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HomeMy WebLinkAbout1201_Burke_Kirksey_MSWLF_GW_FID1287520_20190401461LI I ` E1\JGINEEF11"(7= April 1, 2019 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 2211 W. Meadowview Rd., #101 Greensboro, NC 27409 tel: 336/323-0092 fax: 3361323-0093 www.JoyceEngineering.com RE: December 2018 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 JOYCE Project No. 2181871.03 Dear Ms. Drummond: Please find the attached December 2018 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the December 2018 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the December 2018 monitoring event. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me or Gretta Eller at (336) 323-0092 if you have any questions regarding this report. Sincerely, JOYCE ENGINEERING Van Burbach, Ph.D., P.G. Sr. Technical Consultant Copy: Miles Champion — Burke County pENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Joyce Engineering, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@joyceengineering.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. - Kirksey Dr. Landfill Kirksey Drive 12-01 .0500 December 14, 2018 Morganton, NC February 8, 2018 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., P.G. Technical Consultant (336) 323-0092 a Code) Telephone Number 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Affix NC Licensed/ Professional Geologist Seal r�010,� CARO���� JP49 Revised 6/2009 PREPARED FOR: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. Box 1486 MORGANTON, NORTH CAROLINA 28680 KIRKSEY DRIVE LANDFILL PERMIT No.12-01 DECEMBER 2018 SEMIANNUAL WATER QUALITY MONITORING REPORT APRIL 2019 PREPARED BY: EIVG1fUEEl4!!VG 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAx: (336) 323-0093 JOYCE PROJECT No. 2181871.03 December 2018 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION..............................................................................................................1 1.1 Site Information.........................................................................................................1 1.2 Site Geology...............................................................................................................1 1.3 Regulatory Status........................................................................................................2 2.0 FACILITY MONITORING PROGRAM.......................................................................2 2.1 Groundwater Monitoring Program............................................................................2 2.2 Surface Water Monitoring Program...........................................................................2 3.0 DECEMBER 2018 SEMIANNUAL SAMPLING EVENT............................................3 3.1 Field Work..................................................................................................................3 3.2 Laboratory Analysis and JOYCE Quality Control.....................................................4 4.0 HYDROGEOLOGY..........................................................................................................5 5.0 DATA ANALYSIS.............................................................................................................6 5.1 Analytical Results and Comparisons to Standards.....................................................6 5.1.1 Groundwater................................................................................................................................ 6 5.1.2 Surface Water.............................................................................................................................. 6 5.1.3 Resample Event............................................................................................................................ 6 6.0 CONCLUSION..................................................................................................................7 7.0 REFERENCES...................................................................................................................7 Burke County - Kirksey Drive Landfill, Permit No. 12-01 Joyce Engineering December 2018 Semiannual Water Quality Monitoring Report April 2019 i Tables Figure December 2048 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Table 1 December 2018 Groundwater Elevations Table 2 December 2018 Estimated Hydraulic Gradients and Velocities Table 3 December 2018 Detections Table 4 December 2018 Exceedances Table 5 December 2018 Field Parameters Figure 1 Drawing Drawing 1 Appendices Appendix 1 Appendix 2 Table A2-1 Table A2-2 Table A2-3 Table A2-4 Table A2-5 Site Location Map Groundwater Potentiometric Surface Map Laboratory Analytical Reports and Field Logs Historical Data Historical Groundwater Elevations Historical Groundwater Constituents Historical Groundwater Field Parameters Historical Surface Water Constituents Historical Surface Water Field Parameters December 2018 Semiannual Water Quality Monitoring Report Burke County - Kirksey Drive Landfill, Permit No. 12-01 Joyce Engineering April 2019 11 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01 is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (graywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 1 oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County Monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix I), with the exception of well MW-1 which is damaged and unable to be monitored. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW16D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 DECEMBER 2018 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On December 3rd and 4th, 2018, personnel from JOYCE visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for replacement. Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network except for well MW-1 prior to purging. Groundwater elevations for the December 2018 monitoring event can be found in Table 1. A resampling event was conducted on February 8, 2019, for monitoring well MW-4. A detailed discussion of the resampling event will follow. Monitoring wells were purged using disposable bailers. Measurements of temperature, pH, specific conductivity, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and after sampling. Field measurements are summarized in Table 2. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a laboratory -provided cooler. Analytical reports, chain of custody documents and field sampling logs are provided in Appendix 1. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the December 2018 monitoring event. The surface water samples were collected directly from stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample - induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity and recorded in the site log book. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 3 Immediately after sample collection, the samples were placed on ice in a laboratory - provided cooler. Analytical reports, chains -of -custody, and field sampling logs are provided in Appendix 1. On February 8, 2019, personnel from Joyce Engineering (JOYCE) were on -site to collect a detection verification sample from monitoring well MW-4. This sample was collected to confirm the exceedance of vanadium in MW-4. Measurements of temperature, pH, specific conductivity, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and after sampling. Groundwater samples from the monitoring well were collected directly from the disposable bailer in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the sample was placed on ice in a laboratory -provided cooler. Analytical reports, chain of custody documents and field sampling logs for the resampling event are provided in Appendix 1. 3.2 Laboratory Analysis and JOYCE Quality Control The December 2018 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. JOYCE requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory on December 5th, 2018, in good condition, properly preserved, at proper temperature, and within analysis hold times. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by JOYCE personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only. Upon receipt of the laboratory data package, the data was reviewed by JOYCE personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC 2L), Solid Waste Section Groundwater Protection Standards (GWPS), and/or 15A NCAC 2B Surface Water Standards (NC 213); and • Detections that are above historical levels. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of alluvium, residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in December 2018, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the December 2018 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.0498 to 0.0787, with an average of approximately 0.0642. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = Ki/ne where V = average linear velocity, K = hydraulic conductivity, i = horizontal hydraulic gradient and ne = effective porosity. The mean of hydraulic conductivities from slug - tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of n = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 394 to 465 ft/year, with an average flow velocity of approximately 429.5 ft/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplified assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 5 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the December 2018 sampling event are listed in Table 3. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a "J" are detected below the reporting limit and are considered estimates. Bold values indicate concentrations above their respective NC 2L or GWPS and can be found in Table 4. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2). Barium, cobalt, vanadium, benzene, tetrachloroethane, trichloroethane, vinyl chloride, 1,4-dichlorobenzene, and 1,4-dioxane (p-dioxane) were all detected at quantified concentrations in exceedance of their respective NC 2L standard or GWPS in one or more of the monitoring wells; however, the vanadium exceedance was refuted by a resampling event. In general, these detections are consistent with historical data for the site. This event was the first time 1,4-dioxane was a required analyte, so these are first- time exceedances. 5.1.2 Surface Water Inorganic and organic constituents detected in the surface water during the December 2018 sampling event are listed in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4). All concentrations are reported in micrograms per liter (µg/L). The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC 213 standards or NC Protective Values for class WS-IV waters during this sampling event except 1,4-dioxane. Inorganic constituents barium, chromium, cobalt, nickel, thallium, and zinc were detected at one or more of the surface water sampling locations, but not above the NC 2B surface water standards or the North Carolina Protective Value. 1,4-dioxane (p-dioxane) was detected in the surface water sample for SW-3 in exceedance of the NC Protective Value. 5.1.3 Resampling Event As stated in section 3.1, a resampling event was conducted on February 8, 2019 on monitoring well MW-4. This sample was collected to confirm the presence of vanadium in MW-4, which was in exceedance of its respective GWPS during the December 2018 sampling event. Based on the analytical results of the resampling event, the initial exceedance was refuted. December 2018 Semiannual Water Quality Monitoring Report Joyce Engineering Burke County - Kirksey Drive Landfill, Permit No. 12-01 April 2019 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is scheduled for May 2019. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte lx2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte lx2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte lx2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. December 2018 Semiannual Water Quality Monitoring Report Burke County - Kirksey Drive Landfill, Permit No. 12-01 Joyce Engineering April 2019 7 Tables Table 1 December 2018 Groundwater Elevations Table 2 December 2018 Estimated Hydraulic Gradients and Velocities Table 3 December 2018 Detections Table 4 December 2018 Exceedances Table 5 December 2018 Field Parameters TABLE 1: December 2018 Groundwater Elevations Location TOC Elevation (ft AMSL) Depth to Groundwater (ft BTOC) Lithology Well Depth (ft BTOC) Groundwater Elevation (ft AMSL) MW-1 1119.82 20.90 Saprolite 35.65 1098.92 MW-2 1077.23 26.78 Saprolite 45.70 1050.45 MW-3S 1022.76 5.83 Bedrock 26.69 1016.93 MW-31) 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 20.29 Saprolite 29.50 1034.70 MW-5 1137.43 39.29 Saprolite 49.80 1098.14 MW-6S 1065.00 9.91 Bedrock 25.00 1055.09 MW-61) 1065.00 11.66 Saprolite 60.00 1053.34 Notes: TOC = Top of casing ft = feet BTOC = Below TOC BGS = Below ground surface AMSL = Above mean sea level Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 TABLE 2: December 2018 Hydraulic Gradients and Velocities December 3, 2018 GRADIENT FLOW LINE GROUNDWATER HORIZONTAL HYDRAULIC EFFECTIVE LINEAR FLOW CONDUCTIVITY VELOCITY CALCULATION LENGTH ELEVATION GRADIENT POROSITY DIRECTION K V SEGMENT (ft) (ft) i n (ft/day (ft/ear) 1090 11 900 NE 0.0778 3.28E+00 0.20 465 1020 1090 12 760 E 0.0658 3.28E+00 0.20 394 1040 AVERAGE: 0.0718 AVERAGE: 429.5 Notes: The mean ofKestimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1). Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 TABLE 3: December 2018 Detections Parameter MDL MRL NC 2L/ GWPS* GW Downgradient MW-2 MW-3S MW-31) MW-4 MW-4* MW-5 MW-6S MW-61) Barium 2.5 5 700 1160 507 205 82.0 --- 27.1 42.6 12.8 Cadmium 0.5 1 2 2.0 0.78 J ND ND --- ND ND ND Chromium 2.5 5 10 ND ND ND 3.4 J --- ND ND ND Cobalt 2.5 5 1 * 120 17.3 2.6 J ND --- ND ND ND Lead 2.5 5 15 ND ND ND ND --- ND ND ND Nickel 2.5 5 100 17.2 4.3 J 26.3 ND --- ND ND ND Vanadium 2.5 5 0.3 ND 3.0 J ND 6.0 ND ND ND ND Zinc 5 10 1,000 ND 12.7 ND 5.3 J --- ND ND ND Arsenic 5 10 10 ND 5.1 J ND ND --- ND ND ND Acetone 10 25 6,000 ND ND ND ND --- ND ND ND Benzene 0.25 1 1 7.5 3.8 1.3 ND --- ND ND ND Chlorobenzene 0.23 1 50 23.7 34.4 7.1 ND --- ND ND ND Chloroethane 0.54 1 3,000 ND ND ND ND --- ND ND ND Ethylbenzene 0.3 1 600 10.7 ND ND ND --- ND ND ND Tetrachloroethene 0.46 1 0.7 ND ND 6.6 1.2 --- ND ND ND Toluene 0.26 1 600 0.911 ND ND ND --- ND ND ND Trichloroethene 0.47 1 3 ND ND 4.7 0.66 J --- ND ND ND Vinyl Chloride 0.62 1 0.03 ND ND 1.2 ND --- ND ND ND Xylene (Total) 0.66 1 500 21.4 28.0 ND ND --- ND ND ND 1,1-Dichloroethane 0.32 1 6 0.37 J 0.46 J 4.0 1.1 --- ND ND ND 1,2-Dichlorobenzene 0.3 1 20 2.2 0.91 J ND ND --- ND ND ND 1,2-Dichloropropane 0.27 1 0.6 ND ND 0.94 J ND --- ND ND ND 1,4-Dichlorobenzene 0.33 1 6 39.9 14.8 ND ND --- ND ND ND 2-Butanone (MEK) 0.96 5 4,000 ND ND ND ND --- ND ND ND 2-Hexanone 0.46 5 280 ND ND ND ND --- ND ND ND 4-Methyl-2 pentanone (MIBK) 0.33 5 560* 2.7 J ND ND ND --- ND ND ND 1,4-Dioxane (p-Dioxane) 1.9 2 3 219 56.3 127 ND --- ND ND 4.0 cis-1,2-Dichloroethene 1 0.19 1 1 1 70 1 0.3 J ND 10.8 5.8 --- ND ND ND Surface Monitoring Point Constituent NC 2B MDL MRL Result SW-1 Barium 21000^ 2.5 5 33.1 SW-2 Barium 21000^ 2.5 5 32.0 SW-3 Barium 21000^ 2.5 5 267 SW-3 Chromium 121.58 2.5 5 2.8 J SW-3 Cobalt 3^ 2.5 5 3.6 J SW-3 Nickel 86.71 2.5 5 5.9 SW-3 Zinc 197.14 5 10 7.4 J SW-3 Thallium 0.24^^ 0.06 0.1 0.077 J 1 4-Dioxane SW-3 0.35^^ 1.9 2 10.5 -Dioxane) Note: NC 2B values for Chromium, Nickel, and Zinc were calculated based on hardness results Notes: All results are in micrograms per liter (µg/L). J = Estimated concentration below the SWSL. MDL = Method Detection Limit MRL = Method Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 *GWPS = NC Solid Waste Section Groundwater Protection Standard NC2B = NC Surface Water Standard from 15A NCAC 2B Surface water has been classified as Water Supply IV Bold results are exceedances of the applicable standards. ^ = NC Protective Value ^^ = EPA NRWQC (Naturally Recommended Water Quality Criteria) MW-4* = Resample Burke County, Kirksey Drive Landfill Permit No. 12-01 Joyce Engineering TABLE 4: December 2018 Exceedances Parameter MDL MRL NC 2L /GWPS* GW Downgradient MW-2 MW-3S MW-3D MW-4 I MW-4* MW-5 MW-6S MW-6D Barium 2.5 5 700 1160 -- -- -- -- -- -- -- Cobalt 2.5 5 1* 120 17.3 -- -- -- -- -- -- Vanadium 2.5 5 0.3 -- -- -- 6 ND -- -- -- Benzene 0.25 1 1 7.5 3.8 1.3 -- -- -- -- -- Tetrachloroethene 0.46 1 0.7 -- -- 6.6 1.2 -- -- -- -- Trichloroethene 0.47 1 3 -- -- 4.7 -- -- -- -- -- Vinyl Chloride 0.62 1 0.03 -- -- 1.2 -- -- -- -- -- 1,4-Dichlorobenzene 0.33 1 6 39.9 14.8 -- -- -- -- -- -- 1,4-Dioxane (p-Dioxane) 9.5 10 3 219 56.3 127 -- -- -- -- 4 Surface Water Parameter MDL MRL NC2B SW-3 1,4-Dioxane (p-Dioxane) 1.9 2 0.35 10.5 Notes: All results are in micrograms per liter (µg/L). MDL = Method Detection Limit MRL = Method Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 *GWPS = NCDEQ Solid Waste Section Groundwater Protection Standards MW-4* = Resample NC2B = NC Surface Water Standard from 15A NCAC 2B Bold results are exceedances of the applicable standards. Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 TABLE 5: December 2018 Sampling Event Field Parameters Parameter Units Collect Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 I MW-3S I MW-31) I MW-4 I MW-4* I MW-5 I MW-6S I MW-61) SW-1 SW-2 I SW-3 Well Depth Ft. -- 50.55 45.70 26.69 78.40 29.50 29.50 49.80 25.00 60.00 -- -- -- H S.U. 12/4/2018 -- 5.99 6.55 6.55 6.54 5.64 8.07 7.21 6.15 7.43 7.36 6.78 Temperature °C 12/4/2018 15.3 14.6 13.9 14 15.2 14 13.3 14.5 11.5 11.7 6.3 Conductivity µS/cm 12/4/2018 1604 776 661 70 55.9 48 64.3 92.8 102.9 90.6 395.4 Turbidity NTU 12/4/2018 8.39 29.4 4.31 31.00 7.96 10.3 6.71 4.17 12.30 20.60 7.37 Static Water Level Ft. 12/4/2018 26.78 5.83 0.00 20.29 17.62 39.29 9.91 11.66 -- -- -- Notes: °C = degrees Centigrade S.U. = Standard Units µS/cm = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet * = Resample Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Figure Figure 1 Site Location Map � has Yiivar 10 O 4 D 00 co soh b s �'Ler O ��zoo U 18- -r B64 us O r n� SOURCE: U.S.G.S. TOPOGRAPHIC MAP FOR NORTH MORGANTON, NC. n BUS `e o 70 ^��C 2211 WEST MEADOWVIEW ROAD SCALE PROJECT NO. FIGURE N0. 1 Y ��=��� PHONN...)O.NC,2407 1"=2000' 277 KIRKSEY DRIVE LANDFILL ENGINEERING 323-0092 02016 Joyce Engineering, lnc. SITE LOCATION MAP All nghte reservetl. J Drawing Drawing 1 Groundwater Potentiometric Surface Contour Map / LIMITS OF WASTE (TYP) I / — — — — — \ LIMITS OF WASTE p/ ( \ —� \ - — -MW-3S / / / /1050.98 1016.93 / \ \ I I l I o� /' � \ � I l \ r I moo\ �O�Z0 ( / / 100, N5r -4 10000, \ \ / 10339- Zz — 1 Q&0-6S � / • 1055.09 \ 00� �� / ` 10 MW-6D Mw1 080 1070 w w 0 0 0 w z z 0 o m - cl wv v w z z ❑ w w > = m ivy Li ° ^ 111 w N O � U o W ZM Z ❑I wo. wz �0 Z w _ W �� oa — _ / / \0000' 109 U / \ GRAPHIC SCALE z � I D _---` - 0814 / / 0 I150 300 600 J� 07 \ \ — / \ (FEET) J N 2i co ------T /� w0 Z Fw NOTES � } z m EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING 20' TOPOGRAPHIC CONTOUR GROUNDWATER SURFACE CONTOUR [FEET 1080 — — — — — ABOVE MEAN SEA LEVEL (AMSL)] PROPERTY LINE GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT OSEGMENT USED FOR GRADIENT CALCULATION 1 0 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. w Z d 0 U c� p d w 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 20 FEET. U w 0 EXISTING ROAD Y Y L 3. APPROXIMATE LIMITS OF WASTE STATIC WATER LEVELS WERE MEASURED ON DECEMBER 3, 2018. D/ Q a W � N CENTERLINE OF STREAM 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION D BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, O o - MW-5 COMPLIANCE WELL LOCATION AND IDENTIFICATION TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. 0 PROJECT NO. ELEV WITH STATIC WATER LEVEL ELEVATION (FEET AMSL) FLOW PATH LENGTH 277 Y SW-2 SURFACE MONITORING POINT LOCATION AND IDENTIFICATION 900 LF O Z� SCALE o AS NOTED w O760 LF - DRAWING NO. V 2 1 m Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Appendix I Laboratory Analytical Reports and Field Logs aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 28, 2018 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This revision was issued on 12/28/18 to add hardness to the surface water samples, per client request. If you have any questions concerning this report, please feel free to contact me. Sincerely, Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering �pQ ACrfFO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, 9e0 without the written consent of Pace Analytical Services, LLC. Page 1 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 47 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Lab ID Sample ID Matrix Date Collected Date Received 92409790001 1201-MW2 Water 12/03/1816:15 12/05/18 14:05 92409790002 1201-MW3S Water 12/03/1816:55 12/05/18 14:05 92409790003 1201-MW3D Water 12/03/1817:49 12/05/18 14:05 92409790004 1201-MW4 Water 12/04/18 08:42 12/05/18 14:05 92409790005 1201-MW5 Water 12/04/18 08:13 12/05/18 14:05 92409790006 1201-MW6S Water 12/04/18 08:19 12/05/18 14:05 92409790007 1201-MW6D Water 12/03/1815:19 12/05/18 14:05 92409790008 1201-SW1 Water 12/03/1817:35 12/05/18 14:05 92409790009 1201-SW2 Water 12/03/1817:12 12/05/18 14:05 92409790010 1201-SW3 Water 12/04/18 08:55 12/05/18 14:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co. Kirksey Dr Closed LF 92409790 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92409790001 1201-MW2 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790002 1201-MW3S EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790003 1201-MW3D EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790004 1201-MW4 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790005 1201-MW5 EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790006 1201-MW6S EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790007 1201-MW6D EPA 6010D IDS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790008 1201-SW1 EPA 6010D IDS 15 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790009 1201-SW2 EPA 6010D IDS 15 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409790010 1201-SW3 EPA 6010D IDS 15 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co. Kirksey Dr Closed LF 92409790 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92409790001 1201-MW2 EPA 6010D Barium 1160 ug/L 5.0 12/15/18 19:11 EPA 6010D Cadmium 2.0 ug/L 1.0 12/15/18 19:11 EPA 6010D Cobalt 120 ug/L 5.0 12/15/18 19:11 EPA 6010D Nickel 17.2 ug/L 5.0 12/15/18 19:11 EPA 8260B Benzene 7.5 ug/L 1.0 12/07/18 22:01 EPA 8260B Chlorobenzene 23.7 ug/L 1.0 12/07/18 22:01 EPA 8260B 1,2-Dichlorobenzene 2.2 ug/L 1.0 12/07/18 22:01 EPA 8260B 1,4-Dichlorobenzene 39.9 ug/L 1.0 12/07/18 22:01 EPA 8260B 1,1-Dichloroethane 0.37J ug/L 1.0 12/07/18 22:01 EPA 8260B cis-1,2-Dichloroethene 0.30J ug/L 1.0 12/07/18 22:01 EPA 8260B Ethylbenzene 10.7 ug/L 1.0 12/07/18 22:01 EPA 8260B 4-Methyl-2-pentanone (MIBK) 2.7J ug/L 5.0 12/07/18 22:01 EPA 8260B Toluene 0.91 J ug/L 1.0 12/07/18 22:01 EPA 8260B Xylene (Total) 21.4 ug/L 1.0 12/07/18 22:01 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 219 ug/L 10.0 12/13/18 18:15 92409790002 1201-MW3S EPA 6010D Arsenic 5.1 J ug/L 10.0 12/15/18 19:29 EPA 6010D Barium 507 ug/L 5.0 12/15/18 19:29 EPA 6010D Cadmium 0.78J ug/L 1.0 12/15/18 19:29 EPA 6010D Cobalt 17.3 ug/L 5.0 12/15/18 19:29 EPA 6010D Nickel 4.3J ug/L 5.0 12/15/18 19:29 EPA 6010D Vanadium 3.OJ ug/L 5.0 12/15/18 19:29 EPA 6010D Zinc 12.7 ug/L 10.0 12/15/18 19:29 EPA 8260B Benzene 3.8 ug/L 1.0 12/07/18 22:18 EPA 8260B Chlorobenzene 34.4 ug/L 1.0 12/07/18 22:18 EPA 8260B 1,2-Dichlorobenzene 0.91 J ug/L 1.0 12/07/18 22:18 EPA 8260B 1,4-Dichlorobenzene 14.8 ug/L 1.0 12/07/18 22:18 EPA 8260B 1,1-Dichloroethane 0.46J ug/L 1.0 12/07/18 22:18 EPA 8260B Xylene (Total) 28.0 ug/L 1.0 12/07/18 22:18 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 56.3 ug/L 2.0 12/07/18 17:14 92409790003 1201-MW3D EPA 6010D Barium 205 ug/L 5.0 12/15/18 19:32 EPA 6010D Cobalt 2.6J ug/L 5.0 12/15/18 19:32 EPA 6010D Nickel 26.3 ug/L 5.0 12/15/18 19:32 EPA 8260B Benzene 1.3 ug/L 1.0 12/07/18 22:35 EPA 8260B Chlorobenzene 7.1 ug/L 1.0 12/07/18 22:35 EPA 8260B 1,1-Dichloroethane 4.0 ug/L 1.0 12/07/18 22:35 EPA 8260B cis-1,2-Dichloroethene 10.8 ug/L 1.0 12/07/18 22:35 EPA 8260B 1,2-Dichloropropane 0.94J ug/L 1.0 12/07/18 22:35 EPA 8260B Tetrachloroethene 6.6 ug/L 1.0 12/07/18 22:35 EPA 8260B Trichloroethene 4.7 ug/L 1.0 12/07/18 22:35 EPA 8260B Vinyl chloride 1.2 ug/L 1.0 12/07/18 22:35 EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 127 ug/L 5.0 12/13/18 18:35 92409790004 1201-MW4 EPA 6010D Barium 82.0 ug/L 5.0 12/15/18 19:35 EPA 6010D Chromium 3AJ ug/L 5.0 12/15/18 19:35 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Lab Sample ID Method Client Sample ID Parameters 92409790004 1201-MW4 EPA 601 OD Vanadium EPA 601 OD Zinc EPA 8260B 1,1-Dichloroethane EPA 8260B cis-1,2-Dichloroethene EPA 8260B Tetrachloroethene EPA 8260B Trichloroethene 92409790005 1201-MW5 EPA 601 OD Barium 92409790006 1201-MW6S EPA 601 OD Barium 92409790007 1201-MW6D EPA 601 OD Barium EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) 92409790008 1201-SW1 EPA 601 OD Barium EPA 601 OD Hardness, Total(SM 2340B) 92409790009 1201-SW2 EPA 601 OD Barium EPA 601 OD Hardness, Total(SM 2340B) 92409790010 1201-SW3 EPA 601 OD Barium EPA 601 OD Chromium EPA 601 OD Cobalt EPA 601 OD Nickel EPA 601 OD Hardness, Total(SM 2340B) EPA 601 OD Zinc EPA 6020B Thallium EPA 8260B Mod. 1,4-Dioxane (p-Dioxane) Result Units Report Limit Analyzed 6.0 ug/L 5.0 12/15/1819:35 5.3J ug/L 10.0 12/15/1819:35 1.1 ug/L 1.0 12/13/18 06:38 5.8 ug/L 1.0 12/13/18 06:38 1.2 ug/L 1.0 12/13/18 06:38 0.66J ug/L 1.0 12/13/18 06:38 27.1 ug/L 5.0 12/15/1819:38 42.6 ug/L 5.0 12/15/1819:41 12.8 ug/L 5.0 12/15/1819:44 4.0 ug/L 2.0 12/07/1817:33 33.1 ug/L 5.0 12/15/1819:47 24700 ug/L 662 12/15/1819:47 32.0 ug/L 5.0 12/15/1819:50 24300 ug/L 662 12/15/1819:50 267 ug/L 5.0 12/15/1819:53 2.8J ug/L 5.0 12/15/1819:53 3.6J ug/L 5.0 12/15/1819:53 5.9 ug/L 5.0 12/15/1819:53 183000 ug/L 662 12/15/1819:53 7AJ ug/L 10.0 12/15/1819:53 0.077J ug/L 0.10 12/14/18 23:50 10.5 ug/L 2.0 12/13/18 20:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Qualifiers Page 7 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW2 Lab ID: 92409790001 Collected: 12/03/18 16:15 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:11 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:11 7440-38-2 Barium 1160 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:11 7440-41-7 Cadmium 2.0 ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:11 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-47-3 Cobalt 120 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7439-92-1 Nickel 17.2 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:11 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:11 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:11 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:27 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/07/18 22:01 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/07/18 22:01 107-13-1 Benzene 7.5 ug/L 1.0 0.25 1 12/07/18 22:01 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/07/18 22:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/07/18 22:01 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/07/18 22:01 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/07/18 22:01 74-83-9 L1 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/07/18 22:01 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/07/18 22:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/07/18 22:01 56-23-5 Chlorobenzene 23.7 ug/L 1.0 0.23 1 12/07/18 22:01 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/07/18 22:01 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/07/18 22:01 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/07/18 22:01 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/07/18 22:01 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/07/18 22:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/07/18 22:01 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/07/18 22:01 74-95-3 1,2-Dichlorobenzene 2.2 ug/L 1.0 0.30 1 12/07/18 22:01 95-50-1 1,4-Dichlorobenzene 39.9 ug/L 1.0 0.33 1 12/07/18 22:01 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/07/18 22:01 110-57-6 1,1-Dichloroethane 0.37J ug/L 1.0 0.32 1 12/07/18 22:01 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/07/18 22:01 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/07/18 22:01 75-35-4 cis-1,2-Dichloroethene 0.30J ug/L 1.0 0.19 1 12/07/18 22:01 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/07/18 22:01 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/07/18 22:01 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW2 Lab ID: 92409790001 Collected: 12/03/18 16:15 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 10.7 ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 2.7J ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.911 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 21.4 ug/L 1.0 96 % 70-130 96 % 70-130 96 % 70-130 Analytical Method: EPA 8260E Mod. 219 ug/L 10.0 97 % 50-150 112 % 50-150 0.13 1 12/07/18 22:01 10061-01-5 0.26 1 12/07/18 22:01 10061-02-6 0.30 1 12/07/18 22:01 100-41-4 0.46 1 12/07/18 22:01 591-78-6 0.32 1 12/07/18 22:01 74-88-4 0.97 1 12/07/18 22:01 75-09-2 0.33 1 12/07/18 22:01 108-10-1 0.26 1 12/07/18 22:01 100-42-5 0.33 1 12/07/18 22:01 630-20-6 0.40 1 12/07/18 22:01 79-34-5 0.46 1 12/07/18 22:01 127-18-4 0.26 1 12/07/18 22:01 108-88-3 0.48 1 12/07/18 22:01 71-55-6 0.29 1 12/07/18 22:01 79-00-5 0.47 1 12/07/18 22:01 79-01-6 0.20 1 12/07/18 22:01 75-69-4 0.41 1 12/07/18 22:01 96-18-4 0.35 1 12/07/18 22:01 108-05-4 0.62 1 12/07/18 22:01 75-01-4 0.66 1 12/07/18 22:01 1330-20-7 1 12/07/18 22:01 460-00-4 1 12/07/18 22:01 17060-07-0 1 12/07/18 22:01 2037-26-5 9.5 5 5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 18:15 123-91-1 12/ 13/ 18 18:15 17060-07-0 12/13/1818:15 2037-26-5 Page 9 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW3S Lab ID: 92409790002 Collected: 12/03/18 16:55 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/28/2018 08:45 AM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:29 7440-36-0 5.1J ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:29 7440-38-2 507 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:29 7440-41-7 0.78J ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:29 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-47-3 17.3 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7439-92-1 4.3J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:29 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-22-4 3.OJ ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:29 7440-62-2 12.7 ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:29 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:29 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/07/18 22:18 67-64-1 ND ug/L 10.0 1.9 1 12/07/18 22:18 107-13-1 3.8 ug/L 1.0 0.25 1 12/07/18 22:18 71-43-2 ND ug/L 1.0 0.17 1 12/07/18 22:18 74-97-5 ND ug/L 1.0 0.18 1 12/07/18 22:18 75-27-4 ND ug/L 1.0 0.26 1 12/07/18 22:18 75-25-2 ND ug/L 2.0 0.29 1 12/07/18 22:18 74-83-9 ND ug/L 5.0 0.96 1 12/07/18 22:18 78-93-3 ND ug/L 2.0 1.2 1 12/07/18 22:18 75-15-0 ND ug/L 1.0 0.25 1 12/07/18 22:18 56-23-5 34.4 ug/L 1.0 0.23 1 12/07/18 22:18 108-90-7 ND ug/L 1.0 0.54 1 12/07/18 22:18 75-00-3 ND ug/L 1.0 0.14 1 12/07/18 22:18 67-66-3 ND ug/L 1.0 0.11 1 12/07/18 22:18 74-87-3 ND ug/L 2.0 2.0 1 12/07/18 22:18 96-12-8 ND ug/L 1.0 0.21 1 12/07/18 22:18 124-48-1 ND ug/L 1.0 0.27 1 12/07/18 22:18 106-93-4 ND ug/L 1.0 0.21 1 12/07/18 22:18 74-95-3 0.911 ug/L 1.0 0.30 1 12/07/18 22:18 95-50-1 14.8 ug/L 1.0 0.33 1 12/07/18 22:18 106-46-7 ND ug/L 1.0 1.0 1 12/07/18 22:18 110-57-6 0.46J ug/L 1.0 0.32 1 12/07/18 22:18 75-34-3 ND ug/L 1.0 0.24 1 12/07/18 22:18 107-06-2 ND ug/L 1.0 0.56 1 12/07/18 22:18 75-35-4 ND ug/L 1.0 0.19 1 12/07/18 22:18 156-59-2 ND ug/L 1.0 0.49 1 12/07/18 22:18 156-60-5 ND ug/L 1.0 0.27 1 12/07/18 22:18 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 10 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW3S Lab ID: 92409790002 Collected: 12/03/18 16:55 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 28.0 ug/L 1.0 95 % 70-130 96 % 70-130 95 % 70-130 Analytical Method: EPA 8260E Mod. 56.3 ug/L 2.0 93 % 50-150 115 % 50-150 0.13 1 12/07/18 22:18 10061-01-5 0.26 1 12/07/18 22:18 10061-02-6 0.30 1 12/07/18 22:18 100-41-4 0.46 1 12/07/18 22:18 591-78-6 0.32 1 12/07/18 22:18 74-88-4 0.97 1 12/07/18 22:18 75-09-2 0.33 1 12/07/18 22:18 108-10-1 0.26 1 12/07/18 22:18 100-42-5 0.33 1 12/07/18 22:18 630-20-6 0.40 1 12/07/18 22:18 79-34-5 0.46 1 12/07/18 22:18 127-18-4 0.26 1 12/07/18 22:18 108-88-3 0.48 1 12/07/18 22:18 71-55-6 0.29 1 12/07/18 22:18 79-00-5 0.47 1 12/07/18 22:18 79-01-6 0.20 1 12/07/18 22:18 75-69-4 0.41 1 12/07/18 22:18 96-18-4 0.35 1 12/07/18 22:18 108-05-4 0.62 1 12/07/18 22:18 75-01-4 0.66 1 12/07/18 22:18 1330-20-7 1 12/07/18 22:18 460-00-4 1 12/07/18 22:18 17060-07-0 1 12/07/18 22:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/18 17:14 123-91-1 12/07/18 17:14 17060-07-0 12/07/18 17:14 2037-26-5 Page 11 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW3D Lab ID: 92409790003 Collected: 12/03/18 17:49 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/28/2018 08:45 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:32 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:32 7440-38-2 205 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:32 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:32 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-47-3 2.6J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7439-92-1 26.3 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:32 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:32 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:32 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:31 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/07/18 22:35 67-64-1 ND ug/L 10.0 1.9 1 12/07/18 22:35 107-13-1 1.3 ug/L 1.0 0.25 1 12/07/18 22:35 71-43-2 ND ug/L 1.0 0.17 1 12/07/18 22:35 74-97-5 ND ug/L 1.0 0.18 1 12/07/18 22:35 75-27-4 ND ug/L 1.0 0.26 1 12/07/18 22:35 75-25-2 ND ug/L 2.0 0.29 1 12/07/18 22:35 74-83-9 ND ug/L 5.0 0.96 1 12/07/18 22:35 78-93-3 ND ug/L 2.0 1.2 1 12/07/18 22:35 75-15-0 ND ug/L 1.0 0.25 1 12/07/18 22:35 56-23-5 7.1 ug/L 1.0 0.23 1 12/07/18 22:35 108-90-7 ND ug/L 1.0 0.54 1 12/07/18 22:35 75-00-3 ND ug/L 1.0 0.14 1 12/07/18 22:35 67-66-3 ND ug/L 1.0 0.11 1 12/07/18 22:35 74-87-3 ND ug/L 2.0 2.0 1 12/07/18 22:35 96-12-8 ND ug/L 1.0 0.21 1 12/07/18 22:35 124-48-1 ND ug/L 1.0 0.27 1 12/07/18 22:35 106-93-4 ND ug/L 1.0 0.21 1 12/07/18 22:35 74-95-3 ND ug/L 1.0 0.30 1 12/07/18 22:35 95-50-1 ND ug/L 1.0 0.33 1 12/07/18 22:35 106-46-7 ND ug/L 1.0 1.0 1 12/07/18 22:35 110-57-6 4.0 ug/L 1.0 0.32 1 12/07/18 22:35 75-34-3 ND ug/L 1.0 0.24 1 12/07/18 22:35 107-06-2 ND ug/L 1.0 0.56 1 12/07/18 22:35 75-35-4 10.8 ug/L 1.0 0.19 1 12/07/18 22:35 156-59-2 ND ug/L 1.0 0.49 1 12/07/18 22:35 156-60-5 0.94J ug/L 1.0 0.27 1 12/07/18 22:35 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 12 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW3D Lab ID: 92409790003 Collected: 12/03/18 17:49 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.6 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 4.7 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 1.2 ug/L 1.0 ND ug/L 1.0 94 % 70-130 96 % 70-130 95 % 70-130 Analytical Method: EPA 8260E Mod 127 ug/L 5.0 102 % 50-150 113 % 50-150 0.13 1 12/07/18 22:35 10061-01-5 0.26 1 12/07/18 22:35 10061-02-6 0.30 1 12/07/18 22:35 100-41-4 0.46 1 12/07/18 22:35 591-78-6 0.32 1 12/07/18 22:35 74-88-4 0.97 1 12/07/18 22:35 75-09-2 0.33 1 12/07/18 22:35 108-10-1 0.26 1 12/07/18 22:35 100-42-5 0.33 1 12/07/18 22:35 630-20-6 0.40 1 12/07/18 22:35 79-34-5 0.46 1 12/07/18 22:35 127-18-4 0.26 1 12/07/18 22:35 108-88-3 0.48 1 12/07/18 22:35 71-55-6 0.29 1 12/07/18 22:35 79-00-5 0.47 1 12/07/18 22:35 79-01-6 0.20 1 12/07/18 22:35 75-69-4 0.41 1 12/07/18 22:35 96-18-4 0.35 1 12/07/18 22:35 108-05-4 0.62 1 12/07/18 22:35 75-01-4 0.66 1 12/07/18 22:35 1330-20-7 1 12/07/18 22:35 460-00-4 1 12/07/18 22:35 17060-07-0 1 12/07/18 22:35 2037-26-5 4.8 2.5 2.5 2.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 18:35 123-91-1 12/ 13/18 18:35 17060-07-0 12/13/1818:35 2037-26-5 Page 13 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW4 Lab ID: 92409790004 Collected: 12/04/18 08:42 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:35 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:35 7440-38-2 Barium 82.0 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:35 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:35 7440-43-9 Chromium 3.4J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:35 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-22-4 Vanadium 6.0 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:35 7440-62-2 Zinc 5.3J ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:35 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:33 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 06:38 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 06:38 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 06:38 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 06:38 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 06:38 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 06:38 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 06:38 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 06:38 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 06:38 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 06:38 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 06:38 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 06:38 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 06:38 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 06:38 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 06:38 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 06:38 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 06:38 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 06:38 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 06:38 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 06:38 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 06:38 110-57-6 1,1-Dichloroethane 1.1 ug/L 1.0 0.32 1 12/13/18 06:38 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 06:38 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 06:38 75-35-4 cis-1,2-Dichloroethene 5.8 ug/L 1.0 0.19 1 12/13/18 06:38 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 06:38 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/13/18 06:38 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW4 Lab ID: 92409790004 Collected: 12/04/18 08:42 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.2 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 0.66J ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 101 % 70-130 89 % 70-130 101 % 70-130 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 102 % 50-150 116 % 50-150 0.13 1 12/13/18 06:38 10061-01-5 0.26 1 12/13/18 06:38 10061-02-6 0.30 1 12/13/18 06:38 100-41-4 0.46 1 12/13/18 06:38 591-78-6 0.32 1 12/13/18 06:38 74-88-4 0.97 1 12/13/18 06:38 75-09-2 0.33 1 12/13/18 06:38 108-10-1 0.26 1 12/13/18 06:38 100-42-5 0.33 1 12/13/18 06:38 630-20-6 0.40 1 12/13/18 06:38 79-34-5 0.46 1 12/13/18 06:38 127-18-4 0.26 1 12/13/18 06:38 108-88-3 0.48 1 12/13/18 06:38 71-55-6 0.29 1 12/13/18 06:38 79-00-5 0.47 1 12/13/18 06:38 79-01-6 0.20 1 12/13/18 06:38 75-69-4 0.41 1 12/13/18 06:38 96-18-4 0.35 1 12/13/18 06:38 108-05-4 0.62 1 12/13/18 06:38 75-01-4 0.66 1 12/13/18 06:38 1330-20-7 1 12/13/18 06:38 460-00-4 1 12/13/18 06:38 17060-07-0 1 12/13/18 06:38 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 19:33 123-91-1 12/13/18 19:33 17060-07-0 12/13/18 19:33 2037-26-5 Page 15 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW5 Lab ID: 92409790005 Collected: 12/04/18 08:13 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:38 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:38 7440-38-2 Barium 27.1 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:38 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:38 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:38 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:38 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:38 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:36 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 06:56 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 06:56 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 06:56 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 06:56 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 06:56 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 06:56 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 06:56 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 06:56 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 06:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 06:56 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 06:56 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 06:56 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 06:56 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 06:56 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 06:56 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 06:56 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 06:56 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 06:56 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 06:56 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 06:56 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 06:56 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 06:56 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 06:56 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 06:56 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 06:56 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 06:56 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/13/18 06:56 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW5 Lab ID: 92409790005 Collected: 12/04/18 08:13 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 103 % 70-130 92 % 70-130 97 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 96 % 50-150 112 % 50-150 0.13 1 12/13/18 06:56 10061-01-5 0.26 1 12/13/18 06:56 10061-02-6 0.30 1 12/13/18 06:56 100-41-4 0.46 1 12/13/18 06:56 591-78-6 0.32 1 12/13/18 06:56 74-88-4 0.97 1 12/13/18 06:56 75-09-2 0.33 1 12/13/18 06:56 108-10-1 0.26 1 12/13/18 06:56 100-42-5 0.33 1 12/13/18 06:56 630-20-6 0.40 1 12/13/18 06:56 79-34-5 0.46 1 12/13/18 06:56 127-18-4 0.26 1 12/13/18 06:56 108-88-3 0.48 1 12/13/18 06:56 71-55-6 0.29 1 12/13/18 06:56 79-00-5 0.47 1 12/13/18 06:56 79-01-6 0.20 1 12/13/18 06:56 75-69-4 0.41 1 12/13/18 06:56 96-18-4 0.35 1 12/13/18 06:56 108-05-4 0.62 1 12/13/18 06:56 75-01-4 0.66 1 12/13/18 06:56 1330-20-7 1 12/13/18 06:56 460-00-4 1 12/13/18 06:56 17060-07-0 1 12/13/18 06:56 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 19:52 123-91-1 12/13/18 19:52 17060-07-0 12/13/18 19:52 2037-26-5 Page 17 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW6S Lab ID: 92409790006 Collected: 12/04/18 08:19 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:41 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:41 7440-38-2 Barium 42.6 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:41 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:41 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:41 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:41 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:41 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:38 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 07:13 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 07:13 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 07:13 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 07:13 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 07:13 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 07:13 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 07:13 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 07:13 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 07:13 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 07:13 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 07:13 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 07:13 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 07:13 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 07:13 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 07:13 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 07:13 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 07:13 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 07:13 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 07:13 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 07:13 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 07:13 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 07:13 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 07:13 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 07:13 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 07:13 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 07:13 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.27 1 12/13/18 07:13 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW6S Lab ID: 92409790006 Collected: 12/04/18 08:19 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 101 % 70-130 91 % 70-130 102 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 100 % 50-150 112 % 50-150 0.13 1 12/13/18 07:13 10061-01-5 0.26 1 12/13/18 07:13 10061-02-6 0.30 1 12/13/18 07:13 100-41-4 0.46 1 12/13/18 07:13 591-78-6 0.32 1 12/13/18 07:13 74-88-4 0.97 1 12/13/18 07:13 75-09-2 0.33 1 12/13/18 07:13 108-10-1 0.26 1 12/13/18 07:13 100-42-5 0.33 1 12/13/18 07:13 630-20-6 0.40 1 12/13/18 07:13 79-34-5 0.46 1 12/13/18 07:13 127-18-4 0.26 1 12/13/18 07:13 108-88-3 0.48 1 12/13/18 07:13 71-55-6 0.29 1 12/13/18 07:13 79-00-5 0.47 1 12/13/18 07:13 79-01-6 0.20 1 12/13/18 07:13 75-69-4 0.41 1 12/13/18 07:13 96-18-4 0.35 1 12/13/18 07:13 108-05-4 0.62 1 12/13/18 07:13 75-01-4 0.66 1 12/13/18 07:13 1330-20-7 1 12/13/18 07:13 460-00-4 1 12/13/18 07:13 17060-07-0 1 12/13/18 07:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 20:12 123-91-1 12/13/18 20:12 17060-07-0 12/13/18 20:12 2037-26-5 Page 19 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW6D Lab ID: 92409790007 Collected: 12/03/18 15:19 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/28/2018 08:45 AM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:44 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:44 7440-38-2 12.8 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:44 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:44 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-47-3 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7439-92-1 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:44 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:44 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:44 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:40 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/07/18 22:53 67-64-1 ND ug/L 10.0 1.9 1 12/07/18 22:53 107-13-1 ND ug/L 1.0 0.25 1 12/07/18 22:53 71-43-2 ND ug/L 1.0 0.17 1 12/07/18 22:53 74-97-5 ND ug/L 1.0 0.18 1 12/07/18 22:53 75-27-4 ND ug/L 1.0 0.26 1 12/07/18 22:53 75-25-2 ND ug/L 2.0 0.29 1 12/07/18 22:53 74-83-9 ND ug/L 5.0 0.96 1 12/07/18 22:53 78-93-3 ND ug/L 2.0 1.2 1 12/07/18 22:53 75-15-0 ND ug/L 1.0 0.25 1 12/07/18 22:53 56-23-5 ND ug/L 1.0 0.23 1 12/07/18 22:53 108-90-7 ND ug/L 1.0 0.54 1 12/07/18 22:53 75-00-3 ND ug/L 1.0 0.14 1 12/07/18 22:53 67-66-3 ND ug/L 1.0 0.11 1 12/07/18 22:53 74-87-3 ND ug/L 2.0 2.0 1 12/07/18 22:53 96-12-8 ND ug/L 1.0 0.21 1 12/07/18 22:53 124-48-1 ND ug/L 1.0 0.27 1 12/07/18 22:53 106-93-4 ND ug/L 1.0 0.21 1 12/07/18 22:53 74-95-3 ND ug/L 1.0 0.30 1 12/07/18 22:53 95-50-1 ND ug/L 1.0 0.33 1 12/07/18 22:53 106-46-7 ND ug/L 1.0 1.0 1 12/07/18 22:53 110-57-6 ND ug/L 1.0 0.32 1 12/07/18 22:53 75-34-3 ND ug/L 1.0 0.24 1 12/07/18 22:53 107-06-2 ND ug/L 1.0 0.56 1 12/07/18 22:53 75-35-4 ND ug/L 1.0 0.19 1 12/07/18 22:53 156-59-2 ND ug/L 1.0 0.49 1 12/07/18 22:53 156-60-5 ND ug/L 1.0 0.27 1 12/07/18 22:53 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 20 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-MW6D Lab ID: 92409790007 Collected: 12/03/18 15:19 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 93 % 70-130 93 % 70-130 94 % 70-130 Analytical Method: EPA 8260E Mod 4.0 ug/L 2.0 97 % 50-150 114 % 50-150 0.13 1 12/07/18 22:53 10061-01-5 0.26 1 12/07/18 22:53 10061-02-6 0.30 1 12/07/18 22:53 100-41-4 0.46 1 12/07/18 22:53 591-78-6 0.32 1 12/07/18 22:53 74-88-4 0.97 1 12/07/18 22:53 75-09-2 0.33 1 12/07/18 22:53 108-10-1 0.26 1 12/07/18 22:53 100-42-5 0.33 1 12/07/18 22:53 630-20-6 0.40 1 12/07/18 22:53 79-34-5 0.46 1 12/07/18 22:53 127-18-4 0.26 1 12/07/18 22:53 108-88-3 0.48 1 12/07/18 22:53 71-55-6 0.29 1 12/07/18 22:53 79-00-5 0.47 1 12/07/18 22:53 79-01-6 0.20 1 12/07/18 22:53 75-69-4 0.41 1 12/07/18 22:53 96-18-4 0.35 1 12/07/18 22:53 108-05-4 0.62 1 12/07/18 22:53 75-01-4 0.66 1 12/07/18 22:53 1330-20-7 1 12/07/18 22:53 460-00-4 1 12/07/18 22:53 17060-07-0 1 12/07/18 22:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/18 17:33 123-91-1 12/07/18 17:33 17060-07-0 12/07/18 17:33 2037-26-5 Page 21 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW1 Lab ID: 92409790008 Collected: 12/03/18 17:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:47 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:47 7440-38-2 Barium 33.1 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:47 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:47 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:47 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-22-4 Hardness, Total(SM 2340B) 24700 ug/L 662 662 1 12/08/18 03:15 12/15/18 19:47 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:47 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:47 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:46 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 07:30 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 07:30 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 07:30 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 07:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 07:30 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 07:30 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 07:30 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 07:30 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 07:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 07:30 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 07:30 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 07:30 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 07:30 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 07:30 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 07:30 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 07:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 07:30 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 07:30 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 07:30 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 07:30 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 07:30 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 07:30 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 07:30 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 07:30 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 07:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 07:30 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW1 Lab ID: 92409790008 Collected: 12/03/18 17:35 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 103 % 70-130 91 % 70-130 99 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 95 % 50-150 113 % 50-150 0.27 1 12/13/18 07:30 78-87-5 0.13 1 12/13/18 07:30 10061-01-5 0.26 1 12/13/18 07:30 10061-02-6 0.30 1 12/13/18 07:30 100-41-4 0.46 1 12/13/18 07:30 591-78-6 0.32 1 12/13/18 07:30 74-88-4 0.97 1 12/13/18 07:30 75-09-2 0.33 1 12/13/18 07:30 108-10-1 0.26 1 12/13/18 07:30 100-42-5 0.33 1 12/13/18 07:30 630-20-6 0.40 1 12/13/18 07:30 79-34-5 0.46 1 12/13/18 07:30 127-18-4 0.26 1 12/13/18 07:30 108-88-3 0.48 1 12/13/18 07:30 71-55-6 0.29 1 12/13/18 07:30 79-00-5 0.47 1 12/13/18 07:30 79-01-6 0.20 1 12/13/18 07:30 75-69-4 0.41 1 12/13/18 07:30 96-18-4 0.35 1 12/13/18 07:30 108-05-4 0.62 1 12/13/18 07:30 75-01-4 0.66 1 12/13/18 07:30 1330-20-7 1 12/13/18 07:30 460-00-4 1 12/13/18 07:30 17060-07-0 1 12/13/18 07:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/18 17:52 123-91-1 12/07/18 17:52 17060-07-0 12/07/18 17:52 2037-26-5 Page 23 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW2 Lab ID: 92409790009 Collected: 12/03/18 17:12 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:50 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:50 7440-38-2 Barium 32.0 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:50 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:50 7440-43-9 Chromium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7439-92-1 Nickel ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:50 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-22-4 Hardness, Total(SM 2340B) 24300 ug/L 662 662 1 12/08/18 03:15 12/15/18 19:50 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:50 7440-62-2 Zinc ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:50 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:48 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 07:47 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 07:47 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 07:47 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 07:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 07:47 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 07:47 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 07:47 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 07:47 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 07:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 07:47 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 07:47 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 07:47 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 07:47 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 07:47 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 07:47 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 07:47 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 07:47 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 07:47 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 07:47 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 07:47 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 07:47 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 07:47 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 07:47 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 07:47 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 07:47 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 07:47 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW2 Lab ID: 92409790009 Collected: 12/03/18 17:12 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 102 % 70-130 91 % 70-130 98 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 99 % 50-150 114 % 50-150 0.27 1 12/13/18 07:47 78-87-5 0.13 1 12/13/18 07:47 10061-01-5 0.26 1 12/13/18 07:47 10061-02-6 0.30 1 12/13/18 07:47 100-41-4 0.46 1 12/13/18 07:47 591-78-6 0.32 1 12/13/18 07:47 74-88-4 0.97 1 12/13/18 07:47 75-09-2 0.33 1 12/13/18 07:47 108-10-1 0.26 1 12/13/18 07:47 100-42-5 0.33 1 12/13/18 07:47 630-20-6 0.40 1 12/13/18 07:47 79-34-5 0.46 1 12/13/18 07:47 127-18-4 0.26 1 12/13/18 07:47 108-88-3 0.48 1 12/13/18 07:47 71-55-6 0.29 1 12/13/18 07:47 79-00-5 0.47 1 12/13/18 07:47 79-01-6 0.20 1 12/13/18 07:47 75-69-4 0.41 1 12/13/18 07:47 96-18-4 0.35 1 12/13/18 07:47 108-05-4 0.62 1 12/13/18 07:47 75-01-4 0.66 1 12/13/18 07:47 1330-20-7 1 12/13/18 07:47 460-00-4 1 12/13/18 07:47 17060-07-0 1 12/13/18 07:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/07/18 18:12 123-91-1 12/07/18 18:12 17060-07-0 12/07/18 18:12 2037-26-5 Page 25 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW3 Lab ID: 92409790010 Collected: 12/04/18 08:55 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 12/08/18 03:15 12/15/18 19:53 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:53 7440-38-2 Barium 267 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:53 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 12/08/18 03:15 12/15/18 19:53 7440-43-9 Chromium 2.8J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-47-3 Cobalt 3.6J ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-48-4 Copper ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-50-8 Lead ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7439-92-1 Nickel 5.9 ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-02-0 Selenium ND ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:53 7782-49-2 Silver ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-22-4 Hardness, Total(SM 2340B) 183000 ug/L 662 662 1 12/08/18 03:15 12/15/18 19:53 Vanadium ND ug/L 5.0 2.5 1 12/08/18 03:15 12/15/18 19:53 7440-62-2 Zinc 7.4J ug/L 10.0 5.0 1 12/08/18 03:15 12/15/18 19:53 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.077J ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:50 7440-28-0 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Acetone ND ug/L 25.0 10.0 1 12/13/18 08:04 67-64-1 Acrylonitrile ND ug/L 10.0 1.9 1 12/13/18 08:04 107-13-1 Benzene ND ug/L 1.0 0.25 1 12/13/18 08:04 71-43-2 Bromochloromethane ND ug/L 1.0 0.17 1 12/13/18 08:04 74-97-5 Bromodichloromethane ND ug/L 1.0 0.18 1 12/13/18 08:04 75-27-4 Bromoform ND ug/L 1.0 0.26 1 12/13/18 08:04 75-25-2 Bromomethane ND ug/L 2.0 0.29 1 12/13/18 08:04 74-83-9 2-Butanone (MEK) ND ug/L 5.0 0.96 1 12/13/18 08:04 78-93-3 Carbon disulfide ND ug/L 2.0 1.2 1 12/13/18 08:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.25 1 12/13/18 08:04 56-23-5 Chlorobenzene ND ug/L 1.0 0.23 1 12/13/18 08:04 108-90-7 Chloroethane ND ug/L 1.0 0.54 1 12/13/18 08:04 75-00-3 Chloroform ND ug/L 1.0 0.14 1 12/13/18 08:04 67-66-3 Chloromethane ND ug/L 1.0 0.11 1 12/13/18 08:04 74-87-3 1,2-Dibromo-3-chloropropane ND ug/L 2.0 2.0 1 12/13/18 08:04 96-12-8 Dibromochloromethane ND ug/L 1.0 0.21 1 12/13/18 08:04 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 0.27 1 12/13/18 08:04 106-93-4 Dibromomethane ND ug/L 1.0 0.21 1 12/13/18 08:04 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.30 1 12/13/18 08:04 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 12/13/18 08:04 106-46-7 trans-1,4-Dichloro-2-butene ND ug/L 1.0 1.0 1 12/13/18 08:04 110-57-6 1,1-Dichloroethane ND ug/L 1.0 0.32 1 12/13/18 08:04 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.24 1 12/13/18 08:04 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.56 1 12/13/18 08:04 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.19 1 12/13/18 08:04 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.49 1 12/13/18 08:04 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Sample: 1201-SW3 Lab ID: 92409790010 Collected: 12/04/18 08:55 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/28/2018 08:45 AM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 103 % 70-130 92 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod 10.5 ug/L 2.0 100 % 50-150 113 % 50-150 0.27 1 12/13/18 08:04 78-87-5 0.13 1 12/13/18 08:04 10061-01-5 0.26 1 12/13/18 08:04 10061-02-6 0.30 1 12/13/18 08:04 100-41-4 0.46 1 12/13/18 08:04 591-78-6 0.32 1 12/13/18 08:04 74-88-4 0.97 1 12/13/18 08:04 75-09-2 0.33 1 12/13/18 08:04 108-10-1 0.26 1 12/13/18 08:04 100-42-5 0.33 1 12/13/18 08:04 630-20-6 0.40 1 12/13/18 08:04 79-34-5 0.46 1 12/13/18 08:04 127-18-4 0.26 1 12/13/18 08:04 108-88-3 0.48 1 12/13/18 08:04 71-55-6 0.29 1 12/13/18 08:04 79-00-5 0.47 1 12/13/18 08:04 79-01-6 0.20 1 12/13/18 08:04 75-69-4 0.41 1 12/13/18 08:04 96-18-4 0.35 1 12/13/18 08:04 108-05-4 0.62 1 12/13/18 08:04 75-01-4 0.66 1 12/13/18 08:04 1330-20-7 1 12/13/18 08:04 460-00-4 1 12/13/18 08:04 17060-07-0 1 12/13/18 08:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 20:31 123-91-1 12/13/18 20:31 17060-07-0 12/13/18 20:31 2037-26-5 Page 27 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 446502 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790004, 92409790005, 92409790006, 92409790007, 92409790008,92409790009,92409790010 METHOD BLANK: 2447336 Matrix: Water Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790004, 92409790005, 92409790006, 92409790007, 92409790008,92409790009,92409790010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 12/15/1819:05 Arsenic ug/L ND 10.0 5.0 12/15/1819:05 Barium ug/L ND 5.0 2.5 12/15/1819:05 Beryllium ug/L ND 1.0 0.50 12/15/1819:05 Cadmium ug/L ND 1.0 0.50 12/15/1819:05 Chromium ug/L ND 5.0 2.5 12/15/1819:05 Cobalt ug/L ND 5.0 2.5 12/15/1819:05 Copper ug/L ND 5.0 2.5 12/15/1819:05 Hardness, Total(SM 2340B) ug/L ND 662 662 12/15/18 19:05 Lead ug/L ND 5.0 2.5 12/15/1819:05 Nickel ug/L ND 5.0 2.5 12/15/1819:05 Selenium ug/L ND 10.0 5.0 12/15/1819:05 Silver ug/L ND 5.0 2.5 12/15/1819:05 Vanadium ug/L ND 5.0 2.5 12/15/1819:05 Zinc ug/L ND 10.0 5.0 12/15/1819:05 LABORATORY CONTROL SAMPLE: Parameter 2447337 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 475 95 80-120 Arsenic ug/L 500 461 92 80-120 Barium ug/L 500 480 96 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 480 96 80-120 Chromium ug/L 500 486 97 80-120 Cobalt ug/L 500 479 96 80-120 Copper ug/L 500 480 96 80-120 Hardness, Total(SM 2340B) ug/L 33100 31500 95 80-120 Lead ug/L 500 471 94 80-120 Nickel ug/L 500 477 95 80-120 Selenium ug/L 500 455 91 80-120 Silver ug/L 250 240 96 80-120 Vanadium ug/L 500 487 97 80-120 Zinc ug/L 500 469 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2447338 MS 92409790001 Spike Units Result Conc. MSD Spike Conc. 2447339 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Antimony ug/L ND 500 500 495 494 99 99 75-125 0 20 Arsenic ug/L ND 500 500 479 478 95 95 75-125 0 20 Barium ug/L 1160 500 500 1580 1590 84 87 75-125 1 20 Beryllium ug/L ND 500 500 494 493 99 99 75-125 0 20 Cadmium ug/L 2.0 500 500 468 467 93 93 75-125 0 20 Chromium ug/L ND 500 500 483 484 96 97 75-125 0 20 Cobalt ug/L 120 500 500 583 583 92 93 75-125 0 20 Copper ug/L ND 500 500 512 513 102 103 75-125 0 20 Hardness, Total(SM 2340B) ug/L 483000 33100 33100 500000 502000 54 57 75-125 0 Lead ug/L ND 500 500 459 456 92 91 75-125 1 20 Nickel ug/L 17.2 500 500 477 477 92 92 75-125 0 20 Selenium ug/L ND 500 500 477 475 95 95 75-125 0 20 Silver ug/L ND 250 250 252 250 101 100 75-125 1 20 Vanadium ug/L ND 500 500 507 506 101 101 75-125 0 20 Zinc ug/L ND 500 500 460 460 92 92 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 446879 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790004, 92409790005, 92409790006, 92409790007, 92409790008,92409790009,92409790010 METHOD BLANK: 2449121 Matrix: Water Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790004, 92409790005, 92409790006, 92409790007, 92409790008,92409790009,92409790010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/14/18 23:02 LABORATORY CONTROL SAMPLE: 2449122 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2449123 2449124 MS MSD 92409256007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.2 10.0 102 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 446323 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790007 METHOD BLANK: 2446334 Matrix: Water Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790007 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/07/18 13:46 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/07/18 13:46 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/07/18 13:46 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/07/18 13:46 1,1-Dichloroethane ug/L ND 1.0 0.32 12/07/18 13:46 1,1-Dichloroethene ug/L ND 1.0 0.56 12/07/18 13:46 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/07/18 13:46 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/07/18 13:46 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/07/18 13:46 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/07/18 13:46 1,2-Dichloroethane ug/L ND 1.0 0.24 12/07/18 13:46 1,2-Dichloropropane ug/L ND 1.0 0.27 12/07/18 13:46 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/07/18 13:46 2-Butanone (MEK) ug/L ND 5.0 0.96 12/07/18 13:46 2-Hexanone ug/L ND 5.0 0.46 12/07/18 13:46 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/07/18 13:46 Acetone ug/L ND 25.0 10.0 12/07/18 13:46 Acrylonitrile ug/L ND 10.0 1.9 12/07/18 13:46 Benzene ug/L ND 1.0 0.25 12/07/18 13:46 Bromochloromethane ug/L ND 1.0 0.17 12/07/18 13:46 Bromodichloromethane ug/L ND 1.0 0.18 12/07/18 13:46 Bromoform ug/L ND 1.0 0.26 12/07/18 13:46 Bromomethane ug/L ND 2.0 0.29 12/07/18 13:46 Carbon disulfide ug/L ND 2.0 1.2 12/07/18 13:46 Carbon tetrachloride ug/L ND 1.0 0.25 12/07/18 13:46 Chlorobenzene ug/L ND 1.0 0.23 12/07/18 13:46 Chloroethane ug/L ND 1.0 0.54 12/07/18 13:46 Chloroform ug/L ND 1.0 0.14 12/07/18 13:46 Chloromethane ug/L ND 1.0 0.11 12/07/18 13:46 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/07/18 13:46 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/07/18 13:46 Dibromochloromethane ug/L ND 1.0 0.21 12/07/18 13:46 Dibromomethane ug/L ND 1.0 0.21 12/07/18 13:46 Ethylbenzene ug/L ND 1.0 0.30 12/07/18 13:46 lodomethane ug/L ND 5.0 0.32 12/07/18 13:46 Methylene Chloride ug/L ND 1.0 0.97 12/07/18 13:46 Styrene ug/L ND 1.0 0.26 12/07/18 13:46 Tetrachloroethene ug/L ND 1.0 0.46 12/07/18 13:46 Toluene ug/L ND 1.0 0.26 12/07/18 13:46 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/07/18 13:46 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/07/18 13:46 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 METHOD BLANK: 2446334 Matrix: Water Associated Lab Samples: 92409790001, 92409790002, 92409790003, 92409790007 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 12/07/18 13:46 Trichloroethene ug/L ND 1.0 0.47 12/07/18 13:46 Trichlorofluoromethane ug/L ND 1.0 0.20 12/07/18 13:46 Vinyl acetate ug/L ND 2.0 0.35 12/07/18 13:46 Vinyl chloride ug/L ND 1.0 0.62 12/07/18 13:46 Xylene (Total) ug/L ND 1.0 0.66 12/07/18 13:46 1,2-Dichloroethane-d4 (S) % 93 70-130 12/07/18 13:46 4-Bromofluorobenzene (S) % 93 70-130 12/07/18 13:46 Toluene-d8 (S) % 96 70-130 12/07/18 13:46 LABORATORY CONTROL SAMPLE: 2446335 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.5 107 70-130 1,1,1-Trichloroethane ug/L 50 48.4 97 70-130 1,1,2,2-Tetrachloroethane ug/L 50 46.6 93 70-130 1,1,2-Trichloroethane ug/L 50 48.3 97 70-130 1,1-Dichloroethane ug/L 50 43.5 87 70-130 1,1-Dichloroethene ug/L 50 46.6 93 70-130 CV 1,2,3-Trichloropropane ug/L 50 50.0 100 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.5 109 70-130 1,2-Dibromoethane (EDB) ug/L 50 49.3 99 70-130 1,2-Dichlorobenzene ug/L 50 48.4 97 70-130 1,2-Dichloroethane ug/L 50 45.5 91 70-130 1,2-Dichloropropane ug/L 50 44.2 88 70-130 1,4-Dichlorobenzene ug/L 50 46.6 93 70-130 2-Butanone (MEK) ug/L 100 87.5 87 64-135 2-Hexanone ug/L 100 97.4 97 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 94.1 94 70-130 Acetone ug/L 100 87.9 88 61-157 Acrylonitrile ug/L 250 224 90 61-143 Benzene ug/L 50 46.7 93 70-130 Bromochloromethane ug/L 50 48.9 98 70-130 Bromodichloromethane ug/L 50 49.6 99 70-130 Bromoform ug/L 50 53.9 108 70-130 Bromomethane ug/L 50 78.1 156 38-130 L1 Carbon disulfide ug/L 50 44.5 89 68-130 Carbon tetrachloride ug/L 50 53.3 107 70-130 Chlorobenzene ug/L 50 48.6 97 70-130 Chloroethane ug/L 50 56.9 114 37-142 Chloroform ug/L 50 45.2 90 70-130 Chloromethane ug/L 50 43.3 87 48-130 cis-1,2-Dichloroethene ug/L 50 44.2 88 70-130 cis-1,3-Dichloropropene ug/L 50 47.6 95 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 LABORATORY CONTROL SAMPLE: 2446335 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 53.2 106 70-130 Dibromomethane ug/L 50 54.1 108 70-130 Ethylbenzene ug/L 50 48.0 96 70-130 lodomethane ug/L 100 105 105 40-130 Methylene Chloride ug/L 50 43.1 86 67-132 Styrene ug/L 50 48.6 97 70-130 Tetrachloroethene ug/L 50 49.9 100 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 44.7 89 70-130 trans- 1,3-Dichloropropene ug/L 50 48.5 97 70-130 trans-1,4-Dichloro-2-butene ug/L 50 56.6 113 35-189 Trichloroethene ug/L 50 49.8 100 70-130 Trichlorofluoromethane ug/L 50 60.7 121 63-130 Vinyl acetate ug/L 100 89.3 89 55-143 Vinyl chloride ug/L 50 60.6 121 70-131 CV Xylene (Total) ug/L 150 147 98 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 97 70-130 MATRIX SPIKE SAMPLE: 2446337 92409790007 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.1 96 73-134 1,1,1-Trichloroethane ug/L ND 20 19.2 96 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 18.8 94 70-136 1,1,2-Trichloroethane ug/L ND 20 19.6 98 70-135 1,1-Dichloroethane ug/L ND 20 19.5 98 70-139 1,1-Dichloroethene ug/L ND 20 22.0 110 70-154 1,2,3-Trichloropropane ug/L ND 20 18.3 92 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 20.2 101 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 19.7 99 70-137 1,2-Dichlorobenzene ug/L ND 20 19.9 99 70-133 1,2-Dichloroethane ug/L ND 20 18.5 92 70-137 1,2-Dichloropropane ug/L ND 20 20.3 102 70-140 1,4-Dichlorobenzene ug/L ND 20 19.7 99 70-133 2-Butanone (MEK) ug/L ND 40 37.0 92 60-139 2-Hexanone ug/L ND 40 38.9 97 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 37.7 94 65-135 Acetone ug/L ND 40 38.6 96 60-148 Acrylonitrile ug/L ND 100 93.2 93 64-147 Benzene ug/L ND 20 20.7 104 70-151 Bromochloromethane ug/L ND 20 21.4 107 70-141 Bromodichloromethane ug/L ND 20 18.7 93 70-138 Bromoform ug/L ND 20 16.9 84 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 MATRIX SPIKE SAMPLE: Parameter 2446337 Units 92409790007 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 24.9 125 15-152 Carbon disulfide ug/L ND 20 22.4 112 69-149 Carbon tetrachloride ug/L ND 20 18.2 91 70-143 Chlorobenzene ug/L ND 20 20.0 100 70-138 Chloroethane ug/L ND 20 23.0 115 52-163 Chloroform ug/L ND 20 19.1 96 70-139 Chloromethane ug/L ND 20 21.4 107 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.3 96 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.0 95 70-137 Dibromochloromethane ug/L ND 20 19.0 95 70-134 Dibromomethane ug/L ND 20 19.1 95 70-138 Ethylbenzene ug/L ND 20 19.5 97 66-153 lodomethane ug/L ND 40 48.4 121 20-138 Methylene Chloride ug/L ND 20 19.3 97 42-159 Styrene ug/L ND 20 19.3 96 70-135 Tetrachloroethene ug/L ND 20 18.2 91 59-143 Toluene ug/L ND 20 19.2 96 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.0 100 70-146 trans- 1,3-Dichloropropene ug/L ND 20 18.0 90 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 15.0 75 47-135 Trichloroethene ug/L ND 20 19.5 97 70-147 Trichlorofluoromethane ug/L ND 20 21.4 107 70-148 Vinyl acetate ug/L ND 40 30.7 77 49-151 Vinyl chloride ug/L ND 20 24.0 120 70-156 Xylene (Total) ug/L ND 60 58.4 97 63-158 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (S) % 94 70-130 Toluene-d8 (S) % 96 70-130 SAMPLE DUPLICATE: 2446336 Parameter Units 92409426006 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 SAMPLE DUPLICATE: 2446336 Parameter Units 92409426006 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 97 4-Bromofluorobenzene (S) % 92 Toluene-d8 (S) % 94 Dup Result RPD ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 97 96 97 0 4 3 Max RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 447140 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409790004, 92409790005, 92409790006, 92409790008, 92409790009, 92409790010 METHOD BLANK: 2450452 Matrix: Water Associated Lab Samples: 92409790004, 92409790005, 92409790006, 92409790008, 92409790009, 92409790010 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/13/18 05:13 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/13/18 05:13 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/13/18 05:13 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/13/18 05:13 1,1-Dichloroethane ug/L ND 1.0 0.32 12/13/18 05:13 1,1-Dichloroethene ug/L ND 1.0 0.56 12/13/18 05:13 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/13/18 05:13 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/13/18 05:13 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/13/18 05:13 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/13/18 05:13 1,2-Dichloroethane ug/L ND 1.0 0.24 12/13/18 05:13 1,2-Dichloropropane ug/L ND 1.0 0.27 12/13/18 05:13 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/13/18 05:13 2-Butanone (MEK) ug/L ND 5.0 0.96 12/13/18 05:13 2-Hexanone ug/L ND 5.0 0.46 12/13/18 05:13 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/13/18 05:13 Acetone ug/L ND 25.0 10.0 12/13/18 05:13 Acrylonitrile ug/L ND 10.0 1.9 12/13/18 05:13 Benzene ug/L ND 1.0 0.25 12/13/18 05:13 Bromochloromethane ug/L ND 1.0 0.17 12/13/18 05:13 Bromodichloromethane ug/L ND 1.0 0.18 12/13/18 05:13 Bromoform ug/L ND 1.0 0.26 12/13/18 05:13 Bromomethane ug/L ND 2.0 0.29 12/13/18 05:13 Carbon disulfide ug/L ND 2.0 1.2 12/13/18 05:13 Carbon tetrachloride ug/L ND 1.0 0.25 12/13/18 05:13 Chlorobenzene ug/L ND 1.0 0.23 12/13/18 05:13 Chloroethane ug/L ND 1.0 0.54 12/13/18 05:13 Chloroform ug/L ND 1.0 0.14 12/13/18 05:13 Chloromethane ug/L ND 1.0 0.11 12/13/18 05:13 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/13/18 05:13 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/13/18 05:13 Dibromochloromethane ug/L ND 1.0 0.21 12/13/18 05:13 Dibromomethane ug/L ND 1.0 0.21 12/13/18 05:13 Ethylbenzene ug/L ND 1.0 0.30 12/13/18 05:13 lodomethane ug/L ND 5.0 0.32 12/13/18 05:13 Methylene Chloride ug/L ND 1.0 0.97 12/13/18 05:13 Styrene ug/L ND 1.0 0.26 12/13/18 05:13 Tetrachloroethene ug/L ND 1.0 0.46 12/13/18 05:13 Toluene ug/L ND 1.0 0.26 12/13/18 05:13 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/13/18 05:13 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/13/18 05:13 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 METHOD BLANK: 2450452 Matrix: Water Associated Lab Samples: 92409790004, 92409790005, 92409790006, 92409790008, 92409790009, 92409790010 Blank Reporting Parameter Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 1.0 1.0 12/13/18 05:13 Trichloroethene ug/L ND 1.0 0.47 12/13/18 05:13 Trichlorofluoromethane ug/L ND 1.0 0.20 12/13/18 05:13 Vinyl acetate ug/L ND 2.0 0.35 12/13/18 05:13 Vinyl chloride ug/L ND 1.0 0.62 12/13/18 05:13 Xylene (Total) ug/L ND 1.0 0.66 12/13/18 05:13 1,2-Dichloroethane-d4 (S) % 88 70-130 12/13/18 05:13 4-Bromofluorobenzene (S) % 100 70-130 12/13/18 05:13 Toluene-d8 (S) % 102 70-130 12/13/18 05:13 LABORATORY CONTROL SAMPLE: Parameter 2450453 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 52.1 104 70-130 1,1,1-Trichloroethane ug/L 50 45.0 90 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.6 105 70-130 1,1,2-Trichloroethane ug/L 50 53.5 107 70-130 1,1-Dichloroethane ug/L 50 48.1 96 70-130 1,1-Dichloroethene ug/L 50 47.7 95 70-130 1,2,3-Trichloropropane ug/L 50 46.0 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 51.3 103 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.1 100 70-130 1,2-Dichlorobenzene ug/L 50 49.7 99 70-130 1,2-Dichloroethane ug/L 50 45.7 91 70-130 1,2-Dichloropropane ug/L 50 50.1 100 70-130 1,4-Dichlorobenzene ug/L 50 49.2 98 70-130 2-Butanone (MEK) ug/L 100 92.5 93 64-135 2-Hexanone ug/L 100 102 102 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 102 102 70-130 Acetone ug/L 100 91.9 92 61-157 Acrylonitrile ug/L 250 228 91 61-143 Benzene ug/L 50 52.7 105 70-130 Bromochloromethane ug/L 50 48.4 97 70-130 Bromodichloromethane ug/L 50 52.7 105 70-130 Bromoform ug/L 50 46.8 94 70-130 Bromomethane ug/L 50 43.1 86 38-130 Carbon disulfide ug/L 50 47.3 95 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 50.8 102 70-130 Chloroethane ug/L 50 45.3 91 37-142 Chloroform ug/L 50 45.8 92 70-130 Chloromethane ug/L 50 42.5 85 48-130 cis-1,2-Dichloroethene ug/L 50 47.3 95 70-130 cis-1,3-Dichloropropene ug/L 50 51.9 104 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 47 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 LABORATORY CONTROL SAMPLE: 2450453 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 51.0 102 70-130 Dibromomethane ug/L 50 54.7 109 70-130 Ethylbenzene ug/L 50 51.6 103 70-130 lodomethane ug/L 100 94.4 94 40-130 Methylene Chloride ug/L 50 44.9 90 67-132 Styrene ug/L 50 52.8 106 70-130 Tetrachloroethene ug/L 50 51.0 102 69-130 Toluene ug/L 50 62.6 125 70-130 trans-1,2-Dichloroethene ug/L 50 47.9 96 70-130 trans- 1,3-Dichloropropene ug/L 50 52.9 106 70-130 trans-1,4-Dichloro-2-butene ug/L 50 51.0 102 35-189 Trichloroethene ug/L 50 51.4 103 70-130 Trichlorofluoromethane ug/L 50 46.2 92 63-130 Vinyl acetate ug/L 100 98.3 98 55-143 Vinyl chloride ug/L 50 46.5 93 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 103 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE SAMPLE: 2450490 92409812005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 20.5 102 73-134 1,1,1-Trichloroethane ug/L ND 20 19.0 95 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.8 99 70-136 1,1,2-Trichloroethane ug/L ND 20 20.7 103 70-135 1,1-Dichloroethane ug/L ND 20 19.4 97 70-139 1,1-Dichloroethene ug/L ND 20 19.5 97 70-154 1,2,3-Trichloropropane ug/L ND 20 20.9 104 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 95 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 19.1 95 70-137 1,2-Dichlorobenzene ug/L ND 20 18.8 94 70-133 1,2-Dichloroethane ug/L ND 20 18.1 90 70-137 1,2-Dichloropropane ug/L ND 20 19.2 96 70-140 1,4-Dichlorobenzene ug/L ND 20 18.3 92 70-133 2-Butanone (MEK) ug/L ND 40 38.1 95 60-139 2-Hexanone ug/L ND 40 40.5 101 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 40.0 100 65-135 Acetone ug/L ND 40 40.9 102 60-148 Acrylonitrile ug/L ND 100 90.7 91 64-147 Benzene ug/L ND 20 21.0 105 70-151 Bromochloromethane ug/L ND 20 19.7 98 70-141 Bromodichloromethane ug/L ND 20 20.4 102 70-138 Bromoform ug/L ND 20 18.4 92 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 MATRIX SPIKE SAMPLE: Parameter 2450490 Units 92409812005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 16.4 82 15-152 Carbon disulfide ug/L ND 20 19.0 95 69-149 Carbon tetrachloride ug/L ND 20 21.0 105 70-143 Chlorobenzene ug/L ND 20 19.7 99 70-138 Chloroethane ug/L ND 20 18.3 92 52-163 Chloroform ug/L ND 20 17.6 88 70-139 Chloromethane ug/L ND 20 18.0 90 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.3 96 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.2 96 70-137 Dibromochloromethane ug/L ND 20 19.6 98 70-134 Dibromomethane ug/L ND 20 20.6 103 70-138 Ethylbenzene ug/L ND 20 20.5 102 66-153 lodomethane ug/L ND 40 25.3 63 20-138 Methylene Chloride ug/L ND 20 16.1 80 42-159 Styrene ug/L ND 20 19.8 99 70-135 Tetrachloroethene ug/L ND 20 21.0 105 59-143 Toluene ug/L ND 20 21.3 107 59-148 trans-1,2-Dichloroethene ug/L ND 20 19.8 99 70-146 trans- 1,3-Dichloropropene ug/L ND 20 19.5 97 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 19.4 97 47-135 Trichloroethene ug/L ND 20 20.8 104 70-147 Trichlorofluoromethane ug/L ND 20 19.8 99 70-148 Vinyl acetate ug/L ND 40 27.9 70 49-151 Vinyl chloride ug/L ND 20 19.0 95 70-156 Xylene (Total) ug/L ND 60 60.9 101 63-158 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 102 70-130 Toluene-d8 (S) % 99 70-130 SAMPLE DUPLICATE: 2450489 Parameter Units 92409664002 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND 0.78J 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 39 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 SAMPLE DUPLICATE: 2450489 Parameter Units 92409664002 Result Dup Result 2-Butanone (MEK) ug/L ND ND 2-Hexanone ug/L ND ND 4-Methyl-2-pentanone (MIBK) ug/L ND ND Acetone ug/L ND ND Acrylonitrile ug/L ND ND Benzene ug/L ND ND Bromochloromethane ug/L ND ND Bromodichloromethane ug/L ND ND Bromoform ug/L ND ND Bromomethane ug/L ND ND Carbon disulfide ug/L ND ND Carbon tetrachloride ug/L ND ND Chlorobenzene ug/L ND ND Chloroethane ug/L ND ND Chloroform ug/L ND ND Chloromethane ug/L ND ND cis-1,2-Dichloroethene ug/L ND ND cis-1,3-Dichloropropene ug/L ND ND Dibromochloromethane ug/L ND ND Dibromomethane ug/L ND ND Ethylbenzene ug/L ND ND lodomethane ug/L ND ND Methylene Chloride ug/L ND ND Styrene ug/L ND ND Tetrachloroethene ug/L ND ND Toluene ug/L ND ND trans-1,2-Dichloroethene ug/L ND ND trans- 1,3-Dichloropropene ug/L ND ND trans-1,4-Dichloro-2-butene ug/L ND ND Trichloroethene ug/L ND ND Trichlorofluoromethane ug/L ND 0.34J Vinyl acetate ug/L ND ND Vinyl chloride ug/L ND ND Xylene (Total) ug/L ND ND 1,2-Dichloroethane-d4 (S) % 90 86 4-Bromofluorobenzene (S) % 99 101 Toluene-d8(S) % 100 101 Max RPD RPD Qualifiers 5 2 1 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 40 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 446273 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409790002, 92409790007, 92409790008, 92409790009 METHOD BLANK: 2446001 Matrix: Water Associated Lab Samples: 92409790002, 92409790007, 92409790008, 92409790009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/07/18 11:26 1,2-Dichloroethane-d4 (S) % 97 50-150 12/07/18 11:26 Toluene-d8 (S) % 113 50-150 12/07/18 11:26 LABORATORY CONTROL SAMPLE: 2446002 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.4 87 71-125 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 114 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2446003 2446004 MS MSD 2612158002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 16.6 17.5 82 87 50-150 5 30 1,2-Dichloroethane-d4 (S) % 106 103 50-150 30 Toluene-d8 (S) % 117 116 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 41 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 QC Batch: 447350 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409790001, 92409790003, 92409790004, 92409790005, 92409790006, 92409790010 METHOD BLANK: 2451417 Matrix: Water Associated Lab Samples: 92409790001, 92409790003, 92409790004, 92409790005, 92409790006, 92409790010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/13/18 15:41 1,2-Dichloroethane-d4 (S) % 95 50-150 12/13/18 15:41 Toluene-d8 (S) % 108 50-150 12/13/18 15:41 LABORATORY CONTROL SAMPLE: 2451418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 15.7 79 71-125 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 108 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2451420 2451421 MS MSD 92409812002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 15.3 15.0 76 75 50-150 1 30 1,2-Dichloroethane-d4 (S) % 100 96 50-150 30 Toluene-d8 (S) % 112 109 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 42 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS Cv This compound was outside of the 20% difference criteria but was not detected in any of the associated samples. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/28/2018 08:45 AM without the written consent of Pace Analytical Services, LLC. Page 43 of 47 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co. Kirksey Dr Closed LF Pace Project No.: 92409790 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92409790001 1201-MW2 EPA 3010A 446502 EPA 6010D 446519 92409790002 1201-MW3S EPA 3010A 446502 EPA 6010D 446519 92409790003 1201-MW3D EPA 3010A 446502 EPA 6010D 446519 92409790004 1201-MW4 EPA 3010A 446502 EPA 6010D 446519 92409790005 1201-MW5 EPA 3010A 446502 EPA 6010D 446519 92409790006 1201-MW6S EPA 3010A 446502 EPA 6010D 446519 92409790007 1201-MW6D EPA 3010A 446502 EPA 6010D 446519 92409790008 1201-SW1 EPA 3010A 446502 EPA6010D 446519 92409790009 1201-SW2 EPA 3010A 446502 EPA 6010D 446519 92409790010 1201-SW3 EPA 3010A 446502 EPA 6010D 446519 92409790001 1201-MW2 EPA 3010A 446879 EPA 6020B 447018 92409790002 1201-MW3S EPA 3010A 446879 EPA 6020B 447018 92409790003 1201-MW3D EPA 3010A 446879 EPA 6020B 447018 92409790004 1201-MW4 EPA 3010A 446879 EPA 6020B 447018 92409790005 1201-MW5 EPA 3010A 446879 EPA 6020B 447018 92409790006 1201-MW6S EPA 3010A 446879 EPA 6020B 447018 92409790007 1201-MW6D EPA 3010A 446879 EPA 6020B 447018 92409790008 1201-SW1 EPA 3010A 446879 EPA 6020B 447018 92409790009 1201-SW2 EPA 3010A 446879 EPA 6020B 447018 92409790010 1201-SW3 EPA 3010A 446879 EPA 6020B 447018 92409790001 1201-MW2 EPA 8260B 446323 92409790002 1201-MW3S EPA 8260B 446323 92409790003 1201-MW3D EPA 8260B 446323 92409790004 1201-MW4 EPA 8260B 447140 92409790005 1201-MW5 EPA 8260B 447140 92409790006 1201-MW6S EPA 8260B 447140 92409790007 1201-MW6D EPA 8260B 446323 92409790008 1201-SW1 EPA 8260B 447140 92409790009 1201-SW2 EPA 8260B 447140 92409790010 1201-SW3 EPA 8260B 447140 92409790001 1201-MW2 EPA 8260B Mod. 447350 92409790002 1201-MW3S EPA 8260B Mod. 446273 92409790003 1201-MW3D EPA 8260B Mod. 447350 92409790004 1201-MW4 EPA 8260B Mod. 447350 92409790005 1201-MW5 EPA 8260B Mod. 447350 92409790006 1201-MW6S EPA 8260B Mod. 447350 92409790007 1201-MW6D EPA 8260B Mod. 446273 92409790008 1201-SW1 EPA 8260B Mod. 446273 92409790009 1201-SW2 EPA 8260B Mod. 446273 92409790010 1201-SW3 EPA 8260B Mod. 447350 Date: 12/28/2018 08:45 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 47 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCUR) Page 1 of 2 aceAnalyfical Document No.: Issuing Authority: f F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville[] ConditionSample Client Name: Project ljO" : 92409790 Upon Receipt ` ` i Il1llllllllll�tillll Courier: l .l�r� d Ex ❑UPS ❑LISPS ❑Client Commercial Pace ❑other: 92409790 ❑ � _ Custody Seal Present? Des ONo Seals intact? ❑Yes ❑No Date/Initials Person Examining Contents:; i Packing Material: ❑Bubble Wrap ETBubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer .// Des ❑No ❑N Type of Ice: Jfwet [:]Blue ❑Nane EIR Gun lo: 92T046 Cooler Temp I°Cj: C' ) Correction Factor: Add/Subtract (°C} 0.0 Temp should be above freezing to 6°C Cooler Temp Corrected (°C): []samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soli[ (Q N/A, water sample) Did ' . ' ' - - - rA •IV , cr r r ors --I? MH umnles originate from a foreign source (internationally, COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes []No CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time; Lot ID of split containers: Project Manager SCURF Review: A Project Manager SRF Review: --AY4— Date: 7. l Date• L ttllp— Page 45 of 47 Document Name: Document Revised: February 7, 2018 e Sample Condition Upon Receipt(SCUR) Page 1 of 2 ;ZeAnayical Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle n z 2 L 2 m x = x m 2 QJ N N Q Q N N H m c r_ C.c L LM Q a Q 3 4 u u 7 u u Z H•i%s H V '�.+ % i+ L L a � A w N R m N o. a a n a a E E Q J J J C J J J J 0 o o Q7 E ca E N Ln O — N h N Li # 7 7 ut z H u a m e� � a M a a m m m ca m m m ca 3 a 1 Project IWO# : 92409790 *M: NMG Due Dale: 12/19/18 CLIENT: 92-Joyce Eng z R o z y = z V N G z 1 a c O O m Z o Z ' a a N i ;n N E N ,. p ,n U N 2 Qfn E Q E ¢ O p O O a a * v Q J Q J 7 7 7 7 N N J J v E v 5 E m E E E E " E E l7 t7 l7 L7 t9 t7 > O a a a a a a a o>> 0 >>44 1A Z z r; N a, ° v z y N y N L N N N CL 7 z c ocL ro E c E C J N Q E E J E o E Ln N N rrt o o a m a c 2 'N NX\\� L 4 5 6 7 9 I, l/ to 11 I 12 pH Adjustment Log for Preserved Samples Sample ID I Type of Preservative I pH upon receipt I Date preservation adjusted -rime preservation Amount of Preservative Lot # adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this farm will 6e sent to the North Carolina DEHNiZ Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 46 of 47 A i m a n m (a 3 m n 3 a ro ; o ro r" -4 an cn a to ro ITEM# ` N m � (D 0 N v E• o o j o p o 0 0 o a CT n D y p O W G O O O o O u 3 C)np o nni M.cn Cr CD -� N w W A @ 0 O y o n V 4 3 .. p�0 m m n mim r1i ONm m m , o ? O o ❑ m rD C m c x x f-p' D zi mO a m w c — D A a h ti - ' nn� n��ca �Cc, �_ m vc v d M ' O Ctu �? 171 A O n O S� MATRIX CCCE (see valid codes to left) C in 0 00 1 0 0 G] 0 GD GO)G) SAMPLE TYPE (G-GRAB C=COMP) ? o p - 303 rxn o o m o n n a x s ,", J A n Z m 9 z m o m l7 A = n - L p 1 s m m m 1� [1 v] �� S:�_� � p < IT „ m v; nC a`e a: cn cS m m m I C'•� n_ um, n m t,j U x 7 v q Z I p V't N h -L� ,1 N `� LIB m 6 r D L, m CL SAMPLE TEMP AT COLLECTION14 'rl ' V A m � N J OF CONTAINERS m m m n o �� � O. C S Q rn Unpreserved •o Cn ,� �. m .. ,� n N H2SO4 O >ei X x T ?� HNO3 m n❑ r HCI m n N X x h. X X / m l a Na0H a m 0 D ' m Na2S203 m (D Z m C fl1 oMaltlanol m (D Other D Q air ;05• 01 Analyses Test YIN o a r x x x I x x x x x x x NC Appendix I Metals o 3 n f° m s a X X x x x X X x x x NC Appendix I VOC 8260 Q ;3.%i �, C X X X x X X X x x X X n D m fD N 1,4-Dioxane N O N Q (!5 °m ro ❑ G m N 4 C O _ N dcr c _ N 1F C C m 0 a CD a CL b LA m m v Z N fp A A C K TEMP in C 0 f $ m Residual Chlorine (YIN) m °n a D Received on / m m d Ica(Y1NI 1 rn m N Custody Sealed n a Z �� Cooler (YIN) O O z Samples Intact y -�, — G � C^� [' a C• +' ;YIN) c I+I Page 47 of 47 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 17, 2018 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 27 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Lab ID Sample ID Matrix Date Collected Date Received 92409786001 92409786002 FIELD BLANK TRIP BLANK Water Water 12/04/18 09:05 12/03/18 05:20 12/05/18 14:05 12/05/18 14:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co. Blanks EB & Kirksey 92409786 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92409786001 FIELD BLANK EPA 6010D DS 14 PASI-A EPA 6020E SER 1 PASI-A EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C 92409786002 TRIP BLANK EPA 8260E CL 50 PASI-C EPA 8260B Mod. DLK 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: FIELD BLANK Lab ID: 92409786001 Collected: 12/04/18 09:05 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/17/2018 04:01 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 12/08/18 03:15 12/13/18 09:53 7440-36-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7440-38-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-39-3 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/13/18 09:53 7440-41-7 ND ug/L 1.0 0.50 1 12/08/18 03:15 12/13/18 09:53 7440-43-9 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-47-3 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-48-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-50-8 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7439-92-1 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-02-0 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7782-49-2 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-22-4 ND ug/L 5.0 2.5 1 12/08/18 03:15 12/13/18 09:53 7440-62-2 ND ug/L 10.0 5.0 1 12/08/18 03:15 12/13/18 09:53 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/12/18 03:00 12/14/18 23:25 7440-28-0 Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/16/18 01:30 67-64-1 ND ug/L 10.0 1.9 1 12/16/18 01:30 107-13-1 ND ug/L 1.0 0.25 1 12/16/18 01:30 71-43-2 ND ug/L 1.0 0.17 1 12/16/18 01:30 74-97-5 ND ug/L 1.0 0.18 1 12/16/18 01:30 75-27-4 ND ug/L 1.0 0.26 1 12/16/18 01:30 75-25-2 ND ug/L 2.0 0.29 1 12/16/18 01:30 74-83-9 ND ug/L 5.0 0.96 1 12/16/18 01:30 78-93-3 ND ug/L 2.0 1.2 1 12/16/18 01:30 75-15-0 ND ug/L 1.0 0.25 1 12/16/18 01:30 56-23-5 ND ug/L 1.0 0.23 1 12/16/18 01:30 108-90-7 ND ug/L 1.0 0.54 1 12/16/18 01:30 75-00-3 ND ug/L 1.0 0.14 1 12/16/18 01:30 67-66-3 ND ug/L 1.0 0.11 1 12/16/18 01:30 74-87-3 ND ug/L 2.0 2.0 1 12/16/18 01:30 96-12-8 ND ug/L 1.0 0.21 1 12/16/18 01:30 124-48-1 ND ug/L 1.0 0.27 1 12/16/18 01:30 106-93-4 ND ug/L 1.0 0.21 1 12/16/18 01:30 74-95-3 ND ug/L 1.0 0.30 1 12/16/18 01:30 95-50-1 ND ug/L 1.0 0.33 1 12/16/18 01:30 106-46-7 ND ug/L 1.0 1.0 1 12/16/18 01:30 110-57-6 ND ug/L 1.0 0.32 1 12/16/18 01:30 75-34-3 ND ug/L 1.0 0.24 1 12/16/18 01:30 107-06-2 ND ug/L 1.0 0.56 1 12/16/18 01:30 75-35-4 ND ug/L 1.0 0.19 1 12/16/18 01:30 156-59-2 ND ug/L 1.0 0.49 1 12/16/18 01:30 156-60-5 ND ug/L 1.0 0.27 1 12/16/18 01:30 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: FIELD BLANK Lab ID: 92409786001 Collected: 12/04/18 09:05 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 12/17/2018 04:01 PM Analytical Method: EPA 8260E ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 99 % 70-130 87 % 70-130 100 % 70-130 Analytical Method: EPA 8260E Mod ND ug/L 2.0 102 % 50-150 111 % 50-150 0.13 1 12/16/18 01:30 10061-01-5 0.26 1 12/16/18 01:30 10061-02-6 0.30 1 12/16/18 01:30 100-41-4 0.46 1 12/16/18 01:30 591-78-6 0.32 1 12/16/18 01:30 74-88-4 0.97 1 12/16/18 01:30 75-09-2 0.33 1 12/16/18 01:30 108-10-1 0.26 1 12/16/18 01:30 100-42-5 0.33 1 12/16/18 01:30 630-20-6 0.40 1 12/16/18 01:30 79-34-5 0.46 1 12/16/18 01:30 127-18-4 0.26 1 12/16/18 01:30 108-88-3 0.48 1 12/16/18 01:30 71-55-6 0.29 1 12/16/18 01:30 79-00-5 0.47 1 12/16/18 01:30 79-01-6 0.20 1 12/16/18 01:30 75-69-4 0.41 1 12/16/18 01:30 96-18-4 0.35 1 12/16/18 01:30 108-05-4 0.62 1 12/16/18 01:30 75-01-4 0.66 1 12/16/18 01:30 1330-20-7 1 12/16/18 01:30 460-00-4 1 12/16/18 01:30 17060-07-0 1 12/16/18 01:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 12/13/18 16:00 123-91-1 12/ 13/ 18 16:00 17060-07-0 12/13/1816:00 2037-26-5 Page 6 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: TRIP BLANK Lab ID: 92409786002 Collected: 12/03/18 05:20 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Date: 12/17/2018 04:01 PM Analytical Method: EPA 8260E ND ug/L 25.0 10.0 1 12/07/1814:37 67-64-1 ND ug/L 10.0 1.9 1 12/07/1814:37 107-13-1 ND ug/L 1.0 0.25 1 12/07/1814:37 71-43-2 ND ug/L 1.0 0.17 1 12/07/1814:37 74-97-5 ND ug/L 1.0 0.18 1 12/07/1814:37 75-27-4 ND ug/L 1.0 0.26 1 12/07/1814:37 75-25-2 ND ug/L 2.0 0.29 1 12/07/1814:37 74-83-9 ND ug/L 5.0 0.96 1 12/07/1814:37 78-93-3 ND ug/L 2.0 1.2 1 12/07/1814:37 75-15-0 ND ug/L 1.0 0.25 1 12/07/1814:37 56-23-5 ND ug/L 1.0 0.23 1 12/07/1814:37 108-90-7 ND ug/L 1.0 0.54 1 12/07/1814:37 75-00-3 ND ug/L 1.0 0.14 1 12/07/1814:37 67-66-3 ND ug/L 1.0 0.11 1 12/07/1814:37 74-87-3 ND ug/L 2.0 2.0 1 12/07/1814:37 96-12-8 ND ug/L 1.0 0.21 1 12/07/1814:37 124-48-1 ND ug/L 1.0 0.27 1 12/07/1814:37 106-93-4 ND ug/L 1.0 0.21 1 12/07/1814:37 74-95-3 ND ug/L 1.0 0.30 1 12/07/1814:37 95-50-1 ND ug/L 1.0 0.33 1 12/07/1814:37 106-46-7 ND ug/L 1.0 1.0 1 12/07/1814:37 110-57-6 ND ug/L 1.0 0.32 1 12/07/1814:37 75-34-3 ND ug/L 1.0 0.24 1 12/07/1814:37 107-06-2 ND ug/L 1.0 0.56 1 12/07/1814:37 75-35-4 ND ug/L 1.0 0.19 1 12/07/1814:37 156-59-2 ND ug/L 1.0 0.49 1 12/07/1814:37 156-60-5 ND ug/L 1.0 0.27 1 12/07/1814:37 78-87-5 ND ug/L 1.0 0.13 1 12/07/1814:37 10061-01-5 ND ug/L 1.0 0.26 1 12/07/1814:37 10061-02-6 ND ug/L 1.0 0.30 1 12/07/1814:37 100-41-4 ND ug/L 5.0 0.46 1 12/07/1814:37 591-78-6 ND ug/L 5.0 0.32 1 12/07/1814:37 74-88-4 ND ug/L 1.0 0.97 1 12/07/1814:37 75-09-2 ND ug/L 5.0 0.33 1 12/07/1814:37 108-10-1 ND ug/L 1.0 0.26 1 12/07/1814:37 100-42-5 ND ug/L 1.0 0.33 1 12/07/1814:37 630-20-6 ND ug/L 1.0 0.40 1 12/07/1814:37 79-34-5 ND ug/L 1.0 0.46 1 12/07/1814:37 127-18-4 ND ug/L 1.0 0.26 1 12/07/1814:37 108-88-3 ND ug/L 1.0 0.48 1 12/07/1814:37 71-55-6 ND ug/L 1.0 0.29 1 12/07/1814:37 79-00-5 ND ug/L 1.0 0.47 1 12/07/1814:37 79-01-6 ND ug/L 1.0 0.20 1 12/07/1814:37 75-69-4 ND ug/L 1.0 0.41 1 12/07/1814:37 96-18-4 ND ug/L 2.0 0.35 1 12/07/1814:37 108-05-4 ND ug/L 1.0 0.62 1 12/07/1814:37 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 L1 Page 7 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Sample: TRIP BLANK Lab ID: 92409786002 Collected: 12/03/18 05:20 Received: 12/05/18 14:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260 MSV Low Level Landfill Analytical Method: EPA 8260E Xylene (Total) ND ug/L 1.0 0.66 1 12/07/18 14:37 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 12/07/18 14:37 460-00-4 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 12/07/18 14:37 17060-07-0 Toluene-d8 (S) 96 % 70-130 1 12/07/18 14:37 2037-26-5 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/12/18 17:12 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 94 % 50-150 1 12/12/18 17:12 17060-07-0 Toluene-d8 (S) 99 % 50-150 1 12/12/18 17:12 2037-26-5 Date: 12/17/2018 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446500 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92409786001 METHOD BLANK: 2447328 Associated Lab Samples: 92409786001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 12/13/18 08:15 Arsenic ug/L ND 10.0 5.0 12/13/18 08:15 Barium ug/L ND 5.0 2.5 12/13/18 08:15 Beryllium ug/L ND 1.0 0.50 12/13/18 08:15 Cadmium ug/L ND 1.0 0.50 12/13/18 08:15 Chromium ug/L ND 5.0 2.5 12/13/18 08:15 Cobalt ug/L ND 5.0 2.5 12/13/18 08:15 Copper ug/L ND 5.0 2.5 12/13/18 08:15 Lead ug/L ND 5.0 2.5 12/13/18 08:15 Nickel ug/L ND 5.0 2.5 12/13/18 08:15 Selenium ug/L ND 10.0 5.0 12/13/18 08:15 Silver ug/L ND 5.0 2.5 12/13/18 08:15 Vanadium ug/L ND 5.0 2.5 12/13/18 08:15 Zinc ug/L ND 10.0 5.0 12/13/18 08:15 LABORATORY CONTROL SAMPLE: Parameter 2447329 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 474 95 80-120 Arsenic ug/L 500 465 93 80-120 Barium ug/L 500 481 96 80-120 Beryllium ug/L 500 479 96 80-120 Cadmium ug/L 500 473 95 80-120 Chromium ug/L 500 470 94 80-120 Cobalt ug/L 500 469 94 80-120 Copper ug/L 500 480 96 80-120 Lead ug/L 500 468 94 80-120 Nickel ug/L 500 466 93 80-120 Selenium ug/L 500 460 92 80-120 Silver ug/L 250 244 98 80-120 Vanadium ug/L 500 470 94 80-120 Zinc ug/L 500 469 94 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447330 2447331 MS MSD 92409826001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 492 474 98 95 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB Pace Project No.: 92409786 & Kirksey MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2447330 2447331 MS MSD 92409826001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 474 457 95 91 75-125 4 20 Barium ug/L 24.6 500 500 516 499 98 95 75-125 3 20 Beryllium ug/L ND 500 500 498 477 100 95 75-125 4 20 Cadmium ug/L ND 500 500 483 468 97 94 75-125 3 20 Chromium ug/L ND 500 500 486 471 97 94 75-125 3 20 Cobalt ug/L ND 500 500 480 462 96 92 75-125 4 20 Copper ug/L ND 500 500 490 474 98 95 75-125 3 20 Lead ug/L ND 500 500 474 458 95 91 75-125 4 20 Nickel ug/L ND 500 500 479 461 96 92 75-125 4 20 Selenium ug/L ND 500 500 481 466 96 93 75-125 3 20 Silver ug/L ND 250 250 250 245 100 98 75-125 2 20 Vanadium ug/L ND 500 500 481 467 96 93 75-125 3 20 Zinc ug/L ND 500 500 484 466 97 93 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446879 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92409786001 METHOD BLANK: 2449121 Matrix: Water Associated Lab Samples: 92409786001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/14/18 23:02 LABORATORY CONTROL SAMPLE: 2449122 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.9 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2449123 2449124 MS MSD 92409256007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.2 10.0 102 100 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446318 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409786002 METHOD BLANK: 2446318 Associated Lab Samples: 92409786002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/07/18 13:29 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/07/18 13:29 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/07/18 13:29 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/07/18 13:29 1,1-Dichloroethane ug/L ND 1.0 0.32 12/07/18 13:29 1,1-Dichloroethene ug/L ND 1.0 0.56 12/07/18 13:29 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/07/18 13:29 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/07/18 13:29 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/07/18 13:29 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/07/18 13:29 1,2-Dichloroethane ug/L ND 1.0 0.24 12/07/18 13:29 1,2-Dichloropropane ug/L ND 1.0 0.27 12/07/18 13:29 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/07/18 13:29 2-Butanone (MEK) ug/L ND 5.0 0.96 12/07/18 13:29 2-Hexanone ug/L ND 5.0 0.46 12/07/18 13:29 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/07/18 13:29 Acetone ug/L ND 25.0 10.0 12/07/18 13:29 Acrylonitrile ug/L ND 10.0 1.9 12/07/18 13:29 Benzene ug/L ND 1.0 0.25 12/07/18 13:29 Bromochloromethane ug/L ND 1.0 0.17 12/07/18 13:29 Bromodichloromethane ug/L ND 1.0 0.18 12/07/18 13:29 Bromoform ug/L ND 1.0 0.26 12/07/18 13:29 Bromomethane ug/L ND 2.0 0.29 12/07/18 13:29 Carbon disulfide ug/L ND 2.0 1.2 12/07/18 13:29 Carbon tetrachloride ug/L ND 1.0 0.25 12/07/18 13:29 Chlorobenzene ug/L ND 1.0 0.23 12/07/18 13:29 Chloroethane ug/L ND 1.0 0.54 12/07/18 13:29 Chloroform ug/L ND 1.0 0.14 12/07/18 13:29 Chloromethane ug/L ND 1.0 0.11 12/07/18 13:29 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/07/18 13:29 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/07/18 13:29 Dibromochloromethane ug/L ND 1.0 0.21 12/07/18 13:29 Dibromomethane ug/L ND 1.0 0.21 12/07/18 13:29 Ethylbenzene ug/L ND 1.0 0.30 12/07/18 13:29 lodomethane ug/L ND 5.0 0.32 12/07/18 13:29 Methylene Chloride ug/L ND 1.0 0.97 12/07/18 13:29 Styrene ug/L ND 1.0 0.26 12/07/18 13:29 Tetrachloroethene ug/L ND 1.0 0.46 12/07/18 13:29 Toluene ug/L ND 1.0 0.26 12/07/18 13:29 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/07/18 13:29 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/07/18 13:29 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 METHOD BLANK: 2446318 Associated Lab Samples: 92409786002 Parameter Units trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2446319 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 93 70-130 94 70-130 98 70-130 MDL Analyzed 1.0 12/07/18 13:29 0.47 12/07/18 13:29 0.20 12/07/18 13:29 0.35 12/07/18 13:29 0.62 12/07/18 13:29 0.66 12/07/18 13:29 12/07/18 13:29 12/07/18 13:29 12/07/18 13:29 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.6 103 70-130 1,1,1-Trichloroethane ug/L 50 47.4 95 70-130 1,1,2,2-Tetrachloroethane ug/L 50 45.9 92 70-130 1,1,2-Trichloroethane ug/L 50 46.8 94 70-130 1,1-Dichloroethane ug/L 50 42.9 86 70-130 1,1-Dichloroethene ug/L 50 66.6 133 70-130 CV,L1 1,2,3-Trichloropropane ug/L 50 46.2 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 52.9 106 70-130 1,2-Dibromoethane (EDB) ug/L 50 47.5 95 70-130 1,2-Dichlorobenzene ug/L 50 48.1 96 70-130 1,2-Dichloroethane ug/L 50 44.5 89 70-130 1,2-Dichloropropane ug/L 50 43.7 87 70-130 1,4-Dichlorobenzene ug/L 50 47.5 95 70-130 2-Butanone (MEK) ug/L 100 83.9 84 64-135 2-Hexanone ug/L 100 94.5 94 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.7 94 70-130 Acetone ug/L 100 85.3 85 61-157 Acrylonitrile ug/L 250 214 86 61-143 Benzene ug/L 50 46.3 93 70-130 Bromochloromethane ug/L 50 48.7 97 70-130 Bromodichloromethane ug/L 50 50.1 100 70-130 Bromoform ug/L 50 51.5 103 70-130 Bromomethane ug/L 50 73.8 148 38-130 L1 Carbon disulfide ug/L 50 70.2 140 68-130 L1 Carbon tetrachloride ug/L 50 52.3 105 70-130 Chlorobenzene ug/L 50 47.9 96 70-130 Chloroethane ug/L 50 58.9 118 37-142 Chloroform ug/L 50 44.3 89 70-130 Chloromethane ug/L 50 46.1 92 48-130 cis-1,2-Dichloroethene ug/L 50 44.1 88 70-130 cis-1,3-Dichloropropene ug/L 50 47.1 94 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 LABORATORY CONTROL SAMPLE: 2446319 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 52.9 106 70-130 Dibromomethane ug/L 50 53.6 107 70-130 Ethylbenzene ug/L 50 47.0 94 70-130 lodomethane ug/L 100 146 146 40-130 L1 Methylene Chloride ug/L 50 42.3 85 67-132 Styrene ug/L 50 48.4 97 70-130 Tetrachloroethene ug/L 50 50.8 102 69-130 Toluene ug/L 50 45.1 90 70-130 trans-1,2-Dichloroethene ug/L 50 45.1 90 70-130 trans- 1,3-Dichloropropene ug/L 50 47.8 96 70-130 trans-1,4-Dichloro-2-butene ug/L 50 52.2 104 35-189 Trichloroethene ug/L 50 49.2 98 70-130 Trichlorofluoromethane ug/L 50 61.2 122 63-130 Vinyl acetate ug/L 100 87.3 87 55-143 Vinyl chloride ug/L 50 63.3 127 70-131 CV Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: 2446321 92409426005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 19.4 97 73-134 1,1,1-Trichloroethane ug/L ND 20 19.7 99 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 19.9 100 70-136 1,1,2-Trichloroethane ug/L ND 20 20.5 102 70-135 1,1-Dichloroethane ug/L ND 20 20.2 101 70-139 1,1-Dichloroethene ug/L ND 20 23.3 117 70-154 1,2,3-Trichloropropane ug/L ND 20 19.5 97 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 18.9 94 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 20.0 100 70-137 1,2-Dichlorobenzene ug/L ND 20 18.6 93 70-133 1,2-Dichloroethane ug/L ND 20 18.3 92 70-137 1,2-Dichloropropane ug/L ND 20 20.7 103 70-140 1,4-Dichlorobenzene ug/L ND 20 19.2 96 70-133 2-Butanone (MEK) ug/L ND 40 37.9 95 60-139 2-Hexanone ug/L ND 40 38.9 97 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 38.8 97 65-135 Acetone ug/L ND 40 40.8 102 60-148 Acrylonitrile ug/L ND 100 95.8 96 64-147 Benzene ug/L ND 20 19.4 97 70-151 Bromochloromethane ug/L ND 20 22.2 111 70-141 Bromodichloromethane ug/L ND 20 19.1 96 70-138 Bromoform ug/L ND 20 16.4 82 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 MATRIX SPIKE SAMPLE: Parameter 2446321 Units 92409426005 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Bromomethane ug/L ND 20 25.7 129 15-152 Carbon disulfide ug/L ND 20 22.3 112 69-149 Carbon tetrachloride ug/L ND 20 18.4 92 70-143 Chlorobenzene ug/L ND 20 20.2 101 70-138 Chloroethane ug/L ND 20 23.2 116 52-163 Chloroform ug/L ND 20 19.9 99 70-139 Chloromethane ug/L ND 20 15.0 75 41-139 cis-1,2-Dichloroethene ug/L ND 20 19.8 99 70-141 cis-1,3-Dichloropropene ug/L ND 20 19.7 98 70-137 Dibromochloromethane ug/L ND 20 18.9 94 70-134 Dibromomethane ug/L ND 20 19.4 97 70-138 Ethylbenzene ug/L ND 20 19.6 98 66-153 lodomethane ug/L ND 40 41.4 104 20-138 Methylene Chloride ug/L ND 20 19.5 97 42-159 Styrene ug/L ND 20 19.4 97 70-135 Tetrachloroethene ug/L ND 20 18.0 90 59-143 Toluene ug/L ND 20 19.7 98 59-148 trans-1,2-Dichloroethene ug/L ND 20 20.5 103 70-146 trans- 1,3-Dichloropropene ug/L ND 20 18.5 93 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 15.3 76 47-135 Trichloroethene ug/L ND 20 19.6 98 70-147 Trichlorofluoromethane ug/L ND 20 22.1 111 70-148 Vinyl acetate ug/L ND 40 32.6 82 49-151 Vinyl chloride ug/L ND 20 20.9 105 70-156 Xylene (Total) ug/L ND 60 59.0 98 63-158 1,2-Dichloroethane-d4 (S) % 93 70-130 4-Bromofluorobenzene (S) % 96 70-130 Toluene-d8 (S) % 100 70-130 SAMPLE DUPLICATE: 2446320 Parameter Units 92408410025 Result Dup Result RPD Max RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 SAMPLE DUPLICATE: 2446320 Parameter Units 92408410025 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 98 4-Bromofluorobenzene (S) % 96 Toluene-d8 (S) % 96 Dup Result RPD ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 95 95 96 3 0 1 Max RPD Qualifiers 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 447864 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill Associated Lab Samples: 92409786001 METHOD BLANK: 2453789 Associated Lab Samples: 92409786001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.33 12/16/18 00:56 1,1,1-Trichloroethane ug/L ND 1.0 0.48 12/16/18 00:56 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.40 12/16/18 00:56 1,1,2-Trichloroethane ug/L ND 1.0 0.29 12/16/18 00:56 1,1-Dichloroethane ug/L ND 1.0 0.32 12/16/18 00:56 1,1-Dichloroethene ug/L ND 1.0 0.56 12/16/18 00:56 1,2,3-Trichloropropane ug/L ND 1.0 0.41 12/16/18 00:56 1,2-Dibromo-3-chloropropane ug/L ND 2.0 2.0 12/16/18 00:56 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.27 12/16/18 00:56 1,2-Dichlorobenzene ug/L ND 1.0 0.30 12/16/18 00:56 1,2-Dichloroethane ug/L ND 1.0 0.24 12/16/18 00:56 1,2-Dichloropropane ug/L ND 1.0 0.27 12/16/18 00:56 1,4-Dichlorobenzene ug/L ND 1.0 0.33 12/16/18 00:56 2-Butanone (MEK) ug/L ND 5.0 0.96 12/16/18 00:56 2-Hexanone ug/L ND 5.0 0.46 12/16/18 00:56 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.33 12/16/18 00:56 Acetone ug/L ND 25.0 10.0 12/16/18 00:56 Acrylonitrile ug/L ND 10.0 1.9 12/16/18 00:56 Benzene ug/L ND 1.0 0.25 12/16/18 00:56 Bromochloromethane ug/L ND 1.0 0.17 12/16/18 00:56 Bromodichloromethane ug/L ND 1.0 0.18 12/16/18 00:56 Bromoform ug/L ND 1.0 0.26 12/16/18 00:56 Bromomethane ug/L ND 2.0 0.29 12/16/18 00:56 Carbon disulfide ug/L ND 2.0 1.2 12/16/18 00:56 Carbon tetrachloride ug/L ND 1.0 0.25 12/16/18 00:56 Chlorobenzene ug/L ND 1.0 0.23 12/16/18 00:56 Chloroethane ug/L ND 1.0 0.54 12/16/18 00:56 Chloroform ug/L ND 1.0 0.14 12/16/18 00:56 Chloromethane ug/L ND 1.0 0.11 12/16/18 00:56 cis-1,2-Dichloroethene ug/L ND 1.0 0.19 12/16/18 00:56 cis-1,3-Dichloropropene ug/L ND 1.0 0.13 12/16/18 00:56 Dibromochloromethane ug/L ND 1.0 0.21 12/16/18 00:56 Dibromomethane ug/L ND 1.0 0.21 12/16/18 00:56 Ethylbenzene ug/L ND 1.0 0.30 12/16/18 00:56 lodomethane ug/L ND 5.0 0.32 12/16/18 00:56 Methylene Chloride ug/L ND 1.0 0.97 12/16/18 00:56 Styrene ug/L ND 1.0 0.26 12/16/18 00:56 Tetrachloroethene ug/L ND 1.0 0.46 12/16/18 00:56 Toluene ug/L ND 1.0 0.26 12/16/18 00:56 trans-1,2-Dichloroethene ug/L ND 1.0 0.49 12/16/18 00:56 trans- 1,3-Dichloropropene ug/L ND 1.0 0.26 12/16/18 00:56 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 METHOD BLANK: 2453789 Matrix: Water Associated Lab Samples: 92409786001 Blank Reporting Parameter Units Result Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 1.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 1.0 1,2-Dichloroethane-d4 (S) % 84 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 100 70-130 Analyzed 1.0 12/16/18 00:56 0.47 12/16/18 00:56 0.20 12/16/18 00:56 0.35 12/16/18 00:56 0.62 12/16/18 00:56 0.66 12/16/18 00:56 12/16/18 00:56 12/16/18 00:56 12/16/18 00:56 LABORATORY CONTROL SAMPLE: Parameter 2453790 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.6 103 70-130 1,1,1-Trichloroethane ug/L 50 49.1 98 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.7 105 70-130 1,1,2-Trichloroethane ug/L 50 54.8 110 70-130 1,1-Dichloroethane ug/L 50 50.8 102 70-130 1,1-Dichloroethene ug/L 50 52.2 104 70-130 1,2,3-Trichloropropane ug/L 50 45.9 92 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.0 106 70-130 1,2-Dibromoethane (EDB) ug/L 50 50.3 101 70-130 1,2-Dichlorobenzene ug/L 50 48.6 97 70-130 1,2-Dichloroethane ug/L 50 48.2 96 70-130 1,2-Dichloropropane ug/L 50 50.0 100 70-130 1,4-Dichlorobenzene ug/L 50 47.9 96 70-130 2-Butanone (MEK) ug/L 100 96.4 96 64-135 2-Hexanone ug/L 100 97.2 97 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 97.8 98 70-130 Acetone ug/L 100 96.3 96 61-157 Acrylonitrile ug/L 250 246 98 61-143 Benzene ug/L 50 53.8 108 70-130 Bromochloromethane ug/L 50 56.8 114 70-130 Bromodichloromethane ug/L 50 52.8 106 70-130 Bromoform ug/L 50 49.1 98 70-130 Bromomethane ug/L 50 40.7 81 38-130 Carbon disulfide ug/L 50 53.8 108 68-130 Carbon tetrachloride ug/L 50 51.3 103 70-130 Chlorobenzene ug/L 50 51.0 102 70-130 Chloroethane ug/L 50 48.4 97 37-142 Chloroform ug/L 50 49.2 98 70-130 Chloromethane ug/L 50 45.6 91 48-130 cis-1,2-Dichloroethene ug/L 50 51.2 102 70-130 cis-1,3-Dichloropropene ug/L 50 53.8 108 70-130 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 LABORATORY CONTROL SAMPLE: 2453790 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 51.5 103 70-130 Dibromomethane ug/L 50 56.9 114 70-130 Ethylbenzene ug/L 50 51.0 102 70-130 lodomethane ug/L 100 90.0 90 40-130 Methylene Chloride ug/L 50 44.4 89 67-132 Styrene ug/L 50 52.6 105 70-130 Tetrachloroethene ug/L 50 50.8 102 69-130 Toluene ug/L 50 51.3 103 70-130 trans-1,2-Dichloroethene ug/L 50 51.5 103 70-130 trans- 1,3-Dichloropropene ug/L 50 54.3 109 70-130 trans-1,4-Dichloro-2-butene ug/L 50 47.9 96 35-189 Trichloroethene ug/L 50 54.4 109 70-130 Trichlorofluoromethane ug/L 50 51.0 102 63-130 Vinyl acetate ug/L 100 99.9 100 55-143 Vinyl chloride ug/L 50 51.7 103 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 90 70-130 4-Bromofluorobenzene (S) % 101 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2453791 2453792 MS MSD 92410469002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.0 23.0 115 115 73-134 0 30 1,1,1-Trichloroethane ug/L ND 20 20 21.1 21.3 106 107 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.9 22.0 109 110 70-136 0 30 1,1,2-Trichloroethane ug/L ND 20 20 23.1 23.2 115 116 70-135 1 30 1,1-Dichloroethane ug/L ND 20 20 21.3 21.6 107 108 70-139 1 30 1,1-Dichloroethene ug/L ND 20 20 21.4 21.7 107 108 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 21.8 23.7 109 118 71-137 8 30 1,2-Dibromo-3- ug/L ND 20 20 21.6 21.0 108 105 65-134 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.9 21.1 109 106 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 19.9 19.2 100 96 70-133 4 30 1,2-Dichloroethane ug/L ND 20 20 21.1 20.7 106 104 70-137 2 30 1,2-Dichloropropane ug/L ND 20 20 20.8 21.0 104 105 70-140 1 30 1,4-Dichlorobenzene ug/L ND 20 20 19.6 20.0 98 100 70-133 2 30 2-Butanone (MEK) ug/L ND 40 40 40.8 39.7 102 99 60-139 3 30 2-Hexanone ug/L ND 40 40 41.9 40.9 105 102 65-138 2 30 4-Methyl-2-pentanone ug/L ND 40 40 40.8 42.0 102 105 65-135 3 30 (MIBK) Acetone ug/L ND 40 40 43.4 43.8 108 110 60-148 1 30 Acrylonitrile ug/L ND 100 100 96.9 97.0 97 97 64-147 0 30 Benzene ug/L ND 20 20 23.3 22.9 116 115 70-151 2 30 Bromochloromethane ug/L ND 20 20 23.6 23.6 118 118 70-141 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 27 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2453791 2453792 MS MSD 92410469002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Bromodichloromethane ug/L ND 20 20 21.8 22.3 109 112 70-138 2 30 Bromoform ug/L ND 20 20 19.7 18.8 98 94 63-130 5 30 Bromomethane ug/L ND 20 20 15.3 16.7 76 84 15-152 9 30 Carbon disulfide ug/L ND 20 20 21.5 20.4 108 102 69-149 5 30 Carbon tetrachloride ug/L ND 20 20 23.1 23.2 115 116 70-143 0 30 Chlorobenzene ug/L ND 20 20 22.0 21.5 110 107 70-138 2 30 Chloroethane ug/L ND 20 20 21.3 20.5 106 103 52-163 4 30 Chloroform ug/L ND 20 20 20.9 20.8 104 104 70-139 0 30 Chloromethane ug/L ND 20 20 16.8 16.8 84 84 41-139 0 30 cis-1,2-Dichloroethene ug/L ND 20 20 21.6 21.4 108 107 70-141 1 30 cis-1,3-Dichloropropene ug/L ND 20 20 21.3 22.0 106 110 70-137 4 30 Dibromochloromethane ug/L ND 20 20 21.0 20.8 105 104 70-134 1 30 Dibromomethane ug/L ND 20 20 23.1 23.8 116 119 70-138 3 30 Ethylbenzene ug/L ND 20 20 22.2 21.6 111 108 66-153 3 30 lodomethane ug/L ND 40 40 23.4 32.5 59 81 20-138 32 30 R1 Methylene Chloride ug/L ND 20 20 17.3 17.5 86 87 42-159 1 30 Styrene ug/L ND 20 20 22.7 21.3 114 107 70-135 6 30 Tetrachloroethene ug/L ND 20 20 22.4 21.4 112 107 59-143 4 30 Toluene ug/L ND 20 20 21.7 22.4 109 112 59-148 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 21.9 22.2 109 111 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 21.6 22.7 108 113 70-135 5 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 15.6 15.1 78 75 47-135 3 30 Trichloroethene ug/L ND 20 20 23.5 23.9 117 119 70-147 2 30 Trichlorofluoromethane ug/L ND 20 20 22.0 21.3 110 107 70-148 3 30 Vinyl acetate ug/L ND 40 40 28.7 28.4 72 71 49-151 1 30 Vinyl chloride ug/L ND 20 20 19.5 19.8 97 99 70-156 2 30 Xylene (Total) ug/L ND 60 60 68.0 65.8 113 110 63-158 3 30 1,2-Dichloroethane-d4 (S) % 91 92 70-130 4-Bromofluorobenzene (S) % 104 102 70-130 Toluene-d8 (S) % 97 101 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 446769 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409786002 METHOD BLANK: 2448638 Associated Lab Samples: 92409786002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 101 50-150 101 50-150 MDL Analyzed 1.9 12/12/18 16:33 12/12/18 16:33 12/12/18 16:33 Qualifiers LABORATORY CONTROL SAMPLE: 2448639 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 17.1 86 71-125 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8(S) % 101 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2448640 2448641 MS MSD 92409426003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 17.0 16.5 85 83 50-150 3 30 1,2-Dichloroethane-d4 (S) % 93 93 50-150 30 Toluene-d8 (S) % 104 103 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 QC Batch: 447350 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 92409786001 METHOD BLANK: 2451417 Associated Lab Samples: 92409786001 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 95 50-150 108 50-150 MDL Analyzed 1.9 12/13/18 15:41 12/13/18 15:41 12/13/18 15:41 Qualifiers LABORATORY CONTROL SAMPLE: 2451418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 15.7 79 71-125 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 108 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2451420 2451421 MS MSD 92409812002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 15.3 15.0 76 75 50-150 1 30 1,2-Dichloroethane-d4 (S) % 100 96 50-150 30 Toluene-d8 (S) % 112 109 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS Cv This compound was outside of the 20% difference criteria but was not detected in any of the associated samples. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/17/2018 04:01 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 27 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co. Blanks EB & Kirksey Pace Project No.: 92409786 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92409786001 FIELD BLANK EPA 3010A 446500 EPA 6010D 446517 92409786001 FIELD BLANK EPA 3010A 446879 EPA6020B 447018 92409786001 FIELD BLANK EPA 8260B 447864 92409786002 TRIP BLANK EPA 8260B 446318 92409786001 FIELD BLANK EPA 8260B Mod. 447350 92409786002 TRIP BLANK EPA 8260B Mod. 446769 Date: 12/17/2018 04:01 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 27 Document Name: Document Revised: February 7, 2018 m �Vce Sample Condition Upon Receipt(SOUR) Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office AmIxical Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvjlle'� Raleigh[] Mechanicsville❑ Sample Condition Client Name:Upon Receipt Project; IWO# : 92409786 (i E C- C. 1Z� v II y I I I l Courier: ❑Fed Ex ❑UPS []LISPS Client VI III II III II I I I� �Il ❑ Commercial Pace []Other: 492409786 I 111 Custody Seal Present? ❑Yes \Vo Seals Intact? ❑Yes No Packing Material: ❑Bubble Wrap "Bubble Bags ❑None El Other Thermometer: `�� 92T046 Type of Ice: Wet ❑D1ue IR Gun ID: Cooler Temp {' j: -- `I- Correction Factor: Add/Subtract ('C) 0.0 L-l- Cooler Temp Corrected ('CI: USDA Regulated Soil (tS\N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? nv— Neu a f - Date/Initials Person Examining Contents: � % Biological Tissue Frozen? ❑Yes ❑No []N/A ❑None Temp should be above freezing to 61C []Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (i ernationatly, including Hawaii and Puerto Rico)? ❑Yes No Comments/Discrepancy: Chain of Custody Present? es ❑No ❑N/A I. Samples Arrived within Hold Time? es [IN. ❑NIA 2. Short Hold Time Analysis (<72 hr.)? ❑Yes o ❑N/A 3. Rush Turn Arcund;ime Requested? C] Yes Zgpo ❑NIA 4. Sufficient Volume? fgXes ❑No ❑NIA 5. Correct Containers Used? -Pace Containers Used? ":[jYes OYCs ❑No ❑No ❑N/A ❑NIA 6. Containers Intact? 6Yes ❑No ❑N/A. 7. Dissolved analysis: Samples Field Filtered? [—]Yes ❑No NIA 8. Sample labels Match COC? -Includes Date/Time/ID/Analysis Matrix: Yes []No []N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes No [I N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? Yes es [:]No ❑No ❑N/A ❑NIA 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Nm� OLi Date/Time: Field Data Required? ❑Yes ❑No Lot ID of split containers: Date: ( Z `-+ � f Date: 17,121 10 Page 25 of 27 Document Name: Document Revised: February 7, 2018 m Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: ac�Analk,trcal { F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples, Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Prole Iwo# ; 92409786 l2N: NMO Due Date: 12/19/18 CLIENT: 92-Joyce Eng E m z i? m u •N <o a E V a m z Z m c c i- m`w a E Ln 7 M a m Z I N n c '++ a E o N A. m a rZ.. ¢ai c V a�, m u ? 't &. m v = a O CA N d E v7 C d m v O mw = . a E N Z �'V a m O Z 06 G1 m u q Z uZ •�, J E LA M N a a co V N � ^ _a O O t+ J E Ln U 7 a m � ° n mv sue+ a 3 3 Z d m ava aU Ul E q m H L7 a N v CIAIr E Q m _ ei Lo a v 2' cc a J E `N M W a N v n O N=Q 2 E a v V1 H (7 a V 2 O q J E CDE ry v1 M L7 a ? T Z aUO N i m o a M 0 a x O > a Y M kv e Q z n7 i z q - a f= tl1 0 >> c a 3 O % E 7 0 (7 a 2m a° 2 O J E Y a GI 0 o Q z m a a N ° = Y a O >> z Y a l7 xNa Y L ��° Y L7 � m Q z .� N £ N to a ? «a m^ J E Ln 0 H N 6 m O N r_u a J E N M a z > H m a J E o P C7 Q VI E 0 N {� an s v aa 71 E q E 0 a m (7 1 X"I 2 4 ! 3 4 6 \d 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there Is a discrepancy affecting North Caroiina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 26 of 27 n Gy r A z C nz D re ft 3 m ro to O p A N N z A O 3 m m z A A a c •' Q m Hecelveu ..7 Ice (YIN) Custody Sealed Cooler (YIN) Samples intact A O a H 0 n r n 0 m z N 51121m c i m n n V v i a P A 0 z to D 3 m m n 0 z 0 0 0 z N 3 to I- I- 11 I- 6 IA Iw IN I- 1 ITEMN m a iv W y b O V/ n � e n m c m m > n ro u, m (➢ � 3 � � a N 0 a O Q � � ➢ m O N L c W p- Z 1 p m' 6aC ns n o N n 11 A MD m . 7. C? 4 ai a �on�oNp��a3 to G n v p N n n v O C n N n 40 O i O D O a m O 0 v 0 l.1ATR1X CODE Ilea valitl codes to left) z W p C n n. C o Z SAMPLE TYPE (G=GRAB C=COmp) 6 o l N IJ i n m z Lrmn O SAMPLE TEMP AT COLLECTION # OF CCNTA.INERS Unpreserved H2SO4 HNO3 HCl m nr NaOH Na2S203 �o N Methanol Other Analyses Test Y/N NC Appendix I Metals NC Appendx I VOC 8260'a 1,4-Dloxene e� la w -� 0 � 3 C)D 7 o C O vv�>nn cn N r °a 0 m n m o r; 0 m❑ > o C) o `'? 0 N �? G m � C r m Z 7 N E a1 o ari — m �C CDz G) f° rr > C� w x7 5' QF m n N O C (^A n N (Q to H N N C ❑ a p 3 Q 0 0+ (U C n3 r -6 (p m (U a 4 '< of `z n C z z N m m [D o m C o n n r a " O N O y D b 7 � n 0 Page 27 of 27 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 12, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on February 11, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Lab ID Sample ID Matrix Date Collected Date Received 92417186001 92417186002 MW-4 FIELD BLANK Water Water 02/08/19 08:12 02/08/19 11:57 02/11/19 09:10 02/11/19 09:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92417186001 MW-4 EPA 6010D SH1 1 PASI-A 92417186002 FIELD BLANK EPA 6010D SH1 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Sample: MW-4 Lab ID: 92417186001 Collected: 02/08/19 08:12 Received: 02/11/19 09:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Vanadium ND ug/L 5.0 2.5 1 02/12/19 01:00 02/12/19 12:36 7440-62-2 Date: 02/12/2019 04:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Sample: FIELD BLANK Lab ID: 92417186002 Collected: 02/08/19 11:57 Received: 02/11/19 09:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Vanadium ND ug/L 5.0 2.5 1 02/12/19 01:00 02/12/19 12:39 7440-62-2 Date: 02/12/2019 04:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 QC Batch: 457565 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92417186001, 92417186002 METHOD BLANK: 2495418 Matrix: Water Associated Lab Samples: 92417186001, 92417186002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vanadium ug/L ND 5.0 2.5 02/12/1912:18 LABORATORY CONTROL SAMPLE: 2495419 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vanadium ug/L 500 502 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2495420 2495421 MS MSD 92417140003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vanadium ug/L 61.5 500 500 532 524 94 93 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:57 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:57 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: BURKE CITY KIRKSEY DR RESAMPLE Pace Project No.: 92417186 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92417186001 MW-4 EPA 3010A 457565 EPA 6010D 457574 92417186002 FIELD BLANK EPA 3010A 457565 EPA6010D 457574 Date: 02/12/2019 04:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 12 Document Name: Document Revised: February 7, 2018 Condition Upon Receipt(SCUR) Pagel of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh❑ Mechanicsville[] Sample Condition n .. Client Name: IWOJ# ' J241.7186 on Receiptj Projet .r Illi111lllllllllllil111 Courier: ❑Fed Ex ❑UPS ❑U5P5 ❑Client ❑ Commercial ❑Pace ❑Other 92417186 Custody Seal Present? ❑Yes ❑No Seals Intact? ❑Yes ❑No Date/Initials Person txaminingContents: I- I 1 Packing Material: []Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen? ❑Yes ❑No N/A Thermometer: 92 hang Type of Ice: ❑Wet []Blue❑None ❑IR Gun ID: Cooler Temp (°C): i' Correction Factor: Add/Subtract (°C) 0,p f t + Temp should be above freezing to 6°C Cooler Temp Corrected (°C): ❑samples outoftemP criteria, samples on ice, coaling process has begun USDA Regulated Soil (❑\N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps}? Did samples originate from a foreign source (internationally, ❑Yes ❑JVo including Hawaii and Puerto Rico)? Des❑ o Chain of Custody Present? Samples Arrived within Hold Time? Short Hold Time Analysis (02 hr.)? Rush Turn Around Time Requested? Sufficient Volume? Correct Containers Used? -Pace Containers Used? Containers Intact? Dissolved analysis: Samples Field Filtered? Sample Labels Match COC? -Includes Date/Time/ID/Analyst Headspace in VDA Vials (>5-6mm) Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION <❑Yes ❑Yes Dyes ❑No ❑NO ❑No ❑N/A ❑NIA ❑N/A 1, 2, 3. ❑Yes ❑No ❑N/A 4. ❑Yes (]No ❑NIA S. ❑Yes [:]NO ❑N/A 6. ❑Yes ❑No []N/A ❑Yes ❑No ❑N/A 7. []yes [:]No_ ❑N/A 8. ❑Yes []No ❑N/A 9. A []Yes ❑No []N/A_. 10. ❑Yes ❑No ❑N(A 11. 1-1Yes 11NO ❑N/A Lot ID ofsolit containers: Field Data Required? Dyes []NO Person contacted: Date/Time: Project Manager SCURF Review: M6 Date: L �j Project Manager SRF Review: - 0 ► ' "U' Date: r Page 10 of 12 Document Name: Document Revised: February 7; 2018 m Sample Condition Upon Receipt(SCUR) Page 1 of 2 CeAnaiWdl Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coiiform, TOC, Oil and Grease, DRO/8015 (water) DOC, L ft **Bottom half of box is to list number of bottle i z m- m a 7 a m z a-- v L a 7 u A N- d y a m Q U '0V V Z n O_ a m 0 0 v C' = S O m `0 A 0 0 10 Z C N N a v N Q c- A = T a =° p 1O � Z 13 Gl Y N c ^ Z d a a v E a a a a a a a E ¢ E rN/ 7 m E N 7 m E LQ N 0.m . I N v7 en m a. - N m 3 Nd6 U tD m 3 7 a ate, 2 3 4 5 6 7 8 9 is Project # WOV9241.7186- ISM: NMG Due Date: 02/26/19 CLIENT: 92-Joyce Eng U V z z N = �- E = A (D 4 m N `o. 0 E ¢ E Ln eq rM l9 4 = ¢ v 2 W E m rl Ch G a tl 0 of = E .¢ r" l7 Q Z `y 4 E Q o N LS M L7 ¢ G z U 4 Oa O cn C7 n Z tr1 O N ¢ 0 O tl1 l7 7 Q 2 Q C ¢ O V G5 C7 ? 4 Z v 0 6 O O � L7 0 Y In m Q `m N `D Q 0 7 x a ? a en t7 •> 2 U : —° m N ul a H cc m o Ln N N a u, N rV = a a a O r4 M a m QJ ? a C ¢ M O U 4 N 2 m m C C c o. O c y E Ln Q No 0 > in 7 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount aded Preservative Lot p adjusted NR Certification Office Note: W henever there is a discrepancy affecting North Caroiina compliance samples, a copy of this form wil4 6e sent to the North Carolina aEH Out of hold, incorrect preservative, out of temp, incorrect containers. Page 11 of 12 !, s s _ ;Uumci an °' N s O to co V Cb to A W H ITEM # � a � m iO -. m 3 D N — N N N a a" `C Z: C O21 m f m W n n N r d D N M_ ro ov 0, ggiv O o n Cc y a n m ❑. p ^'� 1 } O Q t9 OO .. � O 3 C Cr x v x f rn 3 an N A z C7 v V n tl A m.0.n a_� ^ - -o n. n. .m - o _ 0 a - m a m m 0 A � O MATRIX CODE {see valid codes to lefl) m S•{ N # ry 3 SAMPLE TYPE (G=GRAB C=COMP) C co r a7 F Q m m i n T rn n C1 a D 7C y V m Or O z Z Z n � p a N C: m a rr Mv � 3 M o m a m rn l.� 5 V N m M Z Z SAMPLE TEMP AT COLLECTION ` C #OF CONTAINERS U m y N m a o 1-10 v Unpreserved .� [, ic M D N d o` , -U it M ->< HNO3 m n i rn `W HCI 0r j NaOH m t� m Na2S203 (D '� �L1 S j Methanol f y m Other o �) C H (2 , Analyses Test YIN x x 6010 (V only) o p z m N m C V Y y w � y Ffl T � N C Q a rn m 0 TEMP in C I 4 ;aLa fl Residual Chlorine (YIN) ' y n p1 m r S. Received an {YfN) O a m n Custody Sealed Cooler z o { Y!N z r� Samples Intact (YIi c J - C-- i o r n �v Page 12 of 12 ILI- &JV 1 `C► DATE: 4-1__3,_-' O 1 S" A LaBella Company GROUND WATER SAMPLING LOG Project Name: .. o — 1 '�, Project No. /Task No.: Z i � Well ID: Sampler(s): Me -- Well Location: 3Cn51':6_ 10- ;�� aeQL tra; r' Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches �?Z)- feet 50,557 feet feet [DTB-DTW] 6 Qallons gallons _ gallons d Qallons Purged with: Bailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp(' C) pH Cond. (IiS/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials Date of sample: Before Sampling Comments (weather conditions, odor, color, silt etc.): � �. � � • Ra • a � �► � ' i i a fI 1 ' IMP a Signature: Date: _ J 2 / 3zz'p 16 QA/QC Sign Off• Date: / Z Z6 461V 1 ` DATE: I Z/3IZot -G U , A t_aBella Company GROUND WATER SAMPLING LOG Project Name: tcy,C.,o"_ �� �� l�Project No. /Task No.: 12 I 1 _/P I-)0--x- DZ Well ID: M \AZ Sampler(s): V1, McSv bed S' )e boi r2,' Well Location: cis aW n Q arf-..V {-),, I eA Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) 2 inches 2&.79 feet y5r % U feet ' .9 Z. feet [DTB-DTW] Calculation for One Well Volume (WV): 7 For 2" Well: WCT X 0.163 = '' gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = 3 gallons Actual Amount Purged/Bailed: - gallons Purged with: Baile Pump Other: Sampled with: ailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp(° C) pH Cond. (0/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials lk) 1 1�,S .5.9 J 57 5, ! ,s 'o.�5 IlIV1 �.e- !(�I 2 Ico. ? (0, s,3s - ` o.s &/s V2 ��� 1(�lS 15.E 5. )(OC> Z. 1s -A, i Date of sample: 101311g Before Sampling j(o 1 5- 15-, 3 1(a D� Comments (weather conditions, odor, color, silt, etc.): Signature: Date: J ISIZO i S QA/QC Sign Off: Date: /Z '. y &JLJ r `L DATE: 0 A LaBetla Company GROUND WATER SAMPLING LOG Project Name: LAC L 0 " ► r KProject No. /Task No.: 2; S l; 71 /f ka%e Well ID: _Ku -26 _ Sampler(s): K . Ni\ e� 6 Well Location: 'Do w n Y-o O-A b n I PTA- @ b r; dw= o n Q L)ctirr y a. Well Diameter: 2 inches Initial Depth to Water (DTW): �, S-5 feet Depth to Bottom (DTB): Z(Q . (,P9 feet Water Column Thickness (WCT): 20, 8 (e feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well For 4" Well WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: Depth to Water before Sampling: Qallons gallons D • Z gallons 1 Q, Z gallons Other: Other: feet Gallons Time Temp(* C) pH Cond. (µS/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials n iN z qJ 7yS G�. i 51 S. ,s3 S,7 ,N1 LD. Z ICoS� l�l, ,Ss '77& 7 -0.9 2q,&I Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.): ��1C (.�e144,.,gr w(�o ciii/llri\� �%SL�S .Ape Icy 5 rQG'�' l Signature: Date: QA/QC Sign Off: Date: F AJ 1 `G DATE: 1 2 13f ZC) q A LaBella Company GROUND WATER SAMPLING LOG Project Name:our6_Co. r 1 C � Project No. /Task No.: 2191371 Ohase 0 2 Well ID• M W _ SP Sampler(s)• . McSv_&_- d ZJ. Se-bod ✓1 r , � Well Location: N e, A ' jS Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with 2 inches feet we.fi� 79, z1Q feet qO feet [DTB-DTW] f 2 . gallons gallons gallons 5� L� gallons Depth to Water before Sampling: feet Gallons FIZIS Time Temp(° C) pH Cond. (µS/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials c NaM 12- 6-s-D 7Z3 O.8( -Z, 3 .5 ►0,'7 RNk (o.y3 73 ,q1 7Z 5S s5 / S.qS -�S. � 14.3l �35 Date of sample: 12/3/Zo1g Before Sampling %�� 1 f SS G(n S,qS -�S Z �i, 3 1:55 Comments (weather conditions, odor, col�o--rf,, silt, etc.): Ur Signature: 4LW -/ "'__ .- - 00r. Date: QA/QC Sign Off: Date: ' Z/ DATE: �_r�12O1g A l_aBella Company GROUND WATER SAMPLING LOG Project Name: C_"� _ V_ rk- Project No. /Task No.: 2119 IS -7/ zlp Well ID: - Sampler(s): R. �4e5u)7eVS, Si,44,4L. Well Location: rG USN MbUN 1 an 51Q U(�r r` 1�,� i n ¢� a�2� y o ✓► Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): 2 inches L" D. Zq feet Z q- �EZ feet 2/ feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = Qallons For 4" Well: WCT X 0.653 = /�— gallons For THREE Well Volumes: WV X 3 = '-1! . S gallons Actual Amount Purged/Bailed: / S� Qallons Purged with: Bailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: Z0. Z feet Gallons Time Temp(° C) pH Cond. (µS/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials I5-36 Z 7y. 14-o o�q ss 11536, 2, 121 A 3, -'� 14 19. S (,,S, S 3,0 I syl )S, & 5, 57 (o - 13 5 Date of sample: I Z1H116 ^ Before Sampling 0, y2 �� C) s� -7D 'j, 0 /,�, s �I.O � Comments (weather conditions, odor, color, silt, etc.): Q_ VA�-aR-� was sv:� n -+- "5 r� 12/ 3 c� n� -+- am IZ/ 1i , lb C'_ e-r-) IJ Signature:. / �a� Date: ) 2 % t-{ l ?oi 3 QA/QC Sign Off: Date: / 02 DATE:VJ �7 f A LaBella Company GROUND WATER SAMPLING LOG Project Name: L)Cv , CO- ;rk�e Project No. /Task No.: 2iq 1'3 7 1 /per Well ID: _ y -= Sampler(s):_ � , Mes- ," /J Sle W4 , kL Well Location: b� kny),,a Ar,� or.QA �-wti r A \, -(flush 1 Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Bailer 2 inches �9.2 feet 00 feet /Q- 5/ feet [DTB-DTW] i` 7 gallons = gallons gallons gallons Other: Sampled with: Bail Pump l fOther: Depth to Water before Sampling: Sq, 7 z feet Gallons Time Temp(° C) pH Cond. (N-S/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials C� 1 17. 3 3,93 W 9 s(o � s� S. 6 6.61 17 o D3 z, s5 �.I � 12 15,62 519 ICI. '7 Z7• 2 S s> Date of sample: i Z qll% BeIIIfore Sampling C6 �'fj , d emu• �^] Comments (weather conditions, odor, color, silt, etc.): wos Pur � on 1 �/3 an6 So�- i Pke- , ena 1 Z ' Signature: 6° Date: 1z1q1201R QA/QC Sign Off: all" ���� Date: Z Well ivV 1`i. DATE: 12/3 — W /2o t 0 A LaBella Company GROUND WATER SAMPLING LOG Project Name: 7Q( Ki CO. - )L-i`k� Project No. /Task No.: Z I g �� 7 Well ID: - l - (e5 Sampler(s): Well Location: Down �r a l' ) across PC, �-Cwl V U � Co�►rl Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 2 inches 9� feet Z�, 0D feet 0 9 feet [DTB-DTW] = 2- gallons = gallons gallons Actual Amount Purged/Bailed: 7• S"- gallons Purged with: Bailer Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp(° C) pH Cond. (µS/cm) DO (mg/L) ORP (mV) Turb.(ntu) Initials O 16S S{ZZ 7 ,( 0151 -13,Z {1 55 i 551 1(0. Z S, s� Z G�{ (o 2q . 3 55 0 I. 5 7 15, " , 05 Lo0, 9 0 -z, 7 .07 1o. 3 o Date of sample: Before Sampling �� �?j, , G i ��� J? Z. 7a -2, -, �, P Comments (weather conditions, odor, color, silt, etc.): Anl and fYk ft f led on ) Z/ti/ ►y, v U Signature: Date: L//ZD 1 S QA/QC Sign Off: Date: /L &J% .`. L.G DATE: L A LaBeLLa Company GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: O2 Well ID:. - Sampler(s): M, 6eA S vlebpdri; k- Well Location: X M - cs Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with 2 inches �. (c(p feet (0 C, W feet '10, feet [DTB-DTW] = 7 q gallons gallons = 25, 7 gallons 2 3- 7 Gallons Depth to Water before Sampling: feet Gallons Time Temp(° C) pH Cond. (µS/cm) DO (mg/L) OPP (mV) Turb.(ntu) Initials D lq q 5 I a y s- -7 -& 5_4 77,2 l��s �sDg 14.E z 3.64 -SO I'3-2 9,M 2_S.-7 1 - I q 45 92.g Z, 37 /y7 q.11 0-lei Date of sample: (2 Before Sampling 151 1 �. 5 ({j. t 5 p 7 Z-6 1 2. �-7 1-11-1,7 J Comments (weather conditions, odor, color, silt, etc.): 1 uJ2p uICcS .Sc/ilit i1 �ta�t Lr�S ir7 ' 04 Signature: Date: 2 QA/QC Sign Off: Date: —12-1 q t� C, klI Geer~ DATE: 12 / 31201 T &'u i `r ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. - Project/Task No.: Ll S i 1,-(5 7— Surface Point ID: SW-1 Sampler(s): R, N1eSu b,8 / . S)ebcJn; �- Location: Upstream of bridge on Quarry Rd. Field Parameters: Time of Sampling: PH: Temperature: 1735- 7, y3 t 1, 5- (°C) Conductivity: b Z - (µS/cm) Turbidity: I Z , 3 (ntu) Comments/Sample Description (weather conditions, odor, color, silt, etc.): _ wea7�_e; 1.vas Sijnriv -4-SD's ©►-t 1Z/ 3/���,�. Sketch of Sample Location (include flow direction, drainage pathways, etc.): Q LAur {fla.a �jf �qd Signature: , Date: 1 -Z � 3 / 2 G QA/QC Sign Off: Date: /Z// Y Az g DATE: 12 3 ZO P? ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. Project/Task No.:2J S i � 71- v-)-- Surface Point ID: SW-2 Sampler(s):_ R. Me-SuW / s- S1-ebCJY); k Location: Down stream of SW- 3 Field Parameters: Time of Sampling: 171 Z. PH: 7 3 6o Temperature: i 1 . (°C) Conductivity: 90• (µS/cm) Turbidity: Zo• % (ntu) Comments/Sample Description (weather conditions, odor, color, silt, etc.): / 2oi s . Signature: Lmmfib av- Date: 12 / 3 / 2 019 QA/QC Sign Off:.. Date: / 2 DATE: I Z1 y / ZD! S A®u MEE ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. Project/Task No.: 21 1 I •C'? Surface Point ID: SW-3 Sampler(s): P. McSu be8 z-S' S)ebod'i. Location: 24" pipe @ base of landfill along river Field Parameters: Time of Sampling: D S � pH: 6,79 Temperature: (°C) Conductivity: (µS/cm) Turbidity: 7 3 7 (ntu) Comments/Sample Description (weather conditions, odor, color, silt, etc.): u 2ea-S 5 u n o o 4- q D 's C.-, i z r-ZCLZ) SL4MK(-0- 09'0_S4o'► / z / H /zo16. Sketch of Sample Location (include flow direction, drainage pathways, etc.): re 5�- �s�- 3 Signature: fdWaz4 fy_ Date: 12/ �ZIOO)e QA/QC Sign Off: Date: /!?Z- IV Gz._ z O CD N o C) o (A OQI C�D 1 LI 3 VI ZCD N .ti 8 3 �o � i r � (D 'C C: � o aN 1.1��1NNN � w � w ww O (NppNO�-�oCc 65o 6` 10 7-- s a s a CD y 3- c—, b r R� 1� CJ a,� C. W Z O .-.. R 171 j~y Ww C.,f �,/ _ W W p i 0 0 a N C. F-� iJ p cn 'C r" b CD CD Q. � z o o o R z � CD j �N FIE Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A24 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Background Downgradient Location MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 3 0-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3 -Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level. All depths measured in feet below TOC. MW-6S and MW-61) TOC Elevations are estimated. MW-31) exhibits artesian conditions. MW-1 damaged approx. June 2017 Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 µg/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 µg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA 6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 3.9 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 1 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND I-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NOL = 50 µg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC2L = 10 µg/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-I1 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 2 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NOL = 2,000 µg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC2L = 700 µg/L, (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-I1 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 NS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1040 388 167 82 J 28 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 --- 1470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 --- 1240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 --- 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 --- 1160 507 205 82 27.1 42.6 12.8 ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 3 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 µg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-I1 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 4 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 1.75 µg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC2L = 2 µg/L,(01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-I1 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND NS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- 2 0.78 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 5 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 50 µg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC2L = 10 µg/L, (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-I1 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND 3.4 J ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 6 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 µg/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 µg/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-I1 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- 102 20.2 ND ND ND 4.2 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- 120 17.3 2.6 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 7 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC2L = 1,000 µg/L, (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-I1 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND NS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 8 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NOL = 15 µg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 9 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC2L = 100 µg/L, (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-I1 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND NS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 --- 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 --- 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 --- 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- 17.2 4.3 J 26.3 ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 10 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NOL = 50 µg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC2L = 20 µg/L, (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 11 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NOL = 17.5 µg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC2L = 20 µg/L, (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-I1 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 12 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 µg/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 µg/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND {4.81 J ND ND 4.0 {ND1 J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-I1 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 0.0 5.5 --- ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6020B 0.03 0.1 --- ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6020B 0.06 0.1 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 13 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 µg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 µg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-I1 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND NS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 --- 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 --- 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 --- 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND 3.0 J ND 6.0 ND ND ND ND Resample --> 8-Feb-19 EPA 6010D 2.5 5.0 --- --- --- --- ND --- --- --- --- Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 14 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NOL = 1,050 µg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC2L = 1,000 µg/L, (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-I1 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 12.7 ND 5.3 J ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 15 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Organic Compounds Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC2L = 700 µg/L (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC2L = 6,000 µg/L, (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-I1 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 --- ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 --- 484 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 10.0 25 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 16 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NOL = 1 µg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-I1 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 NS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 --- 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 --- 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 --- 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 --- 7.5 3.8 1.3 ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 17 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC2L = 700 µg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-I1 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 1.2 2 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 18 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NOL = 50 µg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-I1 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 --- 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 --- 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 --- 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.23 1.0 --- 23.7 34.4 7.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 19 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 2,800 µg/L, (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NOL = 3,000 µg/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-I1 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J NS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 --- ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 --- ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.54 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 20 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC2L = 70 µg/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 l 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 l 19-Dec-I1 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.14 1.0 --- ND ND ND ND ND ND ND ND Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC2L = 2.6 µg/L, (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC2L = 3 µg/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 --- 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.11 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 21 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC2L = 24 µg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC2L = 20 µg/L, (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-I1 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J NS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 --- 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 --- 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 --- 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 2.2 0.91 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 22 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 14-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NOL = 1.4 µg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC2L = 6 µg/L, (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-I1 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 NS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 --- 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 --- 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 --- 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 --- 39.9 14.8 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 23 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 1, 1 -Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NOL = 70 µg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC2L = 6 µg/L, (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-I1 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J NS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 --- 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 --- 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 --- ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 --- 0.37 J 0.46 J 4.0 1.1 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 24 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC2L = 0.4 µg/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-I1 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.24 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 25 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 1, 1 -Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC2L = 7 µg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 2L = 350 µg/L (04/O1/2013) 11-Jun-13 0.56 5.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.56 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 26 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 PA 8260B Mop 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND NC 2L = 3 µg/L cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NOL = 70 µg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J NS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 --- 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 --- 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 --- ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 --- 0.30 J ND 10.8 5.8 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 27 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NOL = 100 µg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J NS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.49 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 28 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NOL = 0.51 µg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC2L = 0.6 µg/L, (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-I1 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 --- ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 --- ND ND 0.94 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 29 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NOL = 550 µg/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC2L = 600 µg/L, (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-I1 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 NS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 --- 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 --- 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 --- 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 10.7 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 30 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 µg/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-I1 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 --- 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.46 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 31 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Iodomethane 11-Jun-13 0.32 10.0 ND ND ND NS ND 7.4 J ND ND ND NC2L = NE µg/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND NO 4-Dec-18 EPA 8260B 0.32 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 32 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 4.6 µg/L, (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC2L = 5 µg/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.97 1.0 --- ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA 8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.97 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 33 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC2L = 4,200 µg/L, (10/23/07) 28-Nov-07 NR 100 18.0 JD ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC2L = 4,000 µg/L, (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.96 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.96 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.96 100 --- 268 ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.96 5 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 34 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 µg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-I1 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 --- 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.33 5 --- 2.7 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 35 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 µg/L, (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-I1 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND NS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 --- ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 --- ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 --- ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 --- ND ND 6.6 1.2 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 36 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NOL = 1,000 µg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC2L = 600 µg/L, (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-I1 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 NS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND --- 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 --- 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 --- 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 --- 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.26 1.0 --- 0.9 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 37 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 µg/L, (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC2L = 3 µg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-I1 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND NS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 --- ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 --- ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 --- ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 --- ND ND 4.7 0.66 J ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 38 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC2L = 0.015 µg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC2L = 0.03 µg/L, (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-I1 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND NS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 --- ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 --- ND ND 1.2 ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 39 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW4 MW-5 MW-6S MW-613 Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NOL = 530 µg/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC2L = 500 µg/L, (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-I1 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 NS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 --- 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 --- 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 --- 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.66 1.0 --- 21.4 28.00 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 40 of 41 TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW4 MW-5 MW-6S MW-61) Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND NS ND ND ND ND ND GWPS = 0.6 µg/L (10/23/07) 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.58 2.0 --- ND ND ND ND ND ND ND NO 4-Dec-18 EPA 8260B 0.29 1.0 ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. NS = Not sampled. NE = Not established. NR = Not reported. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the DENR-SWS for constituents with no listed NC21, standard.. Bold values are greater than the NC2L Groundwater Standards or GWPS. Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 41 of 41 TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Well Depth [ft] -- 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at25c) I1-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [MS/CM] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 ill 24.6 66.6 115.9 26-Jun-17 -- 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 2185.0 920 875 99 25 97 114 14-May-18 -- 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample--> 8-Feb-19 -- -- -- -- 55.9 -- -- -- PH 11-Jun-13 5.9 6.1 6.36 -- 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 -- 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 -- 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample--> 8-Feb-19 -- -- -- -- 5.64 -- -- -- Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 [°C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 -- 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample--> 8-Feb-19 -- -- -- -- 15.2 - -- -- Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 -- 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample--> 8-Feb-19 -- -- - 7.96 -- -- -- Notes: °C= degrees Centigrade S.0 = Standard Units µS = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet Burke County, Kirksey, Drive Landfill Joyce Engineering Pemrit No. 12-01 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks INORGANIC COMPOUNDS Arsenic 28-Jun-95 NR 5 ND ND 10.0 NA 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 µg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.5 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.2 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.8 J NC2B = 1,000 µg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.3 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.7 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 2.5 100 38.1 J 38.0 J 301 2.5 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 2.5 5 33.1 32.0 267 ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR l ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 µg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 1.0 1.0 ND ND ND ND 21-Oct-14 1.0 1.0 ND ND ND ND 19-May-15 0.5 1.0 ND ND Dry NA 7-Dec-15 0.5 1.0 ND ND ND ND 2-May-16 0.5 1.0 ND ND ND ND 12-Dec-16 0.5 1.0 ND ND NS ND 26-Jun-17 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 0.5 1.0 ND ND ND ND 4-Dec-18 0.5 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR I ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.0 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 1 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC213 = 20 µg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 5.0 10.0 ND ND 6.3 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.3 J ND 2-May-16 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 2.8 J ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC2B=NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 6.0 J ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 3.6 J ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 µg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 5.0 10.0 ND ND 6.4 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.0 J ND 2-May-16 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 1 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 µg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 4.1 J ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND ND 4.6 B 2.2 J NC213 = 25 µg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 5.0 50.0 ND ND 10.4 J ND 19-May-15 2.5 50.0 ND ND Dry NA 7-Dec-15 2.5 50.0 ND ND 5.1 J ND 2-May-16 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 2.5 50.0 ND ND NS ND 26-Jun-17 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 2.5 50.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 5.9 ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC213 = 5 µg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND ND ND 21-Oct-14 10.0 10.0 ND ND ND ND 19-May-15 5.0 10.0 ND ND Dry NA 7-Dec-15 5.0 10.0 ND ND ND ND 2-May-16 5.0 10.0 ND ND ND ND 12-Dec-16 5.0 10.0 ND ND NS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC2B = 0.06 µg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND Thallium 4-Dec-18 0.1 0.1 ND ND 0.077 J Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Vanadium 19-Nov-03 NR 40.0 62 56 60 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC2B=NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8.0 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 5.0 25.0 ND ND ND ND 21-Oct-14 5.0 25.0 ND ND ND ND 19-May-15 2.5 25.0 ND ND Dry NA 7-Dec-15 2.5 25.0 ND ND ND ND 2-May-16 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 2.5 25.0 ND ND NS ND 26-Jun-17 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 2.5 25.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 µg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13.0 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND 10.3 ND 21-Oct-14 10.0 10.0 ND ND 18.0 ND 19-May-15 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND 7.4 J ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Organic Compounds Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B=NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 10.0 100 ND ND 17.6 J ND 21-Oct-14 10.0 100 ND ND ND ND 19-May-15 10.0 100 ND ND Dry NA 7-Dec-15 10.0 100 ND ND ND ND 2-May-16 10.0 100 ND ND ND ND 12-Dec-16 10.0 100 ND ND NS ND 26-Jun-17 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 10.0 100 ND ND ND ND 4-Dec-18 10.0 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 µg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 0.25 1.0 ND ND ND ND 21-Oct-14 0.25 1.0 ND ND ND ND 19-May-15 0.25 1.0 ND ND Dry NA 7-Dec-15 0.25 1.0 ND ND ND ND 2-May-16 0.25 1.0 ND ND ND ND 12-Dec-16 0.25 1.0 ND ND NS ND 26-Jun-17 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 0.25 1.0 ND ND ND ND 4-Dec-18 0.25 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 0.29 10.0 ND ND 4.6 J ND NC2B=NE (05/01/2007) 21-Oct-14 0.29 10.0 ND ND 0.41 J ND 19-May-15 0.29 10.0 ND ND Dry NA 7-Dec-15 0.29 10.0 ND ND ND ND 2-May-16 0.29 10.0 ND ND ND ND 12-Dec-16 0.29 10.0 ND ND NS ND 26-Jun-17 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 0.29 10.0 ND ND ND ND 4-Dec-18 0.29 2.0 ND ND ND ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 µg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 0.23 3.0 ND ND ND ND 21-Oct-14 0.23 3.0 ND ND ND ND 19-May-15 0.23 3.0 ND ND Dry NA 7-Dec-15 0.23 3.0 ND ND ND ND 2-May-16 0.23 3.0 ND ND ND ND 12-Dec-16 0.23 3.0 ND ND NS ND 26-Jun-17 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 0.23 3.0 ND ND ND ND 4-Dec-18 0.23 1.0 ND ND ND ND Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B=NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 0.11 1.0 ND ND ND ND 21-Oct-14 0.11 1.0 ND ND 0.19 J ND 19-May-15 0.11 1.0 ND ND Dry NA 7-Dec-15 0.11 1.0 ND ND ND ND 2-May-16 0.11 1.0 ND ND ND ND 12-Dec-16 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 0.11 1.0 ND ND ND ND 4-Dec-18 0.11 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 µg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 0.30 5.0 ND ND ND ND 21-Oct-14 0.30 5.0 ND ND ND ND 19-May-15 0.30 5.0 ND ND Dry NA 7-Dec-15 0.30 5.0 ND ND ND ND 2-May-16 0.30 5.0 ND ND ND ND 12-Dec-16 0.30 5.0 ND ND NS ND 26-Jun-17 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 0.30 5.0 ND ND ND ND 4-Dec-18 0.30 1.0 ND ND ND ND 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 µg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 0.33 1.0 ND ND ND ND 21-Oct-14 0.33 1.0 ND ND ND ND 19-May-15 0.33 1.0 ND ND Dry NA 7-Dec-15 0.33 1.0 ND ND ND ND 2-May-16 0.33 1.0 ND ND ND ND 12-Dec-16 0.33 1.0 ND ND NS ND 26-Jun-17 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 0.33 1.0 ND ND ND ND 4-Dec-18 0.33 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks 1, 1 -Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NC2B=NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 0.32 5.0 ND ND ND ND 21-Oct-14 0.32 5.0 ND ND ND ND 19-May-15 0.32 5.0 ND ND Dry NA 7-Dec-15 0.32 5.0 ND ND ND ND 2-May-16 0.32 5.0 ND ND ND ND 12-Dec-16 0.32 5.0 ND ND NS ND 26-Jun-17 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 0.32 5.0 ND ND ND ND 4-Dec-18 0.32 1.0 ND ND ND ND cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 1 NC2B=NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 0.19 5.0 ND ND ND ND 21-Oct-14 0.19 5.0 ND ND ND ND 19-May-15 0.19 5.0 ND ND Dry NA 7-Dec-15 0.19 5.0 ND ND ND ND 2-May-16 0.19 5.0 ND ND ND ND 12-Dec-16 0.19 5.0 ND ND NS ND 26-Jun-17 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 0.19 5.0 ND ND ND ND 4-Dec-18 0.19 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B=NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 0.27 1.0 ND ND ND ND 21-Oct-14 0.27 1.0 ND ND ND ND 19-May-15 0.27 1.0 ND ND Dry NA 7-Dec-15 0.27 1.0 ND ND ND ND 2-May-16 0.27 1.0 ND ND ND ND 12-Dec-16 0.27 1.0 ND ND NS ND 26-Jun-17 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 0.27 1.0 ND ND ND ND 4-Dec-18 0.27 1.0 ND ND ND ND 1,4-Dioxane (p-Dioxane) 4-Dec-18 1.90 2.0 ND ND 10.5 ND Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 µg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 0.46 1.0 ND ND ND ND 21-Oct-14 0.46 1.0 ND ND ND ND 19-May-15 0.46 1.0 ND ND Dry NA 7-Dec-15 0.46 1.0 ND ND ND ND 2-May-16 0.46 1.0 ND ND ND ND 12-Dec-16 0.46 1.0 ND ND NS ND 26-Jun-17 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 0.46 1.0 ND ND ND ND 4-Dec-18 0.46 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 µg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 0.47 1.0 ND ND ND ND 21-Oct-14 0.47 1.0 ND ND ND ND 19-May-15 0.47 1.0 ND ND Dry NA 7-Dec-15 0.47 1.0 ND ND ND ND 2-May-16 0.47 1.0 ND ND ND ND 12-Dec-16 0.47 1.0 ND ND NS ND 26-Jun-17 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 0.47 1.0 ND ND ND ND 4-Dec-18 0.47 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 17 of 18 TABLE A24: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC2B = 0.025 µg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 0.62 1.0 ND ND ND ND 21-Oct-14 0.62 1.0 ND ND ND ND 19-May-15 0.62 1.0 ND ND Dry NA 7-Dec-15 0.62 1.0 ND ND ND ND 2-May-16 0.62 1.0 ND ND ND ND 12-Dec-16 0.62 1.0 ND ND NS ND 26-Jun-17 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 0.62 1.0 ND ND ND ND 4-Dec-18 0.62 1.0 ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. NS = Not sampled. NE = Not established. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). Dry = Surface water point was considered to be dry and no sample collected. NC2B = 15A NCAC 2B Surface Water Standards. Bold values are greater than the NC2B. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. *May 2016>> NC2B= 24.84 µg/L in SW-3 based on in -stream hardness= 330 mg/L Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01 Page 18 of 18 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25c) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 H 11-Jun-13 7.8 8.25 7.81 [standard units] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 Temperature 11-Jun-13 19.2 18.1 19.7 [°C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14 -May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 Notes: °C= degrees Centigrade S.0 = Standard Units µS = microsemens per cm NTU = Nephelometric Turbidity Units *= resample Burke County, Kirksey Drive Landfill Joyce Engineering Permit No. 12-01