3902_GranvilleCountyLandfill_MSWLF.pdf

PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

BUTNER LANDFILL
PERMIT NO. 39-02

SECOND SEMIANNUAL
WATER QUALITY MONITORING REPORT
OF 2015

DECEMBER 2015

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 660.1601.12

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Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 December 2015
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Second Semiannual Water Quality Monitoring Report of 2015
Butner Landfill, Permit No. 39-02
Granville County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ...................................................................................................................1 
1.2 Site Geology.........................................................................................................................1 
1.3 Groundwater Monitoring History ........................................................................................1 
1.4 Regulatory Status .................................................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................2 
2.1 Groundwater Monitoring Program ......................................................................................2 
2.2 Surface Water Monitoring Program .....................................................................................3 
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015 ............................................3 
3.1 Field Work ...........................................................................................................................3 
3.2 Laboratory Analysis and JOYCE Quality Control ..............................................................4 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES ...................................5 
4.1 Analytical Results for Groundwater and Comparisons to Standards ...................................5 
4.1.1 Inorganic Analyses.................................................................................................... 5 
4.1.2 Organic Analyses ...................................................................................................... 5 
4.2 Statistical Analyses ..............................................................................................................5 
4.2.1 Statistical Methods .................................................................................................... 5 
4.2.2 Results of Statistical Analyses .................................................................................. 6 
4.3 Analytical Results for Surface Water and Comparisons to Standards .................................6 
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................6 
6.0 CORRECTIVE ACTION EVALUATION .....................................................................7 
6.1 Monitored Natural Attenuation Parameters .........................................................................7 
6.2 Phytoremediation .................................................................................................................8 
6.3 Evaluation of Plume Stability and Trends ...........................................................................8 
7.0 CONCLUSIONS ................................................................................................................8 
8.0 REFERENCES ...................................................................................................................9 
9.0 ACRONYMS ......................................................................................................................9 

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TABLE OF CONTENTS
(Continued)

Tables
Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data Table 3 Hydraulic Gradients and Groundwater Flow Velocities
Table 4 Quantified Detections of Groundwater Constituents (August 2015)
Table 5 Exceedances of Groundwater Standards (August 2015) Table 6 Field Parameters (August 2015)
Table 7 Monitored Natural Attenuation Parameters

Chart Chart 1 Benzene Concentrations vs. Time

Figure
Figure 1 Site Location Map

Drawing
Drawing 1 Groundwater Potentiometric Surface Map (August 2015)

Appendices
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater
Appendix D Historical Constituents in Surface Water
Appendix E Statistical Analyses Worksheets & Summary

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Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 December 2015
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Second Semiannual Water Quality Monitoring Report of 2015
Butner Landfill, Permit No. 39-02

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route
1004 near the town of Butner, in Granville County, North Carolina (Figure No. 1). The Butner
facility started receiving waste prior to May 1973. Permit Number 39-02, was issued by the
State of North Carolina on March 3, 1982. The facility stopped receiving waste in August 1998.
A small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.

In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the
Butner Landfill entered an Assessment Monitoring Program in December of 1997 as a result of
detections of volatile organic compounds and pesticide above 15A-NCAC-2L (NC-2L)
Groundwater Standards. An Assessment of Corrective Measures (ACM) was initiated in 2003,
and then suspended by North Carolina Department of Environment and Natural Resources
(DENR) [now the Department of Environmental Quality (NCDEQ)] since there had been no
more NC-2L exceedances. The Nature and Extent Study (NES) and ACM recommenced in 2007
when apparent volatile organic compound (VOC) exceedances of the NC-2L Standards began to
appear; however, they were again suspended when it was determined that the apparent
exceedances were not statistically significant increases (SSIs) above background. An ACM was
reinitiated after an exceedance of benzene in MW-2R in December 2012, and was submitted to
DENR in May 2013. Approval of the ACM was granted in a letter from DENR dated June 27,
2013. A Corrective Action Plan (CAP) was submitted to DENR on May 23, 2014, and was
approved by DENR on June 18, 2014.

1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the
area consists of rolling hills that support farmland and forest. The majority of the landfill area is
underlain by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into
greenish grey foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford
Formation (conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina
Slate Belt felsic volcanic rocks. There is no exposure of the Sanford Formation at the site;
however, float material consisting of grey, coarse-grained sandstone with quartz pebbles was
observed. Diabase dikes have also been observed in the vicinity of the site. Geologic
descriptions were taken from GAI Consultants’ Groundwater and Surface Water Monitoring
System report (GAI, 1994).

1.3 Groundwater Monitoring History
 April 1994 – Current Monitoring Well Network installed.
 Dec. 1997 - The facility entered Assessment Monitoring.
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 June 2003 – NC-2L exceedances for heptachlor in MW-2R and MW-3R initiated an
ACM.
 Dec. 2004 & June 2005 – There were no NC-2L exceedances, so DENR agreed to put
the ACM on hold pending future monitoring results. At first, DENR said the facility
needed deed restrictions on adjoining property owned by the County, but this was
apparently based on false information (the County did not own the property) so the
requirement for deed restrictions was dropped.
 Dec. 2006 – Benzene in MW-2R and 1,4-dichlorobenzene in MW-2R and MW-3R
detected above NC-2L standards.
 June 14, 2007 - Granville County and JOYCE met with DENR to discuss a strategy for
performing a Nature and Extent Study (NES) and an ACM.
 Nov. 2007 – Nature & Extent well NES-1 was installed downgradient of MW-2R &
MW-3R.
 Dec. 2007 – NES & MNA sampling event on selected wells.
 Dec. 2008 – Organic results above the NC-2L standards were determined to not represent
statistically significant exceedances, so corrective action and ACM were suspended with
the concurrence of the DENR and in accordance with the NCSWMR.
 Dec. 2012 – Benzene detections above the NC-2L in MW-2R initiated the ACM.
 May 17, 2013 – ACM addressing the benzene detections above the NC 2L in MW-2R
submitted to DENR.
 June 27, 2013 – ACM approved by DENR.
 September 3, 2013 – Public meeting and selection of remedy.
 May 23, 2014 – CAP submitted to DENR.
 June 18, 2014 – CAP approved by DENR.

1.4 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance
with North Carolina Solid Waste Management Regulations (NCSWMR) §.1634. The site is
currently in a Corrective Action Monitoring Program. Groundwater samples are collected
semiannually and analyzed in accordance with the approved Corrective Action Plan. Surface
water samples are collected and sampled for Appendix I constituents during each sampling
event.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six active groundwater monitoring wells comprise the monitoring network at the Butner
Landfill. The current compliance network consists of the following monitoring wells: MW-1R
(facility background well), MW-2R, MW-3R, MW-4, MW-5, and MW-6. An additional well,
NES-1, was installed as part of a Nature and Extent Study on November 14, 2007. The following
table summarizes the monitoring network and required analytical parameters.

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Groundwater Monitoring Network
Monitoring
Well
Date
Installed Classification Monitoring
Program TD (ft)
Lithology of
Screened
Interval
1st SA Event
Analyses
2nd SA Event
Analyses
MW-1R 4/21/94 Background Assessment/
CAMP 45.1 Saprolite App. II, MNA App. I + Det.,
MNA
MW-2R 4/12/94 Compliance/
Performance
Assessment/
CAMP 19.0 Saprolite App. II, MNA App. I + Det.,
MNA
MW-3R 4/14/94 Compliance/
Performance
Assessment/
CAMP 37.2 Bedrock App. II, MNA App. I + Det.,
MNA
MW-4 4/18/94 Compliance Detection 31.5 Bedrock App. I App. I
MW-5 4/18/94 Compliance Detection 23.4 Saprolite App. I App. I
MW-6 4/19/94 Compliance Detection 31.7 Saprolite/
Bedrock App. I App. I
NES-1 11/14/07 Nature &
Extent Sentinel 33.0 Saprolite/
Bedrock COCs, MNA COCs, MNA
App. I = NCSWMR Appendix I list of constituents. App. II = NCSWMR Appendix II list of constituents.
MNA = Monitoring Natural Attenuation parameters. COCs = Constituents of Concern
App. I + Det. = App. I list plus detected App. II constituents. CAMP = Corrective Action Monitoring Plan
Current Appendix II detected constituents: tin, gamma-BHC, heptachlor, 2,4-D, and
endrin aldehyde.
Current COC: Benzene.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, dissolved carbon dioxide, and ferrous iron.
MNA Laboratory Parameters: Dissolved hydrogen, volatile fatty acids, dissolved
methane, ethane, ethane, alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC).

2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994 at the
Butner Landfill. The points SW-1 and SW-2 are located respectively upstream and downstream
of the facility, along an unnamed tributary of Picture Creek. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2015
3.1 Field Work
On August 17, 2015, Joyce Engineering, (JOYCE) personnel visited the Butner Landfill to purge
and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1.

All monitoring wells were purged and sampled using new, disposable bailers. Measurements of
temperature, pH, turbidity and specific conductivity were recorded in a field log. Prior to
sampling, laboratory-supplied containers were prepared with the following information:

 Monitoring well number (completed by laboratory/field personnel),
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Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
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 Date and time of sample collection (completed by laboratory/field personnel),
 Initials of sampling personnel (completed by laboratory/field personnel),
 Project name and number (completed by the laboratory/field personnel),
 Chemical preservative (completed by the laboratory/field personnel); and
 Requested chemical analysis (completed by the laboratory/field personnel).

Groundwater samples from each monitoring well were collected directly from the bailers into the
provided laboratory containers, either immediately after purging or within 24 hours of the final
purge volume. Immediately after collection, the samples were placed in a laboratory provided
cooler and chilled on ice. Field Logs are provided in Appendix A.

Surface water points SW-1 and SW-2 were dry and were not sampled. Field Logs are included
in Appendix A.

3.2 Laboratory Analysis and JOYCE Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina, analyzed the August 2015,
groundwater and surface water samples under chain-of-custody control. The groundwater
samples from MW-1R, MW-2R, and MW-3R were analyzed for the NC Appendix II list of
constituents. The groundwater samples from MW-4, MW-5, and MW-6 were analyzed for the
NC Appendix I list of constituents. The sample from sentinel well NES-1 was analyzed for
Appendix I VOCs only. Samples from MW-1R, MW-2R, MW-3R, and NES-1 were also
analyzed for MNA parameters. The surface water samples were analyzed for NC Appendix I
constituents. The samples were received by the laboratory on August 18, 2015, in good
condition, properly preserved, at proper temperatures, and within analysis hold times.

In addition to samples collected for compliance monitoring at the Butner Landfill, JOYCE
personnel collected a Field Blank as part of the August 2015 sampling event. The Field Blank
was analyzed for the NC Appendix II constituents. Also, a Trip Blank that was prepared by the
laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip
Blank was analyzed for the Appendix II volatile organic compounds. The complete laboratory
analytical reports are included in Appendix B.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data for:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory
Control Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2l.0202 (NC 2L) Groundwater Standards or the
NCDEQ Solid Waste Section (SWS) Groundwater Water Protection Standards (GWPS);
and
 Detections that are above historical levels.

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The complete laboratory analytical reports and the chains of custody from the August 2015 event
are included in Appendix B. Historical analytical results for groundwater and surface water are
presented in Appendices C and D, respectively.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the
NCDEQ-SWS reporting limits (SWSL’s) in one or more wells during the August 2015 sampling
event: antimony, barium, cobalt, copper, and nickel. Table 4 summarizes all of the quantified
detections from the August 2015 event. These results are consistent with historical data.

Antimony in MW-2R and cobalt in MW-5 were detected above their respective GWPS;
however, not above the calculated background concentration (see section 4.2). Since the
antimony and cobalt detections were below the site specific calculated background values, there
were no exceedances of the GPS as defined by 15A NCAC 13B.1634.g. Exceedances of
groundwater standards from the August 2015 event are summarized in Table 5. The laboratory
analytical reports and the chains of custody are included in Appendix B. Complete historical
analytical results for inorganic constituents are included in Appendix C.

4.1.2 Organic Analyses
The following organic constituents were detected at quantified concentrations above the solid
waste section report limits (SWSL’s) in one or more wells during the August 2015 sampling
event: benzene, chlorobenzene, 1,4-dichlorobenzene, and methylene chloride. Table 4
summarizes all of the quantified detections from the August 2015 event. These results are
consistent with historical data.

Benzene was detected above the NC 2L standard and the GPS in MW-2R. Exceedances of
groundwater standards from the August 2015 event are summarized in Table 5. The benzene
exceedance in MW-2R has been addressed in the ACM, approved in June 2013, and the CAP,
approved in June 2014. No other organic constituents were detected above their GPS during the
August 2015 sampling event. The laboratory analytical reports and the chains of custody are
included in Appendix B. Historical analytical results for organic constituents are presented in
Appendix C.

4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up-gradient background well for the facility. Data
from MW-1R between September 1994 and August 2015 have been used to determine statistical
background concentrations for constituents detected at the facility.

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The background data were evaluated using the Shapiro-Wilk Test, Parametric Prediction Limits,
Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric Prediction Limits, and
Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison’s adjustment, tolerance interval, or prediction limits are used, as appropriate based on
the background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one-tailed tests. The data set was
evaluated to determine the appropriate procedure for calculation of the background value for
each parameter.

4.2.2 Results of Statistical Analyses
Antimony and cobalt were the only inorganic constituents detected in exceedance of their NC 2L
or GWPS during the August 2015 sampling event. The calculated background concentrations for
antimony and cobalt are proposed as the Groundwater Protection Standards specific to the site
per rule .1634(g.5) of the NCSWMR. Statistical analysis worksheets can be found in Appendix
E. The results of the August 2015 statistical background calculations are summarized in the
following table.

Constituent Data
Distribution
Statistical
Method used to
Establish
Background
Background
Concentration GWPS GPS GPS
Exceedances
Antimony 96% ND Upper Poisson
Prediction Limit 56 1 56 None
Cobalt 73% ND Nonparametric
Prediction Interval 130 1 130 None
GWPS = Solid Waste Section Groundwater Standard for constituents with no listed NC 2L.
GPS = Groundwater Protection Standard as defined in 15A NCAC .1634(g).
%ND = percentage of background data that is truncated (non-detect).
All concentrations are in µg/L (micrograms per liter).

4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were dry and no samples were collected during the August
2015 sampling event.

5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks
northeast of the landfill. Groundwater flow direction at deeper levels within the fractured
bedrock is controlled by fracture orientation. A groundwater surface contour map, developed
with static water level data obtained August 17, 2015, is presented as Drawing 1. The static
water elevations depict groundwater flow to the southeast.

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Depth to groundwater was measured in the compliance monitoring wells at the site prior to
purging. The groundwater elevations were calculated relative to the surveyed measuring point
(top of casing) for each monitoring well. The historical groundwater elevations are summarized
in Table 4. The groundwater elevation contours shown on Drawing 1 are based on data from the
August 2015 sampling event. Horizontal groundwater gradients along representative flow paths
were estimated from the August 2015 groundwater contours shown on Drawing 1 and are
summarized in Table 5. Horizontal gradients across the site ranged from 0.049 to 0.056 ft/ft,
with an average of approximately 0.051 ft/ft. This is consistent with previous estimates.

Linear groundwater flow velocities were computed using the modified Darcy equation:
V = Ki/ne
where V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.

The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from slug-
tests conducted in 1994 (GAI, 1994) was used in these calculations. The average effective
porosity (ne = 18%) based on 90% of reported total porosity for soils (GAI, 1994), and ne = 10%
for fractured bedrock were also used. Although the regolith and bedrock are hydraulically
connected, the effective porosity generally decreases with depth into the underlying fractured
bedrock. The modified Darcy equation makes the simplifying assumption of a homogeneous and
isotropic aquifer. The calculated linear groundwater velocities range from approximately 6.1 to
7.0 feet/year, and the average estimated linear groundwater flow velocity under the facility was
calculated at approximately 6.4 feet/year (see Table 3). Groundwater flow direction beneath the
landfill is predominantly to the south and southeast.

Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for
this site.

6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Wells MW-1R (background), MW-2R, MW-3R, and NES-1 were analyzed for the following
MNA parameters during the August 2015 sampling event:

MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, dissolved carbon dioxide, and ferrous iron.

MNA Laboratory Parameters: Dissolved hydrogen, volatile fatty acids, dissolved
methane, ethane, ethane, alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC).
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The current and historical MNA parameter data are presented in Table 7, and the laboratory
analytical report for the August 2015 sampling event is included in Appendix B. The August
2015 sampling event represents the fourth of four required baseline sampling events for the
MNA remedy. The MNA data will be evaluated and reported in the first Corrective Action
Evaluation Report (CAER) for the facility, which will be submitted concurrently with this report.

6.2 Phytoremediation
The second phytoremediation tree survey for the Butner Landfill was conduction in April 2015
and the results will be presented in the 2015 CAER. The CAP requires annual tree surveys, and
the next survey is scheduled for spring 2016.

6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006, possibly due to a higher quantitation limit and the fact that estimated detections
below the quantitation limit were not reported prior to December 2006. From December 2006 to
present, benzene in MW-2R has fluctuated between 1µg/L and 2 µg/L with no clear trend. From
December 2007 to present, benzene in MW-3R has fluctuated between 0.3 µg/L and 0.7 µg/L,
and benzene in MW 4 has fluctuated between non-detect and 0.4 µg/L.

The benzene concentrations from the August 2015 sampling event were slightly higher in all
three wells than the previous (March 2014) event; however, they are within the range of
historical fluctuations. Since there have been no detections of benzene in either the surface water
or sentinel well NES-1, there is no indication that the plume in migrating toward the property
boundary. The plume appears to be stable. The benzene plume will be discussed in more detail
in the 2015 CAER.

7.0 CONCLUSIONS
Antimony in MW-2R and cobalt in MW-5 were detected above their respective GWPS;
however, they were not above the calculated background concentrations. The County of
Granville requests that the background values for antimony and cobalt be considered the GPS at
the Butner Landfill per rule .1634(g.5) of the NCSWMR; in which case there was no
exceedances of the GPS for inorganic constituents from the August 2015 sampling event.

Benzene was detected above the NC-2L in MW-2R during the August 2015 sampling event. In
response to the historical benzene exceedances in MW-2R, Granville County submitted an ACM
on May 17, 2013, which was approved on June 27, 2013. A CAP was submitted on May 23,
2014 and approved on June 18, 2014. Review of MNA parameter data, plume stability, and
benzene trends indicate that the selected remedies of natural attenuation and phytoremediation
are adequately controlling the plume.

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The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. The next semiannual sampling event is scheduled
for the first quarter of 2016.

8.0 REFERENCES
GAI Consultants – NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System,
Granville County, Butner Landfill, NC Permit No. 39-02. June, 1994.

Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.

Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County,
Permit No. 39-02. May 2014.

Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN
Natural Attenuation Decision Support System User’s Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. EPA/600/R-96/087. August 1996.

Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN
Natural Attenuation Decision Support System, Version 1.4 Revisions. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. July 1997.

North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at
Solid Waste Management Facilities. March 2007.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AOC Area of Concern
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site-specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
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Second Semiannual Water Quality Monitoring Report of 2015 Joyce Engineering
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JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC-2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC-2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDENR/NCDEQ)
SWSL North Carolina Solid Waste Section Reporting Limits
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)

TABLES

Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Hydraulic Gradients and Groundwater Flow Velocities
Table 4 Quantified Detections of Groundwater Constituents (August 2015)
Table 5 Exceedances of Groundwater Standards (August 2015)
Table 6 Field Parameters (August 2015)
Table 7 Monitored Natural Attenuation Parameters

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DateDriller's Reg. #Comments
39
-
0
2

M
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1
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N
3
6
º

0
9
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5
5
.
4
9
"

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8
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5
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3
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.
80
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background well replacement
39
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0
2

M
W
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2
R

N
3
6
º

0
9
'

3
8
.
5
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97
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compliance well replacement
39
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0
2

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3
R

N
3
6
º

0
9
'

3
8
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5
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8
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compliance well replacement
39
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0
2

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4

N
3
6
º

0
9
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3
8
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9
3
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5
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39
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2

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0
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3
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39
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Joyce Engineering
TABLE 6: Field Parameters (August 2015)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW1R pH 5.12 s.u 8/18/2015
3902-MW1R Temperature 16.4 ºC 8/18/2015
3902-MW1R Conductivity 134 µS/cm 8/18/2015
3902-MW1R Turbidity 49.40 NTU 8/18/2015
3902-MW1R Dissolved Carbon Dioxide 30.0 mg/L 8/18/2015
3902-MW1R Dissolved Oxygen 4.95 mg/L 8/18/2015
3902-MW1R Ferrous Iron 0.0 mg/L 8/18/2015
3902-MW1R Oxidation Reduction Potential 134.7 mV 8/18/2015
3902-MW1R Static Water Level 45.80 ft 8/18/2015
3902-MW1R Well Depth 56.00 ft 8/18/2015
3902-MW2R pH 6.68 s.u 8/18/2015
3902-MW2R Temperature 17.8 ºC 8/18/2015
3902-MW2R Conductivity 1,630 µS/cm 8/18/2015
3902-MW2R Turbidity 24 NTU 8/18/2015
3902-MW2R Dissolved Carbon Dioxide 275 mg/L 8/18/2015
3902-MW2R Dissolved Oxygen 5.75 mg/L 8/18/2015
3902-MW2R Ferrous Iron 4.5 mg/L 8/18/2015
3902-MW2R Oxidation Reduction Potential -96.3 mV 8/18/2015
3902-MW2R Static Water Level 2.95 ft 8/18/2015
3902-MW2R Well Depth 18.85 ft 8/18/2015
3902-MW3R pH 6.48 s.u 8/18/2015
3902-MW3R Temperature 17.8 ºC 8/18/2015
3902-MW3R Conductivity 1,680 µS/cm 8/18/2015
3902-MW3R Turbidity 10.2 NTU 8/18/2015
3902-MW3R Dissolved Carbon Dioxide 125 mg/L 8/18/2015
3902-MW3R Dissolved Oxygen 1.30 mg/L 8/18/2015
3902-MW3R Ferrous Iron 1.0 mg/L 8/18/2015
3902-MW3R Oxidation Reduction Potential -68.8 mV 8/18/2015
3902-MW3R Static Water Level 3.15 ft 8/18/2015
3902-MW3R Well Depth 35.83 ft 8/18/2015
3902-MW4 pH 6.76 s.u 8/18/2015
3902-MW4 Temperature 17.3 ºC 8/18/2015
3902-MW4 Conductivity 1,244 µS/cm 8/18/2015
3902-MW4 Turbidity 22.6 NTU 8/18/2015
3902-MW4 Oxidation Reduction Potential -33.9 mV 8/18/2015
3902-MW4 Static Water Level 9.75 ft 8/18/2015
3902-MW4 Well Depth 31.43 ft 8/18/2015
3902-MW5 pH 7.03 s.u 8/18/2015
3902-MW5 Temperature 16.47 ºC 8/18/2015
3902-MW5 Conductivity 617 µS/cm 8/18/2015
3902-MW5 Turbidity 57.3 NTU 8/18/2015
3902-MW5 Dissolved Oxygen 3.79 s.u 8/18/2015
3902-MW5 Oxidation Reduction Potential -49.9 mV 8/18/2015
3902-MW5 Static Water Level 16.15 ft 8/18/2015
3902-MW5 Well Depth 23.52 ft 8/18/2015
Butner Landfill, Granville Co.
Permit No. 39-02 1 of 2
Joyce Engineering
TABLE 6: Field Parameters (August 2015)
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW6 pH 6.78 s.u 8/18/2015
3902-MW6 Temperature 16.64 ºC 8/18/2015
3902-MW6 Conductivity 534 µS/cm 8/18/2015
3902-MW6 Turbidity 21.6 NTU 8/18/2015
3902-MW6 Static Water Level 14.9 ft 8/18/2015
3902-MW6 Well Depth 32.63 ft 8/18/2015
3902-NES1 pH 4.94 s.u 8/18/2015
3902-NES1 Temperature 16.05 ºC 8/18/2015
3902-NES1 Conductivity 83 µS/cm 8/18/2015
3902-NES1 Turbidity 76.0 NTU 8/18/2015
3902-NES1 Dissolved Carbon Dioxide 60 mg/L 8/18/2015
3902-NES1 Dissolved Oxygen 1.77 mg/L 8/18/2015
3902-NES1 Ferrous Iron 0.0 mg/L 8/18/2015
3902-NES1 Oxidation Reduction Potential 182.8 mV 8/18/2015
3902-NES1 Static Water Level 19.6 ft 8/18/2015
3902-NES1 Well Depth 36.1 ft 8/18/2015
Units: ºC= degrees Centigrade
S.U.= Standard Units
µS/cm = micro-Seimens per centimeter
NTU = Nephelometric Turbidity Units
mV= milivolts
mg/L= miligrams per liter
Butner Landfill, Granville Co.
Permit No. 39-02 2 of 2
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Temperature 12/30/03 ºC - - 15.4 11.1 11.2 12.5 13.6 14.2 -
(FP)12/19/07 ºC - - 12.3 12.5 13.1 14.4 14.9 14.4 13.3
05/01/13 ºC - - 15.7 13.7 15.1 14.4 14.2 14.2 12.5
08/14/14 ºC - - 17.8 18.0 19.2 19.4 16.8 17.2 16.0
03/10/15 ºC - - 17.3 16.0 15.9 13.8 13.3 13.7 16.1
08/18/15 ºC - - 16.4 17.8 17.8 17.3 16.5 16.6 16.1
pH 12/30/03 SU - - 7.31 6.54 6.81 6.90 7.24 7.29 -
(FP)12/19/07 SU - - 6.89 6.90 7.07 6.87 7.39 6.67 7.64
05/01/13 SU - - 7.32 6.37 6.61 6.42 6.92 7.13 6.10
08/14/14 SU - - 5.84 6.36 6.96 6.79 7.00 6.48 5.59
03/10/15 SU - - 6.11 6.37 6.56 6.30 6.25 6.55 5.68
08/18/15 SU - - 5.12 6.68 6.48 6.76 7.03 6.78 4.94
Conductivity 12/19/07 µS/cm - - 96 1,964 1,591 1,245 -- 510
(FP)05/01/13 µS/cm - - 111 1,587 1,357 1,150 195 594 69.6
08/14/14 µS/cm - - 231 1,897 1,534 1,413 522 565 172.6
03/10/15 µS/cm - - 90 996 1,277 1,186 106 504 114
08/18/15 µS/cm - - 134 1,630 1,680 1,244 617 534 83
Redox Potential 12/30/03 mV - - 257.2 76.2 207.6 212.7 187.3 123.6 -
ORP 12/19/07 mV - - 146 45.0 142 134 -- 138
(FP)05/01/13 mV - - 111.7 -26.7 55.2 120.5 - - 227.1
08/14/14 mV - - 115.8 -37.2 86.9 - - - -
03/10/15 mV - - 87.0 0.8 56.3 - - - 96.7
08/18/15 mV - - 134.7 -96.3 -68.8 -33.9 -49.9 - 182.8
Dissolved Oxygen 12/30/03 mg/L - - 9.49 4.84 26.19 24.19 15.31 20.17 -
DO 12/19/07 mg/L - - - 1.88 1.44 3.21 - - 0.70
(FP)05/01/13 mg/L - - 4.40 1.37 1.79 4.65 -- 2.90
08/14/14 mg/L - - 4.44 3.26 2.48 --- 2.80
03/10/15 mg/L - - 3.84 1.47 1.80 --- 1.85
08/18/15 mg/L - - 4.95 5.75 1.30 - 3.79 - 1.77
Dissolved CO2 12/19/07 mg/L - - 25 365 175 295 -- 60
(FP)05/01/13 mg/L - - 30.0 245 125 225 -- 45
08/14/14 mg/L - - 60.0 390 185 --- 75
03/10/15 mg/L - - 50.0 110 75 --- 50
08/18/15 mg/L - - 30.0 275 125 --- 60
Fe, Ferrous (+2)12/30/03 mg/L - - ND 1.5 ND ND 0.22 ND -
(FP)12/19/07 mg/L - - ND 7.2 ND ND -- 0.2
05/01/13 mg/L - - 0.0 1.0 0.0 0.0 -- 0.0
08/14/14 mg/L - - 0.0 2.5 0 --- 0.0
03/10/15 mg/L - - 0.0 5.3 0 --- 0.0
08/18/15 mg/L - - 0.0 4.5 1 --- 0.0
Alkalinity (as CaCO3) 12/30/03 mg/L 9.00 10.0 37.0 800 690 640 68.0 350 -
12/19/07 mg/L - 5.00 39.0 763 726 619 -- 190
05/01/13 mg/L 1.00 5.00 43.4 757 660.0 645.0 -- 10.4
08/14/14 mg/L 1.00 5.00 41.1 784.0 661.0 --- 14.5
03/10/15 mg/L 1.00 5.00 38.0 744.0 653.0 --- 8.8
08/18/15 mg/L 1.00 5.00 37.8 772.0 664.0 --- 10.3
Chloride 12/30/03 mg/L 0.200 1.00 3.50 280 170 82.0 13.0 44.0 -
12/19/07 mg/L - 5.00 ND 13.1 297 89.1 -- 7.90
05/01/13 mg/L 0.5 1.00 3.54 258 180 123 -- 2.85
08/14/14 mg/L 0.5 1.00 5.53 264 144 --- 5.00
03/10/15 mg/L 0.5 1.00 3.80 266 194 --- 4.09
08/18/15 mg/L 0.5 1.00 4.69 267 178 --- 3.90
Downgradient
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 3
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Dissolved Hydrogen 05/01/13 nM 0.074 0.60 0.400 0.630 0.610 0.500 -- 0.470
08/14/14 nM 0.13 0.60 1.4 1.6 5.4 --- 1.4
03/10/15 nM 0.13 0.60 1.2 1.4 1.4 1.0 -- 1.4
08/18/15 nM 0.13 0.60 1.7 2.2 1.7 --- 1.5
Nitrate-N 12/30/03 mg/L 0.0200 0.0500 0.120 ND ND ND ND 0.13 -
12/19/07 mg/L - 0.100 ND ND ND ND -- 13.0
05/01/13 mg/L 0.001 10.0 0.163 ND ND ND -- 3.58
08/14/14 mg/L 0.001 10.0 0.115 J ND ND --- 2.02 J
03/10/15 mg/L 0.001 10.0 0.252 J ND ND --- 2.56 J
08/18/15 mg/L 0.001 10.0 .124 J ND ND --- 3.27 J
Sulfate 12/30/03 mg/L 0.0600 2.00 ND ND ND 2.60 9.60 9.00 -
12/19/07 mg/L - 5.00 ND ND ND ND -- 36.8
05/01/13 mg/L 1 250 ND ND ND 4.69 -- 10.7
08/14/14 mg/L 1 250 1.08 J 1.2 J ND --- 5.84 J
03/10/15 mg/L 1 250 1.52 J 1.13 J 1.52 J --- 7.04 J
08/18/15 mg/L 1 250 1.56 J 1.31 J 2.49 J --- 524 J
Sulfide 08/14/14 mg/L 0.05 1.00 ND ND ND --- ND
03/10/15 mg/L 0.05 1.00 ND ND ND --- ND
08/18/15 mg/L 0.05 1.00 ND ND ND --- 1.0
Total Organic Carbon 12/19/07 mg/L - 1.0 * 2.9 54.3 23.2 17.2 -- 7.20
05/01/13 mg/L 0.5 1.00 2.24 29.5 30.0 19.4 -- 5.74
08/14/14 mg/L 0.5 1.00 ND 229.00 25.5 --- 8.39
03/10/15 mg/L 0.5 1.00 .781J 34.8 9.5 --- 1.88
08/18/15 mg/L 0.5 1.00 0.917J 32.9 9.86 --- 27.80
Biochemical Oxygen Demand 08/14/14 mg/L 2.0 2.00 ND 83.4 2.49 ----
BOD 03/10/15 mg/L 2.0 2.00 2.55 10.6 ND --- ND
08/18/15 mg/L 2.0 2.00 2.22 11.8 2.0 --- 2.00
Chemical Oxygen Demand 08/14/14 mg/L 12.5 25.0 ND 132.0 ND --- 50.00
COD 03/10/15 mg/L 12.5 25.00 15.0J 235.0 96.0 --- ND
08/18/15 mg/L 12.5 25.00 25.00 110.0 756.0 --- 25.00
Dissolved Ethane 12/30/03 mg/L 0.0002 0.0010 ND ND ND ND ND ND -
12/19/07 mg/L - 20.0 ND ND ND ND -- ND
05/01/13 mg/L 0.0031 0.0062 ND ND ND ND -- ND
08/14/14 mg/L 0.0031 0.0062 ND ND 0.0036 J --- ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND --- ND
08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 --- 0.01
Dissolved Ethene 12/01/03 mg/L 0.0003 0.0010 ND ND ND ND ND ND -
12/19/07 mg/L - 20.0 ND ND ND ND -- ND
05/01/13 mg/L 0.0031 0.0062 ND ND 0.0017 ND -- ND
08/14/14 mg/L 0.0031 0.0062 ND ND ND --- ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND --- ND
08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 --- 0.01
Dissolved Methane 12/30/03 mg/L 0.0002 0.0010 ND 0.660 0.130 0.0099 0.0010 ND -
12/19/07 mg/L - 10.0 ND 0.116 0.186 ND -- ND
05/01/13 mg/L 0.0033 0.0066 ND 0.0379 0.100 0.0337 -- ND
08/14/14 mg/L 0.0033 0.0066 ND 1.2900 0.284 --- ND
03/10/15 mg/L 0.0033 0.0066 0.0072 0.9960 0.158 --- ND
08/18/15 mg/L 0.0033 0.0066 0.0027 2.16 0.316 --- 0.0013
Butner Landfill, Granville Co.
Permit No. 39-02 Page 2 of 3
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Pyruvic Acid 12/19/07 mg/L 2.50 ND 1.50 2.00 -- 1.20
05/01/13 mg/L 2 10 ND ND ND ND -- ND
08/14/14 mg/L 0.77 10 ND ND ND --- ND
03/10/15 mg/L 0.77 10 0.41J 0.41J 0.41J --- 0.41J
08/18/15 mg/L 0.77 10 ND ND ND --- ND
Lactic Acid 12/19/07 mg/L ND 5.40 11.9 3.10 -- ND
05/01/13 mg/L 2.3 25 ND ND ND ND -- ND
08/14/14 mg/L 2.5 25 4.2 J ND ND --- ND
03/10/15 mg/L 2.5 25 ND ND ND --- ND
08/18/15 mg/L 2.5 25 ND ND ND --- ND
Acetic Acid 12/19/07 mg/L ND ND ND ND -- ND
05/01/13 mg/L 1.8 5 ND ND ND ND -- ND
08/14/14 mg/L 0.81 5.0 ND ND ND --- ND
03/10/15 mg/L 0.81 5.0 ND ND ND --- ND
08/18/15 mg/L 0.81 5.0 ND ND 0.97 J --- ND
Propionic Acid 12/19/07 mg/L ND 63.7 38.3 12.8 -- ND
05/01/13 mg/L 1 5 ND ND ND ND -- ND
08/14/14 mg/L 0.66 5.0 ND ND ND --- ND
03/10/15 mg/L 0.66 5.0 ND ND ND --- ND
08/18/15 mg/L 0.66 5.0 ND ND ND --- ND
Butyric Acid 12/19/07 mg/L ND ND ND ND -- ND
05/01/13 mg/L 0.87 5 ND ND ND ND -- ND
08/14/14 mg/L 0.70 5.0 ND ND ND --- ND
03/10/15 mg/L 0.70 5.0 ND ND ND --- ND
08/18/15 mg/L 0.70 5.0 ND ND ND --- ND
Total Volatile Fatty Acids 12/19/07 mg/L 2.50 69.10 51.70 17.90 -- 1.20
(sum of above 5 acids) 05/01/13 mg/L ND ND ND --- ND
08/14/14 mg/L 4.2 J ND ND --- ND
03/10/15 mg/L ND ND ND --- ND
08/18/15 mg/L ND ND 0.97 J --- ND
NOTES:
DL = laboratory detection limit.mg/L = milligrams per liter ºC = degress Celcius
RL = laboratory reporting limit.mV = millivolt µS/cm = micro-Siemen per centimeter
ND = not detected above detection limit.SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL.nM = nano-Molar
- = not analyzed.
DL and QL for Alkalinity for Dec. 03 event was 1 and 2 respectively for wells MW-2R, -3R, and -4 due to different methods used by the labrotory.
* = RL for MW-1R - 1.0, MW-2R - 5.0, MW-3R - 5.0, MW-4 - 2.0, NES-1 - 5.0.
Methane in December 2007 was out of hold time for MW-2R, MW-3R, MW-4, and NES-1.
Butner Landfill, Granville Co.
Permit No. 39-02 Page 3 of 3
Joyce Engineering

CHART

Chart 1 Benzene Concentrations vs. Time

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Joyce Engineering December 2015
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FIGURE

Figure 1 Site Location Map

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater
Appendix D Historical Constituents in Surface Water
Appendix E Statistical Analyses Worksheets & Summary

Appendix A

Field Data Logs

Appendix B

Laboratory Analytical Reports

#=CL#
September 03, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92263803
92263803
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL COMPLIANCE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 18, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 24
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
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Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001
Tennessee Certification #: TN02974Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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Page 2 of 24
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Matrix Date Collected Date Received
92263803001 3902-MW1R Water 08/17/15 13:10 08/18/15 10:25
92263803002 3902-MW2R Water 08/17/15 16:20 08/18/15 10:25
92263803003 3902-NES-1 Water 08/17/15 18:25 08/18/15 10:25
REPORT OF LABORATORY ANALYSIS
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Page 3 of 24
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92263803001 3902-MW1R EPA 8081 5 PASI-CSWB
EPA 8151 2 PASI-OLJM
EPA 6010 16 PASI-ASH1
EPA 8260 50 PASI-CGAW
92263803002 3902-MW2R EPA 8081 5 PASI-CSWB
EPA 8151 2 PASI-OLJM
EPA 6010 16 PASI-ASH1
EPA 8260 50 PASI-CGAW
92263803003 3902-NES-1 EPA 8260 4 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 4 of 24
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92263803001 3902-MW1R
Barium 4.4J ug/L 09/01/15 13:20100EPA 6010
Vanadium 3.4J ug/L 09/01/15 13:2025.0EPA 6010
Zinc 7.4J ug/L 09/01/15 13:2010.0EPA 6010
Chloromethane 0.13J ug/L 08/20/15 17:411.0EPA 8260
Methylene Chloride 1.3 ug/L 08/20/15 17:411.0EPA 8260
92263803002 3902-MW2R
Antimony 6.2 ug/L 09/01/15 13:236.0EPA 6010
Arsenic 5.1J ug/L 09/01/15 13:2310.0EPA 6010
Barium 119 ug/L 09/01/15 13:23100EPA 6010
Chromium 2.7J ug/L 09/01/15 13:2310.0EPA 6010
Cobalt 9.3J ug/L 09/01/15 13:2310.0EPA 6010
Nickel 98.0 ug/L 09/01/15 13:2350.0EPA 6010
Tin 27.7J ug/L 09/01/15 13:23100EPA 6010
Vanadium 6.8J ug/L 09/01/15 13:2325.0EPA 6010
Benzene 1.5 ug/L 08/20/15 17:581.0EPA 8260
Chlorobenzene 12.8 ug/L 08/20/15 17:583.0EPA 8260
Chloroethane 1.2J ug/L 08/20/15 17:5810.0EPA 8260
Chloromethane 0.26J ug/L 08/20/15 17:581.0EPA 8260
1,2-Dichlorobenzene 0.88J ug/L 08/20/15 17:585.0EPA 8260
1,4-Dichlorobenzene 1.5 ug/L 08/20/15 17:581.0EPA 8260
Methylene Chloride 1.1 ug/L 08/20/15 17:581.0EPA 8260
REPORT OF LABORATORY ANALYSIS
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Page 5 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW1R Lab ID: 92263803001 Collected: 08/17/15 13:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
gamma-BHC (Lindane)ND ug/L 08/28/15 02:28 58-89-908/24/15 11:400.050 0.050 1
Endrin aldehyde ND ug/L 08/28/15 02:28 7421-93-408/24/15 11:400.10 0.050 1
Heptachlor ND ug/L 08/28/15 02:28 76-44-808/24/15 11:400.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)83 %08/28/15 02:28 877-09-808/24/15 11:4020-130 1
Decachlorobiphenyl (S)29 %08/28/15 02:28 2051-24-308/24/15 11:4020-130 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 08/25/15 02:59 94-75-708/23/15 16:202.0 0.22 1
Surrogates
2,4-DCAA (S)79 %08/25/15 02:59 19719-28-908/23/15 16:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 09/01/15 13:20 7440-36-008/19/15 19:006.0 3.8 1
Arsenic ND ug/L 09/01/15 13:20 7440-38-208/19/15 19:0010.0 2.5 1
Barium 4.4J ug/L 09/01/15 13:20 7440-39-308/19/15 19:00100 2.5 1
Beryllium ND ug/L 09/01/15 13:20 7440-41-708/19/15 19:001.0 0.50 1
Cadmium ND ug/L 09/01/15 13:20 7440-43-908/19/15 19:001.0 0.50 1
Chromium ND ug/L 09/01/15 13:20 7440-47-308/19/15 19:0010.0 2.5 1
Cobalt ND ug/L 09/01/15 13:20 7440-48-408/19/15 19:0010.0 2.5 1
Copper ND ug/L 09/01/15 13:20 7440-50-808/19/15 19:0010.0 2.5 1
Lead ND ug/L 09/01/15 13:20 7439-92-108/19/15 19:0010.0 2.5 1
Nickel ND ug/L 09/01/15 13:20 7440-02-008/19/15 19:0050.0 2.5 1
Selenium ND ug/L 09/01/15 13:20 7782-49-208/19/15 19:0010.0 5.0 1
Silver ND ug/L 09/01/15 13:20 7440-22-408/19/15 19:0010.0 2.5 1
Thallium ND ug/L 09/01/15 13:20 7440-28-008/19/15 19:005.5 5.0 1
Tin ND ug/L 09/01/15 13:20 7440-31-508/19/15 19:00100 2.5 1
Vanadium 3.4J ug/L 09/01/15 13:20 7440-62-208/19/15 19:0025.0 2.5 1
Zinc 7.4J ug/L 09/01/15 13:20 7440-66-608/19/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/20/15 17:41 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/20/15 17:41 107-13-1200 1.9 1
Benzene ND ug/L 08/20/15 17:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/20/15 17:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/20/15 17:41 75-27-41.0 0.18 1
Bromoform ND ug/L 08/20/15 17:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/20/15 17:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/20/15 17:41 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/20/15 17:41 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/20/15 17:41 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/20/15 17:41 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/20/15 17:41 75-00-310.0 0.54 1
Chloroform ND ug/L 08/20/15 17:41 67-66-35.0 0.14 1
Chloromethane 0.13J ug/L 08/20/15 17:41 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/20/15 17:41 96-12-813.0 2.0 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW1R Lab ID: 92263803001 Collected: 08/17/15 13:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromochloromethane ND ug/L 08/20/15 17:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/20/15 17:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/20/15 17:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/20/15 17:41 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/20/15 17:41 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/20/15 17:41 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/20/15 17:41 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/20/15 17:41 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/20/15 17:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/20/15 17:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/20/15 17:41 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/20/15 17:41 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/20/15 17:41 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/20/15 17:41 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/20/15 17:41 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/20/15 17:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/20/15 17:41 74-88-410.0 0.32 1
Methylene Chloride 1.3 ug/L 08/20/15 17:41 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/20/15 17:41 108-10-1100 0.33 1
Styrene ND ug/L 08/20/15 17:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/20/15 17:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/20/15 17:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/20/15 17:41 127-18-41.0 0.46 1
Toluene ND ug/L 08/20/15 17:41 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/20/15 17:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/20/15 17:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/20/15 17:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/20/15 17:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/20/15 17:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/20/15 17:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/20/15 17:41 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/20/15 17:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)102 %08/20/15 17:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %08/20/15 17:41 17060-07-070-130 1
Toluene-d8 (S)100 %08/20/15 17:41 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 7 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW2R Lab ID: 92263803002 Collected: 08/17/15 16:20 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
gamma-BHC (Lindane)ND ug/L 08/28/15 02:47 58-89-908/24/15 11:400.050 0.050 1
Endrin aldehyde ND ug/L 08/28/15 02:47 7421-93-408/24/15 11:400.10 0.050 1
Heptachlor ND ug/L 08/28/15 02:47 76-44-808/24/15 11:400.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)61 %08/28/15 02:47 877-09-808/24/15 11:4020-130 1
Decachlorobiphenyl (S)80 %08/28/15 02:47 2051-24-308/24/15 11:4020-130 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 08/25/15 03:29 94-75-708/23/15 16:202.0 0.22 1
Surrogates
2,4-DCAA (S)48 %08/25/15 03:29 19719-28-908/23/15 16:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony 6.2 ug/L 09/01/15 13:23 7440-36-008/19/15 19:006.0 3.8 1
Arsenic 5.1J ug/L 09/01/15 13:23 7440-38-208/19/15 19:0010.0 2.5 1
Barium 119 ug/L 09/01/15 13:23 7440-39-308/19/15 19:00100 2.5 1
Beryllium ND ug/L 09/01/15 13:23 7440-41-708/19/15 19:001.0 0.50 1
Cadmium ND ug/L 09/01/15 13:23 7440-43-908/19/15 19:001.0 0.50 1
Chromium 2.7J ug/L 09/01/15 13:23 7440-47-308/19/15 19:0010.0 2.5 1
Cobalt 9.3J ug/L 09/01/15 13:23 7440-48-408/19/15 19:0010.0 2.5 1
Copper ND ug/L 09/01/15 13:23 7440-50-808/19/15 19:0010.0 2.5 1
Lead ND ug/L 09/01/15 13:23 7439-92-108/19/15 19:0010.0 2.5 1
Nickel 98.0 ug/L 09/01/15 13:23 7440-02-008/19/15 19:0050.0 2.5 1
Selenium ND ug/L 09/01/15 13:23 7782-49-208/19/15 19:0010.0 5.0 1
Silver ND ug/L 09/01/15 13:23 7440-22-408/19/15 19:0010.0 2.5 1
Thallium ND ug/L 09/01/15 13:23 7440-28-008/19/15 19:005.5 5.0 1
Tin 27.7J ug/L 09/01/15 13:23 7440-31-508/19/15 19:00100 2.5 1
Vanadium 6.8J ug/L 09/01/15 13:23 7440-62-208/19/15 19:0025.0 2.5 1
Zinc ND ug/L 09/01/15 13:23 7440-66-608/19/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/20/15 17:58 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/20/15 17:58 107-13-1200 1.9 1
Benzene 1.5 ug/L 08/20/15 17:58 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/20/15 17:58 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/20/15 17:58 75-27-41.0 0.18 1
Bromoform ND ug/L 08/20/15 17:58 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/20/15 17:58 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/20/15 17:58 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/20/15 17:58 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/20/15 17:58 56-23-51.0 0.25 1
Chlorobenzene 12.8 ug/L 08/20/15 17:58 108-90-73.0 0.23 1
Chloroethane 1.2J ug/L 08/20/15 17:58 75-00-310.0 0.54 1
Chloroform ND ug/L 08/20/15 17:58 67-66-35.0 0.14 1
Chloromethane 0.26J ug/L 08/20/15 17:58 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/20/15 17:58 96-12-813.0 2.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 8 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW2R Lab ID: 92263803002 Collected: 08/17/15 16:20 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromochloromethane ND ug/L 08/20/15 17:58 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/20/15 17:58 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/20/15 17:58 74-95-310.0 0.21 1
1,2-Dichlorobenzene 0.88J ug/L 08/20/15 17:58 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.5 ug/L 08/20/15 17:58 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/20/15 17:58 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/20/15 17:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/20/15 17:58 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/20/15 17:58 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/20/15 17:58 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/20/15 17:58 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/20/15 17:58 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/20/15 17:58 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/20/15 17:58 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/20/15 17:58 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/20/15 17:58 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/20/15 17:58 74-88-410.0 0.32 1
Methylene Chloride 1.1 ug/L 08/20/15 17:58 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/20/15 17:58 108-10-1100 0.33 1
Styrene ND ug/L 08/20/15 17:58 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/20/15 17:58 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/20/15 17:58 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/20/15 17:58 127-18-41.0 0.46 1
Toluene ND ug/L 08/20/15 17:58 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/20/15 17:58 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/20/15 17:58 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/20/15 17:58 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/20/15 17:58 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/20/15 17:58 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/20/15 17:58 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/20/15 17:58 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/20/15 17:58 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)101 %08/20/15 17:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %08/20/15 17:58 17060-07-070-130 1
Toluene-d8 (S)99 %08/20/15 17:58 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 9 of 24
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Sample: 3902-NES-1 Lab ID: 92263803003 Collected: 08/17/15 18:25 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 08/19/15 15:21 71-43-21.0 0.25 1
Surrogates
4-Bromofluorobenzene (S)100 %08/19/15 15:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %08/19/15 15:21 17060-07-070-130 1
Toluene-d8 (S)104 %08/19/15 15:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 10 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19281
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92263803001, 92263803002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1537575
Associated Lab Samples:92263803001, 92263803002
Matrix: Water
Analyzed
Antimony ug/L ND 6.0 09/01/15 12:55
Arsenic ug/L ND 10.0 09/01/15 12:55
Barium ug/L ND 100 09/01/15 12:55
Beryllium ug/L ND 1.0 09/01/15 12:55
Cadmium ug/L ND 1.0 09/01/15 12:55
Chromium ug/L ND 10.0 09/01/15 12:55
Cobalt ug/L ND 10.0 09/01/15 12:55
Copper ug/L ND 10.0 09/01/15 12:55
Lead ug/L ND 10.0 09/01/15 12:55
Nickel ug/L ND 50.0 09/01/15 12:55
Selenium ug/L ND 10.0 09/01/15 12:55
Silver ug/L ND 10.0 09/01/15 12:55
Thallium ug/L ND 5.5 09/01/15 12:55
Tin ug/L ND 100 09/01/15 12:55
Vanadium ug/L ND 25.0 09/01/15 12:55
Zinc ug/L ND 10.0 09/01/15 12:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1537576LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 472416 113 80-120
Arsenic ug/L 458416 110 80-120
Barium ug/L 466416 112 80-120
Beryllium ug/L 468416 112 80-120
Cadmium ug/L 465416 112 80-120
Chromium ug/L 474416 114 80-120
Cobalt ug/L 469416 113 80-120
Copper ug/L 476416 114 80-120
Lead ug/L 467416 112 80-120
Nickel ug/L 460416 111 80-120
Selenium ug/L 454416 109 80-120
Silver ug/L 229208 110 80-120
Thallium ug/L 465416 112 80-120
Tin ug/L 468416 112 80-120
Vanadium ug/L 461416 111 80-120
Zinc ug/L 453416 109 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1537577MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263797005
1537579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 416 117 75-125114 3 254164.8J 492 479
Arsenic ug/L 416 116 75-125112 3 25416ND482 467
Barium ug/L 416 113 75-125109 3 2541663.1J 532 519
Beryllium ug/L 416 113 75-125111 2 25416ND471 461
Cadmium ug/L 416 114 75-125112 2 25416ND477 466
Chromium ug/L 416 111 75-125109 2 25416ND465 457
Cobalt ug/L 416 108 75-125106 2 25416ND450 440
Copper ug/L 416 117 75-125114 3 254166.7J 494 481
Lead ug/L 416 107 75-125105 2 25416ND446 436
Nickel ug/L 416 106 75-125103 2 2541628.0J 469 458
Selenium ug/L 416 112 75-125109 3 25416ND464 452
Silver ug/L 208 112 75-125110 2 25208ND234 229
Thallium ug/L 416 105 75-125103 1 25416ND437 431
Tin ug/L 416 110 75-125108 2 254167.5J 467 457
Vanadium ug/L 416 111 75-125109 2 254163.6J 465 456
Zinc ug/L 416 104 75-125102 2 25416ND435 427
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33055
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92263803003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536872
Associated Lab Samples:92263803003
Matrix: Water
Analyzed
Benzene ug/L ND 1.0 08/19/15 13:21
1,2-Dichloroethane-d4 (S)%102 70-130 08/19/15 13:21
4-Bromofluorobenzene (S)%99 70-130 08/19/15 13:21
Toluene-d8 (S)%102 70-130 08/19/15 13:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536873LABORATORY CONTROL SAMPLE:
LCSSpike
Benzene ug/L 56.050 112 80-125
1,2-Dichloroethane-d4 (S)%103 70-130
4-Bromofluorobenzene (S)%99 70-130
Toluene-d8 (S)%99 70-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33081
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92263803001, 92263803002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1538227
Associated Lab Samples:92263803001, 92263803002
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/20/15 15:06
1,1,1-Trichloroethane ug/L ND 1.0 08/20/15 15:06
1,1,2,2-Tetrachloroethane ug/L ND 3.0 08/20/15 15:06
1,1,2-Trichloroethane ug/L ND 1.0 08/20/15 15:06
1,1-Dichloroethane ug/L ND 5.0 08/20/15 15:06
1,1-Dichloroethene ug/L ND 5.0 08/20/15 15:06
1,2,3-Trichloropropane ug/L ND 1.0 08/20/15 15:06
1,2-Dibromo-3-chloropropane ug/L ND 13.0 08/20/15 15:06
1,2-Dibromoethane (EDB)ug/L ND 1.0 08/20/15 15:06
1,2-Dichlorobenzene ug/L ND 5.0 08/20/15 15:06
1,2-Dichloroethane ug/L ND 1.0 08/20/15 15:06
1,2-Dichloropropane ug/L ND 1.0 08/20/15 15:06
1,4-Dichlorobenzene ug/L ND 1.0 08/20/15 15:06
2-Butanone (MEK)ug/L ND 100 08/20/15 15:06
2-Hexanone ug/L ND 50.0 08/20/15 15:06
4-Methyl-2-pentanone (MIBK)ug/L ND 100 08/20/15 15:06
Acetone ug/L ND 100 08/20/15 15:06
Acrylonitrile ug/L ND 200 08/20/15 15:06
Benzene ug/L ND 1.0 08/20/15 15:06
Bromochloromethane ug/L ND 3.0 08/20/15 15:06
Bromodichloromethane ug/L ND 1.0 08/20/15 15:06
Bromoform ug/L ND 3.0 08/20/15 15:06
Bromomethane ug/L ND 10.0 08/20/15 15:06
Carbon disulfide ug/L ND 100 08/20/15 15:06
Carbon tetrachloride ug/L ND 1.0 08/20/15 15:06
Chlorobenzene ug/L ND 3.0 08/20/15 15:06
Chloroethane ug/L ND 10.0 08/20/15 15:06
Chloroform ug/L ND 5.0 08/20/15 15:06
Chloromethane ug/L ND 1.0 08/20/15 15:06
cis-1,2-Dichloroethene ug/L ND 5.0 08/20/15 15:06
cis-1,3-Dichloropropene ug/L ND 1.0 08/20/15 15:06
Dibromochloromethane ug/L ND 3.0 08/20/15 15:06
Dibromomethane ug/L ND 10.0 08/20/15 15:06
Ethylbenzene ug/L ND 1.0 08/20/15 15:06
Iodomethane ug/L ND 10.0 08/20/15 15:06
Methylene Chloride ug/L ND 1.0 08/20/15 15:06
Styrene ug/L ND 1.0 08/20/15 15:06
Tetrachloroethene ug/L ND 1.0 08/20/15 15:06
Toluene ug/L ND 1.0 08/20/15 15:06
trans-1,2-Dichloroethene ug/L ND 5.0 08/20/15 15:06
trans-1,3-Dichloropropene ug/L ND 1.0 08/20/15 15:06
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 14 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1538227
Associated Lab Samples:92263803001, 92263803002
Matrix: Water
Analyzed
trans-1,4-Dichloro-2-butene ug/L ND 100 08/20/15 15:06
Trichloroethene ug/L ND 1.0 08/20/15 15:06
Trichlorofluoromethane ug/L ND 1.0 08/20/15 15:06
Vinyl acetate ug/L ND 50.0 08/20/15 15:06
Vinyl chloride ug/L ND 1.0 08/20/15 15:06
Xylene (Total)ug/L ND 5.0 08/20/15 15:06
1,2-Dichloroethane-d4 (S)%101 70-130 08/20/15 15:06
4-Bromofluorobenzene (S)%100 70-130 08/20/15 15:06
Toluene-d8 (S)%101 70-130 08/20/15 15:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538228LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 57.750 115 80-125
1,1,1-Trichloroethane ug/L 57.950 116 71-129
1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124
1,1,2-Trichloroethane ug/L 49.850 100 85-125
1,1-Dichloroethane ug/L 54.350 109 73-126
1,1-Dichloroethene ug/L 60.450 121 66-135
1,2,3-Trichloropropane ug/L 49.750 99 75-130
1,2-Dibromo-3-chloropropane ug/L 51.050 102 71-133
1,2-Dibromoethane (EDB)ug/L 54.850 110 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 50.050 100 67-128
1,2-Dichloropropane ug/L 52.250 104 75-132
1,4-Dichlorobenzene ug/L 49.850 100 78-130
2-Butanone (MEK)ug/L 106100 106 61-144
2-Hexanone ug/L 111100 111 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 101100 101 48-146
Acrylonitrile ug/L 264250 106 40-160
Benzene ug/L 54.750 109 80-125
Bromochloromethane ug/L 55.550 111 71-125
Bromodichloromethane ug/L 56.350 113 78-124
Bromoform ug/L 51.350 103 71-128
Bromomethane ug/L 57.350 115 40-160
Carbon disulfide ug/L 54.2J50 108 50-160
Carbon tetrachloride ug/L 64.450 129 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 47.750 95 39-148
Chloroform ug/L 53.050 106 73-127
Chloromethane ug/L 61.950 124 44-146
cis-1,2-Dichloroethene ug/L 54.650 109 74-124
cis-1,3-Dichloropropene ug/L 56.550 113 72-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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9800 Kincey Ave. Suite 100
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[phone]
Page 15 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538228LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 61.050 122 78-125
Dibromomethane ug/L 53.450 107 82-120
Ethylbenzene ug/L 51.050 102 79-121
Iodomethane ug/L 121100 121 39-154
Methylene Chloride ug/L 58.750 117 64-133
Styrene ug/L 53.950 108 84-126
Tetrachloroethene ug/L 51.350 103 78-122
Toluene ug/L 50.550 101 80-121
trans-1,2-Dichloroethene ug/L 55.650 111 71-127
trans-1,3-Dichloropropene ug/L 56.950 114 69-141
trans-1,4-Dichloro-2-butene ug/L 54.6J50 109 40-160
Trichloroethene ug/L 51.150 102 78-122
Trichlorofluoromethane ug/L 54.450 109 53-137
Vinyl acetate ug/L 114100 114 40-160
Vinyl chloride ug/L 54.750 109 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%106 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1538230MATRIX SPIKE SAMPLE:
MSSpike
Result
92263765006
1,1,1,2-Tetrachloroethane ug/L 33.0 M120165 70-130ND
1,1,1-Trichloroethane ug/L 35.4 M120177 70-130ND
1,1,2,2-Tetrachloroethane ug/L 28.3 M120141 70-130ND
1,1,2-Trichloroethane ug/L 29.5 M120148 70-130ND
1,1-Dichloroethane ug/L 32.4 M120162 70-130ND
1,1-Dichloroethene ug/L 37.2 M120186 70-166ND
1,2,3-Trichloropropane ug/L 28.8 M120144 70-130ND
1,2-Dibromo-3-chloropropane ug/L 29.9 M120150 70-130ND
1,2-Dibromoethane (EDB)ug/L 30.7 M120154 70-130ND
1,2-Dichlorobenzene ug/L 29.6 M120148 70-130ND
1,2-Dichloroethane ug/L 29.1 M120145 70-130ND
1,2-Dichloropropane ug/L 31.0 M120155 70-130ND
1,4-Dichlorobenzene ug/L 28.5 M120142 70-130ND
2-Butanone (MEK)ug/L 70.1J M140175 70-130ND
2-Hexanone ug/L 64.5 M140161 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 61.4J M140153 70-130ND
Acetone ug/L 61.1J M140148 70-130ND
Acrylonitrile ug/L 153J M1100153 70-130ND
Benzene ug/L 32.3 M120161 70-148ND
Bromochloromethane ug/L 32.8 M120164 70-130ND
Bromodichloromethane ug/L 32.7 M120163 70-130ND
Bromoform ug/L 28.9 M120145 70-130ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
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[phone]
Page 16 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1538230MATRIX SPIKE SAMPLE:
MSSpike
Result
92263765006
Bromomethane ug/L 17.520 87 70-130ND
Carbon disulfide ug/L 33.2J M120166 70-130ND
Carbon tetrachloride ug/L 39.1 M120196 70-130ND
Chlorobenzene ug/L 29.120 146 70-146ND
Chloroethane ug/L 32.2 M120161 70-130ND
Chloroform ug/L 32.1 M120161 70-130ND
Chloromethane ug/L 29.0 M120144 70-1300.18J
cis-1,2-Dichloroethene ug/L 32.6 M120163 70-130ND
cis-1,3-Dichloropropene ug/L 31.3 M120156 70-130ND
Dibromochloromethane ug/L 32.8 M120164 70-130ND
Dibromomethane ug/L 30.8 M120154 70-130ND
Ethylbenzene ug/L 30.1 M120148 70-1300.42J
Iodomethane ug/L 55.6 M140139 70-130ND
Methylene Chloride ug/L 30.7 M120150 70-130ND
Styrene ug/L 30.3 M120151 70-130ND
Tetrachloroethene ug/L 30.7 M120153 70-130ND
Toluene ug/L 30.320 151 70-155ND
trans-1,2-Dichloroethene ug/L 34.0 M120170 70-130ND
trans-1,3-Dichloropropene ug/L 31.9 M120160 70-130ND
trans-1,4-Dichloro-2-butene ug/L 29.5J M120147 70-130ND
Trichloroethene ug/L 32.2 M120161 69-151ND
Trichlorofluoromethane ug/L 32.7 M120164 70-130ND
Vinyl acetate ug/L 57.7 M140144 70-130ND
Vinyl chloride ug/L 31.4 M120157 70-130ND
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263765005
1538229SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263765005
1538229SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.21J 300.19J
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L 0.36J 300.39J
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L 1.1 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%107 1105
4-Bromofluorobenzene (S)%102 1101
Toluene-d8 (S)%102 2101
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/37268
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92263803001, 92263803002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540067
Associated Lab Samples:92263803001, 92263803002
Matrix: Water
Analyzed
Endrin aldehyde ug/L ND 0.10 08/26/15 01:13
gamma-BHC (Lindane)ug/L ND 0.050 08/26/15 01:13
Heptachlor ug/L ND 0.050 08/26/15 01:13
Decachlorobiphenyl (S)%82 20-130 08/26/15 01:13
Tetrachloro-m-xylene (S)%99 20-130 08/26/15 01:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540068LABORATORY CONTROL SAMPLE:
LCSSpike
Endrin aldehyde ug/L 0.21.25 86 20-150
gamma-BHC (Lindane)ug/L 0.23.25 94 20-150
Heptachlor ug/L 0.21.25 84 20-150
Decachlorobiphenyl (S)%81 20-130
Tetrachloro-m-xylene (S)%96 20-130
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 24
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/23964
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92263803001, 92263803002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1308144
Associated Lab Samples:92263803001, 92263803002
Matrix: Water
Analyzed
2,4-D ug/L ND 2.0 08/25/15 00:58
2,4-DCAA (S)%99 36-130 08/25/15 00:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1308145LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1310298
2,4-D ug/L 5.16 86 42-1341116.6 25 40
2,4-DCAA (S)%87 36-130108
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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[phone]
Page 20 of 24
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 21 of 24
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92263803
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92263803001 OEXT/37268 GCSV/223823902-MW1R EPA 3510 EPA 8081
92263803002 OEXT/37268 GCSV/223823902-MW2R EPA 3510 EPA 8081
92263803001 OEXT/23964 GCSV/155713902-MW1R EPA 8151 EPA 8151
92263803002 OEXT/23964 GCSV/155713902-MW2R EPA 8151 EPA 8151
92263803001 MPRP/19281 ICP/173373902-MW1R EPA 3010 EPA 6010
92263803002 MPRP/19281 ICP/173373902-MW2R EPA 3010 EPA 6010
92263803001 MSV/330813902-MW1R EPA 8260
92263803002 MSV/330813902-MW2R EPA 8260
92263803003 MSV/330553902-NES-1 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 04:57 PM
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Page 22 of 24
Page 23 of 24
Page 24 of 24
#=CL#
August 31, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92264210
92264210
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL COMPLIANCE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 20, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 28
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079
Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346
Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC ReciprocityNew Hampshire Certification #: 2958New York Certification #: 11608
North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710
Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001
Tennessee Certification #: TN02974Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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Page 2 of 28
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Matrix Date Collected Date Received
92264210001 3902-MW4 Water 08/18/15 08:05 08/20/15 10:30
92264210002 3902-MW5 Water 08/18/15 08:16 08/20/15 10:30
92264210003 3902-MW6 Water 08/18/15 08:45 08/20/15 10:30
92264210004 3902-FIELD BLANK Water 08/18/15 08:42 08/20/15 10:30
92264210005 3902-TRIP BLANK Water 08/17/15 06:15 08/20/15 10:30
REPORT OF LABORATORY ANALYSIS
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Page 3 of 28
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92264210001 3902-MW4 EPA 6010 15 PASI-AJDA
EPA 8260 50 PASI-CNB
92264210002 3902-MW5 EPA 6010 15 PASI-AJDA
EPA 8260 50 PASI-CNB
92264210003 3902-MW6 EPA 6010 15 PASI-AJDA
EPA 8260 50 PASI-CNB
92264210004 3902-FIELD BLANK EPA 8081 5 PASI-CSWB
EPA 8151 2 PASI-OLJM
EPA 6010 16 PASI-AJDA
EPA 8260 50 PASI-CNB
92264210005 3902-TRIP BLANK EPA 8260 50 PASI-CNB
REPORT OF LABORATORY ANALYSIS
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Page 4 of 28
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92264210001 3902-MW4
Antimony 4.1J ug/L 08/30/15 17:386.0EPA 6010
Copper 5.6J ug/L 08/30/15 17:3810.0EPA 6010
Nickel 11.9J ug/L 08/30/15 17:3850.0EPA 6010
Vanadium 19.6J ug/L 08/30/15 17:3825.0EPA 6010
Benzene 0.32J ug/L 08/26/15 14:441.0EPA 8260
Chlorobenzene 4.3 ug/L 08/26/15 14:443.0EPA 8260
Chloroethane 3.7J ug/L 08/26/15 14:4410.0EPA 8260
1,1-Dichloroethane 0.49J ug/L 08/26/15 14:445.0EPA 8260
1,2-Dichloroethane 0.29J ug/L 08/26/15 14:441.0EPA 8260
92264210002 3902-MW5
Barium 81.3J ug/L 08/30/15 17:41100EPA 6010
Cobalt 116 ug/L 08/30/15 17:4110.0EPA 6010
Copper 10.1 ug/L 08/30/15 17:4110.0EPA 6010
Nickel 26.2J ug/L 08/30/15 17:4150.0EPA 6010
Vanadium 2.8J ug/L 08/30/15 17:4125.0EPA 6010
Zinc 5.2J ug/L 08/30/15 17:4110.0EPA 6010
1,2-Dichloroethane 0.36J ug/L 08/26/15 15:011.0EPA 8260
92264210003 3902-MW6
Chromium 6.7J ug/L 08/30/15 17:4410.0EPA 6010
Nickel 5.4J ug/L 08/30/15 17:4450.0EPA 6010
REPORT OF LABORATORY ANALYSIS
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Page 5 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW4 Lab ID: 92264210001 Collected: 08/18/15 08:05 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony 4.1J ug/L 08/30/15 17:38 7440-36-008/21/15 16:306.0 3.8 1
Arsenic ND ug/L 08/30/15 17:38 7440-38-208/21/15 16:3010.0 2.5 1
Barium ND ug/L 08/30/15 17:38 7440-39-308/21/15 16:30100 2.5 1
Beryllium ND ug/L 08/30/15 17:38 7440-41-708/21/15 16:301.0 0.50 1
Cadmium ND ug/L 08/30/15 17:38 7440-43-908/21/15 16:301.0 0.50 1
Chromium ND ug/L 08/30/15 17:38 7440-47-308/21/15 16:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 17:38 7440-48-408/21/15 16:3010.0 2.5 1
Copper 5.6J ug/L 08/30/15 17:38 7440-50-808/21/15 16:3010.0 2.5 1
Lead ND ug/L 08/30/15 17:38 7439-92-108/21/15 16:3010.0 2.5 1
Nickel 11.9J ug/L 08/30/15 17:38 7440-02-008/21/15 16:3050.0 2.5 1
Selenium ND ug/L 08/30/15 17:38 7782-49-208/21/15 16:3010.0 5.0 1
Silver ND ug/L 08/30/15 17:38 7440-22-408/21/15 16:3010.0 2.5 1
Thallium ND ug/L 08/30/15 17:38 7440-28-008/21/15 16:305.5 5.0 1
Vanadium 19.6J ug/L 08/30/15 17:38 7440-62-208/21/15 16:3025.0 2.5 1
Zinc ND ug/L 08/30/15 17:38 7440-66-608/21/15 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/26/15 14:44 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/26/15 14:44 107-13-1200 1.9 1
Benzene 0.32J ug/L 08/26/15 14:44 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/26/15 14:44 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/26/15 14:44 75-27-41.0 0.18 1
Bromoform ND ug/L 08/26/15 14:44 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/26/15 14:44 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/26/15 14:44 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/26/15 14:44 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/26/15 14:44 56-23-51.0 0.25 1
Chlorobenzene 4.3 ug/L 08/26/15 14:44 108-90-73.0 0.23 1
Chloroethane 3.7J ug/L 08/26/15 14:44 75-00-310.0 0.54 1
Chloroform ND ug/L 08/26/15 14:44 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/26/15 14:44 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/26/15 14:44 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/26/15 14:44 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/26/15 14:44 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/26/15 14:44 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/26/15 14:44 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/26/15 14:44 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/26/15 14:44 110-57-6100 1.0 1
1,1-Dichloroethane 0.49J ug/L 08/26/15 14:44 75-34-35.0 0.32 1
1,2-Dichloroethane 0.29J ug/L 08/26/15 14:44 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/26/15 14:44 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/26/15 14:44 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/26/15 14:44 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/26/15 14:44 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/26/15 14:44 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/26/15 14:44 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW4 Lab ID: 92264210001 Collected: 08/18/15 08:05 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 08/26/15 14:44 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/26/15 14:44 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/26/15 14:44 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/26/15 14:44 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/26/15 14:44 108-10-1100 0.33 1
Styrene ND ug/L 08/26/15 14:44 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/26/15 14:44 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/26/15 14:44 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/26/15 14:44 127-18-41.0 0.46 1
Toluene ND ug/L 08/26/15 14:44 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/26/15 14:44 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/26/15 14:44 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/26/15 14:44 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/26/15 14:44 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/26/15 14:44 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/26/15 14:44 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/26/15 14:44 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/26/15 14:44 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %08/26/15 14:44 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %08/26/15 14:44 17060-07-070-130 1
Toluene-d8 (S)101 %08/26/15 14:44 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW5 Lab ID: 92264210002 Collected: 08/18/15 08:16 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 17:41 7440-36-008/21/15 16:306.0 3.8 1
Arsenic ND ug/L 08/30/15 17:41 7440-38-208/21/15 16:3010.0 2.5 1
Barium 81.3J ug/L 08/30/15 17:41 7440-39-308/21/15 16:30100 2.5 1
Beryllium ND ug/L 08/30/15 17:41 7440-41-708/21/15 16:301.0 0.50 1
Cadmium ND ug/L 08/30/15 17:41 7440-43-908/21/15 16:301.0 0.50 1
Chromium ND ug/L 08/30/15 17:41 7440-47-308/21/15 16:3010.0 2.5 1
Cobalt 116 ug/L 08/30/15 17:41 7440-48-408/21/15 16:3010.0 2.5 1
Copper 10.1 ug/L 08/30/15 17:41 7440-50-808/21/15 16:3010.0 2.5 1
Lead ND ug/L 08/30/15 17:41 7439-92-108/21/15 16:3010.0 2.5 1
Nickel 26.2J ug/L 08/30/15 17:41 7440-02-008/21/15 16:3050.0 2.5 1
Selenium ND ug/L 08/30/15 17:41 7782-49-208/21/15 16:3010.0 5.0 1
Silver ND ug/L 08/30/15 17:41 7440-22-408/21/15 16:3010.0 2.5 1
Thallium ND ug/L 08/30/15 17:41 7440-28-008/21/15 16:305.5 5.0 1
Vanadium 2.8J ug/L 08/30/15 17:41 7440-62-208/21/15 16:3025.0 2.5 1
Zinc 5.2J ug/L 08/30/15 17:41 7440-66-608/21/15 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/26/15 15:01 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/26/15 15:01 107-13-1200 1.9 1
Benzene ND ug/L 08/26/15 15:01 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/26/15 15:01 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/26/15 15:01 75-27-41.0 0.18 1
Bromoform ND ug/L 08/26/15 15:01 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/26/15 15:01 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/26/15 15:01 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/26/15 15:01 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/26/15 15:01 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/26/15 15:01 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/26/15 15:01 75-00-310.0 0.54 1
Chloroform ND ug/L 08/26/15 15:01 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/26/15 15:01 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/26/15 15:01 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/26/15 15:01 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/26/15 15:01 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/26/15 15:01 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/26/15 15:01 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/26/15 15:01 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/26/15 15:01 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/26/15 15:01 75-34-35.0 0.32 1
1,2-Dichloroethane 0.36J ug/L 08/26/15 15:01 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/26/15 15:01 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/26/15 15:01 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/26/15 15:01 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/26/15 15:01 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/26/15 15:01 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/26/15 15:01 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW5 Lab ID: 92264210002 Collected: 08/18/15 08:16 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 08/26/15 15:01 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/26/15 15:01 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/26/15 15:01 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/26/15 15:01 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/26/15 15:01 108-10-1100 0.33 1
Styrene ND ug/L 08/26/15 15:01 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/26/15 15:01 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/26/15 15:01 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/26/15 15:01 127-18-41.0 0.46 1
Toluene ND ug/L 08/26/15 15:01 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/26/15 15:01 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/26/15 15:01 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/26/15 15:01 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/26/15 15:01 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/26/15 15:01 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/26/15 15:01 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/26/15 15:01 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/26/15 15:01 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %08/26/15 15:01 460-00-470-130 1
1,2-Dichloroethane-d4 (S)109 %08/26/15 15:01 17060-07-070-130 1
Toluene-d8 (S)100 %08/26/15 15:01 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW6 Lab ID: 92264210003 Collected: 08/18/15 08:45 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 17:44 7440-36-008/21/15 16:306.0 3.8 1
Arsenic ND ug/L 08/30/15 17:44 7440-38-208/21/15 16:3010.0 2.5 1
Barium ND ug/L 08/30/15 17:44 7440-39-308/21/15 16:30100 2.5 1
Beryllium ND ug/L 08/30/15 17:44 7440-41-708/21/15 16:301.0 0.50 1
Cadmium ND ug/L 08/30/15 17:44 7440-43-908/21/15 16:301.0 0.50 1
Chromium 6.7J ug/L 08/30/15 17:44 7440-47-308/21/15 16:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 17:44 7440-48-408/21/15 16:3010.0 2.5 1
Copper ND ug/L 08/30/15 17:44 7440-50-808/21/15 16:3010.0 2.5 1
Lead ND ug/L 08/30/15 17:44 7439-92-108/21/15 16:3010.0 2.5 1
Nickel 5.4J ug/L 08/30/15 17:44 7440-02-008/21/15 16:3050.0 2.5 1
Selenium ND ug/L 08/30/15 17:44 7782-49-208/21/15 16:3010.0 5.0 1
Silver ND ug/L 08/30/15 17:44 7440-22-408/21/15 16:3010.0 2.5 1
Thallium ND ug/L 08/30/15 17:44 7440-28-008/21/15 16:305.5 5.0 1
Vanadium ND ug/L 08/30/15 17:44 7440-62-208/21/15 16:3025.0 2.5 1
Zinc ND ug/L 08/30/15 17:44 7440-66-608/21/15 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/26/15 15:18 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/26/15 15:18 107-13-1200 1.9 1
Benzene ND ug/L 08/26/15 15:18 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/26/15 15:18 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/26/15 15:18 75-27-41.0 0.18 1
Bromoform ND ug/L 08/26/15 15:18 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/26/15 15:18 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/26/15 15:18 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/26/15 15:18 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/26/15 15:18 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/26/15 15:18 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/26/15 15:18 75-00-310.0 0.54 1
Chloroform ND ug/L 08/26/15 15:18 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/26/15 15:18 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/26/15 15:18 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/26/15 15:18 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/26/15 15:18 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/26/15 15:18 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/26/15 15:18 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/26/15 15:18 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/26/15 15:18 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/26/15 15:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/26/15 15:18 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/26/15 15:18 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/26/15 15:18 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/26/15 15:18 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/26/15 15:18 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/26/15 15:18 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/26/15 15:18 10061-02-61.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-MW6 Lab ID: 92264210003 Collected: 08/18/15 08:45 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Ethylbenzene ND ug/L 08/26/15 15:18 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/26/15 15:18 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/26/15 15:18 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/26/15 15:18 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/26/15 15:18 108-10-1100 0.33 1
Styrene ND ug/L 08/26/15 15:18 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/26/15 15:18 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/26/15 15:18 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/26/15 15:18 127-18-41.0 0.46 1
Toluene ND ug/L 08/26/15 15:18 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/26/15 15:18 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/26/15 15:18 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/26/15 15:18 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/26/15 15:18 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/26/15 15:18 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/26/15 15:18 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/26/15 15:18 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/26/15 15:18 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %08/26/15 15:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %08/26/15 15:18 17060-07-070-130 1
Toluene-d8 (S)101 %08/26/15 15:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-FIELD BLANK Lab ID: 92264210004 Collected: 08/18/15 08:42 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
gamma-BHC (Lindane)ND ug/L 08/28/15 03:05 58-89-908/24/15 11:400.050 0.050 1
Endrin aldehyde ND ug/L 08/28/15 03:05 7421-93-408/24/15 11:400.10 0.050 1
Heptachlor ND ug/L 08/28/15 03:05 76-44-808/24/15 11:400.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)89 %08/28/15 03:05 877-09-808/24/15 11:4020-130 1
Decachlorobiphenyl (S)58 %08/28/15 03:05 2051-24-308/24/15 11:4020-130 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 08/25/15 16:38 94-75-708/24/15 15:402.0 0.22 1
Surrogates
2,4-DCAA (S)88 %08/25/15 16:38 19719-28-908/24/15 15:4036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony ND ug/L 08/30/15 17:48 7440-36-008/21/15 16:306.0 3.8 1
Arsenic ND ug/L 08/30/15 17:48 7440-38-208/21/15 16:3010.0 2.5 1
Barium ND ug/L 08/30/15 17:48 7440-39-308/21/15 16:30100 2.5 1
Beryllium ND ug/L 08/30/15 17:48 7440-41-708/21/15 16:301.0 0.50 1
Cadmium ND ug/L 08/30/15 17:48 7440-43-908/21/15 16:301.0 0.50 1
Chromium ND ug/L 08/30/15 17:48 7440-47-308/21/15 16:3010.0 2.5 1
Cobalt ND ug/L 08/30/15 17:48 7440-48-408/21/15 16:3010.0 2.5 1
Copper ND ug/L 08/30/15 17:48 7440-50-808/21/15 16:3010.0 2.5 1
Lead ND ug/L 08/30/15 17:48 7439-92-108/21/15 16:3010.0 2.5 1
Nickel ND ug/L 08/30/15 17:48 7440-02-008/21/15 16:3050.0 2.5 1
Selenium ND ug/L 08/30/15 17:48 7782-49-208/21/15 16:3010.0 5.0 1
Silver ND ug/L 08/30/15 17:48 7440-22-408/21/15 16:3010.0 2.5 1
Thallium ND ug/L 08/30/15 17:48 7440-28-008/21/15 16:305.5 5.0 1
Tin ND ug/L 08/30/15 17:48 7440-31-508/21/15 16:30100 2.5 1
Vanadium ND ug/L 08/30/15 17:48 7440-62-208/21/15 16:3025.0 2.5 1
Zinc ND ug/L 08/30/15 17:48 7440-66-608/21/15 16:3010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/26/15 15:34 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/26/15 15:34 107-13-1200 1.9 1
Benzene ND ug/L 08/26/15 15:34 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/26/15 15:34 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/26/15 15:34 75-27-41.0 0.18 1
Bromoform ND ug/L 08/26/15 15:34 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/26/15 15:34 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/26/15 15:34 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/26/15 15:34 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/26/15 15:34 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/26/15 15:34 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/26/15 15:34 75-00-310.0 0.54 1
Chloroform ND ug/L 08/26/15 15:34 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/26/15 15:34 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/26/15 15:34 96-12-813.0 2.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-FIELD BLANK Lab ID: 92264210004 Collected: 08/18/15 08:42 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromochloromethane ND ug/L 08/26/15 15:34 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/26/15 15:34 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/26/15 15:34 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/26/15 15:34 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/26/15 15:34 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/26/15 15:34 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/26/15 15:34 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/26/15 15:34 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/26/15 15:34 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/26/15 15:34 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/26/15 15:34 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/26/15 15:34 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/26/15 15:34 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/26/15 15:34 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/26/15 15:34 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/26/15 15:34 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/26/15 15:34 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/26/15 15:34 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/26/15 15:34 108-10-1100 0.33 1
Styrene ND ug/L 08/26/15 15:34 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/26/15 15:34 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/26/15 15:34 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/26/15 15:34 127-18-41.0 0.46 1
Toluene ND ug/L 08/26/15 15:34 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/26/15 15:34 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/26/15 15:34 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/26/15 15:34 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/26/15 15:34 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/26/15 15:34 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/26/15 15:34 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/26/15 15:34 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/26/15 15:34 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %08/26/15 15:34 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %08/26/15 15:34 17060-07-070-130 1
Toluene-d8 (S)101 %08/26/15 15:34 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-TRIP BLANK Lab ID: 92264210005 Collected: 08/17/15 06:15 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/26/15 15:51 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/26/15 15:51 107-13-1200 1.9 1
Benzene ND ug/L 08/26/15 15:51 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/26/15 15:51 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/26/15 15:51 75-27-41.0 0.18 1
Bromoform ND ug/L 08/26/15 15:51 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/26/15 15:51 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/26/15 15:51 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/26/15 15:51 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/26/15 15:51 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 08/26/15 15:51 108-90-73.0 0.23 1
Chloroethane ND ug/L 08/26/15 15:51 75-00-310.0 0.54 1
Chloroform ND ug/L 08/26/15 15:51 67-66-35.0 0.14 1
Chloromethane ND ug/L 08/26/15 15:51 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/26/15 15:51 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 08/26/15 15:51 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/26/15 15:51 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/26/15 15:51 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 08/26/15 15:51 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 08/26/15 15:51 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/26/15 15:51 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/26/15 15:51 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 08/26/15 15:51 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/26/15 15:51 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/26/15 15:51 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/26/15 15:51 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/26/15 15:51 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/26/15 15:51 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/26/15 15:51 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/26/15 15:51 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/26/15 15:51 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/26/15 15:51 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 08/26/15 15:51 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/26/15 15:51 108-10-1100 0.33 1
Styrene ND ug/L 08/26/15 15:51 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/26/15 15:51 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/26/15 15:51 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/26/15 15:51 127-18-41.0 0.46 1
Toluene ND ug/L 08/26/15 15:51 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/26/15 15:51 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/26/15 15:51 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/26/15 15:51 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/26/15 15:51 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/26/15 15:51 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/26/15 15:51 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/26/15 15:51 75-01-41.0 0.62 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 28
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Sample: 3902-TRIP BLANK Lab ID: 92264210005 Collected: 08/17/15 06:15 Received: 08/20/15 10:30 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Xylene (Total)ND ug/L 08/26/15 15:51 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %08/26/15 15:51 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %08/26/15 15:51 17060-07-070-130 1
Toluene-d8 (S)102 %08/26/15 15:51 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19312
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92264210001, 92264210002, 92264210003, 92264210004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1538928
Associated Lab Samples:92264210001, 92264210002, 92264210003, 92264210004
Matrix: Water
Analyzed
Antimony ug/L ND 6.0 08/30/15 16:55
Arsenic ug/L ND 10.0 08/30/15 16:55
Barium ug/L ND 100 08/30/15 16:55
Beryllium ug/L ND 1.0 08/30/15 16:55
Cadmium ug/L ND 1.0 08/30/15 16:55
Chromium ug/L ND 10.0 08/30/15 16:55
Cobalt ug/L ND 10.0 08/30/15 16:55
Copper ug/L ND 10.0 08/30/15 16:55
Lead ug/L ND 10.0 08/30/15 16:55
Nickel ug/L ND 50.0 08/30/15 16:55
Selenium ug/L ND 10.0 08/30/15 16:55
Silver ug/L ND 10.0 08/30/15 16:55
Thallium ug/L ND 5.5 08/30/15 16:55
Tin ug/L ND 100 08/30/15 16:55
Vanadium ug/L ND 25.0 08/30/15 16:55
Zinc ug/L ND 10.0 08/30/15 16:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538929LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 494500 99 80-120
Arsenic ug/L 474500 95 80-120
Barium ug/L 484500 97 80-120
Beryllium ug/L 485500 97 80-120
Cadmium ug/L 480500 96 80-120
Chromium ug/L 477500 95 80-120
Cobalt ug/L 486500 97 80-120
Copper ug/L 488500 98 80-120
Lead ug/L 480500 96 80-120
Nickel ug/L 475500 95 80-120
Selenium ug/L 472500 94 80-120
Silver ug/L 239250 96 80-120
Thallium ug/L 485500 97 80-120
Tin ug/L 493500 99 80-120
Vanadium ug/L 484500 97 80-120
Zinc ug/L 475500 95 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1538930MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264209001
1538931
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 96 75-12594 2 25500ND484 474
Arsenic ug/L 500 93 75-12592 2 25500ND467 458
Barium ug/L 500 93 75-12592 1 2550011.0J 477 473
Beryllium ug/L 500 95 75-12594 1 25500ND475 472
Cadmium ug/L 500 93 75-12592 2 25500ND467 458
Chromium ug/L 500 93 75-12592 1 25500ND466 461
Cobalt ug/L 500 93 75-12591 2 25500ND465 456
Copper ug/L 500 95 75-12594 1 255002.8J 476 473
Lead ug/L 500 91 75-12590 2 25500ND458 450
Nickel ug/L 500 91 75-12589 2 25500ND457 448
Selenium ug/L 500 91 75-12590 2 25500ND458 450
Silver ug/L 250 92 75-12592 1 25250ND232 230
Thallium ug/L 500 93 75-12591 2 25500ND466 455
Tin ug/L 500 95 75-12594 1 25500ND476 470
Vanadium ug/L 500 95 75-12594 1 255006.1J 480 475
Zinc ug/L 500 91 75-12590 1 255008.9J 463 457
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33115
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92264210001, 92264210002, 92264210003, 92264210004, 92264210005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540456
Associated Lab Samples:92264210001, 92264210002, 92264210003, 92264210004, 92264210005
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/26/15 12:12
1,1,1-Trichloroethane ug/L ND 1.0 08/26/15 12:12
1,1,2,2-Tetrachloroethane ug/L ND 3.0 08/26/15 12:12
1,1,2-Trichloroethane ug/L ND 1.0 08/26/15 12:12
1,1-Dichloroethane ug/L ND 5.0 08/26/15 12:12
1,1-Dichloroethene ug/L ND 5.0 08/26/15 12:12
1,2,3-Trichloropropane ug/L ND 1.0 08/26/15 12:12
1,2-Dibromo-3-chloropropane ug/L ND 13.0 08/26/15 12:12
1,2-Dibromoethane (EDB)ug/L ND 1.0 08/26/15 12:12
1,2-Dichlorobenzene ug/L ND 5.0 08/26/15 12:12
1,2-Dichloroethane ug/L ND 1.0 08/26/15 12:12
1,2-Dichloropropane ug/L ND 1.0 08/26/15 12:12
1,4-Dichlorobenzene ug/L ND 1.0 08/26/15 12:12
2-Butanone (MEK)ug/L ND 100 08/26/15 12:12
2-Hexanone ug/L ND 50.0 08/26/15 12:12
4-Methyl-2-pentanone (MIBK)ug/L ND 100 08/26/15 12:12
Acetone ug/L ND 100 08/26/15 12:12
Acrylonitrile ug/L ND 200 08/26/15 12:12
Benzene ug/L ND 1.0 08/26/15 12:12
Bromochloromethane ug/L ND 3.0 08/26/15 12:12
Bromodichloromethane ug/L ND 1.0 08/26/15 12:12
Bromoform ug/L ND 3.0 08/26/15 12:12
Bromomethane ug/L ND 10.0 08/26/15 12:12
Carbon disulfide ug/L ND 100 08/26/15 12:12
Carbon tetrachloride ug/L ND 1.0 08/26/15 12:12
Chlorobenzene ug/L ND 3.0 08/26/15 12:12
Chloroethane ug/L ND 10.0 08/26/15 12:12
Chloroform ug/L ND 5.0 08/26/15 12:12
Chloromethane ug/L ND 1.0 08/26/15 12:12
cis-1,2-Dichloroethene ug/L ND 5.0 08/26/15 12:12
cis-1,3-Dichloropropene ug/L ND 1.0 08/26/15 12:12
Dibromochloromethane ug/L ND 3.0 08/26/15 12:12
Dibromomethane ug/L ND 10.0 08/26/15 12:12
Ethylbenzene ug/L ND 1.0 08/26/15 12:12
Iodomethane ug/L ND 10.0 08/26/15 12:12
Methylene Chloride ug/L ND 1.0 08/26/15 12:12
Styrene ug/L ND 1.0 08/26/15 12:12
Tetrachloroethene ug/L ND 1.0 08/26/15 12:12
Toluene ug/L ND 1.0 08/26/15 12:12
trans-1,2-Dichloroethene ug/L ND 5.0 08/26/15 12:12
trans-1,3-Dichloropropene ug/L ND 1.0 08/26/15 12:12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540456
Associated Lab Samples:92264210001, 92264210002, 92264210003, 92264210004, 92264210005
Matrix: Water
Analyzed
trans-1,4-Dichloro-2-butene ug/L ND 100 08/26/15 12:12
Trichloroethene ug/L ND 1.0 08/26/15 12:12
Trichlorofluoromethane ug/L ND 1.0 08/26/15 12:12
Vinyl acetate ug/L ND 50.0 08/26/15 12:12
Vinyl chloride ug/L ND 1.0 08/26/15 12:12
Xylene (Total)ug/L ND 5.0 08/26/15 12:12
1,2-Dichloroethane-d4 (S)%103 70-130 08/26/15 12:12
4-Bromofluorobenzene (S)%98 70-130 08/26/15 12:12
Toluene-d8 (S)%100 70-130 08/26/15 12:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540457LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.350 93 80-125
1,1,1-Trichloroethane ug/L 53.950 108 71-129
1,1,2,2-Tetrachloroethane ug/L 47.750 95 79-124
1,1,2-Trichloroethane ug/L 47.650 95 85-125
1,1-Dichloroethane ug/L 51.350 103 73-126
1,1-Dichloroethene ug/L 57.350 115 66-135
1,2,3-Trichloropropane ug/L 47.650 95 75-130
1,2-Dibromo-3-chloropropane ug/L 52.750 105 71-133
1,2-Dibromoethane (EDB)ug/L 51.550 103 83-124
1,2-Dichlorobenzene ug/L 51.550 103 80-133
1,2-Dichloroethane ug/L 45.950 92 67-128
1,2-Dichloropropane ug/L 47.950 96 75-132
1,4-Dichlorobenzene ug/L 51.350 103 78-130
2-Butanone (MEK)ug/L 88.0J100 88 61-144
2-Hexanone ug/L 94.8100 95 68-143
4-Methyl-2-pentanone (MIBK)ug/L 96.5J100 97 72-135
Acetone ug/L 84.0J100 84 48-146
Acrylonitrile ug/L 241250 96 40-160
Benzene ug/L 52.250 104 80-125
Bromochloromethane ug/L 52.450 105 71-125
Bromodichloromethane ug/L 52.450 105 78-124
Bromoform ug/L 41.850 84 71-128
Bromomethane ug/L 47.650 95 40-160
Carbon disulfide ug/L 47.0J50 94 50-160
Carbon tetrachloride ug/L 49.750 99 69-131
Chlorobenzene ug/L 49.150 98 81-122
Chloroethane ug/L 51.150 102 39-148
Chloroform ug/L 51.650 103 73-127
Chloromethane ug/L 48.950 98 44-146
cis-1,2-Dichloroethene ug/L 52.150 104 74-124
cis-1,3-Dichloropropene ug/L 50.250 100 72-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540457LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 45.350 91 78-125
Dibromomethane ug/L 48.750 97 82-120
Ethylbenzene ug/L 49.150 98 79-121
Iodomethane ug/L 90.3100 90 39-154
Methylene Chloride ug/L 48.550 97 64-133
Styrene ug/L 52.050 104 84-126
Tetrachloroethene ug/L 49.250 98 78-122
Toluene ug/L 49.750 99 80-121
trans-1,2-Dichloroethene ug/L 54.350 109 71-127
trans-1,3-Dichloropropene ug/L 52.150 104 69-141
trans-1,4-Dichloro-2-butene ug/L 45.2J50 90 40-160
Trichloroethene ug/L 48.950 98 78-122
Trichlorofluoromethane ug/L 45.650 91 53-137
Vinyl acetate ug/L 105100 105 40-160
Vinyl chloride ug/L 48.250 96 58-137
Xylene (Total)ug/L 151150 100 81-126
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1540459MATRIX SPIKE SAMPLE:
MSSpike
Result
92264282007
1,1,1,2-Tetrachloroethane ug/L 22.420 112 70-130ND
1,1,1-Trichloroethane ug/L 26.020 130 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.220 116 70-130ND
1,1,2-Trichloroethane ug/L 23.220 116 70-130ND
1,1-Dichloroethane ug/L 24.120 120 70-130ND
1,1-Dichloroethene ug/L 28.720 144 70-166ND
1,2,3-Trichloropropane ug/L 24.520 122 70-130ND
1,2-Dibromo-3-chloropropane ug/L 25.720 129 70-130ND
1,2-Dibromoethane (EDB)ug/L 24.320 121 70-130ND
1,2-Dichlorobenzene ug/L 23.220 116 70-130ND
1,2-Dichloroethane ug/L 23.120 114 70-130ND
1,2-Dichloropropane ug/L 23.020 115 70-130ND
1,4-Dichlorobenzene ug/L 23.220 116 70-130ND
2-Butanone (MEK)ug/L 52.0J40 130 70-130ND
2-Hexanone ug/L 58.5 M140146 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 54.8J M140137 70-130ND
Acetone ug/L 64.2J M140142 70-130ND
Acrylonitrile ug/L 130J100 130 70-130ND
Benzene ug/L 24.020 120 70-148ND
Bromochloromethane ug/L 24.720 124 70-130ND
Bromodichloromethane ug/L 23.720 118 70-130ND
Bromoform ug/L 19.820 99 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1540459MATRIX SPIKE SAMPLE:
MSSpike
Result
92264282007
Bromomethane ug/L 17.920 89 70-130ND
Carbon disulfide ug/L 20.3J20 102 70-130ND
Carbon tetrachloride ug/L 24.620 123 70-130ND
Chlorobenzene ug/L 23.520 118 70-146ND
Chloroethane ug/L 22.820 114 70-130ND
Chloroform ug/L 24.620 123 70-130ND
Chloromethane ug/L 21.520 108 70-130ND
cis-1,2-Dichloroethene ug/L 24.920 124 70-130ND
cis-1,3-Dichloropropene ug/L 20.020 100 70-130ND
Dibromochloromethane ug/L 21.320 106 70-130ND
Dibromomethane ug/L 23.420 117 70-130ND
Ethylbenzene ug/L 23.320 117 70-130ND
Iodomethane ug/L 33.640 84 70-130ND
Methylene Chloride ug/L 24.420 122 70-130ND
Styrene ug/L 22.920 115 70-130ND
Tetrachloroethene ug/L 23.020 115 70-130ND
Toluene ug/L 23.620 118 70-155ND
trans-1,2-Dichloroethene ug/L 25.920 129 70-130ND
trans-1,3-Dichloropropene ug/L 20.920 104 70-130ND
trans-1,4-Dichloro-2-butene ug/L 22.1J20 111 70-130ND
Trichloroethene ug/L 22.920 114 69-151ND
Trichlorofluoromethane ug/L 24.120 120 70-130ND
Vinyl acetate ug/L 27.9J40 70 70-130ND
Vinyl chloride ug/L 21.720 108 70-130ND
1,2-Dichloroethane-d4 (S)%106 70-130
4-Bromofluorobenzene (S)%101 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264282006
1540458SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 0.62J 300.54J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92264282006
1540458SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 0.34J 300.35J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%111 2109
4-Bromofluorobenzene (S)%99 098
Toluene-d8 (S)%103 3100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/37268
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92264210004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540067
Associated Lab Samples:92264210004
Matrix: Water
Analyzed
Endrin aldehyde ug/L ND 0.10 08/26/15 01:13
gamma-BHC (Lindane)ug/L ND 0.050 08/26/15 01:13
Heptachlor ug/L ND 0.050 08/26/15 01:13
Decachlorobiphenyl (S)%82 20-130 08/26/15 01:13
Tetrachloro-m-xylene (S)%99 20-130 08/26/15 01:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540068LABORATORY CONTROL SAMPLE:
LCSSpike
Endrin aldehyde ug/L 0.21.25 86 20-150
gamma-BHC (Lindane)ug/L 0.23.25 94 20-150
Heptachlor ug/L 0.21.25 84 20-150
Decachlorobiphenyl (S)%81 20-130
Tetrachloro-m-xylene (S)%96 20-130
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 28
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/23964
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92264210004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1308144
Associated Lab Samples:92264210004
Matrix: Water
Analyzed
2,4-D ug/L ND 2.0 08/25/15 00:58
2,4-DCAA (S)%99 36-130 08/25/15 00:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1308145LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1310298
2,4-D ug/L 5.16 86 42-1341116.6 25 40
2,4-DCAA (S)%87 36-130108
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 28
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
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Page 25 of 28
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92264210
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92264210004 OEXT/37268 GCSV/223823902-FIELD BLANK EPA 3510 EPA 8081
92264210004 OEXT/23964 GCSV/155713902-FIELD BLANK EPA 8151 EPA 8151
92264210001 MPRP/19312 ICP/173613902-MW4 EPA 3010 EPA 6010
92264210002 MPRP/19312 ICP/173613902-MW5 EPA 3010 EPA 6010
92264210003 MPRP/19312 ICP/173613902-MW6 EPA 3010 EPA 6010
92264210004 MPRP/19312 ICP/173613902-FIELD BLANK EPA 3010 EPA 6010
92264210001 MSV/331153902-MW4 EPA 8260
92264210002 MSV/331153902-MW5 EPA 8260
92264210003 MSV/331153902-MW6 EPA 8260
92264210004 MSV/331153902-FIELD BLANK EPA 8260
92264210005 MSV/331153902-TRIP BLANK EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:38 PM
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[phone]
Page 26 of 28
Page 27 of 28
Page 28 of 28
#=CL#
September 03, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92263797
92263797
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL DISSOLVD H/3R
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 18, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 1 of 34
#=CL#
September 03, 2015
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92263797
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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9800 Kincey Ave. Suite 100
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Page 2 of 34
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174Alabama Certification #: 41320
Connecticut Certification #: PH-0216Delaware Certification: FL NELAC ReciprocityFlorida Certification #: E83079
Georgia Certification #: 955Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC ReciprocityIllinois Certification #: 200068Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC ReciprocityLouisiana Environmental Certificate #: 05007Maryland Certification: #346
Michigan Certification #: 9911Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC ReciprocityNew Hampshire Certification #: 2958New York Certification #: 11608
North Carolina Environmental Certificate #: 667North Carolina Certification #: 12710
Pennsylvania Certification #: 68-00547Puerto Rico Certification #: FL01264South Carolina Certification: #96042001
Tennessee Certification #: TN02974Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC ReciprocityVirginia Environmental Certification #: 460165West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078North Carolina Drinking Water Certification #: 37706North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627Kentucky UST Certification #: 84West Virginia Certification #: 357
Virginia/VELAP Certification #: 460221
Asheville Certification IDs2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001
West Virginia Certification #: 356Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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[phone]
Page 3 of 34
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Lab ID Sample ID Matrix Date Collected Date Received
92263797001 3902-MW1R Water 08/17/15 15:00 08/18/15 10:25
92263797002 3902-MW2R Water 08/17/15 16:50 08/18/15 10:25
92263797003 3902-MW3R Water 08/17/15 17:55 08/18/15 10:25
92263797004 3902-NES-1 Water 08/17/15 18:55 08/18/15 10:25
92263797005 3902-MW3R Water 08/17/15 17:10 08/18/15 10:25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 4 of 34
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92263797005 3902-MW3R EPA 8081 5 PASI-CSWB
EPA 8151 2 PASI-OLJM
EPA 6010 16 PASI-ASH1
EPA 8260 50 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
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Page 5 of 34
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92263797005 3902-MW3R
Antimony 4.8J ug/L 09/01/15 13:016.0EPA 6010
Barium 63.1J ug/L 09/01/15 13:01100EPA 6010
Copper 6.7J ug/L 09/01/15 13:0110.0EPA 6010
Nickel 28.0J ug/L 09/01/15 13:0150.0EPA 6010
Tin 7.5J ug/L 09/01/15 13:01100EPA 6010
Vanadium 3.6J ug/L 09/01/15 13:0125.0EPA 6010
Benzene 0.66J ug/L 08/20/15 17:231.0EPA 8260
Chlorobenzene 17.6 ug/L 08/20/15 17:233.0EPA 8260
Chloroethane 2.0J ug/L 08/20/15 17:2310.0EPA 8260
Chloromethane 0.28J ug/L 08/20/15 17:231.0EPA 8260
1,2-Dichlorobenzene 1.3J ug/L 08/20/15 17:235.0EPA 8260
1,4-Dichlorobenzene 1.1 ug/L 08/20/15 17:231.0EPA 8260
1,2-Dichloroethane 0.33J ug/L 08/20/15 17:231.0EPA 8260
Methylene Chloride 1.6 ug/L 08/20/15 17:23 C91.0EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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Page 6 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Sample: 3902-MW3R Lab ID: 92263797005 Collected: 08/17/15 17:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
gamma-BHC (Lindane)ND ug/L 08/28/15 02:10 58-89-908/24/15 11:400.050 0.050 1
Endrin aldehyde ND ug/L 08/28/15 02:10 7421-93-408/24/15 11:400.10 0.050 1
Heptachlor ND ug/L 08/28/15 02:10 76-44-808/24/15 11:400.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)57 %08/28/15 02:10 877-09-808/24/15 11:4020-130 1
Decachlorobiphenyl (S)79 %08/28/15 02:10 2051-24-308/24/15 11:4020-130 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 08/25/15 02:29 94-75-708/23/15 16:202.0 0.22 1
Surrogates
2,4-DCAA (S)77 %08/25/15 02:29 19719-28-908/23/15 16:2036-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 30106010 ICP Groundwater
Antimony 4.8J ug/L 09/01/15 13:01 7440-36-008/19/15 19:006.0 3.8 1
Arsenic ND ug/L 09/01/15 13:01 7440-38-208/19/15 19:0010.0 2.5 1
Barium 63.1J ug/L 09/01/15 13:01 7440-39-308/19/15 19:00100 2.5 1
Beryllium ND ug/L 09/01/15 13:01 7440-41-708/19/15 19:001.0 0.50 1
Cadmium ND ug/L 09/01/15 13:01 7440-43-908/19/15 19:001.0 0.50 1
Chromium ND ug/L 09/01/15 13:01 7440-47-308/19/15 19:0010.0 2.5 1
Cobalt ND ug/L 09/01/15 13:01 7440-48-408/19/15 19:0010.0 2.5 1
Copper 6.7J ug/L 09/01/15 13:01 7440-50-808/19/15 19:0010.0 2.5 1
Lead ND ug/L 09/01/15 13:01 7439-92-108/19/15 19:0010.0 2.5 1
Nickel 28.0J ug/L 09/01/15 13:01 7440-02-008/19/15 19:0050.0 2.5 1
Selenium ND ug/L 09/01/15 13:01 7782-49-208/19/15 19:0010.0 5.0 1
Silver ND ug/L 09/01/15 13:01 7440-22-408/19/15 19:0010.0 2.5 1
Thallium ND ug/L 09/01/15 13:01 7440-28-008/19/15 19:005.5 5.0 1
Tin 7.5J ug/L 09/01/15 13:01 7440-31-508/19/15 19:00100 2.5 1
Vanadium 3.6J ug/L 09/01/15 13:01 7440-62-208/19/15 19:0025.0 2.5 1
Zinc ND ug/L 09/01/15 13:01 7440-66-608/19/15 19:0010.0 5.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 08/20/15 17:23 67-64-1100 10.0 1
Acrylonitrile ND ug/L 08/20/15 17:23 107-13-1200 1.9 1
Benzene 0.66J ug/L 08/20/15 17:23 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 08/20/15 17:23 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 08/20/15 17:23 75-27-41.0 0.18 1
Bromoform ND ug/L 08/20/15 17:23 75-25-23.0 0.26 1
Bromomethane ND ug/L 08/20/15 17:23 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 08/20/15 17:23 78-93-3100 0.96 1
Carbon disulfide ND ug/L 08/20/15 17:23 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 08/20/15 17:23 56-23-51.0 0.25 1
Chlorobenzene 17.6 ug/L 08/20/15 17:23 108-90-73.0 0.23 1
Chloroethane 2.0J ug/L 08/20/15 17:23 75-00-310.0 0.54 1
Chloroform ND ug/L 08/20/15 17:23 67-66-35.0 0.14 1
Chloromethane 0.28J ug/L 08/20/15 17:23 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 08/20/15 17:23 96-12-813.0 2.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:28 PM
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Page 7 of 34
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Sample: 3902-MW3R Lab ID: 92263797005 Collected: 08/17/15 17:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Dibromochloromethane ND ug/L 08/20/15 17:23 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 08/20/15 17:23 106-93-41.0 0.27 1
Dibromomethane ND ug/L 08/20/15 17:23 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.3J ug/L 08/20/15 17:23 95-50-15.0 0.30 1
1,4-Dichlorobenzene 1.1 ug/L 08/20/15 17:23 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 08/20/15 17:23 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 08/20/15 17:23 75-34-35.0 0.32 1
1,2-Dichloroethane 0.33J ug/L 08/20/15 17:23 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 08/20/15 17:23 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 08/20/15 17:23 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 08/20/15 17:23 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 08/20/15 17:23 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 08/20/15 17:23 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 08/20/15 17:23 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 08/20/15 17:23 100-41-41.0 0.30 1
2-Hexanone ND ug/L 08/20/15 17:23 591-78-650.0 0.46 1
Iodomethane ND ug/L 08/20/15 17:23 74-88-410.0 0.32 1
Methylene Chloride 1.6 ug/L 08/20/15 17:23 75-09-2 C91.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 08/20/15 17:23 108-10-1100 0.33 1
Styrene ND ug/L 08/20/15 17:23 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 08/20/15 17:23 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 08/20/15 17:23 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 08/20/15 17:23 127-18-41.0 0.46 1
Toluene ND ug/L 08/20/15 17:23 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 08/20/15 17:23 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 08/20/15 17:23 79-00-51.0 0.29 1
Trichloroethene ND ug/L 08/20/15 17:23 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 08/20/15 17:23 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 08/20/15 17:23 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 08/20/15 17:23 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 08/20/15 17:23 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 08/20/15 17:23 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)103 %08/20/15 17:23 460-00-470-130 1
1,2-Dichloroethane-d4 (S)108 %08/20/15 17:23 17060-07-070-130 1
Toluene-d8 (S)104 %08/20/15 17:23 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:28 PM
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Page 8 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MPRP/19281
EPA 3010
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92263797005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1537575
Associated Lab Samples:92263797005
Matrix: Water
Analyzed
Antimony ug/L ND 6.0 09/01/15 12:55
Arsenic ug/L ND 10.0 09/01/15 12:55
Barium ug/L ND 100 09/01/15 12:55
Beryllium ug/L ND 1.0 09/01/15 12:55
Cadmium ug/L ND 1.0 09/01/15 12:55
Chromium ug/L ND 10.0 09/01/15 12:55
Cobalt ug/L ND 10.0 09/01/15 12:55
Copper ug/L ND 10.0 09/01/15 12:55
Lead ug/L ND 10.0 09/01/15 12:55
Nickel ug/L ND 50.0 09/01/15 12:55
Selenium ug/L ND 10.0 09/01/15 12:55
Silver ug/L ND 10.0 09/01/15 12:55
Thallium ug/L ND 5.5 09/01/15 12:55
Tin ug/L ND 100 09/01/15 12:55
Vanadium ug/L ND 25.0 09/01/15 12:55
Zinc ug/L ND 10.0 09/01/15 12:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1537576LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 472416 113 80-120
Arsenic ug/L 458416 110 80-120
Barium ug/L 466416 112 80-120
Beryllium ug/L 468416 112 80-120
Cadmium ug/L 465416 112 80-120
Chromium ug/L 474416 114 80-120
Cobalt ug/L 469416 113 80-120
Copper ug/L 476416 114 80-120
Lead ug/L 467416 112 80-120
Nickel ug/L 460416 111 80-120
Selenium ug/L 454416 109 80-120
Silver ug/L 229208 110 80-120
Thallium ug/L 465416 112 80-120
Tin ug/L 468416 112 80-120
Vanadium ug/L 461416 111 80-120
Zinc ug/L 453416 109 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:28 PM
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Page 9 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1537577MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263797005
1537579
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 416 117 75-125114 3 254164.8J 492 479
Arsenic ug/L 416 116 75-125112 3 25416ND482 467
Barium ug/L 416 113 75-125109 3 2541663.1J 532 519
Beryllium ug/L 416 113 75-125111 2 25416ND471 461
Cadmium ug/L 416 114 75-125112 2 25416ND477 466
Chromium ug/L 416 111 75-125109 2 25416ND465 457
Cobalt ug/L 416 108 75-125106 2 25416ND450 440
Copper ug/L 416 117 75-125114 3 254166.7J 494 481
Lead ug/L 416 107 75-125105 2 25416ND446 436
Nickel ug/L 416 106 75-125103 2 2541628.0J 469 458
Selenium ug/L 416 112 75-125109 3 25416ND464 452
Silver ug/L 208 112 75-125110 2 25208ND234 229
Thallium ug/L 416 105 75-125103 1 25416ND437 431
Tin ug/L 416 110 75-125108 2 254167.5J 467 457
Vanadium ug/L 416 111 75-125109 2 254163.6J 465 456
Zinc ug/L 416 104 75-125102 2 25416ND435 427
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 09/03/2015 05:28 PM
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[phone]
Page 10 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
MSV/33081
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92263797005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1538227
Associated Lab Samples:92263797005
Matrix: Water
Analyzed
1,1,1,2-Tetrachloroethane ug/L ND 5.0 08/20/15 15:06
1,1,1-Trichloroethane ug/L ND 1.0 08/20/15 15:06
1,1,2,2-Tetrachloroethane ug/L ND 3.0 08/20/15 15:06
1,1,2-Trichloroethane ug/L ND 1.0 08/20/15 15:06
1,1-Dichloroethane ug/L ND 5.0 08/20/15 15:06
1,1-Dichloroethene ug/L ND 5.0 08/20/15 15:06
1,2,3-Trichloropropane ug/L ND 1.0 08/20/15 15:06
1,2-Dibromo-3-chloropropane ug/L ND 13.0 08/20/15 15:06
1,2-Dibromoethane (EDB)ug/L ND 1.0 08/20/15 15:06
1,2-Dichlorobenzene ug/L ND 5.0 08/20/15 15:06
1,2-Dichloroethane ug/L ND 1.0 08/20/15 15:06
1,2-Dichloropropane ug/L ND 1.0 08/20/15 15:06
1,4-Dichlorobenzene ug/L ND 1.0 08/20/15 15:06
2-Butanone (MEK)ug/L ND 100 08/20/15 15:06
2-Hexanone ug/L ND 50.0 08/20/15 15:06
4-Methyl-2-pentanone (MIBK)ug/L ND 100 08/20/15 15:06
Acetone ug/L ND 100 08/20/15 15:06
Acrylonitrile ug/L ND 200 08/20/15 15:06
Benzene ug/L ND 1.0 08/20/15 15:06
Bromochloromethane ug/L ND 3.0 08/20/15 15:06
Bromodichloromethane ug/L ND 1.0 08/20/15 15:06
Bromoform ug/L ND 3.0 08/20/15 15:06
Bromomethane ug/L ND 10.0 08/20/15 15:06
Carbon disulfide ug/L ND 100 08/20/15 15:06
Carbon tetrachloride ug/L ND 1.0 08/20/15 15:06
Chlorobenzene ug/L ND 3.0 08/20/15 15:06
Chloroethane ug/L ND 10.0 08/20/15 15:06
Chloroform ug/L ND 5.0 08/20/15 15:06
Chloromethane ug/L ND 1.0 08/20/15 15:06
cis-1,2-Dichloroethene ug/L ND 5.0 08/20/15 15:06
cis-1,3-Dichloropropene ug/L ND 1.0 08/20/15 15:06
Dibromochloromethane ug/L ND 3.0 08/20/15 15:06
Dibromomethane ug/L ND 10.0 08/20/15 15:06
Ethylbenzene ug/L ND 1.0 08/20/15 15:06
Iodomethane ug/L ND 10.0 08/20/15 15:06
Methylene Chloride ug/L ND 1.0 08/20/15 15:06
Styrene ug/L ND 1.0 08/20/15 15:06
Tetrachloroethene ug/L ND 1.0 08/20/15 15:06
Toluene ug/L ND 1.0 08/20/15 15:06
trans-1,2-Dichloroethene ug/L ND 5.0 08/20/15 15:06
trans-1,3-Dichloropropene ug/L ND 1.0 08/20/15 15:06
REPORT OF LABORATORY ANALYSIS
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Page 11 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1538227
Associated Lab Samples:92263797005
Matrix: Water
Analyzed
trans-1,4-Dichloro-2-butene ug/L ND 100 08/20/15 15:06
Trichloroethene ug/L ND 1.0 08/20/15 15:06
Trichlorofluoromethane ug/L ND 1.0 08/20/15 15:06
Vinyl acetate ug/L ND 50.0 08/20/15 15:06
Vinyl chloride ug/L ND 1.0 08/20/15 15:06
Xylene (Total)ug/L ND 5.0 08/20/15 15:06
1,2-Dichloroethane-d4 (S)%101 70-130 08/20/15 15:06
4-Bromofluorobenzene (S)%100 70-130 08/20/15 15:06
Toluene-d8 (S)%101 70-130 08/20/15 15:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538228LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 57.750 115 80-125
1,1,1-Trichloroethane ug/L 57.950 116 71-129
1,1,2,2-Tetrachloroethane ug/L 50.950 102 79-124
1,1,2-Trichloroethane ug/L 49.850 100 85-125
1,1-Dichloroethane ug/L 54.350 109 73-126
1,1-Dichloroethene ug/L 60.450 121 66-135
1,2,3-Trichloropropane ug/L 49.750 99 75-130
1,2-Dibromo-3-chloropropane ug/L 51.050 102 71-133
1,2-Dibromoethane (EDB)ug/L 54.850 110 83-124
1,2-Dichlorobenzene ug/L 50.650 101 80-133
1,2-Dichloroethane ug/L 50.050 100 67-128
1,2-Dichloropropane ug/L 52.250 104 75-132
1,4-Dichlorobenzene ug/L 49.850 100 78-130
2-Butanone (MEK)ug/L 106100 106 61-144
2-Hexanone ug/L 111100 111 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 101100 101 48-146
Acrylonitrile ug/L 264250 106 40-160
Benzene ug/L 54.750 109 80-125
Bromochloromethane ug/L 55.550 111 71-125
Bromodichloromethane ug/L 56.350 113 78-124
Bromoform ug/L 51.350 103 71-128
Bromomethane ug/L 57.350 115 40-160
Carbon disulfide ug/L 54.2J50 108 50-160
Carbon tetrachloride ug/L 64.450 129 69-131
Chlorobenzene ug/L 50.550 101 81-122
Chloroethane ug/L 47.750 95 39-148
Chloroform ug/L 53.050 106 73-127
Chloromethane ug/L 61.950 124 44-146
cis-1,2-Dichloroethene ug/L 54.650 109 74-124
cis-1,3-Dichloropropene ug/L 56.550 113 72-132
REPORT OF LABORATORY ANALYSIS
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Page 12 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1538228LABORATORY CONTROL SAMPLE:
LCSSpike
Dibromochloromethane ug/L 61.050 122 78-125
Dibromomethane ug/L 53.450 107 82-120
Ethylbenzene ug/L 51.050 102 79-121
Iodomethane ug/L 121100 121 39-154
Methylene Chloride ug/L 58.750 117 64-133
Styrene ug/L 53.950 108 84-126
Tetrachloroethene ug/L 51.350 103 78-122
Toluene ug/L 50.550 101 80-121
trans-1,2-Dichloroethene ug/L 55.650 111 71-127
trans-1,3-Dichloropropene ug/L 56.950 114 69-141
trans-1,4-Dichloro-2-butene ug/L 54.6J50 109 40-160
Trichloroethene ug/L 51.150 102 78-122
Trichlorofluoromethane ug/L 54.450 109 53-137
Vinyl acetate ug/L 114100 114 40-160
Vinyl chloride ug/L 54.750 109 58-137
Xylene (Total)ug/L 155150 103 81-126
1,2-Dichloroethane-d4 (S)%106 70-130
4-Bromofluorobenzene (S)%102 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1538230MATRIX SPIKE SAMPLE:
MSSpike
Result
92263765006
1,1,1,2-Tetrachloroethane ug/L 33.0 M120165 70-130ND
1,1,1-Trichloroethane ug/L 35.4 M120177 70-130ND
1,1,2,2-Tetrachloroethane ug/L 28.3 M120141 70-130ND
1,1,2-Trichloroethane ug/L 29.5 M120148 70-130ND
1,1-Dichloroethane ug/L 32.4 M120162 70-130ND
1,1-Dichloroethene ug/L 37.2 M120186 70-166ND
1,2,3-Trichloropropane ug/L 28.8 M120144 70-130ND
1,2-Dibromo-3-chloropropane ug/L 29.9 M120150 70-130ND
1,2-Dibromoethane (EDB)ug/L 30.7 M120154 70-130ND
1,2-Dichlorobenzene ug/L 29.6 M120148 70-130ND
1,2-Dichloroethane ug/L 29.1 M120145 70-130ND
1,2-Dichloropropane ug/L 31.0 M120155 70-130ND
1,4-Dichlorobenzene ug/L 28.5 M120142 70-130ND
2-Butanone (MEK)ug/L 70.1J M140175 70-130ND
2-Hexanone ug/L 64.5 M140161 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 61.4J M140153 70-130ND
Acetone ug/L 61.1J M140148 70-130ND
Acrylonitrile ug/L 153J M1100153 70-130ND
Benzene ug/L 32.3 M120161 70-148ND
Bromochloromethane ug/L 32.8 M120164 70-130ND
Bromodichloromethane ug/L 32.7 M120163 70-130ND
Bromoform ug/L 28.9 M120145 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 13 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1538230MATRIX SPIKE SAMPLE:
MSSpike
Result
92263765006
Bromomethane ug/L 17.520 87 70-130ND
Carbon disulfide ug/L 33.2J M120166 70-130ND
Carbon tetrachloride ug/L 39.1 M120196 70-130ND
Chlorobenzene ug/L 29.120 146 70-146ND
Chloroethane ug/L 32.2 M120161 70-130ND
Chloroform ug/L 32.1 M120161 70-130ND
Chloromethane ug/L 29.0 M120144 70-1300.18J
cis-1,2-Dichloroethene ug/L 32.6 M120163 70-130ND
cis-1,3-Dichloropropene ug/L 31.3 M120156 70-130ND
Dibromochloromethane ug/L 32.8 M120164 70-130ND
Dibromomethane ug/L 30.8 M120154 70-130ND
Ethylbenzene ug/L 30.1 M120148 70-1300.42J
Iodomethane ug/L 55.6 M140139 70-130ND
Methylene Chloride ug/L 30.7 M120150 70-130ND
Styrene ug/L 30.3 M120151 70-130ND
Tetrachloroethene ug/L 30.7 M120153 70-130ND
Toluene ug/L 30.320 151 70-155ND
trans-1,2-Dichloroethene ug/L 34.0 M120170 70-130ND
trans-1,3-Dichloropropene ug/L 31.9 M120160 70-130ND
trans-1,4-Dichloro-2-butene ug/L 29.5J M120147 70-130ND
Trichloroethene ug/L 32.2 M120161 69-151ND
Trichlorofluoromethane ug/L 32.7 M120164 70-130ND
Vinyl acetate ug/L 57.7 M140144 70-130ND
Vinyl chloride ug/L 31.4 M120157 70-130ND
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263765005
1538229SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 14 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263765005
1538229SAMPLE DUPLICATE:
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.21J 300.19J
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Ethylbenzene ug/L 0.36J 300.39J
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L 1.1 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%107 1105
4-Bromofluorobenzene (S)%102 1101
Toluene-d8 (S)%102 2101
REPORT OF LABORATORY ANALYSIS
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Page 15 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/37268
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92263797005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1540067
Associated Lab Samples:92263797005
Matrix: Water
Analyzed
Endrin aldehyde ug/L ND 0.10 08/26/15 01:13
gamma-BHC (Lindane)ug/L ND 0.050 08/26/15 01:13
Heptachlor ug/L ND 0.050 08/26/15 01:13
Decachlorobiphenyl (S)%82 20-130 08/26/15 01:13
Tetrachloro-m-xylene (S)%99 20-130 08/26/15 01:13
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1540068LABORATORY CONTROL SAMPLE:
LCSSpike
Endrin aldehyde ug/L 0.21.25 86 20-150
gamma-BHC (Lindane)ug/L 0.23.25 94 20-150
Heptachlor ug/L 0.21.25 84 20-150
Decachlorobiphenyl (S)%81 20-130
Tetrachloro-m-xylene (S)%96 20-130
REPORT OF LABORATORY ANALYSIS
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Page 16 of 34
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
OEXT/23964
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92263797005
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1308144
Associated Lab Samples:92263797005
Matrix: Water
Analyzed
2,4-D ug/L ND 2.0 08/25/15 00:58
2,4-DCAA (S)%99 36-130 08/25/15 00:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1308145LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1310298
2,4-D ug/L 5.16 86 42-1341116.6 25 40
2,4-DCAA (S)%87 36-130108
REPORT OF LABORATORY ANALYSIS
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Page 17 of 34
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Common Laboratory Contaminant.C9
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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Page 18 of 34
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92263797
BUTNER LANDFILL DISSOLVD H/3R
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92263797005 OEXT/37268 GCSV/223823902-MW3R EPA 3510 EPA 8081
92263797005 OEXT/23964 GCSV/155713902-MW3R EPA 8151 EPA 8151
92263797005 MPRP/19281 ICP/173373902-MW3R EPA 3010 EPA 6010
92263797005 MSV/330813902-MW3R EPA 8260
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[phone]
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Page 34 of 34
#=CL#
August 31, 2015
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92263798
92263798
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 18, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
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Page 1 of 36
#=CL#
August 31, 2015
Page 2
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92263798
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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Page 2 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414A2LA Certification #: 2926.01
Alaska Certification #: UST-078Alaska Certification #MN00064Alabama Certification #40770
Arizona Certification #: AZ-0014Arkansas Certification #: 88-0680
California Certification #: 01155CAColorado Certification #PaceConnecticut Certification #: PH-0256
EPA Region 8 Certification #: 8TMS-LFlorida/NELAP Certification #: E87605
Guam Certification #:14-008rGeorgia Certification #: 959Georgia EPD #: Pace
Idaho Certification #: MN00064Hawaii Certification #MN00064
Illinois Certification #: 200011Indiana Certification#C-MN-01Iowa Certification #: 368
Kansas Certification #: E-10167Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062Louisiana DEQ Certification #: 3086Louisiana DHH #: LA140001
Maine Certification #: 2013011Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Minnesota Certification #: 027-053-137Mississippi Certification #: Pace
Montana Certification #: MT0092Nevada Certification #: MN_00064Nebraska Certification #: Pace
New Jersey Certification #: MN-002New York Certification #: 11647
North Carolina Certification #: 530North Carolina State Public Health #: 27700North Dakota Certification #: R-036
Ohio EPA #: 4150Ohio VAP Certification #: CL101
Oklahoma Certification #: 9507Oregon Certification #: MN200001Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563Puerto Rico Certification
Saipan (CNMI) #:MP0003South Carolina #:74003001Texas Certification #: T104704192
Tennessee Certification #: 02818Utah Certification #: MN000642013-4
Virginia DGS Certification #: 251Virginia/VELAP Certification #: PaceWashington Certification #: C486
West Virginia Certification #: 382West Virginia DHHR #:9952C
Wisconsin Certification #: 999407970
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804Florida/NELAP Certification #: E87648Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40South Carolina Certification #: 99030001West Virginia Certification #: 356
Virginia/VELAP Certification #: 460222
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#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Lab ID Sample ID Matrix Date Collected Date Received
92263798001 3902-MW1R Water 08/17/15 13:10 08/18/15 10:25
92263798002 3902-MW2R Water 08/17/15 16:20 08/18/15 10:25
92263798003 3902-MW3R Water 08/17/15 17:10 08/18/15 10:25
92263798004 3902-NES-1 Water 08/17/15 18:25 08/18/15 10:25
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[phone]
Page 4 of 36
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92263798001 3902-MW1R RSK 175 3 PASI-MJRB
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-AEWS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AEWS
SM 5310B 1 PASI-AMDW
92263798002 3902-MW2R RSK 175 3 PASI-MJRB
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-AEWS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AEWS
SM 5310B 1 PASI-AMDW
92263798003 3902-MW3R RSK 175 3 PASI-MJRB
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-AEWS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AEWS
SM 5310B 1 PASI-AMDW
92263798004 3902-NES-1 RSK 175 3 PASI-MJRB
SM 2320B 1 PASI-AMLS
SM 4500-S2D 1 PASI-ASAM
SM 5210B 1 PASI-AEWS
EPA 300.0 1 PASI-AMDW
EPA 353.2 1 PASI-ADMN
SM 4500-Cl-E 1 PASI-AWRC
SM 5220D 1 PASI-AEWS
SM 5310B 1 PASI-AMDW
REPORT OF LABORATORY ANALYSIS
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9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 36
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92263798001 3902-MW1R
Methane 2.7J ug/L 08/21/15 14:1910.0RSK 175
Alkalinity, Total as CaCO3 37800 ug/L 08/19/15 16:505000SM 2320B
BOD, 5 day 2220 ug/L 08/24/15 10:502000SM 5210B
Sulfate 1560J ug/L 08/27/15 10:54 M6250000EPA 300.0
Nitrogen, Nitrate 124J ug/L 08/19/15 10:2110000EPA 353.2
Chloride 4690 ug/L 08/26/15 21:231000SM 4500-Cl-E
Total Organic Carbon 917J ug/L 08/28/15 11:051000SM 5310B
92263798002 3902-MW2R
Methane 2160 ug/L 08/21/15 14:3510.0RSK 175
Alkalinity, Total as CaCO3 772000 ug/L 08/19/15 17:005000SM 2320B
BOD, 5 day 11800 ug/L 08/24/15 10:502000SM 5210B
Sulfate 1310J ug/L 08/27/15 11:08250000EPA 300.0
Chloride 267000 ug/L 08/26/15 21:2415000SM 4500-Cl-E
Chemical Oxygen Demand 110000 ug/L 08/19/15 14:0525000SM 5220D
Total Organic Carbon 32900 ug/L 08/28/15 11:1420000SM 5310B
92263798003 3902-MW3R
Methane 316 ug/L 08/21/15 14:5210.0RSK 175
Alkalinity, Total as CaCO3 664000 ug/L 08/19/15 17:275000SM 2320B
Sulfate 2490J ug/L 08/27/15 11:22250000EPA 300.0
Chloride 178000 ug/L 08/26/15 21:2410000SM 4500-Cl-E
Chemical Oxygen Demand 756000 ug/L 08/19/15 14:0525000SM 5220D
Total Organic Carbon 9860 ug/L 08/28/15 11:475000SM 5310B
92263798004 3902-NES-1
Methane 1.3J ug/L 08/21/15 15:0010.0RSK 175
Alkalinity, Total as CaCO3 10300 ug/L 08/19/15 17:505000SM 2320B
Sulfate 524000J ug/L 08/27/15 00:2662500000EPA 300.0
Nitrogen, Nitrate 3270J ug/L 08/19/15 10:3910000EPA 353.2
Chloride 3900 ug/L 08/26/15 21:251000SM 4500-Cl-E
Total Organic Carbon 27800 ug/L 08/28/15 12:152000SM 5310B
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 6 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Sample: 3902-MW1R Lab ID: 92263798001 Collected: 08/17/15 13:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 08/21/15 14:19 74-84-010.0 5.0 1
Ethene ND ug/L 08/21/15 14:19 74-85-110.0 0.47 1
Methane 2.7J ug/L 08/21/15 14:19 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 37800 ug/L 08/19/15 16:505000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/18/15 17:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 2220 ug/L 08/24/15 10:5008/19/15 05:072000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1560J ug/L 08/27/15 10:54 14808-79-8 M6250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 124J ug/L 08/19/15 10:2110000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4690 ug/L 08/26/15 21:23 16887-00-61000 500 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 08/19/15 14:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 917J ug/L 08/28/15 11:05 7440-44-01000 500 1
REPORT OF LABORATORY ANALYSIS
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9800 Kincey Ave. Suite 100
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Page 7 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Sample: 3902-MW2R Lab ID: 92263798002 Collected: 08/17/15 16:20 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 08/21/15 14:35 74-84-010.0 5.0 1
Ethene ND ug/L 08/21/15 14:35 74-85-110.0 0.47 1
Methane 2160 ug/L 08/21/15 14:35 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 772000 ug/L 08/19/15 17:005000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/18/15 17:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 11800 ug/L 08/24/15 10:5008/19/15 05:072000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1310J ug/L 08/27/15 11:08 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 08/19/15 10:3710000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 267000 ug/L 08/26/15 21:24 16887-00-615000 7500 15
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 110000 ug/L 08/19/15 14:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 32900 ug/L 08/28/15 11:14 7440-44-020000 10000 20
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 8 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Sample: 3902-MW3R Lab ID: 92263798003 Collected: 08/17/15 17:10 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 08/21/15 14:52 74-84-010.0 5.0 1
Ethene ND ug/L 08/21/15 14:52 74-85-110.0 0.47 1
Methane 316 ug/L 08/21/15 14:52 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 664000 ug/L 08/19/15 17:275000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/18/15 17:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 08/24/15 10:5008/19/15 05:072000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 2490J ug/L 08/27/15 11:22 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 08/19/15 10:3810000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 178000 ug/L 08/26/15 21:24 16887-00-610000 5000 10
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 756000 ug/L 08/19/15 14:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 9860 ug/L 08/28/15 11:47 7440-44-05000 2500 5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Sample: 3902-NES-1 Lab ID: 92263798004 Collected: 08/17/15 18:25 Received: 08/18/15 10:25 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175RSK 175 AIR Headspace
Ethane ND ug/L 08/21/15 15:00 74-84-010.0 5.0 1
Ethene ND ug/L 08/21/15 15:00 74-85-110.0 0.47 1
Methane 1.3J ug/L 08/21/15 15:00 74-82-810.0 0.63 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 10300 ug/L 08/19/15 17:505000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 08/18/15 17:00 18496-25-81000 100 1
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 08/24/15 10:5008/19/15 05:072000 2000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 524000J ug/L 08/27/15 00:26 14808-79-862500000250000 250
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 3270J ug/L 08/19/15 10:3910000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3900 ug/L 08/26/15 21:25 16887-00-61000 500 1
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand ND ug/L 08/19/15 14:0525000 12500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 27800 ug/L 08/28/15 12:15 7440-44-02000 1000 2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
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[phone]
Page 10 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
AIR/23944
RSK 175
RSK 175
RSK 175 AIR HEADSPACE
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 2057093
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Ethane ug/L ND 10.0 08/21/15 12:00
Ethene ug/L 1.8J 10.0 08/21/15 12:00
Methane ug/L 2.2J 10.0 08/21/15 12:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
2057094LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
2057095
Ethane ug/L 115114 101 85-115103118 2 20
Ethene ug/L 105106 99 85-115101108 2 20
Methane ug/L 61.460.7 101 85-11510463.0 3 20
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263798001
2057096SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 3.3J 202.7J
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
60200811002
2057097SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 0.82J 201.0J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/39553
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536944
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Alkalinity, Total as CaCO3 ug/L ND 5000 08/19/15 12:52
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536945LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 5000050000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536946MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263817001
1536947
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 90-11096 2 45000053.0 mg/L 102000 101000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536948MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263848001
1536949
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M150000-449 90-110-448 0 450000286 mg/L 61200 61400
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/39539
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536200
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Sulfide ug/L ND 1000 08/18/15 17:00
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536201LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 517J500 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536202MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263798001
1536203
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 95 90-11095 0 10500ND473J 473J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WET/39543
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536643
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
BOD, 5 day ug/L ND 2000 08/24/15 10:50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536644LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 173000198000 87 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92263881001
1536645SAMPLE DUPLICATE:
BOD, 5 day ug/L 262000 9 10286 mg/L
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/24252
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1541561
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Sulfate ug/L ND 250000 08/26/15 19:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1541562LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 20000J20000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1541563MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264348001
1541564
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 92 90-11096 1 102000055.6 mg/L 74100J 74800J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1541565MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263798001
1541566
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M62000060890-110587 10200001560J123000J 119000J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/24166
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536741
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Nitrogen, Nitrate ug/L ND 10000 08/19/15 10:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536742LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2500J2500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536743MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263798001
1536744
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 101 90-110100 1 102500124J2650J 2620J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/24264
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1542020
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Chloride ug/L ND 1000 08/26/15 21:07
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1542021LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2020020000 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542022MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264419004
1542023
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M620000475090-1104740 0 102000087.2 mg/L 1040000 1040000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542024MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264645001
1542025
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 20000 97 90-110101 3 10200003.8 mg/L 23300 24000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/24163
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1536687
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Chemical Oxygen Demand ug/L ND 25000 08/19/15 14:05
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1536688LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 756000750000 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536689MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263743001
1536690
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 94 90-11093 1 375000057.0 mg/L 764000 758000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1536691MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263940001
1536692
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L M115000002890-11028 0 315000002150 mg/L 2560000 2560000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
WETA/24271
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92263798001, 92263798002, 92263798003, 92263798004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1542550
Associated Lab Samples:92263798001, 92263798002, 92263798003, 92263798004
Matrix: Water
Analyzed
Total Organic Carbon ug/L ND 1000 08/27/15 20:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1542551LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2410025000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542552MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92264645001
1542553
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 101 90-110102 1 5250002.4 mg/L 27600 27800
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1542554MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92263798003
1542555
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 100 90-110102 2 525000986034900 35400
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - MinneapolisPASI-M
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92263798
BUTNER LANDFILL MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92263798001 AIR/239443902-MW1R RSK 175
92263798002 AIR/239443902-MW2R RSK 175
92263798003 AIR/239443902-MW3R RSK 175
92263798004 AIR/239443902-NES-1 RSK 175
92263798001 WET/395533902-MW1R SM 2320B
92263798002 WET/395533902-MW2R SM 2320B
92263798003 WET/395533902-MW3R SM 2320B
92263798004 WET/395533902-NES-1 SM 2320B
92263798001 WET/395393902-MW1R SM 4500-S2D
92263798002 WET/395393902-MW2R SM 4500-S2D
92263798003 WET/395393902-MW3R SM 4500-S2D
92263798004 WET/395393902-NES-1 SM 4500-S2D
92263798001 WET/39543 WET/395473902-MW1R SM 5210B SM 5210B
92263798002 WET/39543 WET/395473902-MW2R SM 5210B SM 5210B
92263798003 WET/39543 WET/395473902-MW3R SM 5210B SM 5210B
92263798004 WET/39543 WET/395473902-NES-1 SM 5210B SM 5210B
92263798001 WETA/242523902-MW1R EPA 300.0
92263798002 WETA/242523902-MW2R EPA 300.0
92263798003 WETA/242523902-MW3R EPA 300.0
92263798004 WETA/242523902-NES-1 EPA 300.0
92263798001 WETA/241663902-MW1R EPA 353.2
92263798002 WETA/241663902-MW2R EPA 353.2
92263798003 WETA/241663902-MW3R EPA 353.2
92263798004 WETA/241663902-NES-1 EPA 353.2
92263798001 WETA/242643902-MW1R SM 4500-Cl-E
92263798002 WETA/242643902-MW2R SM 4500-Cl-E
92263798003 WETA/242643902-MW3R SM 4500-Cl-E
92263798004 WETA/242643902-NES-1 SM 4500-Cl-E
92263798001 WETA/241633902-MW1R SM 5220D
92263798002 WETA/241633902-MW2R SM 5220D
92263798003 WETA/241633902-MW3R SM 5220D
92263798004 WETA/241633902-NES-1 SM 5220D
92263798001 WETA/242713902-MW1R SM 5310B
92263798002 WETA/242713902-MW2R SM 5310B
92263798003 WETA/242713902-MW3R SM 5310B
92263798004 WETA/242713902-NES-1 SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..Date: 08/31/2015 03:29 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 36
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Appendix C

Historical Groundwater Analytical Data
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
INORGANICS
Antimony 8-Sep-94 ---30 ND ND ND ND ND ND ------
1-Dec-94 ---30 ND ND ND ND ND ND ------
9-Feb-95 ---30 ND ND ND ND ND ND ------
2-Mar-95 ---30 ND ND ND ND ND ND ------
15-Nov-95 ---30 ND ND ND ND ND ND ------28-May-96 ---30 ND ND ND ND ND ND ------
22-Nov-96 ---30 ND ND ND ND ND ND ------
17-Jun-97 ---30 ND ND ND ND ND ND ------
1-Dec-97 ---30 ND ND ND ND ND ND ------
20-May-98 ---30 ND ND ND ND ND ND ------
19-Nov-98 ---30 ND ND ND ND ND ND ------
21-Jul-99 ---30 ND ND ND ND ND ND ------16-Nov-99 ---30 ND ND ND ND ND ND ------
10-May-00 ---30 ND 80.0 38.0 32.0 33.0 31.0 ------
26-Oct-00 ---30 30.0 ND ND ND ND ND ------
18-Apr-01 ---30 ND ND ND ND ND ND ------
27-Oct-01 ---30 ND ND ND ND ND ND ------
13-Jun-02 ---30 ND ND ND ND ND ND ------
19-Nov-02 ---30 ND ND ND ND ND ND ------27-Jun-03 ---30 ND ND ND ND ND ND ------
30-Dec-03 ---30 ND ND ND ND ND ND ---ND
30-Jun-04 ---30 ND ND ND ND ND ND ---ND
29-Dec-04 ---30 ND ND ND ND ND ND ---ND
29-Jun-05 ---30 ND ND ND ND ND ND ---ND
29-Dec-05 ---30 ND ND ND ND ND ND ---ND
28-Jun-06 ---30 ND ND ND ND ND ND ---ND29-Dec-06 ---6 ND ND ND ND ND ND ---ND
12-Jul-07 ---6 ND ND ND ND ND ND ---ND
GWPS = 1.4 µg/L (10/23/07)19-Dec-07 ---6 ND ND ND ND ND ND ND ND
8-Jul-08 ---6 ND ND ND ND ND ND ---ND
17-Dec-08 2.6 6.0 ND ND ND ND ND ND ---ND
9-Jul-09 2.6 6.0 ND ND ND ND ND ND ND ND
16-Dec-09 2.6 6.0 ND ND ND ND ND ND ---NDNC 2B = NE (03/24/10)24-Jun-10 2.6 6.0 ND ND ND 2.9 J ND ND ---ND
GWPS = 1 µg/L (8/1/10)13-Dec-10 2.6 6.0 ND ND 3.0 J ND 2.8 J ND ---ND
20-Jun-11 5.0 6.0 ND ND ND ND 6.0 ND ---ND
5-Dec-11 5.0 6.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 6.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 6.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 6.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 6.0 ND ND ND ND ND ND ---ND
24-Feb-14 5.0 6.0 8.8 ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 6.0 ND 10.5 8.0 ND ND ND ---ND
10-Mar-15 EPA 6010 3.8 6.0 ND 7.1 6.5 3.9 J ND ND ---ND
18-Aug-15 EPA 6010 3.8 6.0 ND 6.2 4.8 J 4.1 J ND ND ---ND
Arsenic 8-Sep-94 ---10 ND ND ND ND ND ND ------1-Dec-94 ---10 ND ND ND ND ND ND ------
9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------
22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 6.0 J 15.0 ND ND ND ND ------1-Dec-97 ---10 ND 5.0 J ND ND ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 2.0 J ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 4.1 J ND ND ND ND ND ND
8-Jul-08 ---10 ND 4.9 J ND ND ND ND ---ND
17-Dec-08 2.7 10.0 ND ND ND ND ND ND ---ND
9-Jul-09 2.7 10.0 ND 13.5 10.9 5.6 J ND 4.0 J ND ND
16-Dec-09 2.7 10.0 ND 10.6 6.4 J 5.0 J ND 3.6 J ---ND
NC 2L = 10 µg/L (02/05/10)24-Jun-10 2.7 10.0 ND 11.8 8.1 J 8.2 J 3.3 J 3.1 J ---ND
Resample >12-Aug-10 2.7 10.0 ------7.2 J ------------ND
Resample >31-Aug-10 2.7 10.0 ---15.4 ---------------ND
13-Dec-10 2.7 10.0 ND 4.9 J 2.7 J 5.4 J ND ND ---ND
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND 5.4 J ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND 5.6 J ND ND ND ---ND
24-Feb-14 5.0 10.0 ND 6.4 J ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 4.1 J 5.4 J ND ND 3.1 J 3.2 J ---3.0 J
18-Aug-15 EPA 6011 2.5 10.0 ND 5.1 J ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 1 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Barium 8-Sep-94 ---500 ND 270 ND ND 830 860 ------
1-Dec-94 ---500 ND ND ND ND ND ND ------
9-Feb-95 ---500 ND ND ND ND 510 ND ------
2-Mar-95 ---500 ND ND ND ND ND ND ------
15-Nov-95 ---500 ND ND ND ND ND ND ------
28-May-96 ---500 ND ND ND ND ND ND ------22-Nov-96 ---500 ND 82.0 30.0 ND 15.0 ND ------
17-Jun-97 ---500 200 320 37.0 17.0 210 31.0 ------
1-Dec-97 ---500 61.0 180 43.0 46.0 220 33.0 ------
20-May-98 ---500 30.0 150 45.0 13.0 180 22.0 ------
19-Nov-98 ---500 48.0 120 42.0 ND 380 12.0 ------
21-Jul-99 ---500 ND ND ND ND ND ND ------
16-Nov-99 ---500 ND ND ND ND ND ND ------10-May-00 ---500 ND ND ND ND ND ND ------
26-Oct-00 ---500 ND ND ND ND ND ND ------
18-Apr-01 ---500 ND ND ND ND ND ND ------
27-Oct-01 ---500 ND ND ND ND ND ND ------
13-Jun-02 ---500 ND ND ND ND ND ND ------
19-Nov-02 ---500 ND ND ND ND ND ND ------
27-Jun-03 ---500 ND ND ND ND ND ND ------30-Dec-03 ---500 ND ND ND ND ND ND ---ND
30-Jun-04 ---500 ND ND ND ND ND ND ---ND
29-Dec-04 ---500 ND ND ND ND ND ND ---ND29-Dec-04 ---500 ND ND ND ND ND ND ---ND
29-Jun-05 ---500 ND ND ND ND ND ND ---ND
29-Dec-05 ---500 ND ND ND ND ND ND ---ND
28-Jun-06 ---500 ND ND ND ND ND ND ---ND29-Dec-06 ---100 5.2 J 120 64.9 1.5 J 64.1 1.8 J ---0.20 J
12-Jul-07 ---100 2.5 J 129 65.7 J 1.1 J 77.0 J 1.3 J ---ND
NC 2L = 2,000 µg/L (10/23/07)19-Dec-07 ---100 2.8 B 99.2 50.0 B 1.4 B 49.6 B 1.7 B 87.8 11.7
8-Jul-08 ---100 5.8 J 102 58.4 J 1.1 B 57.9 J 1.2 B ---0.29 J
17-Dec-08 0.20 100 2.7 B 92.9 J 53.1 B 1.2 B 55.5 J 1.1 B ---10.7 J
9-Jul-09 0.20 100 4.6 B 121 63.4 B 0.37 B 81.4 B 0.94 B 72.4 B 17.6 J
16-Dec-09 0.20 100 2.9 B 108 62.8 B 0.61 B 56.8 B 0.87 B ---17.1 JNC 2L = 700 µg/L (02/05/10)24-Jun-10 0.20 100 2.5 B 115 B 61.1 B 1.6 B 93.5 B 1.4 B ---27.3 J
13-Dec-10 0.20 100 4.3 B 122 67.9 J 1.3 B 90.6 J 1.5 B ---12.1 J
20-Jun-11 5.0 100 ND 108 70.7 J ND 84.7 J ND ---ND
5-Dec-11 5.0 100 ND 118 73.0 J ND 90.6 J ND ---ND
11-Jun-12 5.0 100 ND 138 65.2 J ND 76.4 J ND 61.3 J ND
12-Dec-12 5.0 100 ND 113 64.7 J ND 73.6 J ND ---ND
1-May-13 5.0 100 ND 118 69.1 J ND 84.2 J ND 81.2 J ND5-Aug-13 5.0 100 ND 111 65.1 J ND 95.6 J ND ---ND
24-Feb-14 5.0 100 ND 93.8 J 44.8 J ND 139 ND ND ND
12-Aug-14 EPA 6010 5.0 100 ND 125 66.4 J ND 121 ND ---ND
10-Mar-15 EPA 6010 2.5 100 3.0 J 109 61.8 J ND 116 ND ---ND
18-Aug-15 EPA 6010 2.5 100 4.4 J 119 63.1 J ND 81.3 J ND ---ND
Beryllium 8-Sep-94 ---2 ND ND ND ND ND ND ------1-Dec-94 ---2 ND ND ND ND 4.0 ND ------
9-Feb-95 ---2 ND ND ND ND ND ND ------
2-Mar-95 ---2 ND ND ND ND 2.0 ND ------
15-Nov-95 ---2 ND ND ND ND ND ND ------
28-May-96 ---2 ND ND ND ND 6.0 ND ------
22-Nov-96 ---2 ND ND ND ND 3.0 ND ------
17-Jun-97 ---2 2.0 3.0 ND ND 1.0 ND ------1-Dec-97 ---2 ND ND ND ND ND ND ------
20-May-98 ---2 ND ND ND ND ND ND ------
19-Nov-98 ---2 ND ND ND ND 2.0 ND ------
21-Jul-99 ---2 ND ND ND ND ND ND ------
16-Nov-99 ---2 ND ND ND ND ND ND ------
10-May-00 ---2 ND ND ND ND ND ND ------
26-Oct-00 ---2 ND ND ND ND ND ND ------18-Apr-01 ---2 ND 12.0 ND ND ND ND ------
27-Oct-01 ---2 ND ND ND ND ND ND ------
13-Jun-02 ---2 ND ND ND ND ND ND ------
19-Nov-02 ---2 ND ND ND ND ND ND ------
27-Jun-03 ---2 ND ND ND ND ND ND ------30-Dec-03 ---2 ND ND ND ND ND ND ---ND
30-Jun-04 ---2 ND ND ND ND ND ND ---ND
29-Dec-04 ---2 ND ND ND ND ND ND ---ND29-Dec-04 ---2 ND ND ND ND ND ND ---ND
29-Jun-05 ---2 ND ND ND ND ND ND ---ND
29-Dec-05 ---2 ND ND ND ND ND ND ---ND
28-Jun-06 ---2 ND ND ND ND ND ND ---ND29-Dec-06 ---1 ND ND ND ND ND ND ---ND
12-Jul-07 ---1 ND ND ND ND ND ND ---ND
GWPS = 4 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND
8-Jul-08 ---1 ND ND ND ND ND ND ---ND
17-Dec-08 0.10 1.0 ND ND ND ND 0.14 J ND ---ND
9-Jul-09 0.10 1.0 ND 0.18 J 0.22 J 0.17 J ND ND 0.23 J ND
16-Dec-09 0.10 1.0 ND 0.15 J 0.17 J 0.15 J 0.25 J ND ---NDNC 2B = 6.5 µg/L (02/05/10)24-Jun-10 0.10 1.0 ND ND 0.27 J 0.16 J ND ND ---ND
13-Dec-10 0.10 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND
1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cadmium 8-Sep-94 ---1 ND ND ND ND ND 4.0 ------
1-Dec-94 ---1 ND ND ND ND ND ND ------
9-Feb-95 ---1 ND ND ND ND ND ND ------
2-Mar-95 ---1 ND ND ND ND ND ND ------
15-Nov-95 ---1 ND ND ND ND ND ND ------
28-May-96 ---1 ND ND ND ND ND ND ------22-Nov-96 ---1 ND ND ND ND ND ND ------
17-Jun-97 ---1 ND 3.0 1.0 ND ND ND ------
1-Dec-97 ---1 ND 2.0 ND ND ND ND ------
20-May-98 ---1 ND ND ND ND ND ND ------
19-Nov-98 ---1 ND ND ND ND ND ND ------
21-Jul-99 ---1 ND ND ND ND ND ND ------
16-Nov-99 ---1 ND 3.0 3.0 ND 2.0 ND ------10-May-00 ---1 5.0 ND ND ND ND ND ------
26-Oct-00 ---1 ND 2.0 ND ND ND ND ------
18-Apr-01 ---1 ND 11.0 ND ND ND ND ------
27-Oct-01 ---1 ND ND ND ND ND ND ------
13-Jun-02 ---1 ND 2.0 ND ND ND ND ------
19-Nov-02 ---1 2.0 2.0 ND ND 2.0 ND ------
27-Jun-03 ---1 ND ND ND ND ND ND ------30-Dec-03 ---1 ND 1.0 ND ND ND ND ---ND
30-Jun-04 ---1 ND ND ND ND ND ND ---ND
29-Dec-04 ---1 ND ND ND ND ND ND ---ND29-Jun-05 ---1 ND ND ND ND ND ND ---ND
29-Dec-05 ---1 ND ND ND ND ND ND ---ND28-Jun-06 ---1 ND ND ND ND ND ND ---ND
29-Dec-06 ---1 ND ND ND ND ND ND ---ND12-Jul-07 ---1 ND ND ND ND ND ND ---ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND
8-Jul-08 ---1 ND ND ND ND ND ND ---ND
17-Dec-08 0.50 1.0 ND ND ND ND ND ND ---ND
9-Jul-09 0.50 1.0 ND 1.4 ND ND ND ND ND ND
16-Dec-09 0.50 1.0 ND ND ND ND ND ND ---ND
NC 2L = 2 µg/L (02/05/10)24-Jun-10 0.50 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.50 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND
1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
Chromium 8-Sep-94 ---10 8.0 44.0 ND 6.0 48.0 80.0 ------
1-Dec-94 ---10 14.0 ND ND ND 18.0 ND ------9-Feb-95 ---10 14.0 ND ND 10.0 ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 13.0 13.0 ND ND ND ND ------
28-May-96 ---10 33.0 ND ND ND ND ND ------
22-Nov-96 ---10 3.0 ND ND ND ND 3.0 ------
17-Jun-97 ---10 57.0 43.0 ND 3.0 2.0 6.0 ------
1-Dec-97 ---10 29.0 ND ND ND ND ND ------20-May-98 ---10 10.0 3.0 ND ND 12.0 ND ------
19-Nov-98 ---10 17.0 3.0 ND ND 5.0 ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND 12.0 ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND
28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 2.0 B ND ND ND ND 1.1 B 1.4 J
8-Jul-08 ---10 ND 0.54 J 0.58 J ND ND ND ---ND
17-Dec-08 0.40 10.0 0.73 J 1.8 J 0.96 J ND 0.96 J 0.70 J ---ND
9-Jul-09 0.40 10.0 1.2 J 2.4 J 1.1 J 1.6 J 0.68 J 0.53 J 4.8 J ND
16-Dec-09 0.40 10.0 1.3 J ND ND ND 0.95 J ND ---ND
NC 2L = 10 µg/L (02/05/10)24-Jun-10 0.40 10.0 1.1 B 3.5 B 2.8 B 2.4 B 1.2 B 1.4 B ---0.71 J
13-Dec-10 0.40 10.0 2.5 J 1.3 J 1.8 J 0.69 J 0.57 J 1.2 J ---ND20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND 8.6 J ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND 5.2 J ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND
24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND 2.7 J ND ND ND 6.7 J ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cobalt 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 11.0 ND 13.0 16.0 22.0 ND ------
9-Feb-95 ---10 20.0 14.0 ND 48.0 39.0 ND ------
2-Mar-95 ---10 16.0 21.0 ND 29.0 121.0 ND ------
15-Nov-95 ---10 20.0 21.0 ND ND 27.0 ND ------
28-May-96 ---10 30.0 16.0 ND ND 122 ND ------22-Nov-96 ---10 6.0 13.0 ND 4.7 93.0 ND ------
17-Jun-97 ---10 130 38.0 ND 6.0 45.0 3.0 ------
1-Dec-97 ---10 32.0 21.0 ND 12.0 36.0 4.0 ------
20-May-98 ---10 15.0 16.0 2.0 9.0 100 3.0 ------
19-Nov-98 ---10 21.0 16.0 2.0 7.0 180 3.0 ------
21-Jul-99 ---10 ND 16.0 ND ND 100 ND ------
16-Nov-99 ---10 ND 15.0 ND ND 38.0 ND ------10-May-00 ---10 ND 17.0 ND ND 61.0 ND ------
26-Oct-00 ---10 ND 15.0 ND ND ND ND ------
18-Apr-01 ---10 ND 27.0 ND ND 74.0 ND ------
27-Oct-01 ---10 ND 12.0 ND ND 47.0 ND ------
13-Jun-02 ---10 ND 14.0 ND ND 251 ND ------
19-Nov-02 ---10 ND 10.0 ND ND 57.0 ND ------
27-Jun-03 ---10 ND 15.0 ND ND 75.0 ND ------30-Dec-03 ---10 ND 17.0 ND ND 52.0 ND ---ND
30-Jun-04 ---10 ND 16.0 ND ND 31.0 ND ---ND
29-Dec-04 ---10 ND 11.0 ND ND 46.0 ND ---ND29-Jun-05 ---10 ND 11.0 ND ND 43.0 ND ---ND
29-Dec-05 ---10 ND 12.0 ND ND 30.0 ND ---ND28-Jun-06 ---10 ND ND ND ND 72.5 ND ---ND
29-Dec-06 ---10 ND 11.4 ND ND 37.5 ND ---ND12-Jul-07 ---10 ND 11.8 ND 2.7 58.4 ND ---ND
GWPS = 70 µg/L (10/23/07)19-Dec-07 ---10 2.5 B ND ND 2.0 B 103 2.6 B 8.0 B 1.8 J
8-Jul-08 ---10 10.3 B 12.1 B 2.0 B 9.0 B 130 4.8 B ---6.2 J
17-Dec-08 0.60 10.0 2.1 B 11.8 B 2.3 B 3.6 B 43.7 1.6 B ---2.5 J
9-Jul-09 0.60 10.0 ND 6.2 J ND ND 100 ND 2.2 J ND
16-Dec-09 0.60 10.0 ND 4.7 J ND ND 6.6 J ND ---ND
24-Jun-10 0.60 10.0 ND 16.3 ND ND 25.0 ND ---NDGWPS = 1 µg/L (2/05/10)13-Dec-10 0.60 10.0 2.5 B 15.5 ND ND {129}{ND}---1.6 {1.0 J}J
20-Jun-11 5.0 10.0 ND 14.2 ND ND 81.8 ND ---ND
5-Dec-11 5.0 10.0 ND 12.7 ND ND 146 ND ---ND
Resample >25-Jan-12 5.0 10.0 ------------47.5 ------ND
11-Jun-12 5.0 10.0 ND 14.2 ND ND 101 ND ND ND
12-Dec-12 5.0 10.0 ND 11.3 ND ND 113 ND ---ND
1-May-13 5.0 10.0 ND 24.3 ND ND 34.0 ND ND ND5-Aug-13 5.0 10.0 ND 24.7 ND ND 50.9 ND ---ND
24-Feb-14 5.0 10.0 ND 18.4 ND ND 9.6 J ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND 9.4 J ND ND 46.3 ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND 8.7 J ND ND 39.2 ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND 9.3 J ND ND 116 ND ---ND
Copper 8-Sep-94 ---200 ND ND ND ND ND 660 ------1-Dec-94 ---200 ND ND ND ND ND ND ------
9-Feb-95 ---200 ND ND ND ND ND ND ------
2-Mar-95 ---200 ND ND ND ND ND ND ------
15-Nov-95 ---200 ND ND ND ND ND ND ------
28-May-96 ---200 ND ND ND ND ND ND ------
22-Nov-96 ---200 ND ND 32.0 13.0 100 ND ------
17-Jun-97 ---200 34.0 350 13.0 37.0 28.0 77.0 ------1-Dec-97 ---200 19.0 72.0 14.0 88.0 15.0 34.0 ------
20-May-98 ---200 12.0 48.0 380 41.0 53.0 28.0 ------
19-Nov-98 ---200 10.0 ND 410 28.0 53.0 14.0 ------
21-Jul-99 ---200 ND ND ND ND ND ND ------
16-Nov-99 ---200 ND ND ND ND ND ND ------
10-May-00 ---200 ND ND ND ND ND ND ------
26-Oct-00 ---200 ND ND ND ND ND ND ------18-Apr-01 ---200 ND ND ND ND ND ND ------
27-Oct-01 ---200 ND ND ND ND ND ND ------
13-Jun-02 ---200 ND ND ND ND ND ND ------
19-Nov-02 ---200 ND ND ND ND ND ND ------
27-Jun-03 ---200 ND ND ND ND ND ND ------30-Dec-03 ---200 ND ND ND ND ND ND ---ND
30-Jun-04 ---200 ND ND ND ND ND ND ---ND
29-Dec-04 ---200 ND ND ND ND ND ND ---ND29-Jun-05 ---200 ND ND ND ND ND ND ---ND
29-Dec-05 ---200 ND ND ND ND ND ND ---ND28-Jun-06 ---200 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND 11.3 5.50 J 10.4 1.90 B ---0.60 J12-Jul-07 ---10 ND ND 13.4 7.90 2.6 J ND ---ND
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---10 2.0 B ND 8.6 B 3.8 B 7.0 B 0.73 B 5.8 B 9.8
8-Jul-08 ---10 0.64 J ND 12.1 3.7 J 8.5 J ND ---ND
17-Dec-08 0.30 10.0 0.80 J 13.6 10.2 3.9 J 11.9 0.37 J ---ND
9-Jul-09 0.30 10.0 ND ND 6.3 J ND 5.7 J ND 8.8 J ND
16-Dec-09 0.30 10.0 ND ND 9.2 J 1.6 J 5.7 J ND ---ND
24-Jun-10 0.30 10.0 ND ND 10 1.2 J 5.1 J ND ---ND13-Dec-10 0.30 10.0 1.1 B ND 13.6 5.8 J 5.6 J 0.59 B ---0.49 J
20-Jun-11 5.0 10.0 ND ND 15.3 8.1 J 8.7 J ND ---ND
5-Dec-11 5.0 10.0 ND ND 16.9 10.0 J 7.6 J ND ---ND
11-Jun-12 5.0 10.0 ND 10.7 12.2 6.3 J 7.4 J ND ND ND
12-Dec-12 5.0 10.0 ND ND 11.6 8.5 J 10.4 ND ---ND1-May-13 5.0 10.0 ND ND 13.6 5.8 J 9.6 J ND ND ND
5-Aug-13 5.0 10.0 ND ND 14.3 ND 10.2 ND ---ND24-Feb-14 5.0 10.0 ND ND 12.2 ND 5.1 J ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND 10.5 ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND 8.7 J ND 15.5 ND ---ND18-Aug-15 EPA 6010 2.5 10.0 ND ND 6.7 J 5.6 J 10.1 ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Lead 8-Sep-94 ---10 ND 13.0 ND ND 30.0 36.0 ------
1-Dec-94 ---10 11.0 ND ND ND 36.0 ND ------
9-Feb-95 ---10 ND ND ND 10.0 37.0 ND ------
2-Mar-95 ---10 ND ND ND ND 44.0 ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND 42.0 ND ------22-Nov-96 ---10 ND ND ND ND 13.0 ND ------
17-Jun-97 ---10 20.0 29.0 ND ND 13.0 ND ------
1-Dec-97 ---10 8.0 14.0 ND 5.0 14.0 ND ------
20-May-98 ---10 ND 6.0 ND 6.0 21.0 ND ------
19-Nov-98 ---10 5.0 ND ND ND 58.0 ND ------
21-Jul-99 ---10 ND 12.0 14.0 ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 11.0 ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND 12.0 ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND 2.1 J ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 15 µg/L (10/23/07)19-Dec-07 ---10 ND ND ND ND ND ND ND ND
8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 4.0 10.0 ND ND ND ND ND ND ---ND
9-Jul-09 4.0 10.0 ND ND ND ND ND ND ND ND
16-Dec-09 4.0 10.0 ND ND ND ND ND ND ---ND
24-Jun-10 4.0 10.0 ND ND ND ND ND ND ---ND13-Dec-10 4.0 10.0 ND ND ND ND ND ND ---ND
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Mercury 1-Dec-97 ---0.5 ND ND ND ND ND ND ------
19-Nov-98 ---0.5 ND ND ND ND ND ND ------16-Nov-99 ---0.5 ND 0.59 0.65 0.65 0.76 ND ------
10-May-00 ---0.5 ---ND ND ND ND ---------
26-Oct-00 ---0.5 ---ND ND ND ND ---------
18-Apr-01 ---0.5 ---ND ND ND ND ---------
13-Jun-02 ---0.5 ---ND ND ND ND ---------
27-Jun-03 ---0.5 ---ND ND ND ND ---------
30-Dec-03 ---0.5 ------------------------30-Jun-04 ---0.5 ND ND ND ND ND ND ---ND
29-Dec-04 ------------------------------
29-Jun-05 ---0.5 ND ND ND ND ND ND ---ND29-Dec-05 ------------------------------
28-Jun-06 ---2 ND ND ND ND ND ND ---ND
29-Dec-06 ------------------------------
12-Jul-07 ---0.2 ND ND ND ND ND ND ---NDNC 2L = 1.05 µg/L (10/23/07)19-Dec-07 ------------------------ND ---
8-Jul-08 ---0.2 ND ND ND ND ND ND ---ND
17-Dec-08 ------------------------------
9-Jul-09 0.070 0.2 ND ND ND ND ND ND ---ND
16-Dec-09 ------------------------------NC 2L = 1 µg/L (02/05/10)24-Jun-10 0.070 0.20 ND ND ND ND ND 0.098 J ---ND
13-Dec-10 ------------------------------
20-Jun-11 0.10 0.20 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 0.10 0.20 ND ND ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 0.10 0.20 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.10 0.20 ND ND ND ND ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 7470 0.10 0.20 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Nickel 8-Sep-94 ---50 ND ND ND ND ND ND ------
1-Dec-94 ---50 ND ND ND ND ND ND ------
9-Feb-95 ---50 ND 72 ND ND ND ND ------
2-Mar-95 ---50 ND 100 ND ND ND ND ------
15-Nov-95 ---50 ND 61.0 ND ND ND ND ------
28-May-96 ---50 ND 85.0 ND ND ND ND ------22-Nov-96 ---50 ND 72.0 ND ND ND ND ------
17-Jun-97 ---50 75 98.0 ND ND ND ND ------
1-Dec-97 ---50 ND 89.0 ND ND ND ND ------
20-May-98 ---50 ND 91.0 ND ND ND ND ------
19-Nov-98 ---50 ND 83.0 ND ND ND ND ------
21-Jul-99 ---50 ND 109 ND ND ND ND ------
16-Nov-99 ---50 ND 122 ND ND ND ND ------10-May-00 ---50 ND 104 ND ND ND ND ------
26-Oct-00 ---50 ND 93.0 ND ND ND ND ------
18-Apr-01 ---50 ND 107 ND ND ND ND ------
27-Oct-01 ---50 ND 92.0 ND ND ND ND ------
13-Jun-02 ---50 ND 98.0 ND ND ND ND ------
19-Nov-02 ---50 ND 74.0 ND ND ND ND ------
27-Jun-03 ---50 ND 85.0 ND ND ND ND ------30-Dec-03 ---50 ND 100 ND ND ND ND ---ND
30-Jun-04 ---50 ND 120 (81.0)ND ND ND ND ---ND
29-Dec-04 ---50 ND 100 ND ND ND ND ---ND29-Jun-05 ---50 ND 150 (92.0)ND ND ND ND ---ND
29-Dec-05 ---50 ND 96.0 ND ND ND ND ---ND28-Jun-06 ---50 ND 88.7 ND ND ND ND ---ND
29-Dec-06 ---50 ND 94.7 30.1 14.2 8.9 J ND ---ND12-Jul-07 ---50 ND 99.0 30.6 J 13.9 J 13.7 J ND ---ND
NC 2L = 100 µg/L (10/23/07)19-Dec-07 ---50 ND 83.4 23.7 11.0 18.3 ND 11.4 ND
8-Jul-08 ---50 ND 76.0 28.1 J 11.5 J 27.0 J ND ---ND
17-Dec-08 1.7 50.0 ND 75.5 27.8 J 12.2 J 11.0 B ND ---2.4 J
9-Jul-09 1.7 50.0 2.2 J 93.5 29.4 J 11.7 J 23.2 J ND 13.1 J ND
16-Dec-09 1.7 50.0 ND 81.2 28.2 J 11.8 B 2.6 B ND ---3.0 J
24-Jun-10 1.7 50.0 ND 76.3 19.7 J 9.0 J 7.0 J 4.5 J ---ND13-Dec-10 1.7 50.0 ND 83.0 23.5 J 6.8 B 20.7 J ND ---2.7 J
20-Jun-11 5.0 50.0 ND 78.8 30.1 J 11.2 J 15.3 J ND ---ND
5-Dec-11 5.0 50.0 ND 89.1 32.8 J 11.7 J 24.3 J ND ---ND
11-Jun-12 5.0 50.0 ND 91.8 28.9 J 10.0 J 17.3 J ND ND ND
12-Dec-12 5.0 50.0 ND 91.8 29.2 J 9.3 J 21.1 J ND ---ND
1-May-13 5.0 50.0 ND 89.6 31.9 J 10.4 J 5.7 J ND ND ND
5-Aug-13 5.0 50.0 ND 87.9 28.1 J 9.0 J 8.4 J ND ---ND24-Feb-14 5.0 50.0 ND 83.1 16.7 J 10.4 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 50.0 ND 97.9 29 J 12.9 J 13.2 J ND ---ND
10-Mar-15 EPA 6010 2.5 50.0 ND 91.9 32.9 J 12.3 J 8.2 J ND ---ND
18-Aug-15 EPA 6010 2.5 50.0 ND 98.0 28.0 J 11.9 J 26.2 J 5.4 J ---ND
Selenium 8-Sep-94 ---20 ND ND ND ND ND ND ------
1-Dec-94 ---20 ND ND ND ND ND ND ------9-Feb-95 ---20 ND ND ND ND ND ND ------
2-Mar-95 ---20 ND ND ND ND ND ND ------
15-Nov-95 ---20 ND ND ND ND ND ND ------
28-May-96 ---20 ND ND ND ND ND ND ------
22-Nov-96 ---20 ND ND ND ND ND ND ------
17-Jun-97 ---20 ND ND ND ND ND ND ------
1-Dec-97 ---20 ND ND ND ND ND ND ------20-May-98 ---20 ND ND ND ND ND ND ------
19-Nov-98 ---20 ND ND ND ND ND ND ------
21-Jul-99 ---20 ND ND ND ND 36.0 ND ------
16-Nov-99 ---20 ND ND ND ND ND ND ------
10-May-00 ---20 ND ND ND ND ND ND ------
26-Oct-00 ---20 ND ND ND ND ND ND ------
18-Apr-01 ---20 ND ND ND ND ND ND ------27-Oct-01 ---20 ND ND ND ND ND ND ------
13-Jun-02 ---20 ND ND ND ND ND ND ------
19-Nov-02 ---20 ND ND ND ND ND ND ------
27-Jun-03 ---20 ND ND ND ND ND ND ------
30-Dec-03 ---20 ND ND ND ND ND ND ---ND30-Jun-04 ---20 ND ND ND ND ND ND ---ND
29-Dec-04 ---20 ND ND ND ND ND ND ---ND
29-Jun-05 ---20 ND ND ND ND ND ND ---ND29-Dec-05 ---20 ND ND ND ND ND ND ---ND
28-Jun-06 ---20 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---NDNC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 11.5 ND ND ND ND ND ND
8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 3.8 10 4.8 B 5.1 B 4.8 B ND ND ND ---4.9 J
9-Jul-09 3.8 10 ND ND 4.2 J ND ND ND ND ND
16-Dec-09 3.8 10 ND ND ND 5.1 J ND ND ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 3.8 10 ND ND ND ND ND ND ---ND
13-Dec-10 3.8 10 ND ND ND ND ND ND ---ND20-Jun-11 10.0 10 ND ND ND ND ND ND ---ND
5-Dec-11 10.0 10 ND ND ND ND ND ND ---ND
11-Jun-12 10.0 10 ND ND ND ND ND ND ND ND
12-Dec-12 10.0 10 ND ND ND ND ND ND ---ND
1-May-13 10.0 10 ND ND ND ND ND ND ND ND
5-Aug-13 10.0 10 ND ND ND ND ND ND ---ND
24-Feb-14 10.0 10 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 10.0 10 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Silver 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 ND ND ND ND ND ND ------
9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND ND ND ND ND ND ------
1-Dec-97 ---10 ND 8.0 ND ND ND 3 ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND 15.0 ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 17.5 µg/L (10/23/07)19-Dec-07 ---10 ND 0.57 J 0.60 J 0.55 J ND 0.33 J ND ND
8-Jul-08 ---10 ND 2.7 J 2.3 J 1.1 J 0.22 J 0.69 J ---0.12 J
17-Dec-08 0.10 10.0 0.13 J 1.8 J 1.4 J 0.85 J 0.12 J 0.51 J ---ND
9-Jul-09 0.10 10.0 ND 0.84 J 0.63 J 0.45 J ND 0.11 J ND ND
16-Dec-09 0.10 10.0 0.12 J 2.0 J 1.6 J 1.0 J 0.12 J 0.52 J ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 0.10 10.0 ND 0.38 J 0.33 J 0.35 J ND ND ---ND13-Dec-10 0.10 10.0 0.15 B 1.3 J 0.99 J 0.45 B {ND}{ND}---0.21 {0.19 J}J
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Thallium 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 ND ND ND ND ND ND ------9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------
22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND 3.0 ND ND ND ND ------
1-Dec-97 ---10 ND ND ND ND ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND 10 J (ND)ND ND ND ND ---ND
29-Jun-05 ---10 ND 22.0 (30.0)13.0 (24.0)ND ND ND ---ND29-Dec-05 ---10 ND 23.0 20.0 ND ND ND ---ND
28-Jun-06 ---10 ND 25.7 12.6 ND ND ND ---ND
29-Dec-06 ---6 ND ND ND ND ND ND ---ND
12-Jul-07 ---5.5 ND ND ND ND ND ND ---NDGWPS = 0.28 µg/L (10/23/07)19-Dec-07 ---5.5 ND 4.0 J ND ND ND ND ND ND
8-Jul-08 ---5.5 ND ND ND ND ND ND ---ND
17-Dec-08 3.0 5.5 ND 3.2 J 3.2 J ND ND ND ---ND
9-Jul-09 3.0 5.5 ND ND ND 4.1 J ND ND ND ND
16-Dec-09 3.0 5.5 ND ND ND ND ND ND ---ND
24-Jun-10 3.0 5.5 ND ND 5.2 J 3.1 J ND ND ---ND
GWPS = 0.2 µg/L (10/1/10)13-Dec-10 3.0 5.5 ND ND 7.7 ND ND ND ---ND20-Jun-11 5.4 5.5 ND ND ND ND ND ND ---ND
5-Dec-11 5.4 5.5 ND ND ND ND ND ND ---ND
11-Jun-12 5.4 5.5 ND ND ND ND ND ND ND ND
12-Dec-12 5.4 5.5 ND ND ND ND ND ND ---ND
1-May-13 5.4 5.5 ND ND ND ND ND ND ND ND
5-Aug-13 5.4 5.5 ND ND ND ND ND ND ---ND
24-Feb-14 5.4 5.5 ND ND ND ND ND ND ND ND12-Aug-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Tin 1-Dec-97 ---100 ND ND ND ND ND ND ------
19-Nov-98 ---100 ND ND ND ND ND ND ------
16-Nov-99 ---100 ND ND ND ND ND ND ------
26-Oct-00 ---100 ---ND ND ND ND ---------
18-Apr-01 ---100 ---ND ND ND ND ---------
27-Oct-01 ---100 ------------------------13-Jun-02 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ------------------------
27-Jun-03 ---100 ND 149 127 ND ND ND ------
30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND
29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND
28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND 41.1 14.4 3.2 J ND ND ---ND
12-Jul-07 ---100 ND 35.2 J 13.9 J 5.2 J ND ND ---ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND 33.6 7.4 ND ND ND ND ND
8-Jul-08 ---100 4.4 J 28.6 J 15.1 J 5.4 J 3.0 J 3.6 J ---ND
17-Dec-08 1.8 100 ND 22.5 J 9.2 J ND ND ND ---ND9-Jul-09 1.8 100 ND 21.4 J 8.6 J ND ND ND ---ND
16-Dec-09 1.8 100 ND 26.3 J 10.7 J ND ND ND ---ND
GWPS = 2100 µg/L (02/05/10)24-Jun-10 1.8 100 ND 23.4 J 10.7 J 3.2 J 2.2 J 1.9 J ---ND
13-Dec-10 1.8 100 ND 30.3 J 12.1 J 5.8 J ND ND ---ND
20-Jun-11 5.0 100 ND 26.8 J 13.8 J ND ND ND ---ND
5-Dec-11 5.0 100 ND 25.8 J 13.9 J ND ND ND ---ND
11-Jun-12 5.0 100 ND 22.2 J 9.0 J ND ND ND ND ND12-Dec-12 5.0 100 ND 30.0 J 13.2 J ND ND ND ---ND
1-May-13 5.0 100 ND 25.8 J 12.2 J ND ND ND ---ND
5-Aug-13 5.0 100 ND 22.7 J 12.5 J ND ND ND ---ND
24-Feb-14 5.0 100 ND 26.7 J 11.7 J 9.8 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 100 ND 30.7 J 8.2 J ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 100 ND 28.7 J 11.1 J ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 100 ND 27.7 J 7.5 J ND ND ND ---ND
Vanadium 8-Sep-94 ---40 ND ND ND ND ND 130 ------
1-Dec-94 ---40 63.0 ND ND 45.0 ND ND ------
9-Feb-95 ---40 ND ND ND ND ND ND ------
2-Mar-95 ---40 41.0 ND ND 45.0 ND ND ------
15-Nov-95 ---40 ND ND ND ND ND ND ------
28-May-96 ---40 83.0 ND ND ND ND ND ------22-Nov-96 ---40 7.0 17 ND 21.0 ND ND ------
17-Jun-97 ---40 450 560 ND 19.0 ND ND ------
1-Dec-97 ---40 62.0 88.0 ND 41.0 ND 10.0 ------
20-May-98 ---40 25.0 15.0 ND 10.0 5.0 ND ------
19-Nov-98 ---40 33.0 29.0 5.0 16.0 9.0 5.0 ------
21-Jul-99 ---40 ND ND ND ND ND ND ------
16-Nov-99 ---40 ND ND ND ND ND ND ------10-May-00 ---40 ND ND ND ND ND ND ------
26-Oct-00 ---40 ND ND ND ND ND ND ------
18-Apr-01 ---40 ND ND ND ND ND ND ------
27-Oct-01 ---40 ND ND ND ND ND ND ------
13-Jun-02 ---40 ND ND ND ND ND ND ------
19-Nov-02 ---40 ND ND ND ND ND ND ------
27-Jun-03 ---40 ND ND ND ND ND ND ------30-Dec-03 ---40 ND ND ND ND ND ND ---ND
30-Jun-04 ---40 ND ND ND ND ND ND ---ND
29-Dec-04 ---40 ND ND ND ND ND ND ---ND29-Jun-05 ---40 ND ND ND ND ND ND ---ND
29-Dec-05 ---40 ND ND ND ND ND ND ---ND28-Jun-06 ---40 ND ND ND ND ND ND ---ND
29-Dec-06 ---25 2.7 J ND ND 14.5 ND 1.0 J ---ND12-Jul-07 ---25 ND ND ND 19.4 J ND ND ---ND
GWPS = 3.5 µg/L (10/23/07)19-Dec-07 ---25 2.2 B 2.2 B ND 15.7 J 3.0 B 1.2 B 4.0 J 0.62 J
8-Jul-08 ---25 2.6 J 2.4 J ND 14.6 J 1.4 J 1.2 J ---0.20 J
17-Dec-08 0.20 25.0 1.9 B 2.3 B ND 13.9 J 2.5 B 1.2 B ---0.76 J
9-Jul-09 0.20 25.0 3.9 B 9.7 J 2.5 B 18.4 J 2.9 B 2.2 B 8.5 J 1.30 J16-Dec-09 0.20 25.0 2.0 B 4.4 J 1.3 B 14.0 J 2.2 B 1.5 B ---0.53 J
24-Jun-10 0.20 25.0 1.8 J 4.4 J 1.5 J 13.3 J 2.2 J 1.3 J ---ND
GWPS = 0.3 µg/L (10/1/10)13-Dec-10 0.20 25.0 3.2 J 3.6 J 0.35 B 16.6 J 1.8 B 1.0 B ---0.36 J
20-Jun-11 5.0 25.0 ND ND ND 14.5 J ND ND ---ND
5-Dec-11 5.0 25.0 ND ND ND 13.5 J ND ND ---ND
11-Jun-12 5.0 25.0 ND 18.0 J ND 12.3 J ND ND ND ND
12-Dec-12 5.0 25.0 ND ND ND 13.6 J ND ND ---ND1-May-13 5.0 25.0 ND ND ND 6.3 J ND ND ND ND
5-Aug-13 5.0 25.0 ND ND ND 10.2 J ND ND ---ND
24-Feb-14 5.0 25.0 ND ND ND 12.9 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 25.0 ND ND ND 18.6 J ND ND ---ND
10-Mar-15 EPA 6010 2.5 25.0 3.1 J 11.6 J 6.2 J 13.4 J ND ND ---ND
18-Aug-15 EPA 6010 2.5 25.0 3.4 J 6.8 J 3.6 J 19.6 J 2.8 J ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 8 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Zinc 8-Sep-94 ---50 110 160 ND ND 320 430 ------
1-Dec-94 ---50 132 ND ND 70 164 ND ------
9-Feb-95 ---50 144 89 ND 91 79 74 ------
2-Mar-95 ---50 67 ND ND ND 111 ND ------
15-Nov-95 ---50 ND 50 ND ND ND ND ------
28-May-96 ---50 136 ND ND ND 122 ND ------22-Nov-96 ---50 79.0 48.0 28.0 ND 38.0 ND ------
17-Jun-97 ---50 370 410 33.0 39.0 36.0 69.0 ------
1-Dec-97 ---50 140 110 11.0 45.0 34.0 30.0 ------
20-May-98 ---50 70.0 63.0 23.0 31.0 47.0 34.0 ------
19-Nov-98 ---50 61.0 33.0 21.0 17.0 53.0 10.0 ------
21-Jul-99 ---50 ND ND ND ND ND ND ------
16-Nov-99 ---50 ND ND ND ND ND ND ------10-May-00 ---50 ND ND ND ND ND ND ------
26-Oct-00 ---50 ND ND ND ND ND ND ------
18-Apr-01 ---50 ND ND ND ND ND ND ------
27-Oct-01 ---50 ND ND ND ND ND ND ------
13-Jun-02 ---50 ND ND ND ND 382 ND ------
19-Nov-02 ---50 ND ND ND ND ND ND ------
27-Jun-03 ---50 ND ND ND ND ND ND ------30-Dec-03 ---50 ND ND ND ND ND ND ---ND
30-Jun-04 ---50 ND ND ND ND ND ND ---ND
29-Dec-04 ---50 ND ND ND 66.0 ND ND ---ND29-Jun-05 ---50 ND 54.0 56.0 ND ND ND ---ND
29-Dec-05 ---50 ND ND ND ND ND ND ---ND28-Jun-06 ---50 ND ND ND ND ND ND ---ND
29-Dec-06 ---50 8.0 J ND ND 4.1 J 4.3 J 4.1 J ---ND12-Jul-07 ---10 9.6 J ND ND ND ND ND ---ND
NC 2L = 1,050 µg/L (10/23/07)19-Dec-07 ---10 4.3 B 14.3 B 6.3 B ND ND ND 2.4 B 102
8-Jul-08 ---10 5.9 B ND ND ND 4.1 B ND ---1.2 J
17-Dec-08 0.40 10.0 2.4 B 6.3 J ND ND 4.6 J 0.60 B ---0.49 J
9-Jul-09 0.40 10.0 3.4 B ND ND ND ND ND 6.1 B 1.6 J
16-Dec-09 0.40 10.0 4.6 B ND ND ND 7.4 B ND ---7.7 J
NC 2L = 1,000 µg/L (02/05/10)24-Jun-10 0.40 10.0 0.58 J ND ND ND ND 1.3 J ---ND13-Dec-10 0.40 10.0 4.5 B ND ND ND ND ND ---6.7 J
20-Jun-11 10.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 10.0 10.0 ND ND ND ND ND ND ---12.4
11-Jun-12 10.0 10.0 ND 20.9 ND ND ND ND ND ND
12-Dec-12 10.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 10.0 10.0 ND ND ND ND 11.8 ND 10.0 ND
5-Aug-13 10.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 10.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 10.0 10.0 ND ND ND ND 16.9 ND ---ND
18-Aug-15 EPA 6010 5.0 10.0 7.4 J ND ND ND 5.2 J ND ---ND
Cyanide 9-Jul-09 5.0 10 ND ND ND ND 46.9 ND ND ND
Resample >28-Sep-09 5.0 10 ------------ND ------ND
NC 2L = 70 µg/L (10/23/07)16-Dec-09 ------------------------------
24-Jun-10 5.0 10.0 ND ND ND ND ND ND ---ND
13-Dec-10 ------------------------------
Resample >20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 5.0 10.0 ND 6.4 J ND ND 8.7 J ND ---ND
12-Dec-12 ------------------------------
1-May-13 5.0 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND 5.5 J
12-Aug-14 5.0 10.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 6010 5.0 10.0 9.5 B 7.5 B 8.5 B 8.8 B 11.8 B 6.6 B ---5.6 J
Granville County
Butner Landfill, Permit No. 39-02 Page 9 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
ORGANICS
Acetone 27-Oct-01 ---100 244 B 109 B ND 130 B 128 B 476 B ---479
13-Jun-02 ---100 ND ND ND ND ND ND ------
13-Jun-02 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND 4.5 J
8-Jul-08 ---100 ND ND ND ND ND ND ---ND
17-Dec-08 20.0 100 ND ND ND ND ND ND ---ND
9-Jul-09 20.0 100 ND ND ND ND ND ND ND ND
16-Dec-09 2.2 100 ND ND ND ND ND ND ---2.8 J
NC 2L = 6,000 µg/L (02/05/10)24-Jun-10 2.2 100 ND 18.5 B 6.5 B ND 2.2 B ND ---7.7 J13-Dec-10 2.2 100 ND ND ND ND ND ND ---ND
20-Jun-11 2.2 100 ND ND ND ND ND 2.4 B ---3.9 J
5-Dec-11 2.2 100 ND 2.3 B ND ND ND ND ---8.8 J
11-Jun-12 2.2 100 ND 3.5 B ND ND ND ND ND 4.7 J
12-Dec-12 10.0 100 ND ND ND ND ND ND ---ND1-May-13 10.0 100 ND ND ND ND ND ND ND 14.6 J
5-Aug-13 10.0 100 ND ND ND ND ND ND ---ND24-Feb-14 10.0 100 ND ND ND ND ND ND ND 25.7 J
*12-Aug-14 EPA 8260 10.0 100 ND ND ND ND ND ND ND 22.0 J
10-Mar-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND
Benzene 8-Sep-94 ---5 ND ND ND ND ND ND ------
1-Dec-94 ---5 ND ND ND ND ND ND ------9-Feb-95 ---5 ND ND ND ND ND ND ------
2-Mar-95 ---5 ND ND ND ND ND ND ------
15-Nov-95 ---5 ND ND ND ND ND ND ------
28-May-96 ---5 ND ND ND ND ND ND ------
22-Nov-96 ---5 ND ND ND ND ND ND ------
17-Jun-97 ---5 ND ND ND ND ND ND ------
1-Dec-97 ---5 ND ND ND ND ND ND ------20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---3 ND 1.5 ND ND ND ND ---ND
Resample >23-Feb-07 ---3 ---1.2 ---------------ND
12-Jul-07 ---1 ND 1.9 ND ND ND ND ---ND
NC 2L = 1 µg/L (10/23/07)19-Dec-07 ---1 ND 1.8 0.48 J 0.26 J ND ND ND ND8-Jul-08 ---1 ND 1.4 0.51 J 0.32 J ND ND ---ND
17-Dec-08 0.25 1.0 ND 1.7 0.54 J ND ND ND ---ND
9-Jul-09 0.25 1.0 ND 1.7 0.34 J ND ND ND ND ND
16-Dec-09 0.25 1.0 ND 1.7 0.60 J 0.29 J ND ND ---ND
24-Jun-10 0.25 1.0 ND 0.77 J 0.49 J 0.33 J ND ND ---ND13-Dec-10 0.25 1.0 ND 1.8 0.59 J 0.37 J ND ND ---ND
Resample >8-Feb-11 0.25 1.0 ---1.4 ---------------ND
20-Jun-11 0.25 1.0 ND 1.7 0.60 J 0.39 J ND ND ---ND
5-Dec-11 0.25 1.0 ND 1.4 0.69 J 0.40 J ND ND ---ND
11-Jun-12 0.25 1.0 ND ND 0.51 J ND ND ND ND ND
12-Dec-12 0.25 1.0 ND 1.6 0.73 J 0.32 J ND ND ---ND
Resample >10-Jan-13 0.25 1.0 ND 1.4 ------------ND ND1-May-13 0.25 1.0 ND 1.3 0.56 J 0.27 J ND ND ND ND
5-Aug-13 0.25 1.0 ND 1.6 0.64 J 0.44 J ND ND ---ND
24-Feb-14 0.25 1.0 ND 1.4 ND ND ND ND ND ND*12-Aug-14 EPA 8260 0.25 1.0 ND 1.7 0.61 J 0.25 J ND ND ND ND
10-Mar-15 EPA 8260 0.25 1.0 ND 1.3 0.54 J ND ND ND ND ND18-Aug-15 EPA 8260 0.25 1.0 ND 1.5 0.66 J 0.32 J ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 10 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Bromomethane 17-Dec-08 0.29 10.0 ND ND 0.58 J ND ND ND ---ND
NC 2L = NE µg/L (10/23/07)9-Jul-09 0.29 10.0 ND ND ND ND ND ND ND ND
16-Dec-09 0.29 10.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.29 10.0 ND ND ND ND ND ND ---ND
GWPS = 10 µg/L (8/1/10)13-Dec-10 0.29 10.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.29 10.0 ND ND ND ND ND ND ---ND5-Dec-11 0.29 10.0 ND ND ND ND ND ND ND ND
11-Jun-12 0.29 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.29 10.0 ND ND ND ND ND ND ---ND
1-May-13 0.29 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.29 10.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.29 10.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ---ND
2-Butanone (MEK)17-Dec-08 0.96 100 ND ND ND ND 1.2 J ND ---ND
NC 2L = 4,200 µg/L (10/23/07)9-Jul-09 0.96 100 ND ND ND ND ND ND ND ND
16-Dec-09 0.96 100 ND ND ND ND ND ND ---ND
NC 2L = 4,000 µg/L (02/05/10)24-Jun-10 0.96 100 ND ND ND ND ND ND ---ND13-Dec-10 0.96 100 ND ND ND ND ND ND ---ND
20-Jun-11 0.96 100 ND ND ND ND ND ND ---ND
5-Dec-11 0.96 100 ND ND ND ND ND ND ---ND
11-Jun-12 0.96 100 ND ND ND ND ND ND ND ND
12-Dec-12 0.96 100 ND ND ND ND ND ND ---ND
1-May-13 0.96 100 ND ND ND ND ND ND ND ND
8-May-13 0.96 100 ND ND ND ND ND ND ---ND24-Feb-14 0.96 100 ND ND ND ND ND ND ND ND
*12-Aug-14 0.96 100 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.96 100 ND ND ND ND ND ND ---ND
Carbon Disulfide 17-Jun-97 ---100 ND 64.0 ND ND ND ND ------
1-Dec-97 ---100 ND 5.0 8.0 ND ND ND ------20-May-98 ---100 ND 7.5 6.2 ND ND ND ------
19-Nov-98 ---100 ND ND ND ND ND ND ------
21-Jul-99 ---100 ND ND ND ND ND ND ------
16-Nov-99 ---100 ND ND ND ND ND ND ------
10-May-00 ---100 ND ND ND ND ND ND ------
26-Oct-00 ---100 ND ND ND ND ND ND ------
18-Apr-01 ---100 ND ND ND ND ND ND ------27-Oct-01 ---100 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------
30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND
29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND
28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND
12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND
8-Jul-08 ---100 ND ND ND ND ND ND ---ND17-Dec-08 1.2 100 ND ND ND ND ND ND ---ND
9-Jul-09 1.2 100 ND ND ND ND ND ND ND ND
16-Dec-09 1.2 100 ND ND ND ND ND ND ---ND
24-Jun-10 1.2 100 ND ND ND ND ND ND ---ND
13-Dec-10 1.2 100 ND ND ND ND ND ND ---ND
20-Jun-11 1.2 100 ND ND ND ND ND ND ---ND
5-Dec-11 1.2 100 ND ND ND ND ND ND ---ND11-Jun-12 1.2 100 ND ND ND ND ND ND ND ND
12-Dec-12 1.2 100 ND ND ND ND ND ND ---ND
1-May-13 1.2 100 ND ND ND ND ND ND ND ND
5-Aug-13 1.2 100 ND ND ND ND ND ND ---ND
24-Feb-14 1.2 100 ND ND ND ND ND ND ND ND*12-Aug-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 1.2 100 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 11 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Chlorobenzene 8-Sep-94 ---5 ND 10.0 7.0 ND ND ND ------
1-Dec-94 ---5 ND ND 7.0 ND ND ND ------
9-Feb-95 ---5 ND 13.0 8.0 6.0 ND ND ------
2-Mar-95 ---5 ND 12.0 9.0 ND ND ND ------
15-Nov-95 ---5 ND 14.0 8.0 9.0 ND ND ------
28-May-96 ---5 ND 15.0 9.0 10.0 ND ND ------22-Nov-96 ---5 ND 15.0 ND 11.0 ND ND ------
17-Jun-97 ---5 ND 19.0 11.0 14.0 ND ND ------
1-Dec-97 ---5 ND 17.0 9.0 14.0 ND ND ------
20-May-98 ---5 ND 20.0 8.6 12.0 ND ND ------
19-Nov-98 ---5 ND 17.2 9.2 10.0 ND ND ------
21-Jul-99 ---5 ND 14.0 10.0 11.0 ND ND ------
16-Nov-99 ---5 ND 16.0 10.0 8.0 ND ND ------10-May-00 ---5 ND 17.0 11.0 10.0 ND ND ------
26-Oct-00 ---5 ND 16.0 12.0 9.0 ND ND ------
18-Apr-01 ---5 ND 16.0 13.0 6.0 ND ND ------
27-Oct-01 ---0.5 ND 17.0 12.0 9.0 ND ND ------
13-Jun-02 ---0.5 ND 16.0 11.0 8.0 ND ND ------
19-Nov-02 ---0.5 ND 18.0 15.0 9.0 ND ND ------
27-Jun-03 ---0.5 ND 17.7 13.3 7.4 ND ND ---ND30-Dec-03 ---5 ND 20.0 15.0 6.1 ND ND ---ND
30-Jun-04 ---5 ND 18.0 15.0 9.9 ND ND ---ND
29-Dec-04 ---5 ND 19.0 16.0 9.4 ND ND ---ND29-Jun-05 ---5 ND 15.0 13.0 8.0 ND ND ---ND
29-Dec-05 ---5 ND 18.0 16.0 5.0 ND ND ---ND28-Jun-06 ---5 ND 16.5 10.8 7.8 ND ND ---ND
29-Dec-06 ---3 ND 17.0 17.0 4.2 ND ND ---ND12-Jul-07 ---3 ND 17.0 16.0 ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---3 ND 17.3 16.9 4.7 ND ND ND ND
8-Jul-08 ---3 ND 17.2 17.4 6.5 ND ND ---ND
17-Dec-08 0.23 3.0 ND 15.9 15.6 2.6 J ND ND ---ND
9-Jul-09 0.23 3.0 ND 16.1 17.2 6.1 ND ND ND ND
16-Dec-09 0.23 3.0 ND 15.5 17.7 4.8 ND ND ---ND
24-Jun-10 0.23 3.0 ND 8.3 15.7 6.3 ND ND ---ND13-Dec-10 0.23 3.0 ND 17.7 18.2 6.4 ND ND ---0.28 J
20-Jun-11 0.23 3.0 ND 16.3 17.2 6.7 ND ND ---ND
5-Dec-11 0.23 3.0 ND 14.2 17.0 5.8 ND ND ---ND
11-Jun-12 0.23 3.0 ND 12 14.8 4.4 ND ND ND ND
12-Dec-12 0.23 3.0 ND 15.8 17.9 4.5 ND ND ---ND
1-May-13 0.23 3.0 ND 14.0 16.6 3.0 J ND ND ND ND
5-Aug-13 0.23 3.0 ND 14.4 15.9 4.6 ND ND ---ND24-Feb-14 0.23 3.0 ND 16.3 2.5 J 1.4 J ND ND ND ND
*12-Aug-14 EPA 8260 0.23 3.0 ND 15.6 18.3 3.6 ND ND ND ND
10-Mar-15 EPA 8260 0.23 3.0 ND 16.0 17.0 2.1 J ND ND ND ND
18-Aug-15 EPA 8260 0.23 3.0 ND 12.8 17.6 4.3 ND ND ---ND
Chloroethane 1-Dec-97 ---10 ND 5.0 2.0 2.0 ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND
28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND 2.2 1.9 ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 2,800 µg/L (10/23/07)19-Dec-07 ---10 ND 1.9 1.9 1.5 ND ND ND ND8-Jul-08 ---10 ND 2.2 J 2.5 J 1.8 J ND ND ---ND
17-Dec-08 0.54 10.0 ND 1.6 J ND ND ND ND ---ND
9-Jul-09 0.54 10.0 ND ND ND 3.8 J ND ND ND ND
16-Dec-09 0.54 10.0 ND ND 2.2 J 2.0 J ND ND ---ND
NC 2L = 3,000 µg/L (02/05/10)24-Jun-10 0.54 10.0 ND ND 2.1 J 2.0 J ND ND ---ND
13-Dec-10 0.54 10.0 ND 1.8 J 2.0 J 1.7 J ND ND ---ND
20-Jun-11 0.54 10.0 ND 1.2 J 2.2 J 2.0 J ND ND ---ND5-Dec-11 0.54 10.0 ND 1.3 J 2.0 J 1.7 J ND ND ---ND
11-Jun-12 0.54 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.54 10.0 ND ND ND ND ND ND ---ND
1-May-13 0.54 10.0 ND ND 1.9 J 2.7 J ND ND ND ND
5-Aug-13 0.54 10.0 ND ND 2.0 J 2.2 J ND ND ---ND
24-Feb-14 0.54 10.0 ND 1.1 J 0.82 J ND ND ND ND ND
*12-Aug-14 EPA 8260 0.54 10.0 ND 1.1 J 1.50 J 1.1 J ND ND ND ND10-Mar-15 EPA 8260 0.54 10.0 ND 1.0 J 1.80 J 0.81 J ND ND ND ND
18-Aug-15 EPA 8260 0.54 10.0 ND 1.2 J 2.0 J 3.7 J ND ND ---ND
Chloromethane 9-Jul-09 0.11 1.0 ND ND ND ND ND ND ND ND
NC 2L = 2.6 µg/L (10/23/07)16-Dec-09 0.11 1.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.11 1.0 ND ND ND ND ND 0.11 J ---ND
NC 2L = 3 µg/L (02/05/10)13-Dec-10 0.11 1.0 ND ND ND ND ND ND ---ND20-Jun-11 0.11 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.11 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.11 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.11 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.11 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.11 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.11 1.0 ND ND ND ND ND ND ND 0.25 J12-Aug-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 12 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,2-Dichlorobenzene 1-Dec-97 ---5 ND 3.0 2.0 1.0 ND ND ------
20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND 2.4 2.3 ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND 1.5 2.3 ND ND ND ---ND
12-Jul-07 ---5 ND 1.4 J 1.7 J 0.31 J ND ND ---NDNC 2L = 24 µg/L (10/23/07)19-Dec-07 ---5 ND 1.6 2.0 0.37 J ND ND ND ND
8-Jul-08 ---5 ND 1.6 J 2.0 J 0.39 J ND ND ---ND
17-Dec-08 0.30 5.0 ND 1.4 J 1.9 J ND ND ND ---ND
9-Jul-09 0.30 5.0 ND 1.6 J 2.0 J 0.36 J ND ND ND ND
16-Dec-09 0.30 5.0 ND 1.6 J 2.0 J 0.33 J ND ND ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 0.30 5.0 ND 0.96 J 1.7 J 0.31 J ND ND ---ND
13-Dec-10 0.30 5.0 ND 1.9 J 1.9 J 0.43 J ND ND ---ND20-Jun-11 0.30 5.0 ND 1.5 J 1.7 J 0.37 J ND ND ---ND
5-Dec-11 0.30 5.0 ND 1.3 J 1.6 J ND ND ND ---ND
11-Jun-12 0.30 5.0 ND 1.0 J 1.5 J ND ND ND ND ND
12-Dec-12 0.30 5.0 ND 1.3 J 1.7 J ND ND ND ---ND
1-May-13 0.30 5.0 ND 1.2 J 1.6 J ND ND ND ND ND
5-Aug-13 0.30 5.0 ND 1.2 J 1.6 J 0.30 J ND ND ---ND
24-Feb-14 0.30 5.0 ND 1.4 J 0.64 J ND ND ND ND ND*12-Aug-14 EPA 8260 0.30 5.0 ND 1.2 J 1.5 J ND ND ND ND ND
10-Mar-15 EPA 8260 0.30 5.0 ND 1.1 J 1.1 J ND ND ND ND ND
18-Aug-15 EPA 8260 0.30 5.0 ND 0.88 J 1.3 J ND ND ND ---ND
1,4-Dichlorobenzene 8-Sep-94 ---5 ND ND 5.0 ND ND ND ------
1-Dec-94 ---5 ND ND 5.0 ND ND ND ------
9-Feb-95 ---5 ND 8.0 6.0 ND ND ND ------2-Mar-95 ---5 ND 7.0 6.0 ND ND ND ------
15-Nov-95 ---5 ND 7.0 6.0 ND ND ND ------
28-May-96 ---5 ND ND ND ND ND ND ------
22-Nov-96 ---5 ND ND ND ND ND ND ------
17-Jun-97 ---5 ND 7.6 6.2 ND ND ND ------
1-Dec-97 ---5 ND 6.0 5.0 4.0 ND ND ------
20-May-98 ---5 ND 7.6 ND ND ND ND ------19-Nov-98 ---5 ND 3.7 2.8 ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND 5.0 6.0 ND ND ND ------
18-Apr-01 ---5 ND ND 5.0 6.0 ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---3 ND 3.0 3.3 ND ND ND ---ND
Resample >23-Feb-07 ---3 ---3.2 3.3 ------------ND
12-Jul-07 ---1 ND 3.3 2.9 0.31 J ND ND ---NDNC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---1 ND 3.0 2.7 ND ND ND ND ND
8-Jul-08 ---1 ND 3.0 2.4 ND ND ND ---ND
17-Dec-08 0.33 1.0 ND 2.9 2.5 ND ND ND ---ND
9-Jul-09 0.33 1.0 ND ND ND ND ND ND ND ND
16-Dec-09 0.33 1.0 ND 2.8 2.2 ND ND ND ---ND
NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.33 1.0 ND 1.6 ND ND ND ND ---ND
13-Dec-10 0.33 1.0 ND 3.1 1.9 ND ND ND ---ND20-Jun-11 0.33 1.0 ND 2.7 1.6 ND ND ND ---ND
5-Dec-11 0.33 1.0 ND 2.2 1.4 ND ND ND ---ND
11-Jun-12 0.33 1.0 ND 1.8 1.4 ND ND ND ND ND
12-Dec-12 0.33 1.0 ND 2.4 1.3 ND ND ND ---ND
1-May-13 0.33 1.0 ND 2.1 1.2 ND ND ND ND ND
5-Aug-13 0.33 1.0 ND 2.0 1.3 ND ND ND ---ND
24-Feb-14 0.33 1.0 ND 2.2 1.8 ND ND ND ND ND*12-Aug-14 EPA 8260 0.33 1.0 ND 2.4 1.3 ND ND ND ND ND
10-Mar-15 EPA 8260 0.33 1.0 ND 2.2 1.1 ND ND ND ND ND
18-Aug-15 EPA 8260 0.33 1.0 ND 1.5 1.1 ND ND ND ---ND
Trans-1,4-Dichloro-2-Butene 20-May-98 ---100 ND ND 5.1 ND ND ND ------
19-Nov-98 ---100 ND ND ND ND ND ND ------
21-Jul-99 ---100 ND ND ND ND ND ND ------16-Nov-99 ---100 ND ND ND ND ND ND ------
10-May-00 ---100 ND ND ND ND ND ND ------
26-Oct-00 ---100 ND ND ND ND ND ND ------
18-Apr-01 ---100 ND ND ND ND ND ND ------
27-Oct-01 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND
8-Jul-08 ---100 ND ND ND ND ND ND ---ND
17-Dec-08 1.0 100 ND ND ND ND ND ND ---ND
9-Jul-09 1.0 100 ND ND ND ND ND ND ND ND
16-Dec-09 1.0 100 ND ND ND ND ND ND ---ND
24-Jun-10 1.0 100 ND ND ND ND ND ND ---ND13-Dec-10 1.0 100 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 100 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 100 ND ND ND ND ND ND ---ND
11-Jun-12 1.0 100 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 100 ND ND ND ND ND ND ---ND
1-May-13 1.0 100 ND ND ND ND ND ND ND ND
5-Aug-13 1.0 100 ND ND ND ND ND ND ---ND24-Feb-14 1.0 100 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 1.0 100 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 13 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,1-Dichloroethane 1-Dec-97 ---5 ND ND 1.0 ND ND ND ------
20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND ND ND ND ND ND ---ND
12-Jul-07 ---5 ND ND 0.36 J 0.52 J ND ND ---NDNC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ND ND ND 0.57 J ND ND ND ND
8-Jul-08 ---5 ND ND ND 0.60 J ND ND ---ND
17-Dec-08 0.32 5.0 ND ND ND 0.51 J ND ND ---ND
9-Jul-09 0.32 5.0 ND ND ND 0.84 J ND ND ND ND
16-Dec-09 0.32 5.0 ND ND ND 0.73 J ND ND ---ND
NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.32 5.0 ND ND ND 0.53 J ND ND ---ND
13-Dec-10 0.32 5.0 ND ND ND 0.60 J ND ND ---ND20-Jun-11 0.32 5.0 ND ND ND 0.63 J ND ND ---ND
5-Dec-11 0.32 5.0 ND ND ND 0.67 J ND ND ---ND
11-Jun-12 0.32 5.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.32 5.0 ND ND ND 0.61 J ND ND ---ND
1-May-13 0.32 5.0 ND ND ND 0.62 J ND ND ND ND
8-May-13 0.32 5.0 ND ND ND 0.53 J ND ND ---ND
24-Feb-14 0.32 5.0 ND ND ND 0.50 J ND ND ND ND*12-Aug-14 EPA 8260 0.32 5.0 ND ND ND 0.47 J ND ND ND ND
10-Mar-15 EPA 8260 0.32 5.0 ND ND ND 0.50 J ND ND ND ND
18-Aug-15 EPA 8260 0.32 5.0 ND ND ND 0.49 J ND ND ---ND
1,2-Dichloroethane 17-Dec-08 0.12 1.0 ND ND 0.15 J ND ND ND ---ND
NC 2L = 0.38 µg/L (10/23/07)9-Jul-09 0.12 1.0 ND ND ND ND ND ND ND 0.19 J
16-Dec-09 0.12 1.0 ND ND 0.14 J ND ND ND ---NDNC 2L = 0.4 µg/L (02/05/10)24-Jun-10 0.12 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.12 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.12 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.12 1.0 ND ND ND ND 0.18 J ND ---ND
11-Jun-12 0.12 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.12 1.0 ND ND ND ND -0.20 J ND ---0.20 (ND)J
1-May-13 0.12 1.0 ND ND ND ND ND ND ND ND5-Aug-13 0.12 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.12 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.24 1.0 ND ND 0.33 J 0.29 J 0.36 J ND ------
Ethylbenzene 17-Dec-08 0.30 1.0 ND 0.31 J ND ND ND ND ---NDNC 2L = 550 µg/L (10/23/07)9-Jul-09 0.30 1.0 ND ND ND ND ND ND ND ND
16-Dec-09 0.30 1.0 ND ND ND ND ND ND ---ND
NC 2L = 600 µg/L (02/05/10)24-Jun-10 0.30 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.30 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.30 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.30 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.30 1.0 ND ND ND ND ND ND ND ND12-Dec-12 0.30 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.30 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.30 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.30 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ---ND
Isobutanol 24-Jun-10 35.0 100 ND 59.0 J ND ND ND ND ---ND
NC 2L = NE µg/L (02/05/10)13-Dec-10 ------------------------------
20-Jun-11 35.0 100 ND 39.5 J ND ND ND ND ---ND
5-Dec-11 ------------------------------11-Jun-12 35.0 100.0 ND ND ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 35.0 100 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 35.0 100 ND ND ND ND ND ND ---ND
*12-Aug-14 35.0 100 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 8260 35.0 100 ND ND ND ------------ND
Methylene Chloride 9-Jul-09 0.97 2.0 ND ND ND ND ND ND ND 9.6
NC 2L = 4.3 µg/L (10/23/07)16-Dec-09 0.97 2.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.97 1.0 ND 19.0 ND ND ND ND ---ND
NC 2L = 5 µg/L (02/05/10) Resample >12-Aug-10 0.97 1.0 ---ND ---------------ND
13-Dec-10 0.97 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.97 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.97 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.97 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.97 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.97 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.97 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.97 1.0 1.0 ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.97 1.0 1.3 1.1 1.6 ND ND ND ND ND
Naphthalene 8-Jul-08 ---10 ND 3.8 J ND ND ND ND ---ND
NC 2L = 21 µg/L (10/23/07)17-Dec-08 ------------------------------
9-Jul-09 0.24 10.0 ND 2.4 J ND ND ND ND ---ND
16-Dec-09 ------------------------------NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.24 10.0 ND 7.4 J ND ND ND ND ---ND
13-Dec-10 ------------------------------
20-Jun-11 0.24 10.0 ND 4.6 J ND ND ND ND ---0.39 J
5-Dec-11 --------- ---------------------
11-Jun-12 0.2 10.0 ND 4.6 J ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 0.24 10.0 ND 5.1 J ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.24 10.0 ND 5.8 J ND ND ND ND ---ND
*12-Aug-14 ------------------------------
10-Mar-15 EPA 8260 0.2 10 ND 5.4 J ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 14 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Toluene 20-May-98 ---5 ND ND 8.1 ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND ND ND ND ND ND ------18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ----
30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND ND ND ND ND ND ---ND
12-Jul-07 ---1 ND 0.49 B ND ND ND ND ---0.34 J
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---1 ND 0.51 J ND ND ND ND ND ND8-Jul-08 ---1 ND 0.39 J ND ND 1.3 ND ---ND
17-Dec-08 0.26 1.0 1.4 1.6 ND ND 11.7 ND ---ND
9-Jul-09 0.26 1.0 ND 0.46 J ND ND ND ND ND ND
16-Dec-09 0.26 1.0 ND 0.42 J ND ND ND ND ---ND
NC 2L = 600 µg/L (02/05/10)24-Jun-10 0.26 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.26 1.0 ND 0.54 J ND ND ND ND ---ND
20-Jun-11 0.26 1.0 ND 0.34 J ND ND ND ND ---ND5-Dec-11 0.26 1.0 ND 0.28 J ND ND 0.30 J ND ---ND
11-Jun-12 0.26 1.0 ND 0.28 J ND ND ND ND ND ND
12-Dec-12 0.26 1.0 ND 0.29 J ND ND 0.36 J ND ---ND
1-May-13 0.26 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.26 1.0 ND 0.29 J ND ND ND ND ---ND
24-Feb-14 0.26 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ---ND
Vinyl Chloride 8-Sep-94 ---10 ND ND 12.0 ND ND ND ------
1-Dec-94 ---10 ND ND 13.0 ND ND ND ------
9-Feb-95 ---10 ND ND 15.0 ND ND ND ------
2-Mar-95 ---10 ND ND 14.0 ND ND ND ------15-Nov-95 ---10 ND ND 11.0 ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------
22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND ND ND ND ND ND ------
1-Dec-97 ---10 ND ND 7.0 4.0 ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---5.5 ND ND 0.98 J ND ND ND ---ND
Resample >23-Feb-07 ---5.5 ------1.0 ------------ND
12-Jul-07 ---1 ND ND ND ND ND ND ---ND
NC 2L = 0.015 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND8-Jul-08 ---1 ND ND 0.76 J ND ND ND ---ND
17-Dec-08 0.62 1.0 ND ND 0.76 J ND ND ND ---ND
9-Jul-09 0.62 1.0 ND ND 0.99 J ND ND ND ND ND
16-Dec-09 0.62 1.0 ND ND 0.81 J ND ND ND ---ND
NC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.62 1.0 ND ND 0.77 J ND ND ND ---ND
13-Dec-10 0.62 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.62 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.62 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.62 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.62 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.62 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.62 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.62 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ---ND
Xylene (Total)29-Dec-06 ---5 ND 1.4 ND ND ND ND ---ND
12-Jul-07 ---4 ND 1.2 J ND ND ND ND ---ND
NC 2L = 530 µg/L (10/23/07)19-Dec-07 ---4 ND 2.0 ND ND ND ND ND ND
8-Jul-08 ---4 ND 1.1 J ND ND ND ND ---ND17-Dec-08 0.66 2.0 1.4 J 2.7 ND ND ND ND ---ND
9-Jul-09 0.66 2.0 ND 1.5 J ND ND ND ND ND ND
16-Dec-09 0.66 2.0 ND 2.2 ND ND ND ND ---ND
NC 2L = 500 µg/L (02/05/10)24-Jun-10 0.66 2.0 ND 0.73 J ND ND ND ND ---ND
13-Dec-10 0.66 2.0 ND 2.0 ND ND ND ND ---ND
20-Jun-11 0.66 2.0 ND 1.4 J ND ND ND ND ---ND
5-Dec-11 0.66 2.0 ND 1.1 J ND ND ND ND ---ND11-Jun-12 0.66 2.0 ND 0.91 J ND ND ND ND ND ND
12-Dec-12 0.66 5.0 ND 0.97 J ND ND ND ND ---ND
1-May-13 0.66 5.0 ND 0.68 J ND ND ND ND ND ND
5-Aug-13 0.66 5.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.66 5.0 ND ND ND ND ND ND ND ND
*12-Aug-14 0.66 5.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ---ND
Bis(2-Ethylhexyl)phthalate 24-Feb-14 0.79 15.0 2.6 J ND ND ND ND ND ND ND
NC 2L = 3 µg/L (2/5/10)15-Apr-14 0.79 15.0 ND ND ND ND ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 15 ND ND ND ------------ND
N-Nitroso-di-n-butylamine 24-Feb-14 7.5 10.0 ND ND ND 8.6 J ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.3 10 ND ND ND ------------ND
Benzo(g,h,i)perylene 20-Jun-11 0.4 10.0 ND ND ND ND ND 1.4 J ---ND
NC 2L = 200 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.38 10.0 ND ND ND ND ND ND ---ND12-Dec-12 ------------------------------
1-May-13 0.38 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.38 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 15 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Dibenz(a,h)anthracene 20-Jun-11 0.55 10.0 ND ND ND ND ND 1.5 J ---ND
NC 2L = 0.005 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.55 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.55 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------24-Feb-14 0.55 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
Fluorene 24-Jun-10 3.8 12.2 ND 4.3 J ND ND ND ND ---ND
NC 2L = 300 µg/L (2/5/10) Resample > 12-Aug-10 3.1 10.0 ---ND ---------------ND
13-Dec-10 ------------------------------20-Jun-11 0.2 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 0.21 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.21 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.21 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND
Indeno(1,2,3-cd)pyrene 20-Jun-11 0.29 10.0 ND ND ND ND ND 1.3 J ---ND
NC 2L = 0.05 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.29 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------1-May-13 0.29 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.29 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
2-Methylnaphthalene 24-Jun-10 5.1 12.2 ND 38.9 ND ND ND ND ---NDNC 2L = 30 µg/L (02/05/10) Resample>12-Aug-10 4.2 10 ---ND ---------------ND
13-Dec-10 ------------------------------
20-Jun-11 0.3 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 0.28 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.28 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.28 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND
Phorate 18-Apr-01 ---10 ---3.2 ND ND ND ---------
27-Oct-01 ---5 ND 8.1 ND ND ND ND ------27-Oct-01 ---0.5 ---8.1 1.3 ND ND ---------
13-Jun-02 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---0.5 ---ND ND ND ND ---------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ------------------------------
28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ------------------------------
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ------------------------ND ---
8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 ------------------------------9-Jul-09 6.6 22.2 ND ND ND ND ND ND ---ND
16-Dec-09 ------------------------------
NC 2L = 1 µg/L (02/05/10)24-Jun-10 6.5 24.1 ND ND ND ND ND ND ---ND
13-Dec-10 ------------------------------
20-Jun-11 5.4 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------
11-Jun-12 5.4 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 5.4 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 5.4 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.8 10.0 ND ND ND ------------ND
Beta-BHC 11-Jun-12 0.050 0.050 ND ND 0.16 ND ND ND ---ND
NC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------
12-Dec-12 ------------------------------
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------24-Feb-14 0.050 0.050 ND 0.052 ND ND ND ND ---ND
Resample >15-Apr-14 0.050 0.050 ---ND ---------------ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
Delta-BHC 11-Jun-12 0.050 0.050 ND ND 0.090 ND ND ND ---ND
NC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------12-Dec-12 ------------------------------
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 16 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
gamma-BHC (Lindane)27-Jun-03 ---1.05 ND 0.085 ND ND ND ND ---ND
30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND
30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND
29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND
12-Jul-07 ---0.05 ND ND ND ND ND ND ---ND
NC 2L = 0.2 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND
8-Jul-08 ---0.50 ND ND ND ND ND ND ---ND
17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND
9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND16-Dec-09 0.01 0.1 ND ND ND ND ND ND ---ND
NC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.00021 0.010 ND ND 0.052 ND ND ND ---ND
Resample >12-Aug-10 0.00020 0.010 ------ND ------------ND
13-Dec-10 0.00020 0.050 ND ND 0.013 J ND ND ND ---ND
20-Jun-11 0.00020 0.050 ND ND 0.066 ND ND ND ---ND
Resample >28-Jul-11 0.00020 0.010 ------ND ------------ND
5-Dec-11 0.050 0.050 ND ND ND ND ND ND ---ND11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND
12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND
24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 0.050 0.050 ND ND ND ------------ND
10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND
Heptachlor 27-Jun-03 ---1.05 ND 0.03 0.17 ND ND ND ---ND
30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND
30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND
29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND
28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND
12-Jul-07 ---0.05 ND ND ND ND ND ND ---ND
NC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND
8-Jul-08 ---0.05 ND ND ND ND ND ND ---ND
17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND
16-Dec-09 0.02 0.1 ND ND ND ND ND ND ---ND
NC 2L = 0.008 µg/L (02/05/10)24-Jun-10 0.0015 0.010 ND ND ND ND ND ND ---ND
13-Dec-10 0.0500 0.0015 ND ND ND ND ND ND ---ND
20-Jun-11 0.050 0.0015 ND ND ND ND ND ND ---ND
5-Dec-11 0.050 0.056 ND 0.062 ND ND ND ND ---ND
Resample >25-Jan-12 0.050 0.0500 ---ND ---------------ND11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND
12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND
24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 0.050 0.050 ND ND ND ------------ND
10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND
2,4-D 27-Jun-03 ---3 ---5.9 ND ND ND ---------
30-Dec-03 ---2 ND ND ND ND ND ND ---ND
30-Jun-04 ---2 ND ND ND ND ND ND ---ND
29-Dec-04 ---2 ND ND ND ND ND ND ---ND
29-Jun-05 ---2 ND ND ND ND ND ND ---ND
29-Dec-05 ---2 ND ND ND ND ND ND ---ND
28-Jun-06 ---2 ND ND ND ND ND ND ---ND
29-Dec-06 ---2 ND ND ND ND ND ND ---ND
12-Jul-07 ---2 ND ND ND ND ND ND ---ND
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---2 ND ND ND ND ND ND ND ND8-Apr-08 ---2 ND ND ND ND ND ND ---ND
17-Dec-08 ---2.0 ND ND ND ND ND ND ---ND
9-Jul-09 ---2.0 ND ND ND ND ND ND ---ND
16-Dec-09 0.11 5.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.23 2.1 ND ND ND ND ND ND ---ND
10-Dec-10 0.22 2.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.22 2.0 ND ND ND ND ND ND ---ND5-Dec-11 0.22 2.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.22 2.0 ND ND ND ND ND ND ---ND
12-Dec-12 0.22 2.0 ND ND ND ND ND ND ---ND
1-May-13 0.22 2.0 ND ND ND ND ND ND ---ND
5-Aug-13 0.22 2.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.22 2.0 ND ND ND ND ND ND ---ND
12-Aug-14 EPA 8151 0.22 2.0 ND ND ND ------------ND10-Mar-15 EPA 8151 0.24 2.1 ND ND ND ------------ND
18-Aug-15 EPA 8151 0.24 2.1 ND ND ND ------------ND
4,4'-DDD 11-Jun-12 0.05 0.05 ND ND 0.13 ND ND ND ---ND
NC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------ND ---------------
12-Dec-12 ------------------------------
1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 17 of 18
Joyce Engineering
TABLE 1: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
4,4'-DDT 11-Jun-12 0.05 0.05 ND ND 0.10 ND ND ND ---ND
NC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------0.063 J ---------------
12-Dec-12 ------------------------------
1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
Dinoseb 10-Mar-15 EPA 8151 0.1 1.1 ND ND 0.11 J ------------ND
Endrin aldehyde 11-Jun-12 0.050 0.050 ND ND 0.14 ND ND ND ------
NC 2L= 2 (2/5/10)12-Dec-12 0.050 0.10 ND ND ND ND ND ND ------
1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND5-Aug-13 0.050 0.10 ND ND ND ND ND ND ---ND
24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 EPA 8081 0.050 0.10 ND ND ND ------------ND
10-Mar-15 EPA 8081 0.050 0.10 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.10 ND ND ND ------------ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.--- = Well was not monitored and/or not reported.
Granville County
Butner Landfill, Permit No. 39-02 Page 18 of 18
Joyce Engineering

Appendix D

Historical Surface Water Analytical Data

TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
INORGANICS
Arsenic 06/24/10 2.7 10.00 4.30 J 2.90 J ND
NC 2B = 10 µg/L (03/28/08)12/13/10 2.7 10.0 ND ND ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND 3.0 J
08/18/15 ------Dry Dry ---
Barium 11/22/96 ---500 37.0 37.0 ---
06/17/97 ---500 37.0 62.0 ---
12/01/97 ---500 53.0 45.0 ---
05/20/98 ---500 24.0 69.0 ---
11/19/98 ---500 ND 100.0 ---
07/21/99 ---500 ND ND ---
11/16/99 ---500 ND ND ---
05/10/00 ---500 ND ND ---
10/26/00 ---500 ND ND ---
04/18/01 ---500 ND ND ---
10/27/01 ---500 ND ND ---
06/13/02 ---500 ---------
11/19/02 ---500 ND ND ---
06/27/03 ---500 ND ND ---
12/30/03 ---500 ND ND ND
06/30/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
06/29/05 ---500 ND ND ND
12/29/05 ---500 ND ND ND
06/28/06 ---500 ND ND ND
12/29/06 ---100 37.5 40.6 0.20 J
07/12/07 ---100 33.3 J ---ND
12/19/07 ---100 52.6 B 149.0 11.7
NC 2B = 1,000 µg/L (03/28/08)07/08/08 ---100 33.8 J 161.0 0.3 J
12/17/08 0.2 100 30.2 B 33.5 B 10.7 J
07/09/09 0.2 100 36.8 B 78.4 B 17.6 J
12/16/09 0.2 100 31.2 B 36.2 B 17.1 J
06/24/10 0.2 100 34.5 B 71.3 B 27.3 J
12/13/10 0.2 100 36.1 B 91.0 J 12.1 J
06/20/11 5.0 100 40.3 J 93.0 J ND
12/05/11 5.0 100 32.9 J 59.0 J ND
06/11/12 5.0 100 40.0 J 95.6 J ND
12/12/12 5.0 100 45.0 J 97.8 J ND
05/01/13 5.0 100 32.7 J 43.1 J ND
08/05/13 5.0 100 49.9 J 79.8 J ND
02/24/14 5.0 100 29.0 J 30.4 J ND
08/12/14 EPA 6010 5.0 100 ---121 ND
03/10/15 EPA 6010 2.5 100 29.0 J 32.1 J ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 1 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Beryllium 07/08/08 ---1.0 0.32 J ND ND
12/17/08 0.1 1.0 ND ND ND
07/09/09 0.1 1.0 ND ND ND
12/16/09 0.1 1.0 0.12 J ND ND
NC 2B = 6.5 µg/L (02/05/10)06/24/10 0.1 1.0 ND ND ND
12/13/10 0.1 1.0 ND ND ND
06/20/11 1.0 1.0 ND ND ND
12/05/11 1.0 1.0 ND ND ND
06/11/12 1.0 1.0 ND ND ND
12/12/12 1.0 1.0 ND ND ND
05/01/13 1.0 1.0 ND ND ND
08/05/13 1.0 1.0 ND ND ND
02/24/14 1.0 1.0 ND ND ND
08/12/14 EPA 6010 1.0 1.0 ---ND ND
03/10/15 EPA 6010 0.5 1.0 ND ND ND
08/18/15 ------Dry Dry ---
Chromium 06/17/97 ---10.0 ND 3.00 ---
12/01/97 ---10.0 ND ND ---
05/20/98 ---10.0 ND ND ---
11/19/98 ---10.0 ND ND ---
07/21/99 ---10.0 ND ND ---
11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---
10/26/00 ---10.0 ND ND ---
04/18/01 ---10.0 ND ND ---
10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND ND ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 2.20 B 2.60 B 1.40 J
NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 2.50 J 2.20 J ND
12/17/08 0.4 10.0 1.40 J 2.60 J ND
07/09/09 0.4 10.0 2.6 J 1.2 J ND
12/16/09 0.4 10.0 4.1 J 3.4 J ND
06/24/10 0.4 10.0 3.3 B 7.3 J 0.71 J
12/13/10 0.4 10.0 1.4 J 1.5 J ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND 7.2 J ND
12/12/12 5.0 10.0 ND 8.2 J ND
05/01/13 5.0 10.0 5.7 J ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 4.4 J 3.6 J ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Cobalt 05/20/98 ---10 2.0 2.0 ---
11/19/98 ---10 ND 3.0 ---
07/21/99 ---10 ND ND ---
11/16/99 ---10 ND ND ---
05/10/00 ---10 ND ND ---
10/26/00 ---10 ND ND ---
04/18/01 ---10 ND ND ---
10/27/01 ---10.0 ND 22.0 ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND 10.0 ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 4.2 B 1.20 B 1.8 J
07/08/08 ---10.0 4.80 B 10.5 B 6.20 J
12/17/08 0.6 10.0 1.70 B 1.1 B 2.50 J
07/09/09 0.6 10.0 ND ND ND
12/16/09 0.6 10.0 ND 1.0 J ND
NC 2B = NE µg/L (03/24/10)06/24/10 0.6 10.0 ND ND ND
12/13/10 0.6 10.0 {4.4}B {ND}1.6 {1.0 J}J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
Resample >01/25/12 5.0 10.0 ------ND
06/11/12 5.0 10.0 ND 5.10 J ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
Copper 12/29/06 ---10.0 1.3 B 1.10 B 0.60 J
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 5.3 B ND 9.8
NC 2B = 7 µg/L (03/28/08)07/08/08 ---10.0 1.7 J 4.20 J ND
12/17/08 0.3 10.0 1.40 J 1.50 J ND
07/09/09 0.3 10.0 ND ND ND
12/16/09 0.3 10.0 1.90 J 2.00 J ND
06/24/10 0.3 10.0 ND 3.10 J ND
12/13/10 0.3 10.0 0.31 B ND 0.49 J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND 5.50 J ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Lead 05/20/98 ---10.0 ND 8.00 ---
11/19/98 ---10.0 ND ND ---
07/21/99 ---10.0 ND 10.0 ---
11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---
10/26/00 ---10.0 ND ND ---
04/18/01 ---10.0 ND ND ---
10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND ND ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 ND ND ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---10.0 ND ND ND
12/17/08 4.0 10.0 ND ND ND
07/09/09 4.0 10.0 ND ND ND
12/16/09 4.0 10.0 ND ND ND
06/24/10 4.0 10.0 ND ND ND
12/13/10 4.0 10.0 ND ND ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
Nickel 12/29/04 ---50.0 ND 50.0 (ND)ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND
06/28/06 ---50.0 ND ND ND
12/29/06 ---50.0 ND 2.9 J ND
07/12/07 ---50.0 3.8 J ---ND
12/19/07 ---50.0 6.0 31.5 ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---50.0 3.2 J 29.8 J ND
12/17/08 1.7 50.0 2.4 B 4.0 B 2.4 J
07/09/09 1.7 50.0 4.1 J 12.3 J ND
12/16/09 1.7 50.0 3.8 B 4.4 B 3.0 J
06/24/10 1.7 50.0 ND 2.0 J ND
12/13/10 1.7 50.0 ND 14.2 J 2.7 J
06/20/11 5.0 50.0 ND 7.8 J ND
12/05/11 5.0 50.0 ND 5.3 J ND
06/11/12 5.0 50.0 ND 11.0 J ND
12/12/12 5.0 50.0 ND 13.8 J ND
05/01/13 5.0 50.0 ND ND ND
08/05/13 5.0 50.0 ND 5.6 J ND
02/24/14 5.0 50.0 ND ND ND
08/12/14 EPA 6010 5.0 50.0 ---20.3 J ND
03/10/15 EPA 6010 2.5 50.0 3.0 J 3.8 J ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Silver 07/12/07 ---10.0 2.20 J ---ND
12/19/07 ---10.0 ND 0.34 J ND
NC 2B = 0.06 µg/L (03/28/08)07/08/08 ---10.0 0.35 B 1.00 J 0.12 J
12/17/08 0.1 10.0 ND ND ND
07/09/09 0.1 10.0 ND 0.10 J ND
12/16/09 0.1 10.0 ND 0.16 J ND
06/24/10 0.1 10.0 ND 0.26 J ND
12/13/10 0.1 10.0 {ND}{0.28}B 0.21 {0.19 J}J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
Thallium 12/29/04 ---10.0 ND 10.0 (ND)ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---6.00 ND ND ND
07/12/07 ---5.5 ND ---ND
12/19/07 ---5.5 3.60 J ND ND
07/08/08 ---5.5 3.40 J ND ND
12/17/08 3.0 5.5 ND ND ND
07/09/09 3.0 5.5 ND ND ND
12/16/09 3.0 5.5 ND ND ND
NC 2B = NE (03/24/10)06/24/10 3.0 5.5 ND ND ND
12/13/10 3.0 5.5 3.80 J ND ND
06/20/11 5.4 5.5 ND ND ND
12/05/11 5.4 5.5 ND ND ND
06/11/12 5.4 5.5 ND ND ND
12/12/12 5.4 5.5 ND ND ND
05/01/13 5.4 5.5 ND ND ND
08/05/13 5.4 5.5 ND ND ND
02/24/14 5.4 5.5 ND ND ND
08/12/14 EPA 6010 5.4 5.5 ---ND ND
03/10/15 EPA 6010 5.0 5.5 ND ND ND
08/18/15 ------Dry Dry ---
Vanadium 12/29/06 ---25.0 1.60 J 2.00 J ND
07/12/07 ---25.0 4.60 J ---ND
12/19/07 ---25.0 3.30 J 1.40 B 0.62 J
NC 2B = NE µg/L (03/28/08)07/08/08 ---25.0 5.20 J 2.30 J 0.20 J
12/17/08 0.2 25.0 1.80 B 2.70 B 0.76 J
07/09/09 0.2 25.0 5.00 B 3.40 B 1.30 J
12/16/09 0.2 25.0 3.60 J 3.50 J 0.53 J
06/24/10 0.2 25.0 5.80 J 2.60 J ND
12/13/10 0.2 25.0 1.60 B 0.67 B 0.36 J
06/20/11 5.0 25.0 ND ND ND
12/05/11 5.0 25.0 ND ND ND
06/11/12 5.0 25.0 ND 11.50 J ND
12/12/12 5.0 25.0 ND ND ND
05/01/13 5.0 25.0 ND ND ND
08/05/13 5.0 25.0 ND ND ND
02/24/14 5.0 25.0 ND ND ND
08/12/14 EPA 6010 5.0 25.0 ---ND ND
03/10/15 EPA 6010 2.5 25.0 3.9 J 4.7 J ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Zinc 11/22/96 ---50.0 11.0 ND ---
06/17/97 ---50.0 ND ND ---
12/01/97 ---50.0 20.0 ND ---
05/20/98 ---50.0 20.0 28.0 ---
11/19/98 ---50.0 ND ND ---
07/21/99 ---50.0 ND ND ---
11/16/99 ---50.0 ND ND ---
05/10/00 ---50.0 ND ND ---
10/26/00 ---50.0 ND ND ---
04/18/01 ---50.0 ND ND ---
10/27/01 ---50.0 ND ND ---
06/13/02 ---50.0 ---------
11/19/02 ---50.0 ND ND ---
06/27/03 ---50.0 ND ND ---
12/30/03 ---50.0 ND ND ND
06/30/04 ---50.0 ND ND ND
12/29/04 ---50.0 ND ND ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND
06/28/06 ---50.0 ND ND ND
12/29/06 ---50.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 24.6 B ND 102
NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 ND ND 1.20 J
12/17/08 0.4 10.0 ND 0.89 B 0.49 J
07/09/09 0.4 10.0 ND 4.90 B 1.60 J
12/16/09 0.4 10.0 2.60 B 2.60 B 7.70 J
06/24/10 0.4 10.0 ND 14.9 ND
12/13/10 0.4 10.0 ND 9.80 B 6.70 J
06/20/11 10.0 10.0 ND ND ND
12/05/11 10.0 10.0 ND ND 12.4
06/11/12 10.0 10.0 ND ND ND
12/12/12 10.0 10.0 ND ND ND
05/01/13 10.0 10.0 ND 16.80 ND
08/05/13 10.0 10.0 ND ND ND
02/24/14 10.0 10.0 ND ND ND
08/12/14 EPA 6010 10.0 10.0 ---ND ND
03/10/15 EPA 6010 5.0 10.0 7.7 B 7.8 B 5.6 J
08/18/15 ------Dry Dry ---
ORGANICS
Acetone 10/27/01 ---100 168.0 B 337.0 B 479.0
06/13/02 ---100 ---------
06/13/02 ---100 ---------
11/19/02 ---100 ND ND ---
06/27/03 ---100 ND ND ---
12/30/03 ---100 ND ND ND
06/30/04 ---100 ND ND ND
12/29/04 ---100 ND ND ND
06/29/05 ---100 ND ND ND
12/29/05 ---100 ND ND ND
06/28/06 ---100 ND ND ND
12/29/06 ---100 ND ND ND
07/12/07 ---100 ND ---ND
12/19/07 ---100 12.70 B ND 4.50 J
NC 2B = 2,000 µg/L (03/28/08)07/08/08 ---100 ND ND ND
12/17/08 20 100 ND ND ND
07/09/09 20 100 ND ND ND
NC 2B = NE (03/24/10)12/16/09 2.2 100 ND ND 2.80 J
06/24/10 2.2 100 2.80 B ND 7.70 J
12/13/10 2.2 100 ND 3.00 J ND
06/20/11 2.2 100 ND 3.80 B 3.90 J
12/05/11 2.2 100 ND 7.20 B 8.80 J
06/11/12 2.2 100 ND 5.50 B 4.70 J
12/12/12 10.0 100 ND ND ND
05/01/13 10.0 100 ND ND 14.6 J
08/05/13 10.0 100 ND ND ND
02/24/14 10.0 100 ND ND 25.7 J
08/12/14 EPA 8260 10.0 100 ---ND 22.0 J
03/10/15 EPA 8260 10.0 100 ND ND ND
08/18/15 ------Dry Dry ---
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 7
Joyce Engineering
TABLE 2: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Chlorobenzene 06/27/03 ---5.0 ND 7.20 ND
12/30/03 ---5.0 ND ND ND
06/30/04 ---5.0 ND ND ND
12/29/04 ---5.0 ND ND ND
06/29/05 ---5.0 ND ND ND
12/29/05 ---5.0 ND ND ND
06/28/06 ---5.0 ND ND ND
12/29/06 ---3.0 ND ND ND
07/12/07 ---3.0 ND ---ND
12/19/07 ---3.0 ND ND ND
NC 2B = 130 µg/L (03/28/08)07/08/08 ---3.0 ND ND ND
12/17/08 0.23 3.0 ND ND ND
07/09/09 0.23 3.0 ND ND ND
12/16/09 0.23 3.0 ND ND ND
06/24/10 0.23 3.0 ND ND ND
12/13/10 0.23 3.0 ND ND 0.28 J
06/20/11 0.23 3.0 ND ND ND
12/05/11 0.23 3.0 ND ND ND
06/11/12 0.23 3.0 ND ND ND
12/12/12 0.23 3.0 ND ND ND
05/01/13 0.23 3.0 ND ND ND
08/05/13 0.23 3.0 ND ND ND
02/24/14 0.23 3.0 ND ND ND
08/12/14 EPA 8260 0.23 3.0 ---ND ND
03/10/15 EPA 8260 0.23 3.0 ND ND ND
08/18/15 ------Dry Dry ---
Chloromethane 07/09/09 0.11 1.0 ND 0.19 J ND
12/16/09 0.11 1.0 ND ND ND
NC 2B = NE (03/24/10)06/24/10 0.11 1.0 ND ND ND
12/13/10 0.11 1.0 ND ND ND
06/20/11 0.11 1.0 ND ND ND
12/05/11 0.11 1.0 ND ND ND
06/11/12 0.11 1.0 ND ND ND
12/12/12 0.11 1.0 ND ND ND
05/01/13 0.11 1.0 ND ND ND
08/05/13 0.11 1.0 ND ND ND
02/24/14 0.11 1.0 ND ND 0.25 J
08/12/14 EPA 8260 0.11 1.0 ---ND ND
03/10/15 EPA 8260 0.11 1.0 ND ND ND
08/18/15 ------Dry Dry ---
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.
NE = Not established.
Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
**SW- 1 and SW-2 were both dry and unable to be sampled on the 8/18/2015 sampling event.**
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 7
Joyce Engineering

Appendix E

Statistical Analysis Worksheets & Summary

JOYCE Project:Granville County - Butner Landfill
Project No:660.1501.12
Date:August 2015
Analyte:Antimony Quantitation
Concentration Limit
Sample No.Sample Date Location (µg/L)Notes (µg/L)
1 8-Sep-94 MW-1R ND 30 8.8
2 1-Dec-94 MW-1R ND 30 30.0
3 9-Feb-95 MW-1R ND 30
4 2-Mar-95 MW-1R ND 30
5 15-Nov-95 MW-1R ND 30
6 28-May-96 MW-1R ND 30
7 22-Nov-96 MW-1R ND 30
8 17-Jun-97 MW-1R ND 30
9 1-Dec-97 MW-1R ND 30
10 20-May-98 MW-1R ND 30
11 19-Nov-98 MW-1R ND 30
12 21-Jul-99 MW-1R ND 30
13 16-Nov-99 MW-1R ND 30
14 10-May-00 MW-1R ND 30
15 26-Oct-00 MW-1R 30.0 30
16 18-Apr-01 MW-1R ND 30
17 27-Oct-01 MW-1R ND 30
18 13-Jun-02 MW-1R ND 30
19 19-Nov-02 MW-1R ND 30
20 27-Jun-03 MW-1R ND 30
21 30-Dec-03 MW-1R ND 30
22 30-Jun-04 MW-1R ND 30
23 29-Dec-04 MW-1R ND 30
24 29-Jun-05 MW-1R ND 30
25 29-Dec-05 MW-1R ND 30
26 28-Jun-06 MW-1R ND 30
27 29-Dec-06 MW-1R ND 6
28 12-Jul-07 MW-1R ND 6
29 19-Dec-07 MW-1R ND 6
30 8-Jul-08 MW-1R ND 6
31 17-Dec-08 MW-1R ND 6.0
32 9-Jul-09 MW-1R ND 6.0
33 16-Dec-09 MW-1R ND 6.0
34 24-Jun-10 MW-1R ND 6.0
35 13-Dec-10 MW-1R ND 6.0
36 20-Jun-11 MW-1R ND 6.0
37 5-Dec-11 MW-1R ND 6.0
38 11-Jun-12 MW-1R ND 6.0
39 12-Dec-12 MW-1R ND 6.0
40 1-May-13 MW-1R ND 6.0
41 5-Aug-13 MW-1R ND 6.0
42 24-Feb-14 MW-1R 8.8 6.0
43 12-Aug-14 MW-1R ND 6.0
44 10-Mar-15 MW-1R ND 6.0
45 17-Aug-15 MW-1R ND 6.0
Number of Data:45
Number of Truncated Data:43
Percentage of Truncated Data:96%
Upper Poisson Prediction Limit: 56 µg/L
All concentrations in micrograms per liter (µg/L).
ND - Not Detected (Truncated)
Sorted
Concentration
JOYCE Project:Granville County - Butner Landfill
Project No:660.1501.12
Date:August 2015
Upper Poisson Prediction Limit
Analyte:Antimony
Background Data Quantitation Half Discrete
Concentration Limit Quantitation Poisson
Sample No.Sample Date Location (µg/l)(µg/l)Limit Count
1 Sep-94 MW-1R ND 30 15 150
2 Dec-94 MW-1R ND 30 15 150
3 Feb-95 MW-1R ND 30 15 150
4 Mar-95 MW-1R ND 30 15 150
5 Nov-95 MW-1R ND 30 15 150
6 May-96 MW-1R ND 30 15 150
7 Nov-96 MW-1R ND 30 15 150
8 Jun-97 MW-1R ND 30 15 150
9 Dec-97 MW-1R ND 30 15 150
10 May-98 MW-1R ND 30 15 150
11 Nov-98 MW-1R ND 30 15 150
12 Jul-99 MW-1R ND 30 15 150
13 Nov-99 MW-1R ND 30 15 150
14 May-00 MW-1R ND 30 15 150
15 Oct-00 MW-1R 30 30 30 300
16 Apr-01 MW-1R ND 30 15 150
17 Oct-01 MW-1R ND 30 15 150
18 Jun-02 MW-1R ND 30 15 150
19 Nov-02 MW-1R ND 30 15 150
20 Jun-03 MW-1R ND 30 15 150
21 Dec-03 MW-1R ND 30 15 150
22 Jun-04 MW-1R ND 30 15 150
23 Dec-04 MW-1R ND 30 15 150
24 Jun-05 MW-1R ND 30 15 150
25 Dec-05 MW-1R ND 30 15 150
26 Jun-06 MW-1R ND 30 15 150
27 Dec-06 MW-1R ND 6 3 30
28 Jul-07 MW-1R ND 6 3 30
29 Dec-07 MW-1R ND 6 3 30
30 Jul-08 MW-1R ND 6 3 30
31 Dec-08 MW-1R ND 6 3 30
32 Jul-09 MW-1R ND 6 3 30
33 Dec-09 MW-1R ND 6 3 30
34 Jun-10 MW-1R ND 6 3 30
35 Dec-10 MW-1R ND 6 3 30
36 Jun-11 MW-1R ND 6 3 30
37 Dec-11 MW-1R ND 6 3 30
38 Jun-12 MW-1R ND 6 3 30
39 Dec-12 MW-1R ND 6 3 30
40 May-13 MW-1R ND 6 3 30
41 Aug-13 MW-1R ND 6 3 30
42 Feb-14 MW-1R 8.8 6 8.8 88
43 Aug-14 MW-1R ND 6 3 30
44 Mar-15 MW-1R ND 6 3 30
45 Aug-15 MW-1R ND 6 3 30
Poisson Discrete Distribution Adjustment Factor:10
Note: All sample concentrations are micrograms per liter
Using the background data, the upper Poisson Prediction Limit, y*, is determined by:
y* = c y + [(t^2) c / 2] + t c [y (1 + (1/c)) + ((t^2) / 4)]^0.5
where:c = k / n
y = Poisson count
t = t(n-1, 0.95), Student's t-distribution
n-1 = degrees of freedom (number of samples - 1)
k = number of downgradient samples per event
.95 = confidence interval
n = number of background samples
For:c = 0.111
y = 4678
t = 1.679
k = 5
n = 45
y* = 560.28
Adjusted y* = 56.03 µg/L
JOYCE Project:Granville County - Butner Landfill
Project No:660.1501.12
Date:17-Aug-15
Analyte:Cobalt
Sample No.Sample Date Location Concentration Sorted
1 Sep-94 MW-1R ND 130
2 Dec-94 MW-1R 11 108
3 Feb-95 MW-1R 20 32.0
4 Mar-95 MW-1R 16 30.0
5 Nov-95 MW-1R 20 21.0
6 May-96 MW-1R 30 20.0
7 Nov-96 MW-1R 6 20.0
8 Jun-97 MW-1R 130 16.0
9 Dec-97 MW-1R 32 15.0
10 May-98 MW-1R 15 11.0
11 Nov-98 MW-1R 21 6.0
12 Jul-99 MW-1R ND
13 Nov-99 MW-1R ND
14 May-00 MW-1R ND
15 Oct-00 MW-1R ND
16 Apr-01 MW-1R ND
17 Oct-01 MW-1R ND
18 Jun-02 MW-1R ND
19 Nov-02 MW-1R ND
20 Jun-03 MW-1R ND
21 Dec-03 MW-1R ND
22 Jun-04 MW-1R ND
23 Dec-04 MW-1R ND
24 Jun-05 MW-1R ND
25 Dec-05 MW-1R ND
26 28-Jun-06 MW-1R ND
27 29-Dec-06 MW-1R ND
28 12-Jul-07 MW-1R ND
29 19-Dec-07 MW-1R 2.5 B
30 08-Jul-08 MW-1R 10.3 B
31 17-Dec-08 MW-1R 2.1 B
32 09-Jul-09 MW-1R ND
33 16-Dec-09 MW-1R ND
34 24-Jun-10 MW-1R ND
35 13-Dec-10 MW-1R 2.5 B
36 20-Jun-11 MW-1R 108
37 05-Dec-11 MW-1R ND
38 11-Jun-12 MW-1R ND
39 12-Dec-12 MW-1R ND
40 01-May-13 MW-1R ND
41 08-May-13 MW-1R ND
42 24-Feb-14 MW-1R ND
43 12-Aug-14 MW-1R ND
44 10-Mar-15 MW-1R ND
45 17-Aug-15 MW-1R ND
Number of Samples:41
Number of truncated data (ND):30
Percent Truncated:73%
130 µg/L
Notes:
All concentrations in micrograms per liter (µg/L).
J = Estimated value below RL (included in statistical calculations).
B = Blank-qualified data (excluded from statistical calculations).
ND = Not Detected (Truncated).
Non-parametric Prediction Limit:
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Joyce Engineering