9601_WayneCountyC&DWQMR_20170822

Wayne County Active C&D and Closed MSWLF
Dudley, North Carolina
February 2017
MESCO Project Number: G17016.0
Semi-Annual Water Quality Monitoring Report
with Corrective Action Update
Prepared for
Municipal Engineering Services Company, P.A.Garner and Boone, North Carolina
P.O. Box 97
Garner, NC 27529
License No. C-0281

Permit Number: 96-01
TABLE OF CONTENTS
SECTION
Introduction Page 1
Background Page 1
Sampling Procedure Page 2
Field Parameter Data Page 2
Laboratory Results Page 3
Quality Control Samples Page 3
Groundwater Samples Detected Above Standards Page 3
Surface Water Samples Detected Above Standards Page 3
Corrective Action Update Page 3
Groundwater and Surface Water Characterization Page 4
Findings Page 4
Closing Page 4
FIGURES
Topographic Map with Site Location Figure 1
Potentiometric Map of Uppermost Aquifer w/ VOC Detection Above 2L Standard Figure 2
TABLES
Groundwater Monitoring Well Construction Table Table 1
Field Observations of Monitoring Locations Table 2
Field Parameter Data Summary Table 3
Sampling and Analysis Summary Table 4
Groundwater Detections Table 5
Surface Water Detections Table 6
MNA Parameter Data Summary Table 7
Hydrologic Properties at Monitoring Well Locations Table 8
APPENDICIES
Laboratory Analysis Reports and Chains of Custody Appendix A
Field Sampling Data Sheet(s) Appendix B
August 22, 2017
Ms. Jaclynne Drummond
Solid Waste Section (SWS)
Division of Waste Management
North Carolina Department of Environmental Quality (NCDEQ)
2090 US 70 Highway
Swannanoa, NC 28778
Re: Semi-Annual Water Quality Monitoring Report with Corrective Action Update
Wayne County Active C&D and Closed MSWLF (Dudley)
Permit No. 96-01
MESCO Project No. G17016.0
Event Date(s): February 16-17, 2017
Dear Ms. Drummond,
Introduction
The Wayne County Landfill (Permit #96-01) is located at 460 S Landfill Road (SR 1129), Dudley, Wayne County,
North Carolina. A topographic map showing the location of the site is included as Figure 1.
The Wayne County unlined closed Municipal Solid Waste Landfill (MSWLF) and active Construction and Demolition
(C&D) Landfill located in Dudley NC, currently operating under Permit #96-01 is required to submit semi-annual
compliance reports as a condition of 15A NCAC 13B.1630. This report documents the quality of the ground and
surface waters during this monitoring event performed on February 16-17, 2017. Laboratory analytical results, which
consisted of targeting Appendix I constituents, indicate that levels four metals were detected above applicable
regulatory groundwater Standards in samples collected from four wells including the background well. No
contaminants were detected in any surface water sample sample during this event. A Corrective Action Evaluation
Report (CAER) dated June 5, 2017 concluded groundwater quality has improved. Corrective action via monitored
natural attenuation (MNA) is planned to continue.
As specified within 15A NCAC 13B.1632(j), the SWS Environmental Monitoring Report Form and SWS
memorandums this report contains sampling procedures, field and laboratory results, corrective action update,
ground/surface water characterization, and findings. Well construction summary table, field observations table, field
parameter data table, sampling and analysis summary table, detections compared to Standards tables, MNA parameter
summary table, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data,
and laboratory analytical data results are enclosed herein.
Background
Prior to operating as a C&D landfill the site operated as a Municipal Solid Waste (MSW) unlined sanitary landfill that
consisted of two units. The first unit (Unit 1) was closed prior to October 1991 with a 24 inch final soil cover. The
second unit (Unit 2) was closed with a low permeability cohesive cap and erosive layer prior to December 31, 1998 in
accordance with the Transition Plan. The C&D landfill is operating on top of the Unit 2 MSW landfill. The separate
active Subtitle D Lined MSWLF (permit #96-06), located adjacent to the C&D landfill across an unnamed tributary of
Edward's Branch, was monitored in conjunction with this site but reported separately.

Water quality at this landfill has been monitored at least semi-annually since 1991. Current data was compared to data
compiled since 1994 in support of this report. Municipal Engineering Services Company, P.A. (MESCO) submitted an
Assessment and Corrective Action (ACM) [DIN8821] report dated August 30, 2007 which was approved by the NC Solid
Waste Section (SWS) on November 1, 2007 [DIN3328]. MESCO then developed a Corrective Action Plan (CAP)
[DIN8821] on October 22, 2009 which was approved by the SWS on October 23, 2009 [DIN8822].
Groundwater remediation using Monitored Natural Attenuation (MNA) was initiated on August 6, 2009 and has
continued on a semi-annual basis.
Following establishment of the two year MNA baseline, MESCO completed a CAER [DIN 13923] on May 10, 2011.
The CAER was reviewed and the proposed modifications of MNA parameters and frequency were approved by the SWS
[DIN 16967]. Background well MW-1 was abandoned and replaced by MW-1R as pre-authorized by SWS [DIN 19050]
on June 4, 2013. MESCO submitted a Request for Appendix II Groundwater Monitoring Modification dated April 24,
2014 which was approved by the SWS. The Water Quality Sampling and Analysis Plan (SAP) which provides for a
subset of wells to decrease Appendix II monitoring frequency was revised and submitted on December 15, 2014 as
requested by the SWS. A second CAER which proposes modifications to the parameters, frequency and wells to continue
MNA is currently under SWS review.
Sampling Procedure
MESCO performed this sampling event utilizing portable monitoring methodology in accordance with the approved SAP
based on the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April 2008.
The new site-specific SAP entails continued semi-annual water quality monitoring which includes annual corrective
action monitoring and targeting of specific Appendix II constituents at a subset of wells once every three years.
Keeping with the established schedule this event consists of targeting Appendix I contaminants and tetrahydrofuran at all
groundwater locations and the full suite of MNA performance parameters at MW-1R, MW-2 and MW-8. Water samples
were collected from monitoring locations designated in the SAP with the exception of SW-2 and SW-3 which are
chronically dry. Water quality monitoring was performed on eight wells (MW-2, MW-3, MW-4, MW-5, MW-6, MW-7,
MW-8 and MW-11), background well (MW-1R) and two surface water points (SW-1, SW-2). Quality control measures
implemented during this event included quantification of an equipment blank (EB), field blank (FB) and travel blank
(TB). A supplemental surface water sample (SW-By_MW-2) was collected from the western tributary of Edward's
Branch directly downgradient of MW-2 to ensure contaminants remain delineated within the property boundary. Data
from a surface water location from the Subtitle D Lined SAP SW-6 (shared) is presented because this local discharge
feature is shared by both permits. Monitoring locations are depicted on the potentiometric map, included as Figure 2.
A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity
of all monitoring locations were visually evaluated and minor deficiencies documented on Table 2. The depth to water in
each well was electronically gaged prior to purging to quantify the static water level elevation. Low-flow pumping
methodology or bailing was utilized to adequately purge the wells a minimum of three times the volume of standing water
in the well or until dry. Surface water samples were dipped from the surface of the creeks at previously designated
locations. Samples were then placed into laboratory-prepared, pre-preserved containers. Samples were kept on ice and
transported to a NC-certified laboratory under proper chain of custody (C-O-C) protocol and analyzed within the required
hold times.
Field Parameter Data
Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature,
dissolved oxygen (DO), oxidation reduction potential (ORP) and visual turbidity. A summary of the field parameter data
is presented in Table 3 and the field sampling data sheet is enclosed in Appendix B.
2
Laboratory Results
Pace Analytical Laboratories (PACE) and their subsidiary Microseeps performed the laboratory analysis. All water
samples were analyzed for constituents listed in Appendix I 40 CFR 258 and CDLF parameter tetrahydrofuran. MW-1R,
MW-2 and MW-8 were tested for mercury. Additionally MNA monitoring consisting of testing for the full suite of MNA
performance parameters was performed on samples collected from MW-1R, MW-2 and MW-8. A sampling and analysis
table summarizing the locations, targeted constituents and methods is presented as Table 4. Laboratory results and C-O-
Cs are contained in Appendix A.
Water samples were analyzed to the laboratory-established Method Detection Limits (MDL), which are at or below the
current Solid Waste Section Limit (SWSL). Tables 5 and 6 summarizes constituents detected that attain or were above
the current SWSL, SWS adopted Groundwater Protection Standards (GWP), North Carolina Groundwater Standards (2L),
the applicable North Carolina Surface Water Standards (2B) for a Class C waterbody and Federal Maximum Contaminant
Levels (MCL) also known as “Primary Drinking Water Standards”.
Quality Control Samples
Methylene chloride was detected in FB and EB and qualified by the laboratory as C9 “common laboratory contaminant”.
Since neither methylene chloride nor it's biodegradation byproducts were detected in any ground or surface water samples
any potential artifact contamination is non-consequential.
Groundwater Samples Detected Above Standards
Metals
A total of four metals were detected above their respective 2L/GWP Standard in samples collected from four wells
including the upgradient background well as summarized below.
Constituents Detected Above 2L/GWP Standards in Groundwater
Ar Cd Cr Va
2L/GWP STD. 1 2 0.28 0.3
MW-1R (BG Well)12.9 19.8 J
MW-2 12.7 8.7 J
MW-5 2.3
MW-11 2.5 J
Concentrations in ug/L. J = “j-qualified” since below the SWSL thus value is considered an estimate
VOCs
VOCs, which are more indicative of a release, were not detected above Standards in any groundwater samples.
Surface Water Samples Detected Above Standards
Constituents were not detected in any surface water sample in concentrations above the established 2B Standards.
Supplemental surface water sample SW-By_MW-2 collected at the property line approximately 166 feet hydraulically
downgradient of MW-2 continues to lack contaminants.
Corrective Action Update
Groundwater remediation measures through MNA continues to be implemented at the facility. Semi-annual MNA
monitoring of MW-2, MW-8 and background well MW-1 was initiated on August 6, 2009 and was consistently
performed for the full suite of SWS recommended parameters for seven consecutive semi-annual events. The SAP
prescribes MNA monitoring for specific constituents to be performed annually or bi-annually. Full suite of MNA
parameters were analyzed during this event with concentrations presented on Table 7.
3
Figures
FIGURE 1Wayne County Landfill (Dudley)SITE LOCATION (USGS TOPO)
DATEDRAWING NO.SHEET NO.
SCALE:
DATE:
DRWN. BY:
CHKD. BY:
PROJECT NUMBERBY REV.DESCRIPTION
Table
Table 1
Groundwater Monitoring Well Construction Table
February 16-17, 2017
Well
Diameter
Total
Well
Depth
Top of
Screen
Depth
Screen
Length
Top of
Casing
Elevation
Ground
Elevation
Groundwater
Elevation
Depth
to
Water
(inches)(ft bgs)(ft bgs)(ft)(ft amsl)(ft amsl)(ft amsl)(ft btoc)
MW-1R 6/4/13 2 27.32 12.32 15 Soil Sand 169.64 166.64 149.13 20.51 35.292408 -78.064431
MW-2 8/28/90 2 15 10 5 Soil Sand 134.52 132.78 130.01 4.51 35.290714 -78.076225
MW-3 8/27/90 2 18 12 6 Soil Sand 134.81 133.03 >134.81 0.00 35.293192 -78.072156
MW-4 8/28/90 2 15 10 5 Soil Sand 150.20 148.17 143.43 6.77 35.293003 -78.066253
MW-5 8/31/94 2 18 3 15 Soil Sand 124.78 120.56 122.56 2.22 35.292597 -78.075936
MW-6 8/31/94 2 18.14 3.14 15 Soil Sand 145.53 143.62 139.71 5.82 35.293439 -78.068656
MW-7 8/31/94 2 19 4 15 Soil Sand 143.59 140.74 137.47 6.12 35.288761 -78.074700
MW-8 8/30/94 2 29 14 15 Soil Sand 161.88 160.88 144.06 17.82 35.290178 -78.068706
MW-9 7/9/09 2 25 10 15 Soil Sand 162.96 159.78 144.95 18.01 35.290025 -78.068242
MW-10 7/9/09 2 25 10 15 Soil Sand 162.90 160.01 147.50 15.40 35.289869 -78.069167
MW-11 7/9/09 2 15 5 10 Soil Sand 127.23 124.50 124.72 2.51 35.291844 -78.076250
NOTE:
na = not available
bgs = below ground surface
amsl= above mean sea level
btoc = below top of PVC well casing
Monitoring
Well
Date
Installed
Geology of
Screened
Interval
Latitude Longitude
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 2
Field Observations of Monitoring Locations
February 16-17, 2017
Sample
Location
Viable
Monitoring
Location
Lack of Any
Evidence of
Tampering
Locked Hinge/Hasp
Operational
Tagged
or
Labeled
Concrete
Surface
Pad
Effective
Comments
MW-1R Yes Yes Yes Yes Yes Yes Upgradient background well
MW-2 Yes Yes Yes Yes Yes Yes Purge water foamy
MW-3 Yes Yes Yes Yes Yes Yes Flowing artesian
MW-4 Yes Yes Yes Yes Yes Covered Pad Covered
MW-5 Yes Yes Yes Yes Yes Covered Pad Covered
MW-6 Yes Yes Yes Yes Yes Yes
MW-7 Yes Yes Yes Yes Yes Yes
MW-8 Yes Yes Yes Yes Yes Yes
MW-9 Yes Yes Yes Yes Yes Yes
MW-10 Yes Yes Yes Yes Yes Yes
MW-11 Yes Yes Yes Yes Yes Yes Lock rusting
SW-1 Yes -----Shared Downstream of SW-3
SW-2 No -----Dry Upstream nearest MW-7.
SW-3 No -----Dry-Shared Upstream nearest MW-4
SW-6 Yes -----Shared nearest MW-5
SW-By _MW-2 Yes -----Not required but supplemental sample
Any unusual field conditions, observations, or events:
SW-2 (Closed) upstream nearest MW-7 was dry which is typical.
SW-3 (Closed) upstream nearest MW-4 was dry which is typical
Wetlands west of landfill are flooded which is likely caused by beaver dam(s)
Wayne County Active CDLF and Closed MSWLF Page 1 of 1
Table 3
Field Parameter Data Summary
February 16-17, 2017
Parameter
Depth to
Water
Water
Elevation
TOC
Elevation Temp.ORP DO pH
Specific
Conductance TDS Turbidity
Units ft (btoc)ft (amsl)ft (amsl) C mV mg/L SU umhos/cm mg/L NTU or Visual
MW-1R 20.51 149.12 169.63 14.6 291 4.8 6.1 7 NR 217
MW-2 4.51 130.01 134.52 13.5 -61 0.6 7.2 1638 NR 181
MW-3 0.00 >134.81 134.81 13.1 231 2.2 5.4 17 NR Slight
MW-4 6.77 143.43 150.20 15.2 253 2.4 6.5 356 NR Clear
MW-5 2.22 122.56 124.78 18.5 213 2.6 7.3 80 NR Clear
MW-6 5.82 139.71 145.53 14.3 138 2.3 5.6 93 NR Clear
MW-7 6.12 137.47 143.59 15.0 299 2.1 6.1 139 NR Slight
MW-8 17.82 144.06 161.88 14.7 341 2.7 5.2 13 NR 119
MW-9 18.01 144.95 162.96 NR NR NR NR NR NR NR
MW-10 15.40 147.50 162.90 NR NR NR NR NR NR NR
MW-11 2.51 124.72 127.23 12.9 109 3.1 5.8 1207 NR Slight
Minimum 0.00 122.56 124.78 12.9 -61 0.6 5.2 7 NR Clear
Average 9.06 138.35 147.09 14.6 202 2.5 6.1 394 NR Slight
Maximum 20.51 149.12 169.63 18.5 341 4.8 7.3 1638 NR Slight
SW-1 ---8.3 126 4.7 6.8 231 NR Clear
SW-2 Dry ---------
SW-ByMW-2 ---5.8 --6.8 137 NR Clear
SW-3 Dry ---------
SW-6 ---5.9 NR -6.8 79 NR Clear
Minimum ---5.8 126 4.7 6.8 79 NR Clear
Average ---6.7 126 4.7 6.8 149 NR Clear
Maximum ---8.3 126 4.7 6.8 231 NR Clear
NR = No reading attempted
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 4
Sampling and Analysis Summary
February 16-17, 2017
CDLF App. II
VOCsTotal MetalsTetrahydrofuranDissolved Oxygen (DO)Oxidation Reduction Potential (ORP)TemperatureConductivityTotal Dissolved Solids (TDS)pHTurbidityVFAHydrogenMethane/Ethene/EthaneDissolved CO2AlkalinitySulfateSulfideChlorideBODCODTOCFerrous IronNitrateMercuryLab EPA 8260B Lab EPA 6000/7000Lab EPA 8260BField MeterField MeterField MeterField MeterField MeterField MeterVisualLab AM23GLab AM20GAXLab AM20GAXField Hach KitEPA 310.2EPA 300.0Lab SM18 4500-S DEPA 300.0SM 5210BSM 5220DSM 5310BLab EPA 8270DLab EPA 9014Lab EPA 7470MW-1 x x x x x x x x x x x x x x x x x x x x x x x
MW-2 x x x x x x x x x x x x x x x x x x x x x x x
MW-3 x x x x x x x x x
MW-4 x x x x x x x x x
MW-5 x x x x x x x x x
MW-6 x x x x x x x x x
MW-7 x x x x x x x x x
MW-8 x x x x x x x x x x x x x x x x x x x x x x x
MW-11 x x x x x x x x x
SW-1 x x x x x x x x x
SW-2
SW-ByMW-2 x x x x x
SW-3
SW-6 x x x x x x x
EB x x x
FB x x x
TB x x
Dry so not sampled
App I & II = Appendix I & II List from current 40 CFR 258
MNAApp. I Field Parameter
Dry so not sampled
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 5
Groundwater Detections
February 16-17, 2017
MW-1R MW-2 MW-3 MW-4 MW-5 MW-6 MW-7 MW-8 MW-11 EB FB TB
BG S S S S S S S S QC QC QC
2/16/17 2/16/17 2/17/17 2/17/17 2/17/17 2/17/17 2/17/17 2/16/17 2/17/17 2/17/17 2/17/17 2/17/17
Arsenic, total 10 10 10 <5 12.7 (N)<5 <5 <5 <5 <5 <5 <5 <5 ----
Barium, total 100 700 2000 16.5 J 171 15.7 J 60.9 J 37.3 J 77.9 J 36.4 J 86.5 J 187 <2.5 ----
Cadmium, total 1 2 5 <0.5 <0.5 2 <0.5 2.3 (N)1.6 0.54 J 1.1 0.95 J <0.5 ----
Chromium, total 10 10 100 12.9 (N)<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 ----
Lead, total 10 15 15 3.5 J <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 2.6 J <2.5 <2.5 ----
Thallium, total 5.5 0.28 2 <0.02 <0.02 <0.02 0.027 <0.02 <0.02 <0.02 <0.02 <0.02 <0.02 ----
Vanadium, total 25 0.3 NE 19.8 J (N)8.7 J (N)<2.5 <2.5 <2.5 <2.5 <2.5 <2.5 2.5 J (N)<2.5 ----
Zinc, total 10 1000 NE <5 <5 8.4 J <5 12.7 6 J <5 <5 <5 <5 ----
1,2-Dichlorobenzene 5 20 NE <0.3 0.38 J <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3 <0.3
1,4-Dichlorobenzene 1 6 75 <0.33 3.5 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33 <0.33
Benzene 1 1 5 <0.25 0.9 J <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25
Chlorobenzene 3 50 100 <0.23 10.5 <0.23 0.36 J <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23 <0.23
Chloroform 5 70 NE 0.42 J <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.42 J <0.14 <0.14 <0.14 <0.14
cis-1,2-Dichloroethene 5 70 70 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 <0.19 0.21 J <0.19 <0.19 <0.19
Methylene Chloride 1 5 5 <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 <0.97 8.3 (B)9.6 (B)4.4
Tetrahydrofuran NE NE NE <3.1 7.4 J <3.1 <3.1 <3.1 <3.1 <3.1 <3.1 4.1 J <3.1 <3.1 <3.1
Units ug/L
Red Bold Above Established MCL/2L/GWP Std.
Above Established Federal MCL Drinking Water Std. No regulatory compliance significance.
(N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic.
(B) Preliminary source is believed to be lab induced artifiact contamination since detected only in quality control blanks.
A definitive source of the detections was not determined as part of this report.
-- = Not Tested, J = Detected >MDL<SWSL, < Not Detected above MDL
BG = Background Well Sample, QC = Quality Control Sample, S = Sentinal Well Sample
Appendix I VOCs
CDLF Specific Parameter
2L/GWP MCLParameter Name SWSL
Appendix I Metals
Wayne County Active CDLF and Closed MSWLF (Dudley)
Table 6
Surface Water Detections
February 16-17, 2017
SW-1 SW-6
D D
2/16/17 2/17/17
Barium, total 100 200000 2000 43.5 J 43.8 J
Lead, total 10 25 15 2.9 J <2.5
Vanadium, total 25 NE NE 2.5 J <2.5
Zinc, total 10 50 NE 12.8 6 J
Units ug/L
Red Bold Above Established 2B Std.
Above Established Federal MCL Drinking Water Std
Parameter Name 2B MCLSWSL
Appendix I Metals
Wayne County Active CDLF and Closed MSWLF (Dudley)
Table 7
MNA Parameter Data Summary
February 16, 2017
MW-1R MW-2 MW-8
02/16/17 02/16/17 02/16/17
VFA – Acetic Acid AM23G 7 ug/L 18 50 28
VFA – Butyric Acid AM23G 7 ug/L <7 <7 7.3
VFA – Hexanoic Acid AM23G 7 ug/L <7 <7 <7
VFA – i-Hexanoic Acid AM23G 4 ug/L <4 <4 <4
VFA – i-Pentanoic Acid AM23G 7 ug/L <7 <7 <7
VFA – Lactic Acid AM23G 6 ug/L 26 70 39
VFA – Pentaonic Acid AM23G 6 ug/L <6 <6 <6
VFA – Propionic Acid AM23G 9 ug/L <9 <9 <9
VFA – Pyruvic Acid AM23G 7 ug/L <7 17 <7
Hydrogen AM20GAX 0.075 nM 1.8 1.6 1.6
Methane AM20GAX 0.027 ug/L 0.032 7000 2.5
Ethene AM20GAX 0.001 ug/L <0.0028 <0.15 0.0068
Ethane AM20GAX 0.003 ug/L 0.1 5 0.0071
CO2-Dissolved Field Hach Kit 0 mg/L 40 >100 >100
Alkalinity SM 2320B 1000 ug/L <1000 566000 <1000
Sulfate EPA 300.0 1000 ug/L 1000 3140 1760
Sulfide SM 4500-S2D 100 ug/L <100 <100 <100
Chloride SM 4500-Cl-E 500 ug/L 3040 113000 8420
TOC SM 5310B 500 ug/L 1160 24400 1720
COD SM 5220D 12500 ug/L 32000 89000 40000
BOD SM 5210B 2000 ug/L <2000 11500 <2000
Iron, ferrous SM 3500-Fe B 0.5 ug/L <0.5 2.6 <0.5
Nitrate EPA 353.2 10 ug/L 108 <10 927
Temperature Field Instrument 0 Degrees C 14.6 13.5 14.7
ORP Field Instrument -900 mV 291 -61 341
DO Field Instrument 0 ug/L 4.8 0.6 2.7
pH Field Instrument 0.00 SU 6.1 7.2 5.19
Specific Conductance Field Instrument 0 uMhos 7 1638 13
Turbidity Field Instrument 1.00 NTU 217 181 119
Notes:
VFA = Volatile Fatty Acids
MDL* = Lowest Method Detection Limit for Lab Parameters or Lowest Field Measurement Possible
>100 = CO2 Concentration Exceeds Maximum capability of Method Used
Constituents Below Quantization Limit are shown as <MDL value
Parameters Method MDL*Units
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Table 8
Hydrogeologic Properties at Monitoring Well Locations
February 16, 2017
Hydraulic
Conductivity
Effective
Porosity
Hydraulic
Gradient
Linear
Velocity
Depth to
Groundwater
Groundwater
Potentiometric
Elevation
(cm/sec)(%)(ft/ft)(ft/yr)(ft btoc)(ft amsl)
MW-1R na 20 0.093 na N68W 20.51 149.13
MW-2 3.00E-04 20 0.002 2 N55W 4.51 130.01
MW-3 6.40E-03 20 0.020 678 N54W 0.00 >134.81
MW-4 9.90E-04 20 0.013 65 N09W 6.77 143.43
MW-5 3.10E-05 20 0.030 5 N41W 2.22 122.56
MW-6 1.60E-04 20 0.018 15 N30W 5.82 139.71
MW-7 7.30E-05 20 0.016 6 N63W 6.12 137.47
MW-8 3.40E-04 20 0.023 40 N22E 17.82 144.06
Minimum 3.10E-05 20 0.002 2 -0.00 122.56
Average 1.18E-03 20 0.027 116 -7.97 137.65
Maximum 6.40E-03 20 0.093 678 -20.51 149.13
NOTE:Data for conductivities and effective porosity obtained from GAI Consultants' Water Sampling Report (January, 1995).
Hydrologic Gradient from groundwater elevations recorded on February 16, 2017
Linear Velocity (Q ) is defined by modified Darcy's equation:
where
K = hydraulic conductivity
ne = effective porosity
dh = head difference
dl = horizontal distance
Monitoring
Well
Flow
Direction
dl
dh
n
KQ
e
×-=
Wayne County Active CDLF and Closed MSWLF (Dudley)Page 1 of 1
Appendix A
Laboratory Analysis Reports
Chains of Custody
#=CL#
April 07, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92330523
92330523
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne Closed LF
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory between February 17,
2017 and February 22, 2017. The results relate only to the samples included in this report. Results
reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's
Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
Report revised on to update sample ID per client request.
Report revised on 4.7.176 include Sulfate results and correct VFA results.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 83
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 83
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330523
Wayne Closed LF
Lab ID Sample ID Matrix Date Collected Date Received
92330523001 MW-1R Water 02/16/17 15:00 02/17/17 08:52
92330523002 MW-2 Water 02/16/17 16:40 02/17/17 08:52
92330523003 MW-8 Water 02/16/17 16:00 02/17/17 08:52
92330523004 MW-3 Water 02/17/17 14:15 02/22/17 08:00
92330523005 MW-4 Water 02/17/17 13:32 02/22/17 08:00
92330523006 MW-5 Water 02/17/17 13:50 02/22/17 08:00
92330523007 MW-6 Water 02/17/17 14:00 02/22/17 08:00
92330523008 MW-7 Water 02/17/17 16:10 02/22/17 08:00
92330523009 MW-11 Water 02/17/17 13:20 02/22/17 08:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330523
Wayne Closed LF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330523001 MW-1R EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-AKDF1
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AEWS
SM 5210B 1 PASI-ACJH
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92330523002 MW-2 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-AKDF1
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AEWS
SM 5210B 1 PASI-ACJH
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92330523003 MW-8 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-AKDF1
SM 3500-Fe B 1 PASI-AAES2
SM 4500-S2D 1 PASI-AEWS
SM 5210B 1 PASI-ACJH
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 83
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330523
Wayne Closed LF
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92330523004 MW-3 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
92330523005 MW-4 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
92330523006 MW-5 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
92330523007 MW-6 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
92330523008 MW-7 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
92330523009 MW-11 EPA 6010 14 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-1R Lab ID: 92330523001 Collected: 02/16/17 15:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:35 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:35 7440-38-202/20/17 19:5510.0 5.0 1
Barium 16.5J ug/L 02/24/17 06:35 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:35 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:35 7440-43-902/20/17 19:551.0 0.50 1
Chromium 12.9 ug/L 02/24/17 06:35 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:35 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:35 7440-50-802/20/17 19:5510.0 2.5 1
Lead 3.5J ug/L 02/24/17 06:35 7439-92-102/20/17 19:5510.0 2.5 1
Nickel ND ug/L 02/24/17 06:35 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:35 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:35 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 19.8J ug/L 02/24/17 06:35 7440-62-202/20/17 19:5525.0 2.5 1
Zinc ND ug/L 02/24/17 06:35 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 18:29 7440-28-002/23/17 02:205.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 18:04 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 21:25 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 21:25 107-13-1200 1.9 1
Benzene ND ug/L 02/28/17 21:25 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 21:25 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 21:25 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 21:25 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 21:25 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 21:25 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 21:25 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 21:25 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/28/17 21:25 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 21:25 75-00-310.0 0.54 1
Chloroform 0.42J ug/L 02/28/17 21:25 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 21:25 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 21:25 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 21:25 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 21:25 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 21:25 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/28/17 21:25 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/28/17 21:25 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 21:25 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 21:25 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 21:25 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 21:25 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-1R Lab ID: 92330523001 Collected: 02/16/17 15:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/28/17 21:25 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 21:25 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 21:25 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/28/17 21:25 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 21:25 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 21:25 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 21:25 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 21:25 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 21:25 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 21:25 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 21:25 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 21:25 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 21:25 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 21:25 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/28/17 21:25 109-99-910.0 3.1 1
Toluene ND ug/L 02/28/17 21:25 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 21:25 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 21:25 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 21:25 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 21:25 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 21:25 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 21:25 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 21:25 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/28/17 21:25 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/28/17 21:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)111 %02/28/17 21:25 17060-07-070-130 1
Toluene-d8 (S)99 %02/28/17 21:25 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 02/24/17 03:435000 1000 1
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous ND mg/L 03/04/17 12:50 H1,N20.50 0.50 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/22/17 13:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/22/17 21:45 B202/18/17 02:302000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 04/06/17 16:08 14808-79-8 H3250000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-1R Lab ID: 92330523001 Collected: 02/16/17 15:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 108J ug/L 02/18/17 00:4710000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3040 ug/L 02/24/17 03:06 16887-00-6 M11000 500 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 32000 ug/L 02/22/17 00:2225000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1160 ug/L 03/01/17 13:36 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-2 Lab ID: 92330523002 Collected: 02/16/17 16:40 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:38 7440-36-002/20/17 19:556.0 3.9 1
Arsenic 12.7 ug/L 02/24/17 06:38 7440-38-202/20/17 19:5510.0 5.0 1
Barium 171 ug/L 02/24/17 06:38 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:38 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:38 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:38 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:38 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:38 7440-50-802/20/17 19:5510.0 2.5 1
Lead ND ug/L 02/24/17 06:38 7439-92-102/20/17 19:5510.0 2.5 1
Nickel ND ug/L 02/24/17 06:38 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:38 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:38 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 8.7J ug/L 02/24/17 06:38 7440-62-202/20/17 19:5525.0 2.5 1
Zinc ND ug/L 02/24/17 06:38 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 18:31 7440-28-002/23/17 02:205.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/17 02:39 7439-97-602/23/17 05:110.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 21:42 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 21:42 107-13-1200 1.9 1
Benzene 0.90J ug/L 02/28/17 21:42 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 21:42 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 21:42 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 21:42 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 21:42 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 21:42 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 21:42 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 21:42 56-23-51.0 0.25 1
Chlorobenzene 10.5 ug/L 02/28/17 21:42 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 21:42 75-00-310.0 0.54 1
Chloroform ND ug/L 02/28/17 21:42 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 21:42 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 21:42 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 21:42 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 21:42 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 21:42 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.38J ug/L 02/28/17 21:42 95-50-15.0 0.30 1
1,4-Dichlorobenzene 3.5 ug/L 02/28/17 21:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 21:42 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 21:42 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 21:42 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 21:42 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-2 Lab ID: 92330523002 Collected: 02/16/17 16:40 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/28/17 21:42 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 21:42 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 21:42 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/28/17 21:42 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 21:42 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 21:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 21:42 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 21:42 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 21:42 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 21:42 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 21:42 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 21:42 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 21:42 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 21:42 127-18-41.0 0.46 1
Tetrahydrofuran 7.4J ug/L 02/28/17 21:42 109-99-910.0 3.1 1
Toluene ND ug/L 02/28/17 21:42 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 21:42 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 21:42 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 21:42 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 21:42 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 21:42 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 21:42 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 21:42 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/28/17 21:42 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)92 %02/28/17 21:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %02/28/17 21:42 17060-07-070-130 1
Toluene-d8 (S)97 %02/28/17 21:42 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 566000 ug/L 02/24/17 03:515000 1000 1
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous 2.6 mg/L 03/04/17 12:50 H1,N20.50 0.50 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/22/17 13:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 11500 ug/L 02/22/17 21:45 B202/18/17 02:302000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3140J ug/L 04/06/17 16:08 14808-79-8 H3250000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-2 Lab ID: 92330523002 Collected: 02/16/17 16:40 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 02/18/17 00:4910000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 113000 ug/L 02/24/17 03:25 16887-00-65000 2500 5
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 89000 ug/L 02/22/17 00:2225000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 24400 ug/L 03/01/17 14:09 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-8 Lab ID: 92330523003 Collected: 02/16/17 16:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:41 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:41 7440-38-202/20/17 19:5510.0 5.0 1
Barium 86.5J ug/L 02/24/17 06:41 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:41 7440-41-702/20/17 19:551.0 0.50 1
Cadmium 1.1 ug/L 02/24/17 06:41 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:41 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:41 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:41 7440-50-802/20/17 19:5510.0 2.5 1
Lead 2.6J ug/L 02/24/17 06:41 7439-92-102/20/17 19:5510.0 2.5 1
Nickel ND ug/L 02/24/17 06:41 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:41 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:41 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium ND ug/L 02/24/17 06:41 7440-62-202/20/17 19:5525.0 2.5 1
Zinc ND ug/L 02/24/17 06:41 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 18:33 7440-28-002/23/17 02:205.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/24/17 02:42 7439-97-602/23/17 05:110.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 21:59 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 21:59 107-13-1200 1.9 1
Benzene ND ug/L 02/28/17 21:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 21:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 21:59 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 21:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 21:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 21:59 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 21:59 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 21:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/28/17 21:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 21:59 75-00-310.0 0.54 1
Chloroform 0.42J ug/L 02/28/17 21:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 21:59 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 21:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 21:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 21:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 21:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/28/17 21:59 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/28/17 21:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 21:59 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 21:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 21:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 21:59 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-8 Lab ID: 92330523003 Collected: 02/16/17 16:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 02/28/17 21:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 21:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 21:59 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/28/17 21:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 21:59 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 21:59 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 21:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 21:59 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 21:59 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 21:59 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 21:59 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 21:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 21:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 21:59 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/28/17 21:59 109-99-910.0 3.1 1
Toluene ND ug/L 02/28/17 21:59 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 21:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 21:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 21:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 21:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 21:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 21:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 21:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/28/17 21:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/28/17 21:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %02/28/17 21:59 17060-07-070-130 1
Toluene-d8 (S)99 %02/28/17 21:59 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 02/24/17 04:145000 1000 1
Analytical Method: SM 3500-Fe BIron, Ferrous
Iron, Ferrous ND mg/L 03/04/17 12:50 H1,N20.50 0.50 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/22/17 13:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/22/17 21:45 B202/18/17 02:302000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1760J ug/L 04/06/17 16:08 14808-79-8 H3250000 1000 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-8 Lab ID: 92330523003 Collected: 02/16/17 16:00 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 927J ug/L 02/18/17 00:4810000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 8420 ug/L 02/24/17 03:14 16887-00-62000 1000 2
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 40000 ug/L 02/22/17 00:2225000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1720 ug/L 03/01/17 14:23 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-3 Lab ID: 92330523004 Collected: 02/17/17 14:15 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 21:50 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 21:50 7440-38-202/23/17 19:3510.0 5.0 1
Barium 15.7J ug/L 03/02/17 21:50 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 21:50 7440-41-702/23/17 19:351.0 0.50 1
Cadmium 2.0 ug/L 03/02/17 21:50 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 21:50 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 21:50 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 21:50 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 21:50 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 21:50 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 21:50 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 21:50 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/02/17 21:50 7440-62-202/23/17 19:3525.0 2.5 1
Zinc 8.4J ug/L 03/02/17 21:50 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 19:40 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 19:34 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 19:34 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 19:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 19:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 19:34 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 19:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 19:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 19:34 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 19:34 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 19:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 19:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 19:34 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 19:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 19:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 19:34 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 19:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 19:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 19:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 19:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 19:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 19:34 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 19:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 19:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 19:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 19:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 19:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 19:34 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-3 Lab ID: 92330523004 Collected: 02/17/17 14:15 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 19:34 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 19:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 19:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 19:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 19:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 19:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 19:34 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 19:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 19:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 19:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 19:34 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 19:34 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 19:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 19:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 19:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 19:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 19:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 19:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 19:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 19:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 19:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %02/27/17 19:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %02/27/17 19:34 17060-07-070-130 1
Toluene-d8 (S)98 %02/27/17 19:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-4 Lab ID: 92330523005 Collected: 02/17/17 13:32 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 21:53 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 21:53 7440-38-202/23/17 19:3510.0 5.0 1
Barium 60.9J ug/L 03/02/17 21:53 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 21:53 7440-41-702/23/17 19:351.0 0.50 1
Cadmium ND ug/L 03/02/17 21:53 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 21:53 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 21:53 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 21:53 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 21:53 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 21:53 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 21:53 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 21:53 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/02/17 21:53 7440-62-202/23/17 19:3525.0 2.5 1
Zinc ND ug/L 03/02/17 21:53 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.027J ug/L 02/24/17 19:42 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 19:51 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 19:51 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 19:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 19:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 19:51 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 19:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 19:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 19:51 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 19:51 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 19:51 56-23-51.0 0.25 1
Chlorobenzene 0.36J ug/L 02/27/17 19:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 19:51 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 19:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 19:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 19:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 19:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 19:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 19:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 19:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 19:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 19:51 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 19:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 19:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 19:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 19:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 19:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 19:51 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-4 Lab ID: 92330523005 Collected: 02/17/17 13:32 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 19:51 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 19:51 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 19:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 19:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 19:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 19:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 19:51 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 19:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 19:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 19:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 19:51 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 19:51 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 19:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 19:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 19:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 19:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 19:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 19:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 19:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 19:51 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 19:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %02/27/17 19:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %02/27/17 19:51 17060-07-070-130 1
Toluene-d8 (S)108 %02/27/17 19:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-5 Lab ID: 92330523006 Collected: 02/17/17 13:50 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 21:56 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 21:56 7440-38-202/23/17 19:3510.0 5.0 1
Barium 37.3J ug/L 03/02/17 21:56 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 21:56 7440-41-702/23/17 19:351.0 0.50 1
Cadmium 2.3 ug/L 03/02/17 21:56 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 21:56 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 21:56 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 21:56 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 21:56 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 21:56 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 21:56 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 21:56 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/02/17 21:56 7440-62-202/23/17 19:3525.0 2.5 1
Zinc 12.7 ug/L 03/02/17 21:56 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 19:43 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 20:08 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 20:08 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 20:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 20:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 20:08 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 20:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 20:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 20:08 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 20:08 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 20:08 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 20:08 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 20:08 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 20:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 20:08 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 20:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 20:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 20:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 20:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 20:08 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 20:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 20:08 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 20:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 20:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 20:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 20:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 20:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 20:08 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-5 Lab ID: 92330523006 Collected: 02/17/17 13:50 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 20:08 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 20:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 20:08 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 20:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 20:08 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 20:08 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 20:08 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 20:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 20:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 20:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 20:08 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 20:08 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 20:08 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 20:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 20:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 20:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 20:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 20:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 20:08 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 20:08 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 20:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/27/17 20:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %02/27/17 20:08 17060-07-070-130 1
Toluene-d8 (S)96 %02/27/17 20:08 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-6 Lab ID: 92330523007 Collected: 02/17/17 14:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 22:08 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 22:08 7440-38-202/23/17 19:3510.0 5.0 1
Barium 77.9J ug/L 03/02/17 22:08 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 22:08 7440-41-702/23/17 19:351.0 0.50 1
Cadmium 1.6 ug/L 03/02/17 22:08 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 22:08 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 22:08 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 22:08 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 22:08 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 22:08 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 22:08 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 22:08 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/02/17 22:08 7440-62-202/23/17 19:3525.0 2.5 1
Zinc 6.0J ug/L 03/02/17 22:08 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 19:45 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 20:25 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 20:25 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 20:25 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 20:25 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 20:25 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 20:25 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 20:25 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 20:25 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 20:25 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 20:25 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 20:25 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 20:25 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 20:25 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 20:25 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 20:25 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 20:25 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 20:25 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 20:25 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 20:25 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 20:25 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 20:25 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 20:25 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 20:25 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 20:25 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 20:25 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 20:25 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 20:25 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-6 Lab ID: 92330523007 Collected: 02/17/17 14:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 20:25 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 20:25 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 20:25 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 20:25 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 20:25 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 20:25 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 20:25 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 20:25 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 20:25 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 20:25 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 20:25 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 20:25 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 20:25 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 20:25 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 20:25 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 20:25 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 20:25 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 20:25 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 20:25 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 20:25 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 20:25 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/27/17 20:25 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %02/27/17 20:25 17060-07-070-130 1
Toluene-d8 (S)95 %02/27/17 20:25 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-7 Lab ID: 92330523008 Collected: 02/17/17 16:10 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 22:12 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 22:12 7440-38-202/23/17 19:3510.0 5.0 1
Barium 36.4J ug/L 03/02/17 22:12 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 22:12 7440-41-702/23/17 19:351.0 0.50 1
Cadmium 0.54J ug/L 03/02/17 22:12 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 22:12 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 22:12 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 22:12 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 22:12 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 22:12 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 22:12 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 22:12 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/02/17 22:12 7440-62-202/23/17 19:3525.0 2.5 1
Zinc ND ug/L 03/02/17 22:12 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 19:47 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 20:42 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 20:42 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 20:42 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 20:42 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 20:42 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 20:42 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 20:42 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 20:42 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 20:42 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 20:42 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 20:42 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 20:42 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 20:42 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 20:42 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 20:42 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 20:42 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 20:42 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 20:42 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 20:42 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 20:42 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 20:42 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 20:42 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 20:42 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 20:42 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 20:42 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 20:42 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 20:42 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-7 Lab ID: 92330523008 Collected: 02/17/17 16:10 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 20:42 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 20:42 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 20:42 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 20:42 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 20:42 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 20:42 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 20:42 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 20:42 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 20:42 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 20:42 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 20:42 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 20:42 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 20:42 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 20:42 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 20:42 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 20:42 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 20:42 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 20:42 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 20:42 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 20:42 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 20:42 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/27/17 20:42 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %02/27/17 20:42 17060-07-070-130 1
Toluene-d8 (S)92 %02/27/17 20:42 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-11 Lab ID: 92330523009 Collected: 02/17/17 13:20 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/02/17 22:15 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/02/17 22:15 7440-38-202/23/17 19:3510.0 5.0 1
Barium 187 ug/L 03/02/17 22:15 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/02/17 22:15 7440-41-702/23/17 19:351.0 0.50 1
Cadmium 0.95J ug/L 03/02/17 22:15 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/02/17 22:15 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/02/17 22:15 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/02/17 22:15 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/02/17 22:15 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/02/17 22:15 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/02/17 22:15 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/02/17 22:15 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium 2.5J ug/L 03/02/17 22:15 7440-62-202/23/17 19:3525.0 2.5 1
Zinc ND ug/L 03/02/17 22:15 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 19:55 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 20:58 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/27/17 20:58 107-13-1200 1.9 1
Benzene ND ug/L 02/27/17 20:58 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 20:58 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 20:58 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 20:58 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 20:58 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 20:58 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 20:58 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 20:58 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 20:58 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 20:58 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 20:58 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 20:58 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 20:58 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 20:58 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 20:58 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 20:58 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 20:58 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/27/17 20:58 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 20:58 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/27/17 20:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 20:58 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 20:58 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.21J ug/L 02/27/17 20:58 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 20:58 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 20:58 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 83
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330523
Wayne Closed LF
Sample: MW-11 Lab ID: 92330523009 Collected: 02/17/17 13:20 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/27/17 20:58 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 20:58 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 20:58 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/27/17 20:58 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 20:58 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/27/17 20:58 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 20:58 108-10-1100 0.33 1
Styrene ND ug/L 02/27/17 20:58 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 20:58 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 20:58 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 20:58 127-18-41.0 0.46 1
Tetrahydrofuran 4.1J ug/L 02/27/17 20:58 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 20:58 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/27/17 20:58 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 20:58 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 20:58 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 20:58 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 20:58 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 20:58 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 20:58 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 20:58 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %02/27/17 20:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %02/27/17 20:58 17060-07-070-130 1
Toluene-d8 (S)104 %02/27/17 20:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349177
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92330523001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936998
Associated Lab Samples:92330523001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 02/23/17 17:030.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936999LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396004
1937001
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 93 75-12591 1 252.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349477
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938932
Associated Lab Samples:92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 02/24/17 02:060.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938933LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938934MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330674021
1938935
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 100 75-12597 3 252.5ND 2.5 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348994
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936214
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 02/24/17 05:123.9
Arsenic ug/L ND 10.0 02/24/17 05:125.0
Barium ug/L ND 5.0 02/24/17 05:122.5
Beryllium ug/L ND 1.0 02/24/17 05:120.50
Cadmium ug/L ND 1.0 02/24/17 05:120.50
Chromium ug/L ND 5.0 02/24/17 05:122.5
Cobalt ug/L ND 5.0 02/24/17 05:122.5
Copper ug/L ND 5.0 02/24/17 05:122.5
Lead ug/L ND 5.0 02/24/17 05:122.5
Nickel ug/L ND 5.0 02/24/17 05:122.5
Selenium ug/L ND 10.0 02/24/17 05:125.0
Silver ug/L ND 5.0 02/24/17 05:122.5
Vanadium ug/L ND 5.0 02/24/17 05:122.5
Zinc ug/L ND 10.0 02/24/17 05:155.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936215LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 479500 96 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 493500 99 80-120
Beryllium ug/L 491500 98 80-120
Cadmium ug/L 479500 96 80-120
Chromium ug/L 496500 99 80-120
Cobalt ug/L 478500 96 80-120
Copper ug/L 487500 97 80-120
Lead ug/L 470500 94 80-120
Nickel ug/L 481500 96 80-120
Selenium ug/L 467500 93 80-120
Silver ug/L 239250 96 80-120
Vanadium ug/L 482500 96 80-120
Zinc ug/L 472500 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-12596 2 20500ND489 478
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 97 75-12595 2 20500ND483 473
Barium ug/L 500 96 75-12595 1 205007.2 488 481
Beryllium ug/L 500 97 75-12595 1 20500ND483 477
Cadmium ug/L 500 96 75-12594 3 20500ND482 470
Chromium ug/L 500 98 75-12595 3 20500ND488 476
Cobalt ug/L 500 96 75-12593 2 20500ND478 466
Copper ug/L 500 98 75-12595 2 20500ND488 477
Lead ug/L 500 93 75-12591 2 20500ND467 457
Nickel ug/L 500 96 75-12593 3 20500ND478 466
Selenium ug/L 500 94 75-12592 2 20500ND471 462
Silver ug/L 250 96 75-12593 3 20250ND240 234
Vanadium ug/L 500 99 75-12595 3 20500ND493 476
Zinc ug/L 500 96 75-12594 3 20500ND482 470
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349552
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939169
Associated Lab Samples:92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 03/02/17 20:353.9
Arsenic ug/L ND 10.0 03/02/17 20:355.0
Barium ug/L ND 5.0 03/02/17 20:352.5
Beryllium ug/L ND 1.0 03/02/17 20:350.50
Cadmium ug/L ND 1.0 03/02/17 20:350.50
Chromium ug/L ND 5.0 03/02/17 20:352.5
Cobalt ug/L ND 5.0 03/02/17 20:352.5
Copper ug/L ND 5.0 03/02/17 20:352.5
Lead ug/L ND 5.0 03/02/17 20:352.5
Nickel ug/L ND 5.0 03/02/17 20:352.5
Selenium ug/L ND 10.0 03/02/17 20:355.0
Silver ug/L ND 5.0 03/02/17 20:352.5
Vanadium ug/L ND 5.0 03/02/17 20:352.5
Zinc ug/L ND 10.0 03/02/17 20:355.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939170LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 509500 102 80-120
Arsenic ug/L 487500 97 80-120
Barium ug/L 448500 90 80-120
Beryllium ug/L 459500 92 80-120
Cadmium ug/L 476500 95 80-120
Chromium ug/L 451500 90 80-120
Cobalt ug/L 482500 96 80-120
Copper ug/L 491500 98 80-120
Lead ug/L 475500 95 80-120
Nickel ug/L 474500 95 80-120
Selenium ug/L 492500 98 80-120
Silver ug/L 239250 96 80-120
Vanadium ug/L 467500 93 80-120
Zinc ug/L 466500 93 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939171MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330875002
1939172
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-125103 4 20500ND496 518
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939171MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330875002
1939172
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 97 75-12599 3 20500ND485 498
Barium ug/L 500 88 75-12590 1 20500182624 632
Beryllium ug/L 500 91 75-12593 3 20500ND455 468
Cadmium ug/L 500 92 75-12596 5 20500ND461 482
Chromium ug/L 500 87 75-12590 3 20500ND439 452
Cobalt ug/L 500 92 75-12597 5 20500ND463 486
Copper ug/L 500 94 75-12597 3 20500ND472 486
Lead ug/L 500 91 75-12595 4 20500ND453 473
Nickel ug/L 500 90 75-12594 4 2050013.2 464 485
Selenium ug/L 500 95 75-12599 4 20500ND480 499
Silver ug/L 250 93 75-12595 3 20250ND232 239
Vanadium ug/L 500 92 75-12595 3 20500ND459 473
Zinc ug/L 500 90 75-12595 5 2050016.6 467 490
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349257
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937708
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 18:000.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937709LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.7100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937710MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330674021
1937711
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 97 75-12595 2 20100ND97.5 95.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349508
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938999
Associated Lab Samples:92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 18:580.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939000LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 96.5100 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939932MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330674028
1939933
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 90 75-12597 8 201000.29 90.0 97.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349990
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941517
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/28/17 19:280.33
1,1,1-Trichloroethane ug/L ND 1.0 02/28/17 19:280.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/28/17 19:280.40
1,1,2-Trichloroethane ug/L ND 1.0 02/28/17 19:280.29
1,1-Dichloroethane ug/L ND 5.0 02/28/17 19:280.32
1,1-Dichloroethene ug/L ND 5.0 02/28/17 19:280.56
1,2,3-Trichloropropane ug/L ND 1.0 02/28/17 19:280.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/28/17 19:282.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/28/17 19:280.27
1,2-Dichlorobenzene ug/L ND 5.0 02/28/17 19:280.30
1,2-Dichloroethane ug/L ND 1.0 02/28/17 19:280.24
1,2-Dichloropropane ug/L ND 1.0 02/28/17 19:280.27
1,4-Dichlorobenzene ug/L ND 1.0 02/28/17 19:280.33
2-Butanone (MEK)ug/L ND 100 02/28/17 19:280.96
2-Hexanone ug/L ND 50.0 02/28/17 19:280.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/28/17 19:280.33
Acetone ug/L ND 100 02/28/17 19:2810.0
Acrylonitrile ug/L ND 200 02/28/17 19:281.9
Benzene ug/L ND 1.0 02/28/17 19:280.25
Bromochloromethane ug/L ND 3.0 02/28/17 19:280.17
Bromodichloromethane ug/L ND 1.0 02/28/17 19:280.18
Bromoform ug/L ND 3.0 02/28/17 19:280.26
Bromomethane ug/L ND 10.0 02/28/17 19:280.29
Carbon disulfide ug/L ND 100 02/28/17 19:281.2
Carbon tetrachloride ug/L ND 1.0 02/28/17 19:280.25
Chlorobenzene ug/L ND 3.0 02/28/17 19:280.23
Chloroethane ug/L ND 10.0 02/28/17 19:280.54
Chloroform ug/L ND 5.0 02/28/17 19:280.14
Chloromethane ug/L ND 1.0 02/28/17 19:280.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/28/17 19:280.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/28/17 19:280.13
Dibromochloromethane ug/L ND 3.0 02/28/17 19:280.21
Dibromomethane ug/L ND 10.0 02/28/17 19:280.21
Ethylbenzene ug/L ND 1.0 02/28/17 19:280.30
Iodomethane ug/L ND 10.0 02/28/17 19:280.32
Methylene Chloride ug/L ND 1.0 02/28/17 19:280.97
Styrene ug/L ND 1.0 02/28/17 19:280.26
Tetrachloroethene ug/L ND 1.0 02/28/17 19:280.46
Tetrahydrofuran ug/L ND 10.0 02/28/17 19:283.1
Toluene ug/L ND 1.0 02/28/17 19:280.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/28/17 19:280.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941517
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/28/17 19:280.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/28/17 19:281.0
Trichloroethene ug/L ND 1.0 02/28/17 19:280.47
Trichlorofluoromethane ug/L ND 1.0 02/28/17 19:280.20
Vinyl acetate ug/L ND 50.0 02/28/17 19:280.35
Vinyl chloride ug/L ND 1.0 02/28/17 19:280.62
Xylene (Total)ug/L ND 5.0 02/28/17 19:280.66
1,2-Dichloroethane-d4 (S)%96 70-130 02/28/17 19:28
4-Bromofluorobenzene (S)%92 70-130 02/28/17 19:28
Toluene-d8 (S)%97 70-130 02/28/17 19:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941518LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.450 101 80-125
1,1,1-Trichloroethane ug/L 49.950 100 71-129
1,1,2,2-Tetrachloroethane ug/L 48.750 97 79-124
1,1,2-Trichloroethane ug/L 52.750 105 85-125
1,1-Dichloroethane ug/L 48.750 97 73-126
1,1-Dichloroethene ug/L 52.350 105 66-135
1,2,3-Trichloropropane ug/L 48.250 96 75-130
1,2-Dibromo-3-chloropropane ug/L 48.450 97 71-133
1,2-Dibromoethane (EDB)ug/L 49.150 98 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 49.550 99 67-128
1,2-Dichloropropane ug/L 51.750 103 75-132
1,4-Dichlorobenzene ug/L 49.350 99 78-130
2-Butanone (MEK)ug/L 105100 105 61-144
2-Hexanone ug/L 103100 103 68-143
4-Methyl-2-pentanone (MIBK)ug/L 105100 105 72-135
Acetone ug/L 110100 110 48-146
Acrylonitrile ug/L 265250 106 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 50.850 102 71-125
Bromodichloromethane ug/L 54.050 108 78-124
Bromoform ug/L 48.550 97 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 47.6J50 95 50-160
Carbon tetrachloride ug/L 50.850 102 69-131
Chlorobenzene ug/L 51.450 103 81-122
Chloroethane ug/L 52.150 104 39-148
Chloroform ug/L 49.650 99 73-127
Chloromethane ug/L 48.350 97 44-146
cis-1,2-Dichloroethene ug/L 50.050 100 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941518LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 52.050 104 78-125
Dibromomethane ug/L 53.150 106 82-120
Ethylbenzene ug/L 49.650 99 79-121
Iodomethane ug/L 111100 111 39-154
Methylene Chloride ug/L 52.350 105 64-133
Styrene ug/L 50.550 101 84-126
Tetrachloroethene ug/L 48.550 97 78-122
Tetrahydrofuran ug/L 527500 105 69-148
Toluene ug/L 52.250 104 80-121
trans-1,2-Dichloroethene ug/L 50.850 102 71-127
trans-1,3-Dichloropropene ug/L 53.750 107 69-141
trans-1,4-Dichloro-2-butene ug/L 47.6J50 95 40-160
Trichloroethene ug/L 50.350 101 78-122
Trichlorofluoromethane ug/L 53.950 108 53-137
Vinyl acetate ug/L 109100 109 40-160
Vinyl chloride ug/L 43.050 86 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1942951MATRIX SPIKE SAMPLE:
MSSpike
Result
92330523002
1,1,1,2-Tetrachloroethane ug/L 20.120 100 70-130ND
1,1,1-Trichloroethane ug/L 21.620 108 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,2-Trichloroethane ug/L 19.920 99 70-130ND
1,1-Dichloroethane ug/L 20.020 100 70-130ND
1,1-Dichloroethene ug/L 21.920 110 70-166ND
1,2,3-Trichloropropane ug/L 20.420 102 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.420 97 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.720 103 70-130ND
1,2-Dichlorobenzene ug/L 20.720 102 70-1300.38J
1,2-Dichloroethane ug/L 18.720 93 70-130ND
1,2-Dichloropropane ug/L 20.420 102 70-130ND
1,4-Dichlorobenzene ug/L 23.620 101 70-1303.5
2-Butanone (MEK)ug/L 37.7J40 94 70-130ND
2-Hexanone ug/L 38.9J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 40.6J40 102 70-130ND
Acetone ug/L 39.3J40 82 70-130ND
Acrylonitrile ug/L 101J100 101 70-130ND
Benzene ug/L 21.920 105 70-1480.90J
Bromochloromethane ug/L 19.820 99 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1942951MATRIX SPIKE SAMPLE:
MSSpike
Result
92330523002
Bromodichloromethane ug/L 20.920 105 70-130ND
Bromoform ug/L 18.820 94 70-130ND
Bromomethane ug/L 15.820 79 70-130ND
Carbon disulfide ug/L 18.6J20 93 70-130ND
Carbon tetrachloride ug/L 21.720 109 70-130ND
Chlorobenzene ug/L 34.920 122 70-14610.5
Chloroethane ug/L 20.020 100 70-130ND
Chloroform ug/L 19.920 99 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.820 99 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 102 70-130ND
Dibromochloromethane ug/L 20.220 101 70-130ND
Dibromomethane ug/L 18.620 93 70-130ND
Ethylbenzene ug/L 20.820 104 70-130ND
Iodomethane ug/L 29.640 74 70-130ND
Methylene Chloride ug/L 18.520 92 70-130ND
Styrene ug/L 20.420 102 70-130ND
Tetrachloroethene ug/L 21.620 108 70-130ND
Tetrahydrofuran ug/L 214200 103 70-1307.4J
Toluene ug/L 20.120 100 70-155ND
trans-1,2-Dichloroethene ug/L 21.220 106 70-130ND
trans-1,3-Dichloropropene ug/L 19.120 96 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.7J20 88 70-130ND
Trichloroethene ug/L 20.620 103 69-151ND
Trichlorofluoromethane ug/L 22.320 112 70-130ND
Vinyl acetate ug/L 37.0J40 92 70-130ND
Vinyl chloride ug/L 16.420 82 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1942950SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1942950SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L 0.33J 300.42J
Chloromethane ug/L 0.21J 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%89 22111
4-Bromofluorobenzene (S)%97 196
Toluene-d8 (S)%105 699
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350034
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/27/17 16:450.33
1,1,1-Trichloroethane ug/L ND 1.0 02/27/17 16:450.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/27/17 16:450.40
1,1,2-Trichloroethane ug/L ND 1.0 02/27/17 16:450.29
1,1-Dichloroethane ug/L ND 5.0 02/27/17 16:450.32
1,1-Dichloroethene ug/L ND 5.0 02/27/17 16:450.56
1,2,3-Trichloropropane ug/L ND 1.0 02/27/17 16:450.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/27/17 16:452.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/27/17 16:450.27
1,2-Dichlorobenzene ug/L ND 5.0 02/27/17 16:450.30
1,2-Dichloroethane ug/L ND 1.0 02/27/17 16:450.24
1,2-Dichloropropane ug/L ND 1.0 02/27/17 16:450.27
1,4-Dichlorobenzene ug/L ND 1.0 02/27/17 16:450.33
2-Butanone (MEK)ug/L ND 100 02/27/17 16:450.96
2-Hexanone ug/L ND 50.0 02/27/17 16:450.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/27/17 16:450.33
Acetone ug/L ND 100 02/27/17 16:4510.0
Acrylonitrile ug/L ND 200 02/27/17 16:451.9
Benzene ug/L ND 1.0 02/27/17 16:450.25
Bromochloromethane ug/L ND 3.0 02/27/17 16:450.17
Bromodichloromethane ug/L ND 1.0 02/27/17 16:450.18
Bromoform ug/L ND 3.0 02/27/17 16:450.26
Bromomethane ug/L ND 10.0 02/27/17 16:450.29
Carbon disulfide ug/L ND 100 02/27/17 16:451.2
Carbon tetrachloride ug/L ND 1.0 02/27/17 16:450.25
Chlorobenzene ug/L ND 3.0 02/27/17 16:450.23
Chloroethane ug/L ND 10.0 02/27/17 16:450.54
Chloroform ug/L ND 5.0 02/27/17 16:450.14
Chloromethane ug/L ND 1.0 02/27/17 16:450.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.13
Dibromochloromethane ug/L ND 3.0 02/27/17 16:450.21
Dibromomethane ug/L ND 10.0 02/27/17 16:450.21
Ethylbenzene ug/L ND 1.0 02/27/17 16:450.30
Iodomethane ug/L ND 10.0 02/27/17 16:450.32
Methylene Chloride ug/L ND 1.0 02/27/17 16:450.97
Styrene ug/L ND 1.0 02/27/17 16:450.26
Tetrachloroethene ug/L ND 1.0 02/27/17 16:450.46
Tetrahydrofuran ug/L ND 10.0 02/27/17 16:453.1
Toluene ug/L ND 1.0 02/27/17 16:450.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92330523004, 92330523005, 92330523006, 92330523007, 92330523008, 92330523009
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/27/17 16:451.0
Trichloroethene ug/L ND 1.0 02/27/17 16:450.47
Trichlorofluoromethane ug/L ND 1.0 02/27/17 16:450.20
Vinyl acetate ug/L ND 50.0 02/27/17 16:450.35
Vinyl chloride ug/L ND 1.0 02/27/17 16:450.62
Xylene (Total)ug/L ND 5.0 02/27/17 16:450.66
1,2-Dichloroethane-d4 (S)%98 70-130 02/27/17 16:45
4-Bromofluorobenzene (S)%97 70-130 02/27/17 16:45
Toluene-d8 (S)%93 70-130 02/27/17 16:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.250 96 80-125
1,1,1-Trichloroethane ug/L 47.150 94 71-129
1,1,2,2-Tetrachloroethane ug/L 47.350 95 79-124
1,1,2-Trichloroethane ug/L 49.450 99 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 51.250 102 66-135
1,2,3-Trichloropropane ug/L 46.550 93 75-130
1,2-Dibromo-3-chloropropane ug/L 48.350 97 71-133
1,2-Dibromoethane (EDB)ug/L 47.350 95 83-124
1,2-Dichlorobenzene ug/L 47.750 95 80-133
1,2-Dichloroethane ug/L 42.850 86 67-128
1,2-Dichloropropane ug/L 47.250 94 75-132
1,4-Dichlorobenzene ug/L 45.550 91 78-130
2-Butanone (MEK)ug/L 95.0J100 95 61-144
2-Hexanone ug/L 96.6100 97 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.2J100 97 72-135
Acetone ug/L 103100 103 48-146
Acrylonitrile ug/L 239250 96 40-160
Benzene ug/L 48.750 97 80-125
Bromochloromethane ug/L 46.350 93 71-125
Bromodichloromethane ug/L 50.250 100 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 49.150 98 40-160
Carbon disulfide ug/L 49.1J50 98 50-160
Carbon tetrachloride ug/L 48.550 97 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 52.150 104 39-148
Chloroform ug/L 44.250 88 73-127
Chloromethane ug/L 48.850 98 44-146
cis-1,2-Dichloroethene ug/L 44.750 89 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 50.150 100 72-132
Dibromochloromethane ug/L 49.250 98 78-125
Dibromomethane ug/L 48.950 98 82-120
Ethylbenzene ug/L 48.050 96 79-121
Iodomethane ug/L 96.4100 96 39-154
Methylene Chloride ug/L 48.050 96 64-133
Styrene ug/L 48.250 96 84-126
Tetrachloroethene ug/L 48.250 96 78-122
Tetrahydrofuran ug/L 474500 95 69-148
Toluene ug/L 47.650 95 80-121
trans-1,2-Dichloroethene ug/L 47.750 95 71-127
trans-1,3-Dichloropropene ug/L 48.750 97 69-141
trans-1,4-Dichloro-2-butene ug/L 44.3J50 89 40-160
Trichloroethene ug/L 48.550 97 78-122
Trichlorofluoromethane ug/L 58.950 118 53-137
Vinyl acetate ug/L 96.8100 97 40-160
Vinyl chloride ug/L 44.050 88 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 22.920 115 70-130ND
1,1,2-Trichloroethane ug/L 23.220 116 70-130ND
1,1-Dichloroethane ug/L 21.920 109 70-130ND
1,1-Dichloroethene ug/L 23.620 118 70-166ND
1,2,3-Trichloropropane ug/L 22.520 113 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.420 112 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.620 102 70-130ND
1,2-Dichloropropane ug/L 22.420 112 70-130ND
1,4-Dichlorobenzene ug/L 21.520 108 70-130ND
2-Butanone (MEK)ug/L 43.0J40 107 70-130ND
2-Hexanone ug/L 45.5J40 114 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 45.1J40 113 70-130ND
Acetone ug/L 43.1J40 105 70-130ND
Acrylonitrile ug/L 104J100 104 70-130ND
Benzene ug/L 24.420 122 70-148ND
Bromochloromethane ug/L 21.520 107 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
Bromodichloromethane ug/L 23.820 119 70-130ND
Bromoform ug/L 19.720 98 70-130ND
Bromomethane ug/L 20.820 104 70-130ND
Carbon disulfide ug/L 21.2J20 106 70-130ND
Carbon tetrachloride ug/L 24.120 121 70-130ND
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 23.320 117 70-130ND
Chloroform ug/L 21.820 109 70-130ND
Chloromethane ug/L 23.720 118 70-130ND
cis-1,2-Dichloroethene ug/L 21.920 110 70-130ND
cis-1,3-Dichloropropene ug/L 22.720 113 70-130ND
Dibromochloromethane ug/L 24.120 121 70-130ND
Dibromomethane ug/L 21.320 107 70-130ND
Ethylbenzene ug/L 23.220 116 70-130ND
Iodomethane ug/L 43.140 108 70-130ND
Methylene Chloride ug/L 21.920 109 70-130ND
Styrene ug/L 22.520 112 70-130ND
Tetrachloroethene ug/L 24.720 124 70-130ND
Tetrahydrofuran ug/L 211200 106 70-130ND
Toluene ug/L 23.920 120 70-155ND
trans-1,2-Dichloroethene ug/L 22.820 114 70-130ND
trans-1,3-Dichloropropene ug/L 22.420 112 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.3J20 96 70-130ND
Trichloroethene ug/L 24.120 121 69-151ND
Trichlorofluoromethane ug/L 25.020 125 70-130ND
Vinyl acetate ug/L 39.2J40 98 70-130ND
Vinyl chloride ug/L 19.520 98 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 298
4-Bromofluorobenzene (S)%94 392
Toluene-d8 (S)%97 3100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349506
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938991
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/23/17 22:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938992LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4810050000 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330946002
1938994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12094 0 255000093.3 mg/L 141000 141000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938995MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330376003
1938996
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 80-12098 0 2550000ND49300 49200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350845
SM 3500-Fe B
SM 3500-Fe B
Iron, Ferrous
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1946308
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Iron, Ferrous mg/L ND 0.50 N203/04/17 12:500.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1946309LABORATORY CONTROL SAMPLE:
LCSSpike
Iron, Ferrous mg/L 1.5 N21.5 102 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1946310SAMPLE DUPLICATE:
Iron, Ferrous mg/L ND H1,N210ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349321
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937896
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/22/17 13:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937897LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 540J500 108 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330450002
1937899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 104 80-120104 0 10500ND536J 538J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937900MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937901
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 91 80-12090 1 10500ND529J 523J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348843
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1935680
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
BOD, 5 day ug/L ND 2000 02/22/17 21:452000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935681LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 181000198000 91 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1935682SAMPLE DUPLICATE:
BOD, 5 day ug/L ND B210ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
355523
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1972184
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 04/06/17 16:081000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1972185LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 48800J50000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1972186MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330523001
1972187
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L H3500009790-11098 0 1050000ND48900J 49200J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348846
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1935691
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 20.0 02/18/17 00:3110.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935692LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 25102500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1935693MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330435003
1935694
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 95 90-11095 0 1025000.041
mg/L 2420 2420
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349485
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938969
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/24/17 03:04500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938970LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2060020000 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938971MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330523001
1938972
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000012690-110129 2 1010000304015600 15900
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
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Huntersville, NC 28078
[phone]
Page 51 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349235
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937618
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 02/22/17 00:2212500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937619LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 747000750000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937620MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330190006
1937621
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 105 90-110104 1 375000050.0 mg/L 835000 830000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937622MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330433001
1937623
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 99 90-110101 1 3750000345 mg/L 1080000 1100000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 83
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330523
Wayne Closed LF
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350294
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92330523001, 92330523002, 92330523003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1942999
Associated Lab Samples:92330523001, 92330523002, 92330523003
Matrix: Water
AnalyzedMDL
Total Organic Carbon ug/L ND 1000 03/01/17 11:59500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1943000LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2510025000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1943001MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331203020
1943002
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 97 90-11097 0 10250001.7 mg/L 26000 26100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1943003MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330909005
1943004
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 98 90-11098 0 1025000ND24600 24600
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 83
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330523
Wayne Closed LF
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.B2
Analysis conducted outside the EPA method holding time.H1
Sample was received or analysis requested beyond the recognized method holding time.H3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 04/07/2017 05:12 PM
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330523
Wayne Closed LF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330523001 348994 349091MW-1R EPA 3010A EPA 6010
92330523002 348994 349091MW-2 EPA 3010A EPA 6010
92330523003 348994 349091MW-8 EPA 3010A EPA 6010
92330523004 349552 349686MW-3 EPA 3010A EPA 6010
92330523005 349552 349686MW-4 EPA 3010A EPA 6010
92330523006 349552 349686MW-5 EPA 3010A EPA 6010
92330523007 349552 349686MW-6 EPA 3010A EPA 6010
92330523008 349552 349686MW-7 EPA 3010A EPA 6010
92330523009 349552 349686MW-11 EPA 3010A EPA 6010
92330523001 349257 349497MW-1R EPA 3010A EPA 6020B
92330523002 349257 349497MW-2 EPA 3010A EPA 6020B
92330523003 349257 349497MW-8 EPA 3010A EPA 6020B
92330523004 349508 349709MW-3 EPA 3010A EPA 6020B
92330523005 349508 349709MW-4 EPA 3010A EPA 6020B
92330523006 349508 349709MW-5 EPA 3010A EPA 6020B
92330523007 349508 349709MW-6 EPA 3010A EPA 6020B
92330523008 349508 349709MW-7 EPA 3010A EPA 6020B
92330523009 349508 349709MW-11 EPA 3010A EPA 6020B
92330523001 349177 349284MW-1R EPA 7470 EPA 7470
92330523002 349477 349493MW-2 EPA 7470 EPA 7470
92330523003 349477 349493MW-8 EPA 7470 EPA 7470
92330523001 349990MW-1R EPA 8260
92330523002 349990MW-2 EPA 8260
92330523003 349990MW-8 EPA 8260
92330523004 350034MW-3 EPA 8260
92330523005 350034MW-4 EPA 8260
92330523006 350034MW-5 EPA 8260
92330523007 350034MW-6 EPA 8260
92330523008 350034MW-7 EPA 8260
92330523009 350034MW-11 EPA 8260
92330523001 349506MW-1R SM 2320B
92330523002 349506MW-2 SM 2320B
92330523003 349506MW-8 SM 2320B
92330523001 350845MW-1R SM 3500-Fe B
92330523002 350845MW-2 SM 3500-Fe B
92330523003 350845MW-8 SM 3500-Fe B
92330523001 349321MW-1R SM 4500-S2D
92330523002 349321MW-2 SM 4500-S2D
92330523003 349321MW-8 SM 4500-S2D
92330523001 348843 348850MW-1R SM 5210B SM 5210B
92330523002 348843 348850MW-2 SM 5210B SM 5210B
92330523003 348843 348850MW-8 SM 5210B SM 5210B
92330523001 355523MW-1R EPA 300.0
REPORT OF LABORATORY ANALYSIS
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#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330523
Wayne Closed LF
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330523002 355523MW-2 EPA 300.0
92330523003 355523MW-8 EPA 300.0
92330523001 348846MW-1R EPA 353.2
92330523002 348846MW-2 EPA 353.2
92330523003 348846MW-8 EPA 353.2
92330523001 349485MW-1R SM 4500-Cl-E
92330523002 349485MW-2 SM 4500-Cl-E
92330523003 349485MW-8 SM 4500-Cl-E
92330523001 349235MW-1R SM 5220D
92330523002 349235MW-2 SM 5220D
92330523003 349235MW-8 SM 5220D
92330523001 350294MW-1R SM 5310B
92330523002 350294MW-2 SM 5310B
92330523003 350294MW-8 SM 5310B
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
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Report ID: 21785 - 909872 Page 1 of 17
Trey Carter
Pace Analytical Charlotte
9800 Kincey Ave
Suite 100
Huntersville, NC 28078
April 6, 2017
RE:
Pace Workorder:
Wayne Closed LF / 92330523
Dear Trey Carter:
21785
Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, February 22, 2017.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 04/06/2017
[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
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LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
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SAMPLE SUMMARY
Workorder: 21785 Wayne Closed LF / 92330523
Lab ID Sample ID Matrix Date Collected Date Received
217850001 MW-1R Water 2/16/2017 15:00 2/22/2017 11:52
217850002 MW-1R Bubble Strip 2/16/2017 15:00 2/22/2017 11:52
217850003 MW-2 Water 2/16/2017 16:40 2/22/2017 11:52
217850004 MW-2 Bubble Strip 2/16/2017 16:40 2/22/2017 11:52
217850005 MW-8 Water 2/16/2017 16:00 2/22/2017 11:52
217850006 MW-8 Bubble Strip 2/16/2017 16:00 2/22/2017 11:52
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PROJECT SUMMARY
Workorder: 21785 Wayne Closed LF / 92330523
Workorder Comments
The container pH for samples 21785 (0003) were measured as below the expected pH (< 10) for those samples preserved with
trisodium phosphate, as assigned to PAES method AM20GAx.
This report is being revised and reissued to correct the "J" value reporting.
This report is being re-issued following corrections made to incorporate the available result qualifiers and to adjust the sample
identification for sample 21785 (0003-0004) as MW-2; 03/10/2017.
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-1R
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 15:00
EDonors - PAES
Analysis Desc: AM23G Analytical Method: AM23G
Lactic Acid 0.026J mg/l 0.20 1 2/25/2017 07:25 KB0.0060
Acetic Acid 0.018J mg/l 0.10 1 2/25/2017 07:25 KB B0.0070
Propionic Acid 0.0090U mg/l 0.10 1 2/25/2017 07:25 KB0.0090
Formic Acid 0.015J mg/l 0.10 1 2/25/2017 07:25 KB B0.0050
Butyric Acid 0.0070U mg/l 0.10 1 2/25/2017 07:25 KB0.0070
Pyruvic Acid 0.0070U mg/l 0.10 1 2/25/2017 07:25 KB0.0070
i-Pentanoic Acid 0.0070U mg/l 0.10 1 2/25/2017 07:25 KB0.0070
Pentanoic Acid 0.0060U mg/l 0.10 1 2/25/2017 07:25 KB0.0060
i-Hexanoic Acid 0.0040U mg/l 0.20 1 2/25/2017 07:25 KB0.0040
Hexanoic Acid 0.0070U mg/l 0.20 1 2/25/2017 07:25 KB0.0070
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Methane 0.032J ug/l 0.50 1 2/23/2017 13:27 BW n0.027
Ethane 0.0030U ug/l 0.10 1 2/23/2017 13:27 BW n0.0030
Ethene 0.0028J ug/l 0.10 1 2/23/2017 13:27 BW n0.0010
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-1R
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 15:00
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 1.8 nM 0.60 1 2/27/2017 12:59 MM n0.075
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-2
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 16:40
EDonors - PAES
Analysis Desc: AM23G Analytical Method: AM23G
Lactic Acid 0.070J mg/l 0.20 1 2/25/2017 08:28 KB0.0060
Acetic Acid 0.050J mg/l 0.10 1 2/25/2017 08:28 KB B0.0070
Propionic Acid 0.0090U mg/l 0.10 1 2/25/2017 08:28 KB0.0090
Formic Acid 0.076J mg/l 0.10 1 2/25/2017 08:28 KB B0.0050
Butyric Acid 0.0070U mg/l 0.10 1 2/25/2017 08:28 KB0.0070
Pyruvic Acid 0.017J mg/l 0.10 1 2/25/2017 08:28 KB0.0070
i-Pentanoic Acid 0.0070U mg/l 0.10 1 2/25/2017 08:28 KB0.0070
Pentanoic Acid 0.0060U mg/l 0.10 1 2/25/2017 08:28 KB0.0060
i-Hexanoic Acid 0.0040U mg/l 0.20 1 2/25/2017 08:28 KB0.0040
Hexanoic Acid 0.0070U mg/l 0.20 1 2/25/2017 08:28 KB0.0070
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Methane 7000 ug/l 0.50 1 2/23/2017 13:06 BW n0.027
Ethane 5.0 ug/l 0.10 1 2/23/2017 13:06 BW n0.0030
Ethene 0.15 ug/l 0.10 1 2/23/2017 13:06 BW n0.0010
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-2
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850004
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 16:40
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 1.6 nM 0.60 1 2/27/2017 13:12 MM n0.075
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-8
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850005
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 16:00
EDonors - PAES
Analysis Desc: AM23G Analytical Method: AM23G
Lactic Acid 0.039J mg/l 0.20 1 2/25/2017 09:32 KB0.0060
Acetic Acid 0.028J mg/l 0.10 1 2/25/2017 09:32 KB B0.0070
Propionic Acid 0.0090U mg/l 0.10 1 2/25/2017 09:32 KB0.0090
Formic Acid 0.022J mg/l 0.10 1 2/25/2017 09:32 KB B0.0050
Butyric Acid 0.0073J mg/l 0.10 1 2/25/2017 09:32 KB0.0070
Pyruvic Acid 0.0070U mg/l 0.10 1 2/25/2017 09:32 KB0.0070
i-Pentanoic Acid 0.0070U mg/l 0.10 1 2/25/2017 09:32 KB0.0070
Pentanoic Acid 0.0060U mg/l 0.10 1 2/25/2017 09:32 KB0.0060
i-Hexanoic Acid 0.0040U mg/l 0.20 1 2/25/2017 09:32 KB0.0040
Hexanoic Acid 0.0070U mg/l 0.20 1 2/25/2017 09:32 KB0.0070
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Methane 2.5 ug/l 0.50 1 2/23/2017 13:16 BW n0.027
Ethane 0.0071J ug/l 0.10 1 2/23/2017 13:16 BW n0.0030
Ethene 0.0068J ug/l 0.10 1 2/23/2017 13:16 BW n0.0010
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ANALYTICAL RESULTS
Workorder: 21785 Wayne Closed LF / 92330523
2/22/2017 11:52
MW-8
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217850006
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/16/2017 16:00
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 1.6 nM 0.60 1 2/27/2017 13:27 MM n0.075
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ANALYTICAL RESULTS QUALIFIERS
Workorder: 21785 Wayne Closed LF / 92330523
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
The analyte was detected in the associated blank.B
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QUALITY CONTROL DATA
Workorder: 21785 Wayne Closed LF / 92330523
QC Batch:
QC Batch Method:
DISG/5929
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:217850001, 217850003, 217850005
METHOD BLANK: 47150
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Methane 0.027Uug/l 0.027 n
Ethane 0.0030Uug/l 0.0030 n
Ethene 0.0010Uug/l 0.0010 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
47152 47154
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Methane ug/l 750 750 100 80-120 n7501000 20
Ethane ug/l 38 38 102 80-120 n391030.98 20
Ethene ug/l 35 36 102 80-120 n361030.98 20
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QUALITY CONTROL DATA
Workorder: 21785 Wayne Closed LF / 92330523
QC Batch:
QC Batch Method:
EDON/3257
AM23G
Analysis Method: AM23G
Associated Lab Samples:217850001, 217850003, 217850005
METHOD BLANK: 47189
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
EDonors
Lactic Acid 0.0060Umg/l 0.0060
Acetic Acid 0.024Jmg/l 0.0070 B
Propionic Acid 0.0090Umg/l 0.0090
Formic Acid 0.022Jmg/l 0.0050 B
Butyric Acid 0.0070Umg/l 0.0070
Pyruvic Acid 0.0070Umg/l 0.0070
i-Pentanoic Acid 0.0070Umg/l 0.0070
Pentanoic Acid 0.0060Umg/l 0.0060
i-Hexanoic Acid 0.0040Umg/l 0.0040
Hexanoic Acid 0.0070Umg/l 0.0070
LABORATORY CONTROL SAMPLE:
Parameter Units Conc.
Spike
Result
LCS
Qualifiers
LCS
% Rec
% Rec
Limits
47190
EDonors
Lactic Acid 2mg/l 2.0 99 70-130
Acetic Acid 2mg/l 2.0 B99 70-130
Propionic Acid 2mg/l 2.0 101 70-130
Formic Acid 2mg/l 1.8 B89 70-130
Butyric Acid 2mg/l 2.0 100 70-130
Pyruvic Acid 2mg/l 2.2 110 70-130
i-Pentanoic Acid 2mg/l 2.0 102 70-130
Pentanoic Acid 2mg/l 2.0 101 70-130
i-Hexanoic Acid 2mg/l 2.1 107 70-130
Hexanoic Acid 2mg/l 2.0 102 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units Conc.
Spike
Result
MS
47191 47192
MSD
Result % Rec
MS MSD
% Rec
% Rec
Limit RPD RPD
Max
QualifiersResult
Original
218110001Original:
EDonors
Lactic Acid mg/l 20 19 95 70-130 d19941.1 300.079
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QUALITY CONTROL DATA
Workorder: 21785 Wayne Closed LF / 92330523
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units Conc.
Spike
Result
MS
47191 47192
MSD
Result % Rec
MS MSD
% Rec
% Rec
Limit RPD RPD
Max
QualifiersResult
Original
218110001Original:
Acetic Acid mg/l 20 21 102 70-130 d,B211030.98 300.34
Propionic Acid mg/l 20 21 107 70-130 d211070 300.013
Formic Acid mg/l 20 18 85 70-130 d,B18861.2 300.78
Butyric Acid mg/l 20 21 107 70-130 d211070 300
Pyruvic Acid mg/l 20 22 110 70-130 d221100 300
i-Pentanoic Acid mg/l 20 22 109 70-130 d221090 300
Pentanoic Acid mg/l 20 22 110 70-130 d221100 300.11
i-Hexanoic Acid mg/l 20 26 128 70-130 d241215.6 300
Hexanoic Acid mg/l 20 23 114 70-130 d231140 300
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QUALITY CONTROL DATA
Workorder: 21785 Wayne Closed LF / 92330523
QC Batch:
QC Batch Method:
DISG/5936
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:217850002, 217850004, 217850006
METHOD BLANK: 47249
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Hydrogen 0.075UnM 0.075 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
47250 47251
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Hydrogen nM 24 27 110 80-120 n271110.9 20
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QUALITY CONTROL DATA QUALIFIERS
Workorder: 21785 Wayne Closed LF / 92330523
QUALITY CONTROL PARAMETER QUALIFIERS
The analyte was detected in the associated blank.B
The analyte concentration was determined from a dilution.d
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
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Report ID: 21785 - 909872 Page 17 of 17
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 21785 Wayne Closed LF / 92330523
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
217850001 MW-1R DISG/5929AM20GAX
217850003 MW-2 DISG/5929AM20GAX
217850005 MW-8 DISG/5929AM20GAX
217850001 MW-1R EDON/3257AM23G
217850003 MW-2 EDON/3257AM23G
217850005 MW-8 EDON/3257AM23G
217850002 MW-1R DISG/5936AM20GAX
217850004 MW-2 DISG/5936AM20GAX
217850006 MW-8 DISG/5936AM20GAX
220 William Pitt Way
Pittsburgh, PA 15238
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Page 80 of 83
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Page 83 of 83
#=CL#
March 01, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92330534
92330534
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne Closed MSWLF SW-ByMW-2`
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on February 17, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 16
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Page 2 of 16
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Lab ID Sample ID Matrix Date Collected Date Received
92330534001 SW-ByMW-2 Water 02/16/17 03:10 02/17/17 08:52
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 3 of 16
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330534001 SW-ByMW-2 EPA 8260 50 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 4 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Sample: SW-ByMW-2 Lab ID: 92330534001 Collected: 02/16/17 03:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 22:16 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 22:16 107-13-1200 1.9 1
Benzene ND ug/L 02/28/17 22:16 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 22:16 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 22:16 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 22:16 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 22:16 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 22:16 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 22:16 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 22:16 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/28/17 22:16 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 22:16 75-00-310.0 0.54 1
Chloroform ND ug/L 02/28/17 22:16 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 22:16 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 22:16 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 22:16 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 22:16 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 22:16 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/28/17 22:16 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/28/17 22:16 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 22:16 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 22:16 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 22:16 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 22:16 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/28/17 22:16 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 22:16 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 22:16 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/28/17 22:16 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 22:16 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 22:16 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 22:16 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 22:16 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 22:16 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 22:16 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 22:16 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 22:16 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 22:16 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 22:16 127-18-41.0 0.46 1
Toluene ND ug/L 02/28/17 22:16 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 22:16 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 22:16 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 22:16 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 22:16 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 22:16 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 22:16 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 22:16 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 5 of 16
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Sample: SW-ByMW-2 Lab ID: 92330534001 Collected: 02/16/17 03:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 02/28/17 22:16 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)91 %02/28/17 22:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %02/28/17 22:16 17060-07-070-130 1
Toluene-d8 (S)101 %02/28/17 22:16 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349990
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330534001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941517
Associated Lab Samples:92330534001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/28/17 19:280.33
1,1,1-Trichloroethane ug/L ND 1.0 02/28/17 19:280.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/28/17 19:280.40
1,1,2-Trichloroethane ug/L ND 1.0 02/28/17 19:280.29
1,1-Dichloroethane ug/L ND 5.0 02/28/17 19:280.32
1,1-Dichloroethene ug/L ND 5.0 02/28/17 19:280.56
1,2,3-Trichloropropane ug/L ND 1.0 02/28/17 19:280.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/28/17 19:282.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/28/17 19:280.27
1,2-Dichlorobenzene ug/L ND 5.0 02/28/17 19:280.30
1,2-Dichloroethane ug/L ND 1.0 02/28/17 19:280.24
1,2-Dichloropropane ug/L ND 1.0 02/28/17 19:280.27
1,4-Dichlorobenzene ug/L ND 1.0 02/28/17 19:280.33
2-Butanone (MEK)ug/L ND 100 02/28/17 19:280.96
2-Hexanone ug/L ND 50.0 02/28/17 19:280.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/28/17 19:280.33
Acetone ug/L ND 100 02/28/17 19:2810.0
Acrylonitrile ug/L ND 200 02/28/17 19:281.9
Benzene ug/L ND 1.0 02/28/17 19:280.25
Bromochloromethane ug/L ND 3.0 02/28/17 19:280.17
Bromodichloromethane ug/L ND 1.0 02/28/17 19:280.18
Bromoform ug/L ND 3.0 02/28/17 19:280.26
Bromomethane ug/L ND 10.0 02/28/17 19:280.29
Carbon disulfide ug/L ND 100 02/28/17 19:281.2
Carbon tetrachloride ug/L ND 1.0 02/28/17 19:280.25
Chlorobenzene ug/L ND 3.0 02/28/17 19:280.23
Chloroethane ug/L ND 10.0 02/28/17 19:280.54
Chloroform ug/L ND 5.0 02/28/17 19:280.14
Chloromethane ug/L ND 1.0 02/28/17 19:280.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/28/17 19:280.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/28/17 19:280.13
Dibromochloromethane ug/L ND 3.0 02/28/17 19:280.21
Dibromomethane ug/L ND 10.0 02/28/17 19:280.21
Ethylbenzene ug/L ND 1.0 02/28/17 19:280.30
Iodomethane ug/L ND 10.0 02/28/17 19:280.32
Methylene Chloride ug/L ND 1.0 02/28/17 19:280.97
Styrene ug/L ND 1.0 02/28/17 19:280.26
Tetrachloroethene ug/L ND 1.0 02/28/17 19:280.46
Toluene ug/L ND 1.0 02/28/17 19:280.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/28/17 19:280.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/28/17 19:280.26
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941517
Associated Lab Samples:92330534001
Matrix: Water
AnalyzedMDL
trans-1,4-Dichloro-2-butene ug/L ND 100 02/28/17 19:281.0
Trichloroethene ug/L ND 1.0 02/28/17 19:280.47
Trichlorofluoromethane ug/L ND 1.0 02/28/17 19:280.20
Vinyl acetate ug/L ND 50.0 02/28/17 19:280.35
Vinyl chloride ug/L ND 1.0 02/28/17 19:280.62
Xylene (Total)ug/L ND 5.0 02/28/17 19:280.66
1,2-Dichloroethane-d4 (S)%96 70-130 02/28/17 19:28
4-Bromofluorobenzene (S)%92 70-130 02/28/17 19:28
Toluene-d8 (S)%97 70-130 02/28/17 19:28
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941518LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 50.450 101 80-125
1,1,1-Trichloroethane ug/L 49.950 100 71-129
1,1,2,2-Tetrachloroethane ug/L 48.750 97 79-124
1,1,2-Trichloroethane ug/L 52.750 105 85-125
1,1-Dichloroethane ug/L 48.750 97 73-126
1,1-Dichloroethene ug/L 52.350 105 66-135
1,2,3-Trichloropropane ug/L 48.250 96 75-130
1,2-Dibromo-3-chloropropane ug/L 48.450 97 71-133
1,2-Dibromoethane (EDB)ug/L 49.150 98 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 49.550 99 67-128
1,2-Dichloropropane ug/L 51.750 103 75-132
1,4-Dichlorobenzene ug/L 49.350 99 78-130
2-Butanone (MEK)ug/L 105100 105 61-144
2-Hexanone ug/L 103100 103 68-143
4-Methyl-2-pentanone (MIBK)ug/L 105100 105 72-135
Acetone ug/L 110100 110 48-146
Acrylonitrile ug/L 265250 106 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 50.850 102 71-125
Bromodichloromethane ug/L 54.050 108 78-124
Bromoform ug/L 48.550 97 71-128
Bromomethane ug/L 50.150 100 40-160
Carbon disulfide ug/L 47.6J50 95 50-160
Carbon tetrachloride ug/L 50.850 102 69-131
Chlorobenzene ug/L 51.450 103 81-122
Chloroethane ug/L 52.150 104 39-148
Chloroform ug/L 49.650 99 73-127
Chloromethane ug/L 48.350 97 44-146
cis-1,2-Dichloroethene ug/L 50.050 100 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 8 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941518LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 52.050 104 78-125
Dibromomethane ug/L 53.150 106 82-120
Ethylbenzene ug/L 49.650 99 79-121
Iodomethane ug/L 111100 111 39-154
Methylene Chloride ug/L 52.350 105 64-133
Styrene ug/L 50.550 101 84-126
Tetrachloroethene ug/L 48.550 97 78-122
Toluene ug/L 52.250 104 80-121
trans-1,2-Dichloroethene ug/L 50.850 102 71-127
trans-1,3-Dichloropropene ug/L 53.750 107 69-141
trans-1,4-Dichloro-2-butene ug/L 47.6J50 95 40-160
Trichloroethene ug/L 50.350 101 78-122
Trichlorofluoromethane ug/L 53.950 108 53-137
Vinyl acetate ug/L 109100 109 40-160
Vinyl chloride ug/L 43.050 86 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%103 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1942951MATRIX SPIKE SAMPLE:
MSSpike
Result
92330523002
1,1,1,2-Tetrachloroethane ug/L 20.120 100 70-130ND
1,1,1-Trichloroethane ug/L 21.620 108 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.220 101 70-130ND
1,1,2-Trichloroethane ug/L 19.920 99 70-130ND
1,1-Dichloroethane ug/L 20.020 100 70-130ND
1,1-Dichloroethene ug/L 21.920 110 70-166ND
1,2,3-Trichloropropane ug/L 20.420 102 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.420 97 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.720 103 70-130ND
1,2-Dichlorobenzene ug/L 20.720 102 70-1300.38J
1,2-Dichloroethane ug/L 18.720 93 70-130ND
1,2-Dichloropropane ug/L 20.420 102 70-130ND
1,4-Dichlorobenzene ug/L 23.620 101 70-1303.5
2-Butanone (MEK)ug/L 37.7J40 94 70-130ND
2-Hexanone ug/L 38.9J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 40.6J40 102 70-130ND
Acetone ug/L 39.3J40 82 70-130ND
Acrylonitrile ug/L 101J100 101 70-130ND
Benzene ug/L 21.920 105 70-1480.90J
Bromochloromethane ug/L 19.820 99 70-130ND
Bromodichloromethane ug/L 20.920 105 70-130ND
Bromoform ug/L 18.820 94 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
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[phone]
Page 9 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1942951MATRIX SPIKE SAMPLE:
MSSpike
Result
92330523002
Bromomethane ug/L 15.820 79 70-130ND
Carbon disulfide ug/L 18.6J20 93 70-130ND
Carbon tetrachloride ug/L 21.720 109 70-130ND
Chlorobenzene ug/L 34.920 122 70-14610.5
Chloroethane ug/L 20.020 100 70-130ND
Chloroform ug/L 19.920 99 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
cis-1,2-Dichloroethene ug/L 19.820 99 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 102 70-130ND
Dibromochloromethane ug/L 20.220 101 70-130ND
Dibromomethane ug/L 18.620 93 70-130ND
Ethylbenzene ug/L 20.820 104 70-130ND
Iodomethane ug/L 29.640 74 70-130ND
Methylene Chloride ug/L 18.520 92 70-130ND
Styrene ug/L 20.420 102 70-130ND
Tetrachloroethene ug/L 21.620 108 70-130ND
Toluene ug/L 20.120 100 70-155ND
trans-1,2-Dichloroethene ug/L 21.220 106 70-130ND
trans-1,3-Dichloropropene ug/L 19.120 96 70-130ND
trans-1,4-Dichloro-2-butene ug/L 17.7J20 88 70-130ND
Trichloroethene ug/L 20.620 103 69-151ND
Trichlorofluoromethane ug/L 22.320 112 70-130ND
Vinyl acetate ug/L 37.0J40 92 70-130ND
Vinyl chloride ug/L 16.420 82 70-130ND
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1942950SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 16
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330523001
1942950SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L 0.33J 300.42J
Chloromethane ug/L 0.21J 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%89 22111
4-Bromofluorobenzene (S)%97 196
Toluene-d8 (S)%105 699
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
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Page 11 of 16
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
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[phone]
Page 12 of 16
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330534
Wayne Closed MSWLF SW-ByMW-2`
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330534001 349990SW-ByMW-2 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:10 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 16
Page 14 of 16
Page 15 of 16
Page 16 of 16
#=CL#
March 03, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92330518
92330518
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne MSWLF-SWs
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory between February 17,
2017 and February 22, 2017. The results relate only to the samples included in this report. Results
reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's
Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID Matrix Date Collected Date Received
92330518001 SW-1 Water 02/16/17 13:10 02/17/17 08:52
92330518002 SW-6 Water 02/17/17 13:35 02/22/17 08:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330518001 SW-1 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
92330518002 SW-6 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 4 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-1 Lab ID: 92330518001 Collected: 02/16/17 13:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:28 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:28 7440-38-202/20/17 19:5510.0 5.0 1
Barium 43.5J ug/L 02/24/17 06:28 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:28 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:28 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:28 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:28 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:28 7440-50-802/20/17 19:5510.0 2.5 1
Lead 2.9J ug/L 02/24/17 06:28 7439-92-102/20/17 19:5510.0 2.5 1
Nickel ND ug/L 02/24/17 06:28 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:28 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:28 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 2.5J ug/L 02/24/17 06:28 7440-62-202/20/17 19:5525.0 2.5 1
Zinc 12.8 ug/L 02/24/17 06:28 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 18:27 7440-28-002/23/17 02:205.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 19:21 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 19:21 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 19:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 19:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 19:21 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 19:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 19:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 19:21 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 19:21 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 19:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 19:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 19:21 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 19:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 19:21 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 19:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 19:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 19:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 19:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 19:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 19:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 19:21 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 19:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 19:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 19:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 19:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 19:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 19:21 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 5 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-1 Lab ID: 92330518001 Collected: 02/16/17 13:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/21/17 19:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 19:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 19:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 19:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 19:21 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 19:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 19:21 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 19:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 19:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 19:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 19:21 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 19:21 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 19:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 19:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 19:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 19:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 19:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 19:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 19:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 19:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 19:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/21/17 19:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/21/17 19:21 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 19:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-6 Lab ID: 92330518002 Collected: 02/17/17 13:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/03/17 07:16 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/03/17 07:16 7440-38-202/23/17 19:3510.0 5.0 1
Barium 43.8J ug/L 03/03/17 07:16 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/03/17 07:16 7440-41-702/23/17 19:351.0 0.50 1
Cadmium ND ug/L 03/03/17 07:16 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/03/17 07:16 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/03/17 07:16 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/03/17 07:16 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/03/17 07:16 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/03/17 07:16 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/03/17 07:16 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/03/17 07:16 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/03/17 07:16 7440-62-202/23/17 19:3525.0 2.5 1
Zinc 6.0J ug/L 03/03/17 07:16 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 20:47 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 02:53 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 02:53 107-13-1200 1.9 1
Benzene ND ug/L 02/28/17 02:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 02:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 02:53 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 02:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 02:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 02:53 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 02:53 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 02:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/28/17 02:53 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 02:53 75-00-310.0 0.54 1
Chloroform ND ug/L 02/28/17 02:53 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 02:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 02:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 02:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 02:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 02:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/28/17 02:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/28/17 02:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 02:53 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 02:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 02:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 02:53 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/28/17 02:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 02:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 02:53 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-6 Lab ID: 92330518002 Collected: 02/17/17 13:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/28/17 02:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 02:53 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 02:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 02:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 02:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 02:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 02:53 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 02:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 02:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 02:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 02:53 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/28/17 02:53 109-99-910.0 3.1 1
Toluene ND ug/L 02/28/17 02:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 02:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 02:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 02:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 02:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 02:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 02:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 02:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/28/17 02:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %02/28/17 02:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %02/28/17 02:53 17060-07-070-130 1
Toluene-d8 (S)101 %02/28/17 02:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
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Page 8 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348994
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936214
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 02/24/17 05:123.9
Arsenic ug/L ND 10.0 02/24/17 05:125.0
Barium ug/L ND 5.0 02/24/17 05:122.5
Beryllium ug/L ND 1.0 02/24/17 05:120.50
Cadmium ug/L ND 1.0 02/24/17 05:120.50
Chromium ug/L ND 5.0 02/24/17 05:122.5
Cobalt ug/L ND 5.0 02/24/17 05:122.5
Copper ug/L ND 5.0 02/24/17 05:122.5
Lead ug/L ND 5.0 02/24/17 05:122.5
Nickel ug/L ND 5.0 02/24/17 05:122.5
Selenium ug/L ND 10.0 02/24/17 05:125.0
Silver ug/L ND 5.0 02/24/17 05:122.5
Vanadium ug/L ND 5.0 02/24/17 05:122.5
Zinc ug/L ND 10.0 02/24/17 05:155.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936215LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 479500 96 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 493500 99 80-120
Beryllium ug/L 491500 98 80-120
Cadmium ug/L 479500 96 80-120
Chromium ug/L 496500 99 80-120
Cobalt ug/L 478500 96 80-120
Copper ug/L 487500 97 80-120
Lead ug/L 470500 94 80-120
Nickel ug/L 481500 96 80-120
Selenium ug/L 467500 93 80-120
Silver ug/L 239250 96 80-120
Vanadium ug/L 482500 96 80-120
Zinc ug/L 472500 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-12596 2 20500ND489 478
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 97 75-12595 2 20500ND483 473
Barium ug/L 500 96 75-12595 1 205007.2 488 481
Beryllium ug/L 500 97 75-12595 1 20500ND483 477
Cadmium ug/L 500 96 75-12594 3 20500ND482 470
Chromium ug/L 500 98 75-12595 3 20500ND488 476
Cobalt ug/L 500 96 75-12593 2 20500ND478 466
Copper ug/L 500 98 75-12595 2 20500ND488 477
Lead ug/L 500 93 75-12591 2 20500ND467 457
Nickel ug/L 500 96 75-12593 3 20500ND478 466
Selenium ug/L 500 94 75-12592 2 20500ND471 462
Silver ug/L 250 96 75-12593 3 20250ND240 234
Vanadium ug/L 500 99 75-12595 3 20500ND493 476
Zinc ug/L 500 96 75-12594 3 20500ND482 470
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349553
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939173
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 03/03/17 06:243.9
Arsenic ug/L ND 10.0 03/03/17 06:245.0
Barium ug/L ND 5.0 03/03/17 06:242.5
Beryllium ug/L ND 1.0 03/03/17 06:240.50
Cadmium ug/L ND 1.0 03/03/17 06:240.50
Chromium ug/L ND 5.0 03/03/17 06:242.5
Cobalt ug/L ND 5.0 03/03/17 06:242.5
Copper ug/L ND 5.0 03/03/17 06:242.5
Lead ug/L ND 5.0 03/03/17 06:242.5
Nickel ug/L ND 5.0 03/03/17 06:242.5
Selenium ug/L ND 10.0 03/03/17 06:245.0
Silver ug/L ND 5.0 03/03/17 06:242.5
Vanadium ug/L ND 5.0 03/03/17 06:242.5
Zinc ug/L ND 10.0 03/03/17 06:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939174LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 482500 96 80-120
Arsenic ug/L 461500 92 80-120
Barium ug/L 461500 92 80-120
Beryllium ug/L 475500 95 80-120
Cadmium ug/L 464500 93 80-120
Chromium ug/L 466500 93 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 460500 92 80-120
Nickel ug/L 460500 92 80-120
Selenium ug/L 463500 93 80-120
Silver ug/L 244250 97 80-120
Vanadium ug/L 472500 94 80-120
Zinc ug/L 460500 92 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12598 3 20500ND480 492
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 92 75-12594 2 20500ND459 469
Barium ug/L 500 91 75-12593 2 20500ND456 465
Beryllium ug/L 500 94 75-12596 2 20500ND469 480
Cadmium ug/L 500 92 75-12594 2 20500ND462 469
Chromium ug/L 500 93 75-12595 2 20500ND466 474
Cobalt ug/L 500 93 75-12595 2 20500ND466 475
Copper ug/L 500 97 75-12598 1 20500ND487 491
Lead ug/L 500 91 75-12594 2 20500ND457 468
Nickel ug/L 500 92 75-12593 2 20500ND458 467
Selenium ug/L 500 92 75-12594 2 20500ND462 471
Silver ug/L 250 97 75-12598 2 20250ND242 246
Vanadium ug/L 500 95 75-12596 1 20500ND475 482
Zinc ug/L 500 91 75-12593 2 20500ND456 465
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349257
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937708
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 18:000.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937709LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.7100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937710MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330674021
1937711
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 97 75-12595 2 20100ND97.5 95.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349668
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939942
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 20:120.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939943LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330519013
1939981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 90 75-12595 6 201000.034J 90.2 95.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349193
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/21/17 11:120.33
1,1,1-Trichloroethane ug/L ND 1.0 02/21/17 11:120.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/21/17 11:120.40
1,1,2-Trichloroethane ug/L ND 1.0 02/21/17 11:120.29
1,1-Dichloroethane ug/L ND 5.0 02/21/17 11:120.32
1,1-Dichloroethene ug/L ND 5.0 02/21/17 11:120.56
1,2,3-Trichloropropane ug/L ND 1.0 02/21/17 11:120.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/21/17 11:122.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/21/17 11:120.27
1,2-Dichlorobenzene ug/L ND 5.0 02/21/17 11:120.30
1,2-Dichloroethane ug/L ND 1.0 02/21/17 11:120.24
1,2-Dichloropropane ug/L ND 1.0 02/21/17 11:120.27
1,4-Dichlorobenzene ug/L ND 1.0 02/21/17 11:120.33
2-Butanone (MEK)ug/L ND 100 02/21/17 11:120.96
2-Hexanone ug/L ND 50.0 02/21/17 11:120.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/21/17 11:120.33
Acetone ug/L ND 100 02/21/17 11:1210.0
Acrylonitrile ug/L ND 200 02/21/17 11:121.9
Benzene ug/L ND 1.0 02/21/17 11:120.25
Bromochloromethane ug/L ND 3.0 02/21/17 11:120.17
Bromodichloromethane ug/L ND 1.0 02/21/17 11:120.18
Bromoform ug/L ND 3.0 02/21/17 11:120.26
Bromomethane ug/L ND 10.0 02/21/17 11:120.29
Carbon disulfide ug/L ND 100 02/21/17 11:121.2
Carbon tetrachloride ug/L ND 1.0 02/21/17 11:120.25
Chlorobenzene ug/L ND 3.0 02/21/17 11:120.23
Chloroethane ug/L ND 10.0 02/21/17 11:120.54
Chloroform ug/L ND 5.0 02/21/17 11:120.14
Chloromethane ug/L ND 1.0 02/21/17 11:120.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.13
Dibromochloromethane ug/L ND 3.0 02/21/17 11:120.21
Dibromomethane ug/L ND 10.0 02/21/17 11:120.21
Ethylbenzene ug/L ND 1.0 02/21/17 11:120.30
Iodomethane ug/L ND 10.0 02/21/17 11:120.32
Methylene Chloride ug/L ND 1.0 02/21/17 11:120.97
Styrene ug/L ND 1.0 02/21/17 11:120.26
Tetrachloroethene ug/L ND 1.0 02/21/17 11:120.46
Tetrahydrofuran ug/L ND 10.0 02/21/17 11:123.1
Toluene ug/L ND 1.0 02/21/17 11:120.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/21/17 11:121.0
Trichloroethene ug/L ND 1.0 02/21/17 11:120.47
Trichlorofluoromethane ug/L ND 1.0 02/21/17 11:120.20
Vinyl acetate ug/L ND 50.0 02/21/17 11:120.35
Vinyl chloride ug/L ND 1.0 02/21/17 11:120.62
Xylene (Total)ug/L ND 5.0 02/21/17 11:120.66
1,2-Dichloroethane-d4 (S)%108 70-130 02/21/17 11:12
4-Bromofluorobenzene (S)%99 70-130 02/21/17 11:12
Toluene-d8 (S)%113 70-130 02/21/17 11:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.250 98 80-125
1,1,1-Trichloroethane ug/L 46.050 92 71-129
1,1,2,2-Tetrachloroethane ug/L 50.250 100 79-124
1,1,2-Trichloroethane ug/L 54.150 108 85-125
1,1-Dichloroethane ug/L 48.650 97 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,2,3-Trichloropropane ug/L 53.850 108 75-130
1,2-Dibromo-3-chloropropane ug/L 49.450 99 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 51.950 104 80-133
1,2-Dichloroethane ug/L 43.650 87 67-128
1,2-Dichloropropane ug/L 51.950 104 75-132
1,4-Dichlorobenzene ug/L 48.950 98 78-130
2-Butanone (MEK)ug/L 90.1J100 90 61-144
2-Hexanone ug/L 89.6100 90 68-143
4-Methyl-2-pentanone (MIBK)ug/L 87.7J100 88 72-135
Acetone ug/L 86.3J100 86 48-146
Acrylonitrile ug/L 219250 88 40-160
Benzene ug/L 52.050 104 80-125
Bromochloromethane ug/L 51.250 102 71-125
Bromodichloromethane ug/L 49.750 99 78-124
Bromoform ug/L 45.050 90 71-128
Bromomethane ug/L 52.150 104 40-160
Carbon disulfide ug/L 49.7J50 99 50-160
Carbon tetrachloride ug/L 49.350 99 69-131
Chlorobenzene ug/L 51.850 104 81-122
Chloroethane ug/L 57.950 116 39-148
Chloroform ug/L 49.650 99 73-127
Chloromethane ug/L 62.650 125 44-146
cis-1,2-Dichloroethene ug/L 50.750 101 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 54.750 109 72-132
Dibromochloromethane ug/L 49.050 98 78-125
Dibromomethane ug/L 47.950 96 82-120
Ethylbenzene ug/L 50.750 101 79-121
Iodomethane ug/L 113100 113 39-154
Methylene Chloride ug/L 47.050 94 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.250 102 78-122
Tetrahydrofuran ug/L 465500 93 69-148
Toluene ug/L 53.050 106 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 54.150 108 69-141
trans-1,4-Dichloro-2-butene ug/L 51.9J50 104 40-160
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 55.850 112 53-137
Vinyl acetate ug/L 97.8100 98 40-160
Vinyl chloride ug/L 43.750 87 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 87 70-13093 7 3020ND17.4 18.6
1,1,1-Trichloroethane ug/L 20 124 70-130122 1 3020ND24.7 24.5
1,1,2,2-Tetrachloroethane ug/L 20 100 70-130103 3 3020ND20.0 20.6
1,1,2-Trichloroethane ug/L 20 105 70-130111 6 3020ND21.0 22.3
1,1-Dichloroethane ug/L M12016770-130157 6 3020ND33.6 31.8
1,1-Dichloroethene ug/L M12016870-166154 9 3020ND33.7 30.8
1,2,3-Trichloropropane ug/L 20 96 70-130104 9 3020ND19.2 20.9
1,2-Dibromo-3-
chloropropane ug/L 20 86 70-13096 11 3020ND17.1 19.2
1,2-Dibromoethane (EDB) ug/L 20 90 70-13099 10 3020ND17.9 19.8
1,2-Dichlorobenzene ug/L 20 105 70-130105 1 3020ND21.1 21.0
1,2-Dichloroethane ug/L 20 122 70-130123 1 3020ND24.4 24.7
1,2-Dichloropropane ug/L 20 113 70-130117 3 3020ND22.6 23.3
1,4-Dichlorobenzene ug/L 20 109 70-130104 5 3020ND22.2 21.1
2-Butanone (MEK)ug/L 40 85 70-13097 13 3040ND34.2J 38.9J
2-Hexanone ug/L 40 91 70-130106 15 3040ND36.2J 42.2J
4-Methyl-2-pentanone
(MIBK)ug/L 40 95 70-130112 16 3040ND38.1J 44.7J
Acetone ug/L 40 82 70-13095 15 3040ND32.9J 38.2J
Acrylonitrile ug/L 100 101 70-130118 15 30100ND101J 118J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 120 70-148121 1 30200.44J 24.4 24.6
Bromochloromethane ug/L M12013670-130132 4 3020ND27.3 26.3
Bromodichloromethane ug/L 20 116 70-130115 1 3020ND23.1 23.0
Bromoform ug/L 20 78 70-13087 11 3020ND15.5 17.4
Bromomethane ug/L M12014070-130134 4 3020ND27.9 26.8
Carbon disulfide ug/L M12016070-130157 1 3020ND31.9J 31.5J
Carbon tetrachloride ug/L 20 113 70-130111 2 3020ND22.7 22.2
Chlorobenzene ug/L 20 113 70-146115 2 3020ND22.6 23.0
Chloroethane ug/L M12020570-130202 1 30200.69J 41.6 41.1
Chloroform ug/L M12013970-130132 5 3020ND27.8 26.4
Chloromethane ug/L M12015870-130149 6 3020ND31.6 29.7
cis-1,2-Dichloroethene ug/L M12016070-130160 0 3020ND32.0 32.0
cis-1,3-Dichloropropene ug/L 20 105 70-130109 3 3020ND21.1 21.7
Dibromochloromethane ug/L 20 81 70-13089 9 3020ND16.2 17.7
Dibromomethane ug/L 20 110 70-130113 3 3020ND21.9 22.6
Ethylbenzene ug/L 20 117 70-130118 0 3020ND23.4 23.5
Iodomethane ug/L M14016170-130180 11 3040ND64.2 72.0
Methylene Chloride ug/L M12015770-130150 5 3020ND31.3 29.9
Styrene ug/L 20 116 70-130118 2 3020ND23.1 23.7
Tetrachloroethene ug/L 20 97 70-130106 9 3020ND19.4 21.3
Tetrahydrofuran ug/L 200 94 70-130115 20 30200ND188 231
Toluene ug/L 20 133 70-155131 1 3020ND26.6 26.2
trans-1,2-Dichloroethene ug/L M12014370-130140 2 3020ND28.6 27.9
trans-1,3-Dichloropropene ug/L 20 102 70-130108 6 3020ND20.4 21.7
trans-1,4-Dichloro-2-butene ug/L M1206770-13087 26 3020ND13.3J 17.4J
Trichloroethene ug/L 20 105 69-151107 2 3020ND21.0 21.5
Trichlorofluoromethane ug/L M12020070-130189 5 3020ND39.9 37.8
Vinyl acetate ug/L 40 83 70-13090 8 3040ND33.2J 36.0J
Vinyl chloride ug/L M12015870-130141 11 3020ND31.5 28.3
1,2-Dichloroethane-d4 (S)%115 70-130117
4-Bromofluorobenzene (S) %99 70-130103
Toluene-d8 (S)%107 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350035
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941762
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/28/17 02:020.33
1,1,1-Trichloroethane ug/L ND 1.0 02/28/17 02:020.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/28/17 02:020.40
1,1,2-Trichloroethane ug/L ND 1.0 02/28/17 02:020.29
1,1-Dichloroethane ug/L ND 5.0 02/28/17 02:020.32
1,1-Dichloroethene ug/L ND 5.0 02/28/17 02:020.56
1,2,3-Trichloropropane ug/L ND 1.0 02/28/17 02:020.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/28/17 02:022.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/28/17 02:020.27
1,2-Dichlorobenzene ug/L ND 5.0 02/28/17 02:020.30
1,2-Dichloroethane ug/L ND 1.0 02/28/17 02:020.24
1,2-Dichloropropane ug/L ND 1.0 02/28/17 02:020.27
1,4-Dichlorobenzene ug/L ND 1.0 02/28/17 02:020.33
2-Butanone (MEK)ug/L ND 100 02/28/17 02:020.96
2-Hexanone ug/L ND 50.0 02/28/17 02:020.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/28/17 02:020.33
Acetone ug/L ND 100 02/28/17 02:0210.0
Acrylonitrile ug/L ND 200 02/28/17 02:021.9
Benzene ug/L ND 1.0 02/28/17 02:020.25
Bromochloromethane ug/L ND 3.0 02/28/17 02:020.17
Bromodichloromethane ug/L ND 1.0 02/28/17 02:020.18
Bromoform ug/L ND 3.0 02/28/17 02:020.26
Bromomethane ug/L ND 10.0 02/28/17 02:020.29
Carbon disulfide ug/L ND 100 02/28/17 02:021.2
Carbon tetrachloride ug/L ND 1.0 02/28/17 02:020.25
Chlorobenzene ug/L ND 3.0 02/28/17 02:020.23
Chloroethane ug/L ND 10.0 02/28/17 02:020.54
Chloroform ug/L ND 5.0 02/28/17 02:020.14
Chloromethane ug/L ND 1.0 02/28/17 02:020.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/28/17 02:020.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/28/17 02:020.13
Dibromochloromethane ug/L ND 3.0 02/28/17 02:020.21
Dibromomethane ug/L ND 10.0 02/28/17 02:020.21
Ethylbenzene ug/L ND 1.0 02/28/17 02:020.30
Iodomethane ug/L ND 10.0 02/28/17 02:020.32
Methylene Chloride ug/L ND 1.0 02/28/17 02:020.97
Styrene ug/L ND 1.0 02/28/17 02:020.26
Tetrachloroethene ug/L ND 1.0 02/28/17 02:020.46
Tetrahydrofuran ug/L ND 10.0 02/28/17 02:023.1
Toluene ug/L ND 1.0 02/28/17 02:020.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/28/17 02:020.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941762
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/28/17 02:020.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/28/17 02:021.0
Trichloroethene ug/L ND 1.0 02/28/17 02:020.47
Trichlorofluoromethane ug/L ND 1.0 02/28/17 02:020.20
Vinyl acetate ug/L ND 50.0 02/28/17 02:020.35
Vinyl chloride ug/L ND 1.0 02/28/17 02:020.62
Xylene (Total)ug/L ND 5.0 02/28/17 02:020.66
1,2-Dichloroethane-d4 (S)%96 70-130 02/28/17 02:02
4-Bromofluorobenzene (S)%94 70-130 02/28/17 02:02
Toluene-d8 (S)%92 70-130 02/28/17 02:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941763LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.550 97 80-125
1,1,1-Trichloroethane ug/L 46.150 92 71-129
1,1,2,2-Tetrachloroethane ug/L 47.550 95 79-124
1,1,2-Trichloroethane ug/L 48.450 97 85-125
1,1-Dichloroethane ug/L 45.350 91 73-126
1,1-Dichloroethene ug/L 47.550 95 66-135
1,2,3-Trichloropropane ug/L 44.950 90 75-130
1,2-Dibromo-3-chloropropane ug/L 46.550 93 71-133
1,2-Dibromoethane (EDB)ug/L 47.650 95 83-124
1,2-Dichlorobenzene ug/L 49.050 98 80-133
1,2-Dichloroethane ug/L 44.050 88 67-128
1,2-Dichloropropane ug/L 47.150 94 75-132
1,4-Dichlorobenzene ug/L 46.650 93 78-130
2-Butanone (MEK)ug/L 98.4J100 98 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.2J100 97 72-135
Acetone ug/L 101100 101 48-146
Acrylonitrile ug/L 247250 99 40-160
Benzene ug/L 49.250 98 80-125
Bromochloromethane ug/L 47.850 96 71-125
Bromodichloromethane ug/L 50.250 100 78-124
Bromoform ug/L 46.650 93 71-128
Bromomethane ug/L 47.350 95 40-160
Carbon disulfide ug/L 44.0J50 88 50-160
Carbon tetrachloride ug/L 47.350 95 69-131
Chlorobenzene ug/L 49.450 99 81-122
Chloroethane ug/L 50.550 101 39-148
Chloroform ug/L 45.250 90 73-127
Chloromethane ug/L 48.250 96 44-146
cis-1,2-Dichloroethene ug/L 45.950 92 74-124
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941763LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 47.150 94 72-132
Dibromochloromethane ug/L 50.150 100 78-125
Dibromomethane ug/L 47.950 96 82-120
Ethylbenzene ug/L 47.350 95 79-121
Iodomethane ug/L 99.6100 100 39-154
Methylene Chloride ug/L 47.850 96 64-133
Styrene ug/L 48.450 97 84-126
Tetrachloroethene ug/L 42.550 85 78-122
Tetrahydrofuran ug/L 489500 98 69-148
Toluene ug/L 46.350 93 80-121
trans-1,2-Dichloroethene ug/L 46.550 93 71-127
trans-1,3-Dichloropropene ug/L 48.250 96 69-141
trans-1,4-Dichloro-2-butene ug/L 40.6J50 81 40-160
Trichloroethene ug/L 48.650 97 78-122
Trichlorofluoromethane ug/L 49.850 100 53-137
Vinyl acetate ug/L 100100 100 40-160
Vinyl chloride ug/L 39.950 80 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1941764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330712012
1941765
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 103 70-130105 2 3020ND20.7 21.0
1,1,1-Trichloroethane ug/L 20 111 70-130113 1 3020ND22.6 22.9
1,1,2,2-Tetrachloroethane ug/L 20 103 70-130102 1 3020ND20.5 20.4
1,1,2-Trichloroethane ug/L 20 100 70-130107 7 3020ND20.0 21.4
1,1-Dichloroethane ug/L 20 102 70-130109 6 30200.62J 21.1 22.5
1,1-Dichloroethene ug/L 20 115 70-166115 0 30200.56J 23.6 23.5
1,2,3-Trichloropropane ug/L 20 99 70-13099 0 3020ND19.8 19.8
1,2-Dibromo-3-
chloropropane ug/L 20 100 70-13097 3 3020ND19.9 19.4
1,2-Dibromoethane (EDB) ug/L 20 101 70-130101 1 3020ND20.1 20.2
1,2-Dichlorobenzene ug/L 20 104 70-130107 3 3020ND20.7 21.3
1,2-Dichloroethane ug/L 20 98 70-130102 4 3020ND19.8 20.7
1,2-Dichloropropane ug/L 20 102 70-130107 5 3020ND20.4 21.4
1,4-Dichlorobenzene ug/L 20 101 70-130105 4 3020ND20.1 21.0
2-Butanone (MEK)ug/L 40 106 70-130106 1 30401.8J 44.3J 44.1J
2-Hexanone ug/L 40 108 70-130105 2 3040ND43.3J 42.4J
4-Methyl-2-pentanone
(MIBK)ug/L 40 105 70-130110 4 3040ND42.2J 43.8J
Acetone ug/L 40 106 70-130107 1 3040ND50.3J 50.6J
Acrylonitrile ug/L 100 111 70-130110 1 30100ND111J 110J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1941764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330712012
1941765
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 107 70-148114 6 3020ND21.4 22.8
Bromochloromethane ug/L 20 101 70-130105 4 3020ND20.2 21.1
Bromodichloromethane ug/L 20 104 70-130112 8 3020ND20.8 22.4
Bromoform ug/L 20 92 70-13095 3 3020ND18.4 19.0
Bromomethane ug/L 20 99 70-130106 6 3020ND19.8 21.1
Carbon disulfide ug/L 20 100 70-130105 5 3020ND20.0J 21.1J
Carbon tetrachloride ug/L 20 110 70-130111 1 3020ND21.9 22.2
Chlorobenzene ug/L 20 110 70-146111 1 3020ND21.9 22.2
Chloroethane ug/L 20 117 70-130120 3 3020ND23.5 24.1
Chloroform ug/L 20 104 70-130107 3 3020ND20.7 21.3
Chloromethane ug/L 20 116 70-130114 1 30200.26J 23.4 23.1
cis-1,2-Dichloroethene ug/L 20 90 70-130109 6 302040.7 58.6 62.5
cis-1,3-Dichloropropene ug/L 20 97 70-130105 8 3020ND19.5 21.1
Dibromochloromethane ug/L 20 103 70-130103 1 3020ND20.6 20.7
Dibromomethane ug/L 20 103 70-130109 5 3020ND20.6 21.7
Ethylbenzene ug/L 20 109 70-130111 2 3020ND21.8 22.2
Iodomethane ug/L 40 104 70-130119 13 3040ND41.8 47.7
Methylene Chloride ug/L 20 104 70-130109 5 3020ND20.8 21.8
Styrene ug/L 20 104 70-130107 3 3020ND20.7 21.4
Tetrachloroethene ug/L 20 108 70-130102 6 3020ND21.8 20.6
Tetrahydrofuran ug/L 200 110 70-130108 1 30200ND219 217
Toluene ug/L 20 105 70-155106 1 3020ND21.0 21.3
trans-1,2-Dichloroethene ug/L 20 110 70-130112 3 3020ND22.1 22.7
trans-1,3-Dichloropropene ug/L 20 96 70-130101 5 3020ND19.1 20.2
trans-1,4-Dichloro-2-butene ug/L 20 83 70-13083 0 3020ND16.6J 16.7J
Trichloroethene ug/L 20 89 69-15199 3 302039.1 56.9 58.8
Trichlorofluoromethane ug/L M12013170-130121 8 3020ND26.2 24.3
Vinyl acetate ug/L 40 89 70-13095 7 3040ND35.7J 38.2J
Vinyl chloride ug/L 20 99 70-130100 1 3020ND19.8 20.0
1,2-Dichloroethane-d4 (S)%97 70-130101
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-13095
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 22 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 23 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330518001 348994 349091SW-1 EPA 3010A EPA 6010
92330518002 349553 349687SW-6 EPA 3010A EPA 6010
92330518001 349257 349497SW-1 EPA 3010A EPA 6020B
92330518002 349668 349712SW-6 EPA 3010A EPA 6020B
92330518001 349193SW-1 EPA 8260
92330518002 350035SW-6 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Huntersville, NC 28078
[phone]
Page 24 of 30
Page 25 of 30
Page 26 of 30
Page 27 of 30
Page 28 of 30
Page 29 of 30
Page 30 of 30
#=CL#
March 03, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92331034
92331034
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
WAYNE MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on February 22, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Huntersville, NC 28078
[phone]
Page 2 of 26
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92331034001 EB Water 02/17/17 17:30 02/22/17 08:00
92331034002 FB Water 02/17/17 17:35 02/22/17 08:00
92331034003 TB Water 02/17/17 00:00 02/22/17 08:00
REPORT OF LABORATORY ANALYSIS
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Page 3 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92331034001 EB EPA 6010 15 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 68 PASI-CCAH
SM 4500-CN-E 1 PASI-ADMN
92331034002 FB EPA 8260 68 PASI-CCAH
92331034003 TB EPA 8260 68 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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[phone]
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: EB Lab ID: 92331034001 Collected: 02/17/17 17:30 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/03/17 06:33 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/03/17 06:33 7440-38-202/23/17 19:3510.0 5.0 1
Barium ND ug/L 03/03/17 06:33 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/03/17 06:33 7440-41-702/23/17 19:351.0 0.50 1
Cadmium ND ug/L 03/03/17 06:33 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/03/17 06:33 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/03/17 06:33 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/03/17 06:33 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/03/17 06:33 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/03/17 06:33 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/03/17 06:33 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/03/17 06:33 7440-22-402/23/17 19:3510.0 2.5 1
Tin ND ug/L 03/03/17 06:33 7440-31-502/23/17 19:35100 2.5 1
Vanadium ND ug/L 03/03/17 06:33 7440-62-202/23/17 19:3525.0 2.5 1
Zinc ND ug/L 03/03/17 06:33 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 20:53 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:15 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:15 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:15 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:15 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:15 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:15 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:15 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:15 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:15 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:15 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:15 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:15 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:15 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:15 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:15 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:15 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:15 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:15 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:15 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:15 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:15 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:15 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:15 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:15 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:15 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:15 110-57-6100 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: EB Lab ID: 92331034001 Collected: 02/17/17 17:30 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dichlorodifluoromethane ND ug/L 02/27/17 21:15 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:15 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:15 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:15 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:15 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:15 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:15 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:15 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:15 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:15 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:15 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:15 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:15 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:15 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:15 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:15 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:15 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:15 126-98-7100 0.93 1
Methylene Chloride 8.3 ug/L 02/27/17 21:15 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/27/17 21:15 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:15 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:15 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:15 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:15 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:15 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:15 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:15 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:15 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:15 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:15 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:15 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:15 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:15 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:15 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:15 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:15 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:15 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:15 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/27/17 21:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %02/27/17 21:15 17060-07-070-130 1
Toluene-d8 (S)107 %02/27/17 21:15 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 03/01/17 13:42 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: FB Lab ID: 92331034002 Collected: 02/17/17 17:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:32 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:32 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:32 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:32 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:32 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:32 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:32 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:32 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:32 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:32 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:32 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:32 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:32 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:32 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:32 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:32 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:32 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/27/17 21:32 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:32 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:32 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:32 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:32 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:32 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:32 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:32 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:32 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:32 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:32 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:32 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:32 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:32 126-98-7100 0.93 1
Methylene Chloride 9.6 ug/L 02/27/17 21:32 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: FB Lab ID: 92331034002 Collected: 02/17/17 17:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/27/17 21:32 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:32 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:32 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:32 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:32 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:32 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:32 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:32 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)107 %02/27/17 21:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)116 %02/27/17 21:32 17060-07-070-130 1
Toluene-d8 (S)104 %02/27/17 21:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: TB Lab ID: 92331034003 Collected: 02/17/17 00:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:49 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:49 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:49 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:49 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:49 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:49 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:49 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:49 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:49 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:49 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:49 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:49 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:49 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:49 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:49 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/27/17 21:49 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:49 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:49 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:49 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:49 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:49 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:49 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:49 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:49 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:49 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:49 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:49 126-98-7100 0.93 1
Methylene Chloride 4.4 ug/L 02/27/17 21:49 75-09-2 C91.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: TB Lab ID: 92331034003 Collected: 02/17/17 00:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/27/17 21:49 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:49 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:49 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:49 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:49 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:49 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:49 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:49 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/27/17 21:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)110 %02/27/17 21:49 17060-07-070-130 1
Toluene-d8 (S)107 %02/27/17 21:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349553
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939173
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 03/03/17 06:243.9
Arsenic ug/L ND 10.0 03/03/17 06:245.0
Barium ug/L ND 5.0 03/03/17 06:242.5
Beryllium ug/L ND 1.0 03/03/17 06:240.50
Cadmium ug/L ND 1.0 03/03/17 06:240.50
Chromium ug/L ND 5.0 03/03/17 06:242.5
Cobalt ug/L ND 5.0 03/03/17 06:242.5
Copper ug/L ND 5.0 03/03/17 06:242.5
Lead ug/L ND 5.0 03/03/17 06:242.5
Nickel ug/L ND 5.0 03/03/17 06:242.5
Selenium ug/L ND 10.0 03/03/17 06:245.0
Silver ug/L ND 5.0 03/03/17 06:242.5
Tin ug/L ND 5.0 03/03/17 06:242.5
Vanadium ug/L ND 5.0 03/03/17 06:242.5
Zinc ug/L ND 10.0 03/03/17 06:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939174LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 482500 96 80-120
Arsenic ug/L 461500 92 80-120
Barium ug/L 461500 92 80-120
Beryllium ug/L 475500 95 80-120
Cadmium ug/L 464500 93 80-120
Chromium ug/L 466500 93 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 460500 92 80-120
Nickel ug/L 460500 92 80-120
Selenium ug/L 463500 93 80-120
Silver ug/L 244250 97 80-120
Tin ug/L 477500 95 80-120
Vanadium ug/L 472500 94 80-120
Zinc ug/L 460500 92 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12598 3 20500ND480 492
Arsenic ug/L 500 92 75-12594 2 20500ND459 469
Barium ug/L 500 91 75-12593 2 20500ND456 465
Beryllium ug/L 500 94 75-12596 2 20500ND469 480
Cadmium ug/L 500 92 75-12594 2 20500ND462 469
Chromium ug/L 500 93 75-12595 2 20500ND466 474
Cobalt ug/L 500 93 75-12595 2 20500ND466 475
Copper ug/L 500 97 75-12598 1 20500ND487 491
Lead ug/L 500 91 75-12594 2 20500ND457 468
Nickel ug/L 500 92 75-12593 2 20500ND458 467
Selenium ug/L 500 92 75-12594 2 20500ND462 471
Silver ug/L 250 97 75-12598 2 20250ND242 246
Tin ug/L 500 95 75-12597 2 20500ND476 488
Vanadium ug/L 500 95 75-12596 1 20500ND475 482
Zinc ug/L 500 91 75-12593 2 20500ND456 465
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349668
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939942
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 20:120.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939943LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330519013
1939981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 90 75-12595 6 201000.034J 90.2 95.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350034
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92331034001, 92331034002, 92331034003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92331034001, 92331034002, 92331034003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/27/17 16:450.33
1,1,1-Trichloroethane ug/L ND 1.0 02/27/17 16:450.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/27/17 16:450.40
1,1,2-Trichloroethane ug/L ND 1.0 02/27/17 16:450.29
1,1-Dichloroethane ug/L ND 5.0 02/27/17 16:450.32
1,1-Dichloroethene ug/L ND 5.0 02/27/17 16:450.56
1,1-Dichloropropene ug/L ND 5.0 02/27/17 16:450.49
1,2,3-Trichloropropane ug/L ND 1.0 02/27/17 16:450.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/27/17 16:450.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/27/17 16:452.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/27/17 16:450.27
1,2-Dichlorobenzene ug/L ND 5.0 02/27/17 16:450.30
1,2-Dichloroethane ug/L ND 1.0 02/27/17 16:450.24
1,2-Dichloropropane ug/L ND 1.0 02/27/17 16:450.27
1,3-Dichlorobenzene ug/L ND 5.0 02/27/17 16:450.24
1,3-Dichloropropane ug/L ND 1.0 02/27/17 16:450.28
1,4-Dichlorobenzene ug/L ND 1.0 02/27/17 16:450.33
2,2-Dichloropropane ug/L ND 15.0 02/27/17 16:450.13
2-Butanone (MEK)ug/L ND 100 02/27/17 16:450.96
2-Hexanone ug/L ND 50.0 02/27/17 16:450.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/27/17 16:450.33
Acetone ug/L ND 100 02/27/17 16:4510.0
Acetonitrile ug/L ND 55.0 02/27/17 16:452.2
Acrolein ug/L ND 53.0 02/27/17 16:451.6
Acrylonitrile ug/L ND 200 02/27/17 16:451.9
Allyl chloride ug/L ND 10.0 02/27/17 16:451.5
Benzene ug/L ND 1.0 02/27/17 16:450.25
Bromochloromethane ug/L ND 3.0 02/27/17 16:450.17
Bromodichloromethane ug/L ND 1.0 02/27/17 16:450.18
Bromoform ug/L ND 3.0 02/27/17 16:450.26
Bromomethane ug/L ND 10.0 02/27/17 16:450.29
Carbon disulfide ug/L ND 100 02/27/17 16:451.2
Carbon tetrachloride ug/L ND 1.0 02/27/17 16:450.25
Chlorobenzene ug/L ND 3.0 02/27/17 16:450.23
Chloroethane ug/L ND 10.0 02/27/17 16:450.54
Chloroform ug/L ND 5.0 02/27/17 16:450.14
Chloromethane ug/L ND 1.0 02/27/17 16:450.11
Chloroprene ug/L ND 20.0 02/27/17 16:450.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.13
Dibromochloromethane ug/L ND 3.0 02/27/17 16:450.21
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92331034001, 92331034002, 92331034003
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 02/27/17 16:450.21
Dichlorodifluoromethane ug/L ND 5.0 02/27/17 16:450.21
Ethyl methacrylate ug/L ND 10.0 02/27/17 16:450.20
Ethylbenzene ug/L ND 1.0 02/27/17 16:450.30
Hexachloro-1,3-butadiene ug/L ND 10.0 02/27/17 16:450.71
Iodomethane ug/L ND 10.0 02/27/17 16:450.32
Isobutanol ug/L ND 100 02/27/17 16:4535.0
Methacrylonitrile ug/L ND 100 02/27/17 16:450.93
Methyl methacrylate ug/L ND 30.0 02/27/17 16:452.0
Methylene Chloride ug/L ND 1.0 02/27/17 16:450.97
Naphthalene ug/L ND 10.0 02/27/17 16:450.24
Propionitrile ug/L ND 150 02/27/17 16:453.6
Styrene ug/L ND 1.0 02/27/17 16:450.26
Tetrachloroethene ug/L ND 1.0 02/27/17 16:450.46
Tetrahydrofuran ug/L ND 10.0 02/27/17 16:453.1
Toluene ug/L ND 1.0 02/27/17 16:450.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/27/17 16:451.0
Trichloroethene ug/L ND 1.0 02/27/17 16:450.47
Trichlorofluoromethane ug/L ND 1.0 02/27/17 16:450.20
Vinyl acetate ug/L ND 50.0 02/27/17 16:450.35
Vinyl chloride ug/L ND 1.0 02/27/17 16:450.62
Xylene (Total)ug/L ND 5.0 02/27/17 16:450.66
1,2-Dichloroethane-d4 (S)%98 70-130 02/27/17 16:45
4-Bromofluorobenzene (S)%97 70-130 02/27/17 16:45
Toluene-d8 (S)%93 70-130 02/27/17 16:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.250 96 80-125
1,1,1-Trichloroethane ug/L 47.150 94 71-129
1,1,2,2-Tetrachloroethane ug/L 47.350 95 79-124
1,1,2-Trichloroethane ug/L 49.450 99 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 51.250 102 66-135
1,1-Dichloropropene ug/L 48.650 97 74-135
1,2,3-Trichloropropane ug/L 46.550 93 75-130
1,2,4-Trichlorobenzene ug/L 49.050 98 75-134
1,2-Dibromo-3-chloropropane ug/L 48.350 97 71-133
1,2-Dibromoethane (EDB)ug/L 47.350 95 83-124
1,2-Dichlorobenzene ug/L 47.750 95 80-133
1,2-Dichloroethane ug/L 42.850 86 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 47.250 94 75-132
1,3-Dichlorobenzene ug/L 47.150 94 77-130
1,3-Dichloropropane ug/L 47.050 94 76-131
1,4-Dichlorobenzene ug/L 45.550 91 78-130
2,2-Dichloropropane ug/L 48.150 96 40-160
2-Butanone (MEK)ug/L 95.0J100 95 61-144
2-Hexanone ug/L 96.6100 97 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.2J100 97 72-135
Acetone ug/L 103100 103 48-146
Acetonitrile ug/L 444500 89 62-150
Acrolein ug/L 235250 94 24-160
Acrylonitrile ug/L 239250 96 40-160
Allyl chloride ug/L 46.550 93 66-137
Benzene ug/L 48.750 97 80-125
Bromochloromethane ug/L 46.350 93 71-125
Bromodichloromethane ug/L 50.250 100 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 49.150 98 40-160
Carbon disulfide ug/L 49.1J50 98 50-160
Carbon tetrachloride ug/L 48.550 97 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 52.150 104 39-148
Chloroform ug/L 44.250 88 73-127
Chloromethane ug/L 48.850 98 44-146
Chloroprene ug/L 50.550 101 75-145
cis-1,2-Dichloroethene ug/L 44.750 89 74-124
cis-1,3-Dichloropropene ug/L 50.150 100 72-132
Dibromochloromethane ug/L 49.250 98 78-125
Dibromomethane ug/L 48.950 98 82-120
Dichlorodifluoromethane ug/L 53.350 107 34-157
Ethyl methacrylate ug/L 49.450 99 82-121
Ethylbenzene ug/L 48.050 96 79-121
Hexachloro-1,3-butadiene ug/L 53.550 107 72-131
Iodomethane ug/L 96.4100 96 39-154
Isobutanol ug/L 9971000 100 34-160
Methacrylonitrile ug/L 469500 94 74-134
Methyl methacrylate ug/L 50.850 102 84-124
Methylene Chloride ug/L 48.050 96 64-133
Naphthalene ug/L 48.450 97 73-133
Propionitrile ug/L 457500 91 73-140
Styrene ug/L 48.250 96 84-126
Tetrachloroethene ug/L 48.250 96 78-122
Tetrahydrofuran ug/L 474500 95 69-148
Toluene ug/L 47.650 95 80-121
trans-1,2-Dichloroethene ug/L 47.750 95 71-127
trans-1,3-Dichloropropene ug/L 48.750 97 69-141
trans-1,4-Dichloro-2-butene ug/L 44.3J50 89 40-160
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 48.550 97 78-122
Trichlorofluoromethane ug/L 58.950 118 53-137
Vinyl acetate ug/L 96.8100 97 40-160
Vinyl chloride ug/L 44.050 88 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 22.920 115 70-130ND
1,1,2-Trichloroethane ug/L 23.220 116 70-130ND
1,1-Dichloroethane ug/L 21.920 109 70-130ND
1,1-Dichloroethene ug/L 23.620 118 70-166ND
1,1-Dichloropropene ug/L 23.020 115 70-130ND
1,2,3-Trichloropropane ug/L 22.520 113 70-130ND
1,2,4-Trichlorobenzene ug/L 22.220 111 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.420 112 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.620 102 70-130ND
1,2-Dichloropropane ug/L 22.420 112 70-130ND
1,3-Dichlorobenzene ug/L 21.920 109 70-130ND
1,3-Dichloropropane ug/L 24.120 120 70-130ND
1,4-Dichlorobenzene ug/L 21.520 108 70-130ND
2,2-Dichloropropane ug/L 20.720 104 70-130ND
2-Butanone (MEK)ug/L 43.0J40 107 70-130ND
2-Hexanone ug/L 45.5J40 114 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 45.1J40 113 70-130ND
Acetone ug/L 43.1J40 105 70-130ND
Acetonitrile ug/L 204200 102 70-130ND
Acrolein ug/L 98.4100 98 70-130ND
Acrylonitrile ug/L 104J100 104 70-130ND
Allyl chloride ug/L 22.320 112 70-130ND
Benzene ug/L 24.420 122 70-148ND
Bromochloromethane ug/L 21.520 107 70-130ND
Bromodichloromethane ug/L 23.820 119 70-130ND
Bromoform ug/L 19.720 98 70-130ND
Bromomethane ug/L 20.820 104 70-130ND
Carbon disulfide ug/L 21.2J20 106 70-130ND
Carbon tetrachloride ug/L 24.120 121 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 23.320 117 70-130ND
Chloroform ug/L 21.820 109 70-130ND
Chloromethane ug/L 23.720 118 70-130ND
Chloroprene ug/L 24.820 124 70-130ND
cis-1,2-Dichloroethene ug/L 21.920 110 70-130ND
cis-1,3-Dichloropropene ug/L 22.720 113 70-130ND
Dibromochloromethane ug/L 24.120 121 70-130ND
Dibromomethane ug/L 21.320 107 70-130ND
Dichlorodifluoromethane ug/L 22.320 112 70-130ND
Ethyl methacrylate ug/L 23.720 118 70-130ND
Ethylbenzene ug/L 23.220 116 70-130ND
Hexachloro-1,3-butadiene ug/L 23.420 117 70-130ND
Iodomethane ug/L 43.140 108 70-130ND
Isobutanol ug/L 388400 97 70-130ND
Methacrylonitrile ug/L 216200 108 70-130ND
Methyl methacrylate ug/L 23.1J20 115 70-130ND
Methylene Chloride ug/L 21.920 109 70-130ND
Naphthalene ug/L 21.620 108 70-130ND
Propionitrile ug/L 206200 103 70-130ND
Styrene ug/L 22.520 112 70-130ND
Tetrachloroethene ug/L 24.720 124 70-130ND
Tetrahydrofuran ug/L 211200 106 70-130ND
Toluene ug/L 23.920 120 70-155ND
trans-1,2-Dichloroethene ug/L 22.820 114 70-130ND
trans-1,3-Dichloropropene ug/L 22.420 112 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.3J20 96 70-130ND
Trichloroethene ug/L 24.120 121 69-151ND
Trichlorofluoromethane ug/L 25.020 125 70-130ND
Vinyl acetate ug/L 39.2J40 98 70-130ND
Vinyl chloride ug/L 19.520 98 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 298
4-Bromofluorobenzene (S)%94 392
Toluene-d8 (S)%97 3100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350196
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1942543
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 03/01/17 13:284.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1942544LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1942545MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331094001
1942546
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 80-12088 1 10100ND89.3 90.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1942547MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331074003
1942548
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M11006780-12070 3 101000.0094
mg/L 76.8 79.5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92331034001 349553 349687EBEPA 3010A EPA 6010
92331034001 349668 349712EBEPA 3010A EPA 6020B
92331034001 350034EBEPA 8260
92331034002 350034FBEPA 8260
92331034003 350034TBEPA 8260
92331034001 350196EBSM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
Page 24 of 26
Page 25 of 26
Page 26 of 26
#=CL#
March 03, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92331034
92331034
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
WAYNE MSWLF BLANKS
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory on February 22, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 26
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 26
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID Matrix Date Collected Date Received
92331034001 EB Water 02/17/17 17:30 02/22/17 08:00
92331034002 FB Water 02/17/17 17:35 02/22/17 08:00
92331034003 TB Water 02/17/17 00:00 02/22/17 08:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92331034001 EB EPA 6010 15 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 68 PASI-CCAH
SM 4500-CN-E 1 PASI-ADMN
92331034002 FB EPA 8260 68 PASI-CCAH
92331034003 TB EPA 8260 68 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 4 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: EB Lab ID: 92331034001 Collected: 02/17/17 17:30 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/03/17 06:33 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/03/17 06:33 7440-38-202/23/17 19:3510.0 5.0 1
Barium ND ug/L 03/03/17 06:33 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/03/17 06:33 7440-41-702/23/17 19:351.0 0.50 1
Cadmium ND ug/L 03/03/17 06:33 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/03/17 06:33 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/03/17 06:33 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/03/17 06:33 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/03/17 06:33 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/03/17 06:33 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/03/17 06:33 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/03/17 06:33 7440-22-402/23/17 19:3510.0 2.5 1
Tin ND ug/L 03/03/17 06:33 7440-31-502/23/17 19:35100 2.5 1
Vanadium ND ug/L 03/03/17 06:33 7440-62-202/23/17 19:3525.0 2.5 1
Zinc ND ug/L 03/03/17 06:33 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 20:53 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:15 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:15 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:15 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:15 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:15 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:15 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:15 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:15 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:15 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:15 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:15 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:15 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:15 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:15 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:15 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:15 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:15 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:15 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:15 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:15 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:15 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:15 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:15 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:15 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:15 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:15 110-57-6100 1.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 5 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: EB Lab ID: 92331034001 Collected: 02/17/17 17:30 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dichlorodifluoromethane ND ug/L 02/27/17 21:15 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:15 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:15 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:15 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:15 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:15 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:15 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:15 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:15 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:15 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:15 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:15 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:15 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:15 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:15 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:15 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:15 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:15 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:15 126-98-7100 0.93 1
Methylene Chloride 8.3 ug/L 02/27/17 21:15 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/27/17 21:15 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:15 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:15 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:15 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:15 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:15 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:15 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:15 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:15 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:15 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:15 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:15 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:15 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:15 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:15 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:15 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:15 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:15 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:15 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/27/17 21:15 460-00-470-130 1
1,2-Dichloroethane-d4 (S)114 %02/27/17 21:15 17060-07-070-130 1
Toluene-d8 (S)107 %02/27/17 21:15 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 03/01/17 13:42 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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[phone]
Page 6 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: FB Lab ID: 92331034002 Collected: 02/17/17 17:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:32 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:32 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:32 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:32 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:32 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:32 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:32 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:32 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:32 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:32 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:32 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:32 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:32 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:32 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:32 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:32 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:32 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:32 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:32 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:32 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:32 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:32 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:32 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:32 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:32 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:32 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/27/17 21:32 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:32 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:32 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:32 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:32 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:32 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:32 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:32 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:32 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:32 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:32 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:32 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:32 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:32 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:32 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:32 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:32 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:32 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:32 126-98-7100 0.93 1
Methylene Chloride 9.6 ug/L 02/27/17 21:32 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 7 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: FB Lab ID: 92331034002 Collected: 02/17/17 17:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/27/17 21:32 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:32 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:32 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:32 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:32 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:32 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:32 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:32 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:32 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:32 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:32 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:32 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:32 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:32 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:32 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:32 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:32 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:32 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:32 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)107 %02/27/17 21:32 460-00-470-130 1
1,2-Dichloroethane-d4 (S)116 %02/27/17 21:32 17060-07-070-130 1
Toluene-d8 (S)104 %02/27/17 21:32 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
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Page 8 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: TB Lab ID: 92331034003 Collected: 02/17/17 00:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/27/17 21:49 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/27/17 21:49 75-05-855.0 2.2 1
Acrolein ND ug/L 02/27/17 21:49 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/27/17 21:49 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/27/17 21:49 107-05-110.0 1.5 1
Benzene ND ug/L 02/27/17 21:49 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/27/17 21:49 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/27/17 21:49 75-27-41.0 0.18 1
Bromoform ND ug/L 02/27/17 21:49 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/27/17 21:49 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/27/17 21:49 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/27/17 21:49 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/27/17 21:49 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/27/17 21:49 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/27/17 21:49 75-00-310.0 0.54 1
Chloroform ND ug/L 02/27/17 21:49 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/27/17 21:49 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/27/17 21:49 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/27/17 21:49 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/27/17 21:49 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/27/17 21:49 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/27/17 21:49 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/27/17 21:49 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/27/17 21:49 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/27/17 21:49 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/27/17 21:49 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/27/17 21:49 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/27/17 21:49 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/27/17 21:49 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/27/17 21:49 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/27/17 21:49 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/27/17 21:49 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/27/17 21:49 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/27/17 21:49 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/27/17 21:49 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/27/17 21:49 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/27/17 21:49 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/27/17 21:49 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/27/17 21:49 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/27/17 21:49 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 02/27/17 21:49 87-68-310.0 0.71 1
2-Hexanone ND ug/L 02/27/17 21:49 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/27/17 21:49 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/27/17 21:49 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/27/17 21:49 126-98-7100 0.93 1
Methylene Chloride 4.4 ug/L 02/27/17 21:49 75-09-2 C91.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 9 of 26
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Sample: TB Lab ID: 92331034003 Collected: 02/17/17 00:00 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 02/27/17 21:49 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/27/17 21:49 108-10-1100 0.33 1
Naphthalene ND ug/L 02/27/17 21:49 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/27/17 21:49 107-12-0150 3.6 1
Styrene ND ug/L 02/27/17 21:49 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/27/17 21:49 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/27/17 21:49 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/27/17 21:49 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/27/17 21:49 109-99-910.0 3.1 1
Toluene ND ug/L 02/27/17 21:49 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/27/17 21:49 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/27/17 21:49 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/27/17 21:49 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/27/17 21:49 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/27/17 21:49 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/27/17 21:49 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/27/17 21:49 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/27/17 21:49 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/27/17 21:49 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/27/17 21:49 460-00-470-130 1
1,2-Dichloroethane-d4 (S)110 %02/27/17 21:49 17060-07-070-130 1
Toluene-d8 (S)107 %02/27/17 21:49 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Huntersville, NC 28078
[phone]
Page 10 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349553
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939173
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 03/03/17 06:243.9
Arsenic ug/L ND 10.0 03/03/17 06:245.0
Barium ug/L ND 5.0 03/03/17 06:242.5
Beryllium ug/L ND 1.0 03/03/17 06:240.50
Cadmium ug/L ND 1.0 03/03/17 06:240.50
Chromium ug/L ND 5.0 03/03/17 06:242.5
Cobalt ug/L ND 5.0 03/03/17 06:242.5
Copper ug/L ND 5.0 03/03/17 06:242.5
Lead ug/L ND 5.0 03/03/17 06:242.5
Nickel ug/L ND 5.0 03/03/17 06:242.5
Selenium ug/L ND 10.0 03/03/17 06:245.0
Silver ug/L ND 5.0 03/03/17 06:242.5
Tin ug/L ND 5.0 03/03/17 06:242.5
Vanadium ug/L ND 5.0 03/03/17 06:242.5
Zinc ug/L ND 10.0 03/03/17 06:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939174LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 482500 96 80-120
Arsenic ug/L 461500 92 80-120
Barium ug/L 461500 92 80-120
Beryllium ug/L 475500 95 80-120
Cadmium ug/L 464500 93 80-120
Chromium ug/L 466500 93 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 460500 92 80-120
Nickel ug/L 460500 92 80-120
Selenium ug/L 463500 93 80-120
Silver ug/L 244250 97 80-120
Tin ug/L 477500 95 80-120
Vanadium ug/L 472500 94 80-120
Zinc ug/L 460500 92 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12598 3 20500ND480 492
Arsenic ug/L 500 92 75-12594 2 20500ND459 469
Barium ug/L 500 91 75-12593 2 20500ND456 465
Beryllium ug/L 500 94 75-12596 2 20500ND469 480
Cadmium ug/L 500 92 75-12594 2 20500ND462 469
Chromium ug/L 500 93 75-12595 2 20500ND466 474
Cobalt ug/L 500 93 75-12595 2 20500ND466 475
Copper ug/L 500 97 75-12598 1 20500ND487 491
Lead ug/L 500 91 75-12594 2 20500ND457 468
Nickel ug/L 500 92 75-12593 2 20500ND458 467
Selenium ug/L 500 92 75-12594 2 20500ND462 471
Silver ug/L 250 97 75-12598 2 20250ND242 246
Tin ug/L 500 95 75-12597 2 20500ND476 488
Vanadium ug/L 500 95 75-12596 1 20500ND475 482
Zinc ug/L 500 91 75-12593 2 20500ND456 465
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349668
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939942
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 20:120.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939943LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330519013
1939981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 90 75-12595 6 201000.034J 90.2 95.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350034
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92331034001, 92331034002, 92331034003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92331034001, 92331034002, 92331034003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/27/17 16:450.33
1,1,1-Trichloroethane ug/L ND 1.0 02/27/17 16:450.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/27/17 16:450.40
1,1,2-Trichloroethane ug/L ND 1.0 02/27/17 16:450.29
1,1-Dichloroethane ug/L ND 5.0 02/27/17 16:450.32
1,1-Dichloroethene ug/L ND 5.0 02/27/17 16:450.56
1,1-Dichloropropene ug/L ND 5.0 02/27/17 16:450.49
1,2,3-Trichloropropane ug/L ND 1.0 02/27/17 16:450.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/27/17 16:450.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/27/17 16:452.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/27/17 16:450.27
1,2-Dichlorobenzene ug/L ND 5.0 02/27/17 16:450.30
1,2-Dichloroethane ug/L ND 1.0 02/27/17 16:450.24
1,2-Dichloropropane ug/L ND 1.0 02/27/17 16:450.27
1,3-Dichlorobenzene ug/L ND 5.0 02/27/17 16:450.24
1,3-Dichloropropane ug/L ND 1.0 02/27/17 16:450.28
1,4-Dichlorobenzene ug/L ND 1.0 02/27/17 16:450.33
2,2-Dichloropropane ug/L ND 15.0 02/27/17 16:450.13
2-Butanone (MEK)ug/L ND 100 02/27/17 16:450.96
2-Hexanone ug/L ND 50.0 02/27/17 16:450.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/27/17 16:450.33
Acetone ug/L ND 100 02/27/17 16:4510.0
Acetonitrile ug/L ND 55.0 02/27/17 16:452.2
Acrolein ug/L ND 53.0 02/27/17 16:451.6
Acrylonitrile ug/L ND 200 02/27/17 16:451.9
Allyl chloride ug/L ND 10.0 02/27/17 16:451.5
Benzene ug/L ND 1.0 02/27/17 16:450.25
Bromochloromethane ug/L ND 3.0 02/27/17 16:450.17
Bromodichloromethane ug/L ND 1.0 02/27/17 16:450.18
Bromoform ug/L ND 3.0 02/27/17 16:450.26
Bromomethane ug/L ND 10.0 02/27/17 16:450.29
Carbon disulfide ug/L ND 100 02/27/17 16:451.2
Carbon tetrachloride ug/L ND 1.0 02/27/17 16:450.25
Chlorobenzene ug/L ND 3.0 02/27/17 16:450.23
Chloroethane ug/L ND 10.0 02/27/17 16:450.54
Chloroform ug/L ND 5.0 02/27/17 16:450.14
Chloromethane ug/L ND 1.0 02/27/17 16:450.11
Chloroprene ug/L ND 20.0 02/27/17 16:450.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.13
Dibromochloromethane ug/L ND 3.0 02/27/17 16:450.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941758
Associated Lab Samples:92331034001, 92331034002, 92331034003
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 02/27/17 16:450.21
Dichlorodifluoromethane ug/L ND 5.0 02/27/17 16:450.21
Ethyl methacrylate ug/L ND 10.0 02/27/17 16:450.20
Ethylbenzene ug/L ND 1.0 02/27/17 16:450.30
Hexachloro-1,3-butadiene ug/L ND 10.0 02/27/17 16:450.71
Iodomethane ug/L ND 10.0 02/27/17 16:450.32
Isobutanol ug/L ND 100 02/27/17 16:4535.0
Methacrylonitrile ug/L ND 100 02/27/17 16:450.93
Methyl methacrylate ug/L ND 30.0 02/27/17 16:452.0
Methylene Chloride ug/L ND 1.0 02/27/17 16:450.97
Naphthalene ug/L ND 10.0 02/27/17 16:450.24
Propionitrile ug/L ND 150 02/27/17 16:453.6
Styrene ug/L ND 1.0 02/27/17 16:450.26
Tetrachloroethene ug/L ND 1.0 02/27/17 16:450.46
Tetrahydrofuran ug/L ND 10.0 02/27/17 16:453.1
Toluene ug/L ND 1.0 02/27/17 16:450.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/27/17 16:450.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/27/17 16:450.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/27/17 16:451.0
Trichloroethene ug/L ND 1.0 02/27/17 16:450.47
Trichlorofluoromethane ug/L ND 1.0 02/27/17 16:450.20
Vinyl acetate ug/L ND 50.0 02/27/17 16:450.35
Vinyl chloride ug/L ND 1.0 02/27/17 16:450.62
Xylene (Total)ug/L ND 5.0 02/27/17 16:450.66
1,2-Dichloroethane-d4 (S)%98 70-130 02/27/17 16:45
4-Bromofluorobenzene (S)%97 70-130 02/27/17 16:45
Toluene-d8 (S)%93 70-130 02/27/17 16:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.250 96 80-125
1,1,1-Trichloroethane ug/L 47.150 94 71-129
1,1,2,2-Tetrachloroethane ug/L 47.350 95 79-124
1,1,2-Trichloroethane ug/L 49.450 99 85-125
1,1-Dichloroethane ug/L 45.250 90 73-126
1,1-Dichloroethene ug/L 51.250 102 66-135
1,1-Dichloropropene ug/L 48.650 97 74-135
1,2,3-Trichloropropane ug/L 46.550 93 75-130
1,2,4-Trichlorobenzene ug/L 49.050 98 75-134
1,2-Dibromo-3-chloropropane ug/L 48.350 97 71-133
1,2-Dibromoethane (EDB)ug/L 47.350 95 83-124
1,2-Dichlorobenzene ug/L 47.750 95 80-133
1,2-Dichloroethane ug/L 42.850 86 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 47.250 94 75-132
1,3-Dichlorobenzene ug/L 47.150 94 77-130
1,3-Dichloropropane ug/L 47.050 94 76-131
1,4-Dichlorobenzene ug/L 45.550 91 78-130
2,2-Dichloropropane ug/L 48.150 96 40-160
2-Butanone (MEK)ug/L 95.0J100 95 61-144
2-Hexanone ug/L 96.6100 97 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.2J100 97 72-135
Acetone ug/L 103100 103 48-146
Acetonitrile ug/L 444500 89 62-150
Acrolein ug/L 235250 94 24-160
Acrylonitrile ug/L 239250 96 40-160
Allyl chloride ug/L 46.550 93 66-137
Benzene ug/L 48.750 97 80-125
Bromochloromethane ug/L 46.350 93 71-125
Bromodichloromethane ug/L 50.250 100 78-124
Bromoform ug/L 47.950 96 71-128
Bromomethane ug/L 49.150 98 40-160
Carbon disulfide ug/L 49.1J50 98 50-160
Carbon tetrachloride ug/L 48.550 97 69-131
Chlorobenzene ug/L 48.850 98 81-122
Chloroethane ug/L 52.150 104 39-148
Chloroform ug/L 44.250 88 73-127
Chloromethane ug/L 48.850 98 44-146
Chloroprene ug/L 50.550 101 75-145
cis-1,2-Dichloroethene ug/L 44.750 89 74-124
cis-1,3-Dichloropropene ug/L 50.150 100 72-132
Dibromochloromethane ug/L 49.250 98 78-125
Dibromomethane ug/L 48.950 98 82-120
Dichlorodifluoromethane ug/L 53.350 107 34-157
Ethyl methacrylate ug/L 49.450 99 82-121
Ethylbenzene ug/L 48.050 96 79-121
Hexachloro-1,3-butadiene ug/L 53.550 107 72-131
Iodomethane ug/L 96.4100 96 39-154
Isobutanol ug/L 9971000 100 34-160
Methacrylonitrile ug/L 469500 94 74-134
Methyl methacrylate ug/L 50.850 102 84-124
Methylene Chloride ug/L 48.050 96 64-133
Naphthalene ug/L 48.450 97 73-133
Propionitrile ug/L 457500 91 73-140
Styrene ug/L 48.250 96 84-126
Tetrachloroethene ug/L 48.250 96 78-122
Tetrahydrofuran ug/L 474500 95 69-148
Toluene ug/L 47.650 95 80-121
trans-1,2-Dichloroethene ug/L 47.750 95 71-127
trans-1,3-Dichloropropene ug/L 48.750 97 69-141
trans-1,4-Dichloro-2-butene ug/L 44.3J50 89 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 16 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941759LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 48.550 97 78-122
Trichlorofluoromethane ug/L 58.950 118 53-137
Vinyl acetate ug/L 96.8100 97 40-160
Vinyl chloride ug/L 44.050 88 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
1,1,1,2-Tetrachloroethane ug/L 21.620 108 70-130ND
1,1,1-Trichloroethane ug/L 22.520 113 70-130ND
1,1,2,2-Tetrachloroethane ug/L 22.920 115 70-130ND
1,1,2-Trichloroethane ug/L 23.220 116 70-130ND
1,1-Dichloroethane ug/L 21.920 109 70-130ND
1,1-Dichloroethene ug/L 23.620 118 70-166ND
1,1-Dichloropropene ug/L 23.020 115 70-130ND
1,2,3-Trichloropropane ug/L 22.520 113 70-130ND
1,2,4-Trichlorobenzene ug/L 22.220 111 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.620 98 70-130ND
1,2-Dibromoethane (EDB)ug/L 22.420 112 70-130ND
1,2-Dichlorobenzene ug/L 22.420 112 70-130ND
1,2-Dichloroethane ug/L 20.620 102 70-130ND
1,2-Dichloropropane ug/L 22.420 112 70-130ND
1,3-Dichlorobenzene ug/L 21.920 109 70-130ND
1,3-Dichloropropane ug/L 24.120 120 70-130ND
1,4-Dichlorobenzene ug/L 21.520 108 70-130ND
2,2-Dichloropropane ug/L 20.720 104 70-130ND
2-Butanone (MEK)ug/L 43.0J40 107 70-130ND
2-Hexanone ug/L 45.5J40 114 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 45.1J40 113 70-130ND
Acetone ug/L 43.1J40 105 70-130ND
Acetonitrile ug/L 204200 102 70-130ND
Acrolein ug/L 98.4100 98 70-130ND
Acrylonitrile ug/L 104J100 104 70-130ND
Allyl chloride ug/L 22.320 112 70-130ND
Benzene ug/L 24.420 122 70-148ND
Bromochloromethane ug/L 21.520 107 70-130ND
Bromodichloromethane ug/L 23.820 119 70-130ND
Bromoform ug/L 19.720 98 70-130ND
Bromomethane ug/L 20.820 104 70-130ND
Carbon disulfide ug/L 21.2J20 106 70-130ND
Carbon tetrachloride ug/L 24.120 121 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 17 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1941760MATRIX SPIKE SAMPLE:
MSSpike
Result
92330540007
Chlorobenzene ug/L 22.720 113 70-146ND
Chloroethane ug/L 23.320 117 70-130ND
Chloroform ug/L 21.820 109 70-130ND
Chloromethane ug/L 23.720 118 70-130ND
Chloroprene ug/L 24.820 124 70-130ND
cis-1,2-Dichloroethene ug/L 21.920 110 70-130ND
cis-1,3-Dichloropropene ug/L 22.720 113 70-130ND
Dibromochloromethane ug/L 24.120 121 70-130ND
Dibromomethane ug/L 21.320 107 70-130ND
Dichlorodifluoromethane ug/L 22.320 112 70-130ND
Ethyl methacrylate ug/L 23.720 118 70-130ND
Ethylbenzene ug/L 23.220 116 70-130ND
Hexachloro-1,3-butadiene ug/L 23.420 117 70-130ND
Iodomethane ug/L 43.140 108 70-130ND
Isobutanol ug/L 388400 97 70-130ND
Methacrylonitrile ug/L 216200 108 70-130ND
Methyl methacrylate ug/L 23.1J20 115 70-130ND
Methylene Chloride ug/L 21.920 109 70-130ND
Naphthalene ug/L 21.620 108 70-130ND
Propionitrile ug/L 206200 103 70-130ND
Styrene ug/L 22.520 112 70-130ND
Tetrachloroethene ug/L 24.720 124 70-130ND
Tetrahydrofuran ug/L 211200 106 70-130ND
Toluene ug/L 23.920 120 70-155ND
trans-1,2-Dichloroethene ug/L 22.820 114 70-130ND
trans-1,3-Dichloropropene ug/L 22.420 112 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.3J20 96 70-130ND
Trichloroethene ug/L 24.120 121 69-151ND
Trichlorofluoromethane ug/L 25.020 125 70-130ND
Vinyl acetate ug/L 39.2J40 98 70-130ND
Vinyl chloride ug/L 19.520 98 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%106 70-130
Toluene-d8 (S)%107 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Page 18 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Huntersville, NC 28078
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Page 19 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330540008
1941761SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 298
4-Bromofluorobenzene (S)%94 392
Toluene-d8 (S)%97 3100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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9800 Kincey Ave. Suite 100
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Page 20 of 26
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350196
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92331034001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1942543
Associated Lab Samples:92331034001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 03/01/17 13:284.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1942544LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1942545MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331094001
1942546
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 80-12088 1 10100ND89.3 90.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1942547MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331074003
1942548
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M11006780-12070 3 101000.0094
mg/L 76.8 79.5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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Huntersville, NC 28078
[phone]
Page 21 of 26
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 26
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92331034
WAYNE MSWLF BLANKS
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92331034001 349553 349687EBEPA 3010A EPA 6010
92331034001 349668 349712EBEPA 3010A EPA 6020B
92331034001 350034EBEPA 8260
92331034002 350034FBEPA 8260
92331034003 350034TBEPA 8260
92331034001 350196EBSM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 03:52 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 26
Page 24 of 26
Page 25 of 26
Page 26 of 26
#=CL#
March 03, 2017
LIMS USE: FR - JONATHAN PFOHL
LIMS OBJECT ID: 92330518
92330518
Project:
Pace Project No.:
RE:
Mr. Jonathan Pfohl
Municipal Engineering Services
68 Shipwash Dr.
Garner, NC 27529
Wayne MSWLF-SWs
Dear Mr. Pfohl:
Enclosed are the analytical results for sample(s) received by the laboratory between February 17,
2017 and February 22, 2017. The results relate only to the samples included in this report. Results
reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's
Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Trey Carter
[e-mail]
Project Manager
[phone]
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 30
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 30
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID Matrix Date Collected Date Received
92330518001 SW-1 Water 02/16/17 13:10 02/17/17 08:52
92330518002 SW-6 Water 02/17/17 13:35 02/22/17 08:00
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 30
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330518001 SW-1 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CGAW
92330518002 SW-6 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 51 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 4 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-1 Lab ID: 92330518001 Collected: 02/16/17 13:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:28 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:28 7440-38-202/20/17 19:5510.0 5.0 1
Barium 43.5J ug/L 02/24/17 06:28 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:28 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:28 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:28 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:28 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:28 7440-50-802/20/17 19:5510.0 2.5 1
Lead 2.9J ug/L 02/24/17 06:28 7439-92-102/20/17 19:5510.0 2.5 1
Nickel ND ug/L 02/24/17 06:28 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:28 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:28 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 2.5J ug/L 02/24/17 06:28 7440-62-202/20/17 19:5525.0 2.5 1
Zinc 12.8 ug/L 02/24/17 06:28 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 18:27 7440-28-002/23/17 02:205.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 19:21 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 19:21 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 19:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 19:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 19:21 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 19:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 19:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 19:21 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 19:21 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 19:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 19:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 19:21 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 19:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 19:21 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 19:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 19:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 19:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 19:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 19:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 19:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 19:21 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 19:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 19:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 19:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 19:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 19:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 19:21 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
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Page 5 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-1 Lab ID: 92330518001 Collected: 02/16/17 13:10 Received: 02/17/17 08:52 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/21/17 19:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 19:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 19:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 19:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 19:21 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 19:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 19:21 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 19:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 19:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 19:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 19:21 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 19:21 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 19:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 19:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 19:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 19:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 19:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 19:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 19:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 19:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 19:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/21/17 19:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/21/17 19:21 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 19:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-6 Lab ID: 92330518002 Collected: 02/17/17 13:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 03/03/17 07:16 7440-36-002/23/17 19:356.0 3.9 1
Arsenic ND ug/L 03/03/17 07:16 7440-38-202/23/17 19:3510.0 5.0 1
Barium 43.8J ug/L 03/03/17 07:16 7440-39-302/23/17 19:35100 2.5 1
Beryllium ND ug/L 03/03/17 07:16 7440-41-702/23/17 19:351.0 0.50 1
Cadmium ND ug/L 03/03/17 07:16 7440-43-902/23/17 19:351.0 0.50 1
Chromium ND ug/L 03/03/17 07:16 7440-47-302/23/17 19:3510.0 2.5 1
Cobalt ND ug/L 03/03/17 07:16 7440-48-402/23/17 19:3510.0 2.5 1
Copper ND ug/L 03/03/17 07:16 7440-50-802/23/17 19:3510.0 2.5 1
Lead ND ug/L 03/03/17 07:16 7439-92-102/23/17 19:3510.0 2.5 1
Nickel ND ug/L 03/03/17 07:16 7440-02-002/23/17 19:3550.0 2.5 1
Selenium ND ug/L 03/03/17 07:16 7782-49-202/23/17 19:3510.0 5.0 1
Silver ND ug/L 03/03/17 07:16 7440-22-402/23/17 19:3510.0 2.5 1
Vanadium ND ug/L 03/03/17 07:16 7440-62-202/23/17 19:3525.0 2.5 1
Zinc 6.0J ug/L 03/03/17 07:16 7440-66-602/23/17 19:3510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/24/17 20:47 7440-28-002/24/17 02:155.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/28/17 02:53 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/28/17 02:53 107-13-1200 1.9 1
Benzene ND ug/L 02/28/17 02:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/28/17 02:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/28/17 02:53 75-27-41.0 0.18 1
Bromoform ND ug/L 02/28/17 02:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/28/17 02:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/28/17 02:53 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/28/17 02:53 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/28/17 02:53 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/28/17 02:53 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/28/17 02:53 75-00-310.0 0.54 1
Chloroform ND ug/L 02/28/17 02:53 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/28/17 02:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/28/17 02:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/28/17 02:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/28/17 02:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/28/17 02:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/28/17 02:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/28/17 02:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/28/17 02:53 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/28/17 02:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/28/17 02:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/28/17 02:53 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/28/17 02:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/28/17 02:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/28/17 02:53 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Huntersville, NC 28078
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Page 7 of 30
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Sample: SW-6 Lab ID: 92330518002 Collected: 02/17/17 13:35 Received: 02/22/17 08:00 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/28/17 02:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/28/17 02:53 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/28/17 02:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/28/17 02:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/28/17 02:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/28/17 02:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/28/17 02:53 108-10-1100 0.33 1
Styrene ND ug/L 02/28/17 02:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/28/17 02:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/28/17 02:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/28/17 02:53 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/28/17 02:53 109-99-910.0 3.1 1
Toluene ND ug/L 02/28/17 02:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/28/17 02:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/28/17 02:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/28/17 02:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/28/17 02:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/28/17 02:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/28/17 02:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/28/17 02:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/28/17 02:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %02/28/17 02:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %02/28/17 02:53 17060-07-070-130 1
Toluene-d8 (S)101 %02/28/17 02:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348994
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936214
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 02/24/17 05:123.9
Arsenic ug/L ND 10.0 02/24/17 05:125.0
Barium ug/L ND 5.0 02/24/17 05:122.5
Beryllium ug/L ND 1.0 02/24/17 05:120.50
Cadmium ug/L ND 1.0 02/24/17 05:120.50
Chromium ug/L ND 5.0 02/24/17 05:122.5
Cobalt ug/L ND 5.0 02/24/17 05:122.5
Copper ug/L ND 5.0 02/24/17 05:122.5
Lead ug/L ND 5.0 02/24/17 05:122.5
Nickel ug/L ND 5.0 02/24/17 05:122.5
Selenium ug/L ND 10.0 02/24/17 05:125.0
Silver ug/L ND 5.0 02/24/17 05:122.5
Vanadium ug/L ND 5.0 02/24/17 05:122.5
Zinc ug/L ND 10.0 02/24/17 05:155.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936215LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 479500 96 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 493500 99 80-120
Beryllium ug/L 491500 98 80-120
Cadmium ug/L 479500 96 80-120
Chromium ug/L 496500 99 80-120
Cobalt ug/L 478500 96 80-120
Copper ug/L 487500 97 80-120
Lead ug/L 470500 94 80-120
Nickel ug/L 481500 96 80-120
Selenium ug/L 467500 93 80-120
Silver ug/L 239250 96 80-120
Vanadium ug/L 482500 96 80-120
Zinc ug/L 472500 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-12596 2 20500ND489 478
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 97 75-12595 2 20500ND483 473
Barium ug/L 500 96 75-12595 1 205007.2 488 481
Beryllium ug/L 500 97 75-12595 1 20500ND483 477
Cadmium ug/L 500 96 75-12594 3 20500ND482 470
Chromium ug/L 500 98 75-12595 3 20500ND488 476
Cobalt ug/L 500 96 75-12593 2 20500ND478 466
Copper ug/L 500 98 75-12595 2 20500ND488 477
Lead ug/L 500 93 75-12591 2 20500ND467 457
Nickel ug/L 500 96 75-12593 3 20500ND478 466
Selenium ug/L 500 94 75-12592 2 20500ND471 462
Silver ug/L 250 96 75-12593 3 20250ND240 234
Vanadium ug/L 500 99 75-12595 3 20500ND493 476
Zinc ug/L 500 96 75-12594 3 20500ND482 470
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349553
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939173
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 5.0 03/03/17 06:243.9
Arsenic ug/L ND 10.0 03/03/17 06:245.0
Barium ug/L ND 5.0 03/03/17 06:242.5
Beryllium ug/L ND 1.0 03/03/17 06:240.50
Cadmium ug/L ND 1.0 03/03/17 06:240.50
Chromium ug/L ND 5.0 03/03/17 06:242.5
Cobalt ug/L ND 5.0 03/03/17 06:242.5
Copper ug/L ND 5.0 03/03/17 06:242.5
Lead ug/L ND 5.0 03/03/17 06:242.5
Nickel ug/L ND 5.0 03/03/17 06:242.5
Selenium ug/L ND 10.0 03/03/17 06:245.0
Silver ug/L ND 5.0 03/03/17 06:242.5
Vanadium ug/L ND 5.0 03/03/17 06:242.5
Zinc ug/L ND 10.0 03/03/17 06:275.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939174LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 482500 96 80-120
Arsenic ug/L 461500 92 80-120
Barium ug/L 461500 92 80-120
Beryllium ug/L 475500 95 80-120
Cadmium ug/L 464500 93 80-120
Chromium ug/L 466500 93 80-120
Cobalt ug/L 467500 93 80-120
Copper ug/L 485500 97 80-120
Lead ug/L 460500 92 80-120
Nickel ug/L 460500 92 80-120
Selenium ug/L 463500 93 80-120
Silver ug/L 244250 97 80-120
Vanadium ug/L 472500 94 80-120
Zinc ug/L 460500 92 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12598 3 20500ND480 492
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939175MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92331034001
1939176
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Arsenic ug/L 500 92 75-12594 2 20500ND459 469
Barium ug/L 500 91 75-12593 2 20500ND456 465
Beryllium ug/L 500 94 75-12596 2 20500ND469 480
Cadmium ug/L 500 92 75-12594 2 20500ND462 469
Chromium ug/L 500 93 75-12595 2 20500ND466 474
Cobalt ug/L 500 93 75-12595 2 20500ND466 475
Copper ug/L 500 97 75-12598 1 20500ND487 491
Lead ug/L 500 91 75-12594 2 20500ND457 468
Nickel ug/L 500 92 75-12593 2 20500ND458 467
Selenium ug/L 500 92 75-12594 2 20500ND462 471
Silver ug/L 250 97 75-12598 2 20250ND242 246
Vanadium ug/L 500 95 75-12596 1 20500ND475 482
Zinc ug/L 500 91 75-12593 2 20500ND456 465
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349257
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937708
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 18:000.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937709LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.7100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937710MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330674021
1937711
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 97 75-12595 2 20100ND97.5 95.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349668
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939942
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 0.10 02/24/17 20:120.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939943LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 94.6100 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939980MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330519013
1939981
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 90 75-12595 6 201000.034J 90.2 95.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349193
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330518001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/21/17 11:120.33
1,1,1-Trichloroethane ug/L ND 1.0 02/21/17 11:120.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/21/17 11:120.40
1,1,2-Trichloroethane ug/L ND 1.0 02/21/17 11:120.29
1,1-Dichloroethane ug/L ND 5.0 02/21/17 11:120.32
1,1-Dichloroethene ug/L ND 5.0 02/21/17 11:120.56
1,2,3-Trichloropropane ug/L ND 1.0 02/21/17 11:120.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/21/17 11:122.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/21/17 11:120.27
1,2-Dichlorobenzene ug/L ND 5.0 02/21/17 11:120.30
1,2-Dichloroethane ug/L ND 1.0 02/21/17 11:120.24
1,2-Dichloropropane ug/L ND 1.0 02/21/17 11:120.27
1,4-Dichlorobenzene ug/L ND 1.0 02/21/17 11:120.33
2-Butanone (MEK)ug/L ND 100 02/21/17 11:120.96
2-Hexanone ug/L ND 50.0 02/21/17 11:120.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/21/17 11:120.33
Acetone ug/L ND 100 02/21/17 11:1210.0
Acrylonitrile ug/L ND 200 02/21/17 11:121.9
Benzene ug/L ND 1.0 02/21/17 11:120.25
Bromochloromethane ug/L ND 3.0 02/21/17 11:120.17
Bromodichloromethane ug/L ND 1.0 02/21/17 11:120.18
Bromoform ug/L ND 3.0 02/21/17 11:120.26
Bromomethane ug/L ND 10.0 02/21/17 11:120.29
Carbon disulfide ug/L ND 100 02/21/17 11:121.2
Carbon tetrachloride ug/L ND 1.0 02/21/17 11:120.25
Chlorobenzene ug/L ND 3.0 02/21/17 11:120.23
Chloroethane ug/L ND 10.0 02/21/17 11:120.54
Chloroform ug/L ND 5.0 02/21/17 11:120.14
Chloromethane ug/L ND 1.0 02/21/17 11:120.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.13
Dibromochloromethane ug/L ND 3.0 02/21/17 11:120.21
Dibromomethane ug/L ND 10.0 02/21/17 11:120.21
Ethylbenzene ug/L ND 1.0 02/21/17 11:120.30
Iodomethane ug/L ND 10.0 02/21/17 11:120.32
Methylene Chloride ug/L ND 1.0 02/21/17 11:120.97
Styrene ug/L ND 1.0 02/21/17 11:120.26
Tetrachloroethene ug/L ND 1.0 02/21/17 11:120.46
Tetrahydrofuran ug/L ND 10.0 02/21/17 11:123.1
Toluene ug/L ND 1.0 02/21/17 11:120.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
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Page 15 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330518001
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/21/17 11:121.0
Trichloroethene ug/L ND 1.0 02/21/17 11:120.47
Trichlorofluoromethane ug/L ND 1.0 02/21/17 11:120.20
Vinyl acetate ug/L ND 50.0 02/21/17 11:120.35
Vinyl chloride ug/L ND 1.0 02/21/17 11:120.62
Xylene (Total)ug/L ND 5.0 02/21/17 11:120.66
1,2-Dichloroethane-d4 (S)%108 70-130 02/21/17 11:12
4-Bromofluorobenzene (S)%99 70-130 02/21/17 11:12
Toluene-d8 (S)%113 70-130 02/21/17 11:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.250 98 80-125
1,1,1-Trichloroethane ug/L 46.050 92 71-129
1,1,2,2-Tetrachloroethane ug/L 50.250 100 79-124
1,1,2-Trichloroethane ug/L 54.150 108 85-125
1,1-Dichloroethane ug/L 48.650 97 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,2,3-Trichloropropane ug/L 53.850 108 75-130
1,2-Dibromo-3-chloropropane ug/L 49.450 99 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 51.950 104 80-133
1,2-Dichloroethane ug/L 43.650 87 67-128
1,2-Dichloropropane ug/L 51.950 104 75-132
1,4-Dichlorobenzene ug/L 48.950 98 78-130
2-Butanone (MEK)ug/L 90.1J100 90 61-144
2-Hexanone ug/L 89.6100 90 68-143
4-Methyl-2-pentanone (MIBK)ug/L 87.7J100 88 72-135
Acetone ug/L 86.3J100 86 48-146
Acrylonitrile ug/L 219250 88 40-160
Benzene ug/L 52.050 104 80-125
Bromochloromethane ug/L 51.250 102 71-125
Bromodichloromethane ug/L 49.750 99 78-124
Bromoform ug/L 45.050 90 71-128
Bromomethane ug/L 52.150 104 40-160
Carbon disulfide ug/L 49.7J50 99 50-160
Carbon tetrachloride ug/L 49.350 99 69-131
Chlorobenzene ug/L 51.850 104 81-122
Chloroethane ug/L 57.950 116 39-148
Chloroform ug/L 49.650 99 73-127
Chloromethane ug/L 62.650 125 44-146
cis-1,2-Dichloroethene ug/L 50.750 101 74-124
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 54.750 109 72-132
Dibromochloromethane ug/L 49.050 98 78-125
Dibromomethane ug/L 47.950 96 82-120
Ethylbenzene ug/L 50.750 101 79-121
Iodomethane ug/L 113100 113 39-154
Methylene Chloride ug/L 47.050 94 64-133
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.250 102 78-122
Tetrahydrofuran ug/L 465500 93 69-148
Toluene ug/L 53.050 106 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 54.150 108 69-141
trans-1,4-Dichloro-2-butene ug/L 51.9J50 104 40-160
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 55.850 112 53-137
Vinyl acetate ug/L 97.8100 98 40-160
Vinyl chloride ug/L 43.750 87 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 87 70-13093 7 3020ND17.4 18.6
1,1,1-Trichloroethane ug/L 20 124 70-130122 1 3020ND24.7 24.5
1,1,2,2-Tetrachloroethane ug/L 20 100 70-130103 3 3020ND20.0 20.6
1,1,2-Trichloroethane ug/L 20 105 70-130111 6 3020ND21.0 22.3
1,1-Dichloroethane ug/L M12016770-130157 6 3020ND33.6 31.8
1,1-Dichloroethene ug/L M12016870-166154 9 3020ND33.7 30.8
1,2,3-Trichloropropane ug/L 20 96 70-130104 9 3020ND19.2 20.9
1,2-Dibromo-3-
chloropropane ug/L 20 86 70-13096 11 3020ND17.1 19.2
1,2-Dibromoethane (EDB) ug/L 20 90 70-13099 10 3020ND17.9 19.8
1,2-Dichlorobenzene ug/L 20 105 70-130105 1 3020ND21.1 21.0
1,2-Dichloroethane ug/L 20 122 70-130123 1 3020ND24.4 24.7
1,2-Dichloropropane ug/L 20 113 70-130117 3 3020ND22.6 23.3
1,4-Dichlorobenzene ug/L 20 109 70-130104 5 3020ND22.2 21.1
2-Butanone (MEK)ug/L 40 85 70-13097 13 3040ND34.2J 38.9J
2-Hexanone ug/L 40 91 70-130106 15 3040ND36.2J 42.2J
4-Methyl-2-pentanone
(MIBK)ug/L 40 95 70-130112 16 3040ND38.1J 44.7J
Acetone ug/L 40 82 70-13095 15 3040ND32.9J 38.2J
Acrylonitrile ug/L 100 101 70-130118 15 30100ND101J 118J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 17 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 120 70-148121 1 30200.44J 24.4 24.6
Bromochloromethane ug/L M12013670-130132 4 3020ND27.3 26.3
Bromodichloromethane ug/L 20 116 70-130115 1 3020ND23.1 23.0
Bromoform ug/L 20 78 70-13087 11 3020ND15.5 17.4
Bromomethane ug/L M12014070-130134 4 3020ND27.9 26.8
Carbon disulfide ug/L M12016070-130157 1 3020ND31.9J 31.5J
Carbon tetrachloride ug/L 20 113 70-130111 2 3020ND22.7 22.2
Chlorobenzene ug/L 20 113 70-146115 2 3020ND22.6 23.0
Chloroethane ug/L M12020570-130202 1 30200.69J 41.6 41.1
Chloroform ug/L M12013970-130132 5 3020ND27.8 26.4
Chloromethane ug/L M12015870-130149 6 3020ND31.6 29.7
cis-1,2-Dichloroethene ug/L M12016070-130160 0 3020ND32.0 32.0
cis-1,3-Dichloropropene ug/L 20 105 70-130109 3 3020ND21.1 21.7
Dibromochloromethane ug/L 20 81 70-13089 9 3020ND16.2 17.7
Dibromomethane ug/L 20 110 70-130113 3 3020ND21.9 22.6
Ethylbenzene ug/L 20 117 70-130118 0 3020ND23.4 23.5
Iodomethane ug/L M14016170-130180 11 3040ND64.2 72.0
Methylene Chloride ug/L M12015770-130150 5 3020ND31.3 29.9
Styrene ug/L 20 116 70-130118 2 3020ND23.1 23.7
Tetrachloroethene ug/L 20 97 70-130106 9 3020ND19.4 21.3
Tetrahydrofuran ug/L 200 94 70-130115 20 30200ND188 231
Toluene ug/L 20 133 70-155131 1 3020ND26.6 26.2
trans-1,2-Dichloroethene ug/L M12014370-130140 2 3020ND28.6 27.9
trans-1,3-Dichloropropene ug/L 20 102 70-130108 6 3020ND20.4 21.7
trans-1,4-Dichloro-2-butene ug/L M1206770-13087 26 3020ND13.3J 17.4J
Trichloroethene ug/L 20 105 69-151107 2 3020ND21.0 21.5
Trichlorofluoromethane ug/L M12020070-130189 5 3020ND39.9 37.8
Vinyl acetate ug/L 40 83 70-13090 8 3040ND33.2J 36.0J
Vinyl chloride ug/L M12015870-130141 11 3020ND31.5 28.3
1,2-Dichloroethane-d4 (S)%115 70-130117
4-Bromofluorobenzene (S) %99 70-130103
Toluene-d8 (S)%107 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 18 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
350035
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330518002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941762
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/28/17 02:020.33
1,1,1-Trichloroethane ug/L ND 1.0 02/28/17 02:020.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/28/17 02:020.40
1,1,2-Trichloroethane ug/L ND 1.0 02/28/17 02:020.29
1,1-Dichloroethane ug/L ND 5.0 02/28/17 02:020.32
1,1-Dichloroethene ug/L ND 5.0 02/28/17 02:020.56
1,2,3-Trichloropropane ug/L ND 1.0 02/28/17 02:020.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/28/17 02:022.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/28/17 02:020.27
1,2-Dichlorobenzene ug/L ND 5.0 02/28/17 02:020.30
1,2-Dichloroethane ug/L ND 1.0 02/28/17 02:020.24
1,2-Dichloropropane ug/L ND 1.0 02/28/17 02:020.27
1,4-Dichlorobenzene ug/L ND 1.0 02/28/17 02:020.33
2-Butanone (MEK)ug/L ND 100 02/28/17 02:020.96
2-Hexanone ug/L ND 50.0 02/28/17 02:020.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/28/17 02:020.33
Acetone ug/L ND 100 02/28/17 02:0210.0
Acrylonitrile ug/L ND 200 02/28/17 02:021.9
Benzene ug/L ND 1.0 02/28/17 02:020.25
Bromochloromethane ug/L ND 3.0 02/28/17 02:020.17
Bromodichloromethane ug/L ND 1.0 02/28/17 02:020.18
Bromoform ug/L ND 3.0 02/28/17 02:020.26
Bromomethane ug/L ND 10.0 02/28/17 02:020.29
Carbon disulfide ug/L ND 100 02/28/17 02:021.2
Carbon tetrachloride ug/L ND 1.0 02/28/17 02:020.25
Chlorobenzene ug/L ND 3.0 02/28/17 02:020.23
Chloroethane ug/L ND 10.0 02/28/17 02:020.54
Chloroform ug/L ND 5.0 02/28/17 02:020.14
Chloromethane ug/L ND 1.0 02/28/17 02:020.11
cis-1,2-Dichloroethene ug/L ND 5.0 02/28/17 02:020.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/28/17 02:020.13
Dibromochloromethane ug/L ND 3.0 02/28/17 02:020.21
Dibromomethane ug/L ND 10.0 02/28/17 02:020.21
Ethylbenzene ug/L ND 1.0 02/28/17 02:020.30
Iodomethane ug/L ND 10.0 02/28/17 02:020.32
Methylene Chloride ug/L ND 1.0 02/28/17 02:020.97
Styrene ug/L ND 1.0 02/28/17 02:020.26
Tetrachloroethene ug/L ND 1.0 02/28/17 02:020.46
Tetrahydrofuran ug/L ND 10.0 02/28/17 02:023.1
Toluene ug/L ND 1.0 02/28/17 02:020.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/28/17 02:020.49
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1941762
Associated Lab Samples:92330518002
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 02/28/17 02:020.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/28/17 02:021.0
Trichloroethene ug/L ND 1.0 02/28/17 02:020.47
Trichlorofluoromethane ug/L ND 1.0 02/28/17 02:020.20
Vinyl acetate ug/L ND 50.0 02/28/17 02:020.35
Vinyl chloride ug/L ND 1.0 02/28/17 02:020.62
Xylene (Total)ug/L ND 5.0 02/28/17 02:020.66
1,2-Dichloroethane-d4 (S)%96 70-130 02/28/17 02:02
4-Bromofluorobenzene (S)%94 70-130 02/28/17 02:02
Toluene-d8 (S)%92 70-130 02/28/17 02:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941763LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.550 97 80-125
1,1,1-Trichloroethane ug/L 46.150 92 71-129
1,1,2,2-Tetrachloroethane ug/L 47.550 95 79-124
1,1,2-Trichloroethane ug/L 48.450 97 85-125
1,1-Dichloroethane ug/L 45.350 91 73-126
1,1-Dichloroethene ug/L 47.550 95 66-135
1,2,3-Trichloropropane ug/L 44.950 90 75-130
1,2-Dibromo-3-chloropropane ug/L 46.550 93 71-133
1,2-Dibromoethane (EDB)ug/L 47.650 95 83-124
1,2-Dichlorobenzene ug/L 49.050 98 80-133
1,2-Dichloroethane ug/L 44.050 88 67-128
1,2-Dichloropropane ug/L 47.150 94 75-132
1,4-Dichlorobenzene ug/L 46.650 93 78-130
2-Butanone (MEK)ug/L 98.4J100 98 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 97.2J100 97 72-135
Acetone ug/L 101100 101 48-146
Acrylonitrile ug/L 247250 99 40-160
Benzene ug/L 49.250 98 80-125
Bromochloromethane ug/L 47.850 96 71-125
Bromodichloromethane ug/L 50.250 100 78-124
Bromoform ug/L 46.650 93 71-128
Bromomethane ug/L 47.350 95 40-160
Carbon disulfide ug/L 44.0J50 88 50-160
Carbon tetrachloride ug/L 47.350 95 69-131
Chlorobenzene ug/L 49.450 99 81-122
Chloroethane ug/L 50.550 101 39-148
Chloroform ug/L 45.250 90 73-127
Chloromethane ug/L 48.250 96 44-146
cis-1,2-Dichloroethene ug/L 45.950 92 74-124
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1941763LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 47.150 94 72-132
Dibromochloromethane ug/L 50.150 100 78-125
Dibromomethane ug/L 47.950 96 82-120
Ethylbenzene ug/L 47.350 95 79-121
Iodomethane ug/L 99.6100 100 39-154
Methylene Chloride ug/L 47.850 96 64-133
Styrene ug/L 48.450 97 84-126
Tetrachloroethene ug/L 42.550 85 78-122
Tetrahydrofuran ug/L 489500 98 69-148
Toluene ug/L 46.350 93 80-121
trans-1,2-Dichloroethene ug/L 46.550 93 71-127
trans-1,3-Dichloropropene ug/L 48.250 96 69-141
trans-1,4-Dichloro-2-butene ug/L 40.6J50 81 40-160
Trichloroethene ug/L 48.650 97 78-122
Trichlorofluoromethane ug/L 49.850 100 53-137
Vinyl acetate ug/L 100100 100 40-160
Vinyl chloride ug/L 39.950 80 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%94 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%95 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1941764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330712012
1941765
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 103 70-130105 2 3020ND20.7 21.0
1,1,1-Trichloroethane ug/L 20 111 70-130113 1 3020ND22.6 22.9
1,1,2,2-Tetrachloroethane ug/L 20 103 70-130102 1 3020ND20.5 20.4
1,1,2-Trichloroethane ug/L 20 100 70-130107 7 3020ND20.0 21.4
1,1-Dichloroethane ug/L 20 102 70-130109 6 30200.62J 21.1 22.5
1,1-Dichloroethene ug/L 20 115 70-166115 0 30200.56J 23.6 23.5
1,2,3-Trichloropropane ug/L 20 99 70-13099 0 3020ND19.8 19.8
1,2-Dibromo-3-
chloropropane ug/L 20 100 70-13097 3 3020ND19.9 19.4
1,2-Dibromoethane (EDB) ug/L 20 101 70-130101 1 3020ND20.1 20.2
1,2-Dichlorobenzene ug/L 20 104 70-130107 3 3020ND20.7 21.3
1,2-Dichloroethane ug/L 20 98 70-130102 4 3020ND19.8 20.7
1,2-Dichloropropane ug/L 20 102 70-130107 5 3020ND20.4 21.4
1,4-Dichlorobenzene ug/L 20 101 70-130105 4 3020ND20.1 21.0
2-Butanone (MEK)ug/L 40 106 70-130106 1 30401.8J 44.3J 44.1J
2-Hexanone ug/L 40 108 70-130105 2 3040ND43.3J 42.4J
4-Methyl-2-pentanone
(MIBK)ug/L 40 105 70-130110 4 3040ND42.2J 43.8J
Acetone ug/L 40 106 70-130107 1 3040ND50.3J 50.6J
Acrylonitrile ug/L 100 111 70-130110 1 30100ND111J 110J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 30
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1941764MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330712012
1941765
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 107 70-148114 6 3020ND21.4 22.8
Bromochloromethane ug/L 20 101 70-130105 4 3020ND20.2 21.1
Bromodichloromethane ug/L 20 104 70-130112 8 3020ND20.8 22.4
Bromoform ug/L 20 92 70-13095 3 3020ND18.4 19.0
Bromomethane ug/L 20 99 70-130106 6 3020ND19.8 21.1
Carbon disulfide ug/L 20 100 70-130105 5 3020ND20.0J 21.1J
Carbon tetrachloride ug/L 20 110 70-130111 1 3020ND21.9 22.2
Chlorobenzene ug/L 20 110 70-146111 1 3020ND21.9 22.2
Chloroethane ug/L 20 117 70-130120 3 3020ND23.5 24.1
Chloroform ug/L 20 104 70-130107 3 3020ND20.7 21.3
Chloromethane ug/L 20 116 70-130114 1 30200.26J 23.4 23.1
cis-1,2-Dichloroethene ug/L 20 90 70-130109 6 302040.7 58.6 62.5
cis-1,3-Dichloropropene ug/L 20 97 70-130105 8 3020ND19.5 21.1
Dibromochloromethane ug/L 20 103 70-130103 1 3020ND20.6 20.7
Dibromomethane ug/L 20 103 70-130109 5 3020ND20.6 21.7
Ethylbenzene ug/L 20 109 70-130111 2 3020ND21.8 22.2
Iodomethane ug/L 40 104 70-130119 13 3040ND41.8 47.7
Methylene Chloride ug/L 20 104 70-130109 5 3020ND20.8 21.8
Styrene ug/L 20 104 70-130107 3 3020ND20.7 21.4
Tetrachloroethene ug/L 20 108 70-130102 6 3020ND21.8 20.6
Tetrahydrofuran ug/L 200 110 70-130108 1 30200ND219 217
Toluene ug/L 20 105 70-155106 1 3020ND21.0 21.3
trans-1,2-Dichloroethene ug/L 20 110 70-130112 3 3020ND22.1 22.7
trans-1,3-Dichloropropene ug/L 20 96 70-130101 5 3020ND19.1 20.2
trans-1,4-Dichloro-2-butene ug/L 20 83 70-13083 0 3020ND16.6J 16.7J
Trichloroethene ug/L 20 89 69-15199 3 302039.1 56.9 58.8
Trichlorofluoromethane ug/L M12013170-130121 8 3020ND26.2 24.3
Vinyl acetate ug/L 40 89 70-13095 7 3040ND35.7J 38.2J
Vinyl chloride ug/L 20 99 70-130100 1 3020ND19.8 20.0
1,2-Dichloroethane-d4 (S)%97 70-130101
4-Bromofluorobenzene (S) %97 70-13097
Toluene-d8 (S)%99 70-13095
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 30
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 30
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330518
Wayne MSWLF-SWs
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330518001 348994 349091SW-1 EPA 3010A EPA 6010
92330518002 349553 349687SW-6 EPA 3010A EPA 6010
92330518001 349257 349497SW-1 EPA 3010A EPA 6020B
92330518002 349668 349712SW-6 EPA 3010A EPA 6020B
92330518001 349193SW-1 EPA 8260
92330518002 350035SW-6 EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/03/2017 02:35 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 30
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Appendix B
Field Sampling Parameter Data Sheet(s)