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HomeMy WebLinkAbout9701_WilkesCounty_MSWLF_WQMR_20170807 2211 W. Meadowview Road, Suite 101 Greensboro, NC 27407 tel: 336/ 323-0092 fax: 336/ 323-0093 www.JoyceEngineering.com August 7, 2017 Mr. Ervin Lane Compliance Hydrogeologist Division of Waste Management/Solid Waste Section 1646 Mail Service Center Raleigh, NC 27699-1646 RE: First Semiannual Water Quality Monitoring Reports of 2017 Wilkes County Landfills: Germantown Landfill, Permit No. 97-01 JOYCE Project No. 356.1701.12, Task No. 05 Dear Ervin: On behalf of Wilkes County, Joyce Engineering is submitting the First Semiannual Water Quality Monitoring Report of 2017 for the Wilkes County Germantown Landfill, Permit No. 97-01. The attached report contains electronic versions of the complete report and all appendices for the April 2017 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the April 2017 monitoring event. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me or Gretta Eller at (336) 323-0092 if you have any questions regarding this report. Sincerely, JOYCE ENGINEERING Hannu Kemppinen P.G. Senior Project Consultant Enclosures C: Kent Brandon - Wilkes County, Solid Waste Director (2 copies) PREPARED FOR: WILKES COUNTY DEPARTMENT OF SOLID WASTE 9219 ELKIN HIGHWAY ROARING RIVER, NORTH CAROLINA 27298 GERMANTOWN LANDFILL PERMIT NO. 97-01 FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2017 AUGUST 2017 PREPARED BY: 2211 WEST MEADOWVIEW ROAD, SUITE 101 GREENSBORO, NORTH CAROLINA 27407 NC LICENSE NUMBER C-0782 PHONE: (336) 323-0092 FAX: (336) 323-0093 JOYCE PROJECT NO. 00356.1701.12 ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 i First Semiannual Water Quality Monitoring Report of 2017 Germantown Landfill Wilkes County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information ....................................................................................................................1 1.2 Site Geology ...........................................................................................................................1 1.3 Regulatory Status ..................................................................................................................1 2.0 FACILITY MONITORING PROGRAM ..........................................................................1 2.1 Groundwater Monitoring Program ....................................................................................1 2.2 Surface Water Monitoring Program ...................................................................................2 3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017 ...................................................2 3.1 Field Work and Visual Inspection .......................................................................................2 3.2 Laboratory Analysis and JOYCE Quality Control ...........................................................3 4.0 DATA ANALYSIS ................................................................................................................4 4.1 Groundwater Data Analysis and Comparisons to Standards ..........................................4 4.2 Surface Water Data Analysis and Comparisons to Standards .........................................5 5.0 CONCLUSION .....................................................................................................................5 6.0 REFERENCES ......................................................................................................................5 Tables Table 1 Summary of Historical Detected Constituents Table 2 Summary of Historical Groundwater Elevations Figure Figure No. 1 Site Location Map Drawing Drawing No. 1 Groundwater Surface Map Appendices Appendix 1 Laboratory Analytical Reports and Field Data Logs Appendix 2 Summary of Detections, Exceedances, and Field Parameters Appendix 3 Horizontal Groundwater Flow Velocities ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 1 1.0 INTRODUCTION 1.1 Site Information The Germantown Landfill is a closed, unlined municipal solid waste (MSW) landfill owned by Wilkes County. The landfill property is located near the town of Wilkesboro, North Carolina. The property boundary is indicated on an excerpt from the 7.5 minutes USGS topographic map for Moravian Falls, North Carolina (Figure No. 1.). The closed landfill currently houses the Wilkes County Fire Marshal and training grounds. The area surrounding the landfill is primarily residential/agricultural and contains open fields and woodlands. 1.2 Site Geology The Germantown Landfill is located at the boundary of the Inner Piedmont Belt and Blue Ridge Belt in the Brevard Fault Zone. In the vicinity of the site, the Brevard Zone is a five-mile wide, east-northeast trending fault zone with a complex structural and metamorphic history. Finely interlayered gneiss and schist within the zone are amphibolite facies, with peak metamorphism as high as the kyanite zone for pelitic assemblages. 1.3 Regulatory Status Wilkes County is currently monitoring groundwater at the Germantown Landfill in accordance with criteria set forth in Rule .0500 of the North Carolina Solid Waste Management Rules (NCSWMR) for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater compliance monitoring network includes five monitoring wells, including one upgradient well and four downgradient wells. These wells are summarized below, along with their current monitoring program status. TOC = Top of casing. Monitoring Well Classification Monitoring Program Total Depth from TOC (ft) MW-1 Background Detection (.0500) 89.69 MW-2 Compliance Detection (.0500) 81.54 MW-3 Compliance Detection (.0500) 64.00 MW-4 Compliance Detection (.0500) 28.21 MW-5 Compliance Detection (.0500) 23.47 ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 2 Groundwater samples are collected semiannually during the second and fourth quarters. Samples are analyzed for all constituents listed in the NCSWMR Appendix I during the first and second semiannual events. 2.2 Surface Water Monitoring Program Surface water at the Germantown Landfill is monitored semiannually in accordance with NCSWMR §0602 and in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (Upstream, Downstream and Outfall #1). Surface water samples are collected and analyzed for the NCSWMR Appendix I list of constituents during both semiannual monitoring events. The results are compared to the 15A NCAC 2B (NC 2B) Surface Water Standards in a value-to-value comparison. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Point Classification Monitoring Program Upstream Up Stream/Compliance Surface Water Downstream Compliance Surface Water Outfall #1 Compliance Surface Water 3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017 3.1 Field Work and Visual Inspection In order to detect potential releases of leachate and/or landfill gas migration in a timely manner, a visual inspection program has been implemented at the Germantown Landfill. This inspection program involves field personnel making the following observations:  Observation of stress induced on the biological community (i.e., dead or dying vegetation),  Indications of leachate impact (i.e., seeps, impacted surface water),  Observations of erosion; and  Negative changes around the waste facility. On April 18, 2017, Joyce Engineering (JOYCE) personnel purged and sampled facility monitoring wells MW-1, MW-2, MW-3, MW-4 and MW-5. Prior to purging, the depth to static water level was measured for all monitoring wells with an electronic water level indicator, accurate to 0.01 foot. Monitoring wells were purged and sampled using either disposable bailers or a 12 volt plastic pump. Measurements of temperature, pH, specific conductivity, and turbidity were recorded in ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 3 the site specific log book prior to purging, after each purge volume, and during sampling. Prior to sampling, laboratory-supplied containers were prepared with the following information:  Monitoring well number (completed by field personnel),  Date and time of sample collection (completed by field personnel),  Initials of sampling personnel (completed by field personnel),  Project name and number (completed by the laboratory),  Chemical preservative (completed by the laboratory); and  Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected directly from the disposable bailers or 12 volt pump in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix to this report. Surface water samples were collected directly from stream flow by lowering the prepared sample containers into the stream flow with the opening facing into the current. There was no running water from Outfall #1 therefore; Outfall #1 was not sampled. Care was taken not to overfill the sample containers (which could lead to preservative loss) and to avoid sampling-induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, and turbidity. After sample collection, the samples were placed in a laboratory provided cooler and chilled on ice. Field data logs are provided in the Appendix. 3.2 Laboratory Analysis and JOYCE Quality Control The April 2017 groundwater and surface water samples were submitted to Pace Analytical Laboratories, Inc. of Huntersville, North Carolina under chain-of-custody control for analysis. As presented earlier, the groundwater and surface water samples were analyzed for the NCSWMR Appendix I constituents. JOYCE requested a Level II data report for the final laboratory report. The samples were received by the laboratory on April 19, 2017, in good condition, properly preserved, and within analysis hold times. In addition to samples collected for compliance monitoring at the Germantown Landfill, a Field Blank was collected by JOYCE personnel as part of the April 2017 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The April 2017 Field Blank was analyzed for the NCSWMR Appendix I constituents while the April 2017 Trip Blank was analyzed for the NCSWMR Appendix I volatile organics only. ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 4 Upon receipt of the laboratory data package, the data was reviewed by JOYCE personnel for the following:  General typographical errors,  Correct analyses performed and within method specified hold times,  Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples,  Blank qualified data (B-flags),  Detections above the groundwater and surface water standards; and  Detections that are above historical levels. 4.0 DATA ANALYSIS 4.1 Groundwater Data Analysis and Comparisons to Standards Results from the April 2017 sampling event were received May 2, 2017 from Pace Analytical Laboratories, Inc. and are found in the Appendix. Analytical results from monitoring wells were compared directly to the NC2L Groundwater Standards (NC2L) or Groundwater Protection Standards (GWPS). The following inorganic and organic constituents were detected at quantified concentrations in groundwater during the April 2017 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations with a “J” are considered to be estimated. Concentrations with a “B” are attributed to lab or field contamination. Bold concentrations were detected above the NC2L or GWPS in downgradient wells. Constituent NC2L/ (GWPS) Background Downgradient Blanks MW-1 MW-2 MW-3 MW-4 MW-5 Barium 700 101 9.9 J 9.2 J 85.4 J 412 ND Cobalt (1) ND ND ND 13.3 15.4 ND Vanadium 0.3 ND ND ND 7.6 J 16.5 J ND Zinc 1000 ND 5.6 J ND ND 14.7 ND Benzene 1 ND ND ND 0.35 J 1.1 ND Chlorobenzene 50 ND ND ND 4.9 9.9 ND 1,4-Dichlorobenzene 6 0.35 J ND ND 2.2 3.9 ND ND= Not Detected In general, the organic and inorganic results are consistent with historical data. Historical groundwater data can be found in Table 1. 4.2 Surface Water Data Analysis and Comparisons to Standards ______________________________________________________________________________ First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering Germantown Landfill, Permit No. 97-01 August 2017 5 No inorganic and organic constituents were detected at quantified concentrations in surface water during the April 2017 sampling event. In general, the results are consistent with historical data. Historical surface water data can be found in Table 1. 5.0 CONCLUSION Based on historical data, inorganic and organic constituents detected above the NC SWSL in groundwater and surface water samples collected during the April 2017 sampling event are generally consistent with previous events. The Germantown Landfill will remain in Detection Monitoring under Rule .0500 of the NCSWMR and the next semiannual sampling event is tentatively scheduled for the October 2017. 6.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Fetter, C.W., 2001, Applied Hydrogeology, Fourth Edition: Prentice-Hall, Inc.. Johnson, A.I., 1967, Specific Yield - Compilation of Specific Yields For Various Materials: U.S. Geological Survey Water Supply Paper 1662-D. North Carolina Department of Environment and Natural Resources, 1990-2011, Solid Waste Management Regulations. USEPA, 1986, RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). USEPA, 1992, Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance, Chapter 2, July. Tables TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks INORGANICS Antimony 28-Nov-07 1.2 6.0 ND ND 3.1 J ND (2.8 J)ND ND ND 1.7 J ---ND GWPS = 1.4 µg/L (10/23/07)21-Apr-08 1.2 6.0 1.2 B ND 1.2 B ND (ND)ND 4.1 B ND 1.9 B ---1.3 J NC 2B = NE (05/01/07)22-Dec-08 1.2 6.0 ND 1.3 J 3.7 (ND)J ND ND ND 1.5 J ND ---ND 23-Jun-09 1.2 6.0 5.9 J 2.3 (5.3 J)J ND ND ND 2.5 J 2.9 J 3.6 J ---ND 15-Dec-09 1.2 6.0 ND 2.3 B 3.9 B ND (3.4 B)1.8 B 2.2 B ND 4.6 B ---3.5 J 28-Jun-10 1.2 6.0 ND 2.0 B 2.5 B ND 1.2 (ND) B 6.6 B ND ND ---2.2 J GWPS = 1 µg/L (8/1/10)02-Nov-10 1.2 6.0 ND ND 2.4 (ND)J 3.5 J 3.1 J ND 2.5 J ND ---ND 12-Apr-11 2.6 6.0 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 5.0 6.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 5.0 6.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 5.0 6.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 6.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 5.0 6.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.0 6.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 5.0 6.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 3.8 6.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 3.8 6.0 ND ND ND 4.2 J ND ND ND ND ---ND 21-Apr-16 0.069 6.0 ND 0.23 J 0.61 J 0.31 J 0.25 J 0.12 J 0.10 J ------ND 11-Oct-16 3.8 6.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 3.9 6.0 ND ND ND ND ND ND ND ------ND Arsenic 19-Jun-07 5.5 10.0 ND ND 8.2 J ND ND (ND)7.7 J ND ND ---ND NC 2L = 50 µg/L (10/23/07)28-Nov-07 5.5 10.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = 50 µg/L (05/01/07)21-Apr-08 5.5 10.0 ND ND ND ND (ND)ND ND ND ND ---ND 22-Dec-08 5.5 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 23-Jun-09 5.5 10.0 ND 6.3 (ND)J ND ND ND ND ND ND ---ND 15-Dec-09 5.5 10.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2L = 10 µg/L (01/01/10)28-Jun-10 5.5 10.0 ND 6.1 J ND ND ND (ND)ND ND ND ---ND 02-Nov-10 5.5 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 2.7 10.0 ND ND ND ND 6.9 J ND ND ND ---ND 18-Oct-11 5.0 10.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 10.0 ND ND ND ND 7.8 J ND ND ND ---ND 08-Oct-13 5.0 10.0 ND ND ND 5.3 J ND ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 2.5 10.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 2.5 10.0 ND ND ND ND 4.3 J ND ND 2.8 J ---ND 21-Apr-16 0.29 10.0 0.76 J ND ND 0.62 J 2.5 J ND ND ------ND 11-Oct-16 2.5 10.0 ND ND ND 3.5 J 3.8 J ND ND ------ND 18-Apr-17 5.0 10.0 ND ND ND ND ND ND ND ------ND Barium Apr-93 ---10 177 220 159 ND 121 ND 166 5600 799 --- Sep-93 ---250 ND 1940 ND ND ND ND ND --------- Apr-94 ---250 ND ND ND ND ND ND ND ND ND --- Oct-94 ---500 ND ND ND ND ND ND ND ND 567 --- Apr-95 ---500 ND ND ND ND ND ND ND ND ------ Nov-95 ---500 ND ND ND ND ND ND ND ND ------ May-96 ---500 ND ND ND ND ND ND ND ND ------ Nov-96 ---500 ND ND ND ND 1040 ND ND ND ---ND Mar-97 ---500 ND ND ND ND 531 ND ND ND ---ND Sep-97 ---500 ND ND ND ND ND ND ND ND ---ND Mar-98 ---500 ND ND ND ND 520 ND ND ND ---ND Sep-98 ---500 ND ND ND ND ND ND ND ND ---ND Mar-99 ---500 ND ND ND ND ND ND ND ND ---ND Sep-99 ---500 ND ND ND ND 549 ND ND ND ---ND May-00 ---500 ND ND ND ND ND ND ND ND ---ND Oct-00 ---500 ND ND ND ND 507 ND ND ND ---ND Mar-01 ---500 ND ND ND ND ND ND ND ND ---ND Oct-01 ---500 ND ND ND ND 566 ND ND ND ---ND Apr-02 ---500 ND ND ND ND ND ND ND ND ---ND Nov-02 ---500 ND ND ND ND 500 ND ND ND ---ND May-03 ---500 ND ND ND ND ND ND ND ND ---ND Nov-03 ---500 ND ND ND ND ND(517)ND ND ND ---ND Apr-04 ---500 ND ND ND ND ND ND ND ND ---ND Oct-04 ---500 ND ND ND ND ND ND ND ND ---ND May-05 ---500 ND ND ND ND ND ND ND ND ---ND Oct-05 ---500 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---500 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---500 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 1.1 100 94.9 J 13.3 B 12.2 B 82.3 J 520 (462)23.6 B 23.1 B 364 ---13.5 J NC 2L = 2,000 µg/L (10/23/07)28-Nov-07 1.1 100 380 43.5 J 10.9 B 128 (109)458 19.7 J 34.7 J 151 ---2.51 J NC 2B = NE (05/01/07)21-Apr-08 1.1 100 101 20.4 B 12.1 B 90.0 (98 J)J 417 19.5 B 27.9 B 177 ---9.7 J 22-Dec-08 1.1 100 95.0 J 9.1 J 8.5 (16.6 J)J 77.6 J 414 20.0 J 21.3 J 132 ---1.6 J 23-Jun-09 1.1 100 168 4.8 (6.1 B)B 13.1 B 65.4 B 440 19.8 B 19.5 B 294 ---8.5 J 15-Dec-09 1.1 100 168 7.6 B 18.1 B 68.6 (64.6 B)B 400 22.2 B 19.7 B 138 ---18.2 J NC 2L = 700 µg/L (01/01/10)28-Jun-10 1.1 100 81.1 J 4.6 B 7.5 B 45.6 J 325 (362)18.1 19.6 234 ---2.0 J 02-Nov-10 1.1 100 157 6.2 B 9.1 (9.2 B)B 51.0 B 318 17.7 B 23.8 B 170 ---10.9 J 12-Apr-11 0.20 100 106 9.6 B 16.2 B 79.4 J 433 19.3 B 18.2 B 39.8 B ---13.2 J 18-Oct-11 5.0 100 133 11.5 J 9.4 J 113 517 19.6 J 20.4 J ------ND 10-Apr-12 5.0 100 122 9.1 B 8.7 B 94.1 J 328 17.6 B 17.2 B ------15.8 J 15-Oct-12 5.0 100 123 5.3 J 8.8 J 72.9 J 359 25.4 J 19.9 J ------ND 16-Apr-13 5.0 100 168 6.6 J 8.0 J 51.9 372 17.6 J 17.6 J 306 ---ND 08-Oct-13 5.0 100 122 5.8 J 8.2 J 71.6 J 393 21.8 J 23.0 J ------ND 29-Apr-14 5.0 100 92.0 J 5.3 J 7.7 J 60.1 J 415 25.4 J 27.3 J ------ND 14-Oct-14 5.0 100 111 6.9 J 8.6 J 82.0 J 377 20.4 J 19.9 J ------ND 09-Apr-15 2.5 100 128 8.0 J 8.6 J 70.6 J 327 18.3 J 54.7 J ------ND 27-Oct-15 2.5 100 116 11.3 J 8.2 J 84.8 J 325 25.3 J 30.0 J 132 ---ND 21-Apr-16 0.041 100 97 J 7.5 J 8.2 J 67 J 360 16 J 18 J ------0.65 J 11-Oct-16 2.5 100 90.1 J 13.5 J 8.6 J 154 395 18.6 J 18.8 J ------ND 18-Apr-17 2.5 100 101 9.9 J 9.2 J 85.4 J 412 18.8 J 17.7 J ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 1 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Beryllium May-96 ---2 3 6 4 4 4 4 4 5 ------ Nov-96 ---2 ND ND ND ND 6 ND ND ND ---ND Mar-97 ---2 ND ND ND 2 4 ND ND ND ---ND Sep-97 ---2 ND ND ND ND ND ND ND ND ---ND Mar-98 ---2 ND ND 6 ND 13 ND ND ND ---ND Sep-98 ---2 ND ND ND 2 8 ND ND 7 ---ND Mar-99 ---2 ND ND ND 3 9 ND ND ND ---ND Sep-99 ---2 ND ND ND ND ND ND ND ND ---ND May-00 ---2 ND ND ND ND ND ND ND ND ---ND Oct-00 ---2 ND ND ND ND ND ND ND ND ---ND Mar-01 ---2 ND ND ND ND ND ND ND ND ---ND Oct-01 ---2 ND ND ND ND ND ND ND ND ---ND Apr-02 ---2 ND ND ND ND ND ND ND ND ---ND Nov-02 ---2 ND ND ND ND ND ND ND ND ---ND May-03 ---2 ND ND ND ND ND ND ND ND ---ND Nov-03 ---2 ND ND ND ND ND ND ND ND ---ND Apr-04 ---2 ND ND ND ND ND ND ND ND ---ND Oct-04 ---2 ND ND ND ND ND ND ND ND ---ND May-05 ---2 ND ND ND ND ND ND ND ND ---ND Oct-05 ---2 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---2 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---2 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.2 1.0 ND ND ND ND ND (ND)ND ND ND ---ND GWPS = 4 µg/L (10/23/07)28-Nov-07 0.2 1.0 ND ND 0.6 B ND (0.21 B)ND ND ND ND ---0.2 J NC 2B = 6.5 µg/L (05/01/07)21-Apr-08 0.2 1.0 0.3 J ND 0.2 J 0.4 (ND)J 0.2 J ND ND ND ---ND 22-Dec-08 0.2 1.0 ND 0.8 J ND (ND)ND ND ND ND ND ---ND 23-Jun-09 0.2 1.0 ND ND (ND)ND ND ND ND ND ND ---ND 15-Dec-09 0.2 1.0 ND ND ND ND (ND)ND ND ND ND ---ND 28-Jun-10 0.2 1.0 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.2 1.0 0.2 J 0.3 J ND (ND)0.4 J 0.3 J 0.2 J 1.8 0.2 J ---ND 12-Apr-11 0.10 1.0 ND ND ND ND 0.48 B ND ND 0.64 B ---0.28 J 18-Oct-11 1.0 1.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 1.0 1.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 1.0 1.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 1.0 1.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 1.0 1.0 ND ND ND ND 1.3 ND ND ------ND 14-Oct-14 1.0 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.5 1.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.5 1.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.047 1.0 ND ND ND 0.087 J 0.18 J ND ND ------ND 11-Oct-16 0.5 1.0 ND ND ND 0.57 J ND ND ND ------ND 18-Apr-17 0.5 1.0 ND ND ND ND ND ND ND ------ND Cadmium Apr-93 ---2 ND 6 2.1 2 5 2 2 2.3 2.8 --- Sep-93 ---2 ND 2.1 ND ND ND ND ND --------- Apr-94 ---2 ND ND ND ND ND ND ND ND ND --- Apr-95 ---1 ND ND ND ND ND ND ND ND ------ Nov-95 ---1 ND ND ND 1 ND ND ND ND ------ May-96 ---1 1 10 ND ND ND 1 ND 4 ------ Nov-96 ---1 ND 4 1 1 23 ND ND ND ---ND Mar-97 ---1 ND ND 1 3 18 ND ND ND ---ND Sep-97 ---1 1 2 4 15 ND ND ND ---ND Mar-98 ---1 ND ND 2 ND 5 ND ND ND ---ND Oct-94 ---1 ND ND 1 ND ND ND ND ND ND --- Sep-98 ---1 ND ND ND (ND)1 4 ND ND 3 ---ND Mar-99 ---1 ND ND ND (ND)ND 2 ND ND ND ---ND Sep-99 ---1 ND ND ND ND ND ND ND ND ---ND May-00 ---1 ND ND ND (ND)ND ND ND ND ND ---ND Oct-00 ---1 1 ND ND 2(1)6 1 ND 1 ---ND Mar-01 ---1 ND ND (ND)ND 1 4 ND ND ND ---ND Oct-01 ---1 ND ND ND ND (ND)ND ND ND ND ---ND Apr-02 ---1 ND 2 ND ND (ND)1 ND ND ND ---ND Nov-02 ---1 ND ND ND (ND)1 ND ND ND ND ---ND May-03 ---1 ND ND ND ND (ND)ND ND ND ND ---ND Nov-03 ---1 ND ND ND ND ND (ND)ND ND ND ---ND Apr-04 ---1 ND 1 ND (ND)ND ND ND ND ND ---ND Oct-04 ---1 ND ND (ND)ND ND ND ND ND ND ---ND May-05 ---1 ND ND (ND)ND ND ND ND ND ND ---ND Oct-05 ---1 ND ND ND ND ND (ND)ND ND ND ---ND 23-May-06 ---1 ND ND (ND)ND 1 6 ND 1 2 ---ND 09-Nov-06 ---1 ND ND ND ND (ND)ND ND ND ND ---ND 19-Jun-07 0.2 1.0 1.6 B 1.8 B 1.0 B 2.4 B 10.2 (8.1)1.3 B 0.9 B 5.9 ---0.7 J NC 2L = 1.75 µg/L (10/23/07)28-Nov-07 0.2 1.0 0.25 J 0.4 J 0.5 J 0.65 (6.0)3.1 J ND ND 0.86 J ---ND NC 2B = 2 µg/L (05/01/07)21-Apr-08 0.2 1.0 0.5 J 0.3 J 0.4 J ND (ND)ND ND ND ND ---ND 22-Dec-08 0.2 1.0 0.96 B 1.0 B ND (ND)ND ND ND ND ND ---0.8 J 23-Jun-09 0.2 1.0 0.6 J 0.5 (ND)J ND ND 0.3 J ND ND ND ---ND 15-Dec-09 0.2 1.0 ND 0.8 J ND ND (ND)ND 0.5 J ND ND ---ND NC 2L = 2 µg/L (01/01/10)28-Jun-10 0.2 1.0 0.4 J 0.2 J 0.3 J 0.6 J 4.5 (4.8)0.3 J ND 2.6 ---ND 02-Nov-10 0.2 1.0 0.5 J 0.4 J ND (1.2)1.0 8.8 0.4 J 0.3 J 0.9 J ---ND 12-Apr-11 0.50 1.0 ND ND ND ND ND ND ND 0.59 J ---ND 18-Oct-11 1.0 1.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 1.0 1.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 1.0 1.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 1.0 1.0 ND ND ND ND 1.7 ND ND ND ---ND 08-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 1.0 1.0 ND ND ND ND 1.3 ND ND ------ND 14-Oct-14 1.0 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.5 1.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.5 1.0 ND 2.4 ND ND 0.75 J ND ND ND ---ND 21-Apr-16 0.019 1.0 0.24 B 0.26 B 0.14 B 0.23 B 0.17 B 0.11 B 0.084 B ------0.068 J 11-Oct-16 0.5 1.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.5 1.0 ND ND ND ND ND ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 2 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Chromium Apr-93 ---40 ND 140 ND ND ND ND ND ND ND --- Sep-93 ---20 ND 673 ND ND ND ND ND ND ------ Apr-94 ---20 ND 31 ND ND ND ND ND ND ND --- Oct-94 ---10 ND ND ND ND ND ND ND ND 16 --- Apr-95 ---10 ND ND ND ND ND ND ND ND ------ Nov-95 ---10 ND ND ND ND ND ND ND ND ------ May-96 ---10 ND 118 11 ND ND ND ND ND ------ Nov-96 ---10 ND 48 12 ND 154 ND ND ND ---ND Mar-97 ---10 ND ND 10 ND 38 ND ND ND ---ND Sep-97 ---10 ND 17 26 ND 11 ND ND ND ---ND Mar-98 ---10 ND ND 25 ND 16 ND ND ND ---ND Sep-98 ---10 ND ND ND 12 17 ND ND ND ---ND Mar-99 ---10 ND ND ND ND ND ND ND ND ---ND Sep-99 ---10 ND ND ND ND 36 ND ND ND ND ND May-00 ---10 ND ND ND ND ND ND ND ND ---ND Oct-00 ---10 ND ND ND ND 11 ND ND ND ---ND Mar-01 ---10 ND ND ND ND ND ND ND ND ---ND Oct-01 ---10 ND ND ND ND 27 ND ND ND ---ND Apr-02 ---10 ND ND ND ND ND ND ND ND ---ND Nov-02 ---10 ND ND ND ND ND ND ND ND ---ND May-03 ---10 ND ND ND ND ND ND ND ND ---ND Nov-03 ---10 ND ND ND ND 12(14)ND ND ND ---ND Apr-04 ---10 ND ND ND ND ND ND ND ND ---ND Oct-04 ---10 ND ND ND ND ND ND ND ND ---ND May-05 ---10 ND ND ND ND ND ND ND ND ---ND Oct-05 ---10 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---10 ND ND ND ND 12 ND ND ND ---ND 09-Nov-06 ---10 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.7 10.0 2.4 B 1.0 B 1.4 B 5.3 B 17.9 B (6.2 B)3.8 B 4.9 B ND ---6.1 J NC 2L = 50 µg/L (10/23/07)28-Nov-07 0.7 10.0 1.8 J 3.3 J 1.3 J 9.0 (19.7)J 4.3 J ND 0.76 J 10.8 ---ND NC 2B = 50 µg/L (05/01/07)21-Apr-08 0.7 10.0 2.1 J ND ND 5.6 (ND)J ND ND ND ND ---ND 22-Dec-08 0.7 10.0 1.1 J 2.2 J ND (1.2 J)7.6 J 7.2 J ND ND 1.9 J ---ND 23-Jun-09 0.7 10.0 2.5 J 1.4 (ND)J 1.1 J 2.0 J 5.6 J 1.0 J 0.8 J 1.0 J ---ND 15-Dec-09 0.7 10.0 2.4 J 4.7 J 0.8 J 2.2 (1.9 J)J 8.0 J 3.6 J ND 1.7 J ---ND NC 2L = 10 µg/L (01/01/10)28-Jun-10 0.7 10.0 ND 1.4 J ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.7 10.0 1.6 J ND ND (ND)2.3 J ND ND ND 1.4 J ---ND 12-Apr-11 0.40 10.0 ND 4.1 J 1.1 J 1.7 J 12.2 0.60 J 0.80 J 1.6 J ---ND 18-Oct-11 5.0 10.0 ND 5.4 J ND 9.4 J 19.5 ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND 6.4 J ND ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 10.0 ND ND ND ND ND ND ND 5.6 J ---ND 08-Oct-13 5.0 10.0 ND ND 8.6 J ND ND ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND ND 16.3 ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND ND ND 10.7 5.4 J ------ND 09-Apr-15 2.5 10.0 ND ND ND 4.0 J 2.7 J ND 5.7 J ------ND 27-Oct-15 2.5 10.0 ND ND ND ND 9.3 J ND ND 4.5 J ---ND 21-Apr-16 0.51 10.0 ND ND ND 0.52 J 3.1 J ND ND ------ND 11-Oct-16 2.5 10.0 ND ND ND 16.4 8.9 J ND ND ------ND 18-Apr-17 2.5 10.0 ND ND ND ND 5.1 J ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 3 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Cobalt Oct-94 ---10 ND ND ND 18 ND ND ND ND 24 --- Apr-95 ---10 ND ND ND ND ND ND ND 10 ------ Nov-95 ---10 ND ND ND ND ND ND ND ND ------ May-96 ---10 ND 34 ND 21 ND ND ND 13 ------ Nov-96 ---10 ND 11 ND 18 86 ND ND ND ---ND Mar-97 ---10 ND ND ND 20 44 ND ND ND ---ND Sep-97 ---10 ND ND 0.014 31 27 ND ND ND ---ND Mar-98 ---10 ND ND 34 18 37 ND ND ND ---ND Sep-98 ---10 ND ND ND 26 30 ND ND 12 ---ND Mar-99 ---10 ND ND ND 16 25 ND ND ND ---ND Sep-99 ---10 ND ND ND 17 33 ND ND ND ---ND May-00 ---10 ND ND ND 18 32 ND ND ND ---ND Oct-00 ---10 ND ND ND 23(22)32 ND ND ND ---ND Mar-01 ---10 ND ND ND 18 24 ND ND ND ---ND Oct-01 ---10 ND ND 20 20(20)35 ND ND ND ---ND Apr-02 ---10 ND ND ND 11(12)25 ND ND ND ---ND Nov-02 ---10 ND ND ND 20 28 ND ND ND ---ND May-03 ---10 ND ND ND 19(19)22 ND ND ND ---ND Nov-03 ---10 ND ND ND 16 28(29)ND ND ND ---ND Apr-04 ---10 ND ND ND 13 23 ND ND 12 ---ND Oct-04 ---10 ND ND ND 14 19 ND ND ND ---ND May-05 ---10 ND ND ND 11 23 ND ND 11 ---ND Oct-05 ---10 ND ND ND 19 19(20)ND ND ND ---ND 23-May-06 ---10 ND ND ND 15 24 ND ND 10 ---ND 09-Nov-06 ---10 ND ND ND 16(15)19 ND ND ND ---ND 19-Jun-07 0.7 10.0 ND ND ND 14.8 28.2 (23.8)ND ND 10.6 ---ND GWPS = 70 µg/L (10/23/07)28-Nov-07 0.7 10.0 ND 0.8 J ND 19.4 (15.3)18.8 ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.7 10.0 1.5 1.0 J 0.8 J 13.8 (12.6)21.7 ND ND 6.1 J ---ND 22-Dec-08 0.7 10.0 ND 1.9 J ND (ND)12.7 20.8 ND ND 4.1 J ---ND 23-Jun-09 0.7 10.0 4.0 J ND (ND)ND 8.7 J 20.1 ND ND 9.9 J ---ND 15-Dec-09 0.7 10.0 3.2 J 1.7 J ND 12.0 (11.6)18.8 ND ND 4.7 J ---ND 28-Jun-10 0.7 10.0 ND ND ND 5.8 J 15.6 (16.4)ND ND 8.5 J ---ND GWPS = 1 µg/L (10/1/10)02-Nov-10 0.7 10.0 3.5 J ND ND (ND)13.9 13.9 ND ND 5.6 J ---ND 12-Apr-11 0.60 10.0 1.5 B 1.9 B 2.2 B 12.4 8.8 J 2.5 B ND 1.4 B ---1.1 J 18-Oct-11 5.0 10.0 ND ND ND 25.0 64.5 ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND 13.1 23.2 ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND 9.5 J ND ND ND ------ND 16-Apr-13 5.0 10.0 13.0 ND ND 7.8 J 95.1 ND ND 14.1 ---ND 08-Oct-13 5.0 10.0 8.4 J ND ND 17.7 102 ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND 6.8 J ND ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND 11.4 11.5 ND ND ------ND 09-Apr-15 2.5 10.0 ND ND ND 9.8 J 13.7 ND ND ------ND 27-Oct-15 2.5 10.0 2.8 J ND ND 12.1 11.7 ND ND 5.8 J ---ND 21-Apr-16 0.013 10.0 4.3 J 0.10 J 0.065 J 11 17 0.13 J 0.20 J ------ND 11-Oct-16 2.5 10.0 ND ND ND 23.6 18.0 ND ND ------ND 18-Apr-17 2.5 10.0 ND ND ND 13.3 15.4 ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 4 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Copper Apr-93 ---20 ND ND ND ND ND ND ND 263 ND --- Sep-93 ---10 ND 138 ND ND ND ND ND --------- Apr-94 ---10 ND ND ND ND ND ND ND ND ND --- Oct-94 ---200 ND ND ND ND ND ND ND ND ND --- Apr-95 ---200 ND ND ND ND ND ND ND ND ------ Nov-95 ---200 ND ND ND ND ND ND ND ND ------ May-96 ---200 ND ND ND ND ND ND ND ND ------ Nov-96 ---200 ND ND ND ND 114 ND ND ND ---ND Mar-97 ---200 ND ND ND ND ND ND ND ND ---ND Sep-97 ---200 ND ND ND ND ND ND ND ND ---ND Mar-98 ---200 ND ND ND ND ND ND ND ND ---ND Sep-98 ---10 ND ND ND ND ND ND ND ND ---ND Mar-99 ---10 ND ND ND ND ND ND ND ND ---ND Sep-99 ---200 ND ND ND ND ND ND ND ND ---ND May-00 ---200 ND ND ND ND ND ND ND ND ---ND Oct-00 ---200 ND ND ND ND ND ND ND ND ---ND Mar-01 ---200 ND ND ND ND ND ND ND ND ---ND Oct-01 ---200 ND ND ND ND ND ND ND ND ---ND Apr-02 ---200 ND ND ND ND ND ND ND ND ---ND Nov-02 ---200 ND ND ND ND ND ND ND ND ---ND May-03 ---200 ND ND ND ND ND ND ND ND ---ND Nov-03 ---200 ND ND ND ND ND ND ND ND ---ND Apr-04 ---200 ND ND ND ND ND ND ND ND ---ND Oct-04 ---200 ND ND ND ND ND ND ND ND ---ND May-05 ---200 ND ND ND ND ND ND ND ND ---ND Oct-05 ---200 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---200 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---200 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 2.0 10.0 2.6 B 2.8 B 2.8 B 15.5 B 15.6 (10.9 B)B 8.6 B 4.0 B ND ---5.1 NC 2L = 1,000 µg/L (10/23/07)28-Nov-07 2.0 10.0 ND 5.7 B 3.2 B 30.5 (24.4)ND 3.7 B 2.8 B 3.3 B ---2.5 J NC 2B = 7 µg/L (05/01/07)21-Apr-08 2.0 10.0 2.3 B ND ND 20.6 (22.0 B)B 7.4 B ND ND 6.6 B ---7.0 J 22-Dec-08 2.0 10.0 ND 2.4 J 3.8 (ND)J 2.7 J ND ND ND ND ---ND 23-Jun-09 2.0 10.0 ND ND (ND)ND 5.5 J 4.4 J 1.3 J ND ND ---ND 15-Dec-09 2.0 10.0 ND 2.4 B ND 5.9 (3.8 B)B 2.9 B ND ND ND ---2.7 J NC 2L = 1,000 µg/L (01/01/10)28-Jun-10 2.0 10.0 ND ND ND 2.0 J 1.3 (2.3 J)J ND ND ND ---ND 02-Nov-10 2.0 10.0 ND ND ND (7.4 J)ND ND ND ND ND ---ND 12-Apr-11 0.30 10.0 0.52 B 4.8 J 3.4 B 5.0 J 10.3 1.0 B 0.94 B 2.5 B ---0.92 J 18-Oct-11 5.0 10.0 ND ND ND 36.5 14.2 ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND 26.0 ND ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 10.0 ND ND ND 5.6 J ND ND ND 11.3 ---ND 08-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND 11.2 ND ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND 10.6 5.3 J ND ND ------ND 09-Apr-15 2.5 10.0 ND 4.0 J ND 17.6 6.0 J ND 4.6 J ------3.2 J 27-Oct-15 2.5 10.0 ND ND ND ND 14.8 ND 2.5 J 12.4 ---ND 21-Apr-16 0.44 10.0 0.48 J 6.8 J 1.4 J 4.9 J 2.9 J 0.58 J 0.65 J ------ND 11-Oct-16 2.5 10.0 ND 3.0 J ND 58.7 6.0 J ND ND ------ND 18-Apr-17 2.5 10.0 ND ND ND ND ND ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 5 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Lead Apr-93 ---5 ND 497 22 ND 18.1 ND ND 163 ND --- Sep-93 ---5 ND 224 16 5 ND ND ND --------- Apr-94 ---5 ND 14.2 6 13 6 ND ND ND ND ND Oct-94 ---10 ND ND ND ND ND ND ND ND ND --- Apr-95 ---10 ND ND 11 ND ND ND ND ND ------ Nov-95 ---10 ND ND 13 ND ND ND ND ND ------ May-96 ---10 ND 41 21 11 ND ND ND ND ------ Nov-96 ---10 ND 20 22 ND 96 ND ND ND ---ND Mar-97 ---10 ND ND 19 ND 37 ND ND ND ---ND Sep-97 ---10 ND 12 51 ND 12 ND 19 ND ---ND Mar-98 ---10 ND ND 130 ND 30 ND ND ND ---ND Sep-98 ---10 ND ND ND 11 14 ND ND ND ---ND Mar-99 ---10 ND ND ND ND 8 ND ND ND ---ND Sep-99 ---10 ND ND ND ND ND ND ND ND ---ND May-00 ---10 ND ND ND ND ND ND ND ND ---ND Oct-00 ---10 ND ND ND 18(10)15 ND ND ND ---ND Mar-01 ---10 ND ND ND ND ND ND ND ND ---ND Oct-01 ---10 ND ND ND ND 19 ND ND ND ---ND Apr-02 ---10 ND ND ND ND ND ND ND ND ---ND Nov-02 ---10 ND ND ND ND 16 ND ND ND ---ND May-03 ---10 ND ND ND ND ND ND ND ND ---ND Nov-03 ---10 ND ND ND ND 16(20)ND ND ND ---ND Apr-04 ---10 ND ND ND ND ND ND ND ND ---ND Oct-04 ---10 ND ND ND ND ND ND ND 13 ---ND May-05 ---10 ND ND ND ND ND ND ND ND ---ND Oct-05 ---10 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---10 ND ND ND ND 12 ND ND ND ---ND 09-Nov-06 ---10 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 2.0 10.0 12.9 ND ND 2.6 J 13.3 (5.1 J)ND ND ND ---ND NC 2L = 15 µg/L (10/23/07)28-Nov-07 2.0 10.0 ND ND ND 6.6 (20.9)B 5.6 B ND ND 6.5 B ---2.1 J NC 2B = 25 µg/L (05/01/07)21-Apr-08 2.0 10.0 ND 3.8 J 2.0 J 5.2 (4.2 J)J 14.5 ND ND 3.1 J ---ND 22-Dec-08 2.0 10.0 3.2 B 5.2 B ND (2.6 B)3.7 B 9.8 B 3.0 B ND ND ---3.1 J 23-Jun-09 2.0 10.0 2.8 J 3.2 (ND)J 3.1 J 3.2 J 11.5 3.2 J ND 4.6 J ---ND 15-Dec-09 2.0 10.0 ND 3.8 J ND 5.6 (ND)J 7.5 J ND ND ND ---ND 28-Jun-10 2.0 10.0 4.8 J 2.9 J 4.7 J ND 5.8 (3.6 J)J 3.4 J 2.1 J 2.7 J ---ND 02-Nov-10 2.0 10.0 2.6 J ND ND (ND)3.0 J 7.5 J ND ND ND ---ND 12-Apr-11 4.0 10.0 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 5.0 10.0 ND ND ND 7.0 J 7.4 J ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 10.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND ND 6.0 J ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 2.5 10.0 ND ND ND 4.6 J 4.4 J ND ND ------ND 27-Oct-15 2.5 10.0 ND ND ND ND 8.7 J ND ND 6.2 J ---ND 21-Apr-16 0.02 10.0 0.12 B 0.39 J 0.37 J 0.58 J 2.4 J 0.17 B 0.27 J ------0.043 J 11-Oct-16 2.5 10.0 ND ND ND 10.4 6.1 J ND ND ------ND 18-Apr-17 2.5 10.0 ND ND ND ND 5.3 J ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 6 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Nickel Nov-96 ---50 ND ND ND ND 76 ND ND ND ---ND Mar-97 ---50 ND ND ND ND ND ND ND ND ---ND Sep-97 ---50 ND ND ND ND ND ND ND ND ---ND Mar-98 ---50 ND ND ND ND ND ND ND ND ---ND Sep-98 ---50 ND ND ND ND ND ND ND ND ---ND Mar-99 ---50 ND ND ND ND ND ND ND ND ---ND Sep-99 ---50 ND ND ND ND ND ND ND ND ---ND May-00 ---50 ND ND ND ND ND ND ND ND ---ND Oct-00 ---50 ND ND ND ND ND ND ND ND ---ND Mar-01 ---50 ND ND ND ND ND ND ND ND ---ND Oct-01 ---50 ND ND ND ND ND ND ND ND ---ND Apr-02 ---50 ND ND ND ND ND ND ND ND ---ND Nov-02 ---50 ND ND ND ND ND ND ND ND ---ND May-03 ---50 ND ND ND ND ND ND ND ND ---ND Nov-03 ---50 ND ND ND ND ND ND ND ND ---ND Apr-04 ---50 ND ND ND ND ND ND ND ND ---ND Oct-04 ---50 ND ND ND ND ND ND ND ND ---ND May-05 ---50 ND ND ND ND ND ND ND ND ---ND Oct-05 ---50 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---50 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---50 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.6 50.0 ND ND 1.4 B 9.0 B 16.8 B (11.4 B)11.2 B 4.0 B 12.8 B ---9.6 J NC 2L = 100 µg/L (10/23/07)28-Nov-07 0.6 50.0 1.4 B ND 1.6 B 5.2 (13.6 J)B 7.9 J 1.9 B 1.1 B 12.2 J ---1.4 J NC 2B = 88 µg/L (05/01/07)21-Apr-08 0.6 50.0 2.0 B ND ND 2.6 (3.9 B)B 9.1 B ND ND 9.5 B ---3.3 J 22-Dec-08 0.6 50.0 ND 5.7 J ND (ND)7.5 J 13.2 J ND ND 7.8 J ---ND 23-Jun-09 0.6 50.0 1.5 B ND (ND)ND 2.4 B 9.9 B ND ND 9.0 B ---2.8 J 15-Dec-09 0.6 50.0 ND 2.1 J ND 1.3 (1.1 J)J 8.2 J ND ND 5.4 J ---ND 28-Jun-10 0.6 10.0 ND ND ND ND 5.7 (5.7 J)J ND ND 8.5 J ---ND 02-Nov-10 0.6 50.0 2.8 B 1.3 B 1.3 (ND)B 5.2 B 7.1 J 1.1 B 0.7 B 9.5 J ---1.3 J 12-Apr-11 1.7 50.0 ND ND ND 2.2 B 11.2 B ND ND ND ---4.4 J 18-Oct-11 5.0 50.0 ND ND ND ND 12.4 J ND ND ------ND 10-Apr-12 5.0 50.0 ND ND ND ND 6.8 J ND ND ------ND 15-Oct-12 5.0 50.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 50.0 ND ND ND ND 8.1 J ND ND 19.6 J ---ND 08-Oct-13 5.0 50.0 ND ND ND ND 6.7 J ND ND ------ND 29-Apr-14 5.0 50.0 ND ND ND ND 10.0 J ND ND ------ND 14-Oct-14 5.0 50.0 ND ND ND ND 9.3 J ND ND ------ND 09-Apr-15 2.5 50.0 ND ND ND 3.6 J 8.4 J ND ND ------ND 27-Oct-15 2.5 50.0 ND 3.0 J ND 4.0 J 9.7 J ND ND 6.7 J ---ND 21-Apr-16 0.053 50.0 1.1 B 0.49 B 0.52 B 3.4 B 9.9 J 0.30 B 0.33 B ------1.1 J 11-Oct-16 2.5 50.0 ND ND ND 8.8 J 13.7 J ND ND ------ND 18-Apr-17 2.5 50.0 ND ND ND 4.1 J 10.8 J ND ND ------ND Selenium Apr-93 ---5 ND ND ND ND ND ND ND ND ND --- Sep-93 ---5 ND 25 ND 5 ND ND ND --------- Apr-94 ---5 ND ND ND ND ND ND ND ND ND --- Oct-94 ---20 ND ND ND ND ND ND ND ND ND --- Apr-95 ---20 ND ND ND ND ND ND ND ND ------ Nov-95 ---20 ND ND ND ND ND ND ND ND ------ May-96 ---20 ND ND ND ND ND ND ND ND ------ Nov-96 ---20 ND ND ND ND ND ND ND ND ---ND Mar-97 ---20 ND ND ND ND ND ND ND ND ---ND Sep-97 ---20 ND ND ND ND ND ND ND ND ---ND Mar-98 ---20 ND ND ND ND ND ND ND ND ---ND Sep-98 ---20 ND ND ND ND ND ND ND ND ---ND Mar-99 ---20 ND ND ND ND ND ND ND ND ---ND Sep-99 ---20 ND ND ND ND ND ND ND ND ---ND May-00 ---20 ND ND ND ND ND ND ND ND ---ND Oct-00 ---20 ND ND ND ND ND ND ND ND ---ND Mar-01 ---20 ND ND ND ND ND ND ND ND ---ND Oct-01 ---20 ND ND ND ND ND ND ND ND ---ND Apr-02 ---20 ND ND ND ND ND ND ND ND ---ND Nov-02 ---20 ND ND ND ND ND ND ND ND ---ND May-03 ---20 ND ND ND ND ND ND ND ND ---ND Nov-03 ---20 ND ND ND ND ND ND ND ND ---ND Apr-04 ---20 ND ND ND ND ND ND ND ND ---ND Oct-04 ---20 ND ND ND ND ND ND ND ND ---ND May-05 ---20 ND ND ND ND ND ND ND ND ---ND Oct-05 ---20 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---20 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---20 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 6.3 10.0 ND ND ND ND ND (ND)ND ND ND ---ND NC 2L = 50 µg/L (10/23/07)28-Nov-07 6.3 10.0 ND ND ND ND (ND)ND 7.6 B ND ND ---7.8 J NC 2B = 5 µg/L (05/01/07)21-Apr-08 6.3 10.0 ND ND ND ND (4.7 J)ND ND ND ND ---ND 22-Dec-08 6.3 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 23-Jun-09 6.3 10.0 ND ND (ND)ND ND ND ND ND ND ---ND 15-Dec-09 6.3 10.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2L = 20 µg/L (01/01/10)28-Jun-10 6.3 10.0 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 6.3 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 3.8 10.0 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 10.0 10.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 10.0 10.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 10.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 10.0 10.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 10.0 10.0 ND ND ND ND 15.7 ND ND ------ND 14-Oct-14 10.0 10.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 5.0 10.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 5.0 10.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.35 10.0 ND 0.71 J ND ND 1.8 J ND 0.36 J ------ND 11-Oct-16 5.0 10.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 5.0 10.0 ND ND ND ND ND ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 7 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Silver 28-Nov-07 1.1 10.0 ND ND 1.5 J ND (ND)ND ND ND ND ---ND NC 2L = 17.5 µg/L (10/23/07)21-Apr-08 1.1 10.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = 0.06 µg/L (05/01/07)22-Dec-08 1.1 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 23-Jun-09 1.1 10.0 ND 1.1 (ND)B ND ND ND ND ND ND ---9.3 J 15-Dec-09 1.1 10.0 ND ND ND 2.3 (ND)B ND 1.4 B 2.2 B ND ---1.6 J NC 2L = 20 µg/L (01/01/10)28-Jun-10 1.1 10.0 1.2 J 1.4 J 1.4 J ND ND (ND)ND ND ND ---ND 02-Nov-10 1.1 10.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 0.10 10.0 ND ND ND ND ND ND ND 0.12 B ---0.21 J 18-Oct-11 5.0 10.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 5.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 10.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.0 10.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 5.0 10.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 2.5 10.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 2.5 10.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.011 10.0 0.056 B 0.029 B 0.18 J 0.11 J 0.023 B 0.024 B 0.014 B ------0.012 J 11-Oct-16 2.5 10.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 2.5 10.0 ND ND ND ND ND ND ND ------ND Thallium 19-Jun-07 2.7 5.5 ND ND 4.3 J ND ND (ND)ND ND ND ---ND GWPS = 0.28 µg/L (10/23/07)28-Nov-07 2.7 5.5 ND ND ND ND ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 2.7 5.5 ND ND 2.9 B ND (ND)ND ND ND ND ---3.3 J 22-Dec-08 2.7 5.5 ND ND ND (ND)ND ND ND ND ND ---4.0 J 23-Jun-09 2.7 5.5 ND 4.0 (ND)J ND ND ND ND ND ND ---ND 15-Dec-09 2.7 5.5 ND ND ND ND (ND)ND ND ND ND ---ND 28-Jun-10 2.7 5.5 ND 3.0 J ND ND ND (ND)ND ND ND ---ND GWPS = 0.2 µg/L (10/1/10)02-Nov-10 2.7 5.5 ND ND ND (ND)ND ND ND 4.7 B 4.5 B ---3.9 J 12-Apr-11 3.0 5.5 ND ND ND ND 3.0 J ND ND ND ---ND 18-Oct-11 5.4 5.5 ND ND ND 5.8 ND ND ND ------ND 10-Apr-12 5.4 5.5 ND ND ND ND ND ND ND ------ND 15-Oct-12 5.4 5.5 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.4 5.5 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.4 5.5 ND ND ND ND ND ND ND ------ND 14-Oct-14 5.4 5.5 ND ND ND ND ND ND ND ------ND 09-Apr-15 5.0 5.5 ND ND ND ND ND ND ND ------ND 27-Oct-15 5.0 5.5 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.0093 5 0.064 J 0.07 J 0.021 J 0.078 J 0.048 J ND ND ------ND 11-Oct-16 5.0 5.5 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.0 5.5 ND 0.09 J ND ND 0.025 J ND ND ------ND Vanadium Oct-94 ---40 ND ND ND 174 62 ND ND 127 256 --- Apr-95 ---40 ND ND ND ND ND ND ND ND ------ Nov-95 ---40 ND ND ND ND ND ND ND ND ------ May-96 ---40 ND 152 ND ND ND ND ND ND ------ Nov-96 ---40 ND 59 ND ND 203 ND ND ND ---ND Mar-97 ---40 ND ND ND ND 66 ND ND ND ---ND Sep-97 ---40 ND ND 55 ND ND ND ND ND ---ND Mar-98 ---40 ND ND 87 ND 48 ND ND ND ---ND Sep-98 ---40 ND ND ND ND ND ND ND ND ---ND Mar-99 ---40 ND ND ND ND ND ND ND ND ---ND Sep-99 ---40 ND ND ND ND 92 ND ND ND ND ND May-00 ---40 ND ND ND ND ND ND ND ND ---ND Oct-00 ---40 ND ND ND ND ND ND ND ND ---ND Mar-01 ---40 ND ND ND ND ND ND ND ND ---ND Oct-01 ---40 ND ND ND ND 57 ND ND ND ---ND Apr-02 ---40 ND ND ND ND ND ND ND ND ---ND Nov-02 ---40 ND ND ND ND ND ND ND ND ---ND May-03 ---40 ND ND ND ND ND ND ND ND ---ND Nov-03 ---40 ND ND ND ND 41(47)ND ND ND ---ND Apr-04 ---40 ND ND ND ND ND ND ND ND ---ND Oct-04 ---40 ND ND ND ND ND ND ND ND ---ND May-05 ---40 ND ND ND ND ND ND ND ND ---ND Oct-05 ---40 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---40 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---40 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.4 25.0 ND ND ND 6.9 J 30.0 (14.0 J)ND ND ND ---ND GWPS = 3.5 µg/L (10/23/07)28-Nov-07 0.4 25.0 ND 3.0 J ND 11.3 (7.4 J)J ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.4 25.0 ND 4.0 J ND 4.3 (4.6 J)J 22.4 J ND ND ND ---ND 22-Dec-08 0.4 25.0 2.2 J 1.9 J ND (ND)1.5 J 16.7 J ND ND ND ---ND 23-Jun-09 0.4 25.0 ND ND (ND)ND 2.5 J 16.8 J ND ND 3.6 J ---ND 15-Dec-09 0.4 25.0 ND 5.6 B 1.9 B 2.3 (2.3 B)B 16.6 B ND ND 0.6 B ---5.2 J 28-Jun-10 0.4 25.0 3.4 J ND ND ND 3.3 (7.1 J)J ND 1.3 J ND ---ND GWPS = 0.3 µg/L (10/1/10)02-Nov-10 0.4 25.0 ND ND 0.9 (1.3 J)J 1.4 J 8.9 J 1.1 J 0.6 J 2.0 J ---ND 12-Apr-11 0.20 25.0 ND 5.3 J 1.7 J ND 23.2 J 0.64 B 0.72 B 1.9 J ---0.27 J 18-Oct-11 5.0 25.0 ND 6.6 J ND 19.1 J 31.8 ND ND ------ND 10-Apr-12 5.0 25.0 ND ND ND 12.1 J ND ND ND ------ND 15-Oct-12 5.0 25.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 5.0 25.0 ND ND ND ND 5.4 J ND ND ND ---ND 08-Oct-13 5.0 25.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 5.0 25.0 ND ND ND ND 20.7 J ND ND ------ND 14-Oct-14 5.0 25.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 2.5 25.0 2.8 J ND ND 11.2 J 8.9 J ND 5.3 J ------ND 27-Oct-15 2.5 25.0 2.7 J ND ND 3.8 J 17.6 J ND ND 9.7 J ---ND 21-Apr-16 2.5 25.0 ND ND ND ND 5.6 J ND ND ------ND 11-Oct-16 2.5 25.0 ND ND ND 41.3 13.1 J ND ND ------ND 18-Apr-17 2.5 25.0 ND ND ND 7.6 J 16.5 J ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 8 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Zinc Apr-93 ---20 49 312 78 44 59 ND 34 4290 83 --- Sep-93 ---20 ND 1640 ND ND ND ND ND --------- Apr-94 ---20 25 88 ND ND ND 26 26 54 60 --- Oct-94 ---50 ND 68 ND ND ND ND ND ND ND --- Apr-95 ---50 ND ND 98 ND ND ND ND ND ------ Nov-95 ---50 ND ND ND ND 81 ND 50 84 ------ May-96 ---50 97 327 159 68 70 71 ND 91 ------ Nov-96 ---50 90 159 84 ND 418 50 86 ND ---ND Mar-97 ---50 ND 99 88 56 130 ND ND ND ---ND Sep-97 ---50 70 560 200 72 171 118 200 ND ---ND Mar-98 ---50 ND 168 197 ND 94 ND ND ND ---ND Sep-98 ---50 ND ND ND ND ND 159 ND 123 ---ND Mar-99 ---50 ND ND ND ND ND ND ND ND ---ND Sep-99 ---50 ND ND ND ND 61 ND ND ND ---ND May-00 ---50 ND ND ND ND ND ND ND ND ------ Oct-00 ---50 ND 63 ND ND ND ND ND ND ---ND Mar-01 ---50 ND ND ND ND ND ND ND ND ---ND Oct-01 ---50 ND ND ND ND ND ND ND ND ---ND Apr-02 ---50 ND ND ND ND ND ND ND ND ---ND Nov-02 ---50 52 70 57(ND)50 69 ND ND ND ---ND May-03 ---50 ND 77 ND ND ND 50 ND 61 ---ND Nov-03 ---50 ND ND ND 78 52(89)ND 51 135 ---ND Apr-04 ---50 ND ND ND ND ND ND ND ND ---ND Oct-04 ---50 ND ND ND ND ND ND ND 138 ---ND May-05 ---50 ND ND ND ND ND ND ND ND ---ND Oct-05 ---50 137 ND ND ND ND ND ND 79 ---ND 23-May-06 ---50 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---50 ND ND ND ND ND ND ND ND ---74 19-Jun-07 2.7 10.0 53.4 103 39.6 49.4 110 (95.8)89.9 73.2 144 ---3.0 J NC 2L = 1,050 µg/L (10/23/07)28-Nov-07 2.7 10.0 13.2 B 33.4 B 8.3 B 11.2 (70.6)B 26.8 B 7.6 B 5.8 B 28.9 B ---7.1 J NC 2B = 50 µg/L (05/01/07)21-Apr-08 2.7 10.0 ND ND ND ND (ND)17.9 B ND ND 21.3 B ---6.0 J 22-Dec-08 2.7 10.0 ND 10.3 B ND (ND)ND 11.4 B ND ND ND ---11.1 J 23-Jun-09 2.7 10.0 83.7 B ND (ND)76.1 B 27.1 B 108 B 36.8 B 41.3 B 79.7 B ---51.8 B 15-Dec-09 2.7 10.0 ND 20.5 B 8.8 B 7.4 (ND)B 29.4 B 30.8 B 11.2 B ND ---26.5 NC 2L = 1,000 µg/L (01/01/10)28-Jun-10 2.7 10.0 20.0 B 9.6 B 14.9 B 18.2 B 15.9 (18.5 B)B 8.5 B 24.6 B 25.9 B ---9.0 J 02-Nov-10 2.7 10.0 11.4 B 17.4 B 11.9 (7.2 B)B 14.6 B 22.8 B 11.3 B 14.3 B 16.5 B ---13.3 12-Apr-11 0.40 10.0 7.4 B 14.8 B 7.0 B 5.0 B 28.9 B 3.6 B 4.2 B 9.7 B ---22.5 18-Oct-11 10.0 10.0 ND 14.0 ND 14.5 57.6 ND ND ------ND 10-Apr-12 10.0 10.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 10.0 10.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 10.0 10.0 ND 12.3 ND ND 11.3 ND ND 17.3 ---ND 08-Oct-13 10.0 10.0 ND ND ND ND 14.5 ND ND ------ND 29-Apr-14 10.0 10.0 ND ND ND ND 27.3 ND ND ------ND 14-Oct-14 10.0 10.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 5.0 10.0 5.9 J 7.4 J ND 6.1 J 5.5 J ND 16.9 ------ND 27-Oct-15 5.0 10.0 6.1 B 9.7 J 6.4 B ND 41 B 8.0 B 10.1 16.6 ---8.6 J 21-Apr-16 0.98 10.0 5.9 B 17 B 9.2 B 6.4 B 10 B 2.8 B 3.8 B ------3.5 J 11-Oct-16 5.0 10.0 ND 15.8 6.5 J 18.2 23.4 ND ND ------ND 18-Apr-17 5.0 10.0 ND 5.6 J ND ND 14.7 ND ND ------ND Organic Compounds Acetone 19-Jun-07 1.2 100 ND ND ND 5.3 J ND (ND)ND ND 7.0 J ---ND NC 2L = 700 µg/L (10/23/07)28-Nov-07 1.2 100 ND 2.40 J 1.85 J 2.0 (2.8 J)J ND 1.8 J 2.7 J 2.3 J ---ND NC 2B = NE (05/01/07)21-Apr-08 1.2 100 8.69 J 7.17 J ND ND (ND)ND ND 6.1 J ND ---ND 22-Dec-08 1.2 100 3.1 J ND ND (ND)3.6 J ND 2.1 J ND ND ---ND 23-Jun-09 1.2 100 ND ND (ND)ND ND ND ND ND ND ---ND 15-Dec-09 1.2 100 ND ND ND ND (ND)ND ND ND ND ---ND NC 2L = 6,000 µg/L (01/01/10)28-Jun-10 1.2 100 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 1.2 100 ND ND ND (ND)ND 20.2 J ND ND ND ---ND 12-Apr-11 2.2 100 ND ND ND ND ND ND ND 2.7 J ---ND 18-Oct-11 2.2 100 ND ND ND 2.3 B 3.2 B 2.8 B 2.5 B ------2.2 J 10-Apr-12 2.2 100 ND ND ND ND ND ND ND ------6.0 J 15-Oct-12 10.0 100 ND ND ND ND 15.1 J ND ND ------ND 16-Apr-13 10.0 100 ND 10.6 B ND 10.0 B ND ND 10.7 B 22.5 B ---48.9 J 08-Oct-13 10.0 100 ND ND ND ND ND ND ND ------ND 29-Apr-14 10.0 100 ND ND ND ND ND ND ND ------ND 14-Oct-14 10.0 100 ND ND ND ND ND ND ND ------ND 09-Apr-15 10.0 100 ND ND ND ND ND ND ND ------ND 27-Oct-15 10.0 100 ND ND ND ND 19.1 J ND ND 10.2 J ---ND 21-Apr-16 0.31 100 ND ND ND 4.2 J ND ND ND ------ND 11-Oct-16 10.0 100 ND ND ND ND ND ND ND ------ND 18-Apr-17 10.0 100 ND ND ND ND ND ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 9 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Benzene 19-Jun-07 0.1 1.0 ND ND ND ND 1.4 (1.4)ND ND ND ---ND NC 2L = 1 µg/L (10/23/07)28-Nov-07 0.1 1.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.1 1.0 ND ND ND ND (ND)1.34 ND ND ND ---ND 22-Dec-08 0.1 1.0 ND ND ND (ND)ND 1.1 ND ND ND ---ND 23-Jun-09 0.1 1.0 ND ND (ND)ND ND 1.0 J ND ND 0.5 J ---ND 15-Dec-09 0.1 1.0 ND ND ND 0.2 (0.2 J)J 1.2 ND ND 0.4 J ---ND 28-Jun-10 0.1 1.0 ND ND ND ND 0.8 (0.8 J)J ND ND 0.3 J ---ND 02-Nov-10 0.1 1.0 ND ND ND (ND)ND 1.1 ND ND ND ---ND 12-Apr-11 0.25 1.0 ND ND ND ND 1.1 ND ND ND ---ND 18-Oct-11 0.25 1.0 ND ND ND ND 1.3 ND ND ------ND 10-Apr-12 0.25 1.0 ND ND ND ND 1.1 ND ND ------ND 15-Oct-12 0.25 1.0 ND ND ND ND 0.96 J ND ND ------ND 16-Apr-13 0.25 1.0 0.69 J ND ND ND 1.2 ND ND ND ---ND 08-Oct-13 0.25 1.0 ND ND ND ND 1.3 ND ND ------ND 29-Apr-14 0.25 1.0 ND ND ND ND 1.2 ND ND ------ND 14-Oct-14 0.25 1.0 ND ND ND ND 1.1 ND ND ------ND 09-Apr-15 0.25 1.0 ND ND ND ND 0.66 J ND ND ------ND 27-Oct-15 0.25 1.0 ND ND ND ND 0.99 J ND ND ND ---ND 21-Apr-16 0.048 1.0 ND ND ND ND 1.2 ND ND ------ND 11-Oct-16 0.25 1.0 ND ND ND 0.33 J 1.0 ND ND ------ND 18-Apr-17 0.25 1.0 ND ND ND 0.35 J 1.1 ND ND ------ND Bromomethane 16-Apr-13 0.29 10.0 0.54 J ND ND ND ND ND ND ND ---ND NC 2L = NE (01/01/10)08-Oct-13 0.29 10.0 ND ND ND ND ND ND ND ------ND NC 2B = NE (05/01/07)29-Apr-14 0.29 10.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.29 10.0 ND ND ND ND ND ND ND ------0.63 J 09-Apr-15 0.29 10.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.29 10.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.18 10.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.29 10.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.29 10.0 ND ND ND ND ND ND ND ------ND Carbon Disulfide 28-Nov-07 0.5 100 1.02 J 11.0 J 2.95 J 1.4 (0.6 J)J ND ND ND ND ---ND NC 2L = 700 µg/L (10/23/07)21-Apr-08 0.5 100 ND ND ND ND (ND)2.9 J ND ND ND ---ND NC 2B = NE (05/01/07)22-Dec-08 0.5 100 ND ND ND 1.0 J 0.9 J ND ND ND ---ND 23-Jun-09 0.5 100 ND ND (ND)ND ND ND ND ND ND ---ND 15-Dec-09 0.5 100 ND ND ND ND (ND)ND ND ND ND ---ND 28-Jun-10 0.5 100 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.5 100 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 1.2 100 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 1.2 100 ND ND ND ND ND ND ND ------ND 10-Apr-12 1.2 100 ND ND ND ND ND ND ND ------ND 15-Oct-12 1.2 100 ND ND ND ND ND ND ND ------ND 16-Apr-13 1.2 100 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 1.2 100 ND ND ND ND ND ND ND ------ND 29-Apr-14 1.2 100 ND ND ND ND ND ND ND ------ND 14-Oct-14 1.2 100 ND ND ND ND ND ND ND ------ND 09-Apr-15 1.2 100 ND ND ND ND ND ND ND ------ND 27-Oct-15 1.2 100 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.075 100 ND ND ND ND ND ND ND ------ND 11-Oct-16 1.2 100 ND ND ND ND ND ND ND ------ND 18-Apr-17 1.2 100 ND ND ND ND ND ND ND ------ND Chlorobenzene Sep-98 ---5 ND ND ND ND 9 ND ND ND ---ND Mar-99 ---5 ND ND ND ND 8 ND ND ND ---ND Oct-99 ---5 ND ND ND ND 5.9 ND ND ND ---ND May-00 ---5 ND ND ND 5.6 9.6 ND ND ND ---ND Oct-00 ---5 ND ND ND ND 8.7 ND ND ND ---ND Mar-01 ---5 ND ND ND ND 8.8 ND ND ND ---ND Oct-01 ---5 ND ND ND ND 11 ND ND ND ---ND Apr-02 ---5 ND ND ND ND 11 ND ND ND ---ND Nov-02 ---5 ND ND ND ND 8.1 ND ND ND ---ND May-03 ---5 ND ND ND ND 9.1 ND ND ND ---ND Nov-03 ---5 ND ND ND ND 8.9(9.7)ND ND ND ---ND Apr-04 ---5 ND ND ND ND 9.3 ND ND ND ---ND Oct-04 ---5 ND ND ND ND 12 ND ND ND ---ND May-05 ---5 ND ND ND ND 6.6 ND ND ND ---ND Oct-05 ---5 ND ND ND ND 8.1(7.8)ND ND ND ---ND 23-May-06 ---5 ND ND ND ND 6.3 ND ND ND ---ND 09-Nov-06 ---5 ND ND ND ND 10 ND ND ND ---ND 19-Jun-07 0.1 3.0 ND ND ND 1.9 J 10.6 (10.6)ND ND 0.8 J ---ND NC 2L = 50 µg/L (10/23/07)28-Nov-07 0.1 3.0 ND ND ND 1.9 (2.3 J)J 7.4 ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.1 3.0 ND ND ND 4.8 (4.6)9.9 ND ND 1.6 J ---ND 22-Dec-08 0.1 3.0 ND ND ND (ND)1.6 J 8.0 ND ND 0.7 J ---ND 23-Jun-09 0.1 3.0 ND ND (ND)ND 1.0 J 8.0 ND ND 2.0 J ---ND 15-Dec-09 0.1 3.0 0.7 J ND ND 2.1 (1.9 J)J 9.6 ND ND 2.6 J ---ND 28-Jun-10 0.1 3.0 ND ND ND ND 7.7 (7.2)ND ND 1.5 J ---ND 02-Nov-10 0.1 3.0 0.8 J ND ND (ND)1.3 J 6.7 ND ND 0.5 J ---ND 12-Apr-11 0.23 3.0 0.34 J ND ND 3.2 9.9 ND ND ND ---ND 18-Oct-11 0.23 3.0 0.42 J ND ND 1.9 J 10 ND ND ------ND 10-Apr-12 0.23 3.0 0.30 B ND ND 3.5 8.8 ND ND ------0.32 J 15-Oct-12 0.23 3.0 0.25 J ND ND 1.7 J 7.0 ND ND ------ND 16-Apr-13 0.23 3.0 1.2 J ND 1.3 J ND 9.4 ND ND ND ---ND 08-Oct-13 0.23 3.0 1.1 J ND ND 2.3 J 10.0 ND ND ------ND 29-Apr-14 0.23 3.0 0.67 J ND ND 1.3 J 10.5 ND ND ------ND 14-Oct-14 0.23 3.0 0.56 J ND ND 4.3 8.7 ND ND ------ND 09-Apr-15 0.23 3.0 0.72 J ND ND 1.9 J 6.7 ND ND ------ND 27-Oct-15 0.23 3.0 0.77 J ND ND 4.8 8.1 ND ND ND ---ND 21-Apr-16 0.062 3.0 0.67 J ND ND 3.0 11 ND ND ------ND 11-Oct-16 0.23 3.0 0.54 J ND ND 6.8 8.9 ND ND ------ND 18-Apr-17 0.23 3.0 ND ND ND 4.9 9.9 ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 10 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Chloromethane 22-Dec-08 0.1 1.0 ND ND ND ND ND ND ND 0.2 J ---ND NC 2L = 2.6 µg/L (10/23/07)23-Jun-09 0.1 1.0 ND ND (ND)ND ND ND ND ND ND ---ND NC 2B = NE (05/01/07)15-Dec-09 0.1 1.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2L = 3 µg/L (01/01/10)28-Jun-10 0.1 1.0 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.1 1.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 0.11 1.0 ND ND 0.19 J ND ND ND ND ND ---ND 18-Oct-11 0.11 1.0 0.14 J ND ND ND ND 0.16 J 0.13 J ------ND 10-Apr-12 0.11 1.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 0.11 1.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 0.11 1.0 0.43 J ND ND ND ND ND ND ND ---ND 08-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 0.11 1.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.11 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.11 1.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.11 1.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.079 1.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.11 1.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.11 1.0 ND ND ND ND ND ND ND ------ND Cis-1,2-Dichloroethene Oct-94 ---5 8 ND ND ND 11 ND ND ND ND ND Apr-95 ---5 ND ND ND ND ND ND ND ND ------ Nov-95 ---5 ND ND ND ND 8 ND ND ND ------ May-96 ---5 ND ND ND ND ND ND ND ND ------ Nov-96 ---5 ND ND ND ND ND ND ND ND ---ND Mar-97 ---5 ND ND ND ND ND ND ND ND ---ND Sep-97 ---5 ND ND ND ND ND ND ND ND ---ND Mar-98 ---5 ND ND ND ND ND ND ND ND ---ND Sep-98 ---5 ND ND ND ND ND ND ND ND ---ND Mar-99 ---5 ND ND ND ND ND ND ND ND ---ND Sep-99 ---5 ND ND ND ND ND ND ND ND ---ND May-00 ---5 ND ND ND ND ND ND ND ND ---ND Oct-00 ---5 ND ND ND ND ND ND ND ND ---ND Mar-01 ---5 ND ND ND ND ND ND ND ND ---ND Oct-01 ---5 ND ND ND ND ND ND ND ND ---ND Apr-02 ---5 ND ND ND ND ND ND ND ND ---ND Nov-02 ---5 ND ND ND ND ND ND ND ND ---ND May-03 ---5 ND ND ND ND ND ND ND ND ---ND Nov-03 ---5 ND ND ND ND ND ND ND ND ---ND Apr-04 ---5 ND ND ND ND ND ND ND ND ---ND Oct-04 ------ND ND ND ND ND ND ND ND ---ND May-05 ---5 ND ND ND ND ND ND ND ND ---ND Oct-05 ---5 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---5 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---5 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.1 5.0 ND ND ND ND ND (ND)ND ND ND ---ND NC 2L = 70 µg/L (10/23/07)28-Nov-07 0.1 5.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.1 5.0 ND ND ND ND (ND)ND ND ND ND ---ND 22-Dec-08 0.1 5.0 ND ND ND (ND)ND ND ND ND ND ---ND 23-Jun-09 0.1 5.0 ND ND (ND)ND ND ND ND ND ND ---ND 15-Dec-09 0.1 5.0 ND ND ND ND (ND)ND ND ND ND ---ND 28-Jun-10 0.1 5.0 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.1 5.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 0.19 5.0 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 0.19 5.0 ND ND ND 0.25 J ND ND ND ------ND 10-Apr-12 0.19 5.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 0.19 5.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 0.19 5.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 0.19 5.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 0.19 5.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.19 5.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.19 5.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.19 5.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.19 5.0 ND ND ND ND ND ND ND ND ---ND 11-Oct-16 0.19 5.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.19 5.0 ND ND ND ND ND ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 11 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks 1,2-Dichlorobenzene Apr-02 ---5 ND ND ND ND 5.4 ND ND ND ---ND Nov-02 ---5 ND ND ND ND 5.2 ND ND ND ---ND May-03 ---5 ND ND ND ND ND ND ND ND ---ND Nov-03 ---5 ND ND ND ND ND ND ND ND ---ND Apr-04 ---5 ND ND ND ND ND ND ND ND ---ND Oct-04 ---5 ND ND ND ND 6.7 ND ND ND ---ND May-05 ---5 ND ND ND ND ND ND ND ND ---ND Oct-05 ---5 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---5 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---5 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.1 5.0 ND ND ND ND ND (ND)ND ND ND ---ND NC 2L = 24 µg/L (10/23/07)28-Nov-07 0.1 5.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.1 5.0 ND ND ND ND (ND)0.4 J ND ND ND ---ND 22-Dec-08 0.1 5.0 ND ND ND (ND)ND 0.3 J ND ND ND ---ND 23-Jun-09 0.1 5.0 ND ND (ND)ND ND 0.4 J ND ND ND ---ND 15-Dec-09 0.1 5.0 ND ND ND ND (ND)0.4 J ND ND ND ---ND NC 2L = 20 µg/L (01/01/10)28-Jun-10 0.1 5.0 ND ND ND ND 0.2 (0.2 J)J ND ND ND ---ND 02-Nov-10 0.1 5.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 0.30 5.0 ND ND ND ND 0.34 J ND ND ND ---ND 18-Oct-11 0.30 5.0 ND ND ND ND 0.32 J ND ND ------ND 10-Apr-12 0.30 5.0 ND ND ND ND 0.32 J ND ND ------ND 15-Oct-12 0.30 5.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 0.30 5.0 0.81 J ND ND ND 0.38 J ND ND ND ---ND 08-Oct-13 0.30 5.0 ND ND ND ND 0.37 J ND ND ------ND 29-Apr-14 0.30 5.0 ND ND ND ND 0.45 J ND ND ------ND 14-Oct-14 0.30 5.0 ND ND ND ND 0.33 J ND ND ------ND 09-Apr-15 0.30 5.0 ND ND ND 1.2 J ND ND ND ------ND 27-Oct-15 0.30 5.0 ND ND ND ND 0.32 J ND ND ND ---ND 21-Apr-16 0.076 5.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.30 5.0 ND ND ND ND 0.33 J ND ND ------ND 18-Apr-17 0.30 5.0 ND ND ND ND 0.34 J ND ND ------ND 1,4-Dichlorobenzene Mar-98 ---5 ND ND ND 6 7 ND ND ND ---ND Sep-98 ---5 ND ND ND 5 5 ND ND ND ---ND Mar-99 ---5 ND ND ND ND 5 ND ND ND ---ND Sep-99 ---5 ND ND ND 7.8 ND ND ND ND ---ND May-00 ---5 ND ND ND 6.9 6 ND ND ND ---ND Oct-00 ---5 ND ND ND 6.1(5.7)5 ND ND ND ---ND Mar-01 ---5 ND ND ND ND 5.5 ND ND ND ---ND Oct-01 ---5 ND ND ND ND 5.3 ND ND ND ---ND Apr-02 ---5 ND ND ND ND ND ND ND ND ---ND Nov-02 ---5 ND ND ND ND ND ND ND ND ---ND May-03 ---5 ND ND ND 5.0(5.1)5.8 ND ND ND ---ND Nov-03 ---5 ND ND ND ND 5.5(5.0)ND ND ND ---ND Apr-04 ---5 ND ND ND ND 6.0 ND ND ND ---ND Oct-04 ------ND ND ND ND 5.3 ND ND ND ---ND May-05 ---5 ND ND ND ND ND ND ND ND ---ND Oct-05 ---5 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---5 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---5 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.1 1.0 ND ND ND 2.2 4.8 (5.0)ND ND 2.8 ---ND NC 2L = 1.4 µg/L (10/23/07)28-Nov-07 0.1 1.0 ND ND ND 2.8 (3.2)3.2 ND ND 1.4 ---ND NC 2B = NE (05/01/07)21-Apr-08 0.1 1.0 ND ND ND 3.3 (3.3)4.5 ND ND 1.6 ---ND 22-Dec-08 0.1 1.0 ND ND ND (ND)2.1 4.4 ND ND 1.2 ---ND 23-Jun-09 0.1 1.0 ND ND (3.3)ND 1.6 4.1 ND ND 2.3 ---ND 15-Dec-09 0.1 1.0 ND ND ND 2.2 (2.0)4.8 ND ND 1.8 ---ND NC 2L = 6 µg/L (01/01/10)28-Jun-10 0.1 1.0 0.1 J ND ND 1.0 3.4 (3.4)ND ND 1.8 ---ND 02-Nov-10 0.1 1.0 ND ND ND (ND)1.6 2.9 ND ND 1.3 ---ND 12-Apr-11 0.33 1.0 ND ND ND ND 4.6 ND ND ND ---ND 18-Oct-11 0.33 1.0 0.53 J ND ND 2.6 4.2 ND ND ------ND 10-Apr-12 0.33 1.0 0.38 J ND ND 2.0 4.2 ND ND ------ND 15-Oct-12 0.33 1.0 0.41 J ND ND 1.9 3.3 ND ND ------ND 16-Apr-13 0.33 1.0 ND ND 1.2 ND 4.6 ND ND ND ---ND 08-Oct-13 0.33 1.0 0.50 J ND ND 2.1 4.4 ND ND ------ND 29-Apr-14 0.33 1.0 ND ND ND 1.6 5.1 ND ND ------ND 14-Oct-14 0.33 1.0 ND ND ND 2.4 3.7 ND ND ------ND 09-Apr-15 0.33 1.0 0.36 J ND ND 1.1 3.0 ND ND ------ND 27-Oct-15 0.33 1.0 0.45 J ND ND 2.2 3.4 ND ND ND ---ND 21-Apr-16 0.05 1.0 ND ND ND 2.6 4.6 ND ND ------ND 11-Oct-16 0.33 1.0 ND ND ND 3.5 3.7 ND ND ------ND 18-Apr-17 0.33 1.0 0.35 J ND ND 2.2 3.9 ND ND ------ND Wilkes County Germantown Landfill Permit No. 97-01 page 12 of 13 Joyce Engineering TABLE 1 Summary of Historically Detected Constituents Sample Analyte Collection Date DL QL MW-1 MW-2 MW-3 MW-4 MW-5 Upstream Downstream Outfall #1 Outfall #2 Blanks Methylene Chloride 16-Apr-13 0.97 1.0 2.4 B 2.7 B 2.6 B 2.7 B 2.4 B 2.5 B 2.5 B 2.5 B ---3.2 NC 2L = 5µg/L (01/01/10)08-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ------1.2 NC 2B = NE (05/01/07)29-Apr-14 0.97 1.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.97 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.97 1.0 ND ND ND ND ND ND ND ------1.3 27-Oct-15 0.97 1.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.083 1.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.97 1.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.97 1.0 ND ND ND ND ND ND ND ------1.2 C9 Styrene 16-Apr-13 0.26 1.0 0.78 J ND ND ND ND ND ND ND ND ND NC 2L = 70µg/L (01/01/10)08-Oct-13 0.26 1.0 ND ND ND ND ND ND ND ------ND NC 2B = NE (05/01/07)29-Apr-14 0.26 1.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.26 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.26 1.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.26 1.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.047 1.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.26 1.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.26 1.0 ND ND ND ND ND ND ND ------ND Toluene 16-Apr-13 0.26 1.0 0.37 J ND ND ND ND ND ND ND ND ND NC 2L = 600µg/L (01/01/10)08-Oct-13 0.26 1.0 ND ND ND ND ND ND ND ------ND NC 2B = 11 (05/01/07)29-Apr-14 0.26 1.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.26 1.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.26 1.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.26 1.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.044 1.0 ND ND ND ND ND ND ND ------ND 11-Oct-16 0.26 1.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.26 1.0 ND ND ND ND ND ND ND ------ND Xylene (Total)Apr-02 ---5 ND 9.3 ND ND ND ND ND ND ---ND Nov-02 ---5 ND ND ND ND ND ND ND ND ---ND May-03 ---5 ND ND ND ND ND ND ND ND ---ND Nov-03 ---5 ND ND ND ND ND ND ND ND ---ND Apr-04 ---5 ND ND ND ND ND ND ND ND ---ND Oct-04 ------ND ND ND ND ND ND ND ND ---ND May-05 ---5 ND ND ND ND ND ND ND ND ---ND Oct-05 ---5 ND ND ND ND ND ND ND ND ---ND 23-May-06 ---5 ND ND ND ND ND ND ND ND ---ND 09-Nov-06 ---5 ND ND ND ND ND ND ND ND ---ND 19-Jun-07 0.3 4.0 ND ND ND ND ND (ND)ND ND ND ---ND NC 2L = 530 µg/L (10/23/07)28-Nov-07 0.3 4.0 ND ND ND ND (ND)ND ND ND ND ---ND NC 2B = NE (05/01/07)21-Apr-08 0.3 4.0 ND ND ND ND (ND)0.4 J ND ND 1.3 J ---ND 22-Dec-08 0.3 4.0 ND ND ND (ND)ND ND ND ND ND ---ND 23-Jun-09 0.3 4.0 ND ND (ND)ND ND ND ND ND 1.2 J ---ND 15-Dec-09 0.3 5.0 ND ND ND ND (ND)ND ND ND 1.2 J ---ND NC 2L = 5,000 µg/L (01/01/10)28-Jun-10 0.3 5.0 ND ND ND ND ND (ND)ND ND ND ---ND 02-Nov-10 0.3 5.0 ND ND ND (ND)ND ND ND ND ND ---ND 12-Apr-11 0.66 2.0 ND ND ND ND ND ND ND ND ---ND 18-Oct-11 0.66 2.0 ND ND ND ND ND ND ND ------ND 10-Apr-12 0.66 2.0 ND ND ND ND ND ND ND ------ND 15-Oct-12 0.66 5.0 ND ND ND ND ND ND ND ------ND 16-Apr-13 0.66 5.0 ND ND ND ND ND ND ND ND ---ND 08-Oct-13 0.66 5.0 ND ND ND ND ND ND ND ------ND 29-Apr-14 0.66 5.0 ND ND ND ND ND ND ND ------ND 14-Oct-14 0.66 5.0 ND ND ND ND ND ND ND ------ND 09-Apr-15 0.66 5.0 ND ND ND ND ND ND ND ------ND 27-Oct-15 0.66 5.0 ND ND ND ND ND ND ND ND ---ND 21-Apr-16 0.15 5.0 ND ND ND ND 0.52 J ND ND ------ND 11-Oct-16 0.66 5.0 ND ND ND ND ND ND ND ------ND 18-Apr-17 0.66 5.0 ND ND ND ND ND ND ND ------ND Notes: All concentrations are reported in micrograms per liter (mg/L). Values shown in parentheses are from duplicate samples. MW = Groundwater monitoring well. DL = Laboratory detection limit. QL = Laboratory reporting limit ( NC SWSL {or lower} From June 2007 to present). B = Reported detect considered to represent blank contamination. --- = Not sampled and/or not reported NC 2L = North Carolina's groundwater quality Standard established under 15A NCAC 2L, .0202. J = Estimate concetrations. GWPS = Groundwater Protection Standards. NC 2B = North Carolina Surface Water Standard. Bold values are above the NC 2L, GWPS and/or NC 2B. Wilkes County Germantown Landfill Permit No. 97-01 page 13 of 13 Joyce Engineering TABLE 2 Summary of Historical Groundwater Elevations MW-1 MW-2 MW-3 MW-4 MW-5 TOC Elevation 1233.00 1177.85 1059.00 1018.00 1045.75 Well Depth 89.69 81.54 64.00 28.21 23.47 Apr-13 1178.75 1131.92 1015.73 1006.25 1036.85 Oct-13 1182.76 1130.85 1016.00 1005.30 1036.17 Apr-14 1182.86 1131.85 1016.20 1006.75 1037.05 Oct-14 1180.81 1129.79 1015.49 1004.49 1036.40 Apr-15 1178.96 1130.81 1015.51 1005.07 1036.59 Oct-15 1177.15 1131.00 1013.10 1004.15 1035.80 Apr-16 1187.15 1132.85 1016.79 1006.45 1036.34 Oct-16 1180.12 1129.75 1015.20 1003.50 1034.97 Apr-17 1175.28 1129.20 1014.50 1002.86 1034.94 Notes: TOC = Top of Casing Location Wilkes County Germantown Landfill Permit No. 97-01 Joyce Engineering Figure Drawing 1 2 2 01210 120 0 1200 1190 118 0 1190 1180 1170 1160 1050125012201 2 3 0 12 4 012101200 11601170118011901160 1150 1140 1130 1120 1110 108010901100111011201130114011501100 1090 1080 1070 1060 1050 1040 1030 1020 1070 1060 105010401030101 0 1010 101 0 114011501 1 4 0 1 1 4 0 115011201140 1 130 1 1 2 010801070 1060 1130 10601070108010901100111011201120113010301 0 4 0 1 0 5 010601 0 7 0 1 0 8 0 10 9 0 1 1 0 011101 1 2 0 11 3 0 1 1 4 01110 1010 10 1 0 1150CLOSED LANDFILL EXIST. GAS VENT (TYP.) GV GV GV GV GV GV EXISTING FIREFIGHTER TRAINING FACILITY APPROX. LOCATION OF EDGE OF CAP EMERGENCY/ DISASTER DEBRIS PROCESSING AREA (2 ACRES) (NOT MONITORED) GP-2 GP-1 EXISTING POLE BARN EXISTING GARAGE EXISTING OFFICES APPROXIMATE LOCATION OF PROPERTY LINE MORAVIAN CREEK MORAVIAN CREEK GP-4 GW-2 GW-4 GW-3 GW-1 GREENHOUSE SEDIMENT BASIN LEGEND EDGE OF LINER PAVED ROAD EXISTING 2 FT CONTOUR EXISTING 10 FT CONTOUR GRAVEL ROAD GROUNDWATER MONITORING WELL LOCATION, IDENTIFICATION, AND GROUNDWATER ELEVATION POINT IN TIME GROUNDWATER CONTOUR (APPROXIMATE) 1 FT. CONTOUR INTERVAL GROUNDWATER FLOW PATHWAY USED TO CALCULATE HYDRAULIC GRADIENT i 1SEGMENT USED FOR GRADIENT CALCULATION MW-3 1014.50 1.STATIC WATER LEVELS MEASURED ON APRIL 18, 2017. 2.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE, GROUNDWATER CONTOURS MUST BE ASSUMED TO BE APPROXIMATE. 3.GROUNDWATER ELEVATIONS ARE MEASURED IN FEET AND REFERENCED TO MEAN SEA LEVEL. 1140 NOT MONITORED NM SEGMENT LENGTH i1 i2 = 382 LF = 801 LF = 1,036 LF 119011801 1 7 0 116 0 MW-1 1175.28 MW-2 1129.20 MW-3 1014.50 MW-4 1002.86 MW-5 1034.94 1040 1060 1080 1100 1140 1160 1160 10401060 1120i1 i 2 i 3 i3 PROPERTY LINE STREAM 1120 11 4 0 1020 10101010102010401120114011201140110010801060 PROJECT NO.APPROVEDCHECKEDDRAWNDESIGNEDDATEDATEREVISIONS AND RECORD OF ISSUEBYNOAPPCKSCALE All rights reserved.Ó Joyce Engineering, Inc.DRAWING NO.L:\Wilkes\GERMANTOWN\dwg\GW MAPS\GW MAP APRIL 2017.dwg Layout=Layout12211 W. MEADOWVIEW ROADGREENSBORO, NC 27407PHONE: (336) 323-0092NC CORP LIC: C-0782356GERMANTOWN LANDFILLWILKES COUNTY, NORTH CAROLINA20171 AS SHOWNGROUNDWATER CONTOUR MAPAPRIL 18. 2017GERWHVBVB07/05/170 (FEET) GRAPHIC SCALE 20010050 Appendices Appendix 1 Laboratory Analytical Reports and Field Data Logs Appendix 2 Summary of Detections, Exceedances, and Field Parameters Appendix 3 Horizontal Groundwater Flow Velocities Appendix 1 Laboratory Analytical Reports and Field Data Logs #=CL# May 02, 2017 LIMS USE: FR - VAN BURBACH LIMS OBJECT ID: 92337680 92337680 Project: Pace Project No.: RE: Mr. Van Burbach Joyce Engineering-NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 Wilkes-Germantown 356.1701.12 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on April 19, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com Project Manager 1(704)875-9092 Enclosures cc:Gretta Eller, Joyce Engineering Mr. Daniel Girdner, Joyce Engineering-Greensboro Haley Seaton, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 1 of 38 #=CP# CERTIFICATIONS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 38 #=SS# SAMPLE SUMMARY Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Lab ID Sample ID Matrix Date Collected Date Received 92337680001 9701-MW1 Water 04/18/17 13:45 04/19/17 10:23 92337680002 9701-MW2 Water 04/18/17 16:11 04/19/17 10:23 92337680003 9701-MW3 Water 04/18/17 15:25 04/19/17 10:23 92337680004 9701-MW4 Water 04/18/17 16:00 04/19/17 10:23 92337680005 9701-MW5 Water 04/18/17 15:57 04/19/17 10:23 92337680006 9701-Upstream Water 04/18/17 15:00 04/19/17 10:23 92337680007 9701-Downstream Water 04/18/17 14:50 04/19/17 10:23 92337680008 9701-Field Blank Water 04/18/17 16:15 04/19/17 10:23 92337680009 9701-Trip Blank Water 04/17/17 07:30 04/19/17 10:23 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 3 of 38 #=SA# SAMPLE ANALYTE COUNT Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Lab ID Sample ID Method Analytes Reported LaboratoryAnalysts 92337680001 9701-MW1 EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680002 9701-MW2 EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680003 9701-MW3 EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680004 9701-MW4 EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680005 9701-MW5 EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680006 9701-Upstream EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680007 9701-Downstream EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680008 9701-Field Blank EPA 6010 14 PASI-ASH1 EPA 6020B 1 PASI-ACDF EPA 8260 50 PASI-CZDO 92337680009 9701-Trip Blank EPA 8260 50 PASI-CZDO REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 4 of 38 #=HO# SUMMARY OF DETECTION Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Parameters AnalyzedResult Lab Sample ID Report Limit QualifiersUnitsMethod Client Sample ID 92337680001 9701-MW1 Barium 101 ug/L 04/22/17 22:00100EPA 6010 1,4-Dichlorobenzene 0.35J ug/L 04/25/17 21:131.0EPA 8260 92337680002 9701-MW2 Barium 9.9J ug/L 04/22/17 22:03100EPA 6010 Zinc 5.6J ug/L 04/22/17 22:0310.0EPA 6010 Thallium 0.092J ug/L 04/21/17 18:245.5EPA 6020B 92337680003 9701-MW3 Barium 9.2J ug/L 04/22/17 22:07100EPA 6010 92337680004 9701-MW4 Barium 85.4J ug/L 04/22/17 22:19100EPA 6010 Cobalt 13.3 ug/L 04/22/17 22:1910.0EPA 6010 Nickel 4.1J ug/L 04/22/17 22:1950.0EPA 6010 Vanadium 7.6J ug/L 04/22/17 22:1925.0EPA 6010 Benzene 0.35J ug/L 04/25/17 22:041.0EPA 8260 Chlorobenzene 4.9 ug/L 04/25/17 22:043.0EPA 8260 1,4-Dichlorobenzene 2.2 ug/L 04/25/17 22:041.0EPA 8260 92337680005 9701-MW5 Barium 412 ug/L 04/22/17 22:22100EPA 6010 Chromium 5.1J ug/L 04/22/17 22:2210.0EPA 6010 Cobalt 15.4 ug/L 04/22/17 22:2210.0EPA 6010 Lead 5.3J ug/L 04/22/17 22:2210.0EPA 6010 Nickel 10.8J ug/L 04/22/17 22:2250.0EPA 6010 Vanadium 16.5J ug/L 04/22/17 22:2225.0EPA 6010 Zinc 14.7 ug/L 04/22/17 22:2210.0EPA 6010 Thallium 0.025J ug/L 04/21/17 18:305.5EPA 6020B Benzene 1.1 ug/L 04/25/17 22:211.0EPA 8260 Chlorobenzene 9.9 ug/L 04/25/17 22:213.0EPA 8260 1,2-Dichlorobenzene 0.34J ug/L 04/25/17 22:215.0EPA 8260 1,4-Dichlorobenzene 3.9 ug/L 04/25/17 22:211.0EPA 8260 92337680006 9701-Upstream Barium 18.8J ug/L 04/29/17 04:12100EPA 6010 92337680007 9701-Downstream Barium 17.7J ug/L 04/29/17 04:21100EPA 6010 92337680008 9701-Field Blank Methylene Chloride 1.2 ug/L 04/25/17 23:11 C91.0EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 5 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW1 Lab ID:92337680001 Collected:04/18/17 13:45 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/22/17 22:00 7440-36-004/21/17 17:036.0 3.9 1 Arsenic ND ug/L 04/22/17 22:00 7440-38-204/21/17 17:0310.0 5.0 1 Barium 101 ug/L 04/22/17 22:00 7440-39-304/21/17 17:031002.5 1 Beryllium ND ug/L 04/22/17 22:00 7440-41-704/21/17 17:031.0 0.50 1 Cadmium ND ug/L 04/22/17 22:00 7440-43-904/21/17 17:031.0 0.50 1 Chromium ND ug/L 04/22/17 22:00 7440-47-304/21/17 17:0310.0 2.5 1 Cobalt ND ug/L 04/22/17 22:00 7440-48-404/21/17 17:0310.0 2.5 1 Copper ND ug/L 04/22/17 22:00 7440-50-804/21/17 17:0310.0 2.5 1 Lead ND ug/L 04/22/17 22:00 7439-92-104/21/17 17:0310.0 2.5 1 Nickel ND ug/L 04/22/17 22:00 7440-02-004/21/17 17:0350.0 2.5 1 Selenium ND ug/L 04/22/17 22:00 7782-49-204/21/17 17:0310.0 5.0 1 Silver ND ug/L 04/22/17 22:00 7440-22-404/21/17 17:0310.0 2.5 1 Vanadium ND ug/L 04/22/17 22:00 7440-62-204/21/17 17:0325.0 2.5 1 Zinc ND ug/L 04/22/17 22:00 7440-66-604/21/17 17:0310.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:22 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 21:13 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 21:13 107-13-12001.9 1 Benzene ND ug/L 04/25/17 21:13 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 21:13 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 21:13 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 21:13 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 21:13 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 21:13 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 21:13 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 21:13 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 21:13 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 21:13 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 21:13 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 21:13 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 21:13 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 21:13 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 21:13 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 21:13 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 21:13 95-50-15.0 0.30 1 1,4-Dichlorobenzene 0.35J ug/L 04/25/17 21:13 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 21:13 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 21:13 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 21:13 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 21:13 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 21:13 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 21:13 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 21:13 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 6 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW1 Lab ID:92337680001 Collected:04/18/17 13:45 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 21:13 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 21:13 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 21:13 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 21:13 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 21:13 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 21:13 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 21:13 108-10-11000.33 1 Styrene ND ug/L 04/25/17 21:13 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 21:13 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 21:13 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 21:13 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 21:13 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 21:13 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 21:13 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 21:13 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 21:13 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 21:13 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 21:13 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 21:13 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 21:13 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)96 %04/25/17 21:13 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %04/25/17 21:13 17060-07-070-130 1 Toluene-d8 (S)101 %04/25/17 21:13 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 7 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW2 Lab ID:92337680002 Collected:04/18/17 16:11 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/22/17 22:03 7440-36-004/21/17 17:036.0 3.9 1 Arsenic ND ug/L 04/22/17 22:03 7440-38-204/21/17 17:0310.0 5.0 1 Barium 9.9J ug/L 04/22/17 22:03 7440-39-304/21/17 17:031002.5 1 Beryllium ND ug/L 04/22/17 22:03 7440-41-704/21/17 17:031.0 0.50 1 Cadmium ND ug/L 04/22/17 22:03 7440-43-904/21/17 17:031.0 0.50 1 Chromium ND ug/L 04/22/17 22:03 7440-47-304/21/17 17:0310.0 2.5 1 Cobalt ND ug/L 04/22/17 22:03 7440-48-404/21/17 17:0310.0 2.5 1 Copper ND ug/L 04/22/17 22:03 7440-50-804/21/17 17:0310.0 2.5 1 Lead ND ug/L 04/22/17 22:03 7439-92-104/21/17 17:0310.0 2.5 1 Nickel ND ug/L 04/22/17 22:03 7440-02-004/21/17 17:0350.0 2.5 1 Selenium ND ug/L 04/22/17 22:03 7782-49-204/21/17 17:0310.0 5.0 1 Silver ND ug/L 04/22/17 22:03 7440-22-404/21/17 17:0310.0 2.5 1 Vanadium ND ug/L 04/22/17 22:03 7440-62-204/21/17 17:0325.0 2.5 1 Zinc 5.6J ug/L 04/22/17 22:03 7440-66-604/21/17 17:0310.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium 0.092J ug/L 04/21/17 18:24 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 21:30 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 21:30 107-13-12001.9 1 Benzene ND ug/L 04/25/17 21:30 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 21:30 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 21:30 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 21:30 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 21:30 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 21:30 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 21:30 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 21:30 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 21:30 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 21:30 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 21:30 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 21:30 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 21:30 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 21:30 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 21:30 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 21:30 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 21:30 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 21:30 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 21:30 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 21:30 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 21:30 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 21:30 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 21:30 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 21:30 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 21:30 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 8 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW2 Lab ID:92337680002 Collected:04/18/17 16:11 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 21:30 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 21:30 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 21:30 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 21:30 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 21:30 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 21:30 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 21:30 108-10-11000.33 1 Styrene ND ug/L 04/25/17 21:30 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 21:30 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 21:30 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 21:30 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 21:30 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 21:30 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 21:30 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 21:30 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 21:30 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 21:30 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 21:30 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 21:30 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 21:30 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %04/25/17 21:30 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/25/17 21:30 17060-07-070-130 1 Toluene-d8 (S)102 %04/25/17 21:30 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 9 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW3 Lab ID:92337680003 Collected:04/18/17 15:25 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/22/17 22:07 7440-36-004/21/17 17:036.0 3.9 1 Arsenic ND ug/L 04/22/17 22:07 7440-38-204/21/17 17:0310.0 5.0 1 Barium 9.2J ug/L 04/22/17 22:07 7440-39-304/21/17 17:031002.5 1 Beryllium ND ug/L 04/22/17 22:07 7440-41-704/21/17 17:031.0 0.50 1 Cadmium ND ug/L 04/22/17 22:07 7440-43-904/21/17 17:031.0 0.50 1 Chromium ND ug/L 04/22/17 22:07 7440-47-304/21/17 17:0310.0 2.5 1 Cobalt ND ug/L 04/22/17 22:07 7440-48-404/21/17 17:0310.0 2.5 1 Copper ND ug/L 04/22/17 22:07 7440-50-804/21/17 17:0310.0 2.5 1 Lead ND ug/L 04/22/17 22:07 7439-92-104/21/17 17:0310.0 2.5 1 Nickel ND ug/L 04/22/17 22:07 7440-02-004/21/17 17:0350.0 2.5 1 Selenium ND ug/L 04/22/17 22:07 7782-49-204/21/17 17:0310.0 5.0 1 Silver ND ug/L 04/22/17 22:07 7440-22-404/21/17 17:0310.0 2.5 1 Vanadium ND ug/L 04/22/17 22:07 7440-62-204/21/17 17:0325.0 2.5 1 Zinc ND ug/L 04/22/17 22:07 7440-66-604/21/17 17:0310.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:26 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 21:47 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 21:47 107-13-12001.9 1 Benzene ND ug/L 04/25/17 21:47 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 21:47 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 21:47 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 21:47 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 21:47 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 21:47 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 21:47 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 21:47 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 21:47 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 21:47 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 21:47 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 21:47 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 21:47 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 21:47 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 21:47 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 21:47 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 21:47 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 21:47 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 21:47 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 21:47 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 21:47 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 21:47 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 21:47 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 21:47 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 21:47 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 10 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW3 Lab ID:92337680003 Collected:04/18/17 15:25 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 21:47 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 21:47 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 21:47 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 21:47 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 21:47 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 21:47 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 21:47 108-10-11000.33 1 Styrene ND ug/L 04/25/17 21:47 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 21:47 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 21:47 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 21:47 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 21:47 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 21:47 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 21:47 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 21:47 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 21:47 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 21:47 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 21:47 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 21:47 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 21:47 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)98 %04/25/17 21:47 460-00-470-130 1 1,2-Dichloroethane-d4 (S)98 %04/25/17 21:47 17060-07-070-130 1 Toluene-d8 (S)101 %04/25/17 21:47 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 11 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW4 Lab ID:92337680004 Collected:04/18/17 16:00 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/22/17 22:19 7440-36-004/21/17 17:036.0 3.9 1 Arsenic ND ug/L 04/22/17 22:19 7440-38-204/21/17 17:0310.0 5.0 1 Barium 85.4J ug/L 04/22/17 22:19 7440-39-304/21/17 17:031002.5 1 Beryllium ND ug/L 04/22/17 22:19 7440-41-704/21/17 17:031.0 0.50 1 Cadmium ND ug/L 04/22/17 22:19 7440-43-904/21/17 17:031.0 0.50 1 Chromium ND ug/L 04/22/17 22:19 7440-47-304/21/17 17:0310.0 2.5 1 Cobalt 13.3 ug/L 04/22/17 22:19 7440-48-404/21/17 17:0310.0 2.5 1 Copper ND ug/L 04/22/17 22:19 7440-50-804/21/17 17:0310.0 2.5 1 Lead ND ug/L 04/22/17 22:19 7439-92-104/21/17 17:0310.0 2.5 1 Nickel 4.1J ug/L 04/22/17 22:19 7440-02-004/21/17 17:0350.0 2.5 1 Selenium ND ug/L 04/22/17 22:19 7782-49-204/21/17 17:0310.0 5.0 1 Silver ND ug/L 04/22/17 22:19 7440-22-404/21/17 17:0310.0 2.5 1 Vanadium 7.6J ug/L 04/22/17 22:19 7440-62-204/21/17 17:0325.0 2.5 1 Zinc ND ug/L 04/22/17 22:19 7440-66-604/21/17 17:0310.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:28 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 22:04 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 22:04 107-13-12001.9 1 Benzene 0.35J ug/L 04/25/17 22:04 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 22:04 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 22:04 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 22:04 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 22:04 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 22:04 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 22:04 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 22:04 56-23-51.0 0.25 1 Chlorobenzene 4.9 ug/L 04/25/17 22:04 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 22:04 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 22:04 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 22:04 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 22:04 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 22:04 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 22:04 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 22:04 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 22:04 95-50-15.0 0.30 1 1,4-Dichlorobenzene 2.2 ug/L 04/25/17 22:04 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 22:04 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 22:04 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 22:04 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 22:04 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 22:04 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 22:04 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 22:04 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 12 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW4 Lab ID:92337680004 Collected:04/18/17 16:00 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 22:04 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 22:04 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 22:04 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 22:04 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 22:04 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 22:04 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 22:04 108-10-11000.33 1 Styrene ND ug/L 04/25/17 22:04 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 22:04 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 22:04 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 22:04 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 22:04 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 22:04 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 22:04 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 22:04 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 22:04 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 22:04 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 22:04 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 22:04 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 22:04 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %04/25/17 22:04 460-00-470-130 1 1,2-Dichloroethane-d4 (S)100 %04/25/17 22:04 17060-07-070-130 1 Toluene-d8 (S)102 %04/25/17 22:04 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 13 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW5 Lab ID:92337680005 Collected:04/18/17 15:57 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/22/17 22:22 7440-36-004/21/17 17:036.0 3.9 1 Arsenic ND ug/L 04/22/17 22:22 7440-38-204/21/17 17:0310.0 5.0 1 Barium 412 ug/L 04/22/17 22:22 7440-39-304/21/17 17:031002.5 1 Beryllium ND ug/L 04/22/17 22:22 7440-41-704/21/17 17:031.0 0.50 1 Cadmium ND ug/L 04/22/17 22:22 7440-43-904/21/17 17:031.0 0.50 1 Chromium 5.1J ug/L 04/22/17 22:22 7440-47-304/21/17 17:0310.0 2.5 1 Cobalt 15.4 ug/L 04/22/17 22:22 7440-48-404/21/17 17:0310.0 2.5 1 Copper ND ug/L 04/22/17 22:22 7440-50-804/21/17 17:0310.0 2.5 1 Lead 5.3J ug/L 04/22/17 22:22 7439-92-104/21/17 17:0310.0 2.5 1 Nickel 10.8J ug/L 04/22/17 22:22 7440-02-004/21/17 17:0350.0 2.5 1 Selenium ND ug/L 04/22/17 22:22 7782-49-204/21/17 17:0310.0 5.0 1 Silver ND ug/L 04/22/17 22:22 7440-22-404/21/17 17:0310.0 2.5 1 Vanadium 16.5J ug/L 04/22/17 22:22 7440-62-204/21/17 17:0325.0 2.5 1 Zinc 14.7 ug/L 04/22/17 22:22 7440-66-604/21/17 17:0310.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium 0.025J ug/L 04/21/17 18:30 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 22:21 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 22:21 107-13-12001.9 1 Benzene 1.1 ug/L 04/25/17 22:21 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 22:21 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 22:21 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 22:21 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 22:21 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 22:21 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 22:21 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 22:21 56-23-51.0 0.25 1 Chlorobenzene 9.9 ug/L 04/25/17 22:21 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 22:21 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 22:21 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 22:21 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 22:21 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 22:21 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 22:21 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 22:21 74-95-310.0 0.21 1 1,2-Dichlorobenzene 0.34J ug/L 04/25/17 22:21 95-50-15.0 0.30 1 1,4-Dichlorobenzene 3.9 ug/L 04/25/17 22:21 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 22:21 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 22:21 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 22:21 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 22:21 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 22:21 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 22:21 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 22:21 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 14 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-MW5 Lab ID:92337680005 Collected:04/18/17 15:57 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 22:21 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 22:21 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 22:21 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 22:21 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 22:21 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 22:21 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 22:21 108-10-11000.33 1 Styrene ND ug/L 04/25/17 22:21 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 22:21 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 22:21 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 22:21 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 22:21 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 22:21 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 22:21 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 22:21 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 22:21 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 22:21 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 22:21 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 22:21 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 22:21 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)100 %04/25/17 22:21 460-00-470-130 1 1,2-Dichloroethane-d4 (S)102 %04/25/17 22:21 17060-07-070-130 1 Toluene-d8 (S)102 %04/25/17 22:21 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 15 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Upstream Lab ID:92337680006 Collected:04/18/17 15:00 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/29/17 04:12 7440-36-004/21/17 10:306.0 3.9 1 Arsenic ND ug/L 04/29/17 04:12 7440-38-204/21/17 10:3010.0 5.0 1 Barium 18.8J ug/L 04/29/17 04:12 7440-39-304/21/17 10:301002.5 1 Beryllium ND ug/L 04/29/17 04:12 7440-41-704/21/17 10:301.0 0.50 1 Cadmium ND ug/L 04/29/17 04:12 7440-43-904/21/17 10:301.0 0.50 1 Chromium ND ug/L 04/29/17 04:12 7440-47-304/21/17 10:3010.0 2.5 1 Cobalt ND ug/L 04/29/17 04:12 7440-48-404/21/17 10:3010.0 2.5 1 Copper ND ug/L 04/29/17 04:12 7440-50-804/21/17 10:3010.0 2.5 1 Lead ND ug/L 04/29/17 04:12 7439-92-104/21/17 10:3010.0 2.5 1 Nickel ND ug/L 04/29/17 04:12 7440-02-004/21/17 10:3050.0 2.5 1 Selenium ND ug/L 04/29/17 04:12 7782-49-204/21/17 10:3010.0 5.0 1 Silver ND ug/L 04/29/17 04:12 7440-22-404/21/17 10:3010.0 2.5 1 Vanadium ND ug/L 04/29/17 04:12 7440-62-204/21/17 10:3025.0 2.5 1 Zinc ND ug/L 04/29/17 04:12 7440-66-604/21/17 10:3010.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:32 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 22:37 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 22:37 107-13-12001.9 1 Benzene ND ug/L 04/25/17 22:37 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 22:37 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 22:37 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 22:37 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 22:37 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 22:37 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 22:37 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 22:37 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 22:37 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 22:37 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 22:37 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 22:37 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 22:37 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 22:37 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 22:37 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 22:37 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 22:37 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 22:37 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 22:37 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 22:37 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 22:37 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 22:37 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 22:37 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 22:37 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 22:37 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 16 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Upstream Lab ID:92337680006 Collected:04/18/17 15:00 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 22:37 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 22:37 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 22:37 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 22:37 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 22:37 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 22:37 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 22:37 108-10-11000.33 1 Styrene ND ug/L 04/25/17 22:37 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 22:37 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 22:37 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 22:37 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 22:37 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 22:37 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 22:37 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 22:37 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 22:37 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 22:37 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 22:37 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 22:37 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 22:37 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %04/25/17 22:37 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %04/25/17 22:37 17060-07-070-130 1 Toluene-d8 (S)103 %04/25/17 22:37 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 17 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Downstream Lab ID:92337680007 Collected:04/18/17 14:50 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/29/17 04:21 7440-36-004/21/17 10:306.0 3.9 1 Arsenic ND ug/L 04/29/17 04:21 7440-38-204/21/17 10:3010.0 5.0 1 Barium 17.7J ug/L 04/29/17 04:21 7440-39-304/21/17 10:301002.5 1 Beryllium ND ug/L 04/29/17 04:21 7440-41-704/21/17 10:301.0 0.50 1 Cadmium ND ug/L 04/29/17 04:21 7440-43-904/21/17 10:301.0 0.50 1 Chromium ND ug/L 04/29/17 04:21 7440-47-304/21/17 10:3010.0 2.5 1 Cobalt ND ug/L 04/29/17 04:21 7440-48-404/21/17 10:3010.0 2.5 1 Copper ND ug/L 04/29/17 04:21 7440-50-804/21/17 10:3010.0 2.5 1 Lead ND ug/L 04/29/17 04:21 7439-92-104/21/17 10:3010.0 2.5 1 Nickel ND ug/L 04/29/17 04:21 7440-02-004/21/17 10:3050.0 2.5 1 Selenium ND ug/L 04/29/17 04:21 7782-49-204/21/17 10:3010.0 5.0 1 Silver ND ug/L 04/29/17 04:21 7440-22-404/21/17 10:3010.0 2.5 1 Vanadium ND ug/L 04/29/17 04:21 7440-62-204/21/17 10:3025.0 2.5 1 Zinc ND ug/L 04/29/17 04:21 7440-66-604/21/17 10:3010.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:34 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 22:54 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 22:54 107-13-12001.9 1 Benzene ND ug/L 04/25/17 22:54 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 22:54 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 22:54 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 22:54 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 22:54 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 22:54 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 22:54 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 22:54 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 22:54 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 22:54 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 22:54 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 22:54 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 22:54 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 22:54 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 22:54 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 22:54 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 22:54 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 22:54 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 22:54 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 22:54 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 22:54 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 22:54 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 22:54 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 22:54 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 22:54 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 18 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Downstream Lab ID:92337680007 Collected:04/18/17 14:50 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 22:54 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 22:54 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 22:54 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 22:54 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 22:54 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 22:54 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 22:54 108-10-11000.33 1 Styrene ND ug/L 04/25/17 22:54 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 22:54 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 22:54 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 22:54 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 22:54 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 22:54 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 22:54 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 22:54 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 22:54 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 22:54 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 22:54 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 22:54 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 22:54 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)86 %04/25/17 22:54 460-00-470-130 1 1,2-Dichloroethane-d4 (S)98 %04/25/17 22:54 17060-07-070-130 1 Toluene-d8 (S)101 %04/25/17 22:54 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 19 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Field Blank Lab ID:92337680008 Collected:04/18/17 16:15 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP Antimony ND ug/L 04/29/17 04:34 7440-36-004/21/17 10:306.0 3.9 1 Arsenic ND ug/L 04/29/17 04:34 7440-38-204/21/17 10:3010.0 5.0 1 Barium ND ug/L 04/29/17 04:34 7440-39-304/21/17 10:301002.5 1 Beryllium ND ug/L 04/29/17 04:34 7440-41-704/21/17 10:301.0 0.50 1 Cadmium ND ug/L 04/29/17 04:34 7440-43-904/21/17 10:301.0 0.50 1 Chromium ND ug/L 04/29/17 04:34 7440-47-304/21/17 10:3010.0 2.5 1 Cobalt ND ug/L 04/29/17 04:34 7440-48-404/21/17 10:3010.0 2.5 1 Copper ND ug/L 04/29/17 04:34 7440-50-804/21/17 10:3010.0 2.5 1 Lead ND ug/L 04/29/17 04:34 7439-92-104/21/17 10:3010.0 2.5 1 Nickel ND ug/L 04/29/17 04:34 7440-02-004/21/17 10:3050.0 2.5 1 Selenium ND ug/L 04/29/17 04:34 7782-49-204/21/17 10:3010.0 5.0 1 Silver ND ug/L 04/29/17 04:34 7440-22-404/21/17 10:3010.0 2.5 1 Vanadium ND ug/L 04/29/17 04:34 7440-62-204/21/17 10:3025.0 2.5 1 Zinc ND ug/L 04/29/17 04:34 7440-66-604/21/17 10:3010.0 5.0 1 Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS Thallium ND ug/L 04/21/17 18:36 7440-28-004/20/17 19:385.5 0.020 1 Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 23:11 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 23:11 107-13-12001.9 1 Benzene ND ug/L 04/25/17 23:11 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 23:11 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 23:11 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 23:11 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 23:11 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 23:11 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 23:11 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 23:11 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 23:11 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 23:11 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 23:11 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 23:11 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 23:11 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 23:11 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 23:11 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 23:11 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 23:11 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 23:11 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 23:11 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 23:11 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 23:11 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 23:11 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 23:11 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 23:11 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 23:11 78-87-51.0 0.27 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 20 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Field Blank Lab ID:92337680008 Collected:04/18/17 16:15 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill cis-1,3-Dichloropropene ND ug/L 04/25/17 23:11 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 23:11 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 23:11 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 23:11 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 23:11 74-88-410.0 0.32 1 Methylene Chloride 1.2 ug/L 04/25/17 23:11 75-09-2 C91.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 23:11 108-10-11000.33 1 Styrene ND ug/L 04/25/17 23:11 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 23:11 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 23:11 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 23:11 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 23:11 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 23:11 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 23:11 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 23:11 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 23:11 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 23:11 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 23:11 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 23:11 75-01-41.0 0.62 1 Xylene (Total)ND ug/L 04/25/17 23:11 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)97 %04/25/17 23:11 460-00-470-130 1 1,2-Dichloroethane-d4 (S)99 %04/25/17 23:11 17060-07-070-130 1 Toluene-d8 (S)102 %04/25/17 23:11 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 21 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Trip Blank Lab ID:92337680009 Collected:04/17/17 07:30 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Acetone ND ug/L 04/25/17 23:28 67-64-110010.0 1 Acrylonitrile ND ug/L 04/25/17 23:28 107-13-12001.9 1 Benzene ND ug/L 04/25/17 23:28 71-43-21.0 0.25 1 Bromochloromethane ND ug/L 04/25/17 23:28 74-97-53.0 0.17 1 Bromodichloromethane ND ug/L 04/25/17 23:28 75-27-41.0 0.18 1 Bromoform ND ug/L 04/25/17 23:28 75-25-23.0 0.26 1 Bromomethane ND ug/L 04/25/17 23:28 74-83-910.0 0.29 1 2-Butanone (MEK)ND ug/L 04/25/17 23:28 78-93-31000.96 1 Carbon disulfide ND ug/L 04/25/17 23:28 75-15-01001.2 1 Carbon tetrachloride ND ug/L 04/25/17 23:28 56-23-51.0 0.25 1 Chlorobenzene ND ug/L 04/25/17 23:28 108-90-73.0 0.23 1 Chloroethane ND ug/L 04/25/17 23:28 75-00-310.0 0.54 1 Chloroform ND ug/L 04/25/17 23:28 67-66-35.0 0.14 1 Chloromethane ND ug/L 04/25/17 23:28 74-87-31.0 0.11 1 1,2-Dibromo-3-chloropropane ND ug/L 04/25/17 23:28 96-12-813.0 2.0 1 Dibromochloromethane ND ug/L 04/25/17 23:28 124-48-13.0 0.21 1 1,2-Dibromoethane (EDB)ND ug/L 04/25/17 23:28 106-93-41.0 0.27 1 Dibromomethane ND ug/L 04/25/17 23:28 74-95-310.0 0.21 1 1,2-Dichlorobenzene ND ug/L 04/25/17 23:28 95-50-15.0 0.30 1 1,4-Dichlorobenzene ND ug/L 04/25/17 23:28 106-46-71.0 0.33 1 trans-1,4-Dichloro-2-butene ND ug/L 04/25/17 23:28 110-57-61001.0 1 1,1-Dichloroethane ND ug/L 04/25/17 23:28 75-34-35.0 0.32 1 1,2-Dichloroethane ND ug/L 04/25/17 23:28 107-06-21.0 0.24 1 1,1-Dichloroethene ND ug/L 04/25/17 23:28 75-35-45.0 0.56 1 cis-1,2-Dichloroethene ND ug/L 04/25/17 23:28 156-59-25.0 0.19 1 trans-1,2-Dichloroethene ND ug/L 04/25/17 23:28 156-60-55.0 0.49 1 1,2-Dichloropropane ND ug/L 04/25/17 23:28 78-87-51.0 0.27 1 cis-1,3-Dichloropropene ND ug/L 04/25/17 23:28 10061-01-51.0 0.13 1 trans-1,3-Dichloropropene ND ug/L 04/25/17 23:28 10061-02-61.0 0.26 1 Ethylbenzene ND ug/L 04/25/17 23:28 100-41-41.0 0.30 1 2-Hexanone ND ug/L 04/25/17 23:28 591-78-650.0 0.46 1 Iodomethane ND ug/L 04/25/17 23:28 74-88-410.0 0.32 1 Methylene Chloride ND ug/L 04/25/17 23:28 75-09-21.0 0.97 1 4-Methyl-2-pentanone (MIBK)ND ug/L 04/25/17 23:28 108-10-11000.33 1 Styrene ND ug/L 04/25/17 23:28 100-42-51.0 0.26 1 1,1,1,2-Tetrachloroethane ND ug/L 04/25/17 23:28 630-20-65.0 0.33 1 1,1,2,2-Tetrachloroethane ND ug/L 04/25/17 23:28 79-34-53.0 0.40 1 Tetrachloroethene ND ug/L 04/25/17 23:28 127-18-41.0 0.46 1 Toluene ND ug/L 04/25/17 23:28 108-88-31.0 0.26 1 1,1,1-Trichloroethane ND ug/L 04/25/17 23:28 71-55-61.0 0.48 1 1,1,2-Trichloroethane ND ug/L 04/25/17 23:28 79-00-51.0 0.29 1 Trichloroethene ND ug/L 04/25/17 23:28 79-01-61.0 0.47 1 Trichlorofluoromethane ND ug/L 04/25/17 23:28 75-69-41.0 0.20 1 1,2,3-Trichloropropane ND ug/L 04/25/17 23:28 96-18-41.0 0.41 1 Vinyl acetate ND ug/L 04/25/17 23:28 108-05-450.0 0.35 1 Vinyl chloride ND ug/L 04/25/17 23:28 75-01-41.0 0.62 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 22 of 38 #=AR# ANALYTICAL RESULTS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Sample:9701-Trip Blank Lab ID:92337680009 Collected:04/17/17 07:30 Received:04/19/17 10:23 Matrix:Water Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit Report Analytical Method: EPA 82608260 MSV Low Level Landfill Xylene (Total)ND ug/L 04/25/17 23:28 1330-20-75.0 0.66 1 Surrogates 4-Bromofluorobenzene (S)99 %04/25/17 23:28 460-00-470-130 1 1,2-Dichloroethane-d4 (S)97 %04/25/17 23:28 17060-07-070-130 1 Toluene-d8 (S)102 %04/25/17 23:28 2037-26-570-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 23 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 357412 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1982610 Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005 Matrix:Water AnalyzedMDL Antimony ug/L ND 6.0 04/22/17 20:423.9 Arsenic ug/L ND 10.0 04/22/17 20:425.0 Barium ug/L ND 100 04/22/17 20:422.5 Beryllium ug/L ND 1.0 04/22/17 20:420.50 Cadmium ug/L ND 1.0 04/22/17 20:420.50 Chromium ug/L ND 10.0 04/22/17 20:422.5 Cobalt ug/L ND 10.0 04/22/17 20:422.5 Copper ug/L ND 10.0 04/22/17 20:422.5 Lead ug/L ND 10.0 04/22/17 20:422.5 Nickel ug/L ND 50.0 04/22/17 20:422.5 Selenium ug/L ND 10.0 04/22/17 20:425.0 Silver ug/L ND 10.0 04/22/17 20:422.5 Vanadium ug/L ND 25.0 04/22/17 20:422.5 Zinc ug/L ND 10.0 04/22/17 20:425.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1982611LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 489500 98 80-120 Arsenic ug/L 475500 95 80-120 Barium ug/L 523500 105 80-120 Beryllium ug/L 478500 96 80-120 Cadmium ug/L 497500 99 80-120 Chromium ug/L 508500 102 80-120 Cobalt ug/L 506500 101 80-120 Copper ug/L 503500 101 80-120 Lead ug/L 497500 99 80-120 Nickel ug/L 491500 98 80-120 Selenium ug/L 494500 99 80-120 Silver ug/L 246250 99 80-120 Vanadium ug/L 503500 101 80-120 Zinc ug/L 531500 106 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1982612MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92337771002 1982613 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 98 75-12599 1 20500ND492497 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 24 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1982612MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92337771002 1982613 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 95 75-12596 1 20500ND477481 Barium ug/L 500 104 75-125104 1 2050030.4 549 552 Beryllium ug/L 500 95 75-12596 1 20500ND477480 Cadmium ug/L 500 100 75-125100 1 20500ND498501 Chromium ug/L 500 101 75-125101 1 205009.4 513 517 Cobalt ug/L 500 101 75-125102 1 20500ND507510 Copper ug/L 500 101 75-125101 1 20500ND503507 Lead ug/L 500 99 75-125100 1 20500ND494499 Nickel ug/L 500 98 75-12598 1 20500ND489492 Selenium ug/L 500 98 75-12599 1 20500ND492498 Silver ug/L 250 98 75-12599 1 20250ND244247 Vanadium ug/L 500 102 75-125102 1 20500ND510513 Zinc ug/L 500 107 75-125107 0 20500ND537539 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 25 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 357413 EPA 3010A EPA 6010 6010 MET Associated Lab Samples:92337680006, 92337680007, 92337680008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1982616 Associated Lab Samples:92337680006, 92337680007, 92337680008 Matrix:Water AnalyzedMDL Antimony ug/L ND 6.0 04/29/17 04:063.9 Arsenic ug/L ND 10.0 04/29/17 04:065.0 Barium ug/L ND 100 04/29/17 04:062.5 Beryllium ug/L ND 1.0 04/29/17 04:060.50 Cadmium ug/L ND 1.0 04/29/17 04:060.50 Chromium ug/L ND 10.0 04/29/17 04:062.5 Cobalt ug/L ND 10.0 04/29/17 04:062.5 Copper ug/L ND 10.0 04/29/17 04:062.5 Lead ug/L ND 10.0 04/29/17 04:062.5 Nickel ug/L ND 50.0 04/29/17 04:062.5 Selenium ug/L ND 10.0 04/29/17 04:065.0 Silver ug/L ND 10.0 04/29/17 04:062.5 Vanadium ug/L ND 25.0 04/29/17 04:062.5 Zinc ug/L ND 10.0 04/29/17 04:065.0 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1982617LABORATORY CONTROL SAMPLE: LCSSpike Antimony ug/L 450500 90 80-120 Arsenic ug/L 442500 88 80-120 Barium ug/L 488500 98 80-120 Beryllium ug/L 466500 93 80-120 Cadmium ug/L 466500 93 80-120 Chromium ug/L 462500 92 80-120 Cobalt ug/L 458500 92 80-120 Copper ug/L 482500 96 80-120 Lead ug/L 455500 91 80-120 Nickel ug/L 453500 91 80-120 Selenium ug/L 459500 92 80-120 Silver ug/L 236250 94 80-120 Vanadium ug/L 453500 91 80-120 Zinc ug/L 456500 91 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1982618MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92337680006 1982619 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Antimony ug/L 500 89 75-12594 6 20500ND449475 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 26 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qual% RecConc. 1982618MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92337680006 1982619 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Arsenic ug/L 500 88 75-12592 5 20500ND442462 Barium ug/L 500 97 75-125103 7 2050018.8J 502 536 Beryllium ug/L 500 93 75-12599 7 20500ND464496 Cadmium ug/L 500 93 75-12598 5 20500ND464488 Chromium ug/L 500 92 75-12598 6 20500ND458488 Cobalt ug/L 500 91 75-12597 6 20500ND457484 Copper ug/L 500 96 75-125102 6 20500ND482512 Lead ug/L 500 91 75-12596 5 20500ND456479 Nickel ug/L 500 90 75-12595 6 20500ND450478 Selenium ug/L 500 92 75-12596 4 20500ND460480 Silver ug/L 250 95 75-12598 4 20250ND237246 Vanadium ug/L 500 91 75-12596 6 20500ND455483 Zinc ug/L 500 91 75-12596 6 20500ND457483 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 27 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 357344 EPA 3010A EPA 6020B 6020 MET Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005, 92337680006, 92337680007, 92337680008 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1982304 Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005, 92337680006, 92337680007, 92337680008 Matrix:Water AnalyzedMDL Thallium ug/L ND 5.5 04/21/17 17:590.020 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1982305LABORATORY CONTROL SAMPLE: LCSSpike Thallium ug/L 92.2100 92 80-120 Parameter Units MS Result % Rec Limits Qual% RecConc. 1982306MATRIX SPIKE & MATRIX SPIKE DUPLICATE: MSSpike Result 92337677002 1982307 MSD Result MSD % Rec RPD RPD Max MSDMS Spike Conc. Thallium ug/L 100 90 75-12592 3 201000.026J 90.1 92.5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 28 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. QC Batch: QC Batch Method: Analysis Method: Analysis Description: 357952 EPA 8260 EPA 8260 8260 MSV Low Level Landfill Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005, 92337680006, 92337680007, 92337680008, 92337680009 Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1985608 Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005, 92337680006, 92337680007, 92337680008, 92337680009 Matrix:Water AnalyzedMDL 1,1,1,2-Tetrachloroethane ug/L ND 5.0 04/25/17 17:330.33 1,1,1-Trichloroethane ug/L ND 1.0 04/25/17 17:330.48 1,1,2,2-Tetrachloroethane ug/L ND 3.0 04/25/17 17:330.40 1,1,2-Trichloroethane ug/L ND 1.0 04/25/17 17:330.29 1,1-Dichloroethane ug/L ND 5.0 04/25/17 17:330.32 1,1-Dichloroethene ug/L ND 5.0 04/25/17 17:330.56 1,2,3-Trichloropropane ug/L ND 1.0 04/25/17 17:330.41 1,2-Dibromo-3-chloropropane ug/L ND 13.0 04/25/17 17:332.0 1,2-Dibromoethane (EDB)ug/L ND 1.0 04/25/17 17:330.27 1,2-Dichlorobenzene ug/L ND 5.0 04/25/17 17:330.30 1,2-Dichloroethane ug/L ND 1.0 04/25/17 17:330.24 1,2-Dichloropropane ug/L ND 1.0 04/25/17 17:330.27 1,4-Dichlorobenzene ug/L ND 1.0 04/25/17 17:330.33 2-Butanone (MEK)ug/L ND 100 04/25/17 17:330.96 2-Hexanone ug/L ND 50.0 04/25/17 17:330.46 4-Methyl-2-pentanone (MIBK)ug/L ND 100 04/25/17 17:330.33 Acetone ug/L ND 100 04/25/17 17:3310.0 Acrylonitrile ug/L ND 200 04/25/17 17:331.9 Benzene ug/L ND 1.0 04/25/17 17:330.25 Bromochloromethane ug/L ND 3.0 04/25/17 17:330.17 Bromodichloromethane ug/L ND 1.0 04/25/17 17:330.18 Bromoform ug/L ND 3.0 04/25/17 17:330.26 Bromomethane ug/L ND 10.0 04/25/17 17:330.29 Carbon disulfide ug/L ND 100 04/25/17 17:331.2 Carbon tetrachloride ug/L ND 1.0 04/25/17 17:330.25 Chlorobenzene ug/L ND 3.0 04/25/17 17:330.23 Chloroethane ug/L ND 10.0 04/25/17 17:330.54 Chloroform ug/L ND 5.0 04/25/17 17:330.14 Chloromethane ug/L ND 1.0 04/25/17 17:330.11 cis-1,2-Dichloroethene ug/L ND 5.0 04/25/17 17:330.19 cis-1,3-Dichloropropene ug/L ND 1.0 04/25/17 17:330.13 Dibromochloromethane ug/L ND 3.0 04/25/17 17:330.21 Dibromomethane ug/L ND 10.0 04/25/17 17:330.21 Ethylbenzene ug/L ND 1.0 04/25/17 17:330.30 Iodomethane ug/L ND 10.0 04/25/17 17:330.32 Methylene Chloride ug/L ND 1.0 04/25/17 17:330.97 Styrene ug/L ND 1.0 04/25/17 17:330.26 Tetrachloroethene ug/L ND 1.0 04/25/17 17:330.46 Toluene ug/L ND 1.0 04/25/17 17:330.26 trans-1,2-Dichloroethene ug/L ND 5.0 04/25/17 17:330.49 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 29 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Blank Result Reporting Limit Qualifiers METHOD BLANK:1985608 Associated Lab Samples:92337680001, 92337680002, 92337680003, 92337680004, 92337680005, 92337680006, 92337680007, 92337680008, 92337680009 Matrix:Water AnalyzedMDL trans-1,3-Dichloropropene ug/L ND 1.0 04/25/17 17:330.26 trans-1,4-Dichloro-2-butene ug/L ND 100 04/25/17 17:331.0 Trichloroethene ug/L ND 1.0 04/25/17 17:330.47 Trichlorofluoromethane ug/L ND 1.0 04/25/17 17:330.20 Vinyl acetate ug/L ND 50.0 04/25/17 17:330.35 Vinyl chloride ug/L ND 1.0 04/25/17 17:330.62 Xylene (Total)ug/L ND 5.0 04/25/17 17:330.66 1,2-Dichloroethane-d4 (S)%97 70-130 04/25/17 17:33 4-Bromofluorobenzene (S)%97 70-130 04/25/17 17:33 Toluene-d8 (S)%100 70-130 04/25/17 17:33 Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1985609LABORATORY CONTROL SAMPLE: LCSSpike 1,1,1,2-Tetrachloroethane ug/L 55.750 111 80-125 1,1,1-Trichloroethane ug/L 52.350 105 71-129 1,1,2,2-Tetrachloroethane ug/L 52.550 105 79-124 1,1,2-Trichloroethane ug/L 54.450 109 85-125 1,1-Dichloroethane ug/L 50.350 101 73-126 1,1-Dichloroethene ug/L 50.750 101 66-135 1,2,3-Trichloropropane ug/L 52.650 105 75-130 1,2-Dibromo-3-chloropropane ug/L 53.250 106 71-133 1,2-Dibromoethane (EDB)ug/L 50.150 100 83-124 1,2-Dichlorobenzene ug/L 54.150 108 80-133 1,2-Dichloroethane ug/L 50.050 100 67-128 1,2-Dichloropropane ug/L 53.950 108 75-132 1,4-Dichlorobenzene ug/L 52.950 106 78-130 2-Butanone (MEK)ug/L 108100 108 61-144 2-Hexanone ug/L 113100 113 68-143 4-Methyl-2-pentanone (MIBK)ug/L 111100 111 72-135 Acetone ug/L 111100 111 48-146 Acrylonitrile ug/L 265250 106 40-160 Benzene ug/L 54.350 109 80-125 Bromochloromethane ug/L 50.450 101 71-125 Bromodichloromethane ug/L 56.950 114 78-124 Bromoform ug/L 55.450 111 71-128 Bromomethane ug/L 42.450 85 40-160 Carbon disulfide ug/L 43.9J50 88 50-160 Carbon tetrachloride ug/L 55.850 112 69-131 Chlorobenzene ug/L 55.050 110 81-122 Chloroethane ug/L 48.250 96 39-148 Chloroform ug/L 51.050 102 73-127 Chloromethane ug/L 43.750 87 44-146 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 30 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units LCS Result % Rec Limits Qualifiers% RecConc. 1985609LABORATORY CONTROL SAMPLE: LCSSpike cis-1,2-Dichloroethene ug/L 50.750 101 74-124 cis-1,3-Dichloropropene ug/L 56.050 112 72-132 Dibromochloromethane ug/L 54.750 109 78-125 Dibromomethane ug/L 54.050 108 82-120 Ethylbenzene ug/L 54.950 110 79-121 Iodomethane ug/L 88.7100 89 39-154 Methylene Chloride ug/L 43.950 88 64-133 Styrene ug/L 55.650 111 84-126 Tetrachloroethene ug/L 52.350 105 78-122 Toluene ug/L 55.250 110 80-121 trans-1,2-Dichloroethene ug/L 50.950 102 71-127 trans-1,3-Dichloropropene ug/L 56.250 112 69-141 trans-1,4-Dichloro-2-butene ug/L 51.7J50 103 40-160 Trichloroethene ug/L 52.050 104 78-122 Trichlorofluoromethane ug/L 50.350 101 53-137 Vinyl acetate ug/L 108100 108 40-160 Vinyl chloride ug/L 44.850 90 58-137 Xylene (Total)ug/L 166150 111 81-126 1,2-Dichloroethane-d4 (S)%97 70-130 4-Bromofluorobenzene (S)%101 70-130 Toluene-d8 (S)%100 70-130 Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1985610MATRIX SPIKE SAMPLE: MSSpike Result 92337677001 1,1,1,2-Tetrachloroethane ug/L 23.720 118 70-130ND 1,1,1-Trichloroethane ug/L 22.520 112 70-130ND 1,1,2,2-Tetrachloroethane ug/L 22.820 114 70-130ND 1,1,2-Trichloroethane ug/L 20.320 101 70-130ND 1,1-Dichloroethane ug/L 21.520 107 70-130ND 1,1-Dichloroethene ug/L 20.220 101 70-166ND 1,2,3-Trichloropropane ug/L 23.520 117 70-130ND 1,2-Dibromo-3-chloropropane ug/L 21.320 106 70-130ND 1,2-Dibromoethane (EDB)ug/L 18.920 94 70-130ND 1,2-Dichlorobenzene ug/L 21.820 109 70-130ND 1,2-Dichloroethane ug/L 21.120 106 70-130ND 1,2-Dichloropropane ug/L 21.920 110 70-130ND 1,4-Dichlorobenzene ug/L 21.320 106 70-130ND 2-Butanone (MEK)ug/L 40.5J40 101 70-130ND 2-Hexanone ug/L 41.1J40 103 70-130ND 4-Methyl-2-pentanone (MIBK)ug/L 44.1J40 110 70-130ND Acetone ug/L 39.1J40 94 70-130ND Acrylonitrile ug/L 109J100 109 70-130ND Benzene ug/L 22.520 113 70-148ND Bromochloromethane ug/L 21.720 108 70-130ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 31 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units MS Result % Rec Limits Qualifiers% RecConc. 1985610MATRIX SPIKE SAMPLE: MSSpike Result 92337677001 Bromodichloromethane ug/L 22.620 113 70-130ND Bromoform ug/L 23.920 119 70-130ND Bromomethane ug/L 16.420 82 70-130ND Carbon disulfide ug/L 16.0J20 80 70-130ND Carbon tetrachloride ug/L 23.520 117 70-130ND Chlorobenzene ug/L 22.620 113 70-146ND Chloroethane ug/L 17.720 89 70-130ND Chloroform ug/L 21.220 106 70-130ND Chloromethane ug/L 16.920 84 70-130ND cis-1,2-Dichloroethene ug/L 21.520 107 70-130ND cis-1,3-Dichloropropene ug/L 21.220 106 70-130ND Dibromochloromethane ug/L 21.620 108 70-130ND Dibromomethane ug/L 22.120 110 70-130ND Ethylbenzene ug/L 24.020 120 70-130ND Iodomethane ug/L 37.940 95 70-130ND Methylene Chloride ug/L 16.620 82 70-130ND Styrene ug/L 24.920 125 70-130ND Tetrachloroethene ug/L 24.220 121 70-130ND Toluene ug/L 23.020 115 70-155ND trans-1,2-Dichloroethene ug/L 19.120 96 70-130ND trans-1,3-Dichloropropene ug/L 21.020 105 70-130ND trans-1,4-Dichloro-2-butene ug/L 18.2J20 91 70-130ND Trichloroethene ug/L 22.420 112 69-151ND Trichlorofluoromethane ug/L 21.320 106 70-130ND Vinyl acetate ug/L 35.5J40 89 70-130ND Vinyl chloride ug/L 16.920 85 70-130ND 1,2-Dichloroethane-d4 (S)%99 70-130 4-Bromofluorobenzene (S)%114 70-130 Toluene-d8 (S)%100 70-130 Parameter Units Dup Result Max RPD QualifiersRPDResult 92337677002 1985611SAMPLE DUPLICATE: 1,1,1,2-Tetrachloroethane ug/L ND 30ND 1,1,1-Trichloroethane ug/L ND 30ND 1,1,2,2-Tetrachloroethane ug/L ND 30ND 1,1,2-Trichloroethane ug/L ND 30ND 1,1-Dichloroethane ug/L ND 30ND 1,1-Dichloroethene ug/L ND 30ND 1,2,3-Trichloropropane ug/L ND 30ND 1,2-Dibromo-3-chloropropane ug/L ND 30ND 1,2-Dibromoethane (EDB)ug/L ND 30ND 1,2-Dichlorobenzene ug/L ND 30ND 1,2-Dichloroethane ug/L ND 30ND 1,2-Dichloropropane ug/L ND 30ND REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 32 of 38 #=QC# QUALITY CONTROL DATA Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. Parameter Units Dup Result Max RPD QualifiersRPDResult 92337677002 1985611SAMPLE DUPLICATE: 1,4-Dichlorobenzene ug/L ND 30ND 2-Butanone (MEK)ug/L ND 30ND 2-Hexanone ug/L ND 30ND 4-Methyl-2-pentanone (MIBK)ug/L ND 30ND Acetone ug/L ND 30ND Acrylonitrile ug/L ND 30ND Benzene ug/L ND 30ND Bromochloromethane ug/L ND 30ND Bromodichloromethane ug/L ND 30ND Bromoform ug/L ND 30ND Bromomethane ug/L ND 30ND Carbon disulfide ug/L ND 30ND Carbon tetrachloride ug/L ND 30ND Chlorobenzene ug/L ND 30ND Chloroethane ug/L ND 30ND Chloroform ug/L ND 30ND Chloromethane ug/L ND 30ND cis-1,2-Dichloroethene ug/L ND 30ND cis-1,3-Dichloropropene ug/L ND 30ND Dibromochloromethane ug/L ND 30ND Dibromomethane ug/L ND 30ND Ethylbenzene ug/L ND 30ND Iodomethane ug/L ND 30ND Methylene Chloride ug/L ND 30ND Styrene ug/L ND 30ND Tetrachloroethene ug/L ND 30ND Toluene ug/L ND 30ND trans-1,2-Dichloroethene ug/L ND 30ND trans-1,3-Dichloropropene ug/L ND 30ND trans-1,4-Dichloro-2-butene ug/L ND 30ND Trichloroethene ug/L ND 30ND Trichlorofluoromethane ug/L ND 30ND Vinyl acetate ug/L ND 30ND Vinyl chloride ug/L ND 30ND Xylene (Total)ug/L ND 30ND 1,2-Dichloroethane-d4 (S)%99 0100 4-Bromofluorobenzene (S)%97 198 Toluene-d8 (S)%102 1101 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 33 of 38 #=QL# QUALIFIERS Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL - Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean-Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES Pace Analytical Services - AshevillePASI-A Pace Analytical Services - CharlottePASI-C ANALYTE QUALIFIERS Common Laboratory Contaminant.C9 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 34 of 38 #=CR# QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Project No.: Project: 92337680 Wilkes-Germantown 356.1701.12 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92337680001 357412 3576299701-MW1 EPA 3010A EPA 6010 92337680002 357412 3576299701-MW2 EPA 3010A EPA 6010 92337680003 357412 3576299701-MW3 EPA 3010A EPA 6010 92337680004 357412 3576299701-MW4 EPA 3010A EPA 6010 92337680005 357412 3576299701-MW5 EPA 3010A EPA 6010 92337680006 357413 3576339701-Upstream EPA 3010A EPA 6010 92337680007 357413 3576339701-Downstream EPA 3010A EPA 6010 92337680008 357413 3576339701-Field Blank EPA 3010A EPA 6010 92337680001 357344 3574979701-MW1 EPA 3010A EPA 6020B 92337680002 357344 3574979701-MW2 EPA 3010A EPA 6020B 92337680003 357344 3574979701-MW3 EPA 3010A EPA 6020B 92337680004 357344 3574979701-MW4 EPA 3010A EPA 6020B 92337680005 357344 3574979701-MW5 EPA 3010A EPA 6020B 92337680006 357344 3574979701-Upstream EPA 3010A EPA 6020B 92337680007 357344 3574979701-Downstream EPA 3010A EPA 6020B 92337680008 357344 3574979701-Field Blank EPA 3010A EPA 6020B 92337680001 3579529701-MW1 EPA 8260 92337680002 3579529701-MW2 EPA 8260 92337680003 3579529701-MW3 EPA 8260 92337680004 3579529701-MW4 EPA 8260 92337680005 3579529701-MW5 EPA 8260 92337680006 3579529701-Upstream EPA 8260 92337680007 3579529701-Downstream EPA 8260 92337680008 3579529701-Field Blank EPA 8260 92337680009 3579529701-Trip Blank EPA 8260 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC.Date: 05/02/2017 04:23 PM Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 35 of 38 Page 36 of 38 Page 37 of 38 Page 38 of 38 Appendix 2 Summary of Detections, Exceedances, and Field Parameters Summary of Detections WELL ID PARAMETER RESULT UNITS SWSL DATE 9701-MW1 Barium 101.0 µg/L 100 4/18/2017 9701-MW4 Cobalt 13.3 µg/L 10 4/18/2017 9701-MW4 1,4-Dichlorobenzene 2.2 µg/L 1 4/18/2017 9701-MW4 Chlorobenzene 4.9 µg/L 3 4/18/2017 9701-MW5 Barium 412 µg/L 100 4/18/2017 9701-MW5 Cobalt 15.4 µg/L 10 4/18/2017 9701-MW5 Zinc 14.7 µg/L 10 4/18/2017 9701-MW5 Benzene 1.1 µg/L 1 4/18/2017 9701-MW5 1,4-Dichlorobenzene 3.9 µg/L 1 4/18/2017 9701-MW5 Chlorobenzene 9.9 µg/L 3 4/18/2017 NOTES:All Results in micorgrams per liter (µg/L) SWSL = NC Soild Waste Section Reporting Limit Wilkes Co. Germantown Landfill Permit 97-01 Page 1 of 1 Joyce Engineering Summary of Exceedances WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS/(NC2B)GPS DATE 9701-MW4 Cobalt 13.3 µg/L 10 1*1 4/18/2017 9701-MW5 Cobalt 15.4 µg/L 10 1*1 4/18/2017 9701-MW5 Benzene 1.1 µg/L 1 1 1 4/18/2017 NOTES:All Results in micorgrams per liter (µg/L) SWSL = NC Soild Waste Section Reporting Limit NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L) GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) Wilkes Co. Germantown Landfill Permit No. 97-01 Joyce Engineering Summary of Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 9701-MW1 pH 5.21 S.U.4/18/2017 9701-MW1 Temperature 15.9 C˚4/18/2017 9701-MW1 Conductivity 111.7 µS/cm 4/18/2017 9701-MW1 Turbidity 2.09 NTU 4/18/2017 9701-MW1 Static Water Level 57.72 ft 4/18/2017 9701-MW1 Well Depth 89.69 ft 4/18/2017 9701-MW2 pH 6.78 S.U.4/18/2017 9701-MW2 Temperature 15.3 C˚4/18/2017 9701-MW2 Conductivity 214 µS/cm 4/18/2017 9701-MW2 Turbidity 3.75 NTU 4/18/2017 9701-MW2 Static Water Level 48.65 ft 4/18/2017 9701-MW2 Well Depth 81.54 ft 4/18/2017 9701-MW3 pH 5.57 S.U.4/18/2017 9701-MW3 Temperature 14.7 C˚4/18/2017 9701-MW3 Conductivity 55.7 µS/cm 4/18/2017 9701-MW3 Turbidity 4.50 NTU 4/18/2017 9701-MW3 Static Water Level 44.50 ft 4/18/2017 9701-MW3 Well Depth 64.00 ft 4/18/2017 9701-MW4 pH 5.98 S.U.4/18/2017 9701-MW4 Temperature 14.0 C˚4/18/2017 9701-MW4 Conductivity 626 µS/cm 4/18/2017 9701-MW4 Turbidity 9.97 NTU 4/18/2017 9701-MW4 Static Water Level 15.14 ft 4/18/2017 9701-MW4 Well Depth 28.21 ft 4/18/2017 Wilkes Co. Germantown Landfill Permit No. 97-01 Joyce Engineering Summary of Field Parameters WELL ID PARAMETER RESULT UNITS COLLECT DATE 9701-MW5 pH 6.14 S.U.4/18/2017 9701-MW5 Temperature 14.8 C˚4/18/2017 9701-MW5 Conductivity 1211 µS/cm 4/18/2017 9701-MW5 Turbidity 20.16 NTU 4/18/2017 9701-MW5 Static Water Level 10.81 ft 4/18/2017 9701-MW5 Well Depth 23.47 ft 4/18/2017 9701-Upstream pH 6.51 S.U.4/18/2017 9701-Upstream Temperature 14.9 C˚4/18/2017 9701-Upstream Conductivity 62.3 µS/cm 4/18/2017 9701-Upstream Turbidity 8.15 NTU 4/18/2017 9701-Downstream pH 6.61 S.U.4/18/2017 9701-Downstream Temperature 15.3 C˚4/18/2017 9701-Downstream Conductivity 66.7 µS/cm 4/18/2017 9701-Downstream Turbidity 9.86 NTU 4/18/2017 NOTES: C˚= degrees Centigrade S.U.= Standard Units µS/cm = microsemens per centimeter NTU = Nephelometric Turbidity Units ft =Feet Wilkes Co. Germantown Landfill Permit No. 97-01 Joyce Engineering Appendix 3 Horizontal Groundwater Flow Velocities Horizontal Groundwater Flow Velocities Date of Water Table Measurements: April 18, 2017 SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY DIRECTION GW ELEVATION i K n e V (feet-AMSL)(ft/ft) (ft/day)(ft/year) 1,160 1,100 1,160 1,010 1,160 1,010 Average 0.1630 Average 204.56 Notes: Linear flow velocity: V = Ki/n e (modified Darcy equation). Hydraulic conductivity (K ) is based on slug test from Wilkes County Roaring River Landfill. Effective porosity (n e ) is based on data for the Wilkes County Roaring River Landfill. Refer to Drawing 1 for flow line segments. 0.16 i 2 801 E 0.1873 0.165.50E-01 197.075.50E-01 181.665.50E-01 FLOW LINE SEGMENT SEGMENT LENGTH (feet) i 3 1036 E 0.1448 234.96 i 1 382 S 0.1571 0.16 Wilkes County Germantown Landfill Permit # 97-01 Joyce Engineering