3901_GranvilleCoOxfordLandfillUnit1WQMR_DIN28679_20170214

PREPARED FOR:
GRANVILLE COUNTY
SOLID WASTE DEPARTMENT
P.O. BOX 906
OXFORD, NORTH CAROLINA 27565

OXFORD UNIT 1 LANDFILL
PERMIT NO. 3901-CDLF-1997

FIRST SEMIANNUAL WATER QUALITY
MONITORING REPORT OF 2017

JUNE 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 660.1701.12

FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2017
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 June 2017
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1.0 INTRODUCTION ................................................................................................................. 1 
1.1 Site Background .................................................................................................................. 1 
1.2 Site Conceptual Model ........................................................................................................ 2 
1.2.1 Site Geology ............................................................................................................ 2 
1.2.2 Site Hydrogeology ................................................................................................... 2 
1.3 Aquifer Characteristics & Groundwater Flow Regime ....................................................... 3 
1.4 Monitoring History and Regulatory Status ......................................................................... 3 
1.4.1 Monitoring History .................................................................................................. 3 
1.4.2 Regulatory Status .................................................................................................... 4 
2.0 FACILITY MONITORING PROGRAM ........................................................................... 5 
2.1 Groundwater Monitoring Program ...................................................................................... 5 
2.2 Surface Water Monitoring Program .................................................................................... 7 
3.0 FISRT SEMIANNUAL SAMPLING EVENT OF 2017 .................................................... 7 
3.1 Field Work ........................................................................................................................... 7 
3.2 Laboratory Analysis and Quality Control ........................................................................... 7 
3.3 Data Analyses ...................................................................................................................... 8 
3.3.1 Analytical Results for Groundwater ........................................................................ 8 
3.3.1.1 Inorganic Analyses ............................................................................................................................................ 8 
3.3.1.2 Organic Analyses .............................................................................................................................................. 9 
3.3.1.3 Performance and Sentinel Wells ........................................................................................................................ 9 
3.3.2 Analytical Results for Surface Water ...................................................................... 9 
3.3.3 Statistical Analyses ............................................................................................... 10 
3.3.3.1 Statistical Methods ............................................................................................................................................ 10 
3.3.3.2 Results of Statistical Analyses ............................................................................................................................. 10 
4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA) .................. 11 
4.1 MNA Parameters and Biodegradation Screening Matrix.................................................. 11 
4.2 Biochlor Modeling and Mass-Balance Assessment .......................................................... 12 
4.3 Trend Analysis and Plume Stability .................................................................................. 12 
5.0 CONCLUSIONS .................................................................................................................. 13 
6.0 REFERENCES .................................................................................................................... 13 
7.0 ACRONYMS ....................................................................................................................... 14 

FIRST SEMIANNUAL WATER QUALITY MONITORING REPORT OF 2017
Oxford Unit 1 Landfill - Granville County - Permit No. 3901-CDLF-1997

TABLE OF CONTENTS

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TABLES:
Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters
Table 7 Statistical Background Results
Table 8 Biodegradation Screening Matrix

CHARTS:
Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

FIGURE:
Figure 1 Site Location Map (USGS Topographic Map)

DRAWING:
Drawing 1 Groundwater Potentiometric Surface Map

APPENDICES:
Appendix A Field Sampling Logs
Appendix B Laboratory Reports with Chains of Custody
Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water
Appendix G Historical MNA Parameter Data
Appendix H Statistical Analysis Worksheets
Appendix I Biochlor Modeling Input and Output

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
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1.0 INTRODUCTION
On behalf of Granville County, Joyce Engineering, (JOYCE) has prepared this Water Quality
Monitoring Report for the Oxford Unit 1 Landfill, Solid Waste Permit Number
3901-CDLF-1997 (facility), in accordance with 15A NCAC 13B.1632 of the North Carolina
Solid Waste Management Rules (NCSWMR).

1.1 Site Background
The Oxford Landfill is located at 6584 Landfill Road, Oxford, Granville County, North Carolina,
near the town of Kinton Fork (Figure 1). The facility is owned and operated by Granville
County under Permit Number 3901-CDLF-1997, issued by the North Carolina Department of
Environment and Natural Resources (NCDENR), now the Department of Environmental Quality
(NCDEQ), Solid Waste Section (SWS). The Oxford Landfill consists of two separate waste
disposal units. Unit 1 is a former unlined municipal solid waste (MSW) landfill originally
permitted for disposal of domestic, institutional, industrial, agricultural, and demolition wastes,
with an active C&D landfill on top. Unit 2 is a Subtitle-D MSW landfill. Currently, the facility
is disposing of construction and demolition (C&D) wastes in Unit 1 on top of the closed MSW
landfill in accordance with their Transition Plan dated 1994. The permitted facility consists of
approximately 283 acres, of which approximately 29 acres constitutes the Unit 1 Landfill waste
unit.

The groundwater monitoring network at the Unit 1 landfill consists of one upgradient well
(MW-7) and five downgradient wells (MW-2, MW-3R, MW-4R, MW-5R and MW-6R) as
shown on Drawing 1. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced
MW-3, MW-4, MW-5, and MW-6, respectively, in 1999, due to the close proximity to waste of
the original wells. Wells NES-1S&D and NES-2S&D were installed down-gradient of MW-4R
and MW-5R, respectively in May 2004 as part of the Nature and Extent Study (NES). The
Corrective Action Plan (CAP) dated April 23, 2009 designated NES-1S and NES-2S as
performance wells and NES-1D and NES-2D as sentinel wells; however, NES-1D and NES-1S
were removed from the monitoring network in June 2014. NES-1D was abandoned in July 2016.
MW-7 replaced MW-1A as the facility background well beginning with the first semiannual
monitoring event of 2011. The monitoring wells are screened within the uppermost aquifer
underlying the facility. Well construction details are summarized in Table 1.

In addition, there are two surface water sampling points, SW-1 and SW-2 associated with Unit 1.
Sampling point SW-1 is a sedimentation pond located near the southeast corner of the waste unit,
and is up-stream of waste. Sampling point SW-2 is a small creek located northeast of the waste
unit and is downstream of the waste unit. The locations of SW-1 and SW-2 are shown on
Drawing 1.

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1.2 Site Conceptual Model
1.2.1 Site Geology
The Oxford Unit 1 Landfill is located in the Carolina Slate Belt of the Piedmont Physiographic
Province of North Carolina. The geologic province is characterized by a rolling topography with
a thick mantle of saprolite overlying Late Proterozoic and Paleozoic igneous and metamorphic
bedrock. The Carolina Slate Belt is comprised of 550 to 650 million year old, metamorphosed
sedimentary and volcanic rocks, intruded by granitic rocks.

The Oxford Unit 1 Landfill is underlain by the Flat River Complex, which is a shallow intrusive
complex of granitic composition, which comprises a large portion of the northern Carolina Slate
Belt (Butler, 1991). The landfill is approximately 18 miles east of the Virgilina Synclinorium,
approximately 10 miles west of the Nutbush Creek Fault Zone, and approximately 4 miles
northwest of the Durham Basin (Butler, 1991).

Previous investigations discovered limited exposures in the borrow area of a competent, massive,
gray to greenish gray meta-volcanic rock that is moderately fractured with prominent fractures
with near vertical dips and striking approximately N25o to 30oW (Woodward-Clyde, 1994).
Boring logs indicate that the depth to bedrock at Oxford Unit 1 Landfill ranges from 5 to 30 feet
below ground surface. The overlying saprolite consists of brownish sandy to clayey silt
(Woodward-Clyde, 1994).

1.2.2 Site Hydrogeology
Groundwater in the Piedmont can occur in substantial volumes where soils and regolith are thick,
but groundwater is typically found in minimal volumes in bedrock, primarily restricted to
fractures. The water table under the area of investigation was encountered in the unconfined
aquifer that is mostly in the transition zone that consists of saprolite and highly fractured
bedrock. This unconfined aquifer is pervasive across the site and generally mimics the surface
topography. The saturated portion of the uppermost aquifer beneath the study area is vertically
continuous to bedrock, and no confining layers have been encountered during site investigations.
There is a high degree of connectivity between the saprolite and underlying fractured bedrock
such that they behave as a single continuous aquifer. Depth to water ranged from 5 to 10 feet
below grade in wells MW-4R, MW-6R, NES-2S, and NES-2D; and 10 to 25 feet below grade in
MW-1A, MW-2, MW-3R, MW-5R, MW-7, NES-1S, and NES-1D (Table 2). In general, the
water table is near the saprolite/bedrock interface.

Groundwater in the saprolite feeds the fractures in the bedrock and is discharged into creeks
north of the landfill. Groundwater flow at deeper levels within the fractured bedrock is
controlled by fractures. A groundwater potentiometric surface map, based on static water level
data obtained on February 14, 2017, is presented as Drawing 1. The groundwater map depicts
groundwater flow to the north.

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1.3 Aquifer Characteristics & Groundwater Flow Regime
Depth to groundwater is measured in all compliance monitoring wells at the site prior to each
sampling event. The groundwater elevations calculated relative to the surveyed measuring point
(top of casing) for each monitoring well are summarized in Table 2. The groundwater elevation
contours shown in Drawing 1 are based on data from the February 2017 sampling event.
Groundwater flow beneath the Unit 1 Landfill is primarily to the north. Horizontal groundwater
gradients were estimated from the February 2017 groundwater levels and are summarized in
Table 3. Horizontal gradients across the site ranged from 0.0145 to 0.0196 ft/ft. These values
are consistent with previous estimates.

Linear groundwater flow velocities for wells screened in saprolite were computed using the
following modified Darcy equation: V = Ki/n , where V = average linear velocity
(feet/year), K = hydraulic conductivity (feet/day), i = horizontal hydraulic gradient, and n =
effective porosity. The mean of hydraulic conductivities from slug-tests conducted in 1995,
1999 and 2004 (K = 4.36 ft/day) were used in these calculations, along with an estimated
effective porosity of 0.31 based on 85% of the average of laboratory-determined porosities for
site soil. The average estimated linear groundwater flow velocity under the facility was
calculated at 100.38 ft/year (Table 3). The linear velocity equation makes the simplifying
assumptions of a homogeneous and isotropic aquifer.

1.4 Monitoring History and Regulatory Status
1.4.1 Monitoring History
 1995: Oxford Unit 1 entered Assessment Monitoring due to detections of organic
constituents in several monitoring wells.
 1998: Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3,
MW-4, MW-5, and MW-6, respectively.
 2003: Assessment of Corrective Measures (ACM) and Nature and Extent Study (NES)
initiated due to 15A NCAC 2L.0202(NC2L) Groundwater Standard exceedances of
benzene in MW-4R and vinyl chloride in MW-5R.
 May 2004: Nature and Extent wells NES-1S&D and NES-2S&D installed.
 May 2005: NES, ACM, & Risk Assessment submitted to the SWS.
 August 21, 2006: ACM Public Meeting held in Oxford, NC.
 June 2008: Corrective Action Plan (CAP) submitted to the SWS.
 December 2008: First Baseline sampling event for MNA
 March 2009: Final Revision of CAP submitted to the SWS.
 April 23, 2009: CAP Approved by the SWS.
 June 2010: Final Baseline sampling event for MNA.
 December 23, 2010: Request for Background Well Replacement approved by the SWS
makes MW-7 (formerly P-2) the new site background monitoring well.
 January 27, 2011: Corrective Action Evaluation Report (CAER) reviewed and approved
by the SWS with an updated list of constituents of concern (COCs), along with the

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Alternate Source Demonstration (ASD) for Chromium, Thallium and TDS in MW-1A.
The SWS denied the request to remove selected MNA parameters but allowed a modified
monitoring frequency (beginning June 2011).
 June 9, 2011: The ASD for Iron and Manganese approved by the SWS.
 February 24, 2012: Beta-BHC added to COC list due to confirmed exceedance during
the December 2011 sampling event.
 June 3, 2014: The SWS approved the following: Monitoring wells MW-2, MW-3R,
MW-4R, and MW-6R reverted back to detection monitoring (Appendix I) from assessment
monitoring (Appendix II). NES-1S and NES-1D were removed from the groundwater
corrective action monitoring network. Sampling for Monitored Natural Attenuation
parameters in monitoring wells MW-3R and MW-4R was discontinued.
 July 30, 2015: Corrective Action Evaluation Report (CAER) reviewed and approved by
the SWS with an updated list of COCs, removing 1,1-dichloroethane and beta-BHC from
the COC list.
 July 8, 2016: Well NES-1D abandoned.

1.4.2 Regulatory Status
The Oxford Unit 1 Landfill has remained in Assessment Monitoring since 1995 due to detections
of organic constituents. There were NC2L Standard exceedances of benzene in MW-4R in 2003,
which have not been detected since, and there have been persistent NC2L exceedances of vinyl
chloride in MW-5R from 2003 to present. The County received a letter from the SWS dated
August 20, 2003, that requested the County to proceed with assessment activities at Oxford Unit
1 Landfill. A meeting between JOYCE and the SWS was held on February 11, 2004, to discuss
the SWS’s requirements for a Nature and Extent Study (NES) and an Assessment of Corrective
Measures (ACM). In May 2005, Granville County submitted a NES (JOYCE, 2005a), and an
ACM (JOYCE, 2005b) and a Quantitative Risk Assessment (QRA) (JOYCE, 2005c) to the SWS
in accordance with 15A NCAC 13B.1634. Granville County held a public meeting for the ACM
on August 21, 2006. A CAP was submitted in June 2008, with revisions in October 2008 and
March 2009 (JOYCE, 2009). The CAP proposed Monitored Natural Attenuation (MNA) as the
primary remedy, supplemented with Control of Decomposition Gasses as a secondary remedy.
The CAP was approved in a letter from the SWS dated April 23, 2009. The gas interception
trench proposed in the Control of Decomposition Gasses was installed July 2009. The last
sampling event for the Baseline MNA was completed in December 2010.

A Request for Background Well Replacement was submitted to the SWS October 25, 2010
because the background monitoring well, MW-1A, was dry or affected by low water levels and
excessive sediment as well as possible bore seal damage. The request proposed piezometer P-2
to be upgraded and re-named MW-7 to become the facility background monitoring well. The
SWS approved the request on December 23, 2010. MW-7 became the background monitoring
well for the first semiannual sampling event of 2011.

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An Alternate Source Demonstration for Iron and Manganese was submitted to the SWS October
26, 2010, after the requirements for additional constituent monitoring for C&D facilities showed
elevated concentrations of iron and manganese across multiple site wells in June 2010. The ASD
showed that the concentrations of iron and manganese were a result of natural occurrence in site
soil and not a release from the landfill. The ASD for Iron and Manganese was approved as
described by the SWS on June 9, 2011.

The first CAER was submitted to the SWS on November 29, 2010, and in a letter dated January
27, 2011, the SWS reviewed and approved the CAER. The SWS denied a request to remove
some of the MNA parameters made on behalf of the county, but did approve a reduced alternate
monitoring frequency as follows; carbon dioxide, ferrous iron, volatile fatty acids, total organic
carbon (TOC), sulfide, and dissolved ethane and ethane for every third year on a semiannual
basis. The SWS also approved removing benzene and cis-1,2-dichloroethylene from the COC
list and adding 1,1-dichloroethane. As a result, the current COC list includes vinyl chloride and
1,1-dichloroethane. The ASD for chromium, thallium, and total dissolved solids in MW-1A was
also approved. The Oxford Unit 1 landfill continues in Assessment Monitoring, with additional
C&D indicator parameters and selected MNA parameters and COC monitored at designated
wells at frequencies presented in the January 27, 2011 SWS review of the CAER and ASD and
summarized in the next section.

Beta-BHC was added to the COC list due to confirmed exceedance during the December 2011
sampling event.

In a letter dated May 22, 2014 Joyce Engineering requested the following changes:
 Revert groundwater monitoring wells MW-2, MW-3R, MW-4R, and MW-6R from
assessment monitoring (Appendix II) to detection monitoring (Appendix I).
 Remove groundwater monitoring wells NES-1S and NES-1D from the groundwater
corrective action monitoring network.
 Discontinue sampling for Monitored Natural Attenuation parameters in groundwater
monitoring wells MW-3R and MW-4R.
The SWS granted approval of the changes in a letter dated June 3, 2014.

The second CAER was submitted to the SWS on July 10, 2015, and in a letter dated July 30, 2015,
the SWS reviewed and approved the CAER. The SWS approval included removal of
1,1-dichloroethane and beta-BHC from the COC list due to the lack of recent exceedances. This left
vinyl chloride as the only COC for the facility.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Six groundwater monitoring wells comprise the compliance monitoring network at the Oxford
Unit 1 Landfill. The compliance network includes monitoring wells MW-7 (the current facility

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background well), MW-2, MW-3R, MW-4R, MW-5R, and MW-6R. In addition, there is one
performance well (NES-2S) that is sampled under the Corrective Action Plan (CAP) for the
facility. Monitoring wells MW-3R, MW-4R, MW-5R, and MW-6R replaced MW-3, MW-4,
MW-5, and MW-6, respectively, in August 1999, due to the close proximity to waste of the
original wells. The former background well, MW-1, was abandoned in 2001 after being
damaged by a vehicle. MW-1A was replaced as the background monitoring well by MW-7 in
2011, as described in Section 1.4.2, above. MW-1A is still monitored for static water level.
Monitoring wells NES-2S, and NES-2D were installed as part of the NES in May 2004. The
following table summarizes the monitoring network and required analytical parameters for the
first semiannual sampling event of 2017:

Groundwater Monitoring Network
Monitoring
Well
Date
Installed Classification Monitoring
Program TD Lithology of Screened
Interval
1st SA Event
Analyses
2nd SA Event
Analyses
MW-1A unknown Observation Water
Level 28.77 Saprolite NS NS
MW-2 unknown Compliance Detection 29.34 Saprolite/Bedrock App. I, C&D App. I, C&D
MW-3R 8/25/99 Compliance Detection 27.12 Partially Weathered
Rock App. I, C&D App. I, C&D
MW-4R 8/26/99 Compliance Detection 63.22 Bedrock App. I, C&D App. I, C&D
MW-5R 8/25/99 Compliance Assessment 40.25 Bedrock App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
MW-6R 8/25/99 Compliance Detection 42.90 Bedrock App. I, C&D App. I, C&D
MW-7 7/28/08 Background Assessment 34.50 Partially Weathered
Rock
App. II, C&D,
MNA
App. I + Det.,
C&D, MNA
NES-2S 5/11/04 Performance CAMP 21.5 Saprolite COC, MNA COC, MNA
NES-2D 5/11/04 Sentinel CAMP 66.5 Bedrock COC, MNA NS
App. I = NCSWMR Appendix I list of constituents. COC = Constituents of concern.
App. II = NCSWMR Appendix II list of constituents. MNA = Monitoring Natural Attenuation parameters.
App. I + Det. = App. I list plus detected App. II constituents. C&D = C&D indicator parameters.
NS = Not Sampled (After baseline period, sentinel wells are sampled annually).
CAMP = Corrective Action Monitoring Plan.

C&D indicator parameters: mercury, manganese, iron, sulfate, chloride, alkalinity, total
dissolved solids (TDS), temperature, pH, and specific conductance.

Current Appendix II detected constituents: mercury, sulfide, endosulfan I, and beta-
BHC.

Constituents of Concern: 1,1-dichloroethane, vinyl chloride, and beta-BHC.

MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen on a semiannual basis. Dissolved carbon dioxide,
and ferrous iron are sampled for both sampling events every third year.

MNA Laboratory Parameters: Dissolved hydrogen, dissolved methane, nitrate, sulfate,
chloride, alkalinity on a semiannual basis. Sulfide, TOC, ethane, ethene, and volatile
fatty acids are sampled for both sampling events every third year.

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2.2 Surface Water Monitoring Program
There are two surface water sampling points, SW-1 and SW-2 associated with the Unit 1 landfill.
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upgradient of the waste. Sampling point SW-2 is located northeast of the waste unit along a
tributary of Little Grassy Creek, down-gradient of the waste. The surface water samples are
analyzed for the NCSWMR Appendix I list of constituents during both semiannual events.

3.0 FISRT SEMIANNUAL SAMPLING EVENT OF 2017
3.1 Field Work
On February 14-15, 2017, JOYCE personnel visited Oxford Unit 1 Landfill to purge and sample
monitoring wells MW-7, MW-2, MW-3R, MW-4R, MW-5R, MW-6R, and NES-2S, collect
samples from surface points SW-1 and SW-2, and obtain a water level for MW-1A.

Monitoring wells were purged and sampled using a 12 volt submersible pump or disposable
bailers. Field measurements of temperature, pH, specific conductivity, and turbidity were
recorded in a field log for all wells and surface water points. For selected wells, additional MNA
field parameters were also measured and recorded. Prior to sampling, laboratory-supplied
containers were prepared with the following information:
 Monitoring well ID (completed by laboratory or field personnel);
 Date and time of sample collection (completed by field personnel);
 Initials of sampling personnel (completed by field personnel);
 Project name and number (completed by the laboratory or field personnel);
 Chemical preservative (completed by the laboratory or field personnel); and
 Requested chemical analysis (completed by the laboratory or field personnel).

Groundwater samples from each monitoring well were collected either immediately after purging
or within 24 hours of the final purge volume and were dispensed directly from the pump flow or
bailers into the provided laboratory containers. Immediately after collection, the samples were
placed in a laboratory provided cooler and chilled on ice. Field sampling logs are provided in
Appendix A.

Surface water point SW-1 and SW-2 were sampled using a decontaminated graduated dipper.
Prepared sampling containers were filled from the dipper, placed in a cooler, and chilled on ice.
Field sampling logs are provided in Appendix A.

3.2 Laboratory Analysis and Quality Control
Pace Analytical Services Inc. of Huntersville, North Carolina analyzed the February 2017
groundwater and surface water samples under chain-of-custody control. Groundwater samples
from the compliance wells were analyzed for the parameters summarized in Section 2.1. The
surface water samples were analyzed for NC Appendix I constituents. The samples were

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received by the laboratory February 16, 2017, in good condition, properly preserved, at proper
temperatures, and within analysis hold times.

In addition to samples collected for compliance monitoring at the Oxford Unit 1 Landfill,
JOYCE personnel collected a Field Blank as part of the February 2017 sampling event. The
Field Blank was analyzed for the NC Appendix I plus previously detected Appendix II
constituents, plus iron, manganese and tetrahydrofuran. Also, a Trip Blank that was prepared by
the laboratory accompanied the volatile sampling containers to and from the laboratory. The
Trip Blank was analyzed for the NC Appendix II list of volatile organic compounds and
tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the following data:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
 Blank qualified data (B-flags);
 Detections above the 15A NCAC 2L (NC2L) Groundwater Standards or NCDEQ Solid
Waste Section Groundwater Water Protection Standards (GWPS), or 15A NCAC 2B (NC
2B) Surface Water Standards; and
 Detections above historical levels.

The complete laboratory analytical packages and chains of custody for the February 2017
sampling event are included in Appendix B. Historical data tables are included in Appendices C,
D, E, F, and G. Constituents with quantified detections during the February 2017 sampling
event are summarized in Table 4. Constituents with exceedances of groundwater or surface
water standards during the February 2017 sampling event are summarized in Table 5. Field
parameters for the February 2017 event are summarized in Table 6.

3.3 Data Analyses
3.3.1 Analytical Results for Groundwater
3.3.1.1 Inorganic Analyses
Inorganic constituents detected at quantified concentrations above the NCDEQ Solid Waste
Section (SWS) report limits (SWSL) in one or monitoring wells during the February 2017 event
include: barium, cobalt, iron, manganese, zinc, alkalinity, chloride, and TDS. A summary of all
constituents with quantified detections for the February 2017 event is presented as Table 4. The
laboratory analytical reports, the laboratory quality assurance/quality control information, and
the chains of custody, are included in the Appendix B. Complete historical analytical results for
inorganic constituents are presented in Appendix C.

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Cobalt, iron, and manganese were detected at quantified concentrations above their NC2L or
GWPS in one or more monitoring well samples. Iron and manganese were shown to be naturally
occurring in an ASD approved by the NCDEQ-SWS on June 9, 2011. The detections of cobalt
in MW-2 were below the statistical background for cobalt (see Section 3.3.3). We request that
the background value be considered the GPS for cobalt per NCSWMR rule .1634.g.5

3.3.1.2 Organic Analyses
The only organic constituents detected at a quantified concentration above the SWSL during the
February 2017 sampling event were vinyl chloride and 1,4-dichlorobenzene in MW-5R. Vinyl
chloride in MW-5R was also above the NC2L Standard, and therefore is in exceedance of the
Groundwater Protection Standard (GPS) as defined in 15A NCAC 13B.1634.g. There were no
other quantified detections or exceedances for organic constituents.

A summary of all constituents with quantified detections for the February 2017 event is
presented as Table 4, and a summary of groundwater and surface water exceedances for the
February 2017 event is presented as Table 5. The laboratory analytical reports, the laboratory
quality assurance/quality control information, and the chains of custody, are included in the
Appendix B. Complete historical analytical results for organic constituents are presented in
Appendix D.

3.3.1.3 Performance and Sentinel Wells
Corrective action performance well, NES-2S was sampled for the contaminants of concern
(COCs) list approved by the SWS and for MNA parameters. No COCs were detected above the
SWSL, and therefore there were no GPS exceedances in the sample from the performance well.
A summary of historical detections of COCs in performance and sentinel wells for the facility is
provided in Appendix E.

3.3.2 Analytical Results for Surface Water
Sampling point SW-1 is located in a sedimentation basin near the southeast corner of the waste
unit, upstream of the waste. Sampling point SW-2 is located northeast of the waste unit along a
tributary of Little Grassy Creek, downstream of the waste.

Surface water analytical results from the site were compared to the 15A-NCAC-2B (NC 2B)
surface water standards for protection of freshwater aquatic life or human health, whichever is
lower (more protective) for a given constituent. Barium and zinc were detected above their
SWSL’s in SW-1 during the February 2017 event.

The analytical results from the February 2017 surface water sampling event at the Oxford Unit 1
Landfill are presented along with historical data in Appendix F. The laboratory analytical
reports, the laboratory quality assurance/quality control information, and the chain of custody,
are included in Appendix B.

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3.3.3 Statistical Analyses
3.3.3.1 Statistical Methods
Monitoring well MW-1A was designated as the background well for the facility until the first
semiannual sampling of 2011. Prior to the spring 2001 sampling event, the site had two
background wells, MW-1 and MW-1A. MW-1 was damaged by a vehicle and, with the approval
of NCDEQ, was abandoned in early 2001. MW-1A was affected by low water levels and impact
from high turbidity levels during more recent events, and was therefore approved to be replaced
by MW-7 as the background for the first semiannual sampling event of 2011. Data from MW-1
between September 1994 and October 2000, data from MW-1A from September 1994 to June
2010 and data from MW-7 from June 2011 to present have been used to determine statistical
background concentrations for inorganic constituents detected at the facility in exceedance of
their respective NC2L or GWPS. Alternatively, intrawell statistics may be used for a
downgradient well by excluding the most recent 6-8 samples and using the earlier results from
that well as the background data.

The background data for inorganic constituents are evaluated in accordance with the procedures
outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported concentrations
exceeded the facility background concentrations using the Shapiro-Wilk Test, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-Parametric
Prediction Limits, and Poisson Prediction Limits as appropriate. Background data, tests for
normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are used, as
appropriate based on the background data. The statistical test by which downgradient data are
compared to facility background data is based upon the nature of the data and the number of data
values that are less than the laboratory limit of detection. All statistical tests are evaluated at the
0.05 level of significance, 95% confidence level, and are conducted as one-tailed tests.

3.3.3.2 Results of Statistical Analyses
Iron and manganese were detected in several wells at concentrations above the NC2L standard in
the February 2017 samples. Iron and manganese were shown to be naturally occurring in an
ASD approved by the NCDEQ-SWS on June 9, 2011.

Cobalt was detected above its GWPS in MW-2 during the February 2017 sampling event.
Interwell statistics based on the data from the upgradient background wells were used to
determine the background concentration for these three metals. The results of the statistical
background analyses are summarized in Table 7 and the complete statistical analysis worksheets
are included as Appendix H.

On behalf of Granville County, JOYCE requests that the background value for cobalt be
considered the GPS per NCSWMR Rule .1634.g.5.

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4.0 EVALUATION OF MONITORED NATURAL ATTENUATION (MNA)
4.1 MNA Parameters and Biodegradation Screening Matrix
In accordance with the CAP for the facility, MNA baseline sampling was initiated with the
December 2008 sampling event. The June 2010 sampling event was the fourth and final baseline
sampling event for MNA. MNA sampling was continued in accordance with the modified
sampling frequency approved by NCDEQ-SWS on January 27, 2011.

During the February 2017 sampling event, MNA parameters were obtained for the: background
well MW-7, downgradient compliance well MW-5R; and performance well NES-2S. MNA
parameters included field parameters temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, as well as laboratory parameters dissolved hydrogen,
nitrate, sulfate, chloride, alkalinity, and methane. In addition, the performance well (NES-2S)
was sampled and analyzed for the COC vinyl chloride. Field parameter data for the February
2017 event are summarized in Table 6. Field data logs and laboratory reports are included in
Appendices A and B, respectively. The MNA parameter data from the February 2017 event, as
well as historical MNA data, are presented in Appendix G.

The MNA parameter data were evaluated in general accordance with the United States
Environmental Protection Agency’s (EPA’s) Technical Protocol Manual (EPA, 1998) to
determine whether the conditions are conducive to, or whether there is evidence for anaerobic
degradation of the chlorinated hydrocarbons. Specifically, the results were evaluated according
to the weighted system presented in Table 2.3 of the Technical Protocol Manual, referred to
hereafter as the Biodegradation Screening Matrix. According to this manual, a score less than 5
indicates that there is inadequate evidence for anaerobic natural attenuation, a score of 6 to 14
indicates that there is limited evidence for anaerobic natural attenuation, a score of 15 to 19
indicates that there is adequate evidence for anaerobic natural attenuation, and a score of 20 or
more indicates that there is strong evidence that anaerobic natural attenuation is occurring.

The evaluation was performed for data from MW-5R based on the results from the February
2017 sampling event. The Biodegradation Screening Matrix is presented in Table 8 of this
report. One aspect of the scoring process is ambiguous with respect to how it should be applied
to a landfill site such as this facility, and that is the issue of daughter products. Methane, carbon
dioxide (CO2), cis-1,2-dichloroethylene, vinyl chloride, and 1,1-dichlroethane can all be
daughter products produced by the biodegradation of higher-order chlorinated ethanes and
ethenes, and as such, their presence can be strong indicators that biodegradation is occurring, and
are therefore included in the EPA scoring matrix. On the other hand, methane and CO2 are gases
produced by the natural metabolization of biomass by microorganisms in a landfill, and cis-1,2-
dichloroethylene, vinyl chloride, and 1,1-dichloroethane can be primary contaminants leached
from waste in landfills. Some of these compounds are present in the groundwater plume;
however, it is unclear whether or not they are daughter products indicating natural attenuation.
For this reason, the score for MW-5R has been calculated both with and without the points for
daughter products.

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The following table summarizes the scoring results from Table 8 for both options for interpreting
the data. The scores ranged from 8 to 16 (limited evidence of natural attenuation to adequate
evidence of natural attenuation). In reality, the best score is probably in the middle of this range.

Points Awarded
including DP’s
Points Awarded
excluding DP’s
14 11
DP’s = Points for possible daughter products.

4.2 Biochlor Modeling and Mass-Balance Assessment
Anaerobic degradation of organic constituents, specifically chlorinated ethylenes, was modeled
using the EPA Biochlor System. The Biochlor model was set up to model flow, dispersion,
advection, adsorption, and biotransformation along a flow line running from the northeast corner
of the waste unit through MW-5R and NES-2S. The concentration in the source area was set
equal to the sampling results from MW-5R in February 2017. Distances from the source were
set equal to the distances from MW-5R (0 feet for MW-5R and 295 feet for NES-2S). The
plume was estimated to be 400 feet wide and 600 feet long based on the current plume maps in
the vicinity of MW-5R. Simulation time was 22 years, the time since closure of the MSW
landfill at the time of the February 2017 sampling event. A seepage velocity of 100.4 feet/year
was used based on observed groundwater flow rates. Biochlor modeling was performed for
ethanes for the 1,1-dichloroethane plume and for ethenes (ethylenes) for the vinyl chloride
plume. The input and output of the Biochlor modeling are presented in Appendix C.

The results of the Biochlor modeling indicated that the observed concentrations at NES-2S (non-
detect) were lower than modeled concentrations. The mass rate calculations from the Biochlor
modeling are summarized below. The results indicate a large percentage of the contaminants are
being removed by biotransformation; however, the modeling is poorly constrained.

1,1-dichloroethane 1,2-dichloroethene(total) vinyl chloride
% Biotransformed 0.0% 0.0% +0.0%
% Change in Mass Rate 0.0% 0.0% 49.5%

4.3 Trend Analysis and Plume Stability
Chart 1 shows the concentration of vinyl chloride (VC) versus time for MW-5 and MW-5R from
June 1994 through February 2017. Similarly, Chart 2 shows the 1,1-dichloroethane (1,1-DCA)
concentration versus time for the same time period and the same wells. Both charts include best-
fit trend lines through the MW-5R data and both display decreasing trends. 1,1-dichloroethane
has not been detected n exceedance of the NC2L standard since June 2011. These data show that
the plume is generally stable and/or decreasing, and that natural attenuation is adequately
controlling the plume.

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5.0 CONCLUSIONS
Iron and manganese were again detected in several wells at concentrations above the NC2L
standard in the February 2017 samples; however, an ASD showing that iron and manganese are
naturally occurring was approved by NCDEQ-SWS. Cobalt was detected in exceedance of its
respective NC2L or GWPS in MW-2 during the February 2017 event. On behalf of Granville
County, JOYCE requests that the background values for cobalt be considered the GPS per
NCSWMR rule .1634.g.5.

Vinyl chloride was detected in MW-5R in exceedance of its NC2L Standard during the February
2017 sampling, which is consistent with historical data. There were no other exceedances for
organic constituents. Overall, the organic detections are consistent with historical data from the
site and indicate decreasing trends. MNA data continues to indicate some evidence that natural
attenuation is occurring in the vicinity of MW-5R. There have been downward trends for all
VOCs included the only remaining COC, vinyl chloride, indicating that natural attenuation is
adequately controlling the plume.

The groundwater flow regime is consistent with previous data and the groundwater monitoring
system remains adequate for monitoring the site. The next semiannual sampling event is
tentatively scheduled for August 2017.

6.0 REFERENCES
The references cited herein were used to prepare this document and may or may not be cited in
the text of this report.

Butler, J. Robert, and Secor, Jr., Donald T., 1991, The Central Piedmont, in Horton, J. W., Jr.,
and Zullo, V. A., eds., The Geology of the Carolinas: The University of Tennessee Press,
p. 59-78.

Cowie, S. (2004). Emission of Non-methane Organic Compounds (NMOCs) and hazardous air
Pollutants (HAPs) from Decomposing Refuse and Individual Waste Components and
Under Different Conditions. Master’s Thesis, North Carolina State University.

Deisper, A. and Stegmann, R. (1994). The Origin and Fate of Volatile Trace Components in
Municipal Solid Waste Landfills. Waste Management & Research. v. 12, p. 129-139.

Joyce Engineering, (JOYCE), 2005a. Nature and Extent Study, Granville County Oxford
Landfill. May 2005.

JOYCE, 2005b. Assessment of Corrective Measures, Granville County Oxford Landfill. May
2005.

JOYCE, 2005c. Quantitative Risk Assessment, Granville County Oxford Landfill. May 2005.

First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Oxford Unit 1 Landfill, Permit No. 3901-CDLF-1997 June 2017
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JOYCE, 2009. Corrective Action Plan, Granville County Oxford Landfill. March 2009.

JOYCE, 2010a. Request for Background Well Replacement, Granville County Oxford Landfill,
Permit # 39-01. October 25, 2010.

JOYCE, 2010b. Alternate Source Demonstration for Iron and Manganese, Granville County
Oxford C&D Over MSW Landfill, Permit # 39-01. October 26, 2010.

JOYCE, 2010c. Corrective Action Evaluation Report and Alternate Source
Demonstrations,Granville County Oxford C&D Over MSW Landfill, Permit # 39-01.
November 29, 2010.

JOYCE, 2011. Second Semiannual Water Quality Report of 2010, Oxford Landfill, Granville
County, Permit Number 39-01. May 2011.

North Carolina Department of Environment, Health, and Natural Resources, 1997. North
Carolina Solid Waste Management Rules. 15 NCAC 13B.1600. January 1, 1997.

North Carolina Geological Survey, 1985, Geologic map of North Carolina: North Carolina
Department of Natural Resources and Community Development, scale 1:500000.

NRC, 2000. Natural Attenuation for Groundwater Remediation. National Academy Press,
Washington, D.C. pp. 108-111.

USEPA, 1998. Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents
in Groundwater. ORD, EPA/600/R-98/128. September 1998.

USEAP, 1992. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities,
Addendum to Interim Final Guidance. July 1992.

Woodward-Clyde Consultants, 1994. Transition Plan, Oxford Landfill Granville County, North
Carolina. April 1994.

7.0 ACRONYMS
ACM Assessment of Corrective Measures (report)
AOC Area of Concern
ASD Alternate Source Demonstration (report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (report)
CAER Corrective Action Evaluation Report (report)
CPVC Chlorinated Poly Vinyl Chloride
CO2 Carbon Dioxide

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COC Contaminant of Concern
DCA Dichloroethane
DCE Dichloroethylene
DENR See NCDEQ
DEQ See NCDENR
DH Dissolved Hydrogen
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
Fe2+ Ferrous Iron
GEU Gas Extraction Unit
GPS Groundwater Protection Standards per NCSWMR rule .1634.g.5.
GWPS Groundwater Protection Standards set by the NCDEQ-SWS for constituents with
no NC2L standard.
HASP Site-specific Health and Safety Plan
HDPE High-density Polyethylene
JE Joyce Engineering
JOYCE Joyce Engineering
LFG Landfill Gas
LEL Lower Explosive Limit
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC 2B North Carolina Surface Water Standards found in 15A NCAC 2B.0101
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L.0202
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources
(now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality
(formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (report)
O&M Operations and Maintenance
ORP Oxidation-Reduction Potential
OSHA Occupational Health and Safety Association
PCE perchloroethylene (aka – tetrachloroethylene)
PVC Poly Vinyl Chloride
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (report)
RL Reporting Limit (for laboratory data)
SC Specific Conductance
SSI Statistically Significant Increase (over background concentration)
SWQS Surface Water Quality Standards

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SWS NCDEQ (or NCDENR) Division of Waste Management, Solid Waste Section
SWSL North Carolina Solid Waste Section Reporting Limits (for laboratory data)
TCE Trichloroethylene
TDS Total Dissolved Solids
TOC Total Organic Carbon
TSS Total Suspended Solids
VC Vinyl Chloride
VFA Volatile Fatty Acid
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (report)

TABLES

Table 1 Monitoring Well Construction Data
Table 2 Historical Groundwater Elevation Data
Table 3 Groundwater Gradients and Calculated Flow Rates
Table 4 Quantified Detections in Groundwater and Surface Water
Table 5 Exceedances of Groundwater and Surface Water Standards
Table 6 Field Parameters
Table 7 Statistical Background Results
Table 8 Biodegradation Screening Matrix

TABLE 1: MONITORING WELL CONSTRUCTION DETAILSWell ID Date Installed Northing EastingGS Elev. (Ft-AMSL)TOC Elev. (Ft-AMSL)AR (Bedrock) (Feet BGS)TD (Boring) (Feet BGS)TD (Well) (Feet TOC)TOC Stick-up (Feet AGS)Top Screen (Feet BGS)Top Screen (Feet TOC)Bottom Screen (Feet BGS)Bottom Screen (Feet TOC)Screened LithologyDTW (Feet TOC)CommentsMW-1A--- 952141.6930 2110755.3908 535.18 538.18 > 22 22.00 25.00 3* 7.00 10.00 22.00 25.00 Saprolite 20.02Former Unit 1 Background Well, No longer Sampled, Stick-up Estimated MW-2--- 953940.0174 2110351.7384 517.00 518.62 21.00 27.50 29.12 1.62 12.50 14.12 27.50 29.12 Sap/BR 10.66 Unit 1 ComplianceMW-3R08/25/99 954025.5824 2111681.3905 501.3* 503.82 25.00 25.00 32.97 2.5* 14.00 21.97 24.00 31.97 Saprolite 20.24Unit 1 ComplianceMW-4------------------ --- 22.00 --- 7.00 --- 22.00 --- Bedrock ---Not SampledMW-4R08/26/99 954975.1334 2110797.9991 504.90 507.34 17.50 60.00 62.44 2.44 50.00 52.44 60.00 62.44 Bedrock 10.28Unit 1 ComplianceMW-5------------------ --- 27.50 --- 12.50 --- 27.50 --- Sap/BR ---Not SampledMW-5R08/25/99 954947.2480 2111685.6720 487.24 489.95 22.00 37.00 39.71 2.71 27.00 29.71 37.00 39.71 Bedrock 21.96Unit 1 ComplianceMW-6R08/25/99 954725.8325 2110287.6108 504.42 506.81 13.00 40.00 42.39 2.39 30.00 32.39 40.00 42.39 Bedrock 9.25Unit 1 ComplianceNES-1S05/01/04 955167.9708 2111057.1915 514.35 516.93 27.00 34.00 36.58 2.58 18.50 21.08 33.50 36.08 Sap/BR 29.90Unit 1 PerfomanceNES-1D05/01/04 955177.3548 2111054.7005 514.38 516.62 27.00 79.00 81.24 2.24 63.50 65.74 78.50 80.74 Bedrock 30.03Unit 1 SentinelNES-2S05/01/04 955091.2902 2111945.3411 474.53 477.20 9.00 21.50 24.17 2.67 11.00 13.67 21.00 23.67 Saprolite 9.14Unit 1 PerfomanceNES-2D05/01/04 955081.7805 2111946.7398 474.72 477.43 21.50 66.50 69.21 2.71 51.00 53.71 66.00 68.71 Bedrock 5.00Unit 1 SentinelMW-7 (former P-2)07/28/08 953292.1160 2112043.4480 531.24 534.24 34.50 34.50 37.50 3.00 19.50 22.50 34.50 37.50 Saprolite 23.91 Units 1 & 2 Background WellNOTES:AR = Auger Refusal (Estimate of depth to bedrock).GS = Ground Surface.* = estimated TOC Stickup, or estimated GS Elev.TD = Total Depth (of boring or well/piezometer).BGS = Below ground surface.MW-3R survey data are after MW-3R was raised and resurveyed in 2012.TOC = Top of Casing (or deoth measured from TOC).AGS = Above ground surface.MW-3R depths relative to TOC have been adjusted to the new TOC, DTW = Depth to Water (as measured on 11/20/08).AMSL = Above mean sea level.but depths BGS have not been adjusted.--- = data not available.Granville County - Oxford Landfill, Unit 1, Permit 3901-CDLF-1997Joyce Engineering
TABLE 2: Histroical Groundwater Elevation DataBackgroundWell ID:MW-1 MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2DWell TOC Elev.: 121.46 538.18 534.24 518.62 503.82 507.34 489.95 506.81 516.93 516.62 477.20 477.43Well Total Depth:28.77 34.50 29.34 31.63 63.22 40.25 42.90 36.10 57.75 24.20 69.2010-Sep-99 101.71 517.91- 507.76 481.40 493.62 467.65 496.53----16-Nov-99 105.76 522.86- 506.32 483.55 494.83 468.75 498.24----10-May-00 109.47 527.66- 507.89 487.20 499.63 470.65 500.59----26-Oct-00 103.54 518.89- 504.12 480.86 495.21 467.39 496.95----18-Apr-01 107.87 526.23- 508.01 486.62 498.50 470.79 500.21----27-Oct-01 - 514.65- 501.42 478.79 494.79 466.70 494.92----10-Jun-02 - 515.06- 502.91 480.10 495.19 467.06 496.26----19-Nov-02 - 518.61- 512.08 489.84 498.82 471.80 498.70----27-Jun-03 - 529.42- 508.76 488.69 500.79 471.72 501.38----29-Dec-03 - 528.91- 509.06 488.06 499.94 471.10 501.21----29-Jun-04 - 520.03- 505.24 481.10 497.84 467.72 499.21----28-Dec-04 - 526.73- 509.09 485.27 499.14 469.51 500.76----29-Jun-05 - 520.37- 504.64 481.10 497.60 467.63 499.15----29-Dec-05 - 519.54- 509.66 482.69 498.33 468.57 499.25----27-Jun-06 - 517.93- 507.85 481.85 497.64 468.00 498.63----27-Dec-06 - 523.00- 511.07 489.81 499.43 471.76 500.83 493.70 - 469.82 -12-Jul-07 - 516.94- 502.49 479.84 497.17 467.18 497.59----18-Dec-07 - 510.35- 501.46 477.54 495.40 464.09 493.14----7-Jul-08- 515.96- 501.99 479.52 497.04 466.79 496.71----16-Dec-08 - 532.53- 509.80 487.98 498.08 470.11 499.29 489.19 488.63 469.47 472.717-Jul-09- 518.28- 505.37 481.57 497.43 467.88 499.36 490.38 490.07 467.73 470.9114-Dec-09 - 533.10- 511.89 491.93 500.61 473.65 501.48 494.70 493.21 470.98 467.1422-Jun-10 - 518.45- 506.72 485.92 499.94 469.67 499.68 493.47 493.07 468.97 471.5313-Dec-10 - 509.41- 507.89 482.82 498.20 467.87 496.65 488.89 - 468.03 -20-Jun-11 - 515.17 513.91 504.60 482.72 499.96 467.76 498.63 492.11 491.51 468.03 474.355-Dec-11 - 513.35 507.92 507.44 484.94 498.29 468.45 497.17 488.15 487.45 468.25 464.9313-Jun-12 - 514.08 513.48 507.48 485.36 499.29 468.04 498.85 487.08 490.33 468.81 467.6412-Dec-12 - 511.34 506.86 503.10 481.55 497.24 466.90 494.83 486.84 486.26 467.26 461.4129-Apr-13 - 515.88 513.26 509.38 485.47 500.82 469.60 501.15 492.31 491.64 470.45 455.265-Aug-13 - 517.21 514.33 505.98 484.47 500.29 468.65 500.83 494.12 - 469.29 -25-Feb-14 - 514.06 511.75 509.82 486.32 501.50 473.05 501.99 491.83 491.54 470.28 461.1812-Aug-14 - 519.34 511.98 507.52 485.44 499.25 468.90 499.30 491.92 491.41 470.29 460.3111-Mar-15 - 524.32 516.39 510.37 487.12 502.94 474.18 504.41 500.98 500.12 470.63 473.6318-Aug-15 - 516.53 512.39 503.47 482.97 500.94 466.45 498.81 492.38 - 469.25 449.7116-Feb-16 - 526.03 515.79 510.07 486.93 501.84 475.45 503.66 500.23 - 471.15 469.1810-Aug-16 - 520.07 514.29 507.08 484.07 500.34 468.20 500.89 491.95 - 470.40 453.2314-Feb-17 - 524.14 510.89 507.72 484.44 500.34 468.86 501.06 491.73 - 468.85 453.13 Notes:TOC = top of casing. - = data not available.Water levels are measured from TOC. MW-7 added to monitoring network in early 2011.All elevations are in feet above mean sea level (ft-amsl). Prior to December 2012, the TOC elevation for M DowngradientPerformance/SentinelGranville Co. - Oxford Landfill, Unit 1Permit 3901-CDLF-1997Joyce Engineering
TABLE 3: Groundwater Gradients and Calculated Flow Rates
Date of Water Table Measurements:
SEGMENT HORIZ.HYDRAULIC EFFECTIVE LINEAR
FLOW BEGIN & END GRADIENT CONDUCTIVITY POROSITY VELOCITY
DIRECTION GW ELEVATION i K n e V
(feet-AMSL) (ft/day)(ft/year)
505
490
505
470
Average 0.0172 Average 87.54
Notes:
Linear flow velocity: V = Ki/n e (modified Darcy equation).
Hydraulic conductivity (K ) is based on the arithmetic mean of values from slug tests conducted at the facility.
Effective porosity (n e ) value is estimated at 85% of the laboratory-determined porosity for soil samples from the facility.
Refer to Drawing 1 for flow line segments.
74.69
February-17
0.31 109.894.36E+000.0214
0.0145 4.36E+00 0.31
FLOW LINE
SEGMENT
SEGMENT
LENGTH
(feet)
i 2 1635 N
i 1 1031 N
Granville Co. - Oxford Landfill, Unit 1
Permit # 3901-CDLF-1997 Joyce Engineering
TABLE 4: Quantified Detections of Groundwater and Surface Water Constituents
NC2L/
GWPS*/NC2B**
3901-MW2 Cobalt 11.3 µg/L 10 1*2/14/2017
3901-MW2 Iron 6,250 µg/L 300 300 2/14/2017
3901-MW2 Manganese 234 µg/L 50 50 2/14/2017
3901-MW2 Chloride 4,970 µg/L -250,000 2/14/2017
3901-MW2 Alkalinity, Total CaCO3 16,000 µg/L 1000 NE 2/14/2017
3901-MW2 Zinc 14.7 µg/L 10 1,000 2/14/2017
3901-MW2 Total Dissolved Solids 62,000 µg/L -500,000 2/14/2017
3901-MW3R Iron 1400 µg/L 300 300 2/15/2017
3901-MW3R Manganese 246 µg/L 50 50 2/15/2017
3901-MW3R Alkalinity, Total CaCO3 92,800 µg/L 1000 NE 2/15/2017
3901-MW3R Chloride 29,300 µg/L -250,000 2/15/2017
3901-MW3R Total Dissolved Solids 154,000 µg/L -500,000 2/15/2017
3901-MW4R Manganese 1,390 µg/L 50 50 2/15/2017
3901-MW4R Alkalinity, Total CaCO3 300,000 µg/L 1000 NE 2/15/2017
3901-MW4R Chloride 59,100 µg/L -250,000 2/15/2017
3901-MW4R Total Dissolved Solids 438,000 µg/L -500,000 2/15/2017
3901-MW5R Manganese 91.4 µg/L 50 50 2/15/2017
3901-MW5R 1,4-Dichlorobenzene 1.1 µg/L 1 6 2/15/2017
3901-MW5R Vinyl Chloride 1.4 µg/L 1 0.03 2/15/2017
3901-MW5R Alkalinity, Total CaCO3 175,000 µg/L 1000 NE 2/15/2017
3901-MW4R Chloride 49,200 µg/L -250,000 2/15/2017
3901-MW5R Total Dissolved Solids 277,000 µg/L -500,000 2/15/2017
COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 4: Quantified Detections of Groundwater and Surface Water Constituents
NC2L/
GWPS*/NC2B** COLLECT DATEWELL ID PARAMETER RESULT UNITS SWSL
3901-MW6R Barium 102 µg/L 100 700 2/15/2017
3901-MW6R Iron 944 µg/L 300 300 2/15/2017
3901-MW6R Manganese 2,210 µg/L 50 50 2/15/2017
3901-MW6R Alkalinity, Total CaCO3 183,000 µg/L 1000 NE 2/15/2017
3901-MW6R Chloride 142,000 µg/L -250,000 2/15/2017
3901-MW6R Total Dissolved Solids 481,000 µg/L -500,000 2/15/2017
3901-MW7 Alkalinity, Total CaCO3 115,000 µg/L 1000 NE 2/15/2017
3901-MW7 Iron 633 µg/L 300 300 2/15/2017
3901-MW7 Chloride 10,900 µg/L -250,000 2/15/2017
3901-MW7 Total Dissolved Solids 233,000 µg/L -500,000 2/15/2017
3901-SW1 Barium 285 µg/L 100 200,000**2/15/2017
3901-SW1 Zinc 11 µg/L 10 36**2/15/2017
NOTES:All Results in micorgrams per liter (µg/L)
MDL = Method Detection Limit
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
NC2B = NC Surface Water standards for fresh-water aquatic life from 15A-NCAC-2B
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
NE= Not Established
J = Estimated concentration below the MRL or SWSL
Bold values= Detections above the NC2L, GWPS, or NC2B stardards (see Table 5)
Oxford Unit 1, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 5: Exceedances of Groundwater and Surface Water Standards
WELL ID PARAMETER RESULT UNITS SWSL NC2L/*GWPS COLLECT DATE
3901-MW2 Cobalt 11.3 µg/L 10 1*2/14/2017
3901-MW2 Iron 6,250 µg/L 300 300 2/14/2017
3901-MW2 Manganese 234 µg/L 50 50 2/14/2017
3901-MW3R Iron 1400 µg/L 300 300 2/15/2017
3901-MW3R Manganese 246 µg/L 50 50 2/15/2017
3901-MW4R Manganese 1,390 µg/L 50 50 2/15/2017
3901-MW5R Manganese 91.4 µg/L 50 50 2/15/2017
3901-MW5R Vinyl Chloride 1.4 µg/L 1 0.03 2/15/2017
3901-MW6R Iron 944 µg/L 300 300 2/15/2017
3901-MW6R Manganese 2,210 µg/L 50 50 2/15/2017
3901-MW7 Iron 633 µg/L 300 300 2/15/2017
NOTES:All Results in micorgrams per liter (µg/L)
SWSL = NC Soild Waste Section Reporting Limit
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202
GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)
GPS for antimony and cobalt are based on the statistical backgound for the facility.
Bold = GPS Exceedance.
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS DATE
3901-MW2 Conductivity 63.6 µS/cm 2/14/2017
3901-MW2 pH 5.73 S.U.2/14/2017
3901-MW2 Static Water Level 10.90 ft 2/14/2017
3901-MW2 Temperature 15.2 ºC 2/14/2017
3901-MW2 Turbidity 8.2 NTU 2/14/2017
3901-MW2 Well Depth 29.34 ft 2/14/2017
3901-MW3R Conductivity 196.7 µS/cm 2/15/2017
3901-MW3R pH 6.23 S.U.2/15/2017
3901-MW3R Static Water Level 19.38 ft 2/15/2017
3901-MW3R Temperature 15.4 ºC 2/15/2017
3901-MW3R Turbidity 9.87 NTU 2/15/2017
3901-MW3R Well Depth 31.63 ft 2/15/2017
3901-MW4R Conductivity 498.6 µS/cm 2/15/2017
3901-MW4R pH 7.08 S.U.2/15/2017
3901-MW4R Static Water Level 7.00 ft 2/15/2017
3901-MW4R Temperature 13.5 ºC 2/15/2017
3901-MW4R Turbidity 7.81 NTU 2/15/2017
3901-MW4R Well Depth 63.22 ft 2/15/2017
3901-MW5R Conductivity 344.6 µS/cm 2/15/2017
3901-MW5R Dissolved Oxygen 3.80 mg/l 2/15/2017
3901-MW5R Oxidation Reduction Potential 53.7 mV 2/15/2017
3901-MW5R pH 6.44 S.U.2/15/2017
3901-MW5R Static Water Level 21.09 ft 2/15/2017
3901-MW5R Temperature 14.0 ºC 2/15/2017
3901-MW5R Turbidity 6.7 NTU 2/15/2017
3901-MW5R Dissloved Carbon Dioxide 105 mg/l 2/15/2017
3901-MW5R Ferrous Iron 0 mg/l 2/15/2017
3901-MW5R Well Depth 40.25 ft 2/15/2017
3901-MW6R Conductivity 540 µS/cm 2/15/2017
3901-MW6R pH 7.30 S.U.2/15/2017
3901-MW6R Static Water Level 5.75 ft 2/15/2017
3901-MW6R Temperature 13.1 ºC 2/15/2017
3901-MW6R Turbidity 7.06 NTU 2/15/2017
3901-MW6R Well Depth 42.90 ft 2/15/2017
3901-MW7 Conductivity 239.0 µS/cm 2/15/2017
3901-MW7 Dissolved Oxygen 9.33 mg/l 2/15/2017
3901-MW7 Oxidation Reduction Potential 72.6 mV 2/15/2017
3901-MW7 pH 6.52 S.U.2/15/2017
3901-MW7 Static Water Level 23.35 ft 2/15/2017
3901-MW7 Temperature 12.0 ºC 2/15/2017
3901-MW7 Turbidity 4.54 NTU 2/15/2017
3901-MW7 Dissloved Carbon Dioxide 35 mg/l 2/15/2017
3901-MW7 Ferrous Iron 0 mg/l 2/15/2017
3901-MW7 Well Depth 37.32 ft 2/15/2017
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 1 of 2
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULT UNITS DATE
3901-NES2S Conductivity 112.4 µS/cm 2/15/2017
3901-NES2S Dissolved Oxygen 6.28 mg/l 2/15/2017
3901-NES2S Oxidation Reduction Potential 39.6 mV 2/15/2017
3901-NES2S pH 6.42 S.U.2/15/2017
3901-NES2S Static Water Level 8.35 ft 2/15/2017
3901-NES2S Temperature 11.6 ºC 2/15/2017
3901-NES2S Turbidity 5.25 NTU 2/15/2017
3901-NES2S Dissloved Carbon Dioxide 20 mg/l 2/15/2017
3901-NES2S Ferrous Iron 0 mg/l 2/15/2017
3901-NES2S Well Depth 24.20 ft 2/15/2017
3901-SW1 Conductivity 81.2 µS/cm 2/15/2017
3901-SW1 pH 5.96 S.U.2/15/2017
3901-SW1 Temperature 8.3 ºC 2/15/2017
3901-SW1 Turbidity 45.3 NTU 2/15/2017
3901-SW2 Conductivity 112.6 µS/cm 2/14/2017
3901-SW2 pH 6.95 S.U.2/14/2017
3901-SW2 Temperature 7.0 ºC 2/14/2017
3901-SW2 Turbidity 23.7 NTU 2/14/2017
Notes: ºC= degrees Centigrade µS/cm = microSemens per centimeter
S.U.= Standard Units NTU = Nephelometric Turbidity Units
ft = feet
Oxford Unit 1 Landfill, Granville Co.
Permit No. 39-01 2 of 2
Joyce Engineering
TABLE 7: STATISTICAL BACKGROUND RESULTSAnalyte Data Distribution Statistical Method used to Establish BackgroundBackground (µg/L)SWSL (µg/L)NC2L or *GWPS (µg/L)GPS (µg/L)Sampling Result (Max.) (µg/L)GPS ExceedancesCobalt59.3%NDNon-parametric Prediction Limit: Interwell430 10 1* 430 11.3NoneNotes: SWSL = NC Solid Waste Section LimitsNC 2L = NC Groundwater Standards (15A NCAC 2L.0202)GWPS = Solid Waste Section Groundwater Protection Standards for Constituents with no NC 2L (indicated by *)%ND = percentage of data that were non-detect (i.e., truncated).GPS = Groundwater Protection Standard per 15A NCAC .1634(g) - Assuming NCDEQ approval of using background as the GPS.Granville Co. - Oxford Landfill, Unit 1Permit No. 3901-CDLF-1997Joyce Engineering
TABLE 8: BIODEGRADATION SCREENING MATRIX (MW-5R)
Parameter Concentration Interpretation Possible Points Awarded Points Awarded
in Plume Points with DP points without DP points
Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0
concentrations
> 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0
aerobically
Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Iron II (Ferrous Iron)> 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0
oxidized under Fe (III) - reducing conditions
Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2
pathway
Sulfide > 1 mg/L Reductive pathway possible 3 0 0
Methane < 0.5 mg/L Vinyl chloride oxidizes 0 0 0
> 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0
accumulates
Oxidation Reduction < 50 mV Reductive pathway possible 1
Potential < -100 mV Reductive pathway likely 2 0 0
pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0
5 > pH > 9 Outside optimal range for reductive pathway -2
TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0
be natural or anthropogenic
Temperature >20o C At T > 20
oC biochemical process is accelerated 10 0
Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 1 0
Alkalinity > 2x background Results from interaction between CO2 and 10 0
aquifer minerals
Chloride > 2x background Daughter product of organic chlorine 2 2 2
Hydrogen > 1 nM Reductive pathway possible 3 3 3
< 1 nM Vinyl chloride oxidizes 0 0 0
Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 2 2
complex compounds; carbon and energy source
BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0
Tetrachloroethene (PCE) --- Material released 0 0 0
Trichloroethene (TCE) --- Material released 0 0 0
--- Daughter product of PCE 2 0 0
Dichloroethenes (DCE) --- Material released 0 0 0
Daughter product of TCE 2
Dichloroethene, cis-1,2, --- Material released 0 0 0
--- Daughter product of trichlorethene 2
Vinyl Chloride (VC) --- Material released 0 0
--- Daughter product of DCE 2 2
1,1,1-Trichloroethane (TCA) --- Material released 0 0 0
1,1-Dichloroethane (DCA) --- Material released 0 0 0
Daughter product of TCA 2
Chloroethane --- Daughter product of dichloroethane or vinyl chloride
under reducing conditions 2 0 0
Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2
> 0.1 mg/L 3 0 0
Chloroform --- Material released 0 0 0
--- Daughter product of carbon tetrachloride 2 0 0
Dichloromethane (MC) --- Material released 0 0 0
(Methylene Chloride) --- Daughter product of chloroform 2 0 0
Based on data collected in August 2014. Total Points Awarded: 14 11
mg/L = miligrams per liter
mV = millivolts NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however,
nM = Nanometer it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we
C = Celcius have two calculation columns. The first column assumes all of these are daughter products, and the
NA = Not Analyzed second column assumes none of them are. The true score is probably between the two.
BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes
SCORE: Evid. of Nat. Atten.
This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's < 5 inadequate
(EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation 6-14 limited
Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents 15-19 adequate
in Groundwater, September 1988.> 20 strong
Granville County - Oxford Landfill Permit 3901-CDLF-1997 Joyce Engineering

CHARTS
(Reference Section 4.2)

Chart 1 Vinyl Chloride in MW-5 & MW-5R vs. Time
Chart 2 1,1-Dichloroethane in MW-5 & MW-5R vs. Time

Granville Co., Oxford Landfill, Unit 1Permit # 3901-CDLF-1997Joyce Engineering0.005.0010.0015.0020.0025.0030.0035.00Aug‐94Feb‐95Aug‐95Feb‐96Aug‐96Feb‐97Aug‐97Feb‐98Aug‐98Feb‐99Aug‐99Feb‐00Aug‐00Feb‐01Aug‐01Feb‐02Aug‐02Feb‐03Aug‐03Feb‐04Aug‐04Feb‐05Aug‐05Feb‐06Aug‐06Feb‐07Aug‐07Feb‐08Aug‐08Feb‐09Aug‐09Feb‐10Aug‐10Feb‐11Aug‐11Feb‐12Aug‐12Feb‐13Aug‐13Feb‐14Aug‐14Feb‐15Aug‐15Feb‐16Aug‐16Feb‐17Vinyl Chloride Concentration  (µg/L)CHART 1:  Vinyl Chloride vs. Time in MW‐5 & MW‐5RMW‐5MW‐5RLinear (MW‐5R)NC 2L Standard for Vinyl Chloride:Prior to February 2010 = 0.015 µg/L;Feb. 2010 to Present = 0.03 µg/L.
Granville Co., Oxford Landfill, Unit 1Permit # 3901-CDLF-1997Joyce Engineering024681012Aug‐94Feb‐95Aug‐95Feb‐96Aug‐96Feb‐97Aug‐97Feb‐98Aug‐98Feb‐99Aug‐99Feb‐00Aug‐00Feb‐01Aug‐01Feb‐02Aug‐02Feb‐03Aug‐03Feb‐04Aug‐04Feb‐05Aug‐05Feb‐06Aug‐06Feb‐07Aug‐07Feb‐08Aug‐08Feb‐09Aug‐09Feb‐10Aug‐10Feb‐11Aug‐11Feb‐12Aug‐12Feb‐13Aug‐13Feb‐14Aug‐14Feb‐15Aug‐15Feb‐16Aug‐16Feb‐171,1‐Dichloroethane Concentration  (µg/L)CHART 2:  1,1‐Dichloroethane vs. Time in MW‐5 & MW‐5RMW‐5MW‐5RLinear (MW‐5R)NC 2L Standard for 1,1‐Dichloroethane:Prior to February 2010 = 70 µg/L;Feb. 2010 to Present = 6 µg/L.

FIGURE

Figure 1 Site Location Map (USGS Topographic Map)

DRAWING

Drawing 1 Groundwater Potentiometric Surface Map

OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OH
OHACCESS ROADACCESS ROAD
ACCESS ROAD
SEDIMENT
BASIN SB-1
APPROXIMATE MSW LANDFILL
LIMITS OF WASTE
UNIT 2
PHASE 1
NES-1D
NM
NES-1S
491.73
NES-2S
468.85NES-2D
453.13
GP-2
GP-4
GP-5
GP-6
GP-7
GP-8
GP-9
MW-2
507.72
MW-6
MW-6R
501.06
MW-4
MW-5
GP-3
GP-1
GP-10
P-23
P-12
P-14
P-21
GP-3A
MW-9
479.36
MW-11
472.17
MW-12
MW-7
510.89
MW-5R
468.86
MW-3
APPROXIMATE MSW LANDFILL
LIMITS OF WASTE
480
480
480
480480480480480
480
480
480
480
480 480
4904904904904904904
9
0
490490490
490
500
500
500
500
5
0
0
500
5
0
0500500 500 500
500500
500500500500500
500500500
50050051051051051051
0 510
510
510
510
520520520
520 520520530
530530540
540
560
550
540
530
520510510
530
530510
510
510
520
510
510
520
530
540
540
530
520
500
510540530520490490500510520530540510
500
500
490
5
1
0
470
500490500490
500
480490500510
AREA SURVEYED WITHIN
THIS BOUNDARY CONSISTS
OF GROUND SURVEY DATED JUNE 2013
UNIT 1
AREA SURVEYED WITHIN
THIS BOUNDARY CONSISTS
OF GROUND SURVEY DATED MARCH 2013
4
8
5
4
8
0
475
47
0
47047548
0
48
5
490
49
5
500
50551
0505 MW-10
475.97
MW-4R
500.34
MW-8
496.36
MW-3R
484.44
i
i
i
SW-1
SW-2
SW-3
SW-4
3
2
1
500500505
510505500495 490(ABANDONED)
(ABANDONED)495495510
MW-X
SW-X
EXISTING 10' TOPOGRAPHIC CONTOUR
EXISTING 2' TOPOGRAPHIC CONTOUR
EXISTING ROAD
GROUNDWATER SURFACE CONTOUR
[FEET ABOVE MEAN SEA LEVEL (AMSL)]
GROUNDWATER FLOW DIRECTION
GROUNDWATER MONITORING WELL LOCATION
AND IDENTIFICATION
SURFACE MONITORING POINT LOCATION AND
IDENTIFICATION
SEGMENT USED FOR GRADIENT CALCULATION
1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
2. GROUNDWATER CONTOUR INTERVAL = 10 FEET
3. GROUNDWATER CONTOURS BASED ON LINEAR
INTERPOLATION BETWEEN AND EXTRAPOLATION
FROM KNOWN DATA, TOPOGRAPHIC CONTOURS,
AND KNOWN FIELD CONDITIONS. THEREFORE,
GROUNDWATER CONTOURS MAY NOT REFLECT
ACTUAL GROUNDWATER CONDITIONS.
4. STATIC WATER LEVELS MEASURED ON 02/14/17.
i
LEGEND
490
NOTES
i
i
i
FLOW PATH LENGTH
1,031 LF
1,635 LF
2,234 LF
PROJECT NO.APPROVEDCHECKEDDRAWNDESIGNEDDATEDATEREVISIONS AND RECORD OF ISSUEBYNO APPCK
SCALE All rights reserved.Ó Joyce Engineering, Inc.DRAWING NO.L:\Granville\dwg\Oxford\GW Event Maps\GW MAP 02-17.dwg Layout=Layout12211 W. MEADOWVIEW ROADGREENSBORO, NC 27407PHONE: [phone]
(FEET)
GRAPHIC SCALE
20010050 NC CORP LIC: C-0782660GRANVILLE COUNTY OXFORD LANDFILLOXFORD, NORTH CAROLINA20171
AS SHOWNFEBRUARY 14, 2017GERWHGVBGVB02/24/17GROUNDWATER POTENTIOMETRIC SURFACE MAP

APPENDICES

Appendix A Field Sampling Logs
Appendix B Laboratory Reports with Chains of Custody
Appendix C Historical Detected Inorganic Constituents in Compliance Wells
Appendix D Historical Detected Organic Constituents in Compliance Wells
Appendix E Historical Detected COCs in Performance and Sentinel Wells
Appendix F Historical Detected Constituents in Surface Water
Appendix G Historical MNA Parameter Data

Appendix A

Field Sampling Logs

ProjectNo./TaskNo.:660.1701.12.02Sampler(s):H.Seaton/G.Eller2inches10.90feet29.34feet18.44feet[DTB-DTW]=3.0gallons=_____________gallons=9.0gallons9.0gallonsDATE:2/14/17GROUNDWATERSAMPLINGLOGBehindSED.BasinatcorneroflandfillJOYCEEN3I(\dEER!f’JGProjectName:OXFORD,GranvilleCo.WellID:MW-2WellLocation:_________________________WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWell Volume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbefore Sampling:--feetTemp.Cond.Turb.GallonsTimepHInitials°C(iSIcm)NTU0111415.06.1365.314.05GE3.0111815.35.8066.19.25GE6.0112015.55.7462.37.59GE9.0112415.25.7363.68.20GEBefore112415.25.7363.68.20GESamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son2/14/17.Signature:QAIQCSignOff:__________________Date:Date:(fL1/Z/7,1,7.7-
2inches19.3$feet31.63feet12.25feet[DTB-DTW]=1.9gallons=_____________gallons=5.7gallons5.0gallonsJOYCEEt’JI(\JEERIt\iGDATE:2/14-15/17GROUNDWATERSAMPLINGLOGProjectName:OXFORD.GranvilleCo.ProjectNo./TaskNo.:660.1701.12.02WellID:MW-3RSampler(s):H.SeatonlG.EllerWellLocation:Backsideoflandfill,turnrightattirepile,downtrailWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(‘NV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:19.30feetTemp.Cond.Turb.GallonsTimepHInitials°C(iSIcm)NTU0105716.06.54194.210.21GE1.9105916.26.43209.3206GE3.8110116.46.22218.2764GEDry@5.02/15/17Before084515.46.23196.79.87HSSamplingConunents(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe50son2/14/17andcloudywithtemperaturesinthe40son2/15/17.Signature:QA/QCSignOff:hØDate:________Date:?7ijil,7
2inches7.00feet63.22feet56.22feet[DTB-DTW]9.2gallons=_____________gallons=27.6gallons9.7gallonsDate:1L4—j7Date:JOYCEErJc3ItJEERIt\JGProjectName:OXFORD,GranvilleCo.WellID:MW-4RDATE:2/14-15/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:660.1701.12.02Sampler(s):H.Seaton/G.EllerBacksideoflandfilLnearroadWellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:_____7.08feetTemp.Cond.Turb.GallonsTimepHInitials°C(iSIcm)NTU0122013.17.355026.90GE9.2122814.97.545498.33GEDry9.72/15/17Before094513.57.08498.67.81GESamplingComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe40son2/14/17andcloudywithtemperaturesinthe40son2/15/17.Signature:QA/QCSignOff:___________________
DATE:2/14-15/17Fe2+:0m2JL.DissolvedC02:105mg/L,2inches21.09feet40.25feet19.16feet[DTB-DTW]3.1gallons=_____________gallons=9.3gallons9.3gallonsSignature:j5/%%4—QAIQCSignOff:Date:Z—1t4-tiDate:2i-,,/,..iJOYCE£NcI(\JERIt]GProjectName:OXFORD,GranvilleCo.WellID:MW-5RWellLocation:FarendofroadGROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:660.1701.12.02Sampler(s):H.Seaton,G.EllerWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:20.80feetTemp.Dis.02Cond.ORPTurb.GallonsTimepHInitials°Cmg/L(iSIcm)mVNTU0124615.31.62390.56.7359.65.39GE3.1124914.53.92384.56.8361.36.15GE6.2125314.72.74389.46.4565.04.6511$9.3125614.73.12388.66.4866.75.00HS2/15/17Before090014.03.80344.66.4453.76.70GESamplingConunents(weatherconditions,odor,color,silt,etc.):TheweatherwassunnywithtemneraturesintheSOson 2/14/17andcloudywithtemneraturesinthe40son2/15/1T
2inches5.75feet42.90feet37.15feet[DTB-DTW]=6.0gallons=_____________gallons=18.0gallons12.0gallonsDATE:2/14-15/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:660.1701.12.02Sampler(s):H.Seaton,G.EllerJOYCELENCIf’1EERII\JGProjectName:OXFORD,GranvilleCo.WellID:MW-6RWellLocation:BackcornerbeyondMW-6WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653forTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:6.00feetTemp.Coud.Turb.GallonsTimep11Initials°C(itS/cm)NTU0115811.86.59477.88.60GE6.0120514.57.045516.77GE12.0121014.67.0757410.11GEDry@12.02/15/17BeforeSampling095613.17.305407.06GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe50son2/14/17andcloudywith temperaturesinthe40son2/15/17.Signature:tiQAIQCSignOff:_________________Date:Date:2-IS-9Z%a,//7
Fe2+:Om/L,DissolvedC02:35mg/L,ProjectNo./TaskNo.:660.1701.12.03Sampler(s):H.Seaton/G.Eller2inches23.35feet37.32feet13.97feet[DTB-DTW]=2.2gallons=____________gallons=6.6gallons6.6gallonsSignature:1frJ%-Date:QAIQCSignOff:Ird%’Date:2H-/7i•j//2DATE:2/14-15/17GROUNDWATERSAMPLINGLOG.vUIIriEERItJGProjectName:OXFORD,GranvilleCo.WellID:MW-7Ye1lLocation:Unit2area,nearpowerlinesWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):Water ColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurgedlBailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:2130feetTemp.DOCond.Turb.GallonsTimepHORPInitials°Cmg/LQrSIcm)NTU0131915.95.42274.46.4078.33.61GE2.2132215.84.65271.96.4477.47.47GE4.4132415.74.84265.76.5476.515.9GE6.6132616.05.19277.66.5974.421.1GE2/15/17Before105012.09.33239.06.5272.64.54GESamplingComments(weatherconditions,odor,color,silt,etc.):TheweatherwassunnywithtemoeraturesintheSOson2/14/17andcloudywithtemoeraturesinthe40son2/15/17.I-
,
JOYCEEf]G1f’JEEfl!NGProjectName:OXFORD,GranvilleCo.WellID: NES-2SSampler(s):H.SeatonIG.FlierFe2+:0.0m/L,DissolvedC02:20mg/L,Signature:____QA/QCSignOff:2inches8.35feet24.20feet15.85feet[DTB-DTW]=2.5gallons=_____________gallons=7.5gallons7.5gallonsDate:2-_Date:Z/’ti/7DATE:2/14-15/17GROUNDWATERSAMPLINGLOGProjectNo./TaskNo.:660.1701.12.02NearMW-4RWellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOne WellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653For THREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:_
__
_
__DisposableBailerSampledwith:_
_
_
_
_DisposableBailerDepthtoWaterbeforeSampling:8.19feetTemp.DOCond.Turb.GallonsTimepHORPInitials°Cmg/L(itS/cm)NTU0134514.89.86163.17.5691.23.69GE2.5134714.19.53102.87.2381.36.05GE5.0135114.35.15104.96.1879.636.5GEDry6.3galGE2/15/17Before101511.66.28112.46.4239.65.25GESamplingComments(weatherconditions,odor,color,silt,etc.):TheweatherwassunnywithtemDeraturesintheSOson2/14/17andcloudywithtemneraturesinthe40son2/15/17.
JOYCEENG1t%JEERII’JGProjectName:OXFORD,GranvilleCo.SurfacePointID:SW-iLocation:Sedimentpondnearrip-ranDATE:2/15/17SURFACEWATERMONITORINGLOGProject/TaskNo.:660.1701.12.02Sampler(s):H.SeatonlG.EllerTimeofSampling:Temperature:Conductivity:Turbidity:(°C)(jiS/cm)(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemneraturesinthe40son2/14/17.Date:Date:FieldParameters:p11:11305.96xl81.245.3SketchofSampleLocation(includeflowdirection,drainagepathways,etc.):4ASignature:____________________—tQA/QCSignOff:__________________7Iz/1/,1
DATE:2/14/17JOYCE__________Ef\JGIfJEERI1VGSURFACEWATERMONITORINGLOGProjectName:OXFORD.GranvilleCo.Project/TaskNo.:660.1701.12.02SurfacePointID:SW-2Sampler(s):H.Seaton!G.FlierLocation:Backcorner,nearpropertylinefieldParameters:TimeofSampling:0945pH:6.95Temperature:7.0(°C)Conductivity:112.6(jiS/cm)Turbidity:23.7(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe50son2/14/17.SketchofSampleLocation(includeflowdirection,drainagepathways,etc.):JS-2SSignature:%--Date:QA/QCSignOff:___________________Date:

Appendix B

Laboratory Reports with Chains of Custody

#=CL#
February 28, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92330376
92330376
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-NC2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
OXFORD COMPLIANCE UNIT 1
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager1(704)875-9092
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 87
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 87
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Matrix Date Collected Date Received
92330376001 3901-MW7 Water 02/15/17 10:50 02/16/17 09:43
92330376002 3901-MW5R Water 02/15/17 09:00 02/16/17 09:43
92330376003 FIELD BLANK Water 02/15/17 11:40 02/16/17 09:43
92330376004 3901-MW2 Water 02/14/17 11:24 02/16/17 09:43
92330376005 3901-MW3R Water 02/15/17 08:45 02/16/17 09:43
92330376006 3901-MW4R Water 02/15/17 09:45 02/16/17 09:43
92330376007 3901-MW6R Water 02/15/17 09:56 02/16/17 09:43
92330376008 3901-SW1 Water 02/15/17 11:30 02/16/17 09:43
92330376009 3901-SW2 Water 02/14/17 09:45 02/16/17 09:43
92330376010 TRIP BLANK Water 02/13/17 07:00 02/16/17 09:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 87
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330376001 3901-MW7 EPA 8081 21 PASI-CRES
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 17 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ACJH1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92330376002 3901-MW5R EPA 8081 21 PASI-CRES
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 17 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ACJH1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92330376003 FIELD BLANK EPA 8081 21 PASI-CRES
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 17 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8270 112 PASI-CBPJ
EPA 8260 67 PASI-CGAW
SM 2320B 1 PASI-AKDF1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 87
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
SM 2540C 1 PASI-ACJH1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
SM 4500-CN-E 1 PASI-AAES2
92330376004 3901-MW2 EPA 6010 16 PASI-ASER
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJP
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92330376005 3901-MW3R EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ACJH1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92330376006 3901-MW4R EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ACJH1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
92330376007 3901-MW6R EPA 6010 16 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 7470 1 PASI-AWAB
EPA 8260 51 PASI-CGAW
SM 2320B 1 PASI-AKDF1
SM 2540C 1 PASI-ACJH1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ABRJ
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 87
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330376008 3901-SW1 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CGAW
92330376009 3901-SW2 EPA 6010 14 PASI-ASH1
EPA 6020B 1 PASI-ACDF
EPA 8260 50 PASI-CGAW
92330376010 TRIP BLANK EPA 8260 67 PASI-CGAW
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 87
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92330376001 3901-MW7
Barium 6.1J ug/L 02/24/17 15:36100EPA 6010
Iron 633 ug/L 02/24/17 15:36300EPA 6010
Manganese 15.5J ug/L 02/24/17 15:3650.0EPA 6010
Alkalinity, Total as CaCO3 115000 ug/L 02/24/17 01:215000SM 2320B
Total Dissolved Solids 233000 ug/L 02/21/17 02:0525000SM 2540C
Sulfate 47100J ug/L 02/22/17 13:17 M11250000EPA 300.0
Chloride 10900 ug/L 02/24/17 02:481000SM 4500-Cl-E
92330376002 3901-MW5R
Barium 38.9J ug/L 02/24/17 15:39100EPA 6010
Chromium 3.1J ug/L 02/24/17 15:3910.0EPA 6010
Iron 30.4J ug/L 02/24/17 15:39300EPA 6010
Manganese 91.4 ug/L 02/24/17 15:3950.0EPA 6010
Chlorobenzene 0.90J ug/L 02/21/17 17:113.0EPA 8260
1,2-Dichlorobenzene 1.1J ug/L 02/21/17 17:115.0EPA 8260
1,3-Dichlorobenzene 0.38J ug/L 02/21/17 17:115.0EPA 8260
1,4-Dichlorobenzene 1.1 ug/L 02/21/17 17:111.0EPA 8260
Vinyl chloride 1.4 ug/L 02/21/17 17:111.0EPA 8260
Alkalinity, Total as CaCO3 175000 ug/L 02/24/17 01:345000SM 2320B
Total Dissolved Solids 277000 ug/L 02/21/17 02:0625000SM 2540C
Sulfate 3510J ug/L 02/21/17 21:17250000EPA 300.0
Chloride 49200 ug/L 02/24/17 02:49 M1,R15000SM 4500-Cl-E
92330376003 FIELD BLANK
Methylene Chloride 1.6 ug/L 02/21/17 11:481.0EPA 8260
92330376004 3901-MW2
Barium 18.2J ug/L 02/24/17 15:45100EPA 6010
Chromium 6.8J ug/L 02/24/17 15:4510.0EPA 6010
Cobalt 11.3 ug/L 02/24/17 15:4510.0EPA 6010
Copper 6.3J ug/L 02/24/17 15:4510.0EPA 6010
Iron 6250 ug/L 02/24/17 15:45300EPA 6010
Manganese 234 ug/L 02/24/17 15:4550.0EPA 6010
Nickel 4.9J ug/L 02/24/17 15:4550.0EPA 6010
Vanadium 13.9J ug/L 02/24/17 15:4525.0EPA 6010
Zinc 14.7 ug/L 02/24/17 15:4510.0EPA 6010
Alkalinity, Total as CaCO3 16000 ug/L 02/22/17 05:565000SM 2320B
Total Dissolved Solids 62000 ug/L 02/17/17 15:59 D625000SM 2540C
Sulfate 11200J ug/L 02/21/17 21:53250000EPA 300.0
Chloride 4970 ug/L 02/24/17 02:531000SM 4500-Cl-E
92330376005 3901-MW3R
Barium 18.6J ug/L 02/24/17 06:13100EPA 6010
Chromium 2.9J ug/L 02/24/17 06:1310.0EPA 6010
Iron 1400 ug/L 02/24/17 06:13300EPA 6010
Manganese 246 ug/L 02/24/17 06:1350.0EPA 6010
Nickel 8.8J ug/L 02/24/17 06:1350.0EPA 6010
Zinc 8.0J ug/L 02/24/17 06:1310.0EPA 6010
Alkalinity, Total as CaCO3 92800 ug/L 02/24/17 02:185000SM 2320B
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 87
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92330376005 3901-MW3R
Total Dissolved Solids 154000 ug/L 02/21/17 02:0725000SM 2540C
Sulfate 7860J ug/L 02/21/17 22:02250000EPA 300.0
Chloride 29300 ug/L 02/24/17 02:542000SM 4500-Cl-E
92330376006 3901-MW4R
Barium 37.2J ug/L 02/24/17 06:16100EPA 6010
Iron 104J ug/L 02/24/17 06:16300EPA 6010
Manganese 1390 ug/L 02/24/17 06:1650.0EPA 6010
Alkalinity, Total as CaCO3 300000 ug/L 02/24/17 02:305000SM 2320B
Total Dissolved Solids 438000 ug/L 02/21/17 02:0825000SM 2540C
Sulfate 7940J ug/L 02/21/17 22:11250000EPA 300.0
Chloride 59100 ug/L 02/24/17 02:585000SM 4500-Cl-E
92330376007 3901-MW6R
Barium 102 ug/L 02/24/17 06:19100EPA 6010
Iron 944 ug/L 02/24/17 06:19300EPA 6010
Manganese 2210 ug/L 02/24/17 06:1950.0EPA 6010
Alkalinity, Total as CaCO3 183000 ug/L 02/24/17 02:445000SM 2320B
Total Dissolved Solids 481000 ug/L 02/21/17 02:0825000SM 2540C
Sulfate 3260J ug/L 02/21/17 22:20250000EPA 300.0
Chloride 142000 ug/L 02/24/17 02:595000SM 4500-Cl-E
92330376008 3901-SW1
Barium 285 ug/L 02/24/17 06:22100EPA 6010
Chromium 6.1J ug/L 02/24/17 06:2210.0EPA 6010
Cobalt 4.0J ug/L 02/24/17 06:2210.0EPA 6010
Copper 5.8J ug/L 02/24/17 06:2210.0EPA 6010
Lead 2.5J ug/L 02/24/17 06:2210.0EPA 6010
Nickel 4.2J ug/L 02/24/17 06:2250.0EPA 6010
Vanadium 18.2J ug/L 02/24/17 06:2225.0EPA 6010
Zinc 11.0 ug/L 02/24/17 06:2210.0EPA 6010
92330376009 3901-SW2
Barium 38.2J ug/L 02/24/17 06:25100EPA 6010
Chromium 7.2J ug/L 02/24/17 06:2510.0EPA 6010
Copper 5.2J ug/L 02/24/17 06:2510.0EPA 6010
Lead 2.5J ug/L 02/24/17 06:2510.0EPA 6010
Nickel 4.1J ug/L 02/24/17 06:2550.0EPA 6010
Vanadium 20.8J ug/L 02/24/17 06:2525.0EPA 6010
Zinc 9.6J ug/L 02/24/17 06:2510.0EPA 6010
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/26/17 23:47 309-00-202/17/17 13:380.050 0.050 1
alpha-BHC ND ug/L 02/26/17 23:47 319-84-602/17/17 13:380.050 0.050 1
beta-BHC ND ug/L 02/26/17 23:47 319-85-702/17/17 13:380.050 0.050 1
delta-BHC ND ug/L 02/26/17 23:47 319-86-802/17/17 13:380.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/26/17 23:47 58-89-902/17/17 13:380.050 0.050 1
Chlordane (Technical)ND ug/L 02/26/17 23:47 57-74-902/17/17 13:380.50 0.20 1
4,4'-DDD ND ug/L 02/26/17 23:47 72-54-802/17/17 13:380.10 0.050 1
4,4'-DDE ND ug/L 02/26/17 23:47 72-55-902/17/17 13:380.10 0.050 1
4,4'-DDT ND ug/L 02/26/17 23:47 50-29-302/17/17 13:380.10 0.050 1
Dieldrin ND ug/L 02/26/17 23:47 60-57-102/17/17 13:380.075 0.050 1
Endosulfan I ND ug/L 02/26/17 23:47 959-98-802/17/17 13:380.10 0.050 1
Endosulfan II ND ug/L 02/26/17 23:47 33213-65-902/17/17 13:380.10 0.050 1
Endosulfan sulfate ND ug/L 02/26/17 23:47 1031-07-802/17/17 13:380.10 0.050 1
Endrin ND ug/L 02/26/17 23:47 72-20-802/17/17 13:380.10 0.050 1
Endrin aldehyde ND ug/L 02/26/17 23:47 7421-93-402/17/17 13:380.10 0.050 1
Heptachlor ND ug/L 02/26/17 23:47 76-44-802/17/17 13:380.050 0.050 1
Heptachlor epoxide ND ug/L 02/26/17 23:47 1024-57-302/17/17 13:380.075 0.050 1
Methoxychlor ND ug/L 02/26/17 23:47 72-43-502/17/17 13:381.0 0.15 1
Toxaphene ND ug/L 02/26/17 23:47 8001-35-202/17/17 13:381.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)89 %02/26/17 23:47 877-09-802/17/17 13:3820-130 1
Decachlorobiphenyl (S)54 %02/26/17 23:47 2051-24-302/17/17 13:3820-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/18/17 04:10 12674-11-202/17/17 09:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/18/17 04:10 11104-28-202/17/17 09:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/18/17 04:10 11141-16-502/17/17 09:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/18/17 04:10 53469-21-902/17/17 09:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/18/17 04:10 12672-29-602/17/17 09:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/18/17 04:10 11097-69-102/17/17 09:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/18/17 04:10 11096-82-502/17/17 09:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)81 %02/18/17 04:10 2051-24-302/17/17 09:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/24/17 09:15 94-75-702/20/17 07:300.93 0.22 1
Dinoseb ND ug/L 02/24/17 09:15 88-85-702/20/17 07:300.19 0.056 1
2,4,5-T ND ug/L 02/24/17 09:15 93-76-502/20/17 07:300.19 0.041 1
2,4,5-TP (Silvex)ND ug/L 02/24/17 09:15 93-72-102/20/17 07:300.19 0.048 1
Surrogates
2,4-DCAA (S)86 %02/24/17 09:15 19719-28-902/20/17 07:3039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 15:36 7440-36-002/18/17 01:006.0 3.9 1
Arsenic ND ug/L 02/24/17 15:36 7440-38-202/18/17 01:0010.0 5.0 1
Barium 6.1J ug/L 02/24/17 15:36 7440-39-302/18/17 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/24/17 15:36 7440-41-702/18/17 01:001.0 0.50 1
Cadmium ND ug/L 02/24/17 15:36 7440-43-902/18/17 01:001.0 0.50 1
Chromium ND ug/L 02/24/17 15:36 7440-47-302/18/17 01:0010.0 2.5 1
Cobalt ND ug/L 02/24/17 15:36 7440-48-402/18/17 01:0010.0 2.5 1
Copper ND ug/L 02/24/17 15:36 7440-50-802/18/17 01:0010.0 2.5 1
Iron 633 ug/L 02/24/17 15:36 7439-89-602/18/17 01:00300 25.0 1
Lead ND ug/L 02/24/17 15:36 7439-92-102/18/17 01:0010.0 2.5 1
Manganese 15.5J ug/L 02/24/17 15:36 7439-96-502/18/17 01:0050.0 2.5 1
Nickel ND ug/L 02/24/17 15:36 7440-02-002/18/17 01:0050.0 2.5 1
Selenium ND ug/L 02/24/17 15:36 7782-49-202/18/17 01:0010.0 5.0 1
Silver ND ug/L 02/24/17 15:36 7440-22-402/18/17 01:0010.0 2.5 1
Tin ND ug/L 02/24/17 15:36 7440-31-502/18/17 01:00100 2.5 1
Vanadium ND ug/L 02/24/17 15:36 7440-62-202/18/17 01:0025.0 2.5 1
Zinc ND ug/L 02/24/17 15:36 7440-66-602/18/17 01:0010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:06 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:38 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 17:14 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 17:14 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 17:14 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 17:14 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 17:14 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 17:14 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 17:14 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 17:14 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 17:14 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 17:14 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 17:14 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 17:14 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 17:14 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 17:14 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 17:14 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 17:14 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 17:14 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 17:14 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 17:14 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 17:14 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 17:14 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 17:14 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 17:14 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 17:14 2303-16-402/17/17 11:0710.0 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenz(a,h)anthracene ND ug/L 02/20/17 17:14 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 17:14 132-64-902/17/17 11:0710.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/20/17 17:14 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 17:14 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 17:14 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 17:14 84-66-202/17/17 11:076000 1.3 1
Dimethoate ND ug/L 02/20/17 17:14 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 17:14 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 17:14 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 17:14 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 17:14 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 17:14 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 17:14 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 17:14 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 17:14 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 17:14 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 17:14 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 17:14 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 17:14 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 17:14 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 17:14 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 17:14 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 17:14 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 17:14 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 17:14 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 17:14 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 17:14 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 17:14 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 17:14 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 17:14 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 17:14 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 17:14 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 17:14 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 17:14 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 17:14 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 17:14 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 17:14 91-80-502/17/17 11:07100 2.7 1
3-Methylcholanthrene ND ug/L 02/20/17 17:14 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 17:14 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 17:14 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 17:14 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 17:14 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 17:1402/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 17:14 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 17:14 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 17:14 130-15-402/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Nitroaniline ND ug/L 02/20/17 17:14 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 17:14 99-09-202/17/17 11:0750.0 2.4 1
4-Nitroaniline ND ug/L 02/20/17 17:14 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 17:14 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 17:14 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 17:14 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 17:14 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 17:14 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 17:14 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 17:14 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 17:14 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 17:14 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 17:14 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 17:14 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 17:14 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 17:14 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 17:14 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 17:14 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 17:14 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 17:14 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 17:14 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 17:14 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 17:14 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 17:1402/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 17:14 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 17:14 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 17:14 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 17:14 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 17:14 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 17:14 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 17:14 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 17:14 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 17:14 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 17:14 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 17:14 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 17:14 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)64 %02/20/17 17:14 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)57 %02/20/17 17:14 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)73 %02/20/17 17:14 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)16 %02/20/17 17:14 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)25 %02/20/17 17:14 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)64 %02/20/17 17:14 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 16:22 67-64-1100 10.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetonitrile ND ug/L 02/21/17 16:22 75-05-855.0 2.2 1
Acrolein ND ug/L 02/21/17 16:22 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/21/17 16:22 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/21/17 16:22 107-05-110.0 1.5 1
Benzene ND ug/L 02/21/17 16:22 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 16:22 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 16:22 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 16:22 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 16:22 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 16:22 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 16:22 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 16:22 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 16:22 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 16:22 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 16:22 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 16:22 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/21/17 16:22 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 16:22 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 16:22 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 16:22 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 16:22 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 16:22 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/21/17 16:22 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/21/17 16:22 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 16:22 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/21/17 16:22 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/21/17 16:22 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 16:22 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 16:22 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 16:22 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 16:22 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 16:22 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/21/17 16:22 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/21/17 16:22 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/21/17 16:22 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 16:22 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 16:22 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 16:22 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/21/17 16:22 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/21/17 16:22 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 16:22 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/21/17 16:22 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/21/17 16:22 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/21/17 16:22 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/21/17 16:22 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 16:22 108-10-1100 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW7 Lab ID: 92330376001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Naphthalene ND ug/L 02/21/17 16:22 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/21/17 16:22 107-12-0150 3.6 1
Styrene ND ug/L 02/21/17 16:22 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 16:22 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 16:22 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 16:22 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 16:22 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 16:22 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/21/17 16:22 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/21/17 16:22 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 16:22 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 16:22 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 16:22 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 16:22 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 16:22 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 16:22 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 16:22 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/21/17 16:22 460-00-470-130 1
1,2-Dichloroethane-d4 (S)107 %02/21/17 16:22 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 16:22 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 115000 ug/L 02/24/17 01:215000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 233000 ug/L 02/21/17 02:0525000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 47100J ug/L 02/22/17 13:17 14808-79-8 M11250000 5000 5
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 10900 ug/L 02/24/17 02:48 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/23/17 18:19 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/27/17 00:05 309-00-202/17/17 13:380.050 0.050 1
alpha-BHC ND ug/L 02/27/17 00:05 319-84-602/17/17 13:380.050 0.050 1
beta-BHC ND ug/L 02/27/17 00:05 319-85-702/17/17 13:380.050 0.050 1
delta-BHC ND ug/L 02/27/17 00:05 319-86-802/17/17 13:380.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/27/17 00:05 58-89-902/17/17 13:380.050 0.050 1
Chlordane (Technical)ND ug/L 02/27/17 00:05 57-74-902/17/17 13:380.50 0.20 1
4,4'-DDD ND ug/L 02/27/17 00:05 72-54-802/17/17 13:380.10 0.050 1
4,4'-DDE ND ug/L 02/27/17 00:05 72-55-902/17/17 13:380.10 0.050 1
4,4'-DDT ND ug/L 02/27/17 00:05 50-29-302/17/17 13:380.10 0.050 1
Dieldrin ND ug/L 02/27/17 00:05 60-57-102/17/17 13:380.075 0.050 1
Endosulfan I ND ug/L 02/27/17 00:05 959-98-802/17/17 13:380.10 0.050 1
Endosulfan II ND ug/L 02/27/17 00:05 33213-65-902/17/17 13:380.10 0.050 1
Endosulfan sulfate ND ug/L 02/27/17 00:05 1031-07-802/17/17 13:380.10 0.050 1
Endrin ND ug/L 02/27/17 00:05 72-20-802/17/17 13:380.10 0.050 1
Endrin aldehyde ND ug/L 02/27/17 00:05 7421-93-402/17/17 13:380.10 0.050 1
Heptachlor ND ug/L 02/27/17 00:05 76-44-802/17/17 13:380.050 0.050 1
Heptachlor epoxide ND ug/L 02/27/17 00:05 1024-57-302/17/17 13:380.075 0.050 1
Methoxychlor ND ug/L 02/27/17 00:05 72-43-502/17/17 13:381.0 0.15 1
Toxaphene ND ug/L 02/27/17 00:05 8001-35-202/17/17 13:381.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)78 %02/27/17 00:05 877-09-802/17/17 13:3820-130 1
Decachlorobiphenyl (S)83 %02/27/17 00:05 2051-24-302/17/17 13:3820-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/18/17 04:30 12674-11-202/17/17 09:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/18/17 04:30 11104-28-202/17/17 09:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/18/17 04:30 11141-16-502/17/17 09:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/18/17 04:30 53469-21-902/17/17 09:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/18/17 04:30 12672-29-602/17/17 09:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/18/17 04:30 11097-69-102/17/17 09:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/18/17 04:30 11096-82-502/17/17 09:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)117 %02/18/17 04:30 2051-24-302/17/17 09:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/24/17 09:45 94-75-702/20/17 07:300.93 0.22 1
Dinoseb ND ug/L 02/24/17 09:45 88-85-702/20/17 07:300.19 0.056 1
2,4,5-T ND ug/L 02/24/17 09:45 93-76-502/20/17 07:300.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 02/24/17 09:45 93-72-102/20/17 07:300.19 0.048 1
Surrogates
2,4-DCAA (S)90 %02/24/17 09:45 19719-28-902/20/17 07:3039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 15:39 7440-36-002/18/17 01:006.0 3.9 1
Arsenic ND ug/L 02/24/17 15:39 7440-38-202/18/17 01:0010.0 5.0 1
Barium 38.9J ug/L 02/24/17 15:39 7440-39-302/18/17 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/24/17 15:39 7440-41-702/18/17 01:001.0 0.50 1
Cadmium ND ug/L 02/24/17 15:39 7440-43-902/18/17 01:001.0 0.50 1
Chromium 3.1J ug/L 02/24/17 15:39 7440-47-302/18/17 01:0010.0 2.5 1
Cobalt ND ug/L 02/24/17 15:39 7440-48-402/18/17 01:0010.0 2.5 1
Copper ND ug/L 02/24/17 15:39 7440-50-802/18/17 01:0010.0 2.5 1
Iron 30.4J ug/L 02/24/17 15:39 7439-89-602/18/17 01:00300 25.0 1
Lead ND ug/L 02/24/17 15:39 7439-92-102/18/17 01:0010.0 2.5 1
Manganese 91.4 ug/L 02/24/17 15:39 7439-96-502/18/17 01:0050.0 2.5 1
Nickel ND ug/L 02/24/17 15:39 7440-02-002/18/17 01:0050.0 2.5 1
Selenium ND ug/L 02/24/17 15:39 7782-49-202/18/17 01:0010.0 5.0 1
Silver ND ug/L 02/24/17 15:39 7440-22-402/18/17 01:0010.0 2.5 1
Tin ND ug/L 02/24/17 15:39 7440-31-502/18/17 01:00100 2.5 1
Vanadium ND ug/L 02/24/17 15:39 7440-62-202/18/17 01:0025.0 2.5 1
Zinc ND ug/L 02/24/17 15:39 7440-66-602/18/17 01:0010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:14 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:40 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 17:42 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 17:42 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 17:42 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 17:42 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 17:42 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 17:42 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 17:42 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 17:42 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 17:42 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 17:42 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 17:42 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 17:42 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 17:42 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 17:42 85-68-7 M102/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 17:42 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 17:42 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 17:42 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 17:42 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 17:42 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 17:42 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 17:42 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 17:42 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 17:42 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 17:42 2303-16-402/17/17 11:0710.0 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenz(a,h)anthracene ND ug/L 02/20/17 17:42 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 17:42 132-64-902/17/17 11:0710.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/20/17 17:42 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 17:42 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 17:42 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 17:42 84-66-202/17/17 11:076000 1.3 1
Dimethoate ND ug/L 02/20/17 17:42 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 17:42 60-11-7 M102/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 17:42 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 17:42 119-93-7 M102/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 17:42 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 17:42 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 17:42 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 17:42 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 17:42 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 17:42 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 17:42 121-14-2 M102/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 17:42 606-20-2 M102/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 17:42 117-84-0 M102/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 17:42 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 17:42 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 17:42 117-81-7 M102/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 17:42 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 17:42 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 17:42 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 17:42 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 17:42 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 17:42 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 17:42 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 17:42 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 17:42 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 17:42 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 17:42 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 17:42 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 17:42 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 17:42 143-50-0 M102/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 17:42 91-80-502/17/17 11:07100 2.7 1
3-Methylcholanthrene ND ug/L 02/20/17 17:42 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 17:42 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 17:42 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 17:42 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 17:42 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 17:4202/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 17:42 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 17:42 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 17:42 130-15-402/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Nitroaniline ND ug/L 02/20/17 17:42 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 17:42 99-09-202/17/17 11:0750.0 2.4 1
4-Nitroaniline ND ug/L 02/20/17 17:42 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 17:42 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 17:42 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 17:42 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 17:42 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 17:42 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 17:42 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 17:42 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 17:42 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 17:42 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 17:42 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 17:42 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 17:42 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 17:42 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 17:42 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 17:42 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 17:42 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 17:42 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 17:42 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 17:42 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 17:42 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 17:4202/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 17:42 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 17:42 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 17:42 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 17:42 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 17:42 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 17:42 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 17:42 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 17:42 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 17:42 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 17:42 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 17:42 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 17:42 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)65 %02/20/17 17:42 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)63 %02/20/17 17:42 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)67 %02/20/17 17:42 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)17 %02/20/17 17:42 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)26 %02/20/17 17:42 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)75 %02/20/17 17:42 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 17:11 67-64-1100 10.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 18 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetonitrile ND ug/L 02/21/17 17:11 75-05-855.0 2.2 1
Acrolein ND ug/L 02/21/17 17:11 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/21/17 17:11 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/21/17 17:11 107-05-110.0 1.5 1
Benzene ND ug/L 02/21/17 17:11 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 17:11 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 17:11 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 17:11 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 17:11 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 17:11 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 17:11 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 17:11 56-23-51.0 0.25 1
Chlorobenzene 0.90J ug/L 02/21/17 17:11 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 17:11 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 17:11 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 17:11 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/21/17 17:11 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 17:11 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 17:11 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 17:11 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 17:11 74-95-310.0 0.21 1
1,2-Dichlorobenzene 1.1J ug/L 02/21/17 17:11 95-50-15.0 0.30 1
1,3-Dichlorobenzene 0.38J ug/L 02/21/17 17:11 541-73-15.0 0.24 1
1,4-Dichlorobenzene 1.1 ug/L 02/21/17 17:11 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 17:11 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/21/17 17:11 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/21/17 17:11 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 17:11 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 17:11 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 17:11 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 17:11 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 17:11 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/21/17 17:11 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/21/17 17:11 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/21/17 17:11 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 17:11 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 17:11 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 17:11 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/21/17 17:11 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/21/17 17:11 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 17:11 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/21/17 17:11 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/21/17 17:11 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/21/17 17:11 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/21/17 17:11 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 17:11 108-10-1100 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 19 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW5R Lab ID: 92330376002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Naphthalene ND ug/L 02/21/17 17:11 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/21/17 17:11 107-12-0150 3.6 1
Styrene ND ug/L 02/21/17 17:11 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 17:11 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 17:11 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 17:11 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 17:11 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 17:11 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/21/17 17:11 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/21/17 17:11 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 17:11 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 17:11 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 17:11 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 17:11 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 17:11 108-05-450.0 0.35 1
Vinyl chloride 1.4 ug/L 02/21/17 17:11 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 17:11 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %02/21/17 17:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %02/21/17 17:11 17060-07-070-130 1
Toluene-d8 (S)114 %02/21/17 17:11 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 175000 ug/L 02/24/17 01:345000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 277000 ug/L 02/21/17 02:0625000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3510J ug/L 02/21/17 21:17 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 49200 ug/L 02/24/17 02:49 16887-00-6 M1,R15000 2500 5
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/23/17 18:20 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 02/27/17 00:23 309-00-202/17/17 13:380.050 0.050 1
alpha-BHC ND ug/L 02/27/17 00:23 319-84-602/17/17 13:380.050 0.050 1
beta-BHC ND ug/L 02/27/17 00:23 319-85-702/17/17 13:380.050 0.050 1
delta-BHC ND ug/L 02/27/17 00:23 319-86-802/17/17 13:380.050 0.050 1
gamma-BHC (Lindane)ND ug/L 02/27/17 00:23 58-89-902/17/17 13:380.050 0.050 1
Chlordane (Technical)ND ug/L 02/27/17 00:23 57-74-902/17/17 13:380.50 0.20 1
4,4'-DDD ND ug/L 02/27/17 00:23 72-54-802/17/17 13:380.10 0.050 1
4,4'-DDE ND ug/L 02/27/17 00:23 72-55-902/17/17 13:380.10 0.050 1
4,4'-DDT ND ug/L 02/27/17 00:23 50-29-302/17/17 13:380.10 0.050 1
Dieldrin ND ug/L 02/27/17 00:23 60-57-102/17/17 13:380.075 0.050 1
Endosulfan I ND ug/L 02/27/17 00:23 959-98-802/17/17 13:380.10 0.050 1
Endosulfan II ND ug/L 02/27/17 00:23 33213-65-902/17/17 13:380.10 0.050 1
Endosulfan sulfate ND ug/L 02/27/17 00:23 1031-07-802/17/17 13:380.10 0.050 1
Endrin ND ug/L 02/27/17 00:23 72-20-802/17/17 13:380.10 0.050 1
Endrin aldehyde ND ug/L 02/27/17 00:23 7421-93-402/17/17 13:380.10 0.050 1
Heptachlor ND ug/L 02/27/17 00:23 76-44-802/17/17 13:380.050 0.050 1
Heptachlor epoxide ND ug/L 02/27/17 00:23 1024-57-302/17/17 13:380.075 0.050 1
Methoxychlor ND ug/L 02/27/17 00:23 72-43-502/17/17 13:381.0 0.15 1
Toxaphene ND ug/L 02/27/17 00:23 8001-35-202/17/17 13:381.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)82 %02/27/17 00:23 877-09-802/17/17 13:3820-130 1
Decachlorobiphenyl (S)77 %02/27/17 00:23 2051-24-302/17/17 13:3820-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 02/18/17 04:50 12674-11-202/17/17 09:000.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 02/18/17 04:50 11104-28-202/17/17 09:000.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 02/18/17 04:50 11141-16-502/17/17 09:000.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 02/18/17 04:50 53469-21-902/17/17 09:000.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 02/18/17 04:50 12672-29-602/17/17 09:000.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 02/18/17 04:50 11097-69-102/17/17 09:000.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 02/18/17 04:50 11096-82-502/17/17 09:000.50 0.50 1
Surrogates
Decachlorobiphenyl (S)123 %02/18/17 04:50 2051-24-302/17/17 09:0010-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 02/24/17 10:15 94-75-702/20/17 07:300.90 0.21 1
Dinoseb ND ug/L 02/24/17 10:15 88-85-702/20/17 07:300.18 0.055 1
2,4,5-T ND ug/L 02/24/17 10:15 93-76-502/20/17 07:300.18 0.040 1
2,4,5-TP (Silvex)ND ug/L 02/24/17 10:15 93-72-102/20/17 07:300.18 0.047 1
Surrogates
2,4-DCAA (S)85 %02/24/17 10:15 19719-28-902/20/17 07:3039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 15:42 7440-36-002/18/17 01:006.0 3.9 1
Arsenic ND ug/L 02/24/17 15:42 7440-38-202/18/17 01:0010.0 5.0 1
Barium ND ug/L 02/24/17 15:42 7440-39-302/18/17 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Beryllium ND ug/L 02/24/17 15:42 7440-41-702/18/17 01:001.0 0.50 1
Cadmium ND ug/L 02/24/17 15:42 7440-43-902/18/17 01:001.0 0.50 1
Chromium ND ug/L 02/24/17 15:42 7440-47-302/18/17 01:0010.0 2.5 1
Cobalt ND ug/L 02/24/17 15:42 7440-48-402/18/17 01:0010.0 2.5 1
Copper ND ug/L 02/24/17 15:42 7440-50-802/18/17 01:0010.0 2.5 1
Iron ND ug/L 02/24/17 15:42 7439-89-602/18/17 01:00300 25.0 1
Lead ND ug/L 02/24/17 15:42 7439-92-102/18/17 01:0010.0 2.5 1
Manganese ND ug/L 02/24/17 15:42 7439-96-502/18/17 01:0050.0 2.5 1
Nickel ND ug/L 02/24/17 15:42 7440-02-002/18/17 01:0050.0 2.5 1
Selenium ND ug/L 02/24/17 15:42 7782-49-202/18/17 01:0010.0 5.0 1
Silver ND ug/L 02/24/17 15:42 7440-22-402/18/17 01:0010.0 2.5 1
Tin ND ug/L 02/24/17 15:42 7440-31-502/18/17 01:00100 2.5 1
Vanadium ND ug/L 02/24/17 15:42 7440-62-202/18/17 01:0025.0 2.5 1
Zinc ND ug/L 02/24/17 15:42 7440-66-602/18/17 01:0010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:16 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:43 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 02/20/17 18:09 83-32-902/17/17 11:0710.0 0.25 1
Acenaphthylene ND ug/L 02/20/17 18:09 208-96-802/17/17 11:0710.0 0.21 1
Acetophenone ND ug/L 02/20/17 18:09 98-86-202/17/17 11:0710.0 2.0 1
2-Acetylaminofluorene ND ug/L 02/20/17 18:09 53-96-302/17/17 11:0720.0 0.84 1
4-Aminobiphenyl ND ug/L 02/20/17 18:09 92-67-102/17/17 11:0720.0 0.92 1
Anthracene ND ug/L 02/20/17 18:09 120-12-702/17/17 11:0710.0 0.14 1
Benzo(a)anthracene ND ug/L 02/20/17 18:09 56-55-302/17/17 11:0710.0 0.33 1
Benzo(a)pyrene ND ug/L 02/20/17 18:09 50-32-802/17/17 11:0710.0 0.30 1
Benzo(b)fluoranthene ND ug/L 02/20/17 18:09 205-99-202/17/17 11:0710.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 02/20/17 18:09 191-24-202/17/17 11:0710.0 0.38 1
Benzo(k)fluoranthene ND ug/L 02/20/17 18:09 207-08-902/17/17 11:0710.0 0.43 1
Benzyl alcohol ND ug/L 02/20/17 18:09 100-51-602/17/17 11:0720.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 02/20/17 18:09 101-55-302/17/17 11:0710.0 1.3 1
Butylbenzylphthalate ND ug/L 02/20/17 18:09 85-68-702/17/17 11:0710.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 02/20/17 18:09 59-50-702/17/17 11:0720.0 4.2 1
4-Chloroaniline ND ug/L 02/20/17 18:09 106-47-802/17/17 11:0720.0 3.4 1
Chlorobenzilate ND ug/L 02/20/17 18:09 510-15-602/17/17 11:0710.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 02/20/17 18:09 111-91-102/17/17 11:0710.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 02/20/17 18:09 111-44-402/17/17 11:0710.0 1.5 1
2-Chloronaphthalene ND ug/L 02/20/17 18:09 91-58-702/17/17 11:0710.0 2.2 1
2-Chlorophenol ND ug/L 02/20/17 18:09 95-57-802/17/17 11:0710.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 02/20/17 18:09 7005-72-302/17/17 11:0710.0 2.1 1
Chrysene ND ug/L 02/20/17 18:09 218-01-902/17/17 11:0710.0 0.21 1
Diallate ND ug/L 02/20/17 18:09 2303-16-402/17/17 11:0710.0 1.3 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Dibenz(a,h)anthracene ND ug/L 02/20/17 18:09 53-70-302/17/17 11:0710.0 0.55 1
Dibenzofuran ND ug/L 02/20/17 18:09 132-64-902/17/17 11:0710.0 1.8 1
3,3'-Dichlorobenzidine ND ug/L 02/20/17 18:09 91-94-102/17/17 11:0720.0 1.4 1
2,4-Dichlorophenol ND ug/L 02/20/17 18:09 120-83-202/17/17 11:0710.0 1.7 1
2,6-Dichlorophenol ND ug/L 02/20/17 18:09 87-65-002/17/17 11:0710.0 1.8 1
Diethylphthalate ND ug/L 02/20/17 18:09 84-66-202/17/17 11:076000 1.3 1
Dimethoate ND ug/L 02/20/17 18:09 60-51-502/17/17 11:0720.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 02/20/17 18:09 60-11-702/17/17 11:0710.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 02/20/17 18:09 57-97-602/17/17 11:0710.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 02/20/17 18:09 119-93-702/17/17 11:0710.0 2.1 1
2,4-Dimethylphenol ND ug/L 02/20/17 18:09 105-67-902/17/17 11:0710.0 2.2 1
Dimethylphthalate ND ug/L 02/20/17 18:09 131-11-302/17/17 11:0710.0 1.5 1
Di-n-butylphthalate ND ug/L 02/20/17 18:09 84-74-202/17/17 11:0710.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 02/20/17 18:09 534-52-102/17/17 11:0750.0 1.7 1
1,3-Dinitrobenzene ND ug/L 02/20/17 18:09 99-65-002/17/17 11:0720.0 1.5 1
2,4-Dinitrophenol ND ug/L 02/20/17 18:09 51-28-502/17/17 11:0750.0 6.5 1
2,4-Dinitrotoluene ND ug/L 02/20/17 18:09 121-14-202/17/17 11:0710.0 1.2 1
2,6-Dinitrotoluene ND ug/L 02/20/17 18:09 606-20-202/17/17 11:0710.0 1.7 1
Di-n-octylphthalate ND ug/L 02/20/17 18:09 117-84-002/17/17 11:0710.0 0.86 1
Diphenylamine ND ug/L 02/20/17 18:09 122-39-402/17/17 11:0710.0 1.3 1
Disulfoton ND ug/L 02/20/17 18:09 298-04-402/17/17 11:0710.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 02/20/17 18:09 117-81-702/17/17 11:0715.0 0.85 1
Ethyl methanesulfonate ND ug/L 02/20/17 18:09 62-50-002/17/17 11:0720.0 1.8 1
Famphur ND ug/L 02/20/17 18:09 52-85-702/17/17 11:0720.0 1.7 1
Fluoranthene ND ug/L 02/20/17 18:09 206-44-002/17/17 11:0710.0 0.21 1
Fluorene ND ug/L 02/20/17 18:09 86-73-702/17/17 11:0710.0 0.21 1
Hexachloro-1,3-butadiene ND ug/L 02/20/17 18:09 87-68-302/17/17 11:0710.0 1.8 1
Hexachlorobenzene ND ug/L 02/20/17 18:09 118-74-102/17/17 11:0710.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 02/20/17 18:09 77-47-402/17/17 11:0710.0 1.8 1
Hexachloroethane ND ug/L 02/20/17 18:09 67-72-102/17/17 11:0710.0 1.5 1
Hexachloropropene ND ug/L 02/20/17 18:09 1888-71-702/17/17 11:0710.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 02/20/17 18:09 193-39-502/17/17 11:0710.0 0.29 1
Isodrin ND ug/L 02/20/17 18:09 465-73-602/17/17 11:0720.0 2.0 1
Isophorone ND ug/L 02/20/17 18:09 78-59-102/17/17 11:0710.0 1.8 1
Isosafrole ND ug/L 02/20/17 18:09 120-58-102/17/17 11:0710.0 1.8 1
Kepone ND ug/L 02/20/17 18:09 143-50-002/17/17 11:0720.0 3.1 1
Methapyrilene ND ug/L 02/20/17 18:09 91-80-502/17/17 11:07100 2.7 1
3-Methylcholanthrene ND ug/L 02/20/17 18:09 56-49-502/17/17 11:0710.0 0.82 1
Methyl methanesulfonate ND ug/L 02/20/17 18:09 66-27-302/17/17 11:0710.0 1.3 1
2-Methylnaphthalene ND ug/L 02/20/17 18:09 91-57-602/17/17 11:0710.0 0.28 1
Methyl parathion ND ug/L 02/20/17 18:09 298-00-002/17/17 11:0710.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 02/20/17 18:09 95-48-702/17/17 11:0710.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 02/20/17 18:0902/17/17 11:0710.0 1.7 1
1-Naphthalenamine ND ug/L 02/20/17 18:09 134-32-702/17/17 11:0710.0 0.96 1
2-Naphthalenamine ND ug/L 02/20/17 18:09 91-59-802/17/17 11:0710.0 0.98 1
1,4-Naphthoquinone ND ug/L 02/20/17 18:09 130-15-402/17/17 11:0710.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 23 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
2-Nitroaniline ND ug/L 02/20/17 18:09 88-74-402/17/17 11:0750.0 2.8 1
3-Nitroaniline ND ug/L 02/20/17 18:09 99-09-202/17/17 11:0750.0 2.4 1
4-Nitroaniline ND ug/L 02/20/17 18:09 100-01-602/17/17 11:0720.0 2.5 1
Nitrobenzene ND ug/L 02/20/17 18:09 98-95-302/17/17 11:0710.0 1.7 1
2-Nitrophenol ND ug/L 02/20/17 18:09 88-75-502/17/17 11:0710.0 1.7 1
4-Nitrophenol ND ug/L 02/20/17 18:09 100-02-702/17/17 11:0750.0 5.8 1
5-Nitro-o-toluidine ND ug/L 02/20/17 18:09 99-55-802/17/17 11:0710.0 1.2 1
N-Nitrosodiethylamine ND ug/L 02/20/17 18:09 55-18-502/17/17 11:0720.0 1.8 1
N-Nitrosodimethylamine ND ug/L 02/20/17 18:09 62-75-902/17/17 11:0710.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 02/20/17 18:09 924-16-302/17/17 11:0710.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 02/20/17 18:09 621-64-702/17/17 11:0710.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 02/20/17 18:09 86-30-602/17/17 11:0710.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 02/20/17 18:09 10595-95-602/17/17 11:0710.0 1.8 1
N-Nitrosopiperidine ND ug/L 02/20/17 18:09 100-75-402/17/17 11:0720.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 02/20/17 18:09 930-55-202/17/17 11:0710.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 02/20/17 18:09 126-68-102/17/17 11:0710.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 02/20/17 18:09 108-60-102/17/17 11:0710.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 02/20/17 18:09 56-38-202/17/17 11:0710.0 1.1 1
Pentachlorobenzene ND ug/L 02/20/17 18:09 608-93-502/17/17 11:0710.0 2.0 1
Pentachloronitrobenzene ND ug/L 02/20/17 18:09 82-68-802/17/17 11:0720.0 1.0 1
Pentachlorophenol ND ug/L 02/20/17 18:09 87-86-502/17/17 11:0725.0 2.3 1
Phenacetin ND ug/L 02/20/17 18:09 62-44-202/17/17 11:0720.0 0.97 1
Phenanthrene ND ug/L 02/20/17 18:09 85-01-802/17/17 11:0710.0 0.22 1
Phenol ND ug/L 02/20/17 18:0902/17/17 11:0710.0 1.7 1
p-Phenylenediamine ND ug/L 02/20/17 18:09 106-50-302/17/17 11:0710.0 0.96 1
Phorate ND ug/L 02/20/17 18:09 298-02-202/17/17 11:0710.0 1.1 1
Pronamide ND ug/L 02/20/17 18:09 23950-58-502/17/17 11:0710.0 0.97 1
Pyrene ND ug/L 02/20/17 18:09 129-00-002/17/17 11:0710.0 0.19 1
Safrole ND ug/L 02/20/17 18:09 94-59-702/17/17 11:0710.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 02/20/17 18:09 95-94-302/17/17 11:0710.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 02/20/17 18:09 58-90-202/17/17 11:0710.0 2.3 1
Thionazin ND ug/L 02/20/17 18:09 297-97-202/17/17 11:0720.0 1.2 1
O-Toluidine ND ug/L 02/20/17 18:09 95-53-402/17/17 11:0710.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 02/20/17 18:09 95-95-402/17/17 11:0710.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 02/20/17 18:09 88-06-202/17/17 11:0710.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 02/20/17 18:09 99-35-4 L1,L302/17/17 11:0710.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)86 %02/20/17 18:09 4165-60-002/17/17 11:0721-110 1
2-Fluorobiphenyl (S)81 %02/20/17 18:09 321-60-802/17/17 11:0727-110 1
Terphenyl-d14 (S)100 %02/20/17 18:09 1718-51-002/17/17 11:0731-107 1
Phenol-d6 (S)20 %02/20/17 18:09 13127-88-302/17/17 11:0710-110 1
2-Fluorophenol (S)34 %02/20/17 18:09 367-12-402/17/17 11:0712-110 1
2,4,6-Tribromophenol (S)81 %02/20/17 18:09 118-79-602/17/17 11:0727-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 11:48 67-64-1100 10.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetonitrile ND ug/L 02/21/17 11:48 75-05-855.0 2.2 1
Acrolein ND ug/L 02/21/17 11:48 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/21/17 11:48 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/21/17 11:48 107-05-110.0 1.5 1
Benzene ND ug/L 02/21/17 11:48 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 11:48 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 11:48 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 11:48 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 11:48 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 11:48 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 11:48 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 11:48 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 11:48 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 11:48 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 11:48 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 11:48 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/21/17 11:48 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 11:48 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 11:48 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 11:48 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 11:48 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 11:48 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/21/17 11:48 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/21/17 11:48 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 11:48 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/21/17 11:48 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/21/17 11:48 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 11:48 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 11:48 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 11:48 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 11:48 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 11:48 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/21/17 11:48 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/21/17 11:48 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/21/17 11:48 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 11:48 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 11:48 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 11:48 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/21/17 11:48 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/21/17 11:48 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 11:48 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/21/17 11:48 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/21/17 11:48 126-98-7100 0.93 1
Methylene Chloride 1.6 ug/L 02/21/17 11:48 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/21/17 11:48 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 11:48 108-10-1100 0.33 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: FIELD BLANK Lab ID: 92330376003 Collected: 02/15/17 11:40 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Naphthalene ND ug/L 02/21/17 11:48 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/21/17 11:48 107-12-0150 3.6 1
Styrene ND ug/L 02/21/17 11:48 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 11:48 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 11:48 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 11:48 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 11:48 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 11:48 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/21/17 11:48 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/21/17 11:48 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 11:48 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 11:48 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 11:48 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 11:48 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 11:48 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 11:48 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 11:48 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)97 %02/21/17 11:48 460-00-470-130 1
1,2-Dichloroethane-d4 (S)105 %02/21/17 11:48 17060-07-070-130 1
Toluene-d8 (S)99 %02/21/17 11:48 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 ND ug/L 02/24/17 01:475000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 02/21/17 02:0625000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate ND ug/L 02/21/17 21:44 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride ND ug/L 02/24/17 02:52 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 02/23/17 18:20 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW2 Lab ID: 92330376004 Collected: 02/14/17 11:24 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 15:45 7440-36-002/18/17 01:006.0 3.9 1
Arsenic ND ug/L 02/24/17 15:45 7440-38-202/18/17 01:0010.0 5.0 1
Barium 18.2J ug/L 02/24/17 15:45 7440-39-302/18/17 01:00100 2.5 1
Beryllium ND ug/L 02/24/17 15:45 7440-41-702/18/17 01:001.0 0.50 1
Cadmium ND ug/L 02/24/17 15:45 7440-43-902/18/17 01:001.0 0.50 1
Chromium 6.8J ug/L 02/24/17 15:45 7440-47-302/18/17 01:0010.0 2.5 1
Cobalt 11.3 ug/L 02/24/17 15:45 7440-48-402/18/17 01:0010.0 2.5 1
Copper 6.3J ug/L 02/24/17 15:45 7440-50-802/18/17 01:0010.0 2.5 1
Iron 6250 ug/L 02/24/17 15:45 7439-89-602/18/17 01:00300 25.0 1
Lead ND ug/L 02/24/17 15:45 7439-92-102/18/17 01:0010.0 2.5 1
Manganese 234 ug/L 02/24/17 15:45 7439-96-502/18/17 01:0050.0 2.5 1
Nickel 4.9J ug/L 02/24/17 15:45 7440-02-002/18/17 01:0050.0 2.5 1
Selenium ND ug/L 02/24/17 15:45 7782-49-202/18/17 01:0010.0 5.0 1
Silver ND ug/L 02/24/17 15:45 7440-22-402/18/17 01:0010.0 2.5 1
Vanadium 13.9J ug/L 02/24/17 15:45 7440-62-202/18/17 01:0025.0 2.5 1
Zinc 14.7 ug/L 02/24/17 15:45 7440-66-602/18/17 01:0010.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:18 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:45 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 16:06 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 16:06 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 16:06 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 16:06 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 16:06 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 16:06 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 16:06 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 16:06 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 16:06 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 16:06 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 16:06 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 16:06 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 16:06 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 16:06 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 16:06 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 16:06 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 16:06 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 16:06 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 16:06 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 16:06 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 16:06 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 16:06 75-34-35.0 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW2 Lab ID: 92330376004 Collected: 02/14/17 11:24 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloroethane ND ug/L 02/21/17 16:06 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 16:06 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 16:06 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 16:06 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 16:06 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 16:06 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 16:06 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 16:06 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 16:06 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 16:06 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 16:06 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 16:06 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 16:06 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 16:06 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 16:06 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 16:06 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 16:06 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 16:06 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 16:06 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 16:06 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 16:06 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 16:06 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 16:06 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 16:06 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 16:06 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 16:06 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/21/17 16:06 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %02/21/17 16:06 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 16:06 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 16000 ug/L 02/22/17 05:565000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 62000 ug/L 02/17/17 15:59 D625000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 11200J ug/L 02/21/17 21:53 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4970 ug/L 02/24/17 02:53 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW3R Lab ID: 92330376005 Collected: 02/15/17 08:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:13 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:13 7440-38-202/20/17 19:5510.0 5.0 1
Barium 18.6J ug/L 02/24/17 06:13 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:13 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:13 7440-43-902/20/17 19:551.0 0.50 1
Chromium 2.9J ug/L 02/24/17 06:13 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:13 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:13 7440-50-802/20/17 19:5510.0 2.5 1
Iron 1400 ug/L 02/24/17 06:13 7439-89-602/20/17 19:55300 25.0 1
Lead ND ug/L 02/24/17 06:13 7439-92-102/20/17 19:5510.0 2.5 1
Manganese 246 ug/L 02/24/17 06:13 7439-96-502/20/17 19:5550.0 2.5 1
Nickel 8.8J ug/L 02/24/17 06:13 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:13 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:13 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium ND ug/L 02/24/17 06:13 7440-62-202/20/17 19:5525.0 2.5 1
Zinc 8.0J ug/L 02/24/17 06:13 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:20 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:48 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 16:54 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 16:54 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 16:54 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 16:54 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 16:54 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 16:54 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 16:54 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 16:54 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 16:54 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 16:54 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 16:54 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 16:54 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 16:54 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 16:54 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 16:54 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 16:54 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 16:54 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 16:54 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 16:54 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 16:54 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 16:54 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 16:54 75-34-35.0 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW3R Lab ID: 92330376005 Collected: 02/15/17 08:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloroethane ND ug/L 02/21/17 16:54 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 16:54 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 16:54 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 16:54 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 16:54 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 16:54 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 16:54 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 16:54 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 16:54 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 16:54 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 16:54 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 16:54 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 16:54 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 16:54 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 16:54 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 16:54 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 16:54 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 16:54 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 16:54 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 16:54 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 16:54 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 16:54 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 16:54 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 16:54 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 16:54 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 16:54 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/21/17 16:54 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %02/21/17 16:54 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 16:54 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 92800 ug/L 02/24/17 02:185000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 154000 ug/L 02/21/17 02:0725000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 7860J ug/L 02/21/17 22:02 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 29300 ug/L 02/24/17 02:54 16887-00-62000 1000 2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW4R Lab ID: 92330376006 Collected: 02/15/17 09:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:16 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:16 7440-38-202/20/17 19:5510.0 5.0 1
Barium 37.2J ug/L 02/24/17 06:16 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:16 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:16 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:16 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:16 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:16 7440-50-802/20/17 19:5510.0 2.5 1
Iron 104J ug/L 02/24/17 06:16 7439-89-602/20/17 19:55300 25.0 1
Lead ND ug/L 02/24/17 06:16 7439-92-102/20/17 19:5510.0 2.5 1
Manganese 1390 ug/L 02/24/17 06:16 7439-96-502/20/17 19:5550.0 2.5 1
Nickel ND ug/L 02/24/17 06:16 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:16 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:16 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium ND ug/L 02/24/17 06:16 7440-62-202/20/17 19:5525.0 2.5 1
Zinc ND ug/L 02/24/17 06:16 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:22 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:50 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 17:27 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 17:27 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 17:27 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 17:27 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 17:27 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 17:27 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 17:27 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 17:27 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 17:27 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 17:27 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 17:27 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 17:27 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 17:27 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 17:27 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 17:27 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 17:27 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 17:27 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 17:27 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 17:27 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 17:27 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 17:27 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 17:27 75-34-35.0 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW4R Lab ID: 92330376006 Collected: 02/15/17 09:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloroethane ND ug/L 02/21/17 17:27 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 17:27 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 17:27 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 17:27 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 17:27 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 17:27 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 17:27 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 17:27 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 17:27 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 17:27 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 17:27 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 17:27 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 17:27 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 17:27 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 17:27 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 17:27 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 17:27 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 17:27 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 17:27 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 17:27 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 17:27 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 17:27 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 17:27 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 17:27 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 17:27 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 17:27 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)96 %02/21/17 17:27 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %02/21/17 17:27 17060-07-070-130 1
Toluene-d8 (S)116 %02/21/17 17:27 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 300000 ug/L 02/24/17 02:305000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 438000 ug/L 02/21/17 02:0825000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 7940J ug/L 02/21/17 22:11 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 59100 ug/L 02/24/17 02:58 16887-00-65000 2500 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW6R Lab ID: 92330376007 Collected: 02/15/17 09:56 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:19 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:19 7440-38-202/20/17 19:5510.0 5.0 1
Barium 102 ug/L 02/24/17 06:19 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:19 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:19 7440-43-902/20/17 19:551.0 0.50 1
Chromium ND ug/L 02/24/17 06:19 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:19 7440-48-402/20/17 19:5510.0 2.5 1
Copper ND ug/L 02/24/17 06:19 7440-50-802/20/17 19:5510.0 2.5 1
Iron 944 ug/L 02/24/17 06:19 7439-89-602/20/17 19:55300 25.0 1
Lead ND ug/L 02/24/17 06:19 7439-92-102/20/17 19:5510.0 2.5 1
Manganese 2210 ug/L 02/24/17 06:19 7439-96-502/20/17 19:5550.0 2.5 1
Nickel ND ug/L 02/24/17 06:19 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:19 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:19 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium ND ug/L 02/24/17 06:19 7440-62-202/20/17 19:5525.0 2.5 1
Zinc ND ug/L 02/24/17 06:19 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:23 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 02/23/17 17:52 7439-97-602/22/17 07:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 16:38 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 16:38 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 16:38 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 16:38 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 16:38 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 16:38 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 16:38 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 16:38 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 16:38 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 16:38 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 16:38 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 16:38 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 16:38 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 16:38 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 16:38 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 16:38 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 16:38 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 16:38 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 16:38 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 16:38 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 16:38 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 16:38 75-34-35.0 0.32 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-MW6R Lab ID: 92330376007 Collected: 02/15/17 09:56 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichloroethane ND ug/L 02/21/17 16:38 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 16:38 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 16:38 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 16:38 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 16:38 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 16:38 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 16:38 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 16:38 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 16:38 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 16:38 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 16:38 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 16:38 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 16:38 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 16:38 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 16:38 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 16:38 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 16:38 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 16:38 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 16:38 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 16:38 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 16:38 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 16:38 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 16:38 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 16:38 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 16:38 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 16:38 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)100 %02/21/17 16:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)108 %02/21/17 16:38 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 16:38 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 183000 ug/L 02/24/17 02:445000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 481000 ug/L 02/21/17 02:0825000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3260J ug/L 02/21/17 22:20 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 142000 ug/L 02/24/17 02:59 16887-00-65000 2500 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW1 Lab ID: 92330376008 Collected: 02/15/17 11:30 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:22 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:22 7440-38-202/20/17 19:5510.0 5.0 1
Barium 285 ug/L 02/24/17 06:22 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:22 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:22 7440-43-902/20/17 19:551.0 0.50 1
Chromium 6.1J ug/L 02/24/17 06:22 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt 4.0J ug/L 02/24/17 06:22 7440-48-402/20/17 19:5510.0 2.5 1
Copper 5.8J ug/L 02/24/17 06:22 7440-50-802/20/17 19:5510.0 2.5 1
Lead 2.5J ug/L 02/24/17 06:22 7439-92-102/20/17 19:5510.0 2.5 1
Nickel 4.2J ug/L 02/24/17 06:22 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:22 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:22 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 18.2J ug/L 02/24/17 06:22 7440-62-202/20/17 19:5525.0 2.5 1
Zinc 11.0 ug/L 02/24/17 06:22 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:25 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 15:47 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 15:47 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 15:47 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 15:47 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 15:47 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 15:47 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 15:47 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 15:47 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 15:47 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 15:47 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 15:47 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 15:47 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 15:47 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 15:47 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 15:47 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 15:47 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 15:47 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 15:47 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 15:47 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 15:47 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 15:47 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 15:47 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 15:47 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 15:47 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 15:47 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 15:47 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 15:47 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW1 Lab ID: 92330376008 Collected: 02/15/17 11:30 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/21/17 15:47 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 15:47 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 15:47 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 15:47 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 15:47 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 15:47 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 15:47 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 15:47 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 15:47 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 15:47 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 15:47 127-18-41.0 0.46 1
Toluene ND ug/L 02/21/17 15:47 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 15:47 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 15:47 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 15:47 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 15:47 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 15:47 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 15:47 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 15:47 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 15:47 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)99 %02/21/17 15:47 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %02/21/17 15:47 17060-07-070-130 1
Toluene-d8 (S)102 %02/21/17 15:47 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW2 Lab ID: 92330376009 Collected: 02/14/17 09:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 MET ICP
Antimony ND ug/L 02/24/17 06:25 7440-36-002/20/17 19:556.0 3.9 1
Arsenic ND ug/L 02/24/17 06:25 7440-38-202/20/17 19:5510.0 5.0 1
Barium 38.2J ug/L 02/24/17 06:25 7440-39-302/20/17 19:55100 2.5 1
Beryllium ND ug/L 02/24/17 06:25 7440-41-702/20/17 19:551.0 0.50 1
Cadmium ND ug/L 02/24/17 06:25 7440-43-902/20/17 19:551.0 0.50 1
Chromium 7.2J ug/L 02/24/17 06:25 7440-47-302/20/17 19:5510.0 2.5 1
Cobalt ND ug/L 02/24/17 06:25 7440-48-402/20/17 19:5510.0 2.5 1
Copper 5.2J ug/L 02/24/17 06:25 7440-50-802/20/17 19:5510.0 2.5 1
Lead 2.5J ug/L 02/24/17 06:25 7439-92-102/20/17 19:5510.0 2.5 1
Nickel 4.1J ug/L 02/24/17 06:25 7440-02-002/20/17 19:5550.0 2.5 1
Selenium ND ug/L 02/24/17 06:25 7782-49-202/20/17 19:5510.0 5.0 1
Silver ND ug/L 02/24/17 06:25 7440-22-402/20/17 19:5510.0 2.5 1
Vanadium 20.8J ug/L 02/24/17 06:25 7440-62-202/20/17 19:5525.0 2.5 1
Zinc 9.6J ug/L 02/24/17 06:25 7440-66-602/20/17 19:5510.0 5.0 1
Analytical Method: EPA 6020B Preparation Method: EPA 3010A6020 MET ICPMS
Thallium ND ug/L 02/18/17 15:27 7440-28-002/18/17 02:555.5 0.020 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 16:21 67-64-1100 10.0 1
Acrylonitrile ND ug/L 02/21/17 16:21 107-13-1200 1.9 1
Benzene ND ug/L 02/21/17 16:21 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 16:21 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 16:21 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 16:21 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 16:21 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 16:21 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 16:21 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 16:21 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 16:21 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 16:21 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 16:21 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 16:21 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 16:21 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 16:21 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 16:21 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 16:21 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 16:21 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 02/21/17 16:21 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 16:21 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 02/21/17 16:21 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 16:21 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 16:21 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 16:21 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 16:21 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 16:21 78-87-51.0 0.27 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: 3901-SW2 Lab ID: 92330376009 Collected: 02/14/17 09:45 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,3-Dichloropropene ND ug/L 02/21/17 16:21 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 16:21 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 16:21 100-41-41.0 0.30 1
2-Hexanone ND ug/L 02/21/17 16:21 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 16:21 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 02/21/17 16:21 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 16:21 108-10-1100 0.33 1
Styrene ND ug/L 02/21/17 16:21 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 16:21 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 16:21 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 16:21 127-18-41.0 0.46 1
Toluene ND ug/L 02/21/17 16:21 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 02/21/17 16:21 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 16:21 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 16:21 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 16:21 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 16:21 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 16:21 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 16:21 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 16:21 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)98 %02/21/17 16:21 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %02/21/17 16:21 17060-07-070-130 1
Toluene-d8 (S)101 %02/21/17 16:21 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: TRIP BLANK Lab ID: 92330376010 Collected: 02/13/17 07:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 02/21/17 12:05 67-64-1100 10.0 1
Acetonitrile ND ug/L 02/21/17 12:05 75-05-855.0 2.2 1
Acrolein ND ug/L 02/21/17 12:05 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 02/21/17 12:05 107-13-1200 1.9 1
Allyl chloride ND ug/L 02/21/17 12:05 107-05-110.0 1.5 1
Benzene ND ug/L 02/21/17 12:05 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 02/21/17 12:05 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 02/21/17 12:05 75-27-41.0 0.18 1
Bromoform ND ug/L 02/21/17 12:05 75-25-23.0 0.26 1
Bromomethane ND ug/L 02/21/17 12:05 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 02/21/17 12:05 78-93-3100 0.96 1
Carbon disulfide ND ug/L 02/21/17 12:05 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 02/21/17 12:05 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 02/21/17 12:05 108-90-73.0 0.23 1
Chloroethane ND ug/L 02/21/17 12:05 75-00-310.0 0.54 1
Chloroform ND ug/L 02/21/17 12:05 67-66-35.0 0.14 1
Chloromethane ND ug/L 02/21/17 12:05 74-87-31.0 0.11 1
Chloroprene ND ug/L 02/21/17 12:05 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 02/21/17 12:05 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 02/21/17 12:05 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 02/21/17 12:05 106-93-41.0 0.27 1
Dibromomethane ND ug/L 02/21/17 12:05 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 02/21/17 12:05 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 02/21/17 12:05 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 02/21/17 12:05 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 02/21/17 12:05 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 02/21/17 12:05 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 02/21/17 12:05 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 02/21/17 12:05 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 02/21/17 12:05 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 02/21/17 12:05 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 02/21/17 12:05 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 02/21/17 12:05 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 02/21/17 12:05 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 02/21/17 12:05 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 02/21/17 12:05 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 02/21/17 12:05 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 02/21/17 12:05 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 02/21/17 12:05 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 02/21/17 12:05 97-63-210.0 0.20 1
2-Hexanone ND ug/L 02/21/17 12:05 591-78-650.0 0.46 1
Iodomethane ND ug/L 02/21/17 12:05 74-88-410.0 0.32 1
Isobutanol ND ug/L 02/21/17 12:05 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 02/21/17 12:05 126-98-7100 0.93 1
Methylene Chloride ND ug/L 02/21/17 12:05 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 02/21/17 12:05 80-62-630.0 2.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 87
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Sample: TRIP BLANK Lab ID: 92330376010 Collected: 02/13/17 07:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)ND ug/L 02/21/17 12:05 108-10-1100 0.33 1
Naphthalene ND ug/L 02/21/17 12:05 91-20-310.0 0.24 1
Propionitrile ND ug/L 02/21/17 12:05 107-12-0150 3.6 1
Styrene ND ug/L 02/21/17 12:05 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 02/21/17 12:05 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 02/21/17 12:05 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 02/21/17 12:05 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 02/21/17 12:05 109-99-910.0 3.1 1
Toluene ND ug/L 02/21/17 12:05 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 02/21/17 12:05 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 02/21/17 12:05 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 02/21/17 12:05 79-00-51.0 0.29 1
Trichloroethene ND ug/L 02/21/17 12:05 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 02/21/17 12:05 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 02/21/17 12:05 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 02/21/17 12:05 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 02/21/17 12:05 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 02/21/17 12:05 1330-20-75.0 0.66 1
Surrogates4-Bromofluorobenzene (S)97 %02/21/17 12:05 460-00-470-130 1
1,2-Dichloroethane-d4 (S)111 %02/21/17 12:05 17060-07-070-130 1
Toluene-d8 (S)103 %02/21/17 12:05 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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[phone]
Page 40 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349177
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936998
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 02/23/17 17:030.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936999LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 98 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937000MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396004
1937001
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 93 75-12591 1 252.5ND 2.3 2.3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348742
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934817
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376004
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/24/17 14:163.9
Arsenic ug/L ND 10.0 02/24/17 14:165.0
Barium ug/L ND 100 02/24/17 14:162.5
Beryllium ug/L ND 1.0 02/24/17 14:160.50
Cadmium ug/L ND 1.0 02/24/17 14:160.50
Chromium ug/L ND 10.0 02/24/17 14:162.5
Cobalt ug/L ND 10.0 02/24/17 14:162.5
Copper ug/L ND 10.0 02/24/17 14:162.5
Iron ug/L ND 300 02/24/17 14:1625.0
Lead ug/L ND 10.0 02/24/17 14:162.5
Manganese ug/L ND 50.0 02/24/17 14:162.5
Nickel ug/L ND 50.0 02/24/17 14:162.5
Selenium ug/L ND 10.0 02/24/17 14:165.0
Silver ug/L ND 10.0 02/24/17 14:162.5
Tin ug/L ND 100 02/24/17 14:162.5
Vanadium ug/L ND 25.0 02/24/17 14:162.5
Zinc ug/L ND 10.0 02/24/17 14:165.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934818LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 488500 98 80-120
Arsenic ug/L 499500 100 80-120
Barium ug/L 455500 91 80-120
Beryllium ug/L 441500 88 80-120
Cadmium ug/L 480500 96 80-120
Chromium ug/L 489500 98 80-120
Cobalt ug/L 481500 96 80-120
Copper ug/L 502500 100 80-120
Iron ug/L 45405000 91 80-120
Lead ug/L 477500 95 80-120
Manganese ug/L 430500 86 80-120
Nickel ug/L 473500 95 80-120
Selenium ug/L 488500 98 80-120
Silver ug/L 236250 94 80-120
Tin ug/L 479500 96 80-120
Vanadium ug/L 433500 87 80-120
Zinc ug/L 472500 94 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934819MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330340003
1934820
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 99 75-125101 2 20500ND494 506
Arsenic ug/L 500 101 75-125104 2 20500ND508 521
Barium ug/L 500 90 75-12590 1 2050089.0J 541 537
Beryllium ug/L 500 89 75-12587 2 20500ND444 437
Cadmium ug/L 500 96 75-12599 3 20500ND482 495
Chromium ug/L 500 98 75-125102 3 20500ND492 510
Cobalt ug/L 500 95 75-12597 3 20500ND474 488
Copper ug/L 500 102 75-125103 1 205003.2J 511 518
Iron ug/L 5000 95 75-12595 0 20500018206550 6560
Lead ug/L 500 94 75-12597 3 20500ND470 486
Manganese ug/L 500 86 75-12589 3 2050063.9 493 510
Nickel ug/L 500 93 75-12596 3 20500ND465 479
Selenium ug/L 500 97 75-12599 2 20500ND486 494
Silver ug/L 250 96 75-12598 2 20250ND239 245
Tin ug/L 500 97 75-125100 4 20500ND483 501
Vanadium ug/L 500 89 75-12591 3 205005.2J 449 461
Zinc ug/L 500 93 75-12596 4 205005.4J 471 487
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348994
EPA 3010A
EPA 6010
6010 MET
Associated Lab Samples: 92330376005, 92330376006, 92330376007, 92330376008, 92330376009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936214
Associated Lab Samples:92330376005, 92330376006, 92330376007, 92330376008, 92330376009
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 02/24/17 05:123.9
Arsenic ug/L ND 10.0 02/24/17 05:125.0
Barium ug/L ND 100 02/24/17 05:122.5
Beryllium ug/L ND 1.0 02/24/17 05:120.50
Cadmium ug/L ND 1.0 02/24/17 05:120.50
Chromium ug/L ND 10.0 02/24/17 05:122.5
Cobalt ug/L ND 10.0 02/24/17 05:122.5
Copper ug/L ND 10.0 02/24/17 05:122.5
Iron ug/L ND 300 02/24/17 05:1225.0
Lead ug/L ND 10.0 02/24/17 05:122.5
Manganese ug/L ND 50.0 02/24/17 05:122.5
Nickel ug/L ND 50.0 02/24/17 05:122.5
Selenium ug/L ND 10.0 02/24/17 05:125.0
Silver ug/L ND 10.0 02/24/17 05:122.5
Vanadium ug/L ND 25.0 02/24/17 05:122.5
Zinc ug/L ND 10.0 02/24/17 05:155.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936215LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 479500 96 80-120
Arsenic ug/L 469500 94 80-120
Barium ug/L 493500 99 80-120
Beryllium ug/L 491500 98 80-120
Cadmium ug/L 479500 96 80-120
Chromium ug/L 496500 99 80-120
Cobalt ug/L 478500 96 80-120
Copper ug/L 487500 97 80-120
Iron ug/L 48405000 97 80-120
Lead ug/L 470500 94 80-120
Manganese ug/L 477500 95 80-120
Nickel ug/L 481500 96 80-120
Selenium ug/L 467500 93 80-120
Silver ug/L 239250 96 80-120
Vanadium ug/L 482500 96 80-120
Zinc ug/L 472500 94 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 44 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936216MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330396001
1936217
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-12596 2 20500ND489 478
Arsenic ug/L 500 97 75-12595 2 20500ND483 473
Barium ug/L 500 96 75-12595 1 205007.2 488 481
Beryllium ug/L 500 97 75-12595 1 20500ND483 477
Cadmium ug/L 500 96 75-12594 3 20500ND482 470
Chromium ug/L 500 98 75-12595 3 20500ND488 476
Cobalt ug/L 500 96 75-12593 2 20500ND478 466
Copper ug/L 500 98 75-12595 2 20500ND488 477
Iron ug/L 5000 97 75-12595 2 20500096.4 4950 4840
Lead ug/L 500 93 75-12591 2 20500ND467 457
Manganese ug/L 500 95 75-12592 3 20500100577 561
Nickel ug/L 500 96 75-12593 3 20500ND478 466
Selenium ug/L 500 94 75-12592 2 20500ND471 462
Silver ug/L 250 96 75-12593 3 20250ND240 234
Vanadium ug/L 500 99 75-12595 3 20500ND493 476
Zinc ug/L 500 96 75-12594 3 20500ND482 470
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 45 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348672
EPA 3010A
EPA 6020B
6020 MET
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007,92330376008, 92330376009
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934628
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007,92330376008, 92330376009
Matrix: Water
AnalyzedMDL
Thallium ug/L ND 5.5 02/18/17 14:320.020
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934629LABORATORY CONTROL SAMPLE:
LCSSpike
Thallium ug/L 103100 103 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330213010
1934631
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Thallium ug/L 100 102 75-125105 3 201000.18 102 105
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 46 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349146
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330376003, 92330376008, 92330376009, 92330376010
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936802
Associated Lab Samples:92330376003, 92330376008, 92330376009, 92330376010
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/21/17 10:060.33
1,1,1-Trichloroethane ug/L ND 1.0 02/21/17 10:060.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/21/17 10:060.40
1,1,2-Trichloroethane ug/L ND 1.0 02/21/17 10:060.29
1,1-Dichloroethane ug/L ND 5.0 02/21/17 10:060.32
1,1-Dichloroethene ug/L ND 5.0 02/21/17 10:060.56
1,1-Dichloropropene ug/L ND 5.0 02/21/17 10:060.49
1,2,3-Trichloropropane ug/L ND 1.0 02/21/17 10:060.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/21/17 10:060.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/21/17 10:062.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/21/17 10:060.27
1,2-Dichlorobenzene ug/L ND 5.0 02/21/17 10:060.30
1,2-Dichloroethane ug/L ND 1.0 02/21/17 10:060.24
1,2-Dichloropropane ug/L ND 1.0 02/21/17 10:060.27
1,3-Dichlorobenzene ug/L ND 5.0 02/21/17 10:060.24
1,3-Dichloropropane ug/L ND 1.0 02/21/17 10:060.28
1,4-Dichlorobenzene ug/L ND 1.0 02/21/17 10:060.33
2,2-Dichloropropane ug/L ND 15.0 02/21/17 10:060.13
2-Butanone (MEK)ug/L ND 100 02/21/17 10:060.96
2-Hexanone ug/L ND 50.0 02/21/17 10:060.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/21/17 10:060.33
Acetone ug/L ND 100 02/21/17 10:0610.0
Acetonitrile ug/L ND 55.0 02/21/17 10:062.2
Acrolein ug/L ND 53.0 02/21/17 10:061.6
Acrylonitrile ug/L ND 200 02/21/17 10:061.9
Allyl chloride ug/L ND 10.0 02/21/17 10:061.5
Benzene ug/L ND 1.0 02/21/17 10:060.25
Bromochloromethane ug/L ND 3.0 02/21/17 10:060.17
Bromodichloromethane ug/L ND 1.0 02/21/17 10:060.18
Bromoform ug/L ND 3.0 02/21/17 10:060.26
Bromomethane ug/L ND 10.0 02/21/17 10:060.29
Carbon disulfide ug/L ND 100 02/21/17 10:061.2
Carbon tetrachloride ug/L ND 1.0 02/21/17 10:060.25
Chlorobenzene ug/L ND 3.0 02/21/17 10:060.23
Chloroethane ug/L ND 10.0 02/21/17 10:060.54
Chloroform ug/L ND 5.0 02/21/17 10:060.14
Chloromethane ug/L ND 1.0 02/21/17 10:060.11
Chloroprene ug/L ND 20.0 02/21/17 10:060.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/21/17 10:060.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/21/17 10:060.13
Dibromochloromethane ug/L ND 3.0 02/21/17 10:060.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 47 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936802
Associated Lab Samples:92330376003, 92330376008, 92330376009, 92330376010
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 02/21/17 10:060.21
Dichlorodifluoromethane ug/L ND 5.0 02/21/17 10:060.21
Ethyl methacrylate ug/L ND 10.0 02/21/17 10:060.20
Ethylbenzene ug/L ND 1.0 02/21/17 10:060.30
Iodomethane ug/L ND 10.0 02/21/17 10:060.32
Isobutanol ug/L ND 100 02/21/17 10:0635.0
Methacrylonitrile ug/L ND 100 02/21/17 10:060.93
Methyl methacrylate ug/L ND 30.0 02/21/17 10:062.0
Methylene Chloride ug/L ND 1.0 02/21/17 10:060.97
Naphthalene ug/L ND 10.0 02/21/17 10:060.24
Propionitrile ug/L ND 150 02/21/17 10:063.6
Styrene ug/L ND 1.0 02/21/17 10:060.26
Tetrachloroethene ug/L ND 1.0 02/21/17 10:060.46
Tetrahydrofuran ug/L ND 10.0 02/21/17 10:063.1
Toluene ug/L ND 1.0 02/21/17 10:060.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/21/17 10:060.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/21/17 10:060.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/21/17 10:061.0
Trichloroethene ug/L ND 1.0 02/21/17 10:060.47
Trichlorofluoromethane ug/L ND 1.0 02/21/17 10:060.20
Vinyl acetate ug/L ND 50.0 02/21/17 10:060.35
Vinyl chloride ug/L ND 1.0 02/21/17 10:060.62
Xylene (Total)ug/L ND 5.0 02/21/17 10:060.66
1,2-Dichloroethane-d4 (S)%111 70-130 02/21/17 10:06
4-Bromofluorobenzene (S)%97 70-130 02/21/17 10:06
Toluene-d8 (S)%94 70-130 02/21/17 10:06
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936803LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 48.850 98 80-125
1,1,1-Trichloroethane ug/L 49.050 98 71-129
1,1,2,2-Tetrachloroethane ug/L 46.550 93 79-124
1,1,2-Trichloroethane ug/L 49.750 99 85-125
1,1-Dichloroethane ug/L 48.550 97 73-126
1,1-Dichloroethene ug/L 48.350 97 66-135
1,1-Dichloropropene ug/L 52.650 105 74-135
1,2,3-Trichloropropane ug/L 47.750 95 75-130
1,2,4-Trichlorobenzene ug/L 52.450 105 75-134
1,2-Dibromo-3-chloropropane ug/L 48.950 98 71-133
1,2-Dibromoethane (EDB)ug/L 47.750 95 83-124
1,2-Dichlorobenzene ug/L 49.250 98 80-133
1,2-Dichloroethane ug/L 47.950 96 67-128
1,2-Dichloropropane ug/L 49.750 99 75-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 48 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936803LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 48.650 97 77-130
1,3-Dichloropropane ug/L 48.950 98 76-131
1,4-Dichlorobenzene ug/L 48.050 96 78-130
2,2-Dichloropropane ug/L 52.650 105 40-160
2-Butanone (MEK)ug/L 101100 101 61-144
2-Hexanone ug/L 97.8100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 98.4J100 98 72-135
Acetone ug/L 90.9J100 91 48-146
Acetonitrile ug/L 493500 99 62-150
Acrolein ug/L 225250 90 24-160
Acrylonitrile ug/L 249250 100 40-160
Allyl chloride ug/L 46.950 94 66-137
Benzene ug/L 53.850 108 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 50.750 101 78-124
Bromoform ug/L 47.450 95 71-128
Bromomethane ug/L 43.650 87 40-160
Carbon disulfide ug/L 45.9J50 92 50-160
Carbon tetrachloride ug/L 50.550 101 69-131
Chlorobenzene ug/L 48.650 97 81-122
Chloroethane ug/L 47.750 95 39-148
Chloroform ug/L 49.350 99 73-127
Chloromethane ug/L 43.150 86 44-146
Chloroprene ug/L 53.050 106 75-145
cis-1,2-Dichloroethene ug/L 49.350 99 74-124
cis-1,3-Dichloropropene ug/L 51.550 103 72-132
Dibromochloromethane ug/L 49.450 99 78-125
Dibromomethane ug/L 48.450 97 82-120
Dichlorodifluoromethane ug/L 31.150 62 34-157
Ethyl methacrylate ug/L 51.750 103 82-121
Ethylbenzene ug/L 48.550 97 79-121
Iodomethane ug/L 93.5100 93 39-154
Isobutanol ug/L 9991000 100 34-160
Methacrylonitrile ug/L 527500 105 74-134
Methyl methacrylate ug/L 52.350 105 84-124
Methylene Chloride ug/L 45.850 92 64-133
Naphthalene ug/L 51.050 102 73-133
Propionitrile ug/L 524500 105 73-140
Styrene ug/L 49.650 99 84-126
Tetrachloroethene ug/L 47.850 96 78-122
Tetrahydrofuran ug/L 520500 104 69-148
Toluene ug/L 49.250 98 80-121
trans-1,2-Dichloroethene ug/L 47.950 96 71-127
trans-1,3-Dichloropropene ug/L 51.550 103 69-141
trans-1,4-Dichloro-2-butene ug/L 48.3J50 97 40-160
Trichloroethene ug/L 48.150 96 78-122
Trichlorofluoromethane ug/L 50.550 101 53-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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[phone]
Page 49 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936803LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 99.4100 99 40-160
Vinyl chloride ug/L 37.850 76 58-137
Xylene (Total)ug/L 147150 98 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%100 70-130
Toluene-d8 (S)%101 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1936805MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376009
1,1,1,2-Tetrachloroethane ug/L 20.620 103 70-130ND
1,1,1-Trichloroethane ug/L 21.420 107 70-130ND
1,1,2,2-Tetrachloroethane ug/L 21.020 105 70-130ND
1,1,2-Trichloroethane ug/L 22.020 110 70-130ND
1,1-Dichloroethane ug/L 21.320 106 70-130ND
1,1-Dichloroethene ug/L 22.520 113 70-166ND
1,1-Dichloropropene ug/L 23.120 116 70-130ND
1,2,3-Trichloropropane ug/L 20.420 102 70-130ND
1,2,4-Trichlorobenzene ug/L 19.520 97 70-130ND
1,2-Dibromo-3-chloropropane ug/L 20.920 105 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.420 102 70-130ND
1,2-Dichlorobenzene ug/L 20.320 101 70-130ND
1,2-Dichloroethane ug/L 22.420 112 70-130ND
1,2-Dichloropropane ug/L 22.320 111 70-130ND
1,3-Dichlorobenzene ug/L 20.020 100 70-130ND
1,3-Dichloropropane ug/L 21.520 107 70-130ND
1,4-Dichlorobenzene ug/L 20.120 100 70-130ND
2,2-Dichloropropane ug/L 19.920 99 70-130ND
2-Butanone (MEK)ug/L 45.3J40 113 70-130ND
2-Hexanone ug/L 47.5J40 119 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 47.0J40 118 70-130ND
Acetone ug/L 47.0J40 114 70-130ND
Acetonitrile ug/L 237200 118 70-130ND
Acrolein ug/L 90.9100 91 70-130ND
Acrylonitrile ug/L 112J100 112 70-130ND
Allyl chloride ug/L 21.120 106 70-130ND
Benzene ug/L 22.220 111 70-148ND
Bromochloromethane ug/L 21.520 108 70-130ND
Bromodichloromethane ug/L 22.320 112 70-130ND
Bromoform ug/L 18.920 94 70-130ND
Bromomethane ug/L 20.720 103 70-130ND
Carbon disulfide ug/L 22.1J20 110 70-130ND
Carbon tetrachloride ug/L 21.220 106 70-130ND
Chlorobenzene ug/L 21.420 107 70-146ND
Chloroethane ug/L 21.420 107 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 50 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1936805MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376009
Chloroform ug/L 20.920 104 70-130ND
Chloromethane ug/L 19.920 100 70-130ND
Chloroprene ug/L 23.520 117 70-130ND
cis-1,2-Dichloroethene ug/L 21.420 107 70-130ND
cis-1,3-Dichloropropene ug/L 21.020 105 70-130ND
Dibromochloromethane ug/L 20.220 101 70-130ND
Dibromomethane ug/L 20.420 102 70-130ND
Dichlorodifluoromethane ug/L 19.720 99 70-130ND
Ethyl methacrylate ug/L 22.720 114 70-130ND
Ethylbenzene ug/L 21.320 107 70-130ND
Iodomethane ug/L 42.740 107 70-130ND
Isobutanol ug/L 543 M1400136 70-130ND
Methacrylonitrile ug/L 237200 119 70-130ND
Methyl methacrylate ug/L 22.5J20 113 70-130ND
Methylene Chloride ug/L 19.620 98 70-130ND
Naphthalene ug/L 20.020 100 70-130ND
Propionitrile ug/L 248200 124 70-130ND
Styrene ug/L 21.120 106 70-130ND
Tetrachloroethene ug/L 20.320 102 70-130ND
Tetrahydrofuran ug/L 236200 118 70-130ND
Toluene ug/L 22.120 111 70-155ND
trans-1,2-Dichloroethene ug/L 22.720 114 70-130ND
trans-1,3-Dichloropropene ug/L 21.020 105 70-130ND
trans-1,4-Dichloro-2-butene ug/L 18.8J20 94 70-130ND
Trichloroethene ug/L 21.320 106 69-151ND
Trichlorofluoromethane ug/L 23.320 116 70-130ND
Vinyl acetate ug/L 35.0J40 88 70-130ND
Vinyl chloride ug/L 17.920 90 70-130ND
1,2-Dichloroethane-d4 (S)%102 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%102 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376008
1936804SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 51 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376008
1936804SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 52 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376008
1936804SAMPLE DUPLICATE:
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%104 1103
4-Bromofluorobenzene (S)%98 199
Toluene-d8 (S)%100 2102
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 53 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349193
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330376001, 92330376002, 92330376004, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330376001, 92330376002, 92330376004, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 02/21/17 11:120.33
1,1,1-Trichloroethane ug/L ND 1.0 02/21/17 11:120.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 02/21/17 11:120.40
1,1,2-Trichloroethane ug/L ND 1.0 02/21/17 11:120.29
1,1-Dichloroethane ug/L ND 5.0 02/21/17 11:120.32
1,1-Dichloroethene ug/L ND 5.0 02/21/17 11:120.56
1,1-Dichloropropene ug/L ND 5.0 02/21/17 11:120.49
1,2,3-Trichloropropane ug/L ND 1.0 02/21/17 11:120.41
1,2,4-Trichlorobenzene ug/L ND 10.0 02/21/17 11:120.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 02/21/17 11:122.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 02/21/17 11:120.27
1,2-Dichlorobenzene ug/L ND 5.0 02/21/17 11:120.30
1,2-Dichloroethane ug/L ND 1.0 02/21/17 11:120.24
1,2-Dichloropropane ug/L ND 1.0 02/21/17 11:120.27
1,3-Dichlorobenzene ug/L ND 5.0 02/21/17 11:120.24
1,3-Dichloropropane ug/L ND 1.0 02/21/17 11:120.28
1,4-Dichlorobenzene ug/L ND 1.0 02/21/17 11:120.33
2,2-Dichloropropane ug/L ND 15.0 02/21/17 11:120.13
2-Butanone (MEK)ug/L ND 100 02/21/17 11:120.96
2-Hexanone ug/L ND 50.0 02/21/17 11:120.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 02/21/17 11:120.33
Acetone ug/L ND 100 02/21/17 11:1210.0
Acetonitrile ug/L ND 55.0 02/21/17 11:122.2
Acrolein ug/L ND 53.0 02/21/17 11:121.6
Acrylonitrile ug/L ND 200 02/21/17 11:121.9
Allyl chloride ug/L ND 10.0 02/21/17 11:121.5
Benzene ug/L ND 1.0 02/21/17 11:120.25
Bromochloromethane ug/L ND 3.0 02/21/17 11:120.17
Bromodichloromethane ug/L ND 1.0 02/21/17 11:120.18
Bromoform ug/L ND 3.0 02/21/17 11:120.26
Bromomethane ug/L ND 10.0 02/21/17 11:120.29
Carbon disulfide ug/L ND 100 02/21/17 11:121.2
Carbon tetrachloride ug/L ND 1.0 02/21/17 11:120.25
Chlorobenzene ug/L ND 3.0 02/21/17 11:120.23
Chloroethane ug/L ND 10.0 02/21/17 11:120.54
Chloroform ug/L ND 5.0 02/21/17 11:120.14
Chloromethane ug/L ND 1.0 02/21/17 11:120.11
Chloroprene ug/L ND 20.0 02/21/17 11:120.27
cis-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.19
cis-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.13
Dibromochloromethane ug/L ND 3.0 02/21/17 11:120.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 54 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330376001, 92330376002, 92330376004, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 02/21/17 11:120.21
Dichlorodifluoromethane ug/L ND 5.0 02/21/17 11:120.21
Ethyl methacrylate ug/L ND 10.0 02/21/17 11:120.20
Ethylbenzene ug/L ND 1.0 02/21/17 11:120.30
Iodomethane ug/L ND 10.0 02/21/17 11:120.32
Isobutanol ug/L ND 100 02/21/17 11:1235.0
Methacrylonitrile ug/L ND 100 02/21/17 11:120.93
Methyl methacrylate ug/L ND 30.0 02/21/17 11:122.0
Methylene Chloride ug/L ND 1.0 02/21/17 11:120.97
Naphthalene ug/L ND 10.0 02/21/17 11:120.24
Propionitrile ug/L ND 150 02/21/17 11:123.6
Styrene ug/L ND 1.0 02/21/17 11:120.26
Tetrachloroethene ug/L ND 1.0 02/21/17 11:120.46
Tetrahydrofuran ug/L ND 10.0 02/21/17 11:123.1
Toluene ug/L ND 1.0 02/21/17 11:120.26
trans-1,2-Dichloroethene ug/L ND 5.0 02/21/17 11:120.49
trans-1,3-Dichloropropene ug/L ND 1.0 02/21/17 11:120.26
trans-1,4-Dichloro-2-butene ug/L ND 100 02/21/17 11:121.0
Trichloroethene ug/L ND 1.0 02/21/17 11:120.47
Trichlorofluoromethane ug/L ND 1.0 02/21/17 11:120.20
Vinyl acetate ug/L ND 50.0 02/21/17 11:120.35
Vinyl chloride ug/L ND 1.0 02/21/17 11:120.62
Xylene (Total)ug/L ND 5.0 02/21/17 11:120.66
1,2-Dichloroethane-d4 (S)%108 70-130 02/21/17 11:12
4-Bromofluorobenzene (S)%99 70-130 02/21/17 11:12
Toluene-d8 (S)%113 70-130 02/21/17 11:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 49.250 98 80-125
1,1,1-Trichloroethane ug/L 46.050 92 71-129
1,1,2,2-Tetrachloroethane ug/L 50.250 100 79-124
1,1,2-Trichloroethane ug/L 54.150 108 85-125
1,1-Dichloroethane ug/L 48.650 97 73-126
1,1-Dichloroethene ug/L 48.150 96 66-135
1,1-Dichloropropene ug/L 51.050 102 74-135
1,2,3-Trichloropropane ug/L 53.850 108 75-130
1,2,4-Trichlorobenzene ug/L 52.050 104 75-134
1,2-Dibromo-3-chloropropane ug/L 49.450 99 71-133
1,2-Dibromoethane (EDB)ug/L 53.250 106 83-124
1,2-Dichlorobenzene ug/L 51.950 104 80-133
1,2-Dichloroethane ug/L 43.650 87 67-128
1,2-Dichloropropane ug/L 51.950 104 75-132
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 55 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 50.350 101 77-130
1,3-Dichloropropane ug/L 55.850 112 76-131
1,4-Dichlorobenzene ug/L 48.950 98 78-130
2,2-Dichloropropane ug/L 44.850 90 40-160
2-Butanone (MEK)ug/L 90.1J100 90 61-144
2-Hexanone ug/L 89.6100 90 68-143
4-Methyl-2-pentanone (MIBK)ug/L 87.7J100 88 72-135
Acetone ug/L 86.3J100 86 48-146
Acetonitrile ug/L 414500 83 62-150
Acrolein ug/L 184250 74 24-160
Acrylonitrile ug/L 219250 88 40-160
Allyl chloride ug/L 47.850 96 66-137
Benzene ug/L 52.050 104 80-125
Bromochloromethane ug/L 51.250 102 71-125
Bromodichloromethane ug/L 49.750 99 78-124
Bromoform ug/L 45.050 90 71-128
Bromomethane ug/L 52.150 104 40-160
Carbon disulfide ug/L 49.7J50 99 50-160
Carbon tetrachloride ug/L 49.350 99 69-131
Chlorobenzene ug/L 51.850 104 81-122
Chloroethane ug/L 57.950 116 39-148
Chloroform ug/L 49.650 99 73-127
Chloromethane ug/L 62.650 125 44-146
Chloroprene ug/L 54.750 109 75-145
cis-1,2-Dichloroethene ug/L 50.750 101 74-124
cis-1,3-Dichloropropene ug/L 54.750 109 72-132
Dibromochloromethane ug/L 49.050 98 78-125
Dibromomethane ug/L 47.950 96 82-120
Dichlorodifluoromethane ug/L 50.050 100 34-157
Ethyl methacrylate ug/L 48.650 97 82-121
Ethylbenzene ug/L 50.750 101 79-121
Iodomethane ug/L 113100 113 39-154
Isobutanol ug/L 8141000 81 34-160
Methacrylonitrile ug/L 471500 94 74-134
Methyl methacrylate ug/L 48.350 97 84-124
Methylene Chloride ug/L 47.050 94 64-133
Naphthalene ug/L 50.550 101 73-133
Propionitrile ug/L 400500 80 73-140
Styrene ug/L 52.150 104 84-126
Tetrachloroethene ug/L 51.250 102 78-122
Tetrahydrofuran ug/L 465500 93 69-148
Toluene ug/L 53.050 106 80-121
trans-1,2-Dichloroethene ug/L 50.150 100 71-127
trans-1,3-Dichloropropene ug/L 54.150 108 69-141
trans-1,4-Dichloro-2-butene ug/L 51.9J50 104 40-160
Trichloroethene ug/L 55.350 111 78-122
Trichlorofluoromethane ug/L 55.850 112 53-137
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 56 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 97.8100 98 40-160
Vinyl chloride ug/L 43.750 87 58-137
Xylene (Total)ug/L 150150 100 81-126
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 87 70-13093 7 3020ND17.4 18.6
1,1,1-Trichloroethane ug/L 20 124 70-130122 1 3020ND24.7 24.5
1,1,2,2-Tetrachloroethane ug/L 20 100 70-130103 3 3020ND20.0 20.6
1,1,2-Trichloroethane ug/L 20 105 70-130111 6 3020ND21.0 22.3
1,1-Dichloroethane ug/L M12016770-130157 6 3020ND33.6 31.8
1,1-Dichloroethene ug/L M12016870-166154 9 3020ND33.7 30.8
1,1-Dichloropropene ug/L 20 125 70-130123 2 3020ND25.0 24.5
1,2,3-Trichloropropane ug/L 20 96 70-130104 9 3020ND19.2 20.9
1,2,4-Trichlorobenzene ug/L 20 99 70-13098 2 3020ND19.9 19.5
1,2-Dibromo-3-chloropropane ug/L 20 86 70-13096 11 3020ND17.1 19.2
1,2-Dibromoethane (EDB) ug/L 20 90 70-13099 10 3020ND17.9 19.8
1,2-Dichlorobenzene ug/L 20 105 70-130105 1 3020ND21.1 21.0
1,2-Dichloroethane ug/L 20 122 70-130123 1 3020ND24.4 24.7
1,2-Dichloropropane ug/L 20 113 70-130117 3 3020ND22.6 23.3
1,3-Dichlorobenzene ug/L 20 101 70-13097 3 3020ND20.1 19.5
1,3-Dichloropropane ug/L 20 105 70-130110 5 3020ND21.1 22.1
1,4-Dichlorobenzene ug/L 20 109 70-130104 5 3020ND22.2 21.1
2,2-Dichloropropane ug/L 20 117 70-130111 5 3020ND23.5 22.3
2-Butanone (MEK)ug/L 40 85 70-13097 13 3040ND34.2J 38.9J
2-Hexanone ug/L 40 91 70-130106 15 3040ND36.2J 42.2J
4-Methyl-2-pentanone(MIBK)ug/L 40 95 70-130112 16 3040ND38.1J 44.7J
Acetone ug/L 40 82 70-13095 15 3040ND32.9J 38.2J
Acetonitrile ug/L 200 92 70-130118 25 30200ND183 236
Acrolein ug/L 100 70 70-13077 8 30100ND70.5 76.6
Acrylonitrile ug/L 100 101 70-130118 15 30100ND101J 118J
Allyl chloride ug/L M12016170-130134 18 3020ND32.2 26.8
Benzene ug/L 20 120 70-148121 1 30200.44J 24.4 24.6
Bromochloromethane ug/L M12013670-130132 4 3020ND27.3 26.3
Bromodichloromethane ug/L 20 116 70-130115 1 3020ND23.1 23.0
Bromoform ug/L 20 78 70-13087 11 3020ND15.5 17.4
Bromomethane ug/L M12014070-130134 4 3020ND27.9 26.8
Carbon disulfide ug/L M12016070-130157 1 3020ND31.9J 31.5J
Carbon tetrachloride ug/L 20 113 70-130111 2 3020ND22.7 22.2
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 57 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chlorobenzene ug/L 20 113 70-146115 2 3020ND22.6 23.0
Chloroethane ug/L M12020570-130202 1 30200.69J 41.6 41.1
Chloroform ug/L M12013970-130132 5 3020ND27.8 26.4
Chloromethane ug/L M12015870-130149 6 3020ND31.6 29.7
Chloroprene ug/L M12013270-130132 0 3020ND26.4 26.4
cis-1,2-Dichloroethene ug/L M12016070-130160 0 3020ND32.0 32.0
cis-1,3-Dichloropropene ug/L 20 105 70-130109 3 3020ND21.1 21.7
Dibromochloromethane ug/L 20 81 70-13089 9 3020ND16.2 17.7
Dibromomethane ug/L 20 110 70-130113 3 3020ND21.9 22.6
Dichlorodifluoromethane ug/L M12014270-130137 4 3020ND28.3 27.4
Ethyl methacrylate ug/L 20 115 70-130124 7 3020ND23.1 24.8
Ethylbenzene ug/L 20 117 70-130118 0 3020ND23.4 23.5
Iodomethane ug/L M14016170-130180 11 3040ND64.2 72.0
Isobutanol ug/L M1,R14003570-13050 34 30400ND141 200
Methacrylonitrile ug/L 200 103 70-130120 16 30200ND205 241
Methyl methacrylate ug/L 20 99 70-130103 3 3020ND19.9J 20.6J
Methylene Chloride ug/L M12015770-130150 5 3020ND31.3 29.9
Naphthalene ug/L 20 93 70-13096 3 3020ND18.6 19.2
Propionitrile ug/L 200 83 70-130102 21 30200ND166 204
Styrene ug/L 20 116 70-130118 2 3020ND23.1 23.7
Tetrachloroethene ug/L 20 97 70-130106 9 3020ND19.4 21.3
Tetrahydrofuran ug/L 200 94 70-130115 20 30200ND188 231
Toluene ug/L 20 133 70-155131 1 3020ND26.6 26.2
trans-1,2-Dichloroethene ug/L M12014370-130140 2 3020ND28.6 27.9
trans-1,3-Dichloropropene ug/L 20 102 70-130108 6 3020ND20.4 21.7
trans-1,4-Dichloro-2-butene ug/L M1206770-13087 26 3020ND13.3J 17.4J
Trichloroethene ug/L 20 105 69-151107 2 3020ND21.0 21.5
Trichlorofluoromethane ug/L M12020070-130189 5 3020ND39.9 37.8
Vinyl acetate ug/L 40 83 70-13090 8 3040ND33.2J 36.0J
Vinyl chloride ug/L M12015870-130141 11 3020ND31.5 28.3
1,2-Dichloroethane-d4 (S)%115 70-130117
4-Bromofluorobenzene (S) %99 70-130103
Toluene-d8 (S)%107 70-130104
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 58 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348796
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1935261
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 02/25/17 14:210.050
4,4'-DDE ug/L ND 0.10 02/25/17 14:210.050
4,4'-DDT ug/L ND 0.10 02/25/17 14:210.050
Aldrin ug/L ND 0.050 02/25/17 14:210.050
alpha-BHC ug/L ND 0.050 02/25/17 14:210.050
beta-BHC ug/L ND 0.050 02/25/17 14:210.050
Chlordane (Technical)ug/L ND 0.50 02/25/17 14:210.20
delta-BHC ug/L ND 0.050 02/25/17 14:210.050
Dieldrin ug/L ND 0.075 02/25/17 14:210.050
Endosulfan I ug/L ND 0.10 02/25/17 14:210.050
Endosulfan II ug/L ND 0.10 02/25/17 14:210.050
Endosulfan sulfate ug/L ND 0.10 02/25/17 14:210.050
Endrin ug/L ND 0.10 02/25/17 14:210.050
Endrin aldehyde ug/L ND 0.10 02/25/17 14:210.050
gamma-BHC (Lindane)ug/L ND 0.050 02/25/17 14:210.050
Heptachlor ug/L ND 0.050 02/25/17 14:210.050
Heptachlor epoxide ug/L ND 0.075 02/25/17 14:210.050
Methoxychlor ug/L ND 1.0 02/25/17 14:210.15
Toxaphene ug/L ND 1.5 02/25/17 14:210.20
Decachlorobiphenyl (S)%91 20-130 02/25/17 14:21
Tetrachloro-m-xylene (S)%80 20-130 02/25/17 14:21
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935262LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.23.25 93 20-150
4,4'-DDE ug/L 0.22.25 90 20-150
4,4'-DDT ug/L 0.24.25 97 20-150
Aldrin ug/L 0.19.25 77 20-150
alpha-BHC ug/L 0.22.25 88 20-150
beta-BHC ug/L 0.19.25 75 20-150
delta-BHC ug/L 0.23.25 93 20-150
Dieldrin ug/L 0.22.25 89 20-150
Endosulfan I ug/L 0.24.25 96 20-150
Endosulfan II ug/L 0.30.25 123 20-150
Endosulfan sulfate ug/L 0.31.25 123 20-150
Endrin ug/L 0.23.25 94 20-150
Endrin aldehyde ug/L 0.20.25 80 20-150
gamma-BHC (Lindane)ug/L 0.22.25 91 20-150
Heptachlor ug/L 0.20.25 79 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 59 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935262LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 91 20-150
Methoxychlor ug/L 0.68J.74 92 20-150
Decachlorobiphenyl (S)%87 20-130
Tetrachloro-m-xylene (S)%78 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1935263MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233003
1935264
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 114 20-150108 6 30.5ND 0.56 0.53
4,4'-DDE ug/L .5 87 20-15078 11 30.5ND 0.43 0.39
4,4'-DDT ug/L .5 107 20-150101 5 30.5ND 0.53 0.50
Aldrin ug/L .5 87 20-15082 5 30.5ND 0.46 0.43
alpha-BHC ug/L .5 97 20-15085 5 30.50.78 1.3 1.2
beta-BHC ug/L E,M1.5 57 20-150-7 5 30.55.6 5.9 5.6
delta-BHC ug/L .5 98 20-15091 4 30.50.31 0.80 0.76
Dieldrin ug/L E.5 72 20-15048 7 30.51.5 1.8 1.7
Endosulfan I ug/L .5 91 20-150101 11 30.5ND 0.45 0.50
Endosulfan II ug/L M1.5 161 20-150153 5 30.5ND 0.80 0.76
Endosulfan sulfate ug/L .5 131 20-150126 4 30.5ND 0.65 0.63
Endrin ug/L .5 114 20-150109 4 30.5ND 0.56 0.54
Endrin aldehyde ug/L .5 116 20-150110 6 30.5ND 0.57 0.54
gamma-BHC (Lindane)ug/L .5 95 20-15093 1 30.50.076 0.54 0.54
Heptachlor ug/L .5 95 20-15090 6 30.5ND 0.47 0.44
Heptachlor epoxide ug/L .5 91 20-15092 0 30.5ND 0.45 0.45
Methoxychlor ug/L 1.5 109 20-150104 4 301.5ND 1.6J 1.5J
Decachlorobiphenyl (S)%76 20-13070
Tetrachloro-m-xylene (S)%82 20-13086
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 60 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348597
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934142
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 02/17/17 13:420.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 02/17/17 13:420.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 02/17/17 13:420.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 02/17/17 13:420.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 02/17/17 13:420.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 02/17/17 13:420.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 02/17/17 13:420.50
Decachlorobiphenyl (S)%171 10-132 S302/17/17 13:42
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934143LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1934144
PCB-1016 (Aroclor 1016)ug/L 3.2 R156450-1501065.3 50 30
PCB-1260 (Aroclor 1260)ug/L 4.1 R158350-1501145.7 32 30
Decachlorobiphenyl (S)%68 10-132100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 61 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
351621
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1890971
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 02/24/17 06:150.042
2,4,5-TP (Silvex)ug/L ND 0.19 02/24/17 06:150.049
2,4-D ug/L ND 0.94 02/24/17 06:150.22
Dinoseb ug/L ND 0.19 02/24/17 06:150.057
2,4-DCAA (S)%83 39-139 02/24/17 06:15
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1890972LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1891097
2,4,5-T ug/L 1.61.2 132 37-1331211.4 9 40
2,4,5-TP (Silvex)ug/L 1.31.2 105 53-134951.1 10 40
2,4-D ug/L 7.36 122 35-1241207.2 2 40
Dinoseb ug/L 1.41.2 115 13-116991.2 14 40
2,4-DCAA (S)%102 39-13998 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 62 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348764
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934957
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 02/20/17 11:011.7
1,3,5-Trinitrobenzene ug/L ND 10.0 02/20/17 11:011.1
1,3-Dinitrobenzene ug/L ND 20.0 02/20/17 11:011.5
1,4-Naphthoquinone ug/L ND 10.0 02/20/17 11:011.8
1-Naphthalenamine ug/L ND 10.0 02/20/17 11:010.96
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 02/20/17 11:011.6
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 02/20/17 11:012.3
2,4,5-Trichlorophenol ug/L ND 10.0 02/20/17 11:012.2
2,4,6-Trichlorophenol ug/L ND 10.0 02/20/17 11:011.9
2,4-Dichlorophenol ug/L ND 10.0 02/20/17 11:011.7
2,4-Dimethylphenol ug/L ND 10.0 02/20/17 11:012.2
2,4-Dinitrophenol ug/L ND 50.0 02/20/17 11:016.5
2,4-Dinitrotoluene ug/L ND 10.0 02/20/17 11:011.2
2,6-Dichlorophenol ug/L ND 10.0 02/20/17 11:011.8
2,6-Dinitrotoluene ug/L ND 10.0 02/20/17 11:011.7
2-Acetylaminofluorene ug/L ND 20.0 02/20/17 11:010.84
2-Chloronaphthalene ug/L ND 10.0 02/20/17 11:012.2
2-Chlorophenol ug/L ND 10.0 02/20/17 11:011.5
2-Methylnaphthalene ug/L ND 10.0 02/20/17 11:010.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 02/20/17 11:011.7
2-Naphthalenamine ug/L ND 10.0 02/20/17 11:010.98
2-Nitroaniline ug/L ND 50.0 02/20/17 11:012.8
2-Nitrophenol ug/L ND 10.0 02/20/17 11:011.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 02/20/17 11:011.7
3,3'-Dichlorobenzidine ug/L ND 20.0 02/20/17 11:011.4
3,3'-Dimethylbenzidine ug/L ND 10.0 02/20/17 11:012.1
3-Methylcholanthrene ug/L ND 10.0 02/20/17 11:010.82
3-Nitroaniline ug/L ND 50.0 02/20/17 11:012.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 02/20/17 11:011.7
4-Aminobiphenyl ug/L ND 20.0 02/20/17 11:010.92
4-Bromophenylphenyl ether ug/L ND 10.0 02/20/17 11:011.3
4-Chloro-3-methylphenol ug/L ND 20.0 02/20/17 11:014.2
4-Chloroaniline ug/L ND 20.0 02/20/17 11:013.4
4-Chlorophenylphenyl ether ug/L ND 10.0 02/20/17 11:012.1
4-Nitroaniline ug/L ND 20.0 02/20/17 11:012.5
4-Nitrophenol ug/L ND 50.0 02/20/17 11:015.8
5-Nitro-o-toluidine ug/L ND 10.0 02/20/17 11:011.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 02/20/17 11:010.77
Acenaphthene ug/L ND 10.0 02/20/17 11:010.25
Acenaphthylene ug/L ND 10.0 02/20/17 11:010.21
Acetophenone ug/L ND 10.0 02/20/17 11:012.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 63 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934957
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
Anthracene ug/L ND 10.0 02/20/17 11:010.14
Benzo(a)anthracene ug/L ND 10.0 02/20/17 11:010.33
Benzo(a)pyrene ug/L ND 10.0 02/20/17 11:010.30
Benzo(b)fluoranthene ug/L ND 10.0 02/20/17 11:010.28
Benzo(g,h,i)perylene ug/L ND 10.0 02/20/17 11:010.38
Benzo(k)fluoranthene ug/L ND 10.0 02/20/17 11:010.43
Benzyl alcohol ug/L ND 20.0 02/20/17 11:013.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 02/20/17 11:011.7
bis(2-Chloroethyl) ether ug/L ND 10.0 02/20/17 11:011.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 02/20/17 11:010.85
Butylbenzylphthalate ug/L ND 10.0 02/20/17 11:010.75
Chlorobenzilate ug/L ND 10.0 02/20/17 11:010.72
Chrysene ug/L ND 10.0 02/20/17 11:010.21
Di-n-butylphthalate ug/L ND 10.0 02/20/17 11:011.1
Di-n-octylphthalate ug/L ND 10.0 02/20/17 11:010.86
Diallate ug/L ND 10.0 02/20/17 11:011.3
Dibenz(a,h)anthracene ug/L ND 10.0 02/20/17 11:010.55
Dibenzofuran ug/L ND 10.0 02/20/17 11:011.8
Diethylphthalate ug/L ND 6000 02/20/17 11:011.3
Dimethoate ug/L ND 20.0 02/20/17 11:010.92
Dimethylphthalate ug/L ND 10.0 02/20/17 11:011.5
Diphenylamine ug/L ND 10.0 02/20/17 11:011.3
Disulfoton ug/L ND 10.0 02/20/17 11:011.4
Ethyl methanesulfonate ug/L ND 20.0 02/20/17 11:011.8
Famphur ug/L ND 20.0 02/20/17 11:011.7
Fluoranthene ug/L ND 10.0 02/20/17 11:010.21
Fluorene ug/L ND 10.0 02/20/17 11:010.21
Hexachloro-1,3-butadiene ug/L ND 10.0 02/20/17 11:011.8
Hexachlorobenzene ug/L ND 10.0 02/20/17 11:011.1
Hexachlorocyclopentadiene ug/L ND 10.0 02/20/17 11:011.8
Hexachloroethane ug/L ND 10.0 02/20/17 11:011.5
Hexachloropropene ug/L ND 10.0 02/20/17 11:011.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 02/20/17 11:010.29
Isodrin ug/L ND 20.0 02/20/17 11:012.0
Isophorone ug/L ND 10.0 02/20/17 11:011.8
Isosafrole ug/L ND 10.0 02/20/17 11:011.8
Kepone ug/L ND 20.0 02/20/17 11:013.1
Methapyrilene ug/L ND 100 02/20/17 11:012.7
Methyl methanesulfonate ug/L ND 10.0 02/20/17 11:011.3
Methyl parathion ug/L ND 10.0 02/20/17 11:011.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 02/20/17 11:012.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 02/20/17 11:012.1
N-Nitrosodiethylamine ug/L ND 20.0 02/20/17 11:011.8
N-Nitrosodimethylamine ug/L ND 10.0 02/20/17 11:011.3
N-Nitrosodiphenylamine ug/L ND 10.0 02/20/17 11:011.3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 64 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934957
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
N-Nitrosomethylethylamine ug/L ND 10.0 02/20/17 11:011.8
N-Nitrosopiperidine ug/L ND 20.0 02/20/17 11:011.9
N-Nitrosopyrrolidine ug/L ND 10.0 02/20/17 11:012.5
Nitrobenzene ug/L ND 10.0 02/20/17 11:011.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 02/20/17 11:011.8
O-Toluidine ug/L ND 10.0 02/20/17 11:011.6
P-Dimethylaminoazobenzene ug/L ND 10.0 02/20/17 11:010.35
p-Phenylenediamine ug/L ND 10.0 02/20/17 11:010.96
Parathion (Ethyl parathion)ug/L ND 10.0 02/20/17 11:011.1
Pentachlorobenzene ug/L ND 10.0 02/20/17 11:012.0
Pentachloronitrobenzene ug/L ND 20.0 02/20/17 11:011.0
Pentachlorophenol ug/L ND 25.0 02/20/17 11:012.3
Phenacetin ug/L ND 20.0 02/20/17 11:010.97
Phenanthrene ug/L ND 10.0 02/20/17 11:010.22
Phenol ug/L ND 10.0 02/20/17 11:011.7
Phorate ug/L ND 10.0 02/20/17 11:011.1
Pronamide ug/L ND 10.0 02/20/17 11:010.97
Pyrene ug/L ND 10.0 02/20/17 11:010.19
Safrole ug/L ND 10.0 02/20/17 11:011.5
Thionazin ug/L ND 20.0 02/20/17 11:011.2
2,4,6-Tribromophenol (S)%79 27-110 02/20/17 11:01
2-Fluorobiphenyl (S)%77 27-110 02/20/17 11:01
2-Fluorophenol (S)%38 12-110 02/20/17 11:01
Nitrobenzene-d5 (S)%79 21-110 02/20/17 11:01
Phenol-d6 (S)%25 10-110 02/20/17 11:01
Terphenyl-d14 (S)%98 31-107 02/20/17 11:01
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 36.250 72 16-129
1,3,5-Trinitrobenzene ug/L 65.2 L150130 55-125
1,3-Dinitrobenzene ug/L 45.350 91 30-122
1,4-Naphthoquinone ug/L 43.250 86 31-120
1-Naphthalenamine ug/L 25.850 52 37-126
2,2'-Oxybis(1-chloropropane)ug/L 27.550 55 18-120
2,3,4,6-Tetrachlorophenol ug/L 46.850 94 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 40.850 82 42-120
2,4-Dichlorophenol ug/L 37.450 75 30-120
2,4-Dimethylphenol ug/L 34.450 69 29-111
2,4-Dinitrophenol ug/L 163250 65 19-132
2,4-Dinitrotoluene ug/L 50.550 101 58-128
2,6-Dichlorophenol ug/L 41.050 82 54-128
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 65 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
2,6-Dinitrotoluene ug/L 48.250 96 54-129
2-Acetylaminofluorene ug/L 46.050 92 81-160
2-Chloronaphthalene ug/L 40.250 80 43-117
2-Chlorophenol ug/L 28.650 57 37-120
2-Methylnaphthalene ug/L 31.650 63 33-120
2-Methylphenol(o-Cresol)ug/L 22.650 45 31-120
2-Naphthalenamine ug/L 40.750 81 41-136
2-Nitroaniline ug/L 90.8100 91 48-121
2-Nitrophenol ug/L 32.850 66 25-116
3&4-Methylphenol(m&p Cresol)ug/L 19.250 38 23-120
3,3'-Dichlorobenzidine ug/L 87.3250 35 10-154
3,3'-Dimethylbenzidine ug/L 63.8100 64 10-157
3-Methylcholanthrene ug/L 41.750 83 65-130
3-Nitroaniline ug/L 81.1100 81 43-115
4,6-Dinitro-2-methylphenol ug/L 74.9100 75 44-124
4-Aminobiphenyl ug/L 40.450 81 21-125
4-Bromophenylphenyl ether ug/L 40.450 81 34-113
4-Chloro-3-methylphenol ug/L 74.8100 75 31-110
4-Chloroaniline ug/L 67.9100 68 20-120
4-Chlorophenylphenyl ether ug/L 40.150 80 34-116
4-Nitroaniline ug/L 84.7100 85 46-128
4-Nitrophenol ug/L 116250 46 11-120
5-Nitro-o-toluidine ug/L 44.350 89 78-160
7,12-Dimethylbenz(a)anthracene ug/L 38.950 78 47-124
Acenaphthene ug/L 37.450 75 48-114
Acenaphthylene ug/L 37.650 75 48-112
Acetophenone ug/L 30.450 61 24-120
Anthracene ug/L 42.050 84 57-118
Benzo(a)anthracene ug/L 44.050 88 56-121
Benzo(a)pyrene ug/L 41.250 82 55-127
Benzo(b)fluoranthene ug/L 44.350 89 53-128
Benzo(g,h,i)perylene ug/L 38.250 76 54-125
Benzo(k)fluoranthene ug/L 41.250 82 51-123
Benzyl alcohol ug/L 52.4100 52 27-120
bis(2-Chloroethoxy)methane ug/L 33.550 67 32-120
bis(2-Chloroethyl) ether ug/L 29.850 60 33-111
bis(2-Ethylhexyl)phthalate ug/L 51.450 103 50-145
Butylbenzylphthalate ug/L 51.350 103 54-138
Chlorobenzilate ug/L 42.350 85 65-132
Chrysene ug/L 42.650 85 58-127
Di-n-butylphthalate ug/L 50.250 100 56-125
Di-n-octylphthalate ug/L 53.250 106 50-134
Diallate ug/L 43.750 87 47-123
Dibenz(a,h)anthracene ug/L 40.550 81 53-129
Dibenzofuran ug/L 37.850 76 45-120
Diethylphthalate ug/L 46.7J50 93 53-120
Dimethoate ug/L 43.150 86 57-139
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 66 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
Dimethylphthalate ug/L 44.550 89 55-116
Diphenylamine ug/L 38.950 78 42-120
Disulfoton ug/L 46.450 93 49-156
Ethyl methanesulfonate ug/L 41.050 82 43-120
Famphur ug/L 55.2100 55 40-160
Fluoranthene ug/L 45.550 91 57-125
Fluorene ug/L 40.850 82 53-118
Hexachloro-1,3-butadiene ug/L 25.350 51 23-120
Hexachlorobenzene ug/L 39.250 78 49-116
Hexachlorocyclopentadiene ug/L 30.850 62 26-158
Hexachloroethane ug/L 22.450 45 30-114
Hexachloropropene ug/L 32.450 65 13-137
Indeno(1,2,3-cd)pyrene ug/L 40.950 82 55-128
Isodrin ug/L 45.050 90 68-129
Isophorone ug/L 43.850 88 31-118
Isosafrole ug/L 35.850 72 48-107
Kepone ug/L 47.3100 47 10-124
Methapyrilene ug/L 46.9J50 94 40-160
Methyl methanesulfonate ug/L 34.050 68 25-114
Methyl parathion ug/L 49.450 99 58-137
N-Nitroso-di-n-butylamine ug/L 32.950 66 36-115
N-Nitroso-di-n-propylamine ug/L 33.850 68 32-119
N-Nitrosodiethylamine ug/L 33.450 67 47-115
N-Nitrosodimethylamine ug/L 21.850 44 13-120
N-Nitrosodiphenylamine ug/L 38.950 78 43-120
N-Nitrosomethylethylamine ug/L 31.350 63 39-120
N-Nitrosopiperidine ug/L 39.150 78 43-113
N-Nitrosopyrrolidine ug/L 29.850 60 32-110
Nitrobenzene ug/L 42.650 85 33-110
O,O,O-Triethylphosphorothioate ug/L 41.550 83 51-127
O-Toluidine ug/L 30.150 60 27-120
P-Dimethylaminoazobenzene ug/L 19.2100 19 10-120
p-Phenylenediamine ug/L 49.050 98 72-143
Parathion (Ethyl parathion)ug/L 53.050 106 56-140
Pentachlorobenzene ug/L 41.550 83 30-137
Pentachloronitrobenzene ug/L 52.550 105 70-124
Pentachlorophenol ug/L 81.3250 33 10-137
Phenacetin ug/L 44.950 90 60-130
Phenanthrene ug/L 41.250 82 57-117
Phenol ug/L 13.850 28 10-120
Phorate ug/L 53.950 108 55-126
Pronamide ug/L 55.750 111 75-124
Pyrene ug/L 44.450 89 55-122
Safrole ug/L 39.250 78 41-120
Thionazin ug/L 43.850 88 63-137
2,4,6-Tribromophenol (S)%85 27-110
2-Fluorobiphenyl (S)%70 27-110
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 67 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934958LABORATORY CONTROL SAMPLE:
LCSSpike
2-Fluorophenol (S)%35 12-110
Nitrobenzene-d5 (S)%77 21-110
Phenol-d6 (S)%25 10-110
Terphenyl-d14 (S)%88 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
1,2,4,5-Tetrachlorobenzene ug/L 44.150 88 50-150ND
1,3,5-Trinitrobenzene ug/L 68.750 137 50-150ND
1,3-Dinitrobenzene ug/L 50.350 101 50-150ND
1,4-Naphthoquinone ug/L 49.250 98 50-150ND
1-Naphthalenamine ug/L 28.050 56 50-150ND
2,2'-Oxybis(1-chloropropane)ug/L 34.250 68 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 60.650 121 50-150ND
2,4,5-Trichlorophenol ug/L 40.150 80 19-105ND
2,4,6-Trichlorophenol ug/L 48.550 97 13-108ND
2,4-Dichlorophenol ug/L 41.150 82 29-111ND
2,4-Dimethylphenol ug/L 39.950 80 21-103ND
2,4-Dinitrophenol ug/L 234250 94 10-109ND
2,4-Dinitrotoluene ug/L 55.7 M150111 27-104ND
2,6-Dichlorophenol ug/L 47.550 95 50-150ND
2,6-Dinitrotoluene ug/L 53.2 M150106 28-101ND
2-Acetylaminofluorene ug/L 51.550 103 50-150ND
2-Chloronaphthalene ug/L 45.850 92 14-102ND
2-Chlorophenol ug/L 35.150 70 16-110ND
2-Methylnaphthalene ug/L 39.450 79 13-110ND
2-Methylphenol(o-Cresol)ug/L 27.750 55 19-110ND
2-Naphthalenamine ug/L 37.350 75 50-150ND
2-Nitroaniline ug/L 102100 102 26-103ND
2-Nitrophenol ug/L 38.250 76 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 22.050 44 20-110ND
3,3'-Dichlorobenzidine ug/L 90.2250 36 25-112ND
3,3'-Dimethylbenzidine ug/L 34.0 M110034 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 88.2100 88 29-110ND
4,6-Dinitro-2-methylphenol ug/L 92.0100 92 10-117ND
4-Aminobiphenyl ug/L 34.350 69 50-150ND
4-Bromophenylphenyl ether ug/L 43.750 87 20-105ND
4-Chloro-3-methylphenol ug/L 84.4100 84 22-110ND
4-Chloroaniline ug/L 73.1100 73 20-100ND
4-Chlorophenylphenyl ether ug/L 43.050 86 19-102ND
4-Nitroaniline ug/L 92.9100 93 29-110ND
4-Nitrophenol ug/L 139250 55 10-110ND
5-Nitro-o-toluidine ug/L 49.050 98 50-150ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 68 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
7,12-Dimethylbenz(a)anthracene ug/L 42.050 84 50-150ND
Acenaphthene ug/L 42.950 86 17-100ND
Acenaphthylene ug/L 43.250 86 21-100ND
Acetophenone ug/L 38.050 76 50-150ND
Anthracene ug/L 46.050 92 24-109ND
Benzo(a)anthracene ug/L 48.550 97 22-117ND
Benzo(a)pyrene ug/L 45.150 90 23-104ND
Benzo(b)fluoranthene ug/L 47.350 95 23-103ND
Benzo(g,h,i)perylene ug/L 43.850 88 18-111ND
Benzo(k)fluoranthene ug/L 45.250 90 22-113ND
Benzyl alcohol ug/L 61.4100 61 19-101ND
bis(2-Chloroethoxy)methane ug/L 37.850 76 22-110ND
bis(2-Chloroethyl) ether ug/L 36.250 72 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 56.5 M150113 23-102ND
Butylbenzylphthalate ug/L 55.5 M150111 25-110ND
Chlorobenzilate ug/L 47.150 94 50-150ND
Chrysene ug/L 47.250 94 23-115ND
Di-n-butylphthalate ug/L 54.450 109 26-110ND
Di-n-octylphthalate ug/L 58.2 M150116 22-110ND
Diallate ug/L 47.450 95 50-150ND
Dibenz(a,h)anthracene ug/L 45.150 90 21-112ND
Dibenzofuran ug/L 42.350 85 19-102ND
Diethylphthalate ug/L 50.5J50 101 29-110ND
Dimethoate ug/L 48.750 97 50-150ND
Dimethylphthalate ug/L 48.350 97 27-110ND
Diphenylamine ug/L 43.550 87 50-150ND
Disulfoton ug/L 53.050 106 50-150ND
Ethyl methanesulfonate ug/L 48.850 98 50-150ND
Famphur ug/L 71.1100 71 50-150ND
Fluoranthene ug/L 49.950 100 23-112ND
Fluorene ug/L 45.350 91 22-104ND
Hexachloro-1,3-butadiene ug/L 36.450 73 10-110ND
Hexachlorobenzene ug/L 44.050 88 21-116ND
Hexachlorocyclopentadiene ug/L 41.250 82 10-110ND
Hexachloroethane ug/L 33.350 67 10-110ND
Hexachloropropene ug/L 45.650 91 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 45.450 91 20-113ND
Isodrin ug/L 48.450 97 50-150ND
Isophorone ug/L 49.750 99 50-150ND
Isosafrole ug/L 41.150 82 50-150ND
Kepone ug/L 45.1 M110045 50-150ND
Methapyrilene ug/L 42.4J50 85 50-150ND
Methyl methanesulfonate ug/L 41.350 83 50-150ND
Methyl parathion ug/L 55.450 111 50-150ND
N-Nitroso-di-n-butylamine ug/L 38.450 77 50-150ND
N-Nitroso-di-n-propylamine ug/L 43.050 86 21-105ND
N-Nitrosodiethylamine ug/L 43.150 86 50-150ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Page 69 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1934959MATRIX SPIKE SAMPLE:
MSSpike
Result
92330376002
N-Nitrosodimethylamine ug/L 25.550 51 10-110ND
N-Nitrosodiphenylamine ug/L 43.550 87 23-107ND
N-Nitrosomethylethylamine ug/L 39.350 79 50-150ND
N-Nitrosopiperidine ug/L 46.950 94 50-150ND
N-Nitrosopyrrolidine ug/L 40.950 82 50-150ND
Nitrobenzene ug/L 49.150 98 20-110ND
O,O,O-Triethylphosphorothioate ug/L 49.850 100 50-150ND
O-Toluidine ug/L 36.050 72 50-150ND
P-Dimethylaminoazobenzene ug/L 20.5 M110021 50-150ND
p-Phenylenediamine ug/L 52.750 105 50-150ND
Parathion (Ethyl parathion)ug/L 60.650 121 50-150ND
Pentachlorobenzene ug/L 45.750 91 50-150ND
Pentachloronitrobenzene ug/L 58.450 117 50-150ND
Pentachlorophenol ug/L 100250 40 10-118ND
Phenacetin ug/L 50.250 100 50-150ND
Phenanthrene ug/L 44.950 90 24-106ND
Phenol ug/L 17.050 34 12-110ND
Phorate ug/L 59.250 118 50-150ND
Pronamide ug/L 60.650 121 50-150ND
Pyrene ug/L 48.950 98 24-114ND
Safrole ug/L 47.050 94 50-150ND
Thionazin ug/L 50.150 100 50-150ND
2,4,6-Tribromophenol (S)%94 27-110
2-Fluorobiphenyl (S)%80 27-110
2-Fluorophenol (S)%42 12-110
Nitrobenzene-d5 (S)%88 21-110
Phenol-d6 (S)%31 10-110
Terphenyl-d14 (S)%87 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,2'-Oxybis(1-chloropropane)ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
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Page 70 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 71 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%61 2781
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 72 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376003
1934960SAMPLE DUPLICATE:
2-Fluorobiphenyl (S)%72 1181
2-Fluorophenol (S)%32 634
Nitrobenzene-d5 (S)%73 1686
Phenol-d6 (S)%19 720
Terphenyl-d14 (S)%81 22100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 73 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349117
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92330376004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936703
Associated Lab Samples:92330376004
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/22/17 00:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936704LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4710050000 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936705MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330450002
1936706
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 25500009.5 mg/L 58100 58100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936707MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330336002
1936708
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 255000012.1 mg/L 60800 60600
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 74 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349506
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938991
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/23/17 22:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938992LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4810050000 96 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330946002
1938994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12094 0 255000093.3 mg/L 141000 141000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938995MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330376003
1938996
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 99 80-12098 0 2550000ND49300 49200
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 75 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348807
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92330376004
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1935381
Associated Lab Samples:92330376004
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 02/17/17 15:5525000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1935382LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 234000250000 94 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329940010
1935383SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330376004
1935384SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 127000 D669562000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 76 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349078
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936587
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 02/21/17 01:5825000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936588LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 238000250000 95 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329937009
1936589SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 105000 D614591.0 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92330213019
1936590SAMPLE DUPLICATE:
Total Dissolved Solids ug/L ND 5ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 77 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349132
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936732
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/21/17 14:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936733LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 544J500 109 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936734MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233001
1936735
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M150013080-120130 0 10500ND680J 680J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936736MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330310001
1936737
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M150012180-120121 0 10500ND627J 627J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 78 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349158
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936889
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 02/21/17 20:321000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936890LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936891MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330376001
1936892
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M1200009090-11088 0 102000047100J65000J 64800J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 79 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349484
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938963
Associated Lab Samples:92330376001, 92330376002, 92330376003, 92330376004, 92330376005, 92330376006, 92330376007
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/24/17 02:32500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938964LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 2060020000 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938965MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330797001
1938966
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M6100008990-11096 1 101000040.8 mg/L 49800 50400
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1938967MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330376002
1938968
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M1,R11000012390-110215 14 10100004920061400 70700
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 80 of 87
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349534
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92330376001, 92330376002, 92330376003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1939073
Associated Lab Samples:92330376001, 92330376002, 92330376003
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 02/23/17 17:554.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1939074LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 99.6100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939075MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330486015
1939076
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1,R11003780-12045 11 101000.035mg/L 71.8 80.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1939077MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330266002
1939078
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 104 80-12095 8 10100ND106 97.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 81 of 87
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Analyte concentration exceeded the calibration range. The reported result is estimated.E
Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associatedsamples may be biased high.L1
Analyte recovery in the laboratory control sample (LCS) exceeded QC limits. Analyte presence below reporting limits inassociated samples.L3
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
RPD value was outside control limits.R1
Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.S3
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 82 of 87
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330376001 348796 3489403901-MW7 EPA 3510 EPA 8081
92330376002 348796 3489403901-MW5R EPA 3510 EPA 8081
92330376003 348796 348940FIELD BLANK EPA 3510 EPA 8081
92330376001 348597 3487693901-MW7 EPA 3510 EPA 8082
92330376002 348597 3487693901-MW5R EPA 3510 EPA 8082
92330376003 348597 348769FIELD BLANK EPA 3510 EPA 8082
92330376001 351621 3523973901-MW7 EPA 8151 EPA 8151
92330376002 351621 3523973901-MW5R EPA 8151 EPA 8151
92330376003 351621 352397FIELD BLANK EPA 8151 EPA 8151
92330376001 348742 3489023901-MW7 EPA 3010A EPA 6010
92330376002 348742 3489023901-MW5R EPA 3010A EPA 6010
92330376003 348742 348902FIELD BLANK EPA 3010A EPA 6010
92330376004 348742 3489023901-MW2 EPA 3010A EPA 6010
92330376005 348994 3490913901-MW3R EPA 3010A EPA 6010
92330376006 348994 3490913901-MW4R EPA 3010A EPA 6010
92330376007 348994 3490913901-MW6R EPA 3010A EPA 6010
92330376008 348994 3490913901-SW1 EPA 3010A EPA 6010
92330376009 348994 3490913901-SW2 EPA 3010A EPA 6010
92330376001 348672 3488643901-MW7 EPA 3010A EPA 6020B
92330376002 348672 3488643901-MW5R EPA 3010A EPA 6020B
92330376003 348672 348864FIELD BLANK EPA 3010A EPA 6020B
92330376004 348672 3488643901-MW2 EPA 3010A EPA 6020B
92330376005 348672 3488643901-MW3R EPA 3010A EPA 6020B
92330376006 348672 3488643901-MW4R EPA 3010A EPA 6020B
92330376007 348672 3488643901-MW6R EPA 3010A EPA 6020B
92330376008 348672 3488643901-SW1 EPA 3010A EPA 6020B
92330376009 348672 3488643901-SW2 EPA 3010A EPA 6020B
92330376001 349177 3492843901-MW7 EPA 7470 EPA 7470
92330376002 349177 3492843901-MW5R EPA 7470 EPA 7470
92330376003 349177 349284FIELD BLANK EPA 7470 EPA 7470
92330376004 349177 3492843901-MW2 EPA 7470 EPA 7470
92330376005 349177 3492843901-MW3R EPA 7470 EPA 7470
92330376006 349177 3492843901-MW4R EPA 7470 EPA 7470
92330376007 349177 3492843901-MW6R EPA 7470 EPA 7470
92330376001 348764 3489793901-MW7 EPA 3510 EPA 8270
92330376002 348764 3489793901-MW5R EPA 3510 EPA 8270
92330376003 348764 348979FIELD BLANK EPA 3510 EPA 8270
92330376001 3491933901-MW7 EPA 8260
92330376002 3491933901-MW5R EPA 8260
92330376003 349146FIELD BLANK EPA 8260
92330376004 3491933901-MW2 EPA 8260
92330376005 3491933901-MW3R EPA 8260
92330376006 3491933901-MW4R EPA 8260
92330376007 3491933901-MW6R EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 83 of 87
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330376
OXFORD COMPLIANCE UNIT 1
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330376008 3491463901-SW1 EPA 8260
92330376009 3491463901-SW2 EPA 8260
92330376010 349146TRIP BLANK EPA 8260
92330376001 3495063901-MW7 SM 2320B
92330376002 3495063901-MW5R SM 2320B
92330376003 349506FIELD BLANK SM 2320B
92330376004 3491173901-MW2 SM 2320B
92330376005 3495063901-MW3R SM 2320B
92330376006 3495063901-MW4R SM 2320B
92330376007 3495063901-MW6R SM 2320B
92330376001 3490783901-MW7 SM 2540C
92330376002 3490783901-MW5R SM 2540C
92330376003 349078FIELD BLANK SM 2540C
92330376004 3488073901-MW2 SM 2540C
92330376005 3490783901-MW3R SM 2540C
92330376006 3490783901-MW4R SM 2540C
92330376007 3490783901-MW6R SM 2540C
92330376001 3491323901-MW7 SM 4500-S2D
92330376002 3491323901-MW5R SM 4500-S2D
92330376003 349132FIELD BLANK SM 4500-S2D
92330376001 3491583901-MW7 EPA 300.0
92330376002 3491583901-MW5R EPA 300.0
92330376003 349158FIELD BLANK EPA 300.0
92330376004 3491583901-MW2 EPA 300.0
92330376005 3491583901-MW3R EPA 300.0
92330376006 3491583901-MW4R EPA 300.0
92330376007 3491583901-MW6R EPA 300.0
92330376001 3494843901-MW7 SM 4500-Cl-E
92330376002 3494843901-MW5R SM 4500-Cl-E
92330376003 349484FIELD BLANK SM 4500-Cl-E
92330376004 3494843901-MW2 SM 4500-Cl-E
92330376005 3494843901-MW3R SM 4500-Cl-E
92330376006 3494843901-MW4R SM 4500-Cl-E
92330376007 3494843901-MW6R SM 4500-Cl-E
92330376001 3495343901-MW7 SM 4500-CN-E
92330376002 3495343901-MW5R SM 4500-CN-E
92330376003 349534FIELD BLANK SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 02/28/2017 04:18 PM
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Page 84 of 87
Page 85 of 87
Page 86 of 87
Page 87 of 87
#=CL#
March 01, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92330310
92330310
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-NC2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
OXFORD UNIT 1 MNA
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontractedlaboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager1(704)875-9092
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 1 of 33
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 33
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Lab ID Sample ID Matrix Date Collected Date Received
92330310001 3901-MW7 Water 02/15/17 10:50 02/16/17 09:43
92330310002 3901-MW5R Water 02/15/17 09:00 02/16/17 09:43
92330310003 3901-NES2S Water 02/15/17 10:15 02/16/17 09:43
REPORT OF LABORATORY ANALYSIS
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Page 3 of 33
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92330310001 3901-MW7 RSK 175 Modified 3 PASI-CWDV
EPA 8260 4 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5310B 1 PASI-AAES2
92330310002 3901-MW5R RSK 175 Modified 3 PASI-CWDV
EPA 8260 4 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5310B 1 PASI-AAES2
92330310003 3901-NES2S RSK 175 Modified 3 PASI-CWDV
EPA 8260 4 PASI-CGAW
SM 2320B 1 PASI-AKDF
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
EPA 353.2 1 PASI-AWRC
SM 4500-Cl-E 1 PASI-ABRJ
SM 5310B 1 PASI-AAES2
REPORT OF LABORATORY ANALYSIS
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Page 4 of 33
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92330310001 3901-MW7
Alkalinity, Total as CaCO3 109000 ug/L 02/22/17 06:075000SM 2320B
Sulfate 46800J ug/L 02/22/17 13:081250000EPA 300.0
Nitrogen, Nitrate 220J ug/L 02/16/17 22:5610000EPA 353.2
Chloride 8650 ug/L 02/23/17 03:281000SM 4500-Cl-E
92330310002 3901-MW5R
Methane 94.9 ug/L 02/22/17 15:4010.0RSK 175 Modified
Vinyl chloride 0.69J ug/L 02/21/17 18:001.0EPA 8260
Alkalinity, Total as CaCO3 168000 ug/L 02/22/17 06:175000SM 2320B
Sulfate 3550J ug/L 02/21/17 20:13250000EPA 300.0
Nitrogen, Nitrate 87.5J ug/L 02/16/17 22:5710000EPA 353.2
Chloride 44700 ug/L 02/23/17 03:4010000SM 4500-Cl-E
Total Organic Carbon 1.7 mg/L 02/25/17 16:391.0SM 5310B
92330310003 3901-NES2S
Methane 336 ug/L 02/22/17 15:5510.0RSK 175 Modified
Alkalinity, Total as CaCO3 48200 ug/L 02/22/17 06:315000SM 2320B
Sulfate 5310J ug/L 02/21/17 20:22250000EPA 300.0
Nitrogen, Nitrate 11.6J ug/L 02/16/17 22:5810000EPA 353.2
Chloride 6830 ug/L 02/23/17 03:341000SM 4500-Cl-E
Total Organic Carbon 0.87J mg/L 02/25/17 17:271.0SM 5310B
REPORT OF LABORATORY ANALYSIS
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Page 5 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Sample: 3901-MW7 Lab ID: 92330310001 Collected: 02/15/17 10:50 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 02/22/17 15:24 74-84-010.0 10.0 1
Ethene ND ug/L 02/22/17 15:24 74-85-110.0 10.0 1
Methane ND ug/L 02/22/17 15:24 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 02/21/17 18:16 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)97 %02/21/17 18:16 460-00-470-130 1
1,2-Dichloroethane-d4 (S)104 %02/21/17 18:16 17060-07-070-130 1
Toluene-d8 (S)113 %02/21/17 18:16 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 109000 ug/L 02/22/17 06:075000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-8 M11000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 46800J ug/L 02/22/17 13:08 14808-79-81250000 5000 5
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 220J ug/L 02/16/17 22:5610000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 8650 ug/L 02/23/17 03:28 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon ND mg/L 02/25/17 16:06 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 6 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Sample: 3901-MW5R Lab ID: 92330310002 Collected: 02/15/17 09:00 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 02/22/17 15:40 74-84-010.0 10.0 1
Ethene ND ug/L 02/22/17 15:40 74-85-110.0 10.0 1
Methane 94.9 ug/L 02/22/17 15:40 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride 0.69J ug/L 02/21/17 18:00 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)97 %02/21/17 18:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)97 %02/21/17 18:00 17060-07-070-130 1
Toluene-d8 (S)120 %02/21/17 18:00 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 168000 ug/L 02/22/17 06:175000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 3550J ug/L 02/21/17 20:13 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 87.5J ug/L 02/16/17 22:5710000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 44700 ug/L 02/23/17 03:40 16887-00-610000 5000 10
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 1.7 mg/L 02/25/17 16:39 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 33
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Sample: 3901-NES2S Lab ID: 92330310003 Collected: 02/15/17 10:15 Received: 02/16/17 09:43 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Ethane ND ug/L 02/22/17 15:55 74-84-010.0 10.0 1
Ethene ND ug/L 02/22/17 15:55 74-85-110.0 10.0 1
Methane 336 ug/L 02/22/17 15:55 74-82-810.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Vinyl chloride ND ug/L 02/21/17 17:43 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)96 %02/21/17 17:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)106 %02/21/17 17:43 17060-07-070-130 1
Toluene-d8 (S)115 %02/21/17 17:43 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 48200 ug/L 02/22/17 06:315000 1000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 02/21/17 14:00 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 5310J ug/L 02/21/17 20:22 14808-79-8250000 1000 1
Analytical Method: EPA 353.2353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate 11.6J ug/L 02/16/17 22:5810000 10.0 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 6830 ug/L 02/23/17 03:34 16887-00-61000 500 1
Analytical Method: SM 5310B5310B TOC
Total Organic Carbon 0.87J mg/L 02/25/17 17:27 7440-44-01.0 0.50 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349352
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1938215
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Ethane ug/L ND 10.0 02/22/17 10:1910.0
Ethene ug/L ND 10.0 02/22/17 10:1910.0
Methane ug/L ND 10.0 02/22/17 10:1910.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1938216LABORATORY CONTROL SAMPLE:
LCSSpike
Ethane ug/L 740658 112 70-130
Ethene ug/L 12501120 112 70-130
Methane ug/L 377396 95 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1938217MATRIX SPIKE SAMPLE:
MSSpike
Result
92329927001
Ethane ug/L 881 M1658134 70-130ND
Ethene ug/L 12701120 113 70-130ND
Methane ug/L 1190396 111 70-130751
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92329927002
1938218SAMPLE DUPLICATE:
Ethane ug/L ND 20ND
Ethene ug/L ND 20ND
Methane ug/L 714 0 20713
REPORT OF LABORATORY ANALYSIS
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Page 9 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349193
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937163
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Vinyl chloride ug/L ND 1.0 02/21/17 11:120.62
1,2-Dichloroethane-d4 (S)%108 70-130 02/21/17 11:12
4-Bromofluorobenzene (S)%99 70-130 02/21/17 11:12
Toluene-d8 (S)%113 70-130 02/21/17 11:12
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937164LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl chloride ug/L 43.750 87 58-137
1,2-Dichloroethane-d4 (S)%89 70-130
4-Bromofluorobenzene (S)%104 70-130
Toluene-d8 (S)%92 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937165MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330577007
1937166
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Vinyl chloride ug/L M12015870-130141 11 3020ND31.5 28.3
1,2-Dichloroethane-d4 (S)%115 70-130117
4-Bromofluorobenzene (S) %99 70-130103
Toluene-d8 (S)%107 70-130104
REPORT OF LABORATORY ANALYSIS
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Page 10 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349117
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936703
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 02/22/17 00:331000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936704LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4710050000 94 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936705MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330450002
1936706
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 25500009.5 mg/L 58100 58100
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936707MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330336002
1936708
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 97 80-12097 0 255000012.1 mg/L 60800 60600
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:07 PM
Pace Analytical Services, LLC
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Page 11 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349132
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936732
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 02/21/17 14:00100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936733LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 544J500 109 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936734MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233001
1936735
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M150013080-120130 0 10500ND680J 680J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936736MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330310001
1936737
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M150012180-120121 0 10500ND627J 627J
REPORT OF LABORATORY ANALYSIS
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Page 12 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349156
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1936874
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 02/21/17 15:411000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1936876LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19500J20000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936877MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329937001
1936878
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 100 90-11099 0 1020000ND20000J 19900J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1936879MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92329937011
1936880
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 97 90-11097 0 10200005.0 mg/L 24500J 24500J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:07 PM
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[phone]
Page 13 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
348659
EPA 353.2
EPA 353.2
353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1934571
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Nitrogen, Nitrate ug/L ND 10000 02/16/17 22:1110.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1934572LABORATORY CONTROL SAMPLE:
LCSSpike
Nitrogen, Nitrate ug/L 2500J2500 100 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934573MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233003
1934574
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 102 90-110102 0 1025000.49 mg/L 3040J 3040J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1934575MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233005
1934576
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Nitrogen, Nitrate ug/L 2500 96 90-11096 0 1025000.063mg/L 2470J 2470J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 03/01/2017 03:07 PM
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[phone]
Page 14 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349277
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1937756
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 02/23/17 02:58500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1937757LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1980020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937758MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330233012
1937759
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 100 90-11099 0 10100001.4 mg/L 11300 11300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1937760MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330435003
1937761
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 107 90-110107 0 10100005.3 mg/L 16000 16000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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[phone]
Page 15 of 33
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
349750
SM 5310B
SM 5310B
5310B TOC
Associated Lab Samples: 92330310001, 92330310002, 92330310003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1940274
Associated Lab Samples:92330310001, 92330310002, 92330310003
Matrix: Water
AnalyzedMDL
Total Organic Carbon mg/L ND 1.0 02/25/17 12:020.50
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1940275LABORATORY CONTROL SAMPLE:
LCSSpike
Total Organic Carbon mg/L 27.325 109 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1940276MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330882001
1940277
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 25 101 90-110100 1 10251.9 27.3 27.0
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1940278MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92330310001
1940279
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Total Organic Carbon mg/L 25 101 90-110101 0 1025ND25.7 25.7
REPORT OF LABORATORY ANALYSIS
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Page 16 of 33
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte isa combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPAMethod 8260.N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 17 of 33
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92330310
OXFORD UNIT 1 MNA
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92330310001 3493523901-MW7 RSK 175 Modified
92330310002 3493523901-MW5R RSK 175 Modified
92330310003 3493523901-NES2S RSK 175 Modified
92330310001 3491933901-MW7 EPA 8260
92330310002 3491933901-MW5R EPA 8260
92330310003 3491933901-NES2S EPA 8260
92330310001 3491173901-MW7 SM 2320B
92330310002 3491173901-MW5R SM 2320B
92330310003 3491173901-NES2S SM 2320B
92330310001 3491323901-MW7 SM 4500-S2D
92330310002 3491323901-MW5R SM 4500-S2D
92330310003 3491323901-NES2S SM 4500-S2D
92330310001 3491563901-MW7 EPA 300.0
92330310002 3491563901-MW5R EPA 300.0
92330310003 3491563901-NES2S EPA 300.0
92330310001 3486593901-MW7 EPA 353.2
92330310002 3486593901-MW5R EPA 353.2
92330310003 3486593901-NES2S EPA 353.2
92330310001 3492773901-MW7 SM 4500-Cl-E
92330310002 3492773901-MW5R SM 4500-Cl-E
92330310003 3492773901-NES2S SM 4500-Cl-E
92330310001 3497503901-MW7 SM 5310B
92330310002 3497503901-MW5R SM 5310B
92330310003 3497503901-NES2S SM 5310B
REPORT OF LABORATORY ANALYSIS
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Page 21 of 33
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 21775 - 895351 Page 1 of 10
Kevin Godwin
Pace Analytical Services, Inc.9800 Kincey Avenue
Suite 100Huntersville, NC 28078
February 28, 2017
RE:
Pace Workorder:
OXFORD UNIT 1 MNA
Dear Kevin Godwin:
21775
Enclosed are the analytical results for sample(s) received by the laboratory on Tuesday, February 21, 2017.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwisenarrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 02/28/[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
12
Page 22 of 33
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 21775 - 895351 Page 2 of 10
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of EnvironmentalLaboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES isaccredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 23 of 33
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CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 21775 - 895351 Page 3 of 10
SAMPLE SUMMARY
Workorder: 21775 OXFORD UNIT 1 MNA
Lab ID Sample ID Matrix Date Collected Date Received
217750001 3901-MW7 Water 2/15/2017 10:50 2/21/2017 14:01
217750002 3901-MW5R Water 2/15/2017 09:00 2/21/2017 14:01
217750003 3901-NES2S Water 2/15/2017 10:15 2/21/2017 14:01
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ANALYTICAL RESULTS
Workorder: 21775 OXFORD UNIT 1 MNA
2/21/2017 14:01
3901-MW7
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217750001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/15/2017 10:50
EDonors - PAES
Analysis Desc: AM21G Analytical Method: AM21G
Acetic Acid 0.33U mg/l 5.0 1 2/24/2017 21:35 BW n0.33
Propionic Acid 0.052U mg/l 5.0 1 2/24/2017 21:35 BW n0.052
Pyruvic Acid 0.14U mg/l 5.0 1 2/24/2017 21:35 BW n0.14
Butyric Acid 0.055U mg/l 5.0 1 2/24/2017 21:35 BW n0.055
Lactic Acid 0.98U mg/l 10 1 2/24/2017 21:35 BW n0.98
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Fax: [phone]
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CERTIFICATE OF ANALYSIS
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Report ID: 21775 - 895351 Page 5 of 10
ANALYTICAL RESULTS
Workorder: 21775 OXFORD UNIT 1 MNA
2/21/2017 14:01
3901-MW5R
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217750002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/15/2017 09:00
EDonors - PAES
Analysis Desc: AM21G Analytical Method: AM21G
Acetic Acid 0.71J mg/l 5.0 1 2/24/2017 21:57 BW n0.33
Propionic Acid 0.052U mg/l 5.0 1 2/24/2017 21:57 BW n0.052
Pyruvic Acid 0.14U mg/l 5.0 1 2/24/2017 21:57 BW n0.14
Butyric Acid 0.055U mg/l 5.0 1 2/24/2017 21:57 BW n0.055
Lactic Acid 0.98U mg/l 10 1 2/24/2017 21:57 BW n0.98
220 William Pitt Way
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Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 26 of 33
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
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Report ID: 21775 - 895351 Page 6 of 10
ANALYTICAL RESULTS
Workorder: 21775 OXFORD UNIT 1 MNA
2/21/2017 14:01
3901-NES2S
Matrix: Water
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217750003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/15/2017 10:15
EDonors - PAES
Analysis Desc: AM21G Analytical Method: AM21G
Acetic Acid 0.95J mg/l 5.0 1 2/24/2017 22:19 BW n0.33
Propionic Acid 0.052U mg/l 5.0 1 2/24/2017 22:19 BW n0.052
Pyruvic Acid 0.14U mg/l 5.0 1 2/24/2017 22:19 BW n0.14
Butyric Acid 0.055U mg/l 5.0 1 2/24/2017 22:19 BW n0.055
Lactic Acid 0.98U mg/l 10 1 2/24/2017 22:19 BW n0.98
220 William Pitt Way
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Fax: [phone]
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Report ID: 21775 - 895351 Page 7 of 10
ANALYTICAL RESULTS QUALIFIERS
Workorder: 21775 OXFORD UNIT 1 MNA
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
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Fax: [phone]
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Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 21775 - 895351 Page 8 of 10
QUALITY CONTROL DATA
Workorder: 21775 OXFORD UNIT 1 MNA
QC Batch:
QC Batch Method:
EDON/3255
AM21G
Analysis Method: AM21G
Associated Lab Samples:217750001, 217750002, 217750003
METHOD BLANK: 47123
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
EDonors
Acetic Acid 0.33Umg/l 0.33 n
Propionic Acid 0.052Umg/l 0.052 n
Pyruvic Acid 0.14Umg/l 0.14 n
Butyric Acid 0.055Umg/l 0.055 n
Lactic Acid 0.98Umg/l 0.98 n
LABORATORY CONTROL SAMPLE:
Parameter Units Conc.
Spike
Result
LCS
Qualifiers
LCS
% Rec
% Rec
Limits
47124
EDonors
Acetic Acid 100mg/l 100 n102 70-130
Propionic Acid 100mg/l 99 n99 70-130
Pyruvic Acid 100mg/l 94 n94 70-130
Butyric Acid 100mg/l 97 n97 70-130
Lactic Acid 100mg/l 82 n83 70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
Parameter Units Conc.
Spike
Result
MS
47125 47126
MSD
Result % Rec
MS MSD
% Rec
% Rec
Limit RPD RPD
Max
QualifiersResult
Original
217740001Original:
EDonors
Acetic Acid mg/l 100 99 99 70-130 n1001023 200
Propionic Acid mg/l 100 97 97 70-130 n1001003 200
Pyruvic Acid mg/l 100 93 93 70-130 n95952.1 200
Butyric Acid mg/l 100 96 96 70-130 n1001004.1 200
Lactic Acid mg/l 100 79 79 70-130 n80801.3 200
220 William Pitt Way
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CERTIFICATE OF ANALYSIS
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Report ID: 21775 - 895351 Page 9 of 10
QUALITY CONTROL DATA QUALIFIERS
Workorder: 21775 OXFORD UNIT 1 MNA
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
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Report ID: 21775 - 895351 Page 10 of 10
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 21775 OXFORD UNIT 1 MNA
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
217750001 3901-MW7 EDON/3255AM21G
217750002 3901-MW5R EDON/3255AM21G
217750003 3901-NES2S EDON/3255AM21G
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Page 33 of 33
#=CL#
March 01, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92330351
92330351
Project:
Pace Project No.:
RE:
Mr. Van BurbachJoyce Engineering-NC2211 West Meadowview RdBoone Bldg, Suite 101Greensboro, NC 27407
OXFORD DISSOLVED HYDROGEN
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 16, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontractedlaboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager1(704)875-9092
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 18
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92330351
OXFORD DISSOLVED HYDROGEN
Lab ID Sample ID Matrix Date Collected Date Received
92330351001 3901-MW7 Water 02/14/17 10:50 02/16/17 09:43
92330351002 3901-MW5R Water 02/14/17 09:00 02/16/17 09:43
92330351003 3901-NES2S Water 02/14/17 10:15 02/16/17 09:43
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Huntersville, NC 28078
[phone]
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Page 5 of 18
Pace Analytical Energy Services LLC
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
Report ID: 21797 - 895251 Page 1 of 11
Kevin Godwin
Pace Analytical Services, Inc.9800 Kincey Avenue
Suite 100Huntersville, NC 28078
February 28, 2017
RE:
Pace Workorder:
OXFORD DISSOLVED HYDROGEN
Dear Kevin Godwin:
21797
Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, February 22, 2017.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwisenarrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Enclosures
Ruth Welsh 02/28/[e-mail]
Total Number of Pages ____
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Customer Service Representative
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
13
Page 6 of 18
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Report ID: 21797 - 895251 Page 2 of 11
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Pennsylvania Department of Environmental Protection, Bureau of Laboratories
02-00538
NELAP Non-Potable Water and Solid & Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
395
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
South Carolina Department of Health and Environmental Control, Office of EnvironmentalLaboratory Certification
89009003
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: New Jersey, Department of Environmental Protection
PA026
Non-Potable Water; Solid and Chemical Materials
Accreditor:
Accreditation ID:
Scope:
NELAP: New York, Department of Health Wadsworth Center
11815
Non-Potable Water; Solid and Hazardous Waste
Accreditor:
Accreditation ID:
Scope:
State of Connecticut, Department of Public Health, Division of Environmental Health
PH-0263
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
Accreditation ID:
Scope:
NELAP: Texas, Commission on Environmental Quality
T104704453-09-TX
Non-Potable Water
Accreditor:
Accreditation ID:
Scope:
State of New Hampshire
299409
Non-potable water
Accreditor:
Accreditation ID:
Scope:
State of Georgia
Chapter 391-3-26
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES isaccredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Accreditor:
Accreditation ID:
Scope:
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
without the written consent of Pace Analytical Energy Services LLC.
Page 7 of 18
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SAMPLE SUMMARY
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
Lab ID Sample ID Matrix Date Collected Date Received
217970001 3901-MW7 Bubble Strip 2/14/2017 10:50 2/22/2017 13:35
217970002 3901-MW5R Bubble Strip 2/14/2017 09:00 2/22/2017 13:35
217970003 3901-NES2S Bubble Strip 2/14/2017 10:15 2/22/2017 13:35
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PROJECT SUMMARY
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
Sample Comments
Lab ID:217970003 Sample ID:3901-NES2S Sample Type:N
Sample headspace vial not sufficiently pressurized for analysis. Vial pressurized with an equal volume of UHP Nitrogen andanalyzed. Results reported at a dilution.
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ANALYTICAL RESULTS
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
2/22/2017 13:35
3901-MW7
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217970001
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/14/2017 10:50
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.2 nM 0.60 1 2/27/2017 13:40 MM n0.075
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ANALYTICAL RESULTS
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
2/22/2017 13:35
3901-MW5R
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217970002
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/14/2017 09:00
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.1 nM 0.60 1 2/27/2017 13:52 MM n0.075
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ANALYTICAL RESULTS
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
2/22/2017 13:35
3901-NES2S
Matrix: Bubble Strip
RegLmtParameters
Lab ID:
Sample ID:
RegLmt
217970003
Results Units PQL DF ByAnalyzedMDL Qualifiers
Date Collected:
Date Received:
2/14/2017 10:15
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.2 nM 1.2 2 2/27/2017 14:06 MM d,n0.15
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ANALYTICAL RESULTS QUALIFIERS
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
DEFINITIONS/QUALIFIERS
U
J
Indicates the compound was analyzed for, but not detected at or above the noted concentration.
Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
The analyte concentration was determined from a dilution.d
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QUALITY CONTROL DATA
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
QC Batch:
QC Batch Method:
DISG/5936
AM20GAX
Analysis Method: AM20GAX
Associated Lab Samples:217970001, 217970002, 217970003
METHOD BLANK: 47249
Parameter Units Result
Blank
Limit
Reporting
Qualifiers
RISK
Hydrogen 0.075UnM 0.075 n
LABORATORY CONTROL SAMPLE & LCSD:
Parameter Units Conc.
Spike
Result
LCS
47250 47251
LCSD
Result % Rec
LCS LCSD
% Rec
% Rec
Limit RPD RPD
Max
Qualifiers
RISK
Hydrogen nM 24 27 110 80-120 n271110.9 20
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QUALITY CONTROL DATA QUALIFIERS
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.n
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 21797 OXFORD DISSOLVED HYDROGEN
Lab ID Sample ID Prep Method Analysis MethodPrep Batch Batch
Analysis
217970001 3901-MW7 DISG/5936AM20GAX
217970002 3901-MW5R DISG/5936AM20GAX
217970003 3901-NES2S DISG/5936AM20GAX
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Page 18 of 18

Appendix C

Historical Detected Inorganic Constituents in Compliance Wells

APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksInorganic CompoundsAntimony 14-Sep-94 --- 30 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-94 --- 30 ND ND ---ND ND ---ND ---ND ---ND------8-Feb-95 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND------2-Mar-95 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------17-Nov-95 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------14-Nov-96 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------18-Jun-97 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 --- 30.0 ND ND ---ND ND ---ND ---ND ---ND ------16-Nov-98 --- 30.0 6 ND ---ND ND ---ND ---ND ---ND ------10-Sep-99 --- 30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 --- 30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---10-May-00 --- 30.0 32 ND ---ND ---ND ---ND ---68 ---ND ---26-Oct-00 --- 30.0 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 --- 30 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 --- 30 ---ND ---ND ---ND ---ND ---ND ---ND ---13-Jun-02 --- 30 ---ND ---ND ---ND ---ND ---ND ---ND ---19-Nov-02 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ---30-Dec-03 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-05 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 30.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND2-Jul-07 --- 6.0 ---ND ---ND ---ND ---ND ---ND ---ND NDGWPS = 1.4 µg/L (10/23/07)19-Dec-07 --- 6.0 ---------ND ---ND ---ND ---ND ---ND ND8-Jul-08 --- 6.0 --- ND# ---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND8-Jul-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 2.6 6.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 1 µg/L (08/01/10)14-Dec-10 2.6 6.0 ---------ND ---ND ---ND ---ND ---ND ND21-Jun-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND11-Dec-12 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND13-Aug-14 5.0 6.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND18-Feb-16 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 3.8 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
15-Feb-17 3.9 6.0 ------ND ND ---ND ---ND ---ND ---ND ND
Arsenic 14-Sep-94 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-94 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------17-Nov-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
23-May-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------18-Jun-97 --- 10 ND 7.0 --- 14.0 14.0 ---ND ---ND ---5.0 ------2-Dec-97 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 --- 10 ND ND ---ND 5.0 ---ND ---ND ---ND ------
16-Nov-98 --- 10 ND ND --- 12.0 8.0 ---ND ---ND ---6.0 ------10-Sep-99 --- 10 ND ND ---ND ---ND ---ND --- 11.0 ---ND ---
16-Nov-99 ---10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 10 ---4.4 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 10 ---ND ---4.9 J ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 --- 10 ---------2.9 J ---ND ---ND ---ND ---ND ND8-Jul-08 --- 10.0 ---182#---3.7 J ---ND ---ND ---ND ---ND ND16-Dec-08 2.7 11.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 2.7 10.0 ---9.7 J ---ND ---ND ---4.9 J ---ND ---2.9 J ND
15-Dec-09 2.7 10.0 ---ND ---3.2 J ---ND ---ND ---ND ---ND NDNC 2L = 10 µg/L (2/5/10)23-Jun-10 2.7 10.0 ---5.9 J ---2.7 J ---ND ---5.2 J ---ND ---4.4 J ND
14-Dec-10 2.7 10.0 ---------ND ---ND ---4.4 J ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 5.5 J ---2.9 J ---3.8 J ---ND ---ND ND19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------ND 3.5 J ---ND ---3.2 J ---ND ---3.7 J ND15-Feb-17 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksBarium14-Sep-94 --- 500 680 680 ---260 580 --- 30,300 ---ND --- 1,740 ------2-Dec-94 --- 500 ND ND ---ND ND ---540 ---ND ---ND ------
8-Feb-95 --- 500 ND ND ---ND ND ---621 ---ND ---ND ------
2-Mar-95 --- 500 ND ND ---ND 541 --- 2,710 ---ND ---ND ------17-Nov-95 --- 500 ND ND ---ND ND --- 2,440 ---ND ---ND ------23-May-96 --- 500 ND ND ---ND ND ---0 ---ND ---ND ------
14-Nov-96 --- 500 2,500 510 ---600 480 --- 1,700 ---39 ---21 ------
18-Jun-97 --- 500 960 1,200 ---280 720 --- 3,400 ---93 ---700 ------2-Dec-97 --- 500 1,100 410 ---150 510 --- 4,300 ---68 ---260 ------27-May-98 --- 500 2,100 310 ---95 660 --- 2,800 ---69 ---350 ------
16-Nov-98 --- 500 5,000 3,200 --- 4,800 7,600 --- 10,000 ---100 --- 5,900 ------
10-Sep-99 --- 500 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 500 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 500 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 500 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 500 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 100 --- 15.4 --- 30.8 --- 24.8 --- 78.5 --- 33.4 --- 77.4 0.20 J
NC 2L = 2,000 µg/L (10/23/07)12-Jul-07 --- 100 --- 19.4 J --- 13.8 J --- 24.5 J --- 82.5 J --- 27.3 J --- 76.2 J ND
19-Dec-07 --- 100 --------- 14.7 B --- 20.1 B --- 28.7 B --- 27.2 B --- 64.9 10.58-Jul-08 --- 100 ---5360#--- 21.7 J --- 19.6 J --- 54.1 J --- 35.3 J --- 78.2 J 0.29 J16-Dec-08 0.20 100 --- 19.4 B --- 11.2 B --- 16.5 B --- 27.0 B --- 38.8 B --- 66.7 J 10.7 J
8-Jul-09 0.20 100 ---213 --- 11.9 B --- 26.6 B --- 74.6 B --- 34.2 B --- 78.4 B 17.6 J
15-Dec-09 0.20 100 --- 12.6 B --- 16.4 B --- 18.8 B --- 38.2 B --- 39.8 B --- 89.3 J 17.1 JNC 2L = 700 µg/L (2/5/10)23-Jun-10 0.20 100 --- 61.2 B --- 12.0 B --- 17.7 B ---107 B --- 36.7 B --- 74.2 B 27.3 J14-Dec-10 0.20 100 --------- 11.7 B --- 26.8 B --- 37.6 B --- 46.1 B --- 79.0 J 12.1 J
21-Jun-11 5.0 100 ------6.8 J 14.6 J --- 18.6 J --- 37.2 J --- 41.7 J --- 78.7 J ND
6-Dec-11 5.0 100 ------ 16.2 J 13.2 J --- 27.8 J --- 38.4 J --- 43.3 J --- 83.7 J ND13-Jun-12 5.0 100 ------9.2 J 16.5 J --- 20.4 J --- 52.2 J --- 39.0 J --- 82.2 J ND
11-Dec-12 5.0 100 ------5.2 J 12.6 J --- 17.2 J --- 32.1 J --- 47.3 J --- 81.9 J ND
29-Apr-13 5.0 100 ------ND 14.7 J --- 19.6 J --- 37.6 J --- 42.2 J --- 81.8 J ND6-Aug-13 5.0 100 ------ND 19.7 J --- 18.7 J --- 39.8 J --- 43.1 J --- 84.7 J ND25-Feb-14 5.0 100 ------5.6 J 15.3 J --- 52.7 J --- 38.0 J --- 48.0 J --- 77.0 J ND
13-Aug-14 5.0 100 ------ND 19.0 J --- 28.4 J --- 37.7 J --- 49.6 J --- 92.6 J ND
12-Mar-15 2.5 100 ------ 12.4 J 13.3 J --- 28.0 J --- 38.6 J --- 38.9 J --- 93.1 J ND19-Aug-15 2.5 100 ------4.9 J 17.5 J --- 25.3 J --- 36.2 J --- 42.2 J --- 90.5 J ND
18-Feb-16 2.5 100 ------4.4 J 12.1 J --- 15.7 J --- 36.4 J --- 36.7 J --- 98.2 J ND
11-Aug-16 2.5 100 ------3.9 J 22.4 J --- 16.1 J --- 42.1 J --- 38.6 J ---102 ND15-Feb-17 2.5 100 ------6.1 J 18.2 J --- 18.6 J --- 37.2 J --- 38.9 J ---102 ND
Beryllium 14-Sep-94 --- 2 ND ND ---ND ND ---200 ---ND ---ND ------
2-Dec-94 --- 2 2.0 ND ---ND 4.0 ---2.0 ---ND ---ND ------8-Feb-95 --- 2 ND ND ---ND ND ---ND ---ND ---ND ------2-Mar-95 --- 2 ND ND ---ND 6.0 ---7.0 ---ND ---ND ------
17-Nov-95 --- 2 ND ND ---ND 2.0 ---7.0 ---ND ---ND ------23-May-96 --- 2 ND ND ---ND ND ---ND ---ND ---ND ------14-Nov-96 --- 2 1.0 2.0 ---ND 2.0 ---2.0 ---ND ---ND ------
18-Jun-97 --- 2 5.0 14.0 ---3.0 7.0 --- 13.0 ---ND ---3.0 ------
2-Dec-97 --- 2 1.0 2.0 ---ND 2.0 ---5.0 ---ND ---1.0 ------27-May-98 --- 2 7.0 4.0 ---2.0 8.0 --- 10.0 ---ND ---3.0 ------16-Nov-98 --- 2 9.0 5.0 ---2.0 5.0 ---4.0 ---ND ---4.0 ------
10-Sep-99 --- 2 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 --- 2 ND ND ---ND ---ND ---ND ---ND ---ND ---10-May-00 --- 2 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 2 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 2 ---ND ---ND ---ND ---ND ---ND ---4.0 ---10-Jun-02 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND12-Jul-07 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/23/07)19-Dec-07 --- 1 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 --- 1.0 ---65.2 --- 0.14 J --- 0.10 J ---ND ---ND ---ND ND16-Dec-08 0.10 1.0 --- 0.21 J ---ND ---ND ---ND --- 0.18 J ---ND ND
8-Jul-09 0.10 1.0 ---4.9 ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 0.10 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND23-Jun-10 0.10 1.0 ---1.3 ---ND ---ND ---ND ---ND ---ND ND
GWPS = 4 µg/L (10/01/10)14-Dec-10 0.10 1.0 ---------ND --- {ND} --- {ND} --- {ND} ---ND ND {0.15} J
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND15-Feb-17 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
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Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksCadmium14-Sep-94 --- 1 ND ND ---ND 2.0 ---4.0 ---ND ---1.0 ------2-Dec-94 --- 1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
8-Feb-95 --- 1 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 --- 1 ND ND ---ND 1.0 ---1.0 ---ND ---ND ------17-Nov-95 --- 1 ND ND ---ND 1.0 ---ND ---ND ---ND ------23-May-96 --- 1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
14-Nov-96 --- 1 ND ND ---ND 1.0 ---ND ---ND ---ND ------
18-Jun-97 --- 1 ND ND ---ND 2.0 ---1.0 ---ND ---3.0 ------2-Dec-97 --- 1 ND ND ---ND ND ---2.0 ---ND ---ND ------27-May-98 --- 1 ND ND ---ND 1.0 ---ND ---ND ---1.0 ------
16-Nov-98 --- 1 2.0 ND ---ND 2.0 ---1.0 ---ND ---4.0 ------
10-Sep-99 --- 1 ND ND ---ND ---1.0 ---ND ---ND ---ND ---16-Nov-99 --- 1 2.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 1 ND ND ---ND ---ND ---ND ---ND ---1.0 ---
26-Oct-00 --- 1 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 1 ---ND ---2.0 ---2.0 ---ND ---ND ---2.0 ---
10-Jun-02 --- 1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---
13-Jun-02 --- 1 ---ND ---ND ---3.0 ---ND ---ND ---3.0 ---19-Nov-02 --- 1 ---4.0 ---3.0 ---2.0 ---ND ---1.0 ---ND ---
27-Jun-03 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 1 ---ND ---ND ---1.0 ---ND ---ND ---ND ND29-Dec-04 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 1 --- 0.90 J ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 1 ---ND ---ND ---ND ---ND ---ND ---ND NDNC 2L = 1.75 µg/L (10/23/07)19-Dec-07 --- 1 ---------ND ---ND ---ND ---ND ---ND ND8-Jul-08 --- 1.0 ---213#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND23-Jun-10 0.50 1.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 0.50 1.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 1.0 1.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND15-Feb-17 0.50 1.0 ------ND ND ---ND ---ND ---ND ---ND ND
Chromium 14-Sep-94 --- 10 74.0 74.0 --- 91.0 340 ---457 ---ND ---177 ------2-Dec-94 --- 10 93.0 ND --- 88.0 106 --- 18.0 ---ND --- 24.0 ------8-Feb-95 --- 10 ND 48.0 --- 56.0 87.0 --- 15.0 ---ND --- 19.0 ------
2-Mar-95 --- 10 ND 41.0 --- 66.0 313 --- 79.0 ---ND ---10 ------17-Nov-95 --- 10 130.0 11.0 --- 53.0 92.0 --- 79.0 ---ND ---ND ------23-May-96 --- 10 71.0 ND --- 34.0 51.0 --- 11.0 ---ND ---ND ------
14-Nov-96 --- 10 3.0 6.0 ---8.0 11.0 ---4.0 ---ND ---8.0 ------
18-Jun-97 --- 10 470 340 ---100 270 ---100 --- 10.0 --- 83.0 ------2-Dec-97 --- 10 17.0 8.0 --- 14.0 ND --- 18.0 ---5.0 --- 26.0 ------27-May-98 --- 10 470 150 --- 31.0 190 --- 69.0 ---6.0 --- 40.0 ------
16-Nov-98 --- 10 1000 220 ---130 190 --- 44.0 ---4.0 ---260 ------
10-Sep-99 --- 10 23.0 ND ---ND --- 40.0 ---ND ---ND --- 23.0 ---16-Nov-99 --- 10 28.0 ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 16.0 ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 10 ---ND ---ND --- 13.0 ---ND ---ND ---ND ---27-Oct-01 --- 10 ---ND --- 16.0 --- 56.0 ---10 ---ND ---ND ---
10-Jun-02 --- 10 ---ND ---ND --- 13.0 ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND ---ND --- 17.0 ---ND ---ND ---ND ---19-Nov-02 --- 10 --- 12.0 --- 12.0 ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 10 ---ND --- 13.0 ---ND ---ND --- 37.0 ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 10 ---ND ---ND --- 67.0 ---ND ---ND ---ND ND28-Dec-06 --- 10 ---2.8 J ---8.9 J ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 10 ---3.3 J ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 --- 10 ---------2.4 J ---2.5 J ---ND ---2.4 J ---ND ND8-Jul-08 --- 10.0 ---488#---8.0 J ---2.8 J ---ND ---1.8 J ---ND ND
6-Dec-08 0.40 10.0 ---1.5 J ---2.0 J ---3.2 J ---ND ---1.9 J ---ND ND
8-Jul-09 0.40 10.0 --- 22.1 ---3.3 J ---7.2 J ---ND --- 0.86 J ---ND ND15-Dec-09 0.40 10.0 --- 0.60 J ---4.6 J ---3.6 J ---ND --- 0.64 J ---ND NDNC 2L = 10 µg/L (2/5/10)23-Jun-10 0.40 10.0 ---12.0 ---4.1 J ---2.6 B --- 0.90 B ---1.3 B ---1.1 B 0.71 J
Resample >12-Aug-10 0.40 10.0 --- 87.8# J ------------------------------ND
14-Dec-10 0.40 10.0 ---------2.8 J ---9.1 J ---1.0 J ---1.2 J --- 0.43 J ND21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ND ND ---11.6 ---ND ---ND ---ND ND
Resample >25-Jan-12 5.0 10.0 ---------------6.1 J ------------------ND13-Jun-12 5.0 10.0 ------ND 5.1 J ---7.5 J ---ND ---ND ---ND ND11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND25-Feb-14 5.0 10.0 ------ND ND ---19.6 ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND 6.1 J ---6.6 J ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 3.3 J ---10.6 ---ND ---ND ---ND ND19-Aug-15 2.5 10.0 ------ND 5.9 J ---7.5 J ---ND ---ND ---ND ND18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 10.0 ------3.4 J 11.0 ---3.1 J ---2.7 J ---ND ---ND ND
15-Feb-17 2.5 10.0 ------ND 6.8 J ---2.9 J ---ND ---3.1 J ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksCobalt14-Sep-94 --- 10 160 160 ---ND 250 --- 2810 ---ND ---ND ------2-Dec-94 --- 10 47.0 ND --- 53.0 133 --- 31.0 ---ND ---ND ------
8-Feb-95 --- 10 ND 45.0 ---ND 158 --- 42.0 ---ND --- 23.0 ------
2-Mar-95 --- 10 ND 35.0 --- 22.0 258 --- 89.0 ---ND --- 24.0 ------17-Nov-95 --- 10 58.0 13.0 --- 31.0 86.0 --- 76.0 ---ND --- 15.0 ------23-May-96 --- 10 29.0 ND --- 19.0 88.0 --- 34.0 ---ND --- 16.0 ------
14-Nov-96 --- 10 12.0 93.0 --- 55.0 120 --- 90.0 ---2.0 --- 16.0 ------
18-Jun-97 --- 10 200 430 --- 52.0 520 ---550 ---4.0 --- 28.0 ------2-Dec-97 --- 10 7.0 34.0 --- 16.0 99.0 ---240 ---6.0 --- 14.0 ------27-May-98 --- 10 150 73.0 --- 13.0 180 ---350 ---4.0 --- 18.0 ------
16-Nov-98 --- 10 380 120 --- 54.0 100 ---440 --- 12.0 --- 45.0 ------
10-Sep-99 --- 10 11.0 ND ---ND --- 32.0 ---ND ---ND ---ND ---16-Nov-99 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 10.0 ND --- 15.0 --- 11.0 ---ND ---ND ---ND ---18-Apr-01 --- 10 --- 17.0 ---ND --- 21.0 ---ND ---ND ---ND ---27-Oct-01 --- 10 ---ND ---ND --- 28.0 ---ND ---ND ---ND ---
10-Jun-02 --- 10 ---ND --- 11.0 --- 15.0 ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND --- 11.0 --- 15.0 ---ND ---ND ---ND ---19-Nov-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 10 ---ND --- 12.0 ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND --- 12.0 ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND --- 11.0 ---ND ---ND ---ND ---ND ND28-Jun-06 --- 10 ---ND ---ND --- 21.3 ---ND ---ND ---ND ND
28-Dec-06 --- 10 ---2.1 J --- 16.4 ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 10 ---ND --- 11.2 ---ND ---ND ---ND ---ND NDGWPS = 70 µg/L (10/23/07)19-Dec-07 --- 10 --------- 17.0 ---4.6 B ---1.1 B ---1.4 B ---ND 1.6 J8-Jul-08 --- 10.0 ---436#--- 15.0 B ---4.2 B ---3.1 B ---5.0 B ---6.1 B 6.2 J
16-Dec-08 0.60 10.0 ---2.5 B --- 11.0 ---3.2 B ---1.4 B ---3.1 B ---2.5 B 2.4 J
8-Jul-09 0.60 10.0 ---8.1 J --- 10.6 ---ND ---ND ---ND ---ND ND15-Dec-09 0.60 10.0 ---ND ---8.8 J ---ND ---ND ---ND ---ND ND23-Jun-10 0.60 10.0 ---3.9 J --- 11.8 ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 0.60 10.0 ------------------------------------ND
GWPS = 1 µg/L (10/01/10)14-Dec-10 0.60 10.0 ---------10.9 ---3.7 B ---ND ---3.1 B --- 0.71 B 1.6 J21-Jun-11 5.0 10.0 ------ND 11.6 ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------5.0 J 9.3 J ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND 10.7 ---ND ---ND ---ND ---ND ND11-Dec-12 5.0 10.0 ------ND 10.1 ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 10.0 ------ND 13.0 ---ND ---ND ---ND ---5.1 J ND
6-Aug-13 5.0 10.0 ------ND 20.5 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND 13.9 ---11.4 ---ND ---ND ---ND ND13-Aug-14 5.0 10.0 ------ND 9.5 J ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND 8.0 J ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 11.8 ---ND ---ND ---ND ---ND ND18-Feb-16 2.5 10.0 ------ND 7.5 J ---ND ---ND ---ND ---ND ND11-Aug-16 2.5 10.0 ------ND 12.7 ---ND ---ND ---ND ---ND ND
15-Feb-17 2.5 10.0 ------ND 11.3 ---ND ---ND ---ND ---ND ND
Copper 14-Sep-94 --- 200 260 260 ---130 340 --- 4780 ---ND ---ND ------2-Dec-94 --- 200 ND ND ---ND 237 ---ND ---ND ---ND ------
8-Feb-95 --- 200 ND ND ---ND ND ---ND ---ND ---ND ------2-Mar-95 --- 200 ND ND ---ND 270 ---545 ---ND ---ND ------17-Nov-95 --- 200 ND ND ---ND ND ---456 ---ND ---ND ------
23-May-96 --- 200 ND ND ---ND ND ---ND ---200 ---ND ------
14-Nov-96 --- 200 10.0 31.0 --- 54.0 17.0 --- 60.0 --- 12.0 --- 15.0 ------18-Jun-97 --- 200 96.0 340 --- 97.0 310 ---660 ---170 --- 45.0 ------2-Dec-97 --- 200 10.0 13.0 --- 24.0 26 ---210 ---130 --- 17.0 ------
27-May-98 --- 200 84.0 100 --- 26.0 300 ---400 --- 91.0 --- 28.0 ------
16-Nov-98 --- 200 280 320 ---150 290 ---400 ---320 --- 80.0 ------10-Sep-99 --- 200 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 --- 200 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 200 ND ND ---ND ---ND ---ND ---ND ---ND ---26-Oct-00 --- 200 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ---19-Nov-02 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 200 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 10 ---1.7 B ---3.5 J ---1.7 B ---2.5 B --- 0.90 B ---ND 0.60 J
12-Jul-07 --- 10 ---ND ---ND ---2.0 J ---ND ---ND ---ND ND
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 --- 10 ---------4.6 B ---3.8 B --- 0.56 B ---1.9 B --- 0.58 B 10.5 B8-Jul-08 ---10.0 --- 828# ---9.3 J ---1.6 J ---ND ---ND --- 0.75 J ND
16-Dec-08 0.30 10.0 ---2.0 J ---2.1 J ---2.3 J ---ND ---6.9 J ---ND ND
8-Jul-09 0.30 10.0 --- 32.7 ---1.6 J ---3.3 J ---ND ---ND ---ND ND15-Dec-09 0.30 10.0 --- 0.79 J ---2.9 J ---2.7 J ---ND ---2.1 J ---ND ND23-Jun-10 0.30 10.0 --- 23.2 ---2.0 J ---1.1 J ---ND --- 0.86 J ---ND ND
Resample >12-Aug-10 0.30 10.0 ------------------------------------ND
14-Dec-10 0.30 10.0 ---------1.8 B ---8.1 J --- 0.39 B ---5.9 J ---ND 0.49 J21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 10.0 ------ 15.5 ND --- 10.0 ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---5.6 J ---ND ---ND ---ND ND11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND 6.6 J ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND --- 14.7 ---ND ---6.4 J ---ND ND13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 2.5 10.0 ------ND ND ---7.6 J ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 5.0 J ---6.8 J ---ND ---ND ---ND ND18-Feb-16 2.5 10.0 ------ND ND ---3.6 J ---ND ---ND ---ND ND11-Aug-16 2.5 10.0 ------ND 7.8 J ---ND ---ND ---ND ---ND ND
15-Feb-17 2.5 10.0 ------ND 6.3 J ---ND ---ND ---ND ---ND ND
Iron 23-Jun-10 14.0 300 ---11800 ---4150 ---1040 ---102 J ---413 ---776 ND
NC 2L = 300 µg/L (2/5/10) Resample > 12-Aug-10 140 3000 ---123,000 ------------------------------ND
14-Dec-10 14 300 ---------3210 ---3880 ---141 J ---877 ---1100 ND21-Jun-11 50.0 300 ------2190 6030 ---667 ---114 J ---981 ---1020 ND6-Dec-11 50.0 300 ------8610 2680 ---5420 --- 86.1 J ---287 J ---1040 ND
13-Jun-12 50.0 300 ------1770 5610 ---3280 --- 63.4 J ---698 ---1680 ND
11-Dec-12 50.0 300 ------1680 4020 ---1260 ---ND ---545 ---981 ND29-Apr-13 50.0 300 ------414 3500 ---1130 ---112 J ---635 ---1750 ND6-Aug-13 50.0 300 ------397 8970 ---307 ---ND ---378 ---2130 ND
25-Feb-14 50.0 300 ------1040 7060 ---9750 ---102 J ---2030 ---1710 ND
13-Aug-14 50.0 300 ------209 J 5380 ---3030 ---107 J ---904 ---2140 ND12-Mar-15 25.0 300 ------269 J 3680 ---6040 --- 40.8 J ---262 J ---2650 ND
19-Aug-15 25.0 300 ------156 J 7250 ---3780 --- 34.9 J --- 58.0 J ---1460 ND
18-Feb-16 25.0 300 ------243 J 792 ---270 J --- 43.0 J --- 86.3 J ---1500 ND11-Aug-16 25.0 300 ------292 J 10400 ---839 --- 104.0 J ---ND ---2090 ND15-Feb-17 25.0 300 ------633 6250 ---1400 --- 104.0 J --- 30.4 J ---944 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksLead14-Sep-94 --- 10 31.0 31.0 ---230 23.0 ---355 ---ND ---190 ------2-Dec-94 --- 10 17.0 ND --- 26.0 30.0 --- 11.0 ---ND --- 31.0 ------
8-Feb-95 --- 10 ND 13.0 --- 23.0 10.0 --- 19.0 ---ND --- 15.0 ------
2-Mar-95 --- 10 ND 11.0 --- 14.0 27.0 --- 47.0 ---ND ---ND ------17-Nov-95 --- 10 ND ND ---ND 13.0 --- 51.0 ---ND ---ND ------23-May-96 --- 10 ND ND --- 10.0 ND ---ND ---ND ---ND ------
14-Nov-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 --- 10 33.0 69.0 --- 21.0 40.0 --- 78.0 ---8 --- 70.0 ------2-Dec-97 --- 10 8.0 8.0 --- 20.0 14.0 --- 21.0 ---11 --- 24.0 ------27-May-98 --- 10 27.0 18.0 --- 23.0 31.0 --- 32.0 ---ND --- 32.0 ------
16-Nov-98 --- 10 43.0 36.0 --- 33.0 34.0 --- 32.0 ---ND ---110 ------
10-Sep-99 --- 10 ND 18.0 ---ND --- 14.0 ---ND ---ND ---ND ---16-Nov-99 --- 10 11.0 ND ---ND ---ND ---ND --- 11.0 ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 10 ---ND --- 28.0 --- 15.0 ---ND --- 18.0 --- 29.0 ---
10-Jun-02 --- 10 ---ND --- 13.0 ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND --- 13.0 ---ND ---ND ---ND ---ND ---19-Nov-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 10 ---ND ---ND ---ND ---ND --- 10.0 ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 10 ---ND ---2.0 J ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND NDNC 2L = 15 µg/L (10/23/07)19-Dec-07 --- 10 ---------ND ---ND ---ND ---ND ---ND ND8-Jul-08 --- 10.0 ---78#---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 4.0 10.0 ---22.5 ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 4.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND23-Jun-10 4.0 10.0 ---6.7 J ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 4.0 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND 2.9 J ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 2.5 10.0 ------ND 2.7 J ---ND ---ND ---ND ---ND ND15-Feb-17 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Mercury 17-Nov-95 --- 0.5 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-97 --- 0.5 ND ND ---ND ND ---ND ---ND ---ND ------23-Mar-98 --- 0.5 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 --- 0.5 ND ND ---ND ND ---ND ---ND ---ND ------16-Nov-98 --- 0.5 ND ND ---ND 1.0 ---ND ---ND ---ND ------10-Sep-99 --- 0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
16-Nov-99 --- 0.5 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 0.5 ---------ND ---ND ---ND ---ND ---ND ---26-Oct-00 --- 0.5 ---------ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 0.5 ---------ND ---ND ---ND ---ND ---ND ---
27-Oct-01 --- --- ---------------------------------------
10-Jun-02 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ---13-Jun-02 --- 0.5 ---------ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- --- ---------------------------------------
27-Jun-03 --- 1.5 ---ND ---ND ---ND ---ND --- 0.78 ---ND ---30-Dec-03 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-04 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-05 --- 0.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 2 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 0.2 ---ND ---ND ---ND ---ND ---ND ---ND ND12-Jul-07 --- 0.2 ---ND ---ND ---ND ---ND ---ND ---ND NDNC 2L = 1.05 µg/L (10/23/07)19-Dec-07 --- 0.2 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 --- 0.20 --- 0.34# ---ND ---ND ---ND ---ND ---ND ND
16-Dec-08 0.090 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND8-Jul-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 0.070 0.20 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 1 µg/L (2/5/10)23-Jun-10 0.070 0.20 ---ND ---ND ---ND --- 0.094 J ---ND ---ND ND
14-Dec-10 0.070 0.20 ---------ND ---ND ---ND ---ND ---ND ND21-Jun-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND11-Dec-12 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND13-Aug-14 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND18-Feb-16 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 0.10 0.20 ------ND 0.11 J ---ND ---ND ---ND ---ND ND
15-Feb-17 0.10 0.20 ------ND ND ---ND ---ND ---ND ---ND ND
Manganese 23-Jun-10 0.30 50.0 ---88.3 ---217 --- 44.0 B ---513 ---127 ---1470 9.0 J
NC 2L = 50 µg/L (2/5/10) Resample> 12-Aug-10 3.00 500 ---972 ------------------------------0.35 J
14-Dec-10 0.30 50.0 ---------208 ---139 ---730 ---194 ---1260 1.1 J21-Jun-11 5.0 50.0 ------ 38.2 J 245 --- 36.9 J ---833 ---130 ---1400 ND6-Dec-11 5.0 50.0 ------198 216 ---170 ---808 ---187 ---1350 ND
13-Jun-12 5.0 50.0 ------ 41.7 J 226 ---95.8 ---760 ---125 ---1360 ND
11-Dec-12 5.0 50.0 ------ 33.8 J 230 --- 28.9 J ---770 ---279 ---1340 ND29-Apr-13 5.0 50.0 ------ 14.2 J 193 --- 47.3 J ---724 ---139 ---1220 ND
6-Aug-13 5.0 50.0 ------ 10.3 J 273 --- 38.5 J ---749 ---135 ---1220 ND
25-Feb-14 5.0 50.0 ------ 29.8 J 222 ---340 ---897 ---154 ---862 ND13-Aug-14 5.0 50.0 ------5.8 J 209 ---108 ---1230 ---125 ---1450 ND12-Mar-15 2.5 50.0 ------6.0 J 210 ---200 ---676 ---104 ---1370 ND
19-Aug-15 2.5 50.0 ------4.3 J 288 ---199 ---802 ---103 ---1490 ND
18-Feb-16 2.5 50.0 ------5.4 J 201 ---72.7 ---981 ---82.4 ---1620 ND11-Aug-16 2.5 50.0 ------5.9 J 336 ---122 ---1550 ---100.0 ---1770 ND15-Feb-17 2.5 50.0 ------ 15.5 J 234 ---246 ---1390 ---91.4 ---2210 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksNickel14-Sep-94 --- 50 180 18.0 ---ND 250 ---680 ---ND ---ND ------2-Dec-94 --- 50 118 ND ---119 164 ---ND ---ND ---ND ------
8-Feb-95 --- 50 ND ND ---ND 84.0 ---ND ---ND ---ND ------
2-Mar-95 --- 50 ND ND ---ND 204 --- 75.0 ---ND ---ND ------17-Nov-95 --- 50 71.0 ND ---ND ND ---ND ---ND ---ND ------23-May-96 --- 50 69.0 ND ---ND 51 ---ND ---ND ---ND ------
14-Nov-96 --- 50 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 --- 50 330 280 --- 65.0 200 ---ND ---ND ---ND ------2-Dec-97 --- 50 ND ND ---ND ND ---ND ---ND ---ND ------27-May-98 --- 50 310 88.0 ---ND 170 ---61 ---ND ---ND ------
16-Nov-98 --- 50 840 270 ---ND ND ---ND ---ND ---150 ------
10-Sep-99 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 50 ---ND ---ND ---59 ---ND ---ND ---ND ---
10-Jun-02 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---19-Nov-02 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 50 ---4.7 J ---7.0 J ---7.2 J ---2.4 J ---ND ---ND ND
12-Jul-07 --- 50 ---4.6 J ---3.2 J ---2.5 J ---ND ---ND ---ND NDNC 2L = 100 µg/L (10/23/07)19-Dec-07 --- 50 ---------3.2 J ---5.0 ---ND ---2.3 J ---ND ND8-Jul-08 --- 50.0 ---122 J ---5.3 J ---2.3 J ---ND ---1.7 J ---ND ND
16-Dec-08 1.7 50.0 ---ND ---2.3 B ---2.5 B ---ND ---2.7 B ---ND 2.4 J
8-Jul-09 1.7 50.0 --- 38.6 J ---3.2 J ---6.0 J ---ND ---1.8 J ---ND ND15-Dec-09 1.7 50.0 ---ND ---3.6 B ---4.4 B ---2.1 B ---2.6 B ---2.0 B 3.0 J23-Jun-10 1.7 50.0 ---10 J ---2.3 J ---ND ---ND ---ND ---ND ND
14-Dec-10 1.7 50.0 ---------1.8 B ---2.6 B ---ND ---ND ---ND 2.7 J
21-Jun-11 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 50.0 ------ND ND ---6.4 J ---ND ---ND ---ND ND
13-Jun-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 50.0 ------ND ND --- 11.3 J ---ND ---ND ---ND ND
13-Aug-14 5.0 50.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 2.5 50.0 ------ND ND --- 11.7 J ---ND ---ND ---ND ND
19-Aug-15 2.5 50.0 ------ND 3.7 J ---8.9 J ---ND ---ND ---ND ND
18-Feb-16 2.5 50.0 ------ND ND ---3.2 J ---ND ---ND ---ND ND11-Aug-16 2.5 50.0 ------ND 6.4 J ---6.7 J ---ND ---ND --- 22.8 J ND15-Feb-17 2.5 50.0 ------ND 4.9 J ---8.8 J ---ND ---ND ---ND ND
Selenium 14-Sep-94 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-94 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------8-Feb-95 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------17-Nov-95 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------23-May-96 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-97 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------27-May-98 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 --- 20 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 --- 20 ND 24.0 ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 20 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 20 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 20 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 20 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND12-Jul-07 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 --- 10 ---------ND ---ND ---ND ---ND ---ND ND
8-Jul-08 --- 10.0 --- ND# ---ND ---ND ---ND ---ND ---ND ND16-Dec-08 3.8 10.0 ---4.2 B ---ND ---ND ---ND ---ND ---ND 4.9 J
8-Jul-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND NDNC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND14-Dec-10 3.8 10.0 ---------ND ---ND ---ND ---ND ---ND ND
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND13-Jun-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND25-Feb-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
12-Mar-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND19-Aug-15 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 5.0 10.0 ------ND ND ---ND ---ND ---ND ---6.0 J ND15-Feb-17 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksSilver14-Sep-94 --- 10 ND ND ---ND ND --- 50.0 ---ND ---ND ------2-Dec-94 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------17-Nov-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------23-May-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-97 --- 10 ND ND ---ND ND ---ND ---ND ---4.0 ------27-May-98 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
10-Sep-99 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
19-Nov-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
NC 2L = 17.5 µg/L (10/23/07)19-Dec-07 --- 10 ---------ND ---ND --- 0.26 J ---ND ---ND ND8-Jul-08 --- 10.0 --- 14.6# J --- 0.27 J --- 0.41 J --- 0.83 J --- 0.39 J --- 0.56 J ND16-Dec-08 0.10 10.0 ---ND ---ND --- 0.25 J --- 0.53 J --- 0.40 J --- 0.46 J ND
8-Jul-09 0.10 10.0 --- 0.16 J ---ND ---ND --- 0.17 J ---ND ---ND ND
15-Dec-09 0.10 10.0 ---ND ---ND --- 0.32 J --- 0.64 J --- 0.53 J --- 0.53 J NDNC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ---ND ---ND ---ND --- 0.13 J --- 0.13 J ---ND ND
14-Dec-10 0.10 10.0 ---------ND --- {0.24} B --- {0.58} B --- {0.34} B --- 0.17 B
{0.25 J}
0.19 J
21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND13-Aug-14 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND15-Feb-17 2.5 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
Thallium 14-Sep-94 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------2-Dec-94 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
8-Feb-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
2-Mar-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------17-Nov-95 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------23-May-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
14-Nov-96 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
18-Jun-97 --- 10 ND ND ---ND ND ---5.0 ---ND ---ND ------2-Dec-97 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
27-May-98 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------
16-Nov-98 --- 10 ND ND ---ND ND ---ND ---ND ---ND ------10-Sep-99 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 10 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Oct-01 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---19-Nov-02 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 0.01 ---ND ---ND ---ND ---ND ---ND ---ND ---
30-Dec-03 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 10 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Dec-06 --- 6 ---ND ---ND ---ND ---ND ---ND ---ND ND
12-Jul-07 --- 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
GWPS = 0.28 µg/L (10/23/07)19-Dec-07 --- 5.5 ---------ND ---ND ---ND ---ND ---ND ND8-Jul-08 --- 5.5 ---31.7#---4.5 J ---ND ---ND ---ND ---ND ND16-Dec-08 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
8-Jul-09 3.0 5.5 ---ND ---ND ---ND ---ND ---ND ---ND ND
15-Dec-09 3.0 5.5 ---ND ---ND ---ND ---ND ---3.8 J ---ND ND23-Jun-10 3.0 5.5 ---6.6 ---ND ---ND ---ND ---ND ---ND ND
Resample >12-Aug-10 30.0 55.0 --- ND# ------------------------------ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 ---------ND ---ND ---8.1 ---ND ---ND ND21-Jun-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND29-Apr-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND13-Aug-14 5.4 5.5 ------ND ND ---ND ---ND ---ND ---ND ND12-Mar-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
19-Aug-15 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
18-Feb-16 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND11-Aug-16 5.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND15-Feb-17 0.0 5.5 ------ND ND ---ND ---ND ---ND ---ND ND
Tin 8-Jul-08 --- 100 --- 232# J ---1.9 J ---3.0 J ---3.0 J ---3.6 J ---3.6 J ND16-Dec-08 1.8 100 ------------------------------------ND
8-Jul-09 1.8 100 ---7.4 J ---ND ---ND ---1.8 J ---ND ---ND ND
15-Dec-09 --- --- ---------------------------------------GWPS = 2100 µg/L (2/5/10)23-Jun-10 1.8 100 ---2.9 J ---ND ---ND ---1.9 J ---2.5 J ---3.3 J NDGWPS = 2000 µg/L (10/01/10)14-Dec-10 --- --- ---------------------------------------
21-Jun-11 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
6-Dec-11 5.0 100 ---------------------------------------13-Jun-12 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 --- --- ---------------------------------------
29-Apr-13 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 --- --- ---------------------------------------25-Feb-14 5.0 100 ------ND ND ---ND ---ND ---ND ---ND ND
13-Aug-14 --- --- ---------------------------------------
12-Mar-15 2.5 100 ------ND ------------------ND ------ND18-Feb-16 2.5 100 ------ND ------------------ND ------ND
15-Feb-17 2.5 100 ------ND ------------------ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksVanadium14-Sep-94 --- 40 580 580 ---390 540 --- 12800 ---ND ---340 ------2-Dec-94 --- 40 107 ND ---233 316 ---201 ---ND ---ND ------
8-Feb-95 --- 40 ND 81.0 ---132 162 ---190 ---ND ---ND ------
2-Mar-95 --- 40 ND 62.0 ---173 468 --- 1260 ---ND ---ND ------17-Nov-95 --- 40 100 ND --- 84.0 120 ---984 ---ND ---ND ------23-May-96 --- 40 92.0 ND ---103 139 ---196 ---ND ---ND ------
14-Nov-96 --- 40 16.0 10.0 ---140 280 ---320 --- 10.0 --- 22.0 ------
18-Jun-97 --- 40 470 1600 ---310 600 --- 1700 --- 57.0 --- 82.0 ------2-Dec-97 --- 40 32.0 15.0 --- 52.0 120 ---970 --- 22.0 --- 27.0 ------27-May-98 --- 40 330 120 --- 71.0 460 --- 1000 --- 34.0 --- 41.0 ------
16-Nov-98 --- 40 900 280 ---340 470 ---730 --- 49.0 --- 97.0 ------
10-Sep-99 --- 40 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 40 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 40 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 40 ND ND ---ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Oct-01 --- 40 ---ND --- 67.0 --- 53.0 ---ND --- 63.0 ---ND ---
10-Jun-02 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ---
13-Jun-02 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ---19-Nov-02 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 40 ---ND ---ND ---ND ---ND --- 94.0 ---ND ---
30-Dec-03 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ND30-Jun-04 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Jun-05 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 40 ---ND ---ND ---ND ---ND ---ND ---ND ND28-Jun-06 --- 40 ---ND ---ND --- 71.1 ---ND ---ND ---ND ND
28-Dec-06 --- 25 ---2.2 J ---28.4 ---ND ---ND ---1.8 J ---ND ND
12-Jul-07 --- 25 ---3.7 J ---3.4 J ---2.2 J ---ND ---ND ---ND NDGWPS = 3.5 µg/L (10/23/07)19-Dec-07 --- 25 ---------7.6 ---3.2 J ---1.1 B --- 0.82 B --- 0.93 B 0.51 JResample > 14-Feb-08 --- 25 ---------7.2 ------------------------0.24 J
Filtered > 14-Feb-08 --- 25 ---------3.2 J ------------------------ND
8-Jul-08 --- 25.0 ---772#--- 21.9 J ---2.2 J --- 0.94 B --- 0.78 B ---2.3 J 0.20 J16-Dec-08 0.20 25.0 ---3.4 J ---4.9 J ---3.4 J --- 0.84 B ---6.1 J --- 0.47 B 0.76 J8-Jul-09 0.20 25.0 ---39.6 --- 10.6 J ---8.3 J ---1.7 B ---1.9 B ---1.4 B 1.3 J
15-Dec-09 0.20 25.0 ---1.2 B --- 12.1 J ---3.8 J ---1.3 B ---2.3 B ---ND 0.53 J
23-Jun-10 0.20 25.0 --- 18.7 J --- 10.7 J ---2.0 J --- 0.51 J ---1.2 J --- 0.54 J NDResample >12-Aug-10 0.20 25.0 ------------------------------------0.33 J
GWPS = 0.3 µg/L (10/01/10)14-Dec-10 0.20 25.0 ---------7.3 J --- {8.0} J --- {1.2} B --- {4.0} J ---ND {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 ------5.9 J 14.6 J ---ND ---ND ---ND ---ND ND6-Dec-11 5.0 25.0 ------ 19.8 J 5.3 J ---10 J ---ND ---ND ---ND ND13-Jun-12 5.0 25.0 ------5.2 J 13.0 J ---6.5 J ---ND ---ND ---ND ND
11-Dec-12 5.0 25.0 ------ND 7.4 J ---ND ---ND ---ND ---ND ND
29-Apr-13 5.0 25.0 ------ND 8.4 J ---ND ---ND ---ND ---ND ND6-Aug-13 5.0 25.0 ------ND 27.6 ---ND ---ND ---ND ---ND ND
25-Feb-14 5.0 25.0 ------ND 18.6 J --- 19.0 J ---ND ---7.0 J ---ND ND
13-Aug-14 5.0 25.0 ------ND 15.0 J ---7.2 J ---ND ---ND ---ND ND12-Mar-15 2.5 25.0 ------ND 9.5 J --- 14.8 J ---ND ---3.3 J ---ND ND19-Aug-15 2.5 25.0 ------ND 19.2 J ---8.3 J ---ND ---ND ---ND ND
18-Feb-16 2.5 25.0 ------ND ND ---ND ---ND ---ND ---ND ND
11-Aug-16 2.5 25.0 ------ND 25.2 ---ND ---ND ---ND ---ND ND15-Feb-17 2.5 25.0 ------ND 13.9 J ---ND ---ND ---ND ---ND ND
Zinc 14-Sep-94 --- 50 680 680 ---400 910 --- 17,400 ---ND ---640 ------2-Dec-94 --- 50 299 ND ---380 553 ---279 ---ND --- 98.0 ------8-Feb-95 --- 50 ND 185 ---236 255 ---320 ---156 ---108 ------
2-Mar-95 --- 50 ND 114 ---102 601 --- 1,530 ---191 ---ND ------
17-Nov-95 --- 50 309 67.0 ---154 199 --- 1,300 --- 59.0 ---ND ------23-May-96 --- 50 237 94.0 ---116 237 ---314 ---149 ---ND ------14-Nov-96 --- 50 240 180 ---140 120 ---140 --- 15.0 --- 48.0 ------
18-Jun-97 --- 50 930 800 ---250 650 --- 1,800 ---160 ---190 ------
2-Dec-97 --- 50 140 150 ---110 120 ---510 ---150 ---130 ------27-May-98 --- 50 1,000 280 --- 90.0 560 --- 1,300 ---100 ---110 ------
16-Nov-98 --- 50 4,300 2,500 --- 3,600 5,600 --- 7,000 ---230 --- 3,900 ------
10-Sep-99 --- 50 153 ND ---ND --- 96.0 ---ND ---ND ---ND ---16-Nov-99 --- 50 140 119 ---ND ---ND ---ND ---ND ---ND ---10-May-00 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---
26-Oct-00 --- 50 ND ND ---ND ---ND ---ND ---ND ---ND ---
18-Apr-01 --- 50 ---ND ---ND --- 64.0 ---ND ---ND ---ND ---27-Oct-01 --- 50 --- 23.0 --- 55.0 --- 136.0 ---ND --- 32.0 ---ND ---
10-Jun-02 --- 50 ---ND ---ND --- 72.0 ---ND ---ND ---370 ---
13-Jun-02 --- 50 ---ND ---ND --- 72.0 ---ND ---ND ---370 ---19-Nov-02 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ---27-Jun-03 --- 50 ---ND ---ND ---ND ---ND --- 52.0 ---ND ---
30-Dec-03 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
30-Jun-04 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Dec-04 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND29-Jun-05 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
29-Dec-05 --- 50 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Jun-06 --- 50 ---ND ---ND ---126 ---ND ---ND ---ND ND28-Dec-06 --- 10 ---7.7 J --- 14.0 ---7.8 J ---ND ---ND ---1.5 J ND
12-Jul-07 --- 10 --- 48.1 ---3.6 J ---6.5 J ---ND ---ND ---ND ND
NC 2L = 1,050 µg/L (10/23/07)19-Dec-07 --- 10 ---------0.4 B ---ND ---4.5 B ---ND ---ND 87.98-Jul-08 --- 10.0 ---4,540#--- 12.6 ---ND ---ND ---ND ---ND 1.2 J16-Dec-08 0.40 10.0 ---9.6 J --- 0.45 J ---3.8 J ---ND --- 12.3 ---ND ND
8-Jul-09 0.40 10.0 ---169 --- 0.67 J ---7.0 J ---ND ---ND ---ND 1.6 J
15-Dec-09 0.40 10.0 ---6.6 B ---5.5 B ---6.9 B ---ND ---1.9 B ---ND 7.7 JNC 2L = 1,000 µg/L (2/5/10)23-Jun-10 0.40 10.0 --- 55.2 ---2.2 J ---1.0 J ---ND ---ND ---ND ND
14-Dec-10 0.40 10.0 --------- 16.3 B --- 12.6 B ---ND ---ND ---2.6 B 6.7 J
21-Jun-11 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 10.0 10.0 ------ 21.8 B ND --- 21.0 B ---ND ---ND ---ND 12.413-Jun-12 10.0 10.0 ------ND ND --- 14.0 ---ND ---ND ---ND ND
11-Dec-12 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
29-Apr-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Aug-13 10.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 10.0 10.0 ------ND ND --- 31.9 ---ND ---ND ---ND ND
13-Aug-14 10.0 10.0 ------ND ND --- 24.1 ---ND ---ND ---ND ND12-Mar-15 5.0 10.0 ------9.2 B 11.5 B --- 24.3 B ---6.8 B ---7.5 B ---7.1 B 6.1 J19-Aug-15 5.0 10.0 ------ND 7.2 B --- 16.3 B ---ND ---ND ---ND 11.5
18-Feb-16 5.0 10.0 ------ 14.8 ND ---ND ---6.6 J ---ND ---ND ND
11-Aug-16 5.0 10.0 ------ND 18.2 ---8.6 J ---ND ---ND ---ND ND15-Feb-17 5.0 10.0 ------ND 14.7 ---8.0 J ---ND ---ND ---ND ND
Alkalinity, Total as CaCO3 23-Jun-10 5,000 5,000 --- 7,290 --- 20,400 --- 82,100 --- 253,000 --- 135,000 ------NDNC 2L = NE µg/L (2/5/10)14-Dec-10 5,000 5,000 --------- 17,600 --- 99,800 --- 291,000 --- 169,000 --- 178,000 ND21-Jun-11 5,000 5,000 ------ 100,000 20,800 --- 77,000 --- 269,000 --- 194,000 --- 156,000 ND
6-Dec-11 5,000 5,000 ------ 98,700 10,500 --- 81,900 --- 274,000 --- 164,000 --- 151,000 ND
13-Jun-12 1,000 1,000 ------ 101,000 13,700 --- 87,500 --- 271,000 --- 152,000 --- 149,000 ND11-Dec-12 1,000 5,000 ------ 100,000 16,500 --- 98,300 --- 284,000 --- 147,000 --- 152,000 ND29-Apr-13 1,000 5,000 ------ 99,300 13,800 --- 97,300 --- 293,000 --- 156,000 --- 122,000 ND
6-Aug-13 1,000 5,000 ------ 102,000 14,300 --- 99,100 --- 148,000 --- 86,800 --- 159,000 ND
25-Feb-14 1,000 5,000 ------ 107,000 15,800 --- 123,000 --- 298,000 --- 178,000 --- 153,000 ND13-Aug-14 1000 5000 ------ 103000 14300 --- 93800 --- 301000 --- 187000 --- 164000 ND
12-Mar-15 1000 5000 ------ 99700 14700 --- 88300 --- 306000 --- 151000 --- 164000 ND
19-Aug-15 1000 5000 ------ 102000 19600 --- 88200 --- 294000 --- 180000 --- 164000 ND18-Feb-16 1000 5000 ------ 108000 4350 J --- 89800 --- 308000 --- 141000 --- 168000 ND11-Aug-16 1000 5000 ------ 108000 24400 --- 91800 --- 304000 --- 176000 --- 173000 ND
15-Feb-17 1000 5000 ------ 115000 16000 --- 92800 --- 300000 --- 175000 --- 183000 ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 9
Joyce Engineering
APPENDIX C:
HISTORICAL DETECTED INORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R BlanksChloride23-Jun-10 5,000 5,000 --- 7,950 ---ND --- 37,400 --- 40,000 --- 39,700 --- 97,900 NDNC 2L = 250000 µg/L (2/5/10)14-Dec-10 5,000 5,000 --------- 5,100 --- 38,400 --- 44,500 --- 39,600 --- 108,000 ND
21-Jun-11 5,000 5,000 ------ 8,600 ND --- 35,800 --- 45,300 --- 41,400 --- 106,000 ND
6-Dec-11 5,000 5,000 ------ 9,340 ND --- 28,600 --- 49,200 --- 39,200 --- 110,000 ND13-Jun-12 1,000 1,000 ------ 9,410 4,540 --- 29,400 --- 49,300 --- 46,400 --- 109,000 ND11-Dec-12 1,000 1,000 ------ 8,570 5,220 --- 30,800 --- 50,600 --- 46,600 --- 107,000 ND
29-Apr-13 1,000 1,000 ------ 9,550 4,120 --- 30,000 --- 49,800 --- 22,300 --- 122,000 ND
6-Aug-13 1,000 1,000 ------ 7,590 5,180 --- 25,700 --- 50,100 --- 48,700 --- 107,000 ND25-Feb-14 1,000 1,000 ------ 9,140 5,510 --- 33,200 --- 60,300 --- 57,400 --- 120,000 ND13-Aug-14 500 1,000 ------ 8,030 4,070 --- 21,300 --- 97,600 --- 43,400 --- 106,000 ND
12-Mar-15 500 1,000 ------ 8,840 4,350 --- 20,700 --- 51,700 --- 42,600 --- 121,000 ND
19-Aug-15 500 1,000 ------ 9,440 5,160 --- 23,200 --- 51,500 --- 48,500 --- 111,000 ND18-Feb-16 500 1,000 ------ 17,200 4,600 --- 20,600 --- 69,500 --- 49,700 --- 153,000 ND
11-Aug-16 500 1,000 ------ 9,410 4,430 --- 23,200 --- 57,300 --- 51,300 --- 147,000 ND
15-Feb-17 2,500 5,000 ------ 10,900 4,970 --- 29,300 --- 59,100 --- 49,200 M1,R --- 142,000 ND
Total Cyanide 8-Jul-08 --- 10.0 ---------ND ---ND ---6.2 J ---ND ---ND ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 --- --- ---------------------------------------
8-Jul-09 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 --- --- ---ND ---------------------------------
23-Jun-10 5.0 10.0 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 --- --- ---------------------------------------21-Jun-11 5.0 10.0 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 --- --- ---------------------------------------
13-Jun-12 5.0 10 ---------5.8 J ---6.2 J ---5.2 J ---------------
11-Dec-12 --- --- ---------------------------------------29-Apr-13 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 --- --- ---------------------------------------
25-Feb-14 5.0 10 ------ND ND ---ND ---ND ---ND ---ND ND13-Aug-14 --- --- ------------------------------------ND
Sulfide 17-Nov-95 --- 1,000 ND ND ---ND ND ---ND ---ND ---ND ------
2-Dec-97 --- 1,000 ND ND ---ND ND ---ND ---ND ---ND ------23-Mar-98 --- 1,000 ND ND --- 1,000 ND ---ND --- 1,200 --- 1400 ------27-May-98 --- 1,000 ND ND --- 1,000 ND ---ND ---ND ---ND ------
16-Nov-98 --- 1,000 12,000 1,200 --- 13,000 2,200 ---ND --- 13,000 ---ND ------
10-Sep-99 --- 1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---16-Nov-99 --- 1,000 ND ND ---ND ---ND ---ND ---ND ---ND ---
10-May-00 --- 1,000 --------- 17,000 --- 5,000 --- 47,000 --- 33,000 --- 36,000 ---
26-Oct-00 --- 1,000 ---------ND ---ND ---ND ---ND ---ND ---18-Apr-01 --- 1,000 ---------ND ---ND ---ND ---ND ---ND ---13-Jun-02 --- 1,000 ---------ND ---ND ---ND ---ND ---ND ---
27-Jun-03 --- 1,000 ---------------------------------ND ---
30-Dec-03 --- 1,000 ---------------------------------------30-Jun-04 --- 1,000 ---ND ---ND ---7 ---ND ---ND ---ND ---
29-Dec-04 --- 1,000 ---------------------------------------
29-Jun-05 --- 1,000 ---ND ---ND ---ND ---ND ---ND --- 1,200 ND29-Dec-05 --- 1,000 --- 1,200 B ---ND ---ND --- 1,700 B ---ND ---ND 1,20028-Jun-06 --- 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
28-Dec-06 --- 1,000 ---700 J ---ND ---500 J ---ND ---ND ---ND ND
12-Jul-07 --- 1,000 ---ND ---ND ---ND ---ND ---ND ---ND NDNC 2L = NE µg/L (10/23/07)19-Dec-07 --- 1,000 ---------ND ---ND ---ND ---ND ---ND ND8-Jul-08 --- 1,000 ---------ND ---ND ---ND ---ND ---ND ND
16-Dec-08 100 1,000 ---259 J ---ND ---150 J ---ND ---141 J ---ND ND8-Jul-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND15-Dec-09 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
23-Jun-10 100 1,000 ---ND ---ND ---ND ---ND ---ND ---ND ND
14-Dec-10 100 1,000 ---------ND ---ND ---ND ---ND ---ND ND21-Jun-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND6-Dec-11 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
13-Jun-12 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
11-Dec-12 100 1,000 ------ND ND ---ND ---ND ---117 J ---ND ND29-Apr-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
6-Aug-13 100 1,000 ------ND ND ---ND ---ND ---ND ---ND ND
25-Feb-14 100 1,000 ------ND ND ---141 J ---189 J ---ND ---ND ND13-Aug-14 50 1,000 ------ND ------------------ND ------ND12-Mar-15 100 1,000 ------ND ------------------ND ------ND
19-Aug-15 100 1,000 ------ND ------------------ND ------ND
18-Feb-16 100 1,000 ------ND ------------------ND ------ND11-Aug-16 100 1,000 ------ND ------------------ND ------ND
15-Feb-17 100 1,000 ------ND ------------------ND ------ND
Sulfate 23-Jun-10 --- 5,000 --- 5,160 --- 14,800 --- 7,180 --- 9,140 ---ND ------NDNC 2L = 250000 µg/L (2/5/10)14-Dec-10 --- 5,000 --------- 14,500 --- 9,210 --- 9,700 ---ND ---ND ND
21-Jun-11 --- 5,000 ------ 24,400 11,400 --- 7,490 --- 7,740 ---ND ---ND ND
6-Dec-11 5,000 5,000 ------ 39,800 13,800 --- 8,000 --- 7,730 ---ND ---ND ND13-Jun-12 2,000 250,000 ------ 25,400 J 13,700 J --- 8,140 J --- 8,400 J --- 2,790 J --- 3,040 J ND11-Dec-12 2,000 250,000 ------ 28,000 J 14,800 J --- 9,120 J --- 10,100 J --- 4,420 J --- 2,900 J ND
29-Apr-13 2,000 250,000 ------ 26,100 J 12,300 J --- 9,150 J --- 17,100 J --- 2,730 J --- 3,200 J ND6-Aug-13 2,000 250,000 ------ 25,300 J 7,370 J --- 7,830 J --- 11,700 J --- 2,760 J --- 3,320 J ND25-Feb-14 2,000 250,000 ------ 28,900 J 11,200 J --- 8,130 J --- 9,550 J --- 2,590 J --- 4,620 J ND
13-Aug-14 1,000 250,000 ------ 31,900 J 9,370 J --- 7,910 J --- 11,600 J --- 2,450 J --- 2,780 J ND
12-Mar-15 1,000 250,000 ------ 32,600 J 12,100 J --- 8,040 J --- 8,340 J --- 3,400 J --- 3,330 J ND19-Aug-15 10,000 250,000 ------ 42,900 J 10,200 J --- 8,110 J --- 10,400 J --- 2,890 J --- 3,210 J ND18-Feb-16 2,000 500,000 ------ 39,300 J 11,200 J --- 7,960 J --- 10,300 J --- 3,830 J --- 3,310 J ND
11-Aug-16 5,000 1,250,000 ------ 112,000 J 8,500 J --- 7,700 J --- 10,300 J --- 3,100 J --- 3,140 J ND
15-Feb-17 1,000 250,000 ------ 47,100 J 11,200 J --- 7,860 J --- 7,940 J --- 3,510 J --- 3,260 J ND
Total Dissolved Solids, Dissolved 23-Jun-10 250,000 250,000 ---710,000 --- 96,200 --- 184,000 --- 364,000 --- 237,000 --- 360,000 ND
NC 2L = 500,000 µg/L (2/5/10)14-Dec-10 25,000 25,000 --------- 100,000 --- 218,000 --- 372,000 --- 260,000 --- 347,000 ND21-Jun-11 5,000 5,000 ------ 170,000 89,000 --- 194,000 --- 374,000 --- 238,000 --- 378,000 ND6-Dec-11 25,000 25,000 ------ 174,000 92,000 --- 168,000 --- 378,000 --- 242,000 --- 408,000 ND
13-Jun-12 25,000 25,000 ------ 189,000 98,000 --- 184,000 --- 390,000 --- 253,000 --- 402,000 ND
11-Dec-12 25,000 25,000 ------ 199,000 141,000 --- 199,000 --- 427,000 --- 274,000 --- 419,000 ND29-Apr-13 25,000 25,000 ------ 170,000 114,000 --- 183,000 --- 416,000 --- 276,000 --- 466,000 ND
6-Aug-13 25,000 25,000 ------ 179,000 142,000 --- 175,000 --- 421,000 --- 291,000 --- 423,000 ND
25-Feb-14 25,000 25,000 ------ 173,000 109,000 --- 206,000 --- 405,000 --- 281,000 --- 421,000 ND13-Aug-14 25,000 25,000 ------ 172,000 184,000 --- 187,000 --- 446,000 --- 319,000 --- 504,000 ND12-Mar-15 25,000 25,000 ------ 229,000 113,000 --- 184,000 --- 430,000 --- 256,000 --- 470,000 ND
19-Aug-15 25,000 25,000 ------ 217,000 149,000 --- 172,000 --- 431,000 --- 303,000 --- 487,000 ND
18-Feb-16 25,000 25,000 ------ 162,000 84,000 --- 140,000 --- 412,000 --- 237,000 --- 475,000 ND11-Aug-16 25,000 25,000 ------ 213,000 122,000 H1,D --- 171,000 --- 437,000 --- 301,000 --- 516,000 ND
15-Feb-17 25,000 25,000 ------ 233,000 62,000 D6 --- 154,000 --- 438,000 --- 277,000 --- 481,000 ND
Notes:
All concentrations are in micrograms per liter (µg/L).RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.ND = Not detected above laboratory reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).When the NC 2L has not been established, the GWPS will be used.Bold values for groundwater are above the NC 2L Standards or GWPS.
--- = Well was not monitored and/or not reported.
# = Data for MW-1A during the July 2008 event was not used in background calculations because samples were composed of too much sediment due to basically dry conditions, leading to skewed values of inorganic constituents.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 9
Joyce Engineering

Appendix D

Historical Detected Organic Constituents in Compliance Wells

APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Organic CompoundsAcetone 15-Dec-09 2.2 100 --- ND --- ND --- ND --- ND --- ND --- ND 2.8 J23-Jun-10 2.2 100 --- ND --- ND --- ND --- ND --- ND --- ND 7.7 J
NC 2L = 700 µg/L (10/23/07)14-Dec-10 2.2 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 2.2 100 --- --- ND 3.8 B --- 2.8 B --- ND --- ND --- ND 3.9 JNC 2B = NE µg/L (05/01/07)6-Dec-11 2.2 100 --- --- ND ND --- ND --- ND --- ND --- ND 8.8 JNC 2L = 6,000 µg/L (2/5/10)13-Jun-12 2.2 100 --- --- ND ND --- ND --- ND --- ND --- ND 4.7 J
12-Dec-12 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND 14.6 J6-Aug-13 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND 19.3 J
13-Aug-14 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 10.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
Benzene 14-Sep-94 --- 5 ND ND --- ND 12.0 --- ND --- ND --- ND ------2-Dec-94 --- 5 ND ND --- ND 14.0 --- ND --- ND --- ND ------8-Feb-95 --- 5 ND ND --- ND 15.0 --- ND --- ND --- ND ------
2-Mar-95 --- 5 ND ND --- ND 13.0 --- ND --- ND --- ND ------
17-Nov-95 --- 5 ND ND --- ND 16.0 --- ND --- ND --- ND ------23-May-96 --- 5 ND ND --- ND 15.0 --- ND --- ND --- ND ------
14-Nov-96 --- 5 ND ND --- ND 9.0 --- ND --- ND --- ND ------
18-Jun-97 --- 5 ND ND --- ND 13.0 --- ND --- ND --- ND ------2-Dec-97 --- 5 ND ND --- ND 13.0 --- ND --- ND --- ND ------27-May-98 --- 5 ND ND --- ND 12.0 --- ND --- ND --- ND ------
16-Nov-98 --- 5 ND ND --- ND 12.4 --- ND --- ND --- ND ------
10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
10-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 5 --- ND --- ND --- ND ---7.0 --- ND --- ND ND
30-Dec-03 --- 5 --- ND --- ND --- ND ---12.0 --- ND --- ND ND
30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 3 --- ND --- ND --- ND 1.3 ND ND ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND --- 0.40 J --- ND ND
NC 2L = 1 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- ND --- ND --- 0.53 J --- ND ND8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND --- 0.59 J --- ND ND16-Dec-08 0.25 1.0 --- ND --- ND --- ND --- ND --- 0.40 J --- ND ND
8-Jul-09 0.25 1.0 --- ND --- ND --- ND --- ND --- 0.54 J --- ND ND15-Dec-09 0.25 1.0 --- ND --- ND --- ND --- ND --- 0.37 J --- ND ND23-Jun-10 0.25 1.0 --- ND --- ND --- ND --- ND --- 0.42 J --- ND ND
14-Dec-10 0.25 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.39 J --- ND ND6-Dec-11 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.40 J --- ND ND13-Jun-12 0.25 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.41 J --- ND ND
29-Apr-13 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.33 J --- ND ND6-Aug-13 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.40 J --- ND ND
25-Feb-14 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.40 J --- ND ND
13-Aug-14 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.41 J --- ND ND12-Mar-15 0.25 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.35 J --- ND ND
18-Feb-16 0.25 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.25 1.0 --- --- ND ND --- ND --- ND --- 0.34 J --- ND ND15-Feb-17 0.25 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Carbon Disulfide 18-Jun-97 --- 100 ND ND --- ND ND --- ND --- ND --- 16.0 ------2-Dec-97 --- 100 ND ND --- ND 12.0 --- ND --- ND --- 23.0 ------27-May-98 --- 100 ND ND --- ND ND --- ND --- ND --- 46.0 ------
16-Nov-98 --- 100 ND ND --- ND 3.3 --- ND --- ND --- 33.5 ------
10-Sep-99 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
19-Nov-02 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Jun-05 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 100 --- ND --- ND --- ND ND ND ND ND --- ND NDNC 2B = NE µg/L (05/01/07)12-Jul-07 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 700 µg/L (10/23/07)19-Dec-07 --- 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
8-Jul-08 --- 100 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 1.2 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 1.2 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
15-Dec-09 1.2 100 --- ND --- ND --- ND --- ND --- ND --- ND ND23-Jun-10 1.2 100 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 1.2 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Jun-12 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND25-Feb-14 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Mar-15 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND18-Feb-16 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
15-Feb-17 1.2 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Chlorobenzene 16-Nov-98 --- 5 ND ND --- ND ND --- 2.7 --- ND --- ND ------
10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 3 --- ND --- ND --- ND --- ND ND ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 3 --- ND --- ND --- ND --- ND --- 0.34 J --- ND ND
NC 2L = 50 µg/L (10/23/07)19-Dec-07 --- 3 --- --- --- ND --- 0.64 J --- ND --- 0.44 J --- ND ND8-Jul-08 --- 3.0 --- --- --- ND --- ND --- ND --- 0.97 J --- ND ND16-Dec-08 0.23 3.0 --- ND --- ND --- ND --- ND --- 0.42 J --- ND ND
8-Jul-09 0.23 3.0 --- ND --- ND --- 0.25 J --- ND --- 0.57 J --- ND ND
15-Dec-09 0.23 3.0 --- ND --- ND --- 0.25 J --- ND --- 0.49 J --- ND ND23-Jun-10 0.23 3.0 --- ND --- ND --- 0.26 J --- ND --- 0.53 J --- ND ND14-Dec-10 0.23 3.0 --- --- --- ND --- ND --- ND --- 0.93 B --- ND 0.43 J
21-Jun-11 0.23 3.0 --- --- ND ND --- 0.27 J --- ND --- 0.65 J --- ND ND
6-Dec-11 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.63 J --- ND ND13-Jun-12 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.55 J --- ND ND
12-Dec-12 0.23 3.0 --- --- ND ND --- ND --- ND --- 1.0 J --- ND ND
29-Apr-13 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.70 J --- ND ND6-Aug-13 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.83 J --- ND ND25-Feb-14 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.78 J --- ND ND
13-Aug-14 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.87 J --- ND ND
12-Mar-15 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.64 J --- ND ND19-Aug-15 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.89 J --- ND ND
18-Feb-16 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.79 J --- ND ND
11-Aug-16 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.96 J --- ND ND15-Feb-17 0.23 3.0 --- --- ND ND --- ND --- ND --- 0.90 J --- ND ND
Chloroethane 14-Sep-94 --- 10 ND ND --- ND 30.0 --- ND --- ND --- ND ------
2-Dec-94 --- 10 ND ND --- ND 26.0 --- ND --- ND --- ND ------8-Feb-95 --- 10 ND ND --- ND 33.0 --- ND --- ND --- 35.0 ------2-Mar-95 --- 10 ND ND --- ND 26.0 --- ND --- ND --- 24.0 ------
17-Nov-95 --- 10 ND ND --- ND 25.0 --- ND --- ND --- 27.0 ------23-May-96 --- 10 ND ND --- ND 26.0 --- ND --- ND --- 56.0 ------14-Nov-96 --- 10 ND ND --- ND 16.0 --- ND --- ND --- ND ------
18-Jun-97 --- 10 ND ND --- ND 21.0 --- ND --- ND --- 63.0 ------
2-Dec-97 --- 10 ND ND --- ND 22.0 --- 2.0 --- ND --- 64.0 ------27-May-98 --- 10 ND ND --- ND 16.0 --- ND --- ND --- 78.0 ------16-Nov-98 --- 10 ND ND --- ND 15.8 --- ND --- ND --- 36.2 ------
10-Sep-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---13-Jun-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
19-Nov-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Jun-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- 10 --- ND --- ND --- ND ND ND ND ND --- ND NDNC 2B = NE µg/L (05/01/07)12-Jul-07 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 2,800 µg/L (10/23/07)19-Dec-07 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ND
8-Jul-08 --- 10.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 0.54 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND8-Jul-09 0.54 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
15-Dec-09 0.54 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 3,000 µg/L (2/5/10)23-Jun-10 0.54 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 0.54 10.0 --- --- --- ND --- ND --- ND --- ND --- ND ND21-Jun-11 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Jun-12 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND25-Feb-14 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Mar-15 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
19-Aug-15 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND18-Feb-16 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
15-Feb-17 0.54 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Chloromethane 23-Jun-10 0.11 1.0 --- 0.14 J --- ND --- 0.12 J --- ND --- ND --- 0.16 J ND
NC 2L = 3 µg/L (2/5/10)14-Dec-10 0.11 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
NC 2B = NE µg/L (05/01/07)21-Jun-11 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Jun-12 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.11 1.0 --- --- ND ND --- ND --- ND --- 0.12 J --- ND ND15-Feb-17 0.11 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,2-Dichlorobenzene 12-Jul-07 --- 5 --- ND --- ND --- ND --- ND --- 0.6 J --- ND ND
NC 2B = NE µg/L (05/01/07)19-Dec-07 --- 5 --- --- --- ND --- 0.32 J --- ND --- 0.99 J --- ND NDNC 2L = 24 µg/L (10/23/07)8-Jul-08 --- 5.0 --- --- --- ND --- ND --- ND --- 1.3 J --- ND ND
16-Dec-08 0.30 5.0 --- ND --- ND --- ND --- ND --- 0.73 J --- ND ND
8-Jul-09 0.30 5.0 --- ND --- ND --- ND --- ND --- 1.1 J --- ND ND15-Dec-09 0.30 5.0 --- ND --- ND --- ND --- ND --- 0.99 J --- ND NDNC 2L = 20 µg/L (2/5/10)23-Jun-10 0.30 5.0 --- ND --- ND --- ND --- ND --- 1.0 J --- ND ND
14-Dec-10 0.30 5.0 --- --- --- ND --- ND --- ND --- 0.78 J --- ND ND
21-Jun-11 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND6-Dec-11 0.30 5.0 --- --- ND ND --- ND --- ND --- 0.74 J --- ND ND
13-Jun-12 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND
12-Dec-12 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND29-Apr-13 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND6-Aug-13 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND
25-Feb-14 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND
13-Aug-14 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND12-Mar-15 0.30 5.0 --- --- ND ND --- ND --- ND --- 0.89 J --- ND ND
19-Aug-15 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND
18-Feb-16 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.0 J --- ND ND11-Aug-16 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND15-Feb-17 0.30 5.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND
1,3-Dichlorobenzene 8-Jul-08 --- 5.0 --- --- --- ND --- ND --- ND --- 0.29 J --- ND NDNC 2L = 170 µg/L (10/23/07)16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 5.0 --- ND --- ND --- ND --- ND --- 0.38 J --- ND ND
15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2L = 200 µg/L (2/5/10)23-Jun-10 0.24 5.0 --- --- --- ND --- --- --- ND --- 0.35 J --- ND ND14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------
21-Jun-11 0.24 5.0 --- --- ND ND --- --- --- ND --- 0.32 J --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.24 5.0 --- --- ND ND --- ND --- ND --- 0.29 J --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.24 5.0 --- --- ND ND --- ND --- ND --- 0.36 J --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 0.24 5.0 --- --- ND ND --- ND --- ND --- 0.29 J --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.24 5.0 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.24 5.0 --- --- ND --- --- --- ------ --- 0.31 J ------ND11-Aug-16 0.24 5.0 --- --- ND --- --- --- ------ --- ND ------ND
15-Feb-17 0.24 5.0 --- --- ND --- --- --- ------ --- 0.38 J ------ND
1,4-Dichlorobenzene 14-Sep-94 --- 5 ND ND --- ND 5.0 --- ND --- ND --- ND ---NA2-Dec-94 --- 5 ND ND --- ND ND --- ND --- ND --- ND ---NA
8-Feb-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ---NA2-Mar-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ---NA17-Nov-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
23-May-96 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
14-Nov-96 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------18-Jun-97 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-97 --- 5 ND ND --- ND 2.0 ---2.0 --- ND --- ND ------
27-May-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 5 ND ND --- ND 2.1 ---3.2 --- ND --- 2.2 ------10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 10.5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 3 --- ND --- ND --- ND 3.7 ND ND ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- 0.32 J --- ND --- ND --- ND ND
Resample >21-Aug-07 --- 1 --- --- --- --- --- 0.30 J ------ --- --- ---------NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- 0.52 J --- ND --- 0.71 J --- ND ND
8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND --- 0.96 J --- ND ND
16-Dec-08 0.33 1.0 --- ND --- ND --- ND --- ND --- 0.64 J --- ND ND8-Jul-09 0.33 1.0 --- ND --- ND --- ND --- ND --- 0.84 J --- ND ND15-Dec-09 0.33 1.0 --- ND --- ND --- ND --- ND --- 0.76 J --- ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.33 1.0 --- ND --- ND --- ND --- ND --- 0.79 J --- ND ND
14-Dec-10 0.33 1.0 --- --- --- ND --- ND --- ND --- 0.96 B --- ND 0.35 J21-Jun-11 0.33 1.0 --- --- ND ND --- ND --- ND --- 1.0 --- ND ND
6-Dec-11 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.81 J --- ND ND
13-Jun-12 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.77 J --- ND ND12-Dec-12 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.83 J --- ND ND29-Apr-13 0.33 1.0 --- --- ND ND --- ND --- ND --- 1.0 --- ND ND
6-Aug-13 0.33 1.0 --- --- ND ND --- ND --- ND --- 1.0 --- ND ND
25-Feb-14 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.82 J --- ND ND13-Aug-14 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.97 J --- ND ND
12-Mar-15 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.86 J --- ND ND
19-Aug-15 0.33 1.0 --- --- ND ND --- ND --- ND --- 1.00 --- ND ND18-Feb-16 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.92 J --- ND ND11-Aug-16 0.33 1.0 --- --- ND ND --- ND --- ND --- 0.93 J --- ND ND
15-Feb-17 0.33 1.0 --- --- ND ND --- ND --- ND --- 1.10 --- ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Trans-1,4-Dichloro-2-Butene 27-May-98 --- 100 ND ND --- ND ND --- ND --- ND --- 6.9 ------
16-Nov-98 --- 100 ND ND --- ND ND --- ND --- ND --- ND ------10-Sep-99 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 100 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Oct-01 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND30-Jun-04 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- 100 --- ND --- ND --- ND ND ND ND ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 100 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = NE µg/L (10/23/07)19-Dec-07 --- 100 --- --- --- ND --- ND --- ND --- ND --- ND ND8-Jul-08 --- 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 1.0 100 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 1.0 100 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 1.0 100 --- ND --- ND --- ND --- ND --- ND --- ND ND23-Jun-10 1.0 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 1.0 100 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Jun-12 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND29-Apr-13 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
19-Aug-15 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND11-Aug-16 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 1.0 100 --- --- ND ND --- ND --- ND --- ND --- ND ND
Dichlorodifluoromethane 17-Nov-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-97 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------23-Mar-98 --- 5 ND ND --- ND ND --- 6.1 --- ND --- 6.0 ------
27-May-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------16-Nov-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 5 --- --- --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 5 --- --- --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 5 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 5 --- --- --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 5 --- --- --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 5 --- --- --- --- --- --- ------ --- --- ---------
30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-05 --- 5 --- --- --- --- --- --- ------ --- --- ---------
28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- --- --- --- --- --- --- --- ND --- ND --- ---------NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 1,400 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-08 --- 5.0 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 --- --- --- --- --- ND --- --- ------ --- --- ---------8-Jul-09 0.21 5.0 --- ND --- ND --- ND --- ND --- 0.37 J --- ND ND
15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2L = 1000 µg/L (2/5/10)23-Jun-10 0.21 5.0 --- --- --- ND --- ND --- ND --- 0.29 J --- ND ND14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------21-Jun-11 0.21 5.0 --- --- ND ND --- ND --- ND --- 0.36 J --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- --- --- --- --- ---------
13-Jun-12 0.21 5.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.21 5.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- --- --- --- --- ---------25-Feb-14 0.21 5.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 --- --- --- --- --- --- --- --- --- --- --- --- ---------
12-Mar-15 0.21 5.0 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.21 5.0 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.21 5.0 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.21 5.0 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
1,1-Dichloroethane 14-Sep-94 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-94 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------8-Feb-95 --- 5 ND ND --- ND ND --- ND --- 7.0 --- ND ------
2-Mar-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
17-Nov-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------23-May-96 --- 5 ND ND --- ND ND --- ND --- 5.0 --- 7.0 ------14-Nov-96 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
18-Jun-97 --- 5 ND ND --- ND ND --- ND --- ND --- 9.7 ------
2-Dec-97 --- 5 ND ND --- ND ND --- 2.0 --- 10.0 --- ND ------27-May-98 --- 5 ND ND --- ND ND --- ND --- 6.0 --- 12.0 ------
16-Nov-98 --- 5 ND ND --- ND ND --- ND --- 9.0 --- 5.2 ------
10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- 6.0 --- ND ---16-Dec-99 --- 5 --- --- --- --- --- --- ------ --- 5.0 ---------
10-May-00 --- 5 ND ND --- ND --- ND --- ND --- 6.0 --- ND ---
26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- 7.0 --- ND ---18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- 6.0 --- ND ---
27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- 7.0 --- ND ---
10-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- 6.0 --- ND ---13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- 6.0 --- ND ---19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- 7.2 --- ND ND
30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- 6.3 --- ND ND30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- 6.5 --- ND ND29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- 6.9 --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- 7.0 --- ND ND
29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- 6.0 --- ND ND28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- 6.6 --- ND ND
28-Dec-06 --- 5 --- ND --- ND --- ND ND ND 1.7 5.3 --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 5 --- ND --- ND --- 0.33 J --- ND --- 5.4 --- ND NDResample >21-Aug-07 --- 5 --- --- --- --- --- 0.40 J ------ --- --- ---------NC 2L = 70 µg/L (10/23/07)19-Dec-07 --- 5 --- --- --- ND --- ND --- ND --- 6.2 --- ND ND
8-Jul-08 --- 5.0 --- --- --- ND --- ND --- ND --- 5.1 --- ND ND
16-Dec-08 0.32 5.0 --- ND --- ND --- ND --- ND --- 3.4 J --- ND ND8-Jul-09 0.32 5.0 --- ND --- ND --- ND --- ND --- 9.3 --- ND ND
15-Dec-09 0.32 5.0 --- ND --- ND --- ND --- ND --- 6.4 --- ND ND
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.32 5.0 --- ND --- ND --- ND --- ND ---6.5 --- ND ND14-Dec-10 0.32 5.0 --- --- --- ND --- ND --- ND --- 3.9 J --- ND ND21-Jun-11 0.32 5.0 --- --- ND ND --- ND --- ND ---6.7 --- ND ND
6-Dec-11 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.0 J --- ND ND
13-Jun-12 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.7 J --- ND ND12-Dec-12 0.32 5.0 --- --- ND ND --- ND --- ND --- 2.5 J --- ND ND29-Apr-13 0.32 5.0 --- --- ND ND --- ND --- ND --- 5.8 --- ND ND
6-Aug-13 0.32 5.0 --- --- ND ND --- ND --- ND --- 5.0 --- ND ND25-Feb-14 0.32 5.0 --- --- ND ND --- ND --- ND --- 4.5 J --- 0.35 J ND13-Aug-14 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.4 J --- 0.39 J ND
12-Mar-15 0.32 5.0 --- --- ND ND --- ND --- ND --- 4.2 J --- ND ND
19-Aug-15 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.7 J --- 0.54 J ND18-Feb-16 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.4 J --- 0.59 J ND11-Aug-16 0.32 5.0 --- --- ND ND --- ND --- ND --- 3.4 J --- 0.77 J ND
15-Feb-17 0.32 5.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
1,2-Dichloroethane 6-Aug-13 0.12 1.0 --- --- ND ND --- 0.62 J --- ND --- ND --- ND ND
NC 2L = 0.4 µg/L (2/5/10)25-Feb-14 0.12 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 0.12 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 0.12 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 0.24 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 0.24 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.24 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 0.24 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
cis-1,2-Dichloroethene 14-Sep-94 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-94 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------8-Feb-95 --- 5 ND ND --- ND ND --- ND --- 23.0 --- ND ------
2-Mar-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
17-Nov-95 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------23-May-96 --- 5 ND ND --- ND ND --- ND --- 14.0 --- ND ------14-Nov-96 --- 5 ND ND --- ND ND --- ND --- 19.0 --- ND ------
18-Jun-97 --- 5 ND ND --- ND ND --- ND --- 12.0 --- ND ------
2-Dec-97 --- 5 ND ND --- ND ND --- ND --- 23.0 --- ND ------27-May-98 --- 5 ND ND --- ND ND --- ND --- 12.0 --- 5.8 ------
16-Nov-98 --- 5 ND ND --- ND ND --- ND --- 24.8 --- 3.7 ------
10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- 7.0 --- ND ---16-Dec-99 --- 5 --- --- --- --- --- --- ------ --- 7.0 ---------
10-May-00 --- 5 ND ND --- ND --- ND --- ND --- 8.0 --- ND ---
26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- 9.0 --- ND ---18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- 7.0 --- ND ---
27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- 13.0 --- ND ---
10-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- 8.0 --- ND ---13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- 8.0 --- ND ---19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- 12.0 --- ND ND
30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- 10.0 --- ND ND30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- 9.3 --- ND ND
29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- 9.4 --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- 8.0 --- ND ND29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- 8.0 --- ND ND28-Jun-06 --- 5 --- ND --- ND --- ND ND ND --- 8.8 --- ND ND
28-Dec-06 --- 5 --- ND --- ND --- ND --- ND 5.3 6.0 --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 5 --- ND --- ND --- ND --- ND --- 6.2 --- ND NDNC 2L = 70 µg/L (10/23/07)19-Dec-07 --- 5 --- --- --- ND --- ND --- ND --- 7.2 --- ND ND8-Jul-08 --- 5.0 --- --- --- ND --- ND --- ND --- 9.8 --- ND ND
16-Dec-08 1.9 5.0 --- ND --- ND --- ND --- 0.91 B --- 4.2 J --- ND 0.31 J
8-Jul-09 0.19 5.0 --- ND --- ND --- ND --- ND --- 7.7 --- ND ND
15-Dec-09 0.19 5.0 --- ND --- ND --- ND --- ND --- 7.4 --- ND ND
23-Jun-10 0.19 5.0 --- ND --- ND --- ND --- ND --- 7.1 --- ND ND14-Dec-10 0.19 5.0 --- --- --- ND --- ND --- ND --- ND --- ND ND21-Jun-11 0.19 5.0 --- --- ND ND --- ND --- ND --- 6.4 --- ND ND
6-Dec-11 0.19 5.0 --- --- ND ND --- ND --- ND --- 3.0 J --- ND ND
13-Jun-12 0.19 5.0 --- --- ND ND --- ND --- ND --- 4.3 J --- ND ND12-Dec-12 0.19 5.0 --- --- ND ND --- ND --- ND --- 3.3 J --- ND ND
29-Apr-13 0.19 5.0 --- --- ND ND --- ND --- ND --- 4.8 J --- ND ND
6-Aug-13 0.19 5.0 --- --- ND ND --- ND --- ND --- 3.6 J --- ND ND25-Feb-14 0.19 5.0 --- --- ND ND --- ND --- ND --- 3.7 J --- ND ND13-Aug-14 0.19 5.0 --- --- ND ND --- ND --- ND --- 2.8 J --- ND ND
12-Mar-15 0.19 5.0 --- --- ND ND --- ND --- ND --- 2.6 J --- ND ND
19-Aug-15 0.19 5.0 --- --- ND ND --- ND --- ND --- 3.1 J --- 0.35 J ND18-Feb-16 0.19 5.0 --- --- ND ND --- ND --- ND --- 2.5 J --- 0.32 J ND
11-Aug-16 0.19 5.0 --- --- ND ND --- ND --- ND --- 2.7 J --- 0.5 J ND
15-Feb-17 0.19 5.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
2-Hexanone 27-May-98 --- 50 ND ND --- ND ND --- ND --- ND --- 61.0 ------
16-Nov-98 --- 50 ND ND --- ND ND --- ND --- ND --- ND ------10-Sep-99 --- 50 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 50 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 50 ND ND --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 50 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Oct-01 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND30-Jun-04 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- 50 --- ND --- ND --- ND ND ND ND ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 50 --- ND --- ND --- ND --- ND --- ND --- ND NDGWPS = 280 µg/L (10/23/07)19-Dec-07 --- 50 --- --- --- ND --- ND --- ND --- ND --- ND ND8-Jul-08 --- 50.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 0.46 50.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 0.46 50.0 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 0.46 50.0 --- ND --- ND --- ND --- ND --- ND --- ND ND23-Jun-10 0.46 50.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 0.46 50.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Jun-12 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND29-Apr-13 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 0.46 50.0 --- --- ND ND --- 0.55 J --- ND --- ND --- ND ND
25-Feb-14 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
19-Aug-15 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND11-Aug-16 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 0.46 50.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Methylene Chloride 14-Sep-94 --- 10 ND ND --- ND ND --- ND --- ND --- ND ---NA2-Dec-94 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------8-Feb-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
2-Mar-95 --- 10 ND ND --- ND ND --- ND --- ND --- 6.0 ------17-Nov-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------23-May-96 --- 10 ND ND --- ND ND --- ND --- ND --- 17.0 ------
14-Nov-96 --- 10 ND ND --- ND ND --- ND --- ND --- 8.2 ------
18-Jun-97 --- 10 ND ND --- ND ND --- ND --- ND --- 12.0 ------2-Dec-97 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------27-May-98 --- 10 ND ND --- ND ND --- ND --- ND --- 15.0 ------
16-Nov-98 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
10-Sep-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
19-Nov-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Jun-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 6 --- ND --- ND --- ND ND ND ND ND --- ND NDNC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 4.6 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ND
8-Jul-08 --- 2.0 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 0.97 2.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 0.97 2.0 --- ND --- ND --- ND --- ND --- ND --- ND 9.6
15-Dec-09 0.97 2.0 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 5 µg/L (2/5/10)23-Jun-10 0.97 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 0.97 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Jun-12 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND25-Feb-14 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND 1.9 J
13-Aug-14 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Mar-15 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND 1.1
18-Feb-16 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 0.97 1.0 --- --- ND ND --- ND --- ND --- ND --- ND 1.6
Naphthalene 8-Jul-08 --- 10.0 --- --- --- ND --- ND --- ND --- ND --- 2.9 J ND
NC 2L = 21 µg/L (10/23/07)16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = NE µg/L (05/01/07)8-Jul-09 0.24 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2L = 6 µg/L (2/5/10)23-Jun-10 0.24 10.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------21-Jun-11 0.24 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- --- --- --- --- ---------
13-Jun-12 0.24 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------29-Apr-13 0.24 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- --- --- --- --- ---------
25-Feb-14 0.24 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 --- --- --- --- --- --- --- --- --- --- --- --- ---------
12-Mar-15 0.24 10.0 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.24 10.0 --- --- ND --- --- --- --- --- --- ND ------ND11-Aug-16 0.24 10.0 --- --- --- --- --- --- ------ --- --- ---------15-Feb-17 0.24 10.0 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Toluene 18-Jun-97 --- 5 ND ND --- ND 13 --- ND --- ND --- ND ------
2-Dec-97 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------27-May-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------
10-Sep-99 --- 5 ND ND ---7 --- ND --- ND --- ND --- ND ---19-Oct-99 --- 5 --- --- --- ND --- --- ------ --- --- ---------16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND --- ND --- ND 0.34 J
NC 2L = 1,000 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ND8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 0.26 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 0.26 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
15-Dec-09 0.26 1.0 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 600 µg/L (2/5/10)23-Jun-10 0.26 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 0.26 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Jun-12 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
29-Apr-13 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Mar-15 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND19-Aug-15 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
18-Feb-16 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
11-Aug-16 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND15-Feb-17 0.26 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Trichloroethene 2-Dec-97 --- 5 ND ND --- ND ND --- ND --- 2.0 --- ND ------27-May-98 --- 5 ND ND --- ND ND --- ND --- ND --- ND ------16-Nov-98 --- 5 ND ND --- ND ND --- ND --- 2.7 --- 2.9 ------
10-Sep-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 5 ND ND --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Oct-01 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---13-Jun-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
19-Nov-02 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND30-Jun-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Jun-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-05 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 5 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- 3 --- ND --- ND --- ND ND ND ND ND --- ND NDNC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND --- 0.68 J --- ND NDNC 2L = 2.8 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- ND --- ND --- 0.64 J --- ND ND
8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND --- 0.51 J --- ND ND
16-Dec-08 0.47 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND8-Jul-09 0.47 1.0 --- ND --- ND --- ND --- ND --- 0.53 J --- ND ND15-Dec-09 0.47 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 3 µg/L (2/5/10)23-Jun-10 0.47 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 0.47 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND21-Jun-11 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Jun-12 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND29-Apr-13 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Mar-15 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
19-Aug-15 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND18-Feb-16 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND11-Aug-16 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
15-Feb-17 0.47 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Vinyl chloride 14-Sep-94 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-94 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------8-Feb-95 --- 10 ND ND --- ND ND --- ND ---26.0 --- ND ------
2-Mar-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
17-Nov-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------23-May-96 --- 10 ND ND --- ND ND --- ND ---13.0 --- ND ------14-Nov-96 --- 10 ND ND --- ND ND --- ND ---17.0 --- ND ------
18-Jun-97 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-97 --- 10 ND ND --- ND 2.0 --- ND ---33.0 --- ND ------27-May-98 --- 10 ND ND --- ND ND --- ND ---13.0 --- ND ------
16-Nov-98 --- 10 ND ND --- ND ND --- ND ---25.8 --- ND ------
10-Sep-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 10 ND ND --- ND --- ND --- ND ---12.0 --- ND ---
26-Oct-00 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Oct-01 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
10-Jun-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---19-Nov-02 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 10 --- ND --- ND --- ND --- ND ---26.9 --- ND ND
30-Dec-03 --- 10 --- ND --- ND --- ND --- ND ---10.0 --- ND ND
30-Jun-04 --- 10 --- ND --- ND --- ND --- ND ---11.0 --- ND ND29-Dec-04 --- 10 --- ND --- ND --- ND --- ND ---12.0 --- ND ND29-Jun-05 --- 10 --- ND --- ND --- ND --- ND ---14.0 --- ND ND
29-Dec-05 --- 10 --- ND --- ND --- ND --- ND ---15.0 --- ND ND
28-Jun-06 --- 10 --- ND --- ND --- ND --- ND ---12.5 --- ND ND28-Dec-06 --- 6 --- ND --- ND --- ND ND ND 8.1 8.9 --- ND ND
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND ---8.3 --- ND ND
NC 2L = 0.015 µg/L (10/23/07)19-Dec-07 --- 1 --- --- --- ND --- ND --- ND ---8.4 --- ND ND8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND ---10.6 --- ND ND16-Dec-08 0.62 1.0 --- ND --- ND --- ND --- ND ---5.0 --- ND ND
8-Jul-09 0.62 1.0 --- ND --- ND --- ND --- ND ---13.3 --- ND ND
15-Dec-09 0.62 1.0 --- ND --- ND --- ND --- ND ---9.9 --- ND NDNC 2L = 0.03 µg/L (2/5/10)23-Jun-10 0.62 1.0 --- ND --- ND --- ND --- ND ---11.2 --- ND ND
14-Dec-10 0.62 1.0 --- --- --- ND --- ND --- ND ---8.4 --- ND ND
21-Jun-11 0.62 1.0 --- --- ND ND --- ND --- ND ---10.5 --- ND ND6-Dec-11 0.62 1.0 --- --- ND ND --- ND --- ND ---4.1 --- ND ND13-Jun-12 0.62 1.0 --- --- ND ND --- ND --- ND ---6.6 --- ND ND
12-Dec-12 0.62 1.0 --- --- ND ND --- ND --- ND ---3.3 --- ND ND
29-Apr-13 0.62 1.0 --- --- ND ND --- ND --- ND ---7.6 --- ND ND6-Aug-13 0.62 1.0 --- --- ND ND --- ND --- ND ---9.1 --- ND ND25-Feb-14 0.62 1.0 --- --- ND ND --- ND --- ND ---6.8 --- ND ND
13-Aug-14 0.62 1.0 --- --- ND ND --- ND --- ND ---5.4 ---ND ND12-Mar-15 0.62 1.0 --- --- ND ND --- ND --- ND ---5.1 --- ND ND19-Aug-15 0.62 1.0 ------ND ND ---ND ---ND ---5.0 ---ND ND18-Feb-16 0.62 1.0 ------ND ND ---ND ---ND ---5.4 ---ND ND11-Aug-16 0.62 1.0 ------ND ND ---ND ---ND ---5.6 ---ND ND15-Feb-17 0.62 1.0 ------ND ND ---ND ---ND ---1.4 ---ND ND
Bis(2-ethylhexyl)phthalate 21-Jun-11 0.79 15.0 --- --- ND 2.5 J --- ND --- 4.5 J --- ND --- ND NDNC 2L = 3 µg/L (2/5/10) 6-Dec-11 --- --- --- --- --- --- --- --- --- --- --- --- --- --- ---13-Jun-12 0.79 15.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.79 15.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------
25-Feb-14 0.79 15.0 --- --- ND ND --- 40.4 --- 5.0 J --- ND --- ND ND
Resample >15-Apr-14 0.79 15.0 --- --- --- --- --- ND ------ --- --- ------ND13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------12-Mar-15 0.49 15.0 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.85 15.0 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.85 15.0 --- --- --- --- --- --- ------ --- --- ---------15-Feb-17 0.85 15.0 --- --- ND --- --- --- ------ --- ND ------ND
Diethylphthalate 17-Nov-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-97 --- 10 ND ND --- ND ND --- 24.0 --- ND --- ND ------23-Mar-98 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
27-May-98 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 10 ND ND --- ND ND --- 10 --- ND --- ND ------10-Sep-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 10.5 --- --- --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 10 --- --- --- --- --- --- ------ --- --- ---------30-Jun-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Jun-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Jun-06 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 5,000 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-08 --- 20.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-09 2.7 11.1 --- ND --- --- --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2L = 6,000 µg/L (2/5/10)23-Jun-10 3.9 14.3 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------21-Jun-11 0.58 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------
13-Jun-12 0.58 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------29-Apr-13 0.58 6000 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------
25-Feb-14 0.58 6000 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------12-Mar-15 0.91 6000 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 1.30 6000 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 1.30 6000 --- --- --- --- --- --- ------15-Feb-17 1.30 6000 --- --- ND --- --- --- ------ --- ND ------ND
Benzo(g,h,i)perylene 21-Jun-11 0.79 15.0 --- --- ND ND --- ND --- ND --- 1.1 J --- ND ND
NC 2L = 200 µg/L (2/5/10)6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.38 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.38 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 0.38 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.45 10.0 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.38 10.0 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.38 10.0 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.38 10.0 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dibenz(a,h)anthracene 21-Jun-11 0.79 15.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND
NC 2L = 0.005 µg/L (2/5/10)6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.55 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.55 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 0.55 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.49 10.0 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.55 10.0 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.55 10.0 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.55 10.0 --- --- ND --- --- --- ------ --- ND ------ND
Indeno(1,2,3-cd)pyrene 21-Jun-11 0.79 15.0 --- --- ND ND --- ND --- ND --- 1.2 J --- ND ND
NC 2L = 0.05 µg/L (2/5/10)6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------
13-Jun-12 0.29 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.29 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 0.29 10.0 --- --- ND --- --- ND --- ND --- ND --- ND ND13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.53 10.0 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.29 10.0 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.29 10.0 --- --- --- --- --- --- ------ --- --- ---------15-Feb-17 0.29 10.0 --- --- ND --- --- --- ------ --- ND ------ND
Phorate 17-Nov-95 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-97 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 10 ND ND --- ND ND --- ND --- ND --- ND ------
10-Sep-99 --- 10 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 10 --- --- --- ND --- 1.0 --- ND --- 0.8 --- ND ---26-Oct-00 --- 1.5 --- --- --- ND --- 5.2 --- ND --- ND --- ND ---
18-Apr-01 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 0.5 --- --- --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 10 --- --- --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 10 --- --- --- --- --- --- ------ --- --- ---------
30-Jun-04 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------29-Jun-05 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 10 --- --- --- --- --- --- ------ --- --- ---------
28-Jun-06 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 10 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 1.4 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-08 --- 40.0 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-09 6.6 22.2 --- ND --- --- --- ND --- ND --- ND --- ND ND
15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2L = 1 µg/L (2/5/10)23-Jun-10 7.7 28.6 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------
21-Jun-11 5.4 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 5.4 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 5.4 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 5.4 10.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.83 10.0 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 1.10 10.0 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 1.10 10.0 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 1.10 10.0 --- --- ND --- --- --- ------ --- ND ------ND
Aldrin 17-Nov-95 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-97 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
23-Mar-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------27-May-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------16-Nov-98 --- 0.05 ND ND --- ND ND --- 0.073 --- ND --- ND ------
10-Sep-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---13-Jun-02 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 0.05 --- --- --- --- --- --- ------ --- --- ---------
30-Jun-04 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Jun-05 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 0.05 --- --- --- --- --- --- ------ --- --- ---------28-Jun-06 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = NE µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-08 --- 0.050 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-09 0.050 0.050 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------23-Jun-10 0.00053 0.011 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------
21-Jun-11 0.00050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.05 0.05 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------
25-Feb-14 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------12-Mar-15 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.050 0.050 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 9 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Alpha-BHC 17-Nov-95 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-97 --- 0.05 ND ND --- ND ND --- 0.20 --- ND --- ND ------23-Mar-98 --- 0.05 ND ND --- ND 0.073 --- 0.16 --- ND --- ND ------
27-May-98 --- 0.05 ND ND --- ND ND --- ND --- 0.095 --- 0.053 ------
16-Nov-98 --- 0.05 ND ND --- ND ND --- 0.23 --- ND --- ND ------10-Sep-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 0.05 --- --- --- --- --- --- ------ --- --- ---------30-Jun-04 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Jun-05 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-05 --- 0.05 --- --- --- --- --- --- ------ --- --- ---------
28-Jun-06 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ---GWPS = 0.006 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-08 --- 0.050 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-09 0.050 0.050 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------
23-Jun-10 0.00032 0.011 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------21-Jun-11 0.00030 0.050 --- --- ND ND ---0.054 --- ND --- ND --- ND ND
Resample >28-Jul-11 0.00030 0.050 --- --- --- --- --- ND ------ --- --- ------ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.05 0.05 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Apr-13 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- --- ---------25-Feb-14 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.050 0.050 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
Beta-BHC 27-Jun-03 --- 1.05 --- ND --- ND --- 0.068 --- ND --- ND --- ND ---30-Dec-03 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
30-Jun-04 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Jun-05 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
28-Jun-06 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = NE µg/L (05/01/07)12-Jul-07 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
GWPS = 0.019 µg/L (10/23/07)19-Dec-07 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ND
8-Jul-08 --- 0.050 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 0.050 0.050 --- ND --- ND --- ND --- ND --- ND --- ND ND
8-Jul-09 0.050 0.050 --- ND --- ND --- ND --- ND --- ND --- ND ND
15-Dec-09 0.010 0.100 --- ND --- ND --- ND --- ND --- ND --- ND ND23-Jun-10 0.00053 0.011 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 0.00050 0.050 --- --- --- ND --- ND --- ND --- ND --- ND ND
21-Jun-11 0.00050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 0.050 0.050 --- --- ND ND --- ND --- ND ---0.059 --- ND NDResample >25-Jan-12 0.050 0.050 --- --- ND --- --- --- ------ ---0.082 ------ND
13-Jun-12 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 0.050 0.050 --- --- ND ND --- ND --- ND ---0.078 --- ND ND29-Apr-13 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 0.050 0.050 --- --- ND ND --- ND --- ND ---0.056 --- ND ND
13-Aug-14 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND12-Mar-15 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND19-Aug-15 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND15-Feb-17 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
4,4'-DDT 23-Jun-10 0.0037 0.010 --- ND --- ND --- ND --- ND --- 0.016 J --- ND NDNC 2L = 0.1 µg/L (2/5/10)14-Dec-10 --- --- --- --- --- --- --- --- ------ --- ND ---------NC 2B = 0.001 µg/L (05/01/07)21-Jun-11 0.0036 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- ND ---------
13-Jun-12 0.05 0.10 --- --- ND ND --- ND --- ND --- 0.090 J --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- ND ---------
29-Apr-13 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- ND ---------25-Feb-14 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.050 0.10 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 10 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Dieldrin 17-Nov-95 --- 0.1 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-97 --- 0.1 ND ND --- ND ND --- 0.10 --- ND --- ND ------23-Mar-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
27-May-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 0.1 ND ND --- ND ND --- ND --- ND --- ND ------10-Sep-99 --- 0.1 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ---
27-Jun-03 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ---30-Dec-03 --- 0.1 --- --- --- --- --- --- ------ --- --- ---------30-Jun-04 --- 0.1 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Jun-05 --- 0.1 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-05 --- 0.1 --- --- --- --- --- --- ------ --- --- ---------
28-Jun-06 --- 0.1 --- --- --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2B = 0.002 µg/L (05/01/07)12-Jul-07 --- 0.075 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 0.0022 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-08 --- 0.075 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-09 0.050 0.075 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2L = 0.002 µg/L (2/5/10)23-Jun-10 0.00053 0.011 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------21-Jun-11 0.00050 0.075 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------
13-Jun-12 0.05 0.05 --- --- ND ND --- ND --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- --- ------ --- ND ---------29-Apr-13 0.050 0.075 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- ND ---------
25-Feb-14 0.050 0.075 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.050 0.075 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.050 0.075 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.050 0.075 --- --- --- --- --- --- ------ --- --- ---------15-Feb-17 0.050 0.075 --- --- ND --- --- --- ------ --- ND ------ND
Endosulfan I 21-Jun-11 0.00070 0.10 --- --- ND ND --- 0.52 --- ND --- ND --- ND NDNC 2L = 40 µg/L (2/5/10) Resample > 28-Jul-11 0.00070 0.10 --- --- --- --- --- ND ------ --- --- ------ND6-Dec-11 --- --- --- --- --- --- --- ND ------ --- --- ------ND
13-Jun-12 0.050 0.10 --- --- ND ND --- 0.33 --- ND --- ND --- ND ND12-Dec-12 0.050 0.10 --- --- ND ND --- 1.33 --- ND --- ND --- ND ND29-Apr-13 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
25-Feb-14 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND13-Aug-14 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND12-Mar-15 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
19-Aug-15 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
15-Feb-17 0.050 0.10 --- --- ND --- --- --- ------ --- ND ------ND
Endosulfan Sulfate 13-Jun-12 0.050 0.10 --- --- ND ND --- 0.090 J --- ND --- ND --- ND ND12-Dec-12 --- --- --- --- --- --- --- ND ------ --- --- ---------
29-Apr-13 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Aug-13 --- --- --- --- --- --- --- --- ------ --- ND ---------25-Feb-14 0.050 0.10 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.05 0.10 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.05 0.10 --- --- ND --- --- --- ------ --- ND ------ND11-Aug-16 0.05 0.10 --- --- --- --- --- --- ------ --- --- ---------
15-Feb-17 0.05 0.10 --- --- ND --- --- --- ------ --- ND ------ND
Heptachlor 17-Nov-95 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------2-Dec-97 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
23-Mar-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------
27-May-98 --- 0.05 ND ND --- ND ND --- ND --- ND --- ND ------16-Nov-98 --- 0.05 ND ND --- ND ND --- 0.068 --- ND --- ND ------
10-Sep-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---
16-Nov-99 --- 0.05 ND ND --- ND --- ND --- ND --- ND --- ND ---10-May-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---26-Oct-00 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
18-Apr-01 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---27-Jun-03 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- 0.05 --- --- --- --- --- --- ------ --- --- ------ND
30-Jun-04 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- 0.05 --- --- --- --- --- --- ------ --- --- ------ND29-Jun-05 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 0.05 --- --- --- --- --- --- ------ --- --- ------ND
28-Jun-06 --- 0.05 --- --- --- ND --- ND --- ND --- ND --- ND ND28-Dec-06 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2B = 0.004 µg/L (05/01/07)12-Jul-07 --- 0.05 --- ND --- ND --- ND --- ND --- ND --- ND ND
NC 2L = 0.0078 µg/L (10/23/07)19-Dec-07 --- 0.05 --- --- --- --- --- --- ------ --- --- ------ND8-Jul-08 --- 0.050 --- --- --- ND --- ND --- ND --- ND --- ND ND16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-09 0.050 0.050 --- ND --- ND --- ND --- ND --- ND --- ND ND
15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2L = 0.008 µg/L (2/5/10)23-Jun-10 0.0016 0.011 --- ND --- ND --- ND --- ND --- ND --- ND ND14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------
21-Jun-11 0.0015 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------13-Jun-12 0.05 0.05 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- ND ------ --- --- ---------
29-Apr-13 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- ND ---------25-Feb-14 0.050 0.050 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------
12-Mar-15 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND18-Feb-16 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.050 0.050 --- ------ --- --- ------ --- --- ---------
15-Feb-17 0.050 0.050 --- --- ND --- --- --- ------ --- ND ------ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 11 of 12
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED ORGANIC CONSTITUENTS IN COMPLIANCE WELLS
Analyte Sample Collection Date DL RL MW-1 MW-1A MW-7 MW-2 MW-3 MW-3R MW-4 MW-4R MW-5 MW-5R MW-6 MW-6R Blanks
Methoxychlor 17-Nov-95 --- 1 ND ND --- ND ND --- ND --- ND --- ND ------
2-Dec-97 --- 1 ND ND --- ND ND --- ND --- ND --- ND ------23-Mar-98 --- 2 ND ND --- ND ND --- ND --- ND --- ND ------
27-May-98 --- 2 ND ND --- ND ND --- ND --- ND --- ND ------
16-Nov-98 --- 1 ND ND --- ND ND --- 0.51 --- ND --- ND ------10-Sep-99 --- 1 ND ND --- ND --- ND --- ND --- ND --- ND ---16-Nov-99 --- 2 ND ND --- ND --- ND --- ND --- ND --- ND ---
10-May-00 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ---
26-Oct-00 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ---18-Apr-01 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ---
13-Jun-02 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ---
30-Dec-03 --- --- --- --- --- --- --- --- ------ --- --- ---------30-Jun-04 --- 1 --- ND --- ND --- ND --- ND --- ND --- ND ND29-Dec-04 --- --- --- --- --- --- --- --- ------ --- --- ---------
29-Jun-05 --- 1 --- ND --- ND --- ND --- ND --- ND --- ND ND
29-Dec-05 --- 1 --- --- --- --- --- --- ------ --- --- ---------28-Jun-06 --- 1 --- --- --- ND --- ND --- ND --- ND --- ND ND
28-Dec-06 --- --- --- --- --- --- --- --- ------ --- --- ---------
NC 2B = 0.03 µg/L (05/01/07)12-Jul-07 --- 1 --- ND --- ND --- ND --- ND --- ND --- ND NDNC 2L = 35 µg/L (10/23/07)19-Dec-07 --- --- --- --- --- --- --- --- ------ --- --- ---------8-Jul-08 --- 1.0 --- --- --- ND --- ND --- ND --- ND --- ND ND
16-Dec-08 --- --- --- --- --- --- --- --- ------ --- --- ---------
8-Jul-09 0.50 1.0 --- ND --- ND --- ND --- ND --- ND --- ND ND15-Dec-09 --- --- --- --- --- --- --- --- ------ --- --- ---------NC 2L = 40 µg/L (2/5/10)23-Jun-10 0.0074 1.1 --- ND --- ND --- ND --- ND --- ND --- ND ND
14-Dec-10 --- --- --- --- --- --- --- --- ------ --- --- ---------
21-Jun-11 0.0070 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Dec-11 --- --- --- --- --- --- --- --- ------ --- --- ---------
13-Jun-12 0.15 0.15 --- --- ND ND --- ND --- ND --- ND --- ND ND
12-Dec-12 --- --- --- --- --- --- --- ND ------ --- --- ---------29-Apr-13 0.15 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND6-Aug-13 --- --- --- --- --- --- --- --- ------ --- ND ---------
25-Feb-14 0.15 1.0 --- --- ND ND --- ND --- ND --- ND --- ND ND
13-Aug-14 --- --- --- --- --- --- --- --- ------ --- --- ---------12-Mar-15 0.15 1.0 --- --- ND --- --- --- ------ --- ND ------ND
18-Feb-16 0.15 1.0 --- --- ND --- --- --- ------ --- ND ------ND
11-Aug-16 0.15 1.0 --- --- --- --- --- --- ------ --- --- ---------15-Feb-17 0.15 1.0 --- --- ND --- --- --- ------ --- ND ------ND
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present).DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.ND = Not detected above laboratory reporting limit.NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.Bold values for groundwater are above the NC 2L Standards or GWPS.--- = Well was not monitored and/or not reported.
# = Constituent is included on the NC Appendix II list but not on the NC Appendix I list.There was a resamplinging event on August 2, 2007 for MW-16D because the prevoius samples from the May 2007 were analyzed out of hold time. There were no detects in the resample.Volatile organics (8260) for MW-9 for November 10, 2004 sampling event were unable to be analyzed and were resampled on December 1, 2004.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 12 of 12
Joyce Engineering

Appendix E

Historical Detected COCs in Performance and Sentinel Wells

APPENDIX E:
Historical Detected COCs in Performance and Sentinel Wells
Sample
Analyte Collection Date RL NES-1S NES-1D NES-2S NES-2D Blanks
ORGANICS
Vinyl Chloride 18-May-04 10 ND ND ND ND ND
30-Jun-04 10 ND ND ND ND ND
28-Dec-06 6 ND NS ND NS ND
NC 2L = 0.015 µg/L (10/23/07)16-Dec-08 1 ND ND ND ND ND
8-Jul-09 1 ND ND ND ND ND
15-Dec-09 2 ND ND ND ND ND
NC 2L = 0.03 µg/L (01/01/10)23-Jun-10 1.0 ND ND ND ND ND
14-Dec-10 1.0 ND NS ND NS ND
21-Jun-11 1.0 ND ND ND ND ND
5-Dec-11 1.0 ND ND ND ND ND
13-Jun-12 1.0 ND ND ND ND ND
10-Dec-12 1.0 ND ND ND ND ND
30-Apr-13 1.0 ND ND ND ND ND
7-Aug-13 1.0 ND NS ND NS ND
25-Feb-14 1.0 ND ND ND ND ND
13-Aug-14 1.0 NS NS ND NS ND
12-Mar-15 1.0 NS NS ND NS ND
19-Aug-15 1.0 NS NS ND NS ND
18-Feb-16 1.0 NS NS ND NS ND
11-Aug-16 1.0 NS NS ND NS ND
15-Feb-17 1.0 NS NS ND NS ND
1,1-Dichloroethane *18-May-04 5 ND ND ND ND ND
30-Jun-04 5 ND ND ND ND ND
28-Dec-06 5 ND NS ND NS ND
NC 2L = 70 µg/L (10/23/07)16-Dec-08 5NS NS NS NS NS
8-Jul-09 5NS NS NS NS NS
15-Dec-09 5NS NS NS NS NS
NC 2L = 6 µg/L (01/01/10)23-Jun-10 5.0 NS NS ND* ND* ND
14-Dec-10 5.0 0.32 J NS ND NS ND
21-Jun-11 5.0 ND 0.33 J ND ND ND
5-Dec-11 5.0 ND ND ND ND ND
13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND 0.38 J ND ND ND
30-Apr-13 5.0 ND 0.38 J ND ND ND
7-Aug-13 5.0 ND NS ND NS ND
25-Feb-14 5.0 ND 0.33 J ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
18-Feb-16 5.0 NS NS ND NS ND
11-Aug-16 5.0 NS NS NS NS NS
15-Feb-17 5.0 NS NS NS NS NS
beta-BHC * 13-Jun-12 5.0 ND ND ND ND ND
10-Dec-12 5.0 ND ND ND ND ND
GWPS = 0.019 µg/L (10/23/07)30-Apr-13 5.0 ND ND ND ND ND
7-Aug-13 5.0 ND ND ND ND ND
25-Feb-14 5.0 ND ND ND ND ND
13-Aug-14 5.0 NS NS ND NS ND
12-Mar-15 5.0 NS NS ND NS ND
18-Feb-16 5.0 NS NS ND NS ND
11-Aug-16 5.0 NS NS NS NS NS
15-Feb-17 5.0 NS NS NS NS NS
Notes:
COC = Constituents of Concern. µg/L = micrograms per liter = parts per billion.
RL = Reporting Limit. J = Estimated concentraion below the RL.
B = Blank-qualified detection.
* 1,1-DCA was added to the COC list and Benzene and cis-1,2-dichloroethylene ND = Not detected above the laboratory detection limit.
were dropped following DENR SWS approval dataed January 27, 2011. NS = Not sampled for this parameter during this event.
1,1-DCA and beta-BHC were dropped from the COC list following DENR-SWS
approval dated July 30, 2015.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Joyce Engineering

Appendix F

Historical Detected Constituents in Surface Water

APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
INORGANICS
Antimony 23-Jun-10 2.6 6.0 2.8 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 2.6 6.0 ND Dry ND
21-Jun-11 5.0 6.0 ND Dry ND
6-Dec-11 5.0 6.0 ND ND ND
13-Jun-12 5.0 6.0 ND ND ND
11-Dec-12 5.0 6.0 ND Dry ND
29-Apr-13 5.0 6.0 ND ND ND
6-Aug-13 5.0 6.0 ND ND ND
25-Feb-14 5.0 6.0 ND ND ND
13-Aug-14 5.0 6.0 ND ND ND
11-Mar-15 3.8 6.0 ND ND ND
19-Aug-15 3.8 6.0 ND Dry ND
18-Feb-16 3.8 6.0 ND ND ND
11-Aug-16 3.8 6.0 ND ND ND
15-Feb-17 3.9 6.0 ND ND ND
Arsenic 19-Dec-07 NR 10 5.3 Dry ND
NC 2B = 50 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 2.7 11.0 ND ND ND
8-Jul-09 2.7 10.0 ND Dry ND
15-Dec-09 2.7 10.0 ND 2.7 J ND
23-Jun-10 2.7 10.0 9.2 J ND ND
14-Dec-10 2.7 10.0 3.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 6.5 J ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 4.9 J 2.7 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 6.8 J 7.3 J ND
15-Feb-17 5.0 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 1 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Barium 14-Sep-94 NR 500 160 ND NS
2-Dec-94 NR 500 ND ND NS
8-Feb-95 NR 500 ND ND NS
2-Mar-95 NR 500 ND ND NS
17-Nov-95 NR 500 ND ND NS
23-May-96 NR 500 ND ND NS
14-Nov-96 NR 500 69 29 NS
18-Jun-97 NR 500 64 25 NS
2-Dec-97 NR 500 61 41 NS
27-May-98 NR 500 130 50 NS
16-Nov-98 NR 500 93 100 NS
10-Sep-99 NR 500 ND ND NS
16-Nov-99 NR 500 ND ND NS
10-May-00 NR 500 ND ND NS
26-Oct-00 NR 500 ND ND NS
18-Apr-01 NR 500 ND ND NS
19-Nov-02 NR 500 NS ND NS
27-Jun-03 NR 500 ND ND NS
30-Dec-03 NR 500 ND ND ND
30-Jun-04 NR 500 ND ND ND
29-Dec-04 NR 500 ND ND ND
29-Jun-05 NR 500 ND ND ND
29-Dec-05 NR 500 ND ND ND
28-Jun-06 NR 500 ND ND ND
NC 2B = NE (05/01/07)28-Dec-06 NR 100 40.0 47.2 0.20 J
12-Jul-07 NR 100 66.2 J Dry ND
19-Dec-07 NR 100 112 Dry 10.5
8-Jul-08 NR 100 89.0 J Dry 0.29 J
16-Dec-08 0.20 100 42.1 B 54.8 J 10.7 J
8-Jul-09 0.20 100 101 Dry 17.6 J
15-Dec-09 0.20 100 36.3 B 48.4 B 17.1 J
23-Jun-10 0.20 100 115 B 39.1 B 27.3 J
14-Dec-10 0.20 100 97.4 J Dry 12.1 J
21-Jun-11 5.0 100 66.3 J Dry ND
6-Dec-11 5.0 100 59.7 J 55.3 J ND
13-Jun-12 5.0 100 161 85.4 J ND
11-Dec-12 5.0 100 71.1 J Dry ND
29-Apr-13 5.0 100 43.5 J 43.5 J ND
6-Aug-13 5.0 100 80.3 J 23.8 J ND
25-Feb-14 5.0 100 63.9 J 61.8 J ND
13-Aug-14 5.0 100 47.4 J 43.9 J ND
11-Mar-15 2.5 100 28.5 J 42.0 J ND
19-Aug-15 2.5 100 37.0 J Dry ND
18-Feb-16 2.5 100 58.2 J 55.0 J ND
11-Aug-16 2.5 100 175 152 ND
15-Feb-17 2.5 100 285 38.2 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 2 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Beryllium 16-Nov-98 NR 2 1.0 1.0 NS
NC 2B = 6.5 µg/L (05/01/07)10-Sep-99 NR 2 ND ND NS
16-Nov-99 NR 2 ND ND NS
10-May-00 NR 2 ND ND NS
26-Oct-00 NR 2 ND ND NS
18-Apr-01 NR 2 ND ND NS
19-Nov-02 NR 2 ND ND NS
27-Jun-03 NR 2 ND ND NS
30-Dec-03 NR 2 ND ND ND
30-Jun-04 NR 2 ND ND ND
29-Dec-04 NR 2 ND ND ND
29-Jun-05 NR 2 ND ND ND
29-Dec-05 NR 2 ND ND ND
28-Jun-06 NR 2 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 6.5 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
19-Dec-07 NR 1 0.93 J Dry ND
8-Jul-08 NR 1.0 0.47 J Dry ND
16-Dec-08 0.10 1.0 0.21 J 0.27 J ND
8-Jul-09 0.10 1.0 0.29 J Dry ND
15-Dec-09 0.10 1.0 0.27 J 0.22 J ND
23-Jun-10 0.10 1.0 1.2 ND ND
14-Dec-10 0.10 1.0 0.78 J Dry ND {0.15} J
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 1.5 ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND Dry ND
18-Feb-16 0.5 1.0 ND ND ND
11-Aug-16 0.5 1.0 1.9 1.7 ND
15-Feb-17 0.5 1.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 3 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cadmium 19-Nov-02 NR 1 ND 1.0 NS
27-Jun-03 NR 1 ND ND NS
30-Dec-03 NR 1 ND ND ND
30-Jun-04 NR 1 ND ND ND
29-Dec-04 NR 1 ND ND ND
29-Jun-05 NR 1 ND ND ND
29-Dec-05 NR 1 ND ND ND
28-Jun-06 NR 1 ND ND ND
28-Dec-06 NR 1 ND ND ND
NC 2B = 2 µg/L (05/01/07)12-Jul-07 NR 1 ND Dry ND
NC 2L = 1.75 µg/L (10/23/07)19-Dec-07 NR 1 ND Dry ND
8-Jul-08 NR 1.0 ND Dry ND
16-Dec-08 0.50 1.0 ND ND ND
8-Jul-09 0.50 1.0 ND Dry ND
15-Dec-09 0.50 1.0 ND ND ND
23-Jun-10 0.50 1.0 ND ND ND
14-Dec-10 0.50 1.0 ND Dry ND
21-Jun-11 1.0 1.0 ND Dry ND
6-Dec-11 1.0 1.0 ND ND ND
13-Jun-12 1.0 1.0 ND ND ND
11-Dec-12 1.0 1.0 ND Dry ND
29-Apr-13 1.0 1.0 ND ND ND
6-Aug-13 1.0 1.0 ND ND ND
25-Feb-14 1.0 1.0 ND ND ND
13-Aug-14 1.0 1.0 ND ND ND
11-Mar-15 0.5 1.0 ND ND ND
19-Aug-15 0.5 1.0 ND ND ND
18-Feb-16 0.5 1.0 ND ND ND
11-Aug-16 0.5 1.0 ND ND ND
15-Feb-17 0.5 1.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 4 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Chromium 18-Jun-97 NR 10 12.0 ND NS
2-Dec-97 NR 10 8.0 ND NS
27-May-98 NR 10 15.0 ND NS
16-Nov-98 NR 10 30.0 31.0 NS
10-Sep-99 NR 10 24.0 ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 12.6 ND ND
28-Dec-06 NR 10 4.8 J 6.1 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 27.9 Dry ND
8-Jul-08 NR 10.0 19.3 Dry ND
6-Dec-08 0.40 10.0 6.4 J 8.4 J ND
8-Jul-09 0.40 10.0 12.9 Dry ND
15-Dec-09 0.40 10.0 6.0 J 5.0 J ND
23-Jun-10 0.40 10.0 41.8 4.8 J 0.71 J
Resample > 12-Aug-10 0.40 10.0 44.4 NS ND
14-Dec-10 0.40 10.0 32.4 Dry ND
21-Jun-11 5.0 10.0 12.1 Dry ND
6-Dec-11 5.0 10.0 11.8 7.5 J ND
13-Jun-12 5.0 10.0 46.1 20.7 ND
11-Dec-12 5.0 10.0 19.1 Dry ND
29-Apr-13 5.0 10.0 5.8 J 5.8 J ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 13.5 13.2 ND
13-Aug-14 5.0 10.0 10.8 10 J ND
NC 2B = 11 µg/L 03/01/16)11-Mar-15 2.5 10.0 4.0 J 3.1 J ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 63.0 55.1 ND
Resample > 13-Sep-16 2.5 10.0 13.8 (ND)DRY ND
15-Feb-17 2.5 10.0 6.1 J 7.2 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 5 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Cobalt 14-Nov-96 NR 10 3.0 ND NS
18-Jun-97 NR 10 3.0 ND NS
2-Dec-97 NR 10 ND ND NS
27-May-98 NR 10 8.0 5.0 NS
16-Nov-98 NR 10 4.9 5.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 2.8 J ND
NC 2B = NE (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 34.3 Dry 1.6 J
8-Jul-08 NR 10.0 10.0 B Dry 6.2 J
16-Dec-08 0.60 10.0 4.8 B 5.1 B 2.4 J
8-Jul-09 0.60 10.0 7.2 J Dry ND
15-Dec-09 0.60 10.0 1.6 J 1.3 J ND
23-Jun-10 0.60 10.0 23.0 2.7 J ND
Resample > 12-Aug-10 0.60 10.0 30.5 NS ND
14-Dec-10 0.60 10.0 27.0 Dry 1.6 J
21-Jun-11 5.0 10.0 5.4 J Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 12.5 6.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 10.2 10.8 ND
6-Aug-13 5.0 10.0 9.0 J ND ND
25-Feb-14 5.0 10.0 10.1 10.6 ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 16.7 12.7 ND
15-Feb-17 2.5 10.0 4.0 J ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 6 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Copper 18-Jun-97 NR 200 11.0 ND NS
2-Dec-97 NR 200 11.0 ND NS
27-May-98 NR 200 21.0 ND NS
16-Nov-98 NR 200 14.0 16.0 NS
10-Sep-99 NR 200 ND ND NS
16-Nov-99 NR 200 ND ND NS
10-May-00 NR 200 ND ND NS
26-Oct-00 NR 200 ND ND NS
18-Apr-01 NR 200 ND ND NS
19-Nov-02 NR 200 NS ND NS
27-Jun-03 NR 200 ND ND NS
30-Dec-03 NR 200 ND ND ND
30-Jun-04 NR 200 ND ND ND
29-Dec-04 NR 200 ND ND ND
29-Jun-05 NR 200 ND ND ND
29-Dec-05 NR 200 ND ND ND
28-Jun-06 NR 200 ND ND ND
28-Dec-06 NR 10 3.0 B 3.9 0.60 J
NC 2B = 7 µg/L (05/01/07)12-Jul-07 NR 10 ND Dry ND
19-Dec-07 NR 10 23.7 B Dry 10.5 B
8-Jul-08 NR 10.0 14.7 Dry ND
16-Dec-08 0.30 10.0 6.4 J 8.0 J ND
8-Jul-09 0.30 10.0 7.0 J Dry ND
15-Dec-09 0.30 10.0 5.2 J 4.4 J ND
23-Jun-10 0.30 10.0 23.9 2.7 J ND
Resample > 12-Aug-10 0.30 10.0 25.9 ND ND
14-Dec-10 0.30 10.0 21.1 Dry 0.49 J
21-Jun-11 5.0 10.0 7.7 J Dry ND
6-Dec-11 5.0 10.0 12.5 7.7 J ND
13-Jun-12 5.0 10.0 34.5 14.8 ND
11-Dec-12 5.0 10.0 16.4 Dry ND
29-Apr-13 5.0 10.0 7.7 J 7.4 J ND
6-Aug-13 5.0 10.0 5.5 J ND ND
25-Feb-14 5.0 10.0 11.2 10.3 ND
13-Aug-14 5.0 10.0 9.6 J 7.7 J ND
11-Mar-15 2.5 10.0 3.1 J 2.6 J ND
NC 2B = 2.7 µg/L 03/01/16)19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 6.3 J 5.7 J ND
11-Aug-16 2.5 10.0 39.9 34.5 ND
Resample > 13-Sep-16 2.5 10.0 9.3 (2.5 B)B DRY 3.5 B
15-Feb-17 2.5 10.0 5.8 J 5.2 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 7 of 13
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APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Lead 2-Dec-97 NR 10 ND 6.0 NS
27-May-98 NR 10 8.0 ND NS
16-Nov-98 NR 10 7.3 8.9 NS
10-Sep-99 NR 10 ND ND NS
16-Nov-99 NR 10 ND ND NS
10-May-00 NR 10 ND ND NS
26-Oct-00 NR 10 ND ND NS
18-Apr-01 NR 10 ND ND NS
19-Nov-02 NR 10 ND ND NS
27-Jun-03 NR 10 ND ND NS
30-Dec-03 NR 10 ND ND ND
30-Jun-04 NR 10 ND ND ND
29-Dec-04 NR 10 ND ND ND
29-Jun-05 NR 10 ND ND ND
29-Dec-05 NR 10 ND ND ND
28-Jun-06 NR 10 ND ND ND
28-Dec-06 NR 10 ND 4.8 J ND
NC 2B = 25 µg/L (05/01/07)12-Jul-07 NR 10 3.2 J Dry ND
19-Dec-07 NR 10 ND Dry ND
8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 4.0 10.0 ND ND ND
8-Jul-09 4.0 10.0 ND Dry ND
15-Dec-09 4.0 10.0 ND ND ND
23-Jun-10 4.0 10.0 9.2 J ND ND
14-Dec-10 4.0 10.0 5.1 J Dry ND
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 14.3 5.5 J ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
NC 2B = 14 µg/L 03/01/16)18-Feb-16 2.5 10.0 4.0 J 2.6 J ND
11-Aug-16 2.5 10.0 16.6 13.6 ND
Resample > 13-Sep-16 2.5 10.0 4.1 (2.6 J)J DRY ND
15-Feb-17 2.5 10.0 2.5 J 2.5 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 8 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Nickel 28-Dec-06 NR 50 4.6 J 6.2 J ND
NC 2B = 88 µg/L (05/01/07)12-Jul-07 NR 50 4.0 J Dry ND
19-Dec-07 NR 50 21.9 Dry ND
8-Jul-08 NR 50.0 12.1 J Dry ND
16-Dec-08 1.7 50.0 5.2 B 6.8 B 2.4 J
8-Jul-09 1.7 50.0 10.0 J Dry ND
15-Dec-09 1.7 50.0 4.8 B 4.7 B 3.0 J
23-Jun-10 1.7 50.0 21.5 J ND ND
14-Dec-10 1.7 50.0 14.4 J Dry 2.7 J
21-Jun-11 5.0 50.0 5.8 J Dry ND
6-Dec-11 5.0 50.0 7.2 J ND ND
13-Jun-12 5.0 50.0 17.1 J 7.5 J ND
11-Dec-12 5.0 50.0 7.6 J Dry ND
29-Apr-13 5.0 50.0 ND ND ND
6-Aug-13 5.0 50.0 ND ND ND
25-Feb-14 5.0 50.0 7.3 J 6.6 J ND
13-Aug-14 5.0 50.0 7.5 J 5.4 J ND
11-Mar-15 2.5 50.0 3.0 J 2.8 J ND
19-Aug-15 2.5 50.0 ND Dry ND
18-Feb-16 2.5 50.0 3.3 J 3.0 J ND
11-Aug-16 2.5 50.0 22.8 J 19.4 J ND
15-Feb-17 2.5 50.0 4.2 J 4.1 J ND
Selenium 19-Dec-07 NR 10 15.6 Dry ND
NC 2B = 5 µg/L (05/01/07)8-Jul-08 NR 10.0 ND Dry ND
16-Dec-08 3.8 10.0 3.9 B ND 4.9 J
8-Jul-09 3.8 10.0 ND Dry ND
15-Dec-09 3.8 10.0 ND ND ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 3.8 10.0 ND ND ND
14-Dec-10 3.8 10.0 5.9 J Dry ND
21-Jun-11 10.0 10.0 ND Dry ND
6-Dec-11 10.0 10.0 ND ND ND
13-Jun-12 10.0 10.0 ND ND ND
11-Dec-12 10.0 10.0 ND Dry ND
29-Apr-13 10.0 10.0 ND ND ND
6-Aug-13 10.0 10.0 ND ND ND
25-Feb-14 10.0 10.0 ND ND ND
13-Aug-14 10.0 10.0 ND ND ND
11-Mar-15 5.0 10.0 ND ND ND
19-Aug-15 5.0 10.0 ND Dry ND
18-Feb-16 5.0 10.0 ND ND ND
11-Aug-16 5.0 10.0 ND 6.0 J ND
15-Feb-17 5.0 10.0 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 9 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Silver 8-Jul-08 NR 10.0 0.22 J Dry ND
NC 2B = 0.06 µg/L (05/01/07)16-Dec-08 0.10 10.0 ND 0.11 J ND
8-Jul-09 0.10 10.0 ND Dry ND
15-Dec-09 0.10 10.0 ND 0.19 J ND
NC 2L = 20 µg/L (2/5/10)23-Jun-10 0.10 10.0 ND ND ND
14-Dec-10 0.10 10.0 0.21 B Dry {0.25 J} 0.19 J
21-Jun-11 5.0 10.0 ND Dry ND
6-Dec-11 5.0 10.0 ND ND ND
13-Jun-12 5.0 10.0 ND ND ND
11-Dec-12 5.0 10.0 ND Dry ND
29-Apr-13 5.0 10.0 ND ND ND
6-Aug-13 5.0 10.0 ND ND ND
25-Feb-14 5.0 10.0 ND ND ND
13-Aug-14 5.0 10.0 ND ND ND
11-Mar-15 2.5 10.0 ND ND ND
19-Aug-15 2.5 10.0 ND Dry ND
18-Feb-16 2.5 10.0 ND ND ND
11-Aug-16 2.5 10.0 ND ND ND
15-Feb-17 2.5 10.0 ND ND ND
Thallium 19-Dec-07 NR 5.5 5.1 J Dry ND
NC 2B = NE (05/01/07)8-Jul-08 NR 5.5 5.2 J Dry ND
16-Dec-08 3.0 5.5 ND ND ND
8-Jul-09 3.0 5.5 ND Dry ND
15-Dec-09 3.0 5.5 ND ND ND
23-Jun-10 3.0 5.5 ND ND ND
Resample > 12-Aug-10 30.0 55.0 NS NS ND
GWPS = 0.2 µg/L (10/01/10)14-Dec-10 3.0 5.5 6.5 Dry ND
21-Jun-11 5.4 5.5 8.2 Dry ND
6-Dec-11 5.4 5.5 ND ND ND
13-Jun-12 5.4 5.5 ND ND ND
11-Dec-12 5.4 5.5 ND Dry ND
29-Apr-13 5.4 5.5 ND ND ND
6-Aug-13 5.4 5.5 ND ND ND
25-Feb-14 5.4 5.5 ND ND ND
13-Aug-14 5.4 5.5 ND ND ND
11-Mar-15 5.0 5.5 ND ND ND
19-Aug-15 5.0 5.5 ND Dry ND
18-Feb-16 5.0 5.5 ND ND ND
11-Aug-16 5.0 5.5 ND ND ND
15-Feb-17 0.0 5.5 ND ND ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 10 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Vanadium 14-Nov-96 NR 40 11.0 5.0 NS
18-Jun-97 NR 40 20.0 ND NS
2-Dec-97 NR 40 16.0 ND NS
27-May-98 NR 40 44.0 ND NS
16-Nov-98 NR 40 44.0 47.0 NS
10-Sep-99 NR 40 ND ND NS
16-Nov-99 NR 40 ND ND NS
10-May-00 NR 40 ND ND NS
26-Oct-00 NR 40 ND ND NS
18-Apr-01 NR 40 ND ND NS
19-Nov-02 NR 40 ND ND NS
27-Jun-03 NR 40 ND ND NS
30-Dec-03 NR 40 ND ND ND
30-Jun-04 NR 40 ND ND ND
29-Dec-04 NR 40 ND ND ND
29-Jun-05 NR 40 ND ND ND
29-Dec-05 NR 40 ND ND ND
28-Jun-06 NR 40 ND ND ND
28-Dec-06 NR 25 8.6 J 10.7 ND
NC 2B = NE (05/01/07)12-Jul-07 NR 25 5.3 J ND ND
19-Dec-07 NR 25 41.2 ND 0.51 J
Resample >14-Feb-08 NR 25 12.4 Dry 0.24 J
Filtered >14-Feb-08 NR 25 1.6 J Dry ND
8-Jul-08 NR 25.0 38.2 Dry 0.20 J
16-Dec-08 0.20 25.0 11.5 J 14.1 J 0.76 J
8-Jul-09 0.20 25.0 24.3 J Dry 1.3 J
15-Dec-09 0.20 25.0 10 J 7.0 J 0.53 J
23-Jun-10 0.20 25.0 63.4 8.3 J ND
Resample > 12-Aug-10 0.20 25.0 67.9 NS 0.33 J
14-Dec-10 0.20 25.0 52.3 Dry {0.57 J} 0.36 J
21-Jun-11 5.0 25.0 25.3 Dry ND
6-Dec-11 5.0 25.0 19.7 J 13.0 J ND
13-Jun-12 5.0 25.0 130 61.5 ND
11-Dec-12 5.0 25.0 50.7 Dry ND
29-Apr-13 5.0 25.0 16.9 J 18.4 J ND
6-Aug-13 5.0 25.0 15.4 J ND ND
25-Feb-14 5.0 25.0 29.2 29.4 ND
13-Aug-14 5.0 25.0 18.0 J 18.2 J ND
11-Mar-15 2.5 25.0 7.8 J 8.3 J ND
19-Aug-15 2.5 25.0 2.8 J Dry ND
18-Feb-16 2.5 25.0 6.4 J 6.1 J ND
11-Aug-16 2.5 25.0 160 144 ND
15-Feb-17 2.5 25.0 18.2 J 20.8 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 11 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Zinc 14-Sep-94 NR 50 ND ND NS
2-Dec-94 NR 50 61.0 ND NS
8-Feb-95 NR 50 ND ND NS
2-Mar-95 NR 50 64.0 ND NS
17-Nov-95 NR 50 ND ND NS
23-May-96 NR 50 ND ND NS
14-Nov-96 NR 50 ND ND NS
18-Jun-97 NR 50 26.0 ND NS
2-Dec-97 NR 50 32.0 40.0 NS
27-May-98 NR 50 57.0 28.0 NS
16-Nov-98 NR 50 28.0 31.0 NS
10-Sep-99 NR 50 ND ND NS
16-Nov-99 NR 50 ND ND NS
10-May-00 NR 50 ND ND NS
26-Oct-00 NR 50 ND ND NS
18-Apr-01 NR 50 ND ND NS
19-Nov-02 NR 50 NS ND NS
27-Jun-03 NR 50 ND ND NS
30-Dec-03 NR 50 ND ND ND
30-Jun-04 NR 50 ND ND ND
29-Dec-04 NR 50 ND ND ND
29-Jun-05 NR 50 ND ND ND
29-Dec-05 NR 50 ND ND ND
28-Jun-06 NR 50 ND ND ND
28-Dec-06 NR 10 7.4 J 8.5 J ND
NC 2B = 50 µg/L (05/01/07)12-Jul-07 NR 10 10.2 Dry ND
19-Dec-07 NR 10 24.1 B Dry 87.9
8-Jul-08 NR 10.0 17.2 Dry 1.2 J
16-Dec-08 0.40 10.0 8.9 J 11.9 ND
8-Jul-09 0.40 10.0 9.4 J Dry 1.6 J
15-Dec-09 0.40 10.0 8.3 B 8.5 B 7.7 J
23-Jun-10 0.40 10.0 29.3 4.0 J ND
14-Dec-10 0.40 10.0 25.1 B Dry 6.7 J
21-Jun-11 10.0 10.0 10.9 Dry ND
6-Dec-11 10.0 10.0 15.0 B 10.3 B 12.4
13-Jun-12 10.0 10.0 46.3 19.8 ND
11-Dec-12 10.0 10.0 25.4 Dry ND
29-Apr-13 10.0 10.0 13.8 12.5 ND
6-Aug-13 10.0 10.0 11.3 ND ND
25-Feb-14 10.0 10.0 15.0 14.8 ND
13-Aug-14 10.0 10.0 14.3 ND ND
11-Mar-15 5.0 10.0 62.3 11.6 B 6.1 J
NC 2B = 36 µg/L (03/01/16)19-Aug-15 5.0 10.0 ND Dry 11.5
18-Feb-16 5.0 10.0 13.0 11.0 ND
11-Aug-16 5.0 10.0 66.4 54.1 ND
Resample > 13-Sep-16 5.0 10.0 14.5 (5.9 J)B DRY ND
15-Feb-17 5.0 10.0 11.0 9.6 J ND
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 12 of 13
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED CONSTITUENTS IN SURFACE WATER
Sample
Analyte Collection Date DL RL SW-1 SW-2 Blanks
Organic Compounds
Acetone 15-Dec-09 2.2 100 3.9 B 3.2 B 2.8 J
NC 2B = NE (05/01/07)23-Jun-10 2.2 100 5.4 B 2.2 B 7.7 J
14-Dec-10 2.2 100 ND Dry ND
21-Jun-11 2.2 100 3.4 B Dry 3.9 J
6-Dec-11 2.2 100 ND ND 8.8 J
13-Jun-12 2.2 100 2.2 B ND 4.7 J
12-Dec-12 10.0 100 ND Dry ND
29-Apr-13 10.0 100 ND ND 14.6 J
6-Aug-13 10.0 100 ND ND ND
25-Feb-14 10.0 100 ND ND ND
13-Aug-14 10.0 100 ND ND 19.3 J
11-Mar-15 10.0 100 ND ND ND
19-Aug-15 10.0 100 ND Dry ND
18-Feb-16 10.0 100 ND ND ND
11-Aug-16 10.0 100 ND ND ND
15-Feb-17 10.0 100 ND ND ND
2-Hexanone 23-Jun-10 0.46 50.0 1.5 J ND ND
NC 2B = NE (05/01/07)14-Dec-10 0.46 50.0 ND Dry ND
21-Jun-11 0.46 50.0 ND Dry ND
6-Dec-11 0.46 50.0 ND ND ND
13-Jun-12 0.46 50.0 ND ND ND
12-Dec-12 0.46 50.0 0.47 J Dry ND
29-Apr-13 0.46 50.0 ND ND ND
6-Aug-13 0.46 50.0 ND ND ND
25-Feb-14 0.46 50.0 ND ND ND
13-Aug-14 0.46 50.0 ND ND ND
11-Mar-15 0.46 50.0 ND ND ND
19-Aug-15 0.46 50.0 ND Dry ND
18-Feb-16 0.46 50.0 ND ND ND
11-Aug-16 0.46 50.0 1.2 J ND ND
15-Feb-17 0.46 50.0 ND ND ND
Methylene Chloride 29-Apr-13 0.97 1.0 0.98 J ND ND
NC 2B = NE (05/01/07)6-Aug-13 0.97 1.0 ND ND ND
25-Feb-14 0.97 1.0 ND ND ND
13-Aug-14 0.97 1.0 ND ND ND
11-Mar-15 0.97 1.0 ND ND ND
19-Aug-15 0.97 1.0 ND Dry ND
18-Feb-16 0.97 1.0 ND ND ND
11-Aug-16 0.97 1.0 ND ND ND
15-Feb-17 0.97 1.0 ND ND 1.6
Notes:
All concentrations are in micrograms per liter (µg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank-qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry (12/14/10 SW-2 sample attempted, but stream was frozen solid).
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.
NE = Not established.
Shaded values for surface water are above the NC 2B.
Surface waters are classified as fresh-water aquatic life.
Please see the report for information regarding NC 2B exceedences of surface water samples.
9/13/16 RESAMPLE= Parenthesis indicate Dissolved concentrations.
Granville County - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 13 of 13
Joyce Engineering

Appendix G

Historical MNA Parameter Data

APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Temperature 30-Dec-03 oC 15.40 NI NA NS 12.51 13.58 NA NS NS NS NS
18-May-04 oC 14.05 NI NA NS 18.17 14.53 NA 15.04 17.15 12.86 16.41
30-Jun-04 oC 13.88 NI NA NS 14.33 14.18 NA 14.37 17.98 15.67 15.6629-Dec-04 oC 14.30 NI NA NS 14.80 14.40 NA NS NS NS NS
28-Dec-06 ºC 11.60 NI 15.10 NS 14.60 13.40 14.50 14.30 NS 11.20 NS
11-Jul-07 ºC 15.90 NI 15.70 NS 17.30 15.90 19.00 NS NS NS NS
19-Dec-08 ºC 14.50 NM 13.50 12.30 12.80 15.70 12.40 13.90 14.30 12.50 13.20
8-Jul-09 ºC 14.80 NM 15.20 16.00 16.10 17.00 16.90 15.40 14.80 16.00 17.50
14-Dec-09 ºC 9.20 NM 12.50 12.80 12.70 12.50 11.30 13.70 14.60 13.20 13.4023-Jun-10 ºC 18.50 NM 16.69 18.93 18.43 15.76 19.05 18.10 20.28 19.65 20.22
14-Dec-10 ºC Dry NM 11.80 11.31 10.63 12.20 13.20 12.12 NS 10.80 NS21-Jun-11 ºC WL 15.26 15.90 15.85 17.20 15.66 18.20 15.56 18.40 18.33 16.53
6-Dec-11 ºC WL 16.75 16.70 15.99 16.18 14.97 15.70 15.10 15.01 15.37 14.7713-Jun-12 ºC WL 18.18 15.60 16.60 15.88 14.90 17.50 15.50 15.60 19.20 17.07
11-Dec-12 ºC WL 16.70 15.00 16.60 16.10 14.90 15.10 15.80 15.20 16.30 15.10
29-Apr-13 ºC WL 16.40 15.90 17.20 16.70 14.90 17.00 15.20 15.20 14.60 16.20
6-Aug-13 ºC WL 18.2 15.9 18.1 18.3 16.1 16.7 15.4 NS 19.4 NS
25-Feb-14 ºC WL 14.9 14.1 15.7 13.4 14.6 13.0 12.6 12.5 12.5 12.5
13-Aug-14 ºC WL 22.4 19.7 19.8 17.3 16.1 15.9 NS NS 21.0 NS
12-Mar-15 ºC WL 13.9 11.6 17.0 11.6 12.5 15.2 NS NS 15.9 20.7
19-Aug-15 ºC WL 17.26 17.80 18.69 16.36 15.75 19.2 NS NS 19.04 NS
18-Feb-16 ºC WL 12.80 13.90 14.20 13.40 12.50 8.5 NS NS 11.3 14.1
11-Aug-16 ºC WL 16.7 15.8 17.3 18.9 18.8 18.4 NS NS 18.3 NS
15-Feb-17 ºC WL 12.0 15.2 15.4 13.5 14.0 13.1 NS NS 11.6 NS
pH 30-Dec-03 SU 7.31 NI NA NS 6.90 7.24 NA NS NS NS NS
[Field Test]18-May-04 SU 6.31 NI NA NS 7.27 6.39 NA 7.29 7.46 7.43 7.73
30-Jun-04 SU 8.03 NI NA NS 7.74 7.11 NA 6.70 6.79 6.93 7.64 29-Dec-04 SU 6.31 NI NA NS 7.47 6.67 NA NS NS NS NS
28-Dec-06 SU 7.50 NI 6.51 NS 7.38 6.46 8.02 6.06 NS 6.52 NS
11-Jul-07 SU 6.73 NI 6.58 NS 7.65 6.72 7.42 NS NS NS NS
19-Dec-08 SU 6.26 NM 5.92 7.81 7.10 6.63 7.03 7.61 5.81 8.12 7.35
8-Jul-09 SU 6.75 NM 7.90 6.13 8.43 7.86 7.46 8.12 8.43 5.93 8.64
14-Dec-09 SU 6.82 NM 6.76 6.20 7.65 6.70 7.23 6.38 7.50 7.43 6.8623-Jun-10 SU 5.28 NM 5.45 5.90 6.98 6.11 6.69 5.52 7.35 5.71 6.92
14-Dec-10 SU Dry NM 7.09 5.92 7.61 6.12 7.20 5.67 NS 6.36 NS21-Jun-11 SU WL 6.20 5.98 6.13 7.07 6.58 7.15 6.07 7.14 6.04 7.12
6-Dec-11 SU WL 6.79 6.10 6.61 7.54 6.73 6.92 6.28 7.05 6.46 7.1713-Jun-12 SU WL 7.49 6.15 6.43 6.95 6.43 6.88 6.46 7.02 7.15 7.31
11-Dec-12 SU WL 6.48 6.15 7.47 7.38 6.25 6.92 5.79 6.99 5.99 7.60
29-Apr-13 SU WL 6.11 5.68 5.96 7.15 6.23 6.91 5.85 6.54 6.69 7.01
6-Aug-13 SU WL 6.29 7.56 5.96 7.00 6.48 6.96 7.23 NS 5.82 NS
25-Feb-14 SU WL 6.73 5.77 5.98 6.61 6.81 6.41 5.89 6.60 6.70 7.61
13-Aug-14 SU WL 6.16 6.86 6.16 7.11 6.69 6.79 NS NS 5.89 NS
12-Mar-15 SU WL 6.53 6.77 6.61 6.26 6.33 6.77 NS NS 6.50 7.49
19-Aug-15 SU WL 6.27 6.67 5.88 7.21 6.46 6.79 NS NS 5.88 NS
18-Feb-16 SU WL 6.89 6.56 6.55 6.36 6.23 5.69 NS NS 6.13 6.52
11-Aug-16 SU WL 4.55 6.17 4.83 4.67 4.66 4.84 NS NS 4.58 NS
15-Feb-17 SU WL 6.52 5.73 6.23 7.08 6.44 7.30 NS NS 6.42 NS
Oxidation-Reduction Potential 30-Dec-03 mV 257.2 NI NS NS 212.7 187.3 NS NS NS NS NS
(ORP) (Redox Potential) 18-May-04 mV 352.8 NI NS NS 158.6 173.2 NS 150.5 105.7 129.1 55.1
[Field Test]30-Jun-04 mV 275.0 NI NS NS 154.1 174.7 NS 182.8 223.0 179.4 199.7
28-Dec-06 mV 70.2 NI NS NS 72.6 75.8 NS 84.7 NS 69.3 NS
11-Jul-07 mV 281.0 NI NS NS 269.0 296.0 NS NS NS NS NS
19-Dec-08 mV 186.0 NM NS 210.0 181.0 149.0 NS 218.0 240.0 44.0 207.0
8-Jul-09 mV 104.0 NM NS 219.0 115.0 124.0 NS 144.0 146.0 160.0 159.0
14-Dec-09 mV 195.0 NM NS 138.0 175.0 92.0 NS 96.0 126.0 147.0 119.0
23-Jun-10 mV 139.6 NM NS 32.0 -15.0 52.8 NS 33.8 22.8 61.7 1.3
14-Dec-10 mV Dry NM NS 50.0 48.0 40.2 NS 42.5 NS 46.2 NS
21-Jun-11 mV WL 89.90 NS 52.8 38.1 50.8 NS 19.9 9.6 44.8 46.46-Dec-11 mV WL 119.6 NS 68.8 38.9 38.4 NS 28.1 25.0 75.1 87.0
13-Jun-12 mV WL -32.2 NS -14.3 136.0 67.5 NS -4.1 105.6 -18.1 21.811-Dec-12 mV WL 114.9 NS 158.8 105.5 98.9 NS 123.7 164.8 157.8 121.9
29-Apr-13 mV WL 78.4 NS 146.9 65.5 117.7 NS 61.3 90.0 142.3 74.3
6-Aug-13 mV WL 89.0 NS 110.6 62.3 83.7 NS 112.7 NS 101.0 NS
25-Feb-14 mV WL 102.3 NS 140.0 -44.2 137.8 NS 60.6 88.0 74.3 102.1
13-Aug-14 mV WL 76.0 NS NS NS 49.2 NS NS NS 90.4 NS
12-Mar-15 mV WL 71.8NSNSNS68.1 NS NS NS 72.2 49.6
19-Aug-15 mV WL 61.9NSNSNS22.5 NS NS NS 57.9 NS
18-Feb-16 mV WL 104.2 NS NS NS 123.5 NS NS NS 105.7 52.9
11-Aug-16 mV WL 58.5NSNSNS48.7 NS NS NS 61.9 NS
15-Feb-17 mV WL 72.6NSNSNS53.7 NS NS NS 39.6 NS
Conductivity 28-Dec-06 µS/cm 65.3 NI 104.8 NS 588.0 355.0 642.0 173.4 NS 172.2 NS
[Field Test]11-Jul-07 µS/cm 62.5 NI 122.4 NS 631.0 373.0 604.0 NS NS NS NS
19-Dec-08 µS/cm 61.0 NM 100.4 291.0 562.0 384.0 530.0 155.0 1137.0 165.0 376.0
8-Jul-09 µS/cm 17.7 NM 111.8 377.0 625.0 421.0 578.0 321.0 792.0 159.0 369.0
14-Dec-09 µS/cm 60.2 NM 83.6 304.0 564.0 373.0 540.0 374.0 527.0 109.7 382.0
23-Jun-10 µS/cm 38.0 NM 68.0 269.0 540.0 347.0 528.0 282.0 466.0 111.0 427.0
14-Dec-10 µS/cm Dry NM 114.3 229.0 355.0 294.0 589.0 236.0 NS 104.0 NS
21-Jun-11 µS/cm WL 230.0 123.5 279.0 568.0 368.0 633.0 297.0 640.0 103.0 401.0
6-Dec-11 µS/cm WL 237.0 104.3 251.0 548.0 360.0 607.0 348.0 518.0 129.0 331.0
13-Jun-12 µS/cm WL 259.0 82.7 246.0 553.0 416.0 586.0 405.0 641.0 122.0 392.011-Dec-12 µS/cm WL 222.2 101.6 246.5 548.0 432.0 624.0 204.6 575.0 165.6 354.5
29-Apr-13 µS/cm WL 215.7 75.7 242.3 562.0 328.9 537.0 389.1 609.0 98.8 356.76-Aug-13 µS/cm WL 286.8 81.9 292.7 636.0 414.8 590 272.4 NS 151.2 NS
25-Feb-14 µS/cm WL 231.3 61.5 289.2 470.2 399.2 502 341.1 450.8 95.3 288.313-Aug-14 µS/cm WL 307.3 95.4 283.0 634.0 452.4 591 NS NS 135.2 NS
12-Mar-15 µS/cm WL 123.4 36.9 222.8 482.9 323.5 553 NS NS 114.2 447.9
19-Aug-15 µS/cm WL 28.4 13.4 215.0 565.0 386.0 556 NS NS 112.0 NS
18-Feb-16 µS/cm WL 250.0 88.7 220.8 547.0 311.6 380 NS NS 95.7 293.9
11-Aug-16 µS/cm WL 287.1 79.9 232.0 670.0 434.4 704 NS NS 123.7 NS
15-Feb-17 µS/cm WL 239.0 63.6 196.7 498.6 344.6 540 NS NS 112.4 NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 1 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ferrous Iron (Fe2+)30-Dec-030.1mg/LNDNINSNSNDNDNSNSNSNSNS
[Field Test] 18-May-04 0.1 mg/L ND NI NS NS ND0.5NSNDNDNDND30-Jun-04 0.1 mg/L ND NI NS NS ND ND NS ND ND ND NS
28-Dec-06 0.1 mg/L 0.0 NI NS NS 0.0 0.0 NS 0.0 NS 0.0 NS
11-Jul-07 0.1 mg/L 0.2 NI NS NS 0.1 0.0 NS NS NS NS NS
19-Dec-08 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 0.0 0.0 0.0 0.08-Jul-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 1.8 0.0 0.0 0.0
14-Dec-09 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 2.0 0.0 0.0 0.023-Jun-10 0.1 mg/L 0.0 NM NS 0.0 0.0 0.0 NS 4.1 0.0 0.0 0.0
14-Dec-10 0.1 mg/L Dry NM NS 0.0 0.0 0.0 NS 1.1 NS 0.0 NS21-Jun-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 0.1 mg/L WL 0.0 NS NS NS NS NS NS NS NS NS
11-Dec-12 NR NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 3.5 0.0 0.0 0.0
6-Aug-13 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 1.0 NS 0.75 NS
25-Feb-14 NR mg/L WL 0.0 NS 0.0 0.0 0.0 NS 2.0 0.0 1.0 0.0
13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 0.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.5 0.0
19-Aug-15 1.1 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 1.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 1.0 0.0
11-Aug-16 1.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.5 NS
15-Feb-17 1.1 mg/L WL 0.0 NS NS NS 0.0 NS NS NS 0.0 NS
Dissolved Carbon Dioxide 11-Jul-07 mg/L 60 NI NS NS 50 100 NS NS NS NS NS[Field Test]19-Dec-08 mg/L 30 NM NS 60 25 102 NS 40 35 35 30
8-Jul-09 mg/L 28 NM NS 120 50 170 NS 175 40 116 40
14-Dec-09 mg/L 40 NM NS 130 50 50 NS 235 30 70 60
23-Jun-10 mg/L 40 NM NS 160 65 140 NS 300 60 90 30
14-Dec-10 mg/L Dry NM NS 135 60 136 NS 435 NS 50 NS
21-Jun-11 NS WL NS NS NS NS NS NS NS NS NS NS6-Dec-11 NS WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL 60 NS NS NS NS NS NS NS NS NS11-Dec-12 NS WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/LWL65NS553570NS856515556-Aug-13 mg/L WL 50 NS 120 55 115 NS 155 NS 45 NS
25-Feb-14 mg/L WL 55 NS 95 60 85 NS 95 50 30 55
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 mg/LWL45NSNSNS50NSNSNS35 20
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 mg/L WL 55 NS NS NS 45 NS NS NS 105 85
11-Aug-16 mg/L WL 70 NS NS NS 75 NS NS NS 90 NS
15-Feb-17 mg/L WL 35 NS NS NS 105 NS NS NS 20 NS
Dissolved Oxygen (DO) 30-Dec-03 0.01 mg/L 9.49 NI NS NS 24.19 15.31 NS NS NS NS NS
[Field Test]18-May-04 0.01 mg/L 7.15 NI NS NS 11.77 1.15 NS 3.48 19.25 2.24 10.70
30-Jun-04 0.01 mg/L -NI NS NS --NS 12.71 9.20 3.59 4.37
28-Dec-06 0.01 mg/L 10.30 NI NS NS 3.18 7.99 NS 1.62 NS 5.11 NS
11-Jul-07 0.01 mg/L 8.20 NI NS NS 3.70 3.60 NS NS NS NS NS
19-Dec-08 0.01 mg/L 2.86 NM NS 4.38 3.56 1.55 NS 1.22 NS NS 8.10
8-Jul-09 0.01 mg/L 2.78 NM NS 1.98 0.88 0.48 NS 0.54 4.51 0.91 7.76
14-Dec-09 0.01 mg/L 1.34 NM NS 4.50 3.46 2.96 NS 0.57 NS 1.89 NS
23-Jun-10 0.01 mg/L 4.09 NM NS 3.35 3.49 2.89 NS 4.76 7.98 1.56 6.06
14-Dec-10 0.01 mg/L Dry NM NS 8.18 4.55 2.97 NS 1.60 NS 5.85 NS
21-Jun-11 0.01 mg/L WL 7.57 NS 3.94 2.68 3.49 NS 1.55 9.12 2.63 6.20
6-Dec-11 0.01 mg/L WL 3.82 NS 6.24 3.13 2.01 NS 1.50 8.50 1.79 8.0813-Jun-12 0.01 mg/L WL 13.78 NS 16.46 12.22 11.31 NS 12.57 12.69 13.09 16.32
11-Dec-12 0.01 mg/L WL 3.51 NS 3.38 3.17 6.21 NS 0.86 8.72 1.53 7.9329-Apr-13 0.01 mg/L WL 3.51 NS 1.27 2.75 1.87 NS 0.98 9.04 2.01 6.68
6-Aug-13 0.01 mg/L WL 2.56 NS 1.26 2.08 1.33 NS 2.43 NS 1.38 NS25-Feb-14 0.01 mg/L WL 3.90 NS 2.11 1.42 1.42 NS 1.69 8.33 1.88 7.12
13-Aug-14 0.01 mg/L WL 3.96 NS NS NS 4.14 NS NS NS 2.22 NS
12-Mar-15 0.01 mg/L WL 3.62 NS NS NS 1.24 NS NS NS 0.74 6.17
19-Aug-15 0.01 mg/L WL 5.29 NS NS NS 2.46 NS NS NS 2.74 NS
18-Feb-16 0.01 mg/L WL 3.51 NS NS NS 2.59 NS NS NS 2.54 7.07
11-Aug-16 0.01 mg/L WL 3.60 NS NS NS 1.45 NS NS NS 1.75 NS
15-Feb-17 0.01 mg/L WL 5.19 NS NS NS 3.80 NS NS NS 5.15 NS
Dissolved Hydrogen 19-Dec-08 0.600 nM 0.920 NM NS 1.300 2.500 1.300 NS 1.100 NS 1.1 NS
8-Jul-09 1.600 nM NS(dry) NM NS 1.100 2.100 1.400 NS 1.900 4.200 4.900 NS(dry)
14-Dec-09 0.600 nM 1.000 NM NS 1.100 3.000 1.000 NS 0.880 2.500 0.750 NS(dry)
23-Jun-10 0.600 nM 4.400 NM NS 4.500 5.600 3.700 NS 4.000 9.100 4.000 NS(dry)
14-Dec-10 0.600 nM Dry NM NS 0.800 1.500 1.000 NS 1.000 NS 0.620 NS(dry)
21-Jun-11 0.600 nM WL 1.30 NS 1.400 2.900 1.400 NS 1.100 3.800 1.100 NS(dry)
6-Dec-11 0.60 nM WL 2.4 NS 3.6 5.4 5.6 NS 5.3 5.2 3.4 NS(dry)
13-Jun-12 0.60 nM WL 0.81 NS 2.7 4.7 3.8 NS 2.8 3.5 0.83 NS(dry)
11-Dec-12 0.60 nM WL 0.53 J NS 0.46 J 3.0 0.6 NS 0.056 J 0.53 J 0.22 J NS
29-Apr-13 0.60 nM WL 0.38 J NS 0.41 J 1.9 NS NS 0.37 J 1.3 0.39 J 0.42 J
6-Aug-13 0.60 nM WL 0.84 NS 0.98 0.83 0.79 NS 1.0 NS 0.84 NS
25-Feb-14 0.60 nM WL 0.65 NS 0.92 0.77 0.86 NS 1.1 0.81 0.70 0.81
13-Aug-14 0.60 nM WL 1.3 NS NS NS 1.2 NS NS NS 1.1 NS12-Mar-15 0.60 nM WL 1.5 NS NS NS -NS NS NS 1.2 1.5
30-Apr-15 0.60 nM WL NS NS NS NS 1.5 NS NS NS NS NS19-Aug-15 0.60 nM WL 1.6 NS NS NS 2.0 NS NS NS 1.7 NS
18-Feb-16 0.60 nM WL 2.9 NS NS NS 10.0 NS NS NS 2.2 NS11-Aug-16 0.60 nM WL 2.2 NS NS NS 2.1 NS NS NS 2.2 NS
15-Feb-17 0.60 nM WL 2.2 NS NS NS 2.1 NS NS NS 2.2 NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 2 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Chloride 30-Dec-03 1 mg/L 3 NI NS NS 17 24 NS NS NS NS NS
18-May-04 1 mg/L 3.2 NI NS NS 26 26 NS 6.3 16 6.2 9.1
30-Jun-04 1 mg/L 2.5 NI NS NS 28 26 NS 8.1 15 7.8 4.3
28-Dec-06 5 mg/L 1.8 NI NS NS 22 18 NS 4.7 NS 6.6 NS
11-Jul-07 5 mg/L 0.66 (2.6) NI NS NS 17 (34) 15 (29)NS NS NS NS NS
19-Dec-08 5 mg/L 5.7 NM NS 37.0 39.4 36.4 NS 16.0 10.8 12.6 6.2
8-Jul-09 5 mg/L 6.8 NM NS 46.8 39.1 38.6 NS 23.1 11.3 7.7 28.4
14-Dec-09 5.0 mg/L ND NM NS 36.4 38.8 37.6 NS 33.0 11.5 5.5 6.2
23-Jun-10 5.0 mg/L 7.95 NM ND 37.4 40.0 39.7 97.9 17.6 13.4 5.97 6.514-Dec-10 5.0 mg/L Dry NM 5.1 38.4 44.5 39.6 108.0 29.1 NS 16.40 NS
NC-2L 250,000 ug/L 21-Jun-11 5.0 mg/L WL 8.6 ND 35.8 45.3 41.4 106.0 23.3 13.5 6.60 6.076-Dec-11 5.0 nM WL 9.34 ND 28.6 49.2 39.2 110.0 47.8 22.5 13.9 6.2
13-Jun-12 5.0 mg/L WL 9.41 4.54 29.4 49.3 46.4 109.0 44.4 26.7 7.77 6.3611-Dec-12 1.0 mg/L WL 8.57 5.22 30.8 50.6 46.6 107.0 40.1 25.7 15.6 6.26
29-Apr-13 1.0 mg/L WL 9.55 4.12 30.0 49.8 22.3 122.0 44.9 31.1 5.84 6.08
6-Aug-13 1.0 mg/L WL 7.59 5.18 25.7 50.1 48.7 107.0 24.8 NS 7.05 NS
25-Feb-14 1.0 mg/L WL 9.22 5.51 33.2 60.3 57.4 120.0 26.9 29.2 5.39 6.53
13-Aug-14 1.0 mg/L WL 8.03 4.07 21.3 97.6 43.4 106.0 NS NS 5.61 NS
12-Mar-15 1.0 mg/L WL 8.84 43.5 20.7 51.7 42.6 121.0 NS NS 5.81 5.58
19-Aug-15 1.0 mg/L WL 9.44 5.16 23.2 51.5 48.5 111.0 NS NS 6.35 NS
18-Feb-16 1.0 mg/L WL 17.20 4.60 20.6 69.5 49.7 153.0 NS NS 6.28 5.65
11-Aug-161.0mg/LWLNSNSNSNSNSNSNSNS7.08NS
15-Feb-17 1.0 mg/L WL 10.90 4.97 29.3 59.1 49.2 142.0 NS NS 6.83 NS
Nitrate 30-Dec-03 0.10 mg/L 0.23 NI NS NS ND ND NS NS NS NS NS
18-May-04 0.10 mg/L 0.21 NI NS NS ND ND NS ND 1.10 0.14 ND
30-Jun-04 0.10 mg/L 0.15 NI NS NS ND ND NS ND 0.95 0.20 ND
28-Dec-06 100.0 mg/L 0.15 NI NS NS 0.51 0.33 NS 0.36 NS 0.43 NS
11-Jul-07 100.0 mg/L 0.14 NI NS NS 0.111 0.031 NS NS NS NS NS
19-Dec-08 100.0 mg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 200.0 mg/L ND NM NS ND ND ND NS ND ND ND 0.30
14-Dec-09 0.10 mg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 0.10 mg/L ND NM NS ND ND ND NS ND ND 183 107
14-Dec-10 0.10 mg/L Dry NM NS ND ND ND NS ND NS ND NS21-Jun-11 0.10 mg/L WL ND NS ND ND ND NS ND ND 0.146 ND
6-Dec-11 0.10 mg/L WL ND NS ND ND ND NS ND ND ND ND13-Jun-12 0.10 mg/L WL 0.181 NS 0.0743 ND ND NS ND 0.0798 0.162 0.251
11-Dec-12 10.00 mg/L WL 0.115 J NS 0.0655 J ND 0.0326 J NS 0.0557 J 0.022 ND 0.192 J
29-Apr-13 0.02 mg/L WL 0.0938 NS 0.0280 ND ND NS ND 0.0298 0.0851 0.141
6-Aug-13 10.00 mg/L WL 0.0999 J NS ND ND ND NS ND NS ND NS
25-Feb-14 10.00 mg/L WL NS NS ND ND ND ND ND ND ND 0.417 J
13-Aug-14 10.00 mg/L WL 0.144 J NS NS NS ND NS NS NS ND NS
12-Mar-15 10.00 mg/L WL 0.134 J NS NS NS 0.0224 J NS NS NS ND 0.229 J
19-Aug-15 10.00 mg/L WL 0.186 J NS NS NS ND NS NS NS ND NS
18-Feb-16 10.00 mg/L WL 0.179 J NS NS NS 0.0373 J NS NS NS ND 0.122 J
11-Aug-16 10.00 mg/L WL 0.196 J NS NS NS 0.0211 J NS NS NS 0.0126 J NS
15-Feb-17 10.00 mg/L WL 0.22 J NS NS NS 0.0875 J NS NS NS 0.0116 J NS
Nitrite 28-Dec-06 mg/L <0.100 NI NS NS <0.100 <0.100 NS <0.100 NS <0.100 NS
11-Jul-07 mg/L <0.1 NI NS NS <0.1 <0.1 NS NS NS NS NS
14-Dec-10 mg/L DryNMNSNSNSNSNSNSNSNSNS
21-Jun-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 mg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Aug-14 mg/L WL NS NS NS NS NS NS NS NS NS NS12-Mar-15 mg/LWLNSNSNSNSNSNSNSNSNSNS
19-Aug-15 mg/L WL NS NS NS NS NS NS NS NS NS NS18-Feb-16 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 mg/L WL NS NS NS NS NS NS NS NS NS NS15-Feb-17 mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 3 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Sulfate 30-Dec-03 2.0 mg/L 4.0 NI NS NS 17 2.7 NS NS NS NS NS
18-May-04 2.0 mg/L 3.3 NI NS NS 40 2.8 NS 21 120 5.6 13
30-Jun-04 2.0 mg/L ND NI NS NS 29 ND NS 5.5 180 4.7 12
28-Dec-06 5 mg/L 0.03 NI NS NS 10 4.6 NS 5.2 NS 12 NS
11-Jul-07 5 mg/L 1.6 NI NS NS 13 2.2 NS NS NS NS NS
19-Dec-08 5 mg/L 11.2 NM NS 9.6 9 ND NS 5.3 191 16.1 18.3
8-Jul-09 5 mg/L 1140 NM NS 8.4 9.3 ND NS 5.2 161 8.4 39.2
14-Dec-09 5 mg/L ND NM NS 6.9 7.3 ND NS ND 79.5 6.5 49.7
23-Jun-10 5 mg/L 5.16 NM 14.8 7.18 9.14 ND ND ND ND 25.1 ND14-Dec-10 5 mg/L Dry NM 14.5 9.21 9.7 ND ND 5.38 NS 10.80 NS
21-Jun-11 5 mg/L WL 24.4 11.4 7.49 7.74 ND ND ND 91.9 ND NDNC-2L 250,000 ug/L 6-Dec-11 5 mg/L WL ND NS ND ND ND NS ND 31.4 11.80 52.9
13-Jun-12 5 mg/L WL 25.4 13.7 8.14 8.4 2.79 3.04 4.70 24.5 5.38 83.111-Dec-12 2 mg/L WL 28.0 J 14.8 J 9.12 J 10.1 J 4.42 J 2.90 J 3.16 J 36.0 7.91 J 78.8
29-Apr-13 250 mg/L WL 26.1 J 12.3 J 9.15 J 17.1 J 2.73 J 3.20 J 5.23 J 57.0 J 4.61 J 73.8 J
6-Aug-13 250 mg/L WL 25.3 J 7.37 J 7.83 J 11.7 J 2.76 J 3.32 J 4.29 J NS 5.07 J NS
25-Feb-14 250 mg/L WL 28.9 J 11.2 J 8.13 J 9.55 J 2.59 J 4.62 J 3.59 J 10.4 J 33.8 J 4.56 J
13-Aug-14 250 mg/L WL 31.9 J 9.37 J 7.91 J 11.6 J 2.45 J 2.78 J NS NS 4.46 J NS
12-Mar-15 250 mg/L WL 32.6 J 12.1 J 8.04 J 8.34 J 3.34 J 3.33 J NS NS 4.81 J 83.4 J
19-Aug-15 250 mg/L WL 42.9 J 102 J 8.11 J 10.4 J 2.89 J 3.21 J NS NS 4.93 J NS
18-Feb-16 250 mg/L WL 39.9 J 112 J 7.96 J 10.3 J 3.83 J 3.31 NS NS 4.84 J 54.7 J
11-Aug-16 250 mg/L WL NS NS NS NS NS NS NS NS 5.33 J NS
15-Feb-17 250 mg/L WL 47.1 J 11.2 J 7.86 J 7.94 J 3.55 J 3.26 NS NS 5.31 J NS
Sulfide 30-Dec-03 1.0 mg/L ND NI NS NS 5.0 ND NS NS NS NS NS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
19-Dec-08 1000 µg/L 259 J NM ND 150 J ND 141 J ND ND ND ND ND
8-Jul-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-09 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
23-Jun-10 1000 µg/L ND NM ND ND ND ND ND ND ND ND ND
14-Dec-10 1000 µg/L Dry NM ND ND ND ND ND ND NS ND NS
21-Jun-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Dec-11 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS13-Jun-12 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 1000 µg/L WL ND ND ND ND 117 J NS NS NS NS NS29-Apr-13 1000 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Aug-13 1000 µg/L WL ND ND ND ND ND ND ND NS ND NS25-Feb-14 1000 µg/L WL ND ND ND ND ND ND ND ND ND ND
13-Aug-14 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
19-Aug-15 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
18-Feb-16 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
11-Aug-16 1000 mg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 1000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Hydrogen Sulfide 30-Dec-031.0mg/LNDNINSNS21NDNSNSNSNSNS
18-May-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 1.0 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 1.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
14-Dec-10 NR mg/L Dry NM NS NS NS NS NS NS NS NS NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1.0 mg/L WL NS NS NS NS NS NS NS NS NS NS
11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Aug-13 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
25-Feb-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS13-Aug-14 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
12-Mar-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS19-Aug-15 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 NR mg/L WL NS NS NS NS NS NS NS NS NS NS11-Aug-16 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 4 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Organic Carbon (TOC) 11-Jul-07 1 mg/L 0.48 NI NS NS 3.2 1.9 NS NS NS NS NS
19-Dec-08 1 mg/L 6.3 NM NS 48 24.7 21.1 NS 21.2 22.8 11.4 19.1
8-Jul-09 1 mg/L 28.1 NM NS 6.6 5.9 6.2 NS 3.4 5.7 4.2 4.4
14-Dec-09 1 mg/L 3.0 NM NS 32.4 48.2 ND NS 11.5 5.0 2.9 3.8
23-Jun-10 1 mg/L 3.7 NM NS 3.16 5.8 6.07 NS 2.91 5.96 2.82 3.61
14-Dec-10 1 mg/L Dry NM NS 23.7 7.52 7.77 NS 23 NS 5.01 NS
21-Jun-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-121mg/LWL3.71NSNSNSNSNSNSNSNSNS11-Dec-12 NR mg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRmg/LWLNSNSNSNSNSNSNSNSNSNS6-Aug-13 1 mg/L WL 4.68 NS 7.42 8.93 9.63 NS 12.4 NS 4.08 NS
25-Feb-14 1 mg/L WL NS NS 8.62 20.4 19.9 NS 33.7 26.2 9.50 8.0313-Aug-141mg/LWL4.55NSNSNS8.34NSNSNS4.33NS
12-Mar-15 1 mg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-151mg/LWLNSNSNSNSNSNSNSNSNSNS
18-Feb-161mg/LWLNSNSNSNSNSNSNSNSNSNS
11-Aug-161mg/LWLNSNSNSNSNSNSNSNSNSNS
15-Feb-17 1 mg/L WL ND NS NS NS 1.7 NS NS NS 0.87 J NS
Alkalinity 30-Dec-03 10 mg/L 14 NI NS NS 90 130 NS NS NS NS NS
(total as CaCO3) 18-May-04 10 mg/L ND NI NS NS 210 140 NS 56 260 63 81
30-Jun-04 10 mg/L 11 NI NS NS 240 160 NS 120 280 46 130
28-Dec-06 5 mg/L 10 NI NS NS 255 133 NS 57 NS 42 NS
11-Jul-07 5 mg/L 20 NI NS NS 220 150 NS NS NS NS NS
19-Dec-08 5 mg/L 18.9 NM NS 88.2 296 163 NS 76.7 202 44.2 222
8-Jul-09 6 mg/L 16.5 NM NS 110 301 176 NS 137 278 44.0 155
14-Dec-09 5 mg/L 6.7 NM NS 82.1 253 135 NS 134 210 29.6 137
23-Jun-10 5 mg/L 7.29 NM 20.4 99.8 291 169 178.0 134 262 39.7 170
14-Dec-10 5 mg/L Dry NM 17.6 99.6 292 168 156 168 NS 39.4 NS
21-Jun-11 5 mg/L WL 100 20.8 77 269 194 156 128 288.0 42.2 153.0
6-Dec-11 5 mg/L WL 98.7 10.5 81.9 274 164 151 146 297 35.7 144
13-Jun-12 5 mg/L WL 101 13.7 87.5 271 152 149 152 309 46.2 147
11-Dec-12 5 mg/L WL 100 16.5 98.3 284 147 152 130 339 44.6 14829-Apr-13 5 mg/L WL 99.3 13.8 97.3 293 156 153 180 339 46.2 143
6-Aug-13 5 mg/L WL 102 14.3 99.1 148 86.8 159 123 NS 43.3 NS25-Feb-14 5 mg/L WL 98 15.8 123 298 178 153 145 303 164 3.87
13-Aug-14 5 mg/L WL 103 14.3 93.8 301 187 164 NS NS 49.8 NS12-Mar-15 5 mg/L WL 99.7 14.7 88.3 306 151 164 NS NS 39.5 139
19-Aug-15 5 mg/L WL 102 19.6 88.2 294 180 164 NS NS 46.9 NS
18-Feb-16 5 mg/L WL 108 4.35 J 89.8 308 141 168 NS NS 49.6 150
11-Aug-165mg/LWLNSNSNSNSNSNSNSNS51.6NS
15-Feb-17 5 mg/L WL 115 16 92.8 300 168 183 NS NS 48.2 NS
Ethane 30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-0820.0µg/LNDNMNSNDNDNDNSNDNDNDND
8-Jul-0910.0µg/LNDNMNSNDNDNDNSNDNDNDND
14-Dec-0910.0µg/LNDNMNSNDNDNDNSNDNDNDND
23-Jun-1010.0µg/LNDNMNSNDNDNDNSNDNDNDND
14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-1210.0µg/LWLNSNSNSNSNSNSNSNSNSNS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-146.2µg/LWLNSNSNDNDNDNSNDNDNDND13-Aug-146.2µg/LWLNDNSNSNSNDNSNSNSNDNS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS19-Aug-156.2µg/LWLNSNSNSNSNSNSNSNSNSNS
18-Feb-166.2µg/LWLNSNSNSNSNSNSNSNSNSNS11-Aug-166.2µg/LWLNSNSNSNSNSNSNSNSNSNS
15-Feb-17 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 5 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Ethylene (Ethene)30-Dec-03 0.001 mg/L ND NI NS NS ND ND NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
30-Jun-04 0.001 mg/L ND NI NS NS ND ND NS ND ND ND ND
28-Dec-06 20.0 mg/L ND NI NS NS ND ND NS ND NS ND NS
11-Jul-07 20.0 mg/L ND NI NS NS ND ND NS NS NS NS NS
19-Dec-0820.0µg/LNDNMNSNDNDNDNSNDNDNDND
8-Jul-0910.0µg/LNDNMNSNDNDNDNSNDNDNDND
14-Dec-0910.0µg/LNDNMNSNDNDNDNSNDNDNDND
23-Jun-1011.0µg/LNDNMNSNDNDNDNSNDNDNDND14-Dec-10 10.0 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-1210.0µg/LWLNSNSNSNSNSNSNSNSNSNS11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 6.2 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-146.2µg/LWLNSNSNDNDNDNSNDNDNDND
13-Aug-146.2µg/LWLNDNSNSNSNDNSNSNSNDNS
12-Mar-15 6.2 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-156.2µg/LWLNSNSNSNSNSNSNSNSNSNS
18-Feb-166.2µg/LWLNSNSNSNSNSNSNSNSNSNS
11-Aug-166.2µg/LWLNSNSNSNSNSNSNSNSNSNS
15-Feb-17 6.2 µg/L WL ND NS NS NS ND NS NS NS ND NS
Methane 30-Dec-03 0.001 mg/L ND NI NS NS 1.8 0.1 NS NS NS NS NS
18-May-04 0.001 mg/L ND NI NS NS 1.50 0.12 NS 0.09 0.46 0.004 ND
30-Jun-04 0.001 mg/L ND NI NS NS 0.66 0.06 NS 0.26 ND ND ND
28-Dec-06 10.0 mg/L 0.01 NI NS NS 0.173 0.044 NS 0.021 NS 0.001 NS
11-Jul-07 10.0 mg/L 0.001 NI NS NS 0.189 0.008 NS NS NS NS NS
19-Dec-08 10.0 mg/L ND NM NS 0.0054 J 0.162 0.102 NS 0.0164 ND ND ND
8-Jul-09 10.0 mg/L ND NM NS 0.0202 0.088 0.128 NS 0.226 ND ND ND
14-Dec-09 10.0 mg/L ND NM NS 0.0083 J 0.0205 0.0648 NS 1.130 ND ND ND
23-Jun-10 0.010 mg/L 0.0018 B NM NS 0.0117 B 0.064 0.101 NS 0.415 0.002 B 0.0012 B 0.0013 B
14-Dec-10 0.010 mg/L Dry NM NS 0.0025 J 0.155 0.102 NS 0.510 NS ND NS21-Jun-11 0.010 mg/L WL 0.0016 J NS 0.099 J 0.103 0.108 NS 0.770 0.0017 J 0.0014 J 0.0017 J
6-Dec-11 0.010 mg/L WL ND NS 0.009 J 0.032 0.086 NS 0.376 ND ND ND13-Jun-12 0.010 mg/L WL 0.0011 J NS 0.0062 J 0.0524 0.0698 NS 0.157 0.0017 J 0.0015 J 0.0013 J
11-Dec-12 0.01 mg/L WL ND NS 0.0036 0.0825 0.0506 NS 0.183 ND ND ND29-Apr-13 0.01 mg/L WL ND NS 0.0180 0.0737 0.0923 NS 1.290 ND ND ND
6-Aug-13 0.0066 mg/L WL ND NS 0.0229 0.0590 0.113 NS 0.284 NS 0.060 NS
25-Feb-14 0.0066 mg/L WL ND NS 0.0170 0.0703 0.0263 NS 0.498 ND ND ND
13-Aug-14 0.0066 mg/L WL ND NS NS NS 0.108 NS NS NS 0.339 NS
12-Mar-15 0.0066 mg/L WL ND NS NS NS 0.0188 NS NS NS 0.330 0.0119
19-Aug-15 0.0066 mg/L WL 0.89 J NS NS NS 0.0398 NS NS NS 0.340 NS
18-Feb-16 0.0066 mg/L WL 0.0018 J NS NS NS 0.0218 NS NS NS 0.512 0.0019 J
11-Aug-16 0.0066 mg/L WL 0.0025 J NS NS NS 0.0676 NS NS NS 0.409 NS
15-Feb-17 0.0100 mg/L WL ND NS NS NS 0.0949 NS NS NS 0.336 NS
Pyruvic Acid 28-Dec-06 100 µg/L ND NI NS ND ND ND NS ND ND ND NS
19-Dec-08 100 µg/L ND NM NS ND ND ND NS ND ND ND ND
8-Jul-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 10000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 10000 µg/L ND NM NS ND ND ND NS ND ND ND 2800 J
14-Dec-10 10000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 10000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 10000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 10000 µg/L WL NS NS ND ND ND NS ND ND ND ND13-Aug-14 10000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS19-Aug-15 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS11-Aug-16 10000 µg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 10000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 6 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Lactic Acid 28-Dec-06 1000 µg/L ND NI NS ND ND NS NS ND ND ND NS
19-Dec-08 1000 µg/L ND NM NS ND ND 4300 NS ND ND ND ND
8-Jul-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 25000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 25000 µg/L ND NM NS ND ND ND NS ND ND 1900 J ND
14-Dec-10 25000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 25000 µg/L WL ND NS NS NS NS NS NS NS NS NS11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS6-Aug-13 25000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 25000 µg/L WL NS NS ND ND ND NS ND ND ND ND13-Aug-14 25000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 25000 µg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 25000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Acetic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND NS ND NS
19-Dec-08 1000 µg/L ND NM NS 1200 ND ND NS ND 1000 ND 1600
8-Jul-09 1000 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-10 1000 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS15-Feb-17 5000 µg/L WL ND NS NS NS 710 J NS NS NS 950.00 J NS
Propionic Acid 28-Dec-06 1000 µg/L ND NI NS NS ND NS NS NS ND ND NS
19-Dec-08 1000 µg/L ND NM NS 9900 ND 64200 NS 1300 ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS 800 J ND ND NS ND 3800 ND ND
14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Butyric Acid 28-Dec-06 1000 µg/L ND NI NS NS ND ND NS ND ND ND NS19-Dec-08 1000 µg/L ND NM NS 1500 ND ND NS ND ND ND ND
8-Jul-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND14-Dec-09 1000 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 1000 µg/L ND NM NS ND 600 J ND NS 1000 J ND ND ND14-Dec-10 1000 µg/L Dry NM NS ND ND ND NS ND NS ND NS
21-Jun-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 1000 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 NR µg/L WL NS NS NS NS NS NS NS NS NS NS
29-Apr-13NRµg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 5000 µg/L WL NS NS ND ND ND NS ND NS ND NS
25-Feb-14 5000 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
12-Mar-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
19-Aug-15 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 5000 µg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 5000 µg/L WL ND NS NS NS ND NS NS NS ND NS
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 7 of 8 Joyce Engineering
APPENDIX G: HISTORICAL MNA PARAMETER DATA
Sample
Analyte Date RL Units MW-1A MW-7 MW-2 MW-3R MW-4R MW-5R MW-6R NES-1S NES-1D NES-2S NES-2D
Total Volatile Fatty Acids 19-Dec-08 µg/L ND NM NS 12600 ND 68500 NS 1300 1000 ND ND
(sum of above 5 parameters) 8-Jul-09 µg/L ND NM NS 700 J ND ND NS ND ND 700 J ND
14-Dec-09 µg/L ND NM NS ND ND ND NS ND ND ND ND
23-Jun-10 µg/L ND NM NS 800 J 600 J ND NS 1000 J 3800 1900 J 2800 J
14-Dec-10 µg/L Dry NM NS ND 600 J 2400 NS ND NS ND NS
21-Jun-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
6-Dec-11 µg/L WL NS NS NS NS NS NS NS NS NS NS
13-Jun-12 µg/L WL ND NS NS NS NS NS NS NS NS NS
11-Dec-12 µg/L WL NS NS NS NS NS NS NS NS NS NS29-Apr-13 µg/LWLNSNSNSNSNSNSNSNSNSNS
6-Aug-13 µg/L WL NS NS ND ND ND NS ND NS ND NS25-Feb-14 µg/L WL NS NS ND ND ND NS ND ND ND ND
13-Aug-14 µg/L WL ND NS NS NS ND NS NS NS ND NS12-Mar-15 µg/LWLNSNSNSNSNSNSNSNSNSNS
19-Aug-15 µg/L WL NS NS NS NS NS NS NS NS NS NS
18-Feb-16 µg/L WL NS NS NS NS NS NS NS NS NS NS
11-Aug-16 µg/L WL NS NS NS NS NS NS NS NS NS NS
15-Feb-17 µg/L WL NS NS NS NS 710 J NS NS NS 950 J NS
BTEX 28-Dec-06 µg/L ND NI ND ND ND NS ND ND ND ND NS
(sum of benzene, toluene,19-Dec-08 µg/L ND NM ND ND ND 0.40 J ND ND ND ND ND
ethylbenzene, & xylenes)8-Jul-09 µg/L ND NM ND ND ND 0.54 J ND 0.60 J ND ND ND
14-Dec-09 µg/L ND NM ND ND ND 0.37 J ND NS J NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 0.42 J ND ND ND ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 0.53 J NS ND NS
21-Jun-11 µg/L WL ND ND ND ND ND ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND ND ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 0.41 J ND NS NS NS NS
29-Apr-13 µg/L WL ND ND ND ND 0.33 J ND NS NS NS NS
6-Aug-13 µg/L WL ND ND ND ND 0.40 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 0.40 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 0.41 J ND NS NS ND NS
12-Mar-15 µg/LWLNDNDNDNDNDNDNSNSNDND19-Aug-15 µg/L WL ND ND ND ND 0.35 J ND NS NS ND ND
18-Feb-16 µg/L WL ND ND ND ND ND ND NS NS ND ND11-Aug-16 µg/L WL ND ND ND ND ND ND NS NS ND ND
15-Feb-17 µg/L WL ND ND ND ND ND ND NS NS ND ND
DCE 28-Dec-06 µg/L ND NI ND NS ND 6 ND 0.84 J NS ND NS
(sum of dichloroethylenes ) 11-Jul-07 µg/L ND NI ND NS ND 6.2 ND NS NS NS NS
19-Dec-08 µg/L ND NM ND ND ND ND ND ND ND ND ND
8-Jul-09 µg/L ND NM ND ND ND 7.7 ND 4.1 J 0.30 J ND ND
14-Dec-09 µg/L ND NM ND ND ND 7.4 ND NS NS NS NS
23-Jun-10 µg/L ND NM ND ND ND 13.6 ND 5.6 0.55 J ND ND
14-Dec-10 µg/L Dry NM ND ND ND ND ND 5.9 NS ND NS
21-Jun-11 µg/L WL ND ND ND ND 6.4 ND NS NS NS NS
6-Dec-11 µg/L WL ND ND ND ND 3.0 J ND NS NS NS NS
13-Jun-12 µg/L WL ND ND ND ND 4.3 J ND NS NS NS NS
11-Dec-12 µg/L WL ND ND ND ND 3.3 J ND NS NS NS NS
29-Apr-13 µg/LWLNDNDNDND4.8JNDNSNSNSNS
6-Aug-13 µg/L WL ND ND ND ND 3.6 J ND NS NS NS NS
25-Feb-14 µg/L WL ND ND ND ND 3.7 J ND NS ND ND ND
13-Aug-14 µg/L WL ND ND ND ND 2.8 J 0.39 J NS NS ND NS
12-Mar-15 µg/LWLNDNDNDND2.6JNDNSNSNDND
19-Aug-15 µg/L WL ND ND ND ND 3.1 J 0.89 J NS NS NS NS
18-Feb-16 µg/L WL ND ND ND ND 2.5 J 0.32 J NS NS NS NS
11-Aug-16 µg/L WL ND ND ND ND 2.7 J 0.5 J NS NS NS NS
15-Feb-17 µg/L WL ND ND ND ND ND ND NS NS ND ND
Notes: ND = Not detected above the laboratory detection limit.mV = millivolts.NA= Data not avaliable
NS = Not sampled for this parameter during this event.mS/cm = milliseimens/centimeter.
mg/L = milligrams per liter = parts per million.SU = standard units.
µg/L = micrograms per liter = parts per billion.ºC = degrees centigrade
Granville Co. - Oxford Landfill, Unit 1
Permit 3901-CDLF-1997 Page 8 of 8 Joyce Engineering

Appendix H

Statistical Analyses Worksheets and Summary

JOYCE Project: Oxford Landfill - Granville County
Project No: 660.1701.12
Date: February 2017
Analyte:Cobalt
Reporting
Sample Sample Sample Concentration Limit
No. Date Location (µg/L) (µg/l)
1 9/14/1994 MW-1 160 10 2.1 430
2 12/2/1994 MW-1 47 10 3.9 380
3 2/8/1995 MW-1 ND 10 7.0 200
4 3/2/1995 MW-1 ND 10 8.1 160
5 11/17/1995 MW-1 58 10 10 160
6 5/23/1996 MW-1 29 10 11 150
7 11/14/1996 MW-1 12 10 12 120
8 6/18/1997 MW-1 200 10 13 93
9 12/2/1997 MW-1 7 10 17 73
10 5/27/1998 MW-1 150 10 29 58
11 11/16/1998 MW-1 380 10 34 47
12 9/10/1999 MW-1 11 10 35 45
13 11/16/1999 MW-1 ND 10 45 35
14 5/10/2000 MW-1 ND 10 47 34
15 10/26/2000 MW-1 10 10 58 29
16 9/14/1994 MW-1A 160 10 73 17
17 12/2/1994 MW-1A ND 10 93 13
18 2/8/1995 MW-1A 45 10 120 12
19 3/2/1995 MW-1A 35 10 150 11
20 11/17/1995 MW-1A 13 10 160 10
21 5/23/1996 MW-1A ND 10 160 8.1
22 11/14/1996 MW-1A 93 10 200 7.0
23 6/18/1997 MW-1A 430 10 380 3.9
24 12/2/1997 MW-1A 34 10 430 2.1
25 5/27/1998 MW-1A 73 10
26 11/16/1998 MW-1A 120 10
27 9/10/1999 MW-1A ND 10
28 11/16/1999 MW-1A ND 10
29 5/10/2000 MW-1A ND 10
30 10/26/2000 MW-1A ND 10
31 4/18/2001 MW-1A 17 10
32 10/27/2001 MW-1A ND 10
33 6/10/2002 MW-1A ND 10
34 6/13/2002 MW-1A ND 10
35 11/19/2002 MW-1A ND 10
36 6/27/2003 MW-1A ND 10
37 12/30/2003 MW-1A ND 10
38 6/30/2004 MW-1A ND 10
39 12/29/2004 MW-1A ND 10
40 6/29/2005 MW-1A ND 10
41 12/29/2005 MW-1A ND 10
42 6/28/2006 MW-1A ND 10
43 12/28/2006 MW-1A 2.1 J 10
44 7/12/2007 MW-1A ND 10
45 7/8/2008 MW-1A 436 # 10
46 12/6/2008 MW-1A 2.5 B 10
47 7/8/2009 MW-1A 8.1 J 10
48 12/15/2009 MW-1A ND 10
49 6/23/2010 MW-1A 3.9 J 10
50 6/21/2011 MW-7 ND 10
51 6/13/2012 MW-7 ND 10
52 12/12/2012 MW-7 ND 10
53 4/29/2013 MW-7 ND 10
54 8/6/2013 MW-7 ND 10
55 2/26/2014 MW-7 ND 10
56 8/13/2014 MW-7 ND 10
57 3/12/2015 MW-7 ND 10
58 8/19/2015 MW-7 ND 10
59 2/18/2016 MW-7 ND 10
60 8/11/2016 MW-7 ND 10
61 2/15/2017 MW-7 ND 10
Number of Data: 59
Number of Truncated Data: 35
Percentage of Truncated Data: 59.3%
Nonparametric Predition Interval: 430 µg/L
Notes:
All concentrations in micrograms per liter (µg/l).
ND = Not detected (truncated).
J = Estimated concentration below the reporing limit (used in stattistical calculations).
B = Blank-qualified data (not used in statistical calculations).
# - Data rejected due to extreamly high tubidity in the samples (not used in satatistical calculations).
Concentration
(µg/l)
Sorted