13 J 0.05 U 0.1 J 0.1 J 0.16 J 0.05 J 0.08 J 0.12 J 0.07 J 0.06 J Nickel 100 2.4J 3.91 5.6J 4.9J 1.91 7.9J 6.2J 4.9J 7.1 J 0.72J 1.1 J 0.55J Selenium 20 0.7J 1.7J 14 4J 1.1 J 3.8J 4J 5.6J 8.4J 0.29J 0.15 U 0.66J Silver 20 0.05 U 0.05 U 0.05 U 0.05 U 0.07 J 0.05 U 0.05 U 0.06 J 0.05 U 0.05 U 0.06 J 0.05 U Thallium 0.2 0.14 J 0.05 U 0.05 U 0.05 U 0.16 J 0.13 J 0.05 U 0.05 U 0.05 U 0.05 U 0.1 J 0.05 U Tin 2,000 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Vanadium 0.3 1.5 0.6 J 5.9 2.5 2.7 2.8 6.2 2.9 3.1 0.03 U 0.03 U 0.03 U Zinc 1,000 2.3J 2.3J 2.8J 3.1 J 3.5J 4.7J 2.2J 5.6J 2.9J 3.8J 4.7J 2.1 J Chloride 250,000 11,000 52,000 229,000 84,000 20,000 78,000 89,000 95,000 176,000 13,000 12,000 21,000 Inorganics Sulfide NE 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U and other Sulfate 250,000 110,000 346,000 98,400 105,000 49,900 241,000 5,300 8,600 186,000 13,300 34,000 8,600 Constituents Alkalinity (CaCO3) NE 165,000 280,000 1,610,000 810,000 342,000 912,000 1,500,000 1,360,000 1,620,000 171,000 182,000 236,000 Total Dissolved Residue (TDR) 500,000 408,000 882,000 2,000,000 1,090,000 448,000 1,450,000 1,630,000 1,470,000 2,160,000 213,000 264,000 309,000 Page 1 of 3 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina June 2019 Analyte Group Parameter Antimony* GWPS 1 MW-9A 0.03 U 0.21 J 0.03 J 2.9 Phase 2 Monitoring Wells 0.1 J 0.06 J 0.04 J 0.46 J 0.03 U 0.04 J Arsenic 10 0.42 U 9 5.5 54 2.3 J 2.2 J 1.6 J 5 1.1 J 0.18 J Barium 700 47.7 321 72.2 759 45.8 98.9 109 418 39 10.1 Beryllium* 4 0.05 U 0.12 J 0.22 J 0.08 J 0.06 J 0.07 J 0.11 J 0.16 J 0.05 U 0.05 U Cadmium 2 0.02 U 0.11 J 0.12 J 0.02 U 0.05 J 0.05 J 0.07 J 0.13 J 0.04 J 0.05 J Cobalt* 1 0.11 J 1.9 0.9 J 3.2 0.75 J 0.69 J 0.26 J 0.94 J 0.2 J 0.05 J Chromium 10 0.15 U 19 0.77 J 55 0.3 J 2 J 0.46 J 2.9 J 0.18 J 0.15 U Copper 1,000 0.84 J 0.8 J 0.31 J 2.5 J 0.56 J 0.92 J 0.4 J 1.4 J 0.17 J 0.94 J Iron 300 2,527 151 19,952 2,164 5,680 8,173 6,850 28,823 2,619 4.96 U Metals Lead 15 0.03 U 0.03 U 0.03 U 0.03 U 0.11 J 0.72 J 0.03 U 0.71 J 0.03 U 0.03 U (Ng/L) Manganese 50 113 158 244 511 59 527 97 173 149 0.7 J Mercury 1 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Nickel 100 1.7J 9.3J 3.8J 9.1 J 2.2J 4J 1.3J 7J 1.4J 1.81 Selenium 20 0.35 J 4.1 J 1.2 J 1 J 0.73 J 1.1 J 0.51 J 4.3 J 0.68 J 0.35 J Silver 20 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Thallium 0.2 0.05 U 0.18 J 0.05 U 0.07 J 0.12 J 0.05 J 0.05 U 0.09 J 0.06 J 0.05 U Tin 2,000 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Vanadium 0.3 0.54 J 9.5 3.2 40 1.5 4.2 5.7 11.9 2.9 0.03 U Zinc 1,000 4.2J 2.7J 6J 4.4J 4.7J 6.2J 5.1 J 5J 3J 9.7J Chloride 250,000 11,000 77,000 36,000 260,000 14,000 20,000 10,000 75,000 9,000 14,000 Inorganics Sulfide NE 100 U 849 J 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U and other Sulfate 250,000 105,000 171,000 204,000 111,000 7,100 13,100 103,000 612,000 174,000 6,000 Constituents Alkalinity (CaCO3) NE 196,000 1,340,000 528,000 1,730,000 232,000 520,000 49,000 240,000 71,000 248,000 Total Dissolved Residue (TDR) 500,000 366,000 1 1,780,000 1 902,000 1 2,150,000 409,000 603,000 233,000 1,310,000 413,000 296,000 Page 2 of 3 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina June 2019 NOTES: Table 5 lists analytes detected in the groundwater samples. Please refer to Environment 1, Incorporated laboratory analysis report for further details. Groundwater samples were collected between June 13 - 19, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. ND = Not Detected. NE = Not Established. Bold font indicates concentration exceeds 2L Standard or IMAC. * indicates associates GWPS is an IMAC Page 3 of 3 Table 6 Summary of Natural Attenuation Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte Group Parameter Carbon Dioxide GWPS NE (Well #1) 68,000 (Well #2) 121,000 (Well #3) 3,000,000 240,000 Phase I Monitoring Wells 130,000 299,000 304,000 342,000 389,000 13,000 6,000 6,000 Dissolved Ethane NE 0.006 Udn 0.018 n 0.069 n 0.24 n 0.038 n 0.15 n 0.039 Jn 0.043 Jn 0.23 n 0.53 n 0.0046 Jn 0.0061 Jn Gasses (Ng/L; Ethene NE 0.010 Udn 0.005 Un 0.005 Un 0.012 n 0.0097 Jn 0.005 Un 0.065 Jn 0.049 Jn 0.068 Jn 0.005 Un 0.005 Un 0.005 Un unless noted) Methane NE 27 do 430 n 440 n 1,100 n 1,900 n 960 n 2,400 n 1,800 n 3,000 n 4,300 n 12 n 9.7 n Hydrogen (nM) NE 1.5 Udn 1.1 n 1.2 n 1 n 0.86 Jn 0.98 Jn NS NS 5.5 n 1 n 0.91 Jn Acetic Acid 5,000* 33 J 55 J 28 U 280 U 58 J 280 U 280 U 290 J 280 U 230 42 J 47 J Butyric Acid NE 11 U 98 J 11 U 370 J 24 J 230 J 380 J 330 J 980 J 11 U 11 U 11 U Hexanoic Acid NE 10 U 10 U 1101 160 J 10 U 160 J 210 J 100 U 1101 10 U 10 U 10 U i-Hexanoic Acid NE 29 U 29 U 29 U 290 U 29 U 290 U 290 U 290 U 290 U 29 U 29 U 29 U Fatty Acids iNgAc i-Pentanoic Acid NE 6 U 6 U 6 U 60 U 6 U 60 U 60 U 60 U 60 U 6 U 6 U 6 U Lactic Acid NE 43 U 43 U 43 U 430 U 43 U 430 U 430 U 430 U 430 U 43 U 43 U 43 U Pentanoic Acid NE 7 U 7 U 36 J 70 U 7 U 70 U 70 U 70 U 79 J 7 U 7 U 7 U Propionic Acid NE 4U 4U 4U 40U 4U 40U 40U 40U 40U 25J 4U 4U Pyruvic Acid NE 5 U 5 U 48 J 50 U 5 U 50 U 50 U 50 U 64 J 5 U 5 U 5 U Nitrate (as N) 10,000 170 100 9 U 9 U D U 9 U 190 2,710 170 9 U 110 350 Biological Oxygen Demand (BOD) NE 2000 U 2000 U 7,500 2000 U 2000 U 3,100 4,100 7,600 13,000 2,000 2000 U 2000 U Other Natural Attenuation Chemical Oxygen Demand (COD) NE 36,000 67,000 423,000 198,000 67,000 148,000 294,000 291,000 432,000 28,000 840 U 840 U Parameters Alkalinity (CaCO3) NE 165,000 280,000 1,610,000 810,000 342,000 912,000 1,500,000 1,360,000 1,620,000 171,000 182,000 236,000 Iron (Ferrous) NE 371 8,136 24,655 27,430 3,957 7,394 20,872 27,011 39,673 2,258 50 U 50 U Total Organic Carbon (TOC) NE 13,000 26,080 164,600 75,200 27,480 50,360 108,500 104,800 275,800 7,140 2,240 2,420 Total Hardness NE 1 316 548 1 856 596 268 896 1,020 720 1 1,032 140 164 92 Page 1 of 3 Table 6 Summary of Natural Attenuation Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina re Group Parameter Carbon Dioxide GWPS NE •A 48,000 408,000 246,000 Phase 11 Monitoring Wells 151,000 462,000 306,000 66,000 332,000 80,000 14,000 Dissolved Ethane NE 0.076 n 0.04 n 0.0078 Jn 0.17 n 0.0066 Jn 0.039 n 0.0079 Jn 0.01 n 0.022 n 0.009 Jn Gasses (Ng/L; Ethene NE 0.005 Un 0.19 n 0.058 n 0.5 n 0.027 n 0.1 n 0.005 Un 0.022 n 0.005 Un 0.0064 Jn unless noted) Methane NE 92 n 3,900 n 130 n 4,600 n 190 n 3,000 n 200 n 660 n 160 n 12 n Hydrogen (nM) NE 0.82 Jn 1.1 n 1.2 n NS 1.5 n 0.84 Jn 0.98 Jn 1.2 n 1.1 n 0.9 Jn Acetic Acid 5,000' 31 J 28 U 63 J 730 J 52 J 44 J 40 J 74 J 46 J 45 J Butyric Acid NE 11 U 240 55 J 1,100 11 U 11 U 11 U 70 J 11 U 11 U Hexanoic Acid NE 10 U 10 U 76 J 100 U 14 J 10 U 10 U 10 U 10 U 10 U i-Hexanoic Acid NE 29 U 29 U 29 U 290 U 29 U 29 U 29 U 29 U 29 U 29 U Fatty Acids (NgAc) i-Pentanoic Acid NE 6 U 6 U 6 U 60 U 6 U 6 U 6 U 6 U 6 U 6 U Lactic Acid NE 43 U 43 U 43 L 430 U 70 J 43 U 43 U 43 U 43 U 43 U Pentanoic Acid NE 7 U 7 U 9.9 J 180 J 7 U 7 U 7 U 7 U 7 U 7 U Propionic Acid NE 4 U 4 U 40 U 4 U 4 U 4 U 4.2 J 4 U 4 U Pyruvic Acid NE 5 U 5 U 17 J 50 U 14 J 15 J 5 U 5.8 J 5 U 5 U Nitrate (as N) 10,000 9 U 9 U 9 U U 460 9 U 9 U 9 U 9 U 240 Biological Oxygen Demand (BOD) NE 2000 U 11,000 2000 U 8,500 2000 U 3,100 2000 U 4,000 2000 U 2000 U Other Natural Attenuation Chemical Oxygen Demand (COD) NE 22,000 276,000 67,000 620,000 55,000 96,000 39,000 141,000 43,000 840 U Parameters Alkalinity (CaCO3) NE 196,000 1,340,000 528,000 1,730,000 232,000 520,000 49,000 240,000 71,000 248,000 Iron (Ferrous) NE 2,394 50 U 19,045 1,887 5,026 5,629 5,962 25,400 2,511 Total Organic Carbon (TOC) NE 4,960 106,300 26,760 220,000 22,320 29,760 15,260 76,400 18,320 2,680 Total Hardness NE 267 1,120 659 749 263 353 114 713 302 161 Page 2 of 3 Table 6 Summary of Natural Attenuation Parameters - June 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina NOTES: Table 3 lists analytes detected in the groundwater samples. Please refer to Environment 1, Incorporated laboratory analysis report for further details. Groundwater samples were collected between June 13 - 19, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. ND = Not Detected. NE = Not Established. Bold font indicates concentration exceeds 2L Standard or IMAC. * indicates associates GWPS is an IMAC nM = nanomoles INS = Not sampled n = The Laboratory does not hold NELAP/TNI accreditation for this method or analyte. d = The analyte concentration was determined from a dilution. Page 3 of 3 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 FIGURES wood. _ ` r Fr � — �- � ■ u air.• l — ! a _ • s # { ' a #a !S'�8 _ F •Pa�taiuS I r ' -'� � fiam,� , r - �* f � f ,4.`��,t F fig a 4 z f hw y26 IL;Car+ k 1i c r 1 e * t _ .1J +•1{��} " w:ate- �1 1YYY� 14L'-14 _ _ Phase 2 N-1 _ Phase.1 -} a a,, ITIP f i h i _—— — — _ _' — - - - }� .*#ems_ I �.• — - .� ir + ♦ C'8 �� - fdF 0 2,000 - 4,000 Legend .* _ - �I : Feet Site r Copyright:.© 2013 National Geographic Society, i-cubed SITE: TITLE: Figure C8YD Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 SITE LOCATION MAP CLIENT: W 0 0 w C8YD LANDFILL INC. SCALE: 1 "=2,00 bATE: 05/01/2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: S. Knox Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142—P R\Figures C DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures _b INK ' ' At. A �6e' 4P t el S MW-14D MW-13x MW-14S Phase 2 1 MW-12S •� MW-8 'r . if - - 1 MW-1 D MW-1 �P � MW-2S - MW-6 Legend SW-2 MOSu rface Water Sampling Location • Shallow Monitoring Well ;y rJL Deep Monitoring Well y Approximate Stream Location , r ' ` Feet Site Boundary Source Esri, Digi I'�I oEye, Earthstar Geographics, CNES/Airbus D DA, G AeroGR ID, IGN, ndthe G6tSMser Community SITE: Figure TITLE: FI C&D Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 MONITORING WELL AND SURFACE WATER SAMPLING LOCATION MAP CLIENT: ^ W 0 do C&D LANDFILL INC. SCALE: 1 " = 200 ' DATE: 05/01 /2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: S. Knox Durham, NC 27703 (919) 381-9900 LOCATION: PAGovernment\State\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures �DA Not Available - well not surveyed 'j, at, no t used for contouring (deep well) t i jK co MW-16 � a MW-15 13.28'' ow MW-14S t . Fi .'� ✓ 12.60' MW-10 . F MW-14D* 12.82' -. r.. 11.30' G MW-11' .12.21'- ' Phase 2 c MW-12S 11 " MW-11 F MW 50 MW-1 S 12.80' ON 11.12 r 1 r 4 J* { v - ,., 4-r 1 .1 Phase 1 ft r s ; MW-3A+ !4y y• 10:73' Y .ix r r� MW-4 MW-5 11!90' MW-7 10.69' r.. Legend MW-6 • Shallow Monitoring Well 10:61' Deep Monitoring Well ' Groundwater Elevation Contour 2 � 0 200 400 - - - Approximate Stream Location Jk ti .+ Feet Site Boundary ource: Esri, 1 r��'�� �' E ,Earth tarGeographics,. N /Ai DA, Vaft, • '_ s• :f'!^' AeroGRID, IGN,, d th �i= r • mmunit Notes: Metals and inorganic constituent concentrations in excess of standards are not illustrated. Units are micrograms per liter (Ng/L). BRL = Contaminant concentrations were below reporting limits. NE = No exceedances of applicable groundwater or surface water standards were reported. NS = Not Sampled J = Estimated value below the laboratory reporting limit ►� MW-17 NE SW-4 NE et \ I A 6 MW-14D BRL MW-13 NE MW-12S i* Benzene 2.52 Vinyl Chloride 3.33 1,4-Dioxane 32.8 Beta-BHC 0.068 ' 01 !" •� _ MW-15 S7 NE Mt -14S Vinyl Chloride 0.13 J MW-10 Benzene 2.26 Vinyl Chloride 1.77 1,4-Dioxane 10.7 Phase 2 MW-11 Benzene 1.89 Vinyl Chloride 0.69 1,4-Dioxane 9.21 e_n r "�49 MW-3D NE MW-3S 1,4-Dioxane 176 MW-3A LA 1,4-Dioxane 66.9 `` +� , 4 r'. MW-8 Benzene 1.17 ' 1,4-Dioxane 94.7 Phase 1 N ;F g { A", is— •+r �i K i� F' t� F� i' MW �. MW-4 1 NE SW-1 MW-7 NE 1,4-Dioxane 17 MW-6 s 1• 1,4-Dioxane 40.1 MW-2S J. 1,4-Dioxane 11.9 a Legend ® Surface Water Sampling Location r • Shallow Monitoring Well Deep Monitoring Well SW-2 NE 0 200 400 - Approximate Stream Location`' #' 1 Feet Site Boundary Source: Esri, DigitalGl ' = oEye, Earthstar Geographics, CNES/Airbus DS, SDA, G AeroGRID, IGN, and th -T ser Community SITE: Figure TITLE: FI C&D Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 GROUNDWATER AND SURFACE WATER STANDARD EXCEEDANCE MAP - JUNE 2019 CLIENT: w wood*C&D LANDFILL INC. SCALE: 1 " = 20EHa 4/24/2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: CHECKED BY: D.Hriciga Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142Prt RTig\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures MW-5 1,4-Dioxane 74.2 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Appendix A Laboratory Analytical Reports wood. Drinking Water ID; 37715 waehemwhur Tn, 1n 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/13/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 08/08/19 DURHAM ,NC 27703 REVIEWED BY: 14 MW-4 MW-5 MW-6 MW-7 MW-8 Analysis Method PARAMETERS MDL MRL Date Analyst Code PH (field measuremenO , Units 6.5 6.6 6.7 6.8 6.7 06/13/19 BF 4500HP-11 BOD, mg/l 2,0 2.0 --- U 7.6 06/14/19 JTH 521OR-11 BOD, mg/l 2.0 2.0 3.1 4.1 13 06/13/19 TCW 5210E-11 COD, mg/l 0.840 20.0 67 148 294 291 432 06/1B/19 SEJ HB000-79 Nitrate Nitrogen as N, mg/1 0.009 0.04 --- U --- U 0.19 2.71 0.17 o6/14/19 DTL 353.2 R2-9 Total Organic Carbon, mg/l 0.129 1,0 27.48 50.36 108,5 104.8 275.8 06/13/19 SRJ 531OC-11 Alkalinity (to pH 4,5), mg CaCO3/1 1.0 1.0 342 912 1500 1360 1620 06/17/19 TCW 2320E-11 Chloride, mg/l 5.0 5.0 20 78 89 95 176 06/17/19 KDE 45000LB-11 Cyanide, uq/1 5.0 5,0 --- U --- U --- U --- U --- U 06/14/19 SECT 4500CNE-11 Total Hardness, mg/1 268 096 1020 72D 1032 06/17/19 JTH 2340C-11 Total Dissolved Residue, mg/l 1.0 10 448 1450 1630 1470 2160 06/18/19 RDS 2540C-11 Sulfate, mg/l 5.0 5,0 49.9 241 5.3 8.6 186 06/17/19 SEJ 4500SO4221 Antimony, ug/l 0.03 1.0 0.06 J 0.26 J 0.15 J 0.10 J 0,24 J 06/21/19 LFJ EPA200,6 Arsenic, ug/l 0.03 5.0 1,5 J 7.0 IS 9 19 06/21/19 LFJ EPA200.8 Barium, ug/1 0.03 1010 167 280 776 524 608 06/21/19 LFJ EPA200.8 Beryllium, ug/l 0.05 1.0 0,13 J 0.09 J 0.07,T 0.06 J 0.08 J 06/21/19 LFJ EPA200.8 Cadmium, ug/l 0.02 110 0.07 J 0.14 J 0.13 J --- U --- U 06/21/19 LFJ EPA200.8 Cobalt, ug/1 0,03 1.0 0.57 J 4.0 3.5 8,0 3.8 06/22/19 LFJ EPA200,B Total Chromium, ug/1 0.15 5.0 3.8J 7.5 7.1 14 21 06/21/19 LFJ EPA200.8 Copper, ug/1 0.03 10.0 0.39 J 1.1 J 0.98 J 2.0 J 2,0 J 06/21/19 LFJ EPA200,8 Iron, ug/1 4.96 50.0 5330 14743 21195 34722 41130 07/01/29 LFJ EPA200.7 Manganese, ug/1 0.31 10.0 93 442 692 365 1041 07/01/19 LFJ EPA200,7 Lead, ug/1 0.03 5.0 0.05 J --- U --- U --- U --- U 06/21/19 LFJ HPA200.8 Mercury, ug/1 0.05 0.20 0.1017 0.10 J 0.26 J 0.05J 0,08 J 06/24/19 MTM 245.1 R3-9 Nickel, u9/1 0,03 10.0 1.9 J 7.9 J 6.2 J 4.9 J 7.1 J 06/21/19 LFJ EPA200.8 selenium, ug/1 0.15 10.0 1.1 J 3.0 J 4.0 J 5.6 J B.4 J 06/21/19 LFJ EPA200.6 Silver, ug/l 0,05 5.0 0.07 J --- U --- U 0,06 J --- U 06/24/19 LFJ EPA200.8 Thallium, ug/l 0.05 1.0 0.16 J 0.13 J --- U --- U --- U 06/21/19 LFJ EPA200.8 Tin, ug/l 0.05 100,0 --- V --- U --- U --- U --- U 07/29/19 LFJ EPA200.8 Vanadium, ug/l 0.03 110 2.7 2.8 6.2 2.9 3.1 06/21/19 LFJ EPA200.8 Zinc, ug/1 0.11 10.0 3.5 J 4.7 J 2.2 J 5.6 J 2.9 J 06/21/19 LFJ EPA200.8 Sulfide, ug/l 100 1000 --- U --- U --- U --- U --- U 06/19/19 LFJ 45GOS21)-11 Conductivity (at 25c), uMhos/cm 1.0 1.0 814 2266 2B51 2908 3957 06/13/19 BF 2510E-11 Dissolved oxygen, mg/1 0.1 0.1 1.47 2.42 1.80 1.45 1.56 06/13/19 EF 45000G-11 Temperature, °C 19 21 19 19 21 06/13/19 BF 255OH-10 Static Water Level, feet 6.80 6.00 9.42 8.75 9.50 06/13/19 BF Well Depth, feet 15,98 9.50 16.65 16.33 20.26 06/13/19 BF Carbon Dioxide, mg/1 1.0 1.0 130 299 304 342 389 06/13/19 RDS 45000O2C-1 ORP, my +55 +46 -70 -112 -105 06/13/19 BF 2580E Turbidity (Fieldl, NTU 110 1.D 6.5 7,8 1.9 5.0 7,2 06/13/19 BF 21308-11 J = Estimated value between the MDL and MRL, U - Below ALL Ouantitation Limits. EflW'woflH(W Ala hcupumUd Drinking Water ID= 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC POSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 DURHAM, NC 27703 DATE EXTRACTED: 06/17/19 DATE ANALYZED: 07/10/19 REVIEWED BY: ✓,r/ DATE REPORTED: 08/08/19 PESTICIDES AND PCH'S EPA METHOD 8081B R2(07) MW-4 MW-5 MW-6 MW-7 MW-0 PARAMETERS, ug/l MDL MRL 1. Aldrin 0.029 0.050 --- U --- U --- U --- U `-- U 2. Alpha-BHC 0.032 0.050 --- U --- U --- U --- U --- U 3. Beta-BHC 0,031 D.050 --- U --- U --- U --- U --- U 4. Delta-BHC 0.030 0.050 --- U --- U --- U --- U --- U 5. Gamma-BHC (Lindane) 0.032 0.050 --- U --- U -'- U --- U --- U 6. Chlordane 0.320 0.500 --- U --- U --- U --- U --- U 7. 4,4-Ann 0.051 0.100 --- U --- U --- U --- U --- U B. 4,4-DDE 0.049 0.100 --- U --- U --- U --- U --- U 9. 4,4-DDT 0.052 0.100 --- U --- U --- U --- U --- U 10. Dieldrin 0.042 D.075 --- U --- U --- U --- U --- U 11. Endoeulfan 1 0.056 0.100 --- U --- U --- U --- U --- U 12. Endoeulfan 11 0.046 0.100 --- U --- U --- U --- U --- U 13, Endoeulfan Sulfate 0.072 0.100 --- U --- U U --- U --- U 14. Endrin 0.053 0.100 --- U --- U '-- U --- U --- U 15. Endrin Aldehyde 0.068 0.100 --- U --- U --- U --- U --- U 16. Heptachlor 0.039 0.050 --- U --- U --- U --- U --- U 17. Heptachlor Epoxide 0.042 0.075 --- U --- U --- U --- U --- U 1B. Methoxychlor 0.530 1.000 --- U --- U --- U --- U --- U 19. Pcb'a (AroclDre) 0.500 2.000 --- U --- U --- U --- U --- U 20. Toxaphene 0.690 1.500 --- U --- U --- U --- U --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. REAT02EM I hmpudid Drinking Water IDS 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 DURHAM, NC 27703 DATE EXTRACTED: 06/18/19 DATE ANALYZED: 06/29/19 REVIEWED BY: DATE REPORTED: 08/08/19 LANDFILL APPENDIX 11 EPA METHOD 8151A R1(96) KW-4 MW-5 MW-6 MW-7 14W-8 PARAMRT3RS, ug/l MDL MRL 1, 2,4-D 0.36 2.000 --- U --- U --- U --- U --- U 2. Dinoaeb 0.54 1.000 --- U --- U --- U --- U --- U 3. 2,4,5-TP 0.42 2.000 --- U --- U --- U --- U --- U 4. 2,4,5-T 0.47 2.000 --- U _-- U --- V --- U -"- U j = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits, Enw,ormEW 1, hmpumbd Drinking Water ID[ 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.G. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST; KPG 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 06/13/19 Page: 1 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) MW-4 MW-5 MW-6 MW-7 MW-8 PARAMETERS, u9/1 MDL MRL 1. Acenaphthene 2.66 10,000 --- U --- U --' U --- U --- U 2, Acenaphthylene 2.60 10.000 --- U --- U --- U --- U --- U 3, Anthracene 2.97 10.000 --- U --- U --- U --- U --- U 4, Benzo[a]antrhacene 4.16 10.000 --- U --- U --- U --- U --- U 5. Benzo[b3fluoranthene 3.32 10.000 --- U --- U --- U -"- U --- U 6, Benzo[k]fluoranthene 4.23 10.000 --- U --- U --- V --- U -•- U 7. Benzo{g,h,i]perylene 2.61 10.000 --- U --- U --- U "-- U --- U 8. Benzo[a]pyrene 3.27 10.000 --- U --- U --- U --- U --- U 9. 4-Bromophenyl Phenyl Ether 2.63 10.000 --- U --- U --- U --- U --- V 10. Butyl Benzyl Phthalate 5.78 10.000 --- U --- U --- U --- U --- U 11. Bie(2-Chloroethoxy) Methane 3.14 10.OD0 --- U --- U --- U --- U --- U 12. Bis(2-Chloroethyl) Ether 2.58 10,000 --- U --- U --- U --- U --- U 13. Bia(2-Chloro-l-methylethyl) Ether 2,58 10.000 --- U --- U --- U --- U --- U 14, 2-Chloronaphthalene 2.17 10.000 --- U --- U --- U --- U --- U 15. 4-Chlorophenyl Phenyl Ether 2.42 10.000 --- U --- V --- U --- U --- U 16. Chrysene 4.04 10.000 --- U --- U --- U --- U --- U 17. Dibenza[a,h]anthracene 2.78 10.000 _-- U --- U --- U --- U --- U 18. Di-N-Butyl Phthalate 3.09 10.000 --- U --- U --- U --- U --- U 19, Dimethyl Phthalate 3.70 10,000 --- U U --- V --- V --- U 20, Diethyl Phthalate 3.92 10,OD0 --- U --- U --- U --- U --- U 21. 2,4-Dinitratoluene 3.95 10.000 --- U --- V --- U --- U •-- U 22, 2,6-Dinitratolusne 3.88 10.00D --- U --- U --- U --- U --- U 23, Di-N-Octyl Phthalate 2.61 10.000 --- U --- U --- U --- U -•- U 24. Bis-(2-Ethylhexyl) Phthalate 9.97 15.000 --- U --- U --- U --- U --- U 25. Fluoranthene 3.92 10.000 --- U --- U --- U --- U --- U 26, Fluorene 2.95 10,000 --- U --- U U --- U --- U 27. Hexachlarobenzene 2.61 10.000 --- U --- U --- U --- U --- U 20. Hexachlorocyclopentadiene 4.16 10.000 --- U --- U --- U --- U --- U 29, Indeno[1,2,3-Cd3pyrene 2.91 10,000 --- U --- U --- U --- U --- U 30. Isopharone 3.74 10.000 --- U --- U --- U --- U --- V 31, Nitrobenzene 2.85 10.000 --- U --- U --- U --- V --" U 32, N-Nitrosodimethylamine 4.25 10.000 --- U --- U --- U --- U --- U 33. N-Nitroaodiphenylamine 3.95 10.000 --- U --- U --- U --- U --` U 34. N-Nitroaodi-N-Propylamine 4,06 10.000 --- U --- U --- U --' Ti --` U 35. Phenanthrena 3.24 10.000 --- U --- U --- U --- U --- U 36. Pyrene 3,63 10.000 --- U --- U --- U --- U --- U 37. 4-Chloro-3-Methylphenol 3.79 20.000 --- U --- U --- U --- U --- U 38, 2-Chlorophenol 2.75 10.000 --- U --- U --- U --- U --- U 39. O-Cresol 3.68 10.000 --- U --- U --- U --- U --- V 40, P-Cresol 4.12 10.000 U --- U --- U --- U --- U 41. 2,9-Dichlorophenol 5.19 10.000 --- U --- V --- U --- U --- U 42. 2,6-Dichlorophenol 4.89 10,000 --- U --- U --- U --- U --- U 43. 2,4-Dimethylphenol 3.21 10.000 --- U --- U --- U --- U "-" U 44. 4,6-Dinitro-2-Methylphanol 4.77 50.00D --- U --- U --- U --- u --- U 45. 2,4-Dinitrophenal 4,37 50.000 --- U --- U --- U --- U --- U 46. Ethyl Methaneeulfonate 5.26 20.000 --- U --- U --- U --- U --- U 47, Methyl Methaneeulfonate 4.92 10.000 --- U --- U --- U --- U --- U 48. 2-Nitrophenol 3.69 10.000 --- U --- U --- U --- U --- U a - Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EEAMEM101 % INOWPHENd Drinking Water ID: 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 06/13/19 Page: 2 DURHAM, NC 27703 DATE EXTRACTED; 06/14/19 DATE ANALYZED; 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) MW-4 MW-5 MW-6 KW-7 Mw-B PARAMETERS, ug/1 MDL MILL 49. 4-Nitrophenol 3.17 50.000 --- U --- U --- U --" U - " U 50. Pentachlorophanol 5.33 25.000 --- U --- U --- U --- U --- U 51. phenol 1,86 10.000 --- U --- U --- U --- U »-- U 52. 2,3,4,6-Tetrachlarophenol 3.12 10.000 --- U --- U --- U --- U --- U 53. 2,4,5-Trichlorophenol 4.17 10.000 --- U --- U --- V --- U --- U 54. 2,4,6-Trichlorophenol 3.84 10.000 --- U --- U --- U --- U --- U 55. Acetophenone 2.89 10,000 --- U --- U --- U --- U --- U 56. 2-Acetylamino8luorene 3,98 20.000 --- U --- U --- U --- U --- U 57. 4-Aminobiphanyl 4,12 20.000 --- U --- U --- U --- U --- U 59. Banzyl Alcohol 4,47 20.000 --- U --- U --- U --- U --- U 59. 4-Chloroaniline 3.36 20.000 --- U --- U --- U --- U --- U 60, Chlorobenzilate 5.12 10.000 --- U --- U --" U --- U --- U 61. Diallate 2.98 10.000 --- U --- U --- U --- U --- U 62, Dibenzofuran 4,28 10.000 --- U --- U --' U --- U --- U 63. 3,3-1)ichlorobenzidine 4.22 20.000 --- U --- U --- U --- U --- U 64. Dimethoate 3.98 20.000 --- U --- U --- U --- U --- U 65. P-nimethylaminoazobenzene 2,89 10.000 »-- U --- U --- U --- U --- U 66. 7,12-Dimethylbenz[a]anthracene 5.26 10.000 --- U --- U --- U --- U --- U 67, 3,3-Dimethyibenzadine 3.21 10.000 --- u --- u --- U --- v --- U 6B, 1,3-Dinitrobenzene 2.89 20,000 --- U --- U --- U --- U --- U 69. Diphenylamine 5.10 10.000 --- U --- U --- U --- U --- U 70. Disulfoton 4.28 10.000 --- U --- U --- U --- U --" U 71. Pamphur 3.98 20.000 --- U --- U --- U --- U --- U 72. Nexachloropropene 4.31 10.000 --- U --- U --- U --- U --- U 73. isosafrole 2.08 10.000 --- U --- U --- U --- U --- U 74, Kepone 2.78 20,000 --- U --- U --- V - " U -'- U 75. Methapyrilene 3,54 100,000 --- U --- U --- V --- U --- U 76. 3-Methylchloroanthrene 4.21 10.000 --- U --- U --- U --- U --- U 77. 2-Methylnaphthalene 3,79 10.000 --- U --- U --- U --- U --- U 78, Methyl Parathion 4.32 10.000 --- U --- U --- U --- U --- U 79. m-Crapol 3.81 10.000 --- U --- U --- U --- U --- U 80. 1,4-Naphthoquinone 4.00 10.000 --- U --- U --- U --- U --- U 81. 1-Naphthylamine 5.61 10,900 --- U --- U --- U --- U --- U B2. 2-Naphthylamine 4.62 10,000 --- U --- U --- U --- U --- U 03. 2-Nitroaniline 3.61 50,000 --- U --- U --- U --- U --- U 04. 3-Nitroaniline 4.81 50.000 --- U --- U --- U --- U --- U 95, 4-Nitroaniline 4.22 20,000 --- U --- U --- U --- U U 86. 5-Nitro-O-Toluidine 4.01 10,000 --- U --- U --- U --- U U 87. N-Nitroeodi-n-butylamine 3,63 10.000 --- U --- U --- U --- U --- U 88. N-Nitroeodiethylamine 3.83 20.000 --- U --- U --- U --• U --- U 89. N-Nitrosomethylethylamine 3.83 10.000 --- U --- U --- U --- U -"• U 90. N-Nitrosopiperidine 5.19 20.000 --- U --- U --- U --- U --- U 91. N-Nitrosopyrrolidine 2.09 10.000 --- U --- U --- U --- U --- U 92, Parathion 3.12 10.000 --- U --- U --- U --- U --- U 93. Pentachlorobenzene 3.92 10.000 --- U --- U --- U --- U --- U 94. 8entachloranitrobenzene 3.71 20.000 --- U --- U --- U --- U --- U 95. Phenacetin 4.41 20.000 U --- U --- U --- U --- U 96. 1,4 Benzenediamine 2.99 101000 --- V --- U --- U --- U --- U a = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. Em,nmHol % bmpmmNd Drinking Water ID: 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYSE': KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 3 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) MW-4 MW-5 MW-6 MW-7 MW-8 PARAMETERS, ug/l MDL MRL 97. Fhorate 3.86 10.000 --- U --- U --- U --- U --- U 90. Pronamide 3.69 10.000 --- U --- U --- U --- U U 99. Safrole 4.12 10.000 --- U --- U --- U --- U --- U 100. 1,2,4,5-Tetraohlorobenzene 5.01 10.000 --- U --- U --- U --- U --- V 101, Thionazin 4.621 20.000 --- U --- U --- U --- U --- U 102. 0-Toluidine 4.11 10.000 --- U --- U --- U --- U --- U 103. 1,3,5-Trinitrobenzene 3.98 10.000 --- U --- U --- U --- U --- U 104, 0,0,0-Triethyl Phoaphorothioate 3.61 10,000 --- U --- U U U U 105. Hexaahloroethane 1.49 10.000 --- U --- U --- U --- U - U 106, laodrin 3.11 20.000 --- U --- U --- U --- U --- U S = Batimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EflAunfluma % hrmpumbd Drinking water SDa 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C, 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 1 DURHAM, NC 7703 DATE ANALYZED: 06/24/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX 11 EPA METHOD 8260D R4(18) KW-4 MW-5 MW-6 Mw-7 MW-8 PARAMETERS, Ug/1 MDL MR:, 1. Chloromethane 0.77 3.000 --- U --- U --- U --- U --- U 2, Vinyl Chloride 0.12 0.200 --- U --- U --- U --- U --- U 3. Bromomethane 0.67 10,000 --- U --- U --- U --- U --- U 4. Chloroethane 0.48 10,00o U --- U --- U -`- U --- U 5. Trichlorofluoromethana 0.24 1.000 --- U --- U --- U --- U --- U 6, 1,1-Dichloroethene 0.17 5,000 --- U --- U --- U --- U - " U 7. Acetone 9.06 100,000 --- U --- U --- U --- U --- U 8, Iodomethane 0.26 10.000 --- U --- V --- U --- U '"' U 9. Carbon Disulfide 0.23 100.000 --- U --- U --- U --- U --- U 10. Methylene Chloride 0.64 1,000 --- V --- U --- U --- U --- V 11. tram -1,2-Dichloroethene 0.23 5.000 --- U --- U --- U --- U --- U 12. 1,1-Dichloroethene 0.20 5.000 --- U --- U --- U --- U --- U 13. Vinyl Acetate 0.20 50.000 --- U --- U --- U --- U --- U 14. Cie-1,2-Dichloroethene 0.25 5.000 --- U --- U --- U --- U --- U 15. 2-Butanone 2.21 100.000 --- U --- U --- U --- U --- U 16. Bromochloromethane 0.27 3,000 --- U --- U --- U --- U --- U 17. Chloroform 0.25 5.000 --- U --- U --- U -"- U --- U 18. 1,1,1-Trichloroethane 0.19 1.000 --- U --- U --- U --- U --- U 19, Carbon Tetrachloride 0.04 0.200 --- U --- U --- U --- U --- U 20, Benzene 0.24 I.000 0.30 J --- U --- U 0.31 J 1.17 21. 1,2-Dichloreethane 0,02 0,200 0.02 J 0.07 J 0.02 J 0.02 J 0.06 J 22. Trichloroethene 0.23 1.000 --- U --- U --- U --- U --- U 23, 1,2-Dichloropropane 0.04 0.200 --- U --- U --- U --- U --- U 24. Bromodichlaromethane 0.04 0,200 --- U --- U --- U --- U - U 25. Cie-1,3-Dichloropropene 0.06 0.200 --- U --- U --- U --- U --- U 26. 4-Me thy l-2- Pent anone 1.19 100.000 --- U --- U --- U --- U " ' U 27, Toluene 0.23 1.000 --- U "-- U --- U --- U `-- U 28. trans-1,3-Dichloropropene 0.04 0.200 --- U --- U --- U --- U - U 29. 1,1,2-Trichloroethane 0.03 0.200 --- U --- U --- U --- U -- U 30, Tetrachloroethene 0.10 0,200 --- U --- U --- U --- U --- U 31. 2-Hexanone 1.57 50.000 --- U --- U --- U --- U --- U 32. Dibromochloromethane 0.03 0.200 --- V --- U --- U --- U --- U 33. 1,2-Dibromoethane 0.03 0.200 --- U --- U --- U --- U -"" U 34. Chlorobenzene 0.30 3.000 --- U --- U --- U --- U --- U 35. 1,1,1,2-Tetrachloroethane 0.22 1,000 --- U --- U --- U --- U --- U 36. Ethylbenzene 0.21 11000 --- U --- U --- U --- V --- U 37, xylenes 0.68 5.000 --- U --- U --- U --- U --- U 3B. Dibromomethane 0.28 10.000 --- U --- V --- U --- U --- U 39, Styrene 0.19 1.000 --- U --- V --- U --- U --- U 40. Bromoform 0.20 3.000 --- U --- U --- U --- U V 41. 1,1,2,2-Tetrachloroethane 0.03 0.200 --- U --- U --- U --- U --- U 42. 1,2,3-Trichloropropane 0.09 0.200 --- U --- U --- U --- U --- U 43. 1,4-Dichlorobenzene 0,39 1.000 --- U --- U --- U --- U --- U 44. 1,2-Dichloroben7ene 0.32 5.000 --- U --- U --- U --- V --- U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U --- U --- U --- U --- U 46, Acrylonitrile 2.72 200.000 --- U --- U --- U --- U ""- U 47. trans-1,4-Dichloro-2-Butene 0.42 100.000 --- U --- U --- U --- U --- U 40. Acrolein 1.97 4.000 --- U --- U '-- U -`" U --- U J = Estimated value between the MDL and MRL, U . Below ALL 0uantitation Limits, EmAmmu(M Tn houpumbd Drinking Water IDz 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 2 DURHAM, NC 7703 DATE ANALYZED: 06/24/19 DATE REPORTED: 0$/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(1$) MW-4 MW-5 MW-6 MW-7 KW-8 PARAMETERS, ug/l MDL MRL 49. Allyl Chloride 0.20 10.000 --- u --- u --- U --- u --- U 50. Chloroprene 0.21 20,000 --- u --- u --- u --- U --- u 51. 1,3-Dichlorobenzene 0.41 5.000 --- u --- u --- u --- U --- u 52. DichlorodiPluoromethane 0.51 5.000 --- u --- u --- u --- 1i --- U 53. 1,3-Dichloropropane 0.28 1.000 --- u --- U --- u --- u --- u 54, 2,2-Dichloropropane 0.17 15.000 --- u --- u --- u --- u --- u 55. 1,1-Dichloropropene 0.22 5.000 --- u --- u --- a --- U --- u 56. Ethyl Methacrylate 0.16 10.000 --- a --- u --- U --- u --- u 57. Hexachlorobutadiene 0.10 01200 --- u --- U '-' u --- u --- u 58. 100butyl Alcohol 12.80 100-000 --- ❑ --- u --- u --- u --- u 59. Methacrylonitrile 1.93 100.000 --- u --- u --- U --- U " ' u 60. Methyl Methacrylate 0.25 30.000 --- u U --- a --- u --- u 61. Naphthalene 0.47 6.000 --- u --- u 1.34 J --- u --- u 62. Propionitrile 3.26 150,000 --- u --- u --- u --- u --- u $3, 1,2,4-Trichlorobenzene 0.50 10.000 --- V --- u --- V --- U --- u 64, Acetonitrile 36.29 55.000 --- D --- U --- u --- u --- u 65. TetrahydroEuran 0.39 11000 2.44 6.90 14.40 27.00 28.10 66. 1,4-Dioxana 2.71 3.000 --- u 74.20 40.10 17.00 94.70 J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limite. ElMnEmIN 1, hvwpomhd Drinking Water IDi 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 3 DURHAM, NC 2 703 DATE ANALYZED: 06/24/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX 11 EPA METHOD 8260D R4(18) PARAMETERS, Ug/1 M➢L MRL Trip Blank 1, Chloramethane 0.77 3.000 --- U 2, Vinyl Chloride 0.12 0.200 --- U 3. Bromomethane 0.67 10.000 --- U 4. Chloroethane 0.48 10.000 ^ - U 5. Trichlorofluoromethane 0.24 1.000 --- U 6, 1,1-Dichloroethene 0.17 5.000 --- U 7. Acetone 9.06 100.000 --- U 8, iodomethane 0.26 10,000 --- U 9. Carbon Diaulfide 0.23 100.000 --- U 10. Methylene Chloride 0.64 1.000 --- U 11. trans-1,2-Dichloroethene 0,23 5.000 --- U 12, 1,1-Dichloroethane 0.20 5.000 --- U 13. Vinyl Acetate 0.20 50.000 --- U 14. Cls-1,2-Dichloroethene 0.25 5.000 --- U 15. 2-Butanone 2.21 100.000 --- U 16. Bromochloromethane 0.27 3,000 --- U 17, chloroform 0.25 5.000 --- U 18. 1,1,1-Trichloroethane D,19 1.000 --- U 19. Carbon Tetrachloride 0.04 0.200 --- U 20, Benzene 0.24 1.000 --- U 21. 1,2-Dichloroethane 0.02 0,200 --- U 22. Trichloxoethene 0.23 1.000 --- U 23. 1,2-Dichloropropane 9104 0.200 --- 24, Bromodichloromethane 0.04 0.200 --- U 25. Cis-1,3-❑ichloropropens 0.06 0.200 --- U 26. 4-Methyl-2-Pentanone 1.19 100,000 --- U 27. Toluene 0.23 1.000 --- U 28. trans-1,3-Dichloropropene 0,D4 0,200 --- U 29. 1,1,2-Trichloroethane 0.03 0.200 --- U 30. Tetrachloroethene 0.10 0.200 --- U 31. 2-Hexanone 1.57 50,000 --- U 32. Dibromochloromethane 0.03 0.200 --- U 33. 1,2-Dibromoethane 0,03 D.200 --- U 34. Chlorobenzene 0.30 3.000 --- U 35. 1,1,1,2-Tetrachloroethane 0.22 1.000 --- U 36. Ethylbenzene 0.21 1.000 --- U 37. %ylenes 0.68 5.000 --- U 38. Dibromomethane 0.28 10.000 --- U 39. Styrene 0.19 1.000 --- U 40. Bromoform 0.20 3.000 --- U 41. 1,1,2,2-Tetrachloroethana 0.03 0.200 --- U 42. 1,2,3-Trichloropropane 0.09 0.200 --- U 43. 1,4-Dichlorobenzene 0.39 1.000 --- U 44. 1,2-Dichlorobenzene 0.32 51000 --- U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U 46. Acrylonitrile 2.72 200,D00 --- U 47. trans-1,4-Dichloro-2-Butene 0.42 100.000 --- U 48. Acrolein 1.97 4.000 --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. Eflwokmmg[W % hmpmmhd Drinking Water IDr 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 4 DURHAM, NC 2 703 DATE ANALYZED: 06/24/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(1B) PARAMETERS, ug/1 MDL MRL Trip Blank 49, Allyl Chloride 0.20 10.000 --- U 50. Chloroprene 0.21 20.000 --- U 51. 1,3-Dichlorobenzene o.41 5.000 --- U 52. Dichlorodifluoramethane 0.51 5.000 --- U 53. 1,3-Diohloropropane 0.28 1.000 --- U 54. 2,2-Dichloropropane 0.17 15.000 --- U 55. 1,1-Dichloropropene 0.22 5.000 --- U 56. Ethyl Methacrylate 0.16 10.000 --- U 57. Hexachlorobutadiene 0.10 0,200 --- U 58, Ieabutyl Alcohol 12.80 100.000 --- v 59. Methacrylnnitrile 1.93 100.000 --- U 60, Methyl Methacrylate 0.25 30,D00 --- U 61. Naphthalene 0.47 6.000 --- U 62, Propionitrile 3,26 150.000 --- U 63. 1,2.4-Trichlorobenzene 0.50 10,000 --- U 64. Acetonitrile 36.29 55.000 --- U 65. Tetrahydrofuran 0.39 1,000 --- U 66, 1,4-Dioxane 2,71 3.000 --- U a = Estimated value between the MDL and MRL, V A Below ALL puantitation Limits. C7 m m O m [n b Fes. p C (tea yn� < D pcn r` £J D Q OWO m Z LyJ m m O o Z :� � c' a o m v y c f] � -' 00 m m K- m N 7y Cn n H bm n ff5 K ,--, NJ00 � n 0n o 00 m n w o t Q IJ 0(A, N cn r O O y G PS N m en m m z m r 0 0 A ao TOTAL CHLORINE, mgll C7 n n R OR ugll AT COLLECTION o o c °C O < n — TEMPERATURE, o < AT COLLECTION 0 # OF CONTAINERS o rzn z jA F-a Imo+ W x M Field pff b h BOD 'd CL @'it'��:COD <>` >: Nitrate x `< Chloride wno :` '% C amide t7 b N z Hardness b 0 S ,b iL v <s Sulfate b 0 Metals W O ;r. = de Sulfide CD {,:: Conductivity DO n'CD x Temperature `d CD cm w G` m N va n PARAMETERS/TESTS n n p ^ n v CD n m x v = m p Z s 7 CZE z w 0 c o r m m r m [n O tad II ■III c� v� n i7 m m [n „ Fwr fir' z a Z rn m m m m m° " F c'c o 'mn cz o o m m m !O m m ^ m m 4 C v v a T ci ➢ r z ', z y z n, z m z o N cl �v n T o z z V a or n z Ocf) O O CTi C d mm r A m M z z cn n cn < r o rn ' O_ Z C7 Q 0 C#n r n rn m C O cn 0 (11� a P CR c CD CD o: m CD C n aCD o _ u3 = w o CCD Ej Er. -0 o w @. n w 3 `° CD o m w r-.4 Im W V O Ln DD DD }-1 it, M 'b C.1 m m w CZ p o 00 O Q Q G x0113 � C!3 0 n (I) UJ V Mc i ' C m x IJ �a.. n Ln 71 n d m m v m 33 m m m TOTAL CHLORINE, mg/I j� j� Ci 11....�� 11��' m m m OR ug/I AT COLLECTION o m Q C 'T, m TEMPERATURE, °C m { °' m AT COLLECTION o n o m # OF CONTAINERS ''•-::'s. ),+field Parameter 8260 Dup. 1 8260 Dup. 2 4� 4r `# ;i:.iis. } EPA 8270E 8270E Dup. 1 > Q] _ m m N m EPA 8081E s� 8081E Duplicate 4� 8260D App. II � 4� N. v.>«': 8260 App. II 1C� 8260 App. II 2 G� S2: "$::ic::s ���•�; 8260 App II 3 8260 App. H 4 4� 8151A Mandrill 4� `M`°' 8151A Duplicate > G) }: u o V rn cn c, PARAMETERSITESTS n S n 2 w rom n Cp 2 C7 a� n n O n m � Z7 _• � �i7 co T SQ = s r z m c� z z m m F /�z f l v�i �/�1' �O y O O z� m m m n n U oQ d z -n m o m y m c� z z m ➢ a o n> o 0 m 0 n- o> m = r m n p O C O 2 u' n m 61�m n m Z n0 O C7 0 = i 0 0 a m rn CD CD M FD !�, w 0 m Er CD C CD C:r VU En E w a 0 c� co 0 o � 0 CD �. SD CD m m CD o m m m G7 .o - C 0 CD n CD Q d W V O 00 (.D cn CD C) m C m a 00 cn x m m 0 m m Ei MEMMI ,y d 10 Li L Li c cn cn O 70 CD o a m u� 0 2f { n n m ^ z n U) n r o ^ Qv m Z z C q Z O m 70 .2! m 0 N 3> v ~ isJJ w m fj3 � ITI O G N� z w L=7 y ► J O o r m --Ao r y x,9 �fDGo Go CA I-»:3 rn n t� c �++ r) I.30 oo 411� o"a 0. 0 k 1� d v N v � 91� Q w w m m TOTAL CHLORINE, mgll OR ugll AT COLLECTION TEMPERATURE,°C O C ATCOLLECTION m # OF CONTAINERS m Field H ;P, 'b BOD 0. COD n w Nitrate ro TOC Alkalinityb Chloride Cyanide Hardness n P"• TDS p `d Sulfate > b Metals > `d Sulfide 'M b Conductivity > b DO 0- Temperature Y b PARAMETERSITESTS m o = c� m c- m = Z O : Ti O O m 73 m m cn m m m -n m a - v G� y 2 O r a O O n n � c � D � r�r O fD mm z r m M aN 0 r 9 O %I u O ul CD Qm w ¢' 0- n� CD m � w 0 cn c o m 0 0 0 CD 0 3 w � w m C tL � c o CD C CD n O W O Lrl OD OD 30 � %z n m m p00 C i O o f 0 0 0 0 z� ', y 2 0 Lh z �7 L7 ti7 W� W Op ��rrJ 4 Lnva�R, C7 N SJ7 S I l m m m CD � r V? m m m m TOTAL CHLORINE, mgll C7 m OR ug/I AT COLLECTidN un 0 m o Q z n OO < r TEMPERATURE,°C °�° ATCOLLECTION tr O O cn m %� CD # OF CONTAINERS z A N ldPar ter Fie ame 8260 Dup. 1 8260 Dup. 2 EPA 8270E 4� 1:?G:-: .,i,.y::i1M1 'C'.'•:+`.. ' "> ti::ry,Ar; fr{ .} 827 0E Dap. 1 i a a p 2!i EPA 8081B 8081B Duplicate ML «a 8260D App. 11 G] '°1:1 " 8260 App. II 1 4} liZ 8260 App. H 2 �� 1, 8260 App.11 3 G] 8260 App. 1T 4 8151A Landfill 8151A Duplicate PARAMETLRSITESTSCD v m o s = m v' -n n m v n z = n O z mrl o z� = z O -rn z m r� F c cn cn O ?p a cn m mn 0 m d G7 c -n m m l7] m ma y{ m � O rn- p O � = 0 S p r m `" cn f7"I n 37 y O > 0 C � Q Oz cn C Q 70 ➢ m cmi i S M Z 9 r� o c7 O � E N Drinking Water ID: 37715 �- Ww f--Ynr TD, 10 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 A J'UDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/12/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 08/06/19 DURHAM ,NC 27703 REVIEWED By MW-18 KW -ID MW-25 MW-2D MW-3S Analysis Method PARAMETERS MDL MRL ❑ate Analyst Code PH (field measurement), Units 6,5 7.2 6.5 9.0 6.8 06/12/19 SEB 450ORB-11 BOD, mg/l 2.0 2.0 --- U 2.0 --- U --- U 7.5 06/12/19 KDS 52105-11 COD, mg/1 0.840 20.0 36 28 67 --- U 423 06/13/19 SEJ HB000-79 Nitrate Nitrogen me N, mg/1 0.009 0.04 0,17 --- U 0,10 0.11 --- U 06/13/19 AKS 353.2 R2-9 Total organic Carbon, mg/l 0.129 110 13.00 7.14 26.08 2.24 164.6 06/13/19 SEJ 531OC-11 Alkalinity (to pH 4,5)0 mg CaCO3/1 1.0 1.0 165 171 280 182 1610 06/17/19 TCW 2320E-11 Chloride, mg/1 5.0 5.0 11 13 52 12 229 06/17/19 KDS 4500CLB-11 Cyanide, ug/1 5.0 5.0 --- U --- U --- U --- U --- U 06/14/19 SEJ 45000NE-11 Total Hardness, mg/1 326 140 546 164 856 06/17/19 JTH 234OC-11 Total Dissolved Residue, mg/l 1.0 10 406 213 882 264 2000 06/13/19 KDS 254OC-11 Sulfate, mg/l 5.0 5.0 110 13.3 346 34.0 98.4 06/17/19 SEJ 4500SO42E1 Antimony, ug/1 0,03 1.0 0.67J 0.04 J 0.09 J 0.03J 0,17 J 06/21/19 LFJ EPA200,8 Arsenic, ug/1 0.03 5.0 0.68 J 1.5 J 5.3 0.06 J 20 06/21/19 LFJ EPA200.8 Barium, ug/1 0,03 10.0 31.3 2B.1 94,7 1512 502 06/21/19 LFJ EPA200.8 Beryllium, ug/l 0.05 1.0 --- U --- U 0.05 J --- U 0,06 J 06/21/19 LFJ EPA200.8 Cadmium, ug/1 0.02 1.0 0.07 J --- U 0.06 J --- U --- U 06/21/19 LFJ EPA200.8 Cobalt, ug/1 0.03 1.0 0.10 J 0.07 J 1.3 0.09 J 2.9 06/21/19 LFJ EPA200.8 Total Chromium, ug/1 0.15 5.0 0.37 J --- U 2.0 J --- U 24 06/21/19 LFJ EPA200.8 Copper, ug/1 0.03 10.0 3.1 J 1.0 J 0,56 J 0.61 J 2.2 J 06/21/19 LFJ EPA200.8 Iran, ug/l 4.96 50,0 683 2960 10502 145 26669 07/01/19 LFJ EPA200.7 Manganese, ug/1 0.31 10.0 7,5 J 207 211 B.2 J 433 07/01/15 LFJ EPA200.7 Lead, ug/1 0.03 5.0 0.60 J --- U 0.04 J --- U --- U 09/21/19 LPJ EPA200.8 Mercury, ug/1 0.05 0.2D 0.06 J 0.12 J 0,08J 0.07 J 0,13 J 06/24/19 MTM 245,1 R3-9 Nickel, ug/l 0,03 10.0 2.4 J 0.72 J 3.9 J 1.1 J 5.6 J 06/21/19 LFJ EPA200.8 Selenium, ug/1 0.15 10.0 0,70 J 0.29 J 1.7 1 --- U 14 06/21/19 LFJ EPA200.8 Silver, ug/1 0.05 5.0 --- U -»- U --- U 0.06 J --- V 06/24/19 LFJ EPA200.8 Thallium, ug/1 0.05 1.0 0.14 J --- U --- U 0.10 J --- U 06/21/19 LFJ EPA200.B Tin, ug/l 0.05 100.0 --- U --- U --- U --- U --- U 07/29/19 LFJ EPA200.B Vanadium, ug/1 0.03 1.0 1.5 --- U 0.60 J --- U 5,9 D6/21/19 LFJ EPA20D,8 Zinc, ug/1 0.11 10.0 2.3 J 3,8 J 2.3 J 4,7 J 2.8 J 06/21/19 LFJ EPA200.8 Sulfide, ug/1 SDO lODO --- U --- U --- U --- U --- V 06/19/19 LFJ 4500S2D-11 Conductivity {at 25c), uMhos/am 2.0 1.0 532 403 1311 456 3792 06/12/19 SEB 2510E-11 Dissolved Oxygen, mg/1 0.1 0.1 0.97 3.76 0187 0.64 0,92 06/12/19 SSB 450000-11 Temperature, °C 19 18 20 19 21 06/12/19 SEB 2550B-10 Static Water Level, feet 8.11 B,64 10.75 12.55 11.90 06/12/19 SEB Well Depth, feet 17.21 33.75 26.57 38.17 22.24 06/12/19 SEB Carbon Dioxide, mg/1 1.0 1.0 68 13 121 6 3000 06/12/19 KDS 45000O2C-1 ORP, my +102 +BO +40 +61 -95 06/12/19 SEE 25BOB Turbidity (Field), NTU 1,0 1.0 3.96 5,88 2.50 3,04 6.40 05/12/19 SEB 213OB-11 J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. ENAmmol % hmpumbd Drinking Water TD: 37715 114 OAKMONT DRIVE GREENVILLE, N,C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 A DATE COLLECTED: 06/12/19 DATE REPORTED : 08/08/19 REVIEWED BY; /Z� MW-3D MW-3A Trip Analysis Method PARAMETERS MDL MRL Blank ➢ate Analyst Code PH (field measurement), Units 7.9 6.8 D6/12/19 SUB 450DHB-11 BOD, mg/l 2.0 2.0 --- U --- U 06/12/19 KDS 5210E-11 COD, mg/l 0,840 20.0 --- U 190 06/13/19 SEJ HOD00-79 Nitrate Nitrogen as N, mg/l 0.009 0.04 0.35 --- U 06/13/19 AKS 353.2 R2-93 Total Organic Carbon, mg/1 0.129 1.0 2.42 75.20 06/13/19 SEJ 531OC-11 Alkalinity {to pH 4.5), mg CaCO3/1 1.0 1.0 236 B10 06/17/19 TCW 232OB-11 Chloride, mg/l 5.0 5,0 21 84 06/17/19 KDS 4500CLB-11 Cyanide, ug/1 5.0 5.0 --- U --- U 06/14/19 SEJ 450OCNE-11 Total Hardness, mg/l 92 596 06/17/19 JTH 234OC-11 Total Dissolved Residue, mg/1 1.0 10 309 1090 06/13/19 KDS 254OC-11 Sulfate, mg/l 5.0 5.0 8.6 105 06/17/19 SEJ 4500SO42Ell Antimony, ug/l 0.03 1,0 0.04 J 0.14 J 06/21/19 LFJ EPA200.8 Arsenio, ug/1 0.03 5.0 0.27 J 11 06/21/19 LFJ EPA200.8 Barium, ug/l 0.03 10.0 9.2 J 238 06/21/19 LFJ EPA2D0.8 Beryllium, ug/l 0,05 1.0 --- V 0,06 J 06/21/19 LFJ EPA200.8 Cadmium, ug/l 0.02 1.0 --- U --- U 06/21/19 LFJ EPA200.8 Cobalt, ug/l 0.03 1.0 0.03J 6.0 06/21/19 LFJ EPA200.8 Total Chromium, ug/l 0.15 5.0 --- U 9.3 06/21/19 LFJ EPA200,8 Copper, ug/1 0.03 10.0 0.73 J 1.0 J 06/21/19 LFJ EPA200,8 Iron, ug/1 4.96 50.0 9B 28630 07/01/19 LFJ EPA200.7 Manganese, ug/1 0.31 10.0 0.33 J 790 07/01/19 LFJ EPA200.7 Lead, ug/1 0.03 5.0 --- U --- U 06/21/19 LFJ UPA200.8 Mercury, ug/l 0.05 0.20 0.06 J --- U 06/24/19 MTM 245.1 R3-94 Nickel, ug/l 0.03 10.0 0.55 J 4.5 J 06/21/19 LFJ UPA200,8 Selenium, ug/l 0.15 10.D 0,66 J 4.0 J 06/21/19 LFJ 13PA200.8 Silver, ug/l 0,05 5.0 --- U --- U 06/24/19 LFJ UPA200.B Thallium, ug/l 0,05 1.0 --- U --- V 06/21/19 LFJ 13PA200.8 Tin, ug/l 0.05 100.0 --- U --- U 07/29/19 LFJ EPA200.8 Vanadium, ug/l 0.03 1.0 --- U 2,5 06/21/19 LFJ UPA200,8 Zinc, ug/l 0.11 10,0 2.1J 3.1 J 06/21/19 LFJ EPA200.8 Sulfide, ug/l 100 1000 --- V --- U 06/19/19 LFJ 4500S2D-11 Conductivity (at 25c), uMhos/cm 1.0 1.0 567 2013 06/12/19 SUB 2510E-11 Dissolved oxygen, mg/l 0.1 0.1 1.26 0.99 06/12/19 SUB 45000G-11 Temperature, °C 18 17 06/12/19 SEE 2550E-10 Static Water Level, feet 12,65 11.20 06/12/19 RUB well Depth, feet 52.30 23.44 06/12/19 SUB Carbon Dioxide, mg/l 1.0 1.0 6 240 06/12/19 KDS 45000O2C-11 ORP, my +91 -12 06/12/19 SUB 2580E Turbidity {Field), NTU 1.0 1.0 2.33 5.62 06/12/19 SUB 2130E-11 J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. Elow,moomsM T, hmpumlod Drinking Water XD; 37715 114 OAKMON7 DRIVE PHONE (252) 756-6208 GREENVILLE, N.C, 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 1 DURHAM, NC 27703 DATE EXTRACTED: 06/17/19 DATE ANALYZED: 07/10/19 REVIEWED BY: DATE REPORTED: 08/08/19 PESTICIDES AND PCB'S EPA METHOD 8081.B R2(07) MW-IS MW-AD MW-2S MW-2D MW-3S PARAMETRRS, ug/1 MDL MRL 1. Aldrin 0.029 0.050 --- U --- U -'- U --- U --- U 2, Alpha-BHC 0.032 0.050 --- U --- U --- U --- V "" U 3, Beta-BHC 0,031 0.050 --- U --- U --- U --- U --- U 4. Delta-BHC 0.030 0.050 --- U --- U --- U --- U --- U 5. Gamma-BHC (Lindane) 0.032 0.050 --- U --- U --- U --- U --- U 6. chlordane 0.320 01500 --- U --- U --- U --- U ^-- U 7. 4,4-DDD 0.051 0.100 --- U --- U --- U --- U --- U 8. 4,4-DDE 0.049 0.100 --- U --- U --- U --- U --- U 9. 4,4-DDT 0.052 0.100 --- U --- U --- U "" U --- U l0. Dieldrin 0.042 0.075 --- U --- U --- u --- U --- U 11. Endooulfan i 0.056 0.100 --- U --- U --- U "'" V --- U 12. Endoeulfan Ii 0,046 0.100 --- U --- U --- U --- U --- U 13. Endoeulfan Sulfate 0.072 0,100 --- U --- U --- U --- U --- U 14, Endrin 0.053 0.100 --- U --- U --- U --- U --- U 15. Endrin Aldehyde 0.066 0.100 --- U --- U 0.079 J --- U --- U 16. Heptachlor 0,039 0.050 --- U --- V --- U --- U --- U 17. Heptachlor Epoxide 0.042 0.075 --- U --- U --- U --- U --- U 1B. Methoxychlor 0,530 1.000 --- U --- U --- U --- U --- U 19, Pcb'a (Aroclore) 0.500 2.000 --- U --- U --- U --- U --• V 20. Toxaphene 0.690 1.500 --- U --- U --- U --- U --- U d p Estimated Value between the MDL and MRL, U n Below ALL Quantitation Limita. ElMommml % hmpumbd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 2 DURHAM, NC 27703 DATE EXTRACTED: 06/17/19 DATE ANALYZED: 07/10/19 REVIEWED BY: DATE REPORTED: 08/08/19 PESTICIDES AND PCB'S EPA METHOD 8081E R2(07) PARAMETERS, ug/l MDL MRL NW-3D MW-3A 1. Aldrin 0.029 0.050 --- U --- U 2. Alpha-BHC 0.032 0.050 --- U --- U 3. Beta-BHC 0.031 D.050 --- U --- U 4. Delta-BHC 0,030 0.050 •-- U --- U S. Gamma-BHC (Lindane) 0.032 0.050 --- U --- U 6. Chlordane 0.320 0.500 -•- U --- U 7. 4,4-DDD 0.051 0.100 --- U --- U B. 4,4-DDE 0.049 0.100 --- U --- U 9. 4,4-DDT 0.052 0.100 --- U --- U 10. Dieldrin 0.042 0,075 --- U --- U 11. Endosulfan I 0.056 0.100 --- U --- U 12. Endosulfan II 0.046 0.100 --- U --- U 13. Rndosulfan SulEate 0.072 0.100 .--- U --- U 14. Endrin 0.053 0.100 --- V --- U 15, Bndrin Aldehyde 0.06E 0.100 --- U 0.069 .7 16. Heptachlor 0.039 0.050 --- U --- U 17. Heptachlor Epoxide 0.042 0.075 --- U --- U 18. Methoxychlor 0,530 1.000 --- U --- U 19. Pcb's (Aroclore) 0.500 2.000 --- U --- U 20. Toxaphene 0.690 1.500 --- V --- U J = Estimated value between the MDL and MRL, U - Below ALL Quantitation Limits, ElMonflumW Ala hmpumbA Drinking Water IDr 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 1 DURHAM, NC 27703 DATE EXTRACTED: 06/18/19 REVIEWED BY: '�LJ DATE REPORTED: 08/08/19 LANDFILL APPENDIX II EPA METHOD 8151A R1(96) Date Analyzed 06/28/19 06/2B/19 06/29/19 06/2B/19 06/29/19 MW-18 MW-ID MW-2S MW-2D MW-3S PARAMETERS, ug/l MDL MRL 1. 2,4-D 0.36 2.000 --- U --- U _-- U --- U --- U 2. Dinoseb 0,54 1.000 --- U --- U --- U --- U --- U 3, 2,4,5-TP 0.42 2.000 --- U --- U --- U -__ U --- U 4. 2,4,5-T D.47 2.000 --- U --- U ^-- U --- U --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits, NuAmmumM % hc0Tpmm%d Drinking Water ID; 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II APA METHOD 8151A R1(96) CLIENT ID: 6003 A ANALYST: JAP DATE COLLECTED: 06/12/19 DATE EXTRACTED: 06/18/19 DATE REPORTED: 08/08/19 Date Analyzed 06/29/19 06/29/19 MW-3D MW-3A PARAMLTERS, Ug/l MDL MRL 1, 214-D 0,36 2,000 --- U --- U 2. Dinoaeb 0.54 1,000 --- U --- U 3. 2,4,5-TP 0,42 2.000 --- U --- U 4. 2,4,5-T 0.47 2,000 --- U --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. Page: 2 ERADTOMESM Flo bw _n 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: 0-UDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: PHONE (252) 756-6208 FAX (252) 756-0633 6003 A ANALYST: KPG DATE COLLECTED: 06/12/19 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) Page: 1 PARAMETERS, ug/l MDL MRL MW-1S MW-ID NW-29 MW-2D MW-3S 1. Acenaphthane 2.66 10,000 --- U --- U --- U --- U 8.10 J 2, Acenaphthylens 2.60 10,000 --- U --- U --- U --- U --- U 3, Anthracene 2.97 10.0D0 --- U --- U --- U --- U --- U 4. Benzo[a]antrhacene 4,16 10.000 --- U "- U -•- U --- U --- U 5. Benzo[b]fluoranthene 3,32 10,000 --- V --- U --- U --- U _-- U 6. Benzo(k]fluoranthene 4.23 10.000 --- U --- U --- V --- U --- U 7. Benzo[g,h,ilperylene 2.61 1D.000 --- U --- U --- U --- U --- U S. Benzo[a]pyrene 3.27 10.000 --- U --- U --- U --- U --- U 9, 4-Bromophenyl Phenyl Ether 2.63 10.000 --- U --- U --- U --- U --- U 10. Butyl Benzyl Phthalate 5.78 10.000 --- U --- V --- U --- U --- U 11. Bis(2-Chloroethoxy) Methane 3.14 10,000 --- U --- U --- U --- U --- U 12. Bis(2-Chloroethyl) Ether 2.5B 10.000 --- U --- U --- U --- U --- V 13. Bis(2-Chloro-l-methylethyl) Ether 2.58 10.000 --- U --- U --- U --- U --- U 14, 2-Chloronaphthalene 2.17 10.000 --- V --- U --- U --- U --- U 15. 4-Chlorophenyl Phenyl Ether 2A2 10.000 --- U --- U --- U --- U --- U 16, Chryaene 4.04 10.000 --- U --- U --- U --- U --- U 17. Dibenzo[a,blanthracene 2.78 10,000 --- U --- U --- U --- U --- U 1B, Di-N-Butyl Phthalate 1.09 10.000 --- U U --- U --- U --- U 19. Dimethyl Phthalate 3.78 10.000 --- U --- U --- U --- U --- U 20, Diethyl Phthalate 3.92 10.000 --- U --- U --- U --- U --- U 21. 2,4-Dinitrotoluene 3.95 10,000 --- U --- U --- U --- O --- U 22. 2,6-Dinitratoluene 3.88 10,000 --- U --- U --- U --- U --` U 23. Di-N-Octyl Phthalate 2.81 10,000 --- U --- V -" U "' U --- U 24, Bia-(2-Ethylhexyl) Phthalate 9,97 25.000 U --- U U --- U --- U 25. Fluoranthene 3.92 20.000 --- U --- U --- U --- U --- U 26. Fluorene 2.95 10.000 --- U --- U --- U --- U 5.31 J 27, Hexachlorobenzene 2.61 10.000 --- U --- U --- U --- U --- U 2B. Hexachlorocyclopentadiene 4.16 10,000 --- U --- U --- U --- U --- U 29, Indeno[l,2,3-Cd1pyrene 2.91 10,000 --- U --• U --- U --- U --- U 30. Isophorone 3.74 10.000 --- U --- U --- U --- U --- U 31. Nitrobenzene 2.85 10.000 --- U --- U --- U --- U --- U 32. N-Nitrosodimethylamine 4,25 10.000 --- U --- U --- U --- U --- U 33, N-Nitroaodiphenylamine 3,95 10.000 --- U --- U --- U --- U --- U 34. N-Nitrosodi-N-Propylamine 4.06 10.000 --- U --- U --- U --- U --- U 35. Phenanthrene 3.24 10.000 --- U --- U --- U --- U --- U 36. pyrene 3.63 10.000 --- U --- U --- U --- U --- U 37, 4-Chlorc-3-Methylphenal 3.79 20.000 --- U --- u --- U --- U --- U 38. 2-Chlorophenal 2.75 10.000 --- V --- U --- U --- U --- U 39, 0-Creso1 3.68 10.D00 --- U --- U --- U --- U --- U 40. P-Cresol 4.12 10.000 --- U --- U --- U --- U --- U 41. 2,4-Dichlorophenol 5119 10.000 --- U --- U --- U --- U --- U 42, 2,6-Dichlorophen0l 4.09 10,000 --- U --- U --- U --- U --- U 43. 2,4-Dimethylphenol 3.21 10.000 --- U --- U --- U --- U --- U 44. 4,6-Dinitro-2-Methylphenol 4.77 50.000 --- U --- U --- U --- U --' U 45, 2,4-Dinitrophenol 4.37 50.000 --- U --- U --- U --- V -'- U 46. Ethyl Methanesulfonate 5.26 20.000 --- U --- U --- U --- U --- U 47. Methyl Mathaneeulfonate 4.92 10.000 --- U --- U --- U --- U --- U 48, 2-Nitrophenol 3.64 10.000 --- U --- U --- U --- U --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EWOmMUMM % Numpumbd Drinking Water IDi 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE. N,C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 2 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) MW-Is MW-1D MW-28 MW-2D taw-3S PARAMETERS, u9/1 MDL MILL 49. 4-Nitrophenol 3.17 50,000 --- U --- U --- U --- V --- U 50. Pentachlorophenol 5.33 25,000 --- U --- U --- U --- U --- U 51, Phenol 1.86 10.000 --- U I --- U --- U --- U --- U 52. 2,3,4,6-Tetrachlorophenol 3.12 10,000 --- U --- U --- U --- U --- Ti 53. 2,4,5-Trichlorophenol 4.17 10.OD0 --- U --- U --- U --- U --- U 54, 2,4,6-Trichlorophenol 3.84 10.000 --- U --- U --- U --- U --- U 55. Acetophenone 2.89 10.000 --- U --- U --- U --- U --- U 56. 2-Acetylamin0flUorane 3.99 20.000 --- U --- U --- U --- U --- V 57. 4-Aminobiphenyl 4.12 20.000 --- U --- U --- U --- U --- U 58, Benzyl Alcohol 4,47 2D.000 _-- U --- U --- U --- U --- U 59. 4-Chloroaniline 3.36 20.000 --- U --- U --- U --- U --- U 60. Chlorobenzilate 5.12 10.000 --- U --- U --- U --- U --- U 61, Diallate 2.98 10.000 --- U --- U --- U --- U --- ❑ 62, Dibenzofuran 4.28 10.D00 --- U --- U --- U --- U --- U 63, 3,3-Dichlorobenzidine 4.22 20,000 --- U --- U --- U --- U --- U 64, Dimethoate 3.98 20.000 --- U --- U --- U --- U --- U 65. P-Dimethylaminoazobenzene 2.89 10.000 --- V --- U --- U --- U --- U 66. 7,12-13imethylbenz[alanthracene 5.26 10.000 --- U --- U --- U --- U --- U 67. 3,3-Dimethylbenzadine 3.21 10.000 --- U --- U --- U _-- U "' U 6B, 1,3-Dinitrobanzene 2.89 20.000 --- U --- U --- U --- U --- U 69. Diphenylamine 5.10 10.000 --- U --- U --- U --- U --- U 10. ❑isulf0ton 4.28 10,000 --- U "' U --- U --" U --- U 71. Famphur 3.98 20.000 --- U --- U --- U --- U --- U 72. Rexachloropropene 4.31 10.000 --- U --- U --- U --- U --- U 73. Iaoeafrole 2.88 10.000 --- U --- V --- U --- U --- U 74. Kepone 2.78 20,000 --- U --- U --- U --- U --- U 75. Methapyrilene 3.54 100.000 --- U --- U --- V --- U --- U 76. 3-Methylchloroanthrens 4.21 10,000 --- U --- U --- U --- U --- U 77, 2-Methylnaphthalene 3,79 10.000 --- U --- U --- U --- U --- U 7B. Methyl Parathion 4.32 10.000 --- U --- U --- U --- U --- U 79. m-Cresol 3,81 1D.000 --- U --- U '-- U --- U --' U 80. 1,4-Naphthoquinone 4.00 10.000 --- U --- U --- U --- U --- U $1. 1-Naphthylamine 5.61 10.000 --- U --- U --- U --- U 0 82, 2-Naphthylamine 4.62 10.000 --- U --- U --- U --- U --- U 83. 2-Nitroaniline 3.61 50,000 --- U --- U --- U --- U --- U 84. 3-24itroaniline 4.81 50,D00 --- U U --- U --- U --- U 85. 4-Nitroaniline 4.22 20.000 --- U --- U --- U --- U --- U 86. 5-Nitro-O-Toluidine 4.01 10.000 --- U --- U "' V "' U --- U 87. N-Nitrosodi-n-butylamine 3.63 10.000 --- V --- U --- U --- U --- V 68. N-Nitronodiethylamine 3.83 20.000 --- V --- U --- U --- U --- U 89, N-Nitrosomethylethylamine 3.83 10.000 --- U --- U --- U --- U --- U 9o, N-Nitroeopiperidine 5.19 20,000 --- U --- U --- U --- U V 91. N-Nitrosopyrrolidine 2.89 10.000 --- U --- U --- U --- U --- U 92. Parathion 3.12 10,000 --- U --- U --- U --- U -"" U 93. Pentachlorobenzene 3.92 10.000 --- U --- U --- U --- U --- U 94. Pentachloronitrobenzene 3,71 20.000 --- U --- U --- U --- U --- U 95. Phenacetin 4.41 20.000 --- U --- U --- U --- U --- U 96. 1,4 Benzenediamine 2.09 10.000 --- U --- U --- U --' U --- U = Estimated value between the MDL and MRL, V = Below ALL Quantitation Limits. ENW'0T@MH@V % hmpufflUd Drinking Water IDi 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WEITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 3 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED; 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) MW-1S MW-1D MW-2S MW-2D MW-38 PARAMETERS, Ug/l MDL MRL 97. Pharate 3.86 10.000 --- U --- U -'- U '-- U --- U 98. Pronamide 3.69 10.000 --- U --- U --- U '-' U --- V 99. Safrole 4.12 10.000 --- U --- U --- U --- U --- U 100. 1,2,4,5-Tetraphlorobenzene 5.01 10.000 --- U --- U --- u --- U --- U 101. Thionazin 4.62 20,000 --- U --- U --- U --- U --- U 102. 0-Toluidine 4.11 10.000 --- U --- U --- U --- U -"" U 103, 1,3,5-Trinitrobenzene 3.98 10.000 --- U --- U --- U --- U --- U 104. 0,0,0-Triethyl Phosphorothioate 3.61 10.000 --- U --- U --- V --- U --- U 105. Eexachloroethane 1.49 10.000 --- V --- U --- U --- U --- U 106. Ieodrin 3.11 20.000 --- U --- U --- U --- U --- V J a Estimated Value between the MDL and MRL, U = Below ALL 4uantitation Limits. EmAmMEW % hom n 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID; 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page; 4 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, u9%1 MDL MRL MW-3D MW-3A 1, Acenaphthene 2.66 10.000 --- U --- U 2. Acenaphthylene 2.60 10.000 --- U --- U 3. Anthracene 2.97 10,000 --- U --- U 4, Benzo[a]antrhacene 4.i6 10.000 --- U --- U 5, Benzo[b]fluoranthene 3.32 10.000 --- U --- U 6, Benzo[k]fluoranthene 4.23 10.000 --- U --- U 7, Benzo[g,h,i]perylene 2.61 10.000 --- U --- U a, Benzo[a]pyrene 3.27 10.000 --- U --- U 9. 4-Bromophenyl Phenyl Ether 2.63 10.000 --- U --- U 10. Butyl Benzyl Phthalate 5.70 10,000 --- U --- U 11. Bis(2-Chloroethoxy) Methane 3.14 10.000 --- U --- U 12, Bis(2-Chloroethyl) Ether 2.58 10,000 --- U --- U 13. Bie(2-Chloro-l-methylethyl) Ether 2.58 10.000 --- U --- U 14. 2-Chloronaphthalene 2.17 10.000 --- U --- U 15, 4-Chlorophenyl Phenyl Ether 2,42 10,000 --- U --- U 16. Chrysene 4.04 10.000 --- U --- U l7. ❑ibenzo(a,h)anthracene 2.78 10.000 --- U --- U 18. Di-N-Butyl Phthalate 3.09 30.000 --- U --- U 19. Dimethyl Phthalate 3.79 10.000 --- U --- U 20, piethyl Phthalate 3.92 10.000 --- U --- U 21. 2,4-Dinitrotoluene 3.95 10.000 --- U --- U 22, 2,6-Dinitrotoluene 3.88 10,000 --- U --- U 23. Di-N-Octyl Phthalate 2.91 10.000 » U --- U 24. Bis-(2-Ethy1hexyl) Phthalate 9.97 25.000 --- U --- U 25. Fluoranthene 3.92 10.000 --- U --- U 26. Fluorene 2.95 10.000 --- U --- U 27. Hexachlorobenzene 2.61 10.000 --- U --- U 20, Hexachlarocyclopentadiene 4.16 10,000 --- U U 29, 1ndeno[1,2,3-Cd]pyrene 2.91 10,000 --- V --- U 30. Isophorone 3.74 10.000 --- U --- U 31. Nitrobenzene 2.05 10.000 --- U --- U 32. N-Nitrosodimethylamine 4.25 10.000 --- U --- U 33. N-Nitrosodiphenylamine 3.95 10.000 --- U --- U 34. N-Nitrosodi-N-Propylamine 4,06 10.000 --- U --- U 35, ehenanthrene 3.24 10.000 --- U --- U 36. Pyrene 3,63 10.000 --- U --- U 37, 4-Chloro-3-Methylphanol 3.79 20.000 --- U --- U 38. 2-Chlorophenol 2.75 10.000 --- U --- U 39. 0-Cresol 3.60 10.000 --- U --- U 40. p-Cresol 4.12 10.000 --- U --- U 41. 2,4-Dichlorophenal 5.19 10,000 --- U U 42. 2,6-Dichlorophenol 4.89 101000 --- V --- U 43, 2,4-Dimethylphenol 3.21 10.000 --- V --- U 44. 4,6-Dinitro-2-Methylphenol 4.77 50.000 --- U --- V 45. 2,4-Dinitrophenol 4.37 50,000 --- U --- U 46. Ethyl Methanesulfonate 5.26 20.000 --- U --- U 47. Methyl MethanesulEonate 4.92 10.000 --- U --- U 48, 2-Nitrophenol 3.64 10.000 --- U --- U a - Estimated value between the MDL and MRL, U = Below ALL Ruantitation Limits. ERWITuMN&W % hcupmhd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 06/12/19 Page: 5 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l MDL MRL MW-3]] MW-3A 49. 4-Nitraphonol 3.17 50.000 --- u --- u 50, Pentachlorophenol 5.33 25,000 --- u --- u 51, Phenol 1.96 10.000 --- u --- u 52, 2,3,4,6-Tetrachlorophenol 3.12 10.000 --- u --- u 53. 2,4,5-Trichloraphenol 4.17 10.000 --- a --- U 54. 2,4,6-Trichloxophenol 3.64 10.000 -•- a --- u 55. %ootophenone 2.89 10,000 --- u --- u 56. 2-AcetylaminQfluorene 3.98 20.000 --- u --- u 57, 4-Aminobiphenyl 4.12 20.000 --- U --- V 58. Benzyl Alcohol 4.47 20.000 --- U --- u 59, 4-Chluroaniline 3.36 20.000 --- u --- u 60, Chlorobenzilate 5.12 10.000 --- u --- u 61, Diallate 2.98 10.000 --- u --- u 62. ➢ibenzofuran 4.28 10.000 --- u --- u 63. 3,3-Dichlorobenzidine 4.22 20.000 --- u --- u 64. Dimethoate 3.99 20.000 --- u --- u 65. P-Dimethylaminoazabenzene 2.89 10.000 --- u --- u 66. 7,12-Dimethylbenzla]anthracena 5.26 10,000 --- u --- u 67. 3,3-Dimethylbenzadine 3.21 10.D00 --- U --- u 68. 1,3-Dinitrobenzene 2.B9 20.000 --- u --- U 69, Diphenylamine 5.1.0 10.000 --- u --- u 70, Disulfoton 4.20 10.000 --- u --- u 71. Famphur 3.96 20.000 --- u --- u 72. Hexachloropropene 4.31 10.000 --- u --- u 73. IeoeaErole 2,88 10.000 --- u --- u 74. Kepone 2.78 20.000 --- a --- u 75. Methapyrilene 3.54 100.000 --- u --- u 76, 3-Methylchloroanthreno 4.21 10.000 --- u --- u 77. 2-Mathylnaphthalene 3.79 10.000 --- u --- u 79. Methyl Parathion 4.32 10.000 --- u --- u 79. m-Cresol 3.81 10.000 --- u --- u 80, 1,4-Naphthoquinone 4.00 10.000 --- U "-- u 81. 1-Naphthylamine 5.61 1u,D00 --- u --- u 92, 2-Naphthylamine 4.62 10.000 --- u --- u 83. 2-Nitroaniline 3.61 50,000 --- u --- u 64. 3-Nitroaniline 4.01 50.000 --- u --- u 85. 4-Nitroaniline 4.22 20,000 --- u --- U 86. 5-Nitro-O-Toluidine 4.01 10.000 --- u --- u $7. N-Nitrosodi-n-butylamine 3.63 10.000 --- U --- u 08. N-Nitrosodiethylamine 3,83 20.000 --- u --- u e9. N-Nitrosomethylethylamine 3.B3 10.000 --- u --- u 90. N-Nitrosopiperidine 5.19 20.000 --- u --- u 91. N-Nitrosopyrrolidine 2,89 10.000 --- u --- u 92. Parathion 3.12 10.000 --- u --- u 93, Pentachlarobenzene 3.92 10.000 U -" u 94. Pentachloronitrobenzene 3.71 20.000 --- u --- u 95. Phenacetin 4.41 20,00o --- U --- u 96. 1,4 Benzenediamine 2.99 10,000 --- u --- u a = Hatimated value between the MDL and MRL, U = Below ALL Quantitation Limits. NRW'w@[MH(pV % hnTpumUd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: KPG 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/12/19 Page: 6 DURHAM, NC 27703 DATE EXTRACTED: 06/14/19 DATE ANALYZED: 06/20/19 REVIEWED Ely: _ DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, u9/1 MDL MRL MW-3D MW-3A 97. Phorate 3.86 10.000 --- u --- u 98. Pronamide 3.69 10.000 --- u --- U 99. Safrole 4.12 10,000 --- U --- u 100. 1,2,4,5-Tetrachlorobenzene 5.01 10.000 --- u --- u 101. Thionazin 4.62 20.000 --- u --- u 102, 0-Toluidine 4.11 10.000 --- u --- u 103. 1,3,5-Trinitrobenzene 3,98 10.000 --- u " ' D 104. 0,0,0-Triethyl Phonphorothioate 3.61 10.000 --- u --- u 105. Hexachloroethane 1.49 10.000 --- u _-- u 106, isodrin 3.11 20,000 --- U --- u a = Estimated value between the MAL and MRL, u - Below ALL Quantitation Limits. NflW'0F@flH@V % hmpumbd Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: /� f LANDFILL APPENDIX 11 P.PA MRTHOD 82 6 0D R4 (18 ) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 A ANALYST: JAP DATE COLLECTED: 06/12/19 Page: 1 DATE REPORTED: 08/08/19 Date Analyzed 06/24/19 06/24/19 06/24/19 06/24/19 06/25/19 MW-15 KW -ID MW-25 MW-2D MW-35 PARAMETERS, ug/l MDT, MRL 1. Chloramethane 0.77 3.000 --- U --- U --- U --- U --- U 2. Vinyl Chloride 0.12 0.200 --- U --- U --- U --- U --- U 3, Bromomethane 0,67 10.000 --- V --- U --- U --- U --- U 4, Chloroethane 0.48 10.000 --- U --- U --- U --- U --- U 5, Trichlor0fluoramethane 0.24 1.000 --- U --- U --- U --- U --- U 6. 1,1-Dichloroethene 0,17 5.000 --- U --- U --- U --- U --- U 7. Acetone 9.06 100.000 --- U --- U --- U --- V --- U B. iodomethane 0.26 10.000 --- U --- U --- U --- U --- U 9. Carbon Disulfide 0.23 100,000 --- U --- U --- U -'- U --- U 10. Methylene Chloride 0.64 1,000 --- U --- U --- U --- U --- U 11, trans-1,2-Dichloroethene 0.23 5.000 --- U --^ U --- U --- U -'- U 12. 1,1-Dichloroethane 0.20 5.000 --- U --- U --- V --- U --- U 13, Vinyl Acetate 0.20 50.000 --- U --- U --- U --- U --- U 14. Cis-1,2-Dichloroethene 0.25 5.000 --- U --- U --- U --- U "-- U 15. 2-Butanone 2.21 100.000 --- U --- U --- U --- U --- U 16. Bromochlaromethane 0.27 3.000 --- U --- U --- U --- U --- U 17. Chloroform 0.25 5.000 --- U --- U --- U --- U --- U 18, 1,1,1-Trichloroethane 0,19 1.000 --- U --- U --- U --- U --- V 19. Carbon Tetrachloride 0.04 0,200 --- U --- U --- U --- U --- U 20. Benzene 0,24 1.000 --- U --- U --- U --- U 0.09 J 21, 1,2-Dichloroethane 0.02 0,200 --- ❑ --- U --- U --- U 0.11 .7 22. Trichloroethene 0.23 1.000 --- U --- U --- U --- U --" U 23. 1,2-Dichloropropane 0.04 0.200 --- U --- U --- U --- U --- U 24. Bromodichloromethane 0.04 0,200 --- U --- U --- U --- U --- U 25. Cie-1,3-Dichloropropene 0.06 0.200 --- U --- U --- U --- U --- U 26. 4-Methyl-2-Pentanone 1.19 100,000 --- U --- U --- U --- U --- U 27. Toluene 0.23 1,000 --- U 1.09 --- U --- V --- U 28, trana-1,3-Dichloropropene 0.04 0.200 --- U --- U --- U --- U --- U 29. 1,1,2-Trichloroethane 0.03 0,200 --- U --- U --- U --- U --- U 3U. Tetrachloroethene 0.10 0.200 --- U --- V --- U --- U --- U 31. 2-Hexanone 1.57 50.000 --- U --- U --- V --- U --- U 32. ❑ibromochloromethane 0.03 0.200 --- D --- U --- U --- U --- U 33. 1,2-Dibromoethane 0.03 0.200 --- U --- U --- U --- U " ' U 34, Chlorobenzene 0.30 3.000 --- U --- U --- U --- U --- U 35. 1,1,1,2-Tetrachloroethane 0.22 11000 --- U --- U --- U --- U --- U 36, Bthylbenzene 0.21 1.000 --- U --- U --- U U U 37. XyleneS 0,6B 5.000 --- U --- U --- U "' U -"" U 38. Dibromomethane 0.28 10.000 --- U --- U --- U --- ❑ --- U 39. Styrene 0.19 1.000 --- U -"- U --- U --- U --- U 40. BromoEorm 0.20 3.000 --- U --- U --- U --- U --- U 41, 1,1,2,2-Tetrachloroathane 0.03 0.200 --- U --- U --- U --- U --- U 42. 1,2,3-Trichloropropane 0.09 0.200 --- U --- U --- U --- U --- U 43. 1,4-Dichlorobenzene 0.39 1.000 --- U --- U --- U --- U --- U 44. 1,2-Dichlorobenzene 0.32 5,000 --- U --- U --- U --- U --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U --- U --- U --- U --- U 46, Acrylonitrile 2.72 200.000 --- U --- U --- U --- U U 47, trane-1,4-Dichloro-2-Butene 0,42 100.000 --- U U -- U U U S . Estimated value between the MDL and MRL, U F Below ALL Quantitation Limits, ElmAmm(W alp hmpmAd Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX 11 EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 A ANALYST: JAP DATE COLLECTED: 06/12/19 Page: 2 DATE REPORTED: 08/08/19 Date Analyzed 06/24/19 06/24/19 06/24/19 06/24/19 06/25/19 MW-lS MW-1D MW-2S MW-2D MW-39 PARAMETERS, u9/1 MDL MRL 48. Acrolein 1.97 4.000 --- U --- U --- U --- U --- U 49. Allyl chloride 0.20 10.000 --- U --- U --- U --- U U 5o, chloroprene 0.21 20.000 --- U --- U --- U --- V --- U 51, 1,3-Dichlorobenzene 0.41 5.000 --- U --- U --- U --- U --- U 52. Dichlorodifluoromethane 0.51 5,000 --- U --- U --- U --- U --- U 53. 1,3-Dichloropropane 0.20 1.000 --- U --- U --- U --- U --- U 54. 2,2-Dichloropropane 0.17 15,000 --- U --- U --- U --- U --- U 55, 1,1-Dichloropropane 0,22 5.000 --- U --- U --- V --- U .-- U 56. Bthyl Methacrylate 0.16 10,000 --- U --- U --- U --- U --- U 57. Hexachlorobutadiene 0.10 0.200 --- U --- U --- U --- U --- V 58. Isobutyl Alcohol 12.80 100.000 --- U --- U --- U --- V --- V 59. Methacrylonitrile 1.93 100.000 --- U --- U --- U --- U --- U 60. Methyl Methacrylate 0.25 30.000 --- U --- U --- U --- U --- U 61, Naphthalene 0,47 6.000 --- U --- U --- U --- U --- U 62. Propionitrile 3,26 150.000 --- U --- U --- U --- U --- U 63. 1,2,4-Trichlorobenzane 0.50 10.000 --- U --- U --- U --- U --- U 64. Acetonitrile 36.29 55.000 --- U --- U --- U --- U --- U 65. Tetrahydrofuran 0.39 1.000 0.62 J 43.30 3.94 0.51 1 26.60 66. 1,4-Dioxane 2.71 3.000 --- U --- U 11.90 --- U 176.00 J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limita. EnArmu(M % hmpuMNA Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: CUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 A ANALYST; JAP DATE COLLECTED: 06/12/19 Page: 3 DATE REPORTED: 08/08/19 PARAMETERS, Ug/l Data Analyzed MDL MRL 06/24/19 MW-3D 06/24/19 MW-3A 06/24/l9 Trip Blank 1, Chloromethane 0.77 3.000 1.97 J --- U --- U 2, Vinyl Chloride 0.12 0.200 --- U --- U --- U 3. Bremomethane 0.67 20.000 --- U -" U --- U 4. Chloroethane 0.48 10.000 --- U --- U --- U 5. Trichlorofluoromethane 0,24 1.000 --- U --- U --- U 6, 1,1-Dichloroethene 0.17 5,000 --- U --- U --- U 7. Acetone 9106 100.000 --- U --- U --- U B. lodomethane 0.26 10.000 --- U --- U --- U 9, carbon Disulfide 0.23 100.000 --- U --- U --- U 10. Methylene Chloride 0.64 1.000 --- V --- U --- U 11, trans-1,2-Diehloroethene 0.23 5.000 --- U --- U __.. U 12. 1,1-Dichloroathane 0.20 5.000 --- U --- U '-- U 13. Vinyl Acetate 0.20 50.000 --- U --- V --- U 14, Cis-1,2-Dichloroathene 0.25 5.000 --- U --- U --- U 15. 2-Butanone 2.21 100.000 --- U --- U --- U 16. Bromochloromethane 0.27 3.000 --- U --- U --- U 17. Chloroform 0.25 5.000 --- U --- U --- U 18. 1,1,1-Trichloroethane 0.19 1.000 --- U --- U --- U 19. Carbon Tetrachloride 0.04 0.200 --- U --- V '"' U 20, Benzene 0.24 1.000 --- U 1.00 --- U 21, 1,2-]Aichloroethane 0.02 0,200 --- U 0.13 J --- U 22, Trichloroethene 0.23 11000 --- U --- U --- U 23. 1,2-Dichloropropene 0.04 0.200 --- U --- U --- U 24. Bromodichloromethane 0,04 0.200 --- U --- U --- U 25. Cie-1,3-Dichloropropene 0.06 0,200 --- U --- U --- U 26. 4-Methyl-2-Pentanone 1,19 100,OOD --- U --- U --- U 27, Toluene 0.23 1.000 --- V --- V --- U 2S. trane-1,3-Dichloropropene 0.04 0.200 --- U --- U --- U 29. 1,1,2-Trichloroethane 0.03 0,200 --- U --- U --- U 30, Tetrachloroethane 0.10 0.200 --- U --- U --- U 31. 2-Hexanone 1.57 50.000 --- U --- U --- U 32. Dibromachloromethane 0.03 0.200 --- U --- U --- U 33. 1,2-Dibromoethane 0.03 0.200 --- U --- U .-- U 34. Chlorobenzene 0,3o 3.000 --- U --- U --- U 35, 1,1,1,2-Tetrachloroethane 0.22 1.000 --- U --- U --- U 36, Ethylbenzene 0,21 1.000 --- U --- U --- U 37. Xylenea 0.68 5.000 --- U --- U --- U 38. Dibromomethane 0.29 10.000 --- U --- U V 39, Styrene 0.19 1.000 --- U --- U U 40. Bromoform 0.20 3.000 --- U --- U --- U 41. 1,1,2,2-Tetrachloroethane 0.03 0.200 --- U --- U --- U 42. 1,2,3-Trichloropropane 0.09 0.200 --- V --- U --- U 43, 1,4-Dichlorobenzene 0.39 1.000 --- U --- U --- U 44, 1,2-Dichlorobenzene 0.32 5.000 --- U --- U --- U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U --- U _-- U 46. Acrylonitrile 2.72 200.000 --- U --- U --- U 47. trana-1,4-Dichloro-2-Butane 0.42 100.000 --- U --- Ti --- U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits, Efiw'mflaW % hmpudod Drinking Water 1Di 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 A ANALYST: J'AP DATE COLLECTED: 06/12/19 Page: 4 DATE REPORTED: 08/08/19 PARAMETERS, ug/1 Date MDL Analyzed MRL 06/24/19 MW-3D 06/24/19 MW-3A 06/24/19 Trip Blank 48. Acrolein 1.97 4,000 --- U --- U --- U 49, A11yl chloride 0.20 10.000 --- U --- U --- U 50. Chloroprene 0,21 20.000 --- U --- U --- U 51. 1,3-Dichlorobenzene 0.41 5.000 --- U --- U --- U 52. Dichlorodifluoromethane 0.51 5.000 --- U --- U --- U 53. 1,3-Dichloropropane 0.28 1.000 --- U --- U --' U 54, 2,2-Dichloropropane 0.17 15.000 --- U --- U --- U 55. 1,1-Dichloropropene, 0.22 5,000 --- U --- U --- U 56. Ethyl Methacrylate 0.16 10.000 --- U --- U --- U 57. Rexachlorobutadione 0.10 0.200 --- U --- U --- U 58, lsabutyl Alcohol 12.80 100,000 --- U --- U --- U 59. Methacrylonitrile 1.93 100.000 --- U --- U --- U 60, Methyl Methacrylate 0,25 30.000 --- U --- U --- U 61, Naphthalene 0.47 6.000 --- U --- V --- U 62. Propionitrile 3.26 150,000 --- U --- U --- U 63, 1,2,4-Trichlorobenzene 0.50 10.000 --- U --- U --- V 64. Acetonitrile 36.29 55.000 --- U --- U --- U 65. Tetrahydrofuran Q,39 1.000 0.52 J 8.44 --- U 66. 1,4-Dioxane 2.71 3.000 --- U 66.90 -- u J n Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. ,n 4 � 1pill `+" T� w fi g F ooz � d E 0 1Es �J �1? Al + hl} 1 -4 a in o c o a m m rn c cu co � O tD a 10 w V 0 w ao V mFY 3 IF, m TOTAL CHLORINE, M9A OR ugA AT COLLECTION TEMPERAiURE,°C ATCOLLECTION A QF CONTAINERS a QFm © 0 n` 8 0 Li COD Z m C Z �v cn mrri M.z �;z z rn n, a rn op o o O0-no p• i rn w w Li G L LJ . TOC n AWalinity is `b Chloride 'v Cyanide tv 'b Hardness n w TDS > Sulfate b Metals b Sulfide conductivity 'b Do Temperature d PARAMEIERSTfE STS 7R 0 #Q O m m Q T 0 _ r I� 0 o n C3 cb m m U3 � o r+ b 10 �g o �OOx b pill p �. 0 0 0 !t7' O7 CA m s TOTAL CHLORINE; mgn Q OR ugh AT COLLECTION TEMPERMRE,°C AT COLLECTION # OF CONTAINERS CD c-) � � D 4 �-n���� �o QP 1�1 z n o A m 8081E 8260D App. U 8260 App..11 1 8260 App.11 2 8260 App.11 3' 8260 App..11 4 8151A Landfill 8151A Duplicafi ORP o :" �. Z .bd t y ck Nt4 C9 �i $ n•�^�. nnon a a w t4 � o all Lj U U L O °z 0 PAAAMETERMESTS � r0 pp m rA a T z 9 n n A 17 � � g ElmdomMEW Flo howpumUd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PARAMETERS MDL PH {field measurement), Unite BOD, mg/l 2.0 COD, mg/1 0.840 Nitrate Nitrogen as N, mg/1 0.009 Total Organic Carbon, mg/1 0.129 Alkalinity (to pH 4.5), mg CaCO3/1 1.0 Chloride, mg/l 5.0 Cyanide, ug/1 5.0 Total Hardness, mg/l Total Dissolved Residue, mg/1 1.0 Total Dissolved Residue, mg/l 1.0 Sulfate, mg/l 5.0 Antimony, ug/l 0.03 Antimony, ug/l 0.01 Arsenic, Ug/l 0.42 Arsenic, ug/1 0.42 Arsenic, ug/1 0.42 Barium, ug/1 0.03 Barium, ug/l 0.03 Beryllium, ug/l 0.05 Beryllium, ug/l 0.05 Cadmium, ug/1 0.02 Cadmium, ug/l 0,02 Cobalt, ug/1 0.03 Cobalt, ug/l 0.03 Total Chromium, ug/1 0115 Total Chromium, ug/1 0.15 copper, ug/1 D.03 Copper, ug/1 0.03 iron, ug/1 4.96 Iron, ug/1 4.96 Manganese, ug/l 0.32 Manganese, ug/l 0.31 Lead, ug/1 0.03 Lead, ug/1 0.03 Mercury, ug/1 0.05 Nickel, ug/l 0.03 Nickel, ug/1 0.03 Selenium, ug/1 0.53 Selenium, ug/1 0.53 Selenium, ug/1 0.53 Silver, ug/1 0.05 Silver, ug/1 D.05 MW-9A MRL PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 B DATE COLLECTED: 06/18/19 DATE REPORTED : 08/08/19 REVIEWED BY. MW-10 MW-11 MW-13 MW-12s Analysis Method 6.7 6.3 6.8 6.2 2,0 --- U 11 --- U --- U 20.0 22 276 67 55 0.04 --- U --- U --- U 0.46 1.0 4,96 106.3 26.76 22.32 1.0 196 1340 528 232 5.0 11 77 36 14 5.0 --- U --- U --- U --- U 267 1120 659 263 10 366 1780 902 409 10 5.0 105 171 204 7.2 IA --- U 0.21 J 1.0 0,03 J 0.10 J 5.0 --- U 9 5,0 5.5 2.3 J 5.0 10.0 47,7 321 10.0 72.2 45.8 1.0 --- U 0.12 J 1.0 0.22 J 0.06 J 1.0 --- U 0.11 J 1.0 0.12 J 0.05 J 1.0 0.11 J 1.9 1.0 0.90J 0.75J 5.0 --- U 19 5,0 0.77 J 0.30 J 10.0 0. 84 J 0. go J 10.0 0.31 J 0.56 J 50.0 2527 151 19952 5680 50.0 10.0 113 158 244 59 10.0 5.0 --- U --- U 5.0 --- U 0.11 J 0.20 --- U --- U --- U --- U 10.0 1.7 J 9.3 J 10.0 3,81 2.2J 10,0 0.35J 4.1J 10 , 0 1. 2 J 0.73 J 10,0 5.0 - -- U - -- U 5.0 - -- U --- U J = Estimated value between the MDL and MRL, U = Below ALL 4uantitation Limits. Date Analyst Code 6.6 06/18/19 SEB 4500HB-11 8.5 06/19/19 JTH 5210E-11 620 06/21/19 SEJ H8000-79 --- U 06/19/19 BID 353.2 R2-9 220 06/24/19 SEJ 531OC-11 1730 06/24/19 TCW 232OB-11 260 06/24/19 JTH 45000LB-11 --- U 06/26/19 SEJ 450OCNE-11 749 06/24/19 TCW 2340C-11 06/20/19 MAR 254OC-11 2150 06/25/19 KDS 254OC-11 111 06/19/19 SECT 4$00SO42E1 2.9 07/18/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 D7/18/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 54 00/07/19 MTM 3113E-10 759 07/18/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 0.08 J 07/10/19 LFJ SPA200.0 06/21/19 LFJ EPA200.8 --- U 07/10/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 3.2 07/10/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 55 07/18/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 2.5 J 07/18/19 LFJ EPA200.8 06/21/19 LFJ EPA200.8 07/01/19 LFJ EPA200.7 2164 07/03/19 LFJ EPA200.7 07/01/19 LFJ EPA200.7 511 07/03/19 LFJ EPA200.7 --- U 07/18/19 LPJ EPA200.8 06/21/19 LFJ EPA200.8 --- U 07/15/19 MTM 245.1 R3-9 9.1J 07/28/19 LFJ EPA200.8 06/22/19 LFJ BPA200,8 07/10/19 LFJ EPA200.8 06/21/19 LFJ EPA200,9 1 J 08/07/19 MTM 3113E-10 --- U 07/18/19 LFJ EPA200.6 06/24/19 LFJ EPA200.8 Drinking water ID: 37715 m.pr. Arar Tn. in 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 B 3UDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/18/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 08/08/19 DURHAM ,NC 27703 REVIEWED BY: Z� MW-9A KW-10 MW-11 MW-13 MW-12e Analysis Method PARAMETERS MDL MRL Date Analyst Code Thallium, u9/1 0.05 1.0 --- U 0.18 J 0.07 J 07/18/19 LPJ EPA200.8 Thallium, ug/l 0.05 1.0 --- U 0.12 J 06/21/19 LFJ EPA200.8 Tin, ug/1 0,05 100,0 --- U --- U --- U --- U --- U 07/29/19 LFJ EPA200.8 Vanadium, ug/l 0.03 1.0 0.54 J 9.5 40 07/29/19 LFJ EPA200.B Vanadium, ug/l D.03 1.0 3.2 1.5 06/21/19 LFJ EPA200.8 zinc, ug/l 0.11 10.0 4.2 J 2.7 J 4.4 J 07/18/19 LFJ EPA200.8 Zinc, ug/l 0.11 10.0 6.0 J 4.7 J 06/21/19 LFJ EPA200.8 Sulfide, ug/1 100 1000 --- U 849 J --- U --- U --- U 06/25/19 LFJ 450092D-11 Conductivity (at 25c), uMhos/cm 1.0 1.0 556 2803 1010 516 4190 06/18/19 SEB 2510E-11 Dissolved Oxygen, mg/l 0.1 0.1 0.67 3.41 0.62 1.22 1.03 06/18/19 SEB 45000G-11 Temperature, °C 23 22 26 24 26 06/18/19 SEB 2550E-10 Static Water Level, feet 6.54 3.79 4.54 8.48 4.72 06/18/19 SEB Well Depth, feet 23.17 22.73 23.84 20,68 22.93 06/10/19 SEB Carbon Dioxide, mg/1 1.0 1.0 48 408 246 462 151 06/18/15 KDS 45000O2C-1 ORF, my +122 -158 -52 +15 -50 06/18/19 SEB 2580B Turbidity (Field), NTU 2.0 1.0 7.67 5.68 5.80 8.44 6.28 06/18/19 SEB 213OB-11 J n Estimated value between the M➢L and MRL, U = Below ALL Quantitation Limits. ENnhERM Ala hcupamUd Drinking Water ID: 37715 114 OAKNIONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/18/19 DURHAM, NC 27703 DATE EXTRACTED: 06/21/19 DATE ANALYZED: 07/30/19 REVIEWED BY: DATE REPORTED: 08/08/19 PESTICIDES AND PCB'S EPA METHOD 8081E R2(07) PARAMETERS, ug/l MDL MRL KW-9A MW-10 MW-11 MW-13 MW-12e 1. Aldrin 0,029 0.050 --- U --- U --- U --- V --- U 2, Alpha-BHC 0.032 0.050 --- U --- U --- U --- U --- U 3, Beta-BHC 0.031 0,050 --- U --- U --- U --- U 0.06E 4. Delta-BHC 0.030 0.050 --- U --- U --- U --- U --- U 5. Gamma-BHC {Lindane) 0.032 0.050 --- D --- v --- U --- U --- U 6, Chlordane 0.320 0.500 --- U --- V --- U -- U --- U 7. 4,4-DDD 0.051 0.100 --- U --- U --- U --- U --- V 8. 4,4-DDE 0.049 4.100 --- U --- U --- U --- U --- U 9. 4,4-DDT 0.052 0.100 --- U --- U --- U --- U --- U 10. Dieldrin 0.042 0.075 --- U --- U --- U --- U --- U 11. EndoeulEan I 0.056 0.100 --- U --- U --- U --- U --- U 12, EndoeulEan II 0.046 0.100 --- U --- U --- U --- U --- U 13, Endoeulfan Sulfate 0.072 0.100 --- U --- U --- U --- U --- U 14. Endrin 0.053 01100 --- U --- U --- U --- U --- U 15. Endrin Aldehyde 0.06E 0.100 --- V --- U --- U --- U --- U 16. Heptachlor 0.039 0.050 --- U --- U --- U --- U --- U 17. Heptachlor Epoxide 0.042 0.075 --- U --- U --- U --- V --- U 18. Methoxychlor 0,530 1.000 --- U --- U --- U --- V --- U 19. Pcble (Araclors) 0,500 2.000 --- U --- U --- U --- V --- U 20. Toxaphene 0,690 1.500 --- U --- U --- U --- U --- U .T = Estimated value between the MDL and MRL, V = Below ALL Quantitation Limits. NuAff @RUM alp bw pff V@d Drinking Water ZDs 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/18/19 DURHAM, NC 27703 DATE EXTRACTED: 06/20/19 DATE REPORTED: 08/08/19 REVIEWED BY: - LANDFILL APPENDIX II EPA METHOD 8151A R1(96) Data Analyzed 07/01/19 07/01/19 07/01/19 07/02/19 07/01/19 MW-9A MW-10 MW-11 MW-13 MW-12s PARAMETERS, u9/1 MDL MRL 1. 2,4-1) 0.36 2,000 --- U --- U --- U --- U --- U 2. Dinoaeb 0.54 1.000 --- U --- U --- U --- U --- U 3. 2,4,5-TP 0.42 2.000 --- U --- U --- U --- v --- U 4. 2,4,5-T 0.47 2.000 --- U --- U --- U --- U --- U J A Estimated value between the MDL and MRL, U - Below ALL Quantitation Limits. mlow,mmmW 1, hmpumbd Drinking Water ID; 37715 114 OAKMONT ©RIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/18/19 Page: 1 DURHAM, N 27703 DATE EXTRACTED: 06/24/19 DATE ANALYZED: 07/03/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l MDL MRL MW-9A MW-10 MW-11 MW-13 MW-12s 1. Acenaphthene 2.66 10.000 --- U --- U --- U --- U --- U 2. Acenaphthylene 2.60 10,000 --- U --- U --- U --- U --- U 3, Anthracene 2.97 10,000 --- V --- U --- U --- U --- U 4. Benzota]antrhacene 4.16 10.000 --- U --- U --- U --- U --- U 5. Benzo[b]fluoranthene 3.32 10.000 --- U --- U --- U --- U --- U 6. Benzo[k]fluoranthene 4.23 1D.000 --- U --- U --- U --- U --- U 7. Benzo[g,h,i]perylene 2.61 10.000 --- U --- U --- U --- U --- U 8, Benzc[a]pyrene 3.27 10,000 --- U --- U --- U --- U --- U 9. 4-Bromophenyl Phenyl Ether 2.63 10,000 --- U --- U --- U --- U --- U 10, Butyl Benzyl Phthalate 5.79 10,000 --- U --- U --- U --- U --- U 11. Bie(2-Chloroethoxy) Methane 3.14 10.000 --- U --- U --- U --- U --- U 12. Bia(2-Chloroethyl) Ether 2.58 10.000 --- U --- U --- U --- U --- U 13. Bis(2-Chloro-l-methylethyl) Ether 2.5B 10.000 --- U --- U --- U --- U --- U 14. 2-Chloronaphthalene 2.17 10,Goo --- U --- U --- U --- U --- U 15. 4-Chlorophenyl Phenyl Ether 2.42 10,DD0 --- U --- U --- U --- U --- U 16, Chryaene 4.04 10.000 --- U --- U --- U --- U --- U 17. Dibenzo[a,h]anthracene 2,70 10.DD0 --- U --- V --- U --- U --- U 10, Di-N-Butyl Phthalate 3.09 10,000 --- U --- U --- U --- U --- U 19. Dimethyl Phthalate 3.78 10.000 --- U --- U --- U --- U --- U 20. Diethyl Phthalate 3.92 10.000 --- U --- U --- U --- U --- U 21. 2,4-Dinitrotoluene 3,95 10,000 --- U --- U --- U --- V --- U 22. 2,6-Dinitrotoluene 3.88 10.000 --- U --- U --- U --- U --- U 23. Di-N-Octyl Phthalate 2,81 10.000 --- U --- U --- U --- U --- U 24. Bis-(2-13thylhexyl) Phthalate 9.97 15.000 --- U --- 11 --- U --- U --- U 25, Fluoranthene 3.92 10,000 --- U --- U --- U --- U --- U 26. Fluorene 2.95 10.000 --- U --- U --- U --- U --- U 27. Hexachlorobenzene 2.61 10.000 --- U --- U --- U --- U --- U 28. Hexachlorocyclopentadiene 4,16 10.000 --- U --- U --- U --- U --- U 29, Indeno[1,2,3-Cd]pyrene 2191 10.000 --- U --- U --- U --- U --- U 30. Isophorone. 3.74 10.000 --- U --- U --- U --- U --- U 31, Nitrobenzene 2.85 10,000 --- U --- U --- U --- U --- U 32. N-Nitr000dimethylamine 4.25 10.000 --- U --- U --- U --- U --- U 33. N-Nitrosodiphenylamine 3.95 10,000 --- U --- U --- U --- U --- U 34. N-Nitroeodi-N-Propylamine 4.06 10.000 --- U --- U --- U --- U --- U 35. Phenanthrene 3.24 10.000 --- U --- U --- U --- U --- U 36. Pyrene 3.63 10.000 --- U --- U U --- U --- U 37. 4-Chloro-3-Methylphenol 3.79 20.000 --- U --- U --- U --- U --- U 38. 2-Chlorophenol 2,75 10.000 --- U --- U --- U --- U --- U 39, D-Cresol 3.68 10.000 --- U --- U --- U --- U --- U 40. P-Cresol 4,12 10.000 --- U --- U --- U --- U --- U 41, 2,4-Dichlorophenol 5.19 1D.000 --- U --- U --- U --- U --- U 42. 2,6-Dichlorophenol 4.89 10.000 --- U --- U --- U --- V --- U 43. 2,4-Dimethylphenol 3.21 10.000 --- U --- U --- U --- U --- U 44. 4,6-Dinitro-2-Methylphenol 4.77 50.000 --- U --- U --- U --- U --- U 45. 2,4-Dinitrophenol 4.37 50.000 --- U --- U --- U --- U --- U 46, Ethyl Mathanesulfonate 5.26 20.000 --- U --- U --- U --- U --- V 47. Methyl Methaneeulfonate 4.92 10.000 --- U --- U --- U --- U --- U 48. 2-Nitrophenol 3,64 10.000 --- U --- U --- U --- U --- V J = Eatimated value between the MDL and MRL, U - Below ALL Quantitation Limits, Emwokomm@M % hCupumho Drinking Water IDs 37715 114 OAKMONT DRIVE GREENVILLE, N.C, 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER. ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/18/19 Page: 2 DURHAM, NC 27703 DATE EXTRACTED: 06/24/19 DATE ANALYZED: 07/03/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l MDL MRL MW-9A MW-10 MW-11 KW-13 MW-12s 49. 4-Nitrophenol 3.17 50.000 --- U --- U --- U --- U --- U 50. Pentachlorophenol 5.33 25,DD0 --- U --- U --- U I --- U --- U 51. Phenol 1.86 10.000 --- U --- U _-- U --- V --- U 52. 2,3,4,6-Tetrachlorophenol 3,12 10.000 --- U --- U --- U --- U --- U 53. 2,4,5-Trichlorophenol 4.17 10.000 --- O --- U --- U --- U --- U 54. 2,4,6-Trichlorophenal 3.94 10.000 --- U --- U --- V --- U --- U 55, Acetophenone 2.89 10.000 --- U --- U --- U --- U --- U 56. 2-Acetylaminofluorene 3.96 20.000 --- U --- U --- U --- U --- V 57. 4-Aminobiphenyl 4.12 20,000 --- U --- U --- U --- U --- U 58, Benzyl Alcohol 4.47 20,000 --- U --- U --- U --- a --- U 59, 4-Chloroaniline 3.36 20.000 --- U --- U --- U --- U --- U 6D. Chlorobenzilate 5.12 10.000 --- U --- U --- U --- U --- U 61, Diallate 2.98 10.000 --- U ^-- U --- U '-' U --- U 62. Dibenzofuran 4.28 10.000 --- U --- U --- U --- U --- U 63. 3,3-Dichlorobenzidine 4.22 20.000 --- U --- V --- U --- U --- U 64. Dimethoate 3.90 20.000 --- U --- U --- U --- U --^ U 65. P-Dimethylaminoazobenzene 2.89 10.000 --- U --- U --- U --- U --- U 66. 7,12-Dimethylbenz[a]anthracene 5.26 10.000 --- U --- U --- U --- U --- U 67. 3,3-Dimethylbenzadine 3.21 10.000 --- V --- U --- U --- U --- U 68, 1,3-1)lnitrobenzene 2.09 20.000 --- U --- U --- U --- U --- V 69, Diphenylamine 5.10 10.DD0 --- U --- U --- U --- U --- U 70. Diaulfoton 4.26 10.000 --- U --- U --- U --- U --- U 71. ramphur 3.99 20.000 --- U --- U --- U --- U --- U 72, Hexachloropropene 4.31 10.000 --- U --- U --- U --- U --- U 73. Isosafrole 2.BB 10.000 --- V --- U --- U --- U --- U 74, Kepone 2.78 20,000 --- U --- U --- U --- U --- U 75. Methapyrilene 3.54 100.000 --- U --- U --- U --- U --- U 76, 3-Methylchloroanthrens 4.21 10.000 --- U U --- U --- U --- U 77. 2-Methylnaphthalene 3,79 10.000 --- U --- U --- U --- U --- U 76, Methyl Parathion 4.32 20,000 --- U --- U --- U --- U --- U 79. m-Cresol 3.81 10,D00 --- U --- U --- U --- U --- U 80. 1,4-Naphthoquinone 4.00 10.000 --- U --- U --- U --- U --- U H1, 1-Naphthylamine 5.61 10.000 --- U --- U --- U --- U --- U 82. 2-Naphthylamine 4.62 10.000 --- U --- V --- U --- U '-- U 03, 2-Nitroaniline 3.61 50.000 --- U --- U --- U --- U "' U 04. 3-Nitroaniline 4.91 50.000 --- U --- U --- U --- U --' U 85, 4-Nitroaniline 4.22 20,000 --- U --- U --- U --- U --- U 86. 5-Nitro-O-Toluidine 4.01 10.000 --- ❑ --- U --- U --- V --- U 87. N-Nitrosadi-n-butylamine 3.63 10.000 --- U --- U --- U --- U --- U BB. N-Nitrosodiethylamine 1,83 20.000 --- U --- U --- U --- U --- V 89, N-Nitrosomethylethylamine 3.83 10.000 --- U --- U --- U --- U --- U 90. N-Nitrosopiparidine -9,19 2D.000 --- U --- U --- U --- U --- U 91, N-Nitrosopyrrolidine 2.89 10.D00 --- U --- U --- U --- U --- U 92. Parathion 3,12 10.DDD --- U --- U --- U --- U --- U 93, Pentachlorobenzene 3.92 10,000 --- U --- U --- U --- U --- U 94, Pentachlorohitrobenzene 3.71 20,000 --- U --- U --- U --- U --- U 95. Phenacetin 4.41 20.000 --- U --- U --- U --- U --- U 96. 1,4 Benzenediamine 2.99 3.0.000 --- U --- U --- U --- U --- U a = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EfiW'5mDH(@M Ala hmpumbd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C, 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/18/19 Page: 3 DURHAM, NC 27703 DATE EXTRACTED: 06/24/19 DATE ANALYZED: 07/03/19 REVIEWED BY: DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS F.PA METROn 8270E R6(18) PARAMETERS, ug/1 MDL MRL MW-9A MW-10 MW-11 MW-13 MW-12e 97. Phonate 3.06 10.000 --- U --- U --- U --- U --- U 98. Pronamide 3.69 10.000 --- U --- V --- U --- U --- U 99. Safrole 4.12 10.000 --- U --- U --- U --- U --- U 100, 1,2,4,5-Tetrachlorobenzene 5.01 10.000 --- U --- U --- U --- U --- U 101. Thionazin 4.62 20.000 --- U --- U --- U --- U --" U 102, 0-Toluidine 4.11 10.000 --- i] --- U --- U --- U --- U 103. 1,3,5-Trinitrobenzene 3.98 10.000 --- U --- U --- U --- U --- U 104. 0,0,0-Triethyl Phoophorothioate 3.61 10.000 --- U --- U --- U --- U --- U 105. Hexachloroethane 1.49 10.000 --- U --- U --- U --- U --- U 106. Isodrin 3.11 20,000 --- U --- U --- U --- U --- U J = 68timatod value between the MDL and MEL, U = Below ALL Vuantitation Limits. EWOT(mmEsma % hmpTOW Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) DNE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 B ANALYST: JAP DATE COLLECTED; 06/18/19 Page: 1 DATE REPORTED: 08/08/19 PARAMETERS, ug/l Date Analyzed MDL MRL 06/25/19 taw-9A 06/25/19 KW-10 06/25/19 MW-11 06/25/19 MW-13 06/24/19 NW-12s 1, Chloromethane 0.77 3.000 --- U --- U --- U --- U --- U 2. Vinyl Chloride 0.12 0.200 --- U 1.17 0.69 --- U 3.33 3. Bromomethane 0.67 10.000 --- U --- U --- U --- U --- U 4, Chloroethane 0.48 10.000 --- U "' U --- U --- U "-- U 5. Trichloroflucromethane 0,24 1.000 --- U --- U --- U --- U --- U 6. 1,1-Dichloroethene 0.17 5.000 --- U --- U --- U --- U -" U 7. Acetone 9,06 100,000 --- U --- U --- U --- U 12.60 J 8, Iodomethane 0.26 10.000 --- U --- U -" U --- U --- U 9. Carbon Disulfide 0.23 100.000 --- U --- U --- U --- U --- U lo. Methylene Chloride 0,64 1.000 --- U --- U --- U --- U --- U 11. trans-1,2-Dichloroethene 0.23 5.000 --- U --- U --- U --- U --- U 12. 1,1-Dichloroethene 0.20 5.000 --- U 0.40 J --- U --- U --- U 13. Vinyl Acetate 0.20 50.000 --- U --- U --- U --- U - U 14, cis-1,2-nichloroethene 0.25 5.000 --- U 0.35 J --- U --- U 0.40 J 15. 2-Butanone 2.21 100,000 --- U --- U --- U --- U --- U 16. Bromochloromethane 0.27 3.000 -»- U --- U --- U --- U --- U 27. Chloroform 0.25 5.000 --- U --- U --- U --- U --- U 18, 1,1,1-Trichloroethane 0.19 1,000 --- U --- U --- U U --- U 19. Carbon Tetrachloride 0.04 0.200 --- U --- U --- U --- U --- U 20. Benzene 0.24 1.000 --- U 2.26 1.89 --- U 2.52 21. 1,2-Dichloroethene O.D2 0.200 --- U 0.40 0118 J --- U 0119 J 22, Trichloroethane 0.23 1.000 --- U --- U --- U --- U --- U 23. 1,2-Dichloropropane 0.04 0.200 --- U 0.26 0.08 J --- U 0.11 J 24. Brcmodichloromethane 0.04 0.200 --- U --- U --- U --- U --- U 25, Cis-1,3-Dichloropropene 0.06 0.200 --- U --- U --- U --- U --- U 26. 4-Methyl-2-Pentanone 1.19 100.000 --- U --- U --- U --- U --- U 27, Toluene 0.23 1.000 --- U --- U --- U --- U 0.46 J 28. trans-1,3-Dichloropropene 0.04 0.200 --- U --- U --- U --- U --- U 29. 1,1,2-Trichloroethane 0.03 0.200 --- U --- U --- U --- U --- U 30. Tetrachloroethene 0.10 0.200 --- U --- U --- U --- U --- U 31, 2-Hexanone 1.57 50.000 --- U --- U _-- U --- U --- U 32. Dibromoohloromethane 0.03 0.200 --- v --- U --- u --- U --- v 33, 1,2-Dibromoethane 0.03 0.200 --- U --- U --- U --- U --- U 34, Chlorobenzene 0.30 3.000 --- U »-- U --- U --- U --- U 35, 1,1,1,2-Tetrachloroethene 0,22 1.000 --- U --- U --- U --- U --- U 36. Ethylbenzene 0.21 1.000 --- U 0,36 J --- U --- U 0.22 J 37, xylenes 0.68 5.000 --- U --- U --- U --- U --- U 38. Dibromomethane 0.28 10.000 --- U --- U --- U --- U --- U 39. Styrene 0.19 1.000 --- U --- U --- U --- U --- U 40. Bromofarm 0,20 3.000 --- U --- U U --- U --- U 42, 1,1,2,2-Tetrachloroethans 0.03 0.200 --- U --- U --- U --- U --- U 42, 1,2,3-Trichloropropane 0,09 0.200 --- U --- U --- U --- U --- U 43, 1,4-Dichlorobenzene 0.39 1.000 --- U --- U --- U --- U 0.57 J 44. 1,2-Dichlorobenzene 0.32 5,000 --- U --- U --- U --- U --- V 45. 1,2-Dibromo-3-Chloropropane 0,07 0.200 --- U --- U --- U --- U --- U 46. Acrylonitrile 2.72 200.000 --- U --- U --- U --- U --- U 47, trans-1,4-Dichloro^2-Butene 0.42 100.000 --- U --- U --- U --- U --» U J = Estimated Value between the MDL and MRL, U - Below ALL Quantitation Limits. Enw,ummoM 1, diumpumbd Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVIL.L.E, N.C. 27858 CLIENT: JUD SON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 H ANALYST: JAP DATE COLLECTED: 06/18/19 Page: 2 DATE REPORTED: 08/08/19 Date Analyzed 06/25/19 06/25/19 06/25/19 06/25/19 06/24/19 MW-9A MW-10 MW-11 MW-13 NW- 12a PARAMETERS, ug/1 MDL MRL 40. Acrolein 1.97 4.000 --- U --- u --- u --- U --- U 49. Allyl Chloride 0.20 10.000 --- U --- u --- u --- u --- U 50. Chloroprene 0.21 20.000 --- U --- u --- U --- u --- u 51, 1,3-Dichlorobenzene 0.41 5.000 --- U --- a --- u --- u --- U 52. Dichlorodifluoromethane 0.51 5.00o --- U --- u --- u --- U --- u 53, 1,3-Dichloropropane 0.28 1.000 --- u --- u --- U --- U --- U 54, 2,2-Dichloropropane 0.17 15.000 --- u --- u --- u --- u --- u 55. 1,1-Dichloropropane 0.22 5.000 --- U --- u --- a --- U --- u 56. Ethyl Methacrylate 0.16 10.000 --- u --- D --- u --- u --- u 57, Hexachlorobutadiene 0.10 0.200 --- U --- U --- u --- u --- u 58, Isobutyl Alcohol 12.80 100,000 --- U --- u --- u --- u --- u 59. Mathacrylonitrile 1,93 100.000 --- u --- u --- U --- u --- u 60. Methyl Methacrylate 0.25 30.000 --- u --- u --- u --- u --- u 61. Naphthalene 0.47 6.000 --- a 1.14 J --- u --- U 0.94 J 62. Propionitrile 3.26 150.000 --- u --- U --- u --- u --- u 63. 1,2,4-Trichlorobenzene 0.50 10.000 --- u --- U --- U --- U --- u 64, Acetonitrile 36.29 55.000 --- U --- u --- u --- u --- U 65. Tetrahydrofuran 0.39 1.000 0.67 1 29.00 17.30 1.47 64.90 66, 1,4-Dioxane 2.71 3.000 --- U 10.70 9.21 --- u 32.B0 J = Eatimated value between the MDL and MRL, U = 9elow ALL Ruantitation Limits. Emkmn(M % hmpTOW Drinking water iD: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) )NE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 B ANALYST: JAP DATE COLLECTED: 06/18/19 Page: 3 DATE REPORTED: 08/08/19 PARAMETERS, ug/l Date MDL Analyzed: MRL 06/25/19 Trip Blank 1, Chloromethane 0.77 3.000 --- U 2. Vinyl Chloride 0.12 0.200 --- U 3, Bromomethane 0.67 10.000 --- U 4. Chloroethane 0.48 10.000 --- U 5. Triohlorofluoromethane 0.24 1,000 --- U 6, 1,1-Dichloroethene 0.17 5.000 --- U 7. Acetone 9.06 100.000 --- U B. iodomethane 0,26 10.000 --- U 9. Carbon Disulfide 0.23 100.000 --- U 10. Methylene Chloride 0.64 1.000 --- U 11, trana-1,2-Dichloroethene 0.23 5.000 U 12. 1,1-Dichloroethane 0.20 5,000 --- U 13. Vinyl Acetate 0.20 50.000 --- U 14. Cie-1,2-Dichlaroethene 0.25 5.000 --- U 15. 2-Butanone 2.21 100.000 --- U 16. Bromoehloromethane 0.27 3.000 --- U 17. Chloroform 0.25 5.000 --- U 18, 1,1,1-Trichloroethans 0.19 1.000 --- U 19. Carbon Tetrachloride 0.04 0.200 --- U 20. Benzene 0.24 1.000 --- U 21. 1,2-Dichloroethane 0.02 0.200 --- U 22, Trichloroethene 0.23 1.000 --- U 23. 1,2-Dichloropropane 0.04 0.200 --- U 24. Bromodichloromethane 0.04 0.200 --- U 25. Cie-1,3-Diehlaropropene 0.06 0.200 --- U 26. 4-Methyl-2-Pentanone 1.19 100.000 --- U 27, Toluene 0.23 1.000 --- u 28. trans-1,3-Dichloropropene 0.04 0.200 --- U 29. 1,1,2-Trichloraethane 0.03 0.200 --- U 30. Tetrachloroethane 0.10 0.200 --- U 31. 2-Hexanone 1.57 50.000 --- U 32. Dibromochloramethane 0.03 0.200 --- U 33. 1,2-Dibromoethane 0.03 0,200 --- U 34. Chlorobenzene 0.30 3.000 --- U 35. 1,1,1,2-Tetrachloroethane D.22 1.000 --- U 36. Ethylbenzone 0.21 1.000 --- U 37. %ylenes 0,68 5.000 --- U 38. Dibromomethana 0.28 10,000 --- U 39, Styrene 0.19 1.000 --- U 40. Bromoform 0.20 3.000 --- U 41. 1,1,2,2-Tetrachloroethane 0.03 0.200 --- U 42, 1,2,3-Trichloropropans 0.09 0,200 --- U 43. 1,4-Dichlorobenzene 0.39 1.000 --- U 44. 1,2-Dichlorobenzene 0,32 5,000 --- U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U 46, Acrylonitrile 2.72 200.000 --- U 47. trans-114-Dichloro-2-Butene 0.42 1D0.000 --- U ,7 a Estimated value between the MDL and MRL, U - Below ALL QuantitatiOn Limits, NflW'UT&flH@[W % hwPuMd 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) Drinking Water IDs 37715 wastewax .�D: 10 - PHUINL (252) /5(i-(j2U6 FAX (252) 756-0633 CLIENT ID: 6003 B ANALYST: JAP DATE COLLECTED: 06/18/19 Page: 4 DATE REPORTED: 08/08/19 PARAMETERS, ug/l Date MDL Analyzed! MRL 06/25/19 Trip Blank 48, Acrolein 1.97 4.000 --- V 49. Allyl Chloride 0.20 10.000 --- U 50. Chloroprene 0.21 20.000 --- U 51. 1,3-Dichlorobenzene 0.41 5.000 --- U 52. Dichlorodifluoromathane 0,51 5.000 --- U 53. 1,3-Dichloropropane 0.26 1.000 --- U 54. 2,2-Dichloropropane 0.17 15.000 --- U 55. l,l-Dichloropropene 0.22 5.000 --- U 96. Ethyl Methacrylate 0.16 10.000 --- U 57. Hexachlorobutadiene 0.10 0.200 --- U 58. isobutyl Alcohol 12.80 100.000 --- U 59. Methacrylonitrile 1.93 100.00D --- U 60, Methyl Methacrylate 0.25 30.000 --- U 61. Naphthalene 0.47 6.000 --- U 62. Propionitrile 3.26 150.000 --- U 63. 1,2,4-Trichlorobenzone 0.50 10.000 --- U 64. Acetonitrile 36.29 55.000 --- U 65. Tetrahydrofuran 0.39 1.000 --- U 66, 1,4-Dioxane 2.71 3.000 --- U .T = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. m m 3> m rri c a 0 V) 0 5. v, Ei 0 C CD CD CL p v 07 w � C m m a- w 27- C5 En m o 0 00 C� 0 n3 0 m w � w � 3 m m 0 (D v m m M m m u� b mm ) c C-) 0 m m m mC) 0 < W cn m d m u) b y i r ➢ W n- oo°z Nt " orD :�' Z t rr O �� o D co � ci to cz m a Z� ?J m TOTAL CHLORINE, mg/l C7 OR ug/I AT COLLECTION O n r3 �j 0 )13 TEMPERATURE,°C AT COLLECTION M # OF CONTAINERS O m � cn 11 v n �r ;I m r p C O 7� �� �m 4 U) O o a C -1 �) o p I +� o a c� z z m '04m *>m �. oJ. ^ice c) m m O m ` r C L> p � N M z z u' m C] a Field pH V-, I BOD > b COD Nitrate TOC n Alkalinity > Chloride ;p- b Cyanide Hardness f5 b s 5 TDS > Sulfate > Metals > J Sulfide Conductivity DO Temperature > b PARAMETERS/TESTS n m a n m � m = Z r 3) _ m O O zo m co Q co a 0 „ m a m 1T� Z N n n O O N s z n n O m a o 0 2 i� O 0 0 ro cU m M- t7 w w � is w m a 3 � C C0 CDrn Q v 0 Ci (n m o6 CO O CD D O cf)w @. P3 � w P� B w m m m O — CD m CD 0 n C o ro ro Q Gi W V O c.n co M A h" a r--I r m z z m z r to r O t w np '+ m m 0 m 0 CS m 0 D t6 V7 CfS FDC�11 Cam] t cn oz CD m En � w rt� ati o 0 n 4 O r', o C�ii t' 9J 0 t" Lo o m m w vn TOTAL CHLORINE, mg/l j� U L OR ugll AT COLLECTION m m m m z n Z 0 TEMPERATURE,°C o d O C 7C m 03 pu 'C VS ATCOLLECTION rzn 0 m G7 Ln L,7 �7 0 0 r� z w N OF CONTAINERS 4tiryvn:- ::Q: }'S: <7;1 •i } . Y` i r Field Parameter EPA 8270E G� 8270E Du . 1 Y 4� EPA 8081B > 0 : s;... y.-.'cr ::c'.: s`s :%iii Duplicate 80818 0 n 8260D A II tt 0 C . 8260 App.II 1 b J 8'2 60 App. II G] E m 'c <Y> ' $260 App. II 3 G� :S'-v:.: Ga 8260 App. 11 4 4� t 8151A Landfill Ga 8151A Duplicate 47 J ORP PARAMETERSITESTS n � z � m co 4 4 m �. cn77 o c p {? m r n z n o m . `3 — 0 - T 2 2 z r m 7G m rnn V'O 0Cm O 0 � y 0 O m f! m (lr 4 n i! cn cn Pmi1 =Q o m v G7 T m v m v z �/� o n z T n n N Sa W �• m n N = z z n m >* m n O > cn m z rn > CD c O cmn z z -� F m R M zn o 0 o z c� n x EnwohnHOM % hmpumbd Drinking Water ID! 37715 wastewater ID: 10 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 C JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/13/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 08/08/19 DURHAM ,NC 27703 REVIEWED BY: /.0/-- SW-1 SW-2 SW-3 SW-4 Analysis Method PARAMETERS MDL MRL Date Analyst Code PH (field measurement), Units 6.5 6.9 6.6 6.6 06/13/19 BF 4500HB-11 Antimony, ug/l 0.03 1.0 0.051T 0.05J 0,07 J 0,08 d 06/21/19 LFJ EFA200.8 ArseniC, ug/1 0.03 5.0 1.5J 0.95 a 1.91 1,1J 06/21/19 LFJ EPA200.8 Barium. ug/1 0.03 10.0 76,7 78.2 121 71.5 06/21/19 LFJ EPA200.8 Beryllium, ug/1 0.05 1.0 0.20 J 0.08 J 0.12 J 0,12 J 06/21/19 LFJ EPA200.8 Cadmium, ug/l 0.02 1.0 0.05 J 0.02 J 0.03 J --- U 06/21/19 LFJ EPA200.8 Cobalt, ug/l 0.03 1.0 0.56 J 0.33 J 0.67 J 0,36 J 06/21/19 LFJ EPA200.8 Total Chromium, ug/l 0.15 5.0 5.1 0.74 J 1.7 J 0,72 J 06/21/19 LFJ EPA200.8 capper, ug/l 0.03 10.0 2.2 J 0.62 J 0.96 J 1.1 J 06/21/19 LFJ EPA200.8 Lead, ug/1 0.03 5.0 3,9J 0.63 J 2.5J 1,1J 06/21/19 LFJ EPA2D0.6 Nickel, ug/l 0.03 10.0 1,8J 0.88J 1.6J 0.81,7 06/21/19 LFJ EPA200,8 Selenium, ug/l 0.15 10.0 0.87J 0.45J 0.65J 0,38 J 06/21/19 LFJ EPA200,8 Silver, ug/1 0.05 5.0 --- U --- U --- U --- U 06/24/19 LFJ EPA200.8 Thallium, ug/l 0.05 1.0 --- U --- U --- U --- U 06/21/19 LFJ EPA200.8 Vanadium, ug/1 0.03 1.0 9.4 0.92 J 2.4 3.1 06/21/19 LFJ EPA200.8 Zinc, ug/1 0.11 10.0 13 5.a J 812 J 4.8 J 06/21/19 LFJ EPA200.8 Conductivity (at 25c), uMhos/cm 1.0 1.0 356 314 362 143 06J13/19 BF 2510E-12 Temperature, "C 20 21 23 24 06/13/19 BF 2556B-10 Turbidity (Field), NTU 1.0 1.0 213 6.2 17 24 06/13/19 BF 2130E-11 J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EnAmmml 1, EfimpumUd Drinking Water IDi 37715 114 OAKMONT DRIVE GREENVILLE, N,C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 2,7,703 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4(18) PHONE (252) 756.6208 FAX (252) 756-0633 CLIENT ID: 6003 C ANALYST: JAP DATE COLLECTED: 06/13/19 Page: 1 DATE ANALYZED: 06/24/19 DATE REPORTED: 08/08/19 PARAMETERS, Ug/l MDL MRL 19W-1 SW-2 8W-3 sw-4 1, Chloromethane 0,77 3.000 --- U --- U --- U --- U 2. Vinyl Chloride 0.12 0.200 --- U --- U --- V --- U 3, Bromomethane 0.67 10.000 --- U --- U --- U --- U 4. Chloroethane 0.48 10,000 --- U --- U --- U --- U 5. Trichlorofluoromethane 0.24 1.000 _-- U --- U --- U --- V 6. 1,1-Dichloroethene 0.17 5.000 --- U --- U --- U --- U 7. Acetone 9.06 100.000 --- U --- U --- U --- U 8, Iodomethane 0.26 10.000 --- U --- U --- U --- U 9. Carbon Disulfide 0.23 100.000 --- U --- U --- U --- U 10. Methylene Chloride 0.64 1.000 --- U --- U --- U --- U 11, trans-1,2-Dichloroethene 0.23 5.000 --- U --- U --- U --- U 12. 1,1-Dichloroethane 0.20 5.000 --- U --- U --- U --- U 13. Vinyl Acetate 0.20 50.000 --- U --- U --- U --- U 14. Cis-1,2-Dichloroethene 0,25 51000 --- U --- U --- U --- U 15, 2-Butanone 2.21 100.000 --- U --- U --- U --- U 16. Bromochloromethane 0.27 3,000 --- U --- U --- U '-- U 17. Chloroform 0.25 5,000 --- U --- U --- U --- U 18, 1,1,1-Trichloroethans 0.19 1.000 --- U --- U --- U --- U 19. Carbon Tetrachloride 0.04 0,200 --- U --- U --- U --- U 20. Benzene 0,24 1.000 --- U --- U --- U --- U 21, 1,2-Dichloroethane 0.02 0.200 --- U --- U --- U --- U 22. Trichloroethene 0.23 1.000 --- U --- U --- U --- U 23. 1,2-Dichloropropans 0.04 0,200 --- U --- U --- U --- U 24. Bromodichloromethane 0.04 0.200 --- U --- U --- U --- U 25, Cis-1,3-Dichloropropene 0.06 0.200 --- U --- U --- U --- U 26, 4-Methyl-2-Pentanone 1.19 100.000 --- U --- ll --- U --- U 27. Toluene 0.23 1.000 9.47 --- u --- U --- U 28. trane-1,3-Dichloropropene 0.04 0.200 --- U --- U --- U --- U 29. 1,1,2-Trichloroethane 0.03 0,200 --- U --- U --- U --- U 30, Tetrachlorcethene 0.10 0,200 --- U --- U --- U --- U 31. 2-Hexanone 1.57 40.000 --- U --- U --- U --- U 32, Dibromochloromethane 0.03 0.200 --- U --- U --- U --- U 33. 1,2-Dibromoethane 0.03 0.200 --- U --- V --- U --- V 34. Chlorobenzene 0.30 3.000 --- U --- U - U --- U 35. 1,1,1,2-Tetrachloroethane 0.22 1.000 --- U --- U --- U --- U 36, Ethylbenzene 0.21 1.000 --- U --- U --- U --- U 37. Xylenes 0.68 5.000 --- U --- D --- U --- U 38. Dibromomethane 0.38 10.000 --- U --- ❑ --- U --- U 39, Styrene 0.19 1.000 --- U --- U --- U --- U 40, Bromoform 0,20 3.000 --- U --- U --- U --- U 41, 1,1,2,2-Tetrachloroethane 0.03 0.200 --- U --- U --- U --- U 42, 1,2,3-Trichloropropane 0.09 0.200 --- U --- U --- U --- U 43. 1,4-Dichlorobenzene 0,39 1.000 --- U --- U --- U --- U 44. 1,2-Dichlorobenzene 0.32 5,000 --- U --- U U --- U 45. 1,2-Dibromo-3-Chloropropane 0,07 0.200 --- U --- U --- U --- U 46. Acrylonitrile 2.72 200.000 --- U --- U --- U --- U 47, trans-1,4-Dichlorc-2-Butene 0.42 100.000 --- U --- U --- U --- U 48. Tetrahydrofuran 0,39 1.000 0,73 J 1.10 1.14 0.40 J ,7 = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EIMAnumW % hc@TpwNW Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 C AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/13/19 Page: 2 DURHAM, NC 277 3 DATE ANALYZED: 06/24/19 DATE REPORTED: 08/08/19 REVIEWED BY: F VOLATILE ORGANICS EPA METHOD 8260D R4(18) PARAMETERS, ug/l :4DL MRL SW-1 SW-2 49W-3 SW-4 49. 1,4-Dioxane 2.71 3.000 --- U --- U --- U --- U J = Estimated value between the NDL and MRL, U = Below ALL Quantitation Limits. m 0 t„ -o m m m 7zj rri cn rcn-F C 0 0 0 0 0 0 0 cn CD sue. G] co � sn m en rCD n CD Q 0 X �_ m o cr o a CD 3 o � 0 CD 0 C. =F y m A� ) �p O [A CD C O (p uF ro 0- LA) V Ln co w H4>'M Wp -u [u cn Ll co � o a o z $ y 0 0 c� ►�d cn : cn � cn O z {� *y n o c (� cr, ri o C) 00 C `3 4r o - n cn J r 0 r u+ m Wa, � C m m m o C" m m m m TOTAL CHLORINE, mgll C7 LJ L OR ug/I AT COLLECTION C C < z c n TEMPERATURE,°C 0 0 m3u O < x °�° AT COLLECTION m 0 "' v3 _ O m z # OF CONTAINERS u, 0 Field PH >by Metals ,. ('onductivi Fem erature EPA 8260D m m N m �. «Q< ::a 8260 Dup. 1 N 8260 Dup. 2 8260 Dup. 3 G� m z "'- 8260 Dup. 4 n>• "> "°<" Field Parameter S� 3 A l IZ S a a = PARAMETERS/TESTS n w > m O _ c7 cn cn o n m r n z 0 O z m O Lam' I.r' z Z r zo m n T1�7 O o � n p O z as z m m m r j kn —I z r �_ z vni m °� n f7 03 0 G7 G7 z 03 `75 m En Z m O Z N = Z = r N y _4 > m n m O 0 � zz cn m Z z � > n � o o o © O T m < z 0 m 0 0 ERW'0ff@EE(W T0 hmpumbd Drinking Water IDz 37715 114 OAKMONT DRIVE GREENVUE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PARAMETERS PH (field measurement), Units BOD, mg/l COD, mg/l Nitrate Nitrogen as N, mg/l Total Organic Carbon, mg/1 Alkalinity (to pH 4.5), mg CaCO3/1 Chloride, mg/l Cyanide, ug/1 Total Hardness, mg/1 Total Dissolved Residue, mg/l Total Dissolved Residue, mg/l Sulfate, mg/l Antimony, ug/1 Arsenio, ug/l Barium, ug/l Beryllium, ug/l Cadmium, ug/1 Cobalt, u9/1 Total Chromium, ug/l Copper, ug/1 Iron, ug/1 Manganese, ug/1 Lead, ug/1 Mercury, ug/1 Nickel, ug/1 Selenium, ug/1 Silver, ug/l Thallium, ug/l Tin, ug/1 Vanadium, ug/1 Zinc, ug/1 Sulfide, ug/1 Conductivity (at 25c), uMhca/cm Dissolved Oxygen, mg/1 Temperature, °C Static Water Level, feet well Depth, feet Carbon Dioxide, mg/1 ORP, my Turbidity (Field), NTU MDL MRL 2.0 2,0 0.840 20.0 0.009 0.04 0.129 1.0 1.0 1.0 5.0 5.0 5,0 5.0 1.0 1.0 5.0 0.03 0.03 0.03 0.05 0.02 0.03 0.15 0.03 4.96 0.31 0.03 0.05 0,03 0.15 0.05 0.05 0.05 0.03 0.11 100 1.0 0,1 10 10 5.0 1.0 5.0 10.0 1.0 1.0 1.0 5.0 10.0 50.0 10,0 5.0 0.20 10.0 10.0 5.0 1.0 100.0 1.0 10.0 1000 1.0 0.1 1.0 1.0 1.0 1,0 MW-15 ENE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 D DATE COLLECTED: 06/19/19 DATE REPORTED : 08/08/19 REVIEWED BY; MW-}6 ; �/- MW-17 MW-14S MW-14D Analysis Method Date Analyst Code 7.4 6.6 6.2 6.6 7.4 --- U 4.0 --- U 3.1 --- U 39 141 43 96 --- U --- ❑ --- U --- U --- U 0,24 15.26 76.40 10.32 29.76 2.68 49 240 71 520 249 10 75 9 20 14 --- U --- U --- V --- U --- U 114 713 302 353 161 233 413 1310 603 296 103 612 174 13.1 6,0 0.04 J 0.46 J --- U 0,06 J 0,04 J 1,6 J 5.0 1.1 J 2, 2 J 0. 18 J 109 418 39.0 98.9 10.1 0,11J 0.16 J --- U 0.07J --- U 0.07 1 0.13 J 0,04 J 0,05 IT 0.051 0,26 J 0.94 J 0.20 J 0,69 J 0.05 J 0.46 J 2.9 J 0.10 J 2.0 J -- - U 0.40 J 1,4 J 0. 17 J 0.92 J 0.94 J 6850 28823 2619 6173 - -- U 97 173 149 527 0.7 J --- U 0.71 J - -- U 0.72 J --- U --- U --- U --- U --- V --- U 1.3J 7.01 1.4J 4.01 1.81 0.51 a 4.3 J 0. 68 1 1. 1 J 0.35 J --- U --- U --- U - -- U --- U --- U 0.09 J 0.06 J 0.05 IT --- U -_- U --- U --- U --- U --- U 5.7 11.9 2.9 4.2 --- U 5.1 J 5.0 1 3.0 J 6.2 7 9.7 J --- U --- U --- U --- U --- U 368 1851 439 310 524 0.10 --- U 0.13 --- U --- U 23 23 23 22 23 6.39 7,51 6.30 4.00 6.15 22,14 22.73 22,25 23.12 41,92 66 332 80 306 14 +91 +46 +50 +54 +81 4.17 7.73 3.14 24.5 1.10 J A Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. 06/19/19 PJC 06/19/19 JTH 06/21/19 SEJ 06/20/19 DTL 06/24/19 SEJ 06/24/19 TCW 06/24/19 JTH 06/26/19 SEJ 06/24/19 TCW 06/20/19 MAR 06/25/19 KDS 06/24/19 SEJ 07/18/19 LFJ 07/10/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/01/19 LFJ 07/01/19 LFJ 07/18/19 LFJ 07/15/19 MTM 07/1B/19 LFJ 07/10/19 LFJ 07/18/19 LFJ 07/18/19 LFJ 07/29/19 LFJ 07/29/19 LFJ 07/18/19 LFJ 06/25/19 LFJ 06/19/19 SEB 06/19/19 Pic 06/19/19 PJC 06/19/19 PJC 06/19/19 PJC 06/19/19 RDS 06/19/19 PJC 06/19/19 PJC 4500HB-11 5210E-11 H8000-79 353.2 R2-9 531OC-11 2320E-11 4500CLB-11 450OCNE-11 2340C-11 254OC-11 254OC-11 4500804201 EPA200.8 EPA200.8 EPA200.8 EPA200.8 RPA200,8 EPA200.8 EPA200.8 6PA200.8 EPA200.7 EPA200,7 EPA200.8 24$.1 R3-9 EPA200.8 EPA200.8 EPA200.B EPA200.B EPA200.8 EPA200,8 EPA200.8 4500S2D-11 2510E-11 45000G-11 25505-10 45000O2C-1 2580B 2130E-11 RoAnNE&M % hompumbd Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: UUD SON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 DURHAM, NC 27703 DATE EXTRACTED: 06/21/19 DATE ANALYZED: 07/30/19 REVIEWED BY: DATE REPORTED: 08/08/19 PESTICIDES AND PCB'S EPA METHOD 8081B R2(07) MW-15 MW-16 MW-17 MW-148 MW-14D PARAMETERS, ug/l MDL MRL 1. Aldrin 0.029 0.050 --- U --- U --- U --- U --- U 2, Alpha-BHC 0.032 0.050 --- U --- U --- U --- U --- U 3. Beta-BHC 0.031 0.050 --- U --- U --- U --- U .-- U 4, Delta-BHC 0,030 0.050 --- U --- ll --- U -- U U 5. Gamma-BHC (Lindane) D.032 0.050 --- U --- a --- U --- U `-» U 6, Chlordane 0,320 0.500 --- U --- U --- U --- U --- U 7. 4,4-DDD 0.051 0.100 --- U --- U -'- U --- U '-- U 8, 4,4-DDE 0.049 0.100 --- U --- U --- U --- U --- U 9. 4,4-DDT 0.052 0.100 --- U --- U --- U --- U --- U 10, Dieldrin 0.042 0.075 --- U --- U --- U --- U --- U 11. Endosulfan 1 0.056 0.100 --- U --- U --- U --- U --- U 12. Endosulfan 11 0.046 0.100 --- U --- U --- U --- U --- U 23, Endoeulfan Sulfate 0.072 0.100 --- U --- U --- U --- U --- U 14. Endrin 0.053 0.100 --- u --- u --- U --- U --- U 15. Endrin Aldehyde 0.066 0.100 --- U --- U --- U --- U --- U 16. Heptachlor 0.039 0.050 --- U --- U --- U --- U --- U 17. Heptachlor Epoxide 0.042 0.075 --- U --- U --- U --- U --- U 18, Mothoxychlor 0.530 1.OD0 --- U --- U --- U --- U --- U 19. Pcb's (AroClcre) 0.500 2.000 --- v --- U --- U --- U --- U 20. Toxaphene 0.690 1.500 --- U --- U -`- U --- U --- U a = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. EmInhamN % hmpumNo Drinking Water ID: 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILL.E. N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&ID LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 DURHAM, NC 27703 DATE EXTRACTED: 06/20/19 DATE ANALYZED: 07/02/19 REVIEWED BY: z L11 DATE REPORTED: 08/08/19 LANDFILL APPENDIX II EPA METHOD 8151A R1(96) MW-15 MW-16 MW-17 MW-14S MW-14❑ PARAMETERS, u9/1 MDL MRL 1. 2,4-D 0.36 2,000 --- U --- U --- U --- U --- U 2, Dinoaab 0.54 1.000 --- U --- U --- U --- U --- U 3, 2,4,5-TP 0.42 2.000 --- U --- U --- U --- U --- U 4. 2,4,5-T 0.47 2.000 ___ U ___ U ___ U ___ U ___ U J = Estimated value between the MDL and MRL, U = Below ALL Quantitation Limits. MEW'noun(M % k@(0rpwMq@d- Drinking Water IDi 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 7703 REVIEWED BY: , PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 D ANALYST: JAP DATE COLLECTED: 06/19/19 Page: 1 DATE EXTRACTED: 06/24/19 DATE REPORTED: 08/08/19 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l Date MDL Analyzed MRL 07/03/19 MW-15 07/03/19 MW-16 07/00/19 MW-17 07/08/19 MW-14S 07/08/19 KW-14D 1. Acenaphthene 2.66 10.000 --- U --- U --- U --- U --- U 2, Acenaphthylene 2,60 I0.000 --- U --- U --- U --- U --- U 3. Anthracene 2.97 10.000 --- U --- U --- U --- U --- U 4. Benzo[a)antrhacene 4.16 10.000 --- U --- U --- U --- U --- U 5, Senzo[b]fluoranthene 3.32 10.000 --- U --- U --- U --- V --- U 6. Benzo[k3fluoranthene 4.23 10.000 --- U --- U --- U --- U --- U 7, Benzo(g,h,i]perylene 2.61 10,000 --- U --- U --- U --- U --- U 8. Benzo[a3pyrene 3.27 10.000 --- U --- U --- U --- U --- U 9. 4-Bromophenyl Phenyl Ether 2.63 10,000 --- U --- V --- U --- U --- U 10. Butyl Benzyl Phthalate 5.70 10.000 --- U --- V --- U --- U --- U 11, Bia(2-Chloroethoxy) Methane 3.14 10,000 --- U --- U --- U --- U --- U 12. Bis(2-Chloroethyl) Ether 2.58 I0.000 --- U --- U --- U --- U --- U 13. Bis(2-Chloro-l-methylethyl) Ether 2.58 10.000 --- U --- U --- U --- U --- U 14. 2-Chloronaphthalone 2,17 10.000 --- U --- U --- U --- U --- U 15. 4-Cblorophenyl Phenyl Ether 2.42 10.000 --- U --- U --- U --- U --- U 16, Chrysene 4.04 10.000 --- U --- U --- U --- U --- U 17. Dibenzo(a,h3anthracene 2.78 10.000 --- U --- U --- U --- U --- U 18, Di-N-Butyl Phthalate 3.09 10.000 --- U --- U --- U --- U --- U 19. Dimethyl Phthalate 3.78 10.000 --- U --- U --- U --- V --- U 20, Diethyl Phthalate 3.92 10.000 --- U --- U --- U --- U --- U 21, 2,4-Dinitrotoluene 3.95 10.000 --- U --- U --- U --- U --- U 22, 2,6-Dinitrotoluene 3.68 10.000 --- U --- U --- U -- U --- U 23. Di-N-Octyl Phthalate 2.81 10,000 --- U --- U --- U --- U --- U 24. Bis-(2-Ethylhexyl) Phthalate 9.97 15,000 --- U --- U --- U --- U --- U 25. Fluoranthene 3.92 10.000 --- U --- U --- U --- U --- U 26. Fluorene 2.95 10.000 --- U --- U --- U --- U --- U 27. Hexaahlorobenzene 2.61 10.000 --- U --- U --- U --- U --- U 28. Hexachlorocyclopentadiene 4.16 10.000 --- U --- U --- V --- U --- U 29. 1ndsno[1,2,3-Cd)pyrene 2.91 10.000 --- U --- U --- U --- U --- U 30. Isophorone 3.74 10.000 --- U --- U --- U --- U --- U 31. Nitrobenzene 2.85 10.000 --- U --- U --- U --- V --- U 32, N-Nitroaudimethylamine 4.25 10.000 --- U --- U --- U --- U --- U 33. N-Nitrosodiphenylamine 3,95 10,000 --- U --- V --- V --- U --- U 34. N-Nitrosodi-N-Propylamine 4.06 10.000 --- U --- U --- U --- U --- V 35. Phenanthrene 3.24 10.000 --- U --- U --- U --- U --- U 36. Pyrene 3.63 10.000 --- U --- U --- U --- U --- U 37, 4-Chloro-3-Methylphanol 3.79 20,000 --- U --- U --- U --- U --- U 38. 2-Chlorophenol 2,75 10.000 --- U --- U --- U --- U --- U 39. O-Cresol 3.68 20.000 --- U --- U --- U --- U --- U 40, P-Cresol 4.12 10.000 --- U --- U --- U --- U --- U 41. 2,4-Dichlorophenol 5.19 10.000 --- U --- U --- U --- U --- U 42. 2,6-Dichlorophenal 4.99 10,000 --- U --- U --- U --- U --- U 43. 2,4-Dimethylphenol 3.21 10.000 --- U --- U --- U --- U --- U 44. 4,6-Dinitra-2-Methylphenol 4.77 50.000 --- U --- U --- U --- U --- U 45. 2,4-Dinitrophanol 4.37 50.000 --- U --- U --- U --- U --- U 46. Ethyl Methanesulfonate 5,26 20,000 U U --- U U --- U 47. Methyl Methanesulfonate 4,92 10,000 --- U --- V --- U --- U --- U ,7 m Estimated value between the MDL and MRL, U - Below ALL Quantitation Limits. EEAmEmW % hmpumbd Drinking Water IAi 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 Page: 2 DURHAM, NC 27703 DATE EXTRACTED: 06/24/19 DATE REPORTED: 08/08/19 REVIEWED BY: SEMI -VOLATILE ORGANICS PPA MRTHOn 8270E R6(1$) PARAMETERS, ug/l Date MDL Analyzed MRL 07/03/19 MW-15 07/03/19 MW-16 07/08/19 MW-17 07/06/19 MW-148 07/08/19 MW-14D 40. 2-Nitrophenol 3.64 10.000 --- U --- U --- U --- U --- U 49. 4-Nitrophenol 3.17 50.000 U --- U --- U --- U --- U 50. Pentachlorophenol 5.33 25.000 --- U --- U --- U --- U --- U 51. Phenol 1.86 10,000 --- U --- U --- U --- U --- U 52. 2,3,4,6-Tetrachlorophenol 3.12 10.000 --- U --- U --- U --- U --- U 53. 2,4,5-Trichlorophenol 4.17 in.000 --- U --- U --- U --- U --- U 54, 2,4,6-Trichlorophenol 3.84 10.000 --- U --- U --- U --- U --- U 55, Acetophenone 2,89 10.000 --- U --- U --- U --- U --- U 56. 2-Acetylaminofluorene 3.98 20.000 --- U --- U --- U --- U --- U 57, 4-Aminobiphenyl 4.12 20.000 --- U --- U --- U --- U "-" U 59. Benzyl Alcohol 4.47 20.000 --- U --- U --- U --- U --- U 59. 4-ChloroaniIino 3.36 20.000 --- U --- U --- U --- U --- U 60. Chlorobenzilate 5.12 10,000 --- U --- U --- U --- U --- U 61, Diallate 2,9B Mono --- v --- U --- U --- U --- U 62. Dibenzofuran 4.20 10.000 --- U --- U --- U --- U --- U 63. 3,3-Dichlorobenzidine 4,22 20.000 --- U --- U --- U --- U --- U 64, Dimethcate 3.98 20.000 --- U --- U --- U --- U --- U 65. P-Dimethylaminoazohenzene 2,89 i0.000 --- U --- U --- U --- U --- U 66. 7,12-Dimethylbenz[a]anthracene 5.26 10.000 --- U --- U --- U --- U U 67. 3,3-Dimethylbenzadine 3.21 10.000 --- U --- U --- U --- U - " U 68, 1,3-Dinitroben7tene 2.89 20.000 --- U --- U --- U -- U --- U 69. Diphenylamine 5.10 10.000 --- U --- U --- U --- U --- U 70, Dieulfoton 4.28 10,000 --- U --- U ---- U --- U --- U 71. ramphur 3.98 20.000 »-- U --- U --- U --- U --- U 72, Hexachloropropene 4.31 10.000 --- U --- U --- U --- U --- U 73. isoeafrole 2.88 10.000 --- U --- U --- U --- U --- U 74. Kepone 2.70 20.000 --- U --- U --- U --- U --- U 75. Methapyrilene 3.54 100.000 --- U --- U --- U --- U --- U 76. 3-Methylchloroanthrene 4.21 10.000 --- U --- U --- U --- U U 77. 2-Methylnaphthalene 3.79 10.000 --- U --- U --- U --- U --- 78. Methyl Parathion 4.32 10.000 --- U --- U --- U --- U --- U 79. m-Creaol 3.81 10.000 --- U --- U --- U --- U --- U 80. 1,4-Naphthoquinone 4.00 10.000 --- U --- U --- U --- U --- U 81, 1-Naphthylamine 5.61 10.000 --- U --- U --- U --- U --- U 82. 2-Naphthylamine 4.62 10.000 --- U --- U --- U --- U --- U 83. 2-Nitroaniline 3.61 50.000 --- U --- U --- U --- U --- U 64, 3-Nitroaniline 4.81 50.000 --- U --- U -- U --- U --- U B5. 4-Nitroaniline 4.22 20.000 --- U --- U --- U --- U --- U 66, 5-Nitro-o-Toluidine 4.01 10.000 --- U --- U --- U --- U --- U 87. N-Nitrosodi-n-butylamine 3.63 10.000 --- U --- U --- U --- U U 88. N-Nitrosodiethylamine 3.83 20.000 --- U --- U --- U --- U --- U 89. N-Nitroaomethylethylamine 3.B3 10.000 --- U --- U --- U --- U U 90. N-Nitrosopiperidine 5.19 20.000 --- U --- U --- U --- U --- U 91, N-Nitrosopyrrolidine 2,89 10,000 --- U --- U --- U --- U --- U 92. Parathion 3.12 10.000 --- U --- U --- U --- U --- U 93, pentachlorobenzene 3.92 10,000 --- U --- U --- U --- U --- U 94, Pentachloronitrobenzene 3.71 20.000 --- U --- U --- U --- U --- U .7 = Retimated value between the MDL and MRL, U = Below ALL Quantitation Limits. Q 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) Drinking Water ID; 37715 Wae.tewater ID:- 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 D ANALYST: JAP DATE COLLECTED: 06/19/19 Page: 3 DATE EXTRACTED: 06/24/19 DATE REPORTED: 08/08/19 Date Analyzed 07/03/19 07/03/19 07/08/19 07/08/19 07/08/19 NW-15 HW-16 MW-17 MW-149 MW-14D PARAMLTERS, ug/l MDL MRL 95. Phenaoetin 4.41 20.000 --- U --- U --- a --- U --- 96. 1,4 Henzenediamine 2.99 10.000 --- U --- U --- U --- U --- U 91. Phorate 3.86 10.000 --- U -'- U '-- U --- U "- U 98. Pronamida 3.69 10.000 --- U --- U --- U --- U --- U 99, 5afrole 4.12 10.000 --- U --- U --- U --- U --- V 100. 1,2,4,5-Tetrachlorobenzene 5.01 10.000 --- U --- U --- U --- U --- U 101, Thionazin 4.62 20.000 --- U --- U --- U --- U --- U 102. O-Toluidine 4.11 10.000 --- U --- U --- V --- U --- U 103, 1,3,5-Trinitrobenzene 3,98 10.000 --- U --- U --- u --- U --- U 104. 0,0,0-Triethyl Phoephorothioate 3.61 10,000 --- U --- U --- U --- U --- U 105, Mexachloroethane 1,49 10.000 --- U --- U --- U --- U --- U 106. loodrin 3.11 20,000 --- U --- U --- U --- U --- U J = Betimated value between the MDL and MRL, U = Delow ALL Quantitation Limito. EWOmME(IM % hompTOW Drinking Water ID: 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 Page: 1 DURHAM, NC 27703 DATE ANALYZED: 06/25/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(1$) MW-15 MW-16 MW-17 MW-149 MW-14D PARAMETERS, ug/l MDL MRL 1. Chloromethane 0.77 3.000 --- U --- U --- U --- U -`- U 2, Vinyl Chloride 0,12 0.200 --- U --- U --- U 0.13 J --- U 3. Bromomethane 0.67 10.000 --- U --- U --- U --- U -^• V 4. Chloroethane 0,48 10.000 --- U --- U --- U --- U --- U 5, Trichlorofluoromethane 0.24 1,000 --- U --- U --- U --- U --- U 6. 1,I-Dichloroethane 0.17 5.000 --- U --- U --- U --- U --- U 7. Acetone 9.06 100.000 --- U --- U --- U --- U --- U S. Iodomethane 0.26 10.000 --- U --' U --- U --- U --- U 9. Carbon Disulfide 0.23 100.00D --- U --- U --- U --- U --- U 10. Methylene Chloride 0.64 1.000 --- U --- U --- V --• U --- U 11. trans-1,2-Dichloroethene 0.23 5.000 --- U --- U --- U --- U --- U 12. 1,1-Dichloroethane O.20 5.000 --- U --- U --- U --- U --- U 13. Vinyl Acetate 0.20 50.000 --- U --- U --- U --- U --- U 14. Cis-1,2-Dichloroethane 0.25 5.000 --- U --- U --- U --- U --- U 15, 2-Butanone 2.21 100.000 --- U --- U --- U --- U --- U 16. bromochloromethane 0.27 3,000 --- U --- U --- U --- U --- V 17. Chloroform 0.25 5.000 --- U --- U --- U --- U --- U 18. 1,1,1-Trichloroethane 0.19 1,000 --- U --- U --- U --- U --- U 19. Carbon Tetrachloride 0.04 0.200 --- U --- U --- U --- U --- U 20. Benzene 0.24 1.000 --- U --- U --- U --- U --- U 21. 1,2-Dichloroethane 0.02 0,200 --- U 0.04 .7 --- U --- U -'- U 22. Trichloroethane 0.23 1,000 --- U --- U --- U --- U --- U 23, 1,2-Dichloropropane 0.04 0.200 --- U --- U --- U --- U --- U 24. Bromodichloromethane 0.04 0.200 --- U --- U --- U --- U --- U 25. Cie-1,3-Dichloropropene 0.06 0.200 --- U --- V --- U --- U --- U 26. 4-Methyl-2-Pentanone 1.19 100.000 --- U --- U '-- U --- U - - U 27. Toluene 0.23 1.000 --- U --- U --- U --- U --- U 28. trans-1,3-Dichloropropene 0.04 0,200 --- U --- U --- U --- U - - U 29. 1,1,2-Trichloroethane 0.03 0.200 --- U --- U --- U --- U --- U 30. Tetrachloroethene 0.10 0.200 --- U --- U "" U --- U --- U 31. 2-Hexanone 1,57 50.000 --- U --- U --- U --- U --- U 32. Dibromochloromethane 0.03 0.200 --- U --- U --- U --- U --- U 33, 1,2-Dibromoethane 0.03 0.200 --- U --- U --" U --- U --- U 34. Chlorobenzene 0.30 3.000 --- U --- U --- U --- U --- U 35. 1,1,1,2-Tetrachloroethane 0.22 1.000 --- U --- U --- V --- U --- V 36, Ethylbanzene 0.21 1.000 --- U --- U --- U --- U U 37, %ylenes 0.60 5.000 --- U --- U --- U --- U --- U 36. Dibromomethans 0.20 10.000 --- U --- U --- U --- U -- U 39. Styrene 0.29 1.000 --- U --- U --- U --- U --- U 40, Bromoform 0.20 3.000 --- U --- U --- U --- U --- U 41. 1,1,2,2-Tetrachlaroethane 0.03 0.200 --- U --- U --- U --- U --- U 42. 1,2,3-Triohloropropane 0.09 0.200 --- U --- U -•^ U --- U --- U 43. 1,4-Dichlorobenzene 0.39 11000 --- U --- SF --- U --- U --- V 44. 1,2-Dichlorobernzene 0.32 5.000 --- U U V --- U --- U 45. 1,2-1)ibromo-3-Chloropropane 0.07 0.200 --- U --- U --- U --- U --- U 46. Acrylonitril9 2.72 200.000 --- U --- U --- U --- V --- U 47. trans-1,4-Dichloro-2-Butene 0.42 100.000 --- U --- U --- U --- U --- U 48. Acrolein 1.97 4,000 --- U --- U - U --- U - U .7 - Estimated Value between the MDL and MRL, U � Below ALL Quantitation Limits. Drinking ^water 1D: 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 Page: 2 DURHAM, NC 27703 DATE ANALYZED: 06/25/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) MW-15 MW-16 MW-17 MW-145 MW-14D PARAMETERS, Ug/l MDL MRL 49. Allyl Chloride 0,20 10.000 --- U --- U --- U --- U --- U 50. Chloroprene 0.21 20.000 --- U --- U --- U --- U --- U 51. 1,3-Dichlorobenzene 0.41 5,000 --- U --- U --- U --- U --' U 52. Dichlorodifluoromethans 0.51 5.000 --- U --- U --- U --- U --- U 53. 1,3-Dichloropropane 0.28 1.000 --- U --- U --- U --- U --- U 54. 2,2-Dichloropropane 0.17 15.000 --- U --- U --- U --- U --- U 55. 1,1-Dichloropropane 0.22 5.000 --- U --- U --- U --- U --- U 56. Ethyl Methacrylate 0.16 10.000 --- U --- U --- U --- U --- U 57. Hexachlorobutadiene 0.10 0,200 --- U --- U --" U --- U --- U 58. Iaobutyl Alcohol 12.80 100.000 --- U --- U --- U --- U --- U 59. Methacrylonitrile 1,93 100.000 --- U --- U --- U --- U --- U 60. Methyl Methacrylate 0.25 30,000 --- U --- U --- U `"- U --- U 61. Naphthalene 0.47 6.000 --- U --- U --- U --- U --- U 62. Propionitrile 3.26 150.000 --- U --- U --- U --- U --- U 63. 1,2,4-Trichlorobenzena 0.50 10.000 --- U --- U --- U --- U --- U 64. AcetOnitrile 36,29 55.000 --- U --- U --- U --- U --- U 65. Tetrahydrofuran 0.39 1.000 --- U 0.59 J 0.50 J O.B1 J --- U 66. 1,4-Dioxane 2.71 3.000 --- U --- U --- U --- U --- U J m Estimated value between the MDL and MRL, U = Below ALL Uuantitation Limits. Drinking Water ID; 37715 �Jaai:BSawYar 7D: 10 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 06/19/19 Page: 3 DURHAM, NC 27703 DATE ANALYZED: 06/25/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) Trip PARAMETERS, ug/1 MDL MRL Blank 1, Chloromethane 0.77 3.000 --- U 2. Vinyl Chloride 0.12 0,200 --- U 3. Bromomethane 0.67 10.000 --- U 4, Chloroethane 0.48 10,000 --- U 5. Trichlorofluoromethane 0.24 1.000 --- U 6. 1,1-Dichloroethene 1 0.17 5.000 --- U 7. Acetone 9.06 100.000 --- U 0. Iodomethane 0.26 10.000 --- U 9, Carbon Disulfide 0.23 100.000 --- U 10, Methylene Chloride 0.64 1.000 --- U 11. trans-1,2-Dichloroethene 0.23 5,0D0 -^- U 12. 1,1-Dichloroethene 0.20 5.000 --- U 13, Vinyl Acetate 0.20 50.000 --- U 14. Cie-1,2-Dichloroethene 0.25 5.000 --- U 15. 2-Butanone 2.21 100.000 --- U 16. Bromochloromethane 0,27 3.000 --- U 17. Chloroform 0.25 5,000 --- U 10. 1,1,1-Trichloroethane 0.19 1.000 --- U 15. Carbon Tetrachloride 0.04 0.200 --- U 20. Benzene 0.24 1.000 --- U 21. 1,2-Dichloroethane D,02 0,200 --- U 22. Trichloroethene 0.23 1.000 --- U 23, 1,2-Dichloropropane 0.04 0,200 --- U 24. Bromodichloromethane 0.04 0.200 --- U 25, Cie-1,3-Dichloropropene 0.06 0.200 --- U 26. 4-Methyl-2-Pentanone 1,19 100.000 --- U 27. Toluene 0.23 1.000 --- U 28. trana-1,3-Diohloropropene 0.04 0,200 --- U 29. 1,1,2-Trichloroethane 0.03 0.200 --- U 30. Tetrachloroethene 0.10 0.200 --- U 31. 2-Hexanone 1.57 50.000 --- U 32. Dibromoohloromethane 0.03 0.200 --- U 33. 1,2-Dibromoethane 0.03 0.200 --- U 34. chlorobenzene 0.30 3.000 --- U 35, 1,1,1,2-Tetrachloroethane 0.22 1.000 --- U 36. Ethylbenzene 0.21 1,000 --- U 37. Xylenea 0.60 5.000 --- U 3B. Dibromomethane 0.28 10,000 --- U 39. Styrene 0.29 1.000 --- U 40. Bromoform 0.20 3.000 --- U 41, 1,1,2,2-Tetrachloroethane 0.03 0.200 --- U 42, 1,2,3-Trichloropropane 0.09 0,200 --- U 43. 1,4-Dichlorobenzene 0.39 1.000 --- U 44. 1,2-Dichlorobenzene 0.32 5.000 --^ U 45. 1,2-Dibromo-3-Chlcropropane 0.07 0.200 --- U 46. Acrylonitrlle 2.72 200.000 --- U 47, trans-1,4-Diahloro-2-Butene 0.42 100.000 --- U 48. Acrolein 1.97 4.000 --- U J = Estimated value between the MDL and MRL, U . Below ALL Quantitaticn Limits, EWOmERM % hmpumbd Drinking Water ID; 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEL{ DR. STE 100 DATE COLLECTED: 06/19/19 Page: 4 DURHAM, NC 27703 DATE ANALYZED: 06/25/19 DATE REPORTED: 08/08/19 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PARAMETERS, uq/l MDL MRL Trip Blank 49, Ally1 chloride 0,20 10,000 --- V 50. Chloroprene 0.21 20,000 --- U 51. 1,3-Dichlorobenzene 0.41 5.000 --- U 52. IAichloroditluoromethane 0.51 5.000 --- U 53, 1,3-Dichlorapropane 0,28 1.000 --- U 54. 2.2-Dichlorapropane 0.17 15,000 --- U 55. 1,1-Dichloropropene 0.22 5.000 --- U 56, Ethyl Methacrylate 0.16 10.000 --- U 57. Rexachlorobutadiene 0.10 0.200 --- U 58. Isabutyl Alcohol 12.80 100.000 --- U 59. Methacrylonitrile 1.93 100.000 --- U 60, Methyl Methacrylate 0.25 30.000 --- U 61. Naphthalene 0.47 6.000 U 62. Propionitrile 3.26 150.000 U 63. 1,2,4-Trichlorobenzene 0,50 10.000 --- U 64, Acotonitrile 36.29 55.000 --- U 65. Tetrahydrofuran 0.39 1.000 --- U 66. 1,4-Dioxane 2.71 3.000 --- U j = Estimated value between the MDL and MRL, u - Below ALL Quantitation Limits. �¢ Z o z 'v ¢ ¢ z Q zwLD CO 11 O Cw3 u3 W a U wLO 3 CDQ z ? w U n �z � O O J z W ¢ cwn N C3 Q Z = N Z U LL ¢ C7 Z Q p C a a W uiui W LL C3 rn z ac o a w h W u Cil Z _ m cn LUU Z O a O \ J cD J CC 7D .�LUO Z U Z U ¢ m U �� Wd C. O 4N3 y S F z CL a 0- M m:m o _ S ¢ [1 ¢ a. U a U S1S311Sa311W d�dd rD u3 cn EXJ W `s 0 ca Q ca ^ Imo• OG J{:ry r:: fi::•:. •;i{ 4 h;:: roj r+7 fo cn S~+:: r: ij:: P, aping 2 -0 nVY:jn: j`+ivi'd ` lies, •x�Sf.0 iro c ,� � U Numnsy~�C ;'fir Sal fn 3:.Vc: 5x• Q U E co CD _ Imo' W do a� potgD :spiv ' 4:it • :Y`.j 3i.'-};y j$:>-::• W W ^ , w 1+1 O v `•]Doi, C4: BIB }}';: tiOj: =': ..... 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Qj F, � C 15 �..� �]] ["� u Ln5 Z o C. 2 Z W 2 r-I Z � D G o:— r Z�O EflAnDEM I hmpuMd 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PARAMETERS Iron (Ferrous), ug/l MW-4 MDL MRL 50.00 200.0 3957 W:a-8t.9w4ta3 xbS 10 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 DATE COLLECTED: 06/13/19 DATE REPORTED : 09/03/19 REVIEWED BY: f Mw-5 MW-6 MW-7 MW-S Analysis Method Date Analyst Cade 7394 20872 27011 39673 O6/13/19 SHU 3500FEB-11 J - Estimated Value between the MDL and MRL, U = Below ALL Quantitation Limits. Emkownq Ala hmpumbd 114 OAKMONT DRIVE GREENVIL.LE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PARAMETERS Iron (Ferrous), ug/l MW-1S MDL MRL 50.00 200.0 371 Wwotewat:ex 114 10 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 A DATE COLLECTED: 06/12/1.9 DATE REPORTED : 09/03/19 REVIEWED BY: )O-�- MW-lD MW-28 MW-2D 14W-35 Analysis Method Date Analyst Code 2258 8136 --- U 24655 06/13/19 SECT 35001'EB-11 J = Estimated Value between the MDL and MRL, U - Below ALL Quantitation Limits. EmMumumt % 6cupormNA 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM rNC 27703 PARAMETERS Iron (Ferrous), ug/l MW-3D MDL MRL wa stewatoY In i io PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 A DATE COLLECTED: 06/12/19 DATE REPORTED : 09/03/19 REVIEWED BY: MW-3A Analysis Method Z�t- Date Analyst Code 50.00 200.0 --- U 27430 06/13/19 SEU 3500FEB-11 a = Estimated Value between the MDL and MRL, U = Below ALL Quantitation Limits. Efidommud Ala RompmW wastewater 1D1 l0' 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 B JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/18/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 09/03/19 DURHAM ,NC 27703 REVIEWED BY: Mw-9A MW-10 MW-11 Mw-13 MW-12e Analysis Method PARAMETERS MDL MRL Date Analyst Code Iron (Ferrous), ug/l 50.00 200.0 2394 --- U 19045 5026 1887 06/19/19 SEJ 3500FEB-11 J = Estimated value between the MDL and MRL, U = Below ALL quantitation Limits. Naw,nangiN Wwab®water M 10 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 D UUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 06/19/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 09/03/19 DURHAM ,NC 27703 REVIEWED BY; MW-15 Mw-16 KW-17 MW-14S MW-14D Analysis Method PARAMETERS MDL MRL Date Analyat Code Iron (FerrOUS), ug/l 50.00 200.0 5962 25400 2511 5629 --- U 06/19/19 SEJ 3500FEB-11 J = Estimated value between the MDL and MRL, u - Below ALL auantitation Limite, /� ace RnalX caJ June 26, 2019 Steve Jones Environment 1, Inc. PO Box 7085 114 Oakmont Drive Greenville, NC 27835 RE: JUDSON / 6003 Pace Workorder. 30656 Dear Steve Jones: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Friday, June 14, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Ruth Welsh 06/26/2019 Ruth.Welsh@pacelabs.com Customer Service Representative Enclosures Report ID: 30656 - 1178346 As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 36 Page 1 of 34 Pace Analytical Energy Services LLC �}^Q �7 r + f 220 William Pitt Way ac A! alyfica7 Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 34 /� ace RnalX caJ SAMPLE SUMMARY Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 306560001 MW1S Bubble Strip 6/12/2019 09:00 6/14/2019 12:00 306560002 MW1 D Bubble Strip 6/12/2019 09:01 6/14/2019 12:00 306560003 MW2S Bubble Strip 6/12/2019 12:45 6/14/2019 12:00 306560004 MW2D Bubble Strip 6/12/2019 12:35 6/14/2019 12:00 306560005 MW3S Bubble Strip 6/12/2019 11:25 6/14/2019 12:00 306560006 MW3D Bubble Strip 6/12/2019 10:30 6/14/2019 12:00 306560007 MW3A Bubble Strip 6/12/2019 10:15 6/14/2019 12:00 306560008 MW4 Bubble Strip 6/13/2019 13:25 6/14/2019 12:00 306560009 MW5 Bubble Strip 6/13/2019 09:55 6/14/2019 12:00 306560010 MW6 Water 6/13/201911:05 6/14/2019 12:00 306560011 MW7 Water 6/13/201912:15 6/14/2019 12:00 306560012 MW8 Water 6/13/2019 08:30 6/14/2019 12:00 306560013 MW1S Water 6/12/201909:00 6/14/2019 12:00 306560014 MW1 D Water 6/12/2019 09:01 6/14/2019 12:00 306560015 MW2S Water 6/12/201912:45 6/14/2019 12:00 306560016 MW2D Water 6/12/201912:35 6/14/2019 12:00 306560017 MW3S Water 6/12/201911:25 6/14/2019 12:00 306560018 MW3D Water 6/12/201910:30 6/14/2019 12:00 306560019 MW3A Water 6/12/201910:15 6/14/2019 12:00 306560020 MW4 Water 6/13/201913:25 6/14/2019 12:00 306560021 MW5 Water 6/13/2019 09:55 6/14/2019 12:00 Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 34 ace RnalX caJ PROJECT SUMMARY Workorder: 30656 JUDSON / 6003 Workorder Comments Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The analysis for volatile fatty acids, method AM23G, was reported at dilution due to matrix interferences; samples 30656 (0010, 0012, 0019, 0021). The analysis for volatile fatty acids, method AM23G, was reported at dilution for samples 30656 (0011) due to the measured chloride concentration within the sample; matrix interfering compound. The container pH for samples 30656 (0010-0012) were measured as below the expected pH (< 10) for those samples preserved with trisodium phosphate, as assigned to PAES method AM20GAx. Sample Comments Lab ID: 306560001 Sample ID: MW1S Sample Type: N Sample headspace vial not sufficiently pressurized for analysis. Vial pressurized with an equal volume of UHP Nitrogen and analyzed. Results reported at a dilution. Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 34 ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560001 Sample ID: MW1S Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 09:00 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 27 ug/I 0.20 0.044 2 6/22/201910:11 TD d,n Ethane 0.00601.11 ug/I 0.020 0.0060 2 6/22/201910:11 TD d,n Ethene 0.0101.11 ug/I 0.020 0.010 2 6/22/201910:11 TD d,n Hydrogen 1.51.11 nM 2.0 1.5 2 6/22/201910:11 TD d,n Report ID: 30656 - 1178346 Page 5 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560002 Sample ID: MW1D Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 09:01 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 4300 ug/I 0.10 0.022 1 6/22/201910:23 TD n Ethane 0.53 ug/I 0.010 0.0030 1 6/22/201910:23 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201910:23 TD n Hydrogen 5.5 nM 1.0 0.75 1 6/22/201910:23 TD n Report ID: 30656 - 1178346 Page 6 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560003 Sample ID: MW2S Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 12:45 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 430 ug/I 0.10 0.022 1 6/22/201910:40 TD n Ethane 0.018 ug/I 0.010 0.0030 1 6/22/201910:40 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201910:40 TD n Hydrogen 1.1 nM 1.0 0.75 1 6/22/201910:40 TD n Report ID: 30656 - 1178346 Page 7 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560004 Sample ID: MW21) Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 12:35 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 12 ug/I 0.10 0.022 1 6/22/201912:27 TD n Ethane 0.0046J ug/I 0.010 0.0030 1 6/22/201912:27 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201912:27 TD n Hydrogen 1.0 nM 1.0 0.75 1 6/22/201912:27 TD n Report ID: 30656 - 1178346 Page 8 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560005 Sample ID: MW3S Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 11:25 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 440 ug/I 0.10 0.022 1 6/22/201912:41 TD n Ethane 0.069 ug/I 0.010 0.0030 1 6/22/201912:41 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201912:41 TD n Hydrogen 1.2 nM 1.0 0.75 1 6/22/201912:41 TD n Report ID: 30656 - 1178346 Page 9 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560006 Sample ID: MW31) Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 10:30 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 9.7 ug/I 0.10 0.022 1 6/22/201912:57 TD n Ethane 0.0061J ug/I 0.010 0.0030 1 6/22/201912:57 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201912:57 TD n Hydrogen 0.91J nM 1.0 0.75 1 6/22/201912:57 TD n Report ID: 30656 - 1178346 Page 10 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560007 Sample ID: MW3A Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/12/2019 10:15 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1100 ug/I 0.10 0.022 1 6/22/201913:10 TD n Ethane 0.24 ug/I 0.010 0.0030 1 6/22/201913:10 TD n Ethene 0.012 ug/I 0.010 0.0050 1 6/22/201913:10 TD n Hydrogen 1.0 nM 1.0 0.75 1 6/22/201913:10 TD n Report ID: 30656 - 1178346 Page 11 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560008 Sample ID: MW4 Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/13/2019 13:25 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1900 ug/I 0.10 0.022 1 6/22/201913:23 TD n Ethane 0.038 ug/I 0.010 0.0030 1 6/22/201913:23 TD n Ethene 0.0097J ug/I 0.010 0.0050 1 6/22/201913:23 TD n Hydrogen 0.86J nM 1.0 0.75 1 6/22/201913:23 TD n Report ID: 30656 - 1178346 Page 12 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560009 Sample ID: MW5 Date Received: 6/14/2019 12:00 Matrix: Date Collected: 6/13/2019 09:55 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 960 ug/I 0.10 0.022 1 6/22/201913:39 TD n Ethane 0.15 ug/I 0.010 0.0030 1 6/22/201913:39 TD n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/22/201913:39 TD n Hydrogen 0.98J nM 1.0 0.75 1 6/22/201913:39 TD n Report ID: 30656 - 1178346 Page 13 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1►F-1wi�I[Illf_NIIIIII0*41111>MV 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560010 Sample ID: MW6 Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/13/2019 11:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.431.11 mg/I 2.0 0.43 10 6/19/2019 06:11 KB d Acetic Acid 0.281.11 mg/I 1.0 0.28 10 6/19/2019 06:11 KB d Propionic Acid 0.0401.11 mg/I 1.0 0.040 10 6/19/2019 06:11 KB d Butyric Acid 0.38J mg/I 1.0 0.11 10 6/19/2019 06:11 KB d Pyruvic Acid 0.0501.11 mg/I 1.0 0.050 10 6/19/2019 06:11 KB d i-Pentanoic Acid 0.0601.11 mg/I 1.0 0.060 10 6/19/2019 06:11 KB d Pentanoic Acid 0.0701.11 mg/I 1.0 0.070 10 6/19/2019 06:11 KB d i-Hexanoic Acid 0.291.11 mg/I 2.0 0.29 10 6/19/2019 06:11 KB d Hexanoic Acid 0.21J mg/I 2.0 0.10 10 6/19/2019 06:11 KB d RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 2400 ug/I 0.50 0.094 1 6/24/201912:40 TD n Ethane 0.039J ug/I 0.10 0.011 1 6/24/201912:40 TD n Ethene 0.065J ug/I 0.10 0.0080 1 6/24/201912:40 TD n Report ID: 30656 - 1178346 Page 14 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1►F-1wi�I[Illf_NIIIIII0*41111>MV 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560011 Sample ID: MW7 Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/13/2019 12:15 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.431.11 mg/I 2.0 0.43 10 6/18/2019 15:03 KB d Acetic Acid 0.29J mg/I 1.0 0.28 10 6/18/2019 15:03 KB d Propionic Acid 0.0401.11 mg/I 1.0 0.040 10 6/18/2019 15:03 KB d Butyric Acid 0.33J mg/I 1.0 0.11 10 6/18/2019 15:03 KB d Pyruvic Acid 0.0501.11 mg/I 1.0 0.050 10 6/18/2019 15:03 KB d i-Pentanoic Acid 0.0601.11 mg/I 1.0 0.060 10 6/18/2019 15:03 KB d Pentanoic Acid 0.0701.11 mg/I 1.0 0.070 10 6/18/2019 15:03 KB d i-Hexanoic Acid 0.291.11 mg/I 2.0 0.29 10 6/18/2019 15:03 KB d Hexanoic Acid 0.101.11 mg/I 2.0 0.10 10 6/18/2019 15:03 KB d RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1800 ug/I 0.50 0.094 1 6/24/201912:56 TD n Ethane 0.043J ug/I 0.10 0.011 1 6/24/201912:56 TD n Ethene 0.049J ug/I 0.10 0.0080 1 6/24/201912:56 TD n Report ID: 30656 - 1178346 Page 15 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1►F-1wi�I[Illf_NIIIIII0*41111>MV 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560012 Sample ID: MW8 Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/13/2019 08:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.431.11 mg/I 2.0 0.43 10 6/19/2019 07:04 KB d Acetic Acid 0.281.11 mg/I 1.0 0.28 10 6/19/2019 07:04 KB d Propionic Acid 0.0401.11 mg/I 1.0 0.040 10 6/19/2019 07:04 KB d Butyric Acid 0.98J mg/I 1.0 0.11 10 6/19/2019 07:04 KB d Pyruvic Acid 0.064J mg/I 1.0 0.050 10 6/19/2019 07:04 KB d i-Pentanoic Acid 0.0601.11 mg/I 1.0 0.060 10 6/19/2019 07:04 KB d Pentanoic Acid 0.079J mg/I 1.0 0.070 10 6/19/2019 07:04 KB d i-Hexanoic Acid 0.291.11 mg/I 2.0 0.29 10 6/19/2019 07:04 KB d Hexanoic Acid 0.11J mg/I 2.0 0.10 10 6/19/2019 07:04 KB d RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3000 ug/I 0.50 0.094 1 6/24/201913:11 TD n Ethane 0.23 ug/I 0.10 0.011 1 6/24/201913:11 TD n Ethene 0.068J ug/I 0.10 0.0080 1 6/24/201913:11 TD n Report ID: 30656 - 1178346 Page 16 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560013 Sample ID: MW1S Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 09:00 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 16:50 KB Acetic Acid 0.033J mg/I 0.10 0.028 1 6/18/2019 16:50 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 16:50 KB Butyric Acid 0.011U mg/I 0.10 0.011 1 6/18/2019 16:50 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 16:50 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 16:50 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 16:50 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 16:50 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 16:50 KB Report ID: 30656 - 1178346 Page 17 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560014 Sample ID: MW1D Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 09:01 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 17:43 KB Acetic Acid 0.23 mg/I 0.10 0.028 1 6/18/2019 17:43 KB Propionic Acid 0.025J mg/I 0.10 0.0040 1 6/18/2019 17:43 KB Butyric Acid 0.011U mg/I 0.10 0.011 1 6/18/2019 17:43 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 17:43 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 17:43 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 17:43 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 17:43 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 17:43 KB Report ID: 30656 - 1178346 Page 18 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560015 Sample ID: MW2S Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 12:45 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 18:37 KB Acetic Acid 0.055J mg/I 0.10 0.028 1 6/18/2019 18:37 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 18:37 KB Butyric Acid 0.098J mg/I 0.10 0.011 1 6/18/2019 18:37 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 18:37 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 18:37 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 18:37 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 18:37 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 18:37 KB Report ID: 30656 - 1178346 Page 19 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560016 Sample ID: MW211) Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 12:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 19:30 KB Acetic Acid 0.042J mg/I 0.10 0.028 1 6/18/2019 19:30 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 19:30 KB Butyric Acid 0.011U mg/I 0.10 0.011 1 6/18/2019 19:30 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 19:30 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 19:30 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 19:30 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 19:30 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 19:30 KB Report ID: 30656 - 1178346 Page 20 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560017 Sample ID: MW3S Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 11:25 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 20:23 KB Acetic Acid 0.028U mg/I 0.10 0.028 1 6/18/2019 20:23 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 20:23 KB Butyric Acid 0.011U mg/I 0.10 0.011 1 6/18/2019 20:23 KB Pyruvic Acid 0.048J mg/I 0.10 0.0050 1 6/18/2019 20:23 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 20:23 KB Pentanoic Acid 0.036J mg/I 0.10 0.0070 1 6/18/2019 20:23 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 20:23 KB Hexanoic Acid 0.11J mg/I 0.20 0.010 1 6/18/2019 20:23 KB Report ID: 30656 - 1178346 Page 21 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560018 Sample ID: MW311) Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 10:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 21:17 KB Acetic Acid 0.047J mg/I 0.10 0.028 1 6/18/2019 21:17 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 21:17 KB Butyric Acid 0.011U mg/I 0.10 0.011 1 6/18/2019 21:17 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 21:17 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 21:17 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 21:17 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 21:17 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 21:17 KB Report ID: 30656 - 1178346 Page 22 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560019 Sample ID: MW3A Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/12/2019 10:15 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.43U mg/I 2.0 0.43 10 6/19/2019 07:58 KB d Acetic Acid 0.28U mg/I 1.0 0.28 10 6/19/2019 07:58 KB d Propionic Acid 0.040U mg/I 1.0 0.040 10 6/19/2019 07:58 KB d Butyric Acid 0.37J mg/I 1.0 0.11 10 6/19/2019 07:58 KB d Pyruvic Acid 0.050U mg/I 1.0 0.050 10 6/19/2019 07:58 KB d i-Pentanoic Acid 0.060U mg/I 1.0 0.060 10 6/19/2019 07:58 KB d Pentanoic Acid 0.070U mg/I 1.0 0.070 10 6/19/2019 07:58 KB d i-Hexanoic Acid 0.29U mg/I 2.0 0.29 10 6/19/2019 07:58 KB d Hexanoic Acid 0.16J mg/I 2.0 0.10 10 6/19/2019 07:58 KB d Report ID: 30656 - 1178346 Page 23 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ ANALYTICAL RESULTS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560020 Sample ID: MW4 Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/13/2019 13:25 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/18/2019 23:03 KB Acetic Acid 0.058J mg/I 0.10 0.028 1 6/18/2019 23:03 KB Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/18/2019 23:03 KB Butyric Acid 0.024J mg/I 0.10 0.011 1 6/18/2019 23:03 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/18/2019 23:03 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/18/2019 23:03 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/18/2019 23:03 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/18/2019 23:03 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/18/2019 23:03 KB Report ID: 30656 - 1178346 Page 24 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11 • ••_[�Cj1Z:�.'�:�11�Jfij.Y�]►1(.^i1ZIjL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306560021 Sample ID: MW5 Date Received: 6/14/2019 12:00 Matrix: Water Date Collected: 6/13/2019 09:55 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.43U mg/I 2.0 0.43 10 6/19/2019 08:52 KB d Acetic Acid 0.28U mg/I 1.0 0.28 10 6/19/2019 08:52 KB d Propionic Acid 0.040U mg/I 1.0 0.040 10 6/19/2019 08:52 KB d Butyric Acid 0.23J mg/I 1.0 0.11 10 6/19/2019 08:52 KB d Pyruvic Acid 0.050U mg/I 1.0 0.050 10 6/19/2019 08:52 KB d i-Pentanoic Acid 0.060U mg/I 1.0 0.060 10 6/19/2019 08:52 KB d Pentanoic Acid 0.070U mg/I 1.0 0.070 10 6/19/2019 08:52 KB d i-Hexanoic Acid 0.29U mg/I 2.0 0.29 10 6/19/2019 08:52 KB d Hexanoic Acid 0.16J mg/I 2.0 0.10 10 6/19/2019 08:52 KB d Report ID: 30656 - 1178346 Page 25 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. /� ace RnalX caJ ANALYTICAL RESULTS QUALIFIERS Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. d The analyte concentration was determined from a dilution. Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 26 of 34 ace RnalX caJ QUALITY CONTROL DATA n..._�cZiZ:�Y:1<11�L�I.Y�L1L:iiZ�X? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4104 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 306560011, 306560013, 306560014, 306560015, 306560016, 306560017, 306560018, 306560020 METHOD BLANK: 61717 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028J 0.028 Propionic Acid mg/I 0.0040U 0.0040 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 LABORATORY CONTROL SAMPLE: 61718 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.0 99 70-130 Acetic Acid mg/I 2 2.0 100 70-130 Propionic Acid mg/I 2 2.0 98 70-130 Butyric Acid mg/I 2 1.9 97 70-130 Pyruvic Acid mg/I 2 1.8 93 70-130 i-Pentanoic Acid mg/I 2 1.9 97 70-130 Pentanoic Acid mg/I 2 1.8 90 70-130 i-Hexanoic Acid mg/I 2 1.8 90 70-130 Hexanoic Acid mg/I 2 1.8 89 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61719 61720 Original: 306330017 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.0054 2 1.9 1.9 96 95 70-130 0.33 30 Acetic Acid mg/I 1.4 2 3.4 3.4 103 102 70-130 0.49 30 Propionic Acid mg/I 0.0056 2 2.1 2.1 105 105 70-130 0.08 30 Butyric Acid mg/I 0.03 2 2.2 2.3 111 112 70-130 0.35 30 Report ID: 30656 - 1178346 Page 27 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. /� ace RnalX caJ QUALITY CONTROL DATA Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61719 61720 Original: 306330017 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Pyruvic Acid mg/I 0 2 2.0 2.0 100 100 70-130 0.38 30 i-Pentanoic Acid mg/I 0 2 2.2 2.2 111 112 70-130 0.73 30 Pentanoic Acid mg/I 0 2 2.2 2.2 110 110 70-130 0.48 30 i-Hexanoic Acid mg/I 0 2 2.1 2.2 106 108 70-130 1.1 30 Hexanoic Acid mg/I 0 2 2.5 2.5 126 126 70-130 0.65 30 Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 28 of 34 ace RnalX caJ QUALITY CONTROL DATA n..._�cZiZ:�Y:1<11�L�I.Y�L1L:iiZ�X? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4108 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 306560010, 306560012, 306560019, 306560021 METHOD BLANK: 61806 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028U 0.028 Propionic Acid mg/I 0.0040U 0.0040 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 LABORATORY CONTROL SAMPLE: 61807 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.0 99 70-130 Acetic Acid mg/I 2 2.1 105 70-130 Propionic Acid mg/I 2 2.0 98 70-130 Butyric Acid mg/I 2 2.0 98 70-130 Pyruvic Acid mg/I 2 1.8 88 70-130 i-Pentanoic Acid mg/I 2 2.0 98 70-130 Pentanoic Acid mg/I 2 1.9 93 70-130 i-Hexanoic Acid mg/I 2 1.8 93 70-130 Hexanoic Acid mg/I 2 1.8 90 70-130 Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 29 of 34 ace RnalX caJ QUALITY CONTROL DATA Workorder: 30656 JUDSON / 6003 QC Batch: DISG/7616 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 306560001, 306560002, 306560003 METHOD BLANK: 61808 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.022U 0.022 n Ethane ug/I 0.0030U 0.0030 n Ethene ug/I 0.0050U 0.0050 n METHOD BLANK: 61810 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 0.75U 0.75 n LABORATORY CONTROL SAMPLE & LCSD: 61811 61814 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 8.1 8.2 8.1 101 101 80-120 0.53 20 n Ethane ug/I 6.4 6.5 6.5 102 101 80-120 0.49 20 n Ethene ug/I 16 16 16 102 102 80-120 0.41 20 n LABORATORY CONTROL SAMPLE & LCSD: 61813 61816 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 25 25 103 103 80-120 0.011 20 n Report ID: 30656 - 1178346 Page 30 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ QUALITY CONTROL DATA Workorder: 30656 JUDSON / 6003 QC Batch: DISG/7617 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 306560004, 306560005, 306560006, 306560007, 306560008, 306560009 METHOD BLANK: 61817 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.022U 0.022 n Ethane ug/I 0.0030U 0.0030 n Ethene ug/I 0.0050U 0.0050 n METHOD BLANK: 61819 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 0.75U 0.75 n LABORATORY CONTROL SAMPLE & LCSD: 61820 61823 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 8.1 8.2 8.2 102 101 80-120 0.38 20 n Ethane ug/I 6.4 6.6 6.5 103 102 80-120 0.38 20 n Ethene ug/I 16 17 17 103 103 80-120 0.3 20 n LABORATORY CONTROL SAMPLE & LCSD: 61822 61825 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 27 27 112 112 80-120 0.31 20 n Report ID: 30656 - 1178346 Page 31 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ QUALITY CONTROL DATA Workorder: 30656 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7618 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 306560010, 306560011, 306560012 METHOD BLANK: 61826 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I 0.094U 0.094 n Ethane ug/I 0.011 U 0.011 n Ethene ug/I 0.0080U 0.0080 n LABORATORY CONTROL SAMPLE & LCSD: 61828 61830 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 860 870 115 116 80-120 0.32 20 n Ethane ug/I 38 40 40 106 106 80-120 0.087 20 n Ethene ug/I 35 38 38 107 107 80-120 0.55 20 n Report ID: 30656 - 1178346 Page 32 of 34 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. /� ace RnalX caJ QUALITY CONTROL DATA QUALIFIERS Workorder: 30656 JUDSON / 6003 QUALITY CONTROL PARAMETER QUALIFIERS The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 33 of 34 ace RnalX caJ QUALITY CONTROL DATA CROSS REFERENCE TABLE n..._�cZiZ:�Y:1<11�L�I.Y�L1L:iiZ�X? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 306560011 MW7 AM23G EDON/4104 306560013 MW1S AM23G EDON/4104 306560014 MW1D AM23G EDON/4104 306560015 MW2S AM23G EDON/4104 306560016 MW21D AM23G EDON/4104 306560017 MW3S AM23G EDON/4104 306560018 MW31D AM23G EDON/4104 306560020 MW4 AM23G EDON/4104 306560010 MW6 AM23G EDON/4108 306560012 MW8 AM23G EDON/4108 306560019 MW3A AM23G EDON/4108 306560021 MW5 AM23G EDON/4108 306560001 MW1S AM20GAX DISG/7616 306560002 MW1D AM20GAX DISG/7616 306560003 MW2S AM20GAX DISG/7616 306560004 MW21D AM20GAX DISG/7617 306560005 MW3S AM20GAX DISG/7617 306560006 MW31D AM20GAX DISG/7617 306560007 MW3A AM20GAX DISG/7617 306560008 MW4 AM20GAX DISG/7617 306560009 MW5 AM20GAX DISG/7617 306560010 MW6 AM20GAX DISG/7618 306560011 MW7 AM20GAX DISG/7618 306560012 MW8 AM20GAX DISG/7618 Report ID: 30656 - 1178346 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. 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CT F' CT a F' I F' Y- (D 'H m O O Vi W m a a n w n a m . m n n w n a a. w 9 t9 n m Y- N- w m CID, x m .,t m 't �C �C O = : O A o. O fD °'•j -! fD r r D .. m . W - v a z; O" =i` n -• l9nn n'..�� Q: �' ro m rororo I m m O ro_ Nz SNnwR'.m Op N: P.N c�+O`RNN N. N7• rD: �` a 3 m' C m 7 < n r� W o o o o rD 3 O 0o o D 3 m 3: Ll rt m y. a' w m n 't 't M Lo w 4 k (Da n Hx firo (D < t W P-0 r PC - .. m n Oom:wN-OH.:n coa ..7 H m : o mo 3 m r 2 3 -p wm m N -(D n r a -: n c r It n m It l0 x ,.� '? - O O z a,�]y ID p 7 o m n � -4 Yk 7 -1 o 3 z ID 0 + a -v a +n n r. o F'- w fD a o fD G (D fD ro ro a IQ N-n O n m m M m ro 3 3 3 D' D° o z n O o' RD 3 -0 m -o r r;n 0 m m m m y m cD Id a n 7- E _m (D (D On D G) : a m m rt n k N : N (D SD (D IDmH n n .fp. v. a p, 7 a c D a a mma x It F-' fD p It 3 ° +J cr vrD °„ z vw m a c+ w 0- �D. O O O- D nnn �� /� ace RnalX caJ July 1, 2019 Steve Jones Environment 1, Inc. PO Box 7085 114 Oakmont Drive Greenville, NC 27835 RE: JUDSON / 6003 Pace Workorder. 30684 Dear Steve Jones: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, June 20, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Ruth Welsh 07/01/2019 Ruth.Welsh@pacelabs.com Customer Service Representative Enclosures Report ID: 30684 - 1180086 As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages Page 1 of 30 Pace Analytical Energy Services LLC �}^Q �7 r + f 220 William Pitt Way ac A! alyfica7 Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 30 /� ace RnalX caJ SAMPLE SUMMARY Workorder: 30684 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 306840001 MW9A Bubble Strip 6/18/2019 09:42 6/20/2019 10:30 306840002 MW10 Bubble Strip 6/18/2019 11:10 6/20/2019 10:30 306840003 MW11 Bubble Strip 6/18/2019 14:46 6/20/2019 10:30 306840004 MW12S Water 6/18/201912:19 6/20/2019 10:30 306840005 MW13 Bubble Strip 6/18/2019 13:27 6/20/2019 10:30 306840006 W14S Bubble Strip 6/19/2019 11:36 6/20/2019 10:30 306840007 W14D Bubble Strip 6/19/2019 10:42 6/20/2019 10:30 306840008 W15 Bubble Strip 6/19/2019 09:34 6/20/2019 10:30 306840009 W16 Bubble Strip 6/19/2019 12:33 6/20/2019 10:30 306840010 W17 Bubble Strip 6/19/2019 13:37 6/20/2019 10:30 306840011 MW9A Water 6/18/2019 09:42 6/20/2019 10:30 306840012 MW10 Water 6/18/201911:10 6/20/2019 10:30 306840013 MW11 Water 6/18/201914:46 6/20/2019 10:30 306840014 MW13 Water 6/18/201913:27 6/20/2019 10:30 306840015 W14S Water 6/19/201911:36 6/20/2019 10:30 306840016 W14D Water 6/19/201910:42 6/20/2019 10:30 306840017 MW15 Water 6/19/2019 09:34 6/20/2019 10:30 306840018 MW16 Water 6/19/201912:33 6/20/2019 10:30 306840019 MW17 Water 6/19/201913:37 6/20/2019 10:30 Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 30 ace RnalX caJ PROJECT SUMMARY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Workorder: 30684 JUDSON / 6003 Workorder Comments The container pH for sample 30684 (0004) were measured as below the expected pH (< 10) for those samples preserved with trisodium phosphate, as assigned to PAES method AM20GAx. Sample Comments Lab ID: 306840004 Sample ID: MW12S Sample Type: N The analysis for low level volatile fatty acids, method AM23G, was reported at dilution due to matrix interferences. Batch Comments Batch: EDON/4111 - Low Level Volatile Fatty Acids The samples were not evaluated against matrix spike and duplicate spike due to matrix interferences associated with the assigned reference sample 306840004. Batch acceptance based on laboratory control sample recovery. Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 30 ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840001 Sample ID: MW9A Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/18/2019 09:42 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 92 ug/I 0.10 0.022 1 6/27/201910:59 MM n Ethane 0.076 ug/I 0.010 0.0030 1 6/27/201910:59 MM n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/27/201910:59 MM n Hydrogen 0.82J nM 1.0 0.75 1 6/27/201910:59 MM n Report ID: 30684 - 1180086 Page 5 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840002 Sample ID: MW10 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/18/2019 11:10 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3900 ug/I 0.10 0.022 1 6/27/201911:11 MM n Ethane 0.040 ug/I 0.010 0.0030 1 6/27/201911:11 MM n Ethene 0.19 ug/I 0.010 0.0050 1 6/27/201911:11 MM n Hydrogen 1.1 nM 1.0 0.75 1 6/27/201911:11 MM n Report ID: 30684 - 1180086 Page 6 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840003 Sample ID: MW11 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/18/2019 14:46 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 130 ug/I 0.10 0.022 1 6/27/201911:23 MM n Ethane 0.0078J ug/I 0.010 0.0030 1 6/27/201911:23 MM n Ethene 0.058 ug/I 0.010 0.0050 1 6/27/201911:23 MM n Hydrogen 1.2 nM 1.0 0.75 1 6/27/201911:23 MM n Report ID: 30684 - 1180086 Page 7 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► F-1wi� I [IllfnNIIIIII 0 *41111>M iV 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840004 Sample ID: MW12S Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/18/2019 12:19 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.431.11 mg/I 2.0 0.43 10 6/26/2019 20:33 KB d Acetic Acid 0.73J mg/I 1.0 0.28 10 6/26/2019 20:33 KB d,B Propionic Acid 0.0401.11 mg/I 1.0 0.040 10 6/26/2019 20:33 KB d Butyric Acid 1.1 mg/I 1.0 0.11 10 6/26/2019 20:33 KB d Pyruvic Acid 0.0501.11 mg/I 1.0 0.050 10 6/26/2019 20:33 KB d i-Pentanoic Acid 0.0601.11 mg/I 1.0 0.060 10 6/26/2019 20:33 KB d Pentanoic Acid 0.18J mg/I 1.0 0.070 10 6/26/2019 20:33 KB d i-Hexanoic Acid 0.291.11 mg/I 2.0 0.29 10 6/26/2019 20:33 KB d Hexanoic Acid 0.101.11 mg/I 2.0 0.10 10 6/26/2019 20:33 KB d RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 4600 ug/I 0.50 0.046 1 6/26/201911:03 BW n Ethane 0.17 ug/I 0.10 0.0050 1 6/26/201911:03 BW n Ethene 0.50 ug/I 0.10 0.0040 1 6/26/201911:03 BW n Report ID: 30684 - 1180086 Page 8 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840005 Sample ID: MW13 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/18/2019 13:27 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 190 ug/I 0.10 0.022 1 6/27/201911:36 MM n Ethane 0.0066J ug/I 0.010 0.0030 1 6/27/201911:36 MM n Ethene 0.027 ug/I 0.010 0.0050 1 6/27/201911:36 MM n Hydrogen 1.5 nM 1.0 0.75 1 6/27/201911:36 MM n Report ID: 30684 - 1180086 Page 9 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840006 Sample ID: W14S Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/19/2019 11:36 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3000 ug/I 0.10 0.022 1 6/27/201911:48 MM n Ethane 0.039 ug/I 0.010 0.0030 1 6/27/201911:48 MM n Ethene 0.10 ug/I 0.010 0.0050 1 6/27/201911:48 MM n Hydrogen 0.84J nM 1.0 0.75 1 6/27/201911:48 MM n Report ID: 30684 - 1180086 Page 10 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840007 Sample ID: W14D Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/19/2019 10:42 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 12 ug/I 0.10 0.022 1 6/27/201912:01 MM n Ethane 0.0090J ug/I 0.010 0.0030 1 6/27/201912:01 MM n Ethene 0.0064J ug/I 0.010 0.0050 1 6/27/201912:01 MM n Hydrogen 0.90J nM 1.0 0.75 1 6/27/201912:01 MM n Report ID: 30684 - 1180086 Page 11 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840008 Sample ID: W15 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/19/2019 09:34 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 200 ug/I 0.10 0.022 1 6/27/201912:15 MM n Ethane 0.0079J ug/I 0.010 0.0030 1 6/27/201912:15 MM n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/27/201912:15 MM n Hydrogen 0.98J nM 1.0 0.75 1 6/27/201912:15 MM n Report ID: 30684 - 1180086 Page 12 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840009 Sample ID: W16 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/19/2019 12:33 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 660 ug/I 0.10 0.022 1 6/27/201912:40 MM n Ethane 0.010 ug/I 0.010 0.0030 1 6/27/201912:40 MM n Ethene 0.022 ug/I 0.010 0.0050 1 6/27/201912:40 MM n Hydrogen 1.2 nM 1.0 0.75 1 6/27/201912:40 MM n Report ID: 30684 - 1180086 Page 13 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840010 Sample ID: W17 Date Received: 6/20/2019 10:30 Matrix: Date Collected: 6/19/2019 13:37 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 160 ug/I 0.10 0.022 1 6/27/201912:58 MM n Ethane 0.022 ug/I 0.010 0.0030 1 6/27/201912:58 MM n Ethene 0.00501.11 ug/I 0.010 0.0050 1 6/27/201912:58 MM n Hydrogen 1.1 nM 1.0 0.75 1 6/27/201912:58 MM n Report ID: 30684 - 1180086 Page 14 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840011 Sample ID: MW9A Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/18/2019 09:42 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/25/2019 19:08 KB Acetic Acid 0.031J mg/I 0.10 0.028 1 6/25/2019 19:08 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 19:08 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/25/2019 19:08 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/25/2019 19:08 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 19:08 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/25/2019 19:08 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 19:08 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/25/2019 19:08 KB Report ID: 30684 - 1180086 Page 15 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840012 Sample ID: MW10 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/18/2019 11:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/25/2019 20:01 KB Acetic Acid 0.028U mg/I 0.10 0.028 1 6/25/2019 20:01 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 20:01 KB Butyric Acid 0.24 mg/I 0.10 0.011 1 6/25/2019 20:01 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/25/2019 20:01 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 20:01 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/25/2019 20:01 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 20:01 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/25/2019 20:01 KB Report ID: 30684 - 1180086 Page 16 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840013 Sample ID: MW11 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/18/2019 14:46 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/25/2019 20:54 KB Acetic Acid 0.063J mg/I 0.10 0.028 1 6/25/2019 20:54 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 20:54 KB Butyric Acid 0.055J mg/I 0.10 0.011 1 6/25/2019 20:54 KB Pyruvic Acid 0.017J mg/I 0.10 0.0050 1 6/25/2019 20:54 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 20:54 KB Pentanoic Acid 0.0099J mg/I 0.10 0.0070 1 6/25/2019 20:54 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 20:54 KB Hexanoic Acid 0.076J mg/I 0.20 0.010 1 6/25/2019 20:54 KB Report ID: 30684 - 1180086 Page 17 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840014 Sample ID: MW13 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/18/2019 13:27 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.070J mg/I 0.20 0.043 1 6/25/2019 21:48 KB Acetic Acid 0.052J mg/I 0.10 0.028 1 6/25/2019 21:48 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 21:48 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/25/2019 21:48 KB Pyruvic Acid 0.014J mg/I 0.10 0.0050 1 6/25/2019 21:48 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 21:48 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/25/2019 21:48 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 21:48 KB Hexanoic Acid 0.014J mg/I 0.20 0.010 1 6/25/2019 21:48 KB Report ID: 30684 - 1180086 Page 18 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840015 Sample ID: W14S Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/19/2019 11:36 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/25/2019 22:41 KB Acetic Acid 0.044J mg/I 0.10 0.028 1 6/25/2019 22:41 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 22:41 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/25/2019 22:41 KB Pyruvic Acid 0.015J mg/I 0.10 0.0050 1 6/25/2019 22:41 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 22:41 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/25/2019 22:41 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 22:41 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/25/2019 22:41 KB Report ID: 30684 - 1180086 Page 19 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840016 Sample ID: W14D Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/19/2019 10:42 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/25/2019 23:34 KB Acetic Acid 0.045J mg/I 0.10 0.028 1 6/25/2019 23:34 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/25/2019 23:34 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/25/2019 23:34 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/25/2019 23:34 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/25/2019 23:34 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/25/2019 23:34 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/25/2019 23:34 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/25/2019 23:34 KB Report ID: 30684 - 1180086 Page 20 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840017 Sample ID: MW15 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/19/2019 09:34 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/26/2019 00:28 KB Acetic Acid 0.040J mg/I 0.10 0.028 1 6/26/2019 00:28 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/26/2019 00:28 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/26/2019 00:28 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/26/2019 00:28 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/26/2019 00:28 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/26/2019 00:28 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/26/2019 00:28 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/26/2019 00:28 KB Report ID: 30684 - 1180086 Page 21 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840018 Sample ID: MW16 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/19/2019 12:33 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/26/2019 01:21 KB Acetic Acid 0.074J mg/I 0.10 0.028 1 6/26/2019 01:21 KB B Propionic Acid 0.0042J mg/I 0.10 0.0040 1 6/26/2019 01:21 KB Butyric Acid 0.070J mg/I 0.10 0.011 1 6/26/2019 01:21 KB Pyruvic Acid 0.0058J mg/I 0.10 0.0050 1 6/26/2019 01:21 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/26/2019 01:21 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/26/2019 01:21 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/26/2019 01:21 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/26/2019 01:21 KB Report ID: 30684 - 1180086 Page 22 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ 11a • or--�TlT.f.*):MIll§T.Yol"'WA"IIIIIL? Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 306840019 Sample ID: MW17 Date Received: 6/20/2019 10:30 Matrix: Water Date Collected: 6/19/2019 13:37 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.043U mg/I 0.20 0.043 1 6/26/2019 02:14 KB Acetic Acid 0.046J mg/I 0.10 0.028 1 6/26/2019 02:14 KB B Propionic Acid 0.0040U mg/I 0.10 0.0040 1 6/26/2019 02:14 KB Butyric Acid 0.011 U mg/I 0.10 0.011 1 6/26/2019 02:14 KB Pyruvic Acid 0.0050U mg/I 0.10 0.0050 1 6/26/2019 02:14 KB i-Pentanoic Acid 0.0060U mg/I 0.10 0.0060 1 6/26/2019 02:14 KB Pentanoic Acid 0.0070U mg/I 0.10 0.0070 1 6/26/2019 02:14 KB i-Hexanoic Acid 0.029U mg/I 0.20 0.029 1 6/26/2019 02:14 KB Hexanoic Acid 0.010U mg/I 0.20 0.010 1 6/26/2019 02:14 KB Report ID: 30684 - 1180086 Page 23 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. /� ace RnalX caJ ANALYTICAL RESULTS QUALIFIERS Workorder: 30684 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. d The analyte concentration was determined from a dilution. Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 24 of 30 ace RnalX caJ QUALITY CONTROL DATA Workorder: 30684 JUDSON / 6003 QC Batch: DISG/7621 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 306840004 METHOD BLANK: 61847 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.046U 0.046 n Ethane ug/I 0.0050U 0.0050 n Ethene ug/I 0.0040U 0.0040 n LABORATORY CONTROL SAMPLE & LCSD: 61848 61849 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 780 810 104 109 80-120 4.7 20 n Ethane ug/I 38 39 40 103 107 80-120 3.6 20 n Ethene ug/I 35 36 37 102 106 80-120 3.2 20 n Report ID: 30684 - 1180086 Page 25 of 30 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ QUALITY CONTROL DATA I1 a.._«cZil:YTilllJfaWol"l1L:iil-l. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4111 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 306840011, 306840012, 306840013, 306840014, 306840015, 306840016, 306840017, 306840018, 306840019 METHOD BLANK: 61864 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.040J 0.028 B Propionic Acid mg/I 0.0040U 0.0040 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 LABORATORY CONTROL SAMPLE: 61865 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.0 102 70-130 Acetic Acid mg/I 2 2.1 107 70-130 B Propionic Acid mg/I 2 2.1 104 70-130 Butyric Acid mg/I 2 2.0 101 70-130 Pyruvic Acid mg/I 2 2.0 98 70-130 i-Pentanoic Acid mg/I 2 2.0 101 70-130 Pentanoic Acid mg/I 2 2.0 99 70-130 i-Hexanoic Acid mg/I 2 1.9 95 70-130 Hexanoic Acid mg/I 2 1.8 92 70-130 Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 26 of 30 ace RnalX caJ QUALITY CONTROL DATA Workorder: 30684 JUDSON / 6003 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7628 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 306840001, 306840002, 306840003, 306840005, 306840006, 306840007, 306840008, 306840009, 306840010 METHOD BLANK: 61896 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I 0.022U 0.022 n Ethane ug/I 0.0030U 0.0030 n Ethene ug/I 0.0050U 0.0050 n METHOD BLANK: 61897 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 0.75U 0.75 n LABORATORY CONTROL SAMPLE & LCSD: 61898 61900 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 8.1 8.1 8.0 100 99 80-120 0.24 20 n Ethane ug/I 6.4 6.4 6.4 101 101 80-120 0.012 20 n Ethene ug/I 16 16 16 101 101 80-120 0.078 20 n LABORATORY CONTROL SAMPLE & LCSD: 61899 61901 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 24 24 97 97 80-120 0.084 20 n Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 27 of 30 ace RnalX caJ QUALITY CONTROL DATA I1 a.._«cZil:YTilllJfaWol"l1L:iil-l. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4115 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 306840004 METHOD BLANK: 61920 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.046J 0.028 B Propionic Acid mg/I 0.0040U 0.0040 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 LABORATORY CONTROL SAMPLE: 61921 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.1 103 70-130 Acetic Acid mg/I 2 2.3 117 70-130 B Propionic Acid mg/I 2 2.1 105 70-130 Butyric Acid mg/I 2 2.1 105 70-130 Pyruvic Acid mg/I 2 1.7 84 70-130 i-Pentanoic Acid mg/I 2 2.1 104 70-130 Pentanoic Acid mg/I 2 2.0 99 70-130 i-Hexanoic Acid mg/I 2 1.9 97 70-130 Hexanoic Acid mg/I 2 1.8 92 70-130 Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 28 of 30 /� ace RnalX caJ QUALITY CONTROL DATA QUALIFIERS Workorder: 30684 JUDSON / 6003 QUALITY CONTROL PARAMETER QUALIFIERS The analyte was detected in the associated blank. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 29 of 30 ace RnalX caJ QUALITY CONTROL DATA CROSS REFERENCE TABLE n..._«cZil:YTilllJfaWol"l1L:iil-l. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 306840004 MW12S AM20GAX DISG/7621 306840011 MW9A AM23G EDON/4111 306840012 MW10 AM23G EDON/4111 306840013 MW11 AM23G EDON/4111 306840014 MW13 AM23G EDON/4111 306840015 W14S AM23G EDON/4111 306840016 W14D AM23G EDON/4111 306840017 MW15 AM23G EDON/4111 306840018 MW16 AM23G EDON/4111 306840019 MW17 AM23G EDON/4111 306840001 MW9A AM20GAX DISG/7628 306840002 MW10 AM20GAX DISG/7628 306840003 MW11 AM20GAX DISG/7628 306840005 MW13 AM20GAX DISG/7628 306840006 W14S AM20GAX DISG/7628 306840007 W14D AM20GAX DISG/7628 306840008 W15 AM20GAX DISG/7628 306840009 W16 AM20GAX DISG/7628 306840010 W17 AM20GAX DISG/7628 306840004 MW12S AM23G EDON/4115 Report ID: 30684 - 1180086 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. 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CD N. r� CD CD 0.0 (D 0 in, 0. w m 0 (D F1 H 0 W F1 F o(D n > ID 0 S) C" tQ (D (D 10 10 (D 0 o It ro m.D: rn H, 0 a 'N m 0 w H m m H 't (D Z P, 1i n a0 0 N. 0 0 m 0 0 I-D 3 2- SDI 3 3 tl It (D a m a It It IQ �4 (D W 0 10 (D 0 P- 0 rd co a 0 0 M on m m 0 FC1 D 3 - - (D 1-1 F1 (D 0 H 1b M U, :j m 0 2 0 r Id M 0 (D 0 ID 0 Fl- M 1i P. gl 0 Fl- (D tJ 0 > CD r CD CD 10 3 z �J 3 o ID n (D. 0 rD m rl 3 3 (D -0 (D -0 'o 0 Q H� a 0 " 0 0 It 0 'd a 0 (D CD (D (D _3 ID Id , 0 CL m < 3 n , (D 0 10 Id 1i �11 3 Z (D - c rD C) n -0 CL < CD (D 0 (D CD rA 0 FL -a 0 rD (D L, �o d 0 0 C, 0 tJ w (t H CD �J CD (t H CD ::% It P, P. a 1 > 0 0 0 C) Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Appendix B wood. Historical Analytical Data and Groundwater Elevations Appendix B MW-ID Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 IL A 10 1 Total 1,000 15 1 1 Thalliurn &,,Vanadium 2,000 Zinc 2001-May ivy ivy NS NS NS NS NS NS NS NS NS NS NS 2001-Nov ND ND ND ND ND ND 83 ND ND NS ND ND ND ND NS 48 53 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov ND ND ND ND ND ND 22 ND ND NS ND ND ND ND NS ND ND 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 1 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 16 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May 0.2J 0.3J 111 0.06U 0.11 0.11 0.3J 0.4 0.04U NS 0.91 0.3J 0.04U ND NS 0.07U 1 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2013-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.57 J 0.49 J 71.1 J 0.02 U 0.85 J 0.22 J 0.24 J 4.8 J 0.27 J NS 3.4 J 0.24 J 0.01 U 0.03 J NS 0.88 J 16 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.3J 0.07U 74.6J 0.07U 0.60J 0.38J 0.13J 4.1J 0.29J 0.07U 4.4J 0.51U 0.20U 0.08U 0.52J 2.2J 11 2017-Dec 0.26J 4.9J 115 0.07J 0.55J 0.57J 2.1J 3.1J 2.1J 0.07U 4.4J 0.63J 0.24J 0.08U 0.911 4.1J 51 2018-Jun 0.08 J 2.6 J 35.6 0.05 U 0.27 J 0.22 J 0.15 U 1.5 J 0.53 J 0.07 U 2 J 0.33 J 0.06 J 0.05 U 0.11 1.4 6.5 J 2018-Dec 0.11 J 2.5 J 35.5 0.05 U 0.111 0.27 J 1.4 J 1.6 J 11 0.05 U 1.6 J 0.3 J 0.09 J 0.05 U 0.17 J 2 14 2019-Jun 9 1.5 J 28.1 0.05 U 0.02 U 0.07 J 0.15 U 11 0.03 U 0.12 J 0.72 J 0.29 J 0.05 U 0.05 U 0.05 U 0.03 U 3.8 J 1 of 53 Appendix B MW-ID Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 0.4 70 NE 2001-May ND ND ND NS ND NS NS 11.12 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May ND ND ND NS ND NS NS 11.98 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May Damaged Damaged Damaged NS Damaged NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May Damaged Damaged Damaged NS Damaged NS NS Damaged 2006-Nov NS NS NS NS NS NS NS NM 2007-May ND ND ND NS ND NS NS 12.52 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May ND ND ND NS ND NS NS 12.24 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS Damaged 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS Damaged 2013-May NS NS NS NS NS NS NS Damaged 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.33 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 100U 0.63U 14.4 NS 13.01 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 117 NS Damaged 2018-Jun 0.24 U 0.21 U 0.25 U 100 0.63 U 30.5 NS Damaged 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 42.7 2.71 U 13.34 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 43.3 2.71 U 12.50 2 of 53 Appendix B MW-IS Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled Antimony Arsenic ND Barium ND Beryllium ND Cadmium ND CobaltCopper ND Total ND ND ND NS ND ND ND ND ND 3 ND ND 2001-May ND 2001-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND 15 ND ND NS ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U 0.42 U 0.42 U 0.2 U 2007-Nov 0.05U 0.47U 62.4J 0.6J 0.7J 1.51 0.3J 1.7 1.3 NS 3.3J 1.91 0.04U 0.04U 1.5J 1.51 7.9J 2008-May 0.44U 0.5J 27.5J 1 0.6J 0.8J 0.2J 1.5 1.6 NS 5.2J 1.91 0.2J 0.11 0.8J 0.8J 4.5J 2008-Nov 0.11 1.11 62.5J 0.7J 0.3J 0.91 0.5J 1.3 2.8 NS 4J 1.6J 0.04U 0.04U 2.6J 2.6J 5.1J 2009-May 0.11 1.8J 26J 2.6 2.3 1.2J 0.10U 0.7 3.7 NS 2.1J 5.2J 0.04U 0.03U 3.5J 3.5J 9.4J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 2.1J 77.4J 0.2J 0.2J 2.5J 0.10U 0.91 0.8J NS 1.7J 5.2J 0.11 0.11 11 11 2.2J 2010-May 0.22U 0.7J 23.5J 0.5J 0.2J 0.7J 0.5J 0.7J 3.0J NS 3.2J 1.01 0.11 0.05U 3.8J 3.8J 2.2J 2010-Nov 0.22U 1.91 56.6J 0.3J 0.2J 0.8J 0.5J 0.5J 2.0J NS 3.9J 1.8J 0.03U 0.05U 3.3J 3.3J 5.6J 2011-May 0.191 0.36J 36J 0.16J 0.111 0.41J 0.44J 1.11 0.6J NS 1.2J 0.46J 0.02U 0.02U 1.2J 1.2J 2.6J 2011-Nov 0.14U 1.11 58.7J 0.26J 0.37J 0.48J 0.66J 0.89J 1.7J NS 1.4J 1.2J 0.02U 0.02U 2.5J 2.5J 3.2J 2012-May 0.12J 0.88J 68.3J 0.191 0.03U 0.38J 0.911 0.87J 1.11 NS 2.6J 1.7J 0.1U 0.35J 1.7J 1.7J 1.4J 2012-Nov 0.14J 0.74J 37.1J 0.18J 0.16J 0.31J 0.45J 1.01 1.11 0.02U 2.6J 1.2J 0.1U 0.07U 1.2J 1.2J 4.7J 2013-May 0.07J 0.02J 73.9J 0.04J 0.15J 0.20J 0.50J 0.96J 0.14J 0.04J 1.8J 1.6J 0.03U 0.04J 1.01 1.01 0.76J 2014-May 0.19 J 0.05 U 20.3 J 0.03 U 0.111 0.13 J 0.45 J 1.0 J 0.111 0.01 U 1.3 J 0.06 U 0.03 U 0.02 U 0.16 J 0.16 J 0.88 J 2014-Nov 16 0.86J 64.5J 0.04U 0.12J 0.33J 1.6J 0.94J 0.18J 0.06U 2.6J 3.0J 0.04U 0.13U 0.96J 0.96J 1.2J 2015-May 0.26J 2.2J 19.91 0.03J 0.13J 0.44J 0.17J 0.60J 0.34J 0.05U 1.6J 0.35J 0.01U 0.02U 1.01 1.01 3.3J 2015-Nov 0.95J 1.01 21.4J 0.04U 0.08J 0.30J 0.12U 1.6J 0.26J 0.05U 2.9J 0.23J 0.01U 0.02U 2.3J 2.3J 1.7J 2016-May 0.56J 2.7J 24.6J 0.07J 0.12J 0.20J 0.52J 3.0J 1.8J 0.04U 2.0J 0.54U 0.06U 0.05U 4.0J 4.0J 3.4J 2016-Nov 0.45J 1.91 49.4J 0.05J 0.13J 0.31J 0.53J 1.8J 0.69J 0.04U 3.8J 1.6J 0.06U 0.05U 2.0J 2.0J 1.8J 2017-May 0.66J 0.31J 31.4J 0.07U 0.11 0.24U 0.17J 3.0J 0.56J NS 2.4J 0.51U 0.20U 0.08U 2.8J 2.8J 1.8J 2017-Dec 0.37J 0.42J 25J 0.07U 0.08U 0.24U 0.111 1.7J 0.191 0.07U 2.7J 0.71J 0.20U 0.08U 1.11 1.11 4.3J 2018-Jun 0.41J 1.5J 33.7 0.05J 0.05J 0.2J 0.15U 1.3J 0.48J 0.07U 2J 0.56J US 0.05U 1.2 1.2 1.11 2018-Dec 0.52 J 0.96 J 38.5 0.05 U 0.14 J 0.27 J 0.77 J 1.9 J 0.28 J 0.05 U 3.1 J 1.9 J US U US U 1.8 1.8 8.1 J 2019-Jun 0.67J 0.68J 31.3 0.05U 0.07J 0.37J 0.18J 3.1J 0.6J 0.06J 2.4J 0.7J 0.05U 0.14J 0.05U 1.5 2.3J 3 of 53 Appendix B MW-IS Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May ND . ND .IA-Dioxane ND NS ND NS NS Groundwater Elevation -- 12 2001-Nov ND ND ND NS ND NS NS 10.83 2002-May ND ND ND NS ND NS NS 13.06 2002-Nov ND ND ND NS ND NS NS 12.35 2003-May ND ND ND NS ND NS NS 13.08 2003-Nov ND ND ND NS ND NS NS 13.57 2004-May ND ND ND NS ND NS NS 12.42 2004-Nov ND ND ND NS ND NS NS 12.01 2005-May ND ND ND NS ND NS NS 12.63 2005-Nov ND ND ND NS ND NS NS 13.5 2006-May ND ND ND NS ND NS NS 12.45 2006-Nov ND ND ND NS ND NS NS 13.71 2007-May ND ND ND NS ND NS NS 13.64 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov ND ND ND NS ND NS NS 11.03 2008-May ND ND ND NS ND NS NS 11.05 2008-Nov ND ND 1.0 J NS ND NS NS 11.77 2009-May ND ND ND NS ND NS NS 10.31 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 13.74 2010-May ND ND ND NS ND NS NS 11.87 2010-Nov 0.6 J ND ND NS ND NS NS 12.71 2011-May 0.3 J ND ND NS ND ND NS 11.97 2011-Nov ND ND ND NS ND ND NS 12.71 2012-May ND ND ND NS ND 1.8 NS 12.04 2012-Nov ND ND ND 100 U ND ND NS 12.71 2013-May ND ND ND 100 U ND ND NS 12.55 2014-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.31 2014-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.17 2015-May 0.24 U 0.27 U 0.25 U 104 J 0.63 U 0.39 U NS 14.21 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 15.71 2016-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 14.48 2016-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.31 2017-May 0.24U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.34 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.35 2018-Jun 0.24 U 0.21 U 0.25 U 147 J 0.63 U 0.39 U NS 13.81 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 5.33 14.17 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.62 J 2.71 U 12.80 4of53 Appendix B MW-2D Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 hmm 20 20 2,000 3 2001-May ND ND ND ND NCB 29 ND AU NS ND -mmmmIL- ND --Jmiliim� ND ND ND ND 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2003-May ND ND ND ND ND ND 24 ND ND NS ND ND ND ND ND ND ND 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2006-May ND ND ND ND ND ND 11 ND ND NS ND ND ND ND ND ND ND 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2007-May 0.05 U 0.47 U NS 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U ND 0.42 U 19 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2008-May 0.44 U 0.4 J 16 J 0.06 U 0.35 J 0.11 0.3 J 0.7 0.2 NS 1.4 J 0.2 J 0.04 U 0.04 U ND 0.07 U 2.2 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2009-May 0.06 J 1.2 J 1.8 J 0.06 U 3.6 0.4 J 1.7 J 5.5 0.7 NS 1.7 J 0.12 U 0.04 U 0.03 U ND 2.6 J 14 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2011-Nov 0.14 U 0.48 J 2.0 J 0.02 U 0.09 J 0.03 U 0.04 U 0.15 J 0.06 J NS 0.3 J 0.38 J 0.02 U 0.02 U ND 2.0 J 1.11 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2012-Nov 0.11 0.35J 1.8J 0.07U 0.03J 0.04J 0.18U 0.76J 0.07J 0.07J 1.11 0.55J 0.1U 0.07U 0.1U 1.51 1.8J 2013-May 0.04J 0.86J 16.5J 0.03J 0.39J 0.26J 0.7J 2.0J 0.33J 0.04J 1.6J 0.06J 0.03U 0.02U 0.24J 1.3J 5.4J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2015-May 0.21J 0.39J 6.1J 0.02U 0.23J 0.04J 0.31J 1.5J 0.05J NS 1.5J 0.71J 0.01U 0.04J ND 1.91 3.5J 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2017-May 0.08 J 0.07 U 15.1 J 0.07 U 0.23 J 0.24 U 0.63 J 1.4 J 0.27 J 0.07 U 1.3 J 0.51 U 0.20 U 0.08 U 0.14 J 2.0 J 5.4 J 2017-Dec 0.06 U 0.79 J 16.7 J 0.07 U 0.08 U 0.24 U 0.57 J 0.55 J 0.24 J 0.07 U 1.2 J 0.51 U 0.20 U 0.08 U 0.13 U 0.98 J 2.7 J 2018-Jun 0.04J 1.3J 19.8 0.11 0.091 0.51J 2J 1.11 0.98J 0.07U 2J 0.31J 0.05U 0.111 0.05U 2.7 5.7J 2018-Dec 0.03 U 0.91 J 15.6 0.05 U 0.02 U 0.12 J 0.35 J 0.35 J 0.03 U 0.05 U 1.11 0.19 J 0.05 U 0.05 U 0.05 U 0.03 U 1.8 J 2019-Jun 0.03 J 0.06 J 15.2 0.05 U 0.02 U 0.15 U 0.09 J 0.61 J 0.03 U 0.07 J 1.11 0.15 U 0.06 J 0.11 0.05 U 0.03 U 4.7 J 5 of 53 Appendix B MW-2D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 2001-May ND ND ND NS ND NS NS 9.11 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May ND ND ND NS ND NS NS 9.74 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May ND ND ND NS ND NS NS 9.47 2005-Nov NS NS NS NS NS NS NS NM 2006-May ND ND ND NS ND NS NS 9.45 2006-Nov NS NS NS NS NS NS NS NM 2007-May ND ND ND NS ND NS NS 9.85 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May ND ND ND NS ND NS NS 9.52 2008-Nov NS NS NS NS NS NS NS NM 2009-May ND ND ND NS ND NS NS 8.99 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov ND ND ND NS ND NS NS 9.47 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND 100 U ND ND NS 9.65 2013-May ND ND ND 100 U ND ND NS 9.42 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.59 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 9.94 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 9.80 2018-Jun 0.24 U 0.21 U 0.25 U 161 J 0.63 U 0.39 U NS 9.99 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 10.08 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 0.51 J 2.71 U 9.25 6 of 53 Appendix B MW-25 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled 2001-May Antimony ND Arsenic ND Barium IN ND Beryllium ND Cadmium AL ND CobaltCopper q%mor"016. ND Total ND ND 15 29 NS ND ND ND 0.2 ND NS 3 ND ND 2001-Nov ND ND ND ND ND ND ND ND 27 NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND 85 ND ND NS ND ND ND ND NS 124 99 2002-Nov ND ND ND ND ND 19 69 ND ND NS ND ND ND ND NS 98 57 2003-May ND ND ND ND ND 16 ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND 22 NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND ND 42 ND 20 NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND 11 33 ND ND NS ND ND ND ND NS 44 ND 2005-May ND ND ND ND ND ND 33 ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND 13 15 ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.4J 4.2J 96.9J 0.06U 0.3J 9.3J 0.5J 2 0.3 NS 3.6J 2.3J 0.04U 0.2J NS 0.91 3.3J 2008-May 0.44U 1.3J 51.8J 0.11 0.11 1.3J 0.6J 1 0.5 NS 2.1J 1.2J 0.11 0.11 NS 0.07U 1.91 2008-Nov 0.11 5.6J 165 0.06U 0.11 10 1.7J 1.2 0.4 NS 6J 4.8J 0.04U 0.11 NS 1.3J 2.4J 2009-May 0.11 2.2J 6.9J 0.06U 0.04U 5.81 0.7J 1.9 0.5 NS 1.8J 2.5J 0.04U 0.03U NS 1.81 5J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.11 0.8J 15.4J 0.91 0.4J 0.4J 0.10U 1.2J 3.9J NS 3.1J 1.91 0.2J 0.03U NS 3.5J 3J 2010-May 0.7J 1.7J 47.5J 0.11 0.8J 1.11 0.7J 0.91 1.11 NS 1.7J 3.5J 0.03U 0.05U NS 2.1J 5.8J 2010-Nov 0.22U 5.6J 149 0.11 0.6J 3.3J 0.6J 1.11 0.5J NS 6.2J 0.32U 0.03U 0.11 NS 0.6J 3.5J 2011-May 0.14U 3.1J 101 0.11 0.29J 3.7J 0.62J 1.5J 0.92J NS 3.1J 0.20U 0.02U 0.11 NS 0.94J 3.1J 2011-Nov 0.14U 0.91 34.3J 0.07J 0.17J 1.11 0.29J 0.49J 0.68J NS 1.2J 1.3J 0.02U 0.07J NS 0.75J 2.0J 2012-May 0.12J 6.1J 166 0.17J 0.25J 7.0J 1.7J 1.3J 1.3J NS 4.4J 13 0.1U 0.22J NS 2.0J 2.0J 2012-Nov 0.28J 91 152 0.091 0.18J 8.6J 1.91 1.3J 0.64J NS 6.6J 15 0.1U 0.101 NS 1.7J 4.6J 2013-May 0.091 5.3J 80.2J 0.101 0.29J 2.0J 0.57J 1.6J 0.55J NS 4.6J 14 0.03U 0.07J NS 0.62J 2.4J 2014-May 0.02 U 0.12 J 33.0 J 0.06 J 0.14 J 1.01 0.81 J 0/8 U 0.19 J NS 1.6 J 0.38 J 0.03 U 0.07 J NS 0.07 U 1.11 2014-Nov 0.16J 7J 273 0.111 0.44J 5.6J 3.5J 2.0J 83 NS 5.9J 0.16U 0.04U 0.13U NS 2.3J 3.2J 2015-May 0.03 J 0.15 J 34.3 J 0.08 J 0.13 J 0.29 J 0.14 J 0.36 J 0.27 J NS 0.57 J 0.22 U 0.01 U 0.06 J NS 0.59 J 0.37 J 2015-Nov 0.15J 1.2J 34.6J 0.07J 0.26J 0.39J 1.2J 2.7J 2.6J NS 1.3J 0.26J 0.01U 0.07J NS 2.8J 3.2J 2016-May 0.05 U 0.66 U 89.5 J 0.08 J 0.10 J 0.49 J 0.70 J 1.2 J 0.32 J NS 2.0 J 1.3 J 0.06 U 0.07 J NS 0.36 U 2.5 J 2016-Nov 0.07J 1.2J 55.2J 0.04U 0.101 1.7J 0.37J 0.34J 0.13J NS 2.6J 2.6J 0.06U 0.101 NS 0.39J 1.61U 2017-May 0.08 J 1.2 J 39.9 J 0.07U 0.13J 1.11 0.82 J 1.3 J 0.37 J 0.07 U 2.5 J 1.3 J 0.20 U 0.08U 0.13U 2.4 J 3.4 J 2017-Dec 0.17J 8.0J 281 0.18J 0.17J 4.1J 7.6J 2.7J 1.8J 0.07U 6.0J 0.5U 0.20U 0.08U 0.13U 5.3J 4.0J 2018-Jun 0.07 J 2 J 62.6 0.06 J 0.06 J 1.1 0.43 J 1.3 J 0.48 J 0.07 U 3.3 J 2.1 J 0.05 U 0.05 U 0.05 U 0.83 J 5.2 J 2018-Dec 0.16 J 4.1 J 135 0.05 U 0.111 1.4 3 J 1.5 J 0.41 J 0.05 U 3.9 J 4.6 J 0.05 U 0.08 J 0.05 U 1.2 2.3 J 2019-Jun 1 0.09 J 1 5.3 1 94.7 1 0.05 J 1 0.06 J 1 2 J 1.3 0.56 J 0.04 J 0.08 J 3.9 J 1.7 J 0.05 U 0.05 U 0.05 U 0.6 J 2.3 J 7 of 53 Appendix B MW-2S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May ND . ND .IA-Dioxane ND NS ND NS NS Groundwater Elevation -- 10.54 2001-Nov ND ND ND NS ND NS NS 9.7 2002-May ND ND ND NS ND NS NS 10.91 2002-Nov ND ND ND NS ND NS NS 9.95 2003-May ND ND ND NS ND NS NS 11.24 2003-Nov ND ND ND NS ND NS NS 11.06 2004-May ND ND ND NS ND NS NS 10.70 2004-Nov ND ND ND NS ND NS NS 10.18 2005-May ND ND ND NS ND NS NS 10.89 2005-Nov ND ND ND NS ND NS NS 11.55 2006-May ND ND ND NS ND NS NS 10.57 2006-Nov ND ND ND NS ND NS NS 11.29 2007-May ND ND ND NS ND NS NS 11.14 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov ND ND ND NS ND NS NS 9.56 2008-May ND ND ND NS ND NS NS 10.93 2008-Nov ND ND ND NS ND NS NS 10.32 2009-May ND ND ND NS ND NS NS 9.14 2009-Aug NS NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 11.65 2010-May ND ND ND NS ND NS NS 10.83 2010-Nov ND ND ND NS ND NS NS 11.43 2011-May ND ND ND NS ND 0.7 NS 10.56 2011-Nov ND ND ND NS ND ND NS 11.88 2012-May ND ND ND NS ND 2.4 NS 10.43 2012-Nov 0.6 J ND ND NS ND 8.5 NS 10.50 2013-May ND ND ND NS ND 1.8 NS 10.71 2014-May 0.24 U 0.27 U 0.27 U NS 0.63 U 1 NS 11.43 2014-Nov 0.60 J 0.27 U 0.27 U NS 0.63 U 17.7 NS 10.33 2015-May 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 12.14 2015-Nov 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.84 2016-May 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.73 2016-Nov 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.94 2017-May 0.24 U 0.27 U 0.27 U 100 U 0.63 U 1 NS 11.43 2017-Dec 0.24 U 0.21 U 0.21 U 100 U 0.63 U 13.1 NS 10.44 2018-Jun 0.24 U 0.21 U 0.21 U 100 U 0.63 U 1.1 NS 11.62 2018-Dec 0.24 U 0.02 U 0.02 U 100 U 0.12 U 4.85 6.2 11.08 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 3.94 11.9 10.69 8 of 53 Appendix B MW-3D Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina 0 ...- GWPS 1 10 71 1 10 1,000 15 1 20 20 2,000 2001-May lm, NS NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov 0.05U 0.6J 4.6J 0.06U 0.5J 0.41U 0.24U 1.3 0.1 NS 1.6J 0.14U 0.04U 0.04U NS 0.7J 3.6J 2008-May 0.1 J 7.3 J 394 0.06 U 0.11 13 1.5 J 1.3 0.1 NS 7.4 J 0.14 U 0.11 0.04 U NS 1.11 2.6 J 2008-Nov 0.05U 0.2J 5J 0.06U 0.04U 0.11 0.11U 1.3 0.1 NS 0.6J 0.3J 0.04U 0.04U NS 0.11 3.3J 2009-May 0.06J 0.5J 5.3J 0.06U 0.11 0.11 0.10U 0.7 0.04U NS 0.4J 0.3J 0.04U 0.03U NS 1.01 5.9J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov 0.14 U 0.36 J 7.6 J 0.02 U 0.24 J 0.05 J 0.15 J 0.52 J 0.08 J NS 0.71 J 0.20 U 0.02 U 0.02 U NS 0.4 J 1.7 J 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov 0.17 J 0.33 J 7.0 J 0.07 U 0.03 U 0.03 J 0.18 U 1.3 J 0.08 U 0.03 J 0.88J 0.52 J 0.1 U 0.07 U 0.17 J 0.1 U 2.5 J 2013-May 0.03J 0.51J 7.8J 0.03U 0.48J 0.08J 0.38J 1.6J 0.13J 0.05J 0.901 0.23J 0.03U 0.18J NS 0.93J 5.0J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.05 J 0.26 J 10.8 J 0.02 U 0.18 J 0.05J 0.40 J 0.92 J 0.07 J NS 0.68 J 0.22 U 0.01 U 0.03 J NS 0.26 J 3.3 J 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.06 U 0.40 J 11.8 J 0.07 U 0.40 J 0.24 U 0.58 J 1.6 J 0.16 J 0.07 U 0.83 J 0.51 U 0.20 U 0.08 U 0.28 J 1.6 J 5.2 J 2017-Dec 0.06 U 0.41 J 11.11 0.07 U 0.08 U 0.24 U 0.08 U 0.86 J 0.111 0.07 U 0.68 J 0.74 J 0.20 U 0.08 U 0.13 U 0.35 J 2.1 J 2018-Jun 0.07J 0.68J 11.4 0.06J 0.2J 0.26J 4.6J 1.8J 0.6J 0.07U 1.5J 0.3J 0.05U 0.05U 1.2J 3 6.8J 2018-Dec 0.04 J 0.12 J 10.1 0.05 U 0.02 U 0.08 J 0.15 U 0.54 J 0.03 U 0.05 U 1 J 0.6 J 0.05 U 0.05 U 0.05 U 0.03 U 1.8 J 2019-Jun 0.04 J 0.27 J 9.2 J 0.05 U 0.02 U 0.15 U 0.03 J 0.73 J 0.03 U 0.06 J 0.55 J 0.66 J 0.05 U 0.05 U 0.05 U 0.03 U 2.1 J 9 of 53 Appendix B MW-3D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov ND ND ND NS ND NS NS 9.06 2008-May ND ND ND NS ND NS NS 10.31 2008-Nov ND ND ND NS ND NS NS 9.83 2009-May ND ND ND NS ND NS NS 8.41 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS ND NS NM 2011-Nov ND ND ND NS ND NS NS 10.18 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND 100 U ND ND NS 10.47 2013-May ND ND ND 100 U ND ND NS 10.30 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.01 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS 100 U NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 100U 0.63 U 0.39 U NS 10.71 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 10.60 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.48 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 10.88 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.52 J 2.71 U 10.18 10of53 Appendix B MW-3S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony NS Arsenic NS Barium NS Beryllium NS Cadmium NS CobaltCopper NS Total NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov 0.11 6.7J 357 0.06U 0.7J 9.4J 1.2J 1.8 0.1 NS 5.9J 5.6J 0.04U 0.04U NS 1.7J 8J 2008-May 0.44U 0.4J 4J 0.06U 1 0.11 0.2J 0.8 0.04U NS 0.5J 0.3J 0.04U 0.04U NS 0.07U 1.6J 2008-Nov 0.11 8.4J 447 0.06U 0.04U 17 1.4J 1.3 0.1 NS 7.1J 9.8J 0.11 0.04U NS 1.51 3.3J 2009-May 0.06 J 7.0 J 460 0.06 U 0.11 12.6 1.6 J 1.4 0.04 U NS 5.4 J 8.2 J 0.04 U 0.03 U NS 2.7 J 5.9 J 2009-Aug 2.95 U 6.4 J 701 B 0.44 U 0.16 J 10.6 8.8 JB 3.64 J 6.79 U 0.024 U 3.47 J 17 8.22 JB 0.198 U 12.9 JB 0.586 U 1.29 U 2010-Jan 0.06J 6.8J 492 0.06U 0.04U 5.7J 11 1.91 0.11 0.03U 5.8J 0.12U 0.2J 0.03U 0.08U 2.3J 1.3J 2010-May 0.22U 9.2J 527 0.02U 0.3J 18 2J 1.11 0.11 0.08U 10.8J 11 0.11 0.05U 1.5J 2J 2.3J 2010-Nov 0.22 U 0.04 U 254 0.11 0.11 37 1.7 J 1.11 0.11 0.08 U 12.1 J 0.32 U 0.03 U 0.05 U 0.5 J 2.6 J 3.4 J 2011-May 0.14 U 3.8 J 242 0.02 U 0.07 J 14 0.76 J 1.3 J 0.16 J 0.05 U 3.3 J 3.5 J 0.02 U 0.02 U 0.23 J 1.4 J 3.6 J 2011-Nov 0.14U 4.9J 484 0.02U 0.12J 6.8J 1.7J 1.5J 0.42J 0.05U 4.3J 6.6J 0.04J 0.24J 0.26J 3J 2.7J 2012-May 0.27J 4.2J 342 0.07U 0.04J 2.6J 1.01 0.911 0.22J 0.091 3.6J 3.8J 0.1U 0.07U 0.15J 1.4J 0.72J 2012-Nov 0.16J 5.7J 425 0.07U 0.05J 15 1.5J 1.6J 0.31J 0.02J 5.8J 0.3J 0.1U 0.07U 0.13J 1.81 7.6J 2013-May 0.02 U 3.7 J 288 0.09 J 0.111 2.2 J 0.50 J 0.77 J 0.03 J 0.03 J 3.5 J 5.4 J 0.03 U 0.02 U 0.24 J 1.9 J 1.2 J 2014-May 0.02 U 3.8 J 343 0.03 U 0.19 J 5.9 J 1.8 J 1.11 0.16 J 0.01 U 3.1 J 2.9 J 0.03 U 0.02 U 0.06 U 1.3 J 2.6 J 2014-Nov 0.14J 91 675 0.04U 0.17J 2.6J 5.1J 1.5J 0.13U 0.06U 5.7J 0.16U 0.04U 0.13U 0.96J 2.5J 2.4J 2015-May 0.06J 6.1J 412 0.04J 0.03J 0.89J 2.6J 0.56J 0.16J 0.05U 2.3J 9.4J 0.01U 0.02U 0.13J 2.2J 0.94J 2015-Nov 0.16J 11 625 0.04J 0.04J 2.7J 7.3J 2.3J 0.091 0.05U 5.7J 0.79J 0.01U 0.02U 0.14J 3.2J 1.7J 2016-May 0.101 10 648 0.06J 0.05U 3.1J 9.8J 2.2J 0.24J 0.04J 4.5J 2J 0.06U 0.05U 0.111 3.4J 3.8J 2016-Nov 0.19 J 7 945 0.14 J 0.05 U 3.0 J 18 1.7 J 0.19 J 4.93 8.5 J 0.62 U 0.06 U 0.05 U 0.06 U 3.3 J 2.5 J 2017-May 0.15J 11 515 0.08J 0.08U 2.5J 13 2.0J 0.30J 0.07U 4.7J 0.51U 0.20U 0.08U 0.22J 5.3J 2.6J 2017-Dec 0.19 J 14 709 0.08 J 0.08 U 3.9 J 17 2.7 J 0.46 J 0.07 U 6.4 J 0.51 U 0.20 U 0.08 U 0.23 J 5.2 J 4.2 J 2018-Jun 0.21 J 25 879 0.07 J 0.02 U 4.7 24 2.6 J 0.13 J 0.07 U 7.9 J 0.15 U 0.05 U 0.05 U 0.05 U 5.8 1.11 2018-Dec 0.28 J 27 689 0.05 U 0.111 3 32 1.5 J 0.03 J 0.05 U 8.1 J NS 0.05 U 0.05 U 0.05 U 7.2 3.6 J 2019-Jun 0.17 J 1 20 1 502 1 0.06 J 1 0.02 U 1 24 2.9 1 2.2 J 1 0.03 U 1 0.13 J 1 5.6 J 1 14 1 0.05 U 1 0.05 U 0.05 U 5.9 2.8 J 11 of 53 Appendix B MW-3S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NS 2001-Nov NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov 1 0.4 J 0.2 J NS 0.4 NS NS 10.28 2008-May 1.1 0.4 J 0.2 J NS ND NS NS 11.02 2008-Nov 2.1 0.7 J 1.3 J NS 0.5 NS NS 10.56 2009-May 1.5 0.5 J 0.2 J NS ND NS NS 9.77 2009-Aug 1.3 ND 0.67 J 134 J ND NS NS 9.58 2010-Jan ND 0.4 0.3 J 100 U ND NS NS 11.42 2010-May 3.1 0.5 0.5 J 100 U ND NS NS 10.70 2010-Nov 2.1 0.3 J 0.3 J 1380 ND NS NS 11.14 2011-May 1 ND 0.3 J 544 J ND 2.5 NS 10.71 2011-Nov 1.1 ND ND 2795 N D 6.7 NS 11.29 2012-May 1 ND ND 137 J ND 4.4 NS 10.53 2012-Nov 1.2 ND ND 644 J ND 4.6 NS 10.68 2013-May ND 1 ND 272 J ND 5.6 NS 10.90 2014-May 1.1 0.27 U 0.25 U 467 J 0.63 U 6.5 NS 11.55 2014-Nov 2.1 0.27 U 0.25 U 100 U 2 15.6 NS 10.38 2015-May 1.5 0.27 U 0.25 U 100 U 0.63 U 16.9 NS 12.21 2015-Nov 1.7 0.27 U 0.25 U 100 U 0.63 U 20.9 NS 12.08 2016-May 1.3 0.27 U 0.25 U 100 U 0.63 U 14.4 NS 12.11 2016-Nov 1.2 0.30 J 0.25 U 100 U 0.63 U 10.6 NS 11.99 2017-May 2.8 0.27 U 0.25 U 100U 0.63 U 19.1 NS 11.86 2017-Dec 1.7 0.21 U 0.25 U 100 U 0.63 U 23.5 NS 11.74 2018-Jun 1.2 0.21 U 0.25 U 100 U 2.7 28.8 NS 12.12 2018-Dec 1.3 0.24 0.25 U 100 U 1.82 35.3 184 11.52 2019-Jun 0.89 J 0.11 J 0.25 U 100 U 0.12 U 26.6 176 11.12 12 of 53 Appendix B MW-3A Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 h1k 20 20 2,000 jib 2001-May lm, NS NS NS NS NS NS i�_ v� NS NS -mmmmmL- NS --jI�lll NS NS NS ___Jjg __ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 125 B 0.44 U 0.18 J 19.9 3.36 JB 2.35 J 6.79 U 0.024 U 2.36 U 4.14 J 7.15 JB 0.198 U 5.34 JB 0.586 U 1.29 U 2010-Jan 0.06J 2.6J 84.2J 0.11 0.2J 15 0.10U 1.3J 0.2J 0.09 2.6J 2.7J 0.11 0.11 0.08U 2.1J 3.1J 2010-May 0.22 U 1.01 42.7 J 0.02 U 0.11 3.8 J 0.11 4.0 J 0.01 U 0.08 U 1.5 J 1.01 0.03 U 0.05 U 3.9 J 0.8 J 2.9 J 2010-Nov 0.22U 5.4J 100 0.11 0.11 17 0.3J 0.5J 0.2J 0.08U 6.4J 8.8J 0.03U 0.05U 0.6J 1.6J 4.1J 2011-May 0.14U 0.93J 36J 0.02U 0.11 7.7J 0.3J 1.11 0.15J 0.05J 1.6J 1.11 0.02U 0.02U 0.32J 0.69J 3.2J 2011-Nov 0.14U 2.2J 70.7J 0.02U 0.36J 15 0.67J 0.88J 0.17J 0.05J 3.6J 2.3J 0.02U 0.14J 0.47J 0.88J 4.7J 2012-May 0.101 2.8J 86.6J 0.07U 0.08J 25 1.5J 0.85J 0.25J 0.04J 4.8J 4.3J 0.1U 0.101 0.24J 2.0J 5.7J 2012-Nov 0.50J 5.5J 120 0.07U 0.34J 28 2.3J 1.4J 0.35J 0.05J 8.8J 11 0.1U 0.13J 0.28J 1.6J 8.4J 2013-May 0.07 J 2.4 J 62.5 J 0.03 U 0.07 J 18 1.01 1.01 0.04 J 0.03 J 5.0 J 4.9 J 0.03 U 0.08 J 0.20 J 0.39 J 3.8 J 2014-May 0.03 J 0.05 U 28.6 J 0.03 U 0.15 J 0.28 J 0.29 J 0.54 J 0.06 J 0.01 U 1.5 J 0.06 U 0.03 U 0.06 J 0.06 J 0.07 U 1.4 J 2014-Nov 0.12U 4.5J 123 0.04U 0.12J 15 2.8J 0.74J 0.13U 0.06U 6.7J 7.2J 0.04U 0.13U 0.05U 0.14J 3.0J 2015-May 0.02 U 0.14 U 17.9 J 0.02 U 0.011 0.12 J 0.12 U 0.12 J 0.06 J 0.05 U 0.43 J 0.53 U 0.01 U 0.02 U 0.06 U 0.46 J 0.27 J 2015-Nov 0.24J 8J 145 0.04J 0.15J 11 5.1J 1.3J 0.28J 0.05U 9.7J 0.22U 0.03J 0.16J 0.35J 1.51 6.9J 2016-May 0.05 U 1.5 J 78.9 J 0.05 J 0.07 J 7.6 J 1.01 1.3 J 0.34 J 0.04 U 2.6 J 1.11 0.06 U 0.05 U 0.06 U 1.51 3.7 J 2016-Nov 0.111 6.8J 198 0.08J 0.08J 6.2J 4.1J 1.11 0.26J 0.04U 5.5J 9.7J 0.06U 0.05U 0.06U 1.91 2.6 J 2017-May 0.191 11 191 0.091 0.08U 8.6J 8.7J 1.5J 0.42J 0.07U 6.2J 0.51U 0.20U 0.08U 0.21J 4.3J 3.7J 2017-Dec 0.2 J 13 253 0.07 J 0.09 J 9.5 J 10 2.2 J 0.78 J 0.07 U 7.4 J 0.5 U 0.20 U 0.08 U 0.24 J 4.1 J 8.2 J 2018-Jun 0.06J 4.4J 56.1 0.12J 0.06J 2.1 2.5J 1.11 0.911 0.07U 1.8J 2.5J 0.05U 0.05U 0.05U 4 3.2J 2018-Dec 0.2 J 21 312 0.05 U 0.04 J 8.3 13 1.2 J 0.04 J 0.05 U 7.1 J NS 0.05 U 0.05 U 0.05 U 3.1 3.1 J 2019-Jun 0.14 J 11 238 0.06 J 0.02 U 9.3 6 1 J 0.03 U 0.05 U 4.9 J 4 J 0.05 U 0.05 U 0.05 U 2.5 3.11 13 of 53 Appendix B MW-3A Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 7.78 2010-Jan ND ND ND 100 U ND NS NS 11.12 2010-May ND ND ND 100 U ND NS NS 10.36 2010-Nov 0.9 J ND ND 100 U ND NS NS 10.61 2011-May ND ND ND 100 U ND ND NS 10.39 2011-Nov 0.6 J ND ND 100 U ND 3.3 NS 10.83 2012-May 0.60 J ND ND 100 U ND 5.1 NS 10.31 2012-Nov 0.70 J ND ND 100 U ND 3.8 NS 10.50 2013-May 0.30 J ND ND 100 U ND 2.4 NS 10.42 2014-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 11.13 2014-Nov 0.50 J 0.27 U 0.25 U 100 U 0.63 U 5.7 NS 10.03 2015-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 11.73 2015-Nov 1.7 0.27 U 0.25 U 100 U 0.63 U 8.6 NS 11.66 2016-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 1.3 NS 11.81 2016-Nov 0.80 J 0.27 U 0.25 U 100 U 0.63 U 6.1 NS 11.53 2017-May 2 0.27 U 0.25 U 100U 0.63U 12.7 NS 11.43 2017-Dec 2.7 0.21 U 0.25 U 100 U 0.63 U 19.1 NS 11.17 2018-Jun 0.5 J 0.21 U 0.25 U 100 U 0.63 U 4.5 NS 12.35 2018-Dec 1.69 0.13 J 0.25 U 100 U 1.09 24.4 87 11.19 2019-Jun 1 0.13 J 0.25 U 100 U 0.12 U 8.44 66.9 10.73 14of53 Appendix B MW-4 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled 2001-May Antimony ILML ND Arsenic ND Barium IN ND Beryllium ND Cadmium AL ND CobaltCopper ND Total 0 ND ND 15 ND NS ND ND ND 0.2 ND NS 3 ND ND 2001-Nov ND ND ND ND ND ND 29 ND 11 NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND 42 ND 13 NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND ND 13 ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND 2 ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND ND 12 ND 25 NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND ND 25 ND 19 NS ND ND ND ND NS 45 ND 2005-May ND ND ND ND ND ND 30 ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND ND ND 14 NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 100 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05 U 1.3 J 207 0.8 J 0.5 J 1.01 2.7 J 2.3 7.2 NS 2.7 J 0.14 U 0.04 U 0.04 U NS 6.9 J 16 2008-May 0.11 1.01 203 0.4J 0.2J 1.01 1.2J 0.7 4.8 NS 2.3J 0.91 0.11 0.11 NS 3.4J 7.8J 2008-Nov 0.11 0.3J 196 0.2J 0.3J 0.4J 1.01 0.9 3.4 NS 1.7J 0.14U 0.04U 0.04U NS 3.1J 5.3J 2009-May 0.7J 2.8J 266 0.91 0.91 1.3J 2.1J 1.8 11 NS 1.2J 0.5J 0.11 0.03U NS 10.01 12 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 2.8J 165 1 0.3J 0.91 2.8J 1.8J 14 NS 2.1J 0.2J 0.11 0.11 NS 11.4J 16 2010-May 0.22U 2.6J 202 0.8J 1.2 0.91 2.1J 1.4J 6.3J NS 2.0J 1.11 0.11 0.11 NS 8.3J 8.5J 2010-Nov 0.22U 2.3J 141 0.7J 0.5J 1.11 3.1J 1.3J 6.4J NS 2.1J 0.7J 0.03U 0.11 NS 9.4J 8.1J 2011-May 0.14U 1.6J 174 0.57J 0.35J 0.58J 3J 1.91 4.8J NS 1.4J 0.73J 0.02U 0.03J NS 7.5J 6.1J 2011-Nov 0.14U 1.91 183 0.65J 0.43J 0.76J 3.7J 1.11 7.3J NS 1.8J 0.61J 0.02U 0.05J NS 8.5J 9.4J 2012-May 0.15J 2.9J 278 0.50J 0.16J 0.63J 5.7J 1.8J 7.6J NS 1.7J 1.6J 0.1U 0.07U NS 7.2J 4.7J 2012-Nov 0.14J 0.91 151 0.47J 0.22J 0.38J 3.6J 0.88J 3.1J NS 1.8J 1.2J 0.1U 0.07U NS 5.81 6.7J 2013-May 0.02 U 0.83 J 108 0.03 U 0.09 J 0.35 J 2.2 J 0.61 J 0.29 J NS 1.8 J 1.11 0.03 U 0.02 U NS 3.3 J 1.6 J 2014-May 0.02 U 0.05 U 80.2 J 0.23 J 0.08 J 0.30 J 1.9 J 0.31 J 0.74 J NS 0.87 J 0.06 U 0.03 U 0.02 U NS 3.2 J 1.8 J 2014-Nov 0.78J 0.66J 7.3J 0.04U 0.04U 0.13J 0.14U 5.5J 0.31J NS 1.5J 2.6J 0.06J 0.13U NS 0.44J 50 2015-May 0.23J 1.7J 151 0.55J 0.33J 0.80J 3.0J 0.911 3.8J NS 2.0J 1.4J 0.02J 0.05J NS 6.3J 8.3J 2015-Nov 0.191 3.6J 109 0.30J 0.21J 1.3J 3.3J 1.01 2.0J NS 2.5J 1.8J 0.02J 0.05J NS 5.3J 5.9J 2016-May 0.05 U 2.1 J 68.1 J 0.18 J 0.08 J 0.38 J 1.9 J 0.50 J 0.87 J NS 1.3 J 0.76 J 0.06 U 0.05 U NS 3.4 J 3.4 J 2016-Nov 0.05 U 0.91 J 123 0.15 J 0.09 J 0.33 J 2.0 J 0.36 J 0.45 J NS 2.4 J 1.7 J 0.06 U 0.05 U NS 2.7 J 1.8 J 2017-May 0.06U 0.75 J 149 0.17 J 0.09 J 0.36 J 2.0 J 0.53 J 1.7 J NS 2.1 J 1.0 J 0.20 U 0.08 U NA 5.9 J 3.3 J 2017-Dec 0.06J 0.74J 68.7J 0.31J 0.111 0.51J 3.2J 0.92J 1.91 0.07U 1.5J 0.59J 0.20U 0.08U 0.13U 4.6J 5.6J 2018-Jun 0.07J 1.11 93.2 0.26J 0.091 0.46J 2.4J 11 1.8J 0.07U 1.7J 0.79J 0.05U 0.06J 0.05U 5.1 3.3J 2018-Dec 0.08 J 0.48 J 52.5 0.11 0.14 J 0.22 J 4.4 J 0.65 J 0.28 J 0.05 U 1.5 J 0.74 J 0.05 U 0.05 U 0.24 J 5 4 J 2019-Jun 0.06J 1.5J 167 0.13J 0.07J 3.8J 0.57J 0.39J 0.05J 0.11 1.91 1.11 0.07J 0.16J 0.05U 2.7 3.5J 15 of 53 Appendix B MW-4 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May ND . ND .IA-Dioxane ND NS ND NS NS Groundwater Elevation -- 11.48 2001-Nov ND ND ND NS ND NS NS 10.95 2002-May ND ND ND NS ND NS NS 11.80 2002-Nov ND ND ND NS ND NS NS 11.66 2003-May ND ND ND NS ND NS NS 11.82 2003-Nov ND ND ND NS ND NS NS 11.96 2004-May ND ND ND NS ND NS NS 11.62 2004-Nov ND ND ND NS ND NS NS 11.46 2005-May ND ND ND NS ND NS NS 11.69 2005-Nov ND ND ND NS ND NS NS 12.02 2006-May ND ND ND NS ND NS NS 11.68 2006-Nov ND ND ND NS ND NS NS 11.99 2007-May ND ND ND NS ND NS NS 11.92 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov ND ND ND NS ND NS NS 10.74 2008-May ND ND ND NS ND NS NS 11.84 2008-Nov ND ND ND NS ND NS NS 11.62 2009-May ND ND ND NS ND NS NS 10.03 2009-Aug NS NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 12.19 2010-May ND ND ND NS ND NS NS 11.62 2010-Nov ND ND ND NS ND NS NS 11.61 2011-May ND ND ND NS ND ND NS 11.49 2011-Nov ND ND ND NS ND ND NS 11.92 2012-May ND ND ND NS ND 1.4 NS 11.49 2012-Nov ND ND ND NS ND ND NS 11.80 2013-May ND ND ND NS ND ND NS 11.85 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.86 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.70 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.1 NS 12.03 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.59 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.26 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 11.87 2017-May 0.24U 0.27 U 0.25 U NS 0.63U 0.5 NS 11.86 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.12 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.87 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 9.70 2019-Jun 0.3 J 0.02 J 0.25 U 100 U 0.12 U 2.44 2.71 U 11.62 16 of 53 Appendix B MW-5 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 71 1 1,000 15 1 20 20 0.2 2,000 3 2001-May lm, NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND 21 ND ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND 12 ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND 29 ND ND ND NS ND ND ND ND NS ND ND 2006-May ND 5.3 ND ND ND 17 ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND 5 J ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05U 5.3J 115 0.11 0.6J 2.3J 0.4J 1.6 0.4 NS 9.11 2.3J 0.04U 0.04U NS 1.6J 5.9J 2008-May 0.5J 5.0J 101 0.11 0.11 1.7J 1.2J 0.9 0.4 NS 4.3J 2.5J 0.11 0.11 NS 1.2J 4.1J 2008-Nov 0.11 2.1J 48.3J 0.11 0.04U 0.5J 1.11 3.3 0.6 NS 3.4J 1.2J 0.11 0.04U NS 1.8J 3.9J 2009-May 0.2J 1.3J 117 0.5J 0.3J 1.2J 0.7J 2.6 0.2 NS 2.5J 1.5J 0.04U 0.03U NS 1.6J 3.3J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.5 5.8J 83.8J 1 0.6J 1.6J 2.7J 1.6J 1.5J NS 4.8J 5.0J 0.11 0.11 NS 5.1J 4.8J 2010-May 0.22U 3.9J 92.1J 0.5J 0.3J 2.8J 2.3J 1.11 0.7J NS 7.1J 7.3J 0.11 0.05U NS 2.3J 4.3J 2010-Nov 0.6J 0.04U 129 1 2 7.8J 11 3.9J 3.9J NS 16.8J 0.32U 0.11 0.51 NS 3.2J 14 2011-May 0.4J 6.4J 80.5J 0.92J 0.64J 1.51 6.2J 4.4J 3.0J NS 5.5J 4.9J 0.02U 0.07J NS 4.3J 7.4J 2011-Nov 0.55J 3.3J 150 0.24J 0.69J 1.6J 9.5J 7.1J 2.1J NS 6.9J 5.9J 0.02U 0.16J NS 2.4J 7.7J 2012-May 0.36J 6.8J 122 0.50J 0.22J 1.7J 6.1J 3.4J 3.5J NS 4.7J 5.0J 0.1U 0.07U NS 5.6J 6.6J 2012-Nov 0.5J 1.91 117 0.13J 0.12J 1.11 5.2J 4.2J 1.4J NS 5.4J 4.3J 0.1U 0.07U NS 2.0J 5.8J 2013-May 0.34J 2.4J 115 0.23J 0.20J 1.6J 4.8J 4.8J 1.5J NS 5.6J 4.4J 0.03U 0.07J NS 3.5J 6.1J 2014-May 0.34J 0.28J 67.9J 0.03U US 0.34J 3.1J 4.0J 0.51J NS 2.2J 0.06U 0.03U 0.02J NS 1.11 2.0J 2014-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2015-May 0.52 J 11 130 0.02 U 0.62 J 2.6 J 9.3 J 3.5 J 3.9 J NS 6.4 J 0.53 U 0.02 J 0.07 J NS 5.5 J 15 2015-Nov 1.4J 3.5J 233 0.08J 0.38J 1.51 9.8J 4.9J 0.65J NS 10.11 10 0.03J 0.091 NS 1.2J 6.6J 2016-May Dry Dry Dry Dry Dry Dry Dry Dry Dry NS Dry Dry Dry Dry NS Dry Dry 2016-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry NS Dry Dry Dry Dry NS Dry Dry 2017-May 0.44J 5.1J 187 0.46J 0.88J 2.9J 13 5.5J 7.8J NS 8.7J 3.6J 0.20U 0.111 NA 17.2J 27 2017-Dec 0.69J 2.1J 76.1J 0.07U 0.08U 0.991 6.7J 3.6J 0.3J 0.07U 4.4J 3.8J 0.20U 0.08U 0.13U 3.0J 2.7J 2018-Jun 0.18J 5J 82.5 0.13J 0.12J 1.1 4.9J 1.6J 1.11 0.07U 3.6J 2.2J 0.05U 0.05U 0.05U 4.6 4.5J 2018-Dec 0.18 J 4.1 J 140 0.05 U 0.08 J 1.2 3.3 J 0.87 J 0.16 J 0.05 U 3.9 J 4.4 J 0.05 U 0.05 U 0.55 J 1.3 3.5 J 2019-Jun 1 0.26 J 1 7 1 280 1 0.09 J 1 0.14 J 1 7.5 1 4 1.1 J 0.03 U 0.1 J 7.9 J 3.8 J 0.05 U 0.13 J 0.05 U 2.8 4.7 J 17 of 53 Appendix B MW-5 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov ND ND ND NS ND NS NS 10.92 2003-May ND ND ND NS ND NS NS 11.72 2003-Nov ND ND ND NS ND NS NS 11.52 2004-May ND ND ND NS ND NS NS 11.29 2004-Nov ND ND ND NS ND NS NS 10.78 2005-May ND ND ND NS ND NS NS 11.29 2005-Nov ND ND ND NS ND NS NS 11.80 2006-May ND ND ND NS ND NS NS 11.10 2006-Nov ND ND ND NS ND NS NS 11.58 2007-May ND ND ND NS ND NS NS 11.59 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov ND ND ND NS ND NS NS 10.47 2008-May ND ND ND NS ND NS NS 11.30 2008-Nov ND ND ND NS ND NS NS 10.90 2009-May ND ND ND NS ND NS NS 10.14 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 12.04 2010-May ND ND ND NS ND NS NS 11.33 2010-Nov ND ND ND NS ND NS NS 11.70 2011-May ND ND ND NS ND 0.9 J NS 11.19 2011-Nov ND ND ND NS ND ND NS 11.64 2012-May ND ND ND NS ND 1.7 NS 11.10 2012-Nov ND ND ND NS ND ND NS 11.32 2013-May ND ND ND NS ND ND NS 11.45 2014-May 0.24 U 0.27 U 0.25U NS 0.63 U 0.39 U NS 11.60 2014-Nov Damaged Damaged Damaged NS Damaged Damaged NS Damaged 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.08 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 13.47 2016-May Dry Dry Dry NS Dry Dry NS Dry 2016-Nov Dry Dry Dry NS Dry Dry NS Dry 2017-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.5 NS 12.66 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.95 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 1.3 NS 12.45 2018-Dec 0.24 U 0.02 U 0.25 U 390 J 0.12 U 2.27 16.4 12.30 2019-Jun 0.24 U 1 0.07 J 0.25 U 100 U 0.12 U 6.8 74.2 11.90 18 of 53 Appendix B MW-6 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium AL ND CobaltCopper ND Total ND ND ND NS ND ND ND 0.2 ND NS ND ND 2001-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND 11 ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND 52 11 ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND 23 15 ND ND NS ND ND ND ND NS ND ND 2004-Nov ND 14 ND ND ND ND 22 ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND 15 20 ND ND NS ND ND ND ND NS ND ND 2005-Nov ND 22 ND ND ND ND 11 ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND 11 ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND ND 12 ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 112 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.2J 16 233 0.91 0.6J 6.3J 13 6.7 5.9 NS 9.11 7.9J 0.04U 0.2J NS 17J 20 2008-May 0.2J 5.3J 65J 0.11 0.4J 1.7J 3.1J 2.1 0.5 NS 3.2J 1.7J 0.11 0.2J NS 4.6J 3.0J 2008-Nov 0.2J 11 161 0.11 0.4J 4.4J 4.7J 2.8 0.4 NS 6.1J 5.3J 0.04U 0.11 NS 4.2J 3.6J 2009-May 0.11 2.9J 56.1 0.11 0.91 1.11 2.5J 2.3 0.3 NS 1.01 0.5J 0.04U 0.03U NS 7.5J 2.5J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 6.4J 137 0.11 0.3J 0.6J 0.8J 1.11 0.5J NS 1.11 2.0J 0.11 0.03U NS 11.6J 3.9J 2010-May 0.22U 6.1J 215 0.11 2.2 5.4J 4.2J 2.4J 0.2J NS 7.5J 7.5J 0.03U 0.05U NS 5.81 3.3J 2010-Nov 0.22U 4.8J 155 0.11 0.6J 0.7J 2J 1.5J 0.3J NS 5.7J 7.2J 0.11 0.11 NS 4.4J 4.5J 2011-May 0.14U 2.2J 124 0.02U 0.43J 1.4J 2.4J 1.6J 0.18J NS 2J 1.3J 0.02U 0.91 NS 3.9J 1.8J 2011-Nov 0.14U 2.4J 157 0.06J 0.29J 1.11 2.7J 1.7J 0.24J NS 2.7J 1.6J 0.02U 0.08J NS 3.3J 3.3J 2012-May 0.17J 2.2J 128 0.07U 0.27J 1.3J 2.5J 2.2J 0.39J NS 2.9J 1.5J 0.1U 0.101 NS 3.0J 0.911 2012-Nov 0.07J 2.4J 53.4J 0.091 0.12J 0.55J 1.8J 1.2J 0.55J NS 1.4J 0.64J 0.1U 0.07U NS 4.7J 4.9J 2013-May 0.07J 2.4J 209 0.16J 0.31J 3.0J 3.2J 1.8J 0.05J NS 4.3J 2.7J 0.03U 0.101 NS 1.51 0.911 2014-May 0.02 U 0.05 U 110 0.05 J 0.31 J 0.22 J 0.38 J 0.52 J 0.04 J NS 0.71 J 0.06 U 0.03 U 0.02 U NS 0.34 J 0.84 J 2014-Nov 0.18J 3.4J 246 0.04U 0.20J 2.8J 2.6J 0.61J 0.13U NS 3.1J 1.7J 0.04U 0.13U NS 1.2J 0.54J 2015-May 0.08J 1.3J 271 0.15J 0.48J 0.911 0.86J 0.84J 0.091 NS 1.7J 0.46J 0.01U 0.101 NS 1.11 2.5J 2015-Nov 0.24J 3.6J 131 0.05J 0.45J 1.11 1.3J 1.91 0.191 NS 2.3J 0.81J 0.011 0.06J NS 4.1J 6.2J 2016-May 0.12J 5.2J 561 0.07J 0.48J 4.5J 4.0J 2.5J 0.14J NS 5.5J 3.2J 0.06U 0.18J NS 4.9J 3.2J 2016-Nov 0.08J 13 336 0.13J 0.18J 2.5J 4.8J 1.01 0.66J NS 3.6J 6.3J 0.06U 0.05U NS 5.6J 1.91 2017-May 0.06U 6.4J 98.1J 0.18J 0.25J 1.4J 3.4J 1.5J 2.2J NS 1.8J 0.52J 0.20U 0.08U NA 17.9J 6.1J 2017-Dec 0.11 J 10 633 0.07 U 0.08 U 2.9 J 7.7 J 1.6 J 0.35 J 0.07 U 4.9 J 0.5 U 0.20 U 0.08 U 0.14 J 7.5 J 2.8 J 2018-Jun 0.08J 1.2J 348 0.05U 0.15J 1.6 1.3J 1.4J 0.07J 0.07U 3.6J 2.5J US 0.11 0.05U 1.2 0.11U 2018-Dec 0.19 J 5.7 470 0.05 U 0.17 J 2.9 4.3 J 1.3 J 0.03 U 0.06 J 6.3 J 3.7 J US U US U 0.05 U 2 2.3 J 2019-Jun 0.15 J 11 776 0.07 J 0.13 J 7.1 3.5 0.98 J 0.03 U 0.16 J 6.2 J 4 J US U US U US U 6.2 2.2 J 19 of 53 Appendix B MW-6 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May ND . ND .IA-Dioxane ND NS ND NS NS Groundwater Elevation -- 10.19 2001-Nov ND ND ND NS ND NS NS 9.57 2002-May ND ND ND NS ND NS NS 10.3 2002-Nov ND ND ND NS ND NS NS 9.73 2003-May ND ND ND NS ND NS NS 10.57 2003-Nov ND ND ND NS ND NS NS 10.75 2004-May ND ND ND NS ND NS NS 10.48 2004-Nov ND ND ND NS ND NS NS 10.16 2005-May ND ND ND NS ND NS NS 10.66 2005-Nov ND ND ND NS ND NS NS 11.03 2006-May ND ND ND NS ND NS NS 10.4 2006-Nov ND ND ND NS ND NS NS 10.95 2007-May ND ND ND NS ND NS NS 10.85 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov 0.2 J ND ND NS ND NS NS 9.65 2008-May ND ND ND NS ND NS NS 10.58 2008-Nov ND ND ND NS ND NS NS 10.19 2009-May ND ND ND NS ND NS NS 9.35 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 11.07 2010-May ND ND ND NS ND NS NS 10.64 2010-Nov ND ND ND NS ND NS NS 10.88 2011-May ND ND ND NS ND 2.3 NS 10.40 2011-Nov ND ND ND NS ND 1.9 NS 10.61 2012-May ND ND ND NS ND 2.7 NS 10.3 2012-Nov ND ND ND NS ND ND NS 10.49 2013-May ND ND ND NS ND 4.4 NS 10.44 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.13 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 3.4 NS 10.68 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.9 NS 11.58 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.8 0.39 U NS 11.49 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 8.2 NS 11.50 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 5.6 NS 11.71 2017-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 11.28 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 12.3 NS 10.88 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 5.6 NS 11.38 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.181 6.88 13.5 10.98 2019-Jun 0.24 U 0.02 J 0.25 U 100 U 0.12 U 14.4 40.1 10.61 20 of 53 Appendix B MW-7 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPSLL Antimony 11117=1 Arsenic ND Barium IN ND Beryllium ND Cadmium AL ND CobaltCopper ND Total 10 ND ND ND NS ND ND ND 0.2 ND NS ND ND 2001-May ND 2001-Nov ND ND ND ND ND ND 15 ND ND NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND 17 ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND 6.4 J ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-Nov ND 3.6 ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND 40 ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 144 0.08 U 0.06 U 12 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05U 6.4J 136 0.11 0.4J 17 1.3J 2.7 0.3 NS 7.5J 6.0J 0.04U 0.04U NS 2.5J 3.4J 2008-May 0.2J 3.6J 31J 0.11 0.04U 2.6J 1.11 2 0.7 NS 2.0J 1.7J 0.04U 0.11 NS 3.1J 3.4J 2008-Nov 0.11 3.3J 103 0.11 0.04U 2.8J 1.11 3 0.3 NS 4.6J 5.9J 0.11 0.11 NS 1.3J 3.0J 2009-May 0.06J 1.01 31J 0.11 0.8J 2.3J 0.5J 1.6 0.1 NS 0.91 0.8J 0.04U 0.03U NS 1.81 2.8J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 0.5J 29.1J 0.06U 0.2J 1.11 0.10U 2.4J 0.11 NS 0.6J 0.2J 0.3J 0.03U NS 0.8J 1.5J 2010-May 0.22U 4.5J 266 0.11 2 9.01 2.5J 2.9J 0.11 NS 10.4J 9.8J 0.03U 0.5J NS 1.3J 3.8J 2010-Nov 0.22U 0.91 34.3J 0.11 0.4J 0.8J 0.4J 0.8J 0.2J NS 1.7J 1.11 0.11 0.05U NS 1.11 4.3J 2011-May 0.14U 1.5J 174 0.02U 0.4J 4.2J 1.2J 1.5J 0.12J NS 2.3J 3J 0.02U 0.24J NS 0.75J 2.4J 2011-Nov 0.14U 0.81J 67.4J 0.06J 0.38J 1.2J 0.92J 0.93J 0.29J NS 1.5J 1.11 0.02U 0.08J NS 1.2J 1.8J 2012-May 0.16J 2.3J 294 0.07U 0.12J 3.6J 2.0J 1.91 0.33J NS 4.3J 4.3J 0.1U 0.26J NS 1.3J 0.66J 2012-Nov 0.15J 0.72J 100 0.07U 0.16J 1.3J 1.5J 1.91 0.20J NS 2.5J 1.91 0.1U 0.29J NS 0.52J 4.6J 2013-May 0.02 U 5.0 J 560 0.03 U 0.14 J 9.2 J 7.4 J 1.9 J 0.08 J NS 5.5 J 9.9 J 0.03 U 0.20 J NS 1.3 J 1.01 2014-May 0.12J 2.1J 291 0.04J 0.29J 5.2J 6.1J 1.7J 0.14J NS 3.5J 3.4J 0.03U 0.26J NS 1.3J 1.91 2014-Nov 0.22J 4.1J 398 0.04U 0.26J 5.01 11 4.8J 0.22J NS 6.0J 0.44U 0.04U 0.13U NS 1.3J 1.4J 2015-May 0.22J 5J 819 0.06J 0.44J 18 18 1.6J 0.25J NS 6.8J 0.53U 0.02J 0.101 NS 2.9J 2.5J 2015-Nov 0.27J 2.9J 294 0.05J 0.35J 4.1J 9.91 5.6J 0.35J NS 5.4J 9.6J 0.01U 0.04J NS 1.91 6.1J 2016-May 0.13J 5.6J 751 0.07J 0.15J 16 18 1.91 0.27J NS 6.3J 9.91 0.06U 0.091 NS 3.0J 2.3J 2016-Nov 0.12J 5.1J 411 0.101 0.30J 3.3J 8.8J 4.1J 0.24J NS 10.4J 0.62U 0.06U 0.05U NS 1.6J 2.7J 2017-May 0.08 J 4.0 J 367 0.07 J 0.11 8.3 J 8.9 J 1.2 J 0.44 J NS 4.2 J 5.0 J 0.20 U 0.08 U NA 4.3 J 2.8 J 2017-Dec 0.12J 0.47U 312 0.07U 0.091 3.5J 8.2J 4.6J 0.24J 0.07U 5.1 J 0.5U 0.20U 0.08J 0.13U 1.11 1.11 2018-Jun 0.06 J 1.9 J 132 0.05 U 0.06 J 2.4 2.7 J 0.65 J 0.14 J 0.07 U 2 J 2.7 J US U 0.06 J US U 1.3 0.19 J 2018-Dec 0.17 J 15 566 0.07 J 0.16 J 12 12 1.2 J 0.2 J 0.05 U 6.3 J NS US U US U US U 2.4 3.4 J 2019-Jun 1 0.1 J 9 524 0.06 J 0.02 U 14 8 2 J 0.03 U 0.05 J 4.9 J 5.6 J 0.06 J 0.05 U 0.05 U 2.9 5.6 J 21 of 53 Appendix B MW-7 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May ND . ND .IA-Dioxane ND NS ND NS NS Groundwater Elevation -- 10.74 2001-Nov ND ND ND NS ND NS NS 10.08 2002-May ND ND ND NS ND NS NS 10.89 2002-Nov ND ND ND NS ND NS NS 10.33 2003-May ND ND ND NS ND NS NS 10.92 2003-Nov ND ND ND NS ND NS NS 11.24 2004-May ND ND ND NS ND NS NS 10.90 2004-Nov ND ND ND NS ND NS NS 10.61 2005-May ND ND ND NS ND NS NS 11.10 2005-Nov ND ND ND NS ND NS NS 11.42 2006-May ND ND ND NS ND NS NS 10.89 2006-Nov ND ND ND NS ND NS NS 11.41 2007-May ND ND ND NS ND NS NS 11.40 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov 0.3 J ND ND NS ND NS NS 9.98 2008-May ND ND ND NS ND NS NS 11.00 2008-Nov ND ND ND NS ND NS NS 10.72 2009-May ND ND ND NS ND NS NS 9.51 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 11.60 2010-May ND ND ND NS ND NS NS 11.06 2010-Nov ND ND ND NS ND NS NS 11.24 2011-May ND ND ND NS ND 4.5 NS 10.85 2011-Nov ND ND ND NS ND ND NS 11.14 2012-May ND ND ND NS ND 6.4 NS 10.79 2012-Nov ND ND ND NS ND 1.2 NS 10.79 2013-May ND 0.40 J ND NS ND 20.9 NS 11.08 2014-May 0.30 J 0.27 U 0.25 U NS 0.63 U 10.8 NS 10.70 2014-Nov 0.30 J 0.27 U 0.25 U NS 0.63 U 7.1 NS 11.75 2015-May 0.60 J 0.27 U 0.25 U NS 0.63 U 34.7 NS 11.89 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 1.6 NS 12.02 2016-May 0.40 J 0.27 U 0.25 U NS 0.63 U 29.7 NS 11.98 2016-Nov 0.40 J 0.27 U 0.25 U NS 0.63 U 16.3 NS 11.95 2017-May 0.24U 0.27 U 0.25 U NS 0.63 U 12.8 NS 11.48 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 3 NS 11.69 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 6.3 NS 11.65 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 1.25 32 18.2 11.45 2019-Jun 0.31 J 0.02 J 0.25 U 100 U 0.12 U 27 17 10.65 22 of 53 Appendix B MW-8 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPSLk. Antimony Arsenic NS Barium NS Beryllium NS Cadmium AL NS CobaltCopper -Wlmnr"016� NS Total NS NS NS NS NS NS NS NS NS WMMMEU NS NS 2001-May NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND 13 ND ND ND ND ND ND 2.8J NS ND ND ND ND NS 115 134 2003-Nov ND ND ND ND ND ND 122 ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND ND 10 ND ND NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND ND 25 ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND 43 ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 38 0.24 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05U 0.47U 214 0.11 0.3J 0.41U 1.01 1.6 0.3 NS 5.3J 4.7J 0.04U 0.04U NS 1.4J 5.1J 2008-May 0.11 4.5J 127 0.11 0.11 19 1.11 0.9 0.2 NS 7.8J 5.9J 0.04U 0.04U NS 1.01 2.7J 2008-Nov 0.05U 2.7J 121 0.06U 0.11 12 0.4J 0.8 0.2 NS 4.7J 3.5J 0.04U 0.04U NS 0.8J 1.7J 2009-May 0.06J 1.6J 113 0.06U 0.2J 8.4J 0.11 0.6 0.1 NS 3.3J 2.2J 0.04U 0.03U NS 1.3J 3.2J 2009-Aug 2.95 U 4.9 U 127 B 0.44 U 0.3 J 12.3 4.76 J B 2.31 J 6.79 U 0.024 U 3.91 J 4.59 J 7.77 J B 0.198 U 5.12 J B 0.586 U 1.29 U 2010-Jan 0.06J 4.0J 169 0.11 0.2J 10 0.10U 0.7J 0.4J 0.03U 5.1J 3.0J 0.3J 0.03U 0.08U 0.91 3.1J 2010-May 0.22U 7.5J 140 0.4J 0.2J 21 0.8J 1.11 0.4J 0.08U 9.2J 4.4J 0.11 0.11 0.4J 1.6J 6.3J 2010-Nov 0.22U 4.0J 164 0.2J 0.3J 24 0.8J 0.8J 0.4J 0.08U 9.11 4.7J 0.11 0.05U 0.5J 1.91 5.4J 2011-May 0.14 U 3.2 J 124 0.06 J 0.06 J 31 0.84 J 1.3 J 0.13 J 0.08 J 5.2 J 3.0 J 0.02 U 0.02 U 0.95 J 0.76 J 5.4 J 2011-Nov 0.14U 2.7J 184 0.24J 0.13J 17 2.1J 0.69J 1.2J 0.05U 5.4J 1.91 0.02U 0.02U 0.24J 4.1J 5.3J 2012-May 0.13J 5.8J 142 0.13J 0.06J 31 1.7J 1.11 0.20J 0.04J 7.2J 4.5J 0.1U 0.07U 0.10U 1.3J 3.2J 2012-Nov 0.16J 8.0J 133 0.091 0.04J 27 3.0J 1.4J 0.191 0.02U 8.6J 6.9J 0.1U 0.07U 0.92J 1.2J 5.5J 2013-May 0.14J 6.2J 144 0.03U 0.13J 24 2.2J 1.3J 0.06J 0.03J 9.3J 6.8J 0.03U 0.06J 0.08J 1.3J 2.9J 2014-May 0.07J 5.8J 157 0.12J 0.39J 22 3.8J 2.0J 0.191 0.01U 7.8J 4.9J 0.03U 0.03J 0.06U 1.01 3.4J 2014-Nov 0.20J 10 189 0.04J 0.08J 12 5.8J 1.2J 0.13U 0.06U 8.4J 0.16U 0.04U 0.13U 0.22J 1.11 2.8J 2015-May 0.11 J 4.3 J 202 0.26 J 0.10 J 14 2.9 J 0.66 J 0.39 J 0.05 U 4.4 J 4.3 J 0.01 U 0.06 J 0.06 J 0.94 J 1.5 J 2015-Nov 0.32J 2.1J 131 0.02U 0.12J 4.0J 1.3J 0.71J 0.16J 0.05U 2.5J 1.7J 0.02J 0.18J 0.20J 1.2J 1.3J 2016-May 0.12 J 11 325 0.06 J US U 11 8.7 J 1.7 J 0.20 J 0.04 J 6.4 J 8.6 J 0.06 U US U 0.09 J 1.8 J 1.9 J 2016-Nov 0.24 J 21 285 0.24 J 0.20 J 9.8 J 9.3 J 1.8 J 0.69 J 0.04 U 10.4 J 0.62 U 0.06 U 0.05 U 0.06 U 3.0 J 3.5 J 2017-May 0.191 16 340 0.18J 0.111 8.0J 12 1.8J 0.22J 0.07U 8.3J 0.51U 0.20U 0.08U 0.20J 3.7J 2.9J 2017-Dec 0.26 J 15 323 0.07 U 0.08 U 3.3 J 17 2.0 J 0.14 J 0.07 U 8.0 J 0.5 U 0.20 U 0.08 U 0.13 U 2.7 J 1.9 J 2018-Jun 0.09 J 5.5 328 0.09 J 0.06 J 3.2 3.9 J 11 0.26 J 0.07 U 3.1 J 4.5 J US U 0.05 U US U 1.7 1.5 J 2018-Dec 0.22 J 15 358 0.06 J 0.08 J 3.4 15 1.11 0.04 J 0.05 U 7.4 J NS US U US U US U 1.6 3 J 2019-Jun 1 0.24 J 19 608 0.08 J 0.02 U 21 3.8 2 J 0.03 U 0.08 J 7.1 J 8.4 J US U 0.05 U US U 3.1 2.9 J 23 of 53 Appendix B MW-8 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov ND ND ND NS ND NS NS 11.03 2003-May ND ND ND NS ND NS NS 11.85 2003-Nov ND ND ND NS ND NS NS 11.63 2004-May ND ND ND NS ND NS NS 11.60 2004-Nov ND ND ND NS ND NS NS 10.92 2005-May ND ND ND NS ND NS NS 11.42 2005-Nov ND ND ND NS ND NS NS 11.81 2006-May ND ND ND NS ND NS NS 11.21 2006-Nov ND ND ND NS ND NS NS 11.56 2007-May ND ND ND NS ND NS NS 11.63 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov 0.7 J ND 0.2 J NS ND NS NS 10.63 2008-May 0.5 J ND 0.2 J NS ND NS NS 11.35 2008-Nov 0.5 J ND 0.2 J NS ND NS NS 10.76 2009-May 0.3 J ND ND NS ND NS NS 10.07 2009-Aug 1.9 ND 0.07 J ND ND NS NS 10.29 2010-Jan ND ND ND 100 U ND NS NS 11.70 2010-May ND ND ND 100 U ND NS NS 12.74 2010-Nov ND ND ND 100 U ND NS NS 11.62 2011-May 0.40 J ND 0.4 J 100 U ND ND NS 11.25 2011-Nov 0.40 J ND ND 100 U ND 3.9 NS 11.76 2012-May 1.1 ND ND 100 U ND 5.2 NS 11.36 2012-Nov 1.6 ND ND 100 U ND 5.5 NS 11.49 2013-May ND 1.2 ND 100 U ND 5.4 NS 11.58 2014-May 1.9 0.27 U 0.25 U 100 U 0.63 U 10.2 NS 12.27 2014-Nov 0.80 J 0.27 U 0.25 U 100 U 1.4 7.7 NS 11.21 2015-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 4.9 NS 12.80 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 2.6 NS 12.74 2016-May 0.90 J 0.27 U 0.25 U 100 U 0.63 U 8.1 NS 12.62 2016-Nov 1.5 0.27 U 0.25 U 100 U 0.63 U 11.7 NS 12.78 2017-May 1.2 0.27 U 0.25 U 100 U 0.63 U 15 NS 12.63 2017-Dec 0.6 J 0.21 U 0.25 U 100 U 0.63 U 22.2 NS 12.46 2018-Jun 0.3 J 0.21 U 0.25 U 100 U 0.63 U 10.5 NS 16.36 2018-Dec 0.48 J 0.02 U 0.25 U 100 U 1.48 21.2 49.3 12.22 2019-Jun 1.17 0.06 J 0.25 U 100 U 0.12 U 28.1 94.7 11.71 24 of 53 Appendix B MW-9A Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina 0 ... GWPS 1 10 71 1 10 1,000 15 1 20 20 2,000 2001-May lm, NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 112 B 0.44 U 0.16 J 1.72 U 3 JB 2.13 J 6.79 U NS 2.36 U 6.61 J 7.15 JB 0.198 U NS 0.586 U 1.66 JB 2010-Jan 0.4J 1.3J 55.4J 0.2J 0.11 0.7J 2.7J 1.3J 1.8J NS 2.5J 0.12U 0.11 0.03U NS 4.9J 7.5J 2010-May 0.22 U 0.3 J 29.4 J 0.02 U 0.2 J 0.2 J 0.3 J 0.11 0.11 NS 2.0 J 0.32 U 0.03 U 0.05 U NS 0.6 J 1.5 J 2010-Nov 0.22 U 0.6 J 32.9 J 0.02 U 0.11 0.2 J 0.03 U 0.03 U 0.01 U NS 1.8 J 0.32 U 0.03 U 0.05 U NS 0.9 J 2.6 J 2011-May 0.14 U 0.60 J 50.7 J 0.02 U 0.05 J 0.09 J 0.17 J 0.29 J 0.16 J NS 0.77 J 0.20 U 0.02 U 0.02 U NS 1.2 J 3.2 J 2011-Nov 0.14 U 0.50 J 43.6 J 0.02 U 0.08 J 0.111 0.23 J 0.05 J 0.16 J NS 0.78 J 0.20 U 0.02 U 0.08 J NS 1.3 J 2.3 J 2012-May 0.03 J 0.50 J 48.9 J 0.07 U 0.14 J 0.06 J 0.18 U 0.111 0.08 U NS 0.23 J 0.17 U 0.1 U 0.07 U NS 0.96 J 0.66 J 2012-Nov 0.06J 0.17J 36.5J 0.07U 0.04J 0.08J 0.18U 0.50J 0.12J NS 1.3J 0.21J 0.1U 0.07U NS 0.25J 4.4J 2013-May 0.04 J 0.15 J 39.5 J 0.03 U 0.64 J 0.04 J 0.13 J 0.35 J 0.12 J NS 0.98 J 0.08 J 0.03 U 0.02 U NS 0.07 J 3.7 J 2014-May 0.02 U 0.05 U 29.3 J 0.03 U 1 0.05 J 0.04 U 0.67 J 0.07 J NS 1.3 J 0.06 U 0.03 U 0.02 U NS 0.07 U 3.4 J 2014-Nov 0.12U 0.14U 32.1J 0.04U 0.31J 0.12U 0.14U 0.51J 0.13U NS 1.2J 0.44U 0.04U 0.13U NS 0.48J 1.3J 2015-May 0.02 U 0.14 U 25.8 J 0.02 U 0.10 J 0.06 J 0.18 J 0.23 J 0.03 U NS 0.87 J 0.22 U 0.01 U 0.02 U NS 0.22 U 2.0 J 2015-Nov 0.20 J 0.14 U 54.3 J 0.02 U 0.18 J 0.10 J 0.12 U 0.46 J 0.16 J NS 1.9 J 0.22 U 0.01 U 0.02 U NS 0.911 4.8 J 2016-May 0.05 U 0.66 U 51.0 J 0.04 U 0.12 J 0.07 J 0.08 J 0.43 J 0.19 J NS 1.2 J 0.54 U 0.06 U 0.05 U NS 0.36 U 3.1 J 2016-Nov 0.05 U 0.66 U 45.3 J 0.04 U 0.13 J 0.113 J 0.06 U 0.16 J 0.06 J NS 1.8 J 0.62 U 0.06 U 0.05 U NS 0.36 U 1.9 J 2017-May 0.06U 0.21 J 39.0 J 0.07 U 0.08 U 0.24 U 0.08 U 0.22 J 0.08 U 0.07 U 1.5 J 0.51 U 0.20 U 0.08 U 0.13 U 0.24 U 2.5 J 2017-Dec 0.1 J 0.36 J 68.4 J 0.07 U 0.09 J 0.29 J 0.36 J 0.68 J 0.35 J 0.07 U 2.1 J 0.5 U 0.20 U 0.08 U 0.13 U 1.5 J 3.7 J 2018-Jun 0.04 J 0.64 J 56.8 0.05 U 0.04 J 0.27 J 0.15 U 0.35 J 0.19 J 0.07 U 1.8 J 0.38 J 0.05 U 0.05 U 0.05 U 1.2 1.6 J 2018-Dec 0.1 J 0.03 J 48.8 0.05 U 0.02 J 0.12 J 0.15 U 0.38 J 0.03 U 0.05 J 2.1 J 0.15 U 0.05 U 0.05 U 0.05 U 0.03 U 3.3 J 2019-Jun 0.03 U 0.42 U 47.7 0.05 U 0.02 U 0.15 U 0.111 0.84 J 0.03 U 0.05 U 1.7 J 0.35 J 0.05 U 0.05 U 0.05 U 0.54 J 4.2 J 25 of 53 Appendix B MW-9A Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 12.86 2010-Jan ND ND ND NS ND NS NS 14.94 2010-May ND ND ND NS ND NS NS 13.76 2010-Nov ND ND ND NS ND NS NS 14.50 2011-May ND ND ND NS ND ND NS 13.57 2011-Nov ND ND ND NS ND ND NS 14.46 2012-May ND ND ND NS ND ND NS 13.67 2012-Nov ND ND ND NS ND ND NS 14.60 2013-May ND ND ND NS ND ND NS 13.99 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.97 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.39 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.47 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 15.46 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.58 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.47 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 14.28 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 15.11 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.38 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 15.76 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.67 J 2.71 U 14.04 26 of 53 Appendix B MW-10 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 ham 20 20 2,000 jib 2001-May lm, NS NS NS NS NS NS NS NS ivy --E�11111 NS NS NS ___Jjg __ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 76.1 B 0.44 U 0.17J 1.72 U 3 JB 2.34J 6.79 U 0.024 U 2.36 U ND 6.95JB 0.198 U 5.36 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.5J 113 0.2J 0.04U 0.3J 0.91 1.01 1.4J NS 0.8J 0.2J 0.11 0.03U NS 4.5J 2.6J 2010-May 0.22U 0.5J 129 0.11 1 0.2J 0.6J 0.6J 2.0J NS 1.5J 0.6J 0.03U 0.05U NS 3.2J 4.0J 2010-Nov 0.22 U 1.1 J 63.2 J 0.11 0.11 0.3 J 0.11 0.03 U 1.11 NS 4.1 J 0.32 U 0.03 U 0.05 U NS 1.91 2.1 J 2011-May 0.14U 0.52J 89.2J 0.29J 0.8J 2.2J 0.83J 1.7J 1.2J NS 1.11 1.11 0.02U 0.05J NS 3.1J 3.5J 2011-Nov 0.14U 2.5J 43.6J 0.16J 0.08J 0.26J 0.86J 0.18J 1.91 NS 1.3J 0.62J 0.02U 0.05J NS 9.2J 1.7J 2012-May 0.04 J 1.1 J 87.5 J 0.09 J 0.05 J 0.45 J 0.50 J 0.37 J 0.74 J NS 2.3 J 0.93 J 0.1 U 0.07 U NS 5.91 0.48 U 2012-Nov 0.091 1.5J 132 0.08J 0.08J 0.86J 0.80J 0.64J 0.43J NS 1.6J 2.1J 0.1U 0.07U NS 4.1J 3.1J 2013-May 0.04 J 0.74 J 169 0.08 J 0.06 J 0.33 J 1.11 0.68 J 0.23 J NS 1.5 J 1.7 J 0.03 U 0.02 U NS 4.6 J 2.1 J 2014-May 0.02 U 0.05 U 58.9 J 0.04 J 0.17 J 0.44 J 0.83 J 0.38 J 0.10 J NS 1.0 J 0.06 U 0.03 U 0.02 U NS 2.9 J 1.3 J 2014-Nov 0.24J 0.84J 100 0.04J 0.21J 0.49J 1.11 0.76J 0.13U NS 1.8J 1.8J 0.04U 0.13U NS 4.4J 1.4J 2015-May 0.02 U 0.73 J 63.2 J 0.04 J 0.08 J 0.31 J 1.4 J 0.27 J 0.05 J NS 1.20 J 1.10 J 0.01 U 0.02 U NS 4.90 J 1.10 J 2015-Nov 0.17J 1.2J 119 0.05J 0.62J 0.38J 1.7J 0.75J 0.111 NS 1.7J 2.5J 0.01U 0.02U NS 5.3J 2.8J 2016-May 0.27J 10 344 0.05J 0.13J 0.92J 9.2J 0.97J 0.12J NS 4.1J 4.6J 0.06U 0.05U NS 8.7J 2.1J 2016-Nov 0.21 J 7 J 260 0.10 J 0.09 J 1.0 J 11 0.70 J 0.06 U NS 6.7 J 9.4 U 0.06 U 0.05 U NS 8.5 J 1.61 U 2017-May 0.31 J 8 J 200 0.07 U 0.17 J 0.87 J 12 0.70 J 0.08 U 0.07 U 6.3 J 5.1 J 0.20 U 0.08 U 0.13 U 8.5 J 1.9 J 2017-Dec 0.15J 2.6J 184 0.07U 0.15J 0.56J 4.7J 0.95J 0.76J 0.07U 3.4J 3.1J 0.20U 0.08U 0.13U 9.11 3.8J 2018-Jun 0.12J 2.2J 161 0.06J 0.04J 0.42J 4.1J 0.69J 0.18J 0.07U 3.3J 4.3J 0.05U 0.05U 0.05U 8 0.32J 2018-Dec 0.03 U 9 368 0.05 J 0.14 J 1.8 14 0.96 J 0.03 J 0.05 U 12.1 7.9 J 0.05 U 0.05 U 0.05 U 8.1 1.5 J 2019-Jun 0.21J 9 321 0.12J 0.111 19 1.9 0.8J 0.03U 0.05U 9.3J 4.1J 0.05U 0.18J 0.05U 9.5 2.7J 27 of 53 Appendix B MW-10 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .IA-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 9.35 2010-Jan ND ND ND NS ND NS NS 13.61 2010-May ND ND ND NS ND NS NS 12.50 2010-Nov ND ND ND NS ND NS NS 12.78 2011-May ND ND ND NS ND ND NS 12.33 2011-Nov ND ND ND NS ND ND NS 12.69 2012-May ND ND ND NS ND ND NS 12.21 2012-Nov ND ND ND NS ND ND NS 12.68 2013-May ND ND ND NS ND ND NS 12.28 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.68 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.59 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.20 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.05 2016-May 0.50 J 0.27 U 0.5 J NS 1.9 14.3 NS 13.42 2016-Nov 0.60 J 0.27 U 0.4 J NS 1.7 8.8 NS 13.42 2017-May 0.40 J 0.27 U 0.25 U 4790 1.1 6.4 NS 13.36 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.9 J 0.39 U NS 13.05 2018-Jun 0.24 U 0.21 U 0.4 J 1182 2 3.4 NS 13.37 2018-Dec 1.57 0.34 0.31 J 328 J 2.2 25.42 5.4 13.72 2019-Jun 2.26 0.4 0.35 J 849 J 1.77 29 10.7 12.82 28 of 53 Appendix B MW-11 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 hm 20 EmmmmmL- 20 2,000 2001-May lm, NS NS NS NS NS NS i�_ v� NS NS NS --Jmiliim� NS NS NS ___Jjg _ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 39.8 B 0.44 U 0.3J 1.72 U 3.09 JB 2.44J 6.79 U 0.024 U 2.75J 4.22J 6.92JB 0.198 U 6.02 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.17U 23.4J 0.3J 0.2J 0.5J 0.10U 0.8J 0.2J NS 2.2J 0.12U 0.04U 0.03U NS 1.3J 2.9J 2010-May 0.7J 0.04U 14.2J 0.11 0.11 0.3J 0.3J 0.2J 0.2J NS 1.8J 0.32U 0.11 0.05U NS 1.01 2.0J 2010-Nov 0.22 U 0.6 J 31.4 J 0.2 J 0.2 J 0.3 J 0.11 0.03 U 0.2 J NS 1.6 J 0.32 U 0.03 U 0.05 U NS 0.6 J 3.2 J 2011-May 0.14 U 0.10 U 19.2 J 0.31 J 0.17 J 0.26 J 0.23 J 0.67 J 0.11 NS 1.2 J 0.20 U 0.02 U 0.02 U NS 0.54 J 2.1 J 2011-Nov 0.14U 0.23J 17.3J 0.101 0.13J 0.20J 0.04J 0.091 0.12J NS 1.2J 0.20U 0.02U 0.12J NS 0.551 1.91 2012-May 0.06 J 0.41 J 23.9 J 0.08 J 0.22 J 0.22 J 0.18 U 0.50 J 0.09 J NS 3.4 J 0.72 J 0.1 U 0.07 U NS 0.78 J 1.7 J 2012-Nov 0.08J 0.82J 19.3J 0.29J 0.64J 0.53J 0.25J 0.70J 0.49J NS 2.3J 1.11 0.1U 0.07U NS 0.44J 6.4J 2013-May 0.05J 0.58J 19.8J 1 0.97J 0.73J 0.78J 1.4J 0.53J NS 2.4J 1.11 0.03J 0.14J NS 0.35J 3.8J 2014-May 0.02 U 0.05 U 18.3 J 0.03 U 0.25 J 0.19 J 0.20 J 0.37 J 0.04 J NS 2.7 J 0.06 U 0.03 U 0.02 U NS 0.07 U 1.3 J 2014-Nov 0.24J 0.17J 19.7J 0.24J 0.58J 0.66J 0.34J 0.96J 0.13U NS 4.5J 0.44U 0.04J 0.13U NS 0.34J 3.1J 2015-May 0.02 U 0.46 J 24.4 J 0.18 J 0.33 J 0.43 J 1.11 0.90 J 0.10 J NS 3.20 J 1.40 J 0.01 U 0.30 J NS 0.22 U 3.0 J 2015-Nov 0.12J 0.24J 21.3J 0.06J 0.45J 0.52J 0.65J 1.11 0.091 NS 4.1J 0.911 0.01U 0.03J NS 0.54J 4.5J 2016-May 0.05 U 0.66 U 23.6 J 0.05 J 0.16 J 0.30 J 0.85 J 0.51 J 0.07 J NS 3.6 J 0.77 J 0.06 U 0.05 U NS 0.36 U 1.9 J 2016-Nov 0.05 U 1.3 J 31.3 J 0.12 J 0.50 J 0.70 J 0.43 J 0.35 J 0.24 J NS 5.2 J 1.4 J 0.06 U 0.05 U NS 0.59 J 2.4 J 2017-May 0.07 J 0.44 J 20.3 J 0.07U 0.15 J 0.28 J 0.08 U 3.5 J 0.08 U 0.07 U 9.3 J 0.74 J 0.20 U 0.08 U 0.13 U 0.24 U 2.5 J 2017-Dec 0.07 J 2.2 J 42.4 J 0.09 J 0.08 U 0.73 J 0.8 J 0.66 J 0.111 0.07 U 4.8 J 1.8 J 0.20 U 0.08 U 0.13 U 1.5 J 3.2 J 2018-Jun 0.11 3.6J 78.3 0.11 0.08J 1.4J 1.3J 0.46J 0.13J 0.07U 5.3J 2J 0.05U 0.06J 0.05U 2.7 2.2J 2018-Dec 0.06 J 3.2 J 55 0.05 U 0.11 1 0.56 J 0.3 J 0.04 J 0.05 U 5.7 J 1.11 0.05 U 0.05 U 0.05 U 1.5 1.3 J 2019-Jun 0.03 J 5.5 72.2 0.22 J 0.12 J 0.77 J 0.9 J 0.31 J 0.03 U 0.05 U 3.8 J 1.2 J 0.05 U 0.05 U 0.05 U 3.2 6 J 29 of 53 Appendix B MW-11 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 0.4 70 INE NE 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 8.49 2010-Jan ND ND ND NS ND NS NS 11.52 2010-May ND ND ND NS ND NS NS 11.02 2010-Nov ND ND ND NS ND NS NS 8.35 2011-May ND ND ND NS ND ND NS 10.26 2011-Nov ND ND ND NS ND ND NS 11.24 2012-May ND ND ND NS ND 18.4 NS 10.33 2012-Nov ND ND ND NS ND 6.2 NS 10.94 2013-May ND ND ND NS ND ND NS 10.32 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.82 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 2.7 NS 11.15 2015-May 0.24 U 0.27 U 0.3 J NS 0.63 U 6.1 NS 11.23 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 2.5 NS 12.06 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.5 NS 11.47 2016-Nov 0.24 U 0.27 U 0.3 J NS 0.63 U 0.39 U NS 11.29 2017-May 0.24U 0.27 U 0.25 U 100U 0.63U 0.9 NS 11.76 2017-Dec 1 0.21 U 0.6 J 100 U 0.63 U 17 NS 11.89 2018-Jun 0.9 J 0.21 U 0.5 J 100 U 0.63 U 16 NS 11.62 2018-Dec 0.48 J 0.08 J 0.25 U 100 U 0.12 U 8.02 8.15 11.69 2019-Jun 1.89 0.18 J 0.25 U 100 U 0.69 17.3 9.21 9.95 30 of 53 Appendix B MW-12S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 h1k 20 20 2,000 jib 2001-May lm, NS NS NS NS NS NS i�_ v� NS NS -.wmmmm.- NS --jI�lll NS NS NS ___Jjg __ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 56.6 B 0.44 U 0.158 U 1.72 U 2.48 JB 1.86J 6.79 U 0.024 U 2.43J 2.78 U 6.87JB 0.198 U 4 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.17U 98.5J 0.06U 0.2J 0.2J 0.10U 0.7J 0.4J NS 0.91 0.2J 0.11 0.03U NS 2.4J 2.8J 2010-May 0.22U 0.4J 39.2J 0.11 0.2J 0.2J 0.6J 0.3J 1.11 NS 0.91 0.32U 0.03U 0.05U NS 3.7J 1.11 2010-Nov 0.8J 5.3J 177 0.11 0.11 0.8J 1.7J 1.11 1.91 NS 4.1J 1.3J 0.11 0.05U NS 4.4J 3.1J 2011-May 0.47J 5.9J 346 0.02U 0.11 1.51 2.6J 1.5J 0.83J NS 6.8J 1.7J 0.02U 0.08J NS 2.9J 3.5J 2011-Nov 0.51 J 11 467 0.02 U 0.06 J 0.84 J 14 0.53 J 0.64 J NS 7.6 J 2.5 J 0.02 U 0.04 J NS 4.8 J 1.8 J 2012-May 0.24 J 24 291 0.07 U 0.05 J 0.72 J 6.5 J 0.87 J 0.90 J NS 5.6 J 3.7 J 0.1 U 0.07 U NS 6.9 J 0.48 U 2012-Nov 0.3J 15 504 0.07U 0.13J 1.11 16 0.911 0.65J NS 7.3J 4.1J 0.1U 0.07U NS 6.4J 4.1J 2013-May 0.18 J 19 342 0.03 J 0.68 J 0.88 J 19 1.5 J 0.07 J NS 4.8 J 5.7 J 0.03 U 0.02 U NS 7.8 J 1.9 J 2014-May 0.10 J 11 368 0.03 U 0.09 J 0.82 J 9.0 J 0.63 J 0.02 U 0.01 U 5.9 J 1.3 J 0.03 U 0.02 U 0.06 U 4.1 J 2.0 J 2014-Nov 0.34J 36 515 0.04U 0.26J 1.11 21 1.2J 0.13U 0.06U 6.7J 0.44U 0.04U 0.13U 0.18J 11.0J 1.9J 2015-May 0.70 J 15 292 0.02 U 0.09 J 0.81 J 8.9 J 0.35 J 0.03 U 0.05 U 4.90 J 3.40 J 0.01 U 0.02 U 0.12 J 5.10 J 13 2015-Nov 0.14J 2.8J 69.2J 0.04J 1 0.30J 2.7J 1.5J 0.191 0.05U 2.3J 0.911 0.03J 0.07J 0.35J 3.2J 6.0J 2016-May 0.26 J 38 550 0.04 U 0.14 J 1.7 J 27 1.6 J 0.07 J 0.04 J 6.6 J 6.7 J 0.06 U 0.05 U 0.33 J 16.5 J 2.0 J 2016-Nov 0.28 J 42 654 0.10 J 0.15 J 2.0 J 28 1.5 J 0.06 J 0.04 U 8.9 J 0.62 U 0.06 U 0.05 U 0.06 U 16.4 J 2.0 J 2017-May 0.29 J 52 507 0.07 U 0.08 U 1.8 J 28 1.11 0.08 U 0.07 U 7.6 J 9.9 J 0.20 U 0.08 U 0.13 U 17.9 J 1.5 J 2017-Dec 0.25J 41 541 0.07U 0.15J 2.0J 31 2.4J 0.24J 0.07U 6.9J 0.5U 0.20U 0.08U 0.24J 21.3J 5.5J 2018-Jun 0.18 J 37 466 0.07 J 0.13 J 1.9 26 0.76 J 0.6 J 0.07 U 5.6 J 0.53 U 0.05 U 0.05 U 0.05 U 16 2 J 2018-Dec 0.17 J 22 398 0.05 U 0.02 U 1.6 24 1.11 0.03 U 0.05 U 6.6 J 8.1 J 0.05 U 0.05 U 0.05 U 17.5 1.2 J 2019-Jun 2.9 54 759 0.08 J 0.02 U 55 3.2 2.5 J 0.03 U 0.05 U 9.11 11 0.05 U 0.07 J 0.05 U 40 4.4 J 31 of 53 Appendix B MW-12S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS . .IA-Dioxane 7loom M13W Groundwater Elevation 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 8.45 2010-Jan ND ND ND ND NS NS 11.71 2010-May ND ND ND NS ND NS NS 12.03 2010-Nov ND ND ND NS ND NS NS 11.25 2011-May ND 0.6 J 0.6 J NS ND ND NS 11.00 2011-Nov 0.30 J 0.4 J 1.2 J NS ND 4.2 NS 11.51 2012-May 1.2 1.1 8.5 NS 0.8 2.5 NS 11.06 2012-Nov 0.70 J ND 4.1 J NS 1.9 10.9 NS 10.70 2013-May 1.1 ND 5.9 J NS 3 3.3 NS 10.50 2014-May 0.4 J 0.27 U 0.7 J 230 J 1.1 5.5 NS 10.93 2014-Nov 1.1 0.27 U 1.7 J 100 U 3.4 10 NS 10.58 2015-May 0.50 J 0.27 U 0.5 J 100 U 1.7 7.1 NS 11.32 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 1.8 NS 11.98 2016-May 1.4 0.27 U 0.8 J 346 J 3.7 46.2 NS 11.64 2016-Nov 1.9 0.27 U 1.6 J 240 J 4.3 49 NS 11.38 2017-May 1.7 0.27 U 0.25 U 537J 4.3 36.4 NS 11.58 2017-Dec 2 0.21 U 1.4 J 100 U 3.7 58.4 NS 12.04 2018-Jun 1.4 0.21 U 0.6 J 298 J 2.9 32.7 NS 11.58 2018-Dec 1.48 0.13 J 0.34 J 115 J 2.21 38.75 8.82 12.03 2019-Jun 2.52 0.19 J 0.4 J 100 U 3.33 64.9 32.8 11.46 32 of 53 Appendix B MW-13 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 ham 20 20 2,000 jib 2001-May lm, NS NS NS NS NS NS NS NS ivy --E�11111 NS NS NS ___Jjg __ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 411 JB 0.44 U 0.16 J 1.72 U 1.77 JB 1.33 J 6.79 U NS 2.44 J 2.78 U 6.91 JB 0.198 U NS 0.586 U 4.63 JB 2010-Jan 0.06J 2.4J 82.8J 0.3J 0.2J 1.3J 0.7J 1.2J 3.2J NS 1.6J 0.5J 0.11 0.03U NS 4.9J 8.5J 2010-May 0.22U 1.4J 86.7J 0.3J 0.4J 0.91 0.8J 0.5J 1.8J NS 1.7J 0.32U 0.03U 0.05U NS 2.4J 7.5J 2010-Nov 0.22U 1.8J 106 0.3J 0.2J 1.01 0.91 0.8J 3.1J NS 2.2J 0.8J 0.03U 0.05U NS 3.6J 8.5J 2011-May 0.14U 0.29J 92.3J 0.12J 0.16J 1.2J 0.51J 2.1J 0.8J NS 2.1J 0.38J 0.02U 0.04J NS 1.01 32 2011-Nov 0.14U 0.52J 67.8J 0.14J 0.13J 0.60J 0.57J 0.82J 0.93J NS 1.3J 0.78J 0.02U 0.07J NS 1.4J 3.2J 2012-May 0.101 0.62J 74.2J 0.12J 0.18J 1.51 0.61J 0.77J 1.01 NS 3.4J 0.64J 0.1U 0.07U NS 2.2J 8.1J 2012-Nov 0.101 0.76J 76.6J 0.13J 0.12J 0.46J 0.68J 1.01 1.5J NS 1.7J 1.01 0.1U 0.07U NS 3.0J 3.3J 2013-May 0.03 J 0.34 J 69.7 J 0.12 J 0.21 J 0.47 J 0.59 J 0.63 J 0.93 J NS 0.84 J 0.83 J 0.03 U 0.02 U NS 2.0 J 3.5 J 2014-May 0.02 U 0.05 U 52.4 J 0.04 J 1 0.32 J 0.46 J 1.0 J 0.40 J NS 1.2 J 0.06 U 0.03 U 0.02 U NS 1.4 J 2.4 J 2014-Nov 0.12U 0.37J 69.9J 0.08J 0.18J 0.47J 0.35J 0.40J 0.52J NS 1.11 0.62J 0.04U 0.13U NS 1.3J 4.6J 2015-May 0.02 U 0.41 J 57.1 J 0.02 U 0.10 J 0.28 J 0.63 J 0.60 J 0.111 NS 1.40 J 0.59 J 0.01 U 0.03 J NS 1.20 J 1.30 J 2015-Nov 0.16J 0.26J 57.7J 0.03J 1 0.35J 0.42J 2.0J 1.01 NS 2.5J 0.63J 0.01U 0.06J NS 5.81 3.6J 2016-May 0.12J 0.66U 46.2J 0.06J 0.23J 0.26J 0.81J 1.3J 2.1J NS 1.4J 0.73J 0.06U 0.07J NS 10.51 4.5J 2016-Nov 0.11 J 0.85 J 53.1 J 0.04 U 0.05 J 0.94 J 0.26 J 0.50 J 0.08 J NS 3.4 J 1.11 0.06 U 0.05 U NS 1.5 J 1.61 U 2017-May 0.16J 1.3J 36.3J 0.07U 0.08U 0.50J 0.15J 0.69J 0.17J 0.07U 1.8J 0.77J 0.20U 0.08J 0.13U 0.911 1.91 2017-Dec 0.13J 1.5J 56.3J 0.07U 0.08U 0.37J 0.4J 0.7J 1.11 0.07U 2.3J 0.77J 0.20U 0.08U 0.13U 6.6J 2.3J 2018-Jun 0.13 J 5 38.7 0.06 J 0.04 J 0.85 J 0.15 U 0.89 J 2.8 J 0.07 U 2.1 J 1.2 J 0.05 U 0.05 U 0.05 U 15 1.6 J 2018-Dec 0.13 J 1.1 J 47.5 0.05 U 0.06 J 0.54 J 0.31 J 0.38 J 0.16 J 0.05 U 3.9 J 0.85 J 0.05 U 0.05 U 0.05 U 1.3 0.911 2019-Jun 0.1 J 2.3 J 45.8 0.06 J 0.05 J 0.3 J 0.75 J 0.56 J 0.111 0.05 U 2.2 J 0.73 J 0.05 U 0.12 J 0.05 U 1.5 4.7 J 33 of 53 Appendix B MW-13 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 9.35 2010-Jan ND ND ND NS ND NS NS 12.45 2010-May ND ND ND NS ND NS NS 11.22 2010-Nov ND ND ND NS ND NS NS 12.44 2011-May ND ND ND NS ND ND NS 12.01 2011-Nov ND ND ND NS ND ND NS 12.10 2012-May ND ND ND NS ND ND NS 11.86 2012-Nov ND ND ND NS ND ND NS 11.51 2013-May ND ND ND NS ND ND NS 10.77 2014-May ND 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.29 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.57 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.69 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.24 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.33 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.17 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.35 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.69 2018-Jun 0.24 U 0.21 U 0.25 U 158 J 0.63 U 0.39 U NS 13.03 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.12 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 1.47 2.71 U 12.21 34 of 53 Appendix B MW-14D Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 ham 20 20 2,000 JIL 2001-May lm, NS NS NS NS NS NS i\1� N-) NS NS N-) --E�11111 NS NS NS ___Jjg _ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 13.9 JB 0.44 U 0.4 J 1.72 U 4.24 JB 1.29 U 6.79 U NS 2.36 U 2.78 U 6.77 JB 0.198 U NS 0.586 U 1.29 U 2010-Jan 0.11 0.2J 13.1J 0.06U 1 0.2J 1.8J 2.4J 1.2J NS 2.14J 0.12U 1.11 0.03U NS 1.4J 21 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov 0.14 U 0.32 J 9.9 J 0.02 U 0.43 J 0.08 J 0.04 U 0.66 J 0.17 J NS 1.4 J 0.20 U 0.02 U 0.02 U NS 0.3 J 3.2 J 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov 0.91 0.24J 11.2J 0.07U 0.43J 0.101 0.4J 1.2J 0.22J NS 1.7J 0.23J 0.1U 0.07U NS 0.41J 6.1J 2013-May 0.4 J 0.08 J 10.2 J 0.03 U 2 0.04 J 0.27 J 0.84 J 0.07 J NS 0.96 J 0.27 J 0.03 U 0.02 U NS 0.07 U 4.2 J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.06 J 0.23 J 10.7 J 0.02 U 0.50 J 0.05 J 0.12 U 1.3 J 0.05 J NS 1.1 J 0.22 U 0.01 U 0.02 U NS 0.22 U 11 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.09 J 0.07 U 9.90 J 0.07 U 0.25 J 0.24 U 0.08U 1.2 J 0.08U 0.07 U 1.7 J 0.51 U 0.20 U 0.08 U 0.13 U 1.4 J 8.4 J 2017-Dec 0.08 J 0.58 J 10.9 J 0.07 U 0.19 J 0.24 U 0.08 J 0.6 J 0.18 J 0.07 U 3.0 J 0.51 U 0.20 U 0.08 U 0.21 J 0.591 7.4 J 2018-Jun 0.03 U 0.24 J 10.2 0.05 U 0.22 J 0.09 J 0.15 U 0.77 J 0.12 J 0.07 U 0.99 J 0.36 J 0.05 U 0.05 U 0.05 U 0.05 J 4.7 J 2018-Dec 0.04 J 0.03 U 8.5 J 0.05 U 0.06 J 0.07 J 0.15 U 0.41 J 0.03 U 0.05 U 1.4 J 0.15 U 0.05 U 0.05 U 0.05 U 0.03 U 2 J 2019-Jun 0.04 J 0.18 J 10.1 0.05 U 0.05 J 0.15 U 0.05 J 0.94 J 0.03 U 0.05 U 1.8 J 0.35 J 0.05 U 0.05 U 0.05 U 0.03 U 9.7 J 35 of 53 Appendix B MW-14D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 A A NE nna INE12001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 10.50 2010-Jan ND ND ND NS ND NS NS 9.49 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov ND ND ND NS ND ND NS 11.71 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND NS ND ND NS 11.86 2013-May ND ND ND NS ND ND NS 11.44 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.43 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.05 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.84 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.15 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 12.21 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 11.30 36 of 53 Appendix B MW-14S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 700 1AP 1.000 15 1 hmm 20 20 2,000 JIL 2001-May lm, NS NS NS NS NS NS i�_ v� NS NS -mmmmmL- NS --Jmiliim� NS NS NS ___Jjg _ NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 111 0.44 U 0.23 J 1.72 U 2.8 JB 1.34 J 6.79 U NS 2.36 U 2.78 U 7.2 JB 0.198 U NS 0.586 U 1.48 JB 2010-Jan 0.2J 1.3J 100 0.6J 0.2J 0.4J 2.6J 2.4J 21 NS 1.01 0.4J 0.11 0.03U NS 35 4.7J 2010-May 0.22U 0.04U 107 0.11 0.11 0.2J 0.5J 0.11 1.5J NS 1.11 0.32U 0.03U 0.05U NS 3.3J 1.2J 2010-Nov 0.22U 1.6J 177 0.2J 0.3J 0.3J 0.5J 0.11 2.2J NS 1.91 0.32U 0.03U 0.05U NS 8.5J 2.6J 2011-May 0.14U 1.5J 127 0.2J 0.12J 0.18J 0.48J 0.81J 4.4J NS 0.86J 0.44J 0.02U 0.04J NS 11.8J 2.6J 2011-Nov 0.14 U 1.7 J 223 0.29 J 0.29 J 0.42 J 1.3 J 0.59 J 3.2 J NS 2 J 0.33 J 0.02 U 0.05 J NS 8.4 J 4.7 J 2012-May 0.34J 4.0J 105 2 0.18J 3.4J 2.0J 1.91 11 NS 5.2J 1.4J 0.1U 0.07U NS 31 6.2J 2012-Nov 0.14J 3.7J 74.7J 0.39J 0.36J 1.6J 1.2J 0.57J 7.9J NS 1.91 0.94J 0.1U 0.07U NS 22.7J 4.6J 2013-May 0.15J 5.0J 69.4J 0.48J 0.18J 2.4J 5.8J 1.8J 0.75J NS 4.4J 5.5J 0.03U 0.30J NS 8.2J 5.6J 2014-May 0.17J 0.30J 90.91 0.03U 2 0.24J 2.1J 1.8J 0.42J NS 1.6J 0.06U 0.03U 0.13J NS 1.4J 2.6J 2014-Nov 0.21J 6.9J 207 0.08J 0.26J 1.81 14 1.11 1.4J NS 6.9J 0.16U 0.04U 0.15J NS 4.3J 5.7J 2015-May 0.18 J 1.2 J 54.3 J 0.04 J 0.86 J 0.79 J 0.82 J 0.55 J 0.56 J NS 1.60 J 0.28 J 0.01 U 0.02 J NS 1.60 J 16 2015-Nov 0.12J 2.4J 93.8J 0.48J 0.66J 1.6J 8.4J 3.6J 13 NS 4.1J 0.22U 0.02J 0.13J NS 27 35 2016-May 0.12J 0.84J 52.1J 0.13J 0.44J 0.61J 3.0J 1.8J 2.7J NS 2.5J 0.54U 0.06U 0.07J NS 5.7J 12 2016-Nov 0.08J 2.1J 73.1J 0.06J 0.29J 1.3J 1.2J 0.62J 1.01 NS 3.0J 0.69J 0.06U 0.05U NS 2.6J 6.8J 2017-May 0.14 J 0.90 J 75.0 J 0.10 J 0.61J 0.74 J 2.1 J 1.4 J 2.1 J 0.07 U 2.6 J 0.51 U 0.20 U 0.08 U NA 5.91 13 2017-Dec 0.111 2.6J 92.0J 0.32J 0.44J 1.6J 9.11 3.8J 8.6J 0.07U 4.5J 0.57J 0.20U 0.12J 0.24J 20.1J 21 2018-Jun 0.03 U 2.4 J 65 0.05 U 0.11 0.59 J 0.84 J 0.56 J 0.69 J 0.07 U 1.5 J 11 0.05 U 0.06 J 0.05 U 2.1 5 J 2018-Dec 0.06 J 0.59 J 49.3 0.05 U 0.07 J 0.36 J 0.48 J 0.52 J 0.73 J 0.05 J 1.8 J 0.15 U 0.05 U 0.05 U 0.05 U 2.3 4.6 J 2019-Jun 0.06 J 2.2 J 98.9 0.07 J 0.05 J 2 J 0.69 J 0.92 J 0.72 J 0.05 U 4 J 1.11 0.05 U 0.05 J 0.05 U 4.2 6.2 J 37 of 53 Appendix B MW-14S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 0.4 70 INE NE 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 11.90 2010-Jan ND ND ND NS ND NS NS 12.51 2010-May ND ND ND NS ND NS NS 11.41 2010-Nov ND ND ND NS ND NS NS 12.59 2011-May ND ND ND NS ND ND NS 12.03 2011-Nov ND ND ND NS ND 0.9 NS 12.03 2012-May ND ND ND NS ND 14 NS 11.99 2012-Nov ND ND ND NS ND 0.7 NS 11.49 2013-May 0.40 J ND 1.4 J NS ND 7.4 NS 11.00 2014-May ND 0.27 U 0.3 J NS 0.63 U 0.8 NS 11.49 2014-Nov 0.50 J 0.27 U 1.6 J NS 0.63 U 17.3 NS 10.84 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1 NS 11.86 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.70 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.65 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.6 NS 12.09 2017-May 0.24U 0.27 U 0.25 U 100U 0.63U 0.39U NS 12.50 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.60 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.80 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.36 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.13 J 0.81 J 2.71 U 12.60 38 of 53 Appendix B MW-15 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 hmm 20 20 2,000 3 2001-May lm, NS NS NS NS NS NS i�_ v� NS NS -mmmmmL- NS --jm�lll NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.101 6.4 J 88.7 J 0.42 J 0.20 J 0.32 2.9J 1.4 J 10 0.07 U 1.11 1.8 J 0.20 U 0.08U 0.13U 71 4.9 J 2017-Dec 0.08J 2.8J 134 0.33J 0.12J 0.36J 2.9J 0.6J 5.6J 0.07U 0.94J 1.8J 0.20U 0.08U 0.13U 34 5.8J 2018-Jun 0.04J 3J 99.5 0.27J 0.17J 0.33J 2.6J 1.11 6.8J 0.07U 11 0.96J 0.05U 0.07J 0.05U 21.2 2.4J 2018-Dec 0.05 J 1.4 J 95.2 0.05 J 0.08 J 0.15 J 0.15 U 0.44 J 0.11 0.05 U 2.1 J 0.15 U 0.05 U 0.05 U 0.05 U 3.5 0.87 J 2019-Jun 0.04 J 1.6 J 109 0.111 0.07 J 0.46 J 0.26 J 0.4 J 0.03 U 0.05 U 1.3 J 0.51 J 0.05 U 0.05 U 0.05 U 5.7 5.1 J 39 of 53 Appendix B MW-15 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 A A NE nna INE12001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.54 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.06 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.37 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 14.47 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.28 40 of 53 Appendix B MW-16 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 71 1 1,000 15 1 20 20 2 2,000 3 2001-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-Dec 0.14J 3.2J 251 0.16J 0.21J 0.86J 6.9J 2.6J 3.1J 0.07U 1.7J 3.0J 0.20U 0.13J 0.18J 12.0J 6.9J 2018-Jun 0.04J 2.4J 196 0.07J 0.13J 0.55J 2.5J 1.2J 0.8J 0.07U 0.97J 2.7J 0.05U 0.11 0.43J 8.8 5.4J 2018-Dec 0.05 J 3.2 J 67.7 0.09 J 0.15 J 0.53 J 1.5 J 0.25 J 0.12 J 0.05 U 1.5 J 2.1 J 0.05 U 0.05 U 0.05 U 9.1 0.84 J 2019-Jun 0.46J 5 418 0.16J 0.13J 2.9J 0.94J 1.4J 0.71J 0.05U 7J 4.3J 0.05U 0.09J 0.05U 11.9 5J 41 of 53 Appendix B MW-16 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 1 A A NE nna INE12001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May NS NS NS NS NS NS NS NM 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS NM 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS NM 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U NM 2019-Jun 0.24 U 0.04 J 0.25 U 100 U 0.12 U 0.59 J 2.71 U NM 42 of 53 Appendix B MW-17 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ! M GWPS 1 10 71 1 1,000 15 1 hm 20 EmmmmmL- 20 2,000 JL3 2001-May --.domEL..- NS NS NS NS NS NS i�_ v� NS NS NS --E�11111 NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.3J 3.6J 51.5J 1 2 1.2J 3.3J 4.8J 5.3J NS 5.2J 2.8J 0.2J 0.03U NS 15.7J 15 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.06U 0.41J 136 0.13J 0.14J 0.33J 1.5J 0.35J 0.34J 0.07U 3.0J 0.51U 0.20U 0.08U 0.13U 4.5J 3.2J 2017-Dec 0.091 2.4J 84.2J 0.31J 0.08U 0.28J 2.4J 0.77J 1.7J 0.07U 2.2J 1.2J 0.20U 0.08U 0.22J 7.1J 5.0J 2018-Jun 0.04 J 0.54 J 89.1 0.16 J 0.111 0.33 J 2.9 J 0.88 J 0.97 J 0.07 U 2.4 J 0.89 J 0.05 U 0.05 U 0.57 J 5.2 8.6 J 2018-Dec 0.04 J 0.03 U 256 0.05 J 0.04 J 0.32 J 0.94 J 0.12 J 0.06 J 0.05 U 5.2 J 0.15 U 0.05 U 0.05 U 0.05 U 1.2 1.5 J 2019-Jun 0.03 U 1.1 J 39 0.05 U 0.04 J 0.18 J 0.2 J 0.17 J 0.03 U 0.05 U 1.4 J 0.68 J 0.05 U 0.06 J 0.05 U 2.9 3 J 43 of 53 Appendix B MW-17 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 14.19 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.52 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 13.72 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 13.44 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 14.59 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 0.5 J 2.71 U 12.44 44 of 53 Appendix B SW-1 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled 2001-May Antimony lir"MINIEU,IL ND Arsenic ND Barium ND Beryllium ND Cadmium AL ND CobaltCopper ND Total ND ND ND ND ND ND ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND 4 ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND 14 ND ND ND ND ND ND 2005-Nov ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND 3 ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 5 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 26 2007-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2008-May 0.2 J 11 174 0.7 J 0.4 J 1.2 J 8.0 J 5.5 25 3.5 J 1.3 J 0.11 0.2 J 40 43 2008-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2009-May 0.1 J 6.3 J 181 0.6 J 0.7 J 1.01 5.1 J 4.9 23 1.9 J 0.8 J 0.11 0.03 U 30 21 2009-Aug NS NS NS NS NS NS NS 2.7 J NS NS NS NS NS NS NS 2010-Jan 0.11 3.9J 89.2J 0.2J 1.9 0.6J 2.1J 0.4J 8.0J 1.3J 0.12U 0.2J 0.11 18.9J 15 2010-May 0.22U 0.91 33.3J 0.11 0.2J 0.3J 0.4J 0.3J 0.91 0.4J 0.32U 0.03U 0.05U 2.0J 2.3J 2010-Nov 0.22U 2J 49.8J 0.11 0.11 0.4J 0.5J 1.7J 11 0.7J 0.32U 0.03U 0.05U 3.1J 5.6J 2011-May 0.14U 3.1J 70.8J 0.12J 0.22J 0.84J 1.8J 0.17J 4.3J 1.3J 0.3J 0.02U 0.05J 6.8J 9.6J 2011-Nov 0.14 U 2.0 J 48.7 J 0.02 U 0.02 J 0.50 J 0.74 J 2.3 J 0.95 J 0.88 J 0.20 J 0.02 U 0.02 U 2.2 J 1.9 J 2012-May 0.13J 4.7J 78.8J 0.191 0.17J 0.89J 2.6J 2.1J 7.0J 3.8J 0.41J 0.1U 0.07U 9.5J 6.4J 2012-Nov 0.02 U 0.93 J 38.0 J 0.07 U 0.07 J 0.42 J 0.54 J 1.3 J 0.45 J 0.46 J 0.17 J 0.1 U 0.07 U 1.5 J 4.8 J 2013-May 0.14J 1.2J 50.2J 0.12J 0.08J 0.73J 2.4J 2.4J 1.6J 0.97J 0.39J 0.03U 0.05J 3.1J 4.1J 2014-May 0.02 U 0.67 J 94.3 J 0.16 J 0.22 J 0.38 J 1.9 J 0.46 J 5.2 J 0.98 J 0.06 U 0.03 U 0.02 J 6.0 J 9.9 J 2014-Nov 0.12 U 0.78 J 86.6 J 0.04 U 0.05 J 0.41 J 0.98 J 0.80 J 0.30 J 1.2 J 0.16 U 0.04 U 0.13 U 0.30 J 3.7 J 2015-May 0.65 J 0.82 J 57.6 J 0.06 J 0.07 J 0.33 J 1.2 J 0.66 J 0.69 J 0.67 J 0.22 U 0.01 U 0.03 J 1.11 2.9 J 2015-Nov 0.10 J 0.71 J 55.8 J 0.02 U 0.04 J 0.26 J 0.86 J 0.68 J 0.38 J 0.80 J 0.46 J 0.01 U 0.02 U 1.3 J 4.7 J 2016-May 0.05 U 0.92 J 56.3 J 0.04 U 0.05 U 0.27 J 1.6 J 0.48 J 0.82 J 0.92 J 0.54 U 0.06 U 0.05 U 1.6 J 3.6 J 2016-Nov 0.05 U 1.2 J 50.0 J 0.05 J 0.05 U 0.34 J 0.95 J 0.45 J 0.32 J 0.72 J 0.54 U 0.06 U 0.05 U 0.57 J 2.4 J 2017-May 0.06 U 1.8 J 128 0.07 U 0.08 U 0.35 J 1.3 J 0.45 J 0.28 J 1.4 J 0.95 J 0.20 U 0.08 U 0.74 J 0.76 J 2017-Dec Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Jun Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Dec 0.17 J 1.6 J 108 0.31 J 0.15 J 0.79 J 6.1 3.1 9.6 2.1 1.4 0.05 0.08 8.4 22 2019-Jun 0.05 J 1.5 J 76.7 0.2 J 0.05 J 5.1 0.56 J 2.2 J 3.9 J 1.8 J 0.87 J 0.05 U 0.05 U 9.4 13 45 of 53 Appendix B SW-1 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina 12001-May GWPS ND ND ND ND NS NS 2001-Nov ND ND ND ND NS NS 2002-May ND ND ND ND NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov Dry Dry Dry Dry NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND ND ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS NS NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.7 NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec Dry Dry Dry Dry Dry NS 2018-Jun Dry Dry Dry Dry Dry NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24 U 0.02 U 0.25 U 0.12 U 0.73 J 2.71 U 46 of 53 Appendix B SW-2 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled SW Standard 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium AL ND CobaltCopper ND Total ND ND ND ND ND E ND ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 2 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.41 U 0.24 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 0.2 U 2007-Nov 0.05 U 2.0 J 126 0.06 U 0.11 0.8 J 1.5 J 1.9 1.6 2.9 J 2.2 J 0.04 U 0.04 U 2.0 J 24 2008-May 0.44U 1.11 71.2J 0.11 0.11 0.8J 1.11 0.8 0.7 1.4J 0.91 0.04U 0.04U 1.4J 7.8J 2008-Nov 0.6J 5.3J 268 0.4J 0.3J 1.91 5.0J 5.6 14 4.2J 3.0J 0.11 0.11 9.2J 96 2009-May 0.06 J 1.4 J 61.6 J 0.06 U 0.04 U 0.4 J 0.5 J 1.5 0.5 0.2 J 0.12 U 0.11 0.03 U 2.3 J 4.8 J 2009-Aug NS NS NS NS NS NS NS 0.8 J NS NS NS NS NS NS NS 2010-Jan 0.11 0.3J 71.3J 0.06U 1.2 0.3J 0.7J 0.4J 0.3J 0.91 0.12U 0.11 0.11 0.8J 8.1J 2010-May 0.22U 1.3J 79.4J 0.11 0.11 0.6J 0.91 0.11 0.5J 1.2J 0.7J 0.11 0.05U 1.5J 5.3J 2010-Nov 0.22U 1.11 59.1J 0.11 0.11 0.5J 0.5J 0.94J 0.11 1.6J 0.6J 0.03U 0.05U 1.11 6.8J 2011-May 0.2 J 0.82 J 71.6 J 0.06 J 0.111 1.5 J 0.58 J 0.46 J 0.5 J 1.8 J 0.22 J 0.02 U 0.02 U 0.86 J 12 2011-Nov 0.14U 2.5J 69.4J 0.06J 0.02J 0.75J 1.2J 1.2J 0.79J 0.991 0.29J 0.02U 0.02U 3.4J 8.2J 2012-May 0.091 2.0J 84.8J 0.07U 0.03U 0.79J 1.4J 0.36J 2.1J 2.9J 0.57J 0.1U 0.07U 2.5J 18 2012-Nov 0.02 U 0.68 J 49.1 J 0.07 U 0.03 J 0.31 J 0.545 J 1.4 J 0.43 J 0.46 J 0.30 J 0.1 U 0.07 U 0.83 J 6.5 J 2013-May 0.04J 0.81J 64.6J 0.07J 0.05J 0.52J 1.6J 0.46J 1.2J 0.65J 0.38J 0.03U 0.02U 1.5J 5.2J 2014-May 0.02 U 1.4 J 72.9 J 0.04 J US U 0.88 J 0.95 J 0.37 J 0.39 J 0.89 J 0.06 U 0.03 U 0.02 U 0.48 J 2.3 J 2014-Nov 0.12U 0.47J 57.7J 0.04U 0.04J 0.34J 0.81J 0.62J 0.21J 1.4J 0.16U 0.04U 0.13U 0.06U 2.0J 2015-May 0.18J 0.56J 59.7J 0.05J 0.02J 0.32J 1.11 0.87J 0.53J 0.70J 0.29J 0.01U 0.02J 0.94J 3.0J 2015-Nov 0.09 J 0.55 J 44.7 J 0.03 J 0.04 J 0.20 J 0.43 J 0.52 J 0.46 J 0.74 J 0.22 U 0.01 U 0.02 U 0.84 J 4.8 J 2016-May 0.09 J 0.89 J 51.8 J 0.04 U US U 0.28 J 0.80 J 0.34 J 0.62 J 0.86 J 0.54 U 0.06 U 0.06 J 0.70 J 2.4 J 2016-Nov US U 0.96 J 65.8 J 0.04 U US U 0.32 J 1.0 J 0.56 J 0.40 J 1.0 J 0.76 J 0.06 U US U 0.54 J 2.9 J 2017-May 0.06 U 1.5 J 77.5 J 0.07 U 0.08 U 0.35 J 0.46 J 0.56 J 0.42 J 1.2 J 0.89 J 0.20 U 0.08 U 0.71 J 1.8 J 2017-Dec 0.06 U 0.54 J 54.4 J 0.07 U 0.08 U 0.24 J 0.64 J 0.43 J 0.33 J 0.6 J 0.86 J 0.20U 0.08 U 1.3 J 2.1 J 2018-Jun 0.07 J 1.3 J 58.3 0.05 J 0.02 U 0.3 J 0.15 U 0.58 J 0.81 J 0.73 J 0.6 J 0.05 U 0.05 U 1.4 1.6 J 2018-Dec 0.04 J 0.68 J 53.8 0.05 U 0.02 U 0.19 J 0.53 J 0.26 J 0.21 J 0.65 J 0.15 U 0.05 U 0.05 U 0.111 1.7 J 2019-Jun 0.05 J 0.95 J 78.2 0.08 J 0.02 J 0.74 J 0.33 J 0.62 J 0.63 J 0.88 J 0.45 J 0.05 U 0.05 U 0.92 J 5 J 47 of 53 Appendix B SW-2 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina 12001-May GWPS ND ND ND ND NS NS 2001-Nov ND ND ND ND NS NS 2002-May ND ND ND ND NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov ND ND ND ND NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND ND ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS ND NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.9 NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 1.2 NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 1.1 2.71U 48 of 53 Appendix B SW-3 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled S 2001-May Antimony NS Arsenic L NS Barium NS Beryllium NS Cadmium AL NS CobaltCopper NS Total NS NS NS NS NS E 0 NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 1 0.41 U 0.24 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 15 2007-Nov 0.05U 0.5J 571 0.11 0.2J 0.7J 0.24U 1.6 0.2 0.7J 0.14U 0.04U 0.04U 0.7J 71 2008-May 0.44U 0.11 63J 0.11 0.11 1.01 0.4J 0.6 0.3 0.8J 0.2J 0.11 0.04U 0.8J 19 2008-Nov 0.11 0.91 75.1J 0.11 0.04U 5.1J 0.3J 1.1 0.9 1.3J 0.3J 0.11 ND 1.2J 36 2009-May 0.06 J 0.8 J 78.7 J 0.11 0.04 U 1.3 J 0.5 J 0.4 0.2 0.4 J 0.12 U 0.04 U 0.03 U 1.9 J 18 2009-Aug NS NS NS NS NS NS NS 0.8 J NS NS NS NS NS NS NS 2010-Jan 0.6J 0.17U 76.1J 0.2J 0.3J 1.2J 0.4J 0.3J 0.6J 0.8J 0.12U 0.2J 0.11 0.91 14 2010-May 0.22U 0.4J 69.2J 0.11 0.11 0.6J 0.4J 0.11 0.6J 0.8J 0.32U 0.03U US 1.4J 11 2010-Nov 0.22 U 0.6 J 75.5 J 0.11 0.11 1.01 0.2 J 1.11 0.5 J 0.8 J 0.32 U 0.03 U 0.05 U 0.9 J 17 2011-May 0.14 U 1.1 J 77.8 J 0.02 U 0.29 J 0.42 J 0.99 J 0.30 J 0.28 J 1.11 0.64 J 0.04 J 0.02 U 0.93 J 5.8 J 2011-Nov 0.14U 0.991 73.3J 0.091 0.14J 1.3J 0.63J 0.34J 1.11 0.76J 0.21J 0.02U 0.12J 1.11 16 2012-May 0.05 J 1.01 60.8 J 0.07 U 0.03 U 0.76 J 0.38 J 0.58 J 0.46 J 5.0 J 0.17 U 0.1 U 0.07 U 1.01 6.0 J 2012-Nov 0.02U 0.50J 74.1J 0.07U 0.04J 0.89J 0.18J 1.11 0.111 0.78J 0.26J 0.1U 0.07U 0.67J 8.2J 2013-May 0.03J 0.35J 30.3J 0.111 0.08J 0.48J 1.6J 0.40J 3.0J 0.47J 0191 0.03U 0.06J 3.4J 6.8J 2014-May 0.02 U 0.26 J 37.9 J 0.04 J US U 0.31 J 0.51 J 0.41 J 1.2 J 0.45 U 0.06 U 0.03 U 0.02 U 1.2 J 2.7 J 2014-Nov 0.46J 0.33J 46.6J 0.08J 0.04J 0.75J 0.14U 0.72J 0.78J 0.53J 0.16U 0.04U 0.13U 1.3J 5.7J 2015-May 0.06J 0.71J 54.2J 0.111 0.03J 0.48J 1.2J 0.72J 2.5J 0.60J 0.22U 0.01U 0.03J 2.5J 6.4J 2015-Nov 0.06J 0.52J 63.2J 0.13J 0.07J 0.74J 0.85J 0.64J 11 0.88J 0.22U 0.01U 0.04J 1.7J 9.4J 2016-May 0.05 U 0.88 J 75.1 J 0.10 J US U 0.72 J 1.11 0.39 J 1.0 J 0.75 J 0.54 U 0.06 U US U 1.7 J 5.2 J 2016-Nov 0.06 J 0.72 J 99.11 0.09 J 0.05 U 0.47 J 0.61 J 0.57 J 0.42 J 0.64 J 0.54 U 0.06 U 0.05 J 1.0 J 5.0 J 2017-May 0.06U 1.1 J 65.7 J 0.07U 0.08U 0.36 J 0.08U 0.57 J 0.56 J 1.11 ND 0.20 U 0.08U 0.95 J 2.6 J 2017-Dec 0.06 U 0.49 J 79.0 J 0.07U 0.08U 0.51 J 0.4 J 0.47 J 0.41 J 0.67 J 0.51 U 0.20U 0.08 U 1.3 J 4.6 J 2018-Jun 0.05J 1.7J 117 0.091 0.03J 0.65J 1.2J 0.66J 1.11 1.11 0.56J 0.05U 0.05U 1.8 5.2J 2018-Dec 0.05 J 0.44 J 77.5 0.05 J 0.02 J 0.32 J 0.37 J 0.46 J 0.32 J 0.79 J 0.15 U 0.05 U 0.05 U 0.57 J 3.6 J 2019-Jun 0.07J 1.91 121 0.12J 0.03J 1.7J 0.67J 0.96J 2.5J 1.6J 0.65J 0.05U 0.05U 2.4 8.2J 49 of 53 Appendix B SW-3 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina 12001-May GWPS 70 nnq NE NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS 2002-May NS NS NS NS NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov ND ND ND ND NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND 1.6 J ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS NS NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND 0.6 NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 1.14 2.71U 50 of 53 Appendix B SW-4 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard ..Barium 640 10 Beryllium Cadmium CobaltA Total 50 7 25 5 0.06 0.47 0 2001-May ivy NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.2J 0.2J 70.9J 0.11 0.11 0.2J 0.3J 0.5J 0.3J 0.6J 0.12U 0.11 0.03U 0.6J 8.8J 2010-May 0.22U 0.6J 82.1J 0.11 0.11 0.5J 0.91 0.3J 1.6J 0.8J 0.32U 0.03U 0.05U 3.0J 3.0J 2010-Nov 0.22U 0.5J 94.2J 0.11 0.2J 0.7J 0.3J 1.5J 0.2J 0.8J 0.32U 0.03U 0.05U 0.91 3.9J 2011-May 0.29J 1.3J 137 0.57J 0.14J 1.6J 3.1J 0.02U 5.7J 1.5J 0.33J 0.02U 0.091 7.2J 9.4J 2011-Nov 0.14U 0.51J 81.2J 0.101 0.05J 0.86J 0.46J 0.42J 0.29J 0.55J 0.20U 0.02U 0.091 0.88J 2.4J 2012-May 0.04J 0.92J 74.3J 0.15J 0.03U 0.72J 1.001 1.2J 1.3J 6.1J 0.17U 0.1U 0.07U 3.0J 0.70J 2012-Nov 0.02U 0.82J 70.6J 0.12J 0.07J 1.7J 1.11 Dry 1.3J 1.11 0.17U 0.1U 0.07U 2.3J 11 2013-May Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2014-May Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2014-Nov Dry Dry Dry Dry Dry Dry Dry 0.60 J Dry Dry Dry Dry Dry Dry Dry 2015-May 0.04J 0.80J 78.3J 0.04J 0.03J 0.34J 0.95J 0.74J 0.84J 0.74J 0.22U 0.01U 0.04J 1.11 5.2J 2015-Nov 0.86 J 0.39 J 74.0 J 0.09 J 0.08 J 0.26 J 0.53 J 0.60 J 0.68 J 0.75 J 0.22 U 0.03 J 0.07 J 1.5 J 9.8 J 2016-May 0.05 U 0.66 U 76.1 J 0.04 U 0.05 U 0.18 J 0.71 J Dry 0.60 J 0.78 J 0.54 U 0.06 U 0.05 U 0.53 J 6.3 J 2016-Nov Dry Dry Dry Dry Dry Dry Dry 1.6 J Dry Dry Dry Dry Dry Dry Dry 2017-May 0.06U 1.2 J 83.3 J 0.07 U 0.08U 0.47 J 3.1 J 1.6 J 4.3 J 1.4 J ND 0.20 U 0.101 5.6 J 8.1 J 2017-Dec 0.07 J 0.14 J 83.0 J 0.07 U 0.08 U 0.24 U 0.08 J 0.68 J 0.24 J 0.94 J 0.51 U 0.20 U 0.08 U 1.11 10 2018-Jun Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Dec 0.04J 0.16J 74.1 0.111 0.04J 0.62J 0.6J 0.43J 0.38J 0.75J 0.15U 0.05U 0.07J 0.7J 4.5J 2019-Jun 0.08J 1.11 71.5 0.12J 0.02U 0.72J 0.36J 1.11 1.11 0.81J 0.38J 0.05U 0.05U 3.1 4.8J 51 of 53 Appendix B SW-4 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina 12001-May GWPS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS 2002-May NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS 2003-May NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS 2004-May NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS 2005-May NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS 2006-May NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS 2007-May NS NS NS NS NS NS 2007-Jun NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS 2008-May NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS 2009-May NS NS NS NS NS NS 2009-Aug NS ND NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May Dry Dry Dry Dry Dry NS 2014-May Dry Dry Dry Dry Dry NS 2014-Nov Dry Dry Dry Dry Dry NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov Dry Dry Dry Dry Dry NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun Dry Dry Dry Dry Dry NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 0.4J 2.71U 52 of 53 Appendix B Notes Historical Analytical Data C&D Landfill, Pitt County, North Carolina NOTES: GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) Surface Water Standard = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters, EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Life, or North Carolina Protective Values for Surface Water< Bold font indicates concentration exceeds GWPS. NS = Not Sampled ND = Not Detected NE = Not Established. S.U. = Standard Units. pS/cm = microsiemens per centimeter. NTU = Nephelometric Turbidity Units. J indicates the reported result is estimated between the laboratry method detection limit and reporting limit U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. * indicates associates GWPS is an IMAC 53 of 53 Water Quality Monitoring Report June 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for • - Analysis Evaluation Date: 29-Aug-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: N /L Sampling Point ID: MW-31S I MW-3A I MW-8 I MW-10 I MW-11 MW-12S 1 1-Nov-15 1.7 1.7 0.24 0.24 2 1-Ma -16 1.3 0.24 0.9 0.5 1.4 3 1-Nov-16 1.2 0.8 1.5 0.6 1.9 4 1-May-17 2.8 2 1.2 0.4 1.7 5 1-Dec-17 1.7 2.7 0.6 0.24 1 2 6 1-Jun-18 1.2 0.5 0.3 0.24 0.9 1.4 7 1-Dec-18 1.3 1.69 0.48 1.57 0.48 1.48 8 1-Jun-19 0.89 1 1.17 2.26 1.89 2.52 9 10 11 12 13 14 15 16 17 18 19 20 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: Stable No Trend Stable No Trend Stable Prob. Increasing 10 M W-3S t M W-3A J M W-8 ai - MW-io v -ix- M W-11 O1 MW-12S i+ d V _ O U 0.1 07115 011161F 08116 03117 09117 04118 10118 05119 12119 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 29-Aug-19 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N IL VINYL CHLORIDE CONCENTRATION / (N9Mann-Kendall Statistic (S): Confidence Factor: U) Concentration Trend: Wo Trend Stable