7304_UpperPiedmontMSWLF_Feb2017GWMR_DIN28657_20170522

PREPARED FOR:
REPUBLIC SERVICES OF NORTH CAROLINA, LLC
D.B.A. UPPER PIEDMONT ENVIRONMENTAL
9650 OXFORD ROAD
ROUGEMOUNT, NORTH CAROLINA 27572

UPPER PIEDMONT REGIONAL LANDFILL
PERMIT NO. 73-04

FIRST SEMIANNUAL
WATER QUALITY MONITORING REPORT
OF 2017

MAY 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE ENGINEERING PROJECT NO. 00893.1701.12

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First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Upper Piedmont Regional Landfill, Permit No. 73-04 May 2017

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EXECUTIVE SUMMARY

This report presents the results of the first semiannual water quality monitoring event of 2017
conducted at the Upper Piedmont Regional Landfill on February 1, 2017. Samples were
collected from the compliance monitoring well network, surface water locations, and the leachate
collection system. The analytical results from the February 1, 2017, monitoring event have been
provided by Pace Analytical Services, LLC of Norcross, Georgia.

During the February 2017 water quality monitoring event, five NC Appendix I inorganic
constituents (arsenic, barium, cobalt, copper, and zinc) and two indicator parameters (iron and
manganese) were reported at quantified concentrations above the Solid Waste Section Reporting
Limits (SWSLs) in samples from one or more downgradient monitoring wells. No other NC
Appendix I inorganic or organic constituents were detected above SWSLs in groundwater during
the February 1, 2017, monitoring event.

The indicator parameters, iron and manganese, were analyzed per a NCDEQ request in a letter
dated September 28, 2007. The concentrations detected in one or more downgradient wells
during the February 1, 2017 sampling event were above their respective SWSLs and NC2L
Standards. Iron and manganese are common, naturally-occurring, inorganic constituents and are
not NC Appendix I constituents. Data from the February 1, 2017, event are generally consistent
with historical values. No further action is required for detections of iron and manganese.

Cobalt was detected above the Solid Waste Section Groundwater Protection Standards (GWPS)
in downgradient monitoring well GW-8. Cobalt is a common, naturally-occurring element in
soils in this region, and these results are generally consistent with historical values. The
proposed background value for cobalt is 31.5µg/L based on the Alternate Source Demonstration
(ASD) for Cobalt, Iron, and Manganese, dated December 2016. In accordance with 15A NCAC
13B.1634.(g).(5), the submittal requested that background concentrations be considered the
applicable Groundwater Protection Standard (GPS) for cobalt for compliance sampling events at
this facility. The ASD submittal is currently under review at NCDEQ.

Three inorganic constituents were detected in surface water monitoring points at quantified
concentrations above the SWSL’s. No NC Appendix I constituents were detected above their
relevant NC 2B surface water standard in surface water monitoring points during the first
semiannual monitoring event of 2017.

Based on the results summarized herein, we recommend that Republic Services of NC, LLC
continue monitoring the uppermost aquifer beneath the Upper Piedmont Regional Landfill in
accordance with the requirements for Detection Monitoring Program as outlined in Title 15A
NCAC 13B .1633.

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First Semiannual Water Quality Monitoring Report of 2017 Joyce Engineering
Upper Piedmont Regional Landfill, Permit No. 73-04 May 2017

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First Semiannual Water Quality Monitoring Report of 2017
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1  Site Description and Background ................................................................................ 1 
1.2 Compliance Monitoring History .................................................................................. 1 
1.3 Hydrogeologic Setting ................................................................................................... 1 
2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION ......................2 
2.1 Visual Inspection Program........................................................................................... 2 
2.2 Well Network and Groundwater Elevation Measurements...................................... 3 
2.3 February 2017 Monitoring Event ................................................................................ 4 
2.4 Laboratory Analysis Program ..................................................................................... 5 
2.5 February 2017 Sampling Results ................................................................................. 5 
3.0 LABORATORY AND FIELD QA/QC ............................................................................5 
4.0 DATA EVALUTION .........................................................................................................6 
4.1 Comparisons to Groundwater and Surface Water Standards ................................. 6 
4.1.1   Groundwater Standard Exceedances ........................................................................ 6 
4.1.2   Surface Water Standard Exceedances ...................................................................... 7 
4.2 Statistical Evaluations .................................................................................................. 7 
5.0 CONCLUSIONS ................................................................................................................7 
6.0 REFERENCES ...................................................................................................................8 

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First Semiannual Water Quality Monitoring Report of 2017
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina

TABLE OF CONTENTS CONTINUED

Tables

Table 1 Historical Groundwater Elevations
Table 2 Estimated Hydraulic Gradients and Average Linear Velocities
Table 3 Well Construction Information
Table 4 Detections by Monitoring Locations
Table 5 Exceedances by Monitoring Locations
Table 6 Field Parameters by Location

Drawing

Drawing 1 Potentiometric Surface Map, February 1, 2017

Appendices

Appendix A Historical Tables
Table 7 Historically Detected Constituents/Analytes in Groundwater
Table 8 Historically Detected Constituents/Analytes in Surface Water
Table 9 Historically Detected Constituents/Analytes in Leachate

Appendix B Field Sampling Logs
Appendix C Laboratory Analytical Report
Appendix D Statistical Analyses Worksheets and Summary Table

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1.0 INTRODUCTION
The Upper Piedmont Regional Landfill, which is an active municipal solid waste landfill located
in Person County, North Carolina, is owned and operated by Republic Services of North
Carolina, LLC (Republic) under Permit No. 73-04 issued by the North Carolina Department of
Environmental Quality (NCDEQ). This report summarizes the monitoring results from the
February 1, 2017 water quality monitoring event at the Upper Piedmont Regional Landfill in
accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 13B
.1632.

1.1 Site Description and Background
The Upper Piedmont Regional Landfill is located approximately nine miles east-southeast of the
Town of Roxboro on U.S. Highway 158, in Person County, North Carolina. The location of the
facility is shown on the inlay on Drawing 1. The landfill is bounded to the north by U.S.
Highway 158, tributaries of Club Creek to the east and south, and Rock Fork Branch to the west.
Surrounding land use is primarily rural residential, silvicultural, and agricultural. Access to the
facility is via a driveway off of Oxford Road (U.S. Highway 158).

As shown on Drawing 1, the landfill is located at an elevation of 500 to 700 feet above mean sea
level. Surface drainage from the landfill and surrounding areas is routed by drainage channels
and storm water control structures to tributaries of the easterly flowing Club Creek, a tributary of
the Tar River.

1.2 Compliance Monitoring History
Water quality monitoring at the facility was initiated in May 1997 under the Detection
Monitoring Program for municipal solid waste landfills. The facility’s monitoring network is
comprised of ten monitoring wells (GW-1R through GW-10), which monitor the uppermost
aquifer beneath the facility. Upstream surface water monitoring point SW-1 and downstream
surface water monitoring point SW-2 are also sampled semiannually in accordance with the
approved monitoring plan. A sample from the facility’s leachate collection system is sampled
semiannually as part of the facility’s environmental monitoring program. An Alternate Source
Demonstration (ASD) for Cobalt, Iron, and Manganese was submitted in December 2016. The
ASD is still under review by NCDEQ.

1.3 Hydrogeologic Setting
Geologically, the facility is located within the Carolina Slate Belt of the Piedmont Physiographic
Province of North Carolina (NCGS 1985). The Carolina Slate Belt is composed of Late
Proterozoic to Cambrian meta-sedimentary and meta-volcanic rocks that locally have been
intruded by diabase dikes and felsic intrusive suites. The rocks underlying the facility are

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mapped as felsic meta-volcanics [dacitic and rhyolitic tuffs and flows interbedded with mafic
meta-volcanics (NCGS 1985)].

The uppermost groundwater beneath the facility is contained in a shallow, unconfined aquifer
comprised of partially weathered, fractured, meta-volcanic rock. Groundwater occurs at depths
of approximately 30 feet below grade along the western, upgradient side of the waste disposal
area, and at an average depth of five feet below grade along the eastern boundary. Depth-to-
water measurements obtained during the February 1, 2017, monitoring event and summarized in
Table 1 were used to prepare a groundwater surface contour map presented as Drawing 1.

The groundwater flow in the uppermost aquifer beneath the site is towards the east, with the flow
appearing to converge on the easterly flowing perennial tributary streams of Club Creek. The
groundwater surface contour map and interpreted flow directions are consistent with previously
submitted groundwater surface contour maps for this facility.

Based on the February 1, 2017, groundwater surface contour map, the hydraulic gradient in the
shallow aquifer underlying the site as measured along the conceptual flow paths shown on the
contour map was calculated to be approximately 0.05 to 0.06 ft/ft. The estimated rates of
groundwater flow for the uppermost aquifer beneath the facility were calculated using the
following modified Darcy equation:

Vgw = Ki/ne

where Vgw = average linear velocity (feet/year), K = hydraulic conductivity (feet/day), i =
horizontal hydraulic gradient, and ne = effective porosity. The calculated linear groundwater
flow velocity under the waste management unit ranges from 5.35 to 6.177 feet/year. The flow
calculations are presented in Table 2.

The linear velocity equation and resultant rates are based on the simplified assumptions of a
homogeneous and isotropic aquifer. This equation can be inaccurate when applied to
heterogeneous and/or anisotropic conditions such as in the saprolite wells used for gradient
estimates at this site. The saprolite may have areas that exhibit relict foliation and these
structures can result in locally anisotropic groundwater flow and fractured bedrock is inherently
anisotropic and heterogeneous.

2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION
2.1 Visual Inspection Program
In order to detect potential releases in a timely manner, a visual inspection program has been
implemented at the Upper Piedmont Regional Landfill.

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This inspection program involves field personnel making the following observations:
 Observation of stress induced on the biological community (e.g., dead or dying vegetation),
 Indications of leachate impact (e.g., seeps, impacted surface water),
 Observations of erosion; and
 Negative changes around the waste facility.

During the February 1, 2017 monitoring event, no physical indicators were observed in the
vicinity of the monitoring wells and surface water monitoring points.

2.2 Well Network and Groundwater Elevation Measurements
The network of groundwater monitoring wells at the Upper Piedmont Regional Landfill currently
consists of GW-1R, GW-2, GW-3, GW-4, GW-5, GW-6, GW-7, GW-8, GW-9, and GW-10.
Monitoring well construction information is summarized on Table 3 and the well locations are
shown on Drawing 1. The network of monitoring wells was constructed to target the flow path
for groundwater underlying waste disposal areas in the partially weathered fractured rock that
comprises the unconfined uppermost aquifer. Two surface water points are also monitored,
upstream point SW-1 and downstream point SW-2.

Monitoring well GW-1R is the facility’s background well and is located hydraulically upgradient
of the waste disposal area. Monitoring wells GW-2, GW-3, GW-4, GW-5, GW-6, GW-7, GW-8,
GW-9, and GW-10 are located downgradient or side-gradient of the waste disposal area and
represent the facility’s downgradient compliance wells. The monitoring wells are equipped with
dedicated bladder pumps and were sampled via the micropurge method.

Monitoring well GW-1R was installed in July 2009 as a replacement background well for GW-1,
which had been dry during several consecutive sampling events. Well GW-1R was sampled for
the first time during the January 2010 sampling event. Well GW-1 was decommissioned
following the July 2009 event.

Downgradient wells GW-9 and GW-10 were installed in July 2009 and wells GW-7 and GW-8
were installed in April 2012 to monitor groundwater downgradient of the new Phase 3 waste unit
(Cells 5A and 6A). Background sampling for these four wells began in May 2012 and was
completed in August 2012.

Depth-to-water measurements were recorded to the nearest 0.01 foot prior to initiating
groundwater purging and sampling activities. The monitoring point summary and respective
water level elevations for this event are presented in Table 1. The historical water level data are
also shown on this table.

The water level data indicate that the hydraulic head in the uppermost aquifer beneath the facility
is fairly consistent, with temporal variation from the long-term average limited to less than five

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feet (plus or minus). As expected, the range in fluctuation generally appears to be greater in the
upgradient wells, as these wells are located in a groundwater recharge area.

2.3 February 2017 Monitoring Event
Personnel from Joyce Engineering (JOYCE) visited the facility on February 1, 2017 to purge and
sample monitoring wells GW-1R, GW-2, GW-3, GW-4, GW-5, GW-6, GW-7, GW-8, GW-9,
and GW-10; sample surface water monitoring points SW-1 (upstream) and SW-2 (downstream);
and collect a leachate sample. Depth-to-water measurements were obtained from the network
monitoring wells to the nearest 0.01 foot using an electronic water level indicator prior to
purging the wells.

Monitoring wells were purged with dedicated bladder pumps using micropurge procedures
pursuant to the facility’s approved monitoring plan. Measurements of pH, specific conductance,
dissolved oxygen, oxidation-reduction potential, temperature, and turbidity were recorded after
each system volume collected during the purge with field-calibrated instruments to monitor for
stabilization of water quality.

During sampling, the laboratory-supplied sample containers were prepared. Each sample
container was labeled with the sample identification number, sampling personnel, date and time
of sample collection, project name and number, and requested chemical analyses.

The groundwater samples were collected directly from the discharge hoses on the bladder pumps
in the pre-preserved sample containers after purging was completed based on stabilization of
water quality parameters. After collection, the samples were placed in a cooler on ice, under
chain-of-custody control.

Surface water samples were collected for NC Appendix I plus indicator parameters for SW-1 and
SW-2 during the February 1, 2017 event. Surface water samples were collected directly from the
stream, by lowering the sample containers into the stream, taking care to prevent the over flow of
the sample containers and to minimize sample-induced turbidity. Measurements of pH, specific
conductivity, dissolved oxygen, oxidation-reduction potential, temperature, and turbidity are
normally recorded during the collection of the surface water samples.

The leachate sample was collected directly from the leachate piping manifolds that serve the
leachate holding tanks. Measurements of pH, specific conductivity, and temperature were
recorded during the collection of the leachate sample.

Copies of the sampling logs are presented in Appendix B. Included in each log is a description of
the sampling equipment, sampling location, sampling method, field observations, and water
quality measurements. The groundwater, surface water, and leachate samples were shipped under
chain-of-custody control to Pace Analytical Services, LLC of Norcross, Georgia for analysis.

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2.4 Laboratory Analysis Program
The February 1, 2017 groundwater, surface water, and leachate samples were submitted to Pace
Analytical under chain-of-custody control for analysis. The groundwater samples, surface water
samples, and the Field Blank were analyzed for North Carolina Appendix I constituents plus iron
and manganese. Indicator parameters iron and manganese were analyzed at NCDEQ’s request.
The leachate sample was analyzed for NC Appendix I constituents, as well as nitrate as N, nitrite
as N, sulfate, biochemical oxygen demand (BOD), chemical oxygen demand (COD),
phosphorus, ammonia, nitrate/nitrite as N, mercury, and cyanide.. The Trip Blank was analyzed
for North Carolina Appendix I organic constituents. Joyce Engineering requested a Level II data
report for the final laboratory report. The groundwater, surface water, and leachate samples were
received by the laboratory on February 2, 2017 in good condition, properly preserved, and within
analysis hold times.

2.5 February 2017 Sampling Results
Analytical detection and exceedance results for the February 1, 2017 groundwater and surface
water samples are summarized in Tables 4 and 5. A summary of field parameter data from the
February 2017 event is included in Table 6 Historical analytical data for groundwater, surface
water and leachate samples are summarized in Tables 7, 8, and 9 in Appendix A. The laboratory
certificates-of-analysis and chains-of-custody for the monitoring event are included in Appendix
C.

Five NC Appendix I inorganic constituents and two indicator parameters were detected in
samples from one or more downgradient compliance monitoring wells or surface water
monitoring points at concentrations above their respective Solid Waste Section Reporting Limits
(SWSLs). The complete list of quantified detections in groundwater and surface water by
monitoring location, constituent and result in comparison to SWSLs is found in Table 4.

No NC Appendix I volatile organic constituents were detected in any groundwater wells or
surface water monitoring points during the February 2017 sampling event at concentrations
above their respective SWSLs.

Constituent concentrations reported for the leachate samples collected during the February 1,
2017 sampling event are typical for leachate at this facility.

3.0 LABORATORY AND FIELD QA/QC
A Field Blank was collected by Joyce Engineering personnel as part of the February 1, 2017
monitoring event. In addition to the Field Blank, a laboratory-prepared Trip Blank accompanied
the volatile sample containers for the sampling event to and from the laboratory. The Field Blank

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was analyzed for NC Appendix I constituents and the Trip Blank for NC Appendix I Volatile
Organic Compounds (VOCs). In addition to the Field and Trip Blanks, at least one Method
Blank was analyzed by the laboratory for each method used.

Upon receipt of the laboratory data package, the data was reviewed by Joyce Engineering
personnel for the following:

 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank qualified data (B-flags);
 Detections above the groundwater and surface water standards; and
 Detections that are above historical levels.

4.0 DATA EVALUTION
4.1 Comparisons to Groundwater and Surface Water Standards
The complete list of constituents in exceedance of applicable standards in groundwater and
surface water samples by monitoring location is presented in Table 5.

4.1.1 Groundwater Standard Exceedances
Cobalt was detected above the Solid Waste Section Groundwater Protection Standards (GWPS)
of 1 µg/L in downgradient monitoring well GW-8 at 13.5µg/L. Cobalt is a common, naturally-
occurring element in soils in this region, and these results are generally consistent with historical
values. Based on interwell statistical analysis, the background value for cobalt is 31.5 µg/L, as
determined in the December 2016 ASD for Cobalt, Iron and Manganese. In accordance with
15A NCAC 13B.1634.(g).(5), we requested that background concentrations be considered the
applicable groundwater protection standard (GPS) for cobalt for compliance sampling events at
this facility. The request is under review at NCDEQ.
Arsenic was initially reported above the NC2L of 10 µg/L in GW-5 at 10.7 µg/L. The arsenic
exceedance in GW-5 was not historically consistent, and so a verification resampling event was
performed on March 31, 2017. The result of the resampling event did not confirm arsenic in
excess of the NC2L.

Two inorganic indicator parameters, iron and manganese, were analyzed per a NCDEQ request in a
letter dated September 28, 2007. The concentrations of iron detected in downgradient wells GW-2,
GW-3, GW-4, GW-5, GW-7, GW-8, GW-9 and GW-10 were above the NC2L Standard during the
February 2017 sampling event. The concentrations of manganese detected in GW-2, GW-3, GW-5,
GW-7, GW-8, GW-9, and GW-10 were above the NC2L Standard during the February 2017
sampling event. The February 2017 groundwater concentrations for iron and manganese are

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generally consistent with historical data. The December 2016 ASD for Cobalt, Iron, and Manganese
is pending review at NCDEQ

4.1.2 Surface Water Standard Exceedances
Two inorganic indicator parameters, iron and manganese, were analyzed per a NCDEQ request
in a letter dated September 28, 2007. Iron and manganese have been historically detected in the
upgradient and down-gradient surface water monitoring points at similar concentrations. There
is no NC2B standard for for iron or manganese. The February 2017 surface water concentrations
for iron and manganese are generally consistent with historical data.
4.2 Statistical Evaluations
If comparison to a groundwater standard indicates an apparent exceedance of the standard for a
constituent, it was statistically evaluated in accordance with the procedures outlined in 15A
NCAC 13B.1632 (g) and (h) to determine if the reported concentrations exceeded the facility
background concentrations. Background data were evaluated using the Shapiro-Wilk Test,
Parametric Prediction Limits, Parametric Tolerance Intervals, Aitchison’s Adjustment, Non-
parametric Prediction Limits, and Poisson Prediction Limits, as appropriate. Background data,
tests for normality, outliers, Aitchison’s adjustment, tolerance interval, or prediction limits are
used, as appropriate based on the background data. The statistical test by which downgradient
data are compared to facility background data is based upon the nature of the data and the
number of data values that are less than the laboratory limit of detection. All statistical tests are
evaluated at the 0.05 level of significance, 95% confidence level, and are conducted as one-tailed
tests.

Cobalt was detected above the SWSL and its GWPS in GW-8 during the February 1, 2017,
sampling event. The cobalt detections were statistically evaluated in accordance with the
procedures outlined in 15A NCAC 13B.1632 (g) and (h) to determine if the reported
concentration exceeded the facility background concentration. Based on interwell non-parametric
prediction interval analysis, the background for cobalt is 31.5 µg/L. Based on the statistical
evaluation; the detection of cobalt in GW-8 was not identified as statistically significant and is
representative of historical background concentrations. In accordance with 15A NCAC
13B.1634.(g).(5), we requested that background concentrations be considered the applicable site
specific groundwater protection standard (GPS) for cobalt, as presented in the December 2016
ASD for Cobalt, Iron, and Manganese. The ASD requests to use background as the GPS for
cobalt, and to cease monitoring for iron and manganese. A summary of the December 2016 ASD
statistical analyses is presented in Appendix D.
5.0 CONCLUSIONS
Based on the results presented herein, we recommend that Republic Services of NC, LLC
continue monitoring the uppermost aquifer beneath the Upper Piedmont Regional Landfill in
accordance with the requirements for Detection Monitoring Program as outlined in Title 15A

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NCAC 13B .1633. The next compliance monitoring event for this facility is tentatively
scheduled for July 2017.
6.0 REFERENCES
BLE (Bunnell-Lammons Engineering, Inc.), December 2004. Report of Ground Water Quality
Results & Statistical Analysis, Second Semi-Annual Sampling Event of 2004 (N18)
Upper Piedmont Regional MSW Landfill, Person County, North Carolina. 3 pp

Golder Associates NC, Inc., February, 2011. First Semi-Annual 2011 Sampling Event. Prepared
for Republic Services of North Carolina, LLC.

HHNT (Hodges, Harbin, Newberry & Tribble), April 2003. Water Monitoring Procedures:
Upper Piedmont Regional MSW Landfill, Phase 2 Construction Permit, Person County,
North Carolina. 28 pp.

North Carolina Geologic Survey, 1985, Geologic Map of North Carolina; North Carolina
Department of Natural Resources and Community Development, Geological Survey
Section; scale 1:500,000.

Tables

TABLE 1: Historical Groundwater ElevationsGW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10TOC Elevation724.15 724.71 600.39 562.55 560.97 562.13 629.29 584.06 636.91 612.26 619.1413-Aug-97693.49 NI 574.91 556.06 554.73 556.61 NI NI NI NI NI29-Apr-98711.81 NI 576.70 559.22 557.35 558.63 NI NI NI NI NI14-Sep-98692.05 NI 573.88 556.74 554.55 557.69 NI NI NI NI NI08-Apr-99707.45 NI 575.26 559.45 556.44 558.08 NI NI NI NI NI08-Sep-99DRY NI 573.66 557.25 555.10 557.84 NI NI NI NI NI12-Apr-00711.08 NI 576.25 557.76 556.28 557.82 NI NI NI NI NI17-Oct-00 692.83 NI 574.06 555.59 554.99 556.66 NI NI NI NI NI23-Apr-01698.84 NI 575.10 557.24 556.37 557.91 NI NI NI NI NI17-Oct-01DRY NI 574.66 555.48 554.94 557.18 NI NI NI NI NI29-Apr-02DRY NI 573.70 556.81 556.17 557.83 NI NI NI NI NI23-Oct-02DRY NI 575.24 557.16 556.64 558.64 NI NI NI NI NI14-Apr-03707.86 NI 578.27 559.32 557.93 559.41 NI NI NI NI NI29-Oct-03705.73 NI 579.25 558.10 557.69 559.38 NI NI NI NI NI28-Apr-04708.26 NI 578.19 558.17 557.18 558.62 619.79 NI NI NI NI26-Oct-04 699.87 NI 577.62 558.00 557.37 559.07 617.89 NI NI NI NI16-Mar-05 706.91 NI 578.35 558.85 558.01 559.79 621.67 NI NI NI NI21-Jul-05 696.92 NI 576.43 555.64 555.20 556.36 617.62 NI NI NI NI26-Jan-06 <691.40 NI 576.63 558.15 557.44 559.04 611.26 NI NI NI NI20-Jul-06 692.72 NI 576.49 557.27 556.94 558.32 617.97 NI NI NI NI22-Jan-07 697.05 NI 575.78 559.05 558.38 559.83 621.78 NI NI NI NI23-Jul-07 692.71 NI 575.77 555.70 555.16 556.48 618.31 NI NI NI NI10-Jan-08 <691.40 NI 574.04 556.85 556.33 558.03 616.04 NI NI NI NI21-Jul-08 <691.40 NI 575.27 555.81 555.25 556.93 617.30 NI NI NI NI29-Jan-09 <691.40 NI 577.25 558.60 557.90 559.36 621.55 NI NI NI NI30-Jul-09 698.11 NI 576.48 556.65 555.93 557.48 620.08 NI NI NI NI14-Jan-10 --689.83 578.32 558.56 557.55 559.28 621.13 NI NI 599.71 --15-Jul-10--690.40 577.66 556.21 555.44 556.77 619.97 NI NI 595.35 --20-Jan-11--679.93 577.34 557.54 556.82 558.19 619.75 NI NI 594.79 601.8614-Jul-11 --688.89 578.01 556.58 555.73 557.23 618.98 NI NI 595.61 601.5630-Jan-12 --686.27 577.85 557.82 556.87 557.65 620.14 NI NI 596.84 602.2425-Jul-12 --684.65 576.94 558.41 554.47 556.23 616.79 572.05 593.72 594.96 601.4204-Feb-13 --683.04 578.20 558.68 557.04 558.17 620.53 576.17 597.06 595.64 602.8508-Jul-13 --695.61 571.79 558.10 557.02 558.81 620.68 572.01 597.46 598.26 602.8221-Jan-14 --691.51 579.49 557.95 557.42 558.96 617.39 575.75 597.70 597.93 604.1621-Jul-14 --692.89 578.93 556.96 556.17 557.83 619.20 574.46 598.46 597.11 606.3729-Jan-15 --697.36 578.63 558.72 557.93 559.50 619.84 577.31 599.16 598.83 604.0427-Jul-15 --694.16 579.28 556.77 556.71 558.00 618.14 575.11 598.06 596.81 602.4926-Jan-16 --697.31 579.79 558.77 558.22 559.93 620.44 576.81 598.56 599.16 604.3426-Jul-16 --697.51 580.19 557.92 557.57 558.73 620.79 576.76 598.21 598.66 604.1401-Feb-17 --695.51 579.37 558.55 557.99 559.23 620.94 577.15 597.16 599.43 604.54MEAN700.81 690.99 576.78 557.56 556.58 558.19 619.11 575.36 597.56 597.27 603.29MAXIMUM711.81 697.51 580.19 559.45 558.38 559.93 621.78 577.31 599.16 599.71 606.37MINIMUM<691.40 679.93 571.79 555.48 554.47 556.23 611.26 572.01 593.72 594.79 601.42Notes:All measurements are given in feet AMSL (above mean sea level).NI = Not installed.-- = No data available.Dry = Monitoring well was dry and no depth to water value was obtained.GW-1 was removed from the approved monitoring network prior to the January 2010 Sampling event.All data prior to 2012 taken from previous report by Golder Associates NC, Inc.LocationBackgroundDowngradientUpper Piedmont Regional LandfillPermit No. 73-04Joyce Engineering
TABLE 2:Estimated Hydraulic Gradients and Linear Groundwater VelocitiesGroundwater Elevations Measured:February 1, 2017Flow Ground- Horizontal Hydraulic Effective LinearLengthwater Gradient Conductivity PorosityVelocityLineElevationiKneVgw(feet)(feet)(ft/ft) (ft/day)(ft/year)700590630560690560Notes:Horizontal velocities based on the modified Darcy equation Vgw = Ki/neValues for K and ne were taken from BLE's 2004 report reference in the text.For flow segments see Drawing 1.0.050.0220.0755.350Gradient Calculation SegmentFlow Directioni12212ENE6.177i32300E0.060.0220.0756.080i21219E0.060.0220.075Upper Piedmont Regional LandfillPermit No. 73-04Joyce Engineering
TABLE 3: Well Construction InformationWell IdentificationGround Surface ElevationTOC Elevation Well DepthWell DiameterScreened IntervalScreened Geologic Formation(Ft-AMSL)(Ft-AMSL) (Feet) (Inches) (Ft-AMSL)GW-1721.4724.1532.52 706.4 - 691.4 Partially Weathered RockGW-1R721.74724.7147.92 676.6 - 661.6BedrockGW-2598.0600.3945.92 569.5 - 554.5 Partially Weathered RockGW-3560.1562.5541.62 536.7 - 521.7 Partially Weathered RockGW-4558.1560.9746.62 531.1 - 516.1 Partially Weathered RockGW-5559.4562.1322.22 554.9 - 539.9 Partially Weathered RockGW-6626.7629.2928.12 616.2 - 601.2 Partially Weathered RockGW-9609.33612.2633.12 594.2 - 579.2BedrockGW-10616.51619.1414.02 603.7 - 588.7BedrockNotes:Ft-AMSL = Feet above mean sea level.TOC = Top of PVC Casing ( Measuring Point ).Upper Piedmont Regional LandfillPermit No. 73-04Joyce Engineering
TABLE 4:
Quantified Detections in Groundwater and Surface Water
Well or Point
ID Constituent Result Units SWSL Collection Date
GW-2 Total Copper 29.2 µg/L 10 2/1/2017
Total Iron 356 µg/L 300 2/1/2017
Total Manganese 623 µg/L 50 2/1/2017
Total Zinc 24.8 µg/L 10 2/1/2017
GW-3 Total Barium 522 µg/L 700 2/1/2017
Total Iron 614 µg/L 300 2/1/2017
Total Manganese 269 µg/L 50 2/1/2017
GW-4 Total Barium 552 µg/L 700 2/1/2017
Total Iron 536 µg/L 300 2/1/2017
GW-5 Total Arsenic 10.7 µg/L 10 2/1/2017
Total Arsenic (resample) 1.16 J µg/L 10 3/31/2017
Total Barium 681 µg/L 700 2/1/2017
Total Iron 7,570 µg/L 300 2/1/2017
Total Manganese 9,200 µg/L 50 2/1/2017
GW-7 Total Barium 193 µg/L 700 2/1/2017
Total Iron 90,900 µg/L 300 2/1/2017
Total Manganese 7,940 µg/L 50 2/1/2017
GW-8 Total Barium 215 µg/L 100 2/1/2017
Total Cobalt 13.5 µg/L 10 2/1/2017
Total Iron 316 µg/L 300 2/1/2017
Total Manganese 446 µg/L 50 2/1/2017
Total Zinc 10.9 µg/L 10 2/1/2017
GW-9 Total Barium 115 µg/L 100 2/1/2017
Total Iron 2,600 µg/L 300 2/1/2017
Total Manganese 151 µg/L 50 2/1/2017
GW-10 Total Barium 150 µg/L 100 2/1/2017
Total Iron 578 µg/L 300 2/1/2017
Total Manganese 196 µg/L 50 2/1/2017
SW-1 Total Iron 2,300 µg/L 300 2/1/2017
Total Manganese 92.5 µg/L 50 2/1/2017
Total Zinc 13.9 µg/L 10 2/1/2017
SW-2 Total Iron 1,940 µg/L 300 2/1/2017
Total Manganese 128 µg/L 50 2/1/2017
Notes:
Concentrations are in micrograms per liter (µg/L).
SWSL = NC DEQ Solid Waste Section Reporting Limits
MDL = Method Detection Limit
B= Blank Qualified .
**= Resample event 3/31/17
Bold Values= Detections exceeding the NC2L, GWPS, or NC2B stardards. (see Table 5)
Upper Piedmont Regional Landfill
Permot No. 73-04 Joyce Engineering
TABLE 5:Exceedences of Groundwater and Surface Water StandardsWell or Point IDConstituent Result Units SWSLNC 2L/ *GWPS/ **NC 2B GPS Collection DateGW-2 Total Iron 346µg/L300 300 300 2/1/2017Total Manganese 623µg/L50 50 50 2/1/2017GW-3 Total Iron 614µg/L300 300 300 2/1/2017Total Manganese 269µg/L50 50 50 2/1/2017GW-4 Total Iron 536µg/L300 300 300 2/1/2017GW-5 Total Arsenic 10.7µg/L10 10 10 2/1/2017Total Iron 7,570µg/L300 300 300 2/1/2017Total Manganese 9,200µg/L50 50 50 2/1/2017GW-7 Total Iron 90,900 µg/L 300 300 300 2/1/2017Total Manganese 7,940µg/L50 50 50 2/1/2017GW-8 Total Cobalt 13.5µg/L10 1* 31.5 2/1/2017Total Iron 316µg/L300 300 300 2/1/2017Total Manganese 446µg/L50 50 50 2/1/2017GW-9 Total Iron 2,600µg/L300 300 300 2/1/2017Total Manganese 151µg/L50 50 50 2/1/2017GW-10 Total Iron 578µg/L300 300 300 2/1/2017Total Manganese 196µg/L50 50 50 2/1/2017SW-1 Total Iron 2,300µg/L300 1000** 1,000 2/1/2017SW-2 Total Iron 1,940µg/L300 1000** 1,000 2/1/2017 Notes:Concentrations are in micrograms per liter (µg/L).SWSL = NC DENR Solid Waste Section reporting LimitsNC 2L = Groundwater Standard established in 15 A NCAC 2L.0202.GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L.GPS = Groundwater Protection Standard per Rule 15A NCAC 13B.1634.g.5.GPS for Cobalt based on Statistical background.NC 2B = Surface Water Protection Standard established in 15 A NCAC 2B (the lowest of Human Health or Fresh Water Aquatic standards).NE = Not EstablisheNA = Not Applicable.Upper Piedmont Regional LandfillPermot No. 73-04Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULTS UNITS COLLECT DATE
7304-GW1R Temperature 14.80 oC 2/1/2017
7304-GW1R Dissolved Oxygen 2.26 mg/l 2/1/2017
7304-GW1R Conductivity 157.6 µS/cm 2/1/2017
7304-GW1R pH 5.88 S.U. 2/1/2017
7304-GW1R Oxidation Reduction Potential 182.5 mV 2/1/2017
7304-GW1R Turbidity 2.86 ntu 2/1/2017
7304-GW1R Static Water Level 29.20 ft 2/1/2017
7304-GW1R Well Depth 64.80 ft 2/1/2017
7304-GW2 Temperature 16.8
oC 2/1/2017
7304-GW2 Dissolved Oxygen 1.34 mg/l 2/1/2017
7304-GW2 Conductivity 268.3 µS/cm 2/1/2017
7304-GW2 pH 6.08 S.U. 2/1/2017
7304-GW2 Oxidation Reduction Potential 116.4 mV 2/1/2017
7304-GW2 Turbidity 3.19 ntu 2/1/2017
7304-GW2 Static Water Level 21.02 ft 2/1/2017
7304-GW2 Well Depth 46.10 ft 2/1/2017
7304-GW3 Temperature 14.6
oC 2/1/2017
7304-GW3 Dissolved Oxygen 0.58 mg/l 2/1/2017
7304-GW3 Conductivity 488.1 µS/cm 2/1/2017
7304-GW3 pH 7.32 S.U. 2/1/2017
7304-GW3 Oxidation Reduction Potential -71.3 mV 2/1/2017
7304-GW3 Turbidity 0.71 ntu 2/1/2017
7304-GW3 Static Water Level 4 ft 2/1/2017
7304-GW3 Well Depth 37.70 ft 2/1/2017
7304-GW4 Temperature 13.9
oC 2/1/2017
7304-GW4 Dissolved Oxygen 1.58 mg/l 2/1/2017
7304-GW4 Conductivity 684 µS/cm 2/1/2017
7304-GW4 pH 6.96 S.U. 2/1/2017
7304-GW4 Oxidation Reduction Potential 77.2 mV 2/1/2017
7304-GW4 Turbidity 14.39 ntu 2/1/2017
7304-GW4 Static Water Level 2.98 ft 2/1/2017
7304-GW4 Well Depth 32.50 ft 2/1/2017
7304-GW5 Temperature 14.3
oC 2/1/2017
7304-GW5 Dissolved Oxygen 3.49 mg/l 2/1/2017
7304-GW5 Conductivity 448.7 µS 2/1/2017
7304-GW5 pH 7.26 S.U. 2/1/2017
7304-GW5 Oxidation Reduction Potential -12.4 mV 2/1/2017
7304-GW5 Turbidity 5.19 ntu 2/1/2017
7304-GW5 Static Water Level 2.90 ft 2/1/2017
7304-GW5 Well Depth 22.10 ft 2/1/2017
Upper Piedmont Regional Landfill
Permit #79-03 Page 1 of 3
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULTS UNITS COLLECT DATE
7304-GW5 Temperature 13.8 oC 3/31/2017
7304-GW5 Dissolved Oxygen 1.55 mg/l 3/31/2017
7304-GW5 Conductivity 430.8 µS 3/31/2017
7304-GW5 pH 7.27 S.U. 3/31/2017
7304-GW5 Oxidation Reduction Potential 27.1 mV 3/31/2017
7304-GW5 Turbidity 3.15 ntu 3/31/2017
7304-GW5 Static Water Level 3.05 ft 3/31/2017
7304-GW5 Well Depth 22.10 ft 3/31/2017
7304-GW6 Temperature 14.3
oC 2/1/2017
7304-GW6 Dissolved Oxygen 5.31 mg/l 2/1/2017
7304-GW6 Conductivity 166.2 µS/cm 2/1/2017
7304-GW6 pH 5.99 S.U. 2/1/2017
7304-GW6 Oxidation Reduction Potential 155.5 mV 2/1/2017
7304-GW6 Turbidity 3.98 ntu 2/1/2017
7304-GW6 Static Water Level 8.35 ft 2/1/2017
7304-GW6 Well Depth 25.20 ft 2/1/2017
7304-GW7 Temperature 14.7
oC 2/1/2017
7304-GW7 Dissolved Oxygen 0.73 mg/l 2/1/2017
7304-GW7 Conductivity 711 µS/cm 2/1/2017
7304-GW7 pH 6.35 S.U. 2/1/2017
7304-GW7 Oxidation Reduction Potential -86.4 mV 2/1/2017
7304-GW7 Turbidity 2.89 ntu 2/1/2017
7304-GW7 Static Water Level 6.91 ft 2/1/2017
7304-GW7 Well Depth 28.45 ft 2/1/2017
7304-GW8 Temperature 16.2
oC 2/1/2017
7304-GW8 Dissolved Oxygen 1.89 mg/l 2/1/2017
7304-GW8 Conductivity 157.3 µS/cm 2/1/2017
7304-GW8 pH 5.3 S.U. 2/1/2017
7304-GW8 Oxidation Reduction Potential 132.9 mV 2/1/2017
7304-GW8 Turbidity 26.27 ntu 2/1/2017
7304-GW8 Static Water Level 39.75 ft 2/1/2017
7304-GW8 Well Depth 57.92 ft 2/1/2017
7304-GW9 Temperature 16.4
oC 2/1/2017
7304-GW9 Dissolved Oxygen 1.35 mg/l 2/1/2017
7304-GW9 Conductivity 83.3 µS/cm 2/1/2017
7304-GW9 pH 5.23 S.U. 2/1/2017
7304-GW9 Oxidation Reduction Potential 158.6 mV 2/1/2017
7304-GW9 Turbidity 37.3 ntu 2/1/2017
7304-GW9 Static Water Level 12.83 ft 2/1/2017
7304-GW9 Well Depth 33.30 ft 2/1/2017
Upper Piedmont Regional Landfill
Permit #79-03 Page 2 of 3
Joyce Engineering
TABLE 6: Field Parameters
WELL ID PARAMETER RESULTS UNITS COLLECT DATE
7304-GW10 Temperature 15.8 oC 2/1/2017
7304-GW10 Dissolved Oxygen 2.07 mg/l 2/1/2017
7304-GW10 Conductivity 112.2 µS/cm 2/1/2017
7304-GW10 pH 5.19 S.U. 2/1/2017
7304-GW10 Oxidation Reduction Potential 168.9 mV 2/1/2017
7304-GW10 Turbidity 3.72 ntu 2/1/2017
7304-GW10 Static Water Level 14.60 ft 2/1/2017
7304-GW10 Well Depth 30.67 ft 2/1/2017
7304-Leachate Temperature 17.7
oC 2/1/2017
7304-Leachate Dissolved Oxygen 3.6 mg/l 2/1/2017
7304-Leachate Conductivity 14124 µS/cm 2/1/2017
7304-Leachate pH 8.26 S.U. 2/1/2017
7304-Leachate Oxidation Reduction Potential 8.26 mV 2/1/2017
7304-Leachate Turbidity 500 ntu 2/1/2017
7304-SW1 Temperature 11.5
oC 2/1/2017
7304-SW1 Dissolved Oxygen 10.45 mg/l 2/1/2017
7304-SW1 Conductivity 48.2 µS/cm 2/1/2017
7304-SW1 pH 7.63 S.U. 2/1/2017
7304-SW1 Oxidation Reduction Potential 17.5 mV 2/1/2017
7304-SW1 Turbidity 192 ntu 2/1/2017
7304-SW2 Temperature 8.1
oC 2/1/2017
7304-SW2 Dissolved Oxygen 10.76 mg/l 2/1/2017
7304-SW2 Conductivity 84.2 µS/cm 2/1/2017
7304-SW2 pH 8.27 S.U.2/1/2017
7304-SW2 Oxidation Reduction Potential 28.3 mV 2/1/2017
7304-SW2 Turbidity 21.84 ntu 2/1/2017
Notes:
oC = degrees Centigrade
mg/l = milligrams per Liter
µS/cm = microSeimens per centimeter = µS/cm
S.U. = Standard units
mV = milliVolts
ntu = Nephelometric Turbidity Units
GW-5 was resampled on March 31, 2017.
Upper Piedmont Regional Landfill
Permit #79-03 Page 3 of 3
Joyce Engineering

Drawing

670680690650670680690700710640660650670680690700710720720730730740740750750660630640650660670680690700710720650670680690700660720710
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xCONCEXISTING CELL 3AEXISTING CELL 3BEXISTING CELL 2BEXISTING CELL 1BEXISTING CELL 2AEXISTING CELL 1AEXISTING CELL 4BEXISTING CELL 4AGW-2579.37GW-3558.55GW-4557.99GW-5559.23GW-9599.43GW-10604.54GW-1GW-1R695.51GW-6620.94SW-1SW-25605
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0 6906903iEXISTING CELL 5AEXISTING CELL 6APROPOSED CELL 6BPROPOSED CELL 5B700700SITE710MW-XSW-XPROPERTY LINEEXISTING 10' TOPOGRAPHIC CONTOUREXISTING 2' TOPOGRAPHIC CONTOUREXISTING ROADGROUNDWATER SURFACE CONTOUR[FEET ABOVE MEAN SEA LEVEL (AMSL)]GROUNDWATER FLOW DIRECTIONTREE LINEGROUNDWATER MONITORING WELL LOCATIONAND IDENTIFICATIONSURFACE MONITORING POINT LOCATION ANDIDENTIFICATIONSEGMENT USED FOR GRADIENT CALCULATION1.TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET2.GROUNDWATER CONTOUR INTERVAL = 10 FEET3.GROUNDWATER CONTOURS BASED ON LINEARINTERPOLATION BETWEEN AND EXTRAPOLATIONFROM KNOWN DATA, TOPOGRAPHIC CONTOURS,AND KNOWN FIELD CONDITIONS. THEREFORE,GROUNDWATER CONTOURS MAY NOT REFLECTACTUAL GROUNDWATER CONDITIONS.4.THIS MAP WAS COMPILED BY AERO-METRIC,DULLES, VIRGINIA. DATE OF AERIALPHOTOGRAPHY 1/21/14. GRID BASED ON NORTHCAROLINA STATE PLANE COORDINATE SYSTEMNAD 1983. VERTICAL DATUM BASED ON NGSMEAN SEA LEVEL.5. STATIC WATER LEVELS MEASURED ON 02/01/17.iLEGEND2660NOTESiiiFLOW PATH LENGTH2,212 LF1,219 LF2,300 LFPROJECT NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
DATE REVISIONS AND RECORD OF ISSUE BYNO APPCKSCALE All rights reserved.
Ó Joyce Engineering, Inc.DRAWING NO.L:\Republic NC\Upper Piedmont\JANUARY 2017 Upper Piedmont GW Map.dwg Layout=Layout1
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
NC CORP LIC: C-0782893UPPER PIEDMONT REGIONAL LANDFILL
ROUGEMONT, NORTH CAROLINA
20171AS SHOWNPOTENTIOMETRIC SURFACE CONTOUR MAP
FEBRUARY 1, 2017
PERMIT NO. 73-04
GE
RH
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GVB
02/21/17 VICINITY MAP0(FEET)GRAPHIC SCALE28014070SOURCE: U.S.G.S. 7.5 MINUTE TOPO FOR MORIAH, NC

Appendix A

Historical Tables

TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Inorganic Compounds
Antimony 05/23/97 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI NDGWPS = 1 µg/L 06/16/97 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND
08/14/97 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND09/30/97 --- 30.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/30/98 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND09/15/98 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND
04/08/99 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND09/09/99 --- 30.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/13/00 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND10/17/00 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND
04/23/01 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND10/18/01 --- 30.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/29/02 --- 30.0 Dry NI ND ND ND ND --- NI NI NI NI ND10/23/02 --- 30.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/14/03 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND
10/30/03 --- 30.0 ND NI ND ND ND ND --- NI NI NI NI ND
03/19/04 --- 30.0 --- NI --- --- --- --- ND NI NI NI NI ND
04/28/04 --- 30.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 30.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 30.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 30.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 30.0 --- NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 30.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 6.00 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 6.00 ND NI ND ND ND ND 1.02 J NI NI NI NI ND
01/10/08 --- 6.00 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 6.00 Dry NI ND ND ND ND 0.79 J NI NI NI NI ND
01/29/09 --- 6.00 Dry NI ND ND ND ND ND NI NI NI NI ND07/30/09 --- 6.00 ND NI ND ND ND ND ND NI NI NI NI ND
01/14/10 --- 6.00 --- ND ND ND ND ND 0.233 J NI NI NI NI ND07/15/10 --- 6.00 --- ND ND ND ND ND 0.470 J NI NI NI NI ND
01/20/11 --- 6.00 --- ND ND ND ND ND 0.364 J NI NI NI NI ND07/14/11 --- 6.00 --- ND ND ND ND ND 0.339 J NI NI NI NI ND
01/30/12 --- 6.00 --- 0.37 B 0.18 B 0.17 B 0.15 B ND 0.370 B NI NI NI NI 0.33 J05/24/12 --- 6.00 --- NS NS NS NS NS NS 0.89 J 0.50 J 0.24 J ND ND
06/28/12 --- 6.00 --- NS NS NS NS NS NS 1.2 J 0.57 J 0.19 J ND ND07/25/12 --- 6.00 --- 1.52 J 0.50 J 0.30 J 0.22 J 0.22 J 0.54 J ND ND ND ND ND
08/24/12 --- 6.00 --- NS NS NS NS NS NS 1.38 J 0.63 J 0.25 J ND ND02/04/13 --- 6.00 --- 1.24 J 0.39 J 0.34 J 0.24 J ND 0.28 J ND ND ND ND ND
07/08/13 --- 6.00 --- ND ND ND ND ND ND ND ND ND ND ND
01/21/14 0.22 6.00 --- ND ND ND ND ND ND ND ND ND ND ND
07/21/14 1.05 6.00 --- ND ND ND ND ND ND ND ND ND ND ND
01/29/15 1.05 6.00 --- ND ND ND ND ND ND ND ND ND ND ND
07/27/15 0.25 6.00 --- ND 0.49 J ND ND ND 0.28 J ND ND ND ND ND
01/26/16 0.25 6.00 --- ND ND ND ND ND 0.30 J ND ND ND ND ND
07/26/16 0.25 6.00 --- ND ND ND ND ND 0.59 J ND ND ND ND ND
02/01/17 0.25 6.00 --- ND ND ND ND ND 0.27 J ND ND ND ND ND
Arsenic 05/23/97 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI NDNC 2L = 10 µg/L 06/16/97 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND
08/14/97 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND09/30/97 --- 10.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/30/98 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND09/15/98 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND
04/08/99 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND09/09/99 --- 10.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/13/00 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND10/17/00 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND10/18/01 --- 10.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/29/02 --- 10.0 Dry NI ND ND ND ND --- NI NI NI NI ND10/23/02 --- 10.0 Dry NI ND ND ND ND --- NI NI NI NI ND
04/14/03 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND
10/30/03 --- 10.0 ND NI ND ND ND ND --- NI NI NI NI ND
03/19/04 --- 10.0 --- NI --- --- --- --- ND NI NI NI NI ND
04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 ND NI ND 2.20 J ND 3.50 J 2.60 J NI NI NI NI ND07/23/07 --- 10.0 ND NI ND ND 2.7 J ND ND NI NI NI NI ND
01/10/08 --- 10.0 Dry NI ND 4.10 J ND 4.10 J ND NI NI NI NI ND07/21/08 --- 10.0 Dry NI ND 4.90 J 3.4 J 8.40 J 3.00 J NI NI NI NI ND
01/29/09 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI 4.20 J07/30/09 --- 10.0 ND NI ND 3.85 J 3.49 J 14.00 ND NI NI NI NI ND
01/14/10 --- 10.0 --- ND 4.24 J ND ND ND 4.02 J NI NI NI NI ND07/15/10 --- 10.0 --- ND ND ND ND ND 5.15 J NI NI NI NI ND
01/20/11 --- 10.0 --- ND 3.48 J 4.37 J 6.27 J ND 8.83 J NI NI NI NI ND07/14/11 --- 10.0 --- 4.13 J 5.58 J 4.47 J 5.52 J 6.94 J 4.07 J NI NI NI NI ND
01/30/12 --- 10.0 --- ND ND ND ND ND 1.83 J NI NI NI NI ND05/24/12 --- 10.0 --- NS NS NS NS NS NS 3.44 J ND ND ND ND
06/28/12 --- 10.0 --- NS NS NS NS NS NS 3.5 J ND ND ND ND07/25/12 --- 10.0 --- ND ND 1.33 B 6.02 B 12.40 B 1.67 B 8 B ND 3.00 B 1.70 B 1.72 J
08/24/12 --- 10.0 --- NS NS NS NS NS NS 8.6 J ND ND ND ND J02/04/13 --- 10.0 --- ND ND ND 6.02 J ND ND 5.79 J ND ND ND ND
07/08/13 --- 10.0 --- 2.02 J ND ND 2.49 J 1.17 J ND 4.23 J ND 3.53 J ND ND
01/21/14 0.78 10.0 --- ND ND 0.85 J 1.42 J ND 1.32 J 5.90 J ND ND ND ND
07/21/14 1.13 10.0 --- ND ND ND 1.58 J 1.80 J 1.29 J 7.03 J ND ND ND ND
01/29/15 1.13 10.0 --- ND 2.47 J 1.91 J ND ND ND 6.49 J ND 2.55 J ND ND
07/27/15 0.75 10.0 --- ND 1.23 J 2.47 J 2.14 J 1.31 J 2.00 J 4.41 J ND 0.84 J ND ND
01/26/16 0.75 10.0 --- ND 1.16 J 2.85 J 3.28 J 4.38 J 1.36 J 4.60 J ND 1.87 J ND ND
07/26/16 0.75 10.0 --- ND ND 3.03 J 3.51 J 3.03 J 1.14 J 3.15 J ND 2.45 J ND ND
02/01/17 0.75 10.0 --- ND 1.21 J 2.37 J 2.16 J 10.7 ND 5.25 J ND 0.92 J ND NDResample > 03/31/17 0.75 10.0 --- --- --- --- --- 1.16 J --- --- --- --- --- ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 1 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Barium 05/23/97 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 700 µg/L 06/16/97 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 20 Dry NI 40.0 280 380 130 ---NI NI NI NI ND04/30/98 --- 20 40.0 NI 40.0 280 370 170 ---NI NI NI NI ND
09/15/98 --- 20 40.0 NI 40.0 270 400 140 ---NI NI NI NI ND
04/08/99 --- 20 50.0 NI 30.0 270 250 220 ---NI NI NI NI ND09/09/99 --- 500 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 500 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 500 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 500 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 500 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 500 ---NI ------------ND NI NI NI NI ND04/28/04 --- 500 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 500 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 500 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 500 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 500 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 500 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 100 41.80 J NI 77.90 J 443 322 342 31.6 J NI NI NI NI 0.50 J07/23/07 --- 100 42.10 J NI 44.30 J 455 332 360 40.0 J NI NI NI NI 0.50 J
01/10/08 --- 100 Dry NI 49.00 J 469 364 271 57.5 J NI NI NI NI ND
07/21/08 --- 100 Dry NI 44.60 J 466 382 415 49.2 J NI NI NI NI ND01/29/09 --- 100 Dry NI 50.20 J 465 361 295 29.9 J NI NI NI NI 0.50 J
07/30/09 --- 100 49.50 J NI 39.20 J 466 383 372 42.8 J NI NI NI NI ND01/14/10 --- 100 ---25.30 J 34.80 J 410 320 332 27.0 J NI NI NI NI ND
07/15/10 --- 100 ---12.30 J 27.50 J 392 380 282 54.8 J NI NI NI NI ND
01/20/11 --- 100 ---15.20 J 41.50 J 454 409 245 21.5 J NI NI NI NI ND07/14/11 --- 100 ---15.70 J 41.10 J 483 447 316 33.2 J NI NI NI NI ND
01/30/12 --- 100 ---13.80 J 42.80 J 468 459 238 21.2 J NI NI NI NI 0.14 J05/24/12 --- 100 ---NS NS NS NS NS NS 287 185 107 76.9 J ND
06/28/12 --- 100 ---NS NS NS NS NS NS 200 161 39.0 J 70.4 J 0.74 J
07/25/12 --- 100 ---14.90 J 39.60 J 441 620 370 19.9 J 267 186 73.5 J 68.4 J 0.79 J08/24/12 --- 100 ---NS NS NS NS NS NS 412 175 62.2 J 82.2 J 0.75 J
02/04/13 --- 100 ---12.90 J 43.4 J 418 811 211 23.8 J 254 143 57.7 J 78.0 J ND07/08/13 --- 100 ---51.80 J 48.40 J 474 508 360 49.4 J 227 162 352 92.0 J 0.57 J
01/21/14 0.25 100 ---17.8 J 47.7 J 449 418 194 82.6 J 245 200 110 87.8 J ND
07/21/14 0.1 100 ---9.06 J 58.2 J 444 599 284 17.8 J 242 254 124 88.0 J 0.34 J01/29/15 0.10 100 ---9.69 J 83.2 J 475 423 187 25.9 J 180 241 234 92.3 J 1.33 J
07/27/15 0.30 100 ---8.09 J 36.4 J 368 350 157 15.8 J 168 171 67.1 J 78.4 J 0.41 J01/26/16 0.30 100 ---11.50 J 50.6 J 492 452 268 25.8 J 199 212 164.0 88.8 J 0.55 J
07/26/16 0.30 100 ---8.42 J 42.6 J 452 453 283 18.7 J 195 164 119 90.6 J 0.30 J
02/01/17 0.30 100 ---9.73 J 59.6 J 522 552 681 20.0 J 193 215 115 150.0 ND
Beryllium 07/21/05 --- 2.00 ND NI ND ND ND ND ND NI NI NI NI NDGWPS = 4 µg/L 01/26/06 --- 2.00 ---NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 2.00 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 1.00 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 1.00 ---NI ND ND ND ND ND NI NI NI NI ND
01/29/09 --- 1.00 Dry NI ND ND ND ND ND NI NI NI NI ND
07/30/09 --- 1.00 0.28 J NI ND ND ND ND 0.19 J NI NI NI NI ND01/14/10 --- 1.00 ---0.11 J ND ND ND ND 0.12 J NI NI NI NI ND
07/15/10 --- 1.00 ---ND ND ND ND ND ND NI NI NI NI ND01/20/11 --- 1.00 ---ND ND ND ND ND ND NI NI NI NI ND
07/14/11 --- 1.00 ---ND ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 1.00 ---ND ND ND ND ND 0.10 J NI NI NI NI ND05/24/12 --- 1.00 ---NS NS NS NS NS NS ND ND 0.47 J ND ND
06/28/12 --- 1.00 ---NS NS NS NS NS NS ND ND ND ND ND07/25/12 --- 1.00 ---ND ND ND ND ND ND ND ND 0.17 J ND ND
08/24/12 --- 1.00 ---NS NS NS NS NS NS ND ND 0.15 J ND ND
02/04/13 --- 1.00 ---ND ND ND ND ND ND ND ND ND ND ND07/08/13 --- 1.00 ---0.40 J ND ND ND ND ND ND ND 1.20 ND ND
01/21/14 0.11 1.00 ---ND ND ND ND ND 0.16 J ND ND 0.27 J ND ND07/21/14 0.05 1.00 ---ND ND ND ND ND 0.07 J ND 0.08 J 0.29 J ND ND
01/29/15 0.05 1.00 ---ND ND ND ND ND 0.10 J ND 0.13 J 0.54 J 0.18 J ND
07/27/15 0.09 1.00 ---ND ND ND ND ND ND ND 0.11 J 0.15 J 0.16 J ND01/26/16 0.09 1.00 ---ND ND ND 0.20 J ND ND ND 0.15 J 0.26 J 0.20 J ND
07/26/16 0.09 1.00 ---ND ND ND 0.21 J ND ND ND 0.10 J 0.24 J 0.22 J ND02/01/17 0.09 1.00 ---ND ND ND 0.10 J ND ND ND 0.16 J 0.32 J 0.34 J ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 2 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Cadmium 05/23/97 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 2 µg/L 06/16/97 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 1.00 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 1.00 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 1.00 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 1.00 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 1.00 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 1.00 ND NI ND ND ND ND ---NI NI NI NI ND03/19/04 --- 1.00 ---NI ------------ND NI NI NI NI ND
04/28/04 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND01/26/06 --- 1.00 ---NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 1.00 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 1.00 1.0 NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 1.00 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 1.00 Dry NI ND ND ND ND ND NI NI NI NI ND
01/29/09 --- 1.00 Dry NI ND ND ND ND ND NI NI NI NI ND
07/30/09 --- 1.00 1.4 NI 0.2 J 0.24 J 0.197 J 0.3 J 0.13 J NI NI NI NI ND01/14/10 --- 1.00 ---0.46 J 0.2 J 0.39 J ND ND 0.21 J NI NI NI NI ND
07/15/10 --- 1.00 ---ND ND 0.53 J ND ND ND NI NI NI NI ND01/20/11 --- 1.00 ---0.55 J ND ND ND ND ND NI NI NI NI ND
07/14/11 --- 1.00 ---ND ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 1.00 ---0.26 J ND 0.22 J 0.18 J ND ND NI NI NI NI ND05/24/12 --- 1.00 ---NS NS NS NS NS NS 0.07 J 0.3 J ND ND ND
06/28/12 --- 1.00 ---NS NS NS NS NS NS ND 0.2 J ND 0.07 J ND07/25/12 --- 1.00 ---0.16 J 0.1 J 0.09 J 0.09 J 0.1 J ND ND 0.1 J ND 0.11 J ND
08/24/12 --- 1.00 ---NS NS NS NS NS NS ND 0.2 J ND 0.08 J ND
02/04/13 --- 1.00 ---0.17 J 0.1 J 0.22 J ND ND ND ND 0.1 J ND 0.06 J ND07/08/13 --- 1.00 ---0.07 J ND 0.63 J 3.46 ND ND 0.36 J 0.1 J 0.06 J ND ND
Resample > 07/26/13 --- 1.00 ---NS NS NS 0.09 J NS NS NS NS NS NS ND01/21/14 0.06 1.00 ---0.07 J ND 0.23 J ND ND ND ND 0.09 J 0.11 J 0.06 J ND
07/21/14 0.05 1.00 ---ND ND 0.15 J 0.92 J ND ND ND 0.09 J ND 0.06 J ND
01/29/15 0.05 1.00 ---ND 0.09 B 0.11 B 0.05 B 0.06 B 0.09 B ND 0.13 B ND 0.18 B 0.06 J07/27/15 0.1 1.00 ---ND ND 0.17 J 0.14 J ND ND ND 0.10 J 0.13 J ND ND
01/26/16 0.1 1.00 ---ND ND 0.12 J ND ND ND ND 0.20 J ND ND ND07/26/16 0.1 1.00 ---1.11 0.25 J ND 0.18 J ND 0.19 J ND ND ND ND ND
02/01/17 0.1 1.00 ---ND 0.30 J ND ND 0.19 J ND ND ND 0.34 J 0.16 J ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 3 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Chromium 05/23/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 10 µg/L 06/16/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 10.0 20 NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 10.0 ---NI ------------ND NI NI NI NI ND04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 3.80 J NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND01/29/09 --- 10.0 Dry NI 0.76 J ND 0.563 J ND 0.68 J NI NI NI NI ND
07/30/09 --- 10.0 6.02 J NI 0.77 J ND 1.1 J 2.62 J 1.41 J NI NI NI NI ND01/14/10 --- 10.0 ---3.64 J ND ND ND 2.10 J ND NI NI NI NI ND
07/15/10 --- 10.0 ---2.42 J ND ND ND ND 1.59 J NI NI NI NI ND
01/20/11 --- 10.0 ---2.43 J ND ND ND ND ND NI NI NI NI ND
07/14/11 --- 10.0 ---3.35 J ND ND ND 1.4 J 1.49 J NI NI NI NI ND
01/30/12 --- 10.0 ---2.11 B ND 1.64 B 0.6 B 1.04 B 1.64 B NI NI NI NI 1.16 J05/24/12 --- 10.0 ---NS NS NS NS NS NS 3.23 B 1.7 B 6.06 B 1.97 B 1.26 J
06/28/12 --- 10.0 ---NS NS NS NS NS NS 6.91 B 2.9 B 4.20 B 1.88 B 1.24 J07/25/12 --- 10.0 ---2.85 J 0.81 J ND 2.56 J ND 0.84 J 1.76 J ND 1.78 J ND ND
08/24/12 --- 10.0 ---NS NS NS NS NS NS 5.37 J 3.9 J 5.45 J 1.11 J ND
02/04/13 --- 10.0 ---3.86 B 2.74 B 3.32 B ND ND 1.98 B 2.93 B ND ND ND 2.66 J07/08/13 --- 10.0 ---11.20 B 2.64 B 1.19 B ND ND 2.61 B 2.08 B ND 13.40 B 3.97 B 1.50 J
01/21/14 0.58 10.0 ---6.54 B 2.10 B 0.72 B ND ND 4.51 B ND ND 7.59 B 1.39 B 1.52 J07/21/14 0.73 10.0 ---1.45 B ND ND ND ND ND ND ND 1.12 B ND 1.40 J
01/29/15 0.73 10.0 ---0.85 J 1.62 J ND ND 6.53 J 1.65 J ND ND 6.78 J ND ND
07/27/15 0.43 10.0 ---2.31 J ND ND ND ND 1.03 J 1.33 J ND 1.05 J ND ND01/26/16 0.43 10.0 ---2.96 J 0.58 J ND 0.45 J 0.80 J 2.52 J 1.44 J 1.63 J 3.82 J 0.44 J ND
07/26/16 0.43 10.0 ---2.00 J ND ND ND 0.67 J 3.04 J 1.38 J 0.91 J 3.18 J ND ND02/01/17 0.43 10.0 ---2.16 J 0.54 J ND 1.34 J 3.10 J 7.17 J 1.12 J 1.29 J 2.58 J 0.81 J ND
Cobalt 05/23/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
GWPS = 1 µg/L 06/16/97 --- 10.0 ND NI 10.0 ND ND ND ---NI NI NI NI ND
08/14/97 --- 10.0 10.0 NI ND ND ND ND ---NI NI NI NI ND09/30/97 --- 40.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/30/98 --- 40.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 40.0 ND NI ND ND ND ND ---NI NI NI NI ND04/08/99 --- 40.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/09/99 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/13/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/17/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/18/01 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/29/02 --- 10.0 Dry NI ND 20.0 20.0 20.0 ---NI NI NI NI ND
10/23/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/14/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/30/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 10.0 ---NI ------------ND NI NI NI NI ND
04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 10.0 ND NI 15.0 ND ND ND ND NI NI NI NI ND07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/22/07 --- 10.0 ND NI 16.4 ND ND 2.70 J ND NI NI NI NI ND
04/10/07 --- 10.0 ---NI 8.10 J ------------NI NI NI NI ND07/23/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 10.0 Dry NI ND 3.20 J ND 3.10 J ND NI NI NI NI ND01/29/09 --- 10.0 Dry NI 4.63 J 1.53 J ND 1.87 J ND NI NI NI NI ND
07/30/09 --- 10.0 2.55 J NI 1.85 J 2.37 J ND 2.91 J ND NI NI NI NI ND01/14/10 --- 10.0 ---0.76 J 3.00 J 2.45 J ND 1.82 J ND NI NI NI NI ND
07/15/10 --- 10.0 ---ND 2.25 J 1.84 J ND 2.21 J ND NI NI NI NI ND
01/20/11 --- 10.0 ---ND 2.46 J 2.43 J ND ND ND NI NI NI NI ND07/14/11 --- 10.0 ---ND 2.33 J 1.31 J ND 1.61 J ND NI NI NI NI ND
01/30/12 --- 10.0 ---0.18 J 4.0 J 3.66 J 0.3 J 0.5 J 0.24 J NI NI NI NI ND05/24/12 --- 10.0 ---NS NS NS NS NS NS 26.2 19.0 0.93 J 2.94 J ND
06/28/12 --- 10.0 ---NS NS NS NS NS NS 25.1 14.5 0.17 J 2.27 J ND
07/25/12 --- 10.0 ---0.44 J 1.6 J 3.54 J 1.14 J 1.8 J 0.22 J 31.5 19.4 1.12 J 2.13 J ND08/24/12 --- 10.0 ---NS NS NS NS NS NS 29.6 16.9 1.12 J 3.85 J ND
02/04/13 --- 10.0 ---0.24 J 4.1 J 2.18 J 1.02 J 0.6 J 0.29 J 19.7 11.2 0.61 J 3.00 J ND07/08/13 --- 10.0 ---2.73 J 3.62 J 1.88 J 0.57 J 1.23 J 0.39 J 12.5 10.7 10.6 8.14 J ND
01/21/14 0.12 10.0 ---0.53 J 6.24 J 4.29 J 0.32 J 0.68 J 0.65 J 13.7 11.2 3.11 J 3.49 J ND
07/21/14 0.26 10.0 ---ND 2.21 J 1.87 J 0.36 J 0.86 J ND 16.8 20.7 4.51 J 11.5 ND01/29/15 0.26 10.0 ---ND 25.8 3.72 J 0.27 J 0.63 J 0.28 J 8.34 J 16.5 20.3 4.50 J ND
07/27/15 0.29 10.0 ---ND 0.93 J 0.80 J ND ND ND 7.55 J 16.1 5.50 J 3.37 J ND01/26/16 0.29 10.0 ---ND 5.06 J 5.58 J ND 1.03 J ND 6.89 J 14.2 8.81 J 4.76 J ND
07/26/16 0.29 10.0 ---ND 1.73 J 1.04 J ND 1.38 J ND 6.33 J 12.6 3.70 J 3.84 J ND
02/01/17 0.29 10.0 ---ND 5.20 J 6.70 J ND 4.94 J 0.41 J 4.18 J 13.5 3.84 J 7.89 J ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 4 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Copper 05/23/97 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND
NC 2L = 1000 µg/L 06/16/97 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND08/14/97 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND
09/30/97 --- 20 Dry NI ND ND ND ND --- NI NI NI NI 3004/30/98 --- 20 ND NI ND ND ND ND --- NI NI NI NI ND09/15/98 --- 20 ND NI ND ND ND ND --- NI NI NI NI ND
04/08/99 --- 20 ND NI ND ND ND ND --- NI NI NI NI ND09/09/99 --- 200 Dry NI ND ND ND ND --- NI NI NI NI ND
04/13/00 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND10/17/00 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND
04/23/01 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND10/18/01 --- 200 Dry NI ND ND ND ND --- NI NI NI NI ND04/29/02 --- 200 Dry NI ND ND ND ND --- NI NI NI NI ND
10/23/02 --- 200 Dry NI ND ND ND ND --- NI NI NI NI ND04/14/03 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND
10/30/03 --- 200 ND NI ND ND ND ND --- NI NI NI NI ND03/19/04 --- 200 --- NI --- --- --- --- ND NI NI NI NI ND04/28/04 --- 200 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 200 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 200 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 200 ND NI ND ND ND ND ND NI NI NI NI ND01/26/06 --- 200 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 200 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 3.30 B NI 10.5 8.20 J 0.8 B ND 3.60 B NI NI NI NI 0.90 J07/23/07 --- 10.0 2.70 B NI 111 ND ND ND 3.20 B NI NI NI NI 1.20 J
01/10/08 --- 10.0 Dry NI 35.0 ND ND ND 3.20 J NI NI NI NI ND07/21/08 --- 10.0 Dry NI 122 ND ND ND 3.10 J NI NI NI NI ND01/29/09 --- 10.0 Dry NI 8.77 J ND ND ND 2.61 J NI NI NI NI ND
07/30/09 --- 10.0 11.30 NI 79.6 ND ND ND 4.42 B NI NI NI NI 1.48 J01/14/10 --- 10.0 --- ND 27.2 ND ND ND ND NI NI NI NI ND
07/15/10 --- 10.0 --- ND 168 ND ND ND 5.08 J NI NI NI NI ND01/20/11 ---10.0 ---2.09 B 53 2.82 B ND ND 4.48 B NI NI NI NI 2.16 J07/14/11 --- 10.0 ---2.19 B 151 ND ND ND 4.83 B NI NI NI NI 1.85 J
01/30/12 --- 10.0 ---1.77 J 127 4.79 J 1.45 J 1.44 J 2.55 J NI NI NI NI ND05/24/12 --- 10.0 ---NS NS NS NS NS NS 3.09 J 4.24 J 2.66 J 2.51 J ND
06/28/12 --- 10.0 ---NS NS NS NS NS NS 2.37 J 5.52 J 1.52 J 2.62 J ND07/25/12 --- 10.0 ---1.55 B 142 2.82 B 2.03 B 1.52 B 3.21 B 1.6 J 4.09 J 2.24 J 2.79 J 0.36 J08/24/12 --- 10.0 ---NS NS NS NS NS NS 2.02 J 7.03 J 4.58 J 4.02 J 0.44 J
02/04/13 --- 10.0 ---1.29 B 126 19.80 2.71 J 0.94 B 2.89 J 1.55 B 4.06 J 1.63 B 3.10 J 0.19 J07/08/13 --- 10.0 ---8.05 J 545 7.29 J 6.67 J 1.04 J 3.58 J 2.33 J 2.36 J 7.58 J 5.11 J ND
01/21/14 0.38 10.0 ---2.03 J 66.6 6.00 J 2.10 J 0.74 J 6.88 J 1.14 J 2.28 J 3.19 J 2.66 J ND07/21/14 0.22 10.0 ---1.28 B 1550 4.61 J 3.14 J 0.67 B 2.98 J 1.12 B 2.23 J 3.33 J 2.51 J 0.44 J
Resample > 08/20/14 0.22 10.0 ------654 B ------------------------778
01/29/15 0.22 10.0 ---0.77 B 87.3 1.00 B 0.89 B 0.68 B 3.19 B 0.81 B 1.90 B 3.56 B 3.38 B 4.34 J07/27/15 0.41 10.0 ---1.07 B 31.8 2.38 B 0.63 B ND 2.75 B ND 1.57 B 0.72 B 4.30 B 1.24 J
01/26/16 0.41 10.0 ---0.73 B 32.6 0.44 B 2.24 B 0.44 B 5.56 B ND 2.11 B 1.25 B 2.73 B 3.93 J07/26/16 0.41 10.0 ---6.11 B 14.9 B 0.88 B 3.71 B 0.56 B 5.55 B ND 2.38 B 1.08 B 5.75 B 6.73 J
02/01/17 0.41 10.0 ---2.13 B 29.2 6.57 B 4.47 B 2.27 B 5.95 B ND 2.21 B 0.70 B 4.45 B 1.04 J
Lead 05/23/97 --- 10.0 10.0 NI 10.0 ND ND ND ---NI NI NI NI ND
NC 2L = 15 µg/L 06/16/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 15.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/30/98 --- 15.0 ND NI ND ND ND ND ---NI NI NI NI ND09/15/98 --- 15.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 15.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/09/99 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/18/01 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/29/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 10.0 10.0 NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND03/19/04 --- 10.0 ---NI ------------ND NI NI NI NI ND
04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/26/06 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 ND NI ND ND ND 3.80 J ND NI NI NI NI ND07/23/07 --- 10.0 4.10 J NI ND ND ND 2.10 J 3.20 J NI NI NI NI ND
01/10/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 10.0 Dry NI 3.90 J ND ND ND 2.50 J NI NI NI NI ND
01/29/09 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/30/09 --- 10.0 1.98 J NI 12.70 ND 2.57 J 4.39 J 3.75 J NI NI NI NI ND01/14/10 --- 10.0 ---1.23 J 8.25 J 1.34 J 1.34 J 1.96 J ND NI NI NI NI ND
07/15/10 --- 10.0 ---ND 10.90 ND ND ND 3.05 J NI NI NI NI ND01/20/11 --- 10.0 ---ND 23.50 ND ND ND ND NI NI NI NI ND
02/18/11 --- 10.0 ------10.20 ------------NI NI NI NI ND
07/14/11 --- 10.0 ---ND 12.50 ND ND 2.24 J ND NI NI NI NI ND01/30/12 --- 10.0 ---ND 4.4 J 0.32 J 0.25 J ND 0.65 J NI NI NI NI ND
05/24/12 --- 10.0 ---NS NS NS NS NS NS 0.53 J 0.24 J 5.10 J 0.24 J ND06/28/12 --- 10.0 ---NS NS NS NS NS NS 0.4 J 0.30 J 0.59 J 0.23 J ND
07/25/12 --- 10.0 ---0.25 B 4.4 J 0.17 B 0.61 B 0.3 B 0.66 B 0.12 J 0.10 J 1.21 J 0.25 J 0.29 J
08/24/12 --- 10.0 ---NS NS NS NS NS NS 0.28 J 0.10 J 1.03 J 0.24 J ND02/04/13 --- 10.0 ---0.18 J 11.5 1.73 J 0.95 J 0.2 J 0.79 J 0.16 J ND 0.18 J 0.10 J ND
07/08/13 --- 10.0 ---4.97 J 4.7 J 0.85 J 4.86 J 0.1 B 1.73 J 4.92 J 1.6 J 9.46 J 0.89 J 0.09 J01/21/14 0.05 10.0 ---0.46 J 3.34 J 0.34 J 0.35 J 0.08 J 3.87 J ND 0.22 J 1.73 J 0.16 J ND
07/21/14 0.05 10.0 ---0.07 J 2.45 J 0.42 J 0.21 J 0.05 J 0.57 J 0.07 J 0.19 J 1.03 J 0.19 J ND01/29/15 0.05 10.0 ---ND 3.44 J ND 0.08 J ND 2.05 J ND ND 3.81 J 0.10 J ND
07/27/15 0.08 10.0 ---0.10 J 0.79 J ND ND ND 0.39 J ND 0.12 J 0.59 J 0.13 J ND
01/26/16 0.08 10.0 ---0.24 J 0.61 J ND 3.97 J 0.09 J 1.14 J ND 0.34 J 1.71 J ND ND07/26/16 0.08 10.0 ---0.25 J 0.72 J ND 4.00 J ND 0.54 J ND 0.29 J 1.71 J ND ND
02/01/17 0.08 10.0 ---ND 2.20 J ND 1.83 J 0.53 J 0.32 J ND 0.56 J 1.40 J 0.13 J ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 5 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Nickel 05/23/97 --- 50.0 10.0 NI 10.0 ND ND ND ---NI NI NI NI ND
NC 2L = 100 µg/L 06/16/97 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 50.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 50.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 50.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 50.0 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 50.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 50.0 10.0 NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 50.0 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 50.0 ---NI ------------ND NI NI NI NI ND04/28/04 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 50.0 ---NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 50.0 2.80 J NI 6.30 J ND ND 2.70 J 5.90 J NI NI NI NI ND07/23/07 --- 50.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 50.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 50.0 Dry NI 3.90 J ND ND ND 4.10 J NI NI NI NI ND01/29/09 --- 50.0 Dry NI 2.89 J ND ND 2.39 J 1.88 J NI NI NI NI ND
07/30/09 --- 50.0 6.29 J NI 3.71 J 0.90 J 0.724 J 7.34 J 4.29 J NI NI NI NI ND01/14/10 --- 50.0 ---3.95 J ND 1.60 J ND 4.57 J ND NI NI NI NI ND
07/15/10 --- 50.0 ---3.23 J 2.97 J ND ND ND ND NI NI NI NI ND
01/20/11 --- 50.0 ---4.61 J 2.10 J ND ND 2.22 J ND NI NI NI NI ND07/14/11 --- 50.0 ---5.41 J 3.31 J ND ND ND ND NI NI NI NI ND
01/30/12 --- 50.0 ---6.99 J 2.11 J 5.12 J 3.42 J 3.43 J 1.54 J NI NI NI NI ND05/24/12 --- 50.0 ---NS NS NS NS NS NS 18.5 J 9.27 J 4.00 J 6.40 J ND
06/28/12 --- 50.0 ---NS NS NS NS NS NS 31.4 J 13.30 J 3.36 J 5.72 J ND
07/25/12 --- 50.0 ---6.55 J 2.65 J 3.47 J 4.21 J 3.62 J 1.36 J 15.6 J 6.76 J 3.14 J 5.59 J ND08/24/12 --- 50.0 ---NS NS NS NS NS NS 18.1 J 22.10 J 16.10 J 10.80 J ND
02/04/13 --- 50.0 ---6.92 J 1.89 J 4.77 J 5.35 J 3.09 J 1.80 J 7.59 J 11.30 J 3.40 J 4.45 J ND
07/08/13 --- 50.0 ---9.66 B 2.58 B 5.66 B 6.03 B 3.29 B 2.26 B 1.56 B 4.62 B 11.10 J 5.62 B 1.99 J01/21/14 0.41 50.0 ---5.93 J 2.08 J 5.35 J 3.28 J 2.72 J 7.75 J 1.78 J 8.46 J 8.53 J 5.99 J ND
07/21/14 0.22 50.0 ---3.74 J 3.85 J 3.55 J 5.52 J 2.87 J 1.70 J 1.66 J 6.42 J 3.93 J 6.21 J ND
01/29/15 0.22 50.0 ---3.78 J 5.34 J 2.05 J 2.33 J 3.62 J 2.19 J 1.51 J 5.44 J 6.22 J 5.45 J ND07/27/15 0.48 50.0 ---3.21 J 1.14 J 0.56 J ND ND 1.07 J 0.84 J 4.62 J 2.54 J 4.13 J ND
01/26/16 0.48 50.0 ---5.08 J 2.12 J ND 0.56 J 1.17 J 3.55 J 1.39 J 4.89 J 5.35 J 4.55 J ND07/26/16 0.48 50.0 ---4.28 J 1.77 J ND 0.97 J 1.92 J 5.70 J 0.86 J 5.26 J 3.15 J 4.60 J ND
02/01/17 0.48 50.0 ---4.39 J 3.10 J ND 1.32 J 5.03 J 27.50 J 1.12 J 5.87 J 2.85 J 9.98 J ND
Selenium 05/23/97 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 20 µg/L 06/16/97 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND09/30/97 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/30/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND09/15/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 20.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/13/00 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/17/00 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND04/23/01 --- 20.0 ND NI ND ND ND 40.0 ---NI NI NI NI ND
10/18/01 --- 20.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 20.0 Dry NI ND ND ND ND ---NI NI NI NI ND10/23/02 --- 20.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/14/03 --- 20.0 ND NI ND ND ND ND ---NI NI NI NI ND10/30/03 --- 20.0 ND NI ND 20.0 ND ND ---NI NI NI NI ND
03/19/04 --- 20.0 ---NI ------------ND NI NI NI NI ND04/28/04 --- 20.0 ND NI ND ND ND ND ND NI NI NI NI ND10/27/04 --- 20.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 20.0 ND NI ND ND ND ND ND NI NI NI NI ND07/21/05 --- 20.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 20.0 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 20.0 ND NI ND ND ND ND ND NI NI NI NI ND01/22/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/23/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/10/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND01/29/09 --- 10.0 Dry NI ND 5.23 J 6.79 J ND ND NI NI NI NI ND07/30/09 --- 10.0 ND NI ND 3.60 J 4.89 J ND ND NI NI NI NI ND
01/14/10 --- 10.0 ---ND ND 1.37 J 1.45 J ND ND NI NI NI NI ND07/15/10 --- 10.0 ---ND ND ND ND ND 3.45 B NI NI NI NI 4.36 J
01/20/11 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND07/14/11 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND01/30/12 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND
05/24/12 --- 10.0 ---NS NS NS NS NS NS 1.26 J ND ND ND ND06/28/12 --- 10.0 ---NS NS NS NS NS NS 0.79 J 0.56 J ND ND ND
07/25/12 --- 10.0 ---ND ND ND 0.65 J ND ND 2.93 J 1.19 J ND ND ND08/24/12 --- 10.0 ---NS NS NS NS NS NS 3.68 J 0.78 J ND ND ND02/04/13 --- 10.0 ---ND ND 1.08 J 0.9 J ND ND 3.6 J 0.84 J ND ND ND
07/08/13 --- 10.0 ---ND ND ND ND ND ND 3.25 J ND ND ND ND01/21/14 0.77 10.0 ---ND ND ND ND ND ND 3.60 B ND ND ND 2.20 J
07/21/14 1.01 10.0 ---ND 1.09 B 1.74 B 1.74 B ND ND 8.69 B 2.10 B 1.81 B 1.27 B 2.88 J01/29/15 1.01 10.0 ---ND 2.44 J ND ND ND ND 2.44 J ND ND ND ND07/27/15 0.85 10.0 ---ND ND ND ND ND ND 1.74 J ND ND ND ND
01/26/16 0.85 10.0 ---ND ND ND 0.87 J ND ND 0.88 J ND 1.23 J ND ND07/26/16 0.85 10.0 ---ND ND ND 1.00 J ND ND 1.09 J ND ND ND ND
02/01/17 0.85 10.0 ---ND ND 1.06 J 1.10 J ND ND 0.90 J ND ND ND ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 6 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Silver 07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
NC 2L = 20 µg/L 01/26/06 --- 10.0 ---NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 10.0 Dry NI ND ND ND ND ND NI NI NI NI ND01/29/09 --- 10.0 Dry NI 1.47 J ND ND ND ND NI NI NI NI ND
07/30/09 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/14/10 --- 10.0 ---ND 0.79 J 2.29 J ND ND ND NI NI NI NI ND
07/15/10 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND
01/20/11 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND07/14/11 --- 10.0 ---ND ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 10.0 ---0.23 J 0.50 J 3.63 J ND 0.14 J ND NI NI NI NI ND05/24/12 --- 10.0 ---NS NS NS NS NS NS ND ND ND ND ND
06/28/12 --- 10.0 ---NS NS NS NS NS NS ND 0.54 J 0.16 J ND ND
07/25/12 --- 10.0 ---0.43 J 1.99 J 4.03 J 0.7 J 0.35 J ND 0.54 J ND ND ND ND08/24/12 --- 10.0 ---NS NS NS NS NS NS 0.12 J ND 0.12 J 0.11 J ND
02/04/13 --- 10.0 ---0.69 J 0.62 J 6.42 J 0.24 J ND ND 0.14 J ND 0.49 J 0.10 J ND07/08/13 --- 10.0 ---0.35 J 0.59 J 1.09 J 4.3 J ND ND ND ND ND ND ND
01/21/14 0.24 10.0 ---2.30 J 0.84 J 0.57 J 0.38 J ND ND ND ND ND ND ND
07/21/14 0.17 10.0 ---0.55 J 0.56 J 0.56 J ND ND ND ND 0.35 J ND ND ND01/29/15 0.17 10.0 ---0.24 J 3.13 J ND ND 0.35 J ND 0.33 J 0.17 J 0.41 J 1.54 J ND
07/27/15 0.22 10.0 ---0.32 J ND 0.40 J ND ND ND ND ND 0.36 J ND ND01/26/16 0.22 10.0 ---0.77 J ND ND 0.49 J 0.36 J ND ND ND ND ND ND
07/26/16 0.22 10.0 ---0.44 J ND ND 0.40 J 0.43 J ND ND ND ND ND ND
02/01/17 0.22 10.0 ---ND 2.69 J ND 0.33 J 6.69 J ND ND ND ND ND ND
Thallium 05/23/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
GWPS = 0.2 µg/L 06/16/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
08/14/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND09/30/97 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/30/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND04/08/99 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/09/99 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/13/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/17/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/18/01 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/29/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND10/23/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/14/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND03/19/04 --- 10.0 ---NI ------------ND NI NI NI NI ND
04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/26/06 --- 10.0 Dry NI ND ND ND 10.00 ND NI NI NI NI ND
07/21/06 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND01/22/07 --- 5.50 ND NI ND ND ND ND ND NI NI NI NI ND
07/23/07 --- 5.50 ND NI ND ND ND ND ND NI NI NI NI 0.05 J
01/10/08 --- 5.50 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 5.50 Dry NI ND ND ND ND ND NI NI NI NI ND
01/29/09 --- 5.50 Dry NI ND ND 0.053 J ND ND NI NI NI NI ND07/30/09 --- 5.50 ND NI ND ND ND ND ND NI NI NI NI ND
01/14/10 --- 5.50 ---ND ND ND ND ND ND NI NI NI NI ND
07/15/10 --- 5.50 ---ND ND ND ND ND ND NI NI NI NI ND01/20/11 --- 5.50 ---ND ND ND ND ND ND NI NI NI NI ND
07/14/11 --- 5.50 ---ND ND ND ND ND ND NI NI NI NI ND01/30/12 --- 5.50 ---ND ND ND ND ND ND NI NI NI NI ND
05/24/12 --- 5.50 ---NS NS NS NS NS NS ND ND ND ND ND
06/28/12 --- 5.50 ---NS NS NS NS NS NS ND ND ND ND ND07/25/12 --- 5.50 ---ND ND ND ND ND ND ND ND ND ND ND
08/24/12 --- 5.50 ---NS NS NS NS NS NS ND ND ND ND ND02/04/13 --- 5.50 ---ND ND ND ND ND ND ND ND ND ND ND
07/08/13 --- 5.50 ---ND ND ND ND ND ND ND ND 0.08 J ND ND
01/21/14 0.06 5.50 ---0.20 J ND ND ND ND ND ND ND ND ND ND07/21/14 0.09 5.50 ---ND ND ND ND ND ND ND ND ND ND ND
01/29/15 0.09 5.50 ---ND ND ND ND ND ND ND ND 0.11 J ND ND07/27/15 0.06 5.50 ---ND 0.38 J 0.09 J ND ND ND 0.15 J ND ND ND 5.50
01/26/16 0.06 5.50 ---0.08 J ND ND ND ND ND ND ND 0.07 J ND ND
07/26/16 0.06 5.50 ---0.10 J ND ND ND ND ND ND ND ND ND ND02/01/17 0.06 5.50 ---ND ND ND ND ND ND ND 0.07 J ND ND ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 7 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Vanadium 05/23/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
GWPS = 0.3 µg/L 06/16/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/08/99 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 10.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 10.0 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 10.0 ---NI ------------ND NI NI NI NI ND04/28/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 10.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 40.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 40.0 ---NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 40.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 25.0 2.80 J NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 25.0 2.30 J NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 25.0 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 25.0 Dry NI ND ND ND ND 1.60 J NI NI NI NI ND01/29/09 --- 25.0 Dry NI 1.45 J 1.44 J ND ND 1.32 J NI NI NI NI ND
07/30/09 --- 25.0 4.29 J NI ND ND ND ND 1.92 J NI NI NI NI ND01/14/10 --- 25.0 ---4.35 J ND ND ND ND 1.22 J NI NI NI NI ND
07/15/10 --- 25.0 ---2.28 J ND ND ND ND 2.16 J NI NI NI NI ND
01/20/11 --- 25.0 ---2.13 J ND ND ND ND ND NI NI NI NI ND07/14/11 --- 25.0 ---1.98 J ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 25.0 ---ND ND ND ND ND ND NI NI NI NI ND05/24/12 --- 25.0 ---NS NS NS NS NS NS 3.07 J ND 4.78 J ND ND
06/28/12 --- 25.0 ---NS NS NS NS NS NS 2.74 J ND ND ND ND
07/25/12 --- 25.0 ---3.45 J 2.15 J 2.28 J ND 2.77 J 4.04 J 5.98 J ND 4.58 J ND ND08/24/12 --- 25.0 ---NS NS NS NS NS NS 8.35 J ND 3.94 J ND ND
02/04/13 --- 25.0 ---3.72 B 2.34 B 6.74 B ND ND 3.51 B 3.75 J ND ND ND 2.12 J07/08/13 --- 25.0 ---7.94 J ND ND ND ND 11.30 J ND ND 17.10 J ND ND
01/21/14 1.97 25.0 ---10.8 B 9.42 B ND ND ND 4.48 B ND ND 3.28 B ND 14.6 J07/21/14 0.93 25.0 ---3.01 B ND 3.50 B ND 2.85 B 1.70 B 3.73 B ND 4.34 B 1.40 B 1.69 J01/29/15 0.93 25.0 ---ND 1.79 J 1.02 J ND ND ND ND ND 10.20 J ND ND
07/27/15 1.57 25.0 ---ND ND 2.19 J ND ND 2.08 J ND ND 1.94 J ND ND
01/26/16 1.57 25.0 ---3.05 J ND ND ND ND ND ND ND 3.33 J ND ND
07/26/16 1.57 25.0 ---2.47 J ND 1.61 J ND ND ND ND ND 4.04 J ND ND02/01/17 1.57 25.0 ---2.68 J ND ND ND ND ND ND ND 2.61 J ND ND
Zinc 05/23/97 --- 50 50 NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 1000 µg/L 06/16/97 --- 50 100 NI ND ND ND 130 ---NI NI NI NI 60008/14/97 --- 50 110 NI 90 ND 70 ND ---NI NI NI NI ND
09/30/97 --- 20 Dry NI ND 30 50 30 ---NI NI NI NI 140
04/30/98 --- 20 70 NI 40 70 90 ND ---NI NI NI NI 10009/15/98 --- 20 ND NI ND ND 50 30 ---NI NI NI NI ND
04/08/99 --- 20 30 NI 20 20 ND 40 ---NI NI NI NI ND09/09/99 --- 50 Dry NI 100 80 60 60 ---NI NI NI NI 60
04/13/00 --- 50 80 NI ND ND ND ND ---NI NI NI NI ND
10/17/00 --- 50 ND NI ND ND ND ND ---NI NI NI NI ND04/23/01 --- 50 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 50 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 50 Dry NI ND ND 70 ND ---NI NI NI NI ND
10/23/02 --- 50 Dry NI ND ND ND 60 ---NI NI NI NI ND
04/14/03 --- 50 170 NI ND ND ND ND ---NI NI NI NI ND10/30/03 --- 50 ND NI ND ND ND 80 ---NI NI NI NI ND
03/19/04 --- 50 ---NI ------------ND NI NI NI NI ND04/28/04 --- 50 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 50 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 50 ND NI ND ND ND ND ND NI NI NI NI ND07/21/05 --- 50 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 50 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 50 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 10.0 7.0 J NI 35.1 ND ND 3.9 J 9.4 J NI NI NI NI ND
07/23/07 --- 10.0 22.3 NI 168.0 ND ND 11.70 B 14.9 B NI NI NI NI 4.0 J01/10/08 --- 10.0 Dry NI 54.9 ND ND 3.1 J 7.6 J NI NI NI NI ND
07/21/08 --- 10.0 Dry NI 411 ND ND 4.7 J 15.5 NI NI NI NI ND01/29/09 --- 10.0 Dry NI 33.0 ND ND 14.9 B 11.7 B NI NI NI NI 5.8 J
07/30/09 --- 10.0 39.3 NI 509 5.19 J ND 7.2 J 12.5 NI NI NI NI ND
01/14/10 --- 10.0 ---12.80 91.5 6.46 J ND 3.4 J 12.2 NI NI NI NI ND07/15/10 --- 10.0 ---5.32 J 431 ND ND 8.3 J 12.1 NI NI NI NI ND
01/20/11 --- 10.0 ---ND 179 ND ND ND 6.06 J NI NI NI NI ND07/14/11 --- 10.0 ---4.04 J 423 ND ND 4.0 J 10.10 NI NI NI NI ND
01/30/12 --- 10.0 ---6.39 B 103 2.91 B 5.03 B 2.8 B 6.75 B NI NI NI NI 3.00 J
05/24/12 --- 10.0 ---NS NS NS NS NS NS 11 B 14.8 B 20.2 B 8.3 B 2.38 J06/28/12 --- 10.0 ---NS NS NS NS NS NS 5.91 B 14.4 B 6.3 B 7.4 B 27.9
07/25/12 --- 10.0 ---4.42 B 103 1.90 B 2.48 B 4.9 B 6.04 B 4.68 B 9.4 B 10.4 B 5.5 B 2.48 J08/24/12 --- 10.0 ---NS NS NS NS NS NS 3.04 B 11.3 B 8.2 B 5.3 B 3.32 J
02/04/13 --- 10.0 ---1.87 B 56.6 4.90 B 3.19 B 1.1 B 5.55 B 1.85 B 8.3 J 3.1 B 4.2 B 0.76 J
07/08/13 --- 10.0 ---21.2 172 5.20 J 11.0 1.2 B 6.73 J 3.12 B 14.5 59.3 5.7 J 0.96 J01/21/14 0.87 10.0 ---4.78 B 30.6 4.85 B 3.69 B 5.07 B 18.3 J 2.45 B 15.0 J 17.0 J 8.36 B 2.35 J
07/21/14 0.64 10.0 ---4.90 B 504 1.86 B 1.51 B 1.45 B 5.32 B 1.76 B 14.4 10.3 5.84 B 1.93 J01/29/15 0.64 10.0 ---2.88 B 18.3 1.31 B 1.79 B 2.28 B 7.32 B 2.56 B 17.9 28.5 7.43 B 1.54 J
07/27/15 1.30 10.0 ---4.63 B 5.19 B 2.89 B 1.66 B ND 4.51 B ND 11.8 6.87 B 7.86 J 1.57 J
01/26/16 1.30 10.0 ---3.65 B 12.4 ND 3.13 B 1.66 B 9.31 J ND 13.0 8.74 J 5.34 B 1.35 J07/26/16 1.30 10.0 ---23.4 10.7 2.32 B 4.78 B 2.88 B 7.12 B 1.73 B 13.3 7.31 B 7.05 B 1.60 J
02/01/17 1.30 10.0 ---4.19 B 24.8 2.34 B 3.93 B 6.52 B 8.59 B 2.37 B 10.9 B 9.02 B 8.09 B 1.54 J
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 8 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Iron 07/23/07 --- 300 2200 NI 20 44 20 7340 676 NI NI NI NI ND
NC 2L = 300 µg/L 01/10/08 --- 300 Dry NI 38 J 71 J ND 4600 575 NI NI NI NI ND07/21/08 --- 300 Dry NI 184 J 47 J ND 10400 1950 NI NI NI NI ND
01/29/09 --- 300 Dry NI 622 142 J 56.1 B 3520 585 NI NI NI NI 33.80 J07/30/09 --- 300 2540 NI 114 J 92 J 95 J 10900 851 NI NI NI NI ND
01/14/10 --- 300 ---1630 249 J 222 J 87 J 5200 597 NI NI NI NI ND
07/15/10 --- 300 ---517 185 J 84 J 47.7 J 7880 1350 NI NI NI NI ND01/20/11 --- 300 ---359 325 106 J 60.4 J 2000 489 NI NI NI NI ND
07/14/11 --- 300 ---490 239 J 97 J 64.6 J 3220 773 NI NI NI NI ND01/30/12 --- 40.0 ---146 189 775 446 1760 722 NI NI NI NI 8.11 J
07/25/12 --- 40.0 ---221 157 1400 4590 10200 708 NS NS NS NS 4.71 J
02/04/13 --- 30.0 ---156 318 1790 5430 1840 950 83700 50.90 B 203 186 5.53 J07/08/13 --- 30.0 ---5280 204 7180 2160 1500 1050 45600 44.50 14300 1440 ND
01/21/14 3.02 30.0 ---783 457 7990 1060 1590 2540 87000 132 3730 271 4.96 J07/21/14 3.1 40.0 ---93.8 138 2120 1700 3000 860 81900 178 1810 1930 ND
01/29/15 3.10 40.0 ---63.0 2950 656 579 1720 726 65900 82.1 14400 225 4.34 J
07/27/15 5.72 40 ---140 153 168 104 561 201 89900 14.9 J 3810 103 ND01/26/16 5.72 300 ---253 J 197 J 249 J 1050 3430 408 98300 209 J 9020 231 J 9.50 J
07/26/16 5.72 300 ---102 J 104 J 194 J 1100 2340 208 J 106000 169 J 10400 180 J ND02/01/17 5.72 300 ---51.7 B 346 614 536 7570 175 J 90900 316 2600 578 12.2 J
Manganese 07/23/07 --- 50.0 77.70 NI 31.6 J 314 59.2 4130 21.4 J NI NI NI NI ND
NC 2L = 50 µg/L 01/10/08 --- 50.0 Dry NI 21.6 J 249 30 J 2130 23.0 J NI NI NI NI ND
07/21/08 --- 50.0 Dry NI 35.8 J 341 41.1 J 4840 23.6 J NI NI NI NI 2.8 J01/29/09 --- 50.0 Dry NI 481 225 25 B 3250 15.6 B NI NI NI NI 13.3 J07/30/09 --- 50.0 48.80 J NI 191 281 55.7 4520 17.1 J NI NI NI NI ND
01/14/10 --- 50.0 ---123 355 294 23.8 J 3680 19.5 J NI NI NI NI ND07/15/10 --- 50.0 ---45.6 J 203 203 45.5 J 3500 25.0 J NI NI NI NI ND
01/20/11 --- 50.0 ---94.3 224 291 26.3 J 1150 10.7 J NI NI NI NI ND07/14/11 --- 50.0 ---83.7 198 167 49.2 3050 13.7 NI NI NI NI 1.16 J01/30/12 --- 10.0 ---27.1 353 273 38 1140 11.0 NI NI NI NI ND
07/25/12 --- 10.0 ---67.2 164 272 218 3690 9.13 J NS NS NS NS ND02/04/13 --- 50.0 ---30.4 J 406 141 393 1560 13.90 J 5190 585 30.3 J 90.2 ND
07/08/13 --- 50.0 ---221 363 182 202 3860 24.20 J 4490 442 636.0 206 0.64 J01/21/14 0.550 50.0 ---101 577 310 52.0 1440 33.2 J 9030 430 184 108 ND07/21/14 0.395 50.0 ---10.7 B 153 72.0 136 2950 10.4 B 13600 920 181 249 2.27 J
01/29/15 0.395 50.0 ---5.60 B 1950 222 25.1 J 1210 48.9 J 6050 561 1610 110 1.33 J07/27/15 1.04 50.0 ---12.9 J 141 51.9 41.0 J 1200 13.6 J 12400 536 214 119 ND
01/26/16 1.04 50.0 ---24.0 J 572 306 26.1 J 2690 28.0 J 12300 514 680 142 ND07/26/16 1.04 50.0 ---14.5 J 228 61.4 40.1 J 3480 19.4 J 14600 460 197 120 ND02/01/17 1.04 50.0 ---9.49 J 623 269.0 42.3 J 9200 26.5 J 7940 446 151 196 ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 9 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Organic Compounds
Acetone 07/25/12 --- 100 --- ND ND ND 29 J ND ND ND ND ND ND NDNC 2L = 6000 µg/L 08/24/12 --- 100 --- NS NS NS NS NS NS ND ND ND ND ND
02/04/13 --- 100 --- ND ND ND ND ND ND ND ND ND ND ND07/08/13 --- 100 --- ND ND ND ND ND ND ND ND ND ND ND
01/21/14 1.6 100 --- ND ND ND ND ND ND ND ND ND ND 3.70 J
07/21/14 5.7 100 --- ND ND ND ND ND ND ND ND ND ND ND01/29/15 5.7 100 --- ND ND ND ND ND ND ND ND ND ND ND
07/27/15 3.1 100 --- ND ND ND ND ND ND ND ND ND ND ND01/26/16 4.9 100 --- ND ND ND ND ND ND 5.5 J ND ND ND ND
07/26/16 4.9 100 --- ND ND ND ND ND ND ND ND ND ND ND
02/01/17 8.2 100 --- ND ND ND ND ND ND ND ND ND ND ND
Benzene 05/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND
NC 2L = 1 µg/L 06/28/12 --- 1.0 ---NS NS NS NS NS NS 0.2 J ND ND ND ND
07/25/12 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
08/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND02/04/13 --- 1.0 ---ND ND ND ND ND ND 0.2 J ND ND ND ND
07/08/13 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND01/21/14 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/21/14 0.2 1.0 ---ND ND ND ND ND ND 0.2 J ND ND ND ND
01/29/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND07/27/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/26/16 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND07/26/16 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
02/01/17 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
Carbon Disulfide 05/23/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 700 µg/L 06/16/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND08/14/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 5 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 5 ND NI ND ND ND 29 ---NI NI NI NI ND
09/15/98 --- 5 ND NI ND ND 120 12 ---NI NI NI NI ND
04/08/99 --- 5 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 100 ---NI ------------ND NI NI NI NI ND04/28/04 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND01/29/09 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND
07/30/09 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND01/14/10 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
07/15/10 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
01/20/11 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND07/14/11 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND05/24/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
06/28/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
07/25/12 --- 100 ---ND ND ND ND ND ND ND ND ND ND ND08/24/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
02/04/13 --- 100 ---ND ND ND ND ND ND ND ND ND ND 3.90 J07/08/13 --- 100 ---ND ND ND ND ND ND ND ND ND ND ND
01/21/14 1.2 100 ---ND ND ND ND ND ND ND ND ND ND ND
07/21/14 0.8 100 ---ND ND ND ND ND ND ND ND ND ND ND01/29/15 0.8 100 ---ND ND ND ND ND ND ND ND ND ND ND
07/27/15 0.3 100 ---ND ND ND ND ND ND ND ND ND ND ND01/26/16 0.9 100 ---ND ND ND ND ND ND ND ND ND ND ND
07/26/16 0.6 100 ---ND ND ND ND ND ND ND ND ND ND ND
02/01/17 0.8 100 ---ND ND ND ND ND ND ND ND ND ND ND
Chloroform 05/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND
NC 2L = 70 µg/L 06/28/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND07/25/12 --- 1.0 ---ND ND ND ND ND ND 0.6 B 0.5 B 0.5 B ND 1.4 J
08/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND 0.6 J02/04/13 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/08/13 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND 2.2 J01/21/14 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND07/21/14 0.2 5.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/29/15 0.2 5.0 ---ND ND ND ND ND ND ND ND ND ND ND07/27/15 0.2 5.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/26/16 0.3 5.0 ---ND ND ND ND ND ND ND ND ND ND ND07/26/16 0.3 5.0 ---ND ND ND ND ND ND ND ND ND ND ND02/01/17 0.6 5.0 ---ND ND ND ND ND ND ND ND ND ND ND
Ethylbenzene 05/24/12 --- 5.0 ---NS NS NS NS NS NS ND ND ND ND ND
NC 2L = 600 µg/L 06/28/12 --- 5.0 ---NS NS NS NS NS NS ND ND ND ND ND
07/25/12 --- 5.0 ---ND ND ND ND ND ND 0.5 J ND ND ND ND08/24/12 --- 5.0 ---NS NS NS NS NS NS ND ND ND ND ND
02/04/13 --- 5.0 ---ND ND ND ND ND ND ND ND ND ND ND07/08/13 --- 5.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/21/14 0.5 5.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/21/14 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND01/29/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/27/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND01/26/16 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/26/16 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
02/01/17 0.4 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
Methylene Chloride 01/26/16 0.5 1 ---ND ND ND ND ND ND ND ND ND ND 0.90 J
07/26/16 0.5 1 ---ND ND ND ND ND ND ND ND ND ND ND
02/01/17 0.5 1 ---ND ND ND ND ND ND ND ND ND ND ND
NC 2L = 5 µg/L
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 10 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Methyl Ethyl Ketone (2-Butanone)05/23/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
06/16/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI NDNC 2L = 4000 µg/L 08/14/97 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
09/30/97 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND04/30/98 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 100 ND NI ND ND 130 ND ---NI NI NI NI ND
04/08/99 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND09/09/99 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND
04/13/00 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND10/17/00 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
10/18/01 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND04/29/02 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND
10/23/02 --- 100 Dry NI ND ND ND ND ---NI NI NI NI ND04/14/03 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 100 ND NI ND ND ND ND ---NI NI NI NI ND
03/19/04 --- 100 ---NI ------------ND NI NI NI NI ND04/28/04 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
10/27/04 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND03/16/05 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/26/06 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/06 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/22/07 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND07/23/07 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND
07/21/08 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND01/29/09 --- 100 Dry NI ND ND ND ND ND NI NI NI NI ND
07/30/09 --- 100 ND NI ND ND ND ND ND NI NI NI NI ND01/14/10 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
07/15/10 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
01/20/11 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND07/14/11 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND
01/30/12 --- 100 ---ND ND ND ND ND ND NI NI NI NI ND05/24/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
06/28/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
07/25/12 --- 100 ---ND ND ND 17.0 J ND ND ND ND ND ND ND08/24/12 --- 100 ---NS NS NS NS NS NS ND ND ND ND ND
02/04/13 --- 100 ---ND ND ND ND ND ND ND ND ND ND ND07/08/13 --- 100 ---ND ND ND ND ND ND ND ND ND ND ND
01/21/14 0.8 100 ---ND ND ND ND ND ND ND ND ND ND 2.7 J
07/21/14 0.8 100 ---ND ND ND ND ND ND ND ND ND ND 1.1 J01/29/15 0.8 100 ---ND ND ND ND ND ND ND ND ND ND ND
07/27/15 0.9 100 ---ND ND ND ND ND ND ND ND ND ND ND01/26/16 1.1 100 ---ND ND ND ND ND ND ND ND ND ND ND
07/26/16 1.1 100 ---ND ND ND ND ND ND ND ND ND ND ND
02/01/17 3.2 100 ---ND ND ND ND ND ND ND ND ND ND ND
Tetrachloroethene 05/23/97 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
NC 2L = 0.7 µg/L 06/16/97 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
08/14/97 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND09/30/97 --- 5.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/30/98 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/15/98 --- 5.0 ND NI ND ND 130 ND ---NI NI NI NI ND04/08/99 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
09/09/99 --- 5.0 Dry NI ND ND ND ND ---NI NI NI NI ND04/13/00 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/17/00 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
04/23/01 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND10/18/01 --- 5.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/29/02 --- 5.0 Dry NI ND ND ND ND ---NI NI NI NI ND10/23/02 --- 5.0 Dry NI ND ND ND ND ---NI NI NI NI ND
04/14/03 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND
10/30/03 --- 5.0 ND NI ND ND ND ND ---NI NI NI NI ND03/19/04 --- 5.0 ---NI ------------ND NI NI NI NI ND
04/28/04 --- 5.0 ND NI ND ND ND ND ND NI NI NI NI ND10/27/04 --- 5.0 ND NI ND ND ND ND ND NI NI NI NI ND
03/16/05 --- 5.0 ND NI ND ND ND ND ND NI NI NI NI ND
07/21/05 --- 5.0 ND NI ND ND ND ND ND NI NI NI NI ND01/26/06 --- 5.0 ---NI ND ND ND ND ND NI NI NI NI ND
07/21/06 --- 5.0 ND NI ND ND ND ND ND NI NI NI NI ND01/22/07 --- 3.0 0.55 J NI 0.30 J ND ND ND ND NI NI NI NI ND
07/23/07 --- 1.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/10/08 --- 1.0 Dry NI ND ND ND ND ND NI NI NI NI ND07/21/08 --- 1.0 Dry NI ND ND ND ND ND NI NI NI NI ND
01/29/09 --- 1.0 Dry NI ND ND ND ND ND NI NI NI NI ND07/30/09 --- 1.0 ND NI ND ND ND ND ND NI NI NI NI ND
01/14/10 --- 1.0 ---ND ND ND ND ND ND NI NI NI NI ND
07/15/10 --- 1.0 ---ND ND ND ND ND ND NI NI NI NI ND01/20/11 --- 1.0 ---ND ND ND ND ND ND NI NI NI NI ND
07/14/11 --- 1.0 ---ND ND ND ND ND ND NI NI NI NI ND01/30/12 --- 1.0 ---ND ND ND ND ND ND NI NI NI NI ND
05/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND
06/28/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND07/25/12 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
08/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND02/04/13 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/08/13 --- 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/21/14 0.4 1.0 ---ND ND ND ND ND ND ND ND 0.7 J ND ND07/21/14 0.4 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
01/29/15 0.4 1.0 ---ND ND ND ND ND ND ND ND ND ND ND07/27/15 0.3 1.0 ---ND 0.70 J ND ND ND ND ND ND 0.60 J ND ND
01/26/16 0.4 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/26/16 0.4 1.0 ---ND ND ND ND ND ND ND ND ND ND ND02/01/17 0.8 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
Toluene 07/25/12 --- 1.0 ---ND ND ND 360 ND ND ND ND ND ND ND08/24/12 --- 1.0 ---NS NS NS NS NS NS ND ND ND ND ND
NC 2L = 600 µg/L 02/04/13 --- 1.0 ---ND ND ND 1.3 ND ND ND ND ND ND ND07/08/13 --- 1.0 ---ND ND ND 3.8 ND ND ND ND ND ND ND
01/21/14 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND07/21/14 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND01/29/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/27/15 0.2 1.0 ---ND ND ND ND ND ND ND ND ND ND ND01/26/16 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
07/26/16 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND02/01/17 0.3 1.0 ---ND ND ND ND ND ND ND ND ND ND ND
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 11 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Field Parameters
pH 05/23/97 FIELD FIELD 5.56 NI 6.38 7.50 7.74 6.33 ---NI NI NI NI ---
(S.U.)06/16/97 FIELD FIELD 5.67 NI 6.67 7.50 7.84 6.25 ---NI NI NI NI ---
08/14/97 FIELD FIELD 5.74 NI 6.50 7.42 7.71 6.18 ---NI NI NI NI ---09/30/97 FIELD FIELD Dry NI 6.49 7.49 7.4 6.10 ---NI NI NI NI ---
04/30/98 FIELD FIELD 5.79 NI 6.24 7.12 7.19 6.56 ---NI NI NI NI ---09/15/98 FIELD FIELD 5.51 NI 6.73 7.66 7.71 6.99 ---NI NI NI NI ---
04/08/99 FIELD FIELD 5.70 NI 6.27 7.26 7.42 6.72 ---NI NI NI NI ---
09/09/99 FIELD FIELD Dry NI 6.99 7.63 7.49 6.60 ---NI NI NI NI ---04/13/00 FIELD FIELD 5.14 NI 6.47 7.51 7.43 6.41 ---NI NI NI NI ---
10/17/00 FIELD FIELD 8.73 NI 7.82 8.83 7.98 7.46 ---NI NI NI NI ---04/23/01 FIELD FIELD 5.70 NI 6.42 7.45 7.36 6.48 ---NI NI NI NI ---
10/18/01 FIELD FIELD Dry NI 6.42 7.38 7.21 6.27 ---NI NI NI NI ---
04/29/02 FIELD FIELD Dry NI 6.51 7.42 7.4 7.18 ---NI NI NI NI ---10/23/02 FIELD FIELD Dry NI 6.57 7.80 7.37 6.82 ---NI NI NI NI ---
04/14/03 FIELD FIELD 5.00 NI 6.10 7.39 7.24 6.34 ---NI NI NI NI ---10/30/03 FIELD FIELD 6.25 NI 6.75 8.10 7.6 6.67 ---NI NI NI NI ---
03/19/04 FIELD FIELD ---NI ------------6.36 NI NI NI NI ---
04/28/04 FIELD FIELD 5.91 NI 6.22 7.45 7.41 6.51 6.56 NI NI NI NI ---10/27/04 FIELD FIELD 5.17 NI 5.99 6.96 6.91 6.12 6.31 NI NI NI NI ---
03/16/05 FIELD FIELD 6.18 NI 6.30 7.19 7.15 6.16 6.40 NI NI NI NI ---07/21/05 FIELD FIELD 6.55 NI 6.56 7.13 7.21 6.95 6.24 NI NI NI NI ---
01/26/06 FIELD FIELD Dry NI 6.07 8.81 8.18 7.64 6.70 NI NI NI NI ---
07/21/06 FIELD FIELD ---NI 6.24 7.22 7.09 6.41 6.18 NI NI NI NI ---01/22/07 FIELD FIELD 5.62 NI 6.51 7.24 7.14 6.40 6.01 NI NI NI NI ---
07/23/07 FIELD FIELD 6.84 NI 5.95 7.53 7.27 6.57 6.29 NI NI NI NI ---01/10/08 FIELD FIELD Dry NI 6.01 7.16 7.1 6.56 6.20 NI NI NI NI ---
07/21/08 FIELD FIELD Dry NI 6.08 7.37 7.07 6.35 6.33 NI NI NI NI ---
01/29/09 FIELD FIELD Dry NI 5.87 7.05 6.91 6.32 6.18 NI NI NI NI ---07/30/09 FIELD FIELD 4.79 NI 5.75 6.60 6.45 5.95 5.89 NI NI NI NI ---
01/14/10 FIELD FIELD ---5.22 5.92 6.82 6.82 6.48 5.93 NI NI NI NI ---07/15/10 FIELD FIELD ---5.49 5.72 6.87 6.82 6.30 5.94 NI NI NI NI ---
01/20/11 FIELD FIELD ---5.71 5.80 6.95 6.75 6.75 5.93 NI NI NI NI ---
02/18/11 FIELD FIELD ------5.65 ------------NI NI NI NI ---07/14/11 FIELD FIELD ---5.47 5.80 6.90 6.7 6.57 5.48 NI NI NI NI ---
01/30/12 FIELD FIELD ---5.86 6.03 7.00 6.99 7.00 5.93 NI NI NI NI ---05/24/12 FIELD FIELD ---NS NS NS NS NS NS 5.94 5.39 5.76 5.65 ---
06/28/12 FIELD FIELD ---NS NS NS NS NS NS 6.07 5.81 6.20 5.82 ---
07/25/12 FIELD FIELD ---6.00 6.20 7.41 6.95 6.94 6.05 6.1 5.52 5.34 5.60 ---08/24/12 FIELD FIELD ---NS NS NS NS NS NS 6.04 5.61 5.46 5.66 ---
02/04/13 FIELD FIELD ---5.65 6.07 7.15 7.09 7.25 5.86 6.28 7.06 5.75 5.74 ---07/08/13 FIELD FIELD ---5.37 5.68 6.75 6.68 6.62 5.32 5.89 4.82 4.99 4.91 ---
01/21/14 FIELD FIELD ---8.96 6.66 6.60 6.98 7.12 7.43 6.97 6.61 5.66 5.78 ---
07/21/14 FIELD FIELD ---5.75 5.94 6.83 6.97 6.98 5.87 5.99 5.24 4.71 5.02 ---01/29/15 FIELD FIELD ---5.45 ---6.40 6.48 6.92 5.57 6.11 5.39 5.12 4.78 ---
07/27/15 FIELD FIELD ---5.95 6.23 7.42 7.02 7.25 5.99 6.23 5.28 5.34 5.12 ---01/26/16 FIELD FIELD ---6.63 5.83 6.55 6.99 6.78 5.99 6.38 5.59 5.24 5.10 ---
07/26/16 FIELD FIELD ---6.80 6.76 6.92 6.78 6.80 6.95 6.61 6.16 5.92 5.80 ---
02/01/17 FIELD FIELD ---5.88 6.08 7.32 6.96 7.26 5.99 6.35 5.30 5.23 5.19 ---Resample > 03/31/17 FIELD FIELD ---------------7.27 ------------------
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 12 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Conductivity 05/23/97 FIELD FIELD 82 NI 232 375 278 149 ---NI NI NI NI ---
(µS/cm)06/16/97 FIELD FIELD 73 NI 299 441 325 186 ---NI NI NI NI ---08/14/97 FIELD FIELD 94 NI 309 384 306 267 ---NI NI NI NI ---
09/30/97 FIELD FIELD Dry NI 215 327 277 181 ---NI NI NI NI ---04/30/98 FIELD FIELD 12 NI 31 53 47 44 ---NI NI NI NI ---
09/15/98 FIELD FIELD 77 NI 180 344 434 274 ---NI NI NI NI ---
04/08/99 FIELD FIELD 72 NI 135 232 206 189 ---NI NI NI NI ---09/09/99 FIELD FIELD Dry NI 102 190 137 130 ---NI NI NI NI ---
04/13/00 FIELD FIELD 62 NI 285 413 3.35 351 ---NI NI NI NI ---10/17/00 FIELD FIELD 53 NI 225 245 274 191 ---NI NI NI NI ---
04/23/01 FIELD FIELD 67 NI 239 472 445 327 ---NI NI NI NI ---
10/18/01 FIELD FIELD Dry NI 178 297 283 231 ---NI NI NI NI ---04/29/02 FIELD FIELD Dry NI 91 136 140 161 ---NI NI NI NI ---
10/23/02 FIELD FIELD Dry NI 149 302 289 201 ---NI NI NI NI ---04/14/03 FIELD FIELD 48 NI 73 63 75 81 ---NI NI NI NI ---
10/30/03 FIELD FIELD 186 NI 174 487 487 108 ---NI NI NI NI ---
03/19/04 FIELD FIELD ---NI ------------971 NI NI NI NI ---04/28/04 FIELD FIELD 82 NI 128 168 154 144 449 NI NI NI NI ---
10/27/04 FIELD FIELD 54 NI 235 532 546 488 658 NI NI NI NI ---03/16/05 FIELD FIELD 49 NI 297 481 ---389 322 NI NI NI NI ---
07/21/05 FIELD FIELD 62 NI 325 542 501 501 413 NI NI NI NI ---
01/26/06 FIELD FIELD Dry NI 189 468 447 361 367 NI NI NI NI ---07/21/06 FIELD FIELD ---NI 279 607 595 551 442 NI NI NI NI ---
01/22/07 FIELD FIELD 57 NI 409 602 634 564 419 NI NI NI NI ---07/23/07 FIELD FIELD 80 NI 295 581 642 577 485 NI NI NI NI ---
01/10/08 FIELD FIELD Dry NI 414 914 999 567 600 NI NI NI NI ---
07/21/08 FIELD FIELD Dry NI 269 617 752 617 406 NI NI NI NI ---01/29/09 FIELD FIELD Dry NI 259 636 750 508 280 NI NI NI NI ---
07/30/09 FIELD FIELD 81 NI 233 623 776 607 279 NI NI NI NI ---01/14/10 FIELD FIELD ---152 236 605 765 543 252 NI NI NI NI ---
07/15/10 FIELD FIELD ---154 211 615 800 577 239 NI NI NI NI ---
01/20/11 FIELD FIELD ---160 225 621 830 556 209 NI NI NI NI ---02/18/11 FIELD FIELD ------234 ------------NI NI NI NI ---
07/14/11 FIELD FIELD ---173 242 660 887 633 224 NI NI NI NI ---01/30/12 FIELD FIELD ---137 199 471 685 424 141 NI NI NI NI ---
05/24/12 FIELD FIELD ---NS NS NS NS NS NS 607 193.0 102.0 117.0 ---
06/28/12 FIELD FIELD ---NS NS NS NS NS NS 588 220.7 119.1 151.7 ---07/25/12 FIELD FIELD ---146.7 247.3 625 917 625 190.7 694 227.9 75.9 118.9 ---
08/24/12 FIELD FIELD ---NS NS NS NS NS NS 689 216.9 82.4 128.2 ---02/04/13 FIELD FIELD ---130.1 173.9 458.9 549 422.6 127.6 634 143.6 64.2 119.8 ---
07/08/13 FIELD FIELD ---118.4 211.4 457.3 711 379.6 136.0 519 110.6 78.8 101.1 ---
01/21/14 FIELD FIELD ---155.7 252.8 487.9 644 490.3 180.3 771 164.4 76.6 72.1 ---07/21/14 FIELD FIELD ---138.7 278.9 508.0 828 510.0 161.5 749 225.4 84.8 108.9 ---
01/29/15 FIELD FIELD ---149.5 ---475.5 658 430.9 152.6 546 171.4 218.4 81.2 ---07/27/15 FIELD FIELD ---135.0 277.0 491.0 689.0 459.0 165.0 635.0 173.0 81.0 75.0 ---
01/26/16 FIELD FIELD ---154.1 283.4 484.7 704.0 478.6 169.8 449.1 196.1 204.8 75.5 ---
07/26/16 FIELD FIELD ---151.7 286.1 511.0 830.0 563.0 179.8 788.0 158.6 102.0 99.0 ---02/01/17 FIELD FIELD ---157.6 268.3 488.1 684.0 448.7 166.2 711.0 157.3 83.3 112.2 ---
Resample > 03/31/17 FIELD FIELD ---------------430.8 ------------------
Temperature 05/23/97 FIELD FIELD 19.7 NI 17.5 16.9 16.9 16.2 ---NI NI NI NI ---
(ºC)06/16/97 FIELD FIELD 19.8 NI 17.6 16.3 15.7 17.7 ---NI NI NI NI ---08/14/97 FIELD FIELD 28.0 NI 19.1 21.9 25 22.1 ---NI NI NI NI ---
09/30/97 FIELD FIELD Dry NI 16.6 19.1 17.1 19.4 ---NI NI NI NI ---04/30/98 FIELD FIELD 22.2 NI 16.0 17.0 16.3 17.7 ---NI NI NI NI ---09/15/98 FIELD FIELD 22.1 NI 15.6 14.2 16.7 22.2 ---NI NI NI NI ---
04/08/99 FIELD FIELD 22.1 NI 20.4 18.0 19 16.4 ---NI NI NI NI ---09/09/99 FIELD FIELD Dry NI 13.3 22.5 22.4 23.3 ---NI NI NI NI ---
04/13/00 FIELD FIELD 16.3 NI 18.0 16.3 11.2 11.3 ---NI NI NI NI ---10/17/00 FIELD FIELD 16.7 NI 18.1 16.8 16.8 18.4 ---NI NI NI NI ---04/23/01 FIELD FIELD 17.7 NI 18.5 17.2 17.2 16.1 ---NI NI NI NI ---
10/18/01 FIELD FIELD Dry NI 15.9 15.3 13.6 14.5 ---NI NI NI NI ---04/29/02 FIELD FIELD Dry NI 17.5 15.8 16 20.0 ---NI NI NI NI ---
10/23/02 FIELD FIELD Dry NI 18.2 17.5 17 20.8 ---NI NI NI NI ---04/14/03 FIELD FIELD 18.8 NI 18.7 17.7 17.5 14.7 ---NI NI NI NI ---10/30/03 FIELD FIELD 17.6 NI 16.8 17.4 16.4 17.6 ---NI NI NI NI ---
03/19/04 FIELD FIELD ---NI ------------12.60 NI NI NI NI ---04/28/04 FIELD FIELD 15.1 NI 16.3 16.2 16.7 10.5 14.50 NI NI NI NI ---
10/27/04 FIELD FIELD 14.4 NI 16.1 15.0 15.8 17.2 15.40 NI NI NI NI ---03/16/05 FIELD FIELD 11.83 NI 13.66 13.49 12.79 11.16 10.12 NI NI NI NI ---07/21/05 FIELD FIELD 18.62 NI 20.70 17.34 19.71 22.59 19.60 NI NI NI NI ---
01/26/06 FIELD FIELD Dry NI 13.92 14.77 14.27 13.00 13.00 NI NI NI NI ---07/21/06 FIELD FIELD ---NI 22.10 18.93 18.34 18.70 15.70 NI NI NI NI ---
01/22/07 FIELD FIELD 14.20 NI 15.20 12.90 13.4 13.40 12.90 NI NI NI NI ---07/23/07 FIELD FIELD 18.50 NI 18.61 18.72 18.5 20.03 16.30 NI NI NI NI ---01/10/08 FIELD FIELD Dry NI 16.44 15.19 14.92 14.37 14.66 NI NI NI NI ---
07/21/08 FIELD FIELD Dry NI 21.25 22.36 22.78 22.99 17.73 NI NI NI NI ---01/29/09 FIELD FIELD Dry NI 14.67 11.89 14.16 10.04 12.24 NI NI NI NI ---
07/30/09 FIELD FIELD 23.94 NI 20.10 20.26 24.22 22.45 19.95 NI NI NI NI ---01/14/10 FIELD FIELD ---13.74 15.97 13.47 13.35 12.42 13.06 NI NI NI NI ---07/15/10 FIELD FIELD ---22.65 22.56 20.04 21.78 19.57 19.23 NI NI NI NI ---
01/20/11 FIELD FIELD ---13.25 15.60 13.65 13.49 13.18 13.25 NI NI NI NI ---02/18/11 FIELD FIELD ------17.03 ------------NI NI NI NI ---
07/14/11 FIELD FIELD ---19.07 20.71 19.14 20.08 19.29 16.80 NI NI NI NI ---01/30/12 FIELD FIELD ---14.13 16.91 14.57 16.56 13.70 13.66 NI NI NI NI ---05/24/12 FIELD FIELD ---NS NS NS NS NS NS 16.78 18.24 16.99 16.41 ---
06/28/12 FIELD FIELD ---NS NS NS NS NS NS 23.1 26.4 23.0 20.1 ---07/25/12 FIELD FIELD ---19.1 18.9 18.4 22.4 17.3 15.8 17.5 18.5 16.8 16.7 ---
08/24/12 FIELD FIELD ---NS NS NS NS NS NS 15.9 16.2 16.7 16.1 ---02/04/13 FIELD FIELD ---14.6 13.2 14.2 10.2 14.5 14.2 13.2 12.4 14.2 14.4 ---07/08/13 FIELD FIELD ---16.0 17.1 16.2 20.4 15.5 14.9 16.2 16.6 15.5 15.1 ---
01/21/14 FIELD FIELD ---15.0 16.2 14.6 13.1 15.1 14.5 14.5 15.2 16.0 15.4 ---07/21/14 FIELD FIELD ---16.7 17.4 16.6 20.6 16.9 14.7 18.1 20.1 16.9 16.0 ---
01/29/15 FIELD FIELD ---14.7 ---14.5 13.3 13.5 12.6 13.0 13.2 15.5 14.6 ---07/27/15 FIELD FIELD ---16.78 18.1 18.56 18.78 17.89 15.70 17.82 17.3 18.4 17.14 ---01/26/16 FIELD FIELD ---14.9 16.7 14.2 14.0 14.8 14.5 15.1 15.2 15.5 15.0 ---
07/26/16 FIELD FIELD ---16.7 17.3 16.1 18.9 17.9 15.3 16.8 16.6 17.1 17.2 ---02/01/17 FIELD FIELD ---14.8 16.8 14.6 13.9 14.3 14.3 14.7 16.2 16.4 15.8 ---
Resample > 03/31/17 FIELD FIELD ---------------13.8 ------------------
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 13 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Turbidity 05/23/97 FIELD FIELD 19 NI 14.0 2.85 7.89 250 ---NI NI NI NI ---
(NTU)06/16/97 FIELD FIELD 100 NI 11.0 5.79 9.82 28.0 ---NI NI NI NI ---08/14/97 FIELD FIELD 770 NI 14.0 8.18 7.13 63.0 ---NI NI NI NI ---
09/30/97 FIELD FIELD Dry NI 4.2 6.56 8.46 47.0 ---NI NI NI NI ---04/30/98 FIELD FIELD 13 NI 23.0 22.00 5.79 16.0 ---NI NI NI NI ---
09/15/98 FIELD FIELD 590 NI 19.7 11.20 22.2 62.8 ---NI NI NI NI ---
04/08/99 FIELD FIELD 11 NI 9.4 8.81 1.23 7.97 ---NI NI NI NI ---09/09/99 FIELD FIELD Dry NI 9.1 5.60 5.71 32.0 ---NI NI NI NI ---
04/13/00 FIELD FIELD 280 NI 32.0 6.79 1.81 70.0 ---NI NI NI NI ---10/17/00 FIELD FIELD 292 NI 22.1 1.91 1.36 26.9 ---NI NI NI NI ---
04/23/01 FIELD FIELD 440 NI 72.0 3.66 4.36 14.0 ---NI NI NI NI ---
10/18/01 FIELD FIELD Dry NI 30.0 1.86 7.92 43.0 ---NI NI NI NI ---04/29/02 FIELD FIELD Dry NI 42.0 1.96 2.03 4.23 ---NI NI NI NI ---
10/23/02 FIELD FIELD Dry NI 34.0 2.81 6.06 6.76 ---NI NI NI NI ---04/14/03 FIELD FIELD 184 NI 23.0 3.96 1.03 3.86 ---NI NI NI NI ---
10/30/03 FIELD FIELD 17 NI 7.2 5.25 3.91 14.0 ---NI NI NI NI ---
03/19/04 FIELD FIELD ---NI ------------5.82 NI NI NI NI ---04/28/04 FIELD FIELD 32 NI 19.0 2.99 0.94 25.0 6.45 NI NI NI NI ---
10/27/04 FIELD FIELD 19 NI 20.0 4.82 9.72 19.0 25.00 NI NI NI NI ---03/16/05 FIELD FIELD 320 NI 224.0 86.50 35.7 37.0 288.00 NI NI NI NI ---
07/21/05 FIELD FIELD 763 NI 438.0 320 240 233.0 426.00 NI NI NI NI ---
01/26/06 FIELD FIELD Dry NI 102.0 88.10 24.2 174.0 126 NI NI NI NI ---07/21/06 FIELD FIELD ---NI 60.3 0.00 0 124.0 147 NI NI NI NI ---
01/22/07 FIELD FIELD 290 NI >1000 30.90 0 197.0 34.8 NI NI NI NI ---07/23/07 FIELD FIELD 364 NI 3.70 4.60 7.1 130.0 52.2 NI NI NI NI ---
01/10/08 FIELD FIELD Dry NI 2.46 2.64 0.48 56.7 16.1 NI NI NI NI ---
07/21/08 FIELD FIELD Dry NI 13.60 0.88 0.64 82.4 37.7 NI NI NI NI ---01/29/09 FIELD FIELD Dry NI 30.70 1.39 1.55 26.6 22.3 NI NI NI NI ---
07/30/09 FIELD FIELD 123 NI 7.50 1.67 1.74 85.3 25.0 NI NI NI NI ---01/14/10 FIELD FIELD ---73.90 7.71 0.95 2.37 61.8 21.1 NI NI NI NI ---
07/15/10 FIELD FIELD ---15.10 3.79 1.58 1.07 39.0 34.4 NI NI NI NI ---
01/20/11 FIELD FIELD ---14.00 6.16 0.30 0.65 32.7 16.3 NI NI NI NI ---02/18/11 FIELD FIELD ------6.26 ------------NI NI NI NI ---
07/14/11 FIELD FIELD ---9.18 2.35 1.19 0.67 43.9 15.2 NI NI NI NI ---01/30/12 FIELD FIELD ---17.92 15.30 10.68 10.52 16.39 24.7 NI NI NI NI ---
05/24/12 FIELD FIELD ---NS NS NS NS NS NS 16.19 11.81 62.4 13.56 ---
06/28/12 FIELD FIELD ---NS NS NS NS NS NS 18.61 6.61 63.7 6.55 ---07/25/12 FIELD FIELD ---5.91 2.84 4.75 5.86 25.8 8.24 3.99 2.83 32.2 5.54 ---
08/24/12 FIELD FIELD ---NS NS NS NS NS NS 5.42 4.60 24.9 5.09 ---02/04/13 FIELD FIELD ---15.10 11.19 16.91 16.39 12.04 16.61 11.39 16.11 19.1 11.37 ---
07/08/13 FIELD FIELD ---3.27 7.10 10.12 4.22 3.24 7.19 9.68 10.81 31.5 10.07 ---
01/21/14 FIELD FIELD ---5.21 3.23 3.62 4.10 3.80 3.97 3.92 4.06 3.91 3.81 ---07/21/14 FIELD FIELD ---3.23 17.90 3.85 7.55 4.31 2.01 5.29 4.27 26.70 4.77 ---
01/29/15 FIELD FIELD ---30.50 ---2.01 ------6.57 1.51 2.07 15.60 3.51 ---07/27/15 FIELD FIELD ---7.32 9.72 6.4 11.3 8.0 13.1 4.6 4.5 70 10 ---
01/26/16 FIELD FIELD ---5.45 4.39 6.2 10.6 7.66 11.6 3.22 4.06 68.0 2.7 ---
07/26/16 FIELD FIELD ---5.76 4.17 5.87 13.04 4.37 9.91 6.64 2.96 32.6 4.18 ---02/01/17 FIELD FIELD ---2.86 3.19 0.71 14.39 5.19 3.98 2.89 26.27 37.3 3.72 ---
Resample > 03/31/17 FIELD FIELD ---------------3.15 ------------------
Oxidation Reduction Potential 03/16/05 FIELD FIELD 194 NI 92 65.0 103 13.0 127.0 NI NI NI NI ---
(mV)07/21/05 FIELD FIELD 206 NI 53 -9.0 3 -26.0 110.0 NI NI NI NI ---01/26/06 FIELD FIELD Dry NI 136 -88.0 -13 35.0 141.0 NI NI NI NI ---
07/21/06 FIELD FIELD ---NI 108 -112.0 -74 9.0 180.0 NI NI NI NI ---01/22/07 FIELD FIELD 279 NI 183 -100.0 -38 -2.0 256.0 NI NI NI NI ---07/23/07 FIELD FIELD ---NI 326 -82.0 -28 -28.0 182.0 NI NI NI NI ---
01/10/08 FIELD FIELD Dry NI 193 -88.0 -16 8.0 206.0 NI NI NI NI ---07/21/08 FIELD FIELD Dry NI 206 -65.0 -33 -52.0 166.0 NI NI NI NI ---
01/29/09 FIELD FIELD Dry NI 210.5 -9.3 103.2 175.8 253.4 NI NI NI NI ---07/30/09 FIELD FIELD 181.6 NI 123.8 -50.2 2.6 -24.1 132.0 NI NI NI NI ---01/14/10 FIELD FIELD ---166.3 70.4 -33.1 20.2 11.1 141.0 NI NI NI NI ---
07/15/10 FIELD FIELD ---40.1 187.9 -70.4 48.3 82.0 -13.8 NI NI NI NI ---01/20/11 FIELD FIELD ---199.8 132.5 -18.5 42.4 18.2 195.6 NI NI NI NI ---
02/18/11 FIELD FIELD ------187.3 ------------NI NI NI NI ---07/14/11 FIELD FIELD ---94.9 118.3 -23.4 5.4 -12.7 114.6 NI NI NI NI ---01/30/12 FIELD FIELD ---31.3 41.9 -73.6 -32.4 -15.5 42.3 NI NI NI NI ---
05/24/12 FIELD FIELD ---NS NS NS NS NS NS 91.4 161.9 147.2 149.1 ---06/28/12 FIELD FIELD ---NS NS NS NS NS NS 13.9 224.3 188.5 219.3 ---
07/25/12 FIELD FIELD ---100.8 152.1 -137.3 -137.8 -51.5 148.0 -108.9 166.7 131.0 133.5 ---08/24/12 FIELD FIELD ---NS NS NS NS NS NS 12.1 156.6 129.8 125.1 ---02/04/13 FIELD FIELD ---181.1 210.2 -6.2 -20.8 -13.1 188.1 -30.1 49.6 211.6 202.4 ---
07/08/13 FIELD FIELD ---140.4 176.2 89.2 -132 -4.6 153.6 31.4 180.4 162.1 151.0 ---01/21/14 FIELD FIELD ---85.9 100.6 -39.8 37.2 -39.8 95.0 -57.2 33.0 157.2 111.3 ---
07/21/14 FIELD FIELD ---95.0 121.5 85.7 82.1 87.6 103.7 -85.4 95.0 146.9 127.5 ---01/29/15 FIELD FIELD ---48.6 ---27.7 28.1 47.8 123.0 -38.8 124.3 124.7 150.4 ---07/27/15 FIELD FIELD ---78.1 169.0 -20.9 -21.6 -23.8 64.5 -132.9 165.3 138.0 146.0 ---
01/26/16 FIELD FIELD ---219.7 194.9 -98.4 62.8 14.3 209.5 -59.6 116.4 204.8 235.6 ---07/26/16 FIELD FIELD ---66.3 78.0 51.4 46.3 -74.9 85.5 -73.3 69.8 76.3 80.3 ---
02/01/17 FIELD FIELD ---182.5 116.4 -71.4 77.2 -12.4 155.5 -86.4 132.9 158.6 168.9 ---Resample > 03/31/17 FIELD FIELD ---------------27.1 ------------------
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 14 of 15
Joyce Engineering
TABLE 7
Historically Detected Constituents/Analytes in Groundwater
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL RL GW-1 GW-1R GW-2 GW-3 GW-4 GW-5 GW-6 GW-7 GW-8 GW-9 GW-10 Blanks
Dissolved Oxygen 03/16/05 FIELD FIELD 5.06 NI 4.90 4.81 5.01 5.66 5.50 NI NI NI NI ---
(mg/L)07/21/05 FIELD FIELD 11.28 NI 12.58 13.67 11.66 11.35 11.38 NI NI NI NI ---01/26/06 FIELD FIELD Dry NI ---0*0*3.18 1.37 NI NI NI NI ---
07/21/06 FIELD FIELD ---NI 8.67 2.28 2.05 7.06 6.95 NI NI NI NI ---01/22/07 FIELD FIELD ---NI 8.40 0.50 0.5 0.30 5.50 NI NI NI NI ---
07/23/07 FIELD FIELD ---NI 4.20 2.30 1.3 3.00 3.90 NI NI NI NI ---
01/10/08 FIELD FIELD Dry NI 3.59 1.04 3.32 2.24 4.58 NI NI NI NI ---07/21/08 FIELD FIELD Dry NI 3.57 1.78 0.44 0.48 4.19 NI NI NI NI ---
01/29/09 FIELD FIELD Dry NI 1.90 0.79 0.72 0.68 4.38 NI NI NI NI ---07/30/09 FIELD FIELD 4.98 NI 2.98 1.74 1.11 1.30 3.11 NI NI NI NI ---
01/14/10 FIELD FIELD ---5.36 2.04 2.07 0.84 1.60 5.16 NI NI NI NI ---
07/15/10 FIELD FIELD ---3.26 1.85 2.63 0.27 0.37 2.72 NI NI NI NI ---01/20/11 FIELD FIELD ---3.70 1.28 1.38 0.63 2.49 5.15 NI NI NI NI ---
02/18/11 FIELD FIELD ------1.56 ------------NI NI NI NI ---07/14/11 FIELD FIELD ---3.96 1.94 0.57 0.96 0.86 3.32 NI NI NI NI ---
01/30/12 FIELD FIELD ---2.87 2.38 0.56 1.91 3.14 5.48 NI NI NI NI ---
05/24/12 FIELD FIELD ---NS NS NS NS NS NS 8.67 7.71 8.49 8.91 ---06/28/12 FIELD FIELD ---NS NS NS NS NS NS 0.71 4.40 4.10 2.12 ---
07/25/12 FIELD FIELD ---1.09 1.13 0.67 0.29 1.22 2.22 0.51 2.20 1.73 2.55 ---08/24/12 FIELD FIELD ---NS NS NS NS NS NS 1 2.13 1.55 2.66 ---
02/04/13 FIELD FIELD ---2.18 4.51 2.89 4.21 3.69 6.29 1.46 7.09 6.47 3.59 ---
07/08/13 FIELD FIELD --- 236.00 1.37 0.48 0.38 0.21 1.69 0.68 2.01 1.47 0.99 ---01/21/14 FIELD FIELD ---5.99 1.79 2.45 4.59 6.40 5.41 0.40 6.81 2.87 5.67 ---
07/21/14 FIELD FIELD ---2.68 1.58 0.56 1.5 0.56 2.36 0.70 2.32 0.81 0.85 ---01/29/15 FIELD FIELD ---3.16 ---2.75 1.56 5.86 7.27 1.19 4.36 1.22 1.34 ---
07/27/15 FIELD FIELD ---3.32 2.70 0.12 0.29 0.09 1.61 0.11 0.95 0.48 0.33 ---
01/26/16 FIELD FIELD ---2.48 3.55 0.38 1.56 3.41 3.88 0.87 1.84 1.40 5.17 ---07/26/16 FIELD FIELD ---3.47 0.47 1.28 0.97 1.39 2.82 2.38 1.53 0.39 0.94 ---
02/01/17 FIELD FIELD ---2.26 13.40 0.58 1.58 3.49 5.31 0.73 1.89 1.35 2.07 ---Resample > 03/31/17 FIELD FIELD ---------------1.55 ------------------
Notes:
DL = Method Detection Limit.RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
PQL = Practical Quantitation Limit.
SWSL = NC-DENR Solid Waste Section Limit. NC 2L = Groundwater Standard established in 15 A NCAC 2L.0202
GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L.ND = Not detected above the DL.
J = Estimated concentration below the RL.
B = Blank qualified data.dry = insufficient water to sample.
--- = No data.All inorganic and organic compounds are in µg/L.
µg/L = micrograms per liter
mg/L = milligrams per literS.U. = Standard Units.
NTU = Nephelometric Turbidity Units.µS/cm= microsiemens per centimeter.
mV = Millivolts.
Bold = Concentrations above the NC 2L or Groundwater Protection standards (GWPS) have been boldeBlanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
Upper Piedmont Regional Landfill
Permot No. 73-04 Page 15 of 15
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Inorganic Compounds
Antimony 01/30/12 --- 6.00 ND 0.14 B 0.33 J
No NC 2B Standard 07/25/12 --- 6.00 Dry Dry ND
02/04/13 --- 6.00 ND ND ND
07/08/13 --- 6.00 ND ND ND
01/21/14 0.22 6.00 ND ND ND
07/21/14 1.05 6.00 ND ND ND
01/29/15 1.05 6.00 ND ND ND
07/27/15 0.25 6.00 DRY 9.27 ND
01/26/16 0.25 6.00 DRY 0.81 J ND
07/26/16 0.25 6.00 DRY 1.49 J ND
02/01/17 0.25 6.00 ND 0.58 J ND
Arsenic 01/30/12 --- 10.0 ND 1.61 J ND
NC 2B = 50 µg/L 07/25/12 --- 10.0 Dry Dry 1.65 J
02/04/13 --- 10.0 1.32 J ND ND
07/08/13 --- 10.0 0.91 J 1.68 J ND
01/21/14 0.78 10.0 ND 0.80 J ND
07/21/14 1.13 10.0 2.84 J ND ND
01/29/15 1.13 10.0 ND ND ND
07/27/15 0.75 10.0 DRY 4.62 J ND
01/26/16 0.75 10.0 DRY 1.00 J ND
07/26/16 0.75 10.0 DRY 0.88 J ND
NC 2B = 10 µg/L 02/01/17 0.75 10.0 0.85 J 0.96 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 1 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Barium 06/16/97 --- 500 ND ND ---
No NC 2B Standard 08/14/97 --- 500 ---ND ---
09/30/97 --- 20 ---30 ---
04/30/98 --- 20 40 30 ---
09/15/98 --- 20 ---30 ---
04/08/99 --- 20 30 20 ---
09/09/99 --- 500 ND ND ND
04/13/00 --- 500 ND ND ND
10/17/00 --- 500 Dry Dry ND
04/23/01 --- 500 ND ND ND
10/18/01 --- 500 ND ND ND
04/29/02 --- 500 ND ND ND
10/23/02 --- 500 ND ND ND
04/14/03 --- 500 ND ND ND
10/30/03 --- 500 ND ND ND
04/28/04 --- 500 1000 ND ND
10/26/04 --- 500 ND ND ND
03/16/05 --- 500 ND ND ND
07/21/05 --- 500 ND Dry ND
01/26/06 --- 500 ND ND ND
07/21/06 --- 500 ND ND ND
01/22/07 --- 100 37.0 J 33.9 J 0.50 J
07/23/07 --- 100 Dry 25.8 J 0.50 J
01/10/08 --- 100 41.8 J 34.1 J ND
07/21/08 --- 100 Dry Dry ND
01/29/09 --- 100 36.6 J 30.5 J 0.50 J
07/30/09 --- --- Dry Dry ---
01/14/10 --- 100 32.8 J 28.2 J ND
07/15/10 --- 100 Dry Dry ND
01/20/11 --- 100 27.9 J 28.1 J ND
07/14/11 --- 100 Dry 39.0 J ND
01/30/12 --- 100 34.9 J 33.8 J 0.14 J
07/25/12 --- 100 Dry Dry 0.79 J
02/04/13 --- 100 39.4 J 37.0 J ND
07/08/13 --- 100 51.3 J 74.7 J 0.57 J
01/21/14 0.25 100 40.8 J 31.4 J ND
07/21/14 0.1 100 61.9 J 44.1 J 0.34 J
01/29/15 0.10 100 33.3 J 31.7 J 1.33 J
07/27/15 0.30 100 DRY 79.2 J 0.41 J
01/26/16 0.30 100 DRY 37.6 J 0.55 J
07/26/16 0.30 100 DRY 39.5 J 0.30 J
02/01/17 0.30 100 35.2 J 33.1 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 2 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Beryllium 06/16/97 --- 2.00 ND ND ---
NC 2B = 6.5 µg/L 08/14/97 --- 2.00 ---ND ---
09/30/97 --- 3.00 ---ND ---
04/30/98 --- 3.00 ND ND ---
09/15/98 --- 3.00 ---ND ---
04/08/99 --- 3.00 ND ND ---
09/09/99 --- 2.00 ND ND ND
04/13/00 --- 2.00 ND ND ND
10/17/00 --- 2.00 Dry Dry ND
04/23/01 --- 2.00 ND ND ND
10/18/01 --- 2.00 ND ND ND
04/29/02 --- 2.00 ND ND ND
10/23/02 --- 2.00 ND ND ND
04/14/03 --- 2.00 ND ND ND
10/30/03 --- 2.00 ND ND ND
04/28/04 --- 2.00 2.00 ND ND
10/26/04 --- 2.00 ND ND ND
03/16/05 --- 2.00 ND ND ND
07/21/05 --- 2.00 ND Dry ND
01/26/06 --- 2.00 ND ND ND
07/21/06 --- 2.00 ND ND ND
01/22/07 --- 1.00 ND ND ND
07/23/07 --- 1.00 Dry ND ND
01/10/08 --- 1.00 ND ND ND
07/21/08 --- 1.00 Dry Dry ND
01/29/09 --- 1.00 ND ND ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 1.00 0.09 J ND ND
07/15/10 --- 1.00 Dry Dry ND
01/20/11 --- 1.00 ND ND ND
07/14/11 --- 1.00 Dry ND ND
01/30/12 --- 1.00 ND 0.05 J ND
07/25/12 --- 1.00 Dry Dry ND
02/04/13 --- 1.00 ND ND ND
07/08/13 --- 1.00 ND 0.12 J ND
01/21/14 0.11 1.00 ND ND ND
07/21/14 0.05 1.00 0.23 J ND ND
01/29/15 0.05 1.00 0.07 J ND ND
07/27/15 0.09 1.00 DRY ND ND
01/26/16 0.09 1.00 DRY ND ND
NC 2B = 6.5 µg/L (d); chronic 07/26/16 0.09 1.00 DRY ND ND
02/01/17 0.09 1.00 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 3 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Cadmium 07/21/05 --- 1.00 ND Dry ND
NC 2B = 2 µg/L 01/26/06 --- 1.00 ND ND ND
07/21/06 --- 1.00 ND ND ND
01/22/07 --- 1.00 ND ND ND
07/23/07 --- 1.00 Dry ND ND
01/10/08 --- 1.00 ND ND ND
07/21/08 --- 1.00 Dry Dry ND
01/29/09 --- 1.00 ND ND ND
01/14/10 --- 1.00 2.04 1.38 ND
07/15/10 --- 1.00 Dry Dry ND
01/20/11 --- 1.00 ND ND ND
07/14/11 --- 1.00 Dry ND ND
01/30/12 --- 1.00 0.34 J ND ND
07/25/12 --- 1.00 Dry Dry ND
02/04/13 --- 1.00 ND ND ND
07/08/13 --- 1.00 1.81 ND ND
01/21/14 0.06 1.00 0.17 J ND ND
07/21/14 0.05 1.00 ND ND ND
01/29/15 0.05 1.00 ND ND 0.1 J
07/27/15 0.10 1.00 DRY 0.12 J ND
01/26/16 0.10 1.00 DRY ND ND
07/26/16 0.10 1.00 DRY 0.51 J ND
NC 2B = 0.15 µg/L; (d)(h), chronic 02/01/17 0.10 1.00 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 4 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Chromium 06/16/97 --- 10.0 ND ND ---
NC 2B = 50 µg/L 08/14/97 --- 10.0 ---ND ---
09/30/97 --- 10.0 ---ND ---
04/30/98 --- 10.0 ND ND ---
09/15/98 --- 10.0 ---ND ---
04/08/99 --- 10.0 ND ND ---
09/09/99 --- 10.0 ND ND ND
04/13/00 --- 10.0 ND ND ND
10/17/00 --- 10.0 Dry Dry ND
04/23/01 --- 10.0 ND ND ND
10/18/01 --- 10.0 ND ND ND
04/29/02 --- 10.0 ND ND ND
10/23/02 --- 10.0 ND ND ND
04/14/03 --- 10.0 ND ND ND
10/30/03 --- 10.0 ND ND ND
04/28/04 --- 10.0 80 ND ND
10/26/04 --- 10.0 ND ND ND
03/16/05 --- 10.0 ND ND ND
07/21/05 --- 10.0 ND Dry ND
01/26/06 --- 10.0 ND ND ND
07/21/06 --- 10.0 ND ND ND
01/22/07 --- 10.0 ND ND ND
07/23/07 --- 10.0 Dry ND ND
01/10/08 --- 10.0 3.90 J ND ND
07/21/08 --- 10.0 Dry Dry ND
01/29/09 --- 10.0 1.54 J 1.47 J ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 10.0 ND ND ND
07/15/10 --- 10.0 Dry Dry ND
01/20/11 --- 10.0 ND ND ND
07/14/11 --- 10.0 Dry 4.50 J ND
01/30/12 --- 10.0 2.56 B 3.67 B 1.16 J
07/25/12 --- 10.0 Dry Dry ND
02/04/13 --- 10.0 5.63 B 4.44 B 2.66 J
07/08/13 --- 10.0 6.25 B 11.6 1.50 J
01/21/14 0.58 10.0 5.82 3.82 ND
07/21/14 0.73 10.0 9.22 J 1.36 B 1.40 J
01/29/15 0.73 10.0 2.56 J ND ND
07/27/15 0.43 10.0 DRY 0.96 J ND
01/26/16 0.43 10.0 DRY 2.28 J ND
NC 2B = 24 µg/L; (d)(h), chronic 07/26/16 0.43 10.0 DRY 0.49 J ND
02/01/17 0.43 10.0 2.41 J 1.45 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 5 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Cobalt 06/16/97 --- 10.0 ND ND ---
No NC 2B Standard 08/14/97 --- 10.0 ---ND ---
09/30/97 --- 40.0 ---ND ---
04/30/98 --- 40.0 ND ND ---
09/15/98 --- 40.0 ---ND ---
04/08/99 --- 40.0 ND ND ---
09/09/99 --- 10.0 ND ND ND
04/13/00 --- 10.0 ND ND ND
10/17/00 --- 10.0 Dry Dry ND
04/23/01 --- 10.0 ND ND ND
10/18/01 --- 10.0 ND ND ND
04/29/02 --- 10.0 ND 10.0 ND
10/23/02 --- 10.0 ND ND ND
04/14/03 --- 10.0 ND ND ND
10/30/03 --- 10.0 ND ND ND
04/28/04 --- 10.0 20.0 ND ND
10/26/04 --- 10.0 ND ND ND
03/16/05 --- 10.0 ND ND ND
07/21/05 --- 10.0 ND Dry ND
01/26/06 --- 10.0 ND ND ND
07/21/06 --- 10.0 ND ND ND
01/22/07 --- 10.0 ND ND ND
07/23/07 --- 10.0 Dry ND ND
01/10/08 --- 10.0 ND ND ND
07/21/08 --- 10.0 Dry Dry ND
01/29/09 --- 10.0 ND ND ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 10.0 0.47 J 0.48 J ND
07/15/10 --- 10.0 Dry Dry ND
01/20/11 --- 10.0 ND ND ND
07/14/11 --- 10.0 Dry 1.11 J ND
01/30/12 --- 10.0 0.80 J 0.66 J ND
07/25/12 --- 10.0 Dry Dry ND
02/04/13 --- 10.0 1.17 J 0.71 J ND
07/08/13 --- 10.0 1.82 J 3.24 J ND
01/21/14 0.12 10.0 0.97 J 0.80 J ND
07/21/14 0.26 10.0 1.72 J 0.89 J ND
01/29/15 0.26 10.0 1.07 J 0.70 J ND
07/27/15 0.29 10.0 DRY 1.31 J ND
01/26/16 0.29 10.0 DRY 1.37 J ND
07/26/16 0.29 10.0 DRY 0.41 J ND
02/01/17 0.29 10.0 1.04 J 0.73 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 6 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Copper 07/21/05 --- 200 ND Dry ND
NC 2B = 7 µg/L 01/26/06 --- 200 ND ND ND
07/21/06 --- 200 ND ND ND
01/22/07 --- 10.0 2.80 J 1.30 J 0.90 J
07/23/07 --- 10.0 Dry 0.70 B 1.20 J
01/10/08 --- 10.0 1.90 J 2.00 J ND
07/21/08 --- 10.0 Dry Dry ND
01/29/09 --- 10.0 ND 1.40 J ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 10.0 3.07 J 2.08 J ND
07/15/10 --- 10.0 Dry Dry ND
01/20/11 --- 10.0 3.79 B 2.59 B 2.16 J
07/14/11 --- 10.0 Dry 4.36 B 1.85 J
01/30/12 --- 10.0 2.46 J 3.09 J ND
07/25/12 --- 10.0 Dry Dry 0.4 J
02/04/13 --- 10.0 3.45 J 2.07 J 0.19 J
07/08/13 --- 10.0 4.25 J 6.96 J ND
01/21/14 0.38 10.0 3.96 J 2.35 J ND
07/21/14 0.22 10.0 6.31 J 1.95 B 0.44 J
01/29/15 0.22 10.0 2.74 B 3.87 B 4.34 J
07/27/15 0.41 10.0 DRY 9.13 J 1.24 J
01/26/16 0.41 10.0 DRY 3.02 J 3.93 J
NC 2B =2.7 µg/L; (d)(h), chronic 07/26/16 0.41 10.0 DRY 3.20 B 6.73 J
02/01/17 0.41 10.0 1.84 B 2.01 B 1.04 J
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 7 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Lead 06/16/97 --- 10.0 ND ND ---
NC 2B = 25 µg/L 08/14/97 --- 10.0 ---ND ---
09/30/97 --- 15.0 ---ND ---
04/30/98 --- 15.0 ND ND ---
09/15/98 --- 15.0 ---ND ---
04/08/99 --- 15.0 ND ND ---
09/09/99 --- 10.0 ND ND ND
04/13/00 --- 10.0 ND ND ND
10/17/00 --- 10.0 Dry Dry ND
04/23/01 --- 10.0 ND ND ND
10/18/01 --- 10.0 ND ND ND
04/29/02 --- 10.0 ND ND ND
10/23/02 --- 10.0 ND ND ND
04/14/03 --- 10.0 ND ND ND
10/30/03 --- 10.0 ND ND ND
04/28/04 --- 10.0 60.0 ND ND
10/26/04 --- 10.0 ND ND ND
03/16/05 --- 10.0 ND ND ND
07/21/05 --- 10.0 ND Dry ND
01/26/06 --- 10.0 ND ND ND
07/21/06 --- 10.0 ND ND ND
01/22/07 --- 10.0 2.80 J 3.50 J ND
07/23/07 --- 10.0 Dry ND ND
01/10/08 --- 10.0 ND ND ND
07/21/08 --- 10.0 Dry Dry ND
01/29/09 --- 10.0 ND ND ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 10.0 1.15 J ND ND
07/15/10 --- 10.0 Dry Dry ND
01/20/11 --- 10.0 ND ND ND
07/14/11 --- 10.0 Dry ND ND
01/30/12 --- 10.0 0.87 J 0.69 J ND
07/25/12 --- 10.0 Dry Dry 0.29 J
02/04/13 --- 10.0 1.37 J 0.47 J ND
07/08/13 --- 10.0 4.57 J 6.71 J 0.09 J
01/21/14 0.05 10.0 1.46 J 0.72 J ND
07/21/14 0.05 10.0 3.75 J 6.29 J ND
01/29/15 0.05 10.0 4.15 J 4.13 J ND
07/27/15 0.08 10.0 ---47.4 ND
Verification sample >09/28/15 0.08 10.0 DRY 8.69 J 0.21 J
01/26/16 0.08 10.0 DRY 4.16 J ND
NC 2B = 0.54 µg/L; (d)(h), chronic 07/26/16 0.08 10.0 DRY 3.81 J ND
02/01/17 0.08 10.0 1.81 J 1.92 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 8 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Nickel 07/21/05 --- 50.0 ND Dry ND
NC 2B = 88 µg/L 01/26/06 --- 50.0 ND ND ND
07/21/06 --- 50.0 ND ND ND
01/22/07 --- 50.0 ND ND ND
07/23/07 --- 50.0 Dry ND ND
01/10/08 --- 50.0 3.20 J ND ND
07/21/08 --- 50.0 Dry Dry ND
01/29/09 --- 50.0 0.69 J 0.92 J ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 50.0 ND ND ND
07/15/10 --- 50.0 Dry Dry ND
01/20/11 --- 50.0 2.00 J ND ND
07/14/11 --- 50.0 Dry 3.07 J ND
01/30/12 --- 50.0 2.47 J 1.88 J ND
07/25/12 --- 50.0 Dry Dry ND
02/04/13 --- 50.0 2.22 J 1.25 J ND
07/08/13 --- 50.0 2.20 B 3.36 B 1.99 J
01/21/14 0.41 50.0 2.07 J 1.65 J ND
07/21/14 0.22 50.0 3.51 J 1.30 J ND
01/29/15 0.22 50.0 1.36 J 1.04 J ND
07/27/15 0.48 50.0 DRY 3.29 J ND
01/26/16 0.48 50.0 DRY 1.33 J ND
NC 2B = 16 µg/L; (d)(h), chronic 07/26/16 0.48 50.0 DRY 1.07 J ND
02/01/17 0.48 50.0 1.17 J 0.92 J ND
Selenium 02/04/13 --- 10.0 ND 0.73 J ND
NC 2B = 5 µg/L 07/08/13 --- 10.0 ND ND ND
01/21/14 0.77 10.0 ND ND 2.20 J
07/21/14 1.01 10.0 ND 1.43 B 2.88 J
01/29/15 1.01 10.0 ND ND ND
07/27/15 0.85 10.0 DRY ND ND
01/26/16 0.85 10.0 DRY ND ND
NC 2B = 5 µg/L 07/26/16 0.85 10.0 DRY ND ND
02/01/17 0.85 10.0 ND ND ND
Silver 01/29/15 0.17 10.0 ND 0.17 J ND
07/27/15 0.22 10.0 DRY 0.81 J ND
01/26/16 0.22 10.0 DRY ND ND
07/26/16 0.22 10.0 DRY ND ND
NC 2B = 0.06 µg/L; (d)(h), chronic 02/01/17 0.22 10.0 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 9 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Thallium 06/16/97 --- 10.0 ND ND ---
NC 2B = 0.47 µg/L 08/14/97 --- 10.0 ---ND ---
09/30/97 --- 10.0 ---ND ---
04/30/98 --- 10.0 ND ND ---
09/15/98 --- 10.0 ---ND ---
04/08/99 --- 10.0 ND ND ---
09/09/99 --- 10.0 ND ND ND
04/13/00 --- 10.0 ND ND ND
10/17/00 --- 10.0 Dry Dry ND
04/23/01 --- 10.0 ND ND ND
10/18/01 --- 10.0 ND ND ND
04/29/02 --- 10.0 ND ND ND
10/23/02 --- 10.0 ND ND ND
04/14/03 --- 10.0 ND ND ND
10/30/03 --- 10.0 ND ND ND
04/28/04 --- 10.0 ND ND ND
10/26/04 --- 10.0 ND ND ND
03/16/05 --- 10.0 ND ND ND
07/21/05 --- 10.0 11.00 Dry ND
01/26/06 --- 10.0 ND ND ND
07/21/06 --- 10.0 ND ND ND
01/22/07 --- 5.50 ND ND ND
07/23/07 --- 5.50 Dry ND 0.05 J
01/10/08 --- 5.50 ND ND ND
07/21/08 --- 5.50 Dry Dry ND
01/29/09 --- 5.50 ND ND ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 5.50 ND ND ND
07/15/10 --- 5.50 Dry Dry ND
01/20/11 --- 5.50 ND ND ND
07/14/11 --- 5.50 Dry ND ND
01/30/12 --- 5.50 ND ND ND
07/25/12 --- 5.50 Dry Dry ND
02/04/13 --- 5.50 ND ND ND
07/08/13 --- 5.50 ND ND ND
01/21/14 0.06 5.50 ND ND ND
07/21/14 0.09 5.50 ND ND ND
01/29/15 0.09 5.50 ND ND ND
07/27/15 0.06 5.50 DRY ND ND
01/26/16 0.06 5.50 DRY ND ND
07/26/16 0.06 5.50 DRY ND ND
02/01/17 0.06 5.50 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 10 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Vanadium 06/16/97 --- 40.0 ND ND ---
No NC 2B Standard 08/14/97 --- 40.0 ---ND ---
09/30/97 --- 20.0 ---ND ---
04/30/98 --- 20.0 ND ND ---
09/15/98 --- 20.0 ---ND ---
04/08/99 --- 20.0 ND ND ---
09/09/99 --- 40.0 ND ND ND
04/13/00 --- 40.0 ND ND ND
10/17/00 --- 40.0 Dry Dry ND
04/23/01 --- 40.0 ND ND ND
10/18/01 --- 40.0 ND ND ND
04/29/02 --- 40.0 ND ND ND
10/23/02 --- 40.0 ND ND ND
04/14/03 --- 40.0 ND ND ND
10/30/03 --- 40.0 ND ND ND
04/28/04 --- 40.0 130.00 ND ND
10/26/04 --- 40.0 ND ND ND
03/16/05 --- 40.0 ND ND ND
07/21/05 --- 40.0 ND Dry ND
01/26/06 --- 40.0 ND ND ND
07/21/06 --- 40.0 ND ND ND
01/22/07 --- 25.0 1.70 J ND ND
07/23/07 --- 25.0 Dry 1.50 J ND
01/10/08 --- 25.0 2.50 J 3.00 J ND
07/21/08 --- 25.0 Dry Dry ND
01/29/09 --- 25.0 2.48 J 2.56 J ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 25.0 1.59 J 1.12 J ND
07/15/10 --- 25.0 Dry Dry ND
01/20/11 --- 25.0 2.13 J ND ND
07/14/11 --- 25.0 Dry 5.56 J ND
01/30/12 --- 25.0 3.80 J 5.50 J ND
07/25/12 --- 25.0 Dry Dry ND
02/04/13 --- 25.0 8.56 B 2.08 B 2.12 J
07/08/13 --- 25.0 8.09 J 19.50 J ND
01/21/14 1.97 25.0 5.96 B 2.11 B ND
07/21/14 0.93 25.0 16.70 J 5.42 B 1.69 J
01/29/15 0.93 25.0 3.15 J 1.10 J ND
07/27/15 1.57 25.0 DRY 1.95 J ND
01/26/16 1.57 25.0 DRY 3.70 J ND
07/26/16 1.57 25.0 DRY ND ND
02/01/17 1.57 25.0 4.07 J 3.43 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 11 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Zinc 06/16/97 --- 50 230 510 ---
NC 2B = 50 µg/L 08/14/97 --- 50 ---90.0 ---
09/30/97 --- 20 ---60.0 ---
04/30/98 --- 20 40.0 70.0 ---
09/15/98 --- 20 ---ND ---
04/08/99 --- 20 30.0 ND ---
09/09/99 --- 50 ND ND 60.0
04/13/00 --- 50 ND ND ND
10/17/00 --- 50 Dry Dry ND
04/23/01 --- 50 ND ND ND
10/18/01 --- 50 ND ND ND
04/29/02 --- 50 ND 90.0 ND
10/23/02 --- 50 ND ND ND
04/14/03 --- 50 ND ND ND
10/30/03 --- 50 ND 60.0 ND
04/28/04 --- 50 70 ND ND
10/26/04 --- 50 ND ND ND
03/16/05 --- 50 ND ND ND
07/21/05 --- 50 ND Dry ND
01/26/06 --- 50 ND ND ND
07/21/06 --- 50 ND ND ND
01/22/07 --- 10 32.2 34.0 ND
07/23/07 --- 10.0 Dry 7.10 B 4.00 J
01/10/08 --- 10.0 5.7 J 2.80 J ND
07/21/08 --- 10.0 Dry Dry ND
01/29/09 --- 10.0 9.3 J 9.29 J 5.8 J
07/30/09 --- --- Dry Dry ---
01/14/10 --- 10.0 8.9 J 5.34 J ND
07/15/10 --- 10.0 Dry Dry ND
01/20/11 --- 10.0 10.3 ND ND
07/14/11 --- 10.0 Dry 8.29 J ND
01/30/12 --- 10.0 8.9 B 8.17 B 3.00 J
07/25/12 --- 10.0 Dry Dry 2.5 J
02/04/13 --- 10.0 8.4 3.33 B 0.76 J
07/08/13 --- 10.0 9.9 J 23.0 0.96 J
01/21/14 0.87 10.0 8.13 B 7.32 B 2.35 J
07/21/14 0.64 10.0 15.8 14.0 1.93 J
01/29/15 0.64 10.0 10.0 8.96 J 1.54 J
07/27/15 1.3 10.0 DRY 13.8 1.57 J
01/26/16 1.3 10.0 DRY 16.8 1.35 J
NC 2B = 36 µg/L; (d)(h), chronic 07/26/16 1.3 10.0 DRY 4.04 J 1.60 J
02/01/17 1.3 10.0 13.9 9.21 B 1.54 J
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 12 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Iron 07/23/07 --- 300 Dry 953 ND
NC 2B = 1000 µg/L 01/10/08 --- 300 1540 2280 ND
07/21/08 --- 300 Dry Dry ND
01/29/09 --- 300 1340 1660 33.80 J
07/30/09 --- --- Dry Dry ---
01/14/10 --- 300 959 1110 ND
07/15/10 --- 300 Dry Dry ND
01/20/11 --- 300 1320 749 ND
07/14/11 --- 300 Dry 2710 ND
01/30/12 --- 300 2050 2930 8.11 J
07/25/12 --- 40.0 Dry Dry 4.71 J
02/04/13 --- 30.0 3950 1710 5.53 J
07/08/13 --- 30.0 3300 8660 ND
01/21/14 3.02 30.0 4050 2870 4.96 J
07/21/14 3.1 40.0 7160 2040 ND
01/29/15 3.1 40.0 2250 1670 ND
07/27/15 5.72 40.0 DRY 1240 ND
01/26/16 5.72 40.0 DRY 2290 9.50 J
No NC 2B Standard 07/26/16 5.72 300.0 DRY 604 ND
02/01/17 5.72 300.0 2300 1940 12.20 J
Manganese 07/23/07 --- 50.0 Dry 28.7 J ND
NC 2L = 50 µg/L 01/10/08 --- 50.0 20.5 J 25.9 J ND
NC 2B water supply = 200 µg/L 07/21/08 --- 50.0 Dry Dry 2.80 J
01/29/09 --- 50.0 65.0 B 75.6 13.30 J
07/30/09 --- --- Dry Dry ---
01/14/10 --- 50.0 43.0 J 142 ND
07/15/10 --- 50.0 Dry Dry ND
01/20/11 --- 50.0 31.5 J 41.5 J ND
07/14/11 --- 50.0 Dry 91.4 1.16 J
01/30/12 --- 50.0 44.6 32.5 ND
07/25/12 --- 10.0 Dry Dry ND
02/04/13 --- 50.0 55.4 160 ND
07/08/13 --- 50.0 134 215 0.64 J
01/21/14 0.55 50.0 33.4 J 123 ND
07/21/14 0.395 50.0 49.8 J 193 2.27 J
01/29/15 0.395 50.0 75.7 128 1.33 J
07/27/15 1.04 50.0 DRY 381 ND
01/26/16 1.04 50.0 DRY 235 ND
No NC 2B Standard 07/26/16 1.04 50.0 DRY 254 ND
02/01/17 1.04 50.0 92.5 128 ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 13 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Organic Compounds
Acetone 07/21/05 --- 100 ND Dry ND
01/26/06 --- 100 ND ND ND
07/21/06 --- 100 ND ND ND
01/22/07 --- 100 ND ND ND
07/23/07 --- 100 Dry ND ND
01/10/08 --- 100 ND ND ND
07/21/08 --- 100 Dry Dry ND
01/29/09 --- 100 ND ND 16.0 J
07/30/09 --- 100 Dry Dry ND
01/14/10 --- 100 ND 9.2 J ND
07/15/10 --- 100 Dry Dry ND
01/20/11 --- 100 ND ND ND
07/14/11 --- 100 Dry ND ND
01/30/12 --- 100 ND ND ND
07/25/12 --- 100 Dry Dry ND
02/04/13 --- 100 Dry Dry ND
07/08/13 --- 100 ND ND ND
01/21/14 1.6 100 ND ND 3.7 J
07/21/14 5.7 100 ND ND ND
01/29/15 5.7 100 ND ND ND
07/27/15 3.1 100 DRY ND ND
01/26/16 4.9 100 DRY ND ND
07/26/16 4.9 100 DRY ND ND
02/01/17 8.2 100 ND ND ND
Methylene Chloride 01/26/16 0.5 1.0 DRY ND 0.90 J
No NC 2B Standard 07/26/16 0.5 1.0 DRY ND ND
02/01/17 0.5 1.0 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 14 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Carbon Disulfide 06/16/97 --- 100 ND ND ---
No NC 2B Standard 08/14/97 --- 100 ---ND ---
09/30/97 --- 5 ---ND ---
04/30/98 --- 5 11.00 73.00 ---
09/15/98 --- 5 ---ND ---
04/08/99 --- 5 ND ND ---
09/09/99 --- 100 ND ND ND
04/13/00 --- 100 ND ND ND
10/17/00 --- 100 Dry Dry ND
04/23/01 --- 100 ND ND ND
10/18/01 --- 100 ND ND ND
04/29/02 --- 100 ND ND ND
10/23/02 --- 100 ND ND ND
04/14/03 --- 100 ND ND ND
10/30/03 --- 100 ND ND ND
04/28/04 --- 100 ND ND ND
10/26/04 --- 100 ND ND ND
03/16/05 --- 100 ND ND ND
07/21/05 --- 100 ND Dry ND
01/26/06 --- 100 ND ND ND
07/21/06 --- 100 ND ND ND
01/22/07 --- 100 ND ND ND
07/23/07 --- 100 Dry ND ND
01/10/08 --- 100 ND ND ND
07/21/08 --- 100 Dry Dry ND
01/29/09 --- 100 ND ND ND
07/30/09 --- --- Dry Dry ---
01/14/10 --- 100 ND ND ND
07/15/10 --- 100 Dry Dry ND
01/20/11 --- 100 ND ND ND
07/14/11 --- 100 Dry ND ND
01/30/12 --- 100 ND ND ND
07/25/12 --- 100 Dry Dry ND
02/04/13 --- 100 ND ND 3.90 J
07/08/13 --- 100 ND ND ND
01/21/14 1.2 100 ND ND ND
07/21/14 0.8 100 ND ND ND
01/29/15 0.8 100 ND ND ND
07/27/15 0.3 100 DRY ND ND
01/26/16 0.9 100 DRY ND ND
07/26/16 0.6 100 DRY ND ND
02/01/17 0.8 100 ND ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 15 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Field Parameters
pH 06/16/97 --- --- 6.70 7.05 ---
(S.U.) 08/14/97 --- --- --- 6.90 ---
09/30/97 --- --- --- 7.46 ---
04/30/98 --- --- 7.18 7.10 ---
09/15/98 --- --- --- 7.10 ---
04/08/99 --- --- 6.97 7.39 ---
09/09/99 --- --- 8.13 7.86 ---
04/13/00 --- --- 7.50 6.45 ---
10/17/00 --- --- Dry Dry ---
04/23/01 --- --- 6.79 7.14 ---
10/18/01 --- --- 7.49 7.85 ---
04/29/02 --- --- 7.12 6.87 ---
10/23/02 --- --- 7.78 7.79 ---
04/14/03 --- --- 6.99 7.38 ---
10/30/03 --- --- 7.37 7.14 ---
04/28/04 --- --- 7.48 7.70 ---
10/26/04 --- --- 7.43 6.59 ---
03/16/05 --- --- 6.21 7.55 ---
07/21/05 --- --- 6.15 Dry ---
01/26/06 --- --- 7.34 8.75 ---
07/21/06 --- --- 6.67 7.51 ---
01/22/07 --- --- 6.84 7.84 ---
07/23/07 --- --- Dry 8.07 ---
01/10/08 --- --- 7.15 7.77 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 5.76 6.97 ---
07/30/09 --- --- Dry Dry ---
01/14/10 --- --- 7.66 7.62 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 7.97 7.35 ---
07/14/11 --- --- Dry 7.23 ---
01/30/12 --- --- 8.11 8.16 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 6.42 8.36 ---
07/08/13 --- --- 6.40 7.81 ---
01/21/14 --- --- 6.18 5.18 ---
07/21/14 --- --- --- 5.18 ---
01/29/15 FIELD --- 8.29 5.18 ---
07/27/15 FIELD --- --- 5.18 ---
09/28/15 FIELD --- DRY 5.18 ---
01/26/16 FIELD --- DRY 5.18 ---
07/26/16 FIELD --- DRY 6.89 ---
02/01/17 FIELD --- 7.63 8.27 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 16 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Conductivity 06/16/97 --- --- 113 179 ---
(µS/cm)08/14/97 --- --- ---111 ---
09/30/97 --- --- ---74.0 ---
04/30/98 --- --- 5.92 13.0 ---
09/15/98 --- --- ---53.0 ---
04/08/99 --- --- 33.0 54.0 ---
09/09/99 --- --- 25.0 42.0 ---
04/13/00 --- --- 39.0 65.0 ---
10/17/00 --- --- Dry Dry ---
04/23/01 --- --- 84.0 104 ---
10/18/01 --- --- 101 120 ---
04/29/02 --- --- 58.0 74.0 ---
10/23/02 --- --- 38.0 50.0 ---
04/14/03 --- --- 25.0 29.0 ---
10/30/03 --- --- 42.0 139 ---
04/28/04 --- --- 147 109 ---
10/26/04 --- --- 102 125 ---
03/16/05 --- --- 42.0 66.0 ---
07/21/05 --- --- 166 Dry ---
01/26/06 --- --- 36.0 78.0 ---
07/21/06 --- --- 134 124 ---
01/22/07 --- --- 45.0 101 ---
07/23/07 --- --- Dry 136 ---
01/10/08 --- --- 136 147 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 53.0 80.0 ---
01/30/09 --- --- Dry Dry ---
01/14/10 --- --- 51.0 106 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 60.0 144 ---
07/14/11 --- --- Dry 170 ---
01/30/12 --- --- 47.0 86.0 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 32.3 86.1 ---
07/08/13 --- --- 43.7 72.5 ---
01/21/14 --- --- 40.2 122.7 ---
07/21/14 --- --- ---120.5 ---
01/29/15 FIELD --- 45.3 828.0 ---
07/27/15 FIELD --- ---686 ---
09/28/15 FIELD --- DRY 409.9 ---
01/26/16 FIELD --- DRY 86.3 ---
07/26/16 FIELD --- DRY 253.2 ---
02/01/17 FIELD --- 48.2 84.2 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 17 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Temperature 06/16/97 --- --- 23.8 26.2 ---
(ºC)08/14/97 --- --- ---23.8 ---
09/30/97 --- --- ---19.3 ---
04/30/98 --- --- 19.4 14.7 ---
09/15/98 --- --- ---22.5 ---
04/08/99 --- --- 23.3 24.0 ---
09/09/99 --- --- 23.6 24.0 ---
04/13/00 --- --- 9.7 11.1 ---
10/17/00 --- --- Dry Dry ---
04/23/01 --- --- 20.4 21.9 ---
10/18/01 --- --- 7.8 7.0 ---
04/29/02 --- --- 17.3 18.4 ---
10/23/02 --- --- 16.9 17.7 ---
04/14/03 --- --- 18.6 20.6 ---
10/30/03 --- --- 12.2 11.5 ---
04/28/04 --- --- 18.5 13.6 ---
10/26/04 --- --- 15.0 14.3 ---
03/16/05 --- --- 5.74 6.71 ---
07/21/05 --- --- 23.57 Dry ---
01/26/06 --- --- 5.14 7.94 ---
07/21/06 --- --- 22.41 25.91 ---
01/22/07 --- --- 7.40 2.50 ---
07/23/07 --- --- Dry 20.98 ---
01/10/08 --- --- 9.15 9.59 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 6.71 7.53 ---
07/30/09 --- --- Dry Dry ---
01/14/10 --- --- 2.06 3.52 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 4.40 6.29 ---
07/14/11 --- --- Dry 22.92 ---
01/30/12 --- --- 8.82 8.28 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 4.90 3.80 ---
07/08/13 --- --- 26.3 25.4 ---
01/21/14 --- --- 6.50 8.10 ---
07/21/14 --- --- ---23.10 ---
01/29/15 FIELD --- 5.20 4.50 ---
07/27/15 FIELD --- ---24.8
09/28/15 FIELD --- DRY 21.2 ---
01/26/16 FIELD --- DRY 6.70 ---
07/26/16 FIELD --- DRY 20.8 ---
02/01/17 FIELD --- 11.5 8.1 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 18 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Turbidity 06/16/97 --- --- 570 281 ---
(NTU)08/14/97 --- --- ---NT ---
09/30/97 --- --- ---37.0 ---
04/30/98 --- --- 24.0 24.0 ---
04/08/99 --- --- 16.0 28.0 ---
09/09/99 --- --- 37.0 30.0 ---
04/13/00 --- --- 17.0 13.0 ---
10/17/00 --- --- Dry Dry ---
04/23/01 --- --- 159 21.0 ---
10/18/01 --- --- 5.0 51.0 ---
04/29/02 --- --- 26.0 7.3 ---
10/23/02 --- --- 13.0 22.0 ---
04/14/03 --- --- 15.0 24.0 ---
10/30/03 --- --- 38.0 289 ---
04/28/04 --- --- 137 15.0 ---
10/26/04 --- --- 24.0 28.0 ---
03/16/05 --- --- 184 116 ---
07/21/05 --- --- >1000 Dry ---
01/26/06 --- --- 188 166 ---
07/21/06 --- --- 188 0.0 ---
01/22/07 --- --- 50.0 54.6 ---
07/23/07 --- --- Dry 59.0 ---
01/10/08 --- --- 124 163 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 32.4 54.5 ---
07/30/09 --- --- Dry Dry ---
01/14/10 --- --- 26.9 17.7 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 24.70 17.50 ---
07/14/11 --- --- Dry 64.00 ---
01/30/12 --- --- 20.20 19.86 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 34.20 22.30 ---
07/08/13 --- --- 22.70 105 ---
01/21/14 --- --- 3.97 4.23 ---
07/21/14 --- --- ---90.00 ---
01/29/15 FIELD --- 20.40 13.30 ---
07/27/15 FIELD --- ---27.6 ---
09/28/15 FIELD --- DRY 13.4 ---
01/26/16 FIELD --- DRY 17.1 ---
07/26/16 FIELD --- DRY 8.3 ---
02/01/17 FIELD --- 192 21.84 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 19 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Oxidation Reduction Potential 03/16/05 --- --- 186 22.0 ---
(mV)07/21/05 --- --- -99.0 Dry ---
01/26/06 --- --- 102 -77.0 ---
07/21/06 --- --- 110 100 ---
01/22/07 --- --- 132 -91.0 ---
07/23/07 --- --- Dry 63.0 ---
01/10/08 --- --- 158.0 85.0 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 236.6 157.9 ---
07/30/09 --- --- Dry Dry ---
01/14/10 --- --- 16.8 3.3 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 60.2 37.2 ---
07/14/11 --- --- Dry 72.5 ---
01/30/12 --- --- -49.8 -22.2 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 145.3 78.7 ---
07/08/13 --- --- 77.7 36.6 ---
01/21/14 --- --- 104.8 147.1 ---
07/21/14 --- --- ---51.3 ---
01/29/15 FIELD --- 25.0 69.3 ---
07/27/15 FIELD --- ---70.1 ---
09/28/15 FIELD --- DRY 166.7 ---
01/26/16 FIELD --- DRY 64.1 ---
07/26/16 FIELD --- DRY 55.4
02/01/17 FIELD --- 17.5 28.3 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 20 of 21
Joyce Engineering
TABLE 8
Historical Surface Water Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample
Collection Date DL SWSL SW-1 SW-2 Blanks
Dissolved Oxygen 03/16/05 --- --- 7.22 6.96 ---
(mg/L)07/21/05 --- --- 7.74 Dry ---
01/26/06 --- --- 5.61 2.98 ---
07/21/06 --- --- 7.52 3.45 ---
01/22/07 --- --- 11.10 9.20 ---
07/23/07 --- --- Dry 6.80 ---
01/10/08 --- --- 8.69 10.54 ---
07/21/08 --- --- Dry Dry ---
01/29/09 --- --- 10.16 10.90 ---
07/30/09 --- --- Dry Dry ---
01/14/10 --- --- 14.29 13.20 ---
07/15/10 --- --- Dry Dry ---
01/20/11 --- --- 11.75 11.46 ---
07/14/11 --- --- Dry 6.79 ---
01/30/12 --- --- 11.84 11.96 ---
07/25/12 --- --- Dry Dry ---
02/04/13 --- --- 13.04 13.57 ---
07/08/13 --- --- 8.19 5.61 ---
01/21/14 --- --- 9.67 12.93 ---
07/21/14 --- --- ---9.04 ---
01/29/15 FIELD --- 13.25 14.45 ---
07/27/15 FIELD --- ---10.96 ---
09/28/15 FIELD --- DRY 4.21 ---
01/26/16 FIELD --- DRY 8.78 ---
07/26/16 FIELD --- DRY 1.34 ---
02/01/17 FIELD --- 10.45 10.76 ---
Notes:
DL = Method Detection Limit.
RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
SWSL = NC-DENR Solid Waste Section Limit.
NC 2B = Surface Water Standard established in 15A NCAC 2B (NC Freshwater Aquatic Life Standards)
ND = Not detected above the DL.
J = Estimated concentration below the RL.
B = Blank qualified data.
dry = Insufficient water flow for sampling.
--- = No data.
All inorganic and organic compounds are in µg/L.
mg/L = milligrams per liter
µg/L = micrograms per liter
S.U. = Standard Units.
NTU = Nephelometric Turbidity Units.
µS/cm= microsiemens per centimeter.
mV = Millivolts.
Bold = Concentrations above the NC 2B Standards.
Blanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 21 of 21
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Antimony 01/26/06 30.0 ND ND
07/21/06 30.0 ND ND
01/23/07 6.00 5.79 ND
07/23/07 6.00 9.48 ND
01/10/08 6.00 4.80 J ND
07/21/08 6.00 7.22 ND
01/29/09 6.00 4.82 J ND
07/30/09 6.00 6.38 ND
01/14/10 6.00 20.9 ND
07/15/10 6.00 9.01 J ND
01/20/11 6.00 29.7 ND
07/14/11 6.00 14.4 ND
01/30/12 6.00 53.4 0.33 J
07/25/12 6.00 30.7 ND
02/04/13 6.00 17.7 ND
07/08/13 6.00 18.8 ND
01/21/14 6.00 53.4 ND
07/21/14 6.00 31.6 ND
01/29/15 6.00 43.6 ND
07/27/15 6.00 33.3 ND
01/26/16 6.00 31.3 ND
07/26/16 6.00 88.2 ND
02/01/17 6.00 47.4 ND
Inorganic Compounds
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 1 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Arsenic 08/04/05 10.0 27.0 ND
01/26/06 10.0 14.0 ND
07/21/06 10.0 16.3 ND
01/23/07 10.0 ND ND
07/23/07 10.0 ND ND
01/10/08 10.0 ND ND
07/21/08 10.0 ND 3.8 J
01/29/09 10.0 ND 4.2 J
07/30/09 10.0 31.8 ND
01/14/10 10.0 15.7 ND
07/15/10 10.0 23.5 ND
01/20/11 10.0 67.3 ND
07/14/11 10.0 76.7 ND
01/30/12 10.0 75.7 ND
07/25/12 10.0 89.8 1.65 J
02/04/13 10.0 42.6 ND
07/08/13 10.0 11.0 ND
01/21/14 10.0 33.8 ND
07/21/14 10.0 82.7 ND
01/29/15 50.0 66.2 ND
07/27/15 10.0 93.6 ND
01/26/16 10.0 70.8 ND
07/26/16 10.0 131.0 ND
02/01/17 10.0 108.0 ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 2 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Barium 08/04/05 500 ND ND
01/26/06 500 ND ND
07/21/06 500 ND ND
01/23/07 100 152 0.50 J
07/23/07 100 334 0.50 J
01/10/08 100 259 ND
07/21/08 100 275 ND
01/29/09 100 193 0.50 J
07/30/09 100 208 ND
01/14/10 100 145 ND
07/15/10 100 131 ND
01/20/11 100 202 ND
07/14/11 100 202 ND
01/30/12 100 225 0.14 J
07/25/12 100 185 0.79 J
02/04/13 100 398 ND
07/08/13 100 271 ND
01/21/14 100 264 ND
07/21/14 100 178 0.34 J
01/29/15 100 190 1.33 J
07/27/15 100 212 0.41 J
01/26/16 100 216 0.55 J
07/26/16 100 220 0.30 J
02/01/17 100 215 ND
Total Beryllium 07/08/13 1.00 ND ND
07/21/14 1.00 0.08 J ND
01/29/15 1.00 0.08 J ND
07/27/15 1.00 ND ND
01/26/16 1.00 ND ND
07/26/16 1.00 ND ND
02/01/17 1.00 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 3 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Cadmium 08/04/05 1.00 ND ND
01/26/06 1.00 ND ND
07/21/06 1.00 ND ND
01/23/07 1.00 ND ND
07/23/07 1.00 ND ND
01/10/08 1.00 ND ND
07/21/08 1.00 ND ND
01/29/09 1.00 ND ND
07/30/09 1.00 0.17 J ND
01/14/10 1.00 ND ND
07/15/10 1.00 ND ND
01/20/11 1.00 ND ND
07/14/11 1.00 ND ND
01/30/12 1.00 ND ND
07/25/12 1.00 ND ND
02/04/13 1.00 ND ND
07/08/13 1.00 ND ND
01/21/14 1.00 0.06 J ND
07/21/14 1.00 ND ND
01/29/15 1.00 ND 0.06 J
07/27/15 1.00 ND ND
01/26/16 1.00 ND ND
07/26/16 1.00 ND ND
02/01/17 1.00 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 4 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Chromium 08/04/05 10.0 ND ND
01/26/06 10.0 ND ND
07/21/06 10.0 ND ND
01/23/07 10.0 ND ND
07/23/07 10.0 ND ND
01/10/08 10.0 ND ND
07/21/08 10.0 6.9 J ND
01/29/09 10.0 ND ND
07/30/09 10.0 67.0 ND
01/14/10 10.0 35.8 ND
07/15/10 10.0 54.0 ND
01/20/11 10.0 93.5 ND
07/14/11 10.0 97.6 ND
01/30/12 10.0 73.8 1.16 J
07/25/12 10.0 65.8 ND
02/04/13 10.0 38.1 2.66 J
07/08/13 10.0 49.6 ND
01/21/14 10.0 56.4 ND
07/21/14 10.0 91.3 1.40 J
01/29/15 10.0 98.8 ND
07/27/15 10.0 156 ND
01/26/16 10.0 142 ND
07/26/16 10.0 277 ND
02/01/17 10.0 260 ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 5 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Cobalt 08/04/05 10.0 23.0 ND
01/26/06 10.0 14.0 ND
07/21/06 10.0 13.6 ND
01/23/07 10.0 11.9 ND
07/23/07 10.0 34.0 J ND
01/10/08 10.0 15.7 ND
07/21/08 10.0 24.5 ND
01/29/09 10.0 18.2 ND
07/30/09 10.0 26.6 ND
01/14/10 10.0 13.2 ND
07/15/10 10.0 14.8 ND
01/20/11 10.0 27.3 ND
07/14/11 10.0 30.0 ND
01/30/12 10.0 23.9 ND
07/25/12 10.0 19.6 ND
02/04/13 10.0 16.1 ND
07/08/13 10.0 16.9 ND
01/21/14 10.0 26.0 ND
07/21/14 10.0 37.0 ND
01/29/15 10.0 28.5 ND
07/27/15 10.0 45.8 ND
01/26/16 10.0 33.3 ND
07/26/16 10.0 58.9 ND
02/01/17 10.0 61.9 ND
Total Copper 01/30/12 10.0 8.23 J ND
07/25/12 10.0 13.10 0.36 J
02/04/13 10.0 8.57 J 0.19 J
07/08/13 10.0 7.54 J ND
01/21/14 10.0 6.99 J ND
07/21/14 10.0 15.0 0.44 J
01/29/15 10.0 9.4 B 4.34 J
07/27/15 10.0 1.2 B 1.24 J
01/26/16 10.0 8.6 J 3.93 J
07/26/16 10.0 10.6 B 6.73 J
02/01/17 10.0 6.2 J 1.04 J
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 6 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Iron 01/26/16 40.0 ---9.50 J
02/01/17 300.0 ---12.20 J
Total Lead 08/04/05 10.0 ND ND
01/26/06 10.0 ND ND
07/21/06 10.0 ND ND
01/23/07 10.0 2.40 J ND
07/23/07 10.0 ND ND
01/10/08 10.0 ND ND
07/21/08 10.0 ND ND
01/29/09 10.0 ND ND
07/30/09 10.0 2.03 J ND
01/14/10 10.0 2.54 J ND
07/15/10 10.0 ND ND
01/20/11 10.0 ND ND
01/30/12 10.0 0.97 J ND
07/25/12 10.0 1.36 J 0.29 J
02/04/13 10.0 0.51 J ND
07/08/13 10.0 0.83 J ND
01/21/14 10.0 1.32 J ND
07/21/14 10.0 0.44 J ND
01/29/15 10.0 3.34 J ND
07/27/15 10.0 0.89 J ND
01/26/16 10.0 1.46 J ND
07/26/16 10.0 5.22 J ND
02/01/17 10.0 6.01 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 7 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Nickel 03/17/05 50.0 76.0 ---
08/04/05 50.0 160 ND
01/26/06 50.0 122 ND
07/21/06 50.0 111 ND
01/23/07 50.0 90.9 ND
07/23/07 50.0 249 ND
01/10/08 50.0 103 ND
07/21/08 50.0 178 ND
01/29/09 50.0 119 ND
07/30/09 50.0 162 ND
01/14/10 50.0 76.3 ND
07/15/10 50.0 97.7 ND
01/20/11 50.0 164 ND
07/14/11 50.0 179 ND
01/30/12 50.0 131 ND
07/25/12 50.0 107 ND
02/04/13 50.0 73.2 ND
07/08/13 50.0 101 ND
01/21/14 50.0 102 ND
07/21/14 50.0 181 ND
01/29/15 50.0 156 ND
07/27/15 50.0 215 ND
01/26/16 50.0 164 ND
07/26/16 50.0 222 ND
02/01/17 50.0 202 ND
Total Selenium 01/30/12 10.0 7.46 J ND
07/25/12 10.0 5.64 J ND
02/04/13 10.0 2.78 J ND
07/08/13 10.0 1.76 J ND
01/21/14 10.0 ND 2.20 J
07/21/14 10.0 8.25 J 2.88 J
01/29/15 10.0 7.65 J ND
07/27/15 10.0 5.58 J ND
01/26/16 10.0 5.94 J ND
07/26/16 10.0 7.42 J ND
02/01/17 10.0 8.45 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 8 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Silver 08/04/05 10.0 ND ND
01/26/06 10.0 ND ND
07/21/06 10.0 ND ND
01/23/07 10.0 ND ND
07/23/07 10.0 ND ND
01/10/08 10.0 ND ND
07/21/08 10.0 ND ND
01/29/09 10.0 ND ND
07/30/09 10.0 ND ND
01/14/10 10.0 0.81 J ND
07/15/10 10.0 ND ND
01/20/11 10.0 ND ND
07/14/11 10.0 3.28 J ND
01/30/12 10.0 0.88 J ND
07/25/12 10.0 0.79 J ND
02/04/13 10.0 0.40 J ND
07/08/13 10.0 0.53 J ND
01/21/14 10.0 0.38 J ND
07/21/14 10.0 1.08 J ND
01/29/15 10.0 0.72 J ND
07/27/15 10.0 0.82 J ND
01/26/16 10.0 ND ND
07/26/16 10.0 ND ND
02/01/17 10.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 9 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Thallium 08/04/05 10.0 ND ND
01/26/06 10.0 ND ND
07/21/06 10.0 ND ND
01/23/07 5.50 ND ND
07/23/07 5.50 ND ND
01/10/08 5.50 ND ND
07/21/08 5.50 ND ND
01/29/09 5.50 ND ND
07/30/09 5.50 ND ND
01/14/10 5.50 ND ND
07/15/10 5.50 1.22 J ND
01/20/11 5.50 ND ND
07/14/11 5.50 ND ND
01/30/12 5.50 ND ND
07/25/12 5.50 ND ND
02/04/13 5.50 ND ND
07/08/13 6.00 ND ND
01/21/14 5.50 ND ND
07/21/14 5.50 ND ND
01/29/15 5.50 ND ND
07/27/15 5.50 0.22 J ND
01/26/16 5.50 ND ND
07/26/16 5.50 ND ND
02/01/17 5.50 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 10 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Vanadium 08/04/05 40.0 55.00 ND
01/26/06 40.0 ND ND
07/21/06 40.0 ND ND
01/23/07 25.0 ND ND
07/23/07 25.0 55.50 ND
01/10/08 25.0 ND ND
07/21/08 25.0 26.30 ND
01/29/09 25.0 5.90 J ND
07/30/09 25.0 54.20 ND
01/14/10 25.0 21.30 J ND
07/15/10 25.0 39.20 ND
01/20/11 25.0 60.60 ND
07/14/11 25.0 61.1 ND
01/30/12 25.0 51.6 ND
07/25/12 25.0 47.8 ND
02/04/13 25.0 30.7 2.12 J
07/08/13 25.0 31.6 ND
01/21/14 25.0 41.9 14.6 J
07/21/14 25.0 58.3 1.69 J
01/29/15 25.0 53.1 ND
07/27/15 25.0 94.9 ND
01/26/16 25.0 67.3 ND
07/26/16 25.0 102 ND
02/01/17 25.0 107 ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 11 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Total Zinc 08/04/05 50.0 ND ND
01/26/06 50.0 ND ND
07/21/06 50.0 ND ND
01/23/07 10.0 26.9 1.50 J
07/23/07 10.0 43.0 J 4.00 J
01/10/08 10.0 11.4 ND
07/21/08 10.0 11.4 ND
01/29/09 10.0 17.5 B 5.82 J
07/30/09 10.0 13.2 ND
01/14/10 10.0 28.1 ND
07/15/10 10.0 7.55 J ND
01/20/11 10.0 22.6 ND
07/14/11 10.0 27.2 ND
01/30/12 10.0 17.2 3.00 J
07/25/12 10.0 32.6 2.48 J
02/04/13 10.0 40.4 0.76 J
07/08/13 10.0 17.0 0.96 J
01/21/14 10.0 472 2.35 J
07/21/14 10.0 88.5 1.93 J
01/29/15 10.0 107 3.61 J
07/27/15 10.0 58.4 1.57 J
01/26/16 10.0 97.8 1.35 J
07/26/16 10.0 603 1.60 J
02/01/17 10.0 1150 1.54 J
Total Mercury 01/29/15 0.50 ND ND
07/27/15 0.20 0.09 J ND
01/26/16 1.33 ND ND
07/26/16 1.33 ND ND
02/01/17 0.20 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 12 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Organic Compounds
Acetone 08/04/05 100 ND ND
01/26/06 25 ND ND
07/21/06 100 329 ND
01/23/07 100 440 ND
07/23/07 100 74 ND
01/10/08 100 2800 ND
07/21/08 100 ND ND
01/29/09 100 71 B 16.0 J
07/30/09 100 ND ND
01/14/10 100 5800 ND
07/15/10 100 ND ND
01/20/11 100 9900 ND
07/14/11 100 77.0 J ND
01/30/12 100 5600 D ND
07/25/12 1000 1400 ND
02/04/13 2500 4100 D ND
07/08/13 100 47.0 J ND
01/21/14 5000 6200 3.7 J
07/21/14 100 8.7 J ND
01/29/15 100 830 ND
07/27/15 100 21.0 J ND
01/26/16 100 100 ND
07/26/16 100 17.0 J ND
02/01/17 100 19.0 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 13 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Benzene 08/04/05 5.0 ND ND
01/26/06 5.0 ND ND
07/21/06 5.0 ND ND
01/23/07 3.0 2.6 ND
07/23/07 1.0 3.8 J ND
01/10/08 1.0 ND ND
07/21/08 1.0 ND ND
01/29/09 1.0 4.6 J ND
07/30/09 1.0 4.1 J 4.1 J
01/14/10 1.0 ND ND
07/15/10 1.0 6.4 ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 4.7 ND
07/25/12 1.0 ND ND
02/04/13 1.0 5.8 ND
07/08/13 1.0 4.7 ND
01/21/14 1.0 2.8 ND
07/21/14 1.0 2.9 ND
01/29/15 1.0 5.5 ND
07/27/15 1.0 3.9 ND
01/26/16 1.0 2.6 ND
07/26/16 1.0 0.40 J ND
02/01/17 1.0 ND ND
Chloroform 01/29/15 5.0 0.300 J ND
07/27/15 5.0 ND ND
01/26/16 5.0 ND ND
07/26/16 5.0 0.30 J ND
02/01/17 5.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 14 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
1,2-Dibromoethane 01/29/15 1.0 0.400 J ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Carbon Disulfide 08/04/05 100 ND ND
01/26/06 25 ND ND
07/21/06 100 ND ND
01/23/07 100 1.40 J ND
07/23/07 100 ND ND
01/10/08 100 ND ND
07/21/08 100 ND ND
01/29/09 100 ND ND
07/30/09 100 ND ND
01/14/10 100 ND ND
07/15/10 100 ND ND
01/20/11 100 ND ND
07/14/11 100 ND ND
01/30/12 100 11.0 J ND
07/25/12 100 1.80 J 3.90
02/04/13 100 ND 3.90 J
07/08/13 100 ND ND
01/21/14 100 10 ND
07/21/14 100 0.50 J ND
01/29/15 100 1.50 J ND
07/27/15 100 0.80 J ND
01/26/16 100 ND ND
07/26/16 100 ND ND
02/01/17 100 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 15 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Chlorobenzene 01/30/12 3.0 0.70 J ND
07/25/12 3.0 0.50 B 0.40 J
02/04/13 3.0 0.70 J ND
07/08/13 3.0 0.80 J ND
01/21/14 3.0 ND ND
07/21/14 3.0 0.60 J ND
01/29/15 3.0 1.50 J ND
07/27/15 3.0 0.50 J ND
01/26/16 3.0 0.70 J ND
07/26/16 3.0 ND ND
02/01/17 3.0 ND ND
Chloroethane 02/04/13 10 0.7 J ND
07/08/13 10 ND ND
01/21/14 10 0.6 ND
07/21/14 10 ND ND
01/29/15 10 ND ND
07/27/15 10 ND ND
01/26/16 10 ND ND
07/26/16 10 ND ND
02/01/17 10 ND ND
Chloromethane 01/30/12 1.0 0.5 J ND
07/25/12 1.0 ND 0.1 J
02/04/13 1.0 ND 0.1 J
07/08/13 1.0 ND ND
01/21/14 1.0 0.5 ND
07/21/14 1.0 ND ND
01/29/15 1.0 ND ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
1,2-Dichlorobenzene 01/29/15 5.0 0.70 J ND
07/27/15 5.0 ND ND
01/26/16 5.0 ND ND
07/26/16 5.0 ND ND
02/01/17 5.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 16 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
1,4-Dichlorobenzene 08/04/05 5.0 ND ND
01/26/06 5.0 5.0 ND
07/21/06 5.0 5.7 ND
01/23/07 3.0 5.6 ND
07/23/07 1.0 4.8 J ND
01/10/08 1.0 ND ND
07/21/08 1.0 4.1 J ND
01/29/09 1.0 9.5 J ND
07/30/09 1.0 6.6 6.6
01/14/10 1.0 ND ND
07/15/10 1.0 9.8 ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 8.6 ND
07/25/12 1.0 4.1 ND
02/04/13 1.0 7.2 ND
07/08/13 1.0 ND ND
01/21/14 1.0 2.2 ND
07/21/14 1.0 4.4 ND
01/29/15 1.0 9.8 ND
07/27/15 1.0 5.6 ND
01/26/16 1.0 7.2 ND
07/26/16 1.0 1.4 ND
02/01/17 1.0 2.9 ND
1,1-Dichloroethane 01/30/12 5.0 0.30 J ND
07/25/12 5.0 ND ND
02/04/13 5.0 0.80 J ND
07/08/13 5.0 ND ND
01/21/14 5.0 ND ND
07/21/14 5.0 ND ND
01/29/15 5.0 0.40 J ND
07/27/15 5.0 ND ND
01/26/16 5.0 ND ND
07/26/16 5.0 ND ND
02/01/17 5.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 17 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
1,2-Dichloroethane 08/04/05 5.0 ND ND
01/26/06 5.0 ND ND
07/21/06 5.0 ND ND
01/23/07 3.0 1.3 J ND
07/23/07 1.0 ND ND
01/10/08 1.0 ND ND
07/21/08 1.0 ND ND
01/29/09 1.0 ND ND
07/30/09 1.0 ND ND
01/14/10 1.0 ND ND
07/15/10 1.0 ND ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 1.0 ND
07/25/12 1.0 ND ND
02/04/13 1.0 5.8 ND
07/08/13 1.0 ND ND
01/21/14 1.0 3.3 ND
07/21/14 1.0 ND ND
01/29/15 1.0 0.8 J ND
07/27/15 1.0 0.3 J ND
01/26/16 1.0 0.3 J ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
cis-1,2-Dichloroethene 02/04/13 5.0 2.8 J ND
07/08/13 5.0 ND ND
01/21/14 5.0 ND ND
07/21/14 5.0 ND ND
01/29/15 5.0 ND ND
07/27/15 5.0 ND ND
01/26/16 5.0 ND ND
07/26/16 5.0 ND ND
02/01/17 5.0 ND ND
Trans-1,2-Dichloroethene 02/04/13 5.0 1.8 J ND
07/08/13 5.0 ND ND
01/21/14 5.0 ND ND
07/21/14 5.0 ND ND
01/29/15 5.0 0.30 J ND
07/27/15 5.0 ND ND
01/26/16 5.0 ND ND
07/26/16 5.0 ND ND
02/01/17 5.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 18 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
1,2-Dichloropropane 01/29/15 1.0 0.500 J ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 19 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Ethylbenzene 08/04/05 5.0 ND ND
01/26/06 5.0 ND ND
07/21/06 5.0 12.9 ND
01/23/07 5.0 3.8 ND
07/23/07 1.0 2.5 J ND
01/10/08 1.0 28 ND
07/21/08 1.0 7.4 J ND
01/29/09 1.0 ND ND
07/30/09 1.0 5.8 5.8
01/14/10 1.0 42 J ND
07/15/10 1.0 25 ND
01/20/11 1.0 ND ND
07/14/11 1.0 9.6 ND
01/30/12 1.0 9.0 ND
07/25/12 1.0 4.9 ND
02/04/13 1.0 20 ND
07/08/13 1.0 ND ND
01/21/14 1.0 5.3 ND
07/21/14 1.0 7.9 ND
01/29/15 1.0 16.0 ND
07/27/15 1.0 7.4 ND
01/26/16 1.0 2.2 ND
07/26/16 1.0 0.50 J ND
02/01/17 1.0 1.30 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 20 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Methylene Chloride 08/04/05 10 ND ND
01/26/06 10 25.0 ND
07/21/06 10 ND ND
01/23/07 5.5 ND ND
07/23/07 1.0 ND ND
01/10/08 1.0 9.0 J ND
07/21/08 1.0 ND ND
01/29/09 1.0 ND ND
07/30/09 1.0 ND ND
01/14/10 1.0 ND ND
07/15/10 1.0 ND ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 ND ND
07/25/12 1.0 ND 0.5 J
02/04/13 1.0 6.5 ND
07/08/13 1.0 ND ND
01/21/14 1.0 2.6 ND
07/21/14 1.0 ND ND
01/29/15 1.0 ND ND
07/27/15 1.0 1.1 ND
01/26/16 1.0 0.70 J 0.90 J
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 21 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Methyl Butyl Ketone (2-Hexanone)07/25/12 50 3.6 J ND
02/04/13 50 16 J ND
07/08/13 50 ND ND
01/21/14 50 13 ND
07/21/14 50 ND ND
01/29/15 50 7 J ND
07/27/15 50 6.4 J ND
01/26/16 50 3.1 J ND
07/26/16 50 ND ND
02/01/17 50 ND ND
Methyl Ethyl Ketone (2-Butanone)08/04/05 100 ND ND
01/26/06 25 255 ND
07/21/06 100 478 ND
01/23/07 100 440 ND
07/23/07 100 ND ND
01/10/08 100 4800 ND
07/21/08 100 ND ND
01/29/09 100 ND ND
07/30/09 100 ND ND
01/14/10 100 4800 ND
07/15/10 100 ND ND
01/20/11 100 6200 ND
07/14/11 100 ND ND
01/30/12 100 4800 D ND
07/25/12 1000 1500 ND
02/04/13 2500 3500 ND
07/08/13 200 ND ND
01/21/14 5000 8400 2.70 J
07/21/14 100 ND 1.10 J
01/29/15 100 1200 ND
07/27/15 100 ND ND
01/26/16 100 ND ND
07/26/16 100 ND ND
02/01/17 100 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 22 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
4-Methyl-2-pentanone (MIBK)08/04/05 100 ND ND
01/26/06 25 25 ND
07/21/06 100 ND ND
01/23/07 100 16 ND
07/23/07 100 ND ND
01/10/08 100 56 J ND
07/21/08 100 ND ND
01/29/09 100 ND ND
07/30/09 100 13 J 13 J
01/14/10 100 350 ND
07/15/10 100 ND ND
01/20/11 100 ND ND
07/14/11 100 37 J ND
01/30/12 100 82 J ND
07/25/12 100 22 ND
02/04/13 100 100 12 J
07/08/13 100 ND ND
01/21/14 100 36 ND
07/21/14 100 15 J ND
01/29/15 100 57 J ND
07/27/15 100 15 J ND
01/26/16 100 25 J ND
07/26/16 100 5.5 J ND
02/01/17 100 21.0 J ND
Styrene 02/04/13 1.0 2.30 ND
07/08/13 1.0 ND ND
01/21/14 1.0 ND ND
07/21/14 1.0 ND ND
01/29/15 1.0 2.20 ND
07/27/15 1.0 2.6 ND
01/26/16 1.0 2.5 ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 23 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Toluene 08/04/05 5.0 ND ND
01/26/06 5.0 11.0 ND
07/21/06 5.0 23.2 ND
01/23/07 5.0 6.4 ND
07/23/07 1.0 3.0 B 0.60 J
01/10/08 1.0 52 ND
07/21/08 1.0 6.8 J ND
01/29/09 1.0 ND ND
07/30/09 1.0 3.6 J 3.60 J
01/14/10 1.0 46 J ND
07/15/10 1.0 11.0 ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 9.6 ND
07/25/12 1.0 2.0 ND
02/04/13 1.0 46 ND
07/08/13 1.0 44 ND
01/21/14 1.0 29 ND
07/21/14 1.0 8.2 ND
01/29/15 1.0 19.0 ND
07/27/15 1.0 5.3 ND
01/26/16 1.0 5.8 ND
07/26/16 1.0 0.4 J ND
02/01/17 1.0 1.5 J ND
Tetrachloroethene 01/29/15 1.0 0.400 J ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Trichloroethene 02/04/13 1.0 1.0 J ND
07/08/13 1.0 ND ND
01/21/14 1.0 ND ND
07/21/14 1.0 ND ND
01/29/15 1.0 ND ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 24 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Vinyl chloride 08/04/05 10.0 ND ND
01/26/06 5.0 ND ND
07/21/06 10.0 ND ND
01/23/07 5.5 0.68 J ND
07/23/07 1.0 ND ND
01/10/08 1.0 ND ND
07/21/08 1.0 ND ND
01/29/09 1.0 ND ND
07/30/09 1.0 ND ND
01/14/10 1.0 ND ND
07/15/10 1.0 ND ND
01/20/11 1.0 ND ND
07/14/11 1.0 ND ND
01/30/12 1.0 0.60 J ND
07/25/12 1.0 ND ND
02/04/13 1.0 1.10 ND
07/08/13 1.0 1.20 ND
01/21/14 1.0 0.4 ND
07/21/14 1.0 ND ND
01/29/15 1.0 0.8 J ND
07/27/15 1.0 ND ND
01/26/16 1.0 ND ND
07/26/16 1.0 ND ND
02/01/17 1.0 ND ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 25 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Xylenes, total 08/04/05 5.0 22 ND
01/26/06 5.0 16 ND
07/21/06 5.0 54 ND
01/23/07 --- 25 ND
07/23/07 4.0 32 ND
01/10/08 5.0 68 ND
07/21/08 5.0 35 ND
01/29/09 5.0 24 ND
07/30/09 5.0 47 47.0
01/14/10 5.0 90 ND
07/15/10 5.0 70 ND
01/20/11 5.0 44 ND
07/14/11 5.0 28 ND
01/30/12 5.0 33 ND
07/25/12 5.0 28 ND
02/04/13 5.0 68 ND
07/08/13 5.0 41 ND
01/21/14 5.0 11 ND
07/21/14 5.0 24 ND
01/29/15 5.0 50 ND
07/27/15 5.0 33 ND
01/26/16 5.0 20 ND
07/26/16 5.0 ND ND
02/01/17 5.0 7.5 J ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 26 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Additional Parameters
Cyanide, Total 01/14/10 10.0 ND ND
07/15/10 0.01 ND ND
01/20/11 0.01 0.01 J ND
07/14/11 0.01 ND ND
01/30/12 20.0 ND ND
07/25/12 10.0 ND ND
02/04/13 10.0 ND 2.0 J
07/08/13 50.0 ND ND
01/21/14 50.0 ND ND
07/21/14 50.0 ND ---
01/29/15 10.0 ND ND
07/27/15 10.0 ND ND
01/26/16 50.0 ND ND
07/26/16 100.0 ND ND
02/01/17 100.0 ND ---
Nitrate as N 03/17/05 0.10 ND ---
08/04/05 0.10 ND ND
01/26/06 0.05 ND ND
07/24/06 0.05 ND ND
01/23/07 --- 0.26 ND
06/12/07 --- ND ND
07/23/07 --- 0.05 J ND
01/10/08 10.0 0.03 J ND
07/21/08 10.0 ND -
01/29/09 10.0 0.04 J ND
07/30/09 10.0 ND ND
01/14/10 10.0 0.02 J ---
07/15/10 10.0 0.06 J -
01/20/11 10.0 ND ND
07/14/11 10.0 0.12 J ND
01/30/12 50.0 19.0 J ND
07/25/12 50.0 ND ND
02/04/13 250 ND ND
07/08/13 50.0 ND ND
01/21/14 100 ND ND
07/21/14 50 ND ---
02/25/15 100 ND ND
07/27/15 500 ND ND
01/26/16 50 760 ND
07/26/16 500 ND ND
02/01/17 50 ND ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 27 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Nitrite as N 07/23/07 --- 0.02 J ND
01/10/08 1.0 0.02 J ND
07/21/08 1.0 0.04 B 0.01 J
01/29/09 1.0 ND ND
07/30/09 1.0 0.02 B 0.01 J
01/14/10 1.0 0.01 J ND
07/15/10 1.0 0.03 J 0.01 J
01/20/11 1.0 0.02 J ND
07/14/11 1.0 0.04 J ND
01/30/12 50.0 190 ND
07/25/12 50.0 ND ND
02/04/13 250 ND ND
07/08/13 50.0 ND ND
01/21/14 100 550 ND
07/21/14 50 ND ---
02/25/15 100 ND ND
07/27/15 500 ND ND
01/26/16 50 1400 ND
07/26/16 500 600 ND
02/01/17 2500 ND ---
Sulfate 03/17/05 2.0 23.0 ---
08/04/05 2.0 13.2 ND
01/26/06 2.0 5.2 ---
07/21/06 0.30 10.6 ND
01/23/07 --- 25.0 2.25 J
07/23/07 --- 26.0 J ND
01/10/08 250 3.0 J ND
07/21/08 250 3.9 J ND
01/29/09 250 6.8 J ND
07/30/09 250 6.9 J ND
01/14/10 250 4.1 J ND
07/15/10 250 2.0 J ND
01/20/11 250 7.9 J ND
07/14/11 250 2.8 J ND
01/30/12 5000 650 J ND
07/25/12 5000 ND ND
02/04/13 10000 ND ND
07/08/13 10000 ND ND
01/21/14 10000 38000 ND
07/21/14 5000 ND ---
01/29/15 250000 ND ND
07/27/15 5000 ND ND
01/26/16 5000 23000 ND
07/26/16 5000 48000 ND
02/01/17 5000 22000 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 28 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Biochemical Oxygen Demand 03/17/05 2.0 40.0 ---
08/04/05 2.0 55.1 ND
01/26/06 2.0 68.0 ---
07/24/06 2.0 50.0 ND
01/23/07 --- 44.0 ND
06/12/07 --- 53.0 ND
07/23/07 --- 100 ND
01/10/08 --- 280 ND
04/17/08 --- 66.0 ND
07/21/08 --- 72.0 ND
01/29/09 --- ND ND
07/30/09 --- 70.0 ND
01/14/10 --- 210 ND
07/15/10 --- 48.0 ND
01/20/11 --- 180.0 ND
07/14/11 --- 75.0 ND
01/30/12 31000 246000 ND
07/25/12 24000 98000 ND
02/04/13 13.0 322 ND
07/08/13 16000 97000 20.0 J
01/21/14 69000 69000 ND
07/21/14 23000 45000 10.0
02/25/15 30000 122000 180 J
07/27/15 32000 97000 D ND
01/26/16 33000 103000 D ND
07/26/16 85000 144000 D ND
02/01/17 51000 138000 D ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 29 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Chemical Oxygen Demand 03/17/05 10 560 ---
08/04/05 10 1030 ND
01/26/06 10 866 ---
07/21/06 10 ND ND
01/23/07 --- 708 ND
07/23/07 --- 1600 ND
01/10/08 --- 1000 ND
07/21/08 --- 1200 ND
01/29/09 --- 860 ND
07/30/09 --- 1200 ND
01/14/10 --- 1200 ND
07/15/10 --- 1300 ND
01/20/11 --- 1600 ND
07/14/11 --- 1500 ND
01/30/12 100000 1970000 ND
07/25/12 100000 1510000 ND
02/04/13 100 1370000 6280 J
07/08/13 200 1180000 7700 J
01/21/14 100 4680000 ND
07/21/14 200 1400000 ---
01/29/15 50 1580000 ND
07/27/15 100000 1860000 ND
01/26/16 50000 1930000 ND
07/26/16 100000 2770000 ND
02/01/17 50 3010000 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 30 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Phosphorus-Total 03/17/05 0.03 1.8 ---
08/04/05 0.03 2.1 ND
01/26/06 0.03 4.0 ---
07/21/06 0.03 2.0 ND
01/23/07 --- 4.3 ND
07/23/07 --- 10.0 ND
01/10/08 --- 5.8 ND
07/21/08 --- 9.2 ND
01/29/09 --- 9.7 ND
07/30/09 --- 12.0 ND
01/14/10 --- 11.0 ND
07/15/10 --- 14.0 ND
01/20/11 --- 15.0 ND
07/14/11 --- 19.0 ND
01/30/12 500 15800 ND
07/25/12 555 13000 ND
02/04/13 0.22 7510 ND
07/08/13 2.00 7000 ND
01/21/14 2.00 6800 ND
07/21/14 2000 18900 ---
01/29/15 222 10500 D ---
07/27/15 0 8270 D ND
01/26/16 222 3360 D ND
07/26/16 2000 19300 ND
02/01/17 2 14300 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 31 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Nitrate/Nitrite as N 07/23/07 --- 0.07 B 0.02 J
01/10/08 --- 0.05 J ND
07/21/08 --- ND ND
01/29/09 --- 0.04 J ND
07/30/09 --- ND ND
01/14/10 --- 0.03 B 0.03
07/15/10 --- 0.08 J ND
01/20/11 --- ND ND
07/14/11 --- 0.16 ND
01/30/12 50.0 190 J ND
07/25/12 50.0 ND ND
02/04/13 250 ND ND
07/08/13 50.0 ND ND
01/21/14 100 600 ND
07/21/14 50 ND ---
02/25/15 100 ND ---
07/27/15 500 ND ND
01/26/16 50 2200 ND
07/26/16 500 830 ND
02/01/17 50 ND ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 32 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Diesel Range Organics 01/26/16 2800 ND
07/26/16 200.00 6800 ND
02/01/17 200.00 5300 ND
Gasoline Range Organics 01/26/16 1000 ND
07/26/16 100.00 700 ND
02/01/17 100.00 400 ND
BTEX. total 01/26/16 30 ND
07/26/16 2.00 ND ND
02/01/17 2.00 8 ND
Ammonia as N 06/12/07 --- 470 ---
07/23/07 --- 940 ---
01/10/08 --- 440 ND
04/17/08 --- 280 ND
07/21/08 --- 640 0.01
01/29/09 --- 500 ND
07/30/09 --- 710 ND
01/14/10 --- 460 ND
07/15/10 --- 760 ND
01/20/11 --- 760 ND
07/14/11 --- 870 ND
01/30/12 10000.00 640000 ND
07/25/12 20.00 810000 ND
02/04/13 10.00 325000 ND
07/08/13 20.00 608000 ND
01/21/14 10 408000 ND
07/21/14 10000 1180000 ---
01/29/15 10 853000 ---
07/27/15 10 559000 ND
01/26/16 5000 645000 ND
07/26/16 10000 1640000 ND
02/01/17 10000 1690000 ND
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 33 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Field Parameters
pH 03/17/05 --- 6.95 ---
(S.U.) 08/04/05 --- 7.91 ---
01/26/06 --- 3.50 ---
07/21/06 --- 7.43 ---
01/23/07 --- 7.53 ---
07/23/07 --- 8.19 ---
01/10/08 --- 7.30 ---
07/21/08 --- 7.77 ---
01/29/09 --- 7.28 ---
07/30/09 --- 7.43 ---
01/14/10 --- 6.77 ---
07/15/10 --- 7.64 ---
01/20/11 --- 7.62 ---
07/14/11 --- 7.68 ---
01/30/12 --- 7.20 ---
07/25/12 --- 7.94 ---
02/04/13 --- 7.34 ---
07/08/13 --- 7.80 ---
01/21/14 --- 6.06 ---
07/21/14 --- 7.91 ---
01/29/15 FIELD 7.25 ---
07/27/15 FIELD 7.84 ---
01/26/16 FIELD 7.84 ---
07/26/16 FIELD 8.15 ---
02/01/17 FIELD 8.26 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 34 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Conductivity 03/17/05 --- 3240 ---
(µS/cm)08/04/05 --- 1078 ---
01/26/06 --- 3680 ---
07/21/06 --- 7460 ---
01/23/07 --- 4860 ---
07/23/07 --- 16000 ---
01/10/08 --- 7140 ---
07/21/08 --- 9000 ---
01/29/09 --- 9500 ---
07/30/09 --- 12720 ---
01/14/10 --- 8756 ---
07/15/10 --- 11840 ---
01/20/11 --- 12180 ---
07/14/11 --- 13250 ---
01/30/12 --- 10950 ---
04/19/12 --- 8460 ---
07/25/12 --- 9019 ---
02/04/13 --- 4678 ---
07/08/13 --- 9232 ---
01/21/14 --- 5917 ---
07/21/14 --- 15103 ---
01/29/15 FIELD 834 ---
07/27/15 FIELD 17437 ---
01/26/16 FIELD 9638 ---
07/26/16 FIELD >3999 ---
02/01/17 FIELD 14129 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 35 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Temperature 03/17/05 --- 2.64 ---
(°C)08/04/05 --- 26.70 ---
01/26/06 --- 8.87 ---
07/21/06 --- 29.69 ---
01/23/07 --- 7.76 ---
07/23/07 --- 28.19 ---
01/10/08 --- 12.40 ---
07/21/08 --- 34.28 ---
01/29/09 --- 9.33 ---
07/30/09 --- 31.69 ---
01/14/10 --- 7.25 ---
07/15/10 --- 29.77 ---
01/20/11 --- 7.31 ---
07/14/11 --- 27.90 ---
01/30/12 --- 12.10 ---
04/19/12 --- 18.80 ---
07/25/12 --- 28.20 ---
02/04/13 --- 11.00 ---
07/08/13 --- 31.00 ---
01/21/14 --- 6.90 ---
07/21/14 --- 25.60 ---
01/29/15 FIELD 8.20 ---
07/27/15 FIELD 28.41 ---
01/26/16 FIELD 7.7 ---
07/26/16 FIELD 32.7 ---
02/01/17 FIELD 17.7 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 36 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Turbidity 03/17/05 --- 56.7 ---
(NTU)08/04/05 --- ------
01/26/06 --- 302 ---
07/21/06 --- 6.70 ---
01/23/07 --- 203 ---
07/23/07 --- 60.9 ---
01/10/08 --- 403 ---
07/21/08 --- 164 ---
07/30/09 --- 670 ---
01/14/10 --- ------
07/15/10 --- ------
07/14/11 --- ------
01/30/12 --- 9.04 ---
04/19/12 --- 38.6 ---
07/25/12 --- 462 ---
02/04/13 --- 1000 ---
07/08/13 --- >1000 ---
01/21/14 --- >1000 ---
07/21/14 --- >1000 ---
01/29/15 FIELD >1000 ---
07/27/15 FIELD >1000 ---
01/26/16 FIELD >1000 ---
07/26/16 FIELD >1000 ---
02/01/17 FIELD 500 ---
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 37 of 38
Joyce Engineering
TABLE 9
Historical Leachate Constituents/Analytes
Upper Piedmont Regional Landfill, Permit No. 73-04
Person County, North Carolina
Analyte
Sample Collection
Date SWSL Leachate Blanks
Dissolved Oxygen 01/29/15 FIELD 5.73 ---
07/27/15 FIELD 0.54 ---
01/26/16 FIELD 2.44 ---
07/26/16 FIELD 0.47 ---
02/01/17 FIELD 3.60 ---
Oxidation Reduction Potential 01/29/15 FIELD 61.2 ---
07/27/15 FIELD -100.1 ---
01/26/16 FIELD 73.4 ---
07/26/16 FIELD -108.2 ---
02/01/17 FIELD 8.26 ---
Notes:
DL = Method Detection Limit.
RL = Reporting Limit = PQL prior to 2007 and SWSL starting January 2007.
PQL = Practical Quantitation Limit.
SWSL = NC-DENR Solid Waste Section Limit.
NC 2L = Groundwater Standard established in 15 A NCAC 2L.0202
GWPS = NC DENR Solid Waste Section Groundwater Protection Standard for constituents with no listed NC 2L.
ND = Not detected above the DL.
J = Estimated concentration below the RL.
B = Blank qualified data.
dry = insufficient water to sample.
--- = No data.
All inorganic and organic compounds are reported in µg/L
Prior to 2012 all "Additional Parameters" were reported in mg/L; beginning with the 1/21/12 event they are reported in µg/L.
µg/L = micrograms per liter
S.U. = Standard Units.
NTU = Nephelometric Turbidity Units.
µS/cm= microsiemens per centimeter.
mV = Millivolts.
Bold = Concentrations above the NC 2L or Groundwater Protection standards (GWPS) have been bolded.
Blanks = field, trip and/or method blanks.
All data prior to 2012 taken from previous reports by Golder Associates NC, Inc.
R = Anomalous data.
*8260B analysis diluted by a factor of 10x for the July 2011 event.
*6020A analysis for Antimony and Thallium diluted by a factor of 10x for the July 2011 event.
*Acetone & MEK DF 50x; C.O.D. DF 10x for the January 2012 event.
Phosphorous, total DF 1.11x for Jan. & July 2012 events.
The 1/29/15 samples for BOD, nitrate, & nitrite arrived at the lab. out of hold, so they were resampled on 2/25/15.
Upper Piedmont Regional Landfill
Permit No. 73-04 Page 38 of 38
Joyce Engineering

Appendix B

Field Sampling Logs

Appendix C

Laboratory Analytical Report
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: Upper Piedmont Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:(none)Prepared For:Attention:March 13, 2017Report Number:AAB0083Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received7304-GW1RAAB0083-0102/01/17 09:16 02/02/17 09:15Ground Water7304-GW2AAB0083-0202/01/17 10:2502/02/17 09:15Ground Water7304-GW3AAB0083-0302/01/17 10:5002/02/17 09:15Ground Water7304-GW4AAB0083-0402/01/17 11:2302/02/17 09:15Ground Water7304-GW5AAB0083-0502/01/17 11:5102/02/17 09:15Ground Water7304-GW6AAB0083-0602/01/17 09:4202/02/17 09:15Ground Water7304-GW7AAB0083-0702/01/17 12:2002/02/17 09:15Ground Water7304-GW8AAB0083-0802/01/17 12:5502/02/17 09:15Ground Water7304-GW9AAB0083-0902/01/17 13:2802/02/17 09:15Ground Water7304-GW10AAB0083-1002/01/17 14:0202/02/17 09:15Ground Water7304-SW1AAB0083-1102/01/17 14:2002/02/17 09:15Surface Water7304-SW2AAB0083-1202/01/17 10:5002/02/17 09:15Surface Water7304-LeachateAAB0083-1302/01/17 14:5002/02/17 09:15Water7304-Field BlankAAB0083-1402/01/17 15:1502/02/17 09:15Water7304-Trip BlankAAB0083-1502/01/17 07:0002/02/17 09:15WaterPage 2 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017Upper Piedmont Regional Landfill Report AAB0083 3/13/2017Report revised per consultant request to perform confirmation rerun on sample AAB0083-05 (GW-5) arsenic.Case NarrativePage 3 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW1RGround WaterAAB0083-01AAB008302/01/17 09:16Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Arsenic10.07020149EPA 3005A0.757440-38-202/10/17 01:4702/07/17 16:50EPA 6020B9.73ug/L1Barium100J7020149EPA 3005A0.307440-39-302/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 01:4702/07/17 16:50EPA 6020B2.16ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Cobalt10.07020149EPA 3005A0.297440-48-402/10/17 01:4702/07/17 16:50EPA 6020B2.13ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Lead10.07020149EPA 3005A0.087439-92-102/10/17 01:4702/07/17 16:50EPA 6020B4.39ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Selenium10.07020149EPA 3005A0.857782-49-202/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Silver10.07020149EPA 3005A0.227440-22-402/10/17 01:4702/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 01:4702/07/17 16:50EPA 6020B2.68ug/L1Vanadium25.0J7020149EPA 3005A1.577440-62-202/10/17 01:4702/07/17 16:50EPA 6020B4.19ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 01:4702/07/17 16:50EPA 6020B51.7ug/L1Iron300J7020149EPA 3005A5.727439-89-602/10/17 01:4702/07/17 16:50EPA 6020B9.49ug/L1Manganese50.0J7020149EPA 3005A1.047439-96-502/10/17 01:4702/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 12:5402/03/17 11:00Page 4 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW1RGround WaterAAB0083-01AAB008302/01/17 09:16Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 12:5402/03/17 11:00Page 5 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW1RGround WaterAAB0083-01AAB008302/01/17 09:16Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 12:5402/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 12:5402/03/17 11:00Page 6 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW1RGround WaterAAB0083-01AAB008302/01/17 09:16Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 12:5402/03/17 11:00EPA 8260B93 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 12:5402/03/17 11:0080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 12:5402/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 12:5402/03/17 11:0080-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 12:5402/03/17 11:0080-120Page 7 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW2Ground WaterAAB0083-02AAB008302/01/17 10:25Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 01:5302/07/17 16:50EPA 6020B1.21ug/L1Arsenic10.0J7020149EPA 3005A0.757440-38-202/10/17 01:5302/07/17 16:50EPA 6020B59.6ug/L1Barium100J7020149EPA 3005A0.307440-39-302/10/17 01:5302/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/10/17 01:5302/07/17 16:50EPA 6020B0.30ug/L1Cadmium1.00J7020149EPA 3005A0.107440-43-902/10/17 01:5302/07/17 16:50EPA 6020B0.54ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 01:5302/07/17 16:50EPA 6020B5.20ug/L1Cobalt10.0J7020149EPA 3005A0.297440-48-402/10/17 01:5302/07/17 16:50EPA 6020B29.2ug/L1Copper10.07020149EPA 3005A0.417440-50-802/10/17 01:5302/07/17 16:50EPA 6020B2.20ug/L1Lead10.0J7020149EPA 3005A0.087439-92-102/10/17 01:5302/07/17 16:50EPA 6020B3.10ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 01:5302/07/17 16:50NDEPA 6020Bug/L1Selenium10.07020149EPA 3005A0.857782-49-202/10/17 01:5302/07/17 16:50EPA 6020B2.69ug/L1Silver10.0J7020149EPA 3005A0.227440-22-402/10/17 01:5302/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 01:5302/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 01:5302/07/17 16:50EPA 6020B24.8ug/L1Zinc10.0B-017020149EPA 3005A1.307440-66-602/10/17 01:5302/07/17 16:50EPA 6020B346ug/L1Iron3007020149EPA 3005A5.727439-89-602/10/17 01:5302/07/17 16:50EPA 6020B623ug/L1Manganese50.07020149EPA 3005A1.047439-96-502/10/17 01:5302/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 13:2102/03/17 11:00Page 8 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW2Ground WaterAAB0083-02AAB008302/01/17 10:25Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 13:2102/03/17 11:00Page 9 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW2Ground WaterAAB0083-02AAB008302/01/17 10:25Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 13:2102/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 13:2102/03/17 11:00Page 10 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW2Ground WaterAAB0083-02AAB008302/01/17 10:25Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 13:2102/03/17 11:00EPA 8260B97 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 13:2102/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 13:2102/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 13:2102/03/17 11:0080-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 13:2102/03/17 11:0080-120Page 11 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW3Ground WaterAAB0083-03AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 01:5802/07/17 16:50EPA 6020B2.37ug/L1Arsenic10.0J7020149EPA 3005A0.757440-38-202/10/17 01:5802/07/17 16:50EPA 6020B522ug/L1Barium1007020149EPA 3005A0.307440-39-302/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Chromium10.07020149EPA 3005A0.437440-47-302/10/17 01:5802/07/17 16:50EPA 6020B6.70ug/L1Cobalt10.0J7020149EPA 3005A0.297440-48-402/10/17 01:5802/07/17 16:50EPA 6020B6.57ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Lead10.07020149EPA 3005A0.087439-92-102/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Nickel50.07020149EPA 3005A0.487440-02-002/10/17 01:5802/07/17 16:50EPA 6020B1.06ug/L1Selenium10.0J7020149EPA 3005A0.857782-49-202/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Silver10.07020149EPA 3005A0.227440-22-402/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 01:5802/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 01:5802/07/17 16:50EPA 6020B2.34ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 01:5802/07/17 16:50EPA 6020B614ug/L1Iron3007020149EPA 3005A5.727439-89-602/10/17 01:5802/07/17 16:50EPA 6020B269ug/L1Manganese50.07020149EPA 3005A1.047439-96-502/10/17 01:5802/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 13:4902/03/17 11:00Page 12 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW3Ground WaterAAB0083-03AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 13:4902/03/17 11:00Page 13 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW3Ground WaterAAB0083-03AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 13:4902/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 13:4902/03/17 11:00Page 14 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW3Ground WaterAAB0083-03AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 13:4902/03/17 11:00EPA 8260B93 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 13:4902/03/17 11:0080-120EPA 8260B100 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 13:4902/03/17 11:0078-120EPA 8260B99 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 13:4902/03/17 11:0080-120EPA 8260B98 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 13:4902/03/17 11:0080-120Page 15 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW4Ground WaterAAB0083-04AAB008302/01/17 11:23Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 02:0402/07/17 16:50EPA 6020B2.16ug/L1Arsenic10.0J7020149EPA 3005A0.757440-38-202/10/17 02:0402/07/17 16:50EPA 6020B552ug/L1Barium1007020149EPA 3005A0.307440-39-302/10/17 02:0402/07/17 16:50EPA 6020B0.10ug/L1Beryllium1.00J7020149EPA 3005A0.097440-41-702/10/17 02:0402/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 02:0402/07/17 16:50EPA 6020B1.34ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 02:0402/07/17 16:50NDEPA 6020Bug/L1Cobalt10.07020149EPA 3005A0.297440-48-402/10/17 02:0402/07/17 16:50EPA 6020B4.47ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 02:0402/07/17 16:50EPA 6020B1.83ug/L1Lead10.0J7020149EPA 3005A0.087439-92-102/10/17 02:0402/07/17 16:50EPA 6020B1.32ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 02:0402/07/17 16:50EPA 6020B1.10ug/L1Selenium10.0J7020149EPA 3005A0.857782-49-202/10/17 02:0402/07/17 16:50EPA 6020B0.33ug/L1Silver10.0J7020149EPA 3005A0.227440-22-402/10/17 02:0402/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 02:0402/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 02:0402/07/17 16:50EPA 6020B3.93ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 02:0402/07/17 16:50EPA 6020B536ug/L1Iron3007020149EPA 3005A5.727439-89-602/10/17 02:0402/07/17 16:50EPA 6020B42.3ug/L1Manganese50.0J7020149EPA 3005A1.047439-96-502/10/17 02:0402/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 14:1602/03/17 11:00Page 16 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW4Ground WaterAAB0083-04AAB008302/01/17 11:23Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 14:1602/03/17 11:00Page 17 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW4Ground WaterAAB0083-04AAB008302/01/17 11:23Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 14:1602/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 14:1602/03/17 11:00Page 18 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW4Ground WaterAAB0083-04AAB008302/01/17 11:23Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 14:1602/03/17 11:00EPA 8260B94 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 14:1602/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 14:1602/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 14:1602/03/17 11:0080-120EPA 8260B99 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 14:1602/03/17 11:0080-120Page 19 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5Ground WaterAAB0083-05AAB008302/01/17 11:51Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 02:2102/07/17 16:50EPA 6020B10.5ug/L1Arsenic10.07030170EPA 3005A0.757440-38-203/07/17 20:2603/07/17 12:25EPA 6020B10.7ug/L1Arsenic10.07020149EPA 3005A0.757440-38-202/10/17 02:2102/07/17 16:50EPA 6020B681ug/L1Barium1007020149EPA 3005A0.307440-39-302/10/17 02:2102/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/15/17 15:4002/07/17 16:50EPA 6020B0.19ug/L1Cadmium1.00J7020149EPA 3005A0.107440-43-902/10/17 02:2102/07/17 16:50EPA 6020B3.10ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 02:2102/07/17 16:50EPA 6020B4.94ug/L1Cobalt10.0J7020149EPA 3005A0.297440-48-402/10/17 02:2102/07/17 16:50EPA 6020B2.27ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 02:2102/07/17 16:50EPA 6020B0.53ug/L1Lead10.0J7020149EPA 3005A0.087439-92-102/10/17 02:2102/07/17 16:50EPA 6020B5.03ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 02:2102/07/17 16:50NDEPA 6020Bug/L1Selenium10.07020149EPA 3005A0.857782-49-202/10/17 02:2102/07/17 16:50EPA 6020B6.69ug/L1Silver10.0J7020149EPA 3005A0.227440-22-402/10/17 02:2102/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 02:2102/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 02:2102/07/17 16:50EPA 6020B6.52ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 02:2102/07/17 16:50EPA 6020B7570ug/L1Iron3007020149EPA 3005A5.727439-89-602/10/17 02:2102/07/17 16:50EPA 6020B9200ug/L1Manganese50.07020149EPA 3005A1.047439-96-502/10/17 02:2102/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 15:3902/03/17 11:00Page 20 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5Ground WaterAAB0083-05AAB008302/01/17 11:51Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 15:3902/03/17 11:00Page 21 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5Ground WaterAAB0083-05AAB008302/01/17 11:51Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 15:3902/03/17 11:00Page 22 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5Ground WaterAAB0083-05AAB008302/01/17 11:51Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 15:3902/03/17 11:00NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 15:3902/03/17 11:00EPA 8260B92 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 15:3902/03/17 11:0080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 15:3902/03/17 11:0078-120EPA 8260B98 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 15:3902/03/17 11:0080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 15:3902/03/17 11:0080-120Page 23 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW6Ground WaterAAB0083-06AAB008302/01/17 09:42Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalEPA 6020B0.27ug/L1Antimony6.00J7020149EPA 3005A0.257440-36-002/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Arsenic10.07020149EPA 3005A0.757440-38-202/10/17 02:2702/07/17 16:50EPA 6020B20.0ug/L1Barium100J7020149EPA 3005A0.307440-39-302/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/15/17 15:4602/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 02:2702/07/17 16:50EPA 6020B7.17ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 02:2702/07/17 16:50EPA 6020B0.41ug/L1Cobalt10.0J7020149EPA 3005A0.297440-48-402/10/17 02:2702/07/17 16:50EPA 6020B5.95ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 02:2702/07/17 16:50EPA 6020B0.32ug/L1Lead10.0J7020149EPA 3005A0.087439-92-102/10/17 02:2702/07/17 16:50EPA 6020B27.5ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Selenium10.07020149EPA 3005A0.857782-49-202/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Silver10.07020149EPA 3005A0.227440-22-402/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 02:2702/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 02:2702/07/17 16:50EPA 6020B8.59ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 02:2702/07/17 16:50EPA 6020B175ug/L1Iron300J7020149EPA 3005A5.727439-89-602/10/17 02:2702/07/17 16:50EPA 6020B26.5ug/L1Manganese50.0J7020149EPA 3005A1.047439-96-502/10/17 02:2702/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 16:0602/03/17 11:00Page 24 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW6Ground WaterAAB0083-06AAB008302/01/17 09:42Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 16:0602/03/17 11:00Page 25 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW6Ground WaterAAB0083-06AAB008302/01/17 09:42Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 16:0602/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 16:0602/03/17 11:00Page 26 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW6Ground WaterAAB0083-06AAB008302/01/17 09:42Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 16:0602/03/17 11:00EPA 8260B92 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 16:0602/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 16:0602/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 16:0602/03/17 11:0080-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 16:0602/03/17 11:0080-120Page 27 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW7Ground WaterAAB0083-07AAB008302/01/17 12:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 02:3302/07/17 16:50EPA 6020B5.25ug/L1Arsenic10.0J7020149EPA 3005A0.757440-38-202/10/17 02:3302/07/17 16:50EPA 6020B193ug/L1Barium1007020149EPA 3005A0.307440-39-302/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/15/17 15:5102/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 02:3302/07/17 16:50EPA 6020B1.12ug/L1Chromium10.0J7020149EPA 3005A0.437440-47-302/10/17 02:3302/07/17 16:50EPA 6020B4.18ug/L1Cobalt10.0J7020149EPA 3005A0.297440-48-402/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Copper10.07020149EPA 3005A0.417440-50-802/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Lead10.07020149EPA 3005A0.087439-92-102/10/17 02:3302/07/17 16:50EPA 6020B1.12ug/L1Nickel50.0J7020149EPA 3005A0.487440-02-002/10/17 02:3302/07/17 16:50EPA 6020B0.90ug/L1Selenium10.0J7020149EPA 3005A0.857782-49-202/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Silver10.07020149EPA 3005A0.227440-22-402/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 02:3302/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 02:3302/07/17 16:50EPA 6020B2.37ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 02:3302/07/17 16:50EPA 6020B90900ug/L20Iron60007020149EPA 3005A1147439-89-602/15/17 16:0302/07/17 16:50EPA 6020B7940ug/L1Manganese50.07020149EPA 3005A1.047439-96-502/10/17 02:3302/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 16:3402/03/17 11:00Page 28 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW7Ground WaterAAB0083-07AAB008302/01/17 12:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 16:3402/03/17 11:00Page 29 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW7Ground WaterAAB0083-07AAB008302/01/17 12:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 16:3402/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 16:3402/03/17 11:00Page 30 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW7Ground WaterAAB0083-07AAB008302/01/17 12:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 16:3402/03/17 11:00EPA 8260B94 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 16:3402/03/17 11:0080-120EPA 8260B104 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 16:3402/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 16:3402/03/17 11:0080-120EPA 8260B99 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 16:3402/03/17 11:0080-120Page 31 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW8Ground WaterAAB0083-08AAB008302/01/17 12:55Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020258EPA 3005A0.257440-36-002/16/17 16:3002/10/17 09:05NDEPA 6020Bug/L1Arsenic10.07020258EPA 3005A0.757440-38-202/16/17 16:3002/10/17 09:05EPA 6020B215ug/L1Barium1007020258EPA 3005A0.307440-39-302/16/17 16:3002/10/17 09:05EPA 6020B0.16ug/L1Beryllium1.00J7020258EPA 3005A0.097440-41-702/16/17 16:3002/10/17 09:05NDEPA 6020Bug/L1Cadmium1.007020258EPA 3005A0.107440-43-902/16/17 16:3002/10/17 09:05EPA 6020B1.29ug/L1Chromium10.0J7020258EPA 3005A0.437440-47-302/16/17 16:3002/10/17 09:05EPA 6020B13.5ug/L1Cobalt10.07020258EPA 3005A0.297440-48-402/16/17 16:3002/10/17 09:05EPA 6020B2.21ug/L1Copper10.0J7020258EPA 3005A0.417440-50-802/16/17 16:3002/10/17 09:05EPA 6020B0.56ug/L1Lead10.0B-01, J7020258EPA 3005A0.087439-92-102/16/17 16:3002/10/17 09:05EPA 6020B5.87ug/L1Nickel50.0J7020258EPA 3005A0.487440-02-002/16/17 16:3002/10/17 09:05NDEPA 6020Bug/L1Selenium10.07020258EPA 3005A0.857782-49-202/16/17 16:3002/10/17 09:05NDEPA 6020Bug/L1Silver10.07020258EPA 3005A0.227440-22-402/16/17 16:3002/10/17 09:05EPA 6020B0.07ug/L1Thallium5.50J7020258EPA 3005A0.067440-28-002/16/17 16:3002/10/17 09:05NDEPA 6020Bug/L1Vanadium25.07020258EPA 3005A1.577440-62-202/16/17 16:3002/10/17 09:05EPA 6020B10.9ug/L1Zinc10.07020258EPA 3005A1.307440-66-602/16/17 16:3002/10/17 09:05EPA 6020B316ug/L1Iron300B-017020258EPA 3005A5.727439-89-602/16/17 16:3002/10/17 09:05EPA 6020B446ug/L1Manganese50.07020258EPA 3005A1.047439-96-502/16/17 16:3002/10/17 09:05Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 17:0102/03/17 11:00Page 32 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW8Ground WaterAAB0083-08AAB008302/01/17 12:55Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 17:0102/03/17 11:00Page 33 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW8Ground WaterAAB0083-08AAB008302/01/17 12:55Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 17:0102/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 17:0102/03/17 11:00Page 34 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW8Ground WaterAAB0083-08AAB008302/01/17 12:55Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 17:0102/03/17 11:00EPA 8260B92 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 17:0102/03/17 11:0080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 17:0102/03/17 11:0078-120EPA 8260B99 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 17:0102/03/17 11:0080-120EPA 8260B99 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 17:0102/03/17 11:0080-120Page 35 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW9Ground WaterAAB0083-09AAB008302/01/17 13:28Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020258EPA 3005A0.257440-36-002/16/17 16:3502/10/17 09:05EPA 6020B0.92ug/L1Arsenic10.0J7020258EPA 3005A0.757440-38-202/16/17 16:3502/10/17 09:05EPA 6020B115ug/L1Barium1007020258EPA 3005A0.307440-39-302/16/17 16:3502/10/17 09:05EPA 6020B0.32ug/L1Beryllium1.00J7020258EPA 3005A0.097440-41-702/16/17 16:3502/10/17 09:05EPA 6020B0.34ug/L1Cadmium1.00J7020258EPA 3005A0.107440-43-902/16/17 16:3502/10/17 09:05EPA 6020B2.58ug/L1Chromium10.0J7020258EPA 3005A0.437440-47-302/16/17 16:3502/10/17 09:05EPA 6020B3.84ug/L1Cobalt10.0J7020258EPA 3005A0.297440-48-402/16/17 16:3502/10/17 09:05EPA 6020B0.70ug/L1Copper10.0J7020258EPA 3005A0.417440-50-802/16/17 16:3502/10/17 09:05EPA 6020B1.40ug/L1Lead10.0B-01, J7020258EPA 3005A0.087439-92-102/16/17 16:3502/10/17 09:05EPA 6020B2.85ug/L1Nickel50.0J7020258EPA 3005A0.487440-02-002/16/17 16:3502/10/17 09:05NDEPA 6020Bug/L1Selenium10.07020258EPA 3005A0.857782-49-202/16/17 16:3502/10/17 09:05NDEPA 6020Bug/L1Silver10.07020258EPA 3005A0.227440-22-402/16/17 16:3502/10/17 09:05NDEPA 6020Bug/L1Thallium5.507020258EPA 3005A0.067440-28-002/16/17 16:3502/10/17 09:05EPA 6020B2.61ug/L1Vanadium25.0J7020258EPA 3005A1.577440-62-202/16/17 16:3502/10/17 09:05EPA 6020B9.02ug/L1Zinc10.0J7020258EPA 3005A1.307440-66-602/16/17 16:3502/10/17 09:05EPA 6020B2600ug/L1Iron300B-017020258EPA 3005A5.727439-89-602/16/17 16:3502/10/17 09:05EPA 6020B151ug/L1Manganese50.07020258EPA 3005A1.047439-96-502/16/17 16:3502/10/17 09:05Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 17:2902/03/17 11:00Page 36 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW9Ground WaterAAB0083-09AAB008302/01/17 13:28Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 17:2902/03/17 11:00Page 37 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW9Ground WaterAAB0083-09AAB008302/01/17 13:28Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 17:2902/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 17:2902/03/17 11:00Page 38 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW9Ground WaterAAB0083-09AAB008302/01/17 13:28Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 17:2902/03/17 11:00EPA 8260B93 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 17:2902/03/17 11:0080-120EPA 8260B104 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 17:2902/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 17:2902/03/17 11:0080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 17:2902/03/17 11:0080-120Page 39 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW10Ground WaterAAB0083-10AAB008302/01/17 14:02Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020258EPA 3005A0.257440-36-002/16/17 16:4102/10/17 09:05NDEPA 6020Bug/L1Arsenic10.07020258EPA 3005A0.757440-38-202/16/17 16:4102/10/17 09:05EPA 6020B150ug/L1Barium1007020258EPA 3005A0.307440-39-302/16/17 16:4102/10/17 09:05EPA 6020B0.34ug/L1Beryllium1.00J7020258EPA 3005A0.097440-41-702/16/17 16:4102/10/17 09:05EPA 6020B0.16ug/L1Cadmium1.00J7020258EPA 3005A0.107440-43-902/16/17 16:4102/10/17 09:05EPA 6020B0.81ug/L1Chromium10.0J7020258EPA 3005A0.437440-47-302/16/17 16:4102/10/17 09:05EPA 6020B7.89ug/L1Cobalt10.0J7020258EPA 3005A0.297440-48-402/16/17 16:4102/10/17 09:05EPA 6020B4.45ug/L1Copper10.0J7020258EPA 3005A0.417440-50-802/16/17 16:4102/10/17 09:05EPA 6020B0.13ug/L1Lead10.0B-01, J7020258EPA 3005A0.087439-92-102/16/17 16:4102/10/17 09:05EPA 6020B9.98ug/L1Nickel50.0J7020258EPA 3005A0.487440-02-002/16/17 16:4102/10/17 09:05NDEPA 6020Bug/L1Selenium10.07020258EPA 3005A0.857782-49-202/16/17 16:4102/10/17 09:05NDEPA 6020Bug/L1Silver10.07020258EPA 3005A0.227440-22-402/16/17 16:4102/10/17 09:05NDEPA 6020Bug/L1Thallium5.507020258EPA 3005A0.067440-28-002/16/17 16:4102/10/17 09:05NDEPA 6020Bug/L1Vanadium25.07020258EPA 3005A1.577440-62-202/16/17 16:4102/10/17 09:05EPA 6020B8.09ug/L1Zinc10.0J7020258EPA 3005A1.307440-66-602/16/17 16:4102/10/17 09:05EPA 6020B578ug/L1Iron300B-017020258EPA 3005A5.727439-89-602/16/17 16:4102/10/17 09:05EPA 6020B196ug/L1Manganese50.07020258EPA 3005A1.047439-96-502/16/17 16:4102/10/17 09:05Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 17:5602/03/17 11:00Page 40 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW10Ground WaterAAB0083-10AAB008302/01/17 14:02Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 17:5602/03/17 11:00Page 41 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW10Ground WaterAAB0083-10AAB008302/01/17 14:02Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 17:5602/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 17:5602/03/17 11:00Page 42 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW10Ground WaterAAB0083-10AAB008302/01/17 14:02Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 17:5602/03/17 11:00EPA 8260B91 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 17:5602/03/17 11:0080-120EPA 8260B102 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 17:5602/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 17:5602/03/17 11:0080-120EPA 8260B99 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 17:5602/03/17 11:0080-120Page 43 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW1Surface WaterAAB0083-11AAB008302/01/17 14:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020258EPA 3005A0.257440-36-002/16/17 16:4702/10/17 09:05EPA 6020B0.85ug/L1Arsenic10.0J7020258EPA 3005A0.757440-38-202/16/17 16:4702/10/17 09:05EPA 6020B35.2ug/L1Barium100J7020258EPA 3005A0.307440-39-302/16/17 16:4702/10/17 09:05NDEPA 6020Bug/L1Beryllium1.007020258EPA 3005A0.097440-41-702/16/17 16:4702/10/17 09:05NDEPA 6020Bug/L1Cadmium1.007020258EPA 3005A0.107440-43-902/16/17 16:4702/10/17 09:05EPA 6020B2.41ug/L1Chromium10.0J7020258EPA 3005A0.437440-47-302/16/17 16:4702/10/17 09:05EPA 6020B1.04ug/L1Cobalt10.0J7020258EPA 3005A0.297440-48-402/16/17 16:4702/10/17 09:05EPA 6020B1.84ug/L1Copper10.0J7020258EPA 3005A0.417440-50-802/16/17 16:4702/10/17 09:05EPA 6020B1.81ug/L1Lead10.0B-01, J7020258EPA 3005A0.087439-92-102/16/17 16:4702/10/17 09:05EPA 6020B1.17ug/L1Nickel50.0J7020258EPA 3005A0.487440-02-002/16/17 16:4702/10/17 09:05NDEPA 6020Bug/L1Selenium10.07020258EPA 3005A0.857782-49-202/16/17 16:4702/10/17 09:05NDEPA 6020Bug/L1Silver10.07020258EPA 3005A0.227440-22-402/16/17 16:4702/10/17 09:05NDEPA 6020Bug/L1Thallium5.507020258EPA 3005A0.067440-28-002/16/17 16:4702/10/17 09:05EPA 6020B4.07ug/L1Vanadium25.0J7020258EPA 3005A1.577440-62-202/16/17 16:4702/10/17 09:05EPA 6020B13.9ug/L1Zinc10.07020258EPA 3005A1.307440-66-602/16/17 16:4702/10/17 09:05EPA 6020B2300ug/L1Iron300B-017020258EPA 3005A5.727439-89-602/16/17 16:4702/10/17 09:05EPA 6020B92.5ug/L1Manganese50.07020258EPA 3005A1.047439-96-502/16/17 16:4702/10/17 09:05Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 18:2402/03/17 11:00Page 44 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW1Surface WaterAAB0083-11AAB008302/01/17 14:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 18:2402/03/17 11:00Page 45 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW1Surface WaterAAB0083-11AAB008302/01/17 14:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 18:2402/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 18:2402/03/17 11:00Page 46 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW1Surface WaterAAB0083-11AAB008302/01/17 14:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 18:2402/03/17 11:00EPA 8260B93 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 18:2402/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 18:2402/03/17 11:0078-120EPA 8260B101 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 18:2402/03/17 11:0080-120EPA 8260B100 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 18:2402/03/17 11:0080-120Page 47 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW2Surface WaterAAB0083-12AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalEPA 6020B0.58ug/L1Antimony6.00J7020258EPA 3005A0.257440-36-002/16/17 17:0402/10/17 09:05EPA 6020B0.96ug/L1Arsenic10.0J7020258EPA 3005A0.757440-38-202/16/17 17:0402/10/17 09:05EPA 6020B33.1ug/L1Barium100J7020258EPA 3005A0.307440-39-302/16/17 17:0402/10/17 09:05NDEPA 6020Bug/L1Beryllium1.007020258EPA 3005A0.097440-41-702/16/17 17:0402/10/17 09:05NDEPA 6020Bug/L1Cadmium1.007020258EPA 3005A0.107440-43-902/16/17 17:0402/10/17 09:05EPA 6020B1.45ug/L1Chromium10.0J7020258EPA 3005A0.437440-47-302/16/17 17:0402/10/17 09:05EPA 6020B0.73ug/L1Cobalt10.0J7020258EPA 3005A0.297440-48-402/16/17 17:0402/10/17 09:05EPA 6020B2.01ug/L1Copper10.0J7020258EPA 3005A0.417440-50-802/16/17 17:0402/10/17 09:05EPA 6020B1.92ug/L1Lead10.0B-01, J7020258EPA 3005A0.087439-92-102/16/17 17:0402/10/17 09:05EPA 6020B0.92ug/L1Nickel50.0J7020258EPA 3005A0.487440-02-002/16/17 17:0402/10/17 09:05NDEPA 6020Bug/L1Selenium10.07020258EPA 3005A0.857782-49-202/16/17 17:0402/10/17 09:05NDEPA 6020Bug/L1Silver10.07020258EPA 3005A0.227440-22-402/16/17 17:0402/10/17 09:05NDEPA 6020Bug/L1Thallium5.507020258EPA 3005A0.067440-28-002/16/17 17:0402/10/17 09:05EPA 6020B3.43ug/L1Vanadium25.0J7020258EPA 3005A1.577440-62-202/16/17 17:0402/10/17 09:05EPA 6020B9.21ug/L1Zinc10.0J7020258EPA 3005A1.307440-66-602/16/17 17:0402/10/17 09:05EPA 6020B1940ug/L1Iron300B-017020258EPA 3005A5.727439-89-602/16/17 17:0402/10/17 09:05EPA 6020B128ug/L1Manganese50.07020258EPA 3005A1.047439-96-502/16/17 17:0402/10/17 09:05Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 18:5102/03/17 11:00Page 48 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW2Surface WaterAAB0083-12AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 18:5102/03/17 11:00Page 49 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW2Surface WaterAAB0083-12AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 18:5102/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 18:5102/03/17 11:00Page 50 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-SW2Surface WaterAAB0083-12AAB008302/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 18:5102/03/17 11:00EPA 8260B93 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 18:5102/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 18:5102/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 18:5102/03/17 11:0080-120EPA 8260B103 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 18:5102/03/17 11:0080-120Page 51 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-LeachateWaterAAB0083-13AAB008302/01/17 14:50Project:Upper Piedmont Regional Landfill02/02/17 09:15General ChemistryEPA 350.11690000ug/L100Ammonia as N100007020404EPA 350.110000NA02/15/17 11:1402/15/17 07:45SM 5210 B138000ug/L4Biochemical Oxygen Demand510007020072SM 5210 B2.0E-1010602/08/17 07:1502/03/17 08:00SM 5220 D3010000ug/L5Chemical Oxygen Demand507020321EPA 410.450E-1011702/13/17 15:0002/11/17 15:20NDEPA 9010C/9014ug/L5Cyanide, Total100R-047020364SM 4500-CN G10057-12-502/14/17 15:3002/14/17 10:45SM 4500-P B,E14300ug/L10Phosphorus-Total2.007020144SM 4500-P B2.007723-14-002/09/17 18:4802/08/17 10:55Inorganic AnionsNDEPA 9056Aug/L1Nitrate/Nitrite as N507020062EPA 300.050E-1012802/03/17 11:0302/02/17 19:15NDEPA 9056Aug/L1Nitrate as N507020062EPA 300.05014797-55-802/03/17 11:0302/02/17 19:15NDEPA 9056Aug/L50Nitrite as N2500H-04, R-017020062EPA 300.025001594-56-502/15/17 17:0002/02/17 19:15EPA 9056A22000ug/L1Sulfate5000B-017020062EPA 300.05114808-79-802/03/17 11:0302/02/17 19:15Metals, TotalEPA 6020B47.4ug/L5Antimony30.07020258EPA 3005A1.257440-36-002/17/17 16:0302/10/17 09:05EPA 6020B108ug/L5Arsenic50.07020258EPA 3005A3.737440-38-202/17/17 16:0302/10/17 09:05EPA 6020B215ug/L5Barium1007020258EPA 3005A1.497440-39-302/17/17 16:0302/10/17 09:05NDEPA 6020Bug/L5Beryllium1.007020258EPA 3005A0.477440-41-702/17/17 16:0302/10/17 09:05NDEPA 6020Bug/L5Cadmium1.007020258EPA 3005A0.487440-43-902/17/17 16:0302/10/17 09:05EPA 6020B260ug/L5Chromium50.07020258EPA 3005A2.167440-47-302/17/17 16:0302/10/17 09:05EPA 6020B61.9ug/L5Cobalt50.07020258EPA 3005A1.447440-48-402/17/17 16:0302/10/17 09:05EPA 6020B6.17ug/L5Copper10.0J7020258EPA 3005A2.047440-50-802/17/17 16:0302/10/17 09:05Page 52 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-LeachateWaterAAB0083-13AAB008302/01/17 14:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalEPA 6020B6.01ug/L5Lead10.0B-01, J7020258EPA 3005A0.427439-92-102/17/17 16:0302/10/17 09:05EPA 6020B202ug/L5Nickel50.07020258EPA 3005A2.427440-02-002/17/17 16:0302/10/17 09:05EPA 6020B8.45ug/L5Selenium10.0J7020258EPA 3005A4.277782-49-202/17/17 16:0302/10/17 09:05NDEPA 6020Bug/L5Silver10.07020258EPA 3005A1.127440-22-402/17/17 16:0302/10/17 09:05NDEPA 6020Bug/L5Thallium5.507020258EPA 3005A0.287440-28-002/17/17 16:0302/10/17 09:05EPA 6020B107ug/L5Vanadium50.07020258EPA 3005A7.867440-62-202/17/17 16:0302/10/17 09:05EPA 6020B1150ug/L5Zinc50.07020258EPA 3005A6.527440-66-602/17/17 16:0302/10/17 09:05NDEPA 7470Aug/L1Mercury0.2007020211EPA 7470A0.1327439-97-602/09/17 15:1502/09/17 10:35Volatile Organic Compounds by EPA 8260EPA 8260B19ug/L1Acetone100J7020120EPA 5030B8.267-64-102/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Acrylonitrile2007020120EPA 5030B2.5107-13-102/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Benzene1.07020120EPA 5030B0.271-43-202/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Bromochloromethane3.07020120EPA 5030B0.574-97-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Bromodichloromethane1.07020120EPA 5030B0.475-27-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Bromoform3.07020120EPA 5030B0.675-25-202/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Bromomethane107020120EPA 5030B1.074-83-902/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Carbon Disulfide1007020120EPA 5030B0.875-15-002/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020120EPA 5030B0.456-23-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Chlorobenzene3.07020120EPA 5030B0.5108-90-702/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Chloroethane107020120EPA 5030B0.575-00-302/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Chloroform5.07020120EPA 5030B0.667-66-302/06/17 11:5402/06/17 09:00Page 53 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-LeachateWaterAAB0083-13AAB008302/01/17 14:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Chloromethane1.07020120EPA 5030B0.474-87-302/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Dibromochloromethane3.07020120EPA 5030B0.3124-48-102/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020120EPA 5030B0.696-12-802/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020120EPA 5030B0.3106-93-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Dibromomethane107020120EPA 5030B0.674-95-302/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020120EPA 5030B0.595-50-102/06/17 11:5402/06/17 09:00EPA 8260B2.9ug/L11,4-Dichlorobenzene1.07020120EPA 5030B0.6106-46-702/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020120EPA 5030B1.6110-57-602/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020120EPA 5030B0.475-34-302/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020120EPA 5030B0.7107-06-202/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020120EPA 5030B0.775-35-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020120EPA 5030B0.7156-59-202/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020120EPA 5030B0.5156-60-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2-Dichloropropane1.07020120EPA 5030B0.678-87-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020120EPA 5030B0.210061-01-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020120EPA 5030B0.310061-02-602/06/17 11:5402/06/17 09:00EPA 8260B1.2ug/L1Ethylbenzene1.07020120EPA 5030B0.4100-41-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Iodomethane107020120EPA 5030B3.174-88-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020120EPA 5030B0.9591-78-602/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Methylene Chloride1.07020120EPA 5030B0.575-09-202/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020120EPA 5030B3.278-93-302/06/17 11:5402/06/17 09:00Page 54 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-LeachateWaterAAB0083-13AAB008302/01/17 14:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260EPA 8260B21ug/L14-Methyl-2-pentanone (MIBK)100J7020120EPA 5030B0.9108-10-102/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Styrene1.07020120EPA 5030B0.5100-42-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020120EPA 5030B0.3630-20-602/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020120EPA 5030B0.579-34-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Tetrachloroethene1.07020120EPA 5030B0.8127-18-402/06/17 11:5402/06/17 09:00EPA 8260B1.3ug/L1Toluene1.07020120EPA 5030B0.3108-88-302/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020120EPA 5030B0.471-55-602/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020120EPA 5030B0.679-00-502/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Trichloroethene1.07020120EPA 5030B0.379-01-602/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020120EPA 5030B0.575-69-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020120EPA 5030B0.596-18-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Vinyl Acetate507020120EPA 5030B0.4108-05-402/06/17 11:5402/06/17 09:00NDEPA 8260Bug/L1Vinyl Chloride1.07020120EPA 5030B0.675-01-402/06/17 11:5402/06/17 09:00EPA 8260B3.9ug/L1Xylenes, total5.0J7020120EPA 5030B0.91330-20-702/06/17 11:5402/06/17 09:00EPA 8260B96 %Surr: Dibromofluoromethane7020120EPA 5030B1868-53-702/06/17 11:5402/06/17 09:0080-120EPA 8260B116 %Surr: 1,2-Dichloroethane-d47020120EPA 5030B17060-07-002/06/17 11:5402/06/17 09:0078-120EPA 8260B97 %Surr: Toluene-d87020120EPA 5030B2037-26-502/06/17 11:5402/06/17 09:0080-120EPA 8260B105 %Surr: 4-Bromofluorobenzene7020120EPA 5030B460-00-402/06/17 11:5402/06/17 09:0080-120Page 55 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Field BlankWaterAAB0083-14AAB008302/01/17 15:15Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, TotalNDEPA 6020Bug/L1Antimony6.007020149EPA 3005A0.257440-36-002/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Arsenic10.07020149EPA 3005A0.757440-38-202/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Barium1007020149EPA 3005A0.307440-39-302/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Beryllium1.007020149EPA 3005A0.097440-41-702/15/17 15:5702/07/17 16:50NDEPA 6020Bug/L1Cadmium1.007020149EPA 3005A0.107440-43-902/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Chromium10.07020149EPA 3005A0.437440-47-302/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Cobalt10.07020149EPA 3005A0.297440-48-402/10/17 02:3902/07/17 16:50EPA 6020B1.04ug/L1Copper10.0J7020149EPA 3005A0.417440-50-802/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Lead10.07020149EPA 3005A0.087439-92-102/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Nickel50.07020149EPA 3005A0.487440-02-002/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Selenium10.07020149EPA 3005A0.857782-49-202/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Silver10.07020149EPA 3005A0.227440-22-402/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Thallium5.507020149EPA 3005A0.067440-28-002/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Vanadium25.07020149EPA 3005A1.577440-62-202/10/17 02:3902/07/17 16:50EPA 6020B1.54ug/L1Zinc10.0B-01, J7020149EPA 3005A1.307440-66-602/10/17 02:3902/07/17 16:50EPA 6020B12.2ug/L1Iron300J7020149EPA 3005A5.727439-89-602/10/17 02:3902/07/17 16:50NDEPA 6020Bug/L1Manganese50.07020149EPA 3005A1.047439-96-502/10/17 02:3902/07/17 16:50Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 19:1902/03/17 11:00Page 56 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Field BlankWaterAAB0083-14AAB008302/01/17 15:15Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 19:1902/03/17 11:00Page 57 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Field BlankWaterAAB0083-14AAB008302/01/17 15:15Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 19:1902/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 19:1902/03/17 11:00Page 58 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Field BlankWaterAAB0083-14AAB008302/01/17 15:15Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 19:1902/03/17 11:00EPA 8260B92 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 19:1902/03/17 11:0080-120EPA 8260B103 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 19:1902/03/17 11:0078-120EPA 8260B99 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 19:1902/03/17 11:0080-120EPA 8260B99 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 19:1902/03/17 11:0080-120Page 59 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Trip BlankWaterAAB0083-15AAB008302/01/17 07:00Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L1Acetone1007020116EPA 5030B8.267-64-102/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Acrylonitrile2007020116EPA 5030B2.5107-13-102/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Benzene1.07020116EPA 5030B0.271-43-202/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Bromochloromethane3.07020116EPA 5030B0.574-97-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Bromodichloromethane1.07020116EPA 5030B0.475-27-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Bromoform3.07020116EPA 5030B0.675-25-202/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Bromomethane107020116EPA 5030B1.074-83-902/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Carbon Disulfide1007020116EPA 5030B0.875-15-002/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Carbon Tetrachloride1.07020116EPA 5030B0.456-23-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Chlorobenzene3.07020116EPA 5030B0.5108-90-702/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Chloroethane107020116EPA 5030B0.575-00-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Chloroform5.07020116EPA 5030B0.667-66-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Chloromethane1.07020116EPA 5030B0.474-87-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Dibromochloromethane3.07020116EPA 5030B0.3124-48-102/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromo-3-chloropropane137020116EPA 5030B0.696-12-802/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,2-Dibromoethane1.07020116EPA 5030B0.3106-93-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Dibromomethane107020116EPA 5030B0.674-95-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,2-Dichlorobenzene5.07020116EPA 5030B0.595-50-102/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,4-Dichlorobenzene1.07020116EPA 5030B0.6106-46-702/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1trans-1,4-Dichloro-2-butene1007020116EPA 5030B1.6110-57-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,1-Dichloroethane5.07020116EPA 5030B0.475-34-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,2-Dichloroethane1.07020116EPA 5030B0.7107-06-202/03/17 19:4602/03/17 11:00Page 60 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Trip BlankWaterAAB0083-15AAB008302/01/17 07:00Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,1-Dichloroethene5.07020116EPA 5030B0.775-35-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1cis-1,2-Dichloroethene5.07020116EPA 5030B0.7156-59-202/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1trans-1,2-Dichloroethene5.07020116EPA 5030B0.5156-60-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,2-Dichloropropane1.07020116EPA 5030B0.678-87-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1cis-1,3-Dichloropropene1.07020116EPA 5030B0.210061-01-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1trans-1,3-Dichloropropene1.07020116EPA 5030B0.310061-02-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Ethylbenzene1.07020116EPA 5030B0.4100-41-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Iodomethane107020116EPA 5030B3.174-88-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Methyl Butyl Ketone (2-Hexanone)507020116EPA 5030B0.9591-78-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Methylene Chloride1.07020116EPA 5030B0.575-09-202/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Methyl Ethyl Ketone (2-Butanone)1007020116EPA 5030B3.278-93-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L14-Methyl-2-pentanone (MIBK)1007020116EPA 5030B0.9108-10-102/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Styrene1.07020116EPA 5030B0.5100-42-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,1,1,2-Tetrachloroethane5.07020116EPA 5030B0.3630-20-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,1,2,2-Tetrachloroethane3.07020116EPA 5030B0.579-34-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Tetrachloroethene1.07020116EPA 5030B0.8127-18-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Toluene1.07020116EPA 5030B0.3108-88-302/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,1,1-Trichloroethane1.07020116EPA 5030B0.471-55-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L11,1,2-Trichloroethane1.07020116EPA 5030B0.679-00-502/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Trichloroethene1.07020116EPA 5030B0.379-01-602/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Trichlorofluoromethane1.07020116EPA 5030B0.575-69-402/03/17 19:4602/03/17 11:00Page 61 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Trip BlankWaterAAB0083-15AAB008302/01/17 07:00Project:Upper Piedmont Regional Landfill02/02/17 09:15Volatile Organic Compounds by EPA 8260NDEPA 8260Bug/L11,2,3-Trichloropropane1.07020116EPA 5030B0.596-18-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Vinyl Acetate507020116EPA 5030B0.4108-05-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Vinyl Chloride1.07020116EPA 5030B0.675-01-402/03/17 19:4602/03/17 11:00NDEPA 8260Bug/L1Xylenes, total5.07020116EPA 5030B0.91330-20-702/03/17 19:4602/03/17 11:00EPA 8260B94 %Surr: Dibromofluoromethane7020116EPA 5030B1868-53-702/03/17 19:4602/03/17 11:0080-120EPA 8260B104 %Surr: 1,2-Dichloroethane-d47020116EPA 5030B17060-07-002/03/17 19:4602/03/17 11:0078-120EPA 8260B100 %Surr: Toluene-d87020116EPA 5030B2037-26-502/03/17 19:4602/03/17 11:0080-120EPA 8260B101 %Surr: 4-Bromofluorobenzene7020116EPA 5030B460-00-402/03/17 19:4602/03/17 11:0080-120Page 62 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7020072 - SM 5210 BBlank (7020072-BLK1)Prepared: 02/03/17 Analyzed: 02/08/17 Biochemical Oxygen Demandug/LND2000B-BODLCS (7020072-BS1)Prepared: 02/03/17 Analyzed: 02/08/17 Biochemical Oxygen Demandug/L195000200019800085-11598Duplicate (7020072-DUP1)Prepared: 02/03/17 Analyzed: 02/08/17 Source: AAB0122-01Biochemical Oxygen Demandug/L19400020002370002020Batch 7020144 - SM 4500-P BBlank (7020144-BLK1)Prepared: 02/08/17 Analyzed: 02/09/17 Phosphorus-Totalug/LND20.0LCS (7020144-BS1)Prepared: 02/08/17 Analyzed: 02/09/17 Phosphorus-Totalug/L47020.0500.0088-11094Matrix Spike (7020144-MS1)Prepared: 02/08/17 Analyzed: 02/09/17 Source: AAB0043-26Phosphorus-Totalug/L58120.0500.0027.072-123111Matrix Spike Dup (7020144-MSD1)Prepared: 02/08/17 Analyzed: 02/09/17 Source: AAB0043-26Phosphorus-Totalug/L57720.0500.0027.01172-1231100.7Batch 7020321 - EPA 410.4Blank (7020321-BLK1)Prepared: 02/11/17 Analyzed: 02/13/17 Chemical Oxygen Demandug/LND10000Page 63 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7020321 - EPA 410.4LCS (7020321-BS1)Prepared: 02/11/17 Analyzed: 02/13/17 Chemical Oxygen Demandug/L1840001000020000090-11092Matrix Spike (7020321-MS1)Prepared: 02/11/17 Analyzed: 02/13/17 Source: AAB0114-25Chemical Oxygen Demandug/L20700010000200000ND90-110103Matrix Spike (7020321-MS2)Prepared: 02/11/17 Analyzed: 02/13/17 Source: AAB0179-01Chemical Oxygen Demandug/L287000100002000007040090-110108Matrix Spike Dup (7020321-MSD1)Prepared: 02/11/17 Analyzed: 02/13/17 Source: AAB0114-25Chemical Oxygen Demandug/L20400010000200000ND1090-1101021Batch 7020364 - SM 4500-CN GBlank (7020364-BLK1)Prepared & Analyzed: 02/14/17 Cyanide, Totalug/LND20.0LCS (7020364-BS1)Prepared & Analyzed: 02/14/17 Cyanide, Totalug/L84.020.080.00085-115105Matrix Spike (7020364-MS1)Prepared & Analyzed: 02/14/17 Source: AAB0470-03Cyanide, Totalug/L86.020.080.000ND85-119108Matrix Spike Dup (7020364-MSD1)Prepared & Analyzed: 02/14/17 Source: AAB0470-03Cyanide, Totalug/L85.020.080.000ND1385-1191061Batch 7020404 - EPA 350.1Blank (7020404-BLK1)Prepared & Analyzed: 02/15/17 Ammonia as Nug/LND100Page 64 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteGeneral Chemistry - Quality ControlBatch 7020404 - EPA 350.1LCS (7020404-BS1)Prepared & Analyzed: 02/15/17 Ammonia as Nug/L95301001000090-11095Matrix Spike (7020404-MS1)Prepared & Analyzed: 02/15/17 Source: AAB0444-05Ammonia as Nug/L854010010000NDQM-0590-11085Matrix Spike (7020404-MS2)Prepared & Analyzed: 02/15/17 Source: AAB0378-01Ammonia as Nug/L950010010000ND90-11095Page 65 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteInorganic Anions - Quality ControlBatch 7020062 - EPA 300.0Blank (7020062-BLK1)Prepared: 02/02/17 Analyzed: 02/03/17 Nitrate/Nitrite as Nug/LND50Nitrate as Nug/LND50Nitrite as Nug/LND50Sulfateug/L53.05000JLCS (7020062-BS1)Prepared: 02/02/17 Analyzed: 02/03/17 Nitrate/Nitrite as Nug/L21900502000090-110109Nitrate as Nug/L10800501002090-110108Nitrite as Nug/L11000501000090-110110Sulfateug/L1100050001002090-110109Matrix Spike (7020062-MS1)Prepared: 02/02/17 Analyzed: 02/03/17 Source: AAB0116-05Nitrate/Nitrite as Nug/L3460050200001400090-110103Nitrate as Nug/L237005010020NDQM-0590-110237Nitrite as Nug/L109005010000ND90-110109Sulfateug/L11900500010020650QM-0590-110112Matrix Spike (7020062-MS2)Prepared: 02/02/17 Analyzed: 02/03/17 Source: AAB0116-11Nitrate/Nitrite as Nug/L21300502000010190-110106Nitrate as Nug/L10600501002010190-110105Nitrite as Nug/L107005010000ND90-110107Sulfateug/L124005000100201210QM-0590-110112Matrix Spike Dup (7020062-MSD1)Prepared: 02/02/17 Analyzed: 02/03/17 Source: AAB0116-05Nitrate/Nitrite as Nug/L349005020000140001590-1101050.9Nitrate as Nug/L238005010020ND15QM-0590-1102370.1Nitrite as Nug/L111005010000ND15QM-0590-1101112Sulfateug/L1280050001002065015QM-0590-1101228Page 66 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020149 - EPA 3005ABlank (7020149-BLK1)Prepared: 02/07/17 Analyzed: 02/10/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Ironug/LND300Leadug/LND10.0Manganeseug/LND50.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/L2.3510.0JLCS (7020149-BS1)Prepared: 02/07/17 Analyzed: 02/10/17 Antimonyug/L1086.00100.0080-120108Arsenicug/L10110.0100.0080-120101Bariumug/L104100100.0080-120104Berylliumug/L1061.00100.0080-120106Cadmiumug/L1061.00100.0080-120106Chromiumug/L10810.0100.0080-120108Cobaltug/L10110.0100.0080-120101Copperug/L10010.0100.0080-120100Ironug/L10203001000.080-120102Page 67 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020149 - EPA 3005ALCS (7020149-BS1)Prepared: 02/07/17 Analyzed: 02/10/17 Leadug/L10610.0100.0080-120106Manganeseug/L10550.0100.0080-120105Nickelug/L10450.0100.0080-120104Seleniumug/L10110.0100.0080-120101Silverug/L10410.0100.0080-120104Thalliumug/L1085.50100.0080-120108Vanadiumug/L10925.0100.0080-120109Zincug/L10710.0100.0080-120107Matrix Spike (7020149-MS1)Prepared: 02/07/17 Analyzed: 02/10/17 Source: AAB0083-04Antimonyug/L1006.00100.00ND75-125100Arsenicug/L10310.0100.002.1675-125101Bariumug/L645100100.0055275-12593Berylliumug/L84.91.00100.000.1075-12585Cadmiumug/L1041.00100.00ND75-125104Chromiumug/L10510.0100.001.3475-125104Cobaltug/L99.010.0100.00ND75-12599Copperug/L10310.0100.004.4775-12598Ironug/L18003001000.0536QM-0275-125126Leadug/L10310.0100.001.8375-125101Manganeseug/L14650.0100.0042.375-125104Nickelug/L10150.0100.001.3275-12599Seleniumug/L10610.0100.001.1075-125104Silverug/L97.410.0100.000.3375-12597Thalliumug/L1035.50100.00ND75-125103Vanadiumug/L10525.0100.00ND75-125105Zincug/L10210.0100.003.9375-12598Page 68 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020149 - EPA 3005AMatrix Spike Dup (7020149-MSD1)Prepared: 02/07/17 Analyzed: 02/10/17 Source: AAB0083-04Antimonyug/L1036.00100.00ND2075-1251032Arsenicug/L10610.0100.002.162075-1251043Bariumug/L669100100.005522075-1251174Berylliumug/L87.81.00100.000.102075-125883Cadmiumug/L1051.00100.00ND2075-1251052Chromiumug/L10510.0100.001.342075-1251040.1Cobaltug/L10010.0100.00ND2075-1251001Copperug/L10610.0100.004.472075-1251013Ironug/L17703001000.05362075-1251232Leadug/L10510.0100.001.832075-1251043Manganeseug/L14650.0100.0042.32075-1251040.2Nickelug/L10150.0100.001.322075-1251000.3Seleniumug/L10710.0100.001.102075-1251061Silverug/L10110.0100.000.332075-1251014Thalliumug/L1075.50100.00ND2075-1251073Vanadiumug/L10825.0100.00ND2075-1251082Zincug/L10610.0100.003.932075-1251024Post Spike (7020149-PS1)Prepared: 02/07/17 Analyzed: 02/10/17 Source: AAB0083-04Antimonyug/L107100.000.1580-120106Arsenicug/L105100.002.1680-120103Bariumug/L631100.00552QM-0280-12079Berylliumug/L85.5100.000.1080-12085Cadmiumug/L103100.000.0880-120103Chromiumug/L107100.001.3480-120106Cobaltug/L102100.000.1380-120102Copperug/L101100.004.4780-12096Ironug/L15901000.053680-120106Page 69 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020149 - EPA 3005APost Spike (7020149-PS1)Prepared: 02/07/17 Analyzed: 02/10/17 Source: AAB0083-04Leadug/L101100.001.8380-120100Manganeseug/L147100.0042.380-120104Nickelug/L101100.001.3280-12099Seleniumug/L103100.001.1080-120101Silverug/L96.6100.000.3380-12096Thalliumug/L102100.000.00980-120102Vanadiumug/L108100.00-1.0680-120108Zincug/L102100.003.9380-12098Batch 7020211 - EPA 7470ABlank (7020211-BLK1)Prepared & Analyzed: 02/09/17 Mercuryug/LND0.200LCS (7020211-BS1)Prepared & Analyzed: 02/09/17 Mercuryug/L2.420.2002.500080-12097Matrix Spike (7020211-MS1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.960.2002.5000ND75-12578Matrix Spike Dup (7020211-MSD1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.920.2002.5000ND2075-125772Post Spike (7020211-PS1)Prepared & Analyzed: 02/09/17 Source: AAB0083-13Mercuryug/L1.321.66670.037QM-0580-12077Page 70 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020258 - EPA 3005ABlank (7020258-BLK1)Prepared: 02/10/17 Analyzed: 02/16/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Ironug/L11.1300JLeadug/L0.1110.0JManganeseug/LND50.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/LND10.0LCS (7020258-BS1)Prepared: 02/10/17 Analyzed: 02/16/17 Antimonyug/L1086.00100.0080-120108Arsenicug/L10410.0100.0080-120104Bariumug/L104100100.0080-120104Berylliumug/L1101.00100.0080-120110Cadmiumug/L1041.00100.0080-120104Chromiumug/L10210.0100.0080-120102Cobaltug/L10110.0100.0080-120101Copperug/L98.610.0100.0080-12099Ironug/L10203001000.080-120102Page 71 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020258 - EPA 3005ALCS (7020258-BS1)Prepared: 02/10/17 Analyzed: 02/16/17 Leadug/L10510.0100.0080-120105Manganeseug/L10550.0100.0080-120105Nickelug/L10450.0100.0080-120104Seleniumug/L10710.0100.0080-120107Silverug/L97.910.0100.0080-12098Thalliumug/L1075.50100.0080-120107Vanadiumug/L10825.0100.0080-120108Zincug/L10410.0100.0080-120104Duplicate (7020258-DUP1)Prepared: 02/10/17 Analyzed: 02/16/17 Source: AAB0157-01Antimonyug/LND6.00ND20Arsenicug/LND10.0ND20Bariumug/L81.010079.920J1Berylliumug/LND1.00ND20Cadmiumug/LND1.00ND20Chromiumug/LND10.0ND20Cobaltug/L67.110.066.9200.3Copperug/L4.1910.04.2520J1Ironug/L35.630085.020QR-01, J82Leadug/L0.1410.00.1620J14Manganeseug/L2150050.021500200.2Nickelug/L3.7050.03.8220J3Seleniumug/L1.4010.01.1220QR-01, J23Silverug/LND10.0ND20Thalliumug/L0.705.500.6520J8Vanadiumug/LND25.0ND20Zincug/L3.1910.05.2620QR-01, J49Page 72 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020258 - EPA 3005AMatrix Spike (7020258-MS1)Prepared: 02/10/17 Analyzed: 02/16/17 Source: AAB0083-11Antimonyug/L1066.00100.00ND75-125106Arsenicug/L10310.0100.000.8575-125102Bariumug/L141100100.0035.275-125106Berylliumug/L94.71.00100.00ND75-12595Cadmiumug/L1021.00100.00ND75-125102Chromiumug/L10510.0100.002.4175-125103Cobaltug/L10510.0100.001.0475-125104Copperug/L10210.0100.001.8475-125100Ironug/L37203001000.02300QM-0275-125143Leadug/L10510.0100.001.8175-125103Manganeseug/L20550.0100.0092.575-125112Nickelug/L10450.0100.001.1775-125103Seleniumug/L10210.0100.00ND75-125102Silverug/L10010.0100.00ND75-125100Thalliumug/L1065.50100.00ND75-125106Vanadiumug/L10925.0100.004.0775-125105Zincug/L11910.0100.0013.975-125106Matrix Spike Dup (7020258-MSD1)Prepared: 02/10/17 Analyzed: 02/16/17 Source: AAB0083-11Antimonyug/L1046.00100.00ND2075-1251042Arsenicug/L10110.0100.000.852075-1251002Bariumug/L135100100.0035.22075-125995Berylliumug/L93.01.00100.00ND2075-125932Cadmiumug/L1031.00100.00ND2075-1251030.7Chromiumug/L10610.0100.002.412075-1251030.3Cobaltug/L10210.0100.001.042075-1251012Copperug/L99.710.0100.001.842075-125982Ironug/L38903001000.0230020QM-0275-1251594Page 73 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7020258 - EPA 3005AMatrix Spike Dup (7020258-MSD1)Prepared: 02/10/17 Analyzed: 02/16/17 Source: AAB0083-11Leadug/L10210.0100.001.812075-1251003Manganeseug/L20550.0100.0092.52075-1251130.02Nickelug/L10150.0100.001.172075-1251003Seleniumug/L10010.0100.00ND2075-1251001Silverug/L98.310.0100.00ND2075-125982Thalliumug/L1025.50100.00ND2075-1251024Vanadiumug/L10925.0100.004.072075-1251040.3Zincug/L11610.0100.0013.92075-1251023Post Spike (7020258-PS1)Prepared: 02/10/17 Analyzed: 02/16/17 Source: AAB0083-11Antimonyug/L101100.000.1280-120101Arsenicug/L102100.000.8580-120101Bariumug/L140100.0035.280-120104Berylliumug/L96.6100.000.0780-12097Cadmiumug/L102100.000.0380-120102Chromiumug/L108100.002.4180-120106Cobaltug/L102100.001.0480-120101Copperug/L105100.001.8480-120103Ironug/L34601000.0230080-120116Leadug/L103100.001.8180-120101Manganeseug/L208100.0092.580-120115Nickelug/L105100.001.1780-120104Seleniumug/L104100.000.5580-120104Silverug/L97.3100.000.0280-12097Thalliumug/L102100.000.0180-120102Vanadiumug/L113100.004.0780-120109Zincug/L119100.0013.980-120105Page 74 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7030170 - EPA 3005ABlank (7030170-BLK1)Prepared & Analyzed: 03/07/17 Antimonyug/LND6.00Arsenicug/LND10.0Bariumug/LND100Berylliumug/LND1.00Cadmiumug/LND1.00Chromiumug/LND10.0Cobaltug/LND10.0Copperug/LND10.0Leadug/LND10.0Nickelug/LND50.0Seleniumug/LND10.0Silverug/LND10.0Thalliumug/LND5.50Vanadiumug/LND25.0Zincug/LND10.0LCS (7030170-BS1)Prepared & Analyzed: 03/07/17 Antimonyug/L1046.00100.0080-120104Arsenicug/L10210.0100.0080-120102Bariumug/L102100100.0080-120102Berylliumug/L93.21.00100.0080-12093Cadmiumug/L1021.00100.0080-120102Chromiumug/L10410.0100.0080-120104Cobaltug/L96.010.0100.0080-12096Copperug/L97.610.0100.0080-12098Leadug/L10410.0100.0080-120104Nickelug/L99.250.0100.0080-12099Seleniumug/L10110.0100.0080-120101Page 75 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7030170 - EPA 3005ALCS (7030170-BS1)Prepared & Analyzed: 03/07/17 Silverug/L10110.0100.0080-120101Thalliumug/L1055.50100.0080-120105Vanadiumug/L10425.0100.0080-120104Zincug/L10210.0100.0080-120102Duplicate (7030170-DUP1)Prepared & Analyzed: 03/07/17 Source: AAB0083-05RE1Antimonyug/LND6.00ND20Arsenicug/L9.5710.010.520J9Bariumug/L670100657202Berylliumug/LND1.00ND20Cadmiumug/L0.151.000.2120J30Chromiumug/L1.6810.01.3220J24Cobaltug/L4.1910.03.6120J15Copperug/L2.4710.02.3420J5Leadug/L0.4910.00.4320J15Nickelug/L4.8250.04.3320J11Seleniumug/LND10.0ND20Silverug/L2.4410.02.2120J10Thalliumug/L0.105.500.0820J24Vanadiumug/L2.3625.01.9820J17Zincug/L5.2810.06.4620J20Matrix Spike (7030170-MS1)Prepared & Analyzed: 03/07/17 Source: AAB0083-05RE1Antimonyug/L1076.00100.00ND75-125107Arsenicug/L11510.0100.0010.575-125105Bariumug/L823100100.0065775-125165Berylliumug/L86.21.00100.00ND75-12586Cadmiumug/L1021.00100.000.2175-125102Page 76 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7030170 - EPA 3005AMatrix Spike (7030170-MS1)Prepared & Analyzed: 03/07/17 Source: AAB0083-05RE1Chromiumug/L11310.0100.001.3275-125112Cobaltug/L10310.0100.003.6175-12599Copperug/L99.610.0100.002.3475-12597Leadug/L10110.0100.000.4375-125101Nickelug/L10950.0100.004.3375-125105Seleniumug/L10310.0100.00ND75-125103Silverug/L10410.0100.002.2175-125102Thalliumug/L1065.50100.000.0875-125106Vanadiumug/L11325.0100.001.9875-125111Zincug/L11010.0100.006.4675-125103Matrix Spike Dup (7030170-MSD1)Prepared & Analyzed: 03/07/17 Source: AAB0083-05RE1Antimonyug/L1076.00100.00ND2075-1251070.3Arsenicug/L11210.0100.0010.52075-1251023Bariumug/L792100100.006572075-1251354Berylliumug/L87.51.00100.00ND2075-125882Cadmiumug/L99.91.00100.000.212075-1251002Chromiumug/L10610.0100.001.322075-1251057Cobaltug/L99.010.0100.003.612075-125954Copperug/L93.310.0100.002.342075-125917Leadug/L99.410.0100.000.432075-125992Nickelug/L10350.0100.004.332075-125996Seleniumug/L10210.0100.00ND2075-1251020.9Silverug/L10810.0100.002.212075-1251063Thalliumug/L1055.50100.000.082075-1251050.9Vanadiumug/L10725.0100.001.982075-1251056Zincug/L10410.0100.006.462075-125976Page 77 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7030170 - EPA 3005APost Spike (7030170-PS1)Prepared & Analyzed: 03/07/17 Source: AAB0083-05RE1Antimonyug/L103100.000.1480-120103Arsenicug/L115100.0010.580-120105Bariumug/L767100.0065780-120110Berylliumug/L86.5100.000.0480-12086Cadmiumug/L102100.000.2180-120102Chromiumug/L111100.001.3280-120110Cobaltug/L102100.003.6180-12098Copperug/L96.7100.002.3480-12094Leadug/L103100.000.4380-120103Nickelug/L107100.004.3380-120103Seleniumug/L102100.000.3880-120102Silverug/L101100.002.2180-12098Thalliumug/L105100.000.0880-120105Vanadiumug/L111100.001.9880-120109Zincug/L105100.006.4680-12098Page 78 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020116 - EPA 5030BBlank (7020116-BLK1)Prepared & Analyzed: 02/03/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0Page 79 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020116 - EPA 5030BBlank (7020116-BLK1)Prepared & Analyzed: 02/03/17 trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9447ug/L50.00078-120Surr: 1,2-Dichloroethane-d410352ug/L50.00080-120Surr: Toluene-d89950ug/L50.00080-120Surr: 4-Bromofluorobenzene9949LCS (7020116-BS1)Prepared & Analyzed: 02/03/17 Benzeneug/L5150.00067-134103Page 80 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020116 - EPA 5030BLCS (7020116-BS1)Prepared & Analyzed: 02/03/17 Chlorobenzeneug/L5150.00069-1221021,1-Dichloroetheneug/L5450.00058-142108Tolueneug/L4650.00068-12792Trichloroetheneug/L5050.00072-132101ug/L50.00080-120Surr: Dibromofluoromethane9548ug/L50.00078-120Surr: 1,2-Dichloroethane-d410251ug/L50.00080-120Surr: Toluene-d89849ug/L50.00080-120Surr: 4-Bromofluorobenzene9648Matrix Spike (7020116-MS1)Prepared & Analyzed: 02/03/17 Source: AAB0083-04Benzeneug/L5750.0000.067-134113Chlorobenzeneug/L5550.0000.069-1221101,1-Dichloroetheneug/L6550.0000.058-142130Tolueneug/L5050.0000.068-127101Trichloroetheneug/L5650.0000.072-132112ug/L50.00080-120Surr: Dibromofluoromethane9447ug/L50.00078-120Surr: 1,2-Dichloroethane-d410352ug/L50.00080-120Surr: Toluene-d89950ug/L50.00080-120Surr: 4-Bromofluorobenzene10050Matrix Spike Dup (7020116-MSD1)Prepared & Analyzed: 02/03/17 Source: AAB0083-04Benzeneug/L3750.0000.09QR-0267-1347343Chlorobenzeneug/L3650.0000.013QR-0269-12272421,1-Dichloroetheneug/L4250.0000.09QR-0258-1428443Tolueneug/L3250.0000.09QM-0668-1276444Trichloroetheneug/L3650.0000.011QM-0672-1327144Page 81 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020116 - EPA 5030BMatrix Spike Dup (7020116-MSD1)Prepared & Analyzed: 02/03/17 Source: AAB0083-04ug/L50.00080-120Surr: Dibromofluoromethane9447ug/L50.00078-120Surr: 1,2-Dichloroethane-d410552ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene9950Batch 7020120 - EPA 5030BBlank (7020120-BLK1)Prepared & Analyzed: 02/03/17 Acetoneug/LND100Acrylonitrileug/LND200Benzeneug/LND1.0Bromochloromethaneug/LND3.0Bromodichloromethaneug/LND1.0Bromoformug/LND3.0Bromomethaneug/LND10Carbon Disulfideug/LND100Carbon Tetrachlorideug/LND1.0Chlorobenzeneug/LND3.0Chloroethaneug/LND10Chloroformug/LND5.0Chloromethaneug/LND1.0Dibromochloromethaneug/LND3.01,2-Dibromo-3-chloropropaneug/LND131,2-Dibromoethaneug/LND1.0Dibromomethaneug/LND101,2-Dichlorobenzeneug/LND5.01,4-Dichlorobenzeneug/LND1.0Page 82 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020120 - EPA 5030BBlank (7020120-BLK1)Prepared & Analyzed: 02/03/17 trans-1,4-Dichloro-2-buteneug/LND1001,1-Dichloroethaneug/LND5.01,2-Dichloroethaneug/LND1.01,1-Dichloroetheneug/LND5.0cis-1,2-Dichloroetheneug/LND5.0trans-1,2-Dichloroetheneug/LND5.01,2-Dichloropropaneug/LND1.0cis-1,3-Dichloropropeneug/LND1.0trans-1,3-Dichloropropeneug/LND1.0Ethylbenzeneug/LND1.0Iodomethaneug/LND10Methyl Butyl Ketone (2-Hexanone)ug/LND50Methylene Chlorideug/LND1.0Methyl Ethyl Ketone (2-Butanone)ug/LND1004-Methyl-2-pentanone (MIBK)ug/LND100Styreneug/LND1.01,1,1,2-Tetrachloroethaneug/LND5.01,1,2,2-Tetrachloroethaneug/LND3.0Tetrachloroetheneug/LND1.0Tolueneug/LND1.01,1,1-Trichloroethaneug/LND1.01,1,2-Trichloroethaneug/LND1.0Trichloroetheneug/LND1.0Trichlorofluoromethaneug/LND1.01,2,3-Trichloropropaneug/LND1.0Vinyl Acetateug/LND50Vinyl Chlorideug/LND1.0Page 83 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020120 - EPA 5030BBlank (7020120-BLK1)Prepared & Analyzed: 02/03/17 Xylenes, totalug/LND5.0ug/L50.00080-120Surr: Dibromofluoromethane9145ug/L50.00078-120Surr: 1,2-Dichloroethane-d49748ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene10150LCS (7020120-BS1)Prepared & Analyzed: 02/03/17 Benzeneug/L491.050.00067-13499Chlorobenzeneug/L473.050.00069-122941,1-Dichloroetheneug/L515.050.00058-142102Tolueneug/L501.050.00068-127100Trichloroetheneug/L471.050.00072-13294ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d810050ug/L50.00080-120Surr: 4-Bromofluorobenzene10452Matrix Spike (7020120-MS1)Prepared & Analyzed: 02/03/17 Source: AAB0060-17Benzeneug/L531.050.000ND67-134106Chlorobenzeneug/L503.050.000ND69-1221001,1-Dichloroetheneug/L555.050.000ND58-142109Tolueneug/L531.050.000ND68-127106Trichloroetheneug/L501.050.000ND72-132100ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d49749Page 84 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organic Compounds by EPA 8260 - Quality ControlBatch 7020120 - EPA 5030BMatrix Spike (7020120-MS1)Prepared & Analyzed: 02/03/17 Source: AAB0060-17ug/L50.00080-120Surr: Toluene-d89749ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike Dup (7020120-MSD1)Prepared & Analyzed: 02/03/17 Source: AAB0060-17Benzeneug/L521.050.000ND967-1341032Chlorobenzeneug/L483.050.000ND1369-1229731,1-Dichloroetheneug/L545.050.000ND958-1421080.9Tolueneug/L531.050.000ND968-1271060.9Trichloroetheneug/L501.050.000ND1172-132990.5ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d89648ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Page 85 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201505/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 86 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFR-04Elevated reporting limit due to sample foaming.R-01Elevated reporting limit due to matrix interference.QR-02The RPD result exceeded the QC control limits; however, both percent recoveries were acceptable. Sample results for the QC batch were accepted based on percent recoveries.QR-01RPD was outside acceptance limits due to sample concentrations near or below the reporting limit.QM-06Due to suspected matrix interference, RPD and Percent Recovery values for the MS and/or MSD were outside control limits. Sample results for the QC batch were accepted based on acceptable LCS recoveries.QM-05The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries.QM-02The spike recovery is outside acceptance limits due to insignificant spike amount as compared to sample concentration.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).H-04Sample dilution was analyzed outside holding time. Sample was originally analyzed within holding time but required further dilution.Page 87 of 90
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 13, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFB-BODOxygen depletion for the batch dilution water blank exceeded the method specified maximum of 0.2mg/L but did not exceed half of the default reporting limit of 2mg/L resulting in blank value reported as "ND".B-01Analyte was detected in the associated method blank at an estimated level equal to or greater than the MDL. Sample values reported as greater than the MDL and less than 10x the method blank value are reported as estimated values.Note: Unless otherwise noted, all results are reported on an as received basis.Page 88 of 90
Page 89 of 90
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
Upper Piedmont Regional LandfillProject:
Client:
Printed: 2/6/2017 1:37:04PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:02/02/17 09:15 Logged In By:Charles Hawks
Work Order:AAB0083
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 15 #Containers: 67
3.0 3.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
The Leachate sample for COD/NH3/NO3+NO2, Metals were pH adjusted from 7 to <2 with H2SO4 and HNO3 respectively.
The CN sample was pH adjusted from 7 to >12 with NaOH. CFH
Comments:
Page 1 of 1Page 90 of 90
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: Upper Piedmont Regional LandfillConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:March 16, 2017Report Number:AAB0091Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received7304-GW2AAB0091-0202/01/17 10:25 02/02/17 09:15Ground Water7304-GW3AAB0091-0302/01/17 10:5002/02/17 09:15Ground Water7304-GW4AAB0091-0402/01/17 11:2302/02/17 09:15Ground Water7304-GW5AAB0091-0502/01/17 11:5102/02/17 09:15Ground Water7304-GW7AAB0091-0602/01/17 12:2002/02/17 09:15Ground Water7304-GW8AAB0091-0702/01/17 12:5502/02/17 09:15Ground Water7304-GW9AAB0091-0802/01/17 13:2802/02/17 09:15Ground Water7304-GW10AAB0091-0902/01/17 14:0202/02/17 09:15Ground WaterPage 2 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW2Ground WaterAAB0091-02AAB009102/01/17 10:25Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 19:3903/08/17 15:40EPA 6020B682ug/L1Manganese10.07030239EPA 3005A0.7067439-96-503/09/17 19:3903/08/17 15:40Page 3 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW3Ground WaterAAB0091-03AAB009102/01/17 10:50Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 19:4403/08/17 15:40EPA 6020B55.0ug/L1Manganese10.07030239EPA 3005A0.7067439-96-503/09/17 19:4403/08/17 15:40Page 4 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW4Ground WaterAAB0091-04AAB009102/01/17 11:23Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 19:5003/08/17 15:40Page 5 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5Ground WaterAAB0091-05AAB009102/01/17 11:51Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedEPA 6020B0.77ug/L1Arsenic10.0J7030239EPA 3005A0.427440-38-203/09/17 20:0703/08/17 15:40NDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 20:0703/08/17 15:40NDEPA 6020Bug/L1Manganese10.07030239EPA 3005A0.7067439-96-503/09/17 20:0703/08/17 15:40Page 6 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW7Ground WaterAAB0091-06AAB009102/01/17 12:20Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 20:1303/08/17 15:40EPA 6020B6680ug/L10Manganese1007030239EPA 3005A7.067439-96-503/15/17 13:2803/08/17 15:40Page 7 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW8Ground WaterAAB0091-07AAB009102/01/17 12:55Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedEPA 6020B10.3ug/L1Cobalt10.07030239EPA 3005A0.457440-48-403/09/17 20:1903/08/17 15:40NDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 20:1903/08/17 15:40EPA 6020B390ug/L5Manganese50.07030239EPA 3005A3.537439-96-503/15/17 13:2803/08/17 15:40Page 8 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW9Ground WaterAAB0091-08AAB009102/01/17 13:28Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 20:2503/08/17 15:40EPA 6020B113ug/L1Manganese10.07030239EPA 3005A0.7067439-96-503/15/17 13:4003/08/17 15:40Page 9 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW10Ground WaterAAB0091-09AAB009102/01/17 14:02Project:Upper Piedmont Regional Landfill02/02/17 09:15Metals, DissolvedNDEPA 6020Bug/L1Iron40.07030239EPA 3005A2.857439-89-603/09/17 20:3003/08/17 15:40EPA 6020B188ug/L1Manganese10.07030239EPA 3005A0.7067439-96-503/15/17 13:4603/08/17 15:40Page 10 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7030239 - EPA 3005ABlank (7030239-BLK1)Prepared: 03/08/17 Analyzed: 03/09/17 Arsenicug/LND10.0Cobaltug/LND10.0Ironug/LND40.0Manganeseug/LND10.0Blank (7030239-BLK2)Prepared: 03/08/17 Analyzed: 03/09/17 Arsenicug/LND10.0Cobaltug/LND10.0Ironug/LND40.0Manganeseug/LND10.0LCS (7030239-BS1)Prepared: 03/08/17 Analyzed: 03/09/17 Arsenicug/L93.910.0100.0080-12094Cobaltug/L10110.0100.0080-120101Ironug/L106040.01000.080-120106Manganeseug/L10910.0100.0080-120109LCS (7030239-BS2)Prepared: 03/08/17 Analyzed: 03/09/17 Arsenicug/L10010.0100.0080-120100Cobaltug/L10210.0100.0080-120102Ironug/L107040.01000.080-120107Manganeseug/L10810.0100.0080-120108Matrix Spike (7030239-MS1)Prepared: 03/08/17 Analyzed: 03/09/17 Source: AAB0091-02Arsenicug/L99.510.0100.000.9175-12599Cobaltug/L11010.0100.005.3575-125104Ironug/L106040.01000.07.9175-125105Manganeseug/L76110.0100.0068275-12578Page 11 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7030239 - EPA 3005AMatrix Spike Dup (7030239-MSD1)Prepared: 03/08/17 Analyzed: 03/09/17 Source: AAB0091-02Arsenicug/L98.810.0100.000.912075-125980.7Cobaltug/L10810.0100.005.352075-1251022Ironug/L106040.01000.07.912075-1251050.2Manganeseug/L74010.0100.0068220QM-0275-125583Post Spike (7030239-PS1)Prepared: 03/08/17 Analyzed: 03/09/17 Source: AAB0091-02Arsenicug/L99.3100.000.9180-12098Cobaltug/L106100.005.3580-120101Ironug/L10301000.07.9180-120102Manganeseug/L720100.00682QM-0280-12038Page 12 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201505/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 13 of 16
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannMarch 16, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFQM-02The spike recovery is outside acceptance limits due to insignificant spike amount as compared to sample concentration.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 14 of 16
Page 15 of 16
LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
Upper Piedmont Regional LandfillProject:
Client:
Printed: 2/6/2017 2:01:37PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:02/02/17 09:15 Logged In By:Charles Hawks
Work Order:AAB0091
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 9 #Containers: 9
3.0 3.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
Comments:
Page 1 of 1Page 16 of 16
PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: Upper Piedmont Regional LeachateConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:(none)Prepared For:Attention:February 17, 2017Report Number:AAB0082Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received7304-LeachateAAB0082-0102/01/17 14:50 02/02/17 09:15Water7304-Trip BlankAAB0082-0202/01/17 07:00 02/02/17 09:15WaterPage 2 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-LeachateWaterAAB0082-01AAB008202/01/17 14:50Project:Upper Piedmont Regional Leachate02/02/17 09:15BTEX by EPA 8260NDEPA 8260Bug/L1Benzene2.07020120EPA 5030B0.271-43-202/04/17 04:2002/03/17 09:00EPA 8260B1.3ug/L1Ethylbenzene2.0J7020120EPA 5030B0.4100-41-402/04/17 04:2002/03/17 09:00EPA 8260B1.5ug/L1Toluene2.0J7020120EPA 5030B0.3108-88-302/04/17 04:2002/03/17 09:00EPA 8260B7.5ug/L1Xylenes, total2.07020120EPA 5030B0.91330-20-702/04/17 04:2002/03/17 09:00EPA 8260B7.5ug/L1BTEX. total2.07020120EPA 5030B2.0BETX02/04/17 04:2002/03/17 09:00EPA 8260B89 %Surr: Dibromofluoromethane7020120EPA 5030B1868-53-702/04/17 04:2002/03/17 09:0080-120EPA 8260B104 %Surr: 1,2-Dichloroethane-d47020120EPA 5030B17060-07-002/04/17 04:2002/03/17 09:0078-120EPA 8260B97 %Surr: Toluene-d87020120EPA 5030B2037-26-502/04/17 04:2002/03/17 09:0080-120EPA 8260B104 %Surr: 4-Bromofluorobenzene7020120EPA 5030B460-00-402/04/17 04:2002/03/17 09:0080-120Volatile OrganicsEPA 8015C400ug/L1Gasoline Range Organics1007020176EPA 5030B50CDF02/07/17 15:5302/07/17 10:00EPA 8015C105 %Surr: 2,5-Dibromotoluene7020176EPA 5030B615-59-802/07/17 15:5302/07/17 10:0010-223Semivolatile OrganicsEPA 8015C5300ug/L1Diesel Range Organics2007020137EPA 3510C2068334-30-502/10/17 16:2902/06/17 14:00EPA 8015C31 %Surr: n-Decane7020137EPA 3510C124-18-502/10/17 16:2902/06/17 14:0010-120EPA 8015C49 %Surr: n-Octacosane7020137EPA 3510C630-02-402/10/17 16:2902/06/17 14:0018-149Page 3 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Trip BlankWaterAAB0082-02AAB008202/01/17 07:00Project:Upper Piedmont Regional Leachate02/02/17 09:15BTEX by EPA 8260NDEPA 8260Bug/L1Benzene2.07020120EPA 5030B0.271-43-202/03/17 18:5702/03/17 09:00NDEPA 8260Bug/L1Ethylbenzene2.07020120EPA 5030B0.4100-41-402/03/17 18:5702/03/17 09:00NDEPA 8260Bug/L1Toluene2.07020120EPA 5030B0.3108-88-302/03/17 18:5702/03/17 09:00NDEPA 8260Bug/L1Xylenes, total2.07020120EPA 5030B0.91330-20-702/03/17 18:5702/03/17 09:00NDEPA 8260Bug/L1BTEX. total2.07020120EPA 5030B2.0BETX02/03/17 18:5702/03/17 09:00EPA 8260B91 %Surr: Dibromofluoromethane7020120EPA 5030B1868-53-702/03/17 18:5702/03/17 09:0080-120EPA 8260B97 %Surr: 1,2-Dichloroethane-d47020120EPA 5030B17060-07-002/03/17 18:5702/03/17 09:0078-120EPA 8260B98 %Surr: Toluene-d87020120EPA 5030B2037-26-502/03/17 18:5702/03/17 09:0080-120EPA 8260B102 %Surr: 4-Bromofluorobenzene7020120EPA 5030B460-00-402/03/17 18:5702/03/17 09:0080-120Volatile OrganicsNDEPA 8015Cug/L1Gasoline Range Organics1007020176EPA 5030B50CDF02/07/17 15:2202/07/17 10:00EPA 8015C113 %Surr: 2,5-Dibromotoluene7020176EPA 5030B615-59-802/07/17 15:2202/07/17 10:0010-223Page 4 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteBTEX by EPA 8260 - Quality ControlBatch 7020120 - EPA 5030BBlank (7020120-BLK1)Prepared & Analyzed: 02/03/17 Benzeneug/LND2.0Ethylbenzeneug/LND2.0Tolueneug/LND2.0Xylenes, totalug/LND2.0BTEX. totalug/LND2.0ug/L50.00080-120Surr: Dibromofluoromethane9145ug/L50.00078-120Surr: 1,2-Dichloroethane-d49748ug/L50.00080-120Surr: Toluene-d89748ug/L50.00080-120Surr: 4-Bromofluorobenzene10150LCS (7020120-BS1)Prepared & Analyzed: 02/03/17 Benzeneug/L492.050.00067-13499Tolueneug/L502.050.00068-127100Chlorobenzeneug/L471050.00069-122941,1-Dichloroetheneug/L512.050.00058-142102Trichloroetheneug/L472.050.00072-13294ug/L50.00080-120Surr: Dibromofluoromethane9346ug/L50.00078-120Surr: 1,2-Dichloroethane-d49547ug/L50.00080-120Surr: Toluene-d810050ug/L50.00080-120Surr: 4-Bromofluorobenzene10452Matrix Spike (7020120-MS1)Prepared & Analyzed: 02/03/17 Source: AAB0060-17Benzeneug/L532.050.000ND67-134106Tolueneug/L532.050.000ND68-127106Chlorobenzeneug/L501050.0000.569-12299Page 5 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteBTEX by EPA 8260 - Quality ControlBatch 7020120 - EPA 5030BMatrix Spike (7020120-MS1)Prepared & Analyzed: 02/03/17 Source: AAB0060-171,1-Dichloroetheneug/L552.050.000ND58-142109Trichloroetheneug/L502.050.000ND72-132100ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d49749ug/L50.00080-120Surr: Toluene-d89749ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Matrix Spike Dup (7020120-MSD1)Prepared & Analyzed: 02/03/17 Source: AAB0060-17Benzeneug/L522.050.000ND967-1341032Tolueneug/L532.050.000ND968-1271060.9Chlorobenzeneug/L481050.0000.51369-1229631,1-Dichloroetheneug/L542.050.000ND958-1421080.9Trichloroetheneug/L502.050.000ND1172-132990.5ug/L50.00080-120Surr: Dibromofluoromethane9246ug/L50.00078-120Surr: 1,2-Dichloroethane-d410050ug/L50.00080-120Surr: Toluene-d89648ug/L50.00080-120Surr: 4-Bromofluorobenzene10251Page 6 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteVolatile Organics - Quality ControlBatch 7020176 - EPA 5030BBlank (7020176-BLK1)Prepared & Analyzed: 02/07/17 Gasoline Range Organicsug/LND100ug/L50.00010-223Surr: 2,5-Dibromotoluene12060LCS (7020176-BS1)Prepared & Analyzed: 02/07/17 Gasoline Range Organicsug/L500100500.0028-18295ug/L50.00010-223Surr: 2,5-Dibromotoluene11960Matrix Spike (7020176-MS1)Prepared & Analyzed: 02/07/17 Source: AAB0082-01Gasoline Range Organicsug/L900100500.0040018-18792ug/L50.00010-223Surr: 2,5-Dibromotoluene11457Matrix Spike Dup (7020176-MSD1)Prepared & Analyzed: 02/07/17 Source: AAB0082-01Gasoline Range Organicsug/L800100500.004001718-187798ug/L50.00010-223Surr: 2,5-Dibromotoluene10854Page 7 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteSemivolatile Organics - Quality ControlBatch 7020137 - EPA 3510CBlank (7020137-BLK1)Prepared: 02/06/17 Analyzed: 02/10/17 Diesel Range Organicsug/LND200ug/L500.0010-120Surr: n-Decane61304ug/L500.0018-149Surr: n-Octacosane110551LCS (7020137-BS1)Prepared: 02/06/17 Analyzed: 02/10/17 Diesel Range Organicsug/L9002001000.026-12091ug/L500.0010-120Surr: n-Decane68341ug/L500.0018-149Surr: n-Octacosane107533Matrix Spike (7020137-MS1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAB0082-01Diesel Range Organicsug/L50002001000.05000QM-0513-1240.6ug/L1000.010-120Surr: n-Decane32321ug/L1000.018-149Surr: n-Octacosane53531Matrix Spike Dup (7020137-MSD1)Prepared: 02/06/17 Analyzed: 02/10/17 Source: AAB0082-01Diesel Range Organicsug/L30002001000.0500055QM-0513-124048ug/L1000.010-120Surr: n-Decane14141ug/L1000.018-149Surr: n-Octacosane26256Page 8 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201503/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2017TX1340Virginia12/14/2017VAPage 9 of 11
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannFebruary 17, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFQM-05The spike recovery was outside acceptance limits for the MS and/or MSD and/or PDS due to suspected matrix interference. Sample results for the QC batch were accepted based on acceptable LCS recoveries.JEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 10 of 11
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PACE ANALYTICAL SERVICES, LLC.Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]Republic Services of North Carolina, LLCProject: Upper Piedmont Landfill ResampleConover, NC 286131220 Commerce Street, SWMr. Matt EinsmannWe appreciate the opportunity to provide the analytical support for your project. The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Pace Analytical Services, LLC. certifies that the following analytical results meet all requirements of the National Environmental Laboratory Accreditation Conference(NELAC).All test results relate only to the samples analyzed.Laboratory ReportProject #:[none]Prepared For:Attention:April 17, 2017Report Number:AAD0056Approved:This report may not be reproduced, except in full, without written approval from Pace Analytical Services, LLC.Page 1 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017Sample IDLaboratory IDMatrixDate SampledANALYTICAL REPORT FOR SAMPLESDate Received7304-GW5AAD0056-0103/31/17 10:34 04/04/17 09:35Water7304-Field BlankAAD0056-0203/31/17 11:5004/04/17 09:35WaterPage 2 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-GW5WaterAAD0056-01AAD005603/31/17 10:34Project:Upper Piedmont Landfill Resample04/04/17 09:35Metals, TotalEPA 6020B1.16ug/L1Arsenic10.0J7040185EPA 3005A0.427440-38-204/07/17 18:1904/07/17 11:30Metals, DissolvedEPA 6020B0.61ug/L1Arsenic10.0J7040224EPA 3005A0.427440-38-204/14/17 00:2204/10/17 09:40Page 3 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultAnalyteSWSL/ RLPrepMethodQual DFUnitsBatchAnalyticalMethodMDLCAS #Prep Date/TimeAnalysis Date/TimeClient ID:Date/Time Sampled:Matrix:Report No.:Lab No:Date/Time Received:7304-Field BlankWaterAAD0056-02AAD005603/31/17 11:50Project:Upper Piedmont Landfill Resample04/04/17 09:35Metals, TotalNDEPA 6020Bug/L1Arsenic10.07040185EPA 3005A0.427440-38-204/07/17 18:2404/07/17 11:30Page 4 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Total - Quality ControlBatch 7040185 - EPA 3005ABlank (7040185-BLK1)Prepared & Analyzed: 04/07/17 Arsenicug/LND10.0LCS (7040185-BS1)Prepared & Analyzed: 04/07/17 Arsenicug/L10210.0100.0080-120102Matrix Spike (7040185-MS1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Arsenicug/L10310.0100.001.1675-125102Matrix Spike Dup (7040185-MSD1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Arsenicug/L10510.0100.001.162075-1251042Post Spike (7040185-PS1)Prepared & Analyzed: 04/07/17 Source: AAD0056-01Arsenicug/L103100.001.1680-120102Page 5 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017ResultLimitReportingUnitsLevelSpikeResultSource%REC%RECLimitsRPDRPDLimitQual AnalyteMetals, Dissolved - Quality ControlBatch 7040224 - EPA 3005ABlank (7040224-BLK1)Prepared: 04/10/17 Analyzed: 04/13/17 Arsenicug/LND10.0Blank (7040224-BLK2)Prepared: 04/10/17 Analyzed: 04/13/17 Arsenicug/LND10.0LCS (7040224-BS1)Prepared: 04/10/17 Analyzed: 04/13/17 Arsenicug/L83.810.0100.0080-12084LCS (7040224-BS2)Prepared: 04/10/17 Analyzed: 04/13/17 Arsenicug/L10510.0100.0080-120105Matrix Spike (7040224-MS1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Arsenicug/L10310.0100.00ND75-125103Matrix Spike Dup (7040224-MSD1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Arsenicug/L10210.0100.00ND2075-1251021Post Spike (7040224-PS1)Prepared: 04/10/17 Analyzed: 04/13/17 Source: AAD0274-01Arsenicug/L102100.00-0.0580-120102Page 6 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017Laboratory CertificationsCodeDescriptionNumberExpires812Georgia DW Inorganics Eff: 07/01/201606/30/2017GADW812Georgia DW Microbiology Eff: 07/01/201505/09/2017GADWM381North Carolina12/31/2017NCE87315FL DOH (Non-Pot. Water, Solids) Eff:: 07/01/201606/30/2017NELACE87315FL DOH NELAC (Drinking Water) Eff: 07/01/201606/30/2017NELDW98011001South Carolina06/30/2017SCT104704397-08-TXTexas03/31/2018TX460204Virginia12/14/2017VAPage 7 of 10
Environmental Monitoring & Laboratory Analysis110 Technology Parkway, Peachtree Corners, GA 30092(770) 734-4200 FAX [phone]PACE ANALYTICAL SERVICES, LLC.Republic Services of North Carolina, LLC1220 Commerce Street, SWConover NC, 28613Attention: Mr. Matt EinsmannApril 17, 2017LegendDefination of Laboratory Terms - Not Detected at levels greater than or equal to SWSL/RLNDSWSL/RLMDL - NC DENR Solid Waste Section LImit/Reporting Limit (Adjusted for DF/Prep Factor) - Method Detection LimitQualifiers - Dilution FactorDFJEstimated value less than Reporting Limit (RL) but greater than Method Detection Limit(MDL) (CLP J-Flag).Note: Unless otherwise noted, all results are reported on an as received basis.Page 8 of 10
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LOG-IN CHECKLIST
Republic Services of North Carolina, LLC
Upper Piedmont Landfill ResampleProject:
Client:
Printed: 4/5/2017 2:05:28PM
Environmental Monitoring & Laboratory Analysis
[phone] FAX [phone]
110 Technology Parkway, Peachtree Corners, GA 30092
PACE ANALYTICAL SERVICES, LLC.
Date Received:04/04/17 09:35 Logged In By:Charles Hawks
Work Order:AAD0056
OBSERVATIONS
Attn: Mr. Matt Einsmann
#Samples: 2 #Containers: 3
2.0 2.0
YES
Minimum Temp(C):Maximum Temp(C):
CHECKLIST ITEMS
COC included with Samples
Sample Container(s) Intact
Chain of Custody Complete
Sample Container(s) Match COC
Custody seal Intact
Temperature in Compliance
Sufficient Sample Volume for Analysis
Zero Headspace Maintained for VOA Analyses
Samples labeled preserved (If Applicable)
Samples received within Allowable Hold Times
Samples Received on Ice
Preservation Confirmed
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
YES
Custody Seal(s) Used:Yes
Comments:
Page 1 of 1Page 10 of 10

Appendix D

Statistical Analyses Summary Table
Appendix D: Results of Statistical Analyses from Alternate Source Demonstration (December 2016) Constituent NC 2L GWPSData DistributionStatistical Method used to Establish BackgroundCalculated Background ConcentrationHighest Reported Concentration July 2016Noted SSI Cobalt N/E 1 µg/L 53% TruncatedNonparmetric Prediction Interval (Interwell)31.5 µg/l 12.6 µg/l in GW-8 NoneIron 300 µg/L N/E0% Truncated, non-normal, non-lognormalNonparmetric Prediction Interval (Interwell)53.6 mg/l 106 mg/l in GW-7 GW-7Iron 300 µg/L N/E0% Truncated, normal and lognormalParmetric Upper Tolerance Limit (Intrawell - GW-7)385 mg/l 106 mg/l in GW-7 NoneManganese 50 µg/L N/E0% Truncated, non-normal, non-lognormalNonparmetric Prediction Interval (Interwell)6.58 mg/l 14.6 mg/l in GW-7 GW-7Manganese 50 µg/L N/E0% Truncated, normal and lognormalParmetric Upper Tolerance Limit (Intrawell - GW-7)14.9 mg/l 14.6 mg/l in GW-7 NoneNotes:NC 2L = North Carolina Groundwater Standard from 15A NCAC 2L.0202.N/E = Not established.GWPS = Solid Waste Section Groundwater Protect Standard.SSI = Statistically Significant Increase above Background.Interwell statistics based on all available data from background wells (GW-1 & GW-1R) and pre-waste background data from GW-7, GW-8, GW-9, & GW-10.Intrawell statistics based only on pre-waste background data from GW-7.Upper Piedmont Regional Landfill, Permit No. 73-04Republic ServicesJoyce EngineeringNovember 2016