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HomeMy WebLinkAbout2803_DareCoCDLF_GWMR_20171218Dare County C&D Landfill Facility Permit Number 2803-CDLF-1995 Semi-Annual Sampling Report (September 2017 Sampling Event) Report Prepared December 2017 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 December 18, 2017 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: September 2017 Semi-Annual Groundwater Sampling Report Dare County C&D Landfill Dare County, North Carolina Facility Permit Number 2803-CDLF-1995 Dear Ms. Drummond: CDM Smith Inc., on behalf of Dare County, is submitting an electronic copy of the September 2017 semi-annual groundwater sampling event report. This letter report presents the results of the most recent semi-annual sampling event that was completed at the Dare County C&D Landfill and constitutes the second semi-annual sampling event for 2017. The approved groundwater monitoring network consists of 13 wells (i.e. MW-1 (background well), -2, -3, -8, -9, -10, -11, -12, -13, -14, -15, -16, and -17) and three surface water sampling locations (i.e. SW-1, -2, and -3). No samples were collected from monitoring well MW-8 due to damage observed by the sampling team during the September 2017 sampling event. The damaged well will be evaluated and repaired or replaced prior to the spring 2018 semi-annual sampling event. Monitoring well MW-9 was abandoned and reinstalled prior to the September 2017 sampling event due to a damaged protective cover and polyvinyl chloride (PVC) riser. Field activities, sampling and landfill gas monitoring results, and abandonment and reinstallation activities for MW-9 are discussed below. Field Activities Groundwater and surface water samples from the Dare County C&D Landfill were collected on September 21-22, 2017, by Environment One, Inc. (Environment One). Monitoring wells and surface water sample locations are shown on Figure 1. Well construction details for the monitoring wells are provided in Table 1. Groundwater elevations were measured at each well prior to sampling using an electronic water level indicator with an accuracy of 0.01 feet. These groundwater elevations as presented in Table 2 were Ms. Jaclynne Drummond December 18, 2017 Page 2 used to construct a potentiometric surface map for this sampling event. The potentiometric contours are presented on Figure 1. Each monitoring well was measured for pH, conductivity, temperature, turbidity, dissolved oxygen, and oxidation-reduction potential (ORP) prior to sampling. The same water quality parameters were measured at the surface water sample locations with the exception of ORP. The water quality parameters at the time samples were collected are presented in Table 2. Due to damage, no samples were collected from monitoring well MW-8. The well will be evaluated for repair or replacement prior to the Spring 2018 sampling event. Sampling Results Environment One located in Greenville, North Carolina, analyzed the groundwater and surface water samples for North Carolina Appendix I volatile organic compounds by U.S. Environmental Protection Agency (EPA) Method 8260B, metals by EPA Methods 200.7, 200.8, and Standard Method (SM) 3111B, mercury by EPA Method 245.1, alkalinity by SM 2320B, chloride and sulfate by SM 4500, and total dissolved solids (TDS) by SM 2540C. In accordance with Solid Waste Section guidelines, the analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below Solid Waste Section Limits (SWSLs). All monitoring wells and surface water sample locations for the C&D Landfill had detections of analytes above the MDL but below SWSLs. These detections were qualified with “J” flags, which indicate an estimated concentration. The following list presents the analytes detected above the MDL at each sample location. No “J” flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Quality Standard, Groundwater Protection Standard, or the 15A NCAC 02B or Protective Value Surface Water Quality Standard for Class C Waters. A complete summary of all detected and estimated concentrations for the September 2017 sampling event and previous events is presented in Table 3. Analytical results for TDS are provided in Table 2. The laboratory analytical report is provided in Appendix A. MW-1 General Chemistry: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-2 General Chemistry: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected Ms. Jaclynne Drummond December 18, 2017 Page 3 MW-3 General Chemistry: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-8 General Chemistry: Not Sampled Metals: Not Sampled Volatile Organic Compounds: Not Sampled MW-9 General Chemistry: Alkalinity, Chloride Metals: Iron Volatile Organic Compounds: None Detected MW-10 General Chemistry: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese Volatile Organic Compounds: None Detected MW-11 General Chemistry: Alkalinity, Chloride, Sulfate Metals: Chromium, Iron, Manganese Volatile Organic Compounds: None Detected MW-12 General Chemistry: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-13 General Chemistry: Alkalinity, Chloride Metals: Iron, Manganese Volatile Organic Compounds: None Detected MW-14 General Chemistry: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese Ms. Jaclynne Drummond December 18, 2017 Page 4 Volatile Organic Compounds: None Detected MW-15 General Chemistry: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese, Zinc Volatile Organic Compounds: None Detected MW-16 General Chemistry: Alkalinity, Chloride Metals: Barium, Iron, Manganese, Selenium Volatile Organic Compounds: None Detected MW-17 General Chemistry: Alkalinity, Chloride Metals: Arsenic, Iron, Manganese, Zinc Volatile Organic Compounds: Toluene SW-1 General Chemistry: Alkalinity, Chloride Metals: Iron, Lead, Manganese Volatile Organic Compounds: None Detected SW-2 General Chemistry: Alkalinity, Chloride Metals: Iron, Lead, Manganese Volatile Organic Compounds: None Detected SW-3 General Chemistry: Alkalinity, Chloride Metals: Iron, Lead, Manganese Volatile Organic Compounds: None Detected “J” flags were not included in the previous list, but several locations had “J” flag detections that exceeded the standards. The “J” flag constituents above the standards along with their locations are listed below. Cobalt: MW-12 and -17 Vanadium: MW-1, -2, -3, -9, -10, -11, -12, -13, -14, -15, -16, and -17 Ms. Jaclynne Drummond December 18, 2017 Page 5 Equipment and trip blanks were analyzed for quality control. A duplicate sample was also collected for quality control. No analytes were detected in the trip blank above the MDL. The equipment blank had estimated detections of antimony, chromium, iron, and lead below their respective NC 2L or Groundwater Protection Standards. The duplicate sample was collected from MW-3 and had similar analyte concentrations as those detected in MW-3, with the exceptions of estimated detections of antimony and zinc, and a detection of tetrahydrofuran in the duplicate sample. As part of the planned Alternate Source Demonstration for the landfill, filtered metals samples were collected from all monitoring wells during the September 2017 sampling event to demonstrate that select metals exceeding the NC 2L or Groundwater Protection Standards are naturally occurring and not related to a release from the landfill. Total metals that exceeded the NC 2L or Groundwater Protection Standards or have a history of exceedances were analyzed for dissolved metals to determine if turbidity was a contributing factor to total reported metals. Below is a summary of the dissolved metal exceedances. Wells with a “*” qualifier were reported as “J” flag detections for that analyte. Arsenic: MW-17 Chromium: MW-11 Cobalt: MW-17* Iron: MW-1, -2, -3, -9, -10, -12, -13, -14, -15, -16, and -17 Manganese: MW-1, -2, -3, -10, -11, -12, -13, -14, -15, -16, and -17 Vanadium: MW-9*, -10*, -12*, -14*, -15*, -16*, and -17* Dissolved metal sample results are provided in Table 3. Based on qualitative and quantitative evaluation of current and historic groundwater sampling data, the NC 2L or Groundwater Protection Standard metal exceedances from the September 2017 sampling event were determined to be indicative of naturally occurring background concentrations as opposed to a release from the landfill. The semi-annual groundwater monitoring program will be continued by Dare County. The first semi- annual sampling event for 2018 is tentatively scheduled for February. Landfill Gas Monitoring The approved landfill gas monitoring network consists of landfill gas probes M-1 through -12. Landfill gas probe locations are shown on Figure 1. Site structures that are monitored on the property include the scale house and the maintenance shop. Quarterly landfill gas monitoring of the C&D Landfill was completed on August 18 and October 20, 2017, using a GEM 2000 Plus landfill gas analyzer. No measurements were collected from M-4 during either event due to a damaged stopcock valve. A new valve will be installed prior to the first quarterly monitoring event in 2018. Ms. Jaclynne Drummond December 18, 2017 Page 6 Methane was detected above the 5% lower explosive limit in M-12 during both monitoring events. This landfill gas well is located next to a swampy area and is near the maintenance shop. No methane was detected in the maintenance shop or any of the site structures. A cut-off trench was installed near M-12 in 2015 to evaluate the source of methane in the well and for remediation purposes. The methane detections in M-12 are likely related to the swampy area adjacent to the well as opposed to a release from the landfill. Future detections will be evaluated. No hydrogen sulfide was detected in any monitoring wells or site structures. Copies of the quarterly landfill gas monitoring results along with the GEM 2000 Plus calibration information have been placed in the landfill operating record and are provided in Appendix B. Well Abandonment and Reinstallation On August 9, 2017, monitoring well MW-9 was abandoned due to a damaged protective cover and PVC riser. MW-9 was abandoned by over drilling to remove the existing well material. Once the material was removed, the borehole was backfilled with a Portland cement and bentonite mixture. A copy of the Well Abandonment Record is provided in Appendix C. Once abandonment was complete, a new well was installed approximately 5 feet from the original location. MW-9 was installed using hollow-stem auger drilling techniques to 15 feet below ground surface. The well was constructed with five feet of 2-inch diameter PVC riser flush-threaded to ten feet of 2-inch diameter 0.01-inch mill slotted PVC pre-packed screen. The borehole annulus was backfilled with an additional sand filter to 1-foot above the screen. A bentonite annular seal was installed two feet above the sand filter. The remainder of the borehole annulus was completed with a Portland cement and bentonite mixture to land surface. The well was completed with an above-grade 4-inch steel protective cover and 3-foot by 3-foot concrete pad. Four protective bollards were installed around the perimeter of the well to prevent future damage. The Well Construction Record and the boring log are provided in Appendix C. Well construction details are provided in Table 1. Ms. Jaclynne Drummond December 18, 2017 Page 7 If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3569. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. Attachments cc: Edward Mann, Dare County Table 1 Monitoring Well Construction Summary Dare County C&D Landfill Permit Number 2803-CDLF-1995 2803-CDLF-1995 MW-1 11/28/1994 HSA 775459.46 2943423.17 Surficial 3.13 1.58 10.0 10.0-20.0 8.0 7.0 2.0 2803-CDLF-1995 MW-2 11/29/1994 HSA 774812.63 2943476.21 Surficial 3.17 1.4 20.0 10.0-20.0 8.0 7.0 2.0 2803-CDLF-1995 MW-3 11/29/1994 HSA 774246.50 2943544.29 Surficial 4.18 1.82 20.0 10.0-20.0 8.0 7.0 2.0 2803-CDLF-1995 MW-8 11/28/1994 HSA 775276.96 2942765.21 Surficial 4.55 2.90 20.0 10.0-20.0 8.0 7.0 2.0 2803-CDLF-1995 MW-9 8/9/2017 HSA ----Surficial 4.85 --15.0 5.0-15.0 4.0 2.0 2.0 2803-CDLF-1995 MW-10 8/13/2002 HSA 772873.78 2943188.48 Surficial 6.02 2.70 20.0 2.0-20.0 2.0 1.0 2.0 2803-CDLF-1995 MW-11 8/12/2002 HSA 773027.15 2943464.85 Surficial 6.41 2.74 20.0 2.0-20.0 2.0 1.0 2.0 2803-CDLF-1995 MW-12 8/13/2002 HSA 773495.49 2943656.65 Surficial 2.8 0.33 20.0 3.0-20.0 1.5 1.0 2.0 2803-CDLF-1995 MW-13 1/24/2006 Mud Rotary 774019.56 2942163.28 Surficial 3.09 0.7 20.0 5.0-20.0 3.0 1.0 2.0 2803-CDLF-1995 MW-14 1/24/2006 Mud Rotary 773577.80 2942224.90 Surficial 3.06 0.52 20.0 5.0-20.0 3.0 1.0 2.0 2803-CDLF-1995 MW-15 1/24/2006 Mud Rotary 772922.37 2942289.76 Surficial 3.24 0.85 20.0 5.0-20.0 3.0 1.0 2.0 2803-CDLF-1995 MW-16 9/1/2010 HSA 775129.98 2942464.11 Surficial 5.56 3.5 20.0 5.0-20.0 3.0 1.0 2.0 2803-CDLF-1995 MW-17 9/1/2010 HSA 772722.10 2942873.18 Surficial 2.85 0.8 20.0 5.0-20.0 3.0 1.0 2.0 Notes: 1. HSA - Hollow-Stem Auger 2. bgs - Below Ground Surface 3. msl - Mean Sea Level 4. Horizontal Control - North American Datum 1983 State Plane Feet North Carolina 5. (--) - Not Measured Top of Seal (feet bgs) Casing Diameter (inches) Top of Casing Elevation (feet msl) Ground Surface Elevation (feet msl) Borehole Depth (feet bgs) Screen Interval (feet bgs) Top of Filter Pack (feet bgs) Facility Permit Number Monitoring Well Code Aquifer Monitoring Interval Drilling Method Completion Date Northing Easting Page 1 of 1 November 2017 Table 2 Water Quality Measurements and Total Dissolved Solids September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 pH (S.U.) Conductivity (µS/cm) Temperature (degrees Celsius) Turbidity (NTUs) Dissolved Oxygen (mg/L) Oxidation-Reduction Potential (mVs) TDS (mg/L) TOC Elevation (feet AMSL) Depth to Groundwater (feet) Groundwater Elevation (feet AMSL) 2803-CDLF-1995 MW-1 6.5 1,827 22 43 2.73 -75 2,540 1.61 1.98 -0.37 2803-CDLF-1995 MW-2 6.8 571 22 9 0.31 -53 600 1.55 2.71 -1.16 2803-CDLF-1995 MW-3 6.8 569 22 3 2.41 -125 990 1.74 4.05 -2.31 2803-CDLF-1995 MW-8 2.90 2803-CDLF-1995 MW-9 5.1 137 24 17 2.14 110 129 4.85 6.20 -1.35 2803-CDLF-1995 MW-10 6.2 518 23 11 2.20 -15 655 2.87 5.42 -2.55 2803-CDLF-1995 MW-11 6.7 648 25 7 5.41 -16 1,550 3.56 4.92 -1.36 2803-CDLF-1995 MW-12 5.3 156 23 11 4.79 65 170 2.80 4.01 -1.21 2803-CDLF-1995 MW-13 6.6 555 22 7 1.88 -21 807 2.96 4.10 -1.14 2803-CDLF-1995 MW-14 6.0 195 22 79 3.21 58 514 2.96 4.15 -1.19 2803-CDLF-1995 MW-15 5.9 178 22 11 0.81 24 209 3.17 4.38 -1.21 2803-CDLF-1995 MW-16 6.0 1,255 24 70 3.01 7 2,290 5.56 5.35 0.21 2803-CDLF-1995 MW-17 6.2 629 27 13 0.44 23 832 2.85 4.40 -1.55 2803-CDLF-1995 SW-1 5.6 296 26 15 1.04 --290 2803-CDLF-1995 SW-2 6.4 185 24 17 1.26 --297 2803-CDLF-1995 SW-3 6.3 317 25 32 1.79 --294 Notes: 1. mg/L - milligrams per liter 2. µS/cm - Microsiemens per centimeter 3. TDS - Total Dissolved Solids 4. AMSL - Above Mean Sea Level 5. TOC - Top of Casing 6. S.U. - Standard Unit 7. mVs - Millivolts 8. NTUs - Nephelometric Turbidity Units 9. (--) - Not Measured 10. (10) - MW-8 was damaged during the September 2017 sampling event and was not sampled. Water Quality Parameters Groundwater Elevations Monitoring Well Code Facility Permit Number --(10)--(10) Page 1 of 1 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 2803-CDLF-1995 MW-1 22-Aug-11 2.7J 48.1J 0.10J 1.6J 0.57J 2.5J 46,050 0.60J 552 2.5J 7.3J 3J 3.9J 239 1,070 58.8J 2803-CDLF-1995 MW-1 16-Feb-12 2.2J 42.2J 0.09J 1.6J 0.39J 1.9J 49,400 0.47J 578 2J 6.7J 2.3J 1.8J 296 1,000 45.2J 2803-CDLF-1995 MW-1 14-Aug-12 1.5J 42.9J 0.13J 0.85J 0.20J 1.9J 46,550 473 2J 5.5J 1J 15 273 906 64.5J 2803-CDLF-1995 MW-1 28-Feb-13 0.15J 3.3J 76.9J 0.71J 3.4J 0.81J 3J 99,700 1.5J 526 3.2J 7.5J 6J 6.6J 254 975 61.5J 2803-CDLF-1995 MW-1 30-Sep-13 0.11J 2.4J 34.1J 0.06J 0.16J 1.7J 20,540 0.03J 341 0.04J 2.2J 7.1J 3J 2J 276 950 27.3J 2803-CDLF-1995 MW-1 17-Feb-14 0.04J 3.9J 18.8J 0.43J 0.25J 2.6J 8,850 0.12J 247 6.3J 15 0.03J 0.26J 1.6J 199 860 39.1J 2803-CDLF-1995 MW-1 26-Aug-14 2.3J 42.8J 0.06J 1.2J 0.18J 2.0J 28,125 528 2.2J 11 0.69J 1.6J 250 324 38.9J 2803-CDLF-1995 MW-1 27-Feb-15 3.0J 28.6J 0.04J 0.43J 0.16J 2.5J 12,870 0.18J 109 2.4J 9.2J 1.0J 2.8J 186 968 37.7J 2803-CDLF-1995 MW-1 26-Oct-15 0.08J 4.2J 35.3J 0.06J 0.26J 0.27J 2.4J 7,760 0.18J 68 4.2J 19 0.01J 0.03J 0.50J 2.2J 174 1,060 34.4J 2803-CDLF-1995 MW-1 29-Feb-16 0.14J 3.3J 33.7J 0.10J 0.19J 2.7J 15,571 0.09J 117 3.8J 0.36J 174 1,220 37.1J 2803-CDLF-1995 MW-1 16-Aug-16 4.5J 60.0J 0.11J 0.61J 0.22J 2.9J 53,486 685 3.8J 0.92J 1.1J 1.20 273 1,290 58.4J 2803-CDLF-1995 MW-1 22-Feb-17 3.1J 34.5J 0.10J 0.22J 6.3J 16,000 0.26J 173 3.4J 0.48J 14 149 1,220 29.3J 2803-CDLF-1995 MW-1 21-Sep-17 1.9J 59.4J 0.80J 2.4J 51,724 726 2.4J 0.87J 1.1J 210 1,310 58.3J 2803-CDLF-1995 MW-1 (dissolved)21-Sep-17 NA NA NA NA NA NA NA NA 20,590 NA 727 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-2 22-Aug-11 0.21J 7.8J 0.14J 0.72J 16,160 0.06J 282 1.2J 0.26J 1.4J 2J 388 39 2803-CDLF-1995 MW-2 16-Feb-12 0.32J 12.9J 0.06J 0.94J 0.18J 1.5J 45,400 0.43J 344 0.88J 0.26J 1.9J 2.8J 393 37 2803-CDLF-1995 MW-2 14-Aug-12 8.7J 0.05J 0.12J 1.0J 23,480 262 1.2J 0.39J 11 378 38 10.9J 2803-CDLF-1995 MW-2 28-Feb-13 0.31J 0.59J 45.8J 0.20J 0.14J 1.4J 0.15J 10 204,100 3.1J 399 1.5J 0.51J 3.9J 46 353 46 12.6J 2803-CDLF-1995 MW-2 30-Sep-13 0.05J 0.22J 8.3J 0.03J 0.13J 0.40J 21,150 0.03J 219 0.04J 1.4J 0.53J 3.3J 1.8J 404 43 16.4J 2803-CDLF-1995 MW-2 17-Feb-14 0.10J 8.7J 0.14J 0.18J 0.77J 14,900 0.08J 354 4.4J 1.3J 0.04J 0.50J 2.0J 379 46 10.4J 2803-CDLF-1995 MW-2 26-Aug-14 8.0J 0.42J 0.14J 0.44J 12,875 311 1.2J 0.68J 1.3J 368 45 10.4J 2803-CDLF-1995 MW-2 27-Feb-15 0.56J 0.24J 10.1J 0.97J 13,130 0.22J 324 1.3J 0.63J 0.86J 6.6J 333 57 2803-CDLF-1995 MW-2 26-Oct-15 0.06J 8.0J 0.03J 0.05J 0.17J 1.7J 11,349 0.30J 199 2.0J 1.1J 0.01J 0.65J 3.3J 312 48 2803-CDLF-1995 MW-2 29-Feb-16 12.3J 0.05J 0.13J 0.63J 26,522 0.07J 364 1.8J 0.97J 0.71J 2.2J 312 60 2803-CDLF-1995 MW-2 16-Aug-16 8.0J 0.13J 0.32J 18,052 363 1.8J 1.0J 0.96J 322 58 2803-CDLF-1995 MW-2 22-Feb-17 12.5J 0.06J 0.14J 0.51J 25,325 0.11J 381 1.4J 1.0J 0.52J 2.4J 235 65 10.8J 2803-CDLF-1995 MW-2 21-Sep-17 8.5J 0.20J 0.18J 18,337 391 0.90J 0.64J 0.67J 378 61 2803-CDLF-1995 MW-2 (dissolved)21-Sep-17 NA NA NA NA NA NA NA NA 1,272 NA 373 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number Page 1 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-3 22-Aug-11 0.18J 13.0J 0.11J 0.04J 0.18J 0.72J 25,400 0.08J 355 1.2J 1.1J 3.6J 391 35 12.1J 2803-CDLF-1995 MW-3 16-Feb-12 10.7J 0.11J 0.04J 0.22J 0.15J 0.28J 25,275 0.07J 398 0.77J 0.71J 408 34 2803-CDLF-1995 MW-3 14-Aug-12 13.8J 0.10J 0.04J 0.28J 0.16J 0.64J 25,325 244 1.6J 0.13J 6.9J 416 38 18.2J 2803-CDLF-1995 MW-3 28-Feb-13 0.04J 0.48J 31.1J 0.32J 0.09J 1.0J 0.20J 0.24J 81,850 0.12J 553 1.9J 0.67J 1.5J 2.1J 473 56 108J 2803-CDLF-1995 MW-3 30-Sep-13 0.04J 0.49J 15.4J 0.11J 0.15J 0.40J 30,090 373 0.04J 1.7J 0.63J 3.1J 1.6J 478 50 56.4J 2803-CDLF-1995 MW-3 17-Feb-14 0.44J 20.5J 0.18J 1.2J 0.25J 0.48J 53,875 0.04J 614 6.3J 2.0J 0.76J 1.9J 448 58 100J 2803-CDLF-1995 MW-3 26-Aug-14 0.27J 18.4J 0.11J 1.2J 0.17J 0.23J 20,700 523 1.5J 1.0J 0.38J 0.85J 443 29 77.0J 2803-CDLF-1995 MW-3 27-Feb-15 0.18J 0.72J 42.8J 0.26J 0.04J 0.90J 0.18J 0.38J 49,125 625 1.8J 1.4J 1.1J 1.9J 379 75 124J 2803-CDLF-1995 MW-3 26-Oct-15 0.06J 0.38J 19.1J 0.12J 0.06J 0.91J 0.25J 0.61J 12,629 0.17J 381 3.0J 2.2J 0.01J 0.59J 2.3J 400 67 98.5J 2803-CDLF-1995 MW-3 29-Feb-16 44.8J 0.39J 0.33J 0.17J 0.52J 85,550 0.06J 552 2.0J 0.90J 0.92J 344 55 32.1J 2803-CDLF-1995 MW-3 16-Aug-16 0.77J 24.7J 0.75J 0.07J 0.86J 0.19J 0.58J 32,375 629 2.6J 2.0J 0.06J 0.90J 389 72 69.0J 2803-CDLF-1995 MW-3 22-Feb-17 23.2J 0.13J 1.5J 0.35J 0.44J 17,647 719 2.7J 2.2J 0.39J 414 99 148J 2803-CDLF-1995 MW-3 21-Sep-17 0.35J 32.4J 0.13J 1.9J 0.19J 52,566 894 1.3J 2.3J 0.65J 464 80 14.5J 2803-CDLF-1995 MW-3 (dissolved)21-Sep-17 NA NA NA NA NA NA NA NA 18,055 NA 860 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-8 22-Aug-11 4.2J 253 0.74J 4.5J 0.12J 7.7J 31,125 0.11J 101 1.3J 0.05J 8.4J 3.1J 128 2,724 213J 2803-CDLF-1995 MW-8 16-Feb-12 3.3J 237 0.5J 3.6J 0.24J 6.0J 24,150 0.16J 166 1.8J 14 5.4J 2.7J 179 2,699 166J 2803-CDLF-1995 MW-8 14-Aug-12 0.04J 4.1J 192 0.96J 5.4J 0.15J 5.1J 35,150 0.17J 95 1.6J 16 11.1J 5.2J 157 2,693 191J 2803-CDLF-1995 MW-8 28-Feb-13 9J 197 0.47J 3.6J 0.28J 8.0J 20,950 130 1.8J 6.3J 2.4J 177 3,049 191J 2803-CDLF-1995 MW-8 30-Sep-13 0.05J 5.2J 215 0.32J 2.8J 0.15J 4.9J 41,480 0.04J 72 0.04J 1.6J 19 4.1J 3.6J 173 2,724 171J 2803-CDLF-1995 MW-8 17-Feb-14 0.12J 213 0.24J 2.2J 0.18J 10 7,525 0.31J 179 3.8J 2.2J 7.6J 129 2,700 187J 2803-CDLF-1995 MW-8 26-Aug-14 5.2J 239 0.27J 3.5J 0.14J 11 34,150 192 2.1J 25 1.7J 6.6J 144 2,360 140J 2803-CDLF-1995 MW-8 27-Feb-15 7J 321 0.52J 2.7J 0.15J 8.8J 20,475 0.43J 206 1.9J 7.0J 10 74 2,620 180J 2803-CDLF-1995 MW-8 26-Oct-15 0.12J 8J 23.1J 0.23J 2.1J 0.20J 8.0J 35,883 0.27J 236 2.6J 0.03J 0.05J 1.8J 7.8J 73 53 119J 2803-CDLF-1995 MW-8 29-Feb-16 263 0.35J 2.4J 0.17J 8.6J 23,145 0.39J 261 0.06J 2.2J 2.5J 11 129 2,800 133J 2803-CDLF-1995 MW-8 16-Aug-16 9J 198 0.30J 3.7J 0.18J 8.8J 41,315 0.10J 257 2.2J 3.3J 3.9J 131 2,560 112J 2803-CDLF-1995 MW-8 22-Feb-17 0.07J 7.1J 228 0.83J 0.24J 4.9J 0.23J 11 43,300 1.4J 245 2.6J 0.10J 10.4J 25 123 2,550 80.5J 2803-CDLF-1995 MW-8 21-Sep-17 --(7) Page 2 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-9 22-Aug-11 21 35.8J 0.18J 0.16J 6.1J 5.6J 2.8J 194,750 2.6J 162 7.1J 1.0J 0.12J 9.4J 47 38 12 194J 2803-CDLF-1995 MW-9 16-Feb-12 0.21J 249 47.4J 0.45J 0.18J 14 3.2J 5.1J 68,075 8.1J 69 3.6J 1.5J 0.07J 0.08J 31 21 11 16 120J 2803-CDLF-1995 MW-9 14-Aug-12 0.12J 36 25.3J 0.26J 0.20J 6.4J 3.6J 3.3J 9,725 3.5J 37J 0.02J 4.1J 0.72J 0.21J 11.5J 22 21 16 74.6J 2803-CDLF-1995 MW-9 28-Feb-13 22 27.3J 0.18J 0.08J 7.6J 1.9J 3.3J 14,470 5.2J 27J 3.3J 0.91J 0.10J 13.9J 10 76 7 35.8J 2803-CDLF-1995 MW-9 30-Sep-13 0.12J 28 21.8J 0.18J 0.17J 4.2J 1.9J 2.9J 24,650 2.2J 27J 0.03J 3.5J 1.4J 0.07J 11.9J 11 57 12 62.1J 2803-CDLF-1995 MW-9 17-Feb-14 0.04J 10 23.3J 0.17J 0.13J 6.2J 1.8J 2.6J 6,115 3.4J 36J 3.3J 1.7J 0.05J 9.1J 7.0J 31 7 37.6J 2803-CDLF-1995 MW-9 26-Aug-14 0.21J 63 15.2J 0.14J 0.12J 6.1J 2.1J 5.1J 13,115 3.3J 32J 3.2J 2.7J 19.7J 14 14.00J 71 11 32.4J 2803-CDLF-1995 MW-9 27-Feb-15 12 28.3J 0.18J 0.15J 7.1J 1.9J 3.2J 7,225 4.4J 33J 3.0J 1.2J 12.1J 11 11 5 124J 2803-CDLF-1995 MW-9 26-Oct-15 0.15J 20 15.9J 0.10J 0.18J 5.9J 1.1J 2.7J 5,819 2.6J 18J 2.5J 1.1J 0.03J 0.08J 13.1J 5.8J 72 22.4J 2803-CDLF-1995 MW-9 29-Feb-16 0.18J 47 18.8J 0.19J 0.24J 9.4J 2.3J 4.2J 20,859 3.7J 34J 0.08J 3.8J 1.6J 0.07J 31 14 15 13 51.8J 2803-CDLF-1995 MW-9 16-Aug-16 0.12J 31 38.1J 0.26J 0.23J 13 1.5J 4.6J 10,469 8.2J 32J 3.7J 0.88J 0.15J 21.9J 17 57 7 2803-CDLF-1995 MW-9 22-Feb-17 0.17J 122 35.3J 0.30J 0.17J 12 1.4J 4.5J 21,950 8.3J 30J 3.5J 1.6J 0.12J 32 13 43 13 33.8J 2803-CDLF-1995 MW-9 21-Sep-17 5.3J 46.1J 0.22J 0.19J 1.9J 0.71J 0.66J 4,085 0.37J 36J 1.8J 3.6J 5.7J 0.40J 15 8 42.2J 2803-CDLF-1995 MW-9 (dissolved)21-Sep-17 NA 4.0J NA NA NA 1.2J 0.53J NA 2,758 NA 30J NA NA NA NA NA 1.8J NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-10 22-Aug-11 0.26J 5.8J 63.1J 0.22J 0.11J 3.9J 0.51J 1.3J 116,250 1.0J 567 2.3J 1.1J 0.05J 7.5J 5.3J 209 34 626 2803-CDLF-1995 MW-10 16-Feb-12 10 42.5J 0.25J 0.12J 3.2J 2J 1.4J 68,475 1.3J 617 6.7J 1.1J 0.07J 8.5J 14 45 39 3,365 2803-CDLF-1995 MW-10 14-Aug-12 0.10J 11 43.5J 0.10J 0.10J 1.2J 0.79J 1.7J 8,875 1.4J 440 4.2J 0.55J 0.37J 5.7J 6.4J 250 7 584 2803-CDLF-1995 MW-10 28-Feb-13 16 20.8J 0.13J 0.05J 1.8J 0.43J 2.5J 36,300 5.7J 111 2.4J 0.52J 20.6J 2.9J 196 8 93.5J 2803-CDLF-1995 MW-10 30-Sep-13 0.05J 6.4J 42.7J 0.08J 0.07J 0.81J 0.38J 0.77J 19,340 0.15J 193 0.05J 2.9J 0.90J 7.3J 3.6J 224 10 297 2803-CDLF-1995 MW-10 17-Feb-14 3.9J 20.1J 0.06J 0.60J 0.34J 0.68J 7,275 0.09J 188 7.2J 0.78J 1.4J 0.87J 251 5 77.8J 2803-CDLF-1995 MW-10 26-Aug-14 0.85J 11 35.1J 0.09J 0.06J 2.2J 0.51J 0.61J 14,145 0.41J 226 2.4J 0.93J 8.2J 3.0J 304 7 103J 2803-CDLF-1995 MW-10 27-Feb-15 8J 11.6J 0.05J 0.76J 0.27J 0.22J 16,875 94 1.3J 0.57J 2.8J 0.61J 150 5 63.4J 2803-CDLF-1995 MW-10 26-Oct-15 1.1J 13 27.1J 0.11J 0.21J 2.2J 0.51J 1.9J 18,428 1.3J 162 0.07J 3.6J 0.82J 0.06J 0.05J 9.9J 6.5J 185 7 96.0J 2803-CDLF-1995 MW-10 29-Feb-16 0.05J 11 18.2J 0.08J 0.07J 1.7J 0.62J 1.2J 35,508 0.93J 144 3.0J 0.70J 4.4J 2.8J 126 22 151J 2803-CDLF-1995 MW-10 16-Aug-16 0.06J 12 27.3J 0.06J 0.05J 1.3J 0.42J 0.51J 43,130 0.26J 221 3.2J 0.67J 4.8J 3.2J 271 18 109J 2803-CDLF-1995 MW-10 22-Feb-17 16 16.4J 0.07J 0.09J 0.7J 0.44J 0.28J 53,044 0.14J 206 2.4J 0.73J 4.0J 2.3J 221 21 134J 2803-CDLF-1995 MW-10 21-Sep-17 11 19.8J 0.08J 1.4J 0.43J 0.55J 51,712 0.36J 273 1.6J 0.68J 3.8J 2.0J 386 14 47.7J 2803-CDLF-1995 MW-10 (dissolved)21-Sep-17 NA 1.7J NA NA NA NA NA NA 22,960 NA 263 NA NA NA NA NA 0.35J NA NA NA NA NA NA NA NA NA NA Page 3 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-11 22-Aug-11 1.7J 50.1J 0.07J 0.10J 2.1J 0.74J 1.3J 18,880 1.4J 257 1.5J 0.41J 0.08J 3.6J 5.6J 93 47 257 2803-CDLF-1995 MW-11 16-Feb-12 5.1J 72.4J 0.13J 0.16J 2.2J 2.7J 1.5J 54,125 1.6J 295 3.6J 0.35J 0.04J 4.7J 9J 48 60 376 2803-CDLF-1995 MW-11 14-Aug-12 0.06J 5.8J 35.6J 0.11J 0.16J 1.8J 1.3J 1.6J 10,965 1.2J 100 3.0J 0.43J 3.8J 7.3J 83 23 192J 2803-CDLF-1995 MW-11 28-Feb-13 2.6J 38.5J 0.11J 0.09J 1.4J 1.0J 1.1J 18,210 0.57J 96 3.0J 0.63J 3.4J 3.4J 141 33 297 2803-CDLF-1995 MW-11 30-Sep-13 0.07J 2.6J 39.9J 0.05J 0.07J 0.46J 0.45J 1.6J 8,090 0.30J 93 0.05J 2.6J 0.65J 4.8J 6.2J 123 20 259 2803-CDLF-1995 MW-11 17-Feb-14 2.3J 27.6J 0.06J 1.4J 0.64J 0.54J 18,900 0.13J 99 3.0J 0.51J 2.8J 59 12 133J 2803-CDLF-1995 MW-11 26-Aug-14 0.24J 3.9J 25.6J 0.11J 0.06J 2.7J 0.96J 1.3J 7,020 0.81J 67 2.0J 0.75J 4.9J 5.9J 98 8 55.8J 2803-CDLF-1995 MW-11 27-Feb-15 3.0J 34.4J 0.07J 0.04J 2.0J 0.42J 0.24J 12,775 75 1.6J 0.34J 3.8J 1.5J 64 12 96.7J 2803-CDLF-1995 MW-11 26-Oct-15 0.46J 7J 35.0J 0.12J 0.26J 2.8J 2.3J 3.9J 11,337 3.3J 72 3.3J 0.75J 0.03J 0.12J 5.4J 13 83 12 48.9J 2803-CDLF-1995 MW-11 29-Feb-16 0.39J 8J 30.6J 0.13J 0.09J 2.1J 1.5J 2.2J 14,571 1.5J 77 2.9J 0.57J 0.09J 5.3J 7.6J 80 20 77.3J 2803-CDLF-1995 MW-11 16-Aug-16 0.08J 4.4J 31.8J 0.10J 0.11J 2.1J 1.6J 1.7J 6,021 1.2J 80 2.9J 0.92J 5.2J 7.6J 105 8 2803-CDLF-1995 MW-11 22-Feb-17 0.58J 8.4J 96.4J 0.26J 0.16J 11 0.99J 1.4J 36,336 0.27J 312 5.4J 1.9J 4.7J 6.7J 118 31 510 2803-CDLF-1995 MW-11 21-Sep-17 0.06J 8J 80.7J 25 0.70J 0.86J 8,265 0.18J 1,186 4.7J 2.2J 1.1J 4.3J 454 48 712 2803-CDLF-1995 MW-11 (dissolved)21-Sep-17 NA NA NA NA NA 26 0.40J NA 145J NA 1,184 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-12 22-Aug-11 5.5J 59.8J 0.10J 0.07J 1.2J 0.54J 0.85J 26,700 0.74J 579 2.3J 0.34J 0.03J 3.7J 6.5J 209 51 2803-CDLF-1995 MW-12 16-Feb-12 3.3J 43.6J 0.1J 0.04J 1.4J 0.93J 0.94J 11,685 1.3J 253 2.2J 0.24J 0.08J 3.6J 4.1J 49 38 14.6J 2803-CDLF-1995 MW-12 14-Aug-12 2.9J 45.4J 0.10J 0.09J 0.97J 0.89J 1.1J 25,825 0.53J 367 3.1J 0.24J 2.0J 8.2J 100 27 19.7J 2803-CDLF-1995 MW-12 28-Feb-13 0.19J 5.5J 38.6J 0.29J 0.10J 3.4J 0.82J 2.9J 13,830 4.2J 48J 0.02J 2.8J 0.32J 11.7J 8.3J 4 10 22.7J 2803-CDLF-1995 MW-12 30-Sep-13 0.05J 1.1J 40.8J 0.11J 0.08J 0.46J 1.3J 474 0.31J 22J 0.04J 1.6J 0.40J 0.04J 3.3J 4.5J 2 25 14.3J 2803-CDLF-1995 MW-12 17-Feb-14 0.09J 54.5J 0.06J 0.08J 0.66J 0.67J 1.1J 340 0.30J 57 2.4J 0.52J 0.16J 3.1J 1.0 31 18.0J 2803-CDLF-1995 MW-12 26-Aug-14 0.14J 1.6J 42.2J 0.14J 0.07J 1.9J 1.0J 1.4J 4,210 1.5J 88 4.8J 0.52J 3.5J 8.5J 4 24 21.5J 2803-CDLF-1995 MW-12 27-Feb-15 0.85J 36.0J 0.11J 0.06J 1.2J 0.39J 1.3J 568 0.92J 39J 1.7J 0.41J 2.4J 5.7J 7 11 11.3J 2803-CDLF-1995 MW-12 26-Oct-15 0.17J 1.5J 30.9J 0.12J 0.12J 1.9J 0.81J 1.3J 4,468 1.2J 41J 3.0J 0.75J 0.03J 0.04J 3.2J 7.1J 23 2803-CDLF-1995 MW-12 29-Feb-16 0.06J 0.77J 23.1J 0.10J 1.4J 0.55J 0.86J 3,341 0.68J 37J 2.6J 0.08J 2.0J 3.5J 4 19 5.3J 2803-CDLF-1995 MW-12 16-Aug-16 0.09J 1.4J 16.6J 0.09J 0.09J 1.8J 0.41J 3.2J 3,087 1.6J 30J 2.2J 4.2J 5.4J 6 16 2803-CDLF-1995 MW-12 22-Feb-17 0.05J 1.3J 20.2J 0.07J 0.86J 0.78J 0.71J 8,300 0.77J 138 4.3J 0.75J 2.7J 3.2J 7 20 2803-CDLF-1995 MW-12 21-Sep-17 0.49J 1.2J 56.7J 0.17J 0.14J 1.4J 1.2J 1.8J 3,491 0.75J 87 4.7J 0.91J 1.9J 9.7J 4 37 2803-CDLF-1995 MW-12 (dissolved)21-Sep-17 NA NA NA NA NA NA NA NA 1,988 NA 87 NA NA NA NA NA 0.58J NA NA NA NA NA NA NA NA NA NA Page 4 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-13 18-Oct-11 2.7J 30.0J 0.10J 0.11J 2.5J 0.59J 0.78J 21,100 0.51J 2,672 1.3J 0.59J 0.03J 2.8J 4.9J 296 43 7.9J 2803-CDLF-1995 MW-13 16-Feb-12 0.25J 3.8J 31.4J 0.08J 0.08J 1.4J 0.26J 0.27J 40,875 0.31J 351 0.11J 0.93J 0.34J 0.03J 2.5J 1.6J 343 46 12.9J 2803-CDLF-1995 MW-13 14-Aug-12 3.4J 28.8J 0.08J 1.2J 0.14J 0.61J 33,860 211 0.85J 0.38J 1.6J 7.7J 253 46 20.0J 2803-CDLF-1995 MW-13 28-Feb-13 0.29J 32 122 1 0.40J 20 5.8J 6.3J 200,400 16 379 0.05J 11.7J 1.2J 0.32J 46 140 209 57 52.8J 2803-CDLF-1995 MW-13 30-Sep-13 0.24J 2.6J 40.7J 0.08J 0.91J 0.17J 0.54J 76,050 0.11J 329 0.05J 1.1J 1J 0.04J 0.06J 1.9J 1.3J 193 80 218J 2803-CDLF-1995 MW-13 17-Feb-14 1.9J 54.2J 0.03J 0.08J 1.2J 0.18J 0.67J 47,825 0.05J 353 3.1J 1.1J 0.04J 0.04J 0.57J 1.2J 159 84 163J 2803-CDLF-1995 MW-13 26-Aug-14 0.62J 22.3J 0.47J 0.16J 0.35J 17,438 357 1.4J 0.60J 0.78J 1.9J 373 57 52.9J 2803-CDLF-1995 MW-13 27-Feb-15 0.67J 3.2J 78.4J 0.14J 0.34J 1.2J 0.29J 0.78J 67,725 0.68J 426 1.7J 0.66J 0.04J 3.0J 12 13.60J 309 74 115J 2803-CDLF-1995 MW-13 27-Oct-15 0.06J 0.55J 23.6J 0.02J 0.06J 0.21J 0.38J 16,200 0.17J 378 2.5J 0.91J 0.72J 2.8J 332 67 117J 2803-CDLF-1995 MW-13 29-Feb-16 0.08J 2.5J 86.5J 0.58J 0.14J 0.67J 0.20J 0.62J 122,992 0.23J 484 2.4J 2.4J 2.1J 4.3J 286 74 126J 2803-CDLF-1995 MW-13 17-Aug-16 0.97J 28.3J 0.06J 0.08J 0.30J 0.64J 23,952 0.42J 541 3.0J 1.4J 1.5J 5.9J 320 78 181J 2803-CDLF-1995 MW-13 23-Feb-17 41.7J 0.07J 0.26J 0.43J 25,744 0.22J 524 2.6J 1.0J 0.82J 3.5J 197 87 214J 2803-CDLF-1995 MW-13 22-Sep-17 0.33J 33.0J 0.19J 23,397 525 1.7J 0.70J 1.1J 334 59 200J 2803-CDLF-1995 MW-13 (dissolved)22-Sep-17 NA NA NA NA NA NA NA NA 2,963 NA 501 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-14 18-Oct-11 33 76.8J 0.54J 0.26J 6.2J 0.40J 0.57J 74,700 0.63J 188 1.0J 0.50J 12.0J 3.5J 243 38 2803-CDLF-1995 MW-14 16-Feb-12 3.3J 29.3J 0.04J 1.9J 0.2J 0.7J 32,250 0.18J 206 0.88J 1.8J 1.9J 273 36 2803-CDLF-1995 MW-14 14-Aug-12 3.6J 42.3J 0.09J 1.4J 0.15J 0.64J 50,075 220 0.94J 0.26J 1.3J 23 226 39 96.4J 2803-CDLF-1995 MW-14 28-Feb-13 0.22J 74 218 2 0.52J 26 6.0J 7.1J 449,500 23 315 0.08J 12.4J 1.2J 0.12J 0.43J 53 129 153 53 175J 2803-CDLF-1995 MW-14 30-Sep-13 0.14J 10 66.1J 0.10J 0.05J 3.2J 0.33J 0.71J 96,150 0.53J 186 0.04J 1.1J 0.62J 0.04J 3.4J 3.7J 228 27 253 2803-CDLF-1995 MW-14 17-Feb-14 3.7J 82.7J 0.07J 0.09J 2.2J 0.18J 0.68J 93,500 0.15J 403 2.3J 0.67J 0.04J 1.9J 1.8J 167 53 194J 2803-CDLF-1995 MW-14 26-Aug-14 12 97.0J 0.17J 0.06J 3.5J 0.34J 0.81J 75,350 0.67J 259 1.2J 0.32J 3.9J 5.0J 164 39 148J 2803-CDLF-1995 MW-14 27-Feb-15 0.20J 9J 78.0J 0.12J 0.09J 3.3J 0.49J 0.85J 54,775 0.94J 311 1.6J 0.59J 3.9J 6.1J 118 45 96.1J 2803-CDLF-1995 MW-14 27-Oct-15 0.06J 15 90.4J 0.17J 0.10J 3.6J 0.56J 1.0J 80,183 1.4J 219 1.5J 0.536J 0.02J 4.4J 9.5J 60 56 165J 2803-CDLF-1995 MW-14 29-Feb-16 0.08J 16 79.4J 0.62J 0.15J 3.6J 0.65J 2.4J 90,632 1.6J 393 2.7J 2.2J 4.7J 9.5J 83 49 141J 2803-CDLF-1995 MW-14 17-Aug-16 9J 77.2J 0.05J 2.1J 0.17J 0.42J 69,564 0.19J 232 1.0J 0.62J 2.0J 2.3J 73 63 184J 2803-CDLF-1995 MW-14 23-Feb-17 12 82.2J 0.22J 0.09J 2.73J 0.39J 0.7J 89,826 0.70J 386 1.7J 0.83J 3.6J 5.7J 119 43 204J 2803-CDLF-1995 MW-14 22-Sep-17 10 50.5J 0.10J 2.7J 0.40J 43,144 0.43J 178 0.96J 3.2J 2.3J 123 63 20.8J 2803-CDLF-1995 MW-14 (dissolved)22-Sep-17 NA 2.9J NA NA NA NA NA NA 23,431 NA 169 NA NA NA NA NA 0.53J NA NA NA NA NA NA NA NA NA NA Page 5 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-15 18-Oct-11 13 43.0J 0.26J 0.23J 3.5J 1.3J 1.6J 43,025 2.1J 292 2.7J 0.28J 0.05J 4.7J 354 191 29 30.2J 2803-CDLF-1995 MW-15 16-Feb-12 5.3J 24.9J 0.07J 0.09J 0.9J 0.33J 0.3J 29,125 0.38J 226 0.62J 1.2J 78 143 30 23.4J 2803-CDLF-1995 MW-15 14-Aug-12 11 28.3J 0.11J 0.13J 0.27J 0.12J 0.80J 32,000 0.12J 99 0.86J 0.07J 0.22J 72 92 28 28.3J 2803-CDLF-1995 MW-15 28-Feb-13 0.16J 65 223 2 0.58J 28 6.8J 8.0J 281,600 30 354 0.08J 14.2J 1.5J 0.13J 0.39J 63 59 177 47 179J 2803-CDLF-1995 MW-15 30-Sep-13 0.08J 13 50.1J 0.13J 0.52J 0.27J 0.57J 38,000 0.11J 110 0.03J 0.92J 0.35J 0.03J 1.1J 98 78 37 26.6J 2803-CDLF-1995 MW-15 17-Feb-14 6.0J 23.6J 0.07J 0.06J 1.1J 0.09J 0.54J 31,375 0.05J 160 0.72J 0.58J 24 69 28 25.4J 2803-CDLF-1995 MW-15 26-Aug-14 0.13J 11 38.0J 0.17J 1.5J 0.33J 0.49J 26,375 0.49J 116 1.1 1.5J 1.3J 35 64 26 25.1J 2803-CDLF-1995 MW-15 27-Feb-15 15 39.5J 0.18J 0.05J 1.1J 0.18J 0.34J 43,625 0.34J 162 0.59J 0.18J 1.7J 36 77 28 39.8J 2803-CDLF-1995 MW-15 27-Oct-15 0.02J 5.8J 37.2J 0.10J 0.02J 0.09J 0.21J 19,103 125 0.37J 0.34J 35 137 27 16.0J 2803-CDLF-1995 MW-15 29-Feb-16 16 44.3J 0.50J 0.08J 0.96J 0.17J 0.40J 50,674 0.24J 175 0.82J 1.1J 0.66J 40 52 29 30.6J 2803-CDLF-1995 MW-15 17-Aug-16 12 37.3J 0.20J 0.95J 0.12J 0.29J 33,901 0.18J 157 0.42J 0.84J 24 24 30 29.0J 2803-CDLF-1995 MW-15 23-Feb-17 13 35.9J 0.18J 0.66J 0.28J 0.25J 42,280 0.98J 192 0.89J 3.1J 47 77 28 22.4J 2803-CDLF-1995 MW-15 22-Sep-17 12 33.6J 0.09J 0.15J 31,645 0.10J 131 0.40J 0.56J 19 0.30J 78 24 23.9J 2803-CDLF-1995 MW-15 (dissolved)22-Sep-17 NA 5.1J NA NA NA NA NA NA 20,470 NA 127 NA NA NA NA NA 0.34J NA NA NA NA NA NA NA NA NA NA 2803-CDLF-1995 MW-16 18-Oct-11 0.15J 3.7J 278 0.48J 3.9J 0.38J 7.6J 29,425 0.22J 89 2.1J 5.5J 3.7J 154 3,099 207J 2803-CDLF-1995 MW-16 16-Feb-12 6.6J 283 0.36J 3.2J 0.17J 6.1J 24,175 0.06J 108 1.8J 21 4.7J 1J 163 2,824 255 2803-CDLF-1995 MW-16 14-Aug-12 0.12J 8J 472 0.38J 3.1J 0.26J 8.2J 27,313 0.16J 81 2.2J 30 0.07J 4.2J 6.2J 133 3,539 177J 2803-CDLF-1995 MW-16 28-Feb-13 0.16J 12 308 0.26J 2.9J 0.37J 9.2J 46,050 307 3.6J 31 3.6J 2.7J 304 2,799 178J 2803-CDLF-1995 MW-16 30-Sep-13 0.10J 6.2J 366 0.44J 3.4J 0.21J 7.7J 45,800 0.09J 145 0.03J 1.8J 24 0.03J 4.6J 3.6J 154 3,374 267 2803-CDLF-1995 MW-16 17-Feb-14 0.02J 10 200 0.35J 3.3J 0.32J 5.8J 23,675 0.02J 271 5.6J 34 4.7J 0.74J 402 1,120 350 2803-CDLF-1995 MW-16 26-Aug-14 3.5J 347 0.22J 3.8J 0.18J 3.8J 71,075 240 2.0J 16 4.2J 1.2J 143 855 128J 2803-CDLF-1995 MW-16 27-Feb-15 0.17J 3.1J 219 0.17J 2.5J 0.44J 2.8J 23,900 396 3.7J 8.3J 3.9J 2.9J 529 792 196J 2803-CDLF-1995 MW-16 27-Oct-15 0.10J 4.3J 244 0.22J 3.0J 0.32J 2.8J 58,325 0.16J 283 0.06J 3.5J 0.03J 3.6J 4.2J 75 1,380 96.5J 2803-CDLF-1995 MW-16 29-Feb-16 0.08J 4.9J 284 0.62J 2.1J 0.24J 4.9J 57,917 265 2.6J 2.8J 2.1J 163 1,360 84.2J 2803-CDLF-1995 MW-16 17-Aug-16 0.07J 8J 282 0.34J 5.7J 1.3J 4.8J 70,642 1.5J 263 3.6J 6.6J 8.9J 0.80J 69 1,630 118J 2803-CDLF-1995 MW-16 23-Feb-17 0.06J 4.1J 213 0.28J 1.8J 0.18J 2.8J 42,040 291 2.3J 15 4.9J 2.3J 292 1,070 8.4J 2803-CDLF-1995 MW-16 22-Sep-17 4.7J 170 0.54J 4.2J 0.57J 2.8J 34,924 0.79J 184 2.1J 16 5.9J 4.4J 100 66 89.3J 2803-CDLF-1995 MW-16 (dissolved)22-Sep-17 NA 3.9J NA NA NA NA NA NA 21,073 NA 170 NA NA NA NA 1.4J NA NA NA NA NA NA NA NA NA NA Page 6 of 9 November 2017 Table 3a Detected Groundwater Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 AntimonyArsenicBariumBerylliumCadmiumChromiumCobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneCarbon DisulfideEthylbenzeneTrichlorofuloromethaneTetrahydrofuranTolueneAlkalinity Chloride Sulfate 1*10 700 4*2 10 1*1,000 300 15 50 1 100 20 20 0.2*0.3*1,000 6,000 700 600 2,000 NE 600 NS 250 250 6 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 100 1 1 NE 1 NE NE 250 Volatile Organic Compounds North Carolina 2L or Groundwater Protection Standard Solid Waste Section Limit Metals General Chemistry Sample Date Monitoring Well Code Facility Permit Number 2803-CDLF-1995 MW-17 18-Oct-11 30 63.5J 1 0.33J 2.9J 3.7J 1.4J 47,875 1.8J 194 7.9J 0.91J 0.03J 8.3J 957 19 287 2803-CDLF-1995 MW-17 16-Feb-12 4.1J 36.8J 0.9J 0.21J 1.8J 3.1J 1.1J 7,748 1.4J 98 6.3J 0.51J 2.1J 382 22 372 2803-CDLF-1995 MW-17 14-Aug-12 11 43.5J 0.80J 0.19J 2.5J 2.9J 1.1J 30,800 1.5J 89 7.8J 0.69J 6.1J 201 4 23 225J 2803-CDLF-1995 MW-17 28-Feb-13 0.04J 1.3J 31.1J 0.36J 0.10J 1.1J 3.8J 1.6J 8,480 1.1J 53 5.9J 0.60J 0.08J 1.9J 103 1 15 140J 2803-CDLF-1995 MW-17 30-Sep-13 0.09J 6J 17.3J 0.11J 0.05J 1.6J 0.31J 1.2J 28,450 0.31J 93 0.05J 2.3J 1.3J 0.03J 3.6J 33 61 17 121J 2803-CDLF-1995 MW-17 17-Feb-14 0.54J 29.0J 0.18J 0.15J 1.5J 1.3J 2.3J 738 0.52J 43J 3.3J 0.73J 1.2J 88 13 114J 2803-CDLF-1995 MW-17 26-Aug-14 5.8J 42.6J 0.14J 0.04J 2.2J 1.5J 1.1J 16,025 1.3J 51 4.1J 0.69J 5.8J 40 13 11 101J 2803-CDLF-1995 MW-17 27-Feb-15 1.2J 31.5J 0.15J 0.10J 1.2J 0.88J 1.5J 1,706 1.1J 28J 2.2J 0.40J 2.8J 26 4 7 19.4J 2803-CDLF-1995 MW-17 27-Oct-15 1.1J 2.4J 38.8J 0.22J 0.11J 2.3J 0.76J 1.4J 8,445 2.2J 38J 0.05J 1.7J 0.80J 0.06J 0.06J 4.7J 57 2 8 59.5J 2803-CDLF-1995 MW-17 29-Feb-16 0.09J 2.8J 44.2J 0.22J 0.06J 2.1J 1.1J 2.5J 10,331 3.8J 35J 2.5J 0.82J 7.1J 45 8 19 75.4J 2803-CDLF-1995 MW-17 17-Aug-16 0.10J 3.6J 49.8J 0.24J 0.11J 2.7J 0.87J 3.1J 8,674 3.2J 29J 2.5J 0.58J 0.08J 0.08J 5.9J 34 27 61.0J 2803-CDLF-1995 MW-17 23-Feb-17 1.3J 40.0J 0.10J 0.48J 0.51J 6,926 1.1J 33J 1.7J 0.67J 3.6J 28 7 26 51.0J 2803-CDLF-1995 MW-17 22-Sep-17 0.15J 20 59.3J 0.09J 0.10J 4.9J 1.2J 3.9J 20,116 3.0J 670 2.9J 2.8J 7.7J 17 2.50 310 71 2803-CDLF-1995 MW-17 (dissolved)22-Sep-17 NA 17 NA NA NA NA 1.2J NA 17,678 NA 623 NA NA NA NA NA 7.9J NA NA NA NA NA NA NA NA NA NA Notes: 1. Metal and volatile organic compound units are in micrograms per liter (parts per billion). 2. General chemistry units are in milligrams per liter (parts per million). 3. * - Groundwater Protection Standard 4. NE - Not Established 5. NS - No Standard 6. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. 7. (7) - MW-8 was damaged during the September 2017 sampling event and was not measured. 8. NA - Not Analyzed 9. Dissolved metal samples were collected as part of an Alternate Source Demonstration to evaluate the influence of turbidity on total metal concentrations. - Blank cell indicates the analyte was not detected - Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or Groundwater Protection Standard Page 7 of 9 November 2017 Table 3b Detected Surface Water Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 VOCs AntimonyArsenicBariumBerylliumCadmiumChromium(6)CobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneAlkalinityChloride Sulfate 5,300*150 21,000*6.5 0.15 23.81 NS 2.26 1,000 0.40 NS 0.012 24.96 5 0.06 NS NS 36.50 2,000 NS 230 NS 10 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 1 NE 250 2803-CDLF-1995 SW-1 22-Aug-11 2.8J 23.7J 0.17J 0.54J 1.4J 274J 0.19J 635 2.5J 2.0J 2.9J 2.4J 214 392 76.3J 2803-CDLF-1995 SW-1 16-Feb-12 2.1J 93J 0.19J 1.0J 2.1J 403 0.17J 201 3.9J 7.2J 0.72J 0.92J 158 935 170J 2803-CDLF-1995 SW-1 14-Aug-12 2.3J 65.1J 0.64J 2.2J 651 0.38J 225 3.4J 5.9J 0.59J 4.7J 143 717 158J 2803-CDLF-1995 SW-1 28-Feb-13 1.7J 1.8J 13.5J 0.85J 0.28J 1.7J 4,220 35 14J 0.82J 0.82J 2.2J 4.8J 5 145 2803-CDLF-1995 SW-1 30-Sep-13 0.09J 2.5J 31.8J 0.09J 0.77J 0.31J 1.7J 832 0.31J 201 0.03J 2.8J 3.1J 2.8J 2J 224 304 30.2J 2803-CDLF-1995 SW-1 17-Feb-14 0.41J 2.1J 25.5J 0.07J 3.0J 0.66J 2.0J 3,580 8.7J 145 3.4J 3.3J 2.3J 4.4J 92 208 38.8J 2803-CDLF-1995 SW-1 26-Aug-14 0.14J 2.7J 25.7J 0.07J 1.2J 0.36J 1.5J 2,426 8.6J 101 2.5J 3.5J 3.3J 2.9J 177 294 39.1J 2803-CDLF-1995 SW-1 27-Feb-15 0.44J 2.1J 32.5J 0.27J 0.05J 3.9J 1.4J 3.3J 5,885 6.9J 197 3.3J 1.3J 7.7J 12 129 165 61.6J 2803-CDLF-1995 SW-1 27-Oct-15 0.18J 2.4J 26.6J 0.17J 1.5J 0.44J 1.3J 3,277 2.4J 192 2.3J 1.8J 4.3J 2.6J 152 175 49.4J 2803-CDLF-1995 SW-1 29-Feb-16 0.27J 0.70J 24.2J 0.08J 1.2J 0.22J 1.7J 2,914 21 25J 0.88J 1.6J 1.0J 5.1J 12 153 8.9J 2803-CDLF-1995 SW-1 17-Aug-16 0.09J 2.1J 13.8J 0.12J 1.3J 0.24J 1.8J 719 0.50J 42J 2.1J 1.0J 4.0J 2.1J 165 120 2803-CDLF-1995 SW-1 23-Feb-17 0.06J 1.5J 23.1J 0.29J 0.93J 0.40J 1.00J 4,234 1.1J 172 1.7J 1.4J 6.5J 2.1J 161 117 45.6 2803-CDLF-1995 SW-1 22-Sep-17 0.16J 2.0J 12.1J 1.3J 0.62J 4,249 14 58 0.90J 0.74J 1.9J 1.4J 23 50 11.7J 2803-CDLF-1995 SW-2 18-Oct-11 0.21J 3.5J 53.3J 0.70J 0.74J 3.3J 2,396 13 153 2.7J 7.4J 0.94J 9.4J 91 1,170 127J 2803-CDLF-1995 SW-2 16-Feb-12 2.9J 97.3J 0.95J 1.4J 2.9J 2,968 4.9J 274 4.4J 6.5J 1.2J 7.6J 143 935 165J 2803-CDLF-1995 SW-2 14-Aug-12 0.14J 3.0J 56.0J 0.93J 0.62J 2.0J 2,389 4.3J 116 3.0J 4.2J 0.80J 5.4J 128 549 150J 2803-CDLF-1995 SW-2 28-Feb-13 0.49J 2.3J 35.4J 0.11J 2.0J 1.1J 3.2J 5,155 7.8J 169 3.1J 2.6J 3.2J 15 96 276 53.5J 2803-CDLF-1995 SW-2 30-Sep-13 0.08J 2.1J 33.8J 0.07J 0.70J 0.28J 1.9J 1,358 0.73J 94 0.03J 2.6J 3.3J 1.8J 2.1J 203 372 22.3J 2803-CDLF-1995 SW-2 17-Feb-14 0.33J 1.4J 23.1J 0.04J 3.1J 0.50J 2.6J 4,080 5.6J 133 3.0J 2.6J 2.0J 5.8J 93 192 56.1J 2803-CDLF-1995 SW-2 26-Aug-14 0.17J 2.3J 26.7J 0.05J 1.1J 0.27J 1.5J 1,293 2.4J 36J 2.7J 3.7J 2.2J 3.3J 175 292 20.7J 2803-CDLF-1995 SW-2 27-Feb-15 0.68J 3.6J 32.1J 0.21J 0.05J 4.6J 1.1J 4.0J 4,195 6.4J 161 3.2J 1.3J 5.8J 16 132 145 57.6J 2803-CDLF-1995 SW-2 27-Oct-15 0.20J 2.5J 29.4J 0.16J 1.8J 0.35J 1.6J 3,543 5.5J 81 2.3J 2.4J 3.5J 3.5J 146 195 52.5J 2803-CDLF-1995 SW-2 29-Feb-16 0.30J 1.4J 21.1J 0.29J 3.2J 0.75J 1.9J 4,021 13 93 2.9J 1.8J 3.7J 4.6J 103 94 23.3J 2803-CDLF-1995 SW-2 17-Aug-16 0.11J 2.9J 16.7J 0.10J 1.4J 0.21J 1.1J 1,604 1.8J 48J 1.8J 1.7J 2.8J 1.7J 158 128 2803-CDLF-1995 SW-2 23-Feb-17 0.07J 1.8J 31.2J 0.27J 0.39J 1.3J 1.4J 4,838 2.5J 149 2.1J 1.9J 6.1J 3.8J 178 127 49.5 2803-CDLF-1995 SW-2 22-Sep-17 0.16J 2.0J 12.3J 1.5J 0.25J 0.91J 4,302 14 58 0.88J 0.76J 2.1J 2.0J 9.40J 29 46 12.7J North Carolina 2B or Protective Value Freshwater Aquatic Life Standard Solid Waste Section Limit Metals General Chemistry Sample Date Surface Water Code Facility Permit Number Page 8 of 9 November 2017 Table 3b Detected Surface Water Constituents - Metals, Volatile Organic Compounds, and General Chemistry September 2017 Semi-Annual Sampling Event Dare County C&D Landfill Permit Number 2803-CDLF-1995 VOCs AntimonyArsenicBariumBerylliumCadmiumChromium(6)CobaltCopperIronLeadManganeseMercuryNickelSeleniumSilverThalliumVanadiumZincAcetoneAlkalinityChloride Sulfate 5,300*150 21,000*6.5 0.15 23.81 NS 2.26 1,000 0.40 NS 0.012 24.96 5 0.06 NS NS 36.50 2,000 NS 230 NS 10 10 100 1 1 10 10 10 300 10 50 0.2 50 10 10 5.5 25 10 100 1 NE 250 North Carolina 2B or Protective Value Freshwater Aquatic Life Standard Solid Waste Section Limit Metals General Chemistry Sample Date Surface Water Code Facility Permit Number 2803-CDLF-1995 SW-3 22-Aug-11 4.5J 44.1J 0.53J 0.93J 3.3J 1,142 2.8J 106 3.2J 6.3J 3.2J 5.2J 178 965 117J 2803-CDLF-1995 SW-3 16-Feb-12 2.7J 94.4J 0.64J 0.9J 2.2J 924 2.1J 249 3.8J 8.1J 0.72J 2.9J 159 910 153J 2803-CDLF-1995 SW-3 14-Aug-12 0.17J 2.9J 55.4J 0.86J 0.60J 1.9J 2,274 3.6J 117 2.9J 4.6J 0.60J 4.8J 116 567 144J 2803-CDLF-1995 SW-3 28-Feb-13 0.48J 2.2J 36.4J 0.12J 0.04J 2.5J 1.0J 4.1J 5,650 8.4J 162 3.1J 2.2J 4.0J 10 99 270 43.0J 2803-CDLF-1995 SW-3 30-Sep-13 0.10J 4.3J 48.7J 0.16J 1.8J 0.97J 3.2J 9,640 6.8J 398 0.04J 3.4J 3.2J 4.9J 11 202 342 22.1J 2803-CDLF-1995 SW-3 17-Feb-14 0.11J 2.1J 21.1J 0.03J 2.0J 0.43J 2.9J 2,198 2.2J 89 2.7J 4.7J 1.2J 4.0J 129 318 29.6J 2803-CDLF-1995 SW-3 26-Aug-14 0.21J 2.7J 27.3J 0.07J 1.3J 0.31J 1.7J 1,883 4.2J 43J 0.45 2.3J 3.7J 2.1J 4.0J 173 290 39.9J 2803-CDLF-1995 SW-3 27-Feb-15 0.68J 3.7J 31.5J 0.22J 0.06J 4.6J 1.1J 4.0J 4,060 6.4J 156 3.1J 1.4J 5.9J 19 121 140 69.5J 2803-CDLF-1995 SW-3 27-Oct-15 0.23J 2.2J 28.3J 0.11J 1.6J 0.36J 1.7J 3,879 5.7J 74 2.2J 1.8J 3.8J 4.5J 142 199 24.8J 2803-CDLF-1995 SW-3 29-Feb-16 0.30J 2.0J 22.7J 0.36J 0.05J 4.1J 0.86J 2.0J 4,773 15 119 3.2J 2.2J 4.2J 5.5J 110 92 33.1J 2803-CDLF-1995 SW-3 17-Aug-16 0.15J 2.6J 18.7J 0.10J 1.6J 0.26J 1.6J 2,023 3.7J 53 2.1J 1.4J 2.8J 5.5J 159 124 2803-CDLF-1995 SW-3 23-Feb-17 0.08J 1.4J 31.8J 0.23J 0.38J 1.4J 1.3J 4,837 2.5J 143 2.1J 1.5J 5.8J 6.7J 167 142 48.9 2803-CDLF-1995 SW-3 22-Sep-17 0.15J 1.9J 14.9J 1.8J 0.32J 1.4J 4,785 16 63 1.0J 0.77J 2.5J 3.5J 30 43 12.7J Notes: 1. Metal and volatile organic compound concentrations are in micrograms per liter (parts per billion). 2. General chemistry concentrations are in milligrams per liter (parts per million). 3. Standards obtained from 15A NCAC 02B (North Carolina 2B) or Protective Value Surface Water Standards for Class C Waters or are National Criteria per the U.S. Environmental Protection Agency (September 2017). 4. * - North Carolina Protective Value 5. VOCs - Volatile Organic Compounds 6. (6) - A Standard for total chromium has not been established. The value provided is for chromium (III). 7. NS - No Standard 8. NE - Not Established 9. J - Indicates the analytical result is an estimated concentration between the method detection limit and the Solid Waste Section Reporting Limit. - Blank cell indicates the analyte was not detected - Concentration exceeds the North Carolina 2B or Protective Value Freshwater Aquatic Life Standard for Class C Waters Page 9 of 9 November 2017 Appendix A Appendix B Appendix C Project:Start Date:8/9/2017 Project No.:End Date:8/9/2017 Logged By:Total Depth: 15' Location Code:Surface Casing Dia./Depth:None Location:Well Casing Dia./Depth:2" PVC to 5' Driller:Screen Dia./Depth/Slot:2" PVC: 5'-15', 0.01" Stabilized Water Level (BTOC):4.95 ft (8/9/2017) MW-9 Boring Log Drilling Rig/Method: ATV, Hollow-Stem Auger 4 5 6 Dare County C&D Landfill - MW-9 Installation 17952-221124 Depth (feet) Unified Soil Classification System Standard Penetration Test (blows per 6 inches) Formation Description Well Construction Above-Grade Completion with Expansion Cap Sand, silty, fine-grained, gray and brown, very loose, wet MacKenzie Perro MW-9 Dare County, North Carolina 1-2-1-2 SW 3 1 2 Fishburne Drilling Boring terminated at 15 feet. 16 15 9 10 11 12 13 14 Sand, fine-grained, gray, very loose, wet 8 1-0-1-0 7 SM 1-1-3-3 Bentonite Seal Bentonite Seal Page 1 of 1 MW-9 cdmsmith.com