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HomeMy WebLinkAbout1302_Cabarrus_Units2_3_MSWLF_GW_FID1285477_20190227Cabarrus County Sanitary Landfill -Units 2 and 3 Semi -Annual Sampling Report Facility Permit # 1302-MSWLF- CDLF-1998 (December 2018 Sampling Event) Prepared February 2019 ENR USE ONLY: ❑Paper Rappr ❑Electronic Data -Email CD (data loatletl: Ves/No) OorJEvent#: c DENR Environmental Monitoring Division of Waste Management -Solid Waste Reporting Form Notice: This farm and any Information attached to it are °Public Records" as definetl In NC Generel StaWte 132-1. As such, these dowmants ate available for inspection and examination by any person upon request (NC General Statute 132-8). InetruOflOnS: • Prepare one form for each lntllvltlually moni[oretl unit. • Please type or print legibly. • Attach a notification table with values that enaln or exceed NC 2L groundwater standards or NC 2B surface water standads. The notification must Include a preliminary analysis of the cause and significance of each value. (e.g. naWrelly occuMng, off -site source, preexisting wndition, etc.). • Auachanotification fable of any groundwater or surface water values that equal or exceetl the reporting limits. AdaW a notifipgon table of any methane gas values that again ar exceetl explosive gas levels. This inclutles any structures an or nearby the facility (NCAC 13B .1629 (4J(a)(I). Sentl the original signed antl sealed farm, any tables, and Electronic Data Dellvemble to: Compliance Unit, NWENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 2]699-1646. Solid Waste Monitoring Data Submittal Information Name of en[Ity submitting data (laboratory, consultant, facility owner) Consultant - GDM Smith Inc. Content for questions about data formatting. Include daU preparer's name, telephone number and Email adtlress: Name: Mathew F. Colone Phone: (9191325-3500 E-mail: rnlnnamtrardmamithrnm NC Landfill Rule: AGuel sampling dates (e.g., Fatality name: Facility Address: Facility Permit# (.0500 ar.1600) OGober 20-24, 2006) Cabarms Ccunty Landfill Units 2 4441 Irish Potato Road 1902-MSWLF- .0500 and .1800 December 1]-20, 2018 and3 Concord, North Carolina 28025 CDLF-1998 Environmental Status: (Check all that apply) ❑ Inlllall6ackground Monitoring Q Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action T eof data eubmittetl: (Check all that apply) X Groundwater manlWring data from monitoring walla ❑X Methane gas mpnlWring data Greuntlwater menitorng tlata from private water supply wells ❑X Coractive action tlata (speGfy) MNA Data Leachate monitoring tlata Ggier(specify) X Surface water monibdng data ❑ NotlFlcaHon atYachedT No. No groundwater or surface water stantlartls were exceetletl. X Ves, a notification of values exceeding a grountlwater or surtace water stantlard is attached. It inclutles a list of groundwater and surface water pnitoring points, dates, analytical values, NC 2L groundwater stantlard, NC 2B surtace water standard or NC Solid Waste GNPS antl preliminary analysts of the cause and signifcance of any concentration. ❑ Ves, a nogfication of values exceeding an explosive methane gas limit is aHachetl. It includes the methane monitoring points, tla[es, sample values and explosive methane gas limits. Certification To the hest of my knowletlge, the Information reportetl antl statements matle on this tlata submittal antl attachments are true antl correct. Furthermore, I have atached complete notiFlcatlon of any sampling values meeting or ezceeding groundwater stantlartls or explosive gas levels, antl a preliminary analysis of the cause and significance of concentrations ezceeding grountlwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification inclutling the possibility of a fine and imprisonment. Afix NC Signature Date 5400 Glerxwood Avenue. Suite 4n9. Raleigh. North Carolina 2]612 Facility Representative Address NC PE Firm License Number (If applicable efiective Revisetl 6I2009 Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 February 22, 2019 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: December 2018 Semi -Annual Sampling Report Cabarrus County Landfill Units 2 and 3 Facility Permit Numbers 1302-MSWLF-CDLF-1998 Dear Ms. Drummond: CDM Smith Inc. (CDM Smith), on behalf of Cabarrus County, is submitting an electronic copy of the December 2018 semi-annual sampling event report. This letter report presents the results of the recently completed sampling at Units 2 and 3 of the Cabarrus County Landfill and constitutes the second semi-annual sampling event for 2018. The approved groundwater monitoring network consists of the following wells: MW-1, -3, -3 deep, -A, -B, -C, -D, -E Rep, -E deep, -F, -G, -H, -H deep, -I, -J, -K, -L, -L deep, -M, -X, CD-4 Rep, assessment wells AMW-1s, -1d, -2s, and -2d, and background wells CD -Is and CD-1d. Surface water sample locations include SW-1 and -2, which also monitor the Unit 1 Landfill. Assessment wells AMW-1s, -1d, -2s, and -2d were added to the groundwater monitoring network in October 2009 as part of the Corrective Action Plan (CAP) implementation. CD-4 Rep was installed in January 2009 as part of the proposed Phase I C&D Landfill expansion. Assessment wells CD-4, -5, and -6 were added to the groundwater monitoring network in September 2006 during the Phase I C&D Landfill expansion. Assessment wells CD-4 and -5 were abandoned in July 2010 in preparation of the Phase 2 C&D Landfill expansion. Assessment well CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Field activities, sampling and landfill gas screening results, and an evaluation of corrective action activities are discussed below. Field Activities Groundwater and surface water samples from Units 2 and 3 of the Cabarrus County Landfill were collected on December 17-20, 2018. Samples are collected from MW-3 deep, -L deep, and -M annually during the spring event. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated TeflonT" bailers or a QED bladder pump system using low -flow Of WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond February 22, 2019 Page 2 sampling techniques. Monitoring well and surface water locations for Units 2 & 3 are provided on Figure 1. Construction details for each monitoring well are summarized in Table 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 2. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. Groundwater elevations from MW-3 deep, -L deep, and -M were measured on January 18, 2019, and were not used for the potentiometric surface interpretation. The groundwater elevations and potentiometric contours were used to estimate groundwater velocities at each well, which are presented in Table 3. After depth to groundwater was measured, three well volumes of water were removed from each well prior to sampling to provide fresh formation water within the well water column. Low -flow sampling techniques were used to purge and sample wells used to monitor natural attenuation. Each well volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen (DO), and oxidation-reduction potential (ORP) using a YSI Pro Plus multi - parameter water quality meter and Micro TPI or TPW turbidity meters. Wells with elevated turbidity were allowed to settle prior to sampling. The water quality parameters at the time of sampling are presented in Table 4. The headspace of each monitoring well was screened for methane gas using a RKI Eagle multi -gas monitor. Screening results are provided in Appendix A. Sampling Results Pace Analytical Services, Inc., located in Peachtree Corners, Georgia, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs), including 1,4-dioxane, and metals. Samples collected from CD -Is and -1d were also analyzed for tetrahydrofuran, iron, mercury, manganese, alkalinity, chloride, sulfate, and total dissolved solids (TDS). Samples for the North Carolina Appendix II constituent, bis (2-ethylhexyl) phthalate, are collected annually during the spring sampling event. Additional groundwater samples were collected to evaluate the effectiveness of natural attenuation and the Phase II injection event and are discussed in the Corrective Action Evaluation section of this letter report. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for Units 2 and 3 with detections of analytes above the MDL but below the MRL were qualified as estimated or "J" flags. The following list indicates the analytes detected above the MRL at each sampling location. No "J" flag or general chemistry detections are provided. Underlined analytes exceeded the 15A NCAC 02L .020 (NC 2L) Groundwater Quality Standard, Interim Maximum Allowable Concentration (IMAC), or the 15A NCAC 02B or North Carolina Protective Value Surface Water Quality Standard for Class C Waters. 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 3 CD-1s (Background) Metals: Chromium, Iron, Manganese Volatile Organic Compounds: Methylene Chloride CD-1d (Background) Metals: Iron, Manganese Volatile Organic Compounds: None Detected CD-4 Rep Metals: Zinc Volatile Organic Compounds: None Detected AMW-1s Metals: None Detected Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Methylene Chloride, Tetra chloroethene, Trichloroethene AMW-1 d Metals: Barium Volatile Organic Compounds: Benzene, 1,4-Dichlorobe nzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene, Trichloroethene, Vinyl Chloride AMW-2s Metals: None Detected Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethe Trichloroethene AMW-2d Metals: None Detected Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene, Tetra chloroethene, Trichloroethene MW-1 Metals: Barium, Cobalt Volatile Organic Compounds: 1,4-Dioxane MW-3 Metals: None Detected Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethene, Trichloroethene 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 4 MW-3 Deep Metals: Not Sampled Volatile Organic Compounds: Not Sampled MW-A Metals: None Detected Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane, 1,2-Dichloroethane cis- 1,2-Dichloroethene, 1,2-Dichloropropane, Tetrachloroethene, Trichloroethene MW-8 Metals: Barium, Zinc Volatile Organic Compounds: 1,4-Dioxane MW-C Metals: None Detected Volatile Organic Compounds: None Detected MW-D Metals: Barium, Cobalt Volatile Organic Compounds: Benzene, 1,4-Dichlorobe nzene, cis-1,2-Dichloroethene, Trichloroethene MW-E Rep Metals: Barium Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene, cis-1,2-Dichloroethene, 1,4-Dioxane, Vinyl Chloride MW-E deep Metals: Barium, Cobalt Volatile Organic Compounds: Benzene, Chloroethane, 1,4-Dichlorobenzene, IA-Dioxane MW-F Metals: Barium Volatile Organic Compounds: 1,4-Dioxane MW-G Metals: Barium Volatile Organic Compounds: 1,4-Dioxane 0 cSmith Ms. Jaclynne Drummond February 22, 2019 Page 5 MW-H Metals: Zinc Volatile Organic Compounds: None Detected MW-H deep Metals: None Detected Volatile Organic Compounds: None Detected MW-1 Metals: None Detected Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene, Methylene Chloride, Tetrachloroethene, Trichloroethene MW-J Metals: None Detected Volatile Organic Compounds: None Detected MW-K Metals: None Detected Volatile Organic Compounds: None Detected MW-L Metals: None Detected Volatile Organic Compounds: None Detected MW-L Deep Metals: Not Sampled Volatile Organic Compounds: Not Sampled MW-M Metals: Not Sampled Volatile Organic Compounds: Not Sampled MW-X Metals: None Detected Volatile Organic Compounds: None Detected SW-1 Metals: None Detected Volatile Organic Compounds: 1,4-Dioxane, Methylene Chloride Smith Ms. Jaclynne Drummond February 22, 2019 Page 6 SW-2 Metals: None Detected Volatile Organic Compounds: 1,4-Dioxane, Methylene Chloride "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Cobalt: CD-4 Rep, AMW-1d, MW-A, -B, -E Rep, -F, -G, and -H Thallium: MW-K Vanadium: CD-1s, -1d, -4 Rep, AMW-1s, -1d, MW-1, -3, -D, -G, -H, -H Deep, -I, -J, -K, and -X 1,2-Dichloropropane: MW-E Rep Vinyl Chloride: MW-D A trip blank, equipment blank, and duplicate sample were analyzed for quality control. Methylene chloride was detected in the equipment and trip blanks below its NC 2L Standard. The duplicate sample, identified as Dup, was collected from MW-F and had similar analyte concentrations as those detected in MW-F, with the exception of an estimated detection of methylene chloride in the duplicate sample below its NC 2L Standard. Metals detected above the standards are likely natural occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. A summary of detected constituents from the May 2011 to the December 2018 sampling events is presented in Table S. Laboratory analytical reports are provided in Appendix A. Corrective Action Evaluation In December 2008, CDM Smith, on behalf of the County, submitted an Assessment of Corrective Measures Report to the Solid Waste Section (SWS) for the closed landfill Units 2 and 3 in accordance with North Carolina Solid Waste Management Rule 15 NCAC 13B .1635. Monitored natural attenuation and institutional controls paired with in situ remediation by enhanced bioremediation was selected as the remedy to address groundwater contamination by select VOCs at the facility. In situ remediation efforts were to be focused on the bedrock contamination near monitoring wells MW-E Rep and -E deep. Groundwater contamination in the area of MW-E deep is caused by migration of leachate from the closed landfill Units 2 and 3 downward into the shallow fractured bedrock, thereby allowing low-level VOCs to migrate into this area prior to being attenuated below NC 2L Standards. Following approval of the CAP in September 2009 and the Phase I injection permit, six injection wells were installed upgradient of the MW-E cluster in October 2009 as shown on Figure 2. A 3% solution of potable water and EOS® 450, which is an emulsion of soybean oil and water, was injected 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 7 simultaneously into the injection wells from November 2-6, 2009. A total of 38,100 gallons of the solution were injected with each well receiving approximately 6,350 gallons. The initial injection of EOS®450 successfully degraded PCE and TCE to daughter products in the injection area and neither compound has been detected above the NC 2L Standards in MW-E deep since the Phase I injection in November 2009. It was assumed that the EOS® 450 would be viable for a period of 3 to 5 years. However, samples collected from the MW-E cluster and wells downgradient of the injection area during the November 2013 sampling event showed that groundwater contaminant concentrations had increased and levels exceeding the applicable NC 2L Standards had been detected in monitoring wells near the property line. Due to the increasing downgradient contaminant concentrations and NC 2L exceedances near the property line, the groundwater conditions were re-evaluated in accordance with the CAP and a Phase II injection was implemented. In order to assess the biological conditions in the injection area prior to initiating the Phase II injection, groundwater samples were collected from MW-E Rep, -E deep, AMW-1s, -1d, -2s, and -2d in January 2014 and analyzed for Deholococcoides spp (DHC), the bacteria responsible for degrading the chlorinated ethene species of VOCs. The specific genes of the bacteria that promote dechlorination were also analyzed. Analytical results for the DHC analyses are summarized in Table 7 and show that a sufficient population exists at monitoring wells MW-E, -E deep, and assessment monitoring well AMW-2s for reductive dechlorination by enhanced anaerobic bioremediation. DHC was detected at low concentrations in assessment monitoring wells AMW-1d and -2d and was not detected at AMW-1s. The absence of DHC at AMW-1s is likely associated with relatively low VOC concentrations. Following approval of the injection permit in January 2014, the Phase II injection was completed from February 10-18, 2014, using potable water and a 10% solution of 60% SRS®-FR large droplet emulsified vegetable oil substrate. SRS®-FR is specifically designed for use in fractured bedrock environments and is a mixture of 60% emulsified vegetable oil, 20% water, 5-15% of proprietary emulsifiers and nutrients, and 5% sodium lactate. The nutrient component of SRS®-FR further enhances the microbial population growth. A total of 9,966 gallons of the solution were injected during the Phase II event with each well receiving approximately 1,661 gallons. In order to monitor the progress of the Phase II injection and the geochemical and biological response of the aquifer, groundwater samples were collected quarterly from monitoring wells MW-E Rep and -E deep and assessment wells AMW-1s, -1d, -2s, and -2d. The first and third quarterly sampling events were completed in conjunction with the May and November 2014 semi-annual sampling events respectively. The second quarterly sampling event was completed in August 2014 and the fourth quarterly sampling event was completed in March 2015. A 15-month post -injection sampling event was completed in May 2015. 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 8 Water quality measurements of pH, temperature, ORP, DO, conductivity, turbidity, and ferrous iron were collected during each sampling event. In addition, the quarterly samples were submitted to an analytical laboratory for analysis of nitrate, sulfate, alkalinity, chloride, chemical oxygen demand (COD), VOCs, dissolved gases (i.e. methane, ethane, ethene, carbon dioxide), and metabolic acids (i.e. acetic acid, butyric acid, lactic acid, propionic acid, and pyruvic acid). North Carolina Appendix I metals were collected during events that corresponded with the semi-annual sampling program. Additional samples were collected during the fourth quarterly sampling event (March 2015) from monitoring wells MW-E Rep and -E deep and assessment wells AMW-1s, -1d, -2s, and -2d and analyzed for DHC to assess the biological conditions in the injection area after initiating the Phase II injection. A sufficient population of DHC existed at assessment monitoring well AMW-1d for reductive dechlorination by enhanced anaerobic bioremediation and DHC was detected at low concentrations in monitoring well MW-E deep. Detections of DHC in AMW-1d indicated a healthy population of DHC in the primary bedrock treatment zone surrounding the injection wells. DHC detections in MW-E deep was an indication that active treatment in bedrock was also occurring downgradient. DHC was not detected at MW-E Rep, AMW-1s, -2s, or -2d and was likely due to reduced VOC concentrations from upgradient treatment. Analytical results for the DHC analyses are summarized in Table 7. On September 28, 2015, a report summarizing the results of the Phase II injection was submitted to the SWS. The report stated that the Phase II injection of emulsified vegetable oil replenished the carbon source and complete reductive dechlorination is occurring at MW-E, -E Deep, and AMW-1d. The presence of DHC populations and functional genes in MW-E Deep and AMW-1d demonstrate that the treatment process is capable of achieving complete chlorinated VOC degradation as long as a sufficient carbon donor is present. As part of the semi-annual monitoring program, additional groundwater samples were collected from the background well CD-1s; monitoring wells MW-A, -E Rep, -E deep, -L, and -3; and assessment wells AMW-1s, -1d, -2s, and -2d. Samples were analyzed for alkalinity, biochemical oxygen demand, COD, carbon dioxide, chloride, dissolved hydrogen, ethane, ethene, volatile fatty acids (i.e. acetic, butyric, hexanoic, lactic, pentanoic, propionic, and pyruvic), ferrous iron, methane, nitrate, sulfate, sulfide, and total organic carbon. Note that ferrous iron was analyzed in the field using a Hach test kit due to the short hold time of 15 minutes. These additional samples were collected to evaluate natural attenuation and the effectiveness of the Phase II injection as part of the CAP. A complete summary of the geochemical results is provided in Table 5. Contaminant concentration trends for MW-A, -3, -E Rep, -E deep, AMW-1s, -1d, -2s, and -2d were evaluated to determine the effectiveness of natural attenuation and the Phase II injection. Figures 3 through 10 present total VOC contaminant concentration data for each well. An isoconcentration contour map with data from the December 2018 sampling event is provided on Figure 11. 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 9 The total VOC trend analysis for MW-A is presented on Figure 3. Total VOC concentrations increased in MW-A between June 1995 and April 2003 and decreased after the April 2003 event. Between the May 2011 and December 2018 events, total VOC concentrations show a fluctuating trend. Figure 4 presents the total VOC trend analysis for MW-3. Total VOC concentrations show an increasing trend. 1,1-Dichloroethane, PCE, and TCE are the only analytes that have been detected in MW-3 above the NC 2L Standards. The geochemical data indicates aerobic conditions at MW-3. VOC concentrations in MW-3 deep have never been detected above the standards. The total VOC trend analyses for MW-E Rep and -E deep are presented on Figures 5 and 6, respectively. Total VOC concentrations in MW-E Rep and -E deep have decreased since the November 2009 Phase I injection. PCE and TCE have not been detected above the NC 2L Standards in MW-E deep since the Phase I injection and have not been detected above the MDL since the August 2010 sampling event. Delivery of the carbon substrate (i.e. SRS®-FR) during the Phase II injection was effective based on the increase in COD at MW-E deep. Historical geochemical data shows reducing conditions exist at the MW-E cluster based on low DO, a negative ORP, and high methane concentrations. The increase in metabolic acids and ferrous iron at MW-E deep also indicates that a reducing subsurface environment exists. A geochemically reducing environment is favorable for anaerobic reductive dechlorination. Figures 7 and 8 present the total VOC trend analyses for assessment wells AMW-1s and -1d, respectively. Total VOC concentrations in AMW-1s show an increasing trend from November 2010 to May 2013 but show a decreasing trend from the May 2013 to the November 2017 sampling event. Total VOC concentrations slightly increased from November 2017 to December 2018. Total VOC concentrations in AMW-Id show a decreasing trend from the initial sampling in October 2009 to the December 2018 sampling event. Historical data shows reducing conditions exist at AMW-1d but DO and ORP were elevated during the October 2017 and June 2018 sampling events. The concentration of vinyl chloride has generally increased since the Phase II injection while the concentration of TCE has decreased, indicating anaerobic reductive dichlorination is occurring as vinyl chloride is a daughter product of TCE. The total VOC trend analyses for AMW-2s and -2d are presented on Figures 9 and 10, respectively. Total VOC concentrations at AMW-2s show an increasing trend between the initial sampling event in October 2009 and November 2014 but have fluctuated since the November 2014 sampling event. Total VOC concentrations show an increasing trend at AMW-2d since the November 2010 sampling event but have fluctuated since the Phase II injection was completed in February 2014. The AMW-2 cluster is located farthest downgradient of the injection area and the shallow well is screened in partially weathered rock. Geochemical results indicate an aerobic subsurface environment. 0 Smith Ms. Jaclynne Drummond February 22, 2019 Page 10 Landfill Gas Monitoring The approved landfill gas monitoring network consists of monitoring wells MGW-1 through -16. Site structures that are monitored on the property include the scale house, maintenance shop, electricity building, and recycling facility. Quarterly landfill gas monitoring of Units 2 and 3 was completed on September 17 and December 12, 2018, using a GEM 5000 landfill gas analyzer. Methane was detected in monitoring well MGW-3 during the September and December monitoring events at 0.6 and 3.2 percent, respectively. No hydrogen sulfide was detected in any monitoring wells or site structures during the monitoring events. Copies of the quarterly landfill gas monitoring results and equipment calibration data have been placed in the landfill operating record and are provided in Appendix B. Recommendations Units 2 and 3 of the Cabarrus County Landfill are unlined and are the source of VOC concentrations that are above the NC 2L Standards in downgradient monitoring wells. The injection remedy successfully reduced the contaminant concentrations in bedrock monitoring well MW-E deep and developed a primary VOC treatment zone in the vicinity of the injection wells and MW-E Rep. Downgradient VOC concentrations in bedrock and saprolite should continue to decrease due to reduced VOC concentrations in the primary treatment zone. Additional injections will be necessary in the future once all electron donors have been consumed and complete dechlorination stalls. The County will continue with the semi-annual assessment monitoring program. In addition to sampling for Appendix I VOCs, including 1,4-dioxane, and metals, and the Appendix II constituent, bis(2- ethylhexyl) phthalate (sampled at CD-1s, -1d, MW-C, -E deep, -H, -I, and AMW-2d during the spring sampling event), samples collected from CD-1s, MW-A, -E Rep, -E deep, -L, -3, AMW-1s, -1d, -2s, and -2d will continue to be analyzed for natural attenuation parameters during the semi-annual sampling events. Future analytical results will be monitored to evaluate if another injection will be needed. The next sampling event will be completed in the spring of 2019. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County 0 Table 1 Monitoring Well Construction Summary Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 DepthMonitoring Well Installation Geology of Total Facility Permit Number I Latitude Longitude Screened Diameter Code Date Interval (feet BTOC) 6-inch Screen, Filter Seal (inches) 1302-MSWLF-CDLF-1998 CD -Is 8/7/2006 35.47788 80.52334 Saprolite 29.53 18.0-28.0 16.0-28.0 14.0-16.0 2.0 (background well) 1302-MSWLF-CDLF-1998 CD-1d (background well) 7/21/2004 35.47788 80.52340 PWR 52.15 40.0-50.0 38.0-50.0 36.0-38.0 2.0 1302-MSWLF-CDLF-1998 AMW-1 10/6/2009 35.46915 80.52225 PWR 67.57 50.0-65.0 48.0-65.0 46.0-48.0 2.0 1302-MSWLF-CDLF-1998 AMW-1d 10/8/2009 35.46914 80.52227 Bedrock 96.93 0-78.0 84.0-94.0 82.0-94.0 80.0-82.0 2.0 1302-MSWLF-CDLF-1998 AMW-2 10/6/2009 35.46829 80.52232 PWR 39.90 -- 22.0-37.0 20.0-37.0 18.0-20.0 2.0 1302-MSWLF-CDLF-1998 AMW-2d 10/8/2009 35.46831 80.52233 Bedrock 63.55 0-51.0 55.0-60.0 53.0-60.0 51.0-53.0 2.0 1302-MSWLF-CDLF-1998 CD-4 Rep 1/15/2009 35.47656 80.52210 Saprolite 19.41 -- 6.0-16.0 4.0-16.0 2.0-4.0 2.0 1302-MSWLF-CDLF-1998 MW-1 1990s 35.47355 80.52105 Saprolite/PWR 29.93 18.0-28.0 16.0-28.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-3 2/17/1992 35.46794 80.52120 Saprolite/PWR 35.10 19.0-34.0 17.0-34.0 15.0-17.0 2.0 1302-MSWLF-CDLF-1998 MW-3 deep 6/3/2003 35.46785 80.52133 Bedrock 93.76 0-44.0 75.0-90.0 71.0-75.0 68.0-71.0 2.0 1302-MSWLF-CDLF-1998 MW-9 1990s 35.47706 80.51740 Saprolite/PWR 51.15 -- 39.0-49.0 37.0-49.0 35.0-37.0 2.0 1302-MSWLF-CDLF-1998 MW-A 9/16/1994 35.47289 80.52524 Saprolite/PWR 50.42 33.0-48.0 31.0-49.9 29.0-31.0 2.0 1302-MSWLF-CDLF-1998 MW-B 9/16/1994 35.47165 80.52081 Saprolite/PWR 15.22 2.5-12.5 2.0-13.0 1.0-2.0 2.0 1302-MSWLF-CDLF-1998 MW-C 9/16/1994 35.47042 80.52556 Saprolite/PWR 18.50 2.5-15.0 2.0-15.0 1.0-2.0 2.0 1302-MSWLF-CDLF-1998 MW-D 9/16/1994 35.47021 80.52394 Saprolite/PWR 30.15 18.0-28.0 16.0-28.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-E Rep 4/9/1996 35.46983 80.52212 PWR/Bedrock 45.65 28.0-43.0 25.0-45.0 23.0-25.0 2.0 1302-MSWLF-CDLF-1998 MW-E deep 9/2/1999 35.46974 80.52220 Bedrock 59.57 41.0-56.0 39.0-56.0 37.0-39.0 2.0 1302-MSWLF-CDLF-1998 MW-F 9/15/1994 35.47050 80.52040 Saprolite/PWR 20.08 3.0-18.0 1.5-18.0 0.5-1.5 2.0 1302-MSWLF-CDLF-1998 MW-G 9/15/1994 35.47290 80.52121 Saprolite/PWR 20.25 3.0-18.0 1.5-18.0 0.5-1.5 2.0 1302-MSWLF-CDLF-1998 MW-H 9/3/1999 35.46861 80.52310 Saprolite/PWR 32.70 19.5-29.5 17.5-29.5 15.5-17.5 2.0 1302-MSWLF-CDLF-1998 MW-H deep 9/2/1999 35.46851 80.52317 Bedrock 59.67 41.0-56.0 39.0-56.0 37.0-39.0 2.0 1302-MSWLF-CDLF-1998 MW-1 9/3/1999 35.46928 80.52076 Saprolite/PWR 65.18 47.0-62.0 45.0-62.0 43.0-45.0 2.0 1302-MSWLF-CDLF-1998 MW-J 9/3/1999 35.47403 80.52647 Saprolite/PWR 34.90 29.0-32.0 28.0-32.0 25.0-28.0 2.0 1302-MSWLF-CDLF-1998 MW-K 9/3/1999 35.46978 80.52467 Saprolite/PWR 36.08 18.0-33.0 16.0-33.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-L 9/2/1999 35.46771 80.52168 Saprolite/PWR 26.90 14.0-24.0 12.0-24.0 10.0-12.0 2.0 1302-MSWLF-CDLF-1998 MW-L deep 6/3/2003 35.46778 80.52168 Bedrock 65.20 0-48.0 53.0-63.0 50.0-63.0 47.0-50.0 2.0 1302-MSWLF-CDLF-1998 MW-M 6/2/2003 35.46743 80.52026 PWR 39.80 -- 21.0-36.0 18.0-36.0 16.0-18.0 2.0 1302-MSWLF-CDLF-1998 MW-X 12/1/1993 35.47225 80.52664 Saprolite/PWR 31.79 -- 20.0-30.0 18.0-30.0 16.0-18.0 2.0 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock 4. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Smith Page 1 of 1 February 2019 Table 2 Groundwater Elevations December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Number Sampling Event -onitori ng Well Code Top of Casing Elevation (AM SQ Groundwater Elevation [AMSL) MW-1 701.37 689.08 689.35 689.82 688.87 690.81 689.03 689.32 690.73 689.22 688.97 688.94 688.76 689.10 688.48 688.76 689.90 MW-3 670.37 652.20 651.67 654.06 652.48 654.70 654.34 656.75 652.60 655.97 654.26 657.31 655.78 657.56 655.20 656.52 659.53 MW-3 deep 668.33 655.15 NS 656.74 NS 657.43 NS 659.63 NS 658.99 657.48 660.27 659.10 661.06 658.68 660.09 660.36 MW-9 780.25 736.07 734.92 735.84 NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 746.80 703.02 702.39 703.59 703.09 702.45 703.45 705.01 702.49 703.28 702.60 704.73 704.39 703.58 703.50 702.71 703.45 MW-B 681.66 679.04 679.56 678.34 677.44 679.71 678.96 678.96 675.25 679.06 678.86 678.89 678.77 679.21 676.88 678.38 679.68 MW-C 694.98 686.66 683.43 684.58 682.88 690.12 683.78 688.55 682.14 688.33 682.70 688.74 683.29 689.03 682.63 683.75 690.09 MW-D 720.28 692.88 691.48 693.12 691.60 692.15 692.58 696.21 692.98 692.78 691.53 694.50 693.39 693.40 692.14 691.86 695.70 MW-E Rep 712.58 679.94 679.07 682.38 NS 680.25 682.53 685.83 682.49 683.00 680.93 684.97 683.18 682.85 678.66 682.76 683.49 MW-E deep 705.70 669.66 668.80 671.10 669.31 670.05 672.21 675.55 672.75 672.71 670.65 674.67 672.88 672.51 675.20 672.38 673.22 1302-MSWLF- CDLF-1998 MW-F 681.06 672.27 672.60 671.61 667.86 673.91 671.41 672.51 668.38 672.66 671.66 672.46 670.61 672.84 669.57 671.73 674.33 MW-G 695.19 685.79 686.40 685.46 685.72 686.74 685.69 685.78 685.11 685.68 685.68 685.62 685.65 685.82 685.37 685.50 686.41 MW-H 699.23 670.19 669.25 671.30 669.74 670.32 672.62 675.66 672.74 672.67 671.03 674.90 673.29 672.50 671.87 671.92 672.52 MW-H deep 699.17 669.30 668.54 670.81 669.32 669.72 672.17 675.17 672.33 672.32 670.62 674.52 672.96 672.16 671.66 671.85 672.22 MW-1 709.30 661.43 660.65 662.40 660.82 662.70 662.90 665.83 662.00 664.00 662.17 665.50 663.72 665.28 662.95 664.52 665.01 MW-1 728.47 698.68 697.11 698.49 696.45 698.77 698.02 700.14 696.55 699.10 696.77 699.52 698.05 699.37 697.55 698.15 700.16 MW-K 702.91 679.22 676.91 679.73 676.51 679.51 679.09 682.24 677.86 680.25 676.84 681.21 678.35 680.15 677.33 678.94 680.58 MW-L 669.54 653.13 651.96 654.24 652.71 655.24 654.74 657.83 654.03 656.54 654.39 657.90 655.72 657.89 655.10 655.62 658.22 MW-L deep 672.51 654.62 NS 655.81 NS 656.74 NS 659.35 NS 658.15 656.14 659.50 657.51 660.49 656.95 658.43 660.66 MW-M 668.49 647.85 NS 648.19 NS 649.98 NS 650.69 NS 649.52 648.01 649.94 648.79 650.25 648.36 649.12 651.25 MW-x 710.28 697.62 700.80 697.38 695.25 699.28 696.54 698.95 695.53 698.02 696.14 698.64 696.83 698.46 695.93 696.67 700.50 smith Page 1 of 2 February 2019 Table 2 Groundwater Elevations December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Sampling Event ag Well Code CD-1s (background well) Top of Casing Elevation 755.00 730.81 729.60 730.65 728.94 729.28 730.20 731.82 730.20 730.42 728.55 731.10 729.77 730.00 728.89 730.00 730.05 CD-1d (background well) 757.40 730.49 729.46 730.96 728.75 729.09 730.00 731.54 729.95 730.20 728.33 730.89 729.57 729.82 728.67 729.57 729.88 CD-4 Rep 739.15 727.71 728.74 727.35 730.70 728.69 730.69 727.97 729.45 728.68 730.45 728.90 730.38 728.00 729.24 731.83 1302-MSWLF- CD-6 741.40 707.71 706.81 707.55 706.10 706.02 704.04 710.20 709.30 707.64 706.65 708.75 708.44 -- -- -- -- CDLF-1998 AMW-1s 725.30 670.87 670.00 672.32 670.00 671.30 673.57 676.79 674.05 674.06 672.00 676.07 674.31 673.89 671.16 673.75 674.20 AMW-1d 725.80 670.58 669.77 672.03 670.34 671.05 673.31 676.62 673.02 673.85 671.73 675.85 674.09 673.67 672.91 672.60 674.05 AMW-2s 694.50 668.16 667.10 669.38 667.78 671.47 670.43 673.40 670.29 671.07 669.09 672.97 671.18 671.15 670.19 670.72 671.41 AMW-2d 694.50 668.49 667.68 669.90 668.32 669.12 671.05 673.95 670.70 671.60 669.65 673.53 671.82 671.60 670.74 671.20 671.72 Notes: 1. AMSL -Above Mean Sea Level 2. Blank Cells- Well not installed 3. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 4. MW-9 was removed from the monitoring program in November 2012. 5. M W-E Rep was not sampled during the Novemver 2012 sampling event due to laboratory oversight. 6. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. 7. Water levels for MW-3 deep, -L deep, and -M were collected on January 18, 2019, during the Fall 2018 sampling event. smith Page 2 of 2 February 2019 Table 3 Summary of Groundwater Velocities December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Number Monitoring Well Code Gradien Average Linear Velocity Gradient Average Linear Velocity Garent] Average Linear Velocity Gradient Average Linear Velocity MW-A 0.0157 feet/day 6.12E+00 0.0162 feet/day 6.31E+00 0.0164 feet/day 6.40E+00 0.0181 feet/day 7.06E+00 MW-B 0.0171 1.27E+00 0.0163 1.20E+00 0.0180 1.33E+00 0.0183 1.35E+00 MW-C 0.0182 3.98E+00 0.0211 4.61E+00 0.0211 4.62E+00 0.0225 4.91E+00 MW-D 0.0097 3.42E+00 0.0104 3.68E+00 0.0100 3.53E+00 0.0109 3.88E+00 MW-E Rep 0.0154 5.36E+01 0.0155 5.42E+01 0.0141 4.93E+01 1302-MSWLF-CDLF-1998 MW-F 0.0181 1.65E+00 0.0175 1.60E+00 0.0188 1.72E+00 0.0207 1.89E+00 MW-G 0.0265 2.92E+00 0.0255 2.82E+00 0.0265 2.93E+00 0.0227 2.51E+00 MW-1 0.0276 6.05E+00 0.0268 5.87E+00 0.0271 5.92E+00 0.0236 5.16E+00 MW-9 0.0185 4.05E+00 0.0187 4.08E+00 0.0190 4.16E+00 CD -Is 0.0196 2.35E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 1 of 4 February 2019 Table 3 Summary of Groundwater Velocities December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Number Monitoring Well Code Gradien Average Linear Velocity Gradient Average Linear Velocity Gr.cr,.nt] Average Linear Velocity Gradient Average Linear Velocity MW-A 0.0143 feet/day 5.56E+00 0.0165 feet/day 6.43E+00 0.0154 feet/day 6.02E+00 0.0169 feet/day 6.59E+00 MW-B 0.0162 1.20E+00 0.0175 1.29E+00 0.0186 1.37E+00 0.0195 1.44E+00 MW-C 0.0137 3.00E+00 0.0219 4.78E+00 0.0183 4.00E+00 0.0226 4.95E+00 MW-D 0.0098 3.47E+00 0.0104 3.67E+00 0.0084 2.97E+00 0.0091 3.21E+00 MW-E Rep 0.0148 5.16E+01 0.0139 4.86E+01 0.0128 4.46E+01 0.0133 4.65E+01 1302-MSWLF-CDLF-1998 MW-F 0.0168 1.53E+00 0.0188 1.72E+00 0.0191 1.74E+00 0.0201 1.83E+00 MW-G 0.0224 2.47E+00 0.0234 2.59E+00 0.0242 2.68E+00 0.0237 2.62E+00 MW-1 0.0226 4.95E+00 0.0242 5.30E+00 0.0250 5.47E+00 0.0232 5.08E+00 M W-9 CD -Is 0.0163 1.96E-02 0.0183 2.20E-02 0.0177 2.13E-02 0.0185 2.23E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 2 of 4 February 2019 Table 3 Summary of Groundwater Velocities December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Number Monitoring Well Code Gradien Average Linear Velocity Gradient Average Linear Velocity Gracrien]t Average Linear Velocity 0: Gradient 0. Average Linear Velocity MW-A 0.0151 feet/day 5.88E+00 0.0165 feet/day 6.42E+00 0.0156 feet/day 6.09E+00 0.0172 feet/day 6.73E+00 MW-B 0.0173 1.28E+00 0.0170 1.25E+00 0.0185 1.36E+00 0.0183 1.35E+00 MW-C 0.0166 3.63E+00 0.0221 4.84E+00 0.0178 3.89E+00 0.0234 5.13E+00 MW-D 0.0100 3.54E+00 0.0105 3.73E+00 0.0097 3.45E+00 0.0105 3.71E+00 MW-E Rep 0.0135 4.71E+01 0.0144 5.03E+01 0.0132 4.59E+01 0.0141 4.93E+01 1302-MSWLF-CDLF-1998 MW-F 0.0180 1.64E+00 0.0182 1.66E+00 0.0190 1.73E+00 0.0199 1.81E+00 MW-G 0.0235 2.60E+00 0.0226 2.49E+00 0.0239 2.64E+00 0.0232 2.56E+00 MW-1 0.0242 5.30E+00 0.0233 5.09E+00 0.0248 5.43E+00 0.0241 5.28E+00 M W-9 CD -Is 0.0173 2.07E-02 0.0181 2.17E-02 0.0178 2.14E-02 0.0189 2.26E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 3 of 4 February 2019 Table 3 Summary of Groundwater Velocities December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Facility Permit Number Monitoring Well Code 5/9/2017 Gradien Average Linear Velocity 0/30/20 Gradient Average Linear Velocity Gracrien]t Average Linear Velocity Gradient Average Linear Velocity MW-A 0.0150 feet/day 5.86E+00 0.0180 feet/day 7.01E+00 0.0161 feet/day 6.26E+00 0.0139 feet/day 5.43E+00 MW-B 0.0174 1.29E+00 0.0191 1.41E+00 0.0174 1.28E+00 0.0170 1.25E+00 MW-C 0.0162 3.54E+00 0.0233 5.09E+00 0.0211 4.61E+00 0.0148 3.25E+00 MW-D 0.0097 3.43E+00 0.0109 3.86E+00 0.0103 3.66E+00 0.0074 2.61E+00 MW-E Rep 0.0138 4.82E+01 0.0166 5.79E+01 0.0133 4.63E+01 0.0133 4.64E+01 1302-MSWLF-CDLF-1998 MW-F 0.0181 1.65E+00 0.0200 1.82E+00 0.0182 1.66E+00 0.0171 1.56E+00 MW-G 0.0233 2.57E+00 0.0240 2.65E+00 0.0234 2.59E+00 0.0230 2.54E+00 MW-1 0.0241 5.26E+00 0.0244 5.34E+00 0.0243 5.31E+00 0.0236 5.17E+00 M W-9 CD -Is 0.0172 2.06E-02 0.0195 2.34E-02 0.0180 2.16E-02 0.0163 1.95E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-1s are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 4 of 4 February 2019 Table 4 December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 32 No. 33 No. 34 No. 35 CD -Is (background well) 5.58 158 16.0 5.96 191 87 5.65 120 ,17.5 3.83 182 59 5.86 111 ,16.3 1.51 181 10 6.06 116 ,13.8 15.50 139 7 CD-ld (background well) 5.55 171 16.2 8.22 191 280 5.80 132 17.9 2.70 171 84 6.27 121 17.3 1.41 150 73 6.16 125 16.4 9.53 140 5 CD-4 Rep NS NS NS NS NS NS 5.84 284 17.9 1.40 145 18 6.37 390 15.4 0.00 156 13 6.47 207 15.6 0.00 -1 2 CD-6 5.55 257 16.8 3.19 130 55 5.49 269 16.4 4.19 183 13 5.76 208 18.4 0.78 202 7 6.03 221 16.2 0.00 71 1 AMW-ls 5.23 225 21.9 1.22 176 10 6.36 237 17.8 0.17 12 7 5.67 292 27.4 0.02 121 9 5.89 230 15.5 3.81 44 5 AMW-1d 6.09 569 22.0 0.01 89 4 7.60 638 17.3 0.00 -112 3 6.00 651 24.1 0.24 95 8 6.47 573 14.5 7.00 169 5 AMW-2s 5.65 135 17.8 2.10 128 36 7.72 148 17.0 2.47 -30 10 5.74 171 18.6 0.42 195 29 6.16 149 15.0 5.36 38 5 AMW-2d 6.24 241 19.1 0.75 107 3 6.96 167 13.9 1.07 -29 3 5.78 195 17.4 0.00 195 4 6.37 183 15.0 3.47 149 1 MW-1 6.03 1,870 16.6 2.96 -77 78 6.01 1,570 16.3 2.44 139 4 6.37 1,794 16.1 0.00 -22 2 6.57 1,480 15.4 0.00 31 9 MW-3 5.57 127 18.1 2.60 164 27 6.01 174 17.8 4.05 198 32 5.73 155 19.5 2.76 113 9 6.19 160 15.8 12.31 73 8 MW-3 deep 7.09 469 18.3 3.98 81 242 NS NS NS NS NS NS 7.93 329 17.1 0.39 21 191 NS NS NS NS NS NS MW-9 6.08 90 18.9 3.45 139 4 5.91 107 18.9 4.70 212 0 6.05 106 19.1 1.82 127 3 NS NS NS NS NS NS MW-A 5.01 292 17.3 1.08 113 4 5.47 324 17.9 0.06 205 1 5.47 411 17.1 0.00 103 3 5.47 371 14.7 2.66 140 2 1302-MSWLF- MW-B 6.45 1,350 14.2 3.70 -116 25 6.26 1,070 15.8 2.39 -78 5 6.70 1,097 14.8 0.00 -49 7 6.87 958 15.2 0.00 -82 10 CDLF-1998 MW-C 5.37 152 13.8 5.23 136 54 5.79 394 16.9 4.01 130 12 5.89 200 18.3 0.83 -16 46 5.93 187 15.2 0.00 28 4 MW-D 5.36 610 16.7 3.14 87 135 5.26 501 16.5 1.99 79 4 5.36 460 16.9 0.00 79 4 5.66 467 15.6 0.00 90 8 MW-E Rep 5.73 586 17.7 0.01 34 9 5.69 659 19.0 0.00 -115 4 5.96 785 19.3 0.00 13 6 DRY DRY DRY DRY DRY DRY MW-E deep 6.40 738 15.9 0 -51 7 6.54 823 18.7 0.00 -67 3 6.50 842 21.1 2.51 -76 9 6.50 822 16.5 1.70 78 >800 MW-F 6.35 1,120 14.3 2.43 -139 10 6.40 979 16.9 1.53 -95 4 6.30 826 16.2 0.00 -57 7 6.81 1,050 15.4 0.00 -92 12 MW-G 6.11 1,110 16.5 5.79 -99 29 5.91 917 17.4 2.85 -61 2 6.21 861 14.1 0.00 -63 3 6.51 997 16.1 0.00 -84 2 MW-H 5.29 230 14.5 9.03 197 212 5.82 176 14.9 6.13 193 7 5.20 145 15.0 3.90 74 13 6.45 171 14.6 0.00 -22 2 MW-H deep 5.53 369 15.1 5.97 192 43 5.83 263 15.1 6.91 186 6 5.74 270 14.6 0.96 35 11 6.40 251 16.1 6.27 17 1 MW-1 5.46 99 16.2 3.44 164 10 5.67 113 15.8 4.67 114 3 5.92 109 17.9 2.58 147 3 6.14 116 14.4 0.00 84 8 MW-J 6.25 341 16.2 4.62 156 86 5.78 343 16.9 6.14 111 1 6.49 247 16.1 1.09 21 4 6.57 251 14.1 0.00 125 1 MW-K 5.47 269 15.6 4.74 153 38 5.09 311 16.4 4.32 47 8 5.75 200 15.8 1.90 143 8 6.00 235 14.8 0.00 103 9 MW-L 5.38 91 14.3 2.31 206 4 5.66 106 16.4 2.59 222 3 5.44 112 16.4 0.04 214 5 6.70 227 14.9 3.03 3 5 MW-Ldeep 6.65 368 18.7 3.49 103 18 NS NS NS NS NS NS 6.20 279 18.5 0.87 75 14 NS NS NS NS NS NS MW-M 5.53 301 14.4 6.58 194 26 NS NS NS NS NS NS 6.09 221 15.4 1.47 91 59 NS NS NS NS NS NS MW-X 5.93 338 15.3 1 4.29 174 51 6.01 260 16.6 6.51 33 20 5.13 241 14.9 0.91 69 4 6.37 253 14.3 0.00 145 1 Surface Water Sam 1302-MSWLF- SW-1 6.14 685 10.5 6.58 78 18 6.14 424 16.8 6.01 170 2 DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY CDLF-1998 SW-2 5.05 667.00 9.67 6.06 121 196 DRY DRY DRY DRY DRY DRY 6.36 455 22.3 2.49 114 13 DRY DRY DRY DRY DRY DRY Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. Smith Page 1 of 4 February 2019 Table 4 December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 36 No. 37 No. 38 No. 39 0 CD -Is (background well) 6.7 02 104 15.1 1.96 206 5 6.06 100 ,13.0 1.74 348 42 6.15 119 ,15.9 0.02 353 9 6.10 129 ,15.1 6.06 135 2 CD -Id (background well) 6.06 117 16.9 1.11 242 27 6.03 119 14.5 1.71 320 32 6.21 134 19.2 4.56 293 9 6.18 139 16.5 4.68 109 14 CD-4 Rep 5.54 256 13.7 0.62 29 30 6.14 177 16.9 1.20 -45 26 6.10 259 13.3 2.19 -7 3 6.15 126 15.9 2.69 58 7 CD-6 5.75 223 16.9 0.60 166 11 6.15 994 17.1 1.24 -17 60 5.84 217 17.7 2.86 137 4 5.77 253 16.4 3.35 45 67 AMW-is 5.56 256 16.4 0.34 523 1 5.72 249 17.9 1.05 149 9 5.83 251 16.8 0.02 400 10 5.72 251 17.5 3.25 132 8 AMW-1d 6.20 755 17.9 0.46 -53 2 6.08 727 19.6 1.40 -23 9 6.04 650 20.1 2.05 -28 604 6.13 643 18.0 1.36 -68 29 AMW-2s 5.60 157 16.7 0.88 153 9 5.69 159 17.7 1.51 75 9 5.76 178 18.8 2.08 114 6 5.77 182 15.2 3.48 121 6 AMW-2d 5.83 192 17.1 0.36 126 0 6.26 203 18.5 1.40 138 1 6.30 231 16.9 3.88 95 1 6.26 252 16.0 4.19 104 1 MW-1 6.19 1,817 15.0 0.77 43 1 6.30 1,381 15.7 1.99 144 22 6.36 1,361 15.0 2.84 37 3 6.34 1,511 15.4 2.59 -37 0 MW-3 5.76 149 16.0 1.88 188 40 5.87 160 17.0 1.99 301 40 6.05 180 18.5 0.04 150 8 5.97 202 16.3 5.94 466 4 MW-3 deep 7.76 348 16.4 0.39 -153 2 NS NS NS NS NS NS 7.75 385 16.5 4.04 -65 4 NS NS NS NS NS NS MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 5.42 309 16.5 0.25 -34 0 5.40 333 15.3 1.89 291 1 5.42 432 16.9 0.04 -17 1 5.47 451 16.4 1.70 45 2 1302-MSWLF- MW-B 6.44 1,037 13.1 1.09 -88 1 6.33 817 16.4 1.35 -67 15 6.66 1,033 12.6 2.58 -67 10 6.62 922 16.6 3.00 -101 1 CDLF-1998 MW-C 5.35 100 13.2 1.06 104 43 5.90 206 16.7 1.31 233 72 5.64 108 12.3 2.23 44 4 6.02 428 16.0 2.58 47 3 MW-D 5.48 462 16.7 0.26 60 9 5.66 490 16.1 1.04 295 51 5.85 705 17.2 1.85 -17 2 5.71 471 15.7 3.39 35 4 MW-E Rep 6.17 991 16.8 0.47 -81 0 6.11 959 16.5 1.64 -40 3 5.99 831 19.0 0.07 -24 2 6.25 1,180 17.6 1.62 -54 3 MW-E deep 6.51 803 18.1 0.51 -80 3 6.35 836 17.1 1.21 -82 3 5.60 1,042 20.2 0.09 -41 800 6.34 1,198 18.0 1.09 -82 13 MW-F 6.30 745 13.7 0.64 -89 3 6.52 877 15.8 1.47 -100 10 6.57 726 13.8 2.74 -81 5 6.46 919 15.4 2.18 -104 6 MW-G 6.10 930 14.0 0.49 -98 0 6.15 1,430 16.7 1.60 -83 23 6.27 1,542 13.7 2.29 -106 8 6.30 1,794 16.3 1.97 -124 14 MW-H 5.79 149 15.7 1.77 60 9 6.04 160 15.2 2.04 335 96 5.92 161 14.5 2.39 230 19 5.92 199 14.2 3.70 466 11 MW-H deep 6.13 255 16.0 1.23 130 2 6.14 259 15.1 2.75 332 15 6.25 269 15.4 2.10 260 4 6.24 317 14.3 3.81 427 4 MW-1 5.74 112 15.3 0.21 159 1 5.97 116 15.1 1.61 311 1 5.95 118 15.3 2.59 84 3 6.11 133 14.4 4.12 199 3 MW-J 6.40 236 15.5 1.45 223 14 6.42 242 14.7 1.64 346 37 6.39 259 15.8 2.05 36 5 6.53 245 14.2 3.75 155 14 MW-K 5.72 207 15.2 0.66 175 1 5.79 199 15.2 1.40 266 33 5.81 202 16.0 2.88 96 6 5.83 229 14.6 2.65 187 10 MW-L 5.30 96 15.1 1.09 188 8 5.54 106 14.6 1.39 258 68 5.80 99 16.6 2.12 379 4 5.78 122 16.4 4.03 59 3 MW-Ldeep 6.02 208 17.1 1.49 133 2 NS NS NS NS NS NS 6.88 201 17.5 2.70 380 3 NS NS NS NS NS NS MW-M 6.34 297 15.3 1.51 54 1 NS NS NS NS NS NS 6.31 271 15.3 2.45 211 4 NS NS NS NS NS NS MW-X 6.15 222 14.6 120 117 2 6.25 236 1 15.4 1 1.45 1 348 36 6.28 216 1 15.2 12.07 106 1 21 16.31 228 1 14.5 4.53 131 2 Surface Water Sam 6.16 560 11.0 2.12 341 11 7.24 502 24.6 1 0.07 -26 22 DRY DRY DRY DRY DRY DRY 1302-MSWLF- SW-1 7.02 466 16.0 4!0 -17 15 CDLF-1998 SW-2 7.10 333 15.5 4.46 -7 6 DRY DRY DRY 1 DRY I DRY DRY 7.50 604 25.4 4.48 3 8 6.50 325 10.4 -69.80 2 43 Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 13. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. Smith Page 2 of 4 February 2019 Table 4 December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Date:Sampling Event: Sampling No. 40 No. 41 , CD -Is (background well) 6.00 115 15.5 15.5 3.99 281 7 5.73 132 ,15.0 3.84 519 3 5.91 103 low 3.45 245 4 5.05 113 ,16.1 4.49 360 6 CD -Id (background well) 5.97 123 16.4 4.84 186 13 5.81 136 14.5 6.96 507 7 6.06 115 15.8 4.50 210 20 5.34 124 15.9 3.10 330 8 CD-4 Rep 6.29 495 13.5 2.75 70.4 4 6.06 231 16.4 3.19 31.2 3 6.90 242 14.2 2.68 -54 28 5.28 209 17.0 1.35 79 3 CD-6 5.79 372 17.4 2.04 142 5 5.90 244 16.3 3.92 111 >800 6.20 271 16.9 1.50 -48 23 5.62 292 16.9 1.38 -4 29 AMW-1s 4.58 243 14.9 2.00 592 6 5.80 443 16.0 2.68 253 3 6.07 224 16.5 3.77 222 8 5.02 297 18.8 1.65 377 6 AMW-1d 5.94 518 15.9 1.78 -52 16 6.11 1,004 15.8 2.55 -42 5 6.13 477 18.1 1.51 -28 4 5.00 583 13.3 1.73 199 8 AMW-2s 5.07 160 14.2 3.50 562 6 5.92 173 16.2 4.19 187 3 5.78 154 15.8 3.22 51 7 4.92 164 16.4 3.38 235 8 AMW-2d 5.77 230 15.2 2.51 391 1 6.36 260 17.2 3.90 158 2 6.04 229 15.9 2.69 88 1 5.52 356 16.5 2.15 346 4 MW-1 6.29 2,379 14.9 2.69 -19 6 6.31 1,743 15.5 1.94 21 7 8.05 1,515 15.4 3.48 94 4 6.13 1,812 16.2 1.03 34 8 MW-3 5.42 166 17.6 2.29 260 14 6.20 178 19.5 3.85 166 3 6.04 167 16.5 3.18 101 1 5.52 246 20.6 3.50 439 5 MW-3 deep 7.49 368 20.5 1.50 -198 4 7.63 387 19.5 1.67 -165 3 7.48 362 15.6 2.26 -130 0 NS NS NS NS NS NS MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 4.78 390 15.6 2.34 27 2 5.30 402 15.5 1.41 29 3 5.48 394 16.1 1.27 -55 1 4.77 412 16.5 1.65 205 4 1302-MSWLF- MW-B 6.70 1,485 13.0 3.03 -68 9 6.00 833 16.9 3.91 -51 6 8.32 976 14.0 3.73 53 17 6.44 1,085 17.5 2.11 -79 9 CDLF-1998 MW-C 5.94 162 12.9 3.89 -181 8 5.21 186 16.7 1.73 153 37 6.50 126 14.0 3.48 -78 6 5.52 243 17.4 2.58 49 7 MW-D 5.86 745 16.8 3.66 15 3 5.19 520 16.5 2.60 85 14 7.26 617 16.3 1.23 -84 4 5.43 627 16.5 1.51 69 6 MW-E Rep 6.04 1,095 17.3 3.61 -38 9 6.10 1,076 16.2 1.25 -36 3 6.27 1,088 17.1 1.40 -59 1 5.59 1,139 17.6 3.79 48 5 MW-E deep 6.41 1,027 18.4 0.88 -100 15 6.44 979 16.2 1.21 -71 5 6.63 1,017 17.5 3.08 -95 9 5.89 959 18.1 2.30 -39 8 MW-F 6.51 1,270 13.9 3.58 -58 3 6.61 1,134 15.5 2.71 -136 3 8.12 796 14.4 2.65 -47 6 6.25 1,141 16.6 1.23 -71 6 MW-G 6.31 2,445 13.9 2.66 -78 6 6.32 1,372 16.8 2.28 -135 0 7.96 1,671 15.0 2.40 49 12 6.07 2,320 17.6 1.09 -80 1 MW-H 5.51 174 15.0 2.71 136-5 10 5.15 203 15.3 0.81 168 43 6.06 162 14.2 5.40 204 38 5.53 211 15.3 1.63 118 59 MW-H deep 6.12 285 15.4 1.62 137 4 5.72 280 15.3 0.64 146 4 6.82 272 14.9 4.99 145 18 5.91 337 15.0 2.21 105 16 MW-1 5.64 134 15.3 2.82 132 3 5.13 128 15.2 0.76 104 3 6.86 127 15.0 4.40 164 7 5.65 164 15.0 1.35 68 9 MW-J 6.54 402 14.9 3.13 137 7 6.48 274 14.3 0.38 210 7 6.92 265 14.8 4.20 28 58 6.05 311 14.8 2.65 21 36 MW-K 5.56 239 14.9 1.50 95 5 4.93 253 15.2 3.43 167 6 7.03 208 15.0 4.34 21 14 5.47 283 15.4 1.89 149 21 MW-L 5.29 97 17.5 4.15 131 3 5.92 93 18.5 3.80 89 4 5.80 95 14.2 3.66 192 2 5.11 146 18.1 3.49 486 5 MW-Ldeep 6.61 341 17.5 4.79 190 3 5.49 395 15.8 0.80 155 2 6.82 209 15.0 3.88 149 2 NS NS NS NS NS NS MW-M 6.31 334 15.4 1.49 116 4 5.67 334 15.7 0.49 151 10 7.97 320 15.3 4.02 -3 8 NS NS NS NS NS NS MW-X 6.19 341 13.5 3.23 140 4 5.03 234 15.3 2.53 342 3 7.19 210 13.9 3.98 20 6 5.94 275 15.3 1.62 78 1 2 Surface Water Sample Locations DRY 6.83 840 16.0 1.04 -54 0 6.99 342 4.99 360.3 >800 DRY DRY DRY DRY DRY DRY 1302-MSWLF- SW-1 DRY DRY DRY DRY DRY 15.4 CDLF-1998 SW-2 6.89 520 24.7 2.19 4 7 5.55 788 15.4 1.34 158 7 6.80 241 15.6 3.51 181 590 DRY DRY DRY DRY DRY DRY Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced M W-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. Smith Page 3 of 4 February 2019 Table 4 December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. No. 4S No. 46 No. 47 FC D-Is (background well) 5.32 117 15.7 1.69 274.6 8 5.35 121 16.1 1.87 57.7 8.09 6.2 110 31.5 3.8 124.1 5 6.3 110 16.7 5.6 38.6 9 (background well) 5.46 129 14.3 1.51 257.2 4 5.64 132 17.3 2.85 36.9 2.89 6.2 117 18.3 2.9 54.2 11 6.1 116 15.8 3.6 25.1 10 CD-4 Rep 5.65 211 14.3 5.00 29.0 9 5.94 156 15.9 1.31 218.4 5.19 6.0 156 16.3 4.5 50.7 153 6.0 139 12.5 5.3 48.9 101 CD-6 -- -- -- -- -- - - -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- AMW-ls 5.46 258 15.7 1.54 148.6 0 5.17 198 16.7 2.39 226.6 0.87 5.8 218 18.0 0.5 566.1 2 5.9 219 14.5 0.7 510.5 0 AMW-1d 5.92 496 17.9 1.59 -6.7 4 5.94 454 23.2 3.51 158.9 4.24 6.0 429 20.4 3.2 21.3 109 6.0 412 14.6 0.5 1.8 10 AMW-2s 5.79 172 19.9 1.55 48.2 4 4.40 159 17.2 4.42 280.1 4.39 5.8 154 22.4 2.2 162.6 4 5.8 144 13.7 2.9 101.3 2 AMW-2d 5.98 264 18.5 1.47 37.0 0 5.17 258 15.5 3.20 151.0 3.79 5.9 244 22.9 0.6 13.9 2 6.0 274 13.2 0.9 65.3 0 MW-1 5.49 1,545 15.7 3.44 53.2 7 6.28 1,533 15.0 2.44 210.9 10.0 6.4 1,385 15.2 3.4 75.4 47 6.4 1,355 12.4 2.0 224.6 7 MW-3 5.61 179 17.9 1.75 229.6 1 5.56 172 17.3 1.60 325.4 1.36 6.0 166 22.3 3.7 130.6 2 6.0 178 15.3 2.8 48.8 8 MW-3 deep 6.60 381 17.2 4.03 95.7 4 7.68 360 17.3 2.29 67 0.20 7.6 341 24.1 0.4 109.8 2 NS NS NS NS NS NS MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 5.23 412 15.6 1.31 140.9 3 5.06 423 16.8 3.21 70.1 4.42 5.6 373 21.2 0.4 63.5 1 5.7 372 9.3 0.6 32.4 1 1302-MSWLF- MW-B 5.53 991 14.2 4.71 -18.3 22 6.53 904 16.1 1.94 -74.6 57.0 6.6 701 18.5 3.4 -18.7 31 6.7 795 9.3 1.3 -64.8 18 CDLF-1998 MW-C 5.40 103 14.0 4.92 34.6 8 5.55 145 15.7 3.71 320.5 9.17 5.7 109 15.0 5.4 64.2 225 5.8 102 12.3 4.8 162.6 11 MW-D 5.98 824 16.9 5.10 10.0 9 5.73 530 15.0 2.33 201.5 21.0 5.9 490 17.2 2.9 62.9 23 6.2 858 15.1 1.1 35.4 1 MW-E Rep 6.31 1,117 18.1 1.35 -50.7 8 6.33 1,116 18.0 2.48 65.1 4.25 6.4 999 23.7 1.3 -26.2 11 6.2 1,012 13.4 0.3 -16.1 4 MW-E deep 6.34 929 18.1 1.65 -78.5 9 5.59 890 17.5 2.45 151.8 8.61 6.5 857 29.0 0.4 -83.5 5 6.3 1,031 11.6 0.4 -56.2 4 MW-F 5.23 911 14.6 3.59 -16.3 5 6.38 934 15.0 2.03 -82.3 20.0 6.5 526 14.9 3.4 -69.3 20 6.1 481 11.6 2.5 11.0 4 MW-G 5.32 1,733 15.5 3.78 -60.0 13 6.17 1,760 16.2 3.20 -85.7 48.0 6.3 1,035 15.9 2.60 -38.7 49 6.1 586 11.3 2.10 -2.8 15 MW-H 4.50 174 14.9 4.17 124.6 43 5.80 162 13.9 1.57 272.2 15.0 6.2 159 14.8 5.3 46.8 49 6.5 242 14.7 9.9 -2.6 10 MW-H deep 5.47 276 15.8 4.80 66.7 7 6.12 264 13.7 1.52 332.9 3.17 6.5 267 15.2 3.0 47.0 28 6.2 165 14.1 5.8 -8.3 173 MW-1 4.56 136 15.7 5.05 119.1 7 5.79 126 13.7 1.15 251.2 7.00 6.3 155 15.5 3.9 26.1 29 6.1 143 14.8 4.5 -2.9 11 MW-J 6.47 254 14.8 4.87 111.6 18 6.41 256 13.6 2.66 428.9 28.0 6.2 243 15.9 3.0 104.2 97 6.6 241 14.1 3.3 143.7 67 MW-K 4.53 215 15.4 5.03 123.1 8 5.72 218 14.2 1.30 327.3 11.0 6.0 192 15.8 4.6 61.8 27 6.0 173 15.1 3.9 129.8 5 MW-L 4.97 100 17.8 1.70 128.9 3 5.65 104 15.8 1.61 360.8 2.07 5.9 95 18.8 1.2 141.2 4 5.8 86 12.5 2.7 100.4 3 MW-L deep 6.17 223 16.5 1.58 72.4 0 6.54 211 15.7 2.63 211 0.61 6.7 207 24.0 0.3 146.7 3 NS NS NS NS NS NS MW-M 6.24 304 16.0 5.29 55.4 4 6.30 305 14.7 2.46 326 14.0 6.6 286 16.1 3.1 91.5 1S NS NS NS NS NS NS MW-X 9 202 14.3 5.19 82.2 6 6.18 207 14.1 1.45 466.4 5.88 6.4 195 15.0 4.0 102.1 20 6.3 185 13.6 3.2 167.5 1 Surface Water Sample Locations �6.73 508 5.13 11.0 4 DRY DRY DRY DRY DRY DRY DRY 7.6 336 6.2 10.1 -73.4 18 1302-MSWLF- SW-1 21.1 CDLF-1998 SW-2 6 528 20.1 5.23 36.7 7 DRY DRY DRY DRY DRY DRY 1 7.5 1 306 21.1 1 4.1 70.2 1 50 7.2 267 6.4 9.8 21.1 19 Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-ld replaced M W-9 as the background monitoring wells. 11. M W-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Smith Page 4 of 4 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 CD-ls 3-May-11 81.41 0.191 o 5.4516 4.231 16.0 2.321 5.931 0.141 20.61 26.5 CD-ls 8-Nov-11 59.71 0.25JB 4.461 2.671 12.4 1.91 4.411 0.081 11.21 11.2 CD-ls 7-May-12 45.5J 3.30J 1.191 8.75J 1.12J 3.011 12.A 12.6E CD-ls 28-Nov-12 63.81 0.17J 5.651 3.051 11.6 1.431 4.661 17.11 16.9 CD-ls 7-May-13 0.94J 2.4JB 35.6J 0.881 0.671 4.04J 0.39J 1.781 0.131 6.06J 5.081 CD-ls 5-Nov-13 46.8J 0.121 3.59J 1.631 10.2 1.35J 3.501 18.41E 15.4E CD-ls 6-May-14 28.81 4.14JB 1.48J 0.111 1.031 .31 3.401 2.98JB 1302-MSWLF- CD-ls 4-Nov-14 28.7J 0.13J 1.311 0.06J 1.041 0.111 2.571E 1.581 CDLF-1998 CD-ls 5-May-15 1.631 29.51B 1.331 0.151 13.8 0.3031E 1.171 2.401 2.751E CD-ls 27-Ocb15 28.4J 0.801 0.39J 0.79J 234 0.121 35.9 1.21J 4.19CN,J 0.151 4.10J 3.36E-01,1 CD-ls 17-May-16 29.31 0.94J 0.991 446 0.12J 17.0J 1.011 4.70J 1.93J CD-ls 1-Nov-16 30.51 1.23J 1.321 1.361 647 0.28J 1.35J 4.30J CD-ls 9-May-17 34.31 1.171 1.261 522 0.201 24.41 0.971 6. 1.821 CD-ls 31-Oc[-17 0.521 36.31 1.8ll 0.54J 2.871 1,270 0.37J 31.2J 1.41J 6.91 4.001 CD-ls 11-Jun-18 29.51 1981 6.7J 0.0511 5.71 4.01 CD -is 17-Dec-18 26.71 0.60J 3.61 498 16.6 15.01 7.0J 9.51 CD -Id 3-May-11 2.44J 231 2.03 16.7 18.6 112 14.0 22.3J 0.111 101 103 CD Id 8-Nov-11 74.5J 0.511 4.081 4.27J 27 2.84J 5.681 24.61 26.3 CD -Id 7-May-12 72.4J 0.581 3.911 4.67J 25 2.81J 5.581 26 27.9B CD Id 28-Nov-12 0.33J 37.7J 0.071 2.381 0.94J 12.6 1.14J 2.501 8.901 13 CD -Id 8-May-13 0.881 1.02JB 31.21 0.07J 0.78J 4.5J 0.49J 1.92J 6.381 13.1 CD-ld 5-Nov-13 35J 0.86J 4.34J 1.13J 1.901 17.3JB 10.8B CD -Id 6-May-14 1.14J 37.8J 0.07J 0.05J 3.22JB 1.161 7.34J 0.811 2.74J 0.121 6.16J 9.4118 1302-MSWLF- CD Id 4-Nov-14 43.1J 0.161 0.111 2.25J 9.09J 0.87J 2.881 10.2JB 10.7 CDLF-1998 CD -Id 5-May-15 34.5JB 0.84J 3.63J 1,320 0.39J 32.5 1.42J 5.181 3.68JB CD Id 27-Oc[-15 0.421 42.3J 0.13J 1.87J 2.151 8.18J 3,170 0.971 87.4 2.491 4.37CN,J 0.061 10.91 14.0B-01 CD -Id 17-May-16 81.3J 0.46J 4.861 7.421 26.0 12,000 3.131 287 7.11J 2.11J 0.07J 29.3 29.7 CD-ld 1-Nov-16 32.61 1.191 0.77J 2.82J 1,200 0.331 31.31 1.24.1 7.961 4.291 CD Id 9-May-17 33.91 1.271 0.521 1.811 720 6.921 25.81 1.091 6.951 3.121 CD-ld 31-Oa-17 29.5J 0.681 0.611 226J 0.11J 11.81 0.64J 5.831 1.24J CD -Id 12-Jun-18 32.41 2.5J 432 13.2J 1.0J 6.91 3.21 CD -Id 17-Dec-18 31.9J 9.3J 2.31 591 0.41J 18.1 3.0J 6.8J 4.11 CD-4 Rep 3-May-11 206 0.9JB 17. 0.62J 8.39J 2.721B CD-4Rep(dup) 3-May-11 0.211 206 17.9 0.681 8.981 0.171 2.851 CD-4 Rep 8-Nov-11 0.141 191 0.931 18.2 1.00J 8.86J 9.44J CD-4 Rep 9-May-12 184 1.69J 18.1 1.70J 0.17J 11.31 3.031 16.1B CD-4 Rep 29-Nov-12 172 13.7 0.62J 7.03J 2.841 2.1418 CD-4 Rep 10-May-13 75.51 0.51 2.711 7.871 1.94J 0.88J 11.2J 11.11 10.3 CD-4 Rep 7-Nov-13 1.36J 60.4J 0.35J 0.071 0.771 5.311 1.83J 0.57J 5.11J 0.131 32 4.401B CD-4 Rep 7-May-14 62.4J 0.31J 0.05J 3.25JB 5..0261 1....701 0.32J 6.52J 22..21J 2897JB 1302-MSWLF- CD-4 Rep 5-No114 70.0J 0.31J 2591 146J 0.72J 4.29J 14.8JB 6.85J CDLF-1998 CD-4 Rep 6-May-15 58.4J 0.39J 1.131 5.94 1.90J 0.53J 4.72J 14.01 2.99J CD-4 Rep 28-Oc[-15 57.91 0.321 2.181 .8 89 1.26J 10.7J 4.14CN,1 1391 8.34E-01) Rep 18-May-16 1.091 56.2J 0.461 0.66J 5.43J 801 1.CD-4 3.70J CD-4 Rep 2-Nov16 46.3J 0.27J 1.351 .5 1 108J 0.901 4.18J 1.11J 8.IJ .81 CD-4 Rep 9-May-17 53.81 0.461 0.951 99J 111 7 052 438 1 73J CD-4 Rep 31-OR-17 45OJ 0.181 0.9 082J0581 0.2 765 2.76J CD-4 Rep 6-Jun-18 52.9J 0.41J 3.41 0.74J 3.3J 13.31 4.01 CD-4 Rep 19-Dec-18 1.11 50.9J 0.961 4.6J 5.51 2.6J 2.9J 7.0J 1.4J 15.51 11.6 CD 4-May-11 66.61 0.421 6.741 4.081 4.6J 2.01J 5.341 0.11 24.71 14 CD-6 9-Nov-11 59.6J 0.261 4.711 2.621 7.89J 1.2 5.22J 15.81 9.62J CD-6 9-May-12 57.81 0.201 4.20J 2.081 3.631 1.21J 4.481 17.21 17.7B CD 29-Nov-12 50.81 0.13J 2.251 1.8W 1.86J 0.73J 3.73J 12.31 6.6118 CD-6 30-May-13 61.4J 0.361 5.891 3.021 4.12J 1.43J 4.77J 20.41 13.8 1302-MSWLF- CD-6 7-Nov-13 0.571 3.77J 298 0.141 18.3 36.9 2.13J 11.71 1.07J 14.6J 6.88JB CDLF-1998 CD-6 7-May-14 38.5J 0.301 3.42JB 1.04J 0.07J 2.30J 4.391 2.401B CD-6 5-Nov-14 120 0.881 7.641 8.021 8.02J 3.83J 9.041 0.141 50.68 25.7 CD-6 6-May-15 47.4J 0.201 1.601 1.841 2.77J 0.81J 3.29J 30.51 5.40J CD-6 28-0R-15 4.971 235 2.03 19.5 25.6 21.61 8.641 4.OSCN,1 0.371 107 73.9E-01 ��746J 1.581 CD-6 I8-May-16 1.921 62.21 0.231 13.2 2.571 8.701 1.0611 12.61 7.941 CD-6 2-Nov-16 1.891 63.71 0.331 13.3 3.121 2.871 9.12J 1.29J 17.3J 1 10.1 AMW-1s 3-May-11 104 0.92J 1.41J 0.311 04 3.591 0.101 8.116 AMW-1s 8-Nov-11 105 0.901 1.431 0.461 1.081 1.941 0.441 3.671 0.101 8.471 AMW-1s 7-May-12 103 0.861 2.391 1.871 0.221 3.87J 2.98) 8.49JB AMW-15 28-Nov-12 0.191 97.41 0.831 0.781 0.781 0.111 3.31J 2.411 4.79J AMW-1s 8-May-13 101 0.871 1.981 0.091 4.051 2.241 6.131 AMW-1s 6-Nov-13 981 0.911 0.22J 2.911 0.321 4.06J 16.7JB 6.70JB AMW-1s 7-May-14 93.01 0.951 2.4418 0.281 2.271 0.471 3.911 1.39J 6.351B 1302-MSWLF- AMW-1s 5-Nov-14 89.21 1.06 0.501 3.371 0.781 4.15J 4.03JB 7.601 CDLF-1998 AMW-1s 7-May-15 87.61 0.971 3.781 0.31J 2.721 0.681 5.86J 3.311 6.51J AMW-1s 29-0R-15 82.51 0.781 1.031 0.711 0.191 4.03J 3.18CN,1 4.221 9.82E-01,1 AMW-1s 18-May-16 0.271 0.821 85.41 1.03 1.431 0.381 2.471 0.921 4.16J 5.381 7.431 AMW-1s 2-Nov-16 71.71 0.561 0.55J 3.19J 5.78J AMW-1s 10-May-17 92.41 0.731 0.611 0.361 3.911 2.fi01 5.45J AMW-1s 1-Nov-17 68.21 0.661 0.891 0.541 0.141 2.711 3.341 6.37J AMW-15 8-Jun-18 91.91 0.77J 5.21 3.91 4.41 17.7 AMW-ls 19-Dec-18 86.41 0.891 3.91 3.11 5.91 Smith Page 1 of 16 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 AMW-ld 3-May-11 0.241 129 0.121 o 1„ 4.671 2.081 0.251 1 1 l.tl 9.16J 2" 0.191 ,00 9.17JB AMW-ld 8-Nov-11 0.181 140 0.07J 0.94J 5.781 1.641 0.211 30.2J 7J AMW-ld 7-May-12 0.291 135 5.20J 2.17J 0.27J 9.17J 8.981E AMW-ld 28-Nov-12 0.411 106 0.14J 1.38JB 3.27J 2.26J 0.521 6.21J 5.501 AMW-ld 8-May-13 1.05JB 133 4.53J 1.63J 0.251 7.81J 3.08J AMW-ld 6-Nov-13 133 1.881 4.33J 1.77J 0.45J 7.45J 20. 4.30JB AMW-ld 7-May-14 143 0.501 0.051 SAW 4.90J 3.011 9.84J 5.891 27.9E 1302-MSWLF- AMW-ld 5-Nov-14 1.46J 168 0.61 0.01 4.41 6.701 1.131 4.14J 11.81 13.81E 20.8 CDLF-1998 AMW-ld 7-May-15 133 0.40J 4.08J 5.53J 3.58J 2.141 9.83J 5.47J 10.3 AMW-ld 29-Oc[-15 1.41J 123 0.181 3.021 5.32J 1.06J 0.931 S.61J 3.57CN,1 4.00J 6.79E-01,l AMW-ld 18-May-16 1.011 131 0.191 2.09J 6.06J 1.52J 0.841 9.03J 2,121 6.84J AMW-ld 3-Nov-16 128 0.17J 2.20J 6.091 1.121 0.811 9.30J 6.65J AMW-ld 30-May-17 0.62B-01,J 131 0.121 1.301 5.501 0.66J 0.491 8.07J 1.39J 5.111 AMW-ld 1-Nov-17 0.851 128 0.141 0.931 6.07J 1.39J 0.451 9.60J 5.49J AMW-ld 8-Jun-18 1.2J 153 0.26J 2.9J 7.3J 2.0J 1.4J 12.4J 4.2J 14.2 AMW-ld 19-Dec-18 0.71J 127 0.16J 6.6J 0.31J 30.1J 2.2J 5.01 AMW-2s 3-May-11 52.11 0.92J 2.49JB 1.10J 1.411 2.21 2.541 7.17J 6.47JB AMW-2s 8-Nov-11 42.31 0.501 1.361 0.291 0.821 2.191 1.361 5.081 AMW-2s 8-May-12 42.81 0.45J 1.481 0.231 2.851 0.661 1.471 3.77J 5.92JB AMW-2s 29-Nov-12 45.31 0.481 1.021 0.23J 0.62J 0.32J 1.191 1.41J AMW-2s 9-May-13 42.6J 0.57J 1.111 0.52J 1.06J 0.63J 1.951 3.09J 3.631 AMW-2s 6-Nov-13 40.11 0.541 0.27J 0.64J 0.42J 1.481 16.81B 3.S1JB AMW-2s 7-May-14 43.7J 0.561 2.16JB 0.30J 0.87J 0.35J 1.41J 1.96JB AMW-2s 5-Nov-14 46.01 0.691 0.44J 1.01J 0.591 1.881 2.841 1302-MSWLF- AMW-2s 6-May-15 2.721 43.41 0.511 1.07J 0.39J 1.461 2.07J 2.371 CDLF-1998 AMW-2s 28-Oa-15 1.02J 50.61 0.881 1.56J 0.75J 0.50J 1.23J 1.961 6.12CN,1 6.231 6.14B-Ol,l AMW-2s (dup) 28-Oc[-15 1.001 51.11 0.851 1.791 0.871 0.57J 1.34J 2.101 3.34CN,1 7.OL 7.O1B-Ol,l AMW-2s 17-May-16 45.8J 0.691 1.151 0.65J 0.481 0.71J 1.631 0.101 4.51J 3.931 AMW-2s 1-Nov-16 46.5J 0.731 1.601 0.58J 0.57J 0.74J 1.811 5.171 AMW-2s 30-May-17 0.62B-01,J 42.7J 0.471 0.951 0.17J 1.02J 3.581 1.621 AMW-2s 1-Nov-17 43.6J 0.541 0.881 0.531 0.26J 1.171 3.64J 3.211 AMW-2s 8-Jun-18 45AJ 0.471 1.41 3.7J 3.0J AMW-2s 20-Dec-18 39.01 0.391 9.81 3.71 5.81 AMW-2d 3-May- 11 55.21 2.861B 0.83J 1.031 AMW-2d 8-Nov-11 47.51 1.081 0.121 0.771 1.231 AMW-2d 8-May-12 78.21 1.26J 3.201 0.33J 1.22J 2.79J 10.5B AMW-2d 28-Nov-12 69.11 0.881 2.34J 0.391 2.561 4.761 AMW-2d 9-May-13 54.71 1.75J 0.061 1.42J 4.03J 2.4J AMW-2d 6-Nov-13 71.11 2.43J 2.69J 18.5JB 7.86JB AMW-2d 7-May-14 57.OJ 0.301 2.08JB 0.84J 1.24J 0.761B 1302-MSWLF- AMW-2d 5-Nov-14 60.4J 0.07J 1.25J 2.33J 1.091B 5.041 CDLF-1998 AMW-2d 6-May-15 1.281 67.4J 0.85J 1.67J AMW-2d 28-OR-15 0.251 63.9J 0.45J 0.14J 1.501 2.79CN,1 2,611 7.41E-01,J AMW-2d 17-May-16 64.5J 0.13J 1.37J 1.07J 1.381 AMW-2d 2-Nov-16 67.7J 0.301 0.66J 1.901 5.021 AMW-2d 30-May-17 0.65B-01,1 70.1J 0.141 3.63J 0.24J 1.32J 4.531 AMW-2d 2-Nov-17 74.2J 0.161 1.48J 2.001 AMW-2d 8-Jun-18 75.7J 0.17J 2.11 3.81 3.11 AMW-2d 20-Dec-18 75.11 0.201 0.581 4.11 MW-1 4-May-11 0.461 5.081 360 0.9J 0.09J 9.051 19.7 11.8 4.59J 20.81 2.391 0.091 35.7 40.4 MW-1 9-Nov-11 2.22J 187 0.52J 16.8 6.67J 0.64J 37.71 3.35J 3.711 MW-1 9-May-12 201 0.161 0.061 2.261 17.8 17.0 3.61J 42.41 6.901 12.2J 13.9B MW-1 28-Nov-12 153 1.03J 0.751 12.6 5.54J 0.75J 29.9JJ 5.751 4.86J 3.551 MW-1 30-May-13 172 0.121 0.261 0.871 15.9 9.48J 0.3J 35.11 8.86J 8.67J MW-1 6-Nov-13 127 0.31J 11.5 8.66J 1.12J 281 11.91B 2.64JB 5.61J MW-1 7-May-14 1.991 120 0061 0.281 10.3 10.2 0.281 28.21 0.101 6.99J 1.931 MW-1 (dup) 7-May-14 119 0:051 0.31J 10.5 10.2 0.29J 28.01 5.701 6.16J 1.911 1302-MSWLF- MW-1 4-Nov-14 2.271 126 0.011 0.441 12.5 9.07J 0.95J 31AJ 2.401 5.471B 1.721 CDLF-1998 MW-1 5-May-15 0.83J 128 0.17J 11.6 7.74J 0.231 29.9J 2.99J 3.77J 1.881 MW-1 28-0R-15 144 0.36J 1.52J 14.4 8.26J 1.151 33.3J 4.32CN,1 3.fi31 4.24B-Ol,J MW-1 19-May-16 144 0.34J 0.511 12.8 12.0 0.28J 29.4J 2.59J 1.991 MW-1 2-Nov-16 143 0.39J 13.7 8.64J 0.63J 30.4J 3.021 MW-1 10-May-17 150 0.171 0.511 12.5 6.82J 0.32J 29.4J 3.291 2.05J MW-1 31-OR-17 132 0.431 0.761 12.4 7.781 0.781 29.0J 3.151 3.051 MW-1 7-Jun-18 0.93J 1.2J 146 0.21J 13.1 7.8J 0.48J 29.61 4.2J MW-1 (dup) 7-Jun-1 0.87J 148 0.34J 13.6 8.31 0.551 31.3J 7.01 MW-1 19-Dec-18 136 0.68J 12.2 6.31 0.681 30.01 2.61 3.01 Smith Page 2 of 16 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-3 E. 4-May-11 36.21 o J 4.19JB 1.561 ,,, 1.64J J 2.341 J 0.111 6.111 0 7.681 MW-3 9-Nov-11 35.21 2.56J 1.221 1.601 2.031 8.11 M (dup) 9-Nov-11 37.11 2.30J 1.201 1.551 2.001 6.291 M3 MW-3 T0.24JB 8-May-12 30.112.07J 0.641 1.69J F41 2.231 3. 7.631B MW-3 28-Nov-12 28.612.30J 0.321 0.84J 1.20J 3541 1.981 MW-3 9-May-13 37.91 3.281 1.531 1.811 2.361635J811MW-3 7-Nov-13 0.50137.91 3.931 1.781 3.551 4.471 24.71 828 1302-MSWLF- MW-3 8-May-14 56.2J 0.70J 3.32J 2.45J 3.08J 3.28J 3.54J 8.621 36.6 CDLF-1998 MW-3 6-Nov-14 30.81 0.051 1.14JB 0.401 1.03J 0.42J 1.56.1 3.851 3.571E MW-3 6-May-15 0.811 55.41 0.711 4.141E 2.591 3.17J 3.691 4.36J 0.071 31.3J 15.3 MW-3 28-Oa-15 25.01 1.231 0.251 0.831 4.17CN,1 3.121 5.438-01,1 MW-3 18-May-16 1.461 0.351 0.991 2.10J MW-3 2-Nov-16 27.41 1.601 0.251 1.001 2.361 MW-3 11-May-17 32.OJ 0.13J 2.001 0.63J 0.551 1.29J 3.65J 2.93J MW-3 1-Nov-17 27.6J 1.45J 0.07J 0.891 2.401 MW-3 7-Jun-18 0.63J 28.01 0.0511 1.31 2.41 3.51 MW-3 19-Dec-18 31.11 0.14J 1.81 0.311 1.01 2.A 2.31 MW-3 Deep 5-May-11 3.111 195 1.73 1.24 26 14 55.4 0.171 0.551 77.3 81 MW-3 Deep 9-May-12 0.35J 38.3J 0.93J 2.12J 1.71JB MW-3 Deep 30-May-13 0.41.1 37.7J 0.121 0.09J 2.18JB 0.13J 1.32J 0.17J 2.49J 2.571 1302-MSWLF- MW-3 Deep 8-May-14 40.81 0.131 4.301 1.59J 0.981 2.781 5.441 CDLF-1998 MW-3 Deep 6-May-15 0.261 2.161 49.01 0.131 0.291 1.90J 1.72J 2.471 33.2 MW-3 Deep 28-Oa-15 1.021 42.21 0.701 0.50J 0.64J 0.571 3.00CN,1 5.87B-01) MW-3 Deep 19-May-16 43.01 0.69J 0.61J 0.40J 0.581 2.371 3.261 MW-3 Deep 11-May-17 0.761 0.501 0.711 44.11 0.55J 0.801 0.431 0.681 2.061 MW-3 Deep 7-Jun-18 0.811 50.31 3.61 1302-MSWLF- MW-9 3-May-11 11.81 1.44JB 0.271 3.871 0.611 5.871 4.62JB CDLF-1998 MW-9 9-Nov-11 9.871 1.731 0.2 2.041 0.541 4.771 MW-9 9-May-12 13.71 1.331 0.341 5.651 0.091 0.801 8.371 6.19.1E MW-A 3-May-11 40J 0.151 1.381B 3.481 0.871 12.51 3.86JB MW-A 9-Nov-11 0.36JB 44.21 0.131 1.831 0.761 9.321 2.821 MW-A 9-May-12 42.41 0.301 1.14J 8.201 0.911 15.51 4.53JB MW-A 27-Nov-12 0.36JB 45.6J 0.13J 0.97J 2.861 1.171 11.6.1 1.861 2.631 MW-A 7-May-13 43.7J 0.14J 0.64J IA81 1.48J 0.071 9.141 1.091 2.31J MW-A 5-Nov-13 43.4J 1.65J 2.051 0.76J 9.93J 20 3.37JB MW-A 6-May-14 49.21 0.14J 3.73JB 8.881 0.841 16.61 1.151 2.101B 1302-MSWLF- MW-A 4-Nov-14 45.11 0.201 6.141 0.941 18.A 1.411 1.871 CDLF-1998 MW-A 5-May-15 46.9J O.151 3A41 0.84J 13.4J 1.411 1.821 MW-A 27-Oc[-15 0.26J 47.2J 0.14J 3.151 1.181 0.17J 12.91 2.25CN,1 2.141 5.23B-01) MW-A 17-May-16 0.35J 1.011 441 0.171 9.541 0.48J 19.81 2. 1.64J MW-A 1-Nov-16 48.6J 0.17J 7.251 1921. 3.851 MW-A 9-May-17 0.45B-01,1 48.9J 0.161 4.691 0.401 14.7J 1.801 MW-A 31-Oc[-17 50.9J O.15J 4.83J 0.271 15.11 1.971 MW-A 7-Jun-18 52.91 0.14J 4.61 2.7J 29.81 22.0 MW-A 20-Dec-18 52.3J 0.0901 5.51 16.81 2.91 MW-B 4-May-11 2.351 269 0.281 3.781E 18 3.451 1.36J 11.31 3.181 0.141 9.951 MW-B 9-Nov-11 2.591 249 0.061 8.75J 1.511 0.70J 8.91J 3.541 0.13J 3.6J MW-B 9-May-12 191 8.681 0.891 0.091 6.351 15.9B MW-B 29-Nov-12 5.881 268 23.5 1.08J 0.20J 9.10J 2.291 3.581 MW-B 30-May-13 2.551 197 9.391 1.11 0.29J 6.41 2.891 10.7 MW-B 6-Nov-13 2.021 225 11.7 0.97J 0.23J 6.721 1.491 1 3.771B MW-B 8-May-14 2.731 236 0.081 11.5 1.25J 0.55J 8.801 1.481 5.811 3.141 1302-MSWLF- MW-B 4-Nov-14 6.041 226 0.061 21.0 1.12J 0.181 12.11 2.751 2.62JB 1.521 CDLF-1998 MW-B 5-May-15 0.30J 1.501 160 8.501 1.25J 0.34J 7.051 2.251 1.97J MW-B 29-0R-15 2.611 171 0.521 16.5 0.53J 0.31J 5.45J 2.39CN,1 0.071 7.39B-01) MW-B 19-May-16 0.308-01,1 2.161 225 1.051 11.7 0.81J 0.39J 6.53J 0.06J 4.641 3.541 MW-B 3-Nov-16 2.431 196 13.5 0.24J 6.84J 2.711 MW-B 10-May-17 1.73B-01,1 258 0.581 9.201 0.451 0.35J 5.541 0.061 3.15J 2.031 MW-B 31-OR-17 3.S5J 256 0.771 14.9 0.29J 0.09J 7.281 2.081 MW-B 6-Jun-18 4.8J 251 0.191 2.3J 15.8 2.1J 0.97J 7.81 0.15J 4.91 6.31 MW-B 19-Dec-18 0.78J 172 0.071J 9.6J 0.36J 5.51 15.1 MW-C 4-May-11 42.31 0.441 0.071 7.32J 5.631 2.581 1.451 4.141 O.OSJ 7.261 9.971 MW-C 9-Nov-11 I5.51 0.151 0.101 0.621 3.43J 1.061 0.431 4.19.1 8.621 MW-C 9-May-12 43.5J 0.43J 7.45J 17 3.94J 2.30J 6.85J 30.4J 22.213 MW-C 29-Nov-12 35.81 0.13J 2.751 9.05J 1.17J 0.711 3.94J 4.87J 8.07J MW-C 9-May-13 19.71 0.241 2.961 0.75J 1.361 0.81 1.77J 3.481 10.1 MW-C 6-Nov-13 31.7J 0.261 3.77J 9.54J 1.79J 0.82J 3.741 23.5JB 18.8B MW-C 7-May-14 19.6J 0.171 2.98JB 3.201 0.79J 0.26J 1.65J 3.081B 1302-MSWLF- MW-C 5-Nov-14 47.2J 0.101 0.57J 1.681 4.201 1.30J 0.29J 4.74J 2.11JB 3.061 CDLF-1998 MW-C 6-May-15 20.4J 0.301 2.38J 2.261 1.66J 0.911 2.34J 3.53J 3.43J MW-C 29-0R-15 1.42J 47.91 0.681 11.6 7.47J 4.52J 3.04J 9.281 1.151 3.79CN,J 0.101 19.41 14.4E-01 MW-C I8-May-16 21.4J 0.211 0.711 1.781 0.47J 0.251 1.69J 4.111 2.011 MW-C 2-Nov-16 2.161 34.OJ 0.111 1.301 10.3 0.551 0.331 3.791 3.511 MW-C 9-May-17 22.51 0.14J 1.081 0.43J 0.30J 1.18J 1.941 1.361 MW-C 1-Nov-17 0.60J 31.91 0.331 4.171 7.81J 1.38J 1.20J 3.92J 8.391 5.701 MW-C 7-Jun-18 2.01 52.5J 0.811 16.5 8.21 4.1J 4.OJ 8.8J 1.5J 25.8 17.7 MW-C 19-Dec.18 22.0J 0.14J O.lL 0.97J 0.33J 1.2J 3.0J Smith Page 3 of 16 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-D o 4-May-11 193 0.11 0.121 11.7 11.1 30.41 0.25J 41.7 37.3 MW-D 9-Nov-11 0.36JB 118 0.25J 8.021 3.051 8.5J 15.31 0.07J 5.681 12.1 MW-D 9-May-12 124 3J S.971 3.94J 15.71 5.121 9.331E MW-D 28-Nov-12 0.981 1.831 117 0.17J 0.061 2.311 3.031 3.631 F7.32J 13.81 12.11 5.111E MW-D 9-May-13 140 0.21J 0.081 6.41 6.721 7.78J 17.31 25.8 10.8 MW-D 6-Nov-13 194 0.861 0.251 28.6 12.8 35.5 27J 305B 37.9E MW-D 7-May-14 169 0.211 3.741E 19.0 1.16J 20.71 8.021 1.4318 1302-MSWLF- MW-D 5-Nov-14 121 O.M 0.06J 1.621 7.631 3.411 0.72J 18.3.1 0.951E 7.001 CDLF-1998 MW-D 5-May-15 1.79J 164 14.2 1.06J 21.71 4.511 1.62J MW-D 29-Oc[-15 0.301 5.111 119 0.741 0.121 39.0 30.4 32.7 6.25J 37.01 5.92J 3.91CN,1 .371 50.7 48.58-01 MW-D 18-May-16 1.65J 157 0 M 0.851 17.0 0.191 21.0.1 3.921 1.72J MW-D 3-Nov-16 134 0.091 8.751 %21 0.851 0.21J 19.91 3.64J MW-D 9-May-17 0.94B-01,J 242 0.07J 0.56J 18.8 0.42J 0.09J 24.3J 5.68J MW-D 1-Nov-17 1.23J 151 0.30J 9.171 6.691 7.621 1.601 20.4.1 1.871 0.061 12.81 14.5 MW-D 7-Jun-18 1.2J 139 0.111 1.7J 3.41 1.4J 0.36J 15.7.1 6.81 15.8 MW-D 19-Dec-18 214 0.11J 1 1 18.6 1 1 1 14.81 14.01 MW- 4-May-11 26 0.57J 1.18JB 22.4 0..62J 1J 6.41 MRep 8-Nov11 1.07JB 267 0.4 9.28 08W-E 1321 2.88J MW-E Rep 8-May-12 303 0.311 22.6 0.85J 03 15.21 1.721 10.3B MW-E Rep 8-May-13 286 0.34J 8.291 1.0BJ 0.081 14J 0.891 3.71J MW-E Rep 5-Nov-13 294 5 01..049J 0.22J 14JB 638E MW-E Rep 6-May-14 342 0.44J 36 1.845J 0.67J 15.91 7.58J 6.4618 1302-MSWLF-MW-E Rep 4-Nov-14 326 0.211 8.391 02 15.91 1.57J 2.99JB 4.31J CDLF-1998 MW-E Rep 5-May-15 348 0.30 7.481 1.02J 0.62J 14.51 144 12.2J4446J MW-E Rp 27-Oa-15 0.911 294 0.26J 1.121 10 0.39J 12.31 2 84B-O11 MW-E Rep 18-May-16 1.111 365 0.271 12. 0.321 12. 2 2.9910 MW-E Rp 1-Nov-16 297 0.151 5.41 017J 114J 5131 MW-E Re 9-May-17 0.71B-01,J 353 0.20 7. 013J 12.1 3.40J MW-E 31 -Oa-17 0.86J 344 0.2165&1 2 3711 .Rp MW-E Rep 11-Jun-18 0.66J 350 0.23J 9.83J 13.11 4.61 MW-E Rep 20-Dec-18 321 0.111 7.1J 131 MW-E Deep 4-May-11 2.96J 2,530 0.251 0.181 1.141B 66.4 3.11J 20 30.81 57.9 MW-E Deep 8-Nov-11 3.661 2,280 0.161 0.221 54.2 1.38J 16.4 26J 43.5 MW-E Deep 8-May-12 2.51J 2,211 0.531 1.361 50.1 31.6 94 24.91 7.651 60.9B MW-E Deep 28-Nov-12 0.711 3.861 1,820 0.841 1.99 4.561 39.6 22.3 213 26.1J 0,181 9.201 67.2 MW-E Deep 8-May-13 4.561B 1,730 0.34J 0.711 37.9 4.7J 74.5 20J 43 MW-E Deep 6-Nov-13 1.091 2,240 0.19J 0.321 39.7 2.34J 39.3 20.5J 16JB 41.2B MW-E Deep 6-May-14 269J 2,080 0.60J 0.44J 63.4 6.29J 60.9 32.7J 2.491 32.2B 1302-MSWLF- MW-E Deep 4-Nov-14 3.29J 2,000 0.311 0.47J 43.6 6.411 55.6 20.4J 3.75JB 30.0 CDLF-1998 MW-E Deep 5-May-15 2.42J 2,040 0.251 0.19J 34.4 2.70J 22.2 17.31 0.87J 2.541 19.3 MW-E Deep 27-0R-15 2.55J 1,91 0.281 0.23J 34.3 4.341 38.2 14.21 2.S1CN,J 2.97J 24.3B-01 MW-E Deep 18-May-16 3.54J 2, 150 0.481 0.67J 0.931 37.0 8.73J 76.4 16DJ 1.07J 8.52J 30.6 MW-E Deep 1-Nov-16 2.43J 1,960 0.221 0.181 34.5 2.34J 18.5 14.61 19.3 MW-E Deep 9-May-17 1.68B-01,J 2,010 0.231 32.9 0.59J 3.96J 14.51 8.051 MW-E Deep 1-Nov-17 1.65J 2, 100 0.261 0.461 32.3 1.63J 9.691 15.21 0.061 8.011 MW-E Deep 11-Jun-18 2.1J 2,310 0.211 33.5 2.1J 13.91 4.81 MW-E Deep 20-Dec-18 I 1.31 1 2,640 0.261 I I 1.6J 39.1 1 1 6.7J I I 1 21.21 1 1 5.21 MW-F 4-May-11 136 0.141 0.75JB 1.291 0.91J 3.151 2.241 MW-F 9-Nov-11 0.171 5.42J 219 0.061 10.6 1.06J 4.44J 1.571 MW-F 9-May-12 3.19J 242 8.351 1.27J 3.331 0.921 2.85J 2.341B MW-F 29-Nov-12 283 O.15J 1.861 8.50J 1.07J 0.591 5.001 1.521 3.76J 4.46J MW-F 30-May-13 1.17J 154 0.2 JJ 1.63JB 5.161 1.56J 0.15J 2.78J 2J 0.121 4.86J MW-F 6-Nov-13 2.011 255 11.2 0.82J 0.19J 3.451 0.831 12.71B 2.431B MW-F 8-May-14 5.17J 213 0.161 30.4 0.97J 0.54J 4.881 1.041 6.841 1.77J 1302-MSWLF- MW-F 4-Nov-14 2.92J 262 0.21 11.3 0.801 0.45J 5.51J 3.09J 1.25J CDLF-1998 MW-F 5-May-15 0.311 2.29J 129 0.111 1.391 0.73J 0.10J 4.57J 1.85J MW-F 28-OR-15 5.941 262 0.451 13.0 0.79J 0.14J 4.80J 1.92CN,J 3.67E-01) MW-F 18-May-16 3.40J 214 9.62J 3.84J MW-F 3-Nov-16 231 0.141 7.64J 4.631 MW-F 11-May-17 0.87B-01,J 190 0.121 4.10J 0.081 5.001 MW-F 31-011-17 0.801 363 13.4 4.31J 1.33J MW-F 6-Jun-18 2.4J 149 0.481 3.11 3.61 Lai 7.11 6.7J 6.4.1 MW-F 19-Dec-18 0.811 103 0.101 1.3.1 5.81 MW-F(dup) 19-Dec-18 I 1.01 1 107 0.101 1 1 1.3.1 1 1 6.11 MW-G 4-May-11 148 0.081 0.19J 1.07JB 14.6 12.6 1.15J 32.5J 8.161 4111J MW-G 9-Nov-11 0.14J 2.75J 420 0.12J 4.99J 0.87JB 3.17J 2.791 2.51J MW-G 9-May-12 4.45J 302 2.19J 0.861 4.401 1.41J 4.25J 13.7B MW-G 29-Nov-12 2.031 385 0.151 2.141 0.961 0.121 3.69J 3.03J 2.79J 2.86J MW-G 10-May-13 354 0.181 5.081 1.191 0.14J 2.43J 1.51J 2.311 5.14J MW-G 6-Nov-13 5.44J 346 3.09J 0.81J 0.09J 4.81J 2.75J 12.4JB 2.49JB MW-G 8-May-14 4.42J 373 0.201 6.69J 1.311 0.27J S.00J 2.95J 7.99J 4.OSJ 1302-MSWLF- MW-G 4-Nov-14 480 0.261 7.02J 2.571 0.611 9.32J 2.96J 0.17J 10.6JB 6.72J CDLF-1998 MW-G 5-May-15 2.13J 340 0.181 5.62J 2.30J 0.37J 5.29J 4.79J 4.85J 4.16J MW-G 28-0R-15 4.45J 387 0.141 1.231 5.01J 0.741 0.191 4.881 2.09CN,J 2.76J 3.69E-01,J MW-G 19-May-16 3.19J 412 0.151 1.311 6.07J 0.89J 0.26J 5.071 4.721 4.62J MW-G(du p) 19-May-16 0.318-01,1 3.51J 417 0.111 1.051 5.37J 0.091 3.64J 2.55J 2.081 MW-G 3-Nov-16 6.65J 418 0.091 1.231 3.67J 1.00J 5.36J 5.04J MW-G 11-104y-17 0.46J 2.21J 448 0.351 2.751 7.45.1 2.82J 1.141 5.53) 1.72J 0.091 13.21 10.5 MW-G 1-Nov-17 5.93J 488 0.101 0.95J 5.961 0.091 5.391 2.411 2.66J MW-G 6-Jun-18 5.2J 448 0,0111 6.31 4.5J 2.2J MW-G 19-Dec-18 1.4J 331 0.20J 6.31 2.51 3.1J 3.8J Smith Page 4 of 16 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-H 5-May-11 J V 2 0.31J t. 9.05J o J1J J1 6.94J 1.681 J 1 i.D 6.891 J 2D , , 0.081 9.851 000 16.9 0.71J MW-H 9-Nov-11 0.141 0.13J 2.69J 2.93J 0.59J 2.831 7.37J MW-H 9-May-12 0.131 3.581 0.891 4.23J 1.17J 3.171 5.791 12.1E MW-H 29-Nov-12 F44.9 1.68J 0.25J 1.62J 0.29J 1.131 2.891 5.65J MW-H 9-May-13 1.941 0.211 1.331 0.221 1.11 2.681 5.451 MW-H 7-Nov-13 0.38J 4.94J 2.511 6.39J 2.651 5.96115.4J 16.4E MW-H 8-May-14 0.47J 3.48J 1.731 6.341 2.121 4.491 9.00J 14.2 1302-MSWLF- MW-H 6-Nov-14 49.81 0.17J 2.04A 0.951 3.67J 0.951 2.97J 5.331 7.5518 CDLF-1998 MW-H 5-May-15 1.20J 52.51 0.201 0.50JB 0.891 4.34J 1.27J 2.941 4.631 7.65J MW-H 29-Ocb15 1.851 78.11 0.481 8.221 2.56J 8.56J 2.511 7.191 2.571 4.201N,1 0.091 14.71 22.9E-Ol MW-H 19-May-16 1.24J 52.3J 0.251 4.011 1.161 3.62J 1.26J 3.271 1.521 8.621 9.43J MW-H 3-Nov-16 67.81 0.33J 5.811 1.96J 5.86J 1.781 5.591 2.871 10.71 15.7 MW-H 11-May-17 0.851 64.81 0.281 6.821 1.831 4.76J 1.68J 6.28J 2.391 0.091 10.21 12.5 MW-H 1-Nov-17 0.62J 59.51 0.23J 4.10J 1.20J 4.29J 1.29J 3.511 3.111 S.68J 9.69J MW-H 7-Jun-18 1.2J 56.6J 0.26J 3.8J 1.21 4.7J 1.31 3.2J 8.11 9.61 MW-H 19-Dec-18 1.1J 74.7J 0.53J 7.8J 2.61 1 9.81 i 2.81 I 6.6J 1.81 15.OJ 17.9 MW-H Deep 5-May-11 57.51 0.22J 4.331B 0.821 4.351 1.571 2.651 7.231 7.841 MW-H Deep 9-Nov-11 29.21 0.05J 1.171 0.711 2.07J 0.451 1.62J 2.55J MW-H Deep 9-May-12 0.741 49.61 0.181 3.41J 0.951 5.671 1.421 2.911 7.531 13.2B MW-H Deep 28-Nov-12 52.4J 1.281 1.59J 0.96J 2.441 2.621 MW-H Deep 9-May-13 0.831 43J 0.47J 2.2J 0.221 1.45J 6.98J MW-H Deep (dup) 9-May-13 0.24J 44.11 1.051 0.191 1.72J 0.22J 1A 3.34J 13.3 MW-H Deep 7-Nov-13 40.91 0.281 1.85J 0.23J 1.391 12.IJ 5.291B MW-H Deep 8-May-14 55.OJ 0.30J 0.32J 2.03J 0.37J 1.63J 3.891 1302-MSWLF- MW-H Deep 6-Nov-14 49.91 0.081 1.33JB 1.45J 0.191 2.001 4.18J 9.2518 MW-H Deep (dup) 6-Nov-14 49.41 1.54JB 0.501 1.741 0.27J 1.93J 6.321B CDLF-1998 MW-H Deep 5-May-15 1.841 44A 0.29J 2.69J 0.381 1.971 2.00J 2.001 MW-H Deep (dup) 5-May-15 39.81 0.13J 1.081 0.31J 2.881 0.37J 2.26J 3.23J MW-H Deep 29-Oc[-15 45.91 0.64J 1.491B 0.23J 1.571 3.82CN,1 4.80J 3.06B-01,J MW-H Deep 19-May-16 55.91 0.121 0.87J 2.36J 0.45J 1.33J 0.101 5.451 2.271 MW-H Deep 3-Nov-16 54.71 1.14J 0.25J 0.89J MW-H Deep 11-May-17 50.5J 0.76J 1.341 0.441 1.23J 3.84J 7.301 MW-H Deep 1-Nov-17 53.0J 0.381 0.82J 0.181 0.801 4.12J 1.831 MW-H Deep 7-Jun-18 0.791 61.9J 0.066J 1.4J 0.281 5.01 2.21 MW-H Deep 19-Dec-18 47.41 0.059J 0.291 3.4J MW-1 4-May-11 26.31 0.161 4.871B 0.291 0.941 0.441 2.441 4.151 3.141 MW-I 9-Nov-11 0.301B 12J 0.12JB 0.661 0.111 0.811 1.241 0.28J 3.36J MW-I 9-May-12 0.251 17.61 0.33J 1.801 0.201 1.651 0.27J 3.01J 3.531 11.5B M. (dup) 9-May-12 16.2J 0.37J 1.77J 1.11J 0.23J 2.39J 8.561B MW-I 28-Nov-12 0.30J 14.3J 0.73J 0.44J 0.941 2.491 1.051B MW-1 30-May-13 0.491 17.81 0.221 0.07J 1.38JB 0.34J 0.79J 0.31J 1.32J 3.391 MW-I 7-Nov-13 14.2J 0.1. 0.21J 0.591 0.20J 1.41J 6.83J 2.611B 1302-MSWLF- MW-1 7-May-14 13.9J 0.13J 3.44JB 0.77J 0.191 1.31J 1.311 1.53JB CDLF-1998 MW-1 5-Nov-14 20.7J 0.161 0.011 0.821 0.26J 0.90J 0.31J 1.561 2.55JB 1.701 MW-I 5-May-15 0.501 15.4J 0.17J 1."1 1.71J 0.33J 1.85J 1.861 MW-I 29-Oc[-15 21.11 0.27J 1.301 0.62J 0.28J 1.57J 4.40CN,1 4.71J 4.32B-Ol,l MW-I 19-May-16 0.378-01,1 20.7J 0.201 1.071 0.33J 1.75J 3.09J 2.421 MW-1 3-Nov-16 24.2J 0.291 0.071 1.301 0.55J 0.841 1.43J 3.581 MW-I 11-May-17 26.3J 0.23J 0.081 1.251 0.55J 0.79J 1.481 3.641 2.451 MW-I 31-Oc[-17 23.4J 0.23J 1.30J 0.39J 0.51J 1.211 3.95J 3.011 MW-I 7-Jun-18 24.4J 0.181 0.35J 1.01 3.11 2.61 MW-1 18-Dec-18 31.0] 0.23J 0.15J I 2.3J 0.64J 1.61 3.91 4.61 MW-1 4-May-11 38.4J 0.311 6.141 2.011 31 2.4J 1.471 0.081 131 11.2 MW-J 9-Nov-11 0.161B 35.3J 1.551 0.441 1.26J 0.271B 5.84J 0.12J 5.981 MW-J 9-May-12 15.21 1.64J 0.38J 1.411 0.52J 2.76J 3.35J 15B MW-J 29-Nov-12 16.41 1.39J 0.30J 2.54J 0.30J 1.20J 3.93.1 4.891 MW-J 8-May-13 30.61 0.861 0.31J 1.16J 0.27J 1.381 4.811 2.71 MW-J 6-Nov-13 17.8J 0.791 1.43J 0.91J 2.281 21.4JB 4.73JB MW-1 7-May-14 31.6J 3.02JB 0.52J 1.41J 0.83J 2.03J 3.401 4.2418 1302-MSWLF- MW-J 4-Nov-14 27.4J 0.171 1.45J 1.24J 2.00J 1.16J 3.54J 9.58JB 6.38JB CDLF-1998 MW-J 6-May-15 10.7J 1.381 0.51J 2.00J 0.63J 2.48J 3.511 3.36J MW-J 28-0R-15 I1.OJ 0.58B-01,1 0.451 1.64J 0.381 2.06J 3.59CN,J 2.47J 5.911 MW-1 18-May-16 0.961 28.2J 0.251 3.1lJ 1.40J 1.621 1.991 3.55J 0.901 12.OJ 6.86J MW-J 2-Nov-16 32.2J 0.281 4.861 2.51J 2.38J 2.97 J 5.69J 1.661 14.9J 11.0 MW-1 9-May-17 18.81 0.111 1.661 0.731 0.97J 1.02J 2.04J fi.181 4.41J MW-J 1-Nov-17 18.7J 0.13J 2.59J 0.921 0.98J 1.24J 2.211 8.181 6.22J MW-1 7-Jun-18 1.2J 37.8J 0.351 5.61 2.9J 2.5J 3.3J 6.01 19.11 14.6 MW-J 19-Dec-18 16.7J 0.1. 2.11 0.91J 1.31 2.51 7.21 6.9J MW-K 4-May-11 25.21 0.261 6.521 1.57J 2.25J 1.531 3.65J 111 7.96J MW-K 9-Nov-11 17.71 0.14JB 2.51J 0.731 3.67J 0.73J 2.07J 0.071 4.96J 4.09J MW-K 9-May-12 35.2J 0.221 7.591 2.981 3.66J 1.92J 6.06J 13.51 20.1B MW-K 28-Nov-12 16.11 1.31J 0.281 0.71 0.281 1.42J 2.53J 4.4418 MW-K 8-May-13 1.02JB 17J 0.151 1.911 0.71J 1.331 0.691 2.24J fi.05J 5.28J MW-K 6-Nov-13 13.91 2.681 0.76J 1.26J 0.43J 1.94J 23JB 4.681B MW-K 7-May-14 17.51 0.121 4.27JB 0.49J 1.30J 0.70J 1.83J 3.49J 2.4618 1302-MSWLF- MW-K 5-Nov-14 13.31 0.131 1.21J 0.53J 1.20J 0.431 1.97J 3.82JB 3.191 CDLF-1998 MW-K 5-May-15 1.42J 15.31 0.141 0.49J 1.99J 0.71J 2.54J 4.661 2.951 MW-K 29-0R-15 0.35J 26.2J 0.191 2.54B-01,1 1.161 2.41J 1.041 4.171 2.87CN,J fi.181 5.60J MW-K I8-May-16 1.43J 17.8J 0.161 3.25J 0.89J 1.03J 0.831 2281 1.181 S.fiSJ 5.35J MW-K 2-Nov-16 17.81 0.161 2.601 0.87J 0.94J 0.72J 2.04J 1.781 4.01J MW-K(dup) 2-Nov-16 4.051 1.311 0.63J 0.181 1.17.1 1.081 2.181 MW-K 9-May-17 0.47B-01,J 13.91 0.101 1.901 0.47J 0.62J 0.41J 1.59J 4.411 1.92J MW-K 1-Nov-17 0.82J 20.2J 0.161 3.28J 1.23J 1.03J 0.87J 2.20J 8.121 4.57J MW-K 7-Jun-18 0.94J 0.881 13.8J 0.131 2.2J 0.59J 1.3J 6.21 221 MW-K 19-Dec-18 15.7J 0.31J 0.121 2.OJ 0.49J 1.11 4. 2.61 Smith Page 5 of 16 February 2019 Table 5a Detected Groundwater Constituents - Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-L 4-May-11 I IrV 2 Ji. 45.7J 2.67JB o trlr 0.35J rl 0.7J 0.21 r rr 1.641 r 2D r r rrr 3.961 ZMW-L 9-Nov-11 0.191 40.9J 0.06J 1.64J 0.411 0.931 0.37J 1.49J 3.721 MW-L 9-May-12 43.8J 1.20J 0.521 0.09J 1.271 1.93J 2.16JB MW-L 28-Nov-12 0.821 23.OJ 1.74J 0.32J 0.39J 2.211 6.4A 3.75J MW-L 9-May-13 1.24JB 43.5J 1.121 0.491 0.83J 1.951 2.9J 3.29J MW-L 7-Nov-13 49.2J 0.191 0.88J 1.201 %21 2.49J 0.851 3.621 31.91 11.5E MW-L 8-May-14 43.7J 0.07J 0.67J 0.141 1.281 1.951 1302-MSWLF- MW-L 5-Nov-14 38.6J 0.76J 0.14J 1.32J 2.44J 2.28JB CDLF-1998 MW-L 6-May-15 40J 0.811 0.161 1.27J 2.23J MW-L 28-Oct-15 33.5J 1.05J 0.29J 0.31J 1.07J 4.04CN,1 2.871 6.06E-01-J MW-L 19-May-16 38.4J 0.881 1.011 2.23J 1.48J MW-L 2-Nov-16 35.21 1.00J 1.041 2.46J MW-L 30-May-17 0.56B-01,J 33.31 1.011 0.49J 0.111 0.951 2.34J 2.80J MW-L 1-Nov-17 33.9J 1.23J 1.30J 0.121 0.851 1.46J 1.87J MW-L 7-Jun-18 32.7J 2.71 60.9 MW-L 19-Dec-18 34.4J 0.0791 MW-LD- 4-May-11 0.44J 56.81 0.34J 1.4.7 3.6J 3..3 13....4 15.21 12.7 MW-Le 9-My-12 0621 231 .2MW-LDeep 0.681 31 831 7.991 30-May-13 0.41J 1% 084J1891 ..00 0.27J 1.613 IL 21.8 MW-L Deep 8-May-14 279 1.341B 0111 1321 6.061 1302-MSWLF- MW-L Deep 6-May-15 0.36J 23.11 0.90 1.24J 1.501 2.45J 45.1 CDLF-1998 MW-LDeep 29-0c-15 0.581 23.01 0.47E-0 1.231 009J 1.62J 3.73CN,J 81.1 MW-LDp 19-May-16 30." 0.44J 8 0.171 1.27 4.59J 116 30-May-17 031-Ol 34.4 0.42J 0.14J 1 1 27J 4.73J 128 MMW-LDeep W-L Deep(dup) 30-May-17 1B-Ol,J 33 0.07J 0.40J 0.821 051 1281 4.701 123 MW-LDeep 7-Jun- 32.11 IAA 24J 352 MWM 5-May-11 64.2 56J .56J 261 2.64 15.6 4.83J 5.841 0.141 18.2J 15.2 9My-12 4031 0 82211 0 3MW 80J 1 15.2B MW-M 30-May-13 34.91 0.161 1.441B . 0.51 1.68 2.21 1302-MSWLF- MW-M 8-May-14 37.1 030 0.801 3 001 2021 0.63J 1911 2421 CDLF-1998 MW-M 5-May-15 1.931 39.4 0.8812.0J 0 2181 4.071 1.71J MW-M 29-0c-15 3 0.30 1.56E-01,J 0.39J 2.101 2J 2.101 309CN1 1.78J 4.96J MW-M 18-May-16 0.921 38.81 0.6 0.46J 1.601 05 1.471 6.84J 18Dep 1.54 MW-M 9-May-17 404J 0.081 0.65J 1.50 0.57J 1.181 4.651 1981 MW-M 7-Jun-18 37.91 0.311 0.991 1 4.01 MW-X 4-May-11 0.32J 51.51 0.211 7.8J 2.911 1.491B 111 0.081 12.21 12.3 MW-x 9-Nov-11 23.11 0.221B 2.97J 2.46J 1.771 4.341 0.071 10.5J 6.751 MW-X 9-May-12 34.91 1.521 1.37J 5.63J 8.7711 MW-X 29-Nov-12 29.31 1.801 0.33J 1.31J 0.25J 4.74J 5. 2.1718 MW-X 29-Nov-12 32.0J 3.201 0.75J 1.54J 0.39J 5.79J 5.631 4.821E MW-X 8-May-13 1.531B 35.41 0.77J 0.73J 1.81 0.24J 6.37J 3.12J 4.551 MW-X 6-Nov-13 24.11 1.121 0.35J 1.04J 0.32J 4.27J 18.21B 3.961E 1302-MSWLF- MW-X 7-May-14 37.01 0.051 4.911E 0.73J 1.25J 0.44J 5.74J 4.70J 3.841E CDLF-1998 MW-X 5-Nov-14 26.81 2.581E 0.36J 0.97J 0.191 3.67J 11.21 2.101B MW-X 6-May-15 28.91 1.861 0.32J 2.681 0.21J 4.33J 2.51J 1.421 MW-X 29-0R-15 27.81 2.08E-Ol,J 1.29J 4.65J 3.24CN,J 1.741 MW-X 18-May-16 0.861 32.01 1.711 0.52J 0.681 0.34J 4.38J 6.501 2.221 MW-X 2-Nov-16 32.31 1.701 1.60J 0.29J 3.56J 2.691 MW-X 9-May-17 30.4J 1.31J 0.71J 0.281 4.03J 3.84J 3.221 MW-X 1-Nov-17 29.6J 1.781 0.681 0.23J 2.64J 5.37J 2.681 MW-X 7-Jun-18 37.4J 0.121 4.3J 0.90J 1.5J 0.62J 5.01 11.7J 4.51 MW-X 19-Dec-18 28.51 3.2J 3.31 Notes. 1. All units are in micrograms per liter (parts per billion). 2. Monitoring wells M W-3 Deep, -L Deep, -and -Mare sampled annually during the spring event. 3. ' - Interim Maximum Allowable Concentration (IMAC) 4. (dup) - Duplicate 5.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 6. BIB-01- Indicates constituent was detected in the batch blank above the method detection limit. 7. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used. S. The November 2012 sampling event was the first event that CD-is/CD-ld replaced M W-9 as the background monitoring wells. 9. MW-9 was removed from the monitoring program in November 2012. 10. M W-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. 11. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit or not analyzed. Smith Page 6 of 16 February 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 CD-ls 3-May-11 CD-ls 8-Nov-11 CD-ls ]-May-12 CD-ls 27-Nov-12 0.41 O.JJ CD-ls ]-May-13 CD-ls 5-Nov-13 CD-ls &May-14 1302-MSWLF- CD-ls 4-Nov-14 CDLF-1998 CD-ls 5-May-15 CD-ls 27-0c[-15 CD-ls 17-May-16 CD-ls 1-Nov-16 CD-ls 9-May-17 CD-ls 31-01t-17 MD 114 -18 11s CD 17-Dec-18 1.2 CD-ld 3-May-11 CD-ld 8-Nov-11 CD-ld 7-May-12 CD-ld 27-Nov-12 CD-ld 7-May-13 CD-ld 5-Nov-13 CD-ld 6-May-14 1302-M5WLF- CD-ld 4-Nov-14 CDLF-1998 CD-ld 5-May-15 CD-ld 2]-Oct-15 CD-ld 1]-May-16 CD-ld 1-Nov-16 CD-ld 9-May-17 CD-ld 31-0ct-17 CD-ld 124 -18 CD-ld 17-Dec-18 CD-4 Rep 3-May-11 CD-4 Rep (dup) 3-May-11 CD-4 Rep 8-Nov-11 CD Rep 8-May-12 CD Rep 28-Nov-12 0.31 CD-4 Rep 9-May-13 CD Rep 7-Nov-13 0.61 1302-MSWLF- CD-4 Rep GMay-14 CDLF-1998 CD-4 Rep 4-Nov-14 CD-4 Rep &May-15 CD-4 Rep 27-0ct-I1 CD Rep 17-May-I6 CD-4 Rep 2-Nov-I6 CD-4 Rep 9-May-17 CD Rep 31-0ct-17 CD-4 Rep &Jun-I8 CD-4 ftep 19-Dec 18 CD-6 3-May-11 O.JI 0.91 CD-6 8-Nov-11 1.J1 1.4 0.61 CD-6 &May-12 2.21 1.] 0.91 CD 2&Nov-12 2.81 0.41 1.2 0.81 CD-6 &May-13 3.61 1.6 1.3 1302-MSWLF- CD-6 ]-Nov-13 36J 1.2 0.6J 1.4J ].8 8.4 0.61 5] 0.51 1.2 4.6 2.4 2.7 CDLF-1998 CD-6 6-May-14 5.2 0.31 1.1 1.2 CD-6 4-Nov-14 4.J1 0.31 1.4 1.2 CD-6 6-May-15 3.J1 1.5 1.1 CD-6 27-0ct-15 3.11 1.0 0.91 CD-6 17-May-16 1.51 0.51 O.J1 CD-6 1-Nov-16 2.21 0.61 0.91 AMW-ls 3-May-11 0.51 11 0.91 L 15 O.JI 3.0 3.8 AMW-ls 8-Nov-11 0.51 0.]1 0.91 M. O.JI 15 O.JI 3.1 3.1 AMW-ls 7-May-12 0.]1 11 1 0.81 16 0.81 3.5 3.9 AMW-ls 2M -12 0.61 0.81 1.1 10 O.J1 14 0.61 3.2 3.4 AMW-ls &May-13 0.91 0.91 1.4 13 0.91 18 11 4.1 4.3 AMW-Ss 6-Nov-13 0.91 0.91 1.3 13 0.91 IS u 3.8 3.9 AMW-Ss 7-May-14 0.91 0.91 1.1 9.8 0.]1 12 1.4 3.6 2.1 1302-MSWLF- AMW-Ss 5-Nov-14 0.61 1.01 9.0 0.51 10 2.5 2.8 CDLF-1998 AMW-Ss 7-May-15 0.81 1.3 6.1 0.51 9.9 0.91 3.1 2.6 AMW-Ss 29-Oct-15 0.41 0.81 0.81 5.8 6.1 1.6 14 AMW-Ss 18-May-16 0.61 0.51 0.91 5.7 7.6 0.61 1.8 l.J AMW-Ss 2-Nov-16 0.21 1.11 24 2.81 IS 10 ].1 0.91 AMW-Ss 10-May-17 0.71 0.91 8.3 0.91 2.1 1.8 AMW-Ss 1-Nov-1J 0.31 8 �4.27Jj 3.21 1.3 0.91 AMW-Ss &Jun-18 0.551 0.]O1 5.] 1.111AMW-Ss 19-Dec-18 0.63J 0.54J . 6.9 1.6 1.6 l.J AMW-Sd 3-May-11 1.1 21 1.11,8 0.81 24 1.91 28 0.31 4.2 4.] 0.31 AMW-Sd 8-Nov-11 1.2 1.41 0.81 28 1.81 30 0.51 0.61 5.8 0.31 0.41 AMW-Sd 7-May-12 1.2 1.71 0.91 27 1.81 35 0.41 041 1.] 4.8 OA1 AMW-Sd 2&Nov-12 1.2 5.01 1.31 0.91 29 1.91 36 0.61 0.41 2.0 5.0 AMW-Sd &May-13 1.1 21 1.7 26 0.2J 21 40 0.61 6.2 OA1 AMW-Sd 6-Nov-13 1.1 2.61 0.81 29 2.21 38 0.41 0.51 5.2 0.51 AMW-Sd ]-May-14 1.2 2.21 1.0 30 2.31 36 0.61 1.6 ].3 0.61 1302-M5WLF- AMW-Sd 5-Nov-14 1.3 1.]1 1.01 31 1.31 13 0.51 0.]1 3.2 0.31 29 CDLI1998 AMW-Sd 7-May-15 1.2 1.21 1.1 24 0.71 7.1 0.41 1.2 1.9 38 AMW-Sd 29-0ct-15 1.0 2.01 0.71 23 2.81 20 AMW-Sd 18-May-16 1.1 0.91 33 9.] 1.6 8.0 AMW-Sd 3-Nov-16 1. 2.21 1.0 26 0.81 ].0 13 AMW-Sd 10-May-1] 1.01413.81 ].4 AMW-Sd 1-Nov-1J IA 3.012] 0.]1 10 2.81 �51 8.0 AMW-Sd &Jun-IB.1 1.51 0.891 18.2 11.] 2.6AMW-ld 1&Dec-18 1.] 2.21 l.J 24A 0.]91 13.0 O.SL 3.1 Smith Page 7 of 16 February 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 AMW-2s 3-May-11 0.81 SO ll 2.81 2.5 5.4 3 0.]1 AMW-2s 8-Nov-11 0.81 11 lJ 3.81 2.9 5 3.2 O81 AMW-2s 8-May-12 0.81 12 1.21 4.31 2.J 5.8 3.8 0.91 AMW-2s 29-Nov-12 0.]1 12 1.11 4.91 2.2 6.4 4.1 0.81 AMW-2s 9-May-13 9 0.81 4.]1 1.4 5.2 3.9 0.61 AMW-2, 6-Nov-13 30 0.91 4.81 1.3 4.9 3.9 0.]J AMW-2s ]-May-14 0.51 12 0.81 5.1 1.2 4.6 3.3 0.51 1302-MSWLF- AMW-2s 5-Nov-14 12 0.91 6.4 0.91 5.5 4.2 0.61 CDLF-1998 AMW-2s 6-May-15 9.3 0.61 5.5 0.61 4.2 3.1 0.41 AMW-21 28-Oc[-15 6.4 5.] O.JJ 3.3 2.6 AMW-2s(dup) 28-Oc[-15 6.4 0.]1 5.9 O.JI 3.1 2.9 AMW-2s 17-May-16 B.5 6.4 O.JI 3.5 3.0 AMW-21 1-Nov-16 30 0.81 8.0 0.9) 4.1now AMW-2s 10-May-1J B.0 6.3 0.61 2.5 2.2 AMW-2s 1-Nov-1J B.J 0.71 7.5 2.6 2.9 AMW-2s 8-Jun-18 3.4 6.3 5.9 1.5 1.J AMW-2s 20-D-18 5.5 5.3 1.8 1.8 AMW-2d 3-May-11 5.6 0.91 1.41 2 4.0 2.3 1.4 AMW-2d 8-Nov-11 8.8 D 1.91 1.2 6.5 2.8 1.3 AMW-2d &May-12 9.7 D 2J 1 6.1 3.1 1.1 AMW-2d 2&Nov-12 11 1.21 2.51 6.6 3.2 0.11 AMW-2d &May-13 12 1.21 4.61 1.1 7.8 4 1.2 AMW-Nov 6-Nov-13 9.4 0.61 9.1 O.J1 2.9 1.9 01..64 AMW-2d 7-May-14 0.1J 6.J 2. AMW-2d 5-No14 4.21302-MSWLF 0.91 CDLF-1998 AMW-2d &May-15 19 1.51 8.4 1.3 9.8 6.3 0.81 AMW-2d 2&0c[-15 14 0.81 6.3 1.3 4.3 3.7 0.61 AMW-2d 1]-May-16 0.5J 0.31 1.01 9.2 1.3 J.6 5.2 0.11 AMW-2d2-Nov-16 0.41 0.5J 6.2 2.01.2AMW-2d 10-May-1J 1.J 13J.9 6.6 AMW-2d 2-Nov-1J 061 1.5J L17 2.61 19 8.J .J061AMW-2d &Jun-18 0.281 0.]21 1.51 15.3 4.5 5.9 AMW-2d 20-De 18 0.]]J 0.721 1.0 1].8 4.2 6.8 MW-1 3-May-11 O.JI MW-1 8-Nov-11 0.41 MW-1 &May-12 0.41 0.71 MW-1 27-Nov-12 0.41 0.81 MW-1 &May-13 MW-1 5-Nov-13 1.01 0.41 MW-1 ]-May-14 0.41 0.41 2.41 0.91 0.51 0.41 MW-1(dup) 7-May-14 0.3J 0.41 2.41 0.91 0.51 0.4) 1302-MSWLF- MW-1 3-Nov-14 1.31 0.41 0.41 CDLF-1998 MW-1 5-May-15 0.41 1.11 0.41 MW-1 27-0ct-15 0.51 MW-1 18-May-16 1.21 0.61 MW-1 1-Nov-16 1.01 MW-1 10-May-17 1.11 MW-1 31-0ct-17 1.11 MW-1 7-Jun-18 1.31 ,I (dup) 7-Jun-18 1.41 0.601 MW-1 1&De 18 1.91 0.741 MW-3 4-May-ll 7.4 1.41 0.81 13 4 1.1 MW-3 9-Nov-11 12 1.J1 1.81 O.JI 36 5.3 1.2 MW-3 (dup) 9-Nov-11 13 2J 1.81 O.J1 35 5.3 1.6 MW-3 &May-12 9.6 1.J1 1.21 0.51 IJ 5.4 1.3 MW-3 2M -12 12 1.41 1.91 0.91 35 5.2 MW-3 &May-13 10 1.41 1.J1 0.61 38 5.J 1.1 MW-3 ]-Nov-13 12 1.51 1.J1 0.61 35 5.1 1.0 1302-MSWLF- MW-3 &May-14 35 2.01 2.61 O.JI IJ 6.1 1.0 CDLF-1998 MW-3 6-Nov-14 36 1.81 3.61 O.JI 38 J.4 1.2 MW-3 &May-15 14 0.81 3.11 0.61 IJ 5.9 0.91 MW-3 2&0ct-15 13 1.41 3.81 13 5.2 0.81 MW-3 18-May-16 13 1.31 4.11 0.61 35 6.0 0.81 MW-3 2-Nov-16 14 2.41 4.81 0.61 14 S.J 1.2 MW-3 11-May-1J 13 1.31 4.01 0.61 13 5.8 0.91 MW-3 1-Nov-1J 0.81 36 2.11 5.91 13 6.6 1.2 MW-3 7-Jun-18 15.8 2.31 5.7 0.51J 6. S.J 0.831 MW-3 19-D-18 21.3 1.91 10.4 0.591 1 7.0 0.951 MW-3 Deep 4-May-ll 0.51 MW-3 Deep &May-12 0.41 MW-3 Deep 10-May-13 IJ 0.61 0.41 1302-MSWLF- MW-3 Deep &May-14 0.41 CDLF-1998 MW-3 Deep &May-15 1.21 0.41 0.41 MW-3 Deep 2&Oc[-15 1.41 0.41 MW-3 Deep 19-May-16 1.21 MW-3 Deep 11-May-1J 1.01 MW-3 Deep 7-Jun-18 1.41 1302-MSWLF- MW-9 3-May-11 0.81 CDLI1998 MW-9 MW-9 9-Nov-11 9-May-12 1.1 1.4 MW-A 3-May-11 JA 11 4.71 12 14 2.2 110 0.41 2.2 0.81 3.9 3.11 3.2 O.JI MW-A 9-Nov-11 9.2 1.41 6.51 36 36 2.6 120 0.61 2A 2 6.5 5.2 3.8 11 MW-A 9-May-12 8.8 1.11 6.51 IJ 26 3.8 0.51 110 OAJ 2 0.91 6.5 2.61 0.51 4.1 0.21 1.1 MW-A 2]-Nov-12 9.3 1.61 6.91 15 25 3.9 0.61 130 0.51 2.2 0.41 0.51 4.J I.J1 0.41 4.4 0.81 MW-A ]-May-13 9.1 1.31 5.11 22 23 3 0 41 120 0.51 2A 0.61 0.81 6.2 0.31 B.0 4.3 MW-A 5-Nov-13 11 1.41 5.71 0.41 25 22 4.1 130 1.4 6.2 6.0 3.8 1.0 MW-A &May-14 11 1.31 5.61 0.3J 28 38 3.6 0.21 120 OAJ 2.2 O.J1 4.6 S.3 0.41 5.8 3.3 1.0 1302-MSWLF- MW-A 4-Nov-14 9.5 1.61 5.61 0.31 31 21 2.6 130 O.SJ 0.41 1.1 5.J 2.01 4.5 1.01 CDLF-1998 MW-A 5-May-15 9.3 1.. 5.01 0.31 24 36 2.5 110 0.5J 2.2 0.81 0.81 5.6 0.41 5.3 3.6 0.61 MW-A 2]-O t-15 9.1 IAJ 5.41 28 15 2.3 110 0.71 0.81 5.9 0.31 4.4J 3.9 O.JI MW-A 1]-May-36 9.J 1.51 31 IS 1.3 110 2.2 1.1 1.4 4.8 0.61 5.2 3.7 0.81 MW-A 1-Nav-36 11 1.61 5.]1 36 IJ 1.6 1, 0.51 2.6 O.JI 1.4 S.J 4.71 3.8 0.91 MW-A 9-May-1] 9.5 1.41 4.51 30 13 1.0 120 0.51 1.9 0.81 1.6 4.8 0.41 4.81 3.1 0.71 MW-A 31-0`17 12 1.41 4.41 35 IS 1.J 140 2A 0.91 2.6 S.3 3.J MW-A J-Jun-IB 8.3 4.51 D. 2.91 I6.6 10.6 100 0.661 1.5 1.5 2.8 MW-A 2&Dec-18 11.0 1.41 4.21 20.3 13.3 1.7 133 0.521 2.1 3.1 2.61 2.8 Smith Page 8 of 16 February 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-B 3-May-11 IIMIMII MW-B 8-Nov-11 MW-B 8-May-12 MW-B 28-Nov-12 0.91 MW-B 9-May-13 MW-8 5-Nov-13 7 MW-e 7-May-14 1302-MSWLF- MW-B 3-Nov-14 CDLF-1998 MW-B 5-May-15 MW-B 28-0c[-15 MW-B 18-May-16 MW-B 2-Nov-16 MW-B 10-May-17 MW-B 31-Oc[-1] MW-B 6-Jun-18 MW-B 19-Dec-18 20.3 0.531 MW-C 3-May-11 MW-C 8-Nov-11 1.41 MW-C B-May-12 MW-C 28-Nov-12 0.61 0.51 MW-C B-May-13 MW-C 5-Nov-13 11 MW-C 6-May-14 1302-M5WLF- MW-C 4-Nov-14 0.3J 4.61 CDLF-1998 MW-C 6-May-15 MW-C 28-0c[-15 0.71 MW-C 17-May-16 MW-C 1-Nov-16 MW-C &May-17 MW-C 1-Nov-17 MW-C 7-Jun-18 MW-C 1&Dec-18 0.611 MW-D 3-May-11 5.5 3.21 1.9 1.91 3] 0.]l 1.61 5.5 0.81 MW-D 8-Nov-11 5.7 3.]J 2.9 1.81 5] 0.41 0.71 0.91 1.51 3.9 0.91 MW-D &May-12 ] 0.31 2.]J 1.31 56 1 11 1.]1 5.3 0.81 MW-D 2]-Nw-12 6.5 0.31 l.L 6. 1.31 54 1.5 0.11 0.21 5.3 4.0 0.61 MW-D &May-13 6.8 0.4J 1.61 8.4 1.21 56 0.81 2.2 2.]1 5.9 0.]1 MW-D 5-Nov-13 ].2 0.51 1.81 9.3 1.01 51 0.81 1.81 4.6 0.91 MW-D 6-May-14 5.1 0.4J 1.L ].8 0.]1 39 3.31 3.9 0.61 1302-M5WLF- MW-D 4-Nov-14 6.9 0.51 0.91 10 0.91 53 OX 0.41 1.51 4.1 0.61 CDLF-1998 MW-D 5-May-15 5.9 0.6J ].3 0.51 38 0.]J 1.81 3.3 0.51 MW-D 2&Oc[-15 5.3 0.91 B.1 0.51 3] 1.51 2.J 0.61 MW-D 1]-May-16 5.0 0.]J 9.9 39 1.]1 2.8 MW-D 2-Nov-16 6.5 0.81 1.3J 12 0.51 48 3.21 2.6 1.1 MW-D 9-May-17 5.1 0.91 8.8 35 2.5 0.81 MW-D 1-Nov-1] 5.9 0.91 1.5J 10 0A 41 3.91 2.3 MW-D ]-Jun-18 5.9 0.931 10.1 36.0 0.621 2.6 MW-D 19-Dec-18 2.7 0.]21 0.691 10.9 0.41J 30.5 1.6 0.801 MMWW--E 4May-11 6.9 2.51 4.5 14 220 0.9 L 65.3 RRep Ep 8-No11 3.3 0.1 21421 11 0].8 0822 MW-E Rep &May-12 2.5 2.4J 5 13 1 47 0.91 0.41 0.31 1.8 6.6 MW-EE &May-13 2.]8 14 19 0.71 21 0.71 0.51 4.4 RRepp M 5-No13 2 3.2 3 41 0.]1 . ]W .3 65 MRepp &May-14 2 32 2.] 36 14 1.0 5 0.]1 02 14 02-.SW- MW-E W E R 4-No14 4.1 3.91 6 36 35 1.1 4 0.71 10 ] CDLF-1998 MW-E Rep 5-May-15 34 . 081 31 42 . 03 IS 8.8 1.01 25 051 3.8 MW-ERp 2]-0c[-15 La 3.9 5.11 31 9.01.1 27 0.44J 0.61 . 4.3 MW-E Rep 18-May-16 0.81 2.3J ].61 8.2 0.91 12 0.91 3.2 MW-E Rep 1-Nov-16 0.61 3.2 8.01 35 11 1.1 18 0.51 4.5 MW-E Rep 9-May-17 0.]1 3.0 6.2J 14 5.9 0.7J 18 0.51 0.61 3.5 MW-E Rep 31-0c[-1] 0.61 3.1 8.21 35 5 1.2 21 0.61 4.4 MW-E Rep 114 -18 0.131 2.81 6.51 10.0 2.51 16.] 0.]Ol 2.9 MW-E Rep 20-Dec-18 0.661 3.8 6.3J 12.3 2.61 22.1 0.531 0.811 2.0 3.6 MW-E Deep 4-May-ll 1.9 11 3.3 32 0.91 L 0.51 1.1 1.8 MW-E Deep 8-Nov-11 1.5 0.61 9.51 3.9 34 0.81 1.11 0.6J 1.3 1.3 MW-E Deep &May-12 1 0.51 12 4.3 29 0.91 0.41 0.51 1.2 0.31 0.61 MW-E Deep 2]-Nov-12 0.91 1.21 14 4.5 30 0.91 1.01 0.41 1.1 0.4J 0.9J MW-E Deep &May-13 0.81 0.]1 6.81 4.1 30 0.91 0.51 1.3 0.4J OSJ MW-E Deep 6-Nov-13 1.2 0.81 12 5.1 26 0.]1 0.41 12 P. MW-E Deep &May-14 851 2.6 18) M 1.01 9.51 9.3 1.1 0.81 2.01 0.I 10J 1.2 3.11 1302-M5WLF- MW-E Deep 4-Nov-14 181 0. ]1 4.31 5.41 0.91 1] 4.1 10 0.61 0.31 3.4 1.01 CDLF-1998 MW-E Deep 5-May-15 0.]1 1.11 14 5.9 B.5 0.]1 1.9 1.41 MW-E Deep 27-0c[-15 0.41 0.91 16 4.3 ].0 0.61 0.81 1.01 MW-E Deep 18-May-16 0.41 0.81 11 4.2 1.01 0.51 0.51 0.51 0.81 MW-E Deep 1-Nov-16 0.61 1.11 26 5.9 1.)1 0.81 0.11 4.81 MW-E Deep 9-May-17 0.]1 1.11 19 6.1 041 0.61 0.11 MW-E Deep 1-Nov-1] 0.81 1.21 26 ].4 1.0 1.1 0.11 3.61 MW-EDeep 114 -18 0.611 6.2 0.921 19.0 3.8 4.0 0.6]J 0.5)1 MW-E Dee 20-Det-18 1.3 1.51 13.5 6.4 0.941 0.611 1.1 2.31 D.351 Smith Page 9 of 16 February 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-F 3-May-11 IIMIMII MW-F 8-Nov-11 MW-F 8-May-12 MW-F 28-Nov-12 0.61 MW-F 9-May-13 MW-F 5-Nov-13 7 MW-F 7-May-14 1302-MSWLF- MW-F 3-Nov-14 CDLF-1998 MW-F 5-May-15 ID MW-F 27-0c[-15 0.1J MW-F 17-May-16 MW-F 2-Nov-16 0.61 MW-F 10-May-17 MW-F 31-0 -1] MW-F 6-Jun-18 MW-F 19-Dec-18 MW-F)dup) 19-Dec-18 0.801 MW-G 3-May-11 0.61 1.61 MW-G 8-Nov-11 1.8 2.11 MW-G B-May-12 0.61 1.11 0.31 MW-G 28-Nov-12 1.61 1.1 0.7I MW-G 9-May-13 2.81 0.51 1.61 MW-G 5-Nov-13 3.11 2.31 0.91 0.41 1.5 0.41 MW-G 7-May-14 021 2.41 0.81 0.41 1.4 0.51 1302-MSWLF- MW-G 3-Nov-14 0.31 2.61 1.01 0.5J 2.0 0.61 0.41 CDLF-1998 MW-G 5-May-15 021 2.4J 0.4J 1.9 0.51 MW-G 27-0c[-15 1.0 5.5 0.6J 2.9 MW-G 19-May-16 021 2.2J 0.11 1.4 0.61 MW-G Wp) 19-May-16 021 2.11 1.3 0.51 MW-G 2-Nov-16 0.61 5.6 1.21 0.]1 3.4 0.61 MW-G 10-May-1J 2.3J 1.3 0.41 MW-G 1-Nov-lJ 0.41 4.2 1.11 0.6J 2.3 O.J1 MW-G 6-Jun-18 3.1 0.85J MW-G 19-Dec-18 8.2 2.3J MW-H 4May-11 MW-H 8-Nov-11 MW-H B-May-12 MW-H 28-Nm-12 0.71 MW-H B-May-13 MW-H 7-Nov-13 MW-H 7-May-14 1302-MSWLF- MW-H 5-Nov-14 CDLF-1998 MW-H 5-May-15 MW-H 28-0c[-15 MW-H 18-May-16 2.71 MW-H 2-Nov-16 MW-H 10-May-17 MW-H 1-Nov-17 MW-H 7-Jun-18 MW-H 19-Dec-18 MW-H Deep 4-May-11 MW-H Deep 8-Nov-11 MW-H Deep B-May-12 MW-H Deep 2&Nov-12 0.41 MW-H Deep &May-13 MW-H Deep (dup) &May-13 MW-H Deep 7-Nov-13 MW-H Deep 7-May-14 MW-H Deep 5-Nov-14 1302-MSWLF- CDLF-1998 MW-H Deep (dup) 5-Nov-14 MW-H Deep 5-May-15 MW-H Deep (dup) 5-May-15 MW-H Deep 28-0c[-15 MW-H Deep 18-May-16 MW-H Deep 2-Nov-16 MW-H Deep 10-May-17 MW-H Deep 1-Nov-17 MW-H Deep 7-Jun-18 0.5]1 MW-H Deep 19-Det-18 0.941 MW-I 4-May-11 41 0.81 2.9 1.3 O.JJ MW-I 8-Nov-11 101 3.51 0.81 2.5 1 0.61 MW-I &May-12 3.31 0.21 0.81 0.41 2.8 1.1 0.]1 MW-I (dup) &May-12 3.31 0.31 0.91 0.41 2.6 1.1 0.71 ,I 27-Nov-12 4.01 0.31 0.91 1.2 2.4 1.1 MW-I 9-May-13 3.61 1.31 0.41 2.8 1.4 0.61 MW-I J-Nov-13 3.91 1.31 0.41 2.8 1.4 0.61 1302-MSWLF- MW-I &May-14 4.71 0.21 1.41 2.9 1.4 0.61 CDLF-1996 MW-I 4-Nov-14 4.91 0.41 I.71 3.6 S.J 0.61 MW-I 5-May-15 4.41 1.41 0.41 3.1 1.5 0.61 MW-I 28-O -15 4.61 1.91 3.2 1.5 0.51 MW-I I8-May-16 3.91 1.81 2.9 1.5 0.51 2.91 MW-I 2-Nov-16 4.61 1.01 2.01 0.61 3.5 1.3 0.81 MW-I 10-May-lJ 4.31 2.11 0.51 2.9 1.6 0.61 MW-I 31-0c -17 5.5 2.]1 3.0 2.0 0.]1 MW-I ]-Jun-I8 S.J 1.11 3.61 1.0 1.8 1.7 MW-1 1B-Dec-18 5.2 1.1 3.3 2.1 Smith Page 10 of 16 February 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-1 3-May-11 MW-1 8-Nov-11 MW-1 S-May-12 MW-1 28-Nov-12 0.81 VIA" 7-May-13 MW-1 5-Nov-13 7 MW-1 6-May-14 1302-MSWLF- MW-1 4-Nov-14 CDLF-1998 VIA" &May-15 MW-1 27-0ct-15 MW-1 17-May-16 MW-1 1-14ov-16 NIA" 9-May-17 NIA" 1-14ov-17 NIA" 7-Jun-18 0.651 MW-1 19-Dec-18 MW-K 3-14ov-30 O.JI MW-K 3-May-11 0.61 MW-K 8-14ov-11 5 U 11 MW-K B-May-12 0.41 MW-K 2J-Nov-12 1.61 0.31 0.7) 0.3) 0.3) MW-K 7-May-13 1.31 0.4) MW-K 5-14ov-13 MW-K &May-14 0.51 1302-M5WLF- MW-K 4-Nov-14 1.11 0.51 CDLF-1998 MW-K 5-May-15 0.61 MW-K 28-0ct-15 1.41 0.81 0.4) MW-K 17-May-16 MW-K 1-Nov-16 0.61 0.61 MW-K(dup) 1-Nov-16 0.51 0.91 0.61 MW-K 9-May-17 B.w MW-K 1-Nov-17 MW-K 7-Jun-18 0.731 MW-K 19-Dec-18 MW-L 4-May-11 MW-L 9-14ov-11 MW-L &May-12 MW-L 28-14ov-12 Lou 1.11 1.2 2.4 MW-L &May-13 MW-L 7-14ov-13 MW-L B-May-14 1302-MSWLF- MW-L 5-14ov-14 CDLF-1998 MW-L &May-15 MW-L 28-0ct-15 MW-L 19-May-16 MW-L 2-14ov-16 MW-L 10-May-17 MW-L 1-14ov-17 O81 0.41 1.0 MW-L 7-Jun-18 0.561 MW-L 19-Dec-18 MW-L Deep 4-May-11 9.4 1.41 1.21 O.J1 13 3.] 1.6 MW-L Deep B-May-12 5.8 0.41 0.61 0.4) 1.4 1.2 0.61 MW-L Deep 9-May-13 11 1.21 1.81 0.91 36 8.1 1.5 MW-L Deep &May-14 04J 6.8 0.51 0.81 2.1 1.7 0.41 1302-MSWLF- MW-L Deep &May-15 5.6 0.51 0.61 0.41 3.5 1.8 0.61 CDLF-1998 MW-L Deep 29-Oc[-15 4.61 0.61 2.1 1.5 0.51 MW-L Deep 19-May-16 3.21 2.0 0.91 MWA Deep 10-May-l7 3.81 2.1 1.0 MWA Deep ldup) 10-May-17 3.J1 1.7 1.1 MW-L Deep 7-Jun-18 0.971 5.3 1.0 0.381 MW-M 4-May-11 0.41 MW-M &May-12 0.91 0.31 ZIA 9-May-13 1.11 0.51 1302-MSWLF- ZIA &May-14 1.11 CDLF-1998 ZIA 5-May-15 1.01 0.4) MW-M 28­0ct-15 0.91 ZIA 17-May-16 0.81 ZIA 9-May-17 0.61 ZIA 7-Jun-18 0.641 0.531 MW-X 3-May-11 MW-X 8-14ov-11 MW-X &May-12 MW-X 2&Nov-12 0.61 MW-X(dup) 2&Nov-12 0.61 MW-X 7-May-13 MW-X 5-14ov-13 1302-MSWLF- MW-X &May-14 CDLF-1998 MW-X 4-14ov-14 MW-X &May-15 MW-X 28­0ct-15 MW-X 17-May-16 MW-X 1-Nov-16 LL-L MW-X 9-May-17 MW-X 1-Nov-17 MW-X J-Jun-18 MW-X 19-Dec-18 Notes: 1. All units are in micrograms per liter (parts per billion). 2. Monitoring wells MW-3 Deep, ADeep, -and -M are sampled annually during the spring event. 3.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 4. B - Indicates he was detected in the batch blank above the method detection limit. 5. (d up)- Duplicate 6. The November 2012 sampling event was the first event that CD-Is/CD-Id replaced MW-9 as the background monitoring wells. 7. MW-9 was removed from the monitoring program in November 2012. 8. M W-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. 9. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) Standard - Indicates the result is belowthe detection limit. Smith Page 11 of 16 February 2019 Table Sc Detected Surface Water Constituents - Volatile Organic Compounds and Metals December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 SW-1 5-May-11 0.0002J 0.07181 0.0012.1 0.003811 0.00115J 0.006231 0.002481 0.003691 SW-1 9-Nov-11 0.094J 0.000771 0.00261 0.000231 0.005321 0.001741 SW-1 30-May-13 0.08211 0.00006J 0.003791 0.00201J 0.00016J 0.00631 0.002051 0.004931 SW-1 5-Nov-13 0.00106J 0.139 0.009521 0.00175J 0.00009J 0.008511 0.002851 0.000121 0.007551B 0.00938JB 21 0.3J SW-1 5-May-14 0.00180J 0.146 0.000371 0.004631B 0.00117 0.00634J 0.003581E 0.009791 0.002831 0.01441 0.0343 1302-MSWLF- SW-1 5-May-15 CDLF-1998 SW-1 29-Oct-15 0.00089J 0.06921 0.001011 0.00172J 0.005091 0.00439J 0.00293CN,J 0.002371 SW-1 19-May-16 0.00352J 0.157 0.00144 Ir 0.0372 0.0156 0.0251 0.0148 0.01721 0.005331 0.000081 0.0652 SW-1 3-Nov-16 DRY DRY SW-1 30-May-17 0.06661 0.003691 0.00204.1 0.00104.11 0.000071 0.005921 SW-1 30-Oct-17 DRY DRY SW-1 6-Jun-18 DRY DRY SW-1 18-Dec-18 0.000701 0.05761 0.0000521 0.00181 0.00261 0.0020J 0.00034J 0.00441 0.00321 0.00491 4.4 2.1 SW-2 5-May-11 0.000191 0.0911 0.000181 0.0025E 0.004251 0.0034.1 0.0013JB 0.006261 0.003881 0.003841 0.006391 SW-2 9-May-12 0.06531 0.001061 0.000881 0.001681 0.00085.1 0.003331 0.001331 0.003011 0.00267J,B SW-2 10-May-13 0.000971 0.07891 0.000631 0.002531 0.00221 0.00084J 0.006361 0.00302J 0.006051 SW-2 6-May-14 0.001451 0.137 0.000051 0.003291 0.00365.1 0.001521B 0.006991 0.00368J 0.007111 0.0245 SW-2 3-Nov-14 0.001881 0.067J 0.0127 0.00057J 0.000051 0.001421 0.00108J 0.00515JB 6.01 2 SW-2 5-May-15 0.00732JB 0.003161 0.00121J 0.00634J 0.00340J 0.001361 1302-MSWLF- SW-2 29-Oct-15 0.001681 0.08111 0.000101 0.000691 0.00364J 0.00095.1 0.00460J 0.00650.1 0.00328CN,J 0.001931 0.00548J CDLF-1998 SW-2 19-May-16 0.002351 0.08901 0.000941 0.0122 0.007211 0.0119 0.00873.1 0.008331 0.00340J 0.0327 0.0350 SW-2 3-Nov-16 DRY DRY SW-2 10-May-17 0.09471 0.00222.1 0.00089.11 0.000311 0.0048E 0.001741 SW-2 30-Oct-17 DRY DRY SW-2 6-Jun-18 0.000991 0.04291 0.00141 0.000371 0.00251 SW-2 18-Dec-18 0.00063J 0.07181 0.000111 0.0019J 0.0018J 0.00191 0.000911 0.00311 0.0043.1 0.0036.1 2.5 1.8 Notes: 1. All units for metals are in milligrams per liter (parts per million). All untis for volatile organic compounds are in micrograms per liter (parts per billion). 2. Standards obtained from 15A NCAC 02B .0211 (North Carolina 2B) or Protective Value Surface Water quality Standards for Class C Waters - September 2017. 3. Isl -A Standard for total chromium has not been established. The value provided is for chromium (III). 4.' - North Carolina Protective Value S. NS - No Standard 6.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 7. B - Indicates constituent was detected in the batch blank above the method detection limit. 8. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used. 9. SW-1 was dry during the Fall 2007, Fall 2009, Spring 2010, Fall 2011, Spring 2012, Fall 2012, Fall 2014, Spring 2015, and Fall 2016 sampling events. 10. SW-2 was dry during the Fall 2009, Spring 2010, Fall 2010, Fall 2011, Fall 2012, Fall 2013, and Fall 2016 sampling events. Concentration exceeds North Carolina Freshwater Aquatic Life Standard for Class C Waters. - Indicates the result is below the detection limit. Smith Page 12 of 16 February 2019 Table Sd Geochemical Constituents in Groundwater December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 1302-MSWLF- MW-9 3-May-11 3.45 139 <0.010 0.004 1.7 0.088 <0.05 <0.1 <0.05 <0.05 <0.15 0.14 <0.07 0.1 <0.15 0.65 37 50 <0.5 <6 1.3 0.161 0.0911 3.1 CDLF-1998 MW-9 9-Nov-11 4.70 212 0.062 0.078 3.5 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.033 <0.07 <0.05 <0.15 1.4 53 35 <2 11 1.3 0.91H 0.0941 0.4B MW-9 9-Ma -12 1.82 127 0.11 0.012 6.7 0.038 <0.05 0.051 <0.05 <0.05 <0.15 0.086 <0.07 <0.05 <0.15 2.8 41 36 <0.002 <10 1.6 <0.2H 0.1801 0.484 CD-ls 3-May-11 47 3.6 7<5<0.2 CD-ls 8-Nov-11 40 4 CD-ls 7-May-12 46 3.9 CD-ls 27-Nov-12 15.56 139 <0.025 0.019 1.1 <0.07 0.029 0.019 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 0.94 54 39 <2 <10 4.1 0 0.06J <1 CD-1s 7-May-13 1.96 206 0.21 0.14 3.8 <0.07 <0.05 0.062 <0.10 <0.05 <0.15 0.055 <0.07 <0.05 <0.15 0.82 30 42 <2 0.64 4 0.22 0.0661 <1 CD-ls 5-Nov-13 1.74 348 0.0033 0.0037 0.33 0.034 0.056 <0.5 <0.1 <0.15 0.20 <0.07 <0.05 <0.15 0.74 15 30 <2 <10 3.8 2.42 0.0821 <5 <0.2 <1 CD-1s 6-May-14 0.02 353 0.0032 0.010 3.4 0.037 <0.05 <0.5 <0.1 <0.15 <0.10 <0.07 <0.05 <0.15 0.94 54 42 <2 <10 3.8 0 0.0771 <5 <0.2 1.07 1302-MSWLF- CD-1s 4-Nov-14 6.06 135 0.0061 0.011 1.8 0.041 <0.05 <0.5 <0.2 <0.15 0.037 <0.07 0.052 <0.15 1.7 62 41 <2 <10 3.9 0 0.0651 <5 <0.2 <1 CDLF-1998 CD-1s 5-May-15 3.99 281 0.0034 0.016 0.060 0.081 <0.05 0.10 <0.5 <0.2 <0.15 0.019 <0.07 <0.05 0.034 26 42 38 <2 <10 3.8 0 0.1201 <5 <0.2 3.48 CD-ls 27-Oa-15 3.84 519 <0.10 0.012 0.12 0.036 0.0094 0.03 <0.20 <0.20 <0.10 <0.20 <0.10 0.0024 <0.10 40 61 43 <2 30.6 3.8 0 0.1301 <5 <0.2 <1 CD-1s 17-May-16 3.45 245 <0.10 <0.30 0.048 0.020 <0.30 0.045 <0.20 <0.20 <0.10 0.011 <0.10 <0.10 <0.10 22 46 43 <2 <10 3.7 0 0.0791 1 <0.2 <1 CD-1s 1-Nov-16 4.49 360.2 0.0031 0.0099 0.84 0.038 0.0076 0.059 <0.20 <0.20 <0.10 0.0090 <0.10 <0.10 <0.10 3.1 60 46 <2 26.5 4.2 0 0.0671,H-02 <5 <0.2 <1 CD-1s 9-May-17 1.69 274.6 0.0035 0.0026 0.50 1.135 <0.30 1.131 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 7.1 48 49 <2 <11 3.6 0 0.0761 1.31 <0.2 <1 CD-15 31-OR-17 1.17 58 <0.10 11.11 0.181 <0.30 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 14 58 50 <2 14.6 4.2 0 0.066 1.01 <0.2 <1 CD- 15 11-Jun-18 3.8 124.1 0.0361 0.031J 15.00 0.031J <0.30 <0.20 <0.20 <0.20 <0.10 0.021J 0.053J <0.10 <0.10 6.4 44 49 <2 <10 3.89 0 )0820 0.9041 <0.2 <1 CD-15 17-Dec-18 1 5.6 1 38.6 <0.10 I <0.30 1 3.50 <0.30 I <0.30 1 <0.20 <0.20 1 <0.20 1 <0.10 1 <0.20 <0.10 I <0.10 I <0.10 420 1 46 1 46 <2 1 <10 1 3.72 0 1 0.146 0.9911 <0.2 <1 CD-ld 3-May-I1 57 2.6 31 CD-ld 8-Nov-11 30 2.9 31 CD-ld 7-May-12 50 2.8 <5 CD-ld 27-Nov-12 953 140 46 3 0 0.07J <5 CD-ld 7-May-13 El 242 0.015 0.015 0.31 0.021 <0.05 0.052 <0.10 <0.05 <0.15 0.06 <0.07 <0.05 <0.15 0.61 40 52 4 6.05 3 0.56 0.0691 <5 <0.2 1.42 CD-ld 5-Nov-13 1.71 320.1 42 3 <5 CD-ld 6-May-14 4.56 293 46 2.9 0.0771 <5 1302-MSWLF- CD-ld 4-Nov-14 4.68 108.7 43 3.1 0 <5 CDLF-1998 CD id 5-May-15 4.84 186 44 2.9 0 0.0861 <5 CD-ld 27-OR-15 4.10 507 46 2.9 0 <5 CD-ld 17-May-16 4.50 230 96 18.0 0 <0.05 14 CD-ld 1-Nov-16 3.10 3310 52 3.4 0 <5 CD-ld 9-May-10 1.51 217.2 53 2.8 0 3.71 CD-ld 31-OR-17 2.85 37 52 3.3 0 0.0791 3.3J CD-ld 12-Jun-18 2.9 54.2 51 3.2 0 3.33J CD-ld 17-Dec-18 3.6 25.1 53 3.11 0 1 3.36J AMW-ls 3-May-11 1.22 176 0.007 0.004 810 0.57 <0.05 <0.1 <0.05 <0.05 <0.15 0.13 <0.07 0.63 <0.15 1 250 114 <0.5 <6 3.2 0.13J <0.016 0.36J <0.6 1 AM; 8-Nov-11 0.17 12 0.031 0.068 1,100 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.08 <0.07 <0.05 <0.15 1.1 320 95 3 9 3.1 <0.2 <0.05 0.26J <1 0.7B AMW-ls 7-May-12 0.02 121 0.043 0.047 1,300 0.061 <0.05 0.055 <0.05 <0.05 <0.15 0.089 <0.07 <0.05 <0.15 82 300 105 <0.002 <11 3.2 <0.2H <0.004 <0.18 <0.2 0.524 AMW-ls 28-Nov-12 3.81 44 0.064 0.031 1,000 <0.07 <0.05 0.036 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 1.1 280 92 <2 <10 3.1 0.3 <0.05 <5 <02 <1 AMW-ls 8-May-13 0.34 523 0.11 0.054 1,600 0.029 <0.05 0.064 <0.10 <0.05 <0.15 0.073 <0.07 <0.05 <0.15 0.69 260 87 <2 14.4 3.5 0.11 <0.05 <5 <0.2 <1 AMW-ls 6-Nov-13 1.05 149 0.11 <0.025 1,400 0.041 0.061 <0.5 <0.1 <0.15 0.15 <0.07 0.015 <0.15 0.85 270 107 <2 <10 3.6 0.34 <0.05 <5 <0.2 <1 AMW-ls 7-May-14 0.02 400 0.095 <0.025 1,200 0.054 <0.05 <0.5 <0.1 <0.15 0.026 <0.07 0.036 <0.15 0.86 280 105 <2 <10 3.4 0 <0.05 <5 <0.2 <1 1302-MSWLF- AMW-ls 5-Nov-14 3.25 132.2 0.15 0.015 1,000 0.055 <0.05 <0.5 <0.2 <0.15 0.031 <0.07 0.053 <0.15 1.7 280 120 <2 <10 3.7 0 <0.05 <5 <0.2 <1 CDLF-199a AMW-ls 7-May-15 2.00 592 0.2 0.0073 1,600 <0.07 <0.05 0.11 <0.5 <0.2 <0.15 0.031 <0.07 <0.05 <0.15 12 310 96 <2 <10 3.5 0 <0.5 <5 <0.2 <1 AMW-ls 29-0R-15 2.68 253 0.21 0.0064 1,100 0.028 0.0052 0.036 <0.20 <0.20 <0.10 0.0014 <0.10 0.0022 <0.10 8.2 300 10.5 <2 <10 3.7 0 <0.05 0.22J <0.2 <3 AMW-15 I8-May-16 3.77 222 0.17 <0.10 1,000 0.015 <0.10 0.030 <0.20 <0.20 <0.10 0.0072 0.012 <0.10 <0.10 1.5 230 85 <2 <10 3.8 0 <0.05 <5 <0.2 1.44 AMW-11 2-Nov-16 1.65 377.2 0.13 0.0064 820 0.044 <0.10 0.048 <0.20 <0.20 <0.10 0.0092 <0.10 <0.10 <0.10 6 270 100 <2 23.6 3.3 0 <0.05 <5 <0.2 <1 AMW-15 10-May-17 1.54 148.6 0.25 0.0046 1,400 0.062 <0.10 0.047 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.0 280 121 <2 25.1 4.2 0 <0.05 0.23J <0.2 <1 AMW-11 1-Nov-17 2.39 227 0.0971 0.030J 600 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 3.1 200 93 <2 <10 3.5 0 <0.05 0.42J <0.2 <1 AMW-ls 8-Jun-18 0.5 566.1 0.14 <0.10 1,200 0.0381 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 0.0601 <0.10 <0.10 5.4 280 383 <2 <10 2.99 0 <0.0500 <0.5 <0.2 <1 AMW-ls 19-Dec-18 0.7 510.5 0.24 <0.10 1,600 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 5.6 260 I15 2.28 <10 3.57 0 0.03601 0.2911 <0.2 <1 Smith Page 13 of 16 February 2019 Table Sd Geochemical Constituents in Groundwater December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 AMW-1 3-May-11 0.01 89 0.059 0.71 1,100 0.11 <0.05 <0.1 <0.05 <0.05 <0.15 <0.1 <0.07 0.29 <0.15 0.89 170 295 1.8 <6 7.3 0.141 <0.006 31J 3 1.3 AMW-ld 8-Nov-11 0.00 -112 0.18 1.4 2,900 0.23 <0.05 <0.1 <0.05 <0.05 <0.15 0.2 <0.07 <0.05 <0.15 0.89 280 320 4 19 6.8 1 <0.05 27J <1 4.6 AMW-ld 7-May-12 0.24 95 0.17 1.7 2,500 0.097 <0.05 0.058 <0.05 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 480 270 230 6 <10 6.6 1.91H 0.0061 151 <0.2 4.11 AMW-ld 28-Nov-12 7.00 169 0.15 1.8 2,000 1.9 <0.05 0.039 <0.10 <0.05 <0.15 <0.10 <0.07 0.039 <0.15 0.51J 240 265 4 30.2 6.4 1.8 <0.05 9.2J 0.4341 3.02 AMW-ld 8-May-13 0.46 -53 0.32 1.6 3,800 0.054 <0.05 0.079 <0.10 <0.05 <0.15 0.089 <0.07 0.028 <0.15 1 300 375 4 8.99 7.1 3.3 <0.05 12J <0.2 4.95 AMW-ld 6-Nov-13 1.40 -22.7 0.28 1.1 3,400 0.033 0.066 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.96 290 315 <2 19.7 5.6 2.91 <0.05 6.4J <0.2 3.4 AMW-ld 7-May-14 2.05 -28 0.32 0.82 3,700 0.082 <0.05 <0.5 <0.1 <0.15 0.047 <0.07 0.032 <0.15 1.3 330 230 2 <10 5.6 5 <0.05 <5 <0.2 2.16 1302-MSWLF- AMW-1d 5-Nov-14 1.36 -67.7 0.33 1.3 3,000 0.34 <0.05 <0.5 <0.2 <0.15 0.042 <0.07 0.077 <0.15 2.0 320 375 2 44.9 5.4 4.0 <0.05 <5 0.2411 2.15 CDLF-1998 AMW-1 7-May-15 1.78 -52 0.5 2.2 3,400 0.15 <0.05 1.11 <0.5 <0.2 <0.15 1.014 <0.07 <0.05 1.031 7.3 320 231 2 35.2 5.4 2.0 <0.5 <5 <0.2 3.41 AMW-ld 29-Oc[-15 2.55 -42 0.79 4.0 4,000 0.27 0.0061 0.038 <0.20 <0.20 <0.10 0.011 <0.10 0.0050 <0.10 8.2 330 255 9BOD-3 <10 5.5 2.5 <0.05 <5 <0.2 2.67 AMW-ld 18-May-16 1.51 -21 2 2.2 3,710 1.121 <0.30 0.040 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.8 310 225 <2 13.2 1.9 3.0 <0.05 <5 <0.2 2.93 AMW-ld 3-Nov-16 1.73 199.2 2.2 3.4 3,900 0.045 <0.30 0.054 <0.20 <0.20 <0.10 0.0083 <0.10 <0.10 <0.10 19.0 350 215 30 41.6 5.9 2.0 <0.05 <5 <0.2 3.42 AMW-ld 30-May-17 1.59 -6.7 3.9 2.2 3,700 0.047 <0.30 0.046 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.5 280 225 30 29.6 6.1 7.0 <0.05 0.0651 <0.2 2.27 AMW-ld 1-Nov-17 3.51 159 3.6 1.6 4,000 <0.30 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.9 280 230 <2 20.0 6.3 3.0 <0.05 0.47J <0.2 2,64 AMW-ld 8-Jun-18 3.2 21.3 1.3 0.75 1,900 0.043J <0.30 0.071J <0.20 <0.20 <0.10 <0.20 0.052J <0.10 <0.10 1.7 260 223 <2 <10 5.26 0 <0.0500 0.5791 <0.2 1.02 AMW-1d 19-Dec-18 1 0.5 1 1.8 2.6 1 1.5 1 3,500 <0.30 I <0.30 1 <0.20 <0.20 1 <0.20 1 <0.10 1 <0.20 <0.10 I <0.10 I <0.10 11 1 360 1 202 <2 1 <10 1 7.18 6.0 1 0.0170J 0.5731 <0.2 1.02 AMW-2s 3-May-11 2.10 121 0.103 0.114 0.241 1.011 <0.05 <0.1 <0.05 <0.05 <0.15 1.12 <0.07 1.163 <0.15 1.2 131 77 <0.5 20 3.2 <0.07 0,016 0.2J <0.6 1.2 AMW-2s 8-Nov-11 2.47 -30 0.016 0.076 4 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.092 <0.07 <0.05 <0.15 0.68 170 70 11 10 3.2 0.2JH 0.1J 0.0971 <1 0.6B AMW-2s 8-May-12 0.42 195 0.014 0.022 0.34 0.042 <0.05 0.066 <0.05 <0.05 <0.15 0.53 <0.07 <0.05 <0.15 9.7 170 70 1.29 <10 3.4 <0.2H 0.12J <5 <0.2 0.418 AMW-2s 29-Nov-12 5.36 38 <0.025 0.026 0.86 <0.07 0.025 0.023 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 0.41J 170 8 <2 <10 3.3 <0.2H 0.11J <5 <0.2 <1 AMW-2s 9-May-13 0.88 153 0.008 0.022 4.30 0.047 <0.05 0.066 0.068 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 0.87 160 46 4 13.5 3.5 0.43 0.13J <5 <0.2 1.52 AMW-2s 6-Nov-13 1.51 75.1 0.0045 <0.025 0.58 0.020 0.068 <0.5 <0.1 <0.15 0.10 <0.07 <0.05 <0.15 0.94 140 63 <2 15.8 3.5 0.55 0.16J <5 <0.2 12.3 AMW-2s 7-May-14 2.08 114 0.022 0.0081 0.31 0.062 0.033 <0.5 <0.1 <0.15 0.032 <0.07 0.032 <0.15 25 180 60.6 <2 <10 3.6 0 0.16J <5 <0.2 1.07 1302-MSWLF- AMW-2s 5-Nov-14 3.48 120.5 0.0054 0.014 0.20 0.036 <0.05 <0.5 <0.2 <0.15 <0.10 <0.07 0.048 0.046 1.4 180 95 <2 <10 3.6 0 0.17J <5 <0.2 <1 CDLF-1998 AMW-2s 6-May-15 3.50 562 0.0044 0.020 1.10 <0.07 <0.05 0.088 <0.5 <0.2 <0.15 0.013 <0.07 <0.05 <0.15 52.0 180 53 <2 <10 3.5 0 0.22J <5 <0.2 1.05 AMW-2s 28-OR-15 4.19 187 0.0048 0.056 0.26 0.026 0.0050 0.044 <0.20 <0.20 <0.10 0,0087 <0.10 0.0016 <0.10 8.0 160 64 <2 <10 3.7 0 0.24J <5 <0.2 1.15 AMW-2s 17-May-16 3.22 51 <0.10 0.012 4.60 0.017 <0.30 0.038 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.9 180 65 <2 <10 3.4 0 0.29J <5 <0.2 <1 AMW-2s 1-Nov-16 3.38 235.1 0.0087 0.014 3.80 0.027 0.0073 0.051 <0.20 <0.20 <0.10 0.0077 <0.10 <0.10 <0.10 2.9 200 69 <2 25.8 3.7 0 0.311,H-02 <5 <0.2 1.02 AMW-2s 30-May-17 1.55 48.2 0.078 0.018 0.82 0.019 <0.30 0.043 <0.20 <0.20 <0.10 0.019 <0.10 <0.10 <0.10 7.3 160 720 <2 14 3.5 0.5 0.41J 0.33J <0.2 <1 AMW-2s 1-Nov-17 4.42 280 0.0095J 0.018J 0.501 <0.30 <0.10 0.072J <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 8.5 150 74.0 <2 10 3.6 0 0.43 0.38 <0.2 <1 AMW-2s 8-Jun-18 2.2 162.2 0.14 0.066J 1.2 0.0281 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 0.059J <0.10 <0.10 2.9 150 257 <2 <10 2.79 0 0.362 <0.5 <0.2 <1 AMW-2s 20-Dec-18 1 2.9 1 101.3 <0.10 I <0.30 1 <0.50 <0.30 I <0.30 1 <0.20 <0.20 1 <0.20 1 <0.10 <0.20 <0.10 <0.10 <0.10 1 12 160 71 <2 <10 3.22 0 0.452 0.7971 <0.2 1.31 AMW-2d 3-May-11 0.75 107 0.005 0.037 0.41 0.052 <0.05 <0.1 <0.05 <0.05 <0.15 0.12 <0.07 0.061 <0.15 0.86 44 129 <0.5 <6 3.1 0.081 0.0171 4.31 <0.6 1.1 AMW-2d 8-Nov-11 1.07 -29 0.03 0.19 7.10 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.032 <0.07 <0.05 <0.15 1.4 96 75 <2 7 2.9 <0.2H 0.0111 3.5J <1 0.7B AMW-2d 8-May-12 0.00 195 0.053 0.073 1 0.037 <0.05 0.053 <0.05 <0.05 <0.15 0.087 <0.07 <0.05 <0.15 31 98 80 <0.002 <10 3 <0.2H <0.05 <5 <0.2 0.932 AMW-2d 28-Nov-12 3.47 149 0.10 0.69 30 0.99 <0.05 0.031 <0.10 <0.05 <0.15 <0.10 <0.07 0.030 <0.15 0.68 1110 79 <2 13.5 3.2 1.3 <0.05 <5 <0.2 <1 AMW-2d 9-May-13 0.36 126 0.013 0.049 1.1 0.1 <0.05 0.064 <0.10 <0.05 <0.15 0.08 <0.07 <0.05 <0.15 1.5 110 65 1.48 11.7 3 0.06 <0.05 <5 <0.2 <1 AMW-2d 6-Nov-13 1.40 137.7 0.0072 0.048 0.48 0.027 0.061 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.65 68 85 20.4 <11 3.1 1.16 1.181 <5 <0.2 <1 AMW-2d 7-May-14 3.88 95 0.0068 0.021 0.36 0.073 <0.05 <0.5 <0.1 <0.11 0.033 <0.07 0.030 <0.15 18 170 71.8 <2 <11 3.2 1.5 <0.05 <5 <0.2 <1 1302-MSWLF- AMW-2d 5-Nov-14 4.19 103.5 0.016 0.016 0.27 0.04 <0.05 <0.5 <0.2 <0.15 0.016 0.082 0.048 <0.15 1.3 100 130 <2 <10 3.3 0 <0.05 <5 <02 <1 CDLF-1998 AMW-2d 6-May-15 2.51 391 0.011 0.035 0.97 <0.07 <0.05 0.098 <0.5 <0.2 <0.15 <0.1 <0.07 <0.05 <0.15 23.0 200 90 <2 <10 3.4 0 <0.5 <5 <0.2 <1 AMW-2d 28-0R-15 3.90 158 0.013 0.039 0.20 0.030 0.0075 0.038 <0.20 <0.20 <0.10 0.0011 <0.10 0.0024 <0.10 9.0 120 98 <2 <11 3.3 0 <0.05 <5 <0.2 <3 AMW-2d 17-May-16 2.69 88 0.023 0.012 0.49 0.036 <0.10 0.095 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.0 160 110 <2 <10 3.5 0 <0.05 <5 <0.2 <1 AMW-2d 2-Nov-16 2.15 345.8 0.015 0.2 2.00 0.020 <0.10 0.046 <0.20 <0.20 <0.10 0.075 <0.10 <0.10 <0.10 2.3 263 110 <2 31.2 4.2 0 <0.15 <5 <0.2 <1 AMW-2d 10-May-17 1.47 37.0 0.080 0.29 6.9 0.020 <0.10 0.035 <0.20 <0.20 <0.10 0.013 <0.10 <0.10 <0.10 7.7 200 121 <2 <10 3.7 0 <0.05 0.32J <0.2 <1 AMW-2d 2-Nov-17 3.20 151.0 0.0201 0.27 9.2 0.021J <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.9 190 131 <2 <10 3.9 0 <0.05 0.52J <0.2 <1 AMW-2d 8-Jun-1. 0.6 13.9 0.0141 0.21 120 0.0461 <0.10 0.089J <0.20 <0.20 <0.10 <0.20 0.058J 10.10 10.10 3.2 200 374 <2 <10 2.86 0 <0.0500 <0.5 <0.2 <3 AMW.2d 20-Dec-18 0.9 65.3 <0.10 <0.30 72 <0.30 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 16 240 137 <2 <10 3.4 1.5 1 <0.050 I 0.8191 0.272 <3 Smith Page 14 of 16 February 2019 Table Sd Geochemical Constituents in Groundwater December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 MW-3 4-May-11 2.60 164 0.003 0.006 0.5 0.24 0.098 <0.1 <0.05 <0.05 <0.15 0.19 <0.07 0.094 <0.15 1.1 69 69 <0.5 <6 2.8 0.181 0.0221 0.25J <0.6 0.3 MW-3 9-Nov-11 4.05 198 0.04 0.059 1.6 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.043 <0.07 <0.05 <0.15 0.8 120 65 <2 <10 2.9 0.18JH 0.0191 0.15J <1 0.4B MW-3 8-May-12 2.76 113 <0.025 0.021 0.14 0.072 <0.05 0.094 <0.05 <0.05 <0.15 0.13 <0.07 <0.05 <0.15 1.5 100 60 <0.002 <10 3.6 0.3H <0.05 <5 <0.2 0.303 MW-3 28-Nov-12 12.31 73 0.044 0.022 0.83 <0.07 <0.05 0.038 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 1.1 120 91 <2 <10 3.2 <0.2H <0.05 <5 <0.2 <1 MW-3 9-May-13 1.88 188 0.018 0.0079 0.40 0.025 <0.05 0.058 <0.10 <0.05 <0.15 0.082 <0.07 <0.05 <0.15 1.6 82 52 <2 10.1 3.1 1.11 <0.05 <5 <0.2 <1 MW-3 7-Nov-13 1.99 301.1 0.0035 0.0075 0.34 0.049 <0.05 <0.5 <0.1 <0.15 0.22 <0.07 0.015 <0.15 1.4 110 69 26 28.1 3.4 0.83 <0.05 <5 <0.2 9.12 MW-3 8-May-14 0.04 150 0.0062 0.030 0.16 0.080 <0.05 <0.5 <0.1 <0.15 0.053 <0.07 0.034 <0.15 1.1 140 63.6 6 <10 3.2 0 <0.05 <5 <0.2 1.67 1302-MSWLF- MW-3 6-Nov-14 5.94 465.6 0.0040 0.015 0.30 0.045 <0.05 <0.5 <0.2 <0.15 0.040 0.068 0.048 <0.15 1.6 140 61 <2 <10 3.3 0 <0.05 <5 <0.2 <1 CDLF-1998 MW-3 6-May-15 2.29 260 0.0085J 0.016 0.18 <0.07 <0.05 0.077 <0.05 <0.02 <0.15 0.014 <0.07 <0.05 <0.15 14 140 65 <2 76.2 3.4 0 <0.5 <5 <0.2 1.43 MW-3 28-OC-15 3.85 166 0.23 0.022 0.20 0.026 0.0058 0.043 <0.20 <0.20 <0.10 <0.20 <0.10 0.0016 <0.10 11 130 69 <2 <10 3.4 0 <0.05 <5 <0.2 <1 MW-3 18-May-16 3.18 101 <0.10 <0.30 0.87 0.015 <0.30 0.079 <0.20 <0.20 <0.10 0.0092 <0.10 <0.10 <0.10 9.6 120 75 <2 <10 3.7 0 <0.05 <5 <0.2 1.32 MW-3 2-Nov-16 3.50 438.8 0.020 0.021 0.72 0.031 <0.30 0.1 <0.20 <0.20 <0.10 0.0082 <0.10 <0.10 <0.10 1.9 130 60 <2 14.9 4.1 0 <0.05 <5 <0.2 <1 MW-3 11-May-17 1.75 229.E 0.0045 0.0017 1.33 1.052 <010 1.040 <0.20 <0.20 <0.10 0.1091 <0.10 1.122 <0.10 1.1 141 78 <2 <10 3.9 0 <0.05 0.61 <0.2 <1 MW-3 1-Nov-17 1.60 325 0.0111 0.022J 0.64 <0.30 <0.30 0.083J <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.4 120 80 <2 <10 4.2 0 <0.05 0.22J <0.2 <1 MW-3 7-Jun-18 3.7 130.6 <0.10 0.017J 0.351 0.034J <0.30 0.077J <0.20 <0.20 <0.10 <0.20 0.047J <0.10 <0.10 3.9 110 79 2.31 <10 3.89 0 0.0180J 0.1371 <0.2 <1 MW-3 19-Dec-18 1 2.8 1 48.8 <0.10 I <0.30 1 <0.20 <0.30 I <0.30 I <0.10 <0.20 1 <0.20 1 <0.10 1 <0.20 <0.10 I <0.10 I <0.10 9.5 1 160 1 89 <2 1 <10 1 3.34 0 1 27.OJ 0.2221 0.381 <1 MW-A 3-May-11 1.08 113 0.018 <0.010 3,600 0.085 0.12 <0.1 <0.05 <0.05 <0.15 0.13 <0.07 0.063 <0.15 1.3 470 134 6 7 11 0.141 <0.006 4.5J <0.6 7.6 MW-A 9-Nov-11 0.06 205 0.084 0.057 9,300 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.22 <0.07 <0.05 <0.15 1.3 610 115 2 <10 11 0.6H <0.05 4.3J <1 2.6 MW-A 9-May-12 0.00 103 0.11 0.027 8,000 0.16 <0.05 0.056 <0.05 <0.05 <0.15 0.11 <0.07 0.02 <0.15 3.2 560 146 6 <10 14 2.22H <0.05 <5 <0.2 0.364 MW-A 27-Nov-12 2.66 140 0.073 0.018 9,000 <0.07 <0.05 0.016 <0.10 <0.05 <0.15 0.043 <0.07 <0.05 0.071 4 530 127 8 13.3 19 0.60 <0.05 <5 0.2281 2.52 MW-A 7-May-13 0.25 -34 0.11 0.033 7,500 0.03 <0.05 0.07 <0.10 <0.05 <0.15 0.07 <0.07 <0.05 <0.15 0.54J 470 131 5 5.15 16 0.28 <0.05 <5 <0.2 2.62 MW-A 5-Nov-13 1.89 290.8 0.051 <0.025 8,000 0.028 0.044 <0.5 <0.1 <0.15 0.11 <0.07 <0.05 <0.15 0.94 530 128 6 <10 20 0.60 <0.05 3J <0.2 2.53 MW-A 6-May-14 0.04 -17 0.048 <0.025 11,000 0.21 0.077 <0.5 <0.1 <0.15 0.026 <0.07 0.050 <0.15 0.90 580 131 4 <10 29 2 <0.05 3.5J 0.2321 3.1 1302-MSWLF- MW-A 4-Nov-14 1.70 45 0.082 0.019 10,000 0.038 <0.05 <0.5 <0.2 <0.15 <0.1 <0.07 0.048 <0.15 4.8 640 111 2 <10 32 1 <0.05 4.4J <0.2 2.32 CDLF-1998 MW-A 5-May-15 2.34 26 0.0801 0.015 10,000 <0.07 <0.05 0.090 <0.5 <0.2 <0.15 0.027 <0.07 <0.05 <0.15 14.0 580 117 4 <10 28 1 <0.05 5.91 <0.2 3.15 MW-A 27-OR-15 1.41 29 0.084 0.011 9,900 0.032 0.0066 0.022 <0.20 <0.20 <0.10 0.013 <0.10 0.0033 <0.10 7.2 600 123 11 <10 25 0.5 <0.05 7.41 <0.2 4.18 MW-A 17-May-16 1.27 -55 0.094 <0.10 11,000 0.21 0.084 0.032 <0.20 <0.20 <0.10 0.0075 <0.10 <0.10 <0.10 1.3 540 85 6 <10 18 1.0 <0.05 13J <0.2 3.68 MW-A 1-Nov-16 1.65 205 0.087 0.015 9,500 0.040 <0.30 0.057 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.8 640 129 12BOD-4 33.8 27 1.5 <0.05 191 <0.2 3.21 MW-A 9-May-17 1.31 140.1 0.014 0.0087 1300 0.088 0.0095 0.053 <0.20 <0.20 <0.10 0.0078 <0.10 0.0090 <0.10 8.0 530 143 14 42.9 27 1.0 <0.15 17J <0.2 3.22 MW-A 31-OR-17 3.21 70 0.0851 0.00651 9,300 <0.20 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.9 450 132 13 35.2 27 0.5 <0.05 24 <0.2 3.22 MW-A 7-Jun-18 0.4 635 <0.10 0.011 6,100 0.0261 <0.30 <0.20 <0.20 <0.20 <0.10 0.0501 0.0681 <0.10 <0.10 73 480 136 <2 <10 24.1 1.5 0.01001 15.5 <0.2 20.5 MW-A 20-Dec-18 0.6 32.4 <0.10 <0.10 7,600 0.22 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 110 600 135 8.06 <10 2.39 3.5 0.01901 1.24 2.03 2.09 MW-E Rep 4-May-11 0.01 34 0.37 0.38 5,000 0.22 0.086 <0.1 <0.05 <0.05 0.092 0.13 <0.07 0.092 0.18 1.4 410 261 5 13 30 <0.07H <0.006 13J <0.6 4.2 MW-E Rep 8-Nov-11 0.00 -115 4.9 0.36 4,300 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.21 <0.07 <0.05 <0.15 1.4 460 275 5 34 32 5.89H <0.05 iii <1 4 MW-E Rep 8-May-12 0.00 13 4.6 0.33 2,200 0.048 <0.05 0.052 <0.05 <0.05 <0.15 0.086 <0.07 <0.05 <0.15 2.1 430 285 4 <10 30 8.22H <0.05 8.11 <0.2 0.317 MW-E Rep 8-May-13 0.47 -81 6.6 0.5 1,600 0.048 <0.05 0.074 <0.05 <0.05 <0.15 0.072 <0.07 <0.05 <0.15 0.561 350 405 2 16.9 52 3.3 <0.05 <5 <0.2 4.89 MW-E Rep 5-Nov-13 1.64 -39.8 4.2 0.36 1,700 0.038 0.058 <0.5 <0.1 <0.15 0.11 <0.07 <0.05 <0.15 0.81 330 320 4.09 24.6 31 2.77 <0.05 5J <0.2 4.18 MW-E Rep 6-May-14 0.07 -24 2.6 0.27 2,400 0.095 0.091 <0.5 <0.1 <0.15 0.15 <0.07 0.048 <0.15 0.97 400 285 3 <10 28 5 <0.05 8.5J <0.2 4.08 1302-MSWLF- MW-E Rep 4-Nov-14 1.62 -54 3.7 0.56 2,800 0.038 <0.05 <0.5 <0.2 <0.15 0.051 0.070 <0.05 <0.15 1.4 430 610 3 <10 45 3.5 <0.05 iii <0.2 4.44 CDLF-1998 MW-E Rep 5-May-15 3.61 -38 3.4 0.47 1,700 <0.07 <0.05 0.12 <0.5 <0.2 <0.15 0.036 0.028 <0.05 0.044 13 340 415 4 11 48 2.5 <0.05 iii <0.2 6.14 MW-E Rep 27-Oc[-15 1.25 -36 4.1 0.73 2,300 0.038 0.0062 0.049 <0.20 <0.20 <0.10 0.011 0.011 0.0026 <0.10 7.3 380 365 5 <10 48 2.0 <0.05 8.3J <0.2 4.82 MW-E Rep 18-May-16 1.40 -59 3.3 0.63 680 0.21 1 0.12 <0.20 <0.20 <0.10 <0.20 0,024 0.021 0.014 1 250 425 3 <10 55 0.5 <0.05 6) <0.2 4.49 MW-E Rep 1-Nov-16 3.79 48.1 4.8 0.73 660 0.035 <0.10 0.056 <0.20 <0.20 <0.10 0.0060 0.0086 <0.10 0.012 2.3 370 475 <2 33.4 50 3.0 <0.05 78J <0.2 5.06 MW-E Rep 9-May-17 1.35 -50.7 3.2 0.55 730 0.077 <0.10 0.058 <0.20 <0.20 <0.10 <0.20 0.0067 <0.10 0.010 2.6 340 457 2 38 65 4.5 <0.05 6.41 <02 4.38 MW-E Rep 31-Oc[-17 11 65 4.0 0.58 600 0.0201 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 3.8 280 484 <2 32 54 2.5 <0.05 6.6 <0.2 4.46 MW-E Rep 11-Jun-18 1.3 -262 2.1 0.44 420 0.0581 <0.10 0.101 <0.20 <0.20 <0.10 0.026J 0.0451 <0.10 <0.10 120 280 462 6 <11 16.4 4.1 <0.0050 5.87 <0.2 3.33 MW-ERep 20-Dec-18 0.3 -16.1 2.9 0.63 830 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 13 380 495 3.59 <10 49 6.0 0.01701 6.81 <02 3.78 Smith Page 15 of 16 February 2019 Table Sd Geochemical Constituents in Groundwater December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 MW-EDeep 4-May-11 0.00 -51 3.3 0.14 6,900 4.3 0.13 <0.1 <0.05 <0.05 <0.15 <0.1 <0.07 0.25 <0.15 2.3 100 401 7 37 27 2.7 <0.006 0.0961 <0.6 5.4 MW-EDeep 8-Nov-11 0.00 -67 10 0.29 19,000 2.2 0.021 <0.1 <0.05 <0.05 <0.15 0.076 <0.07 <0.05 <0.15 2 160 345 16 33 26 2.2 0.0071 <5 <1 2.9 MW-EDeep 8-May-12 2.51 -76 7.5 0.11 14,000 0.84 <0.05 0.090 <0.05 <0.05 <0.15 0.10 <0.07 0.024 <0.15 3.3 160 305 24 22.6 27 4.03H <0.05 <5 <0.2 0.207 MW-EDeep 27-Nov-12 1.70 78 9.8 0.14 16,000 0.19 <0.05 0.058 <0.10 <0.05 <0.15 0,134 <0.07 <0.05 0,11 1.1 160 215 30 39.2 28 7" <0.05 <5 <0.2 1.37 MW-EDeep 8-May-13 0.51 -80 13 0.13 16,000 0.25 <0.05 0.12 <0.10 <0.05 <0.15 0.066 <0.07 0.028 <0.15 0.99 140 370 5 26.4 28 3.3 <0.05 <5 <0.2 2.3 MW-EDeep 6-Nov-13 1.21 -82.2 13 0.18 15,000 0.11 <0.05 <0.5 <0.1 <0.15 0.16 <0.07 <0.05 <0.15 1.5 170 345 5.97 23.1 31 3.3 <0.05 <5 <0.2 2.51 MW-EDeep 6-May-14 0.09 -41 4.6 0.13 19,000 120 20 2.9 <0.1 1.9 <3 20 100 4.0 1.3 480 320 1,580 2,410 20 5.5 <0.05 <5 <0.2 432 1302-MSWLF- MW-E Deep 4-Nov-14 1.09 -82.3 2.8 0.056 22,000 52 2.3 0.44 <0.2 A. 0.046 0.37 5.4 0.21 6.7 330 625 208 355 30 1.5 <0.05 <5 <0.2 41.6 CDLF-1998 MW-E Deep 5-May-15 0.88 -100 9 0.059 22,000 7.1 0.092 0.23 <0.5 <0.2 0.029 0.019 <0.07 0.12 0.042 17 220 410 47 59.2 35 1 <0.50 <5 <2 8.26 MW-EDeep 27-Oct-15 1.20 -71 8.1 <0.50 26,000 2.4 0.085 0.035 0.012 <0.20 <0.10 <0.20 <0.10 0.026 <0.10 8.7 170 415 36 22.4 34 3.0 0.13J <5 <0.2 4.52 MW-EDeep 18-May-16 3.08 -95 3.9 0.021 16,000 2.8 0.2 0.064 <0.20 <0.20 <0.10 <0.20 <0.10 0.064 0.012 2.3 130 <1 28 63.8 37 3.0 <0.05 <5 <0.2 6.34 MW-EDeep 1-Nov-16 2.30 -39 12 0.063 29,000 0.12 <0.30 0.072 <0.20 <0.20 <0.20 <0.20 <0.10 <0.10 <0.10 2.7 210 415 62.5 44 2.0 <0.5 <5 <0.2 3.16 MW-EDeep 9-May-17 1.65 -78.5 8.2 0.067 21,000 0.073 <0.30 0.081 <0.20 <0.20 <0.10 <0.20 0.0095 <0.10 0.0099 3.6 190 395 26 70.7 49 5.0 0.5J 0.15J <0.2 3.39 MW-EDeep 1-Nov-17 2.45 152 6.8 0.048J 17,000 0.18 <0.30 0.13J <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.1 170 407 8 60.6 53 3.0 <0.05 0.0711 <0.2 5.22 MW-EDeep 11-Jun-18 0.4 -84 5.5 0.047J 13,000 0.089J <0.30 0.13J <0.20 <0.20 <0.10 <0.20 0.0691 0.0098J <0.10 2.0 160 398 25.4 16.9 49.2 5.5 <0.0050 <0.0170 <0.2 2.37 MW-E Deep 20-Dec-18 1 0.4 1 -56.2 6.6 1 0.10 1 11,000 <0.10 1 <0.10 1 <0.20 <0.20 1 <0.20 1 <0.30 1 <0.20 <0.10 1 <0.10 <0.10 1 7.7 320 451 7.59 1 303 5.62 1 6.0 1 0.0170J <5 <0.2 5.34 MW-L 4-May-11 2.31 206 <0.01 0.003 0.3 0.22 0.11 <0.1 <0.05 <0.05 <0.15 0.32 <0.07 0.097 <0.11 0.7 72 44 <0.5 <6 2.2 0.161 0.13J 1.81 <0.6 0.5 MW-L 9-Nov-11 2.59 222 <0.025 0.066 0.3 <0.07 0.019 <0.1 <0.05 <0.05 <0.15 0.16 <0.07 <0.05 <0.15 1.4 83 30 <2 101 2.6 <0.2H 0.0961 1.&1 <1 0.5B MW-L 9-May-12 0.04 214 <0.025 0.014 0.69 0.049 <0.05 0.062 <0.05 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 1.1 98 37 <0.002 <10 2.6 <0.2H 0.096J <5 <0.2 0.342 MW-L 28-Nov-12 3.03 3 0.22 0.037 2.8 <0.07 0.033 0.031 <0.10 <0.05 <0.15 0.066 <0.07 <0.05 <0.15 0.43J 72 90 <2 <10 2.7 <0.2H 0.0521 <5 <0.2 <1 MW-L 9-May-13 1.09 188 <0.025 0.024 0.55 0.024 <0.05 0.056 0.044 <0.05 <0.15 0.085 <0.07 <0.05 <0.15 1.2 79 28 1.91 2.22 2.7 0 0.06J <5 <0.2 <3 MW-L 7-Nov-13 1.39 258.1 <0.025 <0.025 0.059 0.034 <0.05 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.78 90 35 2 <10 2.8 0.61 0.065J <5 <0.2 1.43 MW-L 8-May-14 2.12 379 0.0030 0.0038 0.042 0.063 <0.05 <0.5 <0.1 <0.15 0.033 <0.07 0.034 <0.15 0.79 100 34.3 <2 <10 2.8 0.5 0.061J <5 <0.2 <3 1302-MSWLF- MW-L 5-Nov-14 4.03 59.2 0.0037 0.014 0.63 0.042 <0.05 <0.5 <0.2 <0.15 0.058 <0.07 0.049 <0.15 1.3 100 31 <2 <10 3.1 0 0.0811 2.9J <0.2 <1 CDLF-1998 MW-L 6-May-15 4.15 131 0.005 0.016 0.055 <0.07 <0.05 0.12 <0.5 <0.2 <0.15 0.014 <0.07 <0.05 <0.15 26 100 31 <2 11 2.7 0 <0.5 1.91 <0.2 <3 MW-L 28-Oct-15 3.80 89 0.0058 0.019 0.077 0.029 0.0081 0.033 <0.20 <0.20 <0.10 <0.20 <0.10 0.0022 <0.10 8.9 94 39 <2 <10 3 0 0.054J 1.5J <0.2 <1 MW-L 19-May-16 3.66 192 <0.10 <0.10 0.031 0.012 <0.10 0.033 <0.20 <0.20 <0.10 0.0063 <0.10 <0.10 <0.10 0.63 98 35 <2 10 2.8 0 <0.05 1.4J <0.2 <10 MW-L 2-Nov-16 3.49 486 0.028 0.013 0.8 0.029 0.0079 0.046 <0.20 <0.20 <0.10 0.0062 <0.10 <0.10 <0.10 1.7 87 40 <2 12.9 3.2 0 0.0851 <5 <0.2 <1 MW-L 10-May-17 1.40 128.9 0.046 0.011 0.24 0.021 <0.10 0.044 <0.20 <0.20 <0.10 0.030 <0.10 <0.10 <0.10 2.3 89 41 <2 <10 3 0 <0.05 0.95J <0.2 <1 MW-L 1-Nov-17 1.61 361 0.0098J 0.0161 0.251 0.023J <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.3 89 45 <2 <10 3.2 0 0.011 1.81 <0.2 <1 MWI 7-Jun-18 1.2 141.2 0.011J 0.0171 0.231 0.0441 <0.10 0.0731 <0.20 <0.20 <0,10 <0.20 0,0661 <0.10 <0.10 13 94 34 <2 <10 2,94 0 0.0840 0.9841 <0.2 <1 MW-L 19-Dec-18 2.7 100.4 <0.10 <0.30 0.93 <0.30 <0.30 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 13 95 41 <2 <10 2.95 0 0.0770 0.9881 <0.2 <1 Notes: 1. Blank cells indicate parameter was not analyzed or the result was below the detection limit. 2. Assessment wells AMW-1s, -Id, 2" and 2d were installed in October 2009. 3. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 4. BOD-1- Indicates the dilutions selected forthe BOD analysis based on screening COD values did not meet the oxygen depletion criteria of at least 2 mg/L dissolved oxygen depletion. The result is reported as an estimated value or non -detect at the elevated reporting limit. 5. H, H-02 - Sample was analyzed outside the U.S. Environmental Protection Agency recommended holding time. 6. B - Indicates constituent was detected in the batch blank above the method detection limit. 7. BOD-3 - Lab control recovery was outside control limits biased low. Samples could not be reanalyzed due to holding time requirements. Sample values are reported as estimated values with possible low bias. R. BOD-4 - Lab control recovery was outside control limits biased high. Samples are reported as estimated with possible high bias. 9. mg/I - milligrams per liter/pg/I - micrograms per liter/mVolts - millivolts/Nm - nanomoles 10. HIBA - Hydroxyisobutyric Acid 11. Alkalinity, chloride, ferrous iron, sulfate, and total dissolved solids were added to the sampling program in May 2010 for CD -Is and CD-1d. 12. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced M W-9 as the background monitoring wells. 13. MW-9 was removed from the monitoring program in November 2012. 14. M W-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. Smith Page 16 of 16 February 2019 Table 6 Constituents Detected Above Standards December 2018 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 PERMIT MONITORING PARAMETERS EXCEEDING NORTH CAROLINA 2L OR IMAC MONITORING PARAMETERS EXCEEDING NORTH CAROLINA 2L OR IMAC STANDARDFACILITY NUMBER WELL STANDARD 1302-MSWLF- MW-9 Not Sampled MW-D Cobalt*, Vanadium*, Benzene, 1,4-Dichlorobenzene, Vinyl Chloride CDLF-1998 1302-MSWLF- CD-1s Chromium, Iron, Vanadium* MW-E Rep Cobalt*, 1,4-Dichlorobenzene, 1,2-Dichloropropane, Vinyl Chloride CDLF-1998 (background well) 1302-MSWLF- CD-1d Iron, Vanadium* MW-E deep Barium, Cobalt*, Benzene, 1,4-Dichorobenzene, 1,4-Dioxane CDLF-1998 (background well) 1302-MSWLF- CD-4 Rep Cobalt*, Vanadium* MW-F Cobalt*, 1,4-Dioxane CDLF-1998 1302-MSWLF- AMW-1s Vanadium*, Tetrachloroethene MW-G Cobalt*, Vanadium*, 1,4-Dioxane CDLF-1998 1302-MSWLF- Cobalt*, Vanadium*, Benzene, 1,1-Dichloroethane, Trichloethene, AMW-1d MW-H Cobalt*, Vanadium* CDLF-1998 Vinyl Chloride 1302-MSWLF- AMW-2s Tetrachloroethene MW-H deep Vanadium* CDLF-1998 1302-MSWLF- AMW-2d 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene MW-1 Vanadium*, 1,1-Dichloroethane, Tetrachloroethene CDLF-1998 1302-MSWLF- MW-1 Cobalt*, Vanadium*, 1,4-Dioxane MW-J Vanadium* CDLF-1998 1302-MSWLF- MW-3 Vanadium*, 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene MW-K Thallium*, Vanadium* CDLF-1998 1302-MSWLF- MW-3 deep Not Sampled MW-L None Detected CDLF-1998 Cobalt*, Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane, - 1302 MW-A 1,2-Dichloroethane, cis-1,2-Dichloroethene, 1,2-Dichloropropane, MW-L deep Not Sampled CDLF-1998 -1998 Tetrachloroethene 1302-MSWLF- MW-B Cobalt*,1,4-Dioxane MW-M Not Sampled CDLF-1998 1302-MSWLF- MW-C None Detected MW-X Vanadium* CDLF-1998 Notes: 1. Monitoring wells MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 2. * - Constituents exceed the Interim Maximum Allowable Concentration (IMAC) 3. Bold -J Flag - Indicates the analytical result is an estimated concentration between the method detection limit and the method reporting limit. 4. The November 2012 sampling event was the first event that CD-1s/-1d replaced MW-9 as the background monitoring wells. 5. MW-9 was removed from the monitoring program in November 2012. CDM Smith Page 1 of 1 February 2019 Table 7 DHC Sampling Summary Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 .. .. .. MW-E Rep 9-Jan-14 1,958 + 1.37E+06 + 1.81E+05 9.48E+05 + 8.02E+04 0.00E+00 + 0.00E+00 5.46E+02 + 1.02E+02 MW-E Rep 4-Mar-15 328 + 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 MW-E deep 9-Jan-14 3,524 + 1.38E+07 + 2.23E+06 7.85E+05 + 1.10E+05 0.00E+00 + 0.00E+00 2.84E+06 + 4.53E+05 MW-E deep 4-Mar-15 6,848 + 5.20E+03 ± 6.72E+02 9.00E+03 ± 8.24E+01 0.00E+00 ± 0.00E+00 7.06E+02 ± 1.28E02 AMW-1s 9-Jan-14 8,214 + 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-1s 4-Mar-15 538 + 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 AMW-1d 9-Jan-14 2,648 + 3.53E+03 + 3.17E+03 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-1d 4-Mar-15 1,716 + 1.03E+06 ± 1.12E+05 6.18E06 ± 2.89+05 0.00E+00 ± 0.00E+00 3.13E+04 ± 2.79+03 AMW-2s 9-Jan-14 1,917 + 3.09E+05 + 5.12E+04 1.24E+06 + 2.26E+05 9.61E+04 + 1.86E+04 5.66E+04 + 1.12E+04 AMW-2s 4-Mar-15 1,564 + 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 AMW-2d 9-Jan-14 1,320 + 8.81E+03 + 3.15E+02 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-2d 4-Mar-15 108 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 Notes: 1. PCR - Polymearse chain reaction 2. DHC - Dehalococcoides spp 3. * - A "+" inidicates that amplication of bacteria was successful. "-" indicates that ampification was not successful. 4. ng/L - Nanogram per liter S. copy/L - Copy per liter Indicates the result is between the laboratory method detection limit and the reporting limit. Smith Page 1 of 1 February 2019 -� CD- Ds GW 9 M 4 ' '8 D-1S M-1 j _ P EXI "L^& D L P-4 P- AL , PH E A II COVER MATERIAL STOCKPILE o S 3 TIV ER1311T 1 2=CDtF 2 O& -8 \ MW / ABANDON O AB DC6 INV ' AB ND NED SEDIMENTATION POND4Vk�70 PH" S LAN ,„' CD-S��12` 1as1 D -° AB /I/ \\ \\ n== MGW-13 \° 200 0 400 5 / ABANDON *115N / �� / / �a APPROX LIMI °• IRISH POTATO ROAD PHA. o-ANDFIL EXPANSION P ROB=WASTE B U R OLD FILL A / '° CATEGORY 2 K UNIT 1 / CLOSURE A E �, M ANDFILL'°' t" UNIT 2 tee, ei-s" 0�° INACTIVE SED) �-���/ ElNACtIV CD j a1-o ( x E CDLF OVER $ x R s PE MIT' 1302-MSWLF= o x PE IT 2- S 02-C L 1 9 / / MW-8 7 �. P °\ n MGM 2 4fr� ezu 2 W-1 MGW-12 w 89.9 95.5 ° MW B-4 A W MW-7 GW �� N6W G 703 5 / 0 rw 9 '.3 u , MIM-5 \ G*1602.60 LEGEND \- ORR AR 's`9 '// `� g'"` \ _ \� ■M_1 MONITORING WELL PROJE TE BO DAY �11 op-1 METHANE PROBE OCT 9 3 M -B� 6 ORROW AREA \ U 3 - \GW 679. G 9. $ \ CDLF. 0 MSWy, 0MW-5 MONITORING WELL WITH GROUNDWATER ELEVATIONS (INACTIVE SED) PERMIT 1302- F- w OMW-6 ABANDONED GROUNDWATER MONITORING WELL / PERMIT 1302-CDL 999'' I SW-1 MGW-3 1 s b sw-1 SURFACE WATER sAMPu c STATION (713) ESTIMATED ELEVATION OF WATER TABLE S �p-1 r. if PIEZOMETER MW n,= ,.. - ,., F � GW \\�� 1 a � POTENTIOMETRIC CONTOUR W 674.33�- /� _ MGW-1 METHANE GAS MONITORING WELL MW-EREP GW 683.49 G YW 6 .5 M DEEP G G W 67 . 2_ -�D E ATON W6 .01 ro. P o M= c 4 ..CW i � .20 - AMW-1 �° � NOTE: 1. THROUGH M, WITH MW-1-3 M-3 DEEP COMPRISE THE AS 6a, - MW-A ALONG AND GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED _ I /) 1 2.52 MONITORING SYSTEM. CD-4, CD-5, AND CD-6 WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN SEPTEMBER 2006. M HD A g P ,° 67 .2 VV.'.' 1 °'° 7 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. 3. F R U 7, 1. 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS THE C&D LANDFILL. AND CD-1D SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND �. \ W 6 7, j O 4. CD-15, CDD, CAND CD-3 ARE THE APPROVED MONITORING WELLS FOR THE C&D LANDFILL AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. % A W-L DEE °� -,8 n° 1 5. GROUNDWATER ELEVATIONS MEASURED DECEMBER 17-18, 2018, EXCEPT FOR MW-3 DEEP, � 0.6 - G f659.53 I "T e -L DEEP, AND -M WHICH WERE MEASURED ON JANUARY 18, 2019. \ MW DEEP e e 0, 6 '\ \ 6. ASSESSMENT WELLS AMW-1S, -1D, -2S, AND -2D WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN OCTOBER 2009. 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. 822 \ Q rQ W_ �^ °°'M\° , \ 8. WAS REMOVED FROM THE MONITORING PROGRAM AND WAS NOT SAMPLED DURING THE - % '. NOVE NOVEMBER 2014 SAMPLING EVENT. 9. CD-7 AND CD-8, FORMERLY PIEZOMETERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE MONITORING PROGRAM IN JULY 2014. 6 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY J. KILLINGSWORTH SHEET CHK'D BY: D. FORBE5 CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES DATE; FEBRUARY 2019 DM Smith DM Glenwood Ave, Suite 400 UM "" GSm'"`.REV R aleigh, NC2]fi12Tel:(919)3253500 NC F-0412 CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 POTENTIOMETRIC SURFACE MAP PROJECT 276-231402 FILE NAME:: cne-F-la.owc FIGURE NO. DATE DRWN CHKD REMARKS fry �r..,,�•�. ' LEGEND E Regolith Monitoring Well E Bedrock Monitoring Well Injection Well f 1" = Approximately 100' Notes. 1. The injection wells were installed using air -rotary drilling methods from October 5-9, 2009. 2. The injection wells are spaced approximately 30 feet apart perpendicular to groundwater flow and have a radius of influence of approximately 15 feet. 3. Surface area of the injection well network is approximately 5,400 feet. 4. The Phase I injection event was completed from November 2-6, 2009. 5. The Phase II injection event was completed from February 10-18, 2014. CDM_ Figure 2: Injection Area Overview Smith Closed Landfill Units 2 and 3 Cabarrus County, North Carolina Figure 3 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 M W-A 450.0 400.0 350.0 _ 300.0 Mo 0 UO 250.0 a U +; 200.0 v 0 M 41 0 �- 150.0 100.0 50.0 0.0 -:t Ln M lD lD I- n w W M M O O ri ri N N M M -zt -zt Ln Ln lD lD I, r, 00 00 D1 Ol O O ri r-I N N M M -:t -zt Ln Ln lD lD I, r, W W 01 Ol 01 01 T T T Ol 01 Ol T T O O O O O O O O O O O O O O O O O O O O r-I ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri C V C v C v C V C v C v C V C v C v C v C V C v C v C v C v C v C v C V C v C v C V C v C v C v C v Date Smith Note: Only detections above laboratory method detection limits represented in figure. Figure 3 (MW-A) .M 50.0 40.0 3 M ++ H 2O.0 10.0 Figure 4 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 M W-3 W W M M O O rl -1 N N M M IZT I:t eft M l0 l0 I, r, W W M M O O rl c-I N N M M M M l0 l0 I, r, W W Ol T T T O O O O O O O O O O O O O O O O O O O O rl rl rl rl rl rl rl rl rl rl r rl rl rl rl rl rl rl C V C V C V C V C V C V C V C V C U C u C U C V C U C V C U C u C V C V C V C V C u Date Smith Note: Only detections above laboratory method detection limits represented in figure. Figure 4 (MW-3) Figure 5 200.0 180.0 160.0 140.0 tk o 120.0 tA U 0 - 100.0 cu -W U v v 0 80.0 Fu 0 40.0 KIXII we Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 MW-E Rep - - - - - - - - - - - - - - - - - - - - - - - - - � Date CDM Notes: Only detections above laboratory method detection limits represented in figure. Smith MW-E was not sampled during the November 2012 sampling event due to laboratory oversight. Figure 5 (MW-E Rep) 180.0 160.0 140.0 „120.0 J OA 3 0100.0 v U u 80.0 0 M 41 0 ~ 60.0 40.0 20.0 Ml Figure 6 Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 MW-E deep Ol O1 O O r-1 r-I (V N M M 'zt 'zT Ln In l0 l0 I- r- W W M M O O -1 ci N N M M V1 Ln l0 lD I, r, W W C v C U C u C U C v C V C V C V C v C v C U C u C U C u C V C u C V C u C v C U Date Total VOC t PCE fTCE f DCE PVC Smith Note: Only detections above laboratory method detection Imits represented in figure. Figure 6 (MW-E deep) LY111; tw 3 u 40.0 O v U U w v 30.0 0 M +. 0 rM 10.0 Figure 7 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-1s Phase I Emulsified Oil Injection - November 2009 Phase II - February 2014 I 0.0 ' 1 1' 01 CY) O O a--1 r-I N N M M V1 Ln to to I- r- 00 00 C u C U C u C u C U C u C u C U C U C u 7 N 7 a) 7 v 7 w 7 a) 7 v 7 w 7 a) 7 v 7 v Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 7 (AMW-1s) 1W8a111 100.0 80.0 3 V 0 i co O �— 40.0 20.0 b� Figure 8 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-1d Phase I Emulsified Oil Injection - November 2009 Phase II - February 2014 I � I I I 01 M O O 1-1 ri N N M M 1:T -ZT Ln Ln l0 l0 I, r-1 00 00 C u C U C U C U C U C U C U C U C U C u 7 N 7 41 7 v 7 a) 7 41 7 v 7 a) 7 41 7 v 7 v Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 8 (AMW-1d) 35.0 30.0 25.0 20.0 v 15.0 0 M 41 0 H 10.0 5.0 SM Figure 9 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-2s i Phase I Emulsified Oil Injection - November 2009 i Phase II - February 2014 R a) a) O O c-1 ri N N rn M U) Ln lD lD I, r- 00 00 c u c U c u c b c u c U b c u v v D W M v Z) v D W =3 v =3 v D (3) M v Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 9 (AMW-2s) 80.0 70.0 3 50.0 v 40.0 30.0 0 Qiail 10.0 .y-fim Figure 10 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-2d Phase I Emulsified Oil Injection - November 2009 Phase II - February 2014 I Ol M O O c-1 ri N N M M U) Ln lD lD I, r- 00 00 O O i rI 1� I 1� c u c U U c u c U U c u c U c b c u v - v - M — v — v — a) — v Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 10 (AMW-2d) iC 0 CD-1 5 M-4 „y_ I NOC 1. \ M-1 / � P \ EXI G $ P-4 P ° / �% C&D LANDFI L PHASE I AN II , COVER MATERIAL STOCKPILE o ER1311T 1 2=Ci7LF 2 � � ° NOC= 01 ABA ^ ND j GW-14- i ABAD �_ ° / Ic -7 e /y' CD-8 A AND NEO/ $ / _ I A �A ® \ 0 - 0 1y ABANDONED '� A N - " PHAS D ° 1 . = 400, SEDIMENTATION POND _MI Fi'Et P [,. B ONEO , /•/ I \\\ \ MGW�1 200 0 400 \ HI/j', , "'-«. / `\ p-g�/ bQ « PHA I E I + D I i / '«.. APPROX LIMI \ IRISH POTATO ROAD ANDFIL EXP SI N ' RO�•WASTE B U R OLD FILL A I .I� I CATEGORY 2 CLOSURE A E K :° UNIT 1 "" ep I, MSW LANIDFILL'°°' B UNIT 2 oI (INACTIVE/CLOSED) j —o � CDLF OVER R S I PE MIT 1302—MSWLF^�197 ( NAIVE/C 0 g R Q 0 E IT 1302— S « �Q e RM11T TM2—C L 1 9 i / / M A \ 1010 d « MW-A B-4 \ MW Tvc X \ MW LEGEND \� 1\ ORR AR MONITORING WELL \ .\ PROJE TE BO MW 1 / �P-1 E ^� T OF P / ° % METHANE PROBE 3MSV�„ ORROW AR A TM:, 0MW-5 MONITORING WELL WITH TOTAL VOLATILE ORGANIC / / 1� CDLF 0 w I \ COMPOUNDS (TVOC) DATA IN PARTS PER BILLION (PPE) (INACTIVE SED� ERMIT 1302— F— 2S n / OMW-6 ABANDONED GROUNDWATER MONITORING WELL \ 1 - I m $ - SW-1 SURFACE WATER SAMPLING STATION `� P MIT 1302—CDL 998'�' I / _ _ ____ ��� MGW-3 I '� (713) ESTIMATED ELEVATION OF WATER TABLE 0P-1 PIEZOMETER M W-9 w TVOC ISOCONTOUR (PPB) MW R* NOC='4.3 B _ � w /' OMGW-1 METHANE GAS MONITORING WELL OC= 8.3 INJECTION AREA NOC=54.7 W D E ATON D O NO =18.6 SEDIMENTATIO PO D NOTE: YA D u. SW-2 \� 1. MW—A THROUGH M, ALONG WITH AND DEEP COMPRISE THE na.. =52.fi - GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED FOR U AN MONITORING SYSTEM. CD-4, AND CD-6 WERE ADDED TO THE GROUNDWATER WH MONITORING NETWORK IN SEPTEMBTEMBER 2006. "`" 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. — � e 3. MW-5, 7, SA, 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS FOR UNIT 1. CD AND CD—iD SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND OC.4 „� -2p —is THE C&D LANDFILL. ( P) 53.6 = 9 4. CD-1S, CD-1D, CD-2, AND CD-3 ARE THE APPROVED MONITORING WELLS FOR THE C&D LANDFILL AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. \ p, 5. TVOC DATA FROM DECEMBER 17-20, 2018. ALL VALUES ARE REPORTED IN PARTS PER BILLION (PER) AND DETECTIONS ARE AT OR ABOVE LABORATORY REPORTING LIMITS. \ \ 6. ASSESSMENT WELLS AMW-1S, —1D, —zS, AND —2D WERE ADDED TO THE GROUNDWATER \ MONITORING NETWORK IN OCTOBER 2009. 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. 0 '.., N & MW-9 WAS REMED FROM THE MONITORING PROGRAM AND WAS NOT SAMPLED DURING THE OV NOVEMBER 2014 SAMPLING EVENT. 9. CD-7 AND CD-8, FORMERLY PIE70METERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE MONITORING PROGRAM IN JULY 2014. �\ �h JJJ l 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY J. KILLINGSwORTH SHEET CHK'D BY: D. FORBES CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES DATE; FEBRUARY 2019 DM_ Smith DM GlAve, Suite 400 GDM Smenwood ""'"`.REV Raleigh, NO27612Tel:(919)3253500 NOF-0412 CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 TVOC ISOCONCENTRATION CONTOUR MAP PROJECT No. 27e-231402 FILE NAME: cAe—Iso—F1a.owc FIGURE 11 NO. DATE DRWN CHKD REMARKS Appendix A 11!;a'ceAna1j&a( wmpacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 January 10, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory between December 19, 2018 and December 21, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 157 11!;a'ceAna1j&a1" wmpacelabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID Matrix Date Collected Date Received 2612903001 1302-MWI Water 12/18/1810:30 12/19/1810:20 2612903002 1302-MW1 Water 12/19/18 08:20 12/20/18 10:15 2612903003 1302-MW3 Water 12/19/1815:48 12/20/18 10:15 2612903004 1302-MWB Water 12/19/18 09:10 12/20/18 10:15 2612903005 1302-MWC Water 12/19/1810:35 12/20/18 10:15 2612903006 1302-MWD Water 12/19/1812:05 12/20/18 10:15 2612903007 1302-MWF Water 12/19/18 08:45 12/20/18 10:15 2612903008 1302-MWG Water 12/19/18 09:45 12/20/18 10:15 2612903009 1302-MWH Water 12/19/1811:00 12/20/18 10:15 2612903010 1302-MWHdeep Water 12/19/1810:50 12/20/18 10:15 2612903011 1302-MWJ Water 12/19/1811:25 12/20/18 10:15 2612903012 1302-MWK Water 12/19/1812:30 12/20/18 10:15 2612903013 1302-MWL Water 12/19/1816:10 12/20/18 10:15 2612903014 1302-MWX Water 12/19/1811:00 12/20/18 10:15 2612903015 1302-CD4Rep Water 12/19/18 08:10 12/20/18 10:15 2612903016 1302-AMW1s Water 12/19/1813:03 12/20/18 10:15 2612903017 1302-AMW1d Water 12/19/1813:21 12/20/18 10:15 2612903018 1302-DUP2/3 Water 12/19/18 08:45 12/20/18 10:15 2612903019 1302-EQBlank2/3 Water 12/19/1816:00 12/20/18 10:15 2612903020 1302-Trip Blank Water 12/19/18 00:00 12/20/18 10:15 2612903021 1302-MWA Water 12/20/1810:35 12/21/1811:00 2612903022 1302-MWE Rep Water 12/20/18 11:44 12/21/18 11:00 2612903023 1302-MWEdeep Water 12/20/1813:31 12/21/1811:00 2612903024 1302-AMW2s Water 12/20/1811:51 12/21/1811:00 2612903025 1302-AMW2d Water 12/20/1812:34 12/21/1811:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2612903001 1302-MWI EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903002 1302-MW1 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903003 1302-MW3 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903004 1302-MWB EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903005 1302-MWC EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903006 1302-MWD EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903007 1302-MWF EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903008 1302-MWG EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903009 1302-MWH EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903010 1302-MWHdeep EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2612903011 1302-MWJ EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903012 1302-MWK EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903013 1302-MWL EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903014 1302-MWX EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903015 1302-CD4Rep EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903016 1302-AMW1s EPA6020B KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903017 1302-AMW1d EPA6020B KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID Method Analysts Analytes Reported Laboratory SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903018 1302-DUP2/3 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903019 1302-EQBlank2/3 EPA 6020E KLH 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903020 1302-Trip Blank EPA 8260B Mod. DLK 3 PASI-C EPA 8260B LIH 52 PASI-GA 2612903021 1302-MWA EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903022 1302-MWE Rep EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903023 1302-MWEdeep EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG 52 PASI-GA SM 2320B KN 1 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903024 1302-AMW2s EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2612903025 1302-AMW2d EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E JHG 52 PASI-GA SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D JPT 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1s Lab ID: 2612812001 Collected: 12/17/18 15:28 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Date: 01/07/2019 01:17 PM Analytical Method: 6.3 Std. Units 1 01/07/19 13:09 16.7 deg C 1 01/07/19 13:09 110.3 umhos/c 1 01/07/19 13:09 m 8.8 NTU 1 01/07/19 13:09 38.6 mV 1 01/07/19 13:09 5.6 mg/L 1 01/07/19 13:09 7782-44-7 N2 29.02 feet 1 01/07/19 13:09 24.09 feet 1 01/07/19 13:09 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/20/18 11:39 12/20/18 20:37 7440-36-0 ND ug/L 10.0 0.57 1 12/20/18 11:39 12/20/18 20:37 7440-38-2 26.7J ug/L 100 0.78 1 12/20/18 11:39 12/20/18 20:37 7440-39-3 ND ug/L 1.0 0.050 1 12/20/18 11:39 12/20/18 20:37 7440-41-7 ND ug/L 1.0 0.093 1 12/20/18 11:39 12/20/18 20:37 7440-43-9 55.9 ug/L 10.0 1.6 1 12/20/18 11:39 12/20/18 20:37 7440-47-3 0.60J ug/L 10.0 0.52 1 12/20/18 11:39 12/20/18 20:37 7440-48-4 3.6J ug/L 10.0 1.3 1 12/20/18 11:39 12/20/18 20:37 7440-50-8 498 ug/L 40.0 22.8 1 12/20/18 11:39 12/20/18 20:37 7439-89-6 ND ug/L 10.0 0.27 1 12/20/18 11:39 12/20/18 20:37 7439-92-1 16.6 ug/L 10.0 1.2 1 12/20/18 11:39 12/20/18 20:37 7439-96-5 15.OJ ug/L 50.0 0.95 1 12/20/18 11:39 12/20/18 20:37 7440-02-0 ND ug/L 10.0 1.4 1 12/20/18 11:39 12/20/18 20:37 7782-49-2 ND ug/L 10.0 0.95 1 12/20/18 11:39 12/20/18 20:37 7440-22-4 ND ug/L 5.5 0.14 1 12/20/18 11:39 12/20/18 20:37 7440-28-0 7.OJ ug/L 25.0 1.9 1 12/20/18 11:39 12/20/18 20:37 7440-62-2 9.5J ug/L 10.0 2.1 1 12/20/18 11:39 12/20/18 20:37 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.036 1 12/21 /18 10:25 12/21 /18 15:27 7439-97-6 Analytical Method: EPA 8260B Mod. ND ug/L 2.0 1.9 1 12/21/1819:42 123-91-1 93 % 50-150 1 12/21 /18 19:42 17060-07-0 90 % 50-150 1 12/21 /18 19:42 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/27/18 02:23 67-64-1 ND ug/L 200 2.5 1 12/27/18 02:23 107-13-1 ND ug/L 1.0 0.20 1 12/27/18 02:23 71-43-2 ND ug/L 3.0 0.50 1 12/27/18 02:23 74-97-5 ND ug/L 1.0 0.36 1 12/27/18 02:23 75-27-4 ND ug/L 3.0 0.55 1 12/27/18 02:23 75-25-2 ND ug/L 10.0 0.95 1 12/27/18 02:23 74-83-9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1s Lab ID: 2612812001 Collected: 12/17/18 15:28 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Analytical Method: EPA 8260E 2-Butanone (MEK) ND ug/L 100 3.2 1 12/27/18 02:23 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/27/18 02:23 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/27/18 02:23 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/27/18 02:23 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/27/18 02:23 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/27/18 02:23 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 12/27/18 02:23 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 12/27/18 02:23 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.31 1 12/27/18 02:23 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 12/27/18 02:23 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 12/27/18 02:23 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 12/27/18 02:23 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 12/27/18 02:23 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 12/27/18 02:23 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.41 1 12/27/18 02:23 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.67 1 12/27/18 02:23 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.72 1 12/27/18 02:23 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.66 1 12/27/18 02:23 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.46 1 12/27/18 02:23 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.60 1 12/27/18 02:23 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.22 1 12/27/18 02:23 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/27/18 02:23 10061-02-6 Ethylbenzene ND ug/L 1.0 0.45 1 12/27/18 02:23 100-41-4 2-Hexanone ND ug/L 50.0 0.89 1 12/27/18 02:23 591-78-6 lodomethane ND ug/L 10.0 3.1 1 12/27/18 02:23 74-88-4 Methylene Chloride 1.2 ug/L 1.0 0.50 1 12/27/18 02:23 75-09-2 4-Methyl-2-pentanone ND ug/L 100 0.86 1 12/27/18 02:23 108-10-1 (MIBK) Styrene ND ug/L 1.0 0.50 1 12/27/18 02:23 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.32 1 12/27/18 02:23 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.53 1 12/27/18 02:23 79-34-5 Tetrachloroethene ND ug/L 1.0 0.78 1 12/27/18 02:23 127-18-4 Tetrahydrofuran ND ug/L 10.0 1.3 1 12/27/18 02:23 109-99-9 Toluene ND ug/L 1.0 0.31 1 12/27/18 02:23 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 12/27/18 02:23 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 12/27/18 02:23 79-00-5 Trichloroethene ND ug/L 1.0 0.34 1 12/27/18 02:23 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.51 1 12/27/18 02:23 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 12/27/18 02:23 96-18-4 Vinyl acetate ND ug/L 50.0 0.42 1 12/27/18 02:23 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 12/27/18 02:23 75-01-4 Xylene (Total) ND ug/L 5.0 1.5 1 12/27/18 02:23 1330-20-7 Surrogates 1,2-Dichloroethane-d4 (S) 101 %. 81-119 1 12/27/18 02:23 17060-07-0 Dibromofluoromethane (S) 100 %. 82-114 1 12/27/18 02:23 1868-53-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /07/2019 01:17 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1s Lab ID: 2612812001 Collected: 12/17/18 15:28 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Analytical Method: EPA 8260E Surrogates 4-Bromofluorobenzene (S) 97 %. 82-120 1 12/27/18 02:23 460-00-4 Toluene-d8 (S) 101 %. 82-109 1 12/27/18 02:23 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 46000 ug/L 20000 20000 1 12/24/18 11:44 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 119000 ug/L 10000 10000 1 12/20/18 11:52 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/20/1812:00 12/20/1815:47 Demand 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/21/1811:34 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/19/18 09:00 12/24/18 12:07 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 146 ug/L 50.0 5.0 1 12/19/18 01:43 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 3720 ug/L 1000 24.0 1 12/19/18 01:43 16887-00-6 Sulfate 991J ug/L 5000 17.0 1 12/19/18 01:43 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1000 1 12/20/18 07:20 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/20/18 07:20 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/20/18 07:20 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/20/18 07:20 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/20/18 07:20 7440-44-0 Carbon Date: 01/07/2019 01:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1d Lab ID: 2612812002 Collected: 12/17/18 15:57 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water Iron, Ferrous 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Date: 01/07/2019 01:17 PM Analytical Method: 6.1 Std. Units 1 01/07/19 13:09 15.8 deg C 1 01/07/19 13:09 116.8 umhos/c 1 01/07/19 13:09 m 9.4 NTU 1 01/07/19 13:09 25.1 mV 1 01/07/19 13:09 3.6 mg/L 1 01/07/19 13:09 7782-44-7 N2 52.31 feet 1 01/07/19 13:09 27.52 feet 1 01/07/19 13:09 0.0 mg/L 1 01/07/19 13:09 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/20/18 11:39 12/20/18 20:54 7440-36-0 ND ug/L 10.0 0.57 1 12/20/18 11:39 12/20/18 20:54 7440-38-2 31.9J ug/L 100 0.78 1 12/20/18 11:39 12/20/18 20:54 7440-39-3 ND ug/L 1.0 0.050 1 12/20/18 11:39 12/20/18 20:54 7440-41-7 ND ug/L 1.0 0.093 1 12/20/18 11:39 12/20/18 20:54 7440-43-9 9.3J ug/L 10.0 1.6 1 12/20/18 11:39 12/20/18 20:54 7440-47-3 ND ug/L 10.0 0.52 1 12/20/18 11:39 12/20/18 20:54 7440-48-4 2.3J ug/L 10.0 1.3 1 12/20/18 11:39 12/20/18 20:54 7440-50-8 591 ug/L 40.0 22.8 1 12/20/18 11:39 12/20/18 20:54 7439-89-6 0.41J ug/L 10.0 0.27 1 12/20/18 11:39 12/20/18 20:54 7439-92-1 18.1 ug/L 10.0 1.2 1 12/20/18 11:39 12/20/18 20:54 7439-96-5 3.OJ ug/L 50.0 0.95 1 12/20/18 11:39 12/20/18 20:54 7440-02-0 ND ug/L 10.0 1.4 1 12/20/18 11:39 12/20/18 20:54 7782-49-2 ND ug/L 10.0 0.95 1 12/20/18 11:39 12/20/18 20:54 7440-22-4 ND ug/L 5.5 0.14 1 12/20/18 11:39 12/20/18 20:54 7440-28-0 6.8J ug/L 25.0 1.9 1 12/20/18 11:39 12/20/18 20:54 7440-62-2 4.1J ug/L 10.0 2.1 1 12/20/18 11:39 12/20/18 20:54 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.036 1 12/21 /18 10:25 12/21 /18 15:35 7439-97-6 Analytical Method: EPA 8260B Mod. ND ug/L 2.0 1.9 1 12/21/18 20:02 123-91-1 93 % 50-150 1 12/21 /18 20:02 17060-07-0 90 % 50-150 1 12/21 /18 20:02 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/27/18 02:48 67-64-1 ND ug/L 200 2.5 1 12/27/18 02:48 107-13-1 ND ug/L 1.0 0.20 1 12/27/18 02:48 71-43-2 ND ug/L 3.0 0.50 1 12/27/18 02:48 74-97-5 ND ug/L 1.0 0.36 1 12/27/18 02:48 75-27-4 ND ug/L 3.0 0.55 1 12/27/18 02:48 75-25-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1d Lab ID: 2612812002 Collected: 12/17/18 15:57 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Date: 01/07/2019 01:17 PM Analytical Method: EPA 8260E ND ug/L 10.0 0.95 1 12/27/18 02:48 74-83-9 ND ug/L 100 3.2 1 12/27/18 02:48 78-93-3 ND ug/L 100 0.79 1 12/27/18 02:48 75-15-0 ND ug/L 1.0 0.42 1 12/27/18 02:48 56-23-5 ND ug/L 3.0 0.53 1 12/27/18 02:48 108-90-7 ND ug/L 10.0 0.52 1 12/27/18 02:48 75-00-3 ND ug/L 5.0 0.58 1 12/27/18 02:48 67-66-3 ND ug/L 1.0 0.38 1 12/27/18 02:48 74-87-3 ND ug/L 13.0 0.55 1 12/27/18 02:48 96-12-8 ND ug/L 1.0 0.31 1 12/27/18 02:48 124-48-1 ND ug/L 2.0 0.28 1 12/27/18 02:48 106-93-4 ND ug/L 10.0 0.62 1 12/27/18 02:48 74-95-3 ND ug/L 5.0 0.49 1 12/27/18 02:48 95-50-1 ND ug/L 1.0 0.58 1 12/27/18 02:48 106-46-7 ND ug/L 100 1.6 1 12/27/18 02:48 110-57-6 ND ug/L 5.0 0.41 1 12/27/18 02:48 75-34-3 ND ug/L 1.0 0.67 1 12/27/18 02:48 107-06-2 ND ug/L 5.0 0.72 1 12/27/18 02:48 75-35-4 ND ug/L 5.0 0.66 1 12/27/18 02:48 156-59-2 ND ug/L 5.0 0.46 1 12/27/18 02:48 156-60-5 ND ug/L 1.0 0.60 1 12/27/18 02:48 78-87-5 ND ug/L 1.0 0.22 1 12/27/18 02:48 10061-01-5 ND ug/L 1.0 0.30 1 12/27/18 02:48 10061-02-6 ND ug/L 1.0 0.45 1 12/27/18 02:48 100-41-4 ND ug/L 50.0 0.89 1 12/27/18 02:48 591-78-6 ND ug/L 10.0 3.1 1 12/27/18 02:48 74-88-4 ND ug/L 1.0 0.50 1 12/27/18 02:48 75-09-2 ND ug/L 100 0.86 1 12/27/18 02:48 108-10-1 ND ug/L 1.0 0.50 1 12/27/18 02:48 100-42-5 ND ug/L 5.0 0.32 1 12/27/18 02:48 630-20-6 ND ug/L 1.0 0.53 1 12/27/18 02:48 79-34-5 ND ug/L 1.0 0.78 1 12/27/18 02:48 127-18-4 ND ug/L 10.0 1.3 1 12/27/18 02:48 109-99-9 ND ug/L 1.0 0.31 1 12/27/18 02:48 108-88-3 ND ug/L 1.0 0.38 1 12/27/18 02:48 71-55-6 ND ug/L 1.0 0.59 1 12/27/18 02:48 79-00-5 ND ug/L 1.0 0.34 1 12/27/18 02:48 79-01-6 ND ug/L 1.0 0.51 1 12/27/18 02:48 75-69-4 ND ug/L 1.0 0.46 1 12/27/18 02:48 96-18-4 ND ug/L 50.0 0.42 1 12/27/18 02:48 108-05-4 ND ug/L 1.0 0.60 1 12/27/18 02:48 75-01-4 ND ug/L 5.0 1.5 1 12/27/18 02:48 1330-20-7 97 %. 81-119 1 12/27/18 02:48 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County 1302-CD1s/CD1d Pace Project No.: 2612812 Sample: 1302-CD1d Lab ID: 2612812002 Collected: 12/17/18 15:57 Received: 12/18/18 10:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Analytical Method: EPA 8260E Surrogates Dibromofluoromethane (S) 100 %. 82-114 1 12/27/18 02:48 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 12/27/18 02:48 460-00-4 Toluene-d8 (S) 101 %. 82-109 1 12/27/18 02:48 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 53000 ug/L 20000 20000 1 12/24/18 11:52 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 121000 ug/L 10000 10000 1 12/20/18 11:52 9056 IC Anions Analytical Method: EPA 9056A Chloride 3110 ug/L 1000 24.0 1 12/31/1815:09 16887-00-6 Sulfate 3360J ug/L 5000 17.0 1 12/31/1815:09 14808-79-8 Date: 01/07/2019 01:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 51 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWI Lab ID: 2612903001 Collected: 12/18/18 10:30 Received: 12/19/18 10:20 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.1 Std. Units 1 01/07/19 17:05 14.8 deg C 1 01/07/19 17:05 142.7 umhos/c 1 01/07/19 17:05 m 10 NTU 1 01/07/19 17:05 -2.9 mV 1 01/07/19 17:05 4.5 mg/L 1 01/07/19 17:05 7782-44-7 N2 65.46 feet 1 01/07/19 17:05 44.29 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/20/18 11:39 12/20/18 21:00 7440-36-0 ND ug/L 10.0 0.57 1 12/20/18 11:39 12/20/18 21:00 7440-38-2 31.OJ ug/L 100 0.78 1 12/20/18 11:39 12/20/18 21:00 7440-39-3 0.23J ug/L 1.0 0.050 1 12/20/18 11:39 12/20/18 21:00 7440-41-7 0.15J ug/L 1.0 0.093 1 12/20/18 11:39 12/20/18 21:00 7440-43-9 2.3J ug/L 10.0 1.6 1 12/20/18 11:39 12/20/18 21:00 7440-47-3 ND ug/L 10.0 0.52 1 12/20/18 11:39 12/20/18 21:00 7440-48-4 ND ug/L 10.0 1.3 1 12/20/18 11:39 12/20/18 21:00 7440-50-8 0.64J ug/L 10.0 0.27 1 12/20/18 11:39 12/20/18 21:00 7439-92-1 1.6J ug/L 50.0 0.95 1 12/20/18 11:39 12/20/18 21:00 7440-02-0 ND ug/L 10.0 1.4 1 12/20/18 11:39 12/20/18 21:00 7782-49-2 ND ug/L 10.0 0.95 1 12/20/18 11:39 12/20/18 21:00 7440-22-4 ND ug/L 5.5 0.14 1 12/20/18 11:39 12/20/18 21:00 7440-28-0 3.9J ug/L 25.0 1.9 1 12/20/18 11:39 12/20/18 21:00 7440-62-2 4.6J ug/L 10.0 2.1 1 12/20/18 11:39 12/20/18 21:00 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/27/18 20:15 123-91-1 99 % 50-150 1 12/27/18 20:15 17060-07-0 97 % 50-150 1 12/27/18 20:15 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/28/18 00:31 67-64-1 ND ug/L 200 2.5 1 12/28/18 00:31 107-13-1 ND ug/L 1.0 0.20 1 12/28/18 00:31 71-43-2 ND ug/L 3.0 0.50 1 12/28/18 00:31 74-97-5 ND ug/L 1.0 0.36 1 12/28/18 00:31 75-27-4 ND ug/L 3.0 0.55 1 12/28/18 00:31 75-25-2 ND ug/L 10.0 0.95 1 12/28/18 00:31 74-83-9 ND ug/L 100 3.2 1 12/28/18 00:31 78-93-3 ND ug/L 100 0.79 1 12/28/18 00:31 75-15-0 ND ug/L 1.0 0.42 1 12/28/18 00:31 56-23-5 ND ug/L 3.0 0.53 1 12/28/18 00:31 108-90-7 ND ug/L 10.0 0.52 1 12/28/18 00:31 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWI Lab ID: 2612903001 Collected: 12/18/18 10:30 Received: 12/19/18 10:20 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/28/18 00:31 67-66-3 ND ug/L 1.0 0.38 1 12/28/18 00:31 74-87-3 ND ug/L 13.0 0.55 1 12/28/18 00:31 96-12-8 ND ug/L 1.0 0.31 1 12/28/18 00:31 124-48-1 ND ug/L 2.0 0.28 1 12/28/18 00:31 106-93-4 ND ug/L 10.0 0.62 1 12/28/18 00:31 74-95-3 ND ug/L 5.0 0.49 1 12/28/18 00:31 95-50-1 ND ug/L 1.0 0.58 1 12/28/18 00:31 106-46-7 ND ug/L 100 1.6 1 12/28/18 00:31 110-57-6 6.9 ug/L 5.0 0.41 1 12/28/18 00:31 75-34-3 ND ug/L 1.0 0.67 1 12/28/18 00:31 107-06-2 ND ug/L 5.0 0.72 1 12/28/18 00:31 75-35-4 5.2 ug/L 5.0 0.66 1 12/28/18 00:31 156-59-2 ND ug/L 5.0 0.46 1 12/28/18 00:31 156-60-5 ND ug/L 1.0 0.60 1 12/28/18 00:31 78-87-5 ND ug/L 1.0 0.22 1 12/28/18 00:31 10061-01-5 ND ug/L 1.0 0.30 1 12/28/18 00:31 10061-02-6 ND ug/L 1.0 0.45 1 12/28/18 00:31 100-41-4 ND ug/L 50.0 0.89 1 12/28/18 00:31 591-78-6 ND ug/L 10.0 3.1 1 12/28/18 00:31 74-88-4 1.1 ug/L 1.0 0.50 1 12/28/18 00:31 75-09-2 ND ug/L 100 0.86 1 12/28/18 00:31 108-10-1 ND ug/L 1.0 0.50 1 12/28/18 00:31 100-42-5 ND ug/L 5.0 0.32 1 12/28/18 00:31 630-20-6 ND ug/L 1.0 0.53 1 12/28/18 00:31 79-34-5 3.3 ug/L 1.0 0.78 1 12/28/18 00:31 127-18-4 ND ug/L 10.0 1.3 1 12/28/18 00:31 109-99-9 ND ug/L 1.0 0.31 1 12/28/18 00:31 108-88-3 ND ug/L 1.0 0.38 1 12/28/18 00:31 71-55-6 ND ug/L 1.0 0.59 1 12/28/18 00:31 79-00-5 2.1 ug/L 1.0 0.34 1 12/28/18 00:31 79-01-6 ND ug/L 1.0 0.51 1 12/28/18 00:31 75-69-4 ND ug/L 1.0 0.46 1 12/28/18 00:31 96-18-4 ND ug/L 50.0 0.42 1 12/28/18 00:31 108-05-4 ND ug/L 1.0 0.60 1 12/28/18 00:31 75-01-4 ND ug/L 5.0 1.5 1 12/28/18 00:31 1330-20-7 100 %. 81-119 1 12/28/18 00:31 17060-07-0 99 %. 82-114 1 12/28/18 00:31 1868-53-7 104 %. 82-120 1 12/28/18 00:31 460-00-4 104 %. 82-109 1 12/28/18 00:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MW1 Lab ID: 2612903002 Collected: 12/19/18 08:20 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.4 Std. Units 1 01/07/19 17:05 Field Temperature 12.9 deg C 1 01/07/19 17:05 Field Specific 1355 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 6.9 NTU 1 01/07/19 17:05 Field Oxidation Potential 224.6 mV 1 01/07/19 17:05 Oxygen, Dissolved 2.0 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 30.43 feet 1 01/07/19 17:05 Depth to Water 11.47 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1815:50 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/27/1813:38 12/31/1815:50 7440-38-2 Barium 136 ug/L 100 0.78 1 12/27/1813:38 12/31/1815:50 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 12/27/1813:38 12/31/1815:50 7440-41-7 Cadmium 0.68J ug/L 1.0 0.093 1 12/27/1813:38 12/31/1815:50 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1815:50 7440-47-3 Cobalt 12.2 ug/L 10.0 0.52 1 12/27/1813:38 12/31/1815:50 7440-48-4 Copper 6.3J ug/L 10.0 1.3 1 12/27/1813:38 12/31/1815:50 7440-50-8 Lead 0.68J ug/L 10.0 0.27 1 12/27/1813:38 12/31/1815:50 7439-92-1 Nickel 30.OJ ug/L 50.0 0.95 1 12/27/1813:38 12/31/1815:50 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1815:50 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1815:50 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1815:50 7440-28-0 Vanadium 2.6J ug/L 25.0 1.9 1 12/27/1813:38 12/31/1815:50 7440-62-2 Zinc 3.OJ ug/L 10.0 2.1 1 12/27/1813:38 12/31/1815:50 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) 72.6 ug/L 2.0 1.9 1 12/24/18 20:20 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 50-150 1 12/24/18 20:20 17060-07-0 Toluene-d8 (S) 96 % 50-150 1 12/24/18 20:20 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 11:41 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 11:41 107-13-1 R1 Benzene ND ug/L 1.0 0.20 1 12/31/18 11:41 71-43-2 R1 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 11:41 74-97-5 M1,R1 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 11:41 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 11:41 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 11:41 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 11:41 78-93-3 R1 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 11:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 11:41 56-23-5 L1,M0, R1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 11:41 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MW1 Lab ID: 2612903002 Collected: 12/19/18 08:20 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 10.0 0.52 1 12/31/1811:41 75-00-3 ND ug/L 5.0 0.58 1 12/31/1811:41 67-66-3 R1 ND ug/L 1.0 0.38 1 12/31/1811:41 74-87-3 R1 ND ug/L 13.0 0.55 1 12/31/1811:41 96-12-8 ND ug/L 1.0 0.31 1 12/31/1811:41 124-48-1 ND ug/L 2.0 0.28 1 12/31/1811:41 106-93-4 ND ug/L 10.0 0.62 1 12/31/1811:41 74-95-3 ND ug/L 5.0 0.49 1 12/31/1811:41 95-50-1 ND ug/L 1.0 0.58 1 12/31/1811:41 106-46-7 ND ug/L 100 1.6 1 12/31/1811:41 110-57-6 1.9J ug/L 5.0 0.41 1 12/31 /18 11:41 75-34-3 ND ug/L 1.0 0.67 1 12/31/1811:41 107-06-2 R1 ND ug/L 5.0 0.72 1 12/31/1811:41 75-35-4 0.74J ug/L 5.0 0.66 1 12/31/1811:41 156-59-2 R1 ND ug/L 5.0 0.46 1 12/31/1811:41 156-60-5 ND ug/L 1.0 0.60 1 12/31/1811:41 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 11:41 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 11:41 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 11:41 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 11:41 591-78-6 ND ug/L 10.0 3.1 1 12/31/1811:41 74-88-4 ND ug/L 1.0 0.50 1 12/31/1811:41 75-09-2 ND ug/L 100 0.86 1 12/31/1811:41 108-10-1 ND ug/L 1.0 0.50 1 12/31/1811:41 100-42-5 ND ug/L 5.0 0.32 1 12/31/1811:41 630-20-6 ND ug/L 1.0 0.53 1 12/31/1811:41 79-34-5 ND ug/L 1.0 0.78 1 12/31/1811:41 127-18-4 ND ug/L 10.0 1.3 1 12/31/1811:41 109-99-9 R1 ND ug/L 1.0 0.31 1 12/31/1811:41 108-88-3 ND ug/L 1.0 0.38 1 12/31/1811:41 71-55-6 R1 ND ug/L 1.0 0.59 1 12/31/1811:41 79-00-5 R1 ND ug/L 1.0 0.34 1 12/31/1811:41 79-01-6 ND ug/L 1.0 0.51 1 12/31/1811:41 75-69-4 M1 ND ug/L 1.0 0.46 1 12/31/1811:41 96-18-4 ND ug/L 50.0 0.42 1 12/31/1811:41 108-05-4 ND ug/L 1.0 0.60 1 12/31/1811:41 75-01-4 ND ug/L 5.0 1.5 1 12/31/1811:41 1330-20-7 111 %. 81-119 1 12/31/1811:41 17060-07-0 101 %. 82-114 1 12/31/1811:41 1868-53-7 106 %. 82-120 1 12/31 /18 11:41 460-00-4 99 %. 82-109 1 12/31 /18 11:41 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MW3 Lab ID: 2612903003 Collected: 12/19/18 15:48 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.0 Std. Units 1 01/07/19 17:05 15.3 deg C 1 01/07/19 17:05 178.9 umhos/c 1 01/07/19 17:05 m 7.9 NTU 1 01/07/19 17:05 48.8 mV 1 01/07/19 17:05 2.8 mg/L 1 01/07/19 17:05 7782-44-7 N2 35.40 feet 1 01/07/19 17:05 13.90 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1815:55 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1815:55 7440-38-2 31.1J ug/L 100 0.78 1 12/27/18 13:38 12/31/1815:55 7440-39-3 0.14J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1815:55 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1815:55 7440-43-9 1.8J ug/L 10.0 1.6 1 12/27/18 13:38 12/31 /18 15:55 7440-47-3 ND ug/L 10.0 0.52 1 12/27/18 13:38 12/31/1815:55 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1815:55 7440-50-8 0.31J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1815:55 7439-92-1 1.OJ ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 15:55 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1815:55 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1815:55 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1815:55 7440-28-0 2.7J ug/L 25.0 1.9 1 12/27/18 13:38 12/31 /18 15:55 7440-62-2 2.3J ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 15:55 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1815:49 123-91-1 99 % 50-150 1 12/24/1815:49 17060-07-0 95 % 50-150 1 12/24/1815:49 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1812:06 67-64-1 ND ug/L 200 2.5 1 12/31/1812:06 107-13-1 ND ug/L 1.0 0.20 1 12/31/1812:06 71-43-2 ND ug/L 3.0 0.50 1 12/31/1812:06 74-97-5 ND ug/L 1.0 0.36 1 12/31/1812:06 75-27-4 ND ug/L 3.0 0.55 1 12/31/1812:06 75-25-2 ND ug/L 10.0 0.95 1 12/31/1812:06 74-83-9 ND ug/L 100 3.2 1 12/31/1812:06 78-93-3 ND ug/L 100 0.79 1 12/31/1812:06 75-15-0 ND ug/L 1.0 0.42 1 12/31/1812:06 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1812:06 108-90-7 ND ug/L 10.0 0.52 1 12/31/1812:06 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MW3 Lab ID: 2612903003 Collected: 12/19/18 15:48 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1812:06 67-66-3 ND ug/L 1.0 0.38 1 12/31/1812:06 74-87-3 ND ug/L 13.0 0.55 1 12/31/1812:06 96-12-8 ND ug/L 1.0 0.31 1 12/31/1812:06 124-48-1 ND ug/L 2.0 0.28 1 12/31/1812:06 106-93-4 ND ug/L 10.0 0.62 1 12/31/1812:06 74-95-3 ND ug/L 5.0 0.49 1 12/31/1812:06 95-50-1 ND ug/L 1.0 0.58 1 12/31/1812:06 106-46-7 ND ug/L 100 1.6 1 12/31/1812:06 110-57-6 21.3 ug/L 5.0 0.41 1 12/31 /18 12:06 75-34-3 ND ug/L 1.0 0.67 1 12/31/1812:06 107-06-2 1.9J ug/L 5.0 0.72 1 12/31 /18 12:06 75-35-4 10.4 ug/L 5.0 0.66 1 12/31 /18 12:06 156-59-2 ND ug/L 5.0 0.46 1 12/31/1812:06 156-60-5 ND ug/L 1.0 0.60 1 12/31/1812:06 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 12:06 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 12:06 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 12:06 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 12:06 591-78-6 ND ug/L 10.0 3.1 1 12/31/1812:06 74-88-4 0.59J ug/L 1.0 0.50 1 12/31 /18 12:06 75-09-2 ND ug/L 100 0.86 1 12/31/1812:06 108-10-1 ND ug/L 1.0 0.50 1 12/31/1812:06 100-42-5 ND ug/L 5.0 0.32 1 12/31/1812:06 630-20-6 ND ug/L 1.0 0.53 1 12/31/1812:06 79-34-5 14.1 ug/L 1.0 0.78 1 12/31/1812:06 127-18-4 ND ug/L 10.0 1.3 1 12/31/1812:06 109-99-9 ND ug/L 1.0 0.31 1 12/31/1812:06 108-88-3 ND ug/L 1.0 0.38 1 12/31/1812:06 71-55-6 ND ug/L 1.0 0.59 1 12/31/1812:06 79-00-5 7.0 ug/L 1.0 0.34 1 12/31/1812:06 79-01-6 0.95J ug/L 1.0 0.51 1 12/31 /18 12:06 75-69-4 ND ug/L 1.0 0.46 1 12/31/1812:06 96-18-4 ND ug/L 50.0 0.42 1 12/31/1812:06 108-05-4 ND ug/L 1.0 0.60 1 12/31/1812:06 75-01-4 ND ug/L 5.0 1.5 1 12/31/1812:06 1330-20-7 114 %. 81-119 1 12/31/1812:06 17060-07-0 100 %. 82-114 1 12/31/1812:06 1868-53-7 108 %. 82-120 1 12/31 /18 12:06 460-00-4 103 %. 82-109 1 12/31 /18 12:06 2037-26-5 Analytical Method: SM 2320B 89000 ug/L 20000 20000 1 12/24/1811:57 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MW3 Lab ID: 2612903003 Collected: 12/19/18 15:48 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/24/1814:45 12/24/1817:39 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide 381 ug/L 200 200 1 12/21/1811:50 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/21/18 07:00 12/26/18 11:30 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 27.OJ ug/L 50.0 5.0 1 12/21/18 06:23 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 3340 ug/L 1000 24.0 1 01/02/19 20:33 16887-00-6 Sulfate 222J ug/L 5000 17.0 1 01/02/19 20:33 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 16:24 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 16:24 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 16:24 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 16:24 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/21/18 16:24 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWB Lab ID: 2612903004 Collected: 12/19/18 09:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.7 Std. Units 1 01/07/19 17:05 9.3 deg C 1 01/07/19 17:05 795 umhos/c 1 01/07/19 17:05 m 18.8 NTU 1 01/07/19 17:05 -64.8 mV 1 01/07/19 17:05 1.3 mg/L 1 01/07/19 17:05 7782-44-7 N2 15.50 feet 1 01/07/19 17:05 13.52 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1816:01 7440-36-0 0.78J ug/L 10.0 0.57 1 12/27/18 13:38 12/31 /18 16:01 7440-38-2 172 ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 16:01 7440-39-3 0.071J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1816:01 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1816:01 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1816:01 7440-47-3 9.6J ug/L 10.0 0.52 1 12/27/18 13:38 12/31 /18 16:01 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1816:01 7440-50-8 0.36J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1816:01 7439-92-1 5.5J ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 16:01 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1816:01 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1816:01 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1816:01 7440-28-0 ND ug/L 25.0 1.9 1 12/27/18 13:38 12/31/1816:01 7440-62-2 15.1 ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 16:01 7440-66-6 Analytical Method: EPA 8260E Mod. 20.3 ug/L 2.0 1.9 1 12/24/1816:09 123-91-1 100 % 50-150 1 12/24/1816:09 17060-07-0 94 % 50-150 1 12/24/1816:09 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1812:32 67-64-1 ND ug/L 200 2.5 1 12/31/1812:32 107-13-1 ND ug/L 1.0 0.20 1 12/31/1812:32 71-43-2 ND ug/L 3.0 0.50 1 12/31/1812:32 74-97-5 ND ug/L 1.0 0.36 1 12/31/1812:32 75-27-4 ND ug/L 3.0 0.55 1 12/31/1812:32 75-25-2 ND ug/L 10.0 0.95 1 12/31/1812:32 74-83-9 ND ug/L 100 3.2 1 12/31/1812:32 78-93-3 ND ug/L 100 0.79 1 12/31/1812:32 75-15-0 ND ug/L 1.0 0.42 1 12/31/1812:32 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1812:32 108-90-7 ND ug/L 10.0 0.52 1 12/31/1812:32 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWB Lab ID: 2612903004 Collected: 12/19/18 09:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1812:32 67-66-3 ND ug/L 1.0 0.38 1 12/31/1812:32 74-87-3 ND ug/L 13.0 0.55 1 12/31/1812:32 96-12-8 ND ug/L 1.0 0.31 1 12/31/1812:32 124-48-1 ND ug/L 2.0 0.28 1 12/31/1812:32 106-93-4 ND ug/L 10.0 0.62 1 12/31/1812:32 74-95-3 ND ug/L 5.0 0.49 1 12/31/1812:32 95-50-1 ND ug/L 1.0 0.58 1 12/31/1812:32 106-46-7 ND ug/L 100 1.6 1 12/31/1812:32 110-57-6 ND ug/L 5.0 0.41 1 12/31/1812:32 75-34-3 ND ug/L 1.0 0.67 1 12/31/1812:32 107-06-2 ND ug/L 5.0 0.72 1 12/31/1812:32 75-35-4 ND ug/L 5.0 0.66 1 12/31/1812:32 156-59-2 ND ug/L 5.0 0.46 1 12/31/1812:32 156-60-5 ND ug/L 1.0 0.60 1 12/31/1812:32 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 12:32 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 12:32 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 12:32 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 12:32 591-78-6 ND ug/L 10.0 3.1 1 12/31/1812:32 74-88-4 0.53J ug/L 1.0 0.50 1 12/31 /18 12:32 75-09-2 ND ug/L 100 0.86 1 12/31/1812:32 108-10-1 ND ug/L 1.0 0.50 1 12/31/1812:32 100-42-5 ND ug/L 5.0 0.32 1 12/31/1812:32 630-20-6 ND ug/L 1.0 0.53 1 12/31/1812:32 79-34-5 ND ug/L 1.0 0.78 1 12/31/1812:32 127-18-4 ND ug/L 10.0 1.3 1 12/31/1812:32 109-99-9 ND ug/L 1.0 0.31 1 12/31/1812:32 108-88-3 ND ug/L 1.0 0.38 1 12/31/1812:32 71-55-6 ND ug/L 1.0 0.59 1 12/31/1812:32 79-00-5 ND ug/L 1.0 0.34 1 12/31/1812:32 79-01-6 ND ug/L 1.0 0.51 1 12/31/1812:32 75-69-4 ND ug/L 1.0 0.46 1 12/31/1812:32 96-18-4 ND ug/L 50.0 0.42 1 12/31/1812:32 108-05-4 ND ug/L 1.0 0.60 1 12/31/1812:32 75-01-4 ND ug/L 5.0 1.5 1 12/31/1812:32 1330-20-7 104 %. 81-119 1 12/31/1812:32 17060-07-0 101 %. 82-114 1 12/31/1812:32 1868-53-7 111 %. 82-120 1 12/31 /18 12:32 460-00-4 97 %. 82-109 1 12/31 /18 12:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWC Lab ID: 2612903005 Collected: 12/19/18 10:35 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 5.8 Std. Units 1 01/07/19 17:05 12.3 deg C 1 01/07/19 17:05 102.3 umhos/c 1 01/07/19 17:05 m 11 NTU 1 01/07/19 17:05 162.6 mV 1 01/07/19 17:05 4.8 mg/L 1 01/07/19 17:05 7782-44-7 N2 17.89 feet 1 01/07/19 17:05 4.89 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1816:07 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1816:07 7440-38-2 22.OJ ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 16:07 7440-39-3 0.14J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1816:07 7440-41-7 0.11J ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1816:07 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1816:07 7440-47-3 0.97J ug/L 10.0 0.52 1 12/27/18 13:38 12/31 /18 16:07 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1816:07 7440-50-8 0.33J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1816:07 7439-92-1 1.2J ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 16:07 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1816:07 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1816:07 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1816:07 7440-28-0 ND ug/L 25.0 1.9 1 12/27/18 13:38 12/31/1816:07 7440-62-2 3.OJ ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 16:07 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1816:28 123-91-1 98 % 50-150 1 12/24/1816:28 17060-07-0 95 % 50-150 1 12/24/1816:28 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1812:57 67-64-1 ND ug/L 200 2.5 1 12/31/1812:57 107-13-1 ND ug/L 1.0 0.20 1 12/31/1812:57 71-43-2 ND ug/L 3.0 0.50 1 12/31/1812:57 74-97-5 ND ug/L 1.0 0.36 1 12/31/1812:57 75-27-4 ND ug/L 3.0 0.55 1 12/31/1812:57 75-25-2 ND ug/L 10.0 0.95 1 12/31/1812:57 74-83-9 ND ug/L 100 3.2 1 12/31/1812:57 78-93-3 ND ug/L 100 0.79 1 12/31/1812:57 75-15-0 ND ug/L 1.0 0.42 1 12/31/1812:57 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1812:57 108-90-7 ND ug/L 10.0 0.52 1 12/31/1812:57 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWC Lab ID: 2612903005 Collected: 12/19/18 10:35 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1812:57 67-66-3 ND ug/L 1.0 0.38 1 12/31/1812:57 74-87-3 ND ug/L 13.0 0.55 1 12/31/1812:57 96-12-8 ND ug/L 1.0 0.31 1 12/31/1812:57 124-48-1 ND ug/L 2.0 0.28 1 12/31/1812:57 106-93-4 ND ug/L 10.0 0.62 1 12/31/1812:57 74-95-3 ND ug/L 5.0 0.49 1 12/31/1812:57 95-50-1 ND ug/L 1.0 0.58 1 12/31/1812:57 106-46-7 ND ug/L 100 1.6 1 12/31/1812:57 110-57-6 ND ug/L 5.0 0.41 1 12/31/1812:57 75-34-3 ND ug/L 1.0 0.67 1 12/31/1812:57 107-06-2 ND ug/L 5.0 0.72 1 12/31/1812:57 75-35-4 ND ug/L 5.0 0.66 1 12/31/1812:57 156-59-2 ND ug/L 5.0 0.46 1 12/31/1812:57 156-60-5 ND ug/L 1.0 0.60 1 12/31/1812:57 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 12:57 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 12:57 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 12:57 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 12:57 591-78-6 ND ug/L 10.0 3.1 1 12/31/1812:57 74-88-4 0.67J ug/L 1.0 0.50 1 12/31 /18 12:57 75-09-2 ND ug/L 100 0.86 1 12/31/1812:57 108-10-1 ND ug/L 1.0 0.50 1 12/31/1812:57 100-42-5 ND ug/L 5.0 0.32 1 12/31/1812:57 630-20-6 ND ug/L 1.0 0.53 1 12/31/1812:57 79-34-5 ND ug/L 1.0 0.78 1 12/31/1812:57 127-18-4 ND ug/L 10.0 1.3 1 12/31/1812:57 109-99-9 ND ug/L 1.0 0.31 1 12/31/1812:57 108-88-3 ND ug/L 1.0 0.38 1 12/31/1812:57 71-55-6 ND ug/L 1.0 0.59 1 12/31/1812:57 79-00-5 ND ug/L 1.0 0.34 1 12/31/1812:57 79-01-6 ND ug/L 1.0 0.51 1 12/31/1812:57 75-69-4 ND ug/L 1.0 0.46 1 12/31/1812:57 96-18-4 ND ug/L 50.0 0.42 1 12/31/1812:57 108-05-4 ND ug/L 1.0 0.60 1 12/31/1812:57 75-01-4 ND ug/L 5.0 1.5 1 12/31/1812:57 1330-20-7 115 %. 81-119 1 12/31/1812:57 17060-07-0 109 %. 82-114 1 12/31/1812:57 1868-53-7 107 %. 82-120 1 12/31 /18 12:57 460-00-4 103 %. 82-109 1 12/31 /18 12:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWD Lab ID: 2612903006 Collected: 12/19/18 12:05 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.2 Std. Units 1 01/07/19 17:05 15.1 deg C 1 01/07/19 17:05 858 umhos/c 1 01/07/19 17:05 m 1.0 NTU 1 01/07/19 17:05 35.4 mV 1 01/07/19 17:05 1.1 mg/L 1 01/07/19 17:05 7782-44-7 N2 30.53 feet 1 01/07/19 17:05 24.58 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1816:13 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1816:13 7440-38-2 214 ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 16:13 7440-39-3 0.11J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1816:13 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1816:13 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1816:13 7440-47-3 18.6 ug/L 10.0 0.52 1 12/27/18 13:38 12/31 /18 16:13 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1816:13 7440-50-8 ND ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1816:13 7439-92-1 14.8J ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 16:13 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1816:13 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1816:13 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1816:13 7440-28-0 14.OJ ug/L 25.0 1.9 1 12/27/18 13:38 12/31 /18 16:13 7440-62-2 ND ug/L 10.0 2.1 1 12/27/18 13:38 12/31/1816:13 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1816:47 123-91-1 99 % 50-150 1 12/24/1816:47 17060-07-0 95 % 50-150 1 12/24/1816:47 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1813:22 67-64-1 ND ug/L 200 2.5 1 12/31/1813:22 107-13-1 2.7 ug/L 1.0 0.20 1 12/31/1813:22 71-43-2 ND ug/L 3.0 0.50 1 12/31/1813:22 74-97-5 ND ug/L 1.0 0.36 1 12/31/1813:22 75-27-4 ND ug/L 3.0 0.55 1 12/31/1813:22 75-25-2 ND ug/L 10.0 0.95 1 12/31/1813:22 74-83-9 ND ug/L 100 3.2 1 12/31/1813:22 78-93-3 ND ug/L 100 0.79 1 12/31/1813:22 75-15-0 ND ug/L 1.0 0.42 1 12/31/1813:22 56-23-5 L1 0.72J ug/L 3.0 0.53 1 12/31 /18 13:22 108-90-7 0.69J ug/L 10.0 0.52 1 12/31 /18 13:22 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWD Lab ID: 2612903006 Collected: 12/19/18 12:05 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1813:22 67-66-3 ND ug/L 1.0 0.38 1 12/31/1813:22 74-87-3 ND ug/L 13.0 0.55 1 12/31/1813:22 96-12-8 ND ug/L 1.0 0.31 1 12/31/1813:22 124-48-1 ND ug/L 2.0 0.28 1 12/31/1813:22 106-93-4 ND ug/L 10.0 0.62 1 12/31/1813:22 74-95-3 ND ug/L 5.0 0.49 1 12/31/1813:22 95-50-1 10.9 ug/L 1.0 0.58 1 12/31 /18 13:22 106-46-7 ND ug/L 100 1.6 1 12/31/1813:22 110-57-6 0.41J ug/L 5.0 0.41 1 12/31/1813:22 75-34-3 ND ug/L 1.0 0.67 1 12/31/1813:22 107-06-2 ND ug/L 5.0 0.72 1 12/31/1813:22 75-35-4 30.5 ug/L 5.0 0.66 1 12/31 /18 13:22 156-59-2 ND ug/L 5.0 0.46 1 12/31/1813:22 156-60-5 ND ug/L 1.0 0.60 1 12/31/1813:22 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 13:22 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 13:22 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 13:22 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 13:22 591-78-6 ND ug/L 10.0 3.1 1 12/31/1813:22 74-88-4 ND ug/L 1.0 0.50 1 12/31/1813:22 75-09-2 ND ug/L 100 0.86 1 12/31/1813:22 108-10-1 ND ug/L 1.0 0.50 1 12/31/1813:22 100-42-5 ND ug/L 5.0 0.32 1 12/31/1813:22 630-20-6 ND ug/L 1.0 0.53 1 12/31/1813:22 79-34-5 ND ug/L 1.0 0.78 1 12/31/1813:22 127-18-4 ND ug/L 10.0 1.3 1 12/31/1813:22 109-99-9 ND ug/L 1.0 0.31 1 12/31/1813:22 108-88-3 ND ug/L 1.0 0.38 1 12/31/1813:22 71-55-6 ND ug/L 1.0 0.59 1 12/31/1813:22 79-00-5 1.6 ug/L 1.0 0.34 1 12/31/1813:22 79-01-6 ND ug/L 1.0 0.51 1 12/31/1813:22 75-69-4 ND ug/L 1.0 0.46 1 12/31/1813:22 96-18-4 ND ug/L 50.0 0.42 1 12/31/1813:22 108-05-4 0.80J ug/L 1.0 0.60 1 12/31/1813:22 75-01-4 ND ug/L 5.0 1.5 1 12/31/1813:22 1330-20-7 112 %. 81-119 1 12/31/1813:22 17060-07-0 104 %. 82-114 1 12/31/1813:22 1868-53-7 108 %. 82-120 1 12/31 /18 13:22 460-00-4 102 %. 82-109 1 12/31 /18 13:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWF Lab ID: 2612903007 Collected: 12/19/18 08:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.1 Std. Units 1 01/07/19 17:05 Field Temperature 11.6 deg C 1 01/07/19 17:05 Field Specific 481.6 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 3.5 NTU 1 01/07/19 17:05 Field Oxidation Potential 11.0 mV 1 01/07/19 17:05 Oxygen, Dissolved 2.5 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 20.22 feet 1 01/07/19 17:05 Depth to Water 6.73 feet 1 01/07/19 17:05 Iron, Ferrous 5.0 mg/L 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1816:18 7440-36-0 Arsenic 0.81J ug/L 10.0 0.57 1 12/27/1813:38 12/31/1816:18 7440-38-2 Barium 103 ug/L 100 0.78 1 12/27/1813:38 12/31/1816:18 7440-39-3 Beryllium 0.10J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1816:18 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1816:18 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1816:18 7440-47-3 Cobalt 1.3J ug/L 10.0 0.52 1 12/27/1813:38 12/31/1816:18 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1816:18 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/27/1813:38 12/31/1816:18 7439-92-1 Nickel 5.8J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1816:18 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1816:18 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1816:18 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1816:18 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/27/1813:38 12/31/1816:18 7440-62-2 Zinc ND ug/L 10.0 2.1 1 12/27/1813:38 12/31/1816:18 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 01/10/2019 03:57 PM 4.3 ug/L 2.0 1.9 1 12/24/1817:07 123-91-1 100 % 50-150 1 12/24/1817:07 17060-07-0 95 % 50-150 1 12/24/1817:07 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1813:48 67-64-1 ND ug/L 200 2.5 1 12/31/1813:48 107-13-1 ND ug/L 1.0 0.20 1 12/31/1813:48 71-43-2 ND ug/L 3.0 0.50 1 12/31/1813:48 74-97-5 ND ug/L 1.0 0.36 1 12/31/1813:48 75-27-4 ND ug/L 3.0 0.55 1 12/31/1813:48 75-25-2 ND ug/L 10.0 0.95 1 12/31/1813:48 74-83-9 ND ug/L 100 3.2 1 12/31/1813:48 78-93-3 ND ug/L 100 0.79 1 12/31/1813:48 75-15-0 ND ug/L 1.0 0.42 1 12/31/1813:48 56-23-5 ND ug/L 3.0 0.53 1 12/31/1813:48 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 21 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWF Lab ID: 2612903007 Collected: 12/19/18 08:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 10.0 0.52 1 12/31/1813:48 75-00-3 ND ug/L 5.0 0.58 1 12/31/1813:48 67-66-3 ND ug/L 1.0 0.38 1 12/31/1813:48 74-87-3 ND ug/L 13.0 0.55 1 12/31/1813:48 96-12-8 ND ug/L 1.0 0.31 1 12/31/1813:48 124-48-1 ND ug/L 2.0 0.28 1 12/31/1813:48 106-93-4 ND ug/L 10.0 0.62 1 12/31/1813:48 74-95-3 ND ug/L 5.0 0.49 1 12/31/1813:48 95-50-1 ND ug/L 1.0 0.58 1 12/31/1813:48 106-46-7 ND ug/L 100 1.6 1 12/31/1813:48 110-57-6 ND ug/L 5.0 0.41 1 12/31/1813:48 75-34-3 ND ug/L 1.0 0.67 1 12/31/1813:48 107-06-2 ND ug/L 5.0 0.72 1 12/31/1813:48 75-35-4 ND ug/L 5.0 0.66 1 12/31/1813:48 156-59-2 ND ug/L 5.0 0.46 1 12/31/1813:48 156-60-5 ND ug/L 1.0 0.60 1 12/31/1813:48 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 13:48 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 13:48 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 13:48 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 13:48 591-78-6 ND ug/L 10.0 3.1 1 12/31/1813:48 74-88-4 ND ug/L 1.0 0.50 1 12/31/1813:48 75-09-2 ND ug/L 100 0.86 1 12/31/1813:48 108-10-1 ND ug/L 1.0 0.50 1 12/31/1813:48 100-42-5 ND ug/L 5.0 0.32 1 12/31/1813:48 630-20-6 ND ug/L 1.0 0.53 1 12/31/1813:48 79-34-5 ND ug/L 1.0 0.78 1 12/31/1813:48 127-18-4 ND ug/L 10.0 1.3 1 12/31/1813:48 109-99-9 ND ug/L 1.0 0.31 1 12/31/1813:48 108-88-3 ND ug/L 1.0 0.38 1 12/31/1813:48 71-55-6 ND ug/L 1.0 0.59 1 12/31/1813:48 79-00-5 ND ug/L 1.0 0.34 1 12/31/1813:48 79-01-6 ND ug/L 1.0 0.51 1 12/31/1813:48 75-69-4 ND ug/L 1.0 0.46 1 12/31/1813:48 96-18-4 ND ug/L 50.0 0.42 1 12/31/1813:48 108-05-4 ND ug/L 1.0 0.60 1 12/31/1813:48 75-01-4 ND ug/L 5.0 1.5 1 12/31/1813:48 1330-20-7 116 %. 81-119 1 12/31/1813:48 17060-07-0 105 %. 82-114 1 12/31/1813:48 1868-53-7 101 %. 82-120 1 12/31 /18 13:48 460-00-4 101 %. 82-109 1 12/31 /18 13:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWG Lab ID: 2612903008 Collected: 12/19/18 09:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.1 Std. Units 1 01/07/19 17:05 11.3 deg C 1 01/07/19 17:05 586.5 umhos/c 1 01/07/19 17:05 m 15 NTU 1 01/07/19 17:05 -2.8 mV 1 01/07/19 17:05 2.1 mg/L 1 01/07/19 17:05 7782-44-7 N2 20.44 feet 1 01/07/19 17:05 8.78 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1816:36 7440-36-0 1.4J ug/L 10.0 0.57 1 12/27/18 13:38 12/31 /18 16:36 7440-38-2 331 ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 16:36 7440-39-3 0.20J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1816:36 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1816:36 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1816:36 7440-47-3 6.1J ug/L 10.0 0.52 1 12/27/18 13:38 12/31/1816:36 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1816:36 7440-50-8 ND ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1816:36 7439-92-1 2.5J ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 16:36 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1816:36 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1816:36 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1816:36 7440-28-0 3.1J ug/L 25.0 1.9 1 12/27/18 13:38 12/31/1816:36 7440-62-2 3.8J ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 16:36 7440-66-6 Analytical Method: EPA 8260E Mod. 13.3 ug/L 2.0 1.9 1 12/24/1817:26 123-91-1 100 % 50-150 1 12/24/1817:26 17060-07-0 96 % 50-150 1 12/24/1817:26 2037-26-5 Analytical Method: EPA 8260E 8.2J ug/L 100 8.2 1 12/31 /18 14:13 67-64-1 ND ug/L 200 2.5 1 12/31/1814:13 107-13-1 ND ug/L 1.0 0.20 1 12/31/1814:13 71-43-2 ND ug/L 3.0 0.50 1 12/31/1814:13 74-97-5 ND ug/L 1.0 0.36 1 12/31/1814:13 75-27-4 ND ug/L 3.0 0.55 1 12/31/1814:13 75-25-2 ND ug/L 10.0 0.95 1 12/31/1814:13 74-83-9 ND ug/L 100 3.2 1 12/31/1814:13 78-93-3 ND ug/L 100 0.79 1 12/31/1814:13 75-15-0 ND ug/L 1.0 0.42 1 12/31/1814:13 56-23-5 L1 2.3J ug/L 3.0 0.53 1 12/31 /18 14:13 108-90-7 ND ug/L 10.0 0.52 1 12/31/1814:13 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWG Lab ID: 2612903008 Collected: 12/19/18 09:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1814:13 67-66-3 ND ug/L 1.0 0.38 1 12/31/1814:13 74-87-3 ND ug/L 13.0 0.55 1 12/31/1814:13 96-12-8 ND ug/L 1.0 0.31 1 12/31/1814:13 124-48-1 ND ug/L 2.0 0.28 1 12/31/1814:13 106-93-4 ND ug/L 10.0 0.62 1 12/31/1814:13 74-95-3 ND ug/L 5.0 0.49 1 12/31/1814:13 95-50-1 ND ug/L 1.0 0.58 1 12/31/1814:13 106-46-7 ND ug/L 100 1.6 1 12/31/1814:13 110-57-6 ND ug/L 5.0 0.41 1 12/31/1814:13 75-34-3 ND ug/L 1.0 0.67 1 12/31/1814:13 107-06-2 ND ug/L 5.0 0.72 1 12/31/1814:13 75-35-4 ND ug/L 5.0 0.66 1 12/31/1814:13 156-59-2 ND ug/L 5.0 0.46 1 12/31/1814:13 156-60-5 ND ug/L 1.0 0.60 1 12/31/1814:13 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 14:13 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 14:13 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 14:13 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 14:13 591-78-6 ND ug/L 10.0 3.1 1 12/31/1814:13 74-88-4 ND ug/L 1.0 0.50 1 12/31/1814:13 75-09-2 ND ug/L 100 0.86 1 12/31/1814:13 108-10-1 ND ug/L 1.0 0.50 1 12/31/1814:13 100-42-5 ND ug/L 5.0 0.32 1 12/31/1814:13 630-20-6 ND ug/L 1.0 0.53 1 12/31/1814:13 79-34-5 ND ug/L 1.0 0.78 1 12/31/1814:13 127-18-4 ND ug/L 10.0 1.3 1 12/31/1814:13 109-99-9 ND ug/L 1.0 0.31 1 12/31/1814:13 108-88-3 ND ug/L 1.0 0.38 1 12/31/1814:13 71-55-6 ND ug/L 1.0 0.59 1 12/31/1814:13 79-00-5 ND ug/L 1.0 0.34 1 12/31/1814:13 79-01-6 ND ug/L 1.0 0.51 1 12/31/1814:13 75-69-4 ND ug/L 1.0 0.46 1 12/31/1814:13 96-18-4 ND ug/L 50.0 0.42 1 12/31/1814:13 108-05-4 ND ug/L 1.0 0.60 1 12/31/1814:13 75-01-4 ND ug/L 5.0 1.5 1 12/31/1814:13 1330-20-7 116 %. 81-119 1 12/31/1814:13 17060-07-0 106 %. 82-114 1 12/31/1814:13 1868-53-7 105 %. 82-120 1 12/31 /18 14:13 460-00-4 102 %. 82-109 1 12/31 /18 14:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWH Parameters Results Lab ID: 2612903009 Report Units Limit Collected: MDL 12/19/18 11:00 Reg. Limit DF Received: 12/20/18 10:15 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.2 Std. Units 1 01/07/19 17:05 Field Temperature 14.1 deg C 1 01/07/19 17:05 Field Specific 165.1 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 173.8 NTU 1 01/07/19 17:05 Field Oxidation Potential -8.3 mV 1 01/07/19 17:05 Oxygen, Dissolved 5.8 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 33.08 feet 1 01/07/19 17:05 Depth to Water 26.71 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1816:41 7440-36-0 Arsenic 1.1J ug/L 10.0 0.57 1 12/27/1813:38 12/31/1816:41 7440-38-2 Barium 74.7J ug/L 100 0.78 1 12/27/1813:38 12/31/1816:41 7440-39-3 Beryllium 0.53J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1816:41 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1816:41 7440-43-9 Chromium 7.8J ug/L 10.0 1.6 1 12/27/1813:38 12/31/1816:41 7440-47-3 Cobalt 2.6J ug/L 10.0 0.52 1 12/27/1813:38 12/31/1816:41 7440-48-4 Copper 9.8J ug/L 10.0 1.3 1 12/27/1813:38 12/31/1816:41 7440-50-8 Lead 2.8J ug/L 10.0 0.27 1 12/27/1813:38 12/31/1816:41 7439-92-1 Nickel 6.6J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1816:41 7440-02-0 Selenium 1.8J ug/L 10.0 1.4 1 12/27/1813:38 12/31/1816:41 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1816:41 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1816:41 7440-28-0 Vanadium 15.OJ ug/L 25.0 1.9 1 12/27/1813:38 12/31/1816:41 7440-62-2 Zinc 17.9 ug/L 10.0 2.1 1 12/27/1813:38 12/31/1816:41 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/24/18 17:45 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 50-150 1 12/24/18 17:45 17060-07-0 Toluene-d8 (S) 94 % 50-150 1 12/24/18 17:45 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 14:39 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 14:39 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 14:39 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 14:39 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 14:39 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 14:39 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 14:39 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 14:39 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 14:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 14:39 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 14:39 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 14:39 75-00-3 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWH Lab ID: 2612903009 Collected: 12/19/18 11:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1814:39 67-66-3 ND ug/L 1.0 0.38 1 12/31/1814:39 74-87-3 ND ug/L 13.0 0.55 1 12/31/1814:39 96-12-8 ND ug/L 1.0 0.31 1 12/31/1814:39 124-48-1 ND ug/L 2.0 0.28 1 12/31/1814:39 106-93-4 ND ug/L 10.0 0.62 1 12/31/1814:39 74-95-3 ND ug/L 5.0 0.49 1 12/31/1814:39 95-50-1 ND ug/L 1.0 0.58 1 12/31/1814:39 106-46-7 ND ug/L 100 1.6 1 12/31/1814:39 110-57-6 ND ug/L 5.0 0.41 1 12/31/1814:39 75-34-3 ND ug/L 1.0 0.67 1 12/31/1814:39 107-06-2 ND ug/L 5.0 0.72 1 12/31/1814:39 75-35-4 ND ug/L 5.0 0.66 1 12/31/1814:39 156-59-2 ND ug/L 5.0 0.46 1 12/31/1814:39 156-60-5 ND ug/L 1.0 0.60 1 12/31/1814:39 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 14:39 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 14:39 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 14:39 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 14:39 591-78-6 ND ug/L 10.0 3.1 1 12/31/1814:39 74-88-4 ND ug/L 1.0 0.50 1 12/31/1814:39 75-09-2 ND ug/L 100 0.86 1 12/31/1814:39 108-10-1 ND ug/L 1.0 0.50 1 12/31/1814:39 100-42-5 ND ug/L 5.0 0.32 1 12/31/1814:39 630-20-6 ND ug/L 1.0 0.53 1 12/31/1814:39 79-34-5 ND ug/L 1.0 0.78 1 12/31/1814:39 127-18-4 ND ug/L 10.0 1.3 1 12/31/1814:39 109-99-9 ND ug/L 1.0 0.31 1 12/31/1814:39 108-88-3 ND ug/L 1.0 0.38 1 12/31/1814:39 71-55-6 ND ug/L 1.0 0.59 1 12/31/1814:39 79-00-5 ND ug/L 1.0 0.34 1 12/31/1814:39 79-01-6 ND ug/L 1.0 0.51 1 12/31/1814:39 75-69-4 ND ug/L 1.0 0.46 1 12/31/1814:39 96-18-4 ND ug/L 50.0 0.42 1 12/31/1814:39 108-05-4 ND ug/L 1.0 0.60 1 12/31/1814:39 75-01-4 ND ug/L 5.0 1.5 1 12/31/1814:39 1330-20-7 119 %. 81-119 1 12/31/1814:39 17060-07-0 109 %. 82-114 1 12/31/1814:39 1868-53-7 109 %. 82-120 1 12/31 /18 14:39 460-00-4 102 %. 82-109 1 12/31 /18 14:39 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWHdeep Lab ID: 2612903010 Collected: 12/19/18 10:50 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6..5 Std. Units 1 01/07/19 17:05 14.7 deg C 1 01/07/19 17:05 242.0 umhos/c 1 01/07/19 17:05 m 9.9 NTU 1 01/07/19 17:05 -2.6 mV 1 01/07/19 17:05 2.6 mg/L 1 01/07/19 17:05 7782-44-7 N2 59.90 feet 1 01/07/19 17:05 26.95 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1816:47 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1816:47 7440-38-2 47.4J ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 16:47 7440-39-3 0.059J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1816:47 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1816:47 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1816:47 7440-47-3 ND ug/L 10.0 0.52 1 12/27/18 13:38 12/31/1816:47 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1816:47 7440-50-8 0.29J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1816:47 7439-92-1 ND ug/L 50.0 0.95 1 12/27/18 13:38 12/31/1816:47 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1816:47 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1816:47 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1816:47 7440-28-0 3.4J ug/L 25.0 1.9 1 12/27/18 13:38 12/31 /18 16:47 7440-62-2 ND ug/L 10.0 2.1 1 12/27/18 13:38 12/31/1816:47 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1818:05 123-91-1 96 % 50-150 1 12/24/1818:05 17060-07-0 94 % 50-150 1 12/24/1818:05 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1815:04 67-64-1 ND ug/L 200 2.5 1 12/31/1815:04 107-13-1 ND ug/L 1.0 0.20 1 12/31/1815:04 71-43-2 ND ug/L 3.0 0.50 1 12/31/1815:04 74-97-5 ND ug/L 1.0 0.36 1 12/31/1815:04 75-27-4 ND ug/L 3.0 0.55 1 12/31/1815:04 75-25-2 ND ug/L 10.0 0.95 1 12/31/1815:04 74-83-9 ND ug/L 100 3.2 1 12/31/1815:04 78-93-3 ND ug/L 100 0.79 1 12/31/1815:04 75-15-0 ND ug/L 1.0 0.42 1 12/31/1815:04 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1815:04 108-90-7 ND ug/L 10.0 0.52 1 12/31/1815:04 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWHdeep Lab ID: 2612903010 Collected: 12/19/18 10:50 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1815:04 67-66-3 ND ug/L 1.0 0.38 1 12/31/1815:04 74-87-3 ND ug/L 13.0 0.55 1 12/31/1815:04 96-12-8 ND ug/L 1.0 0.31 1 12/31/1815:04 124-48-1 ND ug/L 2.0 0.28 1 12/31/1815:04 106-93-4 ND ug/L 10.0 0.62 1 12/31/1815:04 74-95-3 ND ug/L 5.0 0.49 1 12/31/1815:04 95-50-1 ND ug/L 1.0 0.58 1 12/31/1815:04 106-46-7 ND ug/L 100 1.6 1 12/31/1815:04 110-57-6 ND ug/L 5.0 0.41 1 12/31/1815:04 75-34-3 ND ug/L 1.0 0.67 1 12/31/1815:04 107-06-2 ND ug/L 5.0 0.72 1 12/31/1815:04 75-35-4 ND ug/L 5.0 0.66 1 12/31/1815:04 156-59-2 ND ug/L 5.0 0.46 1 12/31/1815:04 156-60-5 ND ug/L 1.0 0.60 1 12/31/1815:04 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 15:04 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 15:04 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 15:04 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 15:04 591-78-6 ND ug/L 10.0 3.1 1 12/31/1815:04 74-88-4 0.94J ug/L 1.0 0.50 1 12/31 /18 15:04 75-09-2 ND ug/L 100 0.86 1 12/31/1815:04 108-10-1 ND ug/L 1.0 0.50 1 12/31/1815:04 100-42-5 ND ug/L 5.0 0.32 1 12/31/1815:04 630-20-6 ND ug/L 1.0 0.53 1 12/31/1815:04 79-34-5 ND ug/L 1.0 0.78 1 12/31/1815:04 127-18-4 ND ug/L 10.0 1.3 1 12/31/1815:04 109-99-9 ND ug/L 1.0 0.31 1 12/31/1815:04 108-88-3 ND ug/L 1.0 0.38 1 12/31/1815:04 71-55-6 ND ug/L 1.0 0.59 1 12/31/1815:04 79-00-5 ND ug/L 1.0 0.34 1 12/31/1815:04 79-01-6 ND ug/L 1.0 0.51 1 12/31/1815:04 75-69-4 ND ug/L 1.0 0.46 1 12/31/1815:04 96-18-4 ND ug/L 50.0 0.42 1 12/31/1815:04 108-05-4 ND ug/L 1.0 0.60 1 12/31/1815:04 75-01-4 ND ug/L 5.0 1.5 1 12/31/1815:04 1330-20-7 117 %. 81-119 1 12/31/1815:04 17060-07-0 102 %. 82-114 1 12/31/1815:04 1868-53-7 105 %. 82-120 1 12/31 /18 15:04 460-00-4 102 %. 82-109 1 12/31 /18 15:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWJ Parameters Results Lab ID: 2612903011 Report Units Limit Collected: MDL 12/19/18 11:25 Reg. Limit DF Received: 12/20/18 10:15 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.6 Std. Units 1 01/07/19 17:05 Field Temperature 14.1 deg C 1 01/07/19 17:05 Field Specific 241.8 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 67 NTU 1 01/07/19 17:05 Field Oxidation Potential 143.7 mV 1 01/07/19 17:05 Oxygen, Dissolved 3.3 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 35.08 feet 1 01/07/19 17:05 Depth to Water 28.31 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1816:53 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/27/1813:38 12/31/1816:53 7440-38-2 Barium 16.7J ug/L 100 0.78 1 12/27/1813:38 12/31/1816:53 7440-39-3 Beryllium 0.14J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1816:53 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1816:53 7440-43-9 Chromium 2.1J ug/L 10.0 1.6 1 12/27/1813:38 12/31/1816:53 7440-47-3 Cobalt 0.91J ug/L 10.0 0.52 1 12/27/1813:38 12/31/1816:53 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1816:53 7440-50-8 Lead 1.3J ug/L 10.0 0.27 1 12/27/1813:38 12/31/1816:53 7439-92-1 Nickel 2.5J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1816:53 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1816:53 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1816:53 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1816:53 7440-28-0 Vanadium 7.2J ug/L 25.0 1.9 1 12/27/1813:38 12/31/1816:53 7440-62-2 Zinc 6.9J ug/L 10.0 2.1 1 12/27/1813:38 12/31/1816:53 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/24/18 18:24 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 50-150 1 12/24/18 18:24 17060-07-0 Toluene-d8 (S) 93 % 50-150 1 12/24/18 18:24 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 15:30 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 15:30 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 15:30 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 15:30 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 15:30 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 15:30 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 15:30 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 15:30 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 15:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 15:30 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 15:30 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 15:30 75-00-3 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWJ Lab ID: 2612903011 Collected: 12/19/18 11:25 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1815:30 67-66-3 ND ug/L 1.0 0.38 1 12/31/1815:30 74-87-3 ND ug/L 13.0 0.55 1 12/31/1815:30 96-12-8 ND ug/L 1.0 0.31 1 12/31/1815:30 124-48-1 ND ug/L 2.0 0.28 1 12/31/1815:30 106-93-4 ND ug/L 10.0 0.62 1 12/31/1815:30 74-95-3 ND ug/L 5.0 0.49 1 12/31/1815:30 95-50-1 ND ug/L 1.0 0.58 1 12/31/1815:30 106-46-7 ND ug/L 100 1.6 1 12/31/1815:30 110-57-6 ND ug/L 5.0 0.41 1 12/31/1815:30 75-34-3 ND ug/L 1.0 0.67 1 12/31/1815:30 107-06-2 ND ug/L 5.0 0.72 1 12/31/1815:30 75-35-4 ND ug/L 5.0 0.66 1 12/31/1815:30 156-59-2 ND ug/L 5.0 0.46 1 12/31/1815:30 156-60-5 ND ug/L 1.0 0.60 1 12/31/1815:30 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 15:30 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 15:30 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 15:30 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 15:30 591-78-6 ND ug/L 10.0 3.1 1 12/31/1815:30 74-88-4 ND ug/L 1.0 0.50 1 12/31/1815:30 75-09-2 ND ug/L 100 0.86 1 12/31/1815:30 108-10-1 ND ug/L 1.0 0.50 1 12/31/1815:30 100-42-5 ND ug/L 5.0 0.32 1 12/31/1815:30 630-20-6 ND ug/L 1.0 0.53 1 12/31/1815:30 79-34-5 ND ug/L 1.0 0.78 1 12/31/1815:30 127-18-4 ND ug/L 10.0 1.3 1 12/31/1815:30 109-99-9 ND ug/L 1.0 0.31 1 12/31/1815:30 108-88-3 ND ug/L 1.0 0.38 1 12/31/1815:30 71-55-6 ND ug/L 1.0 0.59 1 12/31/1815:30 79-00-5 ND ug/L 1.0 0.34 1 12/31/1815:30 79-01-6 ND ug/L 1.0 0.51 1 12/31/1815:30 75-69-4 ND ug/L 1.0 0.46 1 12/31/1815:30 96-18-4 ND ug/L 50.0 0.42 1 12/31/1815:30 108-05-4 ND ug/L 1.0 0.60 1 12/31/1815:30 75-01-4 ND ug/L 5.0 1.5 1 12/31/1815:30 1330-20-7 117 %. 81-119 1 12/31/1815:30 17060-07-0 101 %. 82-114 1 12/31/1815:30 1868-53-7 107 %. 82-120 1 12/31 /18 15:30 460-00-4 103 %. 82-109 1 12/31 /18 15:30 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWK Lab ID: 2612903012 Collected: 12/19/18 12:30 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.0 Std. Units 1 01/07/19 17:05 15.1 deg C 1 01/07/19 17:05 173.1 umhos/c 1 01/07/19 17:05 m 4.5 NTU 1 01/07/19 17:05 129.8 mV 1 01/07/19 17:05 3.9 mg/L 1 01/07/19 17:05 7782-44-7 N2 36.38 feet 1 01/07/19 17:05 22.33 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1817:16 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1817:16 7440-38-2 15.7J ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 17:16 7440-39-3 0.31J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1817:16 7440-41-7 0.12J ug/L 1.0 0.093 1 12/27/18 13:38 12/31 /18 17:16 7440-43-9 2.OJ ug/L 10.0 1.6 1 12/27/18 13:38 12/31 /18 17:16 7440-47-3 ND ug/L 10.0 0.52 1 12/27/18 13:38 12/31/1817:16 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1817:16 7440-50-8 0.49J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1817:16 7439-92-1 1.1J ug/L 50.0 0.95 1 12/27/18 13:38 12/31/1817:16 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1817:16 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1817:16 7440-22-4 0.22J ug/L 5.5 0.14 1 12/27/18 13:38 12/31 /18 17:16 7440-28-0 4.OJ ug/L 25.0 1.9 1 12/27/18 13:38 12/31 /18 17:16 7440-62-2 2.6J ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 17:16 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1818:43 123-91-1 94 % 50-150 1 12/24/1818:43 17060-07-0 92 % 50-150 1 12/24/1818:43 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1815:56 67-64-1 ND ug/L 200 2.5 1 12/31/1815:56 107-13-1 ND ug/L 1.0 0.20 1 12/31/1815:56 71-43-2 ND ug/L 3.0 0.50 1 12/31/1815:56 74-97-5 ND ug/L 1.0 0.36 1 12/31/1815:56 75-27-4 ND ug/L 3.0 0.55 1 12/31/1815:56 75-25-2 ND ug/L 10.0 0.95 1 12/31/1815:56 74-83-9 ND ug/L 100 3.2 1 12/31/1815:56 78-93-3 ND ug/L 100 0.79 1 12/31/1815:56 75-15-0 ND ug/L 1.0 0.42 1 12/31/1815:56 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1815:56 108-90-7 ND ug/L 10.0 0.52 1 12/31/1815:56 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWK Lab ID: 2612903012 Collected: 12/19/18 12:30 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1815:56 67-66-3 ND ug/L 1.0 0.38 1 12/31/1815:56 74-87-3 ND ug/L 13.0 0.55 1 12/31/1815:56 96-12-8 ND ug/L 1.0 0.31 1 12/31/1815:56 124-48-1 ND ug/L 2.0 0.28 1 12/31/1815:56 106-93-4 ND ug/L 10.0 0.62 1 12/31/1815:56 74-95-3 ND ug/L 5.0 0.49 1 12/31/1815:56 95-50-1 ND ug/L 1.0 0.58 1 12/31/1815:56 106-46-7 ND ug/L 100 1.6 1 12/31/1815:56 110-57-6 ND ug/L 5.0 0.41 1 12/31/1815:56 75-34-3 ND ug/L 1.0 0.67 1 12/31/1815:56 107-06-2 ND ug/L 5.0 0.72 1 12/31/1815:56 75-35-4 ND ug/L 5.0 0.66 1 12/31/1815:56 156-59-2 ND ug/L 5.0 0.46 1 12/31/1815:56 156-60-5 ND ug/L 1.0 0.60 1 12/31/1815:56 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 15:56 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 15:56 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 15:56 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 15:56 591-78-6 ND ug/L 10.0 3.1 1 12/31/1815:56 74-88-4 ND ug/L 1.0 0.50 1 12/31/1815:56 75-09-2 ND ug/L 100 0.86 1 12/31/1815:56 108-10-1 ND ug/L 1.0 0.50 1 12/31/1815:56 100-42-5 ND ug/L 5.0 0.32 1 12/31/1815:56 630-20-6 ND ug/L 1.0 0.53 1 12/31/1815:56 79-34-5 ND ug/L 1.0 0.78 1 12/31/1815:56 127-18-4 ND ug/L 10.0 1.3 1 12/31/1815:56 109-99-9 ND ug/L 1.0 0.31 1 12/31/1815:56 108-88-3 ND ug/L 1.0 0.38 1 12/31/1815:56 71-55-6 ND ug/L 1.0 0.59 1 12/31/1815:56 79-00-5 ND ug/L 1.0 0.34 1 12/31/1815:56 79-01-6 ND ug/L 1.0 0.51 1 12/31/1815:56 75-69-4 ND ug/L 1.0 0.46 1 12/31/1815:56 96-18-4 ND ug/L 50.0 0.42 1 12/31/1815:56 108-05-4 ND ug/L 1.0 0.60 1 12/31/1815:56 75-01-4 ND ug/L 5.0 1.5 1 12/31/1815:56 1330-20-7 120 %. 81-119 1 12/31/1815:56 17060-07-0 S3 106 %. 82-114 1 12/31/1815:56 1868-53-7 109 %. 82-120 1 12/31 /18 15:56 460-00-4 116 %. 82-109 1 12/31 /18 15:56 2037-26-5 S3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWL Lab ID: 2612903013 Collected: 12/19/18 16:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 5.8 Std. Units 1 01/07/19 17:05 12.5 deg C 1 01/07/19 17:05 86.2 umhos/c 1 01/07/19 17:05 m 2.9 NTU 1 01/07/19 17:05 100.4 mV 1 01/07/19 17:05 2.7 mg/L 1 01/07/19 17:05 7782-44-7 N2 27.26 feet 1 01/07/19 17:05 11.32 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1817:21 7440-36-0 ND ug/L 10.0 0.57 1 12/27/1813:38 12/31/1817:21 7440-38-2 34.4J ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 17:21 7440-39-3 0.079J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1817:21 7440-41-7 ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1817:21 7440-43-9 ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1817:21 7440-47-3 ND ug/L 10.0 0.52 1 12/27/1813:38 12/31/1817:21 7440-48-4 ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1817:21 7440-50-8 ND ug/L 10.0 0.27 1 12/27/1813:38 12/31/1817:21 7439-92-1 ND ug/L 50.0 0.95 1 12/27/1813:38 12/31/1817:21 7440-02-0 ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1817:21 7782-49-2 ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1817:21 7440-22-4 ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1817:21 7440-28-0 ND ug/L 25.0 1.9 1 12/27/1813:38 12/31/1817:21 7440-62-2 ND ug/L 10.0 2.1 1 12/27/1813:38 12/31/1817:21 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1819:02 123-91-1 97 % 50-150 1 12/24/1819:02 17060-07-0 92 % 50-150 1 12/24/1819:02 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1816:21 67-64-1 ND ug/L 200 2.5 1 12/31/1816:21 107-13-1 ND ug/L 1.0 0.20 1 12/31/1816:21 71-43-2 ND ug/L 3.0 0.50 1 12/31/1816:21 74-97-5 ND ug/L 1.0 0.36 1 12/31/1816:21 75-27-4 ND ug/L 3.0 0.55 1 12/31/1816:21 75-25-2 ND ug/L 10.0 0.95 1 12/31/1816:21 74-83-9 ND ug/L 100 3.2 1 12/31/1816:21 78-93-3 ND ug/L 100 0.79 1 12/31/1816:21 75-15-0 ND ug/L 1.0 0.42 1 12/31/1816:21 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1816:21 108-90-7 ND ug/L 10.0 0.52 1 12/31/1816:21 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 33 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWL Lab ID: 2612903013 Collected: 12/19/18 16:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1816:21 67-66-3 ND ug/L 1.0 0.38 1 12/31/1816:21 74-87-3 ND ug/L 13.0 0.55 1 12/31/1816:21 96-12-8 ND ug/L 1.0 0.31 1 12/31/1816:21 124-48-1 ND ug/L 2.0 0.28 1 12/31/1816:21 106-93-4 ND ug/L 10.0 0.62 1 12/31/1816:21 74-95-3 ND ug/L 5.0 0.49 1 12/31/1816:21 95-50-1 ND ug/L 1.0 0.58 1 12/31/1816:21 106-46-7 ND ug/L 100 1.6 1 12/31/1816:21 110-57-6 ND ug/L 5.0 0.41 1 12/31/1816:21 75-34-3 ND ug/L 1.0 0.67 1 12/31/1816:21 107-06-2 ND ug/L 5.0 0.72 1 12/31/1816:21 75-35-4 ND ug/L 5.0 0.66 1 12/31/1816:21 156-59-2 ND ug/L 5.0 0.46 1 12/31/1816:21 156-60-5 ND ug/L 1.0 0.60 1 12/31/1816:21 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 16:21 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 16:21 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 16:21 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 16:21 591-78-6 ND ug/L 10.0 3.1 1 12/31/1816:21 74-88-4 ND ug/L 1.0 0.50 1 12/31/1816:21 75-09-2 ND ug/L 100 0.86 1 12/31/1816:21 108-10-1 ND ug/L 1.0 0.50 1 12/31/1816:21 100-42-5 ND ug/L 5.0 0.32 1 12/31/1816:21 630-20-6 ND ug/L 1.0 0.53 1 12/31/1816:21 79-34-5 ND ug/L 1.0 0.78 1 12/31/1816:21 127-18-4 ND ug/L 10.0 1.3 1 12/31/1816:21 109-99-9 ND ug/L 1.0 0.31 1 12/31/1816:21 108-88-3 ND ug/L 1.0 0.38 1 12/31/1816:21 71-55-6 ND ug/L 1.0 0.59 1 12/31/1816:21 79-00-5 ND ug/L 1.0 0.34 1 12/31/1816:21 79-01-6 ND ug/L 1.0 0.51 1 12/31/1816:21 75-69-4 ND ug/L 1.0 0.46 1 12/31/1816:21 96-18-4 ND ug/L 50.0 0.42 1 12/31/1816:21 108-05-4 ND ug/L 1.0 0.60 1 12/31/1816:21 75-01-4 ND ug/L 5.0 1.5 1 12/31/1816:21 1330-20-7 121 %. 81-119 1 12/31/1816:21 17060-07-0 S3 114 %. 82-114 1 12/31/1816:21 1868-53-7 107 %. 82-120 1 12/31 /18 16:21 460-00-4 100 %. 82-109 1 12/31 /18 16:21 2037-26-5 Analytical Method: SM 2320B 41000 ug/L 20000 20000 1 12/24/1812:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWL Lab ID: 2612903013 Collected: 12/19/18 16:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/24/1814:45 12/24/1817:39 Demand 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:03 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/21/18 07:00 12/26/18 11:31 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 77.0 ug/L 50.0 5.0 1 12/21/18 07:05 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 2950 ug/L 1000 24.0 1 01/02/19 20:54 16887-00-6 Sulfate 988J ug/L 5000 17.0 1 01/02/19 20:54 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:16 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:16 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:16 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:16 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/21/18 17:16 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWX Parameters Results Lab ID: 2612903014 Report Units Limit Collected: MDL 12/19/18 11:00 Reg. Limit DF Received: 12/20/18 10:15 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.3 Std. Units 1 01/07/19 17:05 Field Temperature 13.6 deg C 1 01/07/19 17:05 Field Specific 185.1 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 1.4 NTU 1 01/07/19 17:05 Field Oxidation Potential 167.5 mV 1 01/07/19 17:05 Oxygen, Dissolved 3.2 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 32.29 feet 1 01/07/19 17:05 Depth to Water 9.78 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1817:27 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/27/1813:38 12/31/1817:27 7440-38-2 Barium 28.5J ug/L 100 0.78 1 12/27/1813:38 12/31/1817:27 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 12/27/1813:38 12/31/1817:27 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1817:27 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1817:27 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 12/27/1813:38 12/31/1817:27 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1817:27 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/27/1813:38 12/31/1817:27 7439-92-1 Nickel 3.2J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1817:27 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1817:27 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1817:27 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1817:27 7440-28-0 Vanadium 3.3J ug/L 25.0 1.9 1 12/27/1813:38 12/31/1817:27 7440-62-2 Zinc ND ug/L 10.0 2.1 1 12/27/1813:38 12/31/1817:27 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/24/18 19:22 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 93 % 50-150 1 12/24/18 19:22 17060-07-0 Toluene-d8 (S) 92 % 50-150 1 12/24/18 19:22 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 16:47 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 16:47 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 16:47 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 16:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 16:47 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 16:47 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 16:47 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 16:47 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 16:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 16:47 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 16:47 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 16:47 75-00-3 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWX Lab ID: 2612903014 Collected: 12/19/18 11:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1816:47 67-66-3 ND ug/L 1.0 0.38 1 12/31/1816:47 74-87-3 ND ug/L 13.0 0.55 1 12/31/1816:47 96-12-8 ND ug/L 1.0 0.31 1 12/31/1816:47 124-48-1 ND ug/L 2.0 0.28 1 12/31/1816:47 106-93-4 ND ug/L 10.0 0.62 1 12/31/1816:47 74-95-3 ND ug/L 5.0 0.49 1 12/31/1816:47 95-50-1 ND ug/L 1.0 0.58 1 12/31/1816:47 106-46-7 ND ug/L 100 1.6 1 12/31/1816:47 110-57-6 ND ug/L 5.0 0.41 1 12/31/1816:47 75-34-3 ND ug/L 1.0 0.67 1 12/31/1816:47 107-06-2 ND ug/L 5.0 0.72 1 12/31/1816:47 75-35-4 ND ug/L 5.0 0.66 1 12/31/1816:47 156-59-2 ND ug/L 5.0 0.46 1 12/31/1816:47 156-60-5 ND ug/L 1.0 0.60 1 12/31/1816:47 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 16:47 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 16:47 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 16:47 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 16:47 591-78-6 ND ug/L 10.0 3.1 1 12/31/1816:47 74-88-4 ND ug/L 1.0 0.50 1 12/31/1816:47 75-09-2 ND ug/L 100 0.86 1 12/31/1816:47 108-10-1 ND ug/L 1.0 0.50 1 12/31/1816:47 100-42-5 ND ug/L 5.0 0.32 1 12/31/1816:47 630-20-6 ND ug/L 1.0 0.53 1 12/31/1816:47 79-34-5 ND ug/L 1.0 0.78 1 12/31/1816:47 127-18-4 ND ug/L 10.0 1.3 1 12/31/1816:47 109-99-9 ND ug/L 1.0 0.31 1 12/31/1816:47 108-88-3 ND ug/L 1.0 0.38 1 12/31/1816:47 71-55-6 ND ug/L 1.0 0.59 1 12/31/1816:47 79-00-5 ND ug/L 1.0 0.34 1 12/31/1816:47 79-01-6 ND ug/L 1.0 0.51 1 12/31/1816:47 75-69-4 ND ug/L 1.0 0.46 1 12/31/1816:47 96-18-4 ND ug/L 50.0 0.42 1 12/31/1816:47 108-05-4 ND ug/L 1.0 0.60 1 12/31/1816:47 75-01-4 ND ug/L 5.0 1.5 1 12/31/1816:47 1330-20-7 109 %. 81-119 1 12/31/1816:47 17060-07-0 94 %. 82-114 1 12/31/1816:47 1868-53-7 108 %. 82-120 1 12/31 /18 16:47 460-00-4 102 %. 82-109 1 12/31 /18 16:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-CD4Rep Lab ID: 2612903015 Collected: 12/19/18 08:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 6.0 Std. Units 1 01/07/19 17:05 12.5 deg C 1 01/07/19 17:05 139.4 umhos/c 1 01/07/19 17:05 m 101.3 NTU 1 01/07/19 17:05 48.9 mV 1 01/07/19 17:05 5.3 mg/L 1 01/07/19 17:05 7782-44-7 N2 19.82 feet 1 01/07/19 17:05 7.32 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1817:44 7440-36-0 1.1J ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1817:44 7440-38-2 50.9J ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 17:44 7440-39-3 0.96J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1817:44 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1817:44 7440-43-9 4.6J ug/L 10.0 1.6 1 12/27/18 13:38 12/31 /18 17:44 7440-47-3 5.5J ug/L 10.0 0.52 1 12/27/18 13:38 12/31 /18 17:44 7440-48-4 2.6J ug/L 10.0 1.3 1 12/27/18 13:38 12/31 /18 17:44 7440-50-8 2.9J ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1817:44 7439-92-1 7.OJ ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 17:44 7440-02-0 1.4J ug/L 10.0 1.4 1 12/27/18 13:38 12/31 /18 17:44 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1817:44 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1817:44 7440-28-0 15.5J ug/L 25.0 1.9 1 12/27/18 13:38 12/31 /18 17:44 7440-62-2 11.6 ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 17:44 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/1819:41 123-91-1 96 % 50-150 1 12/24/1819:41 17060-07-0 94 % 50-150 1 12/24/1819:41 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1817:12 67-64-1 ND ug/L 200 2.5 1 12/31/1817:12 107-13-1 ND ug/L 1.0 0.20 1 12/31/1817:12 71-43-2 ND ug/L 3.0 0.50 1 12/31/1817:12 74-97-5 ND ug/L 1.0 0.36 1 12/31/1817:12 75-27-4 ND ug/L 3.0 0.55 1 12/31/1817:12 75-25-2 ND ug/L 10.0 0.95 1 12/31/1817:12 74-83-9 ND ug/L 100 3.2 1 12/31/1817:12 78-93-3 ND ug/L 100 0.79 1 12/31/1817:12 75-15-0 ND ug/L 1.0 0.42 1 12/31/1817:12 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1817:12 108-90-7 ND ug/L 10.0 0.52 1 12/31/1817:12 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-CD4Rep Lab ID: 2612903015 Collected: 12/19/18 08:10 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1817:12 67-66-3 ND ug/L 1.0 0.38 1 12/31/1817:12 74-87-3 ND ug/L 13.0 0.55 1 12/31/1817:12 96-12-8 ND ug/L 1.0 0.31 1 12/31/1817:12 124-48-1 ND ug/L 2.0 0.28 1 12/31/1817:12 106-93-4 ND ug/L 10.0 0.62 1 12/31/1817:12 74-95-3 ND ug/L 5.0 0.49 1 12/31/1817:12 95-50-1 ND ug/L 1.0 0.58 1 12/31/1817:12 106-46-7 ND ug/L 100 1.6 1 12/31/1817:12 110-57-6 ND ug/L 5.0 0.41 1 12/31/1817:12 75-34-3 ND ug/L 1.0 0.67 1 12/31/1817:12 107-06-2 ND ug/L 5.0 0.72 1 12/31/1817:12 75-35-4 ND ug/L 5.0 0.66 1 12/31/1817:12 156-59-2 ND ug/L 5.0 0.46 1 12/31/1817:12 156-60-5 ND ug/L 1.0 0.60 1 12/31/1817:12 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 17:12 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 17:12 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 17:12 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 17:12 591-78-6 ND ug/L 10.0 3.1 1 12/31/1817:12 74-88-4 ND ug/L 1.0 0.50 1 12/31/1817:12 75-09-2 ND ug/L 100 0.86 1 12/31/1817:12 108-10-1 ND ug/L 1.0 0.50 1 12/31/1817:12 100-42-5 ND ug/L 5.0 0.32 1 12/31/1817:12 630-20-6 ND ug/L 1.0 0.53 1 12/31/1817:12 79-34-5 ND ug/L 1.0 0.78 1 12/31/1817:12 127-18-4 ND ug/L 10.0 1.3 1 12/31/1817:12 109-99-9 ND ug/L 1.0 0.31 1 12/31/1817:12 108-88-3 ND ug/L 1.0 0.38 1 12/31/1817:12 71-55-6 ND ug/L 1.0 0.59 1 12/31/1817:12 79-00-5 ND ug/L 1.0 0.34 1 12/31/1817:12 79-01-6 ND ug/L 1.0 0.51 1 12/31/1817:12 75-69-4 ND ug/L 1.0 0.46 1 12/31/1817:12 96-18-4 ND ug/L 50.0 0.42 1 12/31/1817:12 108-05-4 ND ug/L 1.0 0.60 1 12/31/1817:12 75-01-4 ND ug/L 5.0 1.5 1 12/31/1817:12 1330-20-7 122 %. 81-119 1 12/31/1817:12 17060-07-0 S3 106 %. 82-114 1 12/31/1817:12 1868-53-7 107 %. 82-120 1 12/31 /18 17:12 460-00-4 103 %. 82-109 1 12/31 /18 17:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1s Lab ID: 2612903016 Collected: 12/19/18 13:03 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 5.9 Std. Units 1 01/07/19 17:05 14.5 deg C 1 01/07/19 17:05 219.2 umhos/c 1 01/07/19 17:05 m 0.4 NTU 1 01/07/19 17:05 510.5 mV 1 01/07/19 17:05 0.7 mg/L 1 01/07/19 17:05 7782-44-7 N2 67.67 feet 1 01/07/19 17:05 51.10 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/27/18 13:38 12/31/1817:50 7440-36-0 ND ug/L 10.0 0.57 1 12/27/18 13:38 12/31/1817:50 7440-38-2 86.4J ug/L 100 0.78 1 12/27/18 13:38 12/31 /18 17:50 7440-39-3 0.89J ug/L 1.0 0.050 1 12/27/18 13:38 12/31/1817:50 7440-41-7 ND ug/L 1.0 0.093 1 12/27/18 13:38 12/31/1817:50 7440-43-9 ND ug/L 10.0 1.6 1 12/27/18 13:38 12/31/1817:50 7440-47-3 ND ug/L 10.0 0.52 1 12/27/18 13:38 12/31/1817:50 7440-48-4 ND ug/L 10.0 1.3 1 12/27/18 13:38 12/31/1817:50 7440-50-8 ND ug/L 10.0 0.27 1 12/27/18 13:38 12/31/1817:50 7439-92-1 3.9J ug/L 50.0 0.95 1 12/27/18 13:38 12/31 /18 17:50 7440-02-0 ND ug/L 10.0 1.4 1 12/27/18 13:38 12/31/1817:50 7782-49-2 ND ug/L 10.0 0.95 1 12/27/18 13:38 12/31/1817:50 7440-22-4 ND ug/L 5.5 0.14 1 12/27/18 13:38 12/31/1817:50 7440-28-0 3.1J ug/L 25.0 1.9 1 12/27/18 13:38 12/31/1817:50 7440-62-2 5.9J ug/L 10.0 2.1 1 12/27/18 13:38 12/31 /18 17:50 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/24/18 20:00 123-91-1 96 % 50-150 1 12/24/18 20:00 17060-07-0 93 % 50-150 1 12/24/18 20:00 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1817:38 67-64-1 ND ug/L 200 2.5 1 12/31/1817:38 107-13-1 0.63J ug/L 1.0 0.20 1 12/31/1817:38 71-43-2 ND ug/L 3.0 0.50 1 12/31/1817:38 74-97-5 ND ug/L 1.0 0.36 1 12/31/1817:38 75-27-4 ND ug/L 3.0 0.55 1 12/31/1817:38 75-25-2 ND ug/L 10.0 0.95 1 12/31/1817:38 74-83-9 ND ug/L 100 3.2 1 12/31/1817:38 78-93-3 ND ug/L 100 0.79 1 12/31/1817:38 75-15-0 ND ug/L 1.0 0.42 1 12/31/1817:38 56-23-5 L1 ND ug/L 3.0 0.53 1 12/31/1817:38 108-90-7 0.54J ug/L 10.0 0.52 1 12/31 /18 17:38 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1s Lab ID: 2612903016 Collected: 12/19/18 13:03 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1817:38 67-66-3 ND ug/L 1.0 0.38 1 12/31/1817:38 74-87-3 ND ug/L 13.0 0.55 1 12/31/1817:38 96-12-8 ND ug/L 1.0 0.31 1 12/31/1817:38 124-48-1 ND ug/L 2.0 0.28 1 12/31/1817:38 106-93-4 ND ug/L 10.0 0.62 1 12/31/1817:38 74-95-3 ND ug/L 5.0 0.49 1 12/31/1817:38 95-50-1 ND ug/L 1.0 0.58 1 12/31/1817:38 106-46-7 ND ug/L 100 1.6 1 12/31/1817:38 110-57-6 5.7 ug/L 5.0 0.41 1 12/31 /18 17:38 75-34-3 ND ug/L 1.0 0.67 1 12/31/1817:38 107-06-2 ND ug/L 5.0 0.72 1 12/31/1817:38 75-35-4 6.9 ug/L 5.0 0.66 1 12/31 /18 17:38 156-59-2 ND ug/L 5.0 0.46 1 12/31/1817:38 156-60-5 ND ug/L 1.0 0.60 1 12/31/1817:38 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 17:38 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 17:38 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 17:38 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 17:38 591-78-6 ND ug/L 10.0 3.1 1 12/31/1817:38 74-88-4 1.6 ug/L 1.0 0.50 1 12/31 /18 17:38 75-09-2 ND ug/L 100 0.86 1 12/31/1817:38 108-10-1 ND ug/L 1.0 0.50 1 12/31/1817:38 100-42-5 ND ug/L 5.0 0.32 1 12/31/1817:38 630-20-6 ND ug/L 1.0 0.53 1 12/31/1817:38 79-34-5 1.6 ug/L 1.0 0.78 1 12/31/1817:38 127-18-4 ND ug/L 10.0 1.3 1 12/31/1817:38 109-99-9 ND ug/L 1.0 0.31 1 12/31/1817:38 108-88-3 ND ug/L 1.0 0.38 1 12/31/1817:38 71-55-6 ND ug/L 1.0 0.59 1 12/31/1817:38 79-00-5 1.7 ug/L 1.0 0.34 1 12/31/1817:38 79-01-6 ND ug/L 1.0 0.51 1 12/31/1817:38 75-69-4 ND ug/L 1.0 0.46 1 12/31/1817:38 96-18-4 ND ug/L 50.0 0.42 1 12/31/1817:38 108-05-4 ND ug/L 1.0 0.60 1 12/31/1817:38 75-01-4 ND ug/L 5.0 1.5 1 12/31/1817:38 1330-20-7 113 %. 81-119 1 12/31/1817:38 17060-07-0 104 %. 82-114 1 12/31/1817:38 1868-53-7 108 %. 82-120 1 12/31 /18 17:38 460-00-4 103 %. 82-109 1 12/31 /18 17:38 2037-26-5 Analytical Method: SM 2320B 115000 ug/L 20000 20000 1 12/24/1812:07 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1s Lab ID: 2612903016 Collected: 12/19/18 13:03 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/24/1814:45 12/24/1817:39 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:03 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 2280 ug/L 2000 2000 1 12/21/18 07:00 12/26/18 11:31 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 36.OJ ug/L 50.0 5.0 1 12/21/18 07:25 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 3570 ug/L 1000 24.0 1 01/02/19 21:14 16887-00-6 Sulfate 291J ug/L 5000 17.0 1 01/02/19 21:14 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:37 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:37 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:37 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 17:37 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/21/18 17:37 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1d Parameters Results Lab ID: 2612903017 Report Units Limit Collected: MDL 12/19/18 13:21 Reg. Limit DF Received: 12/20/18 10:15 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.0 Std. Units 1 01/07/19 17:05 Field Temperature 14.6 deg C 1 01/07/19 17:05 Field Specific 411.6 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 10.1 NTU 1 01/07/19 17:05 Field Oxidation Potential 1.8 mV 1 01/07/19 17:05 Oxygen, Dissolved 0.5 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 96.80 feet 1 01/07/19 17:05 Depth to Water 51.75 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1817:56 7440-36-0 Arsenic 0.71J ug/L 10.0 0.57 1 12/27/1813:38 12/31/1817:56 7440-38-2 Barium 127 ug/L 100 0.78 1 12/27/1813:38 12/31/1817:56 7440-39-3 Beryllium 0.16J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1817:56 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1817:56 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1817:56 7440-47-3 Cobalt 6.6J ug/L 10.0 0.52 1 12/27/1813:38 12/31/1817:56 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1817:56 7440-50-8 Lead 0.31J ug/L 10.0 0.27 1 12/27/1813:38 12/31/1817:56 7439-92-1 Nickel 10.1J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1817:56 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1817:56 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1817:56 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1817:56 7440-28-0 Vanadium 2.2J ug/L 25.0 1.9 1 12/27/1813:38 12/31/1817:56 7440-62-2 Zinc 5.OJ ug/L 10.0 2.1 1 12/27/1813:38 12/31/1817:56 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/27/18 20:34 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 100 % 50-150 1 12/27/18 20:34 17060-07-0 Toluene-d8 (S) 97 % 50-150 1 12/27/18 20:34 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 18:03 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 18:03 107-13-1 Benzene 1.7 ug/L 1.0 0.20 1 12/31/18 18:03 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 18:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 18:03 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 18:03 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 18:03 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 18:03 78-93-3 Carbon disulfide 1.1J ug/L 100 0.79 1 12/31/18 18:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 18:03 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 18:03 108-90-7 Chloroethane 2.2J ug/L 10.0 0.52 1 12/31/18 18:03 75-00-3 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 43 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1d Lab ID: 2612903017 Collected: 12/19/18 13:21 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1818:03 67-66-3 ND ug/L 1.0 0.38 1 12/31/1818:03 74-87-3 ND ug/L 13.0 0.55 1 12/31/1818:03 96-12-8 ND ug/L 1.0 0.31 1 12/31/1818:03 124-48-1 ND ug/L 2.0 0.28 1 12/31/1818:03 106-93-4 ND ug/L 10.0 0.62 1 12/31/1818:03 74-95-3 ND ug/L 5.0 0.49 1 12/31/1818:03 95-50-1 1.7 ug/L 1.0 0.58 1 12/31 /18 18:03 106-46-7 ND ug/L 100 1.6 1 12/31/1818:03 110-57-6 24.4 ug/L 5.0 0.41 1 12/31 /18 18:03 75-34-3 ND ug/L 1.0 0.67 1 12/31/1818:03 107-06-2 0.79J ug/L 5.0 0.72 1 12/31 /18 18:03 75-35-4 13.0 ug/L 5.0 0.66 1 12/31 /18 18:03 156-59-2 ND ug/L 5.0 0.46 1 12/31/1818:03 156-60-5 ND ug/L 1.0 0.60 1 12/31/1818:03 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 18:03 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1818:03 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1818:03 100-41-4 ND ug/L 50.0 0.89 1 12/31/1818:03 591-78-6 ND ug/L 10.0 3.1 1 12/31/1818:03 74-88-4 0.51J ug/L 1.0 0.50 1 12/31/1818:03 75-09-2 ND ug/L 100 0.86 1 12/31/1818:03 108-10-1 ND ug/L 1.0 0.50 1 12/31/1818:03 100-42-5 ND ug/L 5.0 0.32 1 12/31/1818:03 630-20-6 ND ug/L 1.0 0.53 1 12/31/1818:03 79-34-5 ND ug/L 1.0 0.78 1 12/31/1818:03 127-18-4 ND ug/L 10.0 1.3 1 12/31/1818:03 109-99-9 ND ug/L 1.0 0.31 1 12/31/1818:03 108-88-3 ND ug/L 1.0 0.38 1 12/31/1818:03 71-55-6 ND ug/L 1.0 0.59 1 12/31/1818:03 79-00-5 5.2 ug/L 1.0 0.34 1 12/31/1818:03 79-01-6 ND ug/L 1.0 0.51 1 12/31/1818:03 75-69-4 ND ug/L 1.0 0.46 1 12/31/1818:03 96-18-4 ND ug/L 50.0 0.42 1 12/31/1818:03 108-05-4 3.1 ug/L 1.0 0.60 1 12/31/1818:03 75-01-4 ND ug/L 5.0 1.5 1 12/31/1818:03 1330-20-7 123 %. 81-119 1 12/31/1818:03 17060-07-0 SO 104 %. 82-114 1 12/31/1818:03 1868-53-7 106 %. 82-120 1 12/31 /18 18:03 460-00-4 101 %. 82-109 1 12/31 /18 18:03 2037-26-5 Analytical Method: SM 2320B 202000 ug/L 20000 20000 1 12/24/1812:12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW1d Lab ID: 2612903017 Collected: 12/19/18 13:21 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/24/1814:45 12/24/1817:39 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:04 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/21/18 07:00 12/26/18 11:33 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 17.OJ ug/L 50.0 5.0 1 12/21/18 07:46 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 7180 ug/L 1000 24.0 1 12/21/18 07:46 16887-00-6 Sulfate 573J ug/L 5000 17.0 1 12/21/18 07:46 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 1040 ug/L 1000 1000 1 12/21/18 17:59 7440-44-0 Total Organic Carbon 1040 ug/L 1000 1000 1 12/21/18 17:59 7440-44-0 Total Organic Carbon 1020 ug/L 1000 1000 1 12/21/18 17:59 7440-44-0 Total Organic Carbon 1000 ug/L 1000 1000 1 12/21/18 17:59 7440-44-0 Mean Total Organic 1020 ug/L 1000 1000 1 12/21/18 17:59 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 157 11!;a'ceAna1j&a1" WNW'pecalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-DUP2/3 Lab ID: 2612903018 Collected: 12/19/18 08:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1818:01 7440-36-0 Arsenic 1.OJ ug/L 10.0 0.57 1 12/27/1813:38 12/31/1818:01 7440-38-2 Barium 107 ug/L 100 0.78 1 12/27/1813:38 12/31/1818:01 7440-39-3 Beryllium 0.10J ug/L 1.0 0.050 1 12/27/1813:38 12/31/1818:01 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1818:01 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1818:01 7440-47-3 Cobalt 1.3J ug/L 10.0 0.52 1 12/27/1813:38 12/31/1818:01 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1818:01 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/27/1813:38 12/31/1818:01 7439-92-1 Nickel 6.1J ug/L 50.0 0.95 1 12/27/1813:38 12/31/1818:01 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1818:01 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1818:01 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1818:01 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/27/1813:38 12/31/1818:01 7440-62-2 Zinc ND ug/L 10.0 2.1 1 12/27/1813:38 12/31/1818:01 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) 3.6 ug/L 2.0 1.9 1 12/27/18 20:53 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 102 % 50-150 1 12/27/18 20:53 17060-07-0 Toluene-d8 (S) 97 % 50-150 1 12/27/18 20:53 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 18:28 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 18:28 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 18:28 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 18:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 18:28 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 18:28 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 18:28 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 18:28 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 18:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 18:28 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 18:28 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 18:28 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/31/18 18:28 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 12/31/18 18:28 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 12/31/18 18:28 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.31 1 12/31/18 18:28 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 12/31/18 18:28 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 12/31/18 18:28 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 12/31/18 18:28 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 12/31/18 18:28 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 12/31/18 18:28 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-DUP2/3 Lab ID: 2612903018 Collected: 12/19/18 08:45 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 12/31/1818:28 75-34-3 ND ug/L 1.0 0.67 1 12/31/1818:28 107-06-2 ND ug/L 5.0 0.72 1 12/31/1818:28 75-35-4 ND ug/L 5.0 0.66 1 12/31/1818:28 156-59-2 ND ug/L 5.0 0.46 1 12/31/1818:28 156-60-5 ND ug/L 1.0 0.60 1 12/31/1818:28 78-87-5 ND ug/L 1.0 0.22 1 12/31/1818:28 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1818:28 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1818:28 100-41-4 ND ug/L 50.0 0.89 1 12/31/1818:28 591-78-6 ND ug/L 10.0 3.1 1 12/31/1818:28 74-88-4 0.80J ug/L 1.0 0.50 1 12/31 /18 18:28 75-09-2 ND ug/L 100 0.86 1 12/31/1818:28 108-10-1 ND ug/L 1.0 0.50 1 12/31/1818:28 100-42-5 ND ug/L 5.0 0.32 1 12/31/1818:28 630-20-6 ND ug/L 1.0 0.53 1 12/31/1818:28 79-34-5 ND ug/L 1.0 0.78 1 12/31/1818:28 127-18-4 ND ug/L 10.0 1.3 1 12/31/1818:28 109-99-9 ND ug/L 1.0 0.31 1 12/31/1818:28 108-88-3 ND ug/L 1.0 0.38 1 12/31/1818:28 71-55-6 ND ug/L 1.0 0.59 1 12/31/1818:28 79-00-5 ND ug/L 1.0 0.34 1 12/31/1818:28 79-01-6 ND ug/L 1.0 0.51 1 12/31/1818:28 75-69-4 ND ug/L 1.0 0.46 1 12/31/1818:28 96-18-4 ND ug/L 50.0 0.42 1 12/31/1818:28 108-05-4 ND ug/L 1.0 0.60 1 12/31/1818:28 75-01-4 ND ug/L 5.0 1.5 1 12/31/1818:28 1330-20-7 116 %. 81-119 1 12/31/1818:28 17060-07-0 103 %. 82-114 1 12/31/1818:28 1868-53-7 110 %. 82-120 1 12/31 /18 18:28 460-00-4 101 %. 82-109 1 12/31 /18 18:28 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 47 of 157 11!;a'ceAna1j&a1" WNW'pecalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-EQBlank2/3 Lab ID: 2612903019 Collected: 12/19/18 16:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/27/1813:38 12/31/1818:13 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/27/1813:38 12/31/1818:13 7440-38-2 Barium ND ug/L 100 0.78 1 12/27/1813:38 12/31/1818:13 7440-39-3 Beryllium ND ug/L 1.0 0.050 1 12/27/1813:38 12/31/1818:13 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/27/1813:38 12/31/1818:13 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/27/1813:38 12/31/1818:13 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 12/27/1813:38 12/31/1818:13 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/27/1813:38 12/31/1818:13 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/27/1813:38 12/31/1818:13 7439-92-1 Nickel ND ug/L 50.0 0.95 1 12/27/1813:38 12/31/1818:13 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/27/1813:38 12/31/1818:13 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/27/1813:38 12/31/1818:13 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/27/1813:38 12/31/1818:13 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/27/1813:38 12/31/1818:13 7440-62-2 Zinc ND ug/L 10.0 2.1 1 12/27/1813:38 12/31/1818:13 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/27/18 21:13 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 50-150 1 12/27/18 21:13 17060-07-0 Toluene-d8 (S) 95 % 50-150 1 12/27/18 21:13 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 11:15 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 11:15 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 11:15 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 11:15 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 11:15 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 11:15 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 11:15 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 11:15 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 11:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 11:15 56-23-5 L1 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 11:15 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 11:15 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/31/18 11:15 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 12/31/18 11:15 74-87-3 1,2-Dibromo-3- ND ug/L 13.0 0.55 1 12/31/18 11:15 96-12-8 chloropropane Dibromochloromethane ND ug/L 1.0 0.31 1 12/31/18 11:15 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 12/31/18 11:15 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 12/31/18 11:15 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 12/31/18 11:15 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 12/31/18 11:15 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 12/31/18 11:15 110-57-6 butene REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-EQBlank2/3 Lab ID: 2612903019 Collected: 12/19/18 16:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.41 1 12/31/1811:15 75-34-3 ND ug/L 1.0 0.67 1 12/31/1811:15 107-06-2 ND ug/L 5.0 0.72 1 12/31/1811:15 75-35-4 ND ug/L 5.0 0.66 1 12/31/1811:15 156-59-2 ND ug/L 5.0 0.46 1 12/31/1811:15 156-60-5 ND ug/L 1.0 0.60 1 12/31/1811:15 78-87-5 ND ug/L 1.0 0.22 1 12/31/1811:15 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1811:15 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1811:15 100-41-4 ND ug/L 50.0 0.89 1 12/31/1811:15 591-78-6 ND ug/L 10.0 3.1 1 12/31/1811:15 74-88-4 5.2 ug/L 1.0 0.50 1 12/31 /18 11:15 75-09-2 ND ug/L 100 0.86 1 12/31/1811:15 108-10-1 ND ug/L 1.0 0.50 1 12/31/1811:15 100-42-5 ND ug/L 5.0 0.32 1 12/31/1811:15 630-20-6 ND ug/L 1.0 0.53 1 12/31/1811:15 79-34-5 ND ug/L 1.0 0.78 1 12/31/1811:15 127-18-4 ND ug/L 10.0 1.3 1 12/31/1811:15 109-99-9 ND ug/L 1.0 0.31 1 12/31/1811:15 108-88-3 ND ug/L 1.0 0.38 1 12/31/1811:15 71-55-6 ND ug/L 1.0 0.59 1 12/31/1811:15 79-00-5 ND ug/L 1.0 0.34 1 12/31/1811:15 79-01-6 ND ug/L 1.0 0.51 1 12/31/1811:15 75-69-4 ND ug/L 1.0 0.46 1 12/31/1811:15 96-18-4 ND ug/L 50.0 0.42 1 12/31/1811:15 108-05-4 ND ug/L 1.0 0.60 1 12/31/1811:15 75-01-4 ND ug/L 5.0 1.5 1 12/31/1811:15 1330-20-7 108 %. 81-119 1 12/31/1811:15 17060-07-0 97 %. 82-114 1 12/31/1811:15 1868-53-7 106 %. 82-120 1 12/31 /18 11:15 460-00-4 101 %. 82-109 1 12/31 /18 11:15 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-Trip Blank Lab ID: 2612903020 Collected: 12/19/18 00:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/27/1812:11 123-91-1 97 % 50-150 1 12/27/1812:11 17060-07-0 96 % 50-150 1 12/27/1812:11 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 01/02/1912:34 67-64-1 ND ug/L 200 2.5 1 01/02/1912:34 107-13-1 ND ug/L 1.0 0.20 1 01/02/1912:34 71-43-2 ND ug/L 3.0 0.50 1 01/02/1912:34 74-97-5 ND ug/L 1.0 0.36 1 01/02/1912:34 75-27-4 ND ug/L 3.0 0.55 1 01/02/1912:34 75-25-2 ND ug/L 10.0 0.95 1 01/02/1912:34 74-83-9 ND ug/L 100 3.2 1 01/02/1912:34 78-93-3 ND ug/L 100 0.79 1 01/02/1912:34 75-15-0 ND ug/L 1.0 0.42 1 01/02/1912:34 56-23-5 ND ug/L 3.0 0.53 1 01/02/1912:34 108-90-7 ND ug/L 10.0 0.52 1 01/02/1912:34 75-00-3 ND ug/L 5.0 0.58 1 01/02/1912:34 67-66-3 ND ug/L 1.0 0.38 1 01/02/1912:34 74-87-3 ND ug/L 13.0 0.55 1 01/02/1912:34 96-12-8 ND ug/L 1.0 0.31 1 01/02/1912:34 124-48-1 ND ug/L 2.0 0.28 1 01/02/1912:34 106-93-4 ND ug/L 10.0 0.62 1 01/02/1912:34 74-95-3 ND ug/L 5.0 0.49 1 01/02/1912:34 95-50-1 ND ug/L 1.0 0.58 1 01/02/1912:34 106-46-7 ND ug/L 100 1.6 1 01/02/1912:34 110-57-6 ND ug/L 5.0 0.41 1 01/02/1912:34 75-34-3 ND ug/L 1.0 0.67 1 01/02/1912:34 107-06-2 ND ug/L 5.0 0.72 1 01/02/1912:34 75-35-4 ND ug/L 5.0 0.66 1 01/02/1912:34 156-59-2 ND ug/L 5.0 0.46 1 01/02/1912:34 156-60-5 ND ug/L 1.0 0.60 1 01/02/1912:34 78-87-5 ND ug/L 1.0 0.22 1 01/02/1912:34 10061-01-5 ND ug/L 1.0 0.30 1 01/02/1912:34 10061-02-6 ND ug/L 1.0 0.45 1 01/02/1912:34 100-41-4 ND ug/L 50.0 0.89 1 01/02/1912:34 591-78-6 ND ug/L 10.0 3.1 1 01/02/1912:34 74-88-4 1.OJ ug/L 1.0 0.50 1 01/02/1912:34 75-09-2 ND ug/L 100 0.86 1 01/02/1912:34 108-10-1 ND ug/L 1.0 0.50 1 01/02/1912:34 100-42-5 ND ug/L 5.0 0.32 1 01/02/1912:34 630-20-6 ND ug/L 1.0 0.53 1 01/02/1912:34 79-34-5 ND ug/L 1.0 0.78 1 01/02/1912:34 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 50 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-Trip Blank Lab ID: 2612903020 Collected: 12/19/18 00:00 Received: 12/20/18 10:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Analytical Method: EPA 8260E Tetrahydrofuran ND ug/L 10.0 1.3 1 01/02/19 12:34 109-99-9 Toluene ND ug/L 1.0 0.31 1 01/02/19 12:34 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 01/02/19 12:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 01/02/19 12:34 79-00-5 Trichloroethene ND ug/L 1.0 0.34 1 01/02/19 12:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.51 1 01/02/19 12:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 01/02/19 12:34 96-18-4 Vinyl acetate ND ug/L 50.0 0.42 1 01/02/19 12:34 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 01/02/19 12:34 75-01-4 Xylene (Total) ND ug/L 5.0 1.5 1 01/02/19 12:34 1330-20-7 Surrogates 1,2-Dichloroethane-d4 (S) 116 %. 81-119 1 01/02/19 12:34 17060-07-0 Dibromofluoromethane (S) 104 %. 82-114 1 01/02/19 12:34 1868-53-7 4-Bromofluorobenzene (S) 124 %. 82-120 1 01/02/19 12:34 460-00-4 S3 Toluene-d8 (S) 101 %. 82-109 1 01/02/19 12:34 2037-26-5 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWA Lab ID: 2612903021 Collected: 12/20/18 10:35 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Total Well Depth Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 01/10/2019 03:57 PM Analytical Method: 5.7 Std. Units 1 01/07/19 17:05 9.3 deg C 1 01/07/19 17:05 372.4 umhos/c 1 01/07/19 17:05 m 0.8 NTU 1 01/07/19 17:05 32.4 mV 1 01/07/19 17:05 0.6 mg/L 1 01/07/19 17:05 7782-44-7 N2 50.58 feet 1 01/07/19 17:05 43.35 feet 1 01/07/19 17:05 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.78 1 12/31/1812:22 01/02/1917:53 7440-36-0 ND ug/L 10.0 0.57 1 12/31/1812:22 01/02/1917:53 7440-38-2 52.3J ug/L 100 0.78 1 12/31/1812:22 01/02/1917:53 7440-39-3 0.090J ug/L 1.0 0.050 1 12/31/1812:22 01/02/1917:53 7440-41-7 ND ug/L 1.0 0.093 1 12/31/1812:22 01/02/1917:53 7440-43-9 ND ug/L 10.0 1.6 1 12/31/1812:22 01/02/1917:53 7440-47-3 5.5J ug/L 10.0 0.52 1 12/31/1812:22 01/02/1917:53 7440-48-4 ND ug/L 10.0 1.3 1 12/31/1812:22 01/02/1917:53 7440-50-8 ND ug/L 10.0 0.27 1 12/31/1812:22 01/02/1917:53 7439-92-1 16.8J ug/L 50.0 0.95 1 12/31/1812:22 01/02/1917:53 7440-02-0 ND ug/L 10.0 1.4 1 12/31/1812:22 01/02/1917:53 7782-49-2 ND ug/L 10.0 0.95 1 12/31/1812:22 01/02/1917:53 7440-22-4 ND ug/L 5.5 0.14 1 12/31/1812:22 01/02/1917:53 7440-28-0 ND ug/L 25.0 1.9 1 12/31/1812:22 01/02/1917:53 7440-62-2 2.9J ug/L 10.0 2.1 1 12/31/1812:22 01/02/1917:53 7440-66-6 Analytical Method: EPA 8260E Mod. ND ug/L 2.0 1.9 1 12/28/1812:30 123-91-1 104 % 50-150 1 12/28/1812:30 17060-07-0 99 % 50-150 1 12/28/1812:30 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1816:33 67-64-1 ND ug/L 200 2.5 1 12/31/1816:33 107-13-1 11.0 ug/L 1.0 0.20 1 12/31/1816:33 71-43-2 ND ug/L 3.0 0.50 1 12/31/1816:33 74-97-5 ND ug/L 1.0 0.36 1 12/31/1816:33 75-27-4 ND ug/L 3.0 0.55 1 12/31/1816:33 75-25-2 ND ug/L 10.0 0.95 1 12/31/1816:33 74-83-9 ND ug/L 100 3.2 1 12/31/1816:33 78-93-3 ND ug/L 100 0.79 1 12/31/1816:33 75-15-0 ND ug/L 1.0 0.42 1 12/31/1816:33 56-23-5 1.4J ug/L 3.0 0.53 1 12/31 /18 16:33 108-90-7 4.2J ug/L 10.0 0.52 1 12/31 /18 16:33 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWA Lab ID: 2612903021 Collected: 12/20/18 10:35 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1816:33 67-66-3 ND ug/L 1.0 0.38 1 12/31/1816:33 74-87-3 ND ug/L 13.0 0.55 1 12/31/1816:33 96-12-8 ND ug/L 1.0 0.31 1 12/31/1816:33 124-48-1 ND ug/L 2.0 0.28 1 12/31/1816:33 106-93-4 ND ug/L 10.0 0.62 1 12/31/1816:33 74-95-3 ND ug/L 5.0 0.49 1 12/31/1816:33 95-50-1 20.3 ug/L 1.0 0.58 1 12/31 /18 16:33 106-46-7 ND ug/L 100 1.6 1 12/31/1816:33 110-57-6 13.3 ug/L 5.0 0.41 1 12/31 /18 16:33 75-34-3 1.7 ug/L 1.0 0.67 1 12/31 /18 16:33 107-06-2 ND ug/L 5.0 0.72 1 12/31/1816:33 75-35-4 133 ug/L 5.0 0.66 1 12/31 /18 16:33 156-59-2 0.52J ug/L 5.0 0.46 1 12/31 /18 16:33 156-60-5 2.1 ug/L 1.0 0.60 1 12/31 /18 16:33 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 16:33 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1816:33 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1816:33 100-41-4 ND ug/L 50.0 0.89 1 12/31/1816:33 591-78-6 ND ug/L 10.0 3.1 1 12/31/1816:33 74-88-4 ND ug/L 1.0 0.50 1 12/31/1816:33 75-09-2 ND ug/L 100 0.86 1 12/31/1816:33 108-10-1 ND ug/L 1.0 0.50 1 12/31/1816:33 100-42-5 ND ug/L 5.0 0.32 1 12/31/1816:33 630-20-6 ND ug/L 1.0 0.53 1 12/31/1816:33 79-34-5 3.1 ug/L 1.0 0.78 1 12/31/1816:33 127-18-4 ND ug/L 10.0 1.3 1 12/31/1816:33 109-99-9 ND ug/L 1.0 0.31 1 12/31/1816:33 108-88-3 ND ug/L 1.0 0.38 1 12/31/1816:33 71-55-6 ND ug/L 1.0 0.59 1 12/31/1816:33 79-00-5 2.8 ug/L 1.0 0.34 1 12/31/1816:33 79-01-6 ND ug/L 1.0 0.51 1 12/31/1816:33 75-69-4 ND ug/L 1.0 0.46 1 12/31/1816:33 96-18-4 ND ug/L 50.0 0.42 1 12/31/1816:33 108-05-4 ND ug/L 1.0 0.60 1 12/31/1816:33 75-01-4 2.6J ug/L 5.0 1.5 1 12/31 /18 16:33 1330-20-7 104 %. 81-119 1 12/31/1816:33 17060-07-0 103 %. 82-114 1 12/31/1816:33 1868-53-7 98 %. 82-120 1 12/31 /18 16:33 460-00-4 99 %. 82-109 1 12/31 /18 16:33 2037-26-5 Analytical Method: SM 2320B 135000 ug/L 20000 20000 1 12/24/1813:59 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWA Parameters Lab ID: 2612903021 Collected: Report Results Units Limit MDL 12/20/18 10:35 Received: 12/21/18 11:00 Matrix: Water Reg. Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/28/1811:45 12/28/1815:19 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide 2030 ug/L 2000 2000 10 12/24/1814:10 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 8060 ug/L 2940 2940 2 12/21/18 17:00 12/26/18 12:19 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 19.OJ ug/L 50.0 5.0 1 12/22/18 09:25 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 23900 ug/L 1000 24.0 1 12/22/18 09:25 16887-00-6 Sulfate 12400 ug/L 5000 17.0 1 12/22/18 09:25 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 2150 ug/L 1000 1000 1 12/21/18 19:45 7440-44-0 Total Organic Carbon 2090 ug/L 1000 1000 1 12/21/18 19:45 7440-44-0 Total Organic Carbon 2060 ug/L 1000 1000 1 12/21/18 19:45 7440-44-0 Total Organic Carbon 2070 ug/L 1000 1000 1 12/21/18 19:45 7440-44-0 Mean Total Organic 2090 ug/L 1000 1000 1 12/21/18 19:45 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWE Rep Lab ID: 2612903022 Collected: 12/20/18 11:44 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.2 Std. Units 1 01/07/19 17:05 Field Temperature 13.4 deg C 1 01/07/19 17:05 Field Specific 1012 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 4.1 NTU 1 01/07/19 17:05 Field Oxidation Potential -16.1 mV 1 01/07/19 17:05 Oxygen, Dissolved 0.3 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 41.83 feet 1 01/07/19 17:05 Depth to Water 28.92 feet 1 01/07/19 17:05 Iron, Ferrous 6.0 mg/L 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/31/1812:22 01/02/1917:58 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/31/1812:22 01/02/1917:58 7440-38-2 Barium 321 ug/L 100 0.78 1 12/31/1812:22 01/02/1917:58 7440-39-3 Beryllium 0.11J ug/L 1.0 0.050 1 12/31/1812:22 01/02/1917:58 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/31/1812:22 01/02/1917:58 7440-43-9 Chromium ND ug/L 10.0 1.6 1 12/31/1812:22 01/02/1917:58 7440-47-3 Cobalt 7.1J ug/L 10.0 0.52 1 12/31/1812:22 01/02/1917:58 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/31/1812:22 01/02/1917:58 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/31/1812:22 01/02/1917:58 7439-92-1 Nickel 13.1J ug/L 50.0 0.95 1 12/31/1812:22 01/02/1917:58 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/31/1812:22 01/02/1917:58 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/31/1812:22 01/02/1917:58 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/31/1812:22 01/02/1917:58 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/31/1812:22 01/02/1917:58 7440-62-2 Zinc ND ug/L 10.0 2.1 1 12/31/1812:22 01/02/1917:58 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 01/10/2019 03:57 PM 2.0 ug/L 2.0 1.9 1 12/28/1812:50 123-91-1 105 % 50-150 1 12/28/1812:50 17060-07-0 97 % 50-150 1 12/28/1812:50 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1817:03 67-64-1 ND ug/L 200 2.5 1 12/31/1817:03 107-13-1 0.66J ug/L 1.0 0.20 1 12/31/1817:03 71-43-2 ND ug/L 3.0 0.50 1 12/31/1817:03 74-97-5 ND ug/L 1.0 0.36 1 12/31/1817:03 75-27-4 ND ug/L 3.0 0.55 1 12/31/1817:03 75-25-2 ND ug/L 10.0 0.95 1 12/31/1817:03 74-83-9 ND ug/L 100 3.2 1 12/31/1817:03 78-93-3 ND ug/L 100 0.79 1 12/31/1817:03 75-15-0 ND ug/L 1.0 0.42 1 12/31/1817:03 56-23-5 3.8 ug/L 3.0 0.53 1 12/31 /18 17:03 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 55 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWE Rep Lab ID: 2612903022 Collected: 12/20/18 11:44 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E 6.3J ug/L 10.0 0.52 1 12/31 /18 17:03 75-00-3 ND ug/L 5.0 0.58 1 12/31/1817:03 67-66-3 ND ug/L 1.0 0.38 1 12/31/1817:03 74-87-3 ND ug/L 13.0 0.55 1 12/31/1817:03 96-12-8 ND ug/L 1.0 0.31 1 12/31/1817:03 124-48-1 ND ug/L 2.0 0.28 1 12/31/1817:03 106-93-4 ND ug/L 10.0 0.62 1 12/31/1817:03 74-95-3 ND ug/L 5.0 0.49 1 12/31/1817:03 95-50-1 12.3 ug/L 1.0 0.58 1 12/31 /18 17:03 106-46-7 ND ug/L 100 1.6 1 12/31/1817:03 110-57-6 2.6J ug/L 5.0 0.41 1 12/31 /18 17:03 75-34-3 ND ug/L 1.0 0.67 1 12/31/1817:03 107-06-2 ND ug/L 5.0 0.72 1 12/31/1817:03 75-35-4 22.1 ug/L 5.0 0.66 1 12/31 /18 17:03 156-59-2 0.53J ug/L 5.0 0.46 1 12/31 /18 17:03 156-60-5 0.81J ug/L 1.0 0.60 1 12/31/1817:03 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 17:03 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1817:03 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1817:03 100-41-4 ND ug/L 50.0 0.89 1 12/31/1817:03 591-78-6 ND ug/L 10.0 3.1 1 12/31/1817:03 74-88-4 ND ug/L 1.0 0.50 1 12/31/1817:03 75-09-2 ND ug/L 100 0.86 1 12/31/1817:03 108-10-1 ND ug/L 1.0 0.50 1 12/31/1817:03 100-42-5 ND ug/L 5.0 0.32 1 12/31/1817:03 630-20-6 ND ug/L 1.0 0.53 1 12/31/1817:03 79-34-5 ND ug/L 1.0 0.78 1 12/31/1817:03 127-18-4 ND ug/L 10.0 1.3 1 12/31/1817:03 109-99-9 ND ug/L 1.0 0.31 1 12/31/1817:03 108-88-3 ND ug/L 1.0 0.38 1 12/31/1817:03 71-55-6 ND ug/L 1.0 0.59 1 12/31/1817:03 79-00-5 ND ug/L 1.0 0.34 1 12/31/1817:03 79-01-6 ND ug/L 1.0 0.51 1 12/31/1817:03 75-69-4 ND ug/L 1.0 0.46 1 12/31/1817:03 96-18-4 ND ug/L 50.0 0.42 1 12/31/1817:03 108-05-4 3.6 ug/L 1.0 0.60 1 12/31/1817:03 75-01-4 ND ug/L 5.0 1.5 1 12/31/1817:03 1330-20-7 103 %. 81-119 1 12/31/1817:03 17060-07-0 100 %. 82-114 1 12/31/1817:03 1868-53-7 99 %. 82-120 1 12/31 /18 17:03 460-00-4 98 %. 82-109 1 12/31 /18 17:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 56 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWE Rep Lab ID: 2612903022 Collected: 12/20/18 11:44 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 495000 ug/L 20000 20000 1 12/24/18 14:08 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/28/1811:45 12/28/1815:20 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:06 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 3590 ug/L 2000 2000 1 12/21/18 17:00 12/26/18 12:20 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 17.OJ ug/L 50.0 5.0 1 12/22/18 10:28 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 49000 ug/L 1000 24.0 1 01/03/19 06:53 16887-00-6 M1 Sulfate 6810 ug/L 5000 17.0 1 01/03/19 06:53 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 3910 ug/L 1000 1000 1 12/21/18 20:03 7440-44-0 Total Organic Carbon 3810 ug/L 1000 1000 1 12/21/18 20:03 7440-44-0 Total Organic Carbon 3720 ug/L 1000 1000 1 12/21/18 20:03 7440-44-0 Total Organic Carbon 3690 ug/L 1000 1000 1 12/21/18 20:03 7440-44-0 Mean Total Organic 3780 ug/L 1000 1000 1 12/21/18 20:03 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 57 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWEdeep Lab ID: 2612903023 Collected: 12/20/18 13:31 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.3 Std. Units 1 01/07/19 17:05 Field Temperature 11.6 deg C 1 01/07/19 17:05 Field Specific 1031 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 4.3 NTU 1 01/07/19 17:05 Field Oxidation Potential -56.2 mV 1 01/07/19 17:05 Oxygen, Dissolved 0.4 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 59.92 feet 1 01/07/19 17:05 Depth to Water 32.18 feet 1 01/07/19 17:05 Iron, Ferrous 6.0 mg/L 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/31/1812:22 01/02/1918:04 7440-36-0 Arsenic 1.3J ug/L 10.0 0.57 1 12/31/1812:22 01/02/1918:04 7440-38-2 Barium 2640 ug/L 500 3.9 5 12/31/1812:22 01/03/1914:46 7440-39-3 Beryllium 0.26J ug/L 1.0 0.050 1 12/31/1812:22 01/02/1918:04 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/31/1812:22 01/02/1918:04 7440-43-9 Chromium 1.6J ug/L 10.0 1.6 1 12/31/1812:22 01/02/1918:04 7440-47-3 Cobalt 39.1 ug/L 10.0 0.52 1 12/31/1812:22 01/02/1918:04 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/31/1812:22 01/02/1918:04 7440-50-8 Lead 6.7J ug/L 10.0 0.27 1 12/31/1812:22 01/02/1918:04 7439-92-1 Nickel 21.2J ug/L 50.0 0.95 1 12/31/1812:22 01/02/1918:04 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/31/1812:22 01/02/1918:04 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/31/1812:22 01/02/1918:04 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/31/1812:22 01/02/1918:04 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/31/1812:22 01/02/1918:04 7440-62-2 Zinc 5.2J ug/L 10.0 2.1 1 12/31/1812:22 01/02/1918:04 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 01/10/2019 03:57 PM 6.9 ug/L 2.0 1.9 1 12/28/1813:09 123-91-1 104 % 50-150 1 12/28/1813:09 17060-07-0 99 % 50-150 1 12/28/1813:09 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1817:33 67-64-1 ND ug/L 200 2.5 1 12/31/1817:33 107-13-1 1.3 ug/L 1.0 0.20 1 12/31/1817:33 71-43-2 ND ug/L 3.0 0.50 1 12/31/1817:33 74-97-5 ND ug/L 1.0 0.36 1 12/31/1817:33 75-27-4 ND ug/L 3.0 0.55 1 12/31/1817:33 75-25-2 ND ug/L 10.0 0.95 1 12/31/1817:33 74-83-9 ND ug/L 100 3.2 1 12/31/1817:33 78-93-3 ND ug/L 100 0.79 1 12/31/1817:33 75-15-0 ND ug/L 1.0 0.42 1 12/31/1817:33 56-23-5 1.5J ug/L 3.0 0.53 1 12/31 /18 17:33 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWEdeep Lab ID: 2612903023 Collected: 12/20/18 13:31 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E 13.5 ug/L 10.0 0.52 1 12/31 /18 17:33 75-00-3 ND ug/L 5.0 0.58 1 12/31/1817:33 67-66-3 ND ug/L 1.0 0.38 1 12/31/1817:33 74-87-3 ND ug/L 13.0 0.55 1 12/31/1817:33 96-12-8 ND ug/L 1.0 0.31 1 12/31/1817:33 124-48-1 ND ug/L 2.0 0.28 1 12/31/1817:33 106-93-4 ND ug/L 10.0 0.62 1 12/31/1817:33 74-95-3 ND ug/L 5.0 0.49 1 12/31/1817:33 95-50-1 6.4 ug/L 1.0 0.58 1 12/31 /18 17:33 106-46-7 ND ug/L 100 1.6 1 12/31/1817:33 110-57-6 ND ug/L 5.0 0.41 1 12/31/1817:33 75-34-3 0.94J ug/L 1.0 0.67 1 12/31 /18 17:33 107-06-2 ND ug/L 5.0 0.72 1 12/31/1817:33 75-35-4 ND ug/L 5.0 0.66 1 12/31/1817:33 156-59-2 ND ug/L 5.0 0.46 1 12/31/1817:33 156-60-5 0.61J ug/L 1.0 0.60 1 12/31/1817:33 78-87-5 ND ug/L 1.0 0.22 1 12/31/1817:33 10061-01-5 ND ug/L 1.0 0.30 1 12/31/1817:33 10061-02-6 ND ug/L 1.0 0.45 1 12/31/1817:33 100-41-4 ND ug/L 50.0 0.89 1 12/31/1817:33 591-78-6 ND ug/L 10.0 3.1 1 12/31/1817:33 74-88-4 ND ug/L 1.0 0.50 1 12/31/1817:33 75-09-2 ND ug/L 100 0.86 1 12/31/1817:33 108-10-1 ND ug/L 1.0 0.50 1 12/31/1817:33 100-42-5 ND ug/L 5.0 0.32 1 12/31/1817:33 630-20-6 ND ug/L 1.0 0.53 1 12/31/1817:33 79-34-5 ND ug/L 1.0 0.78 1 12/31/1817:33 127-18-4 2.3J ug/L 10.0 1.3 1 12/31 /18 17:33 109-99-9 0.35J ug/L 1.0 0.31 1 12/31 /18 17:33 108-88-3 ND ug/L 1.0 0.38 1 12/31/1817:33 71-55-6 ND ug/L 1.0 0.59 1 12/31/1817:33 79-00-5 ND ug/L 1.0 0.34 1 12/31/1817:33 79-01-6 ND ug/L 1.0 0.51 1 12/31/1817:33 75-69-4 ND ug/L 1.0 0.46 1 12/31/1817:33 96-18-4 ND ug/L 50.0 0.42 1 12/31/1817:33 108-05-4 ND ug/L 1.0 0.60 1 12/31/1817:33 75-01-4 ND ug/L 5.0 1.5 1 12/31/1817:33 1330-20-7 102 %. 81-119 1 12/31/1817:33 17060-07-0 101 %. 82-114 1 12/31/1817:33 1868-53-7 100 %. 82-120 1 12/31 /18 17:33 460-00-4 97 %. 82-109 1 12/31 /18 17:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-MWEdeep Parameters Lab ID: 2612903023 Collected: Report Results Units Limit MDL 12/20/18 13:31 Received: 12/21/18 11:00 Matrix: Water Reg. Limit DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 451000 ug/L 20000 20000 1 12/24/18 14:16 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen 30300 ug/L 10000 10000 1 12/28/1811:45 12/28/1815:20 Demand 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:07 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 7590 ug/L 6310 6310 4.29 12/21/18 17:00 12/26/18 12:21 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 17.OJ ug/L 50.0 5.0 1 12/22/18 11:32 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 56200 ug/L 20000 480 20 01/10/1914:56 16887-00-6 Sulfate ND ug/L 5000 17.0 1 01/03/19 07:55 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 5650 ug/L 1000 1000 1 12/21/18 20:24 7440-44-0 Total Organic Carbon 5410 ug/L 1000 1000 1 12/21/18 20:24 7440-44-0 Total Organic Carbon 5000 ug/L 1000 1000 1 12/21/18 20:24 7440-44-0 Total Organic Carbon 5280 ug/L 1000 1000 1 12/21/18 20:24 7440-44-0 Mean Total Organic 5340 ug/L 1000 1000 1 12/21/18 20:24 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2s Parameters Results Lab ID: 2612903024 Report Units Limit Collected: MDL 12/20/18 11:51 Reg. Limit DF Received: 12/21/18 11:00 Matrix: Water Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.8 Std. Units 1 01/07/19 17:05 Field Temperature 13.7 deg C 1 01/07/19 17:05 Field Specific 144.3 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 2.1 NTU 1 01/07/19 17:05 Field Oxidation Potential 101.3 mV 1 01/07/19 17:05 Oxygen, Dissolved 2.9 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 40.07 feet 1 01/07/19 17:05 Depth to Water 23.09 feet 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/31/1812:22 01/02/1918:10 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 12/31/1812:22 01/02/1918:10 7440-38-2 Barium 39.OJ ug/L 100 0.78 1 12/31/1812:22 01/02/1918:10 7440-39-3 Beryllium 0.39J ug/L 1.0 0.050 1 12/31/1812:22 01/02/1918:10 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/31/1812:22 01/02/1918:10 7440-43-9 Chromium 9.8J ug/L 10.0 1.6 1 12/31/1812:22 01/02/1918:10 7440-47-3 Cobalt ND ug/L 10.0 0.52 1 12/31/1812:22 01/02/1918:10 7440-48-4 Copper ND ug/L 10.0 1.3 1 12/31/1812:22 01/02/1918:10 7440-50-8 Lead ND ug/L 10.0 0.27 1 12/31/1812:22 01/02/1918:10 7439-92-1 Nickel 3.7J ug/L 50.0 0.95 1 12/31/1812:22 01/02/1918:10 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/31/1812:22 01/02/1918:10 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/31/1812:22 01/02/1918:10 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/31/1812:22 01/02/1918:10 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 12/31/1812:22 01/02/1918:10 7440-62-2 Zinc 5.8J ug/L 10.0 2.1 1 12/31/1812:22 01/02/1918:10 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.9 1 12/28/18 13:28 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 101 % 50-150 1 12/28/18 13:28 17060-07-0 Toluene-d8 (S) 99 % 50-150 1 12/28/18 13:28 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/31/18 18:02 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/31/18 18:02 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/31/18 18:02 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/31/18 18:02 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/31/18 18:02 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/31/18 18:02 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/31/18 18:02 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/31/18 18:02 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/31/18 18:02 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/31/18 18:02 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/31/18 18:02 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/31/18 18:02 75-00-3 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 61 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2s Lab ID: 2612903024 Collected: 12/20/18 11:51 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E ND ug/L 5.0 0.58 1 12/31/1818:02 67-66-3 ND ug/L 1.0 0.38 1 12/31/1818:02 74-87-3 ND ug/L 13.0 0.55 1 12/31/1818:02 96-12-8 ND ug/L 1.0 0.31 1 12/31/1818:02 124-48-1 ND ug/L 2.0 0.28 1 12/31/1818:02 106-93-4 ND ug/L 10.0 0.62 1 12/31/1818:02 74-95-3 ND ug/L 5.0 0.49 1 12/31/1818:02 95-50-1 ND ug/L 1.0 0.58 1 12/31/1818:02 106-46-7 ND ug/L 100 1.6 1 12/31/1818:02 110-57-6 5.5 ug/L 5.0 0.41 1 12/31 /18 18:02 75-34-3 ND ug/L 1.0 0.67 1 12/31/1818:02 107-06-2 ND ug/L 5.0 0.72 1 12/31/1818:02 75-35-4 5.3 ug/L 5.0 0.66 1 12/31 /18 18:02 156-59-2 ND ug/L 5.0 0.46 1 12/31/1818:02 156-60-5 ND ug/L 1.0 0.60 1 12/31/1818:02 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 18:02 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 18:02 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 18:02 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 18:02 591-78-6 ND ug/L 10.0 3.1 1 12/31/1818:02 74-88-4 ND ug/L 1.0 0.50 1 12/31/1818:02 75-09-2 ND ug/L 100 0.86 1 12/31/1818:02 108-10-1 ND ug/L 1.0 0.50 1 12/31/1818:02 100-42-5 ND ug/L 5.0 0.32 1 12/31/1818:02 630-20-6 ND ug/L 1.0 0.53 1 12/31/1818:02 79-34-5 1.8 ug/L 1.0 0.78 1 12/31/1818:02 127-18-4 ND ug/L 10.0 1.3 1 12/31/1818:02 109-99-9 ND ug/L 1.0 0.31 1 12/31/1818:02 108-88-3 ND ug/L 1.0 0.38 1 12/31/1818:02 71-55-6 ND ug/L 1.0 0.59 1 12/31/1818:02 79-00-5 1.8 ug/L 1.0 0.34 1 12/31/1818:02 79-01-6 ND ug/L 1.0 0.51 1 12/31/1818:02 75-69-4 ND ug/L 1.0 0.46 1 12/31/1818:02 96-18-4 ND ug/L 50.0 0.42 1 12/31/1818:02 108-05-4 ND ug/L 1.0 0.60 1 12/31/1818:02 75-01-4 ND ug/L 5.0 1.5 1 12/31/1818:02 1330-20-7 103 %. 81-119 1 12/31/1818:02 17060-07-0 99 %. 82-114 1 12/31/1818:02 1868-53-7 97 %. 82-120 1 12/31 /18 18:02 460-00-4 99 %. 82-109 1 12/31 /18 18:02 2037-26-5 Analytical Method: SM 2320B 71000 ug/L 20000 20000 1 12/24/1814:24 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2s Parameters Lab ID: 2612903024 Collected: Report Results Units Limit MDL 12/20/18 11:51 Received: 12/21/18 11:00 Matrix: Water Reg. Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/28/1811:45 12/28/1815:20 Demand 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 200 1 12/24/1814:07 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/21/18 17:00 12/26/18 12:21 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 452 ug/L 50.0 5.0 1 12/22/18 10:49 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 3220 ug/L 1000 24.0 1 01/03/19 08:15 16887-00-6 Sulfate 797J ug/L 5000 17.0 1 01/03/19 08:15 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 1310 ug/L 1000 1000 1 12/21/18 20:47 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 20:47 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 20:47 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 20:47 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/21/18 20:47 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 63 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2d Lab ID: 2612903025 Collected: 12/20/18 12:34 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.0 Std. Units 1 01/07/19 17:05 Field Temperature 13.2 deg C 1 01/07/19 17:05 Field Specific 274.3 umhos/c 1 01/07/19 17:05 Conductance m Field Turbidity 0.2 NTU 1 01/07/19 17:05 Field Oxidation Potential 65.3 mV 1 01/07/19 17:05 Oxygen, Dissolved 0.9 mg/L 1 01/07/19 17:05 7782-44-7 N2 Total Well Depth 62.80 feet 1 01/07/19 17:05 Depth to Water 23.55 feet 1 01/07/19 17:05 Iron, Ferrous 1.5 mg/L 1 01/07/19 17:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 01/02/19 09:37 01/02/19 17:53 7440-36-0 Arsenic ND ug/L 10.0 0.57 1 01/02/19 09:37 01/02/19 17:53 7440-38-2 Barium 75.3J ug/L 100 0.78 1 01/02/19 09:37 01/02/19 17:53 7440-39-3 Beryllium 0.20J ug/L 1.0 0.050 1 01/02/19 09:37 01/02/19 17:53 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 01/02/19 09:37 01/02/19 17:53 7440-43-9 Chromium ND ug/L 10.0 1.6 1 01/02/19 09:37 01/02/19 17:53 7440-47-3 Cobalt 0.58J ug/L 10.0 0.52 1 01/02/19 09:37 01/02/19 17:53 7440-48-4 Copper ND ug/L 10.0 1.3 1 01/02/19 09:37 01/02/19 17:53 7440-50-8 Lead ND ug/L 10.0 0.27 1 01/02/19 09:37 01/02/19 17:53 7439-92-1 Nickel 4.1J ug/L 50.0 0.95 1 01/02/19 09:37 01/02/19 17:53 7440-02-0 Selenium ND ug/L 10.0 1.4 1 01/02/19 09:37 01/02/19 17:53 7782-49-2 Silver ND ug/L 10.0 0.95 1 01/02/19 09:37 01/02/19 17:53 7440-22-4 Thallium ND ug/L 5.5 0.14 1 01/02/19 09:37 01/02/19 17:53 7440-28-0 Vanadium ND ug/L 25.0 1.9 1 01/02/19 09:37 01/02/19 17:53 7440-62-2 Zinc ND ug/L 10.0 2.1 1 01/02/19 09:37 01/02/19 17:53 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 01/10/2019 03:57 PM ND ug/L 2.0 1.9 1 12/28/1813:48 123-91-1 103 % 50-150 1 12/28/1813:48 17060-07-0 99 % 50-150 1 12/28/1813:48 2037-26-5 Analytical Method: EPA 8260E ND ug/L 100 8.2 1 12/31/1818:32 67-64-1 ND ug/L 200 2.5 1 12/31/1818:32 107-13-1 0.77J ug/L 1.0 0.20 1 12/31/1818:32 71-43-2 ND ug/L 3.0 0.50 1 12/31/1818:32 74-97-5 ND ug/L 1.0 0.36 1 12/31/1818:32 75-27-4 ND ug/L 3.0 0.55 1 12/31/1818:32 75-25-2 ND ug/L 10.0 0.95 1 12/31/1818:32 74-83-9 ND ug/L 100 3.2 1 12/31/1818:32 78-93-3 ND ug/L 100 0.79 1 12/31/1818:32 75-15-0 ND ug/L 1.0 0.42 1 12/31/1818:32 56-23-5 ND ug/L 3.0 0.53 1 12/31/1818:32 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2d Lab ID: 2612903025 Collected: 12/20/18 12:34 Received: 12/21/18 11:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Tetrahydrofuran Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/10/2019 03:57 PM Analytical Method: EPA 8260E 0.72J ug/L 10.0 0.52 1 12/31 /18 18:32 75-00-3 ND ug/L 5.0 0.58 1 12/31/1818:32 67-66-3 ND ug/L 1.0 0.38 1 12/31/1818:32 74-87-3 ND ug/L 13.0 0.55 1 12/31/1818:32 96-12-8 ND ug/L 1.0 0.31 1 12/31/1818:32 124-48-1 ND ug/L 2.0 0.28 1 12/31/1818:32 106-93-4 ND ug/L 10.0 0.62 1 12/31/1818:32 74-95-3 ND ug/L 5.0 0.49 1 12/31/1818:32 95-50-1 1.0 ug/L 1.0 0.58 1 12/31 /18 18:32 106-46-7 ND ug/L 100 1.6 1 12/31/1818:32 110-57-6 22.3 ug/L 5.0 0.41 1 12/31 /18 18:32 75-34-3 ND ug/L 1.0 0.67 1 12/31/1818:32 107-06-2 ND ug/L 5.0 0.72 1 12/31/1818:32 75-35-4 17.8 ug/L 5.0 0.66 1 12/31 /18 18:32 156-59-2 ND ug/L 5.0 0.46 1 12/31/1818:32 156-60-5 ND ug/L 1.0 0.60 1 12/31/1818:32 78-87-5 ND ug/L 1.0 0.22 1 12/31 /18 18:32 10061-01-5 ND ug/L 1.0 0.30 1 12/31 /18 18:32 10061-02-6 ND ug/L 1.0 0.45 1 12/31 /18 18:32 100-41-4 ND ug/L 50.0 0.89 1 12/31 /18 18:32 591-78-6 ND ug/L 10.0 3.1 1 12/31/1818:32 74-88-4 ND ug/L 1.0 0.50 1 12/31/1818:32 75-09-2 ND ug/L 100 0.86 1 12/31/1818:32 108-10-1 ND ug/L 1.0 0.50 1 12/31/1818:32 100-42-5 ND ug/L 5.0 0.32 1 12/31/1818:32 630-20-6 ND ug/L 1.0 0.53 1 12/31/1818:32 79-34-5 4.2 ug/L 1.0 0.78 1 12/31/1818:32 127-18-4 ND ug/L 10.0 1.3 1 12/31/1818:32 109-99-9 ND ug/L 1.0 0.31 1 12/31/1818:32 108-88-3 ND ug/L 1.0 0.38 1 12/31/1818:32 71-55-6 ND ug/L 1.0 0.59 1 12/31/1818:32 79-00-5 6.8 ug/L 1.0 0.34 1 12/31/1818:32 79-01-6 ND ug/L 1.0 0.51 1 12/31/1818:32 75-69-4 ND ug/L 1.0 0.46 1 12/31/1818:32 96-18-4 ND ug/L 50.0 0.42 1 12/31/1818:32 108-05-4 ND ug/L 1.0 0.60 1 12/31/1818:32 75-01-4 ND ug/L 5.0 1.5 1 12/31/1818:32 1330-20-7 104 %. 81-119 1 12/31/1818:32 17060-07-0 100 %. 82-114 1 12/31/1818:32 1868-53-7 101 %. 82-120 1 12/31 /18 18:32 460-00-4 97 %. 82-109 1 12/31 /18 18:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 65 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Sample: 1302-AMW2d Parameters Lab ID: 2612903025 Collected: Report Results Units Limit MDL 12/20/18 12:34 Received: 12/21/18 11:00 Matrix: Water Reg. Limit DF Prepared Analyzed CAS No. Qual 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 137000 ug/L 20000 20000 1 12/24/18 14:32 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen ND ug/L 10000 10000 1 12/28/1811:45 12/28/1815:20 Demand 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide 272 ug/L 200 200 1 12/24/1814:08 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 2000 1 12/21/18 17:00 12/26/18 12:22 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N ND ug/L 50.0 5.0 1 12/22/18 11:11 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 3400 ug/L 1000 24.0 1 01/03/19 08:36 16887-00-6 Sulfate 819J ug/L 5000 17.0 1 01/03/19 08:36 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 21:08 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 21:08 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 21:08 7440-44-0 Total Organic Carbon ND ug/L 1000 1000 1 12/21/18 21:08 7440-44-0 Mean Total Organic ND ug/L 1000 1000 1 12/21/18 21:08 7440-44-0 Carbon Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19357 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612903001 METHOD BLANK: 87374 Associated Lab Samples: 2612903001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 12/20/1818:31 Arsenic ug/L ND 10.0 0.57 12/20/1818:31 Barium ug/L ND 100 0.78 12/20/1818:31 Beryllium ug/L ND 1.0 0.050 12/20/1818:31 Cadmium ug/L ND 1.0 0.093 12/20/1818:31 Chromium ug/L ND 10.0 1.6 12/20/1818:31 Cobalt ug/L ND 10.0 0.52 12/20/1818:31 Copper ug/L ND 10.0 1.3 12/20/1818:31 Lead ug/L ND 10.0 0.27 12/20/1818:31 Nickel ug/L ND 50.0 0.95 12/20/1818:31 Selenium ug/L ND 10.0 1.4 12/20/1818:31 Silver ug/L ND 10.0 0.95 12/20/1818:31 Thallium ug/L ND 5.5 0.14 12/20/1818:31 Vanadium ug/L ND 25.0 1.9 12/20/1818:31 Zinc ug/L ND 10.0 2.1 12/20/1818:31 LABORATORY CONTROL SAMPLE: 87375 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 98.8 99 80-120 Arsenic ug/L 100 97.5 98 80-120 Barium ug/L 100 99.5J 100 80-120 Beryllium ug/L 100 94.6 95 80-120 Cadmium ug/L 100 95.2 95 80-120 Chromium ug/L 100 97.9 98 80-120 Cobalt ug/L 100 98.3 98 80-120 Copper ug/L 100 97.8 98 80-120 Lead ug/L 100 94.9 95 80-120 Nickel ug/L 100 98.0 98 80-120 Selenium ug/L 100 95.2 95 80-120 Silver ug/L 100 95.7 96 80-120 Thallium ug/L 100 97.7 98 80-120 Vanadium ug/L 100 99.5 100 80-120 Zinc ug/L 100 93.8 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 87376 87377 MS MSD 2612867006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 104 99.5 104 100 75-125 4 20 Arsenic ug/L ND 100 100 103 103 102 102 75-125 0 20 Barium ug/L 797 100 100 910 890 113 93 75-125 2 20 Beryllium ug/L ND 100 100 97.3 95.5 97 95 75-125 2 20 Cadmium ug/L ND 100 100 99.5 100 99 100 75-125 0 20 Chromium ug/L ND 100 100 111 110 109 108 75-125 1 20 Cobalt ug/L ND 100 100 110 109 107 105 75-125 1 20 Copper ug/L ND 100 100 99.8 101 99 100 75-125 1 20 Lead ug/L ND 100 100 95.8 94.8 95 94 75-125 1 20 Nickel ug/L ND 100 100 106 105 104 103 75-125 1 20 Selenium ug/L ND 100 100 105 101 103 99 75-125 3 20 Silver ug/L ND 100 100 97.9 94.6 98 95 75-125 3 20 Thallium ug/L ND 100 100 97.8 98.5 98 99 75-125 1 20 Vanadium ug/L ND 100 100 115 115 111 112 75-125 0 20 Zinc ug/L ND 100 100 108 108 100 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19757 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612903002, 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010, 2612903011, 2612903012, 2612903013, 2612903014, 2612903015, 2612903016, 2612903017, 2612903018,2612903019 METHOD BLANK: 89103 Associated Lab Samples: Parameter Matrix: Water 2612903002, 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010,2612903011,2612903012,2612903013,2612903014,2612903015,2612903016,2612903017, 2612903018,2612903019 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 12/31/1815:27 Arsenic ug/L ND 10.0 0.57 12/31/1815:27 Barium ug/L ND 100 0.78 12/31/1815:27 Beryllium ug/L ND 1.0 0.050 12/31/1815:27 Cadmium ug/L ND 1.0 0.093 12/31/1815:27 Chromium ug/L ND 10.0 1.6 12/31/1815:27 Cobalt ug/L ND 10.0 0.52 12/31/1815:27 Copper ug/L ND 10.0 1.3 12/31/1815:27 Lead ug/L ND 10.0 0.27 12/31/1815:27 Nickel ug/L ND 50.0 0.95 12/31/1815:27 Selenium ug/L ND 10.0 1.4 12/31/1815:27 Silver ug/L ND 10.0 0.95 12/31/1815:27 Thallium ug/L ND 5.5 0.14 12/31/1815:27 Vanadium ug/L ND 25.0 1.9 12/31/1815:27 Zinc ug/L ND 10.0 2.1 12/31/1815:27 LABORATORY CONTROL SAMPLE: 89104 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 111 111 80-120 Arsenic ug/L 100 99.8 100 80-120 Barium ug/L 100 101 101 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 102 102 80-120 Chromium ug/L 100 106 106 80-120 Cobalt ug/L 100 103 103 80-120 Copper ug/L 100 104 104 80-120 Lead ug/L 100 100 100 80-120 Nickel ug/L 100 104 104 80-120 Selenium ug/L 100 103 103 80-120 Silver ug/L 100 106 106 80-120 Thallium ug/L 100 102 102 80-120 Vanadium ug/L 100 106 106 80-120 Zinc ug/L 100 101 101 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 69 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89105 89106 MS MSD 2612903011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 105 104 105 104 75-125 1 20 Arsenic ug/L ND 100 100 98.7 96.3 98 96 75-125 2 20 Barium ug/L 16.7J 100 100 117 115 101 98 75-125 2 20 Beryllium ug/L 0.14J 100 100 99.7 104 100 104 75-125 4 20 Cadmium ug/L ND 100 100 98.8 99.8 99 100 75-125 1 20 Chromium ug/L 2.1J 100 100 108 106 106 104 75-125 2 20 Cobalt ug/L 0.911 100 100 101 99.2 100 98 75-125 2 20 Copper ug/L ND 100 100 101 99.6 100 99 75-125 1 20 Lead ug/L 1.3J 100 100 97.7 94.9 96 94 75-125 3 20 Nickel ug/L 2.5J 100 100 104 102 101 99 75-125 2 20 Selenium ug/L ND 100 100 99.3 96.0 99 96 75-125 3 20 Silver ug/L ND 100 100 102 99.6 102 100 75-125 2 20 Thallium ug/L ND 100 100 98.6 93.7 99 94 75-125 5 20 Vanadium ug/L 7.2J 100 100 116 113 108 106 75-125 2 20 Zinc ug/L 6.9J 100 100 105 103 98 97 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 70 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19912 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024 METHOD BLANK: 89672 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 01/02/1915:22 Arsenic ug/L ND 10.0 0.57 01/02/1915:22 Barium ug/L ND 100 0.78 01/02/1915:22 Beryllium ug/L ND 1.0 0.050 01/02/1915:22 Cadmium ug/L ND 1.0 0.093 01/02/1915:22 Chromium ug/L ND 10.0 1.6 01/02/1915:22 Cobalt ug/L ND 10.0 0.52 01/02/1915:22 Copper ug/L ND 10.0 1.3 01/02/1915:22 Lead ug/L ND 10.0 0.27 01/02/1915:22 Nickel ug/L ND 50.0 0.95 01/02/1915:22 Selenium ug/L ND 10.0 1.4 01/02/1915:22 Silver ug/L ND 10.0 0.95 01/02/1915:22 Thallium ug/L ND 5.5 0.14 01/02/1915:22 Vanadium ug/L ND 25.0 1.9 01/02/1915:22 Zinc ug/L ND 10.0 2.1 01/02/1915:22 LABORATORY CONTROL SAMPLE: 89673 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 106 106 80-120 Arsenic ug/L 100 103 103 80-120 Barium ug/L 100 99AJ 99 80-120 Beryllium ug/L 100 108 108 80-120 Cadmium ug/L 100 101 101 80-120 Chromium ug/L 100 105 105 80-120 Cobalt ug/L 100 103 103 80-120 Copper ug/L 100 105 105 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 103 103 80-120 Selenium ug/L 100 104 104 80-120 Silver ug/L 100 106 106 80-120 Thallium ug/L 100 103 103 80-120 Vanadium ug/L 100 106 106 80-120 Zinc ug/L 100 104 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89674 89675 MS MSD 2613078005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 104 104 104 104 75-125 0 20 Arsenic ug/L ND 100 100 99.6 100 99 99 75-125 0 20 Barium ug/L 73.0 100 100 179 177 106 104 75-125 1 20 Beryllium ug/L ND 100 100 106 108 106 108 75-125 2 20 Cadmium ug/L ND 100 100 102 104 102 104 75-125 2 20 Chromium ug/L ND 100 100 113 111 110 108 75-125 2 20 Cobalt ug/L ND 100 100 108 106 108 105 75-125 2 20 Copper ug/L ND 100 100 116 110 114 108 75-125 6 20 Lead ug/L ND 100 100 108 105 106 102 75-125 3 20 Nickel ug/L ND 100 100 108 110 107 108 75-125 1 20 Selenium ug/L ND 100 100 90.4 92.9 90 92 75-125 3 20 Silver ug/L ND 100 100 108 105 108 105 75-125 3 20 Thallium ug/L ND 100 100 106 102 106 102 75-125 3 20 Vanadium ug/L ND 100 100 120 119 112 111 75-125 1 20 Zinc ug/L ND 100 100 116 114 97 96 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 72 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19951 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612903025 METHOD BLANK: 89826 Associated Lab Samples: 2612903025 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 01/02/1917:42 Arsenic ug/L ND 10.0 0.57 01/02/1917:42 Barium ug/L ND 100 0.78 01/02/1917:42 Beryllium ug/L ND 1.0 0.050 01/02/1917:42 Cadmium ug/L ND 1.0 0.093 01/02/1917:42 Chromium ug/L ND 10.0 1.6 01/02/1917:42 Cobalt ug/L ND 10.0 0.52 01/02/1917:42 Copper ug/L ND 10.0 1.3 01/02/1917:42 Lead ug/L ND 10.0 0.27 01/02/1917:42 Nickel ug/L ND 50.0 0.95 01/02/1917:42 Selenium ug/L ND 10.0 1.4 01/02/1917:42 Silver ug/L ND 10.0 0.95 01/02/1917:42 Thallium ug/L ND 5.5 0.14 01/02/1917:42 Vanadium ug/L ND 25.0 1.9 01/02/1917:42 Zinc ug/L ND 10.0 2.1 01/02/1917:42 LABORATORY CONTROL SAMPLE: 89827 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 105 105 80-120 Arsenic ug/L 100 100 100 80-120 Barium ug/L 100 101 101 80-120 Beryllium ug/L 100 99.0 99 80-120 Cadmium ug/L 100 103 103 80-120 Chromium ug/L 100 103 103 80-120 Cobalt ug/L 100 102 102 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 101 101 80-120 Nickel ug/L 100 103 103 80-120 Selenium ug/L 100 98.6 99 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 102 102 80-120 Vanadium ug/L 100 102 102 80-120 Zinc ug/L 100 101 101 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 73 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89828 89829 MS MSD 2613188001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 100 105 100 105 75-125 4 20 Arsenic ug/L ND 100 100 96.7 99.5 97 99 75-125 3 20 Barium ug/L 0.051 100 100 146 151 95 100 75-125 3 20 mg/L Beryllium ug/L ND 100 100 94.0 93.2 94 93 75-125 1 20 Cadmium ug/L ND 100 100 99.8 102 100 102 75-125 2 20 Chromium ug/L ND 100 100 95.7 97.7 95 97 75-125 2 20 Cobalt ug/L 0.011 100 100 105 107 94 96 75-125 2 20 mg/L Copper ug/L ND 100 100 96.7 99.5 95 98 75-125 3 20 Lead ug/L ND 100 100 95.4 97.9 95 97 75-125 3 20 Nickel ug/L ND 100 100 97.5 99.1 96 98 75-125 2 20 Selenium ug/L ND 100 100 96.6 98.1 96 98 75-125 2 20 Silver ug/L ND 100 100 95.8 98.1 96 98 75-125 2 20 Thallium ug/L ND 100 100 96.3 98.9 96 99 75-125 3 20 Vanadium ug/L ND 100 100 96.6 98.2 96 98 75-125 2 20 Zinc ug/L ND 100 100 102 106 94 98 75-125 4 20 SAMPLE DUPLICATE: 89834 92412243002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Antimony ug/L ND ND 20 Arsenic ug/L ND ND 20 Barium ug/L 62.6 60.8J 3 20 Beryllium ug/L ND 0.24J 20 Cadmium ug/L ND ND 20 Chromium ug/L ND ND 20 Cobalt ug/L ND ND 20 Copper ug/L ND 2.9J 20 Lead ug/L ND 0.43J 20 Nickel ug/L ND ND 20 Selenium ug/L ND ND 20 Silver ug/L ND ND 20 Thallium ug/L ND ND 20 Vanadium ug/L ND ND 20 Zinc ug/L ND 9.11 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 449396 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010, 2612903011,2612903012,2612903013,2612903014,2612903015,2612903016 METHOD BLANK: 2460781 Matrix: Water Associated Lab Samples: 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010, 2612903011,2612903012,2612903013,2612903014,2612903015,2612903016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/24/18 11:57 1,2-Dichloroethane-d4 (S) % 94 50-150 12/24/18 11:57 Toluene-d8 (S) % 90 50-150 12/24/18 11:57 LABORATORY CONTROL SAMPLE: 2460782 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.4 92 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8(S) % 91 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2460783 2460784 MS MSD 92411913001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L <1.9 20 20 16.3 17.3 82 86 50-150 6 30 1,2-Dichloroethane-d4 (S) % 96 99 50-150 30 Toluene-d8 (S) % 92 95 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 75 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 449397 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612903002 METHOD BLANK: 2460785 Associated Lab Samples: 2612903002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 93 50-150 90 50-150 MDL Analyzed 1.9 12/24/18 11:38 12/24/18 11:38 12/24/18 11:38 Qualifiers LABORATORY CONTROL SAMPLE: 2460786 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 18.0 90 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8 (S) % 91 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2460787 2460788 MS MSD 2612903002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 72.6 20 20 86.1 90.8 68 91 50-150 5 30 1,2-Dichloroethane-d4 (S) % 100 100 50-150 30 Toluene-d8 (S) % 95 94 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 76 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 449723 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612903001, 2612903017, 2612903018, 2612903019, 2612903020 METHOD BLANK: 2461845 Matrix: Water Associated Lab Samples: 2612903001, 2612903017, 2612903018, 2612903019, 2612903020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/27/18 11:13 1,2-Dichloroethane-d4 (S) % 95 50-150 12/27/18 11:13 Toluene-d8 (S) % 94 50-150 12/27/18 11:13 LABORATORY CONTROL SAMPLE: 2461846 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.2 101 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8 (S) % 93 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2461847 2461848 MS MSD 2612903017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 23.1 22.1 115 110 50-150 5 30 1,2-Dichloroethane-d4 (S) % 103 102 50-150 30 Toluene-d8 (S) % 97 98 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 449944 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 2462724 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/28/18 11:13 1,2-Dichloroethane-d4 (S) % 99 50-150 12/28/18 11:13 Toluene-d8 (S) % 97 50-150 12/28/18 11:13 LABORATORY CONTROL SAMPLE: 2462725 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 22.8 114 71-125 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8 (S) % 97 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2462726 2462727 MS MSD 2613064001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 87.7 20 20 116 115 140 138 50-150 0 30 E 1,2-Dichloroethane-d4 (S) % 98 101 50-150 30 Toluene-d8 (S) % 96 99 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 78 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19774 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Associated Lab Samples: 2612903001 METHOD BLANK: 89194 Associated Lab Samples: 2612903001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 12/27/18 21:32 1,1,1-Trichloroethane ug/L ND 1.0 0.38 12/27/18 21:32 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 12/27/18 21:32 1,1,2-Trichloroethane ug/L ND 1.0 0.59 12/27/18 21:32 1,1-Dichloroethane ug/L ND 5.0 0.41 12/27/18 21:32 1,1-Dichloroethene ug/L ND 5.0 0.72 12/27/18 21:32 1,2,3-Trichloropropane ug/L ND 1.0 0.46 12/27/18 21:32 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 12/27/18 21:32 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 12/27/18 21:32 1,2-Dichlorobenzene ug/L ND 5.0 0.49 12/27/18 21:32 1,2-Dichloroethane ug/L ND 1.0 0.67 12/27/18 21:32 1,2-Dichloropropane ug/L ND 1.0 0.60 12/27/18 21:32 1,4-Dichlorobenzene ug/L ND 1.0 0.58 12/27/18 21:32 2-Butanone (MEK) ug/L ND 100 3.2 12/27/18 21:32 2-Hexanone ug/L ND 50.0 0.89 12/27/18 21:32 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 12/27/18 21:32 Acetone ug/L ND 100 8.2 12/27/18 21:32 Acrylonitrile ug/L ND 200 2.5 12/27/18 21:32 Benzene ug/L ND 1.0 0.20 12/27/18 21:32 Bromochloromethane ug/L ND 3.0 0.50 12/27/18 21:32 Bromodichloromethane ug/L ND 1.0 0.36 12/27/18 21:32 Bromoform ug/L ND 3.0 0.55 12/27/18 21:32 Bromomethane ug/L ND 10.0 0.95 12/27/18 21:32 Carbon disulfide ug/L ND 100 0.79 12/27/18 21:32 Carbon tetrachloride ug/L ND 1.0 0.42 12/27/18 21:32 Chlorobenzene ug/L ND 3.0 0.53 12/27/18 21:32 Chloroethane ug/L ND 10.0 0.52 12/27/18 21:32 Chloroform ug/L ND 5.0 0.58 12/27/18 21:32 Chloromethane ug/L ND 1.0 0.38 12/27/18 21:32 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 12/27/18 21:32 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 12/27/18 21:32 Dibromochloromethane ug/L ND 1.0 0.31 12/27/18 21:32 Dibromomethane ug/L ND 10.0 0.62 12/27/18 21:32 Ethylbenzene ug/L ND 1.0 0.45 12/27/18 21:32 lodomethane ug/L ND 10.0 3.1 12/27/18 21:32 Methylene Chloride ug/L ND 1.0 0.50 12/27/18 21:32 Styrene ug/L ND 1.0 0.50 12/27/18 21:32 Tetrachloroethene ug/L ND 1.0 0.78 12/27/18 21:32 Tetrahydrofuran ug/L ND 10.0 1.3 12/27/18 21:32 Toluene ug/L ND 1.0 0.31 12/27/18 21:32 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 12/27/18 21:32 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 METHOD BLANK: 89194 Associated Lab Samples: 2612903001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 12/27/18 21:32 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 12/27/18 21:32 Trichloroethene ug/L ND 1.0 0.34 12/27/18 21:32 Trichlorofluoromethane ug/L ND 1.0 0.51 12/27/18 21:32 Vinyl acetate ug/L ND 50.0 0.42 12/27/18 21:32 Vinyl chloride ug/L ND 1.0 0.60 12/27/18 21:32 Xylene (Total) ug/L ND 5.0 1.5 12/27/18 21:32 1,2-Dichloroethane-d4 (S) %. 101 81-119 12/27/18 21:32 4-Bromofluorobenzene (S) %. 105 82-120 12/27/18 21:32 Dibromofluoromethane (S) %. 93 82-114 12/27/18 21:32 Toluene-d8 (S) %. 102 82-109 12/27/18 21:32 LABORATORY CONTROL SAMPLE: 89195 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 68-137 1,1,1-Trichloroethane ug/L 50 54.1 108 72-134 1,1,2,2-Tetrachloroethane ug/L 50 54.2 108 51-158 1,1,2-Trichloroethane ug/L 50 56.4 113 78-131 1,1-Dichloroethane ug/L 50 52.1 104 69-151 1,1-Dichloroethene ug/L 50 60.2 120 64-158 1,2,3-Trichloropropane ug/L 50 49.0 98 78-133 1,2-Dibromo-3-chloropropane ug/L 50 49.9 100 58-124 1,2-Dibromoethane (EDB) ug/L 50 53.0 106 71-134 1,2-Dichlorobenzene ug/L 50 53.6 107 70-135 1,2-Dichloroethane ug/L 50 55.8 112 72-129 1,2-Dichloropropane ug/L 50 58.8 118 64-135 1,4-Dichlorobenzene ug/L 50 50.9 102 70-131 2-Butanone (MEK) ug/L 100 96.2J 96 52-143 2-Hexanone ug/L 100 93.5 94 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 97.3J 97 71-129 Acetone ug/L 100 99.5J 100 48-224 Acrylonitrile ug/L 200 209 104 66-154 Benzene ug/L 50 54.6 109 68-132 Bromochloromethane ug/L 50 56.4 113 73-133 Bromodichloromethane ug/L 50 51.8 104 67-121 Bromoform ug/L 50 45.8 92 57-125 Bromomethane ug/L 50 53.9 108 35-156 Carbon disulfide ug/L 100 109 109 47-141 Carbon tetrachloride ug/L 50 57.7 115 66-122 Chlorobenzene ug/L 50 53.4 107 71-126 Chloroethane ug/L 50 43.5 87 43-143 Chloroform ug/L 50 54.8 110 71-136 Chloromethane ug/L 50 47.4 95 47-123 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 LABORATORY CONTROL SAMPLE: 89195 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 57.3 115 74-131 cis-1,3-Dichloropropene ug/L 50 51.9 104 78-120 Dibromochloromethane ug/L 50 49.0 98 65-115 Dibromomethane ug/L 50 55.5 111 79-129 Ethylbenzene ug/L 50 53.4 107 68-129 lodomethane ug/L 100 79.7 80 49-154 Methylene Chloride ug/L 50 54.3 109 61-147 Styrene ug/L 50 58.9 118 77-128 Tetrachloroethene ug/L 50 54.5 109 51-139 Tetrahydrofuran ug/L 100 108 108 56-147 Toluene ug/L 50 54.7 109 60-133 trans-1,2-Dichloroethene ug/L 50 58.2 116 69-144 trans- 1,3-Dichloropropene ug/L 50 49.2 98 74-128 trans-1,4-Dichloro-2-butene ug/L 100 90.O1 90 61-139 Trichloroethene ug/L 50 51.2 102 73-126 Trichlorofluoromethane ug/L 50 52.3 105 55-132 Vinyl acetate ug/L 50 49.OJ 98 52-141 Vinyl chloride ug/L 50 46.1 92 50-133 Xylene (Total) ug/L 150 172 114 78-132 1,2-Dichloroethane-d4 (S) %. 101 81-119 4-Bromofluorobenzene (S) %. 103 82-120 Dibromofluoromethane (S) %. 103 82-114 Toluene-d8 (S) %. 100 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89196 89197 MS MSD 2613081041 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 48.3 46.3 97 93 68-137 4 11 1,1,1-Trichloroethane ug/L ND 50 50 58.2 55.6 116 111 66-142 5 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 50.2 49.9 100 100 39-171 1 13 1,1,2-Trichloroethane ug/L ND 50 50 51.8 51.8 104 104 73-136 0 12 1,1-Dichloroethane ug/L ND 50 50 60.8 60.3 122 121 66-155 1 15 1,1-Dichloroethene ug/L ND 50 50 65.4 62.5 131 125 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 42.1 41.1 84 82 78-133 2 14 1,2-Dibromo-3- ug/L ND 50 50 45.4 43.9 91 88 58-124 3 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 48.7 47.5 97 95 71-134 3 12 1,2-Dichlorobenzene ug/L ND 50 50 53.8 50.4 108 101 69-135 6 10 1,2-Dichloroethane ug/L ND 50 50 56.3 53.0 113 106 36-159 6 10 1,2-Dichloropropane ug/L ND 50 50 53.3 53.0 107 106 68-132 1 11 1,4-Dichlorobenzene ug/L ND 50 50 48.2 47.5 96 95 49-153 1 9 2-Butanone (MEK) ug/L ND 100 100 72.8J 70.OJ 73 70 10-189 4 23 2-Hexanone ug/L ND 100 100 77.0 77.9 77 78 40-135 1 18 4-Methyl-2-pentanone ug/L ND 100 100 80.5J 83.6J 80 84 30-177 4 10 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 81 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89196 89197 MS MSD 2613081041 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 100 100 63AJ 66.8J 63 67 44-223 5 14 Acrylonitrile ug/L ND 200 200 1991 195J 100 98 13-189 2 12 Benzene ug/L ND 50 50 53.7 52.8 107 106 66-139 2 10 Bromochloromethane ug/L ND 50 50 52.4 52.0 105 104 73-133 1 13 Bromodichloromethane ug/L ND 50 50 49.5 47.6 99 95 57-120 4 13 Bromoform ug/L ND 50 50 42.9 41.3 86 83 48-128 4 13 Bromomethane ug/L ND 50 50 38.8 43.2 78 86 10-187 11 32 Carbon disulfide ug/L ND 100 100 113 110 113 110 47-141 2 322 Carbon tetrachloride ug/L ND 50 50 75.0 71.0 150 142 58-127 5 14 M1 Chlorobenzene ug/L ND 50 50 51.3 49.6 103 99 63-137 3 10 Chloroethane ug/L ND 50 50 45.9 44.2 92 88 52-146 4 16 Chloroform ug/L ND 50 50 56.6 53.5 113 107 74-137 6 9 Chloromethane ug/L ND 50 50 44.3 44.6 89 89 41-127 1 10 cis-1,2-Dichloroethene ug/L ND 50 50 57.1 53.1 114 106 71-138 7 16 cis-1,3-Dichloropropene ug/L ND 50 50 46.1 44.8 92 90 32-145 3 12 Dibromochloromethane ug/L ND 50 50 45.2 45.2 90 90 52-116 0 13 Dibromomethane ug/L ND 50 50 49.1 49.8 98 100 79-129 2 14 Ethylbenzene ug/L ND 50 50 52.8 50.6 106 101 31-174 4 10 lodomethane ug/L ND 100 100 87.9 87.6 88 88 49-154 0 30 Methylene Chloride ug/L ND 50 50 51.7 50.2 103 100 61-146 3 15 Styrene ug/L ND 50 50 58.6 53.0 117 106 77-128 10 14 Tetrachloroethene ug/L ND 50 50 54.1 53.5 108 107 36-155 1 14 Tetrahydrofuran ug/L ND 100 100 98.0 89.9 98 90 56-147 9 12 Toluene ug/L ND 50 50 52.6 52.9 105 106 52-146 0 11 trans-1,2-Dichloroethene ug/L ND 50 50 59.5 55.4 119 111 61-152 7 14 trans-1,3-Dichloropropene ug/L ND 50 50 42.6 42.4 85 85 37-146 0 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 63.6J 67.9J 64 68 61-139 6 12 Trichloroethene ug/L ND 50 50 51.9 52.3 104 105 61-141 1 12 Trichlorofluoromethane ug/L ND 50 50 63.7 62.3 127 125 51-141 2 13 Vinyl acetate ug/L ND 50 50 81.6 61.0 163 122 52-141 29 14 M1,R1 Vinyl chloride ug/L ND 50 50 51.8 48.5 104 97 22-156 7 26 Xylene (Total) ug/L ND 150 150 169 164 113 109 78-132 3 7 1,2-Dichloroethane-d4 (S) %. 107 103 81-119 4-Bromofluorobenzene (S) %. 106 112 82-120 Dibromofluoromethane (S) %. 109 105 82-114 Toluene-d8 (S) %. 101 100 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 82 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19888 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Associated Lab Samples: 2612903002, 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010, 2612903011, 2612903012, 2612903013, 2612903014, 2612903015, 2612903016, 2612903017, 2612903018,2612903019,2612903020 METHOD BLANK: 89591 Matrix: Water Associated Lab Samples: 2612903002, 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010,2612903011,2612903012,2612903013,2612903014,2612903015,2612903016,2612903017, 2612903018,2612903019,2612903020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 12/31/18 10:24 1,1,1-Trichloroethane ug/L ND 1.0 0.38 12/31/18 10:24 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 12/31/18 10:24 1,1,2-Trichloroethane ug/L ND 1.0 0.59 12/31/18 10:24 1,1-Dichloroethane ug/L ND 5.0 0.41 12/31/18 10:24 1,1-Dichloroethene ug/L ND 5.0 0.72 12/31/18 10:24 1,2,3-Trichloropropane ug/L ND 1.0 0.46 12/31/18 10:24 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 12/31/18 10:24 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 12/31/18 10:24 1,2-Dichlorobenzene ug/L ND 5.0 0.49 12/31/18 10:24 1,2-Dichloroethane ug/L ND 1.0 0.67 12/31/18 10:24 1,2-Dichloropropane ug/L ND 1.0 0.60 12/31/18 10:24 1,4-Dichlorobenzene ug/L ND 1.0 0.58 12/31/18 10:24 2-Butanone (MEK) ug/L ND 100 3.2 12/31/18 10:24 2-Hexanone ug/L ND 50.0 0.89 12/31/18 10:24 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 12/31/18 10:24 Acetone ug/L ND 100 8.2 12/31/18 10:24 Acrylonitrile ug/L ND 200 2.5 12/31/18 10:24 Benzene ug/L ND 1.0 0.20 12/31/18 10:24 Bromochloromethane ug/L ND 3.0 0.50 12/31/18 10:24 Bromodichloromethane ug/L ND 1.0 0.36 12/31/18 10:24 Bromoform ug/L ND 3.0 0.55 12/31/18 10:24 Bromomethane ug/L ND 10.0 0.95 12/31/18 10:24 Carbon disulfide ug/L ND 100 0.79 12/31/18 10:24 Carbon tetrachloride ug/L ND 1.0 0.42 12/31/18 10:24 Chlorobenzene ug/L ND 3.0 0.53 12/31/18 10:24 Chloroethane ug/L ND 10.0 0.52 12/31/18 10:24 Chloroform ug/L ND 5.0 0.58 12/31/18 10:24 Chloromethane ug/L ND 1.0 0.38 12/31/18 10:24 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 12/31/18 10:24 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 12/31/18 10:24 Dibromochloromethane ug/L ND 1.0 0.31 12/31/18 10:24 Dibromomethane ug/L ND 10.0 0.62 12/31/18 10:24 Ethylbenzene ug/L ND 1.0 0.45 12/31/18 10:24 lodomethane ug/L ND 10.0 3.1 12/31/18 10:24 Methylene Chloride ug/L ND 1.0 0.50 12/31/18 10:24 Styrene ug/L ND 1.0 0.50 12/31/18 10:24 Tetrachloroethene ug/L ND 1.0 0.78 12/31/18 10:24 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 METHOD BLANK: 89591 Matrix: Water Associated Lab Samples: 2612903002, 2612903003, 2612903004, 2612903005, 2612903006, 2612903007, 2612903008, 2612903009, 2612903010, 2612903011, 2612903012, 2612903013, 2612903014, 2612903015, 2612903016, 2612903017, 2612903018,2612903019,2612903020 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Tetrahydrofuran ug/L ND 10.0 1.3 12/31/18 10:24 Toluene ug/L ND 1.0 0.31 12/31/18 10:24 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 12/31/18 10:24 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 12/31/18 10:24 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 12/31/18 10:24 Trichloroethene ug/L ND 1.0 0.34 12/31/18 10:24 Trichlorofluoromethane ug/L ND 1.0 0.51 12/31/18 10:24 Vinyl acetate ug/L ND 50.0 0.42 12/31/18 10:24 Vinyl chloride ug/L ND 1.0 0.60 12/31/18 10:24 Xylene (Total) ug/L ND 5.0 1.5 12/31/18 10:24 1,2-Dichloroethane-d4 (S) %. 114 81-119 12/31/18 10:24 4-Bromofluorobenzene (S) %. 106 82-120 12/31/18 10:24 Dibromofluoromethane (S) %. 100 82-114 12/31/18 10:24 Toluene-d8 (S) %. 117 82-109 12/31/18 10:24 LABORATORY CONTROL SAMPLE: Parameter 89592 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.9 104 68-137 1,1,1-Trichloroethane ug/L 50 58.8 118 72-134 1,1,2,2-Tetrachloroethane ug/L 50 52.1 104 51-158 1,1,2-Trichloroethane ug/L 50 54.5 109 78-131 1,1-Dichloroethane ug/L 50 65.7 131 69-151 1,1-Dichloroethene ug/L 50 58.7 117 64-158 1,2,3-Trichloropropane ug/L 50 50.8 102 78-133 1,2-Dibromo-3-chloropropane ug/L 50 55.5 111 58-124 1,2-Dibromoethane (EDB) ug/L 50 52.6 105 71-134 1,2-Dichlorobenzene ug/L 50 52.4 105 70-135 1,2-Dichloroethane ug/L 50 58.6 117 72-129 1,2-Dichloropropane ug/L 50 54.7 109 64-135 1,4-Dichlorobenzene ug/L 50 51.0 102 70-131 2-Butanone (MEK) ug/L 100 91.01 91 52-143 2-Hexanone ug/L 100 81.3 81 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 100 100 71-129 Acetone ug/L 100 69.5J 69 48-224 Acrylonitrile ug/L 200 216 108 66-154 Benzene ug/L 50 54.2 108 68-132 Bromochloromethane ug/L 50 58.5 117 73-133 Bromodichloromethane ug/L 50 52.8 106 67-121 Bromoform ug/L 50 47.1 94 57-125 Bromomethane ug/L 50 50.2 100 35-156 Carbon disulfide ug/L 100 109 109 47-141 S3 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 84 of 157 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW pacalabs.com (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 LABORATORY CONTROL SAMPLE: Parameter 89592 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Carbon tetrachloride ug/L 50 63.5 127 66-122 L1 Chlorobenzene ug/L 50 51.4 103 71-126 Chloroethane ug/L 50 44.3 89 43-143 Chloroform ug/L 50 58.1 116 71-136 Chloromethane ug/L 50 45.0 90 47-123 cis-1,2-Dichloroethene ug/L 50 64.7 129 74-131 cis-1,3-Dichloropropene ug/L 50 59.1 118 78-120 Dibromochloromethane ug/L 50 51.2 102 65-115 Dibromomethane ug/L 50 54.8 110 79-129 Ethylbenzene ug/L 50 52.7 105 68-129 lodomethane ug/L 100 103 103 49-154 Methylene Chloride ug/L 50 54.0 108 61-147 Styrene ug/L 50 57.2 114 77-128 Tetrachloroethene ug/L 50 52.3 105 51-139 Tetrahydrofuran ug/L 100 106 106 56-147 Toluene ug/L 50 53.6 107 60-133 trans-1,2-Dichloroethene ug/L 50 56.8 114 69-144 trans- 1,3-Dichloropropene ug/L 50 52.5 105 74-128 trans-1,4-Dichloro-2-butene ug/L 100 107 107 61-139 Trichloroethene ug/L 50 52.9 106 73-126 Trichlorofluoromethane ug/L 50 52.9 106 55-132 Vinyl acetate ug/L 50 59.4 119 52-141 Vinyl chloride ug/L 50 45.5 91 50-133 Xylene (Total) ug/L 150 167 111 78-132 1,2-Dichloroethane-d4 (S) %. 109 81-119 4-Bromofluorobenzene (S) %. 106 82-120 Dibromofluoromethane (S) %. 112 82-114 Toluene-d8 (S) %. 108 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89593 2612903002 Parameter Units Result MS Spike Conc. MSD Spike Conc. 89594 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual 1, 1, 1,2-Tetrachloroethane ug/L ND 50 50 51.9 51.3 104 103 68-137 1 11 1, 1, 1 -Trichloroethane ug/L ND 50 50 59.4 70.3 119 141 66-142 17 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 51.8 52.2 104 104 39-171 1 13 1,1,2-Trichloroethane ug/L ND 50 50 62.5 53.8 125 108 73-136 15 12 R1 1,1-Dichloroethane ug/L 1.91 50 50 63.1 69.9 123 136 66-155 10 15 1,1-Dichloroethene ug/L ND 50 50 62.4 67.8 125 136 33-181 8 34 1,2,3-Trichloropropane ug/L ND 50 50 48.9 47.5 98 95 78-133 3 14 1,2-Dibromo-3- ug/L ND 50 50 46.7 50.9 93 102 58-124 9 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 54.4 52.3 109 105 71-134 4 12 1,2-Dichlorobenzene ug/L ND 50 50 50.8 51.5 102 103 69-135 1 10 1,2-Dichloroethane ug/L ND 50 50 57.7 66.7 115 133 36-159 14 10 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89593 89594 MS MSD 2612903002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,2-Dichloropropane ug/L ND 50 50 56.2 55.3 112 111 68-132 2 11 1,4-Dichlorobenzene ug/L ND 50 50 49.5 47.2 99 94 49-153 5 9 2-Butanone (MEK) ug/L ND 100 100 78.3J 104 78 104 10-189 29 23 R1 2-Hexanone ug/L ND 100 100 86.6 88.0 87 88 40-135 2 18 4-Methyl-2-pentanone ug/L ND 100 100 90.7J 94.5J 91 94 30-177 4 10 (MIBK) Acetone ug/L ND 100 100 64.3J 73.2J 64 73 44-223 13 14 Acrylonitrile ug/L ND 200 200 189J 221 95 111 13-189 16 12 R1 Benzene ug/L ND 50 50 53.6 63.8 107 128 66-139 17 10 R1 Bromochloromethane ug/L ND 50 50 52.1 67.9 104 136 73-133 26 13 M1,R1 Bromodichloromethane ug/L ND 50 50 54.2 57.9 108 116 57-120 7 13 Bromoform ug/L ND 50 50 46.9 45.2 94 90 48-128 4 13 Bromomethane ug/L ND 50 50 36.9 47.3 74 95 10-187 25 32 Carbon disulfide ug/L ND 100 100 110 121 110 121 47-141 10 322 Carbon tetrachloride ug/L ND 50 50 75.7 88.1 151 176 58-127 15 14 MO,R1 Chlorobenzene ug/L ND 50 50 54.5 51.8 109 104 63-137 5 10 Chloroethane ug/L ND 50 50 45.4 48.3 91 97 52-146 6 16 Chloroform ug/L ND 50 50 57.0 66.1 114 132 74-137 15 9 R1 Chloromethane ug/L ND 50 50 45.8 52.1 92 104 41-127 13 10 R1 cis-1,2-Dichloroethene ug/L 0.74J 50 50 57.4 69.8 113 138 71-138 20 16 R1 cis-1,3-Dichloropropene ug/L ND 50 50 50.6 48.4 101 97 32-145 4 12 Dibromochloromethane ug/L ND 50 50 50.8 48.8 102 98 52-116 4 13 Dibromomethane ug/L ND 50 50 53.7 53.5 107 107 79-129 0 14 Ethylbenzene ug/L ND 50 50 55.3 54.6 111 109 31-174 1 10 lodomethane ug/L ND 100 100 88.3 96.3 88 96 49-154 9 30 Methylene Chloride ug/L ND 50 50 51.7 55.6 103 111 61-146 7 15 Styrene ug/L ND 50 50 58.1 57.7 116 115 77-128 1 14 Tetrachloroethene ug/L ND 50 50 65.3 59.3 131 119 36-155 10 14 Tetrahydrofuran ug/L ND 100 100 95.0 131 95 131 56-147 32 12 R1 Toluene ug/L ND 50 50 57.0 54.9 114 110 52-146 4 11 trans-1,2-Dichloroethene ug/L ND 50 50 57.2 63.7 114 127 61-152 11 14 trans-1,3-Dichloropropene ug/L ND 50 50 47.1 47.0 94 94 37-146 0 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 91.01 97.OJ 91 97 61-139 6 12 Trichloroethene ug/L ND 50 50 57.7 55.7 115 111 61-141 3 12 Trichlorofluoromethane ug/L ND 50 50 68.1 72.9 136 146 51-141 7 13 M1 Vinyl acetate ug/L ND 50 50 55.4 61.5 111 123 52-141 10 14 Vinyl chloride ug/L ND 50 50 49.4 54.8 99 110 22-156 11 26 Xylene (Total) ug/L ND 150 150 179 179 119 119 78-132 0 7 1,2-Dichloroethane-d4 (S) %. 108 124 81-119 SO 4-Bromofluorobenzene (S) %. 107 115 82-120 Dibromofluoromethane (S) %. 103 128 82-114 SO Toluene-d8 (S) %. 101 103 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 86 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19890 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 89600 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 12/31/18 12:04 1,1,1-Trichloroethane ug/L ND 1.0 0.38 12/31/18 12:04 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 12/31/18 12:04 1,1,2-Trichloroethane ug/L ND 1.0 0.59 12/31/18 12:04 1,1-Dichloroethane ug/L ND 5.0 0.41 12/31/18 12:04 1,1-Dichloroethene ug/L ND 5.0 0.72 12/31/18 12:04 1,2,3-Trichloropropane ug/L ND 1.0 0.46 12/31/18 12:04 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 12/31/18 12:04 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 12/31/18 12:04 1,2-Dichlorobenzene ug/L ND 5.0 0.49 12/31/18 12:04 1,2-Dichloroethane ug/L ND 1.0 0.67 12/31/18 12:04 1,2-Dichloropropane ug/L ND 1.0 0.60 12/31/18 12:04 1,4-Dichlorobenzene ug/L ND 1.0 0.58 12/31/18 12:04 2-Butanone (MEK) ug/L ND 100 3.2 12/31/18 12:04 2-Hexanone ug/L ND 50.0 0.89 12/31/18 12:04 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 12/31/18 12:04 Acetone ug/L ND 100 8.2 12/31/18 12:04 Acrylonitrile ug/L ND 200 2.5 12/31/18 12:04 Benzene ug/L ND 1.0 0.20 12/31/18 12:04 Bromochloromethane ug/L ND 3.0 0.50 12/31/18 12:04 Bromodichloromethane ug/L ND 1.0 0.36 12/31/18 12:04 Bromoform ug/L ND 3.0 0.55 12/31/18 12:04 Bromomethane ug/L ND 10.0 0.95 12/31/18 12:04 Carbon disulfide ug/L ND 100 0.79 12/31/18 12:04 Carbon tetrachloride ug/L ND 1.0 0.42 12/31/18 12:04 Chlorobenzene ug/L ND 3.0 0.53 12/31/18 12:04 Chloroethane ug/L ND 10.0 0.52 12/31/18 12:04 Chloroform ug/L ND 5.0 0.58 12/31/18 12:04 Chloromethane ug/L ND 1.0 0.38 12/31/18 12:04 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 12/31/18 12:04 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 12/31/18 12:04 Dibromochloromethane ug/L ND 1.0 0.31 12/31/18 12:04 Dibromomethane ug/L ND 10.0 0.62 12/31/18 12:04 Ethylbenzene ug/L ND 1.0 0.45 12/31/18 12:04 lodomethane ug/L ND 10.0 3.1 12/31/18 12:04 Methylene Chloride ug/L ND 1.0 0.50 12/31/18 12:04 Styrene ug/L ND 1.0 0.50 12/31/18 12:04 Tetrachloroethene ug/L ND 1.0 0.78 12/31/18 12:04 Tetrahydrofuran ug/L ND 10.0 1.3 12/31/18 12:04 Toluene ug/L ND 1.0 0.31 12/31/18 12:04 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 12/31/18 12:04 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 METHOD BLANK: 89600 Associated Lab Samples: Parameter Matrix: Water 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 12/31/18 12:04 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 12/31/18 12:04 Trichloroethene ug/L ND 1.0 0.34 12/31/18 12:04 Trichlorofluoromethane ug/L ND 1.0 0.51 12/31/18 12:04 Vinyl acetate ug/L ND 50.0 0.42 12/31/18 12:04 Vinyl chloride ug/L ND 1.0 0.60 12/31/18 12:04 Xylene (Total) ug/L ND 5.0 1.5 12/31/18 12:04 1,2-Dichloroethane-d4 (S) %. 103 81-119 12/31/18 12:04 4-Bromofluorobenzene (S) %. 103 82-120 12/31/18 12:04 Dibromofluoromethane (S) %. 97 82-114 12/31/18 12:04 Toluene-d8 (S) %. 99 82-109 12/31/18 12:04 LABORATORY CONTROL SAMPLE: 89601 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 49.7 99 68-137 1,1,1-Trichloroethane ug/L 50 57.7 115 72-134 1,1,2,2-Tetrachloroethane ug/L 50 47.6 95 51-158 1,1,2-Trichloroethane ug/L 50 49.0 98 78-131 1,1-Dichloroethane ug/L 50 51.3 103 69-151 1,1-Dichloroethene ug/L 50 53.6 107 64-158 1,2,3-Trichloropropane ug/L 50 44.2 88 78-133 1,2-Dibromo-3-chloropropane ug/L 50 43.8 88 58-124 1,2-Dibromoethane (EDB) ug/L 50 47.6 95 71-134 1,2-Dichlorobenzene ug/L 50 50.5 101 70-135 1,2-Dichloroethane ug/L 50 48.6 97 72-129 1,2-Dichloropropane ug/L 50 48.1 96 64-135 1,4-Dichlorobenzene ug/L 50 49.5 99 70-131 2-Butanone (MEK) ug/L 100 85.9J 86 52-143 2-Hexanone ug/L 100 90.6 91 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 100 100 71-129 Acetone ug/L 100 69.7J 70 48-224 Acrylonitrile ug/L 200 186J 93 66-154 Benzene ug/L 50 51.1 102 68-132 Bromochloromethane ug/L 50 52.6 105 73-133 Bromodichloromethane ug/L 50 47.6 95 67-121 Bromoform ug/L 50 46.2 92 57-125 Bromomethane ug/L 50 58.9 118 35-156 Carbon disulfide ug/L 100 117 117 47-141 Carbon tetrachloride ug/L 50 57.9 116 66-122 Chlorobenzene ug/L 50 49.5 99 71-126 Chloroethane ug/L 50 54.2 108 43-143 Chloroform ug/L 50 50.4 101 71-136 Chloromethane ug/L 50 50.2 100 47-123 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 LABORATORY CONTROL SAMPLE: 89601 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 51.7 103 74-131 cis-1,3-Dichloropropene ug/L 50 46.5 93 78-120 Dibromochloromethane ug/L 50 46.7 93 65-115 Dibromomethane ug/L 50 53.1 106 79-129 Ethylbenzene ug/L 50 52.5 105 68-129 lodomethane ug/L 100 111 111 49-154 Methylene Chloride ug/L 50 52.5 105 61-147 Styrene ug/L 50 48.7 97 77-128 Tetrachloroethene ug/L 50 50.9 102 51-139 Tetrahydrofuran ug/L 100 100 100 56-147 Toluene ug/L 50 50.1 100 60-133 trans-1,2-Dichloroethene ug/L 50 55.6 111 69-144 trans- 1,3-Dichloropropene ug/L 50 45.4 91 74-128 trans-1,4-Dichloro-2-butene ug/L 100 95AJ 95 61-139 Trichloroethene ug/L 50 50.1 100 73-126 Trichlorofluoromethane ug/L 50 57.2 114 55-132 Vinyl acetate ug/L 50 50.6 101 52-141 Vinyl chloride ug/L 50 52.3 105 50-133 Xylene (Total) ug/L 150 155 103 78-132 1,2-Dichloroethane-d4 (S) %. 101 81-119 4-Bromofluorobenzene (S) %. 92 82-120 Dibromofluoromethane (S) %. 109 82-114 Toluene-d8 (S) %. 101 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89602 89603 MS MSD 2613064002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 52.0 52.3 104 105 68-137 0 11 1,1,1-Trichloroethane ug/L ND 50 50 61.2 60.1 122 120 66-142 2 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 54.6 54.1 109 108 39-171 1 13 1,1,2-Trichloroethane ug/L ND 50 50 57.9 57.4 116 115 73-136 1 12 1,1-Dichloroethane ug/L ND 50 50 81.4 87.4 162 174 66-155 7 15 M1 1,1-Dichloroethene ug/L ND 50 50 62.5 63.7 125 127 33-181 2 34 1,2,3-Trichloropropane ug/L ND 50 50 46.6 46.0 93 92 78-133 1 14 1,2-Dibromo-3- ug/L ND 50 50 47.9 45.1 96 90 58-124 6 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.7 55.3 113 111 71-134 3 12 1,2-Dichlorobenzene ug/L ND 50 50 54.3 53.3 108 106 69-135 2 10 1,2-Dichloroethane ug/L ND 50 50 58.1 58.0 116 116 36-159 0 10 1,2-Dichloropropane ug/L ND 50 50 58.5 55.6 117 111 68-132 5 11 1,4-Dichlorobenzene ug/L 4.8 50 50 53.4 51.8 97 94 49-153 3 9 2-Butanone (MEK) ug/L ND 100 100 90.3J 88AJ 90 88 10-189 2 23 2-Hexanone ug/L ND 100 100 92.5 92.0 93 92 40-135 1 18 4-Methyl-2-pentanone ug/L ND 100 100 100 101 100 101 30-177 0 10 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 157 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89602 89603 MS MSD 2613064002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 100 100 74.7J 77.7J 75 78 44-223 4 14 Acrylonitrile ug/L ND 200 200 222 231 111 116 13-189 4 12 Benzene ug/L 1.5 50 50 59.5 58.6 116 114 66-139 2 10 Bromochloromethane ug/L ND 50 50 60.4 59.2 121 118 73-133 2 13 Bromodichloromethane ug/L ND 50 50 52.2 52.4 104 105 57-120 0 13 Bromoform ug/L ND 50 50 46.7 47.7 93 95 48-128 2 13 Bromomethane ug/L ND 50 50 57.6 59.1 115 118 10-187 3 32 Carbon disulfide ug/L ND 100 100 115 117 115 117 47-141 2 322 Carbon tetrachloride ug/L ND 50 50 60.7 60.3 121 121 58-127 1 14 Chlorobenzene ug/L 16.7 50 50 53.7 53.7 74 74 63-137 0 10 Chloroethane ug/L ND 50 50 50.5 52.2 101 104 52-146 3 16 Chloroform ug/L ND 50 50 56.6 56.2 113 112 74-137 1 9 Chloromethane ug/L ND 50 50 45.9 46.9 92 94 41-127 2 10 cis-1,2-Dichloroethene ug/L ND 50 50 79.6 78.8 158 157 71-138 1 16 M1 cis-1,3-Dichloropropene ug/L ND 50 50 49.6 48.4 99 97 32-145 2 12 Dibromochloromethane ug/L ND 50 50 50.7 50.0 101 100 52-116 1 13 Dibromomethane ug/L ND 50 50 63.9 62.4 128 125 79-129 2 14 Ethylbenzene ug/L ND 50 50 57.1 55.8 114 111 31-174 2 10 lodomethane ug/L ND 100 100 112 117 112 117 49-154 4 30 Methylene Chloride ug/L ND 50 50 62.5 63.4 125 127 61-146 1 15 Styrene ug/L ND 50 50 53.2 53.4 106 107 77-128 0 14 Tetrachloroethene ug/L ND 50 50 60.1 60.0 120 120 36-155 0 14 Tetrahydrofuran ug/L 8.3J 100 100 110 112 102 104 56-147 2 12 Toluene ug/L ND 50 50 57.4 56.6 114 113 52-146 1 11 trans-1,2-Dichloroethene ug/L ND 50 50 63.6 63.5 127 127 61-152 0 14 trans-1,3-Dichloropropene ug/L ND 50 50 46.2 45.4 92 91 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 96.5J 92.1J 96 92 61-139 5 12 Trichloroethene ug/L ND 50 50 60.7 59.1 121 118 61-141 3 12 Trichlorofluoromethane ug/L ND 50 50 55.7 56.4 111 113 51-141 1 13 Vinyl acetate ug/L ND 50 50 50.3 51.6 101 103 52-141 3 14 Vinyl chloride ug/L ND 50 50 48.7 51.1 97 102 22-156 5 26 Xylene (Total) ug/L ND 150 150 171 170 114 113 78-132 1 7 1,2-Dichloroethane-d4 (S) %. 100 101 81-119 4-Bromofluorobenzene (S) %. 94 91 82-120 Dibromofluoromethane (S) %. 108 110 82-114 Toluene-d8 (S) %. 100 101 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19560 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 METHOD BLANK: 88503 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 20000 12/24/18 10:13 LABORATORY CONTROL SAMPLE: 88504 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 101000 101 85-115 SAMPLE DUPLICATE: 88509 2612955001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 23.0 mg/L 23000 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19596 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 88593 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 20000 12/24/18 13:43 LABORATORY CONTROL SAMPLE: 88594 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 108000 108 85-115 SAMPLE DUPLICATE: 88595 2612903021 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 135000 141000 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19603 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 METHOD BLANK: 88609 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 10000 12/24/18 17:36 LABORATORY CONTROL SAMPLE: 88610 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 214000 107 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88611 88612 MS MSD 2612955002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 200000 200000 210000 198000 105 99 90-110 6 10 MATRIX SPIKE SAMPLE: 88617 2613007001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L ND 200000 208000 102 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19829 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 89329 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 10000 12/28/18 15:17 LABORATORY CONTROL SAMPLE: 89330 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 191000 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89331 89332 MS MSD 2613065015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 11.8 mg/L 200000 200000 194000 196000 91 92 90-110 1 10 MATRIX SPIKE SAMPLE: 89333 2612903023 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 30300 200000 214000 92 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19451 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2612903003 METHOD BLANK: 87899 Matrix: Water Associated Lab Samples: 2612903003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 200 200 12/21/1811:30 LABORATORY CONTROL SAMPLE: 87900 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 564 113 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 87901 87902 MS MSD 2612821001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 550 599 109 119 30-129 8 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19556 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2612903013, 2612903016, 2612903017, 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 88490 Matrix: Water Associated Lab Samples: 2612903013, 2612903016, 2612903017, 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfide ug/L ND 200 200 12/24/1813:56 LABORATORY CONTROL SAMPLE: 88491 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 596 119 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88492 88493 MS MSD 2613049001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 585 589 117 118 30-129 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19402 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 METHOD BLANK: 87561 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 12/26/18 11:24 LABORATORY CONTROL SAMPLE: 87563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 203000 103 85-115 SAMPLE DUPLICATE: 87564 2612997001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 5730 mg/L ND 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19512 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 88158 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 12/26/18 12:05 1A LABORATORY CONTROL SAMPLE: 88160 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 194000 98 85-115 1A SAMPLE DUPLICATE: 88275 2613072001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 25600 mg/L 23000000 11 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19315 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 METHOD BLANK: 87255 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L ND 50.0 5.0 12/21/18 00:32 LABORATORY CONTROL SAMPLE: 87256 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9740 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 87257 87258 MS MSD 2612939001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 4.3 mg/L 10000 10000 13700 13600 93 92 90-110 1 15 MATRIX SPIKE SAMPLE: 87608 2612939002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 3.6 mg/L 10000 13200 97 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19526 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 88213 Matrix: Water Associated Lab Samples: 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L ND 50.0 5.0 12/22/18 08:42 LABORATORY CONTROL SAMPLE: 88214 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9720 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88215 88216 MS MSD 2612903021 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 19.01 10000 10000 9700 9830 97 98 90-110 1 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19934 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903003, 2612903013, 2612903016 METHOD BLANK: 89763 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L ND 1000 24.0 01/02/1918:08 Sulfate ug/L ND 5000 17.0 01/02/1918:08 LABORATORY CONTROL SAMPLE: 89764 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9990 100 90-110 Sulfate ug/L 10000 9700 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89765 89766 MS MSD 2613077001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L ND 10000 10000 10300 792J 98 2 90-110 15 M1 Sulfate ug/L ND 10000 10000 11900 883J 93 -16 90-110 15 M1 MATRIX SPIKE SAMPLE: 89767 2613077002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L 2.3 mg/L 10000 12500 102 90-110 Sulfate ug/L 20.5 mg/L 10000 28900 84 90-110 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19935 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 89768 Matrix: Water Associated Lab Samples: 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L 79.OJ 1000 24.0 01/03/19 06:11 Sulfate ug/L ND 5000 17.0 01/03/19 06:11 LABORATORY CONTROL SAMPLE: 89769 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9980 100 90-110 Sulfate ug/L 10000 9740 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 89930 89931 MS MSD 2612903022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 49000 10000 10000 53900 54000 49 50 90-110 0 15 E,M1 Sulfate ug/L 6810 10000 10000 16900 17300 101 105 90-110 3 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 20006 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903021 METHOD BLANK: 90003 Matrix: Water Associated Lab Samples: 2612903021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L 91.01 1000 24.0 12/22/18 08:42 Sulfate ug/L ND 5000 17.0 12/22/18 08:42 LABORATORY CONTROL SAMPLE: 90004 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9720 97 90-110 Sulfate ug/L 10000 9720 97 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 20043 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2612903017 METHOD BLANK: 90182 Matrix: Water Associated Lab Samples: 2612903017 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chloride ug/L 82.OJ 1000 24.0 12/21/18 00:32 Sulfate ug/L ND 5000 17.0 12/21/18 00:32 LABORATORY CONTROL SAMPLE: 90183 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9800 98 90-110 Sulfate ug/L 10000 9540 95 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 157 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 QC Batch: 19499 Analysis Method: EPA 9060A QC Batch Method: EPA 9060A Analysis Description: 9060A Total Organic Carbon Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017, 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 METHOD BLANK: 88079 Matrix: Water Associated Lab Samples: 2612903003, 2612903013, 2612903016, 2612903017, 2612903021, 2612903022, 2612903023, 2612903024, 2612903025 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mean Total Organic Carbon ug/L ND 1000 1000 12/21/18 15:48 Total Organic Carbon ug/L ND 1000 1000 12/21/18 15:48 Total Organic Carbon ug/L ND 1000 1000 12/21/18 15:48 Total Organic Carbon ug/L ND 1000 1000 12/21/18 15:48 Total Organic Carbon ug/L ND 1000 1000 12/21/18 15:48 LABORATORY CONTROL SAMPLE: 88080 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon ug/L 20000 20600 103 88-112 Total Organic Carbon ug/L 20000 20600 103 88-112 Total Organic Carbon ug/L 20000 20600 103 88-112 Total Organic Carbon ug/L 20000 20600 103 88-112 Total Organic Carbon ug/L 20000 20600 103 88-112 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88081 88082 MS MSD 2612903003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L ND 20000 20000 20200 20200 100 100 67-141 0 14 Total Organic Carbon ug/L ND 20000 20000 20300 20100 100 99 67-141 1 14 Total Organic Carbon ug/L ND 20000 20000 20100 20300 99 100 67-141 1 14 Total Organic Carbon ug/L ND 20000 20000 20400 20200 100 99 67-141 1 14 Total Organic Carbon ug/L ND 20000 20000 20000 20300 99 100 67-141 1 14 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 157 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW'pacalabsxom (770)734-4200 QUALIFIERS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA BATCH QUALIFIERS Batch: 19631 The calculated seed correction was below the desired range of 0.6 to 1.0 mg/L. All other quality control indicators, including the LCS, are within acceptance criteria. ANALYTE QUALIFIERS 1A The calculated seed correction was below the desired range of 0.6 to 1.0 mg/L. All other quality control indicators, including the LCS, are within acceptance criteria. E Analyte concentration exceeded the calibration range. The reported result is estimated. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 157 11!;a'ceAna1j&a1" WNW'pecalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2612903001 1302-MWI 20106 2612903002 1302-MW1 20106 2612903003 1302-MW3 20106 2612903004 1302-MWB 20106 2612903005 1302-MWC 20106 2612903006 1302-MWD 20106 2612903007 1302-MWF 20106 2612903008 1302-MWG 20106 2612903009 1302-MWH 2O106 2612903010 1302-MWHdeep 20106 2612903011 1302-MWJ 20106 2612903012 1302-MWK 20106 2612903013 1302-MWL 20106 2612903014 1302-MWX 20106 2612903015 1302-C D4Rep 20106 2612903016 1302-AMW1s 20106 2612903017 1302-AMW1d 20106 2612903021 1302-MWA 20106 2612903022 1302-MWE Rep 20106 2612903023 1302-MWEdeep 20106 2612903024 1302-AMW2s 20106 2612903025 1302-AMW2d 20106 2612903001 1302-MWI EPA 3005A 19357 EPA 6020B 19406 2612903002 1302-MW1 EPA 3005A 19757 EPA 6020B 19775 2612903003 1302-MW3 EPA 3005A 19757 EPA 6020B 19775 2612903004 1302-MWB EPA 3005A 19757 EPA 6020B 19775 2612903005 1302-MWC EPA 3005A 19757 EPA 6020B 19775 2612903006 1302-MWD EPA 3005A 19757 EPA 6020B 19775 2612903007 1302-MWF EPA 3005A 19757 EPA 6020B 19775 2612903008 1302-MWG EPA 3005A 19757 EPA 6020B 19775 2612903009 1302-MWH EPA 3005A 19757 EPA 6020B 19775 2612903010 1302-MWHdeep EPA 3005A 19757 EPA 6020B 19775 2612903011 1302-MWJ EPA 3005A 19757 EPA 6020B 19775 2612903012 1302-MWK EPA 3005A 19757 EPA 6020B 19775 2612903013 1302-MWL EPA 3005A 19757 EPA 6020B 19775 2612903014 1302-MWX EPA 3005A 19757 EPA 6020B 19775 2612903015 1302-C D4Rep EPA 3005A 19757 EPA 6020B 19775 2612903016 1302-AMW1s EPA 3005A 19757 EPA 6020B 19775 2612903017 1302-AMW1d EPA 3005A 19757 EPA 6020B 19775 2612903018 1302-DUP2/3 EPA 3005A 19757 EPA 6020B 19775 2612903019 1302-EQBlank2/3 EPA 3005A 19757 EPA 6020B 19775 2612903021 1302-MWA EPA 3005A 19912 EPA 6020B 19927 2612903022 1302-MWE Rep EPA 3005A 19912 EPA 6020B 19927 2612903023 1302-MWEdeep EPA 3005A 19912 EPA 6020B 19927 2612903024 1302-AMW2s EPA 3005A 19912 EPA 6020B 19927 2612903025 1302-AMW2d EPA 3005A 19951 EPA 6020B 19977 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 157 11!;a'ceAna1j&a1" WNW'pecalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 2612903001 1302-MWI EPA 8260B Mod. 449723 2612903002 1302-MWI EPA 8260B Mod. 449397 2612903003 1302-MW3 EPA 8260B Mod. 449396 2612903004 1302-MWB EPA 8260B Mod. 449396 2612903005 1302-MWC EPA 8260B Mod. 449396 2612903006 1302-MWD EPA 8260B Mod. 449396 2612903007 1302-MWF EPA 8260B Mod. 449396 2612903008 1302-MWG EPA 8260B Mod. 449396 2612903009 1302-MWH EPA 8260B Mod. 449396 2612903010 1302-MWHdeep EPA 8260B Mod. 449396 2612903011 1302-MWJ EPA 8260B Mod. 449396 2612903012 1302-MWK EPA 8260B Mod. 449396 2612903013 1302-MWL EPA 8260B Mod. 449396 2612903014 1302-MWX EPA 8260B Mod. 449396 2612903015 1302-CD4Rep EPA 8260B Mod. 449396 2612903016 1302-AMW1s EPA 8260B Mod. 449396 2612903017 1302-AMWId EPA 8260B Mod. 449723 2612903018 1302-DUP2/3 EPA 8260B Mod. 449723 2612903019 1302-EQBIank2/3 EPA 8260B Mod. 449723 2612903020 1302-Trip Blank EPA 8260B Mod. 449723 2612903021 1302-MWA EPA 8260B Mod. 449944 2612903022 1302-MWE Rep EPA 8260B Mod. 449944 2612903023 1302-MWEdeep EPA 8260B Mod. 449944 2612903024 1302-AMW2s EPA 8260B Mod. 449944 2612903025 1302-AMW2d EPA 8260B Mod. 449944 2612903001 1302-MWI EPA 8260B 19774 2612903002 1302-MW1 EPA 8260B 19888 2612903003 1302-MW3 EPA 8260B 19888 2612903004 1302-MWB EPA 8260B 19888 2612903005 1302-MWC EPA 8260B 19888 2612903006 1302-MWD EPA 8260B 19888 2612903007 1302-MWF EPA 8260B 19888 2612903008 1302-MWG EPA 8260B 19888 2612903009 1302-MWH EPA 8260B 19888 2612903010 1302-MWHdeep EPA 8260B 19888 2612903011 1302-MWJ EPA 8260B 19888 2612903012 1302-MWK EPA 8260B 19888 2612903013 1302-MWL EPA 8260B 19888 2612903014 1302-MWX EPA 8260B 19888 2612903015 1302-CD4Rep EPA 8260B 19888 2612903016 1302-AMW 1 s EPA 8260B 19888 2612903017 1302-AMW1 d EPA 8260B 19888 2612903018 1302-DUP2/3 EPA 8260B 19888 2612903019 1302-EQBIank2/3 EPA 8260B 19888 2612903020 1302-Trip Blank EPA 8260B 19888 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch Page 108 of 157 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2612903 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2612903021 1302-MWA EPA 8260B 19890 2612903022 1302-MWE Rep EPA 8260B 19890 2612903023 1302-MWEdeep EPA 8260B 19890 2612903024 1302-AMW2s EPA 8260B 19890 2612903025 1302-AMW2d EPA 8260B 19890 2612903003 1302-MW3 SM 2320B 19560 2612903013 1302-MWL SM 2320B 19560 2612903016 1302-AMW1s SM 2320B 19560 2612903017 1302-AMW1d SM 2320B 19560 2612903021 1302-MWA SM 2320B 19596 2612903022 1302-MWE Rep SM 2320B 19596 2612903023 1302-MWEdeep SM 2320B 19596 2612903024 1302-AMW2s SM 2320B 19596 2612903025 1302-AMW2d SM 2320B 19596 2612903003 1302-MW3 EPA 410.4 19603 EPA 410.4 19615 2612903013 1302-MWL EPA 410.4 19603 EPA 410.4 19615 2612903016 1302-AMW1s EPA 410.4 19603 EPA 410.4 19615 2612903017 1302-AMW1d EPA 410.4 19603 EPA 410.4 19615 2612903021 1302-MWA EPA 410.4 19829 EPA 410.4 19849 2612903022 1302-MWE Rep EPA 410.4 19829 EPA 410.4 19849 2612903023 1302-MWEdeep EPA 410.4 19829 EPA 410.4 19849 2612903024 1302-AMW2s EPA 410.4 19829 EPA 410.4 19849 2612903025 1302-AMW2d EPA 410.4 19829 EPA 410.4 19849 2612903003 1302-MW3 SM 4500-S2 D 19451 2612903013 1302-MWL SM 4500-S2 D 19556 2612903016 1302-AMW1s SM 4500-S2 D 19556 2612903017 1302-AMW1d SM 4500-S2 D 19556 2612903021 1302-MWA SM 4500-S2 D 19556 2612903022 1302-MWE Rep SM 4500-S2 D 19556 2612903023 1302-MWEdeep SM 4500-S2 D 19556 2612903024 1302-AMW2s SM 4500-S2 D 19556 2612903025 1302-AMW2d SM 4500-S2 D 19556 2612903003 1302-MW3 SM 5210B 19402 SM 5210B 19629 2612903013 1302-MWL SM 5210B 19402 SM 5210B 19629 2612903016 1302-AMW1s SM 5210B 19402 SM 5210B 19629 2612903017 1302-AMW1d SM 5210B 19402 SM 5210B 19629 2612903021 1302-MWA SM 5210B 19512 SM 5210B 19631 2612903022 1302-MWE Rep SM 5210B 19512 SM 5210B 19631 2612903023 1302-MWEdeep SM 5210B 19512 SM 5210B 19631 2612903024 1302-AMW2s SM 5210B 19512 SM 5210B 19631 2612903025 1302-AMW2d SM 5210B 19512 SM 5210B 19631 2612903003 1302-MW3 EPA 9056A 19315 2612903013 1302-MWL EPA 9056A 19315 2612903016 1302-AMW 1 s EPA 9056A 19315 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /10/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 157 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2612903 Lab ID Sample ID QC Batch Method QC Batch 2612903017 1302-AMW1 d EPA 9056A 19315 2612903021 1302-MWA EPA 9056A 19526 2612903022 1302-MWE Rep EPA 9056A 19526 2612903023 1302-MWEdeep EPA 9056A 19526 2612903024 1302-AMW2s EPA 9056A 19526 2612903025 1302-AMW2d EPA 9056A 19526 2612903003 1302-MW3 EPA 9056A 19934 2612903013 1302-MWL EPA 9056A 19934 2612903016 1302-AMW 1 s EPA 9056A 19934 2612903017 1302-AMW1 d EPA 9056A 20043 2612903021 1302-MWA EPA 9056A 20006 2612903022 1302-MWE Rep EPA 9056A 19935 2612903023 1302-MWEdeep EPA 9056A 19935 2612903024 1302-AMW2s EPA 9056A 19935 2612903025 1302-AMW2d EPA 9056A 19935 2612903003 1302-MW3 EPA 9060A 19499 2612903013 1302-MWL EPA 9060A 19499 2612903016 1302-AMW 1 s EPA 9060A 19499 2612903017 1302-AMW1 d EPA 9060A 19499 2612903021 1302-MWA EPA 9060A 19499 2612903022 1302-MWE Rep EPA 9060A 19499 2612903023 1302-MWEdeep EPA 9060A 19499 2612903024 1302-AMW2s EPA 9060A 19499 2612903025 1302-AMW2d EPA 9060A 19499 Date: 01/10/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 110 of 157 N tV t�i J k � � � ..1.a N -► O *A V T on A W _ITEM_W O R e' 0 3 - � 7C 2 47 -� m N o � � � � y G O ci 0 mMONOSSON " ID , S N y P0 3 ' �r z N � e 1B ge-'sn Wq 77 7�zo O m !I� Z to o 0 n a 0 n a Wf Wf Wf Wf Wf Wi Wf Wf Wf Wf Wr MATRIX CODE see valid codes to left ( ) Wf F m # i o Q Q 0 G) SAMPLE TYPE (G=GRAB C=COMP) a) s m n o p to 1 y y A � ..�(({{ m 2 y� Z N z D a m m n m m m y a ° v � y v a i g m m 1 , SAMPLE TEMP AT COLLECTION ' C ;U # OF CONTAINERS y y- D n> n Unpreserved ^f -�o p m 3. m 0 \jam �r H2SO4 O M'd m m c HNO3 # d A HCI m o e m o O m NaOH Na2S2O3 N m Methanol Other Analyses Test Y/N r x X X x X X x X x x X x App, I VOC by 8260 3 x x H 6270 SVOC (Bis-2-eh)phtharn y X z 8 3 BOD 5-day, Alk, CI, NO3, S x COD a Sulfide by SM4500-S2-D X Total Organic Carbon " X Dissolved Gases (CO2, M, E� X Dissolved Gases (VFA) e Dissolved Gases (Hydrogen X 3 App. I Metals 4-1 Field Turb pH/CON/femp/furb/DO/OR z x x x x x x x x x x )c TEMP in C y Residual Chlorine (Y/N) z E Received on Ice D (Y/N) �j m n unto y Sealed Cooler O Y/N ' Samples Intact (YIN) m = �D Z o r c O 0 r^ C �< 'C^ N N �v p � oy c� 9 m� ,z D n < ((D :3 .Q lD (D En (A N 3 c in O m A 0 = 3 a n n m m Page 111 of 157 �vm d C,0 m ITEM # = c c m w m j c Q. s WW N WW N ((�� N WW N WW N ww N W N N WW Q 0 Cf D z7 d p m m g 0 3 3 V7 a .2 CDm 9 . N g? o 0 y O m m r -tea D� ��5 �3Z�3� 0 (A 3P '° r ID Er N 9; M 1 v z o " m N � � v C S � v �gPEo�19ff�$ ^f �gn=,� ;� 9 -D- o;mv N OybrZ �'OO N 3 O , m o a a VVT Vr Vr Vr Vr Vr Vr Vr Vr Vr Vr Vr MATRIX CODE (see valid codes to left) # y c £ SAMPLE TYPE (G=GRAB C=COMP) m 0 o w m m G 7 1 D A n 3 1 A j m o g �m D 1 y in n N N z 3 m m m I" U) , o D g0 z � i m SAMPLE TEMP AT COLLECTION m m y y D-77 o D # OF CONTAINERS 'C 3 Unpreserved -0-0 0 m 5 0 0 m H2SO4 p .. p e 0 HNO3 D # m m HCI m o w m NaOH m Na2S203 m m Methanol Other Analyses Test Y/N App. I VOC by 8260 Nr d H 8270 SVOC (Bis-2-eh)phlha m 8 Cn IG BOD 5-day, Alk, Cl, NO3, S -3 COD a SuHide by SM4500-S2-D Total Organic Carbon g Dissolved Gases (CO2, M. E� w � it � Dissolved Gases (VFA) g Dissolved Gases (Hydrogen x x x x x x x x x x x x App. I Metals 3 x x x x x x x x x x x x Field Turb � pH/CON/Temp/Turb/DO/OR TEMP in C is Residual Chlorine (Y/N) m Received on Ice D N (YIN) 'x Custody Sealed Cooler Y/N � Samples Y Intact (Y/N) ?n m = m 7 z o r y -/n Er♦/ C 'CA N N m 0 D 0 C) O a C 3 >y Z rZ D � m < ID .0 m ((D a y N M �a CT n O C v (D m 7 a to 0 c m ro Page 112 of 157 s �i mNM 7 3 O-ois F w ea -4 w a A w ITEM # 0;d I �W o .. Z v AN IQ 3 Ln A 3 3 3 3 0 3 F 3 3 w 3 i y " p nri 3 M xa x p m ma m m m p m m m o ry .0r n V: °DsD 1,j Nu3i PL m en M 3- Z (A" H14a U33 F q o ° R a o n -9 8 a c Cr = m 3 3 0 C S v 'n N 0 S C x x M• IC � T v �9mFsg Njn� {� sai X to F V V • • _ fQ'1 ,Zl A C y , N\ m # Z m o p G c 3 O OD ° \ MATRIX CODE (see valid codes to left) 4 a 3 m y 1+ C) o SAMPLE TYPE (G=GRAB C=COMP) m o D OM o 0 o of 'm o u, 3 p -yi -I M o n m 0 2 C) Z LD Z i r M mr p 0i N N a -4 Z A, 3 `!� `,� m y AC m 9 m 0 CA 3 W m 3 tit v r r r Z CIN SAMPLE TEMP AT COLLECTION _ (� C m # OF CONTAINERS Unpreserved D c� D g rr, a ° ? � I.e. 3 0 _' 1 -�,� "�.: ^1.i `�.� `IJ v-V M v v p N o H2SO4 M m m c n -D m HNO3 m HCI o l o T 0% 01 0% 0-1 Q, 7N A NaOH m W C Na2S203 H x �n 9 Methanol Other m M Analyses Test App. I VOC by 8260 YIN x x x x x x x x x x x x D BOD 5-day, Alk, Cl, NO3, S v m n N W COD 3 U2 n a • Sulfide by SM4500-S2-D Total Organic Carbon a Diss Gases (CO2, M, E. E) m N 1 g Nit Dissolved Gases (VFA) Diss Gases (Hydrogen) \ a App. I Metals Q x x x x x x x x x x x x I x x x x x x x x x x x x A 8260SIM 1,4-Dioxane Z Trip Blank_8260 Trip Blank_8260 SIM .9 x La TEMP in C � A Residual Chlorine (Y/N) n A c m ° Received on Ice (Y/N) g e D n usto y Sealed Cooler 0 Y/N Samples Intact (YIN) < M N M a y N p•' Cv a O m 0 0 C 0 3 M 0 ro r••q� CL 0 C m ro Page 113 of 157 id N ITEM # m 3 R a 0 a ' m m a 3 c ff 3 N a H m .. n r A. z -:5 n n M N m N N N N N N N N N N N m c 7 v p m �pn c> Zg C C G C G C G A 4 C3 C C3 7CC C3 c C3 c O/ A ^3 7 �, o � • � N a N m a i � n � �nsn N P') NN �3c 0v N aim N �3 o J 3 Cn � < ' w �_nm 3 ;d `�• c a x v w x S � � n O a 0 tlo w 92P.T s�f-a V n M M f v° � A mCm # y M R p� 6 [ 3 O v � n o MATRIX CODE (sae valid codes to left) m nm SAMPLETYPE (G=GRAB C=COMP) m o v 0 D m N 7 W0 C) z � m C_ z zz m 0 " z 3 _ ' o m p c� Cn m m 9 ° n1. z p 1 ` VA m A x 1 W\1 :'Q SAMPLE TEMP AT COLLECTION •`' "'hI -{.� •�{,( .� # OF CONTAINERS ACA to m m y n 4 j o n v v p y o n Unpreserved ' ^ vl fD � �' m c H2SO4 HNO3 -fl o 3:CD HCI m NaOH w F Na2S203 m Methanol m Other � Analyses Test Y/N App I VOC by 8260 x x x x x x x x x x x x m p v BOD 5-day, Alk, Cl, NO3, S m COD A �! � 8 SuKde by SM4500-S2-D M Total Organic Carbon a N Diss Gases (CO2, M, E. E) fY Dissolved Gases (VFA) N) .Q t Diss Gases (Hydrogen) O x x x x x Ix x x x x x x App. I Metals x x x x x x x x x x x x 82608IM 1,4-Dioxane Trip Blank_8260 . Trip Blank_8260 SIM TEMP in C toLO Residual Chlorine (Y/N) m z .. 0 R Received on Ice a N (Y/N) o a -Custody Sealed �/ Cooler O M Y/N Samples Intact N (Y/N) m � < CD m CD a y N ry, �v �o m n 0 O 3 CD m N ~ a fU 0 0 d m 1 Page 114 of 157 W W W W W W W N N N N N ITEM #; z v m;a > 0 M c A CI Ch A W N O W Oo -4 CI ch o - c, r a N i N N N 5 N M o s" Z � a; N N N N CN <N <N N N N M v •• N G r C ma G m G DC r3 3 vi a is (fit g y O W a N M T� A D D N IZ D 3, 3_ o All CD 3 m ? n `� i ��,rn 3 ,M N � 17 xv a a 0 m nSPa4Ng.f;? c o v m a n m A m # Z yM o 7 O a 3 m Q � o MATRIX CODE (see valid codes to left) o3i SAMPLE TYPE (G=GRAB C=COMP) m � y 0 o N r m r0 7 ZA C z D Z D m N w . 1 ^ N z3 �. m o m mCn > D D G Z O 3 3 1 m m m � SAMPLE TEMP AT COLLECTION X A I _ C m A N ` ` # OF CONTAINERS y y y a o D v v p 3 3 o j 1 9-3 9J Unpreserved m N? ^� -- '- 1 H2SO4 # m z e n HNO3 m s, 3CD HCl m o N N m w A NaOH Na2S203 MCn x Methanol (jam G', Other Analyses Test Y/N M 7G )< App. I VOC by 8260 m o $ Q >( >( >( >(x >(x >(x BOD 6-day, Alk, CI, NO3, S A m N x x x x x x x x x COD - y $ U2 3 x x x x x x x x x Sulfide by SM4500-S2-D- a x x x x x x x x x Total Organic Carbon N Diss Gases (CO2, M. E, E) m N x x x x x x x x x Dissolved Gases (VFA) x x x x x x x x x Diss Gases (Hydrogen) 7C >G >G App. I Metals m x x x x x x x x x 8260SIM 1,4-Dioxane z Trip Blank_8260 A w Trip Blank 8260 SIM TEMP in C Residual Chlorine (YIN) n m R c iu Received on Ice g 3 m D w (Y/N) g c a usto y Sealed Cooler YIN Samples Intact w (Y/N) sn CD = sD N Z c O N r O n /Cn N M O �v 0 OD C m, z D n CD ;1 < (D 3� m (D a (A Cn 'y Cv e.0 c n CD C o 3 CD m a Iv 0 0 c m m Page 115 of 157 vu... N.c vv..u.a.v.. Project10,01 — Courier: Fed Ex ❑ UPS ❑ USPS ❑ Client ❑Commercial ❑ Pace Other Optional Tracking #: v J l)� Proj. Due Date: l Proj. Name: Custody Seal on Coo er/Box Present: E4yes-----❑ no Seals intact: yes ❑ no Packing Material: ❑ Bubble Wrap Dgubble Bags ❑ None ❑ Other _ Thermometer Used f)-9-? _ Type of Ice: et Blue None ❑ Sampes on Ice, coolina wocess has beaun Biological Tissue is Frozen: Yes No Cooler Temperature g Date and In' f s f perso examining contents: Temp should be above freezing to 6-C Comments: Chain of Custody Present: ElYes []No El N/A 1, Chain of Custody Filled Out: Yes ❑No ❑N/A 2. Chain of Custody Relinquished: ffr� El No El N/A 3. Sampler Name & Signature on COC: =es ❑No ❑N/A 4. Samples Arrived within Hold Time: es El No El N/A 5, t Short Hold Time Analysis (<72hr): es ❑No ❑N/A 6. Rush Turn Around Time Requested: ❑Yes 2hlo ❑N/A 7, Sufficient Volume: es ❑No ❑N/A 8. Correct Containers Used: G"'s E]No ❑N/A g. -Pace Containers Used: es ❑No ❑N/A Containers Intact: Yes ❑No ❑N/A 10. Filtered volume received for Dissolved tests ❑Yes ❑No N/A 11. Sample Labels match COC: �es ❑No ❑N/A 12. & tUy -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. 0-YL 1s No ❑N/A 13. All containers needing preservation are found to be in 2 les �❑No ❑N/A compliance with EPA recommendation. Initial when Lot # of added exceptions:(VOA, oliform, TOC, O&G, WI-DRO (water) es ❑No completed preservative Samples checked for dechlorination: ❑Yes ❑No C N/A 14. Heads ace in VOA Vials ( >6mm): ❑Yes OLN6 ❑N/A 15. Trip Blank Present: Bl' . No ❑N/A 16. Trip Blank Custody Seals Present 5Kes []No ❑N/A Pace Trip Blank Lot # ifpurchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Page 116 of 157 F-ALLC003rev.3, 11 September2006 T d m m w+ d a E8 Ow E I.r H ai N cr �s? va Cp Q U J OW J N V «� Oo z C t S (WA) pelul seldweS N/ O Je!oop Pelees A n (WA) Z �I uo peyeoea (WA) -po140 lenp!sea cl m m O u! dW31 WIS 09Z9 )1ue19 du1 a 09Z8 Muel8 dpl X F euexo! 0 4'l WIS09Z8 X X X X X X X X X X X sleleW I'ddV X X X X X X X X X X X X (uGftPAH) MOO ssi0 X X I X X � O NAM 9ese9 PenlOSS!a X X X X (3 '3 ' W 'ZOO) sese9 ss!a X X X x N uocpe0 o!uedjo 1e101 X X X X O-ZS-0o"S Aq ep91nS X X X X X X X X (300 a X X X X EON to '4IV 'Aep-9 009 09Z9 Aq OOA I 'ddV $ X X X X X X X X X X X X NIA I"J. WSABUV J LAO .a IoueyleW 6OZSZBN o m Z HOeN IOH op L m d EONH -� 885 E # 5 m m m rosZH _ 5z�� ��88 F d pemeseldun `�'� N `� Q U a. a a SM3NItl1NOOd00 _ Wu NOUOT DID dW313ldWVS M f� �O W W xi o N Qa O of o 3 w LU .01.. J Z JLU W C W T i ' U m a CJ (dWOO-J B D-D) 3dA13ldVM Em s0)j Wei W sm— pq- a.$) 3000 xRl1tlW O F ' F a � z "' # S' gwz2tt33 &p 0553ami�3�d Or X � 3 s $o33a$a�asF �o G � N �' O O LL m Q pK G 7 n CD mm m Lu N o � E 9 C 6 r Q 4 aCL ai I H Z C9 O cli # W311 b m_ m E m h age 117 of 11 U a:Lu D d so U co C a E Va Ow E 4.0 W 032 Q c 0 > s,z C� Q U � 0 W j � T LL 4 O Z� a= s� V � a 0 N (WA) 1`l pelul seIdweS ,,. WA O Je100O J peleeS 6 n (WU N 2 �I uo peyeoea (NIA) suuO143 lenplsea m �a 1 0 u! dW31 WIS 09Z9 )luel9 dpl a o9Z8 7luel9 dul X X X X X X X X X X X X Fg � euex0l0 y't WIS09Z9 sletepy I 'ddV X X X x x x x x X x x X (ue8wpAH) sesBO ssla X x x x x ` I (VjM sesBO peAloesl0 x x x x x N (3 '9 'W 'ZOO) sese0 ss!0 X x X X X N uOgiBO a!UBBtO lino- X x x x x O-ZS-OOSYWS Act epwnS QE X X x X x Q0o X x xit S x x x a 'EON 'IO 'mry 'Aep-9 00t3 I>8Z9 (q OOA I 'ddV $ s5 x X x x x x x X X e! c WA wi sesAeUV lad ,a4,0 loue4tey4 m > £OZSZBN HORN IOH � mCL c m £ONH Z c m a m 1.OSZH psAisseldun a m a g g a F SHaNIV1N00 d0 U a a a N0110311001V dW313ldYM 1`n _ Q tu tu 2 w U) ti y LU V w Z 0 U ~ �_ F- tL R t7i U as m U(dW00=) co SWID-0) 3dA13ldWVS & o � � � � � � � � � � � � 6) (Bel at sapoo pit- gas) 3000 XINIV W IL 2 bi E . �1 m is 3 X3 s V/ 1 �o�3do�a�a`�bF go z 1 N Ic C L O LL c . . U 2 W�� $ J a 0 Z St IL V C E E N Q V t >?( 03 U rC11 m O m 2 13 U G U t; cli U G s c4i c4i t4i S" c4i c9i c4i c4i c4i c4i pw o �t a m� age118of1: g E •m . m E m S W311 R� SIC U O w a c r,Sample Condition Upon... , WO# : 2612903 Pace Analytical Client Name: T��� SMM Due Date: 01/08/19 �n 1�"l �� PM: CLIENT: CDM-Raleigh Courier: Fed Ex ❑ UPS ❑ USPS ❑' Client ❑Commercial ❑ Pace Other Tracking #: Custody Seal on Cooler/Box Present: l lyes/ ❑ no Seals intact: Packing Material: le/W Wrap ❑ u� bble Bags ❑ None El Other Thermometer Used /�' 1X ) _ Tvoe of ice: Vt. Blue yes ❑ no V1 iar Proj. Due Date: Proj. Name: None n Samoles on ice. coolina process has beaun Biological Tissue e s Frozen: Yes No Cooler Temperature g Date and Initials of perso examining contents: v j• Temp should be above freezing to 6°C Comments: Chain of Custody Present: es ONO El N/A 1. Chain of Custody Filled Out: -9-� 1s❑No [I N/A 2. Chain of Custody Relinquished: C -YeS El No [I N/A 3. Sampler Name & Signature on COC: CrYeS7 ❑No [I N/A 4. Samples Arrived within Hold Time: DeeS ONO ❑N/A 5. Short Hold Time Analysis (<72hr): Oyes o [)N,A 6 Rush Turn Around Time Requested: []Yes ❑ o ❑N,A 7. Sufficient Volume: Yes ONO ❑KA g Correct Containers Used: D�eg'S [IN. ❑N.A 9. -Pace Containers Used: es [:]No ❑r1,A Containers Intact: es ONO ❑N,A 10. Filtered volume received for Dissolved tests []Yes ❑No ❑ 11. Sample Labels match COC: es ❑No ❑NSA 12. �.:.�1✓ -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. (�❑No ❑NrA 13. All containers needing preservation are found to be in ❑❑No ❑N,A compliance with EPA recommendation. Initial when Lot # of added exceptions: A bliform, TOC, O&G, W!•DRO (water) es ❑N° completed preservative Sample ecked for dechlorination: Oyes ❑No qVe 14. Headspace in VOA Vials ( >6mm): []Yes ❑r1,A 15. Trip Blank Present: []Yes UNe—ON A Trip Blank Custody Seals Present Oyes ONO N,A Pace Trip Blank Lot # (if purchased). Client Notification/ Resolution: Person Contacted: Comments Resolution: Project Manager Review: DaterTime: Field Data Regwred9 Y N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) F•ALLC003rev 3. 11 Septemblya 9iCl19 of 157 Sample Condition Upon FaceAnaocal Client Name: (' Project # Courier: tj Fed Ex ❑ UPS ❑ USPS ❑ Client ❑Commercial ❑ Pace Other Tracking #: Custody Seal on Cooler/Box Present: yes ❑ no Seals intact: Dyes Packing Material: ❑ Bubble Wrap ❑Bubble Bags ❑ None ❑ Other Thprmnmptpr tJced n(�7_ Tvoe of Ice: Wet Blue None Optional Proj. Due Date: Proj. Name: El no n Samples on ice. coolina Drocess has beaun d Biological Tissue is Frozen: Yes No Cooler Temperature �� / Date and [nit i s of rs examining contents: 0 7 Temp should be above freezing to 6'C T Comments: Chain of Custody Present: ❑No ❑N/A 1. Chain of Custody Filled Out: 215s ONO ❑N/A 2. Chain of Custody Relinquished: ElYLIT ONO ❑N/A 3. Sampler Name & Signature on COC: es ❑No ❑N/A 4. Samples Arrived within Hold Time: es ONO ❑N/A 5. Short Hold Time Analysis <72hr : 9-re—s ONO ❑N/A 6. Rush Turn Around Time Requested: ❑Yes -BfTo— ❑N/A 7. Sufficient Volume: �s ONO ❑N/A 8. Correct Containers Used: 0e-s ONO ❑N/A g, -Pace Containers Used: s ❑No ❑N/A Containers Intact: ®�❑No ❑N/A 10. Filtered volume received for Dissolved tests Dyes ONO 11. Sample Labels match COC: ' t�(o ❑N/A 12. ruwg` -Includes date/time/ID/Analysis Matrix: G— All containers needing preservation have been checked. 121es ONO ❑NIA 13, All containers needing preservation are found to be in 1� ONO ❑N/A compliance with EPA recommendation. Initial when Lot # of added exceptions: XO oliform, TOC, O&G, WI-DRO (water) Qx-s ❑No completed preservative Samples checked for dechlorination: Dyes ONO 13N/A 14. Heads ace in VOA Vials ( >6mm): Dyes Ld o❑N/A 15. Trip Blank Present: Dyes Qm-o ❑N/A 1 . Trip Blank Custody Seals Present Dyes ONO /A Pace Trip Blank Lot # (ifpurchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) Page 120 of 157 F-ALLC003rev.3, 11September2006 ?ceAnalytical i January 7, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: 2612903 /CABARRUS CTY UNITS Pace Workorder. 29091 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory between Friday, December 21, 2018 and Thursday, December 27, 2018. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 01/07/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 37 Page 1 of 30 Page 121 of 157 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 30 Page 122 of 157 ?ceAnalytical i SAMPLE SUMMARY Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 290910001 1302-M W3 Water 12/19/2018 15:48 12/21/2018 11:35 290910002 1302-M WL Water 12/19/2018 16:10 12/21/2018 11:35 290910003 1302-AM W 1 S Water 12/19/2018 13:03 12/21/2018 11:35 290910004 1302-AM W 1 D Water 12/19/2018 13:21 12/21/2018 11:35 290910005 1302-MW3 Bubble Strip 12/19/2018 15:48 12/21/2018 11:35 290910006 1302-MWL Bubble Strip 12/19/2018 16:10 12/21/2018 11:35 290910007 1302-AMW1S Bubble Strip 12/19/2018 13:03 12/21/2018 11:35 290910008 1302-AMW1D Bubble Strip 12/19/2018 13:21 12/21/2018 11:35 290910009 1302-MWA Water 12/20/2018 10:35 12/27/2018 12:04 290910010 1302-MWA Bubble Strip 12/20/2018 10:35 12/27/2018 12:04 290910011 1302-MWE REP Water 12/20/2018 11:44 12/27/2018 12:04 290910012 1302-MWE REP Bubble Strip 12/20/2018 11:44 12/27/2018 12:04 290910013 1302-MWE deep Water 12/20/2018 13:31 12/27/2018 12:04 290910014 1302-MWE deep Bubble Strip 12/20/2018 13:31 12/27/2018 12:04 290910015 1302-AMW2s Water 12/20/2018 11:51 12/27/2018 12:04 290910016 1302-AMW2s Bubble Strip 12/20/2018 11:51 12/27/2018 12:04 290910017 1302-AMW2d Water 12/20/2018 12:34 12/27/2018 12:04 290910018 1302-AMW2d Bubble Strip 12/20/2018 12:34 12/27/2018 12:04 Report ID: 29091 - 1129325 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 30 Page 123 of 157 ?ceAnalytical @ PROJECT SUMMARY Workorder: 29091 2612903 /CABARRUS CTY UNITS Batch Comments Batch: EDON/3966 -Low Level Volatile Fatty Acids Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The matrix spike and/or spike duplicate, recovery or relative percent difference; accuracy influenced by the concentration of the reference sample 290900001. Analyte Lactic, Acetic, Propionic, Butyric and Pentanoic acids. Batch acceptance based on laboratory control sample recovery. Report ID: 29091 - 1129325 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 30 Page 124 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910001 Sample ID: 1302-MW3 Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 15:48 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 00:18 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 00:18 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 00:18 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 00:18 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 00:18 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 00:18 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 00:18 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 00:18 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 00:18 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 00:18 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane <0.50 ug/I 0.50 0.014 1 12/31/2018 07:36 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 07:36 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:36 BW n Carbon Dioxide 160 mg/I 5.0 0.12 1 12/31/2018 07:36 BW n Report ID: 29091 - 1129325 Page 5 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 125 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910002 Sample ID: 1302-MWL Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 16:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 01:14 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 01:14 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 01:14 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 01:14 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 01:14 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 01:14 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 01:14 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 01:14 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 01:14 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 01:14 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.93 ug/I 0.50 0.014 1 12/31/2018 07:46 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 07:46 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:46 BW n Carbon Dioxide 95 mg/I 5.0 0.12 1 12/31/2018 07:46 BW n Report ID: 29091 - 1129325 Page 6 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 126 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910003 Sample ID: 1302-AMW1S Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 13:03 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 02:11 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 02:11 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 02:11 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 02:11 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 02:11 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 02:11 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 02:11 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 02:11 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 02:11 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 02:11 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1600 ug/I 0.50 0.014 1 12/31/2018 07:56 BW n Ethane 0.24 ug/I 0.10 0.0070 1 12/31/2018 07:56 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:56 BW n Carbon Dioxide 260 mg/I 5.0 0.12 1 12/31/2018 07:56 BW n Report ID: 29091 - 1129325 Page 7 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 127 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910004 Sample ID: 1302-AMW1D Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 13:21 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 03:07 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 03:07 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 03:07 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 03:07 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 03:07 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 03:07 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 03:07 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 03:07 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 03:07 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 03:07 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3500 ug/I 0.50 0.014 1 12/31/2018 08:05 BW n Ethane 2.6 ug/I 0.10 0.0070 1 12/31/2018 08:05 BW n Ethene 1.5 ug/I 0.10 0.0050 1 12/31/2018 08:05 BW n Carbon Dioxide 360 mg/I 5.0 0.12 1 12/31/2018 08:05 BW n Report ID: 29091 - 1129325 Page 8 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 128 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910005 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-MW3 Date Collected: 12/19/2018 15:48 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 9.5 nM 1.0 0.65 1 12/27/201815:55 MM n Report ID: 29091 - 1129325 Page 9 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 129 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910006 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-MWL Date Collected: 12/19/2018 16:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 13 nM 1.0 0.65 1 12/27/201816:07 MM n Report ID: 29091 - 1129325 Page 10 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 130 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910007 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-AMW1S Date Collected: 12/19/2018 13:03 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 5.6 nM 1.0 0.65 1 12/27/201816:19 MM n Report ID: 29091 - 1129325 Page 11 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 131 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910008 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-AMW1D Date Collected: 12/19/2018 13:21 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 11 nM 1.0 0.65 1 12/27/201816:32 MM n Report ID: 29091 - 1129325 Page 12 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 132 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910009 Sample ID: 1302-MWA Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 04:03 KB M3,M5 Acetic Acid 0.22 mg/I 0.10 0.024 1 12/29/2018 04:03 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 04:03 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 04:03 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 04:03 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 04:03 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 04:03 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 04:03 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 04:03 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 04:03 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 7600 ug/I 0.50 0.014 1 12/31/2018 08:15 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:15 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:15 BW n Carbon Dioxide 600 mg/I 5.0 0.12 1 12/31/2018 08:15 BW n Report ID: 29091 - 1129325 Page 13 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 133 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910010 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWA Date Collected: 12/20/2018 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 110 nM 16 10 16 12/29/2018 05:40 TD d,n Report ID: 29091 - 1129325 Page 14 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 134 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910011 Sample ID: 1302-MWE REP Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 11:44 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 05:00 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 05:00 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 05:00 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 05:00 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 05:00 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 05:00 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 05:00 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 05:00 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 05:00 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 05:00 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 830 ug/I 0.50 0.014 1 12/31/2018 08:27 BW n Ethane 2.9 ug/I 0.10 0.0070 1 12/31/2018 08:27 BW n Ethene 0.63 ug/I 0.10 0.0050 1 12/31/2018 08:27 BW n Carbon Dioxide 380 mg/I 5.0 0.12 1 12/31/2018 08:27 BW n Report ID: 29091 - 1129325 Page 15 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 135 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910012 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWE REP Date Collected: 12/20/2018 11:44 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 13 nM 1.0 0.65 1 12/29/2018 03:44 TD n Report ID: 29091 - 1129325 Page 16 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 136 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910013 Sample ID: 1302-MWE deep Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 13:31 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 05:56 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 05:56 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 05:56 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 05:56 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 05:56 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 05:56 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 05:56 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 05:56 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 05:56 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 05:56 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 11000 ug/I 0.50 0.014 1 12/31/2018 08:37 BW n Ethane 6.6 ug/I 0.10 0.0070 1 12/31/2018 08:37 BW n Ethene 0.10 ug/I 0.10 0.0050 1 12/31/2018 08:37 BW n Carbon Dioxide 320 mg/I 5.0 0.12 1 12/31/2018 08:37 BW n Report ID: 29091 - 1129325 Page 17 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 137 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910014 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWE deep Date Collected: 12/20/2018 13:31 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 7.7 nM 1.0 0.65 1 12/29/2018 03:57 TD n Report ID: 29091 - 1129325 Page 18 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 138 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910015 Sample ID: 1302-AMW2s Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 11:51 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 06:52 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 06:52 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 06:52 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 06:52 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 06:52 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 06:52 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 06:52 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 06:52 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 06:52 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 06:52 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane <0.50 ug/I 0.50 0.014 1 12/31/2018 08:48 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:48 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:48 BW n Carbon Dioxide 160 mg/I 5.0 0.12 1 12/31/2018 08:48 BW n Report ID: 29091 - 1129325 Page 19 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 139 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910016 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-AMW2s Date Collected: 12/20/2018 11:51 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 12 nM 1.0 0.65 1 12/29/2018 04:10 TD n Report ID: 29091 - 1129325 Page 20 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 140 of 157 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910017 Sample ID: 1302-AMW2d Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 12:34 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 07:49 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 07:49 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 07:49 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 07:49 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 07:49 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 07:49 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 07:49 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 07:49 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 07:49 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 07:49 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 72 ug/I 0.50 0.014 1 12/31/2018 08:57 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:57 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:57 BW n Carbon Dioxide 240 mg/I 5.0 0.12 1 12/31/2018 08:57 BW n Report ID: 29091 - 1129325 Page 21 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 141 of 157 ?ceAnalytical I_1►/t I1111I[IllfnNIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910018 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-AMW2d Date Collected: 12/20/2018 12:34 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 16 nM 1.0 0.65 1 12/29/2018 04:24 TD n Report ID: 29091 - 1129325 Page 22 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 142 of 157 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. d The analyte concentration was determined from a dilution. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. M3 The matrix spike sample recovery was outside laboratory control limits. Report ID: 29091 - 1129325 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 23 of 30 Page 143 of 157 ?ceAnalytical QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7302 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910005, 290910006, 290910007, 290910008 METHOD BLANK: 59213 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 59214 59215 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Hydrogen nM 24 26 26 105 108 80-120 2.5 20 n Report ID: 29091 - 1129325 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 24 of 30 Page 144 of 157 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7303 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910001, 290910002, 290910003, 290910004, 290910009, 290910011, 290910013, 290910015, 290910017 METHOD BLANK: 59216 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I <0.50 0.50 n Ethane ug/I <0.10 0.10 n Ethene ug/I <0.10 0.10 n METHOD BLANK: 59217 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I <5.0 5.0 n LABORATORY CONTROL SAMPLE & LCSD: 59218 59220 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Methane ug/I 750 760 750 102 100 80-120 1.9 20 n Ethane ug/I 38 37 37 97 98 80-120 0.77 20 n Ethene ug/I 35 34 34 97 98 80-120 0.73 20 n LABORATORY CONTROL SAMPLE & LCSD: 59219 59221 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Carbon Dioxide mg/I 120 130 130 108 108 80-120 0.095 20 n Report ID: 29091 - 1129325 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 25 of 30 Page 145 of 157 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/3966 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 290910001, 290910002, 290910003, 290910004, 290910009, 290910011, 290910013, 290910015, 290910017 METHOD BLANK: 59234 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I <0.20 0.20 M3,M5 Acetic Acid mg/I <0.10 0.10 M3,M5 Propionic Acid mg/I <0.10 0.10 M3,M5 Formic Acid mg/I <0.20 0.20 B Butyric Acid mg/I <0.10 0.10 M3,M5 Pyruvic Acid mg/I <0.10 0.10 i-Pentanoic Acid mg/I <0.10 0.10 Pentanoic Acid mg/I <0.10 0.10 M3,M5 i-Hexanoic Acid mg/I <0.20 0.20 Hexanoic Acid mg/I <0.20 0.20 LABORATORY CONTROL SAMPLE: 59235 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers EDonors Lactic Acid mg/I 2 2.2 108 70-130 M3,M5 Acetic Acid mg/I 2 2.0 99 70-130 M3,M5 Propionic Acid mg/I 2 2.0 101 70-130 M3,M5 Formic Acid mg/I 2 2.0 103 70-130 B Butyric Acid mg/I 2 2.0 102 70-130 M3,M5 Pyruvic Acid mg/I 2 2.0 99 70-130 i-Pentanoic Acid mg/I 2 2.0 100 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 M3,M5 i-Hexanoic Acid mg/I 2 2.0 102 70-130 Hexanoic Acid mg/I 2 2.0 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 59236 59237 Original: 290900001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 1.1 20 7.3 6.8 31 28 70-130 6.9 30 d,M3,M5 Report ID: 29091 - 1129325 Page 26 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 146 of 157 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Units 59236 Original Result Spike Cone. 59237 MS Result MSD Result Original: MS % Rec 290900001 MSD % Rec % Rec Limit RPD Max RPD Qualifiers Acetic Acid mg/I 1300 20 <1.0 <1.0 -6350 -6350 70-130 0 30 d,M3,M5 Propionic Acid mg/I 720 20 <1.0 <1.0 -3610 -3610 70-130 0 30 d,M3,M5 Formic Acid mg/I 6.3 20 30 30 119 119 70-130 0.19 30 d,B Butyric Acid mg/I 170 20 160 160 -67 -72 70-130 0.63 30 d,M3,M5 Pyruvic Acid mg/I 6.3 20 25 25 92 92 70-130 0.19 30 d i-Pentanoic Acid mg/I 6.1 20 26 26 100 98 70-130 1.2 30 d Pentanoic Acid mg/I 140 20 130 130 -68 -77 70-130 1.4 30 d,M3,M5 i-Hexanoic Acid mg/I 0.7 20 18 17 87 82 70-130 5.2 30 d Hexanoic Acid mg/I 29 20 50 49 106 101 70-130 2.1 30 d Report ID: 29091 - 1129325 Page 27 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 147 of 157 ?ceAnalytical QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7305 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910010, 290910012, 290910014, 290910016, 290910018 METHOD BLANK: 59238 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 59239 59240 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Hydrogen nM 24 23 24 96 99 80-120 3 20 n Report ID: 29091 - 1129325 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 28 of 30 Page 148 of 157 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 29091 2612903 /CABARRUS CTY UNITS QUALITY CONTROL PARAMETER QUALIFIERS The analyte was detected in the associated blank. M3 The matrix spike sample recovery was outside laboratory control limits. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 29091 - 1129325 .==° �� CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 29 of 30 Page 149 of 157 ?ceAnalytical i QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 290910005 1302-MW3 AM20GAX DISG/7302 290910006 1302-MWL AM20GAX DISG/7302 290910007 1302-AMW1S AM20GAX DISG/7302 290910008 1302-AMW1D AM20GAX DISG/7302 290910001 1302-MW3 AM20GAX DISG/7303 290910002 1302-MWL AM20GAX DISG/7303 290910003 1302-AMW1S AM20GAX DISG/7303 290910004 1302-AMW1D AM20GAX DISG/7303 290910009 1302-MWA AM20GAX DISG/7303 290910011 1302-MWE REP AM20GAX DISG/7303 290910013 1302-MWE deep AM20GAX DISG/7303 290910015 1302-AMW2s AM20GAX DISG/7303 290910017 1302-AMW2d AM20GAX DISG/7303 290910001 1302-MW3 AM23G EDON/3966 290910002 1302-MWL AM23G EDON/3966 290910003 1302-AMW1 S AM23G EDON/3966 290910004 1302-AMW1 D AM23G EDON/3966 290910009 1302-MWA AM23G EDON/3966 290910011 1302-MWE REP AM23G EDON/3966 290910013 1302-MWE deep AM23G EDON/3966 290910015 1302-AMW2s AM23G EDON/3966 290910017 1302-AMW2d AM23G EDON/3966 290910010 1302-MWA AM20GAX DISG/7305 290910012 1302-MWE REP AM20GAX DISG/7305 290910014 1302-MWE deep AM20GAX DISG/7305 290910016 1302-AMW2s AM20GAX DISG/7305 290910018 1302-AMW2d AM20GAX DISG/7305 Report ID: 29091 - 1129325 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 30 of 30 Page 150 of 157 0ea 0 N ml w N m -a -0 --t -0 of) m 1 (D 5- (D In CDA i> (n p7 --4 CD :3 m 5, C) 0 0 0 CD (D (D N 3 - :3. Ccn 0 ro ('D :3 CD N. C:) m (D FD > m n C.0 CD 0 SD �n 0 3 0 0 0 r cc IV (D iZ3 cc F3 cc i,3 co co co co w m c, O z C7 0 0 3 w CD 00 0 CD — — N) — IQ — N) — N) — — 0 CD CD 0 CD CD w '3 w CD CD w w CD CS '57 CD L0V <. m W r CD z Unpreserved Cp V — — — CD 0 LD. — — — — — + — < CD 0 (D (D X x X X Sub Volatile Fatty Acids z C4 01 Cn 0 q 0 (D 0 I z C CO m 0 z (D 0) CD w 0 I w Ccb.� I. :t Page 154 of 157 I cn m -U -0 t -0 Cf) �x 0 0) 0 w 0 0 0 0 -1 (D 0 =7 (D w 77 0 > CD 0 (n - - Q n 0 -4 > > (D Z)O e C:) 0 -11 0 0 (D Q C�: �E C�: m m -0 cc :3 3 ' 3 Nj m;7 m CD . 0 a) -�, q - W 0 - rj (D 0 Nj C:) (0 > 0 (D w < 0 0 m 0 (OD rQ 0 3 0 0 0 0 w 0 F3 9 N (P N 2 N 2 1 5 d 21 w (Do 03 (D cn 0 c) 0 0 CD CD c') cn w rj "I. w rj w w P,) PI) w 1 c: — — — — — — — --- c) 0 — — — — — — — — --- — — — Unpreserved g w — — — — — — — — — — — — — — — --- — — — — — — — — — 0 — — — — — — — — — — — ---- BI >< X X >< X >< X X >< Sub Dissolved Carbon Dioxide CD LA I U, ci4 >c, ------------- Am — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — O — ------ — — — — — — ------ — — — — -- --------------- c (1) m 0 z E� 16- CT Page 152 of 157 3 0- 0 2- (n CD 0 10 I a I 91 I I P... 153 Cooler Receipt Form Client fume: Project: 'Lab Work Order: A. Shipping/Container information (circle appropriate response) Courier: ,�FedEx UPS USPS Client Other: Air bill Present" Yes No Tracking number: Custody Seal on Cooler/Box Present: Yes `� No;= Seals intact: Yes No Cooler/Box Packing Material: ,&0bble Wrap Absorbent Foam Other: Type of ice: /Wet�Blue None ice Intact: !Yes =Melted Cooler Temperature ` "" Radiation Screened: Yes /No � Chain of Custody Present. � Yes, No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES NO N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC ,Containers intact Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided PASS containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? Exception: VOA's coliform If yes, see pH form. Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Comments: F-PAE-Q-009-rev.01, 30ct2017 Cooler contents examined/received by: Date: Project Manager Review :_ Date ' - ) Page 154 of 157 Cooler Receipt Form Client Name r Project � Lab !Mork order: ' A. Shipping/Container Information (circle appropriate response) Courier ``Pedx UPS LISPS Client Other: Air bill Present Yes No Tracking Number: r ��` ( Custody Seal on Cooler/Box Present: tYes No Seals intact: jes No Cooler/Box Packing Material: Bubble Wrap Absorbent Foam Other: Type of Ice:�Wc Blue None ice Intact: ;Yes' Melted Cooler Temperature: Radiation Screened: Yes o) Chain of Custody Present: ;l' No Comments: B. Laboratory Assignment/Log-in (check appropriate response) — YES NO I N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC Containers intact Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided _ ,, PAES containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? If yes, see pH form. Exception: VOA's coliform Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Com F-PAE-Q-009-rev.01;. 3 Oct2017 Cooler contents examined/received by ©ate t' y J fi Project Manager Review Date Page 155 of 157 Date: NON-CONTORMANCE FORIA PASS Work Order Time of Receipt: Receiver: R 'ANCE: REASON FOR NON-COl",TFOR-b/ V CA - ACTION TAKEN: Client T-1-alne7 Customer Service laidals: ,F-PA-E-Q-0 I 4-rev,00, 20 Nov20 14 Date: Date: Time: - Page 156 of 157 Page I of 1 Ruth Welsh - 2612903 From: Ruth Welsh To: SukbouMcKenzie Subject: 2612903 I wanted to let you know that during login headspace was noted in one of the vials for the dissolved gases analyses for sample 1302-MWA Ruth Welsh Assistant General Manager Pace Analytical Energy Son/iceo, LLC 22OWilliam Pitt Way, Pittoburgh.PA1523D 412'828-2387(0)1412-200-8005(C) Page 1mm1m ab0n1:blozk I2/27/20I8 11!;a'ceAna1j&a( wmpacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 January 08, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory on December 19, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 19 11!;a'ceAna1j&a1" wmpacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Lab ID Sample ID Matrix Date Collected Date Received 2612904001 2612904002 1302-SW1 1302-SW2 Water Water 12/18/18 09:20 12/18/1811:00 12/19/18 10:20 12/19/1810:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2612904001 1302-SW1 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E RAC 51 PASI-GA 2612904002 1302-SW2 EPA 6020E CSW 15 PASI-GA EPA 8260B Mod. DLK 3 PASI-C EPA 8260E RAC 51 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Sample: 1302-SW1 Lab ID: 2612904001 Collected: 12/18/18 09:20 Received: 12/19/18 10:20 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Analytical Method: Field pH 7.6 Std. Units 1 01/08/19 14:34 Field Temperature 6.2 deg C 1 01/08/19 14:34 Field Specific 335.6 umhos/c 1 01/08/19 14:34 Conductance m Field Turbidity 18 NTU 1 01/08/19 14:34 Field Oxidation Potential -73.4 mV 1 01/08/19 14:34 Oxygen, Dissolved 10.1 mg/L 1 01/08/19 14:34 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.78 1 12/20/18 11:39 12/20/18 21:06 7440-36-0 Arsenic 0.70J ug/L 10.0 0.57 1 12/20/18 11:39 12/20/18 21:06 7440-38-2 Barium 57.6J ug/L 100 0.78 1 12/20/18 11:39 12/20/18 21:06 7440-39-3 Beryllium 0.052J ug/L 1.0 0.050 1 12/20/18 11:39 12/20/18 21:06 7440-41-7 Cadmium ND ug/L 1.0 0.093 1 12/20/18 11:39 12/20/18 21:06 7440-43-9 Chromium 1.8J ug/L 10.0 1.6 1 12/20/18 11:39 12/20/18 21:06 7440-47-3 Cobalt 2.6J ug/L 10.0 0.52 1 12/20/18 11:39 12/20/18 21:06 7440-48-4 Copper 2.OJ ug/L 10.0 1.3 1 12/20/18 11:39 12/20/18 21:06 7440-50-8 Lead 0.34J ug/L 10.0 0.27 1 12/20/18 11:39 12/20/18 21:06 7439-92-1 Nickel 4.4J ug/L 50.0 0.95 1 12/20/18 11:39 12/20/18 21:06 7440-02-0 Selenium ND ug/L 10.0 1.4 1 12/20/18 11:39 12/20/18 21:06 7782-49-2 Silver ND ug/L 10.0 0.95 1 12/20/18 11:39 12/20/18 21:06 7440-22-4 Thallium ND ug/L 5.5 0.14 1 12/20/18 11:39 12/20/18 21:06 7440-28-0 Vanadium 3.2J ug/L 25.0 1.9 1 12/20/18 11:39 12/20/18 21:06 7440-62-2 Zinc 4.9J ug/L 10.0 2.1 1 12/20/18 11:39 12/20/18 21:06 7440-66-6 8260 MSV SIM Analytical Method: EPA 8260E Mod. 1,4-Dioxane (p-Dioxane) 4.4 ug/L 2.0 1.9 1 12/27/18 19:36 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 100 % 50-150 1 12/27/18 19:36 17060-07-0 Toluene-d8 (S) 96 % 50-150 1 12/27/18 19:36 2037-26-5 8260B MSV Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/26/18 20:00 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/26/18 20:00 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/26/18 20:00 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/26/18 20:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/26/18 20:00 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/26/18 20:00 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/26/18 20:00 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/26/18 20:00 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/26/18 20:00 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/26/18 20:00 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/26/18 20:00 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/26/18 20:00 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/26/18 20:00 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 12/26/18 20:00 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Sample: 1302-SW1 Lab ID: 2612904001 Collected: 12/18/18 09:20 Received: 12/19/18 10:20 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 03:44 PM Analytical Method: EPA 8260E ND ug/L 13.0 0.55 1 12/26/18 20:00 96-12-8 ND ug/L 1.0 0.31 1 12/26/18 20:00 124-48-1 ND ug/L 2.0 0.28 1 12/26/18 20:00 106-93-4 ND ug/L 10.0 0.62 1 12/26/18 20:00 74-95-3 ND ug/L 5.0 0.49 1 12/26/18 20:00 95-50-1 ND ug/L 1.0 0.58 1 12/26/18 20:00 106-46-7 ND ug/L 100 1.6 1 12/26/18 20:00 110-57-6 ND ug/L 5.0 0.41 1 12/26/18 20:00 75-34-3 ND ug/L 1.0 0.67 1 12/26/18 20:00 107-06-2 ND ug/L 5.0 0.72 1 12/26/18 20:00 75-35-4 ND ug/L 5.0 0.66 1 12/26/18 20:00 156-59-2 ND ug/L 5.0 0.46 1 12/26/18 20:00 156-60-5 ND ug/L 1.0 0.60 1 12/26/18 20:00 78-87-5 ND ug/L 1.0 0.22 1 12/26/18 20:00 10061-01-5 ND ug/L 1.0 0.30 1 12/26/18 20:00 10061-02-6 ND ug/L 1.0 0.45 1 12/26/18 20:00 100-41-4 ND ug/L 50.0 0.89 1 12/26/18 20:00 591-78-6 ND ug/L 10.0 3.1 1 12/26/18 20:00 74-88-4 2.1 ug/L 1.0 0.50 1 12/26/18 20:00 75-09-2 ND ug/L 100 0.86 1 12/26/18 20:00 108-10-1 ND ug/L 1.0 0.50 1 12/26/18 20:00 100-42-5 ND ug/L 5.0 0.32 1 12/26/18 20:00 630-20-6 ND ug/L 1.0 0.53 1 12/26/18 20:00 79-34-5 ND ug/L 1.0 0.78 1 12/26/18 20:00 127-18-4 ND ug/L 1.0 0.31 1 12/26/18 20:00 108-88-3 ND ug/L 1.0 0.38 1 12/26/18 20:00 71-55-6 ND ug/L 1.0 0.59 1 12/26/18 20:00 79-00-5 ND ug/L 1.0 0.34 1 12/26/18 20:00 79-01-6 ND ug/L 1.0 0.51 1 12/26/18 20:00 75-69-4 ND ug/L 1.0 0.46 1 12/26/18 20:00 96-18-4 ND ug/L 50.0 0.42 1 12/26/18 20:00 108-05-4 ND ug/L 1.0 0.60 1 12/26/18 20:00 75-01-4 ND ug/L 5.0 1.5 1 12/26/18 20:00 1330-20-7 116 %. 81-119 1 12/26/18 20:00 17060-07-0 103 %. 82-114 1 12/26/18 20:00 1868-53-7 109 %. 82-120 1 12/26/18 20:00 460-00-4 94 %. 82-109 1 12/26/18 20:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Sample: 1302-SW2 Parameters Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 8260 MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260B MSV ANALYTICAL RESULTS Lab ID: 2612904002 Report Results Units Limit Collected: 12/ 18/ 18 11: 00 Reg. MDL Limit DF Received: 12/19/18 10:20 Matrix: Water Prepared Analytical Method: 7.2 Std. Units 1 6.4 deg C 1 266.6 umhos/c 1 m 19.3 NTU 1 21.1 mV 1 9.8 mg/L 1 Analytical Method: EPA 6020B Preparation Method: EPA 3005A Analyzed CAS No. Qual 01 /08/19 14:34 01 /08/19 14:34 01 /08/19 14:34 01 /08/19 14:34 01 /08/19 14:34 01/08/1914:34 7782-44-7 N2 ND ug/L 6.0 0.78 1 12/20/18 11:39 12/20/18 21:11 7440-36-0 0.63J ug/L 10.0 0.57 1 12/20/18 11:39 12/20/18 21:11 7440-38-2 71.8J ug/L 100 0.78 1 12/20/18 11:39 12/20/18 21:11 7440-39-3 0.11J ug/L 1.0 0.050 1 12/20/18 11:39 12/20/18 21:11 7440-41-7 ND ug/L 1.0 0.093 1 12/20/18 11:39 12/20/18 21:11 7440-43-9 1.9J ug/L 10.0 1.6 1 12/20/18 11:39 12/20/18 21:11 7440-47-3 1.8J ug/L 10.0 0.52 1 12/20/18 11:39 12/20/18 21:11 7440-48-4 1.9J ug/L 10.0 1.3 1 12/20/18 11:39 12/20/18 21:11 7440-50-8 0.91J ug/L 10.0 0.27 1 12/20/18 11:39 12/20/18 21:11 7439-92-1 3.1J ug/L 50.0 0.95 1 12/20/18 11:39 12/20/18 21:11 7440-02-0 ND ug/L 10.0 1.4 1 12/20/18 11:39 12/20/18 21:11 7782-49-2 ND ug/L 10.0 0.95 1 12/20/18 11:39 12/20/18 21:11 7440-22-4 ND ug/L 5.5 0.14 1 12/20/18 11:39 12/20/18 21:11 7440-28-0 4.3J ug/L 25.0 1.9 1 12/20/18 11:39 12/20/18 21:11 7440-62-2 3.6J ug/L 10.0 2.1 1 12/20/18 11:39 12/20/18 21:11 7440-66-6 Analytical Method: EPA 8260E Mod 2.5 ug/L 2.0 1.9 1 12/27/1819:55 123-91-1 101 % 50-150 1 12/27/1819:55 17060-07-0 97 % 50-150 1 12/27/1819:55 2037-26-5 Analytical Method: EPA 8260E Acetone ND ug/L 100 8.2 1 12/26/18 20:25 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 12/26/18 20:25 107-13-1 Benzene ND ug/L 1.0 0.20 1 12/26/18 20:25 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 12/26/18 20:25 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 12/26/18 20:25 75-27-4 Bromoform ND ug/L 3.0 0.55 1 12/26/18 20:25 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 12/26/18 20:25 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 12/26/18 20:25 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 12/26/18 20:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 12/26/18 20:25 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 12/26/18 20:25 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 12/26/18 20:25 75-00-3 Chloroform ND ug/L 5.0 0.58 1 12/26/18 20:25 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 12/26/18 20:25 74-87-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Sample: 1302-SW2 Lab ID: 2612904002 Collected: 12/18/18 11:00 Received: 12/19/18 10:20 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260B MSV 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 03:44 PM Analytical Method: EPA 8260E ND ug/L 13.0 0.55 1 12/26/18 20:25 96-12-8 ND ug/L 1.0 0.31 1 12/26/18 20:25 124-48-1 ND ug/L 2.0 0.28 1 12/26/18 20:25 106-93-4 ND ug/L 10.0 0.62 1 12/26/18 20:25 74-95-3 ND ug/L 5.0 0.49 1 12/26/18 20:25 95-50-1 ND ug/L 1.0 0.58 1 12/26/18 20:25 106-46-7 ND ug/L 100 1.6 1 12/26/18 20:25 110-57-6 ND ug/L 5.0 0.41 1 12/26/18 20:25 75-34-3 ND ug/L 1.0 0.67 1 12/26/18 20:25 107-06-2 ND ug/L 5.0 0.72 1 12/26/18 20:25 75-35-4 ND ug/L 5.0 0.66 1 12/26/18 20:25 156-59-2 ND ug/L 5.0 0.46 1 12/26/18 20:25 156-60-5 ND ug/L 1.0 0.60 1 12/26/18 20:25 78-87-5 ND ug/L 1.0 0.22 1 12/26/18 20:25 10061-01-5 ND ug/L 1.0 0.30 1 12/26/18 20:25 10061-02-6 ND ug/L 1.0 0.45 1 12/26/18 20:25 100-41-4 ND ug/L 50.0 0.89 1 12/26/18 20:25 591-78-6 ND ug/L 10.0 3.1 1 12/26/18 20:25 74-88-4 1.8 ug/L 1.0 0.50 1 12/26/18 20:25 75-09-2 ND ug/L 100 0.86 1 12/26/18 20:25 108-10-1 ND ug/L 1.0 0.50 1 12/26/18 20:25 100-42-5 ND ug/L 5.0 0.32 1 12/26/18 20:25 630-20-6 ND ug/L 1.0 0.53 1 12/26/18 20:25 79-34-5 ND ug/L 1.0 0.78 1 12/26/18 20:25 127-18-4 ND ug/L 1.0 0.31 1 12/26/18 20:25 108-88-3 ND ug/L 1.0 0.38 1 12/26/18 20:25 71-55-6 ND ug/L 1.0 0.59 1 12/26/18 20:25 79-00-5 ND ug/L 1.0 0.34 1 12/26/18 20:25 79-01-6 ND ug/L 1.0 0.51 1 12/26/18 20:25 75-69-4 ND ug/L 1.0 0.46 1 12/26/18 20:25 96-18-4 ND ug/L 50.0 0.42 1 12/26/18 20:25 108-05-4 ND ug/L 1.0 0.60 1 12/26/18 20:25 75-01-4 ND ug/L 5.0 1.5 1 12/26/18 20:25 1330-20-7 111 %. 81-119 1 12/26/18 20:25 17060-07-0 102 %. 82-114 1 12/26/18 20:25 1868-53-7 109 %. 82-120 1 12/26/18 20:25 460-00-4 98 %. 82-109 1 12/26/18 20:25 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 19 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 QC Batch: 19357 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2612904001, 2612904002 METHOD BLANK: 87374 Associated Lab Samples: Parameter 2612904001, 2612904002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.78 12/20/1818:31 Arsenic ug/L ND 10.0 0.57 12/20/1818:31 Barium ug/L ND 100 0.78 12/20/1818:31 Beryllium ug/L ND 1.0 0.050 12/20/1818:31 Cadmium ug/L ND 1.0 0.093 12/20/1818:31 Chromium ug/L ND 10.0 1.6 12/20/1818:31 Cobalt ug/L ND 10.0 0.52 12/20/1818:31 Copper ug/L ND 10.0 1.3 12/20/1818:31 Lead ug/L ND 10.0 0.27 12/20/1818:31 Nickel ug/L ND 50.0 0.95 12/20/1818:31 Selenium ug/L ND 10.0 1.4 12/20/1818:31 Silver ug/L ND 10.0 0.95 12/20/1818:31 Thallium ug/L ND 5.5 0.14 12/20/1818:31 Vanadium ug/L ND 25.0 1.9 12/20/1818:31 Zinc ug/L ND 10.0 2.1 12/20/1818:31 LABORATORY CONTROL SAMPLE: 87375 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 98.8 99 80-120 Arsenic ug/L 100 97.5 98 80-120 Barium ug/L 100 99.5J 100 80-120 Beryllium ug/L 100 94.6 95 80-120 Cadmium ug/L 100 95.2 95 80-120 Chromium ug/L 100 97.9 98 80-120 Cobalt ug/L 100 98.3 98 80-120 Copper ug/L 100 97.8 98 80-120 Lead ug/L 100 94.9 95 80-120 Nickel ug/L 100 98.0 98 80-120 Selenium ug/L 100 95.2 95 80-120 Silver ug/L 100 95.7 96 80-120 Thallium ug/L 100 97.7 98 80-120 Vanadium ug/L 100 99.5 100 80-120 Zinc ug/L 100 93.8 94 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 19 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Unit 1 MSW 2612904 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 87376 87377 MS MSD 2612867006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 104 99.5 104 100 75-125 4 20 Arsenic ug/L ND 100 100 103 103 102 102 75-125 0 20 Barium ug/L 797 100 100 910 890 113 93 75-125 2 20 Beryllium ug/L ND 100 100 97.3 95.5 97 95 75-125 2 20 Cadmium ug/L ND 100 100 99.5 100 99 100 75-125 0 20 Chromium ug/L ND 100 100 111 110 109 108 75-125 1 20 Cobalt ug/L ND 100 100 110 109 107 105 75-125 1 20 Copper ug/L ND 100 100 99.8 101 99 100 75-125 1 20 Lead ug/L ND 100 100 95.8 94.8 95 94 75-125 1 20 Nickel ug/L ND 100 100 106 105 104 103 75-125 1 20 Selenium ug/L ND 100 100 105 101 103 99 75-125 3 20 Silver ug/L ND 100 100 97.9 94.6 98 95 75-125 3 20 Thallium ug/L ND 100 100 97.8 98.5 98 99 75-125 1 20 Vanadium ug/L ND 100 100 115 115 111 112 75-125 0 20 Zinc ug/L ND 100 100 108 108 100 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 19 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 QC Batch: 449723 Analysis Method: EPA 8260B Mod. QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM Associated Lab Samples: 2612904001, 2612904002 METHOD BLANK: 2461845 Matrix: Water Associated Lab Samples: 2612904001, 2612904002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.9 12/27/18 11:13 1,2-Dichloroethane-d4 (S) % 95 50-150 12/27/18 11:13 Toluene-d8 (S) % 94 50-150 12/27/18 11:13 LABORATORY CONTROL SAMPLE: 2461846 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.2 101 71-125 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8 (S) % 93 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2461847 2461848 MS MSD 2612903017 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 23.1 22.1 115 110 50-150 5 30 1,2-Dichloroethane-d4 (S) % 103 102 50-150 30 Toluene-d8 (S) % 97 98 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 19 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 QC Batch: 19682 Analysis Method: EPA 8260B QC Batch Method: EPA 8260E Analysis Description: 8260E MSV Associated Lab Samples: 2612904001, 2612904002 METHOD BLANK: 88800 Associated Lab Samples: 2612904001, 2612904002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 12/26/18 11:43 1,1,1-Trichloroethane ug/L ND 1.0 0.38 12/26/18 11:43 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 12/26/18 11:43 1,1,2-Trichloroethane ug/L ND 1.0 0.59 12/26/18 11:43 1,1-Dichloroethane ug/L ND 5.0 0.41 12/26/18 11:43 1,1-Dichloroethene ug/L ND 5.0 0.72 12/26/18 11:43 1,2,3-Trichloropropane ug/L ND 1.0 0.46 12/26/18 11:43 1,2-Dibromo-3-chloropropane ug/L ND 13.0 0.55 12/26/18 11:43 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 12/26/18 11:43 1,2-Dichlorobenzene ug/L ND 5.0 0.49 12/26/18 11:43 1,2-Dichloroethane ug/L ND 1.0 0.67 12/26/18 11:43 1,2-Dichloropropane ug/L ND 1.0 0.60 12/26/18 11:43 1,4-Dichlorobenzene ug/L ND 1.0 0.58 12/26/18 11:43 2-Butanone (MEK) ug/L ND 100 3.2 12/26/18 11:43 2-Hexanone ug/L ND 50.0 0.89 12/26/18 11:43 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 12/26/18 11:43 Acetone ug/L ND 100 8.2 12/26/18 11:43 Acrylonitrile ug/L ND 200 2.5 12/26/18 11:43 Benzene ug/L ND 1.0 0.20 12/26/18 11:43 Bromochloromethane ug/L ND 3.0 0.50 12/26/18 11:43 Bromodichloromethane ug/L ND 1.0 0.36 12/26/18 11:43 Bromoform ug/L ND 3.0 0.55 12/26/18 11:43 Bromomethane ug/L ND 10.0 0.95 12/26/18 11:43 Carbon disulfide ug/L ND 100 0.79 12/26/18 11:43 Carbon tetrachloride ug/L ND 1.0 0.42 12/26/18 11:43 Chlorobenzene ug/L ND 3.0 0.53 12/26/18 11:43 Chloroethane ug/L ND 10.0 0.52 12/26/18 11:43 Chloroform ug/L ND 5.0 0.58 12/26/18 11:43 Chloromethane ug/L ND 1.0 0.38 12/26/18 11:43 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 12/26/18 11:43 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 12/26/18 11:43 Dibromochloromethane ug/L ND 1.0 0.31 12/26/18 11:43 Dibromomethane ug/L ND 10.0 0.62 12/26/18 11:43 Ethylbenzene ug/L ND 1.0 0.45 12/26/18 11:43 lodomethane ug/L ND 10.0 3.1 12/26/18 11:43 Methylene Chloride ug/L ND 1.0 0.50 12/26/18 11:43 Styrene ug/L ND 1.0 0.50 12/26/18 11:43 Tetrachloroethene ug/L ND 1.0 0.78 12/26/18 11:43 Toluene ug/L ND 1.0 0.31 12/26/18 11:43 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 12/26/18 11:43 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 12/26/18 11:43 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 19 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 METHOD BLANK: 88800 Associated Lab Samples: Parameter 2612904001, 2612904002 Units Matrix: Blank Result Water Reporting Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 100 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 50.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 5.0 1,2-Dichloroethane-d4 (S) %. 111 81-119 4-Bromofluorobenzene (S) %. 111 82-120 Dibromofluoromethane (S) %. 103 82-114 Toluene-d8 (S) %. 97 82-109 Analyzed 1.6 12/26/18 11:43 0.34 12/26/18 11:43 0.51 12/26/18 11:43 0.42 12/26/18 11:43 0.60 12/26/18 11:43 1.5 12/26/18 11:43 12/26/18 11:43 12/26/18 11:43 12/26/18 11:43 12/26/18 11:43 LABORATORY CONTROL SAMPLE: Parameter 88801 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 53.5 107 68-137 1,1,1-Trichloroethane ug/L 50 54.2 108 72-134 1,1,2,2-Tetrachloroethane ug/L 50 64.5 129 51-158 1,1,2-Trichloroethane ug/L 50 59.2 118 78-131 1,1-Dichloroethane ug/L 50 65.5 131 69-151 1,1-Dichloroethene ug/L 50 60.5 121 64-158 1,2,3-Trichloropropane ug/L 50 52.8 106 78-133 1,2-Dibromo-3-chloropropane ug/L 50 53.7 107 58-124 1,2-Dibromoethane (EDB) ug/L 50 59.4 119 71-134 1,2-Dichlorobenzene ug/L 50 57.3 115 70-135 1,2-Dichloroethane ug/L 50 62.5 125 72-129 1,2-Dichloropropane ug/L 50 62.1 124 64-135 1,4-Dichlorobenzene ug/L 50 56.1 112 70-131 2-Butanone (MEK) ug/L 100 133 133 52-143 2-Hexanone ug/L 100 96.1 96 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 107 107 71-129 Acetone ug/L 100 112 112 48-224 Acrylonitrile ug/L 200 218 109 66-154 Benzene ug/L 50 57.8 116 68-132 Bromochloromethane ug/L 50 62.0 124 73-133 Bromodichloromethane ug/L 50 55.0 110 67-121 Bromoform ug/L 50 49.9 100 57-125 Bromomethane ug/L 50 57.6 115 35-156 Carbon disulfide ug/L 100 93.3J 93 47-141 Carbon tetrachloride ug/L 50 59.2 118 66-122 Chlorobenzene ug/L 50 54.2 108 71-126 Chloroethane ug/L 50 50.8 102 43-143 Chloroform ug/L 50 61.1 122 71-136 Chloromethane ug/L 50 53.7 107 47-123 cis-1,2-Dichloroethene ug/L 50 60.8 122 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 19 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW pacalabs.com (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 LABORATORY CONTROL SAMPLE: Parameter 88801 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 54.1 108 78-120 Dibromochloromethane ug/L 50 53.3 107 65-115 Dibromomethane ug/L 50 58.7 117 79-129 Ethylbenzene ug/L 50 56.5 113 68-129 lodomethane ug/L 100 121 121 49-154 Methylene Chloride ug/L 50 58.7 117 61-147 Styrene ug/L 50 63.9 128 77-128 Tetrachloroethene ug/L 50 48.2 96 51-139 Toluene ug/L 50 57.5 115 60-133 trans-1,2-Dichloroethene ug/L 50 63.2 126 69-144 trans- 1,3-Dichloropropene ug/L 50 51.8 104 74-128 trans-1,4-Dichloro-2-butene ug/L 100 103 103 61-139 Trichloroethene ug/L 50 55.3 111 73-126 Trichlorofluoromethane ug/L 50 56.3 113 55-132 Vinyl acetate ug/L 50 63.6 127 52-141 Vinyl chloride ug/L 50 53.8 108 50-133 Xylene (Total) ug/L 150 179 120 78-132 1,2-Dichloroethane-d4 (S) %. 115 81-119 4-Bromofluorobenzene (S) %. 111 82-120 Dibromofluoromethane (S) %. 117 82-114 SO Toluene-d8 (S) %. 95 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88802 2612867003 Parameter Units Result MS Spike Conc. MSD Spike Conc. 88803 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits Max RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 49.8 48.5 100 97 68-137 3 11 1,1,1-Trichloroethane ug/L ND 50 50 55.1 56.3 110 113 66-142 2 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 57.8 57.2 116 114 39-171 1 13 1,1,2-Trichloroethane ug/L ND 50 50 55.7 54.6 111 109 73-136 2 12 1,1-Dichloroethane ug/L ND 50 50 49.7 49.3 99 99 66-155 1 15 1,1-Dichloroethene ug/L ND 50 50 64.1 68.4 128 137 33-181 7 34 1,2,3-Trichloropropane ug/L ND 50 50 44.6 43.7 89 87 78-133 2 14 1,2-Dibromo-3- ug/L ND 50 50 45.8 46.0 92 92 58-124 1 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 54.7 54.0 109 108 71-134 1 12 1,2-Dichlorobenzene ug/L ND 50 50 53.7 53.3 107 107 69-135 1 10 1,2-Dichloroethane ug/L ND 50 50 58.5 58.1 117 116 36-159 1 10 1,2-Dichloropropane ug/L ND 50 50 59.6 58.0 119 116 68-132 3 11 1,4-Dichlorobenzene ug/L ND 50 50 52.9 51.9 106 104 49-153 2 9 2-Butanone (MEK) ug/L ND 100 100 112 108 112 108 10-189 3 23 2-Hexanone ug/L ND 100 100 89.2 87.6 89 88 40-135 2 18 4-Methyl-2-pentanone ug/L ND 100 100 97.9J 96.8J 98 97 30-177 1 10 (MIBK) Acetone ug/L ND 100 100 76.7J 79.5J 77 79 44-223 3 14 Acrylonitrile ug/L ND 200 200 204 204 102 102 13-189 0 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 19 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 88802 88803 MS MSD 2612867003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Benzene ug/L ND 50 50 58.3 57.2 117 114 66-139 2 10 Bromochloromethane ug/L ND 50 50 59.3 57.2 119 114 73-133 4 13 Bromodichloromethane ug/L ND 50 50 49.7 50.6 99 101 57-120 2 13 Bromoform ug/L ND 50 50 40.7 41.3 81 83 48-128 1 13 Bromomethane ug/L ND 50 50 54.1 56.5 108 113 10-187 4 32 Carbon disulfide ug/L ND 100 100 92.6J 97.6J 93 98 47-141 5 322 Carbon tetrachloride ug/L ND 50 50 63.6 64.8 127 130 58-127 2 14 M1 Chlorobenzene ug/L ND 50 50 54.6 52.8 109 106 63-137 3 10 Chloroethane ug/L ND 50 50 49.9 52.6 100 105 52-146 5 16 Chloroform ug/L ND 50 50 59.7 58.5 119 117 74-137 2 9 Chloromethane ug/L ND 50 50 54.5 56.7 109 113 41-127 4 10 cis-1,2-Dichloroethene ug/L ND 50 50 59.2 57.0 118 114 71-138 4 16 cis-1,3-Dichloropropene ug/L ND 50 50 48.6 49.1 97 98 32-145 1 12 Dibromochloromethane ug/L ND 50 50 47.0 46.3 94 93 52-116 2 13 Dibromomethane ug/L ND 50 50 54.1 54.7 108 109 79-129 1 14 Ethylbenzene ug/L ND 50 50 58.8 57.7 118 115 31-174 2 10 lodomethane ug/L ND 100 100 97.7 114 98 114 49-154 15 30 Methylene Chloride ug/L ND 50 50 54.3 54.7 109 109 61-146 1 15 Styrene ug/L ND 50 50 60.7 60.0 121 120 77-128 1 14 Tetrachloroethene ug/L ND 50 50 51.4 51.2 103 102 36-155 0 14 Toluene ug/L ND 50 50 59.2 57.6 118 115 52-146 3 11 trans-1,2-Dichloroethene ug/L ND 50 50 64.1 63.0 128 126 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 44.1 44.8 88 90 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 84.1J 83AJ 84 83 61-139 1 12 Trichloroethene ug/L ND 50 50 56.4 56.1 113 112 61-141 1 12 Trichlorofluoromethane ug/L ND 50 50 67.6 71.1 135 142 51-141 5 13 M1 Vinyl acetate ug/L ND 50 50 52.7 47.9J 105 96 52-141 10 14 Vinyl chloride ug/L ND 50 50 58.1 62.2 116 124 22-156 7 26 Xylene (Total) ug/L ND 150 150 183 178 122 119 78-132 3 7 1,2-Dichloroethane-d4 (S) %. 112 114 81-119 4-Bromofluorobenzene (S) %. 111 112 82-120 Dibromofluoromethane (S) %. 113 115 82-114 SO Toluene-d8 (S) %. 97 97 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter. SO Surrogate recovery outside laboratory control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 03:44 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 19 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Unit 1 MSW Pace Project No.: 2612904 Lab ID Sample ID QC Batch Method QC Batch 2612904002 1302-SW2 20106 2612904001 1302-SW1 EPA 3005A 19357 2612904002 1302-SW2 EPA 3005A 19357 2612904001 1302-SW1 EPA 8260B Mod. 449723 2612904002 1302-SW2 EPA 8260B Mod. 449723 2612904001 1302-SW1 EPA 8260B 19682 2612904002 1302-SW2 EPA 8260B 19682 Date: 01/08/2019 03:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method EPA 6020B EPA 6020B Analytical Batch 19406 19406 Page 17 of 19 WO l777 _S }1u.rx.aG U(NIx) euiaiU3!snOlvOU 1 R m a Ln co `9 F j 2 ti V [] `} *^+lu I I I 1 12 a A a y a � N [7 E E N N $ cr m euexp!Q•q'i 4Yi509Z9 %C w � r ddv SIGIOVi x x x x x x x x n q 09N Act 30A x x x x x x x x N/A 3sa1 sasRfeuy.:` a 'i'. m JaUlO LU F- lounuieW w Oj EOZSZek MOON •! Ci Q❑ � z CONH U ? S m hOSZH s F— N o$ C y o a as perueseidu[; 5W� � pppy 0 c¢ 4 a Sa3NItl1N97 d9 N Isi, ': N0110311001tldm3131dNVS �� r a w w U a a u 2 i Z a ❑ ~ L [� Z N N Q= 2 a O D 2 N A W h W m W 1 h LU O: z 2 a e C] w 0 YLp U Idwoo-� adao-�t 3d1513'1d Nf'd5 �• .O g (LM of soAm pgQn Gssl 3407vI:rIvYf ] d0 c m 5 ¢ W a r° • r E E V � Page 18 of 19 a s a s # W 311 Face ARalyfical .. .. W0# : ? 512904 Client Name: jj PM: SMM Due Date: 01/08/19 CLIENT- Cf�M-Raleigh Courier: Fed Ex ❑ UPS ❑ USPS [:]Client ❑Commercial ❑ Pace Other Tracking #: _ C o� �� Custody Seal on Cooler/Box Present: t yes ❑ no Seals intact: ❑ yes Packing Material: le WWrap ❑ u� bble Sags ❑ None ❑ Other /no -1 .a)fl 61� Proj. Due Date: Froj, Name: ❑ no M c..--T-J __ r•..f Ii- --- hoc hnnifn 1 IIC1ilulllcacl u.�cu •�N•. .i• •v... i•Z-� •-•--� •--•- - ❑et and Initials a examining r Cooler Temperature Biological Tissue g is Frozen: Yes No �erso c ntents: r '' Tamp should be above freezing to BIC Comments: Chain of Custody Present: EKes ©No E]N A 1. Chain of Custody Filled Out: �❑No ❑NIA 2. Chain of Custody Relinquished: C3rrs ONO ❑NIA 3, Sampler name 81 Signature on COG: try ON. ❑NIA 4. Samples Arrived within Hold Time: es LINO ❑NIA 5. Short Hold Time Anal sis {¢72hr): Oyes aEjNiA 6, Rush Turn Around Time Requested: ❑Yes ❑ o ❑NIA 7. Sufficient Volume: 21 es ❑N❑ ❑NIA 8. Correct Containers Used: � ❑No ❑WA 9. -Pace Containers Used: Wes ❑No ❑NIA Containers Intact: 15es ON. ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑No 0WX 11. Sample Labels match COC: OY9's� ❑No El 12. -Includes dateltime11D1Anal sis Matrix: All containers needing preservation have bean checked. �E]No J©NIA 13, All containers needing preservation are found to be In compliance with EPA recommendation. 9X- ❑No ❑N)A exceptions: A -form, TOC. OBG. WI.ORO {water) es IJNO Initial when completed p Lot of added pres rvative Sam le ecked for de chlorination: ❑yes ONO 14. Heads ace in VOA Vials -- -1): Dyes ©NIA 15 Trip Blank Present: ❑YeS ��N/A , Trip Blank Custody Seals Present Oyes ONO NIA Pace Trio Blank Lot # (i6 purchased): Client Notification/ Resolution: Person Contacted: Date/Time: Fiel Data Required? y I N Comments/ Resolution - Project Manager Review: Date: Note: Whenever there Is a discrepancy affecting North Carolina compliance samples• a copy of this form will be s nt to the North Carolina DEHNR Certification Office ( i.e. Out of hold, incorrect preservative, out of temp, incorrect containers) Page 19 of 19 F-ALLCO03rev % -- ?ceAnalytical i December 31, 2018 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY Pace Workorder. 29060 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, December 19, 2018. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 12/31/2018 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 29060 - 1128661 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 15 Page 1 of 13 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water MEMENNESSEEMIL— Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 29060 - 1128661 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 13 ?ceAnalytical SAMPLE SUMMARY Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 290600001 290600002 Report ID: 29060 - 1128661 1302-CD1 S 1302-CD1 S Water 12/17/2018 15:28 12/19/2018 11:30 Bubble Strip 12/17/2018 15:28 12/19/2018 11:30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 13 ?ceAnalytical @ PROJECT SUMMARY Workorder: 29060 CABARRUS COUNTY Workorder Comments Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The sample 29060 (0002) was collected in an alternate container type, than that assigned to PAES method AM20GAx for the analysis of Hydrogen. The sample container was received under vacuum and was capped with flat septa. Sample volume was adjusted, so as to assure a volume for injection. Results reported at dilution. Report ID: 29060 - 1128661 .==° �� CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 13 ?ceAnalytical i Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290600001 Sample ID: 1302-CD1S Date Received: 12/19/2018 11:30 Matrix: Water Date Collected: 12/17/2018 15:28 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/26/2018 00:53 KB B Acetic Acid <0.10 mg/I 0.10 0.024 1 12/26/2018 00:53 KB B Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/26/2018 00:53 KB Formic Acid <0.20 mg/I 0.20 0.048 1 12/26/2018 00:53 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/26/2018 00:53 KB Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/26/2018 00:53 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/26/2018 00:53 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/26/2018 00:53 KB i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/26/2018 00:53 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/26/2018 00:53 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3.5 ug/I 0.50 0.014 1 12/28/201810:27 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/28/201810:27 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/28/201810:27 BW n Carbon Dioxide 46 mg/I 5.0 0.12 1 12/28/2018 10:27 BW n Report ID: 29060 - 1128661 Page 5 of 13 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290600002 Date Received: 12/19/2018 11:30 Matrix: Bubble Strip Sample ID: 1302-CD1S Date Collected: 12/17/2018 15:28 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 420 nM 20 13 20 12/21/201816:36 MM d,n Report ID: 29060 - 1128661 Page 6 of 13 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. d The analyte concentration was determined from a dilution. Report ID: 29060 - 1128661 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 7 of 13 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29060 CABARRUS COUNTY QC Batch: EDON/3961 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 290600001 METHOD BLANK: 59130 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I <0.20 0.20 B Acetic Acid mg/I <0.10 0.10 B Propionic Acid mg/I <0.10 0.10 Formic Acid mg/I 0.22 0.20 B Butyric Acid mg/I <0.10 0.10 Pyruvic Acid mg/I <0.10 0.10 i-Pentanoic Acid mg/I <0.10 0.10 Pentanoic Acid mg/I <0.10 0.10 i-Hexanoic Acid mg/I <0.20 0.20 Hexanoic Acid mg/I <0.20 0.20 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 59131 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers EDonors Lactic Acid mg/I 2 2.2 112 70-130 B Acetic Acid mg/I 2 2.1 103 70-130 B Propionic Acid mg/I 2 2.0 103 70-130 Formic Acid mg/I 2 2.2 109 70-130 B Butyric Acid mg/I 2 2.1 103 70-130 Pyruvic Acid mg/I 2 2.0 99 70-130 i-Pentanoic Acid mg/I 2 2.0 101 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 i-Hexanoic Acid mg/I 2 2.1 103 70-130 Hexanoic Acid mg/I 2 2.0 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 59132 59133 Original: 290050001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.5 40 42 43 105 105 70-130 0.31 30 d,B Report ID: 29060 - 1128661 Page 8 of 13 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Units 59132 Original Result Spike Cone. 59133 MS Result MSD Result Original: MS % Rec 290050001 MSD % Rec % Rec Limit RPD Max RPD Qualifiers Acetic Acid mg/I 9.4 40 49 49 100 100 70-130 0.26 30 d,B Propionic Acid mg/I 0.65 40 40 40 99 100 70-130 0.48 30 d Formic Acid mg/I 0.81 40 42 43 104 105 70-130 1.1 30 d,B Butyric Acid mg/I 3.3 40 42 43 98 100 70-130 1.7 30 d Pyruvic Acid mg/I 0.078 40 39 39 97 97 70-130 0.61 30 d i-Pentanoic Acid mg/I 0.15 40 38 39 95 98 70-130 3.2 30 d Pentanoic Acid mg/I 0.36 40 39 40 98 100 70-130 2 30 d i-Hexanoic Acid mg/I 0 40 37 39 92 97 70-130 5.2 30 d Hexanoic Acid mg/I 1.1 40 37 39 90 95 70-130 5.6 30 d Report ID: 29060 - 1128661 Page 9 of 13 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical QUALITY CONTROL DATA Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7293 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290600002 METHOD BLANK: 59145 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 59147 59149 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Hydrogen nM 24 24 24 99 100 80-120 1.8 20 n Report ID: 29060 - 1128661 :IAC CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 13 Pace Analytical Energy Services LLC ?ceAnalytical 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QUALITY CONTROL DATA Workorder: 29060 CABARRUS COUNTY QC Batch: DISG/7300 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290600001 METHOD BLANK: 59196 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I <0.50 0.50 n Ethane ug/I <0.10 0.10 n Ethene ug/I <0.10 0.10 n METHOD BLANK: 59197 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I <5.0 5.0 n LABORATORY CONTROL SAMPLE & LCSD: 59198 59200 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Methane ug/I 750 720 740 97 99 80-120 2.2 20 n Ethane ug/I 38 38 39 101 104 80-120 2.7 20 n Ethene ug/I 35 36 36 101 103 80-120 2.2 20 n LABORATORY CONTROL SAMPLE & LCSD: 59199 59201 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Carbon Dioxide mg/I 120 120 120 102 105 80-120 2.4 20 n Report ID: 29060 - 1128661 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 11 of 13 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 29060 CABARRUS COUNTY QUALITY CONTROL PARAMETER QUALIFIERS The analyte was detected in the associated blank. The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 29060 - 1128661 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 12 of 13 ?ceAnalytical QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 29060 CABARRUS COUNTY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 290600001 1302-CD1 S AM23G EDON/3961 290600002 1302-CD1S AM20GAX DISG/7293 290600001 1302-CD1S AM20GAX DISG/7300 Report ID: 29060 - 1128661 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 13 of 13 (D Q N K 0 (D (D 3 m N 0 M i D r C') 0 O N (D G O O N A m 7 N O O O !D 0 W N -a ' U7 A w N — = (n m -' - N � S N 0 o CD D vpr 0� ca o N p -+° N V N - l . A {. C M n o(p o ..r n 0 —. (D p_ (D N V O n g3 . ;o m(D N (D (Q = 'a Wp 3 G N N. ID' N -s (D m Q m �Dm �' rn ;7 p _O�Oo •(ffi � ED m0.N Do C FD Dv N @ W, 7 'o O v O m n Z (D NN) n v .� 3 0 � ° n -( n o co 0 N (D �. L� I00 O N 0 n 3 y� cr vi (�D N) fD 41 C D7 Y C C 7 D O y#. w Z� �.. O Unpreserved C) "t3 � Q. '. Q m n 0' ®' fD �. G m CD CL 7 4 ID m % Sub Methane/ Ethane/ Ethene -c CD I tJ' Z fto 0, M CD g CL in C2' �• N 41 0 O_ Cfl m 41 h �... co Z C c m z Cooler Receipt Foram Client Name: Project: „Lab Work Order: A. Shipping/Container Information (circle appropriate response) Courier: FedEx UPS LISPS Client Other: Air bill Present,' Yes, No Tracking Number: Custody Seal on Cooler/Box Present: Yes No Seals Intact: Yes No i Cooler/Box Packing (Material: Type of Ice: ;Wet Blue Nc Cooler Temperature: Comments: Bubble Wrap Absorbent Foam Other: e Ice Intacti' Yes ' Melted Radiation Screened: Yes No Chain of Custody Present: ,,Yes No B. Laboratory Assignment/Log-in (check appropriate response) YES NO N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC .Containers intact t; Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided �P�AEScon�tainers used Are containers properly preserved for the requested testing? (as labeled) h If an unknown preservation state, were containers checked? Exception: VOA's coliform i If yes, see pH form. Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? P4e space present? Comments: Cooler contents examined/received by : Date Project Manager Review: Date: t l F-PAE-Q-009-rev.01, 3 Uct2017 ?ceAnalytical i January 7, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: 2612903 /CABARRUS CTY UNITS Pace Workorder. 29091 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory between Friday, December 21, 2018 and Thursday, December 27, 2018. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 01/07/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 37 Page 1 of 30 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 30 ?ceAnalytical i SAMPLE SUMMARY Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 290910001 1302-M W3 Water 12/19/2018 15:48 12/21/2018 11:35 290910002 1302-M WL Water 12/19/2018 16:10 12/21/2018 11:35 290910003 1302-AM W 1 S Water 12/19/2018 13:03 12/21/2018 11:35 290910004 1302-AM W 1 D Water 12/19/2018 13:21 12/21/2018 11:35 290910005 1302-MW3 Bubble Strip 12/19/2018 15:48 12/21/2018 11:35 290910006 1302-MWL Bubble Strip 12/19/2018 16:10 12/21/2018 11:35 290910007 1302-AMW1S Bubble Strip 12/19/2018 13:03 12/21/2018 11:35 290910008 1302-AMW1D Bubble Strip 12/19/2018 13:21 12/21/2018 11:35 290910009 1302-MWA Water 12/20/2018 10:35 12/27/2018 12:04 290910010 1302-MWA Bubble Strip 12/20/2018 10:35 12/27/2018 12:04 290910011 1302-MWE REP Water 12/20/2018 11:44 12/27/2018 12:04 290910012 1302-MWE REP Bubble Strip 12/20/2018 11:44 12/27/2018 12:04 290910013 1302-MWE deep Water 12/20/2018 13:31 12/27/2018 12:04 290910014 1302-MWE deep Bubble Strip 12/20/2018 13:31 12/27/2018 12:04 290910015 1302-AMW2s Water 12/20/2018 11:51 12/27/2018 12:04 290910016 1302-AMW2s Bubble Strip 12/20/2018 11:51 12/27/2018 12:04 290910017 1302-AMW2d Water 12/20/2018 12:34 12/27/2018 12:04 290910018 1302-AMW2d Bubble Strip 12/20/2018 12:34 12/27/2018 12:04 Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 30 ?ceAnalytical @ PROJECT SUMMARY Workorder: 29091 2612903 /CABARRUS CTY UNITS Batch Comments Batch: EDON/3966 -Low Level Volatile Fatty Acids Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The matrix spike and/or spike duplicate, recovery or relative percent difference; accuracy influenced by the concentration of the reference sample 290900001. Analyte Lactic, Acetic, Propionic, Butyric and Pentanoic acids. Batch acceptance based on laboratory control sample recovery. Report ID: 29091 - 1129325 .==° ���� CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 30 ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910001 Sample ID: 1302-MW3 Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 15:48 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 00:18 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 00:18 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 00:18 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 00:18 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 00:18 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 00:18 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 00:18 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 00:18 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 00:18 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 00:18 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane <0.50 ug/I 0.50 0.014 1 12/31/2018 07:36 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 07:36 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:36 BW n Carbon Dioxide 160 mg/I 5.0 0.12 1 12/31/2018 07:36 BW n Report ID: 29091 - 1129325 Page 5 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910002 Sample ID: 1302-MWL Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 16:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 01:14 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 01:14 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 01:14 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 01:14 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 01:14 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 01:14 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 01:14 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 01:14 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 01:14 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 01:14 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.93 ug/I 0.50 0.014 1 12/31/2018 07:46 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 07:46 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:46 BW n Carbon Dioxide 95 mg/I 5.0 0.12 1 12/31/2018 07:46 BW n Report ID: 29091 - 1129325 Page 6 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910003 Sample ID: 1302-AMW1S Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 13:03 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 02:11 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 02:11 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 02:11 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 02:11 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 02:11 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 02:11 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 02:11 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 02:11 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 02:11 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 02:11 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1600 ug/I 0.50 0.014 1 12/31/2018 07:56 BW n Ethane 0.24 ug/I 0.10 0.0070 1 12/31/2018 07:56 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 07:56 BW n Carbon Dioxide 260 mg/I 5.0 0.12 1 12/31/2018 07:56 BW n Report ID: 29091 - 1129325 Page 7 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910004 Sample ID: 1302-AMW1D Date Received: 12/21/2018 11:35 Matrix: Water Date Collected: 12/19/2018 13:21 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 03:07 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 03:07 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 03:07 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 03:07 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 03:07 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 03:07 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 03:07 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 03:07 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 03:07 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 03:07 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 3500 ug/I 0.50 0.014 1 12/31/2018 08:05 BW n Ethane 2.6 ug/I 0.10 0.0070 1 12/31/2018 08:05 BW n Ethene 1.5 ug/I 0.10 0.0050 1 12/31/2018 08:05 BW n Carbon Dioxide 360 mg/I 5.0 0.12 1 12/31/2018 08:05 BW n Report ID: 29091 - 1129325 Page 8 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910005 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-MW3 Date Collected: 12/19/2018 15:48 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 9.5 nM 1.0 0.65 1 12/27/201815:55 MM n Report ID: 29091 - 1129325 Page 9 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910006 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-MWL Date Collected: 12/19/2018 16:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 13 nM 1.0 0.65 1 12/27/201816:07 MM n Report ID: 29091 - 1129325 Page 10 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910007 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-AMW1S Date Collected: 12/19/2018 13:03 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 5.6 nM 1.0 0.65 1 12/27/201816:19 MM n Report ID: 29091 - 1129325 Page 11 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910008 Date Received: 12/21/2018 11:35 Matrix: Bubble Strip Sample ID: 1302-AMW1D Date Collected: 12/19/2018 13:21 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 11 nM 1.0 0.65 1 12/27/201816:32 MM n Report ID: 29091 - 1129325 Page 12 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910009 Sample ID: 1302-MWA Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 04:03 KB M3,M5 Acetic Acid 0.22 mg/I 0.10 0.024 1 12/29/2018 04:03 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 04:03 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 04:03 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 04:03 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 04:03 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 04:03 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 04:03 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 04:03 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 04:03 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 7600 ug/I 0.50 0.014 1 12/31/2018 08:15 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:15 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:15 BW n Carbon Dioxide 600 mg/I 5.0 0.12 1 12/31/2018 08:15 BW n Report ID: 29091 - 1129325 Page 13 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910010 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWA Date Collected: 12/20/2018 10:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 110 nM 16 10 16 12/29/2018 05:40 TD d,n Report ID: 29091 - 1129325 Page 14 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910011 Sample ID: 1302-MWE REP Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 11:44 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 05:00 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 05:00 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 05:00 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 05:00 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 05:00 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 05:00 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 05:00 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 05:00 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 05:00 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 05:00 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 830 ug/I 0.50 0.014 1 12/31/2018 08:27 BW n Ethane 2.9 ug/I 0.10 0.0070 1 12/31/2018 08:27 BW n Ethene 0.63 ug/I 0.10 0.0050 1 12/31/2018 08:27 BW n Carbon Dioxide 380 mg/I 5.0 0.12 1 12/31/2018 08:27 BW n Report ID: 29091 - 1129325 Page 15 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910012 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWE REP Date Collected: 12/20/2018 11:44 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 13 nM 1.0 0.65 1 12/29/2018 03:44 TD n Report ID: 29091 - 1129325 Page 16 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910013 Sample ID: 1302-MWE deep Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 13:31 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 05:56 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 05:56 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 05:56 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 05:56 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 05:56 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 05:56 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 05:56 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 05:56 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 05:56 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 05:56 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 11000 ug/I 0.50 0.014 1 12/31/2018 08:37 BW n Ethane 6.6 ug/I 0.10 0.0070 1 12/31/2018 08:37 BW n Ethene 0.10 ug/I 0.10 0.0050 1 12/31/2018 08:37 BW n Carbon Dioxide 320 mg/I 5.0 0.12 1 12/31/2018 08:37 BW n Report ID: 29091 - 1129325 Page 17 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910014 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-MWE deep Date Collected: 12/20/2018 13:31 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 7.7 nM 1.0 0.65 1 12/29/2018 03:57 TD n Report ID: 29091 - 1129325 Page 18 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910015 Sample ID: 1302-AMW2s Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 11:51 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 06:52 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 06:52 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 06:52 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 06:52 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 06:52 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 06:52 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 06:52 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 06:52 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 06:52 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 06:52 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane <0.50 ug/I 0.50 0.014 1 12/31/2018 08:48 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:48 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:48 BW n Carbon Dioxide 160 mg/I 5.0 0.12 1 12/31/2018 08:48 BW n Report ID: 29091 - 1129325 Page 19 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910016 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-AMW2s Date Collected: 12/20/2018 11:51 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 12 nM 1.0 0.65 1 12/29/2018 04:10 TD n Report ID: 29091 - 1129325 Page 20 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910017 Sample ID: 1302-AMW2d Date Received: 12/27/2018 12:04 Matrix: Water Date Collected: 12/20/2018 12:34 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid <0.20 mg/I 0.20 0.014 1 12/29/2018 07:49 KB M3,M5 Acetic Acid <0.10 mg/I 0.10 0.024 1 12/29/2018 07:49 KB M3,M5 Propionic Acid <0.10 mg/I 0.10 0.0044 1 12/29/2018 07:49 KB M3,M5 Formic Acid <0.20 mg/I 0.20 0.048 1 12/29/2018 07:49 KB B Butyric Acid <0.10 mg/I 0.10 0.0047 1 12/29/2018 07:49 KB M3,M5 Pyruvic Acid <0.10 mg/I 0.10 0.0057 1 12/29/2018 07:49 KB i-Pentanoic Acid <0.10 mg/I 0.10 0.0075 1 12/29/2018 07:49 KB Pentanoic Acid <0.10 mg/I 0.10 0.012 1 12/29/2018 07:49 KB M3,M5 i-Hexanoic Acid <0.20 mg/I 0.20 0.0049 1 12/29/2018 07:49 KB Hexanoic Acid <0.20 mg/I 0.20 0.012 1 12/29/2018 07:49 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 72 ug/I 0.50 0.014 1 12/31/2018 08:57 BW n Ethane <0.10 ug/I 0.10 0.0070 1 12/31/2018 08:57 BW n Ethene <0.10 ug/I 0.10 0.0050 1 12/31/2018 08:57 BW n Carbon Dioxide 240 mg/I 5.0 0.12 1 12/31/2018 08:57 BW n Report ID: 29091 - 1129325 Page 21 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical I_1►It I1111I[Illf_NIIIII0*4111111111V Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 290910018 Date Received: 12/27/2018 12:04 Matrix: Bubble Strip Sample ID: 1302-AMW2d Date Collected: 12/20/2018 12:34 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 16 nM 1.0 0.65 1 12/29/2018 04:24 TD n Report ID: 29091 - 1129325 Page 22 of 30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. d The analyte concentration was determined from a dilution. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. M3 The matrix spike sample recovery was outside laboratory control limits. Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 23 of 30 ?ceAnalytical QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7302 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910005, 290910006, 290910007, 290910008 METHOD BLANK: 59213 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 59214 59215 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Hydrogen nM 24 26 26 105 108 80-120 2.5 20 n Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 24 of 30 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7303 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910001, 290910002, 290910003, 290910004, 290910009, 290910011, 290910013, 290910015, 290910017 METHOD BLANK: 59216 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I <0.50 0.50 n Ethane ug/I <0.10 0.10 n Ethene ug/I <0.10 0.10 n METHOD BLANK: 59217 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I <5.0 5.0 n LABORATORY CONTROL SAMPLE & LCSD: 59218 59220 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Methane ug/I 750 760 750 102 100 80-120 1.9 20 n Ethane ug/I 38 37 37 97 98 80-120 0.77 20 n Ethene ug/I 35 34 34 97 98 80-120 0.73 20 n LABORATORY CONTROL SAMPLE & LCSD: 59219 59221 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Carbon Dioxide mg/I 120 130 130 108 108 80-120 0.095 20 n Report ID: 29091 - 1129325 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 25 of 30 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/3966 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 290910001, 290910002, 290910003, 290910004, 290910009, 290910011, 290910013, 290910015, 290910017 METHOD BLANK: 59234 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I <0.20 0.20 M3,M5 Acetic Acid mg/I <0.10 0.10 M3,M5 Propionic Acid mg/I <0.10 0.10 M3,M5 Formic Acid mg/I <0.20 0.20 B Butyric Acid mg/I <0.10 0.10 M3,M5 Pyruvic Acid mg/I <0.10 0.10 i-Pentanoic Acid mg/I <0.10 0.10 Pentanoic Acid mg/I <0.10 0.10 M3,M5 i-Hexanoic Acid mg/I <0.20 0.20 Hexanoic Acid mg/I <0.20 0.20 LABORATORY CONTROL SAMPLE: 59235 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers EDonors Lactic Acid mg/I 2 2.2 108 70-130 M3,M5 Acetic Acid mg/I 2 2.0 99 70-130 M3,M5 Propionic Acid mg/I 2 2.0 101 70-130 M3,M5 Formic Acid mg/I 2 2.0 103 70-130 B Butyric Acid mg/I 2 2.0 102 70-130 M3,M5 Pyruvic Acid mg/I 2 2.0 99 70-130 i-Pentanoic Acid mg/I 2 2.0 100 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 M3,M5 i-Hexanoic Acid mg/I 2 2.0 102 70-130 Hexanoic Acid mg/I 2 2.0 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 59236 59237 Original: 290900001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 1.1 20 7.3 6.8 31 28 70-130 6.9 30 d,M3,M5 Report ID: 29091 - 1129325 Page 26 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: Parameter Units 59236 Original Result Spike Cone. 59237 MS Result MSD Result Original: MS % Rec 290900001 MSD % Rec % Rec Limit RPD Max RPD Qualifiers Acetic Acid mg/I 1300 20 <1.0 <1.0 -6350 -6350 70-130 0 30 d,M3,M5 Propionic Acid mg/I 720 20 <1.0 <1.0 -3610 -3610 70-130 0 30 d,M3,M5 Formic Acid mg/I 6.3 20 30 30 119 119 70-130 0.19 30 d,B Butyric Acid mg/I 170 20 160 160 -67 -72 70-130 0.63 30 d,M3,M5 Pyruvic Acid mg/I 6.3 20 25 25 92 92 70-130 0.19 30 d i-Pentanoic Acid mg/I 6.1 20 26 26 100 98 70-130 1.2 30 d Pentanoic Acid mg/I 140 20 130 130 -68 -77 70-130 1.4 30 d,M3,M5 i-Hexanoic Acid mg/I 0.7 20 18 17 87 82 70-130 5.2 30 d Hexanoic Acid mg/I 29 20 50 49 106 101 70-130 2.1 30 d Report ID: 29091 - 1129325 Page 27 of 30 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical QUALITY CONTROL DATA Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7305 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 290910010, 290910012, 290910014, 290910016, 290910018 METHOD BLANK: 59238 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 59239 59240 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers RISK Hydrogen nM 24 23 24 96 99 80-120 3 20 n Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 28 of 30 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 29091 2612903 /CABARRUS CTY UNITS QUALITY CONTROL PARAMETER QUALIFIERS The analyte was detected in the associated blank. M3 The matrix spike sample recovery was outside laboratory control limits. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 29091 - 1129325 .==° �� CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 29 of 30 ?ceAnalytical i QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 29091 2612903 /CABARRUS CTY UNITS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 290910005 1302-MW3 AM20GAX DISG/7302 290910006 1302-MWL AM20GAX DISG/7302 290910007 1302-AMW1S AM20GAX DISG/7302 290910008 1302-AMW1D AM20GAX DISG/7302 290910001 1302-MW3 AM20GAX DISG/7303 290910002 1302-MWL AM20GAX DISG/7303 290910003 1302-AMW1S AM20GAX DISG/7303 290910004 1302-AMW1D AM20GAX DISG/7303 290910009 1302-MWA AM20GAX DISG/7303 290910011 1302-MWE REP AM20GAX DISG/7303 290910013 1302-MWE deep AM20GAX DISG/7303 290910015 1302-AMW2s AM20GAX DISG/7303 290910017 1302-AMW2d AM20GAX DISG/7303 290910001 1302-MW3 AM23G EDON/3966 290910002 1302-MWL AM23G EDON/3966 290910003 1302-AMW1 S AM23G EDON/3966 290910004 1302-AMW1 D AM23G EDON/3966 290910009 1302-MWA AM23G EDON/3966 290910011 1302-MWE REP AM23G EDON/3966 290910013 1302-MWE deep AM23G EDON/3966 290910015 1302-AMW2s AM23G EDON/3966 290910017 1302-AMW2d AM23G EDON/3966 290910010 1302-MWA AM20GAX DISG/7305 290910012 1302-MWE REP AM20GAX DISG/7305 290910014 1302-MWE deep AM20GAX DISG/7305 290910016 1302-AMW2s AM20GAX DISG/7305 290910018 1302-AMW2d AM20GAX DISG/7305 Report ID: 29091 - 1129325 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 30 of 30 0ea 0 N ml w N m -a -0 --t -0 of) m 1 (D In CDA (n p7 --4 CD :3 m 5, C) 0 0 0 CD (D (D :3. Ccn 3 - N ro ('D :3 CD N. C:) m (D FD > m n C.0 CD 0 SD �n 0 0 0 r cc IV (D iZ3 cc F3 cc i,3 co co co co w m c, O z C7 0 3 w CD 00 0 CD N) IQ N) N) 0 CD CD 0 CD CD w '3 w CD CD w w CD CS '57 CD L0V <. m W r CD z Unpreserved Cp V — — — CD 0 LD. — — — — — + — < CD 0 (D (D X x X X Sub Volatile Fatty Acids z C4 01 Cn 0 q 0 (D 0 I z C CO m 0 z (D 0) CD w 0 I w I cn m -U -0 t -0 Cf) �x 0 0) 0 w 0 0 0 0 -1 (D 0 =7 (D w 77 0 > CD 0 (n - - Q n 0 -4 > > (D Z)O e C:) 0 -11 0 0 (D Q C�: �E C�: m m -0 cc :3 3 ' 3 Nj m;7 m CD . 0 a) -�, q - W 0 - rj (D 0 Nj C:) (0 > 0 (D w < 0 0 m 0 (OD rQ 0 3 0 0 0 0 w 0 F3 9 N (P N 2 N 2 1 5 d 21 w (Do 03 (D cn 0 0 0 CD CD c') cn w rj "I. w rj w w P,) PI) w 1 c: — — — — — — — --- c) 0 — — — — — — — — --- — — — Unpreserved g w — — — — — — — — — — — — — — — --- — — — — — — — — — 0 — — — — — — — — — — — ---- BI >< X X >< X >< X X >< Sub Dissolved Carbon Dioxide CD LA I U, ci4 >c, ------------- Am — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — — O — ------ — — — — — — ------ — — — — -- --------------- c (1) m 0 z CT 16- Cooler Receipt Form Client fume: Project: 'Lab Work Order: A. Shipping/Container information (circle appropriate response) Courier: ,�FedEx UPS USPS Client Other: Air bill Present" Yes No Tracking number: Custody Seal on Cooler/Box Present: Yes `� No;= Seals intact: Yes No Cooler/Box Packing Material: ,&0bble Wrap Absorbent Foam Other: Type of ice: /Wet�Blue None ice Intact: !Yes =Melted Cooler Temperature ` "" Radiation Screened: Yes /No � Chain of Custody Present. � Yes, No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES NO N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC ,Containers intact Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided PASS containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? Exception: VOA's coliform If yes, see pH form. Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by: Date: Project Manager Review :_ Date ' - ) F-PAE-Q-009-rev.01, 30ct2017 Cooler Receipt Form Client Name r Project � Lab !Mork order: ' A. Shipping/Container Information (circle appropriate response) Courier ``Pedx UPS LISPS Client Other: Air bill Present Yes No Tracking Number: r ��` ( Custody Seal on Cooler/Box Present: tYes No Seals intact: jes No Cooler/Box Packing Material: Bubble Wrap Absorbent Foam Other: Type of Ice:�Wc Blue None ice Intact: ;Yes' Melted Cooler Temperature: Radiation Screened: Yes o) Chain of Custody Present: ;l' No Comments: B. Laboratory Assignment/Log-in (check appropriate response) — YES NO I N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC Containers intact Were samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided _ ,, PAES containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? If yes, see pH form. Exception: VOA's coliform Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Com Cooler contents examined/received by ©ate t' y J fi Project Manager Review Date F-PAE-Q-009-rev.01;. 3 Oct2017 Date; NON-CONTORMAXCE FORIA PAES Work Order Teo Receipt: Receivtr E R 'ANCE: ASON FOR NION-COl",TFOR-b/L V CA - ACTION TAKEN: Date: ClieDt Tl-alne7 Culstoma Servir-e laidals: ,F-PA-E-Q-0 1 4-7v,00, 20 No720 14 Time: - Page I of 1 Ruth Welsh - 2612903 From: Ruth Welsh To: SukbouMcKenzie Subject: 2612903 I wanted to let you know that during login headspace was noted in one of the vials for the dissolved gases analyses for sample 1302-MWA Ruth Welsh Assistant General Manager Pace Analytical Energy Son/iceo, LLC 22OWilliam Pitt Way, Pittoburgh.PA1523D 412'828-2387(0)1412-200-8005(C) ab0n1:blozk I2/27/20I8 MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitori Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: Sampling Date: 2612903 12/18-20/2018 Well ID DTW Well ID DTW Well ID DTW Well ID DTW 1302-CD-4 Rep 7.32 1302-MW-E (DEEP) 32.48 1302-MW-J 28.31 1302-AMW-2S 23.09 1302-MW-1 11.47 1302-MW-E (R) 29.09 1302-MW-K 22.33 1302-CD-1S 24.95 1302-MW-3 10.84 1302-MW-F 6.73 1302-MW-L 11.32 1302-CD-1 D 27.52 1302-M W-A 43.35 1302-M W-G 8.78 1302-M W-X 9.78 1302-MW-B 1.98 1302-MW-H 26.71 1302-AMW-1 D 51.75 1302-MW-C 4.89 1302-MW-H (DEEP) 26.95 1302-AMW-1S 51.10 1302-MW-D 24.58 1302-MW-1 44.29 1302-AMW-2D 22.78 Note: 1 DTW - Depth to Water From Top of Casing (ft.) Sampled By: Pace Huntersville Field Specialist(s) Reviewed By: Field Services Manager MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitorin Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: Sampling Date: 2612903 12/18-20/2018 Well ID % Vol Well ID % Vol Well ID % Vol Well ID % Vol 1302-CD-4 Rep 0 1302-MW-E (DEEP) 0 1302-MW-J 0 1302-AMW-2S 0 1302-MW-1 0 1302-MW-E (R) 2.8 1302-MW-K 0 1302-CD-1 S 0 1302-MW-3 0 1302-MW-F 0 1302-MW-L 0 1302-CD-1 D 0 1302-MW-A 58.5 1302-MW-G 32.0 1302-MW-X 0 1302-MW-B 0 1302-MW-H 0 1302-AMW-1 D 0 1302-MW-C 0 1302-MW-H (DEEP) 0 1302-AMW-1 S 0 1302-MW-D 33.1 1302-MW-1 0 1302-AMW-2D 0 Note 1 °I Vol -Volume of Methane Gas in Headspace Sampled By: Pace Huntersville Field Specialist(s) Reviewed By: ,, (�21 -,W i S rvices Manager C—O-) Page 1 of 1 Client Name: Client Contact: Project: Site: MONITORING WELL DATA SUMMARY Dresser & McKee Mr. Mat Colone Semi-annual Ground Water Monitorinc Cabarrus Co. Landfill - Units 2 & 3 Report No.: 2612903 Sampling Date: 12/18-20/2018 eIf urge Well ID BOCK DTWZ Vol' I Vol' pHs SC6 Temp Turbo DO' ORP10 Comments 1302-CD-1 D 52.21 27.52 - 0.6L 1 6.1 116 15.8 9.9 3.6 25.1 No odor 1302-CD-1S 29.02 24.09 - 1.8L 6.3 110 16.7 8.8 5.6 38.6 No odor 1302-CD-4 Rep 19.82 7.32 6.11 7.46 6.0 139.4 12.5 101 5.3 48.9 No odor 1302-MW-1 30.43 11.47 9.27 9.27 6.4 1355 1239 6.90 2.0 224.6 No odor 1302-MW-3 35.40 13.90 3.50 10.2L 6.0 178 15.3 7.90 2.80 48.8 No odor Fe2+=0 1302-MW-A 50.58 43.35 3.53 5.91- 5.7 372 9.3 0.80 0.60 32.4 No odor 1302-MW-B 15.50 1.98 6.61 6.61 6.7 795 9.3 18 1.3 -64.8 Odor 1320-MW-C 17.89 4.89 4.40 9.0 5.8 102 12.3 11.3 4.8 162.6 No odor 1302-MW-D 30.53 24.58 2.90 2.90 6.2 858 15.1 1.0 1.1 35.4 Metalic Fe2+= 5.0 1302-MW-E R 41.83 28.92 6.30 3.7L 6.2 1012 13.4 4.1 0.3 -16.1 Strong odor Fe2+= 6.0 1302-MW-E (DEEP) 59.92 32.18 13.56 4.3L 6.3 1031 11.6 4.3 0.4 -56.2 Foul odor Fe2+= 6.0 1302-MW-F 1 20.22 6.73 6.73 5.40 6.1 1 481 11.6 3.5 1 2.5 11 No odor Fe2+= 5.0 Client Name: Camp, Dresser, & McKeee Site: Cabarrus Co. Landfill - Units 2 & 3 Report No. Sampling Date 2612903 12/18-20/2018 Well Purge Well ID BOC' I DTWZ Vol' I Vol" I pHs SC' I Temp I Turbe I DO' ORP'0 Comments 1302-MW-G 20.44 8.78 1 5.70 5.70 1 6.1 586 1 11.3 15 2.1 -2.8 No odor 1302-MW-H Deep 33.08 26.71 3.11 3.11 6.2 165 14.1 173 5.8 -8.3 No odor 1302-MW-H 59.90 26.95 16.11 16.11 6.5 242 14.7 9.9 9.9 -2.6 No odor 1032-MW-1 65.46 44.29 10.35 10.35 6.1 142.7 14.8 10.7 4.5 -2.9 No odor 1302-MW-J 35.08 28.31 3.31 2.40 6.6 241 14.1 67 3.3 143.7 Slight odor 1302-MW-K 36.38 22.33 6.00 173.1 15.1 4.5 15.1 4.5 3.9 129.8 No odor 1302-MW-L 27.26 11.32 7.80 0.39 5.8 86.2 12.5 2.9 2.7 100.4 No odor Fe2+ =0 1302-MW-X 32.29 9.78 11.00 11.00 6.3 185 13.6 1.40 3.20 167.5 No odor 1302-AMW-1 D 96.80 51.75 22.00 9.5L 6.0 411.6 14.6 10.1 0.50 1.8 No odor 1302-AMW-1S 67.67 51.10 8.10 0.15L 5.9 219 14.5 0.4 0.7 510.5 No odor Fe2+ =0 1302-AMW-2D 62.80 23.55 19.19 5.9L 6.0 274.3 13.2 0.2 0.90 65.3 Slight odor Fe2+ =1.5 1302-AMW-2S 40.07 230.9 8.31 0.15L 5.8 144.3 13.7 2.1 2.9 101.3 No odor Fe2+ =0 Notes: 1 BOC - Bottom of Casing (Ft.) 2 DTW - Depth to Water from Top of Casing (Ft.) 3 Well Vol - Calculated at 3 Times One Well Volume (Gal.) 4 Actual Volume Evacuated Prior to Sample Collection (Gal.) 5 pH - Reported in Standard Units 6 SC - Specific Conductance (uS/cm) 7 Temp - Temperature ('C) 8 Turb - Turbidity (NTU) 9 DO - Dissolved Oxygen (mgtL) 10 ORP - Oxidation/Reduction Potential (mV) Sampled By: Pace Huntersville Field Specialist(s) Reviewed By: %&-III- Field Services Manager SURFACE WATER SAMPLING DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Surface Water Monitoring Site: Cabarrus Co. Landfill - Unit 1 Notes: Report No. Sampling Date: Point ID I pH SC Temp Turb DO ORP Comments 1302-SW-1 7.6 335.6 6.2 18.4 10.1 -73.4 No comment 1302-SW-2 7.2 266.6 6.4 19.3 9.8 1 21.1 INocomment 1 pH - Reported in Standard Units 2 SC - Specific Conductance (uS/cm) 3 Temp - Temperature (°C) 4 Turb - Turbidity (NTU) 5 DO - Dissolved Oxygen (mg/L) 6 ORP - Oxidation/Reduction Potential (mV) 2613064 2612812 12/20/2018 Sampled By: Pace Huntersville Field Specialist(s) Reviewed By: csv� i d Services Manager ;aceAnalytical' 1117? FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: p,ci,— a j `c I Dedicated Pump: No Well ID #: 1302 - e- Date: Weather Conditions: CjOS Method of Well Evacuation: Grundfos ai ristalticBP Total Well Depth in feet (TWD) _ / Z Method of Sample Collection: Grundfos i e eristalticBP Depth to Ground Water in feet (DGW) = '.;t, ,3 Well Yield (subjective): OK GL 5o I Sample Date and Time: / 2 19 - lg7cvo 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 PSI: r Recharge: -� Standard Evacuation Volume (3 casing volumes) = Z Discharge: �— Total Volume of Water Removed (gallons): Time (military) 1 ) 2 1 15 O g ��11 Volume Purged (Gallons) 0— Water Level (ft.) stable PH (s.u.) t z 6,6 6.0 Sp. Cond. (µmhos/cm) :k w •. 16119 Water Temp. (°C) constant Turbidity (NTU) ;io % a<sxTu 2- U 101.3 Dissolved Oxygen (mg/L) do , 5 1.6 ;2 - D 5. g RedOx PotentiaVORP(mV) ��omy ��, 5 O GPM/Hz COMMENTS/OBSERVA IONS: CCeS`J dot -)A S' Fe2+ = A/A mgfL Date: I - % r _ io Page 1 of aceAna/ytica/ b FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel 05 act a l Dedicated Pump: No Well ID #: 1302 - Date: 2 - I `d - I q Weather Conditions: Method of Well Evacuation: Grundfos aile eristalticBP Total Well Depth in feet (TWD) = 6. u 3 Method of Sample Collection: Grundfos aile eristalticBP Depth to Ground Water in feet (DGW) _ //, t( Well Yield (subjective): 15,96 Sample Date and Time: J- 9 I Y g 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = PSI: --� Recharge: — Standard Evacuation Volume (3 casing volumes) _ 2-4 1 Discharge: —� Total Volume of Water Removed (gallons). 7-1 A� Time (military) 0-7111 Ll 7 5r, Volume Purged (Gallons) 0 3. O 90 Water Level (ft.) sa6{e N f ��� f ! 9 pH (s.u.) f , 6.3 q6 y 6 - lo. Sp. Cond. (µmhos/cm) a•. 1-40 Y 1 73 (1/ 7-L 13 ,-S Water Temp. ('C) constant 5 t - 77 5- C/. 1 ae ! Turbidity(NTU) ±iaio«sxna Dissolved Oxygen (mg/L) ±10 : 2 .7, 0 RedOX Potential/ORP (mV) Boma 3 6 . rjCj __!5� oozy. �. GPM/Hz -- -- COMMENTS/OBSERVATIONS: Fe2+= N I mg/L apor Date: la- (Q - / J7 By: 0 Page f of I aceAnalytical " FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: rC, n , C,, Dedicated Pump: No Well ID #: 1302 - - - - Date: 2 • I ci - l Weather Conditions: 5ac, -sunnu Method of Well Evacuation: Grundfos/Bailer/Peristalti P Total Well Depth in feet (TWD) = 3 5. CC) Method of Sample Collection: GrundfosBailer/Peristaltic P Depth to Ground Water in feet (DGW) = 13, cyo Well Yield (subjective): at. 50 c- Sample Date and Time: I . Iq• Ig I Sly 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = . PSI: 3-7- Recharge: J� Standard Evacuation Volume (3 casin volumes = 50q Discharge: Total Volume of Water Removed ( s : L Time (military) 152 a I53 /536, 153`J 1b q Z I5 y 5 Volume Purged (Gallons) —; j 77-60 $50 63 z o (G 2 5G Water Level (ft.) stable 13 cl 1 3 , 9 1 13, 13 . `1 I )3 pH (s.u.) - , .d 6, b1 6.0 b .G 6. Sp. Cond. (µmhos/cm) =lo,. 1 �, I fig,I 1-; j- I I R Water Temp. (°C) cot,stmt l 5. l I. l 5, 15, Turbidity (NTU)-l0xot<5NN I ,5 5 3 -4. rj . Dissolved Oxygen (mg(L) -lox _ 2.9 2. RedOx PotentiaUORP (mV) -lo my g'_S GPM/Hz d513 t.�.rs COMMENTS/OBSERVATIONS: rA L o•c FI . Lo11e c4,-1d, it Fe2+ = mg/L ( ; Dater By: I Z - (l )F Page I of ? aceAnalytical' FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Page i Of/ 1172ceAnalytical' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE- INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRLIS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: A0AGE ; Dedicated Pump: No Well ID #: 1302 - _ Date: Weather Conditions: 30.sMethod of Well Evacuation: Grundfo eristaltieBP Total Well Depth in feet (TWD) = J I Method of Sample Collection: Grundfos ailer eristalticBP Depth to Ground Water in feet (DG W) = g Well Yield (subjective): �p 3 , Sample Date and Time: D 91 D 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = a 7 PSI: --�-�- Recharge: --- Standard Evacuation Volume (3 casing volumes) = J Discharge: Total Volume of Water Removed (gallons): /J Time (military) Q Q la 19 i� f1910 Volume Purged (Gallons) 0 ;, G3 -IB(1 6 - /1 Water Level (ft.) Fae<< J,q K — . - — .a f g pH(su) t' 6 CDe- Sp_ Cond. (µmhos/cm) [a•. j"�' 79S Water Temp. ('C) co"v-1 Turbidity (NTU) ±10% r_<5rPnJ - Dissolved Oxygen (mg/L) 1;10% %a 2, 6 1.3 RedOx PotentiaUORP (mV) iomv — —g _ '� — (o o 3 GPM/Hz — — — COMMENTS/OBSERVATIONS: Fe2+0 mg/L, Q r ,V Date: 1 ;1- / 9 - /g By: Page 1 aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CQ SANITARY LF UNIT Casing Material: PVC Field Personnel: aGQ. (}/to. +:, Ll Dedicated Pump: No Well ID #: 1302 - fil Date: Weather Conditions: j Method of Well Evacuation: Grundfo eristalticBP Total Well Depth in feet (TWD) Method of Sample Collection: Grundfos it eristalticBP Depth to Ground Water in feet (DGW) = y_ Well Yield (subjective): Cl 001 Sample Date and Time: t o?-15 - «5 42 10 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 q6 PSI: -- Recharge: Standard Evacuation Volume (3 casing volumes) _ (f Discharge: Total Volume of Water Removed (gallons): z Lf p f c4o' Time (military) _3 ' 3 Volume Purged (Gallons) d , 6 '^ Water Level (ft.) ma6fe �-- I`, a(o pH (s.u.) t 2j, . S Sp. Cond. (µmhos/cm) ��•. (' _ } l oa o 3 Water Temp. ('C) /Z/. Turbidity (NTU) ±10i a<srnu 43� G 671 i l , 3 Dissolved Oxygen (mg/L) 110% % , RedOx Potential/ORP(mV) GPM/Hz ---� --- COMMENTS/OBSERVATIONS: V/ST Pry fu ��vTP f a5<o Fe2+ = NCB mg/L Date: (a' Pq - (13 Page / of / 2eAnalytical"" FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casin Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: �, Dedicated Pump: No Well ID #: 1302 - Date: , I - I Weather Conditions: SOS S uns Method of Well Evacuation: Grundfo eristalticBP Total Well Depth in feet (TWD) =0 30,53 Method of Sample Collection: Grundfos ailer eristalticBP Depth to Ground Water in feet (DGW) _ $ Well Yield (subjective): 5 5 Sample Date and Time: ja- (9 - (S OS- 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = o PSI: Recharge: Standard Evacuation Volume (3 casing volumes) _ , 9O Discharge: Total Volume of Water Removed (gallons): , c) Qj Time (military) Zr7 1 ( 1 Id-i -/8 005- Volume Purged (Gallons) 0 614110 Water Level (ft.) stable Z . S r— — aS. 57-7 pH (s.u.) t 6-3 61 Sp. Cond. (µmhos/cm) t lo•. Y $ Water Temp. (°C) constant 1A, 14,19 15.1 Turbidity (NTU) ;El0%wS5NTU ® Z� 1-0 Dissolved Oxygen (mg/L) tlo % � 2 a O 1 . RedOx Potentia)/ORP (mV) flo.v 1' , —7 35. • GPM/Hz I— COMMENTS/OBSERVATIONS: S� s -44--CQ6D1Mi Cr 0L'� aStoc7 Fe2+ = S , o mg/L Off(' o #A a • C Date: ta-I`I -f$ Page / of aceAnaiyticai "' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: 135KPTOK — Aww% .V'. caL Dedicated Pump: No Well ID #: 1302 - MW — IERCp- Date: 12 Qp I Weather Conditions: R a : h $' Method of Well Evacuation: Grundfos/Bailer/Peristaltic Total Well Depth in feet (TWD) q 1• 86. Method of Sample Collection: Grundfos/Bailer/Peristaltic Depth to Ground Water in feet (DGW) = Z 8. Z Well Yield (subjective): ���} 06* 7. o Sample Date and Time: 2 Zv 18 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 — 'j. , Q + PSI: Recharge: I2 Standard Evacuation Volume,(3 casing volumes) _ ,'3 %\ Discharge: $ Total Volume of Water Removed -7 go *L Time (military) 11:�.% 1 ai!:I I 1 1 -:�� I t :•ta ► I�t I t 1Volume Purged '(5uitmm) rML Water Level (ft.) 5HO , (% I OF&0 tri .0' Sp. Cond. mhos/cm t io•:(µ ) C 035 1 c l q Water Temp. (°C) co"�, Turbidity (NTU) :m0%a<-5NlU 6, 13,1 3.9 1310 .O 1 , .(, , ; Dissolved Oxygen (mg/L) tioi RedOx Potential/ORP (mV) t,amy �, (�, 0.6 — �gj Q,y _ .O .3 _ 0a3 _ GPM/Hz COMMENTS/OBSERVATIONS: ySI Pro RvS ik02o3 TPW -tCO$6 SAa1-4-4 :55. @ Ip T444w 4-%^,t 201.irt akt : I $0 Mt /r•►A mgfL Oder • out o Date: I 0 Page ` of I aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER_ & MCKEE_ rNC. - RALEIGH Casin Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: b5 K ?CM - peace Anal 4:cal Dedicated Pump: No Well ID #: 1302 - MUj _ De Date: -el -to/ 1$ Weather Conditions: 0.:t► So" Method of Well Evacuation: ticiO Total Well Depth in feet (T ) _ �j'Q, 2 Method of Sample Collection: GrundfosBailer/Peristaltic Depth to Ground Water in feet (DGW) 1 Well Yield (subjective): ExcelleoL VA tz , I Sample Date and Time: 1212e t8 2"Well: 1 Casin Volume in gallons (CV) = LWC x 0.163 = fr[. 2 U PSI: - 12jso Recharge: 2 Standard Evacuation Volume (3 casing volumes) _ -5.5G *. Discharge: 2 Total Volume of Water Removed 432o..L, Time (military) 1310 3 3 13 t e 1314 132-2 1 325 1328 Volume Purged-(£aHotts)- J"L- 5W 0 l080 1SZ0 2(so 2'7ao ,37qo3-780 Water Level (ft.) nabFe 2. IG 32.16 32. 16 32.16 32. l G 3a.1 s 32.16 H (s.u.) t 2 6.3 Q.1 G.3 G.3 .3 C. 3 C. 3 Sp. Cond. (µmhos/cm) t,a.. 10 2 1031 1032 1032 1033 Jo3l 1032 Water Temp. (OC) ion11A l t• s I.6 .6 11. 14 11.5 Turbidity (NTU) t,aia<sNTU 9.14 SA.1 3.9 4.N 3.9 1J.1 Dissolved Oxygen (mg/L) t,ox I-S 0.1 0. 1 O. G 0.5 D A a. L RedOx Potential/ORP (mV) f,omv -39.3 - 46.q -y9.1 - $1. -53.1 _5y. y -SSS GPM/Hz COMMENTS/OBSERVATIONS: / SZ pro pj" 0O203 j4Iaro'rW 490$s S-( reed :ss.2 IMun �w+ 2oN:.n Ro► e : O"'`' M:n �Fe2+= G.0 mg/L Q 4 0 r; N Date: 12 / Z O 11$ By: +' :1/ Page I of D aneAnalytical" FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER_ & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: Dedicated Pump: No Well ID #: 1302 - Ind — Date: Weather Conditions: Method of Well Evacuation: GrundfosBailer/PeristalticBP Total Well Depth in feet (TWD) = Method of Sample Collection: GrundfosBailer/PeristalticBP Depth to Ground Water in feet (DGW) = Well Yield (subjective): Sam le Date and Time: 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = PSI: Recharge: Standard Evacuation Volume (3 casing volumes) = Discharge: Total Volume of Water Removed (gallons): 'Time (military) 1531 Volume Purged (Gallons) q3 2 0 Water Level (ft.) sa61e 32, 6 pH (s.u.) t , 6.3 Sp. Cond. (µmhos/cm) t ion. I O 3 Water Temp. ('C) C""tea T I. 6 Turbidity (NTU) *10%assrm, y.3 Dissolved Oxygen (mg/L) *10% p , L{ RedOx Potential/ORP (mV) t�omv —Ss.a GPM/Hz -- COMMENTS/OBSERVATIONS: Fe2+ = mg/L Date: 17,/20A8 By: IF W Page _J of Q aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: j G[,2 1 +;Gc,l Dedicated Pump: No Well ID #: 1302 - - f Date: Weather Conditions: ,$ $ c Method of Well Evacuation: Grundfo ailer ristalticBP Total Well Depth in feet (TWD) = Method of Sample Collection: Grundfos aile eristalticBP Depth to Ground Water in feet (DGW) =b, 3 Well Yield (subjective): Od 3 11,9 Sample Date and Time: / - ! 9 ! O 816 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 a PSI: — Recharge: -- Standard Evacuation Volume (3 casing volumes) Discharge: Total Volume of Water Removed (gallons): Cj 6 J Time (military) clS / 0'3 o� Q D� Volume Purged (Gallons) 0 qg 9 6 6 .6qi Water Level (ft.) stable 3 — — _ 7 ,Zg PH (sx.) * - G 7 6"15 4.1 Sp. Cond. (µmhos/cm) * lo•. 5 L , 2 535� gl - Water Temp. (°C) constan, 5- 0 �j, 1 15 Turbidity (NTU) :E10% 5NTU Dissolved Oxygen (mg/L.) *lox (. °) _ 2 5 5 RedOx PotentiaVORP (mV) *lo m.t - rj�j . f — �j - �� ,3 _ (�(, GPM/Hz i COMMENTS/OBSERVATIONS Fe2+ = 0 mg/L. r : v i Date: f % -(I- B: 14 L Page ) of ! aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: - a 2 4717A i - aJ Dedicated Pump: No Well ID #: 1302 - - Date: / - 1 19- j Weather Conditions: c1 a o Method of Well Evacuation: Grun dfo eristalticBP Total Well Depth in feet (TWD) = la " zt Method of Sample Collection: Grundfo Bailer eristalticBP Depth to Ground Water in feet (DGW)= $ Well Yield (subjective): try /, 66 Sample Date and Time: g 11,g e ©qYS 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = /,qC0 PSI: Recharge: —Standard Evacuation Volume (3 casing volumes) = Discharge: — Total Volume of Water Removed (gallons): p Time (military) 0 oszq OS39 /a-t9-r� o4y� Volume Purged (Gallons) 0 /. D 3 Q 6,1 Water Level (ft.) ga 13a pH (s_u_) A z 6_ b j e Sp. Cond_ (µmhos/cm) 16 341tik Water Temp. (°C) f 5. 5 �� /L 3 Turbidity (NTU) ±10%m<5NTU e�Q 15 3 V a�Ly- Dissolved Oxygen (mg1L.) Aio% RedOx PotentialJORP (mV) Aiom. -3 .� •- 5 - .. 6 7. —$�_ l — oiA g GPM[Hz r — COMMENTS/OBSERVATIONS: [JcLk r 6� ree,-7 6-ra y Pr u # T # d Fe2+ _ , (} m (7 Date: Page / ot_—/_ aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: _ C4 Dedicated Pump: No Well ID #: 1302 - - Dater - Weather Conditions: 60S S I Method of Well Evacuation: GrundfosM eristalticBP Total Well Depth in feet (TWD) = 3 p Method of Sample Collection: rundfos ail /PeristalticBP Depth to Ground Water in feet (DGW) = z 6- 7 ( Well Yield (subjective): 3 Sample Date and Time: / - 19 -1 & Z77C-L') 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = /„ 0 g PSI: — Recharge: Standard Evacuation Volume (3 casing volumes) _ j c� Discharge: ✓ Total Volume of Water Removed (gallons): g2 5a. Time (military) 2 12 Z �� Q Volume Purged (Gallons) 0— Water Level (ft.) smbk pH (s.u.) t 6_ .Z , Z 2 Sp. Cond. (µmhos/cm) = io•. -Z tf5 2 Water Temp. (°C) co"stam ) �j Is - Turbidity (NTU) :Eioia<_sxru �D 4- i 100 Dissolved Oxygen (mg/L.) do % S, 5,11 RedOx Potential/ORP(mV) f,omv ,2 2, oI r,L' Z GPM/Hz COMMENTS/OBSERVATIONS: 1 O Fe2+ = mg/L Odo f, IV Date: )'Z -1 9 -19 By. Page I of / aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: S — F ffis - G,cp— QjCr- I Dedicated Pump: No Well ID #: 1302 - W Date: Weather Conditions: Method of Well Evacuation: Grundfos aile eristalticBP Total Well Depth in feet (TWD) Method of Sample Collection: Grundfo ai eristalticBP Depth to Ground Water in feet(DGW)= ' fa Well Yield (subjective): . -�7 Sample Date and Time: - $ - 0 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 =3a C' PSI: AJ Rechare: Nq Standard Evacuation Volume(3 casing volumes)= Qr Discharge:N/�- Total Volume of Water Removed (gallons): o Q Time (military) 130r,, ) -- 1.3Z -q 13 z / I ILI Volume Purged (Gallons) 0 ; l.) $p 6 , Q) bQ j 0 SO Water Level (ft.) pH (s.u.) t z �t o Sp. Cond. (µmhos/cm) = io•. Water Temp.("C) conSWI �b,0 tiS, )S.3 15. Turbidity(NTU) _10%ms5NM S�- '63,S% Dissolved Oxygen (mg/L) do!% 5 "b ;� 0 RedOx PotentiaUORP (mV) fiomv kA I Is 3) i l ( 'Ls' q G PM/Hz ---�' COMMENTS/OBSERVATIONS: Fe2+ = mg/L Date: j2-15�is - By: d-Q, 4;�? 0 1 of I`72cieAnalytical' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: - o.AaA(v4-,-(cj Dedicated Pump: No Well ID #: 1302 - W - H Du - Date: I - Weather Conditions: Method of Well Evacuation: Grundfo ail eristalticBP Total Well Depth in feet (TWD) _ _ 9CI Method of Sample Collection: GrundfosMajieristaltic[BP Depth to Ground Water in feet (DGW) _ Zkq5 Well Yield (subjective): o0 ,q3 Sample Date and Time: I - q- /050 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = 3 PSI: -- Recharge: — Standard Evacuation Volume (3 casing volumes) _ _ a Discharge. Total Volume of Water Removed (gallons): _ 6. / a Time (military) Ul 1090 Volume Purged (Gallons) 0 3 0 - G / / Water Level (ft.) stable pH (s.u.) = 2 Sp. Cond. (µmhos/cm) = lo•. 2If 1, 1 9 1/9" Lj , 0 Water Temp. (°C) constant / 1 - Turbidity(NTU) F10%w<5NT, 2 r Dissolved Oxygen (mg/L) tlo% se,, - RedOx PotentiaVORP (mV) Flo nV ,j ,� Z —Z • 6 GPM/Hz -- r-- �- — COMMENTS/OBSERVATIONS: o 7,3 I Fe2+ = NV mg/L r ; Date: 17 • ( R " By: 2�f. (Page of ' aceAnalytical b FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: 0.CP- A `co. ` Dedicated Pump: No Well ID #: 1302 - - Date: IZ- Weather Conditions: pS Method of Well Evacuation: Grundfo eristalticBP Total Well Depth in feet (TWD) = 3 91 05 Method of Sample Collection: Grundfbsk1aij67PeristaJticA3P Depth to Ground Water in feet (DGW) =,'( ,3 ( Well Yield (subjective): D r- "% . Sam le Date and Time: /g //,- 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = �, Q PSI: Recharge: -� Standard Evacuation Volume (3 casing volumes)- . 3 j Discharge: Total Volume of Water Removed (gallons): Z. C Oq0111-1 u Time (military) �1,1q.;01I;?5- Volume Purged (Gallons) 0 1.103 , ZO Water Level (ft.) sable pH (s.u.) t 2 6 g COo fo Sp. Cond. (µmhos/cm) d: to •. Z j LI- 6 y 5 Water Temp. (°C) eons=l r , I Turbidity (NTU) +10% 55MU ::f-T E 19 Dissolved Oxygen (mg/L) A 3F 3 RedOx Potential/ORP(mV) flomv 3 /a(3n 7 GPM/Hz --I-` COMMENTS/OBSERVATIONS: M % (k Color C,-OM.� Fe2+ = mg/L d ©r ; WIP Date: a- 19 - 1 S v i rat�F 0 Wage ' of I aceAna/ytica/ FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: a (� ,'C Dedicated Pum : No Well ID #: 1302 - — k Date: Weather Conditions: S S' Method of Well Evacuation: Grundfos a' eristalticBP Total Well Depth in feet (TWD) = Method of Sample Collection: Grundfos alter ristalticBP Depth to Ground Water in feet (DGW) = 22 ,3 3 Well Yield (subjective): !gyp 1Ya 0 5 Sample Date and Time: 2" Well: I Casing Volume in gallons (CV) = LWC x 0.I63 = PSI: Recharge: --- Standard Evacuation Volume (3 casing volumes) = Discharge: —� Total Volume of Water Removed (gallons): 7-0 Time (military) j 3 l�J 171 j /- j p• t o3, Volume Purged (Gallons) 0 Water Level (ft.) 9ab{e m(_ 3 — A pH (s.u.) t , 2 'o Sp- Cond. (µmhos/cm) tgj.--- ) t? 3. j Water Temp. (°C) co"n�t 16 IA -0 Turbidity (NTU) ±I0%m:S5NTU Dissolved Oxygen (mg/L) f{oi 3c.9 RedOx PotentiaUORP (mV) GPM/Hz -� •—'— COMMENTS/OBSERVATIONS: Sj--(} 02 r f I A�Z�6a iFe2+= PD mg(L ., Date: I a - / � - ( Page I of aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: eA 1' Dedicated Pump: No Well ID #: 1302 - 6:.- Date: Weather Conditions: -510 °F Method of Well Evacuation: GrundfosBailer r'� tic/BP Total Well Depth in feet (TWD) Method of Sample Collection: GrundfosBailer/P ri icBP Depth to Ground Water in feet (DGW) _ // YZ Well Yield (subjective): ��r9 f Izllfll ° Sample Date and Time: 7727 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 PSI: Recharge: Standard Evacuation Volume (3 casing volumes) = Discharge: Total Volume of Water Removed (gallons): D, 3 Time (military) I 5- L $ SS I S5 I Volume Purged (Gallons) 0 ©�0�- 0 o 2 3 —+ 0+3 I6 tq91 Q, 3 �} S Water Level (ft.) Aable IF I k g I I $6 1) 5 I I �$�, I I pH (s.u.) t 2 S,, Sp. Cond. (µmhos/cm) =io•. 101 , ,0I , ti1��1 "e �.� $1.,Z $6,0 %1 Water Temp. (°C) consa,,, � �{ Z i Turbidity(NTU) d0%or55NrU iL 3,O Dissolved Oxygen (mg/L) do % 3, 3. k Z L Ig' RedOx Potential/ORP (mV) t,omy I VL S 01, �I •-r- GPM/Hz I — — — --- COMM ENTS/OBSERVATIONS: Ado J�f 7h1 Z39 -1 ) Fe2+ = mg/L 0N n Date: _le, /,,� //,P By: — Page ! of / 11�7;a?cie Analyticai FIELD DATA INFORNL9TIONLOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO_ SANITARY LF UNIT Casing Material: PVC Field Personnel: Ce o, j Dedicated Pump: No Well ID #: 1302 - rnvi- Date: /a - - / g Weather Conditions: O'S Son fix— Method of Well Evacuation: Grundfo eristaltic/BP Total Well De th in feet (TWD) = 3 Z Method of Sample Collection: Grundfos ailer/PeristalticBP Depth to Ground Water in feet (DGW) _ Well Yield (subjective): C7X 22. Sample Date and Time: a - - / S' (° 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = 3. 6 PSI: - — Recharge: Standard Evacuation Volume (3 casing volumes) = Discharge: -- Total Volume of Water Removed (gallons): il. p O Time (military) 1, /9-/q//CIO Volume Purged (Gallons) 0 ,33 _00-7 Water Level (ft.) stable 9, pH (s.u.) t 2 6.3 S Sp. Cond. (µmhos/cm) Rio•. l f,y n 0, I ($5. Water Temp. (°C) eottstam J S • 13, (o Turbidity (NTU) ;io %m<5NTu 'Zc .5 11& G I. Dissolved Oxygen (mg/L) tiov. 2 • z 2 -3 1, Z 3„a RedOx Potentlal/ORP (mV) fiomv o, �. -Z V67 G PM/Hz COMMENTS/OBSERVATIONS: V5Z efUS Fe2+= mg/L Date: () - (( 6 Page of t 1--7;a?CG- Analytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: J IlY1 c,G� �) �Ca Dedicated Pump: No Well ID #: 1302 - 14M - Date: - 19 I? Weather Conditions: .150'r SLnnw Method of Well Evacuation: GrundfosBailer/Peristaltic Total Well Depth in feet (TWD) = qz (j Method of Sample Collection: GrundfosBailer/Peristaltic Depth to Ground Water in feet (DGW) = 5 Well Yield (subjective): Coof D 6 Sample Date and Time: 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = PSI: 49 Recharge: Standard Evacuation Volume (3 casing volume = 2a . 0 a) Discharge: Total Volume of Water Removed s . '70 L— Y4 t-- Time (military) Q )306 3 ) Volume Purged ( ' 0 500 59 30 N c1 5 5 Water Level (ft.) sable �Z ,q57 - pH (s.u.) 6.0 6,G a , a Sp. Cond. (µmhos/cm) tlU•. /- 0. 0 y 0. (-Ill./ `f 41 . 6 Water Temp. (°C) 16 Ll - 9 L M. Cf 19.1 Turbidity (NTU) :00yor<5NTU V. y i3, 17.6 1 2 10.9 IQ 5 IT Cj Dissolved Oxygen (mg/L) Cloy 0, () . rj 0150.5 RedOx PotentiaVORP (mV) tlo my 3, 12 2 2 - 3 GPM/Hz -- -- — —� COMMENTS/OBSERVATIONS:s4a Q 160 mL 5 -In wall,/0 t,J o Fe2+ _ 9 , Q mwL n p Date: / Z - � - f By: Page 1 of Z— 1�7;ZeAnalydcal- FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: ID - GCS. c.I Dedicated Pump: No Well ID #: 1302 - Date: - Weather Conditions: Method of Well Evacuation: GrundfosBailer/Peristalti BP Total Well Depth in feet (TWD) = Method of Sample Collection: GrundfosBailer/Peristaltic P Depth to Ground Water in feet (DGW) = Well Yield (subjective): aced Sample Date and Time: Iq -/ 13111 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = PSI: Recharge: /p Standard Evacuation Volume (3 casing volumes) = Discharge: Total Volume of Water Removed (gallons): Time (military) )3 /0 Volume Purged ns) Water Level (ft.) sable pH (s.u.) t 2 6 ,6 Sp. Cond. (µmhos/cm) 10-. / , Water Temp. (°C) eonsun, J q, �, Turbidity (NTU) t10Xor55Nn) !- Dissolved Oxygen (mg/L) *10y 5 RedOx Potential/ORP (mV) tlomv , GPM/Hz COMMENTS/OBSERVATIONS: ID6 T�l��O Z3 Fe2+ = mg/L Date:_ uZ' I 1-1 Up Page f �r aceAnalytical " FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: Dedicated Pump: No Well ID #: 1302 - W - Date: 12 - ,�i - 19 Weather Conditions: �f %� �,,, Total Well Depth in feet (TWD) Depth to Ground Water in feet (DGW) =-3'1 N Method of Well Evacuation: Method of Sample Collection: Well Yield (subjective): ,Sample Date and Time: 1 t 119 GrundfosBailer/Peristaltic _ GrundfosBailer/Peristalti D 1 t 1303 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = Zl PSI: Rechar e.. Standard Evacuation Volume (3 casing volumes) 0 Discharge: S' 1PCo, oil Total Volume of Water Removed ( allons): O + [S$ Time (military) 12� I( S} 3 0� Volume Purged (Gallons) 0 ('� �0 - , Water Level (ft.) stable S"O'IN pH (s.u.) t 2 Sp. Cond. (µmhos/cm) = lo'. Water Temp. (°C) Constant Turbidity (NTU) bl %w:55 5 NTU 6 � �A 0, 3 Dissolved Oxygen (mg/L) tlox $ d , 0' RedOx PotentiaUORP (mV) tlomv -513.3 SZo. S GPM/Hz COMMENTS/OBSERVATIONS: IS I pl% Ql\,s t 344l I`^��Ro T^( 1i'11?' Fe2+= O,0 mg/L Date: 1Z // 9//.r Page ( of 1 /'-� 2aceAnalytical' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: S cC Dedicated Pump: No Well ID #: 1302 - F (ht4) Date: ' - ZO Weather Conditions: Ej° — Qwrn Method of Well Evacuation: Grundfos/Bailer/Peristaltic Total Well Depth in feet (TWD) = Method of Sample Collection: GrundfosBailer/Peristalti Depth to Ground Water in feet (DGW) = i 3,Oq Well Yield (subjective): , Sam le Date and Time: i oL 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = Z PSI: Recharge: Standard Evacuation Volume (3 casing volumes)_ W,S1 Discharge: /J' Total Volume of Water Removed (gallons): #'ihtJ. 4UU—.'!�1 Time (military) j I LI -C I LI S �I g Volume Purged (Gallons) 0 \D--A- 9 O� S� —9,,n s ��• ►y Water Level (ft.) stable 3,o�r 23.1) PH (s.u.) t 2 S S S , Sp. Cond. (µmhos/cm) 4 to •. LI , j � U ,� l ill 4 13 Water Temp. (°C) cu"sunt 1315 13 S Turbidity (NTU) tI1516 rnU 31�� LA�2 Z Dissolved Oxygen (mg/L) tlo % i • 9 2 , RedOx Potential/ORP (mV) tlomv 4 1-1 -U GPM/Hz COMMENTS/OBSERVATIONS: OSS ��SI PRES3�I�Z iCRo 11$� Z Fe2+= /N mgfL 10D)a Date: J ZO f j � � � � �iENNEF---- i Page ( of 2 aceAna/ytica/ FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: ,� 5 pact 1 ;, C a I Dedicated Pump: No Well ID #: 1302 1AJ_ 2 Date: I - 1rK Weather Conditions: Q Method of Well Evacuation: GrundfosBailer/Peristalti Total Well Depth in feet (TWD) _ (2 , 0 Method of Sample Collection: GrundfosBailer/Peristaltic Depth to Ground Water in feet (DGW) = 23.5 5 Well Yield (subjective): .2 5 1 Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 =hl. PSI: Recharge: I Standard Evacuation Volume (3 casin volu es - ( Discharge: { Total Volume of Water Removed ( r» 0 yn Time (military) Z Z 5 { Z Z ig, I Z 3 l Volume Purged (Gallons) 6 0 5300 6o 59 Water Level (ft.) stable 3 bG . 60 c pH (s.u.) , 6 L6 . o 6 Sp. Cond. (µmhos/cm) 22 4- Water Temp. (°C) constant 1 j (3. Z 13,2 Turbidity (NTU) :L10yor55NTU Z, 0. Dissolved Oxygen (mg/L) Cloy RedOx Potential/ORP (mV) *lomv5- GPM/Hz I COMMENTS/OBSERVATIONS: S. I iLv� 'tom 3o n,;nV4-CS IM nAL Fe2+ = mg/L ( : e Date: 11 , !.V By: Page —L— of J //7� za Anaiyticai ' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel• A M3 - Dedicated Pump: No Well ID #: - G 5 Date: ) Z_ Weather Conditions: Method of Well Evacuation: Grundfos/Bailer/Peristalti Total Well Depth in feet (TWD) = � % Method of Sample Collection: Grundfos/Bailer/Peristalti Depth to Ground Water in feet (DGW) =J/-,0 c3 Well Yield (subjective): f Sample Date and Time: 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = PSI: Recharge: Standard Evacuation Volume (3 casing volumes) _ ;2,09 Discharge: 1,0 Total Volume of Water Removed ns): IM (ylt, jp1f--(5 Time (military) /5/0 15131 / I57,67 Volume Purged rnL- 0 300 rAl✓ �� rrl /ZDCi S % �b� Water Level (ft.) stable A5 16 a5. Z z 5 lb )46 16 -1 zl� 11-b pH (s.u.) Sp. Cond. (µmhos/cm) _lo•. $7 j09.1 ,7 i(>, /f )1 _ Water Temp. (°C) eonsum 11 0 / tom- Turbidity (NTU) 3l0 %a fi 5 NM _ , g 6 _ z, Dissolved Oxygen (mg/L) *10% `J . O :7c rJ' 5. 6 RedOx PotentiaUORP (mV) tlomv GPM/Hz '— COMMENTS/OBSERVATIONS: /e Fe2+ - mgf L Date: 0 - 1 7 - 1 q Page / of / 1�7;a?CeAnalydcal" FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF UNIT Casing Material: PVC Field Personnel: Bvvy / Z(> PwcR. Dedicated Pump: No Well ID #: 't-302�I-Ll'+jT G 10 Date: ti 2 I '} ! S Weather Conditions: 60"F Method of Well Evacuation: Grundfos/Bailer/Peristaltic Total Well Depth in feet (TWD) Method of Sample Collection: Grundfos/Bailer/PeristaiticAgD Depth to Ground Water in feet (DGW) _ , SZ Well Yield (subjective): (5:-o Sample Date and Time: 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 0�wjjo„S PSI: 34 EQ Recharge: 10 Szco,.�s Standard Evacuation Volume (3 casing volumes) = I Z , I Z la..s Discharge: j Z Seto ,d s Total Volume of Water Removed (gallons): O, 66 c q/ rarc,e. Lfcfe.t IHV L/mir,%f— Time(military) S36 S S�I� S 95Sy Volume Purged (Gallons) 0 1 1 O, -L O 1 SS 66 Water Level (ft.) stable 23,�1C 1},q6 1�.9b 1�-.�6 Z,-3r ( Z.MC 2-i-,9'6 PH (s.u.) _ , .I l 6.1 6 1 6, 1 6 j 611 Sp. Cond. (µmhos/cm) b 10'. 11,4 , 16 , E 116 , $ Water Temp.(°C) runsum I5,9 Turbidity(NTU) Eloicwnsrrw 1$,k Dissolved Oxygen (mg/L) 1:10% Ll ,© 3.7 RedOx Potential/ORP (mV) flllmV -Ls-,O 14 , S Z,S,,-L ZS, -LEE -Z, GPM/Hz I - — — �� — 1S 12 I t- I $ COMMENTS/OBSERVATIONS: Fe2+= O,Ci mg/L Date: / Z//;PLf/,F t Page 2aceAnalydcal- //7� FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER. & MCKEE_ INC. - RALEIGH Casing Diameter: 2" Site Name: CABARRUS CO. SANITARY LF L`NIT Casing Material: PVC Field Personnel: Dedicated Pump: No Well ID Date: Weather Conditions: QS /I Method of Well Evacuation: Total Well Depth in feet (TWD) _ — Method of Sample Collection: Depth to Ground Water in feet (DGW) _ — Well Yield (subjective): -- Sam le Date and Time: 12 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = — PSI: Recharge: Standard Evacuation Volume (3 casing volumes) _ Discharge: -� Total Volume of Water Removed (gallons): — Time (military) Q Q Volume Purged (Gallons) 0 Water Level (ft.) rae<< '-- pH (s.u.) * - 7-e 6 Sp. Cond. (µmhos/cm) * 10'. 33 5 Water Temp. (*C) COMM 6. oL Turbidity (NTU) fio%an5NTU J$, Dissolved Oxygen (mg/L) *10 RedOx PotentiaUORP (mV) r GPM/Hz COMMENTS/OBSERVATIONS: Fe2+ = mg/L Date: t 2 - I q - 11 14 Page 1 of aceAna/ydca/ / /� ! FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: CAMP. DRESSER. & MCKEE. INC. - RALEIGH Casing Diameter: 2" Site Name: CA13ARRLJS CO. SANITARY LF UrNJT Casing Material: PVC Field Personnel: GCQ tq no, 136J.Xc Dedicated Pump: No Well ID #: UA, - - Date: - 1 Weather Conditions: p Method of Well Evacuation: Total Well Depth in feet (TWD) = — G1 Method of Sample Collection: Depth to Ground Water in feet (DGW) _ — Well Yield (subjective): ,Sample Date and Time: Z- lj� - D 'v 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = y— PSI: .� Recharge: --- Standard Evacuation Volume (3 casing volumes) _ — Discharge: l Total Volume of Water Removed (gallons): --- Time (military) /00 Volume Purged (Gallons) 0 Water Level (ft.) stable --� pH (s.u.) t z .2- Sp. Cond. (µmhos/cm) t lo•. 6 6 Water Temp. (°C) eo"51att, Turbidity (NTU) ±lo %or f 5 Nru / Dissolved Oxygen (mg/L) tlo RedOx Potential/ORP (mV) tlomv '2: GPM/Hz COMMENTS/OBSERVATIONS: Fe2+ = --- mg/L en Date: I Z- I 0- 19 By: lev Page I of WELL INTEGRITY AND WATER LEVEL FORM Project Name: Cabarru!(f©L F Date: 01- IS- I01 Site Location: Xan no, 122 1:5 /\)C- Weather: 5 Field Personnel: J"-) S - (3 6 S - Fog_ _ W. L. Measuring Method: Page t of Sounded c �^ jai .o 9 o m t c o C�• 2 0 a� 0 `o y > m Well ID TIME Water Level (BTOC) Depth o �. d co •-' u, m •co �' v ) C'• o y m n a o ° " v � c 5 m m ° c.. c CL 4— o a� �. 3 CL v m e Q. m a 4).2 . i 'o :° o Comments (feet) (BTOC) o coi ° a Cl m m Y °� o 0 � � c� � r oo CL c0 N (feet) — �� n o Y m o' i a m m o o N N ® N N N N C6b J� /'N N 00 NA NA NA NA NA NA NA NA NA NA NA NA LEL= V OZ_ i \ N N IR N N tV N N tP QV CAP N Zl `t M W - LdeeP NA NA NA NA NA NA NA NA NA NA W NA LEL= OZ_ M 6$ S i� i� 3q, S N N & N N Tb N N � QED FA N � y D �,!- NA NA NA NA NA NA N NA NA N LEL= 02= G 0.9 �� 12.3 ci. S. �j NA NA N NA NA NA N NA NA NA NSA A LEL= 4.0 02_ t/Z 3 u N N A N NA N NA N NA N NA N NA N NA N M, NA N NA NA N NA LEL= 0 02= u� ��•\ �S 1 F N N N N N N N `N ` I } �• NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= • N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA JNA NA LEL= 02= I have received this Well Integrity and Water Level Form(s): ignature e (_ 17 y Date Project Name: Cabarrus County Landfill Site Location: Concord North Carolina Field Personnel: ,\ m WELL INTEGRITY AND WATER LEVEL FORM Date: 12 -11 .119 Page of �( Weather: 315 51" An,, W. L. Measuring Method: 7�j i�t / Water Level Sounded c —'' ai '0 v d N m` C o o v o �. adi L w C Y 0 C-. is 2 .- p _ m d — d o d > co '0 o v C m w Well ID TIME (BTOC) Depth (BTOC) ,m a;�v d d .0 y�, v, �� d tp on n o oar Q to �� do d` C-• �a E M o o d C-. 3na�v v m to " o ,n ,n dP:. o o '° c � Comments (feet) (feet) 0 1° _ cdi > (UO o — 0 M Y Y t`v y —> N o w n C w 3 a n w o o O C M U > C C N J - � A 0'126) Z- r , 15 LL 7 7, l 0 NA N NA f,S 9A N N N N N NA 0/� NA ` AA' N NA L E L OZ= `� W -� O , 5 v 9 91.95 NA N NA NNAA N N N N NA N NA N NA (N 1 f� NA N NA / LEL= �' ©l OZ= a3 G 35.57 N NA N NA IC- P NA N NA N NA N NA N NA N NA_ N NA 6D NA N NA N NA � LEL=J o OZ= lI 7 p 6 32,69 3 2 N X N N N N N © �IQJ N 1 10 f D NA N 3 N NA N NA NA NA NA NA NA NA LEL= OZ= a �� �I N V� N N N N 0,v,l N d t� N��•�'A -1� NA )LAN NA N A NA NA LEL= `S ` OZ_ N NA N NA N NA N NA N NA MA N NA N NA rJ A M A N N L LEL= O • I Oz= 1 p ! ►'hW l J. �� ® N N N toN N NA NA A N LEL= ©.� `I OZ_ t �O I ® M N N N N N N LEL=3� VOZ_ y�/� - D I NA NA NA NA N N NA NA NA NA YAW A. L' I I r 30� L �lJ • 13 NA (a)® NA IV NA N NA N NA N NA N NA NA 9 NA NA N NA ® NA �� LEL= OZ= q, O ! J I �i L 6 5 I �j N N N N N N N N N N N N `/ f LEL= �� (� OZ= M W " e2 NA NA NA NA NA NA NA NA NA NA NA NA 1 have received this Well Integrity and Water Level Forms) Z ' Signature Dates c�- Z ri_ 3 '/3 It 1/3 Project Name: Cabarrus County Landfill Site Location: Concord North Carolina Field Personnel: WELL INTEGRITY AND WATER LEVEL FORM Date: - Page 3 of Weather: _'v rw W. L. Measuring Method: Water Level Sounded c c. —' ai L 3 v :? T a s O 0- P O v c, w r.. °' L C1 .Y " C. 0 ' p — m N - o 0 -o a N 19 > m w -O v Well ID TIME (BTOC) Depth (BTOC) u; m �, 0 w N — 0 �' v, 0 0 o 0 o a) c m N m o �, `m 0 a'o c �, E U 0 aD N 3 Q- '0 m 0 U im �, �, o °J 0 0 � d c U Comments (feet) (feet) 0 __ y o �� n n — d m _X M "Y �o o �3 o mo a� om a� d I ILL U c J io►,IS ZL1,S �� N N N N `N N N �I N 1 i ' ` Mw t NA NA NA N_k NA NA NA NA NA NA NA NA LEL= Oz= t 1. "� 'p -A �) ' K •�� NA A NA NA A NA NA NA NNAA NA LEL= l � Oz= ��� ©t� � W -C l �� NA NA A NA A N NA NA IOTA WA IOTA NA LEL= OZ_ T W 3,� N O NA RA NA NA NA NA A NA NA LEL= kQ) , oZ=Z 1 I 35Z d NA �t� �t 1�`o tJ` °-Xa3 NA A A NA A NA NA NA A LEL= Oz_ ` 3 ` 3 35 S NA NA NA NA / I,f - •5 NA NA NA A NA A NA NA LEL= j t5 Oz_ yy t 114rd N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA LEL= Oz_ ONA C !NA NA A A NA A NA NA NA NSA NNA A LEL= l� N ® / NA NA NA NA NA NA NA LEL= `�� Oz= 1 %,•� I� S� N N N N N N N O / ` �Q N A -L J NA NA NA NA NA NA NA NA NA NA NA NA LEL= .0 O z- 1 I4a�j t I have received this Well Integrity and Water Level Form(s) iZ q ;�- le-2 Signalure Date Project Name: Site Location: Field Personnel: Well ID ij.. L WELL INTEGRITY AND WATER LEVEL FORM Cabarrus County Landfill Date: / Z - fI " lCw Concord North Carolina Weather: 10/6 S SU� Jr)S I 66MS - W. L. Measuring Method: _ i Sounded C O Water Level m m y C'' TIME (Bf O j) (BTOC) o ai 0 o (feet) _ o CL n /��/ / "� q 2 / S3 _N NA N Cy NA . Lq NA NA (NA N 6 NA z NA �) lS � , 7 NA N NA IvCv1 v�p. �� 33FU(3 N NA NA 1O O Z 5 rjcj 16 NA NA A V 3,0 10 NA N NA ICJ V) �La 7 ;NA WA NA N A NA NA A l t O 0 N= o� V 7 O a) 0 (o m j (OD -. CU N C'. o d -� 0' w coo �' n w O a) (�. 3 o fo C a m O U N :: U a) 2� Comments C1. to CA (o O U y " N V rn rn f9 t O O n C Q) Y N y 2 U C j c C > ��' O_ aoio o�c �o � U c N N ;NA N NA NA A NA N NA LEL= C� ) /, Oz= firr^ 5 NA NA NA N N N NIO N p `� 1) �b \J, 6 NA NA NAtNA LEL= ` Oz= N N N N N N N /I Ot Oz= NANA NAA NA LEL= N N N N M N N (( t N NA N NA NA NA NA NA NA NA LEL= Oz= N N N Ic N (` Oz= N NA NA NA N NA NA LEL=+0 N N '® N 0 / Oz= N NA NA NA NA NA NA NA NA LEL= N 17- N (cm ® N � 0 /� �� NA NA NA NA NA NA NA NA NA LEL= Oz= . N N N N N N 0�� Oz= NA NA NA NA NA NA NA N LEL= t I l�N N N N N 19 fR & N � NA NA NA NAA NA NA ,� LEL= Oz= /` Oz- �� S\ OA NA NA NA NA N NA NA LEL= I have received this Well Integrity and Water Level Form(s) 4—,J � IZ-/-;Z�-/8 Signature Date WELL INTEGRITY AND WATER LEVEL FORM Project Name: Cabarrus County Landfill Date: jZ - f I - 4 Site Location: Concord North Carolina Weather. �0'5 S Lit Field Personnel: ' - ace A o /_� W. L. Measuring Method: Page -1 of ° L 3 T o N o N c U t` H O — of N C Water Level Sounded c ° �. >1N m ° �, �. n v m o `� N N L o �. � w — °' �. °° > •U 1° v u m Well ID TIME (BTOC) Depth m m m y v, y o m n° MN o ° �' n m ° m 3 n o m n m w fn m a; . o o ;g � c u Comments (feet) (BTOC) U ° f6 —m °' o° a o —_M `—° c �� m> °o g ° mu 2 � -m Y N (feet) °' cf6i Y a a°i 3 o j j N j° C U i C N° J NSA NSA Lip \� ` OZ= LEL= � C -Z NA NA NA NA NA NA NA NA NA �� 1Ob 2 Z oZ Z � NA N N NA NA NA NA � NA NSA NA LEL= O ,O / OZ= ZS \\ °I1 �� 2- 5 NSA NA NA A NA NA NA NA NA NA NA NA LEL= O �� ` �`/ OZ_ Z� N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ, N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ_ N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= Oz= N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ_ N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= OZ= — t� -Z I have received this Well Integrity and Water Level Fonn(s) — Stgnature Date Appendix B NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: This larnr ar+d our infvr+++rrnus artrrrh to rr are Prr6hc REKv+vls"rrs rleJiaee! rn NC General Snmire 132-1. ,ts srrr'h, r&ese dui rrureuls rrre inudeihle for inspection rind exauuna inn hr• w7v person upon +'equesr WC Grneral Stature 132-6) Facility Name: Sampling Date: Sample Collector Name & Position: Gas Meter Type & Serial Number Field Calibration date & Time: Permit Number: _ /. T 61a Landfill Rule (,0500 or, 1600): aoC) — 3 3 9So '-'Gas Meter Calibration Date: Field Calibration Gas Type [ 15/15 0t 35150]: Field Calibration Gas Canister Expiration Date: Gas Meter Pump Rate: Ambient Air Temperature: r Barometric Pressure (in. or mm Ng): . 05weathcr Conditions. Instructions: Under "Location or LFG I Afell", fist monitoring well # or describe monitoring location (e.g., inside field office). Attach a test location rnaV or drawing. Report methane readings as both % LEL and % CI la by volume. ConvertU Cflt (6y vvlu e) to %LEL as follows: %methane (by volume)IZU = %LEL. *llydrag-n Sulfide (1Y2S gas monitoring mrry be regtrired jar Construction & Demolition Lirnfgills jCDLFsf. See individual permit condid s a+rdlor Facility 1 FG monitoring plait. ry Sample Tube Purge i _. i' M W I ___m__ MM a s f ~ [ 6 11 -. .] � 7 M= 1 ' � I"t ` M NOTE. !/'needed, arraclr additional data forna ro [ elude additional LFG mnnitoring darn locutions for dje facility. ACMON LEVELS: Methane: >1.25% b volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen Sulfide: % by volume (inside structures) AND ?4% by volume (at facility boundary) Certification To the best of my knowledge, the in ormation reported and statements made on this data submittal and attachments I true and correct. I am aware th t there are significant penalties for making any false statement, representation, ❑r certification including the possi lity of a fine and imprisonment. RE " ' � TITLE Revised -- March 6, 2017 NC D' ision of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: This lunar and am iafurniuttan atrrtrlr Yd to it are Public Recorzls"as derwed in NC Geuetrd Stamie l3 2-1- As such, these duounenu Ore ataadable for i+r.rpectrurr and exurnirra run by a+{r per soar ryomi request (NC General Stain re 13 7-6) Facility Name: Permit Number: Sampling Date: NC LandfiII Rule (.0500 or. 1600): Sample Collector Name & Position: Gas Meter Type & Serial Number: Gas Meter Calibration Date: Field Calibration Date & Time: Field Calibration Gas Type (15115 oi 35150): Field Calibration Gas Canister Expiration I)ale Gas Meter Pump Rate: Ambient Air Temperature: Barometric Pressure (in. or mm Hg): Weather Conditions: Instructions: Under "Location or LFG el€", list monitoring well # or describe monitoring location (e.g., inside field office). Attach a test location mac r drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % C114 (by vole e) to % LEL as follows: % methane (by volume)/20 = % LEL. *11ydrogen Sulfide (112S gars monitoring nitro be required jar Construction do Demolition Landfills (CDLFS). See individual permit conditi is andlor Facility LFG nio►riloring plan. Location or LFG izoaWelI Sample Tube Purge Time of Day Time PumpedInitial {sec] 3, LEL Stabilized % LEL %CH3 (volume] % d2 {volume] % CO2 (volume) "% 1125• (volume] NOTES Ke `911r ( � �' %!� Or F 0 [ f (3 tj t D U v CJ / &. + ❑ 0 /9. o, o n e ' 3S 3 D j S / D 0 It 3c6e& Sf43 ❑ o I t C) b C) o CC'- dr V t] U NOTE If needed. attach additional daw forms to i chute additiatred LFG mo+ritoring data locaitans for the facilrn•. ACTION LEVELS: Methane:-_1.25% b volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen Sulfide: % by volume (inside structures) AND >4% by volume (at facility boundary) Certification To the best of my knowledge, the inFormation reported and statements made on this data submittal and attachments are true and correct. I am aware th t there are significant penalties for making any false statement, representation, or certification including the possI 'city of a fine and imprisonment. TITLE Revised — March 6, 2017 INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 24 Tower Office Park Woburn, MA 0 180) Poll -free: (800) 519-PINE (7463) Pine Environmental Services, Inc. Instrument ID 33250 Description GEM5000 Calibrated 9/13/2018 4:09:02PM Manufacturer CES Landtec State Certified Model Number 5000 Status Pass Serial Number/ Lot G50309 t Temp °C 23 Number Location Massachusetts Humidity % 56 Department Calibration Specifications Group # 1 Range Ace % 0.0000 Group Name Methane(CH4) Reading Ace % 3,0000 Stated Accy Pct of heading Plus/Nlinus 0.0 Nom In Val I In Val In True Out Val Out Type Fnd As Lft As De►•% Pass/Fail 50.0; 50.0 %Volume 50.0 %Volume 48.9 50.0 0.00% Pass Group # 2 Range Ace % 0.0000 Group Name Carbon Dioxide (CO2) Reading Ace % 3.0000 Stated Ace), Pct of Reading Plus/Minus 0.0 Nom In Val 1 In Val In Type Out Val Out Type Fnd As Lft As DeVI/0 Pass/Fail 35.0:35.0 %Volume 35.0 %volume 34.2 35.0 0,00% Pass Group # 3 Range Ace % 0.0000 Group Name Oxygen (02) Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Nlinus 0.0 Nom In Val 1 In Val In TVPC Out Val Out lype Fnd As Lft As Dev% Pass/Fail 20.9 ' 20.9 %Volume 20.9 %Volume 20.6 20.9 0.0040 Pass Group # 4 Range Ace % 0.0000 Group Name Hydrogen Sulfide (H2S) Reading Ace % 3.0000 Stated ACC%' Pct of Reading Plus/Nlinus 0.0 Nom In Val 1 In Val In Type Out Val Out Type Fnd As Lft As Dey% Pass/Fail 25.0' 25.0 PPM 50.0 PPM 24.2 25.0 -50.00% Pass Group # 5 Range Ace % 0.0000 Group Name Carbon Monoxide (CO) Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Nlinus 0.00 Nom In Val 1 In Val in. Type Out Val Out Type Fnd As Lft As Dcv% Pass/Fail 50.00150.00 PPM 50.00 PPM 49.10 50.00 0.0011/;, Pass Pine Environmental Services LLC Windsor Industrial Park, 92 north Main Street, Bldg 20, Windsor, N3 08561, 800-301-9663 www.pine-environmental.com INSTRUMENT CALIBRATION REPORT Pine Environmental Services, Inc. Instrument ID 33250 Description GEM5000 Calibrated 9! t 3l2018 4.09:02 PM Test Instruments Used During the Calibration Tcst Standard ID Description Manufacturer Model Number NC 4 GAS 20.9 NC 4 GAS 20.9 Gasco 3221E FBH-412-6 EX FBI1-412-6 EX 5/19 5 19 NC 50 CH435 NC 50 CH4!35 CO2 Gasco GP 12115 -- 0O2--MAP-399- 31803 51-20- Notes about this calibration Calibration Result Calibration Successful Who Calibrated Jonathan P. Smith Pine Environmental Services LLC 24 Tower Office Park Wobum, MA 01801 Toll -free: (800) 519-PINE (7463) As Of Cal Entry Date Serial Number ! Next Cal Date Lot Number East Cal Date/ Expiration Date Opened Date FBH-412-6 5/19i2019 MAP-399-5 1/20/2020 All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the manufacturer's specifications and/or the customer's own specific needs. Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment Please call 800-301-9663 for Technical Assistance Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663 www.pine-environmental.com NC IVurirr: T1res loran u+rd rum er+Jor•rrrr+lic„r II"ril.rhle for irr.cpeererrrt and ea Facility Name: Laoam L4 (YX Sampling Date: 19— ) a - f Z Sample Collector Name & Position: Gas Meter Type & Serial Number) Field Calibration Date & Time: sion of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form to it ur•e "Public Rccn+rals"as rleJirreal ir+ NC Gener u157at ae 13 i-1- ds such. w-r M hY am person upon reyrrest {NC Genera! $tar,ete 132-6) Field Calibration Gas Type (I 5115 oo 35150): Gas Meter Pump Rate: Permit Number: �-� - d,� NC Landfill Rolle f.0500 or.1600): L09 a 1 Gas Meter Calibration Date: Field Calibration Gas Canister Expiration Date. Ambient Air Temperature:. L�a Barometric Pressure (in. or nun Hg): Weather Conditions: Instructions: Under "Location or LFG Well", Iist monitoring well 4 or describe monitoring location (e.g., inside field oMee). Attach a test location map or drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % C114 (6v volu e) to % LEL as follows: % methane (by volume)120 = % LEL. *flydrogen Srelfide (H2S) gas monitoring may be required for Con,struclion & Demolition Landfills (CDLF.$). See individtial permit conditio rrs andlor Facility LFG nroniioring plan. [.exation ur I'M Well ED Sample Tube Purge Time of Day Time PUmPLI {sect Initial � �o LEL Stabilized Io LEL % CH4 (volume) /a 02 (volume) °i CO2 (volume) % 112s• (volume) N[7Tl;5 �y L [1 r C r V '' }} o. I � ' C) � �, l o �a L( r r I `n t� �rf 0 r , 3S b � apler o C>, a �] � r Lq l�C� / 1 �d J� �3 7 r 7 Q sic C) a C i o-/ o vs o b 9fe/ n•I 0 d rC i U o D a NOTE: lrneeded. artach addirioa+al dare forn+r to i elude adetitional LFG monitoring darn+ locations fi,r Mcfaudity. ACTIONLF.4'F.L5: Methane:-1.25°!u b volume (inside structures) AND >5"/ by volume (al facility boundary) Hydrogen Sulfide: % by volume (inside structures) AND mod% by volume (at facility boundary) Certification To the best of my knowledge, the are true and correct. 1 am aware oncertification ingludine the vos! EN 1111LI 9 rmation reported and statements made on this data sttbmittaI and attachments there are significant penalties for making any false statement, representation, ty of a fine and imprisonment. r TITLE/ Revised •- Marrh 6, 2017 NC Nate, rl+(s jerrnr arrd rmr urfor7MIUMr [ri errf[rhle_jor inspection and es Facility Name sampling Sample Collector Narne & Position: Gas Meter Type & Serial Number: Field Calibration Date & Tinie: sion of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form to it are "Public Records "as defused in NC Generul Statute 132. 1. As retell, these [lucifulep tS [n-c• i by ons•persorr upon request tNCGenera I Stetlrne 11 i-61. Field Calibration Gas Type (15115 off 35150): Gas Meter Pump Rate: Ambient Air Temperature: Instructions: Under "Location or LFG Attach a test location ma Convert % C114 {bv vol *Hydrogen Sulfide (If individual perntit coed+ Perniit Number: NC Landfill Rule (.0500 or.1600): Gas Meter Calibration Date: Field Calibration Gas Canister Expiration Date: Pressure (in. or rum fig): Weather Conditions: yell", list monitoring well # or describe monitoring location (e.g„ inside field office). or drawing. Report methane readings as both % LEL and % CH4 by volume. e} to % LEL as follows: % methane (by vofume)120 = % LEL. gas ►nnnitoring more be required for Construction eft Demolition Land�rllc (COLFs). See is ❑lldlor Facility LFG monitoringplan. Location or [_I`Cr Well [D S ample Tube Pure g Time of Da y Time [ '1113 See { J 111mal LLL Stabilized % [,EL I, CH4 [volume) % 02 (Volume) volume % CO2 (volume) % l [2S" {va[umel NOTES ec o'��5t° U C� n �/ 0, / D . °'3� E �, a o I 0 o C �!� •r L I£ I� . 7 21, r C) % .j � NOTE. If needed, aaaelr additional data forms to i elude additional LFG nroniron ng data locations for the facilin-. ACTION LEVELS: Methane:-_1.25% b volume (inside structures) AND >ti% by volume (at facility boundary) Hydrogen Sulfide: a % by volume (inside structures) AND >4% by volume (at facility boundary) Certification To the best of my knowledge, the are true and correct. 1 am aware or certification inelpeling the pos! rmation reported and statements made on this data submittal and attachments there are significant penalties for making any false statement, representation, ty of a fine and imprisonment. Revised — March b, 2017 INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 8411 Garvey Drive, Suite 113 Raleigh, NC 27614 Tall -free: (866) 646-PINE (7463 ) Pine Environmental Services, Inc. instrument ID 40901 Description Gem 5000+ Calibrated 12/7/2018 2:24:36PM Manufacturer CES Landtec State Certified Model Number GEM 5000 Status Pass Serial Number/ Lot G500543 Temp °C 20 Number Location North Carolina Humidity % 21 Department Calibration Specifications Group # 1 Range Acc % 0.0000 Group Nance Methane Reading Ace % 3.0000 Stated Accy Pet of Reading Plus/Minus 0.00 Nom In Val 1 In Val In Type Out Val Out Type Fnd As Lft As Dev% Pass/Fail 50,00150.00 %Volume 50.00 %Volume 47.60 50.00 0.00% Pass Group # 2 Range Ace % 0.0000 Group Name Carbon Dioxide Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/N-linus 0.00 Nom In Val 1 In Val In TYpe Out Val Out Type Fnd As Lft As Dev% Pass/Fail MAO / 35.00 %Volume 35.00 %volume 34.80 35.00 0.00% Pass Group # 3 Range Ace % 0.0000 Group Name Oxygen Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Minus 0.00 Nam In Val 1 In Val In T►'Ue Out Val Out Type Fnd As Lft As Dev% Pass/Fail 20.90120.90 %Volume 20.90 %Volume 20,70 20.90 0.00% Pass Group # 4 Range Ace % 0.0000 Group Name Carbon Monoxide Reading Ace % 3.0000 Stated Accy Pet of Readinc Plus/Minus 0.00 Nom In Val 1 In Val In TU Out Val Out TYP Fnd As Lft As Dev% Pass/Fail 1000.0011000.00 PPM 1000.00 PPM 913.00 1,000.00 0.00% Pass Group # 5 Range Ace % 0.0000 Group Name Hydrogen Sulfide Reading Ace % 3.0000 Stated Accy Pet of Reading Plus/Minus 0.00 Nom In Val 1 In Val In Type Out Val out'rype Fnd As Lft As Dev% Pass/Fail 50.00150,00 PPM 50.00 PPM 42.00 50.00 0.00% Pass Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663 www.pine-environmental.com INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 8411 Garvey Drive, Suite 113 Raleigh, NC 27614 Toll -free: (866) 646-PINE (7463) Pine Environmental Services, Inc. instrument ID 40901 Description Gem 5000+ Calibrated 12!7/2018 2:24:36PM Test Instruments Used During the Calibration (As Of Cal Entr►• Date) Serial number 1 Next Cal Date 1 Test Standard 1D Description Manufacturer Model Number Lot Number Last Cal Date/ Expiration Date Opened Date NC 50135 NC 50 CH4135 CO2 Gasc❑ GP 12126 - 31903 MAP-399-5 1/20/2020 MAP-399-5 1 /20 NC CO CARBON Pine BBH408BST- 1000/1-12S50 MONOXIDE/HYDRO 1 GEN SULFIDE ;dotes about this calibration Calibration Result Calibration Successful Who Calibrated Ryan Williamson All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the manufacturer's specifications and/or the customer's own specific needs. Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment Please call 804-301-9663 for Technical Assistance Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, N! 08561, 800-301-9663 www.pine-envirunrncnial.com