Loading...
HomeMy WebLinkAbout0201_Alexander_MSWLF_CDLF_Dec2018GW_FID1319924_20190425NC DENR Division of Waste Management - Solid Waste Data - Email CD (data loaded: Yes / No ) Doc/Event #: Environmental Monitoring Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6), Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646, Solid Name Monitoring Data Submittal Information submitting data (laboratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl E-ma: jpmesco.com ilfohl@ Facility name: Facility Address: Alexander County Active C&D and 2500 Paynes Dairy Road Closed Unlined MSWLF Taylorsville, NC 28681 Phone:(919)772-5393 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑X of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data NC Landfill Rule Permit # couvo or. luou) 1600 Assessment Monitoring Actual sampling dates (e.g., October 20-24, 2006) 27-29, 2018 X❑ Corrective Action Methane gas monitoring data Corrective action data (specify) MNA,Phyto. & LFG Extraction Other(specify) Notification attached? No. No groundwater or surtace water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surtace water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Senior Project Manager (919) 772-5393 Facility Representative Name (Print) Title Signature P.O. Box 97. Garner. NC 27529 Facility Representative Address C-0281 NC PE Firm License Number (if applicable effective May 1, 2009) (Area Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal ®q®tiillll//s11/ H CA `pFE 0 ®�,'i $, Q • e� 7 e r• p i r ftft *0 NEEp; ®`ems Semi -Annual Water Quality Monitoring Report with Corrective Action Update Prepared for Alexander County Active C&D and Closed MSWLF Taylorsville, North Carolina December 2018 Permit Number: 02-01 MESCO Project Number: G18003.0 MUNICIPAL ENGINEERING Anii�_SERVICES COMPANYy P.A. \\r // 6B SHIPWASH DRIVE, GARNER, NC 27529 - PHONE: 919-772-5393 \�\\�/��// P.O. Box 349, BOONE, NC 28607 - PHONE: 828-262-1767 LICENSE NUMBER: C-0281 MUNICIPAL ENGINEERING SERVICES C ❑ M PANY9 P.A. GARNER, NC AND B❑❑NE, NC April 22, 2019 Ms. Jaclynne Drummond Solid Waste Section (SWS) Division of Waste Management/ NCDEQ 2090 US Highway 70 Swannanoa, NC 28778 Re: Semi -Annual Water Quality Monitoring Report with Corrective Action Update Alexander County Active C&D and Closed MSWLF Permit No. 02-01 MESCO Project No. G18003.0 Event Date: December 27-29, 2018 Introduction On behalf of Alexander County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report with Corrective Action Update for an event performed at the Alexander County active construction and demolition (C&D) and closed municipal solid waste landfill (MSWLF) on December 27-29, 2018. NCDENR Solid Waste Rules 15A NCAC 13B.1632 requires that Alexander County provide this report to the NC Solid Waste Section (SWS) on a semi-annual basis. Laboratory analytical results indicate that samples collected from 12 wells contained up to three metals above regulatory compliance Standards. Metal detections are believed to be naturally occurring. One or two volatile organic compounds (VOCs) were detected at levels above the 2L Standard in samples collected from 8 wells. The source of VOCs is likely anthropogenic. VOC concentrations continue to decrease over time and distance. A few surface water samples contained elevated levels of metals which are not believed to have originated from a release. Corrective action to remediate VOCs in groundwater is ongoing within the four areas of concern (AOC) with updated information presented herein. A Corrective Action Evaluation Report (CAER) (DIN:27584) dated April 3, 2017 concluded groundwater quality has improved. The SWS approved that corrective action may continue as proposed and the contingency plan is not required to be implemented. Background The Alexander County active C&D and closed MSWLF, is located at 2500 Paynes Dairy Road near Taylorsville North Carolina. The total waste footprint encompasses approximately 24 acres situated on 283 contiguous acres. The site location topographic map is depicted in the attached Sheet 1. The closed MSWLF ceased operation prior to 1998 and the C&D landfill continues operation on the eastern unit of the closed MSWLF. Both landfill areas are treated as a single unit in this report. Water quality has been monitored at this facility on at least a semi-annual basis since 1990. MESCO submitted two Assessment and Corrective Action (ACM) reports dated August 27, 2002 and April 11, 2008. MESCO then developed a Corrective Action Plan -Revision 1 (CAP -Rev 1) on February 6, 2009. In response to improved water quality and changing geochemical conditions the originally selected remediation approach was amended by MESCO in a Corrective Action Plan -Addendum (CAP -Add) dated December 20, 2010. Groundwater remediation efforts have been implemented at the four distinct areas of concern (AOCs) which are identified as MW-113, MW-16, MW-24 and MW-26. Remediation technologies initiated to date with reference to their respective AOC include monitored natural attenuation (MNA) (MW-16, MW-24, MW- 26), phytoremediation (MW-24), enhanced bioremediation via substrate injection (MW-26) and landfill gas (LFG) extraction (MW-1B). 68 Shipwash Drive * Garner, NC 27529 • ph: 919-772-5393 • fx: 919-772-1176 www.mesco.com LICENSE NUMBER: C-0281 Following establishment of the two-year MNA baseline MESCO completed a CAER (DIN 13596) on March 22, 2011. Based on improved water quality conditions as demonstrated in the CAER the parameters and frequencies of future monitoring events were established by the SWS CAER review response (DIN 14150) dated June 16, 2011. A second CAP -Add was submitted by MESCO dated May 30, 2013 as requested by the SWS in a letter entitled Compliance Boundary (Relevant Point of Compliance) (DIN 18502) dated February 18, 2013. A Request for Appendix II Groundwater Monitoring Modification (DIN 20137) was submitted by MESCO dated November 8, 2013 which was subsequently approved by the SWS (DIN 20144) on November 13, 2013. A second CAER (DIN:27584) dated April 3, 2017 concluded that attenuation is occurring and no corrective actions other than what has already been initiated are planned at this time as approved by the NC SWS (DIN:27678). As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, corrective action update, ground/surface water characterization, and findings. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, time -series graph, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. Sampling Procedures MESCO personnel performed this sampling event following the parameters and frequency established in the Water Quality Monitoring Plan (WQMP) dated August 11, 2016. The water quality monitoring program includes a combination of detection, assessment and corrective action monitoring with specifically defined analysis. Water samples were collected from all monitoring locations outlined in the CAP -Add and CAER with the exception of MW-lA; which has been chronically dry and MW-7 which is exempt from testing during the summer event. Monitoring locations are depicted on the potentiometric map (Sheet 2). Sampling was performed per the protocols outlined in the WQMP. A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Submersible pumping or bailing was utilized to purge the wells a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from previously designated locations along discharge features. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre -preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper chain of custody (C-O-C) protocols and within the specified hold times for each analysis. Field Parameter Data Field parameters were recorded including depth to water, pH, specific conductance, temperature, dissolved oxygen (DO), oxidation reduction potential (ORP) and turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix B. Laboratory Results Pace Analytical Services Inc. (PACE) of Huntersville/Asheville, NC performed the laboratory analyses. All water samples were tested for at least the constituents listed in 40CFR258 Appendix I and 1,4-Dioxane. Nine wells were tested for mercury as part of assessment monitoring. Corrective action monitoring was also performed on 13 wells (MW-3, MW-5, MW-6, MW-7, MW-11, MW-12, MW-12D, MW-16, MW-24, MW-25, MW-26, MW-27 and MW-31) which included a previously approved subset of MNA parameters. Additionally; supplemental samples MW-1 and MW-lB were analyzed for dissolved methane to assess remediation progress. Quality control measures implemented during this event included testing of an equipment blank (EB) and field blank (FB). 2 Water samples were analyzed to the Method Detection Limits (MDL) and reported to the Method Reporting Limit (MRL) which are both established by the laboratory. Any value above the adjusted MDL and below the adjusted MRL was flagged as a `j-qualifier" which the laboratory defines as an estimated concentration. A sampling and analysis table summarizing the locations, laboratory, target analytes and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix A. Quality Control Samples No constituents were detected in either of the quality control blanks (EB, FB) which may indicate that the data set is not compromised by field and/or laboratory artifact contamination. Groundwater Samples Detected Above Standards Enclosed Table 5 summarizes constituents detected in groundwater and QC samples compared to current Groundwater Protection Standards (GWP), Interim Maximum Allowable Concentrations (IMAC) and Groundwater Standards (2L) which have been adopted by the NCDEQ SWS as groundwater compliance Standards. Although not applicable for regulatory compliance, detections were also compared to Maximum Contaminant Level (MCL) commonly referenced as the Federal `Drinking Water Standard". Metals Four metals were detected in quantifiable concentrations above their respective 2L/IMAC Standard in samples collected from 12 wells as summarized below. Metals Detected Above 2L/IMAC Standards in Groundwater Cadmium Cobalt Mercury Zinc 2L/IMAC STD. 2 1 1 1000 MW-113 64.7 1.1 MW-2 303 MW-3 21.7 MW-4R 101 MW-6 12.9 MW-9 329 MW-11 43.5 12700 MW-12 48.9 MW-15 85.3 5.8 MW-16 72.6 MW-20 13.7 MW-33 12.8 Concentrations M ug/L. Concentrations between the MDL and MRL are estimated ' J qualified " values and are not shown VOCs One or two aromatic VOCs were detected above their respective 2L Standard in samples collected from 8 wells as summarized below. VOCs Detected Above 2L Standards in Groundwater 71,4-Dichlorobenzene Benzene 2L STD. 6 1 MW-3 8.4 5.2 MW-4R 1.2 MW-5 2.9 MW-7 2.7 MW-9 1.5 MW-11 2 MW-12 1.6 MW-15 2 Concentrations in ug/L. A bar graph and table comparing the most recent levels of VOCs exceeding the 2L Standard compared to their respective maximum observed levels is presented on Figure 1. A site map depicting the spatial distribution of VOC concentrations exceeding the 2L Standard during this sampling event is shown in Sheet 2. Surface Water Samples Detected Above Standards Attached Table 6 summarizes constituents that were detected above MDL compared to the applicable North Carolina Surface Water Standards (2B) for a Class C waterbody. Surface water detections were also compared to NC Protective Values and MCL. Cadmium and copper were detected in elevated concentrations in samples SW-4R and SW-5 respectively. Groundwater and Surface Water Characterization At the landfill, groundwater flow direction generally mirrors topography, thus flow direction is from higher to lower elevations as shown on the potentiometric map included as Sheet 2. Locally, groundwater flow is expected to be generally westerly toward the Lower Little River, and southerly toward the Catawba River. Groundwater linear velocity rates calculated using modified Darcy's equation varied greatly and were slower in the upper bedrock fracture system than the less prominent regolith (Table 7). Streams at designated monitoring points were visually observed to be of normal seasonal volume, flow rate and low turbidity. Hydrogeologic parameters appear generally consistent with historical observations. Corrective Action Update Groundwater remediation continues to be implemented at the four AOCs designated in the CAP -Add. General background information and activities performed since the CAER and last semi-annual event are briefly presented in the following sections. MNA Analysis (AOCs MW-16, MW-24, MW-26) Semi-annual MNA monitoring of 14 wells for the full suite of SWS recommended parameters was initiated on June 30, 2009 and performed during four consecutive semi-annual events to establish a baseline per the 4 CAP -Revision 1. The number of wells requiring MNA analysis was reduced to 10. The parameters and frequency were also amended per the SWS CAER review response (DIN 14150) dated June 16, 2011. MNA data collected during this event is presented on Table 5. Following an acquisition of a 15.7 acre parcel from Crescent Resources on March 3, 2011, extension of the eastern relative point of compliance downgradient of AOC MW-16 has been approved with conditions by the SWS on February 18, 2013 (DIN:18502). Recordation of Survey Plat titled Survey for Notice of Contaminated Site Alexander County Landfill and A Notice and SWS approved Declaration of Perpetual Land Use Restrictions for this parcel has remained at the Alexander County Register of Deeds Office since November 13, 2012. Alexander County purchased another 2.15 acre parcel that adjoins the NE corner with deed recorded on 3/26/18 which effectively increases the relevant compliance boundary in a NE direction. The SWS approved CAP -Add and CAER (2017) clarifies that groundwater remediation of AOC MW-16 will remain as MNA, rather than other technologies described in the preceding CAP -Add. Phytoremediation (AOC MW-24) County personnel planted approximately 200 hybrid poplar trees over an approximate one acre area between MW-7 and MW-12 in May 2010 in an effort to phytoremediate groundwater in the MW-24 AOC. The County continued to maintain the fence -enclosed stand during this semi-annual period which included continuous supplemental watering and eradication of competing vegetation. Total cumulative VOC concentrations in AOC MW-24 during this event have decreased 64% compared to its respective 2 year baseline established in 2010 and a statistical increasing trend is not evident. Assessment of the phytoremediation area which includes tree measurements and downloading groundwater fluctuation from dedicated transducers will continue semi-annually with the next event scheduled for spring 2019. We recommend that additional trees be planted in the Spring of 2019 to replace trees that have died. Enhanced Bioremediation via Substrate Injection (AOC MW-26) In an attempt to remediate benzene as detected in MW-26, Bac-9 was injected 50 ft upgradient in IW-1 on February 17, 2011 following conditions in the Underground Injection Control (UIC) Permit WI0300160. The UIC permit was recently renewed and as directed by the UIC post -injection water quality monitoring of MW-3, MW-11, MW-26, MW-27 and MW-31 is required on a semi-annual basis. Benzene continues to be detected above the 2L Standard in a sample collected from MW-26. Contaminants remain absent from MW-31 located along the MW-26 flow path beyond the compliance boundary. Most recent levels of total VOCs compared to the baseline established during the four events prior to injection exhibited a reduction both upgradient (-55%) and downgradient (-74%) of the injection point. Most recently, total cumulative VOCs from all samples in AOC MW-26 decreased 59% and benzene concentrations fell 41% compared to the baseline averages established during the four events performed over the two years preceding the injection (Figure 2). Further injections are not planned at this time. Landfill Gas Extraction (AOCMW-1B) Three LFG extraction wells (MEW-1, MEW-2, MEW-3) were installed screening the majority of the vadose zone at the northern border of the closed landfill in the vicinity of the scalehouse. MEW-1 was installed on August 17, 2010 with MEW-2 and MEW-3 installed on October 20, 2010. Well control heads were plumbed to a header pipe by the County which was connected to a soil vacuum extraction (SVE) unit on July 5, 2012. An active LFG blower system pilot study was performed by MESCO between June 14, 2012 and July 12, 2012 to evaluate the effectiveness a vacuum would have on reducing levels of LFG in the soil which may remediate the low-level VOCs detected in groundwater hydraulically upgradient of the landfill. A comparison of LFG concentrations and pressures before and after vacuum start-up indicated the system is capable of eliminating LFG migration at all locations monitored within AOC MW-lB. The active LFG Collection Control System (LFGCCS) has been in continuous operation since November 1, 2012 and been verified and documented by MESCO personnel on at least a quarterly basis to be mitigating LFG migration through the vadose at all locations monitored beyond the extraction wells. Improvement in groundwater quality has also been observed in response to implementation of the LFG extraction system as summarized below and shown on Figure 3. Reduction of Constituents Since LFG Extraction Began Dissolved Well ID Methane Benzene Total VOCs MW-1 -100 -86 -91 MW-113 -98 -97 -97 The LFGCCS is planned to continue operation and will continue to be monitored and assessed on a quarterly basis. Findings During this event there were 16 instances of metals detected in quantifiable concentrations above 2L/IMAC Standards which is typical for this site. Cobalt continues to be the most prevalent metal detected and was found in 56% of the samples including the background well. The source of metals is believed to be a product of erosion of natural deposits rather than anthropogenic. Unprecedented concentrations reported during this event include cadmium, lead and zinc in sample MW- 11 and cobalt in sample MW-15. The reported concentration of cadmium, lead and zinc in sample MW-11 are statistical outliers per Rosner's Outlier Test at a 95% confidence level. None of these metals have exhibited a statistically significant increase (SSI) via interpretation of intrawell Shewhart CUSUM control charts with the exception of cadmium at MW-11 (Appendix Q. Surface water samples SW-4R and SW-5, collected on -site, contained total recoverable forms of metals including concentrations of cadmium (1.7 uq/L) and copper (6.6 uq/L) respectively. The NC 2B Standard for these metals is based on the dissolved form and is determined via a calculation that requires a hardness value which was not quantified. Calculations using a hardness of 400 mg/L were used to convert total metals to soluble metals, and were found to be at concentrations below the 213 Standard. The source of the elevated levels of observed metals is not believed to be anthropogenic rather a product of erosion of natural deposits which were high biased from reaction of acid preservative and sediment entrained in the sample containers. Since dissolved samples are not permissible by the DWM a direct comparison to 213 Standards is not possible. We recommend minimizing sediment in sample containers and measuring hardness values so that a more valid comparison to 213 Standards can be made in the future. The semi-annual laboratory results indicate that dissolved phase VOCs, consisting primarily of benzene and a few chlorinated solvents, continue to be detected in groundwater samples collected within 270 feet of the waste boundary. All VOCs detected during this event remain within their own respective historically identified range. Total VOC concentrations do not exhibit an increasing trend over time site -wide and in each of the AOCs. Statistical Sen's Slope trend analysis performed at both a 90% and 95% confidence interval indicates a downward trend of total VOC concentrations at AOC MW-1B and cumulative of all wells site -wide since corrective action was initiated. The same statistical analysis indicates no trend at AOC MW-16, AOC MW-24 or AOC MW-26 Appendix C. Total VOC concentrations during this event, compared to their own respective averages calculated during the two year baseline period (ended in 2010), indicate a reduction in each of the AOC's as shown on Figure 4 and summarized below. 6 Total Cumulative VOCs Baseline Average Compared to December 2018 AOC Total VOCs Baseline (ug/L) Total VOCs Dec. 2018 (ug/L) Reduction ("�u) Statistical Trend AOC MW-lB 12.16 0.58 -95 Downward AOC MW-16 12.14 3.86 -32 No Trend AOC MW-24 7.92 2.83 -64 No Trend AOC MW-26 30.24 12 -60 No Trend AOC Undesignated 12.39 8.96 -28 Downward All Wells 14.58 7.14 -51 Downward Evaluation of current water quality data continues to support assertions drawn in previous reports. VOCs persist in the upper portion of the aquifer but concentrations continue to decrease over time and distance away from the landfill. NINA data and previous screening models indicate that the plumes within each AOC are stabilizing and/or decreasing and there is evidence that natural attenuation is ongoing at the facility. Implementation of the corrective action measures coupled with natural attenuation is expected to decrease VOC concentrations in groundwater over time. Closing Water quality monitoring and corrective action will continue and the next sampling event is planned for spring 2019. If you have any questions or comments regarding this report, please contact us at (919) 772- 5393 or by email at jpfohl@mesco.com or sgandy@mesco.com. Sincerely, MUNICIPAL ENGINEERING SERVICES CO., P.A. Jonathan Pfohl Steven R. Gandy, Ph.D, P.E. Environmental Specialist Senior Project Manager Enclosures cc: Mr. Josh Mitchell Alexander County 7 Tables Table 1 Groundwater Monitoring Well Construction Table December 26-28, 2018 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Soil & Rock Top of Casing Elevation (ft amsl) Ground Elevation Groundwater Elevation Depth to Water (ft btoc) Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) MW-1 9/14/90 2 40.00 25.00 15 1080.54 1077.98 1045.74 34.80 35.8389 -81.1478 MW-1A 9/30/94 2 47.50 32.50 15 Soil & Rock 1085.32 1083.28 <1035.78 Dry (>49.54) 35.8389 -81.1478 MW-16 5/21/03 2 61.00 46.00 15 Rock 1082.56 1079.56 1040.51 42.05 35.8391 -81.1478 MW-2 9/6/90 2 30.00 15.00 15 Soil 1004.48 1002.28 988.52 15.96 35.8376 -81.1524 MW-3 9/19/90 2 33.00 13.00 20 Soil & Rock 1024.73 1024.23 999.10 25.63 35.8365 -81.1503 MW-4R 9/30/94 2 20.50 5.50 15 Soil & Rock 1012.64 1008.54 998.96 13.68 35.8366 -81.1479 MW-5 9/16/94 2 48.80 33.80 15 Soil & Rock 1051.26 1049.01 1013.43 37.83 35.8373 -81.1465 MW-6 9/29/94 2 41.00 26.00 15 Rock 1010.79 1008.29 988.52 22.27 35.8369 -81.1364 MW-7 9/29/94 2 53.00 38.00 15 Rock 1009.24 1005.84 972.03 37.21 35.8364 -81.1522 MW-9 10/24/00 2 31.50 16.50 15 Rock 996.27 993.76 986.16 10.11 35.8361 -81.1481 MW-10 10/25/00 2 91.00 76.00 15 Rock 1040.80 1037.83 1004.96 35.84 35.8366 -81.1469 MW-11 10/24/00 2 56.00 41.00 15 Rock 1011.96 1008.98 977.80 34.16 35.8359 -81.1505 MW-12 10/23/00 2 66.50 51.50 15 Soil 1007.35 1004.46 958.12 49.23 35.3577 -81.1525 MW-12D 6/9/00 2 100.00 90.00 10 Rock 1008.46 1006.03 952.15 56.31 35.3577 -81.1525 MW-13 10/25/00 2 60.50 45.50 15 Rock 1004.56 1001.63 971.87 32.69 35.8368 -81.1532 MW-14 10/26/00 2 40.50 25.50 15 Soil & Rock 997.44 994.06 966.88 30.56 35.8376 -81.1525 MW-15 10/25/00 2 35.00 20.00 15 Soil & Rock 1023.44 1020.81 1002.62 20.82 35.8385 -81.1508 MW-16 12/20/07 2 40.25 25.25 15 Rock 1037.56 1034.94 1009.50 28.06 35.8371 -81.1465 MW-17 6/10/03 2 22.30 7.30 15 Rock 991.16 988.36 976.46 14.70 35.8386 -81.1511 MW-18 12/19/07 2 56.70 41.70 15 Rock 1084.33 1081.52 1033.34 50.99 35.8392 -81.1467 MW-19 12/20/07 2 63.92 48.92 15 Rock 1071.48 1068.67 1018.66 52.82 35.8391 -81.1487 MW-20 12/20/07 2 63.55 48.55 15 Rock 1046.92 1044.19 1005.96 40.96 35.8391 -81.1502 MW-21 12/19/07 2 41.05 26.05 15 Rock 990.00 987.08 960.87 29.13 35.8386 -81.1514 MW-22 12/19/07 2 18.12 8.12 10 Rock 958.97 956.21 944.04 14.93 35.8381 -81.1524 MW-23 12/19/07 2 21.54 6.54 15 Soil 950.48 947.83 935.09 15.39 35.8376 -81.1529 MW-24 12/20/07 2 35.35 20.35 15 Soil 974.04 971.29 945.99 28.05 35.8356 -81.1533 MW-25 12/19/07 2 44.48 29.48 15 Rock 981.93 979.93 958.22 23.71 35.8353 -81.1528 MW-26 12/20/07 2 49.80 34.80 15 Rock 990.69 988.08 974.78 15.91 35.8354 -81.1504 MW-27 12/20/07 2 49.82 34.82 15 Rock 992.19 989.19 979.39 12.80 35.8356 -81.1493 MW-31 8/16/10 2 32.56 17.56 15 Soil 985.42 982.42 973.67 11.75 35.8348 -81.1506 MW-32 8/16/10 2 42.70 27.7 15 Rock 1025.256 1022.26 994.36 30.90 35.8361 -81.1469 MW-33 4/27/13 2 21.38 6.38 15 PWR 1007.40 1004.40 995.07 12.33 35.8367 -81.1462 MW-34 4/27/13 2 21.19 6.19 15 PWR 1014.60 1011.60 1007.01 7.59 35.8373 -81.1459 IW-1 2/14/11 4 52.44 37.44 15 Rock 990.44 987.44 969.12 21.32 35.8356 -81.1504 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) PWR = partially weathered rock Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 2 Field Observations of Monitoring Locations December 26-28, 2018 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Effective Comments MW-1 Yes Yes Yes Yes Yes Yes MW-1A No Yes Yes Yes Yes Yes Dry which is typical MW-1 B Yes Yes Yes Yes Yes Yes MW-2 Yes Yes Yes Yes Yes ? Pad Covered MW-3 Yes Yes Yes Yes Yes Yes MW-4R Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes Case previously repaired datum may have changed MW-6 Yes Yes Yes Yes Yes Yes MW-7 Yes Yes Yes Yes Yes Yes MW-9 Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11 Yes Yes Yes Yes Yes Yes MW-12 Yes Yes Yes Yes Yes Yes Lock replaced MW-12D Yes Yes Yes Yes Yes Yes MW-13 Yes Yes Yes Yes Yes Yes MW-14 Yes Yes Yes Yes Yes Yes County repaired pad since June 2018 MW-15 Yes Yes Yes Yes Yes Yes MW-16 Yes Yes Yes Yes Yes Yes MW-17 Yes Yes Yes Yes Yes Yes MW-18 Yes Yes Yes Yes Yes Yes MW-19 Yes Yes Yes Yes Yes Yes MW-20 Yes Yes Yes Yes Yes Yes MW-21 Yes Yes Yes Yes Yes Yes MW-22 Yes Yes Yes Yes Yes Yes Purge water turbid, pad slightly cracked MW-23 Yes Yes Yes Yes Yes Yes MW-24 Yes Yes Yes Yes Yes Yes Purge water turbid MW-25 Yes Yes Yes Yes Yes Yes MW-26 Yes Yes Yes Yes Yes Yes MW-27 Yes Yes Yes Yes Yes Yes MW-31 Yes Yes Yes Yes Yes Yes MW-32 Yes Yes Yes Yes Yes Yes MW-33 Yes Yes Yes Yes Yes Yes MW-34 Yes Yes Yes Yes Yes ? Pad Covered with sediment IW-1 Yes Yes Yes Yes Yes Yes Injection well. Not sampled this event. SW-3 Yes - - - - - Moderate gage height and flow rate SW-4R Yes - - - - - Moderate gage height and flow rate SW-5 Yes - - - - - Moderate gage height and flow rate SW-6 Yes - - - - Moderate gage height and flow rate Any unusual field conditions, observations, or events: LFG extraction system operating in AOC MW-1 B which is typical. Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 3 Field Parameter Data Summary December 26-28, 2018 Parameter Water Depth Water Elevation TOC Elevation Temp. ORP DO pH Specific Conductance Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C mV mg/L SU umhos/cm Visual or NTU MW-1 34.80 1045.74 1080.54 16.1 NR NR 6.4 F 408 11 Ir Clear 11 MW-1B 42.05 1040.51 1082.56 14.9 NR NR 5.6 79 Clear MW-2 15.96 988.52 1004.48 15.5 NR NR 6.4 67 Clear MW-3 25.63 999.10 1024.73 16.8 NR NR 5.9 443 Clear MW-4R 13.68 998.96 1012.64 14.9 NR NR 5.98 877 Clear MW-5 37.83 1013.43 1051.26 15.5 -5 0.3 6.71 423 Clear MW-6 22.27 988.52 1010.79 14.8 12 0.9 5.4 57 Clear MW-7 37.21 972.03 1009.24 14.8 NR NR 6.2 647 Clear MW-9 10.11 986.16 996.27 15.9 NR NR 6.7 684 Clear MW-10 35.84 1004.96 1040.80 14.9 17 NR 7.3 139 Clear MW-11 34.16 977.80 1011.96 15.4 5 0.4 5.8 722 Clear MW-12 49.23 958.12 1007.35 15.2 53 0.9 5.2 387 Clear MW-12D 56.31 952.15 1008.46 15.1 21 0.9 7.2 871 Clear MW-13 32.69 971.87 1004.56 15.3 NR NR 6.82 327 Clear MW-14 30.56 966.88 997.44 14.9 NR NR 5.7 53 Clear MW-15 20.82 1002.62 1023.44 15.4 NR NR 5.9 408 Clear MW-16 28.06 1009.50 1037.56 15.1 201 0.7 5.83 152 Clear MW-17 14.70 976.46 991.16 14.3 NR NR 5.1 79 Clear MW-18 50.99 1033.34 1084.33 14.5 203 2.1 4.3* 43 8.91 MW-19 52.82 1018.66 1071.48 14.4 NR NR 6.7 316 Clear MW-20 40.96 1005.96 1046.92 15.3 NR NR 5.8 237 Clear MW-21 29.13 960.87 990.00 14.5 NR NR 5.2 67 Clear MW-22 14.93 944.04 958.97 14.7 NR NR 5.21 37.2 Clear MW-23 15.39 935.09 950.48 12.5 NR NR 5.5 73 Clear MW-24 28.05 945.99 974.04 13.1 109 0.3 6.2 132 Moderate MW-25 23.71 958.22 981.93 13.4 173 0.6 6.0 79 Clear MW-26 15.91 974.78 990.69 16.4 31 2.1 6.32 375 Clear MW-27 12.80 979.39 992.19 15.0 83 2.6 7.5 326 Clear MW-31 11.75 973.67 985.42 15.5 119 0.9 5.3 151 Clear MW-32 30.90 994.36 1025.256 14.8 NR NR 7.1 60 Clear MW-33 12.33 995.07 1007.40 14.8 NR NR 5.3 44 Clear MW-34 7.59 1007.01 1014.60 13.6 NR NR 5.6 45 Clear IW-1 21.32* 969.12* 990.44 NR NR NR NR NR NR Minimum 7.59 935.09 950.48 12.5 NR NR 5.1 37 Clear Average 27.79 986.87 1013.92 14.9 NR NR 6.1 275 Slight Maximum 56.31 1045.74 1084.33 16.8 NR NR 7.5 877 Moderate SW-3 - - - 6.8 NR NR 6.91 363 Clear SW-4R - - - 9.0 NR NR 6.5 69 Clear SW-5 - - - 8.4 NR NR 7.0 55 Clear SW-6 - - - 8.2 NR NR 7.3 29 Clear Minimum - - - 6.8 NR NR 6.5 29 Clear Average - - - 8.1 NR NR 6.9 129 Clear Maximum - - - 9.0 NR NR 7.3 363 Clear NR = No Reading Attempted Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 4 Sampling and Analysis Summary December 26-28, 2018 App. I Other App. 11 MNA Field Parameter a O W O a -a a) C o > N O N N U 7 M N C O O X O N tY c N N C H O N z W o i a O 6 '16 +' U O 6 �' O O O N C O 'C .� N N '6 LL N N 7 c a ' Q o `�° o U o c 2 0 E a O O O ? O LL >. N f0 Y 7 7 L Q O O O — X N O 2 7 U > H > 2 W U Q Cn W U H U o0 — Z 0 O H U a H o 0 oIn U w ai m o o O co or- o L U m Z N N O Q N O V N N O O V c0 O u07 m O 0 O m u- Q a W Q a Q a U O Lo O _ Y C) N CC O M In N N N N N N N N Y N U Q U) CoCry Lo LO LO M a '��:2 Method 4 -O O O cc Q ' J JJ J Q Q W Q m J W J J fn !n fn !n J LL LLLL LL LL MW-1 x x x x x x x x MW-1A Dry so not sampled which is typical MW-1 B x x x x x x x x x MW-2 x x x x x x x x MW-3 x x x x x x x MW-4R x x x x x x x x MW-5 x x x x x x x x x MW-6 x x x x x x x x x MW-7 x x x x x x x MW-9 x x x x x x x MW-10 x x x x x x x MW-11 x x x x x x x x x x x x x x x x x x x MW-12 x x x x x x x x x x x x x x x x x x x MW-12D x x x x x x x x x x x x x x x x x x x MW-13 x x x x x x x MW-14 x x x x x x x MW-15 x x x x x x x x MW-16 x x x x x x x x MW-17 x x x x x x x x MW-18 x x x x x x x x x MW-19 x x x x x x x MW-20 x x x x x x x MW-21 x x x x x x x x MW-22 x x x x x x x MW-23 x x x x x x x MW-24 x x x x x x x x x x x x x x x x x x x MW-25 x x x x x x x x x MW-26 x x x x x x x x x x x x x x x x x x x MW-27 x x x x x x x x MW-31 x x x x x x x x x x x x x x x x x x x x MW-32 x x x x x x x MW-33 x x x x x x x MW-34 x x x x x x x SW-3 x x x x x x x SW-4R x x x x x x x SW-5 x x x x x x x SW-6 x x x x x x x EB x x x x FB xT x x App I = Appendix I Listed in current 40 CFR 258 Alexander County Active C&D and Closed MSWLF Page 1 of 1 Table 5 Groundwater and QC Sample Detections December 27-29, 2018 Parameter Name MDL 2L/GWP/IMAC MCL MW-18 MW-1 MWAB MW-2 MW-3 MW-4R MW-5 MW-6 MW-7 MW-9 MW-10 MW-11 MW-12 MW-121) MW-13 I MW-14 MW-15 I MW-16 MW-17 MW-19 MW-20 MW-21 MW-22 MW-23 MW-24 MW-25 MW-26 MW-27 MW-32 MW-31 MW-33 MW-34 EB FB STANDARD BG I S S S S S S S S S S S S S S I S S I S I S I S S S S S S S S S S S S S QC QC Metals (Targeted 40 CFR 258 Appendix I List) Barium, total 2.5 700 2000 18 J 25.8 J 54.8 J 28.3 J 53.9 J 124 14.9 J 38.6 J 6.6 J 220 12.4 J 68.8 J 104 9.4 J 13.7 J 30.9 J 81.5 J 20.4 J 26.3 J 5.8 J 54.9 J 27.3 J 51.1 J 21.7 J 38.8 J 60.7 J 13.8 J 57.5 J 7.9 J 25.8 J 21.1 J Cadmium, total 0.5 2 5 0.52 J 0.82 J 1.1 0.7 J 1.1 0.84 J 1.2 0.53 J 3.8 (N) 0.87 J 0.52 J 1.8 13.7 (N) 1.8 0.69 J Chromium, total 2.5 10 100 2.9 J 4.5 J 4.1 J 3.1 J Cobalt, total 2.5 1 NE 7.4 J (N) 5.2 J (N) 64.7 (N) 303 (N) 21.7 (N) 101 (N) 12.9 (N) 329 (N) 43.5(N) 48.9 (N) 6.9 J (N) 85.3 (N) 72.6(N) 6 J (N) 3.8 J (N) 4.3 J (N) 4.7 J (N) 12.8 (N) Copper, total 2.5 1000 1300 4.4 J 34.1 3.2 J 3.6 J 4.2 J 12.5 2.9 J Lead, total 2.5 15 15 7.3 J 3 J 44 (N) 3.8 J Nickel, total 2.5 100 NE 6.2J 3.1J 5.5J 6.7J 10.4J 6.4J 3.8J 49.4J 5.1J 6J 7.7J 5.7J 2.6J 4.2J 3J 10.7J 4J 7.4J 2.9J Thallium, total 0.06 0.28 2 0.15 J 0.081 J 0.18 J 0.23 J 0.16 J 0.064 J 0.071 J Vanadium, total 2.5 0.3 NE .8 J (NJ 3.6 J (N) Zinc, total 5 1000 NE 7.7 J 30.8 11.5 13.5 1 13.8 1 12.9 18.2 20.8 8.2 J 12700 (N) 140 11.2 6.8 J 8.1 J 13.4 5.5 J 7.1 J 14.4 31.4 47.3 6.2 J 9.1 J 7.5 J VOCs (Targeted 40 CFR 258 Appendix I List and 1,4-Dioxane) 1,2-Dichlorobenzene 0.3 20 NE 0.67 J 1,2-Dichloroethane 0.24 0.4 5 0.27 J 1,4-Dichlorobenzene 0.33 6 75 8.4 2-Butanone (MEK) 0.96 4000 NE 1.2 J 1.6 J Acetone 10 6000 NE 21.3 J 50.2 J Benzene 0.25 1 5 0.81 J 5.2 1.2 2.9 2.7 1.5 0.84 J 2 1.6 0.42 J 2 0.84 J 0.39 J 0.85 J cis-1,2-Dichloroethene 0.19 70 70 0.84 J 0.66 J 0.24 J 4.5 J 8.7 12.3 5.7 14.5 2.3 J 10.7 6.7 0.66 J 0.69 J 4.6 J 5 1.5 J 0.57 J 6 13.9 1.9 J 0.35 J Ethylbenzene 0.3 600 700 0.92 J Toluene 0.26 600 1000 0.96 J Xylene (Total) 0.66 500 10000 1.2 J 1,1-Dichloroethane 0.32 6 NE 1 J 2.1 J 1.1 J 0.55 J 0.67 J 1 J 1.1 J 0.4 J 0.55 J 0.68 J Assessment Monitoring Parameters (Targeted Mercury, total) Mercury, total 0.1 1 2 1.1 0.17 J 0.39 - -- I -- 1 5.8 - 0.12 J - MNA Parameters Sulfide 50 NE NE -- - 59.1 J 59.7 J - - Alkalinity (total) 1000 NE NE - 261000 130000 422000 29000 155000 - - Sulfate 500 250000 NE - 896 J 7790 J 2430 J 3260 J - - Chloride 500 250000 NE - 64600 22400 63200 14900 19800 W496C - - Nitrogen, Nitrate 10 NE NE - 63.5 J 748 J - - - 304 J - - Chemical Oxygen 12500 NE NE - 90200 26900 26900 - - - 68200 24200 J - - Total Organic Carbon 500 NE NE -- - 8620 3120 3680 - 4920 2900 - - Methane 10 NE NE 76.6 29.6 8460 29.3 - 10900 7330 8140 1970 1550 I - Iron, Ferrous 500 NE NE -- 620 10300 1 -- I I -- Turbidi NTU 0.01 NE NE 8.81 78.6 19 Units ug/L, Blank cells means Not Detected, -- means not tested Red Bold Above Established MCL/2LIGWPIIMAC Std. Regulatory compliance standard Above Established Federal MCL Drinking Water Std. No regulatory compliance significance. MDL = Method Detection Limit, SWSL = Solid Waste Section Limit, 2L/GWP Standard = NC 2L and MAC Standards adopted by SWS, MCL = Maximum Contaminant Level for Drinking Water J= "J-qualified". Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. Preliminary source is believed to be anthropogenic with leachate &/or landfill gas as transport mechanism A definitive source of the detections was not determined as part of this report. BG = Background Well Sample, QC = Quality Control Sample, S = Sentinel Well Sample Alexander Co Active CDLF and Closed Unlined Landfill Page 1 of 1 Table 6 Surface Water Sample Detections December 27, 2018 Parameter Name MDL NC 2113 NC PV MCL SW-3 SW-4111 SW-5 SW-6 Downstream STANDARD Downstream Downstream Downstream Metals Barium, total 2.5 NE (Appendix I 21000 2000 38.1 J 37.6 J 23.8 J 19.3 J Cadmium, total 0.5 NE NE 1.7 Cadmium, dissolved 0.82-9.15 NE NE 1.51-1.70 Cobalt, total 2.5 NE 4 NE 14.2 Copper, total 2.5 NE NE 1300 6.6 J Copper, dissolved (Conversion) 3.64-49.62 NE 1300 6.34 Zinc, total 5 NE NE NE 12.2 6.9 J Zinc, dissolved (Conversion) 36.2-379.30 NE NE 11.93 6.75 VOCs (Appendix 1) cis-1,2-Dichloroethene 0.19 NE 720 70 0.81 J Units ug/L, Blank cells means Not Detected, -- means not tested , NE means Not Established Red Bold Above Highest Established 2B Std. Regulatory compliance standard Above Established Federal MCL Drinking Water Std. No regulatory compliance significance. NC PV= NC Protective Value. These criteria may be based on limited toxicological information and are offered as guidelines only. Contact DWR staff for further J = "J-qualified" by lab. Estimated concentration above the adusted method detection limit and below the adusted reporting limit. 2B Standard for cadmium. copper and zinc are determined via a calculation (below) for acute that is dependent upon hardness. Copper Acute total to dissolved conversion factor 0.960 provided by the US EPA. Copper Calculation:WER*[0.960*e^{0.9422[ln hardness]-1.700)] Zinc Acute total to dissolved conversion factor 0.978 provided by the US EPA. Zinc calculation:WER*[0.986*e^(0.8473[In hardness]+0.884)] Copper Acute total to dissolved conversion factor 0.960 provided by the US EPA. Copper Calculation:WER*[0.960*e^{0.9422[In hardness]-1.700)] Cadmium Acute total to dissolved conversion factor 1.136672-[(In hardness)(0.041838)] provided by the US EPA Cadmium calculation:WER*[{1.136672-[In hardness](0.041838))*e^{0.9151[in hardness]-3.1485)] Hardness ranges to use in calculations per 2B Rules are min: 25 mg/L and max: 400 mg/L Alexander Co Active CDLF and Closed Unlined Landfill Page 1 of 1 Table 7 Hydrogeologic Proporties at Monitoring Well Locations December 27-29, 2018 Monitoring Well Hydraulic Conductivity (cm/sec) Effective Porosity N Hydraulic Gradient (ft/ft) Average Linear Velocity Rate (ft/yr) Flow Direction Depth to Groundwater (ft BTOC) Groundwater Pot levati on etric Elevation (ft amsl) Screened Interval Lithology MW-2 3.70E-06 28 0.370 5 S54E 15.96 988.52 =dj UC MW-12 n/a 28 0.061 n/a S34E 49.23 958.12 UC MW-16 8.72E-04 17 0.088 1 466 S28E 28.06 1009.50 UC MW-17 n/a 17 0.217 n/a S44E 14.70 976.46 UC MW-21 3.77E-03 28 0.217 3028 S53E 29.13 960.87 UC MW-22 6.04E-04 28 0.192 429 S57E 14.93 944.04 UC MW-23 9.83E-04 28 0.327 1189 S41 E 15.39 935.09 UC MW-24 1.33E-02 28 0.095 4692 S84W 28.05 945.99 UC MW-31 n/a 28 0.204 n/a S87W 11.75 973.67 UC MW-33 n/a 28 0.091 n/a S33E 12.33 995.07 UC MW-34 n/a 28 0.093 n/a S34E 7.59 1007.01 UC Minimum 3.70E-06 17 0.061 5 7.59 935.09 - Average 3.26E-03 26 0.178 1635 20.65 972.21 - Maximum 1.33E-02 28 0.370 4692 - 49.23 1009.50 - MW-1 5.60E-05 10 0.174 101 S35E 34.80 1045.74 UC/UBR MW-3 3.90E-06 10 0.116 5 S28W 25.63 999.10 UC/UBR MW-4R 4.90E-04 10 0.063 321 S17W 13.68 998.96 UC/UBR MW-5 6.40E-05 28 0.045 11 S22E 37.83 1013.43 UC/UBR MW-14 n/a 10 0.400 n/a S54E 30.56 966.88 UC/UBR MW-15 n/a 10 0.134 n/a S31E 20.82 1002.62 UC/UBR Minimum 3.90E-06 10 0.045 5 13.68 966.88 Average 1.53E-04 13 0.155 109 27.22 1004.46 - Maximum 4.90E-04 28 0.400 321 37.83 1045.74 - MW-1B n/a 10 0.294 n/a N19W 42.05 1040.51 UBR MW-6 2.40E-05 10 0.167 41 S84W 26.27 988.52 UBR MW-7 1.60E-06 10 0.090 1 S24W 37.21 972.03 UBR MW-9 n/a 10 0.104 n/a S41 E 10.11 986.16 UBR MW-11 n/a 10 0.055 n/a S29W 34.16 977.80 UBR MW-13 n/a 10 0.172 n/a S42W 32.69 971.87 UBR MW-19 1.92E-06 10 0.089 2 S52E 52.82 1018.66 UBR MW-20 5.49E-05 10 0.079 45 S80W 40.96 1005.96 UBR MW-25 5.41 E-05 10 0.005 3 N67W 23.71 958.22 UBR MW-26 1.16E-04 10 0.030 36 S27W 15.91 974.78 UBR MW-27 2.83E-05 10 0.044 13 S03W 12.80 979.39 UBR MW-32 n/a 10 0.063 n/a S10E 30.90 994.36 UBR ini'mum 1.60E-06 10 0.005 1 10.11 958.22 - Average 4.01 E-05 10 0.099 20 29.97 989.02 - Maximum 1.16E-04 10 0.294 1 45 52.82 1040.51 - MW-10 n/a 10 0.052 n/a S11E 35.84 1004.96 LBR MW-12D n/a 10 n/a n/a n/a 56.31 952.15 LBR MW-18 1.19E-04 10 0.161 n/a N15W 50.99 1033.34 LBR inimum 1.19E-04 10 0.052 35.84 952.15 - Average 1.19E-04 10 0.107 - - 47.71 996.82 - Maximum 1.19E-04 10 0.161 56.31 1033.34 - NOTE: Values for hydraulic conductivity obtained from GAI Consultants Sampling Report (April, 1995) & MESCO ACM Report (2008). Average Linear Groundwater Velocities calculated only for UC & UBR wells with hydraulic conductivity values. UC = Unconfined/saprolite; UBR = Upper Bedrock fracture system; LBR = Lower Bedrock fracture system. Wells screened in LBR not utilized for flow directions/gradients. Hydrologic Gradient taken from water elevations recorded on December 27-29, 2018. Flow rate (Q) calculated via modified Darcy's equation: K= hydraulic conductivity Ane = effective porosity ng dh= head difference d1= horizontal distance Alexander County Active C&D and Closed MSWLF Page 1 of 1 Figures Figure 1 VOC 2L Exceedance Comparisons Histograms 4 2 VOCs >2L Std (December 2018 Compared to Maximum) ■ BENZENE Max ■ 1,4-DCB Max BENZENE Dec-2018 1,4-DCB Dec-2018 8 3 6 4 2 0 Parameter Name 2L Std. MW-3 MW-4R MW-5 MW-7 MW-9 MW-11 MW-12 MW-15 Dec-18 Max Dec-18 Max Dec-18 Max Dec-18 Max Dec-18LM Dec-18 Max Dec-18 Max Benzene 1 5.2 13 1.2 5.6 2.9 6.1 2.7 6.7 L L 2 1.6 8.2 2 5.3 1,4-Dichlorobenzene 6 8.4 10.6 Maximum=Highest ever reported (1995 through Dec. 2018) Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 2 Total VOCs and Benzene Concentrations Pre/Post Injection Comparison in AOC MW-26 June 30, 2009 - December 29, 2018 Total Cumulative VOCs Time Series Graph MID shown 112 DL) 1sa 0 1ao a� IMUV27 7Mw3 1IdW11 JU IMU �AOCNMW Benzene Tme Series Graph lND shown 0) Hydraulic Gradient In June 2009 (ug/L) Dec. 2009 (ug/L) July 2010 (ug/L) Dec. 2010 (ug/L) Average of Four Events Preceding Injection (ug/L) All VOCs Benzene Relation to Injection Well (IW-1) Well ID All VOCs BenzeneBenzene All VOCs Benzene All VOCs Benzen e All VOCs Benzene Dec. 2018 (ug/L) Change (ug/L) Change % Dec. 2018 (ug/L) Change (ug/L) Change % Up MW-3 61.66 8.10 F43.03 7.20 31.50 6.00 37.04 6.10 43.31 6.85 23.05 -20.26 -47 5.20 -1.65 -24 Up MW-11 53.28 5.00 4.50 40.81 5.90 43.20 4.20 45.89 4.90 14.30 -31.59 -69 2.00 -2.90 -59 Up MW-27 23.70 0.00 0.00 24.60 0.00 28.00 0.00 24.13 0.00 13.90 -10.23 42 0.00 0.00 0 Subtotal Upgradient 138.64 13.10 109.48 11.70 96.91 11.90 108.24 10.30 113.32 11.75 51.25 -62.07 -55 7.20 -4.55 -39 Down MW-26 39.40 1.40 20.00 1.40 39.50 3.20 30.75 1.60 32.41 1.90 6.85 -25.56 -79 0.85 -1.05 -55 Down MW-31 0.00 0.00 0.00 0.00 0.00 0.00 4.61 0.00 1.15 0.00 1.90 0.75 65 0.00 0.00 0 Subtotal Downgradient 39.40 1.40 20.00 1.40 39.50 3.20 35.36 1.60 33.57 1.90 8.75 -24.82 -74 0.85 -1.05 -55 Up&Down Gradient Total 1178.041 14.50 1129.481 13.10 136.411 15.10 1143.60 11.90 146.88 13.65 60.00 -86.88 -59 8.05 -5.60 -41 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 3 Histograms of Parameters in LFG Extraction Area DISSOLVED METHANE IN GROUNDWATER 8 6 J 4 0) E 2 0 NOV 2012 JUNE 2013 (Post) DEC 2014 (Post) JAN 2016 (Post) DEC 2016 (Post) DEC 2017 (Post) DEC 2018 (Post) JUNE 2012 (Pre) JUNE 2014 (Post) JUNE 2015 (Post) JULY 2016 (Post) JUNE 2017 (Post) JUNE 2018 (Post) MW-1 ................ MW-1 B Extraction Started 1 JL I I 3: -1 , I 3: -i d � � � A �4 I .1. � 1 A J. .6 I d ,1 m .� m e m m m m o 0 0 0 0 0 0 0 0 0 0 0 0 Total Cumulative VOCs >O.nnM ua.� REDUCTION SINCE LFG EXTRACTION BEGAN WELL ID DISSOLVED METHANE TOTAL BENZENE VOCS N N N MW-1 -100 -86 -91 MW-1 B -98 -97 -97 0 0 -1, �tl -L -L J. �II II1 a 71 Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Figure 4 Total VOC Concentrations Histograms Baseline (June 24, 2009-December 9, 2010) Compared to Dec. 2018 35 30 25 J p 20 15 10 TOTAL VOC(s) BASELINE AVERAGE COMPARED TO DEC. 2018 VW-1B MW-16 MW-26 MW-24 UNDESIGNATED SITEWIDE AREA OF CONCERN F.BASELINE AVERAGE ■ DEC 2018 AOC ID WELL ID TOTAL VOC(s) BASELINE AVERAGE (June 2009- Dec. 2010) (ug/1) TOTAL VOC(s) LATEST Dec. 2018 (ug/1) DIFFERENCE BETWEEN LATEST AND BASELINE (ug /L) DIFFERENCE BETWEEN LATEST AND BASELINE (D�D) STATISTICAL TREND* Between June 2009 - Dec. 2018 MW-1 27.86 1.65 -26.21 -94 . Downward. MW-1A NS NS NA NA HNo TrendH MW-1B 17.31 0.66 -16.65 -96 Zownward� MW-1B MW-18 0.00 0.00 0.00 0 HNo TrendH MW-19 3.48 0.00 -3.48 -100 HNo TrendH AOC AVG 12.16 0.58 -11.59 -95 Zownward. MW-5 19.84 38.60 18.76 95 TUpwardT MW-10 3.24 3.14 -0.10 -3 HNo TrendH MW-16 45.06 6.94 -38.12 -85 Downward MW-16 MW-32 0.00 0.00 0.00 0 HNo TrendH MW-33 4.40 0.00 -4.40 -100 HNo TrendH MW-34 0.30 1.03 0.73 243 HNo TrendH AOC AVG 12.14 8.29 -3.86 -32 HNo TrendH MW-6 0.00 0.00 0.00 0 HNo TrendH MW-7 15.27 9.77 -5.50 -36 Zownward. MW-12 34.39 8.97 -25.42 -74 �Downward� MW-24 MW-12D 1.00 1.08 0.08 8 HNo TrendH MW-13 1.59 0.00 -100.00 -100 HNo TrendH MW-24 3.18 0.00 -2.00 -100 Zownward. MW-25 0.00 0.00 0.00 0 HNo TrendH AOC AVG 7.92 2.83 -18.98 -64 HNo TrendH MW-3 45.47 23.05 -22.42 -49 Downward MW-11 47.84 14.30 -33.54 -70 Zownward. MW-26 32.41 6.85 -25.56 -79 HNo TrendH MW-26 MW-27 24.32 13.90 -10.42 -43 Downward MW-31 1.15 1.90 0.75 65 HNo TrendH AOC AVG 30.24 12.00 -18.24 -60 Zownward. MW-2 30.99 0.24 -30.75 -99 HNo TrendH MW-4R 26.73 10.90 -15.83 -59 Zownward� MW-9 19.55 16.55 -3.00 -15 Downward MW-14 17.81 0.69 -17.12 -96 HNo TrendH Undesignated MW-15 13.38 57.80 44.42 331 HNo TrendH (No MW-17 10.55 2.29 -8.26 -78 HNo TrendH Remediation) MW-20 0.69 1.12 0.43 62 HNo TrendH MW-21 0.77 0.00 -0.77 -100 HNo TrendH MW-22 2.70 0.00 -2.70 -100 HNo TrendH MW-23 0.68 0.00 -0.68 -100 HNo TrendH AOC AVG 12.39 8.96 -3.43 -28 Zownward. ALL WELLS ALL WELLS AVG 14.58 7.14 -7.44 -51 Zownward. NS = Not sampled since dry = Statistical trend analysis of all events between June 2009 and Dec. 2018 via Sen's Slope Estimator at both a 90 % or 95 % Confidence Level Alexander County Active CDLF and Closed MSWLF Page 1 of 1 Sheets Topographic Map with Site Location Alexander County Active C&D and Closed MSWLF 'rv��o a1.7e oevewr.•r�f o�' -xe irvreRiov t.... '' . l �. w' lC ,•� •rea+d,.e.w,.e+...�wwr.+•rr s.•,� 2500 Paynes Dairy Road Taylorsville, NC 28681 Lat:35-15-18.7246 Long:-81-08-51.51.32 Northing:767009.09 Easting:1363506.43 tN LANDFILL PROPERTY WWI r• e .-�. ... MlutfNYiuy n.c QUADRANGLELEGEND ROAD CLASSIFICATION Primary highway, Light -duty road, hard or hard surface .............. improved surface .... ___ Secondary highway, hard surface ............ Unimproved road..._________ 0 Interstate Route 0 U. S. Route O State Route 0 1/2 1 MILE SHEET 1 GWE-1018.66 / MW-1B MW-18 GWE an rim �� / / / / M _ M' GWE=1033.34 / / / / =1040.51 BMW--20 Z GWE-_ _1005.96 / ��/ / // / // / — �♦yMW--21\ �\ /� / / / / / / ♦ GWE=960.87 \ \ \ \ \\ \ _ I ( / / MW--1 \\\\ \\ III \ I � / �� / �� d' 1 / / / / / / / / \ \ \ \ \ \\ \ \ /� • GWE=1045.74 ' / I GWE=976,46 \ \ \ \ wo / \ i ` / _} \ / ♦ ♦� 1 \\ III \ \ \\ \\ / / 0 Benzene-2u MEW-1 —MEW-3® 1GWE=1002. MEW-2 —__ —77\ I I — — % /i = Q6 / ( I — — 80 — — \\\ LFG VENTING SYSTEM MW-22 WE=944 G.04' // / / �► / / // �� / / // / j / / / / / �/ /// / / / 1 0� \ // / \ / // // CLOSED // MSWLF -, GWE=s35.09 // // / / / l / // // //// / / / /_// _/ / /i1 Jr/ //// O �o� --------- ------------ —� / //// /// r // // wE-ss8.52, l/% / MW / / / / / /1 I \ /-- - - - - - . GWE=966.88��/ I I \ / /�-- - Ben -2.9u I \ -- / -_ _ - / GWE-1013.43/ S W / �'COO \ 34 ACTIVE C&D OVER CLOSED MSW MSWLF / / / / / / // /i / // I I \\\ \ \ \ \ \ \ \0806� III I I ✓ /�i/ // / // - - - - / i / / SW-6 MW-16,/ / / I l /G ssa.52 // \' \// \ III �� \\\ \\\ \ o\\ III III Il\\ \ \ _ —__ , �// / / — — — — /// / / % / / GWE=1009.50 �=iii //"-�� \ \\\ \ \ \ \\i,-\/ � I/l / /— / FILL AREA 2990MW-13\\ \ _—404GWE=97187 _1070�_— l / l I � ��__ _;� �_ � I III \ \\� �-— - — — — — — — — — — — � 98 _�— I / \\\� ��_—_--------_-- v� 1_0-60\MW-33 / BMW-10 GWE-9s51.01 7III II 1 30 GWE=1004.96 /T I I \ \ I I \ \ \ J.� ___ D4Q —���� \ _=__ _////ill// \ \GWE=998.96\ \ \ \ ///// //// ////// III 11111 IIII Aenzene - 2.7 ug/ / c — _ \ - - --- GW�s7%o3,�\\Mw3 , --------- _ \� \ o —� o/o\ \ \ \ \ \ \ \ � wE-sss.lo \ \ \\\ \ \ V �v v / 0 — /i MW-3 - IIII IIII IIII IIII Benzene --5./-2u /I1 I /l 1,4-DCB8.4u / -I 110_000 // �M—W_� 32 —GWE 994.�36S \e \ v - III I I I II I III1III/II I 1 1 III IIII lIIIlIII l IIIIII I III II III I I III \\ \ \ \ Benzene- I I \ \ \ \ MW-11 �►— 8. o / /GWE=958.12 ^ / / / — — — — Sw-5 \ \ 1 \ \ / / � A / � � �,�� --, GWE=s�7.ao , � � / l � v / / // , i � / I V A \ \ \ 11 1 A \ \ / / / / i / \ \ / /// M � \\ \ \111 1 MW-12D - l A GWE=952.15 I , IW1 MW-24GwE=ss9.12 1 I I 1 �_--- o/ / I \ I I / II I Ills► 1 \ \ \ \ / // // / /, I I I \ \ GWE=945.99 1 \ ` P-2I MW-27 \ \ \ \ X 990_ 'GWE— - / / MW126 I /ll l( //. GWE=974.7s /Ill/ �� I I I 1 I I/ III II ►r\tl 11 IIII II \\V A\11 IIII / // / llllll l / / // (111 I I I III IIII I _ vv yvv vv v MW--25 v v v \ / // / / I / / / /'L� —� T \\ \ \ \ \ J I I 1\1� /1 �' ,// �" cwE=s5s.22 LEGEND TRANSFERSTATION ESTIMATED WASTE LIMITS FACILITY PROPERTY BOUNDARY EXISTING TOPOGRAPHIC CONTOURS MW--31 _ �� ///\\__ \ // / \ \ / \\ II 1 \\ / � II / / IIII I/ l /I I I I \✓ �\nl COMPLIANCE BOUNDARY / / / / / / 1 / l I II j GWE=973.67 / /—� I!- I � �/llllll IIII III (1 I EXISTING BASIN I / ✓/ / \ — J �/ / / \ \ \ \ I 1\\1 \\ \\\ \ \ \r \ / l I 1 / n iw INJECTION WELLS ---///// �-— % I / / ���"'/�� I I v// / I� 1 IIII II I I 1 PIEZOMETER \ V M; MONITORING WELL - IN NETWORK j _ \ \ \ = / — _ \ / / / / / / / / / / / l l ( sw SURFACE WATER SAMPLING LOCATION i / \ / / / / / / / / \ \ \ l 1 \ \ \ \ \ _ _ \ \ \ \ \\ I I I \ \\\ \\ \ \ \\ _ // / / / _ \ � \ \ rl / / / / / / \ //\\--/ l l ll / / 1 \ \ \ \\1� I / \\ \\ \ / / / 71 I 1 I I I 1 \ °�Ol�l/IIII IIII I 1 \ \ ACTIVE LFG EXTRACTION WELL i \ \ \ \ l I l I / / / / / \\� J ! // III I ROADS III 1 \ \ <<�\--L TREE LINE -- / \\\\\ \\\ \ I\ II I II I IIIII IIIIII STREAM/CREEK EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (DECEMBER 26-28, 2018) GWE = 974.6 GROUNDWATER POTENTIOMETRIC ELEVATION \ I — : — — ' \ \ — — — — — — I I 1 1 \ \ \ \ \ \ \ \\ \ \ \\\\ \\ \ 1 1\\ \\\ NOTE: DEEP WELLS NOT USED FOR CONTOURS LFG PASSIVE VENTING SYSTEM PHYTOREMEDIATION AREA \\\ F,l III \ �s- \ GRAPHIC SCALE 100 0 50 100 200 I(c \ I I I III \ \ --- i n �� vv�10� \ \ \ \ / // / / IN FEET ) / // n SHEET 2 _ / ■ Q M M Z ■ � N t0 ILN W 0� mN t0 00 W ;a; N 00 Z Z0 2 -L. EL o co f11 a rn = a N 1�1 Z N Ln U U w 0 N U 0InW 00 2 Z N U ZI Z J �Zw w z m Q Lo m Q �13 Lid,z Z 0 w L1 a w U 't � Z � 2 m Q M X m W IL =° U) rn a ko z �= O� ANN —a J LL O J W I... 0 0 Z 08 Z zI°o O J V OC V u) 0 V Z = L uj O Z O z W J Z u� a uj � 0 W V � Q J V W ILL Q Q � o U OLu Lr- J 0 o a � � L O m Q C) U U Lij W L W � U) U C) m z o Lij a SCALE: AS SHOWN DATE: 0411512019 DRWN. BY: J. PFOHL CHKD. BY: S. GANDY PROJECT NUMBER G 18003.0 DRAWING NO. SHEET NO. SHEET 2 1 OF 1 Appendix A Laboratory Analysis Reports Chains of Custody lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 January 14, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Alexander LF-SWS Pace Project No.: 92412408 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on December 28, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, - �� Trey Carter trey. carter@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services r.Q _Kok Q REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF-SWS Pace Project No.: 92412408 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Alexander LF-SWS Pace Project No.: 92412408 Lab ID Sample ID Matrix Date Collected Date Received 92412408001 MW-11 Water 12/27/1817:40 12/28/1815:54 92412408002 MW-12 Water 12/28/1814:15 12/28/1815:54 92412408003 MW-12D Water 12/28/1814:00 12/28/1815:54 92412408004 MW-24 Water 12/28/1813:51 12/28/1815:54 92412408005 MW-26 Water 12/27/1817:15 12/28/1815:54 92412408006 MW-31 Water 12/27/1817:28 12/28/1815:54 92412408007 MW-5 Water 12/27/1816:30 12/28/1815:54 92412408008 MW-16 Water 12/27/1817:00 12/28/1815:54 92412408009 MW-25 Water 12/28/1811:17 12/28/1815:54 92412408010 MW-1 Water 12/27/1811:50 12/28/1815:54 92412408011 MW-1 B Water 12/27/18 11:49 12/28/18 15:54 92412408012 MW-6 Water 12/27/1810:30 12/28/1815:54 92412408013 MW-17 Water 12/27/1814:45 12/28/1815:54 92412408014 MW-2 Water 12/28/1813:25 12/28/1815:54 92412408015 MW-4R Water 12/28/1813:30 12/28/1815:54 92412408016 MW-9 Water 12/28/1813:45 12/28/1815:54 92412408017 MW-10 Water 12/28/1814:00 12/28/1815:54 92412408018 MW-13 Water 12/28/1810:35 12/28/1815:54 92412408019 MW-14 Water 12/28/1813:19 12/28/1815:54 92412408020 MW-15 Water 12/28/1814:28 12/28/1815:54 92412408021 MW-19 Water 12/28/1814:45 12/28/1815:54 92412408022 MW-21 Water 12/28/1814:51 12/28/1815:54 92412408023 MW-22 Water 12/28/1811:46 12/28/1815:54 92412408024 MW-23 Water 12/28/1811:45 12/28/1815:54 92412408025 MW-20 Water 12/28/1815:00 12/28/1815:54 92412408026 MW-27 Water 12/28/1814:05 12/28/1815:54 92412408027 MW-32 Water 12/28/1813:15 12/28/1815:54 92412408028 MW-33 Water 12/27/1815:30 12/28/1815:54 92412408029 MW-34 Water 12/27/1815:39 12/28/1815:54 92412408030 SW-3 Water 12/27/1813:17 12/28/1815:54 92412408031 SW-4R Water 12/27/1813:00 12/28/1815:54 92412408032 SW-5 Water 12/27/1815:30 12/28/1815:54 92412408033 SW-6 Water 12/27/1815:45 12/28/1815:54 92412408034 EB Water 12/28/1815:10 12/28/1815:54 92412408035 FB Water 12/28/1815:15 12/28/1815:54 92412408036 MW-3 Water 12/27/1817:33 12/28/1815:54 92412408037 MW-7 Water 12/28/1811:46 12/28/1815:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Alexander LF-SWS Pace Project No.: 92412408 Lab ID Sample ID Matrix Date Collected Date Received 92412408038 MW-18 Water 12/27/1811:40 12/28/1815:54 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF-SWS 92412408 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92412408001 MW-11 RSK 175 Modified LMB 1 PASI-C EPA 601 OD DS, SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C SM 2320B-2011 MDW 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92412408002 MW-12 RSK 175 Modified LMB 1 PASI-C EPA 601 OD SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92412408003 MW-12D RSK 175 Modified LMB 1 PASI-C EPA 601 OD SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92412408004 MW-24 RSK 175 Modified LMB 1 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF-SWS Pace Project No.: 92412408 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA 601 OD SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92412408005 MW-26 RSK 175 Modified LMB 1 PASI-C EPA 601 OD SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C EPA 180.1 Rev 2.0 1993 GC 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A 92412408006 MW-31 RSK 175 Modified LMB 1 PASI-C EPA 601 OD SER 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C EPA 180.1 Rev 2.0 1993 GC 1 PASI-A SM 2320B-2011 ECH 1 PASI-A SM 3500-Fe B-2011 MVC 1 PASI-A SM 4500-S2D-2011 GC 1 PASI-A EPA 300.0 Rev 2.1 1993 BRJ 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A SM 4500-CI-E-2011 NAL 1 PASI-A SM 5220D-2011 MVC 1 PASI-A SM 531OB-2011 ECH 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF-SWS 92412408 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92412408007 MW-5 RSK 175 Modified LMB 1 PASI-C EPA 6010D SER 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408008 MW-16 RSK 175 Modified LMB 1 PASI-C EPA 6010D SER 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408009 MW-25 RSK 175 Modified LMB 1 PASI-C EPA 6010D SER 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408010 MW-1 RSK 175 Modified LMB 1 PASI-C EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408011 MW-1B RSK 175 Modified LMB 1 PASI-C EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408012 MW-6 RSK 175 Modified LMB 1 PASI-C EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408013 MW-17 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408014 MW-2 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408015 MW-4R EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF-SWS Pace Project No.: 92412408 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260E CL 51 PASI-C 92412408016 MW-9 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408017 MW-10 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408018 MW-13 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408019 MW-14 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408020 MW-15 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408021 MW-19 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408022 MW-21 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408023 MW-22 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408024 MW-23 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408025 MW-20 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408026 MW-27 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Alexander LF-SWS 92412408 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92412408027 MW-32 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408028 MW-33 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408029 MW-34 EPA 6010D SH1 14 PASI-A EPA 6020E DS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408030 SW-3 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408031 SW-4R EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408032 SW-5 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408033 SW-6 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408034 EB EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C 92412408035 FB EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408036 MW-3 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408037 MW-7 EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A EPA 8260E CL 51 PASI-C 92412408038 MW-18 RSK 175 Modified LMB 1 PASI-C EPA 6010D SH1 14 PASI-A EPA 6020E IDS 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Alexander LF-SWS Pace Project No.: 92412408 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 7470A RDT 1 PASI-A EPA 8260E CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-11 Lab ID: 92412408001 Collected: 12/27/18 17:40 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 10900 ug/L 10.0 10.0 1 12/30/1810:35 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 01:47 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 01:47 7440-38-2 Barium 68.8 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 01:47 7440-41-7 Cadmium 3.8 ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 01:47 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-47-3 Cobalt 43.5 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-48-4 Copper 34.1 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-50-8 Lead 44.0 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7439-92-1 Nickel 6.0 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 01:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:47 7440-62-2 Zinc 12700 ug/L 100 50.0 10 12/29/18 05:00 12/31/18 12:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:23 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 18:01 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 18:01 107-13-1 Benzene 2.0 ug/L 1.0 0.25 1 01/02/19 18:01 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 18:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 18:01 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 18:01 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 18:01 74-83-9 2-Butanone (MEK) 1.6J ug/L 5.0 0.96 1 01/02/19 18:01 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 18:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 18:01 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 18:01 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 18:01 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 18:01 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 18:01 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 18:01 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 18:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 18:01 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 18:01 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 18:01 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 18:01 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 18:01 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 18:01 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 18:01 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 18:01 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-11 Lab ID: 92412408001 Collected: 12/27/18 17:40 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 10.7 ug/L 1.0 0.19 1 01/02/1918:01 156-59-2 ND ug/L 1.0 0.49 1 01/02/1918:01 156-60-5 ND ug/L 1.0 0.27 1 01/02/1918:01 78-87-5 ND ug/L 1.0 0.13 1 01/02/1918:01 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1918:01 10061-02-6 ND ug/L 150 78.4 1 01/02/1918:01 123-91-1 ND ug/L 1.0 0.30 1 01/02/1918:01 100-41-4 ND ug/L 5.0 0.46 1 01/02/1918:01 591-78-6 ND ug/L 5.0 0.32 1 01/02/1918:01 74-88-4 ND ug/L 1.0 0.97 1 01/02/1918:01 75-09-2 ND ug/L 5.0 0.33 1 01/02/1918:01 108-10-1 ND ug/L 1.0 0.26 1 01/02/1918:01 100-42-5 ND ug/L 1.0 0.33 1 01/02/1918:01 630-20-6 ND ug/L 1.0 0.40 1 01/02/1918:01 79-34-5 ND ug/L 1.0 0.46 1 01/02/1918:01 127-18-4 ND ug/L 1.0 0.26 1 01/02/1918:01 108-88-3 ND ug/L 1.0 0.48 1 01/02/1918:01 71-55-6 ND ug/L 1.0 0.29 1 01/02/1918:01 79-00-5 ND ug/L 1.0 0.47 1 01/02/1918:01 79-01-6 ND ug/L 1.0 0.20 1 01/02/1918:01 75-69-4 ND ug/L 1.0 0.41 1 01/02/1918:01 96-18-4 ND ug/L 2.0 0.35 1 01/02/1918:01 108-05-4 ND ug/L 1.0 0.62 1 01/02/1918:01 75-01-4 ND ug/L 1.0 0.66 1 01/02/1918:01 1330-20-7 97 % 70-130 1 01/02/1918:01 460-00-4 105 % 70-130 1 01/02/1918:01 17060-07-0 98 % 70-130 1 01/02/1918:01 2037-26-5 Analytical Method: SM 2320B-2011 261000 ug/L 5000 1000 1 12/29/18 01:33 Analytical Method: SM 3500-Fe B-2011 0.62 mg/L 0.50 0.50 1 01/13/1919:14 H3,N2 Analytical Method: SM 4500-S2D-2011 59.1J ug/L 100 50.0 1 12/31/1815:30 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 896J ug/L 1000 500 1 01/02/1910:02 14808-79-8 M1,R1 Analytical Method: EPA 353.2 Rev 2.0 1993 ND ug/L 20.0 10.0 1 12/28/18 23:34 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-11 Parameters Lab ID: 92412408001 Collected: Report Results Units Limit 12/27/18 17:40 MDL DF Received: 12/28/18 15:54 Matrix: Water Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 64600 ug/L 10000 5000 10 12/31/1817:54 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 90200 ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:55 M1 5310B TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 8620 ug/L 1000 500 1 01/02/19 17:26 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12 Lab ID: 92412408002 Collected: 12/28/18 14:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 7330 ug/L 10.0 10.0 1 12/30/1810:51 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 01:50 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 01:50 7440-38-2 Barium 104 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 01:50 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 01:50 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-47-3 Cobalt 48.9 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-48-4 Copper 3.2J ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7439-92-1 Nickel 7.7 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 01:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 01:50 7440-62-2 Zinc 140 ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 01:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.16 ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:37 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 02:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 02:35 107-13-1 Benzene 1.6 ug/L 1.0 0.25 1 01/03/19 02:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 02:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 02:35 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 02:35 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 02:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 02:35 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 02:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 02:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 02:35 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 02:35 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 02:35 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 02:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 02:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 02:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 02:35 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 02:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 02:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 02:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 02:35 110-57-6 1,1-Dichloroethane 0.67J ug/L 1.0 0.32 1 01/03/19 02:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 02:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 02:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12 Lab ID: 92412408002 Collected: 12/28/18 14:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 6.7 ug/L 1.0 0.19 1 01/03/19 02:35 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 02:35 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 02:35 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 02:35 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 02:35 10061-02-6 ND ug/L 150 78.4 1 01/03/19 02:35 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 02:35 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 02:35 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 02:35 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 02:35 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 02:35 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 02:35 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 02:35 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 02:35 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 02:35 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 02:35 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 02:35 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 02:35 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 02:35 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 02:35 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 02:35 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 02:35 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 02:35 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 02:35 1330-20-7 101 % 70-130 1 01/03/19 02:35 460-00-4 100 % 70-130 1 01/03/19 02:35 17060-07-0 98 % 70-130 1 01/03/19 02:35 2037-26-5 Analytical Method: SM 2320B-2011 130000 ug/L 5000 1000 1 12/31 /18 20:20 Analytical Method: SM 3500-Fe B-2011 ND mg/L 0.50 0.50 1 01/13/1919:16 H3,N2 Analytical Method: SM 4500-S2D-2011 ND ug/L 100 50.0 1 12/31/1815:31 18496-25-8 M1 Analytical Method: EPA 300.0 Rev 2.1 1993 7790 ug/L 1000 500 1 01/02/1911:00 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 63.5 ug/L 20.0 10.0 1 12/28/18 23:38 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12 Lab ID: 92412408002 Collected: 12/28/18 14:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 22400 ug/L 2000 1000 2 12/31/1817:55 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 26900 ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:56 5310B TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 3120 ug/L 1000 500 1 01/02/19 17:36 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12D Lab ID: 92412408003 Collected: 12/28/18 14:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 8140 ug/L 10.0 10.0 1 12/30/1811:06 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:05 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:05 7440-38-2 Barium 9.4 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:05 7440-41-7 Cadmium 0.87J ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:05 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-48-4 Copper 3.6J ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:05 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:05 7440-62-2 Zinc 11.2 ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:05 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:40 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 02:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 02:52 107-13-1 Benzene 0.42J ug/L 1.0 0.25 1 01/03/19 02:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 02:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 02:52 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 02:52 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 02:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 02:52 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 02:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 02:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 02:52 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 02:52 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 02:52 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 02:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 02:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 02:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 02:52 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 02:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 02:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 02:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 02:52 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 02:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 02:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 02:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12D Lab ID: 92412408003 Collected: 12/28/18 14:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 0.66J ug/L 1.0 0.19 1 01/03/19 02:52 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 02:52 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 02:52 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 02:52 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 02:52 10061-02-6 ND ug/L 150 78.4 1 01/03/19 02:52 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 02:52 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 02:52 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 02:52 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 02:52 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 02:52 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 02:52 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 02:52 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 02:52 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 02:52 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 02:52 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 02:52 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 02:52 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 02:52 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 02:52 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 02:52 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 02:52 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 02:52 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 02:52 1330-20-7 96 % 70-130 1 01/03/19 02:52 460-00-4 99 % 70-130 1 01/03/19 02:52 17060-07-0 100 % 70-130 1 01/03/19 02:52 2037-26-5 Analytical Method: SM 2320B-2011 422000 ug/L 5000 1000 1 01/02/1911:56 Analytical Method: SM 3500-Fe B-2011 ND mg/L 0.50 0.50 1 01/13/1919:16 Analytical Method: SM 4500-S2D-2011 ND ug/L 100 50.0 1 12/31/1815:32 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 ND ug/L 1000 500 1 01/02/1911:15 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 748 ug/L 20.0 10.0 1 12/28/18 23:37 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3,N2 Page 18 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-12D Lab ID: 92412408003 Collected: 12/28/18 14:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 63200 ug/L 10000 5000 10 12/31/1817:56 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 26900 ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:56 5310B TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 3680 ug/L 1000 500 1 01/02/19 17:49 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-24 Lab ID: 92412408004 Collected: 12/28/18 13:51 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane ND ug/L 10.0 10.0 1 12/30/1814:09 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:08 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:08 7440-38-2 Barium 38.8 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:08 7440-41-7 Cadmium 1.8 ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:08 7440-43-9 Chromium 3.1J ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-47-3 Cobalt 4.7J ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-48-4 Copper 2.9J ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:08 7440-62-2 Zinc 47.3 ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:43 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 03:09 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 03:09 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 03:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 03:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 03:09 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 03:09 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 03:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 03:09 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 03:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 03:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 03:09 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 03:09 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 03:09 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 03:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 03:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 03:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 03:09 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 03:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 03:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 03:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 03:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 03:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 03:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 03:09 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-24 Lab ID: 92412408004 Collected: 12/28/18 13:51 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Iron, Ferrous Iron, Ferrous 4500S2D Sulfide Water Sulfide 300.0 IC Anions 28 Days Sulfate 353.2 Nitrogen, NO2/NO3 unpres Nitrogen, Nitrate Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.19 1 01/03/19 03:09 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 03:09 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 03:09 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 03:09 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 03:09 10061-02-6 ND ug/L 150 78.4 1 01/03/19 03:09 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 03:09 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 03:09 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 03:09 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 03:09 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 03:09 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 03:09 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 03:09 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 03:09 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 03:09 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 03:09 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 03:09 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 03:09 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 03:09 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 03:09 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 03:09 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 03:09 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 03:09 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 03:09 1330-20-7 102 % 70-130 1 01/03/19 03:09 460-00-4 95 % 70-130 1 01/03/19 03:09 17060-07-0 99 % 70-130 1 01/03/19 03:09 2037-26-5 Analytical Method: SM 2320B-2011 29000 ug/L 5000 1000 1 12/31 /18 20:41 Analytical Method: SM 3500-Fe B-2011 ND mg/L 0.50 0.50 1 01/13/1919:14 Analytical Method: SM 4500-S2D-2011 59.7J ug/L 100 50.0 1 12/31 /18 15:32 18496-25-8 Analytical Method: EPA 300.0 Rev 2.1 1993 2430 ug/L 1000 500 1 01/02/1911:29 14808-79-8 Analytical Method: EPA 353.2 Rev 2.0 1993 ND ug/L 20.0 10.0 1 12/28/18 23:51 14797-55-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. H3,N2 Page 21 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-24 Lab ID: 92412408004 Collected: 12/28/18 13:51 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 14900 ug/L 1000 500 1 12/31/1817:42 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 68200 ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:56 5310B TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 4920 ug/L 1000 500 1 01/02/19 18:02 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-26 Lab ID: 92412408005 Collected: 12/27/18 17:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 1550 ug/L 10.0 10.0 1 12/30/1811:21 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:11 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:11 7440-38-2 Barium 13.8 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:11 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:11 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:11 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:52 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 18:18 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 18:18 107-13-1 Benzene 0.851 ug/L 1.0 0.25 1 01/02/19 18:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 18:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 18:18 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 18:18 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 18:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 18:18 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 18:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 18:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 18:18 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 18:18 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 18:18 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 18:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 18:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 18:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 18:18 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 18:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 18:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 18:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 18:18 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 18:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 18:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 18:18 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-26 Lab ID: 92412408005 Collected: 12/27/18 17:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,2-Dichloroethene 6.0 ug/L 1.0 0.19 1 01/02/19 18:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 18:18 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 18:18 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 18:18 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 18:18 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 18:18 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 18:18 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 18:18 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 18:18 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 18:18 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 18:18 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 18:18 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 18:18 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 18:18 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 18:18 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 18:18 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 18:18 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 18:18 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 18:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 18:18 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 18:18 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 18:18 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 18:18 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 18:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 01/02/19 18:18 460-00-4 1,2-Dichloroethane-d4 (S) 109 % 70-130 1 01/02/19 18:18 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 01/02/19 18:18 2037-26-5 180.1 Turbidity Analytical Method: EPA 180.1 Rev 2.0 1993 Turbidity 78.6 NTU 1.0 0.50 1 12/31/1819:48 H3 2320B Alkalinity Analytical Method: SM 2320B-2011 Alkalinity, Total as CaCO3 155000 ug/L 5000 1000 1 12/31/18 19:59 Iron, Ferrous Analytical Method: SM 3500-Fe B-2011 Iron, Ferrous 10.3 mg/L 2.5 2.5 5 01/13/19 20:08 D6,H3, N2 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Sulfide ND ug/L 100 50.0 1 12/31/1815:30 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 3260 ug/L 1000 500 1 12/30/18 01:45 14808-79-8 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-26 Lab ID: 92412408005 Collected: 12/27/18 17:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 304 ug/L 20.0 10.0 1 12/28/18 23:30 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 19800 ug/L 1000 500 1 12/31/1817:43 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 24200J ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:57 531013 TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 2900 ug/L 1000 500 1 01/02/19 18:13 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-31 Lab ID: 92412408006 Collected: 12/27/18 17:28 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 49.6 ug/L 10.0 10.0 1 12/31/18 09:23 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:14 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:14 7440-38-2 Barium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:14 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:14 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:14 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:55 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 18:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 18:35 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 18:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 18:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 18:35 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 18:35 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 18:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 18:35 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 18:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 18:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 18:35 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 18:35 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 18:35 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 18:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 18:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 18:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 18:35 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 18:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 18:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 18:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 18:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 18:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 18:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 18:35 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-31 Lab ID: 92412408006 Collected: 12/27/18 17:28 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,2-Dichloroethene 1.9 ug/L 1.0 0.19 1 01/02/19 18:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 18:35 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 18:35 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 18:35 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 18:35 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 18:35 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 18:35 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 18:35 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 18:35 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 18:35 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 18:35 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 18:35 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 18:35 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 18:35 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 18:35 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 18:35 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 18:35 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 18:35 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 18:35 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 18:35 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 18:35 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 18:35 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 18:35 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 18:35 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 95 % 70-130 1 01/02/19 18:35 460-00-4 1,2-Dichloroethane-d4 (S) 109 % 70-130 1 01/02/19 18:35 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 01/02/19 18:35 2037-26-5 180.1 Turbidity Analytical Method: EPA 180.1 Rev 2.0 1993 Turbidity 19.0 NTU 1.0 0.50 1 12/31/1819:49 H3 2320B Alkalinity Analytical Method: SM 2320B-2011 Alkalinity, Total as CaCO3 36600 ug/L 5000 1000 1 12/31/18 20:12 Iron, Ferrous Analytical Method: SM 3500-Fe B-2011 Iron, Ferrous ND mg/L 0.50 0.50 1 01/13/19 19:12 H3,N2 4500S2D Sulfide Water Analytical Method: SM 4500-S2D-2011 Sulfide ND ug/L 100 50.0 1 12/31/1815:31 18496-25-8 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 743J ug/L 1000 500 1 12/30/18 01:59 14808-79-8 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-31 Lab ID: 92412408006 Collected: 12/27/18 17:28 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate 1260 ug/L 20.0 10.0 1 12/28/18 23:33 14797-55-8 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Chloride 16700 ug/L 1000 500 1 12/31/1817:44 16887-00-6 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand ND ug/L 25000 12500 1 01/04/19 20:12 01/08/19 00:57 531013 TOC Analytical Method: SM 531 OB-2011 Total Organic Carbon 1510 ug/L 1000 500 1 01/02/19 18:25 7440-44-0 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-5 Lab ID: 92412408007 Collected: 12/27/18 16:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 8460 ug/L 10.0 10.0 1 12/30/1811:52 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:17 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:17 7440-38-2 Barium 14.9 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:17 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:17 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:17 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:17 7440-62-2 Zinc 12.9 ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:17 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 16:58 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone 21.3J ug/L 25.0 10.0 1 01/02/19 18:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 18:52 107-13-1 Benzene 2.9 ug/L 1.0 0.25 1 01/02/19 18:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 18:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 18:52 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 18:52 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 18:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 18:52 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 18:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 18:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 18:52 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 18:52 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 18:52 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 18:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 18:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 18:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 18:52 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 18:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 18:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 18:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 18:52 110-57-6 1,1-Dichloroethane 2.1 ug/L 1.0 0.32 1 01/02/19 18:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 18:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 18:52 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-5 Lab ID: 92412408007 Collected: 12/27/18 16:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 12.3 ug/L 1.0 0.19 1 01/02/1918:52 156-59-2 ND ug/L 1.0 0.49 1 01/02/1918:52 156-60-5 ND ug/L 1.0 0.27 1 01/02/1918:52 78-87-5 ND ug/L 1.0 0.13 1 01 /02/19 18:52 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1918:52 10061-02-6 ND ug/L 150 78.4 1 01/02/1918:52 123-91-1 ND ug/L 1.0 0.30 1 01/02/1918:52 100-41-4 ND ug/L 5.0 0.46 1 01/02/1918:52 591-78-6 ND ug/L 5.0 0.32 1 01/02/1918:52 74-88-4 ND ug/L 1.0 0.97 1 01/02/1918:52 75-09-2 ND ug/L 5.0 0.33 1 01/02/1918:52 108-10-1 ND ug/L 1.0 0.26 1 01/02/1918:52 100-42-5 ND ug/L 1.0 0.33 1 01/02/1918:52 630-20-6 ND ug/L 1.0 0.40 1 01/02/1918:52 79-34-5 ND ug/L 1.0 0.46 1 01/02/1918:52 127-18-4 ND ug/L 1.0 0.26 1 01/02/1918:52 108-88-3 ND ug/L 1.0 0.48 1 01/02/1918:52 71-55-6 ND ug/L 1.0 0.29 1 01/02/1918:52 79-00-5 ND ug/L 1.0 0.47 1 01/02/1918:52 79-01-6 ND ug/L 1.0 0.20 1 01/02/1918:52 75-69-4 ND ug/L 1.0 0.41 1 01/02/1918:52 96-18-4 ND ug/L 2.0 0.35 1 01/02/1918:52 108-05-4 ND ug/L 1.0 0.62 1 01/02/1918:52 75-01-4 ND ug/L 1.0 0.66 1 01/02/1918:52 1330-20-7 100 % 70-130 1 01/02/1918:52 460-00-4 109 % 70-130 1 01/02/1918:52 17060-07-0 99 % 70-130 1 01/02/1918:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-16 Lab ID: 92412408008 Collected: 12/27/18 17:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 1970 ug/L 10.0 10.0 1 12/30/1812:07 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:21 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:21 7440-38-2 Barium 20.4 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:21 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:21 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-47-3 Cobalt 72.6 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7439-92-1 Nickel 3.OJ ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:21 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:01 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 19:10 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 19:10 107-13-1 Benzene 0.84J ug/L 1.0 0.25 1 01/02/19 19:10 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 19:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 19:10 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 19:10 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 19:10 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 19:10 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 19:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 19:10 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 19:10 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 19:10 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 19:10 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 19:10 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 19:10 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 19:10 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 19:10 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 19:10 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 19:10 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 19:10 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 19:10 110-57-6 1,1-Dichloroethane 1.1 ug/L 1.0 0.32 1 01/02/19 19:10 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 19:10 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 19:10 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-16 Lab ID: 92412408008 Collected: 12/27/18 17:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 5.0 ug/L 1.0 0.19 1 01/02/1919:10 156-59-2 ND ug/L 1.0 0.49 1 01/02/1919:10 156-60-5 ND ug/L 1.0 0.27 1 01/02/1919:10 78-87-5 ND ug/L 1.0 0.13 1 01/02/1919:10 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1919:10 10061-02-6 ND ug/L 150 78.4 1 01/02/1919:10 123-91-1 ND ug/L 1.0 0.30 1 01/02/1919:10 100-41-4 ND ug/L 5.0 0.46 1 01/02/1919:10 591-78-6 ND ug/L 5.0 0.32 1 01/02/1919:10 74-88-4 ND ug/L 1.0 0.97 1 01/02/1919:10 75-09-2 ND ug/L 5.0 0.33 1 01/02/1919:10 108-10-1 ND ug/L 1.0 0.26 1 01/02/1919:10 100-42-5 ND ug/L 1.0 0.33 1 01/02/1919:10 630-20-6 ND ug/L 1.0 0.40 1 01/02/1919:10 79-34-5 ND ug/L 1.0 0.46 1 01/02/1919:10 127-18-4 ND ug/L 1.0 0.26 1 01/02/1919:10 108-88-3 ND ug/L 1.0 0.48 1 01/02/1919:10 71-55-6 ND ug/L 1.0 0.29 1 01/02/1919:10 79-00-5 ND ug/L 1.0 0.47 1 01/02/1919:10 79-01-6 ND ug/L 1.0 0.20 1 01/02/1919:10 75-69-4 ND ug/L 1.0 0.41 1 01/02/1919:10 96-18-4 ND ug/L 2.0 0.35 1 01/02/1919:10 108-05-4 ND ug/L 1.0 0.62 1 01/02/1919:10 75-01-4 ND ug/L 1.0 0.66 1 01/02/1919:10 1330-20-7 99 % 70-130 1 01/02/1919:10 460-00-4 106 % 70-130 1 01/02/1919:10 17060-07-0 98 % 70-130 1 01/02/1919:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-25 Lab ID: 92412408009 Collected: 12/28/18 11:17 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane ND ug/L 10.0 10.0 1 12/31/18 09:38 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:00 12/31/18 02:24 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:24 7440-38-2 Barium 60.7 ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:24 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:00 12/31/18 02:24 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:24 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:00 12/31/18 02:24 7440-62-2 Zinc 6.2J ug/L 10.0 5.0 1 12/29/18 05:00 12/31/18 02:24 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.071J ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:04 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 03:26 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 03:26 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 03:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 03:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 03:26 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 03:26 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 03:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 03:26 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 03:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 03:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 03:26 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 03:26 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 03:26 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 03:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 03:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 03:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 03:26 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 03:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 03:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 03:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 03:26 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 03:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 03:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 03:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-25 Lab ID: 92412408009 Collected: 12/28/18 11:17 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.19 1 01/03/19 03:26 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 03:26 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 03:26 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 03:26 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 03:26 10061-02-6 ND ug/L 150 78.4 1 01/03/19 03:26 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 03:26 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 03:26 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 03:26 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 03:26 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 03:26 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 03:26 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 03:26 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 03:26 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 03:26 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 03:26 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 03:26 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 03:26 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 03:26 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 03:26 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 03:26 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 03:26 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 03:26 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 03:26 1330-20-7 100 % 70-130 1 01/03/19 03:26 460-00-4 97 % 70-130 1 01/03/19 03:26 17060-07-0 99 % 70-130 1 01/03/19 03:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-1 Lab ID: 92412408010 Collected: 12/27/18 11:50 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 76.6 ug/L 10.0 10.0 1 12/30/1812:38 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:28 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:28 7440-38-2 Barium 25.8 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:28 7440-41-7 Cadmium 0.82J ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:28 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-47-3 Cobalt 5.2 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7439-92-1 Nickel 3.1J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:28 7440-62-2 Zinc 30.8 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:07 7440-28-0 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/14/2019 01:24 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:07 7439-97-6 M1 Analytical Method: EPA 8260E ND ug/L 25.0 ND ug/L 10.0 0.81J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 10.0 1 01/02/1919:27 67-64-1 1.9 1 01 /02/19 19:27 107-13-1 0.25 1 01 /02/19 19:27 71-43-2 0.17 1 01/02/1919:27 74-97-5 0.18 1 01/02/1919:27 75-27-4 0.26 1 01/02/1919:27 75-25-2 0.29 1 01/02/1919:27 74-83-9 0.96 1 01/02/1919:27 78-93-3 1.2 1 01/02/1919:27 75-15-0 0.25 1 01/02/1919:27 56-23-5 0.23 1 01 /02/19 19:27 108-90-7 0.54 1 01/02/1919:27 75-00-3 0.14 1 01/02/1919:27 67-66-3 0.11 1 01/02/1919:27 74-87-3 2.0 1 01/02/1919:27 96-12-8 0.21 1 01 /02/19 19:27 124-48-1 0.27 1 01 /02/19 19:27 106-93-4 0.21 1 01/02/1919:27 74-95-3 0.30 1 01/02/1919:27 95-50-1 0.33 1 01 /02/19 19:27 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-1 Lab ID: 92412408010 Collected: 12/27/18 11:50 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 1.0 1 01/02/1919:27 110-57-6 ND ug/L 1.0 0.32 1 01/02/1919:27 75-34-3 ND ug/L 1.0 0.24 1 01/02/1919:27 107-06-2 ND ug/L 1.0 0.56 1 01/02/1919:27 75-35-4 0.84J ug/L 1.0 0.19 1 01/02/1919:27 156-59-2 ND ug/L 1.0 0.49 1 01/02/1919:27 156-60-5 ND ug/L 1.0 0.27 1 01/02/1919:27 78-87-5 ND ug/L 1.0 0.13 1 01 /02/19 19:27 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1919:27 10061-02-6 ND ug/L 150 78.4 1 01/02/1919:27 123-91-1 ND ug/L 1.0 0.30 1 01/02/1919:27 100-41-4 ND ug/L 5.0 0.46 1 01/02/1919:27 591-78-6 ND ug/L 5.0 0.32 1 01/02/1919:27 74-88-4 ND ug/L 1.0 0.97 1 01/02/1919:27 75-09-2 ND ug/L 5.0 0.33 1 01/02/1919:27 108-10-1 ND ug/L 1.0 0.26 1 01/02/1919:27 100-42-5 ND ug/L 1.0 0.33 1 01/02/1919:27 630-20-6 ND ug/L 1.0 0.40 1 01/02/1919:27 79-34-5 ND ug/L 1.0 0.46 1 01/02/1919:27 127-18-4 ND ug/L 1.0 0.26 1 01/02/1919:27 108-88-3 ND ug/L 1.0 0.48 1 01/02/1919:27 71-55-6 ND ug/L 1.0 0.29 1 01/02/1919:27 79-00-5 ND ug/L 1.0 0.47 1 01/02/1919:27 79-01-6 ND ug/L 1.0 0.20 1 01/02/1919:27 75-69-4 ND ug/L 1.0 0.41 1 01/02/1919:27 96-18-4 ND ug/L 2.0 0.35 1 01/02/1919:27 108-05-4 ND ug/L 1.0 0.62 1 01/02/1919:27 75-01-4 ND ug/L 1.0 0.66 1 01/02/1919:27 1330-20-7 97 % 70-130 1 01/02/1919:27 460-00-4 105 % 70-130 1 01/02/1919:27 17060-07-0 101 % 70-130 1 01/02/1919:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MWAB Lab ID: 92412408011 Collected: 12/27/18 11:49 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 29.6 ug/L 10.0 10.0 1 12/30/1812:53 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:40 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:40 7440-38-2 Barium 54.8 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:40 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:40 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-47-3 Cobalt 64.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7439-92-1 Nickel 5.5 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:40 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:40 7440-62-2 Zinc 11.5 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:40 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.081J ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:10 7440-28-0 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/14/2019 01:24 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A 1.1 ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:14 7439-97-6 Analytical Method: EPA 8260E ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 10.0 1 01/02/1919:44 67-64-1 1.9 1 01 /02/19 19:44 107-13-1 0.25 1 01 /02/19 19:44 71-43-2 0.17 1 01/02/1919:44 74-97-5 0.18 1 01/02/1919:44 75-27-4 0.26 1 01/02/1919:44 75-25-2 0.29 1 01/02/1919:44 74-83-9 0.96 1 01/02/1919:44 78-93-3 1.2 1 01/02/1919:44 75-15-0 0.25 1 01/02/1919:44 56-23-5 0.23 1 01 /02/19 19:44 108-90-7 0.54 1 01/02/1919:44 75-00-3 0.14 1 01/02/1919:44 67-66-3 0.11 1 01/02/1919:44 74-87-3 2.0 1 01/02/1919:44 96-12-8 0.21 1 01 /02/19 19:44 124-48-1 0.27 1 01 /02/19 19:44 106-93-4 0.21 1 01/02/1919:44 74-95-3 0.30 1 01/02/1919:44 95-50-1 0.33 1 01 /02/19 19:44 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-1B Lab ID: 92412408011 Collected: 12/27/18 11:49 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 1.0 1 01/02/1919:44 110-57-6 ND ug/L 1.0 0.32 1 01/02/1919:44 75-34-3 ND ug/L 1.0 0.24 1 01/02/1919:44 107-06-2 ND ug/L 1.0 0.56 1 01/02/1919:44 75-35-4 0.66J ug/L 1.0 0.19 1 01/02/1919:44 156-59-2 ND ug/L 1.0 0.49 1 01/02/1919:44 156-60-5 ND ug/L 1.0 0.27 1 01/02/1919:44 78-87-5 ND ug/L 1.0 0.13 1 01 /02/19 19:44 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1919:44 10061-02-6 ND ug/L 150 78.4 1 01/02/1919:44 123-91-1 ND ug/L 1.0 0.30 1 01/02/1919:44 100-41-4 ND ug/L 5.0 0.46 1 01/02/1919:44 591-78-6 ND ug/L 5.0 0.32 1 01/02/1919:44 74-88-4 ND ug/L 1.0 0.97 1 01/02/1919:44 75-09-2 ND ug/L 5.0 0.33 1 01/02/1919:44 108-10-1 ND ug/L 1.0 0.26 1 01/02/1919:44 100-42-5 ND ug/L 1.0 0.33 1 01/02/1919:44 630-20-6 ND ug/L 1.0 0.40 1 01/02/1919:44 79-34-5 ND ug/L 1.0 0.46 1 01/02/1919:44 127-18-4 ND ug/L 1.0 0.26 1 01/02/1919:44 108-88-3 ND ug/L 1.0 0.48 1 01/02/1919:44 71-55-6 ND ug/L 1.0 0.29 1 01/02/1919:44 79-00-5 ND ug/L 1.0 0.47 1 01/02/1919:44 79-01-6 ND ug/L 1.0 0.20 1 01/02/1919:44 75-69-4 ND ug/L 1.0 0.41 1 01/02/1919:44 96-18-4 ND ug/L 2.0 0.35 1 01/02/1919:44 108-05-4 ND ug/L 1.0 0.62 1 01/02/1919:44 75-01-4 ND ug/L 1.0 0.66 1 01/02/1919:44 1330-20-7 98 % 70-130 1 01/02/1919:44 460-00-4 105 % 70-130 1 01/02/1919:44 17060-07-0 100 % 70-130 1 01/02/1919:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-6 Lab ID: 92412408012 Collected: 12/27/18 10:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane 29.3 ug/L 10.0 10.0 1 12/30/1813:39 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:43 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:43 7440-38-2 Barium 38.6 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:43 7440-41-7 Cadmium 1.1 ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:43 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-47-3 Cobalt 12.9 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7439-92-1 Nickel 3.8J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:43 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:43 7440-62-2 Zinc 18.2 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:43 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:12 7440-28-0 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/14/2019 01:24 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.39 ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:16 7439-97-6 Analytical Method: EPA 8260E ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 10.0 1 01/02/19 20:01 67-64-1 1.9 1 01/02/19 20:01 107-13-1 0.25 1 01/02/19 20:01 71-43-2 0.17 1 01/02/19 20:01 74-97-5 0.18 1 01/02/19 20:01 75-27-4 0.26 1 01/02/19 20:01 75-25-2 0.29 1 01/02/19 20:01 74-83-9 0.96 1 01/02/19 20:01 78-93-3 1.2 1 01/02/19 20:01 75-15-0 0.25 1 01/02/19 20:01 56-23-5 0.23 1 01/02/19 20:01 108-90-7 0.54 1 01/02/19 20:01 75-00-3 0.14 1 01/02/19 20:01 67-66-3 0.11 1 01/02/19 20:01 74-87-3 2.0 1 01/02/19 20:01 96-12-8 0.21 1 01/02/19 20:01 124-48-1 0.27 1 01/02/19 20:01 106-93-4 0.21 1 01/02/19 20:01 74-95-3 0.30 1 01/02/19 20:01 95-50-1 0.33 1 01/02/19 20:01 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-6 Lab ID: 92412408012 Collected: 12/27/18 10:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 1.0 1 01/02/19 20:01 110-57-6 ND ug/L 1.0 0.32 1 01/02/19 20:01 75-34-3 ND ug/L 1.0 0.24 1 01/02/19 20:01 107-06-2 ND ug/L 1.0 0.56 1 01/02/19 20:01 75-35-4 ND ug/L 1.0 0.19 1 01/02/19 20:01 156-59-2 ND ug/L 1.0 0.49 1 01/02/19 20:01 156-60-5 ND ug/L 1.0 0.27 1 01/02/19 20:01 78-87-5 ND ug/L 1.0 0.13 1 01/02/19 20:01 10061-01-5 ND ug/L 1.0 0.26 1 01/02/19 20:01 10061-02-6 ND ug/L 150 78.4 1 01/02/19 20:01 123-91-1 ND ug/L 1.0 0.30 1 01/02/19 20:01 100-41-4 ND ug/L 5.0 0.46 1 01/02/19 20:01 591-78-6 ND ug/L 5.0 0.32 1 01/02/19 20:01 74-88-4 ND ug/L 1.0 0.97 1 01/02/19 20:01 75-09-2 ND ug/L 5.0 0.33 1 01/02/19 20:01 108-10-1 ND ug/L 1.0 0.26 1 01/02/19 20:01 100-42-5 ND ug/L 1.0 0.33 1 01/02/19 20:01 630-20-6 ND ug/L 1.0 0.40 1 01/02/19 20:01 79-34-5 ND ug/L 1.0 0.46 1 01/02/19 20:01 127-18-4 ND ug/L 1.0 0.26 1 01/02/19 20:01 108-88-3 ND ug/L 1.0 0.48 1 01/02/19 20:01 71-55-6 ND ug/L 1.0 0.29 1 01/02/19 20:01 79-00-5 ND ug/L 1.0 0.47 1 01/02/19 20:01 79-01-6 ND ug/L 1.0 0.20 1 01/02/19 20:01 75-69-4 ND ug/L 1.0 0.41 1 01/02/19 20:01 96-18-4 ND ug/L 2.0 0.35 1 01/02/19 20:01 108-05-4 ND ug/L 1.0 0.62 1 01/02/19 20:01 75-01-4 ND ug/L 1.0 0.66 1 01/02/19 20:01 1330-20-7 96 % 70-130 1 01/02/19 20:01 460-00-4 105 % 70-130 1 01/02/19 20:01 17060-07-0 98 % 70-130 1 01/02/19 20:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-17 Lab ID: 92412408013 Collected: 12/27/18 14:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:46 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:46 7440-38-2 Barium 26.3 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:46 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:46 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-47-3 Cobalt 6.0 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:46 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:46 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:46 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:15 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury 0.12J ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:19 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 20:18 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 20:18 107-13-1 Benzene 0.39J ug/L 1.0 0.25 1 01/02/19 20:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 20:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 20:18 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 20:18 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 20:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 20:18 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 20:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 20:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 20:18 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 20:18 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 20:18 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 20:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 20:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 20:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 20:18 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 20:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 20:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 20:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 20:18 110-57-6 1,1-Dichloroethane 0.40J ug/L 1.0 0.32 1 01/02/19 20:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 20:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 20:18 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-17 Lab ID: 92412408013 Collected: 12/27/18 14:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 1.5 ug/L 1.0 0.19 1 01/02/19 20:18 156-59-2 ND ug/L 1.0 0.49 1 01/02/19 20:18 156-60-5 ND ug/L 1.0 0.27 1 01/02/19 20:18 78-87-5 ND ug/L 1.0 0.13 1 01/02/19 20:18 10061-01-5 ND ug/L 1.0 0.26 1 01/02/19 20:18 10061-02-6 ND ug/L 150 78.4 1 01/02/19 20:18 123-91-1 ND ug/L 1.0 0.30 1 01/02/19 20:18 100-41-4 ND ug/L 5.0 0.46 1 01/02/19 20:18 591-78-6 ND ug/L 5.0 0.32 1 01/02/19 20:18 74-88-4 ND ug/L 1.0 0.97 1 01/02/19 20:18 75-09-2 ND ug/L 5.0 0.33 1 01/02/19 20:18 108-10-1 ND ug/L 1.0 0.26 1 01/02/19 20:18 100-42-5 ND ug/L 1.0 0.33 1 01/02/19 20:18 630-20-6 ND ug/L 1.0 0.40 1 01/02/19 20:18 79-34-5 ND ug/L 1.0 0.46 1 01/02/19 20:18 127-18-4 ND ug/L 1.0 0.26 1 01/02/19 20:18 108-88-3 ND ug/L 1.0 0.48 1 01/02/19 20:18 71-55-6 ND ug/L 1.0 0.29 1 01/02/19 20:18 79-00-5 ND ug/L 1.0 0.47 1 01/02/19 20:18 79-01-6 ND ug/L 1.0 0.20 1 01/02/19 20:18 75-69-4 ND ug/L 1.0 0.41 1 01/02/19 20:18 96-18-4 ND ug/L 2.0 0.35 1 01/02/19 20:18 108-05-4 ND ug/L 1.0 0.62 1 01/02/19 20:18 75-01-4 ND ug/L 1.0 0.66 1 01/02/19 20:18 1330-20-7 100 % 70-130 1 01/02/19 20:18 460-00-4 103 % 70-130 1 01/02/19 20:18 17060-07-0 100 % 70-130 1 01/02/19 20:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-2 Lab ID: 92412408014 Collected: 12/28/18 13:25 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:50 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:50 7440-38-2 Barium 28.3 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:50 7440-41-7 Cadmium 1.1 ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:50 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-47-3 Cobalt 303 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7439-92-1 Nickel 6.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:50 7440-62-2 Zinc 13.5 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.18 ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:18 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury 0.17J ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:21 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 03:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 03:43 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 03:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 03:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 03:43 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 03:43 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 03:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 03:43 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 03:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 03:43 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 03:43 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 03:43 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 03:43 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 03:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 03:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 03:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 03:43 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 03:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 03:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 03:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 03:43 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 03:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 03:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 03:43 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-2 Lab ID: 92412408014 Collected: 12/28/18 13:25 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 0.24J ug/L 1.0 0.19 1 01/03/19 03:43 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 03:43 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 03:43 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 03:43 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 03:43 10061-02-6 ND ug/L 150 78.4 1 01/03/19 03:43 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 03:43 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 03:43 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 03:43 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 03:43 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 03:43 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 03:43 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 03:43 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 03:43 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 03:43 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 03:43 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 03:43 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 03:43 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 03:43 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 03:43 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 03:43 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 03:43 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 03:43 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 03:43 1330-20-7 103 % 70-130 1 01/03/19 03:43 460-00-4 103 % 70-130 1 01/03/19 03:43 17060-07-0 99 % 70-130 1 01/03/19 03:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-4R Lab ID: 92412408015 Collected: 12/28/18 13:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 15:59 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:59 7440-38-2 Barium 124 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:59 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 15:59 7440-43-9 Chromium 2.9J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-47-3 Cobalt 101 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-50-8 Lead 3.OJ ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7439-92-1 Nickel 6.4 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:59 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 15:59 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 15:59 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:27 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 04:00 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 04:00 107-13-1 Benzene 1.2 ug/L 1.0 0.25 1 01/03/19 04:00 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 04:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 04:00 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 04:00 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 04:00 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 04:00 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 04:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 04:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 04:00 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 04:00 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 04:00 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 04:00 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 04:00 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 04:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 04:00 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 04:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 04:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 04:00 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 04:00 110-57-6 1,1-Dichloroethane 1.0 ug/L 1.0 0.32 1 01/03/19 04:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 04:00 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 04:00 75-35-4 cis-1,2-Dichloroethene 8.7 ug/L 1.0 0.19 1 01/03/19 04:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 04:00 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 04:00 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-4R Lab ID: 92412408015 Collected: 12/28/18 13:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 04:00 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 04:00 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 04:00 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 04:00 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 04:00 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 04:00 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 04:00 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 04:00 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 04:00 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 04:00 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 04:00 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 04:00 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 04:00 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 04:00 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 04:00 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 04:00 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 04:00 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 04:00 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 04:00 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 04:00 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 04:00 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/03/19 04:00 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 01/03/19 04:00 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 01/03/19 04:00 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-9 Lab ID: 92412408016 Collected: 12/28/18 13:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:02 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:02 7440-38-2 Barium 220 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:02 7440-41-7 Cadmium 1.2 ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:02 7440-43-9 Chromium 4.5J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-47-3 Cobalt 329 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7439-92-1 Nickel 49.4 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:02 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:02 7440-62-2 Zinc 20.8 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:02 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.23 ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:30 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 04:17 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 04:17 107-13-1 Benzene 1.5 ug/L 1.0 0.25 1 01/03/19 04:17 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 04:17 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 04:17 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 04:17 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 04:17 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 04:17 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 04:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 04:17 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 04:17 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 04:17 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 04:17 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 04:17 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 04:17 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 04:17 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 04:17 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 04:17 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 04:17 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 04:17 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 04:17 110-57-6 1,1-Dichloroethane 0.55J ug/L 1.0 0.32 1 01/03/19 04:17 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 04:17 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 04:17 75-35-4 cis-1,2-Dichloroethene 14.5 ug/L 1.0 0.19 1 01/03/19 04:17 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 04:17 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 04:17 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-9 Lab ID: 92412408016 Collected: 12/28/18 13:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 04:17 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 04:17 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 04:17 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 04:17 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 04:17 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 04:17 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 04:17 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 04:17 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 04:17 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 04:17 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 04:17 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 04:17 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 04:17 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 04:17 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 04:17 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 04:17 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 04:17 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 04:17 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 04:17 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 04:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 04:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 01/03/19 04:17 460-00-4 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 01/03/19 04:17 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 01/03/19 04:17 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-10 Lab ID: 92412408017 Collected: 12/28/18 14:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:06 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:06 7440-38-2 Barium 12.4 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:06 7440-41-7 Cadmium 0.53J ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:06 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7439-92-1 Nickel 5.1 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:06 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:06 7440-62-2 Zinc 8.2J ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:33 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 04:34 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 04:34 107-13-1 Benzene 0.84J ug/L 1.0 0.25 1 01/03/19 04:34 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 04:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 04:34 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 04:34 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 04:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 04:34 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 04:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 04:34 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 04:34 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 04:34 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 04:34 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 04:34 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 04:34 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 04:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 04:34 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 04:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 04:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 04:34 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 04:34 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 04:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 04:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 04:34 75-35-4 cis-1,2-Dichloroethene 2.3 ug/L 1.0 0.19 1 01/03/19 04:34 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 04:34 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 04:34 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-10 Lab ID: 92412408017 Collected: 12/28/18 14:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 04:34 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 04:34 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 04:34 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 04:34 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 04:34 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 04:34 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 04:34 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 04:34 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 04:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 04:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 04:34 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 04:34 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 04:34 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 04:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 04:34 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 04:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 04:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 04:34 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 04:34 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 04:34 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 04:34 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 01/03/19 04:34 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 01/03/19 04:34 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 01/03/19 04:34 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 50 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-13 Lab ID: 92412408018 Collected: 12/28/18 10:35 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:09 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:09 7440-38-2 Barium 13.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:09 7440-41-7 Cadmium 0.52J ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:09 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-48-4 Copper 4.2J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7439-92-1 Nickel 5.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:09 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:09 7440-62-2 Zinc 6.8J ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:36 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 04:51 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 04:51 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 04:51 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 04:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 04:51 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 04:51 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 04:51 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 04:51 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 04:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 04:51 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 04:51 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 04:51 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 04:51 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 04:51 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 04:51 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 04:51 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 04:51 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 04:51 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 04:51 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 04:51 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 04:51 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 04:51 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 04:51 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 04:51 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/03/19 04:51 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 04:51 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 04:51 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-13 Lab ID: 92412408018 Collected: 12/28/18 10:35 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 04:51 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 04:51 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 04:51 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 04:51 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 04:51 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 04:51 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 04:51 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 04:51 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 04:51 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 04:51 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 04:51 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 04:51 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 04:51 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 04:51 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 04:51 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 04:51 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 04:51 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 04:51 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 04:51 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 04:51 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 04:51 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 01/03/19 04:51 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 01/03/19 04:51 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 01/03/19 04:51 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-14 Lab ID: 92412408019 Collected: 12/28/18 13:19 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:12 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:12 7440-38-2 Barium 30.9 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:12 7440-41-7 Cadmium 1.8 ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:12 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-47-3 Cobalt 6.9 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7439-92-1 Nickel 2.6J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:12 7440-62-2 Zinc 8.1J ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:39 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 05:09 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 05:09 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 05:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 05:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 05:09 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 05:09 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 05:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 05:09 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 05:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 05:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 05:09 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 05:09 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 05:09 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 05:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 05:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 05:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 05:09 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 05:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 05:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 05:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 05:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 05:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 05:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 05:09 75-35-4 cis-1,2-Dichloroethene 0.69J ug/L 1.0 0.19 1 01/03/19 05:09 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 05:09 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 05:09 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-14 Lab ID: 92412408019 Collected: 12/28/18 13:19 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 05:09 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 05:09 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 05:09 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 05:09 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 05:09 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 05:09 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 05:09 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 05:09 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 05:09 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 05:09 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 05:09 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 05:09 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 05:09 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 05:09 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 05:09 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 05:09 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 05:09 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 05:09 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 05:09 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 05:09 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 05:09 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 93 % 70-130 1 01/03/19 05:09 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 01/03/19 05:09 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 01/03/19 05:09 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-15 Lab ID: 92412408020 Collected: 12/28/18 14:28 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:15 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:15 7440-38-2 Barium 81.5 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:15 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:15 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-47-3 Cobalt 85.3 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7439-92-1 Nickel 4.2J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:15 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:15 7440-62-2 Zinc 13.4 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.064J ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 17:42 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury 5.8 ug/L 0.40 0.20 2 12/31/1817:42 01/02/1912:42 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone 50.2 ug/L 25.0 10.0 1 01/03/19 05:26 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 05:26 107-13-1 Benzene 2.0 ug/L 1.0 0.25 1 01/03/19 05:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 05:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 05:26 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 05:26 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 05:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 05:26 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 05:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 05:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 05:26 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 05:26 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 05:26 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 05:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 05:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 05:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 05:26 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 05:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 05:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 05:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 05:26 110-57-6 1,1-Dichloroethane 1.0 ug/L 1.0 0.32 1 01/03/19 05:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 05:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 05:26 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-15 Lab ID: 92412408020 Collected: 12/28/18 14:28 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E 4.6 ug/L 1.0 0.19 1 01/03/19 05:26 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 05:26 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 05:26 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 05:26 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 05:26 10061-02-6 ND ug/L 150 78.4 1 01/03/19 05:26 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 05:26 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 05:26 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 05:26 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 05:26 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 05:26 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 05:26 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 05:26 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 05:26 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 05:26 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 05:26 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 05:26 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 05:26 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 05:26 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 05:26 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 05:26 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 05:26 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 05:26 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 05:26 1330-20-7 98 % 70-130 1 01/03/19 05:26 460-00-4 101 % 70-130 1 01/03/19 05:26 17060-07-0 98 % 70-130 1 01/03/19 05:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-19 Lab ID: 92412408021 Collected: 12/28/18 14:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:18 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:18 7440-38-2 Barium 5.8 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:18 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:18 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:18 7440-62-2 Zinc 5.5J ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:22 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:43 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 05:43 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 05:43 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 05:43 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 05:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 05:43 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 05:43 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 05:43 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 05:43 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 05:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 05:43 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 05:43 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 05:43 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 05:43 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 05:43 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 05:43 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 05:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 05:43 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 05:43 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 05:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 05:43 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 05:43 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 05:43 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 05:43 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 05:43 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-19 Lab ID: 92412408021 Collected: 12/28/18 14:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.19 1 01/03/19 05:43 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 05:43 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 05:43 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 05:43 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 05:43 10061-02-6 ND ug/L 150 78.4 1 01/03/19 05:43 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 05:43 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 05:43 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 05:43 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 05:43 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 05:43 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 05:43 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 05:43 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 05:43 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 05:43 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 05:43 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 05:43 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 05:43 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 05:43 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 05:43 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 05:43 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 05:43 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 05:43 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 05:43 1330-20-7 97 % 70-130 1 01/03/19 05:43 460-00-4 99 % 70-130 1 01/03/19 05:43 17060-07-0 95 % 70-130 1 01/03/19 05:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-21 Lab ID: 92412408022 Collected: 12/28/18 14:51 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111�41:49191:261.9 Thallium 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 01/14/2019 01:24 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:21 7440-36-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:21 7440-38-2 27.3 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-39-3 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:21 7440-41-7 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:21 7440-43-9 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-47-3 3.8J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-48-4 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-50-8 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7439-92-1 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-02-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:21 7782-49-2 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-22-4 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:21 7440-62-2 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:37 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:46 7439-97-6 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 01/03/19 06:00 67-64-1 ND ug/L 10.0 1.9 1 01/03/19 06:00 107-13-1 ND ug/L 1.0 0.25 1 01/03/19 06:00 71-43-2 ND ug/L 1.0 0.17 1 01/03/19 06:00 74-97-5 ND ug/L 1.0 0.18 1 01/03/19 06:00 75-27-4 ND ug/L 1.0 0.26 1 01/03/19 06:00 75-25-2 ND ug/L 2.0 0.29 1 01/03/19 06:00 74-83-9 ND ug/L 5.0 0.96 1 01/03/19 06:00 78-93-3 ND ug/L 2.0 1.2 1 01/03/19 06:00 75-15-0 ND ug/L 1.0 0.25 1 01/03/19 06:00 56-23-5 ND ug/L 1.0 0.23 1 01/03/19 06:00 108-90-7 ND ug/L 1.0 0.54 1 01/03/19 06:00 75-00-3 ND ug/L 1.0 0.14 1 01/03/19 06:00 67-66-3 ND ug/L 1.0 0.11 1 01/03/19 06:00 74-87-3 ND ug/L 2.0 2.0 1 01/03/19 06:00 96-12-8 ND ug/L 1.0 0.21 1 01/03/19 06:00 124-48-1 ND ug/L 1.0 0.27 1 01/03/19 06:00 106-93-4 ND ug/L 1.0 0.21 1 01/03/19 06:00 74-95-3 ND ug/L 1.0 0.30 1 01/03/19 06:00 95-50-1 ND ug/L 1.0 0.33 1 01/03/19 06:00 106-46-7 ND ug/L 1.0 1.0 1 01/03/19 06:00 110-57-6 ND ug/L 1.0 0.32 1 01/03/19 06:00 75-34-3 ND ug/L 1.0 0.24 1 01/03/19 06:00 107-06-2 ND ug/L 1.0 0.56 1 01/03/19 06:00 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-21 Lab ID: 92412408022 Collected: 12/28/18 14:51 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.19 1 01/03/19 06:00 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 06:00 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 06:00 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 06:00 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 06:00 10061-02-6 ND ug/L 150 78.4 1 01/03/19 06:00 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 06:00 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 06:00 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 06:00 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 06:00 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 06:00 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 06:00 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 06:00 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 06:00 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 06:00 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 06:00 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 06:00 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 06:00 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 06:00 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 06:00 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 06:00 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 06:00 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 06:00 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 06:00 1330-20-7 97 % 70-130 1 01/03/19 06:00 460-00-4 97 % 70-130 1 01/03/19 06:00 17060-07-0 96 % 70-130 1 01/03/19 06:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-22 Lab ID: 92412408023 Collected: 12/28/18 11:46 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 01/14/2019 01:24 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:24 7440-36-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:24 7440-38-2 51.1 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-39-3 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:24 7440-41-7 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:24 7440-43-9 4.1J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-47-3 4.3J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-48-4 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-50-8 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7439-92-1 4.OJ ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-02-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:24 7782-49-2 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-22-4 3.6J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:24 7440-62-2 14.4 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:24 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:46 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 01/03/19 06:17 67-64-1 ND ug/L 10.0 1.9 1 01/03/19 06:17 107-13-1 ND ug/L 1.0 0.25 1 01/03/19 06:17 71-43-2 ND ug/L 1.0 0.17 1 01/03/19 06:17 74-97-5 ND ug/L 1.0 0.18 1 01/03/19 06:17 75-27-4 ND ug/L 1.0 0.26 1 01/03/19 06:17 75-25-2 ND ug/L 2.0 0.29 1 01/03/19 06:17 74-83-9 ND ug/L 5.0 0.96 1 01/03/19 06:17 78-93-3 ND ug/L 2.0 1.2 1 01/03/19 06:17 75-15-0 ND ug/L 1.0 0.25 1 01/03/19 06:17 56-23-5 ND ug/L 1.0 0.23 1 01/03/19 06:17 108-90-7 ND ug/L 1.0 0.54 1 01/03/19 06:17 75-00-3 ND ug/L 1.0 0.14 1 01/03/19 06:17 67-66-3 ND ug/L 1.0 0.11 1 01/03/19 06:17 74-87-3 ND ug/L 2.0 2.0 1 01/03/19 06:17 96-12-8 ND ug/L 1.0 0.21 1 01/03/19 06:17 124-48-1 ND ug/L 1.0 0.27 1 01/03/19 06:17 106-93-4 ND ug/L 1.0 0.21 1 01/03/19 06:17 74-95-3 ND ug/L 1.0 0.30 1 01/03/19 06:17 95-50-1 ND ug/L 1.0 0.33 1 01/03/19 06:17 106-46-7 ND ug/L 1.0 1.0 1 01/03/19 06:17 110-57-6 ND ug/L 1.0 0.32 1 01/03/19 06:17 75-34-3 ND ug/L 1.0 0.24 1 01/03/19 06:17 107-06-2 ND ug/L 1.0 0.56 1 01/03/19 06:17 75-35-4 ND ug/L 1.0 0.19 1 01/03/19 06:17 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 06:17 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 06:17 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 61 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-22 Lab ID: 92412408023 Collected: 12/28/18 11:46 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 06:17 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 06:17 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 06:17 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 06:17 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 06:17 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 06:17 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 06:17 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 06:17 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 06:17 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 06:17 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 06:17 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 06:17 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 06:17 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 06:17 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 06:17 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 06:17 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 06:17 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 06:17 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 06:17 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 06:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 06:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 01/03/19 06:17 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 01/03/19 06:17 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 01/03/19 06:17 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-23 Lab ID: 92412408024 Collected: 12/28/18 11:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 01/14/2019 01:24 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:27 7440-36-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:27 7440-38-2 21.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-39-3 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:27 7440-41-7 ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:27 7440-43-9 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-47-3 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-48-4 12.5 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-50-8 3.8J ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7439-92-1 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-02-0 ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:27 7782-49-2 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-22-4 ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:27 7440-62-2 31.4 ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:27 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:49 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 01/03/19 06:34 67-64-1 ND ug/L 10.0 1.9 1 01/03/19 06:34 107-13-1 ND ug/L 1.0 0.25 1 01/03/19 06:34 71-43-2 ND ug/L 1.0 0.17 1 01/03/19 06:34 74-97-5 ND ug/L 1.0 0.18 1 01/03/19 06:34 75-27-4 ND ug/L 1.0 0.26 1 01/03/19 06:34 75-25-2 ND ug/L 2.0 0.29 1 01/03/19 06:34 74-83-9 ND ug/L 5.0 0.96 1 01/03/19 06:34 78-93-3 ND ug/L 2.0 1.2 1 01/03/19 06:34 75-15-0 ND ug/L 1.0 0.25 1 01/03/19 06:34 56-23-5 ND ug/L 1.0 0.23 1 01/03/19 06:34 108-90-7 ND ug/L 1.0 0.54 1 01/03/19 06:34 75-00-3 ND ug/L 1.0 0.14 1 01/03/19 06:34 67-66-3 ND ug/L 1.0 0.11 1 01/03/19 06:34 74-87-3 ND ug/L 2.0 2.0 1 01/03/19 06:34 96-12-8 ND ug/L 1.0 0.21 1 01/03/19 06:34 124-48-1 ND ug/L 1.0 0.27 1 01/03/19 06:34 106-93-4 ND ug/L 1.0 0.21 1 01/03/19 06:34 74-95-3 ND ug/L 1.0 0.30 1 01/03/19 06:34 95-50-1 ND ug/L 1.0 0.33 1 01/03/19 06:34 106-46-7 ND ug/L 1.0 1.0 1 01/03/19 06:34 110-57-6 ND ug/L 1.0 0.32 1 01/03/19 06:34 75-34-3 ND ug/L 1.0 0.24 1 01/03/19 06:34 107-06-2 ND ug/L 1.0 0.56 1 01/03/19 06:34 75-35-4 ND ug/L 1.0 0.19 1 01/03/19 06:34 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 06:34 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 06:34 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 63 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-23 Lab ID: 92412408024 Collected: 12/28/18 11:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 06:34 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 06:34 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 06:34 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 06:34 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 06:34 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 06:34 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 06:34 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 06:34 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 06:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 06:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 06:34 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 06:34 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 06:34 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 06:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 06:34 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 06:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 06:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 06:34 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 06:34 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 06:34 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 06:34 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 01/03/19 06:34 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 01/03/19 06:34 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 01/03/19 06:34 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-20 Lab ID: 92412408025 Collected: 12/28/18 15:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/29/18 05:25 12/31/18 16:37 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:37 7440-38-2 Barium 54.9 ug/L 5.0 2.5 1 12/29/18 05:25 01/02/19 16:58 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:37 7440-41-7 Cadmium 13.7 ug/L 1.0 0.50 1 12/29/18 05:25 12/31/18 16:37 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7439-92-1 Nickel 10.7 ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:37 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/29/18 05:25 12/31/18 16:37 7440-62-2 Zinc 7.1J ug/L 10.0 5.0 1 12/29/18 05:25 12/31/18 16:37 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:52 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 06:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 06:52 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 06:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 06:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 06:52 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 06:52 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 06:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 06:52 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 06:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 06:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 06:52 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 06:52 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 06:52 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 06:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 06:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 06:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 06:52 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 06:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 06:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 06:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 06:52 110-57-6 1,1-Dichloroethane 0.55J ug/L 1.0 0.32 1 01/03/19 06:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 06:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 06:52 75-35-4 cis-1,2-Dichloroethene 0.57J ug/L 1.0 0.19 1 01/03/19 06:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 06:52 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 06:52 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-20 Lab ID: 92412408025 Collected: 12/28/18 15:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 06:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 06:52 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 06:52 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 06:52 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 06:52 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 06:52 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 06:52 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 06:52 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 06:52 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 06:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 06:52 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 06:52 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 06:52 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 06:52 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 06:52 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 06:52 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 06:52 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 06:52 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 06:52 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 06:52 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 06:52 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/03/19 06:52 460-00-4 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 01/03/19 06:52 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 01/03/19 06:52 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-27 Lab ID: 92412408026 Collected: 12/28/18 14:05 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 17:46 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 17:46 7440-38-2 Barium 57.5 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 17:46 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 17:46 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 17:46 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 17:46 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 17:46 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:55 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 07:09 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 07:09 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 07:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 07:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 07:09 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 07:09 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 07:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 07:09 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 07:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 07:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 07:09 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 07:09 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 07:09 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 07:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 07:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 07:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 07:09 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 07:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 07:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 07:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 07:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 07:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 07:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 07:09 75-35-4 cis-1,2-Dichloroethene 13.9 ug/L 1.0 0.19 1 01/03/19 07:09 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 07:09 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 07:09 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-27 Lab ID: 92412408026 Collected: 12/28/18 14:05 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 07:09 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 07:09 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 07:09 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 07:09 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 07:09 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 07:09 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 07:09 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 07:09 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 07:09 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 07:09 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 07:09 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 07:09 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 07:09 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 07:09 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 07:09 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 07:09 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 07:09 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 07:09 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 07:09 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 07:09 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 07:09 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/03/19 07:09 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 01/03/19 07:09 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 01/03/19 07:09 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 68 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-32 Lab ID: 92412408027 Collected: 12/28/18 13:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:04 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:04 7440-38-2 Barium 7.9 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:04 7440-41-7 Cadmium 0.69J ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:04 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7439-92-1 Nickel 7.4 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:04 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:04 7440-62-2 Zinc 9.1J ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:04 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 14:58 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/03/19 07:26 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/03/19 07:26 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/03/19 07:26 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/03/19 07:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/03/19 07:26 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/03/19 07:26 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/03/19 07:26 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/03/19 07:26 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/03/19 07:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/03/19 07:26 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/03/19 07:26 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/03/19 07:26 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/03/19 07:26 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/03/19 07:26 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/03/19 07:26 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/03/19 07:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/03/19 07:26 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/03/19 07:26 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/03/19 07:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/03/19 07:26 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/03/19 07:26 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/03/19 07:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/03/19 07:26 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/03/19 07:26 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/03/19 07:26 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/03/19 07:26 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/03/19 07:26 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-32 Lab ID: 92412408027 Collected: 12/28/18 13:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 07:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 07:26 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 07:26 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 07:26 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 07:26 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 07:26 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 07:26 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 07:26 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 07:26 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 07:26 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 07:26 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 07:26 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 07:26 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 07:26 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 07:26 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 07:26 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 07:26 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 07:26 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 07:26 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 07:26 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 07:26 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/03/19 07:26 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 01/03/19 07:26 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 01/03/19 07:26 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-33 Lab ID: 92412408028 Collected: 12/27/18 15:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:07 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:07 7440-38-2 Barium 25.8 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:07 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:07 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-47-3 Cobalt 12.8 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7439-92-1 Nickel 2.9J ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:07 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:07 7440-62-2 Zinc 7.5J ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:07 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:00 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 20:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 20:35 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 20:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 20:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 20:35 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 20:35 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 20:35 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 20:35 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 20:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 20:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 20:35 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 20:35 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 20:35 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 20:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 20:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 20:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 20:35 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 20:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 20:35 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 20:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 20:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 20:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 20:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 20:35 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/02/19 20:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 20:35 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 20:35 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-33 Lab ID: 92412408028 Collected: 12/27/18 15:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 20:35 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 20:35 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 20:35 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 20:35 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 20:35 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 20:35 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 20:35 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 20:35 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 20:35 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 20:35 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 20:35 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 20:35 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 20:35 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 20:35 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 20:35 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 20:35 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 20:35 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 20:35 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 20:35 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 20:35 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 20:35 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/02/19 20:35 460-00-4 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 01/02/19 20:35 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 01/02/19 20:35 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-34 Lab ID: 92412408029 Collected: 12/27/18 15:39 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:10 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:10 7440-38-2 Barium 21.1 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:10 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:10 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:10 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:10 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:10 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:03 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 20:52 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 20:52 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 20:52 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 20:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 20:52 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 20:52 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 20:52 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 20:52 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 20:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 20:52 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 20:52 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 20:52 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 20:52 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 20:52 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 20:52 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 20:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 20:52 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 20:52 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 20:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 20:52 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 20:52 110-57-6 1,1-Dichloroethane 0.68J ug/L 1.0 0.32 1 01/02/19 20:52 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 20:52 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 20:52 75-35-4 cis-1,2-Dichloroethene 0.35J ug/L 1.0 0.19 1 01/02/19 20:52 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 20:52 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 20:52 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-34 Lab ID: 92412408029 Collected: 12/27/18 15:39 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 20:52 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 20:52 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 20:52 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 20:52 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 20:52 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 20:52 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 20:52 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 20:52 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 20:52 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 20:52 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 20:52 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 20:52 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 20:52 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 20:52 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 20:52 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 20:52 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 20:52 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 20:52 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 20:52 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 20:52 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 20:52 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 01/02/19 20:52 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 01/02/19 20:52 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 01/02/19 20:52 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 74 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-3 Lab ID: 92412408030 Collected: 12/27/18 13:17 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:13 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:13 7440-38-2 Barium 38.1 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:13 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:13 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:13 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:13 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:13 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:06 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 21:09 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 21:09 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 21:09 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 21:09 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 21:09 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 21:09 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 21:09 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 21:09 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 21:09 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 21:09 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 21:09 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 21:09 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 21:09 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 21:09 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 21:09 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 21:09 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 21:09 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 21:09 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 21:09 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 21:09 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 21:09 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 21:09 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 21:09 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 21:09 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/02/19 21:09 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 21:09 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 21:09 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-3 Lab ID: 92412408030 Collected: 12/27/18 13:17 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 21:09 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 21:09 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 21:09 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 21:09 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 21:09 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 21:09 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 21:09 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 21:09 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 21:09 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 21:09 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 21:09 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 21:09 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 21:09 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 21:09 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 21:09 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 21:09 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 21:09 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 21:09 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 21:09 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 21:09 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 21:09 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 01/02/19 21:09 460-00-4 1,2-Dichloroethane-d4 (S) 104 % 70-130 1 01/02/19 21:09 17060-07-0 Toluene-d8 (S) 96 % 70-130 1 01/02/19 21:09 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-4R Lab ID: 92412408031 Collected: 12/27/18 13:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:16 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:16 7440-38-2 Barium 37.6 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:16 7440-41-7 Cadmium 1.7 ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:16 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:16 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:16 7440-62-2 Zinc 12.2 ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:16 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:09 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 21:27 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 21:27 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 21:27 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 21:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 21:27 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 21:27 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 21:27 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 21:27 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 21:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 21:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 21:27 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 21:27 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 21:27 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 21:27 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 21:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 21:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 21:27 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 21:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 21:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 21:27 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 21:27 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 21:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 21:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 21:27 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/02/19 21:27 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 21:27 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 21:27 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-4R Lab ID: 92412408031 Collected: 12/27/18 13:00 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 21:27 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 21:27 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 21:27 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 21:27 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 21:27 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 21:27 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 21:27 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 21:27 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 21:27 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 21:27 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 21:27 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 21:27 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 21:27 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 21:27 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 21:27 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 21:27 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 21:27 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 21:27 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 21:27 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 21:27 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 21:27 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/02/19 21:27 460-00-4 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 01/02/19 21:27 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 01/02/19 21:27 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 78 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-5 Lab ID: 92412408032 Collected: 12/27/18 15:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:19 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:19 7440-38-2 Barium 23.8 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:19 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:19 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-47-3 Cobalt 14.2 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-48-4 Copper 6.6 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:19 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:19 7440-62-2 Zinc 6.9J ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:19 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:12 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 21:44 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 21:44 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 21:44 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 21:44 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 21:44 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 21:44 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 21:44 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 21:44 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 21:44 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 21:44 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 21:44 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 21:44 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 21:44 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 21:44 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 21:44 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 21:44 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 21:44 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 21:44 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 21:44 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 21:44 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 21:44 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 21:44 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 21:44 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 21:44 75-35-4 cis-1,2-Dichloroethene 0.811 ug/L 1.0 0.19 1 01/02/19 21:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 21:44 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 21:44 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-5 Lab ID: 92412408032 Collected: 12/27/18 15:30 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 21:44 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 21:44 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 21:44 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 21:44 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 21:44 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 21:44 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 21:44 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 21:44 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 21:44 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 21:44 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 21:44 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 21:44 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 21:44 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 21:44 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 21:44 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 21:44 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 21:44 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 21:44 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 21:44 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 21:44 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 21:44 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/02/19 21:44 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 01/02/19 21:44 17060-07-0 Toluene-d8 (S) 103 % 70-130 1 01/02/19 21:44 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 80 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-6 Lab ID: 92412408033 Collected: 12/27/18 15:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:22 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:22 7440-38-2 Barium 19.3 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:22 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:22 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:22 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:22 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:22 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:21 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 22:18 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 22:18 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 22:18 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 22:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 22:18 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 22:18 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 22:18 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 22:18 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 22:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 22:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 22:18 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 22:18 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 22:18 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 22:18 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 22:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 22:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 22:18 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 22:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 22:18 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 22:18 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 22:18 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 22:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 22:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 22:18 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/02/19 22:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 22:18 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 22:18 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: SW-6 Lab ID: 92412408033 Collected: 12/27/18 15:45 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 22:18 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 22:18 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 22:18 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 22:18 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 22:18 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 22:18 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 22:18 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 22:18 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 22:18 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 22:18 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 22:18 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 22:18 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 22:18 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 22:18 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 22:18 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 22:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 22:18 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 22:18 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 22:18 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 22:18 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 22:18 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 01/02/19 22:18 460-00-4 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 01/02/19 22:18 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 01/02/19 22:18 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: EB Lab ID: 92412408034 Collected: 12/28/18 15:10 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:25 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:25 7440-38-2 Barium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:25 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:25 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:25 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:25 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:25 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:24 7440-28-0 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:48 7439-97-6 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 14:36 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 14:36 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 14:36 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 14:36 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 14:36 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 14:36 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 14:36 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 14:36 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 14:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 14:36 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 14:36 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 14:36 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 14:36 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 14:36 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 14:36 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 14:36 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 14:36 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 14:36 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 14:36 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 14:36 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 14:36 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 14:36 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 14:36 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 14:36 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: EB Lab ID: 92412408034 Collected: 12/28/18 15:10 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.19 1 01/02/1914:36 156-59-2 ND ug/L 1.0 0.49 1 01/02/1914:36 156-60-5 ND ug/L 1.0 0.27 1 01/02/1914:36 78-87-5 ND ug/L 1.0 0.13 1 01 /02/19 14:36 10061-01-5 ND ug/L 1.0 0.26 1 01/02/1914:36 10061-02-6 ND ug/L 150 78.4 1 01/02/1914:36 123-91-1 ND ug/L 1.0 0.30 1 01/02/1914:36 100-41-4 ND ug/L 5.0 0.46 1 01/02/1914:36 591-78-6 ND ug/L 5.0 0.32 1 01/02/1914:36 74-88-4 ND ug/L 1.0 0.97 1 01/02/1914:36 75-09-2 ND ug/L 5.0 0.33 1 01/02/1914:36 108-10-1 ND ug/L 1.0 0.26 1 01/02/1914:36 100-42-5 ND ug/L 1.0 0.33 1 01/02/1914:36 630-20-6 ND ug/L 1.0 0.40 1 01/02/1914:36 79-34-5 ND ug/L 1.0 0.46 1 01/02/1914:36 127-18-4 ND ug/L 1.0 0.26 1 01/02/1914:36 108-88-3 ND ug/L 1.0 0.48 1 01/02/1914:36 71-55-6 ND ug/L 1.0 0.29 1 01/02/1914:36 79-00-5 ND ug/L 1.0 0.47 1 01/02/1914:36 79-01-6 ND ug/L 1.0 0.20 1 01/02/1914:36 75-69-4 ND ug/L 1.0 0.41 1 01/02/1914:36 96-18-4 ND ug/L 2.0 0.35 1 01/02/1914:36 108-05-4 ND ug/L 1.0 0.62 1 01/02/1914:36 75-01-4 ND ug/L 1.0 0.66 1 01/02/1914:36 1330-20-7 98 % 70-130 1 01/02/1914:36 460-00-4 105 % 70-130 1 01/02/1914:36 17060-07-0 101 % 70-130 1 01/02/1914:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 84 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: FB Lab ID: 92412408035 Collected: 12/28/18 15:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:40 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:40 7440-38-2 Barium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:40 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:40 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7439-92-1 Nickel ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:40 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:40 7440-62-2 Zinc ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:40 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:27 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 14:19 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 14:19 107-13-1 Benzene ND ug/L 1.0 0.25 1 01/02/19 14:19 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 14:19 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 14:19 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 14:19 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 14:19 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 01/02/19 14:19 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 14:19 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 14:19 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 14:19 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 14:19 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 14:19 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 14:19 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 14:19 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 14:19 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 14:19 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 14:19 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 01/02/19 14:19 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 01/02/19 14:19 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 14:19 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 14:19 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 14:19 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 14:19 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 01/02/19 14:19 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 14:19 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 14:19 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: FB Lab ID: 92412408035 Collected: 12/28/18 15:15 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 14:19 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 14:19 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 14:19 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/02/19 14:19 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 14:19 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 14:19 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 14:19 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 14:19 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 14:19 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 14:19 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 14:19 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 14:19 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/02/19 14:19 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 14:19 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 14:19 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 14:19 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 14:19 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 14:19 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 14:19 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 14:19 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/02/19 14:19 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 01/02/19 14:19 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-130 1 01/02/19 14:19 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 01/02/19 14:19 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-3 Lab ID: 92412408036 Collected: 12/27/18 17:33 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:43 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:43 7440-38-2 Barium 53.9 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:43 7440-41-7 Cadmium 0.70J ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:43 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-47-3 Cobalt 21.7 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-48-4 Copper ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-50-8 Lead 7.3 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7439-92-1 Nickel 10.4 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:43 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-22-4 Vanadium 4.8J ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:43 7440-62-2 Zinc 13.8 ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:43 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:30 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 01/02/19 22:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 01/02/19 22:35 107-13-1 Benzene 5.2 ug/L 1.0 0.25 1 01/02/19 22:35 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 01/02/19 22:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 01/02/19 22:35 75-27-4 Bromoform ND ug/L 1.0 0.26 1 01/02/19 22:35 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 01/02/19 22:35 74-83-9 2-Butanone (MEK) 1.2J ug/L 5.0 0.96 1 01/02/19 22:35 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 01/02/19 22:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 01/02/19 22:35 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 01/02/19 22:35 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 01/02/19 22:35 75-00-3 Chloroform ND ug/L 1.0 0.14 1 01/02/19 22:35 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 01/02/19 22:35 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 01/02/19 22:35 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 01/02/19 22:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 01/02/19 22:35 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 01/02/19 22:35 74-95-3 1,2-Dichlorobenzene 0.67J ug/L 1.0 0.30 1 01/02/19 22:35 95-50-1 1,4-Dichlorobenzene 8.4 ug/L 1.0 0.33 1 01/02/19 22:35 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 01/02/19 22:35 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 01/02/19 22:35 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 01/02/19 22:35 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 01/02/19 22:35 75-35-4 cis-1,2-Dichloroethene 4.5 ug/L 1.0 0.19 1 01/02/19 22:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 01/02/19 22:35 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 01/02/19 22:35 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-3 Lab ID: 92412408036 Collected: 12/27/18 17:33 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/02/19 22:35 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/02/19 22:35 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/02/19 22:35 123-91-1 Ethylbenzene 0.92J ug/L 1.0 0.30 1 01/02/19 22:35 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/02/19 22:35 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/02/19 22:35 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/02/19 22:35 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/02/19 22:35 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/02/19 22:35 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/02/19 22:35 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/02/19 22:35 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/02/19 22:35 127-18-4 Toluene 0.96J ug/L 1.0 0.26 1 01/02/19 22:35 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/02/19 22:35 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/02/19 22:35 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/02/19 22:35 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/02/19 22:35 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/02/19 22:35 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/02/19 22:35 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/02/19 22:35 75-01-4 Xylene (Total) 1.2 ug/L 1.0 0.66 1 01/02/19 22:35 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 01/02/19 22:35 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 01/02/19 22:35 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 01/02/19 22:35 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 88 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-7 Lab ID: 92412408037 Collected: 12/28/18 11:46 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 01/14/2019 01:24 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:46 7440-36-0 ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:46 7440-38-2 6.6 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-39-3 ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:46 7440-41-7 0.84J ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:46 7440-43-9 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-47-3 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-48-4 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-50-8 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7439-92-1 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-02-0 ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:46 7782-49-2 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-22-4 ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:46 7440-62-2 ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:46 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:33 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 01/03/19 07:43 67-64-1 ND ug/L 10.0 1.9 1 01/03/19 07:43 107-13-1 2.7 ug/L 1.0 0.25 1 01/03/19 07:43 71-43-2 ND ug/L 1.0 0.17 1 01/03/19 07:43 74-97-5 ND ug/L 1.0 0.18 1 01/03/19 07:43 75-27-4 ND ug/L 1.0 0.26 1 01/03/19 07:43 75-25-2 ND ug/L 2.0 0.29 1 01/03/19 07:43 74-83-9 ND ug/L 5.0 0.96 1 01/03/19 07:43 78-93-3 ND ug/L 2.0 1.2 1 01/03/19 07:43 75-15-0 ND ug/L 1.0 0.25 1 01/03/19 07:43 56-23-5 ND ug/L 1.0 0.23 1 01/03/19 07:43 108-90-7 ND ug/L 1.0 0.54 1 01/03/19 07:43 75-00-3 ND ug/L 1.0 0.14 1 01/03/19 07:43 67-66-3 ND ug/L 1.0 0.11 1 01/03/19 07:43 74-87-3 ND ug/L 2.0 2.0 1 01/03/19 07:43 96-12-8 ND ug/L 1.0 0.21 1 01/03/19 07:43 124-48-1 ND ug/L 1.0 0.27 1 01/03/19 07:43 106-93-4 ND ug/L 1.0 0.21 1 01/03/19 07:43 74-95-3 ND ug/L 1.0 0.30 1 01/03/19 07:43 95-50-1 ND ug/L 1.0 0.33 1 01/03/19 07:43 106-46-7 ND ug/L 1.0 1.0 1 01/03/19 07:43 110-57-6 1.1 ug/L 1.0 0.32 1 01/03/19 07:43 75-34-3 0.27J ug/L 1.0 0.24 1 01/03/19 07:43 107-06-2 ND ug/L 1.0 0.56 1 01/03/19 07:43 75-35-4 5.7 ug/L 1.0 0.19 1 01/03/19 07:43 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 07:43 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 07:43 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 89 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-7 Lab ID: 92412408037 Collected: 12/28/18 11:46 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E cis-1,3-Dichloropropene ND ug/L 1.0 0.13 1 01/03/19 07:43 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.26 1 01/03/19 07:43 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 78.4 1 01/03/19 07:43 123-91-1 Ethylbenzene ND ug/L 1.0 0.30 1 01/03/19 07:43 100-41-4 2-Hexanone ND ug/L 5.0 0.46 1 01/03/19 07:43 591-78-6 lodomethane ND ug/L 5.0 0.32 1 01/03/19 07:43 74-88-4 Methylene Chloride ND ug/L 1.0 0.97 1 01/03/19 07:43 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.33 1 01/03/19 07:43 108-10-1 Styrene ND ug/L 1.0 0.26 1 01/03/19 07:43 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.33 1 01/03/19 07:43 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.40 1 01/03/19 07:43 79-34-5 Tetrachloroethene ND ug/L 1.0 0.46 1 01/03/19 07:43 127-18-4 Toluene ND ug/L 1.0 0.26 1 01/03/19 07:43 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.48 1 01/03/19 07:43 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.29 1 01/03/19 07:43 79-00-5 Trichloroethene ND ug/L 1.0 0.47 1 01/03/19 07:43 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.20 1 01/03/19 07:43 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.41 1 01/03/19 07:43 96-18-4 Vinyl acetate ND ug/L 2.0 0.35 1 01/03/19 07:43 108-05-4 Vinyl chloride ND ug/L 1.0 0.62 1 01/03/19 07:43 75-01-4 Xylene (Total) ND ug/L 1.0 0.66 1 01/03/19 07:43 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 98 % 70-130 1 01/03/19 07:43 460-00-4 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 01/03/19 07:43 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 01/03/19 07:43 2037-26-5 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 90 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-18 Lab ID: 92412408038 Collected: 12/27/18 11:40 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane ND ug/L 10.0 10.0 1 12/30/1813:54 74-82-8 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 01/02/19 01:45 01/02/19 18:49 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:49 7440-38-2 Barium 18.0 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:49 7440-41-7 Cadmium 0.52J ug/L 1.0 0.50 1 01/02/19 01:45 01/02/19 18:49 7440-43-9 Chromium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-47-3 Cobalt 7.4 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-48-4 Copper 4.4J ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-50-8 Lead ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7439-92-1 Nickel 6.2 ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-02-0 Selenium ND ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:49 7782-49-2 Silver ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 01/02/19 01:45 01/02/19 18:49 7440-62-2 Zinc 7.7J ug/L 10.0 5.0 1 01/02/19 01:45 01/02/19 18:49 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.15 ug/L 0.10 0.060 1 12/29/18 04:00 12/31/18 15:36 7440-28-0 7470 Mercury Mercury 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 01/14/2019 01:24 PM Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.10 1 12/31/1817:42 01/02/1911:50 7439-97-6 Analytical Method: EPA 8260E ND ug/L 25.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 5.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 10.0 1 01/03/19 02:00 67-64-1 1.9 1 01/03/19 02:00 107-13-1 0.25 1 01/03/19 02:00 71-43-2 0.17 1 01/03/19 02:00 74-97-5 0.18 1 01/03/19 02:00 75-27-4 0.26 1 01/03/19 02:00 75-25-2 0.29 1 01/03/19 02:00 74-83-9 0.96 1 01/03/19 02:00 78-93-3 1.2 1 01/03/19 02:00 75-15-0 0.25 1 01/03/19 02:00 56-23-5 0.23 1 01/03/19 02:00 108-90-7 0.54 1 01/03/19 02:00 75-00-3 0.14 1 01/03/19 02:00 67-66-3 0.11 1 01/03/19 02:00 74-87-3 2.0 1 01/03/19 02:00 96-12-8 0.21 1 01/03/19 02:00 124-48-1 0.27 1 01/03/19 02:00 106-93-4 0.21 1 01/03/19 02:00 74-95-3 0.30 1 01/03/19 02:00 95-50-1 0.33 1 01/03/19 02:00 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 91 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWS Pace Project No.: 92412408 Sample: MW-18 Lab ID: 92412408038 Collected: 12/27/18 11:40 Received: 12/28/18 15:54 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 01/14/2019 01:24 PM Analytical Method: EPA 8260E ND ug/L 1.0 1.0 1 01/03/19 02:00 110-57-6 ND ug/L 1.0 0.32 1 01/03/19 02:00 75-34-3 ND ug/L 1.0 0.24 1 01/03/19 02:00 107-06-2 ND ug/L 1.0 0.56 1 01/03/19 02:00 75-35-4 ND ug/L 1.0 0.19 1 01/03/19 02:00 156-59-2 ND ug/L 1.0 0.49 1 01/03/19 02:00 156-60-5 ND ug/L 1.0 0.27 1 01/03/19 02:00 78-87-5 ND ug/L 1.0 0.13 1 01/03/19 02:00 10061-01-5 ND ug/L 1.0 0.26 1 01/03/19 02:00 10061-02-6 ND ug/L 150 78.4 1 01/03/19 02:00 123-91-1 ND ug/L 1.0 0.30 1 01/03/19 02:00 100-41-4 ND ug/L 5.0 0.46 1 01/03/19 02:00 591-78-6 ND ug/L 5.0 0.32 1 01/03/19 02:00 74-88-4 ND ug/L 1.0 0.97 1 01/03/19 02:00 75-09-2 ND ug/L 5.0 0.33 1 01/03/19 02:00 108-10-1 ND ug/L 1.0 0.26 1 01/03/19 02:00 100-42-5 ND ug/L 1.0 0.33 1 01/03/19 02:00 630-20-6 ND ug/L 1.0 0.40 1 01/03/19 02:00 79-34-5 ND ug/L 1.0 0.46 1 01/03/19 02:00 127-18-4 ND ug/L 1.0 0.26 1 01/03/19 02:00 108-88-3 ND ug/L 1.0 0.48 1 01/03/19 02:00 71-55-6 ND ug/L 1.0 0.29 1 01/03/19 02:00 79-00-5 ND ug/L 1.0 0.47 1 01/03/19 02:00 79-01-6 ND ug/L 1.0 0.20 1 01/03/19 02:00 75-69-4 ND ug/L 1.0 0.41 1 01/03/19 02:00 96-18-4 ND ug/L 2.0 0.35 1 01/03/19 02:00 108-05-4 ND ug/L 1.0 0.62 1 01/03/19 02:00 75-01-4 ND ug/L 1.0 0.66 1 01/03/19 02:00 1330-20-7 100 % 70-130 1 01/03/19 02:00 460-00-4 100 % 70-130 1 01/03/19 02:00 17060-07-0 100 % 70-130 1 01/03/19 02:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 92 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450194 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408007, 92412408008, 92412408010,92412408011,92412408012,92412408038 METHOD BLANK: 2463625 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408007, 92412408008, 92412408010,92412408011,92412408012,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 10.0 12/30/1810:20 LABORATORY CONTROL SAMPLE: 2463626 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Methane ug/L 396 398 101 70-130 MATRIX SPIKE SAMPLE: 2463680 92412408011 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Methane ug/L 29.6 396 410 96 70-130 SAMPLE DUPLICATE: 2463679 92412408003 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 8140 8430 4 20 SAMPLE DUPLICATE: 2463681 92412408038 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L ND ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450214 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Associated Lab Samples: 92412408006, 92412408009 METHOD BLANK: 2463705 Matrix: Water Associated Lab Samples: 92412408006, 92412408009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 10.0 12/31/18 09:08 LABORATORY CONTROL SAMPLE: 2463706 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Methane ug/L 396 369 93 70-130 MATRIX SPIKE SAMPLE: 2463707 92412408006 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Methane ug/L 49.6 396 481 109 70-130 SAMPLE DUPLICATE: 2463708 92412408006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Methane ug/L 49.6 ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450293 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92412408010,92412408011,92412408012,92412408013,92412408014,92412408020,92412408021, 92412408022,92412408034,92412408038 METHOD BLANK: 2464020 Matrix: Water Associated Lab Samples: 92412408010,92412408011,92412408012,92412408013,92412408014,92412408020,92412408021, 92412408022,92412408034,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 01/02/1911:00 LABORATORY CONTROL SAMPLE: 2464021 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.7 109 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2464022 2464023 MS MSD 92412408010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 1.1 0.92 45 37 75-125 20 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450126 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006, 92412408007, 92412408008,92412408009 METHOD BLANK: 2463420 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006, 92412408007, 92412408008,92412408009 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Vanadium ug/L Zinc ug/L Blank Result Reporting Limit MDL Analyzed Qualifiers ND 5.0 3.9 12/31 /18 00:52 ND 10.0 5.0 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 1.0 0.50 12/31 /18 00:52 ND 1.0 0.50 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 10.0 5.0 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 5.0 2.5 12/31 /18 00:52 ND 10.0 5.0 12/31 /18 00:52 LABORATORY CONTROL SAMPLE: Parameter 2463421 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 508 102 80-120 Arsenic ug/L 500 486 97 80-120 Barium ug/L 500 496 99 80-120 Beryllium ug/L 500 499 100 80-120 Cadmium ug/L 500 490 98 80-120 Chromium ug/L 500 490 98 80-120 Cobalt ug/L 500 496 99 80-120 Copper ug/L 500 506 101 80-120 Lead ug/L 500 488 98 80-120 Nickel ug/L 500 490 98 80-120 Selenium ug/L 500 486 97 80-120 Silver ug/L 250 253 101 80-120 Vanadium ug/L 500 499 100 80-120 Zinc ug/L 500 491 98 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Alexander LF-SWS 92412408 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463422 2463423 MS MSD 92412390001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 497 488 99 98 75-125 2 20 Arsenic ug/L ND 500 500 480 473 96 95 75-125 2 20 Barium ug/L ND 500 500 484 472 97 94 75-125 3 20 Beryllium ug/L ND 500 500 488 474 98 95 75-125 3 20 Cadmium ug/L ND 500 500 486 476 97 95 75-125 2 20 Chromium ug/L ND 500 500 486 472 97 94 75-125 3 20 Cobalt ug/L ND 500 500 488 476 98 95 75-125 2 20 Copper ug/L ND 500 500 491 478 98 95 75-125 3 20 Lead ug/L ND 500 500 480 472 96 94 75-125 2 20 Nickel ug/L ND 500 500 483 472 97 94 75-125 2 20 Selenium ug/L ND 500 500 495 486 99 97 75-125 2 20 Silver ug/L ND 250 250 247 241 99 97 75-125 2 20 Vanadium ug/L ND 500 500 488 476 98 95 75-125 3 20 Zinc ug/L ND 500 500 490 481 98 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450127 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92412408010, 92412408011, 92412408012, 92412408013, 92412408014, 92412408015, 92412408016, 92412408017,92412408018,92412408019,92412408020,92412408021,92412408022,92412408023, 92412408024,92412408025 METHOD BLANK: 2463424 Matrix: Water Associated Lab Samples: 92412408010, 92412408011, 92412408012, 92412408013, 92412408014, 92412408015, 92412408016, 92412408017,92412408018,92412408019,92412408020,92412408021,92412408022,92412408023, 92412408024,92412408025 Parameter Units Blank Result Reporting Limit MDL Antimony ug/L ND 5.0 3.9 Arsenic ug/L ND 10.0 5.0 Barium ug/L ND 5.0 2.5 Beryllium ug/L ND 1.0 0.50 Cadmium ug/L ND 1.0 0.50 Chromium ug/L ND 5.0 2.5 Cobalt ug/L ND 5.0 2.5 Copper ug/L ND 5.0 2.5 Lead ug/L ND 5.0 2.5 Nickel ug/L ND 5.0 2.5 Selenium ug/L ND 10.0 5.0 Silver ug/L ND 5.0 2.5 Vanadium ug/L ND 5.0 2.5 Zinc ug/L ND 10.0 5.0 Analyzed Qualifiers 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 12/31/18 15:22 LABORATORY CONTROL SAMPLE: Parameter 2463425 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 482 96 80-120 Arsenic ug/L 500 454 91 80-120 Barium ug/L 500 510 102 80-120 Beryllium ug/L 500 498 100 80-120 Cadmium ug/L 500 477 95 80-120 Chromium ug/L 500 487 97 80-120 Cobalt ug/L 500 478 96 80-120 Copper ug/L 500 495 99 80-120 Lead ug/L 500 468 94 80-120 Nickel ug/L 500 480 96 80-120 Selenium ug/L 500 462 92 80-120 Silver ug/L 250 245 98 80-120 Vanadium ug/L 500 491 98 80-120 Zinc ug/L 500 466 93 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Alexander LF-SWS 92412408 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463426 2463427 MS MSD 92412408010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 480 474 96 95 75-125 1 20 Arsenic ug/L ND 500 500 456 444 91 89 75-125 2 20 Barium ug/L 25.8 500 500 527 525 100 100 75-125 0 20 Beryllium ug/L ND 500 500 490 489 98 98 75-125 0 20 Cadmium ug/L 0.82J 500 500 477 477 95 95 75-125 0 20 Chromium ug/L ND 500 500 483 482 97 96 75-125 0 20 Cobalt ug/L 5.2 500 500 472 468 93 93 75-125 1 20 Copper ug/L ND 500 500 491 487 98 97 75-125 1 20 Lead ug/L ND 500 500 461 459 92 92 75-125 0 20 Nickel ug/L 3.1J 500 500 474 471 94 94 75-125 0 20 Selenium ug/L ND 500 500 468 470 94 94 75-125 0 20 Silver ug/L ND 250 250 242 242 97 97 75-125 0 20 Vanadium ug/L ND 500 500 484 482 97 96 75-125 0 20 Zinc ug/L 30.8 500 500 495 492 93 92 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450327 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92412408026,92412408027,92412408028,92412408029,92412408030,92412408031,92412408032, 92412408033,92412408034,92412408035,92412408036,92412408037,92412408038 METHOD BLANK: 2464077 Matrix: Water Associated Lab Samples: 92412408026,92412408027,92412408028,92412408029,92412408030,92412408031,92412408032, 92412408033,92412408034,92412408035,92412408036,92412408037,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 01/02/1917:40 Arsenic ug/L ND 10.0 5.0 01/02/1917:40 Barium ug/L ND 5.0 2.5 01/02/1917:40 Beryllium ug/L ND 1.0 0.50 01/02/1917:40 Cadmium ug/L ND 1.0 0.50 01/02/1917:40 Chromium ug/L ND 5.0 2.5 01/02/1917:40 Cobalt ug/L ND 5.0 2.5 01/02/1917:40 Copper ug/L ND 5.0 2.5 01/02/1917:40 Lead ug/L ND 5.0 2.5 01/02/1917:40 Nickel ug/L ND 5.0 2.5 01/02/1917:40 Selenium ug/L ND 10.0 5.0 01/02/1917:40 Silver ug/L ND 5.0 2.5 01/02/1917:40 Vanadium ug/L ND 5.0 2.5 01/02/1917:40 Zinc ug/L ND 10.0 5.0 01/02/1917:40 LABORATORY CONTROL SAMPLE: Parameter 2464078 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 513 103 80-120 Arsenic ug/L 500 489 98 80-120 Barium ug/L 500 519 104 80-120 Beryllium ug/L 500 519 104 80-120 Cadmium ug/L 500 508 102 80-120 Chromium ug/L 500 518 104 80-120 Cobalt ug/L 500 515 103 80-120 Copper ug/L 500 529 106 80-120 Lead ug/L 500 499 100 80-120 Nickel ug/L 500 514 103 80-120 Selenium ug/L 500 486 97 80-120 Silver ug/L 250 265 106 80-120 Vanadium ug/L 500 519 104 80-120 Zinc ug/L 500 502 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Alexander LF-SWS 92412408 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2464079 2464080 MS MSD 92412408026 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 519 517 104 103 75-125 0 20 Arsenic ug/L ND 500 500 495 491 99 98 75-125 1 20 Barium ug/L 57.5 500 500 568 570 102 103 75-125 0 20 Beryllium ug/L ND 500 500 527 527 105 105 75-125 0 20 Cadmium ug/L ND 500 500 507 504 101 101 75-125 1 20 Chromium ug/L ND 500 500 515 512 103 102 75-125 0 20 Cobalt ug/L ND 500 500 504 501 100 100 75-125 1 20 Copper ug/L ND 500 500 525 523 105 105 75-125 0 20 Lead ug/L ND 500 500 495 492 99 98 75-125 1 20 Nickel ug/L ND 500 500 503 500 100 100 75-125 1 20 Selenium ug/L ND 500 500 513 506 103 101 75-125 1 20 Silver ug/L ND 250 250 264 261 106 105 75-125 1 20 Vanadium ug/L ND 500 500 519 518 104 103 75-125 0 20 Zinc ug/L ND 500 500 505 501 100 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450131 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006, 92412408007, 92412408008,92412408009,92412408010,92412408011,92412408012,92412408013,92412408014, 92412408015,92412408016,92412408017,92412408018,92412408019,92412408020 METHOD BLANK: 2463442 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006, 92412408007, 92412408008,92412408009,92412408010,92412408011,92412408012,92412408013,92412408014, 92412408015,92412408016,92412408017,92412408018,92412408019,92412408020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/31/1816:17 LABORATORY CONTROL SAMPLE: 2463443 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463444 2463445 MS MSD 92412408001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.2 10.2 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450132 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92412408021, 92412408022, 92412408023, 92412408024, 92412408025, 92412408026, 92412408027, 92412408028,92412408029,92412408030,92412408031,92412408032,92412408033,92412408034, 92412408035,92412408036,92412408037,92412408038 METHOD BLANK: 2463446 Matrix: Water Associated Lab Samples: 92412408021, 92412408022, 92412408023, 92412408024, 92412408025, 92412408026, 92412408027, 92412408028,92412408029,92412408030,92412408031,92412408032,92412408033,92412408034, 92412408035,92412408036,92412408037,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/31/1814:16 LABORATORY CONTROL SAMPLE: 2463447 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.3 93 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463448 2463449 MS MSD 92412408021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.5 9.5 95 95 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450398 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92412408001, 92412408005, 92412408006, 92412408007, 92412408008, 92412408010, 92412408034, 92412408035 METHOD BLANK: 2464415 Matrix: Water Associated Lab Samples: 92412408001, 92412408005, 92412408006, 92412408007, 92412408008, 92412408010, 92412408034, 92412408035 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 01/02/19 13:10 1,1,1-Trichloroethane ug/L ND 1.0 0.48 01/02/19 13:10 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 01/02/19 13:10 1,1,2-Trichloroethane ug/L ND 1.0 0.29 01/02/19 13:10 1,1-Dichloroethane ug/L ND 1.0 0.32 01/02/19 13:10 1,1-Dichloroethene ug/L ND 1.0 0.56 01/02/19 13:10 1,2,3-Trichloropropane ug/L ND 1.0 0.41 01/02/19 13:10 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 01/02/19 13:10 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 01/02/19 13:10 1,2-Dichlorobenzene ug/L ND 1.0 0.30 01/02/19 13:10 1,2-Dichloroethane ug/L ND 1.0 0.24 01/02/19 13:10 1,2-Dichloropropane ug/L ND 1.0 0.27 01/02/19 13:10 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/02/19 13:10 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 01/02/19 13:10 2-Butanone (MEK) ug/L ND 5.0 0.96 01/02/19 13:10 2-Hexanone ug/L ND 5.0 0.46 01/02/19 13:10 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 01/02/19 13:10 Acetone ug/L ND 25.0 10.0 01/02/19 13:10 Acrylonitrile ug/L ND 10.0 1.9 01/02/19 13:10 Benzene ug/L ND 1.0 0.25 01/02/19 13:10 Bromochloromethane ug/L ND 1.0 0.17 01/02/19 13:10 Bromodichloromethane ug/L ND 1.0 0.18 01/02/19 13:10 Bromoform ug/L ND 1.0 0.26 01/02/19 13:10 Bromomethane ug/L ND 2.0 0.29 01/02/19 13:10 Carbon disulfide ug/L ND 2.0 1.2 01/02/19 13:10 Carbon tetrachloride ug/L ND 1.0 0.25 01/02/19 13:10 Chlorobenzene ug/L ND 1.0 0.23 01/02/19 13:10 Chloroethane ug/L ND 1.0 0.54 01/02/19 13:10 Chloroform ug/L ND 1.0 0.14 01/02/19 13:10 Chloromethane ug/L ND 1.0 0.11 01/02/19 13:10 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 01/02/19 13:10 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 01/02/19 13:10 Dibromochloromethane ug/L ND 1.0 0.21 01/02/19 13:10 Dibromomethane ug/L ND 1.0 0.21 01/02/19 13:10 Ethylbenzene ug/L ND 1.0 0.30 01/02/19 13:10 lodomethane ug/L ND 5.0 0.32 01/02/19 13:10 Methylene Chloride ug/L ND 1.0 0.97 01/02/19 13:10 Styrene ug/L ND 1.0 0.26 01/02/19 13:10 Tetrachloroethene ug/L ND 1.0 0.46 01/02/19 13:10 Toluene ug/L ND 1.0 0.26 01/02/19 13:10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 METHOD BLANK: 2464415 Matrix: Water Associated Lab Samples: 92412408001, 92412408005, 92412408006, 92412408007, 92412408008, 92412408010, 92412408034, 92412408035 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.49 01/02/19 13:10 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 01/02/19 13:10 trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 01/02/19 13:10 Trichloroethene ug/L ND 1.0 0.47 01/02/19 13:10 Trichlorofluoromethane ug/L ND 1.0 0.20 01/02/19 13:10 Vinyl acetate ug/L ND 2.0 0.35 01/02/19 13:10 Vinyl chloride ug/L ND 1.0 0.62 01/02/19 13:10 Xylene (Total) ug/L ND 1.0 0.66 01/02/19 13:10 1,2-Dichloroethane-d4 (S) % 103 70-130 01/02/19 13:10 4-Bromofluorobenzene (S) % 95 70-130 01/02/19 13:10 Toluene-d8 (S) % 98 70-130 01/02/19 13:10 LABORATORY CONTROL SAMPLE: 2464416 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.0 96 70-130 1,1,1-Trichloroethane ug/L 50 52.2 104 70-130 1,1,2,2-Tetrachloroethane ug/L 50 46.6 93 70-130 1,1,2-Trichloroethane ug/L 50 51.8 104 70-130 1,1-Dichloroethane ug/L 50 51.9 104 70-130 1,1-Dichloroethene ug/L 50 57.5 115 70-130 1,2,3-Trichloropropane ug/L 50 49.3 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 47.0 94 70-130 1,2-Dibromoethane (EDB) ug/L 50 49.7 99 70-130 1,2-Dichlorobenzene ug/L 50 48.7 97 70-130 1,2-Dichloroethane ug/L 50 52.7 105 70-130 1,2-Dichloropropane ug/L 50 49.0 98 70-130 1,4-Dichlorobenzene ug/L 50 48.0 96 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1080 108 59-169 2-Butanone (MEK) ug/L 100 107 107 64-135 2-Hexanone ug/L 100 96.3 96 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 101 101 70-130 Acetone ug/L 100 107 107 61-157 Acrylonitrile ug/L 250 257 103 61-143 Benzene ug/L 50 50.3 101 70-130 Bromochloromethane ug/L 50 55.4 111 70-130 Bromodichloromethane ug/L 50 50.0 100 70-130 Bromoform ug/L 50 41.2 82 70-130 Bromomethane ug/L 50 44.1 88 38-130 Carbon disulfide ug/L 50 53.5 107 68-130 Carbon tetrachloride ug/L 50 50.5 101 70-130 Chlorobenzene ug/L 50 47.1 94 70-130 Chloroethane ug/L 50 43.4 87 37-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 LABORATORY CONTROL SAMPLE: 2464416 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloroform ug/L 50 51.8 104 70-130 Chloromethane ug/L 50 40.1 80 48-130 cis-1,2-Dichloroethene ug/L 50 53.6 107 70-130 cis-1,3-Dichloropropene ug/L 50 50.7 101 70-130 Dibromochloromethane ug/L 50 47.5 95 70-130 Dibromomethane ug/L 50 47.0 94 70-130 Ethylbenzene ug/L 50 47.4 95 70-130 lodomethane ug/L 100 109 109 40-130 Methylene Chloride ug/L 50 49.7 99 67-132 Styrene ug/L 50 47.2 94 70-130 Tetrachloroethene ug/L 50 46.4 93 69-130 Toluene ug/L 50 48.5 97 70-130 trans-1,2-Dichloroethene ug/L 50 53.9 108 70-130 trans- 1,3-Dichloropropene ug/L 50 50.8 102 70-130 trans-1,4-Dichloro-2-butene ug/L 50 51.0 102 35-189 Trichloroethene ug/L 50 50.4 101 70-130 Trichlorofluoromethane ug/L 50 51.9 104 63-130 Vinyl acetate ug/L 100 106 106 55-143 Vinyl chloride ug/L 50 56.6 113 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 106 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE SAMPLE: 2464418 92412408010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 18.2 91 73-134 1,1,1-Trichloroethane ug/L ND 20 20.2 101 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 17.8 89 70-136 1,1,2-Trichloroethane ug/L ND 20 19.7 99 70-135 1,1-Dichloroethane ug/L ND 20 21.0 105 70-139 1,1-Dichloroethene ug/L ND 20 22.5 113 70-154 1,2,3-Trichloropropane ug/L ND 20 22.0 110 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 16.7 83 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 19.2 96 70-137 1,2-Dichlorobenzene ug/L ND 20 18.5 92 70-133 1,2-Dichloroethane ug/L ND 20 19.8 99 70-137 1,2-Dichloropropene ug/L ND 20 19.8 99 70-140 1,4-Dichlorobenzene ug/L ND 20 21.6 108 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 414 103 53-168 2-Butanone (MEK) ug/L ND 40 43.1 108 60-139 2-Hexanone ug/L ND 40 36.4 91 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 38.2 96 65-135 Acetone ug/L ND 40 47.7 119 60-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 MATRIX SPIKE SAMPLE: Parameter 2464418 Units 92412408010 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Acrylonitrile ug/L ND 100 93.8 94 64-147 Benzene ug/L 0.81 J 20 20.8 100 70-151 Bromochloromethane ug/L ND 20 22.8 114 70-141 Bromodichloromethane ug/L ND 20 18.9 94 70-138 Bromoform ug/L ND 20 13.5 68 63-130 Bromomethane ug/L ND 20 15.4 77 15-152 Carbon disulfide ug/L ND 20 20.6 103 69-149 Carbon tetrachloride ug/L ND 20 19.9 99 70-143 Chlorobenzene ug/L ND 20 19.0 95 70-138 Chloroethane ug/L ND 20 17.6 88 52-163 Chloroform ug/L ND 20 19.4 97 70-139 Chloromethane ug/L ND 20 15.7 79 41-139 cis-1,2-Dichloroethene ug/L 0.84J 20 21.1 101 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.1 95 70-137 Dibromochloromethane ug/L ND 20 16.3 82 70-134 Dibromomethane ug/L ND 20 19.2 96 70-138 Ethylbenzene ug/L ND 20 19.1 95 66-153 lodomethane ug/L ND 40 33.6 84 20-138 Methylene Chloride ug/L ND 20 18.2 91 42-159 Styrene ug/L ND 20 18.4 92 70-135 Tetrachloroethene ug/L ND 20 18.7 94 59-143 Toluene ug/L ND 20 19.3 97 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.4 102 70-146 trans- 1,3-Dichloropropene ug/L ND 20 17.8 89 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 12.5 62 47-135 Trichloroethene ug/L ND 20 20.3 102 70-147 Trichlorofluoromethane ug/L ND 20 21.5 108 70-148 Vinyl acetate ug/L ND 40 32.4 81 49-151 Vinyl chloride ug/L ND 20 22.2 111 70-156 Xylene (Total) ug/L ND 60 57.4 96 63-158 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2464417 92412399001 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 SAMPLE DUPLICATE: 2464417 Parameter Units 92412399001 Result Dup Result 1,2-Dibromoethane (EDB) ug/L ND ND 1,2-Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 1,4-Dioxane (p-Dioxane) ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 110 108 4-Bromofluorobenzene (S) % 99 98 Toluene-d8(S) % 102 101 Max RPD RPD Qualifiers 2 1 1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450400 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92412408011,92412408012,92412408013,92412408028,92412408029,92412408030,92412408031, 92412408032,92412408033,92412408036 METHOD BLANK: 2464426 Matrix: Water Associated Lab Samples: 92412408011,92412408012,92412408013,92412408028,92412408029,92412408030,92412408031, 92412408032,92412408033,92412408036 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 01/02/19 13:27 1,1,1-Trichloroethane ug/L ND 1.0 0.48 01/02/19 13:27 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 01/02/19 13:27 1,1,2-Trichloroethane ug/L ND 1.0 0.29 01/02/19 13:27 1,1-Dichloroethane ug/L ND 1.0 0.32 01/02/19 13:27 1,1-Dichloroethene ug/L ND 1.0 0.56 01/02/19 13:27 1,2,3-Trichloropropane ug/L ND 1.0 0.41 01/02/19 13:27 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 01/02/19 13:27 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 01/02/19 13:27 1,2-Dichlorobenzene ug/L ND 1.0 0.30 01/02/19 13:27 1,2-Dichloroethane ug/L ND 1.0 0.24 01/02/19 13:27 1,2-Dichloropropane ug/L ND 1.0 0.27 01/02/19 13:27 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/02/19 13:27 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 01/02/19 13:27 2-Butanone (MEK) ug/L ND 5.0 0.96 01/02/19 13:27 2-Hexanone ug/L ND 5.0 0.46 01/02/19 13:27 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 01/02/19 13:27 Acetone ug/L ND 25.0 10.0 01/02/19 13:27 Acrylonitrile ug/L ND 10.0 1.9 01/02/19 13:27 Benzene ug/L ND 1.0 0.25 01/02/19 13:27 Bromochloromethane ug/L ND 1.0 0.17 01/02/19 13:27 Bromodichloromethane ug/L ND 1.0 0.18 01/02/19 13:27 Bromoform ug/L ND 1.0 0.26 01/02/19 13:27 Bromomethane ug/L ND 2.0 0.29 01/02/19 13:27 Carbon disulfide ug/L ND 2.0 1.2 01/02/19 13:27 Carbon tetrachloride ug/L ND 1.0 0.25 01/02/19 13:27 Chlorobenzene ug/L ND 1.0 0.23 01/02/19 13:27 Chloroethane ug/L ND 1.0 0.54 01/02/19 13:27 Chloroform ug/L ND 1.0 0.14 01/02/19 13:27 Chloromethane ug/L ND 1.0 0.11 01/02/19 13:27 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 01/02/19 13:27 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 01/02/19 13:27 Dibromochloromethane ug/L ND 1.0 0.21 01/02/19 13:27 Dibromomethane ug/L ND 1.0 0.21 01/02/19 13:27 Ethylbenzene ug/L ND 1.0 0.30 01/02/19 13:27 lodomethane ug/L ND 5.0 0.32 01/02/19 13:27 Methylene Chloride ug/L ND 1.0 0.97 01/02/19 13:27 Styrene ug/L ND 1.0 0.26 01/02/19 13:27 Tetrachloroethene ug/L ND 1.0 0.46 01/02/19 13:27 Toluene ug/L ND 1.0 0.26 01/02/19 13:27 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 METHOD BLANK: 2464426 Matrix: Water Associated Lab Samples: 92412408011,92412408012,92412408013,92412408028,92412408029,92412408030,92412408031, 92412408032,92412408033,92412408036 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.49 01/02/19 13:27 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 01/02/19 13:27 trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 01/02/19 13:27 Trichloroethene ug/L ND 1.0 0.47 01/02/19 13:27 Trichlorofluoromethane ug/L ND 1.0 0.20 01/02/19 13:27 Vinyl acetate ug/L ND 2.0 0.35 01/02/19 13:27 Vinyl chloride ug/L ND 1.0 0.62 01/02/19 13:27 Xylene (Total) ug/L ND 1.0 0.66 01/02/19 13:27 1,2-Dichloroethane-d4 (S) % 105 70-130 01/02/19 13:27 4-Bromofluorobenzene (S) % 99 70-130 01/02/19 13:27 Toluene-d8 (S) % 96 70-130 01/02/19 13:27 LABORATORY CONTROL SAMPLE: 2464427 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.5 95 70-130 1,1,1-Trichloroethane ug/L 50 53.9 108 70-130 1,1,2,2-Tetrachloroethane ug/L 50 46.4 93 70-130 1,1,2-Trichloroethane ug/L 50 52.1 104 70-130 1,1-Dichloroethane ug/L 50 53.0 106 70-130 1,1-Dichloroethene ug/L 50 57.9 116 70-130 1,2,3-Trichloropropane ug/L 50 50.5 101 70-130 1,2-Dibromo-3-chloropropane ug/L 50 46.6 93 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.2 102 70-130 1,2-Dichlorobenzene ug/L 50 49.2 98 70-130 1,2-Dichloroethane ug/L 50 54.1 108 70-130 1,2-Dichloropropane ug/L 50 50.8 102 70-130 1,4-Dichlorobenzene ug/L 50 49.1 98 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1100 110 59-169 2-Butanone (MEK) ug/L 100 110 110 64-135 2-Hexanone ug/L 100 95.8 96 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 105 105 70-130 Acetone ug/L 100 111 111 61-157 Acrylonitrile ug/L 250 260 104 61-143 Benzene ug/L 50 52.3 105 70-130 Bromochloromethane ug/L 50 56.0 112 70-130 Bromodichloromethane ug/L 50 50.5 101 70-130 Bromoform ug/L 50 41.3 83 70-130 Bromomethane ug/L 50 46.0 92 38-130 Carbon disulfide ug/L 50 54.8 110 68-130 Carbon tetrachloride ug/L 50 53.3 107 70-130 Chlorobenzene ug/L 50 47.7 95 70-130 Chloroethane ug/L 50 43.6 87 37-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 LABORATORY CONTROL SAMPLE: 2464427 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloroform ug/L 50 51.8 104 70-130 Chloromethane ug/L 50 40.0 80 48-130 cis-1,2-Dichloroethene ug/L 50 53.8 108 70-130 cis-1,3-Dichloropropene ug/L 50 52.7 105 70-130 Dibromochloromethane ug/L 50 47.3 95 70-130 Dibromomethane ug/L 50 47.9 96 70-130 Ethylbenzene ug/L 50 47.7 95 70-130 lodomethane ug/L 100 114 114 40-130 Methylene Chloride ug/L 50 51.7 103 67-132 Styrene ug/L 50 46.3 93 70-130 Tetrachloroethene ug/L 50 47.8 96 69-130 Toluene ug/L 50 50.1 100 70-130 trans-1,2-Dichloroethene ug/L 50 56.0 112 70-130 trans- 1,3-Dichloropropene ug/L 50 51.9 104 70-130 trans-1,4-Dichloro-2-butene ug/L 50 49.6 99 35-189 Trichloroethene ug/L 50 51.9 104 70-130 Trichlorofluoromethane ug/L 50 53.3 107 63-130 Vinyl acetate ug/L 100 107 107 55-143 Vinyl chloride ug/L 50 58.0 116 70-131 Xylene (Total) ug/L 150 145 96 70-130 1,2-Dichloroethane-d4 (S) % 105 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE SAMPLE: 2464429 92412408033 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.9 104 73-134 1,1,1-Trichloroethane ug/L ND 20 25.0 125 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 22.1 110 70-136 1,1,2-Trichloroethane ug/L ND 20 25.7 129 70-135 1,1-Dichloroethane ug/L ND 20 25.5 127 70-139 1,1-Dichloroethene ug/L ND 20 27.3 137 70-154 1,2,3-Trichloropropane ug/L ND 20 22.8 114 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 21.2 106 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 23.3 116 70-137 1,2-Dichlorobenzene ug/L ND 20 22.6 113 70-133 1,2-Dichloroethane ug/L ND 20 24.9 125 70-137 1,2-Dichloropropene ug/L ND 20 24.1 120 70-140 1,4-Dichlorobenzene ug/L ND 20 22.1 111 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 504 126 53-168 2-Butanone (MEK) ug/L ND 40 53.9 135 60-139 2-Hexanone ug/L ND 40 45.8 114 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 48.8 122 65-135 Acetone ug/L ND 40 53.0 132 60-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 MATRIX SPIKE SAMPLE: Parameter 2464429 Units 92412408033 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Acrylonitrile ug/L ND 100 122 122 64-147 Benzene ug/L ND 20 24.9 124 70-151 Bromochloromethane ug/L ND 20 27.0 135 70-141 Bromodichloromethane ug/L ND 20 22.9 115 70-138 Bromoform ug/L ND 20 16.8 84 63-130 Bromomethane ug/L ND 20 20.9 104 15-152 Carbon disulfide ug/L ND 20 24.6 123 69-149 Carbon tetrachloride ug/L ND 20 24.7 124 70-143 Chlorobenzene ug/L ND 20 22.6 113 70-138 Chloroethane ug/L ND 20 20.7 103 52-163 Chloroform ug/L ND 20 24.9 125 70-139 Chloromethane ug/L ND 20 18.7 94 41-139 cis-1,2-Dichloroethene ug/L ND 20 25.9 130 70-141 cis-1,3-Dichloropropene ug/L ND 20 24.5 123 70-137 Dibromochloromethane ug/L ND 20 20.3 102 70-134 Dibromomethane ug/L ND 20 24.3 121 70-138 Ethylbenzene ug/L ND 20 22.6 113 66-153 lodomethane ug/L ND 40 49.7 124 20-138 Methylene Chloride ug/L ND 20 22.4 112 42-159 Styrene ug/L ND 20 21.9 110 70-135 Tetrachloroethene ug/L ND 20 22.1 111 59-143 Toluene ug/L ND 20 23.2 116 59-148 trans-1,2-Dichloroethene ug/L ND 20 26.4 132 70-146 trans- 1,3-Dichloropropene ug/L ND 20 23.8 119 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 16.3 82 47-135 Trichloroethene ug/L ND 20 24.3 121 70-147 Trichlorofluoromethane ug/L ND 20 27.0 135 70-148 Vinyl acetate ug/L ND 40 41.5 104 49-151 Vinyl chloride ug/L ND 20 28.0 140 70-156 Xylene (Total) ug/L ND 60 68.1 114 63-158 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 102 70-130 SAMPLE DUPLICATE: 2464428 92412408032 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 SAMPLE DUPLICATE: 2464428 Parameter Units 92412408032 Result Dup Result 1,2-Dibromoethane (EDB) ug/L ND ND 1,2-Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 1,4-Dioxane (p-Dioxane) ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L 0.811 0.80J cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 100 103 4-Bromofluorobenzene (S) % 99 100 Toluene-d8(S) % 103 99 Max RPD RPD Qualifiers 3 1 4 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450401 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92412408002,92412408003,92412408004,92412408009,92412408014,92412408015,92412408016, 92412408017,92412408018,92412408019,92412408020,92412408021,92412408022,92412408023, 92412408024,92412408025,92412408026,92412408027,92412408037,92412408038 METHOD BLANK: 2464430 Matrix: Water Associated Lab Samples: 92412408002,92412408003,92412408004,92412408009,92412408014,92412408015,92412408016, 92412408017,92412408018,92412408019,92412408020,92412408021,92412408022,92412408023, 92412408024,92412408025,92412408026,92412408027,92412408037,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 01/03/19 01:26 1,1,1-Trichloroethane ug/L ND 1.0 0.48 01/03/19 01:26 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 01/03/19 01:26 1,1,2-Trichloroethane ug/L ND 1.0 0.29 01/03/19 01:26 1,1-Dichloroethane ug/L ND 1.0 0.32 01/03/19 01:26 1,1-Dichloroethene ug/L ND 1.0 0.56 01/03/19 01:26 1,2,3-Trichloropropane ug/L ND 1.0 0.41 01/03/19 01:26 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 01/03/19 01:26 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 01/03/19 01:26 1,2-Dichlorobenzene ug/L ND 1.0 0.30 01/03/19 01:26 1,2-Dichloroethane ug/L ND 1.0 0.24 01/03/19 01:26 1,2-Dichloropropane ug/L ND 1.0 0.27 01/03/19 01:26 1,4-Dichlorobenzene ug/L ND 1.0 0.33 01/03/19 01:26 1,4-Dioxane (p-Dioxane) ug/L ND 150 78.4 01/03/19 01:26 2-Butanone (MEK) ug/L ND 5.0 0.96 01/03/19 01:26 2-Hexanone ug/L ND 5.0 0.46 01/03/19 01:26 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 01/03/19 01:26 Acetone ug/L ND 25.0 10.0 01/03/19 01:26 Acrylonitrile ug/L ND 10.0 1.9 01/03/19 01:26 Benzene ug/L ND 1.0 0.25 01/03/19 01:26 Bromochloromethane ug/L ND 1.0 0.17 01/03/19 01:26 Bromodichloromethane ug/L ND 1.0 0.18 01/03/19 01:26 Bromoform ug/L ND 1.0 0.26 01/03/19 01:26 Bromomethane ug/L ND 2.0 0.29 01/03/19 01:26 Carbon disulfide ug/L ND 2.0 1.2 01/03/19 01:26 Carbon tetrachloride ug/L ND 1.0 0.25 01/03/19 01:26 Chlorobenzene ug/L ND 1.0 0.23 01/03/19 01:26 Chloroethane ug/L ND 1.0 0.54 01/03/19 01:26 Chloroform ug/L ND 1.0 0.14 01/03/19 01:26 Chloromethane ug/L ND 1.0 0.11 01/03/19 01:26 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 01/03/19 01:26 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 01/03/19 01:26 Dibromochloromethane ug/L ND 1.0 0.21 01/03/19 01:26 Dibromomethane ug/L ND 1.0 0.21 01/03/19 01:26 Ethylbenzene ug/L ND 1.0 0.30 01/03/19 01:26 lodomethane ug/L ND 5.0 0.32 01/03/19 01:26 Methylene Chloride ug/L ND 1.0 0.97 01/03/19 01:26 Styrene ug/L ND 1.0 0.26 01/03/19 01:26 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 METHOD BLANK: 2464430 Matrix: Water Associated Lab Samples: 92412408002,92412408003,92412408004,92412408009,92412408014,92412408015,92412408016, 92412408017,92412408018,92412408019,92412408020,92412408021,92412408022,92412408023, 92412408024,92412408025,92412408026,92412408027,92412408037,92412408038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.46 01/03/19 01:26 Toluene ug/L ND 1.0 0.26 01/03/19 01:26 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 01/03/19 01:26 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 01/03/19 01:26 trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 01/03/19 01:26 Trichloroethene ug/L ND 1.0 0.47 01/03/19 01:26 Trichlorofluoromethane ug/L ND 1.0 0.20 01/03/19 01:26 Vinyl acetate ug/L ND 2.0 0.35 01/03/19 01:26 Vinyl chloride ug/L ND 1.0 0.62 01/03/19 01:26 Xylene (Total) ug/L ND 1.0 0.66 01/03/19 01:26 1,2-Dichloroethane-d4 (S) % 100 70-130 01/03/19 01:26 4-Bromofluorobenzene (S) % 101 70-130 01/03/19 01:26 Toluene-d8 (S) % 98 70-130 01/03/19 01:26 LABORATORY CONTROL SAMPLE: 2464431 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 47.1 94 70-130 1,1,1-Trichloroethane ug/L 50 51.3 103 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.3 97 70-130 1,1,2-Trichloroethane ug/L 50 55.2 110 70-130 1,1-Dichloroethane ug/L 50 49.8 100 70-130 1,1-Dichloroethene ug/L 50 54.7 109 70-130 1,2,3-Trichloropropane ug/L 50 63.8 128 70-130 1,2-Dibromo-3-chloropropane ug/L 50 48.0 96 70-130 1,2-Dibromoethane (EDB) ug/L 50 52.1 104 70-130 1,2-Dichlorobenzene ug/L 50 50.6 101 70-130 1,2-Dichloroethane ug/L 50 52.9 106 70-130 1,2-Dichloropropane ug/L 50 50.8 102 70-130 1,4-Dichlorobenzene ug/L 50 49.8 100 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1100 110 59-169 2-Butanone (MEK) ug/L 100 106 106 64-135 2-Hexanone ug/L 100 97.6 98 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 70-130 Acetone ug/L 100 107 107 61-157 Acrylonitrile ug/L 250 244 97 61-143 Benzene ug/L 50 51.6 103 70-130 Bromochloromethane ug/L 50 54.7 109 70-130 Bromodichloromethane ug/L 50 49.5 99 70-130 Bromoform ug/L 50 40.2 80 70-130 Bromomethane ug/L 50 41.3 83 38-130 Carbon disulfide ug/L 50 48.1 96 68-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 115 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 LABORATORY CONTROL SAMPLE: Parameter 2464431 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Carbon tetrachloride ug/L 50 50.8 102 70-130 Chlorobenzene ug/L 50 49.7 99 70-130 Chloroethane ug/L 50 41.3 83 37-142 Chloroform ug/L 50 50.7 101 70-130 Chloromethane ug/L 50 33.1 66 48-130 cis-1,2-Dichloroethene ug/L 50 52.8 106 70-130 cis-1,3-Dichloropropene ug/L 50 52.3 105 70-130 Dibromochloromethane ug/L 50 47.0 94 70-130 Dibromomethane ug/L 50 52.4 105 70-130 Ethylbenzene ug/L 50 49.3 99 70-130 lodomethane ug/L 100 106 106 40-130 Methylene Chloride ug/L 50 49.7 99 67-132 Styrene ug/L 50 48.5 97 70-130 Tetrachloroethene ug/L 50 48.1 96 69-130 Toluene ug/L 50 50.6 101 70-130 trans-1,2-Dichloroethene ug/L 50 52.5 105 70-130 trans- 1,3-Dichloropropene ug/L 50 51.0 102 70-130 trans-1,4-Dichloro-2-butene ug/L 50 43.0 86 35-189 Trichloroethene ug/L 50 53.2 106 70-130 Trichlorofluoromethane ug/L 50 49.3 99 63-130 Vinyl acetate ug/L 100 105 105 55-143 Vinyl chloride ug/L 50 50.6 101 70-131 Xylene (Total) ug/L 150 147 98 70-130 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE SAMPLE: Parameter 2464433 Units 92412408037 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.9 104 73-134 1,1,1-Trichloroethane ug/L ND 20 23.3 116 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.3 106 70-136 1,1,2-Trichloroethane ug/L ND 20 22.6 113 70-135 1,1-Dichloroethane ug/L 1.1 20 24.4 116 70-139 1,1-Dichloroethene ug/L ND 20 25.2 126 70-154 1,2,3-Trichloropropane ug/L ND 20 22.9 115 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 22.3 112 70-137 1,2-Dichlorobenzene ug/L ND 20 21.3 107 70-133 1,2-Dichloroethane ug/L 0.27J 20 22.9 113 70-137 1,2-Dichloropropane ug/L ND 20 22.1 111 70-140 1,4-Dichlorobenzene ug/L ND 20 22.1 110 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 495 124 53-168 2-Butanone (MEK) ug/L ND 40 47.3 118 60-139 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 116 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 MATRIX SPIKE SAMPLE: Parameter 2464433 Units 92412408037 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 2-Hexanone ug/L ND 40 44.5 111 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 44.1 110 65-135 Acetone ug/L ND 40 59.3 148 60-148 Acrylonitrile ug/L ND 100 110 110 64-147 Benzene ug/L 2.7 20 25.1 112 70-151 Bromochloromethane ug/L ND 20 24.9 124 70-141 Bromodichloromethane ug/L ND 20 20.7 104 70-138 Bromoform ug/L ND 20 16.6 83 63-130 Bromomethane ug/L ND 20 18.1 90 15-152 Carbon disulfide ug/L ND 20 21.7 108 69-149 Carbon tetrachloride ug/L ND 20 22.0 110 70-143 Chlorobenzene ug/L ND 20 23.2 116 70-138 Chloroethane ug/L ND 20 21.7 108 52-163 Chloroform ug/L ND 20 21.9 110 70-139 Chloromethane ug/L ND 20 17.3 86 41-139 cis-1,2-Dichloroethene ug/L 5.7 20 30.0 121 70-141 cis-1,3-Dichloropropene ug/L ND 20 21.5 108 70-137 Dibromochloromethane ug/L ND 20 19.3 96 70-134 Dibromomethane ug/L ND 20 21.7 108 70-138 Ethylbenzene ug/L ND 20 22.0 110 66-153 lodomethane ug/L ND 40 41.6 104 20-138 Methylene Chloride ug/L ND 20 19.2 96 42-159 Styrene ug/L ND 20 21.9 109 70-135 Tetrachloroethene ug/L ND 20 21.5 108 59-143 Toluene ug/L ND 20 21.4 107 59-148 trans-1,2-Dichloroethene ug/L ND 20 23.3 116 70-146 trans- 1,3-Dichloropropene ug/L ND 20 21.0 105 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 15.8 79 47-135 Trichloroethene ug/L ND 20 22.4 112 70-147 Trichlorofluoromethane ug/L ND 20 24.9 125 70-148 Vinyl acetate ug/L ND 40 30.1 75 49-151 Vinyl chloride ug/L ND 20 25.1 126 70-156 Xylene (Total) ug/L ND 60 66.4 111 63-158 1,2-Dichloroethane-d4 (S) % 97 70-130 4-Bromofluorobenzene (S) % 105 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2464432 Parameter Units 1,1,1,2-Tetrachloroethane ug/L 1,1,1-Trichloroethane ug/L 1,1,2,2-Tetrachloroethane ug/L 1,1,2-Trichloroethane ug/L 1,1-Dichloroethane ug/L 92412408038 Dup Max Result Result RPD RPD Qualifiers ND ND 30 ND ND 30 ND ND 30 ND ND 30 ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 117 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 SAMPLE DUPLICATE: 2464432 Parameter Units 92412408038 Result Dup Result 1,1-Dichloroethene ug/L ND ND 1,2,3-Trichloropropane ug/L ND ND 1,2-Dibromo-3-chloropropane ug/L ND ND 1,2-Dibromoethane (EDB) ug/L ND ND 1,2-Dichlorobenzene ug/L ND ND 1,2-Dichloroethane ug/L ND ND 1,2-Dichloropropane ug/L ND ND 1,4-Dichlorobenzene ug/L ND ND 1,4-Dioxane (p-Dioxane) ug/L ND ND 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND ND Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 100 99 4-Bromofluorobenzene (S) % 100 99 Toluene-d8(S) % 100 96 Max RPD RPD Qualifiers 1 2 4 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 118 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450314 Analysis Method: EPA 180.1 Rev 2.0 1993 QC Batch Method: EPA 180.1 Rev 2.0 1993 Analysis Description: 180.1 Turbidity Associated Lab Samples: 92412408005, 92412408006 METHOD BLANK: 2464056 Matrix: Water Associated Lab Samples: 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Turbidity NTU ND 1.0 0.50 12/31/1819:47 LABORATORY CONTROL SAMPLE: 2464057 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Turbidity NTU 10 10 100 90-110 SAMPLE DUPLICATE: 2464058 92412408005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Turbidity NTU 78.6 75.8 4 10 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 119 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450108 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Associated Lab Samples: 92412408001 METHOD BLANK: 2463367 Matrix: Water Associated Lab Samples: 92412408001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 1000 12/29/18 00:31 LABORATORY CONTROL SAMPLE: 2463368 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 51800 104 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463369 2463370 MS MSD 92412408001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 261000 50000 50000 314000 303000 106 85 80-120 3 25 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 120 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450252 Analysis Method: SM 2320B-2011 QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity Associated Lab Samples: 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2463872 Matrix: Water Associated Lab Samples: 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 5000 1000 12/31/18 19:07 LABORATORY CONTROL SAMPLE: 2463873 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 50000 49900 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463874 2463875 MS MSD 92412329007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 ug/L 75.1 mg/L 50000 50000 110000 120000 69 90 80-120 9 25 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 121 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 451837 Analysis Method: SM 3500-Fe B-2011 QC Batch Method: SM 3500-Fe B-2011 Analysis Description: Iron, Ferrous Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2470666 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Iron, Ferrous mg/L ND 0.50 0.50 01/13/19 19:07 N2 LABORATORY CONTROL SAMPLE: 2470667 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Iron, Ferrous mg/L 1.5 1.5 102 90-110 N2 SAMPLE DUPLICATE: 2470668 92412408005 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L 10.3 11.7 12 10 D6,H3,N2 SAMPLE DUPLICATE: 2470669 92412408006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Iron, Ferrous mg/L ND ND 10 H3,N2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 122 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450275 Analysis Method: SM 4500-S2D-2011 QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2463973 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 100 50.0 12/31/1815:25 LABORATORY CONTROL SAMPLE: 2463974 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 490 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463975 2463976 MS MSD 92412407010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L 1.6 mg/L 500 500 2320 2380 137 151 80-120 3 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463977 2463978 MS MSD 92412408002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 336 350 67 70 80-120 4 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450169 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92412408005, 92412408006 METHOD BLANK: 2463562 Matrix: Water Associated Lab Samples: 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 12/29/18 23:34 LABORATORY CONTROL SAMPLE: 2463563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 52900 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463564 2463565 MS MSD 92412266004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 21.7 mg/L 50000 50000 74700 75000 106 107 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 124 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450324 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004 METHOD BLANK: 2464069 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 01/02/19 09:33 LABORATORY CONTROL SAMPLE: 2464070 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 50700 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2464071 2464072 MS MSD 92412408001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 896J 50000 50000 45800 61200 90 121 90-110 29 10 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 125 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450110 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2463373 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 20.0 10.0 12/28/18 23:28 LABORATORY CONTROL SAMPLE: 2463374 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1410 94 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463375 2463376 MS MSD 92412408005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L 304 1500 1500 1860 1790 104 99 90-110 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 126 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450213 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2463701 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 500 12/31/1817:07 LABORATORY CONTROL SAMPLE: 2463702 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 20000 20000 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463703 2463704 MS MSD 92412266001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 7.0 mg/L 10000 10000 16500 16400 95 94 90-110 1 10 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2463898 2463899 MS MSD 92412369002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 71.5 mg/L 10000 10000 78300 86200 67 146 90-110 10 10 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 127 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450899 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2466653 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 01/08/19 00:54 LABORATORY CONTROL SAMPLE: 2466654 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 786000 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2466655 2466656 MS MSD 92412408001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 90200 100000 100000 203000 208000 113 118 90-110 3 3 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2466659 2466660 MS MSD 92412554001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 100000 100000 118000 101000 118 101 90-110 15 3 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 128 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWS Pace Project No.: 92412408 QC Batch: 450352 Analysis Method: SM 531 OB-2011 QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 METHOD BLANK: 2464133 Matrix: Water Associated Lab Samples: 92412408001, 92412408002, 92412408003, 92412408004, 92412408005, 92412408006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Total Organic Carbon ug/L ND 1000 500 01/02/19 15:14 LABORATORY CONTROL SAMPLE: 2464134 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon ug/L 25000 23900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2464135 2464136 MS MSD 92412266001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Total Organic Carbon ug/L 2.4 mg/L 25000 25000 24100 24300 87 87 90-110 1 10 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 129 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Alexander LF-SWS Pace Project No.: 92412408 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. N2 The lab does not hold NELAC/TNI accreditation for this parameter. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 130 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Alexander LF-SWS 92412408 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92412408001 MW-11 RSK 175 Modified 450194 92412408002 MW-12 RSK 175 Modified 450194 92412408003 MW-12D RSK 175 Modified 450194 92412408004 MW-24 RSK 175 Modified 450194 92412408005 MW-26 RSK 175 Modified 450194 92412408006 MW-31 RSK 175 Modified 450214 92412408007 MW-5 RSK 175 Modified 450194 92412408008 MW-16 RSK 175 Modified 450194 92412408009 MW-25 RSK 175 Modified 450214 92412408010 MW-1 RSK 175 Modified 450194 92412408011 MW-1B RSK 175 Modified 450194 92412408012 MW-6 RSK 175 Modified 450194 92412408038 MW-18 RSK 175 Modified 450194 92412408001 MW-11 EPA 3010A 450126 EPA 6010D 450141 92412408002 MW-12 EPA 3010A 450126 EPA 6010D 450141 92412408003 MW-12D EPA 3010A 450126 EPA 6010D 450141 92412408004 MW-24 EPA 3010A 450126 EPA 6010D 450141 92412408005 MW-26 EPA 3010A 450126 EPA 6010D 450141 92412408006 MW-31 EPA 3010A 450126 EPA 6010D 450141 92412408007 MW-5 EPA 3010A 450126 EPA 6010D 450141 92412408008 MW-16 EPA 3010A 450126 EPA 6010D 450141 92412408009 MW-25 EPA 3010A 450126 EPA 6010D 450141 92412408010 MW-1 EPA 3010A 450127 EPA 6010D 450142 92412408011 MW-1 B EPA 3010A 450127 EPA 6010D 450142 92412408012 MW-6 EPA 3010A 450127 EPA 6010D 450142 92412408013 MW-17 EPA 3010A 450127 EPA 6010D 450142 92412408014 MW-2 EPA 3010A 450127 EPA 6010D 450142 92412408015 MW-4R EPA 3010A 450127 EPA 6010D 450142 92412408016 MW-9 EPA 3010A 450127 EPA 6010D 450142 92412408017 MW-10 EPA 3010A 450127 EPA 6010D 450142 92412408018 MW-13 EPA 3010A 450127 EPA 6010D 450142 92412408019 MW-14 EPA 3010A 450127 EPA 6010D 450142 92412408020 MW-15 EPA 3010A 450127 EPA 6010D 450142 92412408021 MW-19 EPA 3010A 450127 EPA 6010D 450142 92412408022 MW-21 EPA 3010A 450127 EPA 6010D 450142 92412408023 MW-22 EPA 3010A 450127 EPA 6010D 450142 92412408024 MW-23 EPA 3010A 450127 EPA 6010D 450142 92412408025 MW-20 EPA 3010A 450127 EPA 6010D 450142 92412408026 MW-27 EPA 3010A 450327 EPA 6010D 450329 92412408027 MW-32 EPA 3010A 450327 EPA 6010D 450329 92412408028 MW-33 EPA 3010A 450327 EPA 6010D 450329 92412408029 MW-34 EPA 3010A 450327 EPA 6010D 450329 92412408030 SW-3 EPA 3010A 450327 EPA 6010D 450329 92412408031 SW-4R EPA 3010A 450327 EPA 6010D 450329 92412408032 SW-5 EPA 3010A 450327 EPA 6010D 450329 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 131 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Alexander LF-SWS Pace Project No.: 92412408 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92412408033 SW-6 EPA 3010A 450327 EPA 6010D 450329 92412408034 EB EPA 3010A 450327 EPA 6010D 450329 92412408035 FB EPA 3010A 450327 EPA 6010D 450329 92412408036 MW-3 EPA 3010A 450327 EPA 6010D 450329 92412408037 MW-7 EPA 3010A 450327 EPA 6010D 450329 92412408038 MW-18 EPA 3010A 450327 EPA 6010D 450329 92412408001 MW-11 EPA 3010A 450131 EPA 6020B 450146 92412408002 MW-12 EPA 3010A 450131 EPA 6020B 450146 92412408003 MW-12D EPA 3010A 450131 EPA 6020B 450146 92412408004 MW-24 EPA 3010A 450131 EPA 6020B 450146 92412408005 MW-26 EPA 3010A 450131 EPA 6020B 450146 92412408006 MW-31 EPA 3010A 450131 EPA 6020B 450146 92412408007 MW-5 EPA 3010A 450131 EPA 6020B 450146 92412408008 MW-16 EPA 3010A 450131 EPA 6020B 450146 92412408009 MW-25 EPA 3010A 450131 EPA 6020B 450146 92412408010 MWA EPA 3010A 450131 EPA 6020B 450146 92412408011 MWA B EPA 3010A 450131 EPA 6020B 450146 92412408012 MW-6 EPA 3010A 450131 EPA 6020B 450146 92412408013 MW-17 EPA 3010A 450131 EPA 6020B 450146 92412408014 MW-2 EPA 3010A 450131 EPA 6020B 450146 92412408015 MW-4R EPA 3010A 450131 EPA 6020B 450146 92412408016 MW-9 EPA 3010A 450131 EPA 6020B 450146 92412408017 MW-10 EPA 3010A 450131 EPA 6020B 450146 92412408018 MW-13 EPA 3010A 450131 EPA 6020B 450146 92412408019 MW-14 EPA 3010A 450131 EPA 6020B 450146 92412408020 MW-15 EPA 3010A 450131 EPA 6020B 450146 92412408021 MW-19 EPA 3010A 450132 EPA 6020B 450147 92412408022 MW-21 EPA 3010A 450132 EPA 6020B 450147 92412408023 MW-22 EPA 3010A 450132 EPA 6020B 450147 92412408024 MW-23 EPA 3010A 450132 EPA 6020B 450147 92412408025 MW-20 EPA 3010A 450132 EPA 6020B 450147 92412408026 MW-27 EPA 3010A 450132 EPA 6020B 450147 92412408027 MW-32 EPA 3010A 450132 EPA 6020B 450147 92412408028 MW-33 EPA 3010A 450132 EPA 6020B 450147 92412408029 MW-34 EPA 3010A 450132 EPA 6020B 450147 92412408030 SW-3 EPA 3010A 450132 EPA 6020B 450147 92412408031 SW-4R EPA 3010A 450132 EPA 6020B 450147 92412408032 SW-5 EPA 3010A 450132 EPA 6020B 450147 92412408033 SW-6 EPA 3010A 450132 EPA 6020B 450147 92412408034 EB EPA 3010A 450132 EPA 6020B 450147 92412408035 FB EPA 3010A 450132 EPA 6020B 450147 92412408036 MW-3 EPA 3010A 450132 EPA 6020B 450147 92412408037 MW-7 EPA 3010A 450132 EPA 6020B 450147 92412408038 MW-18 EPA 3010A 450132 EPA 6020B 450147 92412408010 MWA EPA 7470A 450293 EPA 7470A 450310 92412408011 MWA B EPA 7470A 450293 EPA 7470A 450310 92412408012 MW-6 EPA 7470A 450293 EPA 7470A 450310 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 132 of 160 lacmnalytical' www.pacelabs.corn Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Alexander LF-SWS Pace Project No.: 92412408 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92412408013 MW-17 EPA 7470A 450293 EPA 7470A 450310 92412408014 MW-2 EPA 7470A 450293 EPA 7470A 450310 92412408020 MW-15 EPA 7470A 450293 EPA 7470A 450310 92412408021 MW-19 EPA 7470A 450293 EPA 7470A 450310 92412408022 MW-21 EPA 7470A 450293 EPA 7470A 450310 92412408034 EB EPA 7470A 450293 EPA 7470A 450310 92412408038 MW-18 EPA 7470A 450293 EPA 7470A 450310 92412408001 MW-11 EPA 8260B 450398 92412408002 MW-12 EPA 8260B 450401 92412408003 MW-12D EPA 8260B 450401 92412408004 MW-24 EPA 8260B 450401 92412408005 MW-26 EPA 8260B 450398 92412408006 MW-31 EPA 8260B 450398 92412408007 MW-5 EPA 8260B 450398 92412408008 MW-16 EPA 8260B 450398 92412408009 MW-25 EPA 8260B 450401 92412408010 MW-1 EPA 8260B 450398 92412408011 MW-1B EPA 8260B 450400 92412408012 MW-6 EPA 8260B 450400 92412408013 MW-17 EPA 8260B 450400 92412408014 MW-2 EPA 8260B 450401 92412408015 MW-4R EPA 8260B 450401 92412408016 MW-9 EPA 8260B 450401 92412408017 MW-10 EPA 8260B 450401 92412408018 MW-13 EPA 8260B 450401 92412408019 MW-14 EPA 8260B 450401 92412408020 MW-15 EPA 8260B 450401 92412408021 MW-19 EPA 8260B 450401 92412408022 MW-21 EPA 8260B 450401 92412408023 MW-22 EPA 8260B 450401 92412408024 MW-23 EPA 8260B 450401 92412408025 MW-20 EPA 8260B 450401 92412408026 MW-27 EPA 8260B 450401 92412408027 MW-32 EPA 8260B 450401 92412408028 MW-33 EPA 8260B 450400 92412408029 MW-34 EPA 8260B 450400 92412408030 SW-3 EPA 8260B 450400 92412408031 SW-4R EPA 8260B 450400 92412408032 SW-5 EPA 8260B 450400 92412408033 SW-6 EPA 8260B 450400 92412408034 EB EPA 8260B 450398 92412408035 FB EPA 8260B 450398 92412408036 MW-3 EPA 8260B 450400 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 133 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Alexander LF-SWS 92412408 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92412408037 MW-7 EPA 8260B 450401 92412408038 MW-18 EPA 8260B 450401 92412408005 MW-26 EPA 180.1 Rev 2.0 1993 450314 92412408006 MW-31 EPA 180.1 Rev 2.0 1993 450314 92412408001 MW-11 SM 2320B-2011 450108 92412408002 MW-12 SM 2320B-2011 450252 92412408003 MW-12D SM 2320B-2011 450252 92412408004 MW-24 SM 2320B-2011 450252 92412408005 MW-26 SM 2320B-2011 450252 92412408006 MW-31 SM 2320B-2011 450252 92412408001 MW-11 SM 3500-Fe B-2011 451837 92412408002 MW-12 SM 3500-Fe B-2011 451837 92412408003 MW-12D SM 3500-Fe B-2011 451837 92412408004 MW-24 SM 3500-Fe B-2011 451837 92412408005 MW-26 SM 3500-Fe B-2011 451837 92412408006 MW-31 SM 3500-Fe B-2011 451837 92412408001 MW-11 SM 4500-S2D-2011 450275 92412408002 MW-12 SM 4500-S2D-2011 450275 92412408003 MW-12D SM 4500-S2D-2011 450275 92412408004 MW-24 SM 4500-S2D-2011 450275 92412408005 MW-26 SM 4500-S2D-2011 450275 92412408006 MW-31 SM 4500-S2D-2011 450275 92412408001 MW-11 EPA 300.0 Rev 2.1 1993 450324 92412408002 MW-12 EPA 300.0 Rev 2.1 1993 450324 92412408003 MW-12D EPA 300.0 Rev 2.1 1993 450324 92412408004 MW-24 EPA 300.0 Rev 2.1 1993 450324 92412408005 MW-26 EPA 300.0 Rev 2.1 1993 450169 92412408006 MW-31 EPA 300.0 Rev 2.1 1993 450169 92412408001 MW-11 EPA 353.2 Rev 2.0 1993 450110 92412408002 MW-12 EPA 353.2 Rev 2.0 1993 450110 92412408003 MW-12D EPA 353.2 Rev 2.0 1993 450110 92412408004 MW-24 EPA 353.2 Rev 2.0 1993 450110 92412408005 MW-26 EPA 353.2 Rev 2.0 1993 450110 92412408006 MW-31 EPA 353.2 Rev 2.0 1993 450110 92412408001 MW-11 SM 4500-CI-E-2011 450213 92412408002 MW-12 SM 4500-CI-E-2011 450213 92412408003 MW-12D SM 4500-CI-E-2011 450213 92412408004 MW-24 SM 4500-CI-E-2011 450213 92412408005 MW-26 SM 4500-CI-E-2011 450213 92412408006 MW-31 SM 4500-CI-E-2011 450213 92412408001 MW-11 SM 5220D-2011 450899 SM 5220D-2011 451157 92412408002 MW-12 SM 5220D-2011 450899 SM 5220D-2011 451157 92412408003 MW-12D SM 5220D-2011 450899 SM 5220D-2011 451157 92412408004 MW-24 SM 5220D-2011 450899 SM 5220D-2011 451157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /14/2019 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 134 of 160 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Alexander LF-SWS Pace Project No.: 92412408 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92412408005 MW-26 SM 5220D-2011 450899 SM 5220D-2011 451157 92412408006 MW-31 SM 5220D-2011 450899 SM 5220D-2011 451157 92412408001 MW-11 SM 5310B-2011 450352 92412408002 MW-12 SM 5310B-2011 450352 92412408003 MW-12D SM 5310B-2011 450352 92412408004 MW-24 SM 5310B-2011 450352 92412408005 MW-26 SM 5310B-2011 450352 92412408006 MW-31 SM 5310B-2011 450352 Date: 01/14/2019 01:24 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 135 of 160 Document Name: Occurrent Revised: February7, 2018 Sample Condition Upon Receipt(SCUR) Page 1 of 2 ace Analytical Document No,: Issuing Authority: F-CAR-CS-033-Rev.06 Pace CaroltnasQualitY office Laboratory receiving samples: Asheville ❑ Eden[]Greenwood ❑ Huntersville Raleigh❑ Mechanicsville[] Sample Condition Client Name: WO# : 92412408 Upon Receipt Project #; �Ut�IJ� �` II`` dent d Ex UP USPS Courier: ❑F� ❑ ❑ ❑ Commercial ❑Pace ❑Other: 92412408 Custody Seal Present? []Yes No Seals Intact? [:]YesZr No Qalellnitlais Person Examining Contents; Packing Material: ❑Bubble Wrap Bubble Bags [-]None ❑ Other Biological Tissue F zen? []Yes []NO N/A Thermometer; O Type of Ice: wet ❑slue ❑None CI IR Gun iD: 92TO46 Cooler Temp ('C): r i Correction Factor; Add/Subtract I°C) �0,0 Temp should be above freezingto 6'C Cooler Temp Corrected ('C); []Samples out oftemperiteria. Samples on ice, cooling process has begun USDA Regulated Sail ( -N/A, water samp#e) Did samples a^iginat n-f'quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (InterIn 4+ including Hawaii and Puerto Rico)? ❑Yes ONO Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (42 hr,)? Rush Turn Around Time Requested? , es [a es Yes ❑Yes ❑Na ❑N/A En] No ❑NIA Elmo - ❑N/A No ❑N/A 1. 2, 3. 4. Sufficient Volume? ems ❑No ❑NIA 1 5, Correct Containers Used? OY s [:]No ❑NIA 6. -Pace Containers Used? LlYes " ❑No ❑NIA Containers Intact? I-ires ❑No []N/A_- ?. Dissolved analysis: Samples field Filtered? ❑Yes... ❑No ENIA 8, Sample Labels Match COC? Yes ❑No ❑N/A 9. -includes Date/Time/ID/Analysis Matrix: Head space in VOA Vials (>5-Gmml? []yes EJ'N ❑N/A 10. Trip Blank Present? []yes U No ❑N/A 11. Trip BlankCustodV Seals Present? ❑Yes ❑No ❑ILIA 1MENTS/SAMPLE DISCREPANCY Ll CLIENT NOTIFICATIONIRESOLUTION I -) � 1 Person Contacted: Project Manager SCURF Review: Project Manager SRF Review: 7 Lot ID of split Date/Time: Field Data Required? (—]Yes ❑No Date: 1L 31 f [_ Date: 1Lr Page 136 of 160 aceAnalyticala Document Name: Sample Condltton Upon Rec Document No.: *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Cvliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Document Revised: February 7, 2018 t{SCUR) Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office Project # IWO# y 92412408 PM: CRW Due Date: 01/14/19 CLIENT: 92—Municipal x « Z v Z U a E .Ni 4m Z v u .N 6 E N 7 dm 2 d 2 U ;; a E VI 7 a o a c 7 r `m r? 7LAULL7 6 mmw V V x O T ,� •N a E .N-1 V x 0 Z ¢ E N -6 ,Y�+ a N U •• E r1 to A x 0. Q Z U y = E rl as ¢ _ S.7 F E a 3� 3 2 w y 0. 7 a E 4 ;; ci a N V T EE d •i 2 aaa 1 v iv C 7 n E ¢ J E c N 7 V x G V O = A E 6 w rl N V g Q 0 IV 1V m a J E c3 N z n E Q o Ln d en � 2 u Y d 0 > E q j ? n N ry Z a O > a p v > Z C 7 a O > J E �0 I >0 a 2 qq O m 2 6 O > J E O Y d ' YI r,l x `u a i0 > v ,� > le le m T > « St m ¢ ,� > b z «u+ a °1 `a .n a E N ri i ? '-' N d c '^ .a E o N N w Qi g N ? U `° 6 J E o N a AG a H C W ¢ J E O a rl Q d C E o N ia120Q= > z 5 w ¢ C E J E d � G 1 2 ■ 0 NONE 0 IL40M -M MEN MEMNON 0 M 0 M ENO IN 0 0 0 0 11 MMM 11 ONE' ONE HEMOMMIS OMMEMOMMMEM pH Adjustment Log for Preserved Samples Sample ID Type ai Prese[vative pH upon recelpt Oate preservation adjusted Time preservation Amount of Preservative Lot ft adjus I added Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form Wil; he sent to the North Carolina DEHNS Certification Office (i.e. Out of hold, incorrecl preservative, out of temp, incorrect containers. Page 137 of 160 Sample acefttytical' Document Name: Document No.: AR-CS-033•Rev.06 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Colifarm, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle .I-) Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office Project 41WQ# : 924124Q8 im RWC Due Date: 01/14/19 CLIENT: 92—Municipal L� C 7 m v 'c O E 7 l7 3 Q i a 7 w 4 .{ N l7 d Ni S d �EE d ; r1 rxi l7 a 5 W z d a Q of N m l7 a N V y v 0 Y `m 4 ? rf ,�-i l7 a V x a O N a E N M l7 a = = Z a 0 N ran 0 m l7 a V 4 7 E � ozi l7 a ¢ m O N 2 O > £ `f m C7 7 ¢ z. C 6 O 7 E O Y ate+ t9 a 2 m 6 O 7 E O a a ut mo v1 " Y G m a Y a ] Q n s = �, } Y l7 7 'N N y .a �' EE l'n a Q Z .N a br N E o N r h� ^r vai IL r--5•r , Ol rn M S a J E N a m jp y fJ a a c 7 E a E a r1 o Q Z c 2 c U o N � 7 N N 2 d a E Q a a obi ani Z O v_ N E VI e4 7 E v r m Z N N m u v v v t 2 v x S a o 7 C y 7C U V D U V N R N ,6 E E y E E O O •_ <n N YI .-I N N � 7 7 rif 2 m ry a n m m m m m u H °� ^ Y n a N Z V •W 2 E E N N N U a a 'm m `J � 1 � 2 ✓ 3 7 7 i 3 4- 4 5 � 3 L 6 )/ 7 8 4 10 77 11 Y V--PH- iz\z,- PH Adjustment Log for Preserved Samples sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation AMDUntof Preservative lot a adjusted added Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina OENNN Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 138 of 160 Document Name: Document Revised: February 7, 2018 Sample Condltlon Upon Recelpt(SCUR) page 1 of 2 aeeAnalytical' Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Colirorm, TOC, oil and Grease, ORO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project 1' IW4# : 92412408 PM: RWC Due Date: 01/14/19 CLIENT: 92-Municipal it W 9 m d a e y E ,n 6 m v n e ? E o 6 m 9 m n c V E o 4 m Z v n 7 7 a m N v 0 ni E {h a m v D Z V E O Z d m Z v a Z u E N d w V a SO 1° Z U a. m j A u LL 3 Q ° � a E a = G7 a iv V n Y a = 0 a Z v 2 a c v 4 J of � V' a N v a O = E ¢ `m = l7 a _ V x N Q J a Erq N l7 a 2 7 z rM�e ran �7 L7 l7 a Z U J E va I l7 a>> a ? O 10 Z O J E?E} o q l7 Z 7 a O J 0 Y l7 � rq I 4 O J 0 6 01 a 2 '� N y a ry :° Y a } 1 l7 a �r °� �G y p Q .� J ;-i 0 b = z � n .` 'a 0 E a � \ ! V1 ri1 g N z E o n a CL m m 7 2 E E 0 N O q Z d o c ."' L c E J 0 0 N v 7 0 tv O 7 1 v l7j 2 3 v J U 1 7 J 4 5 6 UNMEMEMMEMEMEMEME MMMMMIMMMMMMMMMOMM 10 11 12 PH Adjustment Log for Preserved Samples Sample I❑ Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot k ad] I added Nate: Whenever therels a discrepancy affecting North Carolina compliance samples, a copy of this form wiii besentto the North Carolina 0FHNR Certification OfFce (Le, Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 139 of 160 Document Name: Sample Condition Upon Receli Document No.: F-CAR-CS-033-Rev.06 Document Revised: February 7, 2 Page 1 of 2 Issuing Authority, Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project WO# : 92412408 verif led and within the acceptance range for preservation samples, Ercceptians: VOA, Conform, TOC, Oil and Grease, DR0/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle PM: RWC Due Date: 01/14/19 CLIENT: 92—Municipal a 4Ei 4 d a�i m $ c 7 in E Yl H j oa. m a v a c 7 E O M a m W N d a c 7 E O o 7 a m N w a C `v — 7 ¢ m U v a v O S m E Lh a oo V a m O z Z rs E z a m O io Z N ro E N a Co U n 6 x p m Z n E u 0. m Z N d p v LL y y v ar c E rp1 H l7 4 V n u 2 a �° .yi l7 ¢ Z a 7 6 o m C7 ¢ V C v ry Z E r1 l7 4 2 V O v, i ¢ c Ln m l7 6 2 d n E 4 J E r`ni m m W ¢ ?, CJ x P E O A C7 G q V rn Ory '^ z O g p m > 6 �. a O % E O T lD 7 Z a s D % E O n a N m N x 6 i 4 7 C_7 x j w Y a a y V {�� ] S V w a v� J �EE rJ K 2 d `^ E p N vai VON7 a z p a o S m a�i c 3 E a E a 7 ¢ .n c 9 ro as 0 7 .d. a j a E ¢ E o 7 L9 G J 1 3 4 IMENSEEMENEEMBEEN mmmmmmmmmmmmmommo 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot q adjusted I added Nate: Whenever therelsa discrepancy affecting North Carolina compliance samples, a copy of this form will hesent to the North Carolina QEHNR Certlficatlon Dike (I.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 140 of 160 X 7 m G) n o a n ¢ v N :A I '0 CO -4 m w n ej " ITEM# n m 7 N o y c •n' o m i n i F ° p a D n j ly �Z h N t�nm ��. o s ry b c, i iii m D p f0 to C)> > W O a A S •J N+,a In x p� � O N ty d n �� T Q C O W a �. Cr 3 b x (I b m m m N v 0 c c _ rp N E n@ f a n c o M 6 n NO�yO� y O � _ �• O 0 m o ro _ 5 MATRIX CGOE (see valid codes to IeR} z z , 0 o a C y 0 0' 3 G) 0 0 cy n L] G) 0 SAMPLE TYPE (G=GRAB C=Co1A P) m x m an � n Y a o u m m 0 71 N �G a A 71 N 3 T rr m o a � r 5 Z m m 3 � _ 9� _ P 4+ O 9L, A 3 z �h` i K 9' 4' W m y� o 0> m a m 1I •TJ m ° ° i � n S.Z 9 _ 7 �i.i a m r Q v m H n "T1 rn m SAId PLE Ti AT COLLECTION p 4 4 of CONTAINERS n n n a° m S n a. 't t- 1 an N N fG w O N Urpraserved o ? Q+ v H2504 n z z o m u n n 7 N HNO3 ai ir y HC1 CDo ' 00 NaOH d w C 7 _ n � m � 1- cni Na2S203 En furl Methanol C) m .--I r Other D n m ro y Analyses Test YIN w N c x x x x x x x x x x Vi Appendix 1 z n �] d J S x Total Metals App- 1 z A en y� {+. z x x Mercury z E (Am LA �! �-" o 1 r "lao AiXalinty z m c❑ a a x Sulfate z m W �. Sulfitle Z y o Chloride z 'll _ a (a an TOO z m rt x x x rt x COI] z m Z to a x x r Ferrous Iron z 3 m m Nitrate z a 0 x x x x x 1,4-Qioxane z c a •�3 — eiD TEMP in C �a '�: n F. � x VFA z d = .K Received on Ice r m x x x x x "— Methane (fi5K�75} z (YIN) 0 - us o y ea e d Q Ocular YlN Samples Inlact .0 0 N " (YIN) li Page 141 of 160 �t I Q� { O 0 16 ©1 1 i h S rw m � n m nn w ^� 5' Z 6 1 c 0 N 1 o 0 a C N (A r 0 D r Q � O D C K M , D a p1 m � co t (p w � N FL N N 'y �v a a 0 co r "3 0 b� It) a �rt a w n n C 51 (G K Page 142 of 160 m O n n n w cc -4 m U+ A w N ITEM# N r d -4 D N z d g o m coo to '�tiJJ '4 t p , (n -4 -4O� UP n: s o -� n> D h, c� a_ ny (D x m I' o J ivd wN �m - 0 S o n 'D 0 n �. m m n o rD n --. n `C f➢ 3 o p T o C' v a x © x(93 �s rn ° m G z n EL �� N - 5 A o -- C c a m - y°fib°��a m , v N m o_ p n O r n MATRIX CODE (sea 4 d codes Weft) 0 z o C N c g D @ o m n G) G) G) G) 0 G) 0 0 C M G) SAMPLETYPE (G=GRAB C-CO'1P) rn a r x 3 4) 6 @ 0 < 'n m D T � En '0a 3 -n r m A n O to z n r � Y F� V 4� !' b { z z z Z m Z m m d° � Si a+ °° > m m o µ o D m z 4 _ _ _ b ui m CP r r z m SAYPLETEMPATCOLLECTION A A m 5 of CONTAINERS Q o Unpreserved C O 3 v v o y o H2504 � py m A o z v MN03 j v m NaOH v n w w _ m m Na25203 N Methanol m O m a ru @ Other m m Analyses Test YIN T r @ h x x x x x x VOCs Appendix 1 z p m x x x x x x x x x Total Metals App. 7 z Nz 0 n c x x x x Mercury z n Alkalinty z a R x Sulfate z SulSde z m T x Chloride z TOG z m n COD z R m z N to x x x Ferrous Iron z L- 3 z a m x Wrate z L'' m 3 w ° o n !L m N x x x x 1,4-Dioxane z TEMP �n C D ' o ' VFA z 9 r m n Received on lca x x x x x Methane (RSK175) z (YIN) n unto y ea e Cooler YIN z Samples Intact (YIN j Z u;L`� m .Z] c m (p ru (D a (J) C �a (m � o a m � n c ar m K Page 143 of 160 C a N Q m w ti rn cn w ra ITEM# d N W N N O W W fn A W rn 0 3 O d Q -a -a -D v a _ in ri N El �r O y n °; r m no M x n C C v o = x ❑ 0 m n 'm y y pn:ioca inn z � r � � o m X Qa i,,ATRIX CCDE (see valid codes to le Ay G 0 0 0 0 C) 0 10 16) 0 C) SAFdPLE TYPE (G-GRAD C=COMP) 6a y ` to m w o �_ n 3-x m n D m O -i m 0 D m �0' 0 ee e�R m m z m 9"` Y +1 im, O m SAMPLE TEMP AT COLLECTION # OF CONTAINERS 1 3 Unpreserved m H2804 H NO3 ro AHCl m 3-NaOH Na2S203 rn m � r--- V m Malhanol v Olher Analyses Test YIN x x x x x VOCs Appendix 1 z r Sx x x x x x x x Tolal Melals App. 1 z O z Mercury z x Alkallnly z Sulfate z x Sulfide z [ ; x Chloride Z TOC z COD z mx Ferrous Iron z *, m T Nilrale z �, w n x x x x x x IA-Dioxane z 3 a x VFA z r m n 0 x �wMdWj Z z (n n � a C 0 n � n D 3 3 =r ro n D w 5' Z C, l 7° to /ram O C1 C ,c N U) m b � 7 O C � W m Z I Page 144 of 160 ki 7 `I N = > 71 - s Z C O N � o 0 Q ♦: N N d r0 fl'I n r oy �:3 m ,z z: na Page 145 of 160 Page 146 of 160 e� m m a n a n m N�Gro00-40 M40"s ITEM# m 5 °-_'- j ° N I a n m m m p z cs W N 'D N +. N 9 n ycn �° v— N im 0. 2 ❑ n Y 7" d N X P1 d ...I N �I to Ip ° 0 O A r0 , j = z° r o W a a- m o m c C z N c a n' n N a 2 �{ 0 n v - n z X N N 55- p n O a N a E 0 y Ayr" W71 � � m N ° ° Q CD 0 m' O v m z d p @° MATRIX CODE (see valid cotles la I=lI) z o =1 L) 0 SAMPLETYPE IG=GRAB C-COMP} m a N= J S o � k a N ° ' d ❑ + 'n,m a a o T cn -n _ D Y r7 0 r U7 z z m %= z p Z ❑ m (n C A m m m a0 0 6 (n 17 i m Z ❑ � � a v � a 5� T m m m SAMPLETEMAATCOLLECTION rn m y a 3 o N w w OF CONTAINERS Unpreserved 0 a g v o N o n m o a Fi2504 py m � n z p x � � m -D pay HNO3 m o N N N HCI � r'a mNa25203 v m CD n m Methanol m Other Analyses Test YIN r t: rn x x x x x VOCs Appendix 1 z ri CD I- Total Metals App. 1 z �y } m O Mercury T Z m x x x x x 1,4-1ane a a Turbidity v n 41. " T � m a V� z N w 0 z o c m � O 0 'o o n 2 ]> A N N TEMP in C n rD V., w a m n Received on Ice (YIN) t n O zz a 0 use y \ Sealed Cooler z Samples Intact (Y1N) VI a Page 147 of 160 G ra s o 'A ,r aJ cn a w ra ITEM# a v. m 0 0 a 3 » N ° -4 w v Z w p r0O J 0� n Ln �Oxm n a N m �^}3 --2% W cn (0 M a. n »"; r o w o c� O m €3 °o X �x a z v CAI C 7 N c z S n' ro N .S] u n 0v _ h 0 p p v F,► Non��omv nn a m Or 3 c " �° v a ° `� 0 C, o p 0 ro Fi m C Z o hl ATRIX CODE (see Yalie codes In Ier1I O LR O SAMPLETYPE {G=GRAB C=CWP} N 3 s n X N O v N 3 B < m � D > a r . — N _n y n N V mD a z R f r m {{7 C n Z - N O U} z z z _ H � O y � 1 v rrnn 0 m 60 m m g $ a z w VI z 0 1 v > N C m mm D y SAI4PLE TEMP AT COLLECTION A m C7 Y 9 N n N w w rJ OF CONTAINERSa s a O Unpreserved -U b O 1.v son 0 3 m o o_ o K a 0v H2SO4 A n o n -• HNO3 'O N w m 7 m n = a. n' HCi Lm ro ro M ) p 0 — NaOH w y w a `i m w Na25203 N - m m Melhanol 03 m \ 01her m Analyses Test YIN T x x x x x VOCs Appendix 1 z n' x x x x Total Metals App. 1 z nAf w m z f x Mercury 0 � N x x x x x 1.4-Dioxane a a x x 7 3 c} O N N m = CL a z -! z y a z ° m TEMP in C 3 m a m @ m Received an ce (YIN) 00 zo us o y Sealed Cooler O Samples Inlacl (YIN) cn M Page 148 of 160 /� ace RnalX caJ January 10, 2019 Trey Carter Pace Analytical Charlotte 9800 Kincey Ave Suite 100 Huntersville, NC 28078 RE: ALEXANDER LF-SWS Pace Workorder. 29131 Dear Trey Carter: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, January 03, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Ruth Welsh 01/10/2019 Ruth.Welsh@pacelabs.com Customer Service Representative Enclosures Report ID: 29131 - 1130521 As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages Page 1 of 10 Page 149 of 160 Pace Analytical Energy Services LLC �}^Q �7 r + f 220 William Pitt Way ac A! alyfica7 Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 29131 - 1130521 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 10 Page 150 of 160 ace RnalX caJ SAMPLE SUMMARY Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 291310001 M W-5 Water 12/27/2018 16:30 1 /3/2019 10:30 291310002 M W-16 Water 12/27/2018 17:00 1 /3/2019 10:30 291310003 M W-25 Water 12/28/2018 11:17 1 /3/2019 10:30 Report ID: 29131 - 1130521 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 10 Page 151 of 160 ace RnalX caJ Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 291310001 Sample ID: MW-5 Date Received: 1/3/2019 10:30 Matrix: Water Date Collected: 12/27/2018 16:30 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.22 mg/I 0.20 0.014 1 1/5/201905:43 KB Acetic Acid 0.28 mg/I 0.10 0.024 1 1/5/201905:43 KB Propionic Acid 0.021J mg/I 0.10 0.0044 1 1/5/201905:43 KB Formic Acid 0.22 mg/I 0.20 0.048 1 1/5/201905:43 KB B Butyric Acid 0.022J mg/I 0.10 0.0047 1 1/5/201905:43 KB Pyruvic Acid 0.015J mg/I 0.10 0.0057 1 1/5/201905:43 KB i-Pentanoic Acid 0.0075U mg/I 0.10 0.0075 1 1/5/201905:43 KB Pentanoic Acid 0.012U mg/I 0.10 0.012 1 1/5/201905:43 KB i-Hexanoic Acid 0.0049U mg/I 0.20 0.0049 1 1/5/2019 05:43 KB Hexanoic Acid 0.012U mg/I 0.20 0.012 1 1/5/201905:43 KB Report ID: 29131 - 1130521 Page 4 of 10 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 152 of 160 ace RnalX caJ Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 291310002 Sample ID: MW-16 Date Received: 1/3/2019 10:30 Matrix: Water Date Collected: 12/27/2018 17:00 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.067J mg/I 0.20 0.014 1 1/5/201910:04 KB Acetic Acid 0.029J mg/I 0.10 0.024 1 1/5/201910:04 KB Propionic Acid 0.0044U mg/I 0.10 0.0044 1 1/5/201910:04 KB Formic Acid 0.15J mg/I 0.20 0.048 1 1/5/201910:04 KB B Butyric Acid 0.0047U mg/I 0.10 0.0047 1 1/5/201910:04 KB Pyruvic Acid 0.0057U mg/I 0.10 0.0057 1 1/5/201910:04 KB i-Pentanoic Acid 0.0075U mg/I 0.10 0.0075 1 1/5/201910:04 KB Pentanoic Acid 0.012U mg/I 0.10 0.012 1 1/5/201910:04 KB i-Hexanoic Acid 0.0049U mg/I 0.20 0.0049 1 1/5/201910:04 KB Hexanoic Acid 0.012U mg/I 0.20 0.012 1 1/5/201910:04 KB Report ID: 29131 - 1130521 Page 5 of 10 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 153 of 160 ace RnalX caJ Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 291310003 Sample ID: MW-25 Date Received: 1/3/2019 10:30 Matrix: Water Date Collected: 12/28/2018 11:17 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.19J mg/I 0.20 0.014 1 1/5/201911:01 KB Acetic Acid 0.029J mg/I 0.10 0.024 1 1/5/201911:01 KB Propionic Acid 0.0044U mg/I 0.10 0.0044 1 1/5/201911:01 KB Formic Acid 0.28 mg/I 0.20 0.048 1 1/5/201911:01 KB B Butyric Acid 0.0047U mg/I 0.10 0.0047 1 1/5/201911:01 KB Pyruvic Acid 0.0070J mg/I 0.10 0.0057 1 1/5/201911:01 KB i-Pentanoic Acid 0.0075U mg/I 0.10 0.0075 1 1/5/201911:01 KB Pentanoic Acid 0.012U mg/I 0.10 0.012 1 1/5/201911:01 KB i-Hexanoic Acid 0.0049U mg/I 0.20 0.0049 1 1/5/201911:01 KB Hexanoic Acid 0.012U mg/I 0.20 0.012 1 1/5/201911:01 KB Report ID: 29131 - 1130521 Page 6 of 10 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 154 of 160 /� ace RnalX caJ ANALYTICAL RESULTS QUALIFIERS Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). B The analyte was detected in the associated blank. Report ID: 29131 - 1130521 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 7 of 10 Page 155 of 160 ace RnalX caJ QUALITY CONTROL DATA Workorder: 29131 ALEXANDER LF-SWS QC Batch: EDON/3969 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 291310001, 291310002, 291310003 METHOD BLANK: 59281 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.014U 0.014 Acetic Acid mg/I 0.024U 0.024 Propionic Acid mg/I 0.0044U 0.0044 Formic Acid mg/I 0.077J 0.048 B Butyric Acid mg/I 0.0047U 0.0047 Pyruvic Acid mg/I 0.0057U 0.0057 i-Pentanoic Acid mg/I 0.0075U 0.0075 Pentanoic Acid mg/I 0.012U 0.012 i-Hexanoic Acid mg/I 0.0049U 0.0049 Hexanoic Acid mg/I 0.012U 0.012 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 59282 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers EDonors Lactic Acid mg/I 2 2.2 109 70-130 Acetic Acid mg/I 2 2.1 103 70-130 Propionic Acid mg/I 2 2.0 102 70-130 Formic Acid mg/I 2 2.0 101 70-130 B Butyric Acid mg/I 2 2.0 101 70-130 Pyruvic Acid mg/I 2 2.2 110 70-130 i-Pentanoic Acid mg/I 2 1.9 97 70-130 Pentanoic Acid mg/I 2 1.9 97 70-130 i-Hexanoic Acid mg/I 2 1.8 91 70-130 Hexanoic Acid mg/I 2 1.8 90 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 59283 59284 Original: 291310001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.22 2 2.4 2.4 111 110 70-130 0.97 30 Report ID: 29131 - 1130521 Page 8 of 10 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 156 of 160 /� ace RnalX caJ QUALITY CONTROL DATA Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Units 59283 Original Result Spike Cone. 59284 MS Result MSD Result Original: MS % Rec 291310001 MSD % Rec % Rec Limit RPD Max RPD Qualifiers Acetic Acid mg/I 0.28 2 2.4 2.3 104 103 70-130 0.29 30 Propionic Acid mg/I 0.021 2 2.1 2.1 104 103 70-130 0.8 30 Formic Acid mg/I 0.22 2 2.0 2.0 88 90 70-130 2.2 30 B Butyric Acid mg/I 0.022 2 2.1 2.1 104 104 70-130 0.75 30 Pyruvic Acid mg/I 0.015 2 2.2 2.2 110 109 70-130 1.2 30 i-Pentanoic Acid mg/I 0 2 2.1 2.0 103 102 70-130 1.1 30 Pentanoic Acid mg/I 0 2 2.1 2.1 107 106 70-130 0.48 30 i-Hexanoic Acid mg/I 0 2 2.1 2.1 107 104 70-130 3.1 30 Hexanoic Acid mg/I 0 2 2.2 2.1 108 107 70-130 1.1 30 Report ID: 29131 - 1130521 Page 9 of 10 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 157 of 160 ace RnalX caJ QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 29131 ALEXANDER LF-SWS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 291310001 MW-5 AM23G EDON/3969 291310002 MW-16 AM23G EDON/3969 291310003 MW-25 AM23G EDON/3969 Report ID: 29131 - 1130521 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 10 Page 158 of 160 RY � U Q O N T V8 as f� V) 49 LL J N co N Q E m Z 49 Y 00 O V N_ V N m a) E. O �A J z 0 en z D O u +O+ C c4 d N M13 Q'r W< z L O u Van E)£zwV X X X E c O Scs t3s. } i3r D- �wauz� N N N o z 25 00 � v M L > r O co O O O 41 ad O coC) O O 00 m N 'y M F= O Ocd P, N Pr In N N N U N N N N r o U c� U Z C _O m � d co d C m O O = 0 -4 `mcnrn d co a U � d d 0 CU QZ or'o (�CL .T CS E ` 0 (D Q Y O � m a ar o.� (Q oo L E e �a O O f— d 0) 2 CL LLJ f/J r N cn � In H r N M (� y w d rn O O N L co N O O Q) N O O U J J Q H U- LL a N O N M .N E 160 RS Page 15 T Cooler Receipt Form Client dame: Project: Lab Work Order: A. Shipping/Container Information (circle appropriate response) Courier: Fed Ex UPS USPS Client Other: Air bill Present: 'Yes No Tracking Number: Custody Sea{ on Cooler/Box Present: Yes No Seals intact: Yes No Cooler/Box Packing Material: Bubble Wrap Absorbent Foam Other:_ Type of Ice: Wet Blue None Ice Intact: Yes Melted Cooler Temperature: * Radiation Screened: Yes No Chain of Custody Present: Yes No Comments: B. Laboratory Assignment/Log-in (check appropriate response) if YES NO N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC ,Containers intact Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided PAES containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? Exception: VOA's coliform If yes, see pH form. Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by : Date: Project Manager Review: Date: F-PAE-Q-009-rev.01, 30ct2017 Page 160 of 160 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 January 04, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Alexander LF-SWs Pace Project No.: 92412475 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on January 02, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Trey Carter trey. carter@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 9 lacmnalytical' www.pacelabs.corn Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF-SWs Pace Project No.: 92412475 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF-SWs Pace Project No.: 92412475 Lab ID Sample ID 92412475001 MW-27 SAMPLE SUMMARY Matrix Date Collected Date Received Water 12/28/18 00:00 01/02/19 09:38 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF-SWs Pace Project No.: 92412475 Lab ID Sample ID 92412475001 MW-27 SAMPLE ANALYTE COUNT Method RSK 175 Modified REPORT OF LABORATORY ANALYSIS Analytes Analysts Reported LMB Laboratory PASI-C This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Alexander LF-SWs Pace Project No.: 92412475 Sample: MW-27 Lab ID: 92412475001 Collected: 12/28/18 00:00 Received: 01/02/19 09:38 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual RSK 175 Headspace Analytical Method: RSK 175 Modified Methane ND ug/L 10.0 10.0 1 01/03/1913:18 74-82-8 Date: 01/04/2019 11:13 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Alexander LF-SWs Pace Project No.: 92412475 QC Batch: 450593 Analysis Method: RSK 175 Modified QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE Associated Lab Samples: 92412475001 METHOD BLANK: 2465263 Matrix: Water Associated Lab Samples: 92412475001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Methane ug/L ND 10.0 10.0 01/03/1913:03 LABORATORY CONTROL SAMPLE: 2465265 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Methane ug/L 396 456 115 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2465266 2465267 MS MSD 92412475001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Methane ug/L ND 396 396 498 491 126 124 70-130 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /04/2019 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Alexander LF-SWs Pace Project No.: 92412475 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /04/2019 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 9 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Alexander LF-SWs Pace Project No.: 92412475 Lab ID Sample ID 92412475001 MW-27 QUALITY CONTROL DATA CROSS REFERENCE TABLE QC Batch Method RSK 175 Modified QC Batch Analytical Method 450593 REPORT OF LABORATORY ANALYSIS Analytical Batch This report shall not be reproduced, except in full, Date: 01 /04/2019 11:13 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 9 7 ni • � nlz F n 1 in in 1/15in n p A ; � � '-^i � a - x 2 J' �• R, ' I rc _ N ao ?- v 0 3 O L1 g P n o Q0 Gl Q m -I (y1 n I a m 9 c m vow 1 v oW Itsco ro m a gi u 'e m O b Q � � 7 Ex S 1 y b Q pin 3 �� Mel �5 i N cs r- m a I .w. Q vry '•L e, / c t - - .ti. ` n S. 3 3 3 ,yam a E 9� vs. Zv f R ro C a t N C J N Of �? i" 69 k A � yLS � lit m tl Q -: � S r 7 '. r ;. FN, -�C F• �rtf �+ �T G n SdI s2 �}��} "@ � Or qp, :. f�i _. A 7 s [} .I o fit:. lit PRO ♦f m w ¢ s5w0.n`� p rn p {.;ie N °m n a3 g � i iS m AAA,� '7. FQ�NH {fr7 _.�.1 n � "VAR n ��yL', ' W a 'Ct ? _-� -i 0. w f{� -= � yo. .-cost a a c e m H'1�a.H n s 1° tag; n � a- ro r3 h �a a IT n z 1 (Y J 9 Appendix B Field Sampling Parameter Data Sheet(s) i • � it hiogleipnl CIlE�L}= 'WrR g :) v.����irs �. , m.v.�� rn,;��..vr. �_ n, n,�.�r.. Project: Alexander Co Closed MSWLF &Active C&D LF Samplers: Page � of E. Lambert Sampling Parameters Water Quality Parameters Depth to Depth to Monitoring Purge Date: Purge Water Sample Date: Sample Water Volume Goes Total S e cific Y CH4 Point Time BTOP ( ) Time BTOP ( ) Sample Dry COMMENT CO2 DO Temp. p TDS � Gas 2018 2018 Sam le Purged Depth ORP pH Cond. � 'Pre -Purge Ti (Gal) Type During S Expected (mg/q (mg/L) © (us/cm (mg/L) 3 Vapors e Purge �- (ppm) MW-1 � � � to r � a� ) � x 40 �,"n t: -- __ MW-1 B } � �� �� 61 i z. t 4.. MW-3 33 MW-4R �- � r � � � t� i' i' � �" � 1,�, t'� �' 21.5 . P%iW-5 ; � I : � � - V 49.1 _ � rr , t� ,�` M W-6 1 � q r} 1��;�� 42 MW-7 �i`I- �( p ' 54 � � � MW-9 31.5 MW-10 F I� �, - t� ��I� I� � � � � ?;� ,i 91 �r� 1'�i`,( �- �-Y MW-11 56 �-� c � 66.5 MW-12D �'; � f � 102.5 t'E�" � ���.; �=� MW-13 (� ��:r j '�i � ` �'i: 1- 1� "' �^� 60:5 � � "- � � MW-15 � 35 � iMW-18 y ` � �7a( 56.7 t� ,� `, MW-19 � � I,t ' i�,{{' 63.92 Comments SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry Vr=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained z � � -. � � -z �.. {3 �, I .: lin a eet �,� t� .:—__> �..�..< ��....H.. Project: Alexander Co Closed MSWLF &Active C&D LF Samplers: J. Pfohl Page ��;3 of `�• E. Lambert Sampling Parameters Water Quality Parameters Depth to Depth to Monitoring Purge Purge Water Sample Sample Water Volume Goes Total S ecific p w CH4 Point Date: Time (BTOP) Date: Time (BTOP) Sam le p Dr y CO2 DO Tem p' TDS � Gas 2018 2018 Sample Pur ed g Type During COMMENTS De th p (mg/I) (mg/L) ORP p H © Cond. (mg/L) s Vapors Pre -Pure g Time (Gal) Expected (us/cm � Purge � (ppm) MW-20 'i i �'' � ` �;.� r ��'�'ra � � �, y 63.55 �;;�- MW-21 ��� �n t� ; 41.05 �' r".. rx '� MW-22 � ' „, � .rr i ; . r � i� , � °I> ��r,� `� � `> 18.12 I � � � , . �f -�, ��{,. MW-23 _ � � ;� � � 21,54 � f.r�. ,� � MW-24 , { 1 ;��' ' s'- � � r�=. �y ; r 35.35 , .�� _„�� MW-25 � � �� : ; � , ��� � 44.48 �� ,� MW-26 r Ir ��; �~ �� � a n � �: � � � �r r ��i�';� �j/ 49.8 �y !�;r�r 4��, �� BMW-27 � � � � � } 49.82 N MW-31 � �����' 32.56 � MW-32 �� �'; a� 42,7 'ta a MW-33 t� `<," l � ! ��' 3-.�p 21.38 � �, . MW-34 � ,' . 21.19 �� SW-3 � �, � �� Y, x, $�,. � _ SW-4R l�"��-`�" �`�aa ate. - - - - - - - - SW-5 - - - �f 1�-r' - - - - - � � � - SW-6 - - - - - �� - - - - EB - - - - - - - - - - - - - - - - FB - - - - - - - - - - - - - - - - - T�B� - - - - - - - - - - - - - - - - - Comments SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained A �' F1- � .. � �, `'as4 Appendix C Statistical Analyses Calculations Alexander Cc CDLF over MSWLF Zinc, total Rosner's Test for Outliers Parameter: Zinc, total Location: MW-11 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Data set mean = 439.958 10 most extreme of 36 measurements by order of magnitude difference from the mean 1 12/27/2018 MW-11 12700 12260 2 6/11/2018 MW-11 ND<2.5 U -437.458 3 6/17/2015 MW-11 6.4 J -433.558 4 1/6/2016 MW-11 7 J -432.958 5 6/24/2014 MW-11 11.6 -428.358 6 6/27/2013 MW-11 16.6 -423.358 7 12/18/2013 MW-11 17.5 -422.458 8 12/3/2014 MW-11 19.4 -420.558 9 6/13/2012 MW-11 21.9 -418.058 10 12/28/2017 MW-11 22.5 -417.458 Iteration i = 9 Mean of 27 measurements = 112.43 Std Dev = 128.45 x(i+1) = 22.5 from measurement 12/28/2017 from location MW-11 Rosner Statistic R = 122.5 - 112.431/128.45 = 0.700115 Lambda(36, 10, 0.05) = 2.86 0.700115 < 2.86 -- No outliers detected for i = 9 Iteration i = 8 Mean of 28 measurements = 109.196 Std Dev = 127.204 x(i+1) = 21.9 from measurement 6/13/2012 from location MW-11 Rosner Statistic R = 121.9 - 109.1961/127.204 = 0.686269 Lambda(36, 9, 0.05) = 2.876 0.686269 < 2.876 -- No outliers detected for i = 8 Iteration i = 7 Mean of 29 measurements = 106.1 Sid Dev = 126.02 x(i+1) = 19.4 from measurement 12/3/2014 from location MW-11 Rosner Statistic R = 119.4 - 106.11/126.02 = 0.687984 Lambda(36, 8, 0.05) = 2.892 0.687984 < 2.892 -- No outliers detected for i = 7 Iteration i = 6 Mean of 30 measurements = 103.147 Std Dev = 124.881 x(i+1) = 17.5 from measurement 12/18/2013 from location MW-11 Rosner Statistic R = 117.5 - 103.1471/124.881 = 0.685828 Lambda(36, 7, 0.05) = 2.908 0.685828 < 2.908 -- No outliers detected for i = 6 Iteration i = 5 Mean of 31 measurements = 100.355 Std Dev = 123.762 x(i+1) = 16.6 from measurement 6/27/2013 from location MW-11 Rosner Statistic R = 116.6 - 100.3551/123.762 = 0.676743 Lambda(36, 6, 0.05) = 2.924 0.676743 < 2.924 -- No outliers detected for i = 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 1 Alexander Cc CDLF over MSWLF Zinc, total Iteration i = 4 Mean of 32 measurements = 97.5812 Std Dev = 122.756 x(i+1) = 11.6 from measurement 6/24/2014 from location MW-11 Rosner Statistic R = 111.6 - 97.58121/122.756 = 0.700424 Lambda(36, 5, 0.05) = 2.94 0.700424 < 2.94 -- No outliers detected for i = 4 Iteration i = 3 Mean of 33 measurements = 94.8364 Std Dev = 121.847 x(i+1) = 7 from measurement 1/6/2016 from location MW-11 Rosner Statistic R = 17 - 94.83641/121.847 = 0.720873 Lambda(36, 4, 0.05) = 2.95 0.720873 < 2.95 -- No outliers detected for i = 3 Iteration i = 2 Mean of 34 measurements = 92.2353 Std Dev = 120.942 x(i+1) = 6.4 from measurement 6/17/2015 from location MW-11 Rosner Statistic R = 16.4 - 92.23531/120.942 = 0.709725 Lambda(36, 3, 0.05) = 2.97 0.709725 < 2.97 -- No outliers detected for i = 2 Iteration i = 1 Mean of 35 measurements = 89.6714 Std Dev = 120.111 x(i+1) = 2.5 from measurement 6/11/2018 from location MW-11 Rosner Statistic R = 12.5 - 89.67141/120.111 = 0.725755 Lambda(36, 2, 0.05) = 2.98 0.725755 < 2.98 -- No outliers detected for i = 1 Iteration i = 0 Mean of 36 measurements = 439.958 Std Dev = 2105.05 x(i+1) = 12700 from measurement 12/27/2018 from location MW-11 Rosner Statistic R = 112700 - 439.9581/2105.05 = 5.8241 Lambda(36, 1, 0.05) = 2.99 5.8241 > 2.99 -- Measurement 12/27/2018 for location MW-11 is an outlier Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 2 Alexander Cc CDLF over MSWLF Zinc, total Zinc, total Time -Series Granh of MW-f f 'Wu i000 1000 000 him him Kim 0in Sample Date Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 3 Alexander Cc CDLF over MSWLF Zinc, total Mann -Kendall Trend Analysis Parameter: Zinc, total Location: MW-11 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 410 560 -150 0 1 250 560 -310 0 2 190 560 -370 0 3 62 560 -498 0 4 93 560 -467 0 5 70 560 -490 0 6 98 560 -462 0 7 ND<25 U 560 -535 0 8 ND<25 U 560 -535 0 9 ND<25 U 560 -535 0 10 ND<25 U 560 -535 0 11 32.5 560 -527.5 0 12 40.7 J 560 -519.3 0 13 246 560 -314 0 14 54 560 -506 0 15 27.7 560 -532.3 0 16 31.7 560 -528.3 0 17 73.2 560 -486.8 0 18 28.2 560 -531.8 0 19 198 560 -362 0 20 68.7 560 -491.3 0 21 21.9 560 -538.1 0 22 81.9 560 -478.1 0 23 16.6 560 -543.4 0 24 17.5 560 -542.5 0 25 11.6 560 -548.4 0 26 19.4 560 -540.6 0 27 6.4 J 560 -553.6 0 28 7 J 560 -553 0 29 161 560 -399 0 30 64.2 560 -495.8 0 31 72.3 560 -487.7 0 32 22.5 560 -537.5 0 33 ND<2.5 U 560 -557.5 0 34 12700 560 12140 1 34 250 410 -160 1 35 190 410 -220 1 36 62 410 -348 1 37 93 410 -317 1 38 70 410 -340 1 39 98 410 -312 1 40 ND<25 U 410 -385 1 41 ND<25 U 410 -385 1 42 ND<25 U 410 -385 1 43 ND<25 U 410 -385 1 44 32.5 410 -377.5 1 45 40.7 J 410 -369.3 1 46 246 410 -164 1 47 54 410 -356 1 48 27.7 410 -382.3 1 49 31.7 410 -378.3 1 50 73.2 410 -336.8 1 51 28.2 410 -381.8 1 52 198 410 -212 1 53 68.7 410 -341.3 1 54 21.9 410 -388.1 1 55 81.9 410 -328.1 1 56 16.6 410 -393.4 1 57 17.5 410 -392.5 1 58 11.6 410 -398.4 1 59 19.4 410 -390.6 1 60 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 4 Alexander Cc CDLF over MSWLF Zinc, total 6.4 J 410 -403.6 1 61 7 J 410 -403 1 62 161 410 -249 1 63 64.2 410 -345.8 1 64 72.3 410 -337.7 1 65 22.5 410 -387.5 1 66 ND<2.5 U 410 -407.5 1 67 12700 410 12290 2 67 190 250 -60 2 68 62 250 -188 2 69 93 250 -157 2 70 70 250 -180 2 71 98 250 -152 2 72 ND<25 U 250 -225 2 73 ND<25 U 250 -225 2 74 ND<25 U 250 -225 2 75 ND<25 U 250 -225 2 76 32.5 250 -217.5 2 77 40.7 J 250 -209.3 2 78 246 250 -4 2 79 54 250 -196 2 80 27.7 250 -222.3 2 81 31.7 250 -218.3 2 82 73.2 250 -176.8 2 83 28.2 250 -221.8 2 84 198 250 -52 2 85 68.7 250 -181.3 2 86 21.9 250 -228.1 2 87 81.9 250 -168.1 2 88 16.6 250 -233.4 2 89 17.5 250 -232.5 2 90 11.6 250 -238.4 2 91 19.4 250 -230.6 2 92 6.4 J 250 -243.6 2 93 7 J 250 -243 2 94 161 250 -89 2 95 64.2 250 -185.8 2 96 72.3 250 -177.7 2 97 22.5 250 -227.5 2 98 ND<2.5 U 250 -247.5 2 99 12700 250 12450 3 99 62 190 -128 3 100 93 190 -97 3 101 70 190 -120 3 102 98 190 -92 3 103 ND<25 U 190 -165 3 104 ND<25 U 190 -165 3 105 ND<25 U 190 -165 3 106 ND<25 U 190 -165 3 107 32.5 190 -157.5 3 108 40.7 J 190 -149.3 3 109 246 190 56 4 109 54 190 -136 4 110 27.7 190 -162.3 4 111 31.7 190 -158.3 4 112 73.2 190 -116.8 4 113 28.2 190 -161.8 4 114 198 190 8 5 114 68.7 190 -121.3 5 115 21.9 190 -168.1 5 116 81.9 190 -108.1 5 117 16.6 190 -173.4 5 118 17.5 190 -172.5 5 119 11.6 190 -178.4 5 120 19.4 190 -170.6 5 121 6.4 J 190 -183.6 5 122 7 J 190 -183 5 123 161 190 -29 5 124 64.2 190 -125.8 5 125 72.3 190 -117.7 5 126 22.5 190 -167.5 5 127 ND<2.5 U 190 -187.5 5 128 12700 190 12510 6 128 93 62 31 7 128 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 5 Alexander Cc CDLF over MSWLF Zinc, total 70 62 8 8 128 98 62 36 9 128 ND<25 U 62 -37 9 129 ND<25 U 62 -37 9 130 ND<25 U 62 -37 9 131 ND<25 U 62 -37 9 132 32.5 62 -29.5 9 133 40.7 J 62 -21.3 9 134 246 62 184 10 134 54 62 -8 10 135 27.7 62 -34.3 10 136 31.7 62 -30.3 10 137 73.2 62 11.2 11 137 28.2 62 -33.8 11 138 198 62 136 12 138 68.7 62 6.7 13 138 21.9 62 -40.1 13 139 81.9 62 19.9 14 139 16.6 62 -45.4 14 140 17.5 62 -44.5 14 141 11.6 62 -50.4 14 142 19.4 62 -42.6 14 143 6.4 J 62 -55.6 14 144 7 J 62 -55 14 145 161 62 99 15 145 64.2 62 2.2 16 145 72.3 62 10.3 17 145 22.5 62 -39.5 17 146 ND<2.5 U 62 -59.5 17 147 12700 62 12638 18 147 70 93 -23 18 148 98 93 5 19 148 ND<25 U 93 -68 19 149 ND<25 U 93 -68 19 150 ND<25 U 93 -68 19 151 ND<25 U 93 -68 19 152 32.5 93 -60.5 19 153 40.7 J 93 -52.3 19 154 246 93 153 20 154 54 93 -39 20 155 27.7 93 -65.3 20 156 31.7 93 -61.3 20 157 73.2 93 -19.8 20 158 28.2 93 -64.8 20 159 198 93 105 21 159 68.7 93 -24.3 21 160 21.9 93 -71.1 21 161 81.9 93 -11.1 21 162 16.6 93 -76.4 21 163 17.5 93 -75.5 21 164 11.6 93 -81.4 21 165 19.4 93 -73.6 21 166 6.4 J 93 -86.6 21 167 7 J 93 -86 21 168 161 93 68 22 168 64.2 93 -28.8 22 169 72.3 93 -20.7 22 170 22.5 93 -70.5 22 171 ND<2.5 U 93 -90.5 22 172 12700 93 12607 23 172 98 70 28 24 172 ND<25 U 70 -45 24 173 ND<25 U 70 -45 24 174 ND<25 U 70 -45 24 175 ND<25 U 70 -45 24 176 32.5 70 -37.5 24 177 40.7 J 70 -29.3 24 178 246 70 176 25 178 54 70 -16 25 179 27.7 70 -42.3 25 180 31.7 70 -38.3 25 181 73.2 70 3.2 26 181 28.2 70 -41.8 26 182 198 70 128 27 182 68.7 70 -1.3 27 183 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 6 Alexander Co CDLF over MSWLF Zinc, total 21.9 70 -48.1 27 184 81.9 70 11.9 28 184 16.6 70 -53.4 28 185 17.5 70 -52.5 28 186 11.6 70 -58.4 28 187 19.4 70 -50.6 28 188 6.4 J 70 -63.6 28 189 7 J 70 -63 28 190 161 70 91 29 190 64.2 70 -5.8 29 191 72.3 70 2.3 30 191 22.5 70 -47.5 30 192 ND<2.5 U 70 -67.5 30 193 12700 70 12630 31 193 ND<25 U 98 -73 31 194 ND<25 U 98 -73 31 195 ND<25 U 98 -73 31 196 ND<25 U 98 -73 31 197 32.5 98 -65.5 31 198 40.7 J 98 -57.3 31 199 246 98 148 32 199 54 98 -44 32 200 27.7 98 -70.3 32 201 31.7 98 -66.3 32 202 73.2 98 -24.8 32 203 28.2 98 -69.8 32 204 198 98 100 33 204 68.7 98 -29.3 33 205 21.9 98 -76.1 33 206 81.9 98 -16.1 33 207 16.6 98 -81.4 33 208 17.5 98 -80.5 33 209 11.6 98 -86.4 33 210 19.4 98 -78.6 33 211 6.4 J 98 -91.6 33 212 7 J 98 -91 33 213 161 98 63 34 213 64.2 98 -33.8 34 214 72.3 98 -25.7 34 215 22.5 98 -75.5 34 216 ND<2.5 U 98 -95.5 34 217 12700 98 12602 35 217 ND<25 U ND<25 U 0 35 217 ND<25 U ND<25 U 0 35 217 ND<25 U ND<25 U 0 35 217 32.5 ND<25 U 7.5 36 217 40.7 J ND<25 U 15.7 37 217 246 ND<25 U 221 38 217 54 ND<25 U 29 39 217 27.7 ND<25 U 2.7 40 217 31.7 ND<25 U 6.7 41 217 73.2 ND<25 U 48.2 42 217 28.2 ND<25 U 3.2 43 217 198 ND<25 U 173 44 217 68.7 ND<25 U 43.7 45 217 21.9 ND<25 U -3.1 45 218 81.9 ND<25 U 56.9 46 218 16.6 ND<25 U -8.4 46 219 17.5 ND<25 U -7.5 46 220 11.6 ND<25 U -13.4 46 221 19.4 ND<25 U -5.6 46 222 6.4 J ND<25 U -18.6 46 223 7 J ND<25 U -18 46 224 161 ND<25 U 136 47 224 64.2 ND<25 U 39.2 48 224 72.3 ND<25 U 47.3 49 224 22.5 ND<25 U -2.5 49 225 ND<2.5 U ND<25 U -22.5 49 226 12700 ND<25 U 12675 50 226 ND<25 U ND<25 U 0 50 226 ND<25 U ND<25 U 0 50 226 32.5 ND<25 U 7.5 51 226 40.7 J ND<25 U 15.7 52 226 246 ND<25 U 221 53 226 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 7 Alexander Co CDLF over MSWLF Zinc, total 54 ND<25 U 29 54 226 27.7 ND<25 U 2.7 55 226 31.7 ND<25 U 6.7 56 226 73.2 ND<25 U 48.2 57 226 28.2 ND<25 U 3.2 58 226 198 ND<25 U 173 59 226 68.7 ND<25 U 43.7 60 226 21.9 ND<25 U -3.1 60 227 81.9 ND<25 U 56.9 61 227 16.6 ND<25 U -8.4 61 228 17.5 ND<25 U -7.5 61 229 11.6 ND<25 U -13.4 61 230 19.4 ND<25 U -5.6 61 231 6.4 J ND<25 U -18.6 61 232 7 J ND<25 U -18 61 233 161 ND<25 U 136 62 233 64.2 ND<25 U 39.2 63 233 72.3 ND<25 U 47.3 64 233 22.5 ND<25 U -2.5 64 234 ND<2.5 U ND<25 U -22.5 64 235 12700 ND<25 U 12675 65 235 ND<25 U ND<25 U 0 65 235 32.5 ND<25 U 7.5 66 235 40.7 J ND<25 U 15.7 67 235 246 ND<25 U 221 68 235 54 ND<25 U 29 69 235 27.7 ND<25 U 2.7 70 235 31.7 ND<25 U 6.7 71 235 73.2 ND<25 U 48.2 72 235 28.2 ND<25 U 3.2 73 235 198 ND<25 U 173 74 235 68.7 ND<25 U 43.7 75 235 21.9 ND<25 U -3.1 75 236 81.9 ND<25 U 56.9 76 236 16.6 ND<25 U -8.4 76 237 17.5 ND<25 U -7.5 76 238 11.6 ND<25 U -13.4 76 239 19.4 ND<25 U -5.6 76 240 6.4 J ND<25 U -18.6 76 241 7 J ND<25 U -18 76 242 161 ND<25 U 136 77 242 64.2 ND<25 U 39.2 78 242 72.3 ND<25 U 47.3 79 242 22.5 ND<25 U -2.5 79 243 ND<2.5 U ND<25 U -22.5 79 244 12700 ND<25 U 12675 80 244 32.5 ND<25 U 7.5 81 244 40.7 J ND<25 U 15.7 82 244 246 ND<25 U 221 83 244 54 ND<25 U 29 84 244 27.7 ND<25 U 2.7 85 244 31.7 ND<25 U 6.7 86 244 73.2 ND<25 U 48.2 87 244 28.2 ND<25 U 3.2 88 244 198 ND<25 U 173 89 244 68.7 ND<25 U 43.7 90 244 21.9 ND<25 U -3.1 90 245 81.9 ND<25 U 56.9 91 245 16.6 ND<25 U -8.4 91 246 17.5 ND<25 U -7.5 91 247 11.6 ND<25 U -13.4 91 248 19.4 ND<25 U -5.6 91 249 6.4 J ND<25 U -18.6 91 250 7 J ND<25 U -18 91 251 161 ND<25 U 136 92 251 64.2 ND<25 U 39.2 93 251 72.3 ND<25 U 47.3 94 251 22.5 ND<25 U -2.5 94 252 ND<2.5 U ND<25 U -22.5 94 253 12700 ND<25 U 12675 95 253 40.7 J 32.5 8.2 96 253 246 32.5 213.5 97 253 54 32.5 21.5 98 253 27.7 32.5 -4.8 98 254 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 8 Alexander Cc CDLF over MSWLF Zinc, total 31.7 32.5 -0.8 98 255 73.2 32.5 40.7 99 255 28.2 32.5 -4.3 99 256 198 32.5 165.5 100 256 68.7 32.5 36.2 101 256 21.9 32.5 -10.6 101 257 81.9 32.5 49.4 102 257 16.6 32.5 -15.9 102 258 17.5 32.5 -15 102 259 11.6 32.5 -20.9 102 260 19.4 32.5 -13.1 102 261 6.4 J 32.5 -26.1 102 262 7 J 32.5 -25.5 102 263 161 32.5 128.5 103 263 64.2 32.5 31.7 104 263 72.3 32.5 39.8 105 263 22.5 32.5 -10 105 264 ND<2.5 U 32.5 -30 105 265 12700 32.5 12667.5 106 265 246 40.7 J 205.3 107 265 54 40.7 J 13.3 108 265 27.7 40.7 J -13 108 266 31.7 40.7 J -9 108 267 73.2 40.7 J 32.5 109 267 28.2 40.7 J -12.5 109 268 198 40.7 J 157.3 110 268 68.7 40.7 J 28 111 268 21.9 40.7 J -18.8 111 269 81.9 40.7 J 41.2 112 269 16.6 40.7 J -24.1 112 270 17.5 40.7 J -23.2 112 271 11.6 40.7 J -29.1 112 272 19.4 40.7 J -21.3 112 273 6.4 J 40.7 J -34.3 112 274 7 J 40.7 J -33.7 112 275 161 40.7 J 120.3 113 275 64.2 40.7 J 23.5 114 275 72.3 40.7 J 31.6 115 275 22.5 40.7 J -18.2 115 276 ND<2.5 U 40.7 J -38.2 115 277 12700 40.7 J 12659.3 116 277 54 246 -192 116 278 27.7 246 -218.3 116 279 31.7 246 -214.3 116 280 73.2 246 -172.8 116 281 28.2 246 -217.8 116 282 198 246 -48 116 283 68.7 246 -177.3 116 284 21.9 246 -224.1 116 285 81.9 246 -164.1 116 286 16.6 246 -229.4 116 287 17.5 246 -228.5 116 288 11.6 246 -234.4 116 289 19.4 246 -226.6 116 290 6.4 J 246 -239.6 116 291 7 J 246 -239 116 292 161 246 -85 116 293 64.2 246 -181.8 116 294 72.3 246 -173.7 116 295 22.5 246 -223.5 116 296 ND<2.5 U 246 -243.5 116 297 12700 246 12454 117 297 27.7 54 -26.3 117 298 31.7 54 -22.3 117 299 73.2 54 19.2 118 299 28.2 54 -25.8 118 300 198 54 144 119 300 68.7 54 14.7 120 300 21.9 54 -32.1 120 301 81.9 54 27.9 121 301 16.6 54 -37.4 121 302 17.5 54 -36.5 121 303 11.6 54 -42.4 121 304 19.4 54 -34.6 121 305 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 9 Alexander Cc CDLF over MSWLF Zinc, total 6.4 J 54 -47.6 121 306 7 J 54 -47 121 307 161 54 107 122 307 64.2 54 10.2 123 307 72.3 54 18.3 124 307 22.5 54 -31.5 124 308 ND<2.5 U 54 -51.5 124 309 12700 54 12646 125 309 31.7 27.7 4 126 309 73.2 27.7 45.5 127 309 28.2 27.7 0.5 128 309 198 27.7 170.3 129 309 68.7 27.7 41 130 309 21.9 27.7 -5.8 130 310 81.9 27.7 54.2 131 310 16.6 27.7 -11.1 131 311 17.5 27.7 -10.2 131 312 11.6 27.7 -16.1 131 313 19.4 27.7 -8.3 131 314 6.4 J 27.7 -21.3 131 315 7 J 27.7 -20.7 131 316 161 27.7 133.3 132 316 64.2 27.7 36.5 133 316 72.3 27.7 44.6 134 316 22.5 27.7 -5.2 134 317 ND<2.5 U 27.7 -25.2 134 318 12700 27.7 12672.3 135 318 73.2 31.7 41.5 136 318 28.2 31.7 -3.5 136 319 198 31.7 166.3 137 319 68.7 31.7 37 138 319 21.9 31.7 -9.8 138 320 81.9 31.7 50.2 139 320 16.6 31.7 -15.1 139 321 17.5 31.7 -14.2 139 322 11.6 31.7 -20.1 139 323 19.4 31.7 -12.3 139 324 6.4 J 31.7 -25.3 139 325 7 J 31.7 -24.7 139 326 161 31.7 129.3 140 326 64.2 31.7 32.5 141 326 72.3 31.7 40.6 142 326 22.5 31.7 -9.2 142 327 ND<2.5 U 31.7 -29.2 142 328 12700 31.7 12668.3 143 328 28.2 73.2 -45 143 329 198 73.2 124.8 144 329 68.7 73.2 -4.5 144 330 21.9 73.2 -51.3 144 331 81.9 73.2 8.7 145 331 16.6 73.2 -56.6 145 332 17.5 73.2 -55.7 145 333 11.6 73.2 -61.6 145 334 19.4 73.2 -53.8 145 335 6.4 J 73.2 -66.8 145 336 7 J 73.2 -66.2 145 337 161 73.2 87.8 146 337 64.2 73.2 -9 146 338 72.3 73.2 -0.9 146 339 22.5 73.2 -50.7 146 340 ND<2.5 U 73.2 -70.7 146 341 12700 73.2 12626.8 147 341 198 28.2 169.8 148 341 68.7 28.2 40.5 149 341 21.9 28.2 -6.3 149 342 81.9 28.2 53.7 150 342 16.6 28.2 -11.6 150 343 17.5 28.2 -10.7 150 344 11.6 28.2 -16.6 150 345 19.4 28.2 -8.8 150 346 6.4 J 28.2 -21.8 150 347 7 J 28.2 -21.2 150 348 161 28.2 132.8 151 348 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 10 Alexander Cc CDLF over MSWLF Zinc, total 64.2 28.2 36 152 348 72.3 28.2 44.1 153 348 22.5 28.2 -5.7 153 349 ND<2.5 U 28.2 -25.7 153 350 12700 28.2 12671.8 154 350 68.7 198 -129.3 154 351 21.9 198 -176.1 154 352 81.9 198 -116.1 154 353 16.6 198 -181.4 154 354 17.5 198 -180.5 154 355 11.6 198 -186.4 154 356 19.4 198 -178.6 154 357 6.4 J 198 -191.6 154 358 7 J 198 -191 154 359 161 198 -37 154 360 64.2 198 -133.8 154 361 72.3 198 -125.7 154 362 22.5 198 -175.5 154 363 ND<2.5 U 198 -195.5 154 364 12700 198 12502 155 364 21.9 68.7 -46.8 155 365 81.9 68.7 13.2 156 365 16.6 68.7 -52.1 156 366 17.5 68.7 -51.2 156 367 11.6 68.7 -57.1 156 368 19.4 68.7 -49.3 156 369 6.4 J 68.7 -62.3 156 370 7 J 68.7 -61.7 156 371 161 68.7 92.3 157 371 64.2 68.7 -4.5 157 372 72.3 68.7 3.6 158 372 22.5 68.7 -46.2 158 373 ND<2.5 U 68.7 -66.2 158 374 12700 68.7 12631.3 159 374 81.9 21.9 60 160 374 16.6 21.9 -5.3 160 375 17.5 21.9 -4.4 160 376 11.6 21.9 -10.3 160 377 19.4 21.9 -2.5 160 378 6.4 J 21.9 -15.5 160 379 7 J 21.9 -14.9 160 380 161 21.9 139.1 161 380 64.2 21.9 42.3 162 380 72.3 21.9 50.4 163 380 22.5 21.9 0.6 164 380 ND<2.5 U 21.9 -19.4 164 381 12700 21.9 12678.1 165 381 16.6 81.9 -65.3 165 382 17.5 81.9 -64.4 165 383 11.6 81.9 -70.3 165 384 19.4 81.9 -62.5 165 385 6.4 J 81.9 -75.5 165 386 7 J 81.9 -74.9 165 387 161 81.9 79.1 166 387 64.2 81.9 -17.7 166 388 72.3 81.9 -9.6 166 389 22.5 81.9 -59.4 166 390 ND<2.5 U 81.9 -79.4 166 391 12700 81.9 12618.1 167 391 17.5 16.6 0.9 168 391 11.6 16.6 -5 168 392 19.4 16.6 2.8 169 392 6.4 J 16.6 -10.2 169 393 7 J 16.6 -9.6 169 394 161 16.6 144.4 170 394 64.2 16.6 47.6 171 394 72.3 16.6 55.7 172 394 22.5 16.6 5.9 173 394 ND<2.5 U 16.6 -14.1 173 395 12700 16.6 12683.4 174 395 11.6 17.5 -5.9 174 396 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 11 Alexander Cc CDLF over MSWLF Zinc, total 19.4 17.5 1.9 175 396 6.4 J 17.5 -11.1 175 397 7 J 17.5 -10.5 175 398 161 17.5 143.5 176 398 64.2 17.5 46.7 177 398 72.3 17.5 54.8 178 398 22.5 17.5 5 179 398 ND<2.5 U 17.5 -15 179 399 12700 17.5 12682.5 180 399 19.4 11.6 7.8 181 399 6.4 J 11.6 -5.2 181 400 7 J 11.6 -4.6 181 401 161 11.6 149.4 182 401 64.2 11.6 52.6 183 401 72.3 11.6 60.7 184 401 22.5 11.6 10.9 185 401 ND<2.5 U 11.6 -9.1 185 402 12700 11.6 12688.4 186 402 6.4 J 19.4 -13 186 403 7 J 19.4 -12.4 186 404 161 19.4 141.6 187 404 64.2 19.4 44.8 188 404 72.3 19.4 52.9 189 404 22.5 19.4 3.1 190 404 ND<2.5 U 19.4 -16.9 190 405 12700 19.4 12680.6 191 405 7 J 6.4 J 0.6 192 405 161 6.4 J 154.6 193 405 64.2 6.4 J 57.8 194 405 72.3 6.4 J 65.9 195 405 22.5 6.4 J 16.1 196 405 ND<2.5 U 6.4 J -3.9 196 406 12700 6.4 J 12693.6 197 406 161 7J 154 198 406 64.2 7 J 57.2 199 406 72.3 7 J 65.3 200 406 22.5 7 J 15.5 201 406 ND<2.5 U 7 J -4.5 201 407 12700 7J 12693 202 407 64.2 161 -96.8 202 408 72.3 161 -88.7 202 409 22.5 161 -138.5 202 410 ND<2.5 U 161 -158.5 202 411 12700 161 12539 203 411 72.3 64.2 8.1 204 411 22.5 64.2 -41.7 204 412 ND<2.5 U 64.2 -61.7 204 413 12700 64.2 12635.8 205 413 22.5 72.3 -49.8 205 414 ND<2.5 U 72.3 -69.8 205 415 12700 72.3 12627.7 206 415 ND<2.5 U 22.5 -20 206 416 12700 22.5 12677.5 207 416 12700 ND<2.5 U 12697.5 208 416 S Statistic = 208 - 416 = -208 Tied GroiValue Members 1 25 4 Time Period Observations 12/11/2000 1 6/12/2001 1 12/27/2001 1 6/13/2002 1 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 12 Alexander Cc CDLF over MSWLF Zinc, total 1 /3/2003 1 6/24/2003 1 12/11/2003 1 6/15/2004 1 12/29/2004 1 6/22/2005 1 1 /12/2006 1 7/7/2006 1 12/14/2006 1 6/27/2007 1 12/27/2007 1 6/20/2008 1 6/30/2009 1 12/17/2009 1 7/14/2010 1 12/17/2010 1 6/30/2011 1 12/15/2011 1 6/13/2012 1 12/12/2012 1 6/27/2013 1 12/18/2013 1 6/24/2014 1 12/3/2014 1 6/17/2015 1 1 /6/2016 1 7/6/2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A = 156 B=0 C=24 D=0 E=12 F=0 a = 97020 b = 385560 c = 2520 Group Variance = 5381.33 Z-Score =-2.82179 Comparison Level at 95% confidence level = 1.65463 (upward trend) -2.82179 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 13 Alexander Cc CDLF over MSWLF Cadmium, total Rosner's Test for Outliers Parameter: Cadmium, total Location: MW-11 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Data set mean = 0.560278 10 most extreme of 36 measurements by order of magnitude difference from the mean 1 12/27/2018 MW-11 3.8 3.23972 2 6/28/2017 MW-11 2.5 1.93972 3 12/11/2003 MW-11 1 0.439722 4 12/17/2010 MW-11 ND<0.18 U -0.380278 5 6/27/2007 MW-11 ND<0.19 U -0.370278 6 12/28/2017 MW-11 ND<0.25 U -0.310278 7 1/6/2016 MW-11 ND<0.25 U -0.310278 8 6/17/2015 MW-11 ND<0.25 U -0.310278 9 12/29/2016 MW-11 ND<0.25 U -0.310278 10 6/11/2018 MW-11 ND<0.25 U -0.310278 Iteration i = 9 Mean of 27 measurements = 0.425926 Std Dev = 0.11633 x(i+1) = 0.25 from measurement 6/11/2018 from location MW-11 Rosner Statistic R = 10.25 - 0.4259261/0.11633 = 1.5123 Lambda(36, 10, 0.01) = 3.18 1.5123 < 3.18 -- No outliers detected for i = 9 Iteration i = 8 Mean of 28 measurements = 0.419643 Std Dev = 0.118899 x(i+1) = 0.25 from measurement 12/29/2016 from location MW-11 Rosner Statistic R = 10.25 - 0.4196431/0.118899 = 1.42678 Lambda(36, 9, 0.01) = 3.198 1.42678 < 3.198 -- No outliers detected for i = 8 Iteration i = 7 Mean of 29 measurements = 0.413793 Std Dev = 0.120931 x(i+1) = 0.25 from measurement 6/17/2015 from location MW-11 Rosner Statistic R = 10.25 - 0.4137931/0.120931 = 1.35443 Lambda(36, 8, 0.01) = 3.216 1.35443 < 3.216 -- No outliers detected for i = 7 Iteration i = 6 Mean of 30 measurements = 0.408333 Std Dev = 0.122533 x(i+1) = 0.25 from measurement 1/6/2016 from location MW-11 Rosner Statistic R = 10.25 - 0.4083331/0.122533 = 1.29217 Lambda(36, 7, 0.01) = 3.234 1.29217 < 3.234 -- No outliers detected for i = 6 Iteration i = 5 Mean of 31 measurements = 0.403226 Std Dev = 0.123784 x(i+1) = 0.25 from measurement 12/28/2017 from location MW-11 Rosner Statistic R = 10.25 - 0.4032261/0.123784 = 1.23784 Lambda(36, 6, 0.01) = 3.252 1.23784 < 3.252 -- No outliers detected for i = 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 14 Alexander Cc CDLF over MSWLF Cadmium, total Iteration i = 4 Mean of 32 measurements = 0.396562 Std Dev = 0.127472 x(i+1) = 0.19 from measurement 6/27/2007 from location MW-11 Rosner Statistic R = 10.19 - 0.3965621/0.127472 = 1.62045 Lambda(36, 5, 0.01) = 3.27 1.62045 < 3.27 -- No outliers detected for i = 4 Iteration i = 3 Mean of 33 measurements = 0.39 Std Dev = 0.131006 x(i+1) = 0.18 from measurement 12/17/2010 from location MW-11 Rosner Statistic R = 10.18 - 0.391/0.131006 = 1.60298 Lambda(36, 4, 0.01) = 3.29 1.60298 < 3.29 -- No outliers detected for i = 3 Iteration i = 2 Mean of 34 measurements = 0.407941 Std Dev = 0.166092 x(i+1) = 1 from measurement 12/11/2003 from location MW-11 Rosner Statistic R = 11 - 0.4079411/0.166092 = 3.56464 Lambda(36, 3, 0.01) = 3.3 3.56464 > 3.3 -- Measurement 12/11/2003 for location MW-11 is an outlier Iteration i = 1 Mean of 35 measurements = 0.467714 Std Dev = 0.389646 x(i+1) = 2.5 from measurement 6/28/2017 from location MW-11 Rosner Statistic R = 12.5 - 0.4677141/0.389646 = 5.21572 Lambda(36, 2, 0.01) = 3.32 Measurement 6/28/2017 for location MW-11 is an outlier Iteration i = 0 Mean of 36 measurements = 0.560278 Std Dev = 0.675229 x(i+1) = 3.8 from measurement 12/27/2018 from location MW-11 Rosner Statistic R = 13.8 - 0.5602781/0.675229 = 4.79796 Lambda(36, 1, 0.01) = 3.33 Measurement 12/27/2018 for location MW-11 is an outlier Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 15 Alexander Cc CDLF over MSWLF Cadmium, total Cadmium, iota Srp� Dale Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 16 Alexander Cc CDLF over MSWLF Cadmium, total Cadmium, total loh.Well ShewhaMUSUM Control Chart of MW1 f Baseline Mean = 0,498; Baseline Sld Deg: 0910188; k =1: h = 5; SC I: 4,5 20 .8 baseline mean=0,498 �'.25 SCL MA WR ND 11P 025 1.25 125 1.25 '098 0,5 0.5 0,5 0.5 0,5 0,5 0,5 1.25 %3 13 '0,25 1.25 1 Standardized mean CUSUM Sample Dale Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 17 Alexander Cc CDLF over MSWLF Cobalt, total Rosner's Test for Outliers Parameter: Cobalt, total Location: MW-15 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Data set mean = 23.3583 10 most extreme of 36 measurements by order of magnitude difference from the mean 1 12/27/2018 MW-15 85.3 61.9417 2 12/17/2013 MW-15 79.6 56.2417 3 6/11/2018 MW-15 70.4 47.0417 4 6/28/2017 MW-15 67.1 43.7417 5 12/11/2000 MW-15 65 41.6417 6 12/28/2017 MW-15 56.3 32.9417 7 12/19/2007 MW-15 ND<1 U -22.3583 8 6/19/2008 MW-15 ND<1 U -22.3583 9 6/18/2015 MW-15 ND<1.25 U -22.1083 10 12/4/2014 MW-15 ND<1.25 U -22.1083 Iteration i = 9 Mean of 27 measurements = 15.3315 Std Dev = 14.2652 x(i+1) = 1.25 from measurement 12/4/2014 from location MW-15 Rosner Statistic R = 11.25 - 15.33151/14.2652 = 0.987119 Lambda(36, 10, 0.05) = 2.86 0.987119 < 2.86 -- No outliers detected for i = 9 Iteration i = 8 Mean of 28 measurements = 14.8286 Std Dev = 14.2493 x(i+1) = 1.25 from measurement 6/18/2015 from location MW-15 Rosner Statistic R = 11.25 - 14.82861/14.2493 = 0.952931 Lambda(36, 9, 0.05) = 2.876 0.952931 < 2.876 -- No outliers detected for i = 8 Iteration i = 7 Mean of 29 measurements = 14.3517 Std Dev = 14.2262 x(i+1) = 1 from measurement 6/19/2008 from location MW-15 Rosner Statistic R = 11 - 14.35171/14.2262 = 0.938532 Lambda(36, 8, 0.05) = 2.892 0.938532 < 2.892 -- No outliers detected for i = 7 Iteration i = 6 Mean of 30 measurements = 13.9067 Std Dev = 14.1897 x(i+1) = 1 from measurement 12/19/2007 from location MW-15 Rosner Statistic R = 11 - 13.90671/14.1897 = 0.909579 Lambda(36, 7, 0.05) = 2.908 0.909579 < 2.908 -- No outliers detected for i = 6 Iteration i = 5 Mean of 31 measurements = 15.2742 Std Dev = 15.8937 x(i+1) = 56.3 from measurement 12/28/2017 from location MW-15 Rosner Statistic R = 156.3 - 15.27421/15.8937 = 2.58126 Lambda(36, 6, 0.05) = 2.924 2.58126 < 2.924 -- No outliers detected for i = 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 18 Alexander Cc CDLF over MSWLF Cobalt, total Iteration i = 4 Mean of 32 measurements = 16.8281 Std Dev = 17.9369 x(i+1) = 65 from measurement 12/11/2000 from location MW-15 Rosner Statistic R = 165 - 16.82811/17.9369 = 2.68563 Lambda(36, 5, 0.05) = 2.94 2.68563 < 2.94 -- No outliers detected for i = 4 Iteration i = 3 Mean of 33 measurements = 18.3515 Std Dev = 19.7044 x(i+1) = 67.1 from measurement 6/28/2017 from location MW-15 Rosner Statistic R = 167.1 - 18.35151/19.7044 = 2.474 Lambda(36, 4, 0.05) = 2.95 2.474 < 2.95 -- No outliers detected for i = 3 Iteration i = 2 Mean of 34 measurements = 19.8824 Std Dev = 21.3582 x(i+1) = 70.4 from measurement 6/11/2018 from location MW-15 Rosner Statistic R = 170.4 - 19.88241/21.3582 = 2.36525 Lambda(36, 3, 0.05) = 2.97 2.36525 < 2.97 -- No outliers detected for i = 2 Iteration i = 1 Mean of 35 measurements = 21.5886 Std Dev = 23.3377 x(i+1) = 79.6 from measurement 12/17/2013 from location MW-15 Rosner Statistic R = 179.6 - 21.58861/23.3377 = 2.48574 Lambda(36, 2, 0.05) = 2.98 2.48574 < 2.98 -- No outliers detected for i = 1 Iteration i = 0 Mean of 36 measurements = 23.3583 Std Dev = 25.3346 x(i+1) = 85.3 from measurement 12/27/2018 from location MW-15 Rosner Statistic R = 185.3 - 23.35831/25.3346 = 2.44495 Lambda(36, 1, 0.05) = 2.99 2.44495 < 2.99 -- No outliers detected for i = 0 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 19 Alexander Cc CDLF over MSWLF Lead, total Rosner's Test for Outliers Parameter: Lead, total Location: MW-11 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL Data set mean = 7.30278 10 most extreme of 36 measurements by order of magnitude difference from the mean 1 12/27/2018 MW-11 44 36.6972 2 12/11/2000 MW-11 34 26.6972 3 12/27/2001 MW-11 28 20.6972 4 6/12/2001 MW-11 24 16.6972 5 6/13/2002 MW-11 17 9.69722 6 12/17/2010 MW-11 ND<0.95 U -6.35278 7 6/27/2007 MW-11 ND<1.55 U -5.75278 8 12/17/2009 MW-11 ND<2 U -5.30278 9 7/14/2010 MW-11 ND<2 U -5.30278 10 6/30/2009 MW-11 ND<2 U -5.30278 Iteration i = 9 Mean of 27 measurements = 4.05185 Std Dev = 1.60393 x(i+1) = 2 from measurement 6/30/2009 from location MW-11 Rosner Statistic R = 12 - 4.051851/1.60393 = 1.27926 Lambda(36, 10, 0.05) = 2.86 1.27926 < 2.86 -- No outliers detected for i = 9 Iteration i = 8 Mean of 28 measurements = 3.97857 Std Dev = 1.62101 x(i+1) = 2 from measurement 7/14/2010 from location MW-11 Rosner Statistic R = 12 - 3.978571/1.62101 = 1.22058 Lambda(36, 9, 0.05) = 2.876 1.22058 < 2.876 -- No outliers detected for i = 8 Iteration i = 7 Mean of 29 measurements = 3.91034 Std Dev = 1.63365 x(i+1) = 2 from measurement 12/17/2009 from location MW-11 Rosner Statistic R = 12 - 3.910341/1.63365 = 1.16937 Lambda(36, 8, 0.05) = 2.892 1.16937 < 2.892 -- No outliers detected for i = 7 Iteration i = 6 Mean of 30 measurements = 3.83167 Std Dev = 1.66208 x(i+1) = 1.55 from measurement 6/27/2007 from location MW-11 Rosner Statistic R = 11.55 - 3.831671/1.66208 = 1.37278 Lambda(36, 7, 0.05) = 2.908 1.37278 < 2.908 -- No outliers detected for i = 6 Iteration i = 5 Mean of 31 measurements = 3.73871 Std Dev = 1.71414 x(i+1) = 0.95 from measurement 12/17/2010 from location MW-11 Rosner Statistic R = 10.95 - 3.738711/1.71414 = 1.62688 Lambda(36, 6, 0.05) = 2.924 1.62688 < 2.924 -- No outliers detected for i = 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 20 Alexander Cc CDLF over MSWLF Lead, total Iteration i = 4 Mean of 32 measurements = 4.15313 Std Dev = 2.88776 x(i+1) = 17 from measurement 6/13/2002 from location MW-11 Rosner Statistic R = 117 - 4.153131/2.88776 = 4.44873 Lambda(36, 5, 0.05) = 2.94 4.44873 > 2.94 -- Measurement 6/1312002 for location MW-11 is an outlier Iteration i = 3 Mean of 33 measurements = 4.75455 Std Dev = 4.4738 x(i+1) = 24 from measurement 6/12/2001 from location MW-11 Rosner Statistic R = 124 - 4.754551/4.4738 = 4.30181 Lambda(36, 4, 0.05) = 2.95 Measurement 6/12/2001 for location MW-11 is an outlier Iteration i = 2 Mean of 34 measurements = 5.43824 Std Dev = 5.94147 x(i+1) = 28 from measurement 12/27/2001 from location MW-11 Rosner Statistic R = 128 - 5.438241/5.94147 = 3.79734 Lambda(36, 3, 0.05) = 2.97 Measurement 12/27/2001 for location MW-11 is an outlier Iteration i = 1 Mean of 35 measurements = 6.25429 Std Dev = 7.58753 x(i+1) = 34 from measurement 12/11/2000 from location MW-11 Rosner Statistic R = 134 - 6.254291/7.58753 = 3.65675 Lambda(36, 2, 0.05) = 2.98 Measurement 12/11/2000 for location MW-11 is an outlier Iteration i = 0 Mean of 36 measurements = 7.30278 Std Dev = 9.7725 x(i+1) = 44 from measurement 12/27/2018 from location MW-11 Rosner Statistic R = 144 - 7.302781/9.7725 = 3.75515 Lambda(36, 1, 0.05) = 2.99 Measurement 12/27/2018 for location MW-11 is an outlier Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 21 Alexander Cc CDLF over MSWLF Lead, total Lead, total Time•Series Graph of MWf 1 Sample Date Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 22 Alexander Cc CDLF over MSWLF Lead, total 1 Skklmil mean CUSUM Lead, tota loh.ftl SheAh .COSOM Control Chart of MW1 f Sample Dale Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 23 Alexander Cc CDLF over MSWLF Cobalt, total Cobalt, total Sample Date Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 24 Alexander Co CDLF over MSWLF Cobalt, total Mann -Kendall Trend Analysis Parameter: Cobalt, total Location: MW-15 Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 30 65 -35 0 1 5.7 65 -59.3 0 2 33 65 -32 0 3 40 65 -25 0 4 28 65 -37 0 5 ND<5 U 65 -60 0 6 ND<5 U 65 -60 0 7 ND<5 U 65 -60 0 8 ND<5 U 65 -60 0 9 ND<5 U 65 -60 0 10 ND<5 U 65 -60 0 11 ND<5 U 65 -60 0 12 ND<1.25 U 65 -63.75 0 13 ND<1 U 65 -64 0 14 ND<1 U 65 -64 0 15 19.5 65 -45.5 0 16 26.8 65 -38.2 0 17 13.8 65 -51.2 0 18 36.7 65 -28.3 0 19 6.6 J 65 -58.4 0 20 40 65 -25 0 21 14.8 65 -50.2 0 22 ND<2.5 U 65 -62.5 0 23 40.4 65 -24.6 0 24 79.6 65 14.6 1 24 ND<2.5 U 65 -62.5 1 25 ND<1.25 U 65 -63.75 1 26 ND<1.25 U 65 -63.75 1 27 ND<1.25 U 65 -63.75 1 28 29.7 65 -35.3 1 29 5.2 J 65 -59.8 1 30 67.1 65 2.1 2 30 56.3 65 -8.7 2 31 70.4 65 5.4 3 31 85.3 65 20.3 4 31 5.7 30 -24.3 4 32 33 30 3 5 32 40 30 10 6 32 28 30 -2 6 33 ND<5 U 30 -25 6 34 ND<5 U 30 -25 6 35 ND<5 U 30 -25 6 36 ND<5 U 30 -25 6 37 ND<5 U 30 -25 6 38 ND<5 U 30 -25 6 39 ND<5 U 30 -25 6 40 ND<1.25 U 30 -28.75 6 41 ND<1 U 30 -29 6 42 ND<1 U 30 -29 6 43 19.5 30 -10.5 6 44 26.8 30 -3.2 6 45 13.8 30 -16.2 6 46 36.7 30 6.7 7 46 6.6 J 30 -23.4 7 47 40 30 10 8 47 14.8 30 -15.2 8 48 ND<2.5 U 30 -27.5 8 49 40.4 30 10.4 9 49 79.6 30 49.6 10 49 ND<2.5 U 30 -27.5 10 50 ND<1.25 U 30 -28.75 10 51 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 25 Alexander Cc CDLF over MSWLF Cobalt, total ND<1.25 U 30 -28.75 10 52 ND<1.25 U 30 -28.75 10 53 29.7 30 -0.3 10 54 5.2 J 30 -24.8 10 55 67.1 30 37.1 11 55 56.3 30 26.3 12 55 70.4 30 40.4 13 55 85.3 30 55.3 14 55 33 5.7 27.3 15 55 40 5.7 34.3 16 55 28 5.7 22.3 17 55 ND<5 U 5.7 -0.7 17 56 ND<5 U 5.7 -0.7 17 57 ND<5 U 5.7 -0.7 17 58 ND<5 U 5.7 -0.7 17 59 ND<5 U 5.7 -0.7 17 60 ND<5 U 5.7 -0.7 17 61 ND<5 U 5.7 -0.7 17 62 ND<1.25 U 5.7 -4.45 17 63 ND<1 U 5.7 -4.7 17 64 ND<1 U 5.7 -4.7 17 65 19.5 5.7 13.8 18 65 26.8 5.7 21.1 19 65 13.8 5.7 8.1 20 65 36.7 5.7 31 21 65 6.6 J 5.7 0.9 22 65 40 5.7 34.3 23 65 14.8 5.7 9.1 24 65 ND<2.5 U 5.7 -3.2 24 66 40.4 5.7 34.7 25 66 79.6 5.7 73.9 26 66 ND<2.5 U 5.7 -3.2 26 67 ND<1.25 U 5.7 -4.45 26 68 ND<1.25 U 5.7 -4.45 26 69 ND<1.25 U 5.7 -4.45 26 70 29.7 5.7 24 27 70 5.2 J 5.7 -0.5 27 71 67.1 5.7 61.4 28 71 56.3 5.7 50.6 29 71 70.4 5.7 64.7 30 71 85.3 5.7 79.6 31 71 40 33 7 32 71 28 33 -5 32 72 ND<5 U 33 -28 32 73 ND<5 U 33 -28 32 74 ND<5 U 33 -28 32 75 ND<5 U 33 -28 32 76 ND<5 U 33 -28 32 77 ND<5 U 33 -28 32 78 ND<5 U 33 -28 32 79 ND<1.25 U 33 -31.75 32 80 ND<1 U 33 -32 32 81 ND<1 U 33 -32 32 82 19.5 33 -13.5 32 83 26.8 33 -6.2 32 84 13.8 33 -19.2 32 85 36.7 33 3.7 33 85 6.6 J 33 -26.4 33 86 40 33 7 34 86 14.8 33 -18.2 34 87 ND<2.5 U 33 -30.5 34 88 40.4 33 7.4 35 88 79.6 33 46.6 36 88 ND<2.5 U 33 -30.5 36 89 ND<1.25 U 33 -31.75 36 90 ND<1.25 U 33 -31.75 36 91 ND<1.25 U 33 -31.75 36 92 29.7 33 -3.3 36 93 5.2 J 33 -27.8 36 94 67.1 33 34.1 37 94 56.3 33 23.3 38 94 70.4 33 37.4 39 94 85.3 33 52.3 40 94 28 40 -12 40 95 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 26 Alexander Co CDLF over MSWLF Cobalt, total ND<5 U 40 -35 40 96 ND<5 U 40 -35 40 97 ND<5 U 40 -35 40 98 ND<5 U 40 -35 40 99 ND<5 U 40 -35 40 100 ND<5 U 40 -35 40 101 ND<5 U 40 -35 40 102 ND<1.25 U 40 -38.75 40 103 ND<1 U 40 -39 40 104 ND<1 U 40 -39 40 105 19.5 40 -20.5 40 106 26.8 40 -13.2 40 107 13.8 40 -26.2 40 108 36.7 40 -3.3 40 109 6.6 J 40 -33.4 40 110 40 40 0 40 110 14.8 40 -25.2 40 111 ND<2.5 U 40 -37.5 40 112 40.4 40 0.4 41 112 79.6 40 39.6 42 112 ND<2.5 U 40 -37.5 42 113 ND<1.25 U 40 -38.75 42 114 ND<1.25 U 40 -38.75 42 115 ND<1.25 U 40 -38.75 42 116 29.7 40 -10.3 42 117 5.2 J 40 -34.8 42 118 67.1 40 27.1 43 118 56.3 40 16.3 44 118 70.4 40 30.4 45 118 85.3 40 45.3 46 118 ND<5 U 28 -23 46 119 ND<5 U 28 -23 46 120 ND<5 U 28 -23 46 121 ND<5 U 28 -23 46 122 ND<5 U 28 -23 46 123 ND<5 U 28 -23 46 124 ND<5 U 28 -23 46 125 ND<1.25 U 28 -26.75 46 126 ND<1 U 28 -27 46 127 ND<1 U 28 -27 46 128 19.5 28 -8.5 46 129 26.8 28 -1.2 46 130 13.8 28 -14.2 46 131 36.7 28 8.7 47 131 6.6 J 28 -21.4 47 132 40 28 12 48 132 14.8 28 -13.2 48 133 ND<2.5 U 28 -25.5 48 134 40.4 28 12.4 49 134 79.6 28 51.6 50 134 ND<2.5 U 28 -25.5 50 135 ND<1.25 U 28 -26.75 50 136 ND<1.25 U 28 -26.75 50 137 ND<1.25 U 28 -26.75 50 138 29.7 28 1.7 51 138 5.2 J 28 -22.8 51 139 67.1 28 39.1 52 139 56.3 28 28.3 53 139 70.4 28 42.4 54 139 85.3 28 57.3 55 139 ND<5 U ND<5 U 0 55 139 ND<5 U ND<5 U 0 55 139 ND<5 U ND<5 U 0 55 139 ND<5 U ND<5 U 0 55 139 ND<5 U ND<5 U 0 55 139 ND<5 U ND<5 U 0 55 139 ND<1.25 U ND<5 U -3.75 55 140 ND<1 U ND<5 U -4 55 141 ND<1 U ND<5 U -4 55 142 19.5 ND<5 U 14.5 56 142 26.8 ND<5 U 21.8 57 142 13.8 ND<5 U 8.8 58 142 36.7 ND<5 U 31.7 59 142 6.6 J ND<5 U 1.6 60 142 40 ND<5 U 35 61 142 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 27 Alexander Cc CDLF over MSWLF Cobalt, total 14.8 ND<5 U 9.8 62 142 ND<2.5 U ND<5 U -2.5 62 143 40.4 ND<5 U 35.4 63 143 79.6 ND<5 U 74.6 64 143 ND<2.5 U ND<5 U -2.5 64 144 ND<1.25 U ND<5 U -3.75 64 145 ND<1.25 U ND<5 U -3.75 64 146 ND<1.25 U ND<5 U -3.75 64 147 29.7 ND<5 U 24.7 65 147 5.2 J ND<5 U 0.2 66 147 67.1 ND<5 U 62.1 67 147 56.3 ND<5 U 51.3 68 147 70.4 ND<5 U 65.4 69 147 85.3 ND<5 U 80.3 70 147 ND<5 U ND<5 U 0 70 147 ND<5 U ND<5 U 0 70 147 ND<5 U ND<5 U 0 70 147 ND<5 U ND<5 U 0 70 147 ND<5 U ND<5 U 0 70 147 ND<1.25 U ND<5 U -3.75 70 148 ND<1 U ND<5 U -4 70 149 ND<1 U ND<5 U -4 70 150 19.5 ND<5 U 14.5 71 150 26.8 ND<5 U 21.8 72 150 13.8 ND<5 U 8.8 73 150 36.7 ND<5 U 31.7 74 150 6.6 J ND<5 U 1.6 75 150 40 ND<5 U 35 76 150 14.8 ND<5 U 9.8 77 150 ND<2.5 U ND<5 U -2.5 77 151 40.4 ND<5 U 35.4 78 151 79.6 ND<5 U 74.6 79 151 ND<2.5 U ND<5 U -2.5 79 152 ND<1.25 U ND<5 U -3.75 79 153 ND<1.25 U ND<5 U -3.75 79 154 ND<1.25 U ND<5 U -3.75 79 155 29.7 ND<5 U 24.7 80 155 5.2 J ND<5 U 0.2 81 155 67.1 ND<5 U 62.1 82 155 56.3 ND<5 U 51.3 83 155 70.4 ND<5 U 65.4 84 155 85.3 ND<5 U 80.3 85 155 ND<5 U ND<5 U 0 85 155 ND<5 U ND<5 U 0 85 155 ND<5 U ND<5 U 0 85 155 ND<5 U ND<5 U 0 85 155 ND<1.25 U ND<5 U -3.75 85 156 ND<1 U ND<5 U -4 85 157 ND<1 U ND<5 U -4 85 158 19.5 ND<5 U 14.5 86 158 26.8 ND<5 U 21.8 87 158 13.8 ND<5 U 8.8 88 158 36.7 ND<5 U 31.7 89 158 6.6 J ND<5 U 1.6 90 158 40 ND<5 U 35 91 158 14.8 ND<5 U 9.8 92 158 ND<2.5 U ND<5 U -2.5 92 159 40.4 ND<5 U 35.4 93 159 79.6 ND<5 U 74.6 94 159 ND<2.5 U ND<5 U -2.5 94 160 ND<1.25 U ND<5 U -3.75 94 161 ND<1.25 U ND<5 U -3.75 94 162 ND<1.25 U ND<5 U -3.75 94 163 29.7 ND<5 U 24.7 95 163 5.2 J ND<5 U 0.2 96 163 67.1 ND<5 U 62.1 97 163 56.3 ND<5 U 51.3 98 163 70.4 ND<5 U 65.4 99 163 85.3 ND<5 U 80.3 100 163 ND<5 U ND<5 U 0 100 163 ND<5 U ND<5 U 0 100 163 ND<5 U ND<5 U 0 100 163 ND<1.25 U ND<5 U -3.75 100 164 ND<1 U ND<5 U -4 100 165 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 28 Alexander Cc CDLF over MSWLF Cobalt, total ND<1 U ND<5 U -4 100 166 19.5 ND<5 U 14.5 101 166 26.8 ND<5 U 21.8 102 166 13.8 ND<5 U 8.8 103 166 36.7 ND<5 U 31.7 104 166 6.6 J ND<5 U 1.6 105 166 40 ND<5 U 35 106 166 14.8 ND<5 U 9.8 107 166 ND<2.5 U ND<5 U -2.5 107 167 40.4 ND<5 U 35.4 108 167 79.6 ND<5 U 74.6 109 167 ND<2.5 U ND<5 U -2.5 109 168 ND<1.25 U ND<5 U -3.75 109 169 ND<1.25 U ND<5 U -3.75 109 170 ND<1.25 U ND<5 U -3.75 109 171 29.7 ND<5 U 24.7 110 171 5.2 J ND<5 U 0.2 111 171 67.1 ND<5 U 62.1 112 171 56.3 ND<5 U 51.3 113 171 70.4 ND<5 U 65.4 114 171 85.3 ND<5 U 80.3 115 171 ND<5 U ND<5 U 0 115 171 ND<5 U ND<5 U 0 115 171 ND<1.25 U ND<5 U -3.75 115 172 ND<1 U ND<5 U -4 115 173 ND<1 U ND<5 U -4 115 174 19.5 ND<5 U 14.5 116 174 26.8 ND<5 U 21.8 117 174 13.8 ND<5 U 8.8 118 174 36.7 ND<5 U 31.7 119 174 6.6 J ND<5 U 1.6 120 174 40 ND<5 U 35 121 174 14.8 ND<5 U 9.8 122 174 ND<2.5 U ND<5 U -2.5 122 175 40.4 ND<5 U 35.4 123 175 79.6 ND<5 U 74.6 124 175 ND<2.5 U ND<5 U -2.5 124 176 ND<1.25 U ND<5 U -3.75 124 177 ND<1.25 U ND<5 U -3.75 124 178 ND<1.25 U ND<5 U -3.75 124 179 29.7 ND<5 U 24.7 125 179 5.2 J ND<5 U 0.2 126 179 67.1 ND<5 U 62.1 127 179 56.3 ND<5 U 51.3 128 179 70.4 ND<5 U 65.4 129 179 85.3 ND<5 U 80.3 130 179 ND<5 U ND<5 U 0 130 179 ND<1.25 U ND<5 U -3.75 130 180 ND<1 U ND<5 U -4 130 181 ND<1 U ND<5 U -4 130 182 19.5 ND<5 U 14.5 131 182 26.8 ND<5 U 21.8 132 182 13.8 ND<5 U 8.8 133 182 36.7 ND<5 U 31.7 134 182 6.6 J ND<5 U 1.6 135 182 40 ND<5 U 35 136 182 14.8 ND<5 U 9.8 137 182 ND<2.5 U ND<5 U -2.5 137 183 40.4 ND<5 U 35.4 138 183 79.6 ND<5 U 74.6 139 183 ND<2.5 U ND<5 U -2.5 139 184 ND<1.25 U ND<5 U -3.75 139 185 ND<1.25 U ND<5 U -3.75 139 186 ND<1.25 U ND<5 U -3.75 139 187 29.7 ND<5 U 24.7 140 187 5.2 J ND<5 U 0.2 141 187 67.1 ND<5 U 62.1 142 187 56.3 ND<5 U 51.3 143 187 70.4 ND<5 U 65.4 144 187 85.3 ND<5 U 80.3 145 187 ND<1.25 U ND<5 U -3.75 145 188 ND<1 U ND<5 U -4 145 189 ND<1 U ND<5 U -4 145 190 19.5 ND<5 U 14.5 146 190 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 29 Alexander Cc CDLF over MSWLF Cobalt, total 26.8 ND<5 U 21.8 147 190 13.8 ND<5 U 8.8 148 190 36.7 ND<5 U 31.7 149 190 6.6 J ND<5 U 1.6 150 190 40 ND<5 U 35 151 190 14.8 ND<5 U 9.8 152 190 ND<2.5 U ND<5 U -2.5 152 191 40.4 ND<5 U 35.4 153 191 79.6 ND<5 U 74.6 154 191 ND<2.5 U ND<5 U -2.5 154 192 ND<1.25 U ND<5 U -3.75 154 193 ND<1.25 U ND<5 U -3.75 154 194 ND<1.25 U ND<5 U -3.75 154 195 29.7 ND<5 U 24.7 155 195 5.2 J ND<5 U 0.2 156 195 67.1 ND<5 U 62.1 157 195 56.3 ND<5 U 51.3 158 195 70.4 ND<5 U 65.4 159 195 85.3 ND<5 U 80.3 160 195 ND<1 U ND<1.25 U -0.25 160 196 ND<1 U ND<1.25 U -0.25 160 197 19.5 ND<1.25 U 18.25 161 197 26.8 ND<1.25 U 25.55 162 197 13.8 ND<1.25 U 12.55 163 197 36.7 ND<1.25 U 35.45 164 197 6.6 J ND<1.25 U 5.35 165 197 40 ND<1.25 U 38.75 166 197 14.8 ND<1.25 U 13.55 167 197 ND<2.5 U ND<1.25 U 1.25 168 197 40.4 ND<1.25 U 39.15 169 197 79.6 ND<1.25 U 78.35 170 197 ND<2.5 U ND<1.25 U 1.25 171 197 ND<1.25 U ND<1.25 U 0 171 197 ND<1.25 U ND<1.25 U 0 171 197 ND<1.25 U ND<1.25 U 0 171 197 29.7 ND<1.25 U 28.45 172 197 5.2 J ND<1.25 U 3.95 173 197 67.1 ND<1.25 U 65.85 174 197 56.3 ND<1.25 U 55.05 175 197 70.4 ND<1.25 U 69.15 176 197 85.3 ND<1.25 U 84.05 177 197 ND<1 U ND<1 U 0 177 197 19.5 ND<1 U 18.5 178 197 26.8 ND<1 U 25.8 179 197 13.8 ND<1 U 12.8 180 197 36.7 ND<1 U 35.7 181 197 6.6 J ND<1 U 5.6 182 197 40 ND<1 U 39 183 197 14.8 ND<1 U 13.8 184 197 ND<2.5 U ND<1 U 1.5 185 197 40.4 ND<1 U 39.4 186 197 79.6 ND<1 U 78.6 187 197 ND<2.5 U ND<1 U 1.5 188 197 ND<1.25 U ND<1 U 0.25 189 197 ND<1.25 U ND<1 U 0.25 190 197 ND<1.25 U ND<1 U 0.25 191 197 29.7 ND<1 U 28.7 192 197 5.2 J ND<1 U 4.2 193 197 67.1 ND<1 U 66.1 194 197 56.3 ND<1 U 55.3 195 197 70.4 ND<1 U 69.4 196 197 85.3 ND<1 U 84.3 197 197 19.5 ND<1 U 18.5 198 197 26.8 ND<1 U 25.8 199 197 13.8 ND<1 U 12.8 200 197 36.7 ND<1 U 35.7 201 197 6.6 J ND<1 U 5.6 202 197 40 ND<1 U 39 203 197 14.8 ND<1 U 13.8 204 197 ND<2.5 U ND<1 U 1.5 205 197 40.4 ND<1 U 39.4 206 197 79.6 ND<1 U 78.6 207 197 ND<2.5 U ND<1 U 1.5 208 197 ND<1.25 U ND<1 U 0.25 209 197 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 30 Alexander Cc CDLF over MSWLF Cobalt, total ND<1.25 U ND<1 U 0.25 210 197 ND<1.25 U ND<1 U 0.25 211 197 29.7 ND<1 U 28.7 212 197 5.2 J ND<1 U 4.2 213 197 67.1 ND<1 U 66.1 214 197 56.3 ND<1 U 55.3 215 197 70.4 ND<1 U 69.4 216 197 85.3 ND<1 U 84.3 217 197 26.8 19.5 7.3 218 197 13.8 19.5 -5.7 218 198 36.7 19.5 17.2 219 198 6.6 J 19.5 -12.9 219 199 40 19.5 20.5 220 199 14.8 19.5 -4.7 220 200 ND<2.5 U 19.5 -17 220 201 40.4 19.5 20.9 221 201 79.6 19.5 60.1 222 201 ND<2.5 U 19.5 -17 222 202 ND<1.25 U 19.5 -18.25 222 203 ND<1.25 U 19.5 -18.25 222 204 ND<1.25 U 19.5 -18.25 222 205 29.7 19.5 10.2 223 205 5.2 J 19.5 -14.3 223 206 67.1 19.5 47.6 224 206 56.3 19.5 36.8 225 206 70.4 19.5 50.9 226 206 85.3 19.5 65.8 227 206 13.8 26.8 -13 227 207 36.7 26.8 9.9 228 207 6.6 J 26.8 -20.2 228 208 40 26.8 13.2 229 208 14.8 26.8 -12 229 209 ND<2.5 U 26.8 -24.3 229 210 40.4 26.8 13.6 230 210 79.6 26.8 52.8 231 210 ND<2.5 U 26.8 -24.3 231 211 ND<1.25 U 26.8 -25.55 231 212 ND<1.25 U 26.8 -25.55 231 213 ND<1.25 U 26.8 -25.55 231 214 29.7 26.8 2.9 232 214 5.2 J 26.8 -21.6 232 215 67.1 26.8 40.3 233 215 56.3 26.8 29.5 234 215 70.4 26.8 43.6 235 215 85.3 26.8 58.5 236 215 36.7 13.8 22.9 237 215 6.6 J 13.8 -7.2 237 216 40 13.8 26.2 238 216 14.8 13.8 1 239 216 ND<2.5 U 13.8 -11.3 239 217 40.4 13.8 26.6 240 217 79.6 13.8 65.8 241 217 ND<2.5 U 13.8 -11.3 241 218 ND<1.25 U 13.8 -12.55 241 219 ND<1.25 U 13.8 -12.55 241 220 ND<1.25 U 13.8 -12.55 241 221 29.7 13.8 15.9 242 221 5.2 J 13.8 -8.6 242 222 67.1 13.8 53.3 243 222 56.3 13.8 42.5 244 222 70.4 13.8 56.6 245 222 85.3 13.8 71.5 246 222 6.6 J 36.7 -30.1 246 223 40 36.7 3.3 247 223 14.8 36.7 -21.9 247 224 ND<2.5 U 36.7 -34.2 247 225 40.4 36.7 3.7 248 225 79.6 36.7 42.9 249 225 ND<2.5 U 36.7 -34.2 249 226 ND<1.25 U 36.7 -35.45 249 227 ND<1.25 U 36.7 -35.45 249 228 ND<1.25 U 36.7 -35.45 249 229 29.7 36.7 -7 249 230 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 31 Alexander Cc CDLF over MSWLF Cobalt, total 5.2 J 36.7 -31.5 249 231 67.1 36.7 30.4 250 231 56.3 36.7 19.6 251 231 70.4 36.7 33.7 252 231 85.3 36.7 48.6 253 231 40 6.6 J 33.4 254 231 14.8 6.6 J 8.2 255 231 ND<2.5 U 6.6 J -4.1 255 232 40.4 6.6 J 33.8 256 232 79.6 6.6 J 73 257 232 ND<2.5 U 6.6 J -4.1 257 233 ND<1.25 U 6.6 J -5.35 257 234 ND<1.25 U 6.6 J -5.35 257 235 ND<1.25 U 6.6 J -5.35 257 236 29.7 6.6 J 23.1 258 236 5.2 J 6.6 J -1.4 258 237 67.1 6.6 J 60.5 259 237 56.3 6.6 J 49.7 260 237 70.4 6.6 J 63.8 261 237 85.3 6.6 J 78.7 262 237 14.8 40 -25.2 262 238 ND<2.5 U 40 -37.5 262 239 40.4 40 0.4 263 239 79.6 40 39.6 264 239 ND<2.5 U 40 -37.5 264 240 ND<1.25 U 40 -38.75 264 241 ND<1.25 U 40 -38.75 264 242 ND<1.25 U 40 -38.75 264 243 29.7 40 -10.3 264 244 5.2 J 40 -34.8 264 245 67.1 40 27.1 265 245 56.3 40 16.3 266 245 70.4 40 30.4 267 245 85.3 40 45.3 268 245 ND<2.5 U 14.8 -12.3 268 246 40.4 14.8 25.6 269 246 79.6 14.8 64.8 270 246 ND<2.5 U 14.8 -12.3 270 247 ND<1.25 U 14.8 -13.55 270 248 ND<1.25 U 14.8 -13.55 270 249 ND<1.25 U 14.8 -13.55 270 250 29.7 14.8 14.9 271 250 5.2 J 14.8 -9.6 271 251 67.1 14.8 52.3 272 251 56.3 14.8 41.5 273 251 70.4 14.8 55.6 274 251 85.3 14.8 70.5 275 251 40.4 ND<2.5 U 37.9 276 251 79.6 ND<2.5 U 77.1 277 251 ND<2.5 U ND<2.5 U 0 277 251 ND<1.25 U ND<2.5 U -1.25 277 252 ND<1.25 U ND<2.5 U -1.25 277 253 ND<1.25 U ND<2.5 U -1.25 277 254 29.7 ND<2.5 U 27.2 278 254 5.2 J ND<2.5 U 2.7 279 254 67.1 ND<2.5 U 64.6 280 254 56.3 ND<2.5 U 53.8 281 254 70.4 ND<2.5 U 67.9 282 254 85.3 ND<2.5 U 82.8 283 254 79.6 40.4 39.2 284 254 ND<2.5 U 40.4 -37.9 284 255 ND<1.25 U 40.4 -39.15 284 256 ND<1.25 U 40.4 -39.15 284 257 ND<1.25 U 40.4 -39.15 284 258 29.7 40.4 -10.7 284 259 5.2 J 40.4 -35.2 284 260 67.1 40.4 26.7 285 260 56.3 40.4 15.9 286 260 70.4 40.4 30 287 260 85.3 40.4 44.9 288 260 ND<2.5 U 79.6 -77.1 288 261 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 32 Alexander Cc CDLF over MSWLF Cobalt, total ND<1.25 U 79.6 -78.35 288 262 ND<1.25 U 79.6 -78.35 288 263 ND<1.25 U 79.6 -78.35 288 264 29.7 79.6 -49.9 288 265 5.2 J 79.6 -74.4 288 266 67.1 79.6 -12.5 288 267 56.3 79.6 -23.3 288 268 70.4 79.6 -9.2 288 269 85.3 79.6 5.7 289 269 ND<1.25 U ND<2.5 U -1.25 289 270 ND<1.25 U ND<2.5 U -1.25 289 271 ND<1.25 U ND<2.5 U -1.25 289 272 29.7 ND<2.5 U 27.2 290 272 5.2 J ND<2.5 U 2.7 291 272 67.1 ND<2.5 U 64.6 292 272 56.3 ND<2.5 U 53.8 293 272 70.4 ND<2.5 U 67.9 294 272 85.3 ND<2.5 U 82.8 295 272 ND<1.25 U ND<1.25 U 0 295 272 ND<1.25 U ND<1.25 U 0 295 272 29.7 ND<1.25 U 28.45 296 272 5.2 J ND<1.25 U 3.95 297 272 67.1 ND<1.25 U 65.85 298 272 56.3 ND<1.25 U 55.05 299 272 70.4 ND<1.25 U 69.15 300 272 85.3 ND<1.25 U 84.05 301 272 ND<1.25 U ND<1.25 U 0 301 272 29.7 ND<1.25 U 28.45 302 272 5.2 J ND<1.25 U 3.95 303 272 67.1 ND<1.25 U 65.85 304 272 56.3 ND<1.25 U 55.05 305 272 70.4 ND<1.25 U 69.15 306 272 85.3 ND<1.25 U 84.05 307 272 29.7 ND<1.25 U 28.45 308 272 5.2 J ND<1.25 U 3.95 309 272 67.1 ND<1.25 U 65.85 310 272 56.3 ND<1.25 U 55.05 311 272 70.4 ND<1.25 U 69.15 312 272 85.3 ND<1.25 U 84.05 313 272 5.2 J 29.7 -24.5 313 273 67.1 29.7 37.4 314 273 56.3 29.7 26.6 315 273 70.4 29.7 40.7 316 273 85.3 29.7 55.6 317 273 67.1 5.2 J 61.9 318 273 56.3 5.2 J 51.1 319 273 70.4 5.2 J 65.2 320 273 85.3 5.2 J 80.1 321 273 56.3 67.1 -10.8 321 274 70.4 67.1 3.3 322 274 85.3 67.1 18.2 323 274 70.4 56.3 14.1 324 274 85.3 56.3 29 325 274 85.3 70.4 14.9 326 274 S Statistic = 326 - 274 = 52 Tied GroiValue Members 1 40 2 2 5 7 3 1.25 4 4 1 2 5 2.5 2 Time Period Observations Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 33 Alexander Cc CDLF over MSWLF Cobalt, total 12/11/2000 1 6/12/2001 1 12/28/2001 1 6/12/2002 1 1 /3/2003 1 6/25/2003 1 12/12/2003 1 6/15/2004 1 12/30/2004 1 6/23/2005 1 1 /12/2006 1 7/7/2006 1 12/15/2006 1 6/28/2007 1 12/19/2007 1 6/19/2008 1 6/25/2009 1 12/15/2009 1 7/8/2010 1 12/9/2010 1 7/1 /2011 1 12/15/2011 1 6/14/2012 1 12/11/2012 1 6/28/2013 1 12/17/2013 1 6/25/2014 1 12/4/2014 1 6/18/2015 1 1 /7/2016 1 7/1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A = 1008 B=0 C=234 D=0 E=60 F=0 a = 97020 b = 385560 c = 2520 Group Variance = 5334 Z-Score = 0.698303 Comparison Level at 95% confidence level = 1.65463 (upward trend) 0.698303 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 34 Alexander Cc CDLF over MSWLF Cobalt, total Cobalt, total Intra•Well ShewharbCUSUM Control Chart of MW15 Ra Iiro M=9nAA1 Q•R—lim.w flay=19A;Q5, k=1•h=5•RCI =A; u 5 4 3 baseline mean=2.08819 2 . 9 1 1701 .0306 4.20618 .6027 .68 .69883 0 2.97041 3.2884 2.62467 1.88707 2.6 63 0 16291 0.9162910.223144 0.223144 0.2 3144 3.3911 1.64866 1 2 b, I I I J— I !., I }„ I I I I I !o I ✓_ I • Standardized mean CUSUM Sample Date 1 SCL 4.44617 Non -Detects Replaced with 1/2 DL Natural Logarithm Transformation Page 35 Alexander Co CDLF over MSWLF Cumulative VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-1 B) Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xi Xk Xj - Xk PositivesNegatives 36.8 84.83 -48.03 0 1 33.76 84.83 -51.07 0 2 41.36 84.83 -43.47 0 3 35.7 84.83 -49.13 0 4 44.37 84.83 -40.46 0 5 32.61 84.83 -52.22 0 6 42.67 84.83 -42.16 0 7 ND<0 84.83 -84.83 0 8 21.71 84.83 -63.12 0 9 17.19 84.83 -67.64 0 10 16.35 84.83 -68.48 0 11 21.87 84.83 -62.96 0 12 13.66 84.83 -71.17 0 13 8.45 84.83 -76.38 0 14 13.51 84.83 -71.32 0 15 8.35 84.83 -76.48 0 16 ND<0 84.83 -84.83 0 17 7.2 84.83 -77.63 0 18 2.31 84.83 -82.52 0 19 33.76 36.8 -3.04 0 20 41.36 36.8 4.56 1 20 35.7 36.8 -1.1 1 21 44.37 36.8 7.57 2 21 32.61 36.8 -4.19 2 22 42.67 36.8 5.87 3 22 ND<0 36.8 -36.8 3 23 21.71 36.8 -15.09 3 24 17.19 36.8 -19.61 3 25 16.35 36.8 -20.45 3 26 21.87 36.8 -14.93 3 27 13.66 36.8 -23.14 3 28 8.45 36.8 -28.35 3 29 13.51 36.8 -23.29 3 30 8.35 36.8 -28.45 3 31 ND<0 36.8 -36.8 3 32 7.2 36.8 -29.6 3 33 2.31 36.8 -34.49 3 34 41.36 33.76 7.6 4 34 35.7 33.76 1.94 5 34 44.37 33.76 10.61 6 34 32.61 33.76 -1.15 6 35 42.67 33.76 8.91 7 35 ND<0 33.76 -33.76 7 36 21.71 33.76 -12.05 7 37 17.19 33.76 -16.57 7 38 16.35 33.76 -17.41 7 39 21.87 33.76 -11.89 7 40 13.66 33.76 -20.1 7 41 8.45 33.76 -25.31 7 42 13.51 33.76 -20.25 7 43 8.35 33.76 -25.41 7 44 ND<0 33.76 -33.76 7 45 7.2 33.76 -26.56 7 46 2.31 33.76 -31.45 7 47 35.7 41.36 -5.66 7 48 44.37 41.36 3.01 8 48 32.61 41.36 -8.75 8 49 42.67 41.36 1.31 9 49 ND<0 41.36 -41.36 9 50 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 1 Alexander Cc CDLF over MSWLF VOCs 21.71 41.36 -19.65 9 51 17.19 41.36 -24.17 9 52 16.35 41.36 -25.01 9 53 21.87 41.36 -19.49 9 54 13.66 41.36 -27.7 9 55 8.45 41.36 -32.91 9 56 13.51 41.36 -27.85 9 57 8.35 41.36 -33.01 9 58 ND<0 41.36 -41.36 9 59 7.2 41.36 -34.16 9 60 2.31 41.36 -39.05 9 61 44.37 35.7 8.67 10 61 32.61 35.7 -3.09 10 62 42.67 35.7 6.97 11 62 ND<0 35.7 -35.7 11 63 21.71 35.7 -13.99 11 64 17.19 35.7 -18.51 11 65 16.35 35.7 -19.35 11 66 21.87 35.7 -13.83 11 67 13.66 35.7 -22.04 11 68 8.45 35.7 -27.25 11 69 13.51 35.7 -22.19 11 70 8.35 35.7 -27.35 11 71 ND<0 35.7 -35.7 11 72 7.2 35.7 -28.5 11 73 2.31 35.7 -33.39 11 74 32.61 44.37 -11.76 11 75 42.67 44.37 -1.7 11 76 ND<0 44.37 -44.37 11 77 21.71 44.37 -22.66 11 78 17.19 44.37 -27.18 11 79 16.35 44.37 -28.02 11 80 21.87 44.37 -22.5 11 81 13.66 44.37 -30.71 11 82 8.45 44.37 -35.92 11 83 13.51 44.37 -30.86 11 84 8.35 44.37 -36.02 11 85 ND<0 44.37 -44.37 11 86 7.2 44.37 -37.17 11 87 2.31 44.37 -42.06 11 88 42.67 32.61 10.06 12 88 ND<0 32.61 -32.61 12 89 21.71 32.61 -10.9 12 90 17.19 32.61 -15.42 12 91 16.35 32.61 -16.26 12 92 21.87 32.61 -10.74 12 93 13.66 32.61 -18.95 12 94 8.45 32.61 -24.16 12 95 13.51 32.61 -19.1 12 96 8.35 32.61 -24.26 12 97 ND<0 32.61 -32.61 12 98 7.2 32.61 -25.41 12 99 2.31 32.61 -30.3 12 100 ND<0 42.67 -42.67 12 101 21.71 42.67 -20.96 12 102 17.19 42.67 -25.48 12 103 16.35 42.67 -26.32 12 104 21.87 42.67 -20.8 12 105 13.66 42.67 -29.01 12 106 8.45 42.67 -34.22 12 107 13.51 42.67 -29.16 12 108 8.35 42.67 -34.32 12 109 ND<0 42.67 -42.67 12 110 7.2 42.67 -35.47 12 111 2.31 42.67 -40.36 12 112 21.71 ND<0 21.71 13 112 17.19 ND<0 17.19 14 112 16.35 ND<0 16.35 15 112 21.87 ND<0 21.87 16 112 13.66 ND<0 13.66 17 112 8.45 ND<0 8.45 18 112 13.51 ND<0 13.51 19 112 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 2 Alexander Cc CDLF over MSWLF VOCS 8.35 ND<0 8.35 20 112 ND<0 ND<0 0 20 112 7.2 ND<0 7.2 21 112 2.31 ND<0 2.31 22 112 17.19 21.71 -4.52 22 113 16.35 21.71 -5.36 22 114 21.87 21.71 0.16 23 114 13.66 21.71 -8.05 23 115 8.45 21.71 -13.26 23 116 13.51 21.71 -8.2 23 117 8.35 21.71 -13.36 23 118 ND<0 21.71 -21.71 23 119 7.2 21.71 -14.51 23 120 2.31 21.71 -19.4 23 121 16.35 17.19 -0.84 23 122 21.87 17.19 4.68 24 122 13.66 17.19 -3.53 24 123 8.45 17.19 -8.74 24 124 13.51 17.19 -3.68 24 125 8.35 17.19 -8.84 24 126 ND<0 17.19 -17.19 24 127 7.2 17.19 -9.99 24 128 2.31 17.19 -14.88 24 129 21.87 16.35 5.52 25 129 13.66 16.35 -2.69 25 130 8.45 16.35 -7.9 25 131 13.51 16.35 -2.84 25 132 8.35 16.35 -8 25 133 ND<0 16.35 -16.35 25 134 7.2 16.35 -9.15 25 135 2.31 16.35 -14.04 25 136 13.66 21.87 -8.21 25 137 8.45 21.87 -13.42 25 138 13.51 21.87 -8.36 25 139 8.35 21.87 -13.52 25 140 ND<0 21.87 -21.87 25 141 7.2 21.87 -14.67 25 142 2.31 21.87 -19.56 25 143 8.45 13.66 -5.21 25 144 13.51 13.66 -0.15 25 145 8.35 13.66 -5.31 25 146 ND<0 13.66 -13.66 25 147 7.2 13.66 -6.46 25 148 2.31 13.66 -11.35 25 149 13.51 8.45 5.06 26 149 8.35 8.45 -0.1 26 150 ND<0 8.45 -8.45 26 151 7.2 8.45 -1.25 26 152 2.31 8.45 -6.14 26 153 8.35 13.51 -5.16 26 154 ND<0 13.51 -13.51 26 155 7.2 13.51 -6.31 26 156 2.31 13.51 -11.2 26 157 ND<0 8.35 -8.35 26 158 7.2 8.35 -1.15 26 159 2.31 8.35 -6.04 26 160 7.2 ND<0 7.2 27 160 2.31 ND<0 2.31 28 160 2.31 7.2 -4.89 28 161 S Statistic = 28 - 161 = -133 Tied GroiValue Members 1 0 2 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 3 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A=18 B=0 C=0 D=0 E=2 F=0 a = 17100 b = 61560 c = 760 Group Variance = 949 Z-Score =-4.2849 Comparison Level at 95% confidence level =-1.65463 (downward trend) -4.2849 <-1.65463 indicating a downward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 4 Alexander Co CDLF over MSWLF VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-16) Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 58.96 74.55 -15.59 0 1 63.2 74.55 -11.35 0 2 75.84 74.55 1.29 1 2 ND<0 74.55 -74.55 1 3 79.21 74.55 4.66 2 3 62.32 74.55 -12.23 2 4 59.16 74.55 -15.39 2 5 ND<0 74.55 -74.55 2 6 58.34 74.55 -16.21 2 7 71.17 74.55 -3.38 2 8 89.27 74.55 14.72 3 8 76.95 74.55 2.4 4 8 67.17 74.55 -7.38 4 9 74.17 74.55 -0.38 4 10 72.75 74.55 -1.8 4 11 55.67 74.55 -18.88 4 12 ND<0 74.55 -74.55 4 13 ND<0 74.55 -74.55 4 14 49.71 74.55 -24.84 4 15 63.2 58.96 4.24 5 15 75.84 58.96 16.88 6 15 ND<0 58.96 -58.96 6 16 79.21 58.96 20.25 7 16 62.32 58.96 3.36 8 16 59.16 58.96 0.2 9 16 ND<0 58.96 -58.96 9 17 58.34 58.96 -0.62 9 18 71.17 58.96 12.21 10 18 89.27 58.96 30.31 11 18 76.95 58.96 17.99 12 18 67.17 58.96 8.21 13 18 74.17 58.96 15.21 14 18 72.75 58.96 13.79 15 18 55.67 58.96 -3.29 15 19 ND<0 58.96 -58.96 15 20 ND<0 58.96 -58.96 15 21 49.71 58.96 -9.25 15 22 75.84 63.2 12.64 16 22 ND<0 63.2 -63.2 16 23 79.21 63.2 16.01 17 23 62.32 63.2 -0.88 17 24 59.16 63.2 -4.04 17 25 ND<0 63.2 -63.2 17 26 58.34 63.2 -4.86 17 27 71.17 63.2 7.97 18 27 89.27 63.2 26.07 19 27 76.95 63.2 13.75 20 27 67.17 63.2 3.97 21 27 74.17 63.2 10.97 22 27 72.75 63.2 9.55 23 27 55.67 63.2 -7.53 23 28 ND<0 63.2 -63.2 23 29 ND<0 63.2 -63.2 23 30 49.71 63.2 -13.49 23 31 ND<0 75.84 -75.84 23 32 79.21 75.84 3.37 24 32 62.32 75.84 -13.52 24 33 59.16 75.84 -16.68 24 34 ND<0 75.84 -75.84 24 35 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 5 Alexander Cc CDLF over MSWLF VOCs 58.34 75.84 -17.5 24 36 71.17 75.84 -4.67 24 37 89.27 75.84 13.43 25 37 76.95 75.84 1.11 26 37 67.17 75.84 -8.67 26 38 74.17 75.84 -1.67 26 39 72.75 75.84 -3.09 26 40 55.67 75.84 -20.17 26 41 ND<0 75.84 -75.84 26 42 ND<0 75.84 -75.84 26 43 49.71 75.84 -26.13 26 44 79.21 ND<0 79.21 27 44 62.32 ND<0 62.32 28 44 59.16 ND<0 59.16 29 44 ND<0 ND<0 0 29 44 58.34 ND<0 58.34 30 44 71.17 ND<0 71.17 31 44 89.27 ND<0 89.27 32 44 76.95 ND<0 76.95 33 44 67.17 ND<0 67.17 34 44 74.17 ND<0 74.17 35 44 72.75 ND<0 72.75 36 44 55.67 ND<0 55.67 37 44 ND<0 ND<0 0 37 44 ND<0 ND<0 0 37 44 49.71 ND<0 49.71 38 44 62.32 79.21 -16.89 38 45 59.16 79.21 -20.05 38 46 ND<0 79.21 -79.21 38 47 58.34 79.21 -20.87 38 48 71.17 79.21 -8.04 38 49 89.27 79.21 10.06 39 49 76.95 79.21 -2.26 39 50 67.17 79.21 -12.04 39 51 74.17 79.21 -5.04 39 52 72.75 79.21 -6.46 39 53 55.67 79.21 -23.54 39 54 ND<0 79.21 -79.21 39 55 ND<0 79.21 -79.21 39 56 49.71 79.21 -29.5 39 57 59.16 62.32 -3.16 39 58 ND<0 62.32 -62.32 39 59 58.34 62.32 -3.98 39 60 71.17 62.32 8.85 40 60 89.27 62.32 26.95 41 60 76.95 62.32 14.63 42 60 67.17 62.32 4.85 43 60 74.17 62.32 11.85 44 60 72.75 62.32 10.43 45 60 55.67 62.32 -6.65 45 61 ND<0 62.32 -62.32 45 62 ND<0 62.32 -62.32 45 63 49.71 62.32 -12.61 45 64 ND<0 59.16 -59.16 45 65 58.34 59.16 -0.82 45 66 71.17 59.16 12.01 46 66 89.27 59.16 30.11 47 66 76.95 59.16 17.79 48 66 67.17 59.16 8.01 49 66 74.17 59.16 15.01 50 66 72.75 59.16 13.59 51 66 55.67 59.16 -3.49 51 67 ND<0 59.16 -59.16 51 68 ND<0 59.16 -59.16 51 69 49.71 59.16 -9.45 51 70 58.34 ND<0 58.34 52 70 71.17 ND<0 71.17 53 70 89.27 ND<0 89.27 54 70 76.95 ND<0 76.95 55 70 67.17 ND<0 67.17 56 70 74.17 ND<0 74.17 57 70 72.75 ND<0 72.75 58 70 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 6 Alexander Cc CDLF over MSWLF VOCs 55.67 ND<0 55.67 59 70 ND<0 ND<0 0 59 70 ND<0 ND<0 0 59 70 49.71 ND<0 49.71 60 70 71.17 58.34 12.83 61 70 89.27 58.34 30.93 62 70 76.95 58.34 18.61 63 70 67.17 58.34 8.83 64 70 74.17 58.34 15.83 65 70 72.75 58.34 14.41 66 70 55.67 58.34 -2.67 66 71 ND<0 58.34 -58.34 66 72 ND<0 58.34 -58.34 66 73 49.71 58.34 -8.63 66 74 89.27 71.17 18.1 67 74 76.95 71.17 5.78 68 74 67.17 71.17 -4 68 75 74.17 71.17 3 69 75 72.75 71.17 1.58 70 75 55.67 71.17 -15.5 70 76 ND<0 71.17 -71.17 70 77 ND<0 71.17 -71.17 70 78 49.71 71.17 -21.46 70 79 76.95 89.27 -12.32 70 80 67.17 89.27 -22.1 70 81 74.17 89.27 -15.1 70 82 72.75 89.27 -16.52 70 83 55.67 89.27 -33.6 70 84 ND<0 89.27 -89.27 70 85 ND<0 89.27 -89.27 70 86 49.71 89.27 -39.56 70 87 67.17 76.95 -9.78 70 88 74.17 76.95 -2.78 70 89 72.75 76.95 -4.2 70 90 55.67 76.95 -21.28 70 91 ND<0 76.95 -76.95 70 92 ND<0 76.95 -76.95 70 93 49.71 76.95 -27.24 70 94 74.17 67.17 7 71 94 72.75 67.17 5.58 72 94 55.67 67.17 -11.5 72 95 ND<0 67.17 -67.17 72 96 ND<0 67.17 -67.17 72 97 49.71 67.17 -17.46 72 98 72.75 74.17 -1.42 72 99 55.67 74.17 -18.5 72 100 ND<0 74.17 -74.17 72 101 ND<0 74.17 -74.17 72 102 49.71 74.17 -24.46 72 103 55.67 72.75 -17.08 72 104 ND<0 72.75 -72.75 72 105 ND<0 72.75 -72.75 72 106 49.71 72.75 -23.04 72 107 ND<0 55.67 -55.67 72 108 ND<0 55.67 -55.67 72 109 49.71 55.67 -5.96 72 110 ND<0 ND<0 0 72 110 49.71 ND<0 49.71 73 110 49.71 ND<0 49.71 74 110 S Statistic = 74 - 110 = -36 Tied GroiValue Members 1 0 4 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 7 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A = 156 B=0 C=24 D=0 E=12 IF a = 17100 b = 61560 c = 760 Group Variance = 941.333 Z-Score =-1.14077 Comparison Level at 95% confidence level = 1.65463 (upward trend) -1.14077 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 8 Alexander Cc CDLF over MSWLF VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-24) Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 43 63.53 -20.53 0 1 32.22 63.53 -31.31 0 2 76.57 63.53 13.04 1 2 51.69 63.53 -11.84 1 3 68.44 63.53 4.91 2 3 ND<0 63.53 -63.53 2 4 61.89 63.53 -1.64 2 5 58.98 63.53 -4.55 2 6 49.41 63.53 -14.12 2 7 62.79 63.53 -0.74 2 8 54.44 63.53 -9.09 2 9 ND<0 63.53 -63.53 2 10 ND<0 63.53 -63.53 2 11 32.385 63.53 -31.145 2 12 53.78 63.53 -9.75 2 13 45.88 63.53 -17.65 2 14 42.54 63.53 -20.99 2 15 23.82 63.53 -39.71 2 16 19.82 63.53 -43.71 2 17 32.22 43 -10.78 2 18 76.57 43 33.57 3 18 51.69 43 8.69 4 18 68.44 43 25.44 5 18 ND<0 43 -43 5 19 61.89 43 18.89 6 19 58.98 43 15.98 7 19 49.41 43 6.41 8 19 62.79 43 19.79 9 19 54.44 43 11.44 10 19 ND<0 43 -43 10 20 ND<0 43 -43 10 21 32.385 43 -10.615 10 22 53.78 43 10.78 11 22 45.88 43 2.88 12 22 42.54 43 -0.46 12 23 23.82 43 -19.18 12 24 19.82 43 -23.18 12 25 76.57 32.22 44.35 13 25 51.69 32.22 19.47 14 25 68.44 32.22 36.22 15 25 ND<0 32.22 -32.22 15 26 61.89 32.22 29.67 16 26 58.98 32.22 26.76 17 26 49.41 32.22 17.19 18 26 62.79 32.22 30.57 19 26 54.44 32.22 22.22 20 26 ND<0 32.22 -32.22 20 27 ND<0 32.22 -32.22 20 28 32.385 32.22 0.165 21 28 53.78 32.22 21.56 22 28 45.88 32.22 13.66 23 28 42.54 32.22 10.32 24 28 23.82 32.22 -8.4 24 29 19.82 32.22 -12.4 24 30 51.69 76.57 -24.88 24 31 68.44 76.57 -8.13 24 32 ND<0 76.57 -76.57 24 33 61.89 76.57 -14.68 24 34 58.98 76.57 -17.59 24 35 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 9 Alexander Co CDLF over MSWLF VOCs 49.41 76.57 -27.16 24 36 62.79 76.57 -13.78 24 37 54.44 76.57 -22.13 24 38 ND<0 76.57 -76.57 24 39 ND<0 76.57 -76.57 24 40 32.385 76.57 -44.185 24 41 53.78 76.57 -22.79 24 42 45.88 76.57 -30.69 24 43 42.54 76.57 -34.03 24 44 23.82 76.57 -52.75 24 45 19.82 76.57 -56.75 24 46 68.44 51.69 16.75 25 46 ND<0 51.69 -51.69 25 47 61.89 51.69 10.2 26 47 58.98 51.69 7.29 27 47 49.41 51.69 -2.28 27 48 62.79 51.69 11.1 28 48 54.44 51.69 2.75 29 48 ND<0 51.69 -51.69 29 49 ND<0 51.69 -51.69 29 50 32.385 51.69 -19.305 29 51 53.78 51.69 2.09 30 51 45.88 51.69 -5.81 30 52 42.54 51.69 -9.15 30 53 23.82 51.69 -27.87 30 54 19.82 51.69 -31.87 30 55 ND<0 68.44 -68.44 30 56 61.89 68.44 -6.55 30 57 58.98 68.44 -9.46 30 58 49.41 68.44 -19.03 30 59 62.79 68.44 -5.65 30 60 54.44 68.44 -14 30 61 ND<0 68.44 -68.44 30 62 ND<0 68.44 -68.44 30 63 32.385 68.44 -36.055 30 64 53.78 68.44 -14.66 30 65 45.88 68.44 -22.56 30 66 42.54 68.44 -25.9 30 67 23.82 68.44 -44.62 30 68 19.82 68.44 -48.62 30 69 61.89 ND<0 61.89 31 69 58.98 ND<0 58.98 32 69 49.41 ND<0 49.41 33 69 62.79 ND<0 62.79 34 69 54.44 ND<0 54.44 35 69 ND<0 ND<0 0 35 69 ND<0 ND<0 0 35 69 32.385 ND<0 32.385 36 69 53.78 ND<0 53.78 37 69 45.88 ND<0 45.88 38 69 42.54 ND<0 42.54 39 69 23.82 ND<0 23.82 40 69 19.82 ND<0 19.82 41 69 58.98 61.89 -2.91 41 70 49.41 61.89 -12.48 41 71 62.79 61.89 0.9 42 71 54.44 61.89 -7.45 42 72 ND<0 61.89 -61.89 42 73 ND<0 61.89 -61.89 42 74 32.385 61.89 -29.505 42 75 53.78 61.89 -8.11 42 76 45.88 61.89 -16.01 42 77 42.54 61.89 -19.35 42 78 23.82 61.89 -38.07 42 79 19.82 61.89 -42.07 42 80 49.41 58.98 -9.57 42 81 62.79 58.98 3.81 43 81 54.44 58.98 -4.54 43 82 ND<0 58.98 -58.98 43 83 ND<0 58.98 -58.98 43 84 32.385 58.98 -26.595 43 85 53.78 58.98 -5.2 43 86 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 10 Alexander Cc CDLF over MSWLF VOCS 45.88 58.98 -13.1 43 87 42.54 58.98 -16.44 43 88 23.82 58.98 -35.16 43 89 19.82 58.98 -39.16 43 90 62.79 49.41 13.38 44 90 54.44 49.41 5.03 45 90 ND<0 49.41 -49.41 45 91 ND<0 49.41 -49.41 45 92 32.385 49.41 -17.025 45 93 53.78 49.41 4.37 46 93 45.88 49.41 -3.53 46 94 42.54 49.41 -6.87 46 95 23.82 49.41 -25.59 46 96 19.82 49.41 -29.59 46 97 54.44 62.79 -8.35 46 98 ND<0 62.79 -62.79 46 99 ND<0 62.79 -62.79 46 100 32.385 62.79 -30.405 46 101 53.78 62.79 -9.01 46 102 45.88 62.79 -16.91 46 103 42.54 62.79 -20.25 46 104 23.82 62.79 -38.97 46 105 19.82 62.79 -42.97 46 106 ND<0 54.44 -54.44 46 107 ND<0 54.44 -54.44 46 108 32.385 54.44 -22.055 46 109 53.78 54.44 -0.66 46 110 45.88 54.44 -8.56 46 111 42.54 54.44 -11.9 46 112 23.82 54.44 -30.62 46 113 19.82 54.44 -34.62 46 114 ND<0 ND<0 0 46 114 32.385 ND<0 32.385 47 114 53.78 ND<0 53.78 48 114 45.88 ND<0 45.88 49 114 42.54 ND<0 42.54 50 114 23.82 ND<0 23.82 51 114 19.82 ND<0 19.82 52 114 32.385 ND<0 32.385 53 114 53.78 ND<0 53.78 54 114 45.88 ND<0 45.88 55 114 42.54 ND<0 42.54 56 114 23.82 ND<0 23.82 57 114 19.82 ND<0 19.82 58 114 53.78 32.385 21.395 59 114 45.88 32.385 13.495 60 114 42.54 32.385 10.155 61 114 23.82 32.385 -8.565 61 115 19.82 32.385 -12.565 61 116 45.88 53.78 -7.9 61 117 42.54 53.78 -11.24 61 118 23.82 53.78 -29.96 61 119 19.82 53.78 -33.96 61 120 42.54 45.88 -3.34 61 121 23.82 45.88 -22.06 61 122 19.82 45.88 -26.06 61 123 23.82 42.54 -18.72 61 124 19.82 42.54 -22.72 61 125 19.82 23.82 -4 61 126 S Statistic = 61 - 126 = -65 Tied GroiValue Members 1 0 3 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 11 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A=66 B=0 C=6 D=0 E=6 F=0 a = 17100 b = 61560 c = 760 Group Variance = 946.333 Z-Score =-2.08045 Comparison Level at 95% confidence level = 1.65463 (upward trend) -2.08045 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 12 Alexander Co CDLF over MSWLF VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (MW-26) Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xi Xk Xj - Xk PositivesNegatives 129.48 ND<0 129.48 1 0 136.41 ND<0 136.41 2 0 ND<0 ND<0 0 2 0 137.92 ND<0 137.92 3 0 124.62 ND<0 124.62 4 0 112.2 ND<0 112.2 5 0 128.11 ND<0 128.11 6 0 112.47 ND<0 112.47 7 0 95.58 ND<0 95.58 8 0 128.48 ND<0 128.48 9 0 133.23 ND<0 133.23 10 0 134.77 ND<0 134.77 11 0 69.28 ND<0 69.28 12 0 ND<0 ND<0 0 12 0 ND<0 ND<0 0 12 0 72.54 ND<0 72.54 13 0 94.62 ND<0 94.62 14 0 91.51 ND<0 91.51 15 0 ND<0 ND<0 0 15 0 136.41 129.48 6.93 16 0 ND<0 129.48-129.48 16 1 137.92 129.48 8.44 17 1 124.62 129.48 -4.86 17 2 112.2 129.48 -17.28 17 3 128.11 129.48 -1.37 17 4 112.47 129.48 -17.01 17 5 95.58 129.48 -33.9 17 6 128.48 129.48 -1 17 7 133.23 129.48 3.75 18 7 134.77 129.48 5.29 19 7 69.28 129.48 -60.2 19 8 ND<0 129.48-129.48 19 9 ND<0 129.48-129.48 19 10 72.54 129.48 -56.94 19 11 94.62 129.48 -34.86 19 12 91.51 129.48 -37.97 19 13 ND<0 129.48-129.48 19 14 ND<0 136.41-136.41 19 15 137.92 136.41 1.51 20 15 124.62 136.41 -11.79 20 16 112.2 136.41 -24.21 20 17 128.11 136.41 -8.3 20 18 112.47 136.41 -23.94 20 19 95.58 136.41 -40.83 20 20 128.48 136.41 -7.93 20 21 133.23 136.41 -3.18 20 22 134.77 136.41 -1.64 20 23 69.28 136.41 -67.13 20 24 ND<0 136.41-136.41 20 25 ND<0 136.41-136.41 20 26 72.54 136.41 -63.87 20 27 94.62 136.41 -41.79 20 28 91.51 136.41 -44.9 20 29 ND<0 136.41-136.41 20 30 137.92 ND<0 137.92 21 30 124.62 ND<0 124.62 22 30 112.2 ND<0 112.2 23 30 128.11 ND<0 128.11 24 30 112.47 ND<0 112.47 25 30 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 13 Alexander Cc CDLF over MSWLF VOCs 95.58 ND<0 95.58 26 30 128.48 ND<0 128.48 27 30 133.23 ND<0 133.23 28 30 134.77 ND<0 134.77 29 30 69.28 ND<0 69.28 30 30 ND<0 ND<0 0 30 30 ND<0 ND<0 0 30 30 72.54 ND<0 72.54 31 30 94.62 ND<0 94.62 32 30 91.51 ND<0 91.51 33 30 ND<0 ND<0 0 33 30 124.62 137.92 -13.3 33 31 112.2 137.92 -25.72 33 32 128.11 137.92 -9.81 33 33 112.47 137.92 -25.45 33 34 95.58 137.92 -42.34 33 35 128.48 137.92 -9.44 33 36 133.23 137.92 -4.69 33 37 134.77 137.92 -3.15 33 38 69.28 137.92 -68.64 33 39 ND<0 137.92 -137.92 33 40 ND<0 137.92 -137.92 33 41 72.54 137.92 -65.38 33 42 94.62 137.92 -43.3 33 43 91.51 137.92 -46.41 33 44 ND<0 137.92 -137.92 33 45 112.2 124.62 -12.42 33 46 128.11 124.62 3.49 34 46 112.47 124.62 -12.15 34 47 95.58 124.62 -29.04 34 48 128.48 124.62 3.86 35 48 133.23 124.62 8.61 36 48 134.77 124.62 10.15 37 48 69.28 124.62 -55.34 37 49 ND<0 124.62 -124.62 37 50 ND<0 124.62 -124.62 37 51 72.54 124.62 -52.08 37 52 94.62 124.62 -30 37 53 91.51 124.62 -33.11 37 54 ND<0 124.62 -124.62 37 55 128.11 112.2 15.91 38 55 112.47 112.2 0.27 39 55 95.58 112.2 -16.62 39 56 128.48 112.2 16.28 40 56 133.23 112.2 21.03 41 56 134.77 112.2 22.57 42 56 69.28 112.2 -42.92 42 57 ND<0 112.2 -112.2 42 58 ND<0 112.2 -112.2 42 59 72.54 112.2 -39.66 42 60 94.62 112.2 -17.58 42 61 91.51 112.2 -20.69 42 62 ND<0 112.2 -112.2 42 63 112.47 128.11 -15.64 42 64 95.58 128.11 -32.53 42 65 128.48 128.11 0.37 43 65 133.23 128.11 5.12 44 65 134.77 128.11 6.66 45 65 69.28 128.11 -58.83 45 66 ND<0 128.11 -128.11 45 67 ND<0 128.11 -128.11 45 68 72.54 128.11 -55.57 45 69 94.62 128.11 -33.49 45 70 91.51 128.11 -36.6 45 71 ND<0 128.11 -128.11 45 72 95.58 112.47 -16.89 45 73 128.48 112.47 16.01 46 73 133.23 112.47 20.76 47 73 134.77 112.47 22.3 48 73 69.28 112.47 -43.19 48 74 ND<0 112.47 -112.47 48 75 ND<0 112.47 -112.47 48 76 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 14 Alexander Cc CDLF over MSWLF VOCs 72.54 112.47 -39.93 48 77 94.62 112.47 -17.85 48 78 91.51 112.47 -20.96 48 79 ND<0 112.47 -112.47 48 80 128.48 95.58 32.9 49 80 133.23 95.58 37.65 50 80 134.77 95.58 39.19 51 80 69.28 95.58 -26.3 51 81 ND<0 95.58 -95.58 51 82 ND<0 95.58 -95.58 51 83 72.54 95.58 -23.04 51 84 94.62 95.58 -0.96 51 85 91.51 95.58 -4.07 51 86 ND<0 95.58 -95.58 51 87 133.23 128.48 4.75 52 87 134.77 128.48 6.29 53 87 69.28 128.48 -59.2 53 88 ND<0 128.48 -128.48 53 89 ND<0 128.48 -128.48 53 90 72.54 128.48 -55.94 53 91 94.62 128.48 -33.86 53 92 91.51 128.48 -36.97 53 93 ND<0 128.48 -128.48 53 94 134.77 133.23 1.54 54 94 69.28 133.23 -63.95 54 95 ND<0 133.23 -133.23 54 96 ND<0 133.23 -133.23 54 97 72.54 133.23 -60.69 54 98 94.62 133.23 -38.61 54 99 91.51 133.23 -41.72 54 100 ND<0 133.23 -133.23 54 101 69.28 134.77 -65.49 54 102 ND<0 134.77 -134.77 54 103 ND<0 134.77 -134.77 54 104 72.54 134.77 -62.23 54 105 94.62 134.77 -40.15 54 106 91.51 134.77 -43.26 54 107 ND<0 134.77 -134.77 54 108 ND<0 69.28 -69.28 54 109 ND<0 69.28 -69.28 54 110 72.54 69.28 3.26 55 110 94.62 69.28 25.34 56 110 91.51 69.28 22.23 57 110 ND<0 69.28 -69.28 57 111 ND<0 ND<0 0 57 111 72.54 ND<0 72.54 58 111 94.62 ND<0 94.62 59 111 91.51 ND<0 91.51 60 111 ND<0 ND<0 0 60 111 72.54 ND<0 72.54 61 111 94.62 ND<0 94.62 62 111 91.51 ND<0 91.51 63 111 ND<0 ND<0 0 63 111 94.62 72.54 22.08 64 111 91.51 72.54 18.97 65 111 ND<0 72.54 -72.54 65 112 91.51 94.62 -3.11 65 113 ND<0 94.62 -94.62 65 114 ND<0 91.51 -91.51 65 115 S Statistic = 65 - 115 = -50 Tied GroiValue Members 1 0 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 15 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A = 300 B=0 C=60 D=0 E=20 F=0 a = 17100 b = 61560 c = 760 Group Variance = 933.333 Z-Score =-1.6039 Comparison Level at 95% confidence level = 1.65463 (upward trend) -1.6039 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 16 Alexander Cc CDLF over MSWLF VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: AOC (UNDGNTD) Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 66.57 161.23 -94.66 0 1 93 161.23 -68.23 0 2 ND<0 161.23 -161.23 0 3 99.9 161.23 -61.33 0 4 145.94 161.23 -15.29 0 5 94.55 161.23 -66.68 0 6 ND<0 161.23 -161.23 0 7 ND<0 161.23 -161.23 0 8 ND<0 161.23 -161.23 0 9 89.36 161.23 -71.87 0 10 116.46 161.23 -44.77 0 11 93.51 161.23 -67.72 0 12 44.28 161.23 -116.95 0 13 83.59 161.23 -77.64 0 14 75.37 161.23 -85.86 0 15 69.51 161.23 -91.72 0 16 ND<0 161.23 -161.23 0 17 ND<0 161.23 -161.23 0 18 89.59 161.23 -71.64 0 19 93 66.57 26.43 1 19 ND<0 66.57 -66.57 1 20 99.9 66.57 33.33 2 20 145.94 66.57 79.37 3 20 94.55 66.57 27.98 4 20 ND<0 66.57 -66.57 4 21 ND<0 66.57 -66.57 4 22 ND<0 66.57 -66.57 4 23 89.36 66.57 22.79 5 23 116.46 66.57 49.89 6 23 93.51 66.57 26.94 7 23 44.28 66.57 -22.29 7 24 83.59 66.57 17.02 8 24 75.37 66.57 8.8 9 24 69.51 66.57 2.94 10 24 ND<0 66.57 -66.57 10 25 ND<0 66.57 -66.57 10 26 89.59 66.57 23.02 11 26 ND<0 93 -93 11 27 99.9 93 6.9 12 27 145.94 93 52.94 13 27 94.55 93 1.55 14 27 ND<0 93 -93 14 28 ND<0 93 -93 14 29 ND<0 93 -93 14 30 89.36 93 -3.64 14 31 116.46 93 23.46 15 31 93.51 93 0.51 16 31 44.28 93 -48.72 16 32 83.59 93 -9.41 16 33 75.37 93 -17.63 16 34 69.51 93 -23.49 16 35 ND<0 93 -93 16 36 ND<0 93 -93 16 37 89.59 93 -3.41 16 38 99.9 ND<0 99.9 17 38 145.94 ND<0 145.94 18 38 94.55 ND<0 94.55 19 38 ND<0 ND<0 0 19 38 ND<0 ND<0 0 19 38 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 17 Alexander Cc CDLF over MSWLF VOCs ND<0 ND<0 0 19 38 89.36 ND<0 89.36 20 38 116.46 ND<0 116.46 21 38 93.51 ND<0 93.51 22 38 44.28 ND<0 44.28 23 38 83.59 ND<0 83.59 24 38 75.37 ND<0 75.37 25 38 69.51 ND<0 69.51 26 38 ND<0 ND<0 0 26 38 ND<0 ND<0 0 26 38 89.59 ND<0 89.59 27 38 145.94 99.9 46.04 28 38 94.55 99.9 -5.35 28 39 ND<0 99.9 -99.9 28 40 ND<0 99.9 -99.9 28 41 ND<0 99.9 -99.9 28 42 89.36 99.9 -10.54 28 43 116.46 99.9 16.56 29 43 93.51 99.9 -6.39 29 44 44.28 99.9 -55.62 29 45 83.59 99.9 -16.31 29 46 75.37 99.9 -24.53 29 47 69.51 99.9 -30.39 29 48 ND<0 99.9 -99.9 29 49 ND<0 99.9 -99.9 29 50 89.59 99.9 -10.31 29 51 94.55 145.94 -51.39 29 52 ND<0 145.94 -145.94 29 53 ND<0 145.94 -145.94 29 54 ND<0 145.94 -145.94 29 55 89.36 145.94 -56.58 29 56 116.46 145.94 -29.48 29 57 93.51 145.94 -52.43 29 58 44.28 145.94 -101.66 29 59 83.59 145.94 -62.35 29 60 75.37 145.94 -70.57 29 61 69.51 145.94 -76.43 29 62 ND<0 145.94 -145.94 29 63 ND<0 145.94 -145.94 29 64 89.59 145.94 -56.35 29 65 ND<0 94.55 -94.55 29 66 ND<0 94.55 -94.55 29 67 ND<0 94.55 -94.55 29 68 89.36 94.55 -5.19 29 69 116.46 94.55 21.91 30 69 93.51 94.55 -1.04 30 70 44.28 94.55 -50.27 30 71 83.59 94.55 -10.96 30 72 75.37 94.55 -19.18 30 73 69.51 94.55 -25.04 30 74 ND<0 94.55 -94.55 30 75 ND<0 94.55 -94.55 30 76 89.59 94.55 -4.96 30 77 ND<0 ND<0 0 30 77 ND<0 ND<0 0 30 77 89.36 ND<0 89.36 31 77 116.46 ND<0 116.46 32 77 93.51 ND<0 93.51 33 77 44.28 ND<0 44.28 34 77 83.59 ND<0 83.59 35 77 75.37 ND<0 75.37 36 77 69.51 ND<0 69.51 37 77 ND<0 ND<0 0 37 77 ND<0 ND<0 0 37 77 89.59 ND<0 89.59 38 77 ND<0 ND<0 0 38 77 89.36 ND<0 89.36 39 77 116.46 ND<0 116.46 40 77 93.51 ND<0 93.51 41 77 44.28 ND<0 44.28 42 77 83.59 ND<0 83.59 43 77 75.37 ND<0 75.37 44 77 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 18 Alexander Cc CDLF over MSWLF VOCs 69.51 ND<0 69.51 45 77 ND<0 ND<0 0 45 77 ND<0 ND<0 0 45 77 89.59 ND<0 89.59 46 77 89.36 ND<0 89.36 47 77 116.46 ND<0 116.46 48 77 93.51 ND<0 93.51 49 77 44.28 ND<0 44.28 50 77 83.59 ND<0 83.59 51 77 75.37 ND<0 75.37 52 77 69.51 ND<0 69.51 53 77 ND<0 ND<0 0 53 77 ND<0 ND<0 0 53 77 89.59 ND<0 89.59 54 77 116.46 89.36 27.1 55 77 93.51 89.36 4.15 56 77 44.28 89.36 -45.08 56 78 83.59 89.36 -5.77 56 79 75.37 89.36 -13.99 56 80 69.51 89.36 -19.85 56 81 ND<0 89.36 -89.36 56 82 ND<0 89.36 -89.36 56 83 89.59 89.36 0.23 57 83 93.51 116.46 -22.95 57 84 44.28 116.46 -72.18 57 85 83.59 116.46 -32.87 57 86 75.37 116.46 -41.09 57 87 69.51 116.46 -46.95 57 88 ND<0 116.46 -116.46 57 89 ND<0 116.46 -116.46 57 90 89.59 116.46 -26.87 57 91 44.28 93.51 -49.23 57 92 83.59 93.51 -9.92 57 93 75.37 93.51 -18.14 57 94 69.51 93.51 -24 57 95 ND<0 93.51 -93.51 57 96 ND<0 93.51 -93.51 57 97 89.59 93.51 -3.92 57 98 83.59 44.28 39.31 58 98 75.37 44.28 31.09 59 98 69.51 44.28 25.23 60 98 ND<0 44.28 -44.28 60 99 ND<0 44.28 -44.28 60 100 89.59 44.28 45.31 61 100 75.37 83.59 -8.22 61 101 69.51 83.59 -14.08 61 102 ND<0 83.59 -83.59 61 103 ND<0 83.59 -83.59 61 104 89.59 83.59 6 62 104 69.51 75.37 -5.86 62 105 ND<0 75.37 -75.37 62 106 ND<0 75.37 -75.37 62 107 89.59 75.37 14.22 63 107 ND<0 69.51 -69.51 63 108 ND<0 69.51 -69.51 63 109 89.59 69.51 20.08 64 109 ND<0 ND<0 0 64 109 89.59 ND<0 89.59 65 109 89.59 ND<0 89.59 66 109 S Statistic = 66 - 109 = -43 Tied GroiValue Members 1 0 6 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 19 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A=510 B=0 C=120 D=0 E=30 F=0 a = 17100 b = 61560 c = 760 Group Variance = 921.667 Z-Score =-1.38345 Comparison Level at 95% confidence level = 1.65463 (upward trend) -1.38345 <= 1.65463 indicating no evidence of an upward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 20 Alexander Cc CDLF over MSWLF VOCs Mann -Kendall Trend Analysis Parameter: Cumulative VOCs Location: ALL WELLS Original Data (Not Transformed) Non -Detects Replaced with 1/2 DL 95% Confidence Level Xj Xk Xj - Xk PositivesNegatives 342.78 562.18 -219.4 0 1 368.21 562.18 -193.97 0 2 ND<0 562.18 -562.18 0 3 395.274 562.18 -166.906 0 4 452.515 562.18 -109.665 0 5 361.245 562.18 -200.935 0 6 412.981 562.18 -149.199 0 7 ND<0 562.18 -562.18 0 8 333.937 562.18 -228.243 0 9 366.65 562.18 -195.53 0 10 ND<0 562.18 -562.18 0 11 379.611 562.18 -182.569 0 12 237.257 562.18 -324.923 0 13 285.937 562.18 -276.243 0 14 327.426 562.18 -234.754 0 15 234.72 562.18 -327.46 0 16 ND<0 562.18 -562.18 0 17 ND<0 562.18 -562.18 0 18 221.43 562.18 -340.75 0 19 368.21 342.78 25.43 1 19 ND<0 342.78 -342.78 1 20 395.274 342.78 52.494 2 20 452.515 342.78 109.735 3 20 361.245 342.78 18.465 4 20 412.981 342.78 70.201 5 20 ND<0 342.78 -342.78 5 21 333.937 342.78 -8.843 5 22 366.65 342.78 23.87 6 22 ND<0 342.78 -342.78 6 23 379.611 342.78 36.831 7 23 237.257 342.78 -105.523 7 24 285.937 342.78 -56.843 7 25 327.426 342.78 -15.354 7 26 234.72 342.78 -108.06 7 27 ND<0 342.78 -342.78 7 28 ND<0 342.78 -342.78 7 29 221.43 342.78 -121.35 7 30 ND<0 368.21 -368.21 7 31 395.274 368.21 27.064 8 31 452.515 368.21 84.305 9 31 361.245 368.21 -6.965 9 32 412.981 368.21 44.771 10 32 ND<0 368.21 -368.21 10 33 333.937 368.21 -34.273 10 34 366.65 368.21 -1.56 10 35 ND<0 368.21 -368.21 10 36 379.611 368.21 11.401 11 36 237.257 368.21 -130.953 11 37 285.937 368.21 -82.273 11 38 327.426 368.21 -40.784 11 39 234.72 368.21 -133.49 11 40 ND<0 368.21 -368.21 11 41 ND<0 368.21 -368.21 11 42 221.43 368.21 -146.78 11 43 395.274 ND<0 395.274 12 43 452.515 ND<0 452.515 13 43 361.245 ND<0 361.245 14 43 412.981 ND<0 412.981 15 43 ND<0 ND<0 0 15 43 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 21 Alexander Cc CDLF over MSWLF VOCs 333.937 ND<0 333.937 16 43 366.65 ND<0 366.65 17 43 ND<0 ND<0 0 17 43 379.611 ND<0 379.611 18 43 237.257 ND<0 237.257 19 43 285.937 ND<0 285.937 20 43 327.426 ND<0 327.426 21 43 234.72 ND<0 234.72 22 43 ND<0 ND<0 0 22 43 ND<0 ND<0 0 22 43 221.43 ND<0 221.43 23 43 452.515 395.274 57.241 24 43 361.245 395.274 -34.029 24 44 412.981 395.274 17.707 25 44 ND<0 395.274 -395.274 25 45 333.937 395.274 -61.337 25 46 366.65 395.274 -28.624 25 47 ND<0 395.274 -395.274 25 48 379.611 395.274 -15.663 25 49 237.257 395.274 -158.017 25 50 285.937 395.274 -109.337 25 51 327.426 395.274 -67.848 25 52 234.72 395.274 -160.554 25 53 ND<0 395.274 -395.274 25 54 ND<0 395.274 -395.274 25 55 221.43 395.274 -173.844 25 56 361.245 452.515 -91.27 25 57 412.981 452.515 -39.534 25 58 ND<0 452.515 -452.515 25 59 333.937 452.515 -118.578 25 60 366.65 452.515 -85.865 25 61 ND<0 452.515 -452.515 25 62 379.611 452.515 -72.904 25 63 237.257 452.515 -215.258 25 64 285.937 452.515 -166.578 25 65 327.426 452.515 -125.089 25 66 234.72 452.515 -217.795 25 67 ND<0 452.515 -452.515 25 68 ND<0 452.515 -452.515 25 69 221.43 452.515 -231.085 25 70 412.981 361.245 51.736 26 70 ND<0 361.245 -361.245 26 71 333.937 361.245 -27.308 26 72 366.65 361.245 5.405 27 72 ND<0 361.245 -361.245 27 73 379.611 361.245 18.366 28 73 237.257 361.245 -123.988 28 74 285.937 361.245 -75.308 28 75 327.426 361.245 -33.819 28 76 234.72 361.245 -126.525 28 77 ND<0 361.245 -361.245 28 78 ND<0 361.245 -361.245 28 79 221.43 361.245 -139.815 28 80 ND<0 412.981 -412.981 28 81 333.937 412.981 -79.044 28 82 366.65 412.981 -46.331 28 83 ND<0 412.981 -412.981 28 84 379.611 412.981 -33.37 28 85 237.257 412.981 -175.724 28 86 285.937 412.981 -127.044 28 87 327.426 412.981 -85.555 28 88 234.72 412.981 -178.261 28 89 ND<0 412.981 -412.981 28 90 ND<0 412.981 -412.981 28 91 221.43 412.981 -191.551 28 92 333.937 ND<0 333.937 29 92 366.65 ND<0 366.65 30 92 ND<0 ND<0 0 30 92 379.611 ND<0 379.611 31 92 237.257 ND<0 237.257 32 92 285.937 ND<0 285.937 33 92 327.426 ND<0 327.426 34 92 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 22 Alexander Cc CDLF over MSWLF VOCs 234.72 ND<0 234.72 35 92 ND<0 ND<0 0 35 92 ND<0 ND<0 0 35 92 221.43 ND<0 221.43 36 92 366.65 333.937 32.713 37 92 ND<0 333.937 -333.937 37 93 379.611 333.937 45.674 38 93 237.257 333.937 -96.68 38 94 285.937 333.937 -48 38 95 327.426 333.937 -6.511 38 96 234.72 333.937 -99.217 38 97 ND<0 333.937 -333.937 38 98 ND<0 333.937 -333.937 38 99 221.43 333.937 -112.507 38 100 ND<0 366.65 -366.65 38 101 379.611 366.65 12.961 39 101 237.257 366.65 -129.393 39 102 285.937 366.65 -80.713 39 103 327.426 366.65 -39.224 39 104 234.72 366.65 -131.93 39 105 ND<0 366.65 -366.65 39 106 ND<0 366.65 -366.65 39 107 221.43 366.65 -145.22 39 108 379.611 ND<0 379.611 40 108 237.257 ND<0 237.257 41 108 285.937 ND<0 285.937 42 108 327.426 ND<0 327.426 43 108 234.72 ND<0 234.72 44 108 ND<0 ND<0 0 44 108 ND<0 ND<0 0 44 108 221.43 ND<0 221.43 45 108 237.257 379.611 -142.354 45 109 285.937 379.611 -93.674 45 110 327.426 379.611 -52.185 45 111 234.72 379.611 -144.891 45 112 ND<0 379.611 -379.611 45 113 ND<0 379.611 -379.611 45 114 221.43 379.611 -158.181 45 115 285.937 237.257 48.68 46 115 327.426 237.257 90.169 47 115 234.72 237.257 -2.537 47 116 ND<0 237.257 -237.257 47 117 ND<0 237.257 -237.257 47 118 221.43 237.257 -15.827 47 119 327.426 285.937 41.489 48 119 234.72 285.937 -51.217 48 120 ND<0 285.937 -285.937 48 121 ND<0 285.937 -285.937 48 122 221.43 285.937 -64.507 48 123 234.72 327.426 -92.706 48 124 ND<0 327.426 -327.426 48 125 ND<0 327.426 -327.426 48 126 221.43 327.426 -105.996 48 127 ND<0 234.72 -234.72 48 128 ND<0 234.72 -234.72 48 129 221.43 234.72 -13.29 48 130 ND<0 ND<0 0 48 130 221.43 ND<0 221.43 49 130 221.43 ND<0 221.43 50 130 S Statistic = 50 - 130 = -80 Tied GroiValue Members 1 0 5 Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 23 Alexander Co CDLF over MSWLF VOCs Time Period Observations 6/24/2009 1 12/15/2009 1 7/7/2010 1 12/8/2010 1 6/28/2011 1 12/13/2011 1 6/12/2012 1 12/10/2012 1 6/25/2013 1 12/16/2013 1 6/24/2014 1 12/2/2014 1 6/6/2015 1 1 /5/2016 1 7/ 1 /2016 1 12/29/2016 1 6/28/2017 1 12/28/2017 1 6/ 11 /2018 1 12/27/2018 1 There are 0 time periods with multiple data A = 300 B=0 C=60 D=0 E=20 F=0 a = 17100 b = 61560 c = 760 Group Variance = 933.333 Z-Score =-2.58588 Comparison Level at 95% confidence level =-1.65463 (downward trend) -2.58588 <-1.65463 indicating a downward trend Non -Detects Replaced with 1/2 DL Original Data (Not Transformed) Page 24