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HomeMy WebLinkAbout1202_Burke_East_MSWLF_GW_FID1287522_20190401&jLjjr& E ENGINEERING March 26, 2019 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 2211 W. Meadowview Rd., #101 Greensboro, NC 27409 tel: 336/323-0092 fax: 336/323-0093 www.JoyceEngineering.com RE: December 2018 Semiannual Groundwater Monitoring Report Burke County East Burke Landfill, Permit No. 12-02 JOYCE Project No. 2181871.03 Dear Ms. Drummond: Please find the attached December 2018 Semiannual Groundwater Monitoring Report for the Burke County East Burke Landfill (Permit No. 12-02). Attached are electronic versions of the complete report and all appendices for the December 2018 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the December 2018 monitoring event and laboratory EDD's. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me or Samantha Slebodnik at (336) 323- 0092 if you have any questions regarding this report. Sincerely, JOYCE ENGINEERING Van Burbach, Ph.D., P.G. Sr.Technical Consultant Copy: Miles Champion — Burke County �pENR USE ONLY []Paper Report [:]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.)_ Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Joyce Engineering Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@loyceengineering.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. - East Burke Landfill Rhodiss Road 12-02 .0500 December 3, 2018 Rhodiss, NC Environmental Status: (Check all that apply) Initial/Background Monitoring X❑ Detection Monitoring Assessment Monitoring Corrective Action T e of data submitted: (Check all that apply) X Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data X Surface water monitoringdata Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach. Ph.D., P.G. Technical Consultant (336) 323-0092 Facili rtnj�tiv a (Pr'9 �ritle (Area Code) Telephone Number /�/�,. A_ .� // /f �I� Affix NC Lic,rofessional Geologist Seal re 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) �oQ�N eAROIi •zJ��9� SEAL 1349 = Revised 6/2009 PREPARED FOR: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. Box 1486 MORGANTON, NORTH CAROLINA 28680 EAST BURKE LANDFILL PERMIT NO. 12-02 DECEMBER 2018 SEMIANNUAL WATER QUALITY MONITORING REPORT MARCH 2O18 PREPARED BY: JO r CE E!V GI111 EER!!V G 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAx: (336) 323-0093 JOYCE PROJECT No. 2181871.03 December 2018 Semiannual Water Quality Monitoring Report East Burke Landfill, Permit No. 12-02 Burke County, North Carolina TABLE OF CONTENTS 1.0 Introduction.......................................................................................... I 1.1 Site Information...............................................................................................1 1.3 Regulatory Status................................................................................1 2.0 FACILITY MONITORING PROGRAM.......................................................................2 2.1 Groundwater Monitoring Program...............................................................................2 2.2 Surface Water Monitoring Program..............................................................................2 3.0 DECEMBER 2018 SEMIANNUAL SAMPLING EVENT............................................3 3.1 Field Work.....................................................................................................................3 3.2 Laboratory Analysis and JOYCE Quality Control........................................................3 4.0 HYDROGEOLOGY..........................................................................................................4 5.0 DATA ANALYSIS..................................................................................5 5.1 Analytical Results and Comparisons to Standards....................................................5 5.1.1 Groundwater.......................................................................................................................................5 5.1.2 Surface Water.....................................................................................................................................5 6.0 CONCLUSION..................................................................................................................6 7.0 REFERENCES.......................................................................................7 December 2018 Semiannual Water Quality Monitoring Report Burke County — East Burke Landfill, Permit No. 12-02 Joyce Engineering March 2019 ii December 2018 Semiannual Water Quality Monitoring Report East Burke Landfill, Permit No. 12-02 Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 December 2018 Groundwater Elevations Table 2 December 2018 Estimated Hydraulic Gradients and Velocities Table 3 December 2018 Detections Table 4 December 2018 Exceedances Table 5 December 2018 Field Parameters Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendix Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Surface Water Constituents Table A2-4 Historical Groundwater Field Parameters Table A2-5 Historical Surface Water Field Parameters December 2018 Semiannual Water Quality Monitoring Report Burke County — East Burke Landfill, Permit No. 12-02 Joyce Engineering March 2019 iii 1.0 INTRODUCTION 1.1 Site Information The East Burke Landfill, Permit No. 12-02, is located in Burke County, North Carolina as shown on Figure 1. The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1972 and 1988 and has been closed to the reception of waste since 1988. 1.2 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors' groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. In March 1995, the North Carolina Department of Environment and Natural Resources (NCDENR), now the Department of Environmental Quality (NCDEQ), requested that the facility perform additional site contamination investigation activities due to the quantified detections of organic constituents in the groundwater on site. In response to this request a Water Quality Assessment Plan for the East Burke Landfill was submitted to the Solid Waste Section (SWS) in September of 1995. Updates on Groundwater Assessment Activities were submitted to NCDENR SWS in June 2003 and August 2003. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the East Burke Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3, and AMW-1. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored for the NC Appendix I list of constituents. Monitoring Date Classification Monitoring Total Depth Lithology of Screened Well Installed Program from TOC (ft) Interval MW-1 Unknown Background .0600 50.55 Bedrock (Est.) MW-2 Unknown Compliance .0600 71.05 Bedrock (Est.) MW-3 Unknown Compliance .0600 32.50 Saprolite (Est.) AMW-1 Apr. 1, 2003 Compliance .0600 7.25 Saprolite December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 1 2.2 Surface Water Monitoring Program Surface water monitoring at the East Burke Landfill is completed in accordance with the monitoring requirements of Rule .0600 of NCSWMR. Surface water samples are collected semiannually and are analyzed for the NC Appendix I constituents. The surface water monitoring network consists of two sampling points: SW-1 located upstream from the sediment pond, and SW-2 located downstream from MW-3 and AMW-1. The approximate locations of the sampling points are shown on Drawing 1. Surface Point Classification Monitoring Program SW-1 Compliance .0600 SW-2 Compliance .0600 3.0 DECEMBER 2018 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On December 3rd, 2018, personnel from Joyce Engineering (JOYCE) visited the East Burke Landfill to obtain water levels to the nearest 0.01 foot, purge, and sample monitoring wells MW-1, MW-2, MW-3, and AMW-1, and sample the two surface monitoring points, SW-1 and SW-2. Monitoring wells were purged and sampled using disposable bailers during the December 2018 sampling event. Measurements of temperature, pH, specific conductivity, and turbidity were recorded in the site log book prior to purging, after each purge volume, and during sampling. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a laboratory provided cooler. Copies of the field data logs are provided in Appendix 1. The surface water monitoring points SW-1 and SW-2 were collected directly from stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity and recorded in the field data log. Immediately after December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 collection, the samples were placed on ice in a laboratory -provided cooler. Copies of the field data logs are presented in Appendix 1. 3.2 Laboratory Analysis and JOYCE Quality Control The December 3rd, 2018 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. JOYCE requested a Level II data report for the final laboratory report. The samples were received by the laboratory on December 51h, 2018, in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the East Burke Landfill, a Field Blank was collected by JOYCE personnel as part of the December 2018 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs. Upon receipt of the laboratory data package, the data was reviewed by JOYCE personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Correct analyte lists; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC2L (NC2L) Groundwater Standards, SWS Groundwater Water Protection Standards (GWPS), and/or 15A NCAC213 (NC2B) Surface Water Standards; and • Detections that are above historical levels. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of alluvium, residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Groundwater discharges into an unnamed tributary to Lake Rhodhiss, northeast of the landfill. A groundwater potentiometric surface map, developed from static water level data obtained on December 3rd, 2018 is presented as Drawing 1. Depth to groundwater was measured in the compliance monitoring wells at the site prior to sampling. The groundwater elevations were calculated relative to the surveyed measuring December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 3 point (top of casing) for each monitoring well to ±0.01 ft. The groundwater elevations are summarized in Table 1 for the December 2018 monitoring event. Historical groundwater elevations are summarized in Table A2-1. The potentiometric surface contours shown in Drawing 1 are based on data from the December 2018 sampling event. Groundwater flow beneath the waste management unit is primarily to the northeast. Estimated horizontal groundwater gradients (i) from the December 2018 groundwater elevations are presented in Table 2. The horizontal gradient (i) calculated for the facility from the data was 0.0647. Linear groundwater flow velocities (V) was estimated using the following modified Darcy equation: V = Kilne, where: V = average linear velocity (feet per day — ft/day); K = hydraulic conductivity (ft/day); i = horizontal hydraulic gradient; and ne = effective porosity. Hydraulic conductivity (K) was estimated at 3.28 ft/day based on slug tests from a nearby site (John's River Landfill). An effective porosity (ne) of 20% was estimated based on typical values for piedmont aquifers. The estimated linear groundwater flow velocity under the facility is 387 ft/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplified assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known preferred pathways or barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS The final results from the December 2018 sampling event were received on December 17tn, 2018, for all monitoring wells (MW-1, MW-2, MW-3, and AMW-1) and surface water monitoring locations (SW-1 and SW-2). All analytical results can be found in Appendix 1. Table 3 summarizes the constituents in all monitoring well and surface water samples for the December 2018 event. Constituents in exceedance of the appropriate standards are summarized in Table 4. Field Parameters for the December 2018 sampling event are summarized in Table 5. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 4 Analytical results from monitoring wells were compared directly to the North Carolina Groundwater Standards found in 15A NCAC 02L.0202 (NC2L Standards) or the NCDEQ Solid Waste Section Groundwater Protection Standards (GWPS) for constituents with no listed NC2L Standard. Note that estimated concentrations below the Method Reporting Limit (MRL) are not considered exceedances of the standard, even if the estimated value is higher than the standard. Analytical results for surface water samples were compared directly to either the Freshwater Aquatic Life Surface Water Standards or Fish Consumption Surface Water Standards (whichever was lower) found in 15A NCAC 02B (NC213 Standards). For metals which have hardness -dependent NC213 Standards, the standards based on a default hardness of 25 mg/L was used. For constituents which have NC213 standards for both chronic and acute exposure, the lower of the two standards was used. For constituents with no NC213 standards, the results were compared to either the NC protective standard (NCPS) or the EPA naturally recommended water quality standard (NRWQS). Note that estimated concentrations below the MRL are not considered exceedances of the standard, even if the estimated value is higher than the standard. 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic constituents detected at quantified concentration in groundwater during the December 2018 sampling event are listed in Table 3. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a "J" are considered to be estimated. Bold values indicate concentrations above the NC 2L or GWPS in the groundwater samples. Historically detected constituents in groundwater can be found in Table A2-2. Inorganic constituents, barium, cobalt, nickel, and thallium were detected above the MRL. Cobalt (MW-1 and MW-3) and thallium (MW-2 and MW-3) were detected at quantified concentrations exceeding the NC 2L or GWPS. Organic constituents were detected in all of the monitoring wells (MW-1, MW-2, MW-3, and AMW-1); however, only 1,4-dioxane (p-dioxane) and cis-1,2-dichloroethene were detected at quantified concentrations above the MRL. Only 1,4-dioxane (p-dioxane) was detected in exceedance of NC 2L standard in MW-2 and MW-3. In general, these detections are consistent with historical data for the inorganic and organic constituents. 5.1.2 Surface Water During the December 2018 sampling event barium, cobalt, thallium, cis-1,2- dichloroethene, and 1,4-dioxane were detected at quantified concentrations above the MRL in surface water samples. Cobalt was detected above the NCPV in surface water monitoring point SW-2. Historical surface water data can be found in Table A2-3. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 6.0 CONCLUSION 1,4-Dioxane was detected in exceedances of groundwater protection standards in MW-2 and MW-3. 1,4-Dioxane analyses were required by the NCDEQ for the first time during the December event, and the NCDEQ has not yet issued a policy concerning regulatory response to 1,4-dioxane exceedances. We recommend continuing to sample for 1,4-dioxane in order to establish possible trends and/or seasonal variability. 1,4-Dioxane was detected in surface water samples SW-1 and SW-2. There is no NC2B surface water standard for 1,4-dioxane; however, there is a NC Protective Value for 1,4-dioxane, which is 80 µg/l for non -water - supply surface waters. None of the 1,4-dioxane detections exceeded the NC Protective Value. Cobalt was detected in SW-2 in exceedance of the NCPV. According to historical groundwater data, inorganic and organic constituents detected above the NC2L or GWPS in groundwater samples collected during the December 2018 sampling event are consistent with previous events with the exception of the 1,4-dioxane, which was analyzed for the first time. Based on the results of this groundwater monitoring event the groundwater monitoring network remains adequate to monitor groundwater at the site. The next semiannual sampling event is tentatively scheduled for the May 2019. 7.0 REFERENCES North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County — East Burke Landfill, Permit No. 12-02 March 2019 Tables Table 1 December 2018 Groundwater Elevations Table 2 December 2018 Estimated Hydraulic Gradients and Velocities Table 3 December 2018 Detections Table 4 December 2018 Exceedances Table 5 December 2018 Field Parameters TABLE 1: DECEMBER 2018 Groundwater Elevations Depth to Groundwater TOC Elevation Well Depth Location Groundwater Lithology Elevation (ft AMSL) (ft BTOC) (ft BTOC) (ft AMSL) MW-1 1147 39.09 Saprolite 50.55 1107.91 MW-2 1096.5 62.18 Saprolite 71.05 1034.32 MW-3 1039 10.39 Bedrock 32.50 1028.61 AMW-1 1021 4.45 Bedrock 7.30 1016.55 Notes: TOC = Top of casing ft = feet BTOC = Below TOC BGS = Below ground surface AMSL = Above mean sea level Burke County -East Burke Joyce Engineering Permit No. 12-02 TABLE 2: December 2018 Estimated Hydraulic Gradients and Velocities GRADIENT FLOW HORIZONTAL HYDRAULIC EFFECTIVE LINEAR LINE FLOW GROUNDWATER CONDUCTIVITY VELOCITY CALCULATION GRADIENT POROSITY LENGTH DIRECTION ELEVATION(ft) K V SEGMENT i n e (ft) (ft/day) (ft/ ear) 110100 0 Z I 1,236 NE 0.0647 3.28E+00 0.20 387 1 Notes: The mean of K estimates from individual well slug tests from the Burke County John's River Facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln e ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Burke County -East Burke Joyce Engineering Permit No. 12-02 TABLE 3: December 2018 Detections Parameter MDL MRL NC GW Upgr d ent GW Downgradient MW-1 MW-2 MW-3 AMW-1 Arsenic 5 10 10 5.1 J -- -- Barium 2.5 5 700 58.4 50.7 120 43.4 Chromium 2.5 5 10 5.0 J -- Cobalt 2.5 5 1* 12.2 -- 26.3 -- Copper 2.5 10 1,000 Lead 2.5 10 15 -- Nickel 2.5 5 100 4.5 J 8.7 Thallium 0.06 0.1 .28* 0.12 0.49 1.3 Zinc 5 10 1,000 -- -- Acetone 10 100 6,000 -- -- Benzene 0.25 1 1 0.92 J 0.70 J -- Chlorobenzene 0.23 1 50 0.55 J 0.80 J -- 1,4-Dichlorobenzene 0.33 1 6 -- -- 1,1-Dichloroethane 0.32 5 6 - 0.70 J -- cis- 1,2-Dichloroethene 0.19 1 70 1.4 20.4 12.7 3.9 1,4-Dioxane (p-Dioxane) 1.9 2 3 3.1 22.5 -- Trichloroethene 1 0.47 1 1 1 3 0.51 J 0.55 J -- Parameter MDL MRL NC2B SW-1 S Barium 2.5 5 21,000^ 39.1 49.3 Cobalt 2.5 5 4^ 2.7 J 7.4 Nickel 2.5 5 16.1 -- 4.3 J Thallium 0.06 0.1 0.47 ^^ -- 0.11 1,4-Dioxane (p-Dioxane) 1.9 2 80 ^ 6.2 10.1 cis- 1, 2-Dichloroethene 1 0.19 1 720 ^ -- 0.97 J Burke County -East Burke Permit No. 12-02 Notes: All results are in micrograms per liter (µg/L). MDL = Method Detection Limit MRL = Method Reporting Limit NC21, = NC Groundwater Standard from 15A NCAC 2L.0202 *GWPS = NC Solid Waste Section Groundwater Protection Standard NC213 = NC Surface Water Standard from 15A NCAC 2B Bold results are exceedances of the applicable standards. NE = Not Established ^ = NC Protective Value ^^ = EPA NRWQC (Naturally Recommended Water Quality Criteria) Joyce Engineering TABLE 4: December 2018 Exceedances Parameter MDL MRL NC 2L GWPS* NCPV** GW Upgradient GW Downgradient Surface Water MW-1 MW-2 MW-3 SW-2 1,4-Dioxane (p 1.9 2 3/80** -- 3.1 22.5 10.1 Dioxane) Cobalt 2.5 5 1*/4** 12.2 -- 26.3 7.4 Thallium 0.06 0.1 0.28*/0.47** 0.12 0.49 1.3 0.11 Notes: All results are in micrograms per liter (µg/L). MDL = Method Detection Limit MRL = Method Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 *GWPS = NCDEQ Solid Waste Section Groundwater Protection Standards **= NC Protective Value Bold results are exceedances of the applicable standards. Burke County -East Burke Joyce Engineering Permit No. 12-02 TABLE 5: December 2018 Field Parameters Parameter Units Collect Date GW Upgradient GW Downgradient SW MW-1 MW-2 MW-3 AMW-1 SW-1 SW-2 H S.U. 12/3/2018 5.57 5.7 6.03 5.38 6.55 6.16 Temperature °C 12/3/2018 15.1 15.5 16 12.5 12.6 12 Conductivity µS/cm 12/3/2018 96.2 187.6 244.8 124.5 129 139 Turbidity NTU 12/3/2018 5.41 8.26 5.98 15.5 13.9 47.6 Static Water Level Ft. 12/3/2018 39.09 62.18 10.39 4.45 -- Well Depth Ft. --1 50.55 71.05 32.5 7.3 -- -- Notes: °C = degrees Centigrade S.U. = Standard Units µS/cm = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County -East Burke Joyce Engineering Permit No. 12-02 Figure 1 Site Location Map 0 . mxmw lilk/ � 7A _ ON ✓J J 0 2211 WEST MEADOWVIEW ROAD SCALE PRoJEcT No. EAST BURKE LANDFILL x FIGURE N0. 1 I ^�GREENSBORO, N.C. 27407 u r `� 1M2000' 277 = PHONE: (336) 323-0092 SITE LOCATION MAP n ENGINEERING ©2017 Joyce Engineering, Inc. All dgM1is reserved. Drawing 1 Potentiometric Surface Contour Map — -1 040 \ I — 1460 1080\ J�1'3' 4.2 70? A W-1 I \ 7070 , 4-040 _ FIELD DETERMINED 1 I / -EDGE OF WASTE O / Rti�oy�s I 1090 o s o _ 110 I OD vy� 1107.91 to O I I "z 0 1100 _ 1 1 GP-5 I L \ sR 1g11 / \ 1__l/ \ f SR 2300 LEGEND 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING 20' TOPOGRAPHIC CONTOUR 020— — GROUNDWATER SURFACE CONTOUR [FEET N ABOVE MEAN SEA LEVEL (AMSL)] o PROPERTY LINE 0 o U GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT z EXISTING ROAD z 0 — APPROXIMATE LIMITS OF WASTE N — CENTERLINE OF STREAM - MW-1 COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC 1107.91 WATER LEVEL ELEVATION (FEET AMSL) 0 SW-2 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION SEGMENT USED FOR GRADIENT CALCULATION O >>a - wm FLOW PATH LENGTH 0 w w O �3cYi�w o` Z1 1,236LF U Q ❑ NOTES 0 �V Z r 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET.Lu `, 3 wro �` 0<00 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. W d ? 3. STATIC WATER LEVELS WERE MEASURED ON DECEMBER 3, 2018. N o 2 ' 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND W N of ? EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. d Q w Z_ U LL J J Q U 00 LL C) z �CD CD N � C? W J O � 2i M � � Yz LU �} z comz O w D_ ❑ O W w W Y LU Q m � z O IY C7 PROJECT NO. 277 GRAPHIC SCALE SCALE 0 150 300 600 AS NOTED (FEET) DRAWING NO. 1 Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Appendix 1 Laboratory Analytical Reports and Field Data Logs aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 17, 2018 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co. East Burke Pace Project No.: 92409793 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. East Burke Pace Project No.: 92409793 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 36 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co. East Burke Pace Project No.: 92409793 Lab ID Sample ID Matrix Date Collected Date Received 92409793001 1202-MW1 Water 12/03/18 08:44 12/05/18 14:05 92409793002 1202-MW2 Water 12/03/1810:42 12/05/1814:05 92409793003 1202-MW3 Water 12/03/1812:35 12/05/1814:05 92409793004 1202-AMW1 Water 12/03/1811:35 12/05/1814:05 92409793005 1202-SW1 Water 12/03/1812:28 12/05/1814:05 92409793006 1202-SW2 Water 12/03/1811:28 12/05/1814:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co. East Burke 92409793 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92409793001 1202-MW1 EPA 6010D IDS 14 PASI-A EPA 6020E SER 2 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409793002 1202-MW2 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409793003 1202-MW3 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409793004 1202-AMW1 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409793005 1202-SW1 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409793006 1202-SW2 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co. East Burke 92409793 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92409793001 1202-MW1 EPA 6010D Arsenic 5.1 J ug/L 10.0 12/15/18 19:56 EPA 6010D Barium 58.4 ug/L 5.0 12/15/18 19:56 EPA 6010D Cobalt 11.8 ug/L 5.0 12/15/18 19:56 EPA 6010D Nickel 4.5J ug/L 5.0 12/15/18 19:56 EPA 6020B Cobalt 12.2 ug/L 0.10 12/14/18 22:10 EPA 6020B Thallium 0.12 ug/L 0.10 12/14/18 22:10 EPA 8260B cis-1,2-Dichloroethene 1.4 ug/L 1.0 12/13/1811:31 92409793002 1202-MW2 EPA 6010D Barium 50.7 ug/L 5.0 12/15/18 20:05 EPA 6010D Chromium 5.OJ ug/L 5.0 12/15/18 20:05 EPA 6020B Thallium 0.49 ug/L 0.10 12/14/18 22:18 EPA 8260B Benzene 0.92J ug/L 1.0 12/13/18 11:49 EPA 8260B Chlorobenzene 0.55J ug/L 1.0 12/13/18 11:49 EPA 8260B cis-1,2-Dichloroethene 20.4 ug/L 1.0 12/13/18 11:49 EPA 8260B Trichloroethene 0.51 J ug/L 1.0 12/13/18 11:49 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 3.1 ug/L 2.0 12/12/18 22:41 92409793003 1202-MW3 EPA 6010D Barium 120 ug/L 5.0 12/15/18 20:08 EPA 6010D Cobalt 26.3 ug/L 5.0 12/15/18 20:08 EPA 6010D Nickel 8.7 ug/L 5.0 12/15/18 20:08 EPA 6020B Thallium 1.3 ug/L 0.10 12/14/18 22:20 EPA 8260B Benzene 0.70J ug/L 1.0 12/13/18 08:21 EPA 8260B Chlorobenzene 0.801 ug/L 1.0 12/13/18 08:21 EPA 8260B 1,1-Dichloroethane 0.70J ug/L 1.0 12/13/18 08:21 EPA 8260B cis-1,2-Dichloroethene 12.7 ug/L 1.0 12/13/18 08:21 EPA 8260B Trichloroethene 0.55J ug/L 1.0 12/13/18 08:21 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 22.5 ug/L 2.0 12/12/18 23:00 92409793004 1202-AMW1 EPA 6010D Barium 43.4 ug/L 5.0 12/15/18 20:11 EPA 8260B cis-1,2-Dichloroethene 3.9 ug/L 1.0 12/13/1813:14 92409793005 1202-SW1 EPA 6010D Barium 39.1 ug/L 5.0 12/15/18 20:14 EPA 6010D Cobalt 2.7J ug/L 5.0 12/15/18 20:14 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 6.2 ug/L 2.0 12/12/18 23:39 92409793006 1202-SW2 EPA 6010D Barium 49.3 ug/L 5.0 12/15/18 20:17 EPA 6010D Cobalt 7.4 ug/L 5.0 12/15/18 20:17 EPA 6010D Nickel 4.3J ug/L 5.0 12/15/18 20:17 EPA 6020B Thallium 0.11 ug/L 0.10 12/14/18 22:31 EPA 8260B cis-1,2-Dichloroethene 0.97J ug/L 1.0 12/13/18 08:55 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 10.1 ug/L 2.0 12/12/18 23:58 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW1 Lab ID: 92409793001 Collected: 12/03/18 08:44 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:56 7440-36-0 Arsenic 5.1J ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:56 7440-38-2 Barium 58.4 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:56 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:56 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-47-3 Cobalt 11.8 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7439-92-1 Nickel 4.5J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:56 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:56 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:56 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Cobalt 12.2 ug/L 0.10 0.050 1 12/12/18 03:00 12/14/18 22:10 7440-48-4 Thallium 0.12 ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:10 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 11:31 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 11:31 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 11:31 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 11:31 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 11:31 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 11:31 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 11:31 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 11:31 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 11:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 11:31 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 11:31 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 11:31 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 11:31 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 11:31 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 11:31 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 11:31 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 11:31 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 11:31 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 11:31 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 11:31 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 11:31 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 11:31 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 11:31 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 11:31 75-35-4 cis-1,2-Dichloroethene 1.4 ug/L 1.0 0.19 1 12/13/18 11:31 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 11:31 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW1 Lab ID: 92409793001 Collected: 12/03/18 08:44 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 102 % 70-130 90 % 70-130 97 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 100 % 50-150 108 % 50-150 0.27 1 12/13/18 11:31 78-87-5 0.13 1 12/13/18 11:31 10061-01-5 0.26 1 12/13/18 11:31 10061-02-6 0.30 1 12/13/18 11:31 100-41-4 0.46 1 12/13/18 11:31 591-78-6 0.32 1 12/13/18 11:31 74-88-4 0.97 1 12/13/18 11:31 75-09-2 0.33 1 12/13/18 11:31 108-10-1 0.26 1 12/13/18 11:31 100-42-5 0.33 1 12/13/18 11:31 630-20-6 0.40 1 12/13/18 11:31 79-34-5 0.46 1 12/13/18 11:31 127-18-4 0.26 1 12/13/18 11:31 108-88-3 0.48 1 12/13/18 11:31 71-55-6 0.29 1 12/13/18 11:31 79-00-5 0.47 1 12/13/18 11:31 79-01-6 0.20 1 12/13/18 11:31 75-69-4 0.41 1 12/13/18 11:31 96-18-4 0.35 1 12/13/18 11:31 108-05-4 0.62 1 12/13/18 11:31 75-01-4 0.66 1 12/13/18 11:31 1330-20-7 1 12/13/18 11:31 460-00-4 1 12/13/18 11:31 17060-07-0 1 12/13/18 11:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 22:21 123-91-1 12/12/18 22:21 17060-07-0 12/12/18 22:21 2037-26-5 Page 7 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW2 Lab ID: 92409793002 Collected: 12/03/18 10:42 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/17/2018 04:53 PM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 20:05 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:05 7440-38-2 50.7 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:05 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:05 7440-43-9 5.OJ ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-47-3 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7439-92-1 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:05 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:05 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:05 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.49 ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:18 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/13/1811:49 67-64-1 ND ug/L 10.0 1.9 1 12/13/1811:49 107-13-1 0.92J ug/L 1.0 0.25 1 12/13/1811:49 71-43-2 ND ug/L 1.0 0.17 1 12/13/1811:49 74-97-5 ND ug/L 1.0 0.18 1 12/13/1811:49 75-27-4 ND ug/L 1.0 0.26 1 12/13/1811:49 75-25-2 ND ug/L 2.0 0.29 1 12/13/1811:49 74-83-9 ND ug/L 5.0 0.96 1 12/13/1811:49 78-93-3 ND ug/L 2.0 1.2 1 12/13/1811:49 75-15-0 ND ug/L 1.0 0.25 1 12/13/1811:49 56-23-5 0.55J ug/L 1.0 0.23 1 12/13/1811:49 108-90-7 ND ug/L 1.0 0.54 1 12/13/1811:49 75-00-3 ND ug/L 1.0 0.14 1 12/13/1811:49 67-66-3 ND ug/L 1.0 0.11 1 12/13/1811:49 74-87-3 ND ug/L 2.0 2.0 1 12/13/1811:49 96-12-8 ND ug/L 1.0 0.21 1 12/13/1811:49 124-48-1 ND ug/L 1.0 0.27 1 12/13/1811:49 106-93-4 ND ug/L 1.0 0.21 1 12/13/1811:49 74-95-3 ND ug/L 1.0 0.30 1 12/13/1811:49 95-50-1 ND ug/L 1.0 0.33 1 12/13/1811:49 106-46-7 ND ug/L 1.0 1.0 1 12/13/1811:49 110-57-6 ND ug/L 1.0 0.32 1 12/13/1811:49 75-34-3 ND ug/L 1.0 0.24 1 12/13/1811:49 107-06-2 ND ug/L 1.0 0.56 1 12/13/1811:49 75-35-4 20.4 ug/L 1.0 0.19 1 12/13/1811:49 156-59-2 ND ug/L 1.0 0.49 1 12/13/1811:49 156-60-5 ND ug/L 1.0 0.27 1 12/13/1811:49 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW2 Lab ID: 92409793002 Collected: 12/03/18 10:42 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.51J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 102 % 70-130 94 % 70-130 103 % 70-130 Analytical Method: EPA 8260E Mod. 3.1 ug/L 2.0 101 % 50-150 110 % 50-150 0.13 1 12/13/18 11:49 10061-01-5 0.26 1 12/13/18 11:49 10061-02-6 0.30 1 12/13/18 11:49 100-41-4 0.46 1 12/13/18 11:49 591-78-6 0.32 1 12/13/18 11:49 74-88-4 0.97 1 12/13/18 11:49 75-09-2 0.33 1 12/13/18 11:49 108-10-1 0.26 1 12/13/18 11:49 100-42-5 0.33 1 12/13/18 11:49 630-20-6 0.40 1 12/13/18 11:49 79-34-5 0.46 1 12/13/18 11:49 127-18-4 0.26 1 12/13/18 11:49 108-88-3 0.48 1 12/13/18 11:49 71-55-6 0.29 1 12/13/18 11:49 79-00-5 0.47 1 12/13/18 11:49 79-01-6 0.20 1 12/13/18 11:49 75-69-4 0.41 1 12/13/18 11:49 96-18-4 0.35 1 12/13/18 11:49 108-05-4 0.62 1 12/13/18 11:49 75-01-4 0.66 1 12/13/18 11:49 1330-20-7 1 12/13/18 11:49 460-00-4 1 12/13/18 11:49 17060-07-0 1 12/13/18 11:49 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 22:41 123-91-1 12/12/18 22:41 17060-07-0 12/12/18 22:41 2037-26-5 Page 9 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW3 Lab ID: 92409793003 Collected: 12/03/18 12:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 20:08 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:08 7440-38-2 Barium 120 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:08 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:08 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-47-3 Cobalt 26.3 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7439-92-1 Nickel 8.7 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:08 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:08 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:08 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 1.3 ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:20 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 08:21 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 08:21 107-13-1 Benzene 0.70J ug/L 1.0 0.25 1 12/13/18 08:21 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 08:21 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 08:21 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 08:21 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 08:21 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 08:21 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 08:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 08:21 56-23-5 Chlorobenzene 0.801 ug/L 1.0 0.23 1 12/13/18 08:21 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 08:21 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 08:21 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 08:21 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 08:21 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 08:21 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 08:21 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 08:21 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 08:21 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 08:21 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 08:21 110-57-6 1,1-Dichloroethane 0.70J ug/L 1.0 0.32 1 12/13/18 08:21 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 08:21 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 08:21 75-35-4 cis-1,2-Dichloroethene 12.7 ug/L 1.0 0.19 1 12/13/18 08:21 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 08:21 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/13/18 08:21 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-MW3 Lab ID: 92409793003 Collected: 12/03/18 12:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.55J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 101 % 70-130 90 % 70-130 98 % 70-130 Analytical Method: EPA 8260E Mod. 22.5 ug/L 2.0 102 % 50-150 109 % 50-150 0.13 1 12/13/18 08:21 10061-01-5 0.26 1 12/13/18 08:21 10061-02-6 0.30 1 12/13/18 08:21 100-41-4 0.46 1 12/13/18 08:21 591-78-6 0.32 1 12/13/18 08:21 74-88-4 0.97 1 12/13/18 08:21 75-09-2 0.33 1 12/13/18 08:21 108-10-1 0.26 1 12/13/18 08:21 100-42-5 0.33 1 12/13/18 08:21 630-20-6 0.40 1 12/13/18 08:21 79-34-5 0.46 1 12/13/18 08:21 127-18-4 0.26 1 12/13/18 08:21 108-88-3 0.48 1 12/13/18 08:21 71-55-6 0.29 1 12/13/18 08:21 79-00-5 0.47 1 12/13/18 08:21 79-01-6 0.20 1 12/13/18 08:21 75-69-4 0.41 1 12/13/18 08:21 96-18-4 0.35 1 12/13/18 08:21 108-05-4 0.62 1 12/13/18 08:21 75-01-4 0.66 1 12/13/18 08:21 1330-20-7 1 12/13/18 08:21 460-00-4 1 12/13/18 08:21 17060-07-0 1 12/13/18 08:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 23:00 123-91-1 12/12/18 23:00 17060-07-0 12/12/18 23:00 2037-26-5 Page 11 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-AMW1 Lab ID: 92409793004 Collected: 12/03/18 11:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/17/2018 04:53 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 20:11 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:11 7440-38-2 43.4 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:11 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:11 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-47-3 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7439-92-1 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:11 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:11 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:11 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:22 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/13/1813:14 67-64-1 ND ug/L 10.0 1.9 1 12/13/1813:14 107-13-1 ND ug/L 1.0 0.25 1 12/13/1813:14 71-43-2 ND ug/L 1.0 0.17 1 12/13/1813:14 74-97-5 ND ug/L 1.0 0.18 1 12/13/1813:14 75-27-4 ND ug/L 1.0 0.26 1 12/13/1813:14 75-25-2 ND ug/L 2.0 0.29 1 12/13/1813:14 74-83-9 ND ug/L 5.0 0.96 1 12/13/1813:14 78-93-3 ND ug/L 2.0 1.2 1 12/13/1813:14 75-15-0 ND ug/L 1.0 0.25 1 12/13/1813:14 56-23-5 ND ug/L 1.0 0.23 1 12/13/1813:14 108-90-7 ND ug/L 1.0 0.54 1 12/13/1813:14 75-00-3 ND ug/L 1.0 0.14 1 12/13/1813:14 67-66-3 ND ug/L 1.0 0.11 1 12/13/1813:14 74-87-3 ND ug/L 2.0 2.0 1 12/13/1813:14 96-12-8 ND ug/L 1.0 0.21 1 12/13/1813:14 124-48-1 ND ug/L 1.0 0.27 1 12/13/1813:14 106-93-4 ND ug/L 1.0 0.21 1 12/13/1813:14 74-95-3 ND ug/L 1.0 0.30 1 12/13/1813:14 95-50-1 ND ug/L 1.0 0.33 1 12/13/1813:14 106-46-7 ND ug/L 1.0 1.0 1 12/13/1813:14 110-57-6 ND ug/L 1.0 0.32 1 12/13/1813:14 75-34-3 ND ug/L 1.0 0.24 1 12/13/1813:14 107-06-2 ND ug/L 1.0 0.56 1 12/13/1813:14 75-35-4 3.9 ug/L 1.0 0.19 1 12/13/1813:14 156-59-2 ND ug/L 1.0 0.49 1 12/13/1813:14 156-60-5 ND ug/L 1.0 0.27 1 12/13/1813:14 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-AMW1 Lab ID: 92409793004 Collected: 12/03/18 11:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 100 % 70-130 91 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 96 % 50-150 108 % 50-150 0.13 1 12/13/18 13:14 10061-01-5 0.26 1 12/13/18 13:14 10061-02-6 0.30 1 12/13/18 13:14 100-41-4 0.46 1 12/13/18 13:14 591-78-6 0.32 1 12/13/18 13:14 74-88-4 0.97 1 12/13/18 13:14 75-09-2 0.33 1 12/13/18 13:14 108-10-1 0.26 1 12/13/18 13:14 100-42-5 0.33 1 12/13/18 13:14 630-20-6 0.40 1 12/13/18 13:14 79-34-5 0.46 1 12/13/18 13:14 127-18-4 0.26 1 12/13/18 13:14 108-88-3 0.48 1 12/13/18 13:14 71-55-6 0.29 1 12/13/18 13:14 79-00-5 0.47 1 12/13/18 13:14 79-01-6 0.20 1 12/13/18 13:14 75-69-4 0.41 1 12/13/18 13:14 96-18-4 0.35 1 12/13/18 13:14 108-05-4 0.62 1 12/13/18 13:14 75-01-4 0.66 1 12/13/18 13:14 1330-20-7 1 12/13/18 13:14 460-00-4 1 12/13/18 13:14 17060-07-0 1 12/13/18 13:14 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 23:19 123-91-1 12/12/18 23:19 17060-07-0 12/12/18 23:19 2037-26-5 Page 13 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-SW1 Lab ID: 92409793005 Collected: 12/03/18 12:28 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 20:14 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:14 7440-38-2 Barium 39.1 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:14 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:14 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-47-3 Cobalt 2.7J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:14 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:14 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:14 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:24 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 08:38 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 08:38 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 08:38 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 08:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 08:38 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 08:38 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 08:38 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 08:38 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 08:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 08:38 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 08:38 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 08:38 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 08:38 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 08:38 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 08:38 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 08:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 08:38 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 08:38 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 08:38 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 08:38 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 08:38 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 08:38 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 08:38 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 08:38 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 08:38 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 08:38 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/13/18 08:38 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-SW1 Lab ID: 92409793005 Collected: 12/03/18 12:28 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 103 % 70-130 90 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod 6.2 ug/L 2.0 98 % 50-150 108 % 50-150 0.13 1 12/13/18 08:38 10061-01-5 0.26 1 12/13/18 08:38 10061-02-6 0.30 1 12/13/18 08:38 100-41-4 0.46 1 12/13/18 08:38 591-78-6 0.32 1 12/13/18 08:38 74-88-4 0.97 1 12/13/18 08:38 75-09-2 0.33 1 12/13/18 08:38 108-10-1 0.26 1 12/13/18 08:38 100-42-5 0.33 1 12/13/18 08:38 630-20-6 0.40 1 12/13/18 08:38 79-34-5 0.46 1 12/13/18 08:38 127-18-4 0.26 1 12/13/18 08:38 108-88-3 0.48 1 12/13/18 08:38 71-55-6 0.29 1 12/13/18 08:38 79-00-5 0.47 1 12/13/18 08:38 79-01-6 0.20 1 12/13/18 08:38 75-69-4 0.41 1 12/13/18 08:38 96-18-4 0.35 1 12/13/18 08:38 108-05-4 0.62 1 12/13/18 08:38 75-01-4 0.66 1 12/13/18 08:38 1330-20-7 1 12/13/18 08:38 460-00-4 1 12/13/18 08:38 17060-07-0 1 12/13/18 08:38 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 23:39 123-91-1 12/12/18 23:39 17060-07-0 12/12/18 23:39 2037-26-5 Page 15 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-SW2 Lab ID: 92409793006 Collected: 12/03/18 11:28 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/17/2018 04:53 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 20:17 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:17 7440-38-2 49.3 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:17 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 20:17 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-47-3 7.4 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7439-92-1 4.3J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:17 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 20:17 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 20:17 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.11 ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 22:31 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/13/18 08:55 67-64-1 ND ug/L 10.0 1.9 1 12/13/18 08:55 107-13-1 ND ug/L 1.0 0.25 1 12/13/18 08:55 71-43-2 ND ug/L 1.0 0.17 1 12/13/18 08:55 74-97-5 ND ug/L 1.0 0.18 1 12/13/18 08:55 75-27-4 ND ug/L 1.0 0.26 1 12/13/18 08:55 75-25-2 ND ug/L 2.0 0.29 1 12/13/18 08:55 74-83-9 ND ug/L 5.0 0.96 1 12/13/18 08:55 78-93-3 ND ug/L 2.0 1.2 1 12/13/18 08:55 75-15-0 ND ug/L 1.0 0.25 1 12/13/18 08:55 56-23-5 ND ug/L 1.0 0.23 1 12/13/18 08:55 108-90-7 ND ug/L 1.0 0.54 1 12/13/18 08:55 75-00-3 ND ug/L 1.0 0.14 1 12/13/18 08:55 67-66-3 ND ug/L 1.0 0.11 1 12/13/18 08:55 74-87-3 ND ug/L 2.0 2.0 1 12/13/18 08:55 96-12-8 ND ug/L 1.0 0.21 1 12/13/18 08:55 124-48-1 ND ug/L 1.0 0.27 1 12/13/18 08:55 106-93-4 ND ug/L 1.0 0.21 1 12/13/18 08:55 74-95-3 ND ug/L 1.0 0.30 1 12/13/18 08:55 95-50-1 ND ug/L 1.0 0.33 1 12/13/18 08:55 106-46-7 ND ug/L 1.0 1.0 1 12/13/18 08:55 110-57-6 ND ug/L 1.0 0.32 1 12/13/18 08:55 75-34-3 ND ug/L 1.0 0.24 1 12/13/18 08:55 107-06-2 ND ug/L 1.0 0.56 1 12/13/18 08:55 75-35-4 0.97J ug/L 1.0 0.19 1 12/13/18 08:55 156-59-2 ND ug/L 1.0 0.49 1 12/13/18 08:55 156-60-5 ND ug/L 1.0 0.27 1 12/13/18 08:55 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. East Burke Pace Project No.: 92409793 Sample: 1202-SW2 Lab ID: 92409793006 Collected: 12/03/18 11:28 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:53 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 102 % 70-130 90 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod 10.1 ug/L 2.0 98 % 50-150 109 % 50-150 0.13 1 12/13/18 08:55 10061-01-5 0.26 1 12/13/18 08:55 10061-02-6 0.30 1 12/13/18 08:55 100-41-4 0.46 1 12/13/18 08:55 591-78-6 0.32 1 12/13/18 08:55 74-88-4 0.97 1 12/13/18 08:55 75-09-2 0.33 1 12/13/18 08:55 108-10-1 0.26 1 12/13/18 08:55 100-42-5 0.33 1 12/13/18 08:55 630-20-6 0.40 1 12/13/18 08:55 79-34-5 0.46 1 12/13/18 08:55 127-18-4 0.26 1 12/13/18 08:55 108-88-3 0.48 1 12/13/18 08:55 71-55-6 0.29 1 12/13/18 08:55 79-00-5 0.47 1 12/13/18 08:55 79-01-6 0.20 1 12/13/18 08:55 75-69-4 0.41 1 12/13/18 08:55 96-18-4 0.35 1 12/13/18 08:55 108-05-4 0.62 1 12/13/18 08:55 75-01-4 0.66 1 12/13/18 08:55 1330-20-7 1 12/13/18 08:55 460-00-4 1 12/13/18 08:55 17060-07-0 1 12/13/18 08:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/12/18 23:58 123-91-1 12/12/18 23:58 17060-07-0 12/12/18 23:58 2037-26-5 Page 17 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 446502 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005, 92409793006 METHOD BLANK: 2447336 Matrix: Water Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005, 92409793006 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 12/15/1819:05 Arsenic ug/L ND 10.0 5.0 12/15/1819:05 Barium ug/L ND 5.0 2.5 12/15/1819:05 Beryllium ug/L ND 1.0 0.50 12/15/1819:05 Cadmium ug/L ND 1.0 0.50 12/15/1819:05 Chromium ug/L ND 5.0 2.5 12/15/1819:05 Cobalt ug/L ND 5.0 2.5 12/15/1819:05 Copper ug/L ND 5.0 2.5 12/15/1819:05 Lead ug/L ND 5.0 2.5 12/15/1819:05 Nickel ug/L ND 5.0 2.5 12/15/1819:05 Selenium ug/L ND 10.0 5.0 12/15/1819:05 Silver ug/L ND 5.0 2.5 12/15/1819:05 Vanadium ug/L ND 5.0 2.5 12/15/1819:05 Zinc ug/L ND 10.0 5.0 12/15/1819:05 LABORATORY CONTROL SAMPLE: Parameter 2447337 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 475 95 80-120 Arsenic ug/L 500 461 92 80-120 Barium ug/L 500 480 96 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 480 96 80-120 Chromium ug/L 500 486 97 80-120 Cobalt ug/L 500 479 96 80-120 Copper ug/L 500 480 96 80-120 Lead ug/L 500 471 94 80-120 Nickel ug/L 500 477 95 80-120 Selenium ug/L 500 455 91 80-120 Silver ug/L 250 240 96 80-120 Vanadium ug/L 500 487 97 80-120 Zinc ug/L 500 469 94 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447338 2447339 MS MSD 92409790001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 495 494 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447338 2447339 MS MSD 92409790001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 479 478 95 95 75-125 0 20 Barium ug/L 1160 500 500 1580 1590 84 87 75-125 1 20 Beryllium ug/L ND 500 500 494 493 99 99 75-125 0 20 Cadmium ug/L 2.0 500 500 468 467 93 93 75-125 0 20 Chromium ug/L ND 500 500 483 484 96 97 75-125 0 20 Cobalt ug/L 120 500 500 583 583 92 93 75-125 0 20 Copper ug/L ND 500 500 512 513 102 103 75-125 0 20 Lead ug/L ND 500 500 459 456 92 91 75-125 1 20 Nickel ug/L 17.2 500 500 477 477 92 92 75-125 0 20 Selenium ug/L ND 500 500 477 475 95 95 75-125 0 20 Silver ug/L ND 250 250 252 250 101 100 75-125 1 20 Vanadium ug/L ND 500 500 507 506 101 101 75-125 0 20 Zinc ug/L ND 500 500 460 460 92 92 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 446880 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005, 92409793006 METHOD BLANK: 2449125 Matrix: Water Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005, 92409793006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Cobalt ug/L ND 0.10 0.050 12/14/18 22:05 Thallium ug/L ND 0.10 0.060 12/14/18 22:05 LABORATORY CONTROL SAMPLE: 2449126 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Cobalt ug/L 10 10.3 103 80-120 Thallium ug/L 10 10.1 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2449127 2449128 MS MSD 92409793001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Cobalt ug/L 12.2 10 10 22.1 21.9 99 96 75-125 1 20 Thallium ug/L 0.12 10 10 10.0 10.0 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 447140 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409793001, 92409793003, 92409793005, 92409793006 METHOD BLANK: 2450452 Matrix: Water Associated Lab Samples: 92409793001, 92409793003, 92409793005, 92409793006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/13/18 05:13 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/13/18 05:13 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/13/18 05:13 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/13/18 05:13 1,1-Dichloroethane ug/L ND 1.0 0.32 12/13/18 05:13 1,1-Dichloroethene ug/L ND 1.0 0.56 12/13/18 05:13 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/13/18 05:13 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/13/18 05:13 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/13/18 05:13 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/13/18 05:13 1,2-Dichloroethane ug/L ND 1.0 0.24 12/13/18 05:13 1,2-Dichloropropane ug/L ND 1.0 0.27 12/13/18 05:13 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/13/18 05:13 2-Butanone (MEK) ug/L ND 5.0 0.96 12/13/18 05:13 2-Hexanone ug/L ND 5.0 0.46 12/13/18 05:13 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/13/18 05:13 Acetone ug/L ND 25.0 10.0 12/13/18 05:13 Acrylonitrile ug/L ND 10.0 1.9 12/13/18 05:13 Benzene ug/L ND 1.0 0.25 12/13/18 05:13 Bromochloromethane ug/L ND 1.0 0.17 12/13/18 05:13 Bromodichloromethane ug/L ND 1.0 0.18 12/13/18 05:13 Bromoform ug/L ND 1.0 0.26 12/13/18 05:13 Bromomethane ug/L ND 2.0 0.29 12/13/18 05:13 Carbon disulfide ug/L ND 2.0 1.2 12/13/18 05:13 Carbon tetrachloride ug/L ND 1.0 0.25 12/13/18 05:13 Chlorobenzene ug/L ND 1.0 0.23 12/13/18 05:13 Chloroethane ug/L ND 1.0 0.54 12/13/18 05:13 Chloroform ug/L ND 1.0 0.14 12/13/18 05:13 Chloromethane ug/L ND 1.0 0.11 12/13/18 05:13 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/13/18 05:13 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/13/18 05:13 Dibromochloromethane ug/L ND 1.0 0.21 12/13/18 05:13 Dibromomethane ug/L ND 1.0 0.21 12/13/18 05:13 Ethylbenzene ug/L ND 1.0 0.30 12/13/18 05:13 lodomethane ug/L ND 5.0 0.32 12/13/18 05:13 Methylene Chloride ug/L ND 1.0 0.97 12/13/18 05:13 Styrene ug/L ND 1.0 0.26 12/13/18 05:13 Tetrachloroethene ug/L ND 1.0 0.46 12/13/18 05:13 Toluene ug/L ND 1.0 0.26 12/13/18 05:13 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/13/18 05:13 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/13/18 05:13 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 METHOD BLANK: 2450452 Matrix: Water Associated Lab Samples: 92409793001, 92409793003, 92409793005, 92409793006 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 12/13/18 05:13 Trichloroethene ug/L ND 1.0 0.47 12/13/18 05:13 Trichlorofluoromethane ug/L ND 1.0 0.20 12/13/18 05:13 Vinyl acetate ug/L ND 2.0 0.35 12/13/18 05:13 Vinyl chloride ug/L ND 1.0 0.62 12/13/18 05:13 Xylene (Total) ug/L ND 1.0 0.66 12/13/18 05:13 1,2-Dichloroethane-d4 (S) % 88 70-130 12/13/18 05:13 4-Bromofluorobenzene (S) % 100 70-130 12/13/18 05:13 Toluene-d8 (S) % 102 70-130 12/13/18 05:13 LABORATORY CONTROL SAMPLE: Parameter 2450453 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 52.1 104 70-130 1,1,1-Trichloroethane ug/L 50 45.0 90 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,2-Trichloroethane ug/L 50 53.5 107 70-130 1,1-Dichloroethane ug/L 50 48.1 96 70-130 1,1-Dichloroethene ug/L 50 47.7 95 70-130 1,2,3-Trichloropropane ug/L 50 46.0 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.3 103 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.1 100 70-130 1,2-Dichlorobenzene ug/L 50 49.7 99 70-130 1,2-Dichloroethane ug/L 50 45.7 91 70-130 1,2-Dichloropropane ug/L 50 50.1 100 70-130 1,4-Dichlorobenzene ug/L 50 49.2 98 70-130 2-Butanone (MEK) ug/L 100 92.5 93 64-135 2-Hexanone ug/L 100 102 102 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 102 102 70-130 Acetone ug/L 100 91.9 92 61-157 Acrylonitrile ug/L 250 228 91 61-143 Benzene ug/L 50 52.7 105 70-130 Bromochloromethane ug/L 50 48.4 97 70-130 Bromodichloromethane ug/L 50 52.7 105 70-130 Bromoform ug/L 50 46.8 94 70-130 Bromomethane ug/L 50 43.1 86 38-130 Carbon disulfide ug/L 50 47.3 95 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 50.8 102 70-130 Chloroethane ug/L 50 45.3 91 37-142 Chloroform ug/L 50 45.8 92 70-130 Chloromethane ug/L 50 42.5 85 48-130 cis-1,2-Dichloroethene ug/L 50 47.3 95 70-130 cis-1,3-Dichloropropene ug/L 50 51.9 104 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 LABORATORY CONTROL SAMPLE: 2450453 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 51.0 102 70-130 Dibromomethane ug/L 50 54.7 109 70-130 Ethylbenzene ug/L 50 51.6 103 70-130 lodomethane ug/L 100 94.4 94 40-130 Methylene Chloride ug/L 50 44.9 90 67-132 Styrene ug/L 50 52.8 106 70-130 Tetrachloroethene ug/L 50 51.0 102 69-130 Toluene ug/L 50 62.6 125 70-130 trans-1,2-Dichloroethene ug/L 50 47.9 96 70-130 trans- 1,3-Dichloropropene ug/L 50 52.9 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 51.0 102 35-189 Trichloroethene ug/L 50 51.4 103 70-130 Trichlorofluoromethane ug/L 50 46.2 92 63-130 Vinyl acetate ug/L 100 98.3 98 55-143 Vinyl chloride ug/L 50 46.5 93 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE SAMPLE: 2450490 92409812005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.5 102 73-134 1,1,1-Trichloroethane ug/L ND 20 19.0 95 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.8 99 70-136 1,1,2-Trichloroethane ug/L ND 20 20.7 103 70-135 1,1-Dichloroethane ug/L ND 20 19.4 97 70-139 1,1-Dichloroethene ug/L ND 20 19.5 97 70-154 1,2,3-Trichloropropane ug/L ND 20 20.9 104 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 19.1 95 70-137 1,2-Dichlorobenzene ug/L ND 20 18.8 94 70-133 1,2-Dichloroethane ug/L ND 20 18.1 90 70-137 1,2-Dichloropropane ug/L ND 20 19.2 96 70-140 1,4-Dichlorobenzene ug/L ND 20 18.3 92 70-133 2-Butanone (MEK) ug/L ND 40 38.1 95 60-139 2-Hexanone ug/L ND 40 40.5 101 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 40.0 100 65-135 Acetone ug/L ND 40 40.9 102 60-148 Acrylonitrile ug/L ND 100 90.7 91 64-147 Benzene ug/L ND 20 21.0 105 70-151 Bromochloromethane ug/L ND 20 19.7 98 70-141 Bromodichloromethane ug/L ND 20 20.4 102 70-138 Bromoform ug/L ND 20 18.4 92 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 MATRIX SPIKE SAMPLE: Parameter 2450490 Units 92409812005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 16.4 82 15-152 Carbon disulfide ug/L ND 20 19.0 95 69-149 Carbon tetrachloride ug/L ND 20 21.0 105 70-143 Chlorobenzene ug/L ND 20 19.7 99 70-138 Chloroethane ug/L ND 20 18.3 92 52-163 Chloroform ug/L ND 20 17.6 88 70-139 Chloromethane ug/L ND 20 18.0 90 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.3 96 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.2 96 70-137 Dibromochloromethane ug/L ND 20 19.6 98 70-134 Dibromomethane ug/L ND 20 20.6 103 70-138 Ethylbenzene ug/L ND 20 20.5 102 66-153 lodomethane ug/L ND 40 25.3 63 20-138 Methylene Chloride ug/L ND 20 16.1 80 42-159 Styrene ug/L ND 20 19.8 99 70-135 Tetrachloroethene ug/L ND 20 21.0 105 59-143 Toluene ug/L ND 20 21.3 107 59-148 trans-1,2-Dichloroethene ug/L ND 20 19.8 99 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.5 97 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.4 97 47-135 Trichloroethene ug/L ND 20 20.8 104 70-147 Trichlorofluoromethane ug/L ND 20 19.8 99 70-148 Vinyl acetate ug/L ND 40 27.9 70 49-151 Vinyl chloride ug/L ND 20 19.0 95 70-156 Xylene (Total) ug/L ND 60 60.9 101 63-158 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 2450489 Parameter Units 92409664002 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND 0.78J 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 SAMPLE DUPLICATE: 2450489 Parameter Units 92409664002 Result Dup Result 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND 0.34J Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 90 86 4-Bromofluorobenzene (S) % 99 101 Toluene-d8(S) % 100 101 Max RPD RPD Qualifiers 5 2 1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 447145 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409793002, 92409793004 METHOD BLANK: 2450496 Associated Lab Samples: 92409793002, 92409793004 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/13/18 05:30 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/13/18 05:30 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/13/18 05:30 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/13/18 05:30 1,1-Dichloroethane ug/L ND 1.0 0.32 12/13/18 05:30 1,1-Dichloroethene ug/L ND 1.0 0.56 12/13/18 05:30 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/13/18 05:30 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/13/18 05:30 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/13/18 05:30 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/13/18 05:30 1,2-Dichloroethane ug/L ND 1.0 0.24 12/13/18 05:30 1,2-Dichloropropane ug/L ND 1.0 0.27 12/13/18 05:30 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/13/18 05:30 2-Butanone (MEK) ug/L ND 5.0 0.96 12/13/18 05:30 2-Hexanone ug/L ND 5.0 0.46 12/13/18 05:30 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/13/18 05:30 Acetone ug/L ND 25.0 10.0 12/13/18 05:30 Acrylonitrile ug/L ND 10.0 1.9 12/13/18 05:30 Benzene ug/L ND 1.0 0.25 12/13/18 05:30 Bromochloromethane ug/L ND 1.0 0.17 12/13/18 05:30 Bromodichloromethane ug/L ND 1.0 0.18 12/13/18 05:30 Bromoform ug/L ND 1.0 0.26 12/13/18 05:30 Bromomethane ug/L ND 2.0 0.29 12/13/18 05:30 Carbon disulfide ug/L ND 2.0 1.2 12/13/18 05:30 Carbon tetrachloride ug/L ND 1.0 0.25 12/13/18 05:30 Chlorobenzene ug/L ND 1.0 0.23 12/13/18 05:30 Chloroethane ug/L ND 1.0 0.54 12/13/18 05:30 Chloroform ug/L ND 1.0 0.14 12/13/18 05:30 Chloromethane ug/L ND 1.0 0.11 12/13/18 05:30 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/13/18 05:30 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/13/18 05:30 Dibromochloromethane ug/L ND 1.0 0.21 12/13/18 05:30 Dibromomethane ug/L ND 1.0 0.21 12/13/18 05:30 Ethylbenzene ug/L ND 1.0 0.30 12/13/18 05:30 lodomethane ug/L ND 5.0 0.32 12/13/18 05:30 Methylene Chloride ug/L ND 1.0 0.97 12/13/18 05:30 Styrene ug/L ND 1.0 0.26 12/13/18 05:30 Tetrachloroethene ug/L ND 1.0 0.46 12/13/18 05:30 Toluene ug/L ND 1.0 0.26 12/13/18 05:30 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/13/18 05:30 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/13/18 05:30 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 METHOD BLANK: 2450496 Matrix: Water Associated Lab Samples: 92409793002, 92409793004 Blank Reporting Parameter Units Result Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 91 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 Analyzed 1.0 12/13/18 05:30 0.47 12/13/18 05:30 0.20 12/13/18 05:30 0.35 12/13/18 05:30 0.62 12/13/18 05:30 0.66 12/13/18 05:30 12/13/18 05:30 12/13/18 05:30 12/13/18 05:30 LABORATORY CONTROL SAMPLE: Parameter 2450497 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,1-Trichloroethane ug/L 50 46.6 93 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.5 105 70-130 1,1,2-Trichloroethane ug/L 50 53.4 107 70-130 1,1-Dichloroethane ug/L 50 47.5 95 70-130 1,1-Dichloroethene ug/L 50 49.0 98 70-130 1,2,3-Trichloropropane ug/L 50 45.3 91 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.8 104 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.0 102 70-130 1,2-Dichlorobenzene ug/L 50 51.8 104 70-130 1,2-Dichloroethane ug/L 50 45.5 91 70-130 1,2-Dichloropropane ug/L 50 49.4 99 70-130 1,4-Dichlorobenzene ug/L 50 52.0 104 70-130 2-Butanone (MEK) ug/L 100 91.5 91 64-135 2-Hexanone ug/L 100 101 101 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 101 101 70-130 Acetone ug/L 100 91.0 91 61-157 Acrylonitrile ug/L 250 231 92 61-143 Benzene ug/L 50 53.2 106 70-130 Bromochloromethane ug/L 50 48.8 98 70-130 Bromodichloromethane ug/L 50 52.5 105 70-130 Bromoform ug/L 50 47.2 94 70-130 Bromomethane ug/L 50 46.4 93 38-130 Carbon disulfide ug/L 50 48.4 97 68-130 Carbon tetrachloride ug/L 50 50.9 102 70-130 Chlorobenzene ug/L 50 51.1 102 70-130 Chloroethane ug/L 50 44.9 90 37-142 Chloroform ug/L 50 46.7 93 70-130 Chloromethane ug/L 50 43.9 88 48-130 cis-1,2-Dichloroethene ug/L 50 49.0 98 70-130 cis-1,3-Dichloropropene ug/L 50 51.8 104 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 LABORATORY CONTROL SAMPLE: 2450497 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 52.2 104 70-130 Dibromomethane ug/L 50 53.4 107 70-130 Ethylbenzene ug/L 50 52.0 104 70-130 lodomethane ug/L 100 94.2 94 40-130 Methylene Chloride ug/L 50 45.9 92 67-132 Styrene ug/L 50 53.0 106 70-130 Tetrachloroethene ug/L 50 51.6 103 69-130 Toluene ug/L 50 51.6 103 70-130 trans-1,2-Dichloroethene ug/L 50 48.8 98 70-130 trans- 1,3-Dichloropropene ug/L 50 51.7 103 70-130 trans-1,4-Dichloro-2-butene ug/L 50 49.8 100 35-189 Trichloroethene ug/L 50 52.5 105 70-130 Trichlorofluoromethane ug/L 50 46.1 92 63-130 Vinyl acetate ug/L 100 100 100 55-143 Vinyl chloride ug/L 50 46.5 93 70-131 Xylene (Total) ug/L 150 159 106 70-130 1,2-Dichloroethane-d4 (S) % 89 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2450498 2450499 MS MSD 92409793004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 18.3 19.2 92 96 73-134 4 30 1,1,1-Trichloroethane ug/L ND 20 20 20.0 20.9 100 104 82-143 4 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 17.8 19.3 89 97 70-136 8 30 1,1,2-Trichloroethane ug/L ND 20 20 19.2 19.0 96 95 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 19.8 20.3 99 101 70-139 3 30 1,1-Dichloroethene ug/L ND 20 20 20.3 19.5 102 97 70-154 4 30 1,2,3-Trichloropropane ug/L ND 20 20 17.8 18.4 89 92 71-137 4 30 1,2-Dibromo-3- ug/L ND 20 20 17.3 17.7 87 89 65-134 2 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 17.7 19.2 89 96 70-137 8 30 1,2-Dichlorobenzene ug/L ND 20 20 18.7 19.1 93 95 70-133 2 30 1,2-Dichloroethane ug/L ND 20 20 19.2 19.4 96 97 70-137 1 30 1,2-Dichloropropane ug/L ND 20 20 19.8 19.7 99 98 70-140 0 30 1,4-Dichlorobenzene ug/L ND 20 20 18.5 19.2 92 96 70-133 4 30 2-Butanone (MEK) ug/L ND 40 40 38.4 40.8 96 102 60-139 6 30 2-Hexanone ug/L ND 40 40 32.2 35.2 80 88 65-138 9 30 4-Methyl-2-pentanone ug/L ND 40 40 35.8 36.1 89 90 65-135 1 30 (MIBK) Acetone ug/L ND 40 40 34.5 35.0 86 87 60-148 1 30 Acrylonitrile ug/L ND 100 100 96.6 97.9 97 98 64-147 1 30 Benzene ug/L ND 20 20 21.0 20.4 105 102 70-151 3 30 Bromochloromethane ug/L ND 20 20 19.3 20.3 97 102 70-141 5 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 36 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2450498 2450499 MS MSD 92409793004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromodichloromethane ug/L ND 20 20 18.8 18.3 94 92 70-138 3 30 Bromoform ug/L ND 20 20 14.0 14.8 70 74 63-130 6 30 Bromomethane ug/L ND 20 20 16.1 16.9 81 84 15-152 5 30 Carbon disulfide ug/L ND 20 20 19.2 19.7 96 99 69-149 2 30 Carbon tetrachloride ug/L ND 20 20 19.6 19.6 98 98 70-143 0 30 Chlorobenzene ug/L ND 20 20 18.3 19.1 92 96 70-138 4 30 Chloroethane ug/L ND 20 20 18.5 20.2 93 101 52-163 9 30 Chloroform ug/L ND 20 20 20.7 20.5 103 103 70-139 1 30 Chloromethane ug/L ND 20 20 18.2 17.4 91 87 41-139 4 30 cis-1,2-Dichloroethene ug/L 3.9 20 20 24.9 24.9 105 105 70-141 0 30 cis-1,3-Dichloropropene ug/L ND 20 20 19.6 18.7 98 93 70-137 5 30 Dibromochloromethane ug/L ND 20 20 17.1 18.2 85 91 70-134 7 30 Dibromomethane ug/L ND 20 20 19.2 18.6 96 93 70-138 3 30 Ethylbenzene ug/L ND 20 20 18.8 19.7 94 99 66-153 5 30 lodomethane ug/L ND 40 40 18.2 22.2 45 55 20-138 20 30 Methylene Chloride ug/L ND 20 20 19.4 19.0 97 95 42-159 2 30 Styrene ug/L ND 20 20 19.0 19.3 95 96 70-135 1 30 Tetrachloroethene ug/L ND 20 20 18.6 19.1 93 96 59-143 3 30 Toluene ug/L ND 20 20 19.3 19.0 97 95 59-148 2 30 trans-1,2-Dichloroethene ug/L ND 20 20 19.5 18.7 97 93 70-146 4 30 trans-1,3-Dichloropropene ug/L ND 20 20 19.5 18.8 97 94 70-135 3 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 18.0 17.2 90 86 47-135 4 30 Trichloroethene ug/L ND 20 20 21.8 21.1 109 106 70-147 3 30 Trichlorofluoromethane ug/L ND 20 20 19.9 19.7 100 99 70-148 1 30 Vinyl acetate ug/L ND 40 40 40.4 42.0 101 105 49-151 4 30 Vinyl chloride ug/L ND 20 20 21.1 21.2 105 106 70-156 0 30 Xylene (Total) ug/L ND 60 60 57.4 59.3 96 99 63-158 3 30 1,2-Dichloroethane-d4 (S) % 96 91 70-130 4-Bromofluorobenzene (S) % 101 102 70-130 Toluene-d8 (S) % 101 97 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 446769 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005 METHOD BLANK: 2448638 Matrix: Water Associated Lab Samples: 92409793001, 92409793002, 92409793003, 92409793004, 92409793005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/12/18 16:33 1,2-Dichloroethane-d4 (S) % 101 50-150 12/12/18 16:33 Toluene-d8 (S) % 101 50-150 12/12/18 16:33 LABORATORY CONTROL SAMPLE: 2448639 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.1 86 71-125 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8(S) % 101 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2448640 2448641 MS MSD 92409426003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.0 16.5 85 83 50-150 3 30 1,2-Dichloroethane-d4 (S) % 93 93 50-150 30 Toluene-d8 (S) % 104 103 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. East Burke Pace Project No.: 92409793 QC Batch: 447055 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409793006 METHOD BLANK: 2449939 Associated Lab Samples: 92409793006 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 95 50-150 98 50-150 MDL Analyzed 1.9 12/12/18 16:14 12/12/18 16:14 12/12/18 16:14 Qualifiers LABORATORY CONTROL SAMPLE: 2449940 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 16.9 85 71-125 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 101 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2449941 2449942 MS MSD 92409793006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 10.1 20 20 26.1 25.1 80 75 50-150 4 30 1,2-Dichloroethane-d4 (S) % 100 102 50-150 30 Toluene-d8 (S) % 111 114 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co. East Burke Pace Project No.: 92409793 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:53 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 36 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Burke Co. East Burke 92409793 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92409793001 1202-MW1 EPA 3010A 446502 EPA 6010D 446519 92409793002 1202-MW2 EPA 3010A 446502 EPA 6010D 446519 92409793003 1202-MW3 EPA 3010A 446502 EPA 6010D 446519 92409793004 1202-AMW1 EPA 3010A 446502 EPA 6010D 446519 92409793005 1202-SW1 EPA 3010A 446502 EPA 6010D 446519 92409793006 1202-SW2 EPA 3010A 446502 EPA 6010D 446519 92409793001 1202-MW1 EPA 3010A 446880 EPA 6020B 447020 92409793002 1202-MW2 EPA 3010A 446880 EPA 6020B 447020 92409793003 1202-MW3 EPA 3010A 446880 EPA 6020B 447020 92409793004 1202-AMW1 EPA 3010A 446880 EPA 6020B 447020 92409793005 1202-SW1 EPA 3010A 446880 EPA 6020B 447020 92409793006 1202-SW2 EPA 3010A 446880 EPA 6020B 447020 92409793001 1202-MW1 EPA 8260B 447140 92409793002 1202-MW2 EPA 8260B 447145 92409793003 1202-MW3 EPA 8260B 447140 92409793004 1202-AMW1 EPA 8260B 447145 92409793005 1202-SW1 EPA 8260B 447140 92409793006 1202-SW2 EPA 8260B 447140 92409793001 1202-MW1 EPA 8260B Mod. 446769 92409793002 1202-MW2 EPA 8260B Mod. 446769 92409793003 1202-MW3 EPA 8260B Mod. 446769 92409793004 1202-AMW1 EPA 8260B Mod. 446769 92409793005 1202-SW1 EPA 8260B Mod. 446769 92409793006 1202-SW2 EPA 8260B Mod. 447055 Date: 12/17/2018 04:53 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 36 m aceAnavicai Document Name: Sample Condition Upon Receipt(SCUR) Document Revise& February 7, 2018 Page 1 of 2 Document No.: F•CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville E] Raleigh[] Mechanicsville❑ Sample Condition Client Name: Project y lWO# : 924Q9793 Upon Receipt 6 L Courier: -❑ d Ex ❑UPS ❑USPS []Client El Commercial Pace ❑Other: 92409793 Custody Seal Present? ❑Yes '1 No Seals tntact? []Yes ❑No' Date/Initials Person Examining Contents: Packing Material: ❑Bubble Wrap 12tubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: ❑Yes ❑No ❑l N%A gjR�Gun ID: 92T046 Type of Ice: owet [_-]Blue []None Cooler Temp (°C): , ) Correction Factor: Add/Subtract (°C) 0.0 Temp should be above freezing to 6°C Cooler Temp Corrected (°Cf : ❑Samples out of temp criteria. Samples on ice, cooling process bas begun USDA Regulated Soil (E]-N//A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, —Iv,.. 741 inrhidine Hawaii and Puerto Rico,? Ayes ❑No Comments/Discrepancy: Chain of Custody Present? QYe/s ❑No ❑N/A 1. Samples Arrived within Hold Time? 13Y s (:]No ❑NIA 2. Short Hold Time Analysis (<72 hr.)? ❑Yes ❑ oo ❑N/A 3. Rush Turn Around Time Requested? ❑Yes 4DIrvo El NIA 4, Sufficient Volume? es ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? es , jD�, ❑No ❑No ❑N/A ❑NIA 6, Containers intact? -tyres ❑No ❑NIA, 7. Dissolved analysis: Samples Field Filtered? Dyes ❑Na A 8. Sample Labels Match COC? -Includes Date/Tirne/ID/Analysis Matrix: []yes I []No ❑NIA 9. Headspace in VOA Vials (>5-6mm)? ❑Yes uN/- 10. Trip Blank Present? Trip BlankCuslodySeals Present? ❑Yes []Yes❑No ❑No IDN/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/T,me: Field Data Required? ❑Yes ❑No Lot ID of split containers: Date: (?— 7 ` y $ Date: - f'21 (7-1 IS Page 34 of 36 Document Name: Sample Condition Upon Receil Document No.: F-CAR-CS.033-Rev.06 Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or clechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, Ll-Hg **Bottom half of box is to list number of mottle V w _ ` Q Z Z QA. .U.• _ Z Z N N Z � 2 41 S 2 ate+ a n !a. v O O I ¢CL r c 7 7 C 2 S N V V 4 V V V m m ro R E E E v E E E N O N .n O Ln n, m — r.i .n ry 1 E M N rl Q rM ' « a m a m a m n. m a m a oa a m 1 1 2 4 1 s X 6 7 S 9 10 11 12 Project Wo# ; 92409793 i2M: NMG Due Date: 12/19/18 CLIENT: 92—Joyce Eng { � —° f7 o y J o z a C a `m H 7 i7t7 4 e U 2 �`m .i S ¢ c 7 E c N 6 rn - i7 4 N O Ln N 2 a ei yr ,� [7 Q N O 2 E O Ln NM ViN m 1.7 a u E a J E o m ❑ rn l% a Z '_' U a J E a m V 4 o VI IC Z a J E m l7 7 2 C O a E O l9 O MX a f O = 0 x e m s O> Z a = a! a r y N z m W m .N-I i ry, �_ °'JE E o N a _ n y In Z Y z j Z c O '�+ o 7 z a C 7 4 a E E ❑ ❑ C: pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot # a I added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will N sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 35 of 36 D rn a y � t z Z m S 7 3 3 m n m g o n z En h O � � N m m z r A -e > m M m n O m m 0 Ca N c 10 w -1 1n v+ ,- w ►,3 - ITEM# Nc N � N N cN C C N N W O W n tl_ Z o n r _ n n m O v ran z 0 N o a Q p n q3j o � a o O E a n tl O O W m r_a� Cr oo 0 Sw m O� C v N A ' M C, V ? O �. [D O rA N ❑ @ � m a � x ,C w ~ o n e o ro n m N a A a r r -L 0 O ° p rl Co 6 nO v h1ATRIX CODE (see valid codes to left) t° O `, C m' z z m n 75 SAMPLETYPE (G=GRAB C=COh1P) W p D l CD Cr m " 0 cn n 0 s rn 0r v m !A r rn c w J� m f N ry c� z L ; �' rn SAMPLE MAP AT COLLECTION # OF CONTAINERS unpreserved H2SO4 HNO3 v HCI N N NaOH a� Na2S203 m Methanol Other A nol�. �. T.... NC Appendix I Maims NC Appendix I V NOMINEE IMMEMEME MM TEMP in C I � Received on ce(Ym) ;ustody Sealed ,Dolor(YIN) )amwas Intact 1 11 n 3 r- m h O 2 O 0 0 z N �.S ,S\ 01 ry 0 o r �o 'n v Y n w i m a Cn 0 v o 3� n ��N� o m0 r- N m O p L 01 C m m Cr C z o m m `C mCD D m X v n �1 O S fD O C CD x 0 7 =^ C D N ua 0 N 3 Q O m O � n CD 3 a w n C z N � @ a CD 0 m C C m o o $ n n O Li Page 36 of 36 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 17, 2018 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 27 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Lab ID Sample ID Matrix Date Collected Date Received 92409786001 92409786002 FIELD BLANK TRIP BLANK Water Water 12/04/18 09:05 12/03/18 05:20 12/05/18 14:05 12/05/18 14:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co. Blanks EB & Kirksey 92409786 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92409786001 FIELD BLANK EPA 6010D DS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409786002 TRIP BLANK EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: FIELD BLANK Lab ID: 92409786001 Collected: 12/04/18 09:05 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/17/2018 04:01 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/13/18 09:53 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7440-38-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/13/18 09:53 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/13/18 09:53 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-47-3 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7439-92-1 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:25 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/16/18 01:30 67-64-1 ND ug/L 10.0 1.9 1 12/16/18 01:30 107-13-1 ND ug/L 1.0 0.25 1 12/16/18 01:30 71-43-2 ND ug/L 1.0 0.17 1 12/16/18 01:30 74-97-5 ND ug/L 1.0 0.18 1 12/16/18 01:30 75-27-4 ND ug/L 1.0 0.26 1 12/16/18 01:30 75-25-2 ND ug/L 2.0 0.29 1 12/16/18 01:30 74-83-9 ND ug/L 5.0 0.96 1 12/16/18 01:30 78-93-3 ND ug/L 2.0 1.2 1 12/16/18 01:30 75-15-0 ND ug/L 1.0 0.25 1 12/16/18 01:30 56-23-5 ND ug/L 1.0 0.23 1 12/16/18 01:30 108-90-7 ND ug/L 1.0 0.54 1 12/16/18 01:30 75-00-3 ND ug/L 1.0 0.14 1 12/16/18 01:30 67-66-3 ND ug/L 1.0 0.11 1 12/16/18 01:30 74-87-3 ND ug/L 2.0 2.0 1 12/16/18 01:30 96-12-8 ND ug/L 1.0 0.21 1 12/16/18 01:30 124-48-1 ND ug/L 1.0 0.27 1 12/16/18 01:30 106-93-4 ND ug/L 1.0 0.21 1 12/16/18 01:30 74-95-3 ND ug/L 1.0 0.30 1 12/16/18 01:30 95-50-1 ND ug/L 1.0 0.33 1 12/16/18 01:30 106-46-7 ND ug/L 1.0 1.0 1 12/16/18 01:30 110-57-6 ND ug/L 1.0 0.32 1 12/16/18 01:30 75-34-3 ND ug/L 1.0 0.24 1 12/16/18 01:30 107-06-2 ND ug/L 1.0 0.56 1 12/16/18 01:30 75-35-4 ND ug/L 1.0 0.19 1 12/16/18 01:30 156-59-2 ND ug/L 1.0 0.49 1 12/16/18 01:30 156-60-5 ND ug/L 1.0 0.27 1 12/16/18 01:30 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: FIELD BLANK Lab ID: 92409786001 Collected: 12/04/18 09:05 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:01 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 99 % 70-130 87 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 102 % 50-150 111 % 50-150 0.13 1 12/16/18 01:30 10061-01-5 0.26 1 12/16/18 01:30 10061-02-6 0.30 1 12/16/18 01:30 100-41-4 0.46 1 12/16/18 01:30 591-78-6 0.32 1 12/16/18 01:30 74-88-4 0.97 1 12/16/18 01:30 75-09-2 0.33 1 12/16/18 01:30 108-10-1 0.26 1 12/16/18 01:30 100-42-5 0.33 1 12/16/18 01:30 630-20-6 0.40 1 12/16/18 01:30 79-34-5 0.46 1 12/16/18 01:30 127-18-4 0.26 1 12/16/18 01:30 108-88-3 0.48 1 12/16/18 01:30 71-55-6 0.29 1 12/16/18 01:30 79-00-5 0.47 1 12/16/18 01:30 79-01-6 0.20 1 12/16/18 01:30 75-69-4 0.41 1 12/16/18 01:30 96-18-4 0.35 1 12/16/18 01:30 108-05-4 0.62 1 12/16/18 01:30 75-01-4 0.66 1 12/16/18 01:30 1330-20-7 1 12/16/18 01:30 460-00-4 1 12/16/18 01:30 17060-07-0 1 12/16/18 01:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 16:00 123-91-1 12/ 13/ 18 16:00 17060-07-0 12/13/1816:00 2037-26-5 Page 6 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: TRIP BLANK Lab ID: 92409786002 Collected: 12/03/18 05:20 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Date: 12/17/2018 04:01 PM Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/07/1814:37 67-64-1 ND ug/L 10.0 1.9 1 12/07/1814:37 107-13-1 ND ug/L 1.0 0.25 1 12/07/1814:37 71-43-2 ND ug/L 1.0 0.17 1 12/07/1814:37 74-97-5 ND ug/L 1.0 0.18 1 12/07/1814:37 75-27-4 ND ug/L 1.0 0.26 1 12/07/1814:37 75-25-2 ND ug/L 2.0 0.29 1 12/07/1814:37 74-83-9 ND ug/L 5.0 0.96 1 12/07/1814:37 78-93-3 ND ug/L 2.0 1.2 1 12/07/1814:37 75-15-0 ND ug/L 1.0 0.25 1 12/07/1814:37 56-23-5 ND ug/L 1.0 0.23 1 12/07/1814:37 108-90-7 ND ug/L 1.0 0.54 1 12/07/1814:37 75-00-3 ND ug/L 1.0 0.14 1 12/07/1814:37 67-66-3 ND ug/L 1.0 0.11 1 12/07/1814:37 74-87-3 ND ug/L 2.0 2.0 1 12/07/1814:37 96-12-8 ND ug/L 1.0 0.21 1 12/07/1814:37 124-48-1 ND ug/L 1.0 0.27 1 12/07/1814:37 106-93-4 ND ug/L 1.0 0.21 1 12/07/1814:37 74-95-3 ND ug/L 1.0 0.30 1 12/07/1814:37 95-50-1 ND ug/L 1.0 0.33 1 12/07/1814:37 106-46-7 ND ug/L 1.0 1.0 1 12/07/1814:37 110-57-6 ND ug/L 1.0 0.32 1 12/07/1814:37 75-34-3 ND ug/L 1.0 0.24 1 12/07/1814:37 107-06-2 ND ug/L 1.0 0.56 1 12/07/1814:37 75-35-4 ND ug/L 1.0 0.19 1 12/07/1814:37 156-59-2 ND ug/L 1.0 0.49 1 12/07/1814:37 156-60-5 ND ug/L 1.0 0.27 1 12/07/1814:37 78-87-5 ND ug/L 1.0 0.13 1 12/07/1814:37 10061-01-5 ND ug/L 1.0 0.26 1 12/07/1814:37 10061-02-6 ND ug/L 1.0 0.30 1 12/07/1814:37 100-41-4 ND ug/L 5.0 0.46 1 12/07/1814:37 591-78-6 ND ug/L 5.0 0.32 1 12/07/1814:37 74-88-4 ND ug/L 1.0 0.97 1 12/07/1814:37 75-09-2 ND ug/L 5.0 0.33 1 12/07/1814:37 108-10-1 ND ug/L 1.0 0.26 1 12/07/1814:37 100-42-5 ND ug/L 1.0 0.33 1 12/07/1814:37 630-20-6 ND ug/L 1.0 0.40 1 12/07/1814:37 79-34-5 ND ug/L 1.0 0.46 1 12/07/1814:37 127-18-4 ND ug/L 1.0 0.26 1 12/07/1814:37 108-88-3 ND ug/L 1.0 0.48 1 12/07/1814:37 71-55-6 ND ug/L 1.0 0.29 1 12/07/1814:37 79-00-5 ND ug/L 1.0 0.47 1 12/07/1814:37 79-01-6 ND ug/L 1.0 0.20 1 12/07/1814:37 75-69-4 ND ug/L 1.0 0.41 1 12/07/1814:37 96-18-4 ND ug/L 2.0 0.35 1 12/07/1814:37 108-05-4 ND ug/L 1.0 0.62 1 12/07/1814:37 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 L1 Page 7 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: TRIP BLANK Lab ID: 92409786002 Collected: 12/03/18 05:20 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Xylene (Total) ND ug/L 1.0 0.66 1 12/07/18 14:37 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 12/07/18 14:37 460-00-4 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 12/07/18 14:37 17060-07-0 Toluene-d8 (S) 96 % 70-130 1 12/07/18 14:37 2037-26-5 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/12/18 17:12 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 94 % 50-150 1 12/12/18 17:12 17060-07-0 Toluene-d8 (S) 99 % 50-150 1 12/12/18 17:12 2037-26-5 Date: 12/17/2018 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446500 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92409786001 METHOD BLANK: 2447328 Associated Lab Samples: 92409786001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 12/13/18 08:15 Arsenic ug/L ND 10.0 5.0 12/13/18 08:15 Barium ug/L ND 5.0 2.5 12/13/18 08:15 Beryllium ug/L ND 1.0 0.50 12/13/18 08:15 Cadmium ug/L ND 1.0 0.50 12/13/18 08:15 Chromium ug/L ND 5.0 2.5 12/13/18 08:15 Cobalt ug/L ND 5.0 2.5 12/13/18 08:15 Copper ug/L ND 5.0 2.5 12/13/18 08:15 Lead ug/L ND 5.0 2.5 12/13/18 08:15 Nickel ug/L ND 5.0 2.5 12/13/18 08:15 Selenium ug/L ND 10.0 5.0 12/13/18 08:15 Silver ug/L ND 5.0 2.5 12/13/18 08:15 Vanadium ug/L ND 5.0 2.5 12/13/18 08:15 Zinc ug/L ND 10.0 5.0 12/13/18 08:15 LABORATORY CONTROL SAMPLE: Parameter 2447329 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 474 95 80-120 Arsenic ug/L 500 465 93 80-120 Barium ug/L 500 481 96 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 473 95 80-120 Chromium ug/L 500 470 94 80-120 Cobalt ug/L 500 469 94 80-120 Copper ug/L 500 480 96 80-120 Lead ug/L 500 468 94 80-120 Nickel ug/L 500 466 93 80-120 Selenium ug/L 500 460 92 80-120 Silver ug/L 250 244 98 80-120 Vanadium ug/L 500 470 94 80-120 Zinc ug/L 500 469 94 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447330 2447331 MS MSD 92409826001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 492 474 98 95 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB Pace Project No.: 92409786 & Kirksey MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447330 2447331 MS MSD 92409826001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 474 457 95 91 75-125 4 20 Barium ug/L 24.6 500 500 516 499 98 95 75-125 3 20 Beryllium ug/L ND 500 500 498 477 100 95 75-125 4 20 Cadmium ug/L ND 500 500 483 468 97 94 75-125 3 20 Chromium ug/L ND 500 500 486 471 97 94 75-125 3 20 Cobalt ug/L ND 500 500 480 462 96 92 75-125 4 20 Copper ug/L ND 500 500 490 474 98 95 75-125 3 20 Lead ug/L ND 500 500 474 458 95 91 75-125 4 20 Nickel ug/L ND 500 500 479 461 96 92 75-125 4 20 Selenium ug/L ND 500 500 481 466 96 93 75-125 3 20 Silver ug/L ND 250 250 250 245 100 98 75-125 2 20 Vanadium ug/L ND 500 500 481 467 96 93 75-125 3 20 Zinc ug/L ND 500 500 484 466 97 93 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446879 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92409786001 METHOD BLANK: 2449121 Matrix: Water Associated Lab Samples: 92409786001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/14/18 23:02 LABORATORY CONTROL SAMPLE: 2449122 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2449123 2449124 MS MSD 92409256007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.2 10.0 102 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446318 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409786002 METHOD BLANK: 2446318 Associated Lab Samples: 92409786002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/07/18 13:29 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/07/18 13:29 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/07/18 13:29 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/07/18 13:29 1,1-Dichloroethane ug/L ND 1.0 0.32 12/07/18 13:29 1,1-Dichloroethene ug/L ND 1.0 0.56 12/07/18 13:29 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/07/18 13:29 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/07/18 13:29 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/07/18 13:29 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/07/18 13:29 1,2-Dichloroethane ug/L ND 1.0 0.24 12/07/18 13:29 1,2-Dichloropropane ug/L ND 1.0 0.27 12/07/18 13:29 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/07/18 13:29 2-Butanone (MEK) ug/L ND 5.0 0.96 12/07/18 13:29 2-Hexanone ug/L ND 5.0 0.46 12/07/18 13:29 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/07/18 13:29 Acetone ug/L ND 25.0 10.0 12/07/18 13:29 Acrylonitrile ug/L ND 10.0 1.9 12/07/18 13:29 Benzene ug/L ND 1.0 0.25 12/07/18 13:29 Bromochloromethane ug/L ND 1.0 0.17 12/07/18 13:29 Bromodichloromethane ug/L ND 1.0 0.18 12/07/18 13:29 Bromoform ug/L ND 1.0 0.26 12/07/18 13:29 Bromomethane ug/L ND 2.0 0.29 12/07/18 13:29 Carbon disulfide ug/L ND 2.0 1.2 12/07/18 13:29 Carbon tetrachloride ug/L ND 1.0 0.25 12/07/18 13:29 Chlorobenzene ug/L ND 1.0 0.23 12/07/18 13:29 Chloroethane ug/L ND 1.0 0.54 12/07/18 13:29 Chloroform ug/L ND 1.0 0.14 12/07/18 13:29 Chloromethane ug/L ND 1.0 0.11 12/07/18 13:29 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/07/18 13:29 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/07/18 13:29 Dibromochloromethane ug/L ND 1.0 0.21 12/07/18 13:29 Dibromomethane ug/L ND 1.0 0.21 12/07/18 13:29 Ethylbenzene ug/L ND 1.0 0.30 12/07/18 13:29 lodomethane ug/L ND 5.0 0.32 12/07/18 13:29 Methylene Chloride ug/L ND 1.0 0.97 12/07/18 13:29 Styrene ug/L ND 1.0 0.26 12/07/18 13:29 Tetrachloroethene ug/L ND 1.0 0.46 12/07/18 13:29 Toluene ug/L ND 1.0 0.26 12/07/18 13:29 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/07/18 13:29 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/07/18 13:29 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 METHOD BLANK: 2446318 Associated Lab Samples: 92409786002 Parameter Units trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2446319 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 93 70-130 94 70-130 98 70-130 MDL Analyzed 1.0 12/07/18 13:29 0.47 12/07/18 13:29 0.20 12/07/18 13:29 0.35 12/07/18 13:29 0.62 12/07/18 13:29 0.66 12/07/18 13:29 12/07/18 13:29 12/07/18 13:29 12/07/18 13:29 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.6 103 70-130 1,1,1-Trichloroethane ug/L 50 47.4 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 45.9 92 70-130 1,1,2-Trichloroethane ug/L 50 46.8 94 70-130 1,1-Dichloroethane ug/L 50 42.9 86 70-130 1,1-Dichloroethene ug/L 50 66.6 133 70-130 CV,L1 1,2,3-Trichloropropane ug/L 50 46.2 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.9 106 70-130 1,2-Dibromoethane (EDB) ug/L 50 47.5 95 70-130 1,2-Dichlorobenzene ug/L 50 48.1 96 70-130 1,2-Dichloroethane ug/L 50 44.5 89 70-130 1,2-Dichloropropane ug/L 50 43.7 87 70-130 1,4-Dichlorobenzene ug/L 50 47.5 95 70-130 2-Butanone (MEK) ug/L 100 83.9 84 64-135 2-Hexanone ug/L 100 94.5 94 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.7 94 70-130 Acetone ug/L 100 85.3 85 61-157 Acrylonitrile ug/L 250 214 86 61-143 Benzene ug/L 50 46.3 93 70-130 Bromochloromethane ug/L 50 48.7 97 70-130 Bromodichloromethane ug/L 50 50.1 100 70-130 Bromoform ug/L 50 51.5 103 70-130 Bromomethane ug/L 50 73.8 148 38-130 L1 Carbon disulfide ug/L 50 70.2 140 68-130 L1 Carbon tetrachloride ug/L 50 52.3 105 70-130 Chlorobenzene ug/L 50 47.9 96 70-130 Chloroethane ug/L 50 58.9 118 37-142 Chloroform ug/L 50 44.3 89 70-130 Chloromethane ug/L 50 46.1 92 48-130 cis-1,2-Dichloroethene ug/L 50 44.1 88 70-130 cis-1,3-Dichloropropene ug/L 50 47.1 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 LABORATORY CONTROL SAMPLE: 2446319 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 52.9 106 70-130 Dibromomethane ug/L 50 53.6 107 70-130 Ethylbenzene ug/L 50 47.0 94 70-130 lodomethane ug/L 100 146 146 40-130 L1 Methylene Chloride ug/L 50 42.3 85 67-132 Styrene ug/L 50 48.4 97 70-130 Tetrachloroethene ug/L 50 50.8 102 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 45.1 90 70-130 trans- 1,3-Dichloropropene ug/L 50 47.8 96 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.2 104 35-189 Trichloroethene ug/L 50 49.2 98 70-130 Trichlorofluoromethane ug/L 50 61.2 122 63-130 Vinyl acetate ug/L 100 87.3 87 55-143 Vinyl chloride ug/L 50 63.3 127 70-131 CV Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: 2446321 92409426005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.4 97 73-134 1,1,1-Trichloroethane ug/L ND 20 19.7 99 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.9 100 70-136 1,1,2-Trichloroethane ug/L ND 20 20.5 102 70-135 1,1-Dichloroethane ug/L ND 20 20.2 101 70-139 1,1-Dichloroethene ug/L ND 20 23.3 117 70-154 1,2,3-Trichloropropane ug/L ND 20 19.5 97 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 94 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.0 100 70-137 1,2-Dichlorobenzene ug/L ND 20 18.6 93 70-133 1,2-Dichloroethane ug/L ND 20 18.3 92 70-137 1,2-Dichloropropane ug/L ND 20 20.7 103 70-140 1,4-Dichlorobenzene ug/L ND 20 19.2 96 70-133 2-Butanone (MEK) ug/L ND 40 37.9 95 60-139 2-Hexanone ug/L ND 40 38.9 97 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 38.8 97 65-135 Acetone ug/L ND 40 40.8 102 60-148 Acrylonitrile ug/L ND 100 95.8 96 64-147 Benzene ug/L ND 20 19.4 97 70-151 Bromochloromethane ug/L ND 20 22.2 111 70-141 Bromodichloromethane ug/L ND 20 19.1 96 70-138 Bromoform ug/L ND 20 16.4 82 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 MATRIX SPIKE SAMPLE: Parameter 2446321 Units 92409426005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 25.7 129 15-152 Carbon disulfide ug/L ND 20 22.3 112 69-149 Carbon tetrachloride ug/L ND 20 18.4 92 70-143 Chlorobenzene ug/L ND 20 20.2 101 70-138 Chloroethane ug/L ND 20 23.2 116 52-163 Chloroform ug/L ND 20 19.9 99 70-139 Chloromethane ug/L ND 20 15.0 75 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.8 99 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.7 98 70-137 Dibromochloromethane ug/L ND 20 18.9 94 70-134 Dibromomethane ug/L ND 20 19.4 97 70-138 Ethylbenzene ug/L ND 20 19.6 98 66-153 lodomethane ug/L ND 40 41.4 104 20-138 Methylene Chloride ug/L ND 20 19.5 97 42-159 Styrene ug/L ND 20 19.4 97 70-135 Tetrachloroethene ug/L ND 20 18.0 90 59-143 Toluene ug/L ND 20 19.7 98 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.5 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 18.5 93 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 15.3 76 47-135 Trichloroethene ug/L ND 20 19.6 98 70-147 Trichlorofluoromethane ug/L ND 20 22.1 111 70-148 Vinyl acetate ug/L ND 40 32.6 82 49-151 Vinyl chloride ug/L ND 20 20.9 105 70-156 Xylene (Total) ug/L ND 60 59.0 98 63-158 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2446320 Parameter Units 92408410025 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 SAMPLE DUPLICATE: 2446320 Parameter Units 92408410025 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 98 4-Bromofluorobenzene (S) % 96 Toluene-d8 (S) % 96 Dup Result RPD ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 95 95 96 3 0 1 Max RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 447864 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409786001 METHOD BLANK: 2453789 Associated Lab Samples: 92409786001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/16/18 00:56 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/16/18 00:56 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/16/18 00:56 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/16/18 00:56 1,1-Dichloroethane ug/L ND 1.0 0.32 12/16/18 00:56 1,1-Dichloroethene ug/L ND 1.0 0.56 12/16/18 00:56 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/16/18 00:56 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/16/18 00:56 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/16/18 00:56 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/16/18 00:56 1,2-Dichloroethane ug/L ND 1.0 0.24 12/16/18 00:56 1,2-Dichloropropane ug/L ND 1.0 0.27 12/16/18 00:56 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/16/18 00:56 2-Butanone (MEK) ug/L ND 5.0 0.96 12/16/18 00:56 2-Hexanone ug/L ND 5.0 0.46 12/16/18 00:56 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/16/18 00:56 Acetone ug/L ND 25.0 10.0 12/16/18 00:56 Acrylonitrile ug/L ND 10.0 1.9 12/16/18 00:56 Benzene ug/L ND 1.0 0.25 12/16/18 00:56 Bromochloromethane ug/L ND 1.0 0.17 12/16/18 00:56 Bromodichloromethane ug/L ND 1.0 0.18 12/16/18 00:56 Bromoform ug/L ND 1.0 0.26 12/16/18 00:56 Bromomethane ug/L ND 2.0 0.29 12/16/18 00:56 Carbon disulfide ug/L ND 2.0 1.2 12/16/18 00:56 Carbon tetrachloride ug/L ND 1.0 0.25 12/16/18 00:56 Chlorobenzene ug/L ND 1.0 0.23 12/16/18 00:56 Chloroethane ug/L ND 1.0 0.54 12/16/18 00:56 Chloroform ug/L ND 1.0 0.14 12/16/18 00:56 Chloromethane ug/L ND 1.0 0.11 12/16/18 00:56 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/16/18 00:56 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/16/18 00:56 Dibromochloromethane ug/L ND 1.0 0.21 12/16/18 00:56 Dibromomethane ug/L ND 1.0 0.21 12/16/18 00:56 Ethylbenzene ug/L ND 1.0 0.30 12/16/18 00:56 lodomethane ug/L ND 5.0 0.32 12/16/18 00:56 Methylene Chloride ug/L ND 1.0 0.97 12/16/18 00:56 Styrene ug/L ND 1.0 0.26 12/16/18 00:56 Tetrachloroethene ug/L ND 1.0 0.46 12/16/18 00:56 Toluene ug/L ND 1.0 0.26 12/16/18 00:56 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/16/18 00:56 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/16/18 00:56 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 METHOD BLANK: 2453789 Matrix: Water Associated Lab Samples: 92409786001 Blank Reporting Parameter Units Result Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 84 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 Analyzed 1.0 12/16/18 00:56 0.47 12/16/18 00:56 0.20 12/16/18 00:56 0.35 12/16/18 00:56 0.62 12/16/18 00:56 0.66 12/16/18 00:56 12/16/18 00:56 12/16/18 00:56 12/16/18 00:56 LABORATORY CONTROL SAMPLE: Parameter 2453790 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.6 103 70-130 1,1,1-Trichloroethane ug/L 50 49.1 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.7 105 70-130 1,1,2-Trichloroethane ug/L 50 54.8 110 70-130 1,1-Dichloroethane ug/L 50 50.8 102 70-130 1,1-Dichloroethene ug/L 50 52.2 104 70-130 1,2,3-Trichloropropane ug/L 50 45.9 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.0 106 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.3 101 70-130 1,2-Dichlorobenzene ug/L 50 48.6 97 70-130 1,2-Dichloroethane ug/L 50 48.2 96 70-130 1,2-Dichloropropane ug/L 50 50.0 100 70-130 1,4-Dichlorobenzene ug/L 50 47.9 96 70-130 2-Butanone (MEK) ug/L 100 96.4 96 64-135 2-Hexanone ug/L 100 97.2 97 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 97.8 98 70-130 Acetone ug/L 100 96.3 96 61-157 Acrylonitrile ug/L 250 246 98 61-143 Benzene ug/L 50 53.8 108 70-130 Bromochloromethane ug/L 50 56.8 114 70-130 Bromodichloromethane ug/L 50 52.8 106 70-130 Bromoform ug/L 50 49.1 98 70-130 Bromomethane ug/L 50 40.7 81 38-130 Carbon disulfide ug/L 50 53.8 108 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 51.0 102 70-130 Chloroethane ug/L 50 48.4 97 37-142 Chloroform ug/L 50 49.2 98 70-130 Chloromethane ug/L 50 45.6 91 48-130 cis-1,2-Dichloroethene ug/L 50 51.2 102 70-130 cis-1,3-Dichloropropene ug/L 50 53.8 108 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 LABORATORY CONTROL SAMPLE: 2453790 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 51.5 103 70-130 Dibromomethane ug/L 50 56.9 114 70-130 Ethylbenzene ug/L 50 51.0 102 70-130 lodomethane ug/L 100 90.0 90 40-130 Methylene Chloride ug/L 50 44.4 89 67-132 Styrene ug/L 50 52.6 105 70-130 Tetrachloroethene ug/L 50 50.8 102 69-130 Toluene ug/L 50 51.3 103 70-130 trans-1,2-Dichloroethene ug/L 50 51.5 103 70-130 trans- 1,3-Dichloropropene ug/L 50 54.3 109 70-130 trans-1,4-Dichloro-2-butene ug/L 50 47.9 96 35-189 Trichloroethene ug/L 50 54.4 109 70-130 Trichlorofluoromethane ug/L 50 51.0 102 63-130 Vinyl acetate ug/L 100 99.9 100 55-143 Vinyl chloride ug/L 50 51.7 103 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2453791 2453792 MS MSD 92410469002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.0 23.0 115 115 73-134 0 30 1,1,1-Trichloroethane ug/L ND 20 20 21.1 21.3 106 107 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.9 22.0 109 110 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 23.1 23.2 115 116 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 21.3 21.6 107 108 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 21.4 21.7 107 108 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 21.8 23.7 109 118 71-137 8 30 1,2-Dibromo-3- ug/L ND 20 20 21.6 21.0 108 105 65-134 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.9 21.1 109 106 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 19.9 19.2 100 96 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 21.1 20.7 106 104 70-137 2 30 1,2-Dichloropropane ug/L ND 20 20 20.8 21.0 104 105 70-140 1 30 1,4-Dichlorobenzene ug/L ND 20 20 19.6 20.0 98 100 70-133 2 30 2-Butanone (MEK) ug/L ND 40 40 40.8 39.7 102 99 60-139 3 30 2-Hexanone ug/L ND 40 40 41.9 40.9 105 102 65-138 2 30 4-Methyl-2-pentanone ug/L ND 40 40 40.8 42.0 102 105 65-135 3 30 (MIBK) Acetone ug/L ND 40 40 43.4 43.8 108 110 60-148 1 30 Acrylonitrile ug/L ND 100 100 96.9 97.0 97 97 64-147 0 30 Benzene ug/L ND 20 20 23.3 22.9 116 115 70-151 2 30 Bromochloromethane ug/L ND 20 20 23.6 23.6 118 118 70-141 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2453791 2453792 MS MSD 92410469002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromodichloromethane ug/L ND 20 20 21.8 22.3 109 112 70-138 2 30 Bromoform ug/L ND 20 20 19.7 18.8 98 94 63-130 5 30 Bromomethane ug/L ND 20 20 15.3 16.7 76 84 15-152 9 30 Carbon disulfide ug/L ND 20 20 21.5 20.4 108 102 69-149 5 30 Carbon tetrachloride ug/L ND 20 20 23.1 23.2 115 116 70-143 0 30 Chlorobenzene ug/L ND 20 20 22.0 21.5 110 107 70-138 2 30 Chloroethane ug/L ND 20 20 21.3 20.5 106 103 52-163 4 30 Chloroform ug/L ND 20 20 20.9 20.8 104 104 70-139 0 30 Chloromethane ug/L ND 20 20 16.8 16.8 84 84 41-139 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.6 21.4 108 107 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.3 22.0 106 110 70-137 4 30 Dibromochloromethane ug/L ND 20 20 21.0 20.8 105 104 70-134 1 30 Dibromomethane ug/L ND 20 20 23.1 23.8 116 119 70-138 3 30 Ethylbenzene ug/L ND 20 20 22.2 21.6 111 108 66-153 3 30 lodomethane ug/L ND 40 40 23.4 32.5 59 81 20-138 32 30 R1 Methylene Chloride ug/L ND 20 20 17.3 17.5 86 87 42-159 1 30 Styrene ug/L ND 20 20 22.7 21.3 114 107 70-135 6 30 Tetrachloroethene ug/L ND 20 20 22.4 21.4 112 107 59-143 4 30 Toluene ug/L ND 20 20 21.7 22.4 109 112 59-148 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 22.2 109 111 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.6 22.7 108 113 70-135 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 15.6 15.1 78 75 47-135 3 30 Trichloroethene ug/L ND 20 20 23.5 23.9 117 119 70-147 2 30 Trichlorofluoromethane ug/L ND 20 20 22.0 21.3 110 107 70-148 3 30 Vinyl acetate ug/L ND 40 40 28.7 28.4 72 71 49-151 1 30 Vinyl chloride ug/L ND 20 20 19.5 19.8 97 99 70-156 2 30 Xylene (Total) ug/L ND 60 60 68.0 65.8 113 110 63-158 3 30 1,2-Dichloroethane-d4 (S) % 91 92 70-130 4-Bromofluorobenzene (S) % 104 102 70-130 Toluene-d8 (S) % 97 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446769 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409786002 METHOD BLANK: 2448638 Associated Lab Samples: 92409786002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 101 50-150 101 50-150 MDL Analyzed 1.9 12/12/18 16:33 12/12/18 16:33 12/12/18 16:33 Qualifiers LABORATORY CONTROL SAMPLE: 2448639 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.1 86 71-125 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8(S) % 101 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2448640 2448641 MS MSD 92409426003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.0 16.5 85 83 50-150 3 30 1,2-Dichloroethane-d4 (S) % 93 93 50-150 30 Toluene-d8 (S) % 104 103 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 447350 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409786001 METHOD BLANK: 2451417 Associated Lab Samples: 92409786001 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 95 50-150 108 50-150 MDL Analyzed 1.9 12/13/18 15:41 12/13/18 15:41 12/13/18 15:41 Qualifiers LABORATORY CONTROL SAMPLE: 2451418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 15.7 79 71-125 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 108 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2451420 2451421 MS MSD 92409812002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 15.3 15.0 76 75 50-150 1 30 1,2-Dichloroethane-d4 (S) % 100 96 50-150 30 Toluene-d8 (S) % 112 109 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS Cv This compound was outside of the 20% difference criteria but was not detected in any of the associated samples. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92409786001 FIELD BLANK EPA 3010A 446500 EPA 6010D 446517 92409786001 FIELD BLANK EPA 3010A 446879 EPA6020B 447018 92409786001 FIELD BLANK EPA 8260B 447864 92409786002 TRIP BLANK EPA 8260B 446318 92409786001 FIELD BLANK EPA 8260B Mod. 447350 92409786002 TRIP BLANK EPA 8260B Mod. 446769 Date: 12/17/2018 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 27 Document Name: Document Revised: February 7, 2018 m �Vce Sample Condition Upon Receipt(SOUR) Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office AmIxical Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvjlle'� Raleigh[] Mechanicsville❑ Sample Condition Client Name:Upon Receipt Project; IWO# : 92409786 (i E C- C. 1Z� v II y I I I l Courier: ❑Fed Ex ❑UPS []LISPS Client VI III II III II I I I� �Il ❑ Commercial Pace []Other: 492409786 I 111 Custody Seal Present? ❑Yes \Vo Seals Intact? ❑Yes No Packing Material: ❑Bubble Wrap "Bubble Bags ❑None El Other Thermometer: `�� 92T046 Type of Ice: Wet ❑D1ue IR Gun ID: Cooler Temp {' j: -- `I- Correction Factor: Add/Subtract ('C) 0.0 L-l- Cooler Temp Corrected ('CI: USDA Regulated Soil (tS\N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? nv— Neu a f - Date/Initials Person Examining Contents: � % Biological Tissue Frozen? ❑Yes ❑No []N/A ❑None Temp should be above freezing to 61C []Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (i ernationatly, including Hawaii and Puerto Rico)? ❑Yes No Comments/Discrepancy: Chain of Custody Present? es ❑No ❑N/A I. Samples Arrived within Hold Time? es [IN. ❑NIA 2. Short Hold Time Analysis (<72 hr.)? ❑Yes o ❑N/A 3. Rush Turn Arcund;ime Requested? C] Yes Zgpo ❑NIA 4. Sufficient Volume? fgXes ❑No ❑NIA 5. Correct Containers Used? -Pace Containers Used? ":[jYes OYCs ❑No ❑No ❑N/A ❑NIA 6. Containers Intact? 6Yes ❑No ❑N/A. 7. Dissolved analysis: Samples Field Filtered? [—]Yes ❑No NIA 8. Sample labels Match COC? -Includes Date/Time/ID/Analysis Matrix: Yes []No []N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes No [I N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? Yes es [:]No ❑No ❑N/A ❑NIA 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Nm� OLi Date/Time: Field Data Required? ❑Yes ❑No Lot ID of split containers: Date: ( Z `-+ � f Date: 17,121 10 Page 25 of 27 Document Name: Document Revised: February 7, 2018 m Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: ac�Analk,trcal { F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Prole Iwo# ; 92409786 l2N: NMO Due Date: 12/19/18 CLIENT: 92-Joyce Eng E m z i? m u •N <o a E V a m z Z m c c i- m`w a E Ln 7 M a m Z I N n c '++ a E o N A. m a rZ.. ¢ai c V a�, m u ? 't &. m v = a O CA N d E v7 C d m v O mw = . a E N Z �'V a m O Z 06 G1 m u q Z uZ •�, J E LA M N a a co V N � ^ _a O O t+ J E Ln U 7 a m � ° n mv sue+ a 3 3 Z d m ava aU Ul E q m H L7 a N v CIAIr E Q m _ ei Lo a v 2' cc a J E `N M W a N v n O N=Q 2 E a v V1 H (7 a V 2 O q J E CDE ry v1 M L7 a ? T Z aUO N i m o a M 0 a x O > a Y M kv e Q z n7 i z q - a f= tl1 0 >> c a 3 O % E 7 0 (7 a 2m a° 2 O J E Y a GI 0 o Q z m a a N ° = Y a O >> z Y a l7 xNa Y L ��° Y L7 � m Q z .� N £ N to a ? «a m^ J E Ln 0 H N 6 m O N r_u a J E N M a z > H m a J E o P C7 Q VI E 0 N {� an s v aa 71 E q E 0 a m (7 1 X"I 2 4 ! 3 4 6 \d 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there Is a discrepancy affecting North Caroiina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 26 of 27 n Gy r A z C nz D re ft 3 m ro to O p A N N z A O 3 m m z A A a c •' Q m Hecelveu ..7 Ice (YIN) Custody Sealed Cooler (YIN) Samples intact A O a H 0 n r n 0 m z N 51121m c i m n n V v i a P A 0 z to D 3 m m n 0 z 0 0 0 z N 3 to I- I- 11 I- 6 IA Iw IN I- 1 ITEMN m a iv W y b O V/ n � e n m c m m > n ro u, m (➢ � 3 � � a N 0 a O Q � � ➢ m O N L c W p- Z 1 p m' 6aC ns n o N n 11 A MD m . 7. C? 4 ai a �on�oNp��a3 to G n v p N n n v O C n N n 40 O i O D O a m O 0 v 0 l.1ATR1X CODE Ilea valitl codes to left) z W p C n n. C o Z SAMPLE TYPE (G=GRAB C=COmp) 6 o l N IJ i n m z Lrmn O SAMPLE TEMP AT COLLECTION # OF CCNTA.INERS Unpreserved H2SO4 HNO3 HCl m nr NaOH Na2S203 �o N Methanol Other Analyses Test Y/N NC Appendix I Metals NC Appendx I VOC 8260'a 1,4-Dloxene e� la w -� 0 � 3 C)D 7 o C O vv�>nn cn N r °a 0 m n m o r; 0 m❑ > o C) o `'? 0 N �? G m � C r m Z 7 N E a1 o ari — m �C CDz G) f° rr > C� w x7 5' QF m n N O C (^A n N (Q to H N N C ❑ a p 3 Q 0 0+ (U C n3 r -6 (p m (U a 4 '< of `z n C z z N m m [D o m C o n n r a " O N O y D b 7 � n 0 Page 27 of 27 ! E ' A LaBe[la Company Project Name: f5v,"L Co DATE: I 'Z/9/20 I?' GROUND WATER SAMPLING LOG ta4 Ear Le - Project No. /Task No.: 0 1 ?1 S71 / phasc- OZ Well ID: ` l _ Sampler(s): , Mesu %-s Siebcdn%k Well Location: ' ;cLakon Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 -q-� q inches 51, feet • 5 s feet a l� feet [DTB-DTW] _ — gallons 7s S _gallons _ -zZ' 5 gallons Actual Amount Purged/Bailed: 2 2.5� 'allons Purged with: Bailer Pump Other: Sampled with: C Bailers Pump Other: _ Depth to Water before Sampling: feet Gallons Time Temp(° C) pH Cond. (0/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials b7sz 15.1 (C'. SS 1(A C) 2.so IS: � SS 7 s' CjSo$ 1 Co, d S, �3� 103, Z. 2.75 5 Z (/'Z• •J ��� 4S•' ��J / I L Si C) 1, 7 PJ,-k Date of sample: Before Sampling �� I s , S. 719 (o , 2 S O 17, 3 S. Comments (weather conditions, odor, color, silt, etc.): VA 1-2 )0/1 W,11 0_ re P 10-ce CO 04 lAo j .J, Signature: Z�/Date: !` ,5/ 201g QA/QC Sign Off: Date: 2 ¢l. &JL.J 1 �iG 0 A LaBella Company DATE: 1 Z13/ 20 i g GROUND WATER SAMPLING LOG Project Name: LY Vr Project No. /Task No.: 21-019171 hake C� Well ID: (' 4W _ 2 Sampler(s): . M2SvbeJ S, SlebnJn,' k Well Location: / I d-11 �cash ack a �o�lnW C/ea,�,, ct ��, ! kees Well Diameter: inches Initial Depth to Water (DTW): feet Depth to Bottom (DTB): feet Water Column Thickness (WCT): g• g 7 feet [DTB-DTWJ Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = Gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 17• gallons Actual Amount Purged/Bailed: / Z gallons Purged with: Bailer Pump Other: Sampled with: Bailer) Pump Other: Depth to Water before Sampling: `�— feet Gallons Time Temp(° C) pH I Cond. (µs/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials n D9s� is, s 3,9 s <g. q y. (" 4, 51-D IC�r I5, 3 5,s/1 S'S 1 loz q is- y � , lC �/ 7 lg2 y 7S +]'s I % y I01_/2 /S: s . Z 1�7, 2,70 1 7, 3 Z, -2(c, SS Date of sample: IZ/311g, Before Sampling I pLf Zfs, j 70 I87.:o 7Z� f 7,7;S. ZCo 5 Comments (weather conditions, odor, color, silt, etc.): '-s .., on w Signature: Date: /Z _5/2a1g QA/QC Sign Off: Date: 2 DATE: Z/3/Zol S A LaBella Company GROUND WATER SAMPLING LOG Project Name: Co s� &,,'L Project No. /Task No.: hQ� Well ID: N — l Sampler(s): . Me5v6x-� S, Sfe.h�1�; ��-- Well Location: L c P1 a-) �v /3, ja go /��. r h � � v� h cuacr4s across Well Diameter: 2 inches Initial Depth to Water (DTW): ' T, S feet Depth to Bottom (DTB): 7 S feet Water Column Thickness (WCT): feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with d. s gallons gallons s gallons gallons Depth to Water before Sampling: ,, '/F feet Gallons Time Temp(' C) pH Cond. (0/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials O /1 z i 12.5 �. � � 11, s� 33,1 7y. 3 r�-K c��' Qa ul to ns Date of sample: [Z/3/ 1$' Before Sampling ( j 12• 5,�53 ? N, S 2, 59 Comments (weather conditions, odor, color, silt, etc.): W-G5 66"-77U `LSD I2 /L . Signature: Date: QA/QC Sign Off: Date: / DATE: A LaBella Company GROUND WATER SAMPLING LOG Project Name: �U'�� �' � v� Project No. /Task No.: G I g) S /pkase' O Z Well ID: t— �/� Sampler(s): , M v{Z5, Jizb eJv7t- I� Well Location: G e_A -1+\roUq k woods Well Diameter: — -- Y inches Initial Depth to Water (DTW): fib. _3q feet Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 9Z , —'Z) feet ZZ, 1 feet [DTB-DTW] = gallons gallons = Li � • L gallons Actual Amount Purged/Bailed: '1 j gallons Purged with: Bail _Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp(' C) pH Cond. (NS/cm) DO (mgAL) ORP (mV) Turb.(ntu) Initials p iZoo !(. 5.77 2 V •(a Ll .S, (oq Z G s, (o 2 , 5D Z, �s 9. Z o N1 -2 1Zz3 16,7 6,91 Z5-9,`� 3,LA SS,(o J(0,0 p�M I Zj5 1(o, o 2. o� Z qY , (� Z.6- Date of sample: J 2�/ Ig Before Sampling )Z3 I(0.Q �,03 Z�fy.$ JJ 1, 6y -Z . 4] Comments (weather conditions, odor, color, silt, etc.): f i ►^ L i,c,.Pecc .e . r,ta s s��,�y DSO s o7 l zl_?Z/g, 'r.e_ Signature: Date: I Z / S / 20 ► $ QA/QC Sign Off: Date: DATE: 1 Z/ 3 l Zo 19 vJV l `G ENGINEER/NG SURFACE WATER MONITORING LOG Project Name: Burke County- East Burke Project/Task No.: 2-L& .1971. 07L Surface Point ID: SW-1 Sampler(s): R. Me-svbe,� /S. Location: Old sed. pond, up old rd. from MW-3 Field Parameters: Time of Sampling: 1 Z2<2 pH: Temperature: 2 (°C) Conductivity: 1 zit, 0 —(AS/cm) Turbidity: 13- (NTU) Comments/Sample , Description (weather conditions, odor, color, silt, etc.): Sketch of Sample Location (include flow WOc Signature: QA/QC Sign Off: drainage pathways, etc.): V �&� $C D , PdN.p OL p J'VJ'6 j' Date: _ 12/ 3/2oiS Date: 'sLoPxr Revised 6/11/18 DATE: I Z/ 3/ 20 I S &'u I ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- East Burke Project/Task No.: 2J JJg7J • 02 Surface Point ID: SW-2 Sampler(s):_ 9. Mesv be / S. S lebodn+ Location: downstream from MW-3 & AMW-1 Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: 11 q > 0 (IS/CM) y 7- & (NTU) Comments/Sample Description (weather conditions, odor, color, silt, etc.): —�L�e wCCLI e - i"%u5 'S b� �2/3% Sketch of Sample Location (include flow direction, drainage pathways, etc.): gwjo 4 r, Signature: A1114, ' ^ Date: 12/ 3% Zo lR QA/QC Sign Off: Date:_ I ,Z/z Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Surface Water Constituents Table A2-4 Historical Groundwater Field Parameters Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Well No.: MW-1 MW-2 MW-3 AMW-1 TOC Elevation: 1147.00 1096.50 1039.00 1021.00 Well Depth (Ft): 50.55 71.05 32.50 7.30 05/18/15 1108.36 1032.09 1030.10 1016.35 12/07/15 1108.30 1030.95 1028.55 1016.55 05/02/16 1109.15 1037.00 1026.50 1016.69 12/12/16 1108.05 1036.20 1026.85 1016.35 06/26/17 1108.15 1042.85 1026.00 1016.30 12/14/17 1107.54 1031.67 1028.00 1016.45 05/16/18 1108.44 1030.65 1028.14 1016.35 12/03/18 1107.91 1034.32 1028.61 1016.55 Notes: All elevations are in feet above mean sea level. TOC Elevations are estimated from best available data. NM = Groundwater level not measured. Burke County -East Burke Permit 12-02 Joyce Engineering TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL RI MW-1 MW-2 MW-3 AMW-1 Blanks INORGANICS Arsenic 28-Apr-94 NR 1 ND 3.0 ND NI ND 2-May-00 NR 10 ND 15 J ND NI ND 8-Nov-00 NR 10 ND 18.0 ND NI ND 31-May-01 NR 10 ND 14 J ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 13.0 10 ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 24.0 15.0 ND NI ND 18-Nov-03 NR 10 ND 27.0 ND ND ND 4-May-04 NR 10 ND 23.0 ND ND ND 9-Nov-04 NR 10 ND 27.0 ND ND ND 25-May-05 NR 10 ND 22.0 ND ND ND 1-Nov-05 NR 10 ND 31.0 ND ND ND 23-May-06 NR 10 ND 32.8 ND ND ND 1-Nov-06 NR 10 ND 31.5 ND ND ND 29-May-07 NR 10 4.4 J 21.8 ND ND ND NC 2L = 50 µg/L (10/23/07) 27-Nov-07 NR 10 8.2 J 40.1 5.4 J ND ND 27-May-08 2.7 10.0 7.8 J 16.8 ND ND ND 4-Nov-08 2.7 10.0 8.4 B 18.5 B 4.2 B ND 4.8 J 1-Jun-09 2.7 10.0 33.5 Dry 5.1 J ND ND 19-Nov-09 2.7 10.0 19.1 16.3 ND ND ND NC 2L = 10 µg/L (01/01/10) 14-Jun-10 2.7 10.0 3.0 J 26.5 3.5 J ND ND 29-Nov-10 2.7 10.0 4.0 J 30.7 3.8 J ND ND 31-May-11 2.7 10.0 3.1 J 34.4 5.5 J ND ND 19-Dec-11 5.0 10.0 6.5 J 30.7 ND ND ND 30-May-12 5.0 10.0 5.3 J 22 ND ND ND 3-Dec-12 5.0 10.0 8.2 J 35.8 9.8 J ND ND 10-Jun-13 5.0 10.0 ND 14.0 ND ND ND 28-Oct-13 5.0 10.0 ND 34.0 ND ND ND 5-May-14 5.0 10.0 ND 32.7 ND ND ND 20-Oct-14 5.0 10.0 ND 39.7 ND ND ND 18-May-15 2.5 10.0 ND 30.4 3.5 J 3.2 J ND 7-Dec-15 2.5 10.0 9.9 J 28.4 4.3 J ND ND 2-May-16 2.5 10.0 ND 24.1 6.5 J ND ND 12-Dec-16 2.5 10.0 ND 26.3 5.4 J 3.8 J ND 26-Jun-17 5.0 10.0 6.1 J 35.4 8.8 J 5.1 J ND 14-Dec-17 5.0 10.0 7.1 J 25.5 ND ND ND 14-May-18 5.0 10.0 10.8 24.4 8.9 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 1 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents AnalYte Sample Collection Date I OL PL MW-1 MW-2 MW-3 AMW-1 Blanks Barium 28-Apr-94 NR 100 ND ND ND NI ND 2-May-00 NR 500 ND ND ND NI ND 8-Nov-00 NR 500 ND ND ND NI ND 31-May-01 NR 500 ND ND ND NI ND 6-Nov-01 NR 500 ND ND ND NI ND 21-May-02 NR 500 ND ND ND NI ND 13-Nov-02 NR 500 ND ND ND NI ND 13-May-03 NR 500 ND ND ND NI ND 18-Nov-03 NR 500 ND ND ND ND ND 4-May-04 NR 500 ND ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND ND 25-May-05 NR 500 ND ND ND ND ND 1-Nov-05 NR 500 ND ND ND ND ND 23-May-06 NR 500 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 74.6 J 70.6 J 109 60.4 J ND NC 2L = 2,000 µg/L (10/23/07) 27-Nov-07 NR 100 71.5 J 63.9 J 110 45.5 J 0.30 J 27-May-08 0.2 100 65.6 J 64.0 J 92.4 J 35.6 J 0.41 J 4-Nov-08 0.20 100 57.3 J 60.9 J 93.0 J 34.1 B 10.5 J 1-Jun-09 0.20 100 62.0 B Dry 81.8 J 32.3 B 15.2 J 19-Nov-09 0.20 100 57.7 B 149 90.5 B 30.1 B 19.8 J NC 2L = 700 µg/L (01/01/10) 14-Jun-10 0.20 100 66.3 J 85.9 J 101 60.2 J 0.58 J 29-Nov-10 0.20 100 67.2 J 76.7 J 111 46.6 J ND 31-May-11 0.20 100 67.0 J 66.8 J 96.2 J 41.7 J ND 19-Dec-11 5.0 100 86.3 J 81.3 J 103 39.5 J ND 30-May-12 5.0 100 70.7 J 61.2 J 92.7 J 39.4 J ND 3-Dec-12 5.0 100 65.2 J 54.2 J 111 27.7 J ND 10-Jun-13 5.0 100 69.8 J 125 93.9 J 25.6 B 13.7 J 28-Oct-13 5.0 100 66.4 J 101 71.5 J 45.5 J ND 5-May-14 5.0 100 65.3 J 68.9 J 110 42.2 J ND 20-Oct-14 5.0 100 62.1 J 56.5 J 116 47.6 J ND 18-May-15 2.5 100 65.0 J 49.7 J 98.6 J 43.4 J ND 7-Dec-15 2.5 100 74.5 J 63 J 114.0 38.7 J ND 2-May-16 2.5 100 62.8 J 80.4 J 111.0 45 J ND 12-Dec-16 2.5 100 65.3 J 48.4 J 119.0 47.8 J ND 26-Jun-17 2.5 100 65.5 J 62.5 J 136.0 53.4 J 2.5 J 14-Dec-17 2.5 100 60.2 J 52.0 J 120.0 37.6 J ND 14-May-18 2.5 100 63.3 J 49.2 J 124.0 42.6 J ND Burke County -East Burke Joyce Engineering Permit No. 12-02 2 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Beryllium 19-Oct-99 NR 2 ND ND ND NI ND 2-May-00 NR 2 ND ND ND NI ND 8-Nov-00 NR 2 ND ND ND NI NA 31-May-01 NR 2 ND ND ND NI ND 6-Nov-01 NR 2 ND ND ND NI ND 21-May-02 NR 2 ND ND ND NI ND 13-Nov-02 NR 2 2.3 3.4 3.7 NI ND 13-May-03 NR 2 ND ND ND NI ND 18-Nov-03 NR 2 ND ND ND ND ND 4-May-04 NR 2 ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND 1-Nov-05 NR 2 ND ND ND ND ND 23-May-06 NR 2 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND GWPS = 4 µg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.1 1.0 0.11 J 0.11 J 0.26 J ND ND 4-Nov-08 0.10 1.0 0.12 J 0.29 J 0.24 J ND ND 1-Jun-09 0.10 1.0 ND Dry 0.17 J ND ND 19-Nov-09 0.10 1.0 ND 0.41 J 0.22 J ND ND 14-Jun-10 0.10 1.0 ND 0.18 J 0.15 J ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND 31-May-11 0.10 1.0 0.27 J 0.18 J 0.25 J ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND 10-Jun-13 1.0 1.0 ND ND ND ND ND 28-Oct-13 1.0 1.0 ND ND ND ND ND 5-May-14 1.0 1.0 ND ND ND ND ND 20-Oct-14 1.0 1.0 ND ND ND ND ND 18-May-15 0.5 1.0 ND ND ND ND ND 7-Dec-15 0.5 1.0 ND 0.54 J ND ND ND 2-May-16 0.5 1.0 ND ND ND ND ND 12-Dec-16 0.5 1.0 ND ND ND ND ND 26-Jun-17 0.5 1.0 ND 0.5 J 0.57 J ND ND 14-Dec-17 0.5 1.0 ND ND ND ND ND 14-May-18 0.5 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 3 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Cadmium 28-Apr-94 NR 1 18.0 ND ND NI ND 2-May-00 NR 1 ND 1.0 J ND NI ND 8-Nov-00 NR I ND 2.0 ND NI ND 31-May-01 NR 1 ND 3.0 J 1.0 J NI ND 6-Nov-01 NR 1 ND 1.4 ND NI ND 21-May-02 NR 1 1.1 1.6 1.7 NI ND 13-Nov-02 NR 1 1.4 2.3 2.4 NI ND 13-May-03 NR 1 1.4 1.4 1.2 NI ND 18-Nov-03 NR 1 ND ND 1.7 ND ND 4-May-04 NR 1 ND ND 1.8 ND ND 9-Nov-04 NR 1 ND 2.6 1.6 ND ND 25-May-05 NR 1 ND ND ND ND ND 1-Nov-05 NR 1 ND ND ND ND ND 23-May-06 NR 1 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND NC 2L = 1.75 µg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.5 1.0 ND ND ND ND ND 4-Nov-08 0.50 1.0 ND ND ND ND ND 1-Jun-09 0.50 1.0 ND Dry ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND NC 2L = 2 µg/L (01/01/10) 14-Jun-10 0.50 1.0 ND ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 31-May-11 0.50 1.0 ND 0.55 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND 10-Jun-13 1.0 1.0 ND ND ND ND ND 28-Oct-13 1.0 1.0 ND ND ND ND ND 5-May-14 1.0 1.0 ND ND ND ND ND 20-Oct-14 1.0 1.0 ND ND ND ND ND 18-May-15 0.5 1.0 ND ND ND ND ND 7-Dec-15 0.5 1.0 ND ND ND ND ND 2-May-16 0.5 1.0 ND ND ND ND ND 12-Dec-16 0.5 1.0 ND ND ND ND ND 26-Jun-17 0.5 1.0 ND ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND ND 14-May-18 0.5 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 4 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I OL RI MW-1 MW-2 MW-3 AMW-1 Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 50 µg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.4 10.0 ND 0.66 B ND 1.0 B 0.85 J 4-Nov-08 0.40 10.0 0.68 J 1.4 J ND 1.4 J ND 1-Jun-09 0.40 10.0 ND Dry ND 1.3 J ND 19-Nov-09 0.40 10.0 ND 6.3 J ND ND 1.1 J NC 2L = 10 µg/L (01/01/10) 14-Jun-10 0.40 10.0 0.97 J 1.3 J ND 2.5 J ND 29-Nov-10 0.40 10.0 1.7 J ND ND 1.0 J ND 31-May-11 0.40 10.0 2.3 B 1.4 B 6.2 J 1.8 B 0.73 J 19-Dec-11 5.00 10.0 11.5 5.3 J ND 7.7 J ND 30-May-12 5.00 10.0 ND ND ND 7.9 J ND 3-Dec-12 5.00 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 5.0 10.0 ND ND ND ND ND 20-Oct-14 5.0 10.0 ND ND ND ND ND 18-May-15 2.5 10.0 ND ND ND ND ND 7-Dec-15 2.5 10.0 3.8 J 9.5 J ND ND ND 2-May-16 2.5 10.0 2.5 J ND ND ND ND 12-Dec-16 2.5 10.0 ND ND ND 3 J ND 26-Jun-17 2.5 10.0 ND 3.6 J ND ND ND 14-Dec-17 2.5 10.0 ND ND ND 3.9 J ND 14-May-18 2.5 10.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 5 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I OL PL MW-1 MW-2 MW-3 AMW-1 Blanks Cobalt 28-Apr-94 NR 20 ND ND ND NI ND 2-May-00 NR 10 ND 54.0 ND NI ND 8-Nov-00 NR 10 ND 40.0 26.0 NI ND 31-May-01 NR 10 44.0 27.0 40.0 NI ND 6-Nov-01 NR 10 ND 22.0 41.0 NI ND 21-May-02 NR 10 18.0 19.0 51.0 NI NA 13-Nov-02 NR 10 10.0 19.0 48.0 NI ND 13-May-03 NR 10 67.0 44.0 47.0 NI ND 18-Nov-03 NR 10 29.0 120 45.0 ND ND 4-May-04 NR 10 21.0 110 35.0 ND ND 9-Nov-04 NR 10 22.0 110 36.0 ND ND 25-May-05 NR 10 23.0 120 32.0 ND ND 1-Nov-05 NR 10 17.0 120 34.0 ND ND 23-May-06 NR 10 14.6 116 31.3 ND ND 6-Nov-06 NR 10 14.8 104 32.0 ND ND 29-May-07 NR 10 17.3 79.0 30.1 2.9 J ND GWPS = 70 µg/L (10/23/07) 27-Nov-07 NR 10 11.6 84.4 32.2 3.0 J ND 27-May-08 0.6 10.0 8.9 J 8.1 J 16.5 ND ND 4-Nov-08 0.6 10.0 15.5 B 20.5 26.1 4.5 B 3.5 J 1-Jun-09 0.60 10.0 36.1 Dry 29.8 6.0 B 3.3 J 19-Nov-09 0.60 10.0 19.6 39.8 23.5 1.4 J ND 14-Jun-10 0.60 10.0 20.1 160 31.1 4.0 J ND GWPS = 1 µg/L, (10/1/10) 29-Nov-10 0.60 10.0 10.2 156 37.7 5.4 J ND 31-May-11 0.60 10.0 12.2 111 27.1 ND ND 19-Dec-11 5.0 10.0 14.7 75.7 24.8 ND ND 30-May-12 5.0 10.0 23.5 78.4 26.2 ND ND 3-Dec-12 5.0 10.0 27.5 124 34.9 ND ND 10-Jun-13 5.0 10.0 19.5 58.9 29.8 ND ND 28-Oct-13 5.0 10.0 14.6 178 14.0 6.6 J ND 5-May-14 5.0 10.0 9.7 J 115 24.8 ND ND 20-Oct-14 5.0 10.0 8.6 J 144 25.3 ND ND 18-May-15 2.5 10.0 10.3 95.3 23.5 ND ND 7-Dec-15 2.5 10.0 16.3 88.6 26.1 ND ND 2-May-16 2.5 10.0 10.4 128 25.6 ND ND 12-Dec-16 2.5 10.0 9.3 J 94.0 24.1 ND ND 26-Jun-17 2.5 10.0 13.9 110.0 26.3 ND ND 14-Dec-17 2.5 10.0 15.8 102.0 24.3 ND ND 14-May-18 2.5 10.0 17.9 84.7 21.0 ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 6 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents AnalYte Sample Collection Date I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Copper 28-Apr-94 NR 10 ND ND ND NI ND 2-May-00 NR 200 ND ND ND NI ND 8-Nov-00 NR 200 ND ND ND NI ND 31-May-01 NR 200 ND ND ND NI ND 6-Nov-01 NR 200 ND ND ND NI ND 21-May-02 NR 200 ND ND ND NI ND 13-Nov-02 NR 200 ND ND ND NI ND 13-May-03 NR 200 ND ND ND NI ND 18-Nov-03 NR 200 ND ND ND ND ND 4-May-04 NR 200 ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND 1-Nov-05 NR 200 ND ND ND ND ND 23-May-06 NR 200 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 1,000 µg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.3 10.0 ND 3.0 J ND ND ND 4-Nov-08 0.30 10.0 ND 2.2 B ND ND 0.94 J 1-Jun-09 0.30 10.0 0.36 J Dry ND ND ND 19-Nov-09 0.30 10.0 0.31 J 3.9 J ND ND ND 14-Jun-10 0.30 10.0 0.99 B 6.1 B ND ND 3.4 J 29-Nov-10 0.30 10.0 0.80 J 2.9 J ND ND ND 31-May-11 0.30 10.0 ND 0.63 J ND ND ND 19-Dec-11 5.0 10.0 5.2 J ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND 10.8 28-Oct-13 5.0 10.0 ND 11.0 ND ND ND 5-May-14 5.0 10.0 ND ND ND ND ND 20-Oct-14 5.0 10.0 ND ND ND ND ND 18-May-15 2.5 10.0 ND ND ND ND ND 7-Dec-15 2.5 10.0 ND 8.5 J ND ND ND 2-May-16 2.5 10.0 ND 4.6 J ND ND ND 12-Dec-16 2.5 10.0 ND ND ND ND ND 26-Jun-17 2.5 10.0 ND ND ND ND ND 14-Dec-17 2.5 10.0 2.9 J ND ND ND ND 14-May-18 2.5 10.0 ND 3 J ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 7 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Lead 28-Apr-94 NR 1 21.0 3.0 4.0 NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND 10.0 ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND 2.5 B 6.9 B 3.9 B 6.1 J NC 2L = 15 µg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 4 10.0 ND ND ND ND ND 4-Nov-08 4.0 10.0 ND ND ND ND ND 1-Jun-09 4.0 10.0 ND Dry ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND ND 14-Jun-10 4.0 10.0 ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND 19-Dec-11 5.0 10.0 6.2 J ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 5.0 10.0 ND ND ND ND ND 20-Oct-14 5.0 10.0 ND ND ND ND ND 18-May-15 2.5 10.0 ND ND ND ND ND 7-Dec-15 2.5 10.0 ND 6.6 J ND ND ND 2-May-16 2.5 10.0 ND ND ND ND ND 12-Dec-16 2.5 10.0 ND ND ND ND ND 26-Jun-17 2.5 10.0 ND 3 J ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 8 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Nickel 28-Apr-94 NR 50 ND ND ND NI ND 2-May-00 NR 50 ND ND ND NI ND 8-Nov-00 NR 50 ND ND ND NI ND 31-May-01 NR 50 ND ND ND NI ND 6-Nov-01 NR 50 ND ND ND NI ND 21-May-02 NR 50 60.0 ND ND NI ND 13-Nov-02 NR 50 ND ND ND NI ND 13-May-03 NR 50 ND ND ND NI ND 18-Nov-03 NR 50 ND 110 ND ND ND 4-May-04 NR 50 ND 99 ND ND ND 9-Nov-04 NR 50 ND 110 ND ND ND 25-May-05 NR 50 ND 100 ND ND ND 1-Nov-05 NR 50 ND 110 ND ND ND 23-May-06 NR 50 ND 103 ND ND ND 6-Nov-06 NR 50 ND 92.6 ND ND ND 29-May-07 NR 50 11.5 J 78.3 7.7 J ND ND NC 2L = 100 µg/L (10/23/07) 27-Nov-07 NR 50 7.7 J 66.4 7.2 J ND ND 27-May-08 1.7 50.0 12.1 J 24.3 J 7.4 J ND ND 4-Nov-08 1.7 50.0 16.5 J 19.2 J 9.1 B 2.2 B 2.2 J 1-Jun-09 1.7 50.0 14.9 J Dry 6.1 J ND ND 19-Nov-09 1.7 50.0 13.2 J 39.9 J 7.7 B ND 2.2 J 14-Jun-10 1.7 50.0 8.6 J 157 6.3 J ND ND 29-Nov-10 1.7 50.0 7.3 J 133 7.2 J ND ND 31-May-11 1.7 50.0 9.1 B 116 9.6 B ND 2.3 J 19-Dec-11 5.0 50.0 10.9 J 85.8 6.8 J ND ND 30-May-12 5.0 50.0 9.9 J 57.4 5.8 J ND ND 3-Dec-12 5.0 50.0 8.0 J 63.3 6.7 J ND ND 10-Jun-13 5.0 50.0 8.1 J 40.9 J 6.5 J ND ND 28-Oct-13 5.0 50.0 ND 161 ND ND ND 5-May-14 5.0 50.0 ND 124 6.8 J ND ND 20-Oct-14 5.0 50.0 ND 132 7.5 J ND ND 18-May-15 2.5 50.0 5.1 J 88.2 7.9 J ND ND 7-Dec-15 2.5 50.0 8.8 J 75.2 8.9 J ND ND 2-May-16 2.5 50.0 5.6 J 122 8.4 J ND ND 12-Dec-16 2.5 50.0 4.3 J 92.5 8.5 J ND ND 26-Jun-17 2.5 50.0 6.0 J 98.8 8.2 J ND ND 14-Dec-17 2.5 50.0 8.1 J 84.0 9.4 J ND ND 14-May-18 2.5 50.0 7.2 J 64.3 6.2 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 9 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I OL RI MW-1 MW-2 MW-3 AMW-1 Blanks Selenium 19-Oct-99 NR 20 ND ND ND NI NA 2-May-00 NR 20 ND ND ND NI ND 8-Nov-00 NR 20 ND ND ND NI NA 31-May-01 NR 20 ND ND ND NI ND 6-Nov-01 NR 20 ND ND ND NI ND 21-May-02 NR 20 ND ND ND NI ND 13-Nov-02 NR 20 ND ND ND NI ND 1-Apr-03 NR 20 NA NA NA ND NA 13-May-03 NR 20 ND ND ND NA ND 18-Nov-03 NR 20 ND ND ND ND ND 4-May-04 NR 20 ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND 1-Nov-05 NR 20 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 50 µg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND 2.4 J 27-May-08 3.8 10.0 ND ND ND ND ND 4-Nov-08 3.8 10.0 ND 7.2 B 5.7 B ND 4.2 J 1-Jun-09 3.8 10.0 ND Dry 5.0 J ND ND 19-Nov-09 3.8 10.0 ND ND ND ND ND NC 2L = 20 µg/L (01/01/10) 14-Jun-10 3.8 10.0 ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND 10-Jun-13 10.0 10.0 ND ND ND ND ND 28-00-13 10.0 10.0 ND ND ND ND ND 5-May-14 10.0 10.0 ND ND ND ND ND 20-Oct-14 10.0 10.0 ND ND ND ND ND 18-May-15 5.0 10.0 ND ND ND ND ND 7-Dec-15 5.0 10.0 ND ND ND ND ND 2-May-16 5.0 10.0 ND ND ND ND ND 12-Dec-16 5.0 10.0 ND ND ND ND ND 26-Jun-17 5.0 10.0 ND ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 10 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analvtc Sample Collection Date I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Silver 19-Oct-99 NR 10 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI NA 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI 15.0 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND NC 2L = 17.5 µg/L (10/23/07) 27-Nov-07 NR 10 ND ND ND ND ND 27-May-08 0.1 10.0 ND ND 0.30 B ND 0.14 J 4-Nov-08 0.10 10.0 0.19 B 0.31 B 0.76 B 0.18 B 0.20 J 1-Jun-09 0.10 10.0 0.18 J Dry 0.45 J ND ND 19-Nov-09 0.10 10.0 0.22 J 0.34 J 0.42 J 0.16 J ND NC 2L = 20 µg/L (01/01/10) 14-Jun-10 0.10 10.0 ND ND ND ND ND 29-Nov-10 0.10 10.0 ND ND ND ND ND 31-May-11 0.10 10.0 0.18 J 0.14 J ND 0.31 J ND 19-Dec-11 5.0 10.0 ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND 10-Jun-13 5.0 10.0 ND ND ND ND ND 28-Oct-13 5.0 10.0 ND ND ND ND ND 5-May-14 5.0 10.0 ND ND ND ND ND 20-Oct-14 5.0 10.0 ND ND ND ND ND 18-May-15 2.5 10.0 ND ND ND ND ND 7-Dec-15 2.5 10.0 ND ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND ND 12-Dec-16 2.5 10.0 ND ND ND ND ND 26-Jun-17 2.5 10.0 ND ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 11 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Thallium 28-Apr-94 NR 1 ND ND ND NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND 12.0 ND ND 1-Nov-05 NR 10 ND 12.0 14.0 ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 5.5 0.167 J 0.525 J 0.625 J 0.053 J ND GWPS = 0.28 µg/L (10/23/07) 27-Nov-07 NR 5.5 0.422 J 0.475 J 0.593 J 0.073 J ND 27-May-08 3 5.5 ND ND ND ND ND 4-Nov-08 3.0 5.5 ND ND ND ND ND 1-Jun-09 3.0 5.5 ND Dry ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 14-Jun-10 3.0 5.5 3.8 J 5.3 J 4.1 J ND ND GWPS = 0.28 µg/L (10/1/10) 29-Nov-10 3.0 5.5 ND ND ND ND ND 31-May-11 3.0 5.5 ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND 3-Dec-12 5.4 5.5 7.6 ND ND ND ND 10-Jun-13 5.4 5.5 ND ND ND ND ND 28-Oct-13 5.4 5.5 ND ND ND ND ND 5-May-14 5.4 5.5 ND ND ND ND ND 20-Oct-14 5.4 5.5 ND ND ND ND ND 18-May-15 5.0 5.5 ND ND ND ND ND 7-Dec-15 5.0 5.5 ND ND ND ND ND 2-May-16 5.0 5.5 ND ND ND ND ND 12-Dec-16 5.0 5.5 ND ND ND ND 5.5 J 26-Jun-17 5.0 5.5 0.083 J 0.57 J 1.4 J 0.034 J ND 14-Dec-17 0.03 0.10 0.10 0.54 1.4 0.040 J 14-May-18 0.50 5.5 ND ND 1.2 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 12 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Vanadium 28-Apr-94 NR 80 ND ND ND NI ND 2-May-00 NR 40 ND ND ND NI ND 8-Nov-00 NR 40 ND ND ND NI ND 31-May-01 NR 40 ND ND ND NI ND 6-Nov-01 NR 40 ND ND ND NI ND 21-May-02 NR 40 ND ND ND NI ND 13-Nov-02 NR 40 ND ND ND NI ND 13-May-03 NR 40 ND ND ND NI ND 18-Nov-03 NR 40 ND ND ND ND ND 4-May-04 NR 40 ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND 1-Nov-05 NR 40 ND ND ND ND ND 23-May-06 NR 40 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND GWPS = 3.5 µg/L (10/23/07) 27-Nov-07 NR 25 ND ND ND ND ND 27-May-08 0.2 25.0 0.90 B 4.5 J 1.0 B 0.93 B 0.22 J 4-Nov-08 0.20 25.0 1.4 B 4.5 J 0.62 B 1.4 B 0.85 J 1-Jun-09 0.20 25.0 0.99 B Dry 0.93 B 2.1 B 1.2 J 19-Nov-09 0.20 25.0 0.81 B 9.1 J 0.96 B 1.4 B 0.58 J 14-Jun-10 0.20 25.0 0.85 B 1.7 J 1.0 B 1.8 J 0.25 J GWPS = 0.3 µg/L (10/1/10) 29-Nov-10 0.20 25.0 1.0 J ND ND ND ND 31-May-11 0.20 25.0 ND ND ND 1.4 J ND 19-Dec-11 5.0 25.0 12.1 J 6.9 J ND 6.7 J ND 30-May-12 5.0 25.0 ND ND ND 6.8 J ND 3-Dec-12 5.0 25.0 ND ND ND 6.9 J ND 10-Jun-13 5.0 25.0 ND ND ND ND ND 28-Oct-13 5.0 25.0 ND ND ND ND ND 5-May-14 5.0 25.0 ND ND ND ND ND 20-Oct-14 5.0 25.0 ND ND ND ND ND 18-May-15 2.5 25.0 ND 7.8 J 3.6 J ND ND 7-Dec-15 2.5 25.0 4.4 J 18.8 J 5.7 J 3.4 J ND 2-May-16 2.5 25.0 ND ND ND 3.2 J ND 12-Dec-16 2.5 25.0 ND ND ND 2.7 J ND 26-Jun-17 2.5 25.0 ND 4.3 J ND ND ND 14-Dec-17 2.5 25.0 ND ND ND ND ND 14-May-18 2.5 25.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 13 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Zinc 28-Apr-94 NR 10 ND ND ND NI ND 2-May-00 NR 50 ND ND ND NI ND 8-Nov-00 NR 50 ND ND ND NI ND 31-May-01 NR 50 ND ND ND NI ND 6-Nov-01 NR 50 ND ND ND NI ND 21-May-02 NR 50 ND ND ND NI ND 13-Nov-02 NR 50 ND ND ND NI ND 13-May-03 NR 50 ND ND ND NI ND 18-Nov-03 NR 50 ND ND ND ND ND 4-May-04 NR 50 ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND 1-Nov-05 NR 50 ND ND ND ND ND 23-May-06 NR 50 ND ND ND 76.9 ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 10 4.7 B 11.3 4.6 B 2.9 B 2.0 J NC 2L = 1,050 µg/L (10/23/07) 27-Nov-07 NR 10 9.1 J 9.5 J 7.3 J 1.6 J ND 27-May-08 0.4 10.0 2.6 J 8.6 B 6.4 B ND 4.8 J 4-Nov-08 0.40 10.0 3.3 B 5.4 B 0.77 B ND 8.9 J 1-Jun-09 0.40 10.0 8.7 B Dry 6.5 B 7.0 B 83.0 19-Nov-09 0.40 10.0 6.0 B 14.0 B 5.0 B 4.2 B 3.5 J NC 2L = 1,000 µg/L (01/O1/10) 14-Jun-10 0.40 10.0 2.1 BB 17.4 B 20.1 B ND 10.1 29-Nov-10 0.40 10.0 1.9 J 13.0 1.8 J ND ND 31-May-11 0.40 10.0 6.5 B 20.5 B 6.8 B 4.3 B 13.7 19-Dec-11 10.0 10.0 21.3 17.0 ND 10.3 ND 30-May-12 10.0 10.0 ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND 10-Jun-13 10.0 10.0 ND ND ND ND 76.3 28-Oct-13 10.0 10.0 ND 21.4 ND ND ND 5-May-14 10.0 10.0 ND 18.7 ND ND ND 20-Oct-14 10.0 10.0 ND 13.4 ND ND ND 18-May-15 5.0 10.0 ND 21.7 ND ND ND 7-Dec-15 5.0 10.0 7.8 B 16.7 B 6.3 B ND 7.2 J 2-May-16 5.0 10.0 5.4 J 17 5.3 J ND ND 12-Dec-16 5.0 10.0 ND 9.7 J 6.0 J 9.0 J ND 26-Jun-17 5.0 10.0 ND 11.1 5.1 J 6.4 J ND 14-Dec-17 5.0 10.0 5.6 J 10.8 6.6 J 9.9 J ND 14-May-18 5.0 10.0 13 15.4 5.6 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 14 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Organic Compounds Acetone 28-Apr-94 NR 100 ND ND ND NI ND 2-May-00 NR 100 ND ND ND NI ND 8-Nov-00 NR 100 ND ND ND NI ND 31-May-01 NR 100 ND ND ND NI ND 6-Nov-01 NR 100 ND ND ND NI ND 21-May-02 NR 100 ND ND ND NI ND 13-Nov-02 NR 100 ND ND ND NI ND 13-May-03 NR 100 210 ND ND NI ND 18-Nov-03 NR 100 ND ND ND ND ND 4-May-04 NR 100 ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND 25-May-05 NR 100 150 ND ND ND ND 1-Nov-05 NR 100 ND ND ND ND ND 23-May-06 NR 100 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND NC 2L = 700 µg/L (10/23/07) 27-Nov-07 NR 100 7.6 B 5.9 B 4.0 B 4.1 B 4.3 J 27-May-08 20 100 ND ND ND ND ND 4-Nov-08 20.0 100 ND ND ND ND ND 1-Jun-09 2.2 100 65.9 J Dry ND ND 3.2 J 19-Nov-09 2.2 100 ND 2.8 B 3.8 B 21.9 B 3.8 J NC 2L = 6,000 µg/L (01/01/10) 14-Jun-10 2.2 100 6.3 B 4.0 B ND ND 8.9 J 29-Nov-10 2.2 100 ND ND ND ND 2.3 J 31-May-11 2.2 100 3.0 B 4.0 B 4.0 B ND 3.9 J 19-Dec-11 2.2 100 ND ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND ND 3-Dec-12 10.0 100 ND ND ND ND ND 10-Jun-13 10.0 100 ND ND ND ND ND 28-Oct-13 10.0 100 ND 11.4 J ND ND ND 5-May-14 10.0 100 ND ND ND ND ND 20-Oct-14 10.0 100 ND ND ND ND ND 18-May-15 10.0 100 ND ND ND ND ND 7-Dec-15 10.0 100 ND ND ND ND ND 2-May-16 10.0 100 ND ND ND ND ND 12-Dec-16 10.0 100 ND ND ND ND ND 26-Jun-17 10.0 100 11.6 J 21.1 J 11 J 17.8 J 23 J 14-Dec-17 10.0 100 ND ND N ND ND ND 14-May-18 10.0 100 ND 10.5 J ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 15 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents AnalYte Sample Collection Date I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Benzene 28-Apr-94 NR 5 ND 6.1 ND NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1.0 1.0 2.0 0.9 J ND ND NC 2L = 1 µg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.25 1.0 0.83 J 2.0 0.74 J ND ND 4-Nov-08 0.25 1.0 0.38 J 2.5 0.88 J ND ND 1-Jun-09 0.25 1.0 0.92 J Dry 0.74 J ND ND 19-Nov-09 0.25 1.0 ND ND ND 1.1 ND 14-Jun-10 0.25 1.0 0.62 J 2.3 0.81 J ND ND 29-Nov-10 0.25 1.0 ND 2.4 ND ND ND 31-May-11 0.25 1.0 0.62 J 2.1 0.75 J ND ND 19-Dec-11 0.25 1.0 0.68 J 1.7 0.75 J ND ND 30-May-12 0.25 1.0 0.81 J 1.6 0.68 J ND ND 3-Dec-12 0.25 1.0 0.87 J 1.3 0.67 J ND ND 10-Jun-13 0.25 1.0 0.79 J 2.0 0.75 J ND ND 28-Oct-13 0.25 1.0 ND 1.1 0.70 J ND ND 5-May-14 0.25 1.0 0.38 J 1.6 0.78 J ND ND 20-Oct-14 0.25 1.0 0.36 J 1.3 0.62 J ND ND 18-May-15 0.25 1.0 ND 0.8 J 0.50 J ND ND 7-Dec-15 0.25 1.0 ND 0.8 J ND ND ND 2-May-16 0.25 1.0 0.33 J 0.9 J 0.65 J ND ND 12-Dec-16 0.25 1.0 0.3 J 1.2 0.62 J ND ND 26-Jun-17 0.25 1.0 0.34 J 0.9 J 0.65 J ND ND 14-Dec-17 0.25 1.0 0.44 J 0.65 J 0.56 J ND ND 14-May-18 0.25 1.0 0.28 J 0.90 J 0.49 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 16 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Sample Collection Date DL RL MW-1 MW-2 MW-3 AMW-1 Blanks 2-Butanone (MEK) 19-Nov-09 0.96 100 ND ND ND 2.8 J ND NC 2L = 4,000 µg/L (01/01/10) 14-Jun-10 0.96 100 ND ND ND ND 1.6 J 29-Nov-10 0.96 100 ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND 19-Dec-11 0.96 100 ND ND ND ND ND 30-May-12 0.96 100 ND ND ND ND ND 3-Dec-12 0.96 100 ND ND ND ND ND IO-Jun-13 0.96 100 ND ND ND ND ND 28-Oct-13 0.96 100 ND ND ND ND ND 5-May-14 0.96 100 ND ND ND ND ND 20-Oct-14 0.96 100 ND ND ND ND ND 18-May-15 0.96 100 ND ND ND ND ND 7-Dec-15 0.96 100 ND ND ND ND ND 2-May-16 0.96 100 ND ND ND ND ND 12-Dec-16 0.96 100 ND ND ND ND ND 26-Jun-17 0.96 100 ND ND ND ND ND 14-Dec-17 0.96 100 ND ND ND ND ND 14-May-18 0.96 100 ND ND ND ND ND Carbon Disulfide 12-May-99 NR 5 5.8 ND ND NI ND 19-Oct-99 NR 100 ND ND ND NI ND 2-May-00 NR 100 ND ND ND NI ND 8-Nov-00 NR 100 ND ND ND NI ND 31-May-01 NR 100 ND ND ND NI ND 6-Nov-01 NR 100 ND ND ND NI ND 21-May-02 NR 100 ND ND ND NI ND 13-Nov-02 NR 100 ND ND ND NI ND 13-May-03 NR 100 ND ND ND NI ND 18-Nov-03 NR 100 ND ND ND ND ND 4-May-04 NR 100 ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND 1-Nov-05 NR 100 ND ND ND ND ND 23-May-06 NR 100 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND NC 2L = 700 µg/L (10/23/07) 27-Nov-07 NR 100 ND ND ND ND ND 27-May-08 1.2 100 ND ND ND ND ND 4-Nov-08 1.2 100 ND ND ND ND ND 1-Jun-09 1.2 100 ND Dry ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND 14-Jun-10 1.2 100 ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND IO-Jun-13 1.2 100 ND ND ND ND ND 28-Oct-13 1.2 100 ND ND ND ND ND 5-May-14 1.2 100 ND ND ND ND ND 20-Oct-14 1.2 100 ND ND ND ND ND 18-May-15 1.2 100 ND ND ND ND ND 7-Dec-15 1.2 100 ND ND ND ND ND 2-May-16 1.2 100 ND ND ND ND ND 12-Dec-16 1.2 100 ND ND ND ND ND 26-Jun-17 1.2 100 ND ND ND ND ND 14-Dec-17 1.2 100 ND ND ND ND ND 14-May-18 1.2 100 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 17 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Chlorobenzene 29-May-07 NR 3 ND 0.73 J 0.76 J 0.24 J ND NC 2L = 50 µg/L (10/23/07) 27-Nov-07 NR 3 ND ND ND ND ND 27-May-08 0.23 3.0 ND 0.57 J 0.58 J ND ND 4-Nov-08 0.23 3.0 ND 0.41 J 0.56 J ND ND 1-Jun-09 0.23 3.0 ND Dry 0.55 J ND ND 19-Nov-09 0.23 3.0 ND ND ND 0.23 J ND 14-Jun-10 0.23 3.0 ND 0.70 J 0.58 J ND ND 29-Nov-10 0.23 3.0 ND 0.84 J ND ND ND 31-May-11 0.23 3.0 ND 0.65 J 0.63 J ND ND 19-Dec-11 0.23 3.0 ND 0.59 J 0.65 J ND ND 30-May-12 0.23 3.0 ND 0.42 J 0.68 J ND ND 3-Dec-12 0.23 3.0 ND 0.32 J 0.60 J ND ND 10-Jun-13 0.23 3.0 ND 0.43 J 0.60 J ND ND 28-Oct-13 0.23 3.0 ND 0.50 J 0.64 J ND ND 5-May-14 0.23 3.0 ND 0.73 J 0.72 J ND ND 20-Oct-14 0.23 3.0 ND 0.67 J 0.70 J ND ND 18-May-15 0.23 3.0 ND ND 0.77 J ND ND 7-Dec-15 0.23 3.0 ND 0.42 J 0.58 J ND ND 2-May-16 0.23 3.0 ND 0.54 J 0.84 J ND ND 12-Dec-16 0.23 3.0 ND 0.46 J 0.67 J ND ND 26-Jun-17 0.23 3.0 ND ND ND ND ND 14-Dec-17 0.23 3.0 ND 0.37 J 0.73 J ND ND 14-May-18 0.23 3.0 ND 0.26 J 0.72 J ND ND Chloromethane 1-Jun-09 0.11 1.0 ND Dry 0.21 J ND ND NC 2L = 2.6 µg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND NC 2L = 3 µg/L (01/01/10) 14-Jun-10 0.11 1.0 ND ND ND ND 0.12 J 29-Nov-10 0.11 1.0 ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND 10-Jun-13 0.11 1.0 ND ND ND ND ND 28-00-13 0.11 1.0 ND ND ND ND ND 5-May-14 0.11 1.0 ND ND ND ND ND 20-Oct-14 0.11 1.0 ND ND ND ND ND 18-May-15 0.11 1.0 ND ND ND ND ND 7-Dec-15 0.11 1.0 ND ND ND ND ND 2-May-16 0.11 1.0 ND ND ND ND ND 12-Dec-16 0.11 1.0 ND ND ND ND 0.36 J 26-Jun-17 0.11 1.0 ND ND ND ND ND 14-Dec-17 0.11 1.0 ND ND ND ND ND 14-May-18 0.11 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 18 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date j1hon RL MW-1 MW-2 MW-3 AMW-1 Blanks 1,2-Dichlorobenzene 28-Oct-13 5.00 30.0 ND ND ND 0.86 J ND NC 2L = 20 µg/L (01/01/10) 5-May-14 0.30 5.0 ND ND ND ND ND 20-Oct-14 0.30 5.0 ND ND ND ND ND 18-May-15 0.30 5.0 ND ND ND ND ND NC 2L = 20 µg/L (01/01/10) 7-Dec-15 0.30 5.0 ND ND ND ND ND 2-May-16 0.30 5.0 ND ND ND ND ND 12-Dec-16 0.30 5.0 ND ND ND ND ND 26-Jun-17 0.30 5.0 ND ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND ND 14-May-18 0.30 5.0 ND ND ND ND ND 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 7.1 ND NI ND 2-May-00 NR 5 ND 10.0 5.2 NI ND 8-Nov-00 NR 5 ND 9.9 5.9 NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND 8.2 6.4 NI ND 13-Nov-02 NR 5 ND 7.6 ND NI ND 13-May-03 NR 5 5.0 5.5 ND NI ND 18-Nov-03 NR 5 ND 5.4 5.4 ND ND 4-May-04 NR 5 ND 7.4 5.0 ND ND 9-Nov-04 NR 5 ND 7.4 5.1 ND ND 25-May-05 NR 5 ND 6.0 5.0 ND ND 1-Nov-05 NR 5 ND 8.0 5.0 ND ND 23-May-06 NR 5 ND 5.8 ND ND ND 6-Nov-06 NR 3 ND 6.7 5.5 ND ND 29-May-07 NR 1 3.6 8.1 6.5 2.2 ND NC 2L = 1.4 µg/L (10/23/07) 27-Nov-07 NR 1 2.7 7.2 5.5 ND ND 27-May-08 0.33 1.0 2.5 8.2 4.7 1.0 ND 4-Nov-08 0.33 1.0 1.2 6.3 4.8 0.94 J ND 1-Jun-09 0.33 1.0 3.4 Dry 4.6 1.2 ND 19-Nov-09 0.33 1.0 ND ND ND 3.7 ND NC 2L = 6 µg/L (01/01/10) 14-Jun-10 0.33 1.0 1.7 2.4 4.6 1.2 ND 29-Nov-10 0.33 1.0 0.97 J 4.2 5.3 1.4 ND 31-May-11 0.33 1.0 1.4 5.6 4.8 0.96 J ND 19-Dec-11 0.33 1.0 1.4 6.3 4.7 0.62 J ND 30-May-12 0.33 1.0 1.9 5.0 4.3 0.73 J ND 3-Dec-12 0.33 1.0 1.7 3.4 4.3 0.63 J ND 10-Jun-13 0.33 1.0 1.5 4.1 4.1 0.77 J ND 28-Oct-13 0.30 1.0 1.1 1.6 4.5 0.88 J ND 5-May-14 0.33 1.0 0.89 J 4.7 4.7 0.78 J ND 20-Oct-14 0.33 1.0 0.92 J 5.3 4.6 0.91 J ND 18-May-15 0.33 1.0 1.2 5.1 4.6 0.68 J ND 7-Dec-15 0.33 1.0 1.2 4.8 4.1 0.50 J ND 2-May-16 0.33 1.0 1.1 2.7 4.4 0.65 J ND 12-Dec-16 0.33 1.0 0.60 J 3.6 4.3 0.60 J ND 26-Jun-17 0.33 1.0 ND 3.5 4.3 ND ND 14-Dec-17 0.33 1.0 1.10 4.7 4.4 0.80 J ND 14-May-18 0.33 1.0 1.20 2.9 3.6 0.63 J ND Burke County -East Burke Joyce Engineering Permit No. 12-02 19 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 ND 6.1 16.0 NI ND 2-May-00 NR 5 ND ND 8.8 J NI ND 8-Nov-00 NR 5 ND ND 11.0 NI ND 31-May-01 NR 5 ND ND 8.4 NI ND 6-Nov-01 NR 5 ND ND 7.4 NI ND 21-May-02 NR 5 ND ND 11.0 NI ND 13-Nov-02 NR 5 ND ND 8.1 NI ND 13-May-03 NR 5 ND ND 6.0 NI ND 18-Nov-03 NR 5 ND ND 6.0 ND ND 4-May-04 NR 5 ND ND 5.2 ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND 5.0 ND ND 1-Nov-05 NR 5 ND ND 5.0 ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 5 1.9 J 2.3 J 5.1 4.0 J ND NC 2L = 70 µg/L (10/23/07) 27-Nov-07 NR 5.0 ND 0.58 J 2.7 J 1.2 J ND 27-May-08 0.32 5.0 0.36 J 0.71 J 2.8 J 1.1 J ND 4-Nov-08 0.32 5.0 0.34 J 0.79 J 3.4 J 0.88 J ND 1-Jun-09 0.32 5.0 0.35 J Dry 2.6 J 0.62 J ND 19-Nov-09 0.32 5.0 ND ND ND 0.32 J ND NC 2L = 6 µg/L (01/01/10) 14-Jun-10 0.32 5.0 0.32 J 0.41 J 2.3 J 1.5 J ND 29-Nov-10 0.32 5.0 ND ND 2.7 J ND ND 31-May-11 0.32 5.0 0.35 J 0.40 J 2.6 J 0.67 J ND 19-Dec-11 0.32 5.0 ND ND 2.2 J ND ND 30-May-12 0.32 5.0 ND ND 1.9 J ND ND 3-Dec-12 0.32 5.0 ND ND 1.7 J ND ND 10-Jun-13 0.32 5.0 ND ND 1.8 J ND ND 28-Oct-13 0.32 5.0 ND ND 1.5 J 0.42 J ND 5-May-14 0.32 5.0 ND ND 1.6 J 0.57 J ND 20-Oct-14 0.32 5.0 ND ND 1.3 J 0.46 J ND 18-May-15 0.32 5.0 ND ND 0.87 J ND ND 7-Dec-15 0.32 5.0 ND ND 0.91 J ND ND 2-May-16 0.32 5.0 ND ND 0.95 J ND ND 12-Dec-16 0.32 5.0 ND ND 0.97 J ND ND 26-Jun-17 0.32 5.0 ND ND 0.97 J ND ND 14-Dec-17 0.32 5.0 ND ND 0.89 J ND ND 14-May-18 0.32 5.0 ND ND 0.63 J ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 20 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL M RL MW-1 MW-2 MW-3 AMW-1 Blanks 1,2-Dichloroethane 31-May-11 0.12 1.0 ND ND 0.12 J ND ND NC 2L = 0.4 µg/L (01/01/10) 19-Dec-11 0.12 1.0 ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND 10-Jun-13 0.12 1.0 ND ND ND ND ND 28-Oct-13 0.12 1.0 ND ND ND ND ND 5-May-14 0.12 1.0 ND ND ND ND ND 20-Oct-14 0.12 1.0 ND ND ND ND ND 18-May-15 0.12 1.0 ND ND ND ND ND 7-Dec-15 0.24 1.0 ND ND ND ND ND 2-May-16 0.24 1.0 ND ND ND ND ND 12-Dec-16 0.24 1.0 ND ND ND ND ND 26-Jun-17 0.24 1.0 ND ND ND ND ND 14-Dec-17 0.24 1.0 ND ND ND ND ND 14-May-18 0.24 1.0 ND ND ND ND ND cis-1,2-Dichloroethene 28-Apr-94 NR 5 12.0 80.0 20.0 NI ND 2-May-00 NR 5 11.0 58.0 22.0 NI ND 8-Nov-00 NR 5 16.0 65.0 33.0 NI ND 31-May-01 NR 5 11.0 75.0 26.0 NI ND 6-Nov-01 NR 5 15.0 68.0 22.0 NI ND 21-May-02 NR 5 21.0 92.0 34.0 NI ND 13-Nov-02 NR 5 16.0 100 29.0 NI ND 1-Apr-03 NR 5 NA NA NA ND NA 13-May-03 NR 5 21.0 82.0 26.0 NA ND 1-Jul-03 NR 5 NA NA NA NA ND 18-Nov-03 NR 5 9.0 91.0 28.0 23.0 ND 4-May-04 NR 5 11.0 78.0 26.0 19.0 ND 9-Nov-04 NR 5 11.0 66.0 24.0 13.0 ND 25-May-05 NR 5 14.0 59.0 28.0 17.0 ND 1-Nov-05 NR 5 ND 26.0 11.0 7.0 ND 23-May-06 NR 5 ND 26.8 14.0 7.4 ND 1-Nov-06 NR 5 13.0 53.0 25.0 13.0 ND 29-May-07 NR 5 15.0 49.0 24.0 20.0 ND NC 2L = 70 µg/L (10/23/07) 27-Nov-07 NR 5 ND 43.0 20.0 7.7 ND 27-May-08 0.19 5.0 9.8 50.3 22.0 7.4 ND 4-Nov-08 0.19 5.0 5.1 61.4 27.9 4.2 J ND 1-Jun-09 0.19 5.0 12.1 Dry 21.1 2.7 J ND 19-Nov-09 0.19 5.0 ND ND ND 12.6 0.26 J 14-Jun-10 0.19 5.0 6.6 51.4 21.7 21.4 ND 29-Nov-10 0.19 5.0 4.4 J 56.5 23.0 11.6 ND 31-May-11 0.19 5.0 7.0 56.2 25.6 12.2 ND 19-Dec-11 0.19 5.0 6.8 41.1 20.9 1.7 J ND 30-May-12 0.19 5.0 8.8 40.1 19.6 1.3 J ND 3-Dec-12 0.19 5.0 7.3 30.0 18.7 0.58 J ND 10-Jun-13 0.19 5.0 7.0 43.0 20.4 0.61 J ND 28-Oct-13 0.19 5.0 4.4 J 23.6 18.4 4.7 J ND 5-May-14 0.19 5.0 2.9 J 40.5 19.2 8.5 ND 20-Oct-14 0.19 5.0 2.7 J 33.9 16.6 7.0 ND 18-May-15 0.19 5.0 2.7 J 19.2 13.4 5.8 ND 7-Dec-15 0.19 5.0 4.0 J 26.9 15.4 3.2 J ND 2-May-16 0.19 5.0 2.1 J 17.2 13.8 7.1 ND 12-Dec-16 0.19 5.0 2.1 J 31.2 16.9 5.2 ND 26-Jun-17 0.19 5.0 2.3 J 24.0 14.7 4.9 J ND 14-Dec-17 0.19 5.0 3.0 J 21.6 15.3 2.6 J ND 14-May-18 0.19 5.0 1.9 J 18.9 10.6 3.6 J ND Burke County -East Burke Joyce Engineering Permit No. 12-02 21 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL RI MW-1 MW-2 MW-3 AMW-1 Blanks trans-1,2-Dichloroethene 29-May-07 NR 5 ND ND ND 0.4 J ND NC 2L = 100 µg/L (10/23/07) 27-Nov-07 NR 5 ND ND ND ND ND 27-May-08 0.49 5.0 ND ND ND ND ND 4-Nov-08 0.49 5.0 ND ND ND ND ND 1-Jun-09 0.49 5.0 ND Dry ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 14-Jun-10 0.49 5.0 ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND 10-Jun-13 0.49 5.0 ND ND ND ND ND 28-Oct-13 0.49 5.0 ND ND ND ND ND 5-May-14 0.49 5.0 ND ND ND ND ND 20-Oct-14 0.49 5.0 ND ND ND ND ND 18-May-15 0.49 5.0 ND ND ND ND ND 7-Dec-15 0.49 5.0 ND ND ND ND ND 2-May-16 0.49 5.0 ND ND ND ND ND 12-Dec-16 0.49 5.0 ND ND ND ND ND 26-Jun-17 0.49 5.0 ND ND ND ND ND 14-Dec-17 0.49 5.0 ND ND ND ND ND 14-May-18 0.49 5.0 ND ND ND ND ND Bromomethane 27-May-08 0.29 10.0 3.4 J ND ND ND ND NC 2L = NE µg/L (10/23/07) 4-Nov-08 0.29 10.0 ND ND ND ND ND 1-Jun-09 0.29 10.0 ND Dry ND ND ND 19-Nov-09 0.29 10.0 ND ND ND ND ND 14-Jun-10 0.29 10.0 ND ND ND ND ND GWPS = 10 µg/L (8/1/10) 29-Nov-10 0.29 10.0 ND ND ND ND ND 31-May-11 0.29 10.0 ND ND ND ND ND 19-Dec-11 0.29 10.0 ND ND ND ND ND 30-May-12 0.29 10.0 ND ND ND ND ND 3-Dec-12 0.29 10.0 ND ND ND ND ND 10-Jun-13 0.29 10.0 ND ND ND ND ND 28-Oct-13 0.29 10.0 ND ND ND ND ND 5-May-14 0.29 10.0 ND ND ND ND ND 20-Oct-14 0.29 10.0 ND ND ND ND ND 18-May-15 0.29 10.0 ND ND ND ND ND 7-Dec-15 0.29 10.0 ND ND ND ND ND 2-May-16 0.29 10.0 ND ND ND ND ND 12-Dec-16 0.29 10.0 ND ND ND ND ND 26-Jun-17 0.29 10.0 ND ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND ND 14-May-18 0.29 10.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 22 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date DL M RL MW-1 MW-2 MW-3 AMW-1 Blanks 1,2-Dichloropropane 14-Jun-10 0.27 1.0 ND ND ND 0.32 J ND NC 2L = 0.6 µg/L (01/01/10) 29-Nov-10 0.27 1.0 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND 0.28 J ND ND 10-Jun-13 0.27 1.0 ND ND ND ND ND 28-Oct-13 0.27 1.0 ND ND ND ND ND 5-May-14 0.27 1.0 ND ND ND ND ND 20-Oct-14 0.27 1.0 ND ND ND ND ND 18-May-15 0.27 1.0 ND ND ND ND ND 7-Dec-15 0.27 1.0 ND ND ND ND ND 2-May-16 0.27 1.0 ND ND ND ND ND 12-Dec-16 0.27 1.0 ND ND ND ND ND 26-Jun-17 0.27 1.0 ND ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND ND 14-May-18 0.27 1.0 ND ND ND ND ND Ethylbenzene 14-Jun-10 0.26 1.0 ND 0.35 J ND ND ND NC 2L = 600 µg/L (01/01/10) 29-Nov-10 0.30 1.0 ND ND ND ND ND 31-May-11 0.30 1.0 ND ND ND ND ND 19-Dec-11 0.30 1.0 ND ND ND ND ND 30-May-12 0.30 1.0 ND ND ND ND ND 3-Dec-12 0.30 1.0 ND ND ND ND ND 10-Jun-13 0.30 1.0 ND ND ND ND ND 28-00-13 0.30 1.0 ND ND ND ND ND 5-May-14 0.30 1.0 ND ND ND ND ND 20-Oct-14 0.30 1.0 ND ND ND ND ND 18-May-15 0.30 1.0 ND ND ND ND ND 7-Dec-15 0.30 1.0 ND ND ND ND ND 2-May-16 0.30 1.0 ND ND ND ND ND 12-Dec-16 0.30 1.0 ND ND ND ND ND 26-Jun-17 0.30 1.0 ND ND ND ND ND 14-Dec-17 0.30 1.0 ND ND ND ND ND 14-May-18 0.30 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 23 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date - MW-1 MW-2 MW-3 AMW-1 Blanks Styrene 1-Jun-09 0.26 1.0 2.0 Dry ND ND ND NC 2L = 100 µg/L (10/23/07) 19-Nov-09 0.26 1.0 ND ND ND ND ND NC 2L = 70 µg/L (01/01/10) 14-Jun-10 0.26 1.0 ND ND ND ND ND 29-Nov-10 0.26 1.0 ND ND ND ND ND 31-May-11 0.26 1.0 ND ND ND ND ND 19-Dec-11 0.26 1.0 ND ND ND ND ND 30-May-12 0.26 1.0 ND ND ND ND ND 3-Dec-12 0.26 1.0 ND ND ND ND ND 10-Jun-13 0.26 1.0 ND ND ND ND ND 28-Oct-13 0.26 1.0 ND ND ND ND ND 5-May-14 0.26 1.0 ND ND ND ND ND 20-Oct-14 0.26 1.0 ND ND ND ND ND 18-May-15 0.26 1.0 ND ND ND ND ND 7-Dec-15 0.26 1.0 ND ND ND ND ND 2-May-16 0.26 1.0 ND ND ND ND ND 12-Dec-16 0.26 1.0 ND ND ND ND ND 26-Jun-17 0.26 1.0 ND ND ND ND ND 14-Dec-17 0.26 1.0 ND ND ND ND ND 14-May-18 0.26 1.0 ND ND ND ND ND Methylene Chloride 28-Apr-94 NR 5 ND 5.8 7.8 NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND NC 2L = 4.6 µg/L (10/23/07) 27-Nov-07 NR 1 ND ND ND ND ND 27-May-08 0.97 2.0 ND ND ND ND 1.5 J 4-Nov-08 0.97 2.0 ND ND ND ND 2.8 1-Jun-09 0.97 2.0 ND Dry ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND NC 2L = 5 µg/L (01/01/10) 14-Jun-10 0.97 2.0 ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND ND 31-May-11 0.97 1.0 ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND IO-Jun-13 0.97 1.0 ND ND ND ND ND 28-Oct-13 0.97 1.0 ND ND ND ND ND 5-May-14 0.97 1.0 ND ND ND ND 2.6 20-Oct-14 0.97 1.0 ND ND ND ND ND 18-May-15 0.97 1.0 ND ND ND ND 1.3 7-Dec-15 0.97 1.0 ND ND ND ND ND 2-May-16 0.97 1.0 ND ND ND ND ND 12-Dec-16 0.97 1.0 ND ND ND ND ND 26-Jun-17 0.97 1.0 ND ND ND ND 1.3 C9 14-Dec-17 0.97 1.0 ND ND ND ND 2.1 C9 14-May-18 0.97 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 24 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Tetrachloroethene 28-Apr-94 NR 5.0 ND 14.0 6.2 NI ND (PCE) 6-Oct-94 NR 5.0 ND 13.0 10.0 NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 0.6 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 0.6 J 0.57 J 1.0 ND ND NC 2L = 0.7 µg/L (10/23/07) 27-Nov-07 NR 1 ND 0.43 J 0.67 J ND ND 27-May-08 0.46 1.0 0.53 J 0.54 J 0.60 J ND ND 4-Nov-08 0.46 1.0 0.48 J ND 0.58 J ND ND 1-Jun-09 0.46 1.0 0.49 J Dry 0.48 J ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND 14-Jun-10 0.46 1.0 0.53 J ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND ND 31-May-11 0.46 1.0 ND ND ND ND ND 19-Dec-11 0.46 1.0 ND ND 0.49 B ND 0.77 J 30-May-12 0.46 1.0 ND ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND ND 10-Jun-13 0.46 1.0 0.50 J ND ND ND ND 28-00-13 0.46 1.0 ND ND ND ND ND 5-May-14 0.46 1.0 ND ND ND ND ND 20-Oct-14 0.46 1.0 ND ND ND ND ND 18-May-15 0.46 1.0 ND ND ND ND ND 7-Dec-15 0.46 1.0 ND ND ND ND ND 2-May-16 0.46 1.0 0.55 J ND ND ND ND 12-Dec-16 0.46 1.0 ND ND ND ND ND 26-Jun-17 0.46 1.0 ND ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND ND 14-May-18 0.46 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 25 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RI MW-1 MW-2 MW-3 AMW-1 Blanks Trichloroethene 28-Apr-94 NR 5 ND 9.9 7.2 NI ND (TCE) 6-Oct-94 NR 5 ND 10.0 7.6 NI ND 2-May-00 NR 5 ND ND ND NI ND 8-Nov-00 NR 5 ND ND 5.5 NI ND 31-May-01 NR 5 ND ND ND NI ND 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 5 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 ND 2.9 3.1 3.0 ND NC 2L = 2.8 µg/L (10/23/07) 27-Nov-07 NR 1 ND 1.5 1.7 ND ND 27-May-08 0.47 1.0 ND 1.5 1.6 0.56 J ND 4-Nov-08 0.47 1.0 ND 1.6 1.6 ND ND 1-Jun-09 0.47 1.0 ND Dry 1.4 ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND NC 2L = 3 µg/L (01/01/10) 14-Jun-10 0.47 1.0 ND 0.92 J 1.3 1.2 ND 29-Nov-10 0.47 1.0 ND 1.3 1.5 ND ND 31-May-11 0.47 1.0 ND 0.84 J 1.3 0.59 J ND 19-Dec-11 0.47 1.0 ND 0.87 J 1.3 ND ND 30-May-12 0.47 1.0 ND 0.61 J 1.1 ND ND 3-Dec-12 0.47 1.0 ND 0.68 J 1.0 ND ND 10-Jun-13 0.47 1.0 ND 1.8 1.1 ND ND 28-00-13 0.47 1.0 ND 0.50 J 0.86 J ND ND 5-May-14 0.47 1.0 ND 0.85 J 0.92 J 0.57 J ND 20-Oct-14 0.47 1.0 ND 0.69 J 0.81 J ND ND 18-May-15 0.47 1.0 ND ND 0.66 J ND ND 7-Dec-15 0.47 1.0 ND ND 0.71 J ND ND 2-May-16 0.47 1.0 ND ND 0.55 J ND ND 12-Dec-16 0.47 1.0 ND 0.51 J 0.65 J ND ND 26-Jun-17 0.47 1.0 ND ND 0.60 J ND ND 14-Dec-17 0.47 1.0 ND ND 0.57 J ND ND 14-May-18 0.47 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 26 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date - MW-1 MW-2 MW-3 AMW-1 Blanks Toluene 19-Nov-09 0.26 1.0 ND ND ND 0.49 J ND NC 2L = 6,000 µg/L (01/01/10) 14-Jun-10 0.26 1.0 1.1 ND ND ND ND 29-Nov-10 0.26 1.0 ND ND ND ND ND 31-May-11 0.26 1.0 ND ND ND ND ND 19-Dec-11 0.26 1.0 ND ND ND ND ND 30-May-12 0.26 1.0 ND ND ND ND ND 3-Dec-12 0.26 1.0 ND ND ND ND ND IO-Jun-13 0.26 1.0 ND ND ND ND ND 28-Oct-13 0.26 1.0 ND ND ND ND ND 5-May-14 0.26 1.0 ND ND ND ND ND 20-Oct-14 0.26 1.0 ND ND ND ND ND 18-May-15 0.26 1.0 ND ND ND ND ND 7-Dec-15 0.26 1.0 ND ND ND ND ND 2-May-16 0.26 1.0 ND ND ND ND ND 12-Dec-16 0.26 1.0 ND ND ND ND ND 26-Jun-17 0.26 1.0 ND ND ND ND ND 14-Dec-17 0.26 1.0 ND ND ND ND ND 14-May-18 0.26 1.0 ND ND ND ND ND Vinyl Chloride 12-May-97 NR 5 ND ND 3.1 J NI ND 2-May-00 NR 10 ND ND ND NI ND 8-Nov-00 NR 10 ND ND ND NI ND 31-May-01 NR 10 ND ND ND NI ND 6-Nov-01 NR 10 ND ND ND NI ND 21-May-02 NR 10 ND ND ND NI ND 13-Nov-02 NR 10 ND ND ND NI ND 13-May-03 NR 10 ND ND ND NI ND 18-Nov-03 NR 10 ND ND ND ND ND 4-May-04 NR 10 ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND 1-Nov-05 NR 10 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 1 1.8 ND 1.3 2.0 ND NC 2L = 0.015 µg/L (10/23/07) 27-Nov-07 NR 1 0.75 J ND 0.69 J ND ND 27-May-08 0.62 1.0 1.3 ND 1.0 ND ND 4-Nov-08 0.62 1.0 0.67 J ND 1.0 ND ND 1-Jun-09 0.62 1.0 1.4 Dry 0.83 J ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.6 ND NC 2L = 0.03 µg/L (01/01/10) 14-Jun-10 0.62 1.0 1.3 ND 1.3 0.67 J ND 29-Nov-10 0.62 1.0 1.1 0.63 J 1.3 0.65 J ND 31-May-11 0.62 1.0 1.3 ND 1.0 0.81 J ND 19-Dec-11 0.62 1.0 1.2 ND 0.84 J ND ND 30-May-12 0.62 1.0 2.1 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND 10-Jun-13 0.62 1.0 1.4 ND 0.86 J ND ND 28-Oct-13 0.62 1.0 0.64 J ND ND ND ND 5-May-14 0.62 1.0 0.65 J ND 0.76 J ND ND 20-Oct-14 0.62 1.0 ND ND ND ND ND 18-May-15 0.62 1.0 ND ND ND ND ND 7-Dec-15 0.62 1.0 1 ND ND ND ND 2-May-16 0.62 1.0 ND ND ND ND ND 12-Dec-16 0.62 1.0 ND ND ND ND ND 26-Jun-17 0.62 1.0 ND ND 0.63 J ND ND 14-Dec-17 0.62 1.0 0.69 J ND 0.71 J ND ND 14-May-18 0.62 1.0 ND ND ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 27 of 28 September 2018 TABLE A2-2: Historical Groundwater Constituents Analyte Sample Collection Date I I DL RL MW-1 MW-2 MW-3 AMW-1 Blanks Xylene (Total) 28-Apr-94 NR 5 5.1 15.0 ND NI ND 8-Nov-00 NR 5 ND ND ND NI ND 1-Oct-99 NR 5 ND 5.9 ND NI ND NC 2L = 530 µg/L (10/23/07) 2-May-00 NR 5 ND ND ND NI ND 31-May-01 NR 5 ND ND ND NI ND C 2L = 500 µg/L (01/01/10) 6-Nov-01 NR 5 ND ND ND NI ND 21-May-02 NR 5 ND ND ND NI ND 13-Nov-02 NR 5 ND ND ND NI ND 13-May-03 NR 5 ND ND ND NI ND 18-Nov-03 NR 5 ND ND ND ND ND 4-May-04 NR 5 ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND 1-Nov-05 NR 5 ND ND ND ND ND 23-May-06 NR 10 ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND 29-May-07 NR 4 ND 1.3 J ND ND ND 27-Nov-07 NR 5 ND 1.4 J ND ND ND 27-May-08 0.89 10.0 ND 1.5 J ND ND ND 4-Nov-08 0.66 10.0 ND 1.3 J ND ND ND NC 2L = 530 µg/L (10/23/07) 1-Jun-09 0.66 2.0 ND Dry ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND ND NC 2L = 500 µg/L (01/01/10) 14-Jun-10 0.66 2.0 ND 3.1 ND ND ND 29-Nov-10 0.66 2.0 ND 2.3 ND ND ND 31-May-11 0.66 2.0 ND 0.80 J ND ND ND 19-Dec-11 0.66 2.0 ND 0.89 J ND ND ND 30-May-12 0.66 2.0 ND ND ND ND ND 3-Dec-12 0.66 2.0 ND ND ND ND ND 10-Jun-13 0.66 5.0 ND ND ND ND ND 28-Oct-13 0.66 5.0 ND ND ND ND ND 5-May-14 0.66 5.0 ND ND ND ND ND 20-Oct-14 0.66 5.0 ND ND ND ND ND 18-May-15 0.66 5.0 ND ND ND ND ND 7-Dec-15 0.66 5.0 ND ND ND ND ND 2-May-16 0.66 5.0 ND ND ND ND ND 12-Dec-16 0.66 5.0 ND ND ND ND ND 26-Jun-17 0.66 5.0 ND ND ND ND ND 14-Dec-17 0.66 5.0 ND ND ND ND ND 14-May-18 0.66 5.0 ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and Solid Waste Section Reporting Limit (SWSL) for December 2006 - 2017; NC PQL for 2018 - present). DL = Laboratory detection limit ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NR = Not reported. NI = Not installed. NE = Not established. J = Estimated concentration less than the RL but greater than the DL. B = Blank -Qualified (Concentration suspected to reflect laboratory or field contamination). NC2L = North Carolina 2L Groundwater Standards (15A NCAC 2L). GWPS = Groundwater Protection Standards established by the Solid Waste Section Bold values are greater than the NC2L Standards or GWPS. Historical data between 1994-1999 availible upon request Burke County -East Burke Joyce Engineering Permit No. 12-02 28 of 28 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks INORGANICS Arsenic 29-May-07 NR 10 Dry 2.3 J ND 27-Nov-07 NR 10 Dry 2.8 J ND lv k� Li71rSrIA 1-4k, - 1 V µg/I- m4 V/0/AQN y_ 27_Ma 08 2.7 10.0 Dry D ND ND 04-Nov-08 2.6 10.0 Dry ND 4.8 J O1-Jun-09 2.6 10.0 Dry ND ND 19-Nov-09 2.7 10.0 ND ND ND NC 2B = 10 µg/L (05/O1/07) 14-Jun-10 2.7 10.0 ND 3.3 J ND 29-Nov-10 2.7 10.0 ND ND ND 31-May-11 2.7 10.0 ND ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND ND ND 28-Oct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry 3.2 J ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 5.0 10.0 Dry ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND 03-Dec-18 EPA 6010 5.0 10.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 1 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Barium Nov-97 NR 100 ND 1000 NA May-98 NR 100 ND ND ND Nov-98 NR 100 ND ND ND May-99 NR 5 18.0 19.0 ND Oct-99 NR 500 ND ND ND May-00 NR 500 ND ND ND Nov-00 NR 500 Dry ND ND May-Ol NR 500 Dry ND ND Nov-Ol NR 500 Dry ND ND May-02 NR 500 Dry ND ND Nov-02 NR 500 ND ND ND May-03 NR 500 ND ND ND Nov-03 NR 500 ND ND ND May-04 NR 500 Dry ND ND Nov-04 NR 500 ND ND ND May-05 NR 500 Dry ND ND Nov-05 NR 500 Dry ND ND 23-May-06 NR 500 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 100 Dry 44.1 J ND 27-Nov-07 NR 100 Dry 46.5 J 0.30 J isk, zrwnrri 1-o" - r,vvv µg/r, fnq /�O/AON 27-Ma 08 3'- 0.2 100 D n' 48.8 J 0.41 J 04-Nov-08 0.20 100 Dry 51.7 B 10.5 J 01-Jun-09 0.20 100 Dry 41.2 B 15.2 J 19-Nov-09 0.20 100 81.4 B 40.5 B 19.8 J NC 2B = 1,000 µg/L (05/O1/07) 14-Jun-10 0.20 100 111 39.8 J 0.58 J 29-Nov-10 0.20 100 94.7 J 39.2 J ND 31-May-11 0.20 100 92.9 J 37.6 J ND 19-Dec-11 5.0 100 Dry 38.2 J ND 29-May-12 5.0 100 Dry 38.5 J ND 03-Dec-12 5.0 100 Dry 43.0 J ND 10-Jun-13 5.0 100 21.3 B 86.4 J 13.7 J 28-Oct-13 5.0 100 15.4 J 36.8 J ND 05-May-14 EPA 6010 5.0 100 13.7 J 44.5 J ND 20-Oct-14 EPA 6010 5.0 100 13.3 J 39.8 J ND 18-May-15 EPA 6010 2.5 100 Dry 38.9 J ND 07-Dec-15 EPA 6010 2.5 100 Dry 54.3 J ND 02-May-16 EPA 6010 2.5 100 Dry 41.6 J ND 12-Dec-16 EPA 6010 2.5 100 Dry 45.4 J ND 26-Jun-17 EPA 6010 2.5 100 Dry 53.1 J 2.5 J 14-May-18 EPA 6010 2.5 100 23.2 J 41.9 J ND 03-Dec-18 EPA 6010 2.5 5 39.1 49.3 ND Burke County -East Burke Joyce Engineering Permit No. 12-02 2 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents alyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Beryllium Nov-02 NR 2 3.2 3.6 ND May-03 NR 2 ND ND ND Nov-03 NR 2 ND ND ND May-04 NR 2 Dry ND ND Nov-04 NR 2 ND ND ND May-05 NR 2 Dry ND ND Nov-05 NR 2 Dry ND ND 23-May-06 NR 2 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND m� i�oino� 27-Ma}'- 08 0.1 1.0 D ND n' ND 04-Nov-08 0.10 1.0 Dry ND ND O1-Jun-09 0.10 1.0 Dry ND ND 19-Nov-09 0.10 1.0 ND ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.10 1.0 ND ND ND 29-Nov-10 0.10 1.0 ND ND ND 31-May-11 0.10 1.0 ND ND ND 19-Dec-11 1.0 1.0 Dry ND ND 29-May-12 1.0 1.0 Dry ND ND 03-Dec-12 1.0 1.0 Dry ND ND 10-Jun-13 1.0 1.0 ND ND ND 28-Oct-13 1.0 1.0 ND ND ND 05-May-14 EPA 6010 1.0 1.0 ND ND ND 20-Oct-14 EPA 6010 1.0 1.0 ND ND ND 18-May-15 EPA 6010 0.5 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.5 1.0 Dry ND ND 02-May-16 EPA 6010 0.5 1.0 Dry ND ND 12-Dec-16 EPA 6010 0.5 1.0 Dry ND ND 26-Jun-17 EPA 6010 0.5 1.0 Dry ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND 03-Dec-18 EPA 6010 0.5 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 3 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents alyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Cadmium Oct-99 NR 1 ND 1.0 ND May-00 NR 1 ND ND ND Nov-00 NR 1 Dry ND ND May-Ol NR 1 Dry ND ND Nov-Ol NR 1 Dry ND ND May-02 NR 1 Dry 1.0 ND Nov-02 NR 1 1.2 1.5 ND May-03 NR 1 ND ND ND Nov-03 NR 1 ND ND ND May-04 NR 1 Dry ND ND Nov-04 NR 1 ND ND ND May-05 NR 1 Dry ND ND Nov-05 NR 1 Dry ND ND 23-May-06 NR 1 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND NC 2B/EPA NC = 2 µg/L (03/28/08) 27-May-08 0.5 1.0 Dry ND ND 04-Nov-08 0.50 1.0 Dry ND ND 01-Jun-09 0.50 1.0 Dry ND ND 19-Nov-09 0.50 1.0 ND ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.50 1.0 ND ND ND 29-Nov-10 0.50 1.0 ND ND ND 31-May-11 0.50 1.0 ND ND ND 19-Dec-11 1.0 1.0 Dry ND ND 29-May-12 1.0 1.0 Dry ND ND 03-Dec-12 1.0 1.0 Dry ND ND 10-Jun-13 1.0 1.0 ND ND ND 28-Oct-13 1.0 1.0 ND ND ND 05-May-14 EPA 6010 1.0 1.0 ND ND ND 20-Oct-14 EPA 6010 1.0 1.0 ND ND ND 18-May-15 EPA 6010 0.5 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.5 1.0 Dry ND ND 02-May-16 EPA 6010 0.5 1.0 Dry ND ND 12-Dec-16 EPA 6010 0.5 1.0 Dry ND ND 26-Jun-17 EPA 6010 0.5 1.0 Dry ND ND 14-May-18 EPA 6010 0.5 1.0 ND ND ND 03-Dec-18 EPA 6010 0.5 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 4 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents alyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Chromium May-97 NR 1 2.0 1.0 ND Nov-97 NR 1 ND ND NA May-98 NR 1 ND ND ND Nov-98 NR 1 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-Ol NR 10 Dry ND ND Nov-Ol NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry ND ND 23-May-06 NR 10 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry ND ND 27-Nov-07 NR 10 Dry ND ND ivi. /MrrIA 1.0- -.w µg/lL mq i�oinoN 27_Ma 08 y- 0.4 10.0 Dry D ND 0.85 J 04-Nov-08 0.40 10.0 Dry ND ND 01-Jun-09 0.40 10.0 Dry ND ND Anmrri ro, - w µg/L, lnninc ii m ins 19-Nov-09 0.40 10.0 0.48 B ND 1.1 J NC 2B = 20 µg/L (05/O1/07) 14-Jun-10 0.40 10.0 7 J 0.42 J ND 29-Nov-10 0.40 10.0 ND ND ND 31-May-11 0.40 10.0 1.2 B 1.2 B 0.73 J 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 16.7 ND 28-Oct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03-Dec-18 EPA 6010 2.5 5.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 5 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents nalyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Cobalt May-98 NR 1.0 ND 3.0 ND Nov-98 NR 1.0 ND ND ND May-99 NR 5.0 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-Ol NR 10 Dry ND ND Nov-Ol NR 10 Dry ND ND May-02 NR 10 Dry ND NA Nov-02 NR 10 ND ND ND May-03 NR 10 23.0 ND ND Nov-03 NR 10 34.0 10.0 ND May-04 NR 10 Dry 10.0 ND Nov-04 NR 10 16.0 12.0 ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry 11.0 ND 23-May-06 NR 10 Dry 12.4 ND 06-Nov-06 NR 10 17.5 ND ND 29-May-07 NR 10 Dry 10.7 ND 27-Nov-07 NR 10 Dry 10.4 ND isk, zrwnrri ro" - 17v µgii fnq i�oinoN 27-Ma 08 y- 0.6 10.0 Dry D 11.3 ND 05-Nov-08 0.60 10.0 Dry 14.9 B 3.5 J 01-Jun-09 0.60 10.0 Dry 15.0 B 3.3 J NC 2B = NE µg/L (05/01/07) 19-Nov-09 0.60 10.0 ND 5.5 J ND 14-Jun-10 0.60 10.0 64.4 11.0 ND 29-Nov-10 0.60 10.0 54.1 10.3 ND 31-May-11 0.60 10.0 23.6 8.1 J ND 19-Dec-11 5.0 10.0 Dry 8.2 J ND 29-May-12 5.0 10.0 Dry 8.9 J ND 03-Dec-12 5.0 10.0 Dry 11.7 ND 10-Jun-13 5.0 10.0 ND 18.2 ND 28-Oct-13 5.0 10.0 ND 11.4 ND 05-May-14 EPA 6010 5.0 10.0 ND 6.9 J ND 20-Oct-14 EPA 6010 5.0 10.0 ND 8.2 J ND 18-May-15 EPA 6010 2.5 10.0 Dry 8.5 J ND 07-Dec-15 EPA 6010 2.5 10.0 Dry 6.2 J ND 02-May-16 EPA 6010 2.5 10.0 Dry 6.3 J ND 12-Dec-16 EPA 6010 2.5 10.0 Dry 9.2 J ND 26-Jun-17 EPA 6010 2.5 10.0 Dry 10.0 J ND 14-May-18 EPA 6010 2.5 10.0 ND 8.5 J ND 03-Dec-18 EPA 6010 2.5 5.0 2.7 J 7.4 ND Burke County -East Burke Joyce Engineering Permit No. 12-02 6 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Copper May-97 NR 10 40.0 ND ND Nov-97 NR 10 ND ND ND May-98 NR 10 ND ND ND Nov-98 NR 10 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 200 ND ND ND May-00 NR 200 ND ND ND Nov-00 NR 200 Dry ND ND May-Ol NR 200 Dry ND ND Nov-Ol NR 200 Dry ND ND May-02 NR 200 Dry ND ND Nov-02 NR 200 ND ND ND May-03 NR 200 ND ND ND Nov-03 NR 200 ND ND ND May-04 NR 200 Dry ND ND Nov-04 NR 200 ND ND ND May-05 NR 200 Dry ND ND Nov-05 NR 200 Dry ND ND 23-May-06 NR 200 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry ND ND 27-Nov-07 NR 10 Dry ND ND NC 2B/EPA NC = 7 µg/L (03/28/08) 27-May-08 0.3 10.0 Dry ND ND 05-Nov-08 0.30 10.0 Dry ND 0.94 J 01-Jun-09 0.30 10.0 Dry ND ND 19-Nov-09 0.30 10.0 1.1 J ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.30 10.0 1.9 B ND 3.4 J 29-Nov-10 0.30 10.0 ND ND ND 31-May-11 0.30 10.0 0.47 J ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 7.7 B 10.8 28-Oct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03-Dec-18 EPA 6010 2.5 5.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 7 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents nalyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Lead 29-May-07 NR 10 Dry 2.9 B 6.1 J 27-Nov-07 NR 10 Dry ND ND ms i�oino� 27-Ma}'- 08 4 10.0 D ND n' ND 04-Nov-08 4.0 10.0 Dry ND ND O1-Jun-09 4.0 10.0 Dry ND ND 19-Nov-09 4.0 10.0 ND ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 4.0 10.0 ND ND ND 29-Nov-10 4.0 10.0 ND ND ND 31-May-11 4.0 10.0 ND ND ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND 8.7 J ND 28-Oct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03-Dec-18 EPA 6010 2.5 5.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 8 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents nalyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Nickel May-97 NR 50 4500 140 ND Nov-97 NR 50 ND ND ND May-98 NR 50 ND ND ND Nov-98 NR 50 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 50 ND ND ND May-00 NR 50 ND ND ND Nov-00 NR 50 Dry ND ND May-Ol NR 50 Dry ND ND Nov-Ol NR 50 Dry ND ND May-02 NR 50 Dry ND ND Nov-02 NR 50 ND ND ND May-03 NR 50 ND ND ND Nov-03 NR 50 ND ND ND May-04 NR 50 Dry ND ND Nov-04 NR 50 ND ND ND May-05 NR 50 Dry ND ND Nov-05 NR 50 Dry ND ND 23-May-06 NR 50 Dry ND ND 06-Nov-06 NR 50 ND ND ND 29-May-07 NR 50 Dry 3.7 J ND 27-Nov-07 NR 50 Dry 4.3 J ND i�i, - �� µy�L, ivi. �/AQN m� i�Qino 27-Ma 08 3'- 1.7 50.0 D 6.0 J n' ND 04-Nov-08 1.7 50.0 Dry 7.9 B 2.2 J 01-Jun-09 1.7 50.0 Dry 4.7 J ND 19-Nov-09 1.7 50.0 4.8 B 3.6 B 2.2 J NC 2B = 25 µg/L (05/O1/07) 14-Jun-10 1.7 50.0 14.1 J 3.3 J ND 29-Nov-10 1.7 50.0 5.3 J 2.4 J ND 31-May-11 1.7 50.0 7.6 B 5.2 B 2.3 J 19-Dec-11 5.0 50.0 Dry ND ND 29-May-12 5.0 50.0 Dry ND ND 03-Dec-12 5.0 50.0 Dry ND ND 10-Jun-13 5.0 50.0 ND 12.8 J ND 28-Oct-13 5.0 50.0 ND ND ND 05-May-14 EPA 6010 5.0 50.0 ND ND ND 20-Oct-14 EPA 6010 5.0 50.0 ND ND ND 18-May-15 EPA 6010 2.5 50.0 Dry 4.4 J ND 07-Dec-15 EPA 6010 2.5 50.0 Dry 4.7 J ND 02-May-16 EPA 6010 2.5 50.0 Dry 3.8 J ND 12-Dec-16 EPA 6010 2.5 50.0 Dry 4.8 J ND 26-Jun-17 EPA 6010 2.5 50.0 Dry 5.7 J ND 14-May-18 EPA 6010 2.5 50.0 ND 5 J ND 03-Dec-18 EPA 6010 2.5 5.0 ND 4.3 J ND Burke County -East Burke Joyce Engineering Permit No. 12-02 9 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents nalyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Silver 27-May-08 0.1 10.0 Dry 0.11 B 0.14 J 04-Nov-08 0.10 10.0 Dry 0.41 B 0.20 J O1-Jun-09 0.10 10.0 Dry 0.12 J ND 19-Nov-09 0.10 10.0 ND 0.14 J ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.10 10.0 ND ND ND 29-Nov-10 0.10 10.0 ND ND ND 31-May-11 0.10 10.0 1.0 J 0.68 J ND 19-Dec-11 5.0 10.0 Dry ND ND 29-May-12 5.0 10.0 Dry ND ND 03-Dec-12 5.0 10.0 Dry ND ND 10-Jun-13 5.0 10.0 ND ND ND 28-Oct-13 5.0 10.0 ND ND ND 05-May-14 EPA 6010 5.0 10.0 ND ND ND 20-Oct-14 EPA 6010 5.0 10.0 ND ND ND 18-May-15 EPA 6010 2.5 10.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 10.0 Dry ND ND 02-May-16 EPA 6010 2.5 10.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 10.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 10.0 Dry ND ND 14-May-18 EPA 6010 2.5 10.0 ND ND ND 03-Dec-18 EPA 6010 2.5 5.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 10 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Thallium Nov-97 NR 1 ND 1.0 ND May-98 NR 1 ND ND ND Nov-98 NR 1 ND ND ND May-99 NR 2 ND ND ND Oct-99 NR 10 ND ND ND May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-Ol NR 10 Dry ND ND Nov-Ol NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 ND ND ND Nov-05 NR 10 Dry ND ND 23-May-06 NR 10 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 5.5 Dry 0.168 J ND 27-Nov-07 NR 5.5 Dry 0.136 J ND m� i�oino� 27-May- 08 3 5.5 D ND n' ND 04-Nov-08 3.0 5.5 Dry ND ND 01-Jun-09 3.0 5.5 Dry ND ND 19-Nov-09 3.0 5.5 ND ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 3.0 5.5 3.0 J ND ND 29-Nov-10 3.0 5.5 ND ND ND 31-May-11 3.0 5.5 ND ND ND 19-Dec-I1 5.4 5.5 Dry ND ND 29-May-12 5.4 5.5 Dry ND ND 03-Dec-12 5.4 5.5 Dry ND ND 10-Jun-13 5.4 5.5 ND ND ND 28-Oct-13 5.4 5.5 ND ND ND 05-May-14 EPA 6010 5.4 5.5 ND ND ND 20-Oct-14 EPA 6010 5.4 5.5 ND ND ND 18-May-15 EPA 6010 5.0 5.5 Dry ND ND 07-Dec-15 EPA 6010 5.0 5.5 Dry ND ND 02-May-16 EPA 6010 5.0 5.5 Dry ND ND 12-Dec-16 EPA 6010 5.0 5.5 Dry ND 5.5 J 26-Jun-17 �nrtl 0.0 5.5 Dry 0.12 J ND 14-May-18 EPA 6020 0.5 5.5 ND ND ND 03-Dec-18 �nrtl 0.06 0.1 ND 0.11 ND Burke County -East Burke Joyce Engineering Permit No. 12-02 11 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Vanadium 01-Jun-09 0.20 25.0 Dry 0.24 B 1.2 J iAI gQ/AQN A iNi, -inn µy�L, ms i�oino� 19-Nov-09 0.20 25.0 0.33 B 0.30 B 0.58 J NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.20 25.0 5.9 J 0.22 B 0.25 J 29-Nov-10 0.20 25.0 ND ND ND 31-May-11 0.20 25.0 ND ND ND 19-Dec-11 5.0 25.0 Dry ND ND 29-May-12 5.0 25.0 Dry ND ND 03-Dec-12 5.0 25.0 Dry ND ND 10-Jun-13 5.0 25.0 ND 21.2 J ND 28-Oct-13 5.0 25.0 ND ND ND 05-May-14 EPA 6010 5.0 25.0 ND ND ND 20-Oct-14 EPA 6010 5.0 25.0 ND ND ND 18-May-15 EPA 6010 2.5 25.0 Dry ND ND 07-Dec-15 EPA 6010 2.5 25.0 Dry ND ND 02-May-16 EPA 6010 2.5 25.0 Dry ND ND 12-Dec-16 EPA 6010 2.5 25.0 Dry ND ND 26-Jun-17 EPA 6010 2.5 25.0 Dry ND ND 14-May-18 EPA 6010 2.5 25.0 ND ND ND 03-Dec-18 EPA 6010 2.5 5.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 12 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents nalyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Zinc Oct-94 NR 10 10.0 10.0 14.0 Jun-95 NR 10 ND ND 12.0 Oct-95 NR 10 NA 46.0 ND Oct-96 NR 10 ND ND NA May-97 NR 10 40.0 10.0 ND Nov-97 NR 10 ND ND NA May-98 NR 10 ND ND ND Nov-98 NR 10 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 50 ND ND ND May-00 NR 50 ND ND ND Nov-00 NR 50 Dry ND ND May-01 NR 50 Dry ND ND Nov-01 NR 50 Dry ND ND May-02 NR 50 Dry ND ND Nov-02 NR 50 ND ND ND May-03 NR 50 ND ND ND Nov-03 NR 50 ND ND ND May-04 NR 50 Dry ND ND Nov-04 NR 50 ND ND ND May-05 NR 50 Dry ND ND Nov-05 NR 50 Dry ND ND 23-May-06 NR 50 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 10 Dry 1.2 B 2.0 J 27-Nov-07 NR 10 Dry ND ND ivi. /MrrIA 1V1, -.w µg/lL mq /�Q/AQN 27_Ma 08 y- 0.4 10.0 D Dry 2.3 B 4.8 J 04-Nov-08 0.40 10.0 Dry ND 8.9 J 01-Jun-09 0.40 10.0 Dry 8.2 B 83.0 19-Nov-09 0.40 10.0 9.1 B 31.9 3.5 J NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.40 10.0 18.0 B ND 10.1 29-Nov-10 0.40 10.0 8.3 J 0.44 J ND 31-May-11 0.40 10.0 7.7 B 8.9 B 13.7 19-Dec-11 10.0 10.0 Dry ND ND 29-May-12 10.0 10.0 Dry ND ND 03-Dec-12 10.0 10.0 Dry ND ND 10-Jun-13 10.0 10.0 ND 30.7 B 76.3 28-Oct-13 10.0 10.0 ND ND ND 05-May-14 EPA 6010 10.0 10.0 ND ND ND 20-Oct-14 EPA 6010 10.0 10.0 ND ND ND 18-May-15 EPA 6010 5.0 10.0 Dry ND ND 07-Dec-15 EPA 6010 5.0 10.0 Dry 5.5 B 7.2 J 02-May-16 EPA 6010 5.0 10.0 Dry ND ND 12-Dec-16 EPA 6010 5.0 10.0 Dry ND ND 26-Jun-17 EPA 6010 5.0 10.0 Dry ND ND 14-May-18 EPA 6010 5.0 10.0 ND ND ND 03-Dec-18 EPA 6010 5.0 10.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 13 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents n-ampie Collection EPA Analyte Date Method DL RL SW-1 SW-2 Blanks Organic Compounds Acetone 27-Nov-07 NR 100 Dry 4.4 B 4.3 J ivk, Znirrri iNk, - /,wv µg/]- m4 NO/n0\ }'- 27-Ma 08 20 100 D n' ND ND 04-Nov-08 20.0 100 Dry ND ND 01-Jun-09 20.0 100 Dry ND 3.2 J 19-Nov-09 2.2 100 ND ND 3.8 J NC 2B = NE µg/L (05/O1/07) 14-Jun-10 2.2 100 5.5 B ND 8.9 J 29-Nov-10 2.2 100 ND ND 2.3 J 31-May-11 2.2 100 5.8 B 2.3 B 3.9 J 19-Dec-11 2.2 100 Dry ND 6.6 J 29-May-12 2.2 100 Dry ND ND 03-Dec-12 10.0 100.0 Dry ND ND 10-Jun-13 10.0 100.0 ND ND ND 28-Oct-13 10.0 100.0 ND ND ND 05-May-14 EPA 8260 10.0 100.0 ND ND ND 20-Oct-14 EPA 8260 10.0 100.0 ND ND ND 18-May-15 EPA 8260 10.0 100.0 Dry ND ND 07-Dec-15 EPA 8260 10.0 100.0 Dry ND ND 02-May-16 EPA 8260 10.0 100.0 Dry ND ND 12-Dec-16 EPA 8260 10.0 100.0 Dry ND ND 26-Jun-17 EPA 8260 10.0 100.0 Dry 20.9 B 23.0 J 14-May-18 EPA 8260 10.0 100.0 ND ND ND 03-Dec-18 EPA 8260 10.0 25.0 ND ND ND Benzene 19-Nov-09 0.25 1.0 3.6 0.76 J ND Resample> 15-Feb-10 0.25 1.0 ND NS ND NC 2B = 1.19 µg/L (05/O1/07) 14-Jun-10 0.25 1.0 ND ND ND 29-Nov-10 0.25 1.0 ND ND ND 31-May-11 0.25 1.0 ND ND ND 19-Dec-11 0.25 1.0 Dry ND ND 29-May-12 0.25 1.0 Dry ND ND 03-Dec-12 0.25 1.0 Dry ND ND 10-Jun-13 0.25 1.0 ND ND ND 28-Oct-13 0.25 1.0 ND ND ND 05-May-14 EPA 8260 0.25 1.0 ND ND ND 20-Oct-14 EPA 8260 0.25 1.0 ND ND ND 18-May-15 EPA 8260 0.25 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.25 1.0 Dry ND ND 02-May-16 EPA 8260 0.25 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.25 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.25 1.0 Dry ND ND 14-May-18 EPA 8260 0.25 1.0 ND ND ND 03-Dec-18 EPA 8260 0.25 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 14 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents n-ampre Collection EPA Date Method DL RL SW-1 -2 Blanks Chlorobenzene 19-Nov-09 0.23 3.0 0.70 J 0.61 J ND 1v1, gnmrrA ivy. - iw µg/L, ms iqoinoN 14-Jun-10 0.23 3.0 ND ND ND NC 2B = 488 µg/L (05/01/07) 29-Nov-10 0.23 3.0 ND ND ND 31-May-11 0.23 3.0 ND ND ND 19-Dec-11 0.23 3.0 Dry ND ND 29-May-12 0.23 3.0 Dry ND ND 03-Dec-12 0.23 3.0 Dry ND ND 10-Jun-13 0.23 3.0 ND ND ND 28-Oct-13 0.23 3.0 ND ND ND 05-May-14 EPA 8260 0.23 3.0 ND ND ND 20-Oct-14 EPA 8260 0.23 3.0 ND ND ND 18-May-15 EPA 8260 0.23 3.0 Dry ND ND 07-Dec-15 EPA 8260 0.23 3.0 Dry ND ND 02-May-16 EPA 8260 0.23 3.0 Dry ND ND 12-Dec-16 EPA 8260 0.23 3.0 Dry ND ND 26-Jun-17 EPA 8260 0.23 3.0 Dry ND ND 14-May-18 EPA 8260 0.23 3.0 ND ND ND 03-Dec-18 EPA 8260 0.23 1.0 ND ND ND 1,4-Dioxane (p-Dioxane) 03-Dec-18 Q,�nD 1.90 2.0 6.2 10.1 ND 1,4-Dichlorobenzene 29-May-07 NR 1 Dry 0.94 J ND 27-Nov-07 NR 1 Dry ND ND m� i�oino� 27-May- 08 0.33 1.0 D 0.64 J n' ND 04-Nov-08 0.33 1.0 Dry 0.96 J ND 01-Jun-09 0.33 1.0 Dry 0.76 J ND 19-Nov-09 0.33 1.0 4.8 4.9 ND NC 2B = 488 µg/L, (05/01/07) 14-Jun-10 0.33 1.0 ND 0.63 J ND 29-Nov-10 0.33 1.0 0.78 J ND ND 31-May-11 0.33 1.0 ND 0.62 J ND 19-Dec-11 0.33 1.0 Dry 0.68 J ND 29-May-12 0.33 1.0 Dry 0.58 J ND 03-Dec-12 0.33 1.0 Dry 0.51 J ND 10-Jun-13 0.33 1.0 ND ND ND 28-Oct-13 0.33 1.0 ND 0.55 J ND 05-May-14 EPA 8260 0.33 1.0 ND 0.55 J ND 20-Oct-14 EPA 8260 0.33 1.0 ND 0.64 J ND 18-May-15 EPA 8260 0.33 1.0 Dry 0.57 J ND 07-Dec-15 EPA 6010 0.33 1.0 Dry 0.44 J ND 02-May-16 EPA 8260 0.33 1.0 Dry 0.43 J ND 12-Dec-16 EPA 8260 0.33 1.0 Dry 0.51 J ND 26-Jun-17 EPA 8260 0.33 1.0 Dry ND ND 14-May-18 EPA 8260 0.33 1.0 ND 0.44 J ND 03-Dec-18 EPA 8260 0.33 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 15 of 2l September 2018 TABLE A2-3: Historical Surface Water Constituents alyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks 1,1-Dichloroethane 29-May-07 NR 5 Dry 2.3 J ND 27-Nov-07 NR 5.0 Dry 0.43 J ND gninrr� i��. - o, iw µy�L, ms i�oino� IAI 27-Ma }'- 08 0.32 5.0 D 0.55 J n' ND 04-Nov-08 0.32 5.0 Dry 1.2 J ND O1-Jun-09 0.32 5.0 Dry 0.41 J ND 19-Nov-09 0.32 5.0 0.65 J 2.4 J ND NC 2B = NE µg/L (05/01/07) 14-Jun-10 0.32 5.0 ND 0.34 J ND 29-Nov-10 0.32 5.0 ND ND ND 31-May-11 0.32 5.0 ND 0.42 J ND 19-Dec-11 0.32 5.0 Dry 0.37 J ND 29-May-12 0.32 5.0 Dry ND ND 03-Dec-12 0.32 5.0 Dry ND ND 10-Jun-13 0.32 5.0 ND ND ND 28-Oct-13 0.32 5.0 ND ND ND 05-May-14 EPA 8260 0.32 5.0 ND ND ND 20-Oct-14 EPA 8260 0.32 5.0 ND ND ND 18-May-15 EPA 8260 0.32 5.0 Dry ND ND 07-Dec-15 EPA 8260 0.32 5.0 Dry ND ND 02-May-16 EPA 8260 0.32 5.0 Dry ND ND 12-Dec-16 EPA 8260 0.32 5.0 Dry ND ND 26-Jun-17 EPA 8260 0.32 5.0 Dry ND ND 14-May-18 EPA 8260 0.32 5.0 ND ND ND 03-Dec-18 EPA 8260 0.32 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 16 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks- cis- 1,2-Dichloroethene May-03 NR 5 ND 5.0 ND Jul-03 NR 5 Dry ND ND Nov-03 NR 5 ND ND ND May-04 NR 5 Dry ND ND Nov-04 NR 5 ND ND ND May-05 NR 5 Dry 5.0 ND Resample> Aug-05 NR 5 NS ND NS Nov-05 NR 5 Dry ND ND 23-May-06 NR 5 Dry ND ND O1-Nov-06 NR 5 ND ND ND 29-May-07 NR 5 Dry 6.4 ND 27-Nov-07 NR 5 Dry 10.4 ND ivy, �ninrr� ivy. - �7v µy�L, ms i�oino� 27-Ma}'- 08 0.19 5.0 D 4.2 J n' ND 04-Nov-08 0.19 5.0 Dry 8.3 ND 01-Jun-09 0.19 5.0 Dry 3.9 J ND 19-Nov-09 0.19 5.0 73.8 21.1 0.26 J NC 2B = NE µg/L (05/01/07) 14-Jun-10 0.19 5.0 ND 3.2 J ND 29-Nov-10 0.19 5.0 3.6 J ND ND 31-May-11 0.19 5.0 ND 3.5 J ND 19-Dec-11 0.19 5.0 Dry 3.4 J ND 29-May-12 0.19 5.0 Dry 2.5 J ND 03-Dec-12 0.19 5.0 Dry 2.5 J ND 10-Jun-13 0.19 5.0 ND ND ND 28-Oct-13 0.19 5.0 ND 2.3 J ND 05-May-14 EPA 8260 0.19 5.0 ND 1.9 J ND 20-Oct-14 EPA 8260 0.19 5.0 ND 2.2 J ND 18-May-15 EPA 8260 0.19 5.0 Dry 1.8 J ND 07-Dec-15 EPA 6010 0.19 5.0 Dry 1.4 J ND 02-May-16 EPA 8260 0.19 5.0 Dry 1.0 J ND 12-Dec-16 EPA 8260 0.19 5.0 Dry 1.9 J ND 26-Jun-17 EPA 8260 0.19 5.0 Dry 1.5 J ND 14-May-18 EPA 8260 0.19 5.0 ND 1.1 J ND 03-Dec-18 EPA 8260 0.19 1.0 ND 0.97 J ND Burke County -East Burke Joyce Engineering Permit No. 12-02 17 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents alyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Methylene Chloride May-97 NR 5 7.0 B ND 6.0 Nov-97 NR 5 ND ND NA May-98 NR 10 ND ND ND Nov-98 NR 5 ND ND ND May-99 NR 5 ND ND ND Oct-99 NR 10 ND ND 21.0 May-00 NR 10 ND ND ND Nov-00 NR 10 Dry ND ND May-Ol NR 10 Dry ND ND Nov-Ol NR 10 Dry ND ND May-02 NR 10 Dry ND ND Nov-02 NR 10 ND ND ND May-03 NR 10 ND ND ND Nov-03 NR 10 ND ND ND May-04 NR 10 Dry ND ND Nov-04 NR 10 ND ND ND May-05 NR 10 Dry ND ND Nov-05 NR 10 Dry ND ND 23-May-06 NR 10 Dry ND ND O1-Nov-06 NR 10 ND ND ND 29-May-07 NR 1 Dry ND ND 27-Nov-07 NR 1 Dry ND ND M., /MrrIA ivi, - 4.0 µg/i, mq /�Q/AQN 27_Ma 08 y- 0.97 2.0 Dry D ND 1.5 J 04-Nov-08 0.97 2.0 Dry ND 2.8 01-Jun-09 0.97 2.0 Dry ND ND 19-Nov-09 0.97 2.0 1.6 J ND ND NC 2B = NE µg/L (05/O1/07) 14-Jun-10 0.97 2.0 ND ND ND 29-Nov-10 0.97 1.0 ND ND ND 31-May-11 0.97 1.0 ND ND ND 19-Dec-11 0.97 1.0 Dry ND 3.3 29-May-12 0.97 1.0 Dry ND ND 03-Dec-12 0.97 1.0 Dry ND ND 10-Jun-13 0.97 1.0 ND ND ND 28-Oct-13 0.97 1.0 ND ND ND 05-May-14 EPA 8260 0.97 1.0 ND ND 2.6 20-Oct-14 EPA 8260 0.97 1.0 ND ND ND 18-May-15 EPA 8260 0.97 1.0 Dry ND 1.3 07-Dec-15 EPA 8260 0.97 1.0 Dry ND 4.8 02-May-16 EPA 8260 0.97 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.97 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.97 1.0 Dry ND 1.3 14-May-18 EPA 8260 0.97 1.0 ND ND ND 03-Dec-18 EPA 8260 0.97 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 18 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 1.5 ND ND NC 2B = 0.07µg/L (5/l/07) Resam 15-Feb-10 0.46 1.0 ND NS ND NC 2B = 0.07 µg/L (05/O1/07) 14-Jun-10 0.46 1.0 ND ND ND 29-Nov-10 0.46 1.0 ND ND ND 31-May-11 0.46 1.0 ND ND ND 19-Dec-11 0.46 1.0 Dry ND 0.77 J 29-May-12 0.46 1.0 Dry ND ND 03-Dec-12 0.46 1.0 Dry ND ND 10-Jun-13 0.46 1.0 ND ND ND 28-Oct-13 0.46 1.0 ND ND ND 05-May-14 EPA 8260 0.46 1.0 ND ND ND 20-Oct-14 EPA 8260 0.46 1.0 ND ND ND 18-May-15 EPA 8260 0.46 1.0 Dry ND ND 07-Dec-15 EPA 6010 0.46 1.0 Dry 0.64 J„ ND 02-May-16 EPA 8260 0.46 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.46 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.46 1.0 Dry ND ND 14-May-18 EPA 8260 0.46 1.0 ND ND ND 03-Dec-18 EPA 8260 0.46 1.0 ND ND ND Trichloroethene 19-Nov-09 0.47 1.0 3.6 1.4 ND C 2B=2.5 µg/L (5/l/07) Resample 15-Feb-10 0.47 1.0 ND NS ND 14-Jun-10 0.47 1.0 ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 31-May-11 0.47 1.0 ND ND ND 19-Dec-11 0.47 1.0 Dry ND ND 29-May-12 0.47 1.0 Dry ND ND 03-Dec-12 0.47 1.0 Dry ND ND 10-Jun-13 0.47 1.0 ND ND ND 28-Oct-13 0.47 1.0 ND ND ND 05-May-14 EPA 8260 0.47 1.0 ND ND ND 20-Oct-14 EPA 8260 0.47 1.0 ND ND ND 18-May-15 EPA 8260 0.47 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.47 1.0 Dry ND ND 02-May-16 EPA 8260 0.47 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.47 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.47 1.0 Dry ND ND 14-May-18 EPA 8260 0.47 1.0 ND ND ND 03-Dec-18 EPA 8260 0.47 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 19 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW-2 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 ND 0.74 J ND NC 2B = 0.025 µg/L (05/01/07) 14-Jun-10 0.62 1.0 ND ND ND 29-Nov-10 0.62 1.0 ND ND ND 31-May-11 0.62 1.0 ND ND ND 19-Dec-11 0.62 1.0 Dry ND ND 29-May-12 0.62 1.0 Dry ND ND 03-Dec-12 0.62 1.0 Dry ND ND 10-Jun-13 0.62 1.0 ND ND ND 28-Oct-13 0.62 1.0 ND ND ND 05-May-14 EPA 8260 0.62 1.0 ND ND ND 20-Oct-14 EPA 8260 0.62 1.0 ND ND ND 18-May-15 EPA 8260 0.62 1.0 Dry ND ND 07-Dec-15 EPA 8260 0.62 1.0 Dry ND ND 02-May-16 EPA 8260 0.62 1.0 Dry ND ND 12-Dec-16 EPA 8260 0.62 1.0 Dry ND ND 26-Jun-17 EPA 8260 0.62 1.0 Dry ND ND 14-May-18 EPA 8260 0.62 1.0 ND ND ND 03-Dec-18 EPA 8260 0.62 1.0 ND ND ND Burke County -East Burke Joyce Engineering Permit No. 12-02 20 of 21 September 2018 TABLE A2-3: Historical Surface Water Constituents Analyte n-ampie Collection Date EPA Method DL RL SW-1 SW- Blanks Xylene (Total) 19-Nov-09 0.66 2.0 8.8 ND ND NC 2B = NE µg/L (05/01/07) 14-Jun-10 0.66 2.0 ND ND ND 29-Nov-10 0.66 2.0 ND ND ND 31-May-11 0.66 2.0 ND ND ND 19-Dec-11 0.66 2.0 Dry ND ND 29-May-12 0.66 2.0 Dry ND ND 03-Dec-12 0.66 5.0 Dry ND ND 10-Jun-13 0.66 5.0 ND ND ND 28-Oct-13 0.66 5.0 ND ND ND 05-May-14 EPA 8260 0.66 5.0 ND ND ND 20-Oct-14 EPA 8260 0.66 5.0 ND ND ND 18-May-15 EPA 8260 0.66 5.0 Dry ND ND 07-Dec-15 EPA 8260 0.66 5.0 Dry ND ND 02-May-16 EPA 8260 0.66 5.0 Dry ND ND 12-Dec-16 EPA 8260 0.66 5.0 Dry ND ND 26-Jun-17 EPA 8260 0.66 5.0 Dry ND ND 14-May-18 EPA 8260 0.66 5.0 ND ND ND 03-Dec-18 EPA 8260 0.66 1.0 ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - 2017; NC PQL for 2018- present) DL = Laboratory method deteciton limt. ND = Not Detected at or above the laboratory RL (prior to Dec. 2006) or the DL (after Dec. 2006). NS = Not sampled. NA = No data available. NR = Not reported. J = Estimated concentration less than the RL but greater than the DL. B = Blank -Qualified (Concentration suspected to reflect laboratory or field contamination). NE = Not established. Dry = Surface water point was considered to be dry and no sample collected. Values above the NC 2B are bold. Surface water is classified as Water Supply IV - Highly Developed, Primary Rec., Critical Area. Burke County -East Burke Joyce Engineering Permit No. 12-02 21 of 21 September 2018 TABLE A24: Historical Groundwater Field Parameters Parame:t:e:r= Collection Date MW-1 MW-2 MW-3 AMW-1 Well Depth [ft] 1 50.55 71.05 32.50 7.30 Conductivity 10-Jun-13 123.0 275.0 299 149.1 (at 25c) [mS/cm] 28-Oct-13 90.1 164.5 228.2 126.2 5-May-14 94.7 209.9 234.1 123.7 20-Oct-14 119.5 186.0 254 189 18-May-15 117.0 250.0 264 135 7-Dec-15 133.0 274.0 287 170 2-May-16 86.0 177.2 241 125.4 12-Dec-16 124.5 254.0 265 176.3 26-Jun-17 126.0 228.0 268 182.3 14-Dec-17 140.0 272.0 283 200 14-May-18 123.0 275.0 299 168 3-Dec-18 96.2 187.6 244.8 124.5 pH [standard units] 10-Jun-13 5.97 5.88 5.75 5.64 28-Oct-13 5.18 5.4 5.53 5.85 5-May-14 5.53 5.53 5.61 5.61 20-Oct-14 4.69 5.39 5.49 6.85 18-May-15 5.05 5.55 5.39 6.09 7-Dec-15 5.22 5.57 5.46 6.29 2-May-16 4.79 5.08 5.15 5.55 12-Dec-16 5.46 5.84 5.6 5.94 26-Jun-17 5.51 5.24 5.18 5.61 14-Dec-17 5.54 5.87 5.73 5.95 14-May-18 5.97 5.88 5.75 6.19 3-Dec-18 5.57 5.7 6.03 5.38 Temperature [°C] 10-Jun-13 18.7 17.6 17.5 15.4 28-Oct-13 16.8 15.9 16 15.1 5-May-14 18.1 17.9 15.7 13.6 20-Oct-14 16.0 15.3 15.3 16.7 18-May-15 17.9 17.3 16.1 18 7-Dec-15 15.4 14.9 15.9 13.9 2-May-16 17.4 17.2 16.1 15.7 12-Dec-16 16.0 15.6 15.9 12.3 26-Jun-17 17.5 16.6 15.8 18.6 14-Dec-17 17.1 14.7 13.7 10.9 14-May-18 18.7 17.6 17.5 18.2 3-Dec-18 15.1 15.5 16.0 12.5 Burke County -East Burke Joyce Engineering Permit No. 12-02 1 of 2 TABLE A24: Historical Groundwater Field Parameters Parameter Collection Date MW-1 MW-2 MW-3 AMW-1 Turbidity [NTU] 10-Jun-13 0.92 0.99 4.58 9.8 28-Oct-13 5.11 3.0 4.38 10.11 5-May-14 6.15 25.30 12.33 21.8 20-Oct-14 17.20 18.40 3.49 20.5 18-May-15 6.95 11.00 3.88 6.29 7-Dec-15 4.29 26.20 6.75 7.26 2-May-16 6.63 15.11 14.56 14.23 12-Dec-16 2.32 2.29 5.81 6.49 26-Jun-17 4.07 4.57 11.8 8.67 14-Dec-17 12.75 8.41 15.71 7.09 14-May-18 0.92 0.99 4.58 0.96 3-Dec-18 5.41 8.26 5.98 15.5 C°= degrees Centigrade NOTES: S.U.= Standard Units µS/cm= microsemens per centimeter NTU= Nephelometric Turbidity Units ft= Feet Burke County -East Burke Joyce Engineering Permit No. 12-02 2 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 pH [standard units] 10-Jun-13 6.45 6.78 28-Oct-13 6.31 6.09 5-May-14 6.29 5.5 20-Oct-14 5.84 6.97 18-May-15 - 6.07 7-Dec-15 - 6.1 2-May-16 - 5.38 12-Dec-16 - 6.22 26-Jun-17 - 5.04 14-Dec-17 6.32 5.9 14-May-18 7.43 6.48 3-Dec-18 6.55 6.16 Temperature [°C] 10-Jun-13 18.3 19.5 28-Oct-13 13.8 13.7 5-May-14 15.2 14.6 20-Oct-14 14 14.2 18-May-15 - 17.7 7-Dec-15 - 10.4 2-May-16 - 16.2 12-Dec-16 - 8.5 26-Jun-17 - 17.6 14-Dec-17 8.9 9.5 14-May-18 18.8 18.4 3-Dec-18 12.6 12 Turbidity [NTU] 10-Jun-13 16.8 32.7 28-Oct-13 15.21 12.94 5-May-14 9.05 10.57 20-Oct-14 7.18 19.2 18-May-15 - 6.19 7-Dec-15 - 6.27 2-May-16 - 11.89 12-Dec-16 - 13.61 26-Jun-17 - 8.95 14-Dec-17 19.06 10.15 14-May-18 0 0 3-Dec-18 13.9 47.6 Conductivity 10-Jun-13 31.5 115.9 (at 25c) [mS/cm] 28-Oct-13 27.5 89.7 5-May-14 26.5 116.1 20-Oct-14 44.2 49.7 18-May-15 - 131 7-Dec-15 - 171 2-May-16 - 112.4 12-Dec-16 - 168.4 26-Jun-17 - 169.8 14-Dec-17 362 300 14-May-18 95 153 3-Dec-18 129 139 NOTES: C°= degrees Centigrade S.U.= Standard Units µS/cm= microsemens per centimeter NTU= Nephelometric Turbidity Units ft= Feet - = Dry/Could not sample Burke County -East Burke Joyce Engineering Permit No. 12-02 1 of 1 September 2018