3902_GranvilleCoButnerLandfillWQMR_DIN28688_20170213

PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

BUTNER LANDFILL
PERMIT NO. 39-02

FIRST SEMIANNUAL
WATER QUALITY MONITORING REPORT
OF 2017

JUNE 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 660.1701.12

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First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Granville County - Butner Landfill, Permit No. 39-02 June 2017
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First Semiannual Water Quality Monitoring Report of 2017
Butner Landfill, Permit No. 39-02
Granville County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1
1.1 Site Information ...................................................................................................................1
1.2 Site Geology.........................................................................................................................1
1.3 Groundwater Monitoring History ........................................................................................1
1.4 Regulatory Status .................................................................................................................2
2.0 FACILITY MONITORING PROGRAM .......................................................................3
2.1 Groundwater Monitoring Program ......................................................................................3
2.2 Surface Water Monitoring Program .....................................................................................3
3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017 ................................................4
3.1 Field Work ...........................................................................................................................4
3.2 Laboratory Analysis and JOYCE Quality Control ..............................................................4
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES....................................5
4.1 Analytical Results for Groundwater and Comparisons to Standards ...................................5
4.1.1 Inorganic Analyses.................................................................................................... 5
4.1.2 Organic Analyses ...................................................................................................... 5
4.2 Statistical Analyses ..............................................................................................................6
4.2.1 Statistical Methods .................................................................................................... 6
4.2.2 Results of Statistical Analyses .................................................................................. 6
4.3 Analytical Results for Surface Water and Comparisons to Standards .................................7
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................7
6.0 CORRECTIVE ACTION EVALUATION .....................................................................8
6.1 Monitored Natural Attenuation Parameters .........................................................................8
6.2 Phytoremediation .................................................................................................................8
6.3 Evaluation of Plume Stability and Trends ...........................................................................8
7.0 CONCLUSIONS ................................................................................................................9
8.0 REFERENCES ...................................................................................................................9
9.0 ACRONYMS ....................................................................................................................10

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TABLE OF CONTENTS
(Continued)

Tables Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Hydraulic Gradients and Groundwater Flow Velocities Table 4 Quantified Detections of Groundwater Constituents
Table 5 Exceedances of Groundwater Standards Table 6 Field Parameters
Table 7 Monitored Natural Attenuation Parameters

Chart Chart 1 Benzene Concentrations vs. Time

Figure
Figure 1 Site Location Map

Drawing
Drawing 1 Groundwater Potentiometric Surface Map (February 2017)
Drawing 2 Tree Survey (2016)

Appendices
Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater
Appendix D Historical Constituents in Surface Water
Appendix E Statistical Analyses Worksheets & Summary

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First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
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First Semiannual Water Quality Monitoring Report of 2016
Butner Landfill, Permit No. 39-02

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route
1004 near the town of Butner, in Granville County, North Carolina (Figure No. 1). The Butner
facility started receiving waste prior to May 1973. Permit Number 39-02, was issued by the
State of North Carolina on March 3, 1982. The facility stopped receiving waste in August 1998.
A small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.

In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the
Butner Landfill entered an Assessment Monitoring Program in December of 1997 as a result of
detections of volatile organic compounds and pesticide above 15A-NCAC-2L (NC2L)
Groundwater Standards. An Assessment of Corrective Measures (ACM) was initiated in 2003,
and then suspended by North Carolina Department of Environment and Natural Resources
(DENR) [now the Department of Environmental Quality (NCDEQ)] since there had been no
more NC2L exceedances. The Nature and Extent Study (NES) and ACM recommenced in 2007
when apparent volatile organic compound (VOC) exceedances of the NC2L Standards began to
appear; however, they were again suspended when it was determined that the apparent
exceedances were not statistically significant increases (SSIs) above background. An ACM was
reinitiated after an exceedance of benzene in MW-2R in December 2012, and was submitted to
DENR in May 2013. Approval of the ACM was granted in a letter from DENR dated June 27,
2013. A Corrective Action Plan (CAP) for monitored natural attenuation (MNA) plus
phytoremediation was submitted to DENR on May 23, 2014, and was approved by DENR on
June 18, 2014.

1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the
area consists of rolling hills that support farmland and forest. The majority of the landfill area is
underlain by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into
greenish grey foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford
Formation (conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina
Slate Belt felsic volcanic rocks. There is no exposure of the Sanford Formation at the site;
however, float material consisting of grey, coarse-grained sandstone with quartz pebbles was
observed. Diabase dikes have also been observed in the vicinity of the site. Geologic
descriptions were taken from GAI Consultants’ Groundwater and Surface Water Monitoring
System report (GAI, 1994).

1.3 Groundwater Monitoring History
 April 1994 – Current Monitoring Well Network installed.
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 Dec. 1997 - The facility entered Assessment Monitoring.
 June 2003 – NC2L exceedances for heptachlor in MW-2R and MW-3R initiated an
ACM.
 Dec. 2004 & June 2005 – There were no NC2L exceedances, so DENR agreed to put the
ACM on hold pending future monitoring results. At first, DENR said the facility needed
deed restrictions on adjoining property owned by the County, but this was apparently
based on false information (the County did not own the property) so the requirement for
deed restrictions was dropped.
 Dec. 2006 – Benzene in MW-2R and 1,4-dichlorobenzene in MW-2R and MW-3R
detected above NC2L standards.
 June 14, 2007 - Granville County and JOYCE met with DENR to discuss a strategy for
performing a Nature and Extent Study (NES) and an ACM.
 Nov. 2007 – Nature & Extent well NES-1 was installed downgradient of MW-2R &
MW-3R.
 Dec. 2007 – NES & MNA sampling event on selected wells.
 Dec. 2008 – Organic results above the NC2L standards were determined to not represent
statistically significant exceedances, so corrective action and ACM were suspended with
the concurrence of the DENR and in accordance with the NCSWMR.
 Dec. 2012 – Benzene detections above the NC2L in MW-2R initiated the ACM.
 May 17, 2013 – ACM addressing the benzene detections above the NC2L in MW-2R
submitted to DENR.
 June 27, 2013 – ACM approved by DENR.
 September 3, 2013 – Public meeting and selection of remedy MNA plus
phytoremediation
 May 23, 2014 – CAP submitted to DENR.
 June 18, 2014 – CAP approved by DENR.
 December 2015 – 1st Corrective Action Evaluation Report (CARE) submitted
 February 2, 2016- Corrective Action Evaluation Report (CARE) reviewed and approved
by NCDEQ. NCDEQ denied the request to remove selected MNA parameters but
allowed a modified monitoring frequency beginning February 2017.

1.4 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance
with North Carolina Solid Waste Management Regulations (NCSWMR) §.1634. The site is
currently in a Corrective Action Monitoring Program. Groundwater samples are collected
semiannually and analyzed in accordance with the approved Corrective Action Plan. Surface
water samples are collected and sampled for Appendix I constituents during each sampling
event.

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2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six active groundwater monitoring wells comprise the monitoring network at the Butner
Landfill. The current compliance network consists of the following monitoring wells: MW-1R
(facility background well), MW-2R, MW-3R, MW-4, MW-5, and MW-6. An additional well,
NES-1, was installed as part of a Nature and Extent Study on November 14, 2007. The following
table summarizes the monitoring network and required analytical parameters.

Groundwater Monitoring Network
Monitoring
Well
Date
Installed Classification Monitoring
Program TD (ft)
Lithology of
Screened
Interval
1st SA Event
Analyses 2nd SA Event
Analyses
MW-1R 4/21/94 Background Assessment/
CAMP 45.1 Saprolite App. II, MNA App. I + Det.,
MNA
MW-2R 4/12/94 Compliance/
Performance
Assessment/
CAMP 19.0 Saprolite App. II, MNA App. I + Det.,
MNA
MW-3R 4/14/94 Compliance/
Performance
Assessment/
CAMP 37.2 Bedrock App. II, MNA App. I + Det.,
MNA
MW-4 4/18/94 Compliance Detection 31.5 Bedrock App. I App. I
MW-5 4/18/94 Compliance Detection 23.4 Saprolite App. I App. I
MW-6 4/19/94 Compliance Detection 31.7 Saprolite/
Bedrock App. I App. I
NES-1 11/14/07 Nature &
Extent Sentinel 33.0 Saprolite/
Bedrock COCs, MNA COCs, MNA
App. I = NCSWMR Appendix I list of constituents. App. II = NCSWMR Appendix II list of constituents.
MNA = Monitoring Natural Attenuation parameters. COCs = Constituents of Concern
App. I + Det. = App. I list plus detected App. II constituents. CAMP = Corrective Action Monitoring Plan
Current Appendix II detected constituents: tin, gamma-BHC, heptachlor, 2,4-D, and
endrin aldehyde.
Current COC: Benzene.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide every
third year.
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic
carbon (TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane and ethene every
third year.

2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994 at the
Butner Landfill. The points SW-1 and SW-2 are located respectively upstream and downstream
of the facility, along an unnamed tributary of Picture Creek. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

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3.0 FIRST SEMIANNUAL SAMPLING EVENT OF 2017
3.1 Field Work
On February 13, 2017, Joyce Engineering, (JOYCE) personnel visited the Butner Landfill to
purge and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and
NES-1.

All monitoring wells were purged and sampled using new, disposable bailers. Measurements of
temperature, pH, turbidity and specific conductivity were recorded in a field log. Prior to
sampling, laboratory-supplied containers were prepared with the following information:

 Monitoring well number (completed by laboratory/field personnel),
 Date and time of sample collection (completed by laboratory/field personnel),
 Initials of sampling personnel (completed by laboratory/field personnel),
 Project name and number (completed by the laboratory/field personnel),
 Chemical preservative (completed by the laboratory/field personnel); and
 Requested chemical analysis (completed by the laboratory/field personnel).

Groundwater samples from each monitoring well were collected directly from the bailers into the
provided laboratory containers, either immediately after purging or within 24 hours of the final
purge volume. Immediately after collection, the samples were placed in a laboratory provided
cooler and chilled on ice. Field Logs are provided in Appendix A and field parameters are
summarized in Table 6.

Surface water points SW-1 and SW-2 were sampled. Field Logs are included in Appendix A.

3.2 Laboratory Analysis and JOYCE Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina, analyzed the February 2017,
groundwater and surface water samples under chain-of-custody control. The groundwater
samples from MW-1R, MW-2R, and MW-3R were analyzed for the NC Appendix II list of
constituents. The groundwater samples from MW-4, MW-5, and MW-6 were analyzed for the
NC Appendix I list of constituents. The sample from sentinel well NES-1 was analyzed for
Appendix I VOCs only. Samples from MW-2R and MW-3R were also analyzed for MNA
parameters. The surface water samples were analyzed for NC Appendix I constituents. The
samples were received by the laboratory on February 14, 2017, in good condition, properly
preserved, at proper temperatures, and within analysis hold times.

In addition to samples collected for compliance monitoring at the Butner Landfill, JOYCE
personnel collected a Field Blank as part of the February 2017 sampling event. The Field Blank
was analyzed for the NC Appendix II constituents. Also, a Trip Blank that was prepared by the
laboratory accompanied the volatile sampling containers to and from the laboratory. The Trip
Blank was analyzed for the Appendix II volatile organic compounds. The complete laboratory
analytical reports are included in Appendix B.

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Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data for:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory
Control Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2l.0202 (NC2L) Groundwater Standards or the
NCDEQ Solid Waste Section (SWS) Groundwater Water Protection Standards (GWPS);
and
 Detections that are above historical levels.

The complete laboratory analytical reports and the chains of custody from the February 2017
event are included in Appendix B. Historical analytical results for groundwater and surface
water are presented in Appendices C and D, respectively.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the
NCDEQ-SWS reporting limits (SWSL’s) in one or more wells during the February 2017
sampling event: Barium, copper, cobalt, nickel and zinc. Table 4 summarizes all of the
quantified detections from the February 2017 event.

Cobalt was the only inorganic constituent detected in exceedance of the GWPS at 78.7 mg/L in
MW-5; however, it was not above the statistical background (see section 4.4.2). Exceedances of
groundwater standards from the February 2017 event are summarized in Table 5.

No other inorganic constituents were detected above their GPS during the February 2017
sampling event. The laboratory analytical reports and the chains of custody are included in
Appendix B. Complete historical analytical results for inorganic constituents are included in
Appendix C.

4.1.2 Organic Analyses
Benzene, chlorobenzene and 1,4-dichlorobenzene were detected at quantified concentrations
above the solid waste section report limits (SWSL’s) in monitoring well MW-2R and MW-3R
during the February 2017 sampling event. Table 4 summarizes all of the quantified detections
from the February 2017 event. These results are consistent with historical data.

Benzene was detected above the NC2L and the GPS in MW-2R. Exceedances of groundwater
standards from the February 2017 event are summarized in Table 5. The benzene exceedance in
MW-2R has been addressed in the ACM, approved in June 2013, and the CAP, approved in June
2014. No other organic constituents were detected above their GPS during the February 2017
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sampling event. The laboratory analytical reports and the chains of custody are included in
Appendix B. Historical analytical results for organic constituents are presented in Appendix C.

4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up-gradient background well for the facility. Data
from MW-1R between September 1994 and February 2017 have been used to determine
intrawell statistical background concentrations for constituents detected at the facility.
Alternatively, intrawell statistical backgrounds for a downgradient well may be calculated using
data from that well, excluding the most recent

The background data were evaluated using the Shapiro-Wilk Test, Parametric Prediction Limits,
Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric Prediction Limits, and
Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison’s adjustment, tolerance interval, or prediction limits are used, as appropriate based on
the background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one-tailed tests. The data set was
evaluated to determine the appropriate procedure for calculation of the background value for
each parameter.

4.2.2 Results of Statistical Analyses
Cobalt was the only inorganic constituents detected in exceedance of their NC2L or GWPS
during the February 2017 sampling event. The calculated background concentration for cobalt is
proposed as the Groundwater Protection Standard specific to the site per rule .1634(g.5) of the
NCSWMR. Statistical analysis worksheets can be found in Appendix E. The results of the
February 2017 statistical background calculations are summarized in the following table.

Constituent Data
Distribution
Statistical
Method used to
Establish
Background
Background
Concentration GWPS Proposed
GPS
GPS
Exceedances
Cobalt 5% ND,
Non-normal
Parametric
Tolerance Interval
(Intrawell- MW-5)
251 1 251 None
GWPS = Solid Waste Section Groundwater Standard for constituents with no listed NC2L.
GPS = Groundwater Protection Standard as defined in 15A NCAC .1634(g).
%ND = percentage of background data that is truncated (non-detect).
All concentrations are in µg/L (micrograms per liter).

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4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were sampled during the February 2017 sampling event.
No constituents, organic or inorganic were detected above the SWSL during the February 2017
sampling event.

5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks
northeast of the landfill. Groundwater flow direction at deeper levels within the fractured
bedrock is controlled by fracture orientation. A groundwater surface contour map, developed
with static water level data obtained February 13, 2017, is presented as Drawing 1. The static
water elevations depict groundwater flow to the southeast.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
purging. The groundwater elevations were calculated relative to the surveyed measuring point
(top of casing) for each monitoring well. The historical groundwater elevations are summarized
in Table 2. The groundwater elevation contours shown on Drawing 1 are based on data from the
February 2017 sampling event. Horizontal groundwater gradients along representative flow
paths were estimated from the February 2017 groundwater contours shown on Drawing 1 and are
summarized in Table 3. Horizontal gradients across the site ranged from 0.047 to 0.055 ft/ft, with
an average of approximately 0.0503 ft/ft. This is consistent with previous estimates.

Linear groundwater flow velocities were computed using the modified Darcy equation:
V = Ki/ne
where V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.

The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from slug-
tests conducted in 1994 (GAI, 1994) was used in these calculations. The average effective
porosity (ne = 18%) based on 90% of reported total porosity for soils (GAI, 1994), and ne = 10%
for fractured bedrock were also used. Although the regolith and bedrock are hydraulically
connected, the effective porosity generally decreases with depth into the underlying fractured
bedrock. Groundwater flow direction beneath the landfill is predominantly to the south and
southeast. The calculated flow velocities range from 5.85-6.92 ft/yr, with an average of 6.30
ft/yr.

Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for
this site.

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6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Wells MW-1R (background), MW-2R, MW-3R and NES-1 were analyzed for the following
MNA parameters during the February 2017 sampling event:

MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, and ferrous iron.

MNA Laboratory Parameters: Alkalinity, sulfide, sulfate, nitrate, chloride, biological
oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon
(TOC).

The current and historical MNA parameter data are presented in Table 7, and the laboratory
analytical report for the February 2017 sampling event is included in Appendix B. Based on
response to the first Corrective Action Evaluation Report (CAER) for the facility submitted in
December 2016, changes to the CAP were implemented starting with the February 2017 event
and the following parameters will be monitored every third year: Dissolved carbon dioxide,
dissolved hydrogen, sulfide, volatile fatty acids, dissolved methane, ethene, and ethane.

6.2 Phytoremediation
The third phytoremediation tree survey for the Butner Landfill was conduction in August 2016
and the results were presented in the second semiannual WQMR of 2016. The CAP requires
annual tree surveys, and the next survey is scheduled for summer 2017 and will be submitted
with the second semiannual event of 2017.

6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006, possibly due to a higher quantitation limit and the fact that estimated detections
below the quantitation limit were not reported prior to December 2006. From December 2006 to
present, benzene in MW-2R has fluctuated between 1µg/L and 2 µg/L with a possible, although
weak, downwaard trend. From December 2007 to present, benzene in MW-3R has fluctuated
between 0.3 µg/L and 0.7 µg/L, and benzene in MW 4R has fluctuated between non-detect and
0.4 µg/L.

The benzene concentrations from the February 2017 are within the range of historical
fluctuations. Since there have been no detections of benzene in either the surface water or
sentinel well NES-1, there is no indication that the plume in migrating toward the property
boundary. The plume appears to be stable.
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7.0 CONCLUSIONS
Cobalt in MW-5 was detected above its respective GWPS; however, not above the calculated
background concentrations. The County of Granville requests that the background value (251
mg/L) for cobalt be considered the GPS at the Butner Landfill per rule .1634(g.5) of the
NCSWMR; in which case there was no exceedances of the GPS for inorganic constituents from
the February 2017 sampling event.

Benzene was detected above the NC2L in MW-2R during the February 2017 sampling event. In
response to the historical benzene exceedances in MW-2R, Granville County submitted an ACM
on May 17, 2013, which was approved on June 27, 2013. A CAP was submitted on May 23,
2014 and approved on June 18, 2014. Review of MNA parameter data, plume stability, and
benzene trends indicate that the selected remedies of natural attenuation and phytoremediation
are adequately controlling the plume.

The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. The next semiannual sampling event is scheduled
for tentatively for August 2017.

8.0 REFERENCES
GAI Consultants – NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System,
Granville County, Butner Landfill, NC Permit No. 39-02. June, 1994.

Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.

Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County,
Permit No. 39-02. May 2014.

Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN
Natural Attenuation Decision Support System User’s Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. EPA/600/R-96/087. August 1996.

Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN
Natural Attenuation Decision Support System, Version 1.4 Revisions. United States
Environmental Protection Agency, Office of Research and Development, Washington
DC. July 1997.

North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at
Solid Waste Management Facilities. March 2007.

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9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AOC Area of Concern
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site-specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDENR/NCDEQ)
SWSL North Carolina Solid Waste Section Reporting Limits
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)

TABLES

Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Hydraulic Gradients and Groundwater Flow Velocities
Table 4 Quantified Detections of Groundwater Constituents
Table 5 Exceedances of Groundwater Standards
Table 6 Field Parameters
Table 7 Monitored Natural Attenuation Parameters

TABLE 1: Monitoring Well Construction Data
Permit #Well ID Lat.Long. Surface
Elevation
Top of
Casing
Top of
Screen
Bottom of
Screen
Total
Depth 2WL-24
3WL
8/17/2015
Depth to
Bedrock 4Geologic Unit Construction
Date
Driller's
Reg. #Comments
39-02 MW-1R N36º 09' 55.49"W78º 45' 37.80"461.01 461.01 420.01 405.01 405.01 420.01 417.71 431.01 Fractured
Bedrock 4/21/1994 446 background well
replacement
39-02 MW-2R N36º 09' 38.57"W78º 45' 34.97"326.60 328.94 322.75 307.75 307.75 324.00 328.65 313.60 Weathered
Bedrock 4/12/1994 446 compliance well
replacement
39-02 MW-3R N36º 09' 38.58"W78º 45' 34.85"328.77 330.95 302.94 292.94 292.94 325.77 327.81 315.77 Fractured
Bedrock 4/14/1994 446 compliance well
replacement
39-02 MW-4 N36º 09' 38.93"W78º 45' 30.15"338.97 340.92 322.54 307.54 307.54 329.17 331.05 325.97 Fractured
Bedrock 4/18/1994 446 compliance well
39-02 MW-5 N36º 09' 39.35"W78º 45' 23.77"341.88 344.00 333.36 318.36 318.36 329.08 327.73 324.88 Fractured
Bedrock 4/18/1994 446 compliance well
39-02 MW-6 N36º 09' 47.00"W78º 45' 25.47"360.80 362.80 343.17 328.17 328.17 349.10 347.63 339.60 Fractured
Bedrock 4/19/1994 446 compliance well
39-02 NES-1 N36º 09' 35.65"W78º 45' 31.59"326.22 328.72 311.22 296.22 296.22 304.22 308.80 300.22 Fractured
Bedrock 11/14/2007 2675 sentinel well
Notes:
1. Locations & Elevations based on March 2013 survey.Ft-AMSL = Feet above mean sea level.
2. WL-24 = Water Levels approx. 24 hours after well installation.
3. WL = Water Levels measured on 8/17/2015.
4. Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Typical Montoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Montoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007, and field observations.
WELL ID Other Information1LOCATION1Elevation (Ft-AMSL)
Butner Landfill, Granville County
Permit No. 39-02
Joyce Engineering
TABLE 2: HISTORICAL GROUNDWATER ELEVATION DATA
Background
MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Well TOC Elev.:460.51 331.60 330.96 340.80 343.88 362.53 328.40
Well Depth:56.00 18.85 35.83 31.43 23.52 32.63 32.80
21-Aug-99 418.68 329.13 328.06 330.50 330.83 352.10 NI
16-Nov-99 419.75 325.38 324.51 331.53 334.33 352.97 NI
10-May-00 424.53 329.60 328.83 334.15 334.49 355.72 NI
26-Oct-00 419.21 329.26 328.15 331.33 330.94 352.78 NI
18-Apr-01 418.76 329.42 328.63 333.57 334.36 354.22 NI
26-Oct-01 412.53 329.04 327.94 330.57 330.23 350.92 NI
13-Jun-02 413.70 328.38 327.41 330.21 330.29 351.04 NI
19-Nov-02 413.40 329.25 328.35 331.57 337.17 350.94 NI
27-Jun-03 423.61 329.57 328.93 334.24 333.99 355.21 NI
29-Dec-03 420.23 329.70 329.11 334.49 334.78 354.92 NI
30-Jun-04 418.81 329.38 328.48 332.26 331.39 353.10 NI
28-Dec-04 418.02 329.50 328.91 333.45 334.14 355.14 NI
29-Jun-05 418.81 329.10 329.26 331.62 330.90 352.76 NI
29-Dec-05 413.38 329.29 328.71 332.78 334.27 351.52 NI
27-Jun-06 414.75 329.17 328.40 332.18 333.56 353.43 NI
28-Dec-06 415.54 329.40 328.86 333.57 335.24 354.02 NI
12-Jul-07 438.64 328.69 327.97 331.31 330.52 352.30 NI
18-Dec-07 412.59 328.94 328.08 330.32 327.92 347.90 306.54
8-Jul-08 414.52 329.20 326.00 331.46 330.85 351.03 NM
17-Dec-08 412.79 329.39 328.84 333.15 335.03 350.82 NM
9-Jul-09 417.16 329.17 329.48 332.30 331.36 352.17 310.12
16-Dec-09 418.11 329.55 329.09 334.57 336.94 352.87 NM
24-Jun-10 422.42 329.41 328.77 333.65 333.15 353.62 NM
13-Dec-10 415.96 329.49 328.85 332.81 330.34 350.08 NM
20-Jun-11 416.00 328.95 328.18 336.77 331.38 351.83 NM
5-Dec-11 412.94 329.31 328.65 332.32 329.51 349.87 NM
11-Jun-12 414.56 329.10 328.35 332.52 331.33 351.75 312.50
12-Dec-12 412.83 329.19 328.36 331.67 330.35 349.48 NM
1-May-13 415.69 329.65 329.13 334.49 335.15 353.63 317.11
5-Aug-13 417.97 329.02 328.41 333.32 332.83 353.01 NM
24-Feb-14 415.81 329.68 329.17 334.48 331.63 351.78 316.15
11-Aug-14 416.23 329.38 328.48 332.04 329.08 350.08 310.93
10-Mar-15 417.09 329.87 329.45 335.07 336.42 353.13 317.55
17-Aug-15 417.71 328.65 327.81 331.05 327.73 347.63 308.80
17-Feb-16 418.51 330.10 329.71 335.05 337.53 353.44 317.87
9-Aug-16 418.59 329.50 328.61 332.95 330.95 352.03 312.65
13-Feb-17 415.21 329.45 328.96 333.10 333.03 350.83 313.45

Notes: TOC = Top of casing.Groundwater levels and well depth are measured from TOC.
NM = Water level not measured.Groundwater elevations in feet above mean sea level.
NI = Well not yet installed.
Well ID:
Downgradient
Granville County
Butner Landfill, Permit No. 39-02 Joyce Engineering
TABLE 3: ESTIMATED HYDRAULIC GRADIENTS AND GROUNDWATER FLOW VELOCITIES
GROUND-HORIZ.HYDRAULIC EFFECTIVE LINEAR
FLOW WATER GRADIENT,CONDUCTIVITY,POROSITY VELOCITY,
DIRECTION ELEVATION i K ne V
(feet)(ft/ft)(ft/day)(ft/year)
410
350
400
320
410
320
Average 0.0503 Average 6.30
Notes:
Hydraulic conductivity (K) value is the average of results from slug-tests conducted in 1994 (GAI, 1994).
Effective Porosity based on average of 90% of reported Total Porosity (GAI, 1995) for soils, or 10% (estimated) for fractured rock.
Linear flow velocity = Ki/n (modified Darcy equation).
February 13, 2017
GRADIENT
CALCULATION
SEGMENT
FLOW LINE
LENGTH
(feet)
i 1 1287 ESE
Based on Water Level Data obtained on:
i 2 1633 SE 0.0490 6.18E-02
5.85
0.0551 6.18E-02 0.18
0.18
6.92
6.18E-02
0.18
0.0466
i 3 1632
6.14
SSE
Granville County
Butner Landfill, Permit No. 39-02
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater Constituents
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS COLLECT DATE
3902-MW1R Zinc 12.3 µg/L 10 1000 2/13/2017
3902-MW2R Barium 112 µg/L 100 700 2/13/2017
3902-MW2R Nickel 89.6 µg/L 50 100 2/13/2017
3902-MW2R Benzene 1.2 µg/L 1 1 2/13/2017
3902-MW2R 1,4-Dichlorobenzene 1.9 µg/L 1 6 2/13/2017
3902-MW2R Chlorobenzene 13.6 µg/L 3 50 2/13/2017
3902-MW3R Chlorobenzene 18.0 µg/L 3 50 2/13/2017
3902-MW5 Barium 151 µg/L 100 700 2/13/2017
3902-MW5 Cobalt 78.7 µg/L 10 1*2/13/2017
3902-MW5 Copper 14.5 µg/L 11 50 2/13/2017
NOTES:All Results in micorgrams per liter (µg/L)
MDL = Method Detection Limit
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
Bold= Exceedance of NC2L/GWPS
Butner Landfill, Granville Co.
Permit No. 39-02
Joyce Engineering
TABLE 5: Exceedances of Groundwater Standards
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS Background COLLECT DATE
3902-MW2R Benzene 1.2 µg/L 1 1 NA 2/13/2017
3902-MW5 Cobalt 78.7 µg/L 10 1*270 2/13/2017
NOTES:All Results in micorgrams per liter (µg/L)
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS for antimony and cobalt are based on the statistical backgound for the facility.
NA= Not applicable
Bold = GPS Exceedance.
Butner Landfill, Granville Co.
Permit No. 39-02
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW1R pH 6.10 s.u 2/13/2017
3902-MW1R Temperature 14.8 ºC 2/13/2017
3902-MW1R Conductivity 68.0 µS/cm 2/13/2017
3902-MW1R Turbidity 15.21 NTU 2/13/2017
3902-MW1R Dissolved Oxygen 5.37 mg/L 2/13/2017
3902-MW1R Oxidation Reduction Potential 87.4 mV 2/13/2017
3902-MW1R Static Water Level 45.30 ft 2/13/2017
3902-MW1R Well Depth 56.00 ft 2/13/2017
3902-MW2R pH 6.55 s.u 2/13/2017
3902-MW2R Temperature 14.4 ºC 2/13/2017
3902-MW2R Conductivity 1,535 µS/cm 2/13/2017
3902-MW2R Turbidity 9.35 NTU 2/13/2017
3902-MW2R Dissolved Oxygen 3.16 mg/L 2/13/2017
3902-MW2R Ferrous Iron 3.0 mg/L 2/13/2017
3902-MW2R Oxidation Reduction Potential 0.8 mV 2/13/2017
3902-MW2R Static Water Level 2.15 ft 2/13/2017
3902-MW2R Well Depth 18.85 ft 2/13/2017
3902-MW3R pH 6.67 s.u 2/13/2017
3902-MW3R Temperature 14.9 ºC 2/13/2017
3902-MW3R Conductivity 1,314 µS/cm 2/13/2017
3902-MW3R Turbidity 9.09 NTU 2/13/2017
3902-MW3R Dissolved Oxygen 2.14 mg/L 2/13/2017
3902-MW3R Ferrous Iron 1.5 mg/L 2/13/2017
3902-MW3R Oxidation Reduction Potential -16.5 mV 2/13/2017
3902-MW3R Static Water Level 2 ft 2/13/2017
3902-MW3R Well Depth 35.83 ft 2/13/2017
3902-MW4 pH 6.78 s.u 2/13/2017
3902-MW4 Temperature 15.7 ºC 2/13/2017
3902-MW4 Conductivity 1,155 µS/cm 2/13/2017
3902-MW4 Turbidity 10.15 NTU 2/13/2017
3902-MW4 Static Water Level 7.70 ft 2/13/2017
3902-MW4 Well Depth 31.43 ft 2/13/2017
3902-MW5 pH 6.24 s.u 2/13/2017
3902-MW5 Temperature 14.1 ºC 2/13/2017
3902-MW5 Conductivity 272.3 µS/cm 2/13/2017
3902-MW5 Turbidity 15.05 NTU 2/13/2017
3902-MW5 Static Water Level 10.85 ft 2/13/2017
3902-MW5 Well Depth 23.52 ft 2/13/2017
Butner Landfill, Granville Co.
Permit No. 39-02 1 of 2
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS COLLECT DATE
3902-MW6 pH 7.37 s.u 2/13/2017
3902-MW6 Temperature 15.3 ºC 2/13/2017
3902-MW6 Conductivity 508 µS/cm 2/13/2017
3902-MW6 Turbidity 5.20 NTU 2/13/2017
3902-MW6 Static Water Level 11.7 ft 2/13/2017
3902-MW6 Well Depth 32.63 ft 2/13/2017
3902-NES1 pH 6.46 s.u 2/13/2017
3902-NES1 Temperature 15.2 ºC 2/13/2017
3902-NES1 Conductivity 89.6 µS/cm 2/13/2017
3902-NES1 Turbidity 16.23 NTU 2/13/2017
3902-NES1 Static Water Level 14.95 ft 2/13/2017
3902-NES1 Well Depth 36.1 ft 2/13/2017
3902-SW1 Conductivity 177.9 µS/cm 2/13/2017
3902-SW1 pH 7.47 S.U.2/13/2017
3902-SW1 Temperature 9.3 ºC 2/13/2017
3902-SW1 Turbidity 9.75 NTU 2/13/2017
3902-SW2 Conductivity 348.8 µS/cm 2/13/2017
3902-SW2 pH 7.07 S.U.2/13/2017
3902-SW2 Temperature 10.9 ºC 2/13/2017
3902-SW2 Turbidity 11.92 NTU 2/13/2017
Units: ºC= degrees Centigrade
S.U.= Standard Units
µS/cm = micro-Seimens per centimeter
NTU = Nephelometric Turbidity Units
mV= milivolts
mg/L= miligrams per liter
Butner Landfill, Granville Co.
Permit No. 39-02 2 of 2
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Temperature 12/30/03 ºC --15.4 11.1 11.2 12.5 13.6 14.2 -
(FP)12/19/07 ºC --12.3 12.5 13.1 14.4 14.9 14.4 13.3
05/01/13 ºC --15.7 13.7 15.1 14.4 14.2 14.2 12.5
08/14/14 ºC --17.8 18.0 19.2 19.4 16.8 17.2 16.0
03/10/15 ºC --17.3 16.0 15.9 13.8 13.3 13.7 16.1
08/18/15 ºC --16.4 17.8 17.8 17.3 16.5 16.6 16.1
02/16/16 ºC --14.6 13.8 14.4 14.0 12.0 13.4 13.1
08/09/16 ºC --16.4 17.3 19.4 18.2 17.1 16.8 17.9
02/13/17 ºC --14.8 14.4 14.9 15.7 14.1 15.3 15.2
pH 12/30/03 SU --7.31 6.54 6.81 6.90 7.24 7.29 -
(FP)12/19/07 SU --6.89 6.90 7.07 6.87 7.39 6.67 7.64
05/01/13 SU --7.32 6.37 6.61 6.42 6.92 7.13 6.10
08/14/14 SU --5.84 6.36 6.96 6.79 7.00 6.48 5.59
03/10/15 SU --6.11 6.37 6.56 6.30 6.25 6.55 5.68
08/18/15 SU --5.12 6.68 6.48 6.76 7.03 6.78 4.94
02/16/16 SU --6.15 6.15 6.61 6.69 7.14 6.10 6.52
08/09/16 SU --4.79 5.05 5.30 5.06 4.41 5.75 6.46
02/13/17 SU --6.10 6.55 6.76 6.78 6.24 7.37 6.23
Conductivity 12/19/07 µS/cm --96 1,964 1,591 1,245 --510
(FP)05/01/13 µS/cm --111 1,587 1,357 1,150 195 594 69.6
08/14/14 µS/cm --231 1,897 1,534 1,413 522 565 172.6
03/10/15 µS/cm --90 996 1,277 1,186 106 504 114
08/18/15 µS/cm --134 1,630 1,680 1,244 617 534 83
02/16/16 µS/cm --72.4 1,611 1,369 1,234 164 474 78.2
08/09/16 µS/cm --100.7 1,924 1,535 1,475 660 600 95.6
02/13/17 µS/cm --68.0 1,535 1,314 1,155 272 508 89.6
Redox Potential 12/30/03 mV --257.2 76.2 207.6 212.7 187.3 123.6 -
ORP 12/19/07 mV --146 45.0 142 134 --138
(FP)05/01/13 mV --111.7 -26.7 55.2 120.5 - -227.1
08/14/14 mV --115.8 -37.2 86.9 -- --
03/10/15 mV --87.0 0.8 56.3 -- -96.7
08/18/15 mV --134.7 -96.3 -68.8 -33.9 -49.9 -182.8
02/16/16 mV --111.7 -47.3 16.9 NS NS -173.4
08/09/16 mV --56.0 -43.1 -6.9 NS NS NS NS
02/13/17 mV --87.4 0.8 -16.5 NS NS NS NS
Dissolved Oxygen 12/30/03 mg/L --9.49 4.84 26.19 24.19 15.31 20.17 -
DO 12/19/07 mg/L ---1.88 1.44 3.21 --0.70
(FP)05/01/13 mg/L --4.40 1.37 1.79 4.65 --2.90
08/14/14 mg/L --4.44 3.26 2.48 ---2.80
03/10/15 mg/L --3.84 1.47 1.80 ---1.85
08/18/15 mg/L --4.95 5.75 1.30 -3.79 -1.77
02/16/16 mg/L --4.45 3.66 2.51 ---3.72
08/09/16 mg/L --3.17 2.87 2.29 NS NS NS NS
02/13/17 mg/L --5.37 3.16 2.14 NS NS NS NS
Dissolved CO2 12/19/07 mg/L --25 365 175 295 --60
(FP)05/01/13 mg/L --30.0 245 125 225 --45
08/14/14 mg/L --60.0 390 185 ---75
03/10/15 mg/L --50.0 110 75 ---50
08/18/15 mg/L --30.0 275 125 ---60
02/16/16 mg/L --30.0 210 230 ---20
08/09/16 mg/L --NS 185 210 NS NS NS NS
02/13/17 mg/L --NS NS NS NS NS NS NS
Downgradient
Butner Landfill, Granville Co.
Permit No. 39-02 Page 1 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Fe, Ferrous (+2)12/30/03 mg/L --ND 1.5 ND ND 0.22 ND -
(FP)12/19/07 mg/L --ND 7.2 ND ND --0.2
05/01/13 mg/L --0.0 1.0 0.0 0.0 --0.0
08/14/14 mg/L --0.0 2.5 0 ---0.0
03/10/15 mg/L --0.0 5.3 0 ---0.0
08/18/15 mg/L --0.0 4.5 1 ---0.0
02/16/16 mg/L --0.0 4.0 1 ---0.0
08/09/16 mg/L --NS 3.1 1 NS NS NS NS
02/13/17 mg/L --0.0 3.0 1.50 NS NS NS NS
Alkalinity (as CaCO3)12/30/03 mg/L 9.00 10.0 37.0 800 690 640 68.0 350 -
12/19/07 mg/L -5.00 39.0 763 726 619 --190
05/01/13 mg/L 1.00 5.00 43.4 757 660.0 645.0 --10.4
08/14/14 mg/L 1.00 5.00 41.1 784.0 661.0 ---14.5
03/10/15 mg/L 1.00 5.00 38.0 744.0 653.0 ---8.8
08/18/15 mg/L 1.00 5.00 37.8 772.0 664.0 ---10.3
02/16/16 mg/L 1.00 5.00 41.2 792.0 741.0 ---8.73
08/09/16 mg/L 1.00 5.00 -783.0 629.0 ----
02/13/17 mg/L 1.00 5.00 37.9 753.0 654.00 NS NS NS 8.79
Chloride 12/30/03 mg/L 0.200 1.00 3.50 280 170 82.0 13.0 44.0 -
12/19/07 mg/L -5.00 ND 13.1 297 89.1 --7.90
05/01/13 mg/L 0.5 1.00 3.54 258 180 123 --2.85
08/14/14 mg/L 0.5 1.00 5.53 264 144 ---5.00
03/10/15 mg/L 0.5 1.00 3.80 266 194 ---4.09
08/18/15 mg/L 0.5 1.00 4.69 267 178 ---3.90
02/16/16 mg/L 0.5 1.00 3.92 274 186 ---3.24
08/09/16 mg/L 0.5 1.00 -269 191 ----
02/13/17 mg/L 0.5 1.00 3.45 309 215 NS NS NS 5.09
Dissolved Hydrogen 05/01/13 nM 0.074 0.60 0.400 0.630 0.610 0.500 --0.470
08/14/14 nM 0.13 0.60 1.4 1.6 5.4 ---1.4
03/10/15 nM 0.13 0.60 1.2 1.4 1.4 1.0 --1.4
08/18/15 nM 0.13 0.60 1.7 2.2 1.7 ---1.5
02/16/16 nM 0.13 0.60 2.0 1.7 1.9 ---1.5
08/09/16 nM 0.13 0.60 -1.5 1.6 ----
02/13/17 nM 0.13 0.60 NS NS NS NS NS NS NS
Nitrate-N 12/30/03 mg/L 0.0200 0.0500 0.120 ND ND ND ND 0.13 -
12/19/07 mg/L -0.100 ND ND ND ND --13.0
05/01/13 mg/L 0.001 10.0 0.163 ND ND ND --3.58
08/14/14 mg/L 0.001 10.0 0.115 J ND ND ---2.02 J
03/10/15 mg/L 0.001 10.0 0.252 J ND ND ---2.56 J
08/18/15 mg/L 0.001 10.0 .124 J ND ND ---3.27 J
02/16/16 mg/L 0.001 10.0 .36 J ND ND ---2.54 J
08/09/16 mg/L 0.001 10.0 -ND ND ----
02/13/17 mg/L 0.001 10.0 .248 J .189 J ND NS NS NS 2.63 J
Sulfate 12/30/03 mg/L 0.0600 2.00 ND ND ND 2.60 9.60 9.00 -
12/19/07 mg/L -5.00 ND ND ND ND --36.8
05/01/13 mg/L 1 250 ND ND ND 4.69 --10.7
08/14/14 mg/L 1 250 1.08 J 1.2 J ND ---5.84 J
03/10/15 mg/L 1 250 1.52 J 1.13 J 1.52 J ---7.04 J
08/18/15 mg/L 1 250 1.56 J 1.31 J 2.49 J ---524 J
02/16/16 mg/L 1 250 1.5 J 1.7 J 1.8 J ---10.0 J
08/09/16 mg/L 1 250 -1.22 J 1.75 J ----
02/13/17 mg/L 1 250 1.53 J 1.59 J 1.78 J NS NS NS 11.9 J
Sulfide 08/14/14 mg/L 0.05 1.00 ND ND ND ---ND
03/10/15 mg/L 0.05 1.00 ND ND ND ---ND
08/18/15 mg/L 0.05 1.00 ND ND ND ---1.0
02/16/16 mg/L 0.05 1.00 ND ND ND ---ND
08/09/16 mg/L 0.05 1.00 -ND ND ----
02/13/16 mg/L 0.05 1.00 ND ND ND NS NS NS NS
Butner Landfill, Granville Co.
Permit No. 39-02 Page 2 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Total Organic Carbon 12/19/07 mg/L -1.0 *2.9 54.3 23.2 17.2 --7.20
05/01/13 mg/L 0.5 1.00 2.24 29.5 30.0 19.4 --5.74
08/14/14 mg/L 0.5 1.00 ND 229.00 25.5 ---8.39
03/10/15 mg/L 0.5 1.00 .781J 34.8 9.5 ---1.88
08/18/15 mg/L 0.5 1.00 0.917J 32.9 9.86 ---27.80
02/16/16 mg/L 0.5 1.00 1.500 27.6 8.46 ---40.90
08/09/16 mg/L 0.5 1.00 -29.4 9.53 ---
02/13/17 mg/L 0.5 1.00 ND 28.5 9.72 NS NS NS 1.36
Biochemical Oxygen Demand 08/14/14 mg/L 2.0 2.00 ND 83.4 2.49 ----
BOD 03/10/15 mg/L 2.0 2.00 2.55 10.6 ND ---ND
08/18/15 mg/L 2.0 2.00 2.22 11.8 2.0 ---2.00
02/16/16 mg/L 2.0 2.00 ND 60.0 6.6 ---ND
08/09/16 mg/L 2.0 2.00 -11.6 ND ----
02/13/17 mg/L 2.0 2.00 ND 9.50 J ND NS NS NS ND
Chemical Oxygen Demand 08/14/14 mg/L 12.5 25.0 ND 132.0 ND ---50.00
COD 03/10/15 mg/L 12.5 25.00 15.0J 235.0 96.0 ---ND
08/18/15 mg/L 12.5 25.00 25.00 110.0 756.0 ---25.00
02/16/16 mg/L 12.5 25.00 ND 295.0 50.0 ---ND
08/09/16 mg/L 12.5 25.00 -131.0 50.0 ----
02/13/17 mg/L 12.5 25.00 17.0 J 119.0 43.0 NS NS NS 22.0 J
Dissolved Ethane 12/30/03 mg/L 0.0002 0.0010 ND ND ND ND ND ND -
12/19/07 mg/L -20.0 ND ND ND ND --ND
05/01/13 mg/L 0.0031 0.0062 ND ND ND ND --ND
08/14/14 mg/L 0.0031 0.0062 ND ND 0.0036 J ---ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND ---ND
08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 ---0.01
02/16/16 mg/L 0.0031 0.0062 ND ND ND ---ND
08/09/16 mg/L 0.0031 0.0062 -1.6 J 2.6 J ----
02/13/17 mg/L 0.0031 0.0062 NS NS NS NS NS NS NS
Dissolved Ethene 12/01/03 mg/L 0.0003 0.0010 ND ND ND ND ND ND -
12/19/07 mg/L -20.0 ND ND ND ND --ND
05/01/13 mg/L 0.0031 0.0062 ND ND 0.0017 ND --ND
08/14/14 mg/L 0.0031 0.0062 ND ND ND ---ND
03/10/15 mg/L 0.0031 0.0062 ND ND ND ---ND
08/18/15 mg/L 0.0031 0.0062 0.01 0.01 0.01 ---0.01
02/16/16 mg/L 0.0031 0.0062 ND ND ND ---ND
08/09/16 mg/L 0.0031 0.0062 -ND ND ----
02/13/17 mg/L 0.0031 0.0062 NS NS NS NS NS NS NS
Dissolved Methane 12/30/03 mg/L 0.0002 0.0010 ND 0.660 0.130 0.0099 0.0010 ND -
12/19/07 mg/L -10.0 ND 0.116 0.186 ND --ND
05/01/13 mg/L 0.0033 0.0066 ND 0.0379 0.100 0.0337 --ND
08/14/14 mg/L 0.0033 0.0066 ND 1.2900 0.284 ---ND
03/10/15 mg/L 0.0033 0.0066 0.0072 0.9960 0.158 ---ND
08/18/15 mg/L 0.0033 0.0066 0.0027 2.16 0.316 ---0.0013
02/16/16 mg/L 0.0033 0.0066 0.007 J 0.87 0.098 ---0.0016 J
08/09/16 mg/L 0.0033 0.0066 -1.85 0.206 ----
02/13/17 mg/L 0.0033 0.0066 NS NS NS NS NS NS NS
Butner Landfill, Granville Co.
Permit No. 39-02 Page 3 of 4
Joyce Engineering
TABLE 7: MONITORED NATURAL ATTENUATION PARAMETERS
Background Sentinel
Parameter Date Units DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1
Downgradient
Pyruvic Acid 12/19/07 mg/L 2.50 ND 1.50 2.00 --1.20
05/01/13 mg/L 2 10 ND ND ND ND --ND
08/14/14 mg/L 0.77 10 ND ND ND ---ND
03/10/15 mg/L 0.77 10 0.41J 0.41J 0.41J ---0.41J
08/18/15 mg/L 0.77 10 ND ND ND ---ND
02/16/16 mg/L 0.77 10 ND ND ND ---ND
08/09/16 mg/L 0.77 10 -ND ND ----
02/13/17 mg/L 0.77 10 NS NS NS NS NS NS NS
Lactic Acid 12/19/07 mg/L ND 5.40 11.9 3.10 --ND
05/01/13 mg/L 2.3 25 ND ND ND ND --ND
08/14/14 mg/L 2.5 25 4.2 J ND ND ---ND
03/10/15 mg/L 2.5 25 ND ND ND ---ND
08/18/15 mg/L 2.5 25 ND ND ND ---ND
02/16/16 mg/L 2.5 25 ND ND ND ---ND
08/09/16 mg/L 2.5 25 -ND ND ----
02/13/17 mg/L 2.5 25 NS NS NS NS NS NS NS
Acetic Acid 12/19/07 mg/L ND ND ND ND --ND
05/01/13 mg/L 1.8 5 ND ND ND ND --ND
08/14/14 mg/L 0.81 5.0 ND ND ND ---ND
03/10/15 mg/L 0.81 5.0 ND ND ND ---ND
08/18/15 mg/L 0.81 5.0 ND ND 0.97 J ---ND
02/16/16 mg/L 0.81 5.0 ND ND ND ---ND
08/09/16 mg/L 0.81 5.0 -ND ND ----
02/13/17 mg/L 0.81 5.0 NS NS NS NS NS NS NS
Propionic Acid 12/19/07 mg/L ND 63.7 38.3 12.8 --ND
05/01/13 mg/L 1 5 ND ND ND ND --ND
08/14/14 mg/L 0.66 5.0 ND ND ND ---ND
03/10/15 mg/L 0.66 5.0 ND ND ND ---ND
08/18/15 mg/L 0.66 5.0 ND ND ND ---ND
02/16/16 mg/L 0.66 5.0 ND ND ND ---ND
08/09/16 mg/L 0.66 5.0 -ND ND ----
02/13/17 mg/L 0.66 5.0 NS NS NS NS NS NS NS
Butyric Acid 12/19/07 mg/L ND ND ND ND --ND
05/01/13 mg/L 0.87 5 ND ND ND ND --ND
08/14/14 mg/L 0.70 5.0 ND ND ND ---ND
03/10/15 mg/L 0.70 5.0 ND ND ND ---ND
08/18/15 mg/L 0.70 5.0 ND ND ND ---ND
02/16/16 mg/L 0.70 5.0 ND ND ND ---ND
08/09/16 mg/L 0.70 5.0 -ND ND ---
02/13/17 mg/L 0.70 5.0 NS NS NS NS NS NS NS
Total Volatile Fatty Acids 12/19/07 mg/L 2.50 69.10 51.70 17.90 --1.20
(sum of above 5 acids)05/01/13 mg/L ND ND ND ---ND
08/14/14 mg/L 4.2 J ND ND ---ND
03/10/15 mg/L ND ND ND ---ND
08/18/15 mg/L ND ND 0.97 J ---ND
02/16/16 mg/L ND ND ND ---ND
08/09/16 mg/L -ND ND ----
02/13/17 mg/L -------
NOTES:
DL = laboratory detection limit.mg/L = milligrams per liter ºC = degress Celcius
RL = laboratory reporting limit.mV = millivolt µS/cm = micro-Siemen per centimeter
ND = not detected above detection limit.SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL.nM = nano-Molar
- = not analyzed.
DL and QL for Alkalinity for Dec. 03 event was 1 and 2 respectively for wells MW-2R, -3R, and -4 due to different methods used by the labrotory.
* = RL for MW-1R - 1.0, MW-2R - 5.0, MW-3R - 5.0, MW-4 - 2.0, NES-1 - 5.0.
Methane in December 2007 was out of hold time for MW-2R, MW-3R, MW-4, and NES-1.
Butner Landfill, Granville Co.
Permit No. 39-02 Page 4 of 4
Joyce Engineering

CHART

Chart 1 Benzene Concentrations vs. Time

Granville Co., Butner Landfill
Permit # 39-02
Joyce Engineering
February 2017
0.00
0.25
0.50
0.75
1.00
1.25
1.50
1.75
2.00
Feb-06Aug-06Feb-07Aug-07Feb-08Aug-08Feb-09Aug-09Feb-10Aug-10Feb-11Aug-11Feb-12Aug-12Feb-13Aug-13Feb-14Aug-14Feb-15Aug-15Feb-16Aug-16Feb-17Benzene Concentration (µg/L) CHART 1: Benzene Concentation vs. Time
MW-1R
MW-2R
MW-3R
MW-4R
MW-5
MW-6
NES-1
NC 2L = 1.0

FIGURE

Figure 1 Site Location Map

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

GP-4
GP-6
GP-5
GP-2
GP-1
400
400390390
380380
3703603603
3
0330340ii
i
MW-1R
418.21
MW-4
333.10
MW-5
330.03
MW-6350.83
MW-2R
329.45
MW-3R
328.96
35034
0410410350GP-3
SW-1
SW-2
NES-1
313.45 3303203203303403503603703803904004
4
0
4
3
0
4
2
0
410 4003
9
0
3
8
0
3
7
0
GV
GV
GV
GV
370
32
0
32
0
31
0
310
300
310
APPROXIMATE
LIMITS OF WASTE
APPROXIMATE
LIMITS OF WASTE
GAS PROBE LOCATION AND
IDENTIFICATIONGP-1
1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
2.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET
3.STATIC WATER LEVELS MEASURED ON 02/13/17.
4.GROUNDWATER CONTOURS BASED ON KNOWN DATA,
TOPOGRAPHIC CONTOURS, LINEAR INTERPOLATION AND
EXTRAPOLATION FROM KNOWN FIELD CONDITIONS.
5.ELEVATION RELATIVE TO MEAN SEA LEVEL.
6.GROUNDWATER ELEVATION IS BASED ON A WELL SURVEY
PERFORMED IN APRIL 2008
7.TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
2007 DATA OBTAINED FROM NCDOT WEBSITE.
8.BOUNDARY SURVEY PROVIDED BY BATEMAN CIVIL SURVEY
COMPANY DATED MARCH 15, 2013.
NOTES
LEGEND
PROPERTY LINE
EXISTING ROAD
EXISTING 10' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
GROUNDWATER MONITORING WELL
LOCATION AND IDENTIFICATION
CENTERLINE OF STREAM
GROUNDWATER SURFACE CONTOUR
(FEET ABOVE MEAN SEA LEVEL)380
i SEGMENT USED FOR GRADIENT
CALCULATIONS
GROUNDWATER FLOW DIRECTION WITH
GRADIENT CALCULATION SEGMENT
NOT MEASURED
SURFACE WATER MONITORING POINTSW-1
APPROXIMATE LIMITS OF WASTE
MW-1R
418.59
(NM)
130
GV GAS VENT
FLOW PATH LENGTH
i
i
= 1,287 LF
= 1,633 LF
i = 1,632 LF 2211 W. MEADOWVIEW ROADGREENSBORO, NC 27407PHONE: [phone]NC CORP LIC: C-0782PROJECT NO.APPROVEDCHECKEDDRAWNDESIGNEDDATEDATEREVISIONS AND RECORD OF ISSUEBYNOAPPCKSCALE All rights reserved.Ó Joyce Engineering, Inc.DRAWING NO.L:\Granville\dwg\Butner\GW Event Maps\GW Event 02-17.dwg Layout=Layout1660BUTNER LANDFILLGRANVILLE COUNTY, NORTH CAROLINA20171
AS NOTEDPOTENTIOMETRIC SURFACE MAPFEBRUARY 13, 2017GERWHGEAE02/24/170
(FEET)
GRAPHIC SCALE
20010050

APPENDICES

Appendix A Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Historical Constituents in Groundwater
Appendix D Historical Constituents in Surface Water
Appendix E Statistical Analyses Worksheets & Summary

Appendix A

Field Data Logs

DATE:2/13/17ProjectNo./TaskNo.:00660.1701.12.04Sampler(s):G.Eller/H.Seaton2inches45.30feet56.00feet10.70feet[DTB-DTW]=1.7gallons=_____________gallons=5.1gallons5.1gallonsJOYCEECJGtNEER!NGProjectName:BUTNER,GranvilleCo.WellID:3902-MW-1RWellLocation:GROUNDWATERSAMPLINGLOGNorthoftheentranceatthetreelineunderthetowerWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:--feetTemp.DOCond.ORPTurb.GallonsTimepHInitials°cMg/L(uS/cm)myntu0114615.710.05110.36.6570.08.73GE1.7115015.46.4765.56.4371.516.71GE3.4115315.36.0869.16.2177.913.81GE5.1115514.85.3768.06.1087.415.21GEBefore115514.85.3768.06.1087.415.21GESamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.Fe2:0.0Signature:L1it1u/Date:QAIQCSignOff:.—
-
--
-
-_Date:C—’—r
2inches2.15feet18.85feet16.7feet[DTB-DTW]=2.7gallons=_____________gallons8.1gallons7.0gallonsDATE:2/13/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:00660.1701.12.04Sampler(s):G.Eller/H.SeatonSouthsideoffill,insidetreelineandnexttoMW-3RJOYCEEI\JGIt’JEEflItJGProjectName:BUTNER,GranvilleCo.WellID:3902-MW-2RtVellLocation:_________________________WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653forTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:3.05feetTemp.DO.Cond.ORPTurb.GallonsTimep11Initials°CMg[L(uS/cm)MVntu0095212.91.5815286.42-27.09.15GE2.7095513.61.6015536.48-39.210.06GE5.4095714.61.7515606.54-45.115.17GEDry7.0Before132014.43.1615356.550.89.35HSSamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.Fe2+:3.0m/LSignature:QAIQCSignOff:__________________Date:Date:
ProjectNo./TaskNo.:00660.1701.12.04Sampler(s):H.Seaton/G.Flier2inches2.00feet35.83feet33.83feet[DTB-DTW]=4.4gallons=____________gallons=13.2gallons9.5gallonsDATE:2/13/17GROUNDWATERSAMPLINGLOGJOYCEProjectName:BUTNER.GranvilleCo.WellID:3902-MW-3RWellLocation:NexttoMW-2R,insidetreelineWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163for4”Well:WCTX0.653forTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:2.75feetTemp.DOCond.Turb.GallonsTimepHOR?Initials°CmgfL(uS/cm)ntu0094012.37.0311077.1464.910.42HS4.4094314.85.1011187.2867.49.75HS8.8094815.03.1612006.8034.09.80HSDry9.5Before130714.92.1413146.76-16.59.09HSSamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.fe2+:1.5mg/LSignature:QAIQCSignOff:___________________Date:Date:
DATE:2/13/17ProjectNo./TaskNo.:00660.1701.12.04Sampler(s):H.Seaton/G.Eller2inches7.70feet31.43feet23.73feet[DTB-DTW]=3.9gallons=_____________gallons=11.7gallons8.2gallonsJOYCE1EfJGItJERR!t’JGProjectName:BUTNER,GranvilleCo.WellID:3902-MW-4WellLocation:southoffill.lustinsidetreelineGROUNDWATERSAMPLINGLOGWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:—14.00feetTemp.Cond.Turb.GallonsTimepHInitials°C(uS/cm)ntu0100914.211926.639.45HS3.9101215.712146.6912.91HS7.8101516.012016.7617.13HSDry@8.2galBefore112715.711556.7810.15HSSamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.Signature:cU‘V4ve%LQA/QCSignOff:__________________Date:Date:II7‘—V-
2inches10.85feet23.52feet12.67feet[DTB-DTW]=2.0gallons=____________gallons=6.0gallons3.5gallonsDate:—L—tc-Date:DATE:2/13/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:00660.1701.12.04Sampler(s):H.Seaton/G.EllerSouthsideofoldSED.nond.BasininthewoodsJOYCEEt\JG1t’JEERtJGProjectName:BUTNER,GranvilleCo.WellID:3902-MW-5WellLocation:--WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DIR):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposableBailerSampledwith:disposableBailerDepthtoWaterbeforeSampling:13.10feetTemp.Cond.Turb.GallonsTimepHInitials°C(uS/cm)ntu0102513.8226.46.259.85GE2.0102713.9211.35.8715.43GEDry@3.5Before111814.1272.36.2415.05GESamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.Signature:FL4(4-ç15LQAIQCSignOff:__________________
2inches11.70feet32.63feet20.93feet[DTB-DTW]=3.4gallonsgallons=10.2gallons10.2gallonsDATE:2/13/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:00660.1701.12.04Sampler(s):H.Seaton/G.EllerothersideoflargemulchnileJOYCEProjectName:BUTNER,GranvilleCo.WellID:3902-MW-6WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(‘VV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposableBailerSampledwith:disposableBailerDepthtoWaterbeforeSampling:--feetTemp.Cond.Turb.GallonsTimepHInitials°C(uS/cm)ntu0104614.76.86470.44.20HS3.4104915.27.025184.701186.8105215.57.035355.80HS10.2105615.37.375085.20HSBefore105615.37.375085.20HSSamplingConunents(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemneraturesinthe60son2/13/17.Signature:)C—I41J%(%àCi%Date:QA/QCSignOff:_________________Date:,3-t
DATE:2/13/17Signature:tC>cIb171QAIQCSignOff:__________________2inches14.95feet36.10feet21.15feet[DTB-DTW]=3.4gallons=_____________gallons=10.2gallons10.2gallonsJOYCE________ENG1NEER!t’JGGROUNDWATERSAMPLINGLOGProjectName:BUTNER,GranvilleCo.ProjectNo./TaskNo.:00660.1701.12.04WellID:3902-NES-1Sampler(s):H.Seaton/G.EllerWellLocation:Southoflandfill,accessthroughWildlifeAreahuntcampWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(‘WV):for2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:disposablebailerSampledwith:disposablebailerDepthtoWaterbeforeSampling:15.00feetTemp.Cond.Turb.GallonsTimep11Initials°C(uS/cm)ntu0123814.585.75.9324.2HS3.4124114.6131.05.7747.0HS6.8124414.775.15.46123.5HS10.2124914.866.35.31>1000HSBefore141515.289.66.2316.23HSSamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.Fe2:0.0Date:Date:t3-t2/a,-,/,.,C
DATE:2/13/17JOYCE_________EC4GthJEERINGSURFACEWATERMONITORINGLOGProjectName:BUTNER,GranvilleCo.Project/TaskNo.:00660.1701.12.04SurfacePointID:3902-SW-iSampler(s):H.Seaton/G.EllerLocation:NearSed.pond,BasinFieldParameters:TimeofSampling:1111pH:7.47Temperature:9.3(°C)Conductivity:177.9(uS/cm)Turbidity:9.75(ntu)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperamresinthe60son2/13/17.SketchofSampleLocation(includeflowdirection,drainagepathways,etc.):NSignature:_____________________________Date:2—(3—11—QAIQCSignOff:,-Date:/z/,7
DATE:2/13/17JOYCE_________E1\JGIt’]EERINGSURFACEWATERMONITORINGLOGProjectName:BUTNER,GranvilleCo.Project/TaskNo.:00660.1701.12.04SurfacePointID:3902-SW-2Sampler(s):H.Seaton/G.EllerLocation:DownfromMW-2R&MW-3RfieldParameters:TimeofSampling:1240pH:7.07Temperature:10.9(°C)Conductivity:348.9(uS/cm)Turbidity:11.92(utu)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe60son2/13/17.FIELDBLANK@1430SketchofSampleLocation(includeflowdirection,drainagepathways,etc.):hi1’MW)-ThN2N:_w-Z__
__
_Signature:/JeA,U’Date:-QA/QCSignOff:_________________Date:7

Appendix B

Laboratory Analytical Reports

#=CL#
February 28, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92329884
92329884
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL COMPLIANCE
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 14, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
1(704)875-9092
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 77
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 77
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Matrix Date Collected Date Received
92329884001 3902-MW1R Water 02/13/17 11:55 02/14/17 10:25
92329884002 3902-MW2R Water 02/13/17 13:20 02/14/17 10:25
92329884003 3902-MW3R Water 02/13/17 13:07 02/14/17 10:25
92329884004 3902-FIELD BLANK Water 02/13/17 14:30 02/14/17 10:25
92329884005 3902-MW4 Water 02/13/17 11:27 02/14/17 10:25
92329884006 3902-MW5 Water 02/13/17 11:18 02/14/17 10:25
92329884007 3902-MW6 Water 02/13/17 10:50 02/14/17 10:25
92329884008 3902-SW1 Water 02/13/17 11:11 02/14/17 10:25
92329884009 3902-SW2 Water 02/13/17 12:40 02/14/17 10:25
92329884010 3902-NES-1 Water 02/13/17 14:15 02/14/17 10:25
92329884011 3902-TRIP BLANK Water 02/13/17 07:00 02/14/17 10:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 77
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92329884001 3902-MW1R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 15 PASI-AJMW, SH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 66 PASI-CZDO
SM 4500-S2D 1 PASI-AAES2
SM 4500-CN-E 1 PASI-AAES2
92329884002 3902-MW2R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 15 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 66 PASI-CZDO
SM 4500-S2D 1 PASI-AAES2
SM 4500-CN-E 1 PASI-AAES2
92329884003 3902-MW3R EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 15 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 66 PASI-CZDO
SM 4500-S2D 1 PASI-AAES2
SM 4500-CN-E 1 PASI-AAES2
92329884004 3902-FIELD BLANK EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 15 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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Page 4 of 77
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
EPA 8260 66 PASI-CZDO
SM 4500-S2D 1 PASI-AAES2
SM 4500-CN-E 1 PASI-AAES2
92329884005 3902-MW4 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CZDO
92329884006 3902-MW5 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CZDO
92329884007 3902-MW6 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CZDO
92329884008 3902-SW1 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CZDO
92329884009 3902-SW2 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CZDO
92329884010 3902-NES-1 EPA 8260 4 PASI-CZDO
92329884011 3902-TRIP BLANK EPA 8260 66 PASI-CZDO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
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[phone]
Page 5 of 77
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92329884001 3902-MW1R
Barium 7.8J ug/L 02/18/17 03:48100EPA 6010
Vanadium 4.4J ug/L 02/18/17 03:4825.0EPA 6010
Zinc 12.3 ug/L 02/18/17 03:4810.0EPA 6010
Thallium 0.023J ug/L 02/16/17 14:435.5EPA 6020B
Chloromethane 0.20J ug/L 02/15/17 12:501.0EPA 8260
92329884002 3902-MW2R
Barium 112 ug/L 02/18/17 04:01100EPA 6010
Chromium 2.6J ug/L 02/18/17 04:0110.0EPA 6010
Cobalt 8.3J ug/L 02/18/17 04:0110.0EPA 6010
Nickel 89.6 ug/L 02/18/17 04:0150.0EPA 6010
Tin 25.5J ug/L 02/18/17 04:01 B100EPA 6010
Vanadium 4.1J ug/L 02/18/17 04:0125.0EPA 6010
Thallium 0.040J ug/L 02/16/17 14:495.5EPA 6020B
Benzene 1.2 ug/L 02/15/17 13:081.0EPA 8260
Chlorobenzene 13.6 ug/L 02/15/17 13:083.0EPA 8260
Chloroethane 0.76J ug/L 02/15/17 13:0810.0EPA 8260
1,2-Dichlorobenzene 1.2J ug/L 02/15/17 13:085.0EPA 8260
1,4-Dichlorobenzene 1.9 ug/L 02/15/17 13:081.0EPA 8260
Naphthalene 6.1J ug/L 02/15/17 13:0810.0EPA 8260
92329884003 3902-MW3R
Barium 68.3J ug/L 02/18/17 04:04100EPA 6010
Copper 6.8J ug/L 02/18/17 04:0410.0EPA 6010
Nickel 30.4J ug/L 02/18/17 04:0450.0EPA 6010
Tin 7.8J ug/L 02/18/17 04:04 B100EPA 6010
Benzene 0.61J ug/L 02/15/17 14:351.0EPA 8260
Chlorobenzene 18.0 ug/L 02/15/17 14:353.0EPA 8260
Chloroethane 1.6J ug/L 02/15/17 14:3510.0EPA 8260
Chloromethane 0.22J ug/L 02/15/17 14:351.0EPA 8260
1,2-Dichlorobenzene 1.4J ug/L 02/15/17 14:355.0EPA 8260
1,4-Dichlorobenzene 0.90J ug/L 02/15/17 14:351.0EPA 8260
92329884004 3902-FIELD BLANK
Tin 3.6J ug/L 02/18/17 04:07 B100EPA 6010
Chloromethane 0.18J ug/L 02/15/17 11:581.0EPA 8260
92329884005 3902-MW4
Copper 4.3J ug/L 02/18/17 04:1010.0EPA 6010
Nickel 13.5J ug/L 02/18/17 04:1050.0EPA 6010
Vanadium 18.4J ug/L 02/18/17 04:1025.0EPA 6010
Chlorobenzene 1.3J ug/L 02/15/17 14:533.0EPA 8260
Chloroethane 1.1J ug/L 02/15/17 14:5310.0EPA 8260
Chloromethane 0.23J ug/L 02/15/17 14:531.0EPA 8260
1,1-Dichloroethane 0.33J ug/L 02/15/17 14:535.0EPA 8260
92329884006 3902-MW5
Barium 151 ug/L 02/18/17 04:13100EPA 6010
Beryllium 0.57J ug/L 02/18/17 04:131.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 6 of 77
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92329884006 3902-MW5
Cobalt 78.7 ug/L 02/18/17 04:1310.0EPA 6010
Copper 14.5 ug/L 02/18/17 04:1310.0EPA 6010
Nickel 16.2J ug/L 02/18/17 04:1350.0EPA 6010
Vanadium 3.0J ug/L 02/18/17 04:1325.0EPA 6010
Zinc 9.8J ug/L 02/18/17 04:1310.0EPA 6010
Thallium 0.035J ug/L 02/16/17 14:575.5EPA 6020B
Chloromethane 0.19J ug/L 02/15/17 15:101.0EPA 8260
92329884007 3902-MW6
Barium 5.6J ug/L 02/18/17 04:16100EPA 6010
Copper 9.4J ug/L 02/18/17 04:1610.0EPA 6010
Vanadium 2.9J ug/L 02/18/17 04:1625.0EPA 6010
Zinc 6.0J ug/L 02/18/17 04:1610.0EPA 6010
Chloromethane 0.32J ug/L 02/15/17 15:271.0EPA 8260
92329884008 3902-SW1
Barium 45.3J ug/L 02/18/17 04:20100EPA 6010
Chloromethane 0.17J ug/L 02/15/17 15:451.0EPA 8260
92329884009 3902-SW2
Barium 60.4J ug/L 02/18/17 04:23100EPA 6010
Nickel 7.3J ug/L 02/18/17 04:2350.0EPA 6010
Zinc 5.2J ug/L 02/18/17 04:2310.0EPA 6010
Chloromethane 0.19J ug/L 02/15/17 16:021.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 7 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/18/17 17:12 309-00-202/15/17 12:130.050 0.050 1
alpha-BHC ND ug/L 02/18/17 17:12 319-84-602/15/17 12:130.050 0.050 1
beta-BHC ND ug/L 02/18/17 17:12 319-85-702/15/17 12:130.050 0.050 1
delta-BHC ND ug/L 02/18/17 17:12 319-86-802/15/17 12:130.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/18/17 17:12 58-89-902/15/17 12:130.050 0.050 1
Chlordane (Technical)ND ug/L 02/18/17 17:12 57-74-902/15/17 12:130.50 0.20 1
4,4'-DDD ND ug/L 02/18/17 17:12 72-54-802/15/17 12:130.10 0.050 1
4,4'-DDE ND ug/L 02/18/17 17:12 72-55-902/15/17 12:130.10 0.050 1
4,4'-DDT ND ug/L 02/18/17 17:12 50-29-302/15/17 12:130.10 0.050 1
Dieldrin ND ug/L 02/18/17 17:12 60-57-102/15/17 12:130.075 0.050 1
Endosulfan I ND ug/L 02/18/17 17:12 959-98-802/15/17 12:130.10 0.050 1
Endosulfan II ND ug/L 02/18/17 17:12 33213-65-902/15/17 12:130.10 0.050 1
Endosulfan sulfate ND ug/L 02/18/17 17:12 1031-07-802/15/17 12:130.10 0.050 1
Endrin ND ug/L 02/18/17 17:12 72-20-802/15/17 12:130.10 0.050 1
Endrin aldehyde ND ug/L 02/18/17 17:12 7421-93-402/15/17 12:130.10 0.050 1
Heptachlor ND ug/L 02/18/17 17:12 76-44-802/15/17 12:130.050 0.050 1
Heptachlor epoxide ND ug/L 02/18/17 17:12 1024-57-302/15/17 12:130.075 0.050 1
Methoxychlor ND ug/L 02/18/17 17:12 72-43-502/15/17 12:131.0 0.15 1
Toxaphene ND ug/L 02/18/17 17:12 8001-35-202/15/17 12:131.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)93 %02/18/17 17:12 877-09-802/15/17 12:1320-130 1
Decachlorobiphenyl (S)59 %02/18/17 17:12 2051-24-302/15/17 12:1320-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/17/17 21:10 12674-11-202/16/17 10:580.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/17/17 21:10 11104-28-202/16/17 10:580.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/17/17 21:10 11141-16-502/16/17 10:580.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/17/17 21:10 53469-21-902/16/17 10:580.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/17/17 21:10 12672-29-602/16/17 10:580.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/17/17 21:10 11097-69-102/16/17 10:580.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/17/17 21:10 11096-82-502/16/17 10:580.50 0.50 1
Surrogates
Decachlorobiphenyl (S)20 %02/17/17 21:10 2051-24-302/16/17 10:5810-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/21/17 04:44 94-75-7 L1,L302/17/17 16:150.94 0.22 1
Dinoseb ND ug/L 02/21/17 04:44 88-85-7 L1,L302/17/17 16:150.19 0.057 1
2,4,5-T ND ug/L 02/21/17 04:44 93-76-502/17/17 16:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 02/21/17 04:44 93-72-102/17/17 16:150.19 0.049 1
Surrogates
2,4-DCAA (S)81 %02/21/17 04:44 19719-28-902/17/17 16:1539-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 03:48 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 03:48 7440-38-202/15/17 22:4510.0 5.0 1
Barium 7.8J ug/L 02/18/17 03:48 7440-39-302/15/17 22:451002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 8 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/18/17 03:48 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 03:48 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 03:48 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 03:48 7440-48-402/15/17 22:4510.0 2.5 1
Copper ND ug/L 02/18/17 03:48 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/20/17 14:05 7439-92-102/15/17 22:4510.0 2.5 1
Nickel ND ug/L 02/18/17 03:48 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 03:48 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 03:48 7440-22-402/15/17 22:4510.0 2.5 1
Tin ND ug/L 02/18/17 03:48 7440-31-502/15/17 22:451002.5 1
Vanadium 4.4J ug/L 02/18/17 03:48 7440-62-202/15/17 22:4525.0 2.5 1
Zinc 12.3 ug/L 02/18/17 03:48 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.023J ug/L 02/16/17 14:43 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/21/17 12:53 7439-97-602/21/17 06:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 14:55 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 14:55 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 14:55 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 14:55 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 14:55 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 14:55 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 14:55 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 14:55 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 14:55 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 14:55 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 14:55 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 14:55 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 14:55 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 14:55 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 14:55 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 14:55 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 14:55 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 14:55 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 14:55 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 14:55 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 14:55 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 14:55 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 14:55 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 14:55 2303-16-402/17/17 11:0710.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/20/17 14:55 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 14:55 132-64-902/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 9 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 02/20/17 14:55 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 14:55 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 14:55 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 14:55 84-66-202/17/17 11:0760001.3 1
Dimethoate ND ug/L 02/20/17 14:55 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 14:55 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 14:55 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 14:55 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 14:55 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 14:55 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 14:55 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 14:55 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 14:55 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 14:55 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 14:55 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 14:55 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 14:55 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 14:55 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 14:55 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 14:55 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 14:55 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 14:55 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 14:55 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 14:55 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 14:55 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 14:55 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 14:55 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 14:55 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 14:55 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 14:55 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 14:55 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 14:55 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 14:55 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 14:55 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 14:55 91-80-502/17/17 11:071002.7 1
3-Methylcholanthrene ND ug/L 02/20/17 14:55 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 14:55 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 14:55 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 14:55 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 14:55 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 14:5502/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 14:55 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 14:55 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 14:55 130-15-402/17/17 11:0710.0 1.8 1
2-Nitroaniline ND ug/L 02/20/17 14:55 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 14:55 99-09-202/17/17 11:0750.0 2.4 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 02/20/17 14:55 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 14:55 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 14:55 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 14:55 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 14:55 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 14:55 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 14:55 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 14:55 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 14:55 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 14:55 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 14:55 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 14:55 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 14:55 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 14:55 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 14:55 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 14:55 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 14:55 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 14:55 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 14:55 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 14:55 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 14:55 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 14:5502/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 14:55 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 14:55 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 14:55 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 14:55 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 14:55 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 14:55 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 14:55 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 14:55 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 14:55 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 14:55 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 14:55 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 14:55 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)82 %02/20/17 14:55 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)78 %02/20/17 14:55 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)90 %02/20/17 14:55 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)25 %02/20/17 14:55 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)38 %02/20/17 14:55 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)74 %02/20/17 14:55 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 12:50 67-64-110010.0 1
Acetonitrile ND ug/L 02/15/17 12:50 75-05-855.0 2.2 1
Acrolein ND ug/L 02/15/17 12:50 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 11 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/15/17 12:50 107-13-12001.9 1
Allyl chloride ND ug/L 02/15/17 12:50 107-05-110.0 1.5 1
Benzene ND ug/L 02/15/17 12:50 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 12:50 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 12:50 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 12:50 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 12:50 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 12:50 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 12:50 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 12:50 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 12:50 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 12:50 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 12:50 67-66-35.0 0.14 1
Chloromethane 0.20J ug/L 02/15/17 12:50 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/15/17 12:50 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 12:50 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 12:50 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 12:50 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 12:50 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 12:50 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/15/17 12:50 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/15/17 12:50 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 12:50 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 02/15/17 12:50 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/15/17 12:50 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 12:50 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 12:50 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 12:50 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 12:50 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 12:50 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/15/17 12:50 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/15/17 12:50 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/15/17 12:50 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 12:50 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 12:50 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 12:50 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/15/17 12:50 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/15/17 12:50 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 12:50 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/15/17 12:50 78-83-110035.0 1
Methacrylonitrile ND ug/L 02/15/17 12:50 126-98-71000.93 1
Methylene Chloride ND ug/L 02/15/17 12:50 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/15/17 12:50 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 12:50 108-10-11000.33 1
Naphthalene ND ug/L 02/15/17 12:50 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/15/17 12:50 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 12 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW1R Lab ID:92329884001 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/15/17 12:50 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 12:50 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 12:50 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 12:50 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 12:50 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 12:50 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/15/17 12:50 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 12:50 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 12:50 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 12:50 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 12:50 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 12:50 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 12:50 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 12:50 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/15/17 12:50 460-00-470-130 1
1,2-Dichloroethane-d4 (S)92 %02/15/17 12:50 17060-07-070-130 1
Toluene-d8 (S)106 %02/15/17 12:50 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/16/17 17:10 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/18/17 18:29 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Huntersville, NC 28078
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Page 13 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/18/17 17:30 309-00-202/15/17 12:130.050 0.050 1
alpha-BHC ND ug/L 02/18/17 17:30 319-84-602/15/17 12:130.050 0.050 1
beta-BHC ND ug/L 02/18/17 17:30 319-85-702/15/17 12:130.050 0.050 1
delta-BHC ND ug/L 02/18/17 17:30 319-86-802/15/17 12:130.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/18/17 17:30 58-89-902/15/17 12:130.050 0.050 1
Chlordane (Technical)ND ug/L 02/18/17 17:30 57-74-902/15/17 12:130.50 0.20 1
4,4'-DDD ND ug/L 02/18/17 17:30 72-54-802/15/17 12:130.10 0.050 1
4,4'-DDE ND ug/L 02/18/17 17:30 72-55-902/15/17 12:130.10 0.050 1
4,4'-DDT ND ug/L 02/18/17 17:30 50-29-302/15/17 12:130.10 0.050 1
Dieldrin ND ug/L 02/18/17 17:30 60-57-102/15/17 12:130.075 0.050 1
Endosulfan I ND ug/L 02/18/17 17:30 959-98-802/15/17 12:130.10 0.050 1
Endosulfan II ND ug/L 02/18/17 17:30 33213-65-902/15/17 12:130.10 0.050 1
Endosulfan sulfate ND ug/L 02/18/17 17:30 1031-07-802/15/17 12:130.10 0.050 1
Endrin ND ug/L 02/18/17 17:30 72-20-802/15/17 12:130.10 0.050 1
Endrin aldehyde ND ug/L 02/18/17 17:30 7421-93-402/15/17 12:130.10 0.050 1
Heptachlor ND ug/L 02/18/17 17:30 76-44-802/15/17 12:130.050 0.050 1
Heptachlor epoxide ND ug/L 02/18/17 17:30 1024-57-302/15/17 12:130.075 0.050 1
Methoxychlor ND ug/L 02/18/17 17:30 72-43-502/15/17 12:131.0 0.15 1
Toxaphene ND ug/L 02/18/17 17:30 8001-35-202/15/17 12:131.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)64 %02/18/17 17:30 877-09-802/15/17 12:1320-130 1
Decachlorobiphenyl (S)73 %02/18/17 17:30 2051-24-302/15/17 12:1320-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/17/17 21:30 12674-11-202/16/17 10:580.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/17/17 21:30 11104-28-202/16/17 10:580.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/17/17 21:30 11141-16-502/16/17 10:580.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/17/17 21:30 53469-21-902/16/17 10:580.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/17/17 21:30 12672-29-602/16/17 10:580.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/17/17 21:30 11097-69-102/16/17 10:580.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/17/17 21:30 11096-82-502/16/17 10:580.50 0.50 1
Surrogates
Decachlorobiphenyl (S)123 %02/17/17 21:30 2051-24-302/16/17 10:5810-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/21/17 05:14 94-75-7 L1,L302/17/17 16:150.94 0.22 1
Dinoseb ND ug/L 02/21/17 05:14 88-85-7 L1,L302/17/17 16:150.19 0.057 1
2,4,5-T ND ug/L 02/21/17 05:14 93-76-502/17/17 16:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 02/21/17 05:14 93-72-102/17/17 16:150.19 0.049 1
Surrogates
2,4-DCAA (S)107 %02/21/17 05:14 19719-28-902/17/17 16:1539-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:01 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:01 7440-38-202/15/17 22:4510.0 5.0 1
Barium 112 ug/L 02/18/17 04:01 7440-39-302/15/17 22:451002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 14 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/18/17 04:01 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:01 7440-43-902/15/17 22:451.0 0.50 1
Chromium 2.6J ug/L 02/18/17 04:01 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt 8.3J ug/L 02/18/17 04:01 7440-48-402/15/17 22:4510.0 2.5 1
Copper ND ug/L 02/18/17 04:01 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:01 7439-92-102/15/17 22:4510.0 2.5 1
Nickel 89.6 ug/L 02/18/17 04:01 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:01 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:01 7440-22-402/15/17 22:4510.0 2.5 1
Tin 25.5J ug/L 02/18/17 04:01 7440-31-5 B02/15/17 22:451002.5 1
Vanadium 4.1J ug/L 02/18/17 04:01 7440-62-202/15/17 22:4525.0 2.5 1
Zinc ND ug/L 02/18/17 04:01 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.040J ug/L 02/16/17 14:49 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/21/17 13:00 7439-97-602/21/17 06:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 15:22 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 15:22 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 15:22 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 15:22 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 15:22 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 15:22 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 15:22 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 15:22 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 15:22 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 15:22 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 15:22 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 15:22 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 15:22 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 15:22 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 15:22 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 15:22 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 15:22 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 15:22 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 15:22 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 15:22 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 15:22 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 15:22 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 15:22 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 15:22 2303-16-402/17/17 11:0710.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/20/17 15:22 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 15:22 132-64-902/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 15 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 02/20/17 15:22 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 15:22 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 15:22 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 15:22 84-66-202/17/17 11:0760001.3 1
Dimethoate ND ug/L 02/20/17 15:22 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 15:22 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 15:22 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 15:22 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 15:22 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 15:22 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 15:22 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 15:22 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 15:22 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 15:22 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 15:22 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 15:22 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 15:22 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 15:22 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 15:22 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 15:22 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 15:22 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 15:22 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 15:22 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 15:22 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 15:22 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 15:22 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 15:22 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 15:22 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 15:22 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 15:22 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 15:22 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 15:22 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 15:22 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 15:22 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 15:22 91-80-502/17/17 11:071002.7 1
3-Methylcholanthrene ND ug/L 02/20/17 15:22 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 15:22 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 15:22 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 15:22 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 15:22 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 15:2202/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 15:22 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 15:22 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 15:22 130-15-402/17/17 11:0710.0 1.8 1
2-Nitroaniline ND ug/L 02/20/17 15:22 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 15:22 99-09-202/17/17 11:0750.0 2.4 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 16 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 02/20/17 15:22 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 15:22 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 15:22 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 15:22 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 15:22 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 15:22 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 15:22 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 15:22 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 15:22 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 15:22 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 15:22 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 15:22 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 15:22 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 15:22 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 15:22 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 15:22 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 15:22 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 15:22 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 15:22 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 15:22 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 15:22 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 15:2202/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 15:22 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 15:22 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 15:22 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 15:22 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 15:22 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 15:22 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 15:22 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 15:22 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 15:22 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 15:22 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 15:22 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 15:22 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)81 %02/20/17 15:22 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)74 %02/20/17 15:22 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)82 %02/20/17 15:22 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)26 %02/20/17 15:22 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)37 %02/20/17 15:22 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)92 %02/20/17 15:22 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 13:08 67-64-110010.0 1
Acetonitrile ND ug/L 02/15/17 13:08 75-05-855.0 2.2 1
Acrolein ND ug/L 02/15/17 13:08 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Page 17 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/15/17 13:08 107-13-12001.9 1
Allyl chloride ND ug/L 02/15/17 13:08 107-05-110.0 1.5 1
Benzene 1.2 ug/L 02/15/17 13:08 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 13:08 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 13:08 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 13:08 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 13:08 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 13:08 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 13:08 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 13:08 56-23-51.0 0.25 1
Chlorobenzene 13.6 ug/L 02/15/17 13:08 108-90-73.0 0.23 1
Chloroethane 0.76J ug/L 02/15/17 13:08 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 13:08 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/15/17 13:08 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/15/17 13:08 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 13:08 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 13:08 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 13:08 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 13:08 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.2J ug/L 02/15/17 13:08 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/15/17 13:08 541-73-15.0 0.24 1
1,4-Dichlorobenzene 1.9 ug/L 02/15/17 13:08 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 13:08 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 02/15/17 13:08 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/15/17 13:08 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 13:08 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 13:08 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 13:08 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 13:08 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 13:08 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/15/17 13:08 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/15/17 13:08 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/15/17 13:08 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 13:08 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 13:08 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 13:08 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/15/17 13:08 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/15/17 13:08 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 13:08 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/15/17 13:08 78-83-110035.0 1
Methacrylonitrile ND ug/L 02/15/17 13:08 126-98-71000.93 1
Methylene Chloride ND ug/L 02/15/17 13:08 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/15/17 13:08 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 13:08 108-10-11000.33 1
Naphthalene 6.1J ug/L 02/15/17 13:08 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/15/17 13:08 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 18 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW2R Lab ID:92329884002 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/15/17 13:08 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 13:08 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 13:08 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 13:08 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 13:08 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 13:08 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/15/17 13:08 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 13:08 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 13:08 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 13:08 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 13:08 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 13:08 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 13:08 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 13:08 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/15/17 13:08 460-00-470-130 1
1,2-Dichloroethane-d4 (S)96 %02/15/17 13:08 17060-07-070-130 1
Toluene-d8 (S)101 %02/15/17 13:08 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/16/17 17:10 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/18/17 18:30 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Page 19 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/18/17 17:48 309-00-202/15/17 12:130.050 0.050 1
alpha-BHC ND ug/L 02/18/17 17:48 319-84-602/15/17 12:130.050 0.050 1
beta-BHC ND ug/L 02/18/17 17:48 319-85-702/15/17 12:130.050 0.050 1
delta-BHC ND ug/L 02/18/17 17:48 319-86-802/15/17 12:130.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/18/17 17:48 58-89-902/15/17 12:130.050 0.050 1
Chlordane (Technical)ND ug/L 02/18/17 17:48 57-74-902/15/17 12:130.50 0.20 1
4,4'-DDD ND ug/L 02/18/17 17:48 72-54-802/15/17 12:130.10 0.050 1
4,4'-DDE ND ug/L 02/18/17 17:48 72-55-902/15/17 12:130.10 0.050 1
4,4'-DDT ND ug/L 02/18/17 17:48 50-29-302/15/17 12:130.10 0.050 1
Dieldrin ND ug/L 02/18/17 17:48 60-57-102/15/17 12:130.075 0.050 1
Endosulfan I ND ug/L 02/18/17 17:48 959-98-802/15/17 12:130.10 0.050 1
Endosulfan II ND ug/L 02/18/17 17:48 33213-65-902/15/17 12:130.10 0.050 1
Endosulfan sulfate ND ug/L 02/18/17 17:48 1031-07-802/15/17 12:130.10 0.050 1
Endrin ND ug/L 02/18/17 17:48 72-20-802/15/17 12:130.10 0.050 1
Endrin aldehyde ND ug/L 02/18/17 17:48 7421-93-402/15/17 12:130.10 0.050 1
Heptachlor ND ug/L 02/18/17 17:48 76-44-802/15/17 12:130.050 0.050 1
Heptachlor epoxide ND ug/L 02/18/17 17:48 1024-57-302/15/17 12:130.075 0.050 1
Methoxychlor ND ug/L 02/18/17 17:48 72-43-502/15/17 12:131.0 0.15 1
Toxaphene ND ug/L 02/18/17 17:48 8001-35-202/15/17 12:131.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)96 %02/18/17 17:48 877-09-802/15/17 12:1320-130 1
Decachlorobiphenyl (S)95 %02/18/17 17:48 2051-24-302/15/17 12:1320-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/17/17 21:50 12674-11-202/16/17 10:580.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/17/17 21:50 11104-28-202/16/17 10:580.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/17/17 21:50 11141-16-502/16/17 10:580.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/17/17 21:50 53469-21-902/16/17 10:580.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/17/17 21:50 12672-29-602/16/17 10:580.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/17/17 21:50 11097-69-102/16/17 10:580.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/17/17 21:50 11096-82-502/16/17 10:580.50 0.50 1
Surrogates
Decachlorobiphenyl (S)122 %02/17/17 21:50 2051-24-302/16/17 10:5810-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/21/17 05:44 94-75-7 L1,L302/17/17 16:150.94 0.22 1
Dinoseb ND ug/L 02/21/17 05:44 88-85-7 L1,L302/17/17 16:150.19 0.057 1
2,4,5-T ND ug/L 02/21/17 05:44 93-76-502/17/17 16:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 02/21/17 05:44 93-72-102/17/17 16:150.19 0.049 1
Surrogates
2,4-DCAA (S)103 %02/21/17 05:44 19719-28-902/17/17 16:1539-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:04 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:04 7440-38-202/15/17 22:4510.0 5.0 1
Barium 68.3J ug/L 02/18/17 04:04 7440-39-302/15/17 22:451002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/18/17 04:04 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:04 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:04 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:04 7440-48-402/15/17 22:4510.0 2.5 1
Copper 6.8J ug/L 02/18/17 04:04 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:04 7439-92-102/15/17 22:4510.0 2.5 1
Nickel 30.4J ug/L 02/18/17 04:04 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:04 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:04 7440-22-402/15/17 22:4510.0 2.5 1
Tin 7.8J ug/L 02/18/17 04:04 7440-31-5 B02/15/17 22:451002.5 1
Vanadium ND ug/L 02/18/17 04:04 7440-62-202/15/17 22:4525.0 2.5 1
Zinc ND ug/L 02/18/17 04:04 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 14:51 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/21/17 13:02 7439-97-602/21/17 06:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 15:50 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 15:50 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 15:50 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 15:50 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 15:50 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 15:50 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 15:50 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 15:50 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 15:50 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 15:50 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 15:50 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 15:50 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 15:50 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 15:50 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 15:50 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 15:50 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 15:50 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 15:50 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 15:50 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 15:50 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 15:50 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 15:50 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 15:50 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 15:50 2303-16-402/17/17 11:0710.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/20/17 15:50 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 15:50 132-64-902/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 02/20/17 15:50 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 15:50 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 15:50 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 15:50 84-66-202/17/17 11:0760001.3 1
Dimethoate ND ug/L 02/20/17 15:50 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 15:50 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 15:50 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 15:50 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 15:50 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 15:50 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 15:50 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 15:50 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 15:50 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 15:50 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 15:50 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 15:50 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 15:50 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 15:50 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 15:50 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 15:50 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 15:50 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 15:50 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 15:50 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 15:50 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 15:50 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 15:50 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 15:50 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 15:50 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 15:50 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 15:50 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 15:50 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 15:50 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 15:50 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 15:50 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 15:50 91-80-502/17/17 11:071002.7 1
3-Methylcholanthrene ND ug/L 02/20/17 15:50 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 15:50 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 15:50 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 15:50 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 15:50 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 15:5002/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 15:50 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 15:50 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 15:50 130-15-402/17/17 11:0710.0 1.8 1
2-Nitroaniline ND ug/L 02/20/17 15:50 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 15:50 99-09-202/17/17 11:0750.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 02/20/17 15:50 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 15:50 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 15:50 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 15:50 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 15:50 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 15:50 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 15:50 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 15:50 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 15:50 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 15:50 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 15:50 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 15:50 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 15:50 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 15:50 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 15:50 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 15:50 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 15:50 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 15:50 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 15:50 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 15:50 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 15:50 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 15:5002/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 15:50 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 15:50 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 15:50 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 15:50 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 15:50 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 15:50 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 15:50 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 15:50 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 15:50 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 15:50 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 15:50 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 15:50 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)60 %02/20/17 15:50 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)56 %02/20/17 15:50 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)75 %02/20/17 15:50 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)19 %02/20/17 15:50 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)29 %02/20/17 15:50 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)74 %02/20/17 15:50 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 14:35 67-64-110010.0 1
Acetonitrile ND ug/L 02/15/17 14:35 75-05-855.0 2.2 1
Acrolein ND ug/L 02/15/17 14:35 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/15/17 14:35 107-13-12001.9 1
Allyl chloride ND ug/L 02/15/17 14:35 107-05-110.0 1.5 1
Benzene 0.61J ug/L 02/15/17 14:35 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 14:35 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 14:35 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 14:35 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 14:35 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 14:35 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 14:35 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 14:35 56-23-51.0 0.25 1
Chlorobenzene 18.0 ug/L 02/15/17 14:35 108-90-73.0 0.23 1
Chloroethane 1.6J ug/L 02/15/17 14:35 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 14:35 67-66-35.0 0.14 1
Chloromethane 0.22J ug/L 02/15/17 14:35 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/15/17 14:35 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 14:35 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 14:35 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 14:35 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 14:35 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.4J ug/L 02/15/17 14:35 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/15/17 14:35 541-73-15.0 0.24 1
1,4-Dichlorobenzene 0.90J ug/L 02/15/17 14:35 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 14:35 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 02/15/17 14:35 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/15/17 14:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 14:35 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 14:35 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 14:35 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 14:35 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 14:35 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/15/17 14:35 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/15/17 14:35 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/15/17 14:35 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 14:35 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 14:35 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 14:35 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/15/17 14:35 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/15/17 14:35 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 14:35 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/15/17 14:35 78-83-110035.0 1
Methacrylonitrile ND ug/L 02/15/17 14:35 126-98-71000.93 1
Methylene Chloride ND ug/L 02/15/17 14:35 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/15/17 14:35 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 14:35 108-10-11000.33 1
Naphthalene ND ug/L 02/15/17 14:35 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/15/17 14:35 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW3R Lab ID:92329884003 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/15/17 14:35 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 14:35 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 14:35 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 14:35 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 14:35 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 14:35 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/15/17 14:35 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 14:35 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 14:35 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 14:35 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 14:35 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 14:35 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 14:35 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 14:35 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %02/15/17 14:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %02/15/17 14:35 17060-07-070-130 1
Toluene-d8 (S)103 %02/15/17 14:35 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/16/17 17:10 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/18/17 18:31 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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[phone]
Page 25 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/18/17 18:24 309-00-202/15/17 12:130.050 0.050 1
alpha-BHC ND ug/L 02/18/17 18:24 319-84-602/15/17 12:130.050 0.050 1
beta-BHC ND ug/L 02/18/17 18:24 319-85-702/15/17 12:130.050 0.050 1
delta-BHC ND ug/L 02/18/17 18:24 319-86-802/15/17 12:130.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/18/17 18:24 58-89-902/15/17 12:130.050 0.050 1
Chlordane (Technical)ND ug/L 02/18/17 18:24 57-74-902/15/17 12:130.50 0.20 1
4,4'-DDD ND ug/L 02/18/17 18:24 72-54-802/15/17 12:130.10 0.050 1
4,4'-DDE ND ug/L 02/18/17 18:24 72-55-902/15/17 12:130.10 0.050 1
4,4'-DDT ND ug/L 02/18/17 18:24 50-29-302/15/17 12:130.10 0.050 1
Dieldrin ND ug/L 02/18/17 18:24 60-57-102/15/17 12:130.075 0.050 1
Endosulfan I ND ug/L 02/18/17 18:24 959-98-802/15/17 12:130.10 0.050 1
Endosulfan II ND ug/L 02/18/17 18:24 33213-65-902/15/17 12:130.10 0.050 1
Endosulfan sulfate ND ug/L 02/18/17 18:24 1031-07-802/15/17 12:130.10 0.050 1
Endrin ND ug/L 02/18/17 18:24 72-20-802/15/17 12:130.10 0.050 1
Endrin aldehyde ND ug/L 02/18/17 18:24 7421-93-402/15/17 12:130.10 0.050 1
Heptachlor ND ug/L 02/18/17 18:24 76-44-802/15/17 12:130.050 0.050 1
Heptachlor epoxide ND ug/L 02/18/17 18:24 1024-57-302/15/17 12:130.075 0.050 1
Methoxychlor ND ug/L 02/18/17 18:24 72-43-502/15/17 12:131.0 0.15 1
Toxaphene ND ug/L 02/18/17 18:24 8001-35-202/15/17 12:131.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)91 %02/18/17 18:24 877-09-802/15/17 12:1320-130 1
Decachlorobiphenyl (S)65 %02/18/17 18:24 2051-24-302/15/17 12:1320-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/17/17 23:30 12674-11-202/16/17 10:580.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/17/17 23:30 11104-28-202/16/17 10:580.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/17/17 23:30 11141-16-502/16/17 10:580.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/17/17 23:30 53469-21-902/16/17 10:580.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/17/17 23:30 12672-29-602/16/17 10:580.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/17/17 23:30 11097-69-102/16/17 10:580.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/17/17 23:30 11096-82-502/16/17 10:580.50 0.50 1
Surrogates
Decachlorobiphenyl (S)100 %02/17/17 23:30 2051-24-302/16/17 10:5810-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/21/17 06:14 94-75-7 L1,L302/17/17 16:150.94 0.22 1
Dinoseb ND ug/L 02/21/17 06:14 88-85-7 L1,L302/17/17 16:150.19 0.057 1
2,4,5-T ND ug/L 02/21/17 06:14 93-76-502/17/17 16:150.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 02/21/17 06:14 93-72-102/17/17 16:150.19 0.049 1
Surrogates
2,4-DCAA (S)90 %02/21/17 06:14 19719-28-902/17/17 16:1539-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:07 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:07 7440-38-202/15/17 22:4510.0 5.0 1
Barium ND ug/L 02/18/17 04:07 7440-39-302/15/17 22:451002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/18/17 04:07 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:07 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:07 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:07 7440-48-402/15/17 22:4510.0 2.5 1
Copper ND ug/L 02/18/17 04:07 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:07 7439-92-102/15/17 22:4510.0 2.5 1
Nickel ND ug/L 02/18/17 04:07 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:07 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:07 7440-22-402/15/17 22:4510.0 2.5 1
Tin 3.6J ug/L 02/18/17 04:07 7440-31-5 B02/15/17 22:451002.5 1
Vanadium ND ug/L 02/18/17 04:07 7440-62-202/15/17 22:4525.0 2.5 1
Zinc ND ug/L 02/18/17 04:07 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 14:53 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/21/17 13:04 7439-97-602/21/17 06:150.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 16:18 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 16:18 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 16:18 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 16:18 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 16:18 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 16:18 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 16:18 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 16:18 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 16:18 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 16:18 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 16:18 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 16:18 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 16:18 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 16:18 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 16:18 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 16:18 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 16:18 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 16:18 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 16:18 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 16:18 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 16:18 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 16:18 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 16:18 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 16:18 2303-16-402/17/17 11:0710.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 02/20/17 16:18 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 16:18 132-64-902/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 02/20/17 16:18 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 16:18 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 16:18 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 16:18 84-66-202/17/17 11:0760001.3 1
Dimethoate ND ug/L 02/20/17 16:18 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 16:18 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 16:18 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 16:18 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 16:18 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 16:18 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 16:18 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 16:18 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 16:18 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 16:18 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 16:18 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 16:18 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 16:18 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 16:18 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 16:18 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 16:18 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 16:18 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 16:18 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 16:18 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 16:18 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 16:18 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 16:18 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 16:18 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 16:18 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 16:18 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 16:18 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 16:18 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 16:18 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 16:18 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 16:18 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 16:18 91-80-502/17/17 11:071002.7 1
3-Methylcholanthrene ND ug/L 02/20/17 16:18 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 16:18 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 16:18 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 16:18 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 16:18 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 16:1802/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 16:18 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 16:18 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 16:18 130-15-402/17/17 11:0710.0 1.8 1
2-Nitroaniline ND ug/L 02/20/17 16:18 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 16:18 99-09-202/17/17 11:0750.0 2.4 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
4-Nitroaniline ND ug/L 02/20/17 16:18 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 16:18 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 16:18 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 16:18 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 16:18 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 16:18 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 16:18 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 16:18 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 16:18 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 16:18 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 16:18 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 16:18 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 16:18 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 16:18 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 16:18 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 16:18 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 16:18 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 16:18 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 16:18 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 16:18 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 16:18 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 16:1802/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 16:18 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 16:18 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 16:18 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 16:18 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 16:18 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 16:18 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 16:18 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 16:18 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 16:18 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 16:18 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 16:18 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 16:18 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)87 %02/20/17 16:18 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)81 %02/20/17 16:18 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)100 %02/20/17 16:18 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)26 %02/20/17 16:18 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)38 %02/20/17 16:18 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)77 %02/20/17 16:18 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 11:58 67-64-110010.0 1
Acetonitrile ND ug/L 02/15/17 11:58 75-05-855.0 2.2 1
Acrolein ND ug/L 02/15/17 11:58 107-02-853.0 1.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Page 29 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acrylonitrile ND ug/L 02/15/17 11:58 107-13-12001.9 1
Allyl chloride ND ug/L 02/15/17 11:58 107-05-110.0 1.5 1
Benzene ND ug/L 02/15/17 11:58 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 11:58 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 11:58 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 11:58 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 11:58 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 11:58 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 11:58 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 11:58 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 11:58 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 11:58 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 11:58 67-66-35.0 0.14 1
Chloromethane 0.18J ug/L 02/15/17 11:58 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/15/17 11:58 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 11:58 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 11:58 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 11:58 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 11:58 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 11:58 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/15/17 11:58 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/15/17 11:58 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 11:58 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 02/15/17 11:58 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/15/17 11:58 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 11:58 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 11:58 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 11:58 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 11:58 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 11:58 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/15/17 11:58 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/15/17 11:58 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/15/17 11:58 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 11:58 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 11:58 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 11:58 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/15/17 11:58 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/15/17 11:58 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 11:58 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/15/17 11:58 78-83-110035.0 1
Methacrylonitrile ND ug/L 02/15/17 11:58 126-98-71000.93 1
Methylene Chloride ND ug/L 02/15/17 11:58 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/15/17 11:58 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 11:58 108-10-11000.33 1
Naphthalene ND ug/L 02/15/17 11:58 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/15/17 11:58 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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Page 30 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-FIELD BLANK Lab ID:92329884004 Collected:02/13/17 14:30 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 02/15/17 11:58 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 11:58 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 11:58 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 11:58 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 11:58 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 11:58 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/15/17 11:58 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 11:58 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 11:58 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 11:58 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 11:58 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 11:58 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 11:58 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 11:58 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/15/17 11:58 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %02/15/17 11:58 17060-07-070-130 1
Toluene-d8 (S)105 %02/15/17 11:58 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/16/17 17:10 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/18/17 18:32 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 31 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW4 Lab ID:92329884005 Collected:02/13/17 11:27 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:10 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:10 7440-38-202/15/17 22:4510.0 5.0 1
Barium ND ug/L 02/18/17 04:10 7440-39-302/15/17 22:451002.5 1
Beryllium ND ug/L 02/18/17 04:10 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:10 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:10 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:10 7440-48-402/15/17 22:4510.0 2.5 1
Copper 4.3J ug/L 02/18/17 04:10 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:10 7439-92-102/15/17 22:4510.0 2.5 1
Nickel 13.5J ug/L 02/18/17 04:10 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:10 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:10 7440-22-402/15/17 22:4510.0 2.5 1
Vanadium 18.4J ug/L 02/18/17 04:10 7440-62-202/15/17 22:4525.0 2.5 1
Zinc ND ug/L 02/18/17 04:10 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 14:55 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 14:53 67-64-110010.0 1
Acrylonitrile ND ug/L 02/15/17 14:53 107-13-12001.9 1
Benzene ND ug/L 02/15/17 14:53 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 14:53 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 14:53 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 14:53 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 14:53 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 14:53 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 14:53 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 14:53 56-23-51.0 0.25 1
Chlorobenzene 1.3J ug/L 02/15/17 14:53 108-90-73.0 0.23 1
Chloroethane 1.1J ug/L 02/15/17 14:53 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 14:53 67-66-35.0 0.14 1
Chloromethane 0.23J ug/L 02/15/17 14:53 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 14:53 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 14:53 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 14:53 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 14:53 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 14:53 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/15/17 14:53 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 14:53 110-57-61001.0 1
1,1-Dichloroethane 0.33J ug/L 02/15/17 14:53 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 14:53 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 14:53 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 14:53 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 14:53 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 14:53 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW4 Lab ID:92329884005 Collected:02/13/17 11:27 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/15/17 14:53 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 14:53 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 14:53 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/15/17 14:53 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 14:53 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/15/17 14:53 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 14:53 108-10-11000.33 1
Styrene ND ug/L 02/15/17 14:53 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 14:53 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 14:53 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 14:53 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 14:53 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/15/17 14:53 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 14:53 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 14:53 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 14:53 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 14:53 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 14:53 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 14:53 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 14:53 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %02/15/17 14:53 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %02/15/17 14:53 17060-07-070-130 1
Toluene-d8 (S)102 %02/15/17 14:53 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 33 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW5 Lab ID:92329884006 Collected:02/13/17 11:18 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:13 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:13 7440-38-202/15/17 22:4510.0 5.0 1
Barium 151 ug/L 02/18/17 04:13 7440-39-302/15/17 22:451002.5 1
Beryllium 0.57J ug/L 02/18/17 04:13 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:13 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:13 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt 78.7 ug/L 02/18/17 04:13 7440-48-402/15/17 22:4510.0 2.5 1
Copper 14.5 ug/L 02/18/17 04:13 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:13 7439-92-102/15/17 22:4510.0 2.5 1
Nickel 16.2J ug/L 02/18/17 04:13 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:13 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:13 7440-22-402/15/17 22:4510.0 2.5 1
Vanadium 3.0J ug/L 02/18/17 04:13 7440-62-202/15/17 22:4525.0 2.5 1
Zinc 9.8J ug/L 02/18/17 04:13 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium 0.035J ug/L 02/16/17 14:57 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 15:10 67-64-110010.0 1
Acrylonitrile ND ug/L 02/15/17 15:10 107-13-12001.9 1
Benzene ND ug/L 02/15/17 15:10 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 15:10 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 15:10 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 15:10 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 15:10 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 15:10 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 15:10 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 15:10 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 15:10 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 15:10 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 15:10 67-66-35.0 0.14 1
Chloromethane 0.19J ug/L 02/15/17 15:10 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 15:10 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 15:10 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 15:10 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 15:10 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 15:10 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/15/17 15:10 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 15:10 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 02/15/17 15:10 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 15:10 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 15:10 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 15:10 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 15:10 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 15:10 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW5 Lab ID:92329884006 Collected:02/13/17 11:18 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/15/17 15:10 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 15:10 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 15:10 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/15/17 15:10 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 15:10 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/15/17 15:10 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 15:10 108-10-11000.33 1
Styrene ND ug/L 02/15/17 15:10 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 15:10 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 15:10 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 15:10 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 15:10 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/15/17 15:10 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 15:10 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 15:10 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 15:10 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 15:10 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 15:10 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 15:10 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 15:10 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %02/15/17 15:10 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/15/17 15:10 17060-07-070-130 1
Toluene-d8 (S)102 %02/15/17 15:10 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW6 Lab ID:92329884007 Collected:02/13/17 10:50 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:16 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:16 7440-38-202/15/17 22:4510.0 5.0 1
Barium 5.6J ug/L 02/18/17 04:16 7440-39-302/15/17 22:451002.5 1
Beryllium ND ug/L 02/18/17 04:16 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:16 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:16 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:16 7440-48-402/15/17 22:4510.0 2.5 1
Copper 9.4J ug/L 02/18/17 04:16 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:16 7439-92-102/15/17 22:4510.0 2.5 1
Nickel ND ug/L 02/18/17 04:16 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:16 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:16 7440-22-402/15/17 22:4510.0 2.5 1
Vanadium 2.9J ug/L 02/18/17 04:16 7440-62-202/15/17 22:4525.0 2.5 1
Zinc 6.0J ug/L 02/18/17 04:16 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 15:04 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 15:27 67-64-110010.0 1
Acrylonitrile ND ug/L 02/15/17 15:27 107-13-12001.9 1
Benzene ND ug/L 02/15/17 15:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 15:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 15:27 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 15:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 15:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 15:27 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 15:27 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 15:27 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 15:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 15:27 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 15:27 67-66-35.0 0.14 1
Chloromethane 0.32J ug/L 02/15/17 15:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 15:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 15:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 15:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 15:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 15:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/15/17 15:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 15:27 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 02/15/17 15:27 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 15:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 15:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 15:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 15:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 15:27 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 36 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-MW6 Lab ID:92329884007 Collected:02/13/17 10:50 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/15/17 15:27 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 15:27 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 15:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/15/17 15:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 15:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/15/17 15:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 15:27 108-10-11000.33 1
Styrene ND ug/L 02/15/17 15:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 15:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 15:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 15:27 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 15:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/15/17 15:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 15:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 15:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 15:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 15:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 15:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 15:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 15:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %02/15/17 15:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %02/15/17 15:27 17060-07-070-130 1
Toluene-d8 (S)101 %02/15/17 15:27 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-SW1 Lab ID:92329884008 Collected:02/13/17 11:11 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:20 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:20 7440-38-202/15/17 22:4510.0 5.0 1
Barium 45.3J ug/L 02/18/17 04:20 7440-39-302/15/17 22:451002.5 1
Beryllium ND ug/L 02/18/17 04:20 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:20 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:20 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:20 7440-48-402/15/17 22:4510.0 2.5 1
Copper ND ug/L 02/18/17 04:20 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:20 7439-92-102/15/17 22:4510.0 2.5 1
Nickel ND ug/L 02/18/17 04:20 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:20 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:20 7440-22-402/15/17 22:4510.0 2.5 1
Vanadium ND ug/L 02/18/17 04:20 7440-62-202/15/17 22:4525.0 2.5 1
Zinc ND ug/L 02/18/17 04:20 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 15:06 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 15:45 67-64-110010.0 1
Acrylonitrile ND ug/L 02/15/17 15:45 107-13-12001.9 1
Benzene ND ug/L 02/15/17 15:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 15:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 15:45 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 15:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 15:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 15:45 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 15:45 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 15:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 15:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 15:45 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 15:45 67-66-35.0 0.14 1
Chloromethane 0.17J ug/L 02/15/17 15:45 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 15:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 15:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 15:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 15:45 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 15:45 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/15/17 15:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 15:45 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 02/15/17 15:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 15:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 15:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 15:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 15:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 15:45 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-SW1 Lab ID:92329884008 Collected:02/13/17 11:11 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/15/17 15:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 15:45 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 15:45 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/15/17 15:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 15:45 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/15/17 15:45 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 15:45 108-10-11000.33 1
Styrene ND ug/L 02/15/17 15:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 15:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 15:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 15:45 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 15:45 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/15/17 15:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 15:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 15:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 15:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 15:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 15:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 15:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 15:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/15/17 15:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)95 %02/15/17 15:45 17060-07-070-130 1
Toluene-d8 (S)104 %02/15/17 15:45 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-SW2 Lab ID:92329884009 Collected:02/13/17 12:40 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/18/17 04:23 7440-36-002/15/17 22:456.0 3.9 1
Arsenic ND ug/L 02/18/17 04:23 7440-38-202/15/17 22:4510.0 5.0 1
Barium 60.4J ug/L 02/18/17 04:23 7440-39-302/15/17 22:451002.5 1
Beryllium ND ug/L 02/18/17 04:23 7440-41-702/15/17 22:451.0 0.50 1
Cadmium ND ug/L 02/18/17 04:23 7440-43-902/15/17 22:451.0 0.50 1
Chromium ND ug/L 02/18/17 04:23 7440-47-302/15/17 22:4510.0 2.5 1
Cobalt ND ug/L 02/18/17 04:23 7440-48-402/15/17 22:4510.0 2.5 1
Copper ND ug/L 02/18/17 04:23 7440-50-802/15/17 22:4510.0 2.5 1
Lead ND ug/L 02/18/17 04:23 7439-92-102/15/17 22:4510.0 2.5 1
Nickel 7.3J ug/L 02/18/17 04:23 7440-02-002/15/17 22:4550.0 2.5 1
Selenium ND ug/L 02/18/17 04:23 7782-49-202/15/17 22:4510.0 5.0 1
Silver ND ug/L 02/18/17 04:23 7440-22-402/15/17 22:4510.0 2.5 1
Vanadium ND ug/L 02/18/17 04:23 7440-62-202/15/17 22:4525.0 2.5 1
Zinc 5.2J ug/L 02/18/17 04:23 7440-66-602/15/17 22:4510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/16/17 15:08 7440-28-002/16/17 05:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 16:02 67-64-110010.0 1
Acrylonitrile ND ug/L 02/15/17 16:02 107-13-12001.9 1
Benzene ND ug/L 02/15/17 16:02 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 16:02 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 16:02 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 16:02 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 16:02 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 16:02 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 16:02 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 16:02 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 16:02 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 16:02 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 16:02 67-66-35.0 0.14 1
Chloromethane 0.19J ug/L 02/15/17 16:02 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 16:02 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 16:02 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 16:02 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 16:02 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 16:02 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/15/17 16:02 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 16:02 110-57-61001.0 1
1,1-Dichloroethane ND ug/L 02/15/17 16:02 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 16:02 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 16:02 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 16:02 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 16:02 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 16:02 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-SW2 Lab ID:92329884009 Collected:02/13/17 12:40 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/15/17 16:02 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 16:02 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 16:02 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/15/17 16:02 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 16:02 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/15/17 16:02 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 16:02 108-10-11000.33 1
Styrene ND ug/L 02/15/17 16:02 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 16:02 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 16:02 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 16:02 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 16:02 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/15/17 16:02 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 16:02 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 16:02 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 16:02 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 16:02 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 16:02 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 16:02 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 16:02 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %02/15/17 16:02 460-00-470-130 1
1,2-Dichloroethane-d4 (S)98 %02/15/17 16:02 17060-07-070-130 1
Toluene-d8 (S)105 %02/15/17 16:02 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-NES-1 Lab ID:92329884010 Collected:02/13/17 14:15 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 02/15/17 16:20 71-43-21.0 0.25 1
Surrogates
4-Bromofluorobenzene (S)93 %02/15/17 16:20 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/15/17 16:20 17060-07-070-130 1
Toluene-d8 (S)102 %02/15/17 16:20 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-TRIP BLANK Lab ID:92329884011 Collected:02/13/17 07:00 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/15/17 11:41 67-64-110010.0 1
Acetonitrile ND ug/L 02/15/17 11:41 75-05-855.0 2.2 1
Acrolein ND ug/L 02/15/17 11:41 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/15/17 11:41 107-13-12001.9 1
Allyl chloride ND ug/L 02/15/17 11:41 107-05-110.0 1.5 1
Benzene ND ug/L 02/15/17 11:41 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/15/17 11:41 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/15/17 11:41 75-27-41.0 0.18 1
Bromoform ND ug/L 02/15/17 11:41 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/15/17 11:41 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/15/17 11:41 78-93-31000.96 1
Carbon disulfide ND ug/L 02/15/17 11:41 75-15-01001.2 1
Carbon tetrachloride ND ug/L 02/15/17 11:41 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/15/17 11:41 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/15/17 11:41 75-00-310.0 0.54 1
Chloroform ND ug/L 02/15/17 11:41 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/15/17 11:41 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/15/17 11:41 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/15/17 11:41 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/15/17 11:41 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/15/17 11:41 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/15/17 11:41 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/15/17 11:41 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/15/17 11:41 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/15/17 11:41 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/15/17 11:41 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 02/15/17 11:41 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/15/17 11:41 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/15/17 11:41 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/15/17 11:41 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/15/17 11:41 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/15/17 11:41 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/15/17 11:41 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/15/17 11:41 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/15/17 11:41 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/15/17 11:41 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/15/17 11:41 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/15/17 11:41 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/15/17 11:41 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/15/17 11:41 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/15/17 11:41 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/15/17 11:41 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/15/17 11:41 78-83-110035.0 1
Methacrylonitrile ND ug/L 02/15/17 11:41 126-98-71000.93 1
Methylene Chloride ND ug/L 02/15/17 11:41 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/15/17 11:41 80-62-630.0 2.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 43 of 77
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Sample:3902-TRIP BLANK Lab ID:92329884011 Collected:02/13/17 07:00 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)ND ug/L 02/15/17 11:41 108-10-11000.33 1
Naphthalene ND ug/L 02/15/17 11:41 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/15/17 11:41 107-12-01503.6 1
Styrene ND ug/L 02/15/17 11:41 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/15/17 11:41 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/15/17 11:41 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/15/17 11:41 127-18-41.0 0.46 1
Toluene ND ug/L 02/15/17 11:41 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/15/17 11:41 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/15/17 11:41 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/15/17 11:41 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/15/17 11:41 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/15/17 11:41 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/15/17 11:41 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/15/17 11:41 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/15/17 11:41 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/15/17 11:41 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %02/15/17 11:41 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/15/17 11:41 17060-07-070-130 1
Toluene-d8 (S)103 %02/15/17 11:41 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349016
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1936297
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 02/21/17 12:120.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936298LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.42.5 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936299MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329740001
1936300
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 96 75-12592 4 252.5ND 2.4 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348311
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932379
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/18/17 03:213.9
Arsenic ug/L ND 10.0 02/18/17 03:215.0
Barium ug/L ND 100 02/18/17 03:212.5
Beryllium ug/L ND 1.0 02/18/17 03:210.50
Cadmium ug/L ND 1.0 02/18/17 03:210.50
Chromium ug/L ND 10.0 02/18/17 03:212.5
Cobalt ug/L ND 10.0 02/18/17 03:212.5
Copper ug/L ND 10.0 02/18/17 03:212.5
Lead ug/L ND 10.0 02/20/17 13:582.5
Nickel ug/L ND 50.0 02/18/17 03:212.5
Selenium ug/L ND 10.0 02/18/17 03:215.0
Silver ug/L ND 10.0 02/18/17 03:212.5
Tin ug/L 2.6J 100 02/18/17 03:212.5
Vanadium ug/L ND 25.0 02/18/17 03:212.5
Zinc ug/L ND 10.0 02/18/17 03:215.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932380LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 481500 96 80-120
Arsenic ug/L 466500 93 80-120
Barium ug/L 489500 98 80-120
Beryllium ug/L 474500 95 80-120
Cadmium ug/L 481500 96 80-120
Chromium ug/L 462500 92 80-120
Cobalt ug/L 479500 96 80-120
Copper ug/L 498500 100 80-120
Lead ug/L 511500 102 80-120
Nickel ug/L 474500 95 80-120
Selenium ug/L 475500 95 80-120
Silver ug/L 240250 96 80-120
Tin ug/L 482500 96 80-120
Vanadium ug/L 467500 93 80-120
Zinc ug/L 472500 94 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932381MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329740001
1932382
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 97 75-125100 3 20500ND486501
Arsenic ug/L 500 95 75-12598 3 20500ND475489
Barium ug/L 500 97 75-12599 1 2050032.9 519 527
Beryllium ug/L 500 96 75-12598 2 20500ND479490
Cadmium ug/L 500 97 75-12599 2 20500ND484493
Chromium ug/L 500 92 75-12595 2 20500ND463474
Cobalt ug/L 500 94 75-12596 2 20500ND472482
Copper ug/L 500 100 75-125101 1 20500ND501506
Lead ug/L 500 93 75-12596 2 20500ND466478
Nickel ug/L 500 94 75-12595 2 20500ND468475
Selenium ug/L 500 95 75-12598 2 20500ND476488
Silver ug/L 250 97 75-12599 2 20250ND243248
Tin ug/L 500 100 75-12599 0 20500ND498496
Vanadium ug/L 500 95 75-12597 3 20500ND475488
Zinc ug/L 500 94 75-12596 2 20500ND470480
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348250
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932179
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009
Matrix:Water
AnalyzedMDL
Thallium ug/L ND 5.5 02/16/17 14:390.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932180LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 101100 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932181MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329884001
1932182
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 88 75-125103 15 201000.023J 88.2 103
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348318
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009, 92329884010, 92329884011
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932416
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009, 92329884010, 92329884011
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/15/17 11:060.33
1,1,1-Trichloroethane ug/L ND 1.0 02/15/17 11:060.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/15/17 11:060.40
1,1,2-Trichloroethane ug/L ND 1.0 02/15/17 11:060.29
1,1-Dichloroethane ug/L ND 5.0 02/15/17 11:060.32
1,1-Dichloroethene ug/L ND 5.0 02/15/17 11:060.56
1,1-Dichloropropene ug/L ND 5.0 02/15/17 11:060.49
1,2,3-Trichloropropane ug/L ND 1.0 02/15/17 11:060.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/15/17 11:060.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/15/17 11:062.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/15/17 11:060.27
1,2-Dichlorobenzene ug/L ND 5.0 02/15/17 11:060.30
1,2-Dichloroethane ug/L ND 1.0 02/15/17 11:060.24
1,2-Dichloropropane ug/L ND 1.0 02/15/17 11:060.27
1,3-Dichlorobenzene ug/L ND 5.0 02/15/17 11:060.24
1,3-Dichloropropane ug/L ND 1.0 02/15/17 11:060.28
1,4-Dichlorobenzene ug/L ND 1.0 02/15/17 11:060.33
2,2-Dichloropropane ug/L ND 15.0 02/15/17 11:060.13
2-Butanone (MEK)ug/L ND 100 02/15/17 11:060.96
2-Hexanone ug/L ND 50.0 02/15/17 11:060.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/15/17 11:060.33
Acetone ug/L ND 100 02/15/17 11:0610.0
Acetonitrile ug/L ND 55.0 02/15/17 11:062.2
Acrolein ug/L ND 53.0 02/15/17 11:061.6
Acrylonitrile ug/L ND 200 02/15/17 11:061.9
Allyl chloride ug/L ND 10.0 02/15/17 11:061.5
Benzene ug/L ND 1.0 02/15/17 11:060.25
Bromochloromethane ug/L ND 3.0 02/15/17 11:060.17
Bromodichloromethane ug/L ND 1.0 02/15/17 11:060.18
Bromoform ug/L ND 3.0 02/15/17 11:060.26
Bromomethane ug/L ND 10.0 02/15/17 11:060.29
Carbon disulfide ug/L ND 100 02/15/17 11:061.2
Carbon tetrachloride ug/L ND 1.0 02/15/17 11:060.25
Chlorobenzene ug/L ND 3.0 02/15/17 11:060.23
Chloroethane ug/L ND 10.0 02/15/17 11:060.54
Chloroform ug/L ND 5.0 02/15/17 11:060.14
Chloromethane ug/L ND 1.0 02/15/17 11:060.11
Chloroprene ug/L ND 20.0 02/15/17 11:060.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/15/17 11:060.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/15/17 11:060.13
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 49 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932416
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004, 92329884005, 92329884006, 92329884007,
92329884008, 92329884009, 92329884010, 92329884011
Matrix:Water
AnalyzedMDL
Dibromochloromethane ug/L ND 3.0 02/15/17 11:060.21
Dibromomethane ug/L ND 10.0 02/15/17 11:060.21
Dichlorodifluoromethane ug/L ND 5.0 02/15/17 11:060.21
Ethyl methacrylate ug/L ND 10.0 02/15/17 11:060.20
Ethylbenzene ug/L ND 1.0 02/15/17 11:060.30
Iodomethane ug/L ND 10.0 02/15/17 11:060.32
Isobutanol ug/L ND 100 02/15/17 11:0635.0
Methacrylonitrile ug/L ND 100 02/15/17 11:060.93
Methyl methacrylate ug/L ND 30.0 02/15/17 11:062.0
Methylene Chloride ug/L ND 1.0 02/15/17 11:060.97
Naphthalene ug/L ND 10.0 02/15/17 11:060.24
Propionitrile ug/L ND 150 02/15/17 11:063.6
Styrene ug/L ND 1.0 02/15/17 11:060.26
Tetrachloroethene ug/L ND 1.0 02/15/17 11:060.46
Toluene ug/L ND 1.0 02/15/17 11:060.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/15/17 11:060.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/15/17 11:060.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/15/17 11:061.0
Trichloroethene ug/L ND 1.0 02/15/17 11:060.47
Trichlorofluoromethane ug/L ND 1.0 02/15/17 11:060.20
Vinyl acetate ug/L ND 50.0 02/15/17 11:060.35
Vinyl chloride ug/L ND 1.0 02/15/17 11:060.62
Xylene (Total)ug/L ND 5.0 02/15/17 11:060.66
1,2-Dichloroethane-d4 (S)%93 70-130 02/15/17 11:06
4-Bromofluorobenzene (S)%97 70-130 02/15/17 11:06
Toluene-d8 (S)%103 70-130 02/15/17 11:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932417LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 55.550 111 80-125
1,1,1-Trichloroethane ug/L 49.550 99 71-129
1,1,2,2-Tetrachloroethane ug/L 52.050 104 79-124
1,1,2-Trichloroethane ug/L 51.250 102 85-125
1,1-Dichloroethane ug/L 46.450 93 73-126
1,1-Dichloroethene ug/L 56.950 114 66-135
1,1-Dichloropropene ug/L 53.350 107 74-135
1,2,3-Trichloropropane ug/L 52.450 105 75-130
1,2,4-Trichlorobenzene ug/L 55.250 110 75-134
1,2-Dibromo-3-chloropropane ug/L 54.050 108 71-133
1,2-Dibromoethane (EDB)ug/L 54.250 108 83-124
1,2-Dichlorobenzene ug/L 53.350 107 80-133
1,2-Dichloroethane ug/L 47.250 94 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932417LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 48.750 97 75-132
1,3-Dichlorobenzene ug/L 52.850 106 77-130
1,3-Dichloropropane ug/L 55.750 111 76-131
1,4-Dichlorobenzene ug/L 51.950 104 78-130
2,2-Dichloropropane ug/L 51.750 103 40-160
2-Butanone (MEK)ug/L 99.5J100 99 61-144
2-Hexanone ug/L 112100 112 68-143
4-Methyl-2-pentanone (MIBK)ug/L 100100 100 72-135
Acetone ug/L 96.2J100 96 48-146
Acetonitrile ug/L 422500 84 62-150
Acrolein ug/L 263250 105 24-160
Acrylonitrile ug/L 234250 94 40-160
Allyl chloride ug/L 50.150 100 66-137
Benzene ug/L 51.050 102 80-125
Bromochloromethane ug/L 47.250 94 71-125
Bromodichloromethane ug/L 50.950 102 78-124
Bromoform ug/L 46.750 93 71-128
Bromomethane ug/L 44.750 89 40-160
Carbon disulfide ug/L 57.9J50 116 50-160
Carbon tetrachloride ug/L 53.150 106 69-131
Chlorobenzene ug/L 52.050 104 81-122
Chloroethane ug/L 45.150 90 39-148
Chloroform ug/L 45.650 91 73-127
Chloromethane ug/L 45.050 90 44-146
Chloroprene ug/L 57.450 115 75-145
cis-1,2-Dichloroethene ug/L 45.750 91 74-124
cis-1,3-Dichloropropene ug/L 52.150 104 72-132
Dibromochloromethane ug/L 50.450 101 78-125
Dibromomethane ug/L 48.550 97 82-120
Dichlorodifluoromethane ug/L 37.950 76 34-157
Ethyl methacrylate ug/L 56.550 113 82-121
Ethylbenzene ug/L 52.250 104 79-121
Iodomethane ug/L 104100 104 39-154
Isobutanol ug/L 9121000 91 34-160
Methacrylonitrile ug/L 503500 101 74-134
Methyl methacrylate ug/L 50.650 101 84-124
Methylene Chloride ug/L 48.350 97 64-133
Naphthalene ug/L 56.250 112 73-133
Propionitrile ug/L 483500 97 73-140
Styrene ug/L 53.050 106 84-126
Tetrachloroethene ug/L 54.450 109 78-122
Toluene ug/L 48.450 97 80-121
trans-1,2-Dichloroethene ug/L 47.950 96 71-127
trans-1,3-Dichloropropene ug/L 51.950 104 69-141
trans-1,4-Dichloro-2-butene ug/L 57.2J50 114 40-160
Trichloroethene ug/L 51.150 102 78-122
Trichlorofluoromethane ug/L 53.150 106 53-137
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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[phone]
Page 51 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932417LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 103100 103 40-160
Vinyl chloride ug/L 38.650 77 58-137
Xylene (Total)ug/L 157150 104 81-126
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%94 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932418MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329294005
1932419
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 400 97 70-130101 4 30400ND388403
1,1,1-Trichloroethane ug/L M140019570-130207 2 30400188026602700
1,1,2,2-Tetrachloroethane ug/L 400 96 70-130100 3 30400ND385399
1,1,2-Trichloroethane ug/L 400 102 70-130108 5 30400ND408431
1,1-Dichloroethane ug/L M140015970-130157 0 3040098116201610
1,1-Dichloroethene ug/L 400 154 70-166163 5 30400136754790
1,1-Dichloropropene ug/L 400 125 70-130128 2 30400ND502513
1,2,3-Trichloropropane ug/L 400 93 70-13094 1 30400ND371374
1,2,4-Trichlorobenzene ug/L 400 101 70-13099 2 30400ND403395
1,2-Dibromo-3-
chloropropane ug/L 400 99 70-13091 8 30400ND397366
1,2-Dibromoethane (EDB)ug/L 400 95 70-13099 4 30400ND381396
1,2-Dichlorobenzene ug/L 400 101 70-130104 2 30400ND406414
1,2-Dichloroethane ug/L 400 103 70-130106 2 30400ND413423
1,2-Dichloropropane ug/L 400 103 70-130108 5 30400ND413432
1,3-Dichlorobenzene ug/L 400 97 70-130102 5 30400ND388407
1,3-Dichloropropane ug/L 400 103 70-130108 4 30400ND412431
1,4-Dichlorobenzene ug/L 400 97 70-130102 4 30400ND390407
2,2-Dichloropropane ug/L 400 82 70-13086 5 30400ND328344
2-Butanone (MEK)ug/L 800 96 70-130105 9 30800ND765J840J
2-Hexanone ug/L 800 99 70-130102 3 30800ND796J816J
4-Methyl-2-pentanone
(MIBK)ug/L 800 86 70-13093 7 3080046.7J 734J 789J
Acetone ug/L 800 88 70-13098 10 30800ND740J818J
Acetonitrile ug/L 4000 113 70-130118 5 304000ND45104740
Acrolein ug/L 2000 112 70-130117 5 302000ND22402340
Acrylonitrile ug/L 2000 106 70-130112 6 302000ND2120J2240J
Allyl chloride ug/L 400 116 70-130113 3 30400ND465452
Benzene ug/L 400 115 70-148120 4 3040014.5J 473 494
Bromochloromethane ug/L 400 110 70-130110 0 30400ND441439
Bromodichloromethane ug/L 400 104 70-130109 4 30400ND417435
Bromoform ug/L 400 90 70-13090 0 30400ND361362
Bromomethane ug/L 400 115 70-130118 3 30400ND460472
Carbon disulfide ug/L M140018570-130183 1 30400ND738J730J
Carbon tetrachloride ug/L 400 118 70-130120 1 30400ND473480
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932418MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329294005
1932419
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chlorobenzene ug/L 400 101 70-146106 5 30400ND403422
Chloroethane ug/L 400 110 70-130118 6 30400ND444474
Chloroform ug/L 400 109 70-130114 5 3040010.5J 445 465
Chloromethane ug/L 400 111 70-130114 3 304002.7J 445 458
Chloroprene ug/L M140013370-130140 5 30400ND531559
cis-1,2-Dichloroethene ug/L M140019270-130203 2 30400167024402480
cis-1,3-Dichloropropene ug/L 400 98 70-130105 7 30400ND391419
Dibromochloromethane ug/L 400 101 70-130104 3 30400ND404417
Dibromomethane ug/L 400 102 70-130101 1 30400ND409405
Dichlorodifluoromethane ug/L 400 101 70-130103 2 30400ND405412
Ethyl methacrylate ug/L 400 100 70-130103 3 30400ND398411
Ethylbenzene ug/L 400 105 70-130106 1 30400ND424428
Iodomethane ug/L 800 122 70-130129 5 30800ND9781030
Isobutanol ug/L 8000 105 70-130103 2 308000ND84008200
Methacrylonitrile ug/L 4000 102 70-130104 3 304000ND40704180
Methyl methacrylate ug/L 400 92 70-130102 10 30400ND370J408J
Methylene Chloride ug/L 400 120 70-130123 3 30400ND478491
Naphthalene ug/L 400 105 70-130103 2 30400ND420410
Propionitrile ug/L 4000 101 70-130110 9 304000ND40304400
Styrene ug/L 400 103 70-130105 2 30400ND412419
Tetrachloroethene ug/L 400 101 70-130107 5 3040061.5 465 490
Toluene ug/L 400 103 70-155110 7 3040015.3J 426 455
trans-1,2-Dichloroethene ug/L M140012370-130131 6 30400ND503533
trans-1,3-Dichloropropene ug/L 400 96 70-130101 5 30400ND385404
trans-1,4-Dichloro-2-butene ug/L 400 100 70-13090 10 30400ND401J361J
Trichloroethene ug/L 400 129 69-151143 3 30400177022902340
Trichlorofluoromethane ug/L 400 114 70-130115 1 30400ND456461
Vinyl acetate ug/L 800 92 70-13091 0 30800ND733J732J
Vinyl chloride ug/L 400 96 70-130100 5 30400ND383402
1,2-Dichloroethane-d4 (S)%101 70-130101
4-Bromofluorobenzene (S)%101 70-13098
Toluene-d8 (S)%95 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348347
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932640
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 02/18/17 19:350.050
4,4'-DDE ug/L ND 0.10 02/18/17 19:350.050
4,4'-DDT ug/L ND 0.10 02/18/17 19:350.050
Aldrin ug/L ND 0.050 02/18/17 19:350.050
alpha-BHC ug/L ND 0.050 02/18/17 19:350.050
beta-BHC ug/L ND 0.050 02/18/17 19:350.050
Chlordane (Technical)ug/L ND 0.50 02/18/17 19:350.20
delta-BHC ug/L ND 0.050 02/18/17 19:350.050
Dieldrin ug/L ND 0.075 02/18/17 19:350.050
Endosulfan I ug/L ND 0.10 02/18/17 19:350.050
Endosulfan II ug/L ND 0.10 02/18/17 19:350.050
Endosulfan sulfate ug/L ND 0.10 02/18/17 19:350.050
Endrin ug/L ND 0.10 02/18/17 19:350.050
Endrin aldehyde ug/L ND 0.10 02/18/17 19:350.050
gamma-BHC (Lindane)ug/L ND 0.050 02/18/17 19:350.050
Heptachlor ug/L ND 0.050 02/18/17 19:350.050
Heptachlor epoxide ug/L ND 0.075 02/18/17 19:350.050
Methoxychlor ug/L ND 1.0 02/18/17 19:350.15
Toxaphene ug/L ND 1.5 02/18/17 19:350.20
Decachlorobiphenyl (S)%99 20-130 02/18/17 19:35
Tetrachloro-m-xylene (S)%101 20-130 02/18/17 19:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932641LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.26.25 107 20-150
4,4'-DDE ug/L 0.27.25 111 20-150
4,4'-DDT ug/L 0.28.25 113 20-150
Aldrin ug/L 0.21.25 86 20-150
alpha-BHC ug/L 0.24.25 98 20-150
beta-BHC ug/L 0.23.25 91 20-150
delta-BHC ug/L 0.28.25 114 20-150
Dieldrin ug/L 0.25.25 102 20-150
Endosulfan I ug/L 0.23.25 94 20-150
Endosulfan II ug/L 0.35.25 142 20-150
Endosulfan sulfate ug/L 0.34.25 137 20-150
Endrin ug/L 0.27.25 111 20-150
Endrin aldehyde ug/L 0.25.25 102 20-150
gamma-BHC (Lindane)ug/L 0.25.25 101 20-150
Heptachlor ug/L 0.23.25 92 20-150
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932641LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.26.25 105 20-150
Methoxychlor ug/L 0.78J.74 104 20-150
Decachlorobiphenyl (S)%96 20-130
Tetrachloro-m-xylene (S)%94 20-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1932642MATRIX SPIKE SAMPLE:
MSSpike
Result
92329884003
4,4'-DDD ug/L 0.27.25 108 20-150ND
4,4'-DDE ug/L 0.28.25 113 20-150ND
4,4'-DDT ug/L 0.28.25 113 20-150ND
Aldrin ug/L 0.22.25 90 20-150ND
alpha-BHC ug/L 0.22.25 88 20-150ND
beta-BHC ug/L 0.30.25 120 20-150ND
delta-BHC ug/L 0.30.25 121 20-150ND
Dieldrin ug/L 0.26.25 105 20-150ND
Endosulfan I ug/L 0.21.25 84 20-150ND
Endosulfan II ug/L 0.34.25 137 20-150ND
Endosulfan sulfate ug/L 0.33.25 135 20-150ND
Endrin ug/L 0.28.25 114 20-150ND
Endrin aldehyde ug/L 0.24.25 96 20-150ND
gamma-BHC (Lindane)ug/L 0.21.25 86 20-150ND
Heptachlor ug/L 0.21.25 87 20-150ND
Heptachlor epoxide ug/L 0.25.25 102 20-150ND
Methoxychlor ug/L 0.80J.74 108 20-150ND
Decachlorobiphenyl (S)%78 20-130
Tetrachloro-m-xylene (S)%72 20-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329884004
1932643SAMPLE DUPLICATE:
4,4'-DDD ug/L ND 30ND
4,4'-DDE ug/L ND 30ND
4,4'-DDT ug/L ND 30ND
Aldrin ug/L ND 30ND
alpha-BHC ug/L ND 30ND
beta-BHC ug/L ND 30ND
Chlordane (Technical)ug/L ND 30ND
delta-BHC ug/L ND 30ND
Dieldrin ug/L ND 30ND
Endosulfan I ug/L ND 30ND
Endosulfan II ug/L ND 30ND
Endosulfan sulfate ug/L ND 30ND
Endrin ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329884004
1932643SAMPLE DUPLICATE:
Endrin aldehyde ug/L ND 30ND
gamma-BHC (Lindane)ug/L ND 30ND
Heptachlor ug/L ND 30ND
Heptachlor epoxide ug/L ND 30ND
Methoxychlor ug/L ND 30ND
Toxaphene ug/L ND 30ND
Decachlorobiphenyl (S)%69 565
Tetrachloro-m-xylene (S)%99 891
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348549
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933765
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 02/17/17 12:020.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 02/17/17 12:020.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 02/17/17 12:020.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 02/17/17 12:020.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 02/17/17 12:020.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 02/17/17 12:020.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 02/17/17 12:020.50
Decachlorobiphenyl (S)%134 10-132 S302/17/17 12:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933766LABORATORY CONTROL SAMPLE:
LCSSpike
PCB-1016 (Aroclor 1016)ug/L 5.65 113 50-150
PCB-1260 (Aroclor 1260)ug/L 6.65 132 50-150
Decachlorobiphenyl (S)%109 10-132
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1933767MATRIX SPIKE SAMPLE:
MSSpike
Result
92329884003
PCB-1016 (Aroclor 1016)ug/L 6.35 127 50-150ND
PCB-1260 (Aroclor 1260)ug/L 6.35 126 50-150ND
Decachlorobiphenyl (S)%112 10-132
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329884004
1933768SAMPLE DUPLICATE:
PCB-1016 (Aroclor 1016)ug/L ND 30ND
PCB-1221 (Aroclor 1221)ug/L ND 30ND
PCB-1232 (Aroclor 1232)ug/L ND 30ND
PCB-1242 (Aroclor 1242)ug/L ND 30ND
PCB-1248 (Aroclor 1248)ug/L ND 30ND
PCB-1254 (Aroclor 1254)ug/L ND 30ND
PCB-1260 (Aroclor 1260)ug/L ND 30ND
Decachlorobiphenyl (S)%81 21100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 57 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
351150
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1887652
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 02/24/17 03:150.042
2,4,5-TP (Silvex)ug/L ND 0.19 02/24/17 03:150.049
2,4-D ug/L 1.2 0.94 02/24/17 03:150.22
Dinoseb ug/L ND 0.19 02/24/17 03:150.057
2,4-DCAA (S)%106 39-139 02/24/17 03:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1887653LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 1.41.2 121 37-133
2,4,5-TP (Silvex)ug/L 1.31.2 108 53-134
2,4-D ug/L 7.5 L1612535-124
Dinoseb ug/L 1.5 L11.2 129 13-116
2,4-DCAA (S)%108 39-139
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1888944MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
35295313001
1888945
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L M12.4 36 37-13337 3 402.40.041U 0.86 0.88
2,4,5-TP (Silvex)ug/L M12.4 34 53-13433 5 402.40.048U 0.82 0.78
2,4-D ug/L 12 47 35-12439 19 40120.22U 5.6 4.6
Dinoseb ug/L 2.4 42 13-11645 5 402.40.055U 1.0 1.1
2,4-DCAA (S)%S03239-13933 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 58 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348764
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1934957
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 02/20/17 11:011.7
1,3,5-Trinitrobenzene ug/L ND 10.0 02/20/17 11:011.1
1,3-Dinitrobenzene ug/L ND 20.0 02/20/17 11:011.5
1,4-Naphthoquinone ug/L ND 10.0 02/20/17 11:011.8
1-Naphthalenamine ug/L ND 10.0 02/20/17 11:010.96
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 02/20/17 11:011.6
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 02/20/17 11:012.3
2,4,5-Trichlorophenol ug/L ND 10.0 02/20/17 11:012.2
2,4,6-Trichlorophenol ug/L ND 10.0 02/20/17 11:011.9
2,4-Dichlorophenol ug/L ND 10.0 02/20/17 11:011.7
2,4-Dimethylphenol ug/L ND 10.0 02/20/17 11:012.2
2,4-Dinitrophenol ug/L ND 50.0 02/20/17 11:016.5
2,4-Dinitrotoluene ug/L ND 10.0 02/20/17 11:011.2
2,6-Dichlorophenol ug/L ND 10.0 02/20/17 11:011.8
2,6-Dinitrotoluene ug/L ND 10.0 02/20/17 11:011.7
2-Acetylaminofluorene ug/L ND 20.0 02/20/17 11:010.84
2-Chloronaphthalene ug/L ND 10.0 02/20/17 11:012.2
2-Chlorophenol ug/L ND 10.0 02/20/17 11:011.5
2-Methylnaphthalene ug/L ND 10.0 02/20/17 11:010.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/20/17 11:011.7
2-Naphthalenamine ug/L ND 10.0 02/20/17 11:010.98
2-Nitroaniline ug/L ND 50.0 02/20/17 11:012.8
2-Nitrophenol ug/L ND 10.0 02/20/17 11:011.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/20/17 11:011.7
3,3'-Dichlorobenzidine ug/L ND 20.0 02/20/17 11:011.4
3,3'-Dimethylbenzidine ug/L ND 10.0 02/20/17 11:012.1
3-Methylcholanthrene ug/L ND 10.0 02/20/17 11:010.82
3-Nitroaniline ug/L ND 50.0 02/20/17 11:012.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 02/20/17 11:011.7
4-Aminobiphenyl ug/L ND 20.0 02/20/17 11:010.92
4-Bromophenylphenyl ether ug/L ND 10.0 02/20/17 11:011.3
4-Chloro-3-methylphenol ug/L ND 20.0 02/20/17 11:014.2
4-Chloroaniline ug/L ND 20.0 02/20/17 11:013.4
4-Chlorophenylphenyl ether ug/L ND 10.0 02/20/17 11:012.1
4-Nitroaniline ug/L ND 20.0 02/20/17 11:012.5
4-Nitrophenol ug/L ND 50.0 02/20/17 11:015.8
5-Nitro-o-toluidine ug/L ND 10.0 02/20/17 11:011.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 02/20/17 11:010.77
Acenaphthene ug/L ND 10.0 02/20/17 11:010.25
Acenaphthylene ug/L ND 10.0 02/20/17 11:010.21
Acetophenone ug/L ND 10.0 02/20/17 11:012.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 59 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1934957
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
Anthracene ug/L ND 10.0 02/20/17 11:010.14
Benzo(a)anthracene ug/L ND 10.0 02/20/17 11:010.33
Benzo(a)pyrene ug/L ND 10.0 02/20/17 11:010.30
Benzo(b)fluoranthene ug/L ND 10.0 02/20/17 11:010.28
Benzo(g,h,i)perylene ug/L ND 10.0 02/20/17 11:010.38
Benzo(k)fluoranthene ug/L ND 10.0 02/20/17 11:010.43
Benzyl alcohol ug/L ND 20.0 02/20/17 11:013.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/20/17 11:011.7
bis(2-Chloroethyl) ether ug/L ND 10.0 02/20/17 11:011.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 02/20/17 11:010.85
Butylbenzylphthalate ug/L ND 10.0 02/20/17 11:010.75
Chlorobenzilate ug/L ND 10.0 02/20/17 11:010.72
Chrysene ug/L ND 10.0 02/20/17 11:010.21
Di-n-butylphthalate ug/L ND 10.0 02/20/17 11:011.1
Di-n-octylphthalate ug/L ND 10.0 02/20/17 11:010.86
Diallate ug/L ND 10.0 02/20/17 11:011.3
Dibenz(a,h)anthracene ug/L ND 10.0 02/20/17 11:010.55
Dibenzofuran ug/L ND 10.0 02/20/17 11:011.8
Diethylphthalate ug/L ND 6000 02/20/17 11:011.3
Dimethoate ug/L ND 20.0 02/20/17 11:010.92
Dimethylphthalate ug/L ND 10.0 02/20/17 11:011.5
Diphenylamine ug/L ND 10.0 02/20/17 11:011.3
Disulfoton ug/L ND 10.0 02/20/17 11:011.4
Ethyl methanesulfonate ug/L ND 20.0 02/20/17 11:011.8
Famphur ug/L ND 20.0 02/20/17 11:011.7
Fluoranthene ug/L ND 10.0 02/20/17 11:010.21
Fluorene ug/L ND 10.0 02/20/17 11:010.21
Hexachloro-1,3-butadiene ug/L ND 10.0 02/20/17 11:011.8
Hexachlorobenzene ug/L ND 10.0 02/20/17 11:011.1
Hexachlorocyclopentadiene ug/L ND 10.0 02/20/17 11:011.8
Hexachloroethane ug/L ND 10.0 02/20/17 11:011.5
Hexachloropropene ug/L ND 10.0 02/20/17 11:011.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/20/17 11:010.29
Isodrin ug/L ND 20.0 02/20/17 11:012.0
Isophorone ug/L ND 10.0 02/20/17 11:011.8
Isosafrole ug/L ND 10.0 02/20/17 11:011.8
Kepone ug/L ND 20.0 02/20/17 11:013.1
Methapyrilene ug/L ND 100 02/20/17 11:012.7
Methyl methanesulfonate ug/L ND 10.0 02/20/17 11:011.3
Methyl parathion ug/L ND 10.0 02/20/17 11:011.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 02/20/17 11:012.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/20/17 11:012.1
N-Nitrosodiethylamine ug/L ND 20.0 02/20/17 11:011.8
N-Nitrosodimethylamine ug/L ND 10.0 02/20/17 11:011.3
N-Nitrosodiphenylamine ug/L ND 10.0 02/20/17 11:011.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Page 60 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1934957
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
N-Nitrosomethylethylamine ug/L ND 10.0 02/20/17 11:011.8
N-Nitrosopiperidine ug/L ND 20.0 02/20/17 11:011.9
N-Nitrosopyrrolidine ug/L ND 10.0 02/20/17 11:012.5
Nitrobenzene ug/L ND 10.0 02/20/17 11:011.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 02/20/17 11:011.8
O-Toluidine ug/L ND 10.0 02/20/17 11:011.6
P-Dimethylaminoazobenzene ug/L ND 10.0 02/20/17 11:010.35
p-Phenylenediamine ug/L ND 10.0 02/20/17 11:010.96
Parathion (Ethyl parathion)ug/L ND 10.0 02/20/17 11:011.1
Pentachlorobenzene ug/L ND 10.0 02/20/17 11:012.0
Pentachloronitrobenzene ug/L ND 20.0 02/20/17 11:011.0
Pentachlorophenol ug/L ND 25.0 02/20/17 11:012.3
Phenacetin ug/L ND 20.0 02/20/17 11:010.97
Phenanthrene ug/L ND 10.0 02/20/17 11:010.22
Phenol ug/L ND 10.0 02/20/17 11:011.7
Phorate ug/L ND 10.0 02/20/17 11:011.1
Pronamide ug/L ND 10.0 02/20/17 11:010.97
Pyrene ug/L ND 10.0 02/20/17 11:010.19
Safrole ug/L ND 10.0 02/20/17 11:011.5
Thionazin ug/L ND 20.0 02/20/17 11:011.2
2,4,6-Tribromophenol (S)%79 27-110 02/20/17 11:01
2-Fluorobiphenyl (S)%77 27-110 02/20/17 11:01
2-Fluorophenol (S)%38 12-110 02/20/17 11:01
Nitrobenzene-d5 (S)%79 21-110 02/20/17 11:01
Phenol-d6 (S)%25 10-110 02/20/17 11:01
Terphenyl-d14 (S)%98 31-107 02/20/17 11:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 36.250 72 16-129
1,3,5-Trinitrobenzene ug/L 65.2 L15013055-125
1,3-Dinitrobenzene ug/L 45.350 91 30-122
1,4-Naphthoquinone ug/L 43.250 86 31-120
1-Naphthalenamine ug/L 25.850 52 37-126
2,2'-Oxybis(1-chloropropane)ug/L 27.550 55 18-120
2,3,4,6-Tetrachlorophenol ug/L 46.850 94 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 40.850 82 42-120
2,4-Dichlorophenol ug/L 37.450 75 30-120
2,4-Dimethylphenol ug/L 34.450 69 29-111
2,4-Dinitrophenol ug/L 163250 65 19-132
2,4-Dinitrotoluene ug/L 50.550 101 58-128
2,6-Dichlorophenol ug/L 41.050 82 54-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 61 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
2,6-Dinitrotoluene ug/L 48.250 96 54-129
2-Acetylaminofluorene ug/L 46.050 92 81-160
2-Chloronaphthalene ug/L 40.250 80 43-117
2-Chlorophenol ug/L 28.650 57 37-120
2-Methylnaphthalene ug/L 31.650 63 33-120
2-Methylphenol(o-Cresol)ug/L 22.650 45 31-120
2-Naphthalenamine ug/L 40.750 81 41-136
2-Nitroaniline ug/L 90.8100 91 48-121
2-Nitrophenol ug/L 32.850 66 25-116
3&4-Methylphenol(m&p Cresol)ug/L 19.250 38 23-120
3,3'-Dichlorobenzidine ug/L 87.3250 35 10-154
3,3'-Dimethylbenzidine ug/L 63.8100 64 10-157
3-Methylcholanthrene ug/L 41.750 83 65-130
3-Nitroaniline ug/L 81.1100 81 43-115
4,6-Dinitro-2-methylphenol ug/L 74.9100 75 44-124
4-Aminobiphenyl ug/L 40.450 81 21-125
4-Bromophenylphenyl ether ug/L 40.450 81 34-113
4-Chloro-3-methylphenol ug/L 74.8100 75 31-110
4-Chloroaniline ug/L 67.9100 68 20-120
4-Chlorophenylphenyl ether ug/L 40.150 80 34-116
4-Nitroaniline ug/L 84.7100 85 46-128
4-Nitrophenol ug/L 116250 46 11-120
5-Nitro-o-toluidine ug/L 44.350 89 78-160
7,12-Dimethylbenz(a)anthracene ug/L 38.950 78 47-124
Acenaphthene ug/L 37.450 75 48-114
Acenaphthylene ug/L 37.650 75 48-112
Acetophenone ug/L 30.450 61 24-120
Anthracene ug/L 42.050 84 57-118
Benzo(a)anthracene ug/L 44.050 88 56-121
Benzo(a)pyrene ug/L 41.250 82 55-127
Benzo(b)fluoranthene ug/L 44.350 89 53-128
Benzo(g,h,i)perylene ug/L 38.250 76 54-125
Benzo(k)fluoranthene ug/L 41.250 82 51-123
Benzyl alcohol ug/L 52.4100 52 27-120
bis(2-Chloroethoxy)methane ug/L 33.550 67 32-120
bis(2-Chloroethyl) ether ug/L 29.850 60 33-111
bis(2-Ethylhexyl)phthalate ug/L 51.450 103 50-145
Butylbenzylphthalate ug/L 51.350 103 54-138
Chlorobenzilate ug/L 42.350 85 65-132
Chrysene ug/L 42.650 85 58-127
Di-n-butylphthalate ug/L 50.250 100 56-125
Di-n-octylphthalate ug/L 53.250 106 50-134
Diallate ug/L 43.750 87 47-123
Dibenz(a,h)anthracene ug/L 40.550 81 53-129
Dibenzofuran ug/L 37.850 76 45-120
Diethylphthalate ug/L 46.7J50 93 53-120
Dimethoate ug/L 43.150 86 57-139
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
Dimethylphthalate ug/L 44.550 89 55-116
Diphenylamine ug/L 38.950 78 42-120
Disulfoton ug/L 46.450 93 49-156
Ethyl methanesulfonate ug/L 41.050 82 43-120
Famphur ug/L 55.2100 55 40-160
Fluoranthene ug/L 45.550 91 57-125
Fluorene ug/L 40.850 82 53-118
Hexachloro-1,3-butadiene ug/L 25.350 51 23-120
Hexachlorobenzene ug/L 39.250 78 49-116
Hexachlorocyclopentadiene ug/L 30.850 62 26-158
Hexachloroethane ug/L 22.450 45 30-114
Hexachloropropene ug/L 32.450 65 13-137
Indeno(1,2,3-cd)pyrene ug/L 40.950 82 55-128
Isodrin ug/L 45.050 90 68-129
Isophorone ug/L 43.850 88 31-118
Isosafrole ug/L 35.850 72 48-107
Kepone ug/L 47.3100 47 10-124
Methapyrilene ug/L 46.9J50 94 40-160
Methyl methanesulfonate ug/L 34.050 68 25-114
Methyl parathion ug/L 49.450 99 58-137
N-Nitroso-di-n-butylamine ug/L 32.950 66 36-115
N-Nitroso-di-n-propylamine ug/L 33.850 68 32-119
N-Nitrosodiethylamine ug/L 33.450 67 47-115
N-Nitrosodimethylamine ug/L 21.850 44 13-120
N-Nitrosodiphenylamine ug/L 38.950 78 43-120
N-Nitrosomethylethylamine ug/L 31.350 63 39-120
N-Nitrosopiperidine ug/L 39.150 78 43-113
N-Nitrosopyrrolidine ug/L 29.850 60 32-110
Nitrobenzene ug/L 42.650 85 33-110
O,O,O-Triethylphosphorothioate ug/L 41.550 83 51-127
O-Toluidine ug/L 30.150 60 27-120
P-Dimethylaminoazobenzene ug/L 19.2100 19 10-120
p-Phenylenediamine ug/L 49.050 98 72-143
Parathion (Ethyl parathion)ug/L 53.050 106 56-140
Pentachlorobenzene ug/L 41.550 83 30-137
Pentachloronitrobenzene ug/L 52.550 105 70-124
Pentachlorophenol ug/L 81.3250 33 10-137
Phenacetin ug/L 44.950 90 60-130
Phenanthrene ug/L 41.250 82 57-117
Phenol ug/L 13.850 28 10-120
Phorate ug/L 53.950 108 55-126
Pronamide ug/L 55.750 111 75-124
Pyrene ug/L 44.450 89 55-122
Safrole ug/L 39.250 78 41-120
Thionazin ug/L 43.850 88 63-137
2,4,6-Tribromophenol (S)%85 27-110
2-Fluorobiphenyl (S)%70 27-110
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 63 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
2-Fluorophenol (S)%35 12-110
Nitrobenzene-d5 (S)%77 21-110
Phenol-d6 (S)%25 10-110
Terphenyl-d14 (S)%88 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
1,2,4,5-Tetrachlorobenzene ug/L 44.150 88 50-150ND
1,3,5-Trinitrobenzene ug/L 68.750 137 50-150ND
1,3-Dinitrobenzene ug/L 50.350 101 50-150ND
1,4-Naphthoquinone ug/L 49.250 98 50-150ND
1-Naphthalenamine ug/L 28.050 56 50-150ND
2,2'-Oxybis(1-chloropropane)ug/L 34.250 68 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 60.650 121 50-150ND
2,4,5-Trichlorophenol ug/L 40.150 80 19-105ND
2,4,6-Trichlorophenol ug/L 48.550 97 13-108ND
2,4-Dichlorophenol ug/L 41.150 82 29-111ND
2,4-Dimethylphenol ug/L 39.950 80 21-103ND
2,4-Dinitrophenol ug/L 234250 94 10-109ND
2,4-Dinitrotoluene ug/L 55.7 M15011127-104ND
2,6-Dichlorophenol ug/L 47.550 95 50-150ND
2,6-Dinitrotoluene ug/L 53.2 M15010628-101ND
2-Acetylaminofluorene ug/L 51.550 103 50-150ND
2-Chloronaphthalene ug/L 45.850 92 14-102ND
2-Chlorophenol ug/L 35.150 70 16-110ND
2-Methylnaphthalene ug/L 39.450 79 13-110ND
2-Methylphenol(o-Cresol)ug/L 27.750 55 19-110ND
2-Naphthalenamine ug/L 37.350 75 50-150ND
2-Nitroaniline ug/L 102100 102 26-103ND
2-Nitrophenol ug/L 38.250 76 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 22.050 44 20-110ND
3,3'-Dichlorobenzidine ug/L 90.2250 36 25-112ND
3,3'-Dimethylbenzidine ug/L 34.0 M11003450-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 88.2100 88 29-110ND
4,6-Dinitro-2-methylphenol ug/L 92.0100 92 10-117ND
4-Aminobiphenyl ug/L 34.350 69 50-150ND
4-Bromophenylphenyl ether ug/L 43.750 87 20-105ND
4-Chloro-3-methylphenol ug/L 84.4100 84 22-110ND
4-Chloroaniline ug/L 73.1100 73 20-100ND
4-Chlorophenylphenyl ether ug/L 43.050 86 19-102ND
4-Nitroaniline ug/L 92.9100 93 29-110ND
4-Nitrophenol ug/L 139250 55 10-110ND
5-Nitro-o-toluidine ug/L 49.050 98 50-150ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 64 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
7,12-Dimethylbenz(a)anthracene ug/L 42.050 84 50-150ND
Acenaphthene ug/L 42.950 86 17-100ND
Acenaphthylene ug/L 43.250 86 21-100ND
Acetophenone ug/L 38.050 76 50-150ND
Anthracene ug/L 46.050 92 24-109ND
Benzo(a)anthracene ug/L 48.550 97 22-117ND
Benzo(a)pyrene ug/L 45.150 90 23-104ND
Benzo(b)fluoranthene ug/L 47.350 95 23-103ND
Benzo(g,h,i)perylene ug/L 43.850 88 18-111ND
Benzo(k)fluoranthene ug/L 45.250 90 22-113ND
Benzyl alcohol ug/L 61.4100 61 19-101ND
bis(2-Chloroethoxy)methane ug/L 37.850 76 22-110ND
bis(2-Chloroethyl) ether ug/L 36.250 72 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 56.5 M15011323-102ND
Butylbenzylphthalate ug/L 55.5 M15011125-110ND
Chlorobenzilate ug/L 47.150 94 50-150ND
Chrysene ug/L 47.250 94 23-115ND
Di-n-butylphthalate ug/L 54.450 109 26-110ND
Di-n-octylphthalate ug/L 58.2 M15011622-110ND
Diallate ug/L 47.450 95 50-150ND
Dibenz(a,h)anthracene ug/L 45.150 90 21-112ND
Dibenzofuran ug/L 42.350 85 19-102ND
Diethylphthalate ug/L 50.5J50 101 29-110ND
Dimethoate ug/L 48.750 97 50-150ND
Dimethylphthalate ug/L 48.350 97 27-110ND
Diphenylamine ug/L 43.550 87 50-150ND
Disulfoton ug/L 53.050 106 50-150ND
Ethyl methanesulfonate ug/L 48.850 98 50-150ND
Famphur ug/L 71.1100 71 50-150ND
Fluoranthene ug/L 49.950 100 23-112ND
Fluorene ug/L 45.350 91 22-104ND
Hexachloro-1,3-butadiene ug/L 36.450 73 10-110ND
Hexachlorobenzene ug/L 44.050 88 21-116ND
Hexachlorocyclopentadiene ug/L 41.250 82 10-110ND
Hexachloroethane ug/L 33.350 67 10-110ND
Hexachloropropene ug/L 45.650 91 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 45.450 91 20-113ND
Isodrin ug/L 48.450 97 50-150ND
Isophorone ug/L 49.750 99 50-150ND
Isosafrole ug/L 41.150 82 50-150ND
Kepone ug/L 45.1 M11004550-150ND
Methapyrilene ug/L 42.4J50 85 50-150ND
Methyl methanesulfonate ug/L 41.350 83 50-150ND
Methyl parathion ug/L 55.450 111 50-150ND
N-Nitroso-di-n-butylamine ug/L 38.450 77 50-150ND
N-Nitroso-di-n-propylamine ug/L 43.050 86 21-105ND
N-Nitrosodiethylamine ug/L 43.150 86 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 65 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
N-Nitrosodimethylamine ug/L 25.550 51 10-110ND
N-Nitrosodiphenylamine ug/L 43.550 87 23-107ND
N-Nitrosomethylethylamine ug/L 39.350 79 50-150ND
N-Nitrosopiperidine ug/L 46.950 94 50-150ND
N-Nitrosopyrrolidine ug/L 40.950 82 50-150ND
Nitrobenzene ug/L 49.150 98 20-110ND
O,O,O-Triethylphosphorothioate ug/L 49.850 100 50-150ND
O-Toluidine ug/L 36.050 72 50-150ND
P-Dimethylaminoazobenzene ug/L 20.5 M11002150-150ND
p-Phenylenediamine ug/L 52.750 105 50-150ND
Parathion (Ethyl parathion)ug/L 60.650 121 50-150ND
Pentachlorobenzene ug/L 45.750 91 50-150ND
Pentachloronitrobenzene ug/L 58.450 117 50-150ND
Pentachlorophenol ug/L 100250 40 10-118ND
Phenacetin ug/L 50.250 100 50-150ND
Phenanthrene ug/L 44.950 90 24-106ND
Phenol ug/L 17.050 34 12-110ND
Phorate ug/L 59.250 118 50-150ND
Pronamide ug/L 60.650 121 50-150ND
Pyrene ug/L 48.950 98 24-114ND
Safrole ug/L 47.050 94 50-150ND
Thionazin ug/L 50.150 100 50-150ND
2,4,6-Tribromophenol (S)%94 27-110
2-Fluorobiphenyl (S)%80 27-110
2-Fluorophenol (S)%42 12-110
Nitrobenzene-d5 (S)%88 21-110
Phenol-d6 (S)%31 10-110
Terphenyl-d14 (S)%87 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,2'-Oxybis(1-chloropropane)ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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[phone]
Page 66 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 67 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%61 2781
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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[phone]
Page 68 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
2-Fluorobiphenyl (S)%72 1181
2-Fluorophenol (S)%32 634
Nitrobenzene-d5 (S)%73 1686
Phenol-d6 (S)%19 720
Terphenyl-d14 (S)%81 22100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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Huntersville, NC 28078
[phone]
Page 69 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348571
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933979
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/16/17 17:10100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933980LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 520J500 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933981MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329770016
1933982
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 106 80-120104 2 10500ND531J522J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933983MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329927002
1933984
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15004980-12049 0 10500ND246J247J
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 70 of 77
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348779
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1935054
Associated Lab Samples:92329884001, 92329884002, 92329884003, 92329884004
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 02/18/17 18:184.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935055LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 86.7100 87 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1935056MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329789002
1935057
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L R11007880-12096 21 10100ND80.2 98.6
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1935058MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329884004
1935059
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 116 80-120114 1 10100ND118116
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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[phone]
Page 71 of 77
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Analyte was detected in the associated method blank.B
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits in
associated samples.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
Surrogate recovery outside laboratory control limits.S0
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
Page 72 of 77
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92329884001 348347 3484953902-MW1R EPA 3510 EPA 8081
92329884002 348347 3484953902-MW2R EPA 3510 EPA 8081
92329884003 348347 3484953902-MW3R EPA 3510 EPA 8081
92329884004 348347 3484953902-FIELD BLANK EPA 3510 EPA 8081
92329884001 348549 3487103902-MW1R EPA 3510 EPA 8082
92329884002 348549 3487103902-MW2R EPA 3510 EPA 8082
92329884003 348549 3487103902-MW3R EPA 3510 EPA 8082
92329884004 348549 3487103902-FIELD BLANK EPA 3510 EPA 8082
92329884001 351150 3518983902-MW1R EPA 8151 EPA 8151
92329884002 351150 3518983902-MW2R EPA 8151 EPA 8151
92329884003 351150 3518983902-MW3R EPA 8151 EPA 8151
92329884004 351150 3518983902-FIELD BLANK EPA 8151 EPA 8151
92329884001 348311 3484463902-MW1R EPA 3010A EPA 6010
92329884002 348311 3484463902-MW2R EPA 3010A EPA 6010
92329884003 348311 3484463902-MW3R EPA 3010A EPA 6010
92329884004 348311 3484463902-FIELD BLANK EPA 3010A EPA 6010
92329884005 348311 3484463902-MW4 EPA 3010A EPA 6010
92329884006 348311 3484463902-MW5 EPA 3010A EPA 6010
92329884007 348311 3484463902-MW6 EPA 3010A EPA 6010
92329884008 348311 3484463902-SW1 EPA 3010A EPA 6010
92329884009 348311 3484463902-SW2 EPA 3010A EPA 6010
92329884001 348250 3485683902-MW1R EPA 3010A EPA 6020B
92329884002 348250 3485683902-MW2R EPA 3010A EPA 6020B
92329884003 348250 3485683902-MW3R EPA 3010A EPA 6020B
92329884004 348250 3485683902-FIELD BLANK EPA 3010A EPA 6020B
92329884005 348250 3485683902-MW4 EPA 3010A EPA 6020B
92329884006 348250 3485683902-MW5 EPA 3010A EPA 6020B
92329884007 348250 3485683902-MW6 EPA 3010A EPA 6020B
92329884008 348250 3485683902-SW1 EPA 3010A EPA 6020B
92329884009 348250 3485683902-SW2 EPA 3010A EPA 6020B
92329884001 349016 3491143902-MW1R EPA 7470 EPA 7470
92329884002 349016 3491143902-MW2R EPA 7470 EPA 7470
92329884003 349016 3491143902-MW3R EPA 7470 EPA 7470
92329884004 349016 3491143902-FIELD BLANK EPA 7470 EPA 7470
92329884001 348764 3489793902-MW1R EPA 3510 EPA 8270
92329884002 348764 3489793902-MW2R EPA 3510 EPA 8270
92329884003 348764 3489793902-MW3R EPA 3510 EPA 8270
92329884004 348764 3489793902-FIELD BLANK EPA 3510 EPA 8270
92329884001 3483183902-MW1R EPA 8260
92329884002 3483183902-MW2R EPA 8260
92329884003 3483183902-MW3R EPA 8260
92329884004 3483183902-FIELD BLANK EPA 8260
92329884005 3483183902-MW4 EPA 8260
92329884006 3483183902-MW5 EPA 8260
92329884007 3483183902-MW6 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:19 PM
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[phone]
Page 73 of 77
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92329884
BUTNER LANDFILL COMPLIANCE
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92329884008 3483183902-SW1 EPA 8260
92329884009 3483183902-SW2 EPA 8260
92329884010 3483183902-NES-1 EPA 8260
92329884011 3483183902-TRIP BLANK EPA 8260
92329884001 3485713902-MW1R SM 4500-S2D
92329884002 3485713902-MW2R SM 4500-S2D
92329884003 3485713902-MW3R SM 4500-S2D
92329884004 3485713902-FIELD BLANK SM 4500-S2D
92329884001 3487793902-MW1R SM 4500-CN-E
92329884002 3487793902-MW2R SM 4500-CN-E
92329884003 3487793902-MW3R SM 4500-CN-E
92329884004 3487793902-FIELD BLANK SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 74 of 77
Page 75 of 77
Page 76 of 77
Page 77 of 77
#=CL#
February 27, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92329874
92329874
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BUTNER LANDFILL MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 14, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 22
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 22
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Lab ID Sample ID Matrix Date Collected Date Received
92329874001 3902-MW-2R Water 02/13/17 13:20 02/14/17 10:25
92329874002 3902-MW3R Water 02/13/17 13:07 02/14/17 10:25
92329874003 3902-MW1R Water 02/13/17 11:55 02/14/17 10:25
92329874004 3902-NES-1 Water 02/13/17 14:15 02/14/17 10:25
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 3 of 22
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92329874001 3902-MW-2R SM 2320B 1 PASI-AKDF
SM 5210B 1 PASI-AALC
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92329874002 3902-MW3R SM 2320B 1 PASI-AKDF
SM 5210B 1 PASI-AALC
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92329874003 3902-MW1R SM 2320B 1 PASI-AKDF
SM 5210B 1 PASI-AALC
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
92329874004 3902-NES-1 EPA 8260 4 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 5210B 1 PASI-AALC
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5220D 1 PASI-AMDW
SM 5310B 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 4 of 22
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92329874001 3902-MW-2R
Alkalinity, Total as CaCO3 753000 ug/L 02/22/17 03:525000SM 2320B
BOD, 5 day 9500 ug/L 02/20/17 09:14 B22000SM 5210B
Sulfate 1590J ug/L 02/16/17 20:08250000EPA 300.0
Nitrogen, Nitrate 189J ug/L 02/15/17 11:0110000EPA 353.2
Chloride 309000 ug/L 02/23/17 03:3610000SM 4500-Cl-E
Chemical Oxygen Demand 119000 ug/L 02/16/17 00:0525000SM 5220D
Total Organic Carbon 28500 ug/L 02/25/17 04:141000SM 5310B
92329874002 3902-MW3R
Alkalinity, Total as CaCO3 654000 ug/L 02/22/17 04:225000SM 2320B
Sulfate 1780J ug/L 02/16/17 20:17250000EPA 300.0
Chloride 215000 ug/L 02/23/17 03:3710000SM 4500-Cl-E
Chemical Oxygen Demand 43000 ug/L 02/16/17 00:0525000SM 5220D
Total Organic Carbon 9720 ug/L 02/25/17 05:051000SM 5310B
92329874003 3902-MW1R
Alkalinity, Total as CaCO3 37900 ug/L 02/22/17 05:365000SM 2320B
Sulfate 1530J ug/L 02/16/17 20:26250000EPA 300.0
Nitrogen, Nitrate 248J ug/L 02/15/17 10:5510000EPA 353.2
Chloride 3450 ug/L 02/23/17 03:121000SM 4500-Cl-E
Chemical Oxygen Demand 17000J ug/L 02/16/17 00:0525000SM 5220D
92329874004 3902-NES-1
Alkalinity, Total as CaCO3 8790 ug/L 02/22/17 05:475000SM 2320B
Sulfate 11900J ug/L 02/17/17 14:311250000EPA 300.0
Nitrogen, Nitrate 2630J ug/L 02/15/17 11:0610000EPA 353.2
Chloride 5090 ug/L 02/23/17 03:131000SM 4500-Cl-E
Chemical Oxygen Demand 22000J ug/L 02/16/17 00:0525000SM 5220D
Total Organic Carbon 1360 ug/L 02/25/17 05:261000SM 5310B
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 5 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Sample:3902-MW-2R Lab ID:92329874001 Collected:02/13/17 13:20 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 753000 ug/L 02/22/17 03:52500010001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day 9500 ug/L 02/20/17 09:14 B202/15/17 03:55200020001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1590J ug/L 02/16/17 20:08 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 189J ug/L 02/15/17 11:011000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 309000 ug/L 02/23/17 03:36 16887-00-610000500010
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 119000 ug/L 02/16/17 00:0525000125001
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 28500 ug/L 02/25/17 04:14 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Sample:3902-MW3R Lab ID:92329874002 Collected:02/13/17 13:07 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 654000 ug/L 02/22/17 04:22500010001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/20/17 09:1402/15/17 03:55200020001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1780J ug/L 02/16/17 20:17 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate ND ug/L 02/15/17 11:001000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 215000 ug/L 02/23/17 03:37 16887-00-610000500010
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 43000 ug/L 02/16/17 00:0525000125001
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 9720 ug/L 02/25/17 05:05 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Sample:3902-MW1R Lab ID:92329874003 Collected:02/13/17 11:55 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 37900 ug/L 02/22/17 05:36500010001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/20/17 09:14 B202/15/17 03:55200020001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1530J ug/L 02/16/17 20:26 14808-79-825000010001
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 248J ug/L 02/15/17 10:551000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 3450 ug/L 02/23/17 03:12 16887-00-610005001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 17000J ug/L 02/16/17 00:0525000125001
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND ug/L 02/25/17 05:15 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 22
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Sample:3902-NES-1 Lab ID:92329874004 Collected:02/13/17 14:15 Received:02/14/17 10:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 02/15/17 12:33 71-43-21.0 0.25 1
Surrogates
4-Bromofluorobenzene (S)96 %02/15/17 12:33 460-00-470-130 1
1,2-Dichloroethane-d4 (S)93 %02/15/17 12:33 17060-07-070-130 1
Toluene-d8 (S)104 %02/15/17 12:33 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 8790 ug/L 02/22/17 05:47500010001
Analytical Method: SM 5210B5210B BOD, 5 day
BOD, 5 day ND ug/L 02/20/17 09:14 B202/15/17 03:55200020001
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 11900J ug/L 02/17/17 14:31 14808-79-8125000050005
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 2630J ug/L 02/15/17 11:061000010.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 5090 ug/L 02/23/17 03:13 16887-00-610005001
Analytical Method: SM 5220D5220D COD
Chemical Oxygen Demand 22000J ug/L 02/16/17 00:0525000125001
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1360 ug/L 02/25/17 05:26 7440-44-010005001
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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Huntersville, NC 28078
[phone]
Page 9 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348318
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932416
Associated Lab Samples:92329874004
Matrix:Water
AnalyzedMDL
Benzene ug/L ND 1.0 02/15/17 11:060.25
1,2-Dichloroethane-d4 (S)%93 70-130 02/15/17 11:06
4-Bromofluorobenzene (S)%97 70-130 02/15/17 11:06
Toluene-d8 (S)%103 70-130 02/15/17 11:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932417LABORATORY CONTROL SAMPLE:
LCSSpike
Benzene ug/L 51.050 102 80-125
1,2-Dichloroethane-d4 (S)%104 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%94 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932418MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329294005
1932419
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 400 115 70-148120 4 3040014.5J 473 494
1,2-Dichloroethane-d4 (S)%101 70-130101
4-Bromofluorobenzene (S)%101 70-13098
Toluene-d8 (S)%95 70-13098
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349117
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1936703
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/22/17 00:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936704LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4710050000 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936705MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330450002
1936706
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 25500009.5 mg/L 58100 58100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936707MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330336002
1936708
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 255000012.1 mg/L 60800 60600
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348225
SM 5210B
SM 5210B
5210B BOD, 5 day
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932072
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
BOD, 5 day ug/L ND 2000 02/20/17 09:142000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932073LABORATORY CONTROL SAMPLE:
LCSSpike
BOD, 5 day ug/L 172000198000 87 84.6-115.4
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329894002
1932074SAMPLE DUPLICATE:
BOD, 5 day ug/L 358000 2 10364 mg/L
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348535
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933689
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Sulfate ug/L ND 250000 02/17/17 11:471000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933690LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933691MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329959001
1933692
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 91 90-11091 1 10200002.0 mg/L 20100J 20300J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933693MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329628003
1933694
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M1200008890-11090 2 10200004.4 mg/L 21900J 22400J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348214
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1932056
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 02/15/17 10:5110.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1932057LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2500J2500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1932058MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329874003
1932059
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 99 90-110100 1 102500248J2730J2740J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 14 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349277
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1937756
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Chloride ug/L ND 1000 02/23/17 02:58500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937757LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1980020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937758MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233012
1937759
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 100 90-11099 0 10100001.4 mg/L 11300 11300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937760MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330435003
1937761
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 107 90-110107 0 10100005.3 mg/L 16000 16000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348423
SM 5220D
SM 5220D
5220D COD
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1933139
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Chemical Oxygen Demand ug/L ND 25000 02/16/17 00:0512500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1933140LABORATORY CONTROL SAMPLE:
LCSSpike
Chemical Oxygen Demand ug/L 751000750000 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933141MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329729001
1933142
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 110 90-110110 0 3750000ND829000829000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1933143MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329741001
1933144
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chemical Oxygen Demand ug/L 750000 104 90-110104 0 3750000116 mg/L 895000 897000
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 22
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349587
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1939465
Associated Lab Samples:92329874001, 92329874002, 92329874003, 92329874004
Matrix:Water
AnalyzedMDL
Total Organic Carbon ug/L ND 1000 02/24/17 23:26500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939466LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon ug/L 2520025000 101 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939467MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329628002
1939468
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 99 90-11099 0 10250008.3 mg/L 33100 33000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939469MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330336001
1939470
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon ug/L 25000 101 90-110102 1 10250003.2 mg/L 28600 28700
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 17 of 22
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Oxygen usage is less than 2.0 for all dilutions set. The reported value is an estimated less than value and is calculated
for the dilution using the most amount of sample.B2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 18 of 22
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92329874
BUTNER LANDFILL MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92329874004 3483183902-NES-1 EPA 8260
92329874001 3491173902-MW-2R SM 2320B
92329874002 3491173902-MW3R SM 2320B
92329874003 3491173902-MW1R SM 2320B
92329874004 3491173902-NES-1 SM 2320B
92329874001 348225 3482313902-MW-2R SM 5210B SM 5210B
92329874002 348225 3482313902-MW3R SM 5210B SM 5210B
92329874003 348225 3482313902-MW1R SM 5210B SM 5210B
92329874004 348225 3482313902-NES-1 SM 5210B SM 5210B
92329874001 3485353902-MW-2R EPA 300.0
92329874002 3485353902-MW3R EPA 300.0
92329874003 3485353902-MW1R EPA 300.0
92329874004 3485353902-NES-1 EPA 300.0
92329874001 3482143902-MW-2R EPA 353.2
92329874002 3482143902-MW3R EPA 353.2
92329874003 3482143902-MW1R EPA 353.2
92329874004 3482143902-NES-1 EPA 353.2
92329874001 3492773902-MW-2R SM 4500-Cl-E
92329874002 3492773902-MW3R SM 4500-Cl-E
92329874003 3492773902-MW1R SM 4500-Cl-E
92329874004 3492773902-NES-1 SM 4500-Cl-E
92329874001 3484233902-MW-2R SM 5220D
92329874002 3484233902-MW3R SM 5220D
92329874003 3484233902-MW1R SM 5220D
92329874004 3484233902-NES-1 SM 5220D
92329874001 3495873902-MW-2R SM 5310B
92329874002 3495873902-MW3R SM 5310B
92329874003 3495873902-MW1R SM 5310B
92329874004 3495873902-NES-1 SM 5310B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/27/2017 02:46 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 22
Page 20 of 22
Page 21 of 22
Page 22 of 22

Appendix C

Historical Groundwater Analytical Data
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
INORGANICS
Antimony 8-Sep-94 ---30 ND ND ND ND ND ND ------
1-Dec-94 ---30 ND ND ND ND ND ND ------
9-Feb-95 ---30 ND ND ND ND ND ND ------
2-Mar-95 ---30 ND ND ND ND ND ND ------
15-Nov-95 ---30 ND ND ND ND ND ND ------28-May-96 ---30 ND ND ND ND ND ND ------
22-Nov-96 ---30 ND ND ND ND ND ND ------
17-Jun-97 ---30 ND ND ND ND ND ND ------
1-Dec-97 ---30 ND ND ND ND ND ND ------
20-May-98 ---30 ND ND ND ND ND ND ------
19-Nov-98 ---30 ND ND ND ND ND ND ------
21-Jul-99 ---30 ND ND ND ND ND ND ------16-Nov-99 ---30 ND ND ND ND ND ND ------
10-May-00 ---30 ND 80.0 38.0 32.0 33.0 31.0 ------
26-Oct-00 ---30 30.0 ND ND ND ND ND ------
18-Apr-01 ---30 ND ND ND ND ND ND ------
27-Oct-01 ---30 ND ND ND ND ND ND ------
13-Jun-02 ---30 ND ND ND ND ND ND ------
19-Nov-02 ---30 ND ND ND ND ND ND ------27-Jun-03 ---30 ND ND ND ND ND ND ------
30-Dec-03 ---30 ND ND ND ND ND ND ---ND
30-Jun-04 ---30 ND ND ND ND ND ND ---ND
29-Dec-04 ---30 ND ND ND ND ND ND ---ND
29-Jun-05 ---30 ND ND ND ND ND ND ---ND
29-Dec-05 ---30 ND ND ND ND ND ND ---ND
28-Jun-06 ---30 ND ND ND ND ND ND ---ND29-Dec-06 ---6 ND ND ND ND ND ND ---ND
12-Jul-07 ---6 ND ND ND ND ND ND ---ND
GWPS = 1.4 µg/L (10/23/07)19-Dec-07 ---6 ND ND ND ND ND ND ND ND
8-Jul-08 ---6 ND ND ND ND ND ND ---ND
17-Dec-08 2.6 6.0 ND ND ND ND ND ND ---ND
9-Jul-09 2.6 6.0 ND ND ND ND ND ND ND ND
16-Dec-09 2.6 6.0 ND ND ND ND ND ND ---NDNC 2B = NE (03/24/10)24-Jun-10 2.6 6.0 ND ND ND 2.9 J ND ND ---ND
GWPS = 1 µg/L (8/1/10)13-Dec-10 2.6 6.0 ND ND 3.0 J ND 2.8 J ND ---ND
20-Jun-11 5.0 6.0 ND ND ND ND 6.0 ND ---ND
5-Dec-11 5.0 6.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 6.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 6.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 6.0 ND ND ND ND ND ND ND ND5-Aug-13 5.0 6.0 ND ND ND ND ND ND ---ND
24-Feb-14 5.0 6.0 8.8 ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 6.0 ND 10.5 8.0 ND ND ND ---ND
10-Mar-15 EPA 6010 3.8 6.0 ND 7.1 6.5 3.9 J ND ND ---ND
18-Aug-15 EPA 6010 3.8 6.0 ND 6.2 4.8 J 4.1 J ND ND ---ND
16-Feb-16 EPA 6010 3.8 6.0 ND 9.9 6.5 4.3 J ND ND ---ND
9-Aug-16 EPA 6010 3.8 6.0 ND 7.7 ND ND ND ND ---ND13-Feb-17 EPA 6010 3.9 6.0 ND ND ND ND ND ND ---ND
Arsenic 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 ND ND ND ND ND ND ------
9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------28-May-96 ---10 ND ND ND ND ND ND ------
22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 6.0 J 15.0 ND ND ND ND ------
1-Dec-97 ---10 ND 5.0 J ND ND ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND
28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 2.0 J ND ND ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 4.1 J ND ND ND ND ND ND
8-Jul-08 ---10 ND 4.9 J ND ND ND ND ---ND
17-Dec-08 2.7 10.0 ND ND ND ND ND ND ---ND9-Jul-09 2.7 10.0 ND 13.5 10.9 5.6 J ND 4.0 J ND ND
16-Dec-09 2.7 10.0 ND 10.6 6.4 J 5.0 J ND 3.6 J ---ND
NC 2L = 10 µg/L (02/05/10)24-Jun-10 2.7 10.0 ND 11.8 8.1 J 8.2 J 3.3 J 3.1 J ---ND
Resample >12-Aug-10 2.7 10.0 ------7.2 J ------------ND
Resample >31-Aug-10 2.7 10.0 ---15.4 ---------------ND
13-Dec-10 2.7 10.0 ND 4.9 J 2.7 J 5.4 J ND ND ---ND
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND 5.4 J ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND 5.6 J ND ND ND ---ND
24-Feb-14 5.0 10.0 ND 6.4 J ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 4.1 J 5.4 J ND ND 3.1 J 3.2 J ---3.0 J
18-Aug-15 EPA 6011 2.5 10.0 ND 5.1 J ND ND ND ND ---ND
16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
9-Aug-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---5.1 J
13-Feb-17 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 1 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Barium 8-Sep-94 ---500 ND 270 ND ND 830 860 ------
1-Dec-94 ---500 ND ND ND ND ND ND ------
9-Feb-95 ---500 ND ND ND ND 510 ND ------
2-Mar-95 ---500 ND ND ND ND ND ND ------
15-Nov-95 ---500 ND ND ND ND ND ND ------
28-May-96 ---500 ND ND ND ND ND ND ------22-Nov-96 ---500 ND 82.0 30.0 ND 15.0 ND ------
17-Jun-97 ---500 200 320 37.0 17.0 210 31.0 ------
1-Dec-97 ---500 61.0 180 43.0 46.0 220 33.0 ------
20-May-98 ---500 30.0 150 45.0 13.0 180 22.0 ------
19-Nov-98 ---500 48.0 120 42.0 ND 380 12.0 ------
21-Jul-99 ---500 ND ND ND ND ND ND ------
16-Nov-99 ---500 ND ND ND ND ND ND ------10-May-00 ---500 ND ND ND ND ND ND ------
26-Oct-00 ---500 ND ND ND ND ND ND ------
18-Apr-01 ---500 ND ND ND ND ND ND ------
27-Oct-01 ---500 ND ND ND ND ND ND ------
13-Jun-02 ---500 ND ND ND ND ND ND ------
19-Nov-02 ---500 ND ND ND ND ND ND ------
27-Jun-03 ---500 ND ND ND ND ND ND ------30-Dec-03 ---500 ND ND ND ND ND ND ---ND
30-Jun-04 ---500 ND ND ND ND ND ND ---ND
29-Dec-04 ---500 ND ND ND ND ND ND ---ND29-Dec-04 ---500 ND ND ND ND ND ND ---ND
29-Jun-05 ---500 ND ND ND ND ND ND ---ND
29-Dec-05 ---500 ND ND ND ND ND ND ---ND
28-Jun-06 ---500 ND ND ND ND ND ND ---ND29-Dec-06 ---100 5.2 J 120 64.9 1.5 J 64.1 1.8 J ---0.20 J
12-Jul-07 ---100 2.5 J 129 65.7 J 1.1 J 77.0 J 1.3 J ---ND
NC 2L = 2,000 µg/L (10/23/07)19-Dec-07 ---100 2.8 B 99.2 50.0 B 1.4 B 49.6 B 1.7 B 87.8 11.7
8-Jul-08 ---100 5.8 J 102 58.4 J 1.1 B 57.9 J 1.2 B ---0.29 J
17-Dec-08 0.20 100 2.7 B 92.9 J 53.1 B 1.2 B 55.5 J 1.1 B ---10.7 J
9-Jul-09 0.20 100 4.6 B 121 63.4 B 0.37 B 81.4 B 0.94 B 72.4 B 17.6 J
16-Dec-09 0.20 100 2.9 B 108 62.8 B 0.61 B 56.8 B 0.87 B ---17.1 JNC 2L = 700 µg/L (02/05/10)24-Jun-10 0.20 100 2.5 B 115 B 61.1 B 1.6 B 93.5 B 1.4 B ---27.3 J
13-Dec-10 0.20 100 4.3 B 122 67.9 J 1.3 B 90.6 J 1.5 B ---12.1 J
20-Jun-11 5.0 100 ND 108 70.7 J ND 84.7 J ND ---ND
5-Dec-11 5.0 100 ND 118 73.0 J ND 90.6 J ND ---ND
11-Jun-12 5.0 100 ND 138 65.2 J ND 76.4 J ND 61.3 J ND
12-Dec-12 5.0 100 ND 113 64.7 J ND 73.6 J ND ---ND
1-May-13 5.0 100 ND 118 69.1 J ND 84.2 J ND 81.2 J ND5-Aug-13 5.0 100 ND 111 65.1 J ND 95.6 J ND ---ND
24-Feb-14 5.0 100 ND 93.8 J 44.8 J ND 139 ND ND ND
12-Aug-14 EPA 6010 5.0 100 ND 125 66.4 J ND 121 ND ---ND
10-Mar-15 EPA 6010 2.5 100 3.0 J 109 61.8 J ND 116 ND ---ND
18-Aug-15 EPA 6010 2.5 100 4.4 J 119 63.1 J ND 81.3 J ND ---ND
16-Feb-16 EPA 6010 2.5 100 5.2 J 123 72.7 J 3.0 J 126 ND ---ND
9-Aug-16 EPA 6010 2.5 100 4.5 J 123 73.3 J ND 109 ND ---ND13-Feb-17 EPA 6010 2.5 100 7.8 J 112 68.3 J ND 151 5.6 J ---ND
Beryllium 8-Sep-94 ---2 ND ND ND ND ND ND ------
1-Dec-94 ---2 ND ND ND ND 4.0 ND ------
9-Feb-95 ---2 ND ND ND ND ND ND ------
2-Mar-95 ---2 ND ND ND ND 2.0 ND ------
15-Nov-95 ---2 ND ND ND ND ND ND ------28-May-96 ---2 ND ND ND ND 6.0 ND ------
22-Nov-96 ---2 ND ND ND ND 3.0 ND ------
17-Jun-97 ---2 2.0 3.0 ND ND 1.0 ND ------
1-Dec-97 ---2 ND ND ND ND ND ND ------
20-May-98 ---2 ND ND ND ND ND ND ------
19-Nov-98 ---2 ND ND ND ND 2.0 ND ------
21-Jul-99 ---2 ND ND ND ND ND ND ------16-Nov-99 ---2 ND ND ND ND ND ND ------
10-May-00 ---2 ND ND ND ND ND ND ------
26-Oct-00 ---2 ND ND ND ND ND ND ------
18-Apr-01 ---2 ND 12.0 ND ND ND ND ------
27-Oct-01 ---2 ND ND ND ND ND ND ------13-Jun-02 ---2 ND ND ND ND ND ND ------
19-Nov-02 ---2 ND ND ND ND ND ND ------
27-Jun-03 ---2 ND ND ND ND ND ND ------
30-Dec-03 ---2 ND ND ND ND ND ND ---ND
30-Jun-04 ---2 ND ND ND ND ND ND ---ND
29-Dec-04 ---2 ND ND ND ND ND ND ---ND
29-Dec-04 ---2 ND ND ND ND ND ND ---ND
29-Jun-05 ---2 ND ND ND ND ND ND ---ND
29-Dec-05 ---2 ND ND ND ND ND ND ---ND
28-Jun-06 ---2 ND ND ND ND ND ND ---ND
29-Dec-06 ---1 ND ND ND ND ND ND ---ND
12-Jul-07 ---1 ND ND ND ND ND ND ---ND
GWPS = 4 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND
8-Jul-08 ---1 ND ND ND ND ND ND ---ND17-Dec-08 0.10 1.0 ND ND ND ND 0.14 J ND ---ND
9-Jul-09 0.10 1.0 ND 0.18 J 0.22 J 0.17 J ND ND 0.23 J ND
16-Dec-09 0.10 1.0 ND 0.15 J 0.17 J 0.15 J 0.25 J ND ---ND
NC 2B = 6.5 µg/L (02/05/10)24-Jun-10 0.10 1.0 ND ND 0.27 J 0.16 J ND ND ---ND
13-Dec-10 0.10 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND
1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
9-Aug-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 6010 0.5 1.0 ND ND ND ND 0.6 J ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cadmium 8-Sep-94 ---1 ND ND ND ND ND 4.0 ------
1-Dec-94 ---1 ND ND ND ND ND ND ------
9-Feb-95 ---1 ND ND ND ND ND ND ------
2-Mar-95 ---1 ND ND ND ND ND ND ------
15-Nov-95 ---1 ND ND ND ND ND ND ------
28-May-96 ---1 ND ND ND ND ND ND ------22-Nov-96 ---1 ND ND ND ND ND ND ------
17-Jun-97 ---1 ND 3.0 1.0 ND ND ND ------
1-Dec-97 ---1 ND 2.0 ND ND ND ND ------
20-May-98 ---1 ND ND ND ND ND ND ------
19-Nov-98 ---1 ND ND ND ND ND ND ------
21-Jul-99 ---1 ND ND ND ND ND ND ------
16-Nov-99 ---1 ND 3.0 3.0 ND 2.0 ND ------10-May-00 ---1 5.0 ND ND ND ND ND ------
26-Oct-00 ---1 ND 2.0 ND ND ND ND ------
18-Apr-01 ---1 ND 11.0 ND ND ND ND ------
27-Oct-01 ---1 ND ND ND ND ND ND ------
13-Jun-02 ---1 ND 2.0 ND ND ND ND ------
19-Nov-02 ---1 2.0 2.0 ND ND 2.0 ND ------
27-Jun-03 ---1 ND ND ND ND ND ND ------30-Dec-03 ---1 ND 1.0 ND ND ND ND ---ND
30-Jun-04 ---1 ND ND ND ND ND ND ---ND
29-Dec-04 ---1 ND ND ND ND ND ND ---ND29-Jun-05 ---1 ND ND ND ND ND ND ---ND
29-Dec-05 ---1 ND ND ND ND ND ND ---ND28-Jun-06 ---1 ND ND ND ND ND ND ---ND
29-Dec-06 ---1 ND ND ND ND ND ND ---ND12-Jul-07 ---1 ND ND ND ND ND ND ---ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND
8-Jul-08 ---1 ND ND ND ND ND ND ---ND
17-Dec-08 0.50 1.0 ND ND ND ND ND ND ---ND
9-Jul-09 0.50 1.0 ND 1.4 ND ND ND ND ND ND
16-Dec-09 0.50 1.0 ND ND ND ND ND ND ---ND
NC 2L = 2 µg/L (02/05/10)24-Jun-10 0.50 1.0 ND ND ND ND ND ND ---ND13-Dec-10 0.50 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 1.0 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 1.0 ND ND ND ND ND ND ---ND
1-May-13 1.0 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 1.0 1.0 ND ND ND ND ND ND ---ND24-Feb-14 1.0 1.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
9-Aug-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 6010 0.5 1.0 ND ND ND ND ND ND ---ND
Chromium 8-Sep-94 ---10 8.0 44.0 ND 6.0 48.0 80.0 ------
1-Dec-94 ---10 14.0 ND ND ND 18.0 ND ------
9-Feb-95 ---10 14.0 ND ND 10.0 ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 13.0 13.0 ND ND ND ND ------
28-May-96 ---10 33.0 ND ND ND ND ND ------22-Nov-96 ---10 3.0 ND ND ND ND 3.0 ------
17-Jun-97 ---10 57.0 43.0 ND 3.0 2.0 6.0 ------
1-Dec-97 ---10 29.0 ND ND ND ND ND ------
20-May-98 ---10 10.0 3.0 ND ND 12.0 ND ------
19-Nov-98 ---10 17.0 3.0 ND ND 5.0 ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND 12.0 ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 2.0 B ND ND ND ND 1.1 B 1.4 J
8-Jul-08 ---10 ND 0.54 J 0.58 J ND ND ND ---ND
17-Dec-08 0.40 10.0 0.73 J 1.8 J 0.96 J ND 0.96 J 0.70 J ---ND
9-Jul-09 0.40 10.0 1.2 J 2.4 J 1.1 J 1.6 J 0.68 J 0.53 J 4.8 J ND16-Dec-09 0.40 10.0 1.3 J ND ND ND 0.95 J ND ---ND
NC 2L = 10 µg/L (02/05/10)24-Jun-10 0.40 10.0 1.1 B 3.5 B 2.8 B 2.4 B 1.2 B 1.4 B ---0.71 J
13-Dec-10 0.40 10.0 2.5 J 1.3 J 1.8 J 0.69 J 0.57 J 1.2 J ---ND
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND 8.6 J ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND 5.2 J ND ND ND ND ---ND1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND
24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND 2.7 J ND ND ND 6.7 J ---ND
16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND9-Aug-16 EPA 6010 2.5 10.0 2.8 B 2.8 B ND ND ND ND ---2.9 J
13-Feb-17 EPA 6010 2.5 10.0 ND 2.6 J ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Cobalt 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 11.0 ND 13.0 16.0 22.0 ND ------
9-Feb-95 ---10 20.0 14.0 ND 48.0 39.0 ND ------
2-Mar-95 ---10 16.0 21.0 ND 29.0 121.0 ND ------
15-Nov-95 ---10 20.0 21.0 ND ND 27.0 ND ------
28-May-96 ---10 30.0 16.0 ND ND 122 ND ------22-Nov-96 ---10 6.0 13.0 ND 4.7 93.0 ND ------
17-Jun-97 ---10 130 38.0 ND 6.0 45.0 3.0 ------
1-Dec-97 ---10 32.0 21.0 ND 12.0 36.0 4.0 ------
20-May-98 ---10 15.0 16.0 2.0 9.0 100 3.0 ------
19-Nov-98 ---10 21.0 16.0 2.0 7.0 180 3.0 ------
21-Jul-99 ---10 ND 16.0 ND ND 100 ND ------
16-Nov-99 ---10 ND 15.0 ND ND 38.0 ND ------10-May-00 ---10 ND 17.0 ND ND 61.0 ND ------
26-Oct-00 ---10 ND 15.0 ND ND ND ND ------
18-Apr-01 ---10 ND 27.0 ND ND 74.0 ND ------
27-Oct-01 ---10 ND 12.0 ND ND 47.0 ND ------
13-Jun-02 ---10 ND 14.0 ND ND 251 ND ------
19-Nov-02 ---10 ND 10.0 ND ND 57.0 ND ------
27-Jun-03 ---10 ND 15.0 ND ND 75.0 ND ------30-Dec-03 ---10 ND 17.0 ND ND 52.0 ND ---ND
30-Jun-04 ---10 ND 16.0 ND ND 31.0 ND ---ND
29-Dec-04 ---10 ND 11.0 ND ND 46.0 ND ---ND29-Jun-05 ---10 ND 11.0 ND ND 43.0 ND ---ND
29-Dec-05 ---10 ND 12.0 ND ND 30.0 ND ---ND28-Jun-06 ---10 ND ND ND ND 72.5 ND ---ND
29-Dec-06 ---10 ND 11.4 ND ND 37.5 ND ---ND12-Jul-07 ---10 ND 11.8 ND 2.7 58.4 ND ---ND
GWPS = 70 µg/L (10/23/07)19-Dec-07 ---10 2.5 B ND ND 2.0 B 103 2.6 B 8.0 B 1.8 J
8-Jul-08 ---10 10.3 B 12.1 B 2.0 B 9.0 B 130 4.8 B ---6.2 J
17-Dec-08 0.60 10.0 2.1 B 11.8 B 2.3 B 3.6 B 43.7 1.6 B ---2.5 J
9-Jul-09 0.60 10.0 ND 6.2 J ND ND 100 ND 2.2 J ND
16-Dec-09 0.60 10.0 ND 4.7 J ND ND 6.6 J ND ---ND
24-Jun-10 0.60 10.0 ND 16.3 ND ND 25.0 ND ---NDGWPS = 1 µg/L (2/05/10)13-Dec-10 0.60 10.0 2.5 B 15.5 ND ND {129}{ND}---1.6 {1.0 J}J
20-Jun-11 5.0 10.0 ND 14.2 ND ND 81.8 ND ---ND
5-Dec-11 5.0 10.0 ND 12.7 ND ND 146 ND ---ND
Resample >25-Jan-12 5.0 10.0 ------------47.5 ------ND
11-Jun-12 5.0 10.0 ND 14.2 ND ND 101 ND ND ND
12-Dec-12 5.0 10.0 ND 11.3 ND ND 113 ND ---ND
1-May-13 5.0 10.0 ND 24.3 ND ND 34.0 ND ND ND5-Aug-13 5.0 10.0 ND 24.7 ND ND 50.9 ND ---ND
24-Feb-14 5.0 10.0 ND 18.4 ND ND 9.6 J ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND 9.4 J ND ND 46.3 ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND 8.7 J ND ND 39.2 ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND 9.3 J ND ND 116 ND ---ND
16-Feb-16 EPA 6010 2.5 10.0 ND 10.0 ND ND 13.1 ND ---ND
9-Aug-16 EPA 6010 2.5 10.0 ND 10.0 J ND ND 144 ND ---ND13-Feb-17 EPA 6010 2.5 10.0 ND 8.3 J ND ND 79 ND ---ND
Copper 8-Sep-94 ---200 ND ND ND ND ND 660 ------
1-Dec-94 ---200 ND ND ND ND ND ND ------
9-Feb-95 ---200 ND ND ND ND ND ND ------
2-Mar-95 ---200 ND ND ND ND ND ND ------
15-Nov-95 ---200 ND ND ND ND ND ND ------28-May-96 ---200 ND ND ND ND ND ND ------
22-Nov-96 ---200 ND ND 32.0 13.0 100 ND ------
17-Jun-97 ---200 34.0 350 13.0 37.0 28.0 77.0 ------
1-Dec-97 ---200 19.0 72.0 14.0 88.0 15.0 34.0 ------
20-May-98 ---200 12.0 48.0 380 41.0 53.0 28.0 ------
19-Nov-98 ---200 10.0 ND 410 28.0 53.0 14.0 ------
21-Jul-99 ---200 ND ND ND ND ND ND ------16-Nov-99 ---200 ND ND ND ND ND ND ------
10-May-00 ---200 ND ND ND ND ND ND ------
26-Oct-00 ---200 ND ND ND ND ND ND ------
18-Apr-01 ---200 ND ND ND ND ND ND ------
27-Oct-01 ---200 ND ND ND ND ND ND ------13-Jun-02 ---200 ND ND ND ND ND ND ------
19-Nov-02 ---200 ND ND ND ND ND ND ------
27-Jun-03 ---200 ND ND ND ND ND ND ------
30-Dec-03 ---200 ND ND ND ND ND ND ---ND
30-Jun-04 ---200 ND ND ND ND ND ND ---ND
29-Dec-04 ---200 ND ND ND ND ND ND ---ND
29-Jun-05 ---200 ND ND ND ND ND ND ---ND
29-Dec-05 ---200 ND ND ND ND ND ND ---ND
28-Jun-06 ---200 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND 11.3 5.50 J 10.4 1.90 B ---0.60 J
12-Jul-07 ---10 ND ND 13.4 7.90 2.6 J ND ---ND
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---10 2.0 B ND 8.6 B 3.8 B 7.0 B 0.73 B 5.8 B 9.8
8-Jul-08 ---10 0.64 J ND 12.1 3.7 J 8.5 J ND ---ND
17-Dec-08 0.30 10.0 0.80 J 13.6 10.2 3.9 J 11.9 0.37 J ---ND9-Jul-09 0.30 10.0 ND ND 6.3 J ND 5.7 J ND 8.8 J ND
16-Dec-09 0.30 10.0 ND ND 9.2 J 1.6 J 5.7 J ND ---ND
24-Jun-10 0.30 10.0 ND ND 10 1.2 J 5.1 J ND ---ND
13-Dec-10 0.30 10.0 1.1 B ND 13.6 5.8 J 5.6 J 0.59 B ---0.49 J
20-Jun-11 5.0 10.0 ND ND 15.3 8.1 J 8.7 J ND ---ND
5-Dec-11 5.0 10.0 ND ND 16.9 10.0 J 7.6 J ND ---ND
11-Jun-12 5.0 10.0 ND 10.7 12.2 6.3 J 7.4 J ND ND ND12-Dec-12 5.0 10.0 ND ND 11.6 8.5 J 10.4 ND ---ND
1-May-13 5.0 10.0 ND ND 13.6 5.8 J 9.6 J ND ND ND
5-Aug-13 5.0 10.0 ND ND 14.3 ND 10.2 ND ---ND24-Feb-14 5.0 10.0 ND ND 12.2 ND 5.1 J ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND 10.5 ND ND ND ---ND10-Mar-15 EPA 6010 2.5 10.0 ND ND 8.7 J ND 15.5 ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND ND 6.7 J 5.6 J 10.1 ND ---NDNC 2L = 50 µg/L (06/01/2016)16-Feb-16 EPA 6010 2.5 10.0 ND ND 7.8 J ND 5.1 J ND ---ND
9-Aug-16 EPA 6010 2.5 10.0 ND ND 5.4 J ND 7.8 J ND ---ND
13-Feb-17 EPA 6010 2.5 10.0 ND ND 6.8 J 4.3 J 14.5 9.4 J ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Lead 8-Sep-94 ---10 ND 13.0 ND ND 30.0 36.0 ------
1-Dec-94 ---10 11.0 ND ND ND 36.0 ND ------
9-Feb-95 ---10 ND ND ND 10.0 37.0 ND ------
2-Mar-95 ---10 ND ND ND ND 44.0 ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND 42.0 ND ------22-Nov-96 ---10 ND ND ND ND 13.0 ND ------
17-Jun-97 ---10 20.0 29.0 ND ND 13.0 ND ------
1-Dec-97 ---10 8.0 14.0 ND 5.0 14.0 ND ------
20-May-98 ---10 ND 6.0 ND 6.0 21.0 ND ------
19-Nov-98 ---10 5.0 ND ND ND 58.0 ND ------
21-Jul-99 ---10 ND 12.0 14.0 ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 11.0 ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND 12.0 ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND 2.1 J ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 15 µg/L (10/23/07)19-Dec-07 ---10 ND ND ND ND ND ND ND ND
8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 4.0 10.0 ND ND ND ND ND ND ---ND
9-Jul-09 4.0 10.0 ND ND ND ND ND ND ND ND
16-Dec-09 4.0 10.0 ND ND ND ND ND ND ---ND
24-Jun-10 4.0 10.0 ND ND ND ND ND ND ---ND13-Dec-10 4.0 10.0 ND ND ND ND ND ND ---ND
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
9-Aug-16 EPA 6010 2.5 10.0 ND 5.1 J ND ND ND ND ---ND
13-Feb-17 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Mercury 1-Dec-97 ---0.5 ND ND ND ND ND ND ------
19-Nov-98 ---0.5 ND ND ND ND ND ND ------
16-Nov-99 ---0.5 ND 0.59 0.65 0.65 0.76 ND ------
10-May-00 ---0.5 ---ND ND ND ND ---------
26-Oct-00 ---0.5 ---ND ND ND ND ---------
18-Apr-01 ---0.5 ---ND ND ND ND ---------13-Jun-02 ---0.5 ---ND ND ND ND ---------
27-Jun-03 ---0.5 ---ND ND ND ND ---------
30-Dec-03 ---0.5 ------------------------
30-Jun-04 ---0.5 ND ND ND ND ND ND ---ND
29-Dec-04 ------------------------------
29-Jun-05 ---0.5 ND ND ND ND ND ND ---ND
29-Dec-05 ------------------------------28-Jun-06 ---2 ND ND ND ND ND ND ---ND
29-Dec-06 ------------------------------
12-Jul-07 ---0.2 ND ND ND ND ND ND ---ND
NC 2L = 1.05 µg/L (10/23/07)19-Dec-07 ------------------------ND ---
8-Jul-08 ---0.2 ND ND ND ND ND ND ---ND17-Dec-08 ------------------------------
9-Jul-09 0.070 0.2 ND ND ND ND ND ND ---ND
16-Dec-09 ------------------------------
NC 2L = 1 µg/L (02/05/10)24-Jun-10 0.070 0.20 ND ND ND ND ND 0.098 J ---ND
13-Dec-10 ------------------------------
20-Jun-11 0.10 0.20 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------11-Jun-12 0.10 0.20 ND ND ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 0.10 0.20 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.10 0.20 ND ND ND ND ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 7470 0.10 0.20 ND ND ND ------------ND16-Feb-16 EPA 7470 0.10 0.20 ND ND ND ------------ND
13-Feb-17 EPA 7470 0.10 0.20 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Nickel 8-Sep-94 ---50 ND ND ND ND ND ND ------
1-Dec-94 ---50 ND ND ND ND ND ND ------
9-Feb-95 ---50 ND 72 ND ND ND ND ------
2-Mar-95 ---50 ND 100 ND ND ND ND ------
15-Nov-95 ---50 ND 61.0 ND ND ND ND ------
28-May-96 ---50 ND 85.0 ND ND ND ND ------22-Nov-96 ---50 ND 72.0 ND ND ND ND ------
17-Jun-97 ---50 75 98.0 ND ND ND ND ------
1-Dec-97 ---50 ND 89.0 ND ND ND ND ------
20-May-98 ---50 ND 91.0 ND ND ND ND ------
19-Nov-98 ---50 ND 83.0 ND ND ND ND ------
21-Jul-99 ---50 ND 109 ND ND ND ND ------
16-Nov-99 ---50 ND 122 ND ND ND ND ------10-May-00 ---50 ND 104 ND ND ND ND ------
26-Oct-00 ---50 ND 93.0 ND ND ND ND ------
18-Apr-01 ---50 ND 107 ND ND ND ND ------
27-Oct-01 ---50 ND 92.0 ND ND ND ND ------
13-Jun-02 ---50 ND 98.0 ND ND ND ND ------
19-Nov-02 ---50 ND 74.0 ND ND ND ND ------
27-Jun-03 ---50 ND 85.0 ND ND ND ND ------30-Dec-03 ---50 ND 100 ND ND ND ND ---ND
30-Jun-04 ---50 ND 120 (81.0)ND ND ND ND ---ND
29-Dec-04 ---50 ND 100 ND ND ND ND ---ND29-Jun-05 ---50 ND 150 (92.0)ND ND ND ND ---ND
29-Dec-05 ---50 ND 96.0 ND ND ND ND ---ND28-Jun-06 ---50 ND 88.7 ND ND ND ND ---ND
29-Dec-06 ---50 ND 94.7 30.1 14.2 8.9 J ND ---ND12-Jul-07 ---50 ND 99.0 30.6 J 13.9 J 13.7 J ND ---ND
NC 2L = 100 µg/L (10/23/07)19-Dec-07 ---50 ND 83.4 23.7 11.0 18.3 ND 11.4 ND
8-Jul-08 ---50 ND 76.0 28.1 J 11.5 J 27.0 J ND ---ND
17-Dec-08 1.7 50.0 ND 75.5 27.8 J 12.2 J 11.0 B ND ---2.4 J
9-Jul-09 1.7 50.0 2.2 J 93.5 29.4 J 11.7 J 23.2 J ND 13.1 J ND
16-Dec-09 1.7 50.0 ND 81.2 28.2 J 11.8 B 2.6 B ND ---3.0 J
24-Jun-10 1.7 50.0 ND 76.3 19.7 J 9.0 J 7.0 J 4.5 J ---ND13-Dec-10 1.7 50.0 ND 83.0 23.5 J 6.8 B 20.7 J ND ---2.7 J
20-Jun-11 5.0 50.0 ND 78.8 30.1 J 11.2 J 15.3 J ND ---ND
5-Dec-11 5.0 50.0 ND 89.1 32.8 J 11.7 J 24.3 J ND ---ND
11-Jun-12 5.0 50.0 ND 91.8 28.9 J 10.0 J 17.3 J ND ND ND
12-Dec-12 5.0 50.0 ND 91.8 29.2 J 9.3 J 21.1 J ND ---ND
1-May-13 5.0 50.0 ND 89.6 31.9 J 10.4 J 5.7 J ND ND ND
5-Aug-13 5.0 50.0 ND 87.9 28.1 J 9.0 J 8.4 J ND ---ND24-Feb-14 5.0 50.0 ND 83.1 16.7 J 10.4 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 50.0 ND 97.9 29 J 12.9 J 13.2 J ND ---ND
10-Mar-15 EPA 6010 2.5 50.0 ND 91.9 32.9 J 12.3 J 8.2 J ND ---ND
18-Aug-15 EPA 6010 2.5 50.0 ND 98.0 28.0 J 11.9 J 26.2 J 5.4 J ---ND
16-Feb-16 EPA 6010 2.5 50.0 ND 92.0 35.4 J 12.7 J 3.7 J ND ---ND
9-Aug-16 EPA 6010 2.5 50.0 3.3 J 88.9 29.0 J 12.2 J 30.7 J ND ---ND
13-Feb-17 EPA 6010 2.5 50.0 ND 89.6 30.4 J 13.5 J 16.2 J ND ---ND
Selenium 8-Sep-94 ---20 ND ND ND ND ND ND ------
1-Dec-94 ---20 ND ND ND ND ND ND ------
9-Feb-95 ---20 ND ND ND ND ND ND ------
2-Mar-95 ---20 ND ND ND ND ND ND ------
15-Nov-95 ---20 ND ND ND ND ND ND ------
28-May-96 ---20 ND ND ND ND ND ND ------22-Nov-96 ---20 ND ND ND ND ND ND ------
17-Jun-97 ---20 ND ND ND ND ND ND ------
1-Dec-97 ---20 ND ND ND ND ND ND ------
20-May-98 ---20 ND ND ND ND ND ND ------
19-Nov-98 ---20 ND ND ND ND ND ND ------
21-Jul-99 ---20 ND ND ND ND 36.0 ND ------
16-Nov-99 ---20 ND ND ND ND ND ND ------10-May-00 ---20 ND ND ND ND ND ND ------
26-Oct-00 ---20 ND ND ND ND ND ND ------
18-Apr-01 ---20 ND ND ND ND ND ND ------
27-Oct-01 ---20 ND ND ND ND ND ND ------
13-Jun-02 ---20 ND ND ND ND ND ND ------19-Nov-02 ---20 ND ND ND ND ND ND ------
27-Jun-03 ---20 ND ND ND ND ND ND ------
30-Dec-03 ---20 ND ND ND ND ND ND ---ND
30-Jun-04 ---20 ND ND ND ND ND ND ---ND
29-Dec-04 ---20 ND ND ND ND ND ND ---ND
29-Jun-05 ---20 ND ND ND ND ND ND ---ND
29-Dec-05 ---20 ND ND ND ND ND ND ---ND28-Jun-06 ---20 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---10 ND 11.5 ND ND ND ND ND ND
8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 3.8 10 4.8 B 5.1 B 4.8 B ND ND ND ---4.9 J
9-Jul-09 3.8 10 ND ND 4.2 J ND ND ND ND ND16-Dec-09 3.8 10 ND ND ND 5.1 J ND ND ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 3.8 10 ND ND ND ND ND ND ---ND
13-Dec-10 3.8 10 ND ND ND ND ND ND ---ND
20-Jun-11 10.0 10 ND ND ND ND ND ND ---ND
5-Dec-11 10.0 10 ND ND ND ND ND ND ---ND
11-Jun-12 10.0 10 ND ND ND ND ND ND ND ND
12-Dec-12 10.0 10 ND ND ND ND ND ND ---ND1-May-13 10.0 10 ND ND ND ND ND ND ND ND
5-Aug-13 10.0 10 ND ND ND ND ND ND ---ND
24-Feb-14 10.0 10 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 10.0 10 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND9-Aug-16 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 6010 5.0 10 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Silver 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 ND ND ND ND ND ND ------
9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND ND ND ND ND ND ------
1-Dec-97 ---10 ND 8.0 ND ND ND 3 ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND 15.0 ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---10 ND ND ND ND ND ND ---ND12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 17.5 µg/L (10/23/07)19-Dec-07 ---10 ND 0.57 J 0.60 J 0.55 J ND 0.33 J ND ND
8-Jul-08 ---10 ND 2.7 J 2.3 J 1.1 J 0.22 J 0.69 J ---0.12 J
17-Dec-08 0.10 10.0 0.13 J 1.8 J 1.4 J 0.85 J 0.12 J 0.51 J ---ND
9-Jul-09 0.10 10.0 ND 0.84 J 0.63 J 0.45 J ND 0.11 J ND ND
16-Dec-09 0.10 10.0 0.12 J 2.0 J 1.6 J 1.0 J 0.12 J 0.52 J ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 0.10 10.0 ND 0.38 J 0.33 J 0.35 J ND ND ---ND13-Dec-10 0.10 10.0 0.15 B 1.3 J 0.99 J 0.45 B {ND}{ND}---0.21 {0.19 J}J
20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 5.0 10.0 ND ND ND ND ND ND ---ND
11-Jun-12 5.0 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 5.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 5.0 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 5.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
9-Aug-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 6010 2.5 10.0 ND ND ND ND ND ND ---ND
Thallium 8-Sep-94 ---10 ND ND ND ND ND ND ------
1-Dec-94 ---10 ND ND ND ND ND ND ------
9-Feb-95 ---10 ND ND ND ND ND ND ------
2-Mar-95 ---10 ND ND ND ND ND ND ------
15-Nov-95 ---10 ND ND ND ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND 3.0 ND ND ND ND ------
1-Dec-97 ---10 ND ND ND ND ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND 10 J (ND)ND ND ND ND ---ND
29-Jun-05 ---10 ND 22.0 (30.0)13.0 (24.0)ND ND ND ---ND
29-Dec-05 ---10 ND 23.0 20.0 ND ND ND ---ND28-Jun-06 ---10 ND 25.7 12.6 ND ND ND ---ND
29-Dec-06 ---6 ND ND ND ND ND ND ---ND
12-Jul-07 ---5.5 ND ND ND ND ND ND ---ND
GWPS = 0.28 µg/L (10/23/07)19-Dec-07 ---5.5 ND 4.0 J ND ND ND ND ND ND
8-Jul-08 ---5.5 ND ND ND ND ND ND ---ND
17-Dec-08 3.0 5.5 ND 3.2 J 3.2 J ND ND ND ---ND
9-Jul-09 3.0 5.5 ND ND ND 4.1 J ND ND ND ND16-Dec-09 3.0 5.5 ND ND ND ND ND ND ---ND
24-Jun-10 3.0 5.5 ND ND 5.2 J 3.1 J ND ND ---ND
GWPS = 0.2 µg/L (10/1/10)13-Dec-10 3.0 5.5 ND ND 7.7 ND ND ND ---ND
20-Jun-11 5.4 5.5 ND ND ND ND ND ND ---ND
5-Dec-11 5.4 5.5 ND ND ND ND ND ND ---ND
11-Jun-12 5.4 5.5 ND ND ND ND ND ND ND ND
12-Dec-12 5.4 5.5 ND ND ND ND ND ND ---ND1-May-13 5.4 5.5 ND ND ND ND ND ND ND ND
5-Aug-13 5.4 5.5 ND ND ND ND ND ND ---ND
24-Feb-14 5.4 5.5 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
18-Aug-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND9-Aug-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 6020B 0.02 5.5 0.023 J 0.040 J ND ND 0.035 J ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Tin 1-Dec-97 ---100 ND ND ND ND ND ND ------
19-Nov-98 ---100 ND ND ND ND ND ND ------
16-Nov-99 ---100 ND ND ND ND ND ND ------
26-Oct-00 ---100 ---ND ND ND ND ---------
18-Apr-01 ---100 ---ND ND ND ND ---------
27-Oct-01 ---100 ------------------------13-Jun-02 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ------------------------
27-Jun-03 ---100 ND 149 127 ND ND ND ------
30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND
29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND
28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND 41.1 14.4 3.2 J ND ND ---ND
12-Jul-07 ---100 ND 35.2 J 13.9 J 5.2 J ND ND ---ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND 33.6 7.4 ND ND ND ND ND
8-Jul-08 ---100 4.4 J 28.6 J 15.1 J 5.4 J 3.0 J 3.6 J ---ND
17-Dec-08 1.8 100 ND 22.5 J 9.2 J ND ND ND ---ND9-Jul-09 1.8 100 ND 21.4 J 8.6 J ND ND ND ---ND
16-Dec-09 1.8 100 ND 26.3 J 10.7 J ND ND ND ---ND
GWPS = 2100 µg/L (02/05/10)24-Jun-10 1.8 100 ND 23.4 J 10.7 J 3.2 J 2.2 J 1.9 J ---ND
13-Dec-10 1.8 100 ND 30.3 J 12.1 J 5.8 J ND ND ---ND
20-Jun-11 5.0 100 ND 26.8 J 13.8 J ND ND ND ---ND
5-Dec-11 5.0 100 ND 25.8 J 13.9 J ND ND ND ---ND
11-Jun-12 5.0 100 ND 22.2 J 9.0 J ND ND ND ND ND12-Dec-12 5.0 100 ND 30.0 J 13.2 J ND ND ND ---ND
1-May-13 5.0 100 ND 25.8 J 12.2 J ND ND ND ---ND
5-Aug-13 5.0 100 ND 22.7 J 12.5 J ND ND ND ---ND
24-Feb-14 5.0 100 ND 26.7 J 11.7 J 9.8 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 100 ND 30.7 J 8.2 J ND ND ND ---ND
10-Mar-15 EPA 6010 2.5 100 ND 28.7 J 11.1 J ND ND ND ---ND
18-Aug-15 EPA 6010 2.5 100 ND 27.7 J 7.5 J ND ND ND ---ND16-Feb-16 EPA 6010 2.5 100 ND 28.6 J 10.4 J ------------ND
9-Aug-16 EPA 6010 2.5 100 ND 20.9 J 5.4 J ------------ND
13-Feb-17 EPA 6010 2.5 100 ND 25.5 B 7.8 B ------------3.6 J,
Vanadium 8-Sep-94 ---40 ND ND ND ND ND 130 ------
1-Dec-94 ---40 63.0 ND ND 45.0 ND ND ------
9-Feb-95 ---40 ND ND ND ND ND ND ------2-Mar-95 ---40 41.0 ND ND 45.0 ND ND ------
15-Nov-95 ---40 ND ND ND ND ND ND ------
28-May-96 ---40 83.0 ND ND ND ND ND ------
22-Nov-96 ---40 7.0 17 ND 21.0 ND ND ------
17-Jun-97 ---40 450 560 ND 19.0 ND ND ------
1-Dec-97 ---40 62.0 88.0 ND 41.0 ND 10.0 ------
20-May-98 ---40 25.0 15.0 ND 10.0 5.0 ND ------19-Nov-98 ---40 33.0 29.0 5.0 16.0 9.0 5.0 ------
21-Jul-99 ---40 ND ND ND ND ND ND ------
16-Nov-99 ---40 ND ND ND ND ND ND ------
10-May-00 ---40 ND ND ND ND ND ND ------
26-Oct-00 ---40 ND ND ND ND ND ND ------
18-Apr-01 ---40 ND ND ND ND ND ND ------
27-Oct-01 ---40 ND ND ND ND ND ND ------13-Jun-02 ---40 ND ND ND ND ND ND ------
19-Nov-02 ---40 ND ND ND ND ND ND ------
27-Jun-03 ---40 ND ND ND ND ND ND ------
30-Dec-03 ---40 ND ND ND ND ND ND ---ND
30-Jun-04 ---40 ND ND ND ND ND ND ---ND
29-Dec-04 ---40 ND ND ND ND ND ND ---ND
29-Jun-05 ---40 ND ND ND ND ND ND ---ND
29-Dec-05 ---40 ND ND ND ND ND ND ---ND
28-Jun-06 ---40 ND ND ND ND ND ND ---ND
29-Dec-06 ---25 2.7 J ND ND 14.5 ND 1.0 J ---ND
12-Jul-07 ---25 ND ND ND 19.4 J ND ND ---ND
GWPS = 3.5 µg/L (10/23/07)19-Dec-07 ---25 2.2 B 2.2 B ND 15.7 J 3.0 B 1.2 B 4.0 J 0.62 J8-Jul-08 ---25 2.6 J 2.4 J ND 14.6 J 1.4 J 1.2 J ---0.20 J
17-Dec-08 0.20 25.0 1.9 B 2.3 B ND 13.9 J 2.5 B 1.2 B ---0.76 J
9-Jul-09 0.20 25.0 3.9 B 9.7 J 2.5 B 18.4 J 2.9 B 2.2 B 8.5 J 1.30 J
16-Dec-09 0.20 25.0 2.0 B 4.4 J 1.3 B 14.0 J 2.2 B 1.5 B ---0.53 J
24-Jun-10 0.20 25.0 1.8 J 4.4 J 1.5 J 13.3 J 2.2 J 1.3 J ---ND
GWPS = 0.3 µg/L (10/1/10)13-Dec-10 0.20 25.0 3.2 J 3.6 J 0.35 B 16.6 J 1.8 B 1.0 B ---0.36 J
20-Jun-11 5.0 25.0 ND ND ND 14.5 J ND ND ---ND5-Dec-11 5.0 25.0 ND ND ND 13.5 J ND ND ---ND
11-Jun-12 5.0 25.0 ND 18.0 J ND 12.3 J ND ND ND ND
12-Dec-12 5.0 25.0 ND ND ND 13.6 J ND ND ---ND
1-May-13 5.0 25.0 ND ND ND 6.3 J ND ND ND ND
5-Aug-13 5.0 25.0 ND ND ND 10.2 J ND ND ---ND
24-Feb-14 5.0 25.0 ND ND ND 12.9 J ND ND ND ND
12-Aug-14 EPA 6010 5.0 25.0 ND ND ND 18.6 J ND ND ---ND10-Mar-15 EPA 6010 2.5 25.0 3.1 J 11.6 J 6.2 J 13.4 J ND ND ---ND
18-Aug-15 EPA 6010 2.5 25.0 3.4 J 6.8 J 3.6 J 19.6 J 2.8 J ND ---ND
16-Feb-16 EPA 6010 2.5 25.0 2.7 J 3.3 J ND 14.4 J ND ND ---ND
9-Aug-16 EPA 6010 2.5 25.0 2.5 J 3.5 J ND 21.2 J ND ND ---ND
13-Feb-17 EPA 6010 2.5 25.0 4.4 J 4.1 J ND 18.4 J 3.0 J 2.9 J ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 8 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Zinc 8-Sep-94 ---50 110 160 ND ND 320 430 ------
1-Dec-94 ---50 132 ND ND 70 164 ND ------
9-Feb-95 ---50 144 89 ND 91 79 74 ------
2-Mar-95 ---50 67 ND ND ND 111 ND ------
15-Nov-95 ---50 ND 50 ND ND ND ND ------
28-May-96 ---50 136 ND ND ND 122 ND ------22-Nov-96 ---50 79.0 48.0 28.0 ND 38.0 ND ------
17-Jun-97 ---50 370 410 33.0 39.0 36.0 69.0 ------
1-Dec-97 ---50 140 110 11.0 45.0 34.0 30.0 ------
20-May-98 ---50 70.0 63.0 23.0 31.0 47.0 34.0 ------
19-Nov-98 ---50 61.0 33.0 21.0 17.0 53.0 10.0 ------
21-Jul-99 ---50 ND ND ND ND ND ND ------
16-Nov-99 ---50 ND ND ND ND ND ND ------10-May-00 ---50 ND ND ND ND ND ND ------
26-Oct-00 ---50 ND ND ND ND ND ND ------
18-Apr-01 ---50 ND ND ND ND ND ND ------
27-Oct-01 ---50 ND ND ND ND ND ND ------
13-Jun-02 ---50 ND ND ND ND 382 ND ------
19-Nov-02 ---50 ND ND ND ND ND ND ------
27-Jun-03 ---50 ND ND ND ND ND ND ------30-Dec-03 ---50 ND ND ND ND ND ND ---ND
30-Jun-04 ---50 ND ND ND ND ND ND ---ND
29-Dec-04 ---50 ND ND ND 66.0 ND ND ---ND29-Jun-05 ---50 ND 54.0 56.0 ND ND ND ---ND
29-Dec-05 ---50 ND ND ND ND ND ND ---ND28-Jun-06 ---50 ND ND ND ND ND ND ---ND
29-Dec-06 ---50 8.0 J ND ND 4.1 J 4.3 J 4.1 J ---ND12-Jul-07 ---10 9.6 J ND ND ND ND ND ---ND
NC 2L = 1,050 µg/L (10/23/07)19-Dec-07 ---10 4.3 B 14.3 B 6.3 B ND ND ND 2.4 B 102
8-Jul-08 ---10 5.9 B ND ND ND 4.1 B ND ---1.2 J
17-Dec-08 0.40 10.0 2.4 B 6.3 J ND ND 4.6 J 0.60 B ---0.49 J
9-Jul-09 0.40 10.0 3.4 B ND ND ND ND ND 6.1 B 1.6 J
16-Dec-09 0.40 10.0 4.6 B ND ND ND 7.4 B ND ---7.7 J
NC 2L = 1,000 µg/L (02/05/10)24-Jun-10 0.40 10.0 0.58 J ND ND ND ND 1.3 J ---ND13-Dec-10 0.40 10.0 4.5 B ND ND ND ND ND ---6.7 J
20-Jun-11 10.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 10.0 10.0 ND ND ND ND ND ND ---12.4
11-Jun-12 10.0 10.0 ND 20.9 ND ND ND ND ND ND
12-Dec-12 10.0 10.0 ND ND ND ND ND ND ---ND
1-May-13 10.0 10.0 ND ND ND ND 11.8 ND 10.0 ND
5-Aug-13 10.0 10.0 ND ND ND ND ND ND ---ND24-Feb-14 10.0 10.0 ND ND ND ND ND ND ND ND
12-Aug-14 EPA 6010 10.0 10.0 ND ND ND ND 16.9 ND ---ND
18-Aug-15 EPA 6010 5.0 10.0 7.4 J ND ND ND 5.2 J ND ---ND
16-Feb-16 EPA 6010 5.0 10.0 14.5 16.7 17.8 46.1 5.9 J ND ---ND
9-Aug-16 EPA 6010 5.0 10.0 12.0 7.7 J ND ND ND ND ---ND
13-Feb-17 EPA 6010 5.0 10.0 12.3 ND ND ND 9.8 J 6.0 J ---ND
Cyanide 9-Jul-09 5.0 10 ND ND ND ND 46.9 ND ND ND
Resample >28-Sep-09 5.0 10 ------------ND ------ND
NC 2L = 70 µg/L (10/23/07)16-Dec-09 ------------------------------
24-Jun-10 5.0 10.0 ND ND ND ND ND ND ---ND
13-Dec-10 ------------------------------
Resample >20-Jun-11 5.0 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 5.0 10.0 ND 6.4 J ND ND 8.7 J ND ---ND
12-Dec-12 ------------------------------
1-May-13 5.0 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 5.0 10.0 ND ND ND ND ND ND ND 5.5 J
12-Aug-14 5.0 10.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 6010 5.0 10.0 9.5 B 7.5 B 8.5 B 8.8 B 11.8 B 6.6 B ---5.6 J
16-Feb-16 SM 4500-CN-E 4.0 10.0 ND ND ND ------------ND
13-Feb-17 SM 4500-CN-E 4.0 10.0 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 9 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
ORGANICS
Acetone 27-Oct-01 ---100 244 B 109 B ND 130 B 128 B 476 B ---479
13-Jun-02 ---100 ND ND ND ND ND ND ------
13-Jun-02 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND 4.5 J
8-Jul-08 ---100 ND ND ND ND ND ND ---ND
17-Dec-08 20.0 100 ND ND ND ND ND ND ---ND
9-Jul-09 20.0 100 ND ND ND ND ND ND ND ND
16-Dec-09 2.2 100 ND ND ND ND ND ND ---2.8 J
NC 2L = 6,000 µg/L (02/05/10)24-Jun-10 2.2 100 ND 18.5 B 6.5 B ND 2.2 B ND ---7.7 J13-Dec-10 2.2 100 ND ND ND ND ND ND ---ND
20-Jun-11 2.2 100 ND ND ND ND ND 2.4 B ---3.9 J
5-Dec-11 2.2 100 ND 2.3 B ND ND ND ND ---8.8 J
11-Jun-12 2.2 100 ND 3.5 B ND ND ND ND ND 4.7 J
12-Dec-12 10.0 100 ND ND ND ND ND ND ---ND1-May-13 10.0 100 ND ND ND ND ND ND ND 14.6 J
5-Aug-13 10.0 100 ND ND ND ND ND ND ---ND24-Feb-14 10.0 100 ND ND ND ND ND ND ND 25.7 J
*12-Aug-14 EPA 8260 10.0 100 ND ND ND ND ND ND ND 22.0 J
10-Mar-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND
16-Feb-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 10.0 100 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 10.0 100 ND ND ND ND ND ND ---ND
Benzene 8-Sep-94 ---5 ND ND ND ND ND ND ------
1-Dec-94 ---5 ND ND ND ND ND ND ------
9-Feb-95 ---5 ND ND ND ND ND ND ------
2-Mar-95 ---5 ND ND ND ND ND ND ------
15-Nov-95 ---5 ND ND ND ND ND ND ------
28-May-96 ---5 ND ND ND ND ND ND ------22-Nov-96 ---5 ND ND ND ND ND ND ------
17-Jun-97 ---5 ND ND ND ND ND ND ------
1-Dec-97 ---5 ND ND ND ND ND ND ------
20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---3 ND 1.5 ND ND ND ND ---ND
Resample >23-Feb-07 ---3 ---1.2 ---------------ND
12-Jul-07 ---1 ND 1.9 ND ND ND ND ---ND
NC 2L = 1 µg/L (10/23/07)19-Dec-07 ---1 ND 1.8 0.48 J 0.26 J ND ND ND ND
8-Jul-08 ---1 ND 1.4 0.51 J 0.32 J ND ND ---ND
17-Dec-08 0.25 1.0 ND 1.7 0.54 J ND ND ND ---ND9-Jul-09 0.25 1.0 ND 1.7 0.34 J ND ND ND ND ND
16-Dec-09 0.25 1.0 ND 1.7 0.60 J 0.29 J ND ND ---ND
24-Jun-10 0.25 1.0 ND 0.77 J 0.49 J 0.33 J ND ND ---ND
13-Dec-10 0.25 1.0 ND 1.8 0.59 J 0.37 J ND ND ---ND
Resample >8-Feb-11 0.25 1.0 ---1.4 ---------------ND
20-Jun-11 0.25 1.0 ND 1.7 0.60 J 0.39 J ND ND ---ND
5-Dec-11 0.25 1.0 ND 1.4 0.69 J 0.40 J ND ND ---ND11-Jun-12 0.25 1.0 ND ND 0.51 J ND ND ND ND ND
12-Dec-12 0.25 1.0 ND 1.6 0.73 J 0.32 J ND ND ---ND
Resample >10-Jan-13 0.25 1.0 ND 1.4 ------------ND ND1-May-13 0.25 1.0 ND 1.3 0.56 J 0.27 J ND ND ND ND
5-Aug-13 0.25 1.0 ND 1.6 0.64 J 0.44 J ND ND ---ND24-Feb-14 0.25 1.0 ND 1.4 ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.25 1.0 ND 1.7 0.61 J 0.25 J ND ND ND ND10-Mar-15 EPA 8260 0.25 1.0 ND 1.3 0.54 J ND ND ND ND ND
18-Aug-15 EPA 8260 0.25 1.0 ND 1.5 0.66 J 0.32 J ND ND ---ND
16-Feb-16 EPA 8260 0.25 1.0 ND 1.3 0.56 J ND ND ND ND ND9-Aug-16 EPA 8260 0.25 1.0 ND 1.4 0.53 J 0.29 J ND ND ND ND
13-Feb-17 EPA 8260 0.25 1.0 ND 1.2 0.61 J ND ND ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 10 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Bromomethane 17-Dec-08 0.29 10.0 ND ND 0.58 J ND ND ND ---ND
NC 2L = NE µg/L (10/23/07)9-Jul-09 0.29 10.0 ND ND ND ND ND ND ND ND
16-Dec-09 0.29 10.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.29 10.0 ND ND ND ND ND ND ---ND
GWPS = 10 µg/L (8/1/10)13-Dec-10 0.29 10.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.29 10.0 ND ND ND ND ND ND ---ND5-Dec-11 0.29 10.0 ND ND ND ND ND ND ND ND
11-Jun-12 0.29 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.29 10.0 ND ND ND ND ND ND ---ND
1-May-13 0.29 10.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.29 10.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.29 10.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.29 10.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.29 10.0 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.29 10.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.29 10.0 ND ND ND ND ND ND ---ND
2-Butanone (MEK)17-Dec-08 0.96 100 ND ND ND ND 1.2 J ND ---NDNC 2L = 4,200 µg/L (10/23/07)9-Jul-09 0.96 100 ND ND ND ND ND ND ND ND
16-Dec-09 0.96 100 ND ND ND ND ND ND ---ND
NC 2L = 4,000 µg/L (02/05/10)24-Jun-10 0.96 100 ND ND ND ND ND ND ---ND
13-Dec-10 0.96 100 ND ND ND ND ND ND ---ND
20-Jun-11 0.96 100 ND ND ND ND ND ND ---ND
5-Dec-11 0.96 100 ND ND ND ND ND ND ---ND
11-Jun-12 0.96 100 ND ND ND ND ND ND ND ND12-Dec-12 0.96 100 ND ND ND ND ND ND ---ND
1-May-13 0.96 100 ND ND ND ND ND ND ND ND
8-May-13 0.96 100 ND ND ND ND ND ND ---ND
24-Feb-14 0.96 100 ND ND ND ND ND ND ND ND
*12-Aug-14 0.96 100 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.96 100 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 0.96 100 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.96 100 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.96 100 ND ND ND ND ND ND ---ND
Carbon Disulfide 17-Jun-97 ---100 ND 64.0 ND ND ND ND ------
1-Dec-97 ---100 ND 5.0 8.0 ND ND ND ------
20-May-98 ---100 ND 7.5 6.2 ND ND ND ------19-Nov-98 ---100 ND ND ND ND ND ND ------
21-Jul-99 ---100 ND ND ND ND ND ND ------
16-Nov-99 ---100 ND ND ND ND ND ND ------
10-May-00 ---100 ND ND ND ND ND ND ------
26-Oct-00 ---100 ND ND ND ND ND ND ------
18-Apr-01 ---100 ND ND ND ND ND ND ------
27-Oct-01 ---100 ND ND ND ND ND ND ------13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------
30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND
29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND
28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND
12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND
8-Jul-08 ---100 ND ND ND ND ND ND ---ND
17-Dec-08 1.2 100 ND ND ND ND ND ND ---ND9-Jul-09 1.2 100 ND ND ND ND ND ND ND ND
16-Dec-09 1.2 100 ND ND ND ND ND ND ---ND
24-Jun-10 1.2 100 ND ND ND ND ND ND ---ND
13-Dec-10 1.2 100 ND ND ND ND ND ND ---ND
20-Jun-11 1.2 100 ND ND ND ND ND ND ---ND5-Dec-11 1.2 100 ND ND ND ND ND ND ---ND
11-Jun-12 1.2 100 ND ND ND ND ND ND ND ND
12-Dec-12 1.2 100 ND ND ND ND ND ND ---ND
1-May-13 1.2 100 ND ND ND ND ND ND ND ND
5-Aug-13 1.2 100 ND ND ND ND ND ND ---ND
24-Feb-14 1.2 100 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 1.2 100 ND ND ND ND ND ND ---ND16-Feb-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 1.2 100 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 1.2 100 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 11 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Chlorobenzene 8-Sep-94 ---5 ND 10.0 7.0 ND ND ND ------
1-Dec-94 ---5 ND ND 7.0 ND ND ND ------
9-Feb-95 ---5 ND 13.0 8.0 6.0 ND ND ------
2-Mar-95 ---5 ND 12.0 9.0 ND ND ND ------
15-Nov-95 ---5 ND 14.0 8.0 9.0 ND ND ------
28-May-96 ---5 ND 15.0 9.0 10.0 ND ND ------22-Nov-96 ---5 ND 15.0 ND 11.0 ND ND ------
17-Jun-97 ---5 ND 19.0 11.0 14.0 ND ND ------
1-Dec-97 ---5 ND 17.0 9.0 14.0 ND ND ------
20-May-98 ---5 ND 20.0 8.6 12.0 ND ND ------
19-Nov-98 ---5 ND 17.2 9.2 10.0 ND ND ------
21-Jul-99 ---5 ND 14.0 10.0 11.0 ND ND ------
16-Nov-99 ---5 ND 16.0 10.0 8.0 ND ND ------10-May-00 ---5 ND 17.0 11.0 10.0 ND ND ------
26-Oct-00 ---5 ND 16.0 12.0 9.0 ND ND ------
18-Apr-01 ---5 ND 16.0 13.0 6.0 ND ND ------
27-Oct-01 ---0.5 ND 17.0 12.0 9.0 ND ND ------
13-Jun-02 ---0.5 ND 16.0 11.0 8.0 ND ND ------
19-Nov-02 ---0.5 ND 18.0 15.0 9.0 ND ND ------
27-Jun-03 ---0.5 ND 17.7 13.3 7.4 ND ND ---ND30-Dec-03 ---5 ND 20.0 15.0 6.1 ND ND ---ND
30-Jun-04 ---5 ND 18.0 15.0 9.9 ND ND ---ND
29-Dec-04 ---5 ND 19.0 16.0 9.4 ND ND ---ND29-Jun-05 ---5 ND 15.0 13.0 8.0 ND ND ---ND
29-Dec-05 ---5 ND 18.0 16.0 5.0 ND ND ---ND28-Jun-06 ---5 ND 16.5 10.8 7.8 ND ND ---ND
29-Dec-06 ---3 ND 17.0 17.0 4.2 ND ND ---ND12-Jul-07 ---3 ND 17.0 16.0 ND ND ND ---ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 ---3 ND 17.3 16.9 4.7 ND ND ND ND
8-Jul-08 ---3 ND 17.2 17.4 6.5 ND ND ---ND
17-Dec-08 0.23 3.0 ND 15.9 15.6 2.6 J ND ND ---ND
9-Jul-09 0.23 3.0 ND 16.1 17.2 6.1 ND ND ND ND
16-Dec-09 0.23 3.0 ND 15.5 17.7 4.8 ND ND ---ND
24-Jun-10 0.23 3.0 ND 8.3 15.7 6.3 ND ND ---ND13-Dec-10 0.23 3.0 ND 17.7 18.2 6.4 ND ND ---0.28 J
20-Jun-11 0.23 3.0 ND 16.3 17.2 6.7 ND ND ---ND
5-Dec-11 0.23 3.0 ND 14.2 17.0 5.8 ND ND ---ND
11-Jun-12 0.23 3.0 ND 12 14.8 4.4 ND ND ND ND
12-Dec-12 0.23 3.0 ND 15.8 17.9 4.5 ND ND ---ND
1-May-13 0.23 3.0 ND 14.0 16.6 3.0 J ND ND ND ND
5-Aug-13 0.23 3.0 ND 14.4 15.9 4.6 ND ND ---ND24-Feb-14 0.23 3.0 ND 16.3 2.5 J 1.4 J ND ND ND ND
*12-Aug-14 EPA 8260 0.23 3.0 ND 15.6 18.3 3.6 ND ND ND ND
10-Mar-15 EPA 8260 0.23 3.0 ND 16.0 17.0 2.1 J ND ND ND ND
18-Aug-15 EPA 8260 0.23 3.0 ND 12.8 17.6 4.3 ND ND ---ND
16-Feb-16 EPA 8260 0.23 3.0 ND 13.5 16.4 1.5 J ND ND ND ND
9-Aug-16 EPA 8260 0.23 3.0 ND 13.5 16.9 4.2 ND ND ---ND
13-Feb-17 EPA 8260 0.23 3.0 ND 13.6 18.0 1.3 J ND ND ---ND
Chloroethane 1-Dec-97 ---10 ND 5.0 2.0 2.0 ND ND ------
20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------
27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND29-Dec-05 ---10 ND ND ND ND ND ND ---ND
28-Jun-06 ---10 ND ND ND ND ND ND ---ND29-Dec-06 ---10 ND 2.2 1.9 ND ND ND ---ND
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 2,800 µg/L (10/23/07)19-Dec-07 ---10 ND 1.9 1.9 1.5 ND ND ND ND
8-Jul-08 ---10 ND 2.2 J 2.5 J 1.8 J ND ND ---ND
17-Dec-08 0.54 10.0 ND 1.6 J ND ND ND ND ---ND
9-Jul-09 0.54 10.0 ND ND ND 3.8 J ND ND ND ND
16-Dec-09 0.54 10.0 ND ND 2.2 J 2.0 J ND ND ---NDNC 2L = 3,000 µg/L (02/05/10)24-Jun-10 0.54 10.0 ND ND 2.1 J 2.0 J ND ND ---ND
13-Dec-10 0.54 10.0 ND 1.8 J 2.0 J 1.7 J ND ND ---ND
20-Jun-11 0.54 10.0 ND 1.2 J 2.2 J 2.0 J ND ND ---ND
5-Dec-11 0.54 10.0 ND 1.3 J 2.0 J 1.7 J ND ND ---ND
11-Jun-12 0.54 10.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.54 10.0 ND ND ND ND ND ND ---ND
1-May-13 0.54 10.0 ND ND 1.9 J 2.7 J ND ND ND ND5-Aug-13 0.54 10.0 ND ND 2.0 J 2.2 J ND ND ---ND
24-Feb-14 0.54 10.0 ND 1.1 J 0.82 J ND ND ND ND ND
*12-Aug-14 EPA 8260 0.54 10.0 ND 1.1 J 1.50 J 1.1 J ND ND ND ND
10-Mar-15 EPA 8260 0.54 10.0 ND 1.0 J 1.80 J 0.81 J ND ND ND ND
18-Aug-15 EPA 8260 0.54 10.0 ND 1.2 J 2.0 J 3.7 J ND ND ---ND
16-Feb-16 EPA 8260 0.54 10.0 ND 1.1 J 1.8 J 0.79 J ND ND ND ND
9-Aug-16 EPA 8260 0.54 10.0 ND 0.68 J 2.4 J 1.5 J ND ND ---ND13-Feb-17 EPA 8260 0.54 10.0 ND 0.76 J 1.6 J 1.1 J ND ND ---ND
Chloromethane 9-Jul-09 0.11 1.0 ND ND ND ND ND ND ND ND
NC 2L = 2.6 µg/L (10/23/07)16-Dec-09 0.11 1.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.11 1.0 ND ND ND ND ND 0.11 J ---ND
NC 2L = 3 µg/L (02/05/10)13-Dec-10 0.11 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.11 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.11 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.11 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.11 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.11 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.11 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.11 1.0 ND ND ND ND ND ND ND 0.25 J
12-Aug-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.11 1.0 0.20 B ND 0.22 B 0.23 B 0.19 B 0.32 B ---0.18 J
Granville County
Butner Landfill, Permit No. 39-02 Page 12 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,2-Dichlorobenzene 1-Dec-97 ---5 ND 3.0 2.0 1.0 ND ND ------
20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND 2.4 2.3 ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND 1.5 2.3 ND ND ND ---ND
12-Jul-07 ---5 ND 1.4 J 1.7 J 0.31 J ND ND ---NDNC 2L = 24 µg/L (10/23/07)19-Dec-07 ---5 ND 1.6 2.0 0.37 J ND ND ND ND
8-Jul-08 ---5 ND 1.6 J 2.0 J 0.39 J ND ND ---ND
17-Dec-08 0.30 5.0 ND 1.4 J 1.9 J ND ND ND ---ND
9-Jul-09 0.30 5.0 ND 1.6 J 2.0 J 0.36 J ND ND ND ND
16-Dec-09 0.30 5.0 ND 1.6 J 2.0 J 0.33 J ND ND ---ND
NC 2L = 20 µg/L (02/05/10)24-Jun-10 0.30 5.0 ND 0.96 J 1.7 J 0.31 J ND ND ---ND
13-Dec-10 0.30 5.0 ND 1.9 J 1.9 J 0.43 J ND ND ---ND20-Jun-11 0.30 5.0 ND 1.5 J 1.7 J 0.37 J ND ND ---ND
5-Dec-11 0.30 5.0 ND 1.3 J 1.6 J ND ND ND ---ND
11-Jun-12 0.30 5.0 ND 1.0 J 1.5 J ND ND ND ND ND
12-Dec-12 0.30 5.0 ND 1.3 J 1.7 J ND ND ND ---ND
1-May-13 0.30 5.0 ND 1.2 J 1.6 J ND ND ND ND ND
5-Aug-13 0.30 5.0 ND 1.2 J 1.6 J 0.30 J ND ND ---ND
24-Feb-14 0.30 5.0 ND 1.4 J 0.64 J ND ND ND ND ND*12-Aug-14 EPA 8260 0.30 5.0 ND 1.2 J 1.5 J ND ND ND ND ND
10-Mar-15 EPA 8260 0.30 5.0 ND 1.1 J 1.1 J ND ND ND ND ND
18-Aug-15 EPA 8260 0.30 5.0 ND 0.88 J 1.3 J ND ND ND ---ND
16-Feb-16 EPA 8260 0.30 5.0 ND 1.1 J 1.4 J ND ND ND ND ND
9-Aug-16 EPA 8260 0.30 5.0 ND 1.2 J 1.4 J ND ND ND ---ND
13-Feb-17 EPA 8260 0.30 5.0 ND 1.2 J 1.4 J ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 13 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,4-Dichlorobenzene 8-Sep-94 ---5 ND ND 5.0 ND ND ND ------
1-Dec-94 ---5 ND ND 5.0 ND ND ND ------
9-Feb-95 ---5 ND 8.0 6.0 ND ND ND ------
2-Mar-95 ---5 ND 7.0 6.0 ND ND ND ------
15-Nov-95 ---5 ND 7.0 6.0 ND ND ND ------
28-May-96 ---5 ND ND ND ND ND ND ------22-Nov-96 ---5 ND ND ND ND ND ND ------
17-Jun-97 ---5 ND 7.6 6.2 ND ND ND ------
1-Dec-97 ---5 ND 6.0 5.0 4.0 ND ND ------
20-May-98 ---5 ND 7.6 ND ND ND ND ------
19-Nov-98 ---5 ND 3.7 2.8 ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND 5.0 6.0 ND ND ND ------
18-Apr-01 ---5 ND ND 5.0 6.0 ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---3 ND 3.0 3.3 ND ND ND ---ND
Resample >23-Feb-07 ---3 ---3.2 3.3 ------------ND
12-Jul-07 ---1 ND 3.3 2.9 0.31 J ND ND ---ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ---1 ND 3.0 2.7 ND ND ND ND ND
8-Jul-08 ---1 ND 3.0 2.4 ND ND ND ---ND
17-Dec-08 0.33 1.0 ND 2.9 2.5 ND ND ND ---ND
9-Jul-09 0.33 1.0 ND ND ND ND ND ND ND ND
16-Dec-09 0.33 1.0 ND 2.8 2.2 ND ND ND ---NDNC 2L = 6 µg/L (02/05/10)24-Jun-10 0.33 1.0 ND 1.6 ND ND ND ND ---ND
13-Dec-10 0.33 1.0 ND 3.1 1.9 ND ND ND ---ND
20-Jun-11 0.33 1.0 ND 2.7 1.6 ND ND ND ---ND
5-Dec-11 0.33 1.0 ND 2.2 1.4 ND ND ND ---ND
11-Jun-12 0.33 1.0 ND 1.8 1.4 ND ND ND ND ND
12-Dec-12 0.33 1.0 ND 2.4 1.3 ND ND ND ---ND
1-May-13 0.33 1.0 ND 2.1 1.2 ND ND ND ND ND5-Aug-13 0.33 1.0 ND 2.0 1.3 ND ND ND ---ND
24-Feb-14 0.33 1.0 ND 2.2 1.8 ND ND ND ND ND
*12-Aug-14 EPA 8260 0.33 1.0 ND 2.4 1.3 ND ND ND ND ND
10-Mar-15 EPA 8260 0.33 1.0 ND 2.2 1.1 ND ND ND ND ND
18-Aug-15 EPA 8260 0.33 1.0 ND 1.5 1.1 ND ND ND ---ND
16-Feb-16 EPA 8260 0.33 1.0 ND 2.0 1.0 ND ND ND ND ND
9-Aug-16 EPA 8260 0.33 1.0 ND 1.9 1.0 ND ND ND ---ND13-Feb-17 EPA 8260 0.33 1.0 ND 1.9 0.90 J ND ND ND ---ND
Trans-1,4-Dichloro-2-Butene 20-May-98 ---100 ND ND 5.1 ND ND ND ------
19-Nov-98 ---100 ND ND ND ND ND ND ------
21-Jul-99 ---100 ND ND ND ND ND ND ------
16-Nov-99 ---100 ND ND ND ND ND ND ------
10-May-00 ---100 ND ND ND ND ND ND ------26-Oct-00 ---100 ND ND ND ND ND ND ------
18-Apr-01 ---100 ND ND ND ND ND ND ------
27-Oct-01 ---100 ND ND ND ND ND ND ------
19-Nov-02 ---100 ND ND ND ND ND ND ------
27-Jun-03 ---100 ND ND ND ND ND ND ------
30-Dec-03 ---100 ND ND ND ND ND ND ---ND
30-Jun-04 ---100 ND ND ND ND ND ND ---ND
29-Dec-04 ---100 ND ND ND ND ND ND ---ND
29-Jun-05 ---100 ND ND ND ND ND ND ---ND
29-Dec-05 ---100 ND ND ND ND ND ND ---ND28-Jun-06 ---100 ND ND ND ND ND ND ---ND
29-Dec-06 ---100 ND ND ND ND ND ND ---ND12-Jul-07 ---100 ND ND ND ND ND ND ---ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 ---100 ND ND ND ND ND ND ND ND
8-Jul-08 ---100 ND ND ND ND ND ND ---ND
17-Dec-08 1.0 100 ND ND ND ND ND ND ---ND
9-Jul-09 1.0 100 ND ND ND ND ND ND ND ND
16-Dec-09 1.0 100 ND ND ND ND ND ND ---ND
24-Jun-10 1.0 100 ND ND ND ND ND ND ---ND13-Dec-10 1.0 100 ND ND ND ND ND ND ---ND
20-Jun-11 1.0 100 ND ND ND ND ND ND ---ND
5-Dec-11 1.0 100 ND ND ND ND ND ND ---ND
11-Jun-12 1.0 100 ND ND ND ND ND ND ND ND
12-Dec-12 1.0 100 ND ND ND ND ND ND ---ND
1-May-13 1.0 100 ND ND ND ND ND ND ND ND
5-Aug-13 1.0 100 ND ND ND ND ND ND ---ND24-Feb-14 1.0 100 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 1.0 100 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 1.0 100 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 1.0 100 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 1.0 100 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 14 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
1,1-Dichloroethane 1-Dec-97 ---5 ND ND 1.0 ND ND ND ------
20-May-98 ---5 ND ND ND ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------
21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ------
30-Dec-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND29-Dec-05 ---5 ND ND ND ND ND ND ---ND
28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND ND ND ND ND ND ---ND
12-Jul-07 ---5 ND ND 0.36 J 0.52 J ND ND ---NDNC 2L = 70 µg/L (10/23/07)19-Dec-07 ---5 ND ND ND 0.57 J ND ND ND ND
8-Jul-08 ---5 ND ND ND 0.60 J ND ND ---ND
17-Dec-08 0.32 5.0 ND ND ND 0.51 J ND ND ---ND
9-Jul-09 0.32 5.0 ND ND ND 0.84 J ND ND ND ND
16-Dec-09 0.32 5.0 ND ND ND 0.73 J ND ND ---ND
NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.32 5.0 ND ND ND 0.53 J ND ND ---ND
13-Dec-10 0.32 5.0 ND ND ND 0.60 J ND ND ---ND20-Jun-11 0.32 5.0 ND ND ND 0.63 J ND ND ---ND
5-Dec-11 0.32 5.0 ND ND ND 0.67 J ND ND ---ND
11-Jun-12 0.32 5.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.32 5.0 ND ND ND 0.61 J ND ND ---ND
1-May-13 0.32 5.0 ND ND ND 0.62 J ND ND ND ND
8-May-13 0.32 5.0 ND ND ND 0.53 J ND ND ---ND
24-Feb-14 0.32 5.0 ND ND ND 0.50 J ND ND ND ND*12-Aug-14 EPA 8260 0.32 5.0 ND ND ND 0.47 J ND ND ND ND
10-Mar-15 EPA 8260 0.32 5.0 ND ND ND 0.50 J ND ND ND ND
18-Aug-15 EPA 8260 0.32 5.0 ND ND ND 0.49 J ND ND ---ND
16-Feb-16 EPA 8260 0.32 5.0 ND ND ND 0.45 J ND ND ND ND
9-Aug-16 EPA 8260 0.32 5.0 ND ND ND 0.34 J ND ND ---ND
13-Feb-17 EPA 8260 0.32 5.0 ND ND ND 0.33 J ND ND ---ND
1,2-Dichloroethane 17-Dec-08 0.12 1.0 ND ND 0.15 J ND ND ND ---ND
NC 2L = 0.38 µg/L (10/23/07)9-Jul-09 0.12 1.0 ND ND ND ND ND ND ND 0.19 J
16-Dec-09 0.12 1.0 ND ND 0.14 J ND ND ND ---ND
NC 2L = 0.4 µg/L (02/05/10)24-Jun-10 0.12 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.12 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.12 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.12 1.0 ND ND ND ND 0.18 J ND ---ND11-Jun-12 0.12 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.12 1.0 ND ND ND ND -0.20 J ND ---0.20 (ND)J
1-May-13 0.12 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.12 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.12 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.12 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.24 1.0 ND ND 0.33 J 0.29 J 0.36 J ND ------
16-Feb-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.24 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.24 1.0 ND ND ND ND ND ND ---ND
Ethylbenzene 17-Dec-08 0.30 1.0 ND 0.31 J ND ND ND ND ---ND
NC 2L = 550 µg/L (10/23/07)9-Jul-09 0.30 1.0 ND ND ND ND ND ND ND ND16-Dec-09 0.30 1.0 ND ND ND ND ND ND ---ND
NC 2L = 600 µg/L (02/05/10)24-Jun-10 0.30 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.30 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.30 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.30 1.0 ND ND ND ND ND ND ---ND11-Jun-12 0.30 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.30 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.30 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.30 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.30 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND18-Aug-15 EPA 8260 0.30 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.30 1.0 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.30 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.30 1.0 ND ND ND ND ND ND ---ND
Isobutanol 24-Jun-10 35.0 100 ND 59.0 J ND ND ND ND ---ND
NC 2L = NE µg/L (02/05/10)13-Dec-10 ------------------------------20-Jun-11 35.0 100 ND 39.5 J ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 35.0 100.0 ND ND ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 35.0 100 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 35.0 100 ND ND ND ND ND ND ---ND*12-Aug-14 35.0 100 ND ND ND ND ND ND ---ND
10-Mar-15 EPA 8260 35.0 100 ND ND ND ------------ND
16-Feb-16 EPA 8260 35.0 100 ND 42.5 J ND ------------ND
13-Feb-17 EPA 8260 35.0 100 ND ND ND ------------ND
Methylene Chloride 9-Jul-09 0.97 2.0 ND ND ND ND ND ND ND 9.6
NC 2L = 4.3 µg/L (10/23/07)16-Dec-09 0.97 2.0 ND ND ND ND ND ND ---ND24-Jun-10 0.97 1.0 ND 19.0 ND ND ND ND ---ND
NC 2L = 5 µg/L (02/05/10) Resample >12-Aug-10 0.97 1.0 ---ND ---------------ND
13-Dec-10 0.97 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.97 1.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.97 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.97 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.97 1.0 ND ND ND ND ND ND ---ND1-May-13 0.97 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.97 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.97 1.0 1.0 ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.97 1.0 1.3 1.1 1.6 ND ND ND ND ND
16-Feb-16 EPA 8260 0.97 1.0 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 0.97 1.0 ND ND 1.0 B ND ND ND ---2.2 B
13-Feb-17 EPA 8260 0.97 1.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 15 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Naphthalene 8-Jul-08 ---10 ND 3.8 J ND ND ND ND ---ND
NC 2L = 21 µg/L (10/23/07)17-Dec-08 ------------------------------
9-Jul-09 0.24 10.0 ND 2.4 J ND ND ND ND ---ND
16-Dec-09 ------------------------------
NC 2L = 6 µg/L (02/05/10)24-Jun-10 0.24 10.0 ND 7.4 J ND ND ND ND ---ND
13-Dec-10 ------------------------------20-Jun-11 0.24 10.0 ND 4.6 J ND ND ND ND ---0.39 J
5-Dec-11 --------- ---------------------
11-Jun-12 0.2 10.0 ND 4.6 J ND ND ND ND ND ND
12-Dec-12 ------------------------------
1-May-13 0.24 10.0 ND 5.1 J ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.24 10.0 ND 5.8 J ND ND ND ND ---ND*12-Aug-14 ------------------------------
10-Mar-15 EPA 8260 0.2 10 ND 5.4 J ND ------------ND
16-Feb-16 EPA 8260 0.2 10 ND 5.7 J ND ------------ND
13-Feb-17 EPA 8260 0.2 10 ND 6.1 J ND ------------ND
Toluene 20-May-98 ---5 ND ND 8.1 ND ND ND ------
19-Nov-98 ---5 ND ND ND ND ND ND ------21-Jul-99 ---5 ND ND ND ND ND ND ------
16-Nov-99 ---5 ND ND ND ND ND ND ------
10-May-00 ---5 ND ND ND ND ND ND ------
26-Oct-00 ---5 ND ND ND ND ND ND ------
18-Apr-01 ---5 ND ND ND ND ND ND ------
27-Oct-01 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---5 ND ND ND ND ND ND ------19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ----
30-Dec-03 ---5 ND ND ND ND ND ND ---ND
30-Jun-04 ---5 ND ND ND ND ND ND ---ND
29-Dec-04 ---5 ND ND ND ND ND ND ---ND
29-Jun-05 ---5 ND ND ND ND ND ND ---ND
29-Dec-05 ---5 ND ND ND ND ND ND ---ND28-Jun-06 ---5 ND ND ND ND ND ND ---ND
29-Dec-06 ---5 ND ND ND ND ND ND ---ND
12-Jul-07 ---1 ND 0.49 B ND ND ND ND ---0.34 J
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 ---1 ND 0.51 J ND ND ND ND ND ND
8-Jul-08 ---1 ND 0.39 J ND ND 1.3 ND ---ND
17-Dec-08 0.26 1.0 1.4 1.6 ND ND 11.7 ND ---ND
9-Jul-09 0.26 1.0 ND 0.46 J ND ND ND ND ND ND16-Dec-09 0.26 1.0 ND 0.42 J ND ND ND ND ---ND
NC 2L = 600 µg/L (02/05/10)24-Jun-10 0.26 1.0 ND ND ND ND ND ND ---ND
13-Dec-10 0.26 1.0 ND 0.54 J ND ND ND ND ---ND
20-Jun-11 0.26 1.0 ND 0.34 J ND ND ND ND ---ND
5-Dec-11 0.26 1.0 ND 0.28 J ND ND 0.30 J ND ---ND
11-Jun-12 0.26 1.0 ND 0.28 J ND ND ND ND ND ND
12-Dec-12 0.26 1.0 ND 0.29 J ND ND 0.36 J ND ---ND1-May-13 0.26 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.26 1.0 ND 0.29 J ND ND ND ND ---ND
24-Feb-14 0.26 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.26 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.26 1.0 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 0.26 1.0 ND 0.33 J ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.26 1.0 ND ND ND ND ND ND ---ND
Vinyl Chloride 8-Sep-94 ---10 ND ND 12.0 ND ND ND ------
1-Dec-94 ---10 ND ND 13.0 ND ND ND ------
9-Feb-95 ---10 ND ND 15.0 ND ND ND ------
2-Mar-95 ---10 ND ND 14.0 ND ND ND ------15-Nov-95 ---10 ND ND 11.0 ND ND ND ------
28-May-96 ---10 ND ND ND ND ND ND ------
22-Nov-96 ---10 ND ND ND ND ND ND ------
17-Jun-97 ---10 ND ND ND ND ND ND ------
1-Dec-97 ---10 ND ND 7.0 4.0 ND ND ------20-May-98 ---10 ND ND ND ND ND ND ------
19-Nov-98 ---10 ND ND ND ND ND ND ------
21-Jul-99 ---10 ND ND ND ND ND ND ------
16-Nov-99 ---10 ND ND ND ND ND ND ------
10-May-00 ---10 ND ND ND ND ND ND ------
26-Oct-00 ---10 ND ND ND ND ND ND ------
18-Apr-01 ---10 ND ND ND ND ND ND ------27-Oct-01 ---10 ND ND ND ND ND ND ------
13-Jun-02 ---10 ND ND ND ND ND ND ------
19-Nov-02 ---10 ND ND ND ND ND ND ------
27-Jun-03 ---10 ND ND ND ND ND ND ------
30-Dec-03 ---10 ND ND ND ND ND ND ---ND
30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Dec-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ---10 ND ND ND ND ND ND ---ND
28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ---5.5 ND ND 0.98 J ND ND ND ---ND
Resample >23-Feb-07 ---5.5 ------1.0 ------------ND
12-Jul-07 ---1 ND ND ND ND ND ND ---ND
NC 2L = 0.015 µg/L (10/23/07)19-Dec-07 ---1 ND ND ND ND ND ND ND ND8-Jul-08 ---1 ND ND 0.76 J ND ND ND ---ND
17-Dec-08 0.62 1.0 ND ND 0.76 J ND ND ND ---ND
9-Jul-09 0.62 1.0 ND ND 0.99 J ND ND ND ND ND
16-Dec-09 0.62 1.0 ND ND 0.81 J ND ND ND ---ND
NC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.62 1.0 ND ND 0.77 J ND ND ND ---ND
13-Dec-10 0.62 1.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.62 1.0 ND ND ND ND ND ND ---ND5-Dec-11 0.62 1.0 ND ND ND ND ND ND ---ND
11-Jun-12 0.62 1.0 ND ND ND ND ND ND ND ND
12-Dec-12 0.62 1.0 ND ND ND ND ND ND ---ND
1-May-13 0.62 1.0 ND ND ND ND ND ND ND ND
5-Aug-13 0.62 1.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.62 1.0 ND ND ND ND ND ND ND ND
*12-Aug-14 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND10-Mar-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.62 1.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.62 1.0 ND ND ND ND ND ND ND ND
9-Aug-16 EPA 8260 0.62 1.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.62 1.0 ND ND ND ND ND ND ---ND
Granville County
Butner Landfill, Permit No. 39-02 Page 16 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Xylene (Total)29-Dec-06 ---5 ND 1.4 ND ND ND ND ---ND
12-Jul-07 ---4 ND 1.2 J ND ND ND ND ---ND
NC 2L = 530 µg/L (10/23/07)19-Dec-07 ---4 ND 2.0 ND ND ND ND ND ND
8-Jul-08 ---4 ND 1.1 J ND ND ND ND ---ND
17-Dec-08 0.66 2.0 1.4 J 2.7 ND ND ND ND ---ND
9-Jul-09 0.66 2.0 ND 1.5 J ND ND ND ND ND ND16-Dec-09 0.66 2.0 ND 2.2 ND ND ND ND ---ND
NC 2L = 500 µg/L (02/05/10)24-Jun-10 0.66 2.0 ND 0.73 J ND ND ND ND ---ND
13-Dec-10 0.66 2.0 ND 2.0 ND ND ND ND ---ND
20-Jun-11 0.66 2.0 ND 1.4 J ND ND ND ND ---ND
5-Dec-11 0.66 2.0 ND 1.1 J ND ND ND ND ---ND
11-Jun-12 0.66 2.0 ND 0.91 J ND ND ND ND ND ND
12-Dec-12 0.66 5.0 ND 0.97 J ND ND ND ND ---ND1-May-13 0.66 5.0 ND 0.68 J ND ND ND ND ND ND
5-Aug-13 0.66 5.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.66 5.0 ND ND ND ND ND ND ND ND
*12-Aug-14 0.66 5.0 ND ND ND ND ND ND ND ND
10-Mar-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ND ND
18-Aug-15 EPA 8260 0.66 5.0 ND ND ND ND ND ND ---ND
16-Feb-16 EPA 8260 0.66 5.0 ND ND ND ND ND ND ND ND9-Aug-16 EPA 8260 0.66 5.0 ND ND ND ND ND ND ---ND
13-Feb-17 EPA 8260 0.66 5.0 ND ND ND ND ND ND ---ND
Bis(2-Ethylhexyl)phthalate 24-Feb-14 0.79 15.0 2.6 J ND ND ND ND ND ND ND
NC 2L = 3 µg/L (2/5/10)15-Apr-14 0.79 15.0 ND ND ND ND ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 15 ND ND ND ------------ND16-Feb-16 EPA 8270 0.9 15 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.9 15 ND ND ND ------------ND
N-Nitroso-di-n-butylamine 24-Feb-14 7.5 10.0 ND ND ND 8.6 J ND ND ND ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.3 10 ND ND ND ------------ND
16-Feb-16 EPA 8270 2.2 10 ND ND ND ------------ND13-Feb-17 EPA 8270 2.2 10 ND ND ND ------------ND
Benzo(g,h,i)perylene 20-Jun-11 0.4 10.0 ND ND ND ND ND 1.4 J ---ND
NC 2L = 200 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.38 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.38 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.38 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 0.4 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.4 10.0 ND ND ND ------------ND
Dibenz(a,h)anthracene 20-Jun-11 0.55 10.0 ND ND ND ND ND 1.5 J ---ND
NC 2L = 0.005 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.55 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.55 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.55 10.0 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 0.6 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.6 10.0 ND ND ND ------------ND
Fluorene 24-Jun-10 3.8 12.2 ND 4.3 J ND ND ND ND ---ND
NC 2L = 300 µg/L (2/5/10) Resample > 12-Aug-10 3.1 10.0 ---ND ---------------ND13-Dec-10 ------------------------------
20-Jun-11 0.2 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 0.21 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------1-May-13 0.21 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.21 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 0.2 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.2 10.0 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 17 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
Indeno(1,2,3-cd)pyrene 20-Jun-11 0.29 10.0 ND ND ND ND ND 1.3 J ---ND
NC 2L = 0.05 µg/L (2/5/10)5-Dec-11 ------------------------------
11-Jun-12 0.29 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.29 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------24-Feb-14 0.29 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 0.5 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 0.3 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.3 10.0 ND ND ND ------------ND
2-Methylnaphthalene 24-Jun-10 5.1 12.2 ND 38.9 ND ND ND ND ---NDNC 2L = 30 µg/L (02/05/10) Resample>12-Aug-10 4.2 10 ---ND ---------------ND
13-Dec-10 ------------------------------
20-Jun-11 0.3 10.0 ND ND ND ND ND ND ---ND
5-Dec-11 ------------------------------
11-Jun-12 0.28 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 0.28 10.0 ND ND ND ND ND ND ---ND5-Aug-13 ------------------------------
24-Feb-14 0.28 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8270 1.0 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 0.3 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 0.3 10.0 ND ND ND ------------ND
Phorate 18-Apr-01 ---10 ---3.2 ND ND ND ---------
27-Oct-01 ---5 ND 8.1 ND ND ND ND ------
27-Oct-01 ---0.5 ---8.1 1.3 ND ND ---------
13-Jun-02 ---5 ND ND ND ND ND ND ------
13-Jun-02 ---0.5 ---ND ND ND ND ---------
19-Nov-02 ---5 ND ND ND ND ND ND ------
27-Jun-03 ---5 ND ND ND ND ND ND ---ND30-Jun-04 ---10 ND ND ND ND ND ND ---ND
29-Jun-05 ---10 ND ND ND ND ND ND ---ND
29-Dec-05 ------------------------------28-Jun-06 ---10 ND ND ND ND ND ND ---ND
29-Dec-06 ------------------------------
12-Jul-07 ---10 ND ND ND ND ND ND ---ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 ------------------------ND ---8-Jul-08 ---10 ND ND ND ND ND ND ---ND
17-Dec-08 ------------------------------
9-Jul-09 6.6 22.2 ND ND ND ND ND ND ---ND
16-Dec-09 ------------------------------
NC 2L = 1 µg/L (02/05/10)24-Jun-10 6.5 24.1 ND ND ND ND ND ND ---ND
13-Dec-10 ------------------------------
20-Jun-11 5.4 10.0 ND ND ND ND ND ND ---ND5-Dec-11 ------------------------------
11-Jun-12 5.4 10.0 ND ND ND ND ND ND ---ND
12-Dec-12 ------------------------------
1-May-13 5.4 10.0 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 5.4 10.0 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------10-Mar-15 EPA 8270 0.8 10.0 ND ND ND ------------ND
16-Feb-16 EPA 8270 1.1 10.0 ND ND ND ------------ND
13-Feb-17 EPA 8270 1.1 10.0 ND ND ND ------------ND
Beta-BHC 11-Jun-12 0.050 0.050 ND ND 0.16 ND ND ND ---ND
NC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------
12-Dec-12 ------------------------------1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.050 ND 0.052 ND ND ND ND ---ND
Resample >15-Apr-14 0.050 0.050 ---ND ---------------ND
12-Aug-14 ------------------------------10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.1 0.1 ND ND ND ------------ND
Delta-BHC 11-Jun-12 0.050 0.050 ND ND 0.090 ND ND ND ---ND
NC 2L = 0.019 µg/L (10/23/07) Resample>19-Jul-12 0.050 0.050 ------ND ---------------
12-Dec-12 ------------------------------1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.1 0.1 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 18 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
gamma-BHC (Lindane)27-Jun-03 ---1.05 ND 0.085 ND ND ND ND ---ND
30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND
30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND
29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND
12-Jul-07 ---0.05 ND ND ND ND ND ND ---ND
NC 2L = 0.2 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND
8-Jul-08 ---0.50 ND ND ND ND ND ND ---ND
17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND
9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND16-Dec-09 0.01 0.1 ND ND ND ND ND ND ---ND
NC 2L = 0.03 µg/L (02/05/10)24-Jun-10 0.00021 0.010 ND ND 0.052 ND ND ND ---ND
Resample >12-Aug-10 0.00020 0.010 ------ND ------------ND
13-Dec-10 0.00020 0.050 ND ND 0.013 J ND ND ND ---ND
20-Jun-11 0.00020 0.050 ND ND 0.066 ND ND ND ---ND
Resample >28-Jul-11 0.00020 0.010 ------ND ------------ND
5-Dec-11 0.050 0.050 ND ND ND ND ND ND ---ND11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND
12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND
24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 0.050 0.050 ND ND ND ------------ND
10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
9-Aug-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.050 0.050 ND ND ND ------------ND
Heptachlor 27-Jun-03 ---1.05 ND 0.03 0.17 ND ND ND ---ND
30-Dec-03 ---0.05 ND ND ND ND ND ND ---ND30-Jun-04 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-04 ---0.05 ND ND ND ND ND ND ---ND
29-Jun-05 ---0.05 ND ND ND ND ND ND ---ND29-Dec-05 ---0.05 ND ND ND ND ND ND ---ND
28-Jun-06 ---0.05 ND ND ND ND ND ND ---ND
29-Dec-06 ---0.05 ND ND ND ND ND ND ---ND
12-Jul-07 ---0.05 ND ND ND ND ND ND ---NDNC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 ---0.05 ND ND ND ND ND ND ND ND
8-Jul-08 ---0.05 ND ND ND ND ND ND ---ND
17-Dec-08 0.050 0.050 ND ND ND ND ND ND ---ND
9-Jul-09 0.050 0.050 ND ND ND ND ND ND ---ND
16-Dec-09 0.02 0.1 ND ND ND ND ND ND ---ND
NC 2L = 0.008 µg/L (02/05/10)24-Jun-10 0.0015 0.010 ND ND ND ND ND ND ---ND
13-Dec-10 0.0500 0.0015 ND ND ND ND ND ND ---ND20-Jun-11 0.050 0.0015 ND ND ND ND ND ND ---ND
5-Dec-11 0.050 0.056 ND 0.062 ND ND ND ND ---ND
Resample >25-Jan-12 0.050 0.0500 ---ND ---------------ND
11-Jun-12 0.050 0.050 ND ND ND ND ND ND ---ND
12-Dec-12 0.050 0.050 ND ND ND ND ND ND ---ND
1-May-13 0.050 0.050 ND ND ND ND ND ND ---ND
5-Aug-13 0.050 0.050 ND ND ND ND ND ND ---ND24-Feb-14 0.050 0.050 ND ND ND ND ND ND ---ND
12-Aug-14 0.050 0.050 ND ND ND ------------ND
10-Mar-15 EPA 8081 0.050 0.050 ND ND ND ------------ND
18-Aug-15 EPA 8081 0.050 0.050 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
9-Aug-16 EPA 8081 0.050 0.050 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.050 0.050 ND ND ND ------------ND
2,4-D 27-Jun-03 ---3 ---5.9 ND ND ND ---------
30-Dec-03 ---2 ND ND ND ND ND ND ---ND
30-Jun-04 ---2 ND ND ND ND ND ND ---ND
29-Dec-04 ---2 ND ND ND ND ND ND ---ND
29-Jun-05 ---2 ND ND ND ND ND ND ---ND
29-Dec-05 ---2 ND ND ND ND ND ND ---ND
28-Jun-06 ---2 ND ND ND ND ND ND ---ND
29-Dec-06 ---2 ND ND ND ND ND ND ---ND
12-Jul-07 ---2 ND ND ND ND ND ND ---ND
NC 2L = 70 µg/L (10/23/07)19-Dec-07 ---2 ND ND ND ND ND ND ND ND
8-Apr-08 ---2 ND ND ND ND ND ND ---ND17-Dec-08 ---2.0 ND ND ND ND ND ND ---ND
9-Jul-09 ---2.0 ND ND ND ND ND ND ---ND
16-Dec-09 0.11 5.0 ND ND ND ND ND ND ---ND
24-Jun-10 0.23 2.1 ND ND ND ND ND ND ---ND
10-Dec-10 0.22 2.0 ND ND ND ND ND ND ---ND
20-Jun-11 0.22 2.0 ND ND ND ND ND ND ---ND
5-Dec-11 0.22 2.0 ND ND ND ND ND ND ---ND11-Jun-12 0.22 2.0 ND ND ND ND ND ND ---ND
12-Dec-12 0.22 2.0 ND ND ND ND ND ND ---ND
1-May-13 0.22 2.0 ND ND ND ND ND ND ---ND
5-Aug-13 0.22 2.0 ND ND ND ND ND ND ---ND
24-Feb-14 0.22 2.0 ND ND ND ND ND ND ---ND
12-Aug-14 EPA 8151 0.22 2.0 ND ND ND ------------ND
10-Mar-15 EPA 8151 0.24 2.1 ND ND ND ------------ND18-Aug-15 EPA 8151 0.24 2.1 ND ND ND ------------ND
16-Feb-16 EPA 8151 0.23 1.0 ND ND ND ------------ND
9-Aug-16 EPA 8151 0.24 1.0 ND ND ND ------------ND
13-Feb-17 EPA 8151 0.22 0.9 ND ND ND ------------ND
Granville County
Butner Landfill, Permit No. 39-02 Page 19 of 20
Joyce Engineering
APPENDIX C: HISTORICAL CONSTITUENTS IN GROUNDWATER
Analyte Sample Date Method DL RL MW-1R MW-2R MW-3R MW-4 MW-5 MW-6 NES-1 Blanks
4,4'-DDD 11-Jun-12 0.05 0.05 ND ND 0.13 ND ND ND ---ND
NC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------ND ---------------
12-Dec-12 ------------------------------
1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.1 0.1 ND ND ND ------------ND
4,4'-DDT 11-Jun-12 0.05 0.05 ND ND 0.10 ND ND ND ---ND
NC 2L = 0.1 µg/L (2/5/10) Resample>19-Jul-12 0.05 0.10 ------0.063 J ---------------12-Dec-12 ------------------------------
1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND
5-Aug-13 ------------------------------
24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND
12-Aug-14 ------------------------------
10-Mar-15 EPA 8081 0.1 0.1 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.1 0.1 ND ND ND ------------ND13-Feb-17 EPA 8081 0.1 0.1 ND ND ND ------------ND
Dinoseb 10-Mar-15 EPA 8151 0.1 1.1 ND ND 0.11 J ------------ND
16-Feb-16 EPA 8151 0.1 0.2 ND ND ND ------------ND
13-Feb-17 EPA 8151 0.1 0.2 ND ND ND ------------ND
Endrin aldehyde 11-Jun-12 0.050 0.050 ND ND 0.14 ND ND ND ------
NC 2L= 2 (2/5/10)12-Dec-12 0.050 0.10 ND ND ND ND ND ND ------1-May-13 0.050 0.10 ND ND ND ND ND ND ---ND
5-Aug-13 0.050 0.10 ND ND ND ND ND ND ---ND24-Feb-14 0.050 0.10 ND ND ND ND ND ND ---ND
12-Aug-14 EPA 8081 0.050 0.10 ND ND ND ------------ND10-Mar-15 EPA 8081 0.050 0.10 ND ND ND ------------ND
18-Aug-15 EPA 8081 0.050 0.10 ND ND ND ------------ND
16-Feb-16 EPA 8081 0.050 0.10 ND ND ND ------------ND9-Aug-16 EPA 8081 0.050 0.10 ND ND ND ------------ND
13-Feb-17 EPA 8081 0.050 0.10 ND ND ND ------------ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
Granville County
Butner Landfill, Permit No. 39-02 Page 20 of 20
Joyce Engineering

Appendix D

Historical Surface Water Analytical Data

APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
INORGANICS
Arsenic 06/24/10 2.7 10.00 4.30 J 2.90 J ND
NC 2B = 10 µg/L (03/28/08)12/13/10 2.7 10.0 ND ND ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND 3.0 J
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
08/09/16 EPA 6010 2.5 10.0 3.10 B ND 5.1 J
02/13/17 EPA 6010 5.0 10.0 ND ND ND
Barium 11/22/96 ---500 37.0 37.0 ---
06/17/97 ---500 37.0 62.0 ---
12/01/97 ---500 53.0 45.0 ---
05/20/98 ---500 24.0 69.0 ---
11/19/98 ---500 ND 100.0 ---
07/21/99 ---500 ND ND ---
11/16/99 ---500 ND ND ---
05/10/00 ---500 ND ND ---
10/26/00 ---500 ND ND ---
04/18/01 ---500 ND ND ---
10/27/01 ---500 ND ND ---
06/13/02 ---500 ---------
11/19/02 ---500 ND ND ---
06/27/03 ---500 ND ND ---
12/30/03 ---500 ND ND ND
06/30/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
12/29/04 ---500 ND ND ND
06/29/05 ---500 ND ND ND
12/29/05 ---500 ND ND ND
06/28/06 ---500 ND ND ND
12/29/06 ---100 37.5 40.6 0.20 J
07/12/07 ---100 33.3 J ---ND
12/19/07 ---100 52.6 B 149.0 11.7
NC 2B = 1,000 µg/L (03/28/08)07/08/08 ---100 33.8 J 161.0 0.3 J
12/17/08 0.2 100 30.2 B 33.5 B 10.7 J
07/09/09 0.2 100 36.8 B 78.4 B 17.6 J
12/16/09 0.2 100 31.2 B 36.2 B 17.1 J
06/24/10 0.2 100 34.5 B 71.3 B 27.3 J
12/13/10 0.2 100 36.1 B 91.0 J 12.1 J
06/20/11 5.0 100 40.3 J 93.0 J ND
12/05/11 5.0 100 32.9 J 59.0 J ND
06/11/12 5.0 100 40.0 J 95.6 J ND
12/12/12 5.0 100 45.0 J 97.8 J ND
05/01/13 5.0 100 32.7 J 43.1 J ND
08/05/13 5.0 100 49.9 J 79.8 J ND
02/24/14 5.0 100 29.0 J 30.4 J ND
08/12/14 EPA 6010 5.0 100 ---121 ND
03/10/15 EPA 6010 2.5 100 29.0 J 32.1 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 100 33.1 J 33.5 J ND
08/09/16 EPA 6010 2.5 100 43.3 J 105 ND
02/13/17 EPA 6010 2.5 100 45.3 J 60.4 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 1 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Beryllium 07/08/08 ---1.0 0.32 J ND ND
12/17/08 0.1 1.0 ND ND ND
07/09/09 0.1 1.0 ND ND ND
12/16/09 0.1 1.0 0.12 J ND ND
NC 2B = 6.5 µg/L (02/05/10)06/24/10 0.1 1.0 ND ND ND
12/13/10 0.1 1.0 ND ND ND
06/20/11 1.0 1.0 ND ND ND
12/05/11 1.0 1.0 ND ND ND
06/11/12 1.0 1.0 ND ND ND
12/12/12 1.0 1.0 ND ND ND
05/01/13 1.0 1.0 ND ND ND
08/05/13 1.0 1.0 ND ND ND
02/24/14 1.0 1.0 ND ND ND
08/12/14 EPA 6010 1.0 1.0 ---ND ND
03/10/15 EPA 6010 0.5 1.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 0.5 1.0 ND ND ND
08/09/16 EPA 6010 0.5 1.0 ND ND ND
02/13/17 EPA 6010 0.5 1.0 ND ND ND
Chromium 06/17/97 ---10.0 ND 3.00 ---
12/01/97 ---10.0 ND ND ---
05/20/98 ---10.0 ND ND ---
11/19/98 ---10.0 ND ND ---
07/21/99 ---10.0 ND ND ---
11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---
10/26/00 ---10.0 ND ND ---
04/18/01 ---10.0 ND ND ---
10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND ND ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 2.20 B 2.60 B 1.40 J
NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 2.50 J 2.20 J ND
12/17/08 0.4 10.0 1.40 J 2.60 J ND
07/09/09 0.4 10.0 2.6 J 1.2 J ND
12/16/09 0.4 10.0 4.1 J 3.4 J ND
06/24/10 0.4 10.0 3.3 B 7.3 J 0.71 J
12/13/10 0.4 10.0 1.4 J 1.5 J ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND 7.2 J ND
12/12/12 5.0 10.0 ND 8.2 J ND
05/01/13 5.0 10.0 5.7 J ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 4.4 J 3.6 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 4.6 J 6.8 J ND
08/09/16 EPA 6010 2.5 10.0 ND ND 2.90 J
02/13/17 EPA 6010 2.5 10.0 ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 2 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Cobalt 05/20/98 ---10 2.0 2.0 ---
11/19/98 ---10 ND 3.0 ---
07/21/99 ---10 ND ND ---
11/16/99 ---10 ND ND ---
05/10/00 ---10 ND ND ---
10/26/00 ---10 ND ND ---
04/18/01 ---10 ND ND ---
10/27/01 ---10.0 ND 22.0 ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND 10.0 ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 4.2 B 1.20 B 1.8 J
07/08/08 ---10.0 4.80 B 10.5 B 6.20 J
12/17/08 0.6 10.0 1.70 B 1.1 B 2.50 J
07/09/09 0.6 10.0 ND ND ND
12/16/09 0.6 10.0 ND 1.0 J ND
NC 2B = NE µg/L (03/24/10)06/24/10 0.6 10.0 ND ND ND
12/13/10 0.6 10.0 {4.4}B {ND}1.6 {1.0 J}J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
Resample >01/25/12 5.0 10.0 ------ND
06/11/12 5.0 10.0 ND 5.10 J ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
08/09/16 EPA 6010 2.5 10.0 ND ND ND
02/13/17 EPA 6010 2.5 10.0 ND ND ND
Copper 12/29/06 ---10.0 1.3 B 1.10 B 0.60 J
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 5.3 B ND 9.8
NC 2B = 7 µg/L (03/28/08)07/08/08 ---10.0 1.7 J 4.20 J ND
12/17/08 0.3 10.0 1.40 J 1.50 J ND
07/09/09 0.3 10.0 ND ND ND
12/16/09 0.3 10.0 1.90 J 2.00 J ND
06/24/10 0.3 10.0 ND 3.10 J ND
12/13/10 0.3 10.0 0.31 B ND 0.49 J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND 5.50 J ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 2.90 J 3.40 J ND
08/09/16 EPA 6010 2.5 10.0 ND ND ND
02/13/17 EPA 6010 2.5 10.0 ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 3 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Lead 05/20/98 ---10.0 ND 8.00 ---
11/19/98 ---10.0 ND ND ---
07/21/99 ---10.0 ND 10.0 ---
11/16/99 ---10.0 ND ND ---
05/10/00 ---10.0 ND ND ---
10/26/00 ---10.0 ND ND ---
04/18/01 ---10.0 ND ND ---
10/27/01 ---10.0 ND ND ---
06/13/02 ---10.0 ---------
11/19/02 ---10.0 ND ND ---
06/27/03 ---10.0 ND ND ---
12/30/03 ---10.0 ND ND ND
06/30/04 ---10.0 ND ND ND
12/29/04 ---10.0 ND ND ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---10.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 ND ND ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---10.0 ND ND ND
12/17/08 4.0 10.0 ND ND ND
07/09/09 4.0 10.0 ND ND ND
12/16/09 4.0 10.0 ND ND ND
06/24/10 4.0 10.0 ND ND ND
12/13/10 4.0 10.0 ND ND ND
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
08/09/16 EPA 6010 2.5 10.0 ND ND ND
02/13/17 EPA 6010 2.5 10.0 ND ND ND
Nickel 12/29/04 ---50.0 ND 50.0 (ND)ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND
06/28/06 ---50.0 ND ND ND
12/29/06 ---50.0 ND 2.9 J ND
07/12/07 ---50.0 3.8 J ---ND
12/19/07 ---50.0 6.0 31.5 ND
NC 2B = 25 µg/L (03/28/08)07/08/08 ---50.0 3.2 J 29.8 J ND
12/17/08 1.7 50.0 2.4 B 4.0 B 2.4 J
07/09/09 1.7 50.0 4.1 J 12.3 J ND
12/16/09 1.7 50.0 3.8 B 4.4 B 3.0 J
06/24/10 1.7 50.0 ND 2.0 J ND
12/13/10 1.7 50.0 ND 14.2 J 2.7 J
06/20/11 5.0 50.0 ND 7.8 J ND
12/05/11 5.0 50.0 ND 5.3 J ND
06/11/12 5.0 50.0 ND 11.0 J ND
12/12/12 5.0 50.0 ND 13.8 J ND
05/01/13 5.0 50.0 ND ND ND
08/05/13 5.0 50.0 ND 5.6 J ND
02/24/14 5.0 50.0 ND ND ND
08/12/14 EPA 6010 5.0 50.0 ---20.3 J ND
03/10/15 EPA 6010 2.5 50.0 3.0 J 3.8 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 50.0 2.9 J 4.7 J ND
08/09/16 EPA 6010 2.5 50.0 3.3 J 15.2 J ND
02/13/17 EPA 6010 2.5 50.0 ND 7.3 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 4 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Silver 07/12/07 ---10.0 2.20 J ---ND
12/19/07 ---10.0 ND 0.34 J ND
NC 2B = 0.06 µg/L (03/28/08)07/08/08 ---10.0 0.35 B 1.00 J 0.12 J
12/17/08 0.1 10.0 ND ND ND
07/09/09 0.1 10.0 ND 0.10 J ND
12/16/09 0.1 10.0 ND 0.16 J ND
06/24/10 0.1 10.0 ND 0.26 J ND
12/13/10 0.1 10.0 {ND}{0.28}B 0.21 {0.19 J}J
06/20/11 5.0 10.0 ND ND ND
12/05/11 5.0 10.0 ND ND ND
06/11/12 5.0 10.0 ND ND ND
12/12/12 5.0 10.0 ND ND ND
05/01/13 5.0 10.0 ND ND ND
08/05/13 5.0 10.0 ND ND ND
02/24/14 5.0 10.0 ND ND ND
08/12/14 EPA 6010 5.0 10.0 ---ND ND
03/10/15 EPA 6010 2.5 10.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 10.0 ND ND ND
08/09/16 EPA 6010 2.5 10.0 ND ND ND
02/13/17 EPA 6010 2.5 10.0 ND ND ND
Thallium 12/29/04 ---10.0 ND 10.0 (ND)ND
06/29/05 ---10.0 ND ND ND
12/29/05 ---10.0 ND ND ND
06/28/06 ---10.0 ND ND ND
12/29/06 ---6.00 ND ND ND
07/12/07 ---5.5 ND ---ND
12/19/07 ---5.5 3.60 J ND ND
07/08/08 ---5.5 3.40 J ND ND
12/17/08 3.0 5.5 ND ND ND
07/09/09 3.0 5.5 ND ND ND
12/16/09 3.0 5.5 ND ND ND
NC 2B = NE (03/24/10)06/24/10 3.0 5.5 ND ND ND
12/13/10 3.0 5.5 3.80 J ND ND
06/20/11 5.4 5.5 ND ND ND
12/05/11 5.4 5.5 ND ND ND
06/11/12 5.4 5.5 ND ND ND
12/12/12 5.4 5.5 ND ND ND
05/01/13 5.4 5.5 ND ND ND
08/05/13 5.4 5.5 ND ND ND
02/24/14 5.4 5.5 ND ND ND
08/12/14 EPA 6010 5.4 5.5 ---ND ND
03/10/15 EPA 6010 5.0 5.5 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 5.0 5.5 ND ND ND
08/09/16 EPA 6010 5.0 5.5 ND ND ND
02/13/17 EPA 6020B 0.0 5.5 ND ND ND
Vanadium 12/29/06 ---25.0 1.60 J 2.00 J ND
07/12/07 ---25.0 4.60 J ---ND
12/19/07 ---25.0 3.30 J 1.40 B 0.62 J
NC 2B = NE µg/L (03/28/08)07/08/08 ---25.0 5.20 J 2.30 J 0.20 J
12/17/08 0.2 25.0 1.80 B 2.70 B 0.76 J
07/09/09 0.2 25.0 5.00 B 3.40 B 1.30 J
12/16/09 0.2 25.0 3.60 J 3.50 J 0.53 J
06/24/10 0.2 25.0 5.80 J 2.60 J ND
12/13/10 0.2 25.0 1.60 B 0.67 B 0.36 J
06/20/11 5.0 25.0 ND ND ND
12/05/11 5.0 25.0 ND ND ND
06/11/12 5.0 25.0 ND 11.50 J ND
12/12/12 5.0 25.0 ND ND ND
05/01/13 5.0 25.0 ND ND ND
08/05/13 5.0 25.0 ND ND ND
02/24/14 5.0 25.0 ND ND ND
08/12/14 EPA 6010 5.0 25.0 ---ND ND
03/10/15 EPA 6010 2.5 25.0 3.9 J 4.7 J ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 2.5 25.0 4.1 J 5.8 J ND
08/09/16 EPA 6010 2.5 25.0 2.9 J 2.8 J ND
02/13/17 EPA 6010 2.5 25.0 ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 5 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Zinc 11/22/96 ---50.0 11.0 ND ---
06/17/97 ---50.0 ND ND ---
12/01/97 ---50.0 20.0 ND ---
05/20/98 ---50.0 20.0 28.0 ---
11/19/98 ---50.0 ND ND ---
07/21/99 ---50.0 ND ND ---
11/16/99 ---50.0 ND ND ---
05/10/00 ---50.0 ND ND ---
10/26/00 ---50.0 ND ND ---
04/18/01 ---50.0 ND ND ---
10/27/01 ---50.0 ND ND ---
06/13/02 ---50.0 ---------
11/19/02 ---50.0 ND ND ---
06/27/03 ---50.0 ND ND ---
12/30/03 ---50.0 ND ND ND
06/30/04 ---50.0 ND ND ND
12/29/04 ---50.0 ND ND ND
06/29/05 ---50.0 ND ND ND
12/29/05 ---50.0 ND ND ND
06/28/06 ---50.0 ND ND ND
12/29/06 ---50.0 ND ND ND
07/12/07 ---10.0 ND ---ND
12/19/07 ---10.0 24.6 B ND 102
NC 2B = 50 µg/L (03/28/08)07/08/08 ---10.0 ND ND 1.20 J
12/17/08 0.4 10.0 ND 0.89 B 0.49 J
07/09/09 0.4 10.0 ND 4.90 B 1.60 J
12/16/09 0.4 10.0 2.60 B 2.60 B 7.70 J
06/24/10 0.4 10.0 ND 14.9 ND
12/13/10 0.4 10.0 ND 9.80 B 6.70 J
06/20/11 10.0 10.0 ND ND ND
12/05/11 10.0 10.0 ND ND 12.4
06/11/12 10.0 10.0 ND ND ND
12/12/12 10.0 10.0 ND ND ND
05/01/13 10.0 10.0 ND 16.80 ND
08/05/13 10.0 10.0 ND ND ND
02/24/14 10.0 10.0 ND ND ND
08/12/14 EPA 6010 10.0 10.0 ---ND ND
03/10/15 EPA 6010 5.0 10.0 7.7 B 7.8 B 5.6 J
08/18/15 ------Dry Dry ---
02/16/16 EPA 6010 5.0 10.0 7.0 J ND ND
08/09/16 EPA 6010 5.0 10.0 ND ND ND
02/13/17 EPA 6010 5.0 10.0 ND 5.2 J ND
Granville County
Butner Landfill, Permit No. 39-02 Page 6 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
ORGANICS
Acetone 10/27/01 ---100 168.0 B 337.0 B 479.0
06/13/02 ---100 ---------
06/13/02 ---100 ---------
11/19/02 ---100 ND ND ---
06/27/03 ---100 ND ND ---
12/30/03 ---100 ND ND ND
06/30/04 ---100 ND ND ND
12/29/04 ---100 ND ND ND
06/29/05 ---100 ND ND ND
12/29/05 ---100 ND ND ND
06/28/06 ---100 ND ND ND
12/29/06 ---100 ND ND ND
07/12/07 ---100 ND ---ND
12/19/07 ---100 12.70 B ND 4.50 J
NC 2B = 2,000 µg/L (03/28/08)07/08/08 ---100 ND ND ND
12/17/08 20 100 ND ND ND
07/09/09 20 100 ND ND ND
NC 2B = NE (03/24/10)12/16/09 2.2 100 ND ND 2.80 J
06/24/10 2.2 100 2.80 B ND 7.70 J
12/13/10 2.2 100 ND 3.00 J ND
06/20/11 2.2 100 ND 3.80 B 3.90 J
12/05/11 2.2 100 ND 7.20 B 8.80 J
06/11/12 2.2 100 ND 5.50 B 4.70 J
12/12/12 10.0 100 ND ND ND
05/01/13 10.0 100 ND ND 14.6 J
08/05/13 10.0 100 ND ND ND
02/24/14 10.0 100 ND ND 25.7 J
08/12/14 EPA 8260 10.0 100 ---ND 22.0 J
03/10/15 EPA 8260 10.0 100 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 8260 10.0 100 ND ND ND
08/09/16 EPA 8260 10.0 100 ND ND ND
02/13/17 EPA 8260 10.0 100 ND ND ND
Granville County
Butner Landfill, Permit No. 39-02 Page 7 of 8
Joyce Engineering
APPENDIX D: HISTORICAL CONSTITUENTS IN SURFACE WATER
Analytes Sample Date Method DL RL SW-1 SW-2 Blanks
Chlorobenzene 06/27/03 ---5.0 ND 7.20 ND
12/30/03 ---5.0 ND ND ND
06/30/04 ---5.0 ND ND ND
12/29/04 ---5.0 ND ND ND
06/29/05 ---5.0 ND ND ND
12/29/05 ---5.0 ND ND ND
06/28/06 ---5.0 ND ND ND
12/29/06 ---3.0 ND ND ND
07/12/07 ---3.0 ND ---ND
12/19/07 ---3.0 ND ND ND
NC 2B = 130 µg/L (03/28/08)07/08/08 ---3.0 ND ND ND
12/17/08 0.23 3.0 ND ND ND
07/09/09 0.23 3.0 ND ND ND
12/16/09 0.23 3.0 ND ND ND
06/24/10 0.23 3.0 ND ND ND
12/13/10 0.23 3.0 ND ND 0.28 J
06/20/11 0.23 3.0 ND ND ND
12/05/11 0.23 3.0 ND ND ND
06/11/12 0.23 3.0 ND ND ND
12/12/12 0.23 3.0 ND ND ND
05/01/13 0.23 3.0 ND ND ND
08/05/13 0.23 3.0 ND ND ND
02/24/14 0.23 3.0 ND ND ND
08/12/14 EPA 8260 0.23 3.0 ---ND ND
03/10/15 EPA 8260 0.23 3.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 8260 0.23 3.0 ND ND ND
08/09/16 EPA 8260 0.23 3.0 ND ND ND
02/13/17 EPA 8260 0.23 3.0 ND ND ND
Chloromethane 07/09/09 0.11 1.0 ND 0.19 J ND
12/16/09 0.11 1.0 ND ND ND
NC 2B = NE (03/24/10)06/24/10 0.11 1.0 ND ND ND
12/13/10 0.11 1.0 ND ND ND
06/20/11 0.11 1.0 ND ND ND
12/05/11 0.11 1.0 ND ND ND
06/11/12 0.11 1.0 ND ND ND
12/12/12 0.11 1.0 ND ND ND
05/01/13 0.11 1.0 ND ND ND
08/05/13 0.11 1.0 ND ND ND
02/24/14 0.11 1.0 ND ND 0.25 J
08/12/14 EPA 8260 0.11 1.0 ---ND ND
03/10/15 EPA 8260 0.11 1.0 ND ND ND
08/18/15 ------Dry Dry ---
02/16/16 EPA 8260 0.11 1.0 ND ND ND
08/09/16 EPA 8260 0.11 1.0 ND ND ND
02/13/17 EPA 8260 0.11 1.0 0.17 J 0.19 J 0.18 J
Methylene Chloride 08/09/16 EPA 8260 0.97 1.0 ND ND 2.20 J
02/13/17 EPA 8260 0.97 1.0 ND ND ND
NC 2L = 5 µg/L (2/5/10)
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.
NE = Not established.
Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
**SW- 1 and SW-2 were both dry and unable to be sampled on the 8/18/2015 sampling event.**
Granville County
Butner Landfill, Permit No. 39-02 Page 8 of 8
Joyce Engineering

Appendix E

Statistical Analysis Worksheets & Summary

JOYCE Project:Granville County- Butner Landfill
Project No: 660.1701.12
Date: February 2017
Analyte:Cobalt
Quantitation
Concentration Limit
Sample No. Sample Date Location (µg/l) (µg/l)
1 9/8/1994 MW-5 ND 10 6.60 251
2 12/1/1994 MW-5 22.0 10 22.0 180
3 2/9/1995 MW-5 39.0 10 25.0 146
4 3/2/1995 MW-5 121 10 27.0 130
5 11/15/1995 MW-5 27.0 10 30.0 129
6 5/28/1996 MW-5 122 10 31.0 122
7 11/22/1996 MW-5 93.0 10 34.0 121
8 6/17/1997 MW-5 45.0 10 36.0 113
9 12/1/1997 MW-5 36.0 10 37.5 103
10 5/20/1998 MW-5 100 10 38.0 101
11 11/19/1998 MW-5 180 10 39.0 100
12 7/21/1999 MW-5 100 10 43.0 100
13 11/16/1999 MW-5 38.0 10 43.7 100
14 5/10/2000 MW-5 61.0 10 45.0 93.0
15 10/26/2000 MW-5 ND 10 46.0 81.8
16 4/18/2001 MW-5 74.0 10 47.0 75.0
17 10/27/2001 MW-5 47.0 10 52.0 74.0
18 6/13/2002 MW-5 251 10 57.0 72.5
19 11/19/2002 MW-5 57.0 10 58.4 61.0
20 6/27/2003 MW-5 75.0 10 61.0 58.4
21 12/30/2003 MW-5 52.0 10 72.5 57.0
22 6/30/2004 MW-5 31.0 10 74.0 52.0
23 12/29/2004 MW-5 46.0 10 75.0 47.0
24 6/29/2005 MW-5 43.0 10 81.8 46.0
25 12/29/2005 MW-5 30.0 10 93.0 45.0
26 6/28/2006 MW-5 72.5 10 100 43.7
27 12/29/2006 MW-5 37.5 10 100 43.0
28 7/12/2007 MW-5 58.4 10 100 39.0
29 12/19/2007 MW-5 103 10 101 38.0
30 7/8/2008 MW-5 130 10 103 37.5
31 12/17/2008 MW-5 43.7 10 113 36.0
32 7/9/2009 MW-5 100 10 121 34.0
33 12/16/2009 MW-5 6.60 10 122 31.0
34 6/24/2010 MW-5 25.0 10 129 30.0
35 12/13/2010 MW-5 129 10 130 27.0
36 6/20/2011 MW-5 81.8 10 146 25.0
37 12/5/2011 MW-5 146 10 180 22.0
38 6/11/2012 MW-5 101 10 251 6.60
39 12/12/2012 MW-5 113 10
40 5/1/2013 MW-5 34.0 10
Number of Data 40
Number of Truncated Data 2
Percentage of Truncated Data 5%
Nonparametric Prediction Interval: 251 µg/l
Note:
All concentrations in micrograms per liter (µg/l).
ND = Not detected above the detection limit (truncated).
J = Estimated concentration between the detection limit and the quatitation limit.
Sorted
Concentration (µg/l)
JEI Project:Granville County- Butner Landfill
Project No: 660.1701.12
Date: February 2017
Shapiro Wilk Test Statistic (W) for normality of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 6.60 251.00 244.40 0.4150 101.43
2 22.00 180.00 158.00 0.2774 43.83
3 25.00 146.00 121.00 0.2110 25.53
4 27.00 130.00 103.00 0.1881 19.37
5 30.00 129.00 99.00 0.1686 16.69
6 31.00 122.00 91.00 0.1513 13.77
7 34.00 121.00 87.00 0.1356 11.80
8 36.00 113.00 77.00 0.1211 9.32
9 37.50 103.00 65.50 0.1075 7.04
10 38.00 101.00 63.00 0.0947 5.97
11 39.00 100.00 61.00 0.0824 5.03
12 43.00 100.00 57.00 0.0706 4.02
13 43.70 100.00 56.30 0.0592 3.33
14 45.00 93.00 48.00 0.0481 2.31
15 46.00 81.80 35.80 0.0372 1.33
16 47.00 75.00 28.00 0.0264 0.74
17 52.00 74.00 22.00 0.0158 0.35
18 57.00 72.50 15.50 0.0053 0.08
19 58.40 61.00 2.60
20 61.00 58.40 -2.60
21 72.50 57.00 -15.50
22 74.00 52.00 -22.00
23 75.00 47.00 -28.00
24 81.80 46.00 -35.80
25 93.00 45.00 -48.00
26 100.00 43.70 -56.30
27 100.00 43.00 -57.00
28 100.00 39.00 -61.00
29 101.00 38.00 -63.00
30 103.00 37.50 -65.50
31 113.00 36.00 -77.00
32 121.00 34.00 -87.00
33 122.00 31.00 -91.00
34 129.00 30.00 -99.00
35 130.00 27.00 -103.00
36 146.00 25.00 -121.00
37 180.00 22.00 -158.00
38 251.00 6.60 -244.40
The test statistic W can be found using:
W = SQR[B/(SD x SQRT(n-1))]
where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 271.94
SD = standard deviation of the data group = 49.82
n = number of samples = 38
W = 0.805
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.938
and the calculated W = 0.805
Therefore the data is Non-Normal
JEI Project:Granville County- Butner Landfill
Project No: 660.1701.12
Date: February 2017
Shapiro Wilk Test Statistic (W) for log normality of Cobalt
Complete the following table where
i = ordered value of sample, arranged from smallest to largest
X(i) = sample values arranged from smallest to largest
X(n-i+1) = sample values arranged from largest to smallest
A(n-i+1) = coefficient from table A-1, Statistical Analysis of Ground-Water
Data at RCRA Facilities
B(i) = summation of (X(n-i+1)-X(i))A(n-i+1)
i X(i) X(n-i+1) X(n-i+1) - X(i) A(n-i+1) B(i)
1 1.89 5.53 3.6384 0.4150 1.5099
2 3.09 5.19 2.1019 0.2774 0.5831
3 3.22 4.98 1.7647 0.2110 0.3724
4 3.30 4.87 1.5717 0.1881 0.2956
5 3.40 4.86 1.4586 0.1686 0.2459
6 3.43 4.80 1.3700 0.1513 0.2073
7 3.53 4.80 1.2694 0.1356 0.1721
8 3.58 4.73 1.1439 0.1211 0.1385
9 3.62 4.63 1.0104 0.1075 0.1086
10 3.64 4.62 0.9775 0.0947 0.0926
11 3.66 4.61 0.9416 0.0824 0.0776
12 3.76 4.61 0.8440 0.0706 0.0596
13 3.78 4.61 0.8278 0.0592 0.0490
14 3.81 4.53 0.7259 0.0481 0.0349
15 3.83 4.40 0.5756 0.0372 0.0214
16 3.85 4.32 0.4673 0.0264 0.0123
17 3.95 4.30 0.3528 0.0158 0.0056
18 4.04 4.28 0.2405 0.0053 0.0013
19 4.07 4.11 0.0436
20 4.11 4.07 -0.0436
21 4.28 4.04 -0.2405
22 4.30 3.95 -0.3528
23 4.32 3.85 -0.4673
24 4.40 3.83 -0.5756
25 4.53 3.81 -0.7259
26 4.61 3.78 -0.8278
27 4.61 3.76 -0.8440
28 4.61 3.66 -0.9416
29 4.62 3.64 -0.9775
30 4.63 3.62 -1.0104
31 4.73 3.58 -1.1439
32 4.80 3.53 -1.2694
33 4.80 3.43 -1.3700
34 4.86 3.40 -1.4586
35 4.87 3.30 -1.5717
36 4.98 3.22 -1.7647
37 5.19 3.09 -2.1019
38 5.53 1.89 -3.6384
The test statistic W can be found using:
W = SQR((B/SD x SQRT(n-1))
where: B = summation of (X(n-i+1)-X(i))A(n-i+1) = 3.9877
SD = standard deviation of the data group = 0.7018
n = number of samples = 38
W = 0.8725
Compare this value to the critical value in Table A-2 of Statistical Analysisof Ground-Water
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance (Draft)
July, 1992, to determine if the data is normally distributed.
From Table A-2 with (n) samples and a 95% confidence level, the critical value is
W(crit) = 0.938
and the calculated W = 0.873
Therefore the data is Non-Log-Normal