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HomeMy WebLinkAbout9222_SouthWakeMSWLF_20161028_GWMReport SECOND SEMI-ANNUAL 2016 SAMPLING EVENT South Wake MSW Landfill, Permit No. 92-22 Wake County, North Carolina Submitted To: Wake County Disposal, LLC 3301 Benson Drive, Suite 501 Raleigh, North Carolina 27609 Submitted By: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA October 2016 0739-603916 WATER QUALITY MONITORING REPORT Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA Engineering Lic. No. C-2862/Geology Lic. No. C-399 Tel: (336) 852-4903 Fax: (336) 852-4904 www.golder.com Golder Associates: Operations in Africa, Asia, Australasia, Europe, North America and South America October 28, 2016 073-9603916 Ms. Jaclynne Drummond, Hydrogeologist Department of Environment and Natural Resources Division of Waste Management Solid Waste Section 2090 US Highway 70, Swannanoa, NC 28778 (828) 296-4604 RE: WATER QUALITY MONITORING REPORT, SECOND SEMI-ANNUAL 2016SAMPLING EVENT SOUTH WAKE MUNICIPAL SOLID WASTE LANDFILL, PERMIT NO. 92-22 WAKE COUNTY, NORTH CAROLINA Dear Jackie: On behalf of Wake County and Wake County Disposal, LLC, Golder Associates NC, Inc. is submitting the enclosed Water Quality Monitoring Report, which documents the results of the September 28, 2016, groundwater and surface water sampling event and the October 3, 2016, leachate sampling event at the above-referenced facility. No flowing water was observed during this event at SW-2 and no sample was obtained. As presented, three NC Appendix I constituents (barium, chromium, and zinc) were detected at concentrations above their Solid Waste Section Limits (SWSLs) in samples from one or more downgradient compliance well during the September 2016 event. Arsenic and nickel were also detected in samples from upgradient well MW-1 during this event at concentrations above their SWSLs. Concentrations of arsenic and barium in the sample from upgradient well MW-1 and the concentrations of chromium in samples from MW-1 and downgradient well MW-2 were detected at quantifiable concentrations above their respective groundwater standards. Above-standard concentrations in samples from the upgradient well are assumed to be naturally occurring. The chromium concentration at MW-2 is just above the applicable standard and entrained sediment may be biasing the metals concentrations high based on recorded field turbidity values; the dissolved chromium concentration is below the standard and the SWSL. A 14-day notification and alternate source demonstration are submitted under separate cover to address these above-standard concentrations. Two NC Appendix I constituents were detected at estimated concentrations below the SWSLs, but above their applicable groundwater standards during this event as they have been during previous events: cobalt and vanadium in samples from MW-2, MW-5, and MW-9. No further action is warranted for these estimated concentrations. No NC Appendix I constituents were detected above both the SWSLs or surface water standards in samples from surface water sampling points during the September 2016 monitoring event. Leachate results were generally consistent with available historical data for this facility. Based on these results, Wake County and Wake County Disposal, LLC will continue groundwater monitoring in accordance with the requirements of the Detection Monitoring Program as outlined in Title 15A NCAC 13B.1633 and .0544. The next sampling event is tentatively scheduled for April 2017. If you have any questions, please contact the undersigned at 336-852-4903. October 2016 i 073-9603916 Table of Contents COVER LETTER 1.0 INTRODUCTION .............................................................................................................................. 1 1.1 Site Description and Background ................................................................................................. 1 1.2 Compliance Monitoring History .................................................................................................... 1 1.3 Hydrogeological Setting ............................................................................................................... 2 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ............................................... 3 2.1 Visual Inspection Program ........................................................................................................... 3 2.2 Well Network and Groundwater Elevation Measurements .......................................................... 3 2.3 September 2016 Groundwater Monitoring Event......................................................................... 4 2.4 Laboratory Analysis Program ....................................................................................................... 5 2.5 September 2016 Sampling Results ............................................................................................. 5 3.0 LABORATORY AND FIELD QA/QC ................................................................................................ 6 4.0 DATA EVALUATION ........................................................................................................................ 6 4.1 North Carolina Groundwater and Surface Water Quality Standard Comparisons ....................... 6 4.2 Additional Evaluations .................................................................................................................. 7 5.0 SUMMARY ....................................................................................................................................... 7 6.0 REFERENCES ................................................................................................................................. 7 List of Tables Table 1 Summary of Historical Groundwater Elevation Data Table 2 Summary of Estimated Horizontal Flow Velocities Table 3 Summary of Well Construction Information Table 4 Summary of Groundwater Monitoring Results Table 5 Summary of Groundwater Field Parameters Table 6 Summary of Surface Water Monitoring Results Table 7 Summary of Surface Water Field Parameters Table 8 Summary of Leachate Monitoring Results List of Drawings Drawing 1 Groundwater Surface Contour Map, September 28, 2016 Drawing 2 Surface Water Location Map List of Appendices Appendix A Groundwater and Surface Water Sampling Logs Appendix B September 2016 Groundwater, Surface Water, and Leachate Certificates-of-Analysis, Chain-of-Custody Forms and Laboratory Data Reviews October 2016 1 073-9603916 1.0 INTRODUCTION This report summarizes the monitoring results from the September 28, 2016, groundwater and surface water sampling event, and the October 3, 2016, leachate sampling event at the active South Wake Municipal Solid Waste (MSW) Landfill in Wake County, North Carolina. Water quality monitoring is performed in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B.1633. The facility is owned by Wake County and operated by Wake County Disposal, LLC, a subsidiary of Waste Industries USA, Inc., under Permit No. 92-22 issued by the North Carolina (NC) Department of Environmental Quality (DEQ), formerly known as the Department of Environment and Natural Resources (DENR). 1.1 Site Description and Background The location of the facility is shown on the inlay on Drawing 1. The South Wake MSW Landfill is located approximately 4 miles south of Apex, NC in Wake County. Access to the site is from NC Highway 55 Bypass, east of the site. The Little Branch Creek is located along the southern property boundary and flows to the west, eventually into the Shearon Harris Reservoir. The location of this surface water feature is shown on Drawing 1 and Drawing 2. Based on the topography as shown on Drawing 1, topographic surface elevations at the facility range from approximately 260 feet above mean sea level (AMSL) along the drainages south and northwest of the facility, to nearly 375 feet AMSL in the northeastern portion of the future footprint. The site is surrounded predominantly by undeveloped, wooded properties, other landfills, and rural residential properties. The closed Feltonsville MSW Landfill, Permit 92-03, is located west of the active South Wake facility and is maintained by Wake County. The active Highway 55 C&D Landfill, Permit 92-30, is operated by Griffin Brothers Companies and is located north of the facility. 1.2 Compliance Monitoring History Between September and November 2007, thirteen monitoring wells (MW-1, MW-1A, MW-2, MW-2A, MW-3, MW-3A, MW-4, MW-5, MW-6, MW-6A, MW-7, MW-8 and MW-8A) were installed at the South Wake facility to monitor groundwater quality beneath the facility. Background groundwater and surface water monitoring at the facility was initiated in December 2007. Prior to the September 2013 event, the facility’s Water Quality Monitoring Plan (WQMP) was revised to remove six existing monitoring wells from the compliance monitoring network (MW-1A, MW-2A, MW-3A, MW-6, MW-6A, and MW-8A). Wells MW-6 and MW-6A were decommissioned and MW-1A, MW-2A, MW-3A, and MW-8A are monitored for water levels only. As part of the revised WQMP, one of the Phase 2 expansion wells (MW-9) was also added to the network; two additional future monitoring wells will be installed after excavation of the Phase 2 area. The facility’s revised monitoring network consists of one upgradient well (MW-1) and seven downgradient October 2016 2 073-9603916 wells (MW-2, MW-3, MW-4, MW-5, MW-7, MW-8, and MW-9) which monitor the uppermost aquifer beneath the facility. The facility’s monitoring network also includes five surface water sampling points: SW-1, SW-2, SW-3, SW-4, and SW-5. The facility’s upstream sampling points consist of SW-1, SW-2, and SW-4. Surface water sampling point SW-1 is located along a tributary to Little Branch north of the facility. Upstream monitoring point SW-2 is located along another unnamed tributary to Little Branch northeast of the facility. The third upstream point, SW-4, is located east of the facility along another unnamed tributary to Little Branch. Surface water point SW-3 is located downstream and west of the MSW disposal area along an unnamed tributary to Little Branch. Surface water point SW-5 is a second downstream sampling location located west of the facility in Little Branch. Surface points are sampled in conjunction with the groundwater monitoring wells in accordance with the facility’s permit and WQMP. Surface water monitoring points SW-1, SW-2, and SW-3 are shared with the adjacent unlined, closed Feltonsville MSW Landfill. 1.3 Hydrogeological Setting Geologically, the facility is located within the Deep River basin and Durham sub-basin, which are Triassic basins in the Piedmont Physiographic Province of North Carolina (NCGS, 1985). Generally, the Triassic basin consists of Lower Mesozoic sedimentary and igneous rocks that filled rift basins. The Durham sub- basin contains conglomerates, fanglomerates, sandstones, and mudstones. More specifically, all three Deep River sub-basins contain a middle clay-shale and mudstone interval approximately 50 to 400 meters thick, which is evident by the red clay present at the site, in addition to the presence of conglomerates and sandstones. The Deep River basin is bounded on the east by the Jonesboro fault system and is intruded by intersecting north- and northwest-striking diabase dikes (Olsen, et al. 1991). A diabase dike was identified within the facility boundaries during a magnetic survey performed during the initial site investigation. The dike is steeply dipping and trends approximately N 45˚ E. The dike bifurcates toward the southeastern portion of the facility property boundary. The dike does not intersect the Phase I disposal area (CDM, 1998). The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of regolith, partially weathered rock, and conglomerate bedrock. Groundwater occurs at depths varying widely from approximately 3 feet below grade to more than 35 feet below grade across the site. Surface water and groundwater at the site generally flows to the south and west toward Little Branch located along the southern property boundary. The Little Branch flows south to southwest and drains into Big Branch, which drains into White Oak Creek. This creek then flows into the Shearon Harris Reservoir, located approximately eight miles southwest of the facility. October 2016 3 073-9603916 Based on the September 28, 2016, groundwater surface contour map, the average hydraulic gradient in the shallow aquifer underlying the site, as measured along the conceptual flow path shown on the contour map, was calculated to be 0.032 feet/foot. Groundwater velocities were calculated using a hydraulic conductivity of 3.77E-6 centimeters per second, which is the geometric mean of the hydraulic conductivities calculated for the monitoring wells at the facility (Golder, December 2007). The estimated effective porosity of the shallow aquifer is based on the most conservative value for the available effective porosities of the hydrogeologic units, which is 0.22 (Golder, 2007). Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne where Vgw = average linear velocity (feet per year), K = hydraulic conductivity (feet per year), i = horizontal hydraulic gradient, and ne = effective porosity. The average estimated linear groundwater flow velocity under the waste management unit is approximately 0.56 feet/year toward the southwest or northwest (Table 2). The linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this equation represents a likely average value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted as part of the September 2016 sampling event are discussed in the following sections. 2.1 Visual Inspection Program In order to ensure that a potential release is detected at the earliest possible time, the visual inspection program is used at the South Wake MSW Landfill by the sampling crew. This program includes physical indicators such as potential water table mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible signs of leachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other change to the environment due to the waste management unit. During the September 2016 compliance monitoring event, no physical indicators of a potential release were observed in the vicinity of the waste management areas by the sampling personnel. 2.2 Well Network and Groundwater Elevation Measurements The current network of groundwater monitoring wells at the facility consists of eight wells. Available monitoring well construction information for all site monitoring wells is summarized in Table 3, and the well locations are shown on Drawing 1. The well locations were selected to yield groundwater samples October 2016 4 073-9603916 representative of the conditions in the uppermost aquifer underlying the facility, and to monitor for potential releases from the landfill unit. Three upstream surface water monitoring points (SW-1, SW-2, and SW-4) and two downstream surface water monitoring points (SW-3 and SW-5) are also monitored. Surface water monitoring points SW-1, SW-2, and SW-3 are shared with the adjacent unlined, closed Feltonsville MSW Landfill. Depth-to-water measurements are recorded to the nearest 0.01 foot prior to initiating groundwater purging and sampling activities. The respective groundwater level elevations for this event are presented in Table 1. The historical water level data are also shown on this table. As presented, recent groundwater elevation data for the monitoring well network indicates that the hydraulic head level in the uppermost aquifer beneath the facility is fairly consistent, with temporal variation with the long-term average limited to approximately 10 feet (plus or minus) under normal conditions. The range in fluctuation in the uppermost aquifer appears to be greatest in upgradient background well MW-1, which is located in a groundwater recharge area, and downgradient wells MW-2 and MW-8A, which have shown large fluctuations between events. Overall, the range in fluctuation in the downgradient compliance wells, which are located near groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge boundary. 2.3 September 2016 Groundwater Monitoring Event Golder personnel visited the facility on September 28, 2016, to purge and sample monitoring wells MW-1, MW-2, MW-3, MW-4, MW-5, MW-7, MW-8, and MW-9, and to sample surface water monitoring points SW-1, SW-2, SW-3, SW-4, and SW-5. No flowing water was observed at SW-2 during this event, and no sample was collected. The facility’s leachate was sampled on October 3, 2016, by Environmental Conservation Laboratories (ENCO). Depth-to-water measurements were obtained from the network monitoring wells to the nearest 0.01 foot using an electronic water level indicator prior to purging the wells. The respective groundwater level elevations for this event are presented in Table 1 along with the historical water level data. The monitoring wells were purged using dedicated bladder pumps. Measurements of pH, specific conductivity, temperature, turbidity, dissolved oxygen, and oxidation reduction potential were recorded on approximately 3- to 5-minute intervals, depending on the purge rate. In general, the purge rate for each well was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to groundwater, up to a maximum purge rate of 500 milliliters per minute. Purging was continued until stabilization was indicated by the water quality parameters. Prior to sampling, the laboratory-supplied sample containers were prepared. Each sample container was labeled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. October 2016 5 073-9603916 The groundwater samples were collected directly from the dedicated bladder pump discharge lines in the labeled, laboratory-supplied, pre-preserved sample containers after purging was completed based on stabilization of all water quality parameters. After collection, the samples were placed in a cooler on ice, under chain-of-custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling method, field observations, well location, and water quality measurements. The surface water samples were either collected directly from the stream, by lowering the sample containers into the stream flow with the opening facing into the current flow or by using a decontaminated stainless steel dipper, taking care to prevent the overflow of the sample containers and to minimize sample-induced turbidity. Measurements of pH, specific conductivity, temperature, turbidity, dissolved oxygen, and oxygen reduction potential were measured directly from the stream and recorded during the collection of the surface water samples. The leachate sample was collected by ENCO personnel on October 3, 2016, directly from the influent leachate piping manifold that serves the leachate holding tank. After collection, the surface water and leachate samples were placed in their respective coolers on ice, under chain-of-custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling location, sampling method, field observations, and water quality measurements. 2.4 Laboratory Analysis Program The September 2016 groundwater, surface water, and leachate samples were submitted to ENCO of Cary, NC under chain-of-custody control for analysis. As presented, groundwater and surface water samples at the facility were analyzed for NC Appendix I constituents. The leachate samples were analyzed for the DEQ approved list of constituents for Subtitle D facilities. The groundwater and surface water samples were received at the laboratory in good condition on September 29, 2016, and properly preserved. The leachate sample was collected and transported to the laboratory in good condition on October 3, 2016, and properly preserved. 2.5 September 2016 Sampling Results Analytical results and field parameters for the September 2016 groundwater, surface water, and leachate samples are summarized in Tables 4 through 8 along with available historical data. The laboratory certificates-of-analysis, chain-of-custody form, and laboratory data reviews for the sampling event are included in Appendix B. As presented in Table 4, three NC Appendix I inorganic constituents (barium, chromium, and zinc) were detected above the Solid Waste Section Limits (SWSLs) in samples from one or more downgradient monitoring wells during the September 2016 monitoring event. Arsenic and nickel were also detected at concentrations above the SWSLs in the upgradient well. No NC Appendix I organic constituents were October 2016 6 073-9603916 detected above the laboratory method detection limits or SWSLs in samples from downgradient monitoring wells during the event. No Appendix I constituents were detected above their respective SWSLs in samples from surface water monitoring locations during the September 2016 event. Also, leachate results were generally consistent with available historical data for this facility. 3.0 LABORATORY AND FIELD QA/QC A field blank was collected by Golder personnel as part of the September 2016 groundwater and surface water sampling event. In addition to the field blank, a laboratory-prepared trip blank accompanied the volatile sample containers to and from the laboratory. ENCO analyzed the field blank for NC Appendix I constituents and the trip blank for NC Appendix I volatile organic compounds. Reviews of the laboratory data were performed by Golder personnel and are included in Appendix B. During the September 2016 event, copper was detected in the field blank and barium was detected in the laboratory method blank at estimated concentrations. Based on Golder’s laboratory data review, the following concentrations are considered blank-qualified: copper at MW-1, MW-2, MW-3, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, SW-1, SW-3, SW-4, and SW-5. A laboratory method blank was also analyzed in conjunction with the October 3, 2016, leachate sample. Antimony was detected at an estimated concentration in the laboratory method blank. No data qualification was necessary for the leachate sample. 4.0 DATA EVALUATION The results of the data evaluations are presented in the following sections. 4.1 North Carolina Groundwater and Surface Water Quality Standard Comparisons As presented in Table 4, three constituents were detected above their respective SWSLs and groundwater standards during this event: arsenic and barium in the sample from upgradient well MW-1, and chromium in the samples from upgradient well MW-1 and downgradient well MW-2. A 14-day notification and alternate source demonstration (ASD) are submitted under separate cover to address these above-standard concentrations. Cobalt and vanadium were detected at estimated concentrations below their respective SWSLs, but above their respective Solid Waste Section (SWS) Groundwater Protection Standards (GPSs) in the samples from MW-2, MW-5, and MW-9 during this event. No further action is warranted because concentrations are estimated below the SWSLs. October 2016 7 073-9603916 No NC Appendix I organic constituents were detected above the SWSLs and groundwater standards during the September 2016 event. There were no detections of NC Appendix I constituents detected above the SWSLs or surface water standards during this event. 4.2 Additional Evaluations Above-standard concentrations in samples from the upgradient well are assumed to be naturally occurring, and the chromium concentration at MW-2 is just above the applicable standard; the dissolved chromium concentration is below the standard and the SWSL. Turbidity values were relatively high at MW-2 during this event and entrained sediment is likely biasing results high. Re-development is recommended for MW-2 prior to the next semi-annual sampling event. 5.0 SUMMARY During this sampling event, chromium at MW-2 was detected above the groundwater standard. As explained above, well re-development is recommended for this well prior to the next semi-annual event. No other actions are warranted based on the ASD submitted under separate cover. There were also no exceedances of surface water standards in the samples from surface water monitoring points during this event. Based on the results summarized herein, Wake County Disposal, LLC is in compliance with respect to water quality monitoring requirements and will continue monitoring the uppermost aquifer beneath this facility in accordance with the requirements of the Detection Monitoring Program as outlined in Title 15A NCAC 13B.1633. The next groundwater monitoring event is tentatively scheduled for April 2017. 6.0 REFERENCES Camp Dresser & McKee (CDM), January 1998 Revision, Water Quality Monitoring Plan (WQMP) and Design Hydrogeological Report, South Wake Landfill. Camp Dresser & McKee (CDM), July 2008, May 2008 Semi-Annual Monitoring Sampling Report, Feltonsville Landfill – Wake County. Golder Associates NC, Inc., (Golder) December 2007, Monitoring Well and Gas Probe Installation Report, South Wake Municipal Solid Waste Landfill, Permit 92-22. NCGS (North Carolina Geologic Survey), 1985, Geologic Map of North Carolina. Olsen et al. (Olsen, Paul E., Froelich, Albert J., Daniels, David L., Smoot, Joseph P., Gore, Pamela J.W.), Rift Basins of Early Mesozoic Age, in Horton, J.W., Jr., and Zullo, V.A., eds., The Geology of the Carolinas: The University of Tennessee Press, 1991, pp. 142-170. g:\projects\waste industries\south wake\groundwater\gwmr\sept 2016\draft\draft south wake 2nd semi-annual 2016 gw event.docx TABLES October 2016 Page 1 of 1 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx TOC Elevation (ft AMSL) Date GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW GW Elev DTW 12/5/2007 337.49 26.10 261.17 101.84 296.73 17.82 284.38 30.48 289.42 22.21 269.59 40.70 307.99 17.84 318.03 18.92 274.64 7.33 274.89 8.51 264.82 18.41 ---- 2/19/2008 341.36 22.23 269.61 93.40 298.23 16.32 284.71 30.15 290.97 20.66 272.27 38.02 308.15 17.68 319.03 17.92 275.58 6.39 275.75 7.65 275.92 7.31 ----4/9/2008 342.75 20.84 279.41 83.60 305.30 9.25 285.50 29.36 293.32 18.31 273.05 37.24 308.84 16.99 319.87 17.08 275.73 6.24 276.45 6.95 276.97 6.26 ----6/24/2008 343.34 20.25 292.80 70.21 300.44 14.11 284.35 30.51 292.01 19.62 270.49 39.80 308.18 17.65 319.74 17.21 274.81 7.16 275.27 8.13 275.61 7.62 ----10/20/2008 343.49 20.10 305.79 57.22 299.23 15.32 284.01 30.85 291.74 19.89 272.14 38.15 306.75 19.08 318.30 18.65 274.69 7.28 275.40 8.00 275.35 7.88 ---- 3/31/2009 343.41 20.18 359.56 3.45 307.10 7.45 285.81 29.05 295.54 16.09 274.73 35.56 308.12 17.71 320.90 16.05 275.53 6.44 276.69 6.71 276.99 6.24 ----9/30/2009 343.88 19.71 352.77 10.24 300.55 14.00 284.15 30.71 292.46 19.17 271.09 39.20 306.92 18.91 319.41 17.54 274.26 7.71 275.18 8.22 274.83 8.40 ----3/31/2010 343.51 20.08 358.92 4.09 300.12 14.43 285.22 29.64 294.01 17.62 274.58 35.71 308.99 16.84 322.88 14.07 274.48 7.49 276.12 7.28 275.18 8.05 ----10/6/2010 343.84 19.75 355.01 8.00 296.99 17.56 283.45 31.41 293.58 18.05 272.99 37.30 307.55 18.28 320.64 16.31 273.92 8.05 275.69 7.71 274.37 8.86 ---- 4/7/2011 342.73 20.86 357.84 5.17 295.00 19.55 283.75 31.11 292.12 19.51 273.77 36.52 306.53 19.30 320.65 16.30 274.72 7.25 276.10 7.30 275.29 7.94 ----9/29/2011 343.81 19.78 355.07 7.94 295.19 19.36 283.27 31.59 292.69 18.94 272.61 37.68 306.45 19.38 318.68 18.27 274.66 7.31 275.96 7.44 274.78 8.45 ----3/29/2012 343.17 20.42 357.82 5.19 296.53 18.02 284.96 29.90 293.83 17.80 274.49 35.80 307.64 18.19 321.41 15.54 274.87 7.10 276.49 6.91 275.59 7.64 ----9/27/2012 343.66 19.93 354.99 8.02 296.19 18.36 283.50 31.36 292.45 19.18 272.69 37.60 307.34 18.49 319.35 17.60 273.03 8.94 274.69 8.71 274.18 9.05 ---- 4/2/2013 342.41 21.18 355.64 7.37 296.84 17.71 284.90 29.96 293.92 17.71 273.88 36.41 307.68 18.15 322.30 14.65 273.71 8.26 276.14 7.26 274.98 8.25 ----9/26/2013 343.71 19.88 355.58 7.43 297.66 16.89 284.48 30.38 293.99 17.64 273.14 37.15 309.80 16.03 323.20 13.75 273.32 8.65 275.62 7.78 274.56 8.67 281.95 10.901/10/2014 ----------------------------------------278.49 14.362/25/2014 ----------------------------------------285.19 7.66 4/2/2014 342.44 21.15 356.62 6.39 303.38 11.17 284.95 29.91 295.78 15.85 274.91 35.38 312.59 13.24 324.93 12.02 274.50 7.47 277.10 6.30 275.93 7.30 285.22 7.639/30/2014 343.18 20.41 355.02 7.99 298.19 16.36 283.15 31.71 293.71 17.92 273.24 37.05 312.93 12.90 324.44 12.51 273.36 8.61 275.83 7.57 274.58 8.65 278.22 14.634/1/2015 342.68 20.91 357.69 5.32 300.99 13.56 285.30 29.56 296.07 15.56 274.68 35.61 314.20 11.63 327.06 9.89 274.19 7.78 276.82 6.58 276.13 7.10 284.62 8.239/29/2015 342.97 20.62 355.08 7.93 297.63 16.92 282.36 32.50 292.87 18.76 271.69 38.60 311.67 14.16 324.20 12.75 272.87 9.10 275.02 8.38 274.23 9.00 276.87 15.98 3/29/2016 342.59 21.00 355.80 7.21 300.58 13.97 ----295.47 16.16 274.38 35.91 313.14 12.69 326.33 10.62 273.80 8.17 276.65 6.75 275.64 7.59 284.13 8.729/28/2016 343.62 19.97 355.33 7.68 299.04 15.51 283.02 31.84 293.75 17.88 273.54 36.75 311.84 13.99 325.47 11.48 273.41 8.56 275.96 7.44 275.07 8.16 280.12 12.73MEAN342.86 20.73 338.45 24.56 299.14 15.41 284.26 30.60 293.32 18.31 273.05 37.24 309.20 16.63 321.75 15.20 274.29 7.68 275.90 7.50 274.81 8.42 281.65 11.20 MAXIMUM 343.88 26.10 359.56 101.84 307.10 19.55 285.81 32.50 296.07 22.21 274.91 40.70 314.20 19.38 327.06 18.92 275.73 9.10 277.10 8.71 276.99 18.41 285.22 15.98 MINIMUM 337.49 19.71 261.17 3.45 295.00 7.45 282.36 29.05 289.42 15.56 269.59 35.38 306.45 11.63 318.03 9.89 272.87 6.24 274.69 6.30 264.82 6.24 276.87 7.63 Notes:GW Elev = Groundwater elevation in feet above mean sea level (AMSL)DTW = Depth to Water (measured in feet below top of casing) TOC = top of casingMW = monitoring well ---- = not measured or no data available 336.95325.83310.29311.63 292.85283.23283.40281.97 MW-8AMW-8MW-7MW-3 MW-5 TABLE 1 Summary of Historical Groundwater Elevation DataSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina 363.59 363.01 MW-1A MW-2AMW-2 314.86314.55 MW-4MW-3AMonitoring WellMW-1 MW-9 October 2016 Page 1 of 1 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx South Wake Landfill, Permit No. 92-22 Wake County, North Carolina Gradient Calculation Segment Flow Direction Gradient Segment Length (feet) Gradient Segment Elevations (feet) Horizontal Gradient (i, feet) Effective Porosity (ne) Hydraulic Conductivity (K, cm/sec) Velocity (Vgw, feet/year) 320290 330 280 330 280 Notes: 1. Horizontal velocities based on the modified Darcy equation Vgw = Ki/ne. 2. Values for ne were based on the most conservative value for soil samples collected from MW-2, MW-5 and MW-6 presented in Golder's Monitoring Well Installation Report (2007). 3. Values for K were based on the geometric mean of slug test values from all site monitoring wells presented in Golder's Monitoring Well Installation Report (2007). TABLE 2 Summary of Estimated Horizontal Flow Velocities September 2016 i1 NW 636 0.0472 0.22 3.77E-06 0.84 0.37 i3 SW 1822 0.0274 0.22 3.77E-06 0.49 i2 SW 2409 0.0208 0.22 3.77E-06 October 2016 Page 1 of 1 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Monitoring Well Identification Northing Easting Date of Construction Ground Surface Elevation (ft. AMSL) Top-of-Casing Elevation (ft. AMSL) Well Depth (feet) Well Diameter (inches) Screened Interval (ft. bgs) Geology of Screened Interval WellStatus MW-1 702673.41 2047352.63 11/19/2007 362.05 363.59 30 2 15-30 Bedrock ActiveMW-1A 702660.56 2047360.61 11/19/2007 361.09 363.01 99 2 89-99 Bedrock Water Level OnlyMW-2 702160.44 2043849.59 9/20/2007 312.21 314.55 26 2 11-26 Regolith/PWR ActiveMW-2A 702149.1 2043849.33 10/4/2007 313.00 314.86 56 2 46-56 Bedrock Water Level OnlyMW-3 701889.1 2043443.96 10/3/2007 309.47 311.63 36 2 21-36 PWR ActiveMW-3A 701891.17 2043457.41 10/3/2007 307.94 310.29 76 2 66-76 PWR Water Level OnlyMW-4 701454.46 2043492.37 10/4/2007 323.71 325.83 33 2 18-33 Regolith/PWR Active MW-5 700894.27 2043468.68 9/18/2007 334.92 336.95 23 2 13-23 Regolith ActiveMW-7 699968.88 2043603.01 10/4/2007 279.81 281.97 26 2 11-26 Regolith/PWR Active MW-8 699833.49 2043779.46 10/16/2007 281.28 283.40 27 2 8-23 Regolith/PWR ActiveMW-8A 699838.47 2043783.12 10/16/2007 281.17 283.23 55 2 45-55 Bedrock Water Level OnlyMW-9 699275.90 2045188.90 2/2/2012 290.09 292.85 20 2 5-20 Regolith Active Notes:1. ft AMSL= feet above mean sea level 2. ft bgs = feet below ground surface3. N/A = Not applicable4. MW = monitoring well5.PWR = partially weathered rock6. Survey information provided by Survey Solutions P.C. of Raleigh North Carolina.7. Monitoring wells MW-1A, MW-2A, MW-3A, and MW-8A were removed from the monitoring network per the revised 2012 WQMP and are used for water levels only. TABLE 3 Summary of Well Construction InformationSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina October 2016 Page 1 of 4 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-1A MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 Antimony ug/L 12/06/07 --6 ND dry ND ND ND ND ND ND --ND SWS GPS = 1 ug/L ug/L 02/19/08 --6 ND ND ND ND ND ND ND ND --ND EPA MCL = 6 ug/L ug/L 04/09/08 --6 ND ND ND ND ND ND ND ND --ND ug/L 06/25/08 --6 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --6 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --6 ND ND ND ND ND ND ND ND --ND ug/L 09/30/09 --6 ND 0.139 J ND ND ND ND ND 0.168 J --ND ug/L 03/31/10 --6 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --6 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --6 ND 0.232 J ND ND ND ND ND ND --ND ug/L 09/29/11 --6 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --6 0.461 J 0.442 J ND 0.223 J 0.840 J ND ND ND --ND ug/L 09/27/12 --6 ND 0.650 J ND ND ND ND ND ND --ND ug/L 04/02/13 --6 0.410 B 1.20 B ND ND ND ND ND ND --0.535 J ug/L 09/26/13 --6 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --6 ----------------ND ND ug/L 02/25/14 --6 ----------------ND ND ug/L 04/02/14 --6 0.304 J --ND ND ND ND ND ND 0.563 J ND ug/L 09/30/14 0.220 6 0.375 J --0.944 J ND ND ND ND ND ND ND ug/L 04/01/15 0.220 6 0.359 J --ND ND ND ND ND ND ND ND ug/L 09/30/15 0.220 6 0.703 B --ND ND ND ND 2.51 J ND ND 0.403 J ug/L 03/29/16 0.220 6 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 0.220 6 ND --ND 0.653 J ND ND ND ND ND ND Arsenic ug/L 12/05/07 --10 ND dry 4.1 J ND ND ND ND ND --ND NC2L = 10 ug/L ug/L 02/19/08 --10 ND ND 4.9 J ND ND ND ND ND --ND EPA MCL = 10 ug/L ug/L 04/09/08 --10 ND ND 9.8 B ND ND ND ND ND --3.3 J ug/L 06/24/08 --10 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --10 ND ND 4.4 J ND ND ND ND ND --ND ug/L 09/30/09 --10 5.40 J ND 5.87 J ND 4.63 J ND ND ND --ND (Dissolved)ug/L 09/30/09 --10 -------------------- ug/L 03/31/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --10 ND ND 4.52 B ND 3.76 B ND 3.29 B ND --5.41 J ug/L 09/29/11 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --10 6.42 J 3.03 J ND ND 3.88 J ND ND ND --ND ug/L 09/27/12 --10 ND ND 3.16 B ND 3.66 B 7.55 B ND ND --5.75 J ug/L 04/02/13 --10 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --10 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --10 ----------------ND ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 ND --5.68 J ND 6.07 J ND ND ND 6.04 J ND ug/L 09/30/14 5.40 10 ND --ND ND ND 5.41 J ND ND ND ND ug/L 04/01/15 6.80 10 ND --ND ND ND ND ND ND ND ND ug/L 09/30/15 6.80 10 ND --ND ND 10.3 8.10 J ND ND 6.90 J ND ug/L 03/29/16 6.80 10 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 6.80 10 14.1 --ND ND ND ND ND ND ND ND Barium ug/L 12/05/07 --100 2060 dry 30.6 B 113 34.3 B 14.5 B 93.5 J 68.4 J --10 J NC2L = 700 ug/L ug/L 02/19/08 --100 3350 63.1 J 38.6 J 133 31.0 J 13.7 J 64.8 J 110 --ND EPA MCL = 2000 ug/L ug/L 04/09/08 --100 3020 1270 262 110 31.6 J 9.80 J 64.3 J 107 --0.90 J ug/L 06/24/08 --100 2810 116 63.3 J 87.9 J 29.1 J 12.6 J 77.5 J 100 --ND ug/L 10/20/08 --100 2770 90.0 J 39.9 J 105 28.3 J 11.4 J 82.8 J 93.5 J --ND ug/L 03/31/09 --100 2570 533 189 54.4 J 31.5 J 8.66 J 76.5 J 104 --ND ug/L 09/30/09 --100 2730 180 77.9 J 76.7 J 27.0 J 10.6 J 124 87.0 J --ND ug/L 03/31/10 --100 2430 212 30.9 J 79.1 J 25.5 J 9.29 J 97.8 J 87.7 J --ND ug/L 10/06/10 --100 2270 88.6 J 38.6 J 87.3 J 17.1 J 8.46 J 87.7 J 71.7 J --ND ug/L 04/07/11 --100 2780 218 48.7 J 96.3 J 26.3 J 9.34 J 120 106 --ND ug/L 09/29/11 --100 3150 114 55.9 J 111 27.0 J 12.0 J 147 129 --ND ug/L 03/29/12 --100 2700 178 38.7 J 105 25.8 J 8.99 J 117 129 --ND ug/L 09/27/12 --100 2550 92.1 J 35.8 J 86.7 J 22.2 J 9.85 J 116 158 --ND ug/L 04/02/13 --100 2820 147 26.3 J 71.1 J 23.5 J 23.6 J 128 141 --1.23 J ug/L 09/26/13 --100 2790 --33.7 J 65.4 J 20.3 J 12.9 J 113 161 99.0 J ND ug/L 01/10/14 --100 ----------------128 ND ug/L 02/25/14 --100 ----------------42.9 J 2.88 J ug/L 04/02/14 --100 2690 --122 55.8 J 23.1 J 14.1 J 109 159 35.2 J ND ug/L 09/30/14 1.00 100 2910 --54.5 J 69.0 J 25.4 J 22.3 J 122 171 92.5 J ND ug/L 04/01/15 1.00 100 3470 --68.9 J 63.5 J 24.1 J 20.2 J 112 160 52.0 J 1.03 J ug/L 09/30/15 1.00 100 3940 --42.1 J 77.4 J 24.3 J 20.3 J 140 185 112 ND ug/L 03/29/16 1.00 100 3480 --25.7 J 64.2 J 25.3 J 19.9 J 95.6 J 158 132 ND ug/L 09/28/16 1.00 100 3250 --42.4 J 78.3 J 25.2 J 27.6 J 104 171 127 1.74 J Beryllium ug/L 12/05/07 --1 ND dry ND ND ND ND ND ND --ND SWS GPS = 4 ug/L ug/L 02/19/08 --1 ND ND ND ND ND ND ND ND --ND EPA MCL = 4 ug/L ug/L 04/09/08 --1 ND ND 1.30 ND ND ND ND ND --ND ug/L 06/24/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --1 ND ND 1.95 ND ND ND ND 0.08 J --ND (Dissolved)ug/L 03/31/09 --1 ----1.75 -------------- ug/L 09/30/09 --1 ND ND ND ND ND 0.257 J ND ND --ND ug/L 03/31/10 --1 ND ND ND ND ND ND ND ND --ND (Verification)ug/L 04/20/10 --1 -------------------- ug/L 10/06/10 --1 ND ND ND 0.114 J ND 0.103 J ND ND --ND ug/L 04/07/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/29/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/27/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --1 ND --0.176 J ND 0.102 J 0.147 J ND ND ND ND ug/L 01/10/14 --1 ----------------ND ND ug/L 02/25/14 --1 ----------------ND ND ug/L 04/02/14 --1 ND --1.76 ND ND ND ND ND ND ND ug/L 09/30/14 0.100 1 ND --0.274 J ND ND ND ND ND ND ND ug/L 04/01/15 0.100 1 ND --0.614 J ND ND ND ND ND ND ND ug/L 09/30/15 0.100 1 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 0.100 1 ND --0.144 J ND ND ND ND ND ND ND ug/L 09/28/16 0.100 1 ND --ND ND ND ND ND ND ND ND Cadmium ug/L 12/05/07 --1 ND dry ND ND ND ND ND ND --ND NC2L = 2 ug/L ug/L 02/19/08 --1 ND ND ND ND ND ND ND ND --ND EPA MCL = 5 ug/L ug/L 04/09/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 06/24/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --1 0.26 J ND 0.09 J 0.15 J ND ND 0.14 J ND --ND ug/L 09/30/09 --1 0.481 J ND 0.386 J ND ND ND ND ND --ND ug/L 03/31/10 --1 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --1 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/29/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/27/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --1 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --1 ----------------ND ND ug/L 02/25/14 --1 ----------------ND ND ug/L 04/02/14 --1 ND --ND ND ND ND ND ND ND ND ug/L 09/30/14 0.360 1 ND --ND ND 0.403 J ND ND ND ND ND ug/L 04/01/15 0.360 1 ND --ND 0.526 J ND ND ND ND ND ND ug/L 09/30/15 0.360 1 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 0.360 1 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 0.360 1 ND --ND ND ND ND ND ND ND ND SWS Reporting Limit BlanksUpgradientDetected Monitoring Constituent/Parameter Sample DateReporting Units DowngradientMethod Detection Limit TABLE 4 Summary of Groundwater Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina October 2016 Page 2 of 4 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-1A MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 SWS Reporting Limit BlanksUpgradientDetected Monitoring Constituent/Parameter Sample DateReporting Units DowngradientMethod Detection Limit TABLE 4 Summary of Groundwater Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Chromium ug/L 12/05/07 --10 ND dry 153 ND ND ND ND ND --ND NC2L = 10 ug/L ug/L 02/19/08 --10 ND ND 118 ND 14.8 ND ND ND --ND EPA MCL = 100 ug/L ug/L 04/09/08 --10 ND 5.3 J 11.6 ND 172 ND ND ND --ND ug/L 06/24/08 --10 ND ND 8.2 J ND 76.1 ND ND ND --ND ug/L 10/20/08 --10 ND ND 41.7 ND 21.4 ND ND ND --1.2 J ug/L 03/31/09 --10 12.0 12.1 14.4 0.7 J 17.1 ND 12.7 1.1 J --ND ug/L 09/30/09 --10 340 11.8 49.2 ND 10.6 ND 48.4 1.18 J --ND ug/L 03/31/10 --10 4.35 J 25.8 12.2 ND 6.98 J 1.03 J 16.6 2.40 J --ND ug/L 10/06/10 --10 8.11 J 26.4 17.4 1.69 J 2.70 J ND 8.37 J ND --ND ug/L 04/07/11 --10 60.0 46.8 8.58 J 1.33 J 4.83 J 1.51 J 4.79 J ND --ND (Dissolved)ug/L 04/07/11 --10 ------------------ND ug/L 09/29/11 --10 70.6 54.3 19.1 1.16 J 5.59 J 1.00 J 1.75 J ND --ND ug/L 03/29/12 --10 85.3 60.9 7.19 J ND 9.14 J ND 1.33 J ND --ND ug/L 09/27/12 --10 10.8 63.9 4.80 J ND 4.38 J ND 1.50 J ND --ND ug/L 04/02/13 --10 5.66 J 69.3 3.51 J ND 5.23 J 5.78 J 1.85 J ND --ND ug/L 09/26/13 --10 2.94 J --3.08 J ND 3.04 J ND ND ND ND ND ug/L 01/10/14 --10 ----------------3.32 J ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 15.0 --6.82 J ND 6.00 J ND ND ND ND ND ug/L 09/30/14 1.40 10 26.8 --65.9 ND 2.85 J 1.81 J ND ND ND ND ug/L 04/01/15 1.40 10 658 --32.3 ND 3.80 J 2.15 J ND ND 1.85 J ND ug/L 09/30/15 1.40 10 66.8 --13.5 ND 2.24 J 1.48 J ND 2.07 J 1.93 J ND ug/L 03/29/16 1.40 10 15.4 --4.06 J ND 2.43 J 1.45 J 3.05 J ND 3.98 J ND ug/L 09/28/16 1.40 10 108 --10.6 ND 2.70 J 1.53 J 2.31 J ND 2.46 J ND (Dissolved)ug/L 09/28/16 1.00 10 ----4.51 J ------------ND Cobalt ug/L 12/05/07 --10 ND dry ND ND ND 5.8 J ND ND --ND SWS GPS = 1 ug/L ug/L 02/19/08 --10 ND ND ND ND ND 4.8 J ND ND --ND (No EPA MCL)ug/L 04/09/08 --10 ND 7.2 J 18.8 ND 6.2 J 4.2 J ND ND --ND ug/L 06/24/08 --10 ND ND ND ND ND 2.8 J ND ND --ND ug/L 10/20/08 --10 ND 2.0 J ND ND ND 1.6 J ND ND --ND ug/L 03/31/09 --10 3.2 J 1.6 J 12.8 ND 1.7 J ND ND ND --ND ug/L 09/30/09 --10 ND 1.19 J 1.40 J ND ND ND 1.74 J ND --ND ug/L 03/31/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --10 ND 1.67 J ND ND ND ND ND ND --ND ug/L 09/29/11 --10 ND 1.60 J 1.16 J ND ND 1.43 J ND ND --ND ug/L 03/29/12 --10 ND 1.49 J ND ND ND ND ND ND --ND ug/L 09/27/12 --10 ND 1.79 J ND ND ND ND ND 1.52 J --ND ug/L 04/02/13 --10 ND 1.98 J ND ND ND 2.94 J ND ND --ND ug/L 09/26/13 --10 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --10 ----------------2.41 J ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 ND --3.91 J ND ND ND ND ND ND ND ug/L 09/30/14 1.10 10 1.59 J --2.69 J ND ND 2.96 J ND ND 1.39 J ND ug/L 04/01/15 1.10 10 1.19 J --2.24 J ND ND 1.68 J ND ND ND ND ug/L 09/30/15 1.10 10 ND --1.71 J ND ND 3.49 J ND ND ND ND ug/L 03/29/16 1.10 10 ND --ND ND ND 1.18 J ND ND 3.40 J ND ug/L 09/28/16 1.10 10 ND --1.24 J ND ND 2.49 J ND ND 1.76 J ND Copper ug/L 12/05/07 --10 ND dry 1.20 J 2.00 J 2.10 J 1.80 J 2.60 J 7.00 J --ND NC2L = 1000 ug/L ug/L 02/19/08 --10 ND ND 1.80 J 1.20 J 3.00 J 0.80 J 2.40 J 4.30 J --ND EPA MCL = 1300 ug/L#ug/L 04/09/08 --10 ND 7.80 J 13.9 J 1.10 B 10.3 1.10 B 2.50 B 1.40 B --1.20 J ug/L 06/24/08 --10 ND ND ND ND 2.10 J 22.5 ND ND --ND ug/L 10/20/08 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --10 ND 3.36 B 15.9 ND 1.01 B ND ND ND --1.08 J (Dissolved)ug/L 03/31/09 --10 -------------------- ug/L 09/30/09 --10 ND 5.57 B ND ND ND ND 5.53 B ND --2.46 J ug/L 03/31/10 --10 ND 7.41 B ND ND ND ND 4.29 B ND --3.07 J ug/L 10/06/10 --10 ND 6.19 J ND ND ND ND 1.93 J ND --ND ug/L 04/07/11 --10 ND 8.09 J ND ND 1.83 J ND 3.60 J ND --ND ug/L 09/29/11 --10 ND 8.19 J ND ND ND ND 1.82 J ND --ND ug/L 03/29/12 --10 ND 6.55 J ND ND ND 1.95 J 2.24 J ND --ND ug/L 09/27/12 --10 ND 6.42 J ND ND ND ND 1.97 J ND --ND ug/L 04/02/13 --10 ND 6.41 J ND ND ND 2.60 J 1.75 J ND --ND ug/L 09/26/13 --10 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --10 ----------------3.47 J ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 ND --8.48 J ND ND ND ND ND ND ND ug/L 09/30/14 1.60 10 5.74 J --ND ND ND ND ND ND ND ND ug/L 04/01/15 1.60 10 38.8 --8.02 J 3.18 J 4.31 J 2.97 J 2.60 J 1.87 J 1.60 J ND ug/L 09/30/15 1.60 10 2.98 J --26.9 ND 1.61 J ND ND ND ND ND ug/L 03/29/16 1.60 10 ND --5.71 J ND ND ND 4.28 J 41.1 2.23 J ND ug/L 09/28/16 1.60 10 8.49 B --10.1 B 3.37 B 3.89 B 3.67 B 6.04 B 4.57 B 4.56 B 4.51 J Lead ug/L 12/05/07 --10 ND dry ND ND ND ND ND 5.2 J --ND NC2L = 15 ug/L ug/L 02/19/08 --10 ND ND ND ND ND ND ND 4.7 J --ND EPA MCL = 15 ug/L#ug/L 04/09/08 --10 ND ND 29.7 ND ND ND ND 5.9 J --ND ug/L 06/24/08 --10 ND ND 3.3 J ND 2.2 J ND ND 3.2 J --ND ug/L 10/20/08 --10 2.0 J ND 2.2 J 2.1 J ND ND ND 2.6 J --ND ug/L 03/31/09 --10 ND ND 22.6 ND ND ND ND 2.0 J --ND (Dissolved)ug/L 03/31/09 --10 -------------------- ug/L 09/30/09 --10 2.14 J ND 2.78 J ND ND ND ND ND --ND (Dissolved)ug/L 09/30/09 --10 -------------------- ug/L 03/31/10 --10 ND ND 1.90 J ND ND ND ND ND --ND (Verification)ug/L 04/20/10 --10 -------------------- (Dissolved)ug/L 04/20/10 --10 -------------------- ug/L 10/06/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --10 2.15 J 2.40 J 2.37 J 2.83 J 3.13 J ND 2.47 J 2.39 J --ND ug/L 09/29/11 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --10 ND ND ND ND ND ND ND ND --ND ug/L 09/27/12 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --10 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --10 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --10 ----------------ND ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 ND --22.0 ND ND ND ND ND ND ND (Dissolved)ug/L 04/02/14 --10 ----ND -------------- ug/L 09/30/14 2.10 10 ND --3.37 J ND ND ND ND ND ND ND ug/L 04/01/15 3.10 10 ND --6.87 J ND ND ND ND ND ND ND ug/L 09/30/15 3.10 10 ND --5.60 J 4.28 J 4.19 J 3.70 J ND 3.25 J ND ND ug/L 03/29/16 3.10 10 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 3.10 10 ND --6.30 J 3.83 J 4.43 J 3.19 J ND ND 4.87 J ND Nickel ug/L 12/05/07 --50 9.0 J dry 2.9 J 3.3 J 8.0 J 6.1 J ND 7.4 J --ND NC2L = 100 ug/L ug/L 02/19/08 --50 9.5 J ND 3.2 J ND 61.4 4.8 J 2.4 J 6.4 J --ND No EPA MCL ug/L 04/09/08 --50 4.6 J 2.3 J 43.9 J ND 270 5.6 J ND ND --ND ug/L 06/24/08 --50 ND ND 2.9 J 3.0 J 79.6 ND ND ND --ND ug/L 10/20/08 --50 6.2 J 4.4 J 2.1 J 2.9 J 97.5 3.3 J 3.6 J 2.0 J --ND ug/L 03/31/09 --50 79.3 1.8 J 31.7 J 3.6 J 63.1 1.3 J 62.2 1.4 J --ND ug/L 09/30/09 --50 110 3.96 J 2.99 J 22.4 J 34.0 J 4.41 J 28.8 J 2.81 J --ND ug/L 03/31/10 --50 167 1.99 J 8.32 J 6.64 J 24.3 J 6.22 J 78.1 ND --ND ug/L 10/06/10 --50 20.1 J ND ND 2.90 J 5.53 J 4.58 J 22.0 J ND --ND ug/L 04/07/11 --50 21.9 J ND ND 4.12 J 7.34 J 11.2 J 7.33 J ND --ND ug/L 09/29/11 --50 16.1 J 2.41 J 3.28 J 8.19 J 10.2 J 5.81 J 12.3 J ND --ND ug/L 03/29/12 --50 47.7 J ND 2.96 J 2.68 J 6.37 J 4.87 J 4.04 J 2.61 J --ND ug/L 09/27/12 --50 26.9 J ND ND 4.57 J 6.21 J 4.95 J 6.28 J 3.48 J --ND ug/L 04/02/13 --50 48.3 J ND ND 4.04 J 5.63 J 5.42 J 3.35 J 2.77 J --ND ug/L 09/26/13 --50 61.3 --ND ND 4.12 J 4.41 J 3.82 J ND ND ND ug/L 01/10/14 --50 ----------------ND ND ug/L 02/25/14 --50 ----------------ND ND ug/L 04/02/14 --50 102 --10.1 J 3.29 J 6.08 J 5.62 J 2.60 J ND ND ND ug/L 09/30/14 1.80 50 323 --65.7 ND 6.00 J 3.34 J ND ND ND ND ug/L 04/01/15 1.80 50 111 --32.6 J ND 6.51 J 4.57 J 5.33 J ND ND ND ug/L 09/30/15 1.80 50 57.7 --65.2 1.95 J 7.22 J 4.83 J 2.19 J 2.35 J 3.10 J ND ug/L 03/29/16 2.20 50 117 --15.5 J 2.49 J 7.02 J 4.38 J 7.82 J 3.62 J 5.55 J ND ug/L 09/28/16 2.20 50 74.5 --17.0 J 2.55 J 7.06 J 5.18 J 8.80 J 2.90 J 3.44 J ND October 2016 Page 3 of 4 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-1A MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 SWS Reporting Limit BlanksUpgradientDetected Monitoring Constituent/Parameter Sample DateReporting Units DowngradientMethod Detection Limit TABLE 4 Summary of Groundwater Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Selenium ug/L 12/05/07 --10 ND dry ND ND ND ND ND ND --ND NC2L = 20 ug/L ug/L 02/19/08 --10 ND ND ND ND 2.2 J ND ND ND --ND EPA MCL = 50 ug/L ug/L 04/09/08 --10 ND ND ND ND ND ND 2.0 J ND --ND ug/L 06/24/08 --10 ND 5.5 B ND ND 3.8 B 3.1 B 2.8 B ND --2.9 J ug/L 10/20/08 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --10 ND ND ND 4.4 B ND ND ND ND --3.5 J ug/L 09/30/09 --10 ND ND ND ND 4.44 J ND ND ND --ND ug/L 03/31/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/07/11 --10 ND ND ND ND ND ND ND ND --ND ug/L 09/29/11 --10 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --10 ND ND ND 3.23 (ND)J ND ND ND ND --ND ug/L 09/27/12 --10 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --10 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --10 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --10 ----------------ND ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 ND --ND ND ND ND ND ND ND ND ug/L 09/30/14 0.910 10 0.969 J --ND ND ND ND ND ND ND ND ug/L 04/01/15 0.910 10 1.00 J --1.06 J ND ND ND ND ND ND ND ug/L 09/30/15 0.910 10 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 6.20 10 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 6.20 10 ND --ND ND ND ND ND ND ND ND Silver ug/L 12/05/07 --10 ND dry ND 3.6 J ND ND ND ND --ND NC2L = 20 ug/L ug/L 02/19/08 --10 2.5 J ND ND ND ND ND ND 15.1 --ND EPA MCL = 100 ug/L*ug/L 04/09/08 --10 3.9 J ND ND ND 2.3 J ND ND 3.7 J --ND ug/L 06/24/08 --10 ND ND ND 21.9 ND ND ND ND --ND ug/L 10/20/08 --10 6.2 J 4.2 J ND 5.7 J ND ND ND ND --ND ug/L 03/31/09 --10 11.0 1.6 J ND ND ND ND ND 1.3 J --ND ug/L 09/30/09 --10 2.13 J 14.4 ND ND ND 3.13 J ND 6.78 J --ND ug/L 03/31/10 --10 3.25 J ND 22.8 ND ND ND ND ND --ND (Verification)ug/L 04/20/10 --10 ----2.78 J -------------- ug/L 10/06/10 --10 6.10 J ND ND 21.1 ND ND ND ND --ND ug/L 04/07/11 --10 2.53 J 3.18 J 1.98 J 2.58 J ND ND ND ND --ND (Dissolved)ug/L 04/07/11 --10 ------------------ND ug/L 09/29/11 --10 3.57 J 3.89 J 9.05 J 44.7 5.44 J ND ND 1.90 J --ND ug/L 03/29/12 --10 2.39 J 3.30 J 4.33 J ND ND ND ND 15.1 --ND ug/L 09/27/12 --10 4.95 J 4.08 J ND 2.79 J ND ND ND 2.78 J --ND ug/L 04/02/13 --10 5.32 J ND 3.75 J 11.5 5.08 J 2.50 J ND 9.18 J --ND ug/L 09/26/13 --10 5.01 J --ND 2.62 J 5.06 J 2.80 J ND 3.42 J ND ND ug/L 01/10/14 --10 ----------------ND ND ug/L 02/25/14 --10 ----------------ND ND ug/L 04/02/14 --10 7.70 J --ND 2.43 J 4.09 J 9.55 J ND 2.51 J ND ND ug/L 09/30/14 1.90 10 2.75 B --ND 4.95 B 7.84 B 2.25 B 2.47 B 6.06 B ND 2.52 J ug/L 04/01/15 1.90 10 9.76 J --ND 2.62 J ND ND ND 12.6 ND ND ug/L 09/30/15 1.90 10 8.60 J --ND ND 3.85 J 6.32 J ND 16.9 ND ND ug/L 03/29/16 1.90 10 ND --ND ND ND ND ND 8.54 J ND ND ug/L 09/28/16 1.90 10 2.77 J --3.04 J ND ND ND ND 4.92 J ND ND Thallium ug/L 12/05/07 --5.5 0.226 B dry 0.187 B ND ND ND ND ND --0.078 J SWS GPS = 0.28 ug/L ug/L 02/19/08 --5.5 ND 0.048 B ND ND ND ND ND ND --0.050 J EPA MCL = 2 ug/L ug/L 04/09/08 --5.5 ND ND 0.081 J ND ND ND ND ND --ND ug/L 06/24/08 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --5.5 ND ND ND 0.084 B 0.049 B 0.041 B ND ND --0.064 J ug/L 03/31/09 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 09/30/09 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 03/31/10 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --5.5 ND ND ND ND ND ND ND ND --ND (Verification)ug/L 11/18/10 --5.5 ------------------ND ug/L 04/07/11 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 09/29/11 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 09/27/12 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --5.5 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --5.5 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --5.5 ----------------ND ND ug/L 02/25/14 --5.5 ----------------ND ND ug/L 04/02/14 --5.5 ND --ND ND ND ND ND ND ND ND ug/L 09/30/14 0.110 5.5 ND --ND ND ND ND ND ND ND ND ug/L 04/01/15 0.110 5.5 ND --ND ND ND ND ND ND ND ND ug/L 09/30/15 0.110 5.5 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 0.110 5.5 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 0.110 5.5 ND --ND ND ND ND ND ND ND ND Vanadium ug/L 12/05/07 --25 ND dry 10.9 J 2.1 J ND ND 3.1 J 5.0 J --ND SWS GPS = 0.3 ug/L ug/L 02/19/08 --25 ND 4.2 J 7.0 J 1.2 J 1.1 J ND 3.9 J 4.6 J --ND No EPA MCL ug/L 04/09/08 --25 ND 158 19.4 J ND ND ND 3.4 J 3.0 J --ND ug/L 06/24/08 --25 ND 167 3.2 J ND ND ND 1.5 J 2.7 J --ND ug/L 10/20/08 --25 ND 92.3 2.6 J ND ND ND ND ND --ND ug/L 03/31/09 --25 0.9 J 68.1 16.8 J 1.8 J 1.6 J ND 2.2 J 2.6 J --ND ug/L 09/30/09 --25 ND 134 6.42 J 1.58 J 2.10 J ND 5.47 J 2.85 J --ND ug/L 03/31/10 --25 3.93 J 137 2.30 J 1.51 J 1.68 J ND ND 2.51 J --ND ug/L 10/06/10 --25 2.67 J 123 2.77 J 2.14 J ND ND ND 1.72 J --ND ug/L 04/07/11 --25 2.22 J 158 2.56 J 2.43 J 1.81 J ND 2.00 J 2.50 J --ND ug/L 09/29/11 --25 1.66 J 171 4.14 J 2.05 J 1.90 J ND 1.50 J 1.75 J --ND ug/L 03/29/12 --25 ND 147 1.92 J 1.72 J 1.58 J ND 1.43 J 1.93 J --ND ug/L 09/27/12 --25 ND 152 1.76 J 1.68 J 1.49 J ND 1.40 J 1.96 J --ND ug/L 04/02/13 --25 ND 151 1.79 J 2.30 J 1.91 J 3.23 J 1.72 J 2.17 J --ND ug/L 09/26/13 --25 ND --2.05 J 1.97 J 2.25 J ND ND ND 2.68 J ND ug/L 01/10/14 --25 ----------------5.54 J ND ug/L 02/25/14 --25 ----------------2.24 J ND ug/L 04/02/14 --25 ND --10.8 J 1.85 J 2.07 J ND ND 1.77 J ND ND ug/L 09/30/14 1.40 25 ND --4.30 J 2.01 J 2.86 J 1.67 J ND 1.52 J 3.21 J ND ug/L 04/01/15 1.40 25 9.97 J --6.12 J ND 2.26 J ND ND ND 1.46 J ND ug/L 09/30/15 1.40 25 ND --2.33 J 2.07 J 2.15 J 1.56 J ND 2.62 J 3.38 J ND ug/L 03/29/16 1.40 25 ND --2.24 J 2.29 J 2.42 J ND 2.32 J 2.24 J 8.95 J ND ug/L 09/28/16 1.40 25 ND --3.43 J ND ND 1.73 J ND ND 4.86 J ND Zinc ug/L 12/05/07 --10 ND dry 6.8 B 15.4 637 9.4 J 11.1 34.6 --1.6 J NC2L = 1000 ug/L ug/L 02/19/08 --10 ND 13.2 15.6 7.2 B 35.6 8.4 B 6.8 B 21.3 --2.1 J EPA MCL = 5000 ug/L*ug/L 04/09/08 --10 ND 13.9 B 102 8.7 B 68.9 8.2 B 4.9 B 15.9 B --3.9 J ug/L 06/24/08 --10 ND ND 38.7 4.6 J 22.6 18.1 ND 11.9 --ND ug/L 10/20/08 --10 ND ND 4.1 J ND 9.4 J ND ND ND --ND ug/L 03/31/09 --10 8.8 J ND 62.1 5.5 J 18.3 7.3 J ND 14.2 --ND (Dissolved)ug/L 03/31/09 --10 -------------------- ug/L 09/30/09 --10 9.56 J 5.10 J 9.08 J ND 10.5 ND 11.1 10.4 --ND ug/L 03/31/10 --10 ND ND 4.14 B 8.39 B 8.51 B ND 7.62 B ND --18.6 ug/L 10/06/10 --10 5.25 J ND 5.20 J 20.5 9.83 J ND ND ND --ND ug/L 04/07/11 --10 4.81 J ND ND 4.54 J 6.21 J ND ND 23.2 --ND ug/L 09/29/11 --10 ND ND 6.96 J 10.6 5.49 J 4.94 J ND ND --ND ug/L 03/29/12 --10 ND ND ND ND 14.6 ND ND ND --ND ug/L 09/27/12 --10 5.71 J ND ND ND ND ND ND 4.96 J --ND ug/L 04/02/13 --10 4.20 J ND ND ND 4.45 J 10.7 ND ND --ND ug/L 09/26/13 --10 ND --4.42 J ND ND 5.30 J ND ND 7.17 J ND ug/L 01/10/14 --10 ----------------21.9 ND ug/L 02/25/14 --10 ----------------9.75 J ND ug/L 04/02/14 --10 ND --39.0 ND 6.61 J 7.15 J ND ND ND ND ug/L 09/30/14 3.80 10 ND --10.6 ND 114 10.1 ND 3.86 J 8.33 J ND ug/L 04/01/15 3.80 10 24.9 B --17.1 B 8.12 B 48.0 10.5 B ND ND 4.31 B 9.21 J ug/L 09/30/15 3.80 10 11.3 --4.94 J ND 20.6 14.6 3.87 J 5.27 J 5.74 J ND ug/L 03/29/16 4.40 10 ND --5.03 J ND 21.3 11.4 22.4 ND 21.9 ND ug/L 09/28/16 4.40 10 ND --7.69 J ND 16.0 12.9 18.9 4.45 J 13.3 ND October 2016 Page 4 of 4 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-1A MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 SWS Reporting Limit BlanksUpgradientDetected Monitoring Constituent/Parameter Sample DateReporting Units DowngradientMethod Detection Limit TABLE 4 Summary of Groundwater Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Acetone ug/L 12/05/07 --100 2.8 B dry 2.0 B ND ND ND ND ND --2.4 J NC2L = 6000 ug/L ug/L 02/19/08 --100 ND ND ND ND ND ND ND ND --ND No EPA MCL ug/L 04/09/08 --100 ND 31 J ND ND ND ND ND ND --ND ug/L 06/24/08 --100 ND 43 J ND ND 6.3 B ND ND ND --7.0 J ug/L 10/20/08 --100 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --100 ND 30 J ND ND ND ND ND ND --ND ug/L 09/30/09 --100 ND 31 J ND ND ND ND ND ND --ND ug/L 03/31/10 --100 ND 56 J ND ND ND ND ND ND --ND ug/L 10/06/10 --100 ND 32 J ND ND ND ND ND ND --ND ug/L 04/07/11 --100 ND 34 J ND ND ND ND ND ND --ND ug/L 09/29/11 --100 ND 23 J ND ND ND ND ND ND --ND ug/L 03/29/12 --100 ND 7.8 J ND ND ND ND ND ND --ND ug/L 09/27/12 --100 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --100 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --100 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --100 ----------------ND ND ug/L 02/25/14 --100 ----------------ND ND ug/L 04/02/14 --100 ND --ND ND ND ND ND ND ND ND ug/L 09/30/14 1.2 100 ND --ND ND ND ND ND ND ND ND ug/L 04/01/15 1.2 100 ND --ND ND ND ND ND ND ND ND ug/L 09/30/15 1.2 100 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 1.2 100 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 10 100 ND --ND ND ND ND ND ND ND ND Chloroform ug/L 12/05/07 --5 ND dry 1.3 J 1.6 J ND ND ND ND --ND NC2L = 70 ug/L ug/L 02/19/08 --5 ND ND 1.5 J 2.1 J ND ND ND ND --ND EPA MCL = 80 ug/L ug/L 04/09/08 --5 ND ND ND 2.0 J ND ND ND ND --ND ug/L 06/24/08 --5 ND ND 0.42 J 1.5 J ND ND ND ND --ND ug/L 10/20/08 --5 ND ND 1.2 J 1.8 J ND ND ND ND --ND ug/L 03/31/09 --5 ND ND ND 1.3 J ND ND ND ND --ND ug/L 09/30/09 --5 ND ND 1.2 J 1.1 J ND ND ND ND --ND ug/L 03/31/10 --5 ND ND 0.42 J 1.2 J ND ND ND ND --ND ug/L 10/06/10 --5 ND ND 0.91 J 1.3 J ND ND ND ND --ND ug/L 04/07/11 --5 ND ND ND 0.93 J ND ND ND ND --ND ug/L 09/29/11 --5 ND ND 0.82 J 1.2 J ND ND ND ND --ND ug/L 03/29/12 --5 ND ND 0.52 J 0.56 J ND ND ND ND --ND ug/L 09/27/12 --5 ND ND 0.44 J 0.65 J ND ND ND ND --ND ug/L 04/02/13 --5 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --5 ND --ND 0.65 J ND ND ND ND ND ND ug/L 01/10/14 --5 ----------------ND ND ug/L 02/25/14 --5 ----------------ND ND ug/L 04/02/14 --5 ND --ND 0.82 J ND ND ND ND ND ND ug/L 09/30/14 0.18 5 ND --ND ND ND ND ND ND ND ND ug/L 04/01/15 0.18 5 0.46 J --ND ND ND ND ND ND ND ND ug/L 09/30/15 0.18 5 ND --0.65 J 0.76 J ND ND ND ND ND ND ug/L 03/29/16 0.18 5 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 0.18 5 ND --ND ND ND ND ND ND ND ND Chloromethane ug/L 12/06/07 --1 ND dry ND ND ND ND ND ND --ND NC2L = 3 ug/L ug/L 02/19/08 --1 ND ND ND ND ND ND ND ND --ND No EPA MCL ug/L 04/09/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 06/25/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 10/20/08 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/31/09 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/30/09 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/31/10 --1 ND ND ND ND ND ND ND ND --ND ug/L 10/06/10 --1 ND 0.45 B ND ND ND ND 0.69 B ND --0.51 J ug/L 04/07/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/29/11 --1 ND ND ND ND ND ND ND ND --ND ug/L 03/29/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/27/12 --1 ND ND ND ND ND ND ND ND --ND ug/L 04/02/13 --1 ND ND ND ND ND ND ND ND --ND ug/L 09/26/13 --1 ND --ND ND ND ND ND ND ND ND ug/L 01/10/14 --1 ----------------ND ND ug/L 02/25/14 --1 ----------------ND ND ug/L 04/02/14 --1 ND --ND ND ND ND ND ND ND ug/L 04/02/14 --1 ----------------ND ND ug/L 09/30/14 0.13 1 ND --ND ND ND ND ND ND ND ND ug/L 04/01/15 0.13 1 ND --ND ND ND ND ND ND ND ND ug/L 09/30/15 0.13 1 ND --ND ND ND ND ND ND ND ND ug/L 03/29/16 0.13 1 ND --ND ND ND ND ND ND ND ND ug/L 09/28/16 0.13 1 ND --ND ND ND ND ND ND ND ND Notes:ug/L =micrograms per liter J =Estimated value B =Blank-qualified value -- =no data available/not applicable# =EPA Action Level * = EPA Secondary MCL Standard =NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard Bold only =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard Shaded and Bold =Concentration above current NC 2L Groundwater Standard or NC SWS Groundwater Protection Standard and EPA MCL Blanks =field, trip and method blanks SWS Reporting Limit =NC Solid Waste Section Limits SWS GPS =Solid Waste Section Groundwater Protection Standard EPA MCL =US Environmental Protection Agency Maximum Contaminant Level NC 2L = North Carolina 2L Groundwater Standard 1) Results in parentheses () are from re-analysis 2) Monitoring wells MW-6 and MW-6A were abandoned prior to the September 2013 event. 3) Monitoring wells MW-1A, MW-2A, MW-3A, and MW-8A have been removed from the monitoring network per the revised 2012 WQMP in September 2013 and are used for water levels only. 4) MW-9 was constructed in February 2012 and added to the monitoring network prior to the September 2013 event. The September 2013 - April 2014 events for MW-9 are background events. 5) Antimony was diluted for MW-1 by 5X for the October 2016 event. October 2016 Page 1 of 2 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 pH S.U.12/05/07 6.77 9.81 6.97 5.64 5.26 6.46 6.49 -- S.U.02/19/08 6.78 8.74 6.42 5.52 5.17 6.53 6.58 --S.U.04/09/08 6.24 6.07 5.99 5.87 5.70 6.54 6.65 --S.U.06/24/08 6.53 7.00 6.27 5.45 5.08 6.26 6.46 --S.U.10/20/08 5.75 6.02 5.35 4.97 4.27 6.96 7.85 -- S.U.03/31/09 6.74 5.58 6.23 5.54 5.64 6.54 6.45 -- S.U.09/30/09 6.25 6.93 6.10 5.15 5.16 6.38 6.24 -- S.U.03/31/10 6.78 5.87 5.99 5.50 5.01 6.36 6.12 -- (Verification)S.U.04/20/10 --5.80 ------------ S.U.10/06/10 6.48 6.52 5.95 5.42 4.86 6.33 6.42 -- S.U.04/07/11 6.45 6.30 5.91 5.35 4.77 6.12 5.93 -- S.U.09/29/11 6.64 6.62 6.19 5.48 4.31 6.12 6.24 -- S.U.03/29/12 6.34 6.28 5.68 5.63 4.64 6.01 6.11 -- S.U.09/27/12 6.46 6.20 6.18 6.08 4.79 5.91 6.31 -- S.U.04/02/13 6.39 6.02 5.87 5.64 4.64 5.98 6.14 -- S.U.09/26/13 6.56 6.09 5.95 5.58 4.98 6.42 6.32 6.01 S.U.01/10/14 --------------6.28 S.U.02/25/14 --------------5.72 S.U.04/02/14 6.86 5.63 6.33 5.93 5.18 6.72 6.65 5.63 S.U.09/30/14 7.11 6.58 6.75 6.33 5.57 6.78 6.95 6.62 S.U.04/01/15 6.69 5.84 6.41 5.97 4.95 6.62 6.55 5.67 S.U.09/29/15 6.69 6.25 6.33 5.65 4.78 6.31 6.39 6.36 S.U.03/29/16 6.61 5.29 5.70 5.48 4.41 6.60 6.26 5.27 S.U.09/28/16 6.46 5.82 5.87 5.17 4.42 6.17 5.98 5.70 Specific Conductance uS/cm 12/05/07 8570 806 371 396 72 319 575 -- uS/cm 02/19/08 7460 602 530 446 69 364 534 -- uS/cm 04/09/08 6849 133 232 292 43 222 319 -- uS/cm 06/24/08 722 247 218 312 47 248 331 -- uS/cm 10/20/08 5580 230 158 229 30 231 290 -- uS/cm 03/31/09 7538 80 182 306 66 267 291 -- uS/cm 09/30/09 5582 268 139 250 33 298 258 -- uS/cm 03/31/10 5635 173 180 295 43 317 248 -- (Verification)uS/cm 04/20/10 --177 ------------ uS/cm 10/06/10 5932 283 188 272 39 303 241 -- uS/cm 04/07/11 6248 278 195 283 39 317 243 -- uS/cm 09/29/11 6198 278 197 274 40 316 262 -- uS/cm 03/29/12 5537 227 172 255 38 276 220 -- uS/cm 09/27/12 5620 209 175 250 37 291 254 -- uS/cm 04/02/13 5154 129 138 224 33 247 212 -- uS/cm 09/26/13 6798 143 163 259 42 339 302 167 uS/cm 01/10/14 --------------171 uS/cm 02/25/14 --------------87 uS/cm 04/02/14 7275 96 187 300 72 364 329 83 uS/cm 09/30/14 7627 174 197 305 81 344 340 168 uS/cm 04/01/15 7519 70 159 263 46 334 295 74 uS/cm 09/29/15 7602 145 167 274 46 280 300 169uS/cm 03/29/16 8005 72.5 163.1 283.1 45 299.1 274 91.7 uS/cm 09/28/16 8250 147 174 284 48 325 293 134 Temperature Celsius 12/05/07 15.06 16.96 15.59 13.70 12.36 15.46 14.40 -- Celsius 02/19/08 15.01 15.41 15.04 16.47 15.58 14.58 13.31 -- Celsius 04/09/08 15.37 16.96 16.23 16.75 17.18 14.97 15.90 -- Celsius 06/24/08 18.42 21.31 22.01 20.65 21.57 17.86 19.63 -- Celsius 10/20/08 19.29 18.68 18.49 17.24 17.32 18.24 18.07 -- Celsius 03/31/09 17.87 15.62 16.26 14.95 15.49 14.02 13.00 -- Celsius 09/30/09 17.05 16.75 19.05 20.13 21.24 17.90 18.06 -- Celsius 03/31/10 15.07 19.48 18.70 20.56 15.93 15.73 16.70 -- (Verification)Celsius 04/20/10 --17.07 ------------ Celsius 10/06/10 18.48 20.08 18.54 17.72 18.93 17.04 17.37 -- Celsius 04/07/11 17.68 19.55 18.55 17.66 20.98 15.15 13.66 -- Celsius 09/29/11 17.95 20.72 21.02 21.46 22.45 17.68 18.32 -- Celsius 03/29/12 15.48 21.57 18.32 18.54 20.67 15.23 14.32 -- Celsius 09/27/12 16.89 20.70 23.14 21.05 23.24 17.39 18.77 -- Celsius 04/02/13 13.54 16.27 16.56 16.63 17.70 13.39 12.30 -- Celsius 09/26/13 17.1 19.0 18.1 20.5 20.5 17.5 18.3 18.7 Celsius 01/10/14 --------------13.4 Celsius 02/25/14 --------------10.7 Celsius 04/02/14 13.9 17.2 17.1 18.3 18.3 14.4 17.2 13.3 Celsius 09/30/14 16.7 16.9 17.2 17.6 19.3 16.9 18.2 17.5 Celsius 04/01/15 13.8 14.7 14.9 15.7 16.7 13.6 13.1 12.8 Celsius 09/29/15 19.14 19.43 21.58 21.66 22.65 18.06 20.32 19.85 Celsius 03/29/16 15.4 16.2 16.5 16.8 17.9 15 14.6 14.9 Celsius 09/28/16 18.6 22.1 20.4 21.1 24 19.3 19.9 19.1 Turbidity NTU 12/05/07 92.1 61.2 40.8 34.8 92.5 64.7 890.0 -- NTU 02/19/08 7.20 52.2 11.3 9.0 6.87 28.1 129.0 -- NTU 04/09/08 17.50 >1000 4.21 17.9 3.01 12.8 95.9 -- NTU 06/24/08 7.97 439.0 4.33 15.6 3.72 4.94 73.2 -- NTU 10/20/08 18.0 62.2 3.55 5.46 2.19 3.28 45.5 -- NTU 03/31/09 27.5 >1000 8.16 8.16 5.04 20.5 45.4 -- NTU 09/30/09 25.5 92.5 5.28 6.31 1.88 67.0 16.0 -- NTU 03/31/10 19.0 85.1 5.10 3.90 10.6 16.2 22.0 -- (Verification)NTU 04/20/10 --51.6 ------------ NTU 10/06/10 10.6 19.9 7.99 0.0 2.44 4.36 0.0 -- NTU 04/07/11 7.50 34.6 9.56 5.24 1.72 3.75 6.06 -- NTU 09/29/11 15.8 98.3 22.5 11.4 14.9 5.25 16.8 -- NTU 03/29/12 23.9 17.5 3.54 7.30 4.58 2.50 16.6 -- NTU 09/27/12 3.59 13.1 3.89 6.60 1.84 3.09 46.2 -- NTU 04/02/13 4.82 20.1 6.78 6.18 128 3.00 11.6 -- NTU 09/26/13 8.48 140 6.92 9.99 9.18 3.06 12.9 86.1 NTU 01/10/14 --------------318 NTU 02/25/14 --------------64.0 NTU 04/02/14 7.99 >1000 3.53 10.8 12.0 3.44 7.80 68.8 NTU 09/30/14 19.1 315 2.44 4.71 60.8 0.63 4.94 56.9 NTU 04/01/15 358 690 1.21 2.25 23.1 0.70 3.02 31.6 NTU 09/29/15 44.3 160 4.23 4.35 61.8 1.02 11.85 80.5 NTU 03/29/16 6.12 111 6.82 8.89 25.8 18.5 15.5 246 NTU 09/28/16 4.20 115 1.87 1.46 49.8 5.47 9.20 113 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Upgradient Downgradient TABLE 5 Summary of Groundwater Field ParametersSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina October 2016 Page 2 of 2 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx MW-1 MW-2 MW-3 MW-4 MW-5 MW-7 MW-8 MW-9 Detected Monitoring Constituent/Parameter Reporting Units Sample Date Upgradient Downgradient TABLE 5 Summary of Groundwater Field ParametersSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Oxidation Reduction Potential mV 12/05/07 148 52 185 219 250 203 106 -- mV 02/19/08 196 98 193 234 278 216 208 -- mV 04/09/08 145.6 206.7 177.9 152.8 191.4 181.1 183.4 -- mV 06/24/08 160 101 161 175 235 157 95 -- mV 10/20/08 105 100 137 157 196 38 -59 -- mV 03/31/09 88.7 225.1 93.9 229.7 227.8 109.7 194.8 -- mV 09/30/09 47.7 39.6 43.7 37.2 93.3 46.9 111.4 -- mV 03/31/10 46.3 105.6 62.9 98.6 179.7 17.6 64.9 -- (Verification)mV 04/20/10 --138.6 ------------ mV 10/06/10 198.6 230.1 242.9 266.9 339.5 288.9 157.7 -- mV 04/07/11 111.8 111.0 107.1 185.0 225.7 154.4 146.7 -- mV 09/29/11 70.8 85.9 84.9 118.1 98.9 43.7 72.4 -- mV 03/29/12 166.2 93.1 100.1 144.6 173.2 95.4 134.8 -- mV 09/27/12 28.1 -32.0 -56.4 -3.6 -14.8 -120.4 -150.8 -- mV 04/02/13 5.1 14.2 -5.0 12.0 55.8 15.4 22.6 -- mV 09/26/13 138.3 182.6 186.4 215.4 272.1 172.3 174.6 190.1 mV 01/10/14 --------------64.2 mV 02/25/14 --------------235.9 mV 04/02/14 80.9 255.0 143.2 160.3 303.5 159.4 165.6 253.6 mV 09/30/14 56.3 177.9 169.9 169.4 299.7 187.6 184.4 165.6 mV 04/01/15 178.7 145.8 110.8 102.0 165.0 121.3 122.9 135.6 mV 09/29/15 -37.5 -353.7 -186.1 -187.2 -142.0 -134.9 -167.7 -145.1 mV 03/29/16 152.9 137.7 64.2 136.1 177.1 48.6 123.8 234.6 mV 09/28/16 185.2 198.5 170.8 248.4 349.3 140.3 213.2 156.2 Dissolved Oxygen mg/L 12/05/07 8.30 4.05 9.13 7.56 5.25 5.41 3.22 -- mg/L 02/19/08 7.26 4.40 6.89 7.00 5.42 6.84 5.58 -- mg/L 04/09/08 7.34 4.21 7.75 6.15 5.69 4.23 4.17 -- mg/L 06/24/08 2.95 0.65 5.48 3.97 5.88 1.39 0.55 -- mg/L 10/20/08 1.98 1.42 1.31 0.58 4.28 0.00 0.00 -- mg/L 03/31/09 1.95 5.10 3.58 2.16 5.28 2.75 3.64 -- mg/L 09/30/09 2.31 4.59 3.25 1.69 4.95 1.33 1.58 -- mg/L 03/31/10 2.99 5.09 3.25 2.41 5.92 1.72 2.98 -- (Verification)mg/L 04/20/10 --5.50 ------------ mg/L 10/06/10 2.55 2.64 2.99 3.36 6.07 6.03 3.10 -- mg/L 04/07/11 2.78 4.30 2.84 2.85 5.32 2.10 4.23 -- mg/L 09/29/11 2.74 4.31 4.07 2.74 3.62 0.63 2.69 -- mg/L 03/29/12 3.51 5.67 2.99 5.09 7.55 2.32 2.76 -- mg/L 09/27/12 1.44 3.80 3.36 1.28 4.28 1.52 1.92 -- mg/L 04/02/13 2.71 6.87 2.96 2.69 5.92 1.92 5.14 -- mg/L 09/26/13 3.07 4.43 1.39 1.38 3.91 1.62 1.73 4.78 mg/L 01/10/14 --------------6.52 mg/L 02/25/14 --------------9.28 mg/L 04/02/14 1.91 5.91 4.00 3.35 4.17 3.42 3.65 8.52 mg/L 09/30/14 3.20 5.26 3.62 2.43 5.34 3.12 2.69 4.82 mg/L 04/01/15 4.18 4.13 3.61 3.40 3.38 2.79 4.31 7.75 mg/L 09/29/15 4.91 4.53 3.32 3.10 2.87 0.88 3.29 3.74 mg/L 03/29/16 3.80 1.58 4.07 4.22 3.06 2.00 3.32 5.49 mg/L 09/28/16 2.97 2.57 1.12 1.15 1.68 0.42 1.21 4.16 Notes:mg/L =milligrams per liter S.U. =Standard Units NTU =Nephelometric Turbidity Units uS/cm =microsiemens per centimeter mV = millivolts -- =no data available/not applicable October 2016 Page 1 of 5 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Antimony ug/L 12/06/07 --6 ND dry ND dry ND ND (No SW Standard)ug/L 04/09/08 --6 ND ND ND ND ND ND ug/L 10/21/08 --6 ND dry ND dry ND ND ug/L 03/31/09 --6 ND ND ND ND ND ND ug/L 09/30/09 --6 dry dry dry dry ND ND ug/L 03/31/10 --6 ND ND ND ND ND ND ug/L 10/06/10 --6 ND dry ND ND ND ND ug/L 04/07/11 --6 ND ND ND ND ND ND ug/L 09/30/11 --6 ND dry ND ND ND ND ug/L 03/29/12 --6 ND ND ND ND ND ND ug/L 09/27/12 --6 ND dry ND dry ND ND ug/L 04/02/13 --6 ND ND ND ND ND 0.535 J ug/L 09/26/13 --6 ND Dry ND ND ND ND ug/L 04/02/14 --6 ND ND ND ND ND NDug/L 09/30/14 0.220 6 0.240 J dry ND ND ND ND ug/L 04/01/15 0.220 6 ND ND ND ND ND ND ug/L 09/30/15 0.220 6 ND ND ND ND ND 0.403 J ug/L 03/29/16 0.220 6 ND ND ND ND ND ND ug/L 09/28/16 0.220 6 ND --ND ND ND ND Arsenic ug/L 12/06/07 --10 2.5 J dry 3.2 J dry 3.8 J NDHuman Health SW Standard = 10 ug/L ug/L 04/09/08 --10 ND ND ND ND ND ND ug/L 10/21/08 --10 ND dry ND dry ND ND ug/L 03/31/09 --10 ND ND ND ND ND ND ug/L 09/30/09 --10 dry dry dry dry ND ND ug/L 03/31/10 --10 ND ND ND ND ND ND ug/L 10/06/10 --10 ND dry ND ND ND ND ug/L 04/07/11 --10 ND ND ND ND ND 5.41 J ug/L 09/30/11 --10 ND dry ND ND ND ND ug/L 03/29/12 --10 ND ND ND 2.95 J ND ND ug/L 09/27/12 --10 4.10 B dry 4.75 B dry 3.40 B 5.75 J ug/L 04/02/13 --10 ND 2.87 J ND ND ND ND ug/L 09/26/13 --10 ND dry ND ND ND ND ug/L 04/02/14 --10 ND ND ND ND ND ND ug/L 09/30/14 5.40 10 ND dry ND ND ND ND ug/L 04/01/15 6.80 10 ND ND ND ND ND ND ug/L 09/30/15 6.80 10 ND ND ND ND ND ND ug/L 03/29/16 6.80 10 ND ND ND ND ND ND ug/L 09/28/16 6.80 10 ND --ND ND ND ND Barium ug/L 12/06/07 --100 51.2 J dry 51.9 J dry 61.5 J 10 JHuman Health SW Standard = 200000 ug/L ug/L 04/09/08 --100 48.1 J 38.3 J 47.8 J 58.0 J 73.7 J ND ug/L 10/21/08 --100 40.5 J dry 107 dry 76.2 J ND ug/L 03/31/09 --100 47.4 J 34.5 J 52.8 J 50.7 J 74.2 J ND ug/L 09/30/09 --100 dry dry dry dry 68.6 J ND ug/L 03/31/10 --100 43.1 J 40.8 J 45.0 J 55.7 J 40.9 J ND ug/L 10/06/10 --100 29.3 J dry 33.3 J 58.6 J 44.8 J NDug/L 04/07/11 --100 49.2 J 45.5 J 56.0 J 66.2 J 46.1 J ND ug/L 09/30/11 --100 78.6 J dry 65.8 J 60.5 J 34.2 J ND ug/L 03/29/12 --100 52.5 J 52.2 J 52.0 J 73.7 J 46.3 J ND ug/L 09/27/12 --100 36.9 J dry 40.7 J dry 50.8 J ND ug/L 04/02/13 --100 51.9 J 50.9 J 52.9 J 68.7 J 49.9 J 1.23 J ug/L 09/26/13 --100 35.5 J dry 46.7 J 63.0 J 57.8 J ND ug/L 04/02/14 --100 45.9 J 35.9 J 44.8 J 48.7 J 269 ND ug/L 09/30/14 1.00 100 80.5 J dry 35.7 J 70.8 J 109 ND ug/L 04/01/15 1.00 100 68.5 J 42.3 J 44.1 J 57.3 J 142 1.03 J ug/L 09/30/15 1.00 100 56.4 J 72.6 J 57.9 J 65.3 J 59.8 J ND ug/L 03/29/16 1.00 100 57.8 J 64.2 J 48.4 J 53.1 J 48.9 J ND ug/L 09/28/16 1.00 100 38.6 J --39.3 J 59.0 J 54.1 J 1.74 J Beryllium ug/L 12/06/07 --1 ND dry ND dry ND ND Freshwater Acute SW Standard = 65 ug/L ug/L 04/09/08 --1 ND ND ND ND ND ND Freshwater Chronic SW Standard = 6.5 ug/L ug/L 10/21/08 --1 ND dry ND dry ND ND ug/L 03/31/09 --1 ND ND 0.13 J ND 0.20 J ND ug/L 09/30/09 --1 dry dry dry dry 0.148 J ND ug/L 03/31/10 --1 ND ND ND ND ND ND ug/L 10/06/10 --1 ND dry 0.116 J ND ND NDug/L 04/07/11 --1 ND ND ND ND ND ND ug/L 09/30/11 --1 0.131 J dry ND ND ND ND ug/L 03/29/12 --1 ND ND ND ND ND ND ug/L 09/27/12 --1 ND dry ND dry ND ND ug/L 04/02/13 --1 ND ND ND ND ND ND ug/L 09/26/13 --1 ND dry ND ND ND NDug/L 04/02/14 --1 ND ND ND ND 0.534 J ND ug/L 09/30/14 0.100 1 ND dry ND ND 0.110 J ND ug/L 04/01/15 0.100 1 ND ND ND ND 0.111 J ND ug/L 09/30/15 0.100 1 ND ND ND ND ND ND ug/L 03/29/16 0.100 1 ND ND ND ND ND ND ug/L 09/28/16 0.100 1 ND --ND ND ND ND Detected Constituent (SW Standard) Reporting Units Sample Date SWS Reporting Limit Surface Water Monitoring PointsMethod Detection Limit TABLE 6 Summary of Surface Water Monitoring Results Detected ConstituentsSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina Blanks SW-1 SW-2 SW-3 SW-4 SW-5 October 2016 Page 2 of 5 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent (SW Standard) Reporting Units Sample Date SWS Reporting Limit Surface Water Monitoring PointsMethod Detection Limit TABLE 6 Summary of Surface Water Monitoring Results Detected ConstituentsSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina Blanks SW-1 SW-2 SW-3 SW-4 SW-5 Cadmium ug/L 12/06/07 --1 ND dry ND dry ND ND Freshwater Acute SW Standard = 0.82 ug/L ug/L 04/09/08 --1 ND ND ND ND ND ND Freshwater Chronic SW Standard = 0.15 ug/L ug/L 10/21/08 --1 ND dry ND dry ND ND ug/L 03/31/09 --1 ND 0.17 J 0.25 J ND ND ND ug/L 09/30/09 --1 dry dry dry dry ND ND ug/L 03/31/10 --1 ND ND ND ND ND ND ug/L 10/06/10 --1 ND dry ND ND ND ND ug/L 04/07/11 --1 ND ND ND ND ND ND ug/L 09/30/11 --1 ND dry ND ND ND ND ug/L 03/29/12 --1 ND ND ND ND ND ND ug/L 09/27/12 --1 ND dry ND dry ND ND ug/L 04/02/13 --1 ND ND ND ND ND ND ug/L 09/26/13 --1 ND dry ND ND ND ND ug/L 04/02/14 --1 ND ND ND ND ND NDug/L 09/30/14 0.360 1 ND dry ND ND 0.391 J ND ug/L 04/01/15 0.360 1 ND ND ND ND ND ND ug/L 09/30/15 0.360 1 ND ND ND ND ND ND ug/L 03/29/16 0.360 1 ND ND ND ND ND ND ug/L 09/28/16 0.360 1 ND --ND ND ND ND Chromium ug/L 12/06/07 --10 ND dry ND dry ND NDFreshwater Acute SW Standard = 180 ug/L ug/L 04/09/08 --10 ND ND ND ND ND ND Freshwater Chronic SW Standard = 24 ug/L ug/L 10/21/08 --10 ND dry 3.7 B dry ND 1.2 J ug/L 03/31/09 --10 0.7 J ND 1.8 J ND 5.2 J ND ug/L 09/30/09 --10 dry dry dry dry 1.48 J ND ug/L 03/31/10 --10 1.12 J 1.13 J ND ND 1.39 J ND ug/L 10/06/10 --10 ND dry ND ND 4.63 J ND ug/L 04/07/11 --10 ND ND ND ND ND ND ug/L 09/30/11 --10 4.25 J dry 2.70 J ND ND ND ug/L 03/29/12 --10 ND ND ND 2.51 J ND ND ug/L 09/27/12 --10 ND dry 1.67 J dry ND ND ug/L 04/02/13 --10 ND 3.00 J ND ND ND ND ug/L 09/26/13 --10 ND dry ND ND 3.54 J ND ug/L 04/02/14 --10 ND ND ND ND 13.0 ND ug/L 09/30/14 1.40 10 4.36 J dry ND ND 3.95 J ND ug/L 04/01/15 1.40 10 3.45 J ND ND ND 5.40 J ND ug/L 09/30/15 1.40 10 ND 2.05 J ND ND 2.23 J ND ug/L 03/29/16 1.40 10 ND 3.44 J ND ND ND ND ug/L 09/28/16 1.40 10 ND --ND ND ND ND Cobalt ug/L 12/06/07 --10 ND dry ND dry ND ND(No SW Standard)ug/L 04/09/08 --10 ND ND ND ND ND ND ug/L 10/21/08 --10 ND dry 1.1 J dry 1.4 J ND ug/L 03/31/09 --10 ND 0.6 J 2.7 J ND 2.2 J ND ug/L 09/30/09 --10 dry dry dry dry ND ND ug/L 03/31/10 --10 ND ND ND ND ND ND ug/L 10/06/10 --10 ND dry ND ND 1.24 J NDug/L 04/07/11 --10 ND ND ND ND ND ND ug/L 09/30/11 --10 1.94 J dry 1.18 J ND ND ND ug/L 03/29/12 --10 ND 1.39 J ND ND ND ND ug/L 09/27/12 --10 ND dry 1.21 J dry 1.20 J ND ug/L 04/02/13 --10 ND ND ND ND ND ND ug/L 09/26/13 --10 ND dry 1.11 J ND 1.36 J ND ug/L 04/02/14 --10 ND ND ND ND 5.75 J ND ug/L 09/30/14 1.10 10 2.28 J dry ND ND 2.72 J ND ug/L 04/01/15 1.10 10 1.86 J ND ND ND 2.96 J ND ug/L 09/30/15 1.10 10 ND ND ND ND 1.85 J ND ug/L 03/29/16 1.10 10 ND 1.97 J ND ND ND ND ug/L 09/28/16 1.10 10 ND --ND ND ND ND Copper ug/L 12/06/07 --10 1.3 J dry 1.3 J dry ND ND Freshwater Acute SW Standard = 3.6 ug/L ug/L 04/09/08 --10 ND ND ND 5.0 B ND 1.2 J Freshwater Chronic SW Standard = 2.7 ug/L ug/L 10/21/08 --10 ND dry ND dry ND ND ug/L 03/31/09 --10 1.14 B 1.24 B 2.62 B 1.26 B 4.54 B 1.08 J ug/L 09/30/09 --10 dry dry dry dry ND 2.46 J ug/L 03/31/10 --10 ND ND ND ND ND 3.07 J ug/L 10/06/10 --10 ND dry 2.89 J 1.81 J 4.12 J NDug/L 04/07/11 --10 ND ND 2.09 J 1.72 J ND ND ug/L 09/30/11 --10 3.86 J dry 3.09 J 1.78 J 1.76 J ND ug/L 03/29/12 --10 ND ND ND ND ND ND ug/L 09/27/12 --10 ND dry ND dry ND ND ug/L 04/02/13 --10 ND 3.56 J ND 1.99 J ND ND ug/L 09/26/13 --10 ND dry ND ND 2.81 J NDug/L 04/02/14 --10 ND ND ND ND 4.58 J ND ug/L 09/30/14 1.60 10 3.84 J dry ND ND ND ND ug/L 04/01/15 1.60 10 4.05 J 2.98 J 2.55 J 2.20 J 4.47 J ND ug/L 09/30/15 1.60 10 1.94 J 3.98 J 2.33 J 2.63 J 2.23 J ND ug/L 03/29/16 1.60 10 ND 3.84 J 2.07 J ND 2.98 J ND ug/L 09/28/16 1.60 10 3.66 B --2.68 B 3.67 B 3.61 B 4.51 J October 2016 Page 3 of 5 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent (SW Standard) Reporting Units Sample Date SWS Reporting Limit Surface Water Monitoring PointsMethod Detection Limit TABLE 6 Summary of Surface Water Monitoring Results Detected ConstituentsSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina Blanks SW-1 SW-2 SW-3 SW-4 SW-5 Lead ug/L 12/06/07 --10 ND dry ND dry 2.7 J ND Freshwater Acute SW Standard = 14 ug/L ug/L 04/09/08 --10 ND ND ND ND 3.6 J ND Freshwater Chronic SW Standard = 0.54 ug/L ug/L 10/21/08 --10 ND dry 10.3 dry 4.6 J ND ug/L 03/31/09 --10 ND ND ND ND 5.6 J ND ug/L 09/30/09 --10 dry dry dry dry 2.10 J ND ug/L 03/31/10 --10 9.71 J 2.15 J ND ND ND ND ug/L 10/06/10 --10 ND dry ND ND ND ND ug/L 04/07/11 --10 2.58 J 2.84 J ND ND 2.11 J ND ug/L 09/30/11 --10 ND dry ND ND ND ND ug/L 03/29/12 --10 ND ND ND ND 2.16 J ND ug/L 09/27/12 --10 ND dry ND dry ND ND ug/L 04/02/13 --10 ND ND ND ND ND ND ug/L 09/26/13 --10 ND dry ND ND ND ND ug/L 04/02/14 --10 ND ND ND ND 18.2 NDug/L 09/30/14 2.10 10 ND dry ND ND 2.50 J ND ug/L 04/01/15 3.10 10 ND ND ND ND 3.11 J ND ug/L 09/30/15 3.10 10 3.25 J 4.63 J 3.37 J 3.56 J 5.91 J ND ug/L 03/29/16 3.10 10 ND ND ND ND ND ND ug/L 09/28/16 3.10 10 ND --ND ND ND ND Nickel ug/L 12/06/07 --50 ND dry ND dry ND NDFreshwater Acute SW Standard = 140 ug/L ug/L 04/09/08 --50 ND ND ND 5.9 J ND ND Freshwater Chronic SW Standard = 16 ug/L ug/L 10/21/08 --50 ND dry 4.0 J dry 2.2 J ND ug/L 03/31/09 --50 0.7 J ND 1.5 J ND 2.5 J ND ug/L 09/30/09 --50 dry dry dry dry ND ND ug/L 03/31/10 --50 ND ND ND ND ND ND ug/L 10/06/10 --50 ND dry ND ND ND ND ug/L 04/07/11 --50 ND ND ND ND ND ND ug/L 09/30/11 --50 2.49 J dry 1.85 J ND ND ND ug/L 03/29/12 --50 ND ND ND 1.89 J ND ND ug/L 09/27/12 --50 ND dry ND dry ND ND ug/L 04/02/13 --50 ND ND ND ND ND ND ug/L 09/26/13 --50 ND dry ND ND ND ND ug/L 04/02/14 --50 1.84 J ND ND ND 4.23 J ND ug/L 09/30/14 1.80 50 ND dry ND ND ND ND ug/L 04/01/15 1.80 50 ND 2.87 J ND ND 1.93 J ND ug/L 09/30/15 1.80 50 ND ND ND ND 2.74 J ND ug/L 03/29/16 2.20 50 ND ND ND ND ND ND ug/L 09/28/16 2.20 50 ND --ND ND ND ND Selenium ug/L 12/06/07 --10 ND dry ND dry ND NDFreshwater Acute SW Standard = 5 ug/L ug/L 04/09/08 --10 4.3 J ND ND ND ND ND Freshwater Chronic SW Standard = 5 ug/L ug/L 10/21/08 --10 ND dry ND dry ND ND ug/L 03/31/09 --10 ND ND ND ND ND 3.5 J ug/L 09/30/09 --10 dry dry dry dry ND ND ug/L 03/31/10 --10 ND ND ND ND ND ND ug/L 10/06/10 --10 ND dry ND ND ND NDug/L 04/07/11 --10 ND ND ND ND 3.05 J (ND)ND ug/L 09/30/11 --10 ND dry ND ND ND ND ug/L 03/29/12 --10 ND ND ND ND ND ND ug/L 09/27/12 --10 ND dry ND dry ND ND ug/L 04/02/13 --10 ND ND ND ND ND ND ug/L 09/26/13 --10 ND dry ND ND ND ND ug/L 04/02/14 --10 ND ND ND ND ND ND ug/L 09/30/14 0.910 10 ND dry ND ND ND ND ug/L 04/01/15 0.910 10 ND ND ND ND ND ND ug/L 09/30/15 0.910 10 ND ND ND ND ND ND ug/L 03/29/16 6.20 10 ND ND ND ND ND ND ug/L 09/28/16 6.20 10 ND --ND ND ND ND Silver ug/L 12/06/07 --10 ND dry ND dry ND ND Freshwater Acute SW Standard = 30 ug/L ug/L 04/09/08 --10 ND ND ND ND ND ND Freshwater Chronic SW Standard = 0.06 ug/L ug/L 10/21/08 --10 ND dry ND dry ND ND ug/L 03/31/09 --10 ND ND ND ND ND ND ug/L 09/30/09 --10 dry dry dry dry ND ND ug/L 03/31/10 --10 ND ND ND ND ND ND ug/L 10/06/10 --10 ND dry ND ND ND NDug/L 04/07/11 --10 ND ND ND ND ND ND ug/L 09/30/11 --10 ND dry ND ND ND ND ug/L 03/29/12 --10 ND ND ND ND ND ND ug/L 09/27/12 --10 ND dry ND dry ND ND ug/L 04/02/13 --10 ND ND 2.34 J ND ND ND ug/L 09/26/13 --10 ND dry ND ND ND NDug/L 04/02/14 --10 ND ND ND ND ND ND ug/L 09/30/14 1.90 10 ND dry 2.43 B 2.31 B ND 2.52 J ug/L 04/01/15 1.90 10 ND ND ND ND ND ND ug/L 09/30/15 1.90 10 ND ND ND ND ND ND ug/L 03/29/16 1.90 10 ND ND ND ND ND ND ug/L 09/28/16 1.90 10 ND --ND ND ND ND October 2016 Page 4 of 5 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent (SW Standard) Reporting Units Sample Date SWS Reporting Limit Surface Water Monitoring PointsMethod Detection Limit TABLE 6 Summary of Surface Water Monitoring Results Detected ConstituentsSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina Blanks SW-1 SW-2 SW-3 SW-4 SW-5 Thallium ug/L 12/06/07 --5.5 0.069 B dry 0.079 B dry ND 0.078 J (No SW Standard)ug/L 04/09/08 --5.5 ND ND ND ND 0.037 J ND ug/L 10/21/08 --5.5 ND dry 0.096 B dry 0.049 B 0.064 J ug/L 03/31/09 --5.5 ND ND ND ND ND ND ug/L 09/30/09 --5.5 dry dry dry dry ND ND ug/L 03/31/10 --5.5 ND ND ND ND ND ND ug/L 10/06/10 --5.5 ND dry ND ND ND ND ug/L 04/07/11 --5.5 ND ND ND ND ND ND ug/L 09/30/11 --5.5 ND dry ND ND ND ND ug/L 03/29/12 --5.5 ND ND ND ND ND ND ug/L 09/27/12 --5.5 ND dry ND dry ND ND ug/L 04/02/13 --5.5 ND ND ND ND ND ND ug/L 09/26/13 --5.5 ND dry ND ND ND ND ug/L 04/02/14 --5.5 ND ND ND ND ND NDug/L 09/30/14 0.110 5.5 ND dry ND ND ND ND ug/L 04/01/15 0.110 5.5 ND ND ND ND ND ND ug/L 09/30/15 0.110 5.5 ND ND ND ND ND ND ug/L 03/29/16 0.110 5.5 ND ND ND ND ND ND ug/L 09/28/16 0.110 5.5 ND --ND ND ND ND Vanadium ug/L 12/06/07 --25 ND dry ND dry ND ND(No SW Standard)ug/L 04/09/08 --25 ND 2.0 J ND 1.9 J 3.4 J ND ug/L 10/21/08 --25 ND dry 16.5 J dry 6.8 J ND ug/L 03/31/09 --25 2.3 J 3.5 J 5.3 J 3.5 J 15.5 J ND ug/L 09/30/09 --25 dry dry dry dry 6.59 J ND ug/L 03/31/10 --25 1.55 J 5.76 J 2.24 J 2.73 J 3.24 J ND ug/L 10/06/10 --25 ND dry ND 3.70 J 16.4 J ND ug/L 04/07/11 --25 ND 5.25 J 2.48 J 2.07 J 2.39 J ND ug/L 09/30/11 --25 15.8 J dry 11.0 J 3.65 J 3.35 J ND ug/L 03/29/12 --25 ND 4.11 J ND 1.51 J 4.53 J ND ug/L 09/27/12 --25 3.90 J dry 6.64 J dry 3.07 J ND ug/L 04/02/13 --25 1.58 J 5.16 J 1.76 J 2.94 J 2.31 J ND ug/L 09/26/13 --25 ND dry 2.11 J ND 12.4 J ND ug/L 04/02/14 --25 1.45 J 2.79 J 1.48 J 2.63 J 60.3 ND ug/L 09/30/14 1.40 25 12.4 J dry ND ND 13.6 J ND ug/L 04/01/15 1.40 25 10.9 J 2.15 J ND 1.72 J 21.3 J ND ug/L 09/30/15 1.40 25 2.35 J 8.86 J 2.95 J 2.86 J 5.14 J ND ug/L 03/29/16 1.40 25 6.10 J 12.9 J 3.77 J 3.19 J 5.49 J ND ug/L 09/28/16 1.40 25 ND --ND 2.08 J 4.21 J ND Zinc ug/L 12/06/07 --10 5.8 B dry 6.7 B dry 11.1 1.6 JFreshwater Acute SW Standard = 36 ug/L ug/L 04/09/08 --10 6.2 J 5.9 J 5.1 J 7.7 J 81.5 ND Freshwater Chronic SW Standard = 36 ug/L ug/L 10/21/08 --10 ND dry 35.7 dry ND ND ug/L 03/31/09 --10 6.9 J 28.6 49.3 60.9 22.4 ND ug/L 09/30/09 --10 dry dry dry dry 12.8 ND ug/L 03/31/10 --10 12.0 B 22.3 B 30.9 B 7.06 B 13.5 B 18.6 ug/L 10/06/10 --10 ND dry 6.38 J 6.50 J 12.5 NDug/L 04/07/11 --10 ND 4.89 J 4.02 J 6.54 J 7.78 J ND ug/L 09/30/11 --10 15.1 dry 9.79 J ND 3.91 J ND ug/L 03/29/12 --10 4.16 J 7.87 J ND ND 4.17 J ND ug/L 09/27/12 --10 ND dry ND dry ND ND ug/L 04/02/13 --10 ND 6.02 J ND 4.51 J 4.73 J ND ug/L 09/26/13 --10 ND dry 5.46 J ND 11.8 ND ug/L 04/02/14 --10 4.84 J 4.62 J 4.32 J 5.07 J 56.2 ND (Verification Event)ug/L 05/15/14 --10 --------ND ND ug/L 09/30/14 3.80 10 16.8 dry ND ND 11.9 ND ug/L 04/01/15 3.80 10 10.9 B 4.83 B 4.02 B ND 34.0 B 9.21 J ug/L 09/30/15 3.80 10 ND 18.9 ND ND 7.52 J ND ug/L 03/29/16 4.40 10 6.57 J 14.0 5.13 J ND 9.36 J ND ug/L 09/28/16 4.40 10 ND --8.54 J ND ND ND Acetone ug/L 12/06/07 --100 7.5 B dry 10 B dry ND 2.4 J SW Standard = 2000 ug/L ug/L 04/09/08 --100 ND ND ND ND ND ND ug/L 10/21/08 --100 ND dry ND dry ND ND ug/L 03/31/09 --100 ND ND 8.2 J ND 7.9 J ND ug/L 09/30/09 --100 dry dry dry dry ND ND ug/L 03/31/10 --100 ND ND ND ND ND NDug/L 10/06/10 --100 ND dry ND 3.2 J ND ND ug/L 04/07/11 --100 3.1 J 3.0 J (ND)3.6 J ND 4.0 J ND ug/L 09/30/11 --100 ND dry ND ND 7.5 J ND ug/L 03/29/12 --100 ND ND ND ND ND ND ug/L 09/27/12 --100 ND dry ND dry 7.4 J ND ug/L 04/02/13 --100 ND ND ND ND ND NDug/L 09/26/13 --100 ND dry ND ND ND ND ug/L 04/02/14 --100 ND ND ND ND ND ND ug/L 09/30/14 1.2 100 ND dry ND ND ND ND ug/L 04/01/15 1.2 100 ND ND ND ND ND ND ug/L 09/30/15 1.2 100 ND ND ND ND 45 J ND ug/L 03/29/16 1.2 100 ND ND ND ND ND ND ug/L 09/28/16 10 100 ND --ND ND ND ND October 2016 Page 5 of 5 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent (SW Standard) Reporting Units Sample Date SWS Reporting Limit Surface Water Monitoring PointsMethod Detection Limit TABLE 6 Summary of Surface Water Monitoring Results Detected ConstituentsSouth Wake Landfill, Permit No. 92-22 Wake County, North Carolina Blanks SW-1 SW-2 SW-3 SW-4 SW-5 2-Butanone ug/L 12/06/07 --100 ND dry ND dry ND ND (No SW Standard)ug/L 04/09/08 --100 ND ND ND ND ND ND ug/L 10/21/08 --100 ND dry ND dry ND ND ug/L 03/31/09 --100 ND ND ND ND 3.3 J ND ug/L 09/30/09 --100 dry dry dry dry ND ND ug/L 03/31/10 --100 ND ND ND ND ND ND ug/L 10/06/10 --100 ND dry ND ND ND ND ug/L 04/07/11 --100 ND ND ND ND ND ND ug/L 09/30/11 --100 ND dry ND ND ND ND ug/L 03/29/12 --100 ND ND ND ND ND ND ug/L 09/27/12 --100 ND dry ND dry ND ND ug/L 04/02/13 --100 ND ND ND ND ND ND ug/L 09/26/13 --100 ND dry ND ND ND ND ug/L 04/02/14 --100 ND ND ND ND ND NDug/L 09/30/14 1.3 100 ND dry ND ND ND ND ug/L 04/01/15 1.3 100 ND ND ND ND ND ND ug/L 09/30/15 1.3 100 ND ND ND ND 2.7 J ND ug/L 03/29/16 1.3 100 ND ND ND ND ND ND ug/L 09/28/16 1.3 100 ND --ND ND ND ND Notes:ug/L =micrograms per liter ND =Not detected at or above the laboratory method detection limit J =Estimated value B =Blank-qualified value -- =no data available / no flow dry = no sample collected because sampling point was drySW Standard =Surface Water Standard Bold =Concentrations above Human Health or Chronic Surface Water Standard Shaded and Bold =Concentration above Acute and Chronic Surface Water Standards Blanks =field, trip and method blanks SWS Reporting Limit =NC Solid Waste Section Limit 1) Surface Water Standards based on Class C Freshwater Aquatic Life or Human Health classification for the Little Branch in the Cape Fear basin per 15A NCAC 2B. 2) Results in parentheses () are from re-analysis. October 2016 Page 1 of 2 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx pH S.U.12/06/07 7.50 dry 7.33 dry 7.59 S.U.04/09/08 6.78 6.69 6.95 7.67 6.78 S.U.10/21/08 5.54 dry 5.39 dry 5.79 S.U.03/31/09 8.00 7.80 7.59 8.68 6.05 S.U.09/30/09 dry dry dry dry 6.16 S.U.03/31/10 6.21 6.70 6.47 7.94 8.97 S.U.10/06/10 6.93 dry 6.84 7.24 6.48 S.U.04/08/11 6.70 6.82 6.53 6.79 6.65 S.U.09/29/11 6.67 dry 6.38 7.00 6.10 S.U.03/29/12 6.75 6.97 6.90 6.94 7.23 S.U.09/27/12 9.56 dry 8.95 dry 4.85 S.U.04/02/13 8.83 8.87 8.70 9.20 5.62 S.U.09/26/13 7.67 dry 7.07 7.29 6.24 S.U.04/02/14 7.63 7.88 7.44 8.75 6.34 (Verification Event)S.U.05/15/14 --------6.12 S.U.09/30/14 7.43 dry 6.78 8.50 7.06 S.U.04/01/15 6.71 7.79 5.92 7.86 6.55 S.U.09/30/15 7.09 6.87 7.26 6.97 7.27 S.U.03/29/16 5.89 6.21 6.47 6.65 6.62 S.U.09/28/16 5.52 --6.11 6.69 6.32 Specific Conductance uS/cm 12/06/07 223 dry 251 dry 129 uS/cm 04/09/08 107 67 104 165 99 uS/cm 10/21/08 96 dry 59 dry 96 uS/cm 03/31/09 101 75 88 145 99 uS/cm 09/30/09 dry dry dry dry 98 uS/cm 03/31/10 98 69 106 167 118 uS/cm 10/06/10 94 dry 103 350 73 uS/cm 04/08/11 130 87 135 231 125 uS/cm 09/29/11 103 dry 109 228 85 uS/cm 03/29/12 100 84 106 209 117 uS/cm 09/27/12 82 dry 73 dry 98 uS/cm 04/02/13 108 105 111 195 103 uS/cm 09/26/13 106 dry 128 309 91 uS/cm 04/02/14 165 167 163 214 125 (Verification Event)uS/cm 05/15/14 --------184 uS/cm 09/30/14 195 dry 143 386 157 uS/cm 04/01/15 204 146 127 264 132 uS/cm 09/30/15 151 144 196 189 173 uS/cm 03/29/16 144.9 172.4 139 134.5 124.8 uS/cm 09/28/16 134 --158 278 117 Temperature Celsius 12/06/07 6.17 dry 5.84 dry 6.82 Celsius 04/09/08 17.96 20.33 17.21 17.88 18.00 Celsius 10/21/08 10.18 dry 11.78 dry 14.00 Celsius 03/31/09 13.22 11.76 15.49 12.52 13.30 Celsius 09/30/09 dry dry dry dry 18.70 Celsius 03/31/10 10.30 15.73 11.46 14.37 19.05 Celsius 10/06/10 12.80 dry 15.13 15.36 15.47 Celsius 04/08/11 13.26 14.14 13.99 14.39 14.81 Celsius 09/29/11 21.87 dry 20.47 19.78 24.70 Celsius 03/29/12 14.94 17.29 15.37 15.55 15.60 Celsius 09/27/12 16.53 dry 17.32 dry 17.42 Celsius 04/02/13 10.11 9.48 10.92 10.62 15.03 Celsius 09/26/13 17.3 dry 17.9 17.6 21.1 Celsius 04/02/14 10.3 10.6 10.6 10.8 15.9 (Verification Event)Celsius 05/15/14 --------21.0 Celsius 09/30/14 17.7 dry 18.8 17.8 19.3 Celsius 04/01/15 11.3 10.3 13.1 10.5 16.1 Celsius 09/30/15 22.25 21.19 22.40 22.30 23.60 Celsius 03/29/16 17.8 18.5 18.2 16.1 19.5 Celsius 09/28/16 22.4 --24.0 21.2 25.0 Detected Constituent (SW Standard) Reporting Units Sample Date TABLE 7 Summary of Surface Water Field Parameters Detected Constituents South Wake Landfill, Permit No. 92-22 Wake County, North Carolina Surface Water Monitoring Points SW-1 SW-2 SW-3 SW-4 SW-5 October 2016 Page 2 of 2 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent (SW Standard) Reporting Units Sample Date TABLE 7 Summary of Surface Water Field Parameters Detected Constituents South Wake Landfill, Permit No. 92-22 Wake County, North Carolina Surface Water Monitoring Points SW-1 SW-2 SW-3 SW-4 SW-5 Turbidity NTU 12/06/07 0 dry 127 dry 730 NTU 04/09/08 43.7 25.1 16.0 18.9 84.5 NTU 10/21/08 17.2 dry 262.0 dry 180 NTU 03/31/09 25.2 34.7 81.6 28.4 276 NTU 09/30/09 dry dry dry dry 92.6 NTU 03/31/10 16.2 53.5 23.4 24.8 35.3 NTU 10/06/10 6.99 dry 2.79 20.1 99.0 NTU 04/08/11 7.34 27.4 22.2 13.1 22.8 NTU 09/29/11 221 dry 165 38.1 76.0NTU03/29/12 11.0 30.4 18.9 19.4 60.6NTU09/27/12 40.4 dry 75.7 dry 64.6NTU04/02/13 17.2 63.0 20.5 28.3 40.9 NTU 09/26/13 16.9 dry 55.5 21.5 176 NTU 04/02/14 22.2 36.8 35.2 32.7 >1000 (Verification Event)NTU 05/15/14 --------39.6NTU09/30/14 113 dry 12.6 7.81 147NTU04/01/15 129 20.1 13.7 21.2 293 NTU 09/30/15 17.4 84.7 21.0 74.2 41.7 NTU 03/29/16 109 134 48.4 30.0 82.6NTU09/28/16 5.30 --15.2 12.3 33.2Oxidation Reduction Potential mV 12/06/07 213 dry 183 dry 176mV04/09/08 148.8 158.1 137.1 93.9 154.9 mV 10/21/08 112 dry 124 dry 114 mV 03/31/09 111.2 103.2 168.1 64.2 206.7 mV 09/30/09 dry dry dry dry 121.5mV03/31/10 185.9 60.2 148.3 3.4 -52.6mV10/06/10 164.6 dry 165.2 205.8 157.8 mV 04/08/11 116.1 120.5 106.2 145.9 67.0 mV 09/29/11 126.8 dry 140.6 138.9 64.8mV03/29/12 107.7 89.0 86.3 111.3 60.4mV09/27/12 44.8 dry 51.3 dry -55.4mV04/02/13 -8.6 -11.2 -4.7 -21.6 28.7 mV 09/26/13 57.3 dry 110.8 37.9 159.2 mV 04/02/14 89.0 121.0 53.6 43.2 129.6 (Verification Event)mV 05/15/14 --------172.0mV09/30/14 67.3 dry 141.7 77.9 148.6mV04/01/15 148.1 138.9 167.7 145.4 168.5 mV 09/30/15 -313.0 -423.8 -338.0 -333.7 -377.0 mV 03/29/16 137.7 314.0 172.3 314.3 409.9mV09/28/16 211.2 --177.6 235.2 172.2Dissolved Oxygen mg/L 12/06/07 10.81 dry 10.21 dry 9.14mg/L 04/09/08 9.45 9.11 9.16 9.44 6.88 mg/L 10/21/08 6.67 dry 4.14 dry 3.10 mg/L 03/31/09 10.66 11.20 7.87 11.52 6.81mg/L 09/30/09 dry dry dry dry 5.62mg/L 03/31/10 9.89 8.29 8.84 8.82 8.43mg/L 10/06/10 8.75 dry 9.31 8.83 7.71 mg/L 04/08/11 10.51 7.95 8.15 10.63 4.81 mg/L 09/29/11 7.98 dry 5.04 5.72 4.59mg/L 03/29/12 8.92 8.69 7.61 7.13 5.13mg/L 09/27/12 7.14 dry 6.85 dry 0.23mg/L 04/02/13 9.15 8.77 8.34 7.92 6.32 mg/L 09/26/13 6.84 dry 5.81 2.61 3.16 mg/L 04/02/14 10.36 8.58 9.79 10.48 9.67 (Verification Event)mg/L 05/15/14 --------0.83mg/L 09/30/14 10.83 dry 7.69 8.86 6.42mg/L 04/01/15 10.53 10.41 11.97 11.50 9.64 mg/L 09/30/15 6.62 1.00 6.01 6.23 3.70 mg/L 03/29/16 7.74 0.72 7.04 8.88 5.54mg/L 09/28/16 6.17 --6.94 5.23 5.63 Notes:mg/L =milligrams per liter S.U. =Standard Units NTU =Nephelometric Turbidity UnitsmS/cm =microsiemens per centimetermV =Millivolts-- =no data available / no flow dry = no sample collected because sampling point was dry October 2016 Page 1 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Antimony ug/L 04/10/08 6 0.73 J ND ug/L 10/06/08 6 2.00 J ND ug/L 04/06/09 6 0.89 J ND ug/L 10/05/09 6 3.45 J ND ug/L 04/05/10 6 9.23 J ND ug/L 10/04/10 6 ND ND ug/L 04/04/11 6 ND ND ug/L 09/29/11 6 ND ND ug/L 04/02/12 6 5.46 J ND ug/L 10/01/12 6 13.9 J ND ug/L 04/01/13 6 6.38 J 0.535 J ug/L 10/08/13 6 6.38 J ND ug/L 04/07/14 6 7.32 J ND ug/L 10/06/14 6 12.0 J ND ug/L 04/06/15 6 13.3 J ND ug/L 10/05/15 6 7.81 J 0.403 J ug/L 04/04/16 6 ND ND ug/L 10/03/16 6 9.07 J 0.388 J Arsenic ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 ND ND ug/L 04/06/09 10 3.8 J ND ug/L 10/05/09 10 4.46 J ND ug/L 04/05/10 10 2.81 J ND ug/L 10/04/10 10 ND 2.94 J ug/L 04/04/11 10 10.6 ND ug/L 09/29/11 10 4.98 J ND ug/L 04/02/12 10 3.98 J ND ug/L 10/01/12 10 31.3 ND ug/L 04/01/13 10 44.1 ND ug/L 10/08/13 10 32.2 J ND ug/L 04/07/14 10 ND ND ug/L 10/06/14 10 73.7 ND ug/L 04/06/15 10 47.4 J ND ug/L 10/05/15 10 47.6 ND ug/L 04/04/16 10 66.8 ND ug/L 10/03/16 10 104 ND Barium ug/L 04/10/08 100 200 ND ug/L 10/06/08 100 438 ND ug/L 04/06/09 100 69.2 J ND ug/L 10/05/09 100 103 ND ug/L 04/05/10 100 63.1 J ND ug/L 10/04/10 100 70.1 J ND ug/L 04/04/11 100 478 ND ug/L 09/29/11 100 374 ND ug/L 04/02/12 100 383 ND ug/L 10/01/12 100 358 ND ug/L 04/01/13 100 386 ND ug/L 10/08/13 100 279 ND ug/L 04/07/14 100 411 ND ug/L 10/06/14 100 411 ND ug/L 04/06/15 100 270 ND ug/L 10/05/15 100 330 ND ug/L 04/04/16 100 345 ND ug/L 10/03/16 100 368 ND Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 October 2016 Page 2 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Beryllium ug/L 04/10/08 1 ND ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 0.301 J ND ug/L 04/05/10 1 ND ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 ND ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 ND ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 ND ND Cadmium ug/L 04/10/08 1 ND ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 0.24 B 0.11 J ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 ND ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 ND ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 10/06/14 1 ND ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 ND ND Chromium ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 4.2 J ND ug/L 04/06/09 10 5.1 B 1.4 J ug/L 10/05/09 10 7.37 J ND ug/L 04/05/10 10 5.67 J ND ug/L 10/04/10 10 3.44 J ND ug/L 04/04/11 10 23.8 ND ug/L 09/29/11 10 13.9 ND ug/L 04/02/12 10 13.6 ND ug/L 10/01/12 10 132 ND ug/L 04/01/13 10 215 ND ug/L 10/08/13 10 69.5 ND ug/L 04/07/14 10 101 ND ug/L 10/06/14 10 229 ND ug/L 04/06/15 10 380 ND ug/L 10/05/15 10 138 ND ug/L 04/04/16 10 331 ND ug/L 10/03/16 10 224 ND October 2016 Page 3 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Cobalt ug/L 04/10/08 10 23.0 ND ug/L 10/06/08 10 15.2 ND ug/L 04/06/09 10 3.9 J ND ug/L 10/05/09 10 4.28 J ND ug/L 04/05/10 10 5.64 J ND ug/L 10/04/10 10 2.28 J ND ug/L 04/04/11 10 24.9 ND ug/L 09/29/11 10 13.5 ND ug/L 04/02/12 10 20.6 ND ug/L 10/01/12 10 29.8 ND ug/L 04/01/13 10 28.5 ND ug/L 10/08/13 10 20.2 J ND ug/L 04/07/14 10 30.8 J ND ug/L 10/06/14 10 28.9 J ND ug/L 04/06/15 10 74.9 ND ug/L 10/05/15 10 34.8 ND ug/L 04/04/16 10 66.3 ND ug/L 10/03/16 10 82.5 ND Copper ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 ND ND ug/L 04/06/09 10 ND ND ug/L 10/05/09 10 6.48 J ND ug/L 04/05/10 10 ND 3.07 J ug/L 10/04/10 10 ND ND ug/L 04/04/11 10 5.10 J ND ug/L 09/29/11 10 6.52 J ND ug/L 04/02/12 10 49.5 ND ug/L 10/01/12 10 65.8 ND ug/L 04/01/13 10 90.4 ND ug/L 10/08/13 10 80.8 ND ug/L 04/07/14 10 74.7 ND ug/L 10/06/14 10 51.4 ND ug/L 04/06/15 10 24.7 J 1.61 J ug/L 10/05/15 10 116 ND ug/L 04/04/16 10 13.9 J ND ug/L 10/03/16 10 105 ND Lead ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 12.7 ND ug/L 04/06/09 10 3.3 J ND ug/L 10/05/09 10 38.7 ND ug/L 04/05/10 10 ND ND ug/L 10/04/10 10 ND ND ug/L 04/04/11 10 5.99 J ND ug/L 09/29/11 10 6.32 J ND ug/L 04/02/12 10 ND ND ug/L 10/01/12 10 6.11 J ND ug/L 04/01/13 10 2.58 J ND ug/L 10/08/13 10 ND ND ug/L 04/07/14 10 10.5 J ND ug/L 10/06/14 10 ND ND ug/L 04/06/15 10 ND ND ug/L 10/05/15 10 7.05 J ND ug/L 04/04/16 10 ND ND ug/L 10/03/16 10 19.6 ND October 2016 Page 4 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Nickel ug/L 04/10/08 50 13.6 J ND ug/L 10/06/08 50 26.5 J ND ug/L 04/06/09 50 19.0 J ND ug/L 10/05/09 50 26.0 J ND ug/L 04/05/10 50 16.0 J ND ug/L 10/04/10 50 8.78 J ND ug/L 04/04/11 50 33.4 J ND ug/L 09/29/11 50 32.5 J ND ug/L 04/02/12 50 33.5 J ND ug/L 10/01/12 50 141 ND ug/L 04/01/13 50 166 ND ug/L 10/08/13 50 102 ND ug/L 04/07/14 50 135 ND ug/L 10/06/14 50 196 ND ug/L 04/06/15 50 395 ND ug/L 10/05/15 50 190 ND ug/L 04/04/16 50 315 ND ug/L 10/03/16 50 321 ND Silver ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 ND ND ug/L 04/06/09 10 2.1 J ND ug/L 10/05/09 10 ND ND ug/L 04/05/10 10 ND ND ug/L 10/04/10 10 ND ND ug/L 04/04/11 10 5.89 J ND ug/L 09/29/11 10 5.81 J ND ug/L 04/02/12 10 ND ND ug/L 10/01/12 10 3.13 J ND ug/L 04/01/13 10 ND ND ug/L 10/08/13 10 ND ND ug/L 04/07/14 10 ND ND ug/L 10/06/14 10 ND ND ug/L 04/06/15 10 ND ND ug/L 10/05/15 10 ND ND ug/L 04/04/16 10 ND ND ug/L 10/03/16 10 2.60 J ND Thallium ug/L 04/10/08 5.5 ND ND ug/L 10/06/08 5.5 ND ND ug/L 04/06/09 5.5 ND ND ug/L 10/05/09 5.5 2.63 B 0.837 J ug/L 04/05/10 5.5 ND ND ug/L 10/04/10 5.5 4.42 J ND ug/L 04/04/11 5.5 ND ND ug/L 09/29/11 5.5 ND ND ug/L 04/02/12 5.5 ND ND ug/L 10/01/12 5.5 ND ND ug/L 04/01/13 5.5 ND ND ug/L 10/08/13 5.5 ND ND ug/L 04/07/14 5.5 ND ND ug/L 10/06/14 5.5 ND ND ug/L 04/06/15 5.5 ND ND ug/L 10/05/15 5.5 ND ND ug/L 04/04/16 5.5 ND ND ug/L 10/03/16 5.5 ND ND October 2016 Page 5 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Vanadium ug/L 04/10/08 25 ND ND ug/L 10/06/08 25 ND ND ug/L 04/06/09 25 1.5 J ND ug/L 10/05/09 25 12.9 J ND ug/L 04/05/10 25 ND ND ug/L 10/04/10 25 ND ND ug/L 04/04/11 25 13.3 J ND ug/L 09/29/11 25 9.89 J ND ug/L 04/02/12 25 10.2 J ND ug/L 10/01/12 25 54.1 ND ug/L 04/01/13 25 31.6 ND ug/L 10/08/13 25 19.3 J ND ug/L 04/07/14 25 25.9 J ND ug/L 10/06/14 25 67.7 ND ug/L 04/06/15 25 49.4 J ND ug/L 10/05/15 25 59.1 ND ug/L 04/04/16 25 92.5 ND ug/L 10/03/16 25 73.1 ND Zinc ug/L 04/10/08 10 175 ND ug/L 10/06/08 10 749 ND ug/L 04/06/09 10 52.1 6.5 J ug/L 10/05/09 10 92.8 ND ug/L 04/05/10 10 71.0 ND ug/L 10/04/10 10 16.2 ND ug/L 04/04/11 10 332 ND ug/L 09/29/11 10 141 ND ug/L 04/02/12 10 467 ND ug/L 10/01/12 10 755 ND ug/L 04/01/13 10 999 ND ug/L 10/08/13 10 404 ND ug/L 04/07/14 10 506 ND ug/L 10/06/14 10 264 ND ug/L 04/06/15 10 3600 ND ug/L 10/05/15 10 777 ND ug/L 04/04/16 10 1030 ND ug/L 10/03/16 10 1690 ND Acetone ug/L 04/10/08 100 310 ND ug/L 10/06/08 100 6600 ND ug/L 04/06/09 100 5.8 J ND ug/L 10/05/09 100 ND ND ug/L 04/05/10 100 14 J ND ug/L 10/04/10 100 14 J ND ug/L 04/04/11 100 5400 ND ug/L 09/29/11 100 580 ND ug/L 04/02/12 100 1100 ND ug/L 10/01/12 100 9700 ND ug/L 04/01/13 100 11000 ND ug/L 10/08/13 100 12000 ND ug/L 04/07/14 100 3900 ND ug/L 10/06/14 100 2100 ND ug/L 04/06/15 100 24000 ND ug/L 10/05/15 100 9700 ND ug/L 04/04/16 100 1200 ND ug/L 10/03/16 100 11000 ND October 2016 Page 6 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Benzene ug/L 04/10/08 1 ND ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 ND ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 12 ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 5.0 J ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 7.3 J ND ug/L 10/03/16 1 ND ND Carbon disulfide ug/L 04/10/08 100 ND ND ug/L 10/06/08 100 ND ND ug/L 04/06/09 100 3.6 J ND ug/L 10/05/09 100 ND ND ug/L 04/05/10 100 ND ND ug/L 10/04/10 100 ND ND ug/L 04/04/11 100 ND ND ug/L 09/29/11 100 ND ND ug/L 04/02/12 100 ND ND ug/L 10/01/12 100 ND ND ug/L 04/01/13 100 ND ND ug/L 10/08/13 100 ND ND ug/L 04/07/14 100 ND ND ug/L 10/06/14 100 ND ND ug/L 04/06/15 100 ND ND ug/L 10/05/15 100 ND ND ug/L 04/04/16 100 ND ND ug/L 10/03/16 100 ND ND 1,2-Dichloroethane ug/L 04/10/08 1 ND ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 ND ND ug/L 10/04/10 1 1.8 ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 ND ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 ND ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 110 ND October 2016 Page 7 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Ethylbenzene ug/L 04/10/08 1 3.1 J ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 0.49 J ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 21 ND ug/L 04/02/12 1 15 ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 5.9 J ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 ND ND 2-Hexanone ug/L 04/10/08 50 ND ND ug/L 10/06/08 50 ND ND ug/L 04/06/09 50 ND ND ug/L 10/05/09 50 ND ND ug/L 04/05/10 50 ND ND ug/L 10/04/10 50 ND ND ug/L 04/04/11 50 ND ND ug/L 09/29/11 50 ND ND ug/L 04/02/12 50 ND ND ug/L 10/01/12 50 ND ND ug/L 04/01/13 50 ND ND ug/L 10/08/13 50 ND ND ug/L 04/07/14 50 ND ND ug/L 10/06/14 50 19 J ND ug/L 04/06/15 50 ND ND ug/L 10/05/15 50 ND ND ug/L 04/04/16 50 ND ND ug/L 10/03/16 50 ND ND Bromomethane ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 ND ND ug/L 04/06/09 10 27 ND ug/L 10/05/09 10 ND ND ug/L 04/05/10 10 24 ND ug/L 10/04/10 10 ND ND ug/L 04/04/11 10 ND ND ug/L 09/29/11 10 ND ND ug/L 04/02/12 10 ND ND ug/L 10/01/12 10 ND ND ug/L 04/01/13 10 ND ND ug/L 10/08/13 10 ND ND ug/L 04/07/14 10 ND ND ug/L 10/06/14 10 ND ND ug/L 04/06/15 10 ND ND ug/L 10/05/15 10 ND ND ug/L 04/04/16 10 ND ND ug/L 10/03/16 10 ND ND October 2016 Page 8 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Chloromethane ug/L 04/10/08 1 ND ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 20 ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 13 ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 ND ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 ND ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 ND ND Methylene chloride ug/L 04/10/08 1 30 ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 ND ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 ND ND ug/L 09/29/11 1 ND ND ug/L 04/02/12 1 ND ND ug/L 10/01/12 1 ND ND ug/L 04/01/13 1 ND ND ug/L 10/08/13 1 ND ND ug/L 04/07/14 1 ND ND ug/L 10/06/14 1 ND ND ug/L 04/06/15 1 ND ND ug/L 10/05/15 1 ND ND ug/L 04/04/16 1 ND ND ug/L 10/03/16 1 ND ND 2-Butanone ug/L 04/10/08 100 320 ND ug/L 10/06/08 100 11000 ND ug/L 04/06/09 100 ND ND ug/L 10/05/09 100 ND ND ug/L 04/05/10 100 16 J ND ug/L 10/04/10 100 ND ND ug/L 04/04/11 100 9600 ND ug/L 09/29/11 100 890 ND ug/L 04/02/12 100 1800 ND ug/L 10/01/12 100 16000 ND ug/L 04/01/13 100 18000 ND ug/L 10/08/13 100 15000 ND ug/L 04/07/14 100 6500 ND ug/L 10/06/14 100 1900 ND ug/L 04/06/15 100 22000 ND ug/L 10/05/15 100 13000 ND ug/L 04/04/16 100 1500 ND ug/L 10/03/16 100 20000 ND October 2016 Page 9 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Iodomethane ug/L 04/10/08 10 ND ND ug/L 10/06/08 10 ND ND ug/L 04/06/09 10 3.1 J ND ug/L 10/05/09 10 ND ND ug/L 04/05/10 10 14 ND ug/L 10/04/10 10 ND ND ug/L 04/04/11 10 ND ND ug/L 09/29/11 10 ND ND ug/L 04/02/12 10 ND ND ug/L 10/01/12 10 ND ND ug/L 04/01/13 10 ND ND ug/L 10/08/13 10 ND ND ug/L 04/07/14 10 ND ND ug/L 10/06/14 10 ND ND ug/L 04/06/15 10 ND ND ug/L 10/05/15 10 ND ND ug/L 04/04/16 10 ND ND ug/L 10/03/16 10 ND ND 4-Methyl-2-pentanone ug/L 04/10/08 100 11 J ND ug/L 10/06/08 100 ND ND ug/L 04/06/09 100 ND ND ug/L 10/05/09 100 ND ND ug/L 04/05/10 100 ND ND ug/L 10/04/10 100 ND ND ug/L 04/04/11 100 130 ND ug/L 09/29/11 100 ND ND ug/L 04/02/12 100 48 J ND ug/L 10/01/12 100 ND ND ug/L 04/01/13 100 180 ND ug/L 10/08/13 100 110 ND ug/L 04/07/14 100 77 J ND ug/L 10/06/14 100 ND ND ug/L 04/06/15 100 ND ND ug/L 10/05/15 100 90 J ND ug/L 04/04/16 100 31 J ND ug/L 10/03/16 100 ND ND Toluene ug/L 04/10/08 1 44 ND ug/L 10/06/08 1 ND ND ug/L 04/06/09 1 ND ND ug/L 10/05/09 1 ND ND ug/L 04/05/10 1 7.5 ND ug/L 10/04/10 1 ND ND ug/L 04/04/11 1 150 ND ug/L 09/29/11 1 19 ND ug/L 04/02/12 1 42 ND ug/L 10/01/12 1 54 ND ug/L 04/01/13 1 330 ND ug/L 10/08/13 1 290 ND ug/L 04/07/14 1 73 ND ug/L 10/06/14 1 24 ND ug/L 04/06/15 1 89 J ND ug/L 10/05/15 1 80 ND ug/L 04/04/16 1 60 ND ug/L 10/03/16 1 170 ND October 2016 Page 10 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Xylenes (Total)ug/L 04/10/08 5 12 ND ug/L 10/06/08 5 ND ND ug/L 04/06/09 5 ND ND ug/L 10/05/09 5 ND ND ug/L 04/05/10 5 0.73 J ND ug/L 10/04/10 5 ND ND ug/L 04/04/11 5 ND ND ug/L 09/29/11 5 38 ND ug/L 04/02/12 5 32 ND ug/L 10/01/12 5 23 ND ug/L 04/01/13 5 ND ND ug/L 10/08/13 5 ND ND ug/L 04/07/14 5 32 J ND ug/L 10/06/14 5 25 J ND ug/L 04/06/15 5 ND ND ug/L 10/05/15 5 ND ND ug/L 04/04/16 5 6.6 J ND ug/L 10/03/16 5 ND ND Nitrate mg/L 04/10/08 10 0.082 J ND mg/L 10/06/08 10 0.025 B 0.028 J mg/L 04/06/09 10 ND ND mg/L 10/05/09 10 64 ND mg/L 04/05/10 10 ND ND mg/L 10/04/10 10 0.88 J ND mg/L 04/04/11 10 0.12 J ND mg/L 09/29/11 10 0.076 J ND mg/L 04/02/12 10 0.220 J ND mg/L 10/01/12 10 0.047 J ND mg/L 04/01/13 10 ND ND mg/L 10/08/13 10 ND ND mg/L 04/07/14 10 0.049 J ND mg/L 10/06/14 10 0.064 J ND mg/L 04/06/15 10 0.092 J ND mg/L 10/05/15 10 ND ND mg/L 04/04/16 10 0.68 J ND mg/L 10/03/16 10 0.062 J ND Sulfate mg/L 04/10/08 250 20 J ND mg/L 10/06/08 250 68 J ND mg/L 04/06/09 250 46 J ND mg/L 10/05/09 250 16 J ND mg/L 04/05/10 250 21 J ND mg/L 10/04/10 250 12 J ND mg/L 04/04/11 250 2.4 J ND mg/L 09/29/11 250 8.7 J ND mg/L 04/02/12 250 1.8 J ND mg/L 10/01/12 250 3.7 J ND mg/L 04/01/13 250 3.4 J ND mg/L 10/08/13 250 ND ND mg/L 04/07/14 250 3.6 J ND mg/L 10/06/14 250 29 J ND mg/L 04/06/15 250 120 J ND mg/L 10/05/15 250 43 J ND mg/L 04/04/16 250 11 J ND mg/L 10/03/16 250 4.5 J ND October 2016 Page 11 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 Biochemical Oxygen Demand mg/L 04/10/08 -->180 ND mg/L 10/06/08 --1500 ND mg/L 04/06/09 --34 ND mg/L 10/05/09 --ND ND mg/L 04/05/10 --110 ND mg/L 10/04/10 --10 ND mg/L 04/04/11 --900 ND mg/L 09/29/11 --64 ND mg/L 04/02/12 --180 ND mg/L 10/01/12 --290 ND mg/L 04/01/13 --> 2200 ND mg/L 10/08/13 --1300 ND mg/L 04/07/14 --530 ND mg/L 10/06/14 --470 ND mg/L 04/06/15 -->7400 ND mg/L 10/05/15 --1100 ND mg/L 04/04/16 --450 ND mg/L 10/03/16 --2000 ND Chemical Oxygen Demand mg/L 04/10/08 --590 ND mg/L 10/06/08 --2100 ND mg/L 04/06/09 --74 ND mg/L 10/05/09 --78 ND mg/L 04/05/10 --120 ND mg/L 10/04/10 --64 ND mg/L 04/04/11 --1500 ND mg/L 09/29/11 --320 ND mg/L 04/02/12 --490 ND mg/L 10/01/12 --3000 ND mg/L 04/01/13 --8300 ND mg/L 10/08/13 --160 ND mg/L 04/07/14 --1800 ND mg/L 10/06/14 --3100 ND mg/L 04/06/15 --24000 ND mg/L 10/05/15 --6200 ND mg/L 04/04/16 --3600 ND mg/L 10/03/16 --4900 ND Phosphorus mg/L 04/10/08 --0.19 ND mg/L 10/06/08 --1.4 ND mg/L 04/06/09 --ND ND mg/L 10/05/09 --0.18 ND mg/L 04/05/10 --0.24 ND mg/L 10/04/10 --0.093 J ND mg/L 04/04/11 --0.77 ND mg/L 09/29/11 --0.6 ND mg/L 04/02/12 --0.5 ND mg/L 10/01/12 --3.1 ND mg/L 04/01/13 --4.1 ND mg/L 10/08/13 --1.8 ND mg/L 04/07/14 --1.6 ND mg/L 10/06/14 --3.7 ND mg/L 04/06/15 --6.6 ND mg/L 10/05/15 --4.2 ND mg/L 04/04/16 --7.1 ND mg/L 10/03/16 --0.39 ND October 2016 Page 12 of 12 Project No. 0739603916 G:\PROJECTS\Waste Industries\South Wake\Groundwater\GWMR\Sept 2016\Tables\South Wake Tables September 2016.xlsx Detected Constituent TABLE 8 Summary of Leachate Monitoring ResultsDetected ConstituentsSouth Wake Landfill, Permit No. 92-22Wake County, North Carolina Reporting Units Sample Date SWS Reporting Limit BlanksL-1 pH (field)S.U.04/10/08 --6.72 -- S.U.10/06/08 --7.42 -- S.U.04/06/09 --7.48 -- S.U.10/05/09 --7.54 -- S.U.04/05/10 --6.93 -- S.U.10/04/10 --7.90 -- S.U.04/04/11 --6.60 -- S.U.09/29/11 --6.81 -- S.U.04/02/12 --6.80 -- S.U.10/01/12 --7.67 -- S.U.04/01/13 --7.57 -- S.U.10/08/13 --7.31 -- S.U.04/07/14 --7.40 -- S.U.10/06/14 --7.90 -- S.U.04/06/15 --7.70 -- S.U.10/05/15 --7.58 -- S.U.04/04/16 --8.35 -- S.U.10/03/16 --7.54 -- Specific Conductance (field)uS/cm 04/10/08 --769 -- (lab through current date)uS/cm 10/06/08 --2300 -- uS/cm 04/06/09 --1400 -- uS/cm 10/14/09 --1300 -- uS/cm 04/05/10 --1700 -- uS/cm 10/04/10 --1000 -- uS/cm 04/04/11 --3900 -- uS/cm 09/29/11 --3600 -- uS/cm 04/02/12 --3400 -- uS/cm 10/01/12 --13000 -- uS/cm 04/01/13 --16000 -- uS/cm 10/08/13 --11000 -- uS/cm 04/07/14 --10000 -- uS/cm 10/06/14 --19000 -- uS/cm 04/06/15 --25000 -- uS/cm 10/05/15 --16000 -- uS/cm 04/04/16 --23000 -- uS/cm 10/03/16 --18000 -- Temperature (field)Celsius 04/10/08 --15.72 -- Celsius 10/06/08 --25.30 -- Celsius 04/06/09 --20.6 -- Celsius 10/05/09 --22.7 -- Celsius 04/05/10 --25.2 -- Celsius 10/04/10 --23.7 -- Celsius 04/04/11 --19.3 -- Celsius 09/29/11 --13.4 -- Celsius 04/02/12 --14.40 -- Celsius 10/01/12 --13.10 -- Celsius 04/01/13 --14.50 -- Celsius 10/08/13 --13.70 -- Celsius 04/07/14 --16.0 -- Celsius 10/06/14 --26.0 -- Celsius 04/06/15 --25.0 -- Celsius 10/05/15 --19.2 -- Celsius 04/04/16 --27.2 -- Celsius 10/03/16 --28.5 -- Notes: mg/L =milligrams per liter ug/L =micrograms per liter S.U. =Standard Units NTU =Nephelometric Turbidity Units ND =Not detected at or above the laboratory method detection limit mS/cm =microsiemens per centimeter mV =Millivolts J =Estimated value B =Blank-qualified value -- =no data available/not applicable 1.The following dilutions were noted for the September 2016 event: VOCs (100X), COD (10X), and antimony and thallium (10X) DRAWINGS WE 314.2' WE 315.1' 310 310 320 330 320 320 330 33034 0 3 4 0 3 3 0 330350 340350 360 3503503 40 340330320 330 330 340 340 310 330 340 320 320 31 0 350 360 370 380 390 400 410 420 350360330340350310 320 330 340310320 310320330350360370390400420430380410330340330440 440 420430350360370380390400340 350 330340340 350 350 36 0 350 360 370 340 350 360 370 330 340 340340330 340350 350 340330330350350350350 3 4 0350340350 340 330 340340330 340 350 32 0440420430360370380390400 32033034035036037038039040041043044042032 0 310300290320 350 420 330 340 360 370 380 390 400 410 430 310 300 290 3303403703803904103604004403504204303 1 0320 32 0 330330 320320 320WE 309.5' 310 320 330330 300 300 310 300 300 310320300300 290 300 300 300 310310 290 300 300 3002 9 0 290 310 300 300 WE 297.0' 327.2 320.8 325.8 333.1 319.0 319.5 325.8 357.5 327.8 337.0 332.5 339.4 316.6 330.8 329.8 323.6 339.2 357.0 356.7 352.6 354.5 345.8 321.1324.4 321.0 332.1 438.4 437.8 437.5 440.6 352.6 355.6 350.8 356.5 340.8 325.6 354.1 340.6 338.9 346.3 346.8 328.3 345.9 346.8 348.5 352.5 352.3 361.9 365.2 352.3 365.4 345.3 351.3 356.8 377.3 345.3 349.1 348.2 334.6 345.8 357.3 356.5 358.2 357.5 349.9 355.5 356.5 331.6 346.0 334.8 333.1 355.8 356.9 356.6 358.2 402.1 443.2 345.2 328.2 331.3 338.2 440.9 442.3 441.5 442.5 411.7 358.7 356.7 355.0 357.6 353.0 351.5 352.8 356.6 344.6 340.9 354.8 355.8 354.9 349.9 353.3 354.4 349.7 351.6 349.4351.2 339.0 346.8 331.1 330.7 334.9 338.7 441.3 331.9 320.2 298.4 296.4 298.3 296.8 313.1 314.1 314.6 320.3 303.2 299.8299.0 300.4 300.4 309.1 301.9 310.3 309.2 WE 302.6' 299.2 300.9 300.8 306.9 288.6 299.0 298.7 298.9 303.6 300.9 301.1 308.8 297.1 301.2 296.6 SCRUB SCRUB SCRUB 35 0340 3303 2 0 310300290 350 340 330 320 31 0 300 28 0 29028029030030 0 290 343.62 355.33 NA 311.34 275.07 273.54 i 1 i 3 i 2 PHASE IA PHASE IB MG-26 MW-5 MW-4 MW-3A MW-2A MW-2 MG-3 MW-1 MW-1A MW-7 MW-8 MW-8A MG-24 MG-2 MG-22 MG-21 SW-4 SW-2 TO APPROXIMATE LIMITS OF PHASE 1A SW-5 299.04 273.41 275.96 MW-3293.75 MG-1 TO TO SW-3 MG-25 SW-1 MG-23 MW-9280.12 LEACHATE TANK PHASE 2A PHASE 2B PHASE 3 PHASE 4A PHASE 4B PHASE 5A PHASE 5B 325.47 CONSULTANT DESIGN PREPARED REVIEW APPROVED YYYY-MM-DD TITLE PROJECT No.Rev. PROJECTCLIENT Path: \\greensboro\CAD\_2007\07396039 - WI - South Wake\PRODUCTION\_D - 2016 GW\ | File Name: 0739603915D002.dwgIF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI D01 in0739603916 PHASE 100 DRAWING 10 2016-05-03 BSD DYR DYR RPK SOUTH WAKE SOLID WASTE MANAGEMENT FACILITY PERMIT NO. 92-22 WAKE COUNTY, NORTH CAROLINA WASTE INDUSTRIES USA, INC. GROUNDWATER SURFACE CONTOUR MAP SEPTEMBER 28, 2016 LEGEND NOTES i 1 1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2.GROUNDWATER CONTOUR INTERVAL = 10 FEET 3.BASE MAP PROVIDED BY RICHARDSON SMITH GARDNER & ASSOCIATES. TOPOGRAPHY PROVIDED FROM AERIAL SURVEYS PREPARED BY SURVEYING SOLUTIONS P.C., PHOTOGRAPHY DATES JANUARY 2, 2015 AND JANUARY 28, 2014. 4.COORDINATE SYSTEM IS N.C. STATE PLANE (NAD 83 AND VERTICAL DATUM IS NAVD 88). 5.MONITORING WELL AND METHANE MONITORING PROBE LOCATIONS WERE SURVEYED BY SURVEY SOLUTIONS, P.C. OF RALEIGH, NORTH CAROLINA. 6.METHANE MONITORING LOCATIONS MG-21, MG-22, AND MG-23 ARE BAR HOLE PUNCH LOCATIONS. 7.GROUNDWATER ELEVATIONS MEASURED ON MARCH 29, 2016 WERE USED IN THE CONSTRUCTION OF THIS GROUNDWATER CONTOUR MAP. 8.GROUNDWATER WELLS MW-1A, MW-2A, MW-3A, MW-4A, AND MW-8A ARE DEEP AQUIFER WELLS AND WERE NOT USED IN THE CONSTRUCTION OF THIS GROUNDWATER CONTOUR MAP. 9.GW WELLS MW-1A, MW-2A, MW-3A, MW-8A ARE NO LONGER SAMPLED PER THE APPROVED MONITORING PLAN. SW-1 MG-1 MW-1 343.62 EXISTING 10-FOOT GROUND SURFACE CONTOUR EXISTING 2-FOOT GROUND SURFACE CONTOUR EXISTING ROADS APPROXIMATE PROPERTY LINE PROPOSED LIMITS OF WASTE POTENTIOMETRIC GROUNDWATER CONTOURS (10-FT. INTERVAL) GROUNDWATER FLOW SEGMENT MONITORING WELL AND GROUNDWATER ELEVATION METHANE MONITORING PROBE SURFACE WATER MONITORING POINT NO DATA AVAILABLE SITE LOCATION SITE LOCATION MAP (LOCATION IS APPROXIMATE) 0 FEET 200 400 SCALE GOLDER ASSOCIATES NC, INC. PG C-399 NA CONSULTANT DESIGN PREPARED REVIEW APPROVED YYYY-MM-DD TITLE PROJECT No.Rev. PROJECTCLIENT Path: \\greensboro\CAD\_2007\07396039 - WI - South Wake\PRODUCTION\_C - 2015 GW\ | File Name: 0739603915C003.dwgIF THIS MEASUREMENT DOES NOT MATCH WHAT IS SHOWN, THE SHEET SIZE HAS BEEN MODIFIED FROM: ANSI D01 in0739603915 PHASE 100 DRAWING 20 2015-11-24 BSD BSD DYR RPK SOUTH WAKE SOLID WASTE MANAGEMENT FACILITY PERMIT NO. 92-22 WAKE COUNTY, NORTH CAROLINA WASTE INDUSTRIES USA, INC. SURFACE WATER LOCATION MAP LEGEND NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2. GROUNDWATER CONTOUR INTERVAL = 10 FEET 3. BASE MAP PROVIDED BY RICHARDSON SMITH GARDNER & ASSOCIATES. TOPOGRAPHY PROVIDED FROM AERIAL SURVEYS PREPARED BY SURVEYING SOLUTIONS P.C., PHOTOGRAPHY DATES JANUARY 2, 2015 AND JANUARY 28, 2014. 4. COORDINATE SYSTEM IS N.C. STATE PLANE (NAD 83 AND VERTICAL DATUM IS NAVD 88). 5. AERIAL PHOTOGRAPHY OBTAINED FROM ESRI IMAGERY BASE LAYER. EXISTING 10-FOOT GROUND SURFACE CONTOUR EXISTING 2-FOOT GROUND SURFACE CONTOUR EXISTING ROADS APPROXIMATE PROPERTY LINE PROPOSED LIMITS OF WASTE SURFACE WATER MONITORING POINT SITE LOCATION SITE LOCATION MAP (LOCATION IS APPROXIMATE) 0 FEET 200 400 SCALE GOLDER ASSOCIATES NC, INC. PG C-399 PHASE 1B PHASE 1A PHASE 2A PHASE 2B PHASE 3 PHASE 4A PHASE 4B PHASE 5B PHASE 5A SW-1 SW-3 SW-5 SW-4 SW-2 CLOSED FELTONSVILLE LANDFILL SOUTH WAKE LANDFILL NC HIGHWAY 55SW-1 APPENDIX A GROUNDWATER AND SURFACE WATER SAMPLING LOGS APPENDIX B SEPTEMBER 2016 CERTIFICATES-OF-ANALYSIS, CHAIN-OF-CUSTODY FORMS AND LABORATORY DATA REVIEWS Page 1 of 64 Page 2 of 64 Page 3 of 64 Page 4 of 64 Page 5 of 64 Page 6 of 64 Page 7 of 64 Page 8 of 64 Page 9 of 64 Page 10 of 64 Page 11 of 64 Page 12 of 64 Page 13 of 64 Page 14 of 64 Page 15 of 64 Page 16 of 64 Page 17 of 64 Page 18 of 64 Page 19 of 64 Page 20 of 64 Page 21 of 64 Page 22 of 64 Page 23 of 64 Page 24 of 64 Page 25 of 64 Page 26 of 64 Page 27 of 64 Page 28 of 64 Page 29 of 64 Page 30 of 64 Page 31 of 64 Page 32 of 64 Page 33 of 64 Page 34 of 64 Page 35 of 64 Page 36 of 64 Page 37 of 64 Page 38 of 64 Page 39 of 64 Page 40 of 64 Page 41 of 64 Page 42 of 64 Page 43 of 64 Page 44 of 64 Page 45 of 64 Page 46 of 64 Page 47 of 64 Page 48 of 64 Page 49 of 64 Page 50 of 64 Page 51 of 64 Page 52 of 64 Page 53 of 64 Page 54 of 64 Page 55 of 64 Page 56 of 64 Page 57 of 64 Page 58 of 64 Page 59 of 64 Page 60 of 64 Page 61 of 64 Page 62 of 64 Page 63 of 64 Page 64 of 64 Page 1 of 1 GOLDER TMSOCIATES INC. QUALITY TMSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 4 Project Name: WI – South Wake LF Project Reference Number: 0739-603916.100 Sampling Event Date: September 28, 2016 Review Date: October 21, 2016 Initials: RK Report #: CZ13507 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility List (.500 Rules) NC C & D List (New Rules) X NC Appendix I NC Appendix I + Detects NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW TM COC was properly signed by all parties. TM Correct project name and number are on the form. TM Sample receipt condition at laboratory was acceptable. TM Each sample and blank submitted for analysis appears in the report. GOLDER TMSOCIATES INC. QUALITY TMSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 4 2.0 SAMPLE HOLDING TIMES TM Holding times for extraction and/or analysis were met for each analytical Method (see below for reference). Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW TM Laboratory analyzed at least one internal blank for each method, where applicable. TM Laboratory blank is interference-free.  Lab Blank: Barium @ 1.74 ug/L (J) TM Surrogate recoveries are provided for each analytical method, where applicable. TM Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). TM MS/MSD/LCS data results are provided for each analytical method. TM MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range).  The initial standard recovery in the 6020B analysis for Antimony was outside of control limits due to matrix interference. The sample was reanalyzed at a dilution, resulting in elevated reporting limits. 4.0 ANALYTE LISTS/METHODS TM The proper number of constituents are present for each analyte list as identified above (including detects where applicable). TM Proper EPA SW-846 analytical methods were used for analysis. GOLDER TMSOCIATES INC. QUALITY TMSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 4 5.0 DATA REPORTING TM All analytical reporting associated with the event was performed by the contracted lab. TM Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below.  Field Blank – Copper @ 4.51 ug/L (J) o B-Flags needed: MW-1, -2, -3, -4, -5, -7, -8, -9, SW-1, -3, -4, and -5 TM It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor.  Antimony was diluted by 5X for MW-1 TM The report provides the reporting limit for each constituent. TM The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. TM No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points.  Arsenic (NC 2L = 10 ug/L) (EPA MCL = 10 ug/L ) (SWSL = 10 ug/L) o MW-1 @ 14.1 ug/L  Barium (NC 2L = 700 ug/L) (EPA MCL = 2000 ug/L) (SWSL = 100 ug/L) o MW-1 @ 3250 ug/L o MW-7 @ 104 ug/L o MW-8 @ 171 ug/L o MW-9 @ 127 ug/L  Chromium (NC 2L = 10ug/L) (SWSL = 10 ug/L) o MW-1 @ 108 ug/L o MW-2 @ 10.6 ug/L  Cobalt (GWPS = 1 ug/L) (SWSL = 10 ug/L) o MW-2 @ 1.24 ug/L (J) o MW-5 @ 2.49 ug/L (J) o MW-9 @ 1.76 ug/L (J) GOLDER TMSOCIATES INC. QUALITY TMSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 4 of 4  Copper (NC 2L = 1000 ug/L) (EPA MCL = 1300 ug/L) (SWSL = 10 ug/L) o MW-2 @ 10.1 ug/L o SW-1 @ 3.66 ug/L (J) o SW-4 @ 3.67 ug/L (J) o SW-5 @ 3.61 ug/L (J) o ***all values B-flagged  Nickel (NC 2L = 100 ug/L) (SWSL = 50 ug/L) o MW-1 @ 74.5 ug/L  Vanadium (NC 2L = 0.3 ug/L) (SWSL = 25 ug/L) o MW-2 @ 3.43 ug/L (J) o MW-5 @ 1.73 ug/L (J) o MW-9 @ 4.86 ug/L (J)  Zinc (SWS GPS = 5000 ug/L) (SWSL = 10 ug/L) o MW-4 @ 16.0 ug/L o MW-5 @ 12.9 ug/L o MW-7 @ 18.9 ug/L o MW-9 @ 13.3 ug/L TM No inorganic or organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: Page 1 of 24 Page 2 of 24 Page 3 of 24 Page 4 of 24 Page 5 of 24 Page 6 of 24 Page 7 of 24 Page 8 of 24 Page 9 of 24 Page 10 of 24 Page 11 of 24 Page 12 of 24 Page 13 of 24 Page 14 of 24 Page 15 of 24 Page 16 of 24 Page 17 of 24 Page 18 of 24 Page 19 of 24 Page 20 of 24 Page 21 of 24 Page 22 of 24 Page 23 of 24 Page 24 of 24 Page 1 of 1 GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: WI – South Wake LF (Leachate) Project Reference Number: 0739-603916 Sampling Event Date: September 28, 2016 Review Date: October 21, 2016 Initials:RK Report #: CZ14764 Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain-of-custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi-Media, Multi-Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility List (.500 Rules) NC C & D List (New Rules) __GA__ GA Appendix I NC Appendix I + Detects NC Appendix II _ NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW RK COC was properly signed by all parties. RK Correct project name and number are on the form.  Project number not present on form RK Sample receipt condition at laboratory was acceptable. RK Each sample and blank submitted for analysis appears in the report.  Leachate Effluent, Leachate Effluent (Grab), and the Low Level Mercury Blank sampled per POTW permit and not included in lab report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES RK Holding times for extraction and/or analysis were met for each analytical method (see below for reference). Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW RK Laboratory analyzed at least one internal blank for each method, where applicable. RK Laboratory blank is interference-free. Antimony in lab blank at 0.388 J ug/L RK Surrogate recoveries are provided for each analytical method, where applicable. RK Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). RK MS/MSD/LCS data results are provided for each analytical method. RK MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range).  The spike recoveries of nitrite, total Pphosphorous and sulfate were outside of control limits for the MS and/or MSD samples. The QC batches were approved based on acceptable LCS recovery of these analytes. 4.0 ANALYTE LISTS/METHODS RK The proper number of constituents are present for each analyte list as identified above (including detects where applicable). GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 3 RK Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING RK All analytical reporting associated with the event was performed by the contracted lab. RK Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been ‘flagged’ with a ‘B’ where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants-acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. RK It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor.  The 6020A analysis of antimony and thallium were processed at a dilution due to matrix interference resulting in elevated reporting limits.  Influent Leachate: o Antimony and thallium 10x o COD 10X o VOCs 100x RK The report provides the reporting limit for each constituent. RK The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. N/A No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. N/A No inorganic or organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). TM Other report issues/Communications with laboratory/etc.: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, NC 27407 USA (336) 852-4903 - Phone (336) 852-4904 - Fax