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HomeMy WebLinkAbout1403_Caldwell_Foothills_MSWLF_GW_FID1319088_20190410REPUBLIC SERVICES April 10, 2019 Ms. Jaclynne Drummond Hydrogeologist Solid Waste Section Division of Waste Management North Carolina Department of Environmental Quality 2090 US Highway 70 Swannanoa, North Carolina 28778 RE: First Semi -Annual Water Quality Monitoring Report of 2019 Foothills Regional Landfill, Permit No. 14-03 Caldwell County, North Carolina Dear Ms. Drummond: Republic Services of North Carolina, LLC is submitting the First Semi -Annual Water Quality Monitoring Report of 2019 for the Foothills Regional Landfill and Environmental Monitoring Reporting Form in electronic format. The report completes the first semi-annual compliance monitoring event of 2019 for the Foothills Regional Landfill, Permit No. 14-03, as required by the North Carolina Division of Waste Management, Solid Waste Section. If you have any questions, please contact Steve Jett with Jett Environmental Consulting at (314) 496- 4654, or me at (314) 302-3634. Sincerely, Republic Services of North Carolina, LLC Digitally signed by: Bouchard, Derek DN: CN = Bouchard, Derek OU = a"Uz Regions, Midwest, Users Date: 2019.04.10 11:47:56-05'00' Mr. Derek Bouchard Environmental Manager Enclosure cc: Stephen Hunter, Foothills Regional Landfill, Republic Services Joe Montello, Republic Services Steve Jett, Jett Environmental Consulting Page 1 of 1 ENR USE ONLY: []Paper Report []Electronic Data - Email CD data loaded: Yes / No Doc/Event #: C DENR IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Steve Jett E-mail: steve.jett@jettenviro.com Phone: (314) 496-4654 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006) Foothills Regional Landfill 2800 Cheraw Road 14-03 .1600 January 28, 2019 Lenoir, NC 28645 Environmental Status: (Check all that apply) F-] Initial/Background Monitoring Detection Monitoring 0 Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells F-1 Leachate monitoring data Surface water monitoring data F-1 Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett Owner (314) 496-4654 Facility Represe WzA&e (Prin Signature Title L �j I o �q Date Jett Environmental Consulting, PLLC, 1002 Morgan Meadow Drive, Wentzville, MO 63385 Facility Representative Address NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 (Area Code) Telephone Number Affix NC Licensed/ Professional Geologist Seal tr 1WWzOa Groundwater Statistical Analysis Report First Semi -Annual 2019 Sampling Event Foothills Regional Landfill Caldwell County, North Carolina April 2019 Prepared by: JETT ENVIRONMLN IHL C O N S U L T I N G 1002 Morgan Meadow Drive 314-496-4654 Wentzville, MO 63385 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................2 4.0 DATA EVALUATION......................................................................3 5.0 STATISTICAL PROCEDURES.......................................................3 5.1 Outlier Analysis...........................................................................4 5.2 Inter -Well Prediction Intervals....................................................4 5.3 Intra-Well Confidence Limits......................................................4 5.4 Statistical Results Summary.......................................................5 6.0 CONCLUSIONS..............................................................................5 7.0 RECOMMENDATIONS...................................................................6 Table 1 Groundwater Monitoring Program Table 2 Groundwater Analytical Data Summary Table 3 Surface Water Analytical Data Summary Table 4 Leachate Analytical Data Summary APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Sampling Forms Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 1 1.0 INTRODUCTION On behalf of Foothills Regional Landfill, Jett Environmental Consulting statistically evaluated the First Semi - Annual 2019 water quality monitoring data. Groundwater, surface water, underdrain, and leachate sampling were completed by Environmental Sampling & Services, Inc. (ES&S) on January 28, 2019, and analytical testing was performed by Pace Analytical Services, LLC. The statistical analysis software package utilized, Sanitasr', follows a documented decision logic that incorporates the following applicable document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK In compliance with North Carolina Department of Environmental Quality (DEQ) Solid Waste Management Regulations, Section .1600 "Requirements for Municipal Solid Waste Landfill Facilities," Jett Environmental Consulting statistically evaluated parameters from the First Semi -Annual 2019 event using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. The facility's monitoring network is comprised of ten monitoring wells: MW-1 R2 (background), MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, and MW-11, which monitor the uppermost aquifer beneath the facility. The monitoring wells are sampled on a semi-annual basis, with the groundwater samples submitted to a qualified laboratory for required analyses in accordance with the facility's environmental monitoring program and permit requirements. The monitoring wells are equipped with dedicated bladder pumps and were purged and sampled via the low -flow method. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the First Semi -Annual 2019 event in January 2019. Groundwater monitoring was initiated in August 1998. Statistical background is defined as samples collected from former upgradient well MW-1, former upgradient well MW-1 R, and current upgradient well MW-1 R2 from 1998 through the current event. The parameters subject to statistical evaluation during detection monitoring are noted in DEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". In addition, in a May 29, 2018 memorandum, DEQ requested groundwater and surface water samples be analyzed for 1,4-dioxane. Therefore, the groundwater and surface water samples were analyzed for 1,4- dioxane initially during the July 2018 event and also during the January 2019 event. Recent soil and bedrock removal in the Northern Borrow Area rendered well MW-1 R dry and inaccessible. Therefore, a replacement monitoring well (MW-1 R2) was installed in September 2018. New well MW-11 was also installed in September 2018 as part of the Cell No. 5B construction. A Groundwater Monitoring Well Installation Report dated October 19, 2018 was compiled by Bunnell Lammons Engineering Inc. and submitted to DEQ by the site. The two new wells have been sampled on September 11, 2018 (n=1), October 8, 2018 (n=2), December 3, 2018 (n=3), and January 28, 2019 (n=4). Well MW-3R2 was added to the monitoring well network on August 17, 2006 as a replacement well for MW-3 and MW-3R. Monitoring wells MW-3 and MW-3R remain for water level data collection purposes only. Monitoring well MW-7 was installed in April 2010 to monitor groundwater beneath Cell 4, which began receiving waste in September 2010. MW-8 was installed in April 2013 to monitor Cell 8A, which was constructed in January 2013. MW-10 was installed in October 2015 to monitor Cell 5A. The former background well MW-1 was abandoned in preparation for construction of Cell 5A and the new background well, MW-1 R, was installed in October 2015. MW-9 was installed June 2016 to monitor Cell 5A. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 2 The site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and three downstream points (SW-2, SW-3, and SW-4). These points are sampled semi-annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Per the DEQ May 29, 2018 memorandum mentioned above, these points were also sampled for 1,4-dioxane this event. Each surface water monitoring point was sampled during the First Semi -Annual 2019 event. A sample from the underdrain for Cell 1 (UD-1) was added to the monitoring network prior to the January 2008 sampling event. A sample from the underdrain for Cells 4 and 8A (UD-2) was added to the monitoring network prior to the January 2014 sampling event. The underdrains are to be sampled semi-annually (contingent on flow availability) for the 40 CFR Part 258 Appendix I list. Both underdrains were able to be sampled during the First Semi -Annual 2019 event. A leachate sample is also routinely collected for analysis. The Ieachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, nitrite as N, phosphorous, and sulfate. The facility was in an Assessment Monitoring Program in 2006. An Alternate Source Demonstration (ASD) for volatile organic compounds (VOCs) detected in wells MW-3 and MW-31R was approved by DEQ on December 14, 2006, and the facility reverted to a Detection Monitoring Program. An ASD for cobalt and a request to use background as the groundwater protection standard (GWPS) for cobalt was submitted to the DEQ in November 2016. The ASD is currently under DEQ review. An ASD for benzene and vinyl chloride at MW-2R was submitted to DEQ in June 2017; however, it was not approved in a letter from DEQ dated October 11, 2017 and Assessment Monitoring was initiated. Therefore, during the First Semi -Annual 2018 event, the initial Appendix II Assessment constituent list was sampled at each well. The constituents detected at quantifiable concentrations (barium, benzene, and cobalt) were consistent with past events and also on the Appendix I Detection Monitoring list. On May 18, 2018, the site requested deleting all non -Appendix I monitoring from future sampling events, with the exception of well MW-2R, which will continue with annual Appendix II monitoring. In correspondence dated July 9, 2018, DEQ approved the request to only include MW-2R for future annual Appendix II monitoring. The annual Appendix II monitoring for MW-2R was performed during January 2019 sampling event. No Appendix 11 constituents, not also on the Appendix I list, were detected above their respective PQLs during the January 2019 event. The next annual Appendix 11 sampling event for MW-2R will be January 2020. 3.0 SITE HYDROGEOLOGY The following site hydrogeology summary was taken from the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Geologically, the facility is located in the northwestern portion of the Inner Piedmont Belt of the Piedomont Physiographic Province, approximately 20 miles east of the thrust belt (Brevard Shear Zone) delineating the boundary between the westerly Blue Ridge Belt and the easterly Inner Piedmont Belt. The metamorphic rocks of the Inner Piedmont Belt generally group within the sillimanite facies of the amphibolite metamorphic sequence. Locally, the bedrock underlying the facility has been mapped as migmatitic granitic gneiss of the Ordovician and older Cambrian Periods. These rocks are described as ranging in composition from granitic to quartz dioritic with smaller biotite gneiss and amphibolite facies present locally. The unit as a whole exhibits a variable massive to foliated fabric. The uppermost aquifer beneath the facility is present within weathered bedrock saprolite and fractured bedrock. The saprolite ranges in texture from clayey silt in the upper, most weathered sections to micaceous sandy silt in the lower sections. Immediately above the competent bedrock surface, a variable thickness transitional zone composed of highly weathered and degraded friable bedrock is present. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 3 The uppermost aquifer is laterally continuous across the site, with depth to water ranging from less than 31 feet in low-lying areas to greater than 77 feet beneath topographic highs. Groundwater in the uppermost aquifer generally flows from recharge areas associated with broad gently sloping topographic areas towards topographically lower areas that are generally delineated by the presence of stream channels, some of which are perennial receiving streams (groundwater discharge areas) and others of which are intermittent discharging streams. In the vicinity of the facility, the general groundwater flow direction is towards the south and west. Appendix A provides a potentiometric surface map utilizing groundwater level data from the First Semi - Annual 2019 event. Groundwater flow direction for the First Semi -Annual 2019 event was to the southwest, which is consistent with previous interpretations for this facility. The First Semi -Annual 2019 event groundwater flow direction was consistent with past events. Groundwater flow rate for the First Semi - Annual 2019 event was estimated at 180 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. 4.0 DATA EVALUATION Appendix C contains a copy of the laboratory analytical report and field sampling forms for the First Semi - Annual 2019 groundwater, surface water, underdrain, and leachate sampling event. Also included in Appendix C is a copy of the laboratory analytical reports and field sampling forms for the September 11, 2018 (n=1), October 8, 2018 (n=2), December 3, 2018 (n=3), and January 28, 2019 (n=4) events for new wells MW-1 R2 and MW-11. . The analytical results for the First Semi -Annual 2019 event for the groundwater, surface water, underdrain and leachate samples are summarized on Tables 2, 3, and 4, respectively. One volatile organic compound (VOC) was detected at a quantified concentration above a laboratory practical quantitation limit (PQL) in groundwater samples: benzene at MW-2R. As shown on Table 2, two Appendix I inorganic constituents (barium at MW-2R, MW-5, and MW-6; and cobalt at MW-4, MW-6, and MW-8) were detected at quantified concentrations. Two Appendix I constituents (benzene at MW-2R; cobalt at MW-4, MW-6, and MW-8) were detected above an NC Interim Maximum Allowable Concentration (IMAC) or 2L Standard during the First Semi -Annual 2019 sampling event. Vanadium (MW-1 R, MW-5, and MW-10) was detected above their respective IMAC, however at estimated concentrations below their PQL. As shown on Table 3, during the First Semi -Annual 2019 event, no NC 2B Surface Water Standards were exceeded in surface water or underdrain samples. No VOCs were detected in surface water or underdrain samples at quantified concentrations above their respective PQLs during the First Semi -Annual 2019 event. Groundwater and surface water samples were analyzed for 1,4-dioxane this event according to the request in the May 29, 2018 DEQ memorandum noted above. There were no detections of 1,4-dioxane in the January 2019 groundwater and surface water samples. The constituents detected in the leachate sample collected during the First Semi -Annual 2019 event are typical for leachate at this facility. 5.0 STATISTICAL PROCEDURES Statistical analyses (i.e. inter -well prediction limits) were performed to establish background concentrations and determine if the IMAC value -to -value exceedances for cobalt exhibited a statistically significant increase. Statistical analyses (i.e., lower confidence limits) were performed to determine if the 2L Standard value -to -value exceedance for benzene statistically exceeded the 2L Standard. Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 4 5.1 Outlier Analysis The background data were evaluated for the presence of statistical outliers. Methodologies for determining a statistical outlier are defined in the EPA document, Statistical Analysis of Ground -Water Monitoring Data at RCRA Facilities — Unified Guidance (March 2009). Any statistical outliers that were determined were removed from the background data set prior to performing prediction interval statistical analysis. According to the EPA guidance documents above, data that are not normally or log -normally distributed are not recommended for evaluation of outliers. In cases where the data were not normally or log -normally distributed, outliers were not removed from the data set. Background outliers flagged for removal are identified on the statistical plots provided in Appendix B. 5.2 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are nondetects, the nondetects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed - normal or contain greater than 50% observations below the reporting limit, SanitasTm automatically constructs a non -parametric prediction interval. During non -parametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. Due to the wide range of laboratory reporting limits utilized over time, the historical reporting limits were conservatively replaced with the current event reporting limit prior to performing statistical analyses. Summary tables and graphs for the inter -well prediction interval analysis are available in Appendix B. Included in Appendix B are time series plots for each of the inorganic constituents. For the First Semi -Annual 2019 event, three inorganic statistically significant increases were exhibited for the groundwater monitoring wells: cobalt at MW-4, MW-6, and MW-8. The First Semi -Annual 2019 concentrations of total cobalt at MW-4 (19.7 ug/L), MW-6 (11.0 ug/L), and MW-8 (10.2 ug/L) were above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). An ASD for cobalt at MW-4 and a request to use background for the GWPS was submitted to the DEQ by the site on November 4, 2016. The statistical background value for cobalt was determined to be 44.1 ug/L based on an Upper Poisson Prediction Limit, which is higher than the detected concentration at MW-4, MW-6, and MW-8. The ASD requested that the background value be considered the GWPS for cobalt per 15A NCAC13B.1634.(g).5. The ASD is currently under DEQ review. 5.3 Intra-Well Confidence Limits Per DEQ Regulation .1634(H), Groundwater Protection Standards (GWPSs) are equal to the National Primary Drinking Water Standard -Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 5 Water Quality Standard, whichever is lower. In instances where an MCL or 2L Standard are not established, the GWPSs were derived from the DEQ-Solid Waste Section published GWPSs. In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs to determine if further action is warranted. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Per the U.S. Environmental Protection Agency document (dated March 2009), titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate concentration limit (i.e. 2L Standard or NC IMAC). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro-Francia test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). Organic concentrations detected above PQLs and GWPSs (See Table 2) were statistically compared to their respective GWPSs utilizing intra-well lower confidence limits. As provided in Appendix B, benzene at MW-2R statistically exceed the GWPS for the First Semi -Annual 2019 event. Time series graphs for VOC detections during recent events are provided in Appendix B. As shown on Table 2, the January 2019 benzene result for MW-2R (1.6 ug/L) confirmed the GWPS (1.0 ug/L) exceedance. 5.4 Statistical Results Summary For the First Semi -Annual 2019 event, three inorganic statistically significant increases were exhibited for the groundwater monitoring wells: cobalt at MW-4, MW-6, MW-8. The First Semi -Annual 2019 concentrations of total cobalt at MW-4 (19.7 ug/L), MW-6 (11.0 ug/L), and MW-8 (10.2 ug/L) were above the background inter -well prediction limit based on pooled data from upgradient wells MW-1, MW-1 R, and MW-1 R2 (10 ug/L, which is equal to the PQL). Intra-well lower confidence limits determined benzene at MW-2R statistically exceed the GWPS for the First Semi -Annual 2019 event. However, benzene concentrations at MW-2R has decreased during the last two semi-annual events (July 2018 and January 2019). 6.0 CONCLUSIONS For the First Semi -Annual 2019 event (January 2019), one inorganic statistically significant increase was confirmed exhibited for the groundwater monitoring wells: cobalt at MW-4. Two new inorganic statistically significant increases were exhibited for the groundwater monitoring wells: cobalt at MW-6 and MW-8. The January 2019 cobalt concentrations at MW-6 (11.0 ug/L) and MW-8 (10.2 ug/L) were only slightly above the laboratory PQL (10 ug/L). Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 6 One VOC was detected at a quantified concentration above a 2L Standard in groundwater samples during the First Semi -Annual 2019 event: benzene at MW-2R. Intra-well lower confidence limits determined benzene at MW-2R statistically exceed the GWPS for the First Semi -Annual 2019 event. During the First Semi -Annual 2019 event, no Appendix I VOCs were detected in surface water and underdrain samples at quantifiable concentrations. No verified detections of Appendix I metals exceeded NC 2B Surface Water Standards for surface water and underdrain points during the First Semi -Annual 2019 event. The annual Appendix II monitoring for MW-2R was performed during the January 2019 sampling event. No Appendix II constituents, not also on the Appendix I list, were detected at MW-2R above their respective PQLs. Groundwater and surface water samples were collected for 1,4-dioxane this event according to the request in the May 29, 2018 DEQ memorandum noted above. This parameter is not specified in the rules or approved monitoring plan. The First Semi -Annual 2019 event was the second consecutive event with no 1,4-dioxane detections. Per a November 28, 2018 DEQ letter, if 1,4-dioxane was reported as non -detect in January 2019, then the site could cease monitoring of the groundwater and surface water samples for 1,4-dioxane. In accordance with the November 28, 2018 DEQ letter, 1,4-dioxane will no longer be analyzed for the groundwater and surface water samples, however will be analyzed annually for the leachate sample. The Foothills Regional Landfill will continue monitoring in accordance with the requirements for Detection and Assessment Monitoring as outlined in Title 15A NCAC 13B .1633 and .1634, respectively. The next semi-annual event is scheduled for July 2019. 7.0 RECOMMENDATIONS Wells in the proximity of MW-2R exist directly upgradient (MW-9) and directly downgradient (MW-3R2). No VOCs have been detected at quantified concentrations at MW-9 or MW-3R2; therefore, the extent of quantified VOC detections (i.e. benzene) has been defined to only MW-2R. As described in the site's June 2017 ASD for benzene/vinyl chloride at MW-2R, the VOCs appear to be related to landfill gas. Wells MW-9, MW-2R, and MW-3R2 would effectively cover the exterior perimeter of the cell (1A) suspected as the source of potential gas migration. The site implemented landfill gas extraction and collection upgrades in the Cell 1A area in late 2017 and installed a horizontal landfill gas collection/mitigation trench in the vicinity of MW-2R in Fall 2018. An additional event or two of groundwater monitoring is recommended before any further actions to determine if benzene levels at MW-2R (1.6 ug/L) decrease to levels below the lab PQL (1.0 ug/L) as a result of the landfill gas system upgrades. It is recommended that wells MW-4, MW-6, and MW-8 continue in Detection Monitoring. The drop of cobalt at MW-4 from 25.4 ug/L in July 2012 to 19.7 ug/L in January 2019, indicates a slow decreasing trend near the laboratory PQL (10 ug/L). The January 2019 cobalt concentrations at MW-6 (11.0 ug/L) and MW-8 (10.2 ug/L) were only slightly above the laboratory PQL (10 ug/L). The first time trace level exceedances of cobalt at MW-6 and MW-8 will be verified during the July 2019 event. In summary the January 2019 cobalt results are very close to the background statistical limit. Since the landfill is lined, it is unlikely the cobalt detections are related to a landfill release. The concentrations are expected to naturally attenuate to levels well below background with minimal migration distance. The lack of receptors of water use in this shallow well, which would not feasibly produce a well with sufficient yield for potable use, is evidence of a lack of risk associated with this level of detection. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site, and is a common element occurring naturally in minerals commonly found in the bedrock, soil, and sediments in the North Carolina Piedmont. According to A Geochemical Atlas of North Carolina (by Jeffery C. Reid, dated 1993 in the North Carolina Geological Survey's Bulletin 93), which displays the distribution Groundwater Statistical Analysis Report Foothills Regional Landfill, North Carolina 7 of cobalt in stream sediments across the state, Caldwell County has been highlighted. Cobalt was found at concentrations as high as 10 mg/kg throughout Caldwell County; with a significant amount of variability. Metals in the soil and bedrock can easily leach into the groundwater, especially if the groundwater is acidic (pH < 7.0). The pH of groundwater samples from the Foothills Landfill during the January 2019 sampling event ranged from 5.58 to 7.20 SU, and the pH of the sample from MW-4, which had the highest cobalt concentration, was 5.23 SU. Review of leachate data for the last 10 years indicates cobalt has ranged from <10 to 33.2 ug/L, with an average concentration of 21.9 ug/L. The occurrence and levels of cobalt at the site has no indication of being related to a release from the MSWLF unit. The site recommends utilizing the upcoming July 2019 event to continue to verify the downward trend of cobalt levels at MW-4 and benzene at MW-2R, since both levels are so close to the laboratory PQL of 10 ug/L and 1.0 ug/L, respectively. The July 2019 event will also be utilized to verify the trace level cobalt detections at MW-6 and MW-8. The proposed actions are protective of human health and the environment and the values at this time do not further action, especially for a naturally occurring element (cobalt). TABLES TABLE 1 GROUNDWATER MONITORING PROGRAM FIRST SEMI-ANNUAL 2019 EVENT FOOTHILLS REGIONAL LANDFILL UPGRADIENT WELLS DOWNGRADIENT WELLS MW-1 R2 I MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11 TABLE 2 GROUNDWATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2019 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units 2LStd IMAC MDL PQL MW-11R2 MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 MW-8 MW-9 MW-10 MW-11 Antimony Total u /L NE 1 0.78 6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 Arsenic Total u /L 10 NE 0.57 10 <10 <10 <10 <10 1.7 J <10 <10 0.71 J <10 <10 <10 Barium Total u /L 700 NE 0.78 100 30.4 J 252 10.7 J 46.6 J 119 166 45.2 J 48.1 J 101 20.9 J 50.4 J Beryllium Total u /L NE 4 0.05 1 <1 0.13 J <1 0.1 J 0.071 J 0.51 J 0.25 J 0.2 J <1 <1 <1 Cadmium Total u /L 2 NE 0.093 1 <1 <1 <1 <1 <1 0.13 J <1 <1 <1 <1 <1 Chromium Total u /L 10 NE 1.6 1 10 <10 <10 <10 <10 <10 <10 2 J <10 <10 I <10 <10 Cobalt Total u /L NE 1 0.52 10 <10 <10 <10 19.7 <10 11 <10 10.2 <10 <10 <10 Copper Total u /L 1,000 NE 1.3 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Lead Total u /L 15 NE 0.27 10 <10 <10 <10 <10 <10 0.36 J <10 <10 <10 <10 <10 Nickel Total u /L 100 NE 0.95 50 <50 <50 <50 1.1 J <50 1.2 J <50 2.3 J <50 <50 1.2 J Selenium Total u /L 20 NE 1.4 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total u /L 20 NE 0.95 10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Thallium Total u /L NE 0.28 0.14 1 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 1 <5.5 Vanadium Total u /L NE 0.3 1.9 25 4 J <25 <25 <25 2.6 J <25 <25 <25 <25 3.4 J <25 Zinc Total u /L 1,000 NE 2.1 10 2.6 J <10 <10 2.5 J <10 <10 <10 3 J <10 <10 2.3 J Field pH SU NE NE NE NE 6.59 5.68 7.20 5.23 5.80 5.58 5.78 5.82 6.18 6.81 7.11 Field Redox mV NE NE NE NE 22.0 68.0 -8.7 90.9 62.2 72.8 62.7 60.3 42.6 11.0 -4.1 Field Specific Conductance umhos/cm NE NE 1 1 105.7 146.7 108.8 35.3 190.1 184.1 113.1 134.5 161.1 70.2 54.7 Field Temperature °C NE NE NE NE 13.9 16.3 17.0 16.6 16.8 14.5 13.8 12.0 13.6 12.0 12.0 Field Turbidity NTU NE NE NE NE 2.48 1.62 4.76 1.41 1.62 8.26 5.26 4.88 3.15 3.58 1.66 Benzene u /L 1 NE 0.2 1 <1 1.6 <1 <1 <1 <1 <1 <1 <1 <1 <1 For VOCs, only constituents with one or more detections above a PQL are included on table. NE: Denotes a NC 2L or IMAC Standard is not established. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Denotes a concentration at or above a PQL is also above a NC 2L or IMAC Standard: Denotes a concentration is above a NC 2L or IMAC Standard, but but below the PQL: TABLE 3 SURFACE WATER ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2019 EVENT FOOTHILLS REGIONAL LANDFILL Constituent Units NC 2B Std MDL PQL SW-1 SW-2 SW-3 SW-4 UD-1 UD-2 Antimony Total u /L 640 0.78 6 <6 <6 <6 <6 <6 <6 Arsenic Total ug/L 10 0.57 10 <10 <10 <10 <10 <10 <10 Barium Total u /L 21,000 0.78 100 15.6 J 25.2 J 24.2 J 24.7 J 76.8 J 49.4 J Beryllium Total u /L 6.5 0.05 1 <1 <1 <1 <1 0.055 J <1 Cadmium Total u /L NE 0.093 1 <1 <1 <1 <1 <1 <1 Chromium Total ug/L NE 1.6 10 <10 <10 <10 <10 <10 <10 Cobalt Total u /L 4 0.52 10 <10 0.7 J 0.63 J 0.63 J 9.1 J 6 J Copper Total ug/L NE 1.3 10 <10 <10 <10 <10 <10 <10 Lead Total u /L NE 0.27 10 <10 <10 <10 <10 <10 <10 Nickel Total ug/L NE 0.95 50 <50 <50 <50 <50 1.8 J <50 Selenium Total u /L 5 1.4 10 <10 <10 <10 <10 <10 <10 Silver Total ug/L 0.06 0.95 10 <10 <10 <10 <10 <10 <10 Thallium Total u /L 0.47 0.14 5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total u /L NE 1.9 25 <25 <25 <25 <25 2.5 J 2.8 J Zinc Total ug/L NE 2.1 10 <10 4.6 J 3.2 J 3.1 J 8.4 J <10 Field pH SU NE NE NE 7.09 7.21 7.52 7.48 5.77 5.86 Field Redox mV NE NE NE -2.7 -8.6 -24.0 -22.3 63.9 68.6 Field Specific Conductance umhos/cm NE 1 1 51.6 76.2 61.6 62.9 207 192.6 Field Temperature °C NE NE NE 3.8 8.6 10.2 10.1 18.9 18.2 Field Turbidity NTU NE NE NE 5.80 8.41 9.88 9.87 5.24 4.96 J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. No VOCs detected above an SWSL, therefore not included on this table. NE: Denotes a NC 2B Standard is not established. Denotes a concentration at or above a PQL is also above the NC 2B Standard: TABLE 4 LEACHATE ANALYTICAL DATA SUMMARY FIRST SEMI-ANNUAL 2019 EVENT FOOTHILLS REGIONAL LANDFILL Indicator Parameters Units MDL PQL Leachate Antimony ug/L 0.78 6 99.7 Arsenic u /L 0.57 10 90.8 Barium ug/L 0.78 100 381 Beryllium u /L 0.05 1 0.085 J BOD, 5 day ug/L 537,000 537,000 831,000 Cadmium u /L 0.093 1 <1 Chemical Oxygen Demand ug/L 100,000 100,000 1,870,000 Chromium u /L 1.6 10 124 Cobalt ug/L 0.52 10 23 Copper u /L 1.3 10 537 Lead ug/L 0.27 10 5.2 J Nickel u /L 0.95 50 116 Nitrate as N u /L 5 50 176 Nitrite as N u /L 11 50 <50 Nitrogen, NO2 plus NO3 ug/L 12 50 176 Phosphorus u /L 2,000 2,000 3,390 Selenium ug/L 1.4 10 2.8 J Silver u /L 0.95 10 <10 Sulfate u /L 17 5,000 4,510 J Thallium u /L 0.14 5.5 <5.5 Vanadium ug/L 1.9 25 37.4 Zinc u /L 2.1 10 240 Field pH SU NE NE 7.68 Field Redox mV NE NE -29.2 Field Specific Conductance umhos/cm 1 1 17,100 Field Temperature °C NE NE 14.8 Field Turbidity NTU NE NE 96.1 Volatile Organic Compounds VOCs Units MDL PQL Leachate 2-Butanone (MEK) ug/L 64 2000 4640 Acetone u /L 410 5000 14300 Ethylbenzene ug/L 9 20 31.8 Methylene Chloride u /L 10 20 22.3 Toluene u /L 6.2 20 36.5 Metals reported at Total. For VOCs, only constituents with detections above a PQL are included on table. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP 10 4$ NORTH 0 100 200 400 &SW-1� K� �� M W-8 164.48 . 1 \MW-7� 1155.43� i ki III V 4°\ NO. 8 NO. A� \ ol000 (STING � ELL NO. tXIS I C L Ay 1200 t �l 11561 E L o.2A j%% — , I 1 MW-53 128.46 \ ' rMW-4 1129.87 1 -\M W 1 R. Abandoned—y it 500 O \ °MW-1 R2� ` 1505.43/ J) 15 0 - \ 20 1450 g° p 41400 l \ 1350 j� \ 0 -1 Inn BMW-3R2 0 MW-3R ° �1212.95 m 1186.67; SSW-3 \_ f Scale in Feet Graphic Scale: 1 inch = 400 feet l&SW-4 -� MW-11 \t 1319.67 t EXIST( CELL NO. (UNDE STRUC ION) �MW-10 A LEGEND 1 SMW-7 Monitoring Well Location L) ®UD-1 Underdrain Location 1155.43 Groundwater Elevation (fmsl) —1300 — Potentiometric Surface Contour (fmsl) Hydraulic Gradient & Inferred i 0.13n Groundwater Flow Direction 3W-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary Water levels collected by Environmental Sampling & Services, Inc. on January 28, 2019. Basemap provided by Joyce Engineering, with topographic survey completed by Cooper Aerial Surveys Co., date of Photography is January 20, 2014. 4 0 JETT ENVIRONMENTAL C O N S U L T I N G Figure 1 1002 Morgan Meadow4654 January 2019 Event, Potentiometric Surface Map Wentzville, MO 63385 314-496-4654 www.jettenviro.com Foothills Regional Landfill, Caldwell County, North Carolina Groundwater Elevation Summary Table Foothills Regional Landfill Well Top of PVC Casing Elevation (fmsl)' Depth to Water (ft)2 Groundwater Elevation (fmsl) MW-1 R2 1516.22 10.79 1505.43 MW-2R 1253.36 46.84 1206.52 MW-3 1241.95 51.79 1190.16 MW-3R 1242.69 56.02 1186.67 MW-3R2 1240.83 27.88 1212.95 MW-4 1171.18 41.31 1129.87 MW-5 1175.07 46.61 1128.46 MW-6 1173.75 40.51 1133.24 MW-7 1183.13 27.70 1155.43 MW-8 1195.18 30.70 1164.48 MW-9 1290.79 68.11 1222.68 MW-10 1356.08 78.53 1277.55 MW-11 1401.71 82.04 1319.67 Note 1: Top of PVC Casing Elevations from Table 1 of the Second Semi -Annual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering; with the exception of MW-1R2 and MW-11. Elevations for MW-1R2 and MW-11 from the Groundwater Monitoring Well Installation Report dated October 19, 2018 by BLE. Note 2: Depth to water measured by Environmental Sampling & Services, Inc. on January 28, 2019. Groundwater Flow Velocity Calculations Foothills Regional Landfill First Semi -Annual 2019 Event Velocity V = [(k)(i)]/(n) V = [(0.374 ft/day)(0.1317 ft/ft)] / 0.1 V = 0.493 ft/day V = 180 ft/year Where, Hydraulic conductivity (k) and effective porosity (n) values from the following document: Table 2 of the Second SemiAnnual Water Quality Monitoring Report of 2017, dated November 17, 2017 by Joyce Engineering. Gradient (i) is from the average gradient at site using the potentiometric surface map from Point A to Point B. Gradient (i) = Change in Groundwater Elevation along Flow Path is From Point A (1500 contour) to Point B (1150 contour) = 350 ft / 2,657 ft = 0.1317 ft/ft APPENDIX B STATISTICAL EVALUATIONS Prediction Limit Foothills Client: RSI Data: Foothills Printed 3/11/2019, 2:54 PM Constituent Well der Lim. Lower Lim. Date Observ. Sia. Ba N Ba Mean Std. Day. %NDs ND Ad. Cobalt Total (ug/L) MW-10 5.00 n/a 1/28/2019 5ND No 45 n/a n/a 93.33 n/a Cobalt Total (ug/L) MW-11 5.00 n/a 1/28/2019 5ND No 45 n/a n/a 93.33 n/a Cobalt Total (ug/L) MW-2R 5.00 n/a 1/28/2019 5ND No 45 n/a We 93.33 n/a Cobalt Total (ug/L) MW-3R2 5.00 n/a 1/28/2019 5ND No 45 n/a We 93.33 n/a Cobalt Total (ug/L) MW-4 5.00 We 1/28/2019 19.7 Yes 45 n/a n/a 93.33 n/a Cobalt Total (ug/L) MW-5 5.00 n/a 1/28/2019 5ND No 45 n/a We 93.33 n/a Cobalt Total (ug/L) MW-6 5.00 We 1/28/2019 11 Yes 45 n/a We 93.33 n/a Cobalt Total (ug/L) MW-7 5.00 n/a 1/28/2019 5ND No 45 n/a n/a 93.33 n/a Cobalt Total (ug/L) MW-8 5.00 n/a 1/28/2019 10.2 Yes 45 n/a We 93.33 We Cobalt Total (ug/L) MW-9 5.00 n/a 1/28/2019 5ND No 45 n/a We 93.33 n/a Transform Aloha Method n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs)1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs)1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 n/a 0.0009192 NP Inter (NDs) 1 of 2 Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-4, MW-6, MW-8 Prediction Limit Interwell Non -parametric 30 ♦ MW-10 • MW-2R 24 ♦ MW-3R2 ♦ MW-4 J 18 ♦ MW-5 12 ■ MW-6 • MW-7 6 ♦ MW-8 ♦ MW-9 0 ♦ MW-11 7/19/99 6/14/03 5/11 /07 4/6/11 3/3/15 1 /28/19 Limit = 5.00 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 45 background values. 93.33% NDs. Annual per -constituent alpha = 0.01823. Individual comparison alpha = 0.0009192 (1 of 2). Comparing 10 points to limit. After outlier removal distribution was non -normal, so outlier results were invalidated. Constituent: Cobalt Total Analysis Run 3/11/2019 2:53 PM Foothills Client: RSI Data: Foothills Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 5 4 3 2 J � 1 111 Constituent: Benzene Analysis Run 3/12/2019 7:58 AM Foothills Client: RSI Data: Foothills Confidence Interval Constituent: Benzene (ug/L) Analysis Run 3/12/2019 7:59 AM Foothills Client: RSI Data: Foothills MW-2R 1/29/2018 2.6 7/23/2018 2 10/8/2018 2.1 1 /28/2019 1.6 Mean 2.075 Std. Dev. 0.4113 Upper Lim. 3.009 Lower Lim. 1.141 TIME SERIES TREND ANALYSIS Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 1 /6/09 Time Series 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: Antimony Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 047 8 6 J ' t� 4 2 0 8/10/98 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Arsenic Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 300 240 180 J 0) 120 60 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 UMMOI Constituent: Barium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 3 2.4 1.8 J 0) Z3 1.2 0.6 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Beryllium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 1 0.8 0.6 J 0.4 0.2 0 8/10/98 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Cadmium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 lvlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 J 0) 16 8 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Chromium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Cobalt Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills f MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 8 4 0 4- 8/10/98 Time Series i 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Copper Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Lead Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 1` 40 FT L 30 — J 20 10 0 8/10/98 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Nickel Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ Ivlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 12 6 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Selenium Total Analysis Run 3/20/2019 1:07 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 0) 20 10 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Silver Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 lvlvv-y MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 6 4.8 3.6 J 0) Z3 2.4 1.2 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Thallium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 lvlvv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 60 48 36 J 24 12 0 4- 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Vanadium Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 ■ MW-1 R (bg) • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 Ivl vv-y ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 0) 80 40 8/10/98 Time Series 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Zinc Total Analysis Run 3/11/2019 3:16 PM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-1 R (bg) MW-2R MW-3R2 MW-4 MW-5 MW-6 MW-7 M W-8 MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 1 0 1 /6/09 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: 11-Dichloroethane Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-9 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J Z3 2 1 - L, 0 8/10/98 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Benzene Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-9 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 1 /6/09 Time Series 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: cis- 12-Dichloroethene Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-2R MW-3R2 M W-4 M W-5 M W-6 MW-7 M W-8 MW-9 MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 0) Z3 2 r 0 8/10/98 9/13/02 10/17/06 11 /20/10 12/24/14 1 /28/19 Constituent: Tetrachloroethene Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-9 ♦ MW-11 ♦ MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0) Z3 0.8 0.4 0 4- 1 /6/09 Time Series 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: Trichloroethene Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-2R MW-3R2 M W-4 M W-5 M W-6 MW-7 M W-8 MW-9 MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J 0) Z3 0.8 0.4 0 4- 1 /6/09 Time Series 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: Vinyl chloride Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills MW-1 (bg) MW-10 MW-2R MW-3R2 M W-4 M W-5 M W-6 M W-7 M W-8 MW-9 MW-11 MW-1 R2 (bg) Sanitas'" v.9.6.12b Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 2 1 0 1 /6/09 1 /10/11 1 /14/13 1 /19/15 1 /23/17 1 /28/19 Constituent: Xylenes [Total] Analysis Run 3/12/2019 8:08 AM Foothills Client: RSI Data: Foothills ♦ MW-1 (bg) ♦ MW-10 • MW-2R ♦ MW-3R2 ♦ MW-4 ♦ MW-5 ■ MW-6 • MW-7 ♦ MW-8 ♦ MW-9 ♦ MW-11 ♦ MW-1 R2 (bg) APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD SAMPLING FORMS aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 March 20, 2019 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF NC 1403 Pace Project No.: 2614222 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 29, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This revised report replaces the report issued on 2/13/2019. It provides reanalysis metals data for MW-4, MW-5, MW-6, and MW-8 per consultant request. MW-5 reanalysis did not confirm. No other changes have been made to this report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC 1403 Pace Project No.: 2614222 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Foothills LF NC 1403 Pace Project No.: 2614222 Lab ID Sample ID Matrix Date Collected Date Received 2614222001 1403-MW-1R2 Water 01/28/1916:57 01/29/19 10:00 2614222002 1403-MW-3R2 Water 01/28/1913:59 01/29/19 10:00 2614222003 1403-MW-4 Water 01/28/1913:09 01/29/19 10:00 2614222004 1403-DUP@MW-4 Water 01/28/1913:11 01/29/19 10:00 2614222005 1403-MW-5 Water 01/28/1911:46 01/29/19 10:00 2614222006 1403-MW-6 Water 01/28/1911:03 01/29/19 10:00 2614222007 1403-MW-7 Water 01/28/1910:06 01/29/19 10:00 2614222008 1403-MW-8 Water 01/28/19 09:04 01/29/19 10:00 2614222009 1403-MW-9 Water 01/28/19 08:16 01/29/19 10:00 2614222010 1403-MW-10 Water 01/28/19 07:31 01/29/19 10:00 2614222011 1403-MW-11 Water 01/28/19 06:45 01/29/19 10:00 2614222012 1403-Field Blank Water 01/28/19 06:01 01/29/19 10:00 2614222013 1403-SW1 Water 01/28/19 09:18 01/29/19 10:00 2614222014 1403-SW2 Water 01/28/1912:15 01/29/19 10:00 2614222015 1403-SW3 Water 01/28/1915:50 01/29/19 10:00 2614222016 1403-SW4 Water 01/28/1915:32 01/29/19 10:00 2614222017 1403-UD1 Water 01/28/1912:01 01/29/19 10:00 2614222018 1403-UD2 Water 01/28/1910:16 01/29/19 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF NC 1403 2614222 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 2614222001 1403-MW-1 R2 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222002 1403-MW-3R2 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222003 1403-MW-4 EPA 6020E CSW, KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222004 1403-DUP@MW-4 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222005 1403-MW-5 EPA 6020E CSW, KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 74 PASI-GA 2614222006 1403-MW-6 EPA 6020E CSW, KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222007 1403-MW-7 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222008 1403-MW-8 EPA 6020E CSW, KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222009 1403-MW-9 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222010 1403-MW-10 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222011 1403-MW-11 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222012 1403-Field Blank EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222013 1403-SW1 EPA 6020E CSW 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF NC 1403 2614222 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222014 1403-SW2 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222015 1403-SW3 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222016 1403-SW4 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2614222017 1403-UD1 EPA 6020E CSW 15 PASI-GA EPA 8260B LIH 51 PASI-GA 2614222018 1403-UD2 EPA 6020E CSW 15 PASI-GA EPA 8260B LIH 51 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MWAR2 Lab ID: 2614222001 Collected: 01/28/19 16:57 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:19 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:19 7440-38-2 Barium 30.4J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:19 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:19 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:19 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:19 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:19 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:19 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:19 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:19 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:19 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:19 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:19 7440-28-0 Vanadium 4.OJ ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:19 7440-62-2 Zinc 2.6J ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:19 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 18:25 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 50-150 1 01/31/19 18:25 17060-07-0 Toluene-d8 (S) 112 % 50-150 1 01/31/19 18:25 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 13:30 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 13:30 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 13:30 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 13:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 13:30 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 13:30 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 13:30 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 13:30 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 13:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 13:30 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 13:30 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 13:30 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 13:30 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 13:30 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 13:30 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 13:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 13:30 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 13:30 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 13:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 13:30 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 13:30 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-1R2 Lab ID: 2614222001 Collected: 01/28/19 16:57 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1913:30 75-34-3 ND ug/L 1.0 0.67 1 02/09/1913:30 107-06-2 ND ug/L 5.0 0.72 1 02/09/1913:30 75-35-4 ND ug/L 5.0 0.66 1 02/09/1913:30 156-59-2 ND ug/L 5.0 0.46 1 02/09/1913:30 156-60-5 ND ug/L 1.0 0.60 1 02/09/1913:30 78-87-5 ND ug/L 1.0 0.22 1 02/09/1913:30 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1913:30 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1913:30 100-41-4 ND ug/L 50.0 0.89 1 02/09/1913:30 591-78-6 ND ug/L 10.0 3.1 1 02/09/1913:30 74-88-4 ND ug/L 1.0 0.50 1 02/09/1913:30 75-09-2 ND ug/L 100 0.86 1 02/09/1913:30 108-10-1 ND ug/L 1.0 0.50 1 02/09/1913:30 100-42-5 ND ug/L 5.0 0.32 1 02/09/1913:30 630-20-6 ND ug/L 3.0 0.53 1 02/09/1913:30 79-34-5 ND ug/L 1.0 0.78 1 02/11/1916:06 127-18-4 ND ug/L 1.0 0.31 1 02/09/1913:30 108-88-3 ND ug/L 1.0 0.38 1 02/09/1913:30 71-55-6 ND ug/L 1.0 0.59 1 02/09/1913:30 79-00-5 ND ug/L 1.0 0.34 1 02/09/1913:30 79-01-6 ND ug/L 1.0 0.51 1 02/09/1913:30 75-69-4 ND ug/L 1.0 0.46 1 02/09/1913:30 96-18-4 ND ug/L 50.0 0.42 1 02/09/1913:30 108-05-4 ND ug/L 1.0 0.60 1 02/09/1913:30 75-01-4 ND ug/L 5.0 1.5 1 02/09/1913:30 1330-20-7 98 %. 81-119 1 02/09/1913:30 17060-07-0 94 %. 82-114 1 02/09/1913:30 1868-53-7 104 %. 82-120 1 02/09/1913:30 460-00-4 98 %. 82-109 1 02/09/1913:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-3R2 Lab ID: 2614222002 Collected: 01/28/19 13:59 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:25 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:25 7440-38-2 Barium 10.7J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:25 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:25 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:25 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:25 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:25 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:25 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:25 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:25 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:25 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:25 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:25 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:25 7440-62-2 Zinc ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:25 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 18:44 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 50-150 1 01/31/19 18:44 17060-07-0 Toluene-d8 (S) 113 % 50-150 1 01/31/19 18:44 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 13:55 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 13:55 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 13:55 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 13:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 13:55 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 13:55 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 13:55 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 13:55 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 13:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 13:55 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 13:55 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 13:55 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 13:55 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 13:55 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 13:55 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 13:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 13:55 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 13:55 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 13:55 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 13:55 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 13:55 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-3R2 Lab ID: 2614222002 Collected: 01/28/19 13:59 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1913:55 75-34-3 ND ug/L 1.0 0.67 1 02/09/1913:55 107-06-2 ND ug/L 5.0 0.72 1 02/09/1913:55 75-35-4 ND ug/L 5.0 0.66 1 02/09/1913:55 156-59-2 ND ug/L 5.0 0.46 1 02/09/1913:55 156-60-5 ND ug/L 1.0 0.60 1 02/09/1913:55 78-87-5 ND ug/L 1.0 0.22 1 02/09/1913:55 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1913:55 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1913:55 100-41-4 ND ug/L 50.0 0.89 1 02/09/1913:55 591-78-6 ND ug/L 10.0 3.1 1 02/09/1913:55 74-88-4 ND ug/L 1.0 0.50 1 02/09/1913:55 75-09-2 ND ug/L 100 0.86 1 02/09/1913:55 108-10-1 ND ug/L 1.0 0.50 1 02/09/1913:55 100-42-5 ND ug/L 5.0 0.32 1 02/09/1913:55 630-20-6 ND ug/L 3.0 0.53 1 02/09/1913:55 79-34-5 ND ug/L 1.0 0.78 1 02/11/1916:31 127-18-4 ND ug/L 1.0 0.31 1 02/09/1913:55 108-88-3 ND ug/L 1.0 0.38 1 02/09/1913:55 71-55-6 ND ug/L 1.0 0.59 1 02/09/1913:55 79-00-5 ND ug/L 1.0 0.34 1 02/09/1913:55 79-01-6 1.OJ ug/L 1.0 0.51 1 02/09/1913:55 75-69-4 ND ug/L 1.0 0.46 1 02/09/1913:55 96-18-4 ND ug/L 50.0 0.42 1 02/09/1913:55 108-05-4 ND ug/L 1.0 0.60 1 02/09/1913:55 75-01-4 ND ug/L 5.0 1.5 1 02/09/1913:55 1330-20-7 99 %. 81-119 1 02/09/1913:55 17060-07-0 94 %. 82-114 1 02/09/1913:55 1868-53-7 104 %. 82-120 1 02/09/1913:55 460-00-4 102 %. 82-109 1 02/09/1913:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-4 Lab ID: 2614222003 Collected: 01/28/19 13:09 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:31 7440-36-0 ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:31 7440-38-2 46.6J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:31 7440-39-3 0.10J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:31 7440-41-7 ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:31 7440-43-9 ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:31 7440-47-3 19.7 ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:31 7440-48-4 24.6 ug/L 10.0 0.52 1 03/12/1914:02 03/13/1914:38 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:31 7440-50-8 ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:31 7439-92-1 1.1J ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:31 7440-02-0 ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:31 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:31 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:31 7440-28-0 ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:31 7440-62-2 2.5J ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:31 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 01/31/1919:04 123-91-1 98 % 50-150 1 01/31/1919:04 17060-07-0 114 % 50-150 1 01/31/1919:04 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1914:20 67-64-1 ND ug/L 200 2.5 1 02/09/1914:20 107-13-1 ND ug/L 1.0 0.20 1 02/09/1914:20 71-43-2 ND ug/L 3.0 0.50 1 02/09/1914:20 74-97-5 ND ug/L 1.0 0.36 1 02/09/1914:20 75-27-4 ND ug/L 3.0 0.55 1 02/09/1914:20 75-25-2 ND ug/L 10.0 0.95 1 02/09/1914:20 74-83-9 ND ug/L 100 3.2 1 02/09/1914:20 78-93-3 ND ug/L 100 0.79 1 02/09/1914:20 75-15-0 ND ug/L 1.0 0.42 1 02/09/1914:20 56-23-5 ND ug/L 3.0 0.53 1 02/09/1914:20 108-90-7 ND ug/L 10.0 0.52 1 02/09/1914:20 75-00-3 ND ug/L 5.0 0.58 1 02/09/1914:20 67-66-3 ND ug/L 1.0 0.38 1 02/09/1914:20 74-87-3 ND ug/L 13.0 0.55 1 02/09/1914:20 96-12-8 ND ug/L 3.0 0.31 1 02/09/1914:20 124-48-1 ND ug/L 2.0 0.28 1 02/09/1914:20 106-93-4 ND ug/L 10.0 0.62 1 02/09/1914:20 74-95-3 ND ug/L 5.0 0.49 1 02/09/1914:20 95-50-1 ND ug/L 1.0 0.58 1 02/09/1914:20 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-4 Lab ID: 2614222003 Collected: 01/28/19 13:09 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 100 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 100 %. 81-119 92 %. 82-114 108 %. 82-120 99 %. 82-109 1.6 1 02/09/19 14:20 110-57-6 0.41 1 02/09/19 14:20 75-34-3 0.67 1 02/09/19 14:20 107-06-2 0.72 1 02/09/19 14:20 75-35-4 0.66 1 02/09/19 14:20 156-59-2 0.46 1 02/09/19 14:20 156-60-5 0.60 1 02/09/19 14:20 78-87-5 0.22 1 02/09/19 14:20 10061-01-5 0.30 1 02/09/19 14:20 10061-02-6 0.45 1 02/09/19 14:20 100-41-4 0.89 1 02/09/19 14:20 591-78-6 3.1 1 02/09/19 14:20 74-88-4 0.50 1 02/09/19 14:20 75-09-2 0.86 1 02/09/19 14:20 108-10-1 0.50 1 02/09/19 14:20 100-42-5 0.32 1 02/09/19 14:20 630-20-6 0.53 1 02/09/19 14:20 79-34-5 0.78 1 02/11 /19 16:56 127-18-4 0.31 1 02/09/19 14:20 108-88-3 0.38 1 02/09/19 14:20 71-55-6 0.59 1 02/09/19 14:20 79-00-5 0.34 1 02/09/19 14:20 79-01-6 0.51 1 02/09/19 14:20 75-69-4 0.46 1 02/09/19 14:20 96-18-4 0.42 1 02/09/19 14:20 108-05-4 0.60 1 02/09/19 14:20 75-01-4 1.5 1 02/09/19 14:20 1330-20-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/09/19 14:20 17060-07-0 02/09/19 14:20 1868-53-7 02/09/19 14:20 460-00-4 02/09/19 14:20 2037-26-5 Page 11 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-DUP@MW-4 Lab ID: 2614222004 Collected: 01/28/19 13:11 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:37 7440-36-0 ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:37 7440-38-2 46.5J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:37 7440-39-3 0.098J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:37 7440-41-7 0.10J ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:37 7440-43-9 6.1J ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:37 7440-47-3 19.2 ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:37 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:37 7440-50-8 ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:37 7439-92-1 3.5J ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:37 7440-02-0 ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:37 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:37 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:37 7440-28-0 ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:37 7440-62-2 ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:37 7440-66-6 Analytical Method: EPA 8260E Mod ND ug/L 2.0 1.9 1 01/31/1919:23 123-91-1 95 % 50-150 1 01/31/1919:23 17060-07-0 112 % 50-150 1 01/31/1919:23 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1914:46 67-64-1 ND ug/L 200 2.5 1 02/09/1914:46 107-13-1 ND ug/L 1.0 0.20 1 02/09/1914:46 71-43-2 ND ug/L 3.0 0.50 1 02/09/1914:46 74-97-5 ND ug/L 1.0 0.36 1 02/09/1914:46 75-27-4 ND ug/L 3.0 0.55 1 02/09/1914:46 75-25-2 ND ug/L 10.0 0.95 1 02/09/1914:46 74-83-9 ND ug/L 100 3.2 1 02/09/1914:46 78-93-3 ND ug/L 100 0.79 1 02/09/1914:46 75-15-0 ND ug/L 1.0 0.42 1 02/09/1914:46 56-23-5 ND ug/L 3.0 0.53 1 02/09/1914:46 108-90-7 ND ug/L 10.0 0.52 1 02/09/1914:46 75-00-3 ND ug/L 5.0 0.58 1 02/09/1914:46 67-66-3 ND ug/L 1.0 0.38 1 02/09/1914:46 74-87-3 ND ug/L 13.0 0.55 1 02/09/1914:46 96-12-8 ND ug/L 3.0 0.31 1 02/09/1914:46 124-48-1 ND ug/L 2.0 0.28 1 02/09/1914:46 106-93-4 ND ug/L 10.0 0.62 1 02/09/1914:46 74-95-3 ND ug/L 5.0 0.49 1 02/09/1914:46 95-50-1 ND ug/L 1.0 0.58 1 02/09/1914:46 106-46-7 ND ug/L 100 1.6 1 02/09/1914:46 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-DUP@MW-4 Lab ID: 2614222004 Collected: 01/28/19 13:11 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1914:46 75-34-3 ND ug/L 1.0 0.67 1 02/09/1914:46 107-06-2 ND ug/L 5.0 0.72 1 02/09/1914:46 75-35-4 ND ug/L 5.0 0.66 1 02/09/1914:46 156-59-2 ND ug/L 5.0 0.46 1 02/09/1914:46 156-60-5 ND ug/L 1.0 0.60 1 02/09/1914:46 78-87-5 ND ug/L 1.0 0.22 1 02/09/1914:46 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1914:46 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1914:46 100-41-4 ND ug/L 50.0 0.89 1 02/09/1914:46 591-78-6 ND ug/L 10.0 3.1 1 02/09/1914:46 74-88-4 ND ug/L 1.0 0.50 1 02/09/1914:46 75-09-2 ND ug/L 100 0.86 1 02/09/1914:46 108-10-1 ND ug/L 1.0 0.50 1 02/09/1914:46 100-42-5 ND ug/L 5.0 0.32 1 02/09/1914:46 630-20-6 ND ug/L 3.0 0.53 1 02/09/1914:46 79-34-5 ND ug/L 1.0 0.78 1 02/11/1917:21 127-18-4 ND ug/L 1.0 0.31 1 02/09/1914:46 108-88-3 ND ug/L 1.0 0.38 1 02/09/1914:46 71-55-6 ND ug/L 1.0 0.59 1 02/09/1914:46 79-00-5 ND ug/L 1.0 0.34 1 02/09/1914:46 79-01-6 ND ug/L 1.0 0.51 1 02/09/1914:46 75-69-4 ND ug/L 1.0 0.46 1 02/09/1914:46 96-18-4 ND ug/L 50.0 0.42 1 02/09/1914:46 108-05-4 ND ug/L 1.0 0.60 1 02/09/1914:46 75-01-4 ND ug/L 5.0 1.5 1 02/09/1914:46 1330-20-7 100 %. 81-119 1 02/09/1914:46 17060-07-0 95 %. 82-114 1 02/09/1914:46 1868-53-7 108 %. 82-120 1 02/09/1914:46 460-00-4 99 %. 82-109 1 02/09/1914:46 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-5 Lab ID: 2614222005 Collected: 01/28/19 11:46 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrolein Acrylonitrile Allyl chloride Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:42 7440-36-0 1.7J ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:42 7440-38-2 119 ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:42 7440-39-3 0.071J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:42 7440-41-7 ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:42 7440-43-9 ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:42 7440-47-3 ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:42 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:42 7440-50-8 ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:42 7439-92-1 ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:42 7440-02-0 ND ug/L 10.0 1.4 1 03/12/1914:02 03/13/1914:44 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:42 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:42 7440-28-0 2.6J ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:42 7440-62-2 ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:42 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 01/31/1919:42 123-91-1 97 % 50-150 1 01/31/1919:42 17060-07-0 114 % 50-150 1 01/31/1919:42 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1915:11 67-64-1 ND ug/L 50.0 7.8 1 02/09/1915:11 107-02-8 ND ug/L 200 2.5 1 02/09/1915:11 107-13-1 ND ug/L 10.0 0.96 1 02/09/1915:11 107-05-1 ND ug/L 1.0 0.20 1 02/09/1915:11 71-43-2 ND ug/L 1.0 0.58 1 02/09/1915:11 108-86-1 ND ug/L 3.0 0.50 1 02/09/1915:11 74-97-5 ND ug/L 1.0 0.36 1 02/09/1915:11 75-27-4 ND ug/L 3.0 0.55 1 02/09/1915:11 75-25-2 ND ug/L 10.0 0.95 1 02/09/1915:11 74-83-9 ND ug/L 100 3.2 1 02/09/1915:11 78-93-3 ND ug/L 100 0.79 1 02/09/1915:11 75-15-0 ND ug/L 1.0 0.42 1 02/09/1915:11 56-23-5 ND ug/L 3.0 0.53 1 02/09/1915:11 108-90-7 ND ug/L 10.0 0.52 1 02/09/1915:11 75-00-3 ND ug/L 5.0 0.58 1 02/09/1915:11 67-66-3 ND ug/L 1.0 0.38 1 02/09/1915:11 74-87-3 ND ug/L 1.0 0.26 1 02/09/1915:11 95-49-8 ND ug/L 1.0 0.68 1 02/09/1915:11 106-43-4 ND ug/L 13.0 0.55 1 02/09/1915:11 96-12-8 ND ug/L 3.0 0.31 1 02/09/1915:11 124-48-1 ND ug/L 2.0 0.28 1 02/09/1915:11 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Mild M1 Page 14 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-5 Lab ID: 2614222005 Collected: 01/28/19 11:46 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Diisopropyl ether Ethylbenzene Ethyl methacrylate Hexachloro-1,3-butadiene 2-Hexanone lodomethane p-Isopropyltoluene Methacrylonitrile Methylene Chloride Methyl methacrylate 4-Methyl-2-pe n to n o n e (MIBK) Methyl-tert-butyl ether Naphthalene Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 10.0 0.62 1 02/09/1915:11 74-95-3 ND ug/L 5.0 0.49 1 02/09/1915:11 95-50-1 ND ug/L 1.0 0.59 1 02/09/1915:11 541-73-1 ND ug/L 1.0 0.58 1 02/09/1915:11 106-46-7 ND ug/L 100 1.6 1 02/09/1915:11 110-57-6 ND ug/L 1.0 0.48 1 02/09/1915:11 75-71-8 ND ug/L 5.0 0.41 1 02/09/1915:11 75-34-3 ND ug/L 1.0 0.67 1 02/09/1915:11 107-06-2 ND ug/L 5.0 0.72 1 02/09/1915:11 75-35-4 ND ug/L 5.0 0.66 1 02/09/1915:11 156-59-2 ND ug/L 5.0 0.46 1 02/09/1915:11 156-60-5 ND ug/L 1.0 0.60 1 02/09/1915:11 78-87-5 ND ug/L 1.0 0.69 1 02/09/1915:11 142-28-9 ND ug/L 1.0 0.23 1 02/09/1915:11 594-20-7 ND ug/L 1.0 0.60 1 02/09/1915:11 563-58-6 ND ug/L 1.0 0.22 1 02/09/1915:11 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1915:11 10061-02-6 ND ug/L 10.0 1.1 1 02/09/1915:11 108-20-3 ND ug/L 1.0 0.45 1 02/09/1915:11 100-41-4 ND ug/L 10.0 0.59 1 02/09/1915:11 97-63-2 ND ug/L 10.0 1.2 1 02/09/1915:11 87-68-3 ND ug/L 50.0 0.89 1 02/09/1915:11 591-78-6 ND ug/L 10.0 3.1 1 02/09/1915:11 74-88-4 ND ug/L 1.0 0.47 1 02/09/1915:11 99-87-6 ND ug/L 10.0 0.79 1 02/09/1915:11 126-98-7 ND ug/L 1.0 0.50 1 02/09/1915:11 75-09-2 ND ug/L 10.0 0.89 1 02/09/1915:11 80-62-6 ND ug/L 100 0.86 1 02/09/1915:11 108-10-1 ND ug/L 10.0 1.6 1 02/09/1915:11 1634-04-4 ND ug/L 1.0 0.30 1 02/09/1915:11 91-20-3 ND ug/L 20.0 3.1 1 02/09/1915:11 107-12-0 ND ug/L 1.0 0.50 1 02/09/1915:11 100-42-5 ND ug/L 5.0 0.32 1 02/09/1915:11 630-20-6 ND ug/L 3.0 0.53 1 02/09/1915:11 79-34-5 ND ug/L 1.0 0.78 1 02/11/1917:46 127-18-4 ND ug/L 1.0 0.31 1 02/09/1915:11 108-88-3 ND ug/L 1.0 0.53 1 02/09/1915:11 87-61-6 ND ug/L 1.0 0.47 1 02/09/1915:11 120-82-1 ND ug/L 1.0 0.38 1 02/09/1915:11 71-55-6 ND ug/L 1.0 0.59 1 02/09/1915:11 79-00-5 ND ug/L 1.0 0.34 1 02/09/1915:11 79-01-6 ND ug/L 1.0 0.51 1 02/09/1915:11 75-69-4 ND ug/L 1.0 0.46 1 02/09/1915:11 96-18-4 ND ug/L 50.0 0.42 1 02/09/1915:11 108-05-4 ND ug/L 1.0 0.60 1 02/09/1915:11 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1 M1 M1 M1 R1 M1 M1 Page 15 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-5 Lab ID: 2614222005 Collected: 01/28/19 11:46 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend Analytical Method: EPA 8260E Xylene (Total) ND ug/L 5.0 1.5 1 02/09/19 15:11 1330-20-7 m&p-Xylene ND ug/L 1.0 0.92 1 02/09/19 15:11 179601-23-1 o-Xylene ND ug/L 1.0 0.54 1 02/09/19 15:11 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 101 %. 81-119 1 02/09/19 15:11 17060-07-0 Dibromofluoromethane (S) 94 %. 82-114 1 02/09/19 15:11 1868-53-7 4-Bromofluorobenzene (S) 104 %. 82-120 1 02/09/19 15:11 460-00-4 Toluene-d8 (S) 101 %. 82-109 1 02/09/19 15:11 2037-26-5 Date: 03/20/2019 10:31 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-6 Lab ID: 2614222006 Collected: 01/28/19 11:03 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 22:17 7440-36-0 ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 22:17 7440-38-2 166 ug/L 100 0.78 1 02/04/19 13:33 02/04/19 22:17 7440-39-3 0.51J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 22:17 7440-41-7 0.13J ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 22:17 7440-43-9 ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 22:17 7440-47-3 11.0 ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 22:17 7440-48-4 15.5 ug/L 10.0 0.52 1 03/12/1914:02 03/13/1915:07 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 22:17 7440-50-8 0.36J ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 22:17 7439-92-1 1.2J ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 22:17 7440-02-0 ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 22:17 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 22:17 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 22:17 7440-28-0 ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 22:17 7440-62-2 ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 22:17 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 01/31/19 20:41 123-91-1 95 % 50-150 1 01/31/19 20:41 17060-07-0 113 % 50-150 1 01/31/19 20:41 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1915:36 67-64-1 ND ug/L 200 2.5 1 02/09/1915:36 107-13-1 ND ug/L 1.0 0.20 1 02/09/1915:36 71-43-2 ND ug/L 3.0 0.50 1 02/09/1915:36 74-97-5 ND ug/L 1.0 0.36 1 02/09/1915:36 75-27-4 ND ug/L 3.0 0.55 1 02/09/1915:36 75-25-2 ND ug/L 10.0 0.95 1 02/09/1915:36 74-83-9 ND ug/L 100 3.2 1 02/09/1915:36 78-93-3 ND ug/L 100 0.79 1 02/09/1915:36 75-15-0 ND ug/L 1.0 0.42 1 02/09/1915:36 56-23-5 ND ug/L 3.0 0.53 1 02/09/1915:36 108-90-7 ND ug/L 10.0 0.52 1 02/09/1915:36 75-00-3 ND ug/L 5.0 0.58 1 02/09/1915:36 67-66-3 ND ug/L 1.0 0.38 1 02/09/1915:36 74-87-3 ND ug/L 13.0 0.55 1 02/09/1915:36 96-12-8 ND ug/L 3.0 0.31 1 02/09/1915:36 124-48-1 ND ug/L 2.0 0.28 1 02/09/1915:36 106-93-4 ND ug/L 10.0 0.62 1 02/09/1915:36 74-95-3 ND ug/L 5.0 0.49 1 02/09/1915:36 95-50-1 ND ug/L 1.0 0.58 1 02/09/1915:36 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-6 Lab ID: 2614222006 Collected: 01/28/19 11:03 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 100 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 97 %. 81-119 92 %. 82-114 105 %. 82-120 99 %. 82-109 1.6 1 02/09/19 15:36 110-57-6 0.41 1 02/09/19 15:36 75-34-3 0.67 1 02/09/19 15:36 107-06-2 0.72 1 02/09/19 15:36 75-35-4 0.66 1 02/09/19 15:36 156-59-2 0.46 1 02/09/19 15:36 156-60-5 0.60 1 02/09/19 15:36 78-87-5 0.22 1 02/09/19 15:36 10061-01-5 0.30 1 02/09/19 15:36 10061-02-6 0.45 1 02/09/19 15:36 100-41-4 0.89 1 02/09/19 15:36 591-78-6 3.1 1 02/09/19 15:36 74-88-4 0.50 1 02/09/19 15:36 75-09-2 0.86 1 02/09/19 15:36 108-10-1 0.50 1 02/09/19 15:36 100-42-5 0.32 1 02/09/19 15:36 630-20-6 0.53 1 02/09/19 15:36 79-34-5 0.78 1 02/11 /19 18:11 127-18-4 0.31 1 02/09/19 15:36 108-88-3 0.38 1 02/09/19 15:36 71-55-6 0.59 1 02/09/19 15:36 79-00-5 0.34 1 02/09/19 15:36 79-01-6 0.51 1 02/09/19 15:36 75-69-4 0.46 1 02/09/19 15:36 96-18-4 0.42 1 02/09/19 15:36 108-05-4 0.60 1 02/09/19 15:36 75-01-4 1.5 1 02/09/19 15:36 1330-20-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/09/19 15:36 17060-07-0 02/09/19 15:36 1868-53-7 02/09/19 15:36 460-00-4 02/09/19 15:36 2037-26-5 Page 18 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-7 Lab ID: 2614222007 Collected: 01/28/19 10:06 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 22:22 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 22:22 7440-38-2 Barium 45.2J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 22:22 7440-39-3 Beryllium 0.25J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 22:22 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 22:22 7440-43-9 Chromium 2.OJ ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 22:22 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 22:22 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 22:22 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 22:22 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 22:22 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 22:22 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 22:22 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 22:22 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 22:22 7440-62-2 Zinc ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 22:22 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 21:00 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 50-150 1 01/31/19 21:00 17060-07-0 Toluene-d8 (S) 116 % 50-150 1 01/31/19 21:00 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 16:02 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 16:02 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 16:02 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 16:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 16:02 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 16:02 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 16:02 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 16:02 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 16:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 16:02 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 16:02 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 16:02 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 16:02 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 16:02 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 16:02 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 16:02 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 16:02 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 16:02 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 16:02 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 16:02 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 16:02 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-7 Lab ID: 2614222007 Collected: 01/28/19 10:06 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1916:02 75-34-3 ND ug/L 1.0 0.67 1 02/09/1916:02 107-06-2 ND ug/L 5.0 0.72 1 02/09/1916:02 75-35-4 ND ug/L 5.0 0.66 1 02/09/1916:02 156-59-2 ND ug/L 5.0 0.46 1 02/09/1916:02 156-60-5 ND ug/L 1.0 0.60 1 02/09/1916:02 78-87-5 ND ug/L 1.0 0.22 1 02/09/1916:02 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1916:02 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1916:02 100-41-4 ND ug/L 50.0 0.89 1 02/09/1916:02 591-78-6 ND ug/L 10.0 3.1 1 02/09/1916:02 74-88-4 ND ug/L 1.0 0.50 1 02/09/1916:02 75-09-2 ND ug/L 100 0.86 1 02/09/1916:02 108-10-1 ND ug/L 1.0 0.50 1 02/09/1916:02 100-42-5 ND ug/L 5.0 0.32 1 02/09/1916:02 630-20-6 ND ug/L 3.0 0.53 1 02/09/1916:02 79-34-5 ND ug/L 1.0 0.78 1 02/11/1918:36 127-18-4 ND ug/L 1.0 0.31 1 02/09/1916:02 108-88-3 ND ug/L 1.0 0.38 1 02/09/1916:02 71-55-6 ND ug/L 1.0 0.59 1 02/09/1916:02 79-00-5 ND ug/L 1.0 0.34 1 02/09/1916:02 79-01-6 ND ug/L 1.0 0.51 1 02/09/1916:02 75-69-4 ND ug/L 1.0 0.46 1 02/09/1916:02 96-18-4 ND ug/L 50.0 0.42 1 02/09/1916:02 108-05-4 ND ug/L 1.0 0.60 1 02/09/1916:02 75-01-4 ND ug/L 5.0 1.5 1 02/09/1916:02 1330-20-7 99 %. 81-119 1 02/09/1916:02 17060-07-0 94 %. 82-114 1 02/09/1916:02 1868-53-7 109 %. 82-120 1 02/09/1916:02 460-00-4 101 %. 82-109 1 02/09/1916:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-8 Lab ID: 2614222008 Collected: 01/28/19 09:04 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 22:28 7440-36-0 0.71J ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 22:28 7440-38-2 48.1J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 22:28 7440-39-3 0.20J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 22:28 7440-41-7 ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 22:28 7440-43-9 ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 22:28 7440-47-3 10.2 ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 22:28 7440-48-4 13.0 ug/L 10.0 0.52 1 03/12/1914:02 03/13/1915:12 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 22:28 7440-50-8 ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 22:28 7439-92-1 2.3J ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 22:28 7440-02-0 ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 22:28 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 22:28 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 22:28 7440-28-0 ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 22:28 7440-62-2 3.OJ ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 22:28 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 01/31/19 21:19 123-91-1 96 % 50-150 1 01/31/19 21:19 17060-07-0 114 % 50-150 1 01/31/19 21:19 2037-26-5 Analytical Method: EPA 8260E 24.3J ug/L 100 8.2 1 02/09/1916:27 67-64-1 ND ug/L 200 2.5 1 02/09/1916:27 107-13-1 ND ug/L 1.0 0.20 1 02/09/1916:27 71-43-2 ND ug/L 3.0 0.50 1 02/09/1916:27 74-97-5 ND ug/L 1.0 0.36 1 02/09/1916:27 75-27-4 ND ug/L 3.0 0.55 1 02/09/1916:27 75-25-2 ND ug/L 10.0 0.95 1 02/09/1916:27 74-83-9 ND ug/L 100 3.2 1 02/09/1916:27 78-93-3 ND ug/L 100 0.79 1 02/09/1916:27 75-15-0 ND ug/L 1.0 0.42 1 02/09/1916:27 56-23-5 ND ug/L 3.0 0.53 1 02/09/1916:27 108-90-7 ND ug/L 10.0 0.52 1 02/09/1916:27 75-00-3 ND ug/L 5.0 0.58 1 02/09/1916:27 67-66-3 ND ug/L 1.0 0.38 1 02/09/1916:27 74-87-3 ND ug/L 13.0 0.55 1 02/09/1916:27 96-12-8 ND ug/L 3.0 0.31 1 02/09/1916:27 124-48-1 ND ug/L 2.0 0.28 1 02/09/1916:27 106-93-4 ND ug/L 10.0 0.62 1 02/09/1916:27 74-95-3 ND ug/L 5.0 0.49 1 02/09/1916:27 95-50-1 ND ug/L 1.0 0.58 1 02/09/1916:27 106-46-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-8 Lab ID: 2614222008 Collected: 01/28/19 09:04 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 100 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 10.0 ND ug/L 1.0 ND ug/L 100 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 3.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 50.0 ND ug/L 1.0 ND ug/L 5.0 100 %. 81-119 91 %. 82-114 104 %. 82-120 99 %. 82-109 1.6 1 02/09/19 16:27 110-57-6 0.41 1 02/09/19 16:27 75-34-3 0.67 1 02/09/19 16:27 107-06-2 0.72 1 02/09/19 16:27 75-35-4 0.66 1 02/09/19 16:27 156-59-2 0.46 1 02/09/19 16:27 156-60-5 0.60 1 02/09/19 16:27 78-87-5 0.22 1 02/09/19 16:27 10061-01-5 0.30 1 02/09/19 16:27 10061-02-6 0.45 1 02/09/19 16:27 100-41-4 0.89 1 02/09/19 16:27 591-78-6 3.1 1 02/09/19 16:27 74-88-4 0.50 1 02/09/19 16:27 75-09-2 0.86 1 02/09/19 16:27 108-10-1 0.50 1 02/09/19 16:27 100-42-5 0.32 1 02/09/19 16:27 630-20-6 0.53 1 02/09/19 16:27 79-34-5 0.78 1 02/09/19 16:27 127-18-4 0.31 1 02/09/19 16:27 108-88-3 0.38 1 02/09/19 16:27 71-55-6 0.59 1 02/09/19 16:27 79-00-5 0.34 1 02/09/19 16:27 79-01-6 0.51 1 02/09/19 16:27 75-69-4 0.46 1 02/09/19 16:27 96-18-4 0.42 1 02/09/19 16:27 108-05-4 0.60 1 02/09/19 16:27 75-01-4 1.5 1 02/09/19 16:27 1330-20-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/09/19 16:27 17060-07-0 02/09/19 16:27 1868-53-7 02/09/19 16:27 460-00-4 02/09/19 16:27 2037-26-5 Page 22 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-9 Lab ID: 2614222009 Collected: 01/28/19 08:16 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 22:34 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 22:34 7440-38-2 Barium 10.OJ ug/L 100 0.78 1 02/04/19 13:33 02/04/19 22:34 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 22:34 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 22:34 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 22:34 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 22:34 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 22:34 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 22:34 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 22:34 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 22:34 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 22:34 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 22:34 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 22:34 7440-62-2 Zinc ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 22:34 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 21:39 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 50-150 1 01/31/19 21:39 17060-07-0 Toluene-d8 (S) 117 % 50-150 1 01/31/19 21:39 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 16:53 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 16:53 107-13-1 Benzene 0.46J ug/L 1.0 0.20 1 02/09/19 16:53 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 16:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 16:53 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 16:53 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 16:53 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 16:53 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 16:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 16:53 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 16:53 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 16:53 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 16:53 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 16:53 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 16:53 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 16:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 16:53 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 16:53 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 16:53 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 16:53 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 16:53 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-9 Lab ID: 2614222009 Collected: 01/28/19 08:16 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1916:53 75-34-3 ND ug/L 1.0 0.67 1 02/09/1916:53 107-06-2 ND ug/L 5.0 0.72 1 02/09/1916:53 75-35-4 1.OJ ug/L 5.0 0.66 1 02/09/1916:53 156-59-2 ND ug/L 5.0 0.46 1 02/09/1916:53 156-60-5 ND ug/L 1.0 0.60 1 02/09/1916:53 78-87-5 ND ug/L 1.0 0.22 1 02/09/1916:53 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1916:53 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1916:53 100-41-4 ND ug/L 50.0 0.89 1 02/09/1916:53 591-78-6 ND ug/L 10.0 3.1 1 02/09/1916:53 74-88-4 ND ug/L 1.0 0.50 1 02/09/1916:53 75-09-2 ND ug/L 100 0.86 1 02/09/1916:53 108-10-1 ND ug/L 1.0 0.50 1 02/09/1916:53 100-42-5 ND ug/L 5.0 0.32 1 02/09/1916:53 630-20-6 ND ug/L 3.0 0.53 1 02/09/1916:53 79-34-5 ND ug/L 1.0 0.78 1 02/09/1916:53 127-18-4 ND ug/L 1.0 0.31 1 02/09/1916:53 108-88-3 ND ug/L 1.0 0.38 1 02/09/1916:53 71-55-6 ND ug/L 1.0 0.59 1 02/09/1916:53 79-00-5 ND ug/L 1.0 0.34 1 02/09/1916:53 79-01-6 ND ug/L 1.0 0.51 1 02/09/1916:53 75-69-4 ND ug/L 1.0 0.46 1 02/09/1916:53 96-18-4 ND ug/L 50.0 0.42 1 02/09/1916:53 108-05-4 ND ug/L 1.0 0.60 1 02/09/1916:53 75-01-4 ND ug/L 5.0 1.5 1 02/09/1916:53 1330-20-7 104 %. 81-119 1 02/09/1916:53 17060-07-0 90 %. 82-114 1 02/09/1916:53 1868-53-7 107 %. 82-120 1 02/09/1916:53 460-00-4 102 %. 82-109 1 02/09/1916:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-10 Lab ID: 2614222010 Collected: 01/28/19 07:31 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 22:39 7440-36-0 ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 22:39 7440-38-2 20.9J ug/L 100 0.78 1 02/04/19 13:33 02/04/19 22:39 7440-39-3 ND ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 22:39 7440-41-7 ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 22:39 7440-43-9 ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 22:39 7440-47-3 ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 22:39 7440-48-4 ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 22:39 7440-50-8 ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 22:39 7439-92-1 ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 22:39 7440-02-0 ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 22:39 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 22:39 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 22:39 7440-28-0 3.4J ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 22:39 7440-62-2 ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 22:39 7440-66-6 Analytical Method: EPA 8260E Mod ND ug/L 2.0 1.9 1 01/31/19 21:58 123-91-1 95 % 50-150 1 01/31/19 21:58 17060-07-0 114 % 50-150 1 01/31/19 21:58 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1917:18 67-64-1 ND ug/L 200 2.5 1 02/09/1917:18 107-13-1 ND ug/L 1.0 0.20 1 02/09/1917:18 71-43-2 ND ug/L 3.0 0.50 1 02/09/1917:18 74-97-5 ND ug/L 1.0 0.36 1 02/09/1917:18 75-27-4 ND ug/L 3.0 0.55 1 02/09/1917:18 75-25-2 ND ug/L 10.0 0.95 1 02/09/1917:18 74-83-9 ND ug/L 100 3.2 1 02/09/1917:18 78-93-3 ND ug/L 100 0.79 1 02/09/1917:18 75-15-0 ND ug/L 1.0 0.42 1 02/09/1917:18 56-23-5 ND ug/L 3.0 0.53 1 02/09/1917:18 108-90-7 ND ug/L 10.0 0.52 1 02/09/1917:18 75-00-3 ND ug/L 5.0 0.58 1 02/09/1917:18 67-66-3 ND ug/L 1.0 0.38 1 02/09/1917:18 74-87-3 ND ug/L 13.0 0.55 1 02/09/1917:18 96-12-8 ND ug/L 3.0 0.31 1 02/09/1917:18 124-48-1 ND ug/L 2.0 0.28 1 02/09/1917:18 106-93-4 ND ug/L 10.0 0.62 1 02/09/1917:18 74-95-3 ND ug/L 5.0 0.49 1 02/09/1917:18 95-50-1 ND ug/L 1.0 0.58 1 02/09/1917:18 106-46-7 ND ug/L 100 1.6 1 02/09/1917:18 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-10 Lab ID: 2614222010 Collected: 01/28/19 07:31 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1917:18 75-34-3 ND ug/L 1.0 0.67 1 02/09/1917:18 107-06-2 ND ug/L 5.0 0.72 1 02/09/1917:18 75-35-4 ND ug/L 5.0 0.66 1 02/09/1917:18 156-59-2 ND ug/L 5.0 0.46 1 02/09/1917:18 156-60-5 ND ug/L 1.0 0.60 1 02/09/1917:18 78-87-5 ND ug/L 1.0 0.22 1 02/09/1917:18 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1917:18 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1917:18 100-41-4 ND ug/L 50.0 0.89 1 02/09/1917:18 591-78-6 ND ug/L 10.0 3.1 1 02/09/1917:18 74-88-4 ND ug/L 1.0 0.50 1 02/09/1917:18 75-09-2 ND ug/L 100 0.86 1 02/09/1917:18 108-10-1 ND ug/L 1.0 0.50 1 02/09/1917:18 100-42-5 ND ug/L 5.0 0.32 1 02/09/1917:18 630-20-6 ND ug/L 3.0 0.53 1 02/09/1917:18 79-34-5 ND ug/L 1.0 0.78 1 02/09/1917:18 127-18-4 ND ug/L 1.0 0.31 1 02/09/1917:18 108-88-3 ND ug/L 1.0 0.38 1 02/09/1917:18 71-55-6 ND ug/L 1.0 0.59 1 02/09/1917:18 79-00-5 ND ug/L 1.0 0.34 1 02/09/1917:18 79-01-6 ND ug/L 1.0 0.51 1 02/09/1917:18 75-69-4 ND ug/L 1.0 0.46 1 02/09/1917:18 96-18-4 ND ug/L 50.0 0.42 1 02/09/1917:18 108-05-4 ND ug/L 1.0 0.60 1 02/09/1917:18 75-01-4 ND ug/L 5.0 1.5 1 02/09/1917:18 1330-20-7 100 %. 81-119 1 02/09/1917:18 17060-07-0 91 %. 82-114 1 02/09/1917:18 1868-53-7 103 %. 82-120 1 02/09/1917:18 460-00-4 102 %. 82-109 1 02/09/1917:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-11 Lab ID: 2614222011 Collected: 01/28/19 06:45 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:13 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:13 7440-38-2 Barium 50.4J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:13 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:13 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:13 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:13 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:13 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:13 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:13 7439-92-1 Nickel 1.2J ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:13 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:13 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:13 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:13 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:13 7440-62-2 Zinc 2.3J ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:13 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 22:17 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 93 % 50-150 1 01/31/19 22:17 17060-07-0 Toluene-d8 (S) 113 % 50-150 1 01/31/19 22:17 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 17:43 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 17:43 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 17:43 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 17:43 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 17:43 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 17:43 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 17:43 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 17:43 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 17:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 17:43 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 17:43 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 17:43 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 17:43 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 17:43 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 17:43 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 17:43 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 17:43 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 17:43 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 17:43 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 17:43 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 17:43 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-MW-11 Lab ID: 2614222011 Collected: 01/28/19 06:45 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1917:43 75-34-3 ND ug/L 1.0 0.67 1 02/09/1917:43 107-06-2 ND ug/L 5.0 0.72 1 02/09/1917:43 75-35-4 ND ug/L 5.0 0.66 1 02/09/1917:43 156-59-2 ND ug/L 5.0 0.46 1 02/09/1917:43 156-60-5 ND ug/L 1.0 0.60 1 02/09/1917:43 78-87-5 ND ug/L 1.0 0.22 1 02/09/1917:43 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1917:43 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1917:43 100-41-4 ND ug/L 50.0 0.89 1 02/09/1917:43 591-78-6 ND ug/L 10.0 3.1 1 02/09/1917:43 74-88-4 ND ug/L 1.0 0.50 1 02/09/1917:43 75-09-2 ND ug/L 100 0.86 1 02/09/1917:43 108-10-1 ND ug/L 1.0 0.50 1 02/09/1917:43 100-42-5 ND ug/L 5.0 0.32 1 02/09/1917:43 630-20-6 ND ug/L 3.0 0.53 1 02/09/1917:43 79-34-5 ND ug/L 1.0 0.78 1 02/09/1917:43 127-18-4 ND ug/L 1.0 0.31 1 02/09/1917:43 108-88-3 ND ug/L 1.0 0.38 1 02/09/1917:43 71-55-6 ND ug/L 1.0 0.59 1 02/09/1917:43 79-00-5 ND ug/L 1.0 0.34 1 02/09/1917:43 79-01-6 ND ug/L 1.0 0.51 1 02/09/1917:43 75-69-4 ND ug/L 1.0 0.46 1 02/09/1917:43 96-18-4 ND ug/L 50.0 0.42 1 02/09/1917:43 108-05-4 ND ug/L 1.0 0.60 1 02/09/1917:43 75-01-4 ND ug/L 5.0 1.5 1 02/09/1917:43 1330-20-7 98 %. 81-119 1 02/09/1917:43 17060-07-0 92 %. 82-114 1 02/09/1917:43 1868-53-7 108 %. 82-120 1 02/09/1917:43 460-00-4 100 %. 82-109 1 02/09/1917:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-Field Blank Lab ID: 2614222012 Collected: 01/28/19 06:01 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:19 7440-36-0 ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:19 7440-38-2 ND ug/L 100 0.78 1 02/05/1918:06 02/06/1918:19 7440-39-3 ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:19 7440-41-7 ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:19 7440-43-9 ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:19 7440-47-3 ND ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:19 7440-48-4 ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:19 7440-50-8 ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:19 7439-92-1 ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:19 7440-02-0 ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:19 7782-49-2 ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:19 7440-22-4 ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:19 7440-28-0 ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:19 7440-62-2 ND ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:19 7440-66-6 Analytical Method: EPA 8260E Mod ND ug/L 2.0 1.9 1 01/31/19 22:36 123-91-1 96 % 50-150 1 01/31/19 22:36 17060-07-0 114 % 50-150 1 01/31/19 22:36 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1918:09 67-64-1 ND ug/L 200 2.5 1 02/09/1918:09 107-13-1 ND ug/L 1.0 0.20 1 02/09/1918:09 71-43-2 ND ug/L 3.0 0.50 1 02/09/1918:09 74-97-5 ND ug/L 1.0 0.36 1 02/09/1918:09 75-27-4 ND ug/L 3.0 0.55 1 02/09/1918:09 75-25-2 ND ug/L 10.0 0.95 1 02/09/1918:09 74-83-9 ND ug/L 100 3.2 1 02/09/1918:09 78-93-3 ND ug/L 100 0.79 1 02/09/1918:09 75-15-0 ND ug/L 1.0 0.42 1 02/09/1918:09 56-23-5 ND ug/L 3.0 0.53 1 02/09/1918:09 108-90-7 ND ug/L 10.0 0.52 1 02/09/1918:09 75-00-3 ND ug/L 5.0 0.58 1 02/09/1918:09 67-66-3 ND ug/L 1.0 0.38 1 02/09/1918:09 74-87-3 ND ug/L 13.0 0.55 1 02/09/1918:09 96-12-8 ND ug/L 3.0 0.31 1 02/09/1918:09 124-48-1 ND ug/L 2.0 0.28 1 02/09/1918:09 106-93-4 ND ug/L 10.0 0.62 1 02/09/1918:09 74-95-3 ND ug/L 5.0 0.49 1 02/09/1918:09 95-50-1 ND ug/L 1.0 0.58 1 02/09/1918:09 106-46-7 ND ug/L 100 1.6 1 02/09/1918:09 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-Field Blank Lab ID: 2614222012 Collected: 01/28/19 06:01 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1918:09 75-34-3 ND ug/L 1.0 0.67 1 02/09/1918:09 107-06-2 ND ug/L 5.0 0.72 1 02/09/1918:09 75-35-4 ND ug/L 5.0 0.66 1 02/09/1918:09 156-59-2 ND ug/L 5.0 0.46 1 02/09/1918:09 156-60-5 ND ug/L 1.0 0.60 1 02/09/1918:09 78-87-5 ND ug/L 1.0 0.22 1 02/09/1918:09 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1918:09 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1918:09 100-41-4 ND ug/L 50.0 0.89 1 02/09/1918:09 591-78-6 ND ug/L 10.0 3.1 1 02/09/1918:09 74-88-4 ND ug/L 1.0 0.50 1 02/09/1918:09 75-09-2 ND ug/L 100 0.86 1 02/09/1918:09 108-10-1 ND ug/L 1.0 0.50 1 02/09/1918:09 100-42-5 ND ug/L 5.0 0.32 1 02/09/1918:09 630-20-6 ND ug/L 3.0 0.53 1 02/09/1918:09 79-34-5 ND ug/L 1.0 0.78 1 02/09/1918:09 127-18-4 ND ug/L 1.0 0.31 1 02/09/1918:09 108-88-3 ND ug/L 1.0 0.38 1 02/09/1918:09 71-55-6 ND ug/L 1.0 0.59 1 02/09/1918:09 79-00-5 ND ug/L 1.0 0.34 1 02/09/1918:09 79-01-6 ND ug/L 1.0 0.51 1 02/09/1918:09 75-69-4 ND ug/L 1.0 0.46 1 02/09/1918:09 96-18-4 ND ug/L 50.0 0.42 1 02/09/1918:09 108-05-4 ND ug/L 1.0 0.60 1 02/09/1918:09 75-01-4 ND ug/L 5.0 1.5 1 02/09/1918:09 1330-20-7 98 %. 81-119 1 02/09/1918:09 17060-07-0 94 %. 82-114 1 02/09/1918:09 1868-53-7 105 %. 82-120 1 02/09/1918:09 460-00-4 102 %. 82-109 1 02/09/1918:09 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW1 Lab ID: 2614222013 Collected: 01/28/19 09:18 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:25 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:25 7440-38-2 Barium 15.6J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:25 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:25 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:25 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:25 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:25 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:25 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:25 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:25 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:25 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:25 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:25 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:25 7440-62-2 Zinc ND ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:25 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 22:56 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 50-150 1 01/31/19 22:56 17060-07-0 Toluene-d8 (S) 116 % 50-150 1 01/31/19 22:56 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 18:34 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 18:34 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 18:34 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 18:34 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 18:34 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 18:34 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 18:34 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 18:34 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 18:34 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 18:34 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 18:34 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 18:34 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 18:34 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 18:34 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 18:34 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 18:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 18:34 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 18:34 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 18:34 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 18:34 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 18:34 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW1 Lab ID: 2614222013 Collected: 01/28/19 09:18 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1918:34 75-34-3 ND ug/L 1.0 0.67 1 02/09/1918:34 107-06-2 ND ug/L 5.0 0.72 1 02/09/1918:34 75-35-4 ND ug/L 5.0 0.66 1 02/09/1918:34 156-59-2 ND ug/L 5.0 0.46 1 02/09/1918:34 156-60-5 ND ug/L 1.0 0.60 1 02/09/1918:34 78-87-5 ND ug/L 1.0 0.22 1 02/09/1918:34 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1918:34 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1918:34 100-41-4 ND ug/L 50.0 0.89 1 02/09/1918:34 591-78-6 ND ug/L 10.0 3.1 1 02/09/1918:34 74-88-4 ND ug/L 1.0 0.50 1 02/09/1918:34 75-09-2 ND ug/L 100 0.86 1 02/09/1918:34 108-10-1 ND ug/L 1.0 0.50 1 02/09/1918:34 100-42-5 ND ug/L 5.0 0.32 1 02/09/1918:34 630-20-6 ND ug/L 3.0 0.53 1 02/09/1918:34 79-34-5 ND ug/L 1.0 0.78 1 02/09/1918:34 127-18-4 ND ug/L 1.0 0.31 1 02/09/1918:34 108-88-3 ND ug/L 1.0 0.38 1 02/09/1918:34 71-55-6 ND ug/L 1.0 0.59 1 02/09/1918:34 79-00-5 ND ug/L 1.0 0.34 1 02/09/1918:34 79-01-6 ND ug/L 1.0 0.51 1 02/09/1918:34 75-69-4 ND ug/L 1.0 0.46 1 02/09/1918:34 96-18-4 ND ug/L 50.0 0.42 1 02/09/1918:34 108-05-4 ND ug/L 1.0 0.60 1 02/09/1918:34 75-01-4 ND ug/L 5.0 1.5 1 02/09/1918:34 1330-20-7 99 %. 81-119 1 02/09/1918:34 17060-07-0 93 %. 82-114 1 02/09/1918:34 1868-53-7 101 %. 82-120 1 02/09/1918:34 460-00-4 101 %. 82-109 1 02/09/1918:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW2 Lab ID: 2614222014 Collected: 01/28/19 12:15 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:30 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:30 7440-38-2 Barium 25.2J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:30 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:30 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:30 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:30 7440-47-3 Cobalt 0.70J ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:30 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:30 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:30 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:30 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:30 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:30 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:30 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:30 7440-62-2 Zinc 4.6J ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:30 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 23:15 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 50-150 1 01/31/19 23:15 17060-07-0 Toluene-d8 (S) 114 % 50-150 1 01/31/19 23:15 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 18:59 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 18:59 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 18:59 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 18:59 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 18:59 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 18:59 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 18:59 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 18:59 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 18:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 18:59 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 18:59 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 18:59 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 18:59 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 18:59 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 18:59 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 18:59 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 18:59 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 18:59 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 18:59 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 18:59 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 18:59 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW2 Lab ID: 2614222014 Collected: 01/28/19 12:15 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1918:59 75-34-3 ND ug/L 1.0 0.67 1 02/09/1918:59 107-06-2 ND ug/L 5.0 0.72 1 02/09/1918:59 75-35-4 ND ug/L 5.0 0.66 1 02/09/1918:59 156-59-2 ND ug/L 5.0 0.46 1 02/09/1918:59 156-60-5 ND ug/L 1.0 0.60 1 02/09/1918:59 78-87-5 ND ug/L 1.0 0.22 1 02/09/1918:59 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1918:59 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1918:59 100-41-4 ND ug/L 50.0 0.89 1 02/09/1918:59 591-78-6 ND ug/L 10.0 3.1 1 02/09/1918:59 74-88-4 ND ug/L 1.0 0.50 1 02/09/1918:59 75-09-2 ND ug/L 100 0.86 1 02/09/1918:59 108-10-1 ND ug/L 1.0 0.50 1 02/09/1918:59 100-42-5 ND ug/L 5.0 0.32 1 02/09/1918:59 630-20-6 ND ug/L 3.0 0.53 1 02/09/1918:59 79-34-5 ND ug/L 1.0 0.78 1 02/09/1918:59 127-18-4 ND ug/L 1.0 0.31 1 02/09/1918:59 108-88-3 ND ug/L 1.0 0.38 1 02/09/1918:59 71-55-6 ND ug/L 1.0 0.59 1 02/09/1918:59 79-00-5 ND ug/L 1.0 0.34 1 02/09/1918:59 79-01-6 ND ug/L 1.0 0.51 1 02/09/1918:59 75-69-4 ND ug/L 1.0 0.46 1 02/09/1918:59 96-18-4 ND ug/L 50.0 0.42 1 02/09/1918:59 108-05-4 ND ug/L 1.0 0.60 1 02/09/1918:59 75-01-4 ND ug/L 5.0 1.5 1 02/09/1918:59 1330-20-7 96 %. 81-119 1 02/09/1918:59 17060-07-0 90 %. 82-114 1 02/09/1918:59 1868-53-7 107 %. 82-120 1 02/09/1918:59 460-00-4 99 %. 82-109 1 02/09/1918:59 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW3 Lab ID: 2614222015 Collected: 01/28/19 15:50 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:36 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:36 7440-38-2 Barium 24.2J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:36 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:36 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:36 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:36 7440-47-3 Cobalt 0.63J ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:36 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:36 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:36 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:36 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:36 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:36 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:36 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:36 7440-62-2 Zinc 3.2J ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:36 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 23:34 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 50-150 1 01/31/19 23:34 17060-07-0 Toluene-d8 (S) 114 % 50-150 1 01/31/19 23:34 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 19:25 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 19:25 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 19:25 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 19:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 19:25 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 19:25 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 19:25 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 19:25 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 19:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 19:25 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 19:25 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 19:25 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 19:25 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 19:25 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 19:25 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 19:25 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 19:25 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 19:25 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 19:25 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 19:25 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 19:25 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW3 Lab ID: 2614222015 Collected: 01/28/19 15:50 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1919:25 75-34-3 ND ug/L 1.0 0.67 1 02/09/1919:25 107-06-2 ND ug/L 5.0 0.72 1 02/09/1919:25 75-35-4 ND ug/L 5.0 0.66 1 02/09/1919:25 156-59-2 ND ug/L 5.0 0.46 1 02/09/1919:25 156-60-5 ND ug/L 1.0 0.60 1 02/09/1919:25 78-87-5 ND ug/L 1.0 0.22 1 02/09/1919:25 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1919:25 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1919:25 100-41-4 ND ug/L 50.0 0.89 1 02/09/1919:25 591-78-6 ND ug/L 10.0 3.1 1 02/09/1919:25 74-88-4 ND ug/L 1.0 0.50 1 02/09/1919:25 75-09-2 ND ug/L 100 0.86 1 02/09/1919:25 108-10-1 ND ug/L 1.0 0.50 1 02/09/1919:25 100-42-5 ND ug/L 5.0 0.32 1 02/09/1919:25 630-20-6 ND ug/L 3.0 0.53 1 02/09/1919:25 79-34-5 ND ug/L 1.0 0.78 1 02/09/1919:25 127-18-4 ND ug/L 1.0 0.31 1 02/09/1919:25 108-88-3 ND ug/L 1.0 0.38 1 02/09/1919:25 71-55-6 ND ug/L 1.0 0.59 1 02/09/1919:25 79-00-5 ND ug/L 1.0 0.34 1 02/09/1919:25 79-01-6 ND ug/L 1.0 0.51 1 02/09/1919:25 75-69-4 ND ug/L 1.0 0.46 1 02/09/1919:25 96-18-4 ND ug/L 50.0 0.42 1 02/09/1919:25 108-05-4 ND ug/L 1.0 0.60 1 02/09/1919:25 75-01-4 ND ug/L 5.0 1.5 1 02/09/1919:25 1330-20-7 100 %. 81-119 1 02/09/1919:25 17060-07-0 96 %. 82-114 1 02/09/1919:25 1868-53-7 108 %. 82-120 1 02/09/1919:25 460-00-4 101 %. 82-109 1 02/09/1919:25 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW4 Lab ID: 2614222016 Collected: 01/28/19 15:32 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:42 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:42 7440-38-2 Barium 24.7J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:42 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:42 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:42 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:42 7440-47-3 Cobalt 0.63J ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:42 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:42 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:42 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:42 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:42 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:42 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:42 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:42 7440-62-2 Zinc 3.1J ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:42 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 01/31/19 23:53 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 95 % 50-150 1 01/31/19 23:53 17060-07-0 Toluene-d8 (S) 112 % 50-150 1 01/31/19 23:53 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 02/09/19 19:50 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 02/09/19 19:50 107-13-1 Benzene ND ug/L 1.0 0.20 1 02/09/19 19:50 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 02/09/19 19:50 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 02/09/19 19:50 75-27-4 Bromoform ND ug/L 3.0 0.55 1 02/09/19 19:50 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 02/09/19 19:50 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 02/09/19 19:50 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 02/09/19 19:50 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 02/09/19 19:50 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 02/09/19 19:50 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 02/09/19 19:50 75-00-3 Chloroform ND ug/L 5.0 0.58 1 02/09/19 19:50 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 02/09/19 19:50 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 02/09/19 19:50 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 02/09/19 19:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 02/09/19 19:50 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 02/09/19 19:50 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 02/09/19 19:50 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 02/09/19 19:50 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 02/09/19 19:50 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-SW4 Lab ID: 2614222016 Collected: 01/28/19 15:32 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 02/09/1919:50 75-34-3 ND ug/L 1.0 0.67 1 02/09/1919:50 107-06-2 ND ug/L 5.0 0.72 1 02/09/1919:50 75-35-4 ND ug/L 5.0 0.66 1 02/09/1919:50 156-59-2 ND ug/L 5.0 0.46 1 02/09/1919:50 156-60-5 ND ug/L 1.0 0.60 1 02/09/1919:50 78-87-5 ND ug/L 1.0 0.22 1 02/09/1919:50 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1919:50 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1919:50 100-41-4 ND ug/L 50.0 0.89 1 02/09/1919:50 591-78-6 ND ug/L 10.0 3.1 1 02/09/1919:50 74-88-4 ND ug/L 1.0 0.50 1 02/09/1919:50 75-09-2 ND ug/L 100 0.86 1 02/09/1919:50 108-10-1 ND ug/L 1.0 0.50 1 02/09/1919:50 100-42-5 ND ug/L 5.0 0.32 1 02/09/1919:50 630-20-6 ND ug/L 3.0 0.53 1 02/09/1919:50 79-34-5 ND ug/L 1.0 0.78 1 02/09/1919:50 127-18-4 ND ug/L 1.0 0.31 1 02/09/1919:50 108-88-3 ND ug/L 1.0 0.38 1 02/09/1919:50 71-55-6 ND ug/L 1.0 0.59 1 02/09/1919:50 79-00-5 ND ug/L 1.0 0.34 1 02/09/1919:50 79-01-6 ND ug/L 1.0 0.51 1 02/09/1919:50 75-69-4 ND ug/L 1.0 0.46 1 02/09/1919:50 96-18-4 ND ug/L 50.0 0.42 1 02/09/1919:50 108-05-4 ND ug/L 1.0 0.60 1 02/09/1919:50 75-01-4 ND ug/L 5.0 1.5 1 02/09/1919:50 1330-20-7 100 %. 81-119 1 02/09/1919:50 17060-07-0 91 %. 82-114 1 02/09/1919:50 1868-53-7 107 %. 82-120 1 02/09/1919:50 460-00-4 100 %. 82-109 1 02/09/1919:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-UD1 Lab ID: 2614222017 Collected: 01/28/19 12:01 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:48 7440-36-0 ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:48 7440-38-2 76.8J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:48 7440-39-3 0.055J ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:48 7440-41-7 ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:48 7440-43-9 ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:48 7440-47-3 9.1J ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:48 7440-48-4 ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:48 7440-50-8 ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:48 7439-92-1 1.8J ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:48 7440-02-0 ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:48 7782-49-2 ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:48 7440-22-4 ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:48 7440-28-0 2.5J ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:48 7440-62-2 8.4J ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:48 7440-66-6 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/11/1918:00 67-64-1 ND ug/L 200 2.5 1 02/11/1918:00 107-13-1 ND ug/L 1.0 0.20 1 02/11/1918:00 71-43-2 ND ug/L 3.0 0.50 1 02/11/1918:00 74-97-5 ND ug/L 1.0 0.36 1 02/11/1918:00 75-27-4 ND ug/L 3.0 0.55 1 02/11/1918:00 75-25-2 ND ug/L 10.0 0.95 1 02/11/1918:00 74-83-9 ND ug/L 100 3.2 1 02/11/1918:00 78-93-3 ND ug/L 100 0.79 1 02/11/1918:00 75-15-0 ND ug/L 1.0 0.42 1 02/11/1918:00 56-23-5 ND ug/L 3.0 0.53 1 02/11/1918:00 108-90-7 ND ug/L 10.0 0.52 1 02/11/1918:00 75-00-3 ND ug/L 5.0 0.58 1 02/11/1918:00 67-66-3 ND ug/L 1.0 0.38 1 02/11/1918:00 74-87-3 ND ug/L 13.0 0.55 1 02/11/1918:00 96-12-8 ND ug/L 3.0 0.31 1 02/11/1918:00 124-48-1 ND ug/L 2.0 0.28 1 02/11/1918:00 106-93-4 ND ug/L 10.0 0.62 1 02/11/1918:00 74-95-3 ND ug/L 5.0 0.49 1 02/11/1918:00 95-50-1 ND ug/L 1.0 0.58 1 02/11/1918:00 106-46-7 ND ug/L 100 1.6 1 02/11/1918:00 110-57-6 ND ug/L 5.0 0.41 1 02/11/1918:00 75-34-3 ND ug/L 1.0 0.67 1 02/11/1918:00 107-06-2 ND ug/L 5.0 0.72 1 02/11/1918:00 75-35-4 ND ug/L 5.0 0.66 1 02/11/1918:00 156-59-2 ND ug/L 5.0 0.46 1 02/11/1918:00 156-60-5 ND ug/L 1.0 0.60 1 02/11/1918:00 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-UD1 Parameters 8260B MSV Water, Extend cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM ANALYTICAL RESULTS Lab ID: 2614222017 Collected: 01/28/19 12:01 Received: 01/29/19 10:00 Matrix: Water Report Reg. Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260E ND ug/L 1.0 0.22 1 02/11/1918:00 10061-01-5 ND ug/L 1.0 0.30 1 02/11/1918:00 10061-02-6 ND ug/L 1.0 0.45 1 02/11/1918:00 100-41-4 ND ug/L 50.0 0.89 1 02/11/1918:00 591-78-6 ND ug/L 10.0 3.1 1 02/11/1918:00 74-88-4 ND ug/L 1.0 0.50 1 02/11/1918:00 75-09-2 ND ug/L 100 0.86 1 02/11/1918:00 108-10-1 ND ug/L 1.0 0.50 1 02/11/1918:00 100-42-5 ND ug/L 5.0 0.32 1 02/11/1918:00 630-20-6 ND ug/L 3.0 0.53 1 02/11/1918:00 79-34-5 ND ug/L 1.0 0.78 1 02/11/1918:00 127-18-4 ND ug/L 1.0 0.31 1 02/11/1918:00 108-88-3 ND ug/L 1.0 0.38 1 02/11/1918:00 71-55-6 ND ug/L 1.0 0.59 1 02/11/1918:00 79-00-5 ND ug/L 1.0 0.34 1 02/11/1918:00 79-01-6 ND ug/L 1.0 0.51 1 02/11/1918:00 75-69-4 ND ug/L 1.0 0.46 1 02/11/1918:00 96-18-4 ND ug/L 50.0 0.42 1 02/11/1918:00 108-05-4 ND ug/L 1.0 0.60 1 02/11/1918:00 75-01-4 ND ug/L 5.0 1.5 1 02/11/1918:00 1330-20-7 99 %. 81-119 1 02/11/1918:00 17060-07-0 94 %. 82-114 1 02/11/1918:00 1868-53-7 109 %. 82-120 1 02/11/1918:00 460-00-4 97 %. 82-109 1 02/11/1918:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-UD2 Lab ID: 2614222018 Collected: 01/28/19 10:16 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 03/20/2019 10:31 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 02/05/1918:06 02/06/1918:53 7440-36-0 ND ug/L 10.0 0.57 1 02/05/1918:06 02/06/1918:53 7440-38-2 49.4J ug/L 100 0.78 1 02/05/1918:06 02/06/1918:53 7440-39-3 ND ug/L 1.0 0.050 1 02/05/1918:06 02/06/1918:53 7440-41-7 ND ug/L 1.0 0.093 1 02/05/1918:06 02/06/1918:53 7440-43-9 ND ug/L 10.0 1.6 1 02/05/1918:06 02/06/1918:53 7440-47-3 6.OJ ug/L 10.0 0.52 1 02/05/1918:06 02/06/1918:53 7440-48-4 ND ug/L 10.0 1.3 1 02/05/1918:06 02/06/1918:53 7440-50-8 ND ug/L 10.0 0.27 1 02/05/1918:06 02/06/1918:53 7439-92-1 ND ug/L 50.0 0.95 1 02/05/1918:06 02/06/1918:53 7440-02-0 ND ug/L 10.0 1.4 1 02/05/1918:06 02/06/1918:53 7782-49-2 ND ug/L 10.0 0.95 1 02/05/1918:06 02/06/1918:53 7440-22-4 ND ug/L 5.5 0.14 1 02/05/1918:06 02/06/1918:53 7440-28-0 2.8J ug/L 25.0 1.9 1 02/05/1918:06 02/06/1918:53 7440-62-2 ND ug/L 10.0 2.1 1 02/05/1918:06 02/06/1918:53 7440-66-6 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/11/1918:25 67-64-1 ND ug/L 200 2.5 1 02/11/1918:25 107-13-1 ND ug/L 1.0 0.20 1 02/11/1918:25 71-43-2 ND ug/L 3.0 0.50 1 02/11/1918:25 74-97-5 ND ug/L 1.0 0.36 1 02/11/1918:25 75-27-4 ND ug/L 3.0 0.55 1 02/11/1918:25 75-25-2 ND ug/L 10.0 0.95 1 02/11/1918:25 74-83-9 ND ug/L 100 3.2 1 02/11/1918:25 78-93-3 ND ug/L 100 0.79 1 02/11/1918:25 75-15-0 ND ug/L 1.0 0.42 1 02/11/1918:25 56-23-5 ND ug/L 3.0 0.53 1 02/11/1918:25 108-90-7 ND ug/L 10.0 0.52 1 02/11/1918:25 75-00-3 ND ug/L 5.0 0.58 1 02/11/1918:25 67-66-3 ND ug/L 1.0 0.38 1 02/11/1918:25 74-87-3 ND ug/L 13.0 0.55 1 02/11/1918:25 96-12-8 ND ug/L 3.0 0.31 1 02/11/1918:25 124-48-1 ND ug/L 2.0 0.28 1 02/11/1918:25 106-93-4 ND ug/L 10.0 0.62 1 02/11/1918:25 74-95-3 ND ug/L 5.0 0.49 1 02/11/1918:25 95-50-1 ND ug/L 1.0 0.58 1 02/11/1918:25 106-46-7 ND ug/L 100 1.6 1 02/11/1918:25 110-57-6 ND ug/L 5.0 0.41 1 02/11/1918:25 75-34-3 ND ug/L 1.0 0.67 1 02/11/1918:25 107-06-2 ND ug/L 5.0 0.72 1 02/11/1918:25 75-35-4 ND ug/L 5.0 0.66 1 02/11/1918:25 156-59-2 ND ug/L 5.0 0.46 1 02/11/1918:25 156-60-5 ND ug/L 1.0 0.60 1 02/11/1918:25 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC 1403 Pace Project No.: 2614222 Sample: 1403-UD2 Parameters 8260B MSV Water, Extend cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/20/2019 10:31 AM ANALYTICAL RESULTS Lab ID: 2614222018 Collected: 01/28/19 10:16 Received: 01/29/19 10:00 Matrix: Water Report Reg. Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260E ND ug/L 1.0 0.22 1 02/11/1918:25 10061-01-5 ND ug/L 1.0 0.30 1 02/11/1918:25 10061-02-6 ND ug/L 1.0 0.45 1 02/11/1918:25 100-41-4 ND ug/L 50.0 0.89 1 02/11/1918:25 591-78-6 ND ug/L 10.0 3.1 1 02/11/1918:25 74-88-4 ND ug/L 1.0 0.50 1 02/11/1918:25 75-09-2 ND ug/L 100 0.86 1 02/11/1918:25 108-10-1 ND ug/L 1.0 0.50 1 02/11/1918:25 100-42-5 ND ug/L 5.0 0.32 1 02/11/1918:25 630-20-6 ND ug/L 3.0 0.53 1 02/11/1918:25 79-34-5 ND ug/L 1.0 0.78 1 02/11/1918:25 127-18-4 ND ug/L 1.0 0.31 1 02/11/1918:25 108-88-3 ND ug/L 1.0 0.38 1 02/11/1918:25 71-55-6 ND ug/L 1.0 0.59 1 02/11/1918:25 79-00-5 ND ug/L 1.0 0.34 1 02/11/1918:25 79-01-6 ND ug/L 1.0 0.51 1 02/11/1918:25 75-69-4 ND ug/L 1.0 0.46 1 02/11/1918:25 96-18-4 ND ug/L 50.0 0.42 1 02/11/1918:25 108-05-4 ND ug/L 1.0 0.60 1 02/11/1918:25 75-01-4 ND ug/L 5.0 1.5 1 02/11/1918:25 1330-20-7 95 %. 81-119 1 02/11/1918:25 17060-07-0 93 %. 82-114 1 02/11/1918:25 1868-53-7 105 %. 82-120 1 02/11/1918:25 460-00-4 99 %. 82-109 1 02/11/1918:25 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 21711 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009,2614222010 METHOD BLANK: 97845 Associated Lab Samples: Parameter Matrix: Water 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009,2614222010 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Antimony ug/L 0.891 6.0 0.78 02/04/1919:54 Arsenic ug/L ND 10.0 0.57 02/04/1919:54 Barium ug/L ND 100 0.78 02/04/1919:54 Beryllium ug/L ND 1.0 0.050 02/04/1919:54 Cadmium ug/L ND 1.0 0.093 02/04/1919:54 Chromium ug/L ND 10.0 1.6 02/04/1919:54 Cobalt ug/L ND 10.0 0.52 02/04/1919:54 Copper ug/L ND 10.0 1.3 02/04/1919:54 Lead ug/L ND 10.0 0.27 02/04/1919:54 Nickel ug/L ND 50.0 0.95 02/04/1919:54 Selenium ug/L ND 10.0 1.4 02/04/1919:54 Silver ug/L ND 10.0 0.95 02/04/1919:54 Thallium ug/L ND 5.5 0.14 02/04/1919:54 Vanadium ug/L ND 25.0 1.9 02/04/1919:54 Zinc ug/L ND 10.0 2.1 02/04/1919:54 LABORATORY CONTROL SAMPLE: Parameter 97846 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 110 110 80-120 Arsenic ug/L 100 95.0 95 80-120 Barium ug/L 100 99.91 100 80-120 Beryllium ug/L 100 98.5 98 80-120 Cadmium ug/L 100 96.8 97 80-120 Chromium ug/L 100 102 102 80-120 Cobalt ug/L 100 97.8 98 80-120 Copper ug/L 100 98.5 98 80-120 Lead ug/L 100 95.1 95 80-120 Nickel ug/L 100 96.9 97 80-120 Selenium ug/L 100 97.2 97 80-120 Silver ug/L 100 102 102 80-120 Thallium ug/L 100 95.2 95 80-120 Vanadium ug/L 100 101 101 80-120 Zinc ug/L 100 98.2 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 43 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97849 97850 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 112 106 112 75-125 5 20 Arsenic ug/L 1.7J 100 100 94.1 95.2 92 93 75-125 1 20 Barium ug/L 119 100 100 202 209 83 91 75-125 4 20 Beryllium ug/L 0.071J 100 100 95.1 101 95 101 75-125 6 20 Cadmium ug/L ND 100 100 94.4 100 94 100 75-125 6 20 Chromium ug/L ND 100 100 107 103 106 102 75-125 4 20 Cobalt ug/L ND 100 100 99.5 99.0 99 99 75-125 0 20 Copper ug/L ND 100 100 99.6 98.3 99 98 75-125 1 20 Lead ug/L ND 100 100 95.9 98.3 96 98 75-125 3 20 Nickel ug/L ND 100 100 99.3 99.2 99 99 75-125 0 20 Selenium ug/L 20.4 100 100 92.1 99.5 72 79 75-125 8 20 M1 Silver ug/L ND 100 100 99.7 102 100 102 75-125 2 20 Thallium ug/L ND 100 100 96.2 97.7 96 98 75-125 2 20 Vanadium ug/L 2.6J 100 100 109 107 106 104 75-125 2 20 Zinc ug/L ND 100 100 96.6 101 96 100 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 44 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 21821 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016, 2614222017, 2614222018 METHOD BLANK: 98209 Matrix: Water Associated Lab Samples: 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016, 2614222017, 2614222018 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 02/06/1917:54 Arsenic ug/L ND 10.0 0.57 02/06/1917:54 Barium ug/L ND 100 0.78 02/06/1917:54 Beryllium ug/L ND 1.0 0.050 02/06/1917:54 Cadmium ug/L ND 1.0 0.093 02/06/1917:54 Chromium ug/L ND 10.0 1.6 02/06/1917:54 Cobalt ug/L ND 10.0 0.52 02/06/1917:54 Copper ug/L ND 10.0 1.3 02/06/1917:54 Lead ug/L ND 10.0 0.27 02/06/1917:54 Nickel ug/L ND 50.0 0.95 02/06/1917:54 Selenium ug/L ND 10.0 1.4 02/06/1917:54 Silver ug/L ND 10.0 0.95 02/06/1917:54 Thallium ug/L ND 5.5 0.14 02/06/1917:54 Vanadium ug/L ND 25.0 1.9 02/06/1917:54 Zinc ug/L ND 10.0 2.1 02/06/1917:54 LABORATORY CONTROL SAMPLE: 98210 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 101 101 80-120 Arsenic ug/L 100 97.9 98 80-120 Barium ug/L 100 99.91 100 80-120 Beryllium ug/L 100 102 102 80-120 Cadmium ug/L 100 97.8 98 80-120 Chromium ug/L 100 102 102 80-120 Cobalt ug/L 100 98.4 98 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 99.5 100 80-120 Nickel ug/L 100 99.8 100 80-120 Selenium ug/L 100 99.8 100 80-120 Silver ug/L 100 105 105 80-120 Thallium ug/L 100 99.3 99 80-120 Vanadium ug/L 100 103 103 80-120 Zinc ug/L 100 100 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 45 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 98211 98212 MS MSD 2614222018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 105 107 105 107 75-125 2 20 Arsenic ug/L ND 100 100 101 104 100 104 75-125 3 20 Barium ug/L 49AJ 100 100 149 153 99 104 75-125 3 20 Beryllium ug/L ND 100 100 102 107 102 107 75-125 5 20 Cadmium ug/L ND 100 100 99.6 103 100 103 75-125 3 20 Chromium ug/L ND 100 100 108 110 108 110 75-125 2 20 Cobalt ug/L 6.OJ 100 100 111 112 105 106 75-125 1 20 Copper ug/L ND 100 100 103 109 103 109 75-125 5 20 Lead ug/L ND 100 100 102 103 102 103 75-125 1 20 Nickel ug/L ND 100 100 104 108 103 107 75-125 4 20 Selenium ug/L ND 100 100 102 106 102 106 75-125 4 20 Silver ug/L ND 100 100 104 108 104 108 75-125 4 20 Thallium ug/L ND 100 100 103 103 103 103 75-125 0 20 Vanadium ug/L 2.8J 100 100 109 111 106 109 75-125 2 20 Zinc ug/L ND 100 100 102 103 100 101 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 46 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 24111 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2614222003, 2614222005, 2614222006, 2614222008 METHOD BLANK: 108038 Matrix: Water Associated Lab Samples: 2614222003, 2614222005, 2614222006, 2614222008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cobalt ug/L ND 10.0 0.52 03/13/1914:26 Selenium ug/L ND 10.0 1.4 03/13/1914:26 LABORATORY CONTROL SAMPLE: 108039 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cobalt ug/L 100 97.2 97 80-120 Selenium ug/L 100 98.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 108040 108041 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cobalt ug/L ND 100 100 130 136 130 136 75-125 5 20 M1 Selenium ug/L 20.4 100 100 130 138 130 138 75-125 5 20 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 47 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 455695 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 METHOD BLANK: 2487081 Matrix: Water Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 01/31/19 16:10 1,2-Dichloroethane-d4 (S) % 93 50-150 01/31/19 16:10 Toluene-d8 (S) % 113 50-150 01/31/19 16:10 LABORATORY CONTROL SAMPLE: 2487082 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.7 98 71-125 1,2-Dichloroethane-d4 (S) % 93 50-150 Toluene-d8 (S) % 108 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2487083 2487084 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.5 ND 97 0 50-150 30 M1 1,2-Dichloroethane-d4 (S) % 97 97 50-150 30 Toluene-d8 (S) % 116 114 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 48 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 22128 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 METHOD BLANK: 99745 Matrix: Water Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 02/09/19 11:22 1,1,1-Trichloroethane ug/L ND 1.0 0.38 02/09/19 11:22 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 02/09/19 11:22 1,1,2-Trichloroethane ug/L ND 1.0 0.59 02/09/19 11:22 1,1-Dichloroethane ug/L ND 5.0 0.41 02/09/19 11:22 1,1-Dichloroethene ug/L ND 5.0 0.72 02/09/19 11:22 1,1-Dichloropropene ug/L ND 1.0 0.60 02/09/19 11:22 1,2,3-Trichlorobenzene ug/L ND 1.0 0.53 02/09/19 11:22 1,2,3-Trichloropropane ug/L ND 1.0 0.46 02/09/19 11:22 1,2,4-Trichlorobenzene ug/L ND 1.0 0.47 02/09/19 11:22 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 02/09/19 11:22 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 02/09/19 11:22 1,2-Dichlorobenzene ug/L ND 5.0 0.49 02/09/19 11:22 1,2-Dichloroethane ug/L ND 1.0 0.67 02/09/19 11:22 1,2-Dichloropropane ug/L ND 1.0 0.60 02/09/19 11:22 1,3-Dichlorobenzene ug/L ND 1.0 0.59 02/09/19 11:22 1,3-Dichloropropane ug/L ND 1.0 0.69 02/09/19 11:22 1,4-Dichlorobenzene ug/L ND 1.0 0.58 02/09/19 11:22 2,2-Dichloropropane ug/L ND 1.0 0.23 02/09/19 11:22 2-Butanone (MEK) ug/L ND 100 3.2 02/09/19 11:22 2-Chlorotoluene ug/L ND 1.0 0.26 02/09/19 11:22 2-Hexanone ug/L ND 50.0 0.89 02/09/19 11:22 4-Chlorotoluene ug/L ND 1.0 0.68 02/09/19 11:22 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 02/09/19 11:22 Acetone ug/L ND 100 8.2 02/09/19 11:22 Acrolein ug/L ND 50.0 7.8 02/09/19 11:22 Acrylonitrile ug/L ND 200 2.5 02/09/19 11:22 Allyl chloride ug/L ND 10.0 0.96 02/09/19 11:22 Benzene ug/L ND 1.0 0.20 02/09/19 11:22 Bromobenzene ug/L ND 1.0 0.58 02/09/19 11:22 Bromochloromethane ug/L ND 3.0 0.50 02/09/19 11:22 Bromodichloromethane ug/L ND 1.0 0.36 02/09/19 11:22 Bromoform ug/L ND 3.0 0.55 02/09/19 11:22 Bromomethane ug/L ND 10.0 0.95 02/09/19 11:22 Carbon disulfide ug/L ND 100 0.79 02/09/19 11:22 Carbon tetrachloride ug/L ND 1.0 0.42 02/09/19 11:22 Chlorobenzene ug/L ND 3.0 0.53 02/09/19 11:22 Chloroethane ug/L ND 10.0 0.52 02/09/19 11:22 Chloroform ug/L ND 5.0 0.58 02/09/19 11:22 Chloromethane ug/L ND 1.0 0.38 02/09/19 11:22 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 49 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 METHOD BLANK: 99745 Matrix: Water Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers cis-1,2-Dichloroethene ug/L ND 5.0 0.66 02/09/19 11:22 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 02/09/19 11:22 Dibromochloromethane ug/L ND 3.0 0.31 02/09/19 11:22 Dibromomethane ug/L ND 10.0 0.62 02/09/19 11:22 Dichlorodifluoromethane ug/L ND 1.0 0.48 02/09/19 11:22 Diisopropyl ether ug/L ND 10.0 1.1 02/09/19 11:22 Ethyl methacrylate ug/L ND 10.0 0.59 02/09/19 11:22 Ethylbenzene ug/L ND 1.0 0.45 02/09/19 11:22 Hexachloro-1,3-butadiene ug/L ND 10.0 1.2 02/09/19 11:22 lodomethane ug/L ND 10.0 3.1 02/09/19 11:22 m&p-Xylene ug/L ND 1.0 0.92 02/09/19 11:22 Methacrylonitrile ug/L ND 10.0 0.79 02/09/19 11:22 Methyl methacrylate ug/L ND 10.0 0.89 02/09/19 11:22 Methyl-tert-butyl ether ug/L ND 10.0 1.6 02/09/19 11:22 Methylene Chloride ug/L ND 1.0 0.50 02/09/19 11:22 Naphthalene ug/L ND 1.0 0.30 02/09/19 11:22 o-Xylene ug/L ND 1.0 0.54 02/09/19 11:22 p-Isopropyltoluene ug/L ND 1.0 0.47 02/09/19 11:22 Propionitrile ug/L ND 20.0 3.1 02/09/19 11:22 Styrene ug/L ND 1.0 0.50 02/09/19 11:22 Toluene ug/L ND 1.0 0.31 02/09/19 11:22 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 02/09/19 11:22 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 02/09/19 11:22 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 02/09/19 11:22 Trichloroethene ug/L ND 1.0 0.34 02/09/19 11:22 Trichlorofluoromethane ug/L ND 1.0 0.51 02/09/19 11:22 Vinyl acetate ug/L ND 50.0 0.42 02/09/19 11:22 Vinyl chloride ug/L ND 1.0 0.60 02/09/19 11:22 Xylene (Total) ug/L ND 5.0 1.5 02/09/19 11:22 1,2-Dichloroethane-d4 (S) %. 94 81-119 02/09/19 11:22 4-Bromofluorobenzene (S) %. 105 82-120 02/09/19 11:22 Dibromofluoromethane (S) %. 92 82-114 02/09/19 11:22 Toluene-d8 (S) %. 99 82-109 02/09/19 11:22 METHOD BLANK: 100248 Matrix: Water Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.78 02/11/19 11:31 1,2-Dichloroethane-d4 (S) %. 99 81-119 02/11/19 11:31 4-Bromofluorobenzene (S) %. 99 82-120 02/11/19 11:31 Dibromofluoromethane (S) %. 94 82-114 02/11/19 11:31 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 50 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 METHOD BLANK: 100248 Matrix: Water Associated Lab Samples: 2614222001, 2614222002, 2614222003, 2614222004, 2614222005, 2614222006, 2614222007, 2614222008, 2614222009, 2614222010, 2614222011, 2614222012, 2614222013, 2614222014, 2614222015, 2614222016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene-d8 (S) %. 91 82-109 02/11/19 11:31 LABORATORY CONTROL SAMPLE: Parameter 99746 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 44.2 88 68-137 1,1,1-Trichloroethane ug/L 50 54.5 109 72-134 1,1,2,2-Tetrachloroethane ug/L 50 46.8 94 51-158 1,1,2-Trichloroethane ug/L 50 49.1 98 78-131 1,1-Dichloroethane ug/L 50 49.8 100 69-151 1,1-Dichloroethene ug/L 50 48.2 96 64-158 1,1-Dichloropropene ug/L 50 48.5 97 70-133 1,2,3-Trichlorobenzene ug/L 50 42.6 85 73-130 1,2,3-Trichloropropane ug/L 50 50.0 100 78-133 1,2,4-Trichlorobenzene ug/L 50 44.6 89 51-163 1,2-Dibromo-3-chloropropane ug/L 50 38.9 78 58-124 1,2-Dibromoethane (EDB) ug/L 50 44.8 90 71-134 1,2-Dichlorobenzene ug/L 50 48.6 97 70-135 1,2-Dichloroethane ug/L 50 45.5 91 72-129 1,2-Dichloropropane ug/L 50 48.7 97 64-135 1,3-Dichlorobenzene ug/L 50 50.1 100 71-134 1,3-Dichloropropane ug/L 50 51.0 102 70-140 1,4-Dichlorobenzene ug/L 50 46.8 94 70-131 2,2-Dichloropropane ug/L 50 46.8 94 34-170 2-Butanone (MEK) ug/L 100 78.8J 79 52-143 2-Chlorotoluene ug/L 50 52.5 105 77-128 2-Hexanone ug/L 100 78.0 78 61-136 4-Chlorotoluene ug/L 50 54.1 108 79-126 4-Methyl-2-pentanone (MIBK) ug/L 100 75.OJ 75 71-129 Acetone ug/L 100 71.OJ 71 48-224 Acrolein ug/L 100 97.7 98 57-185 Acrylonitrile ug/L 200 233 116 66-154 Allyl chloride ug/L 100 103 103 58-150 Benzene ug/L 50 47.6 95 68-132 Bromobenzene ug/L 50 48.8 98 75-122 Bromochloromethane ug/L 50 45.3 91 73-133 Bromodichloromethane ug/L 50 52.7 105 67-121 Bromoform ug/L 50 39.7 79 57-125 Bromomethane ug/L 50 62.2 124 35-156 Carbon disulfide ug/L 100 113 113 47-141 Carbon tetrachloride ug/L 50 50.4 101 66-122 Chlorobenzene ug/L 50 47.5 95 71-126 Chloroethane ug/L 50 46.0 92 43-143 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 51 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC 1403 Pace Project No.: 2614222 LABORATORY CONTROL SAMPLE: 99746 Parameter Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Dichlorodifluoromethane Diisopropyl ether Ethyl methacrylate Ethylbenzene Hexachloro-1,3-butadiene lodomethane m&p-Xylene Methacrylonitrile Methyl methacrylate Methyl-tert-butyl ether Methylene Chloride Naphthalene o-Xylene p-Isopropyltoluene Propionitrile Styrene Tetrachloroethene Toluene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Dibromofluoromethane (S) Toluene-d8 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99747 Parameter 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane QUALITY CONTROL DATA Spike Conc. 50 50 50 50 50 50 50 50 100 50 50 100 100 100 100 100 50 50 50 50 100 50 50 50 50 50 100 50 50 50 50 150 LCS Result 47.6 47.0 46.7 44.0 42.2 46.2 54.0 50.8 86.4 49.2 56.2 88.5 106 77.7 84.4 76.6 48.6 39.1 52.9 49.8 81.0 47.9 48.7 49.7 42.7 41.6 85.8J 43.0 54.0 45.3J 46.6 159 99748 LCS % Rec % Rec Limits 95 71-136 94 47-123 93 74-131 88 78-120 84 65-115 92 79-129 108 29-124 102 70-130 86 75-130 98 68-129 112 58-142 89 49-154 106 67-137 78 74-139 84 75-133 77 59-130 97 61-147 78 48-144 106 52-141 100 58-137 81 69-139 96 77-128 97 51-139 99 60-133 85 69-144 83 74-128 86 61-139 86 73-126 108 55-132 91 52-141 93 50-133 106 78-132 95 81-119 93 82-120 99 82-114 98 82-109 Qualifiers MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual ug/L ND 50 50 40.6 38.3 81 77 68-137 6 11 ug/L ND 50 50 52.5 50.8 105 102 66-142 3 11 ug/L ND 50 50 42.6 40.7 85 81 39-171 5 13 ug/L ND 50 50 45.7 41.4 91 83 73-136 10 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 52 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99747 99748 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1-Dichloroethane ug/L ND 50 50 44.7 43.5 89 87 66-155 3 15 1,1-Dichloroethene ug/L ND 50 50 50.4 45.8 101 92 33-181 10 34 1,1-Dichloropropene ug/L ND 50 50 49.2 45.2 98 90 70-133 9 12 1,2,3-Trichlorobenzene ug/L ND 50 50 34.9 39.0 70 78 73-130 11 22 M1 1,2,3-Trichloropropane ug/L ND 50 50 44.4 42.4 89 85 78-133 4 14 1,2,4-Trichlorobenzene ug/L ND 50 50 36.5 37.8 73 76 44-164 4 13 1,2-Dibromo-3- ug/L ND 50 50 37.6 36.2 75 72 58-124 4 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 43.6 39.6 87 79 71-134 10 12 1,2-Dichlorobenzene ug/L ND 50 50 42.7 40.9 85 82 69-135 4 10 1,2-Dichloroethane ug/L ND 50 50 43.6 40.0 87 80 36-159 9 10 1,2-Dichloropropane ug/L ND 50 50 45.0 41.6 90 83 68-132 8 11 1,3-Dichlorobenzene ug/L ND 50 50 43.6 42.3 87 85 68-135 3 10 1,3-Dichloropropane ug/L ND 50 50 50.2 46.3 100 93 70-138 8 10 1,4-Dichlorobenzene ug/L ND 50 50 41.2 38.9 82 78 49-153 6 9 2,2-Dichloropropane ug/L ND 50 50 35.8 34.7 72 69 34-170 3 9 2-Butanone (MEK) ug/L ND 100 100 65.9J 60.5J 66 61 10-189 9 23 2-Chlorotoluene ug/L ND 50 50 45.6 44.9 91 90 77-128 1 10 2-Hexanone ug/L ND 100 100 69.4 63.0 69 63 40-135 10 18 4-Chlorotoluene ug/L ND 50 50 49.3 45.9 99 92 79-126 7 10 4-Methyl-2-pentanone ug/L ND 100 100 72.1J 63.7J 72 64 30-177 12 10 R1 (MIBK) Acetone ug/L ND 100 100 55.8J 49.7J 56 50 44-223 12 14 Acrolein ug/L ND 100 100 81.1 74.1 81 74 57-185 9 30 Acrylonitrile ug/L ND 200 200 162J 148J 81 74 13-189 9 12 Allyl chloride ug/L ND 100 100 92.9 86.7 93 87 58-150 7 18 Benzene ug/L ND 50 50 44.6 41.0 89 82 66-139 8 10 Bromobenzene ug/L ND 50 50 45.0 42.6 90 85 75-122 6 12 Bromochloromethane ug/L ND 50 50 42.5 40.0 85 80 73-133 6 13 Bromodichloromethane ug/L ND 50 50 49.7 44.6 99 89 57-120 11 13 Bromoform ug/L ND 50 50 37.0 35.0 74 70 48-128 6 13 Bromomethane ug/L ND 50 50 46.0 49.3 92 99 10-187 7 32 Carbon disulfide ug/L ND 100 100 114 103 114 103 47-141 10 322 Carbon tetrachloride ug/L ND 50 50 51.8 47.3 104 95 58-127 9 14 Chlorobenzene ug/L ND 50 50 44.1 42.2 88 84 63-137 4 10 Chloroethane ug/L ND 50 50 43.7 39.6 87 79 52-146 10 16 Chloroform ug/L ND 50 50 44.6 40.3 89 81 74-137 10 9 R1 Chloromethane ug/L ND 50 50 43.1 40.2 86 80 41-127 7 10 cis-1,2-Dichloroethene ug/L ND 50 50 43.9 41.9 87 83 71-138 5 16 cis-1,3-Dichloropropene ug/L ND 50 50 40.5 37.9 81 76 32-145 7 12 Dibromochloromethane ug/L ND 50 50 40.8 37.5 82 75 52-116 8 13 Dibromomethane ug/L ND 50 50 45.5 43.4 91 87 79-129 5 14 Dichlorodifluoromethane ug/L ND 50 50 61.8 61.8 124 124 36-126 0 15 Diisopropyl ether ug/L ND 50 50 46.1 43.1 92 86 70-130 7 20 Ethyl methacrylate ug/L ND 100 100 82.1 73.5 82 74 75-130 11 14 M1 Ethylbenzene ug/L ND 50 50 47.3 43.6 95 87 31-174 8 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 53 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99747 99748 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Hexachloro-1,3-butadiene ug/L ND 50 50 47.6 49.2 95 98 58-142 3 11 lodomethane ug/L ND 100 100 77.3 72.1 77 72 49-154 7 30 m&p-Xylene ug/L ND 100 100 98.9 92.6 99 93 27-179 7 10 Methacrylonitrile ug/L ND 100 100 74.5 68.5 75 68 74-139 8 14 M1 Methyl methacrylate ug/L ND 100 100 83.5 74.2 83 74 75-133 12 13 M1 Methyl-tert-butyl ether ug/L ND 100 100 44.7 43.5 45 44 38-120 3 12 Methylene Chloride ug/L ND 50 50 42.2 36.6 84 73 61-146 14 15 Naphthalene ug/L ND 50 50 31.6 36.1 63 72 25-159 13 14 o-Xylene ug/L ND 50 50 51.1 47.3 102 95 52-141 8 65 p-Isopropyltoluene ug/L ND 50 50 44.9 42.8 90 86 59-134 5 9 Propionitrile ug/L ND 100 100 56.9 63.3 57 63 69-139 11 16 M1 Styrene ug/L ND 50 50 44.1 40.8 88 82 77-128 8 14 Tetrachloroethene ug/L ND 50 50 47.0 42.3 94 85 36-155 10 14 Toluene ug/L ND 50 50 48.0 43.2 96 86 52-146 11 11 trans-1,2-Dichloroethene ug/L ND 50 50 28.4 26.6 57 53 61-152 7 14 M1 trans-1,3-Dichloropropene ug/L ND 50 50 37.2 35.1 74 70 37-146 6 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 66.5J 63.7J 67 64 61-139 4 12 Trichloroethene ug/L ND 50 50 43.3 40.5 87 81 61-141 7 12 Trichlorofluoromethane ug/L ND 50 50 60.4 54.8 121 110 51-141 10 13 Vinyl acetate ug/L ND 50 50 57.5 52.5 115 105 52-141 9 14 Vinyl chloride ug/L ND 50 50 49.0 44.0 98 88 22-156 11 26 Xylene (Total) ug/L ND 150 150 150 140 100 93 78-132 7 7 1,2-Dichloroethane-d4 (S) %. 99 97 81-119 4-Bromofluorobenzene (S) %. 97 98 82-120 Dibromofluoromethane (S) %. 101 102 82-114 Toluene-d8 (S) %. 99 99 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 54 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 QC Batch: 22202 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2614222017, 2614222018 METHOD BLANK: 99962 Associated Lab Samples: 2614222017, 2614222018 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 02/11/19 17:35 1,1,1-Trichloroethane ug/L ND 1.0 0.38 02/11/19 17:35 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 02/11/19 17:35 1,1,2-Trichloroethane ug/L ND 1.0 0.59 02/11/19 17:35 1,1-Dichloroethane ug/L ND 5.0 0.41 02/11/19 17:35 1,1-Dichloroethene ug/L ND 5.0 0.72 02/11/19 17:35 1,2,3-Trichloropropane ug/L ND 1.0 0.46 02/11/19 17:35 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 02/11/19 17:35 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 02/11/19 17:35 1,2-Dichlorobenzene ug/L ND 5.0 0.49 02/11/19 17:35 1,2-Dichloroethane ug/L ND 1.0 0.67 02/11/19 17:35 1,2-Dichloropropane ug/L ND 1.0 0.60 02/11/19 17:35 1,4-Dichlorobenzene ug/L ND 1.0 0.58 02/11/19 17:35 2-Butanone (MEK) ug/L ND 100 3.2 02/11/19 17:35 2-Hexanone ug/L ND 50.0 0.89 02/11/19 17:35 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 02/11/19 17:35 Acetone ug/L ND 100 8.2 02/11/19 17:35 Acrylonitrile ug/L ND 200 2.5 02/11/19 17:35 Benzene ug/L ND 1.0 0.20 02/11/19 17:35 Bromochloromethane ug/L ND 3.0 0.50 02/11/19 17:35 Bromodichloromethane ug/L ND 1.0 0.36 02/11/19 17:35 Bromoform ug/L ND 3.0 0.55 02/11/19 17:35 Bromomethane ug/L ND 10.0 0.95 02/11/19 17:35 Carbon disulfide ug/L ND 100 0.79 02/11/19 17:35 Carbon tetrachloride ug/L ND 1.0 0.42 02/11/19 17:35 Chlorobenzene ug/L ND 3.0 0.53 02/11/19 17:35 Chloroethane ug/L ND 10.0 0.52 02/11/19 17:35 Chloroform ug/L ND 5.0 0.58 02/11/19 17:35 Chloromethane ug/L ND 1.0 0.38 02/11/19 17:35 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 02/11/19 17:35 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 02/11/19 17:35 Dibromochloromethane ug/L ND 3.0 0.31 02/11/19 17:35 Dibromomethane ug/L ND 10.0 0.62 02/11/19 17:35 Ethylbenzene ug/L ND 1.0 0.45 02/11/19 17:35 lodomethane ug/L ND 10.0 3.1 02/11/19 17:35 Methylene Chloride ug/L ND 1.0 0.50 02/11/19 17:35 Styrene ug/L ND 1.0 0.50 02/11/19 17:35 Tetrachloroethene ug/L ND 1.0 0.78 02/11/19 17:35 Toluene ug/L ND 1.0 0.31 02/11/19 17:35 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 02/11/19 17:35 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 02/11/19 17:35 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 55 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 METHOD BLANK: 99962 Associated Lab Samples: Parameter 2614222017, 2614222018 Units Matrix: Blank Result Water Reporting Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) %. 96 81-119 4-Bromofluorobenzene (S) %. 107 82-120 Dibromofluoromethane (S) %. 95 82-114 Toluene-d8 (S) %. 99 82-109 Analyzed 1.6 02/11/1917:35 0.34 02/11/1917:35 0.51 02/11 /19 17:35 0.42 02/11/1917:35 0.60 02/11/1917:35 1.5 02/11/1917:35 02/11 /19 17:35 02/11 /19 17:35 02/11 /19 17:35 02/11 /19 17:35 LABORATORY CONTROL SAMPLE: Parameter 99963 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 47.7 95 68-137 1,1,1-Trichloroethane ug/L 50 54.2 108 72-134 1,1,2,2-Tetrachloroethane ug/L 50 51.3 103 51-158 1,1,2-Trichloroethane ug/L 50 53.0 106 78-131 1,1-Dichloroethane ug/L 50 50.0 100 69-151 1,1-Dichloroethene ug/L 50 48.8 98 64-158 1,2,3-Trichloropropane ug/L 50 59.9 120 78-133 1,2-Dibromo-3-chloropropane ug/L 50 53.5 107 58-124 1,2-Dibromoethane (EDB) ug/L 50 50.8 102 71-134 1,2-Dichlorobenzene ug/L 50 53.7 107 70-135 1,2-Dichloroethane ug/L 50 48.4 97 72-129 1,2-Dichloropropane ug/L 50 51.5 103 64-135 1,4-Dichlorobenzene ug/L 50 50.5 101 70-131 2-Butanone (MEK) ug/L 100 84AJ 84 52-143 2-Hexanone ug/L 100 89.1 89 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 94.5J 95 71-129 Acetone ug/L 100 64.6J 65 48-224 Acrylonitrile ug/L 200 212 106 66-154 Benzene ug/L 50 48.6 97 68-132 Bromochloromethane ug/L 50 50.2 100 73-133 Bromodichloromethane ug/L 50 55.0 110 67-121 Bromoform ug/L 50 46.3 93 57-125 Bromomethane ug/L 50 65.2 130 35-156 Carbon disulfide ug/L 100 112 112 47-141 Carbon tetrachloride ug/L 50 49.2 98 66-122 Chlorobenzene ug/L 50 50.0 100 71-126 Chloroethane ug/L 50 45.0 90 43-143 Chloroform ug/L 50 47.5 95 71-136 Chloromethane ug/L 50 46.9 94 47-123 cis-1,2-Dichloroethene ug/L 50 51.5 103 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 56 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 LABORATORY CONTROL SAMPLE: 99963 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 48.3 97 78-120 Dibromochloromethane ug/L 50 47.1 94 65-115 Dibromomethane ug/L 50 54.3 109 79-129 Ethylbenzene ug/L 50 51.8 104 68-129 lodomethane ug/L 100 99.8 100 49-154 Methylene Chloride ug/L 50 50.3 101 61-147 Styrene ug/L 50 50.4 101 77-128 Tetrachloroethene ug/L 50 51.0 102 51-139 Toluene ug/L 50 52.3 105 60-133 trans-1,2-Dichloroethene ug/L 50 34.6 69 69-144 trans- 1,3-Dichloropropene ug/L 50 47.0 94 74-128 trans-1,4-Dichloro-2-butene ug/L 100 94.8J 95 61-139 Trichloroethene ug/L 50 46.2 92 73-126 Trichlorofluoromethane ug/L 50 52.1 104 55-132 Vinyl acetate ug/L 50 50.9 102 52-141 Vinyl chloride ug/L 50 46.0 92 50-133 Xylene (Total) ug/L 150 168 112 78-132 1,2-Dichloroethane-d4 (S) %. 98 81-119 4-Bromofluorobenzene (S) %. 95 82-120 Dibromofluoromethane (S) %. 98 82-114 Toluene-d8 (S) %. 97 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99964 99965 MS MSD 2614374004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 44.5 44.3 89 89 68-137 0 11 1,1,1-Trichloroethane ug/L ND 50 50 58.2 58.7 116 117 66-142 1 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 47.6 47.6 95 95 39-171 0 13 1,1,2-Trichloroethane ug/L ND 50 50 50.9 48.2 102 96 73-136 6 12 1,1-Dichloroethane ug/L ND 50 50 48.5 50.3 97 101 66-155 4 15 1,1-Dichloroethene ug/L ND 50 50 55.8 54.3 112 109 33-181 3 34 1,2,3-Trichloropropane ug/L ND 50 50 53.0 52.5 106 105 78-133 1 14 1,2-Dibromo-3- ug/L ND 50 50 45.1 46.4 90 93 58-124 3 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 46.5 46.7 93 93 71-134 0 12 1,2-Dichlorobenzene ug/L ND 50 50 47.9 48.5 96 97 69-135 1 10 M1 1,2-Dichloroethane ug/L ND 50 50 46.3 45.1 93 90 36-159 3 10 1,2-Dichloropropane ug/L ND 50 50 47.9 48.0 96 96 68-132 0 11 1,4-Dichlorobenzene ug/L ND 50 50 44.7 44.7 89 89 49-153 0 9 M1 2-Butanone (MEK) ug/L ND 100 100 71.8J 71.1J 72 71 10-189 1 23 2-Hexanone ug/L ND 100 100 80.2 77.5 80 77 40-135 3 18 4-Methyl-2-pentanone ug/L ND 100 100 80.2J 79.6J 80 80 30-177 1 10 (MIBK) Acetone ug/L ND 100 100 64AJ 62.1J 64 62 44-223 4 14 Acrylonitrile ug/L ND 200 200 1891 185J 95 92 13-189 2 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 57 of 64 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC 1403 Pace Project No.: 2614222 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99964 99965 MS MSD 2614374004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Benzene ug/L ND 50 50 47.5 47.3 95 95 66-139 0 10 Bromochloromethane ug/L ND 50 50 47.6 47.7 95 95 73-133 0 13 Bromodichloromethane ug/L ND 50 50 53.7 51.6 107 103 57-120 4 13 Bromoform ug/L ND 50 50 41.6 41.5 83 83 48-128 0 13 Bromomethane ug/L ND 50 50 52.1 59.4 104 119 10-187 13 32 Carbon disulfide ug/L ND 100 100 122 118 122 118 47-141 3 322 Carbon tetrachloride ug/L ND 50 50 54.8 54.3 110 109 58-127 1 14 Chlorobenzene ug/L ND 50 50 46.5 46.7 93 93 63-137 1 10 Chloroethane ug/L ND 50 50 47.1 47.2 94 94 52-146 0 16 Chloroform ug/L ND 50 50 47.0 46.5 94 93 74-137 1 9 Chloromethane ug/L ND 50 50 48.6 47.0 97 94 41-127 3 10 cis-1,2-Dichloroethene ug/L ND 50 50 46.5 47.5 93 95 71-138 2 16 cis-1,3-Dichloropropene ug/L ND 50 50 42.9 42.9 86 86 32-145 0 12 Dibromochloromethane ug/L ND 50 50 44.4 43.2 89 86 52-116 3 13 Dibromomethane ug/L ND 50 50 48.9 49.3 98 99 79-129 1 14 Ethylbenzene ug/L ND 50 50 51.2 49.0 102 98 31-174 4 10 lodomethane ug/L ND 100 100 101 102 101 102 49-154 1 30 Methylene Chloride ug/L ND 50 50 50.2 50.2 100 100 61-146 0 15 Styrene ug/L ND 50 50 47.6 47.0 95 94 77-128 1 14 Tetrachloroethene ug/L ND 50 50 51.8 48.5 104 97 36-155 7 14 Toluene ug/L ND 50 50 51.8 49.7 104 99 52-146 4 11 trans-1,2-Dichloroethene ug/L ND 50 50 31.2 30.8 62 62 61-152 1 14 trans-1,3-Dichloropropene ug/L ND 50 50 42.2 41.5 84 83 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 73.1J 77.5J 73 78 61-139 6 12 Trichloroethene ug/L ND 50 50 45.4 44.4 91 89 61-141 2 12 Trichlorofluoromethane ug/L ND 50 50 67.5 66.1 135 132 51-141 2 13 Vinyl acetate ug/L ND 50 50 62.8 62.8 126 126 52-141 0 14 Vinyl chloride ug/L ND 50 50 52.3 50.6 105 101 22-156 3 26 Xylene (Total) ug/L ND 150 150 163 159 108 106 78-132 2 7 1,2-Dichloroethane-d4 (S) %. 101 95 81-119 4-Bromofluorobenzene (S) %. 93 94 82-120 Dibromofluoromethane (S) %. 97 101 82-114 Toluene-d8 (S) %. 99 96 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 58 of 64 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Foothills LF NC 1403 Pace Project No.: 2614222 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 59 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF NC 1403 2614222 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2614222001 1403-MW-1 R2 EPA 3005A 21711 EPA 6020B 21754 2614222002 1403-MW-3R2 EPA 3005A 21711 EPA 6020B 21754 2614222003 1403-MW-4 EPA 3005A 21711 EPA 6020B 21754 2614222003 1403-MW-4 EPA 3005A 24111 EPA 6020B 24144 2614222004 1403-DUP@MW-4 EPA 3005A 21711 EPA 6020B 21754 2614222005 1403-MW-5 EPA 3005A 21711 EPA 6020B 21754 2614222005 1403-MW-5 EPA 3005A 24111 EPA 6020B 24144 2614222006 1403-MW-6 EPA 3005A 21711 EPA 6020B 21754 2614222006 1403-MW-6 EPA 3005A 24111 EPA 6020B 24144 2614222007 1403-MW-7 EPA 3005A 21711 EPA 6020B 21754 2614222008 1403-MW-8 EPA 3005A 21711 EPA 6020B 21754 2614222008 1403-MW-8 EPA 3005A 24111 EPA 6020B 24144 2614222009 1403-MW-9 EPA 3005A 21711 EPA 6020B 21754 2614222010 1403-MW-10 EPA 3005A 21711 EPA 6020B 21754 2614222011 1403-MW-11 EPA 3005A 21821 EPA 6020B 21903 2614222012 1403-Field Blank EPA 3005A 21821 EPA 6020B 21903 2614222013 1403-SW1 EPA 3005A 21821 EPA 6020B 21903 2614222014 1403-SW2 EPA 3005A 21821 EPA 6020B 21903 2614222015 1403-SW3 EPA 3005A 21821 EPA 6020B 21903 2614222016 1403-SW4 EPA 3005A 21821 EPA 6020B 21903 2614222017 1403-UD1 EPA 3005A 21821 EPA 6020B 21903 2614222018 1403-UD2 EPA 3005A 21821 EPA 6020B 21903 2614222001 1403-MW-1 R2 EPA 8260B Mod. 455695 2614222002 1403-MW-3R2 EPA 8260B Mod. 455695 2614222003 1403-MW-4 EPA 8260B Mod. 455695 2614222004 1403-DUP@MW-4 EPA 8260B Mod. 455695 2614222005 1403-MW-5 EPA 8260B Mod. 455695 2614222006 1403-MW-6 EPA 8260B Mod. 455695 2614222007 1403-MW-7 EPA 8260B Mod. 455695 2614222008 1403-MW-8 EPA 8260B Mod. 455695 2614222009 1403-MW-9 EPA 8260B Mod. 455695 2614222010 1403-MW-10 EPA 8260B Mod. 455695 2614222011 1403-MW-11 EPA 8260B Mod. 455695 2614222012 1403-Field Blank EPA 8260B Mod. 455695 2614222013 1403-SW1 EPA 8260B Mod. 455695 2614222014 1403-SW2 EPA 8260B Mod. 455695 2614222015 1403-SW3 EPA 8260B Mod. 455695 2614222016 1403-SW4 EPA 8260B Mod. 455695 2614222001 1403-MW-1 R2 EPA 8260B 22128 2614222002 1403-MW-3R2 EPA 8260B 22128 2614222003 1403-MW-4 EPA 8260B 22128 2614222004 1403-DUP@MW-4 EPA 8260B 22128 2614222005 1403-MW-5 EPA 8260B 22128 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/20/2019 10:31 AM without the written consent of Pace Analytical Services, LLC. Page 60 of 64 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF NC 1403 Pace Project No.: 2614222 Lab ID Sample ID QC Batch Method QC Batch 2614222006 1403-MW-6 EPA 8260B 22128 2614222007 1403-MW-7 EPA 8260B 22128 2614222008 1403-MW-8 EPA 8260B 22128 2614222009 1403-MW-9 EPA 8260B 22128 2614222010 1403-MW-10 EPA 8260B 22128 2614222011 1403-MW-11 EPA 8260B 22128 2614222012 1403-Field Blank EPA 8260B 22128 2614222013 1403-SW1 EPA 8260B 22128 2614222014 1403-SW2 EPA 8260B 22128 2614222015 1403-SW3 EPA 8260B 22128 2614222016 1403-SW4 EPA 8260B 22128 2614222017 1403-UD1 EPA 8260B 22202 2614222018 1403-UD2 EPA 8260B 22202 Date: 03/20/2019 10:31 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 61 of 64 U �p c U M n 0 U U ti �n o w �•- r 2 O o -v" 6 W uco °m�❑o a ,L o Q Ul 0 Q 2 2= Z z z Q W 2 wm r�r� vu�ep n o N�❑¢1d to Q R U z x F a w ¢ui p h LL1 ¢ �� S �Q a ~ J ¢ � c�aW z u Q N m� � 1a Y uj Z O Z N r Q z �� at--� ���g 2 cV ¢ a ¢U N0 0U)U) W rn r a 4o z a ¢c7 >No �- r� Q m U 2 � d 0 U - w F a = w U .. ¢r w� LU ¢m w L)� G d QLo 11 ['') "CL x mrLL Q>ri -i z �•- 2 UM ¢ w r- i0 O d CL v U z LL 0 U co �C w U LU U) U J m D W D 0 z Hwy LL w 0 o w O D a U � LL w o z z a z z U0 CD o2 (Dcn �- �r` .� ft ram, � r - ❑ ZDEMWX --► T N co -t Lf] CD I` t70 ❑] r r T SW13W - I XI❑N3ddd X XI X X XI XI X XI XI X XI X WIS 09ZS AS 3NVXOIO-t,' I. X X X X X X I X X ]C X X ]C m m ►Zs AS OOA - I XI❑N3ddV X X X X X X I X U 0 Z r Q- 2 W W N j n = m ff M [V N kA o � cfl r� oo r i z EL LU 2i J ❑ c 0 m �] cr3 tr a o vim- 1-� o 0 [v U A r r W a _ ❑ t7x4Um X X 7E X X X X x I xil X X ]C U ❑ 2 a z �q J 2U J `Z t- J LU z 0 o LA to o =' 'X o o -� nn 3' r N ° '� `� ri rn {/] d�F �LLI ❑ g J Q' G` 6` [r Ct' Q" a` [�' z p U 111 muj U fk F- 1 1 1 r}O e}p i r dD ► � Ck7 1 1 1 G� m ,0 O m ❑ F- 0:LU N a L" w U LU ❑ N r1 N N N nl r! N N N U w i r 1 t i 1 1 t t l z 0 U P [z rc a n III — �¢ m ui [V m a c�7 i7 ui Z U IY 0 U m W W a F- 2 U .. d W p IL N v Q m U� n w Q n QCL . fn LL o o Q W n H vp Q 0 LU 0 U) 7 U LL Z a U U � tp c V1 U d U U ca In yo Z (O ¢ VI F z ❑ o Vi � N 0 ¢ i x T a W L) J In a �� ¢ r! N �C] u} z 4 Q m O-jO�Ucr O '� w X Z T z z z VI W N co L!J G =,J (}` N i — I* n U X a z 0¢ a w � < <¢� o cF. N IL g U C7 {� Q w¢ Q�¢ z ❑U� ¢ uj c� 7 1 w W V> � [Y 7 Frw Y� DISC � Z in z MF J d W� U ¢a::) -Q a ¢ U > NO N I i i ❑ 3:(DUSV) w 3 CL CL -¢ m - 0 x D E m wa: T� Lo 0 r co m r W v � w W W Z ry a n uj w D a U ❑ VH+SWiAiN - I XICINDdd'd x X X X f a ` tri N S�'d13W -I XION3ddV X X X WIS ORB AO DNWOKI-V b X X X X X n r > 09Z8 AS OOA - I XION3dcIV X x X X X x X w � tkcw, _ V7 v R z a ° U Qx�Q-zww0 f` f` �¢0 rl S w fY �j CC W ❑ m U Y U CD Q z 0 I 9 Q z W ❑ VJ VJ t./J Vl �C W w z � � I I ! I I ! 7 J U N 0 tN t U v p 2 < < r o o �a¢mxxxxxxX m 0 CL w co 2 U O 2 a. W z z LL - z o ����� 3 U �, I 8q V l 0 m n ti r = D 0 `� -. lry (r 1 0uj — � z a ° z w 0 [r rc 1 l!i ry o 06 o LLJQ LL Q a N F W �; rn w (] g J st- �_' CT Ir Q- 'r a- I z 0 m a z ¢ o z=LU 1 I 1 m.0 m m ❑ do da ao U o r i 0 w � CV N N N N w LI w a a a Q fY Q I 1 L ; r a U 6 .� Ill w a fY . - ... .. 'Z � Client Name: Courier: . Fed Ex ❑ UPS ❑ uSPS ❑ Client [Commercial ❑ Pace Other Tracking #: Custody Seal on Cool riaox Present yes no Seals intact: ❑ yes Packing Material: ❑ Bubble W rap3ubble bags ❑ Nane ❑ Other Thermometer Used —� Type of Ice: V Slue None Cooler Temperature [ 1 nV Biological Tissue is Frozen: Yps No TemP should be above freezing to 6°C Comments: Chain of Guslod Present: EleNo ❑NIA 1Chain of Custod Filled Out: No ❑NIA 2.Chain of Custod Relin uished: No ❑NIA 3. Sampler Name & Si nature on COC: ❑s N❑ ❑NIA 4, Samples Arrived within Hold Time: as ONIA 5, ,❑NO Mes NIA 6• Short Hold Time Analysis a72hr : sue° Rush Turn Around Time Requested: ❑yes No El NIA 7. Sufficient Volume: res ❑No ❑NIA S. Correct Containers Used: res ❑No ❑NIA g. Pace Containers used: Yes ONo ❑NIA Containers Intact: es ❑No ❑NIA 10. Filtered volume received for Dissolved tests es a ❑N.+A 1 1. Sample Labels match COC: , b❑� r fI ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. es ONO ❑NIA 13. All containers needing preservation are found to be in y�❑Nc ❑NIA compliance with EPA recommendation. Initial when exceptions: O�colitorm, TCC, DBG. WI•f]Ro (water) es []Na completed Samples checked for dechlorinatlon: []Yes ❑Na EfIA 14. Heads ace in VOA Vials >6mm : ❑res No ❑NIA 15, Trip Blank Present: Oyes a ❑NIA 16. Trip Blank Custody Seals Present ❑Yes ❑No IA Pace Trip Blank Lot # itpurchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: 2 R422z PM: BM Due Date: 02/12/19 CLIENT J Republic -NC ro • DuNarne.eCWe: ❑ no ❑ samples o ice, cooling process has begun Date and Inili qf r ❑ exa4m�s g cons nts:._7 . r��� � 7; ff of added Field Bata Required? Y 1 N Date: Note: Whenever theta is a discrepancy affecting North Carolina compliance samples, a copy of this torm will bo Certification Ott ice ( i.e out of hold, incorrect preservative, out of Iemp, incorrect containers) to the North Carolina fDEHNR Paa� �g4 of 64 F-ALLCO03rev.3, 11Septembe❑ fi lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 February 13, 2019 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF NC-1403 Pace Project No.: 2614221 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 29, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC-1403 Pace Project No.: 2614221 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Foothills LF NC-1403 Pace Project No.: 2614221 Lab ID Sample ID Matrix Date Collected Date Received 2614221001 2614221002 1403-MW-2R 1403-Trip Blank Water Water 01/28/1914:56 01/28/19 06:03 01/29/1910:00 01/29/19 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Foothills LF NC-1403 2614221 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 2614221001 1403-MW-2R EPA 8011 MZP 3 PASI-GA EPA 8081B SFI 22 PASI-GA EPA 8082A SFI 8 PASI-GA EPA8151A MZP 5 PASI-GA EPA 6020E KLH 16 PASI-GA EPA 7470A DRB 1 PASI-GA EPA 8270D MKI 112 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA8260B LIH 62 PASI-GA EPA 9014 Cyanide KN 1 PASI-GA EPA 9034 JAD 1 PASI-GA 2614221002 1403-Trip Blank EPA 8011 MZP 3 PASI-GA EPA8260B LIH 63 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8011 GCS EDB and DBCP 1,2-Dibromo-3- chloropropane 1,2-Dibromoethane (EDB) Surrogates Bromoform (S) 8081 GCS Pesticide Waters Aldrin alpha-BHC beta-BHC delta-BHC gamma-BHC (Lindane) Chlordane (Technical) 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan 11 Endosulfan sulfate Endrin Endrin aldehyde Heptachlor Heptachlor epoxide Isodrin Methoxychlor Toxaphene Surrogates Tetrachloro-m-xylene (S) Decachlorobiphenyl (S) 8082 PCB Water GCS PCB-1016 (Aroclor 1016) PCB-1221 (Aroclor 1221) PCB-1232 (Aroclor 1232) PCB-1242 (Aroclor 1242) PCB-1248 (Aroclor 1248) PCB-1254 (Aroclor 1254) PCB-1260 (Aroclor 1260) Surrogates Decachlorobiphenyl (S) 8151A Cl Acid Herbicide Waters 2,4-D Dinoseb 2,4,5-T Date: 02/13/2019 02:20 PM Analytical Method: EPA 8011 Preparation Method: EPA 8011 ND ug/L 0.20 0.061 1 02/04/19 11:05 02/04/19 21:01 96-12-8 ND ug/L 0.051 0.015 1 02/04/19 11:05 02/04/19 21:01 106-93-4 99 %. 31-168 1 02/04/19 11:05 02/04/19 21:01 75-25-2 Analytical Method: EPA 8081 B Preparation Method: EPA 3510C ND ug/L 0.10 0.044 1 02/01/19 11:00 02/06/1918:24 309-00-2 ND ug/L 0.10 0.039 1 02/01/19 11:00 02/06/1918:24 319-84-6 ND ug/L 0.10 0.046 1 02/01/19 11:00 02/06/1918:24 319-85-7 ND ug/L 0.10 0.032 1 02/01/19 11:00 02/06/1918:24 319-86-8 ND ug/L 0.10 0.037 1 02/01/19 11:00 02/06/1918:24 58-89-9 ND ug/L 0.50 0.29 1 02/01/19 11:00 02/06/1918:24 57-74-9 ND ug/L 0.10 0.034 1 02/01/19 11:00 02/06/1918:24 72-54-8 ND ug/L 0.10 0.030 1 02/01/19 11:00 02/06/1918:24 72-55-9 ND ug/L 0.10 0.034 1 02/01/19 11:00 02/06/1918:24 50-29-3 ND ug/L 0.10 0.036 1 02/01/19 11:00 02/06/1918:24 60-57-1 ND ug/L 0.50 0.068 1 02/01/19 11:00 02/06/1918:24 959-98-8 ND ug/L 0.50 0.037 1 02/01/19 11:00 02/06/1918:24 33213-65-9 ND ug/L 0.50 0.032 1 02/01/19 11:00 02/06/1918:24 1031-07-8 ND ug/L 0.20 0.040 1 02/01/19 11:00 02/06/1918:24 72-20-8 ND ug/L 0.20 0.081 1 02/01/19 11:00 02/06/1918:24 7421-93-4 ND ug/L 0.10 0.034 1 02/01/19 11:00 02/06/1918:24 76-44-8 ND ug/L 0.10 0.042 1 02/01/19 11:00 02/06/1918:24 1024-57-3 ND ug/L 0.50 0.034 1 02/01/19 11:00 02/06/1918:24 465-73-6 ND ug/L 0.30 0.048 1 02/01/19 11:00 02/06/1918:24 72-43-5 ND ug/L 2.0 0.22 1 02/01/19 11:00 02/06/1918:24 8001-35-2 116 %. 19-148 1 02/01/19 11:00 02/06/19 18:24 877-09-8 112 %. 10-157 1 02/01/19 11:00 02/06/1918:24 2051-24-3 Analytical Method: EPA 8082A Preparation Method: EPA 3510C ND ug/L 0.50 0.19 1 02/01/19 11:00 02/02/19 03:43 12674-11-2 ND ug/L 0.50 0.50 1 02/01/19 11:00 02/02/19 03:43 11104-28-2 ND ug/L 0.50 0.50 1 02/01/19 11:00 02/02/19 03:43 11141-16-5 ND ug/L 0.50 0.50 1 02/01/19 11:00 02/02/19 03:43 53469-21-9 ND ug/L 0.50 0.50 1 02/01/19 11:00 02/02/19 03:43 12672-29-6 ND ug/L 0.50 0.50 1 02/01/19 11:00 02/02/19 03:43 11097-69-1 ND ug/L 0.50 0.23 1 02/01/19 11:00 02/02/19 03:43 11096-82-5 75 %. 17-144 1 02/01/19 11:00 02/02/19 03:43 2051-24-3 Analytical Method: EPA 8151A Preparation Method: EPA8151A ND ug/L 5.0 1.6 1 02/01/19 10:40 02/04/19 22:16 94-75-7 ND ug/L 5.0 1.2 1 02/01/19 10:40 02/04/19 22:16 88-85-7 ND ug/L 5.0 1.1 1 02/01/19 10:40 02/04/19 22:16 93-76-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8151A Cl Acid Herbicide Waters Analytical Method: EPA 8151A Preparation Method: EPA 8151A 2,4,5-TP (Silvex) ND ug/L 10.0 1.0 1 02/01/19 10:40 02/04/19 22:16 93-72-1 Surrogates 2,4-DCAA (S) 99 %. 10-155 1 02/01 /19 10:40 02/04/19 22:16 19719-28-9 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:14 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:14 7440-38-2 Barium 252 ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:14 7440-39-3 Beryllium 0.13J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:14 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:14 7440-43-9 Chromium ND ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:14 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:14 7440-48-4 Copper ND ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:14 7440-50-8 Lead ND ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:14 7439-92-1 Nickel ND ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:14 7440-02-0 Selenium ND ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:14 7782-49-2 Silver ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:14 7440-22-4 Thallium ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:14 7440-28-0 Tin ND ug/L 20.0 7.0 1 02/04/19 13:33 02/04/19 21:14 7440-31-5 Vanadium ND ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:14 7440-62-2 Zinc ND ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:14 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.036 1 01/30/1910:04 01/30/1915:01 7439-97-6 8270D MSSV Water, Extend Analytical Method: EPA 8270D Preparation Method: EPA 3510C Acenaphthene ND ug/L 10.0 1.9 1 02/04/19 11:00 02/11/19 21:51 83-32-9 Acenaphthylene ND ug/L 10.0 1.9 1 02/04/19 11:00 02/11/19 21:51 208-96-8 Acetophenone ND ug/L 10.0 3.3 1 02/04/19 11:00 02/11/19 21:51 98-86-2 2-Acetylaminofluorene ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 53-96-3 4-Aminobiphenyl ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 92-67-1 Anthracene ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 120-12-7 Benzo(a)anthracene ND ug/L 10.0 4.2 1 02/04/19 11:00 02/11/19 21:51 56-55-3 Benzo(a)pyrene ND ug/L 10.0 3.7 1 02/04/19 11:00 02/11/19 21:51 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 4.1 1 02/04/19 11:00 02/11/19 21:51 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 4.0 1 02/04/19 11:00 02/11/19 21:51 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 4.5 1 02/04/19 11:00 02/11/19 21:51 207-08-9 Benzyl alcohol ND ug/L 20.0 2.3 1 02/04/19 11:00 02/11/19 21:51 100-51-6 4-Bromophenylphenyl ND ug/L 10.0 2.5 1 02/04/19 11:00 02/11/19 21:51 101-55-3 ether Butylbenzylphthalate ND ug/L 10.0 4.5 1 02/04/19 11:00 02/11/19 21:51 85-68-7 4-ChIoro-3-methyl phenol ND ug/L 10.0 2.8 1 02/04/19 11:00 02/11/19 21:51 59-50-7 4-Chloroaniline ND ug/L 20.0 2.8 1 02/04/19 11:00 02/11/19 21:51 106-47-8 Chlorobenzilate ND ug/L 10.0 1.6 1 02/04/19 11:00 02/11/19 21:51 510-15-6 bis(2- ND ug/L 10.0 1.6 1 02/04/19 11:00 02/11/19 21:51 111-91-1 Chloroethoxy)methane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270D MSSV Water, Extend bis(2-Chloroethyl) ether 2-Chloronaphthalene 2-Chlorophenol 4-Chlorophenylphenyl ether Chrysene Diallate Dibenz(a,h)anthracene Dibenzofuran 3,3'-Dichlorobenzidine 2,4-Dichlorophenol 2,6-Dichlorophenol Diethylphthalate Dimethoate 7,12- Dimethylbenz(a)anthracen e 3,3'-Dimethylbenzidine 2,4-Dimethylphenol Dimethylphthalate Di-n-butylphthalate 4,6-Dinitro-2-methyl phenol 1,3-Dinitrobenzene 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octylphthalate 1,2-Diphenylhydrazine Disulfoton bis(2- Ethyl hexyl)phthalate Ethyl methanesulfonate Famphur Fluoranthene Fluorene Hexachloro-1,3-butadiene Hexachlorobenzene Hexachlorocyclopentadien e Hexachloroethane Hexachloropropene Indeno(1,2,3-cd)pyrene Isophorone Isosafrole Kepone Methapyrilene 3-Methylcholanthrene Methyl methanesulfonate Date: 02/13/2019 02:20 PM Analytical Method: EPA 8270D Preparation Method: EPA 3510C ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 111-44-4 ND ug/L 10.0 1.6 1 02/04/19 11:00 02/11/19 21:51 91-58-7 ND ug/L 10.0 1.2 1 02/04/19 11:00 02/11/19 21:51 95-57-8 ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 7005-72-3 ND ug/L 10.0 4.1 1 02/04/19 11:00 02/11/19 21:51 218-01-9 ND ug/L 50.0 2.5 1 02/04/19 11:00 02/11/19 21:51 2303-16-4 ND ug/L 10.0 4.5 1 02/04/19 11:00 02/11/19 21:51 53-70-3 ND ug/L 10.0 2.1 1 02/04/19 11:00 02/11/19 21:51 132-64-9 ND ug/L 20.0 5.5 1 02/04/19 11:00 02/11/19 21:51 91-94-1 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 120-83-2 ND ug/L 10.0 5.1 1 02/04/19 11:00 02/11/19 21:51 87-65-0 ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 84-66-2 ND ug/L 50.0 1.4 1 02/04/19 11:00 02/11/19 21:51 60-51-5 ND ug/L 50.0 1.5 1 02/04/19 11:00 02/11/19 21:51 57-97-6 ND ug/L 50.0 2.3 1 02/04/19 11:00 02/11/19 21:51 119-93-7 ND ug/L 10.0 4.4 1 02/04/19 11:00 02/11/19 21:51 105-67-9 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 131-11-3 ND ug/L 10.0 3.5 1 02/04/19 11:00 02/11/19 21:51 84-74-2 ND ug/L 50.0 7.4 1 02/04/19 11:00 02/11/19 21:51 534-52-1 ND ug/L 10.0 2.9 1 02/04/19 11:00 02/11/19 21:51 99-65-0 ND ug/L 50.0 8.1 1 02/04/19 11:00 02/11/19 21:51 51-28-5 ND ug/L 20.0 4.2 1 02/04/19 11:00 02/11/19 21:51 121-14-2 ND ug/L 20.0 2.5 1 02/04/19 11:00 02/11/19 21:51 606-20-2 ND ug/L 10.0 5.8 1 02/04/19 11:00 02/11/19 21:51 117-84-0 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 122-66-7 ND ug/L 10.0 3.0 1 02/04/19 11:00 02/11/19 21:51 298-04-4 ND ug/L 10.0 5.2 1 02/04/19 11:00 02/11/19 21:51 117-81-7 ND ug/L 50.0 3.4 1 02/04/19 11:00 02/11/19 21:51 62-50-0 ND ug/L 10.0 2.1 1 02/04/19 11:00 02/11/19 21:51 52-85-7 ND ug/L 10.0 3.9 1 02/04/19 11:00 02/11/19 21:51 206-44-0 ND ug/L 10.0 2.4 1 02/04/19 11:00 02/11/19 21:51 86-73-7 ND ug/L 10.0 3.7 1 02/04/19 11:00 02/11/19 21:51 87-68-3 ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 118-74-1 ND ug/L 10.0 3.6 1 02/04/19 11:00 02/11/19 21:51 77-47-4 ND ug/L 10.0 2.4 1 02/04/19 11:00 02/11/19 21:51 67-72-1 ND ug/L 10.0 2.9 1 02/04/19 11:00 02/11/19 21:51 1888-71-7 ND ug/L 10.0 4.1 1 02/04/19 11:00 02/11/19 21:51 193-39-5 ND ug/L 10.0 2.1 1 02/04/19 11:00 02/11/19 21:51 78-59-1 ND ug/L 50.0 4.0 1 02/04/19 11:00 02/11/19 21:51 120-58-1 ND ug/L 20.0 12.4 1 02/04/19 11:00 02/11/19 21:51 143-50-0 ND ug/L 50.0 5.0 1 02/04/19 11:00 02/11/19 21:51 91-80-5 ND ug/L 50.0 1.6 1 02/04/19 11:00 02/11/19 21:51 56-49-5 ND ug/L 50.0 4.2 1 02/04/19 11:00 02/11/19 21:51 66-27-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270D MSSV Water, Extend 2-Methylnaphthalene Methyl parathion 2-Methylphenol(o-Cresol) 3&4-Methyl phenol (m&p Cresol) 1-Naphthalenamine 2-Naphthalenamine Naphthalene 1,4-Naphthoquinone 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene 2-Nitrophenol 4-Nitrophenol 5-Nitro-o-toluidine N-Nitrosodiethylamine N-Nitrosodimethylamine N-Nitroso-di-n-butylamine N-Nitroso-di-n- propylamine N-Nitrosodiphenylamine N- Nitrosomethylethylamine N-Nitrosopiperidine N-Nitrosopyrrolidine O,O,O- Tri ethyl phosphorothioate 2,2'-Oxybis(1- chloropropane) Parathion (Ethyl parathion) Pentachlorobenzene Pentachloronitrobenzene Pentachlorophenol Phenacetin Phenanthrene Phenol p-Phenylenediamine Phorate Pronamide Pyrene Safrole 1,2,4,5- Tetrachlorobenzene 2,3,4,6-Tetrachlorophenol Thionazin O-Toluidine Date: 02/13/2019 02:20 PM Analytical Method: EPA 8270D Preparation Method: EPA 3510C ND ug/L 10.0 1.6 1 02/04/19 11:00 02/11/19 21:51 91-57-6 ND ug/L 10.0 2.4 1 02/04/19 11:00 02/11/19 21:51 298-00-0 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 95-48-7 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 ND ug/L 10.0 2.6 1 02/04/19 11:00 02/11/19 21:51 134-32-7 ND ug/L 10.0 1.7 1 02/04/19 11:00 02/11/19 21:51 91-59-8 ND ug/L 10.0 1.3 1 02/04/19 11:00 02/11/19 21:51 91-20-3 ND ug/L 50.0 3.7 1 02/04/19 11:00 02/11/19 21:51 130-15-4 ND ug/L 50.0 3.1 1 02/04/19 11:00 02/11/19 21:51 88-74-4 ND ug/L 50.0 3.3 1 02/04/19 11:00 02/11/19 21:51 99-09-2 ND ug/L 50.0 4.9 1 02/04/19 11:00 02/11/19 21:51 100-01-6 ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 98-95-3 ND ug/L 50.0 2.5 1 02/04/19 11:00 02/11/19 21:51 88-75-5 ND ug/L 50.0 9.6 1 02/04/19 11:00 02/11/19 21:51 100-02-7 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 99-55-8 ND ug/L 10.0 3.5 1 02/04/19 11:00 02/11/19 21:51 55-18-5 ND ug/L 10.0 2.3 1 02/04/19 11:00 02/11/19 21:51 62-75-9 ND ug/L 10.0 4.5 1 02/04/19 11:00 02/11/19 21:51 924-16-3 ND ug/L 10.0 2.1 1 02/04/19 11:00 02/11/19 21:51 621-64-7 ND ug/L 10.0 2.3 1 02/04/19 11:00 02/11/19 21:51 86-30-6 ND ug/L 10.0 3.5 1 02/04/19 11:00 02/11/19 21:51 10595-95-6 ND ug/L 10.0 3.7 1 02/04/19 11:00 02/11/19 21:51 100-75-4 ND ug/L 10.0 4.2 1 02/04/19 11:00 02/11/19 21:51 930-55-2 ND ug/L 10.0 3.2 1 02/04/19 11:00 02/11/19 21:51 126-68-1 ND ug/L 10.0 2.6 1 02/04/19 11:00 02/11/19 21:51 108-60-1 ND ug/L 10.0 2.2 1 02/04/19 11:00 02/11/19 21:51 56-38-2 ND ug/L 10.0 3.3 1 02/04/19 11:00 02/11/19 21:51 608-93-5 ND ug/L 10.0 2.3 1 02/04/19 11:00 02/11/19 21:51 82-68-8 ND ug/L 20.0 8.3 1 02/04/19 11:00 02/11/19 21:51 87-86-5 ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 62-44-2 ND ug/L 10.0 2.5 1 02/04/19 11:00 02/11/19 21:51 85-01-8 ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 108-95-2 ND ug/L 50.0 9.1 1 02/04/19 11:00 02/11/19 21:51 106-50-3 ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 298-02-2 ND ug/L 50.0 1.3 1 02/04/19 11:00 02/11/19 21:51 23950-58-5 ND ug/L 10.0 3.4 1 02/04/19 11:00 02/11/19 21:51 129-00-0 ND ug/L 50.0 3.0 1 02/04/19 11:00 02/11/19 21:51 94-59-7 ND ug/L 10.0 1.7 1 02/04/19 11:00 02/11/19 21:51 95-94-3 ND ug/L 20.0 3.2 1 02/04/19 11:00 02/11/19 21:51 58-90-2 ND ug/L 10.0 1.2 1 02/04/19 11:00 02/11/19 21:51 297-97-2 ND ug/L 10.0 3.4 1 02/04/19 11:00 02/11/19 21:51 95-53-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8270D MSSV Water, Extend 1,2,4-Trichlorobenzene 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 1,3,5-Trinitrobenzene Surrogates Nitrobenzene-d5 (S) 2-Fluorobiphenyl (S) p-Terphenyl-d14 (S) Phenol-d6 (S) 2-Fluorophenol (S) 2,4,6-Tribromophenol (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane Date: 02/13/2019 02:20 PM Analytical Method: EPA 8270D Preparation Method: EPA 3510C ND ug/L 10.0 2.0 1 02/04/19 11:00 02/11/19 21:51 120-82-1 ND ug/L 10.0 2.7 1 02/04/19 11:00 02/11/19 21:51 95-95-4 ND ug/L 10.0 2.2 1 02/04/19 11:00 02/11/19 21:51 88-06-2 ND ug/L 10.0 1.4 1 02/04/19 11:00 02/11/19 21:51 99-35-4 53 %. 13-107 1 02/04/19 11:00 02/11/19 21:51 4165-60-0 65 %. 12-129 1 02/04/19 11:00 02/11/19 21:51 321-60-8 86 %. 14-147 1 02/04/19 11:00 02/11/19 21:51 1718-51-0 23 %. 10-46 1 02/04/19 11:00 02/11/19 21:51 13127-88-3 35 %. 10-64 1 02/04/19 11:00 02/11/19 21:51 367-12-4 81 %. 10-148 1 02/04/19 11:00 02/11/19 21:51 118-79-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 02/01/19 00:12 123-91-1 97 % 50-150 1 02/01 /19 00:12 17060-07-0 116 % 50-150 1 02/01 /19 00:12 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1912:39 67-64-1 ND ug/L 50.0 10.0 1 02/09/1912:39 75-05-8 ND ug/L 50.0 7.8 1 02/09/1912:39 107-02-8 ND ug/L 200 2.5 1 02/09/1912:39 107-13-1 ND ug/L 10.0 0.96 1 02/09/1912:39 107-05-1 1.6 ug/L 1.0 0.20 1 02/09/1912:39 71-43-2 ND ug/L 3.0 0.50 1 02/09/1912:39 74-97-5 ND ug/L 1.0 0.36 1 02/09/1912:39 75-27-4 ND ug/L 3.0 0.55 1 02/09/1912:39 75-25-2 ND ug/L 10.0 0.95 1 02/09/1912:39 74-83-9 ND ug/L 100 3.2 1 02/09/1912:39 78-93-3 ND ug/L 100 0.79 1 02/09/1912:39 75-15-0 ND ug/L 1.0 0.42 1 02/09/1912:39 56-23-5 ND ug/L 3.0 0.53 1 02/09/1912:39 108-90-7 ND ug/L 10.0 0.52 1 02/09/1912:39 75-00-3 ND ug/L 5.0 0.58 1 02/09/1912:39 67-66-3 ND ug/L 1.0 0.38 1 02/09/1912:39 74-87-3 ND ug/L 10.0 1.4 1 02/09/1912:39 126-99-8 ND ug/L 3.0 0.31 1 02/09/1912:39 124-48-1 ND ug/L 10.0 0.62 1 02/09/1912:39 74-95-3 ND ug/L 5.0 0.49 1 02/09/1912:39 95-50-1 ND ug/L 1.0 0.59 1 02/09/1912:39 541-73-1 ND ug/L 1.0 0.58 1 02/09/1912:39 106-46-7 ND ug/L 100 1.6 1 02/09/1912:39 110-57-6 ND ug/L 1.0 0.48 1 02/09/1912:39 75-71-8 1.2J ug/L 5.0 0.41 1 02/09/1912:39 75-34-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-MW-2R Lab ID: 2614221001 Collected: 01/28/19 14:56 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene Ethyl methacrylate 2-Hexanone lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-M ethyl-2-pe n to n o n e (MIBK) Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 9014 Cyanide Cyanide 9034 Sulfide, Titration Sulfide Date: 02/13/2019 02:20 PM Analytical Method: EPA 8260E ND ug/L 1.0 0.67 1 02/09/1912:39 107-06-2 ND ug/L 5.0 0.72 1 02/09/1912:39 75-35-4 2.9J ug/L 5.0 0.66 1 02/09/1912:39 156-59-2 ND ug/L 5.0 0.46 1 02/09/1912:39 156-60-5 ND ug/L 1.0 0.60 1 02/09/1912:39 78-87-5 ND ug/L 1.0 0.69 1 02/09/1912:39 142-28-9 ND ug/L 1.0 0.23 1 02/09/1912:39 594-20-7 ND ug/L 1.0 0.60 1 02/09/1912:39 563-58-6 ND ug/L 1.0 0.22 1 02/09/1912:39 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1912:39 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1912:39 100-41-4 ND ug/L 10.0 0.59 1 02/09/1912:39 97-63-2 ND ug/L 50.0 0.89 1 02/09/1912:39 591-78-6 ND ug/L 10.0 3.1 1 02/09/1912:39 74-88-4 ND ug/L 100 19.0 1 02/09/1912:39 78-83-1 ND ug/L 10.0 0.79 1 02/09/1912:39 126-98-7 ND ug/L 1.0 0.50 1 02/09/1912:39 75-09-2 ND ug/L 10.0 0.89 1 02/09/1912:39 80-62-6 ND ug/L 100 0.86 1 02/09/1912:39 108-10-1 ND ug/L 20.0 3.1 1 02/09/1912:39 107-12-0 ND ug/L 1.0 0.50 1 02/09/1912:39 100-42-5 ND ug/L 5.0 0.32 1 02/09/1912:39 630-20-6 ND ug/L 3.0 0.53 1 02/09/1912:39 79-34-5 0.92J ug/L 1.0 0.78 1 02/11/1914:51 127-18-4 ND ug/L 1.0 0.31 1 02/09/1912:39 108-88-3 ND ug/L 1.0 0.38 1 02/09/1912:39 71-55-6 ND ug/L 1.0 0.59 1 02/09/1912:39 79-00-5 ND ug/L 1.0 0.34 1 02/09/1912:39 79-01-6 ND ug/L 1.0 0.51 1 02/09/1912:39 75-69-4 ND ug/L 1.0 0.46 1 02/09/1912:39 96-18-4 ND ug/L 50.0 0.42 1 02/09/1912:39 108-05-4 0.97J ug/L 1.0 0.60 1 02/09/1912:39 75-01-4 97 %. 81-119 1 02/09/1912:39 17060-07-0 93 %. 82-114 1 02/09/1912:39 1868-53-7 108 %. 82-120 1 02/09/1912:39 460-00-4 98 %. 82-109 1 02/09/1912:39 2037-26-5 Analytical Method: EPA 9014 Cyanide Preparation Method: EPA 9010C ND mg/L 0.010 0.010 1 02/05/1910:35 02/05/1914:17 57-12-5 Analytical Method: EPA 9034 Preparation Method: EPA 9030A ND mg/L 1.0 1.0 1 02/01 /19 11:50 02/01 /19 17:13 18496-25-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-Trip Blank Lab ID: 2614221002 Collected: 01/28/19 06:03 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8011 GCS EDB and DBCP 1,2-Dibromo-3- chloropropane 1,2-Dibromoethane (EDB) Surrogates Bromoform (S) 8260B MSV Water, Extend Acetone Acetonitrile Acrolein Acrylonitrile Allyl chloride Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Chloroprene Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene Ethyl methacrylate 2-Hexanone Date: 02/13/2019 02:20 PM Analytical Method: EPA 8011 Preparation Method: EPA 8011 ND ug/L 0.20 0.061 1 02/04/19 11:05 02/04/19 21:20 96-12-8 ND ug/L 0.051 0.015 1 02/04/19 11:05 02/04/19 21:20 106-93-4 119 %. 31-168 1 02/04/19 11:05 02/04/19 21:20 75-25-2 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 02/09/1913:04 67-64-1 ND ug/L 50.0 10.0 1 02/09/1913:04 75-05-8 ND ug/L 50.0 7.8 1 02/09/1913:04 107-02-8 ND ug/L 200 2.5 1 02/09/1913:04 107-13-1 ND ug/L 10.0 0.96 1 02/09/1913:04 107-05-1 ND ug/L 1.0 0.20 1 02/09/1913:04 71-43-2 ND ug/L 3.0 0.50 1 02/09/1913:04 74-97-5 ND ug/L 1.0 0.36 1 02/09/1913:04 75-27-4 ND ug/L 3.0 0.55 1 02/09/1913:04 75-25-2 ND ug/L 10.0 0.95 1 02/09/1913:04 74-83-9 ND ug/L 100 3.2 1 02/09/1913:04 78-93-3 ND ug/L 100 0.79 1 02/09/1913:04 75-15-0 ND ug/L 1.0 0.42 1 02/09/1913:04 56-23-5 ND ug/L 3.0 0.53 1 02/09/1913:04 108-90-7 ND ug/L 10.0 0.52 1 02/09/1913:04 75-00-3 ND ug/L 5.0 0.58 1 02/09/1913:04 67-66-3 ND ug/L 1.0 0.38 1 02/09/1913:04 74-87-3 ND ug/L 10.0 1.4 1 02/09/1913:04 126-99-8 ND ug/L 3.0 0.31 1 02/09/1913:04 124-48-1 ND ug/L 10.0 0.62 1 02/09/1913:04 74-95-3 ND ug/L 5.0 0.49 1 02/09/1913:04 95-50-1 ND ug/L 1.0 0.59 1 02/09/1913:04 541-73-1 ND ug/L 1.0 0.58 1 02/09/1913:04 106-46-7 ND ug/L 100 1.6 1 02/09/1913:04 110-57-6 ND ug/L 1.0 0.48 1 02/09/1913:04 75-71-8 ND ug/L 5.0 0.41 1 02/09/1913:04 75-34-3 ND ug/L 1.0 0.67 1 02/09/1913:04 107-06-2 ND ug/L 5.0 0.72 1 02/09/1913:04 75-35-4 ND ug/L 5.0 0.66 1 02/09/1913:04 156-59-2 ND ug/L 5.0 0.46 1 02/09/1913:04 156-60-5 ND ug/L 1.0 0.60 1 02/09/1913:04 78-87-5 ND ug/L 1.0 0.69 1 02/09/1913:04 142-28-9 ND ug/L 1.0 0.23 1 02/09/1913:04 594-20-7 ND ug/L 1.0 0.60 1 02/09/1913:04 563-58-6 ND ug/L 1.0 0.22 1 02/09/1913:04 10061-01-5 ND ug/L 1.0 0.30 1 02/09/1913:04 10061-02-6 ND ug/L 1.0 0.45 1 02/09/1913:04 100-41-4 ND ug/L 10.0 0.59 1 02/09/1913:04 97-63-2 ND ug/L 50.0 0.89 1 02/09/1913:04 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF NC-1403 Pace Project No.: 2614221 Sample: 1403-Trip Blank Parameters 8260B MSV Water, Extend lodomethane Isobutanol Methacrylonitrile Methylene Chloride Methyl methacrylate 4-M ethyl-2-pe n to n o n e (MIBK) Propionitrile Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 02/13/2019 02:20 PM ANALYTICAL RESULTS Lab ID: 2614221002 Collected: 01/28/19 06:03 Received: 01/29/19 10:00 Matrix: Water Report Reg. Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Analytical Method: EPA 8260E ND ug/L 10.0 3.1 1 02/09/1913:04 74-88-4 ND ug/L 100 19.0 1 02/09/1913:04 78-83-1 ND ug/L 10.0 0.79 1 02/09/1913:04 126-98-7 ND ug/L 1.0 0.50 1 02/09/1913:04 75-09-2 ND ug/L 10.0 0.89 1 02/09/1913:04 80-62-6 ND ug/L 100 0.86 1 02/09/1913:04 108-10-1 ND ug/L 20.0 3.1 1 02/09/1913:04 107-12-0 ND ug/L 1.0 0.50 1 02/09/1913:04 100-42-5 ND ug/L 5.0 0.32 1 02/09/1913:04 630-20-6 ND ug/L 3.0 0.53 1 02/09/1913:04 79-34-5 ND ug/L 1.0 0.78 1 02/11/1915:16 127-18-4 ND ug/L 1.0 0.31 1 02/09/1913:04 108-88-3 ND ug/L 1.0 0.38 1 02/09/1913:04 71-55-6 ND ug/L 1.0 0.59 1 02/09/1913:04 79-00-5 ND ug/L 1.0 0.34 1 02/09/1913:04 79-01-6 ND ug/L 1.0 0.51 1 02/09/1913:04 75-69-4 ND ug/L 1.0 0.46 1 02/09/1913:04 96-18-4 ND ug/L 50.0 0.42 1 02/09/1913:04 108-05-4 ND ug/L 1.0 0.60 1 02/09/1913:04 75-01-4 ND ug/L 5.0 1.5 1 02/09/1913:04 1330-20-7 101 %. 81-119 1 02/09/1913:04 17060-07-0 95 %. 82-114 1 02/09/1913:04 1868-53-7 105 %. 82-120 1 02/09/1913:04 460-00-4 100 %. 82-109 1 02/09/1913:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21707 Analysis Method: EPA 8011 QC Batch Method: EPA 8011 Analysis Description: GCS 8011 EDB DBCP Associated Lab Samples: 2614221001, 2614221002 METHOD BLANK: 97833 Matrix: Water Associated Lab Samples: 2614221001, 2614221002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,2-Dibromo-3-chloropropane ug/L ND 0.21 0.063 02/04/19 17:29 1,2-Dibromoethane (EDB) ug/L ND 0.052 0.015 02/04/19 17:29 Bromoform (S) %. 95 31-168 02/04/19 17:29 LABORATORY CONTROL SAMPLE: 97834 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,2-Dibromo-3-chloropropane ug/L 0.1 0.078J 75 60-140 1,2-Dibromoethane (EDB) ug/L 0.1 0.067 64 60-140 Bromoform (S) %. 78 31-168 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97835 97836 MS MSD 2614135017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2-Dibromo-3- ug/L ND 0.1 0.1 0.14J 0.101 140 102 32-189 32 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 0.1 0.1 0.13 0.11 126 103 48-189 21 21 Bromoform (S) %. 117 102 31-168 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21462 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2614221001 METHOD BLANK: 96558 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.036 01/30/1913:48 LABORATORY CONTROL SAMPLE: 96559 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 96560 96561 MS MSD 2614123002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.4 2.5 97 99 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21711 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2614221001 METHOD BLANK: 97845 Associated Lab Samples: 2614221001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L 0.89J 6.0 0.78 02/04/1919:54 Arsenic ug/L ND 10.0 0.57 02/04/1919:54 Barium ug/L ND 100 0.78 02/04/1919:54 Beryllium ug/L ND 1.0 0.050 02/04/1919:54 Cadmium ug/L ND 1.0 0.093 02/04/1919:54 Chromium ug/L ND 10.0 1.6 02/04/1919:54 Cobalt ug/L ND 10.0 0.52 02/04/1919:54 Copper ug/L ND 10.0 1.3 02/04/1919:54 Lead ug/L ND 10.0 0.27 02/04/1919:54 Nickel ug/L ND 50.0 0.95 02/04/1919:54 Selenium ug/L ND 10.0 1.4 02/04/1919:54 Silver ug/L ND 10.0 0.95 02/04/1919:54 Thallium ug/L ND 5.5 0.14 02/04/1919:54 Tin ug/L ND 20.0 7.0 02/04/1919:54 Vanadium ug/L ND 25.0 1.9 02/04/1919:54 Zinc ug/L ND 10.0 2.1 02/04/1919:54 LABORATORY CONTROL SAMPLE: 97846 Parameter Units Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Thallium ug/L Tin ug/L Vanadium ug/L Zinc ug/L Spike Conc. LCS Result LCS % Rec % Rec Limits 100 110 110 80-120 100 95.0 95 80-120 100 99.91 100 80-120 100 98.5 98 80-120 100 96.8 97 80-120 100 102 102 80-120 100 97.8 98 80-120 100 98.5 98 80-120 100 95.1 95 80-120 100 96.9 97 80-120 100 97.2 97 80-120 100 102 102 80-120 100 95.2 95 80-120 100 101 101 80-120 100 101 101 80-120 100 98.2 98 80-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97849 97850 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 112 106 112 75-125 5 20 Arsenic ug/L 1.7J 100 100 94.1 95.2 92 93 75-125 1 20 Barium ug/L 119 100 100 202 209 83 91 75-125 4 20 Beryllium ug/L 0.071J 100 100 95.1 101 95 101 75-125 6 20 Cadmium ug/L ND 100 100 94.4 100 94 100 75-125 6 20 Chromium ug/L ND 100 100 107 103 106 102 75-125 4 20 Cobalt ug/L ND 100 100 99.5 99.0 99 99 75-125 0 20 Copper ug/L ND 100 100 99.6 98.3 99 98 75-125 1 20 Lead ug/L ND 100 100 95.9 98.3 96 98 75-125 3 20 Nickel ug/L ND 100 100 99.3 99.2 99 99 75-125 0 20 Selenium ug/L 20.4 100 100 92.1 99.5 72 79 75-125 8 20 M1 Silver ug/L ND 100 100 99.7 102 100 102 75-125 2 20 Thallium ug/L ND 100 100 96.2 97.7 96 98 75-125 2 20 Tin ug/L ND 100 100 103 103 103 103 75-125 0 20 Vanadium ug/L 2.6J 100 100 109 107 106 104 75-125 2 20 Zinc ug/L ND 100 100 96.6 101 96 100 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 455695 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2614221001 METHOD BLANK: 2487081 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 01/31/19 16:10 1,2-Dichloroethane-d4 (S) % 93 50-150 01/31/19 16:10 Toluene-d8 (S) % 113 50-150 01/31/19 16:10 LABORATORY CONTROL SAMPLE: 2487082 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.7 98 71-125 1,2-Dichloroethane-d4 (S) % 93 50-150 Toluene-d8(S) % 108 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2487083 2487084 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.5 ND 97 0 50-150 30 M1 1,2-Dichloroethane-d4 (S) % 97 97 50-150 30 Toluene-d8 (S) % 116 114 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 22128 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2614221001, 2614221002 METHOD BLANK: 99745 Associated Lab Samples: 2614221001, 2614221002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 02/09/19 11:22 1,1,1-Trichloroethane ug/L ND 1.0 0.38 02/09/19 11:22 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 02/09/19 11:22 1,1,2-Trichloroethane ug/L ND 1.0 0.59 02/09/19 11:22 1,1-Dichloroethane ug/L ND 5.0 0.41 02/09/19 11:22 1,1-Dichloroethene ug/L ND 5.0 0.72 02/09/19 11:22 1,1-Dichloropropene ug/L ND 1.0 0.60 02/09/19 11:22 1,2,3-Trichloropropane ug/L ND 1.0 0.46 02/09/19 11:22 1,2-Dichlorobenzene ug/L ND 5.0 0.49 02/09/19 11:22 1,2-Dichloroethane ug/L ND 1.0 0.67 02/09/19 11:22 1,2-Dichloropropane ug/L ND 1.0 0.60 02/09/19 11:22 1,3-Dichlorobenzene ug/L ND 1.0 0.59 02/09/19 11:22 1,3-Dichloropropane ug/L ND 1.0 0.69 02/09/19 11:22 1,4-Dichlorobenzene ug/L ND 1.0 0.58 02/09/19 11:22 2,2-Dichloropropane ug/L ND 1.0 0.23 02/09/19 11:22 2-Butanone (MEK) ug/L ND 100 3.2 02/09/19 11:22 2-Hexanone ug/L ND 50.0 0.89 02/09/19 11:22 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 02/09/19 11:22 Acetone ug/L ND 100 8.2 02/09/19 11:22 Acrolein ug/L ND 50.0 7.8 02/09/19 11:22 Acrylonitrile ug/L ND 200 2.5 02/09/19 11:22 Allyl chloride ug/L ND 10.0 0.96 02/09/19 11:22 Benzene ug/L ND 1.0 0.20 02/09/19 11:22 Bromochloromethane ug/L ND 3.0 0.50 02/09/19 11:22 Bromodichloromethane ug/L ND 1.0 0.36 02/09/19 11:22 Bromoform ug/L ND 3.0 0.55 02/09/19 11:22 Bromomethane ug/L ND 10.0 0.95 02/09/19 11:22 Carbon disulfide ug/L ND 100 0.79 02/09/19 11:22 Carbon tetrachloride ug/L ND 1.0 0.42 02/09/19 11:22 Chlorobenzene ug/L ND 3.0 0.53 02/09/19 11:22 Chloroethane ug/L ND 10.0 0.52 02/09/19 11:22 Chloroform ug/L ND 5.0 0.58 02/09/19 11:22 Chloromethane ug/L ND 1.0 0.38 02/09/19 11:22 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 02/09/19 11:22 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 02/09/19 11:22 Dibromochloromethane ug/L ND 3.0 0.31 02/09/19 11:22 Dibromomethane ug/L ND 10.0 0.62 02/09/19 11:22 Dichlorodifluoromethane ug/L ND 1.0 0.48 02/09/19 11:22 Ethyl methacrylate ug/L ND 10.0 0.59 02/09/19 11:22 Ethylbenzene ug/L ND 1.0 0.45 02/09/19 11:22 lodomethane ug/L ND 10.0 3.1 02/09/19 11:22 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 METHOD BLANK: 99745 Associated Lab Samples: Parameter 2614221001, 2614221002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Methacrylonitrile ug/L ND 10.0 0.79 02/09/19 11:22 Methyl methacrylate ug/L ND 10.0 0.89 02/09/19 11:22 Methylene Chloride ug/L ND 1.0 0.50 02/09/19 11:22 Propionitrile ug/L ND 20.0 3.1 02/09/19 11:22 Styrene ug/L ND 1.0 0.50 02/09/19 11:22 Toluene ug/L ND 1.0 0.31 02/09/19 11:22 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 02/09/19 11:22 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 02/09/19 11:22 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 02/09/19 11:22 Trichloroethene ug/L ND 1.0 0.34 02/09/19 11:22 Trichlorofluoromethane ug/L ND 1.0 0.51 02/09/19 11:22 Vinyl acetate ug/L ND 50.0 0.42 02/09/19 11:22 Vinyl chloride ug/L ND 1.0 0.60 02/09/19 11:22 Xylene (Total) ug/L ND 5.0 1.5 02/09/19 11:22 1,2-Dichloroethane-d4 (S) %. 94 81-119 02/09/19 11:22 4-Bromofluorobenzene (S) %. 105 82-120 02/09/19 11:22 Dibromofluoromethane (S) %. 92 82-114 02/09/19 11:22 Toluene-d8 (S) %. 99 82-109 02/09/19 11:22 Qualifiers METHOD BLANK: 100248 Matrix: Water Associated Lab Samples: 2614221001, 2614221002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrachloroethene ug/L ND 1.0 0.78 02/11/19 11:31 1,2-Dichloroethane-d4 (S) %. 99 81-119 02/11/19 11:31 4-Bromofluorobenzene (S) %. 99 82-120 02/11/19 11:31 Dibromofluoromethane (S) %. 94 82-114 02/11/19 11:31 Toluene-d8 (S) %. 91 82-109 02/11/19 11:31 LABORATORY CONTROL SAMPLE: 99746 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 44.2 88 68-137 1,1,1-Trichloroethane ug/L 50 54.5 109 72-134 1,1,2,2-Tetrachloroethane ug/L 50 46.8 94 51-158 1,1,2-Trichloroethane ug/L 50 49.1 98 78-131 1,1-Dichloroethane ug/L 50 49.8 100 69-151 1,1-Dichloroethene ug/L 50 48.2 96 64-158 1,1-Dichloropropene ug/L 50 48.5 97 70-133 1,2,3-Trichloropropane ug/L 50 50.0 100 78-133 1,2-Dichlorobenzene ug/L 50 48.6 97 70-135 1,2-Dichloroethane ug/L 50 45.5 91 72-129 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 LABORATORY CONTROL SAMPLE: Parameter 99746 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dichloropropane ug/L 50 48.7 97 64-135 1,3-Dichlorobenzene ug/L 50 50.1 100 71-134 1,3-Dichloropropane ug/L 50 51.0 102 70-140 1,4-Dichlorobenzene ug/L 50 46.8 94 70-131 2,2-Dichloropropane ug/L 50 46.8 94 34-170 2-Butanone (MEK) ug/L 100 78.8J 79 52-143 2-Hexanone ug/L 100 78.0 78 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 75.OJ 75 71-129 Acetone ug/L 100 71.OJ 71 48-224 Acrolein ug/L 100 97.7 98 57-185 Acrylonitrile ug/L 200 233 116 66-154 Allyl chloride ug/L 100 103 103 58-150 Benzene ug/L 50 47.6 95 68-132 Bromochloromethane ug/L 50 45.3 91 73-133 Bromodichloromethane ug/L 50 52.7 105 67-121 Bromoform ug/L 50 39.7 79 57-125 Bromomethane ug/L 50 62.2 124 35-156 Carbon disulfide ug/L 100 113 113 47-141 Carbon tetrachloride ug/L 50 50.4 101 66-122 Chlorobenzene ug/L 50 47.5 95 71-126 Chloroethane ug/L 50 46.0 92 43-143 Chloroform ug/L 50 47.6 95 71-136 Chloromethane ug/L 50 47.0 94 47-123 cis-1,2-Dichloroethene ug/L 50 46.7 93 74-131 cis-1,3-Dichloropropene ug/L 50 44.0 88 78-120 Dibromochloromethane ug/L 50 42.2 84 65-115 Dibromomethane ug/L 50 46.2 92 79-129 Dichlorodifluoromethane ug/L 50 54.0 108 29-124 Ethyl methacrylate ug/L 100 86.4 86 75-130 Ethylbenzene ug/L 50 49.2 98 68-129 lodomethane ug/L 100 88.5 89 49-154 Methacrylonitrile ug/L 100 77.7 78 74-139 Methyl methacrylate ug/L 100 84.4 84 75-133 Methylene Chloride ug/L 50 48.6 97 61-147 Propionitrile ug/L 100 81.0 81 69-139 Styrene ug/L 50 47.9 96 77-128 Tetrachloroethene ug/L 50 48.7 97 51-139 Toluene ug/L 50 49.7 99 60-133 trans-1,2-Dichloroethene ug/L 50 42.7 85 69-144 trans- 1,3-Dichloropropene ug/L 50 41.6 83 74-128 trans-1,4-Dichloro-2-butene ug/L 100 85.8J 86 61-139 Trichloroethene ug/L 50 43.0 86 73-126 Trichlorofluoromethane ug/L 50 54.0 108 55-132 Vinyl acetate ug/L 50 45.3J 91 52-141 Vinyl chloride ug/L 50 46.6 93 50-133 Xylene (Total) ug/L 150 159 106 78-132 1,2-Dichloroethane-d4 (S) %. 95 81-119 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 LABORATORY CONTROL SAMPLE: 99746 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4-Bromofluorobenzene (S) %. 93 82-120 Dibromofluoromethane (S) %. 99 82-114 Toluene-d8 (S) %. 98 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99747 2614222005 Parameter Units Result MS Spike Conc. MSD Spike Conc. 99748 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 40.6 38.3 81 77 68-137 6 11 1,1,1-Trichloroethane ug/L ND 50 50 52.5 50.8 105 102 66-142 3 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 42.6 40.7 85 81 39-171 5 13 1,1,2-Trichloroethane ug/L ND 50 50 45.7 41.4 91 83 73-136 10 12 1,1-Dichloroethane ug/L ND 50 50 44.7 43.5 89 87 66-155 3 15 1,1-Dichloroethene ug/L ND 50 50 50.4 45.8 101 92 33-181 10 34 1,1-Dichloropropene ug/L ND 50 50 49.2 45.2 98 90 70-133 9 12 1,2,3-Trichloropropane ug/L ND 50 50 44.4 42.4 89 85 78-133 4 14 1,2-Dichlorobenzene ug/L ND 50 50 42.7 40.9 85 82 69-135 4 10 1,2-Dichloroethane ug/L ND 50 50 43.6 40.0 87 80 36-159 9 10 1,2-Dichloropropane ug/L ND 50 50 45.0 41.6 90 83 68-132 8 11 1,3-Dichlorobenzene ug/L ND 50 50 43.6 42.3 87 85 68-135 3 10 1,3-Dichloropropane ug/L ND 50 50 50.2 46.3 100 93 70-138 8 10 1,4-Dichlorobenzene ug/L ND 50 50 41.2 38.9 82 78 49-153 6 9 2,2-Dichloropropane ug/L ND 50 50 35.8 34.7 72 69 34-170 3 9 2-Butanone (MEK) ug/L ND 100 100 65.9J 60.5J 66 61 10-189 9 23 2-Hexanone ug/L ND 100 100 69.4 63.0 69 63 40-135 10 18 4- Methyl -2-pentanone ug/L ND 100 100 72.1J 63.7J 72 64 30-177 12 10 R1 (MIBK) Acetone ug/L ND 100 100 55.8J 49.7J 56 50 44-223 12 14 Acrolein ug/L ND 100 100 81.1 74.1 81 74 57-185 9 30 Acrylonitrile ug/L ND 200 200 162J 148J 81 74 13-189 9 12 Allyl chloride ug/L ND 100 100 92.9 86.7 93 87 58-150 7 18 Benzene ug/L ND 50 50 44.6 41.0 89 82 66-139 8 10 Bromochloromethane ug/L ND 50 50 42.5 40.0 85 80 73-133 6 13 Bromodichloromethane ug/L ND 50 50 49.7 44.6 99 89 57-120 11 13 Bromoform ug/L ND 50 50 37.0 35.0 74 70 48-128 6 13 Bromomethane ug/L ND 50 50 46.0 49.3 92 99 10-187 7 32 Carbon disulfide ug/L ND 100 100 114 103 114 103 47-141 10 322 Carbon tetrachloride ug/L ND 50 50 51.8 47.3 104 95 58-127 9 14 Chlorobenzene ug/L ND 50 50 44.1 42.2 88 84 63-137 4 10 Chloroethane ug/L ND 50 50 43.7 39.6 87 79 52-146 10 16 Chloroform ug/L ND 50 50 44.6 40.3 89 81 74-137 10 9 R1 Chloromethane ug/L ND 50 50 43.1 40.2 86 80 41-127 7 10 cis-1,2-Dichloroethene ug/L ND 50 50 43.9 41.9 87 83 71-138 5 16 cis-1,3-Dichloropropene ug/L ND 50 50 40.5 37.9 81 76 32-145 7 12 Dibromochloromethane ug/L ND 50 50 40.8 37.5 82 75 52-116 8 13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99747 99748 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Dibromomethane ug/L ND 50 50 45.5 43.4 91 87 79-129 5 14 Dichlorodifluoromethane ug/L ND 50 50 61.8 61.8 124 124 36-126 0 15 Ethyl methacrylate ug/L ND 100 100 82.1 73.5 82 74 75-130 11 14 M1 Ethylbenzene ug/L ND 50 50 47.3 43.6 95 87 31-174 8 10 lodomethane ug/L ND 100 100 77.3 72.1 77 72 49-154 7 30 Methacrylonitrile ug/L ND 100 100 74.5 68.5 75 68 74-139 8 14 M1 Methyl methacrylate ug/L ND 100 100 83.5 74.2 83 74 75-133 12 13 M1 Methylene Chloride ug/L ND 50 50 42.2 36.6 84 73 61-146 14 15 Propionitrile ug/L ND 100 100 56.9 63.3 57 63 69-139 11 16 M1 Styrene ug/L ND 50 50 44.1 40.8 88 82 77-128 8 14 Tetrachloroethene ug/L ND 50 50 47.0 42.3 94 85 36-155 10 14 Toluene ug/L ND 50 50 48.0 43.2 96 86 52-146 11 11 trans-1,2-Dichloroethene ug/L ND 50 50 28.4 26.6 57 53 61-152 7 14 M1 trans-1,3-Dichloropropene ug/L ND 50 50 37.2 35.1 74 70 37-146 6 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 66.5J 63.7J 67 64 61-139 4 12 Trichloroethene ug/L ND 50 50 43.3 40.5 87 81 61-141 7 12 Trichlorofluoromethane ug/L ND 50 50 60.4 54.8 121 110 51-141 10 13 Vinyl acetate ug/L ND 50 50 57.5 52.5 115 105 52-141 9 14 Vinyl chloride ug/L ND 50 50 49.0 44.0 98 88 22-156 11 26 Xylene (Total) ug/L ND 150 150 150 140 100 93 78-132 7 7 1,2-Dichloroethane-d4 (S) %. 99 97 81-119 4-Bromofluorobenzene (S) %. 97 98 82-120 Dibromofluoromethane (S) %. 101 102 82-114 Toluene-d8 (S) %. 99 99 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21609 Analysis Method: EPA 8081 B QC Batch Method: EPA 3510C Analysis Description: 8081 GCS Pesticides Associated Lab Samples: 2614221001 METHOD BLANK: 97308 Associated Lab Samples: 2614221001 Parameter Units 4,4'-DDD ug/L 4,4'-DDE ug/L 4,4'-DDT ug/L Aldrin ug/L alpha-BHC ug/L beta-BHC ug/L Chlordane (Technical) ug/L delta-BHC ug/L Dieldrin ug/L Endosulfan I ug/L Endosulfan 11 ug/L Endosulfan sulfate ug/L Endrin ug/L Endrin aldehyde ug/L gamma-BHC (Lindane) ug/L Heptachlor ug/L Heptachlor epoxide ug/L Isodrin ug/L Methoxychlor ug/L Toxaphene ug/L Decachlorobiphenyl (S) %. Tetrachloro-m-xylene (S) %. LABORATORY CONTROL SAMPLE: 97309 Matrix: Water Blank Result Reporting Limit MDL Analyzed ND 0.10 0.034 02/05/19 17:15 ND 0.10 0.030 02/05/19 17:15 ND 0.10 0.034 02/05/19 17:15 ND 0.10 0.044 02/05/19 17:15 ND 0.10 0.039 02/05/19 17:15 ND 0.10 0.046 02/05/19 17:15 ND 0.50 0.29 02/05/19 17:15 ND 0.10 0.032 02/05/19 17:15 ND 0.10 0.036 02/05/19 17:15 ND 0.50 0.068 02/05/19 17:15 ND 0.50 0.037 02/05/19 17:15 ND 0.50 0.032 02/05/19 17:15 ND 0.20 0.040 02/05/19 17:15 ND 0.20 0.081 02/05/19 17:15 ND 0.10 0.037 02/05/19 17:15 ND 0.10 0.034 02/05/19 17:15 ND 0.10 0.042 02/05/19 17:15 ND 0.50 0.034 02/05/19 17:15 ND 0.30 0.048 02/05/19 17:15 ND 2.0 0.22 02/05/19 17:15 64 10-157 02/05/19 17:15 101 19-148 02/05/19 17:15 Qualifiers Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 4,4'-DDD ug/L 2.5 3.5 138 56-149 4,4'-DDE ug/L 2.5 3.2 129 54-138 4,4'-DDT ug/L 2.5 3.5 139 29-173 Aldrin ug/L 2.5 3.0 120 49-126 alpha-BHC ug/L 2.5 3.2 126 47-135 beta-BHC ug/L 2.5 3.3 130 57-136 delta-BHC ug/L 2.5 3.0 121 39-121 Dieldrin ug/L 2.5 3.0 119 56-129 Endosulfan I ug/L 2.5 3.0 120 57-135 Endosulfan II ug/L 2.5 3.2 129 60-142 Endosulfan sulfate ug/L 2.5 3.1 125 55-133 Endrin ug/L 2.5 3.1 124 58-148 Endrin aldehyde ug/L 2.5 3.1 124 57-131 gamma-BHC (Lindane) ug/L 2.5 3.2 129 48-135 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 LABORATORY CONTROL SAMPLE: 97309 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Heptachlor ug/L 2.5 3.0 120 45-144 Heptachlor epoxide ug/L 2.5 2.9 116 56-131 Isodrin ug/L 2.5 2.8 113 46-147 Methoxychlor ug/L 2.5 3.4 134 47-166 Decachlorobiphenyl (S) %. 96 10-157 Tetrachloro-m-xylene (S) %. 104 19-148 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97310 97311 MS MSD 2614219017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4,4'-DDD ug/L ND 2.5 2.5 3.3 3.1 132 125 38-173 5 36 4,4'-DDE ug/L ND 2.5 2.5 3.4 3.4 136 134 24-172 1 38 4,4'-DDT ug/L ND 2.5 2.5 3.3 3.1 131 123 28-169 6 37 Aldrin ug/L ND 2.5 2.5 3.2 3.4 129 134 25-152 4 35 alpha-BHC ug/L ND 2.5 2.5 3.3 3.5 133 139 45-136 4 33 M1 beta-BHC ug/L ND 2.5 2.5 3.4 3.5 135 138 34-159 3 32 delta-BHC ug/L ND 2.5 2.5 3.1 3.1 122 123 32-138 1 34 Dieldrin ug/L ND 2.5 2.5 3.0 3.0 122 122 32-160 0 40 Endosulfan I ug/L ND 2.5 2.5 3.1 3.2 124 126 48-151 2 31 Endosulfan II ug/L ND 2.5 2.5 3.1 3.0 123 118 55-153 4 38 Endosulfan sulfate ug/L ND 2.5 2.5 2.8 2.6 111 103 52-138 8 38 Endrin ug/L ND 2.5 2.5 3.2 3.2 129 129 39-180 0 35 Endrin aldehyde ug/L ND 2.5 2.5 2.9 2.7 116 109 29-164 6 42 gamma-BHC (Lindane) ug/L ND 2.5 2.5 3.4 3.5 136 141 45-140 4 33 M1 Heptachlor ug/L ND 2.5 2.5 3.2 3.3 129 134 40-153 4 30 Heptachlor epoxide ug/L ND 2.5 2.5 3.0 3.1 121 124 46-144 2 33 Isodrin ug/L ND 2.5 2.5 3.0 3.1 121 125 10-184 3 36 Methoxychlor ug/L ND 2.5 2.5 2.9 2.7 117 106 10-208 10 43 Decachlorobiphenyl (S) %. 63 50 10-157 Tetrachloro-m-xylene (S) %. 109 113 19-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21610 Analysis Method: EPA 8082A QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB Associated Lab Samples: 2614221001 METHOD BLANK: 97312 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers PCB-1016 (Aroclor 1016) ug/L ND 0.50 0.19 02/01/19 23:47 PCB-1221 (Aroclor 1221) ug/L ND 0.50 0.50 02/01/19 23:47 PCB-1232 (Aroclor 1232) ug/L ND 0.50 0.50 02/01/19 23:47 PCB-1242 (Aroclor 1242) ug/L ND 0.50 0.50 02/01/19 23:47 PCB-1248 (Aroclor 1248) ug/L ND 0.50 0.50 02/01/19 23:47 PCB-1254 (Aroclor 1254) ug/L ND 0.50 0.50 02/01/19 23:47 PCB-1260 (Aroclor 1260) ug/L ND 0.50 0.23 02/01/19 23:47 Decachlorobiphenyl (S) %. 38 17-144 02/01/19 23:47 LABORATORY CONTROL SAMPLE: 97313 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers PCB-1016 (Aroclor 1016) ug/L 5 4.4 87 47-120 PCB-1260 (Aroclor 1260) ug/L 5 3.7 75 51-126 Decachlorobiphenyl (S) %. 49 17-144 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97314 97315 MS MSD 2614214024 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual PCB-1016 (Aroclor 1016) ug/L <0.19 5 5 4.7 4.6 94 92 10-183 2 18 PCB-1260 (Aroclor 1260) ug/L <0.23 5 5 4.2 4.3 85 86 19-141 1 27 Decachlorobiphenyl (S) %. 47 53 17-144 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21619 Analysis Method: EPA 8151A QC Batch Method: EPA8151A Analysis Description: 8151AGCS Herbicides Associated Lab Samples: 2614221001 METHOD BLANK: 97344 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 2,4,5-T ug/L ND 5.0 1.1 02/04/19 16:05 2,4,5-TP (Silvex) ug/L ND 10.0 1.0 02/04/19 16:05 2,4-D ug/L ND 5.0 1.6 02/04/19 16:05 Dinoseb ug/L ND 5.0 1.2 02/04/19 16:05 2,4-DCAA (S) %. 151 10-155 02/04/19 16:05 LABORATORY CONTROL SAMPLE: 97345 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 2,4,5-T ug/L 10 11.2 112 31-150 2,4,5-TP (Silvex) ug/L 10 11.1 111 35-138 2,4-D ug/L 10 12.2 122 29-145 Dinoseb ug/L 10 9.9 99 10-182 2,4-DCAA (S) %. 152 10-155 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97346 97347 MS MSD 2614219017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 2,4,5-T ug/L ND 10 10 9.2 10.8 92 108 10-158 16 48 2,4,5-TP (Silvex) ug/L ND 10 10 9.11 10.7 91 107 10-156 46 2,4-D ug/L ND 10 10 10.1 11.8 101 118 10-156 15 49 Dinoseb ug/L ND 10 10 8.8 4.2J 88 42 10-174 56 2,4-DCAA (S) %. 113 136 10-155 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21712 Analysis Method: EPA 8270D QC Batch Method: EPA 3510C Analysis Description: 8270D MSSV Extend Associated Lab Samples: 2614221001 METHOD BLANK: 97851 Associated Lab Samples: 2614221001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 1.7 02/11/19 20:17 1,2,4-Trichlorobenzene ug/L ND 10.0 2.0 02/11/19 20:17 1,2-Diphenylhydrazine ug/L ND 10.0 2.0 02/11/19 20:17 1,3,5-Trinitrobenzene ug/L ND 10.0 1.4 02/11/19 20:17 1,3-Dinitrobenzene ug/L ND 10.0 2.9 02/11/19 20:17 1,4-Naphthoquinone ug/L ND 50.0 3.7 02/11/19 20:17 1-Naphthalenamine ug/L ND 10.0 2.6 02/11/19 20:17 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 2.6 02/11/19 20:17 2,3,4,6-Tetrachlorophenol ug/L ND 20.0 3.2 02/11/19 20:17 2,4,5-Trichlorophenol ug/L ND 10.0 2.7 02/11/19 20:17 2,4,6-Trichlorophenol ug/L ND 10.0 2.2 02/11/19 20:17 2,4-Dichlorophenol ug/L ND 10.0 2.0 02/11/19 20:17 2,4-Dimethylphenol ug/L ND 10.0 4.4 02/11/19 20:17 2,4-Dinitrophenol ug/L ND 50.0 8.1 02/11/19 20:17 2,4-Dinitrotoluene ug/L ND 20.0 4.2 02/11/19 20:17 2,6-Dichlorophenol ug/L ND 10.0 5.1 02/11/19 20:17 2,6-Dinitrotoluene ug/L ND 20.0 2.5 02/11/19 20:17 2-Acetylaminofluorene ug/L ND 10.0 2.7 02/11/19 20:17 2-Chloronaphthalene ug/L ND 10.0 1.6 02/11/19 20:17 2-Chlorophenol ug/L ND 10.0 1.2 02/11/19 20:17 2-Methylnaphthalene ug/L ND 10.0 1.6 02/11/19 20:17 2-Methylphenol(o-Cresol) ug/L ND 10.0 2.0 02/11/19 20:17 2-Naphthalenamine ug/L ND 10.0 1.7 02/11/19 20:17 2-Nitroaniline ug/L ND 50.0 3.1 02/11/19 20:17 2-Nitrophenol ug/L ND 50.0 2.5 02/11/19 20:17 3&4-Methyl phenol (m&p Cresol) ug/L ND 10.0 2.0 02/11/19 20:17 3,3'-Dichlorobenzidine ug/L ND 20.0 5.5 02/11/19 20:17 3,3'-Dimethylbenzidine ug/L ND 50.0 2.3 02/11/19 20:17 3-Methylcholanthrene ug/L ND 50.0 1.6 02/11/19 20:17 3-Nitroaniline ug/L ND 50.0 3.3 02/11/19 20:17 4,6-Dinitro-2-methyl phenol ug/L ND 50.0 7.4 02/11/19 20:17 4-Aminobiphenyl ug/L ND 10.0 1.4 02/11/19 20:17 4-Bromophenylphenyl ether ug/L ND 10.0 2.5 02/11/19 20:17 4-ChIoro-3-methyl phenol ug/L ND 10.0 2.8 02/11/19 20:17 4-Chloroaniline ug/L ND 20.0 2.8 02/11/19 20:17 4-Chlorophenylphenyl ether ug/L ND 10.0 2.7 02/11/19 20:17 4-Nitroaniline ug/L ND 50.0 4.9 02/11/19 20:17 4-Nitrophenol ug/L ND 50.0 9.6 02/11/19 20:17 5-Nitro-o-toluidine ug/L ND 10.0 2.0 02/11/19 20:17 7,12-Dimethylbenz(a)anthracene ug/L ND 50.0 1.5 02/11/19 20:17 Acenaphthene ug/L ND 10.0 1.9 02/11/19 20:17 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 METHOD BLANK: 97851 Associated Lab Samples: 2614221001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Acenaphthylene ug/L ND 10.0 1.9 02/11/19 20:17 Acetophenone ug/L ND 10.0 3.3 02/11/19 20:17 Anthracene ug/L ND 10.0 2.7 02/11/19 20:17 Benzo(a)anthracene ug/L ND 10.0 4.2 02/11/19 20:17 Benzo(a)pyrene ug/L ND 10.0 3.7 02/11/19 20:17 Benzo(b)fluoranthene ug/L ND 10.0 4.1 02/11/19 20:17 Benzo(g,h,i)perylene ug/L ND 10.0 4.0 02/11/19 20:17 Benzo(k)fluoranthene ug/L ND 10.0 4.5 02/11/19 20:17 Benzyl alcohol ug/L ND 20.0 2.3 02/11/19 20:17 bis(2-Chloroethoxy)methane ug/L ND 10.0 1.6 02/11/19 20:17 bis(2-Chloroethyl) ether ug/L ND 10.0 1.4 02/11/19 20:17 bis(2-Ethylhexyl)phthalate ug/L ND 10.0 5.2 02/11/19 20:17 Butylbenzylphthalate ug/L ND 10.0 4.5 02/11/19 20:17 Chlorobenzilate ug/L ND 10.0 1.6 02/11/19 20:17 Chrysene ug/L ND 10.0 4.1 02/11/19 20:17 Di-n-butylphthalate ug/L ND 10.0 3.5 02/11/19 20:17 Di-n-octylphthalate ug/L ND 10.0 5.8 02/11/19 20:17 Diallate ug/L ND 50.0 2.5 02/11/19 20:17 Dibenz(a,h)anthracene ug/L ND 10.0 4.5 02/11/19 20:17 Dibenzofuran ug/L ND 10.0 2.1 02/11/19 20:17 Diethylphthalate ug/L ND 10.0 2.7 02/11/19 20:17 Dimethoate ug/L ND 50.0 1.4 02/11/19 20:17 Dimethylphthalate ug/L ND 10.0 2.0 02/11/19 20:17 Disulfoton ug/L ND 10.0 3.0 02/11/19 20:17 Ethyl methanesulfonate ug/L ND 50.0 3.4 02/11/19 20:17 Famphur ug/L ND 10.0 2.1 02/11/19 20:17 Fluoranthene ug/L ND 10.0 3.9 02/11/19 20:17 Fluorene ug/L ND 10.0 2.4 02/11/19 20:17 Hexachloro-1,3-butadiene ug/L ND 10.0 3.7 02/11/19 20:17 Hexachlorobenzene ug/L ND 10.0 2.7 02/11/19 20:17 Hexachlorocyclopentadiene ug/L ND 10.0 3.6 02/11/19 20:17 Hexachloroethane ug/L ND 10.0 2.4 02/11/19 20:17 Hexachloropropene ug/L ND 10.0 2.9 02/11/19 20:17 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 4.1 02/11/19 20:17 Isophorone ug/L ND 10.0 2.1 02/11/19 20:17 Isosafrole ug/L ND 50.0 4.0 02/11/19 20:17 Kepone ug/L ND 20.0 12.4 02/11/19 20:17 Methapyrilene ug/L ND 50.0 5.0 02/11/19 20:17 Methyl methanesulfonate ug/L ND 50.0 4.2 02/11/19 20:17 Methyl parathion ug/L ND 10.0 2.4 02/11/19 20:17 N-Nitroso-di-n-butylamine ug/L ND 10.0 4.5 02/11/19 20:17 N-Nitroso-di-n-propylamine ug/L ND 10.0 2.1 02/11/19 20:17 N-Nitrosodiethylamine ug/L ND 10.0 3.5 02/11/19 20:17 N-Nitrosodimethylamine ug/L ND 10.0 2.3 02/11/19 20:17 N-Nitrosodiphenylamine ug/L ND 10.0 2.3 02/11/19 20:17 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 METHOD BLANK: 97851 Associated Lab Samples: 2614221001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed N-Nitrosomethylethylamine ug/L ND 10.0 3.5 02/11/19 20:17 N-Nitrosopiperidine ug/L ND 10.0 3.7 02/11/19 20:17 N-Nitrosopyrrolidine ug/L ND 10.0 4.2 02/11/19 20:17 Naphthalene ug/L ND 10.0 1.3 02/11/19 20:17 Nitrobenzene ug/L ND 10.0 1.4 02/11/19 20:17 O,O,O-Triethylphosphorothioate ug/L ND 10.0 3.2 02/11/19 20:17 O-Toluidine ug/L ND 10.0 3.4 02/11/19 20:17 p-Phenylenediamine ug/L ND 50.0 9.1 02/11/19 20:17 Parathion (Ethyl parathion) ug/L ND 10.0 2.2 02/11/19 20:17 Pentachlorobenzene ug/L ND 10.0 3.3 02/11/19 20:17 Pentachloronitrobenzene ug/L ND 10.0 2.3 02/11/19 20:17 Pentachlorophenol ug/L ND 20.0 8.3 02/11/19 20:17 Phenacetin ug/L ND 10.0 1.4 02/11/19 20:17 Phenanthrene ug/L ND 10.0 2.5 02/11/19 20:17 Phenol ug/L ND 10.0 1.4 02/11/19 20:17 Phorate ug/L ND 10.0 2.0 02/11/19 20:17 Pronamide ug/L ND 50.0 1.3 02/11/19 20:17 Pyrene ug/L ND 10.0 3.4 02/11/19 20:17 Safrole ug/L ND 50.0 3.0 02/11/19 20:17 Thionazin ug/L ND 10.0 1.2 02/11/19 20:17 2,4,6-Tribromophenol (S) %. 63 10-148 02/11/19 20:17 2-Fluorobiphenyl (S) %. 52 12-129 02/11/19 20:17 2-Fluorophenol (S) %. 28 10-64 02/11/19 20:17 Nitrobenzene-d5 (S) %. 47 13-107 02/11/19 20:17 p-Terphenyl-d14 (S) %. 81 14-147 02/11/19 20:17 Phenol-d6 (S) %. 16 10-46 02/11/19 20:17 LABORATORY CONTROL SAMPLE: Parameter 97852 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4,5-Tetrachlorobenzene ug/L 80 53.8 67 52-96 1,2,4-Trichlorobenzene ug/L 80 46.0 58 20-123 1,2-Diphenylhydrazine ug/L 80 69.9 87 29-156 2,2'-Oxybis(1-chloropropane) ug/L 80 47.9 60 22-129 2,4,5-Trichlorophenol ug/L 80 66.1 83 42-149 2,4,6-Trichlorophenol ug/L 80 62.4 78 43-150 2,4-Dichlorophenol ug/L 80 53.5 67 41-117 2,4-Dimethylphenol ug/L 80 52.6 66 25-108 2,4-Dinitrophenol ug/L 80 61.6 77 35-160 2,4-Dinitrotoluene ug/L 80 70.3 88 43-162 2,6-Dinitrotoluene ug/L 80 67.9 85 46-145 2-Chloronaphthalene ug/L 80 56.5 71 37-135 2-Chlorophenol ug/L 80 46.6 58 37-104 2-Methylnaphthalene ug/L 80 53.2 66 36-114 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 LABORATORY CONTROL SAMPLE: Parameter 97852 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 2-Methylphenol(o-Cresol) ug/L 80 42.0 52 10-114 2-Nitroaniline ug/L 80 61.4 77 22-161 2-Nitrophenol ug/L 80 52.3 65 42-116 3&4-Methyl phenol (m&p Cresol) ug/L 80 40.0 50 10-110 3,3'-Dichlorobenzidine ug/L 80 69.8 87 34-148 3-Nitroaniline ug/L 80 70.2 88 37-156 4,6-Dinitro-2-methyl phenol ug/L 80 64.6 81 56-154 4-Bromophenylphenyl ether ug/L 80 68.4 85 48-153 4-Chloro-3-methylphenol ug/L 80 53.2 66 46-119 4-Chloroaniline ug/L 80 52.5 66 34-121 4-Chlorophenylphenyl ether ug/L 80 62.6 78 44-145 4-Nitroaniline ug/L 80 66.7 83 37-163 4-Nitrophenol ug/L 80 25.8J 32 15-45 Acenaphthene ug/L 80 59.9 75 37-138 Acenaphthylene ug/L 80 58.4 73 43-136 Anthracene ug/L 80 70.4 88 48-151 Benzo(a)anthracene ug/L 80 67.2 84 49-154 Benzo(a)pyrene ug/L 80 67.3 84 45-164 Benzo(b)fluoranthene ug/L 80 66.9 84 46-157 Benzo(g,h,i)perylene ug/L 80 68.5 86 50-161 Benzo(k)fluoranthene ug/L 80 64.4 80 48-158 Benzyl alcohol ug/L 80 41.4 52 21-124 bis(2-Chloroethoxy)methane ug/L 80 51.9 65 29-120 bis(2-Chloroethyl) ether ug/L 80 43.6 55 23-126 bis(2-Ethylhexyl)phthalate ug/L 80 56.6 71 40-156 Butylbenzylphthalate ug/L 80 62.3 78 40-163 Chrysene ug/L 80 65.7 82 49-155 Di-n-butylphthalate ug/L 80 69.6 87 48-160 Di-n-octylphthalate ug/L 80 53.1 66 65-144 Dibenz(a,h)anthracene ug/L 80 65.4 82 44-165 Dibenzofuran ug/L 80 60.7 76 45-135 Diethylphthalate ug/L 80 68.3 85 38-162 Dimethylphthalate ug/L 80 66.0 82 44-150 Fluoranthene ug/L 80 75.1 94 53-156 Fluorene ug/L 80 63.6 80 45-142 Hexachloro-1,3-butadiene ug/L 80 42.7 53 27-92 Hexachlorobenzene ug/L 80 71.4 89 50-149 Hexachlorocyclopentadiene ug/L 80 43.1 54 23-123 Hexachloroethane ug/L 80 39.0 49 19-91 Indeno(1,2,3-cd)pyrene ug/L 80 66.2 83 43-171 Isophorone ug/L 80 50.6 63 18-137 N-Nitroso-di-n-propylamine ug/L 80 49.2 61 12-148 N-Nitrosodimethylamine ug/L 80 29.4 37 12-83 N-Nitrosodiphenylamine ug/L 80 68.1 85 50-130 Naphthalene ug/L 80 49.4 62 35-106 Nitrobenzene ug/L 80 47.0 59 22-115 Pentachlorophenol ug/L 80 63.8 80 42-127 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 LABORATORY CONTROL SAMPLE: 97852 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phenanthrene ug/L 80 68.6 86 49-146 Phenol ug/L 80 18.7 23 18-48 Pyrene ug/L 80 63.1 79 50-146 2,4,6-Tribromophenol (S) %. 94 10-148 2-Fluorobiphenyl (S) %. 68 12-129 2-Fluorophenol (S) %. 34 10-64 Nitrobenzene-d5 (S) %. 55 13-107 p-Terphenyl-d14 (S) %. 83 14-147 Phenol-d6 (S) %. 21 10-46 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97853 97854 MS MSD 2614353007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2,4,5-Tetrachlorobenzene ug/L ND 80 80 43.5 54.1 54 68 52-96 22 33 1,2,4-Trichlorobenzene ug/L ND 80 80 38.3 46.7 48 58 10-127 20 48 1,2-Diphenylhydrazine ug/L ND 80 80 49.8 59.2 62 74 29-156 17 23 2,2'-Oxybis(1-chloropropane) ug/L ND 80 80 40.0 48.9 50 61 22-129 20 29 2,4,5-Trichlorophenol ug/L ND 80 80 50.1 63.9 63 80 42-149 24 26 2,4,6-Trichlorophenol ug/L ND 80 80 50.3 63.3 63 79 43-150 23 27 2,4-Dichlorophenol ug/L ND 80 80 46.0 55.2 58 69 41-117 18 2 R1 2,4-Dimethylphenol ug/L ND 80 80 41.3 49.1 52 61 25-108 17 33 2,4-Dinitrophenol ug/L ND 80 80 50.9 69.0 64 86 35-160 30 20 R1 2,4-Dinitrotoluene ug/L ND 80 80 50.1 69.0 63 86 43-162 32 26 R1 2,6-Dinitrotoluene ug/L ND 80 80 49.5 64.3 62 80 60-125 26 27 2-Chloronaphthalene ug/L ND 80 80 43.8 54.6 55 68 37-135 22 24 2-Chlorophenol ug/L ND 80 80 39.9 46.2 50 58 33-98 15 37 2-Methyl naphthalene ug/L ND 80 80 44.6 54.6 56 68 36-114 20 25 2-Methyl phenol(o-Cresol) ug/L ND 80 80 36.7 42.6 46 53 10-114 15 30 2-Nitroaniline ug/L ND 80 80 46AJ 58.5 58 73 22-161 22 2-Nitrophenol ug/L ND 80 80 45.OJ 53.4 56 67 42-116 31 3&4-Methylphenol(m&p ug/L ND 80 80 33.0 43.8 41 55 10-110 28 33 Cresol) 3,3'-Dichlorobenzidine ug/L ND 80 80 27.8 33.6 35 42 34-148 19 23 3-Nitroaniline ug/L ND 80 80 51.4 63.6 64 79 37-156 21 21 4,6-Dinitro-2-methylphenol ug/L ND 80 80 48AJ 61.8 61 77 56-154 22 4-Bromophenylphenyl ether ug/L ND 80 80 50.7 63.0 63 79 48-153 22 21 R1 4-Chloro-3-methylphenol ug/L ND 80 80 43.4 55.3 54 69 44-118 24 26 4-Chloroaniline ug/L ND 80 80 43.0 48.7 54 61 34-121 12 34 4-Chlorophenylphenyl ether ug/L ND 80 80 47.2 62.1 59 78 44-145 27 22 R1 4-Nitroaniline ug/L ND 80 80 46.OJ 62.8 57 79 37-163 24 4-Nitrophenol ug/L ND 80 80 21AJ 27.5J 27 34 10-54 37 Acenaphthene ug/L ND 80 80 46.1 58.4 58 73 40-124 24 29 Acenaphthylene ug/L ND 80 80 46.1 56.5 58 71 43-136 20 22 Anthracene ug/L ND 80 80 51.0 63.6 64 80 48-151 22 22 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97853 97854 MS MSD 2614353007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Benzo(a)anth race ne ug/L ND 80 80 49.3 65.8 62 82 49-154 29 22 R1 Benzo(a)pyrene ug/L ND 80 80 48.1 63.8 60 80 45-164 28 24 R1 Benzo(b)fluoranthene ug/L ND 80 80 49.6 61.2 62 77 46-157 21 23 Benzo(g,h,i)perylene ug/L ND 80 80 48.8 69.4 61 87 50-161 35 25 R1 Benzo(k)fluoranthene ug/L ND 80 80 52.0 66.0 65 82 48-158 24 24 Benzyl alcohol ug/L ND 80 80 35.5 28.4 44 36 21-124 22 27 bis(2-Chloroethoxy)methane ug/L ND 80 80 43.0 51.2 54 64 29-120 17 29 bis(2-Chloroethyl) ether ug/L ND 80 80 36.4 41.6 46 52 23-126 13 31 bis(2- Ethyl hexyl)phthalate ug/L ND 80 80 43.5 60.7 54 76 40-156 33 23 R1 Butylbenzylphthalate ug/L ND 80 80 47.1 68.9 59 86 40-163 38 19 R1 Chrysene ug/L ND 80 80 49.5 67.3 62 84 49-155 30 21 R1 Di-n-butylphthalate ug/L ND 80 80 52.3 67.9 65 85 40-163 26 27 Di-n-octylphthalate ug/L ND 80 80 43.9 56.3 55 70 65-144 25 21 M1,R1 Dibenz(a,h)anthracene ug/L ND 80 80 47.4 65.6 59 82 44-165 32 26 R1 Dibenzofuran ug/L ND 80 80 47.2 59.1 59 74 45-135 22 24 Diethylphthalate ug/L ND 80 80 49.4 66.0 62 82 38-162 29 21 R1 Dimethylphthalate ug/L ND 80 80 50.1 66.0 63 82 44-150 27 22 R1 Fluoranthene ug/L ND 80 80 55.2 68.4 69 86 53-156 21 25 Fluorene ug/L ND 80 80 47.0 61.3 59 77 45-142 26 21 R1 Hexachloro-1,3-butadiene ug/L ND 80 80 34.1 39.5 43 49 27-92 15 30 Hexachlorobenzene ug/L ND 80 80 52.8 65.4 66 82 50-149 21 23 Hexachlorocyclopentadiene ug/L ND 80 80 39.4 46.1 49 58 23-123 16 32 Hexachloroethane ug/L ND 80 80 32.8 39.6 41 49 19-91 19 33 Indeno(1,2,3-cd)pyrene ug/L ND 80 80 48.5 67.4 61 84 43-171 33 26 R1 Isophorone ug/L ND 80 80 42.7 54.8 53 68 18-137 25 24 R1 N-Nitroso-di-n-propylamine ug/L ND 80 80 40.4 53.5 51 67 39-106 28 34 N-Nitrosodimethylamine ug/L ND 80 80 25.7 27.7 32 35 12-83 8 28 N-Nitrosodiphenylamine ug/L ND 80 80 46.2 53.8 58 67 50-130 15 28 Naphthalene ug/L ND 80 80 41.3 48.3 52 60 35-106 16 28 Nitrobenzene ug/L ND 80 80 42.2 47.8 53 60 22-115 12 27 Pentachlorophenol ug/L ND 80 80 50.6 63.1 63 79 40-136 22 27 Phenanthrene ug/L ND 80 80 51.6 63.9 64 80 49-146 21 21 Phenol ug/L ND 80 80 18.3 19.5 23 24 20-42 7 36 Pyrene ug/L ND 80 80 46.4 63.3 58 79 52-131 31 27 R1 2,4,6-Tribromophenol (S) %. 71 89 10-148 2-Fluorobiphenyl (S) %. 53 66 12-129 2-Fluorophenol (S) %. 26 29 10-64 Nitrobenzene-d5 (S) %. 46 55 13-107 p-Terphenyl-d14 (S) %. 40 48 14-147 Phenol-d6 (S) %. 17 20 10-46 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21787 Analysis Method: EPA 9014 Cyanide QC Batch Method: EPA 9010C Analysis Description: 9014 Cyanide Associated Lab Samples: 2614221001 METHOD BLANK: 98045 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cyanide mg/L ND 0.010 0.010 02/05/1913:59 LABORATORY CONTROL SAMPLE: 98046 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cyanide mg/L 0.08 0.078 98 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 98047 98048 MS MSD 2614268020 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cyanide mg/L ND 0.08 0.08 0.083 0.080 99 96 85-119 3 13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614221 QC Batch: 21630 Analysis Method: EPA 9034 QC Batch Method: EPA 9030A Analysis Description: 9034 Sulfide Waste Water Associated Lab Samples: 2614221001 METHOD BLANK: 97451 Matrix: Water Associated Lab Samples: 2614221001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide mg/L ND 1.0 1.0 02/01/1917:06 LABORATORY CONTROL SAMPLE: 97452 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide mg/L 4 2.9 72 40-104 MATRIX SPIKE SAMPLE: 97463 2614353007 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfide mg/L ND 4 3.5 80 10-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Foothills LF NC-1403 Pace Project No.: 2614221 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/13/2019 02:20 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 38 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF NC-1403 2614221 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2614221001 1403-MW-2R EPA 8011 21707 EPA 8011 21766 2614221002 1403-Trip Blank EPA 8011 21707 EPA 8011 21766 2614221001 1403-MW-2R EPA 3510C 21609 EPA 8081 B 21853 2614221001 1403-MW-2R EPA 3510C 21610 EPA 8082A 21684 2614221001 1403-MW-2R EPA 8151A 21619 EPA 8151A 21762 2614221001 1403-MW-2R EPA 3005A 21711 EPA 6020B 21754 2614221001 1403-MW-2R EPA 7470A 21462 EPA 7470A 21491 2614221001 1403-MW-2R EPA 3510C 21712 EPA 8270D 22229 2614221001 1403-MW-2R EPA 8260B Mod. 455695 2614221001 1403-MW-2R EPA 8260B 22128 2614221002 1403-Trip Blank EPA 8260B 22128 2614221001 1403-MW-2R EPA 9010C 21787 EPA 9014 Cyanide 21807 2614221001 1403-MW-2R EPA 9030A 21630 EPA 9034 21649 Date: 02/13/2019 02:20 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 38 W Q a N O Co M 0 co w E Z c0i w . 0.0 U c� W w H x U .. W p a N Q ch U > � — Y o (D QC U XX a) } Q cn o 04 Q w I- 0 0 O W } O ca LL Z Q U U c vi U N U U ci ZD c VM Z O Oo avio'o VIN O x0z00 W L oo 50 Q Z xx zz Ix O�x w w . . . o z w N M CO 1� o O U) 0 Q J n. Q a U x w W- w z O cm En3 ww� W Q Q w F G N - W U' 3. Ix V O Q W O _j ix W > W Z�OU W Z Q g Z��LLQ' W Y a' zg2� - �a°x�°a L� Q a QU >cn0 o�(9USU) w N 0 a ¢C9>cn0 3: 3: 3:3 — [] -+a m —G Zm22mww —♦ r- N 3 �08 - S3111VIOA - II'dd`d X X —` 1 � � � > WIS 09Z8 AS 3NVXOIa-b' 6 X w J O Q Z8094808 80d - II 'ddV Xcl N Q Z80949081S3d - II 'dd`d X w af O d Q ~ , X - U $ a to 34131f1S - II 'ddV X o U � a 3GINVAO - II 'ddV X D > Z a co SIVi3W - II'ddV X m l co > 09Z8 - S31liVIOA - II'ddV X X w w x 5 5 w Cm 00 (0 w z w o- ¢a te ff of of fn O U 5 U Z p et z O N Y Z W U. O Q U LL m Z z CW.) O 9 1 , F— V a o W to # U) _ a U 0 a o —o F- ,- o m O � c�am X X a am Z Z U O M a. LLJ 20 w coH J - M ti z > ~ O w 1/i O a w W z a oZ ...� d `� � O a vi , j a a F LL ' �w �' all Co z di w U J ¢ O z Q O w _ a 0 Co L CO 0 co O Z i- of w W w (`( ' w U > Y W w w o w 0 U P H r : - t WO# : 2614221 Sample Condition Upon Receipt. Client Name: �� �i PM: BM Due Date: 02/12/19 Courier: Fed Ex ❑ UPS ❑ US S ❑ Client []Commercial ❑ Pace Other CLIENT: Republic —NC Tracking #: Custod Seal on ool r/Box Presentyes no Seals intact: Y Packing Material: ❑ Bubble Wr/a[ ubble Bags ❑ None ❑ Other Tharmnmater Used 11 /�- Tvae of Ice: �Q Blue Elyes ❑ no r �- None ❑ SamDles on ice. cooling process has begun n l Biological Tissue is Frozen: Yes No Date and Initi f r� exami g Cooler Temperature l V contents: Temp should be above freezing to 6°C Comments: Chain of Custody Present: es ❑No ❑N/A 1. Chain of Custody Filled Out: Yes ONO ❑N/A 2. Chain of Custody Relinquished: es ❑No ❑N/A 3. Sampler Name & Signature on COC: es No ❑N/A 4. Samples Arrived within Hold Time: es ❑No ❑N/A 5. Short Hold Time Analysis <72hr : Gres o N/A 6. Rush Turn Around Time Requested: Dyes 917NO ❑N/A 7. Sufficient Volume: Yes ❑No ❑N/A g, Correct Containers Used: q<s ONO ❑N/A 9. -Pace Containers Used: Yes ❑No ❑N/A Containers Intact: es ❑No ❑N/A 10. Filtered volume received for Dissolved tests 0 le, o ❑N/A 11. Sample Labels match COC: es ❑ o ❑N/A 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. es ONO ❑N/A 13. All containers needing preservation are found to be in QJYes ONO ❑N/A compliance with EPA recommendation. Initial when Lot # of added exceptions: A oliforrn, TOC, O&G, WI-DRO (water) Yes ONO completed preservative Samples checked for dechlorination: ❑Yes ❑No N/A 14. Heads ace in VOA Vials >6mm : ❑Yes No ❑N/A 15. Trip Blank Present: Ye No ❑N/A 16. Trip Blank Custody Seals Present Yes ❑No ❑N/A Pace Trip Blank Lot # if purchased): Client Notification/ Resolution: Field Data Required? Y / N Person Contacted: Date/Time: Comments/ Resolution: Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) F-ALLC003rev.3, 11 Septembp8 of 38 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 February 15, 2019 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF NC-1403 Pace Project No.: 2614220 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on January 29, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 CERTIFICATIONS Project: Foothills LF NC-1403 Pace Project No.: 2614220 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification #: E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 Virginia Certification #: 460204 Georgia DW Microbiology Certification #: 812 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Foothills LF NC-1403 Pace Project No.: 2614220 Lab ID Sample ID Matrix Date Collected Date Received 2614220001 1403 Leachate Water 01/28/19 15:08 01/29/19 10:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Foothills LF NC-1403 Pace Project No.: 2614220 Lab ID Sample ID Method Analysts Analytes Reported 2614220001 1403 Leachate EPA 6020E KLH 15 EPA 8260E LI H 50 EPA410.4 RNB 1 SM 4500-P MWB 1 SM 5210B RNB 1 EPA 300.0 RLC 3 EPA 300.0 RLC 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614220 Sample: 1403 Leachate Lab ID: 2614220001 Collected: 01/28/19 15:08 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 02/15/2019 07:34 AM Analytical Method: EPA 6020E Preparation Method: EPA 3005A 99.7 ug/L 6.0 0.78 1 02/04/19 13:33 02/04/19 21:02 7440-36-0 90.8 ug/L 10.0 0.57 1 02/04/19 13:33 02/04/19 21:02 7440-38-2 381 ug/L 100 0.78 1 02/04/19 13:33 02/04/19 21:02 7440-39-3 0.085J ug/L 1.0 0.050 1 02/04/19 13:33 02/04/19 21:02 7440-41-7 ND ug/L 1.0 0.093 1 02/04/19 13:33 02/04/19 21:02 7440-43-9 124 ug/L 10.0 1.6 1 02/04/19 13:33 02/04/19 21:02 7440-47-3 23.0 ug/L 10.0 0.52 1 02/04/19 13:33 02/04/19 21:02 7440-48-4 537 ug/L 10.0 1.3 1 02/04/19 13:33 02/04/19 21:02 7440-50-8 5.2J ug/L 10.0 0.27 1 02/04/19 13:33 02/04/19 21:02 7439-92-1 116 ug/L 50.0 0.95 1 02/04/19 13:33 02/04/19 21:02 7440-02-0 2.8J ug/L 10.0 1.4 1 02/04/19 13:33 02/04/19 21:02 7782-49-2 ND ug/L 10.0 0.95 1 02/04/19 13:33 02/04/19 21:02 7440-22-4 ND ug/L 5.5 0.14 1 02/04/19 13:33 02/04/19 21:02 7440-28-0 37.4 ug/L 25.0 1.9 1 02/04/19 13:33 02/04/19 21:02 7440-62-2 240 ug/L 10.0 2.1 1 02/04/19 13:33 02/04/19 21:02 7440-66-6 Analytical Method: EPA 8260E 14300 ug/L 5000 410 50 02/01/19 11:50 67-64-1 ND ug/L 4000 50.0 20 02/01/19 03:03 107-13-1 ND ug/L 20.0 4.0 20 02/01/19 03:03 71-43-2 ND ug/L 60.0 10.0 20 02/01/19 03:03 74-97-5 ND ug/L 20.0 7.2 20 02/01/19 03:03 75-27-4 ND ug/L 60.0 11.0 20 02/01/19 03:03 75-25-2 ND ug/L 200 19.0 20 02/01/19 03:03 74-83-9 4640 ug/L 2000 64.0 20 02/01/19 03:03 78-93-3 ND ug/L 2000 15.8 20 02/01/19 03:03 75-15-0 ND ug/L 20.0 8.4 20 02/01/19 03:03 56-23-5 ND ug/L 60.0 10.6 20 02/01/19 03:03 108-90-7 ND ug/L 200 10.4 20 02/01/19 03:03 75-00-3 ND ug/L 100 11.6 20 02/01/19 03:03 67-66-3 ND ug/L 20.0 7.6 20 02/01/19 03:03 74-87-3 ND ug/L 260 11.0 20 02/01/19 03:03 96-12-8 ND ug/L 60.0 6.2 20 02/01/19 03:03 124-48-1 ND ug/L 40.0 5.6 20 02/01/19 03:03 106-93-4 ND ug/L 200 12.4 20 02/01/19 03:03 74-95-3 ND ug/L 100 9.8 20 02/01/19 03:03 95-50-1 ND ug/L 20.0 11.6 20 02/01/19 03:03 106-46-7 ND ug/L 2000 32.0 20 02/01/19 03:03 110-57-6 ND ug/L 100 8.2 20 02/01/19 03:03 75-34-3 ND ug/L 20.0 13.4 20 02/01/19 03:03 107-06-2 ND ug/L 100 14.4 20 02/01/19 03:03 75-35-4 ND ug/L 100 13.2 20 02/01/19 03:03 156-59-2 ND ug/L 100 9.2 20 02/01/19 03:03 156-60-5 ND ug/L 20.0 12.0 20 02/01/19 03:03 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF NC-1403 Pace Project No.: 2614220 Sample: 1403 Leachate Lab ID: 2614220001 Collected: 01/28/19 15:08 Received: 01/29/19 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 410.4 COD Chemical Oxygen Demand 450OPE Total Phosphorus Phosphorus 5210B BOD, 5 day BOD, 5 day 300.0 IC Anions Nitrite as N Nitrate as N Nitrogen, NO2 plus NO3 300.0 IC Anions 28 Days Sulfate Date: 02/15/2019 07:34 AM Analytical Method: EPA 8260E ND ug/L 20.0 4.4 20 02/01/19 03:03 10061-01-5 ND ug/L 20.0 6.0 20 02/01/19 03:03 10061-02-6 31.8 ug/L 20.0 9.0 20 02/01/19 03:03 100-41-4 ND ug/L 1000 17.8 20 02/01/19 03:03 591-78-6 ND ug/L 200 62.0 20 02/01/19 03:03 74-88-4 22.3 ug/L 20.0 10.0 20 02/01/19 03:03 75-09-2 ND ug/L 2000 17.2 20 02/01/19 03:03 108-10-1 ND ug/L 20.0 10.0 20 02/01/19 03:03 100-42-5 ND ug/L 100 6.4 20 02/01/19 03:03 630-20-6 ND ug/L 60.0 10.6 20 02/01/19 03:03 79-34-5 ND ug/L 20.0 15.6 20 02/01/19 03:03 127-18-4 36.5 ug/L 20.0 6.2 20 02/01/19 03:03 108-88-3 ND ug/L 20.0 7.6 20 02/01/19 03:03 71-55-6 ND ug/L 20.0 11.8 20 02/01/19 03:03 79-00-5 ND ug/L 20.0 6.8 20 02/01/19 03:03 79-01-6 ND ug/L 20.0 9.2 20 02/01/19 03:03 96-18-4 ND ug/L 1000 8.4 20 02/01/19 03:03 108-05-4 ND ug/L 20.0 12.0 20 02/01/19 03:03 75-01-4 42.5J ug/L 100 29.2 20 02/01/19 03:03 1330-20-7 108 %. 81-119 20 02/01/19 03:03 17060-07-0 107 %. 82-114 20 02/01/19 03:03 1868-53-7 104 %. 82-120 20 02/01/19 03:03 460-00-4 95 %. 82-109 20 02/01/19 03:03 2037-26-5 Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 1870000 ug/L 100000 100000 1 02/12/1918:30 02/13/1910:59 Analytical Method: SM 4500-P Preparation Method: SM 4500-P 3390 ug/L 2000 2000 10 02/05/1911:20 02/05/1919:34 7723-14-0 Analytical Method: SM 5210B Preparation Method: SM 5210B 831000 ug/L 537000 537000 300 01/30/19 09:00 02/04/19 13:04 1A Analytical Method: EPA 300.0 ND ug/L 50.0 11.0 1 01/29/1917:10 14797-65-0 M1 176 ug/L 50.0 5.0 1 01/29/1917:10 14797-55-8 176 ug/L 50.0 12.0 1 01/29/1917:10 M1 Analytical Method: EPA 300.0 4510J ug/L 5000 17.0 1 01/29/1917:10 14808-79-8 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21711 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2614220001 METHOD BLANK: 97845 Associated Lab Samples: 2614220001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L 0.89J 6.0 0.78 02/04/1919:54 Arsenic ug/L ND 10.0 0.57 02/04/1919:54 Barium ug/L ND 100 0.78 02/04/1919:54 Beryllium ug/L ND 1.0 0.050 02/04/1919:54 Cadmium ug/L ND 1.0 0.093 02/04/1919:54 Chromium ug/L ND 10.0 1.6 02/04/1919:54 Cobalt ug/L ND 10.0 0.52 02/04/1919:54 Copper ug/L ND 10.0 1.3 02/04/1919:54 Lead ug/L ND 10.0 0.27 02/04/1919:54 Nickel ug/L ND 50.0 0.95 02/04/1919:54 Selenium ug/L ND 10.0 1.4 02/04/1919:54 Silver ug/L ND 10.0 0.95 02/04/1919:54 Thallium ug/L ND 5.5 0.14 02/04/1919:54 Vanadium ug/L ND 25.0 1.9 02/04/1919:54 Zinc ug/L ND 10.0 2.1 02/04/1919:54 LABORATORY CONTROL SAMPLE: 97846 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 110 110 80-120 Arsenic ug/L 100 95.0 95 80-120 Barium ug/L 100 99.91 100 80-120 Beryllium ug/L 100 98.5 98 80-120 Cadmium ug/L 100 96.8 97 80-120 Chromium ug/L 100 102 102 80-120 Cobalt ug/L 100 97.8 98 80-120 Copper ug/L 100 98.5 98 80-120 Lead ug/L 100 95.1 95 80-120 Nickel ug/L 100 96.9 97 80-120 Selenium ug/L 100 97.2 97 80-120 Silver ug/L 100 102 102 80-120 Thallium ug/L 100 95.2 95 80-120 Vanadium ug/L 100 101 101 80-120 Zinc ug/L 100 98.2 98 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 97849 97850 MS MSD 2614222005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 106 112 106 112 75-125 5 20 Arsenic ug/L 1.7J 100 100 94.1 95.2 92 93 75-125 1 20 Barium ug/L 119 100 100 202 209 83 91 75-125 4 20 Beryllium ug/L 0.071J 100 100 95.1 101 95 101 75-125 6 20 Cadmium ug/L ND 100 100 94.4 100 94 100 75-125 6 20 Chromium ug/L ND 100 100 107 103 106 102 75-125 4 20 Cobalt ug/L ND 100 100 99.5 99.0 99 99 75-125 0 20 Copper ug/L ND 100 100 99.6 98.3 99 98 75-125 1 20 Lead ug/L ND 100 100 95.9 98.3 96 98 75-125 3 20 Nickel ug/L ND 100 100 99.3 99.2 99 99 75-125 0 20 Selenium ug/L 20.4 100 100 92.1 99.5 72 79 75-125 8 20 M1 Silver ug/L ND 100 100 99.7 102 100 102 75-125 2 20 Thallium ug/L ND 100 100 96.2 97.7 96 98 75-125 2 20 Vanadium ug/L 2.6J 100 100 109 107 106 104 75-125 2 20 Zinc ug/L ND 100 100 96.6 101 96 100 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21547 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2614220001 METHOD BLANK: 96987 Associated Lab Samples: 2614220001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 01/31/19 18:33 1,1,1-Trichloroethane ug/L ND 1.0 0.38 01/31/19 18:33 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 01/31/19 18:33 1,1,2-Trichloroethane ug/L ND 1.0 0.59 01/31/19 18:33 1,1-Dichloroethane ug/L ND 5.0 0.41 01/31/19 18:33 1,1-Dichloroethene ug/L ND 5.0 0.72 01/31/19 18:33 1,2,3-Trichloropropane ug/L ND 1.0 0.46 01/31/19 18:33 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 01/31/19 18:33 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 01/31/19 18:33 1,2-Dichlorobenzene ug/L ND 5.0 0.49 01/31/19 18:33 1,2-Dichloroethane ug/L ND 1.0 0.67 01/31/19 18:33 1,2-Dichloropropane ug/L ND 1.0 0.60 01/31/19 18:33 1,4-Dichlorobenzene ug/L ND 1.0 0.58 01/31/19 18:33 2-Butanone (MEK) ug/L ND 100 3.2 01/31/19 18:33 2-Hexanone ug/L ND 50.0 0.89 01/31/19 18:33 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 01/31/19 18:33 Acetone ug/L ND 100 8.2 01/31/19 18:33 Acrylonitrile ug/L ND 200 2.5 01/31/19 18:33 Benzene ug/L ND 1.0 0.20 01/31/19 18:33 Bromochloromethane ug/L ND 3.0 0.50 01/31/19 18:33 Bromodichloromethane ug/L ND 1.0 0.36 01/31/19 18:33 Bromoform ug/L ND 3.0 0.55 01/31/19 18:33 Bromomethane ug/L ND 10.0 0.95 01/31/19 18:33 Carbon disulfide ug/L ND 100 0.79 01/31/19 18:33 Carbon tetrachloride ug/L ND 1.0 0.42 01/31/19 18:33 Chlorobenzene ug/L ND 3.0 0.53 01/31/19 18:33 Chloroethane ug/L ND 10.0 0.52 01/31/19 18:33 Chloroform ug/L ND 5.0 0.58 01/31/19 18:33 Chloromethane ug/L ND 1.0 0.38 01/31/19 18:33 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 01/31/19 18:33 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 01/31/19 18:33 Dibromochloromethane ug/L ND 3.0 0.31 01/31/19 18:33 Dibromomethane ug/L ND 10.0 0.62 01/31/19 18:33 Ethylbenzene ug/L ND 1.0 0.45 01/31/19 18:33 lodomethane ug/L ND 10.0 3.1 01/31/19 18:33 Methylene Chloride ug/L ND 1.0 0.50 01/31/19 18:33 Styrene ug/L ND 1.0 0.50 01/31/19 18:33 Tetrachloroethene ug/L ND 1.0 0.78 01/31/19 18:33 Toluene ug/L ND 1.0 0.31 01/31/19 18:33 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 01/31/19 18:33 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 01/31/19 18:33 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 METHOD BLANK: 96987 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) %. 107 81-119 4-Bromofluorobenzene (S) %. 105 82-120 Dibromofluoromethane (S) %. 106 82-114 Toluene-d8 (S) %. 95 82-109 Analyzed 1.6 01/31/19 18:33 0.34 01/31/19 18:33 0.42 01/31/19 18:33 0.60 01/31/19 18:33 1.5 01/31/19 18:33 01/31/19 18:33 01/31/19 18:33 01/31/19 18:33 01/31/19 18:33 LABORATORY CONTROL SAMPLE: Parameter 96988 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 45.5 91 68-137 1,1,1-Trichloroethane ug/L 50 51.6 103 72-134 1,1,2,2-Tetrachloroethane ug/L 50 49.7 99 51-158 1,1,2-Trichloroethane ug/L 50 52.8 106 78-131 1,1-Dichloroethane ug/L 50 55.3 111 69-151 1,1-Dichloroethene ug/L 50 58.0 116 64-158 1,2,3-Trichloropropane ug/L 50 44.9 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 49.0 98 58-124 1,2-Dibromoethane (EDB) ug/L 50 47.0 94 71-134 1,2-Dichlorobenzene ug/L 50 45.6 91 70-135 1,2-Dichloroethane ug/L 50 61.2 122 72-129 1,2-Dichloropropane ug/L 50 51.5 103 64-135 1,4-Dichlorobenzene ug/L 50 44.5 89 70-131 2-Butanone (MEK) ug/L 100 93AJ 93 52-143 2-Hexanone ug/L 100 93.4 93 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 85.1J 85 71-129 Acetone ug/L 100 96AJ 96 48-224 Acrylonitrile ug/L 200 274 137 66-154 Benzene ug/L 50 55.7 111 68-132 Bromochloromethane ug/L 50 50.1 100 73-133 Bromodichloromethane ug/L 50 46.4 93 67-121 Bromoform ug/L 50 42.5 85 57-125 Bromomethane ug/L 50 39.7 79 35-156 Carbon disulfide ug/L 100 118 118 47-141 Carbon tetrachloride ug/L 50 55.3 111 66-122 Chlorobenzene ug/L 50 47.2 94 71-126 Chloroethane ug/L 50 49.6 99 43-143 Chloroform ug/L 50 50.3 101 71-136 Chloromethane ug/L 50 39.4 79 47-123 cis-1,2-Dichloroethene ug/L 50 55.8 112 74-131 cis-1,3-Dichloropropene ug/L 50 46.4 93 78-120 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 LABORATORY CONTROL SAMPLE: 96988 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 46.2 92 65-115 Dibromomethane ug/L 50 48.8 98 79-129 Ethylbenzene ug/L 50 47.7 95 68-129 lodomethane ug/L 100 96.4 96 49-154 Methylene Chloride ug/L 50 54.1 108 61-147 Styrene ug/L 50 45.0 90 77-128 Tetrachloroethene ug/L 50 45.0 90 51-139 Toluene ug/L 50 50.3 101 60-133 trans-1,2-Dichloroethene ug/L 50 60.9 122 69-144 trans- 1,3-Dichloropropene ug/L 50 46.1 92 74-128 trans-1,4-Dichloro-2-butene ug/L 100 71.5J 71 61-139 Trichloroethene ug/L 50 44.4 89 73-126 Vinyl acetate ug/L 50 52.0 104 52-141 Vinyl chloride ug/L 50 46.7 93 50-133 Xylene (Total) ug/L 150 149 99 78-132 1,2-Dichloroethane-d4 (S) %. 113 81-119 4-Bromofluorobenzene (S) %. 96 82-120 Dibromofluoromethane (S) %. 114 82-114 Toluene-d8 (S) %. 91 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 96989 96990 MS MSD 2614048004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 44.9 42.6 90 85 68-137 5 11 1,1,1-Trichloroethane ug/L ND 50 50 54.4 52.9 109 106 66-142 3 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 49.2 46.8 98 94 39-171 5 13 1,1,2-Trichloroethane ug/L ND 50 50 55.9 49.0 112 98 73-136 13 12 R1 1,1-Dichloroethane ug/L ND 50 50 60.4 58.2 121 116 66-155 4 15 1,1-Dichloroethene ug/L ND 50 50 65.8 64.1 132 128 33-181 3 34 1,2,3-Trichloropropane ug/L ND 50 50 39.2 39.5 78 79 78-133 1 14 1,2-Dibromo-3- ug/L ND 50 50 42.9 41.8 86 84 58-124 3 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 48.6 45.8 97 92 71-134 6 12 1,2-Dichlorobenzene ug/L ND 50 50 48.4 45.8 97 92 69-135 5 10 1,2-Dichloroethane ug/L ND 50 50 61.1 56.4 122 113 36-159 8 10 1,2-Dichloropropane ug/L ND 50 50 56.0 50.8 112 102 68-132 10 11 1,4-Dichlorobenzene ug/L ND 50 50 44.3 44.3 89 89 49-153 0 9 2-Butanone (MEK) ug/L ND 100 100 80.9J 78.3J 81 78 10-189 3 23 2-Hexanone ug/L ND 100 100 80.3 77.1 80 77 40-135 4 18 4-Methyl-2-pentanone ug/L ND 100 100 85.5J 79AJ 86 79 30-177 7 10 (MIBK) Acetone ug/L ND 100 100 95.5J 87.7J 95 88 44-223 8 14 Acrylonitrile ug/L ND 200 200 209 238 104 119 13-189 13 12 R1 Benzene ug/L ND 50 50 57.4 54.3 115 109 66-139 6 10 Bromochloromethane ug/L ND 50 50 48.4 48.1 97 96 73-133 1 13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 96989 96990 MS MSD 2614048004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromodichloromethane ug/L ND 50 50 51.9 46.0 104 92 57-120 12 13 Bromoform ug/L ND 50 50 41.9 42.0 84 84 48-128 0 13 Bromomethane ug/L ND 50 50 40.8 44.0 82 88 10-187 7 32 Carbon disulfide ug/L ND 100 100 137 127 137 127 47-141 7 322 Carbon tetrachloride ug/L ND 50 50 61.1 59.5 122 119 58-127 3 14 Chlorobenzene ug/L ND 50 50 51.2 46.3 102 93 63-137 10 10 Chloroethane ug/L ND 50 50 54.4 52.0 109 104 52-146 5 16 Chloroform ug/L ND 50 50 53.3 49.8 107 100 74-137 7 9 Chloromethane ug/L ND 50 50 44.7 41.5 89 83 41-127 7 10 cis-1,2-Dichloroethene ug/L ND 50 50 56.6 55.5 113 111 71-138 2 16 cis-1,3-Dichloropropene ug/L ND 50 50 44.6 42.4 89 85 32-145 5 12 Dibromochloromethane ug/L ND 50 50 45.9 44.5 92 89 52-116 3 13 Dibromomethane ug/L ND 50 50 52.2 47.4 104 95 79-129 10 14 Ethylbenzene ug/L ND 50 50 52.5 49.7 105 99 31-174 6 10 lodomethane ug/L ND 100 100 107 96.3 107 96 49-154 11 30 Methylene Chloride ug/L ND 50 50 56.1 53.6 112 107 61-146 5 15 Styrene ug/L ND 50 50 48.1 45.7 96 91 77-128 5 14 Tetrachloroethene ug/L ND 50 50 49.7 47.1 99 94 36-155 5 14 Toluene ug/L ND 50 50 56.5 51.2 113 102 52-146 10 11 trans-1,2-Dichloroethene ug/L ND 50 50 48.1 61.5 96 123 61-152 25 14 R1 trans-1,3-Dichloropropene ug/L ND 50 50 44.3 42.1 89 84 37-146 5 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 63.8J 50.9J 64 51 61-139 23 12 M1,R1 Trichloroethene ug/L ND 50 50 49.7 45.3 99 91 61-141 9 12 Vinyl acetate ug/L ND 50 50 73.5 69.1 147 138 52-141 6 14 M1 Vinyl chloride ug/L ND 50 50 54.8 51.1 110 102 22-156 7 26 Xylene (Total) ug/L ND 150 150 163 153 109 102 78-132 7 7 1,2-Dichloroethane-d4 (S) %. 102 108 81-119 4-Bromofluorobenzene (S) %. 95 99 82-120 Dibromofluoromethane (S) %. 101 110 82-114 Toluene-d8 (S) %. 91 92 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 22334 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2614220001 METHOD BLANK: 100481 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 10000 02/13/19 10:58 LABORATORY CONTROL SAMPLE: 100482 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 217000 108 90-110 MATRIX SPIKE SAMPLE: 100486 2614667001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 3290 mg/L 1000000 4260000 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 100488 100489 MS MSD 2614650001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 468 mg/L 200000 200000 659000 668000 96 100 90-110 1 10 SAMPLE DUPLICATE: 100485 2614220001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand ug/L 1870000 1870000 0 10 SAMPLE DUPLICATE: 100487 2614635002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand ug/L 83.2 mg/L 78600 6 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21791 Analysis Method: SM 4500-P QC Batch Method: SM 4500-P Analysis Description: 450OPE Total Phosphorus Associated Lab Samples: 2614220001 METHOD BLANK: 98059 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus ug/L ND 20.0 20.0 02/05/1919:28 LABORATORY CONTROL SAMPLE: 98060 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus ug/L 100 101 101 89-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 98061 98062 MS MSD 2614132001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 6380 1000 1000 7520 7950 114 157 73-117 6 19 M6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21422 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2614220001 METHOD BLANK: 96434 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 02/04/19 13:00 1A LABORATORY CONTROL SAMPLE: 96436 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 190000 96 85-115 1A SAMPLE DUPLICATE: 96437 2614220001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 831000 834000 0 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21439 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 2614220001 METHOD BLANK: 96483 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L ND 50.0 5.0 01/29/19 16:29 Nitrite as N ug/L ND 50.0 11.0 01/29/19 16:29 Nitrogen, NO2 plus NO3 ug/L ND 50.0 12.0 01/29/19 16:29 LABORATORY CONTROL SAMPLE: 96484 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 10300 103 90-110 Nitrite as N ug/L 10000 10900 109 90-110 Nitrogen, NO2 plus NO3 ug/L 20000 21200 106 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 96485 96486 MS MSD 2614220001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 176 10000 10000 10000 10000 99 99 90-110 0 15 Nitrite as N ug/L ND 10000 10000 12900 12900 129 129 90-110 0 15 M1 Nitrogen, NO2 plus NO3 ug/L 176 20000 20000 22900 22900 114 114 90-110 0 15 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF NC-1403 Pace Project No.: 2614220 QC Batch: 21440 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 2614220001 METHOD BLANK: 96488 Matrix: Water Associated Lab Samples: 2614220001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 5000 17.0 01/29/1916:29 LABORATORY CONTROL SAMPLE: 96489 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 10000 9700 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 96490 96491 MS MSD 2614220001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 4510J 10000 10000 12000 12000 75 75 90-110 0 15 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Foothills LF NC-1403 Pace Project No.: 2614220 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. BATCH QUALIFIERS Batch: 21741 The calculated seed correction was below the desired range of 0.6 to 1.0 mg/L. All other quality control indicators, including the LCS, were within acceptance criteria. ANALYTE QUALIFIERS 1A The calculated seed correction was below the desired range of 0.6 to 1.0 mg/L. All other quality control indicators, including the LCS, were within acceptance criteria. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/15/2019 07:34 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 21 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Foothills LF NC-1403 2614220 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2614220001 1403 Leachate EPA 3005A 21711 EPA 6020B 21754 2614220001 1403 Leachate EPA 8260B 21547 2614220001 1403 Leachate EPA 410.4 22334 EPA 410.4 22338 2614220001 1403 Leachate SM 4500-P 21791 SM 4500-P 21863 2614220001 1403 Leachate SM 5210B 21422 SM 5210B 21741 2614220001 1403 Leachate EPA 300.0 21439 2614220001 1403 Leachate EPA 300.0 21440 Date: 02/15/2019 07:34 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 21 U V1 L) N Z 5 6 w O d_ ~ o w N ❑ co i60 �u}� U p ❑ Q a >U o Nz 0 MM'0 T T 2 Z Z Z ate❑ a° ❑, y: W N N N a7r 0. 2 NC] avim t~ U N- +❑QJCL 0. U N N Z x m m Fr w a:wIr p F Na7 �' ¢¢r a iw7 w 0 ¢ 0 LU� U 13 w tL i N w Q m LU N; LL O w Q z 2wa�w r ¢m:).-a iy ¢ a <0 LO0 ❑UNN� w 0 < O a ¢i7 �N❑ �~� K Cl)U p N Cn N cl z m m m w le �` r 31d=nns x Er> sn8OHdsoHd x 2 � N (XON) 311�J1IN -3-LV8ilN x °` v L' a n 311?J11N `3-LV8ilN x C > IT } A d N ❑❑0 x <v AIM (Iolax _I n o a "' s�'d13W - I XICIN3dd`d x J 0 ¢ CD Z �'` S3111VIOA - I XION3ddV x � U c�7 Q U LLI r- m CL On r t g ° [?❑xFQ—xrsr wm C0 Z qRT Q t� O W U w Z w W o a —' a U) (� v a r Cll a m Z V ❑ R. 0 jL ❑ ix J x zLU x ¢Q J 0 ¢ il? U w w mLU W ui ¢ >- _ O ; n a 0 z LU zd da o ❑ r U} o N �¢r 1L d J r- ¢ 1 LL w ONE U J ¢ o a 0 w g 2= M Z a ¢ tld v~i U CL CM �r m �+m w n U � C] w U `0 U a N # ,p f Ilt � 1 F-L J [n F w Z-3 a � z d m a m a ro LliU 2 0 v e PaceAnaVicai Client Name: Courier: Fed Ex ❑ uP5 ❑ USPS El Client ❑Commercial ❑ Pace Other Tracking #:fl.L Custody Seal on Coo! dBox Present: yes —no Seals Intact: ❑ yes Packing Material: [� Bubble W rap [flg'ubble Bags F. None ❑ Other Thermometer Used Type of Ice: N Blue None Cooler Temperature �� Biological Tissue is Frozen: Yes No Temp should be above freezing to 6"C Comments: Chain of Custody Present: NleS ❑% ❑NIA 1, Chain of Custody Filled Out: 2 ves ❑N❑ ❑N.-A 2. Chain of Custody Relinquished: es DNo ❑N!A 3, Sampler Name & Signature on CDC: es Na ❑N,A q, Samples Arrived within Hold Time: es Na ❑NIA 5, Short Hold Time Analysis (<72hr): es 6No NSA 6. Rush Turn Around Time Requested: ❑yes No ❑N;A 7. Sufficient Volume; res ❑Na 11WA g. Correct Containers Used; yes ❑No ❑N,A 9. -Pace Containers Used: Yes ON0 DWA Containers Intact: es CI No ❑N,A 10- Filtered volume received for Dissolved tests es o ❑WA 111. Sample Labels match COG es ❑Nn EIMA 12. -Includes date/lime/ID/Analysis Mati All containers needrnq preservation have been shed containers needing preservation are found to be in npiiance with EPA recommendation. CNo ❑N+A 13. UV14V4 WVt PM: 8M CLIENT 2614220 Due date: 02/12/19 Republic —NC U tionai Proj. Due Date: Proj. Name: ❑ no ❑ Sample on lee, cooling process has Datand Inili�f of pgr�o c tents: 11 X ❑, ;U 5 � initial when Lot a added Et'ceot�or VO . eol,larm, 7OC, DOG, WI-DRO (water) L7511 El No completed iprese�Ative Sam les checked for dechlorination: Dyes ❑Na NIA 14. Headspace in VOA Vials Amin): ❑Yes L-lNO ❑N;A 15, Trip Blank Present- ❑res ©No ❑NSA 16- Trip Blank Custody Seals Present Dyes ❑No ❑NIA Pace Trip Blank Lot # (ifpurchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: Field Data Required? y , N Project Manager Review: ' Bate: Noie: Whenever there is a discrepancy allecang North Carolina compliance samples. a copy of mis form wit be se it to tho North Carolina DEHNR Certification Office (i.e out of hold, vicorrect preservative, out of temp, incorrect containers) Page 21 of 21 F-ALLCO03rnv.3, t $Seplembor2006 FOOTHILLS LANDFILL JAN UARY 28, 2019 DEPTH TO RISER WATER SAMPLE WATER ELEV. ELEV. ID # (FT.) (FT.) (FT.) MW-1 R2 10.79 1516.22 1505.43 MW-2R 46.84 1253.36 1206.52 MW-3 51.79 1241.95 1190.16 MW-3R 56.02 1242.69 1186.67 MW-3R2 27.88 1240.83 1212.95 MW-4 41.31 1171.18 1129.87 MW-5 46.61 1175.07 1128.46 MW-6 40.51 1176.82 1136.31 MW-7 27.70 1183.13 1155.43 MW-8 30.70 1195.18 1164.48 MW-9 68.11 1290.79 1222.68 MW-10 78.53 1358.53 1280.00 MW-11 82.04 1401.71 1319.67 * FROM THE TOP OF RISER FOOTHILLS LF JANUARY 2019 WELL INSPECTIONS WELL RISER WELL WELL CASING PAINT WELL DEDICATED ID DIAM. SEAL LOCK COND. COND. LABEL EQUIPMENT NOTES: MW- 1R2 2" QD P G` P(Bs P G' Pfq) P B P MW - 2R 2" �G P' P G P G P P B P MW - 3R2 2" P C PS P P r P B P MW-4 2" P J P P P B P MW-5 L" G' P G P (G7 P G P B P W MW-6 2" P r P P G P P B P MW-7 2" G P f PG P G [F G P B P -W7 Ne e� s a, ►� T MW-8 2" G Pr P P G P P B P MW - 9 2" P G P (dJ P P P B P III�1Ct� M W- 10 2" P CGD P �G P P P 6 PV MW - 11 2" G P G P QG P P -G P B P 1 G-good, P-poor (needs aftention), B-bailer, P-grundfos pump, WW-well wizard pump SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA POINT ID: FIELD BLANK SAMPLE MATRIX: ❑EIONIZE❑ WATER LAB SAMPLE/ PROJECT #: EVACUATION INFORMATION INITIAL WA-TEf? LEVEL (FT) DEPTH To BOTTOM (FT) E S & S - R.CHIODO NA ELEV., MEAS. PT. (MSL): --.-` ----_ ELEVATION, G/W (MSL): DATE TIME: START/FINISH 1 METRO - D OF EVACUATION. __ EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUM { ) YES { } NO { } S.S. BAILER { ) QED PUMP { }OTHER WELL RISER DIAMETER (IN-): [ } 2 { ) 3 [ } 4 { } 6 [ } OTHER_ ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS { ] YES NO TOTAL VOL. EVACUATED (GAL) WATER LEVEL END PURGE (FT) - TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE DTW CUMULATIVE TEMP. pH CONDUCT, TURBIDITY OTHER TIME Ihtz) FT VOLUME C) d.Units) (umhoslcm) {NTU) eh (mV) SAMPLING INFORMATION � � " � � L: . G DATE 1 TIME 1 DEPTH TO GROUNDWATER (FT) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: } PVC BAILER ( ) S-S. BAILER { } GRUNDFOS PUMP { ) YES { } S.S. BAILER ( ) QED PUMP [ ) OTHER } NO SAMPLING FIELD MEASUREMENT DATA pH TEMP- CONDUCT. TURBIDITY OTHER ❑ISS.OXY. OTHER TIME (Std.Units) C umhoslcm NTU eh(my) PPM) NA NA NA NA NA NA NA NA GENERAL INFORMATION 'r~ WEATHER CONDITIONS AT TIME OF SAMPLING: Sc.t N +�+y , q.5 SAMPLE CHARACTERISTICS: C Lf—."- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: TRIP BLANK LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: ❑EIONIZED WATER LAB SAMPLE 1 PROJECT #: UATION INFORMATION INITIAL LEVEL (FT) ELEV., MEAS. PT. {MSL} -- DATE DEPTH TO BOTTOM (FT) E S & S - R.CHIODO NA ELEVATION, GIW (MSL): TIME: START/FINISH 1 METHOD OF EVACUATION: - EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP___ ( } YES } NO { } S.S. BAILER ( )QED PUMP { } OTHER WELL RISER DIAMETER (IN.).- ( } 2 { ) 3 ( } 4 } B { } OTHER-----_ ONE (1) RISER VOLUME {GAL} WAS WELL PURGED TO DRYNESS-(- ) YES( )NO TOTAL VOL- EVACUATED (GAL) WATER LEVEL END PURGE (FT) - TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA -_PURGE RATE DTW CUMULATIVE TEMP. pH CONDUCT. TURBIDITY OTHER TIME ~ ( p - tzFT VOLUME (C) (Std.Units) umhoslcm) (NTU) eh (mV) SAMPLING INFORMATION DATE 1 TIME 1 -'Z� A l I G • D 3 DEPTH TO GROUNDWATER (FT) NA _ METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP ( } YES { } S.S. BAILER ( ) QED PUMP [ } OTHER { } NO SAMPLING FIELD MEASUREMENT DATA pH TEMP. CONDUCT. TURBIDITY OTHER DISS.OXY. OTHER TIME (Std.Units) {C} umhoslcm) NTU) [ eh (mV) (PPM)( } NA NA NA NA NA NA NA NA GENERAL INFORMATION [� qF WEATHER CONDITIONS AT TIME OF SAMPLING: J UtM N 5 SAMPLE CHARACTERISTICS: c- U,•Nz- COMMENTS: VOA ONLY SAMPLE COLLECTION NUMBER 72_ SITE NAME FOOTHILLS LF POINT ID: mw - 11 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIOD❑ SAMPLE MATRIX: GROUNDWATER LAB SAMPLE 1 PROJECT #: NA EVACUATION INFORMATION, �� INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM {FT}: Q 2.9 d ELEV., MEAS. PT. [MSL]: iN ` ELEVATION, GlW (MSL): 131 � • (P7 DATE � TIME: START/FINISH • Q s 1 (0:y METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: } PVC BAILER ( } S.S. BAILER { } GRUNDFOS PUMP { X } YES } NO ( j S.S. BAILER (X) CAE❑ WW 'PUMP ( } OTHER WELL RISER DIAMETER {IN.}: j X } 2 } 3 ( } 4 { } 6 ( } OTHER ONE {1) RISER VOLUME {GAL} 9. WAS WELL PURGED TO DRYNESS } YES (X) NO TOTAL VOL. EVACUATED (GAL) '?. sn WATER LEVEL END PURGE {FT} 92, 21 TURBIDITY OF PURGINGS: START C LF AR" FINISH C LEA1PI EVACUATION STABILIZATION DATA TIME o7 6:09 a3 PURGE RATE (ML 1 MIN) 250 250 25o DTW (FT �Zol 2.0 9ZZ3 CUMUL. VOL (GAL) 0 0.25 O.50 TEMP. C f 1.9 1• 11- pH Std.Units 172.3 '7. Za '"]. 17 CONDUCT. umhoslcm ,j (v. 1 s s-. 2_ TURBIDITY [NTU) 03 ].57 y. y REDOX eh (mV) <S- 2- D.O. (MGIL 250 0.75 1 ].S �. 1 `1 5�. i J, 9-G 2.1 250 �21'S 1.00 12. D (0 12,5" 250 2,2; 1.25 1 Z'o 1 Z sy,5 1.72 `/ 07 (a. Zi G:33 250 250 S2.?-5' RZ2-7 1.50 1.75 12,0 t2.0 7 1 Z ').1 ] 5718 5� S' 1. 6 9 f,(vS ' 97 `L1 Y 1.37 1.3L (o'37 250 k2Z8 2.00 12_v '] 11 5y.7 1.7Z "`�3 41 250 &Z Zg 2.25 12,0 '7.11 sy. 7 y 250 ?Z 28 2.50 1 -� 7. I 1 S cl. -7 SAMPLING INFORMATION DATE 1 TIME ) -� " 01 1 • y- DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER } GRUNDFOS PUMP { X } YES } S.S. BAILER (X ) QED WW PUMP } OTHER [ } NO GENERAL INFORMATION r F WEATHER CONDITIONS AT TIME OF SAMPLING: _ SL4AJ+-0y, � SAMPLE CHARACTERISTICS: c �'ZAe-- r COMMENTS: APPENDIX I I IST SAMPLE COLLECTION NUMBER 3 SITE NAME FOOTHILLS LF POINT ID: mw - l Q LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): 1 D. 5-3 ELEV., MEAS. PT. (MSQ: DATE I --Z�r - N FIELD REPRESENTATIV LAB SAMPLE ! PROJECT #: ES&S- B.CHIODO NA DEPTH TO BOTTOM (FT): rI? �-- �z f ELEVATION, GAN (MSQ: I wo • oC TIME: START/FINISH 6 . Sg 1 ? :31 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X) YES ( ) NO [ j S.S. BAILER (X) QED WW PUMP { } OTHER WELL RISER DIAMETER (IN.): (X) 2 ( } 3 ( ) 4 } 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) 1. WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) '?- WATER LEVEL END PURGE (FT)W- 4 o TURBIDITY OF PURGINGS: START C cF-41_ FINISH EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME ML 1 MIN FT VOL (GAL) C Std.Units umhoslcm NTU eh (mV) (MGIL �: sg 250 `] -53 0 U L ?. 30 CoT:5 -13. If 652 �, 03 250 W75 0.25 1,2. 2 (v.g1D (p 5. D �j a f�--� �. 71 r�: o7 250 ?k 7)1 0.50 Iz. 1 ('.&s l7f) 1 6.&& 250 75S. �o 0.75 12.1 �r3 67(, 3,6Lr t)o.1 6.(y 250 7r, r 1.00 12. �3 i�pk-1 3.0' 4-10. Z 6.0 250 76b 1 1.25 12.) 2- &e).:R 3.& Z +1o.5 �. s& 250 701 1.50 1 2.Q {f �p. 8 2 '70, l 3.6,V z7 250 -R 1.75 12. a G. 7o. I 3,59 4 4D. 9 6. 5-3 �7 t 250 -M4 2.00 '70. ;Z 3. 55 4-11_ o 6, s3 SAMPLING INFORMATION DATE/TIME i - 2S-- }zi 1 7, 3 DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES { j S.S. BAILER (X) QE❑ WW PUMP ( } OTHER ( NO GENERAL INFORMATION j ] or WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: i COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER I SITE NAME FOOTHILLS LF POINT ID: mw - j LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV SAMPLE MATRIX: GROUNDWATER LAB SAMPLE/ PROJECT #: EVACUATION INFORMATION E S & S - B.CHIODO NA INITIAL WATER LEVEL (FT): (06, l I DEPTH TO BOTTOM (FT): r7 3.q Q ELEV., MEAS. PT. (MSL): a D. ELEVATION, G/W (MSL): DATE �� & - �� TIME: START/FINISH METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUMP (X) YES [ } NO ( } S.S. BAILER (X ) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X) 2 ( } 3 ( ) 4 { } 6 ( } OTHER ONE (1) RISER VOLUME (GAL) 6. 85- WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) a(. Do WATER LEVEL END PURGE (FT) 68� 33 TURBIDITY OF PURGINGS: START FINISH EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME ML ! MIN} FT VOL GAL) G (Std.Units) (umhoslcm) (NTU eh (mV) (MG/L r7:y�i 250 6?. I a 12. 7 3? 250 cSr 20 0.25 13. . 2 Z 16 0 . Z .'-f 9 f y1, 1 3. ! - `7 : 5 250 +rs; zr 0.50 13.14 6.19 1 b 1. 1 3.3 Y + y2, 5F 3.(S t: S� 250 (4-27 0.75 13.(v (. 17 (o J . q 3. 2-L +`13. 2 3. J y S� 00 250 k z5 1.00 1 3. tv 6 . J 1 1. �. K Y_r. 1 3. 1 L K °`'1 250 6Er.31 1.25 13.E (a. 17 ](01.2 3.27 -- f7. 3.13 9: 08, 250 W.311 1.50 13. (.a 1 & 1. 2- 3. z �_ + V.?. 3. 13 9 , 1 Z 250 (0rs.33 1.75 1 3.1, 161. 1 _?, 18 (Y2. 7 3A 2 :1L 250 6933 2.00 I3. 1 1(oI.1 3,1.5 3.1.2 250 22S7 ma ate SAMPLING INFORMATION DATE 1 TIME I - _)- �') 1 2 • I �, DEPTH TO GROUNDWATER (FT) 6k,33 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED - PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) QED WW PUMP ( } OTHER ( } NO GENERAL INFORMATION [� / p F WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: I'll) L4 COMMENTS: APPENDIX I LIST r-- SAMPLE COLLECTION NUMBER J SITE NAME FOOTHILLS LF POINT ID: MW - 8 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ��•�� ELEV., MEAS. PT. (MSL): } DATE I - "`� r ] q FIELD REPRESENTATIV LAB SAMPLE 1 PROJECT #: E S & S - B.CHIODO 0 r, DEPTH TO BOTTOM (FT): ! 7. - C� ELEVATION, GIW (MSL): I G L Y TIME: START/FINISH R- 32- 1 � METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUMP (X ) YES ( } NO ( } S.S. BAILER (X) QED WIN PUMP [ ) OTHER WELL RISER DIAMETER (IN.): (X ) 2 ( } 3 ( } 4 [ } 6 ( } OTHER ONE (1) RISER VOLUME (GAL) O 2 WAS WELL PURGED TO DRYNESS { } YES (X ) NO TOTAL VOL. EVACUATED (GAL)- Ov WATER LEVEL END PURGE (FT) 3o. S-s TURBIDITY OF PURGINGS: START C LFA�Z FINISH C O AR - EVACUATION STABILIZATION DATA TIME PURGE RATE ML 1 MIN) DTW FT CUMUL. VOL (GAL) TEMP. C} pH Std.Units CONDUCT. umhoslom TURBIDITY NTU REDOX eh (mV) D.O. (MGIL 5: 3 Z 250 3o.70 0 12.y 5.7 t, j )1. 1 9.'% +&3.3 O U :3t' 250 3o,&Z 0.25 12.2 5.8-0 3 !. Io 10.12 +�1. Y 1 S z 8 "10 250 30." 0.50 a z. Z 5- Fro a 3 2.1 q. o 6 f-� 1. 3 1. 1 l ?:44 250 36.�,l 0.75 12.2- 5.ko 133.Y C. 29 +LlI.,Z 1 &(.. �1 49 250 30.$Y 1.00 1 ?. I S. S�1 133. 9- 9, 3& +(v0.9 $ 2_ $ 5 Z 250 3D.&y 1.25 12_ 1 S s 13 K. 2 5, 20 a- 6 a. 8' 1. r711 $ : Sla 250 3o.iT 1.50 12- o 5 .& 1 134_ y 5,02 +L o.7 1.71. 9:oo 250 30.k 1.75 1 72. o 2 ! 3'-1, '1 +-60.y / 7L °J.'oti 250 30.,E 2.00 I2_0 Z 1 3Y.S 250250 SAMPLING INFORMATION DATE 1 TIME 1 r 2 � - 19 1 r - 0 `1 DEPTH TO GROUNDWATER (FT) 3 0.95 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X ) YES ( } S.S. BAILER (X ) QED WW PUMP ( ) OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: Gt COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 6 SITE NAME FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVAr tUATION INFORMATION INITIAL VMT LEVEL (FEET} NA ELEVATION, MEAS_PT.{MSL . NA DATE METHOD OF EVACUATION: { } PVC BAILER { } WELL WIZARD { } S.S. BAILER { } GRUNDFOS PUMP WELL RISER DIAMETER (IN.). { } 2 ONE {1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA PURGE RAT ATLVE TEMP TIME mlhtz VOLUME POINT ID: Sw - 1 FIELD REPRESENTATIVE: E S & S - B,CHIODO LAB SAMPLE/ PROJECT M NA DEPTH TO BOTTOM (FEET NA ELEVATION, GIW (MSL): NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED' ( ) CONTINUOUS-_._ } YES { ) NO PUMPING WELL _ t } 4 { } 5 } OTHER -`-� WAS WELL PURGED TO ❑RYNESS-_() YES ( )NO WATER LEVEL AFTER PURGE (FT-) FINISH pH I SPEC. CONDUCT. j TURBIDITY I OTHER Std.Units} jj {umhoslcm} I (NTU) II i eh (mv) NA a NA NA NA r SAMPLING INFORMATION DATE / TIME 11 J-2-� - � q 1 q.' ! � WATER LEVEL PRIOR TO SAMLING {FT,) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) WELL WIZARD { } WATERRA PUMP (X ) YES S-S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS.OXY. OTHER TIME Std.Units umhos/cm C NTU eh mV PPM 9-.zo Tog 51.(0 3.8 5.90 "�-7 -3� NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: G UEE COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER q SITE NAME FOOTHILLS LF POINT ID: IUIW - 7 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT)_ ELEV., M EAS. PT. (MSL): f` DATE IW-Iq FIELD REPRESENTATIV LAB SAMPLE/ PROJECT #: E S & S - B.CHIODO NA DEPTH TO BOTTOM (FT): q 0. 1 3 ELEVATION, GIW (MSL): I 1 SS. q3 TIME: STARTIFINISH '�." 3 V 1 I o: D 6 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } NO ( } S.S. BAILER (X) QED WW PUMP ( ) OTHER WELL RISER DIAMETER (IN.): (X) 2 ( } 3 ( ) 4 [ } 6 [ } OTHER ONE (1) RISER VOLUME (GAL) 1.91 WAS WELL PURGED TO DRYNESS { ) YES (X) NO TOTAL VOL. EVACUATED (GAL) v? , 4O WATER LEVEL END PURGE (FT) 1127.99 TURBIDITY OF PURGINGS: START C HIV- FINISH C USAZ EVACUATION STABILIZATION DATA X `7. ?o `1S3.13 TIME PURGE RATE ML 1 MIN DTW FT CUMUL, VOL (GAL) TEMP. (C) pH Std.Units CONDUCT. umhoslcm) TURBIDITY (NTU) REDOX eh (mV) D.O. (MGIL 9 3'1 250 -),-710 0 13, a .(3 109.9 mot. /8 +G-9.1 6. oz 9 ', 3 $ 250 2-.7 kS 0.25 13.4 5, 7 2 110, (. k S S7 4-C 5. 3 5-, 9S 9 ; KZ 250 2795 0.50 13. `7 5.7kl M. 1 6. 5-1 9 y 9 :,1 L 250 27.1? 0.75 13. 8 5. 757 1 1 ). 3 6. v g, +G y. l s, g l 9: so 250 27 shy 1.o0 13, 8' S 7 � 112, S- G. o c. 4-63, S' S, 7 Z e7 "6' 250 228V 1.25 13, 8 ST. 7 (o 113, o S, s { -1-63. ' (-g 9"s-8 250 27 81 1.50 13. k . 7 7 1 ]3. 6 5, 3 y -"- (-3. 1 S. 4 y 10;oz 250 _27911 1.75 i 3. 9 a, 7 a 11 3. 1 5,24) +6:2. 8 5: 250 27IM 2.00 13. $ 5.-7F 1 13. 1 5- 2+, +-&Z7 s�G z 2W SAMPLING INFORMATION DATE/TIME $ - �1 1 l ' O DEPTH TO GROUNDWATER (FT) -27. *1 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QE❑ WW PUMP ( } OTHER ( } NO GENERAL INFORMATION a WEATHER CONDITIONS AT TIME OF SAMPLING: _may, G%S SAMPLE CHARACTERISTICS: C CFJ�2 COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER SITE NAME: FOOTHILLS LF POINT ID: U❑ - 2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHfODO SAMPLE MATRIX: UNDERDRAIN WATER LAB SAMPLE 1 PROJECT #: NA EVACUATION INFORMATION INITIAL WEV,�L (FEET NA DEPTH TO BOTTOM {FEET) NA ELEVATION, MEAS.PT.(MSL}: _ _ NA ELEVATION, GIW (MSL): NA DATE TIME: START/FINISH r METHOD OF EVACUATION: - _ EVACUATION EQUIPMENT DEDICATED: [ } PVC BAILER ( ) WELL WIZARD { } CONTINUOUS------_ ( } YES { } NO { } S-S. BAILER ( ) GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): [ } 2 { } 4 { ] 6 { ) OTHER ONE (1) RISER VOLUME (GAL) WAS WELL PURGED TO DRYNESS- {..-} YES { } NO TOTAL VOLUME EVACUATED (GAL) WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA PURGE RATE LJMh JLATIVE TEMP. pH SPEC. CONDUCT. TURBIDITY OTHER TIME mlhtz VOLUME C ---- .Std.Units umhoslcm NTU eh mV NA 0 - - NA NA -- NA SAMPLING INFORMATION ! DATE/TIME f ��&- 1 f Q WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: [ } PVC BAILER ( ) WELL WIZARD { } WATERRA PUMP (X ) YES [ } S-S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( } NO SAMPLING FIELD MEASUREMENT DATA PH SPEC. CONDUCT- TEMP. TURBIDITY REDOX DISS.OXY. OTHER TIME Std.Units umhos/cm C NTU eh (mV) (PPM S- $ 19 I S-. 2. 9 9 6 + � �L. 7. 0 NA GENERAL INFORMATION or - WEATHER CONDITIONS AT TIME OF SAMPLING: 5wrjl4%4 9s SAMPLE CHARACTERISTICS: C COMMENTS; APPENDIX I LIST SAMPLE COLLECTION NUMBER 9 SITE NAME FOOTHILLS LF POINT ID: MW - 6 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV SAMPLE MATRIX: GROUNDWATER LAB SAMPLE 1 PROJECT #: EVACUATION INFORMATIDN E S & S - B.CHIOD❑ NA INITIAL WATER LEVEL (FT): -L) . I DEPTH TO BOTTOM (FT): ELEV., M EAS. PT. (MSL): ELEVATION, G/W (MSL); }r 3� • 1 DATE I " � $ - l � TIME: STARTIFINISH /Q '3 f 1 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER { } GRUNDFOS PUMP (X) YES { } NO ( } S.S. BAILER (X) QED WW RUMP ( } OTHER WELL RISER DIAMETER (IN.): (X) ``2 ( } 3 { ) 4 ( y 6 [ } OTHER ONE (1) RISER VOLUME (GAL) ) • (a WAS WELL PURGED TO DRYNESS { } YES (X) NO TOTAL VOL. EVACUATED (GAL) o�. Oo WATER LEVEL END PURGE (FT) qo • 63 TURBIDITY OF PURGINGS. START C Ut' A(Z FINISH C I..E14R EVACUATION STABILIZATION DATA TIME 10:31 1v:3j l�'•3g PURGE RATE (ML 1 MIN) 250 250 250 ❑TW FT yo.sl J.r 2 ua.61 CUMUL. VOL (GAL 0 0.25 0.50 TEMP, (C) ly b IV-7 ILI. 2, pH (Std,Units) 5.& 2 -563 5-6b CONDUCT. (umhoslcm) BOA 201 19z.8 TURBIDITY (NTU) -?&.❑a 1(a.:2 D jy, &,o REDOX eh (mV) 7 470. +7/,7 D.O, (MGIL 5 2.c->) lo'.w3 250 Poky 0.75 1�. 5.6va 02.L 13.2 f7A 03 10:47 250 uoJW 1.00 5.51 )e--]]. Z?.116 472.2 /.9Z fv: 51 250 o r.5 1.25 lLf, 3 9.59 1 *7. 1 54 72. -3 1. 90 to:5S 250 yatI. 1.50 1`1.1'f 5.S$ lg5e.e-1 y1 ?2.C. Ia: 5-1 250 40.650 1.75 1 9.f �. S& 1 k4l. 2 S'. 3o f 72. 7 I r1:03 250 yas5 2.00 /V..5 S.S9 I8Y. I 9. :2 C, 47,24 1.R5 - 2ag SAMPLING INFORMATION DATE/ TIME 1 - lq- 1 ':i 1 , I: °-3 DEPTH TO GROUNDWATER (FT) `7 O. 45 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) QED WW PUMP { } OTHER [ } NO GENERAL INFORMATION a r WEATHER CONDITIONS AT TIME OF SAMPLING: _ Sii,�1 r.s•�� �S SAMPLE CHARACTERISTICS: c Lr�� COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 10 SITE NAME FOOTHILLS LF POINT ID: mw - 5 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION FIELD REPRESENTATIV LAB SAMPLE 1 PROJECT #: E S & S - B.CHIODO NA INITIAL WATER LEVEL (FT): 1-1 (0. G0 1 DEPTH TO BOTTOM (FT): �, SQ ELEV- MEAS. PT, (MSL): l �. O r] ELEVATION, GIW {MSL}: DATE g - TIME: START/FINISH I ��'% j �• y METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: PVC BAILER ( ) S.S. BAILER } GRUNDFOS PUMP (X ) YES } NO } S.S. BAILER (X )QE❑ WW PUMP { } OTHER WELL RISER DIAMETER (IN.): (X ) 2 ( } 3 ( } 4 } 6 ( ) OTHER ONE (1 ) RISER VOLUME (GAL) I. WAS WELL PURGED TO DRYNESS ( } YES (X ) NO TOTAL VOL. EVACUATED (GAL) 'Zoo WATER LEVEL END PURGE (FT) zy' TURBIDITY OF PURGINGS: START C LEW— FINISH C CJ54e EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME ML 1 MIN FT VOL (GAL) C Std.Units umhoslcm NTU eh (mV) (MGIL f l.14 250 ck'61 0 91 111.7 '7 +S72 3.02. 1,, 1 $ 250 q4.�3 0.25 S.A�]nO 1112.2 �. `� 1 4-s-4.7 Q-81 11 250 r16.95 0.50 fta� f .] - Q r 7 L ) ■ 2. 5" -2 0 2 4- 5-e- 6 -2 3 1]: l• 250 14fr7 0.75 IS_9 5.92 lly. ;Z Q,0'7 +5S1 2.71 1 I '. 0 250 q! P 1.00 ! L . 2 . ? y I q 0. S I.8 $ +j�o. g 2, 7 Sr 1'.3 4 250 NL.9fl 1.25 1b. S 5 1? 2- 11Q-3 1.'71. 'f"�/..a 2.7Y 1 i', 3 $ 250 qMo 1.50 S-1811 i,9a. 2 f.(p, 7 +GI.S 2.71 )1:YZ 250 H4RI 1.75 5,$1 1917.E ].C.S +6/1 ,q 2,71 1 [a 250 lf4.11 2.00 i �. 3-0 4{,2.2 259 Mir - SAMPLING INFORMATION DATE/TIME I 1 11 '11° DEPTH TO GROUNDWATER (FT) �� I METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( ) S.S. BAILER (X )QE❑ WW PUMP ( ] OTHER ( } NO GENERAL INFORMATION QF WEATHER CONDITIONS AT TIME OF SAMPLING: Su f.rm Y.J SAMPLE CHARACTERISTICS: lF COMMENTS: APPENDIX I LIST M S /M Sp 4 rajJ SAMPLE COLLECTION NUMBER 1 ) + 1 D, SITE NAME: FOOTHILLS LF POINT ID: U❑ - 1 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIVE: E S & S - B.CHIOD❑ SAMPLE MATRIX: UNDERDRAIN WATER LAB SAMPLE I PROJECT #: NA EVAQUATION INFORMATION INITIAL WATER -LEVEL {FEETI_ ELEVATION, MEAS.PT.(MSL): DATE NA DEPTH TO BOTTOM (FEET)i NA NA ELEVATION, GIW (MSL): NA TIME: START/FINISH ! METHOD OF EVACUATION: - _ EVACUATION EQUIPMENT DEDICATED, { } PVC BAILER ( ) WELL WIZARD ( ] CONTINUOUS - ( } YES ( ] NO { ] S.S. BAILER { } GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER (IN.): ( ) 2 } 4 { } 6 ( ) OTHER ONE (1) RISER VOLUME (GAL) _ TOTAL VOLUME EVACUATED {GAL} TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA PURGE RATE GU.M-UL_ATIVE TEMP TIME mlhtz VOLUME WAS WELL PURGED TO DRYNESS ( }-YES ( ) NO WATER LEVEL AFTER PURGE (FT.) PH fStd.Units NA 0 ----- NA NA NA SAMPLING INFORMATION 1--1�' 1-1,-) 1 FINISH SPEC. CONDUCT. TURBIDITY OTHER (umhaslcm} (NTU) f eh (mV) DATE 1 TIME I WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) WELL WIZARD ( } WATERRA PUMP (X) YES } S.S. BAILER ( ) GRUNDFOS PUMP (X ) DIP BOTTLE [ ) NO SAMPLING FIELD MEASUREMENT DATA pH TIME Std.Units SPEC. CONDUCT. umhcslcm TEMP, G TURBIDITY NTU REDOX eh mV DISS.OXY. OTHER PPM NA GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C lZA(?-- COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 13 SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL TEf�_LEVEL (FEET) NA ELEVATION, MEAS-PT.(MS —__ NA DATE _ METHOD OF EVACUATION: POINT ID: SW-2 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE ! PROJECT #: NA DEPTH TO BOTTOM (FEET) NA ELEVATION, G/W {MSL}: NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED: { }PVC BAILER ( ) WELL WIZARD ( ) CONTINUQU ( ) YES ( ) NO ( } S.S. BAILER { } GRUNDFOS PUMP PUMPING WELL WELL RISER DIAMETER {IN.}: { } 2 { } 4 { } 6 ( ) OTHER ONE ('I} RISER VOLUME (GAL) WAS WELL PURGED TO DRYNES ( } YES NO TOTAL VOLUME EVACUATED (GAL} WATER LEVEL AFTER PURGE (FT.) TURBIDITY OF PURGINGS : START FINISH EVACUATION STABILIZATION DATA PURGE TIVE TEMP, pH SPEC. CONDUCT, TURBIDITY OTHER TIME m/htz VOLUME C Std. Units) umhoslcm NTU) eh (mV) NA I] — NA NA NA SAMPLING INFORMATION j I - ��� I`7 t DATE 1 TIME l WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED- { } PVC BAILER ( ) WELL WIZARD { } WATERRA PUMP (X ) YES ( } S.S. BAILER ( ) GRUNDFOS PUMP { X } DIP BOTTLE { } NO SAMPLING FIELD MEASUREMENT DATA PH SPEC, CONDUCT. TEMP- TURBIDITY REDOX DISS.OXY_ OTHER TIME S�td.Units umhoslcm C NTU eh mV PPM r7, NA GENERAL INFORMATION WEATHER CONDITIONS o F 3L4n4'JyS AT TIME OF SAMPLING: I 7 SAMPLE CHARACTERISTICS: G LF_A�?__ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 19 SITE NAME FOOTHILLS LF POINT ID: MW - 4 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT): ELEV,, MEAS. PT. (MSL): DATE ) " a � - 19 L4i • 3 I FIELD REPRESENTATIV E S & S - B.CHIODO LAB SAMPLE 1 PROJECT #: DEPTH TO BOTTOM (FT): ELEVATION, GIW (MSL): , TIME: START/FINISH 12 1, NA 13 � . a 6) .' 7 1 l3.' 09 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES ( } NO ( } S.S. BAILER (X) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X) 2 ( ] 3 ( ) 4 ( } 6 ( } OTHER ONE (1) RISER VOLUME (GAL) 1:7 WAS WELL PURGED TO DRYNESS( ) YES (X )NO TOTAL VOL. EVACUATED (GAL) v?. 5p WATER LEVEL END PURGE (FT) ClI. 4f9 TURBIDITY OF PURGINGS: START CLEAR. FINISH (2 LEAK EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME (ML 1 MIN) FT VOL (GAL) C Std.Units) (umhos/om) NTU eh (mV) (MGIL 12`29 250 `f1. 1 0 1(,',) 5..2 35.9 97 +8 3 1 .33 250 `11,gL 0.25 I (ce. S 5, 21 3 5, 3 .. 3 2 4- o, `7 t 2 12, 3 -7 250 y).y7 0.50 1 � . $ s-, 2 3 3 ,) �. 7 S' i1,1 1. 2 o 1 2.' y 1 250 1101 0.75 11 .$ S2!3 3y 7 1.&2- 42- 1.2z 12.,H5 250 q1,yS 1.00 1�.k S,?-Z 3Y.7 +91.6 411 1 : `1 `I 250 yT y$ 1. 25 Sa . $ 5. I � . !o 3 -92.) 1. 1 q 12, 3 250 11l,49 1.50 lip.! 5-,7,Z 3`1.i I.5-5' i91.S 1.17 12-,51 250 11)"fs 1.75 1i ,-7 5.Z.Z 35:Z 1•4fs }91, 4 11. 13.01 250 W).19 2,00 5123 3 5- 3 1. `-13 -+- `JI. r 1.) to 13 : 0,' 250 -11.q i 2.25 5: Z 3 3 5: 3 1. y o 4-9]. b 1.1-%- 13:0°+ 141m,11 2.50 IV 6 5- 23 3 .3 1.Y) SAMPLING INFORMATION DATE/TIME ~ ' 19 1 13 ` (9 f /-3 I ) DEPTH TO GROUNDWATER (FT) METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X) CAE❑ WW PUMP ( } OTHER [ } NO GENERAL INFORMATION cr WEATHER CONDITIONS AT TIME OF SAMPLING: 544 SAMPLE CHARACTERISTICS: C (.9 A P COMMENTS: APPENDIX I LIST D [A P 7-A ICEN SAMPLE COLLECTION NUMBER 1 5+ ) SITE NAME FOOTHILLS LF POINT ID: MW - 3R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV SAMPLE MATRIX: GROUNDWATER LAB SAMPLE r PROJECT #: EVACUATION INFORMATION S g E S & S - B.CHIODO NA INITIAL WATER LEVEL (FT): ell- '• DEPTH TO BOTTOM (FT): r7 3.9 i ELEV., MEAS. PT. (MSL): �;'I to . $ 3 ELEVATION, GIW (MSL): 1 �') 12 . S DATE - ►�. $- 1 q TIME: STARTIFINISH 13 . 71 13 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES { } NO ( ) S.S. BAILER (X) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN,): (X) 2 { } 3 ( ) 4 ( } 6 ( } OTHER ONE (1) RISER VOLUME {GAL} r].3Io WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED {GAL} 0 Q WATER LEVEL END PURGE (FT) � ell 6 TURBIDITY OF PURGINGS: START C LEAP- FINISH C CgAg- EVACUATION STABILIZATION DATA TIME PURGE RATE (ML 1 MIN DTW FT CUMUL. VOL (GAL) TEMP. C pH Std.Units CONDUCT. umhoslcm) TURBIDITY NTU REDOX eh (mV) D.O. (MGIL 13-.21 250 27 U 0 )6.? 7 5S I-?-- ❑ S g7 40 13 : 3 1 250 21r 1t 0.25 1 (v.1 ?. q 9 117.). S, 70 - 2 2 . (. �% o 2 13:3S 250 2r32 0.50 1(.g ?.35 /12. c S.25 -15-Z 3.4Z 13; 31 250 2t 3$ 0.75 )ice. °I 'i zw ) 1 0.3 Sr, v6 -10. 3 3, f 7 13 : Ll 250 2f-gz 1.00 1(. r7. 2-3 109, Z q,9 2- - 9. 9 3_ �s 13:47 250 2MY 1.25 0.a 7.2-1 jag. 1 14,95 -C3. Z 3. ez 13. 5 1 250 a15 1.50 17. o ?. z I to 8; l q,, g Z - 9. I 3, k-o 13.5 S 250 4.. Y5 1.75 17 a 720 l 0$,"1 q, 7 8! - tr S 3r e Z 13:59 250 -2$9l. 2.00 17.E '] a�L,) l0 �l �f.7� '-�7 3.8.2 250 2=7M SAMPLING INFORMATION DATE 1 TIME i - - I �) 1 1 3 . - 9 DEPTH TO GROUNDWATER (FT) -? & ` 6 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( ) PVC BAILER ( ) S.S_ BAILER ( } GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP ( } OTHER ( } NO GENERAL INFORMATION t , OF WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: ClL� AZ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER 1 SITE NAME FOOTHILLS LF POINT ID: IV W - 2R LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT),.- ELEV., MEAS. PT. (MSL): DATE 1 - -1 �-- 0 9G.94 1-253. 3(, FIELD REPRESENTATIV LAB SAMPLE I PROJECT #: E S & S - B.CHIOD❑ NA DEPTH TO BOTTOM (FT): 3- & 0 ELEVATION, GIW {MSL}: 1 4 & • 52 TIME: STARTIFINISH /W I /Lt." � L METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED- { } PVC BAILER { } S.S. BAILER { } GRUNDFOS PUMP { X } YES { } NO { ) S.S. BAILER (X) QED WW PUMP { } OTHER WELL RISER DIAMETER {IN.}: (X ) 2 { ) 3 [ } 4 { } 6 { } OTHER ONE (1) RISER VOLUME {GAL} WAS WELL PURGED TO DRYNESS ( } YES (X ) NO TOTAL VOL. EVACUATED (GAL) �• WATER LEVEL END PURGE {FT} 7. 2 Z TURBIDITY OF PURGINGS: START CtFAfL FINISH C CF� EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME (ML I MIN) (FT VOL {GAL} C} (Std.Units) (umhoslcm {NTU) eh (mV) (MGIL ),I,. I �, 250 g4.9'4 0 1 �. q 5.-� ! 1y 2.3 Q. Uk 4-w..7 .2. 2L tH : 2�o 250 tf 7. OZI 0.25 1� [o 5 . C'I 2. 2.1 !�- I`i:zy 25a L17,1Z 0.50 1� .`i 5`.6,9 14S-5 a_a 1 7) 2-)z 250 L17.11 0.75 1u .'f 5. (A 1 1-I 5, 9 /.1 4- G7. g 2, t v N.' 31 250 �7 Z� 1.00 11 ,,4 5. G • 1 1-9 2 1 �7.FS 2.0� W,3L 250 L1i.7.p 1.25 IV 15-69- �� .�{ ] g� F�7.$ 2_o5 l�l:Ha 250 '0.2a 1.50 ]}:.`i 5.b$ 146-I )--15 4-G7.9 ?.aZ 250 q Zz 1.75 1u.3 5.6$ 1'�b.l� r.72_ +67.9 1,19 250 2.00 16.3 5.119 t'•t � •7 1_ {� (a 4-G71 1.1-7 )H:Sz 250 1147,Z11 2.25 16- Sr-(,S I-4L.-7 J Lf to o 0-7 I`#:Sl, 250 q7-Zz 2.50 l�•3 ��.��� ZG��.7 1 iv � �[c1F,� 117 SAMPLING INFORMATION DATE I TIME -- t ` I • � � DEPTH TO GROUNDWATER {FT} q 7- 2- 2 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { ) PVC BAILER { } S.S. BAILER ( } GRUNDFOS PUMP (X) YES { } S.S. BAILER (X ) QED WW RUMP ( } OTHER ( } NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: C If 42 COMMENTS: APPENDIX II LIST SAMPLE COLLECTION NUMBER 1 SITE NAME: FOOTHILLS LF LOCATION_ LENOIR, NORTH CAROLINA SAMPLE MATRIX: LEACHATE VACUATION INFORMATION INIT! TER LEVEL (FEET) NA ELEVATION, MEAS,ISLj: NA DATE METHOD OF EVACUATION: { } PVC BAILER ( ] WELL WIZARD { } S.S. BAILER } GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA PU ATE ULATIVE TEMP TIME mlhtz VOLUME POINT ID: LEACHATE FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM (FEET NA ELEVATION, GIW (MSL); NA TIME: START/FINISH EVACUATION EQUIPMENT DEDICATED- } �9l7�TINUOUS ( } YES { } NO PUMPING WELL } 4 { ) B { } TOTO HER WAS WELL PURGED T0—D8YNESS ( )YES ( ) NO WATER LEVEL AFTER PURGE (FTT FINISH pH SPEC. CONDUCT. I TURBIDITY I OTHER .Units umhaslcm If {NTU} j eh {mVi NA p NA NA — NA SAMPLING INFORMATION II DATE/TIME I — �— 1 WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: { } PVC BAILER { } WELL WIZARD ( ] WATERRA PUMP (X ) YES { } S.S. BAILER ( ) GRUNDFOS PUMP (X) SAMPLE PORT ( ) NO SAMPLING FIELD MEASUREMENT DATA PH SPEC. CONDUCT. TEMP. TURBIDITY REDOX DISS.OXY. OTHER TIME Std.Units umhaslcm C NTU eh mV PPM Is"17 I.[,2 7 100 I11.$ 9(,. )o ` 29.2- NA NA GENERAL INFORMATION WEATHER F 5tAM CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: 506HTG TNx6l Io _ 4mack COMMENTS SAMPLE COLLECTION NUMBER L I SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER EVACUATION INFORMATION INITIAL AT -ER LEVEL (FEETI ELEVATION, MEAS.PT.{MSL}- DATE METHOD OF EVACUATION NA NA { ) PVC BAILER { ) WELL WIZARD { } S.S- BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA PURGE RATE CUMULATIVE TEMP TIME mlhtz VOLUME POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM {FEET] NA ELEVATION, GIW {MSL}: NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: { ) CONTINUOUS _ ) YES { } NO PUMPING WELL ( ) 4 ( ) 6 { ) OTHER WAS WELL PURGED TO DRYNESS { }_YES { ) NO WATER LEVEL AFTER PURGE (FT-) FINISH pH SPEC. CONDUCT. I TURBIDITY Std.Units umhoslcm NTU NA 6 NA - - NA NA SAMPLING INFORMATION E-1�-- Iq IC,7? OTHER eh (mV) DATE 1 TIME 1 WATER LEVEL PRIOR TO SAMLING (FT-) NA METHOD OF SAMPLING- SAMPLING EQUIPMENT DEDICATED { ) PVC BAILER ( ) WELL WIZARD { ) WATERRA PUMP (X) YES { ) S.S. BAILER ( ) GRUNDFOS PUMP (X ) DIP BOTTLE ( ) NO SAMPLING { ) PVC BAILER { ) WELL WIZARD { } S.S- BAILER ( ) GRUNDFOS PUMP WELL RISER DIAMETER (IN.): ( ) 2 ONE (1) RISER VOLUME (GAL) TOTAL VOLUME EVACUATED (GAL) TURBIDITY OF PURGINGS : START EVACUATION STABILIZATION DATA PURGE RATE CUMULATIVE TEMP TIME mlhtz VOLUME POINT ID: SW-4 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAB SAMPLE I PROJECT #: NA DEPTH TO BOTTOM {FEET] NA ELEVATION, GIW {MSL}: NA TIME: START/FINISH 1 EVACUATION EQUIPMENT DEDICATED: { ) CONTINUOUS _ ) YES { } NO PUMPING WELL ( ) 4 ( ) 6 { ) OTHER WAS WELL PURGED TO DRYNESS { }_YES { ) NO WATER LEVEL AFTER PURGE (FT-) FINISH pH SPEC. CONDUCT. I TURBIDITY Std.Units umhoslcm NTU NA 6 NA - - NA NA SAMPLING INFORMATION E-1�-- Iq IC,7? OTHER eh (mV) DATE 1 TIME 1 WATER LEVEL PRIOR TO SAMLING (FT-) NA METHOD OF SAMPLING- SAMPLING EQUIPMENT DEDICATED { ) PVC BAILER ( ) WELL WIZARD { ) WATERRA PUMP (X) YES { ) S.S. BAILER ( ) GRUNDFOS PUMP (X ) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA pH SPEC- CONDUCT, TEMP. TURBIDITY REDOX TIME Std.Units umhoslcm C NTU eh mV 15�34 '7. cl R 6- ?-.'� lo_ l 9,97 - 2 ?-. 3 GENERAL INFORMATION o r- WEATHER CONDITIONS AT TIME OF SAMPLING: 511tpJ" qS SAMPLE CHARACTERISTICS: C UEA2— COMMENTS_ APPENDIX I LIST ❑ISS- ❑XY. I OTHER 6-? ! NA SAMPLE COLLECTION NUMBER 2 C) SITE NAME: FOOTHILLS LF LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: SURFACE WATER E UATION INFORMATION INITIAL WkTER LEVEL (FE ETL A ELEVATION, MEAS.PT.(MSL}:` DATE METHOD OF EVACUATION { } PVC BAILER ( } WELL WIZARD { } S.S- BAILER } GRUNDFOS PUMP WELL RISER DIAMETER {IN.}: ( } 2 ONE (1) RISER VOLUME {GAL} TOTAL VOLUME EVACUATED {GAL} TURBIDITY OF PURGINGS : START FAA UATION STABILIZATION DATA PURGE RATE CUMULATIVE ---TEMP. TIME { mlhtz} VOLUME C POINT ID: SW - 3 FIELD REPRESENTATIVE: E S & S - B.CHIODO LAH SAMPLE 1 PROJECT #: NA DEPTH TO BOTTOM {FEET} NA ELEVATION, G/W (MSL): NA TIME: START/FINISH 1 { ) CONTINUOUS PUMPING WELL ( ) 4 ( ) 6 EVACUATION EQUIPMENT DEDICATED: ( } YES ( } NO { ] OTHER WAS WELL PURGED TO DRYNESS { ) YES { } NO WATER LEVEL AFTER PURGE {FT.) -� FINISH pH SPEC. CONDUCT, TURBIDITY OTHER ._Units umhoslom) NTU eh mV NA p NA NA NA SAMPLING INFORMATION DATE/TIME 1 - 2!�• L °I / . SO WATER LEVEL PRIOR TO SAMLING (FT.) NA METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED-. { } PVC BAILER ( ) WELL WIZARD ( ] WATERRA PUMP (X) YES ( } S.S. BAILER ( ) GRUNDFOS PUMP (X) DIP BOTTLE ( ) NO SAMPLING FIELD MEASUREMENT DATA pH SPEC. CONDUCT. TEMP. TURBIDITY REDOX TIME Std.Units umhoslcm C NTU eh mV GENERAL INFORMATION {{� WEATHER CONDITIONS AT TIME OF SAMPLING: SAMPLE CHARACTERISTICS: COMMENTS: APPENDIX 1 LIST ❑ISS, OXY. I OTHER o (, I NA SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - I R2 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION j r7 9 INITIAL WATER LEVEL (FT): I ELEV., MEAS. PT. (MSL): S 11n . ;t DATE 1-2$"la FIELD REPRESENTATIV E S & S - B.CHIODQ LAB SAMPLE 1 PROJECT #: DEPTH TO BOTTOM (FT): Ll 3. 3 y ELEVATION, GIW (MSL}: 1 SO S, LG TIME: START/FINISH I to, a 5 1 16 : 5 7 METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: { } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP (X) YES { } NO { } S.S. BAILER (X) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X) 2 ( } 3 [ ) 4 ( } 6 { ) OTHER ONE (1) RISER VOLUME (GAL) • a WAS WELL PURGED TO DRYNESS ( } YES (X) NO TOTAL VOL. EVACUATED (GAL) '�. 00 WATER LEVEL. END PURGE (FT) l o . 9 9 TURBIDITY OF PURGINGS: START G(-E'Afz FINISH cLEAR, EVACUATION STABILIZATION DATA TIME PURGE RATE (ML 1 MIN) ❑TW FT CUMUL. VOL (GAL)_(C TEMP. pH Std.Units) CONDUCT. (umhoslcm TURBIDITY NTU REDOX eh (mV) D.O. (MGIL 250 1,5.79 0 13.:R i 1 C1.�1 R.3 Z +�y,5 1, G z 25a ���y a.25 3 �, S' _2.KS t23.5' i.o IV. . 3 3 250 10 q(. 0.50 17, 2 fv. S $ !0 6 . G �. 5s -r 2-2. fr IV. 37 250 10MO 0.75 i3,�1 (,a 8 1o6. 1 �,(.7 fi 22.7 I.t7 250 1o,�li 1.00 13,9 6'se )0G. I 2. S $ f-Z2. L. Olf 250 IQA7 1.25 13A 105-.9 -2. 5' 3 +22.s /.1 Z 250 ID.18 1.50 13,9 10S,8 2. go +2Z.2 f.r� t V '3 250 1a,9s' 1.75 13.9 '2 + 2 2. 1 I J 2- 1 (p ''S 7 250 10'It 2.00 13.9 (1.159 1()5.7 :2 .4 8 + SAMPLING INFORMATION DATE/TIME - - i �1 1 �'7 DEPTH TO GROUNDWATER (FT) 1D.1 � METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. SAILER ( } GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP ( ) OTHER ( } NO GENERAL INFORMATION lys aT WEATHER CONDITIONS AT TIME OF SAMPLING: Sr.�NN SAMPLE CHARACTERISTICS: C (.F-AK COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER ;? ° lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 September 27, 2018 Derek Bouchard Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills N=1 Pace Project No.: 269230 Dear Derek Bouchard: Enclosed are the analytical results for sample(s) received by the laboratory on September 13, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Bob Chiodo, Environmental Sampling & Services, Inc. (ES&S) Steve Jett, Jett Environmental Consulting Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills N=1 Pace Project No.: 269230 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Texas Certification #: T104704397-08-TX Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Foothills N=1 Pace Project No.: 269230 Lab ID Sample ID Matrix Date Collected Date Received 269230001 269230002 1403-MWIR2 1403-MW11 Water Water 09/11/18 14:14 09/11/18 14:20 09/13/18 09:40 09/13/18 09:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Foothills N=1 Pace Project No.: 269230 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 269230001 1403-MWIR2 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 269230002 1403-MW11 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills N=1 Pace Project No.: 269230 Sample: 1403-MWIR2 Lab ID: 269230001 Collected: 09/11/18 14:14 Received: 09/13/18 09:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Date: 09/27/2018 02:41 PM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 09/20/1810:10 09/24/1816:46 7440-36-0 ND ug/L 10.0 0.57 1 09/20/1810:10 09/24/1816:46 7440-38-2 25.2J ug/L 100 0.78 1 09/20/1810:10 09/24/1816:46 7440-39-3 ND ug/L 1.0 0.050 1 09/20/1810:10 09/24/1816:46 7440-41-7 ND ug/L 1.0 0.093 1 09/20/1810:10 09/24/1816:46 7440-43-9 ND ug/L 10.0 1.6 1 09/20/1810:10 09/24/1816:46 7440-47-3 ND ug/L 10.0 0.52 1 09/20/1810:10 09/24/1816:46 7440-48-4 ND ug/L 10.0 1.3 1 09/20/1810:10 09/24/1816:46 7440-50-8 ND ug/L 10.0 0.27 1 09/20/1810:10 09/24/1816:46 7439-92-1 ND ug/L 50.0 0.95 1 09/20/1810:10 09/24/1816:46 7440-02-0 ND ug/L 10.0 1.4 1 09/20/1810:10 09/24/1816:46 7782-49-2 ND ug/L 10.0 0.95 1 09/20/1810:10 09/24/1816:46 7440-22-4 ND ug/L 5.5 0.14 1 09/20/1810:10 09/24/1816:46 7440-28-0 2.4J ug/L 25.0 1.9 1 09/20/1810:10 09/24/1816:46 7440-62-2 2.9J ug/L 10.0 2.1 1 09/20/1810:10 09/24/1816:46 7440-66-6 Analytical Method: EPA 8260E Mod ND ug/L 2.0 1.9 1 09/18/1814:56 123-91-1 101 % 50-150 1 09/18/1814:56 17060-07-0 104 % 50-150 1 09/18/1814:56 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 09/24/1816:46 67-64-1 ND ug/L 200 2.5 1 09/24/1816:46 107-13-1 ND ug/L 1.0 0.20 1 09/24/1816:46 71-43-2 ND ug/L 3.0 0.50 1 09/24/1816:46 74-97-5 ND ug/L 1.0 0.36 1 09/24/1816:46 75-27-4 ND ug/L 3.0 0.55 1 09/24/1816:46 75-25-2 ND ug/L 10.0 0.95 1 09/24/1816:46 74-83-9 ND ug/L 100 3.2 1 09/24/1816:46 78-93-3 ND ug/L 100 0.79 1 09/24/1816:46 75-15-0 ND ug/L 1.0 0.42 1 09/24/1816:46 56-23-5 ND ug/L 3.0 0.53 1 09/24/1816:46 108-90-7 ND ug/L 10.0 0.52 1 09/24/1816:46 75-00-3 ND ug/L 5.0 0.58 1 09/24/1816:46 67-66-3 ND ug/L 1.0 0.38 1 09/24/1816:46 74-87-3 ND ug/L 13.0 0.55 1 09/24/1816:46 96-12-8 ND ug/L 3.0 0.31 1 09/24/1816:46 124-48-1 ND ug/L 2.0 0.28 1 09/24/1816:46 106-93-4 ND ug/L 10.0 0.62 1 09/24/1816:46 74-95-3 ND ug/L 5.0 0.49 1 09/24/1816:46 95-50-1 ND ug/L 1.0 0.58 1 09/24/1816:46 106-46-7 ND ug/L 100 1.6 1 09/24/1816:46 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 5 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills N=1 Pace Project No.: 269230 Sample: 1403-MWIR2 Lab ID: 269230001 Collected: 09/11/18 14:14 Received: 09/13/18 09:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 09/27/2018 02:41 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 09/24/1816:46 75-34-3 ND ug/L 1.0 0.67 1 09/24/1816:46 107-06-2 ND ug/L 5.0 0.72 1 09/24/1816:46 75-35-4 ND ug/L 5.0 0.66 1 09/24/1816:46 156-59-2 ND ug/L 5.0 0.46 1 09/24/1816:46 156-60-5 ND ug/L 1.0 0.60 1 09/24/1816:46 78-87-5 ND ug/L 1.0 0.22 1 09/24/1816:46 10061-01-5 ND ug/L 1.0 0.30 1 09/24/1816:46 10061-02-6 ND ug/L 1.0 0.45 1 09/24/1816:46 100-41-4 ND ug/L 50.0 0.89 1 09/24/1816:46 591-78-6 ND ug/L 10.0 3.1 1 09/24/1816:46 74-88-4 ND ug/L 1.0 0.50 1 09/24/1816:46 75-09-2 ND ug/L 100 0.86 1 09/24/1816:46 108-10-1 ND ug/L 1.0 0.50 1 09/24/1816:46 100-42-5 ND ug/L 5.0 0.32 1 09/24/1816:46 630-20-6 ND ug/L 3.0 0.53 1 09/24/1816:46 79-34-5 ND ug/L 1.0 0.78 1 09/24/1816:46 127-18-4 ND ug/L 1.0 0.31 1 09/24/1816:46 108-88-3 ND ug/L 1.0 0.38 1 09/24/1816:46 71-55-6 ND ug/L 1.0 0.59 1 09/24/1816:46 79-00-5 ND ug/L 1.0 0.34 1 09/24/1816:46 79-01-6 ND ug/L 1.0 0.51 1 09/24/1816:46 75-69-4 ND ug/L 1.0 0.46 1 09/24/1816:46 96-18-4 ND ug/L 50.0 0.42 1 09/24/1816:46 108-05-4 ND ug/L 1.0 0.60 1 09/24/1816:46 75-01-4 ND ug/L 5.0 1.5 1 09/24/1816:46 1330-20-7 100 %. 81-119 1 09/24/1816:46 17060-07-0 100 %. 82-114 1 09/24/1816:46 1868-53-7 105 %. 82-120 1 09/24/1816:46 460-00-4 97 %. 82-109 1 09/24/1816:46 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills N=1 Pace Project No.: 269230 Sample: 1403-MW11 Lab ID: 269230002 Collected: 09/11/18 14:20 Received: 09/13/18 09:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Water, Extend Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene Date: 09/27/2018 02:41 PM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 09/20/1810:10 09/24/1816:52 7440-36-0 ND ug/L 10.0 0.57 1 09/20/1810:10 09/24/1816:52 7440-38-2 37.2J ug/L 100 0.78 1 09/20/1810:10 09/24/1816:52 7440-39-3 ND ug/L 1.0 0.050 1 09/20/1810:10 09/24/1816:52 7440-41-7 ND ug/L 1.0 0.093 1 09/20/1810:10 09/24/1816:52 7440-43-9 5.1J ug/L 10.0 1.6 1 09/20/1810:10 09/24/1816:52 7440-47-3 0.97J ug/L 10.0 0.52 1 09/20/1810:10 09/24/1816:52 7440-48-4 ND ug/L 10.0 1.3 1 09/20/1810:10 09/24/1816:52 7440-50-8 ND ug/L 10.0 0.27 1 09/20/1810:10 09/24/1816:52 7439-92-1 4.8J ug/L 50.0 0.95 1 09/20/1810:10 09/24/1816:52 7440-02-0 ND ug/L 10.0 1.4 1 09/20/1810:10 09/24/1816:52 7782-49-2 ND ug/L 10.0 0.95 1 09/20/1810:10 09/24/1816:52 7440-22-4 ND ug/L 5.5 0.14 1 09/20/1810:10 09/24/1816:52 7440-28-0 ND ug/L 25.0 1.9 1 09/20/1810:10 09/24/1816:52 7440-62-2 6.5J ug/L 10.0 2.1 1 09/20/1810:10 09/24/1816:52 7440-66-6 Analytical Method: EPA 8260E Mod ND ug/L 2.0 1.9 1 09/18/1815:55 123-91-1 98 % 50-150 1 09/18/1815:55 17060-07-0 102 % 50-150 1 09/18/1815:55 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 09/24/1817:12 67-64-1 ND ug/L 200 2.5 1 09/24/1817:12 107-13-1 ND ug/L 1.0 0.20 1 09/24/1817:12 71-43-2 ND ug/L 3.0 0.50 1 09/24/1817:12 74-97-5 ND ug/L 1.0 0.36 1 09/24/1817:12 75-27-4 ND ug/L 3.0 0.55 1 09/24/1817:12 75-25-2 ND ug/L 10.0 0.95 1 09/24/1817:12 74-83-9 ND ug/L 100 3.2 1 09/24/1817:12 78-93-3 ND ug/L 100 0.79 1 09/24/1817:12 75-15-0 ND ug/L 1.0 0.42 1 09/24/1817:12 56-23-5 ND ug/L 3.0 0.53 1 09/24/1817:12 108-90-7 ND ug/L 10.0 0.52 1 09/24/1817:12 75-00-3 ND ug/L 5.0 0.58 1 09/24/1817:12 67-66-3 ND ug/L 1.0 0.38 1 09/24/1817:12 74-87-3 ND ug/L 13.0 0.55 1 09/24/1817:12 96-12-8 ND ug/L 3.0 0.31 1 09/24/1817:12 124-48-1 ND ug/L 2.0 0.28 1 09/24/1817:12 106-93-4 ND ug/L 10.0 0.62 1 09/24/1817:12 74-95-3 ND ug/L 5.0 0.49 1 09/24/1817:12 95-50-1 ND ug/L 1.0 0.58 1 09/24/1817:12 106-46-7 ND ug/L 100 1.6 1 09/24/1817:12 110-57-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 7 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills N=1 Pace Project No.: 269230 Sample: 1403-MW11 Lab ID: 269230002 Collected: 09/11/18 14:20 Received: 09/13/18 09:40 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 09/27/2018 02:41 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 09/24/1817:12 75-34-3 ND ug/L 1.0 0.67 1 09/24/1817:12 107-06-2 ND ug/L 5.0 0.72 1 09/24/1817:12 75-35-4 ND ug/L 5.0 0.66 1 09/24/1817:12 156-59-2 ND ug/L 5.0 0.46 1 09/24/1817:12 156-60-5 ND ug/L 1.0 0.60 1 09/24/1817:12 78-87-5 ND ug/L 1.0 0.22 1 09/24/1817:12 10061-01-5 ND ug/L 1.0 0.30 1 09/24/1817:12 10061-02-6 ND ug/L 1.0 0.45 1 09/24/1817:12 100-41-4 ND ug/L 50.0 0.89 1 09/24/1817:12 591-78-6 ND ug/L 10.0 3.1 1 09/24/1817:12 74-88-4 ND ug/L 1.0 0.50 1 09/24/1817:12 75-09-2 ND ug/L 100 0.86 1 09/24/1817:12 108-10-1 ND ug/L 1.0 0.50 1 09/24/1817:12 100-42-5 ND ug/L 5.0 0.32 1 09/24/1817:12 630-20-6 ND ug/L 3.0 0.53 1 09/24/1817:12 79-34-5 ND ug/L 1.0 0.78 1 09/24/1817:12 127-18-4 ND ug/L 1.0 0.31 1 09/24/1817:12 108-88-3 ND ug/L 1.0 0.38 1 09/24/1817:12 71-55-6 ND ug/L 1.0 0.59 1 09/24/1817:12 79-00-5 ND ug/L 1.0 0.34 1 09/24/1817:12 79-01-6 ND ug/L 1.0 0.51 1 09/24/1817:12 75-69-4 ND ug/L 1.0 0.46 1 09/24/1817:12 96-18-4 ND ug/L 50.0 0.42 1 09/24/1817:12 108-05-4 ND ug/L 1.0 0.60 1 09/24/1817:12 75-01-4 ND ug/L 5.0 1.5 1 09/24/1817:12 1330-20-7 104 %. 81-119 1 09/24/1817:12 17060-07-0 96 %. 82-114 1 09/24/1817:12 1868-53-7 105 %. 82-120 1 09/24/1817:12 460-00-4 94 %. 82-109 1 09/24/1817:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 QC Batch: 13842 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 269230001, 269230002 METHOD BLANK: 61672 Associated Lab Samples: Parameter 269230001, 269230002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L 0.79J 6.0 0.78 09/24/1815:26 Arsenic ug/L ND 10.0 0.57 09/24/1815:26 Barium ug/L ND 100 0.78 09/24/1815:26 Beryllium ug/L ND 1.0 0.050 09/24/1815:26 Cadmium ug/L ND 1.0 0.093 09/24/1815:26 Chromium ug/L ND 10.0 1.6 09/24/1815:26 Cobalt ug/L ND 10.0 0.52 09/24/1815:26 Copper ug/L ND 10.0 1.3 09/24/1815:26 Lead ug/L ND 10.0 0.27 09/24/1815:26 Nickel ug/L ND 50.0 0.95 09/24/1815:26 Selenium ug/L ND 10.0 1.4 09/24/1815:26 Silver ug/L ND 10.0 0.95 09/24/1815:26 Thallium ug/L ND 5.5 0.14 09/24/1815:26 Vanadium ug/L ND 25.0 1.9 09/24/1815:26 Zinc ug/L 2AJ 10.0 2.1 09/24/1815:26 LABORATORY CONTROL SAMPLE: 61673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 116 116 80-120 Arsenic ug/L 100 104 104 80-120 Barium ug/L 100 101 101 80-120 Beryllium ug/L 100 110 110 80-120 Cadmium ug/L 100 104 104 80-120 Chromium ug/L 100 110 110 80-120 Cobalt ug/L 100 107 107 80-120 Copper ug/L 100 107 107 80-120 Lead ug/L 100 105 105 80-120 Nickel ug/L 100 106 106 80-120 Selenium ug/L 100 104 104 80-120 Silver ug/L 100 105 105 80-120 Thallium ug/L 100 106 106 80-120 Vanadium ug/L 100 111 111 80-120 Zinc ug/L 100 110 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61674 61675 MS MSD 269432006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 127 119 127 119 75-125 6 20 M1 Arsenic ug/L 24.5 100 100 130 126 105 102 75-125 3 20 Barium ug/L 95.2 100 100 213 204 117 108 75-125 4 20 Beryllium ug/L ND 100 100 100 95.4 100 95 75-125 5 20 Cadmium ug/L ND 100 100 106 102 106 102 75-125 4 20 Chromium ug/L ND 100 100 105 101 105 101 75-125 4 20 Cobalt ug/L ND 100 100 104 99.2 103 98 75-125 5 20 Copper ug/L ND 100 100 102 100 102 100 75-125 2 20 Lead ug/L ND 100 100 112 109 112 109 75-125 3 20 Nickel ug/L ND 100 100 101 97.6 100 97 75-125 3 20 Selenium ug/L ND 100 100 105 100 104 99 75-125 4 20 Silver ug/L ND 100 100 107 103 107 103 75-125 4 20 Thallium ug/L ND 100 100 113 109 113 109 75-125 3 20 Vanadium ug/L ND 100 100 105 103 104 103 75-125 2 20 Zinc ug/L ND 100 100 108 104 105 101 75-125 4 20 SAMPLE DUPLICATE: 61676 269432006 Dup Max Parameter Units Result Result RPD RPD Qualifiers Antimony ug/L ND ND 20 Arsenic ug/L 24.5 23.8 3 20 Barium ug/L 95.2 92.OJ 3 20 Beryllium ug/L ND ND 20 Cadmium ug/L ND ND 20 Chromium ug/L ND ND 20 Cobalt ug/L ND 0.73J 20 Copper ug/L ND ND 20 Lead ug/L ND ND 20 Nickel ug/L ND ND 20 Selenium ug/L ND ND 20 Silver ug/L ND ND 20 Thallium ug/L ND ND 20 Vanadium ug/L ND ND 20 Zinc ug/L ND 3.3J 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 QC Batch: 431094 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 269230001, 269230002 METHOD BLANK: 2377573 Associated Lab Samples: 269230001, 269230002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 99 50-150 102 50-150 MDL Analyzed 1.9 09/18/18 13:57 09/18/18 13:57 09/18/18 13:57 Qualifiers LABORATORY CONTROL SAMPLE: 2377574 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.3 86 71-125 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 100 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2377575 2377576 MS MSD 269230001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.3 19.6 87 98 50-150 12 30 1,2-Dichloroethane-d4 (S) % 101 97 50-150 30 Toluene-d8 (S) % 103 101 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 QC Batch: 14052 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 269230001, 269230002 METHOD BLANK: 62619 Associated Lab Samples: 269230001, 269230002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 09/24/18 10:50 1,1,1-Trichloroethane ug/L ND 1.0 0.38 09/24/18 10:50 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 09/24/18 10:50 1,1,2-Trichloroethane ug/L ND 1.0 0.59 09/24/18 10:50 1,1-Dichloroethane ug/L ND 5.0 0.41 09/24/18 10:50 1,1-Dichloroethene ug/L ND 5.0 0.72 09/24/18 10:50 1,2,3-Trichloropropane ug/L ND 1.0 0.46 09/24/18 10:50 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 09/24/18 10:50 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 09/24/18 10:50 1,2-Dichlorobenzene ug/L ND 5.0 0.49 09/24/18 10:50 1,2-Dichloroethane ug/L ND 1.0 0.67 09/24/18 10:50 1,2-Dichloropropane ug/L ND 1.0 0.60 09/24/18 10:50 1,4-Dichlorobenzene ug/L ND 1.0 0.58 09/24/18 10:50 2-Butanone (MEK) ug/L ND 100 3.2 09/24/18 10:50 2-Hexanone ug/L ND 50.0 0.89 09/24/18 10:50 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 09/24/18 10:50 Acetone ug/L ND 100 8.2 09/24/18 10:50 Acrylonitrile ug/L ND 200 2.5 09/24/18 10:50 Benzene ug/L ND 1.0 0.20 09/24/18 10:50 Bromochloromethane ug/L ND 3.0 0.50 09/24/18 10:50 Bromodichloromethane ug/L ND 1.0 0.36 09/24/18 10:50 Bromoform ug/L ND 3.0 0.55 09/24/18 10:50 Bromomethane ug/L ND 10.0 0.95 09/24/18 10:50 Carbon disulfide ug/L ND 100 0.79 09/24/18 10:50 Carbon tetrachloride ug/L ND 1.0 0.42 09/24/18 10:50 Chlorobenzene ug/L ND 3.0 0.53 09/24/18 10:50 Chloroethane ug/L ND 10.0 0.52 09/24/18 10:50 Chloroform ug/L ND 5.0 0.58 09/24/18 10:50 Chloromethane ug/L ND 1.0 0.38 09/24/18 10:50 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 09/24/18 10:50 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 09/24/18 10:50 Dibromochloromethane ug/L ND 3.0 0.31 09/24/18 10:50 Dibromomethane ug/L ND 10.0 0.62 09/24/18 10:50 Ethylbenzene ug/L ND 1.0 0.45 09/24/18 10:50 lodomethane ug/L ND 10.0 3.1 09/24/18 10:50 Methylene Chloride ug/L ND 1.0 0.50 09/24/18 10:50 Styrene ug/L ND 1.0 0.50 09/24/18 10:50 Tetrachloroethene ug/L ND 1.0 0.78 09/24/18 10:50 Toluene ug/L ND 1.0 0.31 09/24/18 10:50 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 09/24/18 10:50 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 09/24/18 10:50 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 METHOD BLANK: 62619 Associated Lab Samples: Parameter 269230001, 269230002 Units Matrix: Blank Result Water Reporting Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) %. 98 81-119 4-Bromofluorobenzene (S) %. 105 82-120 Dibromofluoromethane (S) %. 102 82-114 Toluene-d8 (S) %. 100 82-109 Analyzed 1.6 09/24/18 10:50 0.34 09/24/18 10:50 0.51 09/24/18 10:50 0.42 09/24/18 10:50 0.60 09/24/18 10:50 1.5 09/24/18 10:50 09/24/18 10:50 09/24/18 10:50 09/24/18 10:50 09/24/18 10:50 LABORATORY CONTROL SAMPLE: Parameter 62620 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 44.5 89 68-137 1,1,1-Trichloroethane ug/L 50 51.4 103 72-134 1,1,2,2-Tetrachloroethane ug/L 50 52.3 105 51-158 1,1,2-Trichloroethane ug/L 50 47.1 94 78-131 1,1-Dichloroethane ug/L 50 48.4 97 69-151 1,1-Dichloroethene ug/L 50 51.1 102 64-158 1,2,3-Trichloropropane ug/L 50 45.2 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 43.1 86 58-124 1,2-Dibromoethane (EDB) ug/L 50 47.9 96 71-134 1,2-Dichlorobenzene ug/L 50 47.4 95 70-135 1,2-Dichloroethane ug/L 50 49.3 99 72-129 1,2-Dichloropropane ug/L 50 48.6 97 64-135 1,4-Dichlorobenzene ug/L 50 48.0 96 70-131 2-Butanone (MEK) ug/L 100 66.3J 66 52-143 2-Hexanone ug/L 100 66.3 66 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 72.7J 73 71-129 Acetone ug/L 100 58.1 J 58 48-224 Acrylonitrile ug/L 200 155J 78 66-154 Benzene ug/L 50 52.9 106 68-132 Bromochloromethane ug/L 50 46.5 93 73-133 Bromodichloromethane ug/L 50 45.9 92 67-121 Bromoform ug/L 50 44.1 88 57-125 Bromomethane ug/L 50 44.0 88 35-156 Carbon disulfide ug/L 100 82.1J 82 47-141 Carbon tetrachloride ug/L 50 56.3 113 66-122 Chlorobenzene ug/L 50 52.3 105 71-126 Chloroethane ug/L 50 41.2 82 43-143 Chloroform ug/L 50 47.3 95 71-136 Chloromethane ug/L 50 41.9 84 47-123 cis-1,2-Dichloroethene ug/L 50 48.8 98 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 LABORATORY CONTROL SAMPLE: 62620 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 44.0 88 78-120 Dibromochloromethane ug/L 50 45.2 90 65-115 Dibromomethane ug/L 50 46.0 92 79-129 Ethylbenzene ug/L 50 52.3 105 68-129 lodomethane ug/L 100 56.9 57 49-154 Methylene Chloride ug/L 50 48.7 97 61-147 Styrene ug/L 50 45.3 91 77-128 Tetrachloroethene ug/L 50 46.1 92 51-139 Toluene ug/L 50 46.7 93 60-133 trans-1,2-Dichloroethene ug/L 50 48.4 97 69-144 trans- 1,3-Dichloropropene ug/L 50 42.7 85 74-128 trans-1,4-Dichloro-2-butene ug/L 100 88.5J 88 61-139 Trichloroethene ug/L 50 51.8 104 73-126 Trichlorofluoromethane ug/L 50 47.2 94 55-132 Vinyl acetate ug/L 50 42.8J 86 52-141 Vinyl chloride ug/L 50 44.8 90 50-133 Xylene (Total) ug/L 150 139 93 78-132 1,2-Dichloroethane-d4 (S) %. 101 81-119 4-Bromofluorobenzene (S) %. 103 82-120 Dibromofluoromethane (S) %. 109 82-114 Toluene-d8 (S) %. 95 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 62621 62622 MS MSD 269130008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 41.1 42.4 82 85 68-137 3 11 1,1,1-Trichloroethane ug/L ND 50 50 56.7 50.6 113 101 66-142 11 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 42.0 49.7 84 99 39-171 17 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 46.4 46.4 93 93 73-136 0 12 1,1-Dichloroethane ug/L 20.3 50 50 83.0 81.5 125 122 66-155 2 15 1,1-Dichloroethene ug/L 56.5 50 50 131 126 150 139 33-181 4 34 1,2,3-Trichloropropane ug/L ND 50 50 34.4 40.9 69 82 78-133 17 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 34.1 41.1 68 82 58-124 19 15 R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 46.1 46.9 92 94 71-134 2 12 1,2-Dichlorobenzene ug/L ND 50 50 44.9 47.8 90 96 69-135 6 10 1,2-Dichloroethane ug/L ND 50 50 50.5 52.0 101 104 36-159 3 10 1,2-Dichloropropane ug/L ND 50 50 50.2 47.8 100 96 68-132 5 11 1,4-Dichlorobenzene ug/L ND 50 50 43.6 44.6 87 89 49-153 2 9 2-Butanone (MEK) ug/L 68.3 100 100 72.6J 80.9J 4 13 10-189 11 23 M1 2-Hexanone ug/L ND 100 100 71.4 71.4 71 71 40-135 0 18 4-Methyl-2-pentanone ug/L ND 100 100 74.6J 73.2J 75 73 30-177 2 10 (MIBK) Acetone ug/L 73.0 100 100 65.7J 70.9J -7 -2 44-223 8 14 M1 Acrylonitrile ug/L ND 200 200 1981 207 99 104 13-189 4 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills N=1 Pace Project No.: 269230 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 62621 62622 MS MSD 269130008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Benzene ug/L ND 50 50 55.4 54.3 111 109 66-139 2 10 Bromochloromethane ug/L ND 50 50 49.3 47.4 99 95 73-133 4 13 Bromodichloromethane ug/L ND 50 50 44.9 44.5 90 89 57-120 1 13 Bromoform ug/L ND 50 50 36.5 36.4 73 73 48-128 0 13 Bromomethane ug/L ND 50 50 57.8 53.7 116 107 10-187 7 32 Carbon disulfide ug/L ND 100 100 105 102 105 102 47-141 3 322 Carbon tetrachloride ug/L ND 50 50 66.5 58.7 133 117 58-127 12 14 M1 Chlorobenzene ug/L ND 50 50 50.9 50.5 102 101 63-137 1 10 Chloroethane ug/L ND 50 50 52.8 52.7 106 105 52-146 0 16 Chloroform ug/L ND 50 50 52.6 49.8 105 100 74-137 5 9 Chloromethane ug/L ND 50 50 50.4 52.6 101 105 41-127 4 10 cis-1,2-Dichloroethene ug/L 1.8 50 50 54.1 51.9 105 100 71-138 4 16 cis-1,3-Dichloropropene ug/L ND 50 50 40.4 41.6 81 83 32-145 3 12 Dibromochloromethane ug/L ND 50 50 42.3 41.4 85 83 52-116 2 13 Dibromomethane ug/L ND 50 50 43.9 43.0 88 86 79-129 2 14 Ethylbenzene ug/L ND 50 50 55.4 53.5 111 107 31-174 4 10 lodomethane ug/L ND 100 100 59.8 75.3 60 75 49-154 23 30 Methylene Chloride ug/L ND 50 50 59.6 60.2 119 120 61-146 1 15 Styrene ug/L ND 50 50 46.5 45.6 93 91 77-128 2 14 Tetrachloroethene ug/L 2.4 50 50 49.4 47.8 94 91 36-155 3 14 Toluene ug/L ND 50 50 50.7 48.2 101 96 52-146 5 11 trans-1,2-Dichloroethene ug/L ND 50 50 61.6 61.0 123 122 61-152 1 14 trans-1,3-Dichloropropene ug/L ND 50 50 38.6 38.8 77 78 37-146 1 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 73.2J 79AJ 73 79 61-139 8 12 Trichloroethene ug/L ND 50 50 56.7 51.5 113 103 61-141 10 12 Trichlorofluoromethane ug/L ND 50 50 77.1 75.3 154 151 51-141 2 13 M1 Vinyl acetate ug/L ND 50 50 47.1J 52.8 94 106 52-141 11 14 Vinyl chloride ug/L ND 50 50 64.7 63.9 129 128 22-156 1 26 Xylene (Total) ug/L ND 150 150 147 141 98 94 78-132 4 7 1,2-Dichloroethane-d4 (S) %. 104 107 81-119 4-Bromofluorobenzene (S) %. 86 105 82-120 Dibromofluoromethane (S) %. 124 109 82-114 SO Toluene-d8 (S) %. 96 97 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Foothills N=1 Pace Project No.: 269230 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/27/2018 02:41 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills N=1 Pace Project No.: 269230 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 269230001 1403-MWIR2 EPA 3005A 13842 EPA 6020B 13891 269230002 1403-MW11 EPA 3005A 13842 EPA 6020B 13891 269230001 1403-MWIR2 EPA 8260B Mod. 431094 269230002 1403-MW11 EPA 8260B Mod. 431094 269230001 1403-MWIR2 EPA 8260B 14052 269230002 1403-MW11 EPA 8260B 14052 Date: 09/27/2018 02:41 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 19 N O O O co RR U) Ir W Z Er O QU �W r� C � 2 mU QW W T UILv J Q CM vY0 i<r- LL m �oo >'OC\j �w� UO ~O m a. T 0 0 tU W } 0 N V LL Z 2 L) U N Z to O ¢ c U z Om o (0 v O - CO c w C7p pp H Q jU�Z00�° cc 0�0cr0¢ p wSSS Vol (n(n(nQJa LL Z m cr CO v n m w . , . , , , 00 CO C/) z Q O w a U) U z v) X o M = = c m rnQ a < wW w ¢ F- a_ ¢ O w 11 ~ (Jj J J V¢C7 Q C.7 a : W ?: ZwZQ w Ne LL ¢U)wa>i=W J¢ ¢ z ;=LL¢W a z-12J m OFF- ¢a¢❑�¢ � N — Q Qa¢U >cn0 ❑�iC7U::)) Oa¢C7>u�0 ������ U —� m A U ❑�(7U O N I cp to F w a m - C z 7 m w¢ 3 — N cn LL 41 J ct a: w S t C � W- W o ❑ Z8 1 ns ` W W U � v W wm wnE O 02w 0 8 ° U U Q z ►1 d ��ilG �P �a� z � �p aw ❑ z Q� g aOA II �jv OrM Woo 0 a Q Q J ry N m N w w ° UOzF-¢-ZWWO ► 00 zaz w'w LL ¢a m c°i a �' ¢ ¢ to U z 0 a � U Z z R� "CI w ❑ N w a a - 1 W Li _ U3 I _ —21 w ya U a Ao W W c 0 j 0 0 0a:<m �r v .i z J X- LL9 J a z UO2a ¢ � L X m Oi L11 _ P ° '_ — 7� w ❑ z of Q 0 g U m _ Z Y 1• ., O Lli 1 W O IL Q O , co 0 Z ❑ H � J ¢� H w H w -� F C) O J, 1 wo > z a O U J J O ¢ ¢ U 0- ¢ ¢ U U ¢ a a w I O N LO N N 18 of 19 r' FkeAnalytica( ConditionSample .. Client Name: ", ect # Courier: ❑'I d Ex ❑ UPS ❑ USPS ❑ Client ❑Commercial ❑ Pace Other _ WO# : 269230 Tracking #: PM: BM Due Dale: 09/27/18 Custody Seal on Cooler/Box Present: yes ❑ no Seals intact: yes L1 CLIENT: Republic —NC Packing Material: ❑ Bubble Wrap _2r'ubble Bags ❑ None ❑ Other Thermometer Used Type of Ice: Wel Blue None ❑Samples on ice, cooling process has begun Biological Tissueis Frozen: Yes No Date and Initi f per on examining Cooler Temperature contents: Temp should be above freezing to 6'C Comments: Chain of Custody Present: 121es ❑No ❑N/A 1. Chain of Custody Filled Out: es ON. ❑NiA 2. Chain of Custody Relinquished: ZTYes ❑No ❑N/A 3, Sampler Name & Signature on COC: Yes ❑No ❑N/A 4. Samples Arrived within Hold Time: es ❑No ❑N/A 5. Short Hold Time Analysis (<72hr): ❑Yes 2<V ❑N/A 6. Rush Turn Around Time Requested: ❑Yes r' to ❑N/A 7. Sufficient Volume: -f-I Yes ❑No El N/A g. Correct Containers Used: <IYes ❑No ❑N/A 9. -Pace Containers Used: _,❑Yes ❑No ❑NiA Containers Intact: -1:5Yes ❑No ❑NiA 10. Filtered volume received for Dissolved tests ❑Yes ❑No N/A 11 Sample Labels match COC: A .. Yes ❑No ❑N!A 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. e5e ❑No ❑N/A s 13 All containers needing preservation are found to be in nrlo ❑NiA e7TYes compliance with EPA recommendation. Initial when Lot rk of added exceptions: OA, coliform, TOC, O&G, WI•DRO (water) Yes (--]No completed preservative Samples checked for dechlorination: ❑Yes ❑No 8'� 14. Headspace in VOA Vials ( >6mm): []Yes o ON/A 15. Trip Blank Present: ❑Yes � ,o ❑N/A 16, Trip Blank Custody Seals Present ❑Yes :1N0 - /A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: 1 Field Data Required? Y r) Person Contacted: De--k (>o�-c �a«� Date/Time Comments/ Resolution: e r < l t �C_,. -& Sep ^^S Project Manager Review: &I Date: q a o 1 Note Nhenever there is a discrepancy affecting North Carolina -ompliance samples a :opy Df this form ,vill be sent tc -he "lorth "'arolina DEHNR >n1ficatlon Dffice , e out �f hold. incorrect preservative. 3ut Df temp incorrect :ontainers Page 19 of 19 =ectemCNr., 131,AEA BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: 9/11/18 Casing Diameter: 2 inches Field Personnel: Ivan A. Irizarry, T.J. Daniel Casing Material: PVC Site Name: Foothills Regional MSW Landfill Measuring Point Elevation (ft msl): NA BLE Job #: J18-1235-89 Height of Riser (ft above land surface): NA Well ID #: MW-1R2 Land Surface Elevation (ft msl): NA Downgradient: Screened Interval (ft bgs): 40.34 -25.34 Upgradient: X Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: Yes Air Temperature: 71.6 OF Locking Cap: Yes Total Well Depth in feet (TWD) = 43.54 Protective Post/Abutment: Yes Depth to Ground Water in feet (DGW) = 18.24 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 25.30 Well Yield (subjective): Intermediate 1 Casing Volume in gallons (CV) = LWC x 0.17 = 4.30 Sample Date and Time: 9/11/18 @ 1404 Standard Evacuation Volume (3 casing volumes) = 12.90 Remarks: Low -Flow purging and sampling done with a Proactive Tornado 2.0 Method of Well Evacuation: Submersible Pump Method of Sample Collection: Submersible Pump submersible pump with Teflon tubing. Total Volume of Water Removed (gallons): 66.0 Volume Purged (gallons) FIELD ANALYSIS 0 42 66 Time (military) 1119 1249 1404 pH (S.U.) 6.89 6.32 6.35 Sp. Cond. (umhos/cm) 177.6 108.5 108.2 Water Temp. (°C) 16.1 1 16.4 1 16 Turbidity (subjective) (NTU) >2,000 4.04 7.19 COMMENTS/OBSERVATIONS: 131,AEA BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: 9/11/18 Casing Diameter: 2 inches Field Personnel: Ivan A. Irizarry, T.J. Daniel Casing Material: PVC Site Name: Foothills Regional MSW Landfill Measuring Point Elevation (ft msl): NA BLE Job #: J18-1235-89 Height of Riser (ft above land surface): NA Well ID #: MW-11 Land Surface Elevation (ft msl): NA Downgradient: X Screened Interval (ft bgs): 105.2-90.2 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: Yes Air Temperature: 71.6 OF Locking Cap: Yes Total Well Depth in feet (TWD) = 108.40 Protective Post/Abutment: Yes Depth to Ground Water in feet (DGW) = 80.89 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 27.51 Well Yield (subjective): Intermediate 1 Casing Volume in gallons (CV) = LWC x 0.17 = 4.68 Sample Date and Time: 9/11/18 @ 1420 Standard Evacuation Volume (3 casing volumes) = 14.03 Remarks: Low -Flow purging and sampling done with a Proactive Tornado 2.0 Method of Well Evacuation: Submersible Pump Method of Sample Collection: Submersible Pump submersible pump with Teflon tubing. Total Volume of Water Removed (gallons): 96.0 Volume Purged (gallons) FIELD ANALYSIS 0 35.5 96 Time (military) 1030 1230 1420 pH (S.U.) 7.3 6.8 6.71 Sp. Cond. (umhos/cm) 377.4 58.12 64.91 Water Temp. (°C) 16.3 1 18.3 1 17.3 Turbidity (subjective) (NTU) >2,000 164 3.51 COMMENTS/OBSERVATIONS: lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 October 17, 2018 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on October 09, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Texas Certification #: T104704397-08-TX Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Lab ID Sample ID Matrix Date Collected Date Received 2610240001 2610240002 1403-MW1R2 1403-MW11 Water Water 10/08/18 09:33 10/08/18 10:38 10/09/18 09:35 10/09/18 09:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2610240001 1403-MW1R2 EPA6020B SER 15 PASI-A EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA 2610240002 1403-MW11 EPA 6020E SER 15 PASI-A EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 51 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Sample: 1403-MW1R2 Lab ID: 2610240001 Collected: 10/08/18 09:33 Received: 10/09/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Antimony ND ug/L 0.50 0.10 1 10/10/18 22:30 10/12/18 14:07 7440-36-0 Arsenic 0.11 ug/L 0.10 0.050 1 10/10/18 22:30 10/12/18 14:07 7440-38-2 Barium 30.0 ug/L 0.30 0.11 1 10/10/18 22:30 10/12/18 14:07 7440-39-3 Beryllium ND ug/L 0.10 0.020 1 10/10/18 22:30 10/12/18 14:07 7440-41-7 Cadmium ND ug/L 0.080 0.060 1 10/10/18 22:30 10/12/18 14:07 7440-43-9 Chromium 0.56 ug/L 0.50 0.10 1 10/10/18 22:30 10/12/18 14:07 7440-47-3 Cobalt 0.15 ug/L 0.10 0.010 1 10/10/18 22:30 10/12/18 14:07 7440-48-4 Copper 0.34J ug/L 0.50 0.12 1 10/10/18 22:30 10/12/18 14:07 7440-50-8 B Lead 0.098J ug/L 0.10 0.080 1 10/10/18 22:30 10/12/18 14:07 7439-92-1 Nickel ND ug/L 0.50 0.45 1 10/10/18 22:30 10/12/18 14:07 7440-02-0 Selenium ND ug/L 0.50 0.32 1 10/10/18 22:30 10/12/18 14:07 7782-49-2 Silver ND ug/L 0.40 0.080 1 10/10/18 22:30 10/12/18 14:07 7440-22-4 Thallium ND ug/L 0.10 0.020 1 10/10/18 22:30 10/12/18 14:07 7440-28-0 Vanadium 2.5 ug/L 0.30 0.070 1 10/10/18 22:30 10/12/18 14:07 7440-62-2 Zinc 3.8J ug/L 5.0 2.4 1 10/10/18 22:30 10/12/18 14:07 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 10/16/18 20:44 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 50-150 1 10/16/18 20:44 17060-07-0 Toluene-d8 (S) 113 % 50-150 1 10/16/18 20:44 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 10/13/18 08:27 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/13/18 08:27 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/13/18 08:27 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/13/18 08:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/13/18 08:27 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/13/18 08:27 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/13/18 08:27 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/13/18 08:27 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/13/18 08:27 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/13/18 08:27 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/13/18 08:27 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/13/18 08:27 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/13/18 08:27 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/13/18 08:27 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 10/13/18 08:27 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/13/18 08:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 10/13/18 08:27 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 10/13/18 08:27 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 10/13/18 08:27 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 10/13/18 08:27 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 10/13/18 08:27 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Sample: 1403-MW1R2 Lab ID: 2610240001 Collected: 10/08/18 09:33 Received: 10/09/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 10/17/2018 11:49 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 10/13/18 08:27 75-34-3 ND ug/L 1.0 0.67 1 10/13/18 08:27 107-06-2 ND ug/L 5.0 0.72 1 10/13/18 08:27 75-35-4 ND ug/L 5.0 0.66 1 10/13/18 08:27 156-59-2 ND ug/L 5.0 0.46 1 10/13/18 08:27 156-60-5 ND ug/L 1.0 0.60 1 10/13/18 08:27 78-87-5 ND ug/L 1.0 0.22 1 10/13/18 08:27 10061-01-5 ND ug/L 1.0 0.30 1 10/13/18 08:27 10061-02-6 ND ug/L 1.0 0.45 1 10/13/18 08:27 100-41-4 ND ug/L 50.0 0.89 1 10/13/18 08:27 591-78-6 ND ug/L 10.0 3.1 1 10/13/18 08:27 74-88-4 ND ug/L 1.0 0.50 1 10/13/18 08:27 75-09-2 ND ug/L 100 0.86 1 10/13/18 08:27 108-10-1 ND ug/L 1.0 0.50 1 10/13/18 08:27 100-42-5 ND ug/L 5.0 0.32 1 10/13/18 08:27 630-20-6 ND ug/L 3.0 0.53 1 10/13/18 08:27 79-34-5 ND ug/L 1.0 0.78 1 10/13/18 08:27 127-18-4 ND ug/L 1.0 0.31 1 10/13/18 08:27 108-88-3 ND ug/L 1.0 0.38 1 10/13/18 08:27 71-55-6 ND ug/L 1.0 0.59 1 10/13/18 08:27 79-00-5 ND ug/L 1.0 0.34 1 10/13/18 08:27 79-01-6 ND ug/L 1.0 0.51 1 10/13/18 08:27 75-69-4 ND ug/L 1.0 0.46 1 10/13/18 08:27 96-18-4 ND ug/L 50.0 0.42 1 10/13/18 08:27 108-05-4 ND ug/L 1.0 0.60 1 10/13/18 08:27 75-01-4 ND ug/L 5.0 1.5 1 10/13/18 08:27 1330-20-7 102 %. 81-119 1 10/13/18 08:27 17060-07-0 93 %. 82-114 1 10/13/18 08:27 1868-53-7 106 %. 82-120 1 10/13/18 08:27 460-00-4 99 %. 82-109 1 10/13/18 08:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Sample: 1403-MW11 Lab ID: 2610240002 Collected: 10/08/18 10:38 Received: 10/09/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Antimony ND ug/L 0.50 0.10 1 10/10/18 22:30 10/12/18 14:20 7440-36-0 Arsenic ND ug/L 0.10 0.050 1 10/10/18 22:30 10/12/18 14:20 7440-38-2 Barium 50.9 ug/L 0.30 0.11 1 10/10/18 22:30 10/12/18 14:20 7440-39-3 Beryllium ND ug/L 0.10 0.020 1 10/10/18 22:30 10/12/18 14:20 7440-41-7 Cadmium ND ug/L 0.080 0.060 1 10/10/18 22:30 10/12/18 14:20 7440-43-9 Chromium ND ug/L 0.50 0.10 1 10/10/18 22:30 10/12/18 14:20 7440-47-3 Cobalt 0.55 ug/L 0.10 0.010 1 10/10/18 22:30 10/12/18 14:20 7440-48-4 Copper 0.18J ug/L 0.50 0.12 1 10/10/18 22:30 10/12/18 14:20 7440-50-8 B Lead ND ug/L 0.10 0.080 1 10/10/18 22:30 10/12/18 14:20 7439-92-1 Nickel 2.3 ug/L 0.50 0.45 1 10/10/18 22:30 10/12/18 14:20 7440-02-0 Selenium ND ug/L 0.50 0.32 1 10/10/18 22:30 10/12/18 14:20 7782-49-2 Silver ND ug/L 0.40 0.080 1 10/10/18 22:30 10/12/18 14:20 7440-22-4 Thallium ND ug/L 0.10 0.020 1 10/10/18 22:30 10/12/18 14:20 7440-28-0 Vanadium 0.26J ug/L 0.30 0.070 1 10/10/18 22:30 10/12/18 14:20 7440-62-2 Zinc 4.2J ug/L 5.0 2.4 1 10/10/18 22:30 10/12/18 14:20 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 10/16/18 21:04 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 50-150 1 10/16/18 21:04 17060-07-0 Toluene-d8 (S) 111 % 50-150 1 10/16/18 21:04 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 10/13/18 08:52 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/13/18 08:52 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/13/18 08:52 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/13/18 08:52 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/13/18 08:52 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/13/18 08:52 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/13/18 08:52 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/13/18 08:52 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/13/18 08:52 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/13/18 08:52 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/13/18 08:52 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/13/18 08:52 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/13/18 08:52 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/13/18 08:52 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 10/13/18 08:52 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/13/18 08:52 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 10/13/18 08:52 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 10/13/18 08:52 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 10/13/18 08:52 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 10/13/18 08:52 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 10/13/18 08:52 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Sample: 1403-MW11 Lab ID: 2610240002 Collected: 10/08/18 10:38 Received: 10/09/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 10/17/2018 11:49 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 10/13/18 08:52 75-34-3 ND ug/L 1.0 0.67 1 10/13/18 08:52 107-06-2 ND ug/L 5.0 0.72 1 10/13/18 08:52 75-35-4 ND ug/L 5.0 0.66 1 10/13/18 08:52 156-59-2 ND ug/L 5.0 0.46 1 10/13/18 08:52 156-60-5 ND ug/L 1.0 0.60 1 10/13/18 08:52 78-87-5 ND ug/L 1.0 0.22 1 10/13/18 08:52 10061-01-5 ND ug/L 1.0 0.30 1 10/13/18 08:52 10061-02-6 ND ug/L 1.0 0.45 1 10/13/18 08:52 100-41-4 ND ug/L 50.0 0.89 1 10/13/18 08:52 591-78-6 ND ug/L 10.0 3.1 1 10/13/18 08:52 74-88-4 ND ug/L 1.0 0.50 1 10/13/18 08:52 75-09-2 ND ug/L 100 0.86 1 10/13/18 08:52 108-10-1 ND ug/L 1.0 0.50 1 10/13/18 08:52 100-42-5 ND ug/L 5.0 0.32 1 10/13/18 08:52 630-20-6 ND ug/L 3.0 0.53 1 10/13/18 08:52 79-34-5 ND ug/L 1.0 0.78 1 10/13/18 08:52 127-18-4 ND ug/L 1.0 0.31 1 10/13/18 08:52 108-88-3 ND ug/L 1.0 0.38 1 10/13/18 08:52 71-55-6 ND ug/L 1.0 0.59 1 10/13/18 08:52 79-00-5 ND ug/L 1.0 0.34 1 10/13/18 08:52 79-01-6 ND ug/L 1.0 0.51 1 10/13/18 08:52 75-69-4 ND ug/L 1.0 0.46 1 10/13/18 08:52 96-18-4 ND ug/L 50.0 0.42 1 10/13/18 08:52 108-05-4 ND ug/L 1.0 0.60 1 10/13/18 08:52 75-01-4 ND ug/L 5.0 1.5 1 10/13/18 08:52 1330-20-7 104 %. 81-119 1 10/13/18 08:52 17060-07-0 101 %. 82-114 1 10/13/18 08:52 1868-53-7 111 %. 82-120 1 10/13/18 08:52 460-00-4 100 %. 82-109 1 10/13/18 08:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 QC Batch: 435604 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 2610240001, 2610240002 METHOD BLANK: 2397514 Associated Lab Samples: 2610240001, 2610240002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 0.50 0.10 10/12/1815:21 Arsenic ug/L ND 0.10 0.050 10/12/1815:21 Barium ug/L 0.111 0.30 0.11 10/12/18 15:21 Beryllium ug/L ND 0.10 0.020 10/12/1815:21 Cadmium ug/L ND 0.080 0.060 10/12/1815:21 Chromium ug/L ND 0.50 0.10 10/12/1815:21 Cobalt ug/L ND 0.10 0.010 10/12/1815:21 Copper ug/L 0.20J 0.50 0.12 10/12/1815:21 Lead ug/L ND 0.10 0.080 10/12/1815:21 Nickel ug/L ND 0.50 0.45 10/12/1815:21 Selenium ug/L ND 0.50 0.32 10/12/1815:21 Silver ug/L ND 0.40 0.080 10/12/1815:21 Thallium ug/L ND 0.10 0.020 10/12/1815:21 Vanadium ug/L ND 0.30 0.070 10/12/1815:21 Zinc ug/L ND 5.0 2.4 10/12/1815:21 LABORATORY CONTROL SAMPLE: Parameter 2397515 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 105 105 80-120 Arsenic ug/L 10 10.3 103 80-120 Barium ug/L 50 50.3 101 80-120 Beryllium ug/L 10 10.2 102 80-120 Cadmium ug/L 10 10.0 100 80-120 Chromium ug/L 50 52.1 104 80-120 Cobalt ug/L 10 10.4 104 80-120 Copper ug/L 50 52.8 106 80-120 Lead ug/L 50 50.1 100 80-120 Nickel ug/L 50 52.6 105 80-120 Selenium ug/L 50 50.7 101 80-120 Silver ug/L 25 24.8 99 80-120 Thallium ug/L 10 10 100 80-120 Vanadium ug/L 50 52.1 104 80-120 Zinc ug/L 50 54.0 108 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Republic Foothills NC-1403 2610240 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2397516 2397517 MS MSD 2610240001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 102 103 102 103 75-125 1 20 Arsenic ug/L 0.11 10 10 10.1 10.1 100 100 75-125 0 20 Barium ug/L 30.0 50 50 79.0 79.8 98 100 75-125 1 20 Beryllium ug/L ND 10 10 9.9 9.9 99 99 75-125 0 20 Cadmium ug/L ND 10 10 10.1 10.1 101 101 75-125 0 20 Chromium ug/L 0.56 50 50 51.8 51.8 103 103 75-125 0 20 Cobalt ug/L 0.15 10 10 10.4 10.5 103 103 75-125 1 20 Copper ug/L 0.34J 50 50 52.4 52.9 104 105 75-125 1 20 Lead ug/L 0.098J 50 50 50.8 51.0 101 102 75-125 0 20 Nickel ug/L ND 50 50 51.8 52.1 103 104 75-125 1 20 Selenium ug/L ND 50 50 48.1 48.2 96 96 75-125 0 20 Silver ug/L ND 25 25 24.9 24.9 100 100 75-125 0 20 Thallium ug/L ND 10 10 10.2 10.2 102 102 75-125 1 20 Vanadium ug/L 2.5 50 50 53.8 54.1 103 103 75-125 1 20 Zinc ug/L 3.8J 50 50 54.8 55.5 102 104 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 QC Batch: 436401 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2610240001, 2610240002 METHOD BLANK: 2401092 Matrix: Water Associated Lab Samples: 2610240001, 2610240002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 10/16/18 12:37 1,2-Dichloroethane-d4 (S) % 101 50-150 10/16/18 12:37 Toluene-d8 (S) % 112 50-150 10/16/18 12:37 LABORATORY CONTROL SAMPLE: 2401093 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.9 104 71-125 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8 (S) % 111 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2401094 2401096 MS MSD 2610407003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 20.6 20 20 44.3 40.7 119 101 50-150 8 30 1,2-Dichloroethane-d4 (S) % 108 112 50-150 30 Toluene-d8 (S) % 114 117 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 QC Batch: 15334 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2610240001, 2610240002 METHOD BLANK: 68632 Associated Lab Samples: 2610240001, 2610240002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 10/13/18 02:32 1,1,1-Trichloroethane ug/L ND 1.0 0.38 10/13/18 02:32 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 10/13/18 02:32 1,1,2-Trichloroethane ug/L ND 1.0 0.59 10/13/18 02:32 1,1-Dichloroethane ug/L ND 5.0 0.41 10/13/18 02:32 1,1-Dichloroethene ug/L ND 5.0 0.72 10/13/18 02:32 1,2,3-Trichloropropane ug/L ND 1.0 0.46 10/13/18 02:32 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 10/13/18 02:32 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 10/13/18 02:32 1,2-Dichlorobenzene ug/L ND 5.0 0.49 10/13/18 02:32 1,2-Dichloroethane ug/L ND 1.0 0.67 10/13/18 02:32 1,2-Dichloropropane ug/L ND 1.0 0.60 10/13/18 02:32 1,4-Dichlorobenzene ug/L ND 1.0 0.58 10/13/18 02:32 2-Butanone (MEK) ug/L ND 100 3.2 10/13/18 02:32 2-Hexanone ug/L ND 50.0 0.89 10/13/18 02:32 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 10/13/18 02:32 Acetone ug/L ND 100 8.2 10/13/18 02:32 Acrylonitrile ug/L ND 200 2.5 10/13/18 02:32 Benzene ug/L ND 1.0 0.20 10/13/18 02:32 Bromochloromethane ug/L ND 3.0 0.50 10/13/18 02:32 Bromodichloromethane ug/L ND 1.0 0.36 10/13/18 02:32 Bromoform ug/L ND 3.0 0.55 10/13/18 02:32 Bromomethane ug/L ND 10.0 0.95 10/13/18 02:32 Carbon disulfide ug/L ND 100 0.79 10/13/18 02:32 Carbon tetrachloride ug/L ND 1.0 0.42 10/13/18 02:32 Chlorobenzene ug/L ND 3.0 0.53 10/13/18 02:32 Chloroethane ug/L ND 10.0 0.52 10/13/18 02:32 Chloroform ug/L ND 5.0 0.58 10/13/18 02:32 Chloromethane ug/L ND 1.0 0.38 10/13/18 02:32 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 10/13/18 02:32 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 10/13/18 02:32 Dibromochloromethane ug/L ND 3.0 0.31 10/13/18 02:32 Dibromomethane ug/L ND 10.0 0.62 10/13/18 02:32 Ethylbenzene ug/L ND 1.0 0.45 10/13/18 02:32 lodomethane ug/L ND 10.0 3.1 10/13/18 02:32 Methylene Chloride ug/L ND 1.0 0.50 10/13/18 02:32 Styrene ug/L ND 1.0 0.50 10/13/18 02:32 Tetrachloroethene ug/L ND 1.0 0.78 10/13/18 02:32 Toluene ug/L ND 1.0 0.31 10/13/18 02:32 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 10/13/18 02:32 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 10/13/18 02:32 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 METHOD BLANK: 68632 Associated Lab Samples: Parameter 2610240001, 2610240002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 10/13/18 02:32 Trichloroethene ug/L ND 1.0 0.34 10/13/18 02:32 Trichlorofluoromethane ug/L ND 1.0 0.51 10/13/18 02:32 Vinyl acetate ug/L ND 50.0 0.42 10/13/18 02:32 Vinyl chloride ug/L ND 1.0 0.60 10/13/18 02:32 Xylene (Total) ug/L ND 5.0 1.5 10/13/18 02:32 1,2-Dichloroethane-d4 (S) %. 94 81-119 10/13/18 02:32 4-Bromofluorobenzene (S) %. 109 82-120 10/13/18 02:32 Dibromofluoromethane (S) %. 93 82-114 10/13/18 02:32 Toluene-d8 (S) %. 101 82-109 10/13/18 02:32 LABORATORY CONTROL SAMPLE: Parameter 68633 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 44.6 89 68-137 1,1,1-Trichloroethane ug/L 50 48.5 97 72-134 1,1,2,2-Tetrachloroethane ug/L 50 52.7 105 51-158 1,1,2-Trichloroethane ug/L 50 48.4 97 78-131 1,1-Dichloroethane ug/L 50 56.0 112 69-151 1,1-Dichloroethene ug/L 50 56.3 113 64-158 1,2,3-Trichloropropane ug/L 50 47.2 94 78-133 1,2-Dibromo-3-chloropropane ug/L 50 52.8 106 58-124 1,2-Dibromoethane (EDB) ug/L 50 46.4 93 71-134 1,2-Dichlorobenzene ug/L 50 54.5 109 70-135 1,2-Dichloroethane ug/L 50 52.8 106 72-129 1,2-Dichloropropane ug/L 50 53.9 108 64-135 1,4-Dichlorobenzene ug/L 50 49.5 99 70-131 2-Butanone (MEK) ug/L 100 96.2J 96 52-143 2-Hexanone ug/L 100 94.8 95 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 85.7J 86 71-129 Acetone ug/L 100 118 118 48-224 Acrylonitrile ug/L 200 195J 98 66-154 Benzene ug/L 50 52.2 104 68-132 Bromochloromethane ug/L 50 48.2 96 73-133 Bromodichloromethane ug/L 50 44.8 90 67-121 Bromoform ug/L 50 44.8 90 57-125 Bromomethane ug/L 50 54.0 108 35-156 Carbon disulfide ug/L 100 88.2J 88 47-141 Carbon tetrachloride ug/L 50 48.6 97 66-122 Chlorobenzene ug/L 50 52.9 106 71-126 Chloroethane ug/L 50 47.5 95 43-143 Chloroform ug/L 50 50.7 101 71-136 Chloromethane ug/L 50 46.9 94 47-123 cis-1,2-Dichloroethene ug/L 50 53.0 106 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 LABORATORY CONTROL SAMPLE: 68633 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 46.5 93 78-120 Dibromochloromethane ug/L 50 44.4 89 65-115 Dibromomethane ug/L 50 50.7 101 79-129 Ethylbenzene ug/L 50 53.5 107 68-129 lodomethane ug/L 100 78.6 79 49-154 Methylene Chloride ug/L 50 51.3 103 61-147 Styrene ug/L 50 50.4 101 77-128 Tetrachloroethene ug/L 50 35.7 71 51-139 Toluene ug/L 50 54.2 108 60-133 trans-1,2-Dichloroethene ug/L 50 52.5 105 69-144 trans- 1,3-Dichloropropene ug/L 50 41.1 82 74-128 trans-1,4-Dichloro-2-butene ug/L 100 92.9J 93 61-139 Trichloroethene ug/L 50 51.8 104 73-126 Trichlorofluoromethane ug/L 50 56.4 113 55-132 Vinyl acetate ug/L 50 57.6 115 52-141 Vinyl chloride ug/L 50 51.0 102 50-133 Xylene (Total) ug/L 150 151 100 78-132 1,2-Dichloroethane-d4 (S) %. 102 81-119 4-Bromofluorobenzene (S) %. 97 82-120 Dibromofluoromethane (S) %. 106 82-114 Toluene-d8 (S) %. 99 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 68634 68635 MS MSD 2610090001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 40.1 41.7 80 83 68-137 4 11 1,1,1-Trichloroethane ug/L ND 50 50 48.7 49.3 97 99 66-142 1 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 49.8 51.6 100 103 39-171 4 13 1,1,2-Trichloroethane ug/L ND 50 50 43.8 44.4 88 89 73-136 1 12 1,1-Dichloroethane ug/L 2.7 50 50 80.8 60.0 156 115 66-155 30 15 M1,R1 1,1-Dichloroethene ug/L ND 50 50 57.8 62.0 116 124 33-181 7 34 1,2,3-Trichloropropane ug/L ND 50 50 41.8 44.4 84 89 78-133 6 14 1,2-Dibromo-3- ug/L ND 50 50 45.0 44.5 90 89 58-124 1 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 41.8 43.3 84 87 71-134 4 12 1,2-Dichlorobenzene ug/L ND 50 50 48.1 47.4 96 95 69-135 2 10 1,2-Dichloroethane ug/L ND 50 50 49.2 49.8 98 100 36-159 1 10 1,2-Dichloropropane ug/L ND 50 50 48.3 51.1 97 102 68-132 6 11 1,4-Dichlorobenzene ug/L ND 50 50 45.0 44.2 88 87 49-153 2 9 2-Butanone (MEK) ug/L ND 100 100 79.5J 80.3J 80 80 10-189 1 23 2-Hexanone ug/L ND 100 100 74.2 76.9 74 77 40-135 4 18 4-Methyl-2-pentanone ug/L ND 100 100 76.5J 77.6J 76 78 30-177 1 10 (MIBK) Acetone ug/L ND 100 100 143 154 81 92 44-223 8 14 Acrylonitrile ug/L ND 200 200 166J 187J 83 93 13-189 12 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Republic Foothills NC-1403 Pace Project No.: 2610240 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 68634 68635 MS MSD 2610090001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Benzene ug/L ND 50 50 52.8 52.8 104 104 66-139 0 10 Bromochloromethane ug/L ND 50 50 42.6 44.7 85 89 73-133 5 13 Bromodichloromethane ug/L ND 50 50 39.8 42.3 80 85 57-120 6 13 Bromoform ug/L ND 50 50 37.5 38.6 75 77 48-128 3 13 Bromomethane ug/L ND 50 50 42.0 43.3 84 87 10-187 3 32 Carbon disulfide ug/L ND 100 100 90.91 95.2J 91 95 47-141 5 322 Carbon tetrachloride ug/L ND 50 50 51.1 51.2 102 102 58-127 0 14 Chlorobenzene ug/L ND 50 50 48.8 49.3 96 97 63-137 1 10 Chloroethane ug/L ND 50 50 48.4 51.8 93 100 52-146 7 16 Chloroform ug/L ND 50 50 48.5 49.7 97 99 74-137 2 9 Chloromethane ug/L ND 50 50 44.6 47.8 89 96 41-127 7 10 cis-1,2-Dichloroethene ug/L 16.2 50 50 68.0 71.3 104 110 71-138 5 16 cis-1,3-Dichloropropene ug/L ND 50 50 38.4 40.3 77 81 32-145 5 12 Dibromochloromethane ug/L ND 50 50 38.7 38.5 77 77 52-116 1 13 Dibromomethane ug/L ND 50 50 42.5 43.8 85 88 79-129 3 14 Ethylbenzene ug/L ND 50 50 50.3 50.7 101 101 31-174 1 10 lodomethane ug/L ND 100 100 69.4 85.9 69 86 49-154 21 30 Methylene Chloride ug/L ND 50 50 48.4 50.2 97 100 61-146 4 15 Styrene ug/L ND 50 50 43.8 46.0 88 92 77-128 5 14 Tetrachloroethene ug/L ND 50 50 35.4 35.3 68 68 36-155 0 14 Toluene ug/L ND 50 50 51.1 52.5 102 105 52-146 3 11 trans-1,2-Dichloroethene ug/L ND 50 50 52.9 54.0 106 108 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 34.9 35.7 70 71 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 80.01 84.9J 80 85 61-139 6 12 Trichloroethene ug/L 2.6 50 50 52.5 53.3 100 102 61-141 2 12 Trichlorofluoromethane ug/L ND 50 50 67.6 69.7 135 139 51-141 3 13 Vinyl acetate ug/L ND 50 50 41.1J 35.1J 82 70 52-141 16 14 R1 Vinyl chloride ug/L ND 50 50 53.7 59.5 104 116 22-156 10 26 Xylene (Total) ug/L ND 150 150 138 140 92 93 78-132 2 7 1,2-Dichloroethane-d4 (S) %. 103 103 81-119 4-Bromofluorobenzene (S) %. 98 99 82-120 Dibromofluoromethane (S) %. 107 107 82-114 Toluene-d8 (S) %. 95 99 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Republic Foothills NC-1403 Pace Project No.: 2610240 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/17/2018 11:49 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Republic Foothills NC-1403 Pace Project No.: 2610240 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2610240001 1403-MW1 R2 EPA 3010A 435604 EPA 6020B 435643 2610240002 1403-MW11 EPA 3010A 435604 EPA 6020B 435643 2610240001 1403-MW1 R2 EPA 8260B Mod. 436401 2610240002 1403-MW11 EPA 8260B Mod. 436401 2610240001 1403-MW1 R2 EPA 8260B 15334 2610240002 1403-MW11 EPA 8260B 15334 Date: 10/17/2018 11:49 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 19 N m O O M d u w E Z 0 w v ❑ @ U - w N L fY F-- L.7 . . w o IL N cc U W 0 N U iL Z 2 L? 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I W _ � � PM: Courier: 'Fed Ex •] UPS ❑LISPS --,' Client �Cer-+r•er 1al — Pace Other CLIENT: Tracking 0: �1 n L6 LY 49 rr Custody Seal on Cooler/Box Present: —5 _ rc se.a's IntaCT r. Packing} Material: Bucola wrap : f5bble Bags � ',•_-ne _ Omer Thermometer Used Type of Ice: ;ar Blue •Jane Sarripr dBiological Tissue is Frozen: � Da Cooler Temperature -� �- c TQmp should he atone froo.ing to 61, Comments: A [� � •26102TW ' MM Due Dale: 101 Republic -NC rr0I, N7mL'; -+) : :Doling pmcess has tegun and Initia�n examining nts� ten [/• (/ Chain of Cut ;Llad+ Present:"• - ` -' ' I Chain of Custody Filled Out' Chain of Cu tody Relinquished; 3 Sampler Na 1@ & Signature on COC: ENO 4 Samples A ived within Hold Time: N.A -- Short Hold ime Analysis <72hr}; ,=+r Rush Turn round Time Requested: Sufficient V lume Vies - x. Correct Can -Pace C ainers Used: stainers Used: A. �`v�s —F,r. _."+ •1 g SAMPLE CO TAINER ilnared voluka received tar Dissolved tests Sarnpte Lac lnCludes 1,41 is match COC J4= -"•- -"'' 1 date,t:me,IO:Anafvs:s Nfatr+x; \A -. .•:r:.3 Pill:; 17 ^. ]`. _ udyn-raCk,� , Al l =ntarn?rs�naeuing preserimicn are found .Ll to in campliance .%lth EPA mrominr.anaahun. -:x,:epircns. C rrlcr.^ T �C 73+i. !r'• ar „water f — '= —l`r :ar^Gle[ 'd pra.�r. ri•,� Samples chocked for decNorination. _ _ - ,•, 14 Heads ace rn VDA Vials i >6mm1 _ ; Trip Blank P Trip Blank C Pace Trip BI -esent s,cdy Seals Present ink Lot 9 (it purchase& -. : • +. �. 1 ,. Client Notification/ Person Comment Resolution; Contacted RosaiuTior, ❑•; re. Tir*,,S F el, C its +?r [;uir+ri' N Project Manager Review: �Icta Mh@rever rrgre -s i Jr3creram'I .VvarCn9 %crrh 'ar^,rina -.'rrCi+ary _ ldr cl-.• I -r. . arlfit, aIscr ;fli;@ ;ut :I r•nlr, r::rrort ❑r.)igrdITrn3 :k,r -r r.,rrp r, r•,. ;r[airNr I ate: r "Page 19 231 B )f 19 SITE NAME FOOTHILLS LF POINT ID: IVlW - l R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV SAMPLE MATRIX: GROUNDWATER LAB SAMPLE 1 PROJECT #: EVACUATION INFORMATION E S & S - B.CHIODO UA INITIAL WATER LEVEL (FT): DEPTH TO BOTTOM (FT).- ELEV., MEAS. PT. (MSL): ELEVATION, GIW (MSQ: p DATE 10 - TIME: START/FINISH- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } NO { } S.S. BAILER (X) QED WW PUMP ( } OTHER WELL RISER DIAMETER (IN.): (X) 2 { } 3 ( ) 4 ( } g [ ] OTHER ONE (1) RISER VOLUME (GAL) 3,91 WAS WELL PURGED TO DRYNESS ( ) YES (X) NO TOTAL VOL. EVACUATED (GAL) '2. 50 WATER LEVEL END PURGE (FT) )9i, 7 9 TURBIDITY OF PURGINGS: START G (.r--ARL FINISH C LEA9- EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX D.O. TIME (ML I MIN) F7 VOL GAL C (Std.Units) (umhoslcm) {NTU) eh mV MG/L 9: 3 250 1z �'i 0 1?.� 6.Ya ial.3 3.5S 4338 Yso $'.'5 7 250 Ig, 0 0.25 A--3 Ca. 3 0 1 250 MIA 0.50 1 L, 3 �o . 3'j 1 0 6- 9 5, 2 Y +yv. 2- 1. 3 2 4l;o5, 250 l&7Z 0.75 1G.Y 6-1-7 Ivy. j/ 1oc' k 3 ( C)"o 1 250 4,751 1.00 Irv. `f I? . 2 C, 103. $ 3 `/$ 1 . 19 13 250 ls:7I. 1 1.25 1 V. Lf 103.2 3.100 t �2. 3 1. 2,1 17 250 0071 1.50 1(0.5 4• ay 1.03,1 3.0(. *97 I. 7 �'.2-1 250 1fr,77 1.75 l6. 5 6,23 10 2. 9 2.97 Y3. 250 M-171 2.00 (b.S 6.23 10z7 2.°jy 4-y37 250 l$,79 2.25 16, 6. Z- f D -2.9 v +'137 1.2� °1 33 250 IA71 2.50 !G-5 &.22 j02.6 .2.$Sr +cly.o /.z� SAMPLING INFORMATION DATE/TIME 1 -f 1 1. 33 DEPTH TO GROUNDWATER (FT) 79 METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QED WW PUMP ( ) OTHER { } NO GENERAL INFORMATION [� OF WEATHER CONDITIONS AT TIME OF SAMPLING: 7Q SAMPLE CHARACTERISTICS: L uw COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER l SITE NAME FOOTHILLS LF POINT ID: MW - 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT)--- ELEV., MEAS. PT. {MSL}; _ DATE I r FIELD REPRESENTATIV LAB SAMPLE I PROJECT #: E S & S - B.CHIODO NA DEPTH TO BOTTOM (FT): / 0 0- Yo ELEVATION, G1W (MSL): TIME: START/FINISH '? 579 METHOD OF EVACUATION: { } PVC BAILER ( ) S.S. BAILER { ) GRUNDFOS PUMP EVACUATION EQUIPMENT DEDICATED: (X) YES NO { } S.S. BAILER (X) QED WW PUMP ( } OTHER { ) WELL RISER DIAMETER (IN.): (X) 2 { } 3 [ } 4 [ } 6 [ } OTHER ONE (1) RISER VOLUME (GAL) 4j. LP WAS WELL PURGED TO DRYNESS { } YES (X) NO TOTAL VOL. EVACUATED (GAL) a• �� WATER LEVEL END PURGE (FT) 8/. IS, TURBIDITY OF PURGINGS: START C. L6w- FINISH [F�►e EVACUATION STABILIZATION DATA PURGE RATE DTW CUMUL. TEMP. pH CONDUCT. TURBIDITY REDOX ML 1 MIN FT VOL (GAL C Std.Units (umhoslcm) NTU eh mVGIL ID.O,TIME T s$ 250 8mll 0 17.) HIv + io:oZ, 2501.32 0.25 l(p, Lf v.Co o Sy.n 250 1.3G 0.50 I'O. i 6.G:R Sy. 1.70 ly.S' 1. Ism 250 801 0.75 IG. b (,.7 Sy. t 7-2 �lG.L 1_04 250 9)"Ill 1.00 i�.�. G.Sro sy. Z 1_68 t13.& 407 to •+$ 250 )mZ 1 1.25 .y 1 71 +13 0 1_oG 250 81,qll 1.50 l i7 • (" k 7- sy. If r- 73 t 12.9 u y I v" Z1. 250 81-44 1.75 1 b -7 6, $ 3 1. 7 t12 oy io =3a 250 8).4s 2.00 l(,.-7 J_ 7a tr2. y 103 t o :34 250 S).q5 2.25 1 G.-7 (O • g3 4-12,,7 o 101, 38 250 9"s 2.5a I .7 �. F,; y S�. 1.'73 t r1. �. SAMPLING INFORMATION DATE I TIME 10 -k -!$ 1 1039 DEPTH TO GROUNDWATER (FT)�. �S METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( ) GRUNDFOS PUMP (X) YES { } S.S. BAILER (X) QE❑ WW PUMP { } OTHER { } NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME o 54fjw 70 OF SAMPLING: SAMPLE CHARACTERISTICS: C CEAZ COMMENTS: APPENDIX I LIST SAMPLE COLLECTION NUMBER lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 December 19, 2018 Environmental Manager Foothills Environmental Landfill 2800 Cheraw Road Lenoir, NC 28645 RE: Project: Foothills LF Pace Project No.: 2612158 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on December 04, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Data Manager, TriHydro Corporation REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Foothills LF Pace Project No.: 2612158 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Texas Certification #: T104704397-08-TX Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Foothills LF Pace Project No.: 2612158 Lab ID Sample ID Matrix Date Collected Date Received 2612158001 2612158002 1403-MW1R2 1403-MW11 Water Water 12/03/18 08:12 12/03/18 07:10 12/04/18 09:35 12/04/18 09:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Foothills LF Pace Project No.: 2612158 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2612158001 1403-MW1R2 EPA6020B CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG, LIH 53 PASI-GA 2612158002 1403-MW11 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG, LIH 51 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF Pace Project No.: 2612158 Sample: 1403-MW1R2 Lab ID: 2612158001 Collected: 12/03/18 08:12 Received: 12/04/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/07/18 12:39 12/07/18 20:09 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/07/18 12:39 12/07/18 20:09 7440-38-2 Barium 35.OJ ug/L 100 0.78 1 12/07/18 12:39 12/07/18 20:09 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 12/07/18 12:39 12/07/18 20:09 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/07/18 12:39 12/07/18 20:09 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/07/18 12:39 12/07/18 20:09 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 12/07/18 12:39 12/07/18 20:09 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/07/18 12:39 12/07/18 20:09 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/07/18 12:39 12/07/18 20:09 7439-92-1 Nickel ND ug/L 50.0 0.95 1 12/07/18 12:39 12/07/18 20:09 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/07/18 12:39 12/07/18 20:09 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/07/18 12:39 12/07/18 20:09 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/07/18 12:39 12/07/18 20:09 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/07/18 12:39 12/07/18 20:09 7440-62-2 Zinc 2.4J ug/L 10.0 2.1 1 12/07/18 12:39 12/07/18 20:09 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/07/18 15:57 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 102 % 50-150 1 12/07/18 15:57 17060-07-0 Toluene-d8 (S) 118 % 50-150 1 12/07/18 15:57 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/17/18 14:00 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/17/18 14:00 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/17/18 14:00 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/17/18 14:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/17/18 14:00 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/17/18 14:00 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/17/18 14:00 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/17/18 14:00 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/17/18 14:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/17/18 14:00 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/17/18 14:00 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/17/18 14:00 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/18/1811:42 67-66-3 H1 Chloromethane ND ug/L 1.0 0.38 1 12/17/18 14:00 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 12/17/18 14:00 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 12/17/18 14:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 12/17/18 14:00 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 12/17/18 14:00 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 12/17/18 14:00 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 12/17/18 14:00 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 12/17/18 14:00 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF Pace Project No.: 2612158 Sample: 1403-MW1R2 Lab ID: 2612158001 Collected: 12/03/18 08:12 Received: 12/04/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 12/19/2018 08:49 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 12/17/1814:00 75-34-3 ND ug/L 1.0 0.67 1 12/17/1814:00 107-06-2 ND ug/L 5.0 0.72 1 12/17/1814:00 75-35-4 ND ug/L 5.0 0.66 1 12/17/1814:00 156-59-2 ND ug/L 5.0 0.46 1 12/17/1814:00 156-60-5 ND ug/L 1.0 0.60 1 12/17/1814:00 78-87-5 ND ug/L 1.0 0.22 1 12/17/1814:00 10061-01-5 ND ug/L 1.0 0.30 1 12/17/1814:00 10061-02-6 ND ug/L 1.0 0.45 1 12/17/1814:00 100-41-4 ND ug/L 50.0 0.89 1 12/17/1814:00 591-78-6 ND ug/L 10.0 3.1 1 12/17/1814:00 74-88-4 ND ug/L 1.0 0.50 1 12/17/1814:00 75-09-2 ND ug/L 100 0.86 1 12/17/1814:00 108-10-1 ND ug/L 1.0 0.50 1 12/17/1814:00 100-42-5 ND ug/L 5.0 0.32 1 12/17/1814:00 630-20-6 ND ug/L 3.0 0.53 1 12/17/1814:00 79-34-5 ND ug/L 1.0 0.78 1 12/17/1814:00 127-18-4 ND ug/L 1.0 0.31 1 12/17/1814:00 108-88-3 ND ug/L 1.0 0.38 1 12/17/1814:00 71-55-6 ND ug/L 1.0 0.59 1 12/17/1814:00 79-00-5 ND ug/L 1.0 0.34 1 12/17/1814:00 79-01-6 ND ug/L 1.0 0.51 1 12/17/1814:00 75-69-4 ND ug/L 1.0 0.46 1 12/17/1814:00 96-18-4 ND ug/L 50.0 0.42 1 12/17/1814:00 108-05-4 ND ug/L 1.0 0.60 1 12/17/1814:00 75-01-4 ND ug/L 5.0 1.5 1 12/17/1814:00 1330-20-7 ND ug/L 1.0 0.92 1 12/17/1814:00 179601-23-1 ND ug/L 1.0 0.54 1 12/17/1814:00 95-47-6 105 %. 81-119 1 12/17/1814:00 17060-07-0 100 %. 82-114 1 12/17/1814:00 1868-53-7 102 %. 82-120 1 12/17/1814:00 460-00-4 94 %. 82-109 1 12/17/1814:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF Pace Project No.: 2612158 Sample: 1403-MW11 Lab ID: 2612158002 Collected: 12/03/18 07:10 Received: 12/04/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/07/18 12:39 12/07/18 20:14 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/07/18 12:39 12/07/18 20:14 7440-38-2 Barium 53.OJ ug/L 100 0.78 1 12/07/18 12:39 12/07/18 20:14 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 12/07/18 12:39 12/07/18 20:14 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/07/18 12:39 12/07/18 20:14 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/07/18 12:39 12/07/18 20:14 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 12/07/18 12:39 12/07/18 20:14 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/07/18 12:39 12/07/18 20:14 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/07/18 12:39 12/07/18 20:14 7439-92-1 Nickel 1.2J ug/L 50.0 0.95 1 12/07/18 12:39 12/07/18 20:14 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/07/18 12:39 12/07/18 20:14 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/07/18 12:39 12/07/18 20:14 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/07/18 12:39 12/07/18 20:14 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/07/18 12:39 12/07/18 20:14 7440-62-2 Zinc 3.2J ug/L 10.0 2.1 1 12/07/18 12:39 12/07/18 20:14 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/07/18 14:59 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 50-150 1 12/07/18 14:59 17060-07-0 Toluene-d8 (S) 114 % 50-150 1 12/07/18 14:59 2037-26-5 8260B MSV Water, Extend Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/17/18 14:30 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/17/18 14:30 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/17/18 14:30 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/17/18 14:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/17/18 14:30 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/17/18 14:30 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/17/18 14:30 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/17/18 14:30 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/17/18 14:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/17/18 14:30 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/17/18 14:30 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/17/18 14:30 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/18/1812:08 67-66-3 H1 Chloromethane ND ug/L 1.0 0.38 1 12/17/18 14:30 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 12/17/18 14:30 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 12/17/18 14:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 12/17/18 14:30 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 12/17/18 14:30 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 12/17/18 14:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 12/17/18 14:30 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 12/17/18 14:30 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Foothills LF Pace Project No.: 2612158 Sample: 1403-MW11 Lab ID: 2612158002 Collected: 12/03/18 07:10 Received: 12/04/18 09:35 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Water, Extend 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 12/19/2018 08:49 AM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 12/17/1814:30 75-34-3 ND ug/L 1.0 0.67 1 12/17/1814:30 107-06-2 ND ug/L 5.0 0.72 1 12/17/1814:30 75-35-4 ND ug/L 5.0 0.66 1 12/17/1814:30 156-59-2 ND ug/L 5.0 0.46 1 12/17/1814:30 156-60-5 ND ug/L 1.0 0.60 1 12/17/1814:30 78-87-5 ND ug/L 1.0 0.22 1 12/17/1814:30 10061-01-5 ND ug/L 1.0 0.30 1 12/17/1814:30 10061-02-6 ND ug/L 1.0 0.45 1 12/17/1814:30 100-41-4 ND ug/L 50.0 0.89 1 12/17/1814:30 591-78-6 ND ug/L 10.0 3.1 1 12/17/1814:30 74-88-4 ND ug/L 1.0 0.50 1 12/17/1814:30 75-09-2 ND ug/L 100 0.86 1 12/17/1814:30 108-10-1 ND ug/L 1.0 0.50 1 12/17/1814:30 100-42-5 ND ug/L 5.0 0.32 1 12/17/1814:30 630-20-6 ND ug/L 3.0 0.53 1 12/17/1814:30 79-34-5 ND ug/L 1.0 0.78 1 12/17/1814:30 127-18-4 ND ug/L 1.0 0.31 1 12/17/1814:30 108-88-3 ND ug/L 1.0 0.38 1 12/17/1814:30 71-55-6 ND ug/L 1.0 0.59 1 12/17/1814:30 79-00-5 ND ug/L 1.0 0.34 1 12/17/1814:30 79-01-6 ND ug/L 1.0 0.51 1 12/17/1814:30 75-69-4 ND ug/L 1.0 0.46 1 12/17/1814:30 96-18-4 ND ug/L 50.0 0.42 1 12/17/1814:30 108-05-4 ND ug/L 1.0 0.60 1 12/17/1814:30 75-01-4 ND ug/L 5.0 1.5 1 12/17/1814:30 1330-20-7 105 %. 81-119 1 12/17/1814:30 17060-07-0 100 %. 82-114 1 12/17/1814:30 1868-53-7 100 %. 82-120 1 12/17/1814:30 460-00-4 94 %. 82-109 1 12/17/1814:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 QC Batch: 18393 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612158001, 2612158002 METHOD BLANK: 82915 Associated Lab Samples: Parameter 2612158001, 2612158002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 12/07/1817:45 Arsenic ug/L ND 10.0 0.57 12/07/1817:45 Barium ug/L ND 100 0.78 12/07/1817:45 Beryllium ug/L ND 1.0 0.050 12/07/1817:45 Cadmium ug/L ND 1.0 0.093 12/07/1817:45 Chromium ug/L ND 10.0 1.6 12/07/1817:45 Cobalt ug/L ND 10.0 0.52 12/07/1817:45 Copper ug/L ND 10.0 1.3 12/07/1817:45 Lead ug/L ND 10.0 0.27 12/07/1817:45 Nickel ug/L ND 50.0 0.95 12/07/1817:45 Selenium ug/L ND 10.0 1.4 12/07/1817:45 Silver ug/L ND 10.0 0.95 12/07/1817:45 Thallium ug/L ND 5.5 0.14 12/07/1817:45 Vanadium ug/L ND 25.0 1.9 12/07/1817:45 Zinc ug/L ND 10.0 2.1 12/07/1817:45 LABORATORY CONTROL SAMPLE: 82916 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 114 114 80-120 Arsenic ug/L 100 108 108 80-120 Barium ug/L 100 105 105 80-120 Beryllium ug/L 100 110 110 80-120 Cadmium ug/L 100 106 106 80-120 Chromium ug/L 100 108 108 80-120 Cobalt ug/L 100 107 107 80-120 Copper ug/L 100 111 111 80-120 Lead ug/L 100 106 106 80-120 Nickel ug/L 100 108 108 80-120 Selenium ug/L 100 110 110 80-120 Silver ug/L 100 111 111 80-120 Thallium ug/L 100 107 107 80-120 Vanadium ug/L 100 110 110 80-120 Zinc ug/L 100 110 110 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 82980 82981 MS MSD 2612287003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 114 114 114 114 75-125 0 20 Arsenic ug/L ND 100 100 108 109 107 108 75-125 1 20 Barium ug/L 11.6 100 100 115 116 104 105 75-125 1 20 Beryllium ug/L ND 100 100 112 111 111 110 75-125 1 20 Cadmium ug/L ND 100 100 110 107 109 107 75-125 2 20 Chromium ug/L ND 100 100 113 110 110 106 75-125 3 20 Cobalt ug/L ND 100 100 111 109 110 109 75-125 1 20 Copper ug/L ND 100 100 111 112 108 109 75-125 1 20 Lead ug/L ND 100 100 107 105 106 104 75-125 2 20 Nickel ug/L 7.4 100 100 118 115 110 108 75-125 2 20 Selenium ug/L ND 100 100 106 110 106 110 75-125 3 20 Silver ug/L ND 100 100 112 112 112 112 75-125 0 20 Thallium ug/L ND 100 100 107 103 107 103 75-125 3 20 Vanadium ug/L ND 100 100 112 112 111 111 75-125 0 20 Zinc ug/L 24.1 100 100 132 130 108 106 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 QC Batch: 446273 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612158001, 2612158002 METHOD BLANK: 2446001 Matrix: Water Associated Lab Samples: 2612158001, 2612158002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/07/18 11:26 1,2-Dichloroethane-d4 (S) % 97 50-150 12/07/18 11:26 Toluene-d8 (S) % 113 50-150 12/07/18 11:26 LABORATORY CONTROL SAMPLE: 2446002 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.4 87 71-125 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 114 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2446003 2446004 MS MSD 2612158002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 16.6 17.5 82 87 50-150 5 30 1,2-Dichloroethane-d4 (S) % 106 103 50-150 30 Toluene-d8 (S) % 117 116 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 QC Batch: 19028 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Water, Extend Associated Lab Samples: 2612158001, 2612158002 METHOD BLANK: 85961 Associated Lab Samples: 2612158001, 2612158002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 12/17/18 10:53 1,1,1-Trichloroethane ug/L ND 1.0 0.38 12/17/18 10:53 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 12/17/18 10:53 1,1,2-Trichloroethane ug/L ND 1.0 0.59 12/17/18 10:53 1,1-Dichloroethane ug/L ND 5.0 0.41 12/17/18 10:53 1,1-Dichloroethene ug/L ND 5.0 0.72 12/17/18 10:53 1,2,3-Trichloropropane ug/L ND 1.0 0.46 12/17/18 10:53 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 12/17/18 10:53 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 12/17/18 10:53 1,2-Dichlorobenzene ug/L ND 5.0 0.49 12/17/18 10:53 1,2-Dichloroethane ug/L ND 1.0 0.67 12/17/18 10:53 1,2-Dichloropropane ug/L ND 1.0 0.60 12/17/18 10:53 1,4-Dichlorobenzene ug/L ND 1.0 0.58 12/17/18 10:53 2-Butanone (MEK) ug/L ND 100 3.2 12/17/18 10:53 2-Hexanone ug/L ND 50.0 0.89 12/17/18 10:53 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 12/17/18 10:53 Acetone ug/L ND 100 8.2 12/17/18 10:53 Acrylonitrile ug/L ND 200 2.5 12/17/18 10:53 Benzene ug/L ND 1.0 0.20 12/17/18 10:53 Bromochloromethane ug/L ND 3.0 0.50 12/17/18 10:53 Bromodichloromethane ug/L ND 1.0 0.36 12/17/18 10:53 Bromoform ug/L ND 3.0 0.55 12/17/18 10:53 Bromomethane ug/L ND 10.0 0.95 12/17/18 10:53 Carbon disulfide ug/L ND 100 0.79 12/17/18 10:53 Carbon tetrachloride ug/L ND 1.0 0.42 12/17/18 10:53 Chlorobenzene ug/L ND 3.0 0.53 12/17/18 10:53 Chloroethane ug/L ND 10.0 0.52 12/17/18 10:53 Chloroform ug/L ND 5.0 0.58 12/17/18 10:53 Chloromethane ug/L ND 1.0 0.38 12/17/18 10:53 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 12/17/18 10:53 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 12/17/18 10:53 Dibromochloromethane ug/L ND 3.0 0.31 12/17/18 10:53 Dibromomethane ug/L ND 10.0 0.62 12/17/18 10:53 Ethylbenzene ug/L ND 1.0 0.45 12/17/18 10:53 lodomethane ug/L ND 10.0 3.1 12/17/18 10:53 m&p-Xylene ug/L ND 1.0 0.92 12/17/18 10:53 Methylene Chloride ug/L ND 1.0 0.50 12/17/18 10:53 o-Xylene ug/L ND 1.0 0.54 12/17/18 10:53 Styrene ug/L ND 1.0 0.50 12/17/18 10:53 Tetrachloroethene ug/L ND 1.0 0.78 12/17/18 10:53 Toluene ug/L ND 1.0 0.31 12/17/18 10:53 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 METHOD BLANK: 85961 Associated Lab Samples: Parameter 2612158001, 2612158002 Units Matrix: Blank Result Water Reporting Limit MDL trans-1,2-Dichloroethene ug/L ND 5.0 trans- 1,3-Dichloropropene ug/L ND 1.0 trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) %. 104 81-119 4-Bromofluorobenzene (S) %. 100 82-120 Dibromofluoromethane (S) %. 102 82-114 Toluene-d8 (S) %. 98 82-109 Analyzed 0.46 12/17/18 10:53 0.30 12/17/18 10:53 1.6 12/17/18 10:53 0.34 12/17/18 10:53 0.51 12/17/18 10:53 0.42 12/17/18 10:53 0.60 12/17/18 10:53 1.5 12/17/18 10:53 12/17/18 10:53 12/17/18 10:53 12/17/18 10:53 12/17/18 10:53 LABORATORY CONTROL SAMPLE: Parameter 85962 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 46.0 92 68-137 1,1,1-Trichloroethane ug/L 50 53.2 106 72-134 1,1,2,2-Tetrachloroethane ug/L 50 43.5 87 51-158 1,1,2-Trichloroethane ug/L 50 47.5 95 78-131 1,1-Dichloroethane ug/L 50 50.4 101 69-151 1,1-Dichloroethene ug/L 50 54.1 108 64-158 1,2,3-Trichloropropane ug/L 50 41.4 83 78-133 1,2-Dichlorobenzene ug/L 50 45.4 91 70-135 1,2-Dichloroethane ug/L 50 49.8 100 72-129 1,2-Dichloropropane ug/L 50 42.3 85 64-135 1,4-Dichlorobenzene ug/L 50 43.0 86 70-131 2-Butanone (MEK) ug/L 100 93.6J 94 52-143 2-Hexanone ug/L 100 82.5 83 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 85.OJ 85 71-129 Acetone ug/L 100 86.5J 87 48-224 Acrylonitrile ug/L 200 200J 100 66-154 Benzene ug/L 50 46.8 94 68-132 Bromochloromethane ug/L 50 51.6 103 73-133 Bromodichloromethane ug/L 50 45.8 92 67-121 Bromoform ug/L 50 45.3 91 57-125 Bromomethane ug/L 50 42.9 86 35-156 Carbon disulfide ug/L 100 99AJ 99 47-141 Carbon tetrachloride ug/L 50 59.8 120 66-122 Chlorobenzene ug/L 50 44.6 89 71-126 Chloroethane ug/L 50 46.7 93 43-143 Chloroform ug/L 50 48.9 98 71-136 Chloromethane ug/L 50 46.2 92 47-123 cis-1,2-Dichloroethene ug/L 50 48.4 97 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 LABORATORY CONTROL SAMPLE: 85962 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 45.9 92 78-120 Dibromochloromethane ug/L 50 45.4 91 65-115 Dibromomethane ug/L 50 50.5 101 79-129 Ethylbenzene ug/L 50 46.8 94 68-129 lodomethane ug/L 100 92.5 93 49-154 m&p-Xylene ug/L 100 96.2 96 67-137 Methylene Chloride ug/L 50 48.0 96 61-147 o-Xylene ug/L 50 50.1 100 52-141 Styrene ug/L 50 50.1 100 77-128 Tetrachloroethene ug/L 50 51.6 103 51-139 Toluene ug/L 50 46.9 94 60-133 trans-1,2-Dichloroethene ug/L 50 50.6 101 69-144 trans- 1,3-Dichloropropene ug/L 50 43.2 86 74-128 trans-1,4-Dichloro-2-butene ug/L 100 86.2J 86 61-139 Trichloroethene ug/L 50 46.3 93 73-126 Trichlorofluoromethane ug/L 50 59.1 118 55-132 Vinyl acetate ug/L 50 37AJ 75 52-141 Vinyl chloride ug/L 50 50.0 100 50-133 Xylene (Total) ug/L 150 146 98 78-132 1,2-Dichloroethane-d4 (S) %. 107 81-119 4-Bromofluorobenzene (S) %. 98 82-120 Dibromofluoromethane (S) %. 110 82-114 Toluene-d8 (S) %. 98 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 85963 85964 MS MSD 2612302019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 49.3 46.1 99 92 68-137 7 11 1,1,1-Trichloroethane ug/L ND 50 50 62.1 58.6 124 117 66-142 6 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 45.4 42.1 91 84 39-171 7 13 1,1,2-Trichloroethane ug/L ND 50 50 51.7 49.6 103 99 73-136 4 12 1,1-Dichloroethane ug/L ND 50 50 54.5 51.4 109 103 66-155 6 15 1,1-Dichloroethene ug/L ND 50 50 63.5 64.1 127 128 33-181 1 34 1,2,3-Trichloropropane ug/L ND 50 50 38.7 35.7 77 71 78-133 8 14 M1 1,2-Dibromo-3- ug/L ND 50 50 46.0 46.6 92 93 58-124 1 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.4 54.4 113 109 71-134 4 12 1,2-Dichlorobenzene ug/L ND 50 50 46.5 43.2 93 86 69-135 7 10 1,2-Dichloroethane ug/L ND 50 50 57.9 52.8 116 106 36-159 9 10 1,2-Dichloropropane ug/L ND 50 50 46.9 44.4 94 89 68-132 5 11 1,4-Dichlorobenzene ug/L ND 50 50 43.4 40.9 87 82 49-153 6 9 2-Butanone (MEK) ug/L ND 100 100 93.3J 95.2J 93 95 10-189 2 23 2-Hexanone ug/L ND 100 100 96.7 92.6 97 93 40-135 4 18 4-Methyl-2-pentanone ug/L ND 100 100 94.3J 86AJ 94 86 30-177 9 10 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Foothills LF Pace Project No.: 2612158 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 85963 85964 MS MSD 2612302019 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 100 100 104 98.7J 104 99 44-223 5 14 Acrylonitrile ug/L ND 200 200 205 202 103 101 13-189 2 12 Benzene ug/L ND 50 50 52.3 48.9 105 98 66-139 7 10 Bromochloromethane ug/L ND 50 50 53.0 50.8 106 102 73-133 4 13 Bromodichloromethane ug/L ND 50 50 51.1 49.0 102 98 57-120 4 13 Bromoform ug/L ND 50 50 46.8 43.0 94 86 48-128 9 13 Bromomethane ug/L ND 50 50 41.3 46.1 83 92 10-187 11 32 Carbon disulfide ug/L ND 100 100 110 109 110 109 47-141 1 322 Carbon tetrachloride ug/L ND 50 50 73.1 78.0 146 156 58-127 7 14 M1 Chlorobenzene ug/L ND 50 50 46.2 44.5 92 89 63-137 4 10 Chloroethane ug/L ND 50 50 52.0 54.0 104 108 52-146 4 16 Chloroform ug/L ND 50 50 56.7 52.0 113 104 74-137 9 9 Chloromethane ug/L ND 50 50 48.5 48.5 97 97 41-127 0 10 cis-1,2-Dichloroethene ug/L ND 50 50 50.8 48.2 102 96 71-138 5 16 cis-1,3-Dichloropropene ug/L ND 50 50 42.9 41.8 86 84 32-145 3 12 Dibromochloromethane ug/L ND 50 50 49.5 46.7 99 93 52-116 6 13 Dibromomethane ug/L ND 50 50 53.3 50.4 107 101 79-129 6 14 Ethylbenzene ug/L ND 50 50 50.7 48.6 101 97 31-174 4 10 lodomethane ug/L ND 100 100 97.2 100 97 100 49-154 3 30 m&p-Xylene ug/L ND 100 100 104 100 104 100 27-179 3 10 Methylene Chloride ug/L ND 50 50 51.3 50.8 103 102 61-146 1 15 o-Xylene ug/L ND 50 50 54.0 51.2 108 102 52-141 5 65 Styrene ug/L ND 50 50 51.6 48.8 103 98 77-128 6 14 Tetrachloroethene ug/L ND 50 50 56.8 53.2 114 106 36-155 7 14 Toluene ug/L ND 50 50 52.4 50.4 105 101 52-146 4 11 trans-1,2-Dichloroethene ug/L ND 50 50 56.0 55.1 112 110 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 40.1 40.8 80 82 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 62.6J 52AJ 63 52 61-139 18 12 M1,R1 Trichloroethene ug/L ND 50 50 54.1 49.4 108 99 61-141 9 12 Trichlorofluoromethane ug/L ND 50 50 82.1 77.5 164 155 51-141 6 13 M1 Vinyl acetate ug/L ND 50 50 62.6 58.4 125 117 52-141 7 14 Vinyl chloride ug/L ND 50 50 58.3 58.5 117 117 22-156 0 26 Xylene (Total) ug/L ND 150 150 158 151 105 101 78-132 4 7 1,2-Dichloroethane-d4 (S) %. 118 112 81-119 4-Bromofluorobenzene (S) %. 95 97 82-120 Dibromofluoromethane (S) %. 117 112 82-114 SO Toluene-d8 (S) %. 96 98 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Foothills LF Pace Project No.: 2612158 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS H1 Analysis conducted outside the EPA method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/19/2018 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 19 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Foothills LF Pace Project No.: 2612158 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2612158001 1403-MW1 R2 EPA 3005A 18393 EPA 6020B 18448 2612158002 1403-MW11 EPA 3005A 18393 EPA 6020B 18448 2612158001 1403-MW1 R2 EPA 8260B Mod. 446273 2612158002 1403-MW11 EPA 8260B Mod. 446273 2612158001 1403-MW1 R2 EPA 8260B 19028 2612158002 1403-MW11 EPA 8260B 19028 Date: 12/19/2018 08:49 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 19 w a a 1� on, N n Q c C7 p p ~ p L) `9 JD�s�a vi voi ov0,¢ nsLLJ. z OD LLO ��� Nv�vp,aJa, a x s s MW 0 SS G < W Q a 9 z 3 Z hez Q 2 a za°wIxQ O Y a .. OU) V .,+ _ . 3 N 1 w fa tit � o U 0: Illy pp � � W SIVAN -I XIaN3d X X > �MS 09Z8 A8 3NVXOla-v 6 X X m_ m 0 Z8 AS QOA - I XlaN3dd YJ X X w w d Ci C=7 z g. C)ozI-a-zw�u, ti ti s tu � 'v z d `; o .. O M W QCL.• Z z O V J o c�p - } CO . CO) N u7 M V J U U O a = Q X1 X $ UOi ILw m z z v- z o y LO 0 0 = w ri Q z z ; FW- 19 o 0 ~ _ • CO °� O d0 ru a H LL iii 2 V 2 Cw Q Q O z ~Q m o coei z Q 0. w W w p M co 1 p� w o z a a w � a P� R. Mp V P U U 0: a a -� m I._ FkeAnay66,71 Courier: _.? red Tracking#: Custody Seal on Packing Material: Thermometer Use CaoferTempest Temp should be aboi Sample Client Name: -4Lr� x ❑ UPS ❑ USPS ❑ Client vofy C ooler/Box Present: yes ❑ Bubble Wrap 21eubble Bails d T re �/ B a freezing to 6'C oject # Condition Upon ❑Commercial []Pace Other no Seals intact: yes ❑ None ❑ Other pe of Ice: et Blue None olo ical Tissue is Frozen: Yes g Comments: WO# : 26612158 PM: BM CLIENT: Rep ❑ Samples on ice, c Date and Init contents: Due Dale: blic—NC cell process as begun 2/18/18 als of arson mining Chain of Custody resent: es ONO DN/A 1, Chain of Custody illed Out: F, 1.1 ON. ❑NIA 2, Chain of Custody elin uished: 4 Yes ONO ❑NIA 3, Sampler Name & E i nature on COC: es ON. ❑NIA 4, Samples Arrived w thin Hold Time: Yes ONO ONIA 5, Short Hold Time Analysis <72hr): C Yes ❑NIA 6, Rush Turn Aroun Time Requested: ,jam' Yes ld7vo ❑NIA 7, Sufficient Volume: es ONO ❑NIA g, Correct Containers -Pace Contains Used: s Used: Mes ONO ❑NIA ves ONO ❑NIA 9. Containers Intact: es ONO ❑NIA 10. Filtered volume received for Dissolved tests C Yes ONO 21971—A 11. Sample Labels match -Includes date/ti COC: a a/ID/Analysis Matrix: es ONO ❑N1A 12. 13. All containers needing All containers needin compliance with EPA exceptions: A, ofifo preservation have been checked. preservation are found to be in recommendation. m, TOC, 08G. WI.OFO (water) eS ❑No ❑NIA Yes ❑No _1NiA es ONO Initial when completed Lot # of added preservative Samples checked for dechlorination: C Yes ONO /A 14. Headspace in VOA Vials ( >6mm): C Yes ego ❑NIA 15. Trip Blank Present: Trip Blank Custody Pace Trip Blank Lol C Seals Present C # if purchased): Yes ,e o ❑NIA Yes ONO pmr' 16. Client Notification' Person Contacted: Comments/ Res Resolution: ution: Date/Time: Field Data Requir d? Y I N Project Manager Note: Whenever them Certification Office ( i, Review: is a discrepancy affecting North Carob i out of hold. incorrect preservative. ou Date: rl will be sent to the Nor F•ALLCG h Carolina ll g of 19 3rev.3. t 1 Septembe 006 ia compliance samples. a copy of this fc of temp, incorrect containers) SITE NAME FOOTHILLS LF POINT ID: iV w - 11 LOCATION: LENOIR, NORTH CAROLINA SAMPLE MATRIX: GROUNDWATER EVACUATION INFORMATION INITIAL WATER LEVEL (FT),-.- ELEV., MEAS. PT. (MSL): f FIELD REPRESENTATIV LAB SAMPLE/ PROJECT #: E S & S - B.CHIOD❑ NA DEPTH TO BOTTOM (FT): �• 1 ELEVATION, GIW {MSL}: DATE I A - - I TIME: START/FINISH 6 . 30 1 T i o METHOD OF EVACUATION: EVACUATION EQUIPMENT ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP DEDICATED: ( } S.S. BAILER (X ) QED WW PUMP { ) OTHER { X } YES ( } NO WELL RISER DIAMETER (IN,): (X ) 2 [ } 3 ( } 4 { } 6 ( } OTHER ONE (1) RISER VOLUME (GAL) , �� WAS WELL PURGED TO DRYNESS ( } YES ( X ) NO TOTAL VOL. EVACUATED (GAL)- `-� U WATER LEVEL END PURGE (FT) TURBIDITY OF PURGINGS: START FINISH (f L.f�P- EVACUATION STABILIZATION DATA TIME PURGE RATE (ML !MIN) DTW (FT CUMUL. VOL GAL TEMP. (C) pH Sj Units CONDUCT. (umhoslcm) TURBIDITY (NTU) REDOX D.O. MGIL 30 250 al.6k o 13,3 7 &7 6; .,ci f.'R7 eh mV -33.1 /- ;� 9 N 250 il'7 0.25 12. 7 1- 0.11 55: I [. 7q --1). I 1..28 3 �f 250 09 o.SQ 13. 1 7. 13 55. ;?, t. 7 7 -S-, 7 �. s & . 4 Z 250 l.g o 0.75 13,0 7. 01 .5 ti- G 1. 7 1. 1 250 91,1Z 1.00 12,9 6,-� 5-3,5- 1,7S7 fi3. 2 I. 7 *�:sp 250 1.25 t2M (a v 53.Z I,7g_ �Z/.5 I.a3 (01151 250 $1.54 1.50 12.9 52 9' L"No S.V 1.zz g 250 $I. "I 1.75 l?-. 9" 6�7 j 2. j.7� fS:7 !.2 '7 o Z. 250 gr,� S 2.00 1 Z. (.&)o 2. G 1.7Z -f-6. v 1- z I 250 LgS 2.25 124, 250 &!°ii 2.50 �•�' �v-$C] J-� I."7$ SAMPLING INFORMATION DATE 1 TIME 1 ►Z - 3 - 18 1 I • Q DEPTH TO GROUNDWATER (FT) �?/- 5 - METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X ) YES ( } S.S. BAILER (X ) QED WW PUMP ( } OTHER ( ) NO GENERAL INFORMATION WEATHER CONDITIONS AT TIME OF SAMPLING: cC.Du py, y5 SAMPLE CHARACTERISTICS: [' 1,,��R- - COMMENTS: APPENDIX 1 LIST SAMPLE COLLECTION NUMBER SITE NAME FOOTHILLS LF POINT ID: MW - 1 R2 LOCATION: LENOIR, NORTH CAROLINA FIELD REPRESENTATIV E S & S - B.CHIODO SAMPLE MATRIX: GROUNDWATER LAB SAMPLE 1 PROJECT #: NA EVACUATION INFORMATION } (] Q INITIAL WATER LEVEL {FT}: [ b " r DEPTH TO BOTTOM (FT): . ELEV., MEAS. PT. (MSL): ELEVATION, GIW (MSL}: DATE 12 - 3 -1 V TIME: START/FINISH r7 . 3 ;L 1 '► 12- METHOD OF EVACUATION: EVACUATION EQUIPMENT DEDICATED: } PVC BAILER ( ) S.S. BAILER [ } GRUNDFOS PUMP (X ) YES { } S.S. BAILER (X ) QED WW PUMP ( } OTHER } NO WELL RISER DIAMETER (IN.): (X ) 2 } 3 ( } 4 [ } 6 { } OTHER ONE (1 ) RISER VOLUME {GAL} 3.1 � WAS WELL PURGED TO DRYNESS ( ) YES (X ) NO TOTAL VOL. EVACUATED (GAL) 'Q. SO WATER LEVEL END PURGE (FT) 1. TURBIDITY OF PURGINGS: START CLY-: 14,P- FINISH C LFAY- EVACUATION STABILIZATION DATA TIME r? : 3 '7 : 3(p i1,40 -'. 11 g "7:Sz Sio $ : $:oy g' g S:1Z PURGE RATE (ML 1 MIN 250pH 250 250 250 250 250 250 250 250 250 250 DTW FT tFr6o I5.11 Ij,1-77 ! r1 -J 15. I �' 19,11 11, 11 1 6..d.a 11,21 11.21 19.�ZT, CUMUL. VOL (GAL) 0 0.25 0.50 0.75 1.00 1.25 1.50 1.75 2.00 2.25 2.50 TEMP,jStd- ClUnifs] 13r 13.0 i� ,❑ { G 1 IZA 12 9 1 Z.l 1 1a,9 3'7 6.3 �v.31 �. 3 1 zg �. Z18! (r 2-$ Ii- ?-a 6.2--7 6�.;Z'7 CONDUCT. umhaslcm} I D S-.9 10Y. 1-03,9 I��rV� 102.1 to 1. /o 1. /41.3 to .3 ID1.2, TURBIDITY NTU 3 .'7 5 3,(! 2- 3, l8S <r I 2. S$ .3ff 2. 2.s 2 -Z2- _1 `� 2 0 2. REDOX eh mV -►-3.r 4-39.1 4-35,6 +3Ir ! 4-YO. c +yo.q +zl/r v ` c/l. 1 �`�I.V tyt, S fyl.l� D.O. MGIL I. 3g /.37 1,39 '.3 ! . 3 2- /r32 /.31 /. ,? 1 /.31 1. 3 1-3 SAMPLING INFORMATION DATE/TIME t 2- 3 - )f5" 1 g . I Z DEPTH TO GROUNDWATER (FTC 19. 2- METHOD OF SAMPLING: SAMPLING EQUIPMENT DEDICATED: ( } PVC BAILER ( ) S.S. BAILER ( } GRUNDFOS PUMP (X) YES ( } S.S. BAILER (X ) QED WW PUMP ( j OTHER [ } NO GENERAL INFORMATION c;r WEATHER CONDITIONS AT TIME OF SAMPLING: c- o(4by r YE SAMPLE CHARACTERISTICS: C COMMENTS. APPENDIX I LIST SAMPLE COLLECTION NUMBER