1203_BurkeCountyCDLF_GWMR_DIN28580_20161213

PREPARED FOR:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680

JOHNS RIVER WASTE MANAGEMENT FACILITY
PERMIT NO. 12-03
C&D EXPANSION - PHASE 1A

SECOND SEMIANNUAL WATER QUALITY MONITORING
REPORT OF 2016

MARCH 2017

PREPARED BY:

2211 WEST MEADOWVIEW ROAD, SUITE 101
GREENSBORO, NORTH CAROLINA 27407
NC LICENSE NUMBER C-0782
PHONE: [phone]
FAX: [phone]
JOYCE PROJECT NO. 277.1701.12

2nd Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 March 2017
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Second Semiannual Water Quality Monitoring Report of 2016
Johns River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS

1.0 INTRODUCTION..............................................................................................................1 
1.1 Site Information ........................................................................................................................1 
1.2 Site Geology .............................................................................................................................1 
1.3 Regulatory Status .....................................................................................................................2 
2.0 FACILITY MONITORING PROGRAM .......................................................................2 
2.1 Groundwater Monitoring Program ...........................................................................................2 
2.2 Surface Water Monitoring Program .........................................................................................3 
3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016 ............................................3 
3.1 Field Work ................................................................................................................................3 
3.2 Laboratory Analysis and JOYCE Quality Control ...................................................................5 
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS .....................................5 
4.1 Analytical Results for Inorganic Constituents ..........................................................................6 
4.2 Analytical Results for Organic Constituents ............................................................................6 
4.3 Statistical Analyses ...................................................................................................................6 
4.3.1 Statistical Methods and Background .................................................................................. 6 
4.3.2 Inorganic Constituents ........................................................................................................ 7 
4.4 Analytical Results for Surface Water .......................................................................................7 
5.0 HYDROGEOLOGICAL CONDITIONS ........................................................................7 
6.0 CONCLUSION ..................................................................................................................8 
7.0 REFERENCES ...................................................................................................................9 
9.0 ACRONYMS ....................................................................................................................10 

2nd Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 March 2017
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Second Semiannual Water Quality Monitoring Report of 2016
Johns River Waste Management Facility – Permit No. 12-03
C&D Expansion - Phase 1A
Burke County, North Carolina

TABLE OF CONTENTS (CONTINUED)

Tables:
Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters
Table 3 Quantified Detections of Groundwater Constituents Table 4 Exceedances of Groundwater Standards
Table 5 Quantified Detections in Additional Wells/Piezometers
Table 6 Exceedances in Additional Wells/Piezometers
Table 7 Statistical Background Analyses
Table 8 Hydraulic Gradients and Groundwater Flow Velocities

Figure:
Figure 1 Site Location Map

Drawing:
Drawing 1 Groundwater Surface Map

Appendices:
Appendix a Field Data Logs
Appendix B Laboratory Analytical Reports
Appendix C Statistical Analyses Worksheets
Appendix D Historical Detected Groundwater Constituents
Appendix E Historical Detected Constituents in Additional Wells/ Piezometers
Appendix F Historical Detected Surface Water Constituents

2nd Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 March 2017
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1.0 INTRODUCTION
1.1 Site Information
The Johns River Waste Management Facility (JRWMF) is located in the north-central portion of
Burke County, north of Morganton, North Carolina. The 318-acre landfill property is bounded
by Lower Creek to the north and east, and the Catawba River to the south. The Catawba River
forms Lake Rhodhiss along the southeastern property line (Figure 1). Lake Rhodhiss is a long,
narrow lake formed by the Rhodhiss Hydroelectric Dam located approximately 12 miles
downstream of the landfill. The John’s River flows into the Catawba River near the southwest
corner of the landfill property. A MSW transfer facility is located in the eastern half of the
property. A site plan showing all the pertinent features of the facility is provided in Drawing 1.

The site has rolling topography with elevations ranging from 975 feet to 1,150 feet above mean
sea level (MSL). The central portion is generally gently sloping and contains the higher
elevations; relatively steep slopes and significant drainage features are located around the
perimeter. The 100-year flood boundary extends onto the landfill property. The adjacent
property to the west of the Johns River Waste Management Facility consists of undeveloped,
heavily wooded land. Properties within 2,000 feet of the landfill boundary are covered by
surface water or are heavily wooded.

The C&D-over-MSW waste disposal unit consists of 28 acres in the southwest corner of the
landfill property. The municipal solid waste (MSW) landfill began operation in April 1988, but
was closed in 1997 to comply with Rule .1627(c)(10)(A) of the NCSWMR, a regulation
governing MSW Landfills units that were not designed with a base liner and leachate collection
system. Burke County has operated a permitted Construction and Demolition (C&D) disposal
area on top of the closed portions of the MSW landfill since 1998. The results of the second
semiannual sampling event for the old C&D-over-MSW landfill will be presented in a separate
report.

A Permit to Construct for Phase 1A was issued in March 2014 and Burke County completed
construction of Phase 1A of the C&D landfill expansion in July 2014. A Permit to Operate for
Phase 1A was issued by the North Carolina Department of Environment and Natural Resources,
now the Department of Environmental Quality (NCDEQ), on August 14, 2014. In accordance
with the approved Water Quality Monitoring Plan (WQMP) for the facility (dated August 2012),
there are four groundwater monitoring wells designated as compliance wells for Phase 1A:
MW-21(background), MW-20, MW-22S, and MW-38.

1.2 Site Geology
The Johns River Waste Management Facility is in close proximity to the Brevard Shear Zone,
and is underlain by highly metamorphosed rocks including gneiss and schist, as well as calc-
silicate rocks, felsic rocks, and metavolcanic rocks. The dominant rock type at the facility is
biotite-muscovite schist, as seen in outcrops, boulders, and rock cores located on site. The
structures within limited outcrops indicate that these rocks are complexly-folded, with attitudes
that vary from vertical to horizontal. The site regolith is typical of the inner piedmont and

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consists mostly of silty sand, clayey sand, and sandy silt. The regolith is up to 100 feet thick and
varies in thickness with topography.

An abundance of rounded gravel, cobble, and boulder-sized alluvial deposits are exposed along
the banks of the Catawba River, which borders the site. The greatest accumulation of these
deposits is along the southwestern site boundary. These river deposits are 40 feet or more above
the current river elevation and have been described as ancient river terrace deposits.

1.3 Regulatory Status
The following report of groundwater monitoring data from the JRWMF Phase 1A C&D
expansion has been prepared in accordance with the North Carolina Solid Waste Management
Rules (NCSWMR) 15A NCAC 13B §.0544 (Monitoring Plans and Requirements for C&D
Landfill Facilities). The Phase 1A expansion is currently operating under the Detection
Monitoring Program.

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the JRWMF Phase 1A is performed in accordance with NCSWMR
§.0544. Groundwater samples are collected semiannually and analyzed for constituents
according to the approved Water Quality Monitoring Plan (WQMP) for the facility dated August
2012. Following is a summary of the compliance monitoring wells.

Well ID Date
Installed Classification Monitoring
Program
Total Depth
of Well (ft)
Lithology of
Screened
Interval
Constituent
List
MW-20 5-18-95 Compliance Detection 67.0 Saprolite Comp.
MW-21 5-18-95 Background Detection 45.0 Saprolite Comp.
MW-22s 6-1-96 Compliance Detection 25.0 Saprolite Comp.
MW-38 5-09-11 Compliance/
Performance* Detection 71.0 Bedrock Comp., LFG
Notes: Comp. = Compliance Parameters: NCSWMR Appendix I and/or Appendix II organics and inorganics
plus C&D parameters, as required for routine assessment or detection monitoring.
LFG = Landfill Gas Indicators: Dissolved CH4 and dissolved CO2.
*MW-38 is also a performance well for the C&D-over-MSW Landfill.

The current compliance groundwater monitoring network at the facility consists of one
upgradient well (MW-21), and three downgradient wells (MW-20, MW-22S and MW-38).

In January 2014, in response to the County’s permit application for the C&D expansion area, the
NCDEQ requested that the County sample several additional wells and/or piezometers in the
vicinity of Phases 1 and 2 of the expansion. The County agreed to sample PZ-31, PZ-30S,
PZ-34, MW-36(PZ-36), PZ-12, and MW-15S semiannually beginning with the spring 2014

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sampling event. The County also agreed to sample the following other wells/piezometers in the
event of GPS exceedances, as follows:

 PZ-30D will be added in the event that there are GPS exceedances at PZ-30S;
 PZ-35 will be added in the event that there are GPS exceedances at PZ-34;
 MW-15D will be added in the event that there are GPS exceedances at MW-15S;
 PZ-16S will be added in the event that there are GPS exceedances at PZ-35 or PZ-12;
and
 PZ-16D will be added in the event that there are GPS exceedances at PZ-16S.
 PZ-34 was inadvertently destroyed during the spring of 2014; therefore, PZ-35 is now
sampled instead.

The additional piezometers/wells are to be sampled for the facility’s COCs (excluding alpha-
BHC and beta-BHC). Sampling of the additional piezometers/wells will be conducted for two
years (four sampling events), after which the NCDEQ will reevaluate the need for continued
sampling of the additional piezometers/wells.

2.2 Surface Water Monitoring Program
The current surface water monitoring points are SMP-5, SMP-6, and SMP-7. Surface water
monitoring point SMP-5 (located at the southwestern property line) and SMP-6 (located at the
southeastern property line) are both located downstream from existing sediment basins. Surface
water monitoring point SMP-7 is located downstream from the Phase 1A expansion area. The
surface water monitoring program is designed to monitor for possible impacts from both the
C&D over MSW Landfill and the Phase 1A C&D Landfill; surface water samples are analyzed
for the NCSWMR Appendix I list of constituents plus detected Appendix II constituents during
both semiannual events.

Surface Point Classification Monitoring
Program Location
SMP-5 Compliance Surface Water Creek on west side of landfill,
downstream of sediment basin.
SMP-6 Compliance Surface Water Creek on east side of landfill,
downstream of sediment basin.
SMP-7 Compliance Surface Water
Creek southeast of Phase 1A and
east of sediment basin SB-2A.
Downstream of PZ-12.

3.0 SECOND SEMIANNUAL SAMPLING EVENT OF 2016
3.1 Field Work
In order to detect potential releases of leachate and/or landfill gas migration in a timely manner,
a visual inspection program has been implemented at the Johns River Waste Management
Facility. This inspection program involves field personnel making the following observations:

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 Indications of stress on the biological community (e.g., dead or dying vegetation);
 Indications of leachate impact (e.g., seeps, impacted surface water);
 Observations of erosion;
 Condition of monitoring wells; and
 Negative changes around the waste facility.

On December 13-14, 2016, personnel from JOYCE visited Johns River Waste Management
Facility to purge and sample monitoring wells MW-20, MW-21, MW-22S, and MW-38.
Additional wells/piezometers MW-15S, PZ-12, PZ-30S, PZ-31, PZ-35, and PZ-36 were also
sampled. Surface monitoring points SMP-5, SMP-6, and SMP-7 were also sampled during the
December 2016 event. The usual inspections indicated no unusual issues or concerns.

Depth-to-water measurements were obtained to the nearest 0.01 foot using an electronic water
level indicator for all monitoring wells in the compliance network prior to purging. Table 1
presents current and historical groundwater elevation data. Monitoring wells were purged and
sampled using disposable bailers. Measurements of temperature, pH, specific conductivity, and
turbidity were recorded in the site log book as well as on field data logs prior to purging, after
each purge volume, and during sampling. Field data logs for the December 2016 event are
provided in Appendix A, and the field parameters are summarized in Table 2.

Laboratory-supplied containers were prepared and labeled (either by the laboratory or in the
field, as indicated) with the following information:
 Monitoring well number (completed by field personnel),
 Date and time of sample collection (completed by field personnel),
 Initials of sampling personnel (completed by field personnel),
 Project name and number (completed by the laboratory),
 Chemical preservative (completed by the laboratory); and
 Requested chemical analysis (completed by the laboratory).

Groundwater samples from each monitoring well were dispensed directly from the disposable
bailers into the provided laboratory containers either immediately after purging or within 24
hours of the final purge volume. Immediately after collection, the samples were placed in a
laboratory-provided cooler and chilled with ice.

Surface water samples were collected directly from stream flow by lowering the prepared sample
containers into the stream flow. Care was taken not the overflow the sample containers (which
could lead to preservative loss) and avoid sample-induced turbidity. At the time of sampling,
surface water was also measured for temperature, pH, specific conductivity, and turbidity and
recorded in the site log book. After sample collection, the samples were placed in a laboratory
provided cooler and chilled on ice. Field data logs are provided in Appendix A, and the field
parameters are summarized in Table 2.

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3.2 Laboratory Analysis and JOYCE Quality Control
The Second Semiannual (December 2016) groundwater and surface water samples were
submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain-of-
custody control for analysis. The groundwater samples were analyzed for the NC Appendix I list
of constituents, plus additional required C&D parameters. Surface water samples were analyzed
for the NC Appendix I list of constituents (plus detected Appendix II constituents form the old
C&D-over-MSW landfill) during both semiannual events. JOYCE requested a Level II data
report for the final laboratory report. The samples were received by the laboratory in good
condition, properly preserved, and within required hold times.

In addition to samples collected for compliance monitoring at the John’s River Waste
Management Facility, a Field Blank was collected by JOYCE personnel as part of the December
2016 sampling event. Also, a Trip Blank prepared by the laboratory accompanied the volatile
sampling containers from and to the laboratory. The Field Blank was analyzed for the NC
Appendix I, plus previously detected Appendix II list of constituents, plus iron, manganese and
tetrahydrofuran, and the Trip Blank was analyzed for Appendix I list of constituents plus
additional detected Appendix II volatile organic compounds and tetrahydrofuran.

Upon receipt of the laboratory data package, JOYCE personnel reviewed the data package for
quality assurance/quality control (QA/QC) purposes and for possible regulatory issues. If any
QA/QC or regulatory issues were found, the laboratory would be contacted to resolve the issue,
and a resampling event might be scheduled, if needed. The laboratory analytical packages can
be found in Appendix B of this report. The data package was reviewed for the following:
 General typographical errors;
 Correct analyses performed and within method specified hold times;
 Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate,
and Laboratory Control Samples;
 Blank-qualified data (B-flags);
 Detections exceeding the North Carolina 15A NCAC 2L .0202 Groundwater Standards
(NC2L), NCDEQ-SWS Groundwater Water Protection Standards (GWPS), and North
Carolina 15A NCAC 2B Surface Water Standards (NC2B); and
 Detections that are above historical levels.

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSIS
The constituents with quantified detections above the SWSL in one or more compliance
monitoring wells are presented in Table 3 and the constituents with exceedances of the NC2L
Standards or GWPS in one or more compliance monitoring wells are presented in Table 4. The
constituents with quantified detections above the SWSL in one or more of the additional
wells/piezometers are presented in Table 5 and the constituents with exceedances of the NC2L
Standards or GWPS in one or more additional wells/piezometers are presented in Table 6. The
complete laboratory reports and chains of custody are included in Appendix B. Historical data
are presented in Appendices D, E, and F.

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4.1 Analytical Results for Inorganic Constituents
Four inorganic constituents were detected above the NC2L/GWPS in one or more monitoring
wells during the December 2016 sampling event. The constituents were the C&DLF parameters
iron and manganese. Iron was reported above the NC2L Standard in MW-20, MW-21, MW-22S
and MW-38; and manganese was reported above the NC2L Standard in MW-20 and MW-38;
however, an ASD was approved for iron and manganese by DENR for the Johns River facility
on April 12, 2012. In general, the detections and concentrations are consistent with historical
data.

4.2 Analytical Results for Organic Constituents
Three organic constituents, benzene, 1,1-dichloroethane, and 1,4-dichlorobenzene were detected
above the NC2L Standards in compliance monitoring well MW-38 during the December 2016
sampling event. In addition, results from the additional wells/piezometers indicated NC2L
exceedance of tetrachloroethylene in MW-15S, and of benzene and 1,4-dichlorobenzene in
MW-36. No other exceedances were noted in any of the other wells/piezometers.

The exceedances noted in MW-15S, MW-36, and MW-38 are believed to be due to landfill gas
migration from the C&D-over-MSW Landfill and are being addressed in the Corrective Action
Plan for that landfill. In general, the detections and concentrations are consistent with historical
data and display trends of decreasing concentrations over time.

4.3 Statistical Analyses
4.3.1 Statistical Methods and Background
MW-9 was the facility background well from 1994 until May 2005, when it was abandoned.
MW-17 was the facility background well from May 1999 until June 2011. Both MW-9 and
MW-17 were sampled between May 1999 and May 2005. Due to gas related impacts to MW-17,
MW-20 became the facility background well in December 2010. Both MW-17 and MW-20
were sampled between December 2010 and June 2011. With the opening of Phase 1A of the
C&D expansion in August 2014, MW-21 (formerly PZ-1) became the facility background well
and MW-20 became a compliance well for Phase 1A. Facility background data used to evaluate
Phase 1A groundwater monitoring data include all data collected for wells MW-9, MW-17, and
MW-20 from September 1994 through the May 2015 event, plus the May 2015 to the current
results from MW-21.

The background data for inorganic constituents are evaluated as needed in response to GPS
exceedances using the Shapiro-Wilk Test, Parametric Prediction Limits, Parametric Tolerance
Intervals, Aitchison’s Adjustment, Non-Parametric Prediction Limits, and/or Poisson Prediction
Limits as appropriate. Background data, tests for normality, outliers, Aitchison’s adjustment,
tolerance interval, or prediction limits are used, as appropriate based on the background data.
The statistical test by which downgradient data are compared to facility background data is based
upon the nature of the data and the number of data values that are less than the laboratory limit of
detection. All statistical tests are evaluated at the 0.05 level of significance, 95% confidence
level, and are conducted as one-tailed tests.

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No statistical analyses were conducted for the December 2016 sampling event because there
were no exceedances of NC2L or GWPS for inorganic constituents that were not covered by a
previously-approved ASD.

4.3.2 Inorganic Constituents
The inorganic constituents detected at quantifiable concentrations (excluding blank-qualified
data) above the North Carolina SWSL in downgradient monitoring wells in the December 2016
sampling event were barium, copper, zinc, iron, and manganese. Iron and manganese
exceedances were addressed in an ASD approved by NCDEQ (formerly DENR) in April 2012.
No other organic constituents were detected above their respective NC2L or GWPS during the
December 2016 sampling event.

4.4 Analytical Results for Surface Water
There were no quantified detections in the surface water during the December 2016 sampling
event. In general, the 2016 second semiannual surface water results are consistent with historical
data. Current and historical surface water data can be found in Appendix F.

5.0 HYDROGEOLOGICAL CONDITIONS
Based on outcrop and drilling information, the water table appears to occur within regolith
everywhere across the site. This regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. Inspection of drill cuttings and site
outcrops indicates that water in the regolith is transmitted largely through fractures. In this
regard, regolith behaves similar to unweathered bedrock, except that fractures are more
numerous and better connected in the regolith, and will tend to have more isotropic hydraulic
properties. Along the low-lying areas of the Catawba River and its tributaries, the water table
occurs within surficial alluvial deposits overlying the residual soils and weathered bedrock.

Groundwater discharges into creeks to the east and west of the landfill and to the Catawba River
to the south. A groundwater potentiometric surface map, developed from static water level data
obtained in December 2016, is presented as Drawing 1. The potentiometric surface map depicts
groundwater flow primarily to the south.

Depth to groundwater was measured in the compliance monitoring wells at the site prior to
sampling. The December 2016 and historical groundwater elevations are provided in Table 1.
The groundwater elevations were calculated relative to the surveyed measuring point (top of
casing) for each monitoring well. Horizontal groundwater gradients along representative flow
paths were estimated from the December 2016 groundwater contours shown on Drawing 1 and
are summarized in Table 8. Horizontal gradients across the site ranged from 0.0360 to 0.0580
ft/ft, with an average of approximately 0.0468 ft/ft. This is consistent with previous estimates.

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Linear groundwater flow velocities for wells screened in saprolite were computed using the
modified Darcy equation: V = Ki/n, where V = average linear velocity, K = hydraulic
conductivity, i = horizontal hydraulic gradient, and n = effective porosity. The average of
hydraulic conductivities from slug-tests conducted at the facility (K = 3.28 ft/day) was used in
these calculations, along with an effective porosity of n = 0.40 (40%) based on laboratory
porosities for soil samples from the facility.

The estimated linear groundwater flow velocity under the facility ranged from 108-174 feet/year,
with an average flow velocity of approximately 140 feet/year (Table 8). Because of our
conservative estimate of effective porosity, actual groundwater velocities may be significantly
less than those calculated. Also, the modified Darcy equation makes the simplified assumptions
of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to
heterogeneous and/or anisotropic conditions such as are believed to exist at this site.

The groundwater flow direction and rate have shown no significant seasonal variations over
several years of monitoring. The groundwater flow regime on this site is well constrained and
predictable. Migration of groundwater contaminants are expected to follow the general
groundwater flow paths and there are no known preferred pathways or barriers to groundwater
flow that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility

6.0 CONCLUSION
Benzene and 1,4-dichlorobenzene were detected above their respective NC2L standards in
MW-38; however, these detections are attributed to landfill gas migration from the old C&D-
over-MSW landfill. No other organic constituents were detected above the GPS in any of the
Phase 1A compliance monitoring wells. These results are consistent with historical data from
the site.

Benzene and 1,4-dichlorobenzene were also detected above the NC2L in the additional well
MW-36, and tetrachloroethene was detected above the NC2L in additional well MW-15S. There
were no other organic constituents detected above the GPS in any of the other additional wells or
piezometers. The exceedances in MW-36 and MW-15S are attributed to landfill gas migration
from the old C&D-over-MSW landfill. Since the organic detections in MW-15S are not
attributed to a release from the Phase 1A cell, and the organic detections have shown decreasing
trends over time, sampling for MW-15D has not been implemented at this time.

Detections of inorganic constituents were consistent with historical data from previous sampling
events. An ASD was approved for iron and manganese by NCDEQ (formerly DENR) on April
12, 2012. No other inorganic constituents were detected above NC2L standards or GWPS.

There were no organic or inorganic constituents detected above NC2B standards in the surface
water during the December 2016 sampling event. Surface water monitoring is consistent with
previous monitoring events.

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The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site. Based on analytical results from the December
2016 sampling event, Phase 1A of the Johns River Landfill will remain in Detection Monitoring.
The next semiannual sampling event is scheduled May of 2017.

7.0 REFERENCES
Hinchee, R.E., A. Leeson, L. Semprini, and S.K. Ong. 1994. Bioremediation of Chlorinated and
Polycyclic Aromatic Hydrocarbon Compounds. Lewis Publishers, Boca Raton.

Interstate Technology and Regulatory Cooperation Work Group (ITRC). September 1999.
Natural Attenuation of Chlorinated Solvents in Groundwater: Principles and Practices.
Technical/Regulatory Guidelines.

Interstate Technical Regulatory Council (ITRC). 2003. Technical and Regulatory Guidance
Document for Constructed Treatment Wetlands.

Joyce Engineering (JOYCE), 1994. Transition Plan, Johns River Waste Management Facility.
April 1994.

JOYCE, 2000. Water Quality Assessment Report, Johns River Waste Management Facility.
January 2000.

JOYCE, 2004. Update on Groundwater Assessment Activities, Johns River Waste Management
Facility. October 2004.

JOYCE, 2005a. Assessment of Corrective Measures Report, Johns River Waste Management
Facility. February 2005.

JOYCE, 2005b. Quantitative Risk Assessment, Johns River Waste Management Facility.
February 2005.

JOYCE, 2008. Corrective Action Plan, Johns River Waste Management Facility. June 2008.

JOYCE, 2011. Corrective Action Evaluation Report, Johns River Waste Management Facility.
May 2011.

JOYCE, 2013. Addendum to the Corrective Action Plan, Johns River Waste Management
Facility. August 2013.

JOYCE, 2016. Corrective Action Evaluation Report, Johns River Waste Management Facility.
April 2016.

2nd Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
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National Research Council (NRC), 2000. Natural Attenuation for Groundwater Remediation.
National Academy Press, Washington, D.C. pp. 108-111.

North Carolina Department of Environment, Health, and Natural Resources (NC-DENR), 1997.
North Carolina Solid Waste Management Rules. 15 NCAC 13B. January 1, 1997.

NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid
Waste Management Facilities. March 2007.

Sumsion, C.T., and Laney, R.L., 1967, Geology and Ground-water Resources of the Morganton
area North Carolina. N.C. Department of Water Resources, Ground Water Bulletin No.
12, 119 p.

U.S. Department of Energy (USDE). May 1999. Decision-Making Framework Guide for the
Evaluation and Selection of Monitored Natural Attenuation Remedies at Department of
Energy Sites.

U.S. Environmental Protection Agency (USEPA), 1992. Statistical Analysis of Groundwater
Monitoring Data at RCRA Facilities, Addendum to Interim Final Guidance. July 1992.

USEPA. October 1988. Interim Final Guidance for Conducting Remedial Investigations and
Feasibility Studies under CERCLA. Office of Solid Waste and Emergency Response
(OSWER) Directive 9355.3-01, EPA/540/G-89/004.

USEPA. February 1991. Conducting Remedial Investigations/Feasibility Studies for CERCLA
Municipal Landfill Sites. OSWER Directive 9355.3-11, EPA/540/P-91/001.

USEPA. May 1995. How to Evaluate Alternative Cleanup Technologies for Underground
Storage Tank Sites: A Guide for Corrective Action Plan Reviewers. Chapters 2 (Soil
Vapor Extraction) and 10 (In-Situ Groundwater Bioremediation).

USEPA. May 1996. Seminars on Bioremediation of Hazardous Waste Sites: Practical
Approaches to Implementation. ORD, EPA/625/K-96/001. Chapters 15 (Natural
Attenuation of Groundwater) and 17 (Natural Attenuation of Landfills).

USEPA and U.S. Air Force (USAF). July 1993. Remediation Technologies Screening Matrix
Reference Guide, Version I. Joint Project of OSWER and Environics Directorate, PB93-
2118212.

9.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AMSL Above Mean Sea Level
AOC Area of Concern
BGS Below Ground Surface

2nd Semiannual Water Quality Monitoring Report of 2016 Joyce Engineering
Burke County – Johns River Landfill, Phase 1A, Permit No. 12-03 March 2017
11
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
CAMP Corrective Action Monitoring Plan (Report)
CAS Chemical Abstracts Service
CFR Code of Federal Regulations
CPVC Chlorinated Poly Vinyl Chloride
COC Contaminant of Concern (for corrective action)
COC Chain of Custody (for sampling and lab reports)
DENR North Carolina Department of Environment and Natural Resources
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency (or USEPA)
GWPS Groundwater Protection Standards (Established by DENR-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
MW Monitoring Well
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCGS North Carolina Geological Survey
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
O&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
RQD Rock Quality Designation
SPT Standard Penetration Test
SSI Statistically Significant Increase (above background concentrations)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of DENR-Division of Waste Management)
SWSL North Carolina Solid Waste Section Reporting Limits
TOC Top of Casing (Well)
USCS Unified Soil Classification System
USEPA United States Environmental Protection Agency (or EPA)
USGS United States Geological Survey
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)

TABLES

Table 1 Historical Groundwater Elevation Data
Table 2 Field Parameters
Table 3 Quantified Detections of Groundwater Constituents
Table 4 Exceedances of Groundwater Standards
Table 5 Quantified Detections in Additional Wells/Piezometers Table 6 Exceedances in Additional Wells/Piezometers
Table 7 Hydraulic Gradients and Groundwater Flow Velocities

TABLE 1: HISTORICAL GROUNDWATER ELEVATIONSClassification: BackgroundWell No. (Former ID)MW-21 (PZ-1)MW-20 (PZ-4)MW-22S (PZ-22S)MW-38 (PZ-38)MW-36 (PZ-36)MW-15S PZ-12 PZ-30S PZ-31 PZ-35TOC Elevation1099.86 1115.04 1061.20 1087.76 1099.52 1069.04 1025.64 1088.92 1089.81 1063.39Well Depth41.00 67.00 26.40 73.13 45.00 56.16 15.09 55.25 43.13 37.7518-Jun-96 NM NM 1049.88 NI NI 1022.70 1017.92 NI NI NI4-Dec-96 NM NM 1046.75 NI NI 1021.30 1017.91 NI NI NI6-May-14 1066.06 1058.24 1048.70 1042.18 1069.17 1025.74 1018.14 1041.92 1064.14 1044.4721-Oct-14 1063.48 1056.42 1045.76 1045.18 1066.52 1024.64 1017.68 1048.92 1061.04 1042.1321-May-15 1062.18 1053.69 1043.65 1044.68 1066.03 1025.17 1017.60 1047.22 1060.17 1041.129-Dec-15 1061.71 1051.65 1042.60 1046.24 1066.72 1025.19 1017.69 1045.57 1058.70 fill in!4-May-16 1065.36 1056.81 1045.81 1044.91 1071.22 1026.24 1017.94 1047.47 1056.31 fill in!13-Dec-16 1061.11 1051.66 1042.52 1042.81 1065.99 1022.89 1017.19 1046.32 1057.01 1039.44Notes: All elevations are in feet above mean sea level.NM = Groundwater level not measured.NI = well not yet installed.Phase 1A ComplianceAdditional Wells & PiezometersBurke County Johns River CDLF - Phase 1A Permit 12-03 Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
MW-20 Conductivity 66 µS/cm 12/14/2016
MW-20 Dissolved Oxygen 7.69 mg/L 12/14/2016
MW-20 Oxidation Reduction Potential 217.4 mV 12/14/2016
MW-20 pH 6.45 S.U.12/14/2016
MW-20 Static Water Level 63.38 ft 12/14/2016
MW-20 Temperature 14.1 ºC 12/14/2016
MW-20 Turbidity 17.55 NTU 12/14/2016
MW-20 Well Depth 67.00 ft 12/14/2016
MW-21 Conductivity 115 µS/cm 12/13/2016
MW-21 Dissolved Oxygen 5.41 mg/L 12/13/2016
MW-21 Ferrous Iron 0.5 mg/L 12/13/2016
MW-21 Oxygen Reduction Potential 180.4 mV 12/13/2016
MW-21 pH 5.17 S.U.12/13/2016
MW-21 Static Water Level 38.75 ft 12/13/2016
MW-21 Temperature 14.4 ºC 12/13/2016
MW-21 Turbidity 12.63 NTU 12/13/2016
MW-21 Well Depth 46.80 ft 12/13/2016
MW-22S Static Water Level 18.68 ft 12/14/2016
MW-22S pH 5.70 S.U.12/14/2016
MW-22S Conductivity 19.00 µS/cm 12/14/2016
MW-22S Temperature 16.6 ºC 12/14/2016
MW-22S Turbidity 9.10 NTU 12/14/2016
MW-22S Well Depth 26.40 ft 12/14/2016
MW-38 Static Water Level 44.95 ft 12/14/2016
MW-38 pH 6.70 S.U.12/14/2016
MW-38 Conductivity 522 µS/cm 12/14/2016
MW-38 Temperature 15.1 ºC 12/14/2016
MW-38 Turbidity 13.47 NTU 12/14/2016
MW-38 Well Depth 74.50 ft 12/14/2016
PZ-12 Static Water Level 8.45 ft 12/14/2016
PZ-12 pH 6.14 S.U.12/14/2016
PZ-12 Conductivity 26.0 µS/cm 12/14/2016
PZ-12 Temperature 13.5 ºC 12/14/2016
PZ-12 Turbidity 17.00 NTU 12/14/2016
PZ-12 Well Depth 14.90 ft 12/14/2016
MW-15S Static Water Level 46.15 ft 12/14/2016
MW-15S pH 5.55 S.U.12/14/2016
MW-15S Conductivity 51.0 µS/cm 12/14/2016
MW-15S Temperature 14.8 ºC 12/14/2016
MW-15S Turbidity 10.50 NTU 12/14/2016
MW-15S Well Depth 58.27 ft 12/14/2016
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 Page 1 of 2
Joyce Engineering
TABLE 2:
FIELD PARAMETERS
WELL ID PARAMETER RESULT UNITS COLLECT DATE
PZ-30S Static Water Level 42.60 ft 12/14/2016
PZ-30S pH 5.89 S.U.12/14/2016
PZ-30S Conductivity 21.0 µS/cm 12/14/2016
PZ-30S Temperature 15.40 ºC 12/14/2016
PZ-30S Turbidity 9.15 NTU 12/14/2016
PZ-30S Well Depth 55.30 ft 12/14/2016
PZ-31 Static Water Level 32.80 ft 12/14/2016
PZ-31 pH 6.78 S.U.12/14/2016
PZ-31 Conductivity 33.0 µS/cm 12/14/2016
PZ-31 Temperature 14.3 ºC 12/14/2016
PZ-31 Turbidity 9.20 NTU 12/14/2016
PZ-31 Well Depth 45.60 ft 12/14/2016
PZ-35 Static Water Level 23.95 ft 12/14/2016
PZ-35 pH 6.17 S.U.12/14/2016
PZ-35 Conductivity 22.0 µS/cm 12/14/2016
PZ-35 Temperature 15.2 ºC 12/14/2016
PZ-35 Turbidity 9.73 NTU 12/14/2016
PZ-35 Well Depth 39.05 ft 12/14/2016
MW-36 Static Water Level 28.30 ft 12/14/2016
MW-36 pH 5.97 S.U.12/14/2016
MW-36 Conductivity 241 µS/cm 12/14/2016
MW-36 Temperature 15.6 ºC 12/14/2016
MW-36 Turbidity 13.61 NTU 12/14/2016
MW-36 Well Depth 45.58 ft 12/14/2016
SMP-5 Conductivity 118.7 µS/cm 12/14/2016
SMP-5 pH 7.40 S.U.12/14/2016
SMP-5 Temperature 11.5 ºC 12/14/2016
SMP-5 Turbidity 30.4 NTU 12/14/2016
SMP-6 Conductivity 81 µS/cm 12/14/2016
SMP-6 pH 6.69 S.U.12/14/2016
SMP-6 Temperature 10.7 ºC 12/14/2016
SMP-6 Turbidity 14.43 NTU 12/14/2016
SMP-7 Conductivity 25 µS/cm 12/14/2016
SMP-7 pH 6.32 S.U.12/14/2016
SMP-7 Temperature 8.9 ºC 12/14/2016
SMP-7 Turbidity 10.15 NTU 12/14/2016
Notes:ºC= degrees Centigrade
S.U.= Standard Units
µS = microsemens
NTU = Nephelometric Turbidity Units
mg/L = milligrams per liter
ft = feet
(Resample) = Parameters taken during verification sampling on given date in table.
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 Page 2 of 2
Joyce Engineering
TABLE 3:
QUANTIFIED DETECTIONS OF GROUNDWATER and SURFACE WATER
CONSTITUENTS
WELL ID PARAMETER RESULT UNITS SWSL COLLECT DATE
1203-MW20 Barium 123 µg/L 100 12/13/2016
1203-MW20 Copper 11.9 µg/L 10 12/13/2016
1203-MW20 Iron 9,700 µg/L 300 12/13/2016
1203-MW20 Manganese 169 µg/L 50 12/13/2016
1203-MW20 Zinc 23.8 µg/L 10 12/13/2016
1203-MW20 Alkalinity, Total as CaCO3 6,190 µg/L NE 12/13/2016
1203-MW20 Total Dissolved Solids (TDS) 33,000 µg/L NE 12/13/2016
1203-MW20 Chloride 1,460 µg/L NE 12/13/2016
1203-MW21 Iron 2,020 µg/l 300 12/13/2016
1203-MW21 Chloride 1,470 µg/L NE 12/13/2016
1203-MW22S Iron 2,440 µg/L 300 12/13/2016
1203-MW22S Chloride 1,240 µg/L NE 12/13/2016
1203-MW38 Iron 37,400 µg/L 300 12/13/2016
1203-MW38 Manganese 3,380 µg/L 50 12/13/2016
1203-MW38 1,1-Dichloroethane 6.0 µg/L 5 12/13/2016
1203-MW38 1,4-Dichlorobenzene 8.3 µg/L 1 12/13/2016
1203-MW38 Benzene 3.0 µg/L 1 12/13/2016
1203-MW38 Trichloroethene 1.8 µg/L 1 12/13/2016
1203-MW38 Carbon Dioxide 300,000 µg/L NE 12/13/2016
1203-MW38 cis-1,2-Dichloroethene 12.7 µg/L 5 12/13/2016
1203-MW38 Alkalinity, Total as CaCO3 294,000 µg/L NE 12/13/2016
1203-MW38 Total Dissolved Solids (TDS) 366,000 µg/L NE 12/13/2016
1203-MW38 Chloride 4,760 µg/L NE 12/13/2016
Notes: µg/L = micorgrams per liter.
SWSL = NC Soild Waste Section Reporting Limit. NE = Not Established.
Laboratory Reporting limit used when SWSL has not been established.
There were no quantified detections in surface water from the December 2016 sampling event.
MW-38 detections are impacts from the old C&D-over-MSWLF and not from new Phase 1A cell.
Burke County Johns River CDLF - Phase 1A
Permit No. 12-03 1 of 1 Joyce Engineering
TABLE 4:EXCEEDANCES OF GROUNDWATER and SURFACE WATER STANDARDSWELL IDPARAMETERRESULT UNITS SWSLNC2L /*GWPS /**NC2BGPS COLLECT DATE1203-MW20 Iron9,700 µg/L 300 300 ASD 12/13/20161203-MW20 Manganese169 µg/L 5050 ASD 12/13/20161203-MW21 Iron2,020 µg/l 300 300 ASD 5/3/20161203-MW22S Iron2,440 µg/L 300 300 ASD 12/13/20161203-MW38 Iron37,400 µg/L 300 300 ASD 12/13/20161203-MW38 Manganese3,380 µg/L 5050 ASD 12/13/20161203-MW38 1,4-Dichlorobenzene8.3 µg/L 16612/13/20161203-MW38 Benzene3.0 µg/L 11112/13/2016Notes:µg/L = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit. NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 NC2B = NC Surface Water Standards & Protective Values from 15A NCAC 02B GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g) GPS for chromium, cobalt, and vanadium are based on background calculations for the site.GPS Exceedances are bold.ASD = Alternate Source Demonstration. An ASD for Iron and Manganese was approved by DEQ in April 2012; therefore, they are not considered GPS exceedances.MW-38 detections are attributed to impacts from the old C&D-over-MSWLF, and not from the new Phase 1A cell.Burke County Johns River CDLF - Phase 1APermit No. 12-031 of 1Joyce Engineering
TABLE 5:QUANTIFIED DETECTIONS IN ADDITIONAL MONITORING WELLS/PIEZOMETERS (LFG DELINEATION STUDY)WELL IDPARAMETERRESULT UNITS SWSL COLLECT DATE1203-PZ12 Carbon Dioxide 35,000µg/LNE 12/13/20161203-PZ30S Carbon Dioxide 22,000µg/LNE 12/13/20161203-PZ31 Carbon Dioxide 14,000µg/LNE 12/13/20161203-PZ31 Methane 27µg/LNE 12/13/20161203-PZ35 Carbon Dioxide 29,000µg/LNE 12/13/20161203-MW15S Methane 16,700 µg/L NE 12/13/20161203-MW15S Carbon Dioxide 350,000µg/LNE 12/13/20161203-MW15S Tetrachloroethene1.4µg/L 1 12/13/20161203-MW36 1,4-Dichlorobenzene15.8µg/L 1 12/13/20161203-MW36 Benzene5.5µg/L 1 12/13/20161203-MW36 Methane 32,200 µg/L NE 12/13/20161203-MW36 Carbon Dioxide 510,000µg/LNE 12/13/20161203-MW38 Carbon Dioxide 300,000µg/LNE 12/13/20161203-MW38 Methane 15,300 µg/L NE 12/13/2016Notes: µg/L = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit. NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.Burke County Johns River CDLF - Phase 1APermit No. 12-031 of 1Joyce Engineering
TABLE 6:EXCEEDANCES IN ADDITIONAL MONITORING WELLS/PIEZOMETERS(LFG DELINEATION STUDY)WELL IDPARAMETERRESULT UNITS SWSL NC2L/*GWPS GPS COLLECT DATE1203-MW15S Tetrachloroethene 1.4 µg/L 1 0.7 0.7 12/13/20161203-MW36 1,4-Dichlorobenzene 15.8 µg/L 1 6 6 12/13/20161203-MW36 Benzene 5.5 µg/L 1 1 1 12/13/2016Notes: µg/L = micorgrams per liter.SWSL = NC Soild Waste Section Reporting Limit. NE = Not Established.Laboratory Reporting limit used when SWSL has not been established.NC2L = NC Groundwater Standard from 15A NCAC 2L.0202 GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)GPS = Groundwater Protection Standard as defined by 15A NCAC 13B.1634(g)GPS Exceedances are bold.Burke County Johns River CDLF - Phase 1APermit No. 12-031 of 1Joyce Engineering
TABLE 7: HYDRAULIC GRADIENTS AND GROUNDWATER FLOW VELOCITIESGRADIENT CALCULATION SEGMENTFLOW LINE LENGTH (feet)FLOW DIRECTIONGROUNDWATER ELEVATION (feet)HORIZONTAL GRADIENT i (ft/ft)HYDRAULIC CONDUCTIVITY K (ft/day)EFFECTIVE POROSITY neLINEAR VELOCITY V (ft/year)10701030107010001070101010601030AVERAGE: 0.0468AVERAGE: 140.0Notes:Hydraulic conductivity (K=3.28 ft/day) is based on the arithmetric means of K from individual slug tests in saprolite wells at the facility.Effective Porosity (ne = 0.40) is assummed to be slightly less than the average laboratory porosity for site soil samples (saprolite) = 44% (0.44).Gradient segments are based on the December 2016 groundwater potentiometric surface map (see Drawing 1).V = Ki/ne; assumes homogeneous isotropic porous aquifer.December 2016i1907SSW0.0441 3.28E+00 0.40 132.0146.5i31,035SSE0.0580 3.28E+00 0.40 173.5i21,430S0.0490 3.28E+00 0.40107.8i4833SE0.0360 3.28E+00 0.40Burke County Johns River CDLF - Phase 1APermit 12-03Joyce Engineering

FIGURE

Figure 1: Site Location Map

APPROXIMATE LOCATION
OF EXISTING LANDFILL
APPROXIMATE LOCATION
OF PROPERTY LINE
SOURCE: U.S.G.S. TOPOGRAPHIC MAP
FOR MORGANTON NORTH, N.C.
0
(FEET)
GRAPHIC SCALE
400020001000
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
PROJECT NO.
FIGURE NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
All rights reserved.
Ó Joyce Engineering, Inc.
SCALE
NC CORP LIC: C-0782
JOHN'S RIVER LANDFILL
BURKE COUNTY, NORTH CAROLINA
SITE LOCATION MAP
277
1
AS SHOWN
2017
ACE
RH
ACE
ACE
2017

DRAWING

Drawing 1: Groundwater Potentiometric Surface Map

SMP-5SURFACE MONITORING POINT LOCATION AND IDENTIFICATIONNOT MEASUREDLEGENDPROPERTY LINEEXISTING ROADEXISTING 25' TOPOGRAPHIC CONTOUREXISTING 2' TOPOGRAPHIC CONTOURGROUNDWATER SURFACE CONTOUR [FEETABOVE MEAN SEA LEVEL (AMSL)]APPROXIMATE LIMITS OF WASTECENTERLINE OF STREAMGAS PROBE LOCATION AND IDENTIFICATIONPIEZOMETER LOCATION AND IDENTIFICATIONCOMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)(NM)GP10501020MW-131009.66PZ-9DGMP-3TOPOGRAPHIC CONTOUR INTERVAL = 2 AND 10 FEET.GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.STATIC WATER LEVELS WERE MEASURED ON DECEMBER 12, 2016.GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN ANDEXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWNFIELD CONDITIONS.MW-16D GROUNDWATER ELEVATION WAS NOT USED IN CALCULATINGGROUNDWATER CONTOURS.NOTESEXISTING 5' TOPOGRAPHIC CONTOUREXISTING 10' TOPOGRAPHIC CONTOUR1080T1TEMPORARY WELLAPPROXIMATE LOCATION OF SPRING HEAD1.2.3.4.5.JE-0020CONTROL POINT LOCATION AND IDENTIFICATIONSENTINEL WELL LOCATION AND IDENTIFICATION WITH STATICWATER LEVEL ELEVATION (FEET AMSL)MW-18GROUNDWATER FLOW PATHWAY USED TOCALCULATE HYDRAULIC GRADIENTi1SEGMENT USED FOR GRADIENT CALCULATIONMW-9ABANDONED OR UNUSED MONITORING WELLiiiFLOW PATH LENGTH907 LF1,430 LF1035 LF833 LFi1030102
01010102010101000100010101020103010401050 106010701080109011001110112011301140115011601150114011301120111011001090108011701080107010601050104010501040103010201010100010601050104010301020101010001070i1i2
i3i41060(ABANDONED)PZ-2S(ABANDONED)PZ-2D(NM)PZ-23(NM)PZ-15(NM)MW-22D1042.52MW-22S(NM)PZ-16D(NM)PZ-16S1017.19PZ-12(NM)PZ-27(NM)PZ-14(NM)PZ-13(ND)PZ-9D(NM)PZ-9S1007.90MW-13SMP-6993.47MW-12992.90MW-11993.47MW-16D992.08MW-16S998.88MW-10SMP-5(ABANDONED)MW-9(NM)MW-141022.89MW-15S(NM)MW-15D1041.18MW-8(NM)MW-1(FORMERLY PZ-4)MW-20NMMW-17SHOOTINGRANGEMULCHINGAREALOWER CREEKJOHNS RIVERCATAWBA R
IVER PROTECTED AREAWETLANDEXISTING TRAILAPPROX. LIMIT OFEXISTING WASTETRANSFER FACILITYBOUNDARYEXISTINGSEDIMENTBASINEXISTING C&DDISPOSAL AREACURRENT BACKGROUND WELLFORMER MW-18MW-19NMNM1056.66OFFICEANDGARAGE1040 1050 1070 1080 1090 11001060MW-381042.81MW-361065.99PZ-30S1046.32PZ-30DPZ-311057.01PZ-351039.441061.11MW-21 (FORMERLY PZ-1)BACKGROUND WELLCURRENT PHASE 1A LIMITSPROJECT NO.APPROVED
CHECKED
DRAWN
DESIGNED
DATE
DATE REVISIONS AND RECORD OF ISSUE BYNO APPCKSCALE All rights reserved.
Ó Joyce Engineering, Inc.DRAWING NO.N:\Dwgs\Drawings-Current\BURKE\GW EVENT MAPS\GW-EVENT 12-16.DWG Layout=SHT 01
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]JOHNS RIVER, WASTE MANAGEMENT FACILITY
BURKE COUNTY, NORTH CAROLINA
20171AS NOTEDGROUNDWATER POTENTIOMETRIC SURFACE MAP
DECEMBER 12, 2016
PERMIT NO. 12-03
GE
RWH
VB
VB
01/25/170(FEET)GRAPHIC SCALE400200100

APPENDICES

Appendix A: Field Data Logs
Appendix B: Laboratory Analytical Reports
Appendix C: Statistical Analyses Worksheets
Appendix D: Historical Detected Groundwater Constituents
Appendix E: Historical Detected Constituents in Additional Wells and Piezometers
Appendix F: Historical Detected Surface Water Constituents

Appendix A

Field Data Logs

Fe2+:0.5m/LProjectNo./TaskNo.:277.1701.12.02G.Eller/H.Seaton2inches38.75feet46.80feet8.05feet[DTB-DTW]=1.3gallons=_____________gallons=3.9gallons3.9aHonsSignature:J-q.Date:QA/QCSignOff:_________________Date:t2—r--tLDATE:12/13/2016DEVELOPMENTANDGROUNDWATERSAMPLINGLOGOfftheroadbythewesternoronertvboundary.unfromGP-1JOYCEGI(\J8RIrJProjectName:John’sRiver,BurkeCoWellID:MW-21Sampler(s):WellLocation:__________________________WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653forTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:38.76feetGallonsTimeTemp(°C)DOCond.pHORP(mV)Turb.Initials(mg/L)(pS/cm)(s.u.)(NTU)0080113.77.55192.34.56384.78.25GE1.3080314.06.98218.43.26381.570.6GE2.6080513.37.71120.44.92279.1175GE3.9080713.57.60119.24.93286.8200GEBeforeSampling124514.45.41115.05.17180.412.63HSComments(weatherconditions,odor,color,silt, etc.):inthe40son12/13/2016.Theweatherwassunnywithtemperatures
DATE:12/14/2016JOYCE&JGir’JRIt’]GWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:_____2inches46.15feet58.27feet12.12feet[DTB-DTW]=1.9gallons=____________gallons=5.7gallons5.7gallonsSignature:Date:QAIQCSignOff:___________________Date:1?-1(—tL7GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-15SSampler(s):H.Seaton/G.EllerWellLocation:southwestofMW-38.acrossfromGP-4-feetGallonsTimeTemp(°C)pH(s.u.)Cond.DOORPTurb.Initials_
__
_
_
__
_
_
__(p.S/cm)(mg/L)(mV)(NTU)0091214.95.50482.16157.111.19GE1.9091414.85.50501.59133.29.76GE3.8091714.95.52522.13116.310.23GE5.7092414.85.55511.77140.210.50GEBefore092414.85.55511.77140.210.50GESampleComments(weatherconditions,odor,temoeraturesinthe40son12/14/2016.color,silt,etc.):TheweatherwassunnywithRevised12/30/05
2inches63.38feet67.00feet3.62feet[DTB-DTW]=0.6gallons=_____________gallons=1.8gallons1.8gallonsDate:Date:///3,/I)JOYCEErJGIr\JR!tJGDATE:12/13-14/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo.ITaskNo.:00277.1701.12.02WellID:MW-20Sampler(s):G.Eller/H.SeatonWellLocation:infieldonleftbetweenshopandroadtoC&DentranceWellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:63.50feetGallonsTimeTemp(°C)DO(mgIL)Cond.p11ORP(mV)Turb.InitialsQiSIcm)(s.u.)(NTU)0112014.99.26175.43154.433.2GE0.6112115.31.46165.58164.2486GE1.2112315.48.01165.70170.4>1000GE1.8112415.58.11185.76178.5>1000GE12/14/16BeforeSample074714.17.69666.45217.417.55GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son12/13/2016andon 12/14/16.Thewellwaspurgedon12/13/16andsamoledon 12/14/16.Signature:QAIQCSignOff:_________________Revised12/30/05
DATE:12/14/16JOYCE8r\JcIr\ISERII\JcProjectName:John’sRiver,BurkeCoWellID:MW-22SSampler(s):WellLocation:_________________________WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposablebailerSampledwith:DisposablebailerDepthtoWaterbeforeSampling:ProjectNo./TaskNo.:277.1701.12.02G.Eller/H.Seaton2inches18.68feet26.40feet7.42feet[DTB-DTW]=1.2gallons=____________gallons=3.6gallons3.6gallonsDevelopmentandGROUNDWATERSAMPLINGLOGInthewoodsontheedgeofthenewC&Dcell18.00feetGallonsTimeTemp(°C)pHCond.Turb.Initials(s.u.)(pS/cm)(NTU)0084416.16.41339.83GE1.2084616.25.8520206GE2.4084816.35.8019163GE3.6085016.05.681847.0GEBeforeSampling123016.65.70199.10GEComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son12/14/2016.Date:Date:QA/QCSignOff:
2inches33.53feet45.58feet12.05feet[DTB-DTW]=1.9gallons=____________gallons=5.7gallons5.7gallonsSignature:JifQA/QCSignOff:__________________Date:t2-HH—IcDate:JOYCE8r\JcIr\JSSRIr\JGDATE:12/14/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-36Sampler(s):H.Seaton/G.EllerProposedexpansionarea,downhillfromGP-2WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:-feetGallonsTimeTemp(°C)p11(s.u.)Cond.DOORPTurb.Initials(IIS/cm)(mg/L)(mV)(NTU)0110$15.55.852211.1938.06.04US1.9111015.85.882242.0430.78.28HS3.8111315.65.912322.8720.610.70HS5.7111615.65.972412.6813.913.61HSBeforeSampling111615.65.972412.6813.913.61USComments(weatherconditions,odor,color,silt,etc.):temnerafuresinthe 40son12/14/2016Theweatherwassunnywith
DATE:12/14/20162inches44.95feet74.50feet29.55feet[DTB-DTW]=4.8gallons=_____________gallons=14.4gallons14.4gallonsJOYCESI\JGIC’.JSSRIt’JGGROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:MW-38Sampler(s):H.Seaton/G.EllerProposedExpansionArea.SouthofPZ-36WellLocation:WellDiameter:Initial DepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWell Volumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:--feetGallonsTimeTemp(°C)pH(s.u.)Cond.DOORPTurb.Initials(.tS/cm)(mg/L)(mV)(NTU)0082015.26.384006.58-30.74.82GE4.8082415.16.224001.28-35.66.55GE9.6082815.36.625331.58-33.58.81GE14.4083415.16.705220.92-33.613.47GEBeforeSampling083415.16.705220.92 -33.613.47GEComments(weatherconditions,odor,color,silt, etc.):Theweatherwassunnywithtemoeraturesinthe40son12/14/2016.Signature:QAI
QC
Si
g
n
Off:__
__
_
__
_
__
_
__
__
_
__Date:Date:)//?/J7
DATE:12/14/2016JOYCE_________sir\JSSF?Ir\Jc9GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo.ITaskNo.:00277.1701.12.02WellID:PZ-12Sampler(s):H.Seaton/ G.EllerWellLocation:Proposedexpansionarea,WestofPZ-16S&-16DWellDiameter:2inchesInitialDepthtoWater(DTW):8.45feetDepthtoBottom(DTB):14.90feetWater ColumnThickness(WCT):6.45feet[DTB-DTW]CalculationforOneWellVolume(WV):For2”Well:WCTX0.163=1.0gallonsFor4” Well:WCTX0.653=____________gallonsForTHREEWellVolumes:WVX33.0gallonsActualAmountPurged/Baited:1.5gallonsPurgedwith:DisposablebailerSampledwith:DisposableBailerDepthtoWaterbefore Sampling:8.55feetGallonsTimeTemp(°C)pH(s.u.)Cond.ORPDOTurb.Initials(jiS/cm)(mV)(mgIL)(NTU)0095714.36.3027127.18.105.12HS1.0095813.96.1826144.36.9759.3HSDry1.5BeforeSample100813.56.1426 141.26.7817.0HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunnywithtemperaturesinthe 40son12/14/2016.Signature:_____________________________Date:1ltQA/QCSignOff:2-%---Date:
Signature:Q.tt/._//d-%QAIQCSignOff:2inches42.60feet55.30feet12.70feet[DTB-DTW]2.1gallons________gallons6.3gallons61a11onsJOYCEIrJ8SF?Ir’JcDATE:12/14/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo./TaskNo.:00277.1701.12.02WellID:PZ-30sSampler(s):H.Seaton/ G.EllerWellLocation:Proposedexpansionarea,SouthofMW-36WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):for2”Well:WCTX0.163for4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:43.XXfeetGallonslimelemp(°C)p11(s.u.)Cond.lurb.Initials(j.rS/cm)(NTU)0103514.56.36249.75HS2.1103815.36.161925HS4.2104115.36.493975HS6.3104515.46.746312511$BeforeSample120815.45.89219.15HSComments(weatherconditions,odor,color,temneraturesinthe40son12/14/2016.silt,etc.):TheweatherwasSunnywithDate:Date:1j_ttt-taRevised12/30/05
JOYCEEr%JG1r\JssRIr\JcDATE:12/14/2016GROUNDWATERSAMPLINGLOGProjectName:BurkeCounty-JohnsRiverProjectNo.ITaskNo.:00277.1701.12.01Signature:1%&Z7d-’QAIQCSignOff:___________________2inches32.80feet45.60feet12.80feet[DTB-DTW]=2.0gallons=_____________gallons=6.0gallons6.0gallonsDate:Date:BorrowpitareaSampler(s):H.Seaton/ G.EllerWellID:PZ-31VellLocation:_____WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):Water ColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WV X3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:33.48feetGallonslimeTemp(°C)pHCond.lurb.Initials(s.u.)(.tS/cm)(NIU)0105215.46.42238.87GE2.0105415.66.3216127GE4.0105615.66.3220152GE6.0105815.76.3219162GEBeforeSampling121814.36.78339.20HSComments(weatherconditions,odor,color,silt,etc.):Theweatherwassunny withtemperaturesinthe40son12/14/2016.1/131,7
JOYCE8r\JG!r%JsERIrJcDATE:12/14/2016GROUNDWATERSAMPLING1LOGProjectName:BurkeCounty-JohnsRiverProjectNo.IlaskNo.:00277.1701.12.02Signature:%iJ&_i”QA!QCSignOff:Sampler(s):H.Seaton/G.Eller2inches23.95feet39.05feet15.10feet[DTB-DTWI=2.4gallons=____________gallons=7.2gallons7.2gallonsProposedexpansionarea,downhillfromPZ-34andsed.pondWellID:PZ-35WellLocation:WellDiameter:InitialDepthtoWater(DTW):DepthtoBottom(DTB):WaterColumnThickness(WCT):CalculationforOneWellVolume(WV):For2”Well:WCTX0.163For4”Well:WCTX0.653ForTHREEWellVolumes:WVX3ActualAmountPurged/Bailed:Purgedwith:DisposableBailerSampledwith:DisposableBailerDepthtoWaterbeforeSampling:24.00feetGallonsTimeTemp(°C) pH(s.u.)Cond.Turb.Initials(p.S/cm)(NTU)0085714.95.95208.3711$2.4090015.26.1020518HS4.8090215.26.1319>1000HS7.2090415.16.1120>1000HSBeforeSampling120015.26.22229.73HSComments(weatherconditions,odor,color,silt,etc.):temperaturesinthe 40son12/14/2016.TheweatherwassunnywithDate:Date:/Zi/i
DATE:12/14/2016JOYCE__________srJGIr\JsERIrJGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:SMP-5Sampler(s):G.Eller/H.SeatonLocation:downroadtoriver,rightatforkinroadbesidebarnfieldParameters:TimeofSampling:1320pH:7.40Temperature:11.5(°C)Conductivity:118.7(jiS/cm)Turbidity:30.4(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwasunnywithtemperaturesinthe40son12/14/2016.Signature:______________________________Date:—IQA/QCSignOff:AVDate://i/i7
DATE:12/14/2016JOYCE__________Ef\JGICJ8RIPJGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:$MP-6Sampler(s):G.Eller/H.$eatonLocation:downhillfrombetweenMW-12&MW-13tostreamFieldParameters:TimeofSampling:1145pH:6.69Temperature:10.7(°C)Conductivity:81(p.S/cm)Turbidity:14.43(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwassunnywithtemperaturesinthe40son12/14/2016.Date:12.riLfr(4.i
DATE:12/14/2016JOYCE__________IrJERIC’JGSURFACEWATERMONITORINGLOGProjectName:BurkeCounty-JohnsRiverProject/TaskNo.:00277.1701.12.02SurfacePointID:$MP-7Sampler(s):G.EllenH.SeatonLocation:UpstreamfromPZ-12FieldParameters:TimeofSampling:1005pH:6.32Temperature:8.9(°C)Conductivity:25(jiS/cm)Turbidity:10.15(NTU)Comments/SampleDescription(weatherconditions,odor,color,silt,etc.):___________Theweatherwassunnywithtemperaturesinthe40son12/14/2016.FIELDBLANK(1430I—Kf-tC1///7

Appendix B

Laboratory Analytical Reports

#=CL#
January 03, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323296
92323296
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
BURKE CO. JOHNS R BACKGROUND
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 14, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 46
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 46
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID Matrix Date Collected Date Received
92323296001 1203-MW21 Water 12/13/16 12:45 12/14/16 10:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 46
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323296001 1203-MW21 EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-AWAB
EPA 8270 110 PASI-CBPJ
EPA 8260 68 PASI-CZDO
SM 2320B 1 PASI-AKDF
SM 2540C 1 PASI-AMJS1
SM 4500-S2D 1 PASI-AEWS
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-ADMN
SM 4500-CN-E 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 46
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323296001 1203-MW21
Barium 13.4J ug/L 12/23/16 06:15100EPA 6010
Copper 4.1J ug/L 12/23/16 06:1510.0EPA 6010
Iron 2020 ug/L 12/23/16 06:15300EPA 6010
Manganese 48.1J ug/L 12/23/16 06:1550.0EPA 6010
Vanadium 6.8J ug/L 12/23/16 06:1525.0EPA 6010
Alkalinity, Total as CaCO3 1190J ug/L 12/23/16 09:065000SM 2320B
Sulfate 1340J ug/L 12/17/16 21:06250000EPA 300.0
Chloride 1470 ug/L 12/29/16 16:141000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/16/16 23:09 309-00-212/15/16 16:340.050 0.050 1
alpha-BHC ND ug/L 12/16/16 23:09 319-84-612/15/16 16:340.050 0.050 1
beta-BHC ND ug/L 12/16/16 23:09 319-85-712/15/16 16:340.050 0.050 1
delta-BHC ND ug/L 12/16/16 23:09 319-86-812/15/16 16:340.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/16/16 23:09 58-89-912/15/16 16:340.050 0.050 1
Chlordane (Technical)ND ug/L 12/16/16 23:09 57-74-912/15/16 16:340.50 0.20 1
4,4'-DDD ND ug/L 12/16/16 23:09 72-54-812/15/16 16:340.10 0.050 1
4,4'-DDE ND ug/L 12/16/16 23:09 72-55-912/15/16 16:340.10 0.050 1
4,4'-DDT ND ug/L 12/16/16 23:09 50-29-312/15/16 16:340.10 0.050 1
Dieldrin ND ug/L 12/16/16 23:09 60-57-112/15/16 16:340.075 0.050 1
Endosulfan I ND ug/L 12/16/16 23:09 959-98-812/15/16 16:340.10 0.050 1
Endosulfan II ND ug/L 12/16/16 23:09 33213-65-912/15/16 16:340.10 0.050 1
Endosulfan sulfate ND ug/L 12/16/16 23:09 1031-07-812/15/16 16:340.10 0.050 1
Endrin ND ug/L 12/16/16 23:09 72-20-812/15/16 16:340.10 0.050 1
Endrin aldehyde ND ug/L 12/16/16 23:09 7421-93-412/15/16 16:340.10 0.050 1
Heptachlor ND ug/L 12/16/16 23:09 76-44-812/15/16 16:340.050 0.050 1
Heptachlor epoxide ND ug/L 12/16/16 23:09 1024-57-312/15/16 16:340.075 0.050 1
Methoxychlor ND ug/L 12/16/16 23:09 72-43-512/15/16 16:341.0 0.15 1
Toxaphene ND ug/L 12/16/16 23:09 8001-35-212/15/16 16:341.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)80 %12/16/16 23:09 877-09-812/15/16 16:3420-130 1
Decachlorobiphenyl (S)56 %12/16/16 23:09 2051-24-312/15/16 16:3420-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 20:10 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 20:10 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 20:10 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 20:10 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 20:10 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 20:10 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 20:10 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)45 %12/20/16 20:10 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/21/16 19:27 94-75-712/19/16 08:400.97 0.23 1
Dinoseb ND ug/L 12/21/16 19:27 88-85-712/19/16 08:400.19 0.059 1
2,4,5-T ND ug/L 12/21/16 19:27 93-76-512/19/16 08:400.19 0.043 1
2,4,5-TP (Silvex)ND ug/L 12/21/16 19:27 93-72-112/19/16 08:400.20 0.050 1
Surrogates
2,4-DCAA (S)94 %12/21/16 19:27 19719-28-912/19/16 08:4039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:22 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:15 7440-38-212/17/16 01:0010.0 2.5 1
Barium 13.4J ug/L 12/23/16 06:15 7440-39-312/17/16 01:00100 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 06:15 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:22 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:15 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:15 7440-48-412/17/16 01:0010.0 2.5 1
Copper 4.1J ug/L 12/23/16 06:15 7440-50-812/17/16 01:0010.0 2.5 1
Iron 2020 ug/L 12/23/16 06:15 7439-89-612/17/16 01:00300 25.0 1
Lead ND ug/L 12/23/16 21:22 7439-92-112/17/16 01:0010.0 2.5 1
Manganese 48.1J ug/L 12/23/16 06:15 7439-96-512/17/16 01:0050.0 2.5 1
Nickel ND ug/L 12/23/16 21:22 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:15 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:15 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:15 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:15 7440-31-512/17/16 01:00100 2.5 1
Vanadium 6.8J ug/L 12/23/16 06:15 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:15 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/20/16 05:49 7439-97-612/17/16 04:300.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/23/16 11:30 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/23/16 11:30 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/23/16 11:30 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/23/16 11:30 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/23/16 11:30 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/23/16 11:30 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/23/16 11:30 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/23/16 11:30 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/23/16 11:30 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/23/16 11:30 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/23/16 11:30 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/23/16 11:30 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/23/16 11:30 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/23/16 11:30 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/23/16 11:30 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/23/16 11:30 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/23/16 11:30 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/23/16 11:30 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/23/16 11:30 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/23/16 11:30 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/23/16 11:30 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/23/16 11:30 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/23/16 11:30 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/23/16 11:30 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/23/16 11:30 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/23/16 11:30 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/23/16 11:30 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/23/16 11:30 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/23/16 11:30 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/23/16 11:30 84-66-212/20/16 17:286000 1.3 1
Dimethoate ND ug/L 12/23/16 11:30 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/23/16 11:30 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/23/16 11:30 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/23/16 11:30 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/23/16 11:30 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/23/16 11:30 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/23/16 11:30 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/23/16 11:30 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/23/16 11:30 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/23/16 11:30 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/23/16 11:30 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/23/16 11:30 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/23/16 11:30 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/23/16 11:30 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/23/16 11:30 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/23/16 11:30 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/23/16 11:30 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/23/16 11:30 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/23/16 11:30 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/23/16 11:30 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/23/16 11:30 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/23/16 11:30 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/23/16 11:30 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/23/16 11:30 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/23/16 11:30 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/23/16 11:30 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/23/16 11:30 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/23/16 11:30 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/23/16 11:30 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/23/16 11:30 91-80-512/20/16 17:28100 2.7 1
3-Methylcholanthrene ND ug/L 12/23/16 11:30 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/23/16 11:30 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/23/16 11:30 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/23/16 11:30 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/23/16 11:30 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/23/16 11:3012/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/23/16 11:30 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/23/16 11:30 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/23/16 11:30 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/23/16 11:30 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/23/16 11:30 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/23/16 11:30 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 8 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/23/16 11:30 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/23/16 11:30 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/23/16 11:30 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/23/16 11:30 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/23/16 11:30 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/23/16 11:30 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/23/16 11:30 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/23/16 11:30 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/23/16 11:30 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/23/16 11:30 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/23/16 11:30 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/23/16 11:30 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/23/16 11:30 126-68-112/20/16 17:2810.0 1.8 1
Parathion (Ethyl parathion)ND ug/L 12/23/16 11:30 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/23/16 11:30 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/23/16 11:30 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/23/16 11:30 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/23/16 11:30 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/23/16 11:30 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/23/16 11:3012/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/23/16 11:30 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/23/16 11:30 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/23/16 11:30 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/23/16 11:30 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/23/16 11:30 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/23/16 11:30 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/23/16 11:30 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/23/16 11:30 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/23/16 11:30 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/23/16 11:30 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/23/16 11:30 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/23/16 11:30 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)39 %12/23/16 11:30 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)37 %12/23/16 11:30 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)86 %12/23/16 11:30 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)18 %12/23/16 11:30 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)21 %12/23/16 11:30 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)60 %12/23/16 11:30 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 06:59 67-64-1100 10.0 1
Acetonitrile ND ug/L 12/16/16 06:59 75-05-855.0 2.2 1
Acrolein ND ug/L 12/16/16 06:59 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/16/16 06:59 107-13-1200 1.9 1
Allyl chloride ND ug/L 12/16/16 06:59 107-05-110.0 1.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/16/16 06:59 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 06:59 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 06:59 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 06:59 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 06:59 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 06:59 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 06:59 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 06:59 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/16/16 06:59 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 06:59 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 06:59 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 06:59 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/16/16 06:59 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 06:59 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 06:59 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 06:59 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 06:59 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 06:59 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/16/16 06:59 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/16/16 06:59 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 06:59 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/16/16 06:59 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/16/16 06:59 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/16/16 06:59 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 06:59 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/16/16 06:59 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 06:59 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 06:59 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/16/16 06:59 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/16/16 06:59 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/16/16 06:59 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 06:59 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 06:59 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 06:59 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/16/16 06:59 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/16/16 06:59 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/16/16 06:59 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 06:59 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/16/16 06:59 78-83-1100 35.0 1
Methacrylonitrile ND ug/L 12/16/16 06:59 126-98-7100 0.93 1
Methylene Chloride ND ug/L 12/16/16 06:59 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/16/16 06:59 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 06:59 108-10-1100 0.33 1
Naphthalene ND ug/L 12/16/16 06:59 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/16/16 06:59 107-12-0150 3.6 1
Styrene ND ug/L 12/16/16 06:59 100-42-51.0 0.26 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 46
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Sample: 1203-MW21 Lab ID: 92323296001 Collected: 12/13/16 12:45 Received: 12/14/16 10:24 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 06:59 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 06:59 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 06:59 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 06:59 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 06:59 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/16/16 06:59 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/16/16 06:59 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 06:59 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/16/16 06:59 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 06:59 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 06:59 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 06:59 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 06:59 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 06:59 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/16/16 06:59 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 06:59 17060-07-070-130 1
Toluene-d8 (S)99 %12/16/16 06:59 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 1190J ug/L 12/23/16 09:065000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/18/16 20:1625000 25000 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/16/16 13:30 18496-25-81000 100 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1340J ug/L 12/17/16 21:06 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1470 ug/L 12/29/16 16:14 16887-00-61000 500 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:36 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
340994
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1891549
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/20/16 05:170.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1891550LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 101 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1891551MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991014
1891552
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 102 75-125103 2 252.5ND 2.6 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Iron ug/L ND 300 12/23/16 05:1125.0
Lead ug/L ND 10.0 12/23/16 05:112.5
Manganese ug/L ND 50.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Iron ug/L 44805000 90 80-120
Lead ug/L 426500 85 80-120
Manganese ug/L 442500 88 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Iron ug/L 5000 80 75-12584 5 255000ND4010 4220
Lead ug/L 500 99 75-125103 3 25500ND497 514
Manganese ug/L 500 79 75-12584 6 25500ND395 419
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386 411
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341133
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892566
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/15/16 23:350.33
1,1,1-Trichloroethane ug/L ND 1.0 12/15/16 23:350.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/15/16 23:350.40
1,1,2-Trichloroethane ug/L ND 1.0 12/15/16 23:350.29
1,1-Dichloroethane ug/L ND 5.0 12/15/16 23:350.32
1,1-Dichloroethene ug/L ND 5.0 12/15/16 23:350.56
1,1-Dichloropropene ug/L ND 5.0 12/15/16 23:350.49
1,2,3-Trichloropropane ug/L ND 1.0 12/15/16 23:350.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/15/16 23:350.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/15/16 23:352.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/15/16 23:350.27
1,2-Dichlorobenzene ug/L ND 5.0 12/15/16 23:350.30
1,2-Dichloroethane ug/L ND 1.0 12/15/16 23:350.24
1,2-Dichloropropane ug/L ND 1.0 12/15/16 23:350.27
1,3-Dichlorobenzene ug/L ND 5.0 12/15/16 23:350.24
1,3-Dichloropropane ug/L ND 1.0 12/15/16 23:350.28
1,4-Dichlorobenzene ug/L ND 1.0 12/15/16 23:350.33
2,2-Dichloropropane ug/L ND 15.0 12/15/16 23:350.13
2-Butanone (MEK)ug/L ND 100 12/15/16 23:350.96
2-Hexanone ug/L ND 50.0 12/15/16 23:350.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/15/16 23:350.33
Acetone ug/L ND 100 12/15/16 23:3510.0
Acetonitrile ug/L ND 55.0 12/15/16 23:352.2
Acrolein ug/L ND 53.0 12/15/16 23:351.6
Acrylonitrile ug/L ND 200 12/15/16 23:351.9
Allyl chloride ug/L ND 10.0 12/15/16 23:351.5
Benzene ug/L ND 1.0 12/15/16 23:350.25
Bromochloromethane ug/L ND 3.0 12/15/16 23:350.17
Bromodichloromethane ug/L ND 1.0 12/15/16 23:350.18
Bromoform ug/L ND 3.0 12/15/16 23:350.26
Bromomethane ug/L ND 10.0 12/15/16 23:350.29
Carbon disulfide ug/L ND 100 12/15/16 23:351.2
Carbon tetrachloride ug/L ND 1.0 12/15/16 23:350.25
Chlorobenzene ug/L ND 3.0 12/15/16 23:350.23
Chloroethane ug/L ND 10.0 12/15/16 23:350.54
Chloroform ug/L ND 5.0 12/15/16 23:350.14
Chloromethane ug/L ND 1.0 12/15/16 23:350.11
Chloroprene ug/L ND 20.0 12/15/16 23:350.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:350.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:350.13
Dibromochloromethane ug/L ND 3.0 12/15/16 23:350.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892566
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/15/16 23:350.21
Dichlorodifluoromethane ug/L ND 5.0 12/15/16 23:350.21
Ethyl methacrylate ug/L ND 10.0 12/15/16 23:350.20
Ethylbenzene ug/L ND 1.0 12/15/16 23:350.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/15/16 23:350.71
Iodomethane ug/L ND 10.0 12/15/16 23:350.32
Isobutanol ug/L ND 100 12/15/16 23:3535.0
Methacrylonitrile ug/L ND 100 12/15/16 23:350.93
Methyl methacrylate ug/L ND 30.0 12/15/16 23:352.0
Methylene Chloride ug/L ND 1.0 12/15/16 23:350.97
Naphthalene ug/L ND 10.0 12/15/16 23:350.24
Propionitrile ug/L ND 150 12/15/16 23:353.6
Styrene ug/L ND 1.0 12/15/16 23:350.26
Tetrachloroethene ug/L ND 1.0 12/15/16 23:350.46
Tetrahydrofuran ug/L ND 10.0 12/15/16 23:353.1
Toluene ug/L ND 1.0 12/15/16 23:350.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/15/16 23:350.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/15/16 23:350.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/15/16 23:351.0
Trichloroethene ug/L ND 1.0 12/15/16 23:350.47
Trichlorofluoromethane ug/L ND 1.0 12/15/16 23:350.20
Vinyl acetate ug/L ND 50.0 12/15/16 23:350.35
Vinyl chloride ug/L ND 1.0 12/15/16 23:350.62
Xylene (Total)ug/L ND 5.0 12/15/16 23:350.66
1,2-Dichloroethane-d4 (S)%101 70-130 12/15/16 23:35
4-Bromofluorobenzene (S)%95 70-130 12/15/16 23:35
Toluene-d8 (S)%101 70-130 12/15/16 23:35
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.550 93 80-125
1,1,1-Trichloroethane ug/L 48.950 98 71-129
1,1,2,2-Tetrachloroethane ug/L 47.750 95 79-124
1,1,2-Trichloroethane ug/L 48.650 97 85-125
1,1-Dichloroethane ug/L 51.750 103 73-126
1,1-Dichloroethene ug/L 54.350 109 66-135
1,1-Dichloropropene ug/L 52.950 106 74-135
1,2,3-Trichloropropane ug/L 46.150 92 75-130
1,2,4-Trichlorobenzene ug/L 48.850 98 75-134
1,2-Dibromo-3-chloropropane ug/L 46.450 93 71-133
1,2-Dibromoethane (EDB)ug/L 46.550 93 83-124
1,2-Dichlorobenzene ug/L 47.950 96 80-133
1,2-Dichloroethane ug/L 46.250 92 67-128
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
1,2-Dichloropropane ug/L 50.750 101 75-132
1,3-Dichlorobenzene ug/L 47.150 94 77-130
1,3-Dichloropropane ug/L 49.650 99 76-131
1,4-Dichlorobenzene ug/L 46.650 93 78-130
2,2-Dichloropropane ug/L 48.250 96 40-160
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 101100 101 68-143
4-Methyl-2-pentanone (MIBK)ug/L 101100 101 72-135
Acetone ug/L 99.3J100 99 48-146
Acetonitrile ug/L 560500 112 62-150
Acrolein ug/L 327250 131 24-160
Acrylonitrile ug/L 280250 112 40-160
Allyl chloride ug/L 52.650 105 66-137
Benzene ug/L 50.450 101 80-125
Bromochloromethane ug/L 50.950 102 71-125
Bromodichloromethane ug/L 48.150 96 78-124
Bromoform ug/L 44.050 88 71-128
Bromomethane ug/L 43.350 87 40-160
Carbon disulfide ug/L 58.6J50 117 50-160
Carbon tetrachloride ug/L 44.950 90 69-131
Chlorobenzene ug/L 47.550 95 81-122
Chloroethane ug/L 52.950 106 39-148
Chloroform ug/L 49.050 98 73-127
Chloromethane ug/L 52.350 105 44-146
Chloroprene ug/L 50.850 102 75-145
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 49.150 98 72-132
Dibromochloromethane ug/L 47.050 94 78-125
Dibromomethane ug/L 45.150 90 82-120
Dichlorodifluoromethane ug/L 45.150 90 34-157
Ethyl methacrylate ug/L 51.850 104 82-121
Ethylbenzene ug/L 47.650 95 79-121
Hexachloro-1,3-butadiene ug/L 50.050 100 72-131
Iodomethane ug/L 100100 100 39-154
Isobutanol ug/L 9871000 99 34-160
Methacrylonitrile ug/L 519500 104 74-134
Methyl methacrylate ug/L 51.550 103 84-124
Methylene Chloride ug/L 51.650 103 64-133
Naphthalene ug/L 47.750 95 73-133
Propionitrile ug/L 535500 107 73-140
Styrene ug/L 48.350 97 84-126
Tetrachloroethene ug/L 42.750 85 78-122
Tetrahydrofuran ug/L 564500 113 69-148
Toluene ug/L 48.450 97 80-121
trans-1,2-Dichloroethene ug/L 54.150 108 71-127
trans-1,3-Dichloropropene ug/L 49.050 98 69-141
trans-1,4-Dichloro-2-butene ug/L 45.7J50 91 40-160
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892567LABORATORY CONTROL SAMPLE:
LCSSpike
Trichloroethene ug/L 46.250 92 78-122
Trichlorofluoromethane ug/L 52.950 106 53-137
Vinyl acetate ug/L 109100 109 40-160
Vinyl chloride ug/L 44.450 89 58-137
Xylene (Total)ug/L 142150 95 81-126
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892568MATRIX SPIKE SAMPLE:
MSSpike
Result
92323289008
1,1,1,2-Tetrachloroethane ug/L 14.220 71 70-130ND
1,1,1-Trichloroethane ug/L 15.720 79 70-130ND
1,1,2,2-Tetrachloroethane ug/L 14.620 73 70-130ND
1,1,2-Trichloroethane ug/L 15.120 76 70-130ND
1,1-Dichloroethane ug/L 16.420 82 70-130ND
1,1-Dichloroethene ug/L 18.020 90 70-166ND
1,1-Dichloropropene ug/L 17.220 86 70-130ND
1,2,3-Trichloropropane ug/L 13.920 70 70-130ND
1,2,4-Trichlorobenzene ug/L 13.920 70 70-130ND
1,2-Dibromo-3-chloropropane ug/L 14.020 70 70-130ND
1,2-Dibromoethane (EDB)ug/L 14.220 71 70-130ND
1,2-Dichlorobenzene ug/L 14.720 74 70-130ND
1,2-Dichloroethane ug/L 15.020 75 70-130ND
1,2-Dichloropropane ug/L 16.320 82 70-130ND
1,3-Dichlorobenzene ug/L 14.820 74 70-130ND
1,3-Dichloropropane ug/L 15.220 76 70-130ND
1,4-Dichlorobenzene ug/L 14.820 74 70-130ND
2,2-Dichloropropane ug/L 14.0J20 70 70-130ND
2-Butanone (MEK)ug/L 32.2J40 80 70-130ND
2-Hexanone ug/L 30.3J40 76 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 30.6J40 77 70-130ND
Acetone ug/L 28.7J40 72 70-130ND
Acetonitrile ug/L 178200 89 70-130ND
Acrolein ug/L 88.0100 88 70-130ND
Acrylonitrile ug/L 86.0J100 86 70-130ND
Allyl chloride ug/L 16.620 83 70-130ND
Benzene ug/L 16.120 81 70-148ND
Bromochloromethane ug/L 15.720 78 70-130ND
Bromodichloromethane ug/L 15.220 76 70-130ND
Bromoform ug/L 13.2 M12066 70-130ND
Bromomethane ug/L 14.220 71 70-130ND
Carbon disulfide ug/L 19.4J20 97 70-130ND
Carbon tetrachloride ug/L 15.320 77 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1892568MATRIX SPIKE SAMPLE:
MSSpike
Result
92323289008
Chlorobenzene ug/L 15.220 76 70-146ND
Chloroethane ug/L 18.120 90 70-130ND
Chloroform ug/L 16.420 82 70-130ND
Chloromethane ug/L 17.120 86 70-130ND
Chloroprene ug/L 16.7J20 83 70-130ND
cis-1,2-Dichloroethene ug/L 16.820 84 70-130ND
cis-1,3-Dichloropropene ug/L 14.220 71 70-130ND
Dibromochloromethane ug/L 14.020 70 70-130ND
Dibromomethane ug/L 14.420 72 70-130ND
Dichlorodifluoromethane ug/L 16.120 81 70-130ND
Ethyl methacrylate ug/L 15.120 75 70-130ND
Ethylbenzene ug/L 15.420 77 70-130ND
Hexachloro-1,3-butadiene ug/L 14.720 73 70-130ND
Iodomethane ug/L 29.340 73 70-130ND
Isobutanol ug/L 282400 70 70-130ND
Methacrylonitrile ug/L 164200 82 70-130ND
Methyl methacrylate ug/L 15.0J20 75 70-130ND
Methylene Chloride ug/L 15.720 78 70-130ND
Naphthalene ug/L 13.1 M12065 70-130ND
Propionitrile ug/L 168200 84 70-130ND
Styrene ug/L 14.720 73 70-130ND
Tetrachloroethene ug/L 14.120 71 70-130ND
Tetrahydrofuran ug/L 173200 87 70-130ND
Toluene ug/L 15.720 78 70-155ND
trans-1,2-Dichloroethene ug/L 17.520 87 70-130ND
trans-1,3-Dichloropropene ug/L 14.020 70 70-130ND
trans-1,4-Dichloro-2-butene ug/L 11.3J M12056 70-130ND
Trichloroethene ug/L 15.320 76 69-151ND
Trichlorofluoromethane ug/L 18.120 90 70-130ND
Vinyl acetate ug/L 24.6J M14061 70-130ND
Vinyl chloride ug/L 15.420 77 70-130ND
1,2-Dichloroethane-d4 (S)%97 70-130
4-Bromofluorobenzene (S)%95 70-130
Toluene-d8 (S)%98 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L ND 30ND
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L ND 30ND
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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Huntersville, NC 28078
[phone]
Page 20 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323289009
1892569SAMPLE DUPLICATE:
Tetrachloroethene ug/L ND 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L ND 30ND
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%104 2101
4-Bromofluorobenzene (S)%95 095
Toluene-d8 (S)%101 1100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341110
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892410
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDE ug/L ND 0.10 12/16/16 12:470.050
4,4'-DDT ug/L ND 0.10 12/16/16 12:470.050
Aldrin ug/L ND 0.050 12/16/16 12:470.050
alpha-BHC ug/L ND 0.050 12/16/16 12:470.050
beta-BHC ug/L ND 0.050 12/16/16 12:470.050
Chlordane (Technical)ug/L ND 0.50 12/16/16 12:470.20
delta-BHC ug/L ND 0.050 12/16/16 12:470.050
Dieldrin ug/L ND 0.075 12/16/16 12:470.050
Endosulfan I ug/L ND 0.10 12/16/16 12:470.050
Endosulfan II ug/L ND 0.10 12/16/16 12:470.050
Endosulfan sulfate ug/L ND 0.10 12/16/16 12:470.050
Endrin ug/L ND 0.10 12/16/16 12:470.050
Endrin aldehyde ug/L ND 0.10 12/16/16 12:470.050
gamma-BHC (Lindane)ug/L ND 0.050 12/16/16 12:470.050
Heptachlor ug/L ND 0.050 12/16/16 12:470.050
Heptachlor epoxide ug/L ND 0.075 12/16/16 12:470.050
Methoxychlor ug/L ND 1.0 12/16/16 12:470.15
Toxaphene ug/L ND 1.5 12/16/16 12:470.20
Decachlorobiphenyl (S)%108 20-130 12/16/16 12:47
Tetrachloro-m-xylene (S)%97 20-130 12/16/16 12:47
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.25.25 99 20-150
4,4'-DDE ug/L 0.23.25 92 20-150
4,4'-DDT ug/L 0.25.25 99 20-150
Aldrin ug/L 0.19.25 78 20-150
alpha-BHC ug/L 0.22.25 90 20-150
beta-BHC ug/L 0.24.25 96 20-150
delta-BHC ug/L 0.24.25 98 20-150
Dieldrin ug/L 0.24.25 96 20-150
Endosulfan I ug/L 0.25.25 102 20-150
Endosulfan II ug/L 0.26.25 107 20-150
Endosulfan sulfate ug/L 0.27.25 109 20-150
Endrin ug/L 0.27.25 108 20-150
Endrin aldehyde ug/L 0.24.25 96 20-150
gamma-BHC (Lindane)ug/L 0.23.25 91 20-150
Heptachlor ug/L 0.20.25 82 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892411LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.23.25 94 20-150
Methoxychlor ug/L 0.87J.74 117 20-150
Decachlorobiphenyl (S)%99 20-130
Tetrachloro-m-xylene (S)%89 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892412MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1892413
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 92 20-15087 6 30.5ND 0.46 0.43
4,4'-DDE ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
4,4'-DDT ug/L .5 93 20-15086 8 30.5ND 0.46 0.42
Aldrin ug/L .5 80 20-15083 4 30.5ND 0.39 0.41
alpha-BHC ug/L .5 88 20-15086 2 30.5ND 0.43 0.42
beta-BHC ug/L .5 96 20-15092 4 30.5ND 0.48 0.46
delta-BHC ug/L .5 102 20-15098 5 30.5ND 0.51 0.48
Dieldrin ug/L .5 89 20-15085 5 30.5ND 0.44 0.42
Endosulfan I ug/L .5 90 20-15083 8 30.5ND 0.45 0.41
Endosulfan II ug/L .5 98 20-15095 4 30.5ND 0.49 0.47
Endosulfan sulfate ug/L .5 101 20-15096 5 30.5ND 0.50 0.48
Endrin ug/L .5 95 20-15090 5 30.5ND 0.47 0.45
Endrin aldehyde ug/L .5 82 20-15082 0 30.5ND 0.41 0.41
gamma-BHC (Lindane)ug/L .5 92 20-15088 4 30.5ND 0.45 0.44
Heptachlor ug/L .5 84 20-15082 2 30.5ND 0.42 0.41
Heptachlor epoxide ug/L .5 93 20-15089 5 30.5ND 0.46 0.44
Methoxychlor ug/L 1.5 105 20-15098 7 301.5ND 1.6J 1.5J
Decachlorobiphenyl (S)%45 20-13045
Tetrachloro-m-xylene (S)%84 20-13085
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341274
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893343
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/19/16 13:170.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/19/16 13:170.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/19/16 13:170.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/19/16 13:170.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/19/16 13:170.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/19/16 13:170.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/19/16 13:170.50
Decachlorobiphenyl (S)%92 10-132 12/19/16 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893344LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1893345
PCB-1016 (Aroclor 1016)ug/L 4.85 95 50-150904.5 6 30
PCB-1260 (Aroclor 1260)ug/L 5.55 111 50-1501035.1 8 30
Decachlorobiphenyl (S)%82 10-13279
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339306
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1820541
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/21/16 10:550.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/21/16 10:550.049
2,4-D ug/L ND 0.94 12/21/16 10:550.22
Dinoseb ug/L ND 0.19 12/21/16 10:550.057
2,4-DCAA (S)%86 39-139 12/21/16 10:55
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1820542LABORATORY CONTROL SAMPLE:
LCSSpike
2,4,5-T ug/L 1.31.2 106 37-133
2,4,5-TP (Silvex)ug/L 1.01.2 87 53-134
2,4-D ug/L 6.16 102 35-124
Dinoseb ug/L 0.971.2 81 13-116
2,4-DCAA (S)%87 39-139
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1820630MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991001
1820631
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
2,4,5-T ug/L 1.2 118 37-133114 3 401.2ND 1.4 1.4
2,4,5-TP (Silvex)ug/L 1.2 99 53-13495 3 401.2ND 1.2 1.1
2,4-D ug/L 6 114 35-124111 1 406ND6.8 6.7
Dinoseb ug/L 1.2 89 13-11685 4 401.2ND 1.1 1.0
2,4-DCAA (S)%94 39-13993 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 25 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341825
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/22/16 10:331.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/22/16 10:331.1
1,3-Dinitrobenzene ug/L ND 20.0 12/22/16 10:331.5
1,4-Naphthoquinone ug/L ND 10.0 12/22/16 10:331.8
1-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.96
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/22/16 10:332.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/22/16 10:332.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/22/16 10:331.9
2,4-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.7
2,4-Dimethylphenol ug/L ND 10.0 12/22/16 10:332.2
2,4-Dinitrophenol ug/L ND 50.0 12/22/16 10:336.5
2,4-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.2
2,6-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.8
2,6-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.7
2-Acetylaminofluorene ug/L ND 20.0 12/22/16 10:330.84
2-Chloronaphthalene ug/L ND 10.0 12/22/16 10:332.2
2-Chlorophenol ug/L ND 10.0 12/22/16 10:331.5
2-Methylnaphthalene ug/L ND 10.0 12/22/16 10:330.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/22/16 10:331.7
2-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.98
2-Nitroaniline ug/L ND 50.0 12/22/16 10:332.8
2-Nitrophenol ug/L ND 10.0 12/22/16 10:331.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/22/16 10:331.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/22/16 10:331.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/22/16 10:332.1
3-Methylcholanthrene ug/L ND 10.0 12/22/16 10:330.82
3-Nitroaniline ug/L ND 50.0 12/22/16 10:332.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/22/16 10:331.7
4-Aminobiphenyl ug/L ND 20.0 12/22/16 10:330.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/22/16 10:331.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/22/16 10:334.2
4-Chloroaniline ug/L ND 20.0 12/22/16 10:333.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/22/16 10:332.1
4-Nitroaniline ug/L ND 20.0 12/22/16 10:332.5
4-Nitrophenol ug/L ND 50.0 12/22/16 10:335.8
5-Nitro-o-toluidine ug/L ND 10.0 12/22/16 10:331.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/22/16 10:330.77
Acenaphthene ug/L ND 10.0 12/22/16 10:330.25
Acenaphthylene ug/L ND 10.0 12/22/16 10:330.21
Acetophenone ug/L ND 10.0 12/22/16 10:332.0
Anthracene ug/L ND 10.0 12/22/16 10:330.14
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Benzo(a)anthracene ug/L ND 10.0 12/22/16 10:330.33
Benzo(a)pyrene ug/L ND 10.0 12/22/16 10:330.30
Benzo(b)fluoranthene ug/L ND 10.0 12/22/16 10:330.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/22/16 10:330.38
Benzo(k)fluoranthene ug/L ND 10.0 12/22/16 10:330.43
Benzyl alcohol ug/L ND 20.0 12/22/16 10:333.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/22/16 10:331.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/22/16 10:331.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/22/16 10:330.85
Butylbenzylphthalate ug/L ND 10.0 12/22/16 10:330.75
Chlorobenzilate ug/L ND 10.0 12/22/16 10:330.72
Chrysene ug/L ND 10.0 12/22/16 10:330.21
Di-n-butylphthalate ug/L ND 10.0 12/22/16 10:331.1
Di-n-octylphthalate ug/L ND 10.0 12/22/16 10:330.86
Diallate ug/L ND 10.0 12/22/16 10:331.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/22/16 10:330.55
Dibenzofuran ug/L ND 10.0 12/22/16 10:331.8
Diethylphthalate ug/L ND 6000 12/22/16 10:331.3
Dimethoate ug/L ND 20.0 12/22/16 10:330.92
Dimethylphthalate ug/L ND 10.0 12/22/16 10:331.5
Diphenylamine ug/L ND 10.0 12/22/16 10:331.3
Disulfoton ug/L ND 10.0 12/22/16 10:331.4
Ethyl methanesulfonate ug/L ND 20.0 12/22/16 10:331.8
Famphur ug/L ND 20.0 12/22/16 10:331.7
Fluoranthene ug/L ND 10.0 12/22/16 10:330.21
Fluorene ug/L ND 10.0 12/22/16 10:330.21
Hexachlorobenzene ug/L ND 10.0 12/22/16 10:331.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/22/16 10:331.8
Hexachloroethane ug/L ND 10.0 12/22/16 10:331.5
Hexachloropropene ug/L ND 10.0 12/22/16 10:331.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/22/16 10:330.29
Isodrin ug/L ND 20.0 12/22/16 10:332.0
Isophorone ug/L ND 10.0 12/22/16 10:331.8
Isosafrole ug/L ND 10.0 12/22/16 10:331.8
Kepone ug/L ND 20.0 12/22/16 10:333.1
Methapyrilene ug/L ND 100 12/22/16 10:332.7
Methyl methanesulfonate ug/L ND 10.0 12/22/16 10:331.3
Methyl parathion ug/L ND 10.0 12/22/16 10:331.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/22/16 10:332.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/22/16 10:332.1
N-Nitrosodiethylamine ug/L ND 20.0 12/22/16 10:331.8
N-Nitrosodimethylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/22/16 10:331.8
N-Nitrosopiperidine ug/L ND 20.0 12/22/16 10:331.9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896583
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
N-Nitrosopyrrolidine ug/L ND 10.0 12/22/16 10:332.5
Nitrobenzene ug/L ND 10.0 12/22/16 10:331.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/22/16 10:331.8
O-Toluidine ug/L ND 10.0 12/22/16 10:331.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/22/16 10:330.35
p-Phenylenediamine ug/L ND 10.0 12/22/16 10:330.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/22/16 10:331.1
Pentachlorobenzene ug/L ND 10.0 12/22/16 10:332.0
Pentachloronitrobenzene ug/L ND 20.0 12/22/16 10:331.0
Pentachlorophenol ug/L ND 25.0 12/22/16 10:332.3
Phenacetin ug/L ND 20.0 12/22/16 10:330.97
Phenanthrene ug/L ND 10.0 12/22/16 10:330.22
Phenol ug/L ND 10.0 12/22/16 10:331.7
Phorate ug/L ND 10.0 12/22/16 10:331.1
Pronamide ug/L ND 10.0 12/22/16 10:330.97
Pyrene ug/L ND 10.0 12/22/16 10:330.19
Safrole ug/L ND 10.0 12/22/16 10:331.5
Thionazin ug/L ND 20.0 12/22/16 10:331.2
2,4,6-Tribromophenol (S)%70 27-110 12/22/16 10:33
2-Fluorobiphenyl (S)%54 27-110 12/22/16 10:33
2-Fluorophenol (S)%26 12-110 12/22/16 10:33
Nitrobenzene-d5 (S)%50 21-110 12/22/16 10:33
Phenol-d6 (S)%23 10-110 12/22/16 10:33
Terphenyl-d14 (S)%71 31-107 12/22/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 33.650 67 16-129
1,3,5-Trinitrobenzene ug/L 43.250 86 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 37.450 75 31-120
1-Naphthalenamine ug/L 24.050 48 37-126
2,3,4,6-Tetrachlorophenol ug/L 56.550 113 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 41.050 82 42-120
2,4-Dichlorophenol ug/L 38.450 77 30-120
2,4-Dimethylphenol ug/L 38.750 77 29-111
2,4-Dinitrophenol ug/L 123250 49 19-132
2,4-Dinitrotoluene ug/L 42.350 85 58-128
2,6-Dichlorophenol ug/L 42.550 85 54-128
2,6-Dinitrotoluene ug/L 42.850 86 54-129
2-Acetylaminofluorene ug/L 43.750 87 81-160
2-Chloronaphthalene ug/L 41.150 82 43-117
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
2-Chlorophenol ug/L 36.050 72 37-120
2-Methylnaphthalene ug/L 37.550 75 33-120
2-Methylphenol(o-Cresol)ug/L 25.350 51 31-120
2-Naphthalenamine ug/L 36.650 73 41-136
2-Nitroaniline ug/L 68.5100 69 48-121
2-Nitrophenol ug/L 37.350 75 25-116
3&4-Methylphenol(m&p Cresol)ug/L 38.850 78 23-120
3,3'-Dichlorobenzidine ug/L 86.0250 34 10-154
3,3'-Dimethylbenzidine ug/L 62.6100 63 10-157
3-Methylcholanthrene ug/L 47.750 95 65-130
3-Nitroaniline ug/L 82.5100 83 43-115
4,6-Dinitro-2-methylphenol ug/L 89.5100 89 44-124
4-Aminobiphenyl ug/L 33.650 67 21-125
4-Bromophenylphenyl ether ug/L 37.950 76 34-113
4-Chloro-3-methylphenol ug/L 73.5100 73 31-110
4-Chloroaniline ug/L 67.3100 67 20-120
4-Chlorophenylphenyl ether ug/L 37.750 75 34-116
4-Nitroaniline ug/L 89.4100 89 46-128
4-Nitrophenol ug/L 76.4250 31 11-120
5-Nitro-o-toluidine ug/L 42.150 84 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.250 94 47-124
Acenaphthene ug/L 39.450 79 48-114
Acenaphthylene ug/L 40.750 81 48-112
Acetophenone ug/L 32.650 65 24-120
Anthracene ug/L 41.650 83 57-118
Benzo(a)anthracene ug/L 41.350 83 56-121
Benzo(a)pyrene ug/L 45.750 91 55-127
Benzo(b)fluoranthene ug/L 44.150 88 53-128
Benzo(g,h,i)perylene ug/L 45.950 92 54-125
Benzo(k)fluoranthene ug/L 46.850 94 51-123
Benzyl alcohol ug/L 57.5100 57 27-120
bis(2-Chloroethoxy)methane ug/L 35.650 71 32-120
bis(2-Chloroethyl) ether ug/L 36.450 73 33-111
bis(2-Ethylhexyl)phthalate ug/L 48.250 96 50-145
Butylbenzylphthalate ug/L 47.650 95 54-138
Chlorobenzilate ug/L 45.250 90 65-132
Chrysene ug/L 41.350 83 58-127
Di-n-butylphthalate ug/L 47.250 94 56-125
Di-n-octylphthalate ug/L 49.350 99 50-134
Diallate ug/L 48.250 96 47-123
Dibenz(a,h)anthracene ug/L 47.150 94 53-129
Dibenzofuran ug/L 39.650 79 45-120
Diethylphthalate ug/L 43.4J50 87 53-120
Dimethoate ug/L 50.850 102 57-139
Dimethylphthalate ug/L 41.150 82 55-116
Diphenylamine ug/L 42.350 85 42-120
Disulfoton ug/L 50.050 100 49-156
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Ethyl methanesulfonate ug/L 38.250 76 43-120
Famphur ug/L 45.6100 46 40-160
Fluoranthene ug/L 45.450 91 57-125
Fluorene ug/L 41.450 83 53-118
Hexachlorobenzene ug/L 39.850 80 49-116
Hexachlorocyclopentadiene ug/L 34.350 69 26-158
Hexachloroethane ug/L 29.350 59 30-114
Hexachloropropene ug/L 33.350 67 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.650 95 55-128
Isodrin ug/L 46.450 93 68-129
Isophorone ug/L 35.550 71 31-118
Isosafrole ug/L 32.650 65 48-107
Kepone ug/L 45.7100 46 10-124
Methapyrilene ug/L 51.7J50 103 40-160
Methyl methanesulfonate ug/L 25.350 51 25-114
Methyl parathion ug/L 51.750 103 58-137
N-Nitroso-di-n-butylamine ug/L 30.850 62 36-115
N-Nitroso-di-n-propylamine ug/L 38.050 76 32-119
N-Nitrosodiethylamine ug/L 38.250 76 47-115
N-Nitrosodimethylamine ug/L 24.850 50 13-120
N-Nitrosodiphenylamine ug/L 42.350 85 43-120
N-Nitrosomethylethylamine ug/L 33.450 67 39-120
N-Nitrosopiperidine ug/L 43.950 88 43-113
N-Nitrosopyrrolidine ug/L 35.650 71 32-110
Nitrobenzene ug/L 33.950 68 33-110
O,O,O-Triethylphosphorothioate ug/L 37.850 76 51-127
O-Toluidine ug/L 33.650 67 27-120
P-Dimethylaminoazobenzene ug/L 19.3100 19 10-120
p-Phenylenediamine ug/L 45.950 92 72-143
Parathion (Ethyl parathion)ug/L 50.750 101 56-140
Pentachlorobenzene ug/L 35.650 71 30-137
Pentachloronitrobenzene ug/L 49.950 100 70-124
Pentachlorophenol ug/L 89.3250 36 10-137
Phenacetin ug/L 46.650 93 60-130
Phenanthrene ug/L 41.150 82 57-117
Phenol ug/L 17.350 35 10-120
Phorate ug/L 51.650 103 55-126
Pronamide ug/L 51.550 103 75-124
Pyrene ug/L 39.350 79 55-122
Safrole ug/L 39.450 79 41-120
Thionazin ug/L 40.050 80 63-137
2,4,6-Tribromophenol (S)%43 27-110
2-Fluorobiphenyl (S)%36 27-110
2-Fluorophenol (S)%20 12-110
Nitrobenzene-d5 (S)%35 21-110
Phenol-d6 (S)%14 10-110
Terphenyl-d14 (S)%38 31-107
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 30 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
1,2,4,5-Tetrachlorobenzene ug/L 33.050 66 50-150ND
1,3,5-Trinitrobenzene ug/L 48.950 98 50-150ND
1,3-Dinitrobenzene ug/L 40.450 81 50-150ND
1,4-Naphthoquinone ug/L 33.950 68 50-150ND
1-Naphthalenamine ug/L 23.3 M15047 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 38.450 77 50-150ND
2,4,5-Trichlorophenol ug/L 27.650 55 19-105ND
2,4,6-Trichlorophenol ug/L 25.050 50 13-108ND
2,4-Dichlorophenol ug/L 34.450 69 29-111ND
2,4-Dimethylphenol ug/L 36.750 73 21-103ND
2,4-Dinitrophenol ug/L 28.1J250 11 10-109ND
2,4-Dinitrotoluene ug/L 37.650 75 27-104ND
2,6-Dichlorophenol ug/L 33.350 67 50-150ND
2,6-Dinitrotoluene ug/L 41.750 83 28-101ND
2-Acetylaminofluorene ug/L 40.550 81 50-150ND
2-Chloronaphthalene ug/L 43.950 88 14-102ND
2-Chlorophenol ug/L 31.250 62 16-110ND
2-Methylnaphthalene ug/L 39.850 80 13-110ND
2-Methylphenol(o-Cresol)ug/L 22.650 45 19-110ND
2-Naphthalenamine ug/L 30.350 61 50-150ND
2-Nitroaniline ug/L 59.8100 60 26-103ND
2-Nitrophenol ug/L 33.350 67 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 47.650 95 20-110ND
3,3'-Dichlorobenzidine ug/L 82.5250 33 25-112ND
3,3'-Dimethylbenzidine ug/L 53.4100 53 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 75.3100 75 29-110ND
4,6-Dinitro-2-methylphenol ug/L 51.8100 52 10-117ND
4-Aminobiphenyl ug/L 34.950 70 50-150ND
4-Bromophenylphenyl ether ug/L 40.950 82 20-105ND
4-Chloro-3-methylphenol ug/L 64.1100 64 22-110ND
4-Chloroaniline ug/L 66.4100 66 20-100ND
4-Chlorophenylphenyl ether ug/L 41.850 84 19-102ND
4-Nitroaniline ug/L 99.6100 100 29-110ND
4-Nitrophenol ug/L 36.2J250 14 10-110ND
5-Nitro-o-toluidine ug/L 42.950 86 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 43.750 87 50-150ND
Acenaphthene ug/L 38.350 77 17-100ND
Acenaphthylene ug/L 39.650 79 21-100ND
Acetophenone ug/L 30.850 62 50-150ND
Anthracene ug/L 40.550 81 24-109ND
Benzo(a)anthracene ug/L 39.450 79 22-117ND
Benzo(a)pyrene ug/L 42.050 84 23-104ND
Benzo(b)fluoranthene ug/L 41.050 82 23-103ND
Benzo(g,h,i)perylene ug/L 42.350 85 18-111ND
Benzo(k)fluoranthene ug/L 42.750 85 22-113ND
Benzyl alcohol ug/L 48.7100 49 19-101ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 31 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
bis(2-Chloroethoxy)methane ug/L 32.350 65 22-110ND
bis(2-Chloroethyl) ether ug/L 33.950 68 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 42.550 85 23-102ND
Butylbenzylphthalate ug/L 41.950 84 25-110ND
Chlorobenzilate ug/L 42.450 84 50-150ND
Chrysene ug/L 39.850 80 23-115ND
Di-n-butylphthalate ug/L 44.150 88 26-110ND
Di-n-octylphthalate ug/L 43.850 88 22-110ND
Diallate ug/L 46.450 93 50-150ND
Dibenz(a,h)anthracene ug/L 41.250 82 21-112ND
Dibenzofuran ug/L 40.450 81 19-102ND
Diethylphthalate ug/L 39.2J50 78 29-110ND
Dimethoate ug/L 50.950 102 50-150ND
Dimethylphthalate ug/L 42.950 86 27-110ND
Diphenylamine ug/L 49.550 99 50-150ND
Disulfoton ug/L 41.050 82 50-150ND
Ethyl methanesulfonate ug/L 34.450 69 50-150ND
Famphur ug/L 51.1100 51 50-150ND
Fluoranthene ug/L 45.150 90 23-112ND
Fluorene ug/L 46.050 92 22-104ND
Hexachlorobenzene ug/L 42.750 85 21-116ND
Hexachlorocyclopentadiene ug/L 33.950 68 10-110ND
Hexachloroethane ug/L 29.550 59 10-110ND
Hexachloropropene ug/L 37.550 75 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 43.150 86 20-113ND
Isodrin ug/L 45.950 92 50-150ND
Isophorone ug/L 31.950 64 50-150ND
Isosafrole ug/L 31.950 64 50-150ND
Kepone ug/L 60.3100 60 50-150ND
Methapyrilene ug/L 46.8J50 94 50-150ND
Methyl methanesulfonate ug/L 26.950 54 50-150ND
Methyl parathion ug/L 46.350 93 50-150ND
N-Nitroso-di-n-butylamine ug/L 30.250 60 50-150ND
N-Nitroso-di-n-propylamine ug/L 32.750 65 21-105ND
N-Nitrosodiethylamine ug/L 43.250 86 50-150ND
N-Nitrosodimethylamine ug/L 23.050 46 10-110ND
N-Nitrosodiphenylamine ug/L 49.550 99 23-107ND
N-Nitrosomethylethylamine ug/L 31.950 64 50-150ND
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.050 62 50-150ND
Nitrobenzene ug/L 28.250 56 20-110ND
O,O,O-Triethylphosphorothioate ug/L 39.250 78 50-150ND
O-Toluidine ug/L 28.750 57 50-150ND
P-Dimethylaminoazobenzene ug/L 18.4 M110018 50-150ND
p-Phenylenediamine ug/L 43.850 88 50-150ND
Parathion (Ethyl parathion)ug/L 45.450 91 50-150ND
Pentachlorobenzene ug/L 34.750 69 50-150ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
Pentachloronitrobenzene ug/L 43.150 86 50-150ND
Pentachlorophenol ug/L 32.6250 13 10-118ND
Phenacetin ug/L 45.550 91 50-150ND
Phenanthrene ug/L 41.250 82 24-106ND
Phenol ug/L 14.750 29 12-110ND
Phorate ug/L 46.150 92 50-150ND
Pronamide ug/L 49.050 98 50-150ND
Pyrene ug/L 35.650 71 24-114ND
Safrole ug/L 40.950 82 50-150ND
Thionazin ug/L 42.550 85 50-150ND
2,4,6-Tribromophenol (S)%70 27-110
2-Fluorobiphenyl (S)%75 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%56 21-110
Phenol-d6 (S)%23 10-110
Terphenyl-d14 (S)%68 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 33 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 34 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%68 169
2-Fluorobiphenyl (S)%58 1165
2-Fluorophenol (S)%22 2227
Nitrobenzene-d5 (S)%51 654
Phenol-d6 (S)%15 1818
Terphenyl-d14 (S)%70 473
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 35 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342108
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898057
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/23/16 07:251000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898058LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4510050000 90 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898059MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323286001
1898060
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 95 80-12096 1 25500001090J48600 49300
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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Page 36 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341433
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894510
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/18/16 20:1025000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894511LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 230000250000 92 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323216029
1894512SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 344000 0 5343 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323257005
1894513SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 130000 1 5131000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341249
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893118
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/16/16 13:30100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893119LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 520J500 104 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893120MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323296001
1893121
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 96 80-12096 0 10500ND492J 491J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893122MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323316010
1893123
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L 500 92 80-12091 0 10500ND458J 457J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341402
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894399
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/17/16 17:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894400LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238003
1894402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011590-110110 2 102000026.5 mg/L 49500J 48400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1894404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 99 90-11094 5 10200002.1 mg/L 22000J 21000J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342770
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1901305
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 12/29/16 15:53500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1901306LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1970020000 98 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901307MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92322991013
1901308
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000013490-110136 0 101000066.5 mg/L 79900 80000
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901309MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1901310
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L 10000 98 90-110101 3 10100001.6 mg/L 11400 11700
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 40 of 46
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323296001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323296001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 41 of 46
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 42 of 46
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323296
BURKE CO. JOHNS R BACKGROUND
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323296001 341110 3412291203-MW21 EPA 3510 EPA 8081
92323296001 341274 3414911203-MW21 EPA 3510 EPA 8082
92323296001 339306 3398961203-MW21 EPA 8151 EPA 8151
92323296001 341173 3415711203-MW21 EPA 3010A EPA 6010
92323296001 340994 3413841203-MW21 EPA 7470 EPA 7470
92323296001 341825 3421661203-MW21 EPA 3510 EPA 8270
92323296001 3411331203-MW21 EPA 8260
92323296001 3421081203-MW21 SM 2320B
92323296001 3414331203-MW21 SM 2540C
92323296001 3412491203-MW21 SM 4500-S2D
92323296001 3414021203-MW21 EPA 300.0
92323296001 3427701203-MW21 SM 4500-Cl-E
92323296001 3425331203-MW21 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/03/2017 04:36 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 43 of 46
Page 44 of 46
Page 45 of 46
Page 46 of 46
#=CL#
January 04, 2017
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323610
92323610
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Johns R. Phase 1A GW
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Lab ID Sample ID Matrix Date Collected Date Received
92323610001 1203-MW20 Water 12/14/16 07:47 12/15/16 10:10
92323610002 1203-MW22S Water 12/14/16 12:30 12/15/16 10:10
92323610003 1203-MW38 Water 12/14/16 08:34 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323610001 1203-MW20 EPA 6010 17 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-ASER
SM 2540C 1 PASI-AMJS1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-AWRC
92323610002 1203-MW22S EPA 6010 17 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-ASER
SM 2540C 1 PASI-AMJS1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-AWRC
92323610003 1203-MW38 EPA 6010 17 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 51 PASI-CZDO
SM 2320B 1 PASI-ASER
SM 2540C 1 PASI-AMJS1
EPA 300.0 1 PASI-AAES2
SM 4500-Cl-E 1 PASI-AWRC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323610001 1203-MW20
Barium 123 ug/L 12/23/16 06:21100EPA 6010
Chromium 9.8J ug/L 12/23/16 06:2110.0EPA 6010
Cobalt 3.6J ug/L 12/23/16 06:2110.0EPA 6010
Copper 11.9 ug/L 12/23/16 06:2110.0EPA 6010
Iron 9700 ug/L 12/23/16 06:21300EPA 6010
Lead 5.1J ug/L 12/23/16 21:2810.0EPA 6010
Manganese 169 ug/L 12/23/16 06:2150.0EPA 6010
Nickel 6.8J ug/L 12/23/16 21:2850.0EPA 6010
Vanadium 13.9J ug/L 12/23/16 06:2125.0EPA 6010
Zinc 23.8 ug/L 12/23/16 06:2110.0EPA 6010
Alkalinity, Total as CaCO3 6190 ug/L 12/24/16 21:075000SM 2320B
Total Dissolved Solids 33000 ug/L 12/19/16 21:5325000SM 2540C
Sulfate 1530J ug/L 12/17/16 21:34250000EPA 300.0
Chloride 1460 ug/L 01/03/17 14:381000SM 4500-Cl-E
92323610002 1203-MW22S
Barium 56.6J ug/L 12/23/16 06:24100EPA 6010
Copper 2.8J ug/L 12/23/16 06:2410.0EPA 6010
Iron 2440 ug/L 12/23/16 06:24300EPA 6010
Manganese 33.0J ug/L 12/23/16 06:2450.0EPA 6010
Vanadium 3.3J ug/L 12/23/16 06:2425.0EPA 6010
Zinc 9.3J ug/L 12/23/16 06:2410.0EPA 6010
Alkalinity, Total as CaCO3 4100J ug/L 12/24/16 21:155000SM 2320B
Sulfate 1460J ug/L 12/17/16 21:43250000EPA 300.0
Chloride 1240 ug/L 01/03/17 14:391000SM 4500-Cl-E
92323610003 1203-MW38
Arsenic 3.2J ug/L 12/23/16 06:2810.0EPA 6010
Barium 92.8J ug/L 12/23/16 06:28100EPA 6010
Chromium 4.0J ug/L 12/23/16 06:2810.0EPA 6010
Copper 9.1J ug/L 12/23/16 06:2810.0EPA 6010
Iron 37400 ug/L 12/23/16 06:28300EPA 6010
Lead 6.2J ug/L 12/23/16 21:3410.0EPA 6010
Manganese 3380 ug/L 12/23/16 06:2850.0EPA 6010
Nickel 3.4J ug/L 12/23/16 21:3450.0EPA 6010
Zinc 9.5J ug/L 12/23/16 06:2810.0EPA 6010
Benzene 3.0 ug/L 12/16/16 22:381.0EPA 8260
Chlorobenzene 0.41J ug/L 12/16/16 22:383.0EPA 8260
1,4-Dichlorobenzene 8.3 ug/L 12/16/16 22:381.0EPA 8260
1,1-Dichloroethane 6.0 ug/L 12/16/16 22:385.0EPA 8260
1,2-Dichloroethane 0.63J ug/L 12/16/16 22:381.0EPA 8260
cis-1,2-Dichloroethene 12.7 ug/L 12/16/16 22:385.0EPA 8260
Trichloroethene 1.8 ug/L 12/16/16 22:381.0EPA 8260
Alkalinity, Total as CaCO3 294000 ug/L 12/24/16 21:245000SM 2320B
Total Dissolved Solids 366000 ug/L 12/19/16 21:5425000SM 2540C
Sulfate 6820J ug/L 12/17/16 21:52250000EPA 300.0
Chloride 4760 ug/L 01/03/17 14:401000SM 4500-Cl-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW20 Lab ID: 92323610001 Collected: 12/14/16 07:47 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:28 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:21 7440-38-212/17/16 01:0010.0 2.5 1
Barium 123 ug/L 12/23/16 06:21 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:21 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:28 7440-43-912/17/16 01:001.0 0.50 1
Chromium 9.8J ug/L 12/23/16 06:21 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt 3.6J ug/L 12/23/16 06:21 7440-48-412/17/16 01:0010.0 2.5 1
Copper 11.9 ug/L 12/23/16 06:21 7440-50-812/17/16 01:0010.0 2.5 1
Iron 9700 ug/L 12/23/16 06:21 7439-89-612/17/16 01:00300 25.0 1
Lead 5.1J ug/L 12/23/16 21:28 7439-92-112/17/16 01:0010.0 2.5 1
Manganese 169 ug/L 12/23/16 06:21 7439-96-512/17/16 01:0050.0 2.5 1
Nickel 6.8J ug/L 12/23/16 21:28 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:21 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:21 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:21 7440-28-012/17/16 01:005.5 5.0 1
Vanadium 13.9J ug/L 12/23/16 06:21 7440-62-212/17/16 01:0025.0 2.5 1
Zinc 23.8 ug/L 12/23/16 06:21 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 12:53 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 22:03 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/16/16 22:03 107-13-1200 1.9 1
Benzene ND ug/L 12/16/16 22:03 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 22:03 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 22:03 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 22:03 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 22:03 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 22:03 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 22:03 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 22:03 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/16/16 22:03 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 22:03 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 22:03 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 22:03 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 22:03 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 22:03 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 22:03 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 22:03 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 22:03 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/16/16 22:03 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 22:03 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 12/16/16 22:03 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/16/16 22:03 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 22:03 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW20 Lab ID: 92323610001 Collected: 12/14/16 07:47 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/16/16 22:03 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 22:03 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 22:03 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 22:03 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 22:03 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 22:03 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/16/16 22:03 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 22:03 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/16/16 22:03 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 22:03 108-10-1100 0.33 1
Styrene ND ug/L 12/16/16 22:03 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 22:03 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 22:03 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 22:03 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 22:03 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 22:03 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/16/16 22:03 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 22:03 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/16/16 22:03 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 22:03 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 22:03 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 22:03 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 22:03 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 22:03 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/16/16 22:03 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/16/16 22:03 17060-07-070-130 1
Toluene-d8 (S)99 %12/16/16 22:03 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 6190 ug/L 12/24/16 21:075000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 33000 ug/L 12/19/16 21:5325000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1530J ug/L 12/17/16 21:34 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1460 ug/L 01/03/17 14:38 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW22S Lab ID: 92323610002 Collected: 12/14/16 12:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:31 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:24 7440-38-212/17/16 01:0010.0 2.5 1
Barium 56.6J ug/L 12/23/16 06:24 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:24 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:31 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:24 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:24 7440-48-412/17/16 01:0010.0 2.5 1
Copper 2.8J ug/L 12/23/16 06:24 7440-50-812/17/16 01:0010.0 2.5 1
Iron 2440 ug/L 12/23/16 06:24 7439-89-612/17/16 01:00300 25.0 1
Lead ND ug/L 12/23/16 21:31 7439-92-112/17/16 01:0010.0 2.5 1
Manganese 33.0J ug/L 12/23/16 06:24 7439-96-512/17/16 01:0050.0 2.5 1
Nickel ND ug/L 12/23/16 21:31 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:24 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:24 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:24 7440-28-012/17/16 01:005.5 5.0 1
Vanadium 3.3J ug/L 12/23/16 06:24 7440-62-212/17/16 01:0025.0 2.5 1
Zinc 9.3J ug/L 12/23/16 06:24 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:00 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 22:20 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/16/16 22:20 107-13-1200 1.9 1
Benzene ND ug/L 12/16/16 22:20 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 22:20 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 22:20 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 22:20 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 22:20 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 22:20 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 22:20 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 22:20 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/16/16 22:20 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 22:20 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 22:20 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 22:20 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 22:20 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 22:20 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 22:20 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 22:20 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 22:20 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/16/16 22:20 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 22:20 110-57-6100 1.0 1
1,1-Dichloroethane ND ug/L 12/16/16 22:20 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/16/16 22:20 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 22:20 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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[phone]
Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW22S Lab ID: 92323610002 Collected: 12/14/16 12:30 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene ND ug/L 12/16/16 22:20 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 22:20 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 22:20 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 22:20 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 22:20 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 22:20 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/16/16 22:20 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 22:20 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/16/16 22:20 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 22:20 108-10-1100 0.33 1
Styrene ND ug/L 12/16/16 22:20 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 22:20 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 22:20 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 22:20 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 22:20 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 22:20 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/16/16 22:20 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 22:20 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/16/16 22:20 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 22:20 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 22:20 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 22:20 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 22:20 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 22:20 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/16/16 22:20 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/16/16 22:20 17060-07-070-130 1
Toluene-d8 (S)100 %12/16/16 22:20 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 4100J ug/L 12/24/16 21:155000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids ND ug/L 12/19/16 21:5425000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 1460J ug/L 12/17/16 21:43 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 1240 ug/L 01/03/17 14:39 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW38 Lab ID: 92323610003 Collected: 12/14/16 08:34 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:34 7440-36-012/17/16 01:006.0 3.8 1
Arsenic 3.2J ug/L 12/23/16 06:28 7440-38-212/17/16 01:0010.0 2.5 1
Barium 92.8J ug/L 12/23/16 06:28 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:28 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:34 7440-43-912/17/16 01:001.0 0.50 1
Chromium 4.0J ug/L 12/23/16 06:28 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:28 7440-48-412/17/16 01:0010.0 2.5 1
Copper 9.1J ug/L 12/23/16 06:28 7440-50-812/17/16 01:0010.0 2.5 1
Iron 37400 ug/L 12/23/16 06:28 7439-89-612/17/16 01:00300 25.0 1
Lead 6.2J ug/L 12/23/16 21:34 7439-92-112/17/16 01:0010.0 2.5 1
Manganese 3380 ug/L 12/23/16 06:28 7439-96-512/17/16 01:0050.0 2.5 1
Nickel 3.4J ug/L 12/23/16 21:34 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:28 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:28 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:28 7440-28-012/17/16 01:005.5 5.0 1
Vanadium ND ug/L 12/23/16 06:28 7440-62-212/17/16 01:0025.0 2.5 1
Zinc 9.5J ug/L 12/23/16 06:28 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:02 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/16/16 22:38 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/16/16 22:38 107-13-1200 1.9 1
Benzene 3.0 ug/L 12/16/16 22:38 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/16/16 22:38 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/16/16 22:38 75-27-41.0 0.18 1
Bromoform ND ug/L 12/16/16 22:38 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/16/16 22:38 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/16/16 22:38 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/16/16 22:38 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/16/16 22:38 56-23-51.0 0.25 1
Chlorobenzene 0.41J ug/L 12/16/16 22:38 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/16/16 22:38 75-00-310.0 0.54 1
Chloroform ND ug/L 12/16/16 22:38 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/16/16 22:38 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/16/16 22:38 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/16/16 22:38 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/16/16 22:38 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/16/16 22:38 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/16/16 22:38 95-50-15.0 0.30 1
1,4-Dichlorobenzene 8.3 ug/L 12/16/16 22:38 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/16/16 22:38 110-57-6100 1.0 1
1,1-Dichloroethane 6.0 ug/L 12/16/16 22:38 75-34-35.0 0.32 1
1,2-Dichloroethane 0.63J ug/L 12/16/16 22:38 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/16/16 22:38 75-35-45.0 0.56 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Sample: 1203-MW38 Lab ID: 92323610003 Collected: 12/14/16 08:34 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
cis-1,2-Dichloroethene 12.7 ug/L 12/16/16 22:38 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/16/16 22:38 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/16/16 22:38 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/16/16 22:38 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/16/16 22:38 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/16/16 22:38 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/16/16 22:38 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/16/16 22:38 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/16/16 22:38 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/16/16 22:38 108-10-1100 0.33 1
Styrene ND ug/L 12/16/16 22:38 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/16/16 22:38 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/16/16 22:38 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/16/16 22:38 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/16/16 22:38 109-99-910.0 3.1 1
Toluene ND ug/L 12/16/16 22:38 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/16/16 22:38 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/16/16 22:38 79-00-51.0 0.29 1
Trichloroethene 1.8 ug/L 12/16/16 22:38 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/16/16 22:38 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/16/16 22:38 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/16/16 22:38 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/16/16 22:38 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/16/16 22:38 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/16/16 22:38 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/16/16 22:38 17060-07-070-130 1
Toluene-d8 (S)100 %12/16/16 22:38 2037-26-570-130 1
Analytical Method: SM 2320B2320B Alkalinity
Alkalinity, Total as CaCO3 294000 ug/L 12/24/16 21:245000 1000 1
Analytical Method: SM 2540C2540C Total Dissolved Solids
Total Dissolved Solids 366000 ug/L 12/19/16 21:5425000 25000 1
Analytical Method: EPA 300.0300.0 IC Anions 28 Days
Sulfate 6820J ug/L 12/17/16 21:52 14808-79-8250000 1000 1
Analytical Method: SM 4500-Cl-E4500 Chloride
Chloride 4760 ug/L 01/03/17 14:40 16887-00-61000 500 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Iron ug/L ND 300 12/23/16 05:1125.0
Lead ug/L ND 10.0 12/23/16 05:112.5
Manganese ug/L ND 50.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Iron ug/L 44805000 90 80-120
Lead ug/L 426500 85 80-120
Manganese ug/L 442500 88 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Iron ug/L 5000 80 75-12584 5 255000ND4010 4220
Lead ug/L 500 99 75-125103 3 25500ND497 514
Manganese ug/L 500 79 75-12584 6 25500ND395 419
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341293
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893540
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/16/16 13:490.33
1,1,1-Trichloroethane ug/L ND 1.0 12/16/16 13:490.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/16/16 13:490.40
1,1,2-Trichloroethane ug/L ND 1.0 12/16/16 13:490.29
1,1-Dichloroethane ug/L ND 5.0 12/16/16 13:490.32
1,1-Dichloroethene ug/L ND 5.0 12/16/16 13:490.56
1,2,3-Trichloropropane ug/L ND 1.0 12/16/16 13:490.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/16/16 13:492.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/16/16 13:490.27
1,2-Dichlorobenzene ug/L ND 5.0 12/16/16 13:490.30
1,2-Dichloroethane ug/L ND 1.0 12/16/16 13:490.24
1,2-Dichloropropane ug/L ND 1.0 12/16/16 13:490.27
1,4-Dichlorobenzene ug/L ND 1.0 12/16/16 13:490.33
2-Butanone (MEK)ug/L ND 100 12/16/16 13:490.96
2-Hexanone ug/L ND 50.0 12/16/16 13:490.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/16/16 13:490.33
Acetone ug/L ND 100 12/16/16 13:4910.0
Acrylonitrile ug/L ND 200 12/16/16 13:491.9
Benzene ug/L ND 1.0 12/16/16 13:490.25
Bromochloromethane ug/L ND 3.0 12/16/16 13:490.17
Bromodichloromethane ug/L ND 1.0 12/16/16 13:490.18
Bromoform ug/L ND 3.0 12/16/16 13:490.26
Bromomethane ug/L ND 10.0 12/16/16 13:490.29
Carbon disulfide ug/L ND 100 12/16/16 13:491.2
Carbon tetrachloride ug/L ND 1.0 12/16/16 13:490.25
Chlorobenzene ug/L ND 3.0 12/16/16 13:490.23
Chloroethane ug/L ND 10.0 12/16/16 13:490.54
Chloroform ug/L ND 5.0 12/16/16 13:490.14
Chloromethane ug/L ND 1.0 12/16/16 13:490.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/16/16 13:490.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/16/16 13:490.13
Dibromochloromethane ug/L ND 3.0 12/16/16 13:490.21
Dibromomethane ug/L ND 10.0 12/16/16 13:490.21
Ethylbenzene ug/L ND 1.0 12/16/16 13:490.30
Iodomethane ug/L ND 10.0 12/16/16 13:490.32
Methylene Chloride ug/L ND 1.0 12/16/16 13:490.97
Styrene ug/L ND 1.0 12/16/16 13:490.26
Tetrachloroethene ug/L ND 1.0 12/16/16 13:490.46
Tetrahydrofuran ug/L ND 10.0 12/16/16 13:493.1
Toluene ug/L ND 1.0 12/16/16 13:490.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/16/16 13:490.49
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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[phone]
Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893540
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
trans-1,3-Dichloropropene ug/L ND 1.0 12/16/16 13:490.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/16/16 13:491.0
Trichloroethene ug/L ND 1.0 12/16/16 13:490.47
Trichlorofluoromethane ug/L ND 1.0 12/16/16 13:490.20
Vinyl acetate ug/L ND 50.0 12/16/16 13:490.35
Vinyl chloride ug/L ND 1.0 12/16/16 13:490.62
Xylene (Total)ug/L ND 5.0 12/16/16 13:490.66
1,2-Dichloroethane-d4 (S)%103 70-130 12/16/16 13:49
4-Bromofluorobenzene (S)%93 70-130 12/16/16 13:49
Toluene-d8 (S)%100 70-130 12/16/16 13:49
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893541LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 46.250 92 80-125
1,1,1-Trichloroethane ug/L 49.050 98 71-129
1,1,2,2-Tetrachloroethane ug/L 47.850 96 79-124
1,1,2-Trichloroethane ug/L 48.850 98 85-125
1,1-Dichloroethane ug/L 52.250 104 73-126
1,1-Dichloroethene ug/L 56.250 112 66-135
1,2,3-Trichloropropane ug/L 46.150 92 75-130
1,2-Dibromo-3-chloropropane ug/L 47.250 94 71-133
1,2-Dibromoethane (EDB)ug/L 46.350 93 83-124
1,2-Dichlorobenzene ug/L 48.050 96 80-133
1,2-Dichloroethane ug/L 46.150 92 67-128
1,2-Dichloropropane ug/L 51.350 103 75-132
1,4-Dichlorobenzene ug/L 47.350 95 78-130
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 103100 103 68-143
4-Methyl-2-pentanone (MIBK)ug/L 103100 103 72-135
Acetone ug/L 99.8J100 100 48-146
Acrylonitrile ug/L 282250 113 40-160
Benzene ug/L 51.050 102 80-125
Bromochloromethane ug/L 50.850 102 71-125
Bromodichloromethane ug/L 49.550 99 78-124
Bromoform ug/L 44.950 90 71-128
Bromomethane ug/L 44.850 90 40-160
Carbon disulfide ug/L 60.7J50 121 50-160
Carbon tetrachloride ug/L 47.450 95 69-131
Chlorobenzene ug/L 47.950 96 81-122
Chloroethane ug/L 53.450 107 39-148
Chloroform ug/L 49.350 99 73-127
Chloromethane ug/L 50.650 101 44-146
cis-1,2-Dichloroethene ug/L 52.350 105 74-124
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893541LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,3-Dichloropropene ug/L 51.150 102 72-132
Dibromochloromethane ug/L 47.350 95 78-125
Dibromomethane ug/L 45.750 91 82-120
Ethylbenzene ug/L 48.350 97 79-121
Iodomethane ug/L 101100 101 39-154
Methylene Chloride ug/L 52.750 105 64-133
Styrene ug/L 47.950 96 84-126
Tetrachloroethene ug/L 43.950 88 78-122
Tetrahydrofuran ug/L 572500 114 69-148
Toluene ug/L 49.050 98 80-121
trans-1,2-Dichloroethene ug/L 54.850 110 71-127
trans-1,3-Dichloropropene ug/L 50.850 102 69-141
trans-1,4-Dichloro-2-butene ug/L 46.2J50 92 40-160
Trichloroethene ug/L 46.450 93 78-122
Trichlorofluoromethane ug/L 53.950 108 53-137
Vinyl acetate ug/L 113100 113 40-160
Vinyl chloride ug/L 45.550 91 58-137
Xylene (Total)ug/L 143150 95 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893546MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062015
1893547
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
1,1,1,2-Tetrachloroethane ug/L 20 96 70-13091 5 3020ND19.2 18.3
1,1,1-Trichloroethane ug/L 20 104 70-130103 2 3020ND20.9 20.6
1,1,2,2-Tetrachloroethane ug/L 20 99 70-13096 4 3020ND19.8 19.1
1,1,2-Trichloroethane ug/L 20 102 70-13096 6 3020ND20.5 19.3
1,1-Dichloroethane ug/L 20 75 70-130110 27 30207.2 22.1 29.1
1,1-Dichloroethene ug/L 20 117 70-166115 2 3020ND23.5 23.0
1,2,3-Trichloropropane ug/L 20 94 70-13090 5 3020ND18.8 18.0
1,2-Dibromo-3-
chloropropane ug/L 20 93 70-13089 5 3020ND18.6 17.8
1,2-Dibromoethane (EDB) ug/L 20 96 70-13092 4 3020ND19.2 18.4
1,2-Dichlorobenzene ug/L 20 96 70-13095 1 30200.65J 19.9 19.7
1,2-Dichloroethane ug/L 20 87 70-13095 8 30202.5 19.8 21.4
1,2-Dichloropropane ug/L 20 105 70-130103 2 30200.51J 21.5 21.1
1,4-Dichlorobenzene ug/L M1206570-13094 25 30206.6 19.7 25.4
2-Butanone (MEK)ug/L 40 111 70-130102 9 3040ND44.5J 40.8J
2-Hexanone ug/L 40 103 70-13099 5 3040ND41.4J 39.5J
4-Methyl-2-pentanone
(MIBK)ug/L 40 104 70-13098 6 3040ND41.6J 39.3J
Acetone ug/L 40 100 70-13096 4 3040ND40.1J 38.5J
Acrylonitrile ug/L 100 115 70-130112 3 30100ND115J 112J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1893546MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062015
1893547
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Benzene ug/L 20 93 70-148107 12 30202.8 21.5 24.2
Bromochloromethane ug/L 20 105 70-130102 3 3020ND20.9 20.3
Bromodichloromethane ug/L 20 101 70-13098 3 3020ND20.1 19.6
Bromoform ug/L 20 89 70-13086 3 3020ND17.7 17.2
Bromomethane ug/L 20 94 70-130103 9 3020ND18.7 20.5
Carbon disulfide ug/L 20 127 70-130124 2 3020ND25.5J 24.8J
Carbon tetrachloride ug/L 20 101 70-13098 3 3020ND20.2 19.6
Chlorobenzene ug/L 20 83 70-14698 14 30203.7 20.2 23.3
Chloroethane ug/L 20 111 70-130112 1 30200.70J 22.9 23.0
Chloroform ug/L 20 106 70-130103 3 3020ND21.2 20.5
Chloromethane ug/L 20 109 70-130107 2 3020ND21.8 21.4
cis-1,2-Dichloroethene ug/L M1,R120-156 70-130104 108 302053.2 22.1 74.0
cis-1,3-Dichloropropene ug/L 20 99 70-13094 4 3020ND19.7 18.9
Dibromochloromethane ug/L 20 97 70-13093 4 3020ND19.3 18.6
Dibromomethane ug/L 20 96 70-13090 6 3020ND19.2 18.1
Ethylbenzene ug/L 20 103 70-13099 5 3020ND20.7 19.7
Iodomethane ug/L 40 101 70-130105 4 3040ND40.3 42.0
Methylene Chloride ug/L 20 73 70-130111 30 30206.4 21.0 28.5
Styrene ug/L 20 100 70-13097 3 3020ND20.0 19.3
Tetrachloroethene ug/L 20 74 70-13092 18 30203.6 18.3 21.9
Tetrahydrofuran ug/L 200 113 70-130112 1 302008.8J 236 233
Toluene ug/L 20 103 70-155100 3 3020ND20.6 20.0
trans-1,2-Dichloroethene ug/L 20 112 70-130115 3 3020ND22.9 23.5
trans-1,3-Dichloropropene ug/L 20 97 70-13093 5 3020ND19.5 18.5
trans-1,4-Dichloro-2-butene ug/L 20 83 70-13080 4 3020ND16.7J 15.9J
Trichloroethene ug/L 20 81 69-15197 15 30203.9 20.1 23.4
Trichlorofluoromethane ug/L 20 115 70-130112 3 3020ND23.0 22.4
Vinyl acetate ug/L 40 105 70-13096 9 3040ND41.9J 38.3J
Vinyl chloride ug/L 20 94 70-13094 0 3020ND19.2 19.1
1,2-Dichloroethane-d4 (S)%97 70-130100
4-Bromofluorobenzene (S) %96 70-13096
Toluene-d8 (S)%100 70-13099
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342135
SM 2320B
SM 2320B
2320B Alkalinity
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898143
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Alkalinity, Total as CaCO3 ug/L ND 5000 12/24/16 16:071000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898144LABORATORY CONTROL SAMPLE:
LCSSpike
Alkalinity, Total as CaCO3 ug/L 4770050000 95 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898145MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1898146
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L M1500007980-12077 1 255000026.8 mg/L 66200 65300
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1898147MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323602008
1898148
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Alkalinity, Total as CaCO3 ug/L 50000 94 80-120103 2 2550000163 mg/L 210000 214000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341553
SM 2540C
SM 2540C
2540C Total Dissolved Solids
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895143
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Total Dissolved Solids ug/L ND 25000 12/19/16 21:4525000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895144LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids ug/L 252000250000 101 90-110
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323450019
1895145SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 268000 1 5270 mg/L
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323459010
1895146SAMPLE DUPLICATE:
Total Dissolved Solids ug/L 155000 D665164 mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341402
EPA 300.0
EPA 300.0
300.0 IC Anions
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1894399
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Sulfate ug/L ND 250000 12/17/16 17:461000
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894400LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfate ug/L 19400J20000 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894401MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323238003
1894402
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L M12000011590-110110 2 102000026.5 mg/L 49500J 48400J
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894403MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1894404
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfate ug/L 20000 99 90-11094 5 10200002.1 mg/L 22000J 21000J
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342771
SM 4500-Cl-E
SM 4500-Cl-E
4500 Chloride
Associated Lab Samples: 92323610001, 92323610002, 92323610003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1901312
Associated Lab Samples:92323610001, 92323610002, 92323610003
Matrix: Water
AnalyzedMDL
Chloride ug/L ND 1000 01/03/17 14:32500
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1901313LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride ug/L 1990020000 99 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901314MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92324292003
1901315
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011690-110128 1 101000077.7 mg/L 89200 90400
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1901316MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1901317
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Chloride ug/L M11000011290-110115 2 10100003.3 mg/L 14500 14800
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 01/04/2017 05:07 AM
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Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323610
Johns R. Phase 1A GW
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323610001 341173 3415711203-MW20 EPA 3010A EPA 6010
92323610002 341173 3415711203-MW22S EPA 3010A EPA 6010
92323610003 341173 3415711203-MW38 EPA 3010A EPA 6010
92323610001 341661 3419801203-MW20 EPA 7470 EPA 7470
92323610002 341661 3419801203-MW22S EPA 7470 EPA 7470
92323610003 341661 3419801203-MW38 EPA 7470 EPA 7470
92323610001 3412931203-MW20 EPA 8260
92323610002 3412931203-MW22S EPA 8260
92323610003 3412931203-MW38 EPA 8260
92323610001 3421351203-MW20 SM 2320B
92323610002 3421351203-MW22S SM 2320B
92323610003 3421351203-MW38 SM 2320B
92323610001 3415531203-MW20 SM 2540C
92323610002 3415531203-MW22S SM 2540C
92323610003 3415531203-MW38 SM 2540C
92323610001 3414021203-MW20 EPA 300.0
92323610002 3414021203-MW22S EPA 300.0
92323610003 3414021203-MW38 EPA 300.0
92323610001 3427711203-MW20 SM 4500-Cl-E
92323610002 3427711203-MW22S SM 4500-Cl-E
92323610003 3427711203-MW38 SM 4500-Cl-E
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Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
December 28, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323605
92323605
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Johns R. Add MW LFG
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 1 of 36
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 2 of 36
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID Matrix Date Collected Date Received
92323605001 1203-MW15S Water 12/14/16 09:24 12/15/16 10:10
92323605002 1203-PZ12 Water 12/14/16 10:08 12/15/16 10:10
92323605003 1203-PZ30S Water 12/14/16 12:08 12/15/16 10:10
92323605004 1203-PZ31 Water 12/14/16 12:18 12/15/16 10:10
92323605005 1203-PZ35 Water 12/14/16 12:00 12/15/16 10:10
92323605006 1203-MW36 Water 12/14/16 11:16 12/15/16 10:10
92323605007 1203-MW38 Water 12/14/16 08:34 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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Page 3 of 36
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323605001 1203-MW15S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605002 1203-PZ12 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605003 1203-PZ30S RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605004 1203-PZ31 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605005 1203-PZ35 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605006 1203-MW36 RSK 175 Modified 1 PASI-CWDV
EPA 8260 11 PASI-CCAH
92323605007 1203-MW38 RSK 175 Modified 1 PASI-CWDV
REPORT OF LABORATORY ANALYSIS
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#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323605001 1203-MW15S
Methane 16700 ug/L 12/23/16 12:51 N2200RSK 175 Modified
Benzene 0.85J ug/L 12/21/16 18:431.0EPA 8260
1,4-Dichlorobenzene 0.73J ug/L 12/21/16 18:431.0EPA 8260
1,1-Dichloroethane 0.85J ug/L 12/21/16 18:435.0EPA 8260
Tetrachloroethene 1.4 ug/L 12/21/16 18:431.0EPA 8260
Trichloroethene 0.81J ug/L 12/21/16 18:431.0EPA 8260
92323605004 1203-PZ31
Methane 27.0 ug/L 12/22/16 17:06 N210.0RSK 175 Modified
92323605006 1203-MW36
Methane 32200 ug/L 12/23/16 12:35 N2400RSK 175 Modified
Benzene 5.5 ug/L 12/21/16 20:091.0EPA 8260
1,4-Dichlorobenzene 15.8 ug/L 12/21/16 20:091.0EPA 8260
1,1-Dichloroethane 4.4J ug/L 12/21/16 20:095.0EPA 8260
1,2-Dichloroethane 0.77J ug/L 12/21/16 20:091.0EPA 8260
92323605007 1203-MW38
Methane 15300 ug/L 12/23/16 11:01 N2100RSK 175 Modified
REPORT OF LABORATORY ANALYSIS
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Page 5 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW15S Lab ID: 92323605001 Collected: 12/14/16 09:24 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 16700 ug/L 12/23/16 12:51 74-82-8 N2200 200 20
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 0.85J ug/L 12/21/16 18:43 71-43-21.0 0.25 1
1,4-Dichlorobenzene 0.73J ug/L 12/21/16 18:43 106-46-71.0 0.33 1
1,1-Dichloroethane 0.85J ug/L 12/21/16 18:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 18:43 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 18:43 75-09-21.0 0.97 1
Tetrachloroethene 1.4 ug/L 12/21/16 18:43 127-18-41.0 0.46 1
Trichloroethene 0.81J ug/L 12/21/16 18:43 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 18:43 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 18:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 18:43 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 18:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 6 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ12 Lab ID: 92323605002 Collected: 12/14/16 10:08 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/23/16 12:19 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:00 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:00 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:00 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:00 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:00 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:00 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:00 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:00 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)104 %12/21/16 19:00 460-00-470-130 1
1,2-Dichloroethane-d4 (S)99 %12/21/16 19:00 17060-07-070-130 1
Toluene-d8 (S)97 %12/21/16 19:00 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 7 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ30S Lab ID: 92323605003 Collected: 12/14/16 12:08 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/22/16 16:51 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:18 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:18 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:18 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:18 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:18 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:18 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:18 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:18 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 19:18 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/21/16 19:18 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 19:18 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 8 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ31 Lab ID: 92323605004 Collected: 12/14/16 12:18 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 27.0 ug/L 12/22/16 17:06 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:35 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:35 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:35 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:35 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:35 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:35 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:35 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:35 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)106 %12/21/16 19:35 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/21/16 19:35 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 19:35 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 9 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-PZ35 Lab ID: 92323605005 Collected: 12/14/16 12:00 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane ND ug/L 12/22/16 17:22 74-82-8 N210.0 10.0 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene ND ug/L 12/21/16 19:52 71-43-21.0 0.25 1
1,4-Dichlorobenzene ND ug/L 12/21/16 19:52 106-46-71.0 0.33 1
1,1-Dichloroethane ND ug/L 12/21/16 19:52 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 19:52 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 19:52 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 19:52 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 19:52 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 19:52 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 19:52 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/21/16 19:52 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 19:52 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 10 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW36 Lab ID: 92323605006 Collected: 12/14/16 11:16 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 32200 ug/L 12/23/16 12:35 74-82-8 N2400 400 40
Analytical Method: EPA 82608260 MSV Low Level Landfill
Benzene 5.5 ug/L 12/21/16 20:09 71-43-21.0 0.25 1
1,4-Dichlorobenzene 15.8 ug/L 12/21/16 20:09 106-46-71.0 0.33 1
1,1-Dichloroethane 4.4J ug/L 12/21/16 20:09 75-34-35.0 0.32 1
1,2-Dichloroethane 0.77J ug/L 12/21/16 20:09 107-06-21.0 0.24 1
Methylene Chloride ND ug/L 12/21/16 20:09 75-09-21.0 0.97 1
Tetrachloroethene ND ug/L 12/21/16 20:09 127-18-41.0 0.46 1
Trichloroethene ND ug/L 12/21/16 20:09 79-01-61.0 0.47 1
Vinyl chloride ND ug/L 12/21/16 20:09 75-01-41.0 0.62 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 20:09 460-00-470-130 1
1,2-Dichloroethane-d4 (S)103 %12/21/16 20:09 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 20:09 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
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Page 11 of 36
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Sample: 1203-MW38 Lab ID: 92323605007 Collected: 12/14/16 08:34 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: RSK 175 ModifiedRSK 175 Headspace
Methane 15300 ug/L 12/23/16 11:01 74-82-8 N2100 100 10
REPORT OF LABORATORY ANALYSIS
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Page 12 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342220
RSK 175 Modified
RSK 175 Modified
RSK 175 HEADSPACE
Associated Lab Samples: 92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006, 92323605007
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1898651
Associated Lab Samples:92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006, 92323605007
Matrix: Water
AnalyzedMDL
Methane ug/L ND 10.0 N212/22/16 14:0410.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1898652LABORATORY CONTROL SAMPLE:
LCSSpike
Methane ug/L 376 N239695 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1898653MATRIX SPIKE SAMPLE:
MSSpike
Result
92324178004
Methane ug/L 449 N2396113 70-130ND
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92324178005
1898654SAMPLE DUPLICATE:
Methane ug/L ND N220ND
REPORT OF LABORATORY ANALYSIS
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Page 13 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342009
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1897422
Associated Lab Samples:92323605001, 92323605002, 92323605003, 92323605004, 92323605005, 92323605006
Matrix: Water
AnalyzedMDL
1,1-Dichloroethane ug/L ND 5.0 12/21/16 16:100.32
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:100.24
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:100.33
Benzene ug/L ND 1.0 12/21/16 16:100.25
Methylene Chloride ug/L ND 1.0 12/21/16 16:100.97
Tetrachloroethene ug/L ND 1.0 12/21/16 16:100.46
Trichloroethene ug/L ND 1.0 12/21/16 16:100.47
Vinyl chloride ug/L ND 1.0 12/21/16 16:100.62
1,2-Dichloroethane-d4 (S)%100 70-130 12/21/16 16:10
4-Bromofluorobenzene (S)%107 70-130 12/21/16 16:10
Toluene-d8 (S)%99 70-130 12/21/16 16:10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897423LABORATORY CONTROL SAMPLE:
LCSSpike
1,1-Dichloroethane ug/L 50.150 100 73-126
1,2-Dichloroethane ug/L 46.450 93 67-128
1,4-Dichlorobenzene ug/L 47.650 95 78-130
Benzene ug/L 52.250 104 80-125
Methylene Chloride ug/L 57.650 115 64-133
Tetrachloroethene ug/L 40.750 81 78-122
Trichloroethene ug/L 51.350 103 78-122
Vinyl chloride ug/L 37.150 74 58-137
1,2-Dichloroethane-d4 (S)%99 70-130
4-Bromofluorobenzene (S)%103 70-130
Toluene-d8 (S)%88 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897424MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991018
1,1-Dichloroethane ug/L 17.620 83 70-1301.0
1,2-Dichloroethane ug/L 17.920 89 70-130ND
1,4-Dichlorobenzene ug/L 21.220 95 70-1302.1
Benzene ug/L 19.620 98 70-148ND
Methylene Chloride ug/L 16.020 80 70-130ND
Tetrachloroethene ug/L 17.020 79 70-1301.2
Trichloroethene ug/L 23.220 99 69-1513.3
Vinyl chloride ug/L 15.720 75 70-1300.71J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 36
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897424MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991018
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%86 70-130
Toluene-d8 (S)%97 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991019
1897425SAMPLE DUPLICATE:
1,1-Dichloroethane ug/L 0.60J 300.57J
1,2-Dichloroethane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 0.86J 300.85J
Benzene ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Tetrachloroethene ug/L 2.4 0 302.4
Trichloroethene ug/L 11.1 5 3010.6
Vinyl chloride ug/L 1.3 3 301.3
1,2-Dichloroethane-d4 (S)%101 0101
4-Bromofluorobenzene (S)%104 1105
Toluene-d8 (S)%97 299
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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[phone]
Page 15 of 36
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
The lab does not hold NELAC/TNI accreditation for this parameter.N2
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Page 16 of 36
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323605
Johns R. Add MW LFG
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323605001 3422201203-MW15S RSK 175 Modified
92323605002 3422201203-PZ12 RSK 175 Modified
92323605003 3422201203-PZ30S RSK 175 Modified
92323605004 3422201203-PZ31 RSK 175 Modified
92323605005 3422201203-PZ35 RSK 175 Modified
92323605006 3422201203-MW36 RSK 175 Modified
92323605007 3422201203-MW38 RSK 175 Modified
92323605001 3420091203-MW15S EPA 8260
92323605002 3420091203-PZ12 EPA 8260
92323605003 3420091203-PZ30S EPA 8260
92323605004 3420091203-PZ31 EPA 8260
92323605005 3420091203-PZ35 EPA 8260
92323605006 3420091203-MW36 EPA 8260
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 02:23 PM
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Huntersville, NC 28078
[phone]
Page 17 of 36
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Page 36 of 36
#=CL#
December 27, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323615
92323615
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Johns R. Surface Water
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc: Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 1 of 27
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
Page 2 of 27
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID Matrix Date Collected Date Received
92323615001 1203-SMP5 Water 12/14/16 13:20 12/15/16 10:10
92323615002 1203-SMP6 Water 12/14/16 11:45 12/15/16 10:10
92323615003 1203-SMP7 Water 12/14/16 10:05 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 3 of 27
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323615001 1203-SMP5 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
92323615002 1203-SMP6 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
92323615003 1203-SMP7 EPA 8081 4 PASI-CSWB
EPA 6010 16 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8260 52 PASI-CZDO
SM 4500-CN-E 1 PASI-ADMN
REPORT OF LABORATORY ANALYSIS
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Page 4 of 27
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323615001 1203-SMP5
Barium 44.7J ug/L 12/23/16 06:34100EPA 6010
Cobalt 5.9J ug/L 12/23/16 06:3410.0EPA 6010
92323615002 1203-SMP6
Barium 21.2J ug/L 12/23/16 06:37100EPA 6010
1,1-Dichloroethane 2.6J ug/L 12/17/16 03:115.0EPA 8260
cis-1,2-Dichloroethene 0.43J ug/L 12/17/16 03:115.0EPA 8260
Trichloroethene 0.52J ug/L 12/17/16 03:111.0EPA 8260
92323615003 1203-SMP7
Barium 17.5J ug/L 12/23/16 06:49100EPA 6010
Zinc 6.9J ug/L 12/23/16 06:4910.0EPA 6010
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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Page 5 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP5 Lab ID: 92323615001 Collected: 12/14/16 13:20 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:23 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:23 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)89 %12/22/16 16:23 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)90 %12/22/16 16:23 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:50 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:34 7440-38-212/17/16 01:0010.0 2.5 1
Barium 44.7J ug/L 12/23/16 06:34 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:34 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:50 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:34 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt 5.9J ug/L 12/23/16 06:34 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:34 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 21:50 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:50 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:34 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:34 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:34 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:34 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:34 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:34 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:07 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 02:54 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 02:54 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 02:54 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 02:54 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 02:54 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 02:54 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 02:54 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 02:54 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 02:54 75-15-0 M1100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 02:54 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 02:54 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 02:54 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 02:54 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 02:54 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 02:54 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 02:54 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 02:54 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 02:54 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 6 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP5 Lab ID: 92323615001 Collected: 12/14/16 13:20 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 02:54 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 02:54 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 02:54 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 02:54 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/17/16 02:54 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 02:54 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 02:54 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/17/16 02:54 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 02:54 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 02:54 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 02:54 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 02:54 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 02:54 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 02:54 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 02:54 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 02:54 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 02:54 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 02:54 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 02:54 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 02:54 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 02:54 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 02:54 109-99-9 M110.0 3.1 1
Toluene ND ug/L 12/17/16 02:54 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 02:54 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 02:54 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/17/16 02:54 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 02:54 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 02:54 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 02:54 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 02:54 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 02:54 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)95 %12/17/16 02:54 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/17/16 02:54 17060-07-070-130 1
Toluene-d8 (S)100 %12/17/16 02:54 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:47 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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Page 7 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP6 Lab ID: 92323615002 Collected: 12/14/16 11:45 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:40 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:40 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)78 %12/22/16 16:40 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)88 %12/22/16 16:40 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:53 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:37 7440-38-212/17/16 01:0010.0 2.5 1
Barium 21.2J ug/L 12/23/16 06:37 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:37 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:53 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:37 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:37 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:37 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 21:53 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:53 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:37 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:37 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:37 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:37 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:37 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:37 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:09 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 03:11 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 03:11 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 03:11 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 03:11 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 03:11 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 03:11 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 03:11 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 03:11 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 03:11 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 03:11 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 03:11 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 03:11 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 03:11 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 03:11 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 03:11 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 03:11 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 03:11 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 03:11 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 8 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP6 Lab ID: 92323615002 Collected: 12/14/16 11:45 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 03:11 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 03:11 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 03:11 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 03:11 75-71-85.0 0.21 1
1,1-Dichloroethane 2.6J ug/L 12/17/16 03:11 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 03:11 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 03:11 75-35-45.0 0.56 1
cis-1,2-Dichloroethene 0.43J ug/L 12/17/16 03:11 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 03:11 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 03:11 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 03:11 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 03:11 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 03:11 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 03:11 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 03:11 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 03:11 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 03:11 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 03:11 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 03:11 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 03:11 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 03:11 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 03:11 109-99-910.0 3.1 1
Toluene ND ug/L 12/17/16 03:11 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 03:11 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 03:11 79-00-51.0 0.29 1
Trichloroethene 0.52J ug/L 12/17/16 03:11 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 03:11 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 03:11 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 03:11 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 03:11 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 03:11 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)94 %12/17/16 03:11 460-00-470-130 1
1,2-Dichloroethane-d4 (S)102 %12/17/16 03:11 17060-07-070-130 1
Toluene-d8 (S)101 %12/17/16 03:11 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:51 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
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[phone]
Page 9 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP7 Lab ID: 92323615003 Collected: 12/14/16 10:05 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
alpha-BHC ND ug/L 12/22/16 16:58 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:58 319-85-712/20/16 16:160.050 0.050 1
Surrogates
Tetrachloro-m-xylene (S)105 %12/22/16 16:58 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)94 %12/22/16 16:58 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:56 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:49 7440-38-212/17/16 01:0010.0 2.5 1
Barium 17.5J ug/L 12/23/16 06:49 7440-39-312/17/16 01:00100 2.5 1
Beryllium ND ug/L 12/23/16 06:49 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:56 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:49 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:49 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:49 7440-50-812/17/16 01:0010.0 2.5 1
Lead ND ug/L 12/23/16 06:49 7439-92-112/17/16 01:0010.0 2.5 1
Nickel ND ug/L 12/23/16 21:56 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:49 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:49 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:49 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:49 7440-31-512/17/16 01:00100 2.5 1
Vanadium ND ug/L 12/23/16 06:49 7440-62-212/17/16 01:0025.0 2.5 1
Zinc 6.9J ug/L 12/23/16 06:49 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:11 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/17/16 03:45 67-64-1100 10.0 1
Acrylonitrile ND ug/L 12/17/16 03:45 107-13-1200 1.9 1
Benzene ND ug/L 12/17/16 03:45 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/17/16 03:45 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/17/16 03:45 75-27-41.0 0.18 1
Bromoform ND ug/L 12/17/16 03:45 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/17/16 03:45 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/17/16 03:45 78-93-3100 0.96 1
Carbon disulfide ND ug/L 12/17/16 03:45 75-15-0100 1.2 1
Carbon tetrachloride ND ug/L 12/17/16 03:45 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/17/16 03:45 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/17/16 03:45 75-00-310.0 0.54 1
Chloroform ND ug/L 12/17/16 03:45 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/17/16 03:45 74-87-31.0 0.11 1
1,2-Dibromo-3-chloropropane ND ug/L 12/17/16 03:45 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/17/16 03:45 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/17/16 03:45 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/17/16 03:45 74-95-310.0 0.21 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 10 of 27
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Sample: 1203-SMP7 Lab ID: 92323615003 Collected: 12/14/16 10:05 Received: 12/15/16 10:10 Matrix: Water
Parameters Results Units DF Prepared Analyzed CAS No. QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
1,2-Dichlorobenzene ND ug/L 12/17/16 03:45 95-50-15.0 0.30 1
1,4-Dichlorobenzene ND ug/L 12/17/16 03:45 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/17/16 03:45 110-57-6100 1.0 1
Dichlorodifluoromethane ND ug/L 12/17/16 03:45 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/17/16 03:45 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/17/16 03:45 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/17/16 03:45 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/17/16 03:45 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/17/16 03:45 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/17/16 03:45 78-87-51.0 0.27 1
cis-1,3-Dichloropropene ND ug/L 12/17/16 03:45 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/17/16 03:45 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/17/16 03:45 100-41-41.0 0.30 1
2-Hexanone ND ug/L 12/17/16 03:45 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/17/16 03:45 74-88-410.0 0.32 1
Methylene Chloride ND ug/L 12/17/16 03:45 75-09-21.0 0.97 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/17/16 03:45 108-10-1100 0.33 1
Styrene ND ug/L 12/17/16 03:45 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/17/16 03:45 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/17/16 03:45 79-34-53.0 0.40 1
Tetrachloroethene ND ug/L 12/17/16 03:45 127-18-41.0 0.46 1
Tetrahydrofuran ND ug/L 12/17/16 03:45 109-99-910.0 3.1 1
Toluene ND ug/L 12/17/16 03:45 108-88-31.0 0.26 1
1,1,1-Trichloroethane ND ug/L 12/17/16 03:45 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/17/16 03:45 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/17/16 03:45 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/17/16 03:45 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/17/16 03:45 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/17/16 03:45 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/17/16 03:45 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/17/16 03:45 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)93 %12/17/16 03:45 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/17/16 03:45 17060-07-070-130 1
Toluene-d8 (S)99 %12/17/16 03:45 2037-26-570-130 1
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:54 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 11 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1895623
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1892896
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Lead ug/L ND 10.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Lead ug/L 426500 85 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491 508
Arsenic ug/L 500 78 75-12583 6 25500ND393 415
Barium ug/L 500 76 75-12580 6 25500ND378 402
Beryllium ug/L 500 79 75-12584 5 25500ND397 418
Cadmium ug/L 500 76 75-12580 5 25500ND380 402
Chromium ug/L 500 78 75-12582 6 25500ND388 412
Cobalt ug/L 500 76 75-12581 7 25500ND381 407
Copper ug/L 500 82 75-12587 6 25500ND413 438
Lead ug/L 500 99 75-125103 3 25500ND497 514
Nickel ug/L M15007375-12577 6 25500ND364 386
Selenium ug/L 500 81 75-12585 5 25500ND404 425
Silver ug/L 250 88 75-12591 4 25250ND219 227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386 411
Vanadium ug/L 500 78 75-12583 6 25500ND390 413
Zinc ug/L 500 77 75-12583 7 25500ND387 415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341294
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893558
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/17/16 02:020.33
1,1,1-Trichloroethane ug/L ND 1.0 12/17/16 02:020.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/17/16 02:020.40
1,1,2-Trichloroethane ug/L ND 1.0 12/17/16 02:020.29
1,1-Dichloroethane ug/L ND 5.0 12/17/16 02:020.32
1,1-Dichloroethene ug/L ND 5.0 12/17/16 02:020.56
1,2,3-Trichloropropane ug/L ND 1.0 12/17/16 02:020.41
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/17/16 02:022.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/17/16 02:020.27
1,2-Dichlorobenzene ug/L ND 5.0 12/17/16 02:020.30
1,2-Dichloroethane ug/L ND 1.0 12/17/16 02:020.24
1,2-Dichloropropane ug/L ND 1.0 12/17/16 02:020.27
1,4-Dichlorobenzene ug/L ND 1.0 12/17/16 02:020.33
2-Butanone (MEK)ug/L ND 100 12/17/16 02:020.96
2-Hexanone ug/L ND 50.0 12/17/16 02:020.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/17/16 02:020.33
Acetone ug/L ND 100 12/17/16 02:0210.0
Acrylonitrile ug/L ND 200 12/17/16 02:021.9
Benzene ug/L ND 1.0 12/17/16 02:020.25
Bromochloromethane ug/L ND 3.0 12/17/16 02:020.17
Bromodichloromethane ug/L ND 1.0 12/17/16 02:020.18
Bromoform ug/L ND 3.0 12/17/16 02:020.26
Bromomethane ug/L ND 10.0 12/17/16 02:020.29
Carbon disulfide ug/L ND 100 12/17/16 02:021.2
Carbon tetrachloride ug/L ND 1.0 12/17/16 02:020.25
Chlorobenzene ug/L ND 3.0 12/17/16 02:020.23
Chloroethane ug/L ND 10.0 12/17/16 02:020.54
Chloroform ug/L ND 5.0 12/17/16 02:020.14
Chloromethane ug/L ND 1.0 12/17/16 02:020.11
cis-1,2-Dichloroethene ug/L ND 5.0 12/17/16 02:020.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/17/16 02:020.13
Dibromochloromethane ug/L ND 3.0 12/17/16 02:020.21
Dibromomethane ug/L ND 10.0 12/17/16 02:020.21
Dichlorodifluoromethane ug/L ND 5.0 12/17/16 02:020.21
Ethylbenzene ug/L ND 1.0 12/17/16 02:020.30
Iodomethane ug/L ND 10.0 12/17/16 02:020.32
Methylene Chloride ug/L ND 1.0 12/17/16 02:020.97
Styrene ug/L ND 1.0 12/17/16 02:020.26
Tetrachloroethene ug/L ND 1.0 12/17/16 02:020.46
Tetrahydrofuran ug/L ND 10.0 12/17/16 02:023.1
Toluene ug/L ND 1.0 12/17/16 02:020.26
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 15 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1893558
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
trans-1,2-Dichloroethene ug/L ND 5.0 12/17/16 02:020.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/17/16 02:020.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/17/16 02:021.0
Trichloroethene ug/L ND 1.0 12/17/16 02:020.47
Trichlorofluoromethane ug/L ND 1.0 12/17/16 02:020.20
Vinyl acetate ug/L ND 50.0 12/17/16 02:020.35
Vinyl chloride ug/L ND 1.0 12/17/16 02:020.62
Xylene (Total)ug/L ND 5.0 12/17/16 02:020.66
1,2-Dichloroethane-d4 (S)%103 70-130 12/17/16 02:02
4-Bromofluorobenzene (S)%94 70-130 12/17/16 02:02
Toluene-d8 (S)%101 70-130 12/17/16 02:02
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893559LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 47.450 95 80-125
1,1,1-Trichloroethane ug/L 50.350 101 71-129
1,1,2,2-Tetrachloroethane ug/L 48.950 98 79-124
1,1,2-Trichloroethane ug/L 48.850 98 85-125
1,1-Dichloroethane ug/L 53.550 107 73-126
1,1-Dichloroethene ug/L 57.750 115 66-135
1,2,3-Trichloropropane ug/L 46.950 94 75-130
1,2-Dibromo-3-chloropropane ug/L 47.250 94 71-133
1,2-Dibromoethane (EDB)ug/L 48.350 97 83-124
1,2-Dichlorobenzene ug/L 48.750 97 80-133
1,2-Dichloroethane ug/L 47.050 94 67-128
1,2-Dichloropropane ug/L 52.550 105 75-132
1,4-Dichlorobenzene ug/L 47.650 95 78-130
2-Butanone (MEK)ug/L 114100 114 61-144
2-Hexanone ug/L 110100 110 68-143
4-Methyl-2-pentanone (MIBK)ug/L 107100 107 72-135
Acetone ug/L 106100 106 48-146
Acrylonitrile ug/L 298250 119 40-160
Benzene ug/L 52.550 105 80-125
Bromochloromethane ug/L 52.250 104 71-125
Bromodichloromethane ug/L 48.650 97 78-124
Bromoform ug/L 45.250 90 71-128
Bromomethane ug/L 46.250 92 40-160
Carbon disulfide ug/L 63.0J50 126 50-160
Carbon tetrachloride ug/L 48.150 96 69-131
Chlorobenzene ug/L 48.450 97 81-122
Chloroethane ug/L 57.650 115 39-148
Chloroform ug/L 49.850 100 73-127
Chloromethane ug/L 61.650 123 44-146
REPORT OF LABORATORY ANALYSIS
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Page 16 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893559LABORATORY CONTROL SAMPLE:
LCSSpike
cis-1,2-Dichloroethene ug/L 53.550 107 74-124
cis-1,3-Dichloropropene ug/L 50.550 101 72-132
Dibromochloromethane ug/L 48.250 96 78-125
Dibromomethane ug/L 46.050 92 82-120
Dichlorodifluoromethane ug/L 57.450 115 34-157
Ethylbenzene ug/L 48.950 98 79-121
Iodomethane ug/L 105100 105 39-154
Methylene Chloride ug/L 53.750 107 64-133
Styrene ug/L 49.350 99 84-126
Tetrachloroethene ug/L 44.850 90 78-122
Tetrahydrofuran ug/L 611500 122 69-148
Toluene ug/L 49.050 98 80-121
trans-1,2-Dichloroethene ug/L 57.150 114 71-127
trans-1,3-Dichloropropene ug/L 50.250 100 69-141
trans-1,4-Dichloro-2-butene ug/L 43.7J50 87 40-160
Trichloroethene ug/L 48.150 96 78-122
Trichlorofluoromethane ug/L 56.750 113 53-137
Vinyl acetate ug/L 112100 112 40-160
Vinyl chloride ug/L 50.050 100 58-137
Xylene (Total)ug/L 146150 97 81-126
1,2-Dichloroethane-d4 (S)%95 70-130
4-Bromofluorobenzene (S)%98 70-130
Toluene-d8 (S)%100 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1893560MATRIX SPIKE SAMPLE:
MSSpike
Result
92323615001
1,1,1,2-Tetrachloroethane ug/L 20.020 100 70-130ND
1,1,1-Trichloroethane ug/L 22.220 111 70-130ND
1,1,2,2-Tetrachloroethane ug/L 20.920 104 70-130ND
1,1,2-Trichloroethane ug/L 21.220 106 70-130ND
1,1-Dichloroethane ug/L 23.620 118 70-130ND
1,1-Dichloroethene ug/L 25.520 127 70-166ND
1,2,3-Trichloropropane ug/L 19.720 98 70-130ND
1,2-Dibromo-3-chloropropane ug/L 19.820 99 70-130ND
1,2-Dibromoethane (EDB)ug/L 20.520 103 70-130ND
1,2-Dichlorobenzene ug/L 20.720 103 70-130ND
1,2-Dichloroethane ug/L 21.020 104 70-130ND
1,2-Dichloropropane ug/L 22.620 113 70-130ND
1,4-Dichlorobenzene ug/L 20.120 100 70-130ND
2-Butanone (MEK)ug/L 49.7J40 124 70-130ND
2-Hexanone ug/L 46.4J40 116 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 45.5J40 114 70-130ND
Acetone ug/L 48.1J40 115 70-130ND
Acrylonitrile ug/L 128J100 128 70-130ND
REPORT OF LABORATORY ANALYSIS
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Page 17 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1893560MATRIX SPIKE SAMPLE:
MSSpike
Result
92323615001
Benzene ug/L 22.820 114 70-148ND
Bromochloromethane ug/L 22.220 111 70-130ND
Bromodichloromethane ug/L 21.420 107 70-130ND
Bromoform ug/L 18.520 92 70-130ND
Bromomethane ug/L 19.520 98 70-130ND
Carbon disulfide ug/L 26.8J M120134 70-130ND
Carbon tetrachloride ug/L 20.920 104 70-130ND
Chlorobenzene ug/L 21.020 105 70-146ND
Chloroethane ug/L 24.320 121 70-130ND
Chloroform ug/L 22.920 115 70-130ND
Chloromethane ug/L 23.820 119 70-130ND
cis-1,2-Dichloroethene ug/L 23.320 116 70-130ND
cis-1,3-Dichloropropene ug/L 20.320 101 70-130ND
Dibromochloromethane ug/L 20.220 101 70-130ND
Dibromomethane ug/L 20.020 100 70-130ND
Dichlorodifluoromethane ug/L 19.220 96 70-130ND
Ethylbenzene ug/L 21.320 107 70-130ND
Iodomethane ug/L 40.940 102 70-130ND
Methylene Chloride ug/L 22.820 114 70-130ND
Styrene ug/L 20.820 104 70-130ND
Tetrachloroethene ug/L 19.220 96 70-130ND
Tetrahydrofuran ug/L 263 M1200131 70-130ND
Toluene ug/L 21.920 109 70-155ND
trans-1,2-Dichloroethene ug/L 24.820 124 70-130ND
trans-1,3-Dichloropropene ug/L 20.420 102 70-130ND
trans-1,4-Dichloro-2-butene ug/L 18.1J20 91 70-130ND
Trichloroethene ug/L 21.120 106 69-151ND
Trichlorofluoromethane ug/L 25.020 125 70-130ND
Vinyl acetate ug/L 39.1J40 98 70-130ND
Vinyl chloride ug/L 20.620 103 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%97 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323615002
1893561SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 2.7J 4 302.6J
1,1-Dichloroethene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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Page 18 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323615002
1893561SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Benzene ug/L ND 30ND
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L ND 30ND
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 0.46J 300.43J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L 0.49J 30ND
Tetrahydrofuran ug/L ND 30ND
Toluene ug/L ND 30ND
trans-1,2-Dichloroethene ug/L ND 30ND
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.49J 300.52J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L ND 30ND
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 2102
4-Bromofluorobenzene (S)%95 094
Toluene-d8 (S)%100 1101
REPORT OF LABORATORY ANALYSIS
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Page 19 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341799
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples: 92323615001, 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1896365
Associated Lab Samples:92323615001, 92323615002, 92323615003
Matrix: Water
AnalyzedMDL
alpha-BHC ug/L ND 0.050 12/22/16 17:160.050
beta-BHC ug/L ND 0.050 12/22/16 17:160.050
Decachlorobiphenyl (S)%104 20-130 12/22/16 17:16
Tetrachloro-m-xylene (S)%88 20-130 12/22/16 17:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
alpha-BHC ug/L 0.24.25 97 20-150
beta-BHC ug/L 0.25.25 102 20-150
Decachlorobiphenyl (S)%91 20-130
Tetrachloro-m-xylene (S)%94 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896367MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896368
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
alpha-BHC ug/L .5 89 20-15096 7 30.5ND 0.44 0.47
beta-BHC ug/L .5 103 20-150106 2 30.5ND 0.51 0.52
Decachlorobiphenyl (S)%85 20-13088
Tetrachloro-m-xylene (S)%89 20-130100
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 20 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323615001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900210
Associated Lab Samples:92323615001
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDND ND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 21 of 27
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342534
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples: 92323615002, 92323615003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK: 1900216
Associated Lab Samples:92323615002, 92323615003
Matrix: Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:484.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900217LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 100100 100 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900218MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323615002
1900219
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 98 75-12594 5 10100ND99.7 95.1
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900220MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1900221
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L R110010475-12592 11 10100ND105 94.0
REPORT OF LABORATORY ANALYSIS
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[phone]
Page 22 of 27
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323615
Johns R. Surface Water
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported foreach analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
ANALYTE QUALIFIERS
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
RPD value was outside control limits.R1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 23 of 27
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323615
Johns R. Surface Water
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323615001 341799 3422261203-SMP5 EPA 3510 EPA 8081
92323615002 341799 3422261203-SMP6 EPA 3510 EPA 8081
92323615003 341799 3422261203-SMP7 EPA 3510 EPA 8081
92323615001 341173 3415711203-SMP5 EPA 3010A EPA 6010
92323615002 341173 3415711203-SMP6 EPA 3010A EPA 6010
92323615003 341173 3415711203-SMP7 EPA 3010A EPA 6010
92323615001 341661 3419801203-SMP5 EPA 7470 EPA 7470
92323615002 341661 3419801203-SMP6 EPA 7470 EPA 7470
92323615003 341661 3419801203-SMP7 EPA 7470 EPA 7470
92323615001 3412941203-SMP5 EPA 8260
92323615002 3412941203-SMP6 EPA 8260
92323615003 3412941203-SMP7 EPA 8260
92323615001 3425331203-SMP5 SM 4500-CN-E
92323615002 3425341203-SMP6 SM 4500-CN-E
92323615003 3425341203-SMP7 SM 4500-CN-E
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/27/2016 05:06 PM
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Page 24 of 27
Page 25 of 27
Page 26 of 27
Page 27 of 27
#=CL#
December 28, 2016
LIMS USE: FR - VAN BURBACH
LIMS OBJECT ID: 92323613
92323613
Project:
Pace Project No.:
RE:
Mr. Van Burbach
Joyce Engineering-Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
Burke Co. Johns R. Blanks
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2016.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
cc:Alex Everhart, Joyce Engineering-NC
REPORT OF LABORATORY ANALYSIS
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Page 1 of 45
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 45
#=SS#
SAMPLE SUMMARY
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID Matrix Date Collected Date Received
92323613001 1203-Field Blank Water 12/14/16 14:30 12/15/16 10:10
92323613002 1203-Trip Blank Water 12/13/16 07:00 12/15/16 10:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 45
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92323613001 1203-Field Blank EPA 8081 21 PASI-CSWB
EPA 8082 8 PASI-CSWB
EPA 8151 5 PASI-OLJM
EPA 6010 18 PASI-ASH1
EPA 7470 1 PASI-ASER
EPA 8270 111 PASI-CBPJ
EPA 8260 67 PASI-CCAH
SM 4500-S2D 1 PASI-AEWS
SM 4500-CN-E 1 PASI-ADMN
92323613002 1203-Trip Blank EPA 8260 67 PASI-CCAH
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 4 of 45
#=HO#
SUMMARY OF DETECTION
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Parameters AnalyzedResult
Lab Sample ID
Report Limit QualifiersUnitsMethod
Client Sample ID
92323613001 1203-Field Blank
Chloromethane 0.17J ug/L 12/21/16 20:261.0EPA 8260
Naphthalene 0.26J ug/L 12/21/16 20:2610.0EPA 8260
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 5 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8081 Preparation Method: EPA 35108081 Organochlorine Pesticides
Aldrin ND ug/L 12/22/16 16:05 309-00-212/20/16 16:160.050 0.050 1
alpha-BHC ND ug/L 12/22/16 16:05 319-84-612/20/16 16:160.050 0.050 1
beta-BHC ND ug/L 12/22/16 16:05 319-85-712/20/16 16:160.050 0.050 1
delta-BHC ND ug/L 12/22/16 16:05 319-86-812/20/16 16:160.050 0.050 1
gamma-BHC (Lindane)ND ug/L 12/22/16 16:05 58-89-912/20/16 16:160.050 0.050 1
Chlordane (Technical)ND ug/L 12/22/16 16:05 57-74-912/20/16 16:160.50 0.20 1
4,4'-DDD ND ug/L 12/22/16 16:05 72-54-812/20/16 16:160.10 0.050 1
4,4'-DDE ND ug/L 12/22/16 16:05 72-55-912/20/16 16:160.10 0.050 1
4,4'-DDT ND ug/L 12/22/16 16:05 50-29-312/20/16 16:160.10 0.050 1
Dieldrin ND ug/L 12/22/16 16:05 60-57-112/20/16 16:160.075 0.050 1
Endosulfan I ND ug/L 12/22/16 16:05 959-98-812/20/16 16:160.10 0.050 1
Endosulfan II ND ug/L 12/22/16 16:05 33213-65-912/20/16 16:160.10 0.050 1
Endosulfan sulfate ND ug/L 12/22/16 16:05 1031-07-812/20/16 16:160.10 0.050 1
Endrin ND ug/L 12/22/16 16:05 72-20-812/20/16 16:160.10 0.050 1
Endrin aldehyde ND ug/L 12/22/16 16:05 7421-93-412/20/16 16:160.10 0.050 1
Heptachlor ND ug/L 12/22/16 16:05 76-44-812/20/16 16:160.050 0.050 1
Heptachlor epoxide ND ug/L 12/22/16 16:05 1024-57-312/20/16 16:160.075 0.050 1
Methoxychlor ND ug/L 12/22/16 16:05 72-43-512/20/16 16:161.0 0.15 1
Toxaphene ND ug/L 12/22/16 16:05 8001-35-212/20/16 16:161.5 0.20 1
Surrogates
Tetrachloro-m-xylene (S)106 %12/22/16 16:05 877-09-812/20/16 16:1620-130 1
Decachlorobiphenyl (S)98 %12/22/16 16:05 2051-24-312/20/16 16:1620-130 1
Analytical Method: EPA 8082 Preparation Method: EPA 35108082 GCS PCB
PCB-1016 (Aroclor 1016)ND ug/L 12/20/16 20:30 12674-11-212/16/16 11:530.50 0.50 1
PCB-1221 (Aroclor 1221)ND ug/L 12/20/16 20:30 11104-28-212/16/16 11:530.50 0.50 1
PCB-1232 (Aroclor 1232)ND ug/L 12/20/16 20:30 11141-16-512/16/16 11:530.50 0.50 1
PCB-1242 (Aroclor 1242)ND ug/L 12/20/16 20:30 53469-21-912/16/16 11:530.50 0.50 1
PCB-1248 (Aroclor 1248)ND ug/L 12/20/16 20:30 12672-29-612/16/16 11:530.50 0.50 1
PCB-1254 (Aroclor 1254)ND ug/L 12/20/16 20:30 11097-69-112/16/16 11:530.50 0.50 1
PCB-1260 (Aroclor 1260)ND ug/L 12/20/16 20:30 11096-82-512/16/16 11:530.50 0.50 1
Surrogates
Decachlorobiphenyl (S)49 %12/20/16 20:30 2051-24-312/16/16 11:5310-132 1
Analytical Method: EPA 8151 Preparation Method: EPA 81518151 Chlorinated Herbicides
2,4-D ND ug/L 12/23/16 08:40 94-75-7 H212/22/16 07:300.94 0.22 1
Dinoseb ND ug/L 12/23/16 08:40 88-85-7 H212/22/16 07:300.19 0.057 1
2,4,5-T ND ug/L 12/23/16 08:40 93-76-5 H212/22/16 07:300.19 0.042 1
2,4,5-TP (Silvex)ND ug/L 12/23/16 08:40 93-72-1 H212/22/16 07:300.19 0.049 1
Surrogates
2,4-DCAA (S)79 %12/23/16 08:40 19719-28-912/22/16 07:3039-139 1
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Antimony ND ug/L 12/23/16 21:47 7440-36-012/17/16 01:006.0 3.8 1
Arsenic ND ug/L 12/23/16 06:31 7440-38-212/17/16 01:0010.0 2.5 1
Barium ND ug/L 12/23/16 06:31 7440-39-312/17/16 01:001002.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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[phone]
Page 6 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 6010 Preparation Method: EPA 3010A6010 ICP Groundwater
Beryllium ND ug/L 12/23/16 06:31 7440-41-712/17/16 01:001.0 0.50 1
Cadmium ND ug/L 12/23/16 21:47 7440-43-912/17/16 01:001.0 0.50 1
Chromium ND ug/L 12/23/16 06:31 7440-47-312/17/16 01:0010.0 2.5 1
Cobalt ND ug/L 12/23/16 06:31 7440-48-412/17/16 01:0010.0 2.5 1
Copper ND ug/L 12/23/16 06:31 7440-50-812/17/16 01:0010.0 2.5 1
Iron ND ug/L 12/23/16 06:31 7439-89-612/17/16 01:0030025.0 1
Lead ND ug/L 12/23/16 21:47 7439-92-112/17/16 01:0010.0 2.5 1
Manganese ND ug/L 12/23/16 06:31 7439-96-512/17/16 01:0050.0 2.5 1
Nickel ND ug/L 12/23/16 21:47 7440-02-012/17/16 01:0050.0 2.5 1
Selenium ND ug/L 12/23/16 06:31 7782-49-212/17/16 01:0010.0 5.0 1
Silver ND ug/L 12/23/16 06:31 7440-22-412/17/16 01:0010.0 2.5 1
Thallium ND ug/L 12/23/16 06:31 7440-28-012/17/16 01:005.5 5.0 1
Tin ND ug/L 12/23/16 06:31 7440-31-512/17/16 01:001002.5 1
Vanadium ND ug/L 12/23/16 06:31 7440-62-212/17/16 01:0025.0 2.5 1
Zinc ND ug/L 12/23/16 06:31 7440-66-612/17/16 01:0010.0 5.0 1
Analytical Method: EPA 7470 Preparation Method: EPA 74707470 Mercury
Mercury ND ug/L 12/25/16 13:04 7439-97-612/24/16 03:000.20 0.10 1
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Acenaphthene ND ug/L 12/22/16 19:23 83-32-912/20/16 17:2810.0 0.25 1
Acenaphthylene ND ug/L 12/22/16 19:23 208-96-812/20/16 17:2810.0 0.21 1
Acetophenone ND ug/L 12/22/16 19:23 98-86-212/20/16 17:2810.0 2.0 1
2-Acetylaminofluorene ND ug/L 12/22/16 19:23 53-96-312/20/16 17:2820.0 0.84 1
4-Aminobiphenyl ND ug/L 12/22/16 19:23 92-67-112/20/16 17:2820.0 0.92 1
Anthracene ND ug/L 12/22/16 19:23 120-12-712/20/16 17:2810.0 0.14 1
Benzo(a)anthracene ND ug/L 12/22/16 19:23 56-55-312/20/16 17:2810.0 0.33 1
Benzo(a)pyrene ND ug/L 12/22/16 19:23 50-32-812/20/16 17:2810.0 0.30 1
Benzo(b)fluoranthene ND ug/L 12/22/16 19:23 205-99-212/20/16 17:2810.0 0.28 1
Benzo(g,h,i)perylene ND ug/L 12/22/16 19:23 191-24-212/20/16 17:2810.0 0.38 1
Benzo(k)fluoranthene ND ug/L 12/22/16 19:23 207-08-912/20/16 17:2810.0 0.43 1
Benzyl alcohol ND ug/L 12/22/16 19:23 100-51-612/20/16 17:2820.0 3.4 1
4-Bromophenylphenyl ether ND ug/L 12/22/16 19:23 101-55-312/20/16 17:2810.0 1.3 1
Butylbenzylphthalate ND ug/L 12/22/16 19:23 85-68-712/20/16 17:2810.0 0.75 1
4-Chloro-3-methylphenol ND ug/L 12/22/16 19:23 59-50-712/20/16 17:2820.0 4.2 1
4-Chloroaniline ND ug/L 12/22/16 19:23 106-47-812/20/16 17:2820.0 3.4 1
Chlorobenzilate ND ug/L 12/22/16 19:23 510-15-612/20/16 17:2810.0 0.72 1
bis(2-Chloroethoxy)methane ND ug/L 12/22/16 19:23 111-91-112/20/16 17:2810.0 1.7 1
bis(2-Chloroethyl) ether ND ug/L 12/22/16 19:23 111-44-412/20/16 17:2810.0 1.5 1
2-Chloronaphthalene ND ug/L 12/22/16 19:23 91-58-712/20/16 17:2810.0 2.2 1
2-Chlorophenol ND ug/L 12/22/16 19:23 95-57-812/20/16 17:2810.0 1.5 1
4-Chlorophenylphenyl ether ND ug/L 12/22/16 19:23 7005-72-312/20/16 17:2810.0 2.1 1
Chrysene ND ug/L 12/22/16 19:23 218-01-912/20/16 17:2810.0 0.21 1
Diallate ND ug/L 12/22/16 19:23 2303-16-412/20/16 17:2810.0 1.3 1
Dibenz(a,h)anthracene ND ug/L 12/22/16 19:23 53-70-312/20/16 17:2810.0 0.55 1
Dibenzofuran ND ug/L 12/22/16 19:23 132-64-912/20/16 17:2810.0 1.8 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 7 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
3,3'-Dichlorobenzidine ND ug/L 12/22/16 19:23 91-94-112/20/16 17:2820.0 1.4 1
2,4-Dichlorophenol ND ug/L 12/22/16 19:23 120-83-212/20/16 17:2810.0 1.7 1
2,6-Dichlorophenol ND ug/L 12/22/16 19:23 87-65-012/20/16 17:2810.0 1.8 1
Diethylphthalate ND ug/L 12/22/16 19:23 84-66-212/20/16 17:2860001.3 1
Dimethoate ND ug/L 12/22/16 19:23 60-51-512/20/16 17:2820.0 0.92 1
P-Dimethylaminoazobenzene ND ug/L 12/22/16 19:23 60-11-712/20/16 17:2810.0 0.35 1
7,12-Dimethylbenz(a)anthracene ND ug/L 12/22/16 19:23 57-97-612/20/16 17:2810.0 0.77 1
3,3'-Dimethylbenzidine ND ug/L 12/22/16 19:23 119-93-712/20/16 17:2810.0 2.1 1
2,4-Dimethylphenol ND ug/L 12/22/16 19:23 105-67-912/20/16 17:2810.0 2.2 1
Dimethylphthalate ND ug/L 12/22/16 19:23 131-11-312/20/16 17:2810.0 1.5 1
Di-n-butylphthalate ND ug/L 12/22/16 19:23 84-74-212/20/16 17:2810.0 1.1 1
4,6-Dinitro-2-methylphenol ND ug/L 12/22/16 19:23 534-52-112/20/16 17:2850.0 1.7 1
1,3-Dinitrobenzene ND ug/L 12/22/16 19:23 99-65-012/20/16 17:2820.0 1.5 1
2,4-Dinitrophenol ND ug/L 12/22/16 19:23 51-28-512/20/16 17:2850.0 6.5 1
2,4-Dinitrotoluene ND ug/L 12/22/16 19:23 121-14-212/20/16 17:2810.0 1.2 1
2,6-Dinitrotoluene ND ug/L 12/22/16 19:23 606-20-212/20/16 17:2810.0 1.7 1
Di-n-octylphthalate ND ug/L 12/22/16 19:23 117-84-012/20/16 17:2810.0 0.86 1
Diphenylamine ND ug/L 12/22/16 19:23 122-39-412/20/16 17:2810.0 1.3 1
Disulfoton ND ug/L 12/22/16 19:23 298-04-412/20/16 17:2810.0 1.4 1
bis(2-Ethylhexyl)phthalate ND ug/L 12/22/16 19:23 117-81-712/20/16 17:2815.0 0.85 1
Ethyl methanesulfonate ND ug/L 12/22/16 19:23 62-50-012/20/16 17:2820.0 1.8 1
Famphur ND ug/L 12/22/16 19:23 52-85-712/20/16 17:2820.0 1.7 1
Fluoranthene ND ug/L 12/22/16 19:23 206-44-012/20/16 17:2810.0 0.21 1
Fluorene ND ug/L 12/22/16 19:23 86-73-712/20/16 17:2810.0 0.21 1
Hexachlorobenzene ND ug/L 12/22/16 19:23 118-74-112/20/16 17:2810.0 1.1 1
Hexachlorocyclopentadiene ND ug/L 12/22/16 19:23 77-47-412/20/16 17:2810.0 1.8 1
Hexachloroethane ND ug/L 12/22/16 19:23 67-72-112/20/16 17:2810.0 1.5 1
Hexachloropropene ND ug/L 12/22/16 19:23 1888-71-712/20/16 17:2810.0 1.6 1
Indeno(1,2,3-cd)pyrene ND ug/L 12/22/16 19:23 193-39-512/20/16 17:2810.0 0.29 1
Isodrin ND ug/L 12/22/16 19:23 465-73-612/20/16 17:2820.0 2.0 1
Isophorone ND ug/L 12/22/16 19:23 78-59-112/20/16 17:2810.0 1.8 1
Isosafrole ND ug/L 12/22/16 19:23 120-58-112/20/16 17:2810.0 1.8 1
Kepone ND ug/L 12/22/16 19:23 143-50-012/20/16 17:2820.0 3.1 1
Methapyrilene ND ug/L 12/22/16 19:23 91-80-512/20/16 17:281002.7 1
3-Methylcholanthrene ND ug/L 12/22/16 19:23 56-49-512/20/16 17:2810.0 0.82 1
Methyl methanesulfonate ND ug/L 12/22/16 19:23 66-27-312/20/16 17:2810.0 1.3 1
2-Methylnaphthalene ND ug/L 12/22/16 19:23 91-57-612/20/16 17:2810.0 0.28 1
Methyl parathion ND ug/L 12/22/16 19:23 298-00-012/20/16 17:2810.0 1.1 1
2-Methylphenol(o-Cresol)ND ug/L 12/22/16 19:23 95-48-712/20/16 17:2810.0 1.7 1
3&4-Methylphenol(m&p Cresol)ND ug/L 12/22/16 19:2312/20/16 17:2810.0 1.7 1
1-Naphthalenamine ND ug/L 12/22/16 19:23 134-32-712/20/16 17:2810.0 0.96 1
2-Naphthalenamine ND ug/L 12/22/16 19:23 91-59-812/20/16 17:2810.0 0.98 1
1,4-Naphthoquinone ND ug/L 12/22/16 19:23 130-15-412/20/16 17:2810.0 1.8 1
2-Nitroaniline ND ug/L 12/22/16 19:23 88-74-412/20/16 17:2850.0 2.8 1
3-Nitroaniline ND ug/L 12/22/16 19:23 99-09-212/20/16 17:2850.0 2.4 1
4-Nitroaniline ND ug/L 12/22/16 19:23 100-01-612/20/16 17:2820.0 2.5 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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[phone]
Page 8 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 8270 Preparation Method: EPA 35108270 MSSV Semivolatile Organic
Nitrobenzene ND ug/L 12/22/16 19:23 98-95-312/20/16 17:2810.0 1.7 1
2-Nitrophenol ND ug/L 12/22/16 19:23 88-75-512/20/16 17:2810.0 1.7 1
4-Nitrophenol ND ug/L 12/22/16 19:23 100-02-712/20/16 17:2850.0 5.8 1
5-Nitro-o-toluidine ND ug/L 12/22/16 19:23 99-55-812/20/16 17:2810.0 1.2 1
N-Nitrosodiethylamine ND ug/L 12/22/16 19:23 55-18-512/20/16 17:2820.0 1.8 1
N-Nitrosodimethylamine ND ug/L 12/22/16 19:23 62-75-912/20/16 17:2810.0 1.3 1
N-Nitroso-di-n-butylamine ND ug/L 12/22/16 19:23 924-16-312/20/16 17:2810.0 2.2 1
N-Nitroso-di-n-propylamine ND ug/L 12/22/16 19:23 621-64-712/20/16 17:2810.0 2.1 1
N-Nitrosodiphenylamine ND ug/L 12/22/16 19:23 86-30-612/20/16 17:2810.0 1.3 1
N-Nitrosomethylethylamine ND ug/L 12/22/16 19:23 10595-95-612/20/16 17:2810.0 1.8 1
N-Nitrosopiperidine ND ug/L 12/22/16 19:23 100-75-412/20/16 17:2820.0 1.9 1
N-Nitrosopyrrolidine ND ug/L 12/22/16 19:23 930-55-212/20/16 17:2810.0 2.5 1
O,O,O-Triethylphosphorothioate ND ug/L 12/22/16 19:23 126-68-112/20/16 17:2810.0 1.8 1
2,2'-Oxybis(1-chloropropane)ND ug/L 12/22/16 19:23 108-60-112/20/16 17:2810.0 1.6 1
Parathion (Ethyl parathion)ND ug/L 12/22/16 19:23 56-38-212/20/16 17:2810.0 1.1 1
Pentachlorobenzene ND ug/L 12/22/16 19:23 608-93-512/20/16 17:2810.0 2.0 1
Pentachloronitrobenzene ND ug/L 12/22/16 19:23 82-68-812/20/16 17:2820.0 1.0 1
Pentachlorophenol ND ug/L 12/22/16 19:23 87-86-512/20/16 17:2825.0 2.3 1
Phenacetin ND ug/L 12/22/16 19:23 62-44-212/20/16 17:2820.0 0.97 1
Phenanthrene ND ug/L 12/22/16 19:23 85-01-812/20/16 17:2810.0 0.22 1
Phenol ND ug/L 12/22/16 19:2312/20/16 17:2810.0 1.7 1
p-Phenylenediamine ND ug/L 12/22/16 19:23 106-50-312/20/16 17:2810.0 0.96 1
Phorate ND ug/L 12/22/16 19:23 298-02-212/20/16 17:2810.0 1.1 1
Pronamide ND ug/L 12/22/16 19:23 23950-58-512/20/16 17:2810.0 0.97 1
Pyrene ND ug/L 12/22/16 19:23 129-00-012/20/16 17:2810.0 0.19 1
Safrole ND ug/L 12/22/16 19:23 94-59-712/20/16 17:2810.0 1.5 1
1,2,4,5-Tetrachlorobenzene ND ug/L 12/22/16 19:23 95-94-312/20/16 17:2810.0 1.7 1
2,3,4,6-Tetrachlorophenol ND ug/L 12/22/16 19:23 58-90-212/20/16 17:2810.0 2.3 1
Thionazin ND ug/L 12/22/16 19:23 297-97-212/20/16 17:2820.0 1.2 1
O-Toluidine ND ug/L 12/22/16 19:23 95-53-412/20/16 17:2810.0 1.6 1
2,4,5-Trichlorophenol ND ug/L 12/22/16 19:23 95-95-412/20/16 17:2810.0 2.2 1
2,4,6-Trichlorophenol ND ug/L 12/22/16 19:23 88-06-212/20/16 17:2810.0 1.9 1
1,3,5-Trinitrobenzene ND ug/L 12/22/16 19:23 99-35-412/20/16 17:2810.0 1.1 1
Surrogates
Nitrobenzene-d5 (S)58 %12/22/16 19:23 4165-60-012/20/16 17:2821-110 1
2-Fluorobiphenyl (S)68 %12/22/16 19:23 321-60-812/20/16 17:2827-110 1
Terphenyl-d14 (S)71 %12/22/16 19:23 1718-51-012/20/16 17:2831-107 1
Phenol-d6 (S)16 %12/22/16 19:23 13127-88-312/20/16 17:2810-110 1
2-Fluorophenol (S)26 %12/22/16 19:23 367-12-412/20/16 17:2812-110 1
2,4,6-Tribromophenol (S)70 %12/22/16 19:23 118-79-612/20/16 17:2827-110 1
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 20:26 67-64-110010.0 1
Acetonitrile ND ug/L 12/21/16 20:26 75-05-855.0 2.2 1
Acrolein ND ug/L 12/21/16 20:26 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/21/16 20:26 107-13-12001.9 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
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Page 9 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Allyl chloride ND ug/L 12/21/16 20:26 107-05-110.0 1.5 1
Benzene ND ug/L 12/21/16 20:26 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 20:26 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 20:26 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 20:26 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/21/16 20:26 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 20:26 78-93-31000.96 1
Carbon disulfide ND ug/L 12/21/16 20:26 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/21/16 20:26 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 20:26 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/21/16 20:26 75-00-310.0 0.54 1
Chloroform ND ug/L 12/21/16 20:26 67-66-35.0 0.14 1
Chloromethane 0.17J ug/L 12/21/16 20:26 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/21/16 20:26 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 20:26 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 20:26 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 20:26 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 20:26 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 20:26 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/21/16 20:26 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/21/16 20:26 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 20:26 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/21/16 20:26 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/21/16 20:26 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 20:26 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 20:26 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 20:26 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 20:26 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/21/16 20:26 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/21/16 20:26 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/21/16 20:26 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/21/16 20:26 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 20:26 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 20:26 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 20:26 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/21/16 20:26 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/21/16 20:26 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/21/16 20:26 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/21/16 20:26 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/21/16 20:26 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/21/16 20:26 126-98-71000.93 1
Methylene Chloride ND ug/L 12/21/16 20:26 75-09-21.0 0.97 1
Methyl methacrylate ND ug/L 12/21/16 20:26 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 20:26 108-10-11000.33 1
Naphthalene 0.26J ug/L 12/21/16 20:26 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/21/16 20:26 107-12-01503.6 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Page 10 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Field Blank Lab ID:92323613001 Collected:12/14/16 14:30 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Styrene ND ug/L 12/21/16 20:26 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 20:26 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 20:26 79-34-5 L23.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 20:26 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 20:26 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/21/16 20:26 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/21/16 20:26 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 20:26 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 20:26 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 20:26 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 20:26 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 20:26 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 20:26 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 20:26 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)107 %12/21/16 20:26 460-00-470-130 1
1,2-Dichloroethane-d4 (S)101 %12/21/16 20:26 17060-07-070-130 1
Toluene-d8 (S)99 %12/21/16 20:26 2037-26-570-130 1
Analytical Method: SM 4500-S2D4500S2D Sulfide Water
Sulfide ND ug/L 12/20/16 15:05 18496-25-810001001
Analytical Method: SM 4500-CN-E4500CNE Cyanide, Total
Cyanide ND ug/L 12/27/16 14:46 57-12-510.0 4.0 1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Page 11 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Trip Blank Lab ID:92323613002 Collected:12/13/16 07:00 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Acetone ND ug/L 12/21/16 20:43 67-64-110010.0 1
Acetonitrile ND ug/L 12/21/16 20:43 75-05-855.0 2.2 1
Acrolein ND ug/L 12/21/16 20:43 107-02-853.0 1.6 1
Acrylonitrile ND ug/L 12/21/16 20:43 107-13-12001.9 1
Allyl chloride ND ug/L 12/21/16 20:43 107-05-110.0 1.5 1
Benzene ND ug/L 12/21/16 20:43 71-43-21.0 0.25 1
Bromochloromethane ND ug/L 12/21/16 20:43 74-97-53.0 0.17 1
Bromodichloromethane ND ug/L 12/21/16 20:43 75-27-41.0 0.18 1
Bromoform ND ug/L 12/21/16 20:43 75-25-23.0 0.26 1
Bromomethane ND ug/L 12/21/16 20:43 74-83-910.0 0.29 1
2-Butanone (MEK)ND ug/L 12/21/16 20:43 78-93-31000.96 1
Carbon disulfide ND ug/L 12/21/16 20:43 75-15-01001.2 1
Carbon tetrachloride ND ug/L 12/21/16 20:43 56-23-51.0 0.25 1
Chlorobenzene ND ug/L 12/21/16 20:43 108-90-73.0 0.23 1
Chloroethane ND ug/L 12/21/16 20:43 75-00-310.0 0.54 1
Chloroform ND ug/L 12/21/16 20:43 67-66-35.0 0.14 1
Chloromethane ND ug/L 12/21/16 20:43 74-87-31.0 0.11 1
Chloroprene ND ug/L 12/21/16 20:43 126-99-820.0 0.27 1
1,2-Dibromo-3-chloropropane ND ug/L 12/21/16 20:43 96-12-813.0 2.0 1
Dibromochloromethane ND ug/L 12/21/16 20:43 124-48-13.0 0.21 1
1,2-Dibromoethane (EDB)ND ug/L 12/21/16 20:43 106-93-41.0 0.27 1
Dibromomethane ND ug/L 12/21/16 20:43 74-95-310.0 0.21 1
1,2-Dichlorobenzene ND ug/L 12/21/16 20:43 95-50-15.0 0.30 1
1,3-Dichlorobenzene ND ug/L 12/21/16 20:43 541-73-15.0 0.24 1
1,4-Dichlorobenzene ND ug/L 12/21/16 20:43 106-46-71.0 0.33 1
trans-1,4-Dichloro-2-butene ND ug/L 12/21/16 20:43 110-57-61001.0 1
Dichlorodifluoromethane ND ug/L 12/21/16 20:43 75-71-85.0 0.21 1
1,1-Dichloroethane ND ug/L 12/21/16 20:43 75-34-35.0 0.32 1
1,2-Dichloroethane ND ug/L 12/21/16 20:43 107-06-21.0 0.24 1
1,1-Dichloroethene ND ug/L 12/21/16 20:43 75-35-45.0 0.56 1
cis-1,2-Dichloroethene ND ug/L 12/21/16 20:43 156-59-25.0 0.19 1
trans-1,2-Dichloroethene ND ug/L 12/21/16 20:43 156-60-55.0 0.49 1
1,2-Dichloropropane ND ug/L 12/21/16 20:43 78-87-51.0 0.27 1
1,3-Dichloropropane ND ug/L 12/21/16 20:43 142-28-91.0 0.28 1
2,2-Dichloropropane ND ug/L 12/21/16 20:43 594-20-715.0 0.13 1
1,1-Dichloropropene ND ug/L 12/21/16 20:43 563-58-65.0 0.49 1
cis-1,3-Dichloropropene ND ug/L 12/21/16 20:43 10061-01-51.0 0.13 1
trans-1,3-Dichloropropene ND ug/L 12/21/16 20:43 10061-02-61.0 0.26 1
Ethylbenzene ND ug/L 12/21/16 20:43 100-41-41.0 0.30 1
Ethyl methacrylate ND ug/L 12/21/16 20:43 97-63-210.0 0.20 1
Hexachloro-1,3-butadiene ND ug/L 12/21/16 20:43 87-68-310.0 0.71 1
2-Hexanone ND ug/L 12/21/16 20:43 591-78-650.0 0.46 1
Iodomethane ND ug/L 12/21/16 20:43 74-88-410.0 0.32 1
Isobutanol ND ug/L 12/21/16 20:43 78-83-110035.0 1
Methacrylonitrile ND ug/L 12/21/16 20:43 126-98-71000.93 1
Methylene Chloride ND ug/L 12/21/16 20:43 75-09-21.0 0.97 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 12 of 45
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Sample:1203-Trip Blank Lab ID:92323613002 Collected:12/13/16 07:00 Received:12/15/16 10:10 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualMDLLimit
Report
Analytical Method: EPA 82608260 MSV Low Level Landfill
Methyl methacrylate ND ug/L 12/21/16 20:43 80-62-630.0 2.0 1
4-Methyl-2-pentanone (MIBK)ND ug/L 12/21/16 20:43 108-10-11000.33 1
Naphthalene ND ug/L 12/21/16 20:43 91-20-310.0 0.24 1
Propionitrile ND ug/L 12/21/16 20:43 107-12-01503.6 1
Styrene ND ug/L 12/21/16 20:43 100-42-51.0 0.26 1
1,1,1,2-Tetrachloroethane ND ug/L 12/21/16 20:43 630-20-65.0 0.33 1
1,1,2,2-Tetrachloroethane ND ug/L 12/21/16 20:43 79-34-5 L23.0 0.40 1
Tetrachloroethene ND ug/L 12/21/16 20:43 127-18-41.0 0.46 1
Toluene ND ug/L 12/21/16 20:43 108-88-31.0 0.26 1
1,2,4-Trichlorobenzene ND ug/L 12/21/16 20:43 120-82-110.0 0.35 1
1,1,1-Trichloroethane ND ug/L 12/21/16 20:43 71-55-61.0 0.48 1
1,1,2-Trichloroethane ND ug/L 12/21/16 20:43 79-00-51.0 0.29 1
Trichloroethene ND ug/L 12/21/16 20:43 79-01-61.0 0.47 1
Trichlorofluoromethane ND ug/L 12/21/16 20:43 75-69-41.0 0.20 1
1,2,3-Trichloropropane ND ug/L 12/21/16 20:43 96-18-41.0 0.41 1
Vinyl acetate ND ug/L 12/21/16 20:43 108-05-450.0 0.35 1
Vinyl chloride ND ug/L 12/21/16 20:43 75-01-41.0 0.62 1
Xylene (Total)ND ug/L 12/21/16 20:43 1330-20-75.0 0.66 1
Surrogates
4-Bromofluorobenzene (S)105 %12/21/16 20:43 460-00-470-130 1
1,2-Dichloroethane-d4 (S)100 %12/21/16 20:43 17060-07-070-130 1
Toluene-d8 (S)98 %12/21/16 20:43 2037-26-570-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 13 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341661
EPA 7470
EPA 7470
7470 Mercury
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1895623
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
Mercury ug/L ND 0.20 12/25/16 12:220.10
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1895624LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ug/L 2.52.5 102 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1895625MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323062024
1895626
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Mercury ug/L 2.5 101 75-125103 2 252.5ND 2.5 2.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 14 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341173
EPA 3010A
EPA 6010
6010 MET NC Groundwater
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1892896
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
Antimony ug/L ND 6.0 12/23/16 05:113.8
Arsenic ug/L ND 10.0 12/23/16 05:112.5
Barium ug/L ND 100 12/23/16 05:112.5
Beryllium ug/L ND 1.0 12/23/16 05:110.50
Cadmium ug/L ND 1.0 12/23/16 05:110.50
Chromium ug/L ND 10.0 12/23/16 05:112.5
Cobalt ug/L ND 10.0 12/23/16 05:112.5
Copper ug/L ND 10.0 12/23/16 05:112.5
Iron ug/L ND 300 12/23/16 05:1125.0
Lead ug/L ND 10.0 12/23/16 05:112.5
Manganese ug/L ND 50.0 12/23/16 05:112.5
Nickel ug/L ND 50.0 12/23/16 05:112.5
Selenium ug/L ND 10.0 12/23/16 05:115.0
Silver ug/L ND 10.0 12/23/16 05:112.5
Thallium ug/L ND 5.5 12/23/16 05:115.0
Tin ug/L ND 100 12/23/16 05:112.5
Vanadium ug/L ND 25.0 12/23/16 05:112.5
Zinc ug/L ND 10.0 12/23/16 05:115.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1892897LABORATORY CONTROL SAMPLE:
LCSSpike
Antimony ug/L 430500 86 80-120
Arsenic ug/L 435500 87 80-120
Barium ug/L 423500 85 80-120
Beryllium ug/L 443500 89 80-120
Cadmium ug/L 418500 84 80-120
Chromium ug/L 433500 87 80-120
Cobalt ug/L 429500 86 80-120
Copper ug/L 462500 92 80-120
Iron ug/L 44805000 90 80-120
Lead ug/L 426500 85 80-120
Manganese ug/L 442500 88 80-120
Nickel ug/L 406500 81 80-120
Selenium ug/L 446500 89 80-120
Silver ug/L 233250 93 80-120
Thallium ug/L 462500 92 80-120
Tin ug/L 430500 86 80-120
Vanadium ug/L 435500 87 80-120
Zinc ug/L 433500 87 80-120
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 15 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1892898MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323288001
1892899
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Antimony ug/L 500 98 75-125102 3 25500ND491508
Arsenic ug/L 500 78 75-12583 6 25500ND393415
Barium ug/L 500 76 75-12580 6 25500ND378402
Beryllium ug/L 500 79 75-12584 5 25500ND397418
Cadmium ug/L 500 76 75-12580 5 25500ND380402
Chromium ug/L 500 78 75-12582 6 25500ND388412
Cobalt ug/L 500 76 75-12581 7 25500ND381407
Copper ug/L 500 82 75-12587 6 25500ND413438
Iron ug/L 5000 80 75-12584 5 255000ND40104220
Lead ug/L 500 99 75-125103 3 25500ND497514
Manganese ug/L 500 79 75-12584 6 25500ND395419
Nickel ug/L M15007375-12577 6 25500ND364386
Selenium ug/L 500 81 75-12585 5 25500ND404425
Silver ug/L 250 88 75-12591 4 25250ND219227
Thallium ug/L 500 83 75-12589 6 255005.5J 422 448
Tin ug/L 500 77 75-12582 6 25500ND386411
Vanadium ug/L 500 78 75-12583 6 25500ND390413
Zinc ug/L 500 77 75-12583 7 25500ND387415
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 16 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342010
EPA 8260
EPA 8260
8260 MSV Low Level Landfill
Associated Lab Samples:92323613001, 92323613002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1897428
Associated Lab Samples:92323613001, 92323613002
Matrix:Water
AnalyzedMDL
1,1,1,2-Tetrachloroethane ug/L ND 5.0 12/21/16 16:270.33
1,1,1-Trichloroethane ug/L ND 1.0 12/21/16 16:270.48
1,1,2,2-Tetrachloroethane ug/L ND 3.0 12/21/16 16:270.40
1,1,2-Trichloroethane ug/L ND 1.0 12/21/16 16:270.29
1,1-Dichloroethane ug/L ND 5.0 12/21/16 16:270.32
1,1-Dichloroethene ug/L ND 5.0 12/21/16 16:270.56
1,1-Dichloropropene ug/L ND 5.0 12/21/16 16:270.49
1,2,3-Trichloropropane ug/L ND 1.0 12/21/16 16:270.41
1,2,4-Trichlorobenzene ug/L ND 10.0 12/21/16 16:270.35
1,2-Dibromo-3-chloropropane ug/L ND 13.0 12/21/16 16:272.0
1,2-Dibromoethane (EDB)ug/L ND 1.0 12/21/16 16:270.27
1,2-Dichlorobenzene ug/L ND 5.0 12/21/16 16:270.30
1,2-Dichloroethane ug/L ND 1.0 12/21/16 16:270.24
1,2-Dichloropropane ug/L ND 1.0 12/21/16 16:270.27
1,3-Dichlorobenzene ug/L ND 5.0 12/21/16 16:270.24
1,3-Dichloropropane ug/L ND 1.0 12/21/16 16:270.28
1,4-Dichlorobenzene ug/L ND 1.0 12/21/16 16:270.33
2,2-Dichloropropane ug/L ND 15.0 12/21/16 16:270.13
2-Butanone (MEK)ug/L ND 100 12/21/16 16:270.96
2-Hexanone ug/L ND 50.0 12/21/16 16:270.46
4-Methyl-2-pentanone (MIBK)ug/L ND 100 12/21/16 16:270.33
Acetone ug/L ND 100 12/21/16 16:2710.0
Acetonitrile ug/L ND 55.0 12/21/16 16:272.2
Acrolein ug/L ND 53.0 12/21/16 16:271.6
Acrylonitrile ug/L ND 200 12/21/16 16:271.9
Allyl chloride ug/L ND 10.0 12/21/16 16:271.5
Benzene ug/L ND 1.0 12/21/16 16:270.25
Bromochloromethane ug/L ND 3.0 12/21/16 16:270.17
Bromodichloromethane ug/L ND 1.0 12/21/16 16:270.18
Bromoform ug/L ND 3.0 12/21/16 16:270.26
Bromomethane ug/L ND 10.0 12/21/16 16:270.29
Carbon disulfide ug/L ND 100 12/21/16 16:271.2
Carbon tetrachloride ug/L ND 1.0 12/21/16 16:270.25
Chlorobenzene ug/L ND 3.0 12/21/16 16:270.23
Chloroethane ug/L ND 10.0 12/21/16 16:270.54
Chloroform ug/L ND 5.0 12/21/16 16:270.14
Chloromethane ug/L ND 1.0 12/21/16 16:270.11
Chloroprene ug/L ND 20.0 12/21/16 16:270.27
cis-1,2-Dichloroethene ug/L ND 5.0 12/21/16 16:270.19
cis-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.13
Dibromochloromethane ug/L ND 3.0 12/21/16 16:270.21
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 17 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1897428
Associated Lab Samples:92323613001, 92323613002
Matrix:Water
AnalyzedMDL
Dibromomethane ug/L ND 10.0 12/21/16 16:270.21
Dichlorodifluoromethane ug/L ND 5.0 12/21/16 16:270.21
Ethyl methacrylate ug/L ND 10.0 12/21/16 16:270.20
Ethylbenzene ug/L ND 1.0 12/21/16 16:270.30
Hexachloro-1,3-butadiene ug/L ND 10.0 12/21/16 16:270.71
Iodomethane ug/L ND 10.0 12/21/16 16:270.32
Isobutanol ug/L ND 100 12/21/16 16:2735.0
Methacrylonitrile ug/L ND 100 12/21/16 16:270.93
Methyl methacrylate ug/L ND 30.0 12/21/16 16:272.0
Methylene Chloride ug/L ND 1.0 12/21/16 16:270.97
Naphthalene ug/L ND 10.0 12/21/16 16:270.24
Propionitrile ug/L ND 150 12/21/16 16:273.6
Styrene ug/L ND 1.0 12/21/16 16:270.26
Tetrachloroethene ug/L ND 1.0 12/21/16 16:270.46
Toluene ug/L ND 1.0 12/21/16 16:270.26
trans-1,2-Dichloroethene ug/L ND 5.0 12/21/16 16:270.49
trans-1,3-Dichloropropene ug/L ND 1.0 12/21/16 16:270.26
trans-1,4-Dichloro-2-butene ug/L ND 100 12/21/16 16:271.0
Trichloroethene ug/L ND 1.0 12/21/16 16:270.47
Trichlorofluoromethane ug/L ND 1.0 12/21/16 16:270.20
Vinyl acetate ug/L ND 50.0 12/21/16 16:270.35
Vinyl chloride ug/L ND 1.0 12/21/16 16:270.62
Xylene (Total)ug/L ND 5.0 12/21/16 16:270.66
1,2-Dichloroethane-d4 (S)%99 70-130 12/21/16 16:27
4-Bromofluorobenzene (S)%104 70-130 12/21/16 16:27
Toluene-d8 (S)%100 70-130 12/21/16 16:27
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,1,1,2-Tetrachloroethane ug/L 44.750 89 80-125
1,1,1-Trichloroethane ug/L 49.250 98 71-129
1,1,2,2-Tetrachloroethane ug/L 36.5 L0507379-124
1,1,2-Trichloroethane ug/L 53.350 107 85-125
1,1-Dichloroethane ug/L 52.050 104 73-126
1,1-Dichloroethene ug/L 49.950 100 66-135
1,1-Dichloropropene ug/L 53.650 107 74-135
1,2,3-Trichloropropane ug/L 37.950 76 75-130
1,2,4-Trichlorobenzene ug/L 56.250 112 75-134
1,2-Dibromo-3-chloropropane ug/L 51.950 104 71-133
1,2-Dibromoethane (EDB)ug/L 47.550 95 83-124
1,2-Dichlorobenzene ug/L 46.650 93 80-133
1,2-Dichloroethane ug/L 45.050 90 67-128
1,2-Dichloropropane ug/L 48.550 97 75-132
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 18 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
1,3-Dichlorobenzene ug/L 45.650 91 77-130
1,3-Dichloropropane ug/L 48.150 96 76-131
1,4-Dichlorobenzene ug/L 44.850 90 78-130
2,2-Dichloropropane ug/L 53.050 106 40-160
2-Butanone (MEK)ug/L 107100 107 61-144
2-Hexanone ug/L 97.5100 98 68-143
4-Methyl-2-pentanone (MIBK)ug/L 104100 104 72-135
Acetone ug/L 109100 109 48-146
Acetonitrile ug/L 527500 105 62-150
Acrolein ug/L 223250 89 24-160
Acrylonitrile ug/L 292250 117 40-160
Allyl chloride ug/L 48.450 97 66-137
Benzene ug/L 46.450 93 80-125
Bromochloromethane ug/L 49.850 100 71-125
Bromodichloromethane ug/L 51.250 102 78-124
Bromoform ug/L 43.850 88 71-128
Bromomethane ug/L 34.550 69 40-160
Carbon disulfide ug/L 46.6J50 93 50-160
Carbon tetrachloride ug/L 47.750 95 69-131
Chlorobenzene ug/L 43.350 87 81-122
Chloroethane ug/L 45.850 92 39-148
Chloroform ug/L 50.950 102 73-127
Chloromethane ug/L 38.550 77 44-146
Chloroprene ug/L 57.050 114 75-145
cis-1,2-Dichloroethene ug/L 51.150 102 74-124
cis-1,3-Dichloropropene ug/L 52.650 105 72-132
Dibromochloromethane ug/L 49.350 99 78-125
Dibromomethane ug/L 49.850 100 82-120
Dichlorodifluoromethane ug/L 44.650 89 34-157
Ethyl methacrylate ug/L 50.650 101 82-121
Ethylbenzene ug/L 40.650 81 79-121
Hexachloro-1,3-butadiene ug/L 60.650 121 72-131
Iodomethane ug/L 75.3100 75 39-154
Isobutanol ug/L 9791000 98 34-160
Methacrylonitrile ug/L 455500 91 74-134
Methyl methacrylate ug/L 53.350 107 84-124
Methylene Chloride ug/L 54.950 110 64-133
Naphthalene ug/L 57.350 115 73-133
Propionitrile ug/L 485500 97 73-140
Styrene ug/L 43.850 88 84-126
Tetrachloroethene ug/L 46.250 92 78-122
Toluene ug/L 51.350 103 80-121
trans-1,2-Dichloroethene ug/L 50.250 100 71-127
trans-1,3-Dichloropropene ug/L 53.450 107 69-141
trans-1,4-Dichloro-2-butene ug/L 31.5J50 63 40-160
Trichloroethene ug/L 46.750 93 78-122
Trichlorofluoromethane ug/L 53.750 107 53-137
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 19 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1897429LABORATORY CONTROL SAMPLE:
LCSSpike
Vinyl acetate ug/L 110100 110 40-160
Vinyl chloride ug/L 36.350 73 58-137
Xylene (Total)ug/L 131150 87 81-126
1,2-Dichloroethane-d4 (S)%100 70-130
4-Bromofluorobenzene (S)%84 70-130
Toluene-d8 (S)%110 70-130
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
1,1,1,2-Tetrachloroethane ug/L 19.820 99 70-130ND
1,1,1-Trichloroethane ug/L 20.320 101 70-130ND
1,1,2,2-Tetrachloroethane ug/L 23.720 118 70-130ND
1,1,2-Trichloroethane ug/L 15.720 78 70-130ND
1,1-Dichloroethane ug/L 22.920 115 70-130ND
1,1-Dichloroethene ug/L 22.820 114 70-166ND
1,1-Dichloropropene ug/L 20.020 100 70-130ND
1,2,3-Trichloropropane ug/L 23.920 120 70-130ND
1,2,4-Trichlorobenzene ug/L 19.420 97 70-130ND
1,2-Dibromo-3-chloropropane ug/L 17.620 88 70-130ND
1,2-Dibromoethane (EDB)ug/L 19.020 95 70-130ND
1,2-Dichlorobenzene ug/L 20.020 100 70-130ND
1,2-Dichloroethane ug/L 18.520 92 70-130ND
1,2-Dichloropropane ug/L 18.920 95 70-130ND
1,3-Dichlorobenzene ug/L 19.720 99 70-130ND
1,3-Dichloropropane ug/L 18.920 95 70-130ND
1,4-Dichlorobenzene ug/L 19.520 98 70-130ND
2,2-Dichloropropane ug/L 22.620 113 70-130ND
2-Butanone (MEK)ug/L 35.8J40 89 70-130ND
2-Hexanone ug/L 39.0J40 97 70-130ND
4-Methyl-2-pentanone (MIBK)ug/L 39.0J40 97 70-130ND
Acetone ug/L 40.5J40 98 70-130ND
Acetonitrile ug/L 232200 116 70-130ND
Acrolein ug/L 83.8100 84 70-130ND
Acrylonitrile ug/L 125J100 125 70-130ND
Allyl chloride ug/L 20.920 105 70-130ND
Benzene ug/L 16.820 84 70-148ND
Bromochloromethane ug/L 22.420 112 70-130ND
Bromodichloromethane ug/L 19.220 96 70-130ND
Bromoform ug/L 21.420 107 70-130ND
Bromomethane ug/L 15.420 77 70-130ND
Carbon disulfide ug/L 21.5J20 107 70-130ND
Carbon tetrachloride ug/L 18.220 91 70-130ND
Chlorobenzene ug/L 19.820 99 70-146ND
Chloroethane ug/L 20.720 104 70-130ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 20 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1897430MATRIX SPIKE SAMPLE:
MSSpike
Result
92323683001
Chloroform ug/L 22.420 112 70-130ND
Chloromethane ug/L 16.420 82 70-130ND
Chloroprene ug/L 25.220 126 70-130ND
cis-1,2-Dichloroethene ug/L 19.520 98 70-130ND
cis-1,3-Dichloropropene ug/L 19.120 95 70-130ND
Dibromochloromethane ug/L 19.520 98 70-130ND
Dibromomethane ug/L 17.720 89 70-130ND
Dichlorodifluoromethane ug/L 20.420 102 70-130ND
Ethyl methacrylate ug/L 19.620 98 70-130ND
Ethylbenzene ug/L 20.020 100 70-130ND
Hexachloro-1,3-butadiene ug/L 22.120 111 70-130ND
Iodomethane ug/L 23.2 M1405870-130ND
Isobutanol ug/L 416400 104 70-130ND
Methacrylonitrile ug/L 183200 92 70-130ND
Methyl methacrylate ug/L 18.3J20 91 70-130ND
Methylene Chloride ug/L 21.020 105 70-130ND
Naphthalene ug/L 20.320 101 70-130ND
Propionitrile ug/L 197200 99 70-130ND
Styrene ug/L 22.220 111 70-130ND
Tetrachloroethene ug/L 24.020 120 70-130ND
Toluene ug/L 19.720 98 70-155ND
trans-1,2-Dichloroethene ug/L 21.020 105 70-130ND
trans-1,3-Dichloropropene ug/L 19.620 98 70-130ND
trans-1,4-Dichloro-2-butene ug/L 19.4J20 97 70-130ND
Trichloroethene ug/L 19.020 95 69-151ND
Trichlorofluoromethane ug/L 24.620 123 70-130ND
Vinyl acetate ug/L 47.6J40 119 70-130ND
Vinyl chloride ug/L 16.320 81 70-130ND
1,2-Dichloroethane-d4 (S)%98 70-130
4-Bromofluorobenzene (S)%124 70-130
Toluene-d8 (S)%96 70-130
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,1,1,2-Tetrachloroethane ug/L ND 30ND
1,1,1-Trichloroethane ug/L ND 30ND
1,1,2,2-Tetrachloroethane ug/L ND 30ND
1,1,2-Trichloroethane ug/L ND 30ND
1,1-Dichloroethane ug/L 1.2J 2 301.2J
1,1-Dichloroethene ug/L ND 30ND
1,1-Dichloropropene ug/L ND 30ND
1,2,3-Trichloropropane ug/L ND 30ND
1,2,4-Trichlorobenzene ug/L ND 30ND
1,2-Dibromo-3-chloropropane ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 21 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
1,2-Dibromoethane (EDB)ug/L ND 30ND
1,2-Dichlorobenzene ug/L ND 30ND
1,2-Dichloroethane ug/L ND 30ND
1,2-Dichloropropane ug/L 0.45J 300.39J
1,3-Dichlorobenzene ug/L ND 30ND
1,3-Dichloropropane ug/L ND 30ND
1,4-Dichlorobenzene ug/L 1.4 0 301.4
2,2-Dichloropropane ug/L ND 30ND
2-Butanone (MEK)ug/L ND 30ND
2-Hexanone ug/L ND 30ND
4-Methyl-2-pentanone (MIBK)ug/L ND 30ND
Acetone ug/L ND 30ND
Acetonitrile ug/L ND 30ND
Acrolein ug/L ND 30ND
Acrylonitrile ug/L ND 30ND
Allyl chloride ug/L ND 30ND
Benzene ug/L 0.72J 300.72J
Bromochloromethane ug/L ND 30ND
Bromodichloromethane ug/L ND 30ND
Bromoform ug/L ND 30ND
Bromomethane ug/L ND 30ND
Carbon disulfide ug/L ND 30ND
Carbon tetrachloride ug/L ND 30ND
Chlorobenzene ug/L 5.4 10 304.9
Chloroethane ug/L ND 30ND
Chloroform ug/L ND 30ND
Chloromethane ug/L 0.16J 300.11J
Chloroprene ug/L ND 30ND
cis-1,2-Dichloroethene ug/L 3.3J 1 303.3J
cis-1,3-Dichloropropene ug/L ND 30ND
Dibromochloromethane ug/L ND 30ND
Dibromomethane ug/L ND 30ND
Dichlorodifluoromethane ug/L 1.0J 300.93J
Ethyl methacrylate ug/L ND 30ND
Ethylbenzene ug/L ND 30ND
Hexachloro-1,3-butadiene ug/L ND 30ND
Iodomethane ug/L ND 30ND
Isobutanol ug/L ND 30ND
Methacrylonitrile ug/L ND 30ND
Methyl methacrylate ug/L ND 30ND
Methylene Chloride ug/L ND 30ND
Naphthalene ug/L ND 30ND
Propionitrile ug/L ND 30ND
Styrene ug/L ND 30ND
Tetrachloroethene ug/L ND 30ND
Toluene ug/L 0.37J 300.37J
trans-1,2-Dichloroethene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 22 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92323911001
1897431SAMPLE DUPLICATE:
trans-1,3-Dichloropropene ug/L ND 30ND
trans-1,4-Dichloro-2-butene ug/L ND 30ND
Trichloroethene ug/L 0.76J 300.58J
Trichlorofluoromethane ug/L ND 30ND
Vinyl acetate ug/L ND 30ND
Vinyl chloride ug/L 4.9 6 304.6
Xylene (Total)ug/L ND 30ND
1,2-Dichloroethane-d4 (S)%100 5106
4-Bromofluorobenzene (S)%106 1105
Toluene-d8 (S)%98 098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 23 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341799
EPA 3510
EPA 8081
8081A GCS Pesticides
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896365
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
4,4'-DDD ug/L ND 0.10 12/22/16 17:160.050
4,4'-DDE ug/L ND 0.10 12/22/16 17:160.050
4,4'-DDT ug/L ND 0.10 12/22/16 17:160.050
Aldrin ug/L ND 0.050 12/22/16 17:160.050
alpha-BHC ug/L ND 0.050 12/22/16 17:160.050
beta-BHC ug/L ND 0.050 12/22/16 17:160.050
Chlordane (Technical)ug/L ND 0.50 12/22/16 17:160.20
delta-BHC ug/L ND 0.050 12/22/16 17:160.050
Dieldrin ug/L ND 0.075 12/22/16 17:160.050
Endosulfan I ug/L ND 0.10 12/22/16 17:160.050
Endosulfan II ug/L ND 0.10 12/22/16 17:160.050
Endosulfan sulfate ug/L ND 0.10 12/22/16 17:160.050
Endrin ug/L ND 0.10 12/22/16 17:160.050
Endrin aldehyde ug/L ND 0.10 12/22/16 17:160.050
gamma-BHC (Lindane)ug/L ND 0.050 12/22/16 17:160.050
Heptachlor ug/L ND 0.050 12/22/16 17:160.050
Heptachlor epoxide ug/L ND 0.075 12/22/16 17:160.050
Methoxychlor ug/L ND 1.0 12/22/16 17:160.15
Toxaphene ug/L ND 1.5 12/22/16 17:160.20
Decachlorobiphenyl (S)%104 20-130 12/22/16 17:16
Tetrachloro-m-xylene (S)%88 20-130 12/22/16 17:16
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
4,4'-DDD ug/L 0.27.25 108 20-150
4,4'-DDE ug/L 0.25.25 101 20-150
4,4'-DDT ug/L 0.27.25 108 20-150
Aldrin ug/L 0.22.25 89 20-150
alpha-BHC ug/L 0.24.25 97 20-150
beta-BHC ug/L 0.25.25 102 20-150
delta-BHC ug/L 0.27.25 108 20-150
Dieldrin ug/L 0.25.25 102 20-150
Endosulfan I ug/L 0.27.25 109 20-150
Endosulfan II ug/L 0.28.25 115 20-150
Endosulfan sulfate ug/L 0.29.25 116 20-150
Endrin ug/L 0.28.25 114 20-150
Endrin aldehyde ug/L 0.26.25 103 20-150
gamma-BHC (Lindane)ug/L 0.24.25 98 20-150
Heptachlor ug/L 0.23.25 93 20-150
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 24 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896366LABORATORY CONTROL SAMPLE:
LCSSpike
Heptachlor epoxide ug/L 0.25.25 103 20-150
Methoxychlor ug/L 0.91J.74 123 20-150
Decachlorobiphenyl (S)%91 20-130
Tetrachloro-m-xylene (S)%94 20-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1896367MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323758005
1896368
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
4,4'-DDD ug/L .5 109 20-150112 2 30.5ND 0.54 0.55
4,4'-DDE ug/L .5 108 20-150111 3 30.5ND 0.53 0.55
4,4'-DDT ug/L .5 112 20-150115 3 30.5ND 0.55 0.57
Aldrin ug/L .5 91 20-15099 8 30.5ND 0.45 0.49
alpha-BHC ug/L .5 89 20-15096 7 30.5ND 0.44 0.47
beta-BHC ug/L .5 103 20-150106 2 30.5ND 0.51 0.52
delta-BHC ug/L .5 94 20-15098 4 30.5ND 0.46 0.49
Dieldrin ug/L .5 104 20-150108 4 30.5ND 0.51 0.53
Endosulfan I ug/L .5 111 20-150113 2 30.5ND 0.55 0.56
Endosulfan II ug/L .5 114 20-150120 5 30.5ND 0.57 0.60
Endosulfan sulfate ug/L .5 120 20-150125 4 30.5ND 0.60 0.62
Endrin ug/L .5 115 20-150122 6 30.5ND 0.57 0.60
Endrin aldehyde ug/L .5 106 20-150107 2 30.5ND 0.52 0.53
gamma-BHC (Lindane)ug/L .5 92 20-15097 5 30.5ND 0.46 0.48
Heptachlor ug/L .5 85 20-15092 8 30.5ND 0.42 0.46
Heptachlor epoxide ug/L .5 103 20-150106 3 30.5ND 0.51 0.52
Methoxychlor ug/L 1.5 125 20-150128 3 301.5ND 1.9J 1.9J
Decachlorobiphenyl (S)%85 20-13088
Tetrachloro-m-xylene (S)%89 20-130100
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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[phone]
Page 25 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341274
EPA 3510
EPA 8082
8082 GCS PCB
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1893343
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
PCB-1016 (Aroclor 1016)ug/L ND 0.50 12/19/16 13:170.50
PCB-1221 (Aroclor 1221)ug/L ND 0.50 12/19/16 13:170.50
PCB-1232 (Aroclor 1232)ug/L ND 0.50 12/19/16 13:170.50
PCB-1242 (Aroclor 1242)ug/L ND 0.50 12/19/16 13:170.50
PCB-1248 (Aroclor 1248)ug/L ND 0.50 12/19/16 13:170.50
PCB-1254 (Aroclor 1254)ug/L ND 0.50 12/19/16 13:170.50
PCB-1260 (Aroclor 1260)ug/L ND 0.50 12/19/16 13:170.50
Decachlorobiphenyl (S)%92 10-132 12/19/16 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1893344LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1893345
PCB-1016 (Aroclor 1016)ug/L 4.85 95 50-150904.5 6 30
PCB-1260 (Aroclor 1260)ug/L 5.55 111 50-1501035.1 8 30
Decachlorobiphenyl (S)%82 10-13279
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 26 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
339874
EPA 8151
EPA 8151
8151A GCS Herbicides
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1823467
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
2,4,5-T ug/L ND 0.19 12/23/16 05:410.042
2,4,5-TP (Silvex)ug/L ND 0.19 12/23/16 05:410.049
2,4-D ug/L ND 0.94 12/23/16 05:410.22
Dinoseb ug/L ND 0.19 12/23/16 05:410.057
2,4-DCAA (S)%85 39-139 12/23/16 05:41
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1823468LABORATORY CONTROL SAMPLE & LCSD:
LCSSpike LCSD
% Rec RPD
Max
RPD
LCSD
Result
1823948
2,4,5-T ug/L 1.31.2 108 37-1331181.4 9 40
2,4,5-TP (Silvex)ug/L 1.01.2 84 53-134961.2 14 40
2,4-D ug/L 6.16 101 35-1241106.6 8 40
Dinoseb ug/L 0.851.2 70 13-116820.98 15 40
2,4-DCAA (S)%82 39-13990 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 27 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341825
EPA 3510
EPA 8270
8270 Water MSSV
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896583
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
1,2,4,5-Tetrachlorobenzene ug/L ND 10.0 12/22/16 10:331.7
1,3,5-Trinitrobenzene ug/L ND 10.0 12/22/16 10:331.1
1,3-Dinitrobenzene ug/L ND 20.0 12/22/16 10:331.5
1,4-Naphthoquinone ug/L ND 10.0 12/22/16 10:331.8
1-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.96
2,2'-Oxybis(1-chloropropane)ug/L ND 10.0 12/22/16 10:331.6
2,3,4,6-Tetrachlorophenol ug/L ND 10.0 12/22/16 10:332.3
2,4,5-Trichlorophenol ug/L ND 10.0 12/22/16 10:332.2
2,4,6-Trichlorophenol ug/L ND 10.0 12/22/16 10:331.9
2,4-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.7
2,4-Dimethylphenol ug/L ND 10.0 12/22/16 10:332.2
2,4-Dinitrophenol ug/L ND 50.0 12/22/16 10:336.5
2,4-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.2
2,6-Dichlorophenol ug/L ND 10.0 12/22/16 10:331.8
2,6-Dinitrotoluene ug/L ND 10.0 12/22/16 10:331.7
2-Acetylaminofluorene ug/L ND 20.0 12/22/16 10:330.84
2-Chloronaphthalene ug/L ND 10.0 12/22/16 10:332.2
2-Chlorophenol ug/L ND 10.0 12/22/16 10:331.5
2-Methylnaphthalene ug/L ND 10.0 12/22/16 10:330.28
2-Methylphenol(o-Cresol)ug/L ND 10.0 12/22/16 10:331.7
2-Naphthalenamine ug/L ND 10.0 12/22/16 10:330.98
2-Nitroaniline ug/L ND 50.0 12/22/16 10:332.8
2-Nitrophenol ug/L ND 10.0 12/22/16 10:331.7
3&4-Methylphenol(m&p Cresol)ug/L ND 10.0 12/22/16 10:331.7
3,3'-Dichlorobenzidine ug/L ND 20.0 12/22/16 10:331.4
3,3'-Dimethylbenzidine ug/L ND 10.0 12/22/16 10:332.1
3-Methylcholanthrene ug/L ND 10.0 12/22/16 10:330.82
3-Nitroaniline ug/L ND 50.0 12/22/16 10:332.4
4,6-Dinitro-2-methylphenol ug/L ND 50.0 12/22/16 10:331.7
4-Aminobiphenyl ug/L ND 20.0 12/22/16 10:330.92
4-Bromophenylphenyl ether ug/L ND 10.0 12/22/16 10:331.3
4-Chloro-3-methylphenol ug/L ND 20.0 12/22/16 10:334.2
4-Chloroaniline ug/L ND 20.0 12/22/16 10:333.4
4-Chlorophenylphenyl ether ug/L ND 10.0 12/22/16 10:332.1
4-Nitroaniline ug/L ND 20.0 12/22/16 10:332.5
4-Nitrophenol ug/L ND 50.0 12/22/16 10:335.8
5-Nitro-o-toluidine ug/L ND 10.0 12/22/16 10:331.2
7,12-Dimethylbenz(a)anthracene ug/L ND 10.0 12/22/16 10:330.77
Acenaphthene ug/L ND 10.0 12/22/16 10:330.25
Acenaphthylene ug/L ND 10.0 12/22/16 10:330.21
Acetophenone ug/L ND 10.0 12/22/16 10:332.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 28 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896583
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
Anthracene ug/L ND 10.0 12/22/16 10:330.14
Benzo(a)anthracene ug/L ND 10.0 12/22/16 10:330.33
Benzo(a)pyrene ug/L ND 10.0 12/22/16 10:330.30
Benzo(b)fluoranthene ug/L ND 10.0 12/22/16 10:330.28
Benzo(g,h,i)perylene ug/L ND 10.0 12/22/16 10:330.38
Benzo(k)fluoranthene ug/L ND 10.0 12/22/16 10:330.43
Benzyl alcohol ug/L ND 20.0 12/22/16 10:333.4
bis(2-Chloroethoxy)methane ug/L ND 10.0 12/22/16 10:331.7
bis(2-Chloroethyl) ether ug/L ND 10.0 12/22/16 10:331.5
bis(2-Ethylhexyl)phthalate ug/L ND 15.0 12/22/16 10:330.85
Butylbenzylphthalate ug/L ND 10.0 12/22/16 10:330.75
Chlorobenzilate ug/L ND 10.0 12/22/16 10:330.72
Chrysene ug/L ND 10.0 12/22/16 10:330.21
Di-n-butylphthalate ug/L ND 10.0 12/22/16 10:331.1
Di-n-octylphthalate ug/L ND 10.0 12/22/16 10:330.86
Diallate ug/L ND 10.0 12/22/16 10:331.3
Dibenz(a,h)anthracene ug/L ND 10.0 12/22/16 10:330.55
Dibenzofuran ug/L ND 10.0 12/22/16 10:331.8
Diethylphthalate ug/L ND 6000 12/22/16 10:331.3
Dimethoate ug/L ND 20.0 12/22/16 10:330.92
Dimethylphthalate ug/L ND 10.0 12/22/16 10:331.5
Diphenylamine ug/L ND 10.0 12/22/16 10:331.3
Disulfoton ug/L ND 10.0 12/22/16 10:331.4
Ethyl methanesulfonate ug/L ND 20.0 12/22/16 10:331.8
Famphur ug/L ND 20.0 12/22/16 10:331.7
Fluoranthene ug/L ND 10.0 12/22/16 10:330.21
Fluorene ug/L ND 10.0 12/22/16 10:330.21
Hexachlorobenzene ug/L ND 10.0 12/22/16 10:331.1
Hexachlorocyclopentadiene ug/L ND 10.0 12/22/16 10:331.8
Hexachloroethane ug/L ND 10.0 12/22/16 10:331.5
Hexachloropropene ug/L ND 10.0 12/22/16 10:331.6
Indeno(1,2,3-cd)pyrene ug/L ND 10.0 12/22/16 10:330.29
Isodrin ug/L ND 20.0 12/22/16 10:332.0
Isophorone ug/L ND 10.0 12/22/16 10:331.8
Isosafrole ug/L ND 10.0 12/22/16 10:331.8
Kepone ug/L ND 20.0 12/22/16 10:333.1
Methapyrilene ug/L ND 100 12/22/16 10:332.7
Methyl methanesulfonate ug/L ND 10.0 12/22/16 10:331.3
Methyl parathion ug/L ND 10.0 12/22/16 10:331.1
N-Nitroso-di-n-butylamine ug/L ND 10.0 12/22/16 10:332.2
N-Nitroso-di-n-propylamine ug/L ND 10.0 12/22/16 10:332.1
N-Nitrosodiethylamine ug/L ND 20.0 12/22/16 10:331.8
N-Nitrosodimethylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosodiphenylamine ug/L ND 10.0 12/22/16 10:331.3
N-Nitrosomethylethylamine ug/L ND 10.0 12/22/16 10:331.8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 29 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1896583
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
N-Nitrosopiperidine ug/L ND 20.0 12/22/16 10:331.9
N-Nitrosopyrrolidine ug/L ND 10.0 12/22/16 10:332.5
Nitrobenzene ug/L ND 10.0 12/22/16 10:331.7
O,O,O-Triethylphosphorothioate ug/L ND 10.0 12/22/16 10:331.8
O-Toluidine ug/L ND 10.0 12/22/16 10:331.6
P-Dimethylaminoazobenzene ug/L ND 10.0 12/22/16 10:330.35
p-Phenylenediamine ug/L ND 10.0 12/22/16 10:330.96
Parathion (Ethyl parathion)ug/L ND 10.0 12/22/16 10:331.1
Pentachlorobenzene ug/L ND 10.0 12/22/16 10:332.0
Pentachloronitrobenzene ug/L ND 20.0 12/22/16 10:331.0
Pentachlorophenol ug/L ND 25.0 12/22/16 10:332.3
Phenacetin ug/L ND 20.0 12/22/16 10:330.97
Phenanthrene ug/L ND 10.0 12/22/16 10:330.22
Phenol ug/L ND 10.0 12/22/16 10:331.7
Phorate ug/L ND 10.0 12/22/16 10:331.1
Pronamide ug/L ND 10.0 12/22/16 10:330.97
Pyrene ug/L ND 10.0 12/22/16 10:330.19
Safrole ug/L ND 10.0 12/22/16 10:331.5
Thionazin ug/L ND 20.0 12/22/16 10:331.2
2,4,6-Tribromophenol (S)%70 27-110 12/22/16 10:33
2-Fluorobiphenyl (S)%54 27-110 12/22/16 10:33
2-Fluorophenol (S)%26 12-110 12/22/16 10:33
Nitrobenzene-d5 (S)%50 21-110 12/22/16 10:33
Phenol-d6 (S)%23 10-110 12/22/16 10:33
Terphenyl-d14 (S)%71 31-107 12/22/16 10:33
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
1,2,4,5-Tetrachlorobenzene ug/L 33.650 67 16-129
1,3,5-Trinitrobenzene ug/L 43.250 86 55-125
1,3-Dinitrobenzene ug/L 42.150 84 30-122
1,4-Naphthoquinone ug/L 37.450 75 31-120
1-Naphthalenamine ug/L 24.050 48 37-126
2,2'-Oxybis(1-chloropropane)ug/L 36.150 72 18-120
2,3,4,6-Tetrachlorophenol ug/L 56.550 113 54-276
2,4,5-Trichlorophenol ug/L 35.450 71 43-113
2,4,6-Trichlorophenol ug/L 41.050 82 42-120
2,4-Dichlorophenol ug/L 38.450 77 30-120
2,4-Dimethylphenol ug/L 38.750 77 29-111
2,4-Dinitrophenol ug/L 123250 49 19-132
2,4-Dinitrotoluene ug/L 42.350 85 58-128
2,6-Dichlorophenol ug/L 42.550 85 54-128
2,6-Dinitrotoluene ug/L 42.850 86 54-129
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
Page 30 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
2-Acetylaminofluorene ug/L 43.750 87 81-160
2-Chloronaphthalene ug/L 41.150 82 43-117
2-Chlorophenol ug/L 36.050 72 37-120
2-Methylnaphthalene ug/L 37.550 75 33-120
2-Methylphenol(o-Cresol)ug/L 25.350 51 31-120
2-Naphthalenamine ug/L 36.650 73 41-136
2-Nitroaniline ug/L 68.5100 69 48-121
2-Nitrophenol ug/L 37.350 75 25-116
3&4-Methylphenol(m&p Cresol)ug/L 38.850 78 23-120
3,3'-Dichlorobenzidine ug/L 86.0250 34 10-154
3,3'-Dimethylbenzidine ug/L 62.6100 63 10-157
3-Methylcholanthrene ug/L 47.750 95 65-130
3-Nitroaniline ug/L 82.5100 83 43-115
4,6-Dinitro-2-methylphenol ug/L 89.5100 89 44-124
4-Aminobiphenyl ug/L 33.650 67 21-125
4-Bromophenylphenyl ether ug/L 37.950 76 34-113
4-Chloro-3-methylphenol ug/L 73.5100 73 31-110
4-Chloroaniline ug/L 67.3100 67 20-120
4-Chlorophenylphenyl ether ug/L 37.750 75 34-116
4-Nitroaniline ug/L 89.4100 89 46-128
4-Nitrophenol ug/L 76.4250 31 11-120
5-Nitro-o-toluidine ug/L 42.150 84 78-160
7,12-Dimethylbenz(a)anthracene ug/L 47.250 94 47-124
Acenaphthene ug/L 39.450 79 48-114
Acenaphthylene ug/L 40.750 81 48-112
Acetophenone ug/L 32.650 65 24-120
Anthracene ug/L 41.650 83 57-118
Benzo(a)anthracene ug/L 41.350 83 56-121
Benzo(a)pyrene ug/L 45.750 91 55-127
Benzo(b)fluoranthene ug/L 44.150 88 53-128
Benzo(g,h,i)perylene ug/L 45.950 92 54-125
Benzo(k)fluoranthene ug/L 46.850 94 51-123
Benzyl alcohol ug/L 57.5100 57 27-120
bis(2-Chloroethoxy)methane ug/L 35.650 71 32-120
bis(2-Chloroethyl) ether ug/L 36.450 73 33-111
bis(2-Ethylhexyl)phthalate ug/L 48.250 96 50-145
Butylbenzylphthalate ug/L 47.650 95 54-138
Chlorobenzilate ug/L 45.250 90 65-132
Chrysene ug/L 41.350 83 58-127
Di-n-butylphthalate ug/L 47.250 94 56-125
Di-n-octylphthalate ug/L 49.350 99 50-134
Diallate ug/L 48.250 96 47-123
Dibenz(a,h)anthracene ug/L 47.150 94 53-129
Dibenzofuran ug/L 39.650 79 45-120
Diethylphthalate ug/L 43.4J50 87 53-120
Dimethoate ug/L 50.850 102 57-139
Dimethylphthalate ug/L 41.150 82 55-116
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 31 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Diphenylamine ug/L 42.350 85 42-120
Disulfoton ug/L 50.050 100 49-156
Ethyl methanesulfonate ug/L 38.250 76 43-120
Famphur ug/L 45.6100 46 40-160
Fluoranthene ug/L 45.450 91 57-125
Fluorene ug/L 41.450 83 53-118
Hexachlorobenzene ug/L 39.850 80 49-116
Hexachlorocyclopentadiene ug/L 34.350 69 26-158
Hexachloroethane ug/L 29.350 59 30-114
Hexachloropropene ug/L 33.350 67 13-137
Indeno(1,2,3-cd)pyrene ug/L 47.650 95 55-128
Isodrin ug/L 46.450 93 68-129
Isophorone ug/L 35.550 71 31-118
Isosafrole ug/L 32.650 65 48-107
Kepone ug/L 45.7100 46 10-124
Methapyrilene ug/L 51.7J50 103 40-160
Methyl methanesulfonate ug/L 25.350 51 25-114
Methyl parathion ug/L 51.750 103 58-137
N-Nitroso-di-n-butylamine ug/L 30.850 62 36-115
N-Nitroso-di-n-propylamine ug/L 38.050 76 32-119
N-Nitrosodiethylamine ug/L 38.250 76 47-115
N-Nitrosodimethylamine ug/L 24.850 50 13-120
N-Nitrosodiphenylamine ug/L 42.350 85 43-120
N-Nitrosomethylethylamine ug/L 33.450 67 39-120
N-Nitrosopiperidine ug/L 43.950 88 43-113
N-Nitrosopyrrolidine ug/L 35.650 71 32-110
Nitrobenzene ug/L 33.950 68 33-110
O,O,O-Triethylphosphorothioate ug/L 37.850 76 51-127
O-Toluidine ug/L 33.650 67 27-120
P-Dimethylaminoazobenzene ug/L 19.3100 19 10-120
p-Phenylenediamine ug/L 45.950 92 72-143
Parathion (Ethyl parathion)ug/L 50.750 101 56-140
Pentachlorobenzene ug/L 35.650 71 30-137
Pentachloronitrobenzene ug/L 49.950 100 70-124
Pentachlorophenol ug/L 89.3250 36 10-137
Phenacetin ug/L 46.650 93 60-130
Phenanthrene ug/L 41.150 82 57-117
Phenol ug/L 17.350 35 10-120
Phorate ug/L 51.650 103 55-126
Pronamide ug/L 51.550 103 75-124
Pyrene ug/L 39.350 79 55-122
Safrole ug/L 39.450 79 41-120
Thionazin ug/L 40.050 80 63-137
2,4,6-Tribromophenol (S)%43 27-110
2-Fluorobiphenyl (S)%36 27-110
2-Fluorophenol (S)%20 12-110
Nitrobenzene-d5 (S)%35 21-110
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 32 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1896584LABORATORY CONTROL SAMPLE:
LCSSpike
Phenol-d6 (S)%14 10-110
Terphenyl-d14 (S)%38 31-107
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
1,2,4,5-Tetrachlorobenzene ug/L 33.050 66 50-150ND
1,3,5-Trinitrobenzene ug/L 48.950 98 50-150ND
1,3-Dinitrobenzene ug/L 40.450 81 50-150ND
1,4-Naphthoquinone ug/L 33.950 68 50-150ND
1-Naphthalenamine ug/L 23.3 M1504750-150ND
2,2'-Oxybis(1-chloropropane)ug/L 28.150 56 50-150ND
2,3,4,6-Tetrachlorophenol ug/L 38.450 77 50-150ND
2,4,5-Trichlorophenol ug/L 27.650 55 19-105ND
2,4,6-Trichlorophenol ug/L 25.050 50 13-108ND
2,4-Dichlorophenol ug/L 34.450 69 29-111ND
2,4-Dimethylphenol ug/L 36.750 73 21-103ND
2,4-Dinitrophenol ug/L 28.1J250 11 10-109ND
2,4-Dinitrotoluene ug/L 37.650 75 27-104ND
2,6-Dichlorophenol ug/L 33.350 67 50-150ND
2,6-Dinitrotoluene ug/L 41.750 83 28-101ND
2-Acetylaminofluorene ug/L 40.550 81 50-150ND
2-Chloronaphthalene ug/L 43.950 88 14-102ND
2-Chlorophenol ug/L 31.250 62 16-110ND
2-Methylnaphthalene ug/L 39.850 80 13-110ND
2-Methylphenol(o-Cresol)ug/L 22.650 45 19-110ND
2-Naphthalenamine ug/L 30.350 61 50-150ND
2-Nitroaniline ug/L 59.8100 60 26-103ND
2-Nitrophenol ug/L 33.350 67 20-110ND
3&4-Methylphenol(m&p Cresol)ug/L 47.650 95 20-110ND
3,3'-Dichlorobenzidine ug/L 82.5250 33 25-112ND
3,3'-Dimethylbenzidine ug/L 53.4100 53 50-150ND
3-Methylcholanthrene ug/L 45.350 91 50-150ND
3-Nitroaniline ug/L 75.3100 75 29-110ND
4,6-Dinitro-2-methylphenol ug/L 51.8100 52 10-117ND
4-Aminobiphenyl ug/L 34.950 70 50-150ND
4-Bromophenylphenyl ether ug/L 40.950 82 20-105ND
4-Chloro-3-methylphenol ug/L 64.1100 64 22-110ND
4-Chloroaniline ug/L 66.4100 66 20-100ND
4-Chlorophenylphenyl ether ug/L 41.850 84 19-102ND
4-Nitroaniline ug/L 99.6100 100 29-110ND
4-Nitrophenol ug/L 36.2J250 14 10-110ND
5-Nitro-o-toluidine ug/L 42.950 86 50-150ND
7,12-Dimethylbenz(a)anthracene ug/L 43.750 87 50-150ND
Acenaphthene ug/L 38.350 77 17-100ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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[phone]
Page 33 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
Acenaphthylene ug/L 39.650 79 21-100ND
Acetophenone ug/L 30.850 62 50-150ND
Anthracene ug/L 40.550 81 24-109ND
Benzo(a)anthracene ug/L 39.450 79 22-117ND
Benzo(a)pyrene ug/L 42.050 84 23-104ND
Benzo(b)fluoranthene ug/L 41.050 82 23-103ND
Benzo(g,h,i)perylene ug/L 42.350 85 18-111ND
Benzo(k)fluoranthene ug/L 42.750 85 22-113ND
Benzyl alcohol ug/L 48.7100 49 19-101ND
bis(2-Chloroethoxy)methane ug/L 32.350 65 22-110ND
bis(2-Chloroethyl) ether ug/L 33.950 68 16-110ND
bis(2-Ethylhexyl)phthalate ug/L 42.550 85 23-102ND
Butylbenzylphthalate ug/L 41.950 84 25-110ND
Chlorobenzilate ug/L 42.450 84 50-150ND
Chrysene ug/L 39.850 80 23-115ND
Di-n-butylphthalate ug/L 44.150 88 26-110ND
Di-n-octylphthalate ug/L 43.850 88 22-110ND
Diallate ug/L 46.450 93 50-150ND
Dibenz(a,h)anthracene ug/L 41.250 82 21-112ND
Dibenzofuran ug/L 40.450 81 19-102ND
Diethylphthalate ug/L 39.2J50 78 29-110ND
Dimethoate ug/L 50.950 102 50-150ND
Dimethylphthalate ug/L 42.950 86 27-110ND
Diphenylamine ug/L 49.550 99 50-150ND
Disulfoton ug/L 41.050 82 50-150ND
Ethyl methanesulfonate ug/L 34.450 69 50-150ND
Famphur ug/L 51.1100 51 50-150ND
Fluoranthene ug/L 45.150 90 23-112ND
Fluorene ug/L 46.050 92 22-104ND
Hexachlorobenzene ug/L 42.750 85 21-116ND
Hexachlorocyclopentadiene ug/L 33.950 68 10-110ND
Hexachloroethane ug/L 29.550 59 10-110ND
Hexachloropropene ug/L 37.550 75 50-150ND
Indeno(1,2,3-cd)pyrene ug/L 43.150 86 20-113ND
Isodrin ug/L 45.950 92 50-150ND
Isophorone ug/L 31.950 64 50-150ND
Isosafrole ug/L 31.950 64 50-150ND
Kepone ug/L 60.3100 60 50-150ND
Methapyrilene ug/L 46.8J50 94 50-150ND
Methyl methanesulfonate ug/L 26.950 54 50-150ND
Methyl parathion ug/L 46.350 93 50-150ND
N-Nitroso-di-n-butylamine ug/L 30.250 60 50-150ND
N-Nitroso-di-n-propylamine ug/L 32.750 65 21-105ND
N-Nitrosodiethylamine ug/L 43.250 86 50-150ND
N-Nitrosodimethylamine ug/L 23.050 46 10-110ND
N-Nitrosodiphenylamine ug/L 49.550 99 23-107ND
N-Nitrosomethylethylamine ug/L 31.950 64 50-150ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 34 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
1896585MATRIX SPIKE SAMPLE:
MSSpike
Result
92322991014
N-Nitrosopiperidine ug/L 38.050 76 50-150ND
N-Nitrosopyrrolidine ug/L 31.050 62 50-150ND
Nitrobenzene ug/L 28.250 56 20-110ND
O,O,O-Triethylphosphorothioate ug/L 39.250 78 50-150ND
O-Toluidine ug/L 28.750 57 50-150ND
P-Dimethylaminoazobenzene ug/L 18.4 M11001850-150ND
p-Phenylenediamine ug/L 43.850 88 50-150ND
Parathion (Ethyl parathion)ug/L 45.450 91 50-150ND
Pentachlorobenzene ug/L 34.750 69 50-150ND
Pentachloronitrobenzene ug/L 43.150 86 50-150ND
Pentachlorophenol ug/L 32.6250 13 10-118ND
Phenacetin ug/L 45.550 91 50-150ND
Phenanthrene ug/L 41.250 82 24-106ND
Phenol ug/L 14.750 29 12-110ND
Phorate ug/L 46.150 92 50-150ND
Pronamide ug/L 49.050 98 50-150ND
Pyrene ug/L 35.650 71 24-114ND
Safrole ug/L 40.950 82 50-150ND
Thionazin ug/L 42.550 85 50-150ND
2,4,6-Tribromophenol (S)%70 27-110
2-Fluorobiphenyl (S)%75 27-110
2-Fluorophenol (S)%34 12-110
Nitrobenzene-d5 (S)%56 21-110
Phenol-d6 (S)%23 10-110
Terphenyl-d14 (S)%68 31-107
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
1,2,4,5-Tetrachlorobenzene ug/L ND 30ND
1,3,5-Trinitrobenzene ug/L ND 30ND
1,3-Dinitrobenzene ug/L ND 30ND
1,4-Naphthoquinone ug/L ND 30ND
1-Naphthalenamine ug/L ND 30ND
2,2'-Oxybis(1-chloropropane)ug/L ND 30ND
2,3,4,6-Tetrachlorophenol ug/L ND 30ND
2,4,5-Trichlorophenol ug/L ND 30ND
2,4,6-Trichlorophenol ug/L ND 30ND
2,4-Dichlorophenol ug/L ND 30ND
2,4-Dimethylphenol ug/L ND 30ND
2,4-Dinitrophenol ug/L ND 30ND
2,4-Dinitrotoluene ug/L ND 30ND
2,6-Dichlorophenol ug/L ND 30ND
2,6-Dinitrotoluene ug/L ND 30ND
2-Acetylaminofluorene ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Huntersville, NC 28078
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Page 35 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
2-Chloronaphthalene ug/L ND 30ND
2-Chlorophenol ug/L ND 30ND
2-Methylnaphthalene ug/L ND 30ND
2-Methylphenol(o-Cresol)ug/L ND 30ND
2-Naphthalenamine ug/L ND 30ND
2-Nitroaniline ug/L ND 30ND
2-Nitrophenol ug/L ND 30ND
3&4-Methylphenol(m&p Cresol)ug/L ND 30ND
3,3'-Dichlorobenzidine ug/L ND 30ND
3,3'-Dimethylbenzidine ug/L ND 30ND
3-Methylcholanthrene ug/L ND 30ND
3-Nitroaniline ug/L ND 30ND
4,6-Dinitro-2-methylphenol ug/L ND 30ND
4-Aminobiphenyl ug/L ND 30ND
4-Bromophenylphenyl ether ug/L ND 30ND
4-Chloro-3-methylphenol ug/L ND 30ND
4-Chloroaniline ug/L ND 30ND
4-Chlorophenylphenyl ether ug/L ND 30ND
4-Nitroaniline ug/L ND 30ND
4-Nitrophenol ug/L ND 30ND
5-Nitro-o-toluidine ug/L NDND
7,12-Dimethylbenz(a)anthracene ug/L ND 30ND
Acenaphthene ug/L ND 30ND
Acenaphthylene ug/L ND 30ND
Acetophenone ug/L ND 30ND
Anthracene ug/L ND 30ND
Benzo(a)anthracene ug/L ND 30ND
Benzo(a)pyrene ug/L ND 30ND
Benzo(b)fluoranthene ug/L ND 30ND
Benzo(g,h,i)perylene ug/L ND 30ND
Benzo(k)fluoranthene ug/L ND 30ND
Benzyl alcohol ug/L ND 30ND
bis(2-Chloroethoxy)methane ug/L ND 30ND
bis(2-Chloroethyl) ether ug/L ND 30ND
bis(2-Ethylhexyl)phthalate ug/L ND 30ND
Butylbenzylphthalate ug/L ND 30ND
Chlorobenzilate ug/L ND 30ND
Chrysene ug/L ND 30ND
Di-n-butylphthalate ug/L ND 30ND
Di-n-octylphthalate ug/L ND 30ND
Diallate ug/L ND 30ND
Dibenz(a,h)anthracene ug/L ND 30ND
Dibenzofuran ug/L ND 30ND
Diethylphthalate ug/L ND 30ND
Dimethoate ug/L ND 30ND
Dimethylphthalate ug/L ND 30ND
Diphenylamine ug/L ND 30ND
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 36 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Disulfoton ug/L ND 30ND
Ethyl methanesulfonate ug/L ND 30ND
Famphur ug/L ND 30ND
Fluoranthene ug/L ND 30ND
Fluorene ug/L ND 30ND
Hexachlorobenzene ug/L ND 30ND
Hexachlorocyclopentadiene ug/L ND 30ND
Hexachloroethane ug/L ND 30ND
Hexachloropropene ug/L ND 30ND
Indeno(1,2,3-cd)pyrene ug/L ND 30ND
Isodrin ug/L ND 30ND
Isophorone ug/L ND 30ND
Isosafrole ug/L ND 30ND
Kepone ug/L ND 30ND
Methapyrilene ug/L ND 30ND
Methyl methanesulfonate ug/L ND 30ND
Methyl parathion ug/L ND 30ND
N-Nitroso-di-n-butylamine ug/L ND 30ND
N-Nitroso-di-n-propylamine ug/L ND 30ND
N-Nitrosodiethylamine ug/L ND 30ND
N-Nitrosodimethylamine ug/L ND 30ND
N-Nitrosodiphenylamine ug/L ND 30ND
N-Nitrosomethylethylamine ug/L ND 30ND
N-Nitrosopiperidine ug/L ND 30ND
N-Nitrosopyrrolidine ug/L ND 30ND
Nitrobenzene ug/L ND 30ND
O,O,O-Triethylphosphorothioate ug/L ND 30ND
O-Toluidine ug/L ND 30ND
P-Dimethylaminoazobenzene ug/L ND 30ND
p-Phenylenediamine ug/L ND 30ND
Parathion (Ethyl parathion)ug/L ND 30ND
Pentachlorobenzene ug/L ND 30ND
Pentachloronitrobenzene ug/L ND 30ND
Pentachlorophenol ug/L ND 30ND
Phenacetin ug/L ND 30ND
Phenanthrene ug/L ND 30ND
Phenol ug/L ND 30ND
Phorate ug/L ND 30ND
Pronamide ug/L ND 30ND
Pyrene ug/L ND 30ND
Safrole ug/L ND 30ND
Thionazin ug/L ND 30ND
2,4,6-Tribromophenol (S)%68 169
2-Fluorobiphenyl (S)%58 1165
2-Fluorophenol (S)%22 2227
Nitrobenzene-d5 (S)%51 654
Phenol-d6 (S)%15 1818
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 37 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
Dup
Result
Max
RPD QualifiersRPDResult
92322991016
1896586SAMPLE DUPLICATE:
Terphenyl-d14 (S)%70 473
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 38 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
341532
SM 4500-S2D
SM 4500-S2D
4500S2D Sulfide Water
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1894991
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
Sulfide ug/L ND 1000 12/20/16 15:05100
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1894992LABORATORY CONTROL SAMPLE:
LCSSpike
Sulfide ug/L 527J500 105 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894993MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323602010
1894994
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15001580-12015 10500NDNDND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1894995MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323608006
1894996
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Sulfide ug/L M15004680-12046 0 10500ND231J231J
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 39 of 45
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
342533
SM 4500-CN-E
SM 4500-CN-E
4500CNE Cyanide, Total
Associated Lab Samples:92323613001
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:1900210
Associated Lab Samples:92323613001
Matrix:Water
AnalyzedMDL
Cyanide ug/L ND 10.0 12/27/16 14:204.0
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
1900211LABORATORY CONTROL SAMPLE:
LCSSpike
Cyanide ug/L 98.7100 99 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900212MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323840002
1900213
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L M1100075-1250 10100NDNDND
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
1900214MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92323553001
1900215
MSD
Result
MSD
% Rec RPD RPD
Max
MSDMS
Spike
Conc.
Cyanide ug/L 100 87 75-12592 5 10100ND89.5 94.0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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[phone]
Page 40 of 45
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
Pace Analytical Services - AshevillePASI-A
Pace Analytical Services - CharlottePASI-C
Pace Analytical Services - Ormond BeachPASI-O
BATCH QUALIFIERS
Batch: 340487
A matrix spike/matrix spike duplicate was not performed for this batch due to insufficient sample volume.[M5]
ANALYTE QUALIFIERS
Extraction or preparation conducted outside EPA method holding time.H2
Analyte recovery in the laboratory control sample (LCS) was outside QC limits.L0
Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.L2
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.Date: 12/28/2016 09:24 AM
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Page 41 of 45
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92323613
Burke Co. Johns R. Blanks
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92323613001 341799 3422261203-Field Blank EPA 3510 EPA 8081
92323613001 341274 3414911203-Field Blank EPA 3510 EPA 8082
92323613001 339874 3404871203-Field Blank EPA 8151 EPA 8151
92323613001 341173 3415711203-Field Blank EPA 3010A EPA 6010
92323613001 341661 3419801203-Field Blank EPA 7470 EPA 7470
92323613001 341825 3421661203-Field Blank EPA 3510 EPA 8270
92323613001 3420101203-Field Blank EPA 8260
92323613002 3420101203-Trip Blank EPA 8260
92323613001 3415321203-Field Blank SM 4500-S2D
92323613001 3425331203-Field Blank SM 4500-CN-E
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Page 42 of 45
Page 43 of 45
Page 44 of 45
Page 45 of 45

Appendix C

Statistical Analyses Worksheets

This page intentionally left blank:
No constituents required statistical analysis.

Appendix D

Historical Detected Groundwater Constituents

APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
INORGANICS
Alkalinity, Total as CaCO3 10-Apr-14 1,000 5,000 1,560 J --- 5,510 208,000 ND
NC 2L = NE (01/01/10) 6-May-14 1,000 5,000 1,170 J --- 4,060 J 209,000 ND
20-Jun-14 1,000 5,000 2,020 J --- 4,060 J 262,000 ND
17-Jul-14 1,000 5,000 1,990 J --- 3,960 J 197,000 ND
23-Oct-14 1,000 5,000 1,360 J 7,980 4,340 J 232,000 ND
21-May-15 1,000 5,000 ND 6,540 3,630 J 206,000 ---
8-Dec-15 1,000 5,000 1,030 J 8,280 6,670 234,000 ---
4-May-16 1,000 5,000 1,250 J 5,640 4,190 J 239,000 ---
13-Dec-16 1,000 5,000 1,190 J 6,190 4,100 J 294,000 ---
Arsenic 8-Dec-15 2.5 10 ND ND 12.7 4.9 J ND
NC 2L = 10 µg/L (01/01/10) 4-Feb-16 2.5 10 ------ 5.8 J ---ND
4-May-16 2.5 10 ND ND ND ND ND
13-Dec-16 2.5 10 ND ND ND 3.2 J ---
Barium 10-Apr-14 5 100 14.4 J --- 86.9 J 127 ND
NC 2L = 700 µg/L (01/01/10) 6-May-14 5 100 11.7 J --- 75.7 J 110 ND
20-Jun-14 5 100 14.2 J --- 52.2 J 85.2 J ND
17-Jul-14 5 100 14.4 J --- 52.4 J 58.1 J ND
23-Oct-14 5 100 20.3 J 70.0 J 20.8 J 97.8 J ND
21-May-15 5 100 17.9 J 116.0 28.3 J 91 J ND
8-Dec-15 2.5 100 17.6 J 67.3 J 1110 83.5 J ND
Verification Sample >4-Feb-16 2.5 100 --- --- 264 --- ND
4-May-16 2.5 100 26.6 J 118.0 38.4 J 111 ND
13-Dec-16 2.5 100 13.4 J 123 56.6 J 92.8 J ---
Beryllium 8-Dec-15 0.5 1 ND ND 3.4 ND ND
Verification Sample >4-Feb-16 0.5 1 --- --- 0.83 J --- ND
GWPS = 4 µg/L (01/01/10). 4-May-16 0.5 1 ND ND ND ND ND
13-Dec-16 0.5 1 ND ND ND ND ---
Chloride 10-Apr-14 1,000 1,000 ND --- ND 4,980 ND
NC 2L = 250,000 µg/L (01/01/10)6-May-14 1,000 1,000 ND --- 1,140 4,930 ND
20-Jun-14 1,000 1,000 ND --- 1,320 4,410 ND
17-Jul-14 500 1,000 570 J --- 1,090 4,310 ND
23-Oct-14 500 1,000 ND 1,050 727 J 4,650 ND
21-May-15 500 1,000 750 J 1,550 1,380 4,980 ---
8-Dec-15 500 1,000 859 J 1,840 4,200 4,390 ---
4-May-16 500 1,000 558 J 4,500 2,440 5,980 ---
13-Dec-16 500 1,000 1,470 1,460 1,240 4,760 ---
Chromium 10-Apr-14 5 10 ND ---ND ND ND
NC 2L = 10 µg/L (01/01/10) 6-May-14 5 10 ND ---ND ND ND
20-Jun-14 5 10 ND ---ND ND ND
17-Jul-14 5 10 ND ---ND ND ND
23-Oct-14 5 10 ND 7.0 J ND ND ND
21-May-15510ND7.4JNDNDND
8-Dec-15 2.5 10 ND 4.7 J 16.8 ND ND
Verification Sample >4-Feb-16 2.5 10 --- ---6.6 J ---ND
4-May-16 2.5 10 4.2 J 10.4 ND ND ND
13-Dec-16 2.5 10 ND 9.8 JND 4.0 J ---
Cobalt 10-Apr-14 5 10 ND ---ND 80.8 ND
GWPS = 1 µg/L (10/1/10)6-May-14 5 10 ND ---ND 58.0 ND
20-Jun-14 5 10 ND ---ND 12.5 ND
17-Jul-14 5 10 ND ---ND 18.9 ND
23-Oct-14 5 10 ND ND ND 21.5 ND
21-May-15 5 10 ND 2.9 J ND 10.5 ND
8-Dec-15 2.5 10 ND ND 11.2 4.1 J ND
Verification Sample >4-Feb-16 2.5 10 ------3.2 J ---ND
4-May-16 2.5 10 4.0 J 3.1 JND 10.0 ND
13-Dec-16 2.5 10 ND 3.6 JND ND ---
Copper 8-Dec-15 2.5 10 ND J 30.0 3.3 J ND
NC 2L = 1,000 µg/L (01/01/10). Verifi. Sample > 4-Feb-16 2.5 10 ------10.4 ---ND
4-May-16 2.5 10 8.7 J 9.8 JND 2.8 JND
13-Dec-16 2.5 10 4.1 J 11.9 2.8 J 9.1 J ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 6
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Iron 10-Apr-14 50 300 ND ---559 22,800 ND
NC 2L = 300 µg/L (01/01/10) 6-May-14 50 300 177 J ---3,930 16,300 ND
20-Jun-14 50 300 200 J ---402 14,400 ND
17-Jul-14 50 300 381 ---2,280 4,390 ND
23-Oct-14 50 300 2,340 3,990 719 16,700 ND
21-May-15 50 300 350 6,660 295 J 16,100 ND
8-Dec-15 25 300 1,380 3,590 29,700 27,800 ND
Verification Sample >4-Feb-16 25 300 ------9,840 ---ND
4-May-16 25 300 7,630 8,590 929 30,500 27.3 J
13-Dec-16 25 300 2,020 9,700 2,440 37,400 ---
Lead 8-Dec-15 2.5 10 ND 3.0 J 39.4 3.2 J ND
NC 2L = 15 µg/L (01/01/10)4-Feb-16 2.5 10 ------10.5 ---ND
4-May-16 2.5 10 ND 4.4 JND ND ND
13-Dec-16 2.5 10 ND 5.1 JND 6.2 J ---
Manganese 10-Apr-14 5 50 20.8 J ---132 5,450 ND
NC 2L = 50 µg/L (01/01/10)6-May-14 5 50 22.5 J ---77.5 4,830 ND
20-Jun-14 5 50 24.7 J ---52.2 3,790 ND
17-Jul-14 5 50 27.9 J ---39.8 J 3,380 ND
23-Oct-14 5 50 73.6 77.5 16.6 J 3,930 ND
21-May-15 5 50 27.4 J 146 11.7 J 3,060 ND
8-Dec-15 2.5 50 50.0 J 68.5 462 3,220 ND
Verification Sample >4-Feb-16 2.5 50 ------124 ---ND
4-May-16 2.5 50 142 148 14.3 J 4,170 ND
13-Dec-16 2.5 50 48.1 J 169 33.0 J 3,380 ---
Nickel 10-Apr-14 5 50 ND ---ND ND ND
NC 2L = 100 µg/L (10/23/07)6-May-14 5 50 ND ---ND 10.6 J ND
20-Jun-14 5 50 ND ---ND ND ND
17-Jul-14 5 50 ND ---ND 5 J ND
23-Oct-14 5 50 ND ND ND 5.1 J ND
21-May-15 5 50 ND 4.3 ND 4.3 J ND
8-Dec-15 2.5 50 ND 2.5 J 18.7 J 3.0 J ND
Verification Sample >4-Feb-16 2.5 50 ------5.7 J ---ND
4-May-16 2.5 50 ND 5.9 JND 2.7 JND
13-Dec-16 2.5 50 ND 6.8 JND 3.4 J ---
Thallium 8-Dec-15 5 5.5 ND ND ND ND J ND
GWPS = 0.28 µg/L 4-Feb-16 2.5 50 ------9.1 ---ND
4-May-16 5 5.5 ND ND ND ND ND
13-Dec-16 5 5.5 ND ND ND ND ---
Sulfate 10-Apr-14 2,000 250,000 ND ---2,110 J 3,430 J ND
NC 2L = 250,000 µg/L (01/01/10)6-May-14 2,000 250,000 ND ---8,740 J ND ND
20-Jun-14 2,000 250,000 ND ---ND 10,100 J ND
17-Jul-14 1,000 250,000 1,340 J ---1,560 J 8,720 J ND
23-Oct-14 1,000 250,000 ND 1,300 J 1,320 J 3,320 J ND
21-May-15 1,000 250,000 ND ND ND 2,650 J ND
8-Dec-15 1,000 250,000 ND ND ND 4,640 J ND
4-May-16 1,000 250,000 ND 1,270 J 1,290 J 2,770 J ND
13-Dec-16 1,000 250,000 1,340 J 1,530 J 1,460 J 6,820 J ---
Total Dissolved Solids, Dissolved 10-Apr-14 25,000 25,000 37,000 ---68,000 302,000 ND
NC 2L = 500,000 µg/L (01/01/10)6-May-14 25,000 25,000 ND ---30,000 257,000 ND
20-Jun-14 25,000 25,000 ND ---ND 301,000 ND
17-Jul-14 25,000 25,000 ND ---ND 245,000 ND
23-Oct-14 25,000 25,000 ND 25,000 ND 265,000 ND
21-May-15 25,000 25,000 ND 36,000 29,000 268,000 ---
8-Dec-15 25,000 25,000 ND 31,000 96,000 311,000 ---
4-May-16 25,000 25,000 ND 30,000 30,000 299,000 ---
13-Dec-16 25,000 25,000 ND 33,000 ND 366,000 ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 6
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Vanadium 10-Apr-14 5 25 ND ---ND ND ND
GWPS = 0.3 µg/L (10/1/10)6-May-14 5 25 ND ---7.3 J ND ND
20-Jun-14 5 25 ND ---ND ND ND
17-Jul-14 5 25 ND ---ND ND ND
23-Oct-14 5 25 9.6 J 6.5 J ND ND ND
21-May-15 5 25 ND 11.6 ND 4 J ND
8-Dec-15 2.5 25 ND J 6.9 J 44.8 8.5 J ND
Verification Sample >4-Feb-16 2.5 50 ------16.0 J ---ND
4-May-16 2.5 25 29.7 14.5 JND ND ND
13-Dec-16 2.5 25 6.80 J 13.9 J3.30JND ---
Zinc 10-Apr-14 10 10 ND ---19.6 ND ND
NC 2L = 1,000 µg/L (01/01/10)6-May-14 10 10 ND ---15.5 15.8 ND
20-Jun-14 10 10 ND ---ND ND 10.9
17-Jul-14 10 10 ND ---ND 12.5 B 10.5
23-Oct-14 10 10 ND 12.8 ND ND ND
21-May-15 10 10 26.4 19.7 ND ND ND
8-Dec-15 5 10 ND 10.3 127 8.7 J ND
Verification Sample >4-Feb-16 5 10 ------36.5 ND ND
4-May-16 5 10 10.5 22.4 5.5 J 6.4 J ND
13-Dec-16 5 10 ND 23.8 9.3 J 9.5 J ---
ORGANICS
Acetone 10-Apr-14 10 100 ND ---ND 10.2 J ND
NC 2L = 6,000 µg/L 6-May-14 10 100 ND ---ND ND ND
20-Jun-14 10 100 ND ---ND ND ND
17-Jul-14 10 100 ND ---ND ND ND
23-Oct-14 10 100 ND ND ND ND ND
21-May-1510100NDNDNDNDND
8-Dec-1510100NDNDNDNDND
4-May-1610100NDNDNDNDND
13-Dec-16 10 100 ND ND ND ND ---
Benzene 10-Apr-14 0.25 1 ND ---ND 6.6 ND
NC 2L = 1 µg/L (10/23/07)6-May-14 0.25 1 ND ---ND 6.5 ND
20-Jun-14 0.25 1 ND ---ND 5.5 ND
17-Jul-14 0.25 1 ND ---ND 4.6 ND
23-Oct-14 0.25 1 ND ND ND 5.9 ND
21-May-15 0.25 1 ND ND ND 4.9 ND
8-Dec-15 0.25 1 ND ND ND 4.4 ND
4-May-16 0.25 1 ND ND ND 5.4 ND
13-Dec-16 0.25 1 ND ND ND 3.0 ---
Chlorobenzene 10-Apr-14 0.23 3 ND ---ND 0.71 J ND
NC 2L = 50 µg/L (10/23/07)6-May-14 0.23 3 ND ---ND 0.6 J ND
20-Jun-14 0.23 3 ND ---ND 0.5 J ND
17-Jul-14 0.23 3 ND ---ND 0.61 J ND
23-Oct-14 0.23 3 ND ND ND 0.61 J ND
21-May-15 0.23 3 ND ND ND 0.51 J ND
8-Dec-15 0.23 3 ND ND ND 0.49 J ND
4-May-16 0.23 3 ND ND ND 0.56 J ND
13-Dec-16 0.23 3 ND ND ND 0.41 J ---
1,2-Dichlorobenzene 10-Apr-14 0.3 5 ND ---ND 0.3 J ND
NC 2L = 20 µg/L (01/01/10)6-May-14 0.3 5 ND ---ND 0.36 J ND
20-Jun-14 0.3 5 ND ---ND ND ND
17-Jul-14 0.3 5 ND ---ND ND ND
23-Oct-14 0.3 5 ND ND ND 0.31 J ND
21-May-15 0.3 5 ND ND ND ND ND
8-Dec-15 0.3 5 ND ND ND ND ND
4-May-16 0.3 5 ND ND ND 0.30 J ND
13-Dec-16 0.3 5 ND ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 6
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
1,4-Dichlorobenzene 10-Apr-14 0.33 1 ND ---ND 13.9 ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.33 1 ND ---ND 13.5 ND
20-Jun-14 0.33 1 ND ---ND 9.9 ND
17-Jul-14 0.33 1 ND ---ND 13.0 ND
23-Oct-14 0.33 1 ND ND ND 12.9 ND
21-May-15 0.33 1 ND ND ND 12.3 ND
8-Dec-15 0.33 1 ND ND ND 12.2 ND
4-May-16 0.33 1 ND ND ND 13.3 ND
13-Dec-16 0.33 1 ND ND ND 8.3 ---
1,1-Dichloroethane 10-Apr-14 0.32 5 ND ---ND 8.6 ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.32 5 ND ---ND 8.1 ND
20-Jun-14 0.32 5 ND ---ND 8.0 ND
17-Jul-14 0.32 5 ND ---ND 5.7 ND
23-Oct-14 0.32 5 ND ND ND 6.9 ND
21-May-15 0.32 5 ND ND ND 5.5 ND
8-Dec-15 0.32 5 ND ND ND 7.2 ND
4-May-16 0.32 5 ND ND ND 6.5 ND
13-Dec-16 0.32 5 ND ND ND 6.0 ---
1,2-Dichloroethane 10-Apr-14 0.12 1 ND ---ND 0.77 J ND
NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.12 1 ND ---ND ND ND
20-Jun-14 0.12 1 ND ---ND 0.63 J ND
17-Jul-14 0.12 1 ND ---ND 0.79 J ND
23-Oct-14 0.12 1 ND ND ND 0.63 J ND
21-May-150.121NDNDNDNDND
8-Dec-15 0.24 1 ND ND ND 0.70 J ND
4-May-16 0.24 1 ND ND ND 0.74 J ND
13-Dec-16 0.24 1 ND ND ND 0.63 J ---
cis-1,2-Dichloroethene 10-Apr-14 0.19 5 ND ---ND 19.6 ND
NC 2L = 70 µg/L (10/23/07)6-May-14 0.19 5 ND ---ND 17.1 ND
20-Jun-14 0.19 5 ND ---ND 16 ND
17-Jul-14 0.19 5 ND ---ND 14.1 ND
23-Oct-14 0.19 5 ND ND ND 16.3 ND
21-May-15 0.19 5 ND ND ND 12.1 ND
8-Dec-15 0.19 5 ND ND ND 14.7 ND
4-May-16 0.19 5 ND ND ND 13.2 ND
13-Dec-16 0.19 5 ND ND ND 12.7 ---
Ethylbenzene 10-Apr-14 0.3 1 ND ---ND 1.2 ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.3 1 ND ---ND 1.3 ND
20-Jun-14 0.3 1 ND ---ND 0.77 J ND
17-Jul-14 0.3 1 ND ---ND 0.64 J ND
23-Oct-14 0.3 1 ND ND ND 1.3 ND
21-May-15 0.3 1 ND ND ND 1.1 ND
8-Dec-15 0.3 1 ND ND ND ND ND
4-May-16 0.3 1 ND ND ND 0.72 J ND
13-Dec-16 0.3 1 ND ND ND ND ---
2-Hexanone (MBK)10-Apr-14 0.46 50 ND ---0.55 J ND ND
GWPS = 280 µg/L (01/01/10)6-May-14 0.46 50 ND ---ND ND ND
20-Jun-14 0.46 50 ND ---ND ND ND
17-Jul-14 0.46 50 ND ---ND ND ND
23-Oct-140.4650NDNDNDNDND
GWPS = 280 µg/L (02/01/15)21-May-15 0.46 50 ND ND ND ND ND
8-Dec-15 0.46 50 ND ND ND ND ND
4-Methyl-2-pentanone (MIBK)10-Apr-14 0.33 100 ND ---ND 3.7 J ND
GWPS = 560 µg/L (12/7/10)6-May-14 0.33 100 ND ---ND 8.2 J ND
20-Jun-14 0.33 100 ND ---ND ND ND
17-Jul-14 0.33 100 ND ---ND ND ND
23-Oct-14 0.33 100 ND ND ND 1.5 J ND
21-May-15 0.33 100 ND ND ND ND
8-Dec-150.33100NDNDNDNDND
4-May-16 0.33 100 ND ND ND 0.89 J ND
13-Dec-16 0.33 100 ND ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 6
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Methane 10-Apr-14 3.3 6.6 ---------------
6-May-14 3.3 6.6 ---------4,150 ---
20-Jun-14 3.3 6.6 ---------------
17-Jul-14 3.3 6.6 ---------------
23-Oct-14 3.3 6.6 ---------6,820 ---
21-May-15 3.3 6.6 ---------4,900 ---
8-Dec-15 3.3 6.6 ---------3,112 2.0 J
13-Dec-16 100 100 ---------15,300 J ---
Methylene Chloride 8-Dec-15 0.97 1 ND ND ND ND 2.0
4-May-16 0.97 1 ND ND ND ND ND
13-Dec-16 0.97 1 ND ND ND ND ---
NC 2L = 5 (02/01/15)
Tetrahydrofuran 10-Apr-14 3.1 10 ND ---ND 923 ND
NC 2L = NE (01/01/10)6-May-14 3.1 10 ND ---ND 848 ND
20-Jun-14 3.1 10 ND ---ND 758 ND
17-Jul-14 3.1 10 ND ---ND 841 ND
23-Oct-14 3.1 10 ND ND ND 744 ND
21-May-15 3.1 10 ND ND ND 407 ND
8-Dec-15 3.1 10 ND ND ND 39.1 ND
4-May-16 3.1 10 ND ND ND 313 ND
13-Dec-16 3.1 10 ND ND ND ND ---
Toluene 10-Apr-14 0.26 1 ND ---ND 0.62 J ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.26 1 ND ---ND 0.68 J ND
20-Jun-14 0.26 1 ND ---ND 0.32 J ND
17-Jul-14 0.26 1 ND ---ND 0.28 J ND
23-Oct-14 0.26 1 ND ND ND 0.66 J ND
21-May-15 0.26 1 ND ND ND 0.48 J ND
8-Dec-150.261NDNDNDNDND
4-May-16 0.26 1 ND ND ND 0.49 J ND
13-Dec-16 0.26 1 ND ND ND ND ---
Trichloroethene 10-Apr-14 0.47 1 ND ---ND 2.7 ND
NC 2L = 3 µg/L (01/01/10)6-May-14 0.47 1 ND ---ND 2.1 ND
20-Jun-14 0.47 1 ND ---ND 2.2 ND
17-Jul-14 0.47 1 ND ---ND 2.5 ND
23-Oct-14 0.47 1 ND ND ND 1.8 ND
21-May-15 0.47 1 ND ND ND 0.92 J ND
8-Dec-15 0.47 1 ND ND ND 2.1 ND
4-May-16 0.47 1 ND ND ND 1.7 ND
13-Dec-16 0.47 1 ND ND ND 1.8 ---
Vinyl chloride 4-May-16 0.62 1 ND ND ND 1.8 ND
Verification Sample >9-Jun-16 0.62 1 ---------ND ND
NC 2L = 0.03 µg/L (02/01/15)13-Dec-16 0.62 1 ND ND ND ND ---
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 6
Joyce Engineering
APPENDIX D:
HISTORICAL DETECTED GROUNDWATER CONSTITUENTS
Sample
Analyte Collection Date DL QL MW-21 MW-20 MW-22S MW-38 Blanks
Xylene (Total)10-Apr-14 0.66 5 ND ---ND 16.9 ND
NC 2L = 500 µg/L (01/01/10)6-May-14 0.66 5 ND ---ND 19.3 ND
20-Jun-14 0.66 5 ND ---ND 2.5 J ND
17-Jul-14 0.66 5 ND ---ND 8.8 ND
23-Oct-14 0.66 5 ND ND ND 18.7 ND
21-May-15 0.66 5 ND ND ND 17.1 ND
8-Dec-15 0.66 5 ND ND ND 1.6 J ND
4-May-16 0.66 5 ND ND ND 11.5 ND
13-Dec-16 0.66 5 ND ND ND ND ---
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (SWSL).
DL = Laboratory Detection Limit.
--- = Not sampled for this parameter or Not reported.
ND = Not Detected at or above the DL.
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on similar concentrations detected in field, trip, or method blanks).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.
GWPS = Groundwater Protection Standard set by NC-DENR-SWS for constituents with no listed NC 2L standard.
NE = No NC 2L or GWPS established.
Values above the NC 2L Standard or GWPS are bold.
Background data: April to July 2014.
Verification Sampling Event for metals in MW-22S was performed on February 4, 2016
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 6
Joyce Engineering

Appendix E

Historical Detected Constituents in Additional Wells and Piezometers

APPENDIX E:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
Organic Compounds
Acetone 18-Feb-13 10.0 100 19.8 J ------ND ---ND ND
18-Jul-13 10.0 100 ------------ND ---15.80 J
NC 2L = 6,000 µg/L (01/01/10)6-May-14 10.0 100 ------------------ND
22-Oct-14 10.0 100 ------------------ND
21-May-15 10.0 100 ------------------ND
9-Dec-15 10.0 100 ------------------ND
Benzene 18-Feb-13 0.25 1.0 8.0 --- --- ND --- ND ND
18-Jul-13 0.25 1.0 --- --- --- ---7.6 --- ND
NC 2L = 1 µg/L (10/23/07)6-May-14 0.25 1.0 8.7 4.6 --- ND ND ND ND
22-Oct-14 0.25 1.0 8.3 3.3 ND ND ND ND ND
21-May-15 0.25 1.0 5.8 2.0 ND ND ND ND ND
9-Dec-15 0.25 1.0 5.8 1.2 ND ND ND ND ND
4-May-16 0.25 1.0 6.7 1.3 ND ND ND ND ND
14-Dec-16 0.25 1.0 5.5 0.9JNDNDNDNDND
Chlorobenzene 18-Feb-13 0.23 3.0 0.760 J ------ND ---ND ND
18-Jul-13 0.23 3.0 ------------0.480 J ---ND
NC 2L = 50 µg/L (10/23/07)6-May-14 0.23 3.0 ------------------ND
22-Oct-14 0.23 3.0 ------------------ND
21-May-15 0.23 3.0 ------------------ND
9-Dec-15 0.23 3.0 ------------------ND
Chloroethane 18-Feb-13 0.54 10.0 1.10 J ------ND ---ND ND
18-Jul-13 0.54 10.0 ------------ND ---ND
NC 2L = 3,000 µg/L (01/01/10)6-May-14 0.54 10.0 ------------------ND
22-Oct-14 0.54 10.0 ------------------ND
21-May-15 0.54 10.0 ------------------ND
9-Dec-15 0.54 10.0 ------------------ND
1,2-Dichlorobenzene 18-Feb-13 0.30 5.0 0.44 J ------ND ---ND ND
18-Jul-13 0.30 5.0 ------------0.61 J ---ND
NC 2L = 20 µg/L (01/01/10)6-May-14 0.30 5.0 ------------------ND
22-Oct-14 0.30 5.0 ------------------ND
21-May-15 0.30 5.0 ------------------ND
9-Dec-15 0.30 5.0 ------------------ND
1,4-Dichlorobenzene 18-Feb-13 0.33 1.0 18.0 --- --- ND --- ND ND
18-Jul-13 0.33 1.0 ------------6.5 ---ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.33 1.0 10.0 2.3 --- ND ND ND ND
22-Oct-14 0.33 1.0 15.2 1.6 ND ND ND ND ND
21-May-15 0.33 1.0 18.7 1.4 ND ND ND ND ND
9-Dec-15 0.33 1.0 19.6 1.0 ND ND ND ND ND
4-May-16 0.33 1.0 16.5 0.9JNDNDNDND---
14-Dec-16 0.33 1.0 15.8 0.7JNDNDNDNDND
1,1-Dichloroethane 18-Feb-13 0.32 5.0 7.9 --- --- ND --- ND ND
18-Jul-13 0.32 5.0 ------------11.3 ---ND
NC 2L = 6 µg/L (01/01/10)6-May-14 0.32 5.0 11.6 7.1 --- ND ND ND ND
22-Oct-14 0.32 5.0 9.0 4.9JNDNDNDNDND
21-May-15 0.32 5.0 4.8 J 2.4JNDNDNDNDND
9-Dec-15 0.32 5.0 5.9 2.2 J ND ND ND ND ND
4-May-16 0.32 5.0 5.9 1.5 J ND ND ND ND ---
14-Dec-16 0.32 5.0 4.4 J 0.9 J ND ND ND ND ND
1,2-Dichloroethane 18-Feb-13 0.12 1.0 1.0 --- --- ND --- ND ND
18-Jul-13 0.12 1.0 ------------0.54 J ---ND
NC 2L = 0.4 µg/L (01/01/10)6-May-14 0.12 1.0 0.78 J ND ---ND ND ND ND
22-Oct-14 0.12 1.0 0.92 J ND ND ND ND ND ND
21-May-15 0.12 1.0 ND ND ND ND ND ND ND
9-Dec-15 0.24 1.0 0.66 J ND ND ND ND ND ND
4-May-16 0.24 1.0 0.92 J ND ND ND ND ND ---
14-Dec-16 0.24 1.0 0.77 J ND ND ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 3
Joyce Engineering
APPENDIX E:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
cis-1,2-Dichloroethylene 18-Feb-13 0.19 5.0 21.0 ------ND ---ND ND
18-Jul-13 0.19 5.0 ------------19.3 ---ND
NC 2L = 70 µg/L (10/23/07)6-May-14 0.19 5.0 ------------------ND
22-Oct-14 0.19 5.0 ------------------ND
21-May-15 0.19 5.0 ------------------ND
9-Dec-15 0.19 5.0 ------------------ND
Ethylbenzene 18-Feb-13 0.30 1.0 23.2 ------ND ---ND ND
18-Jul-13 0.30 1.0 ------------0.94 J ---ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.30 1.0 ------------------ND
22-Oct-14 0.30 1.0 ------------------ND
21-May-15 0.30 1.0 ------------------ND
9-Dec-15 0.30 1.0 ------------------ND
Methylene Chloride 18-Feb-13 0.97 1.0 17.9 --- --- ND --- ND ND
18-Jul-13 0.97 1.0 NS --- --- ---16.4 --- ND
NC 2L = 5 µg/L (01/01/10)6-May-14 0.97 1.0 24.1 16.7 --- ND ND ND 2.20
22-Oct-14 0.97 1.0 15.7 1.6 ND ND ND ND ND
21-May-15 0.97 1.0 9.5 B 4.4 B ND ND ND ND 1.70
9-Dec-15 0.97 1.0 11.2 B 2.6 B ND ND ND ND 2.0
4-May-16 0.97 1.0 3.1 2.0 ND ND ND ND ---
14-Dec-16 0.97 1.0 ND ND ND ND ND ND ND
Tetrachloroethene 18-Feb-13 0.46 1.0 5.5 --- --- ND --- ND ND
18-Jul-13 0.46 1.0 NS ---------7.8 ---ND
NC 2L = 0.7 µg/L (10/23/07)6-May-14 0.46 1.0 7.9 6.9 --- ND ND ND ND
22-Oct-14 0.46 1.0 7.3 5.2 ND ND ND ND ND
21-May-15 0.46 1.0 6.0 3.3 ND ND ND ND ND
9-Dec-15 0.46 1.0 5.0 2.1 ND ND ND ND ND
4-May-16 0.46 1.0 4.5 2.0 ND ND ND ND ---
14-Dec-16 0.46 1.0 ND 1.4 ND ND ND ND ND
Toluene 18-Feb-13 0.26 1.0 44.10 ------ND ---ND ND
18-Jul-13 0.26 1.0 ------------1.50 ---ND
NC 2L = 600 µg/L (01/01/10)6-May-14 0.26 1.0 ------------------ND
22-Oct-14 0.26 1.0 ------------------ND
21-May-15 0.26 1.0 ------------------ND
9-Dec-15 0.26 1.0 ------------------ND
Trichloroethene 18-Feb-13 0.47 1.0 3.6 --- --- ND --- ND ND
18-Jul-13 0.47 1.0 ------------5.8 ---ND
NC 2L = 3 µg/L (01/01/10)6-May-14 0.47 1.0 6.0 4.3 --- ND ND ND ND
22-Oct-14 0.47 1.0 5.1 3.4 ND ND ND ND ND
21-May-15 0.47 1.0 3.5 2.1 ND ND ND ND ND
9-Dec-15 0.47 1.0 2.9 1.1 ND ND ND ND ND
4-May-16 0.47 1.0 3.1 --- ND ND ND ND ---
14-Dec-16 0.47 1.0 ND 0.8 J ND ND ND ND ND
Trichlorofluoromethane 18-Feb-13 0.20 1.0 0.650 J ------ND ---ND ND
18-Jul-13 0.20 1.0 ------------0.890 J ---ND
NC 2L = 2,000 µg/L (01/01/10)6-May-14 0.20 1.0 ------------------ND
22-Oct-14 0.20 1.0 ------------------ND
21-May-15 0.20 1.0 ------------------ND
9-Dec-15 0.20 1.0 ------------------ND
Vinyl chloride 18-Feb-13 0.62 1.0 1.2 --- --- ND --- ND ND
18-Jul-13 0.62 1.0 ------------ND ---ND
NC 2L = 0.03 µg/L (01/01/10)6-May-14 0.62 1.0 1.1 ND --- ND ND ND ND
22-Oct-14 0.62 1.0 0.87 J ND ND ND ND ND ND
21-May-15 0.62 1.0 ND ND ND ND ND ND ND
9-Dec-15 0.62 1.0 0.80 J ND ND ND ND ND ND
4-May-16 0.62 1.0 0.80 J ND ND ND ND ND ---
14-Dec-16 0.62 1.0 ND ND ND ND ND ND ND
Xylene (Total)18-Feb-13 0.66 2.0 295 ------ND ---ND ND
18-Jul-13 0.66 2.0 ------------92.5 ---ND
NC 2L = 500 µg/L (01/01/10)6-May-14 0.66 2.0 ------------------ND
22-Oct-14 0.66 2.0 ------------------ND
21-May-15 0.66 2.0 ---ND ND ND ND ---ND
9-Dec-15 0.66 2.0 ---ND ND ND ND ---ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 3
Joyce Engineering
APPENDIX E:
DETECTED CONSTITUENTS IN ADDITIONAL WELLS/PIEZOMETERS
Sample
Analyte Collection Date DL RL MW-36 MW-15S PZ-12 PZ-30S PZ-31 PZ-35 Blanks
Carbon Dioxide 14-Dec-16 450 5000 510000 350000 35000 22000 14000 29000 ---
(Dissolved Carbon Dioxide)
Methane 18-Feb-13 0.66 2.0 ---------------------
(Dissolved Methane)18-Jul-13 0.66 2.0 ---------------------
6-May-14 0.66 2.0 348 9940 ---ND ND ND ---
22-Oct-14 3.30 6.6 8450 13000 ND ND ND ND ND
21-May-15 0.63 10.0 173 4680 2.0 J 1.5 J 1.7 J 2.0 J ---
9-Dec-15 0.63 10.0 3780 8550 3.0 J 2.5 J 4.8 J 2.7 J ---
4-May-16 0.49 10.0 8920 7860 1.6 J 1.6 J 1.8 J 2.3 J ---
14-Dec-16 200 200 32200 16700 ND ND 27.0 J ND ---
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.ND = Not Detected above the DL.
DL = Laboratory Detection Limit.J = Estimated value - Concentration is less than the SWSL but greater than the DL.
RL = SWSL = Solid Waste Section Reporting Limit.B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination).
NC 2L = Groundwater Standard from 15A NCAC 2L.0202.Values above the NC 2L Standard are bold
Italics = Constituent of Concern (COC).
nle = No longer exists (MW-34 was accidentaly destroyed during construciton activties).
--- = Not reported or Not monitored
MW-36 was converted from PZ-36.
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 3
Joyce Engineering

Appendix F

Historical Detected Surface Water Constituents

APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Inorganic Compounds
Antimony 6-Nov-08 2.6 6.0 ND 8.4 ---ND
3-Jun-09 2.6 6.0 ND ND --- ND
18-Nov-09 2.6 6.0 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.6 6.0 ND ND --- ND
1-Dec-10 2.6 6.0 ND ND --- ND
1-Jun-11 2.6 6.0 ND ND --- ND
20-Dec-11 5.0 6.0 ND ND --- ND
30-May-12 5.0 6.0 ND ND --- ND
5-Dec-12 5.0 6.0 ND ND --- ND
12-Jun-13 5.0 6.0 ND ND --- ND
28-Oct-13 5.0 6.0 ND ND --- ND
6-May-14 5.0 6.0 ND ND --- ND
22-Oct-14 5.0 6.0 --- ND ND ND
21-May-15 3.8 6.0 ND ND ND ND
9-Dec-15 3.8 6.0 ND ND ND ND
NC 2B = 5.6 µg/L (03/01/16) 4-May-16 3.8 6.0 ND ND ND ND
14-Dec-16 3.8 6.0 ND ND ND ND
Arsenic 6-Nov-08 2.7 10.0 2.9 B 4.5 B ---4.1 J
3-Jun-09 2.7 10.0 ND 4.5 J --- ND
18-Nov-09 2.7 10.0 ND ND --- ND
NC 2B = 10 µg/L (05/01/07) 15-Jun-10 2.7 10.0 ND ND --- ND
1-Dec-10 2.7 10.0 ND ND --- ND
1-Jun-11 2.7 10.0 ND ND --- ND
20-Dec-11 5.0 10.0 ND ND --- ND
30-May-12 5.0 10.0 ND ND --- ND
5-Dec-12 5.0 10.0 ND ND --- ND
12-Jun-13 5.0 10.0 ND ND --- ND
28-Oct-13 5.0 10.0 ND ND --- ND
6-May-14 5.0 10.0 ND ND --- ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 10 µg/L (03/01/16) 4-May-16 2.5 10.0 3.0 J ND 3.3 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 1 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Barium 30-May-07 --- 100 81.3 J 23.8 J ---0.2 J
29-Nov-07 --- 100 116 27.5 J --- 0.50 J
29-May-08 0.2 100 71.9 J 19.6 J ---ND
6-Nov-08 0.20 100 82.5 J 40.2 B ---9.6 J
3-Jun-09 0.20 100 104 36.2 B --- 15.9 J
18-Nov-09 0.20 100 49.9 B 15.7 B --- 20.1 J
NC 2B = 1,000 µg/L (05/01/07)15-Jun-10 0.20 100 47.6 J 20.7 J --- 0.77 J
1-Dec-10 0.20 100 39.8 J 46.8 J ---ND
1-Jun-11 0.20 100 51.6 J 19.9 J ---ND
20-Dec-11 5.0 100 63.7 J 13.9 J ---ND
30-May-12 5.0 100 16.9 J 22.0 J ---ND
5-Dec-12 5.0 100 69.9 J 24.8 J ---ND
12-Jun-13 5.0 100 54.9 B 40.0 B ---13.6 J
28-Oct-13 5.0 100 35.4 J 20.8 J ---ND
6-May-14 5.0 100 37.0 J 17.8 J ---ND
22-Oct-14 5.0 100 --- 25.5 J 19.8 J ND
21-May-15 2.5 100 53.0 J 14.6 J 21.6 J ND
9-Dec-15 2.5 100 26.1 J 23.4 J 27.8 J ND
NC 2B = 1,000 µg/L (03/01/16)4-May-16 2.5 100 41.4 J 37.3 J 51.0 J ND
14-Dec-16 2.5 100 44.7 J 21.2 J 17.5 J ND
Beryllium 14-Nov-02 --- 2 2.0 B 2.2 B ---2.1
14-May-03 --- 2 ND ND ---ND
20-Nov-03 --- 2 ND ND ---ND
6-May-04 --- 2 ND ND ---ND
10-Nov-04 --- 2 ND ND ---ND
5-May-05 --- 2 ND ND ---ND
3-Nov-05 --- 2 ND ND ---ND
25-May-06 --- 2 ND ND ---ND
2-Nov-06 --- 2 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.10 1.0 ND ND ---ND
6-Nov-08 0.10 1.0 0.24 B 0.37 B ---0.29 J
3-Jun-09 0.10 1.0 0.64 J 0.21 J ---ND
18-Nov-09 0.10 1.0 ND ND ---ND
NC 2B = 6.5 µg/L (05/01/07)15-Jun-10 0.10 1.0 ND ND ---ND
1-Dec-10 0.10 1.0 ND ND ---ND
1-Jun-11 0.10 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 6.5 µg/L Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 2 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cadmium 7-Nov-01 --- 1 ND 1.0 ---ND
22-May-02 --- 1 ND 1.7 B ---1.3
14-Nov-02 --- 1 ND ND ---ND
14-May-03 --- 1 ND ND ---ND
20-Nov-03 --- 1 ND ND ---ND
6-May-04 --- 1 ND ND ---ND
10-Nov-04 --- 1 ND ND ---ND
5-May-05 --- 1 ND ND ---ND
3-Nov-05 --- 1 ND ND ---ND
25-May-06 --- 1 ND ND ---ND
2-Nov-06 --- 1 ND ND ---ND
30-May-07 --- 1 ND ND ---ND
29-Nov-07 --- 1 ND ND ---ND
29-May-08 0.5 1.0 ND ND ---ND
6-Nov-08 0.50 1.0 ND ND ---ND
3-Jun-09 0.50 1.0 ND ND ---ND
18-Nov-09 0.50 1.0 ND ND ---ND
NC 2B = 2 µg/L (05/01/07)15-Jun-10 0.50 1.0 ND ND ---ND
1-Dec-10 0.50 1.0 ND ND ---ND
1-Jun-11 0.50 1.0 ND ND ---ND
20-Dec-11 1.0 1.0 ND ND ---ND
30-May-12 1.0 1.0 ND ND ---ND
5-Dec-12 1.0 1.0 ND ND ---ND
12-Jun-13 1.0 1.0 ND ND ---ND
28-Oct-13 1.0 1.0 ND ND ---ND
6-May-14 1.0 1.0 ND ND ---ND
22-Oct-14 1.0 1.0 --- ND ND ND
21-May-15 0.5 1.0 ND ND ND ND
9-Dec-15 0.5 1.0 ND ND ND ND
NC 2B = 0.15 µg/L Chronic (03/01/16)*4-May-16 0.5 1.0 ND ND ND ND
14-Dec-16 0.5 1.0 ND ND ND ND
Chromium, total 6-Nov-08 0.40 10.0 ND 0.47 J ---ND
3-Jun-09 0.40 10.0 7.5 J 3.2 J ---ND
18-Nov-09 0.40 10.0 ND ND ---ND
NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 1.2 B 0.48 B --- 0.74 J
1-Dec-10 0.40 10.0 0.68 B 5.1 J --- 0.51 J
1-Jun-11 0.40 10.0 0.59 B 0.59 B --- 0.73 J
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND 9.7 J ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 11 µg/L Chronic (03/01/16)*4-May-16 2.5 10.0 4.7 J 4.6 J 8.8 J ND
14-Oct-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 3 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Cobalt 22-May-02 --- 10 14.0 17.0 --- 11.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND 10.0 ---ND
20-Nov-03 --- 10 14.0 ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 10.0 ND ---ND
5-May-05 --- 10 10.0 ND ---ND
3-Nov-05 --- 10 16.0 ND ---ND
25-May-06 --- 10 12 ND ---ND
2-Nov-06 --- 10 13.6 ND ---ND
30-May-07 --- 10 12.3 8.8 J ---ND
29-Nov-07 --- 10 19.0 2.1 J ---ND
29-May-08 0.60 10.0 13.7 ND ---ND
6-Nov-08 0.60 10.0 12.6 ND --- 0.65 J
3-Jun-09 0.60 10.0 11.9 B 6.6 B ---7.6 J
18-Nov-09 0.60 10.0 3.6 J 4.6 J ---ND
NC 2B = NE (05/01/07)15-Jun-10 0.60 10.0 6.4 J 22.3 ---ND
1-Dec-10 0.60 10.0 0.76 J 4.1 J ---ND
1-Jun-11 0.60 10.0 2.0 J 1.7 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 29.0 7.7 J ---ND
12-Jun-13 5.0 10.0 ND 9.1 J ---ND
28-Oct-13 5.0 10.0 11.5 12.4 ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 6.3 J ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 3 µg/L (03/01/16)4-May-16 2.5 10.0 4.0 J 5.6 J 3.3 J ND
14-Dec-16 2.5 10.0 5.9 J ND ND ND
Copper 29-May-08 0.30 10.0 ND 1.3 B --- 0.37 J
6-Nov-08 4.0 10.0 0.45 B 3.4 J --- 0.65 J
3-Jun-09 0.30 10.0 6.6 J 2.1 J ---ND
18-Nov-09 0.30 10.0 ND ND ---ND
NC 2B = 7 µg/L (05/01/07)15-Jun-10 0.30 10.0 0.56 B ND --- 0.77 J
1-Dec-10 0.30 10.0 3.6 J 5.9 J ---ND
1-Jun-11 0.30 10.0 1.8 J 0.35 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 5.2 B ND ---9.8 J
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 2.7 µg/L Chronic (3/1/16)*4-May-16 2.5 10.0 4.6 J 5.5 J 11 ND
resample 17-May-16 2.5 10.0 --- --- ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 4 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Lead 3-Jun-09 4.0 10.0 7.3 J ND ---ND
18-Nov-09 4.0 10.0 ND ND ---ND
NC 2B = 25 µg/L (05/01/07)15-Jun-10 4.0 10.0 ND ND ---ND
1-Dec-10 4.0 10.0 ND 4.6 J ---ND
1-Jun-11 4.0 10.0 ND ND ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 14 µg/L Acute, 0.54 µg/L Chronic * 4-May-16 2.5 10.0 ND 4.9 J 7.2 J ND
14-Dec-16 2.5 10.0 ND ND ND ND
Nickel 3-Jun-09 1.7 50.0 5.5 B ND ---1.7 J
18-Nov-09 1.7 50.0 ND ND ---ND
NC 2B = 25 µg/L (05/01/07)15-Jun-10 1.7 50.0 ND ND ---ND
1-Dec-10 1.7 50.0 2.8 J 2.8 J ---ND
1-Jun-11 1.7 50.0 ND ND ---2.3 J
20-Dec-11 5.0 50.0 ND ND ---ND
30-May-12 5.0 50.0 ND ND ---ND
5-Dec-12 5.0 50.0 ND ND ---ND
12-Jun-13 5.0 50.0 ND ND ---ND
28-Oct-13 5.0 50.0 ND ND ---ND
6-May-14 5.0 50.0 ND ND ---ND
22-Oct-14 5.0 50.0 --- ND ND ND
21-May-15 2.5 50.0 ND ND ND ND
9-Dec-15 2.5 50.0 ND ND ND ND
NC 2B = 16 µg/L Chronic (03/01/16)*4-May-16 2.5 50.0 3.8 J 3.9 J 6.7 J ND
14-Dec-16 2.5 50.0 ND ND ND ND
Selenium 6-Nov-08 3.8 10 ND 10.9 ---ND
3-Jun-09 3.8 10.0 ND ND ---ND
18-Nov-09 3.8 10.0 ND ND ---ND
NC 2B = 5 µg/L (05/01/07)15-Jun-10 3.8 10.0 ND ND ---ND
1-Dec-10 3.8 10.0 ND ND ---ND
1-Jun-11 3.8 10.0 ND ND ---ND
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND ---ND
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND ND ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 5 µg/L (03/01/16)4-May-16 5.0 10.0 ND ND ND ND
14-Dec-16 5.0 10.0 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 5 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Silver 22-May-02 --- 10 16.0 B 15.0 B --- 15.0
14-Nov-02 --- 10 ND ND ---ND
14-May-03 --- 10 ND ND ---ND
20-Nov-03 --- 10 ND ND ---ND
6-May-04 --- 10 ND ND ---ND
10-Nov-04 --- 10 ND ND ---ND
5-May-05 --- 10 ND ND ---ND
3-Nov-05 --- 10 ND ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 10 ND ND ---ND
29-Nov-07 --- 10 ND ND ---ND
29-May-08 0.10 10.0 0.29 J 0.13 J ---ND
6-Nov-08 0.10 10.0 0.72 B 0.38 B --- 0.23 J
3-Jun-09 0.10 10.0 0.18 B ND --- 0.31 J
18-Nov-09 0.10 10.0 0.27 B 0.23 B --- 0.23 J
NC 2B = 0.06 µg/L (05/01/07)15-Jun-10 0.10 10.0 ND ND ---ND
1-Dec-10 0.10 10.0 ND ND ---ND
1-Jun-11 0.10 10.0 ND 0.22 J ---ND
20-Dec-11 5.0 10.0 ND ND ---ND
30-May-12 5.0 10.0 ND ND ---ND
5-Dec-12 5.0 10.0 ND ND ---ND
12-Jun-13 5.0 10.0 ND ND ---ND
28-Oct-13 5.0 10.0 ND ND ---ND
6-May-14 5.0 10.0 ND ND ---ND
22-Oct-14 5.0 10.0 --- ND ND ND
21-May-15 2.5 10.0 ND ND ND ND
9-Dec-15 2.5 10.0 ND ND ND ND
NC 2B = 0.06 µg/L Chronic (03/01/16)*4-May-16 2.5 10.0 ND ND ND ND
14-Dec-16 2.5 10.0 ND ND ND ND
Thallium 5-May-05 --- 10 22.0 11.0 ---ND
3-Nov-05 --- 10 20.0 ND ---ND
25-May-06 --- 10 ND ND ---ND
2-Nov-06 --- 10 ND ND ---ND
30-May-07 --- 5.5 0.053 J ND ---ND
29-Nov-07 --- 5.5 0.055 J ND ---ND
29-May-08 3.0 5.5 ND ND ---ND
6-Nov-08 3.0 5.5 ND ND ---ND
3-Jun-09 3.0 5.5 ND ND ---ND
18-Nov-09 3.0 5.5 ND ND ---4.2 J
NC 2B = NE (05/01/07)15-Jun-10 3.0 5.5 3.2 J ND ---ND
1-Dec-10 3.0 5.5 ND ND ---4.0 J
1-Jun-11 3.0 5.5 ND ND ---ND
20-Dec-11 5.4 5.5 ND ND ---ND
30-May-12 5.4 5.5 ND ND ---ND
5-Dec-12 5.4 5.5 ND ND ---ND
12-Jun-13 5.4 5.5 ND ND ---ND
28-Oct-13 5.4 5.5 ND ND ---ND
6-May-14 5.4 5.5 ND ND ---ND
22-Oct-14 5.4 5.5 --- ND ND ND
21-May-15 5.0 5.5 ND ND ND ND
9-Dec-15 5.0 5.5 ND ND ND ND
NC 2B = 0.24 (03/01/16)4-May-16 5.0 5.5 ND ND ND ND
14-Dec-16 5.0 5.5 ND ND ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 6 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Vanadium 6-Nov-08 0.20 25.0 0.90 B 8.9 B ---2.1 J
3-Jun-09 0.20 25.0 17.4 J 7.5 J ---1.0 J
18-Nov-09 0.20 25.0 0.26 B 0.30 B --- 0.56 J
NC 2B = NE (05/01/07)15-Jun-10 0.20 25.0 1.5 B 1.0 B --- 0.98 J
1-Dec-10 0.20 25.0 1.1 J 13.7 J ---ND
1-Jun-11 0.20 25.0 1.1 J 0.74 J ---ND
20-Dec-11 5.0 25.0 ND ND ---ND
30-May-12 5.0 25.0 ND ND ---ND
5-Dec-12 5.0 25.0 ND ND ---ND
12-Jun-13 5.0 25.0 7.6 J ND ---ND
28-Oct-13 5.0 25.0 ND ND ---ND
6-May-14 5.0 25.0 ND ND ---ND
22-Oct-14 5.0 25.0 --- ND ND ND
21-May-15 2.5 25.0 7.5 J ND 4.1 J ND
9-Dec-15 2.5 25.0 ND ND 3.9 J ND
4-May-16 2.5 25.0 10.9 J 11.4 J 23.9 J ND
14-Dec-16 2.5 25.0 ND ND ND ND
Zinc 30-May-07 --- 10 1.8 B ND ---1.6 J
29-Nov-07 --- 10 9.6 B ND ---3.1 J
29-May-08 0.40 10.0 6.0 B ND ---3.0 J
6-Nov-08 0.40 10.0 0.82 B 1.4 B ---2.7 J
3-Jun-09 0.40 10.0 33.7 B 9.6 B --- 82.0
18-Nov-09 0.40 10.0 2.2 B 2.5 B ---3.1 J
NC 2B = 50 µg/L (05/01/07)15-Jun-10 0.40 10.0 ND ND ---ND
1-Dec-10 0.40 10.0 8.8 J 6.6 J --- 0.62 J
1-Jun-11 0.40 10.0 15.1 B 21.5 B --- 13.7
20-Dec-11 10.0 10.0 ND ND ---ND
30-May-12 10.0 10.0 ND ND ---ND
5-Dec-12 10.0 10.0 ND ND ---ND
12-Jun-13 10.0 10.0 ND ND --- 76.5
28-Oct-13 10.0 10.0 ND ND ---ND
6-May-14 10.0 10.0 ND ND ---ND
22-Oct-14 10.0 10.0 --- ND ND ND
21-May-15 5.0 10.0 ND 5.8 J ND ND
9-Dec-15 5.0 10.0 ND ND ND ND
NC 2B = 36 µg/L Acute, Chronic (03/01/16)* 4-May-16 5.0 10.0 8.7 J 7.7 J 15.2 ND
14-Dec-16 5.0 10.0 ND ND 6.9 J ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 7 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
Organic Compounds
Acetone 29-Nov-07 --- 100 3.6 B ND --- 5.1 J
29-May-08 20 100 ND ND --- ND
6-Nov-08 20 100 ND ND --- ND
3-Jun-09 2.2 100 5.7 J ND --- ND
18-Nov-09 2.2 100 ND ND --- ND
NC 2B = NE (05/01/07) 15-Jun-10 2.2 100 2.2 B 2.3 B --- 7.2 J
1-Dec-10 2.2 100 ND ND --- 3.7 J
1-Jun-11 2.2 100 5.4 B 2.9 B --- 3.9 J
20-Dec-11 2.2 100 ND ND --- ND
30-May-12 2.2 100 ND ND --- ND
5-Dec-12 10.0 100 ND ND --- ND
12-Jun-13 10.0 100 ND ND --- ND
28-Oct-13 10.0 100 ND ND --- ND
6-May-14 10.0 100 ND ND --- ND
22-Oct-14 10.0 100 --- ND ND ND
21-May-15 10.0 100 ND ND ND ND
9-Dec-15 10.0 100 ND ND ND ND
NC 2B = 1,100 mg/L (03/01/16) 4-May-16 10.0 100 ND ND ND ND
14-Dec-16 10.0 100 ND ND ND ND
Chloromethane 15-Jun-10 0.11 1.0 ND 0.11 J --- ND
NC 2B = NE (05/01/07) 1-Dec-10 0.11 1.0 ND ND --- ND
1-Jun-11 0.11 1.0 ND ND --- ND
20-Dec-11 0.11 1.0 ND ND --- ND
30-May-12 0.11 1.0 ND ND --- ND
5-Dec-12 0.11 1.0 ND ND --- ND
12-Jun-13 0.11 1.0 ND ND --- ND
28-Oct-13 0.11 1.0 ND ND --- ND
6-May-14 0.11 1.0 ND ND --- ND
22-Oct-14 0.11 1.0 --- ND ND ND
21-May-15 0.11 1.0 ND ND ND ND
9-Dec-15 0.11 1.0 ND ND ND ND
NC 2B = NE (03/01/16) 4-May-16 0.11 1.0 ND ND ND ND
14-Dec-16 0.11 1.0 ND ND ND 0.17 J
Trichloroethene 14-Dec-16 0.47 1.0 ND 0.52 J ND ND
NC 2B = 30 µg/L (03/01/16)
1,1-Dichloroethane 1-Jun-11 0.32 5.0 ND 0.41 J --- ND
NC 2B = NE (05/01/07) 20-Dec-11 0.32 5.0 ND ND --- ND
30-May-12 0.32 5.0 ND ND --- ND
5-Dec-12 0.32 5.0 ND 1.6 J --- ND
12-Jun-13 0.32 5.0 ND ND --- ND
28-Oct-13 0.32 5.0 ND 0.96 J --- ND
6-May-14 0.32 5.0 ND ND --- ND
22-Oct-14 0.32 5.0 --- 1.5 J ND ND
21-May-15 0.32 5.0 ND ND ND ND
9-Dec-15 0.32 5.0 ND ND ND ND
NC 2B = 0.38 µg/L (03/01/16) 4-May-16 0.32 5.0 ND ND ND ND
14-Dec-16 0.32 5.0 ND 2.6 J ND ND
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 8 of 9
Joyce Engineering
APPENDIX F:
HISTORICAL DETECTED SURFACE WATER CONSTITUENTS
Sample
Analyte Collection Date DL RL SMP-5 SMP-6 SMP-7 Blanks
cis-1,2-Dichloroethene 22-Oct-14 0.2 5.0 --- 0.20 J ND ND
NC 2B = NE (05/15/13)21-May-15 0.2 5.0 ND ND ND ND
9-Dec-15 0.2 5.0 ND ND ND ND
NC 2B = 60 µg/L (03/01/16)4-May-16 0.2 5.0 ND ND ND ND
14-Dec-16 0.2 5.0 ND 0.43 J ND ND
Notes:
All concentrations in micrograms per liter (µg/L) = parts per billion.
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and SWSL for December 2006 - present).
DL = Laboratory Detection Limit.
NI = Monitoring well not yet installed.
AB = Monitoring well abandoned.
--- = Not sampled for this parameter or Not reported
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
J = Estimated value - concentration is less than the RL but greater than the DL.
B = Blank-Qualified (Concentration suspected to reflect laboratory or field contamination based on
similar concentrations detected in field, trip, or method blanks).
D = Sample was diluted when analyzed.
NC 2B = Groundwater Standard from 15A NCAC 2B.
NE = No NC 2B established.
Values above the NC 2B Standard are bold.
Surface waters classified as WS-IV (water supply IV, highly developed), B (primary recreation, fresh water), and CA (critical area).
based on dissolved metal and in-stream water hardness results. Site specific values may be calculated based on water hardness at time of sampling.
*NC 2B Groundwater Standards and Protective Values updated March 2016 to include acute and chronic exposure levels for designated metals
Burke County John's River Landfill - Phase 1A
Permit 12-03 Page 9 of 9
Joyce Engineering